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Sample records for remediation system process

  1. Tank Waste Remediation System optimized processing strategy

    SciTech Connect

    Slaathaug, E.J.; Boldt, A.L.; Boomer, K.D.; Galbraith, J.D.; Leach, C.E.; Waldo, T.L.

    1996-03-01

    This report provides an alternative strategy evolved from the current Hanford Site Tank Waste Remediation System (TWRS) programmatic baseline for accomplishing the treatment and disposal of the Hanford Site tank wastes. This optimized processing strategy performs the major elements of the TWRS Program, but modifies the deployment of selected treatment technologies to reduce the program cost. The present program for development of waste retrieval, pretreatment, and vitrification technologies continues, but the optimized processing strategy reuses a single facility to accomplish the separations/low-activity waste (LAW) vitrification and the high-level waste (HLW) vitrification processes sequentially, thereby eliminating the need for a separate HLW vitrification facility.

  2. Tank waste remediation system process engineering instruction manual

    SciTech Connect

    ADAMS, M.R.

    1998-11-04

    The purpose of the Tank Waste Remediation System (TWRS) Process Engineering Instruction Manual is to provide guidance and direction to TWRS Process Engineering staff regarding conduct of business. The objective is to establish a disciplined and consistent approach to business such that the work processes within TWRS Process Engineering are safe, high quality, disciplined, efficient, and consistent with Lockheed Martin Hanford Corporation Policies and Procedures. The sections within this manual are of two types: for compliance and for guidance. For compliance sections are intended to be followed per-the-letter until such time as they are formally changed per Section 2.0 of this manual. For guidance sections are intended to be used by the staff for guidance in the conduct of work where technical judgment and discernment are required. The guidance sections shall also be changed per Section 2.0 of this manual. The required header for each manual section is illustrated in Section 2.0, Manual Change Control procedure. It is intended that this manual be used as a training and indoctrination resource for employees of the TWRS Process Engineering organization. The manual shall be required reading for all TWRS Process Engineering staff, matrixed, and subcontracted employees.

  3. Control of Groundwater Remediation Process as Distributed Parameter System

    NASA Astrophysics Data System (ADS)

    Mendel, M.; Kovács, T.; Hulkó, G.

    2014-12-01

    Pollution of groundwater requires the implementation of appropriate solutions which can be deployed for several years. The case of local groundwater contamination and its subsequent spread may result in contamination of drinking water sources or other disasters. This publication aims to design and demonstrate control of pumping wells for a model task of groundwater remediation. The task consists of appropriately spaced soil with input parameters, pumping wells and control system. Model of controlled system is made in the program MODFLOW using the finitedifference method as distributed parameter system. Control problem is solved by DPS Blockset for MATLAB & Simulink.

  4. Facility design philosophy: Tank Waste Remediation System Process support and infrastructure definition

    SciTech Connect

    Leach, C.E.; Galbraith, J.D.; Grant, P.R.; Francuz, D.J.; Schroeder, P.J.

    1995-11-01

    This report documents the current facility design philosophy for the Tank Waste Remediation System (TWRS) process support and infrastructure definition. The Tank Waste Remediation System Facility Configuration Study (FCS) initially documented the identification and definition of support functions and infrastructure essential to the TWRS processing mission. Since the issuance of the FCS, the Westinghouse Hanford Company (WHC) has proceeded to develop information and requirements essential for the technical definition of the TWRS treatment processing programs.

  5. Tank waste remediation system privatization infrastructure program requirements and document management process guide

    SciTech Connect

    ROOT, R.W.

    1999-05-18

    This guide provides the Tank Waste Remediation System Privatization Infrastructure Program management with processes and requirements to appropriately control information and documents in accordance with the Tank Waste Remediation System Configuration Management Plan (Vann 1998b). This includes documents and information created by the program, as well as non-program generated materials submitted to the project. It provides appropriate approval/control, distribution and filing systems.

  6. Tank waste remediation system optimized processing strategy with an altered treatment scheme

    SciTech Connect

    Slaathaug, E.J.

    1996-03-01

    This report provides an alternative strategy evolved from the current Hanford Site Tank Waste Remediation System (TWRS) programmatic baseline for accomplishing the treatment and disposal of the Hanford Site tank wastes. This optimized processing strategy with an altered treatment scheme performs the major elements of the TWRS Program, but modifies the deployment of selected treatment technologies to reduce the program cost. The present program for development of waste retrieval, pretreatment, and vitrification technologies continues, but the optimized processing strategy reuses a single facility to accomplish the separations/low-activity waste (LAW) vitrification and the high-level waste (HLW) vitrification processes sequentially, thereby eliminating the need for a separate HLW vitrification facility.

  7. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation.

    PubMed

    De Biase, Cecilia; Carminati, Andrea; Oswald, Sascha E; Thullner, Martin

    2013-11-01

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile losses to the atmosphere. Especially for (potentially) toxic VOCs, the latter needs to be minimized to limit atmospheric emissions. In this study, numerical simulation was used to investigate quantitatively the removal of volatile organic compounds in two pilot-scale water treatment systems: an unplanted vertical flow filter and a planted one, which could also be called a vertical flow constructed wetland, both used for the treatment of contaminated groundwater. These systems were intermittently loaded with contaminated water containing benzene and MTBE as main VOCs. The highly dynamic but permanently unsaturated conditions in the porous medium facilitated aerobic biodegradation but could lead to volatile emissions of the contaminants. Experimental data from porous material analyses, flow rate measurements, solute tracer and gas tracer test, as well as contaminant concentration measurements at the boundaries of the systems were used to constrain a numerical reactive transport modeling approach. Numerical simulations considered unsaturated water flow, transport of species in the aqueous and the gas phase as well as aerobic degradation processes, which made it possible to quantify the rates of biodegradation and volatile emissions and calculating their contribution to total contaminant removal. A range of degradation rates was determined using experimental results of both systems under two operation modes and validated by field data obtained at different operation modes applied to the filters. For both filters, simulations and experimental data point to high biodegradation rates, if the flow filters have had time to build up their removal capacity. For this case volatile

  8. Tank Waste Remediation System Guide

    SciTech Connect

    Robershotte, M.A.; Dirks, L.L.; Seaver, D.A.; Bothers, A.J.; Madden, M.S.

    1995-06-01

    The scope, number and complexity of Tank Waste Remediation System (TWRS) decisions require an integrated, consistent, and logical approach to decision making. TWRS has adopted a seven-step decision process applicable to all decisions. Not all decisions, however, require the same degree of rigor/detail. The decision impact will dictate the appropriate required detail. In the entire process, values, both from the public as well as from the decision makers, play a key role. This document concludes with a general discussion of the implementation process that includes the roles of concerned parties.

  9. Toxic Remediation System And Method

    DOEpatents

    Matthews, Stephen M.; Schonberg, Russell G.; Fadness, David R.

    1996-07-23

    What is disclosed is a novel toxic waste remediation system designed to provide on-site destruction of a wide variety of hazardous organic volatile hydrocarbons, including but not limited to halogenated and aromatic hydrocarbons in the vapor phase. This invention utilizes a detoxification plenum and radiation treatment which transforms hazardous organic compounds into non-hazardous substances.

  10. Tank Waste Remediation System tank waste pretreatment and vitrification process development testing requirements assessment

    SciTech Connect

    Howden, G.F.

    1994-10-24

    A multi-faceted study was initiated in November 1993 to provide assurance that needed testing capabilities, facilities, and support infrastructure (sampling systems, casks, transportation systems, permits, etc.) would be available when needed for process and equipment development to support pretreatment and vitrification facility design and construction schedules. This first major report provides a snapshot of the known testing needs for pretreatment, low-level waste (LLW) and high-level waste (HLW) vitrification, and documents the results of a series of preliminary studies and workshops to define the issues needing resolution by cold or hot testing. Identified in this report are more than 140 Hanford Site tank waste pretreatment and LLW/HLW vitrification technology issues that can only be resolved by testing. The report also broadly characterizes the level of testing needed to resolve each issue. A second report will provide a strategy(ies) for ensuring timely test capability. Later reports will assess the capabilities of existing facilities to support needed testing and will recommend siting of the tests together with needed facility and infrastructure upgrades or additions.

  11. Remediation of PAH-contaminated soil at a gas manufacturing plant by a combined two-phase partition system washing and microbial degradation process.

    PubMed

    Gong, Xuan; Xu, Xinyang; Gong, Zongqiang; Li, Xiaojun; Jia, Chunyun; Guo, Meixia; Li, Haibo

    2015-08-01

    The aim of this study was to design a remediation technique using both soil washing and microbial degradation to remove polycyclic aromatic hydrocarbons (PAHs) from contaminated soil. PAH biodegradation by inoculation of Mycobacterium sp. was first tested. The effectiveness of washing agents (Tween 80 solution, biodiesel, and a two-phase partition system (TPPS)) was then evaluated with column experiments. Third, the combination of TPPS washing and microbial degradation was studied. PAH bioavailability before and after biodegradation and the joint remediation was also assessed using hydroxypropyl-β-cyclodextrin (HPCD) extraction. Only phenanthrene and anthracene were noticeably biodegradable when the soil was inoculated with Mycobacterium sp. TPPS containing 2% (v/v) biodiesel and 2.5% (w/v) Tween 80 was used as the washing agent for the joint remediation test because it gave higher PAH extractions than Tween 80 solution with lower doses, and there was less residue in the soil. Joint TPPS washing and microbial degradation gave a total PAH removal of 92.6%, which was much higher than the results from either the biodegradation or washing experiments alone. Removals of all high molecular weight (HMW) PAHs were improved. Bioavailable concentrations of all PAHs decreased significantly after the joint remediation process, indicating that there were reduced risks from all PAHs. The results demonstrate that the combination of TPPS washing and microbial degradation is a useful and innovative process for remediation of PAH-contaminated soils.

  12. Tank waste remediation system phase I high-level waste feed processability assessment report

    SciTech Connect

    Lambert, S.L.; Stegen, G.E., Westinghouse Hanford

    1996-08-01

    This report evaluates the effects of feed composition on the Phase I high-level waste immobilization process and interim storage facility requirements for the high-level waste glass.Several different Phase I staging (retrieval, blending, and pretreatment) scenarios were used to generate example feed compositions for glass formulations, testing, and glass sensitivity analysis. Glass models and data form laboratory glass studies were used to estimate achievable waste loading and corresponding glass volumes for various Phase I feeds. Key issues related to feed process ability, feed composition, uncertainty, and immobilization process technology are identified for future consideration in other tank waste disposal program activities.

  13. The Remedial Action Assessment System Automated Decision Support for the CERCLA RI/FS Process

    DTIC Science & Technology

    1992-01-01

    the basic object-oriented structure used by RAAS to depict the CERCLA technology screening process (Bohn, 1991). The " cell " object contains the 26...up the site depicted in the " cell " object according to the general response action (GRA) defined by the user. Technologies cell UserInefc Figure 5...and 28 physical properties which might be encountered in a treatment process. The site object is a temporary instance of the cell object which shows

  14. WASTE PACKAGE REMEDIATION SYSTEM DESCRIPTION DOCUMENT

    SciTech Connect

    N.D. Sudan

    2000-06-22

    The Waste Package Remediation System remediates waste packages (WPs) and disposal containers (DCs) in one of two ways: preparation of rejected DC closure welds for repair or opening of the DC/WP. DCs are brought to the Waste Package Remediation System for preparation of rejected closure welds if testing of the closure weld by the Disposal Container Handling System indicates an unacceptable, but repairable, welding flaw. DC preparation of rejected closure welds will require removal of the weld in such a way that the Disposal Container Handling System may resume and complete the closure welding process. DCs/WPs are brought to the Waste Package Remediation System for opening if the Disposal Container Handling System testing of the DC closure weld indicates an unrepairable welding flaw, or if a WP is recovered from the subsurface repository because suspected damage to the WP or failure of the WP has occurred. DC/WP opening will require cutting of the DC/WP such that a temporary seal may be installed and the waste inside the DC/WP removed by another system. The system operates in a Waste Package Remediation System hot cell located in the Waste Handling Building that has direct access to the Disposal Container Handling System. One DC/WP at a time can be handled in the hot cell. The DC/WP arrives on a transfer cart, is positioned within the cell for system operations, and exits the cell without being removed from the cart. The system includes a wide variety of remotely operated components including a manipulator with hoist and/or jib crane, viewing systems, machine tools for opening WPs, and equipment used to perform pressure and gas composition sampling. Remotely operated equipment is designed to facilitate DC/WP decontamination and hot cell equipment maintenance, and interchangeable components are provided where appropriate. The Waste Package Remediation System interfaces with the Disposal Container Handling System for the receipt and transport of WPs and DCs. The Waste

  15. Tank waste remediation system high-level waste feed processability assessment report

    SciTech Connect

    Lambert, S.L.; Kim, D.S.

    1994-12-01

    This study evaluates the effect of feed composition on the performance of the high-level vitrification process. It is assumed in this study that the tank wastes are retrieved and blended by tank farms, producing 12 different blends from the single-shell tank farms, two blends of double-shell tank waste, and a separately defined all-tank blend. This blending scenario was chosen only for evaluating the impact of composition on the volume of high- level waste glass produced. Special glass compositions were formulated for each waste blend based on glass property models and the properties of similar glasses. These glasses were formulated to meet the applicable viscosity, electrical conductivity, and liquidus temperature constraints for the identified candidate melters. Candidate melters in this study include the low-temperature stirred melter, which operates at 1050{degrees}C; the reference Hanford Waste Vitrification Plant liquid-fed ceramic melter, which operates at 1150{degrees}C; and the high-temperature, joule-heated melter and the cold-crucible melter, which operate over a temperature range of 1150{degrees}C to 1400{degrees}C. In the most conservative case, it is estimated that 61,000 MT of glass will be produced if the Site`s high-level wastes are retrieved by tank farms and processed in the reference joule-heated melter. If an all-tank blend was processed under the same conditions, the reference melter would produce 21,250 MT of glass. If cross-tank blending were used, it is anticipated that $2.0 billion could be saved in repository disposal costs (based on an average disposal cost of $217,000 per canister) by blending the S, SX, B, and T Tank Farm wastes with other wastes prior to vitrification. General blending among all the tank farms is expected to produce great potential benefit.

  16. Tank waste remediation system systems engineering management plan

    SciTech Connect

    Peck, L.G.

    1996-02-06

    This Systems Engineering Management Plan (SEMP) describes the Tank Waste Remediation Systems (TWRS) implementation of U.S. Department of Energy (DOE) Systems Engineering (SE) policy provided in Tank Waste Remediation System Systems Engineering Management Policy, DOE/RL letter, 95-RTI-107, Oct. 31, 1995. This SEMP defines the products, process, organization, and procedures used by the TWRS Program to accomplish SE objectives. This TWRS SEMP is applicable to all aspects of the TWRS Program and will be used as the basis for tailoring SE to apply necessary concepts and principles to develop and mature the processes and physical systems necessary to achieve the desired end states of the program.

  17. Tank waste remediation system (TWRS) mission analysis

    SciTech Connect

    Rieck, R.H.

    1996-10-03

    The Tank Waste Remediation System Mission Analysis provides program level requirements and identifies system boundaries and interfaces. Measures of success appropriate to program level accomplishments are also identified.

  18. Tank waste remediation system mission analysis report

    SciTech Connect

    Acree, C.D.

    1998-01-09

    This document describes and analyzes the technical requirements that the Tank Waste Remediation System (TWRS) must satisfy for the mission. This document further defines the technical requirements that TWRS must satisfy to supply feed to the private contractors` facilities and to store or dispose the immobilized waste following processing in these facilities. This document uses a two phased approach to the analysis to reflect the two-phased nature of the mission.

  19. Site remediation using biological processes

    SciTech Connect

    Lei, J.; Sansregret, J.L.; Cyr, B.; Pouliot, Y.

    1995-11-01

    The main process used in the bioremediation of contaminated sites is the microbial degradation and mineralization of pollutants. The bioengineering processes developed and applied by the company to optimize the microbial degradation are described and full scale case studies are reviewed. In each case, the site characteristics (type of contaminants, nature of soil, geographic location, etc.) and the results obtained are presented. The selected projects cover different bioremediation techniques (biopile, bioventing and air sparging), different contaminants (PAH, PCP, hydrocarbons) and different types of industrial sites (former gas work plant, petroleum depot, refinery, etc.).

  20. Remediation processes for heavy metals contaminated soils

    SciTech Connect

    Torma, G.A.; Torma, A.E.; Hsu, Pei-Cheng

    1996-12-31

    This paper provides information on selected technologies available for remediation of metal contaminated soils and industrial effluent solutions. Because some of the industrial sites are contaminated with organics (solvents, gasolines and oils), an effort has been made to introduce the most frequently used cost-effective cleanup methods, such as {open_quotes}bioventing{close_quotes} and {open_quotes}composting.{close_quotes} The microorganisms involved in these processes are capable of degrading organic soil contaminants to environmentally harmless compounds: water and carbon dioxide. Heavy metals and radionuclides contaminated mining and industrial sites can be remediated by using adapted heap and dump leaching technologies, which can be chemical in nature or bio-assisted. The importance of volume reduction by physical separation is discussed. A special attention is devoted to the remediation of soils by leaching (soil washing) to remove heavy metal contaminants, such as chromium, lead, nickel and cadmium. Furthermore, the applicability of biosorption technology in the remediation of heavy metals and radionuclides contaminated industrial waste waters and acidic mining effluent solutions was indicated. 60 refs., 9 figs.

  1. Tank waste remediation system compensatory measure removal

    SciTech Connect

    MILLIKEN, N.J.

    1999-05-18

    In support of Fiscal Year 1998 Performance Agreement TWR1.4.3, ''Replace Compensatory Measures,'' the Tank Waste Remediation System is documenting the completion of field modifications supporting the removal of the temporary exemptions from the approved Tank Waste Remediation System Technical Safety Requirements (TSRs), HNF-SD-WM-TSR-006. These temporary exemptions or compensatory measures expire September 30, 1998.

  2. Tank waste remediation system engineering plan

    SciTech Connect

    Rifaey, S.H.

    1998-01-09

    This Engineering Plan describes the engineering process and controls that will be in place to support the Technical Baseline definition and manage its evolution and implementation to the field operations. This plan provides the vision for the engineering required to support the retrieval and disposal mission through Phase 1 and 2, which includes integrated data management of the Technical Baseline. Further, this plan describes the approach for moving from the ``as is`` condition of engineering practice, systems, and facilities to the desired ``to be`` configuration. To make this transition, Tank Waste Remediation System (TWRS) Engineering will become a center of excellence for TWRS which,will perform engineering in the most effective manner to meet the mission. TWRS engineering will process deviations from sitewide systems if necessary to meet the mission most effectively.

  3. Information Management System for Site Remediation Efforts.

    PubMed

    Laha; Mukherjee; Nebhrajani

    2000-05-01

    / Environmental regulatory agencies are responsible for protecting human health and the environment in their constituencies. Their responsibilities include the identification, evaluation, and cleanup of contaminated sites. Leaking underground storage tanks (USTs) constitute a major source of subsurface and groundwater contamination. A significant portion of a regulatory body's efforts may be directed toward the management of UST-contaminated sites. In order to manage remedial sites effectively, vast quantities of information must be maintained, including analytical dataon chemical contaminants, remedial design features, and performance details. Currently, most regulatory agencies maintain such information manually. This makes it difficult to manage the data effectively. Some agencies have introduced automated record-keeping systems. However, the ad hoc approach in these endeavors makes it difficult to efficiently analyze, disseminate, and utilize the data. This paper identifies the information requirements for UST-contaminated site management at the Waste Cleanup Section of the Department of Environmental Resources Management in Dade County, Florida. It presents a viable design for an information management system to meet these requirements. The proposed solution is based on a back-end relational database management system with relevant tools for sophisticated data analysis and data mining. The database is designed with all tables in the third normal form to ensure data integrity, flexible access, and efficient query processing. In addition to all standard reports required by the agency, the system provides answers to ad hoc queries that are typically difficult to answer under the existing system. The database also serves as a repository of information for a decision support system to aid engineering design and risk analysis. The system may be integrated with a geographic information system for effective presentation and dissemination of spatial data.

  4. Electrokinetic soil remediation: Advances and process enhancement

    SciTech Connect

    Hodko, D.; Franaszczuk, K.; Rogers, T.D.

    1995-12-31

    Electrokinetic remediation is an in situ emerging technology that offers potential cost and process benefits for contaminated soil treatment. The innovative approach under development at Lynntech, Inc. is based on the application of nonhomogeneous pulsed DC or AC electric fields with the objective to maximize rates of contaminant removal. The process combines several DC and AC electrokinetic phenomena occurring in soil when pulsed electric fields are applied across the electrodes positioned in the soil and utilize them for an enhanced contaminant removal from soil. Removal of contaminants is achieved by: (i) electroosmotic pore fluid flow; (ii) electromigration of anionic and cationic contaminants towards electrode wells, where they can be removed by electrodeposition, and, (iii) dielectrophoretically induced pore fluid flow and migration of charged and noncharged contaminants through the soil. Successful combination of DC and AC electrokinetic phenomena in soil presents a basis for an enhanced electrokinetic process for removal of both charged and noncharged contaminants from soil. The process utilizes an electrochemically produced acid in the anode well which propagates through the soil and solubilizes heavy metal ions in the pore fluid. An appropriate leachant. which depends on the type of soil and heavy metal contaminant, is electrokinetically delivered and distributed in soil to further enhance solubilization and mobilization of heavy metal contaminants through the soil. It can be efficiently combined with other existing in situ contaminated soil treatment processes, e.g. bioremediation, soil extraction and soil washing. A field scale study is initiated in 1995 and preliminary results will be described.

  5. Usability Studies of a Remedial Multimedia System.

    ERIC Educational Resources Information Center

    Anjaneyulu, K. S. R.; Singer, R. A.; Harding, R.

    1998-01-01

    Describes the formative evaluation of a multimedia computer system that provides remedial support for university students learning concepts concerning the structure and function of the human brain and describes usability studies of the system using the Software Usability Measurement Inventory (SUMI). Analysis of SUMI items and the student…

  6. Integrated system for remediation of contaminated soils

    SciTech Connect

    Khodadoust, A.P.; Sorial, G.A.; Wilson, G.J.; Suidan, M.T.; Griffiths, R.A.; Brenner, R.C.

    1999-11-01

    A pilot-scale study was conducted to evaluate an integrated system for the remediation of soils contaminated primarily with pentachlorophenol (PCP), a wood preserver. The integrated soil remediation system consisting of three unit processes (1) Soil solvent washing; (2) solvent recovery; and (3) biotreatment of the contaminant residual. Pilot-scale countercurrent solvent washing was carried out using a 95% ethanol solution--a solvent that in an earlier bench-scale study was found to be effective in removing PCP and hydrocarbons (HCs) from soils. Three-stage countercurrent solvent washing of a field-contaminated soil was performed using batches of 7.5 kg of soil and 30 L of solvent. The washed soil was rinsed with water in a single stage after three countercurrent wash stages. Pilot-scale, three-stage countercurrent solvent washing with 95% ethanol reduced the PCP and HC contamination on the soil by 98 and 95%, respectively. The spent solvent and the spent rinse water were combined as the spent wash fluid for further treatment. A pilot-scale distillation unit was used to recover the ethanol from the spent wash fluid. The HC constituents of the spent wash fluid were removed by pH adjustment prior to feeding the spent wash fluid to a distillation unit. Greater than 96% of the ethanol in the spent wash fluid was recovered in the distillate stream, whereas PCP was captured in the bottoms stream. The bottoms stream was treated sequentially in anaerobic and aerobic granular-activated carbon fluidized-bed reactors. Complete mineralization of PCP was achieved using this treatment train.

  7. Process safety management and interim or remedial action plans

    SciTech Connect

    Boss, M.J.; Henney, D.A.; Heitzman, V.K.; Day, D.W.

    1996-12-31

    Remedial Actions, including Interim Remedial Activities, often require the use of treatment facilities or stabilization techniques using on-site chemical processes. As such, the 29 CFR 1910.119 Process Safety Management (PSM) of Highly Hazardous Chemicals (PSM Standard) and the USEPA regulations for Risk Management Planning require that these chemicals and their attendant potential hazards be identified. A Hazard and Operation (HAZOP) study, Failure Mode and Effect Analysis (FMEA), Fault Tree Analysis, or equivalent graphic presentation of processes must be completed. These studies form a segment of the Process Hazard Analysis (PHA). HAZOP addresses each system and each element of a system that could deviate from normal operations and thus cause a hazard. A full assessment of each process is produced by looking at the hazards, consequences, causes and personnel protection needed. Many variables must be considered when choosing the appropriate PHA technique including the size of the plant, the number of processes, the types of processes, and the types of chemicals used. A mixture of these techniques may be required to adequately transmit information about the process being evaluated.

  8. Metallic iron for environmental remediation: learning from the Becher process.

    PubMed

    Noubactep, C

    2009-09-15

    Metallic iron (Fe(0)) is a moderately reducing agent that has been reported to be capable of reducing many environmental contaminants. Reduction by Fe(0) used for environmental remediation is a well-known process to organic chemists, corrosion scientists and hydrometallurgists. However, considering Fe(0) as a reducing agent for contaminants has faced considerable scepticism because of the universal role of oxide layers on Fe(0) in the process of electron transfer at the Fe(0)/oxide/water interface. This communication shows how progress achieved in developing the Becher process in hydrometallurgy could accelerate the comprehension of processes in Fe(0)/H(2)O systems for environmental remediation. The Becher process is an industrial process for the manufacture of synthetic rutile (TiO(2)) by selectively removing metallic iron (Fe(0)) from reduced ilmenite (RI). This process involves an aqueous oxygen leaching step at near neutral pH. Oxygen leaching suffers from serious limitations imposed by limited mass transport rates of dissolved oxygen across the matrix of iron oxides from initial Fe(0) oxidation. In a Fe(0)/H(2)O system pre-formed oxide layers similarly act as physical barrier limiting the transport of dissolved species (including contaminants and O(2)) to the Fe(0)/H(2)O interface. Instead of this universal role of oxide layers on Fe(0), improper conceptual models have been developed to rationalize electron transfer mechanisms at the Fe(0)/oxide/water interface.

  9. Tank waste remediation system program plan

    SciTech Connect

    Powell, R.W.

    1998-01-05

    This program plan establishes the framework for conduct of the Tank Waste Remediation System (TWRS) Project. The plan focuses on the TWRS Retrieval and Disposal Mission and is specifically intended to support the DOE mid-1998 Readiness to Proceed with Privatized Waste Treatment evaluation for establishing firm contracts for waste immobilization.

  10. Remediation System Evaluation, Ellis Property Superfund Site

    EPA Pesticide Factsheets

    The Ellis Property Superfund Site is located in a rural area of Burlington County, New Jersey. Most ofthe land at the site has not been developed. However, there is a building in a fenced area that is used tohouse the remedial system..

  11. Tank waste remediation system systems engineering management plan

    SciTech Connect

    Peck, L.G.

    1998-01-08

    This Systems Engineering Management Plan (SEMP) describes the Tank Waste Remediation System (TWRS) implementation of the US Department of Energy (DOE) systems engineering policy provided in 97-IMSD-193. The SEMP defines the products, process, organization, and procedures used by the TWRS Project to implement the policy. The SEMP will be used as the basis for tailoring the systems engineering applications to the development of the physical systems and processes necessary to achieve the desired end states of the program. It is a living document that will be revised as necessary to reflect changes in systems engineering guidance as the program evolves. The US Department of Energy-Headquarters has issued program management guidance, DOE Order 430. 1, Life Cycle Asset Management, and associated Good Practice Guides that include substantial systems engineering guidance.

  12. Method and system for extraction of chemicals from aquifer remediation effluent water

    DOEpatents

    McMurtrey, Ryan D.; Ginosar, Daniel M.; Moor, Kenneth S.; Shook, G. Michael; Barker, Donna L.

    2003-01-01

    A method and system for extraction of chemicals from an groundwater remediation aqueous effluent are provided. The extraction method utilizes a critical fluid for separation and recovery of chemicals employed in remediating groundwater contaminated with hazardous organic substances, and is particularly suited for separation and recovery of organic contaminants and process chemicals used in surfactant-based remediation technologies. The extraction method separates and recovers high-value chemicals from the remediation effluent and minimizes the volume of generated hazardous waste. The recovered chemicals can be recycled to the remediation process or stored for later use.

  13. Full-scale soil washing system remediates Superfund site

    SciTech Connect

    1993-11-01

    One of the first full-scale soil washing systems in the United States is currently being used to remediate the King of Prussia (KOP) Technical Corporation Superfund site (Winslow Township, New Jersey). The soil washing facility began operating at the site in June 1993. About 20,300 tons of soil require remediation, and operations were expected to be completed in October 1993. The soil washing process was supplied by Alternative Remedial Technologies, Inc. (ART) of Tampa, Florida, a 50-50 joint venture of Geraghty & Miller, Inc. and the Dutch company, Heidemij Realisatie. Heidemij developed the process and has been involved with hazardous soil washing in the Netherlands for about ten years. 1 tab., 1 fig.

  14. Testing and development strategy for the tank waste remediation system

    SciTech Connect

    Reddick, G.W.

    1994-12-01

    This document provides a strategy for performing radioactive (hot) and nonradioactive testing to support processing tank waste. It evaluates the need for hot pilot plant(s) to support pretreatment and other processing functions and presents a strategy for performing hot test work. A strategy also is provided for nonradioactive process and equipment testing. The testing strategy supports design, construction, startup, and operation of Tank Waste Remediation System (TWRS) facilities.

  15. SADA: Ecological Risk Based Decision Support System for Selective Remediation

    EPA Science Inventory

    Spatial Analysis and Decision Assistance (SADA) is freeware that implements terrestrial ecological risk assessment and yields a selective remediation design using its integral geographical information system, based on ecological and risk assessment inputs. Selective remediation ...

  16. SADA: Ecological Risk Based Decision Support System for Selective Remediation

    EPA Science Inventory

    Spatial Analysis and Decision Assistance (SADA) is freeware that implements terrestrial ecological risk assessment and yields a selective remediation design using its integral geographical information system, based on ecological and risk assessment inputs. Selective remediation ...

  17. Briefing paper -- Remedial Action Assessment System

    SciTech Connect

    Buelt, J.L.

    1990-04-01

    Congress has mandated a more comprehensive management of hazardous wastes with the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund'') and the Superfund Amendment and Reauthorization Act (SARA). This mandate includes restoration of disposal sites contaminated through past disposal practices. This mandate applies to facilities operated for and by the Department of Energy (DOE), just as it does to industrial and other institutions. To help implement the CERCLA/SARA remedial investigation and feasibility study (RI/FS) process in a consistent, timely, and cost-effective manner, a methodology needs to be developed that will allow definition, sorting, and screening of remediation technologies for each operable unit (waste site). This need is stated specifically in Section 2.2.2.1 of the October 1989 Applied Research, Development, Demonstration, Testing, and Evaluation (RDDT E) Plan of the DOE. This Briefing Paper is prepared to respond to this need. 1 fig.

  18. Cavitational Hydrothermal Oxidation: A New Remediation Process - Final Report

    SciTech Connect

    Suslick, K. S.

    2001-07-05

    During the past year, we have continued to make substantial scientific progress on our understanding of cavitation phenomena in aqueous media and applications of cavitation to remediation processes. Our efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions.

  19. Applications of Ecological Engineering Remedies for Uranium Processing Sites, USA

    SciTech Connect

    Waugh, William

    2016-05-23

    The U.S. Department of Energy (USDOE) is responsible for remediation of environmental contamination and long-term stewardship of sites associated with the legacy of nuclear weapons production during the Cold War in the United States. Protection of human health and the environment will be required for hundreds or even thousands of years at many legacy sites. USDOE continually evaluates and applies advances in science and technology to improve the effectiveness and sustainability of surface and groundwater remedies (USDOE 2011). This paper is a synopsis of ecological engineering applications that USDOE is evaluating to assess the effectiveness of remedies at former uranium processing sites in the southwestern United States. Ecological engineering remedies are predicated on the concept that natural ecological processes at legacy sites, once understood, can be beneficially enhanced or manipulated. Advances in tools for characterizing key processes and for monitoring remedy performance are demonstrating potential. We present test cases for four ecological engineering remedies that may be candidates for international applications.

  20. Environmental remediation and waste management information systems

    SciTech Connect

    Harrington, M.W.; Harlan, C.P.

    1993-12-31

    The purpose of this paper is to document a few of the many environmental information systems that currently exist worldwide. The paper is not meant to be a comprehensive list; merely a discussion of a few of the more technical environmental database systems that are available. Regulatory databases such as US Environmental Protection Agency`s (EPA`s) RODS (Records of Decision System) database [EPA, 1993] and cost databases such as EPA`s CORA (Cost of Remedial Action) database [EPA, 1993] are not included in this paper. Section 2 describes several US Department of Energy (DOE) Environmental Restoration and Waste Management (EM) information systems and databases. Section 3 discusses several US EPA information systems on waste sites and technologies. Section 4 summarizes a few of the European Community environmental information systems, networks, and clearinghouses. And finally, Section 5 provides a brief overview of Geographical Information Systems. Section 6 contains the references, and the Appendices contain supporting information.

  1. Portable System for Field-Feeding Greywater Remediation and Recycling

    DTIC Science & Technology

    2006-07-01

    with greywater reuse regulations2 base their water quality standards on the secondary treatment standard. In addition, each system’s process rate...to the system and converted to greywater . Of this added water, 80% is cleaned for reuse while 20% is unusable concentrate that requires backhauling...Field- Feeding Greywater Remediation and Recycling July 2006 Report Documentation Page Form ApprovedOMB No. 0704-0188 Public reporting burden for the

  2. Land use in the CERCLA remedy selection process. Directive

    SciTech Connect

    1995-05-01

    The directive presents additional information for considering land use in making remedy selection decisions under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) at National Priorities List (NPL) sites. The U.S. Environmental Protection Agency (EPA) believes that early community involvement, with a particular focus on the community`s desired future uses of property associated with the CERCLA site, should result in a more democratic decisionmaking process; greater community support for remedies selected as a result of this process; and more expedited, cost-effective cleanups.

  3. TECHNICAL GUIDANCE DOCUMENT: CONSTRUCTION QUALITY MANAGEMENT FOR REMEDIAL ACTION AND REMEDIAL DESIGN WASTE CONTAINMENT SYSTEMS

    EPA Science Inventory

    This Technical Guidance Document is intended to augment the numerous construction quality control and construction quality assurance (CQC and CQA) documents that are available far materials associated with waste containment systems developed for Superfund site remediation. In ge...

  4. Subsurface Remediation: Improving Long-Term Monitoring and Remedial Systems Performance Conference Proceedings

    EPA Pesticide Factsheets

    This document summarizes the presentations and workshops of a conference on improving long-term monitoring (LTM) and remedial systems performance that was held in St. Louis, Missouri between June 8th to 11th, 1999.

  5. TECHNICAL GUIDANCE DOCUMENT: CONSTRUCTION QUALITY MANAGEMENT FOR REMEDIAL ACTION AND REMEDIAL DESIGN WASTE CONTAINMENT SYSTEMS

    EPA Science Inventory

    This Technical Guidance Document is intended to augment the numerous construction quality control and construction quality assurance (CQC and CQA) documents that are available far materials associated with waste containment systems developed for Superfund site remediation. In ge...

  6. Spectral induced polarization for monitoring electrokinetic remediation processes

    NASA Astrophysics Data System (ADS)

    Masi, Matteo; Losito, Gabriella

    2015-12-01

    Electrokinetic remediation is an emerging technology for extracting heavy metals from contaminated soils and sediments. This method uses a direct or alternating electric field to induce the transport of contaminants toward the electrodes. The electric field also produces pH variations, sorption/desorption and precipitation/dissolution of species in the porous medium during remediation. Since heavy metal mobility is pH-dependent, the accurate control of pH inside the material is required in order to enhance the removal efficiency. The common approach for monitoring the remediation process both in laboratory and in the field is the chemical analysis of samples collected from discrete locations. The purpose of this study is the evaluation of Spectral Induced Polarization as an alternative method for monitoring geochemical changes in the contaminated mass during remediation. The advantage of this technique applied to field-scale is to offer higher resolution mapping of the remediation site and lower cost compared to the conventional sampling procedure. We carried out laboratory-scale electrokinetic remediation experiments on fine-grained marine sediments contaminated by heavy metal and we made Spectral Induced Polarization measurements before and after each treatment. Measurements were done in the frequency range 10- 3-103 Hz. By the deconvolution of the spectra using the Debye Decomposition method we obtained the mean relaxation time and total chargeability. The main finding of this work is that a linear relationship exists between the local total chargeability and pH, with good agreement. The observed behaviour of chargeability is interpreted as a direct consequence of the alteration of the zeta potential of the sediment particles due to pH changes. Such relationship has a significant value for the interpretation of induced polarization data, allowing the use of this technique for monitoring electrokinetic remediation at field-scale.

  7. Mathematical Modelling of Bacterial Populations in Bio-remediation Processes

    NASA Astrophysics Data System (ADS)

    Vasiliadou, Ioanna A.; Vayenas, Dimitris V.; Chrysikopoulos, Constantinos V.

    2011-09-01

    An understanding of bacterial behaviour concerns many field applications, such as the enhancement of water, wastewater and subsurface bio-remediation, the prevention of environmental pollution and the protection of human health. Numerous microorganisms have been identified to be able to degrade chemical pollutants, thus, a variety of bacteria are known that can be used in bio-remediation processes. In this study the development of mathematical models capable of describing bacterial behaviour considered in bio-augmentation plans, such as bacterial growth, consumption of nutrients, removal of pollutants, bacterial transport and attachment in porous media, is presented. The mathematical models may be used as a guide in designing and assessing the conditions under which areas contaminated with pollutants can be better remediated.

  8. Process for remediation of plastic waste

    DOEpatents

    Pol, Vilas G; Thiyagarajan, Pappannan

    2013-11-12

    A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of about 700.degree. C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically carbon nanotubes having a partially filled core (encapsulated) adjacent to one end of the nanotube. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.

  9. Process for remediation of plastic waste

    DOEpatents

    Pol, Vilas G [Westmont, IL; Thiyagarajan, Pappannan [Germantown, MD

    2012-04-10

    A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of 700.degree. C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically egg-shaped and spherical-shaped solid carbons. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.

  10. Remediation of phenol, lignin and paper effluents by advanced oxidative processes.

    PubMed

    Peralta-Zamora, P; Wypych, F; Carneiro, L M; Vaz, S R

    2004-12-01

    The tremendous environmental impact of pulping and bleaching effluents and the relatively low efficiency of the current biological remediation processes represent one of the most important problems of the paper industry. In this work the efficiency of heterogeneous and homogeneous advanced oxidative processes was evaluated toward the degradation of model substrates (phenol and lignin) and the remediation of paper effluents. Best results were found by application of the UV-H2O2 system, with almost total discoloration of both pulping and bleaching effluents and typical COD removal higher than 60%, at reaction times of 120 min. In view of the reported results, and mainly on account of the simplicity of the UV-H2O2 system, shows good potential for the advanced process to remediation of recalcitrant effluents like those studied in this present work.

  11. Dredging processes and remedy effectiveness: Relationship to the 4 Rs of environmental dredging.

    PubMed

    Bridges, Todd S; Gustavson, Karl E; Schroeder, Paul; Ells, Stephen J; Hayes, Donald; Nadeau, Steven C; Palermo, Michael R; Patmont, Clay

    2010-10-01

    Timely and effective remediation of contaminated sediments is essential for protecting human health and the environment and restoring beneficial uses to waterways. A number of site operational conditions influence the effect of environmental dredging of contaminated sediment on aquatic systems. Site experience shows that resuspension of contaminated sediment and release of contaminants occur during dredging and that contaminated sediment residuals will remain after operations. It is also understood that these processes affect the magnitude, distribution, and bioavailability of the contaminants, and hence the exposure and risk to receptors of concern. However, even after decades of sediment remediation project experience, substantial uncertainties still exist in our understanding of the cause-effect relationships relating dredging processes to risk. During the past few years, contaminated sediment site managers, researchers, and practitioners have recognized the need to better define and understand dredging-related processes. In this article, we present information and research needs on these processes as synthesized from recent symposia, reports, and remediation efforts. Although predictions about the effect of environmental dredging continue to improve, a clear need remains to better understand the effect that sediment remediation processes have on contaminant exposures and receptors of concern. Collecting, learning from, and incorporating new information into practice is the only avenue to improving the effectiveness of remedial operations. © 2010 SETAC.

  12. On-line monitoring of remediation process of chromium polluted soil using LIBS.

    PubMed

    Gondal, M A; Hussain, T; Yamani, Z H; Baig, M A

    2009-04-30

    Due to large growth in leather and textile industries to cater for the needs of a growing world population, contamination of soil and water resources by chromium has become a great threat for humans and animals. In this work, Laser Induced Breakdown Spectroscopy (LIBS) was applied to monitor the remediation process of soil contaminated with Chromium metal. This study was conducted at a laboratory scale by setting up an experiment in a container holding soil contaminated with chromium. This setup represents actual field conditions where remediation process could be applied and monitored for the removal of toxic metals like Cr. For generation of LIBS spectrum, the plasma was produced by focusing a pulsed Nd: YAG laser at 1064 nm on the soil contaminated with chromium under remediation process. The evaluation of the potential and capabilities of LIBS as a rapid tool for remediation process of contaminated sites is discussed in detail. Optimal experimental conditions were evaluated for improving the sensitivity of our LIBS system for monitoring of remediation process through parametric dependence study. The minimum detection limit of our spectrometer for chromium in soil matrix was 2 mg Kg(-1).

  13. Hanford site tank waste remediation system programmatic environmental review report

    SciTech Connect

    Haass, C.C.

    1998-09-03

    The US Department of Energy (DOE) committed in the Tank Waste Remediation System (TWRS) Environmental Impact Statement (EIS) Record of Decision (ROD) to perform future National Environmental Policy Act (NEPA) analysis at key points in the Program. Each review will address the potential impacts that new information may have on the environmental impacts presented in the TWRS EIS and support an assessment of whether DOE`s plans for remediating the tank waste are still pursuing the appropriate plan for remediation or whether adjustments to the program are needed. In response to this commitment, DOE prepared a Supplement Analysis (SA) to support the first of these reevaluations. Subsequent to the completion of the SA, the Phase IB negotiations process with private contractors resulted in several changes to the planned approach. These changes along with other new information regarding the TWRS Program have potential implications for Phase 1 and Phase 2 of tank waste retrieval and waste storage and/or disposal that may influence the environmental impacts of the Phased Implementation alternative. This report focuses on identifying those potential environmental impacts that may require NEPA analysis prior to authorization to begin facility construction and operations.

  14. Optimization of remediation strategies using vadose zone monitoring systems

    NASA Astrophysics Data System (ADS)

    Dahan, Ofer

    2016-04-01

    In-situ bio-remediation of the vadose zone depends mainly on the ability to change the subsurface hydrological, physical and chemical conditions in order to enable development of specific, indigenous, pollutants degrading bacteria. As such the remediation efficiency is much dependent on the ability to implement optimal hydraulic and chemical conditions in deep sections of the vadose zone. These conditions are usually determined in laboratory experiments where parameters such as the chemical composition of the soil water solution, redox potential and water content of the sediment are fully controlled. Usually, implementation of desired optimal degradation conditions in deep vadose zone at full scale field setups is achieved through infiltration of water enriched with chemical additives on the land surface. It is assumed that deep percolation into the vadose zone would create chemical conditions that promote biodegradation of specific compounds. However, application of water with specific chemical conditions near land surface dose not necessarily results in promoting of desired chemical and hydraulic conditions in deep sections of the vadose zone. A vadose-zone monitoring system (VMS) that was recently developed allows continuous monitoring of the hydrological and chemical properties of deep sections of the unsaturated zone. The VMS includes flexible time-domain reflectometry (FTDR) probes which allow continuous monitoring of the temporal variation of the vadose zone water content, and vadose-zone sampling ports (VSPs) which are designed to allow frequent sampling of the sediment pore-water and gas at multiple depths. Implementation of the vadose zone monitoring system in sites that undergoes active remediation provides real time information on the actual chemical and hydrological conditions in the vadose zone as the remediation process progresses. Up-to-date the system has been successfully implemented in several studies on water flow and contaminant transport in

  15. Level 1 remedial investigation work plan, 300 Area Process Ponds

    SciTech Connect

    Not Available

    1987-06-01

    This report discusses the objectives of the site characterization for the 300 Area Process Ponds which are to identify and quantify contamination at the ponds and to estimate their potential impact on human health and the environment. The results of the site characterization will be used to identify any future actions related to contamination at the site and to identify any additional data requirements needed to support selection of a remedial action. 9 refs., 12 figs., 8 tabs.

  16. Processes affecting the remediation of chromium-contaminated sites.

    PubMed Central

    Palmer, C D; Wittbrodt, P R

    1991-01-01

    The remediation of chromium-contaminated sites requires knowledge of the processes that control the migration and transformation of chromium. Advection, dispersion, and diffusion are physical processes affecting the rate at which contaminants can migrate in the subsurface. Heterogeneity is an important factor that affects the contribution of each of these mechanisms to the migration of chromium-laden waters. Redox reactions, chemical speciation, adsorption/desorption phenomena, and precipitation/dissolution reactions control the transformation and mobility of chromium. The reduction of CrVI to CrIII can occur in the presence of ferrous iron in solution or in mineral phases, reduced sulfur compounds, or soil organic matter. At neutral to alkaline pH, the CrIII precipitates as amorphous hydroxides or forms complexes with organic matter. CrIII is oxidized by manganese dioxide, a common mineral found in many soils. Solid-phase precipitates of hexavalent chromium such as barium chromate can serve either as sources or sinks for CrVI. Adsorption of CrVI in soils increases with decreasing chromium concentration, making it more difficult to remove the chromium as the concentration decreases during pump-and-treat remediation. Knowledge of these chemical and physical processes is important in developing and selecting effective, cost-efficient remediation designs for chromium-contaminated sites. PMID:1935849

  17. Evaluation of remedial countermeasures using the analytic network process.

    PubMed

    Promentilla, M A B; Furuichi, T; Ishii, K; Tanikawa, N

    2006-01-01

    The aim of this paper is to present an evaluation method to aid decision makers in the prioritization and selection of appropriate countermeasures at the planning stage of site remediation. We introduced a hierarchical network (hiernet) decision structure and applied the Analytic Network Process (ANP) supermatrix approach to measure the relative desirability of the remedial alternatives using the decision maker's value judgment as input. A simplified illustrative example is presented to elucidate the process, as it is being applied to evaluate the feasible remedial countermeasures of a contaminated site caused by uncontrolled landfill. Four decision models derived from the generalized hiernet were examined to describe the effect of hierarchic functional dependence, inner dependence and feedback cycle on the derivation of the priority weights. The ANP could provide a more flexible analytical framework to break down one's judgment through a more elaborate structure in a systematic way to understand the complexity of the decision problem. The proposed method therefore may not only aid in selecting the best alternative but also may help to facilitate communication to understand why an alternative is preferred over the other alternatives through the analysis of the derived weights and its underlying decision structure.

  18. Remediation System Evaluation, Former Occidental Facility in Tacoma, Washington

    EPA Pesticide Factsheets

    The former Occidental Chemical Corporation (OCC) property (“site”) is approximately 37 acres in extent and is located at 605 Alexander Avenue in Tacoma, Washington along the Hylebos Waterway. This is a Remediation System Evaluation document.

  19. In situ aeration: Air sparging, bioventing, and related remediation process

    SciTech Connect

    Hinchee, R.E.; Miller, R.N.; Johnson, P.C.

    1995-12-31

    This volume is part of a ten volume set of papers derived from the Third International In Situ and On-Site Bioreclamation Symposium which was held in San Diego, California, in April 1995. The purpose of the conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on bioremediation. This volume focuses on the use of air sparging, bioventing, and other aeration processes to remediate hydrocarbon-contaminated soils and groundwater. Individual papers have been processed separately for inclusion in the appropriate data bases.

  20. Remediation of a radioactively contaminated soil using a mobile soil-washing system

    SciTech Connect

    Grant, D.C.; Lahoda, E.J. ); Dietrich, A.J.; Weigle, D.H.; Keegan, C.P.; Sachse, J.D. )

    1993-01-01

    In order to obtain free-release of a former uranium mining site in Texas, it was required that the surface soil meet specific radiological guidelines. The soil has been contaminated with uranium and radium as a result of the spillage of well-drilling material, process solutions, and ion exchange resins during mining. To meet the required guidelines, the contaminated soil had to be either removed and disposed of off-site or remediated. For economic and long-term liability reasons, remediation of the soil by soil washing was performed. The remediation of this site utilizing the Scientific Ecology Group's soil washing system is discussed in this paper.

  1. Simulation and optimization technologies for petroleum waste management and remediation process control.

    PubMed

    Qin, X S; Huang, G H; He, L

    2009-01-01

    Leakage and spill of petroleum hydrocarbons from underground storage tanks and pipelines have posed significant threats to groundwater resources across many petroleum-contaminated sites. Remediation of these sites is essential for protecting the soil and groundwater resources and reducing risks to local communities. Although many efforts have been made, effective design and management of various remediation systems are still challenging to practitioners. In recent years, the subsurface simulation model has been combined with techniques of optimization to address important problems of contaminated site management. The combined simulation-optimization system accounts for the complex behavior of the subsurface system and identifies the best management strategy under consideration of the management objectives and constraints. During the past decades, a large number of studies were conducted to simulate contaminant flow and transport in the subsurface and seek cost-effective remediation designs. This paper gives a comprehensive review on recent developments, advancements, challenges, and barriers associated with simulation and optimization techniques in supporting process control of petroleum waste management and site remediation. A number of related methodologies and applications were examined. Perspectives of effective site management were investigated, demonstrating many demanding areas for enhanced research efforts, which include issues of data availability and reliability, concerns in uncertainty, necessity of post-modeling analysis, and usefulness of development of process control techniques.

  2. Building Sustainability into the Air Force Remediation Process

    DTIC Science & Technology

    2009-05-06

    Sustainability in AF Remediation: “Green” Remediation Phytoremediation , Travis AFB, CA  Sustainability metrics not new endeavor  ER programs focus on cost, risk...remediation technology examples:  Phytoremediation – 5  LNAPL recovery – 16  Passive in situ treatment Wetlands  Enh bio – 114  MNA – 105

  3. Effective remediation of fish processing waste using mixed culture biofilms capable of simultaneous nitrification and denitrification.

    PubMed

    Markande, Anoop R; Kapagunta, Chandrika; Patil, Pooja S; Nayak, Binaya B

    2016-09-01

    Fish processing waste water causes pollution and eutrophication of water bodies when released untreated. Use of bacteria capable of simultaneous nitrification and denitrification (SND) as biofilms on carriers in a moving bed bioreactor (MBBR) is a popular approach but seldom used for fish processing waste water remediation. Here, we studied the variations in biofilm formation and application activities by isolates Lysinibacillus sp. HT13, Alcaligenes sp. HT15 and Proteus sp. HT37 previously reported by us. While HT13 and HT15 formed significantly higher biofilms in polystyrene microtitre plates than on carriers, HT37 exhibited highest on carriers. A consortium of the three selected bacteria grown as biofilm on MBBR carriers exhibited better remediation of ammonia (200-600 ppm and 50 mM) than the individual isolates on carriers. The mixed biofilm set on the carriers was used for nitrogenous waste removal from fish processing waste water in 2 and 20 L setups. The total nitrogen estimated by elemental analysis showed complete remediation from 250 ppm in both 2 and 20 L waste water systems within 48 h. The usual toxic nitrogenous components-ammonia, nitrite and nitrate were also remediated efficiently. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Environmental biocatalysis: from remediation with enzymes to novel green processes.

    PubMed

    Alcalde, Miguel; Ferrer, Manuel; Plou, Francisco J; Ballesteros, Antonio

    2006-06-01

    Modern biocatalysis is developing new and precise tools to improve a wide range of production processes, which reduce energy and raw material consumption and generate less waste and toxic side-products. Biocatalysis is also achieving new advances in environmental fields, from enzymatic bioremediation to the synthesis of renewable and clean energies and biochemical cleaning of 'dirty' fossil fuels. Despite the obvious benefits of biocatalysis, the major hurdles hindering the exploitation of the repertoire of enzymatic processes are, in many cases, the high production costs and the low yields obtained. This article will discuss these issues, pinpointing specific new advances in recombinant DNA techniques amenable to future biocatalyst development, in addition to drawing the attention of the biotechnology community to the active pursuit and development of environmental biocatalysis, from remediation with enzymes to novel green processes.

  5. Remedy of dye manufacturing process effluent by UV/H2O2 process.

    PubMed

    Shu, Hung-Yee; Chang, Ming-Chin; Hsieh, Wen-Pin

    2006-01-16

    The effluent from dye manufacturing industry is more difficult to be treated than laboratory synthesized wastewater according to high variability of composition and color intensity. Thus, this study aimed to propose the method for remedying industrial effluent by UV/H2O2 process in a recirculated batch reactor system while considering the effects on hydrogen peroxide dosage, UV power and wastewater intensity for the removal of color and COD. From the experimental results, it was feasibly treated that the distinguished removal of color and COD by increasing the hydrogen peroxide dosage and UV power, but not by the strong intensity of industrial effluent. Therefore, UV/H2O2 process of the developed reactor was a positively superior treatment or pre-treatment for dye manufacturing plant effluent to comply the regulated requirements.

  6. Bioelectrochemical system platform for sustainable environmental remediation and energy generation.

    PubMed

    Wang, Heming; Luo, Haiping; Fallgren, Paul H; Jin, Song; Ren, Zhiyong Jason

    2015-01-01

    The increasing awareness of the energy-environment nexus is compelling the development of technologies that reduce environmental impacts during energy production as well as energy consumption during environmental remediation. Countries spend billions in pollution cleanup projects, and new technologies with low energy and chemical consumption are needed for sustainable remediation practice. This perspective review provides a comprehensive summary on the mechanisms of the new bioelectrochemical system (BES) platform technology for efficient and low cost remediation, including petroleum hydrocarbons, chlorinated solvents, perchlorate, azo dyes, and metals, and it also discusses the potential new uses of BES approach for some emerging contaminants remediation, such as CO2 in air and nutrients and micropollutants in water. The unique feature of BES for environmental remediation is the use of electrodes as non-exhaustible electron acceptors, or even donors, for contaminant degradation, which requires minimum energy or chemicals but instead produces sustainable energy for monitoring and other onsite uses. BES provides both oxidation (anode) and reduction (cathode) reactions that integrate microbial-electro-chemical removal mechanisms, so complex contaminants with different characteristics can be removed. We believe the BES platform carries great potential for sustainable remediation and hope this perspective provides background and insights for future research and development.

  7. Defining Uniform Processes for Remediation, Probation and Termination in Residency Training

    PubMed Central

    Smith, Jessica L.; Lypson, Monica; Silverberg, Mark; Weizberg, Moshe; Murano, Tiffany; Lukela, Michael; Santen, Sally A.

    2017-01-01

    It is important that residency programs identify trainees who progress appropriately, as well as identify residents who fail to achieve educational milestones as expected so they may be remediated. The process of remediation varies greatly across training programs, due in part to the lack of standardized definitions for good standing, remediation, probation, and termination. The purpose of this educational advancement is to propose a clear remediation framework including definitions, management processes, documentation expectations and appropriate notifications. Informal remediation is initiated when a resident’s performance is deficient in one or more of the outcomes-based milestones established by the Accreditation Council for Graduate Medical Education, but not significant enough to trigger formal remediation. Formal remediation occurs when deficiencies are significant enough to warrant formal documentation because informal remediation failed or because issues are substantial. The process includes documentation in the resident’s file and notification of the graduate medical education office; however, the documentation is not disclosed if the resident successfully remediates. Probation is initiated when a resident is unsuccessful in meeting the terms of formal remediation or if initial problems are significant enough to warrant immediate probation. The process is similar to formal remediation but also includes documentation extending to the final verification of training and employment letters. Termination involves other stakeholders and occurs when a resident is unsuccessful in meeting the terms of probation or if initial problems are significant enough to warrant immediate termination. PMID:28116019

  8. Development of a Groundwater Transport Simulation Tool for Remedial Process Optimization

    SciTech Connect

    Ivarson, Kristine A.; Hanson, James P.; Tonkin, M.; Miller, Charles W.; Baker, S.

    2015-01-14

    The groundwater remedy for hexavalent chromium at the Hanford Site includes operation of five large pump-and-treat systems along the Columbia River. The systems at the 100-HR-3 and 100-KR-4 groundwater operable units treat a total of about 9,840 liters per minute (2,600 gallons per minute) of groundwater to remove hexavalent chromium, and cover an area of nearly 26 square kilometers (10 square miles). The pump-and-treat systems result in large scale manipulation of groundwater flow direction, velocities, and most importantly, the contaminant plumes. Tracking of the plumes and predicting needed system modifications is part of the remedial process optimization, and is a continual process with the goal of reducing costs and shortening the timeframe to achieve the cleanup goals. While most of the initial system evaluations are conducted by assessing performance (e.g., reduction in contaminant concentration in groundwater and changes in inferred plume size), changes to the well field are often recommended. To determine the placement for new wells, well realignments, and modifications to pumping rates, it is important to be able to predict resultant plume changes. In smaller systems, it may be effective to make small scale changes periodically and adjust modifications based on groundwater monitoring results. Due to the expansive nature of the remediation systems at Hanford, however, additional tools were needed to predict the plume reactions to system changes. A computer simulation tool was developed to support pumping rate recommendations for optimization of large pump-and-treat groundwater remedy systems. This tool, called the Pumping Optimization Model, or POM, is based on a 1-layer derivation of a multi-layer contaminant transport model using MODFLOW and MT3D.

  9. Acceleration of the remediation process through interim action

    SciTech Connect

    Clark, T.R.; Throckmorton, J.D.; Hampshire, L.H.; Dalga, D.G.; Janke, R.J.

    1993-11-01

    During the Remedial Investigation and Feasibility Study (RI/FS) phase of a CERCLA cleanup, it is possible to implement interim actions at a site ``to respond to an immediate site threat or take advantage of an opportunity to significantly reduce risk quickly.`` An interim action is a short term action that addresses threats to public health and safety and is generally followed by the RI/FS process to achieve complete long term protection of human health and the environment. Typically, an interim action is small in scope and can be implemented quickly to reduce risks, such as the addition of a security fence around a known or suspected hazard, or construction of a temporary cap to reduce run-on/run-off from a contaminant source. For more specialized situations, however, the possibility exists to apply the intent of the interim action guidance to a much larger project scope. The primary focus of this paper is the discussion of the interim action approach for streamlined remedial action and presentation of an example large-scale project utilizing this approach at the Fernald Environmental Management Project (FEMP).

  10. Is Sustainable Remediation Now a Self-Sustaining Process? an International Progress Report

    NASA Astrophysics Data System (ADS)

    Smith, J. W. N.

    2014-12-01

    Sustainable remediation - the consideration of environmental, social and economic factors associated with soil and groundwater risk-management options, to help select the best overall solution - has been a rapidly evolving topic in recent years. The first published reference[1] to 'sustainable remediation' was in the title of a 1999 conference paper by Kearney et al., (1999), but activity really accelerated in the middle-late 2000's, with establishment of a number of collaborative sustainable remediation groups and fora, and increased publication rates in the peer reviewed literature (Fig 1). Figure 1. Journal paper publications with search term 'sustainable remediation' (SCOPUS survey, 17 July 2014) This presentation will review the international progress of sustainable remediation concept development and application in regulatory and corporate decision-making processes. It will look back at what has already been achieved, provide an update on the latest initiatives and developments, and look forward to what the future of sustainable remediation might look like. Specifically it will describe: Sustainable remediation frameworks: synergies and international collaboration; Latest guidance and tools developed by the various sustainable remediation organisations (SuRFs), including the SuRF-UK Best Management Practices and Tier 1 Briefcase; Best practice standard development by ASTM and ISO; Regulatory acceptance of sustainable remediation, including incorporation into legislation, and the NICOLE - Common Forum Joint statement on 'risk-informed and sustainable remediation' in Europe; Examples of corporate adoption of sustainable remediation principles. The presentation will conclude with a look forward to a vision of sustainable remediation in 2020.

  11. Computerized cognitive remediation improves verbal learning and processing speed in schizophrenia.

    PubMed

    Sartory, Gudrun; Zorn, Cornelia; Groetzinger, Gerd; Windgassen, Klaus

    2005-06-15

    Computerized cognitive remediation has resulted in improved executive function in schizophrenia, whereas results with regard to verbal memory were inconsistent. In the present study, 42 inpatients with schizophrenia were randomly assigned to a computerized cognitive remediation group or to a treatment-as-usual (TAU) control group. The remediation group received 15 sessions of computerized cognitive training (Cogpack) over a 3-week period. Neurocognitive functions were assessed at the beginning and end of this period. Compared to the control condition, remediation training resulted in improvements in verbal learning, processing speed and executive function (verbal fluency). The results indicate that cognitive remediation may lead to improvements beyond those of executive function.

  12. Monitoring of Soil Remediation Process in the Metal Mining Area

    NASA Astrophysics Data System (ADS)

    Kim, Kyoung-Woong; Ko, Myoung-Soo; Han, Hyeop-jo; Lee, Sang-Ho; Na, So-Young

    2016-04-01

    Stabilization using proper additives is an effective soil remediation technique to reduce As mobility in soil. Several researches have reported that Fe-containing materials such as amorphous Fe-oxides, goethite and hematite were effective in As immobilization and therefore acid mine drainage sludge (AMDS) may be potential material for As immobilization. The AMDS is the by-product from electrochemical treatment of acid mine drainage and mainly contains Fe-oxide. The Chungyang area in Korea is located in the vicinity of the huge abandoned Au-Ag Gubong mine which was closed in the 1970s. Large amounts of mine tailings have been remained without proper treatment and the mobilization of mine tailings can be manly occurred during the summer heavy rainfall season. Soil contamination from this mobilization may become an urgent issue because it can cause the contamination of groundwater and crop plants in sequence. In order to reduce the mobilization of the mine tailings, the pilot scale study of in-situ stabilization using AMDS was applied after the batch and column experiments in the lab. For the monitoring of stabilization process, we used to determine the As concentration in crop plants grown on the field site but it is not easily applicable because of time and cost. Therefore, we may need simple monitoring technique to measure the mobility or leachability which can be comparable with As concentration in crop plants. We compared several extraction methods to suggest the representative single extraction method for the monitoring of soil stabilization efficiency. Several selected extraction methods were examined and Mehlich 3 extraction method using the mixture of NH4F, EDTA, NH4NO3, CH3COOH and HNO3 was selected as the best predictor of the leachability or mobility of As in the soil remediation process.

  13. In-situ remediation system for groundwater and soils

    DOEpatents

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1991-01-01

    The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  14. A Simple and Effective Remedial Learning System with a Fuzzy Expert System

    ERIC Educational Resources Information Center

    Lin, C.-C.; Guo, K.-H.; Lin, Y.-C.

    2016-01-01

    This study aims at implementing a simple and effective remedial learning system. Based on fuzzy inference, a remedial learning material selection system is proposed for a digital logic course. Two learning concepts of the course have been used in the proposed system: number systems and combinational logic. We conducted an experiment to validate…

  15. A Simple and Effective Remedial Learning System with a Fuzzy Expert System

    ERIC Educational Resources Information Center

    Lin, C.-C.; Guo, K.-H.; Lin, Y.-C.

    2016-01-01

    This study aims at implementing a simple and effective remedial learning system. Based on fuzzy inference, a remedial learning material selection system is proposed for a digital logic course. Two learning concepts of the course have been used in the proposed system: number systems and combinational logic. We conducted an experiment to validate…

  16. A novel sequential process for remediating rare-earth wastewater.

    PubMed

    Cui, Mingcan; Jang, Min; Kang, Kyounglim; Kim, Dukmin; Snyder, Shane A; Khim, Jeehyeong

    2016-02-01

    A novel and economic sequential process consisting of precipitation, adsorption, and oxidation was developed to remediate actual rare-earth (RE) wastewater containing various toxic pollutants, including radioactive species. In the precipitation step, porous air stones (PAS) containing waste oyster shell (WOS), PASWOS, was prepared and used to precipitate most heavy metals with >97% removal efficiencies. The SEM-EDS analysis revealed that PAS plays a key role in preventing the surface coating of precipitants on the surface of WOS and in releasing the dissolved species of WOS successively. For the adsorption step, a polyurethane (PU) impregnated by coal mine drainage sludge (CMDS), PUCMDS, was synthesized and applied to deplete fluoride (F), arsenic (As), uranium (U), and thorium (Th) that remained after precipitation. The continuous-mode sequential process using PAS(WOS), PU(CMDS), and ozone (O3) had 99.9-100% removal efficiencies of heavy metals, 99.3-99.9% of F and As, 95.8-99.4% of U and Th, and 92.4% of COD(Cr) for 100 days. The sequential process can treat RE wastewater economically and effectively without stirred-tank reactors, pH controller, continuous injection of chemicals, and significant sludge generation, as well as the quality of the outlet met the EPA recommended limits.

