Rock.XML - Towards a library of rock physics models

NASA Astrophysics Data System (ADS)

Jensen, Erling Hugo; Hauge, Ragnar; Ulvmoen, Marit; Johansen, Tor Arne; Drottning, Åsmund

2016-08-01

Rock physics modelling provides tools for correlating physical properties of rocks and their constituents to the geophysical observations we measure on a larger scale. Many different theoretical and empirical models exist, to cover the range of different types of rocks. However, upon reviewing these, we see that they are all built around a few main concepts. Based on this observation, we propose a format for digitally storing the specifications for rock physics models which we have named Rock.XML. It does not only contain data about the various constituents, but also the theories and how they are used to combine these building blocks to make a representative model for a particular rock. The format is based on the Extensible Markup Language XML, making it flexible enough to handle complex models as well as scalable towards extending it with new theories and models. This technology has great advantages as far as documenting and exchanging models in an unambiguous way between people and between software. Rock.XML can become a platform for creating a library of rock physics models; making them more accessible to everyone.

Rating the strength of coal mine roof rocks. Information circular/1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Molinda, G.M.; Mark, C.

1996-05-01

The Ferm pictoral classification of coal measure rocks is widely utilized in coalfield exploration. Although extremely useful as an alternative to conventional geologic description, no material properties are provided that would be suitable for engineering solutions. To remedy this problem, the USBM has tested over 30 common coal measure roof rock types for axial and bedding strength. More than 1,300 individual point load tests have been conducted on core from 8 different coal mines representing the full range of common coal measure rocks. The USBM core and roof exposure properties database has been merged with the picture classification to provide,more » for the first time, a simple, clear guide from field identification of core to the associated mechanical strength of the rock. For 33 of the most common roof rocks, the axial and diametral point load strength, as well as the ultimate unit rating, is overprinted onto the photograph.« less

S-type granitic magmas—petrogenetic issues, models and evidence

NASA Astrophysics Data System (ADS)

Clemens, J. D.

2003-04-01

Despite a perception that it represents a perverse divergence, it is perfectly possible to believe in the existence of S- and I-type granites (and the implications for the nature of their protoliths), and to disbelieve in the applicability of the restite-unmixing model for chemical variation in granitic magmas. White and Chappell erected the S-I classification with impeccable validity. The isotopic evidence demands contrasting source reservoirs for S- and I-type granitic magmas. However, the major advance was not the classification, but the recognition that highly contrasting parental materials must be involved in the genesis of granitic magmas. The restite-unmixing model is commonly seen as a companion to the S-I classification, but it is really a separate issue. This model implies that the compositions of granites 'image' those of their source rocks in a simple way. However, there are other equally valid models that can explain the data, and none of them represents a unique solution. The most cogent explanation for the high-grade metasedimentary enclaves in most S-type granites is that they represent mid-crustal xenoliths; restitic enclaves are either rare or absent. Inherited zircons in S-type rocks are certainly restitic. However, the occurrence of a substantial restitic zircon population does not imply an equally substantial restitic component in the rest of the rock. Zircon and zirconium behaviours are controlled by disequilibrium and kinetics, and Zr contents of granitic rocks can rarely be used to infer magma temperatures. Since the dominant ages among inherited zircons in Lachlan Fold Belt (LFB) S-type granites are Ordovician and Proterozoic, it seems likely that crust of this age, but geochemically different from the exposed rocks, not only underlies much of the LFB but also forms a component in the granite magma sources. The evidence is overwhelming that the dark, microgranular enclaves that occur in both S- and I-type granites are igneous in origin. They represent globules of quenched, more mafic magma mingled and modified by exchange with the host granitic magma. However, magma mixing does not appear to be a significant process affecting the chemical evolution of the host magmas. Likewise, the multicomponent mixing models erected for some granitic rock suites are mathematically nonunique and, in some cases, violate constraints from isotopic studies. S- and I-type magmas commonly retain their distinct identities. This suggests limited source mixing, limited magma mixing and limited wall-rock assimilation. Though intermediate types certainly exist, they are probably relatively minor in volume. Crystal fractionation probably plays the major role in the differentiation of very many granitic magmas, including most S-types, especially those emplaced at high crustal levels or in the volcanic environment. Minor mechanisms include magma mixing, wall-rock assimilation and restite unmixing. Isotopic variations within plutons and in granite suites could be caused by source heterogeneities, magma mixing, assimilation and even by isotopic disequilibrium. However, source heterogeneity, coupled with the inefficiency of magma mixing is probably the major cause of observed heterogeneity. Normal geothermal gradients are seldom sufficient to provide the necessary heat for partial melting of the crust, and crustal thickening likewise fails to provide sufficient heat. Generally, the mantle must be the major heat source. This might be provided through mantle upwelling and crustal thinning, and possibly through the intra- and underplating of mafic magmas. Upper crustal extension seems to have been common in regions undergoing granitic magmatism. Migmatites probably provide poor analogues of granite source regions because they are mostly formed by fluid-present reactions. Granitic magmas are mostly formed by fluid-absent processes. Where we do see rare evidence for arrested fluid-absent partial melting, the melt fraction is invariably concentrated into small shear zones, veinlets and small dykes. Thus, it seems likely that dyking is important in transporting granitic magma on a variety of scales and at many crustal levels. However, one major missing link in the chain is the mechanism by which melt fractions, in small-scale segregations occurring over a wide area, can be gathered and focused to efficiently feed much wider-spaced major magma conduits. Answers may lie in the geometry of the melting zones and in the tendency of younger propagating fractures to curve toward and merge with older ones. Self-organization almost certainly plays a role.

Influences of petrographic parameters on technological properties of greywackes used for crushed stone production

NASA Astrophysics Data System (ADS)

Prikryl, Richard; Cermak, Martin; Krutilova, Katerina

2014-05-01

This study focuses on the influence of petrographic parameters on technological properties of greywackes. These sedimentary rocks make about 27 % of crushed stone market in the Czech Republic. Mainly in Moravia (eastern part of the Czech Republic), greywackes represent almost exclusive high quality aggregate. The behaviour of greywackes varies, however, from quarry to quarry. In this study, we have selected the most important deposits that cover major lithological variation of local greywackes. Studied greywackes were analysed for their petrographic parameters quantitatively (using image analysis of thin sections). The pore space characteristics were determined by using fluorescent dye - epoxy resin impregnated specimens. The studied rocks are composed of subangular and angular quartz grains, lithoclasts (stable rocks: quartzites, and unstable rocks: phylites, metaphylites, siltstones, slates, greywackes, and less frequently acid eruptive rocks), feldspars (orthoclas, microcline, plagioclase), and detrital micas. Detrital and authigenic chlorite has been found as well. The matrix which represents the largest volume of rock-forming components contains a mixture of sericite, chlorite, clay minerals, cements, and clasts in aleuropelitic size. Based on the microscopic examination, all studied rock types were classified as greywacke with fine- to medium-grained massive rock fabric. Only specimen from Bělkovice has shown partly layered structure. Alteration of feldspars and unstable rock fragments represents common feature. Diagenetic features included pressure dissolution of quartz clasts and formation of siliceous and/or calcite cements. Based on the experimental study of technological performance of studied greywackes and its correlation to petrographic features, the average size of clasts and volume of matrix make the driving factors affecting the LA values. The LA values decrease with the increasing of volume of matrix (R = 0.61) and with decreasing average grain size (R = 0.44). The degree of sorting influences LA values as well; more graded greywackes tend to show higher LA values. Regarding PSV, its values increase with increasing volume of quartz clasts.

Fault rock texture and porosity type in Triassic dolostones

NASA Astrophysics Data System (ADS)

Agosta, Fabrizio; Grieco, Donato; Bardi, Alessandro; Prosser, Giacomo

2015-04-01

Preliminary results of an ongoing project aimed at deciphering the micromechanics and porosity evolution associated to brittle deformation of Triassic dolostones are presented. Samples collected from high-angle, oblique-slip, 10's to 100's m-throw normal faults crosscutting Mesozoic carbonates of the Neo Tethys (Campanian-Lucanian Platform) are investigated by mean of field geological mapping, optical microscopy, SEM and image analyses. The goal is to characterize in detail composition, texture and porosity of cataclastic rocks in order to assess the structural architecture of dolomitic fault cores. Moreover, the present study addresses the time-space control exerted by several micro-mechanisms such as intragranular extensional fracturing, chipping and shear fracturing, which took place during grain rolling and crushing within the evolving faults, on type, amount, dimensions and distribution of micropores present within the cataclastic fault cores. Study samples are representative of well-exposed dolomitic fault cores of oblique-slip normal faults trending either NW-SE or NE-SW. The high-angle normal faults crosscut the Mesozoic carbonates of the Campanian-Lucanian Platform, which overrode the Lagonegro succession by mean of low-angle thrust faults. Fault throws are measured by considering the displaced thrust faults as key markers after large scale field mapping (1:10,000 scale) of the study areas. In the field, hand samples were selected according to their distance from main slip surfaces and, in some case, along secondary slip surfaces. Microscopy analysis of about 100 oriented fault rock samples shows that, mostly, the study cataclastic rocks are made up of dolomite and sparse, minute survivor silicate grains deriving from the Lagonegro succession. In order to quantitatively assess the main textural classes, a great attention is paid to the grain-matrix ratio, grain sphericity, grain roundness, and grain sorting. By employing an automatic box-counting technique, the fractal dimension of representative samples is also computed. Results of such a work shows that five main textural types are present: 1) fractured and fragmented dolomites; 2) protocataclasites characterized by intense intragranular extensional fracturing; 3) cataclasites due to a chipping-dominated mechanism; 4) cataclasites and ultracataclasites with pronounced shear fracturing; 5) cemented fault rocks, which localize along the main slip surfaces. The first four textural types are therefore indicative to the fault rock maturity within individual cataclastic fault cores. A negative correlation among grain-matrix ratio and grain sphericity, roundness and sorting is computed, which implies that ultracataclasites are made up of more spherical and rounded smaller grains relative to cataclasites and protocataclasites. Each textural type shows distinct D0-values (box-counting dimension). As expected, a good correlation between the D0-value and fault rock maturity is computed. Ongoing analysis of selected images obtained from representative samples of the five textural classes will shed lights on the relative role played by the aforementioned micro-mechanisms on the porosity evolution within the cataclastic fault cores.

Semimicro chemical and x-ray fluorescence analysis of lunar samples

USGS Publications Warehouse

Rose, H.J.; Cuttitta, F.; Dwornik, E.J.; Carron, M.K.; Christian, R.P.; Lindsay, J.R.; Ligon, D.T.; Larson, R.R.

1970-01-01

Major and selected minor elements were determined in seven whole rock fragments, five portions of pulverized lunar rock, and the lunar soil. Three different rock types were represented: vesicular, fine-grained basaltic rocks; medium-to coarse-grained, vuggy gabbroic rocks; and breccia. The ranges (in percent) for the major constituents of the lunar samples are: SiO2, 38 to 42; Al2O3, 8 to 14; total iron as FeO, 15 to 20; MgO, 6 to 8; CaO, 10 to 12; Na2O, 0.5 to 1; K2O, 0.05 to 0.4; TiO2, 8 to 13; MnO, 0.2 to 0.3; and Cr2O3, 0.2 to 0.4. The high reducing capacity of the samples strongly suggests the presence of Ti(III).

Historical rock falls in Yosemite National Park, California (1857-2011)

USGS Publications Warehouse

Stock, Greg M.; Collins, Brian D.; Santaniello, David J.; Zimmer, Valerie L.; Wieczorek, Gerald F.; Snyder, James B.

2013-01-01

Inventories of rock falls and other types of landslides are valuable tools for improving understanding of these events. For example, detailed information on rock falls is critical for identifying mechanisms that trigger rock falls, for quantifying the susceptibility of different cliffs to rock falls, and for developing magnitude-frequency relations. Further, inventories can assist in quantifying the relative hazard and risk posed by these events over both short and long time scales. This report describes and presents the accompanying rock fall inventory database for Yosemite National Park, California. The inventory database documents 925 events spanning the period 1857–2011. Rock falls, rock slides, and other forms of slope movement represent a serious natural hazard in Yosemite National Park. Rock-fall hazard and risk are particularly relevant in Yosemite Valley, where glacially steepened granitic cliffs approach 1 km in height and where the majority of the approximately 4 million yearly visitors to the park congregate. In addition to damaging roads, trails, and other facilities, rock falls and other slope movement events have killed 15 people and injured at least 85 people in the park since the first documented rock fall in 1857. The accompanying report describes each of the organizational categories in the database, including event location, type of slope movement, date, volume, relative size, probable trigger, impact to humans, narrative description, references, and environmental conditions. The inventory database itself is contained in a Microsoft Excel spreadsheet (Yosemite_rock_fall_database_1857-2011.xlsx). Narrative descriptions of events are contained in the database, but are also provided in a more readable Adobe portable document format (pdf) file (Yosemite_rock_fall_database_narratives_1857-2011.pdf) available for download separate from the database.

Cobalt—Styles of deposits and the search for primary deposits

USGS Publications Warehouse

Hitzman, Murray W.; Bookstrom, Arthur A.; Slack, John F.; Zientek, Michael L.

2017-11-30

Cobalt (Co) is a potentially critical mineral. The vast majority of cobalt is a byproduct of copper and (or) nickel production. Cobalt is increasingly used in magnets and rechargeable batteries. More than 50 percent of primary cobalt production is from the Central African Copperbelt. The Central African Copperbelt is the only sedimentary rock-hosted stratiform copper district that contains significant cobalt. Its presence may indicate significant mafic-ultramafic rocks in the local basement. The balance of primary cobalt production is from magmatic nickel-copper and nickel laterite deposits. Cobalt is present in several carbonate-hosted lead-zinc and copper districts. It is also variably present in Besshi-type volcanogenic massive sulfide and siliciclastic sedimentary rock-hosted deposits in back arc and rift environments associated with mafic-ultramafic rocks. Metasedimentary cobalt-copper-gold deposits (such as Blackbird, Idaho), iron oxide-copper-gold deposits, and the five-element vein deposits (such as Cobalt, Ontario) contain different amounts of cobalt. None of these deposit types show direct links to mafic-ultramafic rocks; the deposits may result from crustal-scale hydrothermal systems capable of leaching and transporting cobalt from great depths. Hydrothermal deposits associated with ultramafic rocks, typified by the Bou Azzer district of Morocco, represent another type of primary cobalt deposit.In the United States, exploration for cobalt deposits may focus on magmatic nickel-copper deposits in the Archean and Proterozoic rocks of the Midwest and the east coast (Pennsylvania) and younger mafic rocks in southeastern and southern Alaska; also, possibly basement rocks in southeastern Missouri. Other potential exploration targets include—The Belt-Purcell basin of British Columbia (Canada), Idaho, Montana, and Washington for different styles of sedimentary rock-hosted cobalt deposits;Besshi-type VMS deposits, such as the Greens Creek (Alaska) deposit and the Ducktown (Tennessee) waste and tailings; andKnown five-element vein districts in Arizona and New Mexico, as well as in the Yukon-Tanana terrane of Alaska; and hydrothermal deposits associated with ultramafic rocks along the west coast, in Alaska, and in the Appalachian Mountains.

A preliminary report on the geology of the Dennison-Bunn uranium claim, Sandoval County, New Mexico

USGS Publications Warehouse

Ridgley, Jennie L.

1978-01-01

Uranium at the Dennison-Bunn claim, south of Cuba, N. Mex., along the east margin of the San Juan Basin, occurs in unoxidized gray, fluvial channel sandstone of the Westwater Canyon Member of the Upper Jurassic Morrison Formation. The uranium-bearing sandstone is bounded on the north and south by a variable zone of buff and orange sandstone. Within the mineralized zone, the uranium has been remobilized and reconcentrated along the margins of numerous smaller tongues of oxidized rock in a configuration similar to that found in roll-type uranium deposits. In cross section, these small-scale features are zoned; they have an inner, pale orange, oxidized core, a mineralized redox rim cemented with hematite(?), and an outer-shell of -gray, slightly to moderately mineralized rock. The uranium content in the mineralized rock ranges from 0.001 to 0.07 percent U3O8. The uranium, at this locality, is believed to have originated within the Westwater Canyon Member or to have been derived from the overlying Brushy Basin Member. Based on observed outcrop relations, two hypotheses are proposed for explaining the origin of the occurrence. Briefly these hypotheses are: (1) the mineralized zone represents the remnant of an original roll-type uranium deposit, formed during early Eocene time, which has undergone subsequent oxidation with remobilization and redeposition of uranium around the margins of smaller tongues of oxidized rock; and (2) the mineralized zone represents the remnant of an original tabular deposit which has undergone subsequent oxidation with remobilization and redeposition of uranium around the margins of smaller tongues of oxidized rock.

Alaska geology revealed

USGS Publications Warehouse

Wilson, Frederic H.; Labay, Keith A.

2016-11-09

This map shows the generalized geology of Alaska, which helps us to understand where potential mineral deposits and energy resources might be found, define ecosystems, and ultimately, teach us about the earth history of the State. Rock units are grouped in very broad categories on the basis of age and general rock type. A much more detailed and fully referenced presentation of the geology of Alaska is available in the Geologic Map of Alaska (http://dx.doi.org/10.3133/sim3340). This product represents the simplification of thousands of individual rock units into just 39 broad groups. Even with this generalization, the sheer complexity of Alaskan geology remains evident.

Stratigraphy and structure of the Strawberry Mine roof pendant, central Sierra Nevada, California

USGS Publications Warehouse

Nokleberg, W.J.

1981-01-01

The Strawberry mine roof pendant, 90 km northeast of Fresno, Calif., is composed of a sequence of metasedimentary rocks of probable Early Jurassic age and a sequence of metaigneous rocks of middle Cretaceous age. The metasedimentary rocks are a former miogeosynclinal sequence of marl and limestone now metamorphosed to calc-silicate hornfels and marble. A pelecypod found in the calc-silicate hornfels has been tentatively identified as a Mesozoic bivalve, possibly Inoceramus pseudomytiloides of Early Jurassic age. These metasedimentary rocks are similar in lithology, structure, and gross age to the metasedimentary rocks of the Boyden Cave roof pendant and are assigned to the Lower Jurassic Kings sequence. The younger metaigneous rocks are metamorphosed shallow-in trusi ve rocks that range in composi tion from granodiorite to rhyolite. These rocks are similar in composition and age to the metavolcanic rocks of the surrounding Merced Peak quadrangle and nearby Ritter Range, and probably represent necks or dikes that were one source for the meta volcanic rocks. The roof pendant is intruded by several plutons, ranging in composition from dioritic to highly felsic, that constitute part of the granodiorite of Jackass Lakes, also M middle Cretaceous age. The contemporaneous suites of metaigneous, metavolcanic, and plutonic rocks in the region represent a middle Cretaceous period of calc-alkalic volcanism and plutonism in the central Sierra Nevada and are interpreted as part of an Andean-type volcanic-plutonic arc. Three deformations are documented in the roof pendant. The first deformation is reflected only in the metasedimentary rocks and consists of northeast-to east-west-trending folds. Similar structures occur in the Boyden Cave roof pendant and in the Calaveras Formation and represent a Middle Jurassic regional deformation. Evidence of the second deformation occurs in the metasedimentary and metaigneous rocks and consists of folds, faults, minor structures, and regional metamorphism along N. 25? W. trends. Crosscutting of these structures by the contemporaneous granodiorite of Jackass Lakes indicates that this deformation occurred simultaneously with volcanism and plutonism during the middle Cretaceous. The third deformation involved both the roof pendant and adjacent plutonic rocks and consists of folds, faults, schistosities, and regional metamorphism along N. 65? -900 W. trends. Crosscutting of similar structures in other middle Cretaceous plutonic rocks of the Merced Peak quadrangle by undeformed late Cretaceous plutonic rocks indicates a regional deformation of middle to late Cretaceous age. Structures of similar style, orientation, and age occur elsewhere in metavolcanic and plutonic rocks throughout the central Sierra Nevada.