  17. SELPhOx process for remediation of contaminated soil

    SciTech Connect

    Ekhtera, M.R.; Mensinger, M.C.; Rehmat, A.; Deville, B.

    1996-10-01

    The SELPhOx process is being developed as a highly flexible means of remediating and destroying both high and low concentrations of light aliphatic to heavy aromatic contaminants from solid and soil matrices. The process employs two distinct technologies: extraction of organic contaminants with supercritical carbon dioxide and wet air oxidation (WAO) destruction of the extracted contaminants. A separation step links the two process stages. IGT has conducted supercritical extraction tests over wide ranges of temperature, pressure, and CO{sub 2}/contaminant ratios with soils from a wood treatment plant and two manufacturing gas plant sites. The addition of methanol as an extraction modifier was also explored. At comparable CO{sub 2}-to-contaminant ratios and extraction conditions of 48{degrees}C and 137 atm, the total PAHs removed from the three soils ranged from 76.9 to 97.9 percent with CO{sub 2} alone and from 88.4 to 98.6 percent with methanol added. Results of these tests are presented.

  18. Development of a biological treatment system for Hanford groundwater remediation

    SciTech Connect

    Brouns, T.M.; Koegler, S.S.; Heath, W.O.; Fredrickson, J.K. ); Stensel, H.D. ); Johnstone, D.L. ); Donaldson, T.L. )

    1990-04-01

    The primary objective of the biological treatment program is to develop and demonstrate a biological process for Hanford groundwater remediation that is capable of nitrate (NO {sub 3}{sup {minus}}) and organic contaminant destruction. Biodenitrification using facultative anaerobic microorganisms is a promising technology for the simultaneous removal of NO{sub 3}{sup {minus}} and organics from contaminated aqueous streams. During FY 1989, microbial consortium from the Hanford groundwater was shown to degrade both NO{sub 3}{sup {minus}} and carbon tetrachloride (CC1{sub 4}). A pilot-scale treatment system was subsequently designed and constructed based on the results of laboratory- and bench-scale testing. The pilot-scale system demonstrated continuous degradation of NO{sub 3}{sup {minus}} and CC1{sub 4} in a simulated groundwater. This report summarizes the results of biological groundwater treatment studies performed during FY 1989 at the pilot-, laboratory-, and bench-scales. Pilot-scale test were conducted using a simulate Hanford groundwater with a continuous stirred-tank bioreactor (CSTR) and a fluidized-bed bioreactor that was added to the pilot-scale treatment system in FY 1989. Laboratory test focused on the degradation of CC1{sub 4} and on the microbial toxicity from CC1{sub 4}, hexavalent chromium (Cr{plus} {sup 6}), and cyanide (CN){sup {minus}} 15 refs., 18 figs., 1 tab.

  19. DEMONSTRATION BULLETIN: PNEUMATIC FRACTURING EXTRACTION™ AND HOT GAS INJECTION, PHASE I - ACCUTECH REMEDIAL SYSTEMS, INC.

    EPA Science Inventory

    The Pneumatic Fracturing Extraction(PFE) process developed by Accutech Remedial Systems, Inc. makes it possible to use vapor extraction to remove volatile organics at increased rates from a broader range of vadose zones. The low permeability of silts, clays, shales, etc. would ot...

  20. DEMONSTRATION BULLETIN: PNEUMATIC FRACTURING EXTRACTION™ AND HOT GAS INJECTION, PHASE I - ACCUTECH REMEDIAL SYSTEMS, INC.

    EPA Science Inventory

    The Pneumatic Fracturing Extraction(PFE) process developed by Accutech Remedial Systems, Inc. makes it possible to use vapor extraction to remove volatile organics at increased rates from a broader range of vadose zones. The low permeability of silts, clays, shales, etc. would ot...

  1. Tank waste remediation system integrated technology plan. Revision 2

    SciTech Connect

    Eaton, B.; Ignatov, A.; Johnson, S.; Mann, M.; Morasch, L.; Ortiz, S.; Novak, P.

    1995-02-28

    The Hanford Site, located in southeastern Washington State, is operated by the US Department of Energy (DOE) and its contractors. Starting in 1943, Hanford supported fabrication of reactor fuel elements, operation of production reactors, processing of irradiated fuel to separate and extract plutonium and uranium, and preparation of plutonium metal. Processes used to recover plutonium and uranium from irradiated fuel and to recover radionuclides from tank waste, plus miscellaneous sources resulted in the legacy of approximately 227,000 m{sup 3} (60 million gallons) of high-level radioactive waste, currently in storage. This waste is currently stored in 177 large underground storage tanks, 28 of which have two steel walls and are called double-shell tanks (DSTs) an 149 of which are called single-shell tanks (SSTs). Much of the high-heat-emitting nuclides (strontium-90 and cesium-137) has been extracted from the tank waste, converted to solid, and placed in capsules, most of which are stored onsite in water-filled basins. DOE established the Tank Waste Remediation System (TWRS) program in 1991. The TWRS program mission is to store, treat, immobilize and dispose, or prepare for disposal, the Hanford tank waste in an environmentally sound, safe, and cost-effective manner. Technology will need to be developed or improved to meet the TWRS program mission. The Integrated Technology Plan (ITP) is the high-level consensus plan that documents all TWRS technology activities for the life of the program.

  2. Land Use in the CERCLA Remedy Selection Process

    EPA Pesticide Factsheets

    This directive presents additional information for considering land use in making remedy selection decisions under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) at National Priorities List (NPL) sites.

  3. Tank waste remediation system environmental program plan

    SciTech Connect

    Borneman, L.E.

    1998-01-09

    This Environmental Program Plan has been developed in support of the Integrated Environmental, Safety and Health Management System and consistent with the goals of DOE/RL-96-50, Hanford Strategic Plan (RL 1996a), and the specifications and guidance for ANSI/ISO 14001-1996, Environmental Management Systems Specification with guidance for use (ANSI/ISO 1996).

  4. Remediation System Evaluation, Raymark Superfund Site (PDF)

    EPA Pesticide Factsheets

    The Raymark site occupies 7 acres off Jacksonville Road in an industrial part of Hatboro, Pennsylvania.The pump-and-treat system addresses groundwater contamination, primarily trichloroethylene (TCE),associated with the operations of various ...

  5. Isotope Specific Remediation Media and Systems - 13614

    SciTech Connect

    Denton, Mark S.; Mertz, Joshua L.; Morita, Keisuke

    2013-07-01

    On March 11, 2011, now two years ago, the magnitude 9.0 Great East Japan earthquake, Tohoku, hit off the Fukushima coast of Japan. While, of course, most of the outcome of this unprecedented natural and manmade disaster was a negative, both in Japan and worldwide, there have been some extremely invaluable lessons learned and new emergency recovery technologies and systems developed. As always, the mother of invention is necessity. Among these developments has been the development and full-scale implementation of proven isotope specific media (ISMs) with the intent of surgically removing specific hazardous isotopes for the purpose of minimizing dose to workers and the environment. The first such ISMs to be deployed at the Fukushima site were those removing cesium (Cs-137) and iodine (I-129). Since deployment on June 17, 2011, along with treated cooling water recycle, some 70% of the curies in the building liquid wastes have been removed by the Kurion system alone. The current levels of cesium are now only 2% of the original levels. Such an unprecedented, 'external cooling system' not only allowed the eventual cold shut down of the reactors in mid-December, 2011, but has allowed workers to concentrate on the cleanup of other areas of the site. Water treatment will continue for quite some time due to continued leakage into the buildings and the eventual goal of cleaning up the reactors and fuel pools themselves. With the cesium removal now in routine operation, other isotopes of concern are likely to become priorities. One such isotope is that of strontium, and yttrium (Sr-90 and Y-90), which is still at original levels causing further dose issues as well as impediments to discharge of the treated waste waters. For over a year now, a new synthetic strontium specific media has been under development and testing both in our licensed facility in Oak Ridge, Tennessee, but also in confirmatory tests by the Japan Atomic Energy Agency (JAEA) in Japan for Tokyo Electric Power

  6. Tandem microwave waste remediation and decontamination system

    DOEpatents

    Wicks, George G.; Clark, David E.; Schulz, Rebecca L.

    1999-01-01

    The invention discloses a tandem microwave system consisting of a primary chamber in which microwave energy is used for the controlled combustion of materials. A second chamber is used to further treat the off-gases from the primary chamber by passage through a susceptor matrix subjected to additional microwave energy. The direct microwave radiation and elevated temperatures provide for significant reductions in the qualitative and quantitative emissions of the treated off gases. The tandem microwave system can be utilized for disinfecting wastes, sterilizing materials, and/or modifying the form of wastes to solidify organic or inorganic materials. The simple design allows on-site treatment of waste by small volume waste generators.

  7. The Development and Evaluation of Listening and Speaking Diagnosis and Remedial Teaching System

    ERIC Educational Resources Information Center

    Hsiao, Hsien-Sheng; Chang, Cheng-Sian; Lin, Chiou-Yan; Chen, Berlin; Wu, Chia-Hou; Lin, Chien-Yu

    2016-01-01

    In this study, a system was developed to offer adaptive remedial instruction materials to learners of Chinese as a foreign language (CFL). The Chinese Listening and Speaking Diagnosis and Remedial Instruction (CLSDRI) system integrated computerized diagnostic tests and remedial instruction materials to diagnose errors made in listening…

  8. The Development and Evaluation of Listening and Speaking Diagnosis and Remedial Teaching System

    ERIC Educational Resources Information Center

    Hsiao, Hsien-Sheng; Chang, Cheng-Sian; Lin, Chiou-Yan; Chen, Berlin; Wu, Chia-Hou; Lin, Chien-Yu

    2016-01-01

    In this study, a system was developed to offer adaptive remedial instruction materials to learners of Chinese as a foreign language (CFL). The Chinese Listening and Speaking Diagnosis and Remedial Instruction (CLSDRI) system integrated computerized diagnostic tests and remedial instruction materials to diagnose errors made in listening…

  9. ISS Internal Active Thermal Control System (IATCS) Coolant Remediation Project

    NASA Technical Reports Server (NTRS)

    Morrison, Russell H.; Holt, Mike

    2005-01-01

    The IATCS coolant has experienced a number of anomalies in the time since the US Lab was first activated on Flight 5A in February 2001. These have included: 1) a decrease in coolant pH, 2) increases in inorganic carbon, 3) a reduction in phosphate buffer concentration, 4) an increase in dissolved nickel and precipitation of nickel salts, and 5) increases in microbial concentration. These anomalies represent some risk to the system, have been implicated in some hardware failures and are suspect in others. The ISS program has conducted extensive investigations of the causes and effects of these anomalies and has developed a comprehensive program to remediate the coolant chemistry of the on-orbit system as well as provide a robust and compatible coolant solution for the hardware yet to be delivered. The remediation steps include changes in the coolant chemistry specification, development of a suite of new antimicrobial additives, and development of devices for the removal of nickel and phosphate ions from the coolant. This paper presents an overview of the anomalies, their known and suspected system effects, their causes, and the actions being taken to remediate the coolant.

  10. Green PCB Remediation from Sediment Systems (GPRSS) Project

    NASA Technical Reports Server (NTRS)

    Falker, John; Thompson, Karen; Zeitlin, Nancy; Quinn, Jacqueline; Parrish, Lewis M.

    2014-01-01

    An ongoing problem facing the global environment community including NASA centers is the removal and remediation of polychlorinated biphenyls (PCBs). PCBs were commonly used in a variety of materials including paints, caulking, and adhesives due to the advantageous physical and chemical properties that PCBs imparted to these various materials. Unfortunately, these properties have made the treatment of sites contaminated with these chemicals extremely difficult to deal with, due to their inherent chemical stability. The remediation of sediments contaminated with PCBs is especially difficult, primarily due to the risk of releasing the contaminant into the environment during the treatment process. Traditional treatment options involve the use of dredging and incineration of the contaminated soils/sediments, in which the chance of releasing the contaminants is greatly increased. The purpose of this project is to develop cleanup technology capable of remediating contaminated sediments in-situ, with minimum intrusion. This allows for the minimization of any potential contaminant release during the treatment process, providing a safer method for cleanup operations (as opposed to dredging/incineration) and still treating the basic problem of PCB contamination (as opposed to capping).

  11. Tank waste remediation system program plan

    SciTech Connect

    Powell, R.W.

    1998-01-09

    This TWRS Program plan presents the planning requirements and schedules and management strategies and policies for accomplishing the TWRS Project mission. It defines the systems and practices used to establish consistency for business practices, engineering, physical configuration and facility documentation, and to maintain this consistency throughout the program life cycle, particularly as changes are made. Specifically, this plan defines the following: Mission needs and requirements (what must be done and when must it be done); Technical objectives/approach (how well must it be done); Organizational structure and philosophy (roles, responsibilities, and interfaces); and Operational methods (objectives and how work is to be conducted in both management and technical areas). The plan focuses on the TWRS Retrieval and Disposal Mission and supports the DOE mid-1998 Readiness to Proceed with Privatized Waste Treatment evaluation for establishing contracts with private contractors for the treatment (immobilization) of Hanford tank high-level radioactive waste.

  12. A comparison of the RCRA Corrective Action and CERCLA Remedial Action Processes

    SciTech Connect

    Traceski, Thomas T.

    1994-02-01

    This document provides a comprehensive side-by-side comparison of the RCRA corrective action and the CERCLA remedial action processes. On the even-numbered pages a discussion of the RCRA corrective action process is presented and on the odd-numbered pages a comparative discussion of the CERCLA remedial action process can be found. Because the two programs have a difference structure, there is not always a direct correlation between the two throughout the document. This document serves as an informative reference for Departmental and contractor personnel responsible for oversight or implementation of RCRA corrective action and CERCLA remedial action activities at DOE environmental restoration sites.

  13. A complete remediation process for a uranium-contaminated site and application to other sites

    SciTech Connect

    Mason, C.F.V.; Lu, N.; Kitten, H.D.; Williams, M.; Turney, W.R.J.R.

    1998-12-31

    During the summer of 1996 the authors were able to test, at the pilot scale, the concept of leaching uranium (U) from contaminated soils. The results of this pilot scale operation showed that the system they previously had developed at the laboratory scale is applicable at the pilot scale. The paper discusses these results, together with laboratory scale results using soil from the Fernald Environmental Management Project (FEMP), Ohio. These FEMP results show how, with suitable adaptations, the process is widely applicable to other sites. The purpose of this paper is to describe results that demonstrate remediation of uranium-contaminated soils may be accomplished through a leach scheme using sodium bicarbonate.

  14. MEMBRANE SYSTEM FOR RECOVERY OF VOLATILE ORGANIC COMPOUNDS FROM REMEDIATION OFF-GASES

    SciTech Connect

    J.G. Wijmans

    2003-11-17

    In situ vacuum extraction, air or steam sparging, and vitrification are widely used to remediate soil contaminated with volatile organic compounds (VOCs). All of these processes produce a VOC-laden air stream from which the VOC must be removed before the air can be discharged or recycled to the generating process. Treatment of these off-gases is often a major portion of the cost of the remediation project. Currently, carbon adsorption and catalytic incineration are the most common methods of treating these gas streams. Membrane Technology and Research, Inc. (MTR) proposed an alternative treatment technology based on selective membranes that separate the organic components from the gas stream, producing a VOC-free air stream. This technology can be applied to off-gases produced by various remediation activities and the systems can be skid-mounted and automated for easy transportation and unattended operation. The target performance for the membrane systems is to produce clean air (less than 10 ppmv VOC) for discharge or recycle, dischargeable water (less than 1 ppmw VOC), and a concentrated liquid VOC phase. This report contains the results obtained during Phase II of a two-phase project. In Phase I, laboratory experiments were carried out to demonstrate the feasibility of the proposed approach. In the subsequent Phase II project, a demonstration system was built and operated at the McClellan Air Force Base near Sacramento, California. The membrane system was fed with off-gas from a Soil Vacuum Extraction (SVE) system. The work performed in Phase II demonstrated that the membrane system can reduce the VOC concentration in remediation off-gas to 10 ppmv, while producing a concentrated VOC phase and dischargeable water containing less than 1 ppmw VOC. However, the tests showed that the presence of 1 to 3% carbon dioxide in the SVE off-gas reduced the treatment capacity of the system by a factor of three to four. In an economic analysis, treatment costs of the membrane

  15. Evaluation of Processes for Remediating Explosives-Contaminated Debris

    DTIC Science & Technology

    1994-05-05

    treatment process concept ....................... 7 Figure 3-2. Hammermill crushing process concept ............................... 12 Figure 3-3. Soil...Toothed-roll crushers for coarse crushing "e Jaw crushers for initial crushing of hard or large materials "C Hammermills to produce controlled particle size...size reduction required. However, two crushers in series would increase both the capital cost and the system complexity. Hammermills are capable of

  16. Remediation process monitoring of PAH-contaminated soils using laser-induced fluorescence.

    PubMed

    Ko, Eun-Joung; Kim, Kyoung-Woong; Wachsmuth, U

    2004-03-01

    In order to investigate the feasibility of Laser-Induced Fluorescence (LIF) for soil remediation process monitoring, the variation in the LIF intensity was studied, in relation to the moisture content and soil particle size distribution for different soil conditions. For each set of conditions, significant correlation was shown between the level of Polycyclic Aromatic Hydrocarbon (PAH) and the LIF intensity (R2 > 0.97). Higher fluorescence intensities were measured for PAH contaminated soils with higher sand and moisture contents. The results of the LIF monitoring for the remediation process were compared with the traditional High Pressure Liquid Chromatography (HPLC) results, after applying a surfactant-enhanced electrokinetic process for the remediation of PAH-contaminated soils. In the electrokinetic (EK) process cell. the PAH concentration, and the normalized LIF intensity near the anode and cathode, showed somewhat contrary trends with respect to the degree of the remediation, even though significantly similar trends were observed in the middle of the soil cell. This may be interpreted as the EK remediation advances, as the electro osmotic flow induce a different moisture and silt/clay, or sand, distribution throughout the soil media, which in turn influences the LIF intensity of the soils. Therefore, in order to overcome these differences, the corrected LIF intensity, using the diffuse reflectance, was applied, which showed a similar remediation trend for the soil specimens in the electrokinetic process cell.

  17. Air-Based Remediation Workshop - Section 6 Thermal Systems

    EPA Science Inventory

    Pursuant to the EPA-AIT Implementing Arrangement 7 for Technical Environmental Collaboration, Activity 11 "Remediation of Contaminated Sites," the USEPA Office of International Affairs Organized a Forced Air Remediation Workshop in Taipei to deliver expert training to the Environ...

  18. Air-Based Remediation Workshop - Section 6 Thermal Systems

    EPA Science Inventory

    Pursuant to the EPA-AIT Implementing Arrangement 7 for Technical Environmental Collaboration, Activity 11 "Remediation of Contaminated Sites," the USEPA Office of International Affairs Organized a Forced Air Remediation Workshop in Taipei to deliver expert training to the Environ...

  19. Real-Time Remediation Utilizing The Backpack Sodium Iodide System And The U.S. EPA Triad Approach

    SciTech Connect

    John R. Giles; Michael V. Carpenter; Lyle G. Roybal; C. P. Oertel; J. J. Jacobson; D. L. Eaton; G. L. Schwendiman

    2006-03-01

    Real-time characterization during remediation activities is being accomplished at the Idaho National Laboratory (INL) with the use of the backpack sodium iodide system (BaSIS). The BaSIS is comprised of a 3-in. by 5-in. sodium iodide (NaI) detector, differential corrected global positioning system (GPS), and portable computer, integrated into a lightweight backpack deployment platform. The system is operated with specialized software that allows the operator and/or remediation field manager to view data as they are collected. Upon completion of planned excavation stages, the area is surveyed for residual radiological contamination. After data collection is complete, data is available to the remediation field manager as a contour map showing the area(s) that require further excavation. The use of real-time measurement systems, rapid turn-around time of data, and dynamic work strategy support the U.S. Environmental Protection Agency’s (EPA) Triad approach. Decisions are made in real-time as to the need for further remediation. This paper describes the BaSIS system calibration, testing and use, and outlines negotiations with the appropriate CERCLA regulatory agencies (U.S. Environmental Protection Agency, Idaho Department of Environmental Quality, and U.S. Department of Energy Idaho Operations Office) to allow the use of real-time instrumentation during the remediation process, and for confirmation surveys. By using the BaSIS in such a manner, the INL seeks to demonstrate compliance with remediation objectives.

  20. Environmental assessment of remedial action at the Naturita Uranium processing site near Naturita, Colorado. Revision 2

    SciTech Connect

    Not Available

    1994-01-01

    The proposed remedial action for the Naturita processing site is relocation of the contaminated materials and debris to the Dry Flats disposal sits, 6 road miles (mi) [10 kilometers (km)) to the southeast. At the disposal site, the contaminated materials would be stabilized and covered with layers of earth and rock. The proposed disposal site is on land administered by the Bureau of Land Management (BLM) and used primarily for livestock grazing. The final disposal sits would cover approximately 57 ac (23 ha), which would be permanently transferred from the BLM to the DOE and restricted from future uses. The remedial action activities would be conducted by the DOE`s Uranium Mill Tailings Remedial Action (UMTRA) Project. The proposed remedial action would result in the loss of approximately 162 ac (66 ha) of soils at the processing and disposal sites; however, 133 ac (55 ha) of these soils at and adjacent to the processing site are contaminated and cannot be used for other purposes. If supplemental standards are approved by the NRC and state of Colorado, approximately 112 ac (45 ha) of contaminated soils adjacent to the processing site would not be cleaned up. This area is steeply sloped. The cleanup of this contamination would have adverse environmental consequences and would be potentially hazardous to remedial action workers. Another 220 ac (89 ha) of soils would be temporarily disturbed during the remedial action. The final disposal site would result in approximately 57 ac (23 ha) being removed from livestock grazing and wildlife use.

  1. Environmental assessment of remedial action at the Naturita uranium processing site near Naturita, Colorado. Revision 3

    SciTech Connect

    Not Available

    1994-02-01

    The proposed remedial action for the Naturita processing site is relocation of the contaminated materials and debris to the Dry Flats disposal site, 6 road miles (mi) [10 kilometers (km)] to the southeast. At the disposal site, the contaminated materials would be stabilized and covered with layers of earth and rock. The proposed disposal site is on land administered by the Bureau of Land Management (BLM) and used primarily for livestock grazing. The final disposal site would cover approximately 57 ac (23 ha), which would be permanently transferred from the BLM to the DOE and restricted from future uses. The remedial action activities would be conducted by the DOE`s Uranium Mill Tailings Remedial Action (UMTRA) Project. The proposed remedial action would result in the loss of approximately 162 ac (66 ha) of soils at the processing and disposal sites; however, 133 ac (55 ha) of these soils at and adjacent to the processing site are contaminated and cannot be used for other purposes. If supplemental standards are approved by the NRC and state of Colorado, approximately 112 ac (45 ha) of contaminated soils adjacent to the processing site would not be cleaned up. This area is steeply sloped. The cleanup of this contamination would have adverse environmental consequences and would be potentially hazardous to remedial action workers. Another 220 ac (89 ha) of soils would be temporarily disturbed during the remedial action. The final disposal site would result in approximately 57 ac (23 ha) being removed from livestock grazing and wildlife use.

  2. Role of cost in the superfund remedy selection process

    SciTech Connect

    1996-09-01

    The fact sheet describes the role of cost in the selection of remedial actions under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA, commonly referred to as Superfund). The objective of this fact sheet is to clarify the current role of cost as established in existing law, regulation, and policy. This fact sheet describes the current role of cost as established by the Superfund statute (CERCLA) and the Superfund regulations (the National Oil and Hazardous Substances Contingency Plan (NCP)), and as expanded upon in EPA guidance.

  3. Comparison of bioleaching and electrokinetic remediation processes for removal of heavy metals from wastewater treatment sludge.

    PubMed

    Xu, Ying; Zhang, Chaosheng; Zhao, Meihua; Rong, Hongwei; Zhang, Kefang; Chen, Qiuli

    2017-02-01

    Heavy metals prevent the growing amount of sewage sludge from being disposed as fertilizeron land. The electrokinetic remediation and bioleaching technology are the promising methods to remove heavy metals. In recent years, some innovation has been made to achieve better efficiency, including the innovation of processes and agents. This paper reviews the development of the electrokinetic remediation and bioleaching technology and analyses their advantages and limitation, pointing out the need of the future research for the heavy metals-contaminated sewage sludge.

  4. Using visual processing training to enhance standard cognitive remediation outcomes in schizophrenia: A pilot study.

    PubMed

    Contreras, Natalia A; Tan, Eric J; Lee, Stuart J; Castle, David J; Rossell, Susan L

    2017-09-14

    Approaches to cognitive remediation (CR) that address sensory perceptual skills before higher cognitive skills, have been found to be effective in enhancing cognitive performance in schizophrenia. To date, however, most of the conducted trials have concentrated on auditory processing. The aim of this study was to explore whether the addition of visual processing training could enhance standard cognitive remediation outcomes in a schizophrenia population. Twenty participants were randomised to either receive 20h of computer-assisted cognitive remediation alone or 20h of visual processing training modules and cognitive remediation training. All participants were assessed at baseline and at the end of cognitive remediation training on cognitive and psychosocial (i.e. self-esteem, quality of life) measures. At the end of the study participants across both groups improved significantly in overall cognition and psychosocial functioning. No significant differences were observed between groups on any of the measures. Of potential interest, however, was that the Cohen's d assessing the between group difference in the rates of change were moderate/large for a greater improvement in Visual Learning, Working Memory and Social Cognition for the visual training plus cognitive remediation group. On the basis of our effect sizes on three domains of cognition, we recommend replicating this intervention with a larger sample. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Tank waste remediation system milestone report magnetic separation of tank waste: Surrogate system separations report

    SciTech Connect

    Avens, L.R.; Worl, L.A.; Schake, A.R.; Padilla, D.D.; de Aguero, K.J.; Prenger, F.C.; Stewart, W.F.; Hill, D.D.

    1994-01-14

    High-level radioactive waste (HLW) has been stored in large underground storage tanks (UST) at the US Department of Energy`s Hanford Site since 1944. More than 253,000 m{sup 3} of waste have been accumulated in 177 tanks. The waste consists of many different chemicals and are in the form of liquids, slurries, salt cakes and sludges. A magnetic separation effort at Los Alamos National Laboratory is funded through the Tank Waste Remediation System (TWRS) to explore the use of high-gradient magnetic separation (HGMS) for tank waste segregation. The concept is to concentrate into a low volume waste stream, all or most of the magnetic components, which include actinide compounds, most of the fission products and precious metals. As a first step in this process investigations were made on surrogate systems. This milestone report discusses the HGMS results on these systems.

  6. Development of an ultrasonic process for soil remediation

    SciTech Connect

    Wu, J.M.; Huang, H.S.; Livengood, C.D.

    1995-06-01

    An ultrasonic process for the detoxification of carbon tetrachloride- (CCl{sub 4}{sup {minus}}) contaminated soil was investigated in the laboratory by using a batch irradiation reactor equipped with a 600-W ultrasonic power supply operated at a frequency of 20 kHz. Key parameters studied included soil characteristics, irradiation time, CCl{sub 4} concentration, steady-state operating temperature, applied ultrasonic-wave energy, and the ratio of soil to water in the system. The results of the experiments showed that (1) residual CCl{sub 4} concentrations could be decreased with longer irradiation periods and (2) detoxification efficiency was proportional to steady-state operating temperature and applied ultrasonic-wave energy. The characteristics of the contaminated soil were found to be an important factor in the design of an ultrasonic detoxification system. A soil-phase CCl{sub 4} concentration below 1 ppm (initial concentration of 56 ppm) was achieved through this process, indicating that the application of ultrasonic irradiation is feasible and effective in the detoxification of soil contaminated by organic compounds. On the basis of the experimental results, a schematic of a full-scale ultrasonic soil-detoxification system was developed. Improvements to this novel process are discussed.

  7. Recovery of Rare Earth Elements and Yttrium from Passive-Remediation Systems of Acid Mine Drainage.

    PubMed

    Ayora, Carlos; Macías, Francisco; Torres, Ester; Lozano, Alba; Carrero, Sergio; Nieto, José-Miguel; Pérez-López, Rafael; Fernández-Martínez, Alejandro; Castillo-Michel, Hiram

    2016-08-02

    Rare earth elements and yttrium (REY) are raw materials of increasing importance for modern technologies, and finding new sources has become a pressing need. Acid mine drainage (AMD) is commonly considered an environmental pollution issue. However, REY concentrations in AMD can be several orders of magnitude higher than in naturally occurring water bodies. With respect to shale standards, the REY distribution pattern in AMD is enriched in intermediate and valuable REY, such as Tb and Dy. The objective of the present work is to study the behavior of REY in AMD passive-remediation systems. Traditional AMD passive remediation systems are based on the reaction of AMD with calcite-based permeable substrates followed by decantation ponds. Experiments with two columns simulating AMD treatment demonstrate that schwertmannite does not accumulate REY, which, instead, are retained in the basaluminite residue. The same observation is made in two field-scale treatments from the Iberian Pyrite Belt (IPB, southwest Spain). On the basis of the amplitude of this process and on the extent of the IPB, our findings suggest that the proposed AMD remediation process can represent a modest but suitable REY source. In this sense, the IPB could function as a giant heap-leaching process of regional scale in which rain and oxygen act as natural driving forces with no energy investment. In addition to having environmental benefits of its treatment, AMD is expected to last for hundreds of years, and therefore, the total reserves are practically unlimited.

  8. Environmental assessment of remedial action at the Naturita Uranium Processing Site near Naturita, Colorado. Revision 4

    SciTech Connect

    Not Available

    1994-05-01

    The Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978, Public Law (PL) 95-604, authorized the US Department of Energy (DOE) to perform remedial action at the Naturita, Colorado, uranium processing site to reduce the potential health effects from the radioactive materials at the site and at vicinity properties associated with the site. The US Environmental Protection Agency (EPA) promulgated standards for the UMTRCA that contain measures to control the contaminated materials and to protect groundwater quality. Remedial action at the Naturita site must be performed in accordance with these standards and with the concurrence of the US Nuclear Regulatory Commission (NRC) and the state of Colorado. The proposed remedial action for the Naturita processing site is relocation of the contaminated materials and debris to either the Dry Flats disposal site, 6 road miles (mi) [10 kilometers (km)] to the southeast, or a licensed non-DOE disposal facility capable of handling RRM. At either disposal site, the contaminated materials would be stabilized and covered with layers of earth and rock. The proposed Dry Flats disposal site is on land administered by the Bureau of Land Management (BLM) and used primarily for livestock grazing. The final disposal site would cover approximately 57 ac (23 ha), which would be permanently transferred from the BLM to the DOE and restricted from future uses. The remedial action would be conducted by the DOE`s Uranium Mill Tailings Remedial Action (UMTRA) Project. This report discusses environmental impacts associated with the proposed remedial action.

  9. Process-Based Remediation of Decoding in Gifted LD Students: Three Case Studies.

    ERIC Educational Resources Information Center

    Crawford, Shawn; Snart, Fern

    1994-01-01

    Three gifted males (ages 10-13) with deficits in successive coding participated in a process-based remedial program which combined global training on tasks requiring successive processing and tasks applying successive processing to decoding in reading, and which utilized verbal mediation. Differences in student improvement were related to entry…

  10. System description for DART (Decision Analysis for Remediation Technologies)

    SciTech Connect

    Nonte, J.; Bolander, T.; Nickelson, D.; Nielson, R.; Richardson, J.; Sebo, D.

    1997-09-01

    DART is a computer aided system populated with influence models to determine quantitative benefits derived by matching requirements and technologies. The DART database is populated with data from over 900 DOE sites from 10 Field Offices. These sites are either source terms, such as buried waste pits, or soil or groundwater contaminated plumes. The data, traceable to published documents, consists of site-specific data (contaminants, area, volume, depth, size, remedial action dates, site preferred remedial option), problems (e.g., offsite contaminant plume), and Site Technology Coordinating Group (STCG) need statements (also contained in the Ten-Year Plan). DART uses this data to calculate and derive site priorities, risk rankings, and site specific technology requirements. DART is also populated with over 900 industry and DOE SCFA technologies. Technology capabilities can be used to match technologies to waste sites based on the technology`s capability to meet site requirements and constraints. Queries may be used to access, sort, roll-up, and rank site data. Data roll-ups may be graphically displayed.

  11. Biogeochemical dynamics of pollutants in Insitu groundwater remediation systems

    NASA Astrophysics Data System (ADS)

    Kumar, N.; Millot, R.; Rose, J.; Négrel, P.; Battaglia-Brunnet, F.; Diels, L.

    2010-12-01

    Insitu (bio) remediation of groundwater contaminants has been area of potential research interest in last few decades as the nature of contaminant encountered has also changed drastically. This gives tough challenge to researchers in finding a common solution for all contaminants together in one plume. Redox processes play significant role in pollutant dynamics and mobility in such systems. Arsenic particularly in reduced environments can get transformed into its reduced form (As3+), which is apparently more mobile and highly toxic. Also parallel sulfate reduction can lead to sulfide production and formation of thioarsenic species. On the other hand heavy metals (Zn, Fe, and Cd) in similar conditions will favour more stable metal sulfide precipitation. In the present work, we tested Zero Valent Iron (ZVI) in handling such issues and found promising results. Although it has been well known for contaminants like arsenic and chlorinated compounds but not much explored for heavy metals. Its high available surface area supports precipitation and co -precipitation of contaminants and its highly oxidizing nature and water born hydrogen production helps in stimulation of microbial activities in sediment and groundwater. These sulfate and Iron reducing bacteria can further fix heavy metals as stable metal sulfides by using hydrogen as potential electron donor. In the present study flow through columns (biotic and control) were set up in laboratory to understand the behaviour of contaminants in subsurface environments, also the impact of microbiology on performance of ZVI was studied. These glass columns (30 x 4cm) with intermediate sampling points were monitored over constant temperature (20°C) and continuous groundwater (up)flow at ~1ml/hr throughout the experiment. Simulated groundwater was prepared in laboratory containing sulfate, metals (Zn,Cd) and arsenic (AsV). While chemical and microbial parameters were followed regularly over time, solid phase has been

  12. Tank waste remediation system functions and requirements document

    SciTech Connect

    Carpenter, K.E

    1996-10-03

    This is the Tank Waste Remediation System (TWRS) Functions and Requirements Document derived from the TWRS Technical Baseline. The document consists of several text sections that provide the purpose, scope, background information, and an explanation of how this document assists the application of Systems Engineering to the TWRS. The primary functions identified in the TWRS Functions and Requirements Document are identified in Figure 4.1 (Section 4.0) Currently, this document is part of the overall effort to develop the TWRS Functional Requirements Baseline, and contains the functions and requirements needed to properly define the top three TWRS function levels. TWRS Technical Baseline information (RDD-100 database) included in the appendices of the attached document contain the TWRS functions, requirements, and architecture necessary to define the TWRS Functional Requirements Baseline. Document organization and user directions are provided in the introductory text. This document will continue to be modified during the TWRS life-cycle.

  13. UXO detection, characterization, and remediation using intelligent robotic systems

    NASA Astrophysics Data System (ADS)

    Amer, Saed; Shirkhodaie, Amir; Rababaah, Haroun

    2008-04-01

    An intelligent robotic system can be distinguished from other machines by its ability to sense, learn, and react to its environment despite various task uncertainties. One of the most powerful sensing modality for robotic system is vision as it enables the robot to see its environment, recognize objects around it and interact with objects to accomplish its task. This paper discusses vision enabling techniques that allows a robot to detect, characterize, classify, and discriminate UneXploded Ordnance (UXO) from clutters in unstructured environments. A soft-computing approach is proposed and validated via indoor and outdoor experiments to measure its performance efficiency and effectiveness in correctly detection and classifying UXO vs. XO and other clutter. The proposed technique has many potential applications for military, homeland security, law enforcement, and in particular, environment UXO remediation and clean-up operations.

  14. Decision and systems analysis for underground storage tank waste retrieval systems and tank waste remediation system

    SciTech Connect

    Bitz, D.A.; Berry, D.L.; Jardine, L.J.

    1994-03-01

    Hanford`s underground tanks (USTs) pose one of the most challenging hazardous and radioactive waste problems for the Department of Energy (DOE). Numerous schemes have been proposed for removing the waste from the USTs, but the technology options for doing this are largely unproven. To help assess the options, an Independent Review Group (IRG) was established to conduct a broad review of retrieval systems and the tank waste remediation system. The IRG consisted of the authors of this report.

  15. Duct Remediation Program: Remediation operations and implementation

    SciTech Connect

    Beckman, T.d.; Davis, M.M.; Karas, T.M.

    1992-11-01

    Plutonium holdup material has accumulated in the process ventilation duct systems at Rocky Flats. Non-Destructive Assay (NDA) measurements identified ducts containing this material. The Defense Nuclear Facility Safety Board and the Department of Energy established the criteria for remediation of these ducts. A remediation team was assembled and a program plan created. This program plan included activities such as fissile material accumulation identification, criticality safety assessments, radiation dose determinations, facility safety evaluations, prevention of future accumulation, and removal of holdup material. Several operational considerations had to be evaluated in determining completion of remediation.

  16. Research and development support of the Hanford site tank waste remediation system

    SciTech Connect

    Johnson, B.M.; Wodrich, D.D.

    1992-08-01

    The research and development of new technology in support of the tank waste remediation system (TWRS) program at Hanford is largely driven by the unique situation with the Hanford radioactive tank wastes. The operational history at Hanford has involved three different major processes and several major campaigns to recover fission products from the wastes, and has not maintained a segregation of the high-level wastes. The result is a very diverse inventory with very high content of solids of many different chemical constituents and great complexity. The R & D program must not only assure that an acceptable strategy for remediation of these wastes can be put in place, it must also define ways of improving the cost effectiveness of the strategy to make the mammoth task more tractable.

  17. A systematic look at Tank Waste Remediation System privatization

    SciTech Connect

    Holbrook, J.H.; Duffy, M.A.; Vieth, D.L.; Sohn, C.L.

    1996-01-01

    The mission of the Tank Waste Remediation System (TWRS) Program is to store, treat, immobilize, and dispose, or prepare for disposal, the Hanford radioactive tank waste in an environmentally sound, safe, and cost effective manner. Highly radioactive Hanford waste includes current and future tank waste plus the cesium and strontium capsules. In the TWRS program, as in other Department of Energy (DOE) clean-up activities, there is an increasing gap between the estimated funding required to enable DOE to meet all of its clean-up commitments and level of funding that is perceived to be available. Privatization is one contracting/management approach being explored by DOE as a means to achieve cost reductions and as a means to achieve a more outcome-oriented program. Privatization introduces the element of competition, a proven means of establishing true cost as well as achieving significant cost reduction.

  18. 49 CFR 510.12 - Remedies for failure to comply with compulsory process.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... process. 510.12 Section 510.12 Transportation Other Regulations Relating to Transportation (Continued) NATIONAL HIGHWAY TRAFFIC SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION INFORMATION GATHERING POWERS § 510.12 Remedies for failure to comply with compulsory process. Any failure to comply with compulsory...

  19. 76 FR 30696 - Reimbursement for Costs of Remedial Action at Active Uranium and Thorium Processing Sites

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-26

    .... Funds for reimbursement will be provided from the Uranium Enrichment Decontamination and Decommissioning... Reimbursement for Costs of Remedial Action at Active Uranium and Thorium Processing Sites AGENCY: Department of... eligible active uranium and thorium processing site licensees for reimbursement under Title X of the Energy...

  20. Environmental implications of soil remediation using the Fenton process.

    PubMed

    Villa, Ricardo D; Trovó, Alam G; Nogueira, Raquel F Pupo

    2008-03-01

    This work evaluates some collateral effects caused by the application of the Fenton process to 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethane (DDT) and diesel degradation in soil. While about 80% of the diesel and 75% of the DDT present in the soil were degraded in a slurry system, the dissolved organic carbon (DOC) in the slurry filtrate increased from 80 to 880mgl(-1) after 64h of reaction and the DDT concentration increased from 12 to 50microgl(-1). Experiments of diesel degradation conducted on silica evidenced that soluble compounds were also formed during diesel oxidation. Furthermore, significant increase in metal concentrations was also observed in the slurry filtrate after the Fenton treatment when compared to the control experiment leading to excessive concentrations of Cr, Ni, Cu and Mn according to the limits imposed for water. Moreover, 80% of the organic matter naturally present in the soil was degraded and a drastic volatilization of DDT and 2,2-bis(4-chlorophenyl)-1,1-dichloroethylene was observed. Despite the high percentages of diesel and DDT degradation in soil, the potential overall benefits of its application must be evaluated beforehand taking into account the metal and target compounds dissolution and the volatilization of contaminants when the process is applied.

  1. Feasibility Process for Remediation of the Crude Oil Contaminated Soil

    NASA Astrophysics Data System (ADS)

    Keum, H.; Choi, H.; Heo, H.; Lee, S.; Kang, G.

    2015-12-01

    More than 600 oil wells were destroyed in Kuwait by Iraqi in 1991. During the war, over 300 oil lakes with depth of up to 2m at more than 500 different locations which has been over 49km2. Therefore, approximately 22 million m3was crude oil contaminated. As exposure of more than 20 years under atmospheric conditions of Kuwait, the crude oil has volatile hydrocarbons and covered heavy oily sludge under the crude oil lake. One of crude oil contaminated soil which located Burgan Oilfield area was collected by Kuwait Oil Company and got by H-plus Company. This contaminated soil has about 42% crude oil and could not biodegraded itself due to the extremely high toxicity. This contaminated soil was separated by 2mm sieve for removal oil sludge ball. Total petroleum hydrocarbons (TPH) was analysis by GC FID and initial TPH concentration was average 48,783 mg/kg. Ten grams of the contaminated soil replaced in two micro reactors with 20mL of bio surfactant produce microorganism. Reactor 1 was added 0.1g powder hemoglobin and other reactor was not added hemoglobin at time 0 day. Those reactors shake 120 rpm on the shaker for 7 days and CO2 produced about 150mg/L per day. After 7 days under the slurry systems, the rest days operated by hemoglobin as primary carbon source for enhanced biodegradation. The crude oil contaminated soil was degraded from 48,783mg/kg to 20,234mg/kg by slurry process and final TPH concentration degraded 11,324mg/kg for 21days. Therefore, highly contaminated soil by crude oil will be combined bio slurry process and biodegradation process with hemoglobin as bio catalytic source. Keywords: crude-oil contaminated soil, bio slurry, biodegradation, hemoglobin ACKOWLEDGEMENTS This project was supported by the Korea Ministry of Environment (MOE) GAIA Program

  2. Tank waste remediation system retrieval and disposal mission initial updated baseline summary

    SciTech Connect

    Swita, W.R.

    1998-01-05

    This document provides a summary of the proposed Tank Waste Remediation System Retrieval and Disposal Mission Initial Updated Baseline (scope, schedule, and cost) developed to demonstrate the Tank Waste Remediation System contractor`s Readiness-to-Proceed in support of the Phase 1B mission.

  3. The Rush to Remediate: Long Term Performance Favors Passive Systems at SRS

    SciTech Connect

    Hoffman, D.; Cauthen, K.; Beul. R. R.

    2003-02-24

    The purpose of this paper is to describe the long-term performance of groundwater remediation systems at SRS and compare active versus passive systems. The presentation will focus on the limited effectiveness of active pump and treat systems and share the experience with more passive and natural systems such as soil vapor extraction, barometric pumping, bioremediation, and phytoremediation. Three remediation projects are presented. In each case the waste source is capped with clay or synthetic barriers; however, extensive groundwater contamination remains. The first project features the cleanup of the largest plume in the United States. The second project entails solvent and vinyl chloride remediation of groundwater beneath a hazardous waste landfill. The third project discusses tritium containment from a 160-acre radioactive waste disposal area. Special emphasis is placed on performance data from alternate technology cleanup. The goals are to share remediation data, successes and lessons learned, while making a case for passive systems use in groundwater remediation.

  4. Remediation of contaminated soil by a solvent/surfactant system.

    PubMed

    Chu, W; Kwan, C Y

    2003-10-01

    This study investigates a new approach using a solvent/surfactant-aided soil-washing process to improve the performance of conventional surfactant-aided soil remediation. Three surfactants (Brij 35, Tween 80, and SDS) and three organic solvents (acetone, triethylamine, and squalane) were used to evaluate the desorption performances of 4,4'-dichlorobiphenyl (DCB) out of three soils with different sorption characteristics. The performance improvement is likely due to better dissolution of the hydrophobic contaminants from the soil assisted by the solvent, and the formation of solvent-incorporated surfactant micelles, which increases both the size (i.e. capacity) and affinity of micelles for more effective contaminant extraction. The foc of soils were found to be important in determining the performance of a solvent/surfactant-aided soil-washing process. Judging from the experimental data and as verified by the two constants in the proposed soil-washing model, as the organic solvent is coexisting with the surfactant micelles, both the marginal soil-washing performance (right after the use of a very small amount of solvent compared to that of none) and the final soil-washing capacity are increased compared to those of a pure surfactant-aided washing process.

  5. Analysis of the remediation systems on the contaminant plume at the Plainville landfill

    SciTech Connect

    Woodworth, R.L.

    1999-06-01

    The Plainville landfill, located in Plainville, Massachusetts, has been the subject of study by several groups in recent years. A contaminant plume, exiting from the southwest corner of the landfill, is contaminating the groundwater downgradient and may affect drinking water wells located there. A two-phase remediation scheme, consisting of an interim overburden air sparging system and a final proposed pump and treat and air sparging system, has been proposed to mitigate the groundwater contaminant plume. This thesis assesses these remediation systems to determine their ability to remediate the contaminants in the groundwater plume. The interim and final proposed air sparging systems were analyzed using existing quarterly reports and a literature review. A MODFLOW groundwater flow model was used to analyze the pump and treat system. These analyses were then compared to the model utilized to design the remediation scheme. Several discrepancies in the design of the remediation scheme were noted as a result of this analysis. First, the presence of till lenses throughout the remediation zone was not addressed. Also, the extraction of water from the competent bedrock layer appears counterproductive. In addition, the air sparging system was not field tested to ascertain the flow pattern in the subsurface. Finally, the installation of the bedrock air sparging wells appears redundant. These discrepancies, however, will only decrease the projected efficiency of the proposed remediation schemes and increase clean up time. Consequently, the results of this study seem to indicate that the proposed remediation scheme is adequately designed.

  6. Environmental assessment of remedial action at the Naturita Uranium processing site near Naturita, Colorado. Revision 1

    SciTech Connect

    Not Available

    1993-08-01

    The proposed remedial action for the Naturita processing site is relocation of the contaminated materials and debris to the Dry Flats disposal site, 6 road miles (mi) [ 1 0 kilometers (km)] to the southeast. At the disposal site, the contaminated materials would be stabilized and covered with layers of earth and rock. The proposed disposal site is on land administered by the Bureau of Land Management (BLM) and used primarily for livestock grazing. The final disposal site would cover approximately 57 ac (23 ha), which would be permanently transferred from the BLM to the DOE and restricted from future uses. The remedial action activities would be conducted by the DOE`s Uranium Mill Tailings Remedial Action (UMTRA) Project. The remedial action would result in the loss of approximately 164 ac (66 ha) of soils, but 132 ac (53 ha) of these soils are contaminated and cannot be used for other purposes. Another 154 ac (62 ha) of soils would be temporarily disturbed. Approximately 57 ac (23 ha) of open range land would be permanently removed from livestock grazing and wildlife use. The removal of the contaminated materials would affect the 1 00-year floodplain of the San Miguel River and would result in the loss of riparian habitat along the river. The southwestern willow flycatcher, a Federal candidate species, may be affected by the remedial action, and the use of water from the San Miguel River ``may affect`` the Colorado squawfish, humpback chub, bonytail chub, and razorback sucker. Traffic levels on State Highways 90 and 141 would be increased during the remedial action, as would the noise levels along these transportation routes. Measures for mitigating the adverse environmental impacts of the proposed remedial action are discussed in Section 6.0 of this environmental assessment (EA).

  7. Sobol‧ sensitivity analysis of NAPL-contaminated aquifer remediation process based on multiple surrogates

    NASA Astrophysics Data System (ADS)

    Luo, Jiannan; Lu, Wenxi

    2014-06-01

    Sobol‧ sensitivity analyses based on different surrogates were performed on a trichloroethylene (TCE)-contaminated aquifer to assess the sensitivity of the design variables of remediation duration, surfactant concentration and injection rates at four wells to remediation efficiency First, the surrogate models of a multi-phase flow simulation model were constructed by applying radial basis function artificial neural network (RBFANN) and Kriging methods, and the two models were then compared. Based on the developed surrogate models, the Sobol‧ method was used to calculate the sensitivity indices of the design variables which affect the remediation efficiency. The coefficient of determination (R2) and the mean square error (MSE) of these two surrogate models demonstrated that both models had acceptable approximation accuracy, furthermore, the approximation accuracy of the Kriging model was slightly better than that of the RBFANN model. Sobol‧ sensitivity analysis results demonstrated that the remediation duration was the most important variable influencing remediation efficiency, followed by rates of injection at wells 1 and 3, while rates of injection at wells 2 and 4 and the surfactant concentration had negligible influence on remediation efficiency. In addition, high-order sensitivity indices were all smaller than 0.01, which indicates that interaction effects of these six factors were practically insignificant. The proposed Sobol‧ sensitivity analysis based on surrogate is an effective tool for calculating sensitivity indices, because it shows the relative contribution of the design variables (individuals and interactions) to the output performance variability with a limited number of runs of a computationally expensive simulation model. The sensitivity analysis results lay a foundation for the optimal groundwater remediation process optimization.

  8. Ecopiling: a combined phytoremediation and passive biopiling system for remediating hydrocarbon impacted soils at field scale

    PubMed Central

    Germaine, Kieran J.; Byrne, John; Liu, Xuemei; Keohane, Jer; Culhane, John; Lally, Richard D.; Kiwanuka, Samuel; Ryan, David; Dowling, David N.

    2015-01-01

    Biopiling is an ex situ bioremediation technology that has been extensively used for remediating a wide range of petrochemical contaminants in soils. Biopiling involves the assembling of contaminated soils into piles and stimulating the biodegrading activity of microbial populations by creating near optimum growth conditions. Phytoremediation is another very successful bioremediation technique and involves the use of plants and their associated microbiomes to degrade, sequester or bio-accumulate pollutants from contaminated soil and water. The objective of this study was to investigate the effectiveness of a combined phytoremediation/biopiling system, termed Ecopiling, to remediate hydrocarbon impacted industrial soil. The large scale project was carried out on a sandy loam, petroleum impacted soil [1613 mg total petroleum hydrocarbons (TPHs) kg-1 soil]. The contaminated soil was amended with chemical fertilizers, inoculated with TPH degrading bacterial consortia and then used to construct passive biopiles. Finally, a phyto-cap of perennial rye grass (Lolium perenne) and white clover (Trifolium repens) was sown on the soil surface to complete the Ecopile. Monitoring of important physico-chemical parameters was carried out at regular intervals throughout the trial. Two years after construction the TPH levels in the petroleum impacted Ecopiles were below detectable limits in all but one subsample (152 mg TPH kg-1 soil). The Ecopile system is a multi-factorial bioremediation process involving bio-stimulation, bio-augmentation and phytoremediation. One of the key advantages to this system is the reduced costs of the remediation process, as once constructed, there is little additional cost in terms of labor and maintenance (although the longer process time may incur additional monitoring costs). The other major advantage is that many ecological functions are rapidly restored to the site and the process is esthetically pleasing. PMID:25601875

  9. Ecopiling: a combined phytoremediation and passive biopiling system for remediating hydrocarbon impacted soils at field scale.

    PubMed

    Germaine, Kieran J; Byrne, John; Liu, Xuemei; Keohane, Jer; Culhane, John; Lally, Richard D; Kiwanuka, Samuel; Ryan, David; Dowling, David N

    2014-01-01

    Biopiling is an ex situ bioremediation technology that has been extensively used for remediating a wide range of petrochemical contaminants in soils. Biopiling involves the assembling of contaminated soils into piles and stimulating the biodegrading activity of microbial populations by creating near optimum growth conditions. Phytoremediation is another very successful bioremediation technique and involves the use of plants and their associated microbiomes to degrade, sequester or bio-accumulate pollutants from contaminated soil and water. The objective of this study was to investigate the effectiveness of a combined phytoremediation/biopiling system, termed Ecopiling, to remediate hydrocarbon impacted industrial soil. The large scale project was carried out on a sandy loam, petroleum impacted soil [1613 mg total petroleum hydrocarbons (TPHs) kg(-1) soil]. The contaminated soil was amended with chemical fertilizers, inoculated with TPH degrading bacterial consortia and then used to construct passive biopiles. Finally, a phyto-cap of perennial rye grass (Lolium perenne) and white clover (Trifolium repens) was sown on the soil surface to complete the Ecopile. Monitoring of important physico-chemical parameters was carried out at regular intervals throughout the trial. Two years after construction the TPH levels in the petroleum impacted Ecopiles were below detectable limits in all but one subsample (152 mg TPH kg(-1) soil). The Ecopile system is a multi-factorial bioremediation process involving bio-stimulation, bio-augmentation and phytoremediation. One of the key advantages to this system is the reduced costs of the remediation process, as once constructed, there is little additional cost in terms of labor and maintenance (although the longer process time may incur additional monitoring costs). The other major advantage is that many ecological functions are rapidly restored to the site and the process is esthetically pleasing.

  10. Identification and remediation of reading difficulties based on successive processing deficits and delay in general reading.

    PubMed

    Churches, Melinda; Skuy, Mervyn; Das, J P

    2002-12-01

    Widespread learning problems among South African children are associated with the apartheid era and show a need for effective reading programs. In selecting these programs, it is useful to differentiate between children with dyslexia and children whose reading is poor because teaching was inadequate. In this study, the Woodcock Tests of Reading Mastery-Revised and tests modelled on the Cognitive Assessment System were used to define a group of children with deficits in successive processing associated with dyslexia and a group of children with general reading delay. There were two girls and five boys in each group. For the children with successive processing deficit, the mean age was 9 yr., 8 mo. For the other group, mean age was 9 yr., 3 mo. Control groups were matched for age and sex and kind of reading difficulty. The first group received Das's PASS Reading Enhancement Program, and the second participated in a remedial program based on Whole Language principles. The treatment groups received 24 1-hr. long sessions. Gains in successive processing were shown for the first group, as measured by the tests modelled on Cognitive Assessment System subtests but not for the second group. Both groups showed gains in phonics and word identification, relative to their respective control groups, suggesting the respective intervention program was effective for each group.

  11. Application of a participative process for DSS development in soil remediation

    NASA Astrophysics Data System (ADS)

    José Blanco-Velázquez, Francisco; Muñoz-Vallés, Sara; Anaya-Romero, María

    2017-04-01

    A wide range of current legislation concerning environmental protection and public health at the national and international level include mandatory actions related to site characterization and the implementation of effective soil remediation measures. The efficiency, in terms of reliability and costs, of this kind of assessment, involves the development and linkage of integrated-harmonized databases, simulating models and specialization tools. So far, no data/knowledge engineering technologies in the academy or market provides the possibility for simulating soil remediation processes for hypothetic spatio-temporal scenarios in a harmonized manner across Europe. In this context, under the framework of RECARE (Preventing and Remediating degradation of Soils in Europe through Land Care) project, we are designing a Decision Support System (DSS) comprising a large database of knowledge including soil, climatic and socio-economic attributes, focused on soil remediation techniques that allows the user to automatically perform a more accurate quantifying of soil pollution, spatial identification of vulnerable zones and formulation of action programs to deal with the particular problem under scenarios of climate and land-use changes. The pilot study area is the Guadiamar valley (SW Spain) where the main threat is soil contamination, after a mine spill occurred on April 1998. About four hm3 of acid waters and two hm3 of mud, rich in heavy metals, were released into the Agrio and Guadiamar rivers affecting more than 4,600 ha of agricultural and pasture land. Consequently, the area was subjected to a large-scale phyto-management project, including the removal of sludge and topsoil, the addition of amendments, and plantation of native shrubs and trees. The objective of this research is to test the feasibility of the DSS concept as well as the likelihood to establish a solid high-potential innovation tool, aligned with the scientific and market strategy and within a European

  12. Remediation System Evaluation, Ott/Story/Cordova Superfund Site

    EPA Pesticide Factsheets

    The Ott/Story/Cordova Superfund Site occupies approximately 20 acres in Dalton Township, MuskegonCounty, Michigan. The remedies at the site address contamination stemming from a specialty organicchemical production facility operated under a series of..

  13. Geochemistry of rare earth elements in a passive treatment system built for acid mine drainage remediation.

    PubMed

    Prudêncio, Maria Isabel; Valente, Teresa; Marques, Rosa; Sequeira Braga, Maria Amália; Pamplona, Jorge

    2015-11-01

    Rare earth elements (REE) were used to assess attenuation processes in a passive system for acid mine drainage treatment (Jales, Portugal). Hydrochemical parameters and REE contents in water, soils and sediments were obtained along the treatment system, after summer and winter. A decrease of REE contents in the water resulting from the interaction with limestone after summer occurs; in the wetlands REE are significantly released by the soil particles to the water. After winter, a higher water dynamics favors the AMD treatment effectiveness and performance since REE contents decrease along the system; La and Ce are preferentially sequestered by ochre sludge but released to the water in the wetlands, influencing the REE pattern of the creek water. Thus, REE fractionation occurs in the passive treatment systems and can be used as tracer to follow up and understand the geochemical processes that promote the remediation of AMD. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. In situ remediation of hydrocarbon contamination using an injection-extraction process

    SciTech Connect

    Ross, A.; Tremblay, C.; Boulanger, C.

    1995-12-31

    Ecosite Inc. has developed a soil treatment technology to be applied in situ using an injection-extraction system (IES). This new restoration process uses custom-designed equipment for recovering free-phase hydrocarbons and for injection/recovery of different treatment solutions through cyclic manipulation of the water table level. Process development applied the basic principles of soil washing with improved distribution of the washing solution and improved hydraulic control using air sparging and vacuum capability. In this case study, free-phase recovery and soil washing have been used successfully to remediate the site. During the fall and winter of 1993--94, in situ restoration of soil contaminated with cutting oil below a machine shop was begun. The contamination extended from 1.83 to 4.27 m underneath the concrete slab. This represents a volume of 1,800 m{sup 3} of oil-laden soil with concentrations reaching 200,000 mg/kg. Moreover, free-floating phase hydrocarbons up to 1 m thick were observed. To clean the site, 400 injection/recovery points were arranged into three networks. A data collection system was used to monitor the water table level. A total of 160,000 kg of oil was extracted from the subsoil in less than 110 days of operation.

  15. Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants

    NASA Astrophysics Data System (ADS)

    Krishnan, S.; Rawindran, H.; Sinnathambi, C. M.; Lim, J. W.

    2017-06-01

    Due to the scarcity of water, it has become a necessity to improve the quality of wastewater that is discharged into the environment. Conventional wastewater treatment can be either a physical, chemical, and/or biological processes, or in some cases a combination of these operations. The main purpose of wastewater treatment is to eliminate nutrients, solids, and organic compounds from effluents. Current wastewater treatment technologies are deemed ineffective in the complete removal of pollutants, particularly organic matter. In many cases, these organic compounds are resistant to conventional treatment methods, thus creating the necessity for tertiary treatment. Advanced oxidation process (AOP), constitutes as a promising treatment technology for the management of wastewater. AOPs are characterised by a common chemical feature, where they utilize the highly reactive hydroxyl radicals for achieving complete mineralization of the organic pollutants into carbon dioxide and water. This paper delineates advanced oxidation processes currently used for the remediation of water and wastewater. It also provides the cost estimation of installing and running an AOP system. The costs are separated into three categories: capital, operational, and operating & maintenance.

  16. In-situ remediation system for groundwater and soils

    DOEpatents

    Corey, John C.; Kaback, Dawn S.; Looney, Brian B.

    1993-01-01

    A method and system for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants.

  17. The Hanford Site Tank Waste Remediation System: An update

    SciTech Connect

    Alumkal, W.T.; Babad, H.; Harmon, H.D.; Wodrich, D.D.

    1994-01-27

    The U.S. Department of Energy`s Hanford Site, located in southeastern Washington State, has the most diverse and largest amount of highly radioactive waste in the United States. High-level radioactive waste has been stored in large underground tanks since 1944. Approximately 230,000 m{sup 3} (61 Mgal) of caustic liquids, slurries, saltcakes, and sludges have {sup 137}Cs accumulated in 177 tanks. In addition, significant amounts of {sup 90}Sr and were removed from the tank waste, converted to salts, doubly encapsulated in metal containers., and stored in water basins. A Tank Waste Remediation System Program was established by the U.S. Department of Energy in 1991 to safely manage and immobilize these wastes in anticipation of permanent disposal of the high-level waste fraction in a geologic repository. Since 1991, progress has been made resolving waste tank safety issues, upgrading Tank Farm facilities and operations, and developing a new strategy for retrieving, treating, and immobilizing the waste for disposal.

  18. In-situ remediation system for groundwater and soils

    DOEpatents

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1993-11-23

    A method and system are presented for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants. 4 figures.

  19. Comparison of surrogate models with different methods in groundwater remediation process

    NASA Astrophysics Data System (ADS)

    Luo, Jiannan; Lu, Wenxi

    2014-10-01

    Surrogate modelling is an effective tool for reducing computational burden of simulation optimization. In this article, polynomial regression (PR), radial basis function artificial neural network (RBFANN), and kriging methods were compared for building surrogate models of a multiphase flow simulation model in a simplified nitrobenzene contaminated aquifer remediation problem. In the model accuracy analysis process, a 10-fold cross validation method was adopted to evaluate the approximation accuracy of the three surrogate models. The results demonstrated that: RBFANN surrogate model and kriging surrogate model had acceptable approximation accuracy, and further that kriging model's approximation accuracy was slightly higher than RBFANN model. However, the PR model demonstrated unacceptably poor approximation accuracy. Therefore, the RBFANN and kriging surrogates were selected and used in the optimization process to identify the most cost-effective remediation strategy at a nitrobenzene-contaminated site. The optimal remediation costs obtained with the two surrogate-based optimization models were similar, and had similar computational burden. These two surrogate-based optimization models are efficient tools for optimal groundwater remediation strategy identification.

  20. Decision and systems analysis for underground storage tank waste retrieval systems and tank waste remediation system

    SciTech Connect

    Berry, D.L.; Jardine, L.J.

    1993-10-01

    Hanford`s underground storage tanks (USTs) pose one of the most challenging hazardous and radioactive waste problems for the Department of Energy (DOE). Numerous schemes have been proposed for removing the waste from the USTs, but the technology options for doing this are largely unproven. To help assess the options, an Independent Review Group (IRG) was established to conduct a broad review of retrieval systems and the tank waste remediation system. The IRG consisted of the authors of this report. The IRG`s Preliminary Report assessed retrieval systems for underground storage tank wastes at Hanford in 1992. Westinghouse Hanford Company (WHC) concurred with the report`s recommendation that a tool should be developed for evaluating retrieval concepts. The report recommended that this tool include (1) important considerations identified previously by the IRG, (2) a means of documenting important decisions concerning retrieval systems, and (3) a focus on evaluations and assessments for the Tank Waste Remediation System (TWRS) and the Underground Storage Tank-Integrated Demonstration (UST-ID).

  1. Process control plan for tank 241-SY-101 surface level rise remediation

    SciTech Connect

    ESTEY, S.D.

    1999-06-29

    The tank 241-SY-101 transfer system was conceived and designed to address the immediate needs presented by rapidly changing waste conditions in tank 241-SY-101. Within the past year or so, the waste in this tank has exhibited unexpected behavior in the form of rapidly increasing crust growth. The Process Control Plan (PCP), HNF-4264, was written to translate high-level guidance and regulatory criteria and express it in terms of operating instructions for the waste transfer system. These controls include: (1) Tank Farm Operations Administrative Controls developed in response to DOE-ORP direction reg,arding supplemental controls placed upon tank 241-SY-101 surface level rise remediation activities specifically involving waste transfer activities. (2) Authorization Basis controls (Basis for Interim Operation (BIO)/Technical Safety Requirements (TSRs)) and supplemental DOE direction. (3) Environmental, Industrial Hygiene and Safety controls. (4) Operating Specification Document (OSD) controls. (5) Good operating practices. Included in the document are descriptions of tank conditions, waste conditions, major equipment, and a high-level overview of the system and the line-ups in which it operates. Primarily, the PCP addresses how the waste transfer will be managed, defining the monitoring and control methods including material balances to determine the progress and to define completion criteria for the transfer. The actual plant modifications and waste transfer will be authorized and controlled by plant procedures.

  2. Self-sustaining smoldering combustion for NAPL remediation: laboratory evaluation of process sensitivity to key parameters.

    PubMed

    Pironi, Paolo; Switzer, Christine; Gerhard, Jason I; Rein, Guillermo; Torero, Jose L

    2011-04-01

    Smoldering combustion has been introduced recently as a potential remediation strategy for soil contaminated by nonaqueous phase liquids (NAPLs). Published proof-of-concept experiments demonstrated that the process can be self-sustaining (i.e., requires energy input only to start the process) and achieve essentially complete remediation of the contaminated soil. Those initial experiments indicated that the process may be applicable across a broad range of NAPLs and soils. This work presents the results of a series of bench-scale experiments that examine in detail the sensitivity of the process to a range of key parameters, including contaminant concentration, water saturation, soil type, and air flow rates for two contaminants, coal tar and crude oil. Smoldering combustion was observed to be self-sustaining in the range 28,400 to 142,000 mg/kg for coal tar and in the range 31,200 to 104,000 mg/kg for crude oil, for the base case air flux. The process remained self-sustaining and achieved effective remediation across a range of initial water concentrations (0 to 177,000 mg/kg water) despite extended ignition times and decreased temperatures and velocities of the reaction front. The process also exhibited self-sustaining and effective remediation behavior across a range of fine to coarse sand grain sizes up to a threshold maximum value between 6 mm and 10 mm. Propagation velocity is observed to be highly dependent on air flux, and smoldering was observed to be self-sustaining down to an air Darcy flux of at least 0.5 cm/s for both contaminants. The extent of remediation in these cases was determined to be at least 99.5% and 99.9% for crude oil and coal tar, respectively. Moreover, no physical evidence of contamination was detected in the treatment zone for any case where a self-sustaining reaction was achieved. Lateral heat losses to the external environment were observed to significantly affect the smoldering process at the bench scale, suggesting that the field

  3. Tank waste remediation system multi-year work plan

    SciTech Connect

    Not Available

    1994-09-01

    The Tank Waste Remediation System (TWRS) Multi-Year Work Plan (MYWP) documents the detailed total Program baseline and was constructed to guide Program execution. The TWRS MYWP is one of two elements that comprise the TWRS Program Management Plan. The TWRS MYWP fulfills the Hanford Site Management System requirement for a Multi-Year Program Plan and a Fiscal-Year Work Plan. The MYWP addresses program vision, mission, objectives, strategy, functions and requirements, risks, decisions, assumptions, constraints, structure, logic, schedule, resource requirements, and waste generation and disposition. Sections 1 through 6, Section 8, and the appendixes provide program-wide information. Section 7 includes a subsection for each of the nine program elements that comprise the TWRS Program. The foundation of any program baseline is base planning data (e.g., defendable product definition, logic, schedules, cost estimates, and bases of estimates). The TWRS Program continues to improve base data. As data improve, so will program element planning, integration between program elements, integration outside of the TWRS Program, and the overall quality of the TWRS MYWP. The MYWP establishes the TWRS baseline objectives to store, treat, and immobilize highly radioactive Hanford waste in an environmentally sound, safe, and cost-effective manner. The TWRS Program will complete the baseline mission in 2040 and will incur costs totalling approximately 40 billion dollars. The summary strategy is to meet the above objectives by using a robust systems engineering effort, placing the highest possible priority on safety and environmental protection; encouraging {open_quotes}out sourcing{close_quotes} of the work to the extent practical; and managing significant but limited resources to move toward final disposition of tank wastes, while openly communicating with all interested stakeholders.

  4. Tank waste remediation system multi-year work plan

    SciTech Connect

    Not Available

    1994-09-01

    The Tank Waste Remediation System (TWRS) Multi-Year Work Plan (MYWP) documents the detailed total Program baseline and was constructed to guide Program execution. The TWRS MYWP is one of two elements that comprise the TWRS Program Management Plan. The TWRS MYWP fulfills the Hanford Site Management System requirement for a Multi-Year Program Plan and a Fiscal-Year Work Plan. The MYWP addresses program vision, mission, objectives, strategy, functions and requirements, risks, decisions, assumptions, constraints, structure, logic, schedule, resource requirements, and waste generation and disposition. Sections 1 through 6, Section 8, and the appendixes provide program-wide information. Section 7 includes a subsection for each of the nine program elements that comprise the TWRS Program. The foundation of any program baseline is base planning data (e.g., defendable product definition, logic, schedules, cost estimates, and bases of estimates). The TWRS Program continues to improve base data. As data improve, so will program element planning, integration between program elements, integration outside of the TWRS Program, and the overall quality of the TWRS MYWP. The MYWP establishes the TWRS baseline objectives to store, treat, and immobilize highly radioactive Hanford waste in an environmentally sound, safe, and cost-effective manner. The TWRS Program will complete the baseline mission in 2040 and will incur costs totalling approximately 40 billion dollars. The summary strategy is to meet the above objectives by using a robust systems engineering effort, placing the highest possible priority on safety and environmental protection; encouraging {open_quotes}out sourcing{close_quotes} of the work to the extent practical; and managing significant but limited resources to move toward final disposition of tank wastes, while openly communicating with all interested stakeholders.

  5. Remedial action plan for the inactive Uranium Processing Site at Naturita, Colorado. Remedial action plan: Attachment 2, Geology report, Attachment 3, Ground water hydrology report: Working draft

    SciTech Connect

    Not Available

    1994-09-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the US Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), 42 USC {section}7901 et seq. Part of the UMTRCA requires that the US Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the US Environmental Protection Agency (EPA). This RAP serves two purposes. First, it describes the activities that are proposed by the DOE to accomplish remediation and long-term stabilization and control of the radioactive materials at the inactive uranium processing site near Naturita, Colorado. Second, this RAP, upon concurrence and execution by the DOE, the state of Colorado, and the NRC, become Appendix B of the cooperative agreement between the DOE and the state of Colorado.

  6. Business process reengineering: a remedy for health care.

    PubMed

    Carmichael, B D

    1994-01-01

    Health care organizations are facing significant economic constraints that threaten to dismantle core services. The perceived need for reform is great. Business process reengineering may be the strong medicine required to achieve dramatic productivity improvement without jeopardizing the quality and scope of core health care services. Reengineering challenges health care organizations to eliminate functions that do not contribute to a flattened organization structure in which fewer care providers deliver a wider range of health care services. Information technology is used to displace manual checks and controls. Reengineering may facilitate the implementation of contemporary management models, such as patient-focused care, case management and product or program management. The product of reengineering can be enhanced over time by Continuous Quality Improvement.

  7. Ultrasonically aided mineral processing technique for remediation of soil contaminated by heavy metals.

    PubMed

    Kyllönen, Hanna; Pirkonen, Pentti; Hintikka, Väinö; Parvinen, Pekka; Grönroos, Antti; Sekki, Hannu

    2004-05-01

    In this study, power ultrasound was used as aiding method for the mineral processing technique, which have recently been developed for the remediation of soil contaminated by heavy metal containing bullets, their broken parts and alteration products. Power ultrasound was used to disperse the soil to remove metals and metal compounds from soil particle surfaces instead of attrition conditioning. The soil diluted with water was treated using 22 kHz ultrasound power of 100 W up to 500 W. The effect of different ultrasonic treatment time and pulsation of ultrasound were studied on the purity of sink and float fractions in heavy medium separation process, screen fractions, and mineral concentrates and tailings from flotation process. Ultrasound enhanced the remediation of soil fractions in all the studied cases. Optimisation of the ultrasonic power will be done in the continuation study.

  8. Application of electro-Fenton technology to remediation of polluted effluents by self-sustaining process.

    PubMed

    Fernández de Dios, Maria Ángeles; Iglesias, Olaia; Pazos, Marta; Sanromán, Maria Ángeles

    2014-01-01

    The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel cells (MFCs) were designed in order to supply electricity to electro-Fenton processes and to achieve high treatment efficiency at low cost. Initially, the effect of key parameters on the MFC power generation was evaluated. Afterwards, the degradation of Reactive Black 5 dye and phenanthrene was evaluated in an electro-Fenton reactor, containing iron-enriched zeolite as catalyst, using the electricity supplied by the MFC. Near complete dye decolourization and 78% of phenanthrene degradation were reached after 90 min and 30 h, respectively. Furthermore, preliminary reusability tests of the developed catalyst showed high degradation levels for successive cycles. The results permit concluding that the integrated system is adequate to achieve high treatment efficiency with low electrical consumption.

  9. Application of Electro-Fenton Technology to Remediation of Polluted Effluents by Self-Sustaining Process

    PubMed Central

    Fernández de Dios, Maria Ángeles; Iglesias, Olaia; Pazos, Marta; Sanromán, Maria Ángeles

    2014-01-01

    The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel cells (MFCs) were designed in order to supply electricity to electro-Fenton processes and to achieve high treatment efficiency at low cost. Initially, the effect of key parameters on the MFC power generation was evaluated. Afterwards, the degradation of Reactive Black 5 dye and phenanthrene was evaluated in an electro-Fenton reactor, containing iron-enriched zeolite as catalyst, using the electricity supplied by the MFC. Near complete dye decolourization and 78% of phenanthrene degradation were reached after 90 min and 30 h, respectively. Furthermore, preliminary reusability tests of the developed catalyst showed high degradation levels for successive cycles. The results permit concluding that the integrated system is adequate to achieve high treatment efficiency with low electrical consumption. PMID:24723828

  10. A scholastic appeals process for dental hygiene student remediation and retention.

    PubMed

    Freudenthal, Jacqueline; Bowen, Denise M

    2010-03-01

    A scholastic appeals process tailoring individualized remediation for dental hygiene students not meeting academic standards was assessed retrospectively (1999-2008) to evaluate retention and academic failure rates, nature of academic problems, type of remediation, and success of recommendations. Academic records of students (n=55) not meeting academic standards and/or withdrawing were reviewed. Overall retention (92.7 percent) ranged from 86.7 percent to 96.6 percent. Of the fifty-five students whose records were reviewed, six students (10.91 percent) withdrew for medical/personal reasons, and forty-nine (89.1 percent) petitioned for individualized remediation. The number and percentage of students in each category of reasons are as follows: four (7.5 percent) preclinical; thirty-seven (69.8 percent) clinical; eight (15.1 percent) academic/clinical/personal reasons; and four (7.5 percent) academic dishonesty. The options approved were the following: continue in the program with grade below C- (n=3), summer clinical course with individualized contract (n=11), or independent study course during the academic year plus the summer course (n=13), all without delaying graduation; repeating a course with a one-semester delay in graduation (n=7); and auditing/repeating multiple courses with a one-year delay in graduation (n=3). Twelve students were dismissed after denial of a petition requesting remediation or second failure. The scholastic appeals process was successful for 75.5 percent (n=37) of the students who petitioned after failing to meet academic standards, thereby contributing to the 92.7 percent overall retention rate. Student-specific remediation plans based on individual academic appeals are viable options for ensuring success.

  11. Environmental assessment of remedial action at the Naturita uranium processing site near Naturita, Colorado: Revision 5

    SciTech Connect

    Not Available

    1994-10-01

    Title 1 of the Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978, Public Law (PL) 95-604, authorized the US Department of Energy (DOE) to perform remedial action at the inactive Naturita, Colorado, uranium processing site to reduce the potential health effects from the radioactive materials at the site and at vicinity properties associated with the site. Title 2 of the UMTRCA authorized the US Nuclear Regulatory Commission (NRC) or agreement state to regulate the operation and eventual reclamation of active uranium processing sites. The uranium mill tailings at the site were removed and reprocessed from 1977 to 1979. The contaminated areas include the former tailings area, the mill yard, the former ore storage area, and adjacent areas that were contaminated by uranium processing activities and wind and water erosion. The Naturita remedial action would result in the loss of 133 acres (ac) of contaminated soils at the processing site. If supplemental standards are approved by the NRC and the state of Colorado, approximately 112 ac of steeply sloped contaminated soils adjacent to the processing site would not be cleaned up. Cleanup of this contamination would have adverse environmental consequences and would be potentially hazardous to remedial action workers.

  12. In situ remediation process using divalent metal cations

    DOEpatents

    Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

    2004-12-14

    An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

  13. Fenton's oxidation process for phenolic wastewater remediation and biodegradability enhancement.

    PubMed

    Martins, Rui C; Rossi, André F; Quinta-Ferreira, Rosa M

    2010-08-15

    A mixture of six phenolic acids, corresponding to an initial TOC of 370 mgC/L, was studied by Fenton's peroxidation aiming to improve the biodegradability of agro-industrial wastewaters. Input operating variables including the concentration of pollutants, iron and hydrogen peroxide as well as the reaction time were used to assess the mineralization degree through a factorial experimental methodology. A TOC removal in the range of 15.0-58.8% was attained within the operational conditions used. A reduced model was achieved using the statistically important independent factors and interactions to predict TOC degradation. On the hydrogen peroxide injection methodology, the results showed that the continuous introduction of small volumes is advantageous when compared with one single addition of the overall volume at the zero reaction time with a mineralization improvement of 11%. The use of FeSO(4).7H(2)O correspondent to a Fe(2+) load of 271 mg; [H(2)O(2)]=488.0 mM, injected in twelve aliquots each 30 min during 6h of reaction reached optimal efficiencies with the parent compounds (quantified by HPLC and the Folin-Ciocalteau method) quickly totally removed and TOC, COD and BOD(5) final values of 123 mgC/L, 180 mgO(2)/L and 146 mgO(2)/L, respectively. Toxicity assessment by Vibrio fischeri light inhibition revealed that Fenton's process reduces the effluent ecological impact related with the decomposition of the toxic phenolic acids. Indeed, EC(50) changed from 32.2% dilution to no-dilution needed. The analysis of BOD(5)/COD ratio pointed out a high improvement of the treated wastewater biodegradability from 0.30 to 0.80 meaning that the application of Fenton's oxidation as a pre-treatment enables a further application of an efficient post-biological technology which was also confirmed by respirometry.

  14. Membrane System for Recovery of Volatile Organic Compounds from Remediation Off-Gases.: Phase 1.

    SciTech Connect

    Wijmans, J.G.; Goakey, S.; Wang, X.; Baker, R.W.; Kaschemekat, J.H.

    1997-04-01

    In situ vacuum extraction, air or steam sparging, and vitrification are widely used methods of remediating soil contaminated with volatile organic compounds (VOCs). All of these processes produce a VOC-laden air stream from which the VOC must be removed before the air can be discharged or recycled to the generating process. Treatment of these off-gases is often a major portion of the cost of the remediation project. Carbon adsorption and catalytic incineration, the most common methods of treating these gas streams, suffer from significant drawbacks. This report covers the first phase of a two-phase project. The first phase involved the laboratory demonstration of the water separation section of the unit, the production and demonstration of new membrane modules to improve the separation, the design studies required for the demonstration system, and initial contacts with potential field sites. In the second phase, the demonstration system will be built and, after a short laboratory evaluation, will be tested at two field sites.

  15. IMPACT OF REDOX DISEQUILIBRIA ON CONTAMINANT TRANSPORT AND REMEDIATION IN SUBSURFACE SYSTEMS

    EPA Science Inventory

    Partitioning to mineral surfaces exerts significant control on inorganic contaminant transport in subsurface systems. Remedial technologies for in-situ treatment of subsurface contamination are frequently designed to optimize the efficiency of contaminant partitioning to solid s...

  16. IMPACT OF REDOX DISEQUILIBRIA ON CONTAMINANT TRANSPORT AND REMEDIATION IN SUBSURFACE SYSTEMS

    EPA Science Inventory

    Partitioning to mineral surfaces exerts significant control on inorganic contaminant transport in subsurface systems. Remedial technologies for in-situ treatment of subsurface contamination are frequently designed to optimize the efficiency of contaminant partitioning to solid s...

  17. Remedial investigation of the High-Explosives (HE) Process Area, Lawrence Livermore National Laboratory Site 300

    SciTech Connect

    Crow, N.B.; Lamarre, A.L.

    1990-08-01

    This report presents the results of a Remedial Investigation (RI) to define the extent of high explosives (HE) compounds and volatile organic compounds (VOCs) found in the soil, rocks, and ground water of the HE Process Area of Lawrence Livermore National Laboratory's (LLNL) Site 300 Facility. The report evaluates potential public health environmental risks associated with these compounds. Hydrogeologic information available before February 15, 1990, is included; however, chemical analyses and water-level data are reported through March 1990. This report is intended to assist the California Regional Water Quality Control Board (RWQCB)--Central Valley Region and the US Environmental Protection Agency (EPA) in evaluating the extent of environmental contamination of the LLNL HE Process Area and ultimately in designing remedial actions. 90 refs., 20 figs., 7 tabs.

  18. Evaluation of Geochemical Processes Affecting Uranium Sequestration and Longevity of Permeable Reactive Barriers for Groundwater Remediation

    NASA Astrophysics Data System (ADS)

    Fuller, C. C.; Webb, S.; Bargar, J.; Naftz, D. L.

    2009-12-01

    Development of effective remediation techniques for protecting existing drinking water supplies and for mitigating existing contamination problems requires evaluating both the contaminant sequestration processes and the secondary reactions affecting the long term stability of contaminant attenuation. Permeable reactive barriers (PRB) provide a means for passive remediation of dissolved groundwater contaminants and may be an effective strategy for remediation of uranium (U) groundwater contamination provided that long term stability of the sequestered U can be achieved for the geochemical conditions of the aquifer expected subsequent to remediation. Understanding the chemical reaction mechanisms resulting in U uptake and PRB performance are critical to evaluating the potential for release of sequestered U and for improved design of remediation devices. We are using synchrotron X-ray techniques to investigate U sequestration reaction mechanisms and biogeochemical processes in PRB materials recovered from a 9-year field demonstration of zero-valent iron (ZVI) and bone char apatite PRBs in a U contaminated aquifer near Fry Canyon, Utah. X-ray microprobe mapping of iron phases shows that extensive secondary precipitation of mackinawite, siderite and aragonite in the ZVI PRB has resulted from ZVI corrosion coupled with microbial sulfate reduction. Bulk U-EXAFS measurements and micron-scale U-oxidation state mapping indicates that U removal occurs largely by reduction and precipitation of a UO2-like U(IV) phase on the ZVI surfaces, and that the sequestered U is often buried by the secondary Fe precipitates. These findings are significant to the efficacy of ZVI PRBs for remediation of U and other contaminants in that the ongoing secondary phase precipitation cements grains and fills internal porosity resulting in the observed decreased PRB permeability and limits subsequent U removal, but likely limits oxidative remobilization of U. In the bone char apatite PRB, elevated

  19. Operable Unit 3-13, Group 7, SFE-20 Hot Waste Tank System Remedial Action Request

    SciTech Connect

    L. Davison

    2009-06-30

    This Remedial Action Report summarizes activities undertaken to remediate the Operable Unit 3-13, Group 7, SFE-20 Hot Waste Tank System at the Idaho Nuclear Technology and Engineering Center at the Idaho National Laboratory Site. The site addressed in this report was defined in the Operable Unit 3-13 Record of Decision and subsequent implementing documents. This report concludes that remediation requirements and cleanup goals established for the site have been accomplished and is hereafter considered a No Further Action site.

  20. Operable Unit 3-13, Group 7, SFE-20 Hot Waste Tank System Remedial Action Report

    SciTech Connect

    Lee Davison

    2009-06-30

    This Remedial Action Report summarizes activities undertaken to remediate the Operable Unit 3-13, Group 7, SFE-20 Hot Waste Tank System at the Idaho Nuclear Technology and Engineering Center at the Idaho National Laboratory Site. The site addressed in this report was defined in the Operable Unit 3-13 Record of Decision and subsequent implementing documents. This report concludes that remediation requirements and cleanup goals established for the site have been accomplished and is hereafter considered a No Further Action site.

  1. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Remedial action selection report, Attachment 2, Geology report: Preliminary final

    SciTech Connect

    Not Available

    1993-08-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the US Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), Public Law 95-604. Part of the UMTRCA requires that the US Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the US Environmental Protection Agency (EPA). Included in the RAP is this Remedial Action Selection Report (RAS), which serves two purposes. First, it describes the activities that are proposed by the DOE to accomplish remediation and long-term stabilization and control of the radioactive materials at the inactive uranium processing site near Naturita, Colorado. Second, this document and the rest of the RAP, upon concurrence and execution by the DOE, the state of Colorado, and the NRC, become Appendix B of the cooperative agreement between the DOE and the State of Colorado.

  2. Decommissioning of the remediation systems at Waverly, Nebraska, in 2011-2012.

    SciTech Connect

    LaFreniere, L. M.

    2012-06-29

    the CCC/USDA characterization and remediation efforts, including the quarterly monitoring reports, is on the compact disc inside the back cover of this report. The EPA reported on the progress of the remediation systems in a series of five-year reviews (EPA 1993, 1999, 2004, 2009). These reports and other EPA documentation are also on the compact disc inside the back cover of this report, along with the Woodward-Clyde (1986, 1988a,b) documentation cited. Starting in 2006, the analytical results for groundwater (the only medium still being monitored) showed no carbon tetrachloride concentrations above the maximum contaminant level (MCL) of 5.0 g/L. Because the cleanup goals specified in the ROD (EPA 1990) had been met, the EPA removed the site from the NPL in November 2006 (Appendix A). In 2008 the National Pollutant Discharge Elimination System (NPDES) permit for the remediation system was deactivated, and a year later the EPA released its fourth and final five-year report (EPA 2009), indicating that no further action was required for the site and that the site was ready for unlimited use. In 2011-2012, the CCC/USDA decommissioned the remediation systems at Waverly. This report documents the decommission process and closure of the site.

  3. Metal attenuation processes in a landfill containing coal combustion waste: Implications for remediation

    SciTech Connect

    Barton, Christopher; Paddock, Lindy; Romanek, Christopher; Maharaj, Sally; Seaman, John

    2005-03-01

    Barton, Christopher, L. Paddock, Cromanek, S. Maharaj, and J. Seaman. 2005. Metal attenuation processes in a landfill containing coal combustion waste: Implications for remediation. Env. Geosci. 12(1): 45-55. Abstract - The 488-D Ash Basin (488-DAB) is an unlined, earthen landfill containing approximately 1 million t of dry ash and coal reject material at the U.S. Department of Energy's Savannah River Site, South Carolina. The pyritic nature of the coal rejects has resulted in the formation of acidic drainage, which has contributed to groundwater deterioration and threatened biota in adjacent wetlands. Establishment of a vegetation cover to both deplete oxygen through biological means and optimize evapotranspiration has been established as a remedial alternative for reducing acidic drainage generation in the 488-DAB. To determine the potential benefits of a cover, a series of characterization studies were conducted prior to field deployment to gain a better understanding of the metal attenuation processes and to use water quality and substrate data to evaluate the potential effectiveness of this remedial approach. The characterization study indicated that metal attenuation was primarily controlled by fluctuating redox and pH gradients associated with alternating saturated and unsaturated conditions in the basin. Based on this information, a vegetative cover could reduce the production of acid leachate over time, pending that oxygen transport to the subsurface is limited.

  4. Remedial Investigation/Feasibility Study (RI/FS) process, elements and techniques guidance

    SciTech Connect

    Not Available

    1993-12-01

    This manual provides detailed guidance on Remedial Investigation/Feasibility Studies (RI/FSs) conducted pursuant to the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) at Department of Energy (DOE) facilities. The purpose of the RI/FS, to assess the risk posed by a hazardous waste site and to determine the best way to reduce that risk, and its structure (site characterization, risk assessment, screening and detailed analysis of alternatives, etc.) is defined in the National Oil and Hazardous Substances Pollution Contingency Plan (NCP) and further explained in the Environmental Protection Agency`s (EPA`s) Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA (Interim Final) 540/G-89/004, OSWER Directive 9355.3-01, October 1988. Though issued in 1988, the EPA guidance remains an excellent source of information on the conduct and structure of an RI/FS. This document makes use of supplemental RI/FS-related guidance that EPA has developed since its initial document was issued in 1988, incorporates practical lessons learned in more than 12 years of experience in CERCLA hazardous site remediation, and drawing on those lessons, introduces the Streamlined Approach For Environmental Restoration (SAFER), developed by DOE as a way to proceed quickly and efficiently through the RI/FS process at DOE facilities. Thus as its title implies, this guidance is intended to describe in detail the process and component elements of an RI/FS, as well as techniques to manage the RI/FS effectively.

  5. Ultrasonic process for remediation of organics-contaminated groundwater/wastewater

    SciTech Connect

    Wu, J.M.; Peters, R.W.

    1995-07-01

    A technology is being developed that employs ultrasonic-wave energy for remediation of groundwater/wastewater contaminated with volatile organic compounds such as carbon tetrachloride (CCl{sub 4}) and trichloroethylene (TCE). This paper presents the updated results of a laboratory investigation of ultrasonic groundwater remediation using synthetic groundwaters prepared with laboratory deionized water. Key process parameters investigated included steady-state temperature, contaminant concentration, solution pH, sonication time, and intensity of the applied ultrasonics-wave energy. High destruction efficiencies of the target contaminants were achieved, and the sonication time required for a given degree of destruction decreased with increasing intensity of the applied ultrasonic energy. The sonication time can be further reduced by adding a chemical oxidant such as hydrogen peroxide.

  6. The role of chemical and physical watershed processes in the remediation of AMD impacted streams

    NASA Astrophysics Data System (ADS)

    Lopez, D. A. L.; Kruse, N.; Bowman, J.

    2016-12-01

    Thousands of miles of streams in the United States are impacted by acid mine drainage (AMD) produced by the exploitation of metal and coal mines. Several methods of remediation are used to improve the water quality and recover the diversity in the aquatic life. One of these methods is the addition of alkaline materials to the stream to neutralize the water, precipitate minerals of heavy metals, and rise the pH. Parameters that are usually considered to determine the load of alkalinity to remediate the water include the acidity and flow of the source(s), and concentration of heavy metals. However, recent studies in AMD remediated streams in SE Ohio suggest that the evolution of the water and sediment chemistry along the stream after remediation is also important, and than that evolution depends no only in the added alkalinity but also in the physical and chemical characteristics of the impacted stream. Retention of precipitated fine-grained sediments is important to improve the physical environment for the aquatic life downstream. If sediment retention ponds cannot be constructed, the occurrence of areas where sediments can be deposited and stored is determined by the topographic gradient of the stream. A detailed high-resolution profile of the stream should be constructed to identify regions where the sediments can be retained. The addition of water, dissolved and suspended matter from tributaries to the main stem should also be considered. Tributaries can provide additional alkalinity or acidity to the stream helping to the remediation process or making it more difficult. Groundwater discharges to the stream can also provide either additional alkalinity or acidity to the stream, affecting the chemical budget. These additions from surface and/or groundwater can play an important role in stream recovery. A budget of alkalinity, acidity, and other chemical species along the impacted stream can provide important information to predict the effect of alkaline additions

  7. A niched Pareto tabu search for multi-objective optimal design of groundwater remediation systems

    NASA Astrophysics Data System (ADS)

    Yang, Yun; Wu, Jianfeng; Sun, Xiaomin; Wu, Jichun; Zheng, Chunmiao

    2013-05-01

    This study presents a new multi-objective optimization method, the niched Pareto tabu search (NPTS), for optimal design of groundwater remediation systems. The proposed NPTS is then coupled with the commonly used flow and transport code, MODFLOW and MT3DMS, to search for the near Pareto-optimal tradeoffs of groundwater remediation strategies. The difference between the proposed NPTS and the existing multiple objective tabu search (MOTS) lies in the use of the niche selection strategy and fitness archiving to maintain the diversity of the optimal solutions along the Pareto front and avoid repetitive calculations of the objective functions associated with the flow and transport model. Sensitivity analysis of the NPTS parameters is evaluated through a synthetic pump-and-treat remediation application involving two conflicting objectives, minimizations of both remediation cost and contaminant mass remaining in the aquifer. Moreover, the proposed NPTS is applied to a large-scale pump-and-treat groundwater remediation system of the field site at the Massachusetts Military Reservation (MMR) in Cape Cod, Massachusetts, involving minimizations of both total pumping rates and contaminant mass remaining in the aquifer. Additional comparison of the results based on the NPTS with those obtained from other two methods, namely the single objective tabu search (SOTS) and the nondominated sorting genetic algorithm II (NSGA-II), further indicates that the proposed NPTS has desirable computation efficiency, stability, and robustness and is a promising tool for optimizing the multi-objective design of groundwater remediation systems.

  8. Management assessment of tank waste remediation system contractor readiness to proceed with phase 1B privatization

    SciTech Connect

    Honeyman, J.O.

    1998-01-09

    This Management Assessment of Tank Waste Remediation System (TWRS) Contractor Readiness to Proceed With Phase 1B Privatization documents the processes used to determine readiness to proceed with tank waste treatment technologies from private industry, now known as TWRS privatization. An overall systems approach was applied to develop action plans to support the retrieval and disposal mission of the TWRS Project. The systems and infrastructure required to support the mission are known. Required systems are either in place or plans have been developed to ensure they exist when needed. Since October 1996 a robust system engineering approach to establishing integrated Technical Baselines, work breakdown structures, tank farms organizational structure and configurations, work scope, and costs has become part of the culture within the TWRS Project. An analysis of the programmatic, management, and technical activities necessary to declare readiness to proceed with execution of the mission demonstrates that the system, personnel, and hardware will be on-line and ready to support the private contractors. The systems approach included defining the retrieval and disposal mission requirements and evaluating the readiness of the Project Hanford Management Contract (PHMC) team to support initiation of waste processing by the private contractors in June 2002 and to receive immobilized waste shortly thereafter. The Phase 1 feed delivery requirements from the private contractor Requests for Proposal were reviewed. Transfer piping routes were mapped, existing systems were evaluated, and upgrade requirements were defined.

  9. DOE underground storage tank waste remediation chemical processing hazards. Part I: Technology dictionary

    SciTech Connect

    DeMuth, S.F.

    1996-10-01

    This document has been prepared to aid in the development of Regulating guidelines for the Privatization of Hanford underground storage tank waste remediation. The document has been prepared it two parts to facilitate their preparation. Part II is the primary focus of this effort in that it describes the technical basis for established and potential chemical processing hazards associated with Underground Storage Tank (UST) nuclear waste remediation across the DOE complex. The established hazards involve those at Sites for which Safety Analysis Reviews (SARs) have already been prepared. Potential hazards are those involving technologies currently being developed for future applications. Part I of this document outlines the scope of Part II by briefly describing the established and potential technologies. In addition to providing the scope, Part I can be used as a technical introduction and bibliography for Regulatory personnel new to the UST waste remediation, and in particular Privatization effort. Part II of this document is not intended to provide examples of a SAR Hazards Analysis, but rather provide an intelligence gathering source for Regulatory personnel who must eventually evaluate the Privatization SAR Hazards Analysis.

  10. Calcium polysulfide remediation of hexavalent chromium contamination from chromite ore processing residue.

    PubMed

    Graham, Margaret C; Farmer, John G; Anderson, Peter; Paterson, Edward; Hillier, Stephen; Lumsdon, David G; Bewley, Richard J F

    2006-07-01

    Past disposal of high-lime chromite ore processing residue (COPR) from a chemical works in S.E. Glasgow, UK, has led to continuing release of toxic and carcinogenic hexavalent chromium (Cr(VI)) to groundwaters which are highly contaminated with Cr(VI)O4(2-). Traditional methods of remediating Cr(VI)-contaminated land, e.g. using ferrous sulfate and organic matter, have had limited success in converting Cr(VI) to less harmful and insoluble Cr(III). This paper describes the first application of calcium polysulfide (CaS(x)) to the remediation of contaminated groundwater and high-lime COPR in a series of laboratory experiments, which have demonstrated the effectiveness of the treatment in quantitatively and rapidly reducing Cr(VI) to Cr(III) over the pH range (8-12.5) typically found at the sites. Cr(III)-organic complexes, present in groundwater at one location, were also effectively precipitated upon treatment with CaS(x). The potential for large-scale use of CaS(x) in the remediation of Cr(VI) from COPR is also discussed.

  11. The Resilience of Groundwater Remediation System in Response to Changing Conditions

    NASA Astrophysics Data System (ADS)

    Hou, D.

    2016-12-01

    Anthropogenic activities have caused the contamination of groundwater resources at many locations. In an effort to protect human health and prevent further spreading of groundwater contamination, remediation systems have been or will be built at hundreds of thousands of sites. While the short term effectiveness has been the focus of past research and practice, the long-term effectiveness is increasingly scrutinized. When assessing the long-term effectiveness of groundwater remediation systems, it is important to examine how existing remediation systems respond to changing geophysical (e.g. climate change) and social (e.g. improved living standard and changing development needs) conditions. The resilience of remediation strategies, or their potential to adapt to future changes, is a critical sustainability consideration. We intend to examine the resilience of groundwater remediation systems in response to changing conditions. Among others, we explore the effects of sea level rise and changing hydroclimatic conditions on the life cycle impact of phytoremediation and bioremediation systems. The study was conducted in the San Francisco Bay area, where thousands of contaminated sites are located in an area that may be affected by sea level rise and changing hydroclimatic conditions.

  12. Hanford Tank Waste Remediation Systems (TWRS) Waste Pretreatment Program strategy and issues

    SciTech Connect

    Gasper, K.A.

    1994-02-01

    The US Department of Energy (DOE) has established the Tank Waste Remediation System (TWRS) to safely manage an dispose of the Hanford Site tank waste. Pretreatment is one of the major program elements of the TWRS. The scope of the TWRS Tank Waste Pretreatment Program is to treat tank waste to separate it into high- and low-level waste fractions and to provide additional treatment as required to feed low-level waste fractions and to provide additional treatment as required to feed low-level and high-level waste immobilization processes. The Pretreatment Program activities include technology development, design, fabrication, construction, and operation of facilities to support the pretreatment of radioactive mixed waste retrieved from 28 large underground double-shell tanks and 149 single-shell tanks.

  13. Final audit report of remedial action construction at the UMTRA Project, Grand Junction, Colorado, processing site

    SciTech Connect

    1995-02-01

    This final audit report (FAR) for remedial action at the Grand Junction, Colorado, Uranium Mill Tailings Remedial Action (UMTRA) Project processing site consists of a summary of the radiological surveillances/ audits, the quality assurance (QA) in-process surveillances, and the QA final close-out inspection performed by the US Department of Energy (DOE) and Technical Assistance Contractor (TAC). The FAR also summarizes other surveillances performed by the US Nuclear Regulatory Commission (NRC). To summarize, a total of one finding and 127 observations were noted during DOE/TAC audit and surveillance activities. The NRC noted general site-related observations during the OSCRs. Follow-up to responses required from MK-Ferguson for the DOE/TAC finding and observations indicated that all issues related to the Grand Junction processing site were resolved and closed out to the DOE`s satisfaction. The NRC OSCRs resulted in no issues related to the Grand Junction processing site requiring a response from MK-Ferguson.

  14. Chromium-Removal Processes during Groundwater Remediation by a Zerovalent Iron Permeable Reactive Barrier

    SciTech Connect

    Wilkin, Richard T.; Su, Chunming; Ford, Robert G.; Paul, Cynthia J.

    2008-06-09

    Solid-phase associations of chromium were examined in core materials collected from a full-scale, zerovalent iron permeable reactive barrier (PRB) at the U.S. Coast Guard Support Center located near Elizabeth City, NC. The PRB was installed in 1996 to treat groundwater contaminated with hexavalent chromium. After eight years of operation, the PRB remains effective at reducing concentrations of Cr from average values >1500 {micro}g L{sup -1} in groundwater hydraulically upgradient of the PRB to values <1 {micro}g L{sup -1} in groundwater within and hydraulically downgradient of the PRB. Chromium removal from groundwater occurs at the leading edge of the PRB and also within the aquifer immediately upgradient of the PRB. These regions also witness the greatest amount of secondary mineral formation due to steep geochemical gradients that result from the corrosion of zerovalent iron. X-ray absorption near-edge structure (XANES) spectroscopy indicated that chromium is predominantly in the trivalent oxidation state, confirming that reductive processes are responsible for Cr sequestration. XANES spectra and microscopy results suggest that Cr is, in part, associated with iron sulfide grains formed as a consequence of microbially mediated sulfate reduction in and around the PRB. Results of this study provide evidence that secondary iron-bearing mineral products may enhance the capacity of zerovalent iron systems to remediate Cr in groundwater, either through redox reactions at the mineral-water interface or by the release of Fe(II) to solution via mineral dissolution and/or metal corrosion.

  15. Feasibility study of a self-remediation system for mine drainage using its thermal energy

    NASA Astrophysics Data System (ADS)

    Oh, Chamteut; Cheong, Youngwook; Yim, Giljae; Ji, Sangwoo

    2016-04-01

    Mine drainage is defined as the water which is discharged to the ground surface through shafts and/or cracks formed by mining activities. Typically, mine drainage features high concentration of acidity and metals since it passes through the underground. Therefore, for the purpose of protecting the surrounding natural environment, mine drainage should be remediated before being discharged to nature. Mine drainage, due to its nature of being retained underground, shows constant temperature which is independent from the temperature of the atmosphere above ground. This condition allows mine drainage to become a promising renewable energy source since energy can be recovered from water with constant temperature. In this research, a self-remediation system is proposed which remediates the mine drainage through electrochemical reactions powered by the thermal energy of mine drainage. High energy efficiency is able to be achieved by shortening the distance between the energy source and consumption, and therefore, this system has a strong advantage to be actualized. A feasibility study for the system was conducted in this research where the thermal energy of mine drainage over time and depth was calculated as energy supply and the required electrical energy for remediating the mine drainage was measured as energy consumption. While the technology of converting thermal energy directly into electrical energy is yet to be developed, energy balance analysis results showed that the proposed self-remediation system is theoretically possible.

  16. Effect of soil organic matter on antimony bioavailability after the remediation process.

    PubMed

    Nakamaru, Yasuo Mitsui; Martín Peinado, Francisco José

    2017-09-01

    We evaluated the long-term (18 year) and short-term (4 weeks) changes of Sb in contaminated soil with SOM increase under remediation process. In the Aznalcóllar mine accident (1998) contaminated area, the remediation measurement implemented the Guadiamar Green Corridor, where residual pollution is still detected. Soils of the re-vegetated area (O2) with high pH and high SOM content, moderately re-vegetated area (O1) and unvegetated area (C) were sampled. Soil pH, CEC, SOM amount and soil Sb forms were evaluated. Soil Sb was measured as total, soluble, exchangeable, EDTA extractable, acid oxalate extractable, and pyro-phosphate extractable fractions. Further, the short-term effect of artificial organic matter addition was also evaluated with incubation study by adding compost to the sampled soil from C, O1 and O2 areas. After 4 weeks of incubation, soil chemical properties and Sb forms were evaluated. In re-vegetated area (O2), soil total Sb was two times lower than in unvegetated area (C); however, soluble, exchangeable, and EDTA extractable Sb were 2-8 times higher. The mobile/bioavailable Sb increase was also observed after 4 weeks of incubation with the addition of compost. Soluble, exchangeable, and EDTA extractable Sb was increased 2-4 times by compost addition. By the linear regression analysis, the significantly related factors for soluble, exchangeable, and EDTA extractable Sb values were pH, CEC, and SOM, respectively. Soluble Sb increase was mainly related to pH rise. Exchangeable Sb should be bound by SOM-metal complex and increased with CEC. EDTA extractable fraction should be increased with increase of SOM as SOM-Fe associated Sb complex. From these results, it was shown that increase of SOM under natural conditions or application of organic amendment under remediation process should increase availability of Sb to plants. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. 29 CFR 1602.43 - Commission's remedy for school systems' or districts' failure to file report.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...' failure to file report. Any school system or district failing or refusing to file report EEO-5 when... 29 Labor 4 2010-07-01 2010-07-01 false Commission's remedy for school systems' or districts' failure to file report. 1602.43 Section 1602.43 Labor Regulations Relating to Labor (Continued)...

  18. 29 CFR 1602.43 - Commission's remedy for school systems' or districts' failure to file report.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Elementary-Secondary Staff Information Report § 1602.43 Commission's remedy for school systems' or districts' failure to file report. Any school system or district failing or refusing to file report EEO-5 when...' failure to file report. 1602.43 Section 1602.43 Labor Regulations Relating to Labor (Continued) EQUAL...

  19. 29 CFR 1602.43 - Commission's remedy for school systems' or districts' failure to file report.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Elementary-Secondary Staff Information Report § 1602.43 Commission's remedy for school systems' or districts' failure to file report. Any school system or district failing or refusing to file report EEO-5 when...' failure to file report. 1602.43 Section 1602.43 Labor Regulations Relating to Labor (Continued) EQUAL...

  20. A Cercla-Based Decision Support System for Environmental Remediation Strategy Selection.

    DTIC Science & Technology

    1997-03-01

    A CERCLA -BASED DECISION SUPPORT SYSTEM FOR ENVIRONMENTAL REMEDIATION STRATEGY SELECTION 2Lt Brian J. Grelk AFIT/GORI97M- 10 DEPARTMENT OF THE AIR...FORCE AIR UNIVERSITY AIR FORCE INSTITUTE OF TECHNOLOGY Wright-Patterson Air Force Base, Ohio vimC ’QEjA BP3f AFIT/GOR/ENS/97M- 10 A CERCLA -BASED DECISION...unlimited MC QULM TnpEOM1 AFIT/GOR/ENS/97M- 10 A CERCLA -BASED DECISION SUPPORT SYSTEM FOR ENVIRONMENTAL REMEDIATION STRATEGY SELECTION THESIS Presented to

  1. Enhanced soil washing process for the remediation of PBDEs/Pb/Cd-contaminated electronic waste site with carboxymethyl chitosan in a sunflower oil-water solvent system and microbial augmentation.

    PubMed

    Ye, Mao; Sun, Mingming; Wan, Jinzhong; Fang, Guodong; Li, Huixin; Hu, Feng; Jiang, Xin; Kengara, Fredrick Orori

    2015-02-01

    An innovative ex situ soil washing technology was developed to remediate polybrominated diphenyl ethers (PBDEs) and heavy metals in an electronic waste site. Elevated temperature (50 °C) in combination with ultrasonication (40 kHz, 20 min) at 5.0 mL L(-1) sunflower oil and 2.5 g L(-1) carboxymethyl chitosan were found to be effective in extracting mixed pollutants from soil. After two successive washing cycles, the removal efficiency rates for total PBDEs, BDE28, BDE47, BDE209, Pb, and Cd were approximately 94.1, 93.4, 94.3, 99.1, 89.3, and 92.7 %, respectively. Treating the second washed soil with PBDE-degrading bacteria (Rhodococcus sp. strain RHA1) inoculation and nutrient addition for 3 months led to maximum biodegradation rates of 37.3, 52.6, 23.9, and 1.3 % of the remaining total PBDEs, BDE28, BDE47, BDE209, respectively. After the combined treatment, the microbiological functions of washed soil was partially restored, as indicated by a significant increase in the counts, biomass C, N, and functioning diversity of soil microorganisms (p < 0.05), and the residual PBDEs and heavy metals mainly existed as very slow desorbing fractions and residual fractions, as evaluated by Tenax extraction combined with a first-three-compartment model and sequential extraction with metal stability indices (I R and U ts). Additionally, the secondary environmental risk of mixed contaminants in the remediated soil was limited. Therefore, the proposed combined cleanup strategy is an environment-friendly technology that is important for risk assessment and management in mixed-contaminated sites.

  2. Fractionation and bioavailability of Cu in soil remediated by EDTA leaching and processed by earthworms (Lumbricus terrestris L.).

    PubMed

    Udovic, Metka; Lestan, Domen

    2010-03-01

    Soil remediation with ethylenediamine tetraacetic acid (EDTA) leaching is capable of removing only part of the total metal concentration in the soil, mostly the labile, bioavailable metal species (metal bioavailability stripping). However, reintroduction of remediated soil in the environment exposes the soil to various environmental factors, which could potentially shift nonlabile residual metals back to labile bioavailable forms. We studied the effect of autochthonous earthworm species as model biotic environmental factor on the fractionation and bioavailability of Cu residual in soil after remediation. We used soil from a 50-year-old vineyard regularly managed and treated with CuSO(4)*5H(2)O (Bordeaux mixture) as fungicide. Soil containing 400 mg kg(-1) of Cu was leached with total 15 mmol kg(-1) EDTA. Remediated and nonremediated soil was processed by fully clitellated adult specimens of Lumbricus terrestris L., a prevailing autochthonous soil earthworm species. Cu fractionation, phytoavailability, and oral-bioavailability in processed and nonprocessed soil were determined using six-step sequential extraction, extraction with diethylenediamine pentaacetic acid, and in vitro physiologically based extraction test, respectively. EDTA leaching removed 41% of the pseudototal Cu, mostly from the soil Fe- and Mn-oxides, carbonates, and organic matter. A 2.7-fold decrease in Cu phytoavailability and a 4.4- and 2.8-fold decrease in Cu oral-bioavailability in the stomach and small intestine fractions, respectively, were achieved after remediation. In nonremediated soil, earthworms increased the share of nonlabile Cu in residual soil fraction, while in remediated soil they increased the share of Cu bound to carbonates. A statistically significant 1.1- and 1.7-fold increase in Cu phytoavailability and intestinal oral-bioavailability, respectively, was observed in earthworm processed remediated soil. Cu occurs in various soil "pools" of different solubilities with different

  3. FIELD TESTING OF THE TABORR (TANK BOTTOM RECOVERY AND REMEDIATION) PROCESS USING THE ASPHALT AND DRY BOTTOMS CONFIGURATIONS

    SciTech Connect

    Robert M. Satchwell; Vijay K. Sethi; Lyle A. Johnson, Jr.; Lee E. Brecher

    1997-04-01

    The TaBoRR{reg_sign} (Tank Bottom Recovery and Remediation) process being developed at Western Research Institute (WRI) offers an alternative to current disposal methods. The TaBoRR process is designed to: (1) process these wastes, (2) provide a cost saving, and (3) limit or reduce the environmental liability of the producers. This process removes the water through evaporation, eliminating water disposal costs, creates a salable crude oil that has been valued at or above the current market price for sweet West-Texas intermediate crude, and reduces the solids to a benign state for disposal at a landfill. This report presents the background information associated with this program, a detailed description of the process, and the work that has been completed during the first year of this program. The plant assembly, unit operations, product analyses of the materials created during operations, the pyrolyzer design, and permitting of the process in Wyoming are described. Also discussed in the report is the future work required to take this process to commercialization. Future work discussed includes shakedown and operation of the pyrolyzer, control systems and plant automation, integrated operations, equipment reliability, effluent sample analysis, and long-term testing of the process.

  4. Dynamic least-cost optimisation of wastewater system remedial works requirements.

    PubMed

    Vojinovic, Z; Solomatine, D; Price, R K

    2006-01-01

    In recent years, there has been increasing concern for wastewater system failure and identification of optimal set of remedial works requirements. So far, several methodologies have been developed and applied in asset management activities by various water companies worldwide, but often with limited success. In order to fill the gap, there are several research projects that have been undertaken in exploring various algorithms to optimise remedial works requirements, but mostly for drinking water supply systems, and very limited work has been carried out for the wastewater assets. Some of the major deficiencies of commonly used methods can be found in either one or more of the following aspects: inadequate representation of systems complexity, incorporation of a dynamic model into the decision-making loop, the choice of an appropriate optimisation technique and experience in applying that technique. This paper is oriented towards resolving these issues and discusses a new approach for the optimisation of wastewater systems remedial works requirements. It is proposed that the optimal problem search is performed by a global optimisation tool (with various random search algorithms) and the system performance is simulated by the hydrodynamic pipe network model. The work on assembling all required elements and the development of an appropriate interface protocols between the two tools, aimed to decode the potential remedial solutions into the pipe network model and to calculate the corresponding scenario costs, is currently underway.

  5. Finding of No Significant Impact, proposed remediation of the Maybell Uranium Mill Processing Site, Maybell, Colorado

    SciTech Connect

    Not Available

    1995-12-31

    The U.S. Department of Energy (DOE) has prepared an environmental assessment (EA) (DOE/EA-0347) on the proposed surface remediation of the Maybell uranium mill processing site in Moffat County, Colorado. The mill site contains radioactively contaminated materials from processing uranium ore that would be stabilized in place at the existing tailings pile location. Based on the analysis in the EA, DOE has determined that the proposed action does not constitute a major federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969, Public Law 91-190 (42 U.S.C. {section}4321 et seq.), as amended. Therefore, preparation of an environmental impact statement is not required and DOE is issuing this Finding of No Significant Impact (FONSI).

  6. Cavitational hydrothermal oxidation: A new remediation process. 1998 annual progress report

    SciTech Connect

    Suslick, K.S.

    1998-06-01

    'The primary goal is to develop a quantitative understanding of cavitation phenomena in aqueous media and the development of applications of cavitation to remediation processes. Efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions. This report summarizes work after one year of a three year project. In order to gain further understanding of the conditions present during cavitation, the author has continued his studies of sonoluminescence. He has made recent breakthroughs in the use of emission spectroscopy for temperature and pressure measurement of cavitation events, which he expects to publish shortly. He has been able to measure for the first time the temperature of cavitation in water during multi-bubble cavitation in the presence of aromatic hydrocarbons. The emission from excited states of C{sub 2} in water gives temperatures that are consistent with adiabatic compressional heating, with maximum temperatures of 4,300 K. Prior measurements of cavitation temperatures in low vapor pressure nonaqueous media gave somewhat higher temperatures of 5,000 K. This work lays permanently to rest exotic mechanisms for cavitational chemistry, at least for cavitation fields.'

  7. Cavitational hydrothermal oxidation: A new remediation process. Annual progress report, September 1996--August 1997

    SciTech Connect

    Suslick, K.S.

    1997-11-21

    'During the past year, the authors have continued to make substantial scientific progress on the understanding of cavitation phenomena in aqueous media and applications of cavitation to remediation processes. The efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions. In order to gain further understanding of the conditions present during cavitation, the author has continued his studies of sonoluminescence. He has made recent breakthroughs in the use of emission spectroscopy for temperature and pressure measurement of cavitation events, which he expects to publish shortly. He has been able to measure for the first time the temperature of cavitation in water during multi-bubble cavitation in the presence of aromatic hydrocarbons. The emission from excited states of C{sub 2} in water gives temperatures that are consistent with adiabatic compressional heating, with maximum temperatures of 4,300 K. Prior measurements of cavitation temperatures in low vapor pressure nonaqueous media gave somewhat higher temperatures of 5,000 K. This work lays permanently to rest exotic mechanisms for cavitational chemistry, at least for cavitation fields.'

  8. Metal attenuation processes in a landfill containing coal combustion waste: Implications for remediation.

    SciTech Connect

    Barton, Christopher; Paddock, Lindy; Romanek, Christopher; Maharaj, Sally; Seaman, John

    2005-03-01

    The 488-D Ash Basin (488-DAB) is an unlined, earthen landfill containing approximately 1 million t of dry ash and coal reject material at the U.S. Department of Energy’s Savannah River Site, South Carolina. The pyritic nature of the coal rejects has resulted in the formation of acidic drainage, which has contributed to groundwater deterioration and threatened biota in adjacent wetlands. Establishment of a vegetation cover to both deplete oxygen through biological means and optimize evapotranspiration has been established as a remedial alternative for reducing acidic drainage generation in the 488-DAB. To determine the potential benefits of a cover, a series of characterization studies were conducted prior to field deployment to gain a better understanding of the metal attenuation processes and to use water quality and substrate data to evaluate the potential effectiveness of this remedial approach. The characterization study indicated that metal attenuation was primarily controlled by fluctuating redox and pH gradients associated with alternating saturated and unsaturated conditions in the basin. Based on this information, a vegetative cover could reduce the production of acid leachate over time, pending that oxygen transport to the subsurface is limited.

  9. Remediation of phenanthrene-contaminated soil by simultaneous persulfate chemical oxidation and biodegradation processes.

    PubMed

    Mora, Verónica C; Madueño, Laura; Peluffo, Marina; Rosso, Janina A; Del Panno, María T; Morelli, Irma S

    2014-06-01

    Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous compounds with carcinogenic and/or mutagenic potential. To address the limitations of individual remediation techniques and to achieve better PAH removal efficiencies, the combination of chemical and biological treatments can be used. The degradation of phenanthrene (chosen as a model of PAH) by persulfate in freshly contaminated soil microcosms was studied to assess its impact on the biodegradation process and on soil properties. Soil microcosms contaminated with 140 mg/kgDRY SOIL of phenanthrene were treated with different persulfate (PS) concentrations 0.86-41.7 g/kgDRY SOIL and incubated for 28 days. Analyses of phenanthrene and persulfate concentrations and soil pH were performed. Cultivable heterotrophic bacterial count was carried out after 28 days of treatment. Genetic diversity analysis of the soil microcosm bacterial community was performed by PCR amplification of bacterial 16S rDNA fragments followed by denaturing gradient gel electrophoresis (DGGE). The addition of PS in low concentrations could be an interesting biostimulatory strategy that managed to shorten the lag phase of the phenanthrene biological elimination, without negative effects on the physicochemical and biological soil properties, improving the remediation treatment.

  10. Remedial Process Optimization and Green In-Situ Ozone Sparging for Treatment of Groundwater Impacted with Petroleum Hydrocarbons

    NASA Astrophysics Data System (ADS)

    Leu, J.

    2012-12-01

    A former natural gas processing station is impacted with TPH and BTEX in groundwater. Air sparging and soil vapor extraction (AS/AVE) remediation systems had previously been operated at the site. Currently, a groundwater extraction and treatment system is operated to remove the chemicals of concern (COC) and contain the groundwater plume from migrating offsite. A remedial process optimization (RPO) was conducted to evaluate the effectiveness of historic and current remedial activities and recommend an approach to optimize the remedial activities. The RPO concluded that both the AS/SVE system and the groundwater extraction system have reached the practical limits of COC mass removal and COC concentration reduction. The RPO recommended an in-situ chemical oxidation (ISCO) study to evaluate the best ISCO oxidant and approach. An ISCO bench test was conducted to evaluate COC removal efficiency and secondary impacts to recommend an application dosage. Ozone was selected among four oxidants based on implementability, effectiveness, safety, and media impacts. The bench test concluded that ozone demand was 8 to 12 mg ozone/mg TPH and secondary groundwater by-products of ISCO include hexavalent chromium and bromate. The pH also increased moderately during ozone sparging and the TDS increased by approximately 20% after 48 hours of ozone treatment. Prior to the ISCO pilot study, a capture zone analysis (CZA) was conducted to ensure containment of the injected oxidant within the existing groundwater extraction system. The CZA was conducted through a groundwater flow modeling using MODFLOW. The model indicated that 85%, 90%, and 95% of an injected oxidant could be captured when a well pair is injecting and extracting at 2, 5, and 10 gallons per minute, respectively. An ISCO pilot test using ozone was conducted to evaluate operation parameters for ozone delivery. The ozone sparging system consisted of an ozone generator capable of delivering 6 lbs/day ozone through two ozone

  11. Remediation of Pb/Cr co-contaminated soil using electrokinetic process and approaching electrode technique.

    PubMed

    Ng, Yee-Sern; Sen Gupta, Bhaskar; Hashim, Mohd Ali

    2016-01-01

    Electrokinetic process has emerged as an important tool for remediating heavy metal-contaminated soil. The process can concentrate heavy metals into smaller soil volume even in the absence of hydraulic flow. This makes it an attractive soil pre-treatment method before other remediation techniques are applied such that the chemical consumption in the latter stage can be reduced. The present study evaluates the feasibility of electrokinetic process in concentrating lead (Pb) and chromium (Cr) in a co-contaminated soil using different types of wetting agents, namely 0.01 M NaNO3, 0.1 M citric acid and 0.1 M EDTA. The data obtained showed that NaNO3 and citric acid resulted in poor Pb electromigration in this study. As for Cr migration, these agents were also found to give lower electromigration rate especially at low pH region as a result of Cr(VI) adsorption and possible reduction into Cr(III). In contrast, EDTA emerged as the best wetting agent in this study as it formed water-soluble anionic complexes with both Pb and Cr. This provided effective one-way electromigration towards the anode for both ions, and they were accumulated into smaller soil volume with an enrichment ratio of 1.55-1.82. A further study on the application of approaching cathode in EDTA test showed that soil alkalisation was achieved, but this did not provide significant enhancement on electromigration for Pb and Cr. Nevertheless, the power consumption for electrokinetic process was decreased by 22.5%.

  12. Innovative technology summary report: System for Tracking Remediation, Exposure, Activities and Materials

    SciTech Connect

    1998-09-01

    The System for Tracking Remediation, Exposure, Activities, and Materials (STREAM) technology is a multi-media database that consolidates project information into a single, easily-accessible place for day-to-day work performance and management tracking. Information inputs can range from procedures, reports, and references to waste generation logs and manifests to photographs and contaminant survey maps. Key features of the system are quick and easy information organization and retrieval, versatile information display options, and a variety of visual imaging methods. These elements enhance productivity and compliance and facilitate communications with project staff, clients, and regulators. Use of STREAM also gives visual access to contaminated areas, reducing the number of physical entries and promoting safety and as low as reasonably achievable (ALARA) principles. The STREAM system can be customized to focus on the information needs of a specific project, and provides a capability and work process improvement well beyond the usual collection of paperwork and independent databases. Especially when incorporated early in project planning and implemented to the fullest extent, it is a systematic and cost-effective tool for controlling and using project information. The STREAM system can support up to 50 different work stations. This report covers the period February through October 1997, when the STREAM software program, owned by Delphinus Engineering, was demonstrated at the Hanford Site`s Reactor Interim Safe Storage (ISS) Project.

  13. REDUCED PERMEABILITY IN GROUNDWATER REMEDIATION SYSTEMS: ROLE OF MOBILIZED COLLOIDS AND INJECTED CHEMICALS

    EPA Science Inventory

    The success of pump-and-treat or in situ remediation of contaminated aquifers depends in part on the ability to maintain the permeability of the aquifer, withdrawal wells, and delivery systems at a reasonable cost while moving significant quantities of water. We have considered o...

  14. REDUCED PERMEABILITY IN GROUNDWATER REMEDIATION SYSTEMS: ROLE OF MOBILIZED COLLOIDS AND INJECTED CHEMICALS

    EPA Science Inventory

    The success of pump-and-treat or in situ remediation of contaminated aquifers depends in part on the ability to maintain the permeability of the aquifer, withdrawal wells, and delivery systems at a reasonable cost while moving significant quantities of water. We have considered o...

  15. Tank 241-SY-101 surface level rise remediation test and evaluation plan for transfer system

    SciTech Connect

    BAUER, R.E.

    1999-07-14

    The purpose of this testing and evaluation plan (TEP) is to provide the high level guidance on testing requirements for ensuring that the equipment and systems to be implemented for remediation of the SY-101 waste level rise USQ are effective.

  16. Bases for solid waste volume estimates for tank waste remediation system

    SciTech Connect

    Reddick, G.W., Westinghouse Hanford

    1996-08-01

    This document presents the background and basis for the Tank Waste Remediation System forecast for solid waste submitted in June 1996. The forecast was generated for single-shell tank and double-shell tank activities including operations through retrieval and disposal of chemical tank waste.

  17. Hanford Site Tank Waste Remediation System. Waste management 1993 symposium papers and viewgraphs

    SciTech Connect

    Not Available

    1993-05-01

    The US Department of Energy`s (DOE) Hanford Site in southeastern Washington State has the most diverse and largest amount of highly radioactive waste of any site in the US. High-level radioactive waste has been stored in large underground tanks since 1944. A Tank Waste Remediation System Program has been established within the DOE to safely manage and immobilize these wastes in anticipation of permanent disposal in a geologic repository. The Hanford Site Tank Waste Remediation System Waste Management 1993 Symposium Papers and Viewgraphs covered the following topics: Hanford Site Tank Waste Remediation System Overview; Tank Waste Retrieval Issues and Options for their Resolution; Tank Waste Pretreatment - Issues, Alternatives and Strategies for Resolution; Low-Level Waste Disposal - Grout Issue and Alternative Waste Form Technology; A Strategy for Resolving High-Priority Hanford Site Radioactive Waste Storage Tank Safety Issues; Tank Waste Chemistry - A New Understanding of Waste Aging; Recent Results from Characterization of Ferrocyanide Wastes at the Hanford Site; Resolving the Safety Issue for Radioactive Waste Tanks with High Organic Content; Technology to Support Hanford Site Tank Waste Remediation System Objectives.

  18. Application of a constructed wetland system for polluted stream remediation

    NASA Astrophysics Data System (ADS)

    Tu, Y. T.; Chiang, P. C.; Yang, J.; Chen, S. H.; Kao, C. M.

    2014-03-01

    In 2010, the multi-function Kaoping River Rail Bridge Constructed Wetland (KRRBW) was constructed to improve the stream water quality and rehabilitate the ecosystem of the surrounding environment of Dashu Region, Kaohsiung, Taiwan. The KRRBW consists of five wetland basins with a total water surface area of 15 ha, a total hydraulic retention time (HRT) of 10.1 days at a averaged flow rate of 14 740 m3/day, and an averaged water depth of 1.1 m. The influent of KRRBW coming from the local drainage systems containing untreated domestic, agricultural, and industrial wastewaters. Based on the quarterly investigation results of water samples taken in 2011-2012, the overall removal efficiencies were 91% for biochemical oxygen demand (BOD), 75% for total nitrogen (TN), 96% for total phosphorus (TP), and 99% for total coliforms (TC). The calculated first-order decay rates for BOD, TN, TP, NH3-N, and TC ranged from 0.14 (TN) to 0.42 (TC) 1/day. This indicates that the KRRBW was able to remove organics, TC, and nutrients effectively. The high ammonia/nitrate removal efficiency indicates that nitrification and denitrification processes occurred simultaneously in the wetland system, and the detected nitrite concentration confirmed the occurrence of denitrification/nitrification. Results from sediment analyses reveal that the sediment contained high concentrations of organics (sediment oxygen demand = 1.9-5.2 g O2/m2 day), nutrients (up to 15.8 g total nitrogen/kg of sediment and 1.48 g total phosphorus/kg of sediment), and metals (up to 547 mg/kg of Zn and 97 mg/kg of Cu). Appropriate wetland management strategies need to be developed to prevent the release of contaminants into the wetland system. The wetland system caused the variations in the microbial diversities and dominant microbial bacteria. Results show the dominant nitrogen utilization bacteria including Denitratisoma oestradiolicum, Nitrosospira sp., Nitrosovibrio sp., D. oestradiolicum, Alcaligenes sp

  19. Improving the two-step remediation process for CCA-treated wood. Part I, Evaluating oxalic acid extraction

    Treesearch

    Carol Clausen

    2004-01-01

    In this study, three possible improvements to a remediation process for chromated-copper-arsenate (CCA) treated wood were evaluated. The process involves two steps: oxalic acid extraction of wood fiber followed by bacterial culture with Bacillus licheniformis CC01. The three potential improvements to the oxalic acid extraction step were (1) reusing oxalic acid for...

  20. 78 FR 21352 - Update on Reimbursement for Costs of Remedial Action at Active Uranium and Thorium Processing Sites

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-10

    ... will be provided from the Uranium Enrichment Decontamination and Decommissioning Fund established at... on Reimbursement for Costs of Remedial Action at Active Uranium and Thorium Processing Sites AGENCY... reimbursement for cleanup work performed by licensees at eligible uranium and thorium processing sites in...