Magnetic mineralogy and rock magnetic properties of silicate and carbonatite rocks from Oldoinyo Lengai volcano (Tanzania)

NASA Astrophysics Data System (ADS)

Mattsson, H. B.; Balashova, A.; Almqvist, B. S. G.; Bosshard-Stadlin, S. A.; Weidendorfer, D.

2018-06-01

Oldoinyo Lengai, a stratovolcano in northern Tanzania, is most famous for being the only currently active carbonatite volcano on Earth. The bulk of the volcanic edifice is dominated by eruptive products produced by silica-undersaturated, peralkaline, silicate magmas (effusive, explosive and/or as cumulates at depth). The recent (2007-2008) explosive eruption produced the first ever recorded pyroclastic flows at this volcano and the accidental lithics incorporated into the pyroclastic flows represent a broad variety of different rock types, comprising both extrusive and intrusive varieties, in addition to various types of cumulates. This mix of different accidental lithics provides a unique insight into the inner workings of the world's only active carbonatite volcano. Here, we focus on the magnetic mineralogy and the rock magnetic properties of a wide selection of samples spanning the spectrum of Oldoinyo Lengai rock types compositionally, as well from a textural point of view. Here we show that the magnetic properties of most extrusive silicate rocks are dominated by magnetite-ulvöspinel solid solutions, and that pyrrhotite plays a larger role in the magnetic properties of the intrusive silicate rocks. The natrocarbonatitic lavas, for which the volcano is best known for, show distinctly different magnetic properties in comparison with the silicate rocks. This discrepancy may be explained by abundant alabandite crystals/blebs in the groundmass of the natrocarbonatitic lavas. A detailed combination of petrological/mineralogical studies with geophysical investigations is an absolute necessity in order to understand, and to better constrain, the overall architecture and inner workings of the subvolcanic plumbing system. The results presented here may also have implications for the quest in order to explain the genesis of the uniquely natrocarbonatitic magmas characteristic of Oldoinyo Lengai.

Development of a Unified Rock Bolt Model in Discontinuous Deformation Analysis

NASA Astrophysics Data System (ADS)

He, L.; An, X. M.; Zhao, X. B.; Zhao, Z. Y.; Zhao, J.

2018-03-01

In this paper, a unified rock bolt model is proposed and incorporated into the two-dimensional discontinuous deformation analysis. In the model, the bolt shank is discretized into a finite number of (modified) Euler-Bernoulli beam elements with the degrees of freedom represented at the end nodes, while the face plate is treated as solid blocks. The rock mass and the bolt shank deform independently, but interact with each other through a few anchored points. The interactions between the rock mass and the face plate are handled via general contact algorithm. Different types of rock bolts (e.g., Expansion Shell, fully grouted rebar, Split Set, cone bolt, Roofex, Garford and D-bolt) can be realized by specifying the corresponding constitutive model for the tangential behavior of the anchored points. Four failure modes, namely tensile failure and shear failure of the bolt shank, debonding along the bolt/rock interface and loss of the face plate, are available in the analysis procedure. The performance of a typical conventional rock bolt (fully grouted rebar) and a typical energy-absorbing rock bolt (D-bolt) under the scenarios of suspending loosened blocks and rock dilation is investigated using the proposed model. The reliability of the proposed model is verified by comparing the simulation results with theoretical predictions and experimental observations. The proposed model could be used to reveal the mechanism of each type of rock bolt in realistic scenarios and to provide a numerical way for presenting the detailed profile about the behavior of bolts, in particular at intermediate loading stages.

The Žermanice sill: new insights into the mineralogy, petrology, age, and origin of the teschenite association rocks in the Western Carpathians, Czech Republic

NASA Astrophysics Data System (ADS)

Matýsek, Dalibor; Jirásek, Jakub; Skupien, Petr; Thomson, Stuart N.

2018-04-01

The Žermanice locality represents the best-exposed example of the meta-basaltoid/meta-gabbroic rock type of the teschenite association. It forms a subhorizontal volcanic body (sill) 27-30 m thick. The subvolcanic rock is inhomogeneous and slightly differentiated. The predominant rock type is a basaltoid (diabase-dolerite), medium-grained, speckled, mesocratic rock exhibiting an evident subophitic texture. Miarolitic cavities are abundant in some places. The major rock constituents are albite, microcline, chlorite, and pyroxene, as well as analcime and plagioclase in places. The accessory magmatic phases are biotite, ilmenite, fluorapatite, sulphides, Ti-rich magnetite, Nb-rich baddeleyite, and chevkinite-(Ce) or perrierite-(Ce). A large extent of alteration is evident from the presence of chloritization, albitization of plagioclases, and zeolitization (analcimization). Geochemical analyses reveal an affinity for metaluminous igneous rocks. The best fit is with the within-plate basalts or the within-plate volcanic zones. The classification of this rock is problematic because of the mixed intrusive and extrusive features; the choice is between meta-alkali basalt and metadolerite (meta-microgabbro). 207Pb common lead-corrected U-Pb apatite dating yields a weighted mean age of 120.4 ± 9.6 Ma, which corresponds to the middle Aptian. The igneous body is at most ca. 10 Ma younger than the surrounding late Hauterivian sediments and might have been emplaced into unconsolidated or partly consolidated sediments. According to our research, it is evident that at least some teschenite association rocks are in fact low-grade metamorphic rocks.

Mapping Rock and Soil Units in the MPF IMP SuperPan Using a Kohonen Self Organizing Map

NASA Technical Reports Server (NTRS)

Farrand, W.; Merenyi, E.; Murchie, S.; Barnouin-Jha, O.; Johnson, J.

2004-01-01

The 1997 Mars Pathfinder mission provided information on a site in the Ares Vallis floodplain. Initial analysis of multispectral data from the Imager for Mars Pathfinder (IMP) indicated the presence of only a single rock type, the 'gray rock' spectral class and various coated variants thereof (e.g., 'maroon rock'). Continued analysis of the IMP 'SuperPan' mosaic has confirmed multiple examples of a second 'black rock' spectral class existing as small cobbles in the near field and as boulders in the far field. These results are consistent with recent analysis of MGS Thermal Emission Spectrometer (TES) data which indicates that there is likely a mix of both 'Surface Type 1' (ST1) and 'Surface Type 2' (ST2) spectral classes at the MPF landing site. Nominally, the black rock spectral class would correspond to ST1 (basalts) and 'gray rock' would correspond to ST2 (andesites). Orbital remote sensing has also revealed the pervasive presence of layering on Mars. Recently it was suggested that there are extensive outcrops of the black rock spectral class in the SuperPan far field on the flanks of the Twin Peaks and on the rim of Big Crater. These authors suggested that these exposures represented outcrops of black rock from beneath a surficial, flood deposited layer. In this work, we have reexamined the MPF IMP SuperPan mosaic using an artificial neural network self organizing map (SOM) processing architecture in order to classify the distribution of spectral classes within the SuperPan. In this paper, we present initial results from that work and draw specific attention to a subset of the identified spectral classes in order to address questions relating to whether there are extensive exposures of black rock in the IMP far field, what other materials might be exposed in the far field, and what evidence there is for subsurface layering at the MPF landing site.

Geochemistry of lunar crustal rocks from breccia 67016 and the composition of the moon

NASA Technical Reports Server (NTRS)

Norman, Marc D.; Taylor, Stuart R.

1992-01-01

The geochemistry of anorthositic clasts from an Apollo 16 breccia 67016 is studied in order to investigate the role of these rock types in lunar crustal evolution. The samples have aluminous, alkali-poor compositions and varied FeO and MgO contents. Three compositional groups are recognized. One group is poor in mafic constituents with low abundances of lithophile trace elements typical of lunar anorthosites, while the other two groups are more mafic and are distinguished from each other by FeO/MgO ratios greater than one in the case of ferroan noritic and less than one in the case of magnesian troctolitic. These mafic-enriched varieties have considerably higher lithophile element concentrations, at levels similar to that of the bulk lunar crust. The ferroan noritic clasts may represent a fundamental type of igneous rock in the lunar crust which has not been widely recognized.

Geochemical constraints on the petrogenesis of the pyroclastic rocks in Abakaliki basin (Lower Benue Rift), Southeastern Nigeria

NASA Astrophysics Data System (ADS)

Chukwu, Anthony; Obiora, Smart C.

2018-05-01

The pyroclastic rocks in the Cretaceous Abakaliki basin occur mostly as oval-shaped bodies, consisting of lithic/lava and vitric fragments. They are commonly characterized by parallel and cross laminations, as well contain xenoliths of shale, mudstone and siltstones from the older Asu River Group of Albian age. The rocks are basic to ultrabasic in composition, comprising altered alkali basalts, altered tuffs, minor lapillistones and agglomerates. The mineral compositions are characterized mainly by laths of calcic plagioclase, pyroxene (altered), altered olivines and opaques. Calcite, zeolite and quartz represent the secondary mineral constituents. Geochemically, two groups of volcaniclastic rocks, are distinguished: alkaline and tholeiitic rocks, both represented by fresh and altered rock samples. The older alkali basalts occur within the core of the Abakaliki anticlinorium while the younger tholeiites occur towards the periphery. Though most of the rocks are moderate to highly altered [Loss on ignition (LOI, 3.43-22.07 wt. %)], the use of immobile trace element such as Nb, Zr, Y, Hf, Ti, Ta and REEs reflect asthenospheric mantle source compositions. The rocks are enriched in incompatible elements and REEs (∑REE = 87.98-281.0 ppm for alkaline and 69.45-287.99 ppm for tholeiites). The ratios of La/Ybn are higher in the alkaline rocks ranging from 7.69 to 31.55 compared to the tholeiitic rocks which range from 4.4 to 16.89 and indicating the presence of garnet-bearing lherzolite in the source mantle. The spidergrams and REEs patterns along with Zr/Nb, Ba/Nb, Rb/Nb ratios suggest that the rocks were generated by a mantle plume from partial melting of mixed enriched mantle sources (HIMU, EMI and EMII) similar to the rocks of the south Atlantic Ocean such as St. Helena (alkaline rocks) and Ascension rocks (tholeiitic rocks). The rocks were formed in a within-plate setting of the intra-continental rift type similar to other igneous rocks in the Benue Rift and are not related to any subduction event as previously suggested.

ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

2002-11-18

During the seven quarter of the project the research team analyzed some of the acoustic velocity data and rock deformation data. The goal is to create a series of ''deformation-velocity maps'' which can outline the types of rock deformational mechanisms which can occur at high pressures and then associate those with specific compressional or shear wave velocity signatures. During this quarter, we began to analyze both the acoustical and deformational properties of the various rock types. Some of the preliminary velocity data from the Danian chalk will be presented in this report. This rock type was selected for the initialmore » efforts as it will be used in the tomographic imaging study outlined in Task 10. This is one of the more important rock types in the study as the Danian chalk is thought to represent an excellent analog to the Ekofisk chalk that has caused so many problems in the North Sea. Some of the preliminary acoustic velocity data obtained during this phase of the project indicates that during pore collapse and compaction of this chalk, the acoustic velocities can change by as much as 200 m/s. Theoretically, this significant velocity change should be detectable during repeated successive 3-D seismic images. In addition, research continues with an analysis of the unconsolidated sand samples at high confining pressures obtained in Task 9. The analysis of the results indicate that sands with 10% volume of fines can undergo liquefaction at lower stress conditions than sand samples which do not have fines added. This liquefaction and/or sand flow is similar to ''shallow water'' flows observed during drilling in the offshore Gulf of Mexico.« less

Sudbury project (University of Muenster-Ontario Geological Survey): New investigations on Sudbury breccia

NASA Astrophysics Data System (ADS)

Mueller-Mohr, V.

Sudbury breccias occur as discordant dike breccias within the footwall rocks of the Sudbury structure, which is regarded as the possible remnant of a multiring basin. Exposures of Sudbury breccias in the North Range are known up to a radial distance of 60-80 km from the Sudbury Igneous Complex (SIC). The breccias appear more frequent within a zone of 10 km adjacent to the SIC and a further zone located about 20-33 km north of the structure. From differences in the structure of the breccias, as for example the size of the breccia dikes, contact relationships between breccia and country rock as well as between different breccia dikes, fragment content, and fabric of the ground mass, as seen in this section, the Sudbury Breccias have been classified into four different types. (1) Early breccias with a clastic/crystalline matrix comprise small dikes ranging in size from approx. 1 cm to max. 20 cm. (2) Polymict breccias with a clastic matrix represent the most common type of Sudbury breccia. The thickness of the dikes varies from several tens of centimeters to a few meters but can also extend to more than 100 m in the case of the largest known breccia dike. Contacts with country rock are sharp or gradational. Heterogenous matrix consisting of a fine-grained rock flour displays nonoriented textures as well as extreme flow lines. Chemical analysis substantiates at least some mixing with allochthonous material. (3) Breccias with a crystalline matrix are a subordinate type of Sudbury breccia. According to petrographical and chemical differences, three subtypes have been separated. (4) Late breccias with a clastic matrix are believed to represent the latest phase of brecciation. Two subtypes have been distinguished due to differences in the fragment content.

Sudbury project (University of Muenster-Ontario Geological Survey): New investigations on Sudbury breccia

NASA Technical Reports Server (NTRS)

Mueller-Mohr, V.

1992-01-01

Sudbury breccias occur as discordant dike breccias within the footwall rocks of the Sudbury structure, which is regarded as the possible remnant of a multiring basin. Exposures of Sudbury breccias in the North Range are known up to a radial distance of 60-80 km from the Sudbury Igneous Complex (SIC). The breccias appear more frequent within a zone of 10 km adjacent to the SIC and a further zone located about 20-33 km north of the structure. From differences in the structure of the breccias, as for example the size of the breccia dikes, contact relationships between breccia and country rock as well as between different breccia dikes, fragment content, and fabric of the ground mass, as seen in this section, the Sudbury Breccias have been classified into four different types. (1) Early breccias with a clastic/crystalline matrix comprise small dikes ranging in size from approx. 1 cm to max. 20 cm. (2) Polymict breccias with a clastic matrix represent the most common type of Sudbury breccia. The thickness of the dikes varies from several tens of centimeters to a few meters but can also extend to more than 100 m in the case of the largest known breccia dike. Contacts with country rock are sharp or gradational. Heterogenous matrix consisting of a fine-grained rock flour displays nonoriented textures as well as extreme flow lines. Chemical analysis substantiates at least some mixing with allochthonous material. (3) Breccias with a crystalline matrix are a subordinate type of Sudbury breccia. According to petrographical and chemical differences, three subtypes have been separated. (4) Late breccias with a clastic matrix are believed to represent the latest phase of brecciation. Two subtypes have been distinguished due to differences in the fragment content.

Late Cretaceous tectonothermal evolution of the southern Lhasa terrane, South Tibet: Consequence of a Mesozoic Andean-type orogeny

NASA Astrophysics Data System (ADS)

Dong, Xin; Zhang, Ze-ming; Klemd, Reiner; He, Zhen-yu; Tian, Zuo-lin

2018-04-01

The Lhasa terrane of the southern Tibetan Plateau participated in a Mesozoic Andean-type orogeny caused by the northward subduction of the Neo-Tethyan oceanic lithosphere. However, metamorphic rocks, which can unravel details of the geodynamic evolution, are rare and only exposed in the south-eastern part of the Lhasa terrane. Therefore, we conducted a detailed petrological, geochemical and U-Pb zircon geochronological study of the late Cretaceous metamorphic rocks and associated gabbros from the Nyemo inlier of the southern Lhasa terrane. The Nyemo metamorphic rocks including gneisses, schists, marbles and calc-silicate rocks, experienced peak amphibolite-facies contact metamorphism under P-T conditions of 3.5-4.0 kbar and 642-657 °C with a very high geothermal gradient of 45-50 °C/km, revealing a distinct deflection from the steady-state geotherm during low-pressure metamorphism. Inherited magmatic zircon cores from the metamorphic rocks yielded protolith ages of 197-194 Ma, while overgrowth zircon rims yielded metamorphic ages of ca. 86 Ma. Whole-rock chemistry and zircon Hf isotopes suggest that the protoliths of the gneisses and schists are andesites and tuffs of the early Jurassic Sangri Group, which were derived from a depleted mantle source of a continental arc affinity. The coeval intimately-associated gabbro (ca. 86 Ma) crystallized under P-T conditions of 3.5-5.3 kbar and 914-970 °C, supplying the heat flux high enough to cause the contact metamorphism of the Sangri Group rock types. We propose that the intrusion of the gabbro and a simultaneous pressure increase of up to 4.0 kbar, which is related to crustal thickening due to crustal overthrusting and the intrusion of mafic material, resulted in the late Cretaceous metamorphism of the early Jurassic Sangri Group during an Andean-type orogeny. Furthermore the Nyemo metamorphic rocks, which have previously been considered to represent slivers of the Precambrian metamorphic basement of the Lhasa terrane, are late Cretaceous metamorphic supracrustal rocks.

Geochemistry and tectonic setting of the Golabad granitoid complex (SW Nain, Iran)

NASA Astrophysics Data System (ADS)

Mansouri Esfahani, Mahin; Khalili, Mahmoud; Alaminia, Zahra

2018-03-01

The Oligo-Miocene Golabad granitoid complex intrusive into the Eocene volcanic rocks occurs in the Urumieh-Dokhtar Magmatic Arc (UDMA) in Iran. According to microscopic and chemical studies, the granitoid complex consists of three different rock types: 1) plutonic rocks comprising diorite, quartz diorite, granodiorite and granite; 2) volcanic rocks composed of basalt, andesite basalt, ± pyroxene bearing andesite and rhyolite, and 3) pyroclastic rocks. The main mineral constituents of these rocks are mostly plagioclase (oligoclase and andesine), quartz, K-feldspar, amphibole (magnesio-hornblende and actinolite-hornblende) and Mg-biotite. In addition, apatite, titanite, zircon, and opaque minerals are common accessory minerals. The studied enclaves are classified as mafic micro-granular enclaves (MME) with monzodiorite compositions. Geochemically, the rocks in this study represent medium to high-K calc-alkaline series, metaluminous and I-type nature. Plotting, the chemical composition of plagioclase on the An-Ab-Or ternary diagram, the temperature of crystallization is estimated to range from 700 to 900 °C at a pressure of 4.5 Kbar. High TiO2 values of biotites from the Golabad granitoid complex suggest magmatic origin and the crystallization temperature is estimated to range from 700 to 750 °C. The amphiboles according to their chemical analysis, are classified as igneous amphiboles generated in high oxygen fugacity conditions. The chemical data of the amphiboles and biotites pointed out to the I- type nature of the Golabad granitoid complex emplaced in an active continental margin subduction setting. The amphibole crystallization pressure was estimated by Al in amphibole varies from 1.09 to 2.28 Kbar. Using the calculated pressure the depth of the formation of the Golabad granitoid complex estimated from 4 to 9 Km.

Contributions to the gold metallogeny of northern Nevada

USGS Publications Warehouse

Tosdal, Richard M.

1998-01-01

Nevada is one of the Earth's premier gold producing regions, accounting for approximately 64 percent of the U.S and nine percent of the world total. The impact of these mines on nearby local economies and on our national balance of payments is profound, and will continue well into the next century. Of principal importance in this region are giant sedimentary-rock-hosted (Carlin-type) deposits. These are some of the world's largest deposits, but yet are poorly understood. Other sedimentary-rock hosted deposits in the region, the distal-disseminated Ag-Au type, are genetically related to shallow plutonic complexes. Hot-spring gold-silver systems associated with Tertiary volcanic rocks represent a third type of precious metal deposit in northern Nevada. These deposits, despite being generally smaller than sedimentary-rock-hosted gold deposits, are also important gold-silver resources. Aspects about the geologic and metallogenic setting of gold-silver deposits in northern Nevada are addressed in the twenty-two chapters that compose this volume. The volume is organized along four themes: (1) crustal structure; (2) Carlin-type deposits; (3) pluton-related gold-silver deposits near Battle Mountain; and (4) hot-spring gold-silver deposits. This Open-File Report, the result of ongoing geologic and mineral-resource investigations, provides a basis for mineral exploration, for land-use planning decisions, and for environmental questions in northern Nevada.

The Usability of Rock-Like Materials for Numerical Studies on Rocks

NASA Astrophysics Data System (ADS)

Zengin, Enes; Abiddin Erguler, Zeynal

2017-04-01

The approaches of synthetic rock material and mass are widely used by many researchers for understanding the failure behavior of different rocks. In order to model the failure behavior of rock material, researchers take advantageous of different techniques and software. But, the majority of all these instruments are based on distinct element method (DEM). For modeling the failure behavior of rocks, and so to create a fundamental synthetic rock material model, it is required to perform related laboratory experiments for providing strength parameters. In modelling studies, model calibration processes are performed by using parameters of intact rocks such as porosity, grain size, modulus of elasticity and Poisson ratio. In some cases, it can be difficult or even impossible to acquire representative rock samples for laboratory experiments from heavily jointed rock masses and vuggy rocks. Considering this limitation, in this study, it was aimed to investigate the applicability of rock-like material (e.g. concrete) to understand and model the failure behavior of rock materials having complex inherent structures. For this purpose, concrete samples having a mixture of %65 cement dust and %35 water were utilized. Accordingly, intact concrete samples representing rocks were prepared in laboratory conditions and their physical properties such as porosity, pore size and density etc. were determined. In addition, to acquire the mechanical parameters of concrete samples, uniaxial compressive strength (UCS) tests were also performed by simultaneously measuring strain during testing. The measured physical and mechanical properties of these extracted concrete samples were used to create synthetic material and then uniaxial compressive tests were modeled and performed by using two dimensional discontinuum program known as Particle Flow Code (PFC2D). After modeling studies in PFC2D, approximately similar failure mechanism and testing results were achieved from both experimental and artificial simulations. The results obtained from these laboratory tests and modelling studies were compared with the other researcher's studies in respect to failure mechanism of different type of rocks. It can be concluded that there is similar failure mechanism between concrete and rock materials. Therefore, the results obtained from concrete samples that would be prepared at different porosity and pore sizes can be used in future studies in selection micro-mechanical and physical properties to constitute synthetic rock materials for understanding failure mechanism of rocks having complex inherent structures such as vuggy rocks or heavily jointed rock masses.

From vein precipitates to deformation and fluid rock interaction within a SSZ: Insights from the Izu-Bonin-Mariana fore arc

NASA Astrophysics Data System (ADS)

Micheuz, Peter; Quandt, Dennis; Kurz, Walter

2017-04-01

International Ocean Discovery Program (IODP) expeditions 352 and 351 drilled through oceanic crust of the Philippine Sea plate. The two study areas are located near the outer Izu-Bonin-Mariana (IBM) fore arc and in the Amami Sankaku Basin. The primary objective was to improve our understanding of supra-subduction zones (SSZ) and the process of subduction initiation. The recovered drill cores during IODP expedition 352 represent approximately 50 Ma old fore arc basalts (FAB) and boninites revealing an entire volcanic sequence of a SSZ. Expedition 351 drilled FAB like oceanic crust similar in age to the FABs of expedition 352. In this study we present data on vein microstructures, geochemical data and isotopic signatures of vein precipitates to give new insights into fluid flow and precipitation processes and deformation within the Izu-Bonin fore arc. Veins formed predominantly as a consequence of hydrofracturing resulting in the occurrence of branched vein systems and brecciated samples. Along these hydrofractures the amount of altered host rock fragments varies and locally alters the host rock completely to zeolites and carbonates. Subordinately extensional veins released after the formation of the host rocks. Cross-cutting relationships of different vein types point to multiple fracturing events subsequently filled with minerals originating from a fluid with isotopic seawater signature. Based on vein precipitates, their morphology and their growth patterns four vein types have been defined. Major vein components are (Mg-) calcite and various zeolites determined by Raman spectra and electron microprobe analyses. Zeolites result from alteration of volcanic glass during interaction with a seawaterlike fluid. Type I veins which are characterized by micritic infill represent neptunian dykes. They predominantly occur in the upper levels of drill cores being the result of an initial volume change subsequently to crystallization of the host rocks. Type II veins are characterized by blocky carbonates and idiomorphic to blocky zeolites. Blocky carbonates locally exhibit zonation patterns. Type III and type IV veins are both assumed to be extensional veins. Type III is characterized by syntaxial growth and elongate blocky carbonate minerals. They predominantly occur as asymmetric syntaxial veins, locally exhibiting more than one crack-seal event. Type IV veins are defined as antitaxial fibrous carbonates. Type II veins commonly show deformation microstructures like twinning (type I/II twins), slightly curved twins, and subgrain boundaries indicative of incipient plastic deformation. Based on these observations differential stresses around 50 MPa were needed to deform vein minerals, presumably related to IBM fore arc extension due to the retreat of the subducted Pacific plate. We acknowledge financial support by the Austrian Research Fund (P27982-N29) to W. Kurz

Constraining mechanisms of quartz precipitation in the Archean ocean using silicon isotopes

NASA Astrophysics Data System (ADS)

Brengman, L. A.; Fedo, C.; Martin, W.

2017-12-01

To constrain reservoir values for the Archean silica cycle we measured silicon isotope compositions (δ30Si) of 28 igneous, siliciclastic sedimentary, hydrothermal, and chemical sedimentary rock samples from three Archean greenstone belts representing different times (>3.7 - 2.7 Ga) and tectonic regimes. We posit that silicon isotope compositions of quartz (746 analyses measured in situ by secondary ion mass spectrometry at the NORDSIM facility) are linked to changes in key geochemical parameters that vary within local depositional environments, coupled with a dependency on size and δ30Si composition of the source reservoir. Collectively, siliceous precipitates from even a single basin span a 7‰ range in δ30Si values. Such heterogeneity, regardless of basinal position or presence of Fe-phases demonstrates that δ30Si values of chemical sediments are linked to neither a well-mixed water column representative of a single ocean composition, nor a specific time in Earth history. Combining data from all three greenstone belts we discern that all measured Algoma-type iron formation (IF) and about 50% of associated chert samples possess δ30Si values <0‰, while the majority of silicified volcanic rocks and the remaining 50% of chert samples have δ30Si values >0‰. Negative values of Algoma-type IF can be explained by rate-dependent fractionation during precipitation and/or adsorption to Fe/Al. Combined experimental and natural data for quartz precipitates suggest slow precipitation rates coupled with closed system, Rayleigh type distillation could produce the isotopically heavy values. Such results suggest the quartz-precipitating fluid for these rocks evolves from an open system in disequilibrium, to one that is closed, and in equilibrium with the host rock. In contrast to the static range of values through time for Algoma-type IF, associated cherts and silicified rocks, compiled data for Superior-type IF from 3 - 1.8 Ga record a systematic increasing trend from dominantly 30Si-depleted to 30Si-enriched values over the Archean-Paleoproterozoic transition. Interpreted in the context of our provisional, mass-balance based flux model for the Precambrian silicon cycle, we conclude the 30Si-enrichment to reflect the evolving δ30Si composition of the ocean due to the addition of continentally derived silica.

Lithium isotopes as indicators of meteorite parent body alteration

NASA Astrophysics Data System (ADS)

Sephton, Mark A.; James, Rachael H.; Fehr, Manuela A.; Bland, Philip A.; Gounelle, Matthieu

2013-05-01

Hydrothermal processing on planetesimals in the early solar system produced new mineral phases, including those generated by the transformation of anhydrous silicates into their hydrated counterparts. Carbonaceous chondrites represent tangible remnants of such alteration products. Lithium isotopes are known to be responsive to aqueous alteration, yet previously recognized variability within whole rock samples from the same meteorite appears to complicate the use of these isotopes as indicators of processing by water. We demonstrate a new way to use lithium isotopes that reflects aqueous alteration in carbonaceous chondrites. Temperature appears to exert a control on the production of acetic acid-soluble phases, such as carbonates and poorly crystalline Fe-oxyhydroxides. Temperature and degree of water-rock interaction determines the amount of lithium isotope fractionation expressed as the difference between whole rock and acetic acid-leachable fractions. Using these features, the type 1 chondrite Orgueil (δ7Li(whole rock) = 4.3‰; Δ7Li(acetic-whole) = 1.2‰) can be distinguished from the type 2 chondrites Murchison (δ7Li(whole rock) = 3.8; Δ7Li(acetic-whole) = 8.8‰) and carbonate-poor Tagish Lake (δ7Li(whole rock) = 4.3; Δ7Li(acetic-whole) = 9.4‰). This initial study suggests that lithium isotopes have the potential to reveal the role of liquid water in the early solar system.

Integration of rock physical signatures with depositional environments: A case study from East Coast of India

NASA Astrophysics Data System (ADS)

Mondal, Samit; Yadav, Ashok; Chatterjee, Rima

2018-01-01

Rock physical crossplots from different geological setup along eastern continental margin of India (ECMI) represent diversified signatures. To characterize the reservoirs in rock physics domain (velocity/modulus versus porosity) and then connecting the interpretation with geological model has been the objectives of the present study. Petrophysical logs (total porosity and volume of shale) from five wells located at sedimentary basins of ECMI have been analyzed to quantify the types of shale such as: laminated, dispersed and structural in reservoir. Presence of various shale types belonging to different depositional environments is coupled to define distinct rock physical crossplot trends for different geological setup. Wells from three different basins in East Coast of India have been used to capture diversity in depositional environments. Contact model theory has been applied to the crossplot to examine the change in rock velocity with change in reservoir properties like porosity and volume of shale. The depositional and diagenetic trends have been shown in the crossplot to showcase the prime controlling factor which reduces the reservoir porosity. Apart from that, the effect of geological factors like effective stress, sorting, packing, grain size uniformity on reservoir properties have also been focused. The rock physical signatures for distinct depositional environments, effect of crucial geological factors on crossplot trends coupled with established sedimentological models in drilled area are investigated to reduce the uncertainties in reservoir characterization for undrilled potentials.

Representative Bulk Composition of Oil Types for the 2002 U.S. Geological Survey Resource Assessment of National Petroleum Reserve in Alaska

USGS Publications Warehouse

Lillis, Paul G.

2004-01-01

Bulk oil composition is an important economic consideration of a petroleum resource assessment. Geological and geochemical interpretations from previous North Slope studies combined with recently acquired geochemical data are used to predict representative oil gravity (?API) and sulfur content (wt.% S) of the oil types for the 2002 U.S. Geological Survey resource assessment of the National Petroleum Reserve of Alaska (NPRA). The oil types are named after their respective source rock units and include Kuna-Lisburne, Shublik-Otuk, Kingak-Blankenship, and Pebble-GRZ-Torok. The composition of the oil (24?API, 1.6 wt.% S) in the South Barrow 12 well was selected as representative of Kuna-Lisburne oil. The average gravity and sulfur values (23?API and 1.6 wt.% S, respectively) of the Kuparuk field were selected to be representative of Shublik-Otuk oil type. The composition of the oil (39?API, 0.3 wt.% S) from the Alpine field discovery well (ARCO Bergschrund 1) was selected to be representative of Kingak-Blankenship oil. The oil composition (37?API, 0.1 wt.% S) of Tarn field was considered representative of the Pebble-GRZ-Torok oil type in NPRA.

Experimental Studies on Permeability of Intact and Singly Jointed Meta-Sedimentary Rocks Under Confining Pressure

NASA Astrophysics Data System (ADS)

Wong, Louis Ngai Yuen; Li, Diyuan; Liu, Gang

2013-01-01

Three different types of permeability tests were conducted on 23 intact and singly jointed rock specimens, which were cored from rock blocks collected from a rock cavern under construction in Singapore. The studied rock types belong to inter-bedded meta-sandstone and meta-siltstone with very low porosity and high uniaxial compressive strength. The transient pulse water flow method was employed to measure the permeability of intact meta-sandstone under a confining pressure up to 30 MPa. It showed that the magnitude order of meta-sandstone's intrinsic permeability is about 10-18 m2. The steady-state gas flow method was used to measure the permeability of both intact meta-siltstone and meta-sandstone in a triaxial cell under different confining pressures spanning from 2.5 to 10 MPa. The measured permeability of both rock types ranged from 10-21 to 10-20 m2. The influence of a single natural joint on the permeability of both rock types was studied by using the steady-state water flow method under different confining pressures spanning from 1.25 to 5.0 MPa, including loading and unloading phases. The measured permeability of both jointed rocks ranged from 10-13 to 10-11 m2, where the permeability of jointed meta-siltstone was usually slightly lower than that of jointed meta-sandstone. The permeability of jointed rocks decreases with increasing confining pressure, which can be well fitted by an empirical power law relationship between the permeability and confining pressure or effective pressure. The permeability of partly open cracked specimens is lower than that of open cracked specimens, but it is higher than that of the specimen with a dominant vein for the meta-sandstone under the same confining pressure. The permeability of open cracked rock specimens will partially recover during the unloading confining pressure process. The equivalent crack (joint) aperture is as narrow as a magnitude order of 10-6 m (1 μm) in the rock specimens under confining pressures spanning from 1.25 to 5.0 MPa, which represent the typical ground stress conditions in the cavern. The in situ hydraulic conductivity measurements conducted in six boreholes by the injection test showed that the in situ permeability of rock mass varies between 10-18 and 10-11 m2. The lower bound of the in situ permeability is larger than that of the present laboratory-tested intact rock specimens, while the upper bound of the in situ permeability is less than that of the present laboratory-tested jointed rock specimens. The in situ permeability test results were thus compatible with our present laboratory permeability results of both intact and jointed rock specimens.

Metabasalts from the Mid-Atlantic Ridge: new insights into hydrothermal systems in slow-spreading crust

NASA Astrophysics Data System (ADS)

Gillis, Kathryn M.; Thompson, Geoffrey

1993-12-01

An extensive suite of hydrothermally altered rocks were recovered by Alvin and dredging along the MARK [Mid-Atlantic Ridge, south of the Kane Fracture Zone (23 24°N)] where detachment faulting has provided a window into the crustal component of hydrothermal systems. Rocks of basaltic composition are altered to two assemblages with these characteristics: (i) type I: albitic plagioclase (An02 10)+mixed-layer smectite/chlorite or chlorite±actinolite±quartz±sphene, <10% of the clinopyroxene is altered, and there is no trace metal mobility; (ii) type II: plagioclase (An10 30)+amphibole (actinolite-magnesio-hornblende) +chlorite+sphene, >20% of the clinopyroxene is altered, and Cu and Zn are leached. The geochemical signature of these alteration types reflects the relative proportion and composition of secondary minerals, and the degree of alteration of primary phases, and does not show simple predictive relationships. Element mobilities indicate that both alteration types formed at low water/rock ratios. The MARK assemblages are typical of the greenschist and transition to the amphibolite facies, and represent two distinct, albeit overlapping, temperature regimes: type I-180 to 300°C and type II-250 to 450°C. By analogy with DSDP/ODP Hole 504B and many ophiolites, the MARK metabasalts were altered within the downwelling limb of a hydrothermal cell and type I and II samples formed in the upper and lower portions of the sheeted like complex, respectively. Episodic magmatic and hydrothermal events at slow-spreading ridges suggest that these observed mineral assemblages represent the cumulative effects of more than one hydrothermal event. Groundmass and vein assemblages in the MARK metabasalts indicate either that alteration conditions did not change during successive hydrothermal events or that these assemblages record only the highest temperature event. Lack of retrograde reactions or overprinting of lower temperature assemblages (e.g., zeolites) suggests that there is a continuum in alteration conditions while crustal segments remain in the ridge axis environment. The type II samples may be representative of the reaction zone where compositions of hydrothermal fluids actively venting at the seafloor today become fixed. This prediction necessitates interaction between hydrothermal fluids and intersertal glass and/or mafic phases, in addition to plagioclase, in order to produce the observed range in vented fluid pH.

Performance Evaluation Test of the Orbit Screen Model 68A and the Komplet Model 48-25 Rock Crusher

DTIC Science & Technology

2008-08-01

two representatives from the Government of Ecuador, Ms . Viviana Anabela Meza Cevallos, from the Demining Center of Ecuador, and Lieutenant Jose Luis...Mines ( MRMs ) Antipersonnel Simulants............................ 8 4 Orbit Screen Model 68 Testing...Mock Mine .............................................................................................................. 7 Figure 8: MRM Simulant, Type

The Widespread Distribution of Komatiitic Tuffs in the 3.3 Ga Weltevreden Formation, Barberton Greenstone Belt, South Africa

NASA Astrophysics Data System (ADS)

Thompson, M. E.; Lowe, D. R.; Byerly, G. R.

2007-12-01

The 3.5-3.2 Ga Barberton greenstone belt is a heavily deformed, 10-15 km thick succession of volcanic and sedimentary rocks representing one of the best preserved Paleoarchean supracrustal sequences known. It consists of the basal volcanic-dominated Onverwacht Group and the overlying sedimentary-dominated Fig Tree and Moodies Groups. Major volcanic rocks in the BGB include komatiites, tholeiitic basalts, and dacites. Although flow rocks and fragmental deposits have been identified representing all extrusive magma types, the abundance of komatiitic volcaniclastic units is remarkable considering the mechanical difficulties in explosively erupting low viscosity ultramafic lava. In the Onverwacht Group, most komatiitic tuffs contain 85-95 wt% SiO2, due to early silicification, and very low concentrations of most other elements, making original compositions somewhat uncertain. However, in the northernmost part of the BGB, north of the Inyoka Fault, the ~ 3.3 Ga Weltevreden Formation is composed largely of komatiitic flow rocks, tuffs, layered ultramafic complexes, and subordinate black and banded cherts. Previous studies have established the extrusive nature of the komatiites, but there are also many thick interlayered slaty units, previously interpreted as sheared flow rocks, which show cross-bedding, soft-sediment deformation, and other features indicating an alternate derivation. These units range from 2 to 80 m thick and may represent 10% or more of the overall stratigraphy of the Weltevreden Formation. They are characterized by low-temperature serpentinization that has commonly preserved original elemental abundances, enabling a more precise determination of primary komatiitic liquid composition. These rocks are magnesium rich, with MgO ranging from 23 to 36 wt%, and high Ni (~1500 ppm) and Cr (~2600 ppm) contents typical of komatiites. Several possible mechanisms could have produced these rocks, including (1) erosion and transport of pre-existing komatiitic flow rock, (2) volcanic base surges, (3) current reworking of fall-deposited pyroclastic material, and (4) remobilization of hyaloclastitic debris. The abundance of fine-grained sediments and of flat- and cross-laminated beds, the paucity of cr-spinels, and komatiitic immobile element ratios suggest that most of these high-Mg beds formed by minor reworking of komatiitic pyroclastic ash in a subaqueous environment.

The effect of organic acids on wettability of sandstone and carbonate rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mwangi, Paulina; Brady, Patrick V.; Radonjic, Mileva

This paper examines the role of crude oil’s organic acid surface active compounds (SAC) in determining the reservoir wettability over a range of salinities and temperatures. To isolate the effects of individual SACs, this project used model oil mixtures of pure decane and single SACs to represent the oleic phase. Due to the large number of experiments in this study, we used wettability measurement method by the modified flotation technique (MFT) to produce fast, reliable, and quantitative results. The results showed that oil wetting by decane increased with temperature for carbonate rocks. Sandstones oil wetting showed little temperature dependency. Themore » presence of long-chained acids in decane increased oil wetting in sandstone and carbonate rocks as salinity was lowered, while the short-chained acid increased water wetting under the same conditions. The effect of organic acids on wettability was slightly enhanced with increasing temperature for all rock types.« less

The effect of organic acids on wettability of sandstone and carbonate rocks

DOE PAGES

Mwangi, Paulina; Brady, Patrick V.; Radonjic, Mileva; ...