  1. Mobility Controlled Flooding (MCF) Technology for Enhanced Sweeping and NAPL Remediation in Heterogeneous Systems

    NASA Astrophysics Data System (ADS)

    Zhong, L.; Oostrom, M.; Wietsma, T.

    2005-12-01

    Heterogeneity is often encountered in subsurface contamination characterization and remediation. Low-permeability zones are bypassed when remedial fluid is injected into heterogeneous systems. The contaminant in the bypassed areas is therefore untouched by the remedial fluid, which can prolong the remediation operations significantly. Methods of forcing fluids into low-permeability flow paths have been developed and widely implemented to solve the heterogeneity-induced bypassing problem encountered during oil recovery in the petroleum industry over the past 40 years. Since the intent of the petroleum reservoir engineers is to control the mobility of the injected fluid in the high-permeable zones so that the fluid can be pushed through the low-permeable zones to contact and mobilize the remaining oil in these zones, this method are referred as mobility controlled flooding (MCF) technology in the petroleum engineering literature. Two methods of mobility control have been developed. One method is to use a water-soluble polymer to increase the viscosity of the injectate so that the in situ pore pressure is raised, and cross-flow between layers with different permeability occurs. The other method is to use surfactant-foam flood to generate foam in high permeable zones in situ; therefore, the injected fluid is forced into the low-permeable areas. A water-soluble polymer, xanthan gum, and surfactant MA-80 was used to formulate MCF remedial fluids to remediate nonaqueous phase liquid (NAPL) contaminated heterogonous systems in two-dimensional (2-D) flow-cell (40 by 50 by 5 cm) experiments. It was demonstrated that the MCF technology is capable of sweeping the low-permeability flow paths. The bypassing of low-permeable zones was significantly reduced. The removal of NAPL trapped in the low-perm zones was remarkable enhanced attributed to more efficient NAPL mobilization. The results also indicate that the MCF technology is able to manage the fluid density effects. The

  2. Best Practices for Fuel System Contamination Detection and Remediation

    DTIC Science & Technology

    2015-12-14

    Task 4: Contact coating manufactures for material composition and application process . ........ 7 Task 5: Analyze additional fuel and water-bottom...and alloy composition. Task 4: Contact coating manufactures for material composition and application process . Authorized coatings for fuel storage...Area fuel laboratories and contract laboratories occupy a central position in the process of contaminant investigations. Occasionally their analysis

  3. The large-scale process of microbial carbonate precipitation for nickel remediation from an industrial soil.

    PubMed

    Zhu, Xuejiao; Li, Weila; Zhan, Lu; Huang, Minsheng; Zhang, Qiuzhuo; Achal, Varenyam

    2016-12-01

    Microbial carbonate precipitation is known as an efficient process for the remediation of heavy metals from contaminated soils. In the present study, a urease positive bacterial isolate, identified as Bacillus cereus NS4 through 16S rDNA sequencing, was utilized on a large scale to remove nickel from industrial soil contaminated by the battery industry. The soil was highly contaminated with an initial total nickel concentration of approximately 900 mg kg(-1). The soluble-exchangeable fraction was reduced to 38 mg kg(-1) after treatment. The primary objective of metal stabilization was achieved by reducing the bioavailability through immobilizing the nickel in the urease-driven carbonate precipitation. The nickel removal in the soils contributed to the transformation of nickel from mobile species into stable biominerals identified as calcite, vaterite, aragonite and nickelous carbonate when analyzed under XRD. It was proven that during precipitation of calcite, Ni(2+) with an ion radius close to Ca(2+) was incorporated into the CaCO3 crystal. The biominerals were also characterized by using SEM-EDS to observe the crystal shape and Raman-FTIR spectroscopy to predict responsible bonding during bioremediation with respect to Ni immobilization. The electronic structure and chemical-state information of the detected elements during MICP bioremediation process was studied by XPS. This is the first study in which microbial carbonate precipitation was used for the large-scale remediation of metal-contaminated industrial soil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. Tank waste remediation system operation and utilization plan,vol. I {ampersand} II

    SciTech Connect

    Kirkbride, R.A.

    1997-09-01

    The U.S. Department of Energy Richland Operations Office (RL) is in the first stages of contracting with private companies for the treatment and immobilization of tank wastes. The components of tank waste retrieval, treatment, and immobilization have been conceived in two phases (Figure 1.0-1). To meet RL's anticipated contractual requirements, the Project Hanford Management Contractor (PHMC) companies will be required to provide waste feeds to the private companies consistent with waste envelopes that define the feeds in terms of quantity, and concentration of both chemicals and radionuclides. The planning that supports delivery of the feed must be well thought out in four basic areas: (1) Low-activity waste (LAW)/high-level waste (HLW) feed staging plans. How is waste moved within the existing tanks to deliver waste that corresponds to the defined feed envelopes to support the Private Contractor's processing schedule and processing rate? (2) Single-shell tank (SST) retrieval sequence. How are Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) (Ecology et al. 1994) milestones for SST retrieval integrated into the Phase I processing to set the stage for Phase II processing to complete the mission? (3) Tank Waste Remediation System (TWRS) process flowsheet. How do materials flow from existing tank inventories through: (1) blending and pretreatment functions in the double-shell tanks (DSTs), (2) contractor processing facilities, and (3) stored waste forms (Figure 1.0-2); (4) Storage and disposal of the immobilized low-activity waste (ILAW) and immobilized high-level waste (IHLW) product. How is the ILAW and IHLW product received from the private companies, the ILAW disposed onsite, and the IHLW stored onsite until final disposal?

  5. Remediation System Evaluation, Delphi Corporation Site in Vandalia, Ohio

    EPA Pesticide Factsheets

    This RSE pertains to aspects of the corrective action underway at two neighboring plants, the Delphi Energy and Chassis Systems Plant and Delphi Safety and Interior Systems Plant, collectively referred to as the “facility” in this report.

  6. Public values related to decisions in the Tank Waste Remediation System Program

    SciTech Connect

    Armacost, L.L.; Robershotte, M.; von Winterfeldt, D.; Creighton, J.

    1994-10-01

    Managers of the Tank Waste Remediation System (TWRS) Program have to make numerous decisions, ranging from the strategic decisions on the fundamental tank cleanup goals to technical decisions on which types of equipment to use in mechanical retrieval of wastes. Furthermore, many of these decisions have to be made repeatedly (e.g., the annual allocation of research and development funds to TWRS activities). These decisions have many potential consequences in terms of risks to workers, risks to the public, environmental impacts, and economic development and cost. Because these consequences affect the values of many parties, the consequences need to be evaluated in terms that are accepted and understood by the interested parties. Therefore, an effort needs to be made to incorporate public concerns and values into the TWRS decision-making process. The purpose of this report is to review and integrate this past work on values and to create a maser list of values in order to create a consistent value framework for the numerous TWRS decisions; efficiently and effectively use public values in the decision-making process by updating this report on a regular basis to ensure that the information represents the public`s current views; provide guidance about using values in technical TWRS decisions.

  7. Tank waste remediation system characterization project quality policies

    SciTech Connect

    Board, D.C.

    1997-09-24

    This quality plan describes the system used by Characterization Project management to achieve quality. This plan is comprised of eleven quality policies which, when taken together, form a management system deployed to achieve quality. This quality management system is based on the customer`s quality requirements known as the `RULE`, 10 CFR 830.120, Quality Assurance.

  8. Tank waste remediation system characterization project quality policies

    SciTech Connect

    Trible, T.C., Westinghouse Hanford

    1996-07-31

    This quality plan describes the system used by Characterization Project management to achieve quality. This plan is comprised on eleven quality policies which, when taken together, form a management system deployed to achieve quality. This quality management system is based on the customer`s quality requirements known as the `RULE`, 10 CFR 830.120, Quality Assurance.

  9. Dopingless impact ionization MOS (DL-IMOS)—a remedy for complex process flow

    NASA Astrophysics Data System (ADS)

    Singh, Sangeeta; Kondekar, P. N.

    2015-07-01

    We propose a unique approach for realizing dopingless impact ionization MOS (DL-IMOS) based on the charge plasma concept as a remedy for complex process flow. It uses work-function engineering of electrodes to form charge plasma as surrogate doping. This charge plasma induces a uniform p-region in the source side and an n-region in the drain side on intrinsic silicon film with a thickness less than the intrinsic Debye length. DL-IMOS offers a simple fabrication process flow as it avoids the need of ion implantation, photo masking and complicated thermal budget via annealing devices. The lower thermal budget is required for DL-IMOS fabrication enables its fabrication on single crystal silicon-on-glass substrate realized by wafer scale epitaxial transfer. It is highly immune to process variations, doping control issues and random dopant fluctuations, while retaining the inherent advantages of conventional IMOS. To epitomize the fabrication process flow for the proposed device a virtual fabrication flow is also proposed here. Extensive device simulation of the major device performance metrics such as subthreshold slope, threshold voltage, drain induced current enhancement, and breakdown voltage have been done for a wide range of electrodes work-function. To evaluate the potential applications of the proposed device at circuit level, its mixed mode simulations are also carried out.

  10. Improving the two-step remediation process for CCA-treated wood. Part II, Evaluating bacterial nutrient sources

    Treesearch

    Carol A. Clausen

    2004-01-01

    Remediation processes for recovery and reuse of chromated-copper-arsenate-(CCA) treated wood are not gaining wide acceptance because they are more expensive than landfill disposal. One reason is the high cost of the nutrient medium used to culture the metal tolerant bacterium, Bacillus licheniformis, which removes 70-100% of the copper, chromium, and arsenic from CCA-...

  11. March 2016 Memo: Planning for Removal and Remedial Activities at Hardrock Mining and Mineral Processing Sites with Fluid Hazards

    EPA Pesticide Factsheets

    Memo from EPA Assistant Administrator Mathy Stanislaus, regarding planning for removal and remedial activities at hardrock mining and mineral processing sites with fluid hazards, and to share the Agency’s expectations for the work that is done at these sit

  12. Behavior of dioxin during thermal remediation in the zone combustion process.

    PubMed

    Harjanto, Sri; Kasai, Eiki; Terui, Toshikatsu; Nakamura, Takashi

    2002-05-01

    In the previous study, a new process concept for the thermal remediation of particulate/powder materials contaminated by polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) has been verified. It leads to removal efficiencies of more than 99.9% in the soil contaminated by PCDD/Fs in terms of toxicity equivalent quantity (TEQ). However, details of the reactions and phenomena during the process, i.e., decomposition, vaporization, reformation and trap of PCDD/Fs and their relating compounds, have not sufficiently been clarified yet. The present study aims to examine experimentally the transport and fate of PCDD/Fs in the process. In the experiment, a laboratory-scale process simulator and a soil sample preliminary mixed with octachlorinated dibenzo-p-dioxin spiked by carbon-13 isotope (13C-OCDD) were used. The distribution of 13C-OCDD in the soil bed during the process was measured by applying a quench technique that rapidly cools-down the bed. Further, the total amount of 13C-OCDD discharged with outlet gas was measured. Using the obtained data, mass balance of 13C-OCDD in the process was estimated. The results show that about 99% of 13C-OCDD preliminary admixed with the soil was decomposed rather than released to the outlet gas. Only a trace amount of 13C-OCDD remained in the treated soil. In addition, a very small amount of other congeners having the 13C-cycles was detected in the treated soil and outlet gas although its TEQ values are not significant. These were probably formed by dechlorination reactions occurring in the process.

  13. Toxic remediation

    DOEpatents

    Matthews, Stephen M.; Schonberg, Russell G.; Fadness, David R.

    1994-01-01

    What is disclosed is a novel toxic waste remediation system designed to provide on-site destruction of a wide variety of hazardous organic volatile hydrocarbons, including but not limited to halogenated and aromatic hydrocarbons in the vapor phase. This invention utilizes a detoxification plenum and radiation treatment which transforms hazardous organic compounds into non-hazardous substances.

  14. Necessary and Sufficient Standards Closure Process pilot: F- and H-Area groundwater remediation

    SciTech Connect

    Bullington, M.

    1995-09-25

    The DOE Standards Committee`s Necessary and Sufficient (N and S) Standards Closure Process was piloted at SRS on the F- and H- Area Seepage Basins Groundwater Remediation Project. For this existing Environmental Restoration project, the set of N and S standards for design and safety documentation were identified, independently confirmed and approved. Implementation of these standards on the project can lead to a $2.8 Million cost savings on the design, construction/installation, and safety documentation scope of $18 Million. These savings were primarily from site design of power distribution and piping for the water treatment units. Also contributing to the savings were a more appropriate level of safety documentation and the alternate ``commercial`` bids made by vendors in response to a request for proposals for water treatment units. The use of the N and S Process on an ER activity, details on the cost savings, lessons learned and recommendations for broader implementation of the N and S Process are described herein.

  15. Tank waste remediation system vadose zone program plan

    SciTech Connect

    Fredenburg, E.A.

    1998-07-27

    The objective of the vadose zone characterization under this program is to develop a better conceptual geohydrologic model of identified tank farms which will be characterized so that threats to human health and the environment from past leaks and spills, intentional liquid discharges, potential future leaks during retrieval, and from residual contaminants that may remain in tank farms at closure can be explicitly addressed in decision processes. This model will include geologic, hydrologic, and hydrochemical parameters as defined by the requirements of each of the TWRS programs identified here. The intent of this TWRS Vadose Zone Program Plan is to provide justification and an implementation plan for the following activities: Develop a sufficient understanding of subsurface conditions and transport processes to support decisions on management, cleanup, and containment of past leaks, spills, and intentional liquid discharges; Develop a sufficient understanding of transport processes to support decisions on controlling potential retrieval leaks; Develop a sufficient understanding of transport processes to support decisions on tank farm closure, including allowable residual waste that may remain at closure; and Provide new information on geotechnical properties in the 200 Area to supplement data used for design and performance assessment for immobilized low-activity waste disposal facilities.

  16. Advanced fuel hydrocarbon remediation national test location - in situ air sparging system (revised)

    SciTech Connect

    Health, J.; Lory, E.

    1997-03-01

    Air sparging is the process of injecting clean air directly into an aquifer for remediation of contaminated groundwater. For removing contaminants, air sparging relies on two basic mechanisms working either alone or in tandem: biodegradation and volatilization. The objective of air sparging is to force air through contaminated aquifer materials to provide oxygen for bioremediation and/or to strip contaminants out of the aquifer.

  17. Biogeochemistry of the compost bioreactor components of a composite acid mine drainage passive remediation system.

    PubMed

    Johnson, D Barrie; Hallberg, Kevin B

    2005-02-01

    The compost bioreactor ("anaerobic cell") components of three composite passive remediation systems constructed to treat acid mine drainage (AMD) at the former Wheal Jane tin mine, Cornwall, UK were studied over a period of 16 months. While there was some amelioration of the preprocessed AMD in each of the three compost bioreactors, as evidenced by pH increase and decrease in metal concentrations, only one of the cells showed effective removal of the two dominant heavy metals (iron and zinc) present. With two of the compost bioreactors, concentrations of soluble (ferrous) iron draining the cells were significantly greater than those entering the reactors, indicating that there was net mobilisation (by reductive dissolution) of colloidal and/or solid-phase ferric iron compounds within the cells. Soluble sulfide was also detected in waters draining all three compost bioreactors which was rapidly oxidised, in contrast to ferrous iron. Oxidation and hydrolysis of iron, together with sulfide oxidation, resulted in reacidification of processed AMD downstream of the compost bioreactors in two of the passive treatment systems. The dominant cultivatable microorganism in waters draining the compost bioreactors was identified, via analysis of its 16S rRNA gene, as a Thiomonas sp. and was capable of accelerating the dissimilatory oxidation of both ferrous iron and reduced sulfur compounds. Sulfate-reducing bacteria (SRB) were also detected, although only in the bioreactor that was performing well were these present in significant numbers. This particular compost bioreactor had been shut down for 10 months prior to the monitoring period due to operational problems. This unforeseen event appears to have allowed more successful development of AMD-tolerant and other microbial populations with critical roles in AMD bioremediation, including neutrophilic SRB (nSRB), in this compost bioreactor than in the other two, where the throughput of AMD was not interrupted. This study has

  18. The Dnieper River Aquatic System Radioactive Contamination; Long-tern Natural Attenuation And Remediation History

    NASA Astrophysics Data System (ADS)

    Voitsekhovych, Oleg; Laptev, Genadiy; Kanivets, Vladimir; Konoplev, Alexey

    2013-04-01

    Near 27 year passed after the Chernobyl Accident, and the experience gained to study radionuclide behavior in the aquatic systems and to mitigate water contamination are still pose of interest for scientists, society and regulatory austerities. There are different aspects of radionuclide transport in the environment were studied since the Chernobyl fallout in 1986 covered the river catchments, wetlands, river, lakes/reservoirs and reached the Black Sea. The monitoring time series data set and also data on the radionuclides behavior studies in the water bodies (river, lakes and the Black Sea) are available now in Ukraine and other affected countries. Its causation analyses, considering the main geochemical, physical and chemical and hydrological process, governing by radionuclide mobility and transport on the way from the initially contaminated catchments, through the river-reservoir hydrological system to the Black Sea can help in better understanding of the main factors governing be the radionuclide behavior in the environment. Radionuclide washout and its hydrological transport are determined speciation of radionuclides as well as soil types and hydrological mode and also geochemistry and landscape conditions at the affected areas. Mobility and bioavailability of radionuclides are determined by ratio of radionuclide chemical forms in fallout and site-specific environmental characteristics determining rates of leaching, fixation/remobilization as well as sorption-desorption of mobile fraction (its solid-liquid distribution). In many cases the natural attenuation processes governing by the above mentioned processes supported by water flow transportation and sedimentation played the key role in self-rehabilitation of the aquatic ecosystems. The models developed during post-Chernobyl decade and process parameters studies can help in monitoring and remediation programs planed for Fukusima Daichi affected watersheds areas as well. Some most important monitoring data

  19. Test processing system (SEE)

    NASA Technical Reports Server (NTRS)

    Gaulene, P.

    1986-01-01

    The SEE data processing system, developed in 1985, manages and process test results. General information is provided on the SEE system: objectives, characteristics, basic principles, general organization, and operation. Full documentation is accessible by computer using the HELP SEE command.

  20. USE OF THE AERIAL MEASUREMENT SYSTEM HELICOPTER EMERGENCY RESPONSE ACQUISITION SYSTEMS WITH GEOGRAPHIC INFORMATION SYSTEM FOR RADIOACTIVE SOIL REMEDIATION - [11504

    SciTech Connect

    BROCK CT

    2011-02-15

    The Aerial Measurement System (AMS) Helicopter Emergency Response Acquisition System provides a thorough and economical means to identify and characterize the contaminants for large area radiological surveys. The helicopter system can provide a 100-percent survey of an area that qualifies as a scoping survey under the Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM) methodology. If the sensitivity is adequate when compared to the clean up values, it may also be used for the characterization survey. The data from the helicopter survey can be displayed and manipulated to provide invaluable data during remediation activities.

  1. Application of a solar UV/chlorine advanced oxidation process to oil sands process-affected water remediation.

    PubMed

    Shu, Zengquan; Li, Chao; Belosevic, Miodrag; Bolton, James R; El-Din, Mohamed Gamal

    2014-08-19

    The solar UV/chlorine process has emerged as a novel advanced oxidation process for industrial and municipal wastewaters. Currently, its practical application to oil sands process-affected water (OSPW) remediation has been studied to treat fresh OSPW retained in large tailings ponds, which can cause significant adverse environmental impacts on ground and surface waters in Northern Alberta, Canada. Degradation of naphthenic acids (NAs) and fluorophore organic compounds in OSPW was investigated. In a laboratory-scale UV/chlorine treatment, the NAs degradation was clearly structure-dependent and hydroxyl radical-based. In terms of the NAs degradation rate, the raw OSPW (pH ∼ 8.3) rates were higher than those at an alkaline condition (pH = 10). Under actual sunlight, direct solar photolysis partially degraded fluorophore organic compounds, as indicated by the qualitative synchronous fluorescence spectra (SFS) of the OSPW, but did not impact NAs degradation. The solar/chlorine process effectively removed NAs (75-84% removal) and fluorophore organic compounds in OSPW in the presence of 200 or 300 mg L(-1) OCl(-). The acute toxicity of OSPW toward Vibrio fischeri was reduced after the solar/chlorine treatment. However, the OSPW toxicity toward goldfish primary kidney macrophages after solar/chlorine treatment showed no obvious toxicity reduction versus that of untreated OSPW, which warrants further study for process optimization.

  2. Tank waste remediation system (TWRS) privatization contractor samples waste envelope D material 241-C-106

    SciTech Connect

    Esch, R.A.

    1997-04-14

    This report represents the Final Analytical Report on Tank Waste Remediation System (TWRS) Privatization Contractor Samples for Waste Envelope D. All work was conducted in accordance with ''Addendum 1 of the Letter of Instruction (LOI) for TWRS Privatization Contractor Samples Addressing Waste Envelope D Materials - Revision 0, Revision 1, and Revision 2.'' (Jones 1996, Wiemers 1996a, Wiemers 1996b) Tank 241-C-1 06 (C-106) was selected by TWRS Privatization for the Part 1A Envelope D high-level waste demonstration. Twenty bottles of Tank C-106 material were collected by Westinghouse Hanford Company using a grab sampling technique and transferred to the 325 building for processing by the Pacific Northwest National Laboratory (PNNL). At the 325 building, the contents of the twenty bottles were combined into a single Initial Composite Material. This composite was subsampled for the laboratory-scale screening test and characterization testing, and the remainder was transferred to the 324 building for bench-scale preparation of the Privatization Contractor samples.

  3. Geophysical Monitoring of Hydrocarbon-Contaminated Soils Remediated with a Bioelectrochemical System.

    PubMed

    Mao, Deqiang; Lu, Lu; Revil, André; Zuo, Yi; Hinton, John; Ren, Zhiyong Jason

    2016-08-02

    Efficient noninvasive techniques are desired for monitoring the remediation process of contaminated soils. We applied the direct current resistivity technique to image conductivity changes in sandbox experiments where two sandy and clayey soils were initially contaminated with diesel hydrocarbon. The experiments were conducted over a 230 day period. The removal of hydrocarbon was enhanced by a bioelectrochemical system (BES) and the electrical potentials of the BES reactors were also monitored during the course of the experiment. We found that the variation in electrical conductivity shown in the tomograms correlate well with diesel removal from the sandy soil, but this is not the case with the clayey soil. The clayey soil is characterized by a larger specific surface area and therefore a larger surface conductivity. In sandy soil, the removal of the diesel and products from degradation leads to an increase in electrical conductivity during the first 69 days. This is expected since diesel is electrically insulating. For both soils, the activity of BES reactors is moderately imaged by the inverted conductivity tomogram of the reactor. An increase in current production by electrochemically active bacteria activity corresponds to an increase in conductivity of the reactor.

  4. Remediation of DDTs contaminated soil in a novel Fenton-like system with zero-valent iron.

    PubMed

    Cao, Menghua; Wang, Linling; Wang, Li; Chen, Jing; Lu, Xiaohua

    2013-02-01

    Application of a novel Fenton-like system with zero-valent iron, EDTA and Air (ZVI/EDTA/Air) was investigated to degrade dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethane, and dichlorodiphenyldichloroethylene (DDE) in the actual contaminated soil from an organochlorine pesticide site. It was found DDTs in the soil were effectively degraded by the system at room temperature, ambient atmosphere pressure and near neutral pH. The dosages of EDTA and ZVI were the dominant factors influencing the removal of contaminants. An increase of EDTA from 0.05 to 0.2 mM and ZVI from 1 to 5 g L(-1) improved the removal of the contaminants significantly. However, excessive amount of EDTA led to a negative effect on the degradation process. Meanwhile, EDTA was simultaneously degraded so as to avoid the secondary pollution risk on soil remediation. Only a small amount of 4,4'-DDE and 2,2-bis(4-chlorophenyl)-1-chloroethylene (4,4'-DDMU) generated as the intermediates of DDT degradation during the process. Our investigation suggests that the Fenton-like system is a promising alternative for remediation of organochlorine pesticides contaminated soils.

  5. Remediation of chromite ore processing residue by pyrolysis process with sewage sludge.

    PubMed

    Zhang, Dalei; Kong, Hainan; Wu, Deyi; He, Shengbing; Hu, Zhanbo; Hu, Xiaofang

    2009-06-01

    The present work developed a novel technique to treat chromite ore processing residue (COPR). The process involved mixing the COPR with sewage sludge followed by pyrolysis. The gaseous organic fraction generated during pyrolysis of sludge was beneficial to Cr(VI) reduction. Process variables, such as the amount of sludge added to COPR (sludge-to-COPR (S/C) ratio), heating temperature, reaction time and particle size, were systematically varied, and their influences on the Cr(VI) reduction in COPR were investigated. Cr(VI) content had decreased greatly, from 3384 mg kg(-1) for untreated COPR to less than 30 mg kg(-1) for COPR treated at 600 degrees C.

  6. Cost Analysis of Remediation Systems for Depleted Uranium

    DTIC Science & Technology

    2014-04-01

    osmosis . Physical separation techniques do not change the state of the contaminant. A number of chemical treatment processes can be used to separate DU...is breaking off. The sabot type round is used mainly for the M1 battle tank and Stryker MGS. The purpose of the sabot is to pick up the pressure of...environmentalist pressures against leaving DU in situ. ERDC/EL TR-14-5 37 Table 5-7. Cost summary for Alternative 4: Containment and monitoring. Category

  7. Tank waste remediation system baseline tank waste inventory estimates for fiscal year 1995

    SciTech Connect

    Shelton, L.W., Westinghouse Hanford

    1996-12-06

    A set of tank-by-tank waste inventories is derived from historical waste models, flowsheet records, and analytical data to support the Tank Waste Remediation System flowsheet and retrieval sequence studies. Enabling assumptions and methodologies used to develop the inventories are discussed. These provisional inventories conform to previously established baseline inventories and are meant to serve as an interim basis until standardized inventory estimates are made available.

  8. Sorption of colloids, organics, and metals onto gas-water, interfaces: Transport processes and potential remediation technology. 1997 annual progress report

    SciTech Connect

    Wan, J.

    1997-01-01

    'This research project has two objectives. The first is to improve basic understanding of contaminant interactions with gas-water interfaces, with emphasis on behavior of mixed contaminant systems. The second objective is to develop a sorptive microbubble fractionation remediation technique. Hypotheses supporting these objectives are: (1) contaminants and natural organics can sorb on and alter the interface hydrophobicity of the gas-water interfaces, and therefore influence sorption of colloids, metals, and radionuclides at gas-water interfaces; (2) surfactants can vastly increase sorption of colloids, metals and radionuclides selectively onto gas- water interfaces; (3) a sorptive microbubble fractionation remediation technique can be developed based on understanding of the previously mentioned processes. These hypotheses are being tested through quantification and visualization at both micro- and macro-scales.'

  9. Collocation and Pattern Recognition Effects on System Failure Remediation

    NASA Technical Reports Server (NTRS)

    Trujillo, Anna C.; Press, Hayes N.

    2007-01-01

    Previous research found that operators prefer to have status, alerts, and controls located on the same screen. Unfortunately, that research was done with displays that were not designed specifically for collocation. In this experiment, twelve subjects evaluated two displays specifically designed for collocating system information against a baseline that consisted of dial status displays, a separate alert area, and a controls panel. These displays differed in the amount of collocation, pattern matching, and parameter movement compared to display size. During the data runs, subjects kept a randomly moving target centered on a display using a left-handed joystick and they scanned system displays to find a problem in order to correct it using the provided checklist. Results indicate that large parameter movement aided detection and then pattern recognition is needed for diagnosis but the collocated displays centralized all the information subjects needed, which reduced workload. Therefore, the collocated display with large parameter movement may be an acceptable display after familiarization because of the possible pattern recognition developed with training and its use.

  10. Power punch: A new system for sampling and remediating groundwater

    SciTech Connect

    Cordry, K.

    1994-12-31

    In 1994, a rugged, low cost direct push tool that provides short term or permanent access to the formation was designed and field tested. The tool has the unique capacity to seal itself in position, solving many of the problems associated with permanent installation of direct push sampling devices. The tool is pushed or driven into position using standard, drilling or penetrometer rod. Once in place, inexpensive PVC pipe is used to connect the screen section to the surface. The drive rods are disconnected from the tool and removed, leaving the screen sealed in the formation by the body of the tool and connected to the surface via PVC pipe. The body of the tool provides an excellent annular seal, replacing the traditional bentonite seal. Grouting is often unnecessary. The screen interval can also be adjusted from a few inches to over 20 feet, after the tool is pushed into position. The tool provides a new system for installing/long term monitoring, soil vapor extraction and air sparging wells using direct push methods. It has the added advantage of being adaptable to almost any drilling or direct push system.

  11. In-situ remediation system and method for contaminated groundwater

    DOEpatents

    Corey, J.C.; Looney, B.B.; Kaback, D.S.

    1989-05-23

    A system for removing volatile contaminants from a subsurface plume of contamination comprising two sets of wells, a well for injecting a fluid into a saturated zone on one side of the plume and an extracting well for collecting the fluid together with volatilized contaminants from the plume on the other side of the plume. The fluid enables the volatile contaminants to be volatilized and carried therewith through the ground to the extracting well. Injecting and extracting wells are preferably horizontal wells positioned below the plume in the saturated zone and above the plume in the vadose zone, respectively. The fluid may be air or other gas or a gas and liquid mixture depending on the type of contaminant to be removed and may be preheated to facilitate volatilization. Treatment of the volatilized contamination may be by filtration, incineration, atmospheric dispersion or the like. 3 figs.

  12. In-situ remediation system and method for contaminated groundwater

    DOEpatents

    Corey, John C.; Looney, Brian B.; Kaback, Dawn S.

    1989-01-01

    A system for removing volatile contaminants from a subsurface plume of contamination comprising two sets of wells, a well for injecting a fluid into a saturated zone on one side of the plume and an extracting well for collecting the fluid together with volatilized contaminants from the plume on the other side of the plume. The fluid enables the volatile contaminants to be volatilized and carried therewith through the ground to the extracting well. Injecting and extracting wells are preferably horizontal wells positioned below the plume in the saturated zone and above the plume in the vadose zone, respectively. The fluid may be air or other gas or a gas and liquid mixture depending on the type of contaminant to be removed and may be preheated to facilitate volatilization. Treatment of the volatilized contamination may be by filtration, incineration, atmospheric dispersion or the like.

  13. Functional remediation components: A conceptual method of evaluating the effects of remediation on risks to ecological receptors

    SciTech Connect

    Burger, Joanna; Gochfeld, Michael; Bunn, Amoret; Downs, Janelle; Jeitner, Christian; Pittfield, Taryn; Salisbury, Jennifer

    2016-08-30

    Governmental agencies, regulators, health professionals, tribal leaders, and the public are faced with understanding and evaluating the effects of cleanup activities on species, populations, and ecosystems. While engineers and managers understand the processes involved in different remediation types such as capping, pump and treat, and natural attenuation, there is often a disconnect between (1) how ecologists view the influence of different types of remediation, (2) how the public perceives them, and (3) how engineers understand them. The overall goal of the present investigation was to define the components of remediation types (= functional remediation). Objectives were to (1) define and describe functional components of remediation, regardless of the remediation type, (2) provide examples of each functional remediation component, and (3) explore potential effects of functional remediation components in the post-cleanup phase that may involve continued monitoring and assessment. Functional remediation components include types, numbers, and intensity of people, trucks, heavy equipment, pipes, and drill holes, among others. Several components may be involved in each remediation type, and each results in ecological effects, ranging from trampling of plants, to spreading invasive species, to disturbing rare species, and to creating fragmented habitats. In some cases remediation may exert a greater effect on ecological receptors than leaving the limited contamination in place. A goal of this conceptualization is to break down functional components of remediation such that managers, regulators, and the public might assess the effects of timing, extent, and duration of different remediation options on ecological systems.

  14. Remediation approach for organic compounds and arsenic co-contaminated soil using pressurized hot water extraction process.

    PubMed

    Islam, Mohammad Nazrul; Jo, Young-Tae; Jeong, Yeon-Jae; Park, Jeong-Hun

    2017-09-15

    Successful remediation of soil with co-existing organics contaminants and arsenic (As) is a challenge as the chemical and remediation technologies are different for each group of pollutants. In this study, the treatment effectiveness of pressurized hot water (PHW) extraction process was investigated for remediation of soil co-contaminated with phenol, crude oil, polycyclic aromatic hydrocarbons (PAHs) and As. An elimination percentage of about 99% was achieved for phenol, and in the range of 63-100% was observed for the PAHs at 260 °C for 90 min operation. The performance of PHW extraction in the removal of total petroleum hydrocarbons was found to be 86%. Of the 87 mg/kg of As in untreated soil, 67% of which was eliminated after treatment. The removal of organic contaminants was mainly via desorption, dissolution and degradation in subcritical water, while As was eliminated probably by oxidation and dissolution of arsenic-bearing minerals. According to the experimental results, PHW extraction process can be suggested as an alternative cleaning technology, instead of using any organic solvents for remediation of such co-contaminated soil.

  15. Environmental assessment of remedial action at the inactive uraniferous lignite processing sites at Belfield and Bowman, North Dakota. [UMTRA Project

    SciTech Connect

    Beranich, S.; Berger, N.; Bierley, D.; Bond, T.M.; Burt, C.; Caldwell, J.A.; Dery, V.A.; Dutcher, A.; Glover, W.A.; Heydenburg, R.J.; Larson, N.B.; Lindsey, G.; Longley, J.M.; Millard, J.B.; Miller, M.; Peel, R.C.; Persson-Reeves, C.H.; Titus, F.B.; Wagner, L.

    1989-09-01

    The Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), to clean up the Belfield and Bowman, North Dakota, uraniferous lignite processing sites to reduce the potential health impacts associated with the residual radioactive materials remaining at these sites. Remedial action at these sites must be performed in accordance with the US Environmental Protection Agency's (EPA) standards promulgated for the remedial action and with the concurrence of the US Nuclear Regulatory Commission (NRC) and the state of North Dakota. The inactive Belfield uraniferous lignite processing site is one mile southeast of Belfield, North Dakota. The inactive Bowman uraniferous lignite processing site at the former town of Griffin, is seven miles northwest of Bowman, North Dakota and 65 road miles south of Belfield. Lignite ash from the processing operations has contaminated the soils over the entire 10.7-acre designated Belfield site and the entire 12.1-acre designated Bowman site. Dispersion of the ash has contaminated an additional 20.6 acres surrounding the Belfield processing site and an additional 59.2 acres surrounding the Bowman processing site. The proposed remedial action is to relocate the contaminated materials at the Belfield processing site to the Bowman processing/disposal site for codisposal with the Bowman contaminated soils. The environmental impacts assessed in this EA were evaluated for the proposed remedial action and the no action alternative and demonstrate that the proposed action would not significantly affect the quality of the human environment and would be performed in compliance with applicable environmental laws. The no action alternative would not be consistent with the intent of Public Law 95-604 and would not comply with the EPA standards. 48 refs., 10 figs., 7 tabs.

  16. A vertical equilibrium model for assessing nonaqueous phase liquid contamination and remediation of groundwater systems

    SciTech Connect

    Wu, Y.S.; Huyakorn, P.S.; Park, N.S. )

    1994-04-01

    The areal numerical model was developed to simulate the simultaneous flow of ground water and a nonaqueous phase liquid (NAPL) for specific application to petroleum or chemical spills and leaks and remedial design and evaluation. The gravity-capillary vertical equilibrium (GCVE) formulation incorporates history-dependent pseudo capillary and relative permeability functions. These functions were developed to allow realistic simulations of migration and remediation scenarios involving partly contaminated ground water systems and significant residual NAPL saturations. Robust and efficient mass-conservative numerical solution techniques were implemented to allow complete analyses of site-specific field problems. Simulation examples were provided to demonstrate the model verification and utility. Both analytical and rigorous multiphase numerical solutions were used to check the results from the GCVE formulation. For the various test cases the GCVE performed remarkably well, yielding good accuracy in predicting of vertical profiles of NAPL saturation and cumulative recovery curves.

  17. In-Situ Anaerobic Biosurfactant Production Process For Remediation Of DNAPL Contamination In Subsurface Aquifers

    NASA Astrophysics Data System (ADS)

    Albino, J. D.; Nambi, I. M.

    2009-12-01

    Microbial Enhanced Oil Recovery (MEOR) and remediation of aquifers contaminated with hydrophobic contaminants require insitu production of biosurfactants for mobilization of entrapped hydrophobic liquids. Most of the biosurfactant producing microorganisms produce them under aerobic condition and hence surfactant production is limited in subsurface condition due to lack of oxygen. Currently bioremediation involves expensive air sparging or excavation followed by exsitu biodegradation. Use of microorganisms which can produce biosurfactants under anaerobic conditions can cost effectively expedite the process of insitu bioremediation or mobilization. In this work, the feasibility of anaerobic biosurfactant production in three mixed anaerobic cultures prepared from groundwater and soil contaminated with chlorinated compounds and municipal sewage sludge was investigated. The cultures were previously enriched under complete anaerobic conditions in the presence of Tetrachloroethylene (PCE) for more than a year before they were studied for biosurfactant production. Biosurfactant production under anaerobic conditions was simulated using two methods: i) induction of starvation in the microbial cultures and ii) addition of complex fermentable substrates. Positive result for biosurfactant production was not observed when the cultures were induced with starvation by adding PCE as blobs which served as the only terminal electron acceptor. However, slight reduction in interfacial tension was noticed which was caused by the adherence of microbes to water-PCE interface. Biosurfactant production was observed in all the three cultures when they were fed with complex fermentable substrates and surface tension of the liquid medium was lowered below 35 mN/m. Among the fermentable substrates tested, vegetable oil yielded highest amount of biosurfactant in all the cultures. Complete biodegradation of PCE to ethylene at a faster rate was also observed when vegetable oil was amended to the

  18. Remediation trials for hydrocarbon-contaminated sludge from a soil washing process: evaluation of bioremediation technologies.

    PubMed

    Frutos, F J García; Pérez, R; Escolano, O; Rubio, A; Gimeno, A; Fernandez, M D; Carbonell, G; Perucha, C; Laguna, J

    2012-01-15

    The usual fate of highly contaminated fine products (silt-clay fractions) from soil washing plants is disposal in a dump or thermal destruction (organic contaminants), with consequent environmental impacts. Alternative treatments for these fractions with the aim of on-site reuse are needed. Therefore, the feasibility of two technologies, slurry bioremediation and landfarming, has been studied for the treatment of sludge samples with a total petroleum hydrocarbon (TPH) content of 2243 mg/kg collected from a soil washing plant. The treatability studies were performed at the laboratory and pilot-real scales. The bioslurry assays yielded a TPH reduction efficiency of 57% and 65% in 28 days at the laboratory and pilot scale, respectively. In the landfarming assays, a TPH reduction of 85% in six months was obtained at laboratory scale and 42% in three months for the bioremediation performed in the full-scale. The efficiency of these processes was evaluated by ecotoxicity assessments. The toxic effects in the initial sludge sample were very low for most measured parameters. After the remediation treatments, a decrease in toxic effects was observed in earthworm survival and in carbon mineralisation. The results showed the applicability of two well known bioremediation technologies on these residues, this being a novelty. Copyright © 2011 Elsevier B.V. All rights reserved.

  19. Assessment of calcium polysulfide for the remediation of hexavalent chromium in chromite ore processing residue (COPR).

    PubMed

    Wazne, Mahmoud; Jagupilla, Santhi Chandra; Moon, Deok Hyun; Jagupilla, Sarath Chandra; Christodoulatos, Christos; Kim, Min Gyu

    2007-05-17

    Bench scale and pilot scale treatability studies were conducted to evaluate the remediation of hexavalent chromium [Cr(VI)] in chromite ore processing residue (COPR) using calcium polysulfide. The results from the bench scale study indicated that a calcium polysulfide dosage twice the molar stoichiometric requirement (2x) proved effective in meeting the New Jersey Department of Environmental Protection (NJDEP) total Cr(VI) and the Environmental Protection Agency (EPA) Toxicity Characteristic Leaching Procedure (TCLP) regulatory standards. The treatment results were more effective at pH 12 than at pH 9.5. X-ray powder diffraction (XRPD) and X-ray absorption near edge structure (XANES) spectroscopy were also used to assess the treatment performance. Based on the bench scale results, an ex-situ pugmill pilot program was implemented to evaluate the applicability of the calcium polysulfide treatment on a larger scale (1000-lb batch test). The pugmill treatment results met Cr(VI) and TCLP regulatory standards over a period of 15 months. XANES analysis indicated that approximately 62% of Cr(VI) was reduced by calcium polysulfide at stoichiometric ratio of 2x after a curing period of 10 months.

  20. Status report on remedial investigation of the 300 Area process ponds

    SciTech Connect

    Dennison, D.I.; Sherwood, D.R.; Young, J.S.

    1989-09-01

    A remedial investigation (RI) of the South and North Process Ponds adjacent to the 300 Area at the US Department of Energy (DOE) Hanford Site was initiated in FY 1987 as partial implementation of the DOE Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Program. The objective of FY 1987 activities was initial characterization of the quantity and distribution of contaminants in the sediments. Sediment samples from 14 locations in and adjacent to the ponds were collected and analyzed. Initial results indicated that contaminated sediments in the ponds typically contained high gross alpha and gross beta activities and concentrations of Ag, Al, Cr, Cu, Ni, and Zn that were elevated relative to background levels. Radiochemical analyses of the sediments showed that the primary radiological contaminant was uranium; cobalt-60 and cesium-137 were detected in several samples. Organic compounds, including polychlorinated biphenyls (PCBs), were also detected in several samples. Future RI activities will be undertaken under EPA-approved RI/FS work plans. 5 refs., 14 figs., 11 tabs.

  1. Evaluation of a remediation process for lead contaminated soil by toxicity bioassays: Plants and earthworms

    SciTech Connect

    Chana, L.W.; Smith, K.

    1995-12-31

    Soil from a site contaminated with heavy metals (predominantly lead) was treated using the TERRAMET{reg_sign} lead extraction process. Earthworm acute toxicity and plant seed germination/root elongation (SG/RE) bioassays were used to evaluate the toxicity of the soil before treatment (BT), after treatment (AT) and after treatment, followed by rinsing with water, intended to simulate exposure to rainfall (RT). The results showed BT and RT were not toxic to earthworms in a 14-day exposure while AT showed significant toxicity. The LC{sub 50} values for Eisenia and Lumbricus were 44.04 and 28.83 (as % AT soil/test soil mixture), respectively. The phytotoxicity data indicated that all 3 test soils significantly inhibited lettuce SG/RE in a dose-related manner, with AT being the most phytotoxic. In oats, RT had no effect on SG/RE and AT was more toxic than BT. For the two local-site grass seeds tested (blue grama and sideoat grama), the AT soil was the most phytotoxic followed by BT and RT. The results suggest that the soil after this remediation process exerts significant toxicity on both plant and earthworm, but after a rain-simulating rinse, the toxicity is the same as, or less than, the toxicity before treatment. Further studies are in progress to confirm the assumption that the high salt concentrations generated by acidification during the leaching process, followed by neutralization are responsible for the increased toxicity of unrinsed soil in both plant and earthworm.

  2. Final report of the systems engineering technical advisory board for the Tank Waste Remediation Program

    SciTech Connect

    Baranowski, F.P.; Goodlett, C.B.; Beard, S.J.; Duckworth, J.P.; Schneider, A.; Zahn, L.L.

    1993-03-01

    The Tank Waste Remediation System (TWRS) is one segment of the environmental restoration program at the Hanford site. The scope is to retrieve the contents of both the single shell and double shell tanks and process the wastes into forms acceptable for long term storage and/or permanent disposal. The quantity of radioactive waste in tanks is significantly larger and substantially more complex in composition than the radioactive waste stored in tanks at other DOE sites. The waste is stored in 149 single shell tanks and 28 double shell tanks. The waste was produced over a period from the mid 1940s to the present. The single shell tanks have exceeded their design life and are experiencing failures. The oldest of the double shell tanks are approaching their design life. Spar double shell tank waste volume is limited. The priorities in the Board`s view are to manage safely the waste tank farms, accelerate emptying of waste tanks, provide spare tank capacity and assure a high degree of confidence in performance of the TWRS integrated program. At its present design capacity, the glass vitrification plant (HWVP) will require a period of about 15 years to empty the double shell tanks; the addition of the waste in single shell tanks adds another 100 years. There is an urgent need to initiate now a well focused and centralized development and engineering program on both larger glass melters and advanced separations processes that reduce radioactive constituents in the low-level waste (LLW). The Board presents its conclusions and has other suggestions for the management plan. The Board reviews planning schedules for accelerating the TWRS program.

  3. Process Control Plan for Tank 241-SY-101 Surface Level Rise Remediation

    SciTech Connect

    ESTEY, S.D.

    1999-09-28

    The tank 241-SY-101 transfer system was conceived and designed to address the immediate needs presented by rapidly changing waste conditions in tank 241-SY-101. Within the last year or so, the waste in this tank has exhibited unexpected behavior (Rassat et al. 1999) in the form of rapidly increasing crust growth. This growth has been brought about by a rapidly increasing rate of gas entrapment within the crust. It has been conceived that the lack of crust agitation beginning upon the advent of mixer pump operations may have set-up a more consolidated, gas impermeable barrier when compared to a crust regularly broken up by the prior buoyant displacement events within the tank. As a result, a series of level-growth remediation activities have been developed for tank 241-SY-101. The initial activities are also known as near-term crust mitigation. The first activity of near-term mitigation is to perform the small transfer of convective waste from tank 241-SY-101 into tank 241-SY-102. A 100 kgal transfer represents about a 10% volume reduction allowing a 10% water in-tank dilution. Current thinking holds that this should be enough to dissolve nitrite solids in the crust and perhaps largely eliminate gas retention problem in the crust (Raymond 1999).

  4. Self-sustaining smoldering combustion: a novel remediation process for non-aqueous-phase liquids in porous media.

    PubMed

    Switzer, C; Pironi, P; Gerhard, J I; Rein, G; Torero, J L

    2009-08-01

    Smoldering combustion, the slow burning process associated typically with porous solids (e.g., charcoal), is here proposed as a novel remediation approach for nonaqueous phase liquids (NAPLs) embedded in porous media. Several one-dimensional vertical smoldering experiments are conducted on quartz sand containing fresh coal tar at an initial concentration of 71 000 mg/kg (approximately 25% saturation) and employing an upward darcy air flux of 4.25 cm/s. Following a short-duration energy input to achieve ignition at the lower boundary, a self-sustaining combustion front is observed to propagate upward at 1.3 x 10(-2) cm/s. The process is self-sustaining because the energy released during NAPL smoldering is efficiently trapped and recirculated by the soil matrix, preheating the NAPL ahead of the reaction front. The smoldering process is observed to self-terminate when all of the NAPL is destroyed or when the oxygen source is removed. Pre- and post-soil analysis revealed that NAPL smoldering reduced the concentration of total extractable petroleum hydrocarbons (TPH) from 38 000 mg/kg to below detection limits (< 0.1 mg/kg) throughout the majority of the column. A comparable experiment in which conductive heating is applied in the absence of smoldering demonstrates a 6-fold reduction in the net energy in the system and residual TPH values of 2000-35 000 mg/kg. A further repeat in which the air supply is prematurely terminated demonstrated that the NAPL smoldering process can be extinguished via external control. A suite of 23 demonstration experiments shows that NAPL smoldering is successful across a range of soil types (including simple layered systems) and contaminants (including laboratory mixtures of dodecane, DCA/ grease, TCE/oil, vegetable oil, crude oil, and mineral oil) as well as field-obtained samples of materials containing coal tar, oil drill cutting waste, and oil sands.

  5. Comparison of Scale in a Photosynthetic Reactor System for Algal Remediation of Wastewater.

    PubMed

    Sniffen, Kaitlyn D; Sales, Christopher M; Olson, Mira S

    2017-03-06

    An experimental methodology is presented to compare the performance of two different sized reactors designed for wastewater treatment. In this study, ammonia removal, nitrogen removal and algal growth are compared over an 8-week period in paired sets of small (100 L) and large (1,000 L) reactors designed for algal remediation of landfill wastewater. Contents of the small and large scale reactors were mixed before the beginning of each weekly testing interval to maintain equivalent initial conditions across the two scales. System characteristics, including surface area to volume ratio, retention time, biomass density, and wastewater feed concentrations, can be adjusted to better equalize conditions occurring at both scales. During the short 8-week representative time period, starting ammonia and total nitrogen concentrations ranged from 3.1-14 mg NH3-N/L, and 8.1-20.1 mg N/L, respectively. The performance of the treatment system was evaluated based on its ability to remove ammonia and total nitrogen and to produce algal biomass. Mean ± standard deviation of ammonia removal, total nitrogen removal and biomass growth rates were 0.95±0.3 mg NH3-N/L/day, 0.89±0.3 mg N/L/day, and 0.02±0.03 g biomass/L/day, respectively. All vessels showed a positive relationship between the initial ammonia concentration and ammonia removal rate (R(2)=0.76). Comparison of process efficiencies and production values measured in reactors of different scale may be useful in determining if lab-scale experimental data is appropriate for prediction of commercial-scale production values.

  6. Remediation of anionic dye from aqueous system using bio-adsorbent prepared by microwave activation.

    PubMed

    Sharma, Arush; Sharma, Gaurav; Naushad, Mu; Ghfar, Ayman A; Pathania, Deepak

    2017-04-07

    The present study was attempted to ascertain the possible application of activated carbon as cost effective and eco-friendly adsorbent prepared via microwave (MW) assisted chemical activation. The activated carbon was characterized using different techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and field-emission scanning electron microscope (FESEM). The various adsorption parameters have been optimized to examine the viability of activated carbon as a plausible sorbent for the remediation of Congo red (CR) dye from aquatic system. The adsorption equilibrium was interpreted using Langmuir, Freundlich and Tempkin isotherms. The equilibrium data adequately fitted to Langmuir isotherm with stronger R(2) (0.994). The maximum adsorption capacity (qm) of activated carbon was recorded to be 68.96 mg/g. Additionally, sorptional kinetic data were examined by reaction based and diffusion based models such as pseudo-first-order, pseudo-second-order, Elovich model and intra-particle diffusion, Dumwald-Wagner models, respectively. The experimental results indicated that pseudo-second-order equation and Elovich model better discuss the adsorption kinetics. The computed values of thermodynamic parameters such as free energy change (ΔG(0)), enthalpy change (ΔH(0)) and entropy change (ΔS(0)) were recorded as -3.63 kJ/mol, 42.47 kJ/mol, 152.07 J/mol K, respectively at 30°C, which accounted for favorable, spontaneous and endothermic process. The regeneration study emphasized that percentage uptake declined from 90.35 to 83.45% after 6cycles of testing. So, our findings implied that activated carbon produced from biomass must be cost-effectively used as an adsorbent for detoxifying the CR dye from industrial effluents.

  7. Assessment of ferrous chloride and Portland cement for the remediation of chromite ore processing residue.

    PubMed

    Jagupilla, Santhi C; Wazne, Mahmoud; Moon, Deok Hyun

    2015-10-01

    Chromite Ore Processing Residue (COPR) is an industrial waste containing up to 7% chromium (Cr) including up to 5% hexavalent chromium [Cr(VI)]. The remediation of COPR has been challenging due to the slow release of Cr(VI) from a clinker like material and thereby the incomplete detoxification of Cr(VI) by chemical reagents. The use of sulfur based reagents such as ferrous sulfate and calcium polysulfide to detoxify Cr(VI) has exasperated the swell potential of COPR upon treatment. This study investigated the use of ferrous chloride alone and in combination with Portland cement to address the detoxification of Cr(VI) in COPR and the potential swell of COPR. Chromium regulatory tests, X-ray powder diffraction (XRPD) analyses and X-ray absorption near edge structure (XANES) analyses were used to assess the treatment results. The treatment results indicated that Cr(VI) concentrations for the acid pretreated micronized COPR as measured by XANES analyses were below the New Jersey Department of Environmental Protection (NJDEP) standard of 20 mg kg(-1). The Toxicity characteristic leaching procedure (TCLP) Cr concentrations for all acid pretreated samples also were reduced below the TCLP regulatory limit of 5 mg L(-1). Moreover, the TCLP Cr concentration for the acid pretreated COPR with particle size ⩽0.010 mm were less than the universal treatment standard (UTS) of 0.6 mg L(-1). The treatment appears to have destabilized all COPR potential swell causing minerals. The unconfined compressive strength (UCS) for the treated samples increased significantly upon treatment with Portland cement.

  8. PETRO-SAFE '92 conference papers: Volume 7 (Processing and Refining 2), Volume 8 (Transportation and storage), Volume 9 (Spill control, disposal and remedial treatment 1) and Volume 10 (Spill control, disposal and remedial treatment 2)

    SciTech Connect

    Not Available

    1992-01-01

    This conference presents papers on a wide range of petroleum and petrochemical industry issues which pertain to waste disposal, waste processing, and safety issues. It presents specific papers on waste reduction and processing;fire prevention and suppression of oil and gas fires in storage and processing facilities; safety engineering and monitoring and plants and facilities;transportation and storage issues as they relate to safety and leak detection; and oil spill remediation and disposal. Spill topics include sorption techniques, bioremediation, dispersions, and air stripping. The remediation papers include both on and offshore sites and approach the topic from both safety and environmental aspects.

  9. Spitzer Telemetry Processing System

    NASA Technical Reports Server (NTRS)

    Stanboli, Alice; Martinez, Elmain M.; McAuley, James M.

    2013-01-01

    The Spitzer Telemetry Processing System (SirtfTlmProc) was designed to address objectives of JPL's Multi-mission Image Processing Lab (MIPL) in processing spacecraft telemetry and distributing the resulting data to the science community. To minimize costs and maximize operability, the software design focused on automated error recovery, performance, and information management. The system processes telemetry from the Spitzer spacecraft and delivers Level 0 products to the Spitzer Science Center. SirtfTlmProc is a unique system with automated error notification and recovery, with a real-time continuous service that can go quiescent after periods of inactivity. The software can process 2 GB of telemetry and deliver Level 0 science products to the end user in four hours. It provides analysis tools so the operator can manage the system and troubleshoot problems. It automates telemetry processing in order to reduce staffing costs.

  10. Pitfalls in the Multicultural Diagnostic/Remedial Process: A Central American Experience.

    ERIC Educational Resources Information Center

    Howard, Douglas P.

    The author discusses his observations from administering such tests as the Denver Developmental Screening Test (DDST) to young disabled children in Costa Rica. Cultural influences and nuances of translations are seen to affect performance. Factors involved in remediation programing are also noted. A final consideration is the "barrio…

  11. Field demonstration of a full-scale in situ thermal desorption system for the remediation of soil containing PCBS and other hydrocarbons

    SciTech Connect

    Sheldon, R.B.; Iben, I.E.T.; Edelstein, W.A.

    1996-12-31

    A field demonstration of a full-sale, innovative and cost-effective remediation system using in situ thermal description (ISTD) was conducted at a state Superfund site in the northeastern United States in early 1996. The Demonstration was performed as part of the regulatory process to obtain a nationwide Toxic Substances Control Act (TSCA) permit for the remediation of soils containing PCBs at concentrations up to 5,000 ppm. An area of approximately 4800 square feet was remediated during six applications of an in situ Thermal Blanket covering an area of 800 square feet. Each application utilized five 160 square foot, electrically heated, 100-kilowatt modules. The Thermal Blanket heaters were operated at temperatures as high as 925 C. The modules contain 10 in. of vermiculite insulation to reduce upward heat losses to less than 10% of total power. The modules are covered with an impermeable silicone sheet and the in situ process is run at negative pressure to collect contaminants, prevent contaminant migration and eliminate odors. Off-gas emissions are controlled by a vapor extraction system comprised of a cyclonic separator for particulate removal, a flameless thermal oxidizer for destruction of residual contaminants, and a carbon polishing unit. Treatment times ranged from slightly more than 24 hours to treat the upper six inches to approximately four days to treat soil 12 to 18 inches deep. Temperature profiles and remedial efficiency are consistent with results from a computer thermal simulator. Post-treatment soil samples demonstrated the capability to achieve stringent soil cleanup levels of less than 2 ppm for PCBs while concurrently meeting ambient air quality standards with respect to air emissions and worker exposure limits. The Thermal Blanket is less intrusive than other permanent remedies and produces less noise, generates less dust and has a minimum of other impacts on the surrounding community.

  12. Electrolytic arsenic removal for recycling of washing solutions in a remediation process of CCA-treated wood.

    PubMed

    Nanseu-Njiki, Charles-Péguy; Alonzo, Véronique; Bartak, Duane; Ngameni, Emmanuel; Darchen, André

    2007-10-01

    The remediation of chromated copper arsenate or CCA-treated wood is a challenging problem in many countries. In a wet remediation, the recycling of the washing solutions is the key step for a successful process. Within this goal, owing to its solubility and its toxicity, the removal of arsenic from washing solution is the most difficult process. The efficiency of arsenic removal from As(III) solutions by electrolysis was investigated in view of the recycling of acidic washing solutions usable in the remediation of CCA-treated wood. Electrochemical reduction of As(III) is irreversible and thus difficult to perform at carbon electrodes. However the electrolytic extraction of arsenic can be performed by the concomitant reduction of the cupric cation and arsenite anion. The cathodic deposits obtained by controlled potential electrolysis were analyzed by X-ray diffraction (XRD) and energy dispersive X-ray microanalysis. XRD diffraction data indicated that these deposits were mixtures of copper and copper arsenides Cu(3)As and Cu(5)As(2). Electrolysis was carried out in an undivided cell with graphite cathode and copper anode, under a controlled nitrogen atmosphere. The evolution of arsine gas AsH(3) was not observed under these conditions.

  13. Design of aquifer remediation systems: (2) Estimating site-specific performance and benefits of partial source removal

    NASA Astrophysics Data System (ADS)

    Wood, A. Lynn; Enfield, Carl G.; Espinoza, Felipe P.; Annable, Michael; Brooks, Michael C.; Rao, P. S. C.; Sabatini, David; Knox, Robert

    2005-12-01

    A Lagrangian stochastic model is proposed as a tool that can be utilized in forecasting remedial performance and estimating the benefits (in terms of flux and mass reduction) derived from a source zone remedial effort. The stochastic functional relationships that describe the hydraulic "structure" and non-aqueous phase liquid (NAPL) "architecture" have been described in a companion paper (Enfield, C.G., Wood, A.L., Espinoza, F.P., Brooks, M.C., Annable, M., Rao, P.S.C., this issue. Design of aquifer remediation systems: (1) describing hydraulic structure and NAPL architecture using tracers. J. Contam. Hydrol.). The previously defined functions were used along with the properties of the remedial fluids to describe remedial performance. There are two objectives for this paper. First, is to show that a simple analytic element model can be used to give a reasonable estimate of system performance. This is accomplished by comparing forecast performance to observed performance. The second objective is to display the model output in terms of change in mass flux and mass removal as a function of pore volumes of remedial fluid injected. The modelling results suggest that short term benefits are obtained and related to mass reduction at the sites where the model was tested.

  14. Industrial Process Surveillance System

    DOEpatents

    Gross, Kenneth C.; Wegerich, Stephan W; Singer, Ralph M.; Mott, Jack E.

    2001-01-30

    A system and method for monitoring an industrial process and/or industrial data source. The system includes generating time varying data from industrial data sources, processing the data to obtain time correlation of the data, determining the range of data, determining learned states of normal operation and using these states to generate expected values, comparing the expected values to current actual values to identify a current state of the process closest to a learned, normal state; generating a set of modeled data, and processing the modeled data to identify a data pattern and generating an alarm upon detecting a deviation from normalcy.

  15. Industrial process surveillance system

    DOEpatents

    Gross, Kenneth C.; Wegerich, Stephan W.; Singer, Ralph M.; Mott, Jack E.

    1998-01-01

    A system and method for monitoring an industrial process and/or industrial data source. The system includes generating time varying data from industrial data sources, processing the data to obtain time correlation of the data, determining the range of data, determining learned states of normal operation and using these states to generate expected values, comparing the expected values to current actual values to identify a current state of the process closest to a learned, normal state; generating a set of modeled data, and processing the modeled data to identify a data pattern and generating an alarm upon detecting a deviation from normalcy.

  16. Industrial process surveillance system

    DOEpatents

    Gross, K.C.; Wegerich, S.W.; Singer, R.M.; Mott, J.E.

    1998-06-09

    A system and method are disclosed for monitoring an industrial process and/or industrial data source. The system includes generating time varying data from industrial data sources, processing the data to obtain time correlation of the data, determining the range of data, determining learned states of normal operation and using these states to generate expected values, comparing the expected values to current actual values to identify a current state of the process closest to a learned, normal state; generating a set of modeled data, and processing the modeled data to identify a data pattern and generating an alarm upon detecting a deviation from normalcy. 96 figs.

  17. Development and Testing of Geo-Processing Models for the Automatic Generation of Remediation Plan and Navigation Data to Use in Industrial Disaster Remediation

    NASA Astrophysics Data System (ADS)

    Lucas, G.; Lénárt, C.; Solymosi, J.

    2015-08-01

    This paper introduces research done on the automatic preparation of remediation plans and navigation data for the precise guidance of heavy machinery in clean-up work after an industrial disaster. The input test data consists of a pollution extent shapefile derived from the processing of hyperspectral aerial survey data from the Kolontár red mud disaster. Three algorithms were developed and the respective scripts were written in Python. The first model aims at drawing a parcel clean-up plan. The model tests four different parcel orientations (0, 90, 45 and 135 degree) and keeps the plan where clean-up parcels are less numerous considering it is an optimal spatial configuration. The second model drifts the clean-up parcel of a work plan both vertically and horizontally following a grid pattern with sampling distance of a fifth of a parcel width and keep the most optimal drifted version; here also with the belief to reduce the final number of parcel features. The last model aims at drawing a navigation line in the middle of each clean-up parcel. The models work efficiently and achieve automatic optimized plan generation (parcels and navigation lines). Applying the first model we demonstrated that depending on the size and geometry of the features of the contaminated area layer, the number of clean-up parcels generated by the model varies in a range of 4% to 38% from plan to plan. Such a significant variation with the resulting feature numbers shows that the optimal orientation identification can result in saving work, time and money in remediation. The various tests demonstrated that the model gains efficiency when 1/ the individual features of contaminated area present a significant orientation with their geometry (features are long), 2/ the size of pollution extent features becomes closer to the size of the parcels (scale effect). The second model shows only 1% difference with the variation of feature number; so this last is less interesting for planning

  18. ISS Internal Active Thermal Control System (IATCS) Coolant Remediation Project -2006 Update

    NASA Technical Reports Server (NTRS)

    Morrison, Russell H.; Holt, Mike

    2006-01-01

    The IATCS coolant has experienced a number of anomalies in the time since the US Lab was first activated on Flight 5A in February 2001. These have included: 1) a decrease in coolant pH, 2) increases in inorganic carbon, 3) a reduction in phosphate concentration, 4) an increase in dissolved nickel and precipitation of nickel salts, and 5) increases in microbial concentration. These anomalies represent some risk to the system, have been implicated in some hardware failures and are suspect in others. The ISS program has conducted extensive investigations of the causes and effects of these anomalies and has developed a comprehensive program to remediate the coolant chemistry of the on-orbit system as well as provide a robust and compatible coolant solution for the hardware yet to be delivered. This paper presents a status of the coolant stability over the past year as well as results from destructive analyses of hardware removed from the on-orbit system and the current approach to coolant remediation.

  19. An Empirical Measure of Computer Security Strength for Vulnerability Remediation

    ERIC Educational Resources Information Center

    Villegas, Rafael

    2010-01-01

    Remediating all vulnerabilities on computer systems in a timely and cost effective manner is difficult given that the window of time between the announcement of a new vulnerability and an automated attack has decreased. Hence, organizations need to prioritize the vulnerability remediation process on their computer systems. The goal of this…

  20. An Empirical Measure of Computer Security Strength for Vulnerability Remediation

    ERIC Educational Resources Information Center

    Villegas, Rafael

    2010-01-01

    Remediating all vulnerabilities on computer systems in a timely and cost effective manner is difficult given that the window of time between the announcement of a new vulnerability and an automated attack has decreased. Hence, organizations need to prioritize the vulnerability remediation process on their computer systems. The goal of this…

  1. EARSEC SAR processing system

    NASA Astrophysics Data System (ADS)

    Protheroe, Mark; Sloggett, David R.; Sieber, Alois J.