2018-02-21

This paper examines the role of crude oil’s organic acid surface active compounds (SAC) in determining the reservoir wettability over a range of salinities and temperatures. To isolate the effects of individual SACs, this project used model oil mixtures of pure decane and single SACs to represent the oleic phase. Due to the large number of experiments in this study, we used wettability measurement method by the modified flotation technique (MFT) to produce fast, reliable, and quantitative results. The results showed that oil wetting by decane increased with temperature for carbonate rocks. Sandstones oil wetting showed little temperature dependency. Themore » presence of long-chained acids in decane increased oil wetting in sandstone and carbonate rocks as salinity was lowered, while the short-chained acid increased water wetting under the same conditions. The effect of organic acids on wettability was slightly enhanced with increasing temperature for all rock types.« less

Differences in dissolved organic matter lability between alpine glaciers and alpine rock glaciers of the American West

NASA Astrophysics Data System (ADS)

Hall, E.; Fegel, T. S., II; Baron, J.; Boot, C. M.

2015-12-01

While alpine glaciers in montane regions represent the largest flux of dissolved organic matter (DOM) from global ice melt no research has examined the bioavailability of DOM melted out of glacial ice in the western continental United States. Furthermore, rock glaciers are an order of magnitude more abundant than ice glaciers in U.S., yet are not included in budgets for perennial ice carbon stores. Our research aims to understand differences in the bioavailability of carbon from ice glaciers and rock glaciers along the Central Rocky Mountains of Colorado. Identical microbial communities were fed standardized amounts of DOM from four different ice glacier-rock glaciers pairs. Using laboratory incubations, paired with mass spectrometry based metabolomics and 16S gene sequencing; we were able to examine functional definitions of DOM lability in glacial ice. We hypothesized that even though DOM quantities are similar in the outputs of both glacial types in our study area, ice glacial DOM would be more bioavailable than DOM from rock glaciers due to higher proportions of byproducts from microbial metabolism than rock glacier DOM, which has higher amounts of "recalcitrant" plant material. Our results show that DOM from ice glaciers is more labile than DOM from geologically and geographically similar paired rock glaciers. Ice glacier DOM represents an important pool of labile carbon to headwater ecosystems of the Rocky Mountains. Metabolomic analysis shows numerous compounds from varying metabolite pathways, including byproducts of nitrification before and after incubation, meaning that, similar to large maritime glaciers in Alaska and Europe, subglacial environments in the mountain ranges of the United States are hotspots for biological activity and processing of organic carbon.

Magnetic signatures of the orogenic crust of the Patagonian Andes with implication for planetary exploration

NASA Astrophysics Data System (ADS)

Díaz Michelena, Marina; Kilian, Rolf

2015-11-01

The Patagonian Andes represent a good scenario of study because they have outcrops of diverse plutonic rocks representative of an orogenic crust on Earth and other planets. Furthermore, metamorphic surface rocks provide a window into deeper crustal lithologies. In such remote areas, satellite and aerial magnetic surveys could provide important geological information concerning exposed and not exposed rocks, but they integrate the magnetic anomalies in areas of kilometres. For the southernmost Andes long wavelength satellite data show clear positive magnetic anomalies (>+100 nT) for the Patagonian Batholith (PB), similar as parts of the older martian crust. This integrated signal covers regions with different ages and cooling histories during magnetic reversals apart from the variability of the rocks. To investigate the complex interplay of distinct magnetic signatures at short scale, we have analysed local magnetic anomalies across this orogen at representative sites by decimeter-scale magnetic ground surveys. As expected, the investigated sites have positive and negative local anomalies. They are related to surface and subsurface rocks, and their different formation and alternation processes including geomagnetic inversions, distinct Curie depths of the magnetic carriers, intracrustal deformation among other factors. Whole rock chemistry (ranging from 45 to >80 wt.% SiO2 and from 1 to 18 wt.% FeOtot.), magnetic characteristics (susceptibilities, magnetic remanence and Königsberger ratios) as well as the composition and texture of the magnetic carriers have been investigated for representative rocks. Rocks of an ultramafic to granodioritic intrusive suite of the western and central PB contain titanomagnetite as major magnetic carrier. Individual magnetic signatures of these plutonic rocks reflect their single versus multidomain status, complex exolution processes with ilmenite lamella formations and the stoichiometric proportions of Cr, Fe and Ti in the oxides. At the eastern margin of the PB the investigated plutons and mafic dykes have been emplaced and equilibrated at 4-6 km depth. They do not contain magnetite but include variable amounts of ferrimagnetic monoclinic C4 pyrrhotite, which was formed along fractures zones by a hydrothermal gold-bearing mineralisation. The intensity of their positive magnetic anomalies (up to +220 nT) is well correlated with the amount of pyrrhotite (1-4 vol.%). In all cases, high resolution ground surveys variations of the magnetic signature down to 20 nT could be used to clearly distinguish different rock types on a decimeter scale. Vector magnetometer MOURA designed for martian exploration was successfully used for these surveys and provides results comparable to a commonly used caesium scalar magnetometer. This is important for near future ground surveys on Mars and the Moon.

Igneous stratigraphy and rock-types from a deep transect of the gabbroic lower crust of the Atlantis Bank core complex (SW Indian Ridge): preliminary results from IODP Expedition 360

NASA Astrophysics Data System (ADS)

Sanfilippo, A.; France, L.; Ghosh, B.; Liu, C. Z.; Morishita, T.; Natland, J. H.; Dick, H. J.; MacLeod, C. J.; Expedition 360 Scientists, I.

2016-12-01

International Ocean Discovery Program (IODP) Expedition 360 represents the first leg of a multi-phase drilling programme ('SloMo' project) aimed at investigating the nature of the lower crust and Moho at slow spreading ridges. As an initial phase of the SloMo project, IODP Exp. 360 intended to recover a representative transect of the lower oceanic crust formed at Atlantis Bank, an oceanic core complex on the SW Indian Ridge. During this expedition, 89 cores of gabbroic rocks were recovered at Hole U1473A, drilled to 789.7 m below seafloor. This hole was subsequently deepened to 809.4 mbsf during transit Expedition 362T, which recovered additional 7 cores. The gabbroic section recovered at Hole U1473A consists of several types of gabbro, diabase, and felsic veins. The main lithology is dominated by olivine gabbro (76.5% in abundance), followed by gabbro containing 1-2% oxide (9.5%), gabbro with >2% oxide (7.4%), gabbro sensu stricto (5.1%), felsic veins (1.5%) and diabase (<0.5%). The different lithologies appear randomly distributed throughout the section, although oxide abundance seems to decrease slightly downhole, except for the lowermost intervals where oxide gabbros are more abundant. Based on changes in rock types, grain size, texture, and the occurrence of felsic material, we identified eight lithologic units, which locally define separate geochemical trends. Each unit is characterized by meter-scale heterogeneity which classically characterizes gabbros formed at slow spreading ridges. Reaction textures in olivine gabbros, crosscutting relationships between oxide gabbros and host rocks, the presence of intrusive to sutured contacts, igneous layering and the widespread occurrence of felsic veins and segregations indicate that the evolution of this section was controlled by complicated interactions of magmatic processes, e.g., fractional crystallization, melt-rock reaction, late-stage melt migration, which were active in a crystal mush formed by multiple injections of magma. This contribution describes the main features of these rocks and discusses the complexity of the igneous processes producing this 800 m-long transect of oceanic crust that was formed in a robust magmatic segment of an ultraslow spreading ridge.

Generation of felsic rocks of bimodal volcanic suites from thinned and rifted continental margins: Geochemical and Nd, Sr, Pb-isotopic evidence from Haida Gwaii, British Columbia, Canada

NASA Astrophysics Data System (ADS)

Dostal, Jaroslav; Hamilton, Tark S.; Shellnutt, J. Gregory

2017-11-01

The compositionally bimodal volcanic rocks of the Eocene-Miocene Masset Formation from Queen Charlotte basin, Haida Gwaii, British Columbia, Canada, underlie an area greater than 5000 km2 where their exposed sections are up to 1.6 km thick. The suite of mafic and felsic rocks (dacites and rhyolites) that erupted closely spaced in time, in both submarine and subaerial conditions, was associated with significant crustal extension and thin continental crust ( 19-24 km thick), with volcanism persisting for 35 Ma (from 46 to 11 Ma). Predominant mafic types (mafic:felsic 2:1) are moderately enriched mid-ocean-ridge-like basalts that were derived by a partial melting of a heterogeneous spinel peridotite source. Felsic rocks are plagioclase-phyric, two pyroxene-bearing, mainly peraluminous types which have Nd, Pb and Sr isotopic compositions overlapping those of basalts including high positive ƐNd(t) values (up to >+6). The chondrite-normalized REE patterns show light REE enrichment but flat heavy REE along with a variable negative Eu anomaly. Mineralogy, major and trace elements, Nd-Sr-Pb isotopic data and model calculations using MELTS are consistent with a derivation of felsic rocks from the basalts by fractional crystallization. The intercalation of basaltic and felsic rocks suggests the existence of separate, simultaneously active plumbing and feeder systems and relatively stable magma chamber(s) to generate large volumes of differentiated felsic magmas by fractional crystallization. The Masset rocks provide an example for the generation of felsic magmas of bimodal volcanic suites during rifting along a thinned continental margin. Appendix 1b Representative analyses of minerals of the Masset Formation felsic rocks

Results from the Mars Pathfinder camera.

PubMed

Smith, P H; Bell, J F; Bridges, N T; Britt, D T; Gaddis, L; Greeley, R; Keller, H U; Herkenhoff, K E; Jaumann, R; Johnson, J R; Kirk, R L; Lemmon, M; Maki, J N; Malin, M C; Murchie, S L; Oberst, J; Parker, T J; Reid, R J; Sablotny, R; Soderblom, L A; Stoker, C; Sullivan, R; Thomas, N; Tomasko, M G; Wegryn, E

1997-12-05

Images of the martian surface returned by the Imager for Mars Pathfinder (IMP) show a complex surface of ridges and troughs covered by rocks that have been transported and modified by fluvial, aeolian, and impact processes. Analysis of the spectral signatures in the scene (at 440- to 1000-nanometer wavelength) reveal three types of rock and four classes of soil. Upward-looking IMP images of the predawn sky show thin, bluish clouds that probably represent water ice forming on local atmospheric haze (opacity approximately 0.5). Haze particles are about 1 micrometer in radius and the water vapor column abundance is about 10 precipitable micrometers.

GRANITE PEAK ROADLESS AREA, CALIFORNIA.

USGS Publications Warehouse

Huber, Donald F.; Thurber, Horace K.

1984-01-01

The Granite Peak Roadless Area occupies an area of about 5 sq mi in the southern part of the Trinity Alps of the Klamath Mountains, about 12 mi north-northeast of Weaverville, California. Rock and stream-sediment samples were analyzed. All streams draining the roadless area were sampled and representative samples of the rock types in the area were collected. Background values were established for each element and anomalous values were examined within their geologic settings and evaluated for their significance. On the basis of mineral surveys there seems little likelihood for the occurrence of mineral or energy resources.

Effect of Small Numbers of Test Results on Accuracy of Hoek-Brown Strength Parameter Estimations: A Statistical Simulation Study

NASA Astrophysics Data System (ADS)

Bozorgzadeh, Nezam; Yanagimura, Yoko; Harrison, John P.

2017-12-01

The Hoek-Brown empirical strength criterion for intact rock is widely used as the basis for estimating the strength of rock masses. Estimations of the intact rock H-B parameters, namely the empirical constant m and the uniaxial compressive strength σc, are commonly obtained by fitting the criterion to triaxial strength data sets of small sample size. This paper investigates how such small sample sizes affect the uncertainty associated with the H-B parameter estimations. We use Monte Carlo (MC) simulation to generate data sets of different sizes and different combinations of H-B parameters, and then investigate the uncertainty in H-B parameters estimated from these limited data sets. We show that the uncertainties depend not only on the level of variability but also on the particular combination of parameters being investigated. As particular combinations of H-B parameters can informally be considered to represent specific rock types, we discuss that as the minimum number of required samples depends on rock type it should correspond to some acceptable level of uncertainty in the estimations. Also, a comparison of the results from our analysis with actual rock strength data shows that the probability of obtaining reliable strength parameter estimations using small samples may be very low. We further discuss the impact of this on ongoing implementation of reliability-based design protocols and conclude with suggestions for improvements in this respect.

Geologic map of the Kechumstuk fault zone in the Mount Veta area, Fortymile mining district, east-central Alaska

USGS Publications Warehouse

Day, Warren C.; O’Neill, J. Michael; Dusel-Bacon, Cynthia; Aleinikoff, John N.; Siron, Christopher R.

2014-01-01

This map was developed by the U.S. Geological Survey Mineral Resources Program to depict the fundamental geologic features for the western part of the Fortymile mining district of east-central Alaska, and to delineate the location of known bedrock mineral prospects and their relationship to rock types and structural features. This geospatial map database presents a 1:63,360-scale geologic map for the Kechumstuk fault zone and surrounding area, which lies 55 km northwest of Chicken, Alaska. The Kechumstuk fault zone is a northeast-trending zone of faults that transects the crystalline basement rocks of the Yukon-Tanana Upland of the western part of the Fortymile mining district. The crystalline basement rocks include Paleozoic metasedimentary and metaigneous rocks as well as granitoid intrusions of Triassic, Jurassic, and Cretaceous age. The geologic units represented by polygons in this dataset are based on new geologic mapping and geochronological data coupled with an interpretation of regional and new geophysical data collected by the Alaska Department of Natural Resources, Division of Geological and Geophysical Surveys. The geochronological data are reported in the accompanying geologic map text and represent new U-Pb dates on zircons collected from the igneous and metaigneous units within the map area.

Geological evolution of the Iraqi Mesopotamia Foredeep, inner platform and near surroundings of the Arabian Plate

NASA Astrophysics Data System (ADS)

Sissakian, Varoujan K.

2013-08-01

The Iraqi territory could be divided into four main tectonic zones; each one has its own characteristics concerning type of the rocks, their age, thickness and structural evolution. These four zones are: (1) Inner Platform (stable shelf), (2) Outer Platform (unstable shelf), (3) Shalair Zone (Terrain), and (4) Zagros Suture Zone. The first two zones of the Arabian Plate lack any kind of metamorphism and volcanism. The Iraqi territory is located in the extreme northeastern part of the Arabian Plate, which is colliding with the Eurasian (Iranian) Plate. This collision has developed a foreland basin that includes: (1) Imbricate Zone, (2) High Folded Zone, (3) Low Folded Zone and (4) Mesopotamia Foredeep. The Mesopotamia Foredeep, in Iraq includes the Mesopotamia Plain and the Jazira Plain; it is less tectonically disturbed as compared to the Imbricate, High Folded and Low Folded Zones. Quaternary alluvial sediments of the Tigris and Euphrates Rivers and their tributaries as well as distributaries cover the central and southeastern parts of the Foredeep totally; it is called the Mesopotamian Flood Plain. The extension of the Mesopotamia Plain towards northwest however, is called the Jazira Plain, which is covered by Miocene rocks. The Mesopotamia Foredeep is represented by thick sedimentary sequence, which thickens northwestwards including synrift sediments; especially of Late Cretaceous age, whereas on surface the Quaternary sediments thicken southeastwards. The depth of the basement also changes from 8 km, in the west to 14 km, in the Iraqi-Iranian boarders towards southeast. The anticlinal structures have N-S trend, in the extreme southern part of the Mesopotamia Foredeep and extends northwards until the Latitude 32°N, within the Jazira Plain, there they change their trends to NW-SE, and then to E-W trend. The Mesozoic sequence is almost without any significant break, with increase in thickness from the west to the east, attaining 5 km. The sequence forms the main source and reservoir rocks in the central and southern parts of Iraq. The Cenozoic sequence consists of Paleogene open marine carbonates, which grades upwards into Neogene lagoonal marine; of Early Miocene and evaporitic rocks; of Middle Miocene age, followed by thick molasses of continental clastics that attain 3500 m in thickness; starting from Late Miocene. The Quaternary sediments are very well developed in the Mesopotamia Plain and they thicken southwards to reach about 180 m near Basra city; in the extreme southeastern part of Iraq. The Iraqi Inner Platform (stable shelf) is a part of the Arabian Plate, being less affected by tectonic disturbances; it covers the area due to south and west of the Euphrates River. The main tectonic feature in this zone that had affected on the geology of the area is the Rutbah Uplift; with less extent is the Ga'ara High. The oldest exposed rocks within the Inner Platform belong to Ga'ara Formation of Permian age; it is exposed only in the Ga'ara Depression. The Permian rocks are overlain by Late Triassic rocks; represented by Mulussa and Zor Hauran formations, both of marine carbonates with marl intercalations. The whole Triassic rocks are absent west, north and east of Ga'ara Depression. Jurassic rocks, represented by five sedimentary cycles, overlie the Triassic rocks. Each cycle consists of clastic rocks overlain by carbonates, being all of marine sediments; whereas the last one (Late Jurassic) consists of marine carbonates only. All the five formations are separated from each other by unconformable contacts. Cretaceous rocks, represented by seven sedimentary cycles, overlie the Jurassic rocks. Marine clastics overlain by marine carbonates. Followed upwards (Late Cretaceous) by continental clastics overlain by marine carbonates; then followed by marine carbonates with marl intercalations, and finally by marine clastics overlain by carbonates; representing the last three cycles, respectively. The Paleocene rocks form narrow belt west of the Ga'ara Depression, represented by Early-Late Paleocene phosphatic facies, which is well developed east of Rutbah Uplift and extends eastwards in the Foredeep. Eocene rocks; west of Rutbah Uplift are represented by marine carbonates that has wide aerial coverage in south Iraq. Locally, east of Rutbah Uplift unconformable contacts are recorded between Early, Middle and Late Eocene rocks. During Oligocene, in the eastern margin of the Inner Platform, the Outer Platform was uplifted causing very narrow depositional Oligocene basin. Therefore, very restricted exposures are present in the northern part of the Inner Platform (north of Ga'ara Depression), represented by reef, forereef sediments of some Oligocene formations. The Miocene rocks have no exposures west of Rutbah Uplift, but north and northwestwards are widely exposed represented by Early Miocene of marine carbonates with marl intercalations. Very locally, Early Miocene deltaic clastics and carbonates, are interfingering with the marine carbonates. The last marine open sea sediments, locally with reef, represent the Middle Miocene rocks and fore reef facies that interfingers with evaporates along the northern part of Abu Jir Fault Zone, which is believed to be the reason for the restriction of the closed lagoons; in the area. During Late Miocene, the continental phase started in Iraq due to the closure of the Neo-Tethys and collision of the Sanandaj Zone with the Arabian Plate. The continental sediments consist of fine clastics. The Late Miocene - Middle Pliocene sediments were not deposited in the Inner Platform. The Pliocene-Pleistocene sediments are represented by cyclic sediments of conglomeratic sandstone overlain by fresh water limestone, and by pebbly sandstone. The Quaternary sediments are poorly developed in the Inner Platform. Terraces of Euphrates River and those of main valleys represent pleistocene sediments. Flood plain of the Euphrates River and those of large valleys represent Holocene sediments. Residual soil is developed, widely in the western part of Iraq, within the western marginal part of the Inner Platform.

Estimating regional-scale permeability-depth relations in a fractured-rock terrain using groundwater-flow model calibration

NASA Astrophysics Data System (ADS)

Sanford, Ward E.

2017-03-01

The trend of decreasing permeability with depth was estimated in the fractured-rock terrain of the upper Potomac River basin in the eastern USA using model calibration on 200 water-level observations in wells and 12 base-flow observations in subwatersheds. Results indicate that permeability at the 1-10 km scale (for groundwater flowpaths) decreases by several orders of magnitude within the top 100 m of land surface. This depth range represents the transition from the weathered, fractured regolith into unweathered bedrock. This rate of decline is substantially greater than has been observed by previous investigators that have plotted in situ wellbore measurements versus depth. The difference is that regional water levels give information on kilometer-scale connectivity of the regolith and adjacent fracture networks, whereas in situ measurements give information on near-hole fractures and fracture networks. The approach taken was to calibrate model layer-to-layer ratios of hydraulic conductivity (LLKs) for each major rock type. Most rock types gave optimal LLK values of 40-60, where each layer was twice a thick as the one overlying it. Previous estimates of permeability with depth from deeper data showed less of a decline at <300 m than the regional modeling results. There was less certainty in the modeling results deeper than 200 m and for certain rock types where fewer water-level observations were available. The results have implications for improved understanding of watershed-scale groundwater flow and transport, such as for the timing of the migration of pollutants from the water table to streams.

An Experimental Study of Cutting Performances of Worn Picks

NASA Astrophysics Data System (ADS)

Dogruoz, Cihan; Bolukbasi, Naci; Rostami, Jamal; Acar, Cemil

2016-01-01

The best means to assess rock cuttability and efficiency of cutting process for using mechanical excavation is specific energy (SE), measured in full-scale rock cutting test. This is especially true for the application of roadheaders, often fitted with drag-type cutting tools. Radial picks or drag bits are changed during the operation as they reach a certain amount of wear and become blunt. In this study, full-scale cutting tests in different sedimentary rock types with bits having various degree of wear were used to evaluate the influence of bit wear on cutting forces and specific energy. The relationship between the amount of wear as represented by the size of the wear flats at the tip of the bit, and cutting forces as well as specific energy was examined. The influence of various rock properties such as mineral content, uniaxial compressive strength, tensile strength, indentation index, shore hardness, Schmidt hammer hardness, and density with required SE of cutting using different levels of tool wear was also studied. The preliminary analysis of the data shows that the mean cutting forces increase 2-3 times and SE by 4-5 times when cutting with 4 mm wear flat as compared to cutting with new or sharp wedge shape bits. The grain size distribution of the muck for cutting different rock types and different level of bit wear was analyzed and discussed. The best fit prediction models for SE based on statistical analysis of laboratory test results are introduced. The model can be used for estimating the performance of mechanical excavators using radial tools, especially roadheaders, continuous miners and longwall drum shearers.

Estimating regional-scale permeability–depth relations in a fractured-rock terrain using groundwater-flow model calibration

USGS Publications Warehouse

Sanford, Ward E.

2017-01-01

The trend of decreasing permeability with depth was estimated in the fractured-rock terrain of the upper Potomac River basin in the eastern USA using model calibration on 200 water-level observations in wells and 12 base-flow observations in subwatersheds. Results indicate that permeability at the 1–10 km scale (for groundwater flowpaths) decreases by several orders of magnitude within the top 100 m of land surface. This depth range represents the transition from the weathered, fractured regolith into unweathered bedrock. This rate of decline is substantially greater than has been observed by previous investigators that have plotted in situ wellbore measurements versus depth. The difference is that regional water levels give information on kilometer-scale connectivity of the regolith and adjacent fracture networks, whereas in situ measurements give information on near-hole fractures and fracture networks. The approach taken was to calibrate model layer-to-layer ratios of hydraulic conductivity (LLKs) for each major rock type. Most rock types gave optimal LLK values of 40–60, where each layer was twice a thick as the one overlying it. Previous estimates of permeability with depth from deeper data showed less of a decline at <300 m than the regional modeling results. There was less certainty in the modeling results deeper than 200 m and for certain rock types where fewer water-level observations were available. The results have implications for improved understanding of watershed-scale groundwater flow and transport, such as for the timing of the migration of pollutants from the water table to streams.

A new species of Leptodactylus Fitzinger (Anura, Leptodactylidae, Leptodactylinae) from montane rock fields of the Chapada Diamantina, northeastern Brazil.

PubMed

De Carvalho, Thiago Ribeiro; Leite Felife Sa Fortes; Pezzuti, Tiago Leite

2013-01-01

In this paper, we describe a new species of the Leptodactylusfuscus group on the basis of adult morphology and advertisement call, occurring restricted to montane rock fields of the Chapada Diamantina, northern portion of the Espinhaço Range, central State of Bahia, northeastern Brazil. In addition, we re-describe the advertisement call ofL. camaquara from its type locality. Leptodactylus oreomantis sp. nov. represents the first species of the genus occurring restricted to montane rock fields of the Chapada Diamantina, northeastern Brazil, whereas the other three species of the L. fuscus group assumed to be restricted to montane field environments (L. camaquara, L. cunicularius, and L. tapiti) occur in association with mountain ranges of southeastern or central Brazil.

Late Carboniferous to Early Permian magmatic pulses in the Uliastai continental margin linked to slab rollback: Implications for evolution of the Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Chai, Hui; Wang, Qingfei; Tao, Jixiong; Santosh, M.; Ma, Tengfei; Zhao, Rui

2018-05-01

The Paleo Asian Ocean underwent a protracted closure history during Late Paleozoic. Here we investigate the magmatic evolution during this process based on a detailed study in the Baiyinwula region along the Uliastai continental margin. The major rock types in this area are Late Carboniferous-Early Permian volcanic sequences and coeval intrusions. We identified four stages of magmatic evolution based on the diverse assemblages and their precise isotopic ages. The first stage is represented by andesites with a zircon 206Pb/238U age of ca. 326 ± 12 Ma. These rocks are metaluminous to weakly peraluminous, high-K calc-alkaline, and possess high Na2O/K2O ratios in the range of 1.23 to 2.45. They also display enrichment of large ion lithophile elements (LILE) and depletion of high field strength elements (HFSE), with markedly positive zircon εHf (t) varying from 8.1 to 15.6.The geochemical features of these andesites are similar to those of typical arc volcanic rocks. The second stage includes granodiorites emplaced at 318.6 + 1.8 Ma. The rocks are high-K calc-alkaline with A/CNK values ranging from 0.95 to 1.06, and show enrichment in LILE and depletion in HFSE. They show geochemical affinities to adakites, with high Sr and low Y and Yb contents, indicating magma derivation from thickened lower crust. Zircon grains from these rocks display positive initial εHf (t) values ranging from 11.1 to 14.6 with corresponding two-stage Hf model ages (TDM2) of 394-622 Ma. The third stage consists of syenogranite together with a volcanic suite ranging in composition from rhyolite todacite, which formed during 303.4 ± 1.2 to 285.1 ± 2.2 Ma. They possess elevated silica and alkali contents, high FeOt/MgO and Ga/Al ratios, low Al2O3, MgO and CaO contents, and high Rb, Y, Nb, Ce, Zr, Y, and Ga contents, strong negative Ba, Sr and Eu anomalies, showing I- to A-type granitic affinities. Zircons in these rocks show elevated Hf isotopic compositions (εHf (t) = 9.9 to 14.6) with TDM2 varying from 324 to 673 Ma. The fourth magmatic pulse is represented by K-feldspar granite with zircon U-Pb ages from 283.2 ± 1.9 Ma to 280.0 ± 1.4 Ma, and typical alkalic A-type granite geochemistry. These rocks possess positive εHf (t) values in the range of 9.7 to15.2, and a restricted range of Hf model age from 327 to 684 Ma. The magmatic rocks from the four stages show comparable εHf (t) and T2DM, suggesting that the magmas were derived from the same evolving mantle-derived source. We propose a tectonic model linking the evolution of the magmatism with the closure of the Paleo Asian Ocean that involved the following stages. The andesites were formed during the initial oceanic subduction stage with magma sourced from the metasomatized lithospheric mantle. Stage 2 adakite-like rocks were derived from subduction-induced thickened crust. Subsequent slab rollback resulted in asthenospheric upwelling and melting of residual juvenile crust to generate the I- and A- type syenogranite, rhyolite and dacite suite, finally followed by the A-type K-feldspar granite.

A quantitative analysis of rock cliff erosion environments

NASA Astrophysics Data System (ADS)

Lim, M.; Rosser, N.; Petley, D. N.; Norman, E. C.; Barlow, J.

2009-12-01

The spatial patterns and temporal sequencing of failures from coastal rock cliffs are complex and typically generate weak correlations with environmental variables such as tidal inundation, wave energy, wind and rain. Consequently, understanding of rock cliff behaviour, its response to predicted changes in environmental forcing and, more specifically, the interaction between marine and climatic factors in influencing failure processes has remained limited. This work presents the results from the first attempt to characterise and quantify the conditions on coastal cliffs that lead to accelerated rates of material detachment. The rate of change in an 80 m high section of coastal rock cliffs has been surveyed annually with high-resolution terrestrial laser scanning (TLS). The rockfall data have been analysed according to a simplified source geology that exhibit distinct magnitude-frequency distributions relating to the dominance of particular failure types. An integrated network of sensors and instrumentation designed to reflect the lithological control on failure has been installed to examine both the distinction between prevailing conditions and those affecting the local cliff environment and the physical response of different rock types to micro-climatic processes. The monitoring system records near-surface rock strain, temperature, moisture and micro-seismic displacement in addition to air temperature, humidity, radiation, precipitation, water-level and three-dimensional wind characteristics. A characteristic environmental signal, unique to the cliff face material, has been identified that differs substantially from that experienced by the surrounding area; suggesting that established methods of meteorological and tidal data collection are insufficient and inappropriate to represent erosive processes. The interaction between thermo- and hydro-dynamics of the cliff environment and the physical response of the rock highlights the composite environmental effects acting on the rock mass and provides a new interpretation on the dominant controls on the behaviour of coastal rock cliffs that challenges the almost universal application of undercutting and cantilever collapse as the primary driver of rock cliff erosion.

Fluid inclusions in jadeitite and jadeite-rich rock from serpentinite mélanges in northern Hispaniola: Trapped ambient fluids in a cold subduction channel

NASA Astrophysics Data System (ADS)

Kawamoto, Tatsuhiko; Hertwig, Andreas; Schertl, Hans-Peter; Maresch, Walter V.

2018-05-01

Freezing-point depression was measured in aqueous fluid inclusions to determine salinities in six samples of jadeitite and jadeite-rich rock from the Jagua Clara serpentinite mélange of the Rio San Juan Complex, Dominican Republic. The mélange represents a fossil subduction-zone channel from a cold, mature subduction zone with a geothermal gradient of 6 °C/km. One hundred and twenty-five determinations of salinity in primary inclusions hosted in jadeite, quartz, apatite and lawsonite range between extremes of 1.2 and 8.7, but yield a well-defined mean of 4.5 ± 1.1 wt% (±1 s.d.) NaCl equiv, slightly higher than mean seawater (3.5 wt%). In one sample, eight additional fluid inclusions in quartz aligned along grain boundaries yield slightly lower values of 2.7 ± 1.3 wt% NaCl equiv. Homogenization temperatures were also measured for 47 fluid inclusions in two samples, but primary entrapment densities are not preserved. It is significant that the suite includes two types of samples: those precipitated directly from an aqueous fluid as well as examples of metasomatic replacement of a pre-existing magmatic rock. Nevertheless, the results indicate identical salinity for both types and suggest a much stronger genetic link between the two types of jadeitite and jadeite-rich rock than has previously been assumed. Based on the results of conductivity measurements in modern subduction zones, we envision a pervasive fluid in the subduction channel that evolved from salinity levels lower than those in sea-water up to the measured values due to on-going but largely completed serpentinization in the subduction channel. The present data represent a reference marker for the subduction channel of the Rio San Juan intra-oceanic subduction zone at 30-50 km depth and after 50-60 Myr of operation.

Nature and geodynamic setting of the protoliths of the UHP metamorphic Complex and migmatites in Bixiling area, the Dabie Orogen, China

NASA Astrophysics Data System (ADS)

Li, H.; Jahn, B.; Wang, D.; Yu, H.; Liu, Z.; Hou, G.

2013-12-01

As the largest coesite-bearing mafic-ultramafic body in the Dabie-Sulu orogen, the Bixiling Complex is composed of meta-ultramafic rocks, MgAl-rich eclogites and FeTi-rich eclogites. The FeTi-rich eclogites are further divided into low-Si-high-Fe type (Type I) and high-Si-low-Fe type (Type II) according to their mineral assemblages and bulk chemical composition. Field, petrographic, petrological and geochemical characteristics of these rocks, although suffered an ultra-high pressure metamorphism, still show a magmatic differentiation process among the protoliths of the meta-ultramafic rocks, MgAl-rich eclogites and Type I FeTi-rich eclogites. A small degree of lower crustal contamination occurred during their magma chamber process. Amphibolite is widespread in the periphery of the complex. Non-foliation and fine-grained texture are their obvious characteristics. Geochemical and isotopic affinities suggest that the amphibolites represent a product of complete retrogression from type II FeTi-rich eclogites. The UHP complex is enclosed in granitic gneisses, which variably include two-mica plagioclase gneiss, epidote two-mica plagioclase gneiss, or white-mica plagioclase gneiss. They all show TTG, especially trondjhemitic composition. A migmatite outcrop was found near the northeastern end of the complex. The migmatites consist of dark colored, non-foliated amphibolites and light-colored, fine-grained trondhjemitic gneisses. Field occurrences, microstructures observed under optical microscope and SEM, Sr-Nd isotopic data suggest an origin of partial melting. Chemical composition of two stages of amphiboles occurred in both the amphibolites and the trondhjemitic gneisses also imply a partial melting process occurred. Trace element, Sr-Nd isotope and SHRIMP zircon U-Pb dating of MgAl-rich eclogite, amphibolites and trondhjemite suggest that the migmatites represent a partial melting of crustal materials at about 780Ma, possibly accompanied by the coeval emplacement of a differentiated mafic intrusive body. These rocks were deeply subducted into a mantle depth during the Triassic continental collision between the Yangtze Craton and North China Craton, and thereafter were exhumed to the surface. Their residual geochemical characteristics and spatial / temporal relationship could impose constraints on the tectonic evolution of the Dabieshan UHP terrane.

Rock types of South Pole-Aitken basin and extent of basaltic volcanism

USGS Publications Warehouse

Pieters, C.M.; Head, J. W.; Gaddis, L.; Jolliff, B.; Duke, M.

2001-01-01

The enormous pre-Nectarian South Pole-Aitken (SPA) basin represents a geophysically and compositionally unique region on the Moon. We present and analyze the mineralogical diversity across this basin and discuss the implications for basin evolution. Rock types are derived from Clementine multispectral data based on diagnostic characteristics of ferrous absorptions in fresh materials. Individual areas are characterized as noritic (dominated by low-Ca pyroxene), gabbroic/basaltic (dominated by high-Ca pyroxene), feldspathic (<3-6% FeO), and olivine-gabbro (dominated by high-Ca pyroxene and olivine). The anorthositic crust has effectively been removed from the interior of the basin. The style of volcanism within the basin extends over several 100 Myr and includes mare basalt and pyroclastic deposits. Several areas of ancient (pre-Orientale) volcanism, or cryptomaria, have also been identified. The nonmare mafic lithology that occurs across the basin is shown to be noritic in composition and is pervasive laterally and vertically. We interpret this to represent impact melt/breccia deposits derived from the lower crust. A few localized areas are identified within the basin that contain more diverse lithologies (gabbro, olivine-gabbro), some of which may represent material from the deepest part of the lower crust and perhaps uppermost mantle involved in the SPA event. Copyright 2001 by the American Geophysical Union.

Multispectral Imaging from Mars PATHFINDER

NASA Technical Reports Server (NTRS)

Ferrand, William H.; Bell, James F., III; Johnson, Jeffrey R.; Bishop, Janice L.; Morris, Richard V.

2007-01-01

The Imager for Mars Pathfinder (IMP) was a mast-mounted instrument on the Mars Pathfinder lander which landed on Mars Ares Vallis floodplain on July 4, 1997. During the 83 sols of Mars Pathfinders landed operations, the IMP collected over 16,600 images. Multispectral images were collected using twelve narrowband filters at wavelengths between 400 and 1000 nm in the visible and near infrared (VNIR) range. The IMP provided VNIR spectra of the materials surrounding the lander including rocks, bright soils, dark soils, and atmospheric observations. During the primary mission, only a single primary rock spectral class, Gray Rock, was recognized; since then, Black Rock, has been identified. The Black Rock spectra have a stronger absorption at longer wavelengths than do Gray Rock spectra. A number of coated rocks have also been described, the Red and Maroon Rock classes, and perhaps indurated soils in the form of the Pink Rock class. A number of different soil types were also recognized with the primary ones being Bright Red Drift, Dark Soil, Brown Soil, and Disturbed Soil. Examination of spectral parameter plots indicated two trends which were interpreted as representing alteration products formed in at least two different environmental epochs of the Ares Vallis area. Subsequent analysis of the data and comparison with terrestrial analogs have supported the interpretation that the rock coatings provide evidence of earlier martian environments. However, the presence of relatively uncoated examples of the Gray and Black rock classes indicate that relatively unweathered materials can persist on the martian surface.

Prospecting for Diverse Igneous Rock Types on Mars: Pixl on "black Beauty" Nwa 7533

NASA Astrophysics Data System (ADS)

Liu, Y.; Flannery, D.; Allwood, A.; Thompson, D. R.; Hodyss, R. P.; Clark, B. C.; Elam, W. T.; Hurowitz, J.

2015-12-01

In order to understand the evolution of the Martian crust and mantle, we need to acquire and analyze samples of igneous rocks other than the basaltic and ultramafic lithologies represented by the majority of Martian meteorites. Recent results from the Curiosity Rover demonstrate that diverse rock types exist in some Martian sedimentary environments in the form of conglomerate components or float, some of which shed light on the nature of early Martian crust (e.g., Sautter et al., 2015). We are developing investigation strategies for the in-situ instruments that will be flown on the Mars 2020 rover. These instruments will be used to inform the sampling campaigns required for future sample return missions. To achieve this, we applied PIXL (Planetary Instrument for X-ray Lithochemistry), an instrument for the Mars 2020 rover mission, to the meteorite NWA 7533. This meteorite is a pairing of NWA 7034, known informally as "Black Beauty", a new type of Martian meteorite that is broadly similar to the average composition of the Martian crust. This type of meteorite is essentially a 'conglomerate', with many diverse rock types, including mafic, feldspathic, and exotic rock fragments such as feldspar-ilmenite-phosphate clasts, as observed using higher-spatial resolution and higher sensitivity laboratory instruments (e.g., Agee et al., 2013; Humayun et al., 2014; Santos et al., 2015). Using PIXL, we analyzed a mm-scale cut and polished surface and applied algorithms developed by the PIXL team to semi-autonomously define and group regions containing similar lithological components (Thompson et al., 2015). PIXL data rapidly reveal distinctive zircon-bearing lithologies and feldspar-ilmenite-phosphate clasts similar to the detailed petrographic and mineralogical observations. Results suggest that PIXL readily identifies lithologies with minerals and elements (e.g., Rb and Sr) that are important for geochronology studies.

Thermal Inertia of Rocks and Rock Populations and Implications for Landing Hazards on Mars

NASA Technical Reports Server (NTRS)

Golombek, M. P.; Jakosky, B. M.; Mellon, M. T.

2001-01-01

Rocks represent an obvious potential hazard to a landing spacecraft. They also represent an impediment to rover travel and objects of prime scientific interest. Although Mars Orbiter Camera (MOC) images are of high enough resolution to distinguish the largest rocks (an extremely small population several meters diameter or larger), traditionally the abundance and distribution of rocks on Mars have been inferred from thermal inertia and radar measurements, our meager ground truth sampling of landing sites, and terrestrial rock populations. In this abstract, we explore the effective thermal inertia of rocks and rock populations, interpret the results in terms of abundances and populations of potentially hazardous rocks, and conclude with interpretations of rock hazards on the Martian surface and in extremely high thermal inertia areas.