    1994-12-01

    Traditionally, the production of high quality Synthetic Aperture Radar imagery has been an area where a potential user would have to expend large amounts of money in either the bespoke development of a processing chain dedicated to his requirements or in the purchase of a dedicated hardware platform adapted using accelerator boards and enhanced memory management. Whichever option the user adopted there were limitations based on the desire for a realistic throughput in data load and time. The user had a choice, made early in the purchase, for either a system that adopted innovative algorithmic manipulation, to limit the processing time of the purchase of expensive hardware. The former limits the quality of the product, while the latter excludes the user from any visibility into the processing chain. Clearly there was a need for a SAR processing architecture that gave the user a choice into the methodology to be adopted for a particular processing sequence, allowing him to decide on either a quick (lower quality) product or a detailed slower (high quality) product, without having to change the algorithmic base of his processor or the hardware platform. The European Commission, through the Advanced Techniques unit of the Joint Research Centre (JRC) Institute for Remote Sensing at Ispra in Italy, realizing the limitations on current processing abilities, initiated its own program to build airborne SAR and Electro-Optical (EO) sensor systems. This program is called the European Airborne Remote Sensing Capabilities (EARSEC) program. This paper describes the processing system developed for the airborne SAR sensor system. The paper considers the requirements for the system and the design of the EARSEC Airborne SAR Processing System. It highlights the development of an open SAR processing architecture where users have full access to intermediate products that arise from each of the major processing stages. It also describes the main processing stages in the overall

  2. Process evaluation distributed system

    NASA Technical Reports Server (NTRS)

    Moffatt, Christopher L. (Inventor)

    2006-01-01

    The distributed system includes a database server, an administration module, a process evaluation module, and a data display module. The administration module is in communication with the database server for providing observation criteria information to the database server. The process evaluation module is in communication with the database server for obtaining the observation criteria information from the database server and collecting process data based on the observation criteria information. The process evaluation module utilizes a personal digital assistant (PDA). A data display module in communication with the database server, including a website for viewing collected process data in a desired metrics form, the data display module also for providing desired editing and modification of the collected process data. The connectivity established by the database server to the administration module, the process evaluation module, and the data display module, minimizes the requirement for manual input of the collected process data.

  3. The importance of Soil Science to understand and remediate Land Degradation and Desertification processes

    NASA Astrophysics Data System (ADS)

    Bouma, Johan; Keesstra, Saskia; Cerdà, Artemi

    2017-04-01

    Documentation is abundantly available to demonstrate the devastating effect of Land degradation and desertification on sustainable development in many countries. This present a major barrier to achieving the UN Sustainable Development Goals by 2030, as agreed upon at the General Assembly of the UN in September 2015. Research has certainly been successful in reversing these two processes in many case studies but persistant problems remain not only in developing countries but also in developed countries where, for example, soil compaction and loss of soil organic matter due to the industrialization of agriculture, result in a structural decline of agricultural productivity and environmental quality. The problems are quite complex because not only technical matters play a role but also, and often quite prominantly, socio-economic factors. What turn out to be successful remediation procedures at a given location or region, based on the characterization of underlying soil processes, will most likely not work in other regions inhibiting the extrapolation of local research results to areas elsewhere. One important reason for location specificity of research is the variation of soil properties in combination with the location of soils in a given landscape which governs its water, energy and nutrient dynamics, also considering the climate. Different soils are characterized by different natural riks for degradation and , in arid regions, deserticification and their particular remediation potential differs widely as well. Such risks can sometimes be overcome by innovative soil management and knowing the soil type, the climate and landscape processes, extrapolation of such types of innovative management to comparable soils and landscapes elsewhere may be feasible and effective , provided that socio-economic conditions allow the required risk-reducing measures to be realized in practice. More cooperation between soil scientists and physical geographers, familiar with landscape

  4. Baking soda misuse as a home remedy: case experience of the California Poison Control System.

    PubMed

    Al-Abri, S A; Kearney, T

    2014-02-01

    Baking soda is a common household product promoted by the manufacturer as an antacid. It contains sodium bicarbonate and has the potential for significant toxicity when ingested in excessive amounts. Characterizing the patterns and outcomes from the misuse of baking soda as a home remedy can guide the clinical assessment and preventative counselling of patients at risk for use of this product. We conducted a retrospective review of all symptomatic cases involving ingestion and misuse of a baking soda powder product that were reported to the California Poison Control System between the years 2000 and 2012. Of the 192 cases we identified, 55·8% were female, ages ranged 2 months to 79 years, and the most common reasons for misuse included antacid (60·4%), 'beat a urine drug test' (11·5%) and treat a UTI (4·7%). Most cases (55·2%) had significant symptoms warranting a medical evaluation, whereas 12 patients required hospital admission developed either electrolyte imbalances, metabolic alkalosis or respiratory depression. Misuse of baking soda can result in serious electrolyte and acid/base imbalances. Patients at highest risk of toxicity may include those who chronically use an antacid, those who use the method to 'beat' urine drug screens, pregnant women and young children. Self-treatment with baking soda as a home remedy may also mask or delay medical care thereby complicating or exacerbating an existing medical problem. We suggest that healthcare providers counsel high-risk patients about the potential complications of misuse of baking soda as a home remedy. © 2013 John Wiley & Sons Ltd.

  5. Enhanced removal of petroleum hydrocarbons using a bioelectrochemical remediation system with pre-cultured anodes.

    PubMed

    Venkidusamy, Krishnaveni; Megharaj, Mallavarapu; Marzorati, Massimo; Lockington, Robin; Naidu, Ravi

    2016-01-01

    Bioelectrochemical remediation (BER) systems such as microbial fuel cells (MFCs) have recently emerged as a green technology for the effective remediation of petroleum hydrocarbon contaminants (PH) coupled with simultaneous energy recovery. Recent research has shown that biofilms previously enriched for substrate degrading bacteria resulted in excellent performance in terms of substrate removal and electricity generation but the effects on hydrocarbon contaminant degradation were not examined. Here we investigate the differences between enriched biofilm anodes and freshly inoculated new anodes in diesel fed single chamber mediatorless microbial fuel cells (DMFC) using various techniques for the enhancement of PH contaminant remediation with concomitant electricity generation. An anodophilic microbial consortium previously selected for over a year through continuous culturing with a diesel concentration of about 800mgl(-1) and which now showed complete removal of this concentration of diesel within 30days was compared to that of a freshly inoculated new anode MFC (showing 83.4% removal of diesel) with a simultaneous power generation of 90.81mW/m(2) and 15.04mW/m(2) respectively. The behaviour of pre-cultured anodes at a higher concentration of PH (8000mgl(-1)) was also investigated. Scanning electron microscopy observation revealed a thick biofilm covering the pre-cultured anodic electrode but not the anode from the freshly inoculated MFC. High resolution imaging showed the presence of thin 60nm diametre pilus-like projections emanating from the cells. Anodic microbial community profiling confirmed that the selection for diesel degrading exoelectrogenic bacteria had occurred. Identification of a biodegradative gene (alkB) provided strong evidence of the catabolic pathway used for diesel degradation in the DMFCs.

  6. Dynamic remediation test of polluted river water by Eco-tank system.

    PubMed

    Xiao, Jibo; Wang, Huiming; Chu, Shuyi; Wong, Ming-Hung

    2013-01-01

    Dynamic remediation of river water polluted by domestic sewage using an aquatic plants bed-based Eco-tank system was investigated. Over a period of 18 days, the test demonstrated that average effluent concentrations of chemical oxygen demand (COD), ammonium nitrogen (NH4(+)-N) and total phosphorus (TP) were as low as 17.28, 0.23 and 0.03 mg/L, respectively, under the hydraulic retention time (HRT) of 8.7 d. The average removal efficiencies in terms of COD, NH4(+)-N and TP could reach 71.95, 97.96 and 97.84%, respectively. The loss of both NH4(+)-N and TP was mainly ascribed to the uptake by plants. Hydrocotyle leucocephala was effective in promoting the dissolved oxygen (DO) level, while Pistia stratiotes with numerous fibrous roots was significantly effective for the removal of organic compounds. The net photosynthetic rate, stomatal conductance, transpiration rate and biomass accumulation rate of Myriophyllum aquaticum were the highest among all tested plants. Thus, the Eco-tank system could be considered as an alternative approach for the in situ remediation of polluted river water, especially nutrient-laden river water.

  7. Results from a National Central Auditory Processing Disorder Service: A Real-World Assessment of Diagnostic Practices and Remediation for Central Auditory Processing Disorder

    PubMed Central

    Cameron, Sharon; Glyde, Helen; Dillon, Harvey; King, Alison; Gillies, Karin

    2015-01-01

    This article describes the development and evaluation of a national service to diagnose and remediate central auditory processing disorder (CAPD). Data were gathered from 38 participating Australian Hearing centers over an 18-month period from 666 individuals age 6, 0 (years, months) to 24, 8 (median 9, 0). A total of 408 clients were diagnosed with either a spatial processing disorder (n = 130), a verbal memory deficit (n = 174), or a binaural integration deficit (n = 104). A hierarchical test protocol was used so not all children were assessed on all tests in the battery. One hundred fifty clients decided to proceed with deficit-specific training (LiSN & Learn or Memory Booster) and/or be fitted with a frequency modulation system. Families were provided with communication strategies targeted to a child's specific listening difficulties and goals. Outcomes were measured using repeat assessment of the relevant diagnostic test, as well as the Client Oriented Scale of Improvement measure and Listening Inventories for Education teacher questionnaire. Group analyses revealed significant improvements postremediation for all training/management options. Individual posttraining performance and results of outcome measures also are discussed. PMID:27587910

  8. Effects of particle size and acid addition on the remediation of chromite ore processing residue using ferrous sulfate.

    PubMed

    Jagupilla, Santhi Chandra; Moon, Deok Hyun; Wazne, Mahmoud; Christodoulatos, Christos; Kim, Min Gyu

    2009-08-30

    A bench-scale treatability study was conducted to assess the effects of particle size and acid addition on the remediation of chromite ore processing residue (COPR) using ferrous sulfate. The remediation scheme entailed the chemical reduction of hexavalent chromium [Cr(VI)] and the mitigation of swell potential. Leaching tests and the EQ3/6 geochemical model were used to estimate the acid dosage required to destabilize Cr(VI)-bearing and swell-causing minerals. The model predicted greater acid dosage than that estimated from the batch leaching tests. This indicated that mass transfer limitation may be playing a significant role in impeding the dissolution of COPR minerals following acid addition and hence hindering the remediation of COPR. Cr(VI) concentrations determined by alkaline digestion for the treated samples were less than the current NJDEP standard. However, Cr(VI) concentrations measured by X-ray absorption near edge structure (XANES) were greater than those measured by alkaline digestion. Greater Cr(VI) percentages were reduced for acid pretreated and also for smaller particle size COPR samples. Upon treatment, brownmillerite content was greatly reduced for the acid pretreated samples. Conversely, ettringite, a swell-causing mineral, was not observed in the treated COPR.

  9. Laser material processing system

    DOEpatents

    Dantus, Marcos

    2015-04-28

    A laser material processing system and method are provided. A further aspect of the present invention employs a laser for micromachining. In another aspect of the present invention, the system uses a hollow waveguide. In another aspect of the present invention, a laser beam pulse is given broad bandwidth for workpiece modification.

  10. Image Processing System

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Mallinckrodt Institute of Radiology (MIR) is using a digital image processing system which employs NASA-developed technology. MIR's computer system is the largest radiology system in the world. It is used in diagnostic imaging. Blood vessels are injected with x-ray dye, and the images which are produced indicate whether arteries are hardened or blocked. A computer program developed by Jet Propulsion Laboratory known as Mini-VICAR/IBIS was supplied to MIR by COSMIC. The program provides the basis for developing the computer imaging routines for data processing, contrast enhancement and picture display.

  11. MGP soil remediation in a slurry-phase system: A pilot-scale test

    SciTech Connect

    Liu, Bill Y.; Srivastava, V.J.; Paterek, J.R.; Pradhan, S.P.; Pope, J.R.; Hayes, T.D.; Linz, D.G.; Jerger, D.E.

    1993-12-31

    An overall protocol for remediating manufactured gas plant (MGP) soils generally includes bench-scale evaluation of the technology, pilot-scale demonstration, and full-scale implementation. This paper summarizes the results of the bench-scale and pilot-scale study for treating an MGP soil with IGT`s integrated Chemical/Biological Treatment (CBT) or Manufactured Gas Plant Remediation (MGP-REM) process in the slurry-phase mode of application. MGP soils are contaminated primarily with polynuclear aromatic hydrocarbons (PAHs). An MGP site in New Jersey was the subject of this study. Soils from the site were used for the bench-scale evaluation of the integrated Chemical/Biological Treatment. The bench-scale study started with biological pre-treatment followed by chemical treatment and biological polishing. Results of the bench-scale study showed that this process was effective in degrading EPA Total as well as EPA Carcinogenic PAHs. A test matrix was developed to assess this technology at a pilot-scale facility. The test matrix consisted of at least eight semi-continuous runs designed to evaluate the effects of PAH concentration, total solids concentration, residence time, and a number of chemical reagent additions. An operating permit for 14 days was obtained to evaluate the process primarily for air emission data and secondarily for PAH degradation data. The PAH data showed that the MGP-REM process was very effective in degrading carcinogenic PAHs even under sub-optimal operating conditions. The field data also showed that the emissions of volatile organic compounds were well below the regulatory limits.

  12. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Remedial Action Selection Report, Appendix B of Attachment 2: Geology report, Final

    SciTech Connect

    Not Available

    1994-03-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the US Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), 42 USC {section} 7901 et seq. Part of the UMTRCA requires that the US Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the US Environmental Protection Agency (EPA). Included in the RAP is this Remedial Action Selection Report (RAS), which describes the proposed remedial action for the Naturita site. An extensive amount of data and supporting information has been generated and evaluated for this remedial action. These data and supporting information are not incorporated into this single document but are included or referenced in the supporting documents. The RAP consists of this RAS and four supporting documents or attachments. This Attachment 2, Geology Report describes the details of geologic, geomorphic, and seismic conditions at the Dry Flats disposal site.

  13. Data and Information Management System for the ORNL Remedial Action Program

    SciTech Connect

    Voorhees, L.D.; Hook, L.A.; Gentry, M.J.; Owen, P.T.; Newman, K.A.; McCord, R.A.; Faulkner, M.A.; Bledsoe, J.L.

    1988-01-01

    A Remedial Action Program (RAP) was established in FY 1985 at Oak Ridge National Laboratory (ORNL) to provide corrective measures at areas contaminated with radioactive and/or hazardous chemical wastes. To achieve this goal, numerous and varied studies are being conducted to characterize the waste disposal sites. Environmental data collected in support of other programs at ORNL are also of use to RAP. Collectively, these studies are generating a voluminous amount of data on a scale unprecedented for ORNL. A computerized Data and Information Management System (DIMS) was developed to (1) provide a centralized repository for data pertinent to RAP and (2) provide support for the investigations and assessments leading to the long-term remediation of contaminated sites and facilities. The current DIMS and its role in supporting RAP are described. The DIMS consists of three components: (1) the Bibliographic Data Base, (2) the Records Control Data Base, and (3) the Numeric Data Base. This paper/poster emphasizes the Numeric Data Base, including its development and organization, and also summarizes the status of other activities associated with management and use of such data (i.e., bibliographic information, records control, geographic information, and quality assurance). The types of data currently available have been summarized, and a synopsis of the contents of the RAP numeric data base has been compiled in a menu-driven program available on PC diskettes. The synopsis will be demonstrated at the conference. 4 refs., 5 figs.

  14. Tank Waste Remediation System retrieval and disposal mission technical baseline summary description

    SciTech Connect

    McLaughlin, T.J.

    1998-01-06

    This document is prepared in order to support the US Department of Energy`s evaluation of readiness-to-proceed for the Waste Retrieval and Disposal Mission at the Hanford Site. The Waste Retrieval and Disposal Mission is one of three primary missions under the Tank Waste Remediation System (TWRS) Project. The other two include programs to characterize tank waste and to provide for safe storage of the waste while it awaits treatment and disposal. The Waste Retrieval and Disposal Mission includes the programs necessary to support tank waste retrieval, wastefeed, delivery, storage and disposal of immobilized waste, and closure of tank farms. This mission will enable the tank farms to be closed and turned over for final remediation. The Technical Baseline is defined as the set of science and engineering, equipment, facilities, materials, qualified staff, and enabling documentation needed to start up and complete the mission objectives. The primary purposes of this document are (1) to identify the important technical information and factors that should be used by contributors to the mission and (2) to serve as a basis for configuration management of the technical information and factors.

  15. Hot air vapor extraction system for remediation of petroleum contaminated sites

    SciTech Connect

    Pal, D.; Karr, L.; Fann, S.; Mathews, A.P.; Price, P.A.; Linginemi, S.

    1996-12-01

    This paper describes the results of a demonstration of a technology entitled ``Hot Air Vapor Extraction (HAVE)`` at the Hydrocarbon National Test Site (HNTS), Port Hueneme, California. The demonstration of the HAVE technology at HNTS was conducted over a 3-month period between August 21, 1995 and November 22, 1995 and the lessons learned from the demonstration are discussed in details to guide the Department of Defense decision makers in analyzing the applicability of this technology to their contaminated sites. This technology demonstration was conducted under the Department of Defense Strategic Environmental Research and Development Program (SERDP) as part of the National Environmental Technology Demonstration Program (NETDP). The primary objectives of the demonstration were to (1) validate the efficacy of the HAVE technology to treat a wide range of hydrocarbons contaminated soils, (2) gather data to estimate treatment costs, and (3) develop engineering guidance needed to apply this remediation technology DoD-wide. Test runs were made on 5 different treatment cells containing various fuel hydrocarbons, ranging from gasoline to heavier petroleum fractions such as lubricating oil. Computer modeling was conducted to analyze the test results and also to optimize the HAVE system design. An economic analysis conducted for various remediation project sizes ranging from 750 to 9,000 cubic yards, the per cubic yard treatment costs are found to vary from $64.05 down to $36.54 respectively.

  16. Vadose Zone Remediation Assessment: M-Area Process Sewer Soil Vapor Extraction Units 782-5M, 782-7M, and 782-8M

    SciTech Connect

    Riha, B.D.

    2001-04-20

    This study focuses on the status of the vadose zone remediation along 1600 ft of the process sewer line between the M-Area security fence and the M-Area settling basin. Three soil vapor extraction (SVE) units 782-5M, 782-7M, and 782-8M, connected to 4 vertical wells and 3 horizontal wells have been addressing the vadose zone volatile organic contamination (VOC) since 1995. The specific objectives of this study were to obtain soil gas and sediment samples, evaluate SVE units and vadose zone remediation, and make recommendations to address further remediation needs.

  17. Transparent materials processing system

    NASA Technical Reports Server (NTRS)

    Hetherington, J. S.

    1977-01-01

    A zero gravity processing furnace system was designed that will allow acquisition of photographic or other visual information while the sample is being processed. A low temperature (30 to 400 C) test model with a flat specimen heated by quartz-halide lamps was constructed. A high temperature (400 to 1000 C) test model heated by resistance heaters, utilizing a cylindrical specimen and optics, was also built. Each of the test models is discussed in detail. Recommendations are given.

  18. The Influence of Chinese Character Handwriting Diagnosis and Remedial Instruction System on Learners of Chinese as a Foreign Language

    ERIC Educational Resources Information Center

    Hsiao, Hsien-Sheng; Chang, Cheng-Sian; Chen, Chiao-Jia; Wu, Chia-Hou; Lin, Chien-Yu

    2015-01-01

    This study designed and developed a Chinese character handwriting diagnosis and remedial instruction (CHDRI) system to improve Chinese as a foreign language (CFL) learners' ability to write Chinese characters. The CFL learners were given two tests based on the CHDRI system. One test focused on Chinese character handwriting to diagnose the CFL…

  19. The Influence of Chinese Character Handwriting Diagnosis and Remedial Instruction System on Learners of Chinese as a Foreign Language

    ERIC Educational Resources Information Center

    Hsiao, Hsien-Sheng; Chang, Cheng-Sian; Chen, Chiao-Jia; Wu, Chia-Hou; Lin, Chien-Yu

    2015-01-01

    This study designed and developed a Chinese character handwriting diagnosis and remedial instruction (CHDRI) system to improve Chinese as a foreign language (CFL) learners' ability to write Chinese characters. The CFL learners were given two tests based on the CHDRI system. One test focused on Chinese character handwriting to diagnose the CFL…

  20. Risk-based systems analysis of emerging high-level waste tank remediation technologies. Volume 2: Final report

    SciTech Connect

    Peters, B.B.; Cameron, R.J.; McCormack, W.D.

    1994-08-01

    The objective of DOE`s Radioactive Waste Tank Remediation Technology Focus Area is to identify and develop new technologies that will reduce the risk and/or cost of remediating DOE underground waste storage tanks and tank contents. There are, however, many more technology investment opportunities than the current budget can support. Current technology development selection methods evaluate new technologies in isolation from other components of an overall tank waste remediation system. This report describes a System Analysis Model developed under the US Department of Energy (DOE) Office of Technology Development (OTD) Underground Storage Tank-Integrated Demonstration (UST-ID) program. The report identifies the project objectives and provides a description of the model. Development of the first ``demonstration`` version of this model and a trial application have been completed and the results are presented. This model will continue to evolve as it undergoes additional user review and testing.

  1. Evaluation of the assimilation of As by vegetables in contaminated soils submitted to a remediation process

    NASA Astrophysics Data System (ADS)

    Pérez-Sirvent, Carmen; Martinez Sanchez, Maria Jose; Agudo, Ines; Belen Martinez, Lucia; Bech, Jaume

    2016-04-01

    A greenhouse trial was carried out to evaluate the assimilation of heavy metals by three types of plants (lettuce, onion and broccoli), different parts of which are destined for human and farm animals consumption (leaves, roots, fruits). The experiments were carried out to check the validity of the use of calcareous materials to recover soils contaminated with heavy metals. The aim of this work was to apply a technology for decontamination to ensure that As do not enter into the trophic chain at risky levels and analyze and to assess the risk pre and post operational of the different treatments proposed. The materials used was a soils to be remediated (mining soils) and the materials used for remediation were lime filler and Construction and Demolition Waste (CDW). The plants were cultivated in greenhouse with several types of soil. Five experiments were used, namely, Tc (contaminated soil), T1 (uncontaminated soil (blank soil)), T2 (50% T1 + 50% Tc), T3 (Tc + (25%) lime residues coming from quarries) and T4 (Tc + (25%) residues coming from demolition and construction activities). The entire project involves twenty experiments which were prepared from soils highly contaminated mixed with two types of calcareous materials. The total As content of the soils samples, rhizosphere and vegetable samples, were measured and the translocation factor (TF), which is defined as the ratio of metal concentration in the leaves or shoots to the roots, and the Bioconcentration factor (BCF), which is defined as the ratio of metal concentration in the roots to that in soil were calculated. The use of CDR is shown to be a suitable way for remediating soils contaminated by metals. The methodology permits a revalorization of CDW.

  2. Optimization of Engineering Design of Subsurface Environmental Remediation Systems: Development and Testing of Community Benchmark Problems

    NASA Astrophysics Data System (ADS)

    Mayer, A. S.; Miller, C. T.

    2003-12-01

    It is well established that the design of economically efficient subsurface remediation systems can benefit from the joint use of formal optimization and simulation models. It is also well known that obtaining the optimal solution for such designs is usually difficult and computationally expensive, due to the characteristic nonlinear, nonconvex nature of the solution spaces. We believe that more rapid progress on optimal design methods might result from both improved methods of evaluation and comparison of existing methods on realistic problems and from the investigation of novel methods not yet studied in subsurface remediation field. This work responds to these needs. We have designed a set of systematic test problems to be attacked by the engineering and mathematics community, as a means for benchmarking and comparing optimization approaches. The test problems pose many of the difficulties anticipated in solving real-world problems such as (a) mixed continuous and integer, nonlinear objective functions, (b) the combination of boundary conditions and system parameters gives rise to complex relationships between the objective function, the decision variables, the constraints, and the state variables, (c) evaluation of the objective function is based on solving model equations that are difficult to solve accurately and quickly; and (d) the number and range of decision variables is potentially enormous. The physical problems include water supply design problems in freshwater and freshwater-saltwater systems, a contaminant plume capture zone design problem, and a contaminant plume pump-and-treat design problem. Problem domains are specified in terms of hydraulic conductivity distributions- from homogeneous domains to spatially-correlated random fields- and in terms of confined vs. unconfined conditions. Each problem is specified completely in mathematical and numerical terms, but sufficient flexibility is allowed to provide for a wide range of problem solution

  3. THERMAL REMEDIATION

    EPA Science Inventory

    Thermal remediation is being proposed by Region I for remediation of the overburden soil and groundwater at the Solvent Recovery Services New England Superfund site. This presentation at the public meeting will acquaint area residents with thermal remediation. The two types of ...

  4. THERMAL REMEDIATION

    EPA Science Inventory

    Thermal remediation is being proposed by Region I for remediation of the overburden soil and groundwater at the Solvent Recovery Services New England Superfund site. This presentation at the public meeting will acquaint area residents with thermal remediation. The two types of ...

  5. In-situ wastewater treatment and groundwater remediation at a sugar beet processing facility

    SciTech Connect

    Olson, J.L.; Fuller-Pratt, P.R.; Mielke, R.A.

    1996-06-01

    Groundwater monitoring data collected at the Western Sugar Company sugar beet processing plant, in Billings, Montana identified groundwater mounding and groundwater nitrogen concentration increases associated with lime slurry discharge to an on-site storage pile. The nitrogen impacts (primarily ammonia) likely originated through decomposition of organic matter in the slurry. Initially, Western Sugar considered constructing an expensive anaerobic and nitrification-denitrification wastewater treatment system. However, further investigation of the lime pile revealed that it was already serving as an efficient filter and anaerobic reactor. Comparisons of slurry application with other land application systems suggested that groundwater nitrogen impacts could be minimized through groundwater capture, re-application, and improved slurry management. The resultant system required little capitol and maintenance cost. The immediate effect was to substantially decrease the groundwater mound. Subsequent monitoring has demonstrated a gradual decline in nitrogen concentrations under the lime pile and a considerable concentration decrease downgradient of the groundwater recovery system.

  6. Quartz resonator processing system

    DOEpatents

    Peters, Roswell D. M.

    1983-01-01

    Disclosed is a single chamber ultra-high vacuum processing system for the oduction of hermetically sealed quartz resonators wherein electrode metallization and sealing are carried out along with cleaning and bake-out without any air exposure between the processing steps. The system includes a common vacuum chamber in which is located a rotatable wheel-like member which is adapted to move a plurality of individual component sets of a flat pack resonator unit past discretely located processing stations in said chamber whereupon electrode deposition takes place followed by the placement of ceramic covers over a frame containing a resonator element and then to a sealing stage where a pair of hydraulic rams including heating elements effect a metallized bonding of the covers to the frame.

  7. Tank waste remediation system FSAR hazard identification/facility configuration verification report

    SciTech Connect

    Mendoza, D.P., Westinghouse Hanford

    1996-05-01

    This document provides the results of the Tank Waste Remediation System Final Safety Analysis Report (TWRS FSAR) hazards identification/facility configuration activities undertaken from the period of March 7, 1996 to May 31, 1996. The purpose of this activity was to provide an independent overview of the TWRS facility specific hazards and configurations that were used in support of the TWRS FSAR hazards and accident analysis development. It was based on a review of existing published documentation and field inspections. The objective of the verification effort was to provide a `snap shot` in time of the existing TWRS facility hazards and configurations and will be used to support hazards and accident analysis activities.

  8. Causes and remedies for the dominant risk factors in Enterprise System implementation projects: the consultants' perspective.

    PubMed

    Lech, Przemysław

    2016-01-01

    The purpose of this research was to investigate the causes of the dominant risk factors, affecting Enterprise System implementation projects and propose remedies for those risk factors from the perspective of implementation consultants. The study used a qualitative research strategy, based on e-mail interviews, semi-structured personal interviews with consultants and participant observation during implementation projects. The main contribution of this paper is that it offers viable indications of how to mitigate the dominant risk factors. These indications were grouped into the following categories: stable project scope, smooth communication supported by the project management, dedicated, competent and decision-making client team, competent and engaged consultant project manager, schedule and budget consistent with the project scope, use of methodology and procedures, enforced and enabled by the project managers, competent and dedicated consultants. A detailed description is provided for each category.

  9. Log processing systems

    SciTech Connect

    Bowlin, W.P.; Kneer, M.P.; Ballance, J.D.

    1989-11-07

    This patent describes an improvement in a computer controlled processing system for lumber production. It comprises: a computer, a sequence of processing stations for processing a log segment including; an excess material removing station for generating opposed flat side surfaces on the log segment. The flat side surfaces determined by the computer to become sides of boards to be severed from the log segments; a profiling station for forming profiled edges above and below the flat side surfaces to become the side edges of the boards to be severed from the log segment, and a severing station for severing the boards from the log segments, a conveyance means establishing a path of conveyance and having continuous control of the log segment on conveying the log segment along the path and through the above defined sequence of processing stations.

  10. Remediation of acid mine drainage at the friendship hill national historic site with a pulsed limestone bed process

    USGS Publications Warehouse

    Sibrell, P.L.; Watten, B.; Boone, T.; ,

    2003-01-01

    A new process utilizing pulsed fluidized limestone beds was tested for the remediation of acid mine drainage at the Friendship Hill National Historic Site, in southwestern Pennsylvania. A 230 liter-per-minute treatment system was constructed and operated over a fourteen-month period from June 2000 through September 2001. Over this period of time, 50,000 metric tons of limestone were used to treat 50 million liters of water. The influent water pH was 2.5 and acidity was 1000 mg/L as CaCO3. Despite the high potential for armoring at the site, effluent pH during normal plant operation ranged from 5.7 to 7.8 and averaged 6.8. As a result of the high influent acidity, sufficient CO2 was generated and recycled to provide a net alkaline discharge with about 50 mg/L as CaCO3 alkalinity. Additions of commercial CO2 increased effluent alkalinity to as high as 300 mg/L, and could be a useful process management tool for transient high flows or acidities. Metal removal rates were 95% for aluminum (60 mg/L in influent), 50 to 90% for iron (Fe), depending on the ratio of ferrous to ferric iron, which varied seasonally (200 mg/L in influent), and <10% of manganese (Mn) (10 mg/L in influent). Ferrous iron and Mn removal was incomplete because of the high pH required for precipitation of these species. Iron removal could be improved by increased aeration following neutralization, and Mn removal could be effected by a post treatment passive settling/oxidation pond. Metal hydroxide sludges were settled in settling tanks, and then hauled from the site for aesthetic purposes. Over 450 metric tons of sludge were removed from the water over the life of the project. The dried sludge was tested by the Toxicity Characteristics Leaching Protocol (TCLP) and was found to be non-hazardous. Treatment costs were $43,000 per year and $1.08 per m 3, but could be decreased to $22,000 and $0.51 per m3 by decreasing labor use and by onsite sludge handling. These results confirm the utility of the new

  11. Telescoping Strategies for Improved Simulation-based Optimization of Environmental Remediation Systems

    NASA Astrophysics Data System (ADS)

    Hymiak, B.; Matott, L.

    2012-12-01

    Water contamination is a worldwide problem that is often addressed through simulation-based design and optimization of site-specific environmental remediation systems. Heuristic global search algorithms are particularly appropriate for such activity and have aided with the design of pump-and-treat systems and landfill liners, among others. However, many algorithms yield lackluster performance when computational budgets are restricted, as is often required in practice. This research explored the performance of a suite of 5 heuristic optimizers when applied to a diverse array of 45 optimization test functions. The test functions ranged in dimensionality from easily visualized 2-parameter surfaces to much more complex 100-parameter landscapes. Taken as a whole, these test functions are representative of the variety of cost surfaces encountered in real environmental remediation applications. Massively parallel numerical experiments were applied using the test suite, facilitating benchmark comparisons of the selected optimizers across a variety of restrictive computational budgets. Additional numerical experiments were performed to evaluate so-called "telescoping" strategies - a set of alternative range reduction techniques that work in conjunction with a given optimizer to scale the bounds of the search space in accordance with the remaining computational budget. Preliminary benchmarking results identify the shuffled complex evolutionary algorithm as delivering "best-in-class" performance for most of the test functions. However, the dynamically dimensioned search algorithm was notable for its stellar performance when applied to so-called 'deceptive' cost functions. Furthermore, in some cases the performances of several different algorithms were not statistically different. Finally, it appears that range-reduction strategies have a normalizing effect on algorithm performance in that they increase the frequency at which different algorithms yield statistically the same

  12. Radiation processing techniques in remediation of pollutants, and the role of the IAEA in supporting capacity building in developing countries

    NASA Astrophysics Data System (ADS)

    Haji-Saeid, S. Mohammad.; Sampa, M. H.; Safrany, A.; Sabharwal, S.; Ramamoorthy, N.

    2012-08-01

    Radiation treatment, or a combination of radiation with conventional biological-chemical-physical processes, can help in the remediation of contaminated surfaces and in combating industrial chemical effluents and air pollution. The use of ionizing radiation as a powerful tool for inactivation of microbes is a valuable option to address likely threats from biohazard contamination that could be introduced either deliberately or inadvertently into areas where the public are exposed to, as well as for treatment of volatile organic compounds and similar hazardous chemical agents is an emerging development in tackling harmful pollutants. The role of the IAEA has been crucial both in supporting the development of local capabilities as well as in fostering international cooperation due to the multidisciplinary expertise required for achieving sustainable benefits. The IAEA is implementing Coordinated Research Projects, (CRP) thematic topical reviews of issues and challenges involved, and Technical Cooperation (TC) assistance in establishing and maintaining infrastructure in the MS. This paper will give an insight into the above mentioned IAEA activities, with examples of successes achieved through CRPs, as well as challenges on the road for broader dissemination of radiation processing technology for environmental remediation.

  13. Radiological audit of remedial action activities at the processing sites Mexican Hat, Utah and Monument Valley, Arizona. Audit date: May 3--7, 1993, Final report

    SciTech Connect

    1993-05-01

    The Uranium Mill Tailings Remedial Action (UMTRA) Project`s Technical Assistance Contractor (TAC) performed a radiological audit of the Remedial Action Contractor (RAC), MK-Ferguson and CWM Federal Environmental Services, Inc., at the processing sites in Mexican Hat, Utah, and Monument Valley, Arizona. This audit was conducted May 3--7, 1993, by Bill James and Gerry Simiele of the TAC. Three site-specific findings and four observations were identified during the audit and are presented in this report. The overall conclusion from the audit is that the majority of the radiological aspects of the Mexican Hat, Utah, and Monument Valley, Arizona, remedial action programs are performed adequately. However, the findings identify that there is some inconsistency in following procedures and meeting requirements for contamination control, and a lack of communication between the RAC and the DOE on variances from the published remedial action plan (RAP).

  14. Effect of eco-remediation using planted floating bed system on nutrients and heavy metals in urban river water and sediment: a field study in China.

    PubMed

    Ning, Daliang; Huang, Yong; Pan, Ruisong; Wang, Fayuan; Wang, Hui

    2014-07-01

    To investigate the effect of the eco-remediation on nutrients and heavy metals in river water and sediment, a field study was carried out in a site of a 2-year eco-remediation mainly using planted floating bed system in an urban river in China. Before remediation, the tested properties of water and sediment in the will-be remediated area were not different from the control area, except higher concentrations of chemical oxygen demand (COD) and total nitrogen (TN) in the river water. After remediation, the remediation area showed effective removal of in-stream nutrients and elevation of dissolved oxygen and transparency. Compared to the control area, the remediation area had higher concentration of nitrate and lower concentrations of COD, ammonium, Mn and hexavalent Cr in the river water after a 2-year remediation. The remediation area also showed higher concentrations of organic carbon, TN, nitrate, sulfate, Fe, Cu, Pb and Zn in the sediment than in the control area. Accordingly, special attention should be paid to the ecological risk of heavy metals in sediments and plants in river eco-remediation projects especially in rivers polluted by heavy metals, although the metals were lower than the level of considerable ecological risk in this study.

  15. Managing soil remediation problems.

    PubMed

    Okx, J P; Hordijk, L; Stein, A

    1996-12-01

    Soil remediation has only a short history but the problem addressed is a significant one. Cost estimates for the clean-up of contaminated sites in the European Union and the United States are in the order of magnitude of 1,400 billion ECU. Such an enormous operation deserves the best management it can get. Reliable cost estimations per contaminated site are an important prerequisite. This paper addresses the problems related to site-wise estimations.When solving soil remediation problems, we have to deal with a large number of scientific disciplines. Too often solutions are presented from the viewpoint of only one discipline. In order to benefit from the combined disciplinary knowledge and experience, we think that it is necessary to describe the interrelations between these disciplines. This can be realized by developing an adequate model of the desired process which enables to consider and evaluate the essential factors as interdependent components of the total system.The resulting model provides a binding paradigm to the contributing disciplines which will result in improved efficiency and effectivity of the decision and the cost estimation process. In the near future, we will release the "Biosparging and Bioventing Expert Support System", an expert support system for problem owners, consultants and authorities dealing with the design and operation of a biosparging and/or a bioventing system.

  16. A two-stage process using electrokinetic remediation and electrochemical degradation for treating benzo[a]pyrene spiked kaolin.

    PubMed

    Gómez, J; Alcántara, M T; Pazos, M; Sanromán, M A

    2009-03-01

    An innovative process that combines soil electrokinetic remediation and liquid electrochemical oxidation for the degradation of organic compounds present in a polluted soil was developed and evaluated by using benzo[a]pyrene spiked kaolin. In order to increase benzo[a]pyrene solubility during electrokinetic treatment, the addition of a co-solvent or surfactant, such as ethanol or Brij 35, as flushing solution was tested. The research carried out demonstrated the influence of the desorption agent employed on benzo[a]pyrene remediation from the kaolin matrix. Thus, if the flushing solution was ethanol at 40%, there was no presence of contaminant in either chamber. On the contrary, when a solution of surfactant Brij 35 was used, benzo[a]pyrene was transported towards the cathode chamber, where it was collected. Moreover, the extent of this recovery depends on the pH profile on the soil. When no pH control was used, around 17% of initial contaminant was detected in the cathode chamber; however, when pH control was applied, the recovery of benzo[a]pyrene could be higher than 76%, when the pH control in the anode chamber was set at 7.0. In order to obtain the total degradation of mobilised benzo[a]pyrene from the contaminated soil, the liquid collected by electrokinetic remediation was oxidised by electrochemical treatment. This oxidation was accomplished via an electrochemical cell with a working volume of 0.4 L, and graphite as electrode material. The benzo[a]pyrene was almost totally degraded in 1d, reaching a degradation of about 73% in 16 h.

  17. Remediation Performance and Mechanism of Heavy Metals by a Bottom Up Activation and Extraction System Using Multiple Biochemical Materials.

    PubMed

    Xiao, Kemeng; Li, Yunzhen; Sun, Yang; Liu, Ruyue; Li, Junjie; Zhao, Yun; Xu, Heng

    2017-09-13

    Soil contamination with heavy metals has caused serious environmental problems and increased the risks to humans and biota. Herein, we developed an effective bottom up metals removal system based on the synergy between the activation of immobilization metal-resistant bacteria and the extraction of bioaccumulator material (Stropharia rugosoannulata). In this system, the advantages of biochar produced at 400 °C and sodium alginate were integrated to immobilize bacteria. Optimized by response surface methodology, the biochar and bacterial suspension were mixed at a ratio of 1:20 (w:v) for 12 h when 2.5% sodium alginate was added to the mixture. Results demonstrated that the system significantly increased the proportion of acid soluble Cd and Cu and improved the soil microecology (microbial counts, soil respiration, and enzyme activities). The maximum extractions of Cd and Cu were 8.79 and 77.92 mg kg(-1), respectively. Moreover, details of the possible mechanistic insight into the metal removal are discussed, which indicate positive correlation with the acetic acid extractable metals and soil microecology. Meanwhile, the "dilution effect" in S. rugosoannulata probably plays an important role in the metal removal process. Furthermore, the metal-resistant bacteria in this system were successfully colonized, and the soil bacteria community were evaluated to understand the microbial diversity in metal-contaminated soil after remediation.

  18. Remediation System Evaluation, Vineland Chemical Company Superfund Site, Vineland, New Jersey

    EPA Pesticide Factsheets

    The Vineland Chemical Company Superfund Site was selected by EPA OSRTI based on recommendations from the EPA Remedial Project Manager for the site and from the U.S. Army Corps of Engineers (USACE) Philadelphia District that provides oversight of remedial..

  19. Advanced information processing system

    NASA Technical Reports Server (NTRS)

    Lala, J. H.

    1984-01-01

    Design and performance details of the advanced information processing system (AIPS) for fault and damage tolerant data processing on aircraft and spacecraft are presented. AIPS comprises several computers distributed throughout the vehicle and linked by a damage tolerant data bus. Most I/O functions are available to all the computers, which run in a TDMA mode. Each computer performs separate specific tasks in normal operation and assumes other tasks in degraded modes. Redundant software assures that all fault monitoring, logging and reporting are automated, together with control functions. Redundant duplex links and damage-spread limitation provide the fault tolerance. Details of an advanced design of a laboratory-scale proof-of-concept system are described, including functional operations.

  20. The Effectiveness of Peer Tutoring in Remedying Misconceptions of Operating System Concepts: A Design-Based Approach

    ERIC Educational Resources Information Center

    Çakiroglu, Ünal; Öngöz, Sakine

    2017-01-01

    This study attempted to examine students' experiences on collaborative work with peer tutoring in projects. The study also focused impact of peer tutoring on remedying misconceptions. The study was conducted in the context of an operating system course in which 30 pre-service ICT teachers are the participants. Data were gathered from pre-tests,…

  1. The Effect on Ecological Systems of Remediation to Protect Human Health

    PubMed Central

    Burger, Joanna

    2007-01-01

    Environmental remediation of contaminated eco-sytems reduces stresses to these ecosystems, including stresses caused by the production, use, and storage of weapons of mass destruction. The effects of these various stressors on humans can be reduced by remediation or by blocking the exposure of humans, but blocking the exposure of resident biota is almost impossible. Remediation may involve trade-offs between reducing a minor risk to public health and increasing risks to workers and ecosystems. Remediation practices such as soil removal disrupt ecosystems, which take decades to recover. Without further human disturbances, and with low levels of exposure to stress-ors, ecosystems can recover from physical disruptions and spills. Remediation to remove negligible risk to humans can destroy delicate ecosystems for very little gain in public health. PMID:17666693

  2. Influence of multiple stressors on the auto-remediation processes occurring in salt marshes.

    PubMed

    Sousa, Ana I; Lillebø, Ana I; Pardal, Miguel A; Caçador, Isabel

    2011-07-01

    Due to increasing global population, salt marshes have been subjected to multiple stressors such as increasing nutrient loadings and historical contamination. In order to better understand how does the salt marsh plants auto-remediation capacity (phytoaccumulation of metals) is affected by cultural eutrophication, an experiment was performed under controlled conditions. Plants were exposure to equal metal concentrations (Zn, Cu, and Ni - micronutrients, and Cd - class B metal) simulating historical contamination and three different concentrations of nitrogen (nitrate) simulating steps of cultural eutrophication. According to our study, under the tested concentrations, cultural eutrophication does not seem to affect Zn, Cu and Ni phytoremediation of H. portulacoides, but the ecosystem service of Cd phytoremediation seems to be promoted. Nevertheless, Cd high toxicity and bioaccumulation should be taken into account, as well as the vulnerability of salt marsh ecosystems, whose reduction will have drastic consequences to the ecosystem health.

  3. Integrating long-term stewardship goals into the remediation process: natural resource damages and the Department of Energy.

    PubMed

    Burger, Joanna; Gochfeld, Michael; Powers, Charles W

    2007-01-01

    The United States and other developed countries are faced with restoring and managing degraded ecosystems. Evaluations of the degradation of ecological resources can be used for determining ecological risk, making remediation or restoration decisions, aiding stakeholders with future land use decisions, and assessing natural resource damages. Department of Energy (DOE) lands provide a useful case study for examining degradation of ecological resources in light of past or present land uses and natural resource damage assessment (NRDA). We suggest that past site history should be incorporated into the cleanup and restoration phase to reduce the ultimate NRDA costs, and hasten resource recovery. The lands that DOE purchased over 50 years ago ranged from relatively undisturbed to heavily impacted farmland, and the impact that occurred from DOE occupation varies from regeneration of natural ecosystems (benefits) to increased exposure to several stressors (negative effects). During the time of the DOE releases, other changes occurred on the lands, including recovery from the disturbance effects of farming, grazing, and residential occupation, and the cessation of human disturbance. Thus, the injury to natural resources that occurred as a result of chemical and radiological releases occurred on top of recovery of already degraded systems. Both spatial (size and dispersion of patch types) and temporal (past/present/future land use and ecological condition) components are critical aspects of resource evaluation, restoration, and NRDA. For many DOE sites, integrating natural resource restoration with remediation to reduce or eliminate the need for NRDA could be a win-win situation for both responsible parties and natural resource trustees by eliminating costly NRDAs by both sides, and by restoring natural resources to a level that satisfies the trustees, while being cost-effective for the responsible parties. It requires integration of remediation, restoration, and end

  4. Remediation of uranium-contaminated soil using the Segmented Gate System and containerized vat leaching techniques: a cost effectiveness study

    SciTech Connect

    Cummings, M.; Booth, S.R.

    1996-09-01

    Because it is difficult to characterize heterogeneously contaminated soils in detail and to excavate such soils precisely using heavy equipment, it is common for large quantities of uncontaminated soil to be removed during excavation of contaminated sites. Until now, volume reduction of radioactively contaminated soil depended upon manual screening and analysis of samples, a costly and impractical approach, particularly with large volumes of heterogeneously contaminated soil. The baseline approach for the remediation of soils containing radioactive waste is excavation, pretreatment, containerization, and disposal at a federally permitted landfill. However, disposal of low-level radioactive waste is expensive and storage capacity is limited. ThermoNuclean`s Segmented Gate System (SGS) removes only the radioactively contaminated soil, in turn greatly reducing the volume of soils that requires disposal. After processing using the SGS, the fraction of contaminated soil is processed using the containerized vat leaching (CVL) system developed at LANL. Uranium is leached out of the soil in solution. The uranium is recovered with an ion exchange resin, leaving only a small volume of liquid low-level waste requiring disposal. The reclaimed soil can be returned to its original location after treatment with CVL.

  5. Innovative Vitrification for Soil Remediation

    SciTech Connect

    Hnat, James G.; Patten, John S.; Jetta, Norman W.

    1996-12-31

    Vortec has successfully completed Phases 1 and 2 of a technology demonstration program for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation.'' The principal objective of the program is to demonstrate the ability of a Vortec Cyclone Melting System (CMS) to remediate DOE contaminated soils and other waste forms containing TM RCRA hazardous materials, low levels of radionuclides and TSCA (PCB) containing wastes. The demonstration program will verify the ability of this vitrification process to produce a chemically stable glass final waste form which passes both TCLP and PCT quality control requirements, while meeting all federal and state emission control regulations. The demonstration system is designed to process 36 ton/day of as-received drummed or bulk wastes. The processing capacity equates to approximately 160 barrels/day of waste materials containing 30% moisture at an average weight of 450 lbs./barrel.

  6. The implications of integrated assessment and modelling studies for the future remediation of chromite ore processing residue disposal sites.

    PubMed

    Farmer, J G; Paterson, E; Bewley, R J F; Geelhoed, J S; Hillier, S; Meeussen, J C L; Lumsdon, D G; Thomas, R P; Graham, M C

    2006-05-01

    Chromite ore processing residue (COPR) waste from a former chromium chemical works (1830-1968) is still contaminating groundwater in Glasgow, Scotland, with carcinogenic hexavalent chromium, Cr(VI). An integrated analytical, experimental and modelling approach has identified and accounted for mineral phases and processes responsible for the retention and release of Cr(VI) under prevailing field conditions. Both the nature of mineral phase retention and the buffered high pH of the sites, however, militate against direct remediative treatment of the source material, for example by the application of generic methods (e.g. FeSO4) that have been successfully employed elsewhere for the reduction of Cr(VI) to Cr(III) in other matrices. The interception and treatment of groundwater to remove Cr(VI) and the capping of sites to reduce human exposure to airborne Cr(VI)-contaminated dust may well be more realistic and effective, at least in the short to medium term.

  7. Nonlinear dynamical systems effects of homeopathic remedies on multiscale entropy and correlation dimension of slow wave sleep EEG in young adults with histories of coffee-induced insomnia.

    PubMed

    Bell, Iris R; Howerter, Amy; Jackson, Nicholas; Aickin, Mikel; Bootzin, Richard R; Brooks, Audrey J

    2012-07-01

    Investigators of homeopathy have proposed that nonlinear dynamical systems (NDS) and complex systems science offer conceptual and analytic tools for evaluating homeopathic remedy effects. Previous animal studies demonstrate that homeopathic medicines alter delta electroencephalographic (EEG) slow wave sleep. The present study extended findings of remedy-related sleep stage alterations in human subjects by testing the feasibility of using two different NDS analytic approaches to assess remedy effects on human slow wave sleep EEG. Subjects (N=54) were young adult male and female college students with a history of coffee-related insomnia who participated in a larger 4-week study of the polysomnographic effects of homeopathic medicines on home-based all-night sleep recordings. Subjects took one bedtime dose of a homeopathic remedy (Coffea cruda or Nux vomica 30c). We computed multiscale entropy (MSE) and the correlation dimension (Mekler-D2) for stages 3 and 4 slow wave sleep EEG sampled in artifact-free 2-min segments during the first two rapid-eye-movement (REM) cycles for remedy and post-remedy nights, controlling for placebo and post-placebo night effects. MSE results indicate significant, remedy-specific directional effects, especially later in the night (REM cycle 2) (CC: remedy night increases and post-remedy night decreases in MSE at multiple sites for both stages 3 and 4 in both REM cycles; NV: remedy night decreases and post-remedy night increases, mainly in stage 3 REM cycle 2 MSE). D2 analyses yielded more sporadic and inconsistent findings. Homeopathic medicines Coffea cruda and Nux vomica in 30c potencies alter short-term nonlinear dynamic parameters of slow wave sleep EEG in healthy young adults. MSE may provide a more sensitive NDS analytic method than D2 for evaluating homeopathic remedy effects on human sleep EEG patterns. Copyright © 2012 The Faculty of Homeopathy. Published by Elsevier Ltd. All rights reserved.

  8. Nonlinear Dynamical Systems Effects of Homeopathic Remedies on Multiscale Entropy and Correlation Dimension of Slow Wave Sleep EEG in Young Adults with Histories of Coffee-Induced Insomnia

    PubMed Central

    Bell, Iris R.; Howerter, Amy; Jackson, Nicholas; Aickin, Mikel; Bootzin, Richard R.; Brooks, Audrey J.

    2012-01-01

    Background Investigators of homeopathy have proposed that nonlinear dynamical systems (NDS) and complex systems science offer conceptual and analytic tools for evaluating homeopathic remedy effects. Previous animal studies demonstrate that homeopathic medicines alter delta electroencephalographic (EEG) slow wave sleep. The present study extended findings of remedy-related sleep stage alterations in human subjects by testing the feasibility of using two different NDS analytic approaches to assess remedy effects on human slow wave sleep EEG. Methods Subjects (N=54) were young adult male and female college students with a history of coffee-related insomnia who participated in a larger 4-week study of the polysomnographic effects of homeopathic medicines on home-based all-night sleep recordings. Subjects took one bedtime dose of a homeopathic remedy (Coffea cruda or Nux vomica 30c). We computed multiscale entropy (MSE) and the correlation dimension (Mekler-D2) for stage 3 and 4 slow wave sleep EEG sampled in artifact-free 2-minute segments during the first two rapid-eye-movement (REM) cycles for remedy and post-remedy nights, controlling for placebo and post-placebo night effects. Results MSE results indicate significant, remedy-specific directional effects, especially later in the night (REM cycle 2) (CC: remedy night increases and post-remedy night decreases in MSE at multiple sites for both stages 3 and 4 in both REM cycles; NV: remedy night decreases and post-remedy night increases, mainly in stage 3 REM cycle 2 MSE). D2 analyses yielded more sporadic and inconsistent findings. Conclusions Homeopathic medicines Coffea cruda and Nux vomica in 30c potencies alter short-term nonlinear dynamic parameters of slow wave sleep EEG in healthy young adults. MSE may provide a more sensitive NDS analytic method than D2 for evaluating homeopathic remedy effects on human sleep EEG patterns. PMID:22818237

  9. Remediating Common Math Errors.

    ERIC Educational Resources Information Center

    Wagner, Rudolph F.

    1981-01-01

    Explanations and remediation suggestions for five types of mathematics errors due either to perceptual or cognitive difficulties are given. Error types include directionality problems, mirror writing, visually misperceived signs, diagnosed directionality problems, and mixed process errors. (CL)

  10. Floating rice-culture system for nutrient remediation and feed production in a eutrophic lake.

    PubMed

    Srivastava, Ankita; Chun, Seong-Jun; Ko, So-Ra; Kim, Junhwan; Ahn, Chi-Yong; Oh, Hee-Mock

    2017-12-01

    The increased inputs of nutrients have been demonstrated to be a major contributing factor to the eutrophication of lakes and reservoirs which can lead to the production of harmful algal/cyanobacterial blooms and deleteriously affect the aesthetics of water-bodies. Floating plant-culture systems have been widely used for the ecological remediation of eutrophic water in a cost-effective manner. We investigated the applicability of Korean japonica rice variety 'Nampyeong' in a floating-culture system in a eutrophic lake for nutrient uptake and biomass production. Chemical and organic compound compositions were analyzed two times during the growth stages of the rice plant: 98 DAT (days after transplanting) and 165 DAT. Total nitrogen and phosphorus contributed around 1.36 and 0.15 (% dry weight), respectively, in rice plant components at 165 DAT. Crude protein, lipids, fiber and ash were 4.35, 1.91, 23.66 and 5.55 (% dry weight), respectively. In addition, microcystin levels in the rice plant components ranged from 0.0008 to 0.002 μg/g and did not exceed the recommended tolerable limits. These results suggested that the developed floating rice-culture system showed a good potential as a holistic management approach in terms of nutrient reduction, rice production for further use as feed and for bloom control. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Genesis Eco Systems, Inc. soil washing process

    SciTech Connect

    Cena, R.J.

    1994-10-11

    The Genesis soil washing system is an integrated system of modular design allowing for maximum material handling capabilities, with optimized use of space for site mobility. The Surfactant Activated Bio-enhanced Remediation Equipment-Generation 1 (SABRE-1, Patent Applied For) modification was developed specifically for removing petroleum byproducts from contaminated soils. Scientifically formulated surfactants, introduced by high pressure spray nozzles, displace the contaminant from the surface of the soil particles into the process solution. Once the contaminant is dispersed into the liquid fraction of the process, it is either mechanically removed, chemically oxidized, or biologically oxidized. The contaminated process water is pumped through the Genesis Biosep (Patent Applied For) filtration system where the fines portion is flocculated, and the contaminant-rich liquid portion is combined with an activated mixture of nutrients and carefully selected bacteria to decompose the hydrocarbon fraction. The treated soil and dewatered fines are transferred to a bermed stockpile where bioremediation continues during drying. The process water is reclaimed, filtered, and recycled within the system.

  12. Risk-based systems analysis of emerging high-level waste tank remediation technologies. Volume 1: Executive summary

    SciTech Connect

    Peters, B.B.; Cameron, R.J.; McCormack, W.D.

    1994-08-01

    This report describes a System Analysis Model developed under the US Department of Energy (DOE) Office of Technology Development (OTD) Underground Storage Tank-Integrated Demonstration (UST-ID) program to aid technology development funding decisions for radioactive tank waste remediation. Current technology development selection methods evaluate new technologies in isolation from other components of an overall tank waste remediation system. These methods do not show the relative effect of new technologies on tank remediation systems as a whole. Consequently, DOE may spend its resources on technologies that promise to improve a single function but have a small or possibly negative, impact on the overall system, or DOE may overlook a technology that does not address a high priority problem in the system but that does, if implemented, offer sufficient overall improvements. Systems engineering and detailed analyses often conducted under the National Environmental Policy Act (NEPA 1969) use a ``whole system`` approach but are costly, too time-consuming, and often not sufficiently focused to support the needs of the technology program decision-makers. An alternative approach is required to evaluate these systems impacts but still meet the budget and schedule needs of the technology program.

  13. Assessment and remediation of an auditory processing disorder associated with head trauma.

    PubMed

    Musiek, Frank E; Baran, Jane A; Shinn, Jennifer

    2004-02-01

    This case study involves a 41-year-old female who had sustained a mild traumatic brain injury during a horseback riding accident. The patient was seen for medical and neuropsychological testing following this incident and was referred to a speech-language pathologist for rehabilitative services. At 13 months posttrauma, the patient, who was frustrated by a lack of significant progress, requested an audiologic work-up. Results of testing conducted at this time revealed normal peripheral hearing and significant central auditory deficits. Based on these findings, an auditory rehabilitation program was developed and implemented. The components of this patient's rehabilitation program are reviewed, and the posttherapy improvements noted in her auditory functions are detailed. The case is important in that it demonstrates (1) that auditory deficits can be a sequel to minor head injury, (2) that these deficits are often subtle and may not be detected unless central auditory testing is conducted, and (3) that these deficits may be amenable to remediation.

  14. Tank waste remediation system fiscal year 1997 multi-year workplan WBS 1.1

    SciTech Connect

    Wilson, C.E.

    1996-09-23

    The U.S. Department of Energy (DOE) established the Tank Waste Remediation System (TWRS) Program to manage and immobilize for disposal the waste contained in underground storage tanks at the Hanford Site. The TWRS program was established as a DOE major system acquisition under an approved Justification of Mission Need (JMN) dated January 19, 1993. The JMN states that the purpose of the TWRS Program is to: Resolve the tank waste safety issues; Integrate the waste disposal mission with the ongoing waste management mission; Assess the technical bases for tank waste management and disposal; Determine the technology available and develop any needed technologies; and Establish a dedicated organization and provide the resources to meet the technical challenge. The principal objectives of management of existing and future tank wastes is to cost-effectively minimize the environmental, safety, and health risks associated with stored wastes, with reduction of safety risks given the highest priority. The potentials must be minimized for release of tank wastes to the air and to the ground (and subsequently to the groundwater) and for exposure of the operating personnel to tank wastes.

  15. Engineering biogenic magnetite for sustained Cr(VI) remediation in flow-through systems.

    PubMed

    Crean, Daniel E; Coker, Victoria S; van der Laan, Gerrit; Lloyd, Jonathan R

    2012-03-20

    In this work, we report a route to enhance the reactivity and longevity of biogenic magnetite in Cr(VI) remediation under continuous-flow conditions by combining functionalization of the biomagnetite surface with a precious metal catalyst, nanoscale palladium, and exposure to formate. Column influent conditions were varied to simulate oxic, anoxic, and nitrate cocontaminated environments. The addition of sodium formate as an electron donor for Pd-functionalized magnetite increased capacity and longevity allowing 80% removal of Cr(VI) after 300 h in anoxic conditions, whereas complete breakthrough occurred after 60 h in anoxic nonformate and nonfunctionalized systems. Removal of Cr(VI) was optimized under anoxic conditions, and the presence of oxidizing agents results in a modest loss in reductive capacity. Examination of reacted Pd-functionalized magnetite reveals close association of Fe with Cr, suggesting that Pd-coupled oxidation of formate serves to regenerate the reactive surface. XMCD studies revealed that Cr(III) is partially substituted for Fe in the magnetite structure, which serves to immobilize Cr. No evidence for a mechanistic interference by nitrate cocontamination was observed, suggesting that this novel system could provide robust, effective and sustained reduction of contaminants, even in the presence of common oxidizing cocontaminants, outperforming the reductive capacity of nonfunctionalized biogenic magnetite.

  16. Tank Waste Remediation System fiscal year 1996 multi-year program plan WBS 1.1. Revision 1, Appendix A

    SciTech Connect

    1995-09-01

    This document is a compilation of data relating to the Tank Waste Remediation System Multi-Year Program. Topics discussed include: management systems; waste volume, transfer and evaporation management; transition of 200 East and West areas; ferricyanide, volatile organic vapor, and flammable gas management; waste characterization; retrieval from SSTs and DSTs; heat management; interim storage; low-level and high-level radioactive waste management; and tank farm closure.

  17. Finding of no significant impact proposed remedial action at two uranium processing sites near Slick Rock, Colorado

    SciTech Connect

    Not Available

    1994-10-01

    The U.S. Department of Energy (DOE) has prepared an environmental assessment (EA) (DOE/EA-0339) of the proposed remedial action at two uranium processing sites near Slick Rock in San Miguel County, Colorado. These sites contain radioactively contaminated materials that would be removed and stabilized at a remote location. Based on the information and analyses in the EA, the DOE has determined that the proposed action does not constitute a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 U.S.C. 4321 et seq.), as amended. Therefore, preparation of an environmental impact statement is not required, and the DOE is issuing this Finding of No Significant Impact (ONSI).

  18. Remediation of hexavalent chromium contamination in chromite ore processing residue by sodium dithionite and sodium phosphate addition and its mechanism.

    PubMed

    Li, Yunyi; Cundy, Andrew B; Feng, Jingxuan; Fu, Hang; Wang, Xiaojing; Liu, Yangsheng

    2017-05-01

    Large amounts of chromite ore processing residue (COPR) wastes have been deposited in many countries worldwide, generating significant contamination issues from the highly mobile and toxic hexavalent chromium species (Cr(VI)). In this study, sodium dithionite (Na2S2O4) was used to reduce Cr(VI) to Cr(III) in COPR containing high available Fe, and then sodium phosphate (Na3PO4) was utilized to further immobilize Cr(III), via a two-step procedure (TSP). Remediation and immobilization processes and mechanisms were systematically investigated using batch experiments, sequential extraction studies, X-ray diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS). Results showed that Na2S2O4 effectively reduced Cr(VI) to Cr(III), catalyzed by Fe(III). The subsequent addition of Na3PO4 further immobilized Cr(III) by the formation of crystalline CrPO4·6H2O. However, addition of Na3PO4 simultaneously with Na2S2O4 (via a one-step procedure, OSP) impeded Cr(VI) reduction due to the competitive reaction of Na3PO4 and Na2S2O4 with Fe(III). Thus, the remediation efficiency of the TSP was much higher than the corresponding OSP. Using an optimal dosage in the two-step procedure (Na2S2O4 at a dosage of 12× the stoichiometric requirement for 15 days, and then Na3PO4 in a molar ratio (i.e. Na3PO4: initial Cr(VI)) of 4:1 for another 15 days), the total dissolved Cr in the leachate determined via Toxicity Characteristic Leaching Procedure (TCLP Cr) testing of our samples was reduced to 3.8 mg/L (from an initial TCLP Cr of 112.2 mg/L, i.e. at >96% efficiency).

  19. Mars Aqueous Processing System

    NASA Technical Reports Server (NTRS)

    Berggren, Mark; Wilson, Cherie; Carrera, Stacy; Rose, Heather; Muscatello, Anthony; Kilgore, James; Zubrin, Robert

    2012-01-01

    The goal of the Mars Aqueous Processing System (MAPS) is to establish a flexible process that generates multiple products that are useful for human habitation. Selectively extracting useful components into an aqueous solution, and then sequentially recovering individual constituents, can obtain a suite of refined or semi-refined products. Similarities in the bulk composition (although not necessarily of the mineralogy) of Martian and Lunar soils potentially make MAPS widely applicable. Similar process steps can be conducted on both Mars and Lunar soils while tailoring the reaction extents and recoveries to the specifics of each location. The MAPS closed-loop process selectively extracts, and then recovers, constituents from soils using acids and bases. The emphasis on Mars involves the production of useful materials such as iron, silica, alumina, magnesia, and concrete with recovery of oxygen as a byproduct. On the Moon, similar chemistry is applied with emphasis on oxygen production. This innovation has been demonstrated to produce high-grade materials, such as metallic iron, aluminum oxide, magnesium oxide, and calcium oxide, from lunar and Martian soil simulants. Most of the target products exhibited purities of 80 to 90 percent or more, allowing direct use for many potential applications. Up to one-fourth of the feed soil mass was converted to metal, metal oxide, and oxygen products. The soil residue contained elevated silica content, allowing for potential additional refining and extraction for recovery of materials needed for photovoltaic, semiconductor, and glass applications. A high-grade iron oxide concentrate derived from lunar soil simulant was used to produce a metallic iron component using a novel, combined hydrogen reduction/metal sintering technique. The part was subsequently machined and found to be structurally sound. The behavior of the lunar-simulant-derived iron product was very similar to that produced using the same methods on a Michigan iron

  20. Modeling lead bioavailability and bioaccumulation by Lumbriculus variegatus using artificial particles. Potential use in chemical remediation processes.