Surface Properties and Characteristics of Mars Landing Sites from Remote Sensing Data and Ground Truth

NASA Astrophysics Data System (ADS)

Golombek, M. P.; Haldemann, A. F.; Simpson, R. A.; Furgason, R. L.; Putzig, N. E.; Huertas, A.; Arvidson, R. E.; Heet, T.; Bell, J. F.; Mellon, M. T.; McEwen, A. S.

2008-12-01

Surface characteristics at the six sites where spacecraft have successfully landed on Mars can be related favorably to their signatures in remotely sensed data from orbit and from the Earth. Comparisons of the rock abundance, types and coverage of soils (and their physical properties), thermal inertia, albedo, and topographic slope all agree with orbital remote sensing estimates and show that the materials at the landing sites can be used as ground truth for the materials that make up most of the equatorial and mid- to moderately high-latitude regions of Mars. The six landing sites sample two of the three dominant global thermal inertia and albedo units that cover ~80% of the surface of Mars. The Viking, Spirit, Mars Pathfinder, and Phoenix landing sites are representative of the moderate to high thermal inertia and intermediate to high albedo unit that is dominated by crusty, cloddy, blocky or frozen soils (duricrust that may be layered) with various abundances of rocks and bright dust. The Opportunity landing site is representative of the moderate to high thermal inertia and low albedo surface unit that is relatively dust free and composed of dark eolian sand and/or increased abundance of rocks. Rock abundance derived from orbital thermal differencing techniques in the equatorial regions agrees with that determined from rock counts at the surface and varies from ~3-20% at the landing sites. The size-frequency distributions of rocks >1.5 m diameter fully resolvable in HiRISE images of the landing sites follow exponential models developed from lander measurements of smaller rocks and are continuous with these rock distributions indicating both are part of the same population. Interpretation of radar data confirms the presence of load bearing, relatively dense surfaces controlled by the soil type at the landing sites, regional rock populations from diffuse scattering similar to those observed directly at the sites, and root-mean-squared slopes that compare favorably with 100 m scale topographic slopes extrapolated from altimetry profiles and meter scale slopes from high-resolution stereo images. The third global unit has very low thermal inertia and very high albedo, indicating it is dominated by deposits of bright red atmospheric dust that may be neither load bearing nor trafficable. The landers have thus sampled the majority of likely safe and trafficable surfaces that cover most of Mars and show that remote sensing data can be used to infer the surface characteristics, slopes, and surface materials present at other locations.

The ancient lunar crust, Apollo 17 region

NASA Technical Reports Server (NTRS)

James, O. B.

1992-01-01

The Apollo 17 highland collection is dominated by fragment-laden melt rocks, generally thought to represent impact melt from the Serenitatis basin-forming impact. Fortunately for our understanding of the lunar crust, the melt rocks contain unmelted clasts of preexisting rocks. Similar ancient rocks are also found in the regolith; most are probably clasts eroded out of melt rocks. The ancient rocks can be divided into groups by age, composition, and history. Oldest are plutonic igneous rocks, representing the magmatic components of the ancient crust. The younger are granulitic breccias, which are thoroughly recrystallized rocks of diverse parentages. The youngest are KREEPy basalts and felsites, products of relatively evolved magmas. Some characteristics of each group are given.

The post-collisional late Variscan ferroan granites of southern Sardinia (Italy): Inferences for inhomogeneity of lower crust

NASA Astrophysics Data System (ADS)

Conte, Aida Maria; Cuccuru, Stefano; D'Antonio, Massimo; Naitza, Stefano; Oggiano, Giacomo; Secchi, Francesco; Casini, Leonardo; Cifelli, Francesca

2017-12-01

The post-collisional late Variscan magmatism of Sardinia-Corsica batholith attained a peak at about 290 Ma. In southern Sardinia, in the frontal part of the Variscan orogenic wedge, this magmatism is represented by three suites of granitoids, here defined as GS1, GS2 and GS3. GS1, GS2 and GS3 are slightly peraluminous and F-bearing granitoids; GS1 and GS3 granites show in addition a ferroan character, whereas GS2 rocks range from magnesian to ferroan, from granodiorites to leucogranites. From magnetic susceptibility data, GS1 and GS2 belong to the ilmenite series, whereas GS3 is a slightly oxidized rock-suite plotting on the ilmenite/magnetite series boundary. Each rock-suite shows distinctive characters, in terms of petrography, petrochemistry, rock associations, as well as metallogenic signature of the related fluids. The distinction among rock-suite types is made on the basis of both mafic and characteristic accessory minerals. Siderophyllitic dark mica as the only mafic phase, and accessory xenotime (Y) characterize the GS1 rocks; GS2 mineral associations include biotite ± hornblende + allanite + magnetite; GS3 rocks show an association of hastingsite + annite + allanite + magnetite. Chemical variations in the studied samples suggest different magmatic evolution of independent magmas. Pb, Sr and Nd isotopic data constrain the origin of magmas to lower crustal sources. Chemical composition of rocks and dark micas meet those of liquids experimentally obtained by low degrees of partial melting of different meta-igneous deep crustal sources, felsic for GS1 rock-types and more mafic for GS3 rock-types. GS1 intrusions show granophile-type (Sn-W-Mo) metallogenic signatures, very low magnetic susceptibility, and Nd model ages (referred to the Depleted Mantle - TDM) of 2.3 Ga, coherent with a possible derivation from an old (early Proterozoic-Neoarchean), reduced and weathered basement, tectonically buried under Variscan covers. A definite deep crustal inhomogeneity is mirrored by GS3 granites, whose compositional and isotopic features indicate a younger (Nd model age: 1.6 Ga) tonalitic amphibolite source. Overall, the peculiarities of the studied granitoids suggest further compositional differences in the deep crust between southern and northern portion of the Sardinia-Corsica Variscan transect. Late Variscan lithospheric delamination appears as the most reliable mechanism that may have determined the high thermal regime that triggered partial melting of the crust. The close field association, at 290 Ma, of tholeiitic dike swarms and ferroan granitoids, supports this inference.

Paleoproterozoic Keulik-Kenirim Ore-Bearing Gabbro-Peridotite Complex, Kola Region: A New Occurrence of Ferropicritic Magmatism

NASA Astrophysics Data System (ADS)

Smolkin, V. F.; Lokhov, K. I.; Skublov, S. G.; Sergeeva, L. Yu.; Lokhov, D. K.; Sergeev, S. A.

2018-03-01

Comprehensive research of ore-bearing differentiated intrusions of the Keulik-Kenirim structural unit, which represents a fragment of the Paleoproterozoic Pechenga-Varzuga Belt, has been carried out for the first time. The intrusions are subvolcanic by type and lenticular in shape, nearly conformable and steeply dipping. They are made up of peridotite, olivine and plagioclase pyroxenites, and gabbro metamorphosed under amphibolite facies conditions along with host basic volcanics. All intrusive rocks are enriched in TiO2 and FeO. Sulfide Cu-Ni mineralization is represented by disseminated, pocket, and stringer-disseminated types, which are clustered in the peridotitic zone as hanging units and bottom lodes. The Ni content in disseminated ore is estimated at 0.45-0.55 wt % and 1.15-3.32 wt % in ore pockets; the Cu grades are 0.17-0.20 and 0.46-5.65 wt %, respectively. To determine the age of intrusions and metamorphism of intrusive and volcanic rocks, various isotopic systems have been used: Sm-Nd (TIMS) in rock and U-Pb (SIMS SHRIMP) and Lu-Hf (LA-ICP-MS) in zircon. Conclusions on the origin of zircons are based on concentrations of trace elements including REE therein and Hf-Nd correlation in zircons and rocks. The U-Pb system of zircons reflects episodes of igneous rock formation (1982 ± 12 Ma) and their postmagmatic transformation (1938 ± 20 Ma). The last disturbance of the U-Pb isotopic system occurred 700 and 425 Ma. Xenogenic zircons dated from 3.17 to 2.65 Ga have been revealed in the studied samples. These zircons were captured by magma from the Archean basement during its ascent. The intrusions were emplaced synchronously with economic ore formation in the Pechenga ore field (1985 ± 10 Ma). The peak metamorphism of intrusive rocks under amphibolite facies conditions is recorded at 40 Ma later. The differentiated intrusions of the Keulik-Kenirim structural unit are close in their internal structure, mineralogy, and geochemistry, as well as in age and features of related Cu-Ni mineralization to ore-bearing intrusions of the Pechenga ore field, which are derivatives of ferropicritic (ferriferous) magmatism.

Fluid evolution of Au-Cu zones in Um Balad area, North Eastern Desert of Egypt: Implications from mineral chemistry and fluid inclusions

NASA Astrophysics Data System (ADS)

Abd El Monsef, Mohamed; Salem, Ibrahim; Slobodník, Marek; Ragab, Ahmed

2018-07-01

Scanning electron microscope (SEM), Electron microprobe (EMPA) and fluid inclusion studies of the ore body, as well as geochemical analyses of country rocks were performed to determine the nature and characteristics of the mineralizing fluid responsible for Au-Cu deposits in Um Balad area, Northern Eastern Desert of Egypt. The Um Balad Au-Cu deposits are confined to well developed-quartz veins and veinlets cutting through the hosting country rocks. Petrographic and geochemical investigations of the hosting rocks distinguished between two main rock units; 1) metagabbro-diorite rocks with tholeiitic nature derived in island arc/continental margin tectonic regime, and 2) granodiorite rocks formed from calc-alkaline magma in continental margin regime. Wallrock alterations are represented by propylitic and argillic types. The mineralized quartz veins are striking in NE-SW direction and dipping between (35°-45°) in SE direction, other mineralized mafic dykes enriched with auriferous quartz veinlets are trending NE-SW and dipping 70°/SE. The main ore minerals are represented by gold, chalcopyrite, pyrite, sphalerite, malachite, covellite and goethite. While, geffroyite, cuprite, chrysocolla, pseudomalachite, britholite, wolframite, scheelite, hematite and rutile are detected as minor constituents. Fluid inclusions microthermometry and isochore calculations combined with chlorite geothermometry revealed that the Um Balad deposits were formed at temperature ranging from 305 °C to 325 °C and pressure between (100-500 bar). The mineralization had been developed in the shallow levels, beneath the water table at depth of 350-1760 m, rather than common mesothermal vein-type deposits in Egypt. Magmatic water have been suggested as the main source for the mineralized fluid. The transportation of the gold metal seems to be happen as bisulfide complexes in moderately acidic environment. The deposition was resulted from combination of changes in physico-chemical parameters, temperature and pressure plus the instability of the reduced sulfur complexes. A contamination with metamorphic and/or meteoric water was also proposed that has strong influence during the depositional process.

Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.

The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of amore » ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.« less

Effect of heterogeneity and anisotropy related to the construction method on transfer processes in waste rock piles.

PubMed

Lahmira, Belkacem; Lefebvre, René; Aubertin, Michel; Bussière, Bruno

2016-01-01

Waste rock piles producing acid mine drainage (AMD) are partially saturated systems involving multiphase (gas and liquid) flow and coupled transfer processes. Their internal structure and heterogeneous properties are inherited from their wide-ranging material grain sizes, their modes of deposition, and the underlying topography. This paper aims at assessing the effect of physical heterogeneity and anisotropy of waste rock piles on the physical processes involved in the generation of AMD. Generic waste rock pile conditions were represented with the numerical simulator TOUGH AMD based on those found at the Doyon mine waste rock pile (Canada). Models included four randomly distributed material types (coarse, intermediate, fine and very fine-grained). The term "randomly" as used in this study means that the vertical profile and spatial distribution of materials in waste rock piles (internal structure) defy stratigraphy principles applicable to natural sediments (superposition and continuity). The materials have different permeability and capillary properties, covering the typical range of materials found in waste rock piles. Anisotropy with a larger horizontal than vertical permeability was used to represent the effect of pile construction by benches, while the construction by end-dumping was presumed to induce a higher vertical than horizontal permeability. Results show that infiltrated precipitation preferentially flows in fine-grained materials, which remain almost saturated, whereas gas flows preferentially through the most permeable coarse materials, which have higher volumetric gas saturation. Anisotropy, which depends on pile construction methods, often controls global gas flow paths. Construction by benches favours lateral air entry close to the pile slope, whereas end-dumping leads to air entry from the surface to the interior of the pile by secondary gas convection cells. These results can be useful to construct and rehabilitate waste rock piles to minimize AMD, while controlling gas flow and oxygen supply. Copyright © 2015 Elsevier B.V. All rights reserved.

Digital Rock Simulation of Flow in Carbonate Samples

NASA Astrophysics Data System (ADS)

Klemin, D.; Andersen, M.

2014-12-01

Reservoir engineering has becomes more complex to deal with current challenges, so core analysts must understand and model pore geometries and fluid behaviors at pores scales more rapidly and realistically. We introduce an industry-unique direct hydrodynamic pore flow simulator that operates on pore geometries from digital rock models obtained using microCT or 3D scanning electron microscope (SEM) images. The PVT and rheological models used in the simulator represent real reservoir fluids. Fluid-solid interactions are introduced using distributed micro-scale wetting properties. The simulator uses density functional approach applied for hydrodynamics of complex systems. This talk covers selected applications of the simulator. We performed microCT scanning of six different carbonate rock samples from homogeneous limestones to vuggy carbonates. From these, we constructed digital rock models representing pore geometries for the simulator. We simulated nonreactive tracer flow in all six digital models using a digital fluid description that included a passive tracer solution. During the simulation, we evaluated the composition of the effluent. Results of tracer flow simulations corresponded well with experimental data of nonreactive tracer floods for the same carbonate rock types. This simulation data of the non-reactive tracer flow can be used to calculate the volume of the rock accessible by the fluid, which can be further used to predict response of a porous medium to a reactive fluid. The described digital core analysis workflow provides a basis for a wide variety of activities, including input to design acidizing jobs and evaluating treatment efficiency and EOR economics. Digital rock multiphase flow simulations of a scanned carbonate rock evaluated the effect of wettability on flow properties. Various wetting properties were tested: slightly oil wet, slightly water wet, and water wet. Steady-state relative permeability simulations yielded curves for all three ranges of wetting properties. The wetting variation affected phase mobility and residual phase saturations for primary oil flood and floods with varying ratios of oil and water.

Petrology and geochemistry of komatiites and tholeiites from Gorgona Island, Colombia

NASA Astrophysics Data System (ADS)

Aitken, Bruce G.; Echeverría, Lina M.

1984-04-01

Komatiitic rocks from Gorgona Island, Colombia, in contrast to their Archaean counterparts, occur as rather structureless flows. In addition, textural and mineralogical features indicate that the Gorgona komatiites may have crystallized from superheated liquids. Komatiitic rocks have MgO contents which range from 24 to 11 wt.% and plot on well-defined olivine (Fo90) control lines. Calculations show that potential evolved liquids (MgO<11 wt%) will be SiO2-poor. Komatiites, in this case, cannot be regarded as parental to the associated tholeiitic basalt sequence. On the basis of REE concentrations and Sr, Nd isotopic compositions, the associated basalts are found to be of two types. One type (K-tholeiite) is characterized by noticeably fractionated REE patterns and relatively primitive isotopic compositions similar to those of the komatiites. K-tholeiites, together with komatiites, are regarded as comprising a distinctive komatiitic suite. REE patterns within this suite show progressive depletion in the LREE from K-tholeiites to komatiites, and represent increasingly higher degrees of melting of the same mantle source region. The other type (T-tholeiite), representative of the bulk of the exposed basalt sequence, has flat REE patterns and relatively evolved isotopic compositions. This tholeiitic suite is clearly genetically unrelated to the komatiitic suite.

An unconventional depiction of viewpoint in rock art.

PubMed

Pettigrew, Jack; Scott-Virtue, Lee

2015-01-01

Rock art in Africa sometimes takes advantage of three-dimensional features of the rock wall, such as fissures or protuberances, that can be incorporated into the artistic composition (Lewis-Williams, 2002). More commonly, rock artists choose uniform walls on which two-dimensional depictions may represent three-dimensional figures or objects. In this report we present such a two-dimensional depiction in rock art that we think reveals an intention by the artist to represent an unusual three-dimensional viewpoint, namely, with the two human figures facing into the rock wall, instead of the accustomed Western viewpoint facing out!

Stress-Induced Fracturing of Reservoir Rocks: Acoustic Monitoring and μCT Image Analysis

NASA Astrophysics Data System (ADS)

Pradhan, Srutarshi; Stroisz, Anna M.; Fjær, Erling; Stenebråten, Jørn F.; Lund, Hans K.; Sønstebø, Eyvind F.

2015-11-01

Stress-induced fracturing in reservoir rocks is an important issue for the petroleum industry. While productivity can be enhanced by a controlled fracturing operation, it can trigger borehole instability problems by reactivating existing fractures/faults in a reservoir. However, safe fracturing can improve the quality of operations during CO2 storage, geothermal installation and gas production at and from the reservoir rocks. Therefore, understanding the fracturing behavior of different types of reservoir rocks is a basic need for planning field operations toward these activities. In our study, stress-induced fracturing of rock samples has been monitored by acoustic emission (AE) and post-experiment computer tomography (CT) scans. We have used hollow cylinder cores of sandstones and chalks, which are representatives of reservoir rocks. The fracture-triggering stress has been measured for different rocks and compared with theoretical estimates. The population of AE events shows the location of main fracture arms which is in a good agreement with post-test CT image analysis, and the fracture patterns inside the samples are visualized through 3D image reconstructions. The amplitudes and energies of acoustic events clearly indicate initiation and propagation of the main fractures. Time evolution of the radial strain measured in the fracturing tests will later be compared to model predictions of fracture size.

Detection and mapping of hydrothermally altered rocks in the vicinity of the Comstock Lode, Virginia Range, Nevada, using enhanced Landsat images

USGS Publications Warehouse

Ashley, Roger P.; Goetz, A.F.H.; Rowan, L.C.; Abrams, M.J.

1979-01-01

The Virginia Range, immediately southeast of Reno, Nev., consists mainly of flows, breccias, and turfs of Miocene age. Most of these volcanic rocks are of intermediate composition; rhyodacite is the most common rock type. Basalt, rhyolite and rhyolite tuff, and tuffaceous sedimentary rocks of Miocene and Pliocene age also cover substantial areas in the range. Pre-Tertiary metasedimentary, metavolcanic, and granitic rocks are exposed in scattered inliers, mostly along the southern and eastern margins of the range. Several large areas and many small areas within the volcanic pile were subjected to hydrothermal alteration during and after the period of intermediate volcanic activity. Economic precious metal mineralization is spatially and temporally associated with the hydrothermal alteration in several areas. The most important deposit is the Comstock Lode, which produced 192 million troy ounces of silver and 8.3 million troy ounces of gold from epithermal veins (Bonham, 1969). The hydrothermally altered rocks include silicified, advanced argillic, montmorillonite-bearing argillic, and propylitic types. The first three types typically contain pyrite, and some propylitic rocks contain pyrite as well. Supergene oxidation of these pyritic rocks produces limonitic bleached rocks. The term 'limonite,' as used here, refers to any combination of the minerals hematite, goethite, and Jarosite. Where vegetation cover is sparse to moderate, these limonitic rocks are readily identified on Landsat images enhanced by the color-ratio composite technique developed by Rowan and others (1974), so the altered areas can be mapped. About 30 percent tree cover (here mainly pinyon pine) is sufficient to change the spectral signature of individual picture elements (pixels) enough so that limonitic materials can no longer be uniquely identified. As in all other areas where this technique has been applied, limonitic unaltered rocks with intermediate to high albedos have the same appearance on the color-ratio composite as limonitic altered rocks. This problem represents the most important limitation to the use of enhanced Landsat images for detection and mapping of hydrothermally altered rocks. Reflectance spectra of altered and unaltered rocks taken in the field in the Virginia Range show that most altered rocks have a conspicuous absorption band near 2.2 ?m produced by clay minerals or alunite, whereas unaltered rocks have no features in this spectral region. Thus spectral information for selected bands in the 1.1-2.5 ?m region may allow discrimination between limonitic altered and limonitic unaltered rocks (Rowan and others, 1977; Abrams and others, 1977; Rowan and Abrams, 1978). Another potential limitation is loss of spectral information on slopes with low effective sun angle. Although a minor problem in the Virginia Range, loss of information sufficient to preclude identification of limonitic altered rocks occurs with effective sun angle lower than 20-25 degrees. Thus, even at moderate latitudes substantial parts of areas with high topographic relief may be lost to observation.