    PubMed

    Miño, Lelia A; Folco, Sabina; Pechén de D'Angelo, Ana M; Verrengia Guerrero, Noemí R

    2006-04-01

    Artificial particles, specifically a diverse selection of chromatographical resins, have been recommended and used as a useful experimental model to predict the bioavailability and bioaccumulation of sediment-bound organic chemicals. In this work the same experimental model was adopted to investigate the bioavailability and bioaccumulation of lead by the freshwater oligochaete Lumbriculus variegatus. Particle-water partition coefficients were also determined. Sand particles and the anionic exchange resin promoted a similar uptake and bioaccumulation of lead. Instead, in the presence of the cationic exchanger the metal was not detected in the animals. For neutral particles, the uptake and accumulation depended on the chemistry of the functional groups at the active sites. In addition, a significant negative correlation was found between bioaccumulation and the particle-water partition coefficients. These studies may help to develop alternative methods for chemical remediation of lead-contaminated aquatic systems.

  1. Tank waste remediation system year 2000 dedicated file server project HNF-3418 project plan

    SciTech Connect

    SPENCER, S.G.

    1999-04-26

    The Server Project is to ensure that all TWRS supporting hardware (fileservers and workstations) will not cause a system failure because of the BIOS or Operating Systems cannot process Year 2000 dates.

  2. Remedial action plan for the inactive uranium processing site at Naturita, Colorado. Remedial action selection report: Attachment 2, geology report; Attachment 3, ground water hydrology report; Attachment 4, supplemental information

    SciTech Connect

    1998-03-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the U.S. Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), 42 USC {section} 7901 et seq. Part of the UMTRCA requires that the U.S. Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the U.S. Environmental Protection Agency (EPA). This RAP serves two purposes. First, it describes the activities that are proposed by the DOE to accomplish remediation and long-term stabilization and control of the radioactive materials at the inactive uranium processing site near Naturita, Colorado. Second, this RAP, upon concurrence and execution by the DOE, the state of Colorado, and the NRC, becomes Appendix B of the cooperative agreement between the DOE and the state of Colorado.

  3. Supplemental Assessment of the Y-12 Groundwater Protection Program Using Monitoring and Remediation Optimization System Software

    SciTech Connect

    Elvado Environmental LLC; GSI Environmental LLC

    2009-01-01

    A supplemental quantitative assessment of the Groundwater Protection Program (GWPP) at the Y-12 National Security Complex (Y-12) in Oak Ridge, TN was performed using the Monitoring and Remediation Optimization System (MAROS) software. This application was previously used as part of a similar quantitative assessment of the GWPP completed in December 2005, hereafter referenced as the 'baseline' MAROS assessment (BWXT Y-12 L.L.C. [BWXT] 2005). The MAROS software contains modules that apply statistical analysis techniques to an existing GWPP analytical database in conjunction with hydrogeologic factors, regulatory framework, and the location of potential receptors, to recommend an improved groundwater monitoring network and optimum sampling frequency for individual monitoring locations. The goal of this supplemental MAROS assessment of the Y-12 GWPP is to review and update monitoring network optimization recommendations resulting from the 2005 baseline report using data collected through December 2007. The supplemental MAROS assessment is based on the findings of the baseline MAROS assessment and includes only the groundwater sampling locations (wells and natural springs) currently granted 'Active' status in accordance with the Y-12 GWPP Monitoring Optimization Plan (MOP). The results of the baseline MAROS assessment provided technical rationale regarding the 'Active' status designations defined in the MOP (BWXT 2006). One objective of the current report is to provide a quantitative review of data collected from Active but infrequently sampled wells to confirm concentrations at these locations. This supplemental MAROS assessment does not include the extensive qualitative evaluations similar to those presented in the baseline report.

  4. Countercurrent soil washing system for remediation of viscous hydrocarbons, heavy metals, radionuclides

    SciTech Connect

    Kuhlman, M.I.; Karlsson, M.K.; Downie, C.A.

    1995-12-31

    Drying augers and multicell DAF tanks are excellent machines in which to countercurrently wash soil and remove hazardous hydrocarbons, metals or radionuclides. An auger works well because it preferentially moves soil along one side of its trough. Thus, when enough high pressure and temperature water jets are placed along that path, contaminants can be melted, or dissolved and scoured from the soil. Contaminants and fines flow down the opposite side of the auger and out for extraction in a series of flotation tanks. Countercurrent washing of the silt results when soil settles in tanks through rising water and air bubbles then is pumped through cyclones placed above the next DAF tank of the series. LNAPLs, DNAPLs, or metallic contaminants made hydrophobic by chemicals in the system are removed at the overflow of the cyclones or by flotation in the tanks. The overflow from the cyclones and DAF tanks flows into the previous tank of the series. Examples of contaminants remediated include; arsenic, cadmium, lead and mercury, Naturally Occurring Radioactive Materials (NORM), uranium, solid oils, polyaromatic hydrocarbons in creosote and coal tars, and polychlorinated hydrocarbons.

  5. Tank waste remediation system retrieval and disposal mission initial updated baseline summary

    SciTech Connect

    Swita, W.R.

    1998-01-09

    This document provides a summary of the Tank Waste Remediation System (TWRS) Retrieval and Disposal Mission Initial Updated Baseline (scope, schedule, and cost), developed to demonstrate Readiness-to-Proceed (RTP) in support of the TWRS Phase 1B mission. This Updated Baseline is the proposed TWRS plan to execute and measure the mission work scope. This document and other supporting data demonstrate that the TWRS Project Hanford Management Contract (PHMC) team is prepared to fully support Phase 1B by executing the following scope, schedule, and cost baseline activities: Deliver the specified initial low-activity waste (LAW) and high-level waste (HLW) feed batches in a consistent, safe, and reliable manner to support private contractors` operations starting in June 2002; Deliver specified subsequent LAW and HLW feed batches during Phase 1B in a consistent, safe, and reliable manner; Provide for the interim storage of immobilized HLW (IHLW) products and the disposal of immobilized LAW (ILAW) products generated by the private contractors; Provide for disposal of byproduct wastes generated by the private contractors; and Provide the infrastructure to support construction and operations of the private contractors` facilities.

  6. A Framework for Remediating Number Combination Deficits

    ERIC Educational Resources Information Center

    Fuchs, Lynn S.; Powell, Sarah R.; Seethaler, Pamela M.; Fuchs, Douglas; Hamlett, Carol L.; Cirino, Paul T.; Fletcher, Jack M.

    2010-01-01

    This article introduces a framework for the remediation of number combination (NC) deficits. Research on the remediation of NC deficits is summarized, and research program studies are used to illustrate the 3 approaches to remediation. The Framework comprises a 2-stage system of remediation. The less intensive stage implementing 1 of 3…

  7. Ultrasonic and mechanical soil washing processes for the remediation of heavy-metal-contaminated soil

    NASA Astrophysics Data System (ADS)

    Kim, Seulgi; Lee, Wontae; Son, Younggyu

    2016-07-01

    Ultrasonic/mechanical soil washing process was investigated and compared with ultrasonic process and mechanical process using a relatively large lab-scale sonoreactor. It was found that higher removal efficiencies were observed in the combined processes for 0.1 and 0.3 M HCl washing liquids. It was due to the combination effects of macroscale removal for the overall range of slurry by mechanical mixing and microscale removal for the limited zone of slurry by cavitational actions.

  8. Potato processing scenario in India: Industrial constraints, future projections, challenges ahead and remedies - A review.

    PubMed

    Marwaha, R S; Pandey, S K; Kumar, Dinesh; Singh, S V; Kumar, Parveen

    2010-03-01

    Indian potato (Solanum tuberosum L.) processing industry has emerged fast due to economic liberalization coupled with growing urbanization, expanding market options and development of indegenous processing varieties. India's first potato processing varieties 'Kufri Chipsona-1' and 'Kufri Chipsona-2' were developed in 1998, followed by an improved processing variety 'Kufri Chipsona-3' in 2005 for the Indian plains and first chipping variety 'Kufri Himsona' for the hills. These varieties have >21% tuber dry matter content, contain low reducing sugars (<0.1% on fresh wt) and are most suitable for producing chips, French fries and dehydrated products. The availability of these varieties and standardization of storage techniques for processing potatoes at 10-12°C with sprout suppressant isopropyl N-(3-chlorophenyl) carbamate have revolutionized the processing scenario within a short span of 10 years. Currently about 4% of total potato produce is being processed in organized and unorganized sector. Potato processing industry mainly comprises 4 segments: potato chips, French fries, potato flakes/powder and other processed products. However, potato chips still continue to be the most popular processed product. The major challenge facing the industries lies in arranging round the year supply of processing varieties at reasonable price for their uninterrupted operation, besides several others which have been discussed at length and addressed with concrete solutions.

  9. Integrated in-situ remediation

    SciTech Connect

    Fustos, V.; Lieberman, P.

    1996-01-01

    This article presents an integrated approach to ex-situ and in-situ remediation. A sequence of processes, used successfully in their own right, but used synergistically in this approach, have achieved short-term, economic remediation. In addition the range of contaminants that can be treated is extended. The Process uses ozone, compressed oxygen, water vapor, heat, bioaugmentation and vapor extraction to remediate lower molecular weight hydrocarbons and higher molecular weight hydrocarbons. 3 figs.

  10. Electrokinetic remediation prefield test methods

    NASA Technical Reports Server (NTRS)

    Hodko, Dalibor (Inventor)

    2000-01-01

    Methods for determining the parameters critical in designing an electrokinetic soil remediation process including electrode well spacing, operating current/voltage, electroosmotic flow rate, electrode well wall design, and amount of buffering or neutralizing solution needed in the electrode wells at operating conditions are disclosed These methods are preferably performed prior to initiating a full scale electrokinetic remediation process in order to obtain efficient remediation of the contaminants.

  11. The Multi-Scale Mass Transfer Processes Controlling Natural Attenuation and Engineered Remediation: An IFC Focused on Hanford’s 300 Area Uranium Plume Quality Assurance Project Plan

    SciTech Connect

    Fix, N. J.

    2008-01-31

    The purpose of the project is to conduct research at an Integrated Field-Scale Research Challenge Site in the Hanford Site 300 Area, CERCLA OU 300-FF-5 (Figure 1), to investigate multi-scale mass transfer processes associated with a subsurface uranium plume impacting both the vadose zone and groundwater. The project will investigate a series of science questions posed for research related to the effect of spatial heterogeneities, the importance of scale, coupled interactions between biogeochemical, hydrologic, and mass transfer processes, and measurements/approaches needed to characterize a mass-transfer dominated system. The research will be conducted by evaluating three (3) different hypotheses focused on multi-scale mass transfer processes in the vadose zone and groundwater, their influence on field-scale U(VI) biogeochemistry and transport, and their implications to natural systems and remediation. The project also includes goals to 1) provide relevant materials and field experimental opportunities for other ERSD researchers and 2) generate a lasting, accessible, and high-quality field experimental database that can be used by the scientific community for testing and validation of new conceptual and numerical models of subsurface reactive transport.

  12. [Continuous remediation of heavy metal contaminated soil by co-cropping system enhanced with chelator].

    PubMed

    Wei, Ze-Bin; Guo, Xiao-Fang; Wu, Qi-Tang; Long, Xin-Xian

    2014-11-01

    In order to elucidate the continuous effectiveness of co-cropping system coupling with chelator enhancement in remediating heavy metal contaminated soils and its environmental risk towards underground water, soil lysimeter (0.9 m x 0.9 m x 0.9 m) experiments were conducted using a paddy soil affected by Pb and Zn mining in Lechang district of Guangdong Province, 7 successive crops were conducted for about 2.5 years. The treatments included mono-crop of Sedum alfredii Hance (Zn and Cd hyperaccumulator), mono-crop of corn (Zea mays, cv. Yunshi-5, a low-accumulating cultivar), co-crop of S. alfredii and corn, and co-crop + MC (Mixture of Chelators, comprised of citric acid, monosodium glutamate waste liquid, EDTA and KCI with molar ratio of 10: 1:2:3 at the concentration of 5 mmol x kg(-1) soil). The changes of heavy metal concentrations in plants, soil and underground water were monitored. Results showed that the co-cropping system was suitable only in spring-summer seasons and significantly increased Zn and Cd phytoextraction. In autumn-winter seasons, the growth of S. alfredii and its phytoextraction of Zn and Cd were reduced by co-cropping and MC application. In total, the mono-crops of S. alfredii recorded a highest phytoextraction of Zn and Cd. However, the greatest reduction of soil Zn, Cd and Pb was observed with the co-crop + MC treatment, the reduction rates were 28%, 50%, and 22%, respectively, relative to the initial soil metal content. The reduction of this treatment was mainly attributed to the downwards leaching of metals to the subsoil caused by MC application. The continuous monitoring of leachates during 2. 5 year's experiment also revealed that the addition of MC increased heavy metal concentrations in the leaching water, but they did not significantly exceed the III grade limits of the underground water standard of China.

  13. Notification: Audit of EPA's Processes for Managing Background Investigations of Privileged Users and Taking Action to Remediate Weaknesses in Agency's Information Security Program

    EPA Pesticide Factsheets

    Project #OA-FY17-0139, Feb 15, 2017.The EPA OIG plans to begin preliminary research on an audit of EPA's processes for managing background investigations of privileged users and taking action to remediate weaknesses in agency's info security program.

  14. Rapid response tools and datasets for post-fire modeling: Linking Earth Observations and process-based hydrological models to support post-fire remediation

    Treesearch

    M. E. Miller; M. Billmire; W. J. Elliot; K. A. Endsley; P. R. Robichaud

    2015-01-01

    Preparation is key to utilizing Earth Observations and process-based models to support post-wildfire mitigation. Post-fire flooding and erosion can pose a serious threat to life, property and municipal water supplies. Increased runoff and sediment delivery due to the loss of surface cover and fire-induced changes in soil properties are of great concern. Remediation...

  15. A model for homeopathic remedy effects: low dose nanoparticles, allostatic cross-adaptation, and time-dependent sensitization in a complex adaptive system

    PubMed Central

    2012-01-01

    Background This paper proposes a novel model for homeopathic remedy action on living systems. Research indicates that homeopathic remedies (a) contain measurable source and silica nanoparticles heterogeneously dispersed in colloidal solution; (b) act by modulating biological function of the allostatic stress response network (c) evoke biphasic actions on living systems via organism-dependent adaptive and endogenously amplified effects; (d) improve systemic resilience. Discussion The proposed active components of homeopathic remedies are nanoparticles of source substance in water-based colloidal solution, not bulk-form drugs. Nanoparticles have unique biological and physico-chemical properties, including increased catalytic reactivity, protein and DNA adsorption, bioavailability, dose-sparing, electromagnetic, and quantum effects different from bulk-form materials. Trituration and/or liquid succussions during classical remedy preparation create “top-down” nanostructures. Plants can biosynthesize remedy-templated silica nanostructures. Nanoparticles stimulate hormesis, a beneficial low-dose adaptive response. Homeopathic remedies prescribed in low doses spaced intermittently over time act as biological signals that stimulate the organism’s allostatic biological stress response network, evoking nonlinear modulatory, self-organizing change. Potential mechanisms include time-dependent sensitization (TDS), a type of adaptive plasticity/metaplasticity involving progressive amplification of host responses, which reverse direction and oscillate at physiological limits. To mobilize hormesis and TDS, the remedy must be appraised as a salient, but low level, novel threat, stressor, or homeostatic disruption for the whole organism. Silica nanoparticles adsorb remedy source and amplify effects. Properly-timed remedy dosing elicits disease-primed compensatory reversal in direction of maladaptive dynamics of the allostatic network, thus promoting resilience and recovery from

  16. A model for homeopathic remedy effects: low dose nanoparticles, allostatic cross-adaptation, and time-dependent sensitization in a complex adaptive system.

    PubMed

    Bell, Iris R; Koithan, Mary

    2012-10-22

    This paper proposes a novel model for homeopathic remedy action on living systems. Research indicates that homeopathic remedies (a) contain measurable source and silica nanoparticles heterogeneously dispersed in colloidal solution; (b) act by modulating biological function of the allostatic stress response network (c) evoke biphasic actions on living systems via organism-dependent adaptive and endogenously amplified effects; (d) improve systemic resilience. The proposed active components of homeopathic remedies are nanoparticles of source substance in water-based colloidal solution, not bulk-form drugs. Nanoparticles have unique biological and physico-chemical properties, including increased catalytic reactivity, protein and DNA adsorption, bioavailability, dose-sparing, electromagnetic, and quantum effects different from bulk-form materials. Trituration and/or liquid succussions during classical remedy preparation create "top-down" nanostructures. Plants can biosynthesize remedy-templated silica nanostructures. Nanoparticles stimulate hormesis, a beneficial low-dose adaptive response. Homeopathic remedies prescribed in low doses spaced intermittently over time act as biological signals that stimulate the organism's allostatic biological stress response network, evoking nonlinear modulatory, self-organizing change. Potential mechanisms include time-dependent sensitization (TDS), a type of adaptive plasticity/metaplasticity involving progressive amplification of host responses, which reverse direction and oscillate at physiological limits. To mobilize hormesis and TDS, the remedy must be appraised as a salient, but low level, novel threat, stressor, or homeostatic disruption for the whole organism. Silica nanoparticles adsorb remedy source and amplify effects. Properly-timed remedy dosing elicits disease-primed compensatory reversal in direction of maladaptive dynamics of the allostatic network, thus promoting resilience and recovery from disease. Homeopathic

  17. Spontaneous vegetation encroachment upon bauxite residue (red mud) as an indicator and facilitator of in situ remediation processes.

    PubMed

    Santini, Talitha C; Fey, Martin V

    2013-01-01

    The spontaneous colonization of a bauxite residue (alumina refining tailings) deposit by local vegetation in Linden, Guyana, over 30 years, indicates that natural weathering processes can ameliorate tailings to the extent that it can support vegetation. Samples were collected from vegetated and unvegetated areas to investigate the relationships between bauxite residue properties and vegetation cover. Compared to unvegetated areas, bauxite residue in vegetated areas had lower pH (mean pH 7.9 vs 10.9), lower alkalinity (mean titratable alkalinity 0.4 vs 1.4 mol H(+) kg(-1)), lower electrical conductivity (mean EC 0.3 vs 2.1 mS cm(-1)), lower total Al (mean Al2O3 19.8 vs 25.8% wt) and Na (mean Na2O 0.9 vs 3.7% wt), and less sodalite and calcite. Accumulation of N, NH4(+), and organic C occurred under vegetation, demonstrating the capacity for plants to modify residue to suit their requirements as a soil-like growth medium. Aeolian redistribution of coarse grained tailings appeared to support vegetation establishment by providing a thin zone of enhanced drainage at the surface. Natural pedogenic processes may be supplemented by irrigation, enhanced drainage, and incorporation of sand and organic matter at other tailings deposits to accelerate the remediation process and achieve similar results in a shorter time frame.

  18. The Advanced Monitoring Systems Initiative--Performance Monitoring for DOE Environmental Remediation and Contaminant Containment

    NASA Astrophysics Data System (ADS)

    Haas, W. J.; Venedam, R. J.; Lohrstorfer, C. F.; Weeks, S. J.

    2005-05-01

    The Advanced Monitoring System Initiative (AMSI) is a new approach to accelerate the development and application of advanced sensors and monitoring systems in support of Department of Energy needs in monitoring the performance of environmental remediation and contaminant containment activities. The Nevada Site Office of the National Nuclear Security Administration (NNSA) and Bechtel Nevada manage AMSI, with funding provided by the DOE Office of Environmental Management (DOE EM). AMSI has easy access to unique facilities and capabilities available at the Nevada Test Site (NTS), including the Hazardous Materials (HazMat) Spill Center, a one-of-a-kind facility built and permitted for releases of hazardous materials for training purposes, field-test detection, plume dispersion experimentation, and equipment and materials testing under controlled conditions. AMSI also has easy access to the facilities and considerable capabilities of the DOE and NNSA National Laboratories, the Special Technologies Laboratory, Remote Sensing Laboratory, Desert Research Institute, and Nevada Universities. AMSI provides rapid prototyping, systems integration, and field-testing, including assistance during initial site deployment. The emphasis is on application. Important features of the AMSI approach are: (1) customer investment, involvement and commitment to use - including definition of needs, desired mode of operation, and performance requirements; and (2) employment of a complete systems engineering approach, which allows the developer to focus maximum attention on the essential new sensing element or elements while AMSI assumes principal responsibility for infrastructure support elements such as power, packaging, and general data acquisition, control, communication, visualization and analysis software for support of decisions. This presentation describes: (1) the needs for sensors and performance monitoring for environmental systems as seen by the DOE Long Term Stewardship Science and

  19. Application of remedy studies to the development of a soil washing pilot plant that uses mineral processing technology: a practical experience.

    PubMed

    Richardson, W S; Phillips, C R; Luttrell, J; Hicks, R; Cox, C

    1999-04-23

    Soil washing employing mineral processing technology to treat radionuclide-contaminated soils has been examined as a remedy alternative to the exclusive excavation, transportation, and disposal of the soil. Successful application depends on a thorough remedy study, employing a systematic tiered approach that is efficient, self-limiting, and cost effective. The study includes: (1) site and soil characterization to determine the basic mineral and physical properties of both the soil and contaminants and to identify their relative associations; (2) treatment studies to evaluate the performance of process units for contaminant separation; (3) conceptual process design to develop a treatment pilot plant; and (4) engineering design to construct, test, and optimize the actual full-scale plant. A pilot plant using soil washing technology for the treatment of radium-contaminated soil was developed, tested, and demonstrated. The plant used particle-size separation to produced a remediated product that represented approximately 50% of the contaminated soil. Subsequently, it was modified for more effective performance and application to soil with alternate characteristics; it awaits further testing. The economic analysis of soil washing using the pilot plant as a model indicates that a remedy plan based on mineral processing technology is very competitive with the traditional alternative employing excavation, transportation, and disposal exclusively, even when disposal costs are modest or when recovery of remediated soil during treatment is low. This paper reviews the tiered approach as it applies to mineral processing technology to treat radionuclide-contaminated soils and a pilot plant developed to test the soil washing process.

  20. A Model of the Writing Process for Use in Teaching and Remediating Written Expression.

    ERIC Educational Resources Information Center

    Rager, John J.

    The writing process depends heavily on linguistic, psycho-perceptual, and psycho-motor abilities. If a student has a significant weakness in one of these major trait clusters, then thinking will suffer and he or she may experience great difficulty in writing. The process of writing can be broken down into four main phases, which can be labeled…

  1. Improved television signal processing system

    NASA Technical Reports Server (NTRS)

    Wong, R. Y.

    1967-01-01

    Digital system processes spacecraft television pictures by converting images sensed on a photostorage vidicon to pulses which can be transmitted by telemetry. This system can be applied in the processing of medical X ray photographs and in electron microscopy.

  2. SAR processing using SHARC signal processing systems

    NASA Astrophysics Data System (ADS)

    Huxtable, Barton D.; Jackson, Christopher R.; Skaron, Steve A.

    1998-09-01

    Synthetic aperture radar (SAR) is uniquely suited to help solve the Search and Rescue problem since it can be utilized either day or night and through both dense fog or thick cloud cover. Other papers in this session, and in this session in 1997, describe the various SAR image processing algorithms that are being developed and evaluated within the Search and Rescue Program. All of these approaches to using SAR data require substantial amounts of digital signal processing: for the SAR image formation, and possibly for the subsequent image processing. In recognition of the demanding processing that will be required for an operational Search and Rescue Data Processing System (SARDPS), NASA/Goddard Space Flight Center and NASA/Stennis Space Center are conducting a technology demonstration utilizing SHARC multi-chip modules from Boeing to perform SAR image formation processing.

  3. Performance characteristics of DRI, CEDIA, and REMEDi systems for preliminary tests of amphetamines and opiates in human urine.

    PubMed

    Huang, Min-Kun; Dai, Yu-Shan; Lee, Choung-Huei; Liu, Chiareiy; Tsay, Wen-Ing; Li, Jih-Heng

    2006-01-01

    Arrestee urine specimens (930) were tested with DRI, CEDIA, and REMEDi; those that tested positive for amphetamines and opiates (616 and 414, respectively) were then confirmed by gas chromatography-mass spectrometry. The performance characteristics of these three preliminary systems were evaluated using the following commonly used parameters: true positive, true negative, false positive, and false negative. The sensitivity, specificity, and efficiency of these methods were also calculated. Data derived from this study indicated DRI and CEDIA adapted by this study generated acceptable preliminary test results for amphetamine/methamphetamine and morphine/codeine, but not for MDA/MDMA and REMEDi has lower sensitivity than DRI and CEDIA, but with better specificity and efficiency, supporting its use under emergency room settings where drug concentrations in overdose cases are expectedly at high levels.

  4. Potential enhancements to addressing programmatic risk in the tank waste remediation system (TWRS) program

    SciTech Connect

    Brothers, A.; Fassbender, L.; Bilyard, G.; Levine, L.

    1996-04-01

    Pacific Northwest National Laboratory (PNNL) conducted a Tank Waste Remediation System (TWRS) Risk Management methodology development task. The objective of this task was to develop risk management methodology focused on (1) the use of programmatic risk information in making TWRS architecture selection decisions and (2) the identification/evaluation/selection of TWRS risk-handling actions. Methods for incorporating programmatic risk/uncertainty estimates into trade studies are provided for engineers/analysts. Methods for identifying, evaluating, and selecting risk-handling actions are provided for managers. The guidance provided in this report is designed to help decision-makers make difficult judgments. Current approaches to architecture selection decisions and identification/evaluation/selection of risk-handling actions are summarized. Three categories of sources of programmatic risk (parametric, external, and organizational) are examined. Multiple analytical approaches are presented to enhance the current alternative generation and analysis (AGA) and risk-handling procedures. Appendix A describes some commercially available risk management software tools and Appendix B provides a brief introduction to quantification of risk attitudes. The report provides three levels of analysis for enhancing the AGA Procedure: (1) qualitative discussion coupled with estimated uncertainty ranges for scores in the alternatives-by-criteria matrix; (2) formal elicitation of probability distributions for the alternative scores; and (3) a formal, more structured, comprehensive risk analysis. A framework is also presented for using the AGA programmatic risk analysis results in making better decisions. The report also presents two levels of analysis for evaluation and selection of risk-handling actions: (1) qualitative analysis and judgmental rankings of alternative actions, and (2) Simple Multi-Attribute Rating Technique (SMART).

  5. Bioavailability and ecotoxicity of arsenic species in solution culture and soil system: implications to remediation.

    PubMed

    Bolan, Nanthi; Mahimairaja, Santiago; Kunhikrishnan, Anitha; Seshadri, Balaji; Thangarajan, Ramya

    2015-06-01

    In this work, bioavailability and ecotoxicity of arsenite (As(III)) and arsenate (As(V)) species were compared between solution culture and soil system. Firstly, the adsorption of As(III) and As(V) was compared using a number of non-allophanic and allophanic soils. Secondly, the bioavailability and ecotoxicity were examined using germination, phytoavailability, earthworm, and soil microbial activity tests. Both As-spiked soils and As-contaminated sheep dip soils were used to test bioavailability and ecotoxicity. The sheep dip soil which contained predominantly As(V) species was subject to flooding to reduce As(V) to As(III) and then used along with the control treatment soil to compare the bioavailability between As species. Adsorption of As(V) was much higher than that of As(III), and the difference in adsorption between these two species was more pronounced in the allophanic than non-allophanic soils. In the solution culture, there was no significant difference in bioavailability and ecotoxicity, as measured by germination and phytoavailability tests, between these two As species. Whereas in the As-spiked soils, the bioavailability and ecotoxicity were higher for As(III) than As(V), and the difference was more pronounced in the allophanic than non-allophanic soils. Bioavailability of As increased with the flooding of the sheep dip soils which may be attributed to the reduction of As(V) to As(III) species. The results in this study have demonstrated that while in solution, the bioavailability and ecotoxicity do not vary between As(III) and As(V), in soils, the latter species is less bioavailable than the former species because As(V) is more strongly retained than As(III). Since the bioavailability and ecotoxicity of As depend on the nature of As species present in the environment, risk-based remediation approach should aim at controlling the dynamics of As transformation.

  6. Selecting remediation goals by assessing the natural attenuation capacity of groundwater systems

    USGS Publications Warehouse

    Chapelle, Francis H.; Bradley, Paul M.

    1998-01-01

    Remediation goals for the source areas of a chlorinated ethene‐contaminated groundwater plume were identified by assessing the natural attenuation capacity of the aquifer system. The redox chemistry of the site indicates that sulfate‐reducing (H2 ∼ 2 nanomoles [nM]) per liter conditions near the contaminant source grade to Fe(III)‐reducing conditions (H2 ∼ 0.5 nM) downgradient of the source. Sulfate‐reducing conditions facilitate the initial reduction of perchloroethene (PCE) to trichloroethene (TCE), cis‐dichloroethene (cis‐DCE), and vinyl chloride (VC). Subsequently, the Fe(III)‐reducing conditions drive the oxidation of cis‐DCE and VC to carbon dioxide and chloride. This sequence gives the aquifer a substantial capacity for biodegrading chlorinated ethenes. Natural attenuation capacity (the slope of the steady‐state contaminant concentration profile along a groundwater flowpath) is a function of biodegradation rates, aquifer dispersive characteristics, and groundwater flow velocity. The natural attenuation capacity at the Kings Bay, Georgia site was assessed by estimating groundwater flowrates (∼0.23 ± 0.12 m/d) and aquifer dispersivity (∼1 m) from hydrologic and scale considerations. Apparent biodegradation rate constants (PCE and TCE ∼ 0.01 d−1; cis‐DCE and VC ∼ 0.025 d−1) were estimated from observed contaminant concentration changes along aquifer flowpaths. A boundary‐value problem approach was used to estimate levels to which contaminant concentrations in the source areas must be lowered (by engineered removal), or groundwater flow velocities lowered (by pumping) for the natural attenuation capacity to achieve maximum concentration limits (MCLs) prior to reaching a predetermined regulatory point of compliance.

  7. Value tradeoffs for the Hanford Tank Waste Remediation System (TWRS) program

    SciTech Connect

    Keeney, R.L.; Winterfeldt, D. von

    1997-09-01

    The Tank Waste Remediation System (TWRS) program at the Hanford Site of the Department of Energy has adopted a logical approach to making decisions that uses decision analysis to structure and analyze decision alternatives and public values to evaluate them. This report is the third in a series to support this effort. The first identified a set of objectives (called {open_quotes}ends objectives{close_quotes}) that characterize the ultimate goals and desires of Hanford decision makers and stakeholders. The second report developed operational measures for these ends objectives (called {open_quotes}ends measures{close_quotes}) and it also developed a set of performance objectives and associated performance measures that are more directly related to how well decision alternatives in the TWRS program perform to achieve the ends objectives. The present report describes the development of quantitative value tradeoffs for both the ends measures and the performance measures. First, five national value experts were interviewed to obtain value tradeoffs for units of the ends measures identified in Keeney and von Winterfeldt (1996). The results of this assessment are shown in Table S1. Second, the implied value tradeoffs for the units of the performance measures were calculated from the value tradeoffs for units of the ends measures provided by the national experts. When calculating the value tradeoffs for the units of the performance measures, very simple quantitative relationships between ends and performance measures were assumed. The results of this calculation are shown in Table S2. The results of this report shown in Tables S1 and S2 should be considered preliminary and largely illustrative of the principles for developing value tradeoffs. The report lists several important caveats and recommendations for how future work can improve on the assessment of value tradeoffs.

  8. A comparison of physicochemical methods for the remediation of porous medium systems contaminated with tar

    NASA Astrophysics Data System (ADS)

    Hauswirth, Scott C.; Miller, Cass T.

    2014-10-01

    The remediation of former manufactured gas plant (FMGP) sites contaminated with tar DNAPLs (dense non-aqueous phase liquids) presents a significant challenge. The tars are viscous mixtures of thousands of individual compounds, including known and suspected carcinogens. This work investigates the use of combinations of mobilization, solubilization, and chemical oxidation approaches to remove and degrade tars and tar components in porous medium systems. Column experiments were conducted using several flushing solutions, including an alkaline-polymer (AP) solution containing NaOH and xanthan gum (XG), a surfactant-polymer (SP) solution containing Triton X-100 surfactant (TX100) and XG, an alkaline-surfactant-polymer (ASP) solution containing NaOH, TX100, and XG, and base-activated sodium persulfate both with and without added TX100. The effectiveness of the flushing solutions was assessed based on both removal of polycyclic aromatic hydrocarbon (PAH) mass and on the reduction of dissolved-phase PAH concentrations. SP flushes of 6.6 to 20.9 PV removed over 99% of residual PAH mass and reduced dissolved-phase concentrations by up to two orders of magnitude. ASP flushing efficiently removed 95-96% of residual PAH mass within about 2 PV, and significantly reduced dissolved-phase concentrations of several low molar mass compounds, including naphthalene, acenaphthene, fluorene, and phenanthrene. AP flushing removed a large portion of the residual tar (77%), but was considerably less effective than SP and ASP in terms of the effect on dissolved PAH concentrations. Persulfate was shown to oxidize tar components, primarily those with low molar mass, however, the overall degradation was relatively low (30-50% in columns with low initial tar saturations), and the impact on dissolved-phase concentrations was minimal.

  9. Central waste processing system

    NASA Technical Reports Server (NTRS)

    Kester, F. L.

    1973-01-01

    A new concept for processing spacecraft type wastes has been evaluated. The feasibility of reacting various waste materials with steam at temperatures of 538 - 760 C in both a continuous and batch reactor with residence times from 3 to 60 seconds has been established. Essentially complete gasification is achieved. Product gases are primarily hydrogen, carbon dioxide, methane, and carbon monoxide. Water soluble synthetic wastes are readily processed in a continuous tubular reactor at concentrations up to 20 weight percent. The batch reactor is able to process wet and dry wastes at steam to waste weight ratios from 2 to 20. Feces, urine, and synthetic wastes have been successfully processed in the batch reactor.

  10. Application of SBA-15 in Adsorption-Fenton Oxidation Process for Simultaneous Remediation of Dehp and As(iii)

    NASA Astrophysics Data System (ADS)

    Latorre, I.; Hwang, S.

    2013-12-01

    Di-2-ethylhexyl phthalate (DEHP) has been widely used as plasticizer in the manufacturing of polymeric materials to enhance flexibility, transparency and softness, particularly, in polyvinyl chloride (PVC) production. Several studies elucidated that DEHP could be linked to hepatocellular tumors and pre-term birth and may be a developmental and reproductive toxicant. Arsenic (As) contamination has been widespread in the environment and because of its toxicity and prevalence in nature; it also has become a significant environmental health concern. Most solid waste materials containing DEHP and As(III) are disposed of in landfills and may migrate to groundwater and soil environments representing a threat to human receptors. Therefore, the application of adsorption-Fenton oxidation process with Fe adsorbed to SBA-15 matrix was assessed for simultaneous remediation of DEHP and As(III). Three sequences were run to assess the regeneration efficiency of the SBA-15. A response surface methodology was employed to optimize adsorption and Fenton regeneration. Adsorption optimization was evaluated with regard to SBA-15 doses and the extent of As(III) and Fe concentrations. Optimization of Fenton regeneration, in addition, assessed initial H2O2 concentration. Global optimization for maximum reduction of DEHP and As(III) was performed by D-Optimal. Highest adsorption of DEHP (90-95%) and As (40-95%) into the SBA-15 was predicted at 1.16 mM Fe, 18.74 mg SBA-15 and 3.71 mg/L As(III). Highest reduction of As (78-99%) and DEHP (90-97%) was predicted with 0.50 mM Fe, 22 mg SBA-15, 3.02 mg/L As(III) and 22.50 mM H2O2. Global optimal treatments were validated and SBA-15 regenerated material was characterized via SEM and XPS. The efficiency of DEHP and As(III) remediation by adsorption-Fenton oxidation process, applying optimal treatment combinations, was evaluated using leachate from a lab scale bioreactor monofill (i.e., filled with PVC materials). Capability of As(III) and DEHP

  11. VALUING ACID MINE DRAINAGE REMEDIATION IN WEST VIRGINIA: A HEDONIC MODELING APPROACH INCORPORATING GEOGRAPHIC INFORMATION SYSTEMS

    EPA Science Inventory

    States with active and abandoned mines face large private and public costs to remediate damage to streams and rivers from acid mine drainage (AMD). Appalachian states have an especially large number of contaminated streams and rivers, and the USGS places AMD as the primary source...

  12. VALUING ACID MINE DRAINAGE REMEDIATION IN WEST VIRGINIA: A HEDONIC MODELING APPROACH INCORPORATING GEOGRAPHIC INFORMATION SYSTEMS

    EPA Science Inventory

    States with active and abandoned mines face large private and public costs to remediate damage to streams and rivers from acid mine drainage (AMD). Appalachian states have an especially large number of contaminated streams and rivers, and the USGS places AMD as the primary source...

  13. Effects of remedies made in patient setup process on residual setup errors and margins in head and neck cancer radiotherapy based on 2D image guidance.

    PubMed

    Kapanen, Mika; Laaksomaa, Marko; Tulijoki, Tapio; Kellokumpu-Lehtinen, Pirkko-Liisa; Hyödynmaa, Simo

    2015-01-01

    Patient setup errors were aimed to be reduced in radiotherapy (RT) of head-and-neck (H&N) cancer. Some remedies in patient setup procedure were proposed for this purpose. RT of H&N cancer has challenges due to patient rotation and flexible anatomy. Residual position errors occurring in treatment situation and required setup margins were estimated for relevant bony landmarks after the remedies made in setup process and compared with previous results. The formation process for thermoplastic masks was improved. Also image matching was harmonized to the vertebrae in the middle of the target and a 5 mm threshold was introduced for immediate correction of systematic errors of the landmarks. After the remedies, residual position errors of bony landmarks were retrospectively determined from 748 orthogonal X-ray images of 40 H&N cancer patients. The landmarks were the vertebrae C1-2, C5-7, the occiput bone and the mandible. The errors include contributions from patient rotation, flexible anatomy and inter-observer variation in image matching. Setup margins (3D) were calculated with the Van Herk formula. Systematic residual errors of the landmarks were reduced maximally by 49.8% (p ≤ 0.05) and the margins by 3.1 mm after the remedies. With daily image guidance the setup margins of the landmarks were within 4.4 mm, but larger margins of 6.4 mm were required for the mandible. Remarkable decrease in the residual errors of the bony landmarks and setup margins were achieved through the remedies made in the setup process. The importance of quality assurance of the setup process was demonstrated.

  14. Woodchip-sulfur based heterotrophic and autotrophic denitrification (WSHAD) process for nitrate contaminated water remediation.

    PubMed

    Li, Rui; Feng, Chuanping; Hu, Weiwu; Xi, Beidou; Chen, Nan; Zhao, Baowei; Liu, Ying; Hao, Chunbo; Pu, Jiaoyang

    2016-02-01

    Nitrate contaminated water can be effectively treated by simultaneous heterotrophic and autotrophic denitrification (HAD). In the present study, woodchips and elemental sulfur were used as co-electron donors for HAD. It was found that ammonium salts could enhance the denitrifying activity of the Thiobacillus bacteria, which utilize the ammonium that is produced by the dissimilatory nitrate reduction to ammonium (DNRA) in the woodchip-sulfur based heterotrophic and autotrophic denitrification (WSHAD) process. The denitrification performance of the WSHAD process (reaction constants range from 0.05485 h(-1) to 0.06637 h(-1)) is better than that of sulfur-based autotrophic denitrification (reaction constants range from 0.01029 h(-1) to 0.01379 h(-1)), and the optimized ratio of woodchips to sulfur is 1:1 (w/w). No sulfate accumulation is observed in the WSHAD process and the alkalinity generated in the heterotrophic denitrification can compensate for alkalinity consumption by the sulfur-based autotrophic denitrification. The symbiotic relationship between the autotrophic and the heterotrophic denitrification processes play a vital role in the mixotrophic environment. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. 75 FR 71677 - Reimbursement for Costs of Remedial Action at Active Uranium and Thorium Processing Sites

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-24

    ... 1992. In FY 2009, Congress appropriated $70 million for Title X in the American Recovery and Reinvestment Act of 2009 (Recovery Act). In addition, Congress provided $10 million for Title X through the normal appropriation process. As of the end of FY 2010, there are approximately $24.3 million of Recovery...

  16. Developing Self-Awareness about Writing Processes: The Perry Model and the Remedial Writer.

    ERIC Educational Resources Information Center

    Overbeck, Lois More

    The William Perry model of learning is directly parallel to what has been learned about writing processes. He observed that the student is essentially a dualist who sees everything as right or wrong. This stance of absolute acceptance wavers when the student encounters varieties of or disagreements among truths, thus gradually evolving into the…

  17. Ultrasound as a basic and auxiliary process for dye remediation: a review.

    PubMed

    Eren, Zeynep

    2012-08-15

    Ultrasonic treatment of recalcitrant contaminants has been of utmost interest recently due to the advantages of the cavitation phenomenon, which enhances the efficiency of Advanced Oxidation Processes (AOPs). The current review summarizes the use of ultrasound with biochemical, electrochemical, ozonation, photolysis, photocatalysis and Fenton processes for the degradation of mostly textile dyes and dyebath. There is a few studies about ultrasonic degradation of textile effluents or wastewater due to highly variable contents. It was found that the most common use of ultrasonic irradiation for dye degradation is the combined with the heterogeneous catalysts/adsorbents. The reaction mechanism of the ultrasonic irradiation in heterogeneous media was well investigated and understood. However, there is still lack of information about the reaction mechanism of ultrasonic irradiation in the homogeneous solutions, especially containing ferrous ions. Fenton reaction is already fast itself and gives effective degradation during the oxidation. Therefore, addition of ultrasonic irradiation to Fenton oxidation was less effective compared to other auxiliary processes. It should also be noted that ultrasonic irradiation had a negative effect on dye degradation during combined with electro-oxidation process. Copyright © 2012 Elsevier Ltd. All rights reserved.

  18. ARSENIC UPTAKE PROCESSES IN REDUCING ENVIRONMENTS: IMPLICATIONS FOR ACTIVE REMEDIATION AND NATURAL ATTENUATION

    EPA Science Inventory

    Reductive dissolution of iron oxyhydr(oxides) and release of adsorbed or coprecipitated arsenic is often implicated as a key process that controls the mobility and bioavailability of arsenic in anoxic environments. Yet a complete assessment of arsenic transport and fate requires...

  19. BENCH-SCALE VISUALIZATION OF DNAPL REMEDIATION PROCESSES IN ANALOG HETEROGENEOUS AQUIFERS: SURFACTANT FLOODS, AND IN SITU OXIDATION USING PERMANGANATE

    EPA Science Inventory

    We have conducted well-controlled DNAPL remediation experiments using surfactants (Aerosol MA and Tween 80) to increase solubility and an oxidant (permanganate) to chemically degrade the DNAPL. Photographs and digital image analysis illustrate previously unobserved interactions b...

  20. Remediation of a winery wastewater combining aerobic biological oxidation and electrochemical advanced oxidation processes.

    PubMed

    Moreira, Francisca C; Boaventura, Rui A R; Brillas, Enric; Vilar, Vítor J P

    2015-05-15

    Apart from a high biodegradable fraction consisting of organic acids, sugars and alcohols, winery wastewaters exhibit a recalcitrant fraction containing high-molecular-weight compounds as polyphenols, tannins and lignins. In this context, a winery wastewater was firstly subjected to a biological oxidation to mineralize the biodegradable fraction and afterwards an electrochemical advanced oxidation process (EAOP) was applied in order to mineralize the refractory molecules or transform them into simpler ones that can be further biodegraded. The biological oxidation led to above 97% removals of dissolved organic carbon (DOC), chemical oxygen demand (COD) and 5-day biochemical oxygen demand (BOD5), but was inefficient on the degradation of a bioresistant fraction corresponding to 130 mg L(-1) of DOC, 380 mg O2 L(-1) of COD and 8.2 mg caffeic acid equivalent L(-1) of total dissolved polyphenols. Various EAOPs such as anodic oxidation with electrogenerated H2O2 (AO-H2O2), electro-Fenton (EF), UVA photoelectro-Fenton (PEF) and solar PEF (SPEF) were then applied to the recalcitrant effluent fraction using a 2.2 L lab-scale flow plant containing an electrochemical cell equipped with a boron-doped diamond (BDD) anode and a carbon-PTFE air-diffusion cathode and coupled to a photoreactor with compound parabolic collectors (CPCs). The influence of initial Fe(2+) concentration and current density on the PEF process was evaluated. The relative oxidative ability of EAOPs increased in the order AO-H2O2 < EF < PEF ≤ SPEF. The SPEF process using an initial Fe(2+) concentration of 35 mg L(-1), current density of 25 mA cm(-2), pH of 2.8 and 25 °C reached removals of 86% on DOC and 68% on COD after 240 min, regarding the biologically treated effluent, along with energy consumptions of 45 kWh (kg DOC)(-1) and 5.1 kWh m(-3). After this coupled treatment, color, odor, COD, BOD5, NH4(+), NO3(-) and SO4(2-) parameters complied with the legislation targets and, in addition, a total

  1. US Department of Energy final response to standards for remedial actions at inactive uranium processing sites; Proposed rule

    SciTech Connect

    Not Available

    1988-11-14

    This document revisits and supplements information and recommendations presented in the January 1988 US Department of Energy (DOE) submission to the US Environmental Protection Agency (EPA) regarding the proposed standards for Title I uranium processing sites (DOE, 1988). The clarifications and comments in this report are based on further DOE investigation, contemplation, and interpretation of the proposed standards. Since the January response, the DOE has undertaken a number of special studies to -investigate, evaluate, focus, and clarify issues relating to the standards. In addition, the Nuclear Regulatory Commission (NRC) has issued a draft technical position outlining its interpretation of the proposed standards and clarifying how the standards will be implemented (NRC, 1988). Some issues presented are based on previous positions, and the original DOE position is restated for reference. Other issues or recommendations are more recent than the January DOE response; therefore, no former position was advanced. The order of presentation reflects the general order of significance to the DOE, specifically in regards to the Uranium Mill Tailings Remedial Action (UMTRA) Project.

  2. US Department of Energy response to standards for remedial actions at inactive uranium processing sites: Proposed rule

    SciTech Connect

    Not Available

    1988-01-29

    The Title I groundwater standards for inactive uranium mill tailings sites, which were promulgated on January 5, 1983, by the US Environmental Protection Agency (EPA) for the Uranium Mill Tailings Remedial Action (UMTRA) Project, were remanded to the EPA on September 3, 1985, by the US Tenth Circuit Court of Appeals. The Court instructed the EPA to compile general groundwater standards for all Title I sites. On September 24, 1987, the EPA published proposed standards (52FR36000-36008) in response to the remand. This report includes an evaluation of the potential effects of the proposed EPA groundwater standards on the UMTRA Project, as well as a discussion of the DOE's position on the proposed standards. The report also contains and appendix which provides supporting information and cost analyses. In order to assess the impacts of the proposed EPA standards, this report summarizes the proposed EPA standards in Section 2.0. The next three sections assess the impacts of the three parts of the EPA standards: Subpart A considers disposal sites; Subpart B is concerned with restoration at processing sites; and Subpart C addresses supplemental standards. Section 6.0 integrates previous sections into a recommendations section. Section 7.0 contains the DOE response to questions posed by the EPA in the preamble to the proposed standards. 6 refs., 5 figs., 3 tabs.

  3. Remediation of Rare Earth Element Pollutants by Sorption Process Using Organic Natural Sorbents.

    PubMed

    Butnariu, Monica; Negrea, Petru; Lupa, Lavinia; Ciopec, Mihaela; Negrea, Adina; Pentea, Marius; Sarac, Ionut; Samfira, Ionel

    2015-09-10

    The effects of the sorption of environmental applications by various source materials of natural organic matter, i.e., bone powder, was examined. Sorption capacities and subsequent rare earth element retention characteristics of all metals tested were markedly increased by ionic task-specific. In this study, the abilities of three models' isotherms widely were used for the equilibrium sorption data: Langmuir, Freundlich and Redlich-Peterson. For all studied metal ions the maximum adsorption capacity is close to those experimentally determined. The characteristic parameters for each isotherm and related coefficients of determination have been determined. The experimental data achieved excellent fits within the following isotherms in the order: Langmuir > Redlich-Peterson > Freundlich, based on their coefficient of determination values. The bone powder has developed higher adsorption performance in the removal process of Nd(III), Eu(III), La(III) from aqueous solutions than in the case of the removal process of Cs(I), Sr(II) and Tl(I) from aqueous solutions. The described relationships provide direct experimental evidence that the sorption-desorption properties of bone powder are closely related to their degree of the type of the metal. The results suggest a potential for obtaining efficient and cost-effective engineered natural organic sorbents for environmental applications.

  4. Remediation of Rare Earth Element Pollutants by Sorption Process Using Organic Natural Sorbents

    PubMed Central

    Butnariu, Monica; Negrea, Petru; Lupa, Lavinia; Ciopec, Mihaela; Negrea, Adina; Pentea, Marius; Sarac, Ionut; Samfira, Ionel

    2015-01-01

    The effects of the sorption of environmental applications by various source materials of natural organic matter, i.e., bone powder, was examined. Sorption capacities and subsequent rare earth element retention characteristics of all metals tested were markedly increased by ionic task-specific. In this study, the abilities of three models’ isotherms widely were used for the equilibrium sorption data: Langmuir, Freundlich and Redlich-Peterson. For all studied metal ions the maximum adsorption capacity is close to those experimentally determined. The characteristic parameters for each isotherm and related coefficients of determination have been determined. The experimental data achieved excellent fits within the following isotherms in the order: Langmuir > Redlich-Peterson > Freundlich, based on their coefficient of determination values. The bone powder has developed higher adsorption performance in the removal process of Nd(III), Eu(III), La(III) from aqueous solutions than in the case of the removal process of Cs(I), Sr(II) and Tl(I) from aqueous solutions. The described relationships provide direct experimental evidence that the sorption-desorption properties of bone powder are closely related to their degree of the type of the metal. The results suggest a potential for obtaining efficient and cost-effective engineered natural organic sorbents for environmental applications. PMID:26378553

  5. Temporal processing deficits in remediation-resistant reading-impaired children.

    PubMed

    Cacace, A T; McFarland, D J; Ouimet, J R; Schrieber, E J; Marro, P

    2000-01-01

    There is considerable interest in whether a deficit in temporal processing underlies specific learning and language disabilities in school-aged children. This view is particularly controversial in the area of developmental reading problems. The temporal-processing hypothesis was tested in a sample of normal children, 9-11 years of age, and in a sample of age-matched children with reading impairments, by assessing temporal-order discrimination. Five different binary temporal-order tasks were evaluated in the auditory and visual sensory modalities. Other basic discrimination abilities for single auditory stimuli were also assessed, including just noticeable differences (JNDs) for frequency and intensity and a simple threshold detection task. In these tasks, the temporal dimension was the duration of the individual stimuli (20 and 200 ms). All data were obtained using forced- choice psychophysical methods, either in a single-track adaptive format or using psychometric functions. The results from these experiments showed that children with reading impairments had deficits in temporal-order discrimination, but these effects were not modality specific. These same children also had significantly elevated frequency and intensity JNDs and their performance on these tasks were not dependent on stimulus duration. No group differences were observed on the threshold detection task, and the derived measurements of temporal integration (i.e. the threshold difference between the 20- and 200-ms stimuli) were considered normal, averaging 11.7 dB. As a whole, discrimination deficits observed in the reading-impaired group only occurred with suprathreshold stimuli. The deficits were neither modality specific nor temporal (duration) specific. Copyright 2000 S. Karger AG, Basel.

  6. Remediation of TCE contaminated soils by in situ EK-Fenton process.

    PubMed

    Yang, G C; Liu, C Y

    2001-08-17

    The treatment performance and cost analysis of in situ electrokinetic (EK)-Fenton process for oxidation of trichloroethylene (TCE) in soils were evaluated in this work. In all experiments, an electric gradient of 1V/cm, de-ionized water as the cathode reservoir fluid and a treatment time of 10 days were employed. Treatment efficiencies of TCE were evaluated in terms of the electrode material, soil type, catalyst type, and catalyst dosage and granular size if applicable. Test results show that graphite electrodes are superior to stainless steel electrodes. It was found that the soil with a higher content of organic matter would result in a lower treatment efficiency (e.g. a sandy loam is less efficient than a loamy sand). Experimental results show that the type of catalyst and its dosage would markedly affect the reaction mechanisms (i.e. "destruction" and "removal") and the treatment efficiency. Aside from FeSO4, scrap iron powder (SIP) in the form of a permeable reactive wall was also found to be an effective catalyst for Fenton reaction to oxidize TCE. In general, the smaller the granular size of SIP, the lower the overall treatment efficiency and the greater the destruction efficiency. When a greater quantity of SIP was used, a decrease of the overall treatment efficiency and an increase of percent destruction of TCE were found. Experimental results have shown that the quantity of electro-osmotic (EO) flow decreased as the quantity of SIP increased. It has been verified that the treatment performances are closely related to the corresponding EO permeability. Results of the cost analysis have indicated that the EK-Fenton process employed in this work is very cost-effective with respect to TCE destruction.

  7. NORSAR Detection Processing System.

    DTIC Science & Technology

    1987-05-31

    systems have been reliable. NTA/Lillestrom and Hamar will take a new initiative medio April regarding 04C. The line will be remeasured and if a certain...estimate of the ambient noise level at the site of the FINESA array, ground motion spectra were calculated for four time intervals. Two intervals were

  8. Enhancing Monitoring of Recharge-Related Environmental Remediation Processes Using Time-Lapse Seismic Refraction

    NASA Astrophysics Data System (ADS)

    Gaines, D. P.; Baker, G. S.; Hubbard, S. S.; Watson, D. B.; Jardine, P. M.

    2008-12-01

    The application of time-lapse seismic methods has typically been constrained to large-scale geologic investigations associated with petroleum exploration and exploitation; however, there is growing interest in monitoring near-surface phenomena (e.g., fluid flow in fractured or karstic geologic media, hydraulic recharge, and near-surface anthropogenic manipulations) using time-lapse seismic methods. In order to demonstrate the feasibility of detailed time-lapse seismic refraction tomography (TLSRT), we have monitored a perched water table at Oak Ridge National Laboratory (ORNL) Y-12 site in conjunction with a multi- disciplinary investigation of the fate and transport of contaminants. Due to remnant anthropogenic alterations of the site (i.e., replacement of 0-7 meters of contaminated soil with poorly sorted limestone gravel fill during construction of a seepage basin cap), the near surface hydrology is extremely complex and is hypothesized to have a large influence on infiltration, contaminant distribution, and contaminant remobilization. Understanding the impact of recharge-related flow and transport processes is especially important in regions that are subjected to significant precipitation events, such as at the ORNL Y-12 site. Here, TLSRT techniques are used to monitor the changing geometry of a perched water table located near the covered seepage basin, while coincident time-lapse surface electrical resistivity (TLERT) measurements are used to monitor changes in total dissolved solids due to recharge-related dilution. Data are collected at multiple time intervals (i.e., daily, weekly, monthly, yearly) and at varying stages in the evolution of the perch zone. The resulting seismic data are processed using wavepath eikonal tomography (WET) and differenced to identify areas of variable velocity associated with a change in saturation. The differenced tomograms correlate with discrete point water table measurements; however, the highly variable water table at this

  9. Dutch refinery remediating contaminated soils on site

    SciTech Connect

    Not Available

    1994-02-07

    A Rotterdam refinery is treating 10,000 metric tons of petroleum-contaminated soils in above ground bioremediation cells equipped with vapor-extraction systems. The treatment process, designed by Groundwater Technology Inc., Norwood, Mass., the refinery's remediation consultant, is degrading the hydrocarbons to meet strict Dutch standards. Project completion is expected by Spring, requiring a total of only about 9 months. The contamination was accumulated in more than 25 years of refining operations at the site. As part of the construction of a new hydrocracker, the refinery was required to remediate the soils and take measures to reduce groundwater contamination.

  10. Impact of heavy metal toxicity and constructed wetland system as a tool in remediation.

    PubMed

    Usharani, B; Vasudevan, N

    2016-01-01

    The objective of this review is to throw light upon the global concern of heavy metal-contaminated sites and their remediation through an ecofriendly approach. Accumulated heavy metals in soil and water bodies gain entry through the food chain and pose serious threat to all forms of life. This has engendered interest in phytoremediation techniques where hyperaccumulators are used. Constructed wetland has a pivotal role and is a cost-effective technique in the remediation of heavy metals. Metal availability and mobility are influenced by the addition of chelating agents, which enhance the availability of metal uptake. This review helps in identifying the critical knowledge gaps and areas to enhance research in the future to develop strategies such as genetically engineered hyperaccumulators to attain an environment devoid of heavy metal contamination.

  11. ELECTROCHEMICAL REMEDIATION TECHNOLOGIES (ECRTS) DEMONSTRATION BULLETIN

    EPA Science Inventory

    The ElectroChemical Remediation Technologies (ECRTs) process was developed by P2-Soil Remediation, Inc. P-2 Soil Remediation, Inc. formed a partnership with Weiss Associates and ElectroPetroleum, Inc. to apply the technology to contaminated sites. The ECRTs process was evaluated ...

  12. ELECTROCHEMICAL REMEDIATION TECHNOLOGIES (ECRTS) DEMONSTRATION BULLETIN

    EPA Science Inventory

    The ElectroChemical Remediation Technologies (ECRTs) process was developed by P2-Soil Remediation, Inc. P-2 Soil Remediation, Inc. formed a partnership with Weiss Associates and ElectroPetroleum, Inc. to apply the technology to contaminated sites. The ECRTs process was evaluated ...

  13. There's always a villain to punish: group processes contributing to violence and its remediation.

    PubMed

    Thomas, Nina K

    2015-01-01

    This paper considers the widespread use of violent metaphors, such as "combat" and "war," to represent the current social, psychological, and political problems within the United States. I apply Lakoff and Johnson's (1980) thesis that metaphor shapes thought, policy, and behavior. I examine how use of such metaphors inclines the national consciousness toward violence and punishment for it. In addition, I discuss shame and humiliation as psychological precursors of violence, particularly as these play out in the exclusion and extrusion via group scapegoating of individuals and whole groups from active participation in an esteemed or powerful other group. Included within the concept of "violence" are those harmful social policies that invalidate the experiences of disempowered people within the United States. I consider the role of group processes in resolving the injuries wrought by violence, particularly as these operate within such restorative justice projects as the Glencree Ex-Combatants Programme in Northern Ireland. Lessons emerge from restorative justice projects installed internationally for ameliorating conflict within and between "victim" groups in the United States.

  14. Remediation of a biodiesel blend-contaminated soil by using a modified Fenton process.

    PubMed

    Pardo, Fernando; Rosas, Juana M; Santos, Aurora; Romero, Arturo

    2014-11-01

    A soil contaminated with a B20 biodiesel blend (20 % biodiesel, 80 % diesel) has been treated by modified Fenton process with or without chelant addition. All experiments were conducted without pH adjustment. The reagents used were as follows: hydrogen peroxide as oxidant (400-4,000 mmol L(-1)), ferric ion as catalyst (5-20 mmol L(-1)), and trisodium citrate (50 mmol L(-1)) as chelating agent. Soil was spiked at two different pollutant concentrations (1,000-10,000 mg diesel kg(-1) soil). Higher total petroleum hydrocarbon (TPH) removal efficiencies were obtained (up to 75 %) after the treatment in the absence of the chelant due to the low pH obtained in this case. In the presence of chelant, the TPH conversion obtained was lower because both higher pH is obtained and chelant competes with diesel for the oxidant. On the other hand, at neutral pH, the lifetime of the oxidant was increased. Fatty acid methyl esters (FAMEs) are easier to remove than diesel aliphatic hydrocarbons from the blend. An important decrease of the aqueous phase toxicity was observed after the modified Fenton reaction, supporting that nontoxic by-products were released to the aqueous phase during the treatment.

  15. Electromagnetic mixed-waste processing system for asbestos decontamination

    SciTech Connect

    1995-04-01

    The first phase of a program to develop and demonstrate a cost-effective, integrated process for remediation of asbestos-containing material that is contaminated with organics, heavy metals, and radioactive compounds was successfully completed. Laboratory scale tests were performed to demonstrate initial process viability for asbestos conversion, organics removal, and radionuclide and heavy metal removal. All success criteria for the laboratory tests were met. (1) Ohio DSI demonstrated greater than 99% asbestos conversion to amorphous solids using their commercial process. (2) KAI demonstrated 90% removal of organics from the asbestos suspension. (3) Westinghouse STC achieved the required metals removal criteria on a laboratory scale (e.g., 92% removal of uranium from solution, resin loadings of 0.6 equivalents per liter, and greater than 50% regeneration of resin in a batch test.) Using the information gained in the laboratory tests, the process was reconfigured to provide the basis for the mixed waste remediation system. An integrated process is conceptually developed, and a Phase 2 program plan is proposed to provide the bench-scale development needed in order to refine the design basis for a pilot processing system.

  16. Optimal design of active spreading systems to remediate sorbing groundwater contaminants in situ.

    PubMed

    Piscopo, Amy N; Neupauer, Roseanna M; Kasprzyk, Joseph R

    2016-07-01

    The effectiveness of in situ remediation to treat contaminated aquifers is limited by the degree of contact between the injected treatment chemical and the groundwater contaminant. In this study, candidate designs that actively spread the treatment chemical into the contaminant are generated using a multi-objective evolutionary algorithm. Design parameters pertaining to the amount of treatment chemical and the duration and rate of its injection are optimized according to objectives established for the remediation - maximizing contaminant degradation while minimizing energy and material requirements. Because groundwater contaminants have different reaction and sorption properties that influence their ability to be degraded with in situ remediation, optimization was conducted for six different combinations of reaction rate coefficients and sorption rates constants to represent remediation of the common groundwater contaminants, trichloroethene, tetrachloroethene, and toluene, using the treatment chemical, permanganate. Results indicate that active spreading for contaminants with low reaction rate coefficients should be conducted by using greater amounts of treatment chemical mass and longer injection durations relative to contaminants with high reaction rate coefficients. For contaminants with slow sorption or contaminants in heterogeneous aquifers, two different design strategies are acceptable - one that injects high concentrations of treatment chemical mass over a short duration or one that injects lower concentrations of treatment chemical mass over a long duration. Thus, decision-makers can select a strategy according to their preference for material or energy use. Finally, for scenarios with high ambient groundwater velocities, the injection rate used for active spreading should be high enough for the groundwater divide to encompass the entire contaminant plume. Copyright © 2016 Elsevier B.V. All rights reserved.

  17. Advanced fuel hydrocarbon remediation national test location - groundwater circulation well environmental cleanup systems

    SciTech Connect

    Heath, J.; Lory, E.

    1997-03-01

    When a contaminant is treated in place on the original site it is termed in situ remediation. Bioremediation refers to cleanup effected by living organisms such as bacteria and fungi. Certain species of bacteria are able to consume pollutants as a food source, thus detoxifying these compounds. In situ bioremediation is being considered as a viable and practical solution for reducing petroleum contamination levels in groundwater.

  18. Optimal design of active spreading systems to remediate sorbing groundwater contaminants in situ

    NASA Astrophysics Data System (ADS)

    Piscopo, Amy N.; Neupauer, Roseanna M.; Kasprzyk, Joseph R.