Properties of carbonate rocks related to SO2 reactivity

USGS Publications Warehouse

Borgwardt, R.H.; Harvey, R.D.

1972-01-01

Petrographic examination and grain size-distribution measurements were made on 11 specimens representing a broad spectrum of limestones and dolomites. The SO2 reaction kinetics of calcines prepared from each rock type were determined at 980??C. Stones of various geological types yield calcines of distinctly different physical structures that show correspondingly large differences in both rate of reaction and capacity for SO2 sorption. Pore size and particle size together determine the extent to which the interiors of individual particles react. Particles smaller than 0.01 cm with pores larger than 0.1 ?? react throughout their internal pore structure at a rate directly proportional to the BET surface. The rate decays exponentially as sulfation proceeds until the pores are filled with reaction product. The ultimate capacity of small particles is determined by the pore volume available for product accumulation, which is generally equivalent to about 50% conversion of the CaO in limestones. Variations in effectiveness of carbonate rocks for flue gas desulfurization are explained by the physical properties of their calcines, which are related to the crystal structure of the original rock. The high reaction rates achieved in the limestone injection process apparently result from the large surface area existing for short periods immediately following the dissociation of CaCO3.

Géochimie et cadre géodynamique du volcanisme néoprotérozoïque terminal (vendien) du Haut Atlas occidental, Maroc(Geochemical features and tectonic setting of late Neoproterozoic Vendian volcanism in the western High Atlas, Morocco)

NASA Astrophysics Data System (ADS)

Jouhari, A.; El-Archi, A.; Aarab, M.; El-Attari, A.; Ennih, N.; Laduron, D.

2001-05-01

Late Neoproterozoic Vendian volcanic and volcaniclastic rocks are widely distributed in the western High Atlas. They are located north of the Tizi n'Test Fault, separating the West African Craton from a northerly adjacent craton. These volcanic rocks overlie a semipelitic formation, which represents the equivalent of the Tidilline and Anzi Formations of the Anti-Atlas. The geochemical characteristics of these volcanic rocks suggest a calc-alkaline active margine environment associated with the post Pan-African tectonics. They differ from those of the Anti-Atlas by their lower content of K 2O. The later rock type was generated by a melting process of the crust subducted beneath the northern craton. A carbonate-shale unit, which contains examples of interstratified calc-alkaline dacite, overlies the volcanic succession, demonstrating that the volcanic activity continued sporadically until Early Cambrian times.

Concentrations of radioactive elements in lunar materials

NASA Astrophysics Data System (ADS)

Korotev, Randy L.

1998-01-01

As an aid to interpreting data obtained remotely on the distribution of radioactive elements on the lunar surface, average concentrations of K, U, and Th as well as Al, Fe, and Ti in different types of lunar rocks and soils are tabulated. The U/Th ratio in representative samples of lunar rocks and regolith is constant at 0.27; K/Th ratios are more variable because K and Th are carried by different mineral phases. In nonmare regoliths at the Apollo sites, the main carriers of radioactive elements are mafic (i.e., 6-8 percent Fe) impact-melt breccias created at the time of basin formation and products derived therefrom.

A chilled margin of komatiite and Mg-rich basaltic andesite in the western Bushveld Complex, South Africa

NASA Astrophysics Data System (ADS)

Maier, W. D.; Barnes, S.-J.; Karykowski, B. T.

2016-06-01

A chill sequence at the base of the Lower Zone of the western Bushveld Complex at Union Section, South Africa, contains aphanitic Mg-rich basaltic andesite and spinifex-textured komatiite. The basaltic andesite has an average composition of 15.2 % MgO, 52.8 % SiO2, 1205 ppm Cr, and 361 ppm Ni, whereas the komatiite has 18.7 % MgO, 1515 ppm Cr, and 410 ppm Ni. Both rock types have very low concentrations of immobile incompatible elements (0.14-0.72 ppm Nb, 7-31 ppm Zr, 0.34-0.69 ppm Th, 0.23-0.27 wt% TiO2), but high PGE contents (19-23 ppb Pt, 15-16 ppb Pd) and Pt/Pd ratios (Pt/Pd 1.4). Strontium and S isotopes show enriched signatures relative to most other Lower Zone rocks. The rocks could represent a ~20 % partial melt of subcontinental lithospheric mantle. This would match the PGE content of the rocks. However, this model is inconsistent with the high SiO2, Fe, and Na2O contents and, in particular, the low K2O, Zr, Hf, Nb, Ta, Th, LREE, Rb, and Ba contents of the rocks. Alternatively, the chills could represent a komatiitic magma derived from the asthenosphere that underwent assimilation of the quartzitic floor accompanied by crystallization of olivine and chromite. This model is consistent with the lithophile elements and the elevated Sr and S isotopic signatures of the rocks. However, in order to account for the high Pt and Pd contents of the magma, the mantle must have been twice as rich in PGE as the current estimate for PUM, possibly due to a component of incompletely equilibrated late veneer.

Characterization of rock samples and mineralogical controls on leachates

USGS Publications Warehouse

Hammarstrom, Jane M.; Cravotta, Charles A.; Galeone, Daniel G.; Jackson, John C.; Dulong, Frank T.; Hornberger, Roger J.; Brady, Keith B.C.

2009-01-01

Rocks associated with coal beds typically include shale, sandstone, and (or) limestone. In addition to common rock-forming minerals, all of these rock types may contain sulfide and sulfate minerals, various carbonate minerals, and organic material. These different minerals have inherently different solubility characteristics, as well as different acid-generating or acid-neutralizing potentials. The abundance and composition of sulfur- and carbonate-bearing minerals are of particular interest in interpreting the leaching column data because (1) pyrite and carbonate minerals are the primary controls on the acid-base account of a sample, (2) these minerals incorporate trace metals that can be released during weathering, and (3) these minerals readily react during weathering due to mineral dissolution and oxidation of iron.Rock samples were collected by the Pennsylvania Department of Environmental Protection (PaDEP) from five different sites to assess the draft standardized leaching column method (ADTI-WP2) for the prediction of weathering rates and water quality at coal mines. Samples were sent to USGS laboratories for mineralogical characterization and to ActLabs for chemical analysis. The samples represent a variety of rock types (shales, sandstones, and coal refuse) that are typical of coal overburden in the eastern United States. These particular samples were chosen for testing the weathering protocols because they represent a range of geochemical and lithologic characteristics, sulfur contents, and acid-base accounting characteristics (Hornberger et al., 2003). The rocks contain variable amounts of pyrite and carbonate minerals and vary in texture.This chapter includes bulk rock chemical data and detailed mineralogical and textural data for unweathered starting materials used in the interlaboratory validation study, and for two samples used in the early phases of leaching column tests (Wadesville Sandstone, Leechburg Coal Refuse). We also characterize some of the post-weathering rock samples, report trace-element content in leachate, and discuss mineralogical controls on leachate quality based on data from one of the participating laboratories. Table 5.1 lists the samples described in this chapter, the sample numbers, and comments on the characteristics of each lithology. Sample locations are plotted in Figure 5.1. Chapters 2 and 3 describe the sample locations, sample preparation protocols, ABA characteristics, and rationale for selection of rock samples for testing. Microprobe data for pyrite and carbonate minerals are tabulated in Appendix 5.1. Leachate data, along with a series of graphs showing concentration and cumulative transport trends, for the laboratory data discussed in this chapter are included as Excel spreadsheets in Appendices 5.2 and 5.3. Leach column data for the interlaboratory study are evaluated and interpreted in Chapters 7 -11.

Mantle sources and origin of the Middle Paleoproterozoic Jatulian Large Igneous Province of the Fennoscandian shield: evidence from isotope geochemical data on the Kuetsjarvi volcanics, Kola Craton

NASA Astrophysics Data System (ADS)

Bogina, Maria; Zlobin, Valeriy; Chistyakov, Alexeii; Evgenii, Sharkov

2014-05-01

Paleoproterozoic is one of the most important stages in the Earth's evolution as marking a cardinal change in a style of tectonomagmatic processes at 2.2-2.0 Ga, which corresponds to the formation of the Jatulian Large Igneous Province at the Fennoscandian Shield. The fragment of this province is represented by the volcanics of the Kuetsjarvi Group in the Kola Craton. These rocks differ in the extremely wide rock diversity and prominent role of alkaline rocks, the extremely rare rocks in the Precambrian. The rocks of the group are subdivided into the alkaline and tholeiitic basaltic series. The tholeiites are highly fractionated (mg# 38) high-Ti rocks enriched in HFSE. The alkaline series show wider mg# variations (32-52), which is inconsistent with a single fractionation sequence of these series. All rocks have high HFSE, at extremely wide LILE variations. Tholeiites show moderate LREE fractionation pattern at practically flat HREE: La/YbN = 3.6-4.5; La/SmN = 2.2-2.4, Gd/YbN = 1.5-1.7 and slight Eu anomaly (Eu/Eu* = 0.80-0.85). The alkaline rocks display much more fractionated LREE and fractionated HREE (La/YbN = 43.9-5.8; La/SmN = 2.2-2.4, Gd/YbN = 2.04-3.92) patterns at Eu anomaly varying from 0.53 to 1. The spidergrams of both series reveal negative Nb and Sr anomalies at sign-variable Ti anomaly. The alkaline rocks are enriched relative to tholeiites in U, Th, and Nb. Examination of behavior of incompatible trace elements offers an opportunity to compare the conditions of generation of parental mantle magmas of the studied series. In particular, the tholeiitic basalts have higher Zr/Nb ratios than the alkaline rocks, which in combination with their lower La/Yb ratios indicates their formation under the higher melting degree of mantle source as compared to the alkaline rocks. Simultaneous increase in Ce/Y ratio in the alkaline rocks may indicate their formation at greater depths. Tholeiitic basalts have lower Nb/U ratio, which testifies some crustal contamination of the melts. In addition, they have low Ti/Y (323-449) ratios and high Lu/Hf (0.11-0.16), which is typical of the rocks formed by melting of spinel peridotites. The alkaline basalts were derived from a deeper garnet-bearing mantle source (Ti/Y = 640-1140, Lu/Hf = 0.03-0.05). Isotope-geochemical study showed that these rocks have very similar Nd isotope composition ((eNd (2200) = +1.5 in the alkaline basalt and +1.9 in the tholeiites). It was found that the studied alkaline rocks are similar in composition to the OIB-type Tristan da Kunha basalts, while tholeiites are closer to the high-Ti rocks of the Parana plateau, which experienced significant lithospheric contribution. Obtained data confirm the within-plate setting at the Jatulian stage of the Fennoscandian Shield. The Kutesjarvi Group consists of two rock types: OIB-type alkaline and E-MORB-type tholeiitic, which is typical of most Phanerozoic large igneous provinces. However, unlike the latters, the rocks of this area were too much tectonized and eroded to compile a systematic sequence. But, the Kuetsjarvi Group may be considered as the fragment of the oldest large igneous province.

Prioritizing Scientific Data for Transmission

NASA Technical Reports Server (NTRS)

Castano, Rebecca; Anderson, Robert; Estlin, Tara; DeCoste, Dennis; Gaines, Daniel; Mazzoni, Dominic; Fisher, Forest; Judd, Michele

2004-01-01

A software system has been developed for prioritizing newly acquired geological data onboard a planetary rover. The system has been designed to enable efficient use of limited communication resources by transmitting the data likely to have the most scientific value. This software operates onboard a rover by analyzing collected data, identifying potential scientific targets, and then using that information to prioritize data for transmission to Earth. Currently, the system is focused on the analysis of acquired images, although the general techniques are applicable to a wide range of data modalities. Image prioritization is performed using two main steps. In the first step, the software detects features of interest from each image. In its current application, the system is focused on visual properties of rocks. Thus, rocks are located in each image and rock properties, such as shape, texture, and albedo, are extracted from the identified rocks. In the second step, the features extracted from a group of images are used to prioritize the images using three different methods: (1) identification of key target signature (finding specific rock features the scientist has identified as important), (2) novelty detection (finding rocks we haven t seen before), and (3) representative rock sampling (finding the most average sample of each rock type). These methods use techniques such as K-means unsupervised clustering and a discrimination-based kernel classifier to rank images based on their interest level.

Estimation Criteria for Rock Brittleness Based on Energy Analysis During the Rupturing Process

NASA Astrophysics Data System (ADS)

Ai, Chi; Zhang, Jun; Li, Yu-wei; Zeng, Jia; Yang, Xin-liang; Wang, Ji-gang

2016-12-01

Brittleness is one of the most important mechanical properties of rock: it plays a significant role in evaluating the risk of rock bursts and in analysis of borehole-wall stability during shale gas development. Brittleness is also a critical parameter in the design of hydraulic fracturing. However, there is still no widely accepted definition of the concept of brittleness in rock mechanics. Although many criteria have been proposed to characterize rock brittleness, their applicability and reliability have yet to be verified. In this paper, the brittleness of rock under compression is defined as the ability of a rock to accumulate elastic energy during the pre-peak stage and to self-sustain fracture propagation in the post-peak stage. This ability is related to three types of energy: fracture energy, post-peak released energy and pre-peak dissipation energy. New brittleness evaluation indices B 1 and B 2 are proposed based on the stress-strain curve from the viewpoint of energy. The new indices can describe the entire transition of rock from absolute plasticity to absolute brittleness. In addition, the brittle characteristics reflected by other brittleness indices can be described, and the calculation results of B 1 and B 2 are continuous and monotonic. Triaxial compression tests on different types of rock were carried out under different confining pressures. Based on B 1 and B 2, the brittleness of different rocks shows different trends with rising confining pressure. The brittleness of red sandstone decreases with increasing confining pressure, whereas for black shale it initially increases and then decreases in a certain range of confining pressure. Granite displays a constant increasing trend. The brittleness anisotropy of black shale is discussed. The smaller the angle between the loading direction and the bedding plane, the greater the brittleness. The calculation B 1 and B 2 requires experimental data, and the values of these two indices represent only relative brittleness under certain conditions. In field operations, both the relative brittleness and the brittleness obtained from seismic data or mineral composition should be considered to gain a more comprehensive knowledge of the brittleness of rock material.

Some Cenozoic hydrocarbon basins on the continental shelf of Vietnam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dien, P.T.

1994-07-01

The formation of the East Vietnam Sea basins was related to different geodynamic processes. The pre-Oligocene basement consists of igneous, metamorphic, and metasediment complexes. The Cretaceous-Eocene basement formations are formed by convergence of continents after destruction of the Tethys Ocean. Many Jurassic-Eocene fractured magmatic highs of the Cuulong basin basement constitute important reservoirs that are producing good crude oil. The Paleocene-Eocene formations are characterized by intramountain metamolasses, sometimes interbedded volcanic rocks. Interior structures of the Tertiary basins connect with rifted branches of the widened East Vietnam Sea. Bacbo (Song Hong) basin is predominated by alluvial-rhythmic clastics in high-constructive deltas, whichmore » developed on the rifting and sagging structures of the continental branch. Petroleum plays are constituted from Type III source rocks, clastic reservoirs, and local caprocks. Cuulong basin represents sagging structures and is predominated by fine clastics, with tidal-lagoonal fine sandstone and shalestone in high-destructive deltas that are rich in Type II source rocks. The association of the pre-Cenozoic fractured basement reservoirs and the Oligocene-Miocene clastic reservoir sequences with the Oligocene source rocks and the good caprocks is frequently met in petroleum plays of this basin. Nan Conson basin was formed from complicated structures that are related to spreading of the oceanic branch. This basin is characterized by Oligocene epicontinental fine clastics and Miocene marine carbonates that are rich in Types I, II, and III organic matter. There are both pre-Cenozoic fractured basement reservoirs, Miocene buildup carbonate reservoir rocks and Oligocene-Miocene clastic reservoir sequences, in this basin. Pliocene-Quaternary sediments are sand and mud carbonates in the shelf facies of the East Vietnam Sea back-arc basin. Their great thickness provides good conditions for maturation and trapping.« less

Petrological processes in mantle plume heads: Evidence from study of mantle xenoliths in the late Cenozoic alkali Fe-Ti basalts in Western Syria

NASA Astrophysics Data System (ADS)

Sharkov, Evgenii

2015-04-01

It is consensus now that within-plate magmatism is considered with ascending of mantle plumes and adiabatic melting of their head. At the same time composition of the plumes' matter and conditions of its adiabatic melting are unclear yet. The major source of objective information about it can be mantle xenoliths in alkali basalts and basanites which represent fragments of material of the plume heads above magma-generation zone. They are not represent material in melting zone, however, carry important information about material of modern mantle plumes, its phase composition and components, involved in melting. Populations of mantle xenoliths in basalts are characterized by surprising sameness in the world and represented by two major types: (1) dominated rocks of ``green'' series, and (2) more rare rocks of ``black'' series, which formed veins in the ``green'' series matrix. It can evidence about common composition of plume material in global scale. In other words, the both series of xenoliths represent two types of material of thermochemical mantle plumes, ascended from core-mantle boundary (Maruyama, 1994; Dobretsov et al., 2001). The same types of xenoliths are found in basalts and basanites of Western Syria (Sharkov et al., 1996). Rocks of ``green'' series are represented by Sp peridotites with cataclastic and protogranular structures and vary in composition from dominated spinel lherzolites to spinel harzburgites and rare spinel pyroxenites (websterites). It is probably evidence about incomplete homogenizing of the plume head matter, where material, underwent by partial melting, adjoins with more fertile material. Such heterogeneity was survived due to quick cooling of upper rim of the plume head in contact with relatively cold lithosphere. Essential role among xenoliths of the ``black'' series play Al-Ti-augite and water-bearing phases like hornblende (kaersutute) and Ti-phlogopite. Rocks of this series are represented by wehrlite, clinopyroxenite, amphibole clinopyroxenite, hornbledite, etc. as well as megacrysts of Al-Ti-augite, kaersutite, ilmenite, sanidine, etc. Numerous vesicles often occurred in megacrysts, especially in kaersurtite. Sp peridotites of the matrix are sharply different on their geochemical features from the ``black series'' rocks (in this case, megacrysts of kaersutite) which are the most close to composition of xenoliths-bearing alkali basalts. From this follows that geochemistry of plume-related basalts was determined by mantle fluids which occurred in magma-generation zone. Very likely, that these fluids, enriched in Fe, Ti, LREE, alkalis, and incompatible elements, initially were parts of intergranular material of original mantle plume material and were released due to its decompression. Because their high mobility, the fluids percolated upwards and accumulated in the upper part of the mantle plume head, where promoted its melting by lowering of solidus of the matter. Excess of the fluids gathered beneath the cooled upper rim and penetrated in its rocks which led to appearance of centers of secondary melting (melt-pockets). Very likely, that these secondary melts formed rocks of the ``black series'' (Ismail et al., 2008;Ryabchkov et al., 2011; Ma et al., 2014). According to geobarometric estimations, Sp peridotite xenoliths from Syria derived from depths 24-42 km (0.8-1.4 GPa) under temperatures 896-980oC; formation of melt-pockets, enriched in volatiles, occurred at the depths 21-27 km (0.7-0.9 GPa) under 826-981oC (Sharkov et al., 1996; Ismail et al., 2008; Ma et al., 2014). From this follows that plumeheads reached depths approximately 21-30 km which is in agree with practically absence of lower-crustal xenoliths in the populations. One of the problems of plume-related magmatism is coexisting of alkali and tholeiitic basalts, which origin often considered with different PT conditions. However, these basalt not rarely interlayered, especially at low and middle levels of LIPs or in single volcanoes (Hawaii, Etna, etc.) which is not in a good agreement with such idea. We suggest that the situation can be more likely explained by nonuniform impregnation of peridotite matrix with fluid components which composition and/or quantity can play essential role in composition of smeltings. It is especially important because even small differences in their ñomposition near to plane of SiO2 saturation in ``basalt tetrahedron'' (Yoder and Tilley, 1962) lead to appearance of Ne-normative or Ne-free melts at practically similar PT conditions. Thus, judging on composition of the mantle xenoliths in basalts of all occurrences in the world, quite possible that Sp peridotites (mainly lherzolites) together with intergranular geochemical-enriched fluid components represent the matter of the modern thermochemical mantle plumes. Origin of two major types of the plume-related magmas, probably, considered with fluid regime in the plume head.