    2016-07-01

    The effectiveness of in situ remediation to treat contaminated aquifers is limited by the degree of contact between the injected treatment chemical and the groundwater contaminant. In this study, candidate designs that actively spread the treatment chemical into the contaminant are generated using a multi-objective evolutionary algorithm. Design parameters pertaining to the amount of treatment chemical and the duration and rate of its injection are optimized according to objectives established for the remediation - maximizing contaminant degradation while minimizing energy and material requirements. Because groundwater contaminants have different reaction and sorption properties that influence their ability to be degraded with in situ remediation, optimization was conducted for six different combinations of reaction rate coefficients and sorption rates constants to represent remediation of the common groundwater contaminants, trichloroethene, tetrachloroethene, and toluene, using the treatment chemical, permanganate. Results indicate that active spreading for contaminants with low reaction rate coefficients should be conducted by using greater amounts of treatment chemical mass and longer injection durations relative to contaminants with high reaction rate coefficients. For contaminants with slow sorption or contaminants in heterogeneous aquifers, two different design strategies are acceptable - one that injects high concentrations of treatment chemical mass over a short duration or one that injects lower concentrations of treatment chemical mass over a long duration. Thus, decision-makers can select a strategy according to their preference for material or energy use. Finally, for scenarios with high ambient groundwater velocities, the injection rate used for active spreading should be high enough for the groundwater divide to encompass the entire contaminant plume.

  19. Remediation of sentence processing deficits in aphasia using a computer-based microworld.

    PubMed

    Crerar, M A; Ellis, A W; Dean, E C

    1996-01-01

    Byng (1988) has argued that some aphasic patients who show problems in sentence comprehension are unable to "map" a syntactic analysis of the sentence form onto the thematic roles specified by the verb or preposition in the sentence. In Byng's study, therapy aimed at improving the mapping process as applied to sentences containing locative prepositions led to improvements not only in the comprehension of such sentences but also in the comprehension of reversible verb sentences. In the present study, 14 aphasic patients were selected for having problems with sentence-picture matching involving reversible verb and preposition sentences. These problems were shown to be stable across three pre-intervention assessments. All assessments were computer-based and involved the matching of written sentences to pictures. A small vocabulary was used in assessment and therapy which involved a "microworld" of three characters (ball, box, and star) which could engage in a limited number of actions and could occupy a limited set of spatial relationships. Before therapy began, all the patients were given an assessment battery which included a 40-item Verb Test and a 40-item Preposition Test. The patients were then divided into two groups, A and B. Group A received two 1-hr sessions of therapy per week for 3 weeks aimed at improving the comprehension of verb sentences, then a second full assessment, followed by the same amount of therapy aimed at improving the comprehension of preposition sentences, and finally a third assessment. Group B received the preposition therapy first, followed by the verb therapy. The therapy involved the patient and therapist interacting with the computer, either assembling pictures to match written sentences ("picture-building mode") or assembling sentences to match pictures ("sentence-building mode"). Group A showed a classical "cross-over" treatment outcome. Performance on treated verb sentences improved during verb therapy and was retained when therapy

  20. Digital TV processing system

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Two digital video data compression systems directly applicable to the Space Shuttle TV Communication System were described: (1) For the uplink, a low rate monochrome data compressor is used. The compression is achieved by using a motion detection technique in the Hadamard domain. To transform the variable source rate into a fixed rate, an adaptive rate buffer is provided. (2) For the downlink, a color data compressor is considered. The compression is achieved first by intra-color transformation of the original signal vector, into a vector which has lower information entropy. Then two-dimensional data compression techniques are applied to the Hadamard transformed components of this last vector. Mathematical models and data reliability analyses were also provided for the above video data compression techniques transmitted over a channel encoded Gaussian channel. It was shown that substantial gains can be achieved by the combination of video source and channel coding.

  1. Performance assessment of biofuel production in an algae-based remediation system.

    PubMed

    Wuang, Shy Chyi; Luo, Yanpei Darren; Wang, Simai; Chua, Pei Qiang Danny; Tee, Pok Siang

    2016-03-10

    The production of biofuel from microalgae has been an area of great interest as microalgae have higher productivities than land plants, and certain species have high lipid constituents which are the major feedstock for biodiesel production. One way to enhance the economic feasibility of algal-based biofuel is to couple it with waste remediation. This study investigated the technical feasibility of cultivating Chlorella sp. and Nannochloropsis sp. with fish water for biofuel production. The remediation potential of Chlorella sp. was found to be higher but the lipid yield is lower, when compared to Nannochloropsis sp. Lipid productivities were found to be similar for both types of algae at 1.1-1.3mgL(-1)h(-1). The fatty acid profiles of the obtained lipids were found suitable for biofuel production, and the calorific values were high at 30-32MJ/kg. The results provide insights into lipid production in Chlorella sp. and Nannochloropsis sp., when coupled with waste remediation.

  2. Secure Reliable Processing Systems

    DTIC Science & Technology

    1981-07-01

    independent security control, i.e. when access control decisions do not depend on stored application data values. This particular case is of considerable prac...kernel supports. It is true that the values stored as access con- trol data , the information used by the system to determine which users may access...following • I-’, responsibilities: 1. assure that a given data item is stored with the correct name labelling it, 2. check the access control

  3. Removal and degradation of phenol in a saturated flow by in-situ electrokinetic remediation and Fenton-like process.

    PubMed

    Yang, G C; Long, Y

    1999-11-15

    In this laboratory study, a sandy loam soil saturated with phenol solution was treated by in-situ electrokinetics-Fenton process incorporated with a permeable reactive wall of scrap iron powder (SIP). The soil was contaminated and saturated with aqueous phenol solution of 90-115 mg/kg in concentration. It was then placed in a soil cell. The soil cell was assembled with an anode reservoir and a cathode reservoir at its ends. A bed of SIP (1.05-32.69 g) was inserted in the soil cell at a distance of 5 cm from the anode reservoir compartment. For the test runs, 0.3% H(2)O(2) was used as the anode reservoir fluid, whereas de-ionized water was used as the cathode reservoir fluid. An electric gradient of 1 V/cm was applied to enhance the saturated flow in the soil cell for a period of 10 days. Experimental results have shown that the electroosmotic (EO) flow quantity decreased as the amount of SIP increased. This phenomenon was in good agreement with the results showing the value of EO permeability increased with a decreasing amount of SIP. Results also showed that throughout the test period the cumulative, consumed mass of H(2)O(2) in the anode reservoir increased as the amount of SIP decreased. On the other hand, the cumulative, increased mass of phenol in the cathode reservoir was found to increase with a decreasing amount of SIP. Meanwhile, the residual phenol concentration in the soil cell was found to decrease with a decreasing amount of SIP. When 1.05 g scrap iron powder was used, an overall removal and destruction efficiency of phenol of 99.7% was obtained. Therefore, it is evident that an in-situ combined technology of electrokinetic remediation and Fenton-like process is capable of simultaneously removing and degrading the phenol in a saturated flow.

  4. Sulfate Reduction in Groundwater: Characterization and Applications for Remediation

    SciTech Connect

    Miao, Z.; Brusseau, M. L.; Carroll, Kenneth C.; Carreon-Diazconti, C.; Johnson, B.

    2012-06-01

    Sulfate is ubiquitous in groundwater, with both natural and anthropogenic sources. Sulfate reduction reactions play a significant role in mediating redox conditions and biogeochemical processes for subsurface systems. They also serve as the basis for innovative in-situ methods for groundwater remediation. An overview of sulfate reduction in subsurface environments is provided, with a specific focus on implications for groundwater remediation. A case study presenting the results of a pilot-scale ethanol injection test illustrates the advantages and difficulties associated with the use of electron-donor amendments for sulfate remediation.

  5. Process Control Plan for Tank 241-SY-101 Surface Level Rise Remediation

    SciTech Connect

    ESTEY, S.D.

    1999-11-01

    The tank 241-SY-101 transfer system was conceived and designed to address the immediate needs presented by rapidly changing waste conditions in tank 241-SY-101. Within approximately the last year, the waste in this tank has exhibited unexpected behavior (Rassat et al. 1999) in the form of rapidly increasing crust growth. This growth has been brought about by a rapidly increasing rate of gas entrapment within the crust. It has been conceived that the lack of crust agitation beginning upon the advent of mixer pump operations may have set-up a more consolidated, gas impermeable barrier when compared to a crust regularly broken up by the prior buoyant displacement events within the tank. The interim goals of the project are to: (1) protect the mixer pump operability (2) begin releasing gas from the crust, and (3) begin dissolving the crust and solids in the slurry layer. The final goals of the project (Final State) are to solve both the level growth and BD-GRE safety issues in this tank by achieving a condition of the waste such that no active measures are required to safely store the waste, i.e., crust and non convective layer are mostly dissolved, and therefore the mixer pump will no longer be needed to prevent BD-GREs in excess of 100% LFL. Transfers (which are designed to create space in the tank) and dilution (which will dissolve the solids) will accomplish this. Dissolution of solids will result in a release of gas retained by those solids and remove that volume of solids as a future retention site.

  6. Process gas solidification system

    DOEpatents

    Fort, William G. S.; Lee, Jr., William W.

    1978-01-01

    It has been the practice to (a) withdraw hot, liquid UF.sub.6 from various systems, (b) direct the UF.sub.6 into storage cylinders, and (c) transport the filled cylinders to another area where the UF.sub.6 is permitted to solidify by natural cooling. However, some hazard attends the movement of cylinders containing liquid UF.sub.6, which is dense, toxic, and corrosive. As illustrated in terms of one of its applications, the invention is directed to withdrawing hot liquid UF.sub.6 from a system including (a) a compressor for increasing the pressure and temperature of a stream of gaseous UF.sub.6 to above its triple point and (b) a condenser for liquefying the compressed gas. A network containing block valves and at least first and second portable storage cylinders is connected between the outlet of the condenser and the suction inlet of the compressor. After an increment of liquid UF.sub.6 from the condenser has been admitted to the first cylinder, the cylinder is connected to the suction of the compressor to flash off UF.sub.6 from the cylinder, thus gradually solidifying UF.sub.6 therein. While the first cylinder is being cooled in this manner, an increment of liquid UF.sub.6 from the condenser is transferred into the second cylinder. UF.sub.6 then is flashed from the second cylinder while another increment of liquid UF.sub.6 is being fed to the first. The operations are repeated until both cylinders are filled with solid UF.sub.6, after which they can be moved safely. As compared with the previous technique, this procedure is safer, faster, and more economical. The method also provides the additional advantage of removing volatile impurities from the UF.sub.6 while it is being cooled.

  7. Toxicological screening in urine: comparison of two automated HPLC screening systems, toxicological identification system (TOX.I.S.*) versus REMEDI-HS.

    PubMed

    Schönberg, Lena; Grobosch, Thomas; Lampe, Dagmar; Kloft, Charlotte

    2007-01-01

    In this paper, the comparison of two automated high-performance liquid chromatography (HPLC) screening systems, a newly developed toxicological identification system (TOX.I.S.) versus the commercially available Remedi-HS (Bio-Rad), is presented. Urine samples from 405 cases screened positive for amphetamines, cocaine, and opiates by immunological assays and confirmed by GC-MS were analyzed with both systems. In more than 80% (TOX.I.S.) and 78% (Remedi-HS) of the cases (except for cocaine), the results obtained by both HPLC methods showed agreement with the earlier obtained results by immunoassay prescreening and gas chromatography-mass spectrometry (GC-MS). The evaluation showed that both automated HPLC methods led to comparable results and can be used alternatively. As the confirmation results for cocaine were rather poor (45% TOX.I.S., 54% Remedi-HS) in comparison to GC-MS, the TOX.I.S. was further optimized for the detection of the cocaine metabolite benzoylecgonine (BEC). The BEC method improved the detectability of BEC from 45% to 80%. Besides confirmation screening, the use of both systems in cases of acute intoxications was investigated. Information about basic compounds was obtained from urine screening by both systems, which therefore were useful as complementary techniques in the toxicological laboratory. The TOX.I.S. offers advantages such as common equipment, modern software, and higher versatility with the opportunity to establish additional methods in the system.

  8. Management assessment of tank waste remediation system contractor readiness to proceed with phase 1B privatization

    SciTech Connect

    Certa, P.J.

    1998-01-07

    Readiness to Proceed With Phase 1B Privatization documents the processes used to determine readiness to proceed with tank waste treatment technologies from private industry, now known as TWRS privatization. An overall systems approach was applied to develop action plans to support the retrieval and disposal mission of the TWRS Project. The systems and infrastructure required to support the mission are known. Required systems are either in place or plans have been developed to ensure they exist when needed. Since October 1996 a robust system engineering approach to establishing integrated Technical Baselines, work breakdown structures, tank farms organizational structure and configurations, work scope, and costs has become part of the culture within the TWRS Project. An analysis of the programmatic, management, and technical activities necessary to declare readiness to proceed with execution of the mission demonstrates that the system, personnel, and hardware will be on line and ready to support the private contractors. The systems approach included defining the retrieval and disposal mission requirements and evaluating the readiness of the Project Hanford Management Contract (PHMC) team to support initiation of waste processing by the private contractors in June 2002 and to receive immobilized waste shortly thereafter. The Phase 1 feed delivery requirements from the private contractor Requests for Proposal were reviewed. Transfer piping routes were mapped, existing systems were evaluated, and upgrade requirements were defined.

  9. Implications of soil mixing for NAPL source zone remediation: Column studies and modeling of field-scale systems

    NASA Astrophysics Data System (ADS)

    Olson, Mitchell R.; Sale, Tom C.

    2015-06-01

    Soil remediation is often inhibited by subsurface heterogeneity, which constrains contaminant/reagent contact. Use of soil mixing techniques for reagent delivery provides a means to overcome contaminant/reagent contact limitations. Furthermore, soil mixing reduces the permeability of treated soils, thus extending the time for reactions to proceed. This paper describes research conducted to evaluate implications of soil mixing on remediation of non-aqueous phase liquid (NAPL) source zones. The research consisted of column studies and subsequent modeling of field-scale systems. For column studies, clean influent water was flushed through columns containing homogenized soils, granular zero valent iron (ZVI), and trichloroethene (TCE) NAPL. Within the columns, NAPL depletion occurred due to dissolution, followed by either column-effluent discharge or ZVI-mediated degradation. Complete removal of TCE NAPL from the columns occurred in 6-8 pore volumes of flow. However, most of the TCE (> 96%) was discharged in the column effluent; less than 4% of TCE was degraded. The low fraction of TCE degraded is attributed to the short hydraulic residence time (< 4 days) in the columns. Subsequently, modeling was conducted to scale up column results. By scaling up to field-relevant system sizes (> 10 m) and reducing permeability by one-or-more orders of magnitude, the residence time could be greatly extended, potentially for periods of years to decades. Model output indicates that the fraction of TCE degraded can be increased to > 99.9%, given typical post-mixing soil permeability values. These results suggest that remediation performance can be greatly enhanced by combining contaminant degradation with an extended residence time.

  10. Implications of soil mixing for NAPL source zone remediation: Column studies and modeling of field-scale systems.

    PubMed

    Olson, Mitchell R; Sale, Tom C

    2015-01-01

    Soil remediation is often inhibited by subsurface heterogeneity, which constrains contaminant/reagent contact. Use of soil mixing techniques for reagent delivery provides a means to overcome contaminant/reagent contact limitations. Furthermore, soil mixing reduces the permeability of treated soils, thus extending the time for reactions to proceed. This paper describes research conducted to evaluate implications of soil mixing on remediation of non-aqueous phase liquid (NAPL) source zones. The research consisted of column studies and subsequent modeling of field-scale systems. For column studies, clean influent water was flushed through columns containing homogenized soils, granular zero valent iron (ZVI), and trichloroethene (TCE) NAPL. Within the columns, NAPL depletion occurred due to dissolution, followed by either column-effluent discharge or ZVI-mediated degradation. Complete removal of TCE NAPL from the columns occurred in 6-8 pore volumes of flow. However, most of the TCE (>96%) was discharged in the column effluent; less than 4% of TCE was degraded. The low fraction of TCE degraded is attributed to the short hydraulic residence time (<4 days) in the columns. Subsequently, modeling was conducted to scale up column results. By scaling up to field-relevant system sizes (>10 m) and reducing permeability by one-or-more orders of magnitude, the residence time could be greatly extended, potentially for periods of years to decades. Model output indicates that the fraction of TCE degraded can be increased to >99.9%, given typical post-mixing soil permeability values. These results suggest that remediation performance can be greatly enhanced by combining contaminant degradation with an extended residence time. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. Reimagining Remediation

    ERIC Educational Resources Information Center

    Handel, Stephen J.; Williams, Ronald A.

    2011-01-01

    In 2007, the College Board's Community College Advisory Panel--a group of college presidents that advises the organization's membership on community college issues--asked these authors to write a paper describing effective remedial education programs. They never wrote the paper. The problem was not the lack of dedicated faculty and staff working…

  12. Process Knowledge Characterization of Radioactive Waste at the Classified Waste Landfill Remediation Project Sandia National Laboratories, Albuquerque, New Mexico

    SciTech Connect

    DOTSON,PATRICK WELLS; GALLOWAY,ROBERT B.; JOHNSON JR,CARL EDWARD

    1999-11-03

    This paper discusses the development and application of process knowledge (PK) to the characterization of radioactive wastes generated during the excavation of buried materials at the Sandia National Laboratories/New Mexico (SNL/NM) Classified Waste Landfill (CWLF). The CWLF, located in SNL/NM Technical Area II, is a 1.5-acre site that received nuclear weapon components and related materials from about 1950 through 1987. These materials were used in the development and testing of nuclear weapon designs. The CWLF is being remediated by the SNL/NM Environmental Restoration (ER) Project pursuant to regulations of the New Mexico Environment Department. A goal of the CWLF project is to maximize the amount of excavated materials that can be demilitarized and recycled. However, some of these materials are radioactively contaminated and, if they cannot be decontaminated, are destined to require disposal as radioactive waste. Five major radioactive waste streams have been designated on the CWLF project, including: unclassified soft radioactive waste--consists of soft, compatible trash such as paper, plastic, and plywood; unclassified solid radioactive waste--includes scrap metal, other unclassified hardware items, and soil; unclassified mixed waste--contains the same materials as unclassified soft or solid radioactive waste, but also contains one or more Resource Conservation and Recovery Act (RCRA) constituents; classified radioactive waste--consists of classified artifacts, usually weapons components, that contain only radioactive contaminants; and classified mixed waste--comprises radioactive classified material that also contains RCRA constituents. These waste streams contain a variety of radionuclides that exist both as surface contamination and as sealed sources. To characterize these wastes, the CWLF project's waste management team is relying on data obtained from direct measurement of radionuclide activity content to the maximum extent possible and, in cases where

  13. A system to investigate the remediation of organic vapors using microwave-induced plasma with fluidized carbon granules

    SciTech Connect

    Dawson, Elizabeth A.; Parkes, Gareth M. B.; Bond, Gary; Mao, Runjie

    2009-03-15

    This article describes a system to investigate the parameters for the remediation of organic vapors using microwave-induced plasma on fluidized carbon granules. The system is based on a single mode microwave apparatus with a variable power (2.45 GHz) generator. Carbon granules are fluidized in a silica tube situated in the sample section of a waveguide incorporating two additional ports to allow plasma intensity monitoring using a light sensor and imaging with a digital camera. A fluoroptic probe is used for in situ measurement of the carbon granule temperature, while the effluent gas temperature is measured with a thermocouple situated in the silica tube outside the cavity. Data acquisition and control software allow experiments using a variety of microwave power regimes while simultaneously recording the light intensity of any plasma generated within the carbon bed, together with its temperature. Evaluation using two different granular activated carbons and ethyl acetate, introduced as a vapor into the fluidizing air stream at a concentration of 1 ppm, yielded results which indicated that significant destruction of ethyl acetate, as monitored using a mass spectrometer, was achieved only with the carbon granules showing high plasma activity under pulsed microwave conditions. The system is therefore suitable for comparison of the relative microwave activities of various activated carbon granules and their performance in microwave remediation and regeneration.

  14. A system to investigate the remediation of organic vapors using microwave-induced plasma with fluidized carbon granules.

    PubMed

    Dawson, Elizabeth A; Parkes, Gareth M B; Bond, Gary; Mao, Runjie

    2009-03-01

    This article describes a system to investigate the parameters for the remediation of organic vapors using microwave-induced plasma on fluidized carbon granules. The system is based on a single mode microwave apparatus with a variable power (2.45 GHz) generator. Carbon granules are fluidized in a silica tube situated in the sample section of a waveguide incorporating two additional ports to allow plasma intensity monitoring using a light sensor and imaging with a digital camera. A fluoroptic probe is used for in situ measurement of the carbon granule temperature, while the effluent gas temperature is measured with a thermocouple situated in the silica tube outside the cavity. Data acquisition and control software allow experiments using a variety of microwave power regimes while simultaneously recording the light intensity of any plasma generated within the carbon bed, together with its temperature. Evaluation using two different granular activated carbons and ethyl acetate, introduced as a vapor into the fluidizing air stream at a concentration of 1 ppm, yielded results which indicated that significant destruction of ethyl acetate, as monitored using a mass spectrometer, was achieved only with the carbon granules showing high plasma activity under pulsed microwave conditions. The system is therefore suitable for comparison of the relative microwave activities of various activated carbon granules and their performance in microwave remediation and regeneration.

  15. Performance Assessment of the Waste Dislodging Conveyance System During the Gunite And Associated Tanks Remediation Project

    SciTech Connect

    Lloyd, P.D.

    2001-02-21

    The Waste Dislodging and Conveyance System (WD and CS) and other components of the Tank Waste Retrieval System (TWRS) were developed to address the need for removal of hazardous wastes from underground storage tanks (USTs) in which radiation levels and access limitations make traditional waste retrieval methods impractical. Specifically, these systems were developed for cleanup of the Gunite and Associated Tanks (GAAT) Operable Unit (OU) at the Oak Ridge National Laboratory (ORNL). The WD and CS is comprised of a number of different components. The three primary hardware subsystems are the Hose Management System (HMS), the Confined Sluicing End-Effector (CSEE), and the Flow Control Equipment and Containment Box (FCE/CB). In addition, a Decontamination Spray Ring (DSR) and a control system were developed for the system. The WD and CS is not a stand-alone system; rather, it is designed for deployment with either a long-reach manipulator like the Modified Light Duty Utility Arm (MLDUA) or a remotely operated vehicle system such as the Houdini{trademark}. The HMS was designed to act as a pipeline for the transfer of dislodged waste; as a hose-positioning and tether-management system; and as a housing for process equipment such as the water-powered jet pump that provides the necessary suction to vacuum slurried waste from the UST. The HMS was designed to facilitate positioning of an end-effector at any point within the 25-ft- or 50-ft-diameter USTs in the GAAT OU.

  16. Simulation of the injection of colloidal suspensions for the remediation of contaminated aquifer systems

    NASA Astrophysics Data System (ADS)

    Tosco, Tiziana; Gastone, Francesca; Sethi, Rajandrea

    2014-05-01

    Concentrated suspensions of microscale and nanoscale zerovalent iron particles (MZVI and NZVI) have been studied in recent years for the remediation of contaminated aquifers. The suspensions are injected into the subsurface to generate a reactive zone, and consequently the prediction of the particles distribution during the injection is a key aspect in the design of a field-scale injection. Colloidal dispersions of MZVI and NZVI are not stable in pure water, and shear thinning, environmentally friendly fluids (guar gum and xanthan gum solutions) were found to be effective in improving colloidal stability, thus greatly improving handling and injectability (1 - 3). Shear thinning fluids exhibit high viscosity in static conditions, improving the colloidal stability, and lower viscosity at high flow rates enabling the injection at limited pressures. Shear thinning fluids exhibit high viscosity in static conditions, improving the colloidal stability, and lower viscosity at high flow rates enabling the injection at limited pressures. In this work, co-funded by European Union project AQUAREHAB (FP7 - Grant Agreement Nr. 226565), laboratory and pilot field tests for MZVI injection in saturated porous media are reported. MZVI was dispersed in guar gum solutions, and the transport behaviour under several polymer concentrations and injection rates was assessed in column tests (4). Based on the experimental results, a modelling approach is proposed to simulate the transport in porous media of nanoscale iron slurries, implemented in E-MNM1D (www.polito.it/groundwater/software). Colloid transport mechanisms are controlled by particle-collector and particle-particle interactions, usually modelled by a non equilibrium kinetic model accounting for deposition and release processes. The key aspects included in the E-MNM1D are clogging phenomena (i.e. reduction of porosity and permeability due to particles deposition), and the rheological properties of the carrier fluid (in this

  17. ICDF Complex Remedial Action Work Plan

    SciTech Connect

    W. M. Heileson

    2006-12-01

    This Remedial Action Work Plan provides the framework for operation of the Idaho Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Disposal Facility Complex (ICDF). This facility includes (a) an engineered landfill that meets the substantial requirements of DOE Order 435.1, Resource Conservation and Recovery Act Subtitle C, Idaho Hazardous Waste Management Act, and Toxic Substances Control Act polychlorinated biphenyl landfill requirements; (b) centralized receiving, inspections, administration, storage/staging, and treatment facilities necessary for CERCLA investigation-derived, remedial, and removal waste at the Idaho National Laboratory (INL) prior to final disposition in the disposal facility or shipment off-Site; and (c) an evaporation pond that has been designated as a corrective action management unit. The ICDF Complex, including a buffer zone, will cover approximately 40 acres, with a landfill disposal capacity of approximately 510,000 yd3. The ICDF Complex is designed and authorized to accept INL CERCLA-generated wastes, and includes the necessary subsystems and support facilities to provide a complete waste management system. This Remedial Action Work Plan presents the operational approach and requirements for the various components that are part of the ICDF Complex. Summaries of the remedial action work elements are presented herein, with supporting information and documents provided as appendixes to this work plan that contain specific detail about the operation of the ICDF Complex. This document presents the planned operational process based upon an evaluation of the remedial action requirements set forth in the Operable Unit 3-13 Final Record of Decision.

  18. Respiratory Allergies: A General Overview of Remedies, Delivery Systems, and the Need to Progress

    PubMed Central

    Colombo, Giselda; Celenza, Cinzia

    2014-01-01

    The spread of respiratory allergies is increasing in parallel with the alarm of the scientific community. Evidently, our knowledge of the onset mechanisms of these diseases and, as a consequence, of the available remedies is inadequate. This review provides a brief, general description of current therapeutic resources and the state of research with regard to both drugs and medical devices in order to highlight their limits and the urgent need for progress. Increasing the amount of basic biochemical research will improve our knowledge of such onset mechanisms and the potential efficacy of therapeutic preparations. PMID:25006500

  19. Remediation; An overview

    SciTech Connect

    Bishop, J.

    1988-09-01

    The U.SD. government began committing the nation legally and financially in the last decade to the ultimate remediation of virtually all of the hazardous wastes that were produced in the past and remain to threaten human health and the environment, all that continue to be generated, and all that will be created in the future. Whether engendered by acts of God or human industry, the laws and regulations mandate, hazardous wastes and the threats they pose will be removed or rendered harmless. As mobilization for tackling the monumental task implied by those commitments has progressed, key concepts have changed in meaning. The remedy of remediation once literally meant burying our hazardous waste problems in landfills, for example, a solution now officially defined as the least desirable-although still commonly chosen - course of action. The process of identifying hazardous substances and determining in what quantities they constitute health and environmental hazards continues apace. As measurement technologies become increasingly precise and capable to detecting more 9s to the right of the decimal point, acceptable levels of emissions into the air and concentrations in the ground or water are reduced. This article is intended as a sketch of where the national commitment of remediation currently stands, with examples of implications for both generators of hazardous wastes and those who have entered-or seek to enter-the rapidly growing business of remediation.

  20. Optimal design of groundwater remediation systems using a probabilistic multi-objective fast harmony search algorithm under uncertainty

    NASA Astrophysics Data System (ADS)

    Luo, Q.; Wu, J.; Qian, J.

    2013-12-01

    This study develops a new probabilistic multi-objective fast harmony search algorithm (PMOFHS) for optimal design of groundwater remediation system under uncertainty associated with the hydraulic conductivity of aquifers. The PMOFHS integrates the previously developed deterministic multi-objective optimization method, namely multi-objective fast harmony search algorithm (MOFHS) with a probabilistic Pareto domination ranking and probabilistic niche technique to search for Pareto-optimal solutions to multi-objective optimization problems in a noisy hydrogeological environment arising from insufficient hydraulic conductivity data. The PMOFHS is then coupled with the commonly used flow and transport codes, MODFLOW and MT3DMS, to identify the optimal groundwater remediation system of a two-dimensional hypothetical test problem involving two objectives: (i) minimization of the total remediation cost through the engineering planning horizon, and (ii) minimization of the percentage of mass remaining in the aquifer at the end of the operational period, which uses the Pump-and-Treat (PAT) technology to clean up contaminated groundwater. Also, Monte Carlo (MC) analysis is used to demonstrate the effectiveness of the proposed methodology. The MC analysis is taken to each Pareto solutions for every K realization. Then the statistical mean and the upper and lower bounds of uncertainty intervals of 95% confidence level are calculated. The MC analysis results show that all of the Pareto-optimal solutions are located between the upper and lower bounds of the MC analysis. Moreover, the root mean square errors (RMSEs) between the Pareto-optimal solutions by the PMOFHS and the average values of optimal solutions by the MC analysis are 0.0204 for the first objective and 0.0318 for the second objective, quite smaller than those RMSEs between the results by the existing probabilistic multi-objective genetic algorithm (PMOGA) and the MC analysis, 0.0384 and 0.0397, respectively. In

  1. The Process of Systemic Change

    ERIC Educational Resources Information Center

    Duffy, Francis M.; Reigeluth, Charles M.; Solomon, Monica; Caine, Geoffrey; Carr-Chellman, Alison A.; Almeida, Luis; Frick, Theodore; Thompson, Kenneth; Koh, Joyce; Ryan, Christopher D.; DeMars, Shane

    2006-01-01

    This paper presents several brief papers about the process of systemic change. These are: (1) Step-Up-To-Excellence: A Protocol for Navigating Whole-System Change in School Districts by Francis M. Duffy; (2) The Guidance System for Transforming Education by Charles M. Reigeluth; (3) The Schlechty Center For Leadership In School Reform by Monica…

  2. The Process of Systemic Change

    ERIC Educational Resources Information Center

    Duffy, Francis M.; Reigeluth, Charles M.; Solomon, Monica; Caine, Geoffrey; Carr-Chellman, Alison A.; Almeida, Luis; Frick, Theodore; Thompson, Kenneth; Koh, Joyce; Ryan, Christopher D.; DeMars, Shane

    2006-01-01

    This paper presents several brief papers about the process of systemic change. These are: (1) Step-Up-To-Excellence: A Protocol for Navigating Whole-System Change in School Districts by Francis M. Duffy; (2) The Guidance System for Transforming Education by Charles M. Reigeluth; (3) The Schlechty Center For Leadership In School Reform by Monica…

  3. The Impact of Traditional Septic Tank Soakaway Systems and the Effects of Remediation on Water Quality in Ireland

    NASA Astrophysics Data System (ADS)

    Kilroy, Kate; Keggan, Mary; Barrett, Maria; Dubber, Donata; Gill, Laurence W.; O'Flaherty, Vincent

    2014-05-01

    In Ireland the domestic wastewater of over 1/3 of the population is treated by on-site systems. These systems are based on a traditional design for disposal of domestic wastewater and rely on the surrounding subsoil for further treatment. Inefficient treatment is often associated with these systems and can cause pollution of local aquifers and waterways. The effluent nutrient load can contribute to eutrophication, depletion of dissolved oxygen and excessive algae growth in surface water bodies. Human enteric pathogens associated with faecal pollution of water sources may promote the outbreak of disease through contamination of drinking water supplies. The subsoil attenuation plays an important role in the protection of groundwater from effluent pollution. Therefore, as over 25% of the countries domestic water supplies are provided by groundwater, the protection of groundwater resources is crucial. This project involves both the assessment of traditional septic tank soakaway systems and the effects of remediation in low permeability subsoil settings on water quality in Ireland. The study aims to confirm by microbial source tracking (MST), the source (human and/or animal) of faecal microorganisms detected in groundwater, surface water and effluent samples, and to monitor the transport of pathogens specific to on-site wastewater outflows. In combination with MST, the evaluation of nitrification and denitrification in surrounding soil and effluent samples aims to assess nitrogen removal at specific intervals; pre-remediation and post-remediation. Two experimental sites have been routinely sampled for effluent, soil and groundwater samples as well as soil moisture samples using suction lysimeters located at various depths. A robust and reproducible DNA extraction method was developed, applicable to both sites. MST markers based on host-specific Bacteriodales bacteria for universal, human and cow-derived faecal matter are being employed to determine quantitative target

  4. Development of a remediation strategy for surface soils contaminated with energetic materials by thermal processes: Phases 1, 2 and 3

    DTIC Science & Technology

    2009-11-01

    Various remediation strategies are currently being studied ( phytoremediation , fire ecology, etc.) in order to address the problem of surface soils...treatments for explosives-contaminated soils: aqueous-phase bioreactor treatment, composting, land farming, phytoremediation , white rot fungus treatment...study achieved a 30 to 40 % contaminant degradation. • Phytoremediation : The U.S. Army Environmental Center (USAEC) is developing technologies to

  5. Overview of the LAU Center Technical Assistance Process and the Office for Civil Rights Task Force Remedies: Phase 1 Manual.

    ERIC Educational Resources Information Center

    Mazon, M. Reyes

    This manual, first in a series dealing with the Lau Center technical assistance approach, is designed to assist school districts in their efforts to develop an educational master plan to meet Title VI (1964 Civil Rights Act) compliance guidelines. The manual summarizes the legislation, judicial decisions, and the Task Force Remedies which have…

  6. [Analysis of heavy-metal-mediated disease and development of a novel remediation system based on fieldwork and experimental research].

    PubMed

    Yajima, Ichiro; Zou, Cunchao; Li, Xiang; Nakano, Chizuru; Omata, Yasuhiro; Kumasaka, Mayuko Y

    2015-01-01

    Heavy-metal pollution occurs in various environments, including water, air and soil, and has serious effects on human health. Since heavy-metal pollution in drinking water causes various diseases including skin cancer, it has become a global problem worldwide. However, there is limited information on the mechanism of development of heavy-metal-mediated disease. We performed both fieldwork and experimental studies to elucidate the levels of heavy-metal pollution and mechanisms of development of heavy-metal-related disease and to develop a novel remediation system. Our fieldwork in Bangladesh, Vietnam and Malaysia demonstrated that drinking well water in these countries was polluted with high concentrations of several heavy metals including arsenic, barium, iron and manganese. Our experimental studies based on the data from our fieldwork demonstrated that these heavy metals caused skin cancer and hearing loss. Further experimental studies resulted in the development of a novel remediation system with which toxic heavy metals were absorbed from polluted drinking water. Implementation of both fieldwork and experimental studies is important for prediction, prevention and therapy of heavy-metal-mediated diseases.

  7. Plutonium process monitoring (PPM) system

    NASA Astrophysics Data System (ADS)

    Wong, A. S.; Ricketts, T. E.; Pansoy-Hejlvik, M. E.; Ramsey, K. B.; Hansel, K. M.; Romero, M. K.

    2000-07-01

    In mid-1980, Marsh and Pope developed an online gamma system to monitor americium, uranium and plutonium gamma rays during anion-exchange process for plutonium aqueous recovery operations. It has been shown that the real-time elution profiles of actinide impurities are important for plutonium loss via break-through, waste minimization, and process monitoring. However, the current monitoring equipment and data acquisition software are obsolete and are frequently problematic. In 1999, we redesigned the on-line gamma monitoring system in collaboration with Perkin-Elmer ORTEC (Oak Ridge, TN) to enhance and upgrade the current system. This paper describes the new integrated plutonium process monitoring (PPM) system for the aqueous plutonium recovery and anion-exchange processes at the Los Alamos Plutonium Facility.

  8. Intelligent Work Process Engineering System

    NASA Technical Reports Server (NTRS)

    Williams, Kent E.

    2003-01-01

    Optimizing performance on work activities and processes requires metrics of performance for management to monitor and analyze in order to support further improvements in efficiency, effectiveness, safety, reliability and cost. Information systems are therefore required to assist management in making timely, informed decisions regarding these work processes and activities. Currently information systems regarding Space Shuttle maintenance and servicing do not exist to make such timely decisions. The work to be presented details a system which incorporates various automated and intelligent processes and analysis tools to capture organize and analyze work process related data, to make the necessary decisions to meet KSC organizational goals. The advantages and disadvantages of design alternatives to the development of such a system will be discussed including technologies, which would need to bedesigned, prototyped and evaluated.

  9. Stochastic goal programming based groundwater remediation management under human-health-risk uncertainty.

    PubMed

    Li, Jing; He, Li; Lu, Hongwei; Fan, Xing

    2014-08-30

    An optimal design approach for groundwater remediation is developed through incorporating numerical simulation, health risk assessment, uncertainty analysis and nonlinear optimization within a general framework. Stochastic analysis and goal programming are introduced into the framework to handle uncertainties in real-world groundwater remediation systems. Carcinogenic risks associated with remediation actions are further evaluated at four confidence levels. The differences between ideal and predicted constraints are minimized by goal programming. The approach is then applied to a contaminated site in western Canada for creating a set of optimal remediation strategies. Results from the case study indicate that factors including environmental standards, health risks and technical requirements mutually affected and restricted themselves. Stochastic uncertainty existed in the entire process of remediation optimization, which should to be taken into consideration in groundwater remediation design.

  10. Simultaneous application of chemical oxidation and extraction processes is effective at remediating soil Co-contaminated with petroleum and heavy metals.

    PubMed

    Yoo, Jong-Chan; Lee, Chadol; Lee, Jeung-Sun; Baek, Kitae

    2017-01-15

    Chemical extraction and oxidation processes to clean up heavy metals and hydrocarbon from soil have a higher remediation efficiency and take less time than other remediation processes. In batch extraction/oxidation process, 3% hydrogen peroxide (H2O2) and 0.1 M ethylenediaminetetraacetic acid (EDTA) could remove approximately 70% of the petroleum and 60% of the Cu and Pb in the soil, respectively. In particular, petroleum was effectively oxidized by H2O2 without addition of any catalysts through dissolution of Fe oxides in natural soils. Furthermore, heavy metals bound to Fe-Mn oxyhydroxides could be extracted by metal-EDTA as well as Fe-EDTA complexation due to the high affinity of EDTA for metals. However, the strong binding of Fe-EDTA inhibited the oxidation of petroleum in the extraction-oxidation sequential process because Fe was removed during the extraction process with EDTA. The oxidation-extraction sequential process did not significantly enhance the extraction of heavy metals from soil, because a small portion of heavy metals remained bound to organic matter. Overall, simultaneous application of oxidation and extraction processes resulted in highly efficient removal of both contaminants; this approach can be used to remove co-contaminants from soil in a short amount of time at a reasonable cost. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Sustainable multistage process for enhanced productivity of bioplastics from waste remediation through aerobic dynamic feeding strategy: Process integration for up-scaling.

    PubMed

    Amulya, K; Jukuri, Srinivas; Venkata Mohan, S

    2015-01-01

    Polyhydroxyalkanoates (PHA) production was evaluated in a multistage operation using food waste as a renewable feedstock. The first step involved the production of bio-hydrogen (bio-H2) via acidogenic fermentation. Volatile fatty acid (VFA) rich effluent from bio-H2 reactor was subsequently used for PHA production, which was carried out in two stages, Stage II (culture enrichment) and Stage III (PHA production). PHA-storing microorganisms were enriched in a sequencing batch reactor (SBR), operated at two different cycle lengths (CL-24; CL-12). Higher polymer recovery as well as VFA removal was achieved in CL-12 operation both in Stage II (16.3% dry cell weight (DCW); VFA removal, 84%) and Stage III (23.7% DCW; VFA removal, 88%). The PHA obtained was a co-polymer [P(3HB-co-3HV)] of PHB and PHV. The results obtained indicate that this integrated multistage process offers new opportunities to further leverage large scale PHA production with simultaneous waste remediation in the framework of biorefinery. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. Thermal processing system concepts and considerations for RWMC buried waste

    SciTech Connect

    Eddy, T.L.; Kong, P.C.; Raivo, B.D.; Anderson, G.L.

    1992-02-01

    This report presents a preliminary determination of ex situ thermal processing system concepts and related processing considerations for application to remediation of transuranic (TRU)-contaminated buried wastes (TRUW) at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Beginning with top-level thermal treatment concepts and requirements identified in a previous Preliminary Systems Design Study (SDS), a more detailed consideration of the waste materials thermal processing problem is provided. Anticipated waste stream elements and problem characteristics are identified and considered. Final waste form performance criteria, requirements, and options are examined within the context of providing a high-integrity, low-leachability glass/ceramic, final waste form material. Thermal processing conditions required and capability of key systems components (equipment) to provide these material process conditions are considered. Information from closely related companion study reports on melter technology development needs assessment and INEL Iron-Enriched Basalt (IEB) research are considered. Five potentially practicable thermal process system design configuration concepts are defined and compared. A scenario for thermal processing of a mixed waste and soils stream with essentially no complex presorting and using a series process of incineration and high temperature melting is recommended. Recommendations for applied research and development necessary to further detail and demonstrate the final waste form, required thermal processes, and melter process equipment are provided.

  13. Thermal processing system concepts and considerations for RWMC buried waste

    SciTech Connect

    Eddy, T.L.; Kong, P.C.; Raivo, B.D.; Anderson, G.L.

    1992-02-01

    This report presents a preliminary determination of ex situ thermal processing system concepts and related processing considerations for application to remediation of transuranic (TRU)-contaminated buried wastes (TRUW) at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Beginning with top-level thermal treatment concepts and requirements identified in a previous Preliminary Systems Design Study (SDS), a more detailed consideration of the waste materials thermal processing problem is provided. Anticipated waste stream elements and problem characteristics are identified and considered. Final waste form performance criteria, requirements, and options are examined within the context of providing a high-integrity, low-leachability glass/ceramic, final waste form material. Thermal processing conditions required and capability of key systems components (equipment) to provide these material process conditions are considered. Information from closely related companion study reports on melter technology development needs assessment and INEL Iron-Enriched Basalt (IEB) research are considered. Five potentially practicable thermal process system design configuration concepts are defined and compared. A scenario for thermal processing of a mixed waste and soils stream with essentially no complex presorting and using a series process of incineration and high temperature melting is recommended. Recommendations for applied research and development necessary to further detail and demonstrate the final waste form, required thermal processes, and melter process equipment are provided.

  14. Removing Remediation Requirements: Effectiveness of Intervention Programs

    ERIC Educational Resources Information Center

    Fine, Anne; Duggan, Mickle; Braddy, Linda

    2009-01-01

    Remediation of incoming college freshman students is a national concern because remediated students are at higher risk of failing to complete their degrees. Some Oklahoma higher education institutions are working to assist K-12 systems in finding ways to reduce the number of incoming college freshman students requiring remediation. This study…

  15. Removing Remediation Requirements: Effectiveness of Intervention Programs

    ERIC Educational Resources Information Center

    Fine, Anne; Duggan, Mickle; Braddy, Linda

    2009-01-01

    Remediation of incoming college freshman students is a national concern because remediated students are at higher risk of failing to complete their degrees. Some Oklahoma higher education institutions are working to assist K-12 systems in finding ways to reduce the number of incoming college freshman students requiring remediation. This study…

  16. 48 CFR 2009.570-10 - Remedies.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... ACQUISITION PLANNING CONTRACTOR QUALIFICATIONS Organizational Conflicts of Interest 2009.570-10 Remedies. In addition to other remedies permitted by law or contract for a breach of the restrictions in this subpart or... 48 Federal Acquisition Regulations System 6 2010-10-01 2010-10-01 true Remedies....

  17. Innovative vitrification for soil remediation

    SciTech Connect

    Jetta, N.W.; Patten, J.S.; Hart, J.G.

    1995-12-01

    The objective of this DOE demonstration program is to validate the performance and operation of the Vortec Cyclone Melting System (CMS{trademark}) for the processing of LLW contaminated soils found at DOE sites. This DOE vitrification demonstration project has successfully progressed through the first two phases. Phase 1 consisted of pilot scale testing with surrogate wastes and the conceptual design of a process plant operating at a generic DOE site. The objective of Phase 2, which is scheduled to be completed the end of FY 95, is to develop a definitive process plant design for the treatment of wastes at a specific DOE facility. During Phase 2, a site specific design was developed for the processing of LLW soils and muds containing TSCA organics and RCRA metal contaminants. Phase 3 will consist of a full scale demonstration at the DOE gaseous diffusion plant located in Paducah, KY. Several DOE sites were evaluated for potential application of the technology. Paducah was selected for the demonstration program because of their urgent waste remediation needs as well as their strong management and cost sharing financial support for the project. During Phase 2, the basic nitrification process design was modified to meet the specific needs of the new waste streams available at Paducah. The system design developed for Paducah has significantly enhanced the processing capabilities of the Vortec vitrification process. The overall system design now includes the capability to shred entire drums and drum packs containing mud, concrete, plastics and PCB`s as well as bulk waste materials. This enhanced processing capability will substantially expand the total DOE waste remediation applications of the technology.

  18. ELECTROCHEMICAL REMEDIATION TECHNOLOGIES (ECRTS) - IN SITU REMEDIATION OF CONTAMINATED MARINE SEDIMENTS

    EPA Science Inventory

    This Innovative Technology Evaulation Report summarizes the results of the evaluation of the Electrochemical Remediation Technologies (ECRTs) process, developed by P2-Soil Remediation, Inc. (in partnership with Weiss Associates and Electro-Petroleum, Inc.). This evaluation was co...

  19. ELECTROCHEMICAL REMEDIATION TECHNOLOGIES (ECRTS) - IN SITU REMEDIATION OF CONTAMINATED MARINE SEDIMENTS

    EPA Science Inventory

    This Innovative Technology Evaulation Report summarizes the results of the evaluation of the Electrochemical Remediation Technologies (ECRTs) process, developed by P2-Soil Remediation, Inc. (in partnership with Weiss Associates and Electro-Petroleum, Inc.). This evaluation was co...

  20. Remediation on off-gas system deposits in a radioactive waste glass melter

    SciTech Connect

    Jantzen, C.M.; Choi, A.S.; Randall, C.T.

    1991-01-01

    Since the early 1980's, research glass melters have been used at the Savannah River Laboratory (SRL) to develop the reference vitrification process for immobilization of high level radioactive waste. One of the operating concerns for these melters has been the pluggage of the off-gas system with solid deposits. Samples of these deposits were analyzed to be mixture of alkali-rich chlorides, sulfates, borates, and fluorides with entrained Fe{sub 2}O{sub 3} spinel, and frit particles. The spatial distribution of these deposits throughout the off-gas system indicates that they form by vapor-phase transport and subsequently condensation. Condensation of the alkali-rich phases cements entrained particulates causing the off-gas line to plug. It is concluded that off-gas system pluggage can be effectively controlled by maintaining the off-gas velocity above 16 m/s, while maintaining the off-gas temperature as high as practical below the glass softening point. This paper summarizes the results of chemical and physical analyses of off-gas deposit samples from various melters at SRL. Recent design changes made to the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) to alleviate the pluggage problem are also discussed.

  1. Remediation on off-gas system deposits in a radioactive waste glass melter

    SciTech Connect

    Jantzen, C.M.; Choi, A.S.; Randall, C.T.

    1991-12-31

    Since the early 1980`s, research glass melters have been used at the Savannah River Laboratory (SRL) to develop the reference vitrification process for immobilization of high level radioactive waste. One of the operating concerns for these melters has been the pluggage of the off-gas system with solid deposits. Samples of these deposits were analyzed to be mixture of alkali-rich chlorides, sulfates, borates, and fluorides with entrained Fe{sub 2}O{sub 3} spinel, and frit particles. The spatial distribution of these deposits throughout the off-gas system indicates that they form by vapor-phase transport and subsequently condensation. Condensation of the alkali-rich phases cements entrained particulates causing the off-gas line to plug. It is concluded that off-gas system pluggage can be effectively controlled by maintaining the off-gas velocity above 16 m/s, while maintaining the off-gas temperature as high as practical below the glass softening point. This paper summarizes the results of chemical and physical analyses of off-gas deposit samples from various melters at SRL. Recent design changes made to the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) to alleviate the pluggage problem are also discussed.

  2. In-situ remediation system for volatile organic compounds with deep recharge mechanism

    DOEpatents

    Jackson, Jr., Dennis G.; Looney, Brian B.; Nichols, Ralph L.; Phifer, Mark A.

    2001-01-01

    A method and apparatus for the treatment and remediation of a contaminated aquifer in the presence of an uncontaminated aquifer at a different hydraulic potential. The apparatus consists of a wellbore inserted through a first aquifer and into a second aquifer, an inner cylinder within the wellbore is supported and sealed to the wellbore to prevent communication between the two aquifers. Air injection is used to sparge the liquid having the higher static water level and, to airlift it to a height whereby it spills into the inner cylinder. The second treatment area provides treatment in the form of aeration or treatment with a material. Vapor stripped in sparging is vented to the atmosphere. Treated water is returned to the aquifer having the lower hydraulic potential.

  3. Funnel-and-gate remediation systems augmented with passive filter wells.

    PubMed

    Hudak, Paul F

    2010-09-01

    The objective of this study was to evaluate the ability of funnel-and-gate structures augmented with passive wells containing filter cartridges to capture contaminated groundwater in hypothetical, homogeneous and heterogeneous, unconfined aquifers. Perpendicular to groundwater flow, linear structures were 15 m wide, 1 m thick, and keyed into the base of the aquifer. Gates occupied 4 m of the total width of each simulated structure; one gate was 5 m from a contaminant plume's leading tip, while others occupied cross-gradient margins of the plume. Results suggest a modest reduction in remediation timeframes, up to 425 d per well added in these simulations; however, incremental benefits are highly variable and case specific.

  4. A demonstration of the applicability of implementing the enhanced Remedial Action Priority System (RAPS) for environmental releases

    SciTech Connect

    Whelan, G.; Droppo, J.G. Jr.; Strenge, D.L.; Walter, M.B.; Buck, J.W.

    1989-12-01

    The Remedial Action Priority System (RAPS) and the Multimedia Environmental Pollutant Assessment System (MEPAS) were developed to prioritize problems associated with potential releases of hazardous chemical and radioactive materials in a scientific and objective manner based on limited site information. This report documents the model testing efforts of the RAPS/MEPAS methodology for the atmospheric, surface water, groundwater, and exposure components. Comparisons are given of model outputs with measured data at three sites: the US Department of Energy's Mound facility in Ohio and Hanford facility in Washington, and a chromium-cadmium plating site in New York. The results show that the simulated magnitudes, spacial and temporal trends, and distributions of contaminants corresponded well with the measured data. 25 refs., 86 figs., 26 tabs.

  5. Radiological surveillance of Remedial Action activities at the processing site, Ambrosia Lake, New Mexico, April 12--16, 1993. Final report

    SciTech Connect

    1993-04-01

    The Uranium Mill Tailings Remedial Action (UMTRA) Project`s Technical Assistance Contractor (TAC) performed a radiological surveillance of the Remedial Action Contractor (RAC), MK-Ferguson and CWM Federal Environmental Services, Inc., at the processing site in Ambrosia Lake, New Mexico. The requirements and attributes examined during the audit were developed from reviewing working-level procedures developed by the RAC. Objective evidence, comments, and observations were verified based on investigating procedures, documentation, records located at the site, personal interviews, and tours of the site. No findings were identified during this audit. Ten site-specific observations, three good practice observations, and five programmatic observations are presented in this report. The overall conclusion from the surveillance is that the radiological aspects of the Ambrosia Lake, New Mexico, remedial action program are performed adequately. The results of the good practice observations indicate that the site health physics (HP) staff is taking the initiative to address and resolve potential issues, and implement suggestions useful to the UMTRA Project. However, potential exists for improving designated storage areas for general items, and the RAC Project Office should consider resolving site-specific and procedural inconsistencies.

  6. Courseware for Remedial Mathematics: A Case Study in the Benefits and Costs of the Mediated Learning System in the California State University.

    ERIC Educational Resources Information Center

    Jewett, Frank

    This report is one of a series from a project entitled Case Studies in Evaluating the Benefits and Costs of Mediated Instruction and Distributed Learning. This project examines the benefits and costs of the mediated learning system (MLS) courseware for remedial mathematics developed by Academic Systems Corporation. Comparisons were made at two…

  7. Effective use of risk assessments and the public comment process to achieve acceptable remediation goals for mercury-contaminated sites

    SciTech Connect

    Miller, J.Q.; Barnett, M.

    1996-04-01

    As a result of recalculating risk levels using new information, the remediation goals and cleanup strategy for the Lower East Fork Poplar Creek floodplains have been significantly changed to reflect an important reduction in cleanup costs while ensuring protectionof human health and the environment. This project and its stakeholders have made the risk assessment more effective by better defining the contaminant and adjusting assessment parameters. As a result, the remediation goal initially set at 50 ppM Hg has been changed to 400 ppM, resulting in significant reductions in both the destruction of the floodplain landscape and project costs. Volume of soils to be excavated has been decreased from 1 million cubic yards to 25,000 cubic yards, and the cost has been reduced from about $1 billion to less than $20 million. The Record of Decision for Lower East Fork Poplar Creek was approved in August 1995.

  8. Characterization and optimization of long-term controlled release system for groundwater remediation: a generalized modeling approach.

    PubMed

    Lee, Eung Seok; Schwartz, Franklin W

    2007-09-01

    A well-based reactive barrier system using controlled-release KMnO4 has been recently developed as a long-term in situ treatment option for plumes of dense and non-aqueous phase liquids in groundwater. In order to take advantage of the merits of controlled release systems (CRS) in environmental remediation, the release behavior needs to be optimized for the hydrologic and environmental conditions of target treatment zone. Where release systems are expected to be operated over long times, like for the reactive barriers, it may only be practical to describe the long-term behavior numerically. We developed a numerical model capable of describing release characteristics associated with variable forms and structures of long-term CRS. Sensitivity analyses and illustrative simulations showed that the release kinetics and durations would be constrained by changes in agent solubility, bulk diffusion coefficients, or structures of the release devices. The generality of the numerical model was demonstrated through simulations for CRS with monolithic and double-layered matrices. The generalized model was then used for actual design and analyses of an encapsulated-matrix CRS, which can yield constant release kinetics for several years. A well-based reactive barrier system (4.05 x 10(3)m3) using the encapsulated-matrix CRS can release approximately 1.65 kg of active agent (here MnO4(-)) daily over the next 6.6 yr, creating prolonged reaction zone in the subsurface. The generalized model-based, target-specific approach using the long-term CRS could provide practical tool for improving the efficacy of advanced in situ remediation schemes such as in situ chemical oxidation, bioremediation, or in situ redox manipulation. Development of techniques for adjusting the bulk diffusion coefficients of the release matrices and facilitating the lateral spreading of the released agent is warranted.

  9. Advanced System for Process Engineering

    SciTech Connect

    Williams, K. E.; Saus, L. S.; Regenhardt, P. A.

    1992-02-01

    ASPEN (Advanced System for Process Engineering) is a state of the art process simulator and economic evaluation package which was designed for use in engineering fossil energy conversion processes. ASPEN can represent multiphase streams including solids, and handle complex substances such as coal. The system can perform steady state material and energy balances, determine equipment size and cost, and carry out preliminary economic evaluations. It is supported by a comprehensive physical property system for computation of major properties such as enthalpy, entropy, free energy, molar volume, equilibrium ratio, fugacity coefficient, viscosity, thermal conductivity, and diffusion coefficient for specified phase conditions; vapor, liquid, or solid. The properties may be computed for pure components, mixtures, or components in a mixture, as appropriate. The ASPEN Input Language is oriented towards process engineers.

  10. Glass melter off-gas system pluggages: Cause, significance, and remediation

    SciTech Connect

    Jantzen, C.M.

    1991-03-01

    Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. The glass will be produced in the Defense Waste Processing Facility (DWPF) where the glass will be poured into stainless steel canisters for eventual disposal in a geologic repository. Experimental glass melters used to develop the vitrification process for immobilization of the waste have experienced problems with pluggage of the off-gas line with solid deposits. Off-gas deposits from the DWPF 1/2 Scale Glass Melter (SGM) and the 1/10th scale Integrated DWPF Melter System (IDMS) were determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides with entrained Fe{sub 2}O{sub 3}, spinel, and frit particles. The distribution and location of the alkali deposits throughout the off-gas system indicate that the deposits form by vapor-phase transport and condensation. Condensation of the alkali-rich phases cement the entrained particulates causing off-gas system pluggages. The identification of vapor phase transport as the operational mechanism causing off-gas system pluggage indicates that deposition can be effectively eliminated by increasing the off-gas velocity. Scale glass melter operating experience indicates that a velocity of >50 fps is necessary in order to transport the volatile species to the quencher to prevent having condensation occur in the off-gas line. Hotter off-gas line temperatures would retain the alkali compounds as vapors so that they would remain volatile until they reach the quencher. However, hotter off-gas temperatures can only be achieved by using less air/steam flow at the off-gas entrance, e.g. at the off-gas film cooler (OGFC). This would result in lower off-gas velocities. Maintaining a high velocity is, therefore, considered to be a more important criterion for controlling off-gas pluggage than temperature control. 40 refs., 16 figs., 5 tabs.

  11. Exploring the biochemical properties and remediation applications of the unusual explosive-degrading P450 system XplA/B

    PubMed Central

    Jackson, Rosamond G.; Rylott, Elizabeth L.; Fournier, Diane; Hawari, Jalal; Bruce, Neil C.

    2007-01-01

    Widespread contamination of land and groundwater has resulted from the use, manufacture, and storage of the military explosive hexa-hydro-1,3,5-trinitro-1,3,5-triazine (RDX). This contamination has led to a requirement for a sustainable, low-cost method to remediate this problem. Here, we present the characterization of an unusual microbial P450 system able to degrade RDX, consisting of flavodoxin reductase XplB and fused flavodoxin-cytochrome P450 XplA. The affinity of XplA for the xenobiotic compound RDX is high (Kd = 58 μM) and comparable with the Km of other P450s toward their natural substrates (ranging from 1 to 500 μM). The maximum turnover (kcat) is 4.44 per s, only 10-fold less than the fastest self-sufficient P450 reported, BM3. Interestingly, the presence of oxygen determines the final products of RDX degradation, demonstrating that the degradation chemistry is flexible, but both pathways result in ring cleavage and release of nitrite. Carbon monoxide inhibition is weak and yet the nitroaromatic explosive 2,4,6-trinitrotoluene (TNT) is a potent inhibitor. To test the efficacy of this system for the remediation of groundwater, transgenic Arabidopsis plants expressing both xplA and xplB were generated. They are able to remove saturating levels of RDX from liquid culture and soil leachate at rates significantly faster than those of untransformed plants and xplA-only transgenic lines, demonstrating the applicability of this system for the phytoremediation of RDX-contaminated sites. PMID:17940033

  12. Parallel processing spacecraft communication system

    NASA Technical Reports Server (NTRS)

    Bolotin, Gary S. (Inventor); Donaldson, James A. (Inventor); Luong, Huy H. (Inventor); Wood, Steven H. (Inventor)

    1998-01-01

    An uplink controlling assembly speeds data processing using a special parallel codeblock technique. A correct start sequence initiates processing of a frame. Two possible start sequences can be used; and the one which is used determines whether data polarity is inverted or non-inverted. Processing continues until uncorrectable errors are found. The frame ends by intentionally sending a block with an uncorrectable error. Each of the codeblocks in the frame has a channel ID. Each channel ID can be separately processed in parallel. This obviates the problem of waiting for error correction processing. If that channel number is zero, however, it indicates that the frame of data represents a critical command only. That data is handled in a special way, independent of the software. Otherwise, the processed data further handled using special double buffering techniques to avoid problems from overrun. When overrun does occur, the system takes action to lose only the oldest data.

  13. Remediation of transuranic-contaminated coral soil at Johnston Atoll using the segmented gate system

    SciTech Connect

    Bramlitt, E.; Johnson, N.

    1994-12-31

    Thermo Analytical, Inc. (TMA) has developed a system to remove clean soil from contaminated soil. The system consists of a soil conveyor, an array of radiation detectors toward the conveyor feed end, a gate assembly at the conveyor discharge end, and two additional conveyors which move discharged soil to one or another paths. The gate assembly is as wide as the ``sorter conveyor,`` and it has eight individual gates or segments. The segments automatically open or close depending on the amount of radioactivity present. In one position they pass soil to a clean soil conveyor, and in the other position they let soil fall to a hot soil conveyor. The soil sorting process recovers clean soil for beneficial use and it substantially reduces the quantity of soil which must be decontaminated or prepared for waste disposal. The Segmented Gate System (SGS) was developed for the cleanup of soil contaminated with some transuranium elements at Johnston Atoll. It has proven to be an effective means for recovering clean soil and verifying that soil is clean, minimizing the quantity of truly contaminated soil, and providing measures of contamination for waste transport and disposal. TMA is constructing a small, transportable soil cleanup as it is confident the SGS technology can be adapted to soils and contaminants other than those at Johnston Atoll. It will use this transportable plant to demonstrate the technology and to develop site specific parameters for use in designing plants to meet cleanup needs.

  14. Glass melter off-gas system pluggages: Cause, significance, and remediation

    SciTech Connect

    Jantzen, C.M.

    1991-12-31

    Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. Experimental glass melters, used to develop the vitrification process, have occasionally experienced problems with pluggage of the off-gas line with solid deposits. The deposits were determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides with entrained insoluble particles of Fe{sub 2}O{sub 3} spinel, and frit. The distribution and location of the alkali deposits throughout the off-gas system indicate that the deposits form by vapor-phase transport and condensation. Condensation of the alkali-rich phases cements the entrained particulates causing the off-gas system pluggages. The identification of vapor phase transport as the operational mechanism causing off-gas system pluggages indicates that deposition can be effectively eliminated by increasing the off-gas velocity. The cementitious alkali borates, halides, and sulfates comprising the off-gas line deposits were determined to be water soluble. Thus pluggage can be effectively removed with water and/or steam.

  15. Glass melter off-gas system pluggages: Cause, significance, and remediation

    SciTech Connect

    Jantzen, C.M.

    1991-01-01

    Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. Experimental glass melters, used to develop the vitrification process, have occasionally experienced problems with pluggage of the off-gas line with solid deposits. The deposits were determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides with entrained insoluble particles of Fe{sub 2}O{sub 3} spinel, and frit. The distribution and location of the alkali deposits throughout the off-gas system indicate that the deposits form by vapor-phase transport and condensation. Condensation of the alkali-rich phases cements the entrained particulates causing the off-gas system pluggages. The identification of vapor phase transport as the operational mechanism causing off-gas system pluggages indicates that deposition can be effectively eliminated by increasing the off-gas velocity. The cementitious alkali borates, halides, and sulfates comprising the off-gas line deposits were determined to be water soluble. Thus pluggage can be effectively removed with water and/or steam.

  16. Advanced Information Processing System (AIPS)

    NASA Technical Reports Server (NTRS)

    Pitts, Felix L.

    1993-01-01

    Advanced Information Processing System (AIPS) is a computer systems philosophy, a set of validated hardware building blocks, and a set of validated services as embodied in system software. The goal of AIPS is to provide the knowledgebase which will allow achievement of validated fault-tolerant distributed computer system architectures, suitable for a broad range of applications, having failure probability requirements of 10E-9 at 10 hours. A background and description is given followed by program accomplishments, the current focus, applications, technology transfer, FY92 accomplishments, and funding.

  17. Methodology to remediate a mixed waste site

    SciTech Connect

    Berry, J.B.

    1994-08-01

    In response to the need for a comprehensive and consistent approach to the complex issue of mixed waste management, a generalized methodology for remediation of a mixed waste site has been developed. The methodology is based on requirements set forth in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the Resource Conservation and Recovery Act (RCRA) and incorporates ``lessons learned`` from process design, remediation methodologies, and remediation projects. The methodology is applied to the treatment of 32,000 drums of mixed waste sludge at the Oak Ridge K-25 Site. Process technology options are developed and evaluated, first with regard to meeting system requirements and then with regard to CERCLA performance criteria. The following process technology options are investigated: (1) no action, (2) separation of hazardous and radioactive species, (3) dewatering, (4) drying, and (5) solidification/stabilization. The first two options were eliminated from detailed consideration because they did not meet the system requirements. A quantitative evaluation clearly showed that, based on system constraints and project objectives, either dewatering or drying the mixed waste sludge was superior to the solidification/stabilization process option. The ultimate choice between the drying and the dewatering options will be made on the basis of a technical evaluation of the relative merits of proposals submitted by potential subcontractors.

  18. DEMONSTRATION OF PILOT-SCALE PREVAPORATION SYSTEMS FOR VOLATILE ORGANIC COMPOUND REMOVAL FROM A SURFACTANT ENHANCED AQUIFER REMEDIATION FLUID. I. SPIRAL WOUND MEMBRANE MODULES

    EPA Science Inventory

    During the summer of 1996, a pilot-scale demonstration of a surfactant enhanced aquifer remediation (SEAR) process for removal of dense non-aqueous phase liquids (DNAPLs) from soils was conducted at Hill Air Force Base in Layton, Utah. Five thousand gallons of the extracted DNAP...

  19. DEMONSTRATION OF PILOT-SCALE PREVAPORATION SYSTEMS FOR VOLATILE ORGANIC COMPOUND REMOVAL FROM A SURFACTANT ENHANCED AQUIFER REMEDIATION FLUID. I. SPIRAL WOUND MEMBRANE MODULES

    EPA Science Inventory

    During the summer of 1996, a pilot-scale demonstration of a surfactant enhanced aquifer remediation (SEAR) process for removal of dense non-aqueous phase liquids (DNAPLs) from soils was conducted at Hill Air Force Base in Layton, Utah. Five thousand gallons of the extracted DNAP...

  20. Data Management Plan and Functional System Design for the Information Management System of the Clinch River Remedial Investigation and Waste Area Grouping 6

    SciTech Connect

    Ball, T.; Brandt, C.; Calfee, J.; Garland, M.; Holladay, S.; Nickle, B.; Schmoyer, D.; Serbin, C.; Ward, M.

    1994-03-01

    The Data Management Plan and Functional System Design supports the Clinch River Remedial Investigation (CRRI) and Waste Area Grouping (WAG) 6 Environmental Monitoring Program. The objective of the Data Management Plan and Functional System Design is to provide organization, integrity, security, traceability, and consistency of the data generated during the CRRI and WAG 6 projects. Proper organization will ensure that the data are consistent with the procedures and requirements of the projects. The Information Management Groups (IMGs) for these two programs face similar challenges and share many common objectives. By teaming together, the IMGs have expedited the development and implementation of a common information management strategy that benefits each program.

  1. XCPU2 process management system

    SciTech Connect

    Ionkov, Latchesar; Van Hensbergen, Eric

    2009-01-01

    Xcpu2 is a new process management system that allows the users to specify custom file system for a running job. Most cluster management systems enforce single software distribution running on all nodes. Xcpu2 allows programs running on the cluster to work in environment identical to the user's desktop, using the same versions of the libraries and tools the user installed locally, and accessing the configuration file in the same places they are located on the desktop. Xcpu2 builds on our earlier work with the Xcpu system. Like Xcpu, Xcpu2's process management interface is represented as a set of files exported by a 9P file server. It supports heterogeneous clusters and multiple head nodes. Unlike Xcpu, it uses pull instead of push model. In this paper we describe the Xcpu2 clustering model, its operation and how the per-job filesystem configuration can be used to solve some of the common problems when running a cluster.

  2. Network command processing system overview

    NASA Technical Reports Server (NTRS)

    Nam, Yon-Woo; Murphy, Lisa D.

    1993-01-01

    The Network Command Processing System (NCPS) developed for the National Aeronautics and Space Administration (NASA) Ground Network (GN) stations is a spacecraft command system utilizing a MULTIBUS I/68030 microprocessor. This system was developed and implemented at ground stations worldwide to provide a Project Operations Control Center (POCC) with command capability for support of spacecraft operations such as the LANDSAT, Shuttle, Tracking and Data Relay Satellite, and Nimbus-7. The NCPS consolidates multiple modulation schemes for supporting various manned/unmanned orbital platforms. The NCPS interacts with the POCC and a local operator to process configuration requests, generate modulated uplink sequences, and inform users of the ground command link status. This paper presents the system functional description, hardware description, and the software design.

  3. Turbine Blade Image Processing System

    NASA Astrophysics Data System (ADS)

    Page, Neal S.; Snyder, Wesley E.; Rajala, Sarah A.

    1983-10-01

    A vision system has been developed at North Carolina State University to identify the orientation and three dimensional location of steam turbine blades that are stacked in an industrial A-frame cart. The system uses a controlled light source for structured illumination and a single camera to extract the information required by the image processing software to calculate the position and orientation of a turbine blade in real time.

  4. Parallel processing and expert systems

    NASA Technical Reports Server (NTRS)

    Lau, Sonie; Yan, Jerry C.

    1991-01-01

    Whether it be monitoring the thermal subsystem of Space Station Freedom, or controlling the navigation of the autonomous rover on Mars, NASA missions in the 1990s cannot enjoy an increased level of autonomy without the efficient implementation of expert systems. Merely increasing the computational speed of uniprocessors may not be able to guarantee that real-time demands are met for larger systems. Speedup via parallel processing must be pursued alongside the optimization of sequential implementations. Prototypes of parallel expert systems have been built at universities and industrial laboratories in the U.S. and Japan. The state-of-the-art research in progress related to parallel execution of expert systems is surveyed. The survey discusses multiprocessors for expert systems, parallel languages for symbolic computations, and mapping expert systems to multiprocessors. Results to date indicate that the parallelism achieved for these systems is small. The main reasons are (1) the body of knowledge applicable in any given situation and the amount of computation executed by each rule firing are small, (2) dividing the problem solving process into relatively independent partitions is difficult, and (3) implementation decisions that enable expert systems to be incrementally refined hamper compile-time optimization. In order to obtain greater speedups, data parallelism and application parallelism must be exploited.

  5. The norms, rules and motivational values driving sustainable remediation of contaminated environments: A study of implementation.

    PubMed

    Prior, Jason

    2016-02-15

    Efforts to achieve sustainability are transforming the norms, rules and values that affect the remediation of contaminated environments. This is altering the ways in which remediation impacts on the total environment. Despite this transformation, few studies have provided systematic insights into the diverse norms and rules that drive the implementation of sustainable remediation at contaminated sites, and no studies have investigated how values motivate compliance with these norms and rules. This study is a systematic analysis of the rules, norms and motivational values embedded in sustainable remediation processes at three sites across Australia, using in-depth interviews conducted with 18 participants between 2011 and 2014, through the application of Crawford and Ostrom's Institutional Grammar and Schwartz's value framework. These approaches offered methods for identifying the rules, norms, and motivational values that guided participants' actions within remediation processes at these sites. The findings identify a core set of 16 norms and 18 rules (sanctions) used by participants to implement sustainable remediation at the sites. These norms and rules: define the position of participants within the process, provide means for incorporating sustainability into established remediation practices, and define the scope of outcomes that constitute sustainable remediation. The findings revealed that motivational values focused on public interest and self-interest influenced participants' compliance with norms and rules. The findings also found strong interdependence between the norms and rules (sanctions) within the remediation processes and the normative principles operating within the broader domain of environmental management and planning. The paper concludes with a discussion of: the system of norms operating within sustainable remediation (which far exceed those associated with ESD); their link, through rules (sanctions) to contemporary styles of regulatory

  6. Development of an Automated Remedy Performance Evaluation Program - 13622

    SciTech Connect

    Tonkin, Matthew J.; Kennel, Jonathan; Biebesheimer, Frederick; Dooley, David

    2013-07-01

    Performance monitoring is a vital element of groundwater remediation. Unfortunately, the enormous efforts and costs that are expended procuring, managing, processing and storing monitoring data are often not subject to correspondingly rigorous evaluation. This is despite the fact that many steps in the process are predictable and are repeated many times over the remedy life cycle. At the Department of Energy (DOE) Hanford Site, a program is underway to automate many of these steps - processing, formatting any analyzing large volumes of heterogeneous data associated with the operation of several groundwater pump-and-treat (P and T) and in-situ remedies. The Automated Remedy Performance Evaluation Program (ARPEP) was developed from a work-flow process designed to deliver (a) monthly data summaries and preliminary analysis, (b) quarterly performance assessments, and (c) annual roll-up analyses that detect changes in long-term monitoring datasets and support remedy optimization. The intent of the ARPEP is to provide detailed, systematic and traceable data summaries, depictions and analyses that can be used by project scientists to complete their evaluation of remedy performance. The ARPEP work-flow was formalized following extensive review of applicable guidance, regulation and industry standards. The ARPEP incorporates disparate data types collected over different frequencies, such as water levels and pumping rates recorded every minute, and groundwater sample results obtained on quarterly, annual or irregular intervals. The data are processed, reduced to frequencies suitable for assessment, and combined in various ways leading to performance indicators such as (a) pumped well capacities and system downtime that reflect operational performance; (b) hydraulic gradients and areas of hydraulic containment that reflect hydraulic performance; and (c) time-series (longitudinal) and geo-statistical (spatial) trend analyses that reflect progress toward attainment of Remedial

  7. A multi-process phytoremediation system for removal of polycyclic aromatic hydrocarbons from contaminated soils.

    PubMed

    Huang, Xiao-Dong; El-Alawi, Yousef; Penrose, Donna M; Glick, Bernard R; Greenberg, Bruce M

    2004-08-01

    To improve phytoremediation processes, multiple techniques that comprise different aspects of contaminant removal from soils have been combined. Using creosote as a test contaminant, a multi-process phytoremediation system composed of physical (volatilization), photochemical (photooxidation) and microbial remediation, and phytoremediation (plant-assisted remediation) processes was developed. The techniques applied to realize these processes were land-farming (aeration and light exposure), introduction of contaminant degrading bacteria, plant growth promoting rhizobacteria (PGPR), and plant growth of contaminant-tolerant tall fescue (Festuca arundinacea). Over a 4-month period, the average efficiency of removal of 16 priority PAHs by the multi-process remediation system was twice that of land-farming, 50% more than bioremediation alone, and 45% more than phytoremediation by itself. Importantly, the multi-process system was capable of removing most of the highly hydrophobic, soil-bound PAHs from soil. The key elements for successful phytoremediation were the use of plant species that have the ability to proliferate in the presence of high levels of contaminants and strains of PGPR that increase plant tolerance to contaminants and accelerate plant growth in heavily contaminated soils. The synergistic use of these approaches resulted in rapid and massive biomass accumulation of plant tissue in contaminated soil, putatively providing more active metabolic processes, leading to more rapid and more complete removal of PAHs.

  8. DESIGN OF AQUIFER REMEDIATION SYSTEMS: (2) Estimating site-specific performance and benefits of partial source removal

    EPA Science Inventory

    A Lagrangian stochastic model is proposed as a tool that can be utilized in forecasting remedial performance and estimating the benefits (in terms of flux and mass reduction) derived from a source zone remedial effort. The stochastic functional relationships that describe the hyd...

  9. DESIGN OF AQUIFER REMEDIATION SYSTEMS: (2) Estimating site-specific performance and benefits of partial source removal

    EPA Science Inventory

    A Lagrangian stochastic model is proposed as a tool that can be utilized in forecasting remedial performance and estimating the benefits (in terms of flux and mass reduction) derived from a source zone remedial effort. The stochastic functional relationships that describe the hyd...

  10. Chromium remediation or release? Effect of iron(II) sulfate addition on chromium(VI) leaching from columns of chromite ore processing residue.

    PubMed

    Geelhoed, Jeanine S; Meeussen, Johannes C L; Roe, Martin J; Hillier, Stephen; Thomas, Rhodri P; Farmer, John G; Paterson, Edward

    2003-07-15

    Chromite ore processing residue (COPR), derived from the so-called high lime processing of chromite ore, contains high levels of Cr(III) and Cr(VI) and has a pH between 11 and 12. Ferrous sulfate, which is used for remediation of Cr(VI) contamination in wastewater and soils via reduction to Cr(III) and subsequent precipitation of iron(III)/chromium(III) hydroxide, has also been proposed for remediation of Cr(VI) in COPR. Instead, however, addition of FeSO4 to the infiltrating solution in column experiments with COPR greatly increased leaching of Cr(VI). Leached Cr(VI) increased from 3.8 to 12.3 mmol kg(-1) COPR in 25 pore volumes with 20 mM FeSO4, reaching solution concentrations as high as 1.6 mM. Fe(II) was ineffective in reducing Cr(VI) to Cr(III) because it precipitated when it entered the column due to the high pH of COPR, while Cr(VI) in solution was transported away with the infiltrating solution. The large increase in leaching of Cr(VI) upon infiltration of sulfate, either as FeSO4 or Na2SO4, was caused by anion exchange of sulfate for chromate in the layered double hydroxide mineral hydrocalumite, a process for which scanning electron microscopy with energy-dispersive X-ray microanalysis provided direct evidence.

  11. Monitoring and remediating groundwater

    SciTech Connect

    Vedder, M.

    1995-03-01

    Choosing the optimum groundwater remediation process is a site-specific task. A variety of factors--including soil type, water type, water flow, water table levels and contaminant type--influence sampling and treatment techniques. Because underground contaminant plumes must first be characterized and mapped, initial sampling often is a hit or miss proposition. Historical geophysical data can be obtained from many local water boards to supplement the process. Equipment used in sampling includes drilling rigs, depth probes, bailers, sample tubing and well pumps. Once samples are collected, they are preserved with ice and transported to an environmental laboratory for analysis. Common groundwater contaminants include hydrocarbons, solvents, metals and volatile organic compounds. Typical lab analysis methods include gas chromatography and spectrometry. Remediation options include air stripping, carbon adsorption, the use of bacterial cultures, chemical precipitation, ion exchange, reverse osmosis and ultrafiltration.

  12. Sales of over-the-counter remedies as an early warning system for winter bed crises.

    PubMed

    Davies, G R; Finch, R G

    2003-08-01

    To evaluate the pattern of emergency adult medical admissions during the winter period and the usefulness of sales of over-the-counter cough/cold remedies as a predictor of these. The databases of a single NHS trust acute unit and pharmacy outlets in its catchment area were analyzed retrospectively, comparing numbers of emergency admissions, ICD-10 discharge codes, local electronic point-of-sale (EPOS) and national sales data. Over nine consecutive winter periods from 1992/3, peak admissions always occurred within a defined ten-day period from 29th December to 9th January. Emergency admissions increased significantly during this period (P = 0.0002). Pharmaceutical/retail data were available for three consecutive winters 1998/99, 1999/2000 and 2000/2001, none of which coincided with increased influenza activity nationally. Acute respiratory illness as defined by International Classification of Diseases, 10th edition (ICD-10) discharge coding did not appear to contribute to the increase in admissions at the peak. However, National and Local EPOS sales were positively correlated with admissions and the rate of EPOS sales exceeded an empiric threshold of 1000 units per week two weeks prior to the admissions peak in each year. Emergency admissions over the winter period are increasing and can be expected within a period of only ten days each year. No firm relationship between acute respiratory illness and admissions could be defined but local EPOS data may give up to two weeks warning of the peak in admissions and merits further prospective evaluation.

  13. Remediation of Uranium Impacted Sediments in a Watercourse - 12486

    SciTech Connect

    Shephard, E.; Walter, N.; Downey, H.; Collopy, P.; Conant, J.

    2012-07-01

    In 2009, remediation was initiated for a non-operational fuel cycle facility previously used for government contract work. Between 2009 and the spring of 2011, remediation efforts were focused on demolition of contaminated buildings and removal of contaminated soil. In the late spring of 2011, the last phase of remediation commenced involving the removal of contaminated sediments from portions of a 1,200 meter long gaining stream. Planning and preparation for remediation of the stream began in 2009 with submittal of permit applications to undertake construction activities in a wetland area. The permitting process was lengthy and involved securing permits from multiple agencies. However, early and frequent communication with stakeholders played an integral role in efficiently obtaining the permit approvals. Frequent communication with stakeholders throughout the planning and remediation process also proved to be a key factor in timely completion of the project. The remediation of the stream involved the use of temporary bladder berms to divert surface water flow, water diversion piping, a sediment vacuum removal system, excavation of sediments using small front-end loaders, sediment dewatering, and waste packaging, transportation and disposal. Many safeguards were employed to protect several species of concern in the work area, water management during project activities, challenges encountered during the project, methods of Final Status Survey, and stream restoration. The planning and permitting effort for the Site Brook remediation began in May 2009 and permits were approved and in place by February 2011. The remediation and restoration of the Site Brook began in April 2011 and was completed in November 2011. The remediation of the Site Brook involved the use of temporary bladder berms to divert surface water flow, water diversion piping, a sediment vacuum removal system, excavation of sediments using small front-end loaders, sediment dewatering, and waste

  14. [Effect of different soil types on the remediation of copper-pyrene compound contaminated soils by EK-oxidation process].

    PubMed

    Fan, Guang-Ping; Cang, Long; Zhou, Dong-Mei; Zhou, Li-Xiang

    2011-11-01

    The effect of different soil types (red soil,yellow-brown soil and black soil) on the electrokinetic (EK)-oxidation remediation of heavy metals-organic pollutant contaminated soil was studied in laboratory-scale experiments. Copper and pyrene were chosen as model pollutant, and 12% H2O2, 10% hydroxypropyl-beta-cyclodextrin and 0.01 mol x L(-1) NaNO3 solution were added into the anode and cathode cell. The applied voltage was 1 V x cm(-1). After 15 days of EK remediation, the removal rate of pyrene and copper in red soil, yellow-brown soil and black soil were 38.5%, 46.8%, 51.3% for pyrene and 85.0%, 22.6%, 24.1% for Cu, respectively. The high pH of black soil produced high electroosmotic flow and increased the exposure of oxidants and pollutants, meanwhile the low clay content was also conducive to the desorption of pyrene. The low pH and organic matter of red soil affected the chemical species distribution of Cu and increased its removal rate. It is concluded that soil pH, clay content and heavy metal speciation in soil are the dominant factors affecting the migration and removal efficiency of pollutants.

  15. GUIDE FOR CONDUCTING TREATABILITY STUDIES UNDER CERCLA: AEROBIC BIODEGRADATION REMEDY SCREENING

    EPA Science Inventory

    Systematically conducted, well-documented treatability studies are an important component of the remedial investigation/feasibility study (KU FS) process and the remedial design/remedial action (RD/RA) process under the Comprehensive Environmental Response, Compensation, and L...

  16. GUIDE FOR CONDUCTING TREATABILITY STUDIES UNDER CERCLA: AEROBIC BIODEGRADATION REMEDY SCREENING

    EPA Science Inventory

    Systematically conducted, well-documented treatability studies are an important component of the remedial investigation/feasibility study (KU FS) process and the remedial design/remedial action (RD/RA) process under the Comprehensive Environmental Response, Compensation, and L...

  17. Source control strategy accelerates remediation

    SciTech Connect

    Garland, S.B. II; Hammond, R.

    1993-06-01

    Shallow land burial of ion-level radioactive wastes at ORNL has resulted in the release of contaminants into surrounding soil, groundwater, and surface water. Multiple contaminated areas occurring in close proximity make it difficult to relate contaminant releases to a specific site. To address this issue, similar and contiguous contaminated sites within the same drainage area have been combined into Waste Area Groupings. These Waste Area Groupings were prioritized and became the focus of the Comprehensive Environmental Response, Compensation, and Liability Act remediation process. Since the majority of the groupings are in the White Oak Creek drainage basin, the remediation strategy is to control contaminant releases from these source areas first, followed by remediation of White Oak Creek. In planning the remediation program, it became clear that until the issues of ultimate land use and institutional control, waste treatment technologies, and waste disposal facilities are resolved, final remediation objectives cannot be defined and remedial alternatives cannot be evaluated. Consequently, instead of postponing remedial actions until these issues are resolved, a strategy to control the sources of contaminant release with a serie s of interim actions was developed. In the near term, this strategy reduces off-site risk by eliminating contaminant releases and controls on-site risk through institutional control. Source control will allow time to achieve consensus on long-term institutional control and land use issues to develop appropriate treatment technologies, and to construct the necessary disposal facilities without further environmental degradation.

  18. Advanced information processing system: Local system services

    NASA Technical Reports Server (NTRS)

    Burkhardt, Laura; Alger, Linda; Whittredge, Roy; Stasiowski, Peter

    1989-01-01

    The Advanced Information Processing System (AIPS) is a multi-computer architecture composed of hardware and software building blocks that can be configured to meet a broad range of application requirements. The hardware building blocks are fault-tolerant, general-purpose computers, fault-and damage-tolerant networks (both computer and input/output), and interfaces between the networks and the computers. The software building blocks are the major software functions: local system services, input/output, system services, inter-computer system services, and the system manager. The foundation of the local system services is an operating system with the functions required for a traditional real-time multi-tasking computer, such as task scheduling, inter-task communication, memory management, interrupt handling, and time maintenance. Resting on this foundation are the redundancy management functions necessary in a redundant computer and the status reporting functions required for an operator interface. The functional requirements, functional design and detailed specifications for all the local system services are documented.

  19. Optimizing multiphase aquifer remediation using ITOUGH2

    SciTech Connect

    Finsterle, S.; Pruess, K.

    1994-06-01

    The T2VOC computer model for simulating the transport of organic chemical contaminants in non-isothermal multiphase systems has been coupled to the ITOUGH2 code which solves parameter optimization problems. This allows one to use nonlinear programming and simulated annealing techniques to solve groundwater management problems, i.e. the optimization of multiphase aquifer remediation. This report contains three illustrative examples to demonstrate the optimization of remediation operations by means of simulation-minimization techniques. The code iteratively determines an optimal remediation strategy (e.g. pumping schedule) which minimizes, for instance, pumping and energy costs, the time for cleanup, and residual contamination. While minimizing the objective function is straightforward, the relative weighting of different performance measures--e.g. pumping costs versus cleanup time versus residual contaminant content--is subject to a management decision process. The intended audience of this report is someone who is familiar with numerical modeling of multiphase flow of contaminants, and who might actually use T2VOC in conjunction with ITOUGH2 to optimize the design of aquifer remediation operations.

  20. Formation and transport of PCDD/Fs in the packed bed of soil containing organic chloride during a thermal remediation process.

    PubMed

    Harjanto, Sri; Kasai, Eiki; Terui, Toshikatsu; Nakamura, Takashi

    2002-10-01

    The authors previously proposed the concept of a new thermal remediation process for particulate/powder materials contaminated by polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and experimentally verified its validity on the basis of process efficiency. However, contaminees such as soils and fly ashes from waste incinerators often contain a considerable amount of other chlorides, which may act as a main source of chlorine in the formation of PCDD/Fs via thermal processes. The present study aims to examine the formation and transport of PCDD/Fs in the packed bed of soil containing a chloride during the process. Polyvinyl chloride (PVC) polymer was mixed with soil sample as an organic chloride model. A laboratory-scale apparatus was employed as a process simulator. Further, a technique to quench the process was applied to observe the concentration distribution of PCDD/Fs in the solid bed in the vertical direction. The result shows that the PCDFs tend to form dominantly in the high temperature (calcination and/or combustion) zone and are successively trapped in the low temperature (wet) zone. Especially, TeCDF is the most dominant homologue contained in the wet zone and outlet gas. Although PCDD/Fs are once trapped at the wet zone, the concentration of the remediated materials gives fairly low value (1.9 pg/g-dry, 0.04 pg-TEQ/g-dry). It signifies that organic chlorides mingled in the solid contaminee not affect the removal efficiency of PCDD/Fs in the process. Nevertheless, attention should be paid to the potential emission of PCDD/Fs in the outlet gas due to the presence of organic chloride in the soil.

  1. 300-FF-1 remedial design report/remedial action work plan

    SciTech Connect

    Gustafson, F.W.

    1997-02-01

    The 300 Area has been divided into three operable units 300-FF-1, 300-FF-2, and 300-FF-5 all of which are in various stages of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) process. The 300-FF-1 Operable Unit, the subject of this report, includes liquid waste disposal sites, landfills, and a burial ground. This Remedial Design Report/Remedial Action Work Plan (RDR/RAWP) provides a summary description of each waste site included in the 300-FF-1 Operable Unit, the basis for remedial actions to be taken, and the remedial action approach and management process for implementing these actions. The remedial action approach and management sections provide a description of the remedial action process description, the project schedule, the project team, required planning documentation, the remedial action change process, the process for verifying attainment of the remedial action goals, and the required CERCLA and RCRA closeout documentation. Appendix A provides additional details on each waste site. In addition to remediation of the waste sites, waste generated during the remedial investigation/feasibility study portions of the project will also be disposed at the Environmental Restoration Disposal Facility (ERDF). Appendix B provides a summary of the modeling performed in the 300-FF-1 Phase 3 FS and a description of the modeling effort to be used to show attainment of the remedial action goals. Appendix C provides the sampling and analysis plan (SAP) for all sampling and field-screening activities performed during remediation and for verification of attainment with the remedial action goals. Appendix D provides the public involvement plan, prepared to ensure information is provided to the public during remedial design and remedial action processes.

  2. Lunar materials processing system integration

    NASA Technical Reports Server (NTRS)

    Sherwood, Brent

    1992-01-01

    The theme of this paper is that governmental resources will not permit the simultaneous development of all viable lunar materials processing (LMP) candidates. Choices will inevitably be made, based on the results of system integration trade studies comparing candidates to each other for high-leverage applications. It is in the best long-term interest of the LMP community to lead the selection process itself, quickly and practically. The paper is in five parts. The first part explains what systems integration means and why the specialized field of LMP needs this activity now. The second part defines the integration context for LMP -- by outlining potential lunar base functions, their interrelationships and constraints. The third part establishes perspective for prioritizing the development of LMP methods, by estimating realistic scope, scale, and timing of lunar operations. The fourth part describes the use of one type of analytical tool for gaining understanding of system interactions: the input/output model. A simple example solved with linear algebra is used to illustrate. The fifth and closing part identifies specific steps needed to refine the current ability to study lunar base system integration. Research specialists have a crucial role to play now in providing the data upon which this refinement process must be based.

  3. 40 CFR 63.7882 - What site remediation sources at my facility does this subpart affect?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... processes. (2) Remediation material management units. Remediation material management unit means a tank... entire group of remediation material management units used for the site remediations at your site. For... process vent, as defined in § 63.7957, is not a remediation material management unit, but instead this...

  4. Characterization technologies for environmental remediation

    SciTech Connect

    Pruett, J.G.

    1991-01-01

    Improved site characterization technologies are being developed at Martin Marietta Energy Systems for the US Department of Energy (DOE) Office of Technology Development (OTD) in support of environmental restoration activities throughout the DOE complex. Since site characterization is an expensive and time consuming process that must be performed prior to, during, and following remediation efforts, an obvious way to reduce the overall cost of remediation is to develop improved characterization methods. For example, the Derivative Ultraviolet Absorption Spectrometer (DUVAS), which is being field tested as part of the OTD program, is a fiberoptic device for in situ, real time measurement of aromatic organic compounds in groundwater. A transportable, direct sampling Ion Trap Mass Spectrometer (ITMS) is being developed for continuous monitoring of hazardous organic compounds in air. In areas where the environment is hazardous to human health, it is desirous to perform site characterization remotely; if robotics are to be employed, the Ultrasonic Ranging and Data System (USRADS) can be used to provide telemetry information on robot location as well as sensor measurements. Once fully developed, these technologies can be transferred to the private sector. 19 refs., 2 tabs.

  5. Intelligent process development of foam molding for the Thermal Protection System (TPS) of the space shuttle external tank

    NASA Technical Reports Server (NTRS)

    Bharwani, S. S.; Walls, J. T.; Jackson, M. E.

    1987-01-01

    A knowledge based system to assist process engineers in evaluating the processability and moldability of poly-isocyanurate (PIR) formulations for the thermal protection system of the Space Shuttle external tank (ET) is discussed. The Reaction Injection Molding- Process Development Advisor (RIM-PDA) is a coupled system which takes advantage of both symbolic and numeric processing techniques. This system will aid the process engineer in identifying a startup set of mold schedules and in refining the mold schedules to remedy specific process problems diagnosed by the system.

  6. Observational Approach to Chromium Site Remediation - 13266

    SciTech Connect

    Scott Myers, R.

    2013-07-01

    Production reactors at the U.S. Department of Energy's (DOE) Hanford Site in Richland, Washington, required massive quantities of water for reactor cooling and material processing. To reduce corrosion and the build-up of scale in pipelines and cooling systems, sodium dichromate was added to the water feedstock. Spills and other releases at the makeup facilities, as well as leaks from miles of pipelines, have led to numerous areas with chromium-contaminated soil and groundwater, threatening fish populations in the nearby Columbia River. Pump-and-treat systems have been installed to remove chromium from the groundwater, but significant contamination remain in the soil column and poses a continuing threat to groundwater and the Columbia River. Washington Closure Hanford, DOE, and regulators are working on a team approach that implements the observational approach, a strategy for effectively dealing with the uncertainties inherent in subsurface conditions. Remediation of large, complex waste sites at a federal facility is a daunting effort. It is particularly difficult to perform the work in an environment of rapid response to changing field and contamination conditions. The observational approach, developed by geotechnical engineers to accommodate the inherent uncertainties in subsurface conditions, is a powerful and appropriate method for site remediation. It offers a structured means of quickly moving into full remediation and responding to the variations and changing conditions inherent in waste site cleanups. A number of significant factors, however, complicate the application of the observational approach for chromium site remediation. Conceptual models of contamination and site conditions are difficult to establish and get consensus on. Mid-stream revisions to the design of large excavations are time-consuming and costly. And regulatory constraints and contract performance incentives can be impediments to the flexible responses required under the observational

  7. Parallel processing and expert systems

    NASA Technical Reports Server (NTRS)

    Yan, Jerry C.; Lau, Sonie

    1991-01-01

    Whether it be monitoring the thermal subsystem of Space Station Freedom, or controlling the navigation of the autonomous rover on Mars, NASA missions in the 90's cannot enjoy an increased level of autonomy without the efficient use of expert systems. Merely increasing the computational speed of uniprocessors may not be able to guarantee that real time demands are met for large expert systems. Speed-up via parallel processing must be pursued alongside the optimization of sequential implementations. Prototypes of parallel expert systems have been built at universities and industrial labs in the U.S. and Japan. The state-of-the-art research in progress related to parallel execution of expert systems was surveyed. The survey is divided into three major sections: (1) multiprocessors for parallel expert systems; (2) parallel languages for symbolic computations; and (3) measurements of parallelism of expert system. Results to date indicate that the parallelism achieved for these systems is small. In order to obtain greater speed-ups, data parallelism and application parallelism must be exploited.

  8. Remediation of water contaminated with diesel oil using a coupled process: Biological degradation followed by heterogeneous Fenton-like oxidation.

    PubMed

    Chen, Yuan; Lin, Jiajiang; Chen, Zuliang

    2017-09-01

    The treatment of a synthetically prepared wastewater containing diesel oil has been investigated using combined treatment schemes based on the biological treatment followed by an advanced oxidation process. 78% of diesel oil was degraded by Acinetobacter venetianus in 96 h, while the removal efficiency of chemical oxygen demand (COD) in the aqueous phase was only 56.8%, indicating that degraded metabolites existed in solution. To solve this problem, a Fenton-like system consisting of nanoscale zero-valent iron (nZVI) and hydrogen peroxide was used for further oxidation of the metabolites after biodegradation. Results showed that the total COD removal increased from 56.8% to 89% under the optimal condition. In addition, effects of initial pH (2.0-9.0), ZVI dosage (0-2.0 g L-1), hydrogen peroxide (H2O2) dosage concentration (0-15 mmol L-1) and temperature (298-308 K) on the treatment efficiency of the combined process were studied. Scanning electron microscopy (SEM) demonstrated that changes to the surface of nZVI occurred. GC-MS revealed that the degraded metabolites were mineralized practically by nZVI/H2O2 system. The results points towards the potential of Fenton-like oxidation as a short post-treatment after a biological process for the treatment of organic pollutants in wastewater. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. An unmanned ground vehicle for landmine remediation

    NASA Astrophysics Data System (ADS)

    Wasson, Steven R.; Guilberto, Jose; Ogg, Wade; Wedeward, Kevin; Bruder, Stephen; El-Osery, Aly

    2004-09-01

    Anti-tank (AT) landmines slow down and endanger military advances and present sizeable humanitarian problems. The remediation of these mines by direct human intervention is both dangerous and costly. The Intelligent Systems & Robotics Group (ISRG) at New Mexico Tech has provided a partial solution to this problem by developing an Unmanned Ground Vehicle (UGV) to remediate these mines without endangering human lives. This paper presents an overview of the design and operation of this UGV. Current results and future work are also described herein. To initiate the remediation process the UGV is given the GPS coordinates of previously detected landmines. Once the UGV autonomously navigates to an acceptable proximity of the landmine, a remote operator acquires control over a wireless network link using a joystick on a base station. Utilizing two cameras mounted on the UGV, the operator is able to accurately position the UGV directly over the landmine. The UGV houses a self-contained drill system equipped with its own processing resources, sensors, and actuators. The drill system deploys a neutralizing device over the landmine to neutralize it. One such device, developed by Science Applications International Corporation (SAIC), employs incendiary materials to melt through the container of the landmine and slowly burn the explosive material, thereby safely and remotely disabling the landmine.

  10. Review of passive groundwater remediation systems: Lessons learned Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect

    1997-08-01

    One of the proposed solutions for treatment of the contaminated groundwater in the Bear Creek Valley is the installation of a passive treatment system. Such a system would use a reactive media installed in a continuous trench or in a gate as part of a barrier wall and gate system. This report evaluates information on five similar systems [no information was available on two additional systems] and evaluates the shortcomings and the advantages of each. Section 5 provides a short summary of the findings and presents some recommendations on how to avoid some of the common problems encountered with the existing systems.

  11. Chemical production processes and systems

    DOEpatents

    Holladay, Johnathan E.; Muzatko, Danielle S.; White, James F.; Zacher, Alan H.

    2014-06-17

    Hydrogenolysis systems are provided that can include a reactor housing an Ru-comprising hydrogenolysis catalyst and wherein the contents of the reactor is maintained at a neutral or acidic pH. Reactant reservoirs within the system can include a polyhydric alcohol compound and a base, wherein a weight ratio of the base to the compound is less than 0.05. Systems also include the product reservoir comprising a hydrogenolyzed polyhydric alcohol compound and salts of organic acids, and wherein the moles of base are substantially equivalent to the moles of salts or organic acids. Processes are provided that can include an Ru-comprising catalyst within a mixture having a neutral or acidic pH. A weight ratio of the base to the compound can be between 0.01 and 0.05 during exposing.

  12. Chemical production processes and systems

    DOEpatents

    Holladay, Johnathan E; Muzatko, Danielle S; White, James F; Zacher, Alan H

    2015-04-21

    Hydrogenolysis systems are provided that can include a reactor housing an Ru-comprising hydrogenolysis catalyst and wherein the contents of the reactor is maintained at a neutral or acidic pH. Reactant reservoirs within the system can include a polyhydric alcohol compound and a base, wherein a weight ratio of the base to the compound is less than 0.05. Systems also include the product reservoir comprising a hydrogenolyzed polyhydric alcohol compound and salts of organic acids, and wherein the moles of base are substantially equivalent to the moles of salts or organic acids. Processes are provided that can include an Ru-comprising catalyst within a mixture having a neutral or acidic pH. A weight ratio of the base to the compound can be between 0.01 and 0.05 during exposing.

  13. NDMAS System and Process Description

    SciTech Connect

    Larry Hull

    2012-10-01

    Experimental data generated by the Very High Temperature Reactor Program need to be more available to users in the form of data tables on Web pages that can be downloaded to Excel or in delimited text formats that can be used directly for input to analysis and simulation codes, statistical packages, and graphics software. One solution that can provide current and future researchers with direct access to the data they need, while complying with records management requirements, is the Nuclear Data Management and Analysis System (NDMAS). This report describes the NDMAS system and its components, defines roles and responsibilities, describes the functions the system performs, describes the internal processes the NDMAS team uses to carry out the mission, and describes the hardware and software used to meet Very High Temperature Reactor Program needs.

  14. A Systems Approach to the Development of a Junior College Course in Remedial Mathematics.

    ERIC Educational Resources Information Center

    Carman, Robert A.

    This paper explains the systems approach. Of several definitions, the simplest is that a system is a set of parts coordinated to achieve a [goal or] set of goals. A modified systems approach could likely be an effective tool in educational planning. The information feedback loop permits the manager to base his actions on the actual performance of…

  15. Remediation of language processing in aphasia: Improving activation and maintenance of linguistic representations in (verbal) short-term memory

    PubMed Central

    Kalinyak-Fliszar, Michelene; Kohen, Francine; Martin, Nadine

    2012-01-01

    Background Verbal short-term memory (STM) impairments are invariably present in aphasia. Word processing involves a minimal form of verbal STM, i.e., the time course over which semantic and phonological representations are activated and maintained until they are comprehended, produced, or repeated. Thus it is reasonable that impairments of word processing and verbal STM may co-occur. The co-occurrence of language and STM impairments in aphasia has motivated an active area of research that has revealed much about the relationship of these two systems and the effect of their impairment on language function and verbal learning (Freedman & Martin, 2001; Martin & Saffran, 1999; Trojano & Grossi, 1995). In keeping with this view a number of researchers have developed treatment protocols to improve verbal STM in order to improve language function (e.g., Koenig-Bruhin & Studer-Eichenberger, 2007). This account of aphasia predicts that treatment of a fundamental ability, such as STM, which supports language function, should lead to improvements that generalise to content and tasks beyond those implemented in treatment. Aims We investigated the efficacy of a treatment for language impairment that targets two language support processes: verbal short-term memory (STM) and executive processing, in the context of a language task (repetition). We hypothesised that treatment of these abilities would improve repetition abilities and performance on other language tasks that require STM. Method A single-participant, multiple-baseline, multiple-probe design across behaviours was used with a participant with conduction aphasia. The treatment involved repetition of words and nonwords under three “interval” conditions, which varied the time between hearing and repeating the stimulus. Measures of treatment effects included acquisition, maintenance, and follow-up data, effect sizes, and pre- and post-treatment performance on a test battery that varies the STM and executive function

  16. Remediating munitions contaminated soils

    SciTech Connect

    Shea, P.J.; Comfort, S.D.

    1995-10-01

    The former Nebraska Ordnance Plant (NOP) at Mead, NE was a military loading, assembling, and packing facility that produced bombs, boosters and shells during World War II and the Korean War (1942-1945, 1950-1956). Ordnances were loaded with 2,4,6-trinitrotoluene (TNT), amatol (TNT and NH{sub 4}NO{sub 3}), tritonal (TNT and Al) and Composition B (hexahydro-1,3,5-trinitro-1,3,5-triazine [RDX] and TNT). Process waste waters were discharged into wash pits and drainage ditches. Soils within and surrounding these areas are contaminated with TNT, RDX and related compounds. A continuous core to 300 cm depth obtained from an NOP drainage ditch revealed high concentrations of TNT in the soil profile and substantial amounts of monoamino reduction products, 4-amino-2,6-dinitrotoluene (4ADNT) and 2-amino-4,6-dinitrotoluene (2ADNT). Surface soil contained TNT in excess of 5000 mg kg{sup -1} and is believed to contain solid phase TNT. This is supported by measuring soil solution concentrations at various soil to solution ratios (1:2 to 1:9) and obtaining similar TNT concentrations (43 and 80 mg L{sup -1}). Remediating munitions-contaminated soil at the NOP and elsewhere is of vital interest since many of the contaminants are carcinogenic, mutagenic or otherwise toxic to humans and the environment. Incineration, the most demonstrated remediation technology for munitions-containing soils, is costly and often unacceptable to the public. Chemical and biological remediation offer potentially cost-effective and more environmentally acceptable alternatives. Our research objectives are to: (a) characterize the processes affecting the transport and fate of munitions in highly contaminated soil; (b) identify effective chemical and biological treatments to degrade and detoxify residues; and (c) integrate these approaches for effective and practical remediation of soil contaminated with TNT, RDX, and other munitions residues.

  17. Developing a Reciprocal Teaching/Learning System for College Remedial Reading Instruction

    ERIC Educational Resources Information Center

    Yang, Yu-Fen

    2010-01-01

    In face-to-face instruction of "Reciprocal Teaching (RT)", students' reading processes and dialogues with their peers are hardly observed. As a result, the teacher has few clues to identify students' learning difficulties and provide further scaffoldings. To record students' reading processes and enhance their comprehension, this study reports on…

  18. Remedial Action Assessment System (RAAS): Evaluation of selected feasibility studies of CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act) hazardous waste sites

    SciTech Connect

    Whelan, G. ); Hartz, K.E.; Hilliard, N.D. and Associates, Seattle, WA )

    1990-04-01

    Congress and the public have mandated much closer scrutiny of the management of chemically hazardous and radioactive mixed wastes. Legislative language, regulatory intent, and prudent technical judgment, call for using scientifically based studies to assess current conditions and to evaluate and select costeffective strategies for mitigating unacceptable situations. The NCP requires that a Remedial Investigation (RI) and a Feasibility Study (FS) be conducted at each site targeted for remedial response action. The goal of the RI is to obtain the site data needed so that the potential impacts on public health or welfare or on the environment can be evaluated and so that the remedial alternatives can be identified and selected. The goal of the FS is to identify and evaluate alternative remedial actions (including a no-action alternative) in terms of their cost, effectiveness, and engineering feasibility. The NCP also requires the analysis of impacts on public health and welfare and on the environment; this analysis is the endangerment assessment (EA). In summary, the RI, EA, and FS processes require assessment of the contamination at a site, of the potential impacts in public health or the environment from that contamination, and of alternative RAs that could address potential impacts to the environment. 35 refs., 7 figs., 1 tab.

  19. Comparison of three types of oil crop rotation systems for effective use and remediation of heavy metal contaminated agricultural soil.

    PubMed

    Yang, Yang; Zhou, Xihong; Tie, Boqing; Peng, Liang; Li, Hongliang; Wang, Kelin; Zeng, Qingru

    2017-12-01

    Selecting suitable plants tolerant to heavy metals and producing products of economic value may be a key factor in promoting the practical application of phytoremediation polluted soils. The aim of this study is to further understand the utilization and remediation of seriously contaminated agricultural soil. In a one-year field experiment, we grew oilseed rape over the winter and then subsequently sunflowers, peanuts and sesame after the first harvest. This three rotation system produced high yields of dry biomass; the oilseed rape-sunflower, oilseed rape-peanut and oilseed rape-sesame rotation allowed us to extract 458.6, 285.7, and 134.5 g ha(-1) of cadmium, and 1264.7, 1006.1, and 831.1 g ha(-1) of lead from soil, respectively. The oilseed rape-sunflower rotation showed the highest phytoextraction efficiency (1.98%) for cadmium. Lead and cadmium in oils are consistent with standards after extraction with n-hexane. Following successive extractions with potassium tartrate, concentrations of lead and cadmium in oilseed rape and peanut seed meals were lower than levels currently permissible for feeds. Thus, this rotation system could be useful for local farmers as it would enable the generation of income during otherwise sparse phytoremediation periods. Copyright © 2017. Published by Elsevier Ltd.

  20. Use of natural and applied tracers to guide targeted remediation efforts in an acid mine drainage system, Colorado Rockies, USA

    USGS Publications Warehouse

    Cowie, Rory; Williams, Mark W.; Wireman, Mike; Runkel, Robert L.

    2014-01-01

    Stream water quality in areas of the western United States continues to be degraded by acid mine drainage (AMD), a legacy of hard-rock mining. The Rico-Argentine Mine in southwestern Colorado consists of complex multiple-level mine workings connected to a drainage tunnel discharging AMD to passive treatment ponds that discharge to the Dolores River. The mine workings are excavated into the hillslope on either side of a tributary stream with workings passing directly under the stream channel. There is a need to define hydrologic connections between surface water, groundwater, and mine workings to understand the source of both water and contaminants in the drainage tunnel discharge. Source identification will allow targeted remediation strategies to be developed. To identify hydrologic connections we employed a combination of natural and applied tracers including isotopes, ionic tracers, and fluorescent dyes. Stable water isotopes (δ18O/δD) show a well-mixed hydrological system, while tritium levels in mine waters indicate a fast flow-through system with mean residence times of years not decades or longer. Addition of multiple independent tracers indicated that water is traveling through mine workings with minimal obstructions. The results from a simultaneous salt and dye tracer application demonstrated that both tracer types can be successfully used in acidic mine water conditions.

  1. Evaluation of remediation process with soapberry derived saponin for removal of heavy metals from contaminated soils in Hai-Pu, Taiwan.

    PubMed

    Maity, Jyoti Prakash; Huang, Yuh Ming; Fan, Cheng-Wei; Chen, Chien-Cheng; Li, Chun-Yi; Hsu, Chun-Mei; Chang, Young-Fo; Wu, Ching-I; Chen, Chen-Yen; Jean, Jiin-Shuh

    2013-06-01

    The use of a biodegradable natural plant-based surfactant extracted from soapberry is proposed for the remediation of Ni, Cr and Mn from industrial soil site in Hai-Pu, Taiwan. Batch experiments were performed under variation of fundamental factors (saponin concentration, pH, and incubation time) for metal remediation. Removal of Ni and Mn were increased with increasing saponin concentration (0.015-0.150 g/L), whereas the removal of Cr was increased upto 0.075 g/L saponin. The Ni, Cr and Mn were removed significantly (p < or = 0.05) at near to the neutral and slightly acidic (pH 5 to 8) conditions. Removal efficiency of Ni (99%) from the soil was found to be greater than that of Cr (73%) or Mn (25%) in the presence of saponin at a concentration of 0.150 g/L at pH 5. The removal percentage increased with incubation time where the removal of Ni was faster than that of Cr and Mn. The result indicates the feasibility of eco-friendly removal of heavy metal (Ni, Cr and Mn) from industrial soil by soil washing process in presence of plant derived saponin.

  2. Remedial action and feedback processing in a time-estimation task: evidence for a role of the rostral cingulate zone in behavioral adjustments without learning.

    PubMed

    van der Veen, Frederik M; Röder, Christian H; Mies, Gabry W; van der Lugt, Aad; Smits, Marion

    2011-01-01

    The present study examined the role of the rostral cingulate zone (RCZ) in feedback processing, and especially focused on effects of modality of the feedback stimulus and remedial action. Participants performed a time-estimation task in which they had to estimate a 1-second interval. After the estimation participants received verbal (correct/false) or facial (fearful face/happy face) feedback. Percentage of positive and negative feedback was kept at 50% by dynamically adjusting the interval in which estimations were labeled correct. Contrary to predictions of the reinforcement learning theory, which predicts more RCZ activation when the outcome of behavior is worse than expected, we found that the RCZ was more active after positive feedback than after negative feedback, independent of the modality of the feedback stimulus. More in line with the suggested role of the RCZ in reinforcement learning was the finding that the RCZ was more active after negative feedback that was followed by a correct adjustment as compared to negative feedback followed by an incorrect adjustment. Both findings can be explained in terms of the RCZ being involved in facilitating remedial action as opposed to the suggested signaling function (outcome is worse than expected) proposed by the reinforcement learning theory.

  3. An approach to quantify sources, seasonal change, and biogeochemical processes affecting metal loading in streams: Facilitating decisions for remediation of mine drainage

    USGS Publications Warehouse

    Kimball, B.A.; Runkel, R.L.; Walton-Day, K.

    2010-01-01

    Historical mining has left complex problems in catchments throughout the world. Land managers are faced with making cost-effective plans to remediate mine influences. Remediation plans are facilitated by spatial mass-loading profiles that indicate the locations of metal mass-loading, seasonal changes, and the extent of biogeochemical processes. Field-scale experiments during both low- and high-flow conditions and time-series data over diel cycles illustrate how this can be accomplished. A low-flow experiment provided spatially detailed loading profiles to indicate where loading occurred. For example, SO42 - was principally derived from sources upstream from the study reach, but three principal locations also were important for SO42 - loading within the reach. During high-flow conditions, Lagrangian sampling provided data to interpret seasonal changes and indicated locations where snowmelt runoff flushed metals to the stream. Comparison of metal concentrations between the low- and high-flow experiments indicated substantial increases in metal loading at high flow, but little change in metal concentrations, showing that toxicity at the most downstream sampling site was not substantially greater during snowmelt runoff. During high-flow conditions, a detailed temporal sampling at fixed sites indicated that Zn concentration more than doubled during the diel cycle. Monitoring programs must account for diel variation to provide meaningful results. Mass-loading studies during different flow conditions and detailed time-series over diel cycles provide useful scientific support for stream management decisions.

  4. MULTI-OBJECTIVE OPTIMAL DESIGN OF GROUNDWATER REMEDIATION SYSTEMS: APPLICATION OF THE NICHED PARETO GENETIC ALGORITHM (NPGA). (R826614)

    EPA Science Inventory

    A multiobjective optimization algorithm is applied to a groundwater quality management problem involving remediation by pump-and-treat (PAT). The multiobjective optimization framework uses the niched Pareto genetic algorithm (NPGA) and is applied to simultaneously minimize the...

  5. Optimization Strategies for Long-Term Ground Water Remedies (with Particular Emphasis on Pump and Treat Systems)

    EPA Pesticide Factsheets

    This fact sheet has been prepared to assist environmental case managers from Federal and State agencies, environmental program managers from private organizations, and environmental contractors with optimization of operating long-term ground water remedies

  6. MULTI-OBJECTIVE OPTIMAL DESIGN OF GROUNDWATER REMEDIATION SYSTEMS: APPLICATION OF THE NICHED PARETO GENETIC ALGORITHM (NPGA). (R826614)

    EPA Science Inventory

    A multiobjective optimization algorithm is applied to a groundwater quality management problem involving remediation by pump-and-treat (PAT). The multiobjective optimization framework uses the niched Pareto genetic algorithm (NPGA) and is applied to simultaneously minimize the...

  7. Dynamic security assessment processing system

    NASA Astrophysics Data System (ADS)

    Tang, Lei

    The architecture of dynamic security assessment processing system (DSAPS) is proposed to address online dynamic security assessment (DSA) with focus of the dissertation on low-probability, high-consequence events. DSAPS upgrades current online DSA functions and adds new functions to fit into the modern power grid. Trajectory sensitivity analysis is introduced and its applications in power system are reviewed. An index is presented to assess transient voltage dips quantitatively using trajectory sensitivities. Then the framework of anticipatory computing system (ACS) for cascading defense is presented as an important function of DSAPS. ACS addresses various security problems and the uncertainties in cascading outages. Corrective control design is automated to mitigate the system stress in cascading progressions. The corrective controls introduced in the dissertation include corrective security constrained optimal power flow, a two-stage load control for severe under-frequency conditions, and transient stability constrained optimal power flow for cascading outages. With state-of-the-art computing facilities to perform high-speed extended-term time-domain simulation and optimization for large-scale systems, DSAPS/ACS efficiently addresses online DSA for low-probability, high-consequence events, which are not addressed by today's industrial practice. Human interference is reduced in the computationally burdensome analysis.

  8. Multipurpose Vacuum Induction Processing System

    NASA Astrophysics Data System (ADS)

    Govindaraju, M.; Kulkarni, Deepak; Balasubramanian, K.

    2012-11-01

    Multipurpose vacuum processing systems are cost effective; occupy less space, multiple functional under one roof and user friendly. A multipurpose vacuum induction system was designed, fabricated and installed in a record time of 6 months time at NFTDC Hyderabad. It was designed to function as a) vacuum induction melting/refining of oxygen free electronic copper/pure metals, b) vacuum induction melting furnace for ferrous materials c) vacuum induction melting for non ferrous materials d) large vacuum heat treatment chamber by resistance heating (by detachable coil and hot zone) e) bottom discharge vacuum induction melting system for non ferrous materials f) Induction heat treatment system and g) directional solidification /investment casting. It contains provision for future capacity addition. The attachments require to manufacture multiple shaped castings and continuous rod casting can be added whenever need arises. Present capacity is decided on the requirement for 10years of development path; presently it has 1.2 ton liquid copper handling capacity. It is equipped with provision for capacity addition up to 2 ton liquid copper handling capacity in future. Provision is made to carry out the capacity addition in easy steps quickly. For easy operational maintenance and troubleshooting, design was made in easily detachable sections. High vacuum system is also is detachable, independent and easily movable which is first of its kind in the country. Detailed design parameters, advantages and development history are presented in this paper.

  9. A systems process of reinforcement.

    PubMed

    Sudakov, K V

    1997-01-01

    Functional systems theory was used to consider the process of reinforcement of the actions on the body of reinforcing factors, i.e., the results of behavior satisfying the body's original needs. The systems process of reinforcement includes reverse afferentation entering the CNS from receptors acted upon by various parameters of the desired results, and mechanisms for comparing reverse afferentation with the apparatus which accepts the results of the action and the corresponding emotional component. A tight interaction between reinforcement and the dominant motivation is generated on the basis of the hologram principle. Reinforcement forms an apparatus for predicting a desired result, i.e. a result-of-action acceptor. Reinforcement procedures significant changes in the activities of individual neurons in the various brain structures involved in dominant motivation, transforming their spike activity for a burst pattern to regular discharges; there are also molecular changes in neuron properties. After preliminary reinforcement, the corresponding motivation induces the ribosomal system of neurons to start synthesizing special effector molecules, which organize molecular engrams of the acceptor of the action's result. Sensory mechanisms of reinforcement are considered, with particular reference to the information role of emotions.

  10. Vertical circulation flows for vadose and groundwater zone in situ (bio-)remediation

    SciTech Connect

    Stamm, J.

    1995-12-31

    Vertical circulation flows have been established under in situ remediation techniques. Their hydraulic flow field permits physical and biological remediation of the saturated, as well as the unsaturated subsoil. A special advantage is that these techniques can be combined with any appropriate in-well or on-site technique. Even addition of nutrients and/or electron acceptors for stimulating biological degradation processes are possible. This paper discusses the different remediation techniques and the numerical results associated with the influence of hydrogeologic conditions on the system`s radius of influence and time behavior. Attention is focused on BTEX, PCE, and TCE.

  11. Lasagna{trademark} soil remediation

    SciTech Connect

    1996-04-01

    Lasagna{trademark} is an integrated, in situ remediation technology being developed which remediates soils and soil pore water contaminated with soluble organic compounds. Lasagna{trademark} is especially suited to sites with low permeability soils where electroosmosis can move water faster and more uniformly than hydraulic methods, with very low power consumption. The process uses electrokinetics to move contaminants in soil pore water into treatment zones where the contaminants can be captured and decomposed. Initial focus is on trichloroethylene (TCE), a major contaminant at many DOE and industrial sites. Both vertical and horizontal configurations have been conceptualized, but fieldwork to date is more advanced for the vertical configuration. Major features of the technology are electrodes energized by direct current, which causes water and soluble contaminants to move into or through the treatment layers and also heats the soil; treatment zones containing reagents that decompose the soluble organic contaminants or adsorb contaminants for immobilization or subsequent removal and disposal; and a water management system that recycles the water that accumulates at the cathode (high pH) back to the anode (low pH) for acid-base neutralization. Alternatively, electrode polarity can be reversed periodically to reverse electroosmotic flow and neutralize pH.

  12. Environmental impact of phosphogypsum stockpile in remediated Schistos waste site (Piraeus, Greece) using a combination of γ-ray spectrometry with geographic information systems.

    PubMed

    Papageorgiou, F; Godelitsas, A; Mertzimekis, T J; Xanthos, S; Voulgaris, N; Katsantonis, G

    2016-03-01

    From 1979 to 1989, ten million tons of phosphogypsum, a waste by-product of the Greek phosphate fertilizer industry, was disposed into an abandoned limestone quarry in Schistos former waste site, Piraeus (Greece). The quarry has been recently closed and remediated using geomembranes and thick soil cover with vegetation. A part of the deposited phosphogypsum has been exposed due to intense rainfall episodes leading to concerns about how could potentially released radioactivity affect the surrounding environment. This study seeks to assess the environmental impact of the phosphogypsum deposited in the Schistos quarry, using laboratory-based γ-ray spectrometry measurements and geographical information systems. Radioactivity concentrations were mapped onto spatial-data to yield a spatial-distribution of radioactivity in the area. The data indicate elevated (226)Ra concentrations in a specific area on the steep south-eastern cliff of the remediated waste site that comprises uncovered phosphogypsum and is known to be affected by local weather conditions. (226)Ra concentrations range from 162 to 629 Bq/kg, with an average activity being on the low side, compared to the global averages for phosphogypsum. Nevertheless, the low environmental risk may be minimized by remediating this area with geomembranes and thick soil cover with vegetation, a technique, which has worked successfully over the remainder of the remediated quarry.

  13. COUPLED IRON CORROSION AND CHROMATE REDUCTION: MECHANISMS FOR SUBSURFACE REMEDIATION

    EPA Science Inventory

    The reduction of chromium from the Cr(VI) to the Cr- (Ill) state by the presence of elemental, or zero-oxidation-state, iron metal was studied to evaluate the feasibility of such a process for subsurface chromate remediation. Reactions were studied in systems of natural aquifer m...

  14. COUPLED IRON CORROSION AND CHROMATE REDUCTION: MECHANISMS FOR SUBSURFACE REMEDIATION

    EPA Science Inventory

    The reduction of chromium from the Cr(VI) to the Cr- (Ill) state by the presence of elemental, or zero-oxidation-state, iron metal was studied to evaluate the feasibility of such a process for subsurface chromate remediation. Reactions were studied in systems of natural aquifer m...

  15. [The systems process of reinforcement].

    PubMed

    Sudakov, K V

    1996-01-01

    The process of reinforcement is considered in the context of the general theory of functional systems as an important part of behavioural act organization closely interacting with the dominant motivation. It is shown that reinforcement substantially changes the activities of separate neurons in different brain structures involved in dominant motivation. After a preliminary reinforcement under the influence of corresponding motivation the ribosomal apparatus of neurons begins to synthesize special molecular engrams of the action acceptor. The sensory mechanisms of reinforcement and, especially, the role of emotions are considered in details in the paper.

  16. Contaminated Groundwater Remediation by Catalyzed Hydrogen Peroxide and Persulfate Oxidants System

    NASA Astrophysics Data System (ADS)

    Yan, N.; Wang, Y.; Brusseau, M. L.

    2014-12-01

    A binary oxidant system, catalyzed hydrogen peroxide (H2O2) coupled with persulfate (S2O82-), was investigated for use in in-situ chemical oxidation (ISCO) applications. Trichloroethene (TCE) and 1,4-dioxane were used as target contaminants. Batch experiments were conducted to investigate the catalytic efficiency between ferrous ion (Fe2+) and base (NaOH), oxidant decomposition rates, and contaminant degradation efficiency. For the base-catalyzed H2O2-S2O82- system, oxidant release was moderate and sustained over the entire test period of 96 hours. Conversely, the oxidants were depleted within 24 hours for the Fe2+-catalyzed system. Solution pH decreased slightly for the Fe2+-catalyzed system, whereas the pH increased for the base-catalyzed system. The rates of degradation for TCE and 1,4-dioxane are compared as a function of system conditions. The results of this study indicate that the binary H2O2-S2O82- oxidant system is effective for oxidation of the tested contaminants.

  17. Tank waste remediation system retrieval and disposal mission key enabling assumptions

    SciTech Connect

    Baldwin, J.H.

    1998-01-09

    An overall systems approach has been applied to develop action plans to support the retrieval and immobilization waste disposal mission. The review concluded that the systems and infrastructure required to support the mission are known. Required systems are either in place or plans have been developed. An analysis of the programmatic, management and technical activities necessary to declare Readiness to Proceed with execution of the mission demonstrates that the system, people, and hardware will be on line and ready to support the private contractors. The systems approach included defining the retrieval and immobilized waste disposal mission requirements and evaluating the readiness of the TWRS contractor to supply waste feed to the private contractors in June 2002. The Phase 1 feed delivery requirements from the Private Contractor Request for Proposals were reviewed, transfer piping routes were mapped on it, existing systems were evaluated, and upgrade requirements were defined. Technical Basis Reviews were completed to define work scope in greater detail, cost estimates and associated year by year financial analyses were completed. Personnel training, qualifications, management systems and procedures were reviewed and shown to be in place and ready to support the Phase 1B mission. Key assumptions and risks that could negatively impact mission success were evaluated and appropriate mitigative actions plans were planned and scheduled.

  18. CENTRAL PLATEAU REMEDIATION

    SciTech Connect

    ROMINE, L.D.

    2006-02-01

    A systematic approach to closure planning is being implemented at the Hanford Site's Central Plateau to help achieve the goal of closure by the year 2035. The overall objective of Central Plateau remediation is to protect human health and the environment from the significant quantity of contaminated material that resulted from decades of plutonium production in support of the nation's defense. This goal will be achieved either by removing contaminants or placing the residual contaminated materials in a secure configuration that minimizes further migration to the groundwater and reduces the potential for inadvertent intrusion into contaminated sites. The approach to Central Plateau cleanup used three key concepts--closure zones, closure elements, and closure process steps--to create an organized picture of actions required to complete remediation. These actions were merged with logic ties, constraints, and required resources to produce an integrated time-phased schedule and cost profile for Central Plateau closure. Programmatic risks associated with implementation of Central Plateau closure were identified and analyzed. Actions to mitigate the most significant risks are underway while high priority remediation projects continue to make progress.

  19. Acid Mine Drainage Research in Gauteng Highlighting Impacts on Infrastructure and Innovation of Concrete-Based Remedial Systems

    NASA Astrophysics Data System (ADS)

    Diop, S.; Ekolu, S.; Azene, F.

    2013-12-01

    Acid mine drainage (AMD) is presently one of the most important environmental problems in in the densely populated Gauteng Province, South Africa. The threat of acid mine drainage has demanded short-term interventions (some of which are being implemented by government) but more importantly sustainable long-term innovative solutions. There have been moments of public apprehension with some media reports dubbing the current scenario as a future 'nightmare of biblical proportions' and 'South Africa's own Chernobyl' that could cause dissolving of concrete foundations of buildings and reinforcement steel, leading to collapse of structures. In response to the needs of local and provincial authorities, this research was conducted to (1) generate scientific understanding of the effects of AMD on infrastructure materials and structures, and (2) propose innovative long-term remedial systems based on cementitious materials for potential AMD treatment applications of engineering scale. Two AMD solutions from the goldfields and two others from the coalfields were used to conduct corrosion immersion tests on mild steel, stainless steel, mortars, pastes and concretes. Results show that AMD water from the gold mines is more corrosive than that from the coal mines, the corrosion rate of the former being about twice that of the latter. The functionality of metal components of mild steel can be expected to fail within one month of exposure to the mine water. The investigation has also led to development of a pervious concrete filter system of water-cement ratio = 0.27 and cement content = 360 kg/m3, to be used as a permeable reactive barrier for AMD treatment. Early results show that the system was effective in removing heavy metal contaminants with removal levels of 30% SO4, 99% Fe, 50-83% Mn, 85% Ca, and 30% TDS. Further work is on-going to improve and optimise the system prior to field demonstration studies.

  20. Rapid response tools and datasets for post-fire modeling: linking Earth Observations and process-based hydrological models to support post-fire remediation

    NASA Astrophysics Data System (ADS)

    Miller, M. E.; Billmire, M.; Elliot, W. J.; Endsley, K. A.; Robichaud, P. R.

    2015-04-01

    Preparation is key to utilizing Earth Observations and process-based models to support post-wildfire mitigation. Post-fire flooding and erosion can pose a serious threat to life, property and municipal water supplies. Increased runoff and sediment delivery due to the loss of surface cover and fire-induced changes in soil properties are of great concern. Remediation plans and treatments must be developed and implemented before the first major storms in order to be effective. One of the primary sources of information for making remediation decisions is a soil burn severity map derived from Earth Observation data (typically Landsat) that reflects fire induced changes in vegetation and soil properties. Slope, soils, land cover and climate are also important parameters that need to be considered. Spatially-explicit process-based models can account for these parameters, but they are currently under-utilized relative to simpler, lumped models because they are difficult to set up and require spatially-explicit inputs (digital elevation models, soils, and land cover). Our goal is to make process-based models more accessible by preparing spatial inputs before a fire, so that datasets can be rapidly combined with soil burn severity maps and formatted for model use. We are building an online database (http://geodjango.mtri.org/geowepp /) for the continental United States that will allow users to upload soil burn severity maps. The soil burn severity map is combined with land cover and soil datasets to generate the spatial model inputs needed for hydrological modeling of burn scars. Datasets will be created to support hydrological models, post-fire debris flow models and a dry ravel model. Our overall vision for this project is that advanced GIS surface erosion and mass failure prediction tools will be readily available for post-fire analysis using spatial information from a single online site.