Micro-Ct Imaging of Multi-Phase Flow in Carbonates and Sandstones

NASA Astrophysics Data System (ADS)

Andrew, M. G.; Bijeljic, B.; Blunt, M. J.

2013-12-01

One of the most important mechanisms that limits the escape of CO2 when injected into the subsurface for the purposes of carbon storage is capillary trapping, where CO2 is stranded as pore-scale droplets (ganglia). Prospective storage sites are aquifers or reservoirs that tend to be at conditions where CO2 will reside as a super-critical phase. In order to fully describe physical mechanisms characterising multi-phase flow during and post CO2 injection, experiments need to be conducted at these elevated aquifer/reservoir conditions - this poses a considerable experimental challenge. A novel experimental apparatus has been developed which uses μCT scanning for the non-invasive imaging of the distribution of CO2 in the pore space of rock with resolutions of 7μm at temperatures and pressures representative of the conditions present in prospective saline aquifer CO2 storage sites. The fluids are kept in chemical equilibrium with one-another and with the rock into which they are injected. This is done to prevent the dissolution of the CO2 in the brine to form carbonic acid, which can then react with the rock, particularly carbonates. By eliminating reaction we study the fundamental mechanisms of capillary trapping for an unchanging pore structure. In this study we present a suite of results from three carbonate and two sandstone rock types, showing that, for both cases the CO2 acts as the non-wetting phase and significant quantities of CO2 is trapped. The carbonate examined represent a wide variety of pore topologies with one rock with a very well connected, high porosity pore space (Mt Gambier), one with a lower porosity, poorly connected pore space (Estaillades) and one with a cemented bead pack type pore space (Ketton). Both sandstones (Doddington and Bentheimer) were high permeability granular quartzites. CO2 was injected into each rock, followed by brine injection. After brine injection the entire length of the rock core was scanned, processed and segmented into grain, brine and CO2. Experiments were repeated five times for each rock type, allowing for statistical errors to be estimated. The images from each experiment were approximately 900x900x3200 voxels, representing a sample size of approximately 6.4mm x 6.4mm x 22.4mm. Higher residual saturations were found in the sandstones (Bentheimer: 0.299×0.009, Doddington: 0.27×0.03) than in the carbonates (Mt Gambier: 0.187×0.007, Estaillades: 0.190×0.005, Ketton: 0.193×0.012). The size frequency distribution of ganglia was also examined. The largest ganglia contributed negligibly to the total residual saturation in all cases apart from Mt Gambier, where the increased connectivity of the pore-space inhibits non-wetting phase snap-off. The snap-off of ganglia is understood theoretically as a percolation process, and ganglia size distributions show approximately power-law distributions with exponents agreeing with predictions from percolation theory apart from in Mt Gambier limestone, where the extreme connectivity of the pore space may cause snap-off to be a non-percolation like process. We also present the first dynamic real time multiphase fluid displacements at reservoir conditions. These images were taken using the same reservoir-condition flow rig at Diamond Light Source synchrotron. This advanced facility allows for scanning intervals of 30 seconds, enabling the imaging of discrete pore-filling events (Haines jumps).

10 CFR 960.3-1-2 - Diversity of rock types.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 10 Energy 4 2011-01-01 2011-01-01 false Diversity of rock types. 960.3-1-2 Section 960.3-1-2... NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-1-2 Diversity of rock types. Consideration... sites for characterization shall have different types of host rock. ...

10 CFR 960.3-1-2 - Diversity of rock types.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 10 Energy 4 2013-01-01 2013-01-01 false Diversity of rock types. 960.3-1-2 Section 960.3-1-2... NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-1-2 Diversity of rock types. Consideration... sites for characterization shall have different types of host rock. ...

10 CFR 960.3-1-2 - Diversity of rock types.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 10 Energy 4 2014-01-01 2014-01-01 false Diversity of rock types. 960.3-1-2 Section 960.3-1-2... NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-1-2 Diversity of rock types. Consideration... sites for characterization shall have different types of host rock. ...

10 CFR 960.3-1-2 - Diversity of rock types.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 10 Energy 4 2012-01-01 2012-01-01 false Diversity of rock types. 960.3-1-2 Section 960.3-1-2... NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-1-2 Diversity of rock types. Consideration... sites for characterization shall have different types of host rock. ...

Age of Barrier Canyon-style rock art constrained by cross-cutting relations and luminescence dating techniques.

PubMed

Pederson, Joel L; Chapot, Melissa S; Simms, Steven R; Sohbati, Reza; Rittenour, Tammy M; Murray, Andrew S; Cox, Gary

2014-09-09

Rock art compels interest from both researchers and a broader public, inspiring many hypotheses about its cultural origin and meaning, but it is notoriously difficult to date numerically. Barrier Canyon-style (BCS) pictographs of the Colorado Plateau are among the most debated examples; hypotheses about its age span the entire Holocene epoch and previous attempts at direct radiocarbon dating have failed. We provide multiple age constraints through the use of cross-cutting relations and new and broadly applicable approaches in optically stimulated luminescence dating at the Great Gallery panel, the type section of BCS art in Canyonlands National Park, southeastern Utah. Alluvial chronostratigraphy constrains the burial and exhumation of the alcove containing the panel, and limits are also set by our related research dating both a rockfall that removed some figures and the rock's exposure duration before that time. Results provide a maximum possible age, a minimum age, and an exposure time window for the creation of the Great Gallery panel, respectively. The only prior hypothesis not disproven is a late Archaic origin for BCS rock art, although our age result of A.D. ∼ 1-1100 coincides better with the transition to and rise of the subsequent Fremont culture. This chronology is for the type locality only, and variability in the age of other sites is likely. Nevertheless, results suggest that BCS rock art represents an artistic tradition that spanned cultures and the transition from foraging to farming in the region.

Permian A-type rhyolites of the Muráň Nappe, Inner Western Carpathians, Slovakia: in-situ zircon U-Pb SIMS ages and tectonic setting

NASA Astrophysics Data System (ADS)

Ondrejka, Martin; Li, Xian-Hua; Vojtko, Rastislav; Putis, Marian; Uher, Pavel; Sobocký, Tomas

2018-04-01

Three representative A-type rhyolitic rock samples from the Muráň Nappe of the inferred Silicic Unit of the Inner Western Carpathians (Slovakia) were dated using the high-precision SIMS U-Pb isotope technique on zircons. The geochronological data presented in this paper is the first in-situ isotopic dating of these volcanic rocks. Oscillatory zoned zircon crystals mostly revealed concordant Permian (Guadalupian) ages: 266.6 ± 2.4 Ma in Tisovec-Rejkovo (TIS-1), 263.3 ± 1.9 Ma in Telgárt-Gregová Hill (TEL-1) and 269.5 ± 1.8 Ma in Veľká Stožka-Dudlavka (SD-2) rhyolites. The results indicate that the formation of A-type rhyolites and their plutonic equivalents are connected to magmatic activity during the Permian extensional tectonics and most likely related to the Pangea supercontinent break-up.

The effect of the Ras homolog gene family (Rho), member A/Rho associated coiled-coil forming protein kinase pathway in atrial fibrosis of type 2 diabetes in rats.

PubMed

Chen, Jinling; Li, Qingqing; Dong, Ruiqing; Gao, Huikuan; Peng, Hui; Wu, Yongquan

2014-09-01

Diabetes mellitus promotes atrial structural remodeling, thereby producing atrial arrhythmogenicity. Atrial arrhythmia can substantially increase the risk of premature death. The aim of this study was to investigate the role of Ras homolog gene family, member A (RhoA)/Rho associated coiled-coil forming protein kinase (ROCK) in atrial fibrosis in diabetic hearts, and the effects of fasudil hydrochloride hydrate on atrial fibrosis. An eight-week-old male Sprague-Dawley rat model of type 2 diabetes was established using a high-fat diet combined with streptozotocin [30 mg/kg, once, intraperitoneal (i.p.)]. Animals were randomly divided into three groups: Control rats, untreated diabetic rats that received vehicle, and treated diabetic rats that received Rho kinase inhibitor fasudil hydrochloride hydrate (10 mg/kg/day, i.p., for 14 weeks). The morphological features of atrial fibrosis were observed using Masson staining. The mRNA expression levels of RhoA, ROCK1, ROCK2, type-I and type-III procollagen were assessed with quantitative polymerase chain reaction. The protein levels of RhoA, ROCK1 and ROCK2 were evaluated using western blot analysis. The atria of untreated diabetic rats showed evident atrial fibrosis as compared to the control rats; the mRNA expression levels of RhoA, ROCK1, ROCK2, type-I and type-III procollagen were upregulated; and the protein levels of RhoA, ROCK1 and ROCK2 were increased. The treatment with fasudil hydrochloride hydrate significantly reduced atrial fibrosis, mRNA levels of RhoA, ROCK1, ROCK2, type-I and type-III procollagen, and the protein levels of RhoA, ROCK1 and ROCK2. The results suggested that RhoA/ROCK was involved in atrial fibrosis, and that fasudil hydrochloride hydrate ameliorates atrial fibrosis through the RhoA/ROCK pathway in rats with type 2 diabetes.

Paleomagnetic Results From the Mid-Tertiary Cripple Creek Diatreme Complex

NASA Astrophysics Data System (ADS)

Rampe, J. S.; Geissman, J. W.; Melker, M.

2001-12-01

The Cripple Creek diatreme complex, located about 30 km southwest of Pikes Peak, Colorado, is host to gold and high grade telluride deposits associated with mid-Tertiary alkaline magmatism. Formation of the diatreme took place between about 32.5 and 28.7 Ma, based on previously reported ArAr age determinations. The complex consists of breccia (the primary rock type), that was subsequently intruded by aphanitic phonolite, porphyritic phonolite, phonotephrite, and finally lamprophyre. Rocks presently at the surface were emplaced within a few kilometers of the paleosurface, followed by hydrothermal activity resulting in pervasive K metasomatism and gold mineralization. Mineralized deposits within the diatreme are currently being mined in an open pit fashion allowing for fresh three dimensional exposures of all representative rock types in the district. The Front Fange of Colorado, since cessation of northeast-directed Laramide compression, is characterized by east-west Rio Grande rift extension. Determining Laramide and younger deformation in the Front Range of Colorado is diffucult due to the dominance of Laramide structures and exposed Precambrian rocks with complex structural histories. Structures that affect the Cripple Creek diatreme complex and host Precambrian crystalline rocks clearly were active after intrusive activity and therefore reflect tectonism in the Front Range since early diatreme formation. Over 100 sites have been collected from all representative rock types in the district, with eight to ten oriented samples per site. Results indicate that the materials are capable of carrying geologically stable magnetizations and generally reveal excellent magnetization behavior using both AF and thermal methods. Many sites are associated with contact and breccia tests. Site mean directions are of both normal (D = 5.0° , I = 67.5° , α 95 = 6.4, κ = 89.2), N = 7 and reverse polarity (D = 162.2° , I = -67.3° , α 95 = 4.2, κ = 61.1) N =13; with site mean directions steeper than the expected mid-Tertiary polarity direction. Also, some sites exhibit multiple component behavior with both normal and reverse polarity magnetizations that are well defined (D = 29.7° , I = 72.5° , α 95 = 9.2, κ = 28.4) N = 10 and (D = 173.6° , I = -64.1° , α 95 = 3.1, κ = 594.8) N = 5, in aphanitic phonolite site CC89. We interpret these results to indicate that diatreme formation took place over at least one magnetic reversal and that the diatreme was modestly deformed resulting in north-side down tilting.

Mapping known and potential mineral occurrences and host rocks in the Bonnifield Mining District using minimal cloud- and snow-cover ASTER data: Chapter E in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

USGS Publications Warehouse

Hubbard, Bernard E.; Dusel-Bacon, Cynthia; Rowan, Lawrence C.; Eppinger, Robert G.; Gough, Larry P.; Day, Warren C.

2007-01-01

On July 8, 2003, the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor acquired satellite imagery of a 60-kilometer-wide swath covering a portion of the Bonnifield mining district within the southernmost part of the Tintina Gold Province, Alaska, under unusually favorable conditions of minimal cloud and snow cover. Although rocks from more than eight different lithotectonic terranes are exposed within the extended swath of data, we focus on volcanogenic massive sulfides (VMS) and porphyry deposits within the Yukon-Tanana terrane (YTT), the largest Mesozoic accretionary terrane exposed between the Denali fault system to the south of Fairbanks and the Tintina fault system to the north of Fairbanks. Comparison of thermal-infrared region (TIR) decorrelation stretch data to available geologic maps indicates that rocks from the YTT contain a wide range of rock types ranging in composition from mafic metavolcanic rocks to felsic rock types such as metarhyolites, pelitic schists, and quartzites. The nine-band ASTER visible-near-infrared region--short-wave infrared region (VNIR-SWIR) reflectance data and spectral matched-filter processing were used to map hydrothermal alteration patterns associated with VMS and porphyry deposit types. In particular, smectite, kaolinite, opaline silica, jarosite and (or) other ferric iron minerals defined narrow (less than 250-meter diameter) zonal patterns around Red Mountain and other potential VMS targets. Using ASTER we identified some of the known mineral deposits in the region, as well as mineralogically similar targets that may represent potential undiscovered deposits. Some known deposits were not identified and may have been obscured by vegetation or snow cover or were too small to be resolved.

The rocks of Gusev Crater as viewed by the Mini-TES instrument

USGS Publications Warehouse

Ruff, S.W.; Christensen, P.R.; Blaney, D.L.; Farrand, W. H.; Johnson, J. R.; Michalski, J.R.; Moersch, J.E.; Wright, S.P.; Squyres, S. W.

2006-01-01

The Miniature Thermal Emission Spectrometer (Mini-TES) on board the Mars Exploration Rover Spirit is part of a payload designed to investigate whether a lake once existed in Gusev Crater. Mini-TES has observed hundreds of rocks along the rover's traverse into the Columbia Hills, yielding information on their distribution, bulk mineralogy, and the potential role of water at the site. Although dust in various forms produces contributions to the spectra, we have established techniques for dealing with it. All of the rocks encountered on the plains traverse from the lander to the base of the Columbia Hills share common spectral features consistent with an olivine-rich basaltic rock known as Adirondack Class. Beginning at the base of the West Spur of the Columbia Hills and across its length, the rocks are spectrally distinct from the plains but can be grouped into a common type called Clovis Class. These rocks, some of which appear as in-place outcrop, are dominated by a component whose spectral character is consistent with unaltered basaltic glass despite evidence from other rover instruments for significant alteration. The northwest flank of Husband Hill is covered in float rocks known as Wishstone Class with spectral features that can be attributed uniquely to plagioclase feldspar, a phase that represents more than half of the bulk mineralogy. Rare exceptions are three classes of basaltic "exotics" found scattered across Husband Hill that may represent impact ejecta and/or float derived from local intrusions within the hills. The rare outcrops observed on Husband Hill display distinctive spectral characteristics. The outcrop called Peace shows a feature attributable to molecular bound water, and the outcrop that hosts the rock called Watchtower displays a dominant basaltic glass component. Despite evidence from the rover's payload for significant alteration of some of the rocks, no unambiguous detection of crystalline phyllosilicates or other secondary silicates has been observed by Mini-TES. The mineralogical results supplied by Mini-TES provide no clear evidence that a lake once existed in Gusev Crater. Copyright 2006 by the American Geophysical Union.

Evaluating the competing effects of lithology and sediment supply on the erosional dynamics of rivers crossing active faults.

NASA Astrophysics Data System (ADS)

Whittaker, Alex; Boulton, Sarah; Kent, Emiko; Zondervan, Jesse; Hann, Madeleine; Watkins, Stephen; Bell, Rebecca; Brooke, Sam

2017-04-01

Lithology and sediment supply influence the erosional dynamics of rivers crossing active faults and together these effects govern the style, timescale and means by which landscapes respond to their tectono-climatic boundary conditions. Here, for transient bedrock catchments in the Gediz Graben, Turkey, and the Gulf of Corinth, Greece, for which the timing and rate of active faulting is known, we quantify the relative importance of rock strength and sediment supply on models of fluvial incision. We determine rock type, strength and erodibility using a Schmidt hammer and structural measurements of joint density and size. We evaluate the downstream distribution of channel width and stream power and calculate the extent to which the latter scales with tectonic rates and rock strength. Sediment supply is constrained using estimates of bedrock exposure, transport capacities and erosional fluxes. For the Turkish examples, stream powers in the metamorphic rocks are four times greater than in the Neogene sediment units, indicating a four-fold difference in bedrock erodibility, K, for a two-fold variation in in Schmidt hammer hardness. In the Gulf of Corinth examples, we interpret differences in stream powers near the active faults to represent order of magnitude differences in bedrock erodibility between carbonate and sandstone/conglomerate units. We also observe that in both cases, significant along-strike variation in fault slip rate is not associated with an increase in stream power for the sedimentary rocks and we assess the extent to which this stream power deficit may also represent the effects of sediment-flux-dependent incision.

The deep layers of a Paleozoic arc: geochemistry of the Copley-Balaklala series, northern California

NASA Astrophysics Data System (ADS)

Brouxel, Marc; Lapierre, Henriette; Michard, Annie; Albarède, Francis

1987-10-01

REE, Zr, Nb concentrations and Sr, Nd isotope compositions have been measured in Copley basalts and andesites, Balaklala rhyolites, and Mule Mountain trondhjemites (northern California) which represent the deep layers of a well preserved intra-oceanic island arc of Siluro-Devonian age. 87Sr/ 86Sr is shifted towards high values (up to 0.707) whereas Ce is preferentially removed from rhyolites. A large proportion of the analyzed samples including some acidic rocks shows a pronounced depletion in light REE. The ɛ Nd(T) values of most Copley, Balaklala, and Mule Mountain rocks fall in the range +6 to +8 which suggests that they originated from a normal MORB-type source ( ɛ Nd(T) ≈ +9 ) contaminated with either sediments or an OIB-type component. In modern island arcs, only the shallow levels are accessible: comparison with the Copley-Balaklala-Mule Mountain Series suggests that, at depth, an immature island arc is likely to comprise thick layers of LILE-depleted tholeiites and rhyolites intensely altered by pervasive circulation of seawater. Least-square solutions of trace element models suggest that rhyolites and trondhjemites represent remelting of mafic volcanics from the arc basement rather than residual melts of basalt-andesite differentiation.

Variation of rock-forming metals in sub-annual increments of modern Greenland snow

USGS Publications Warehouse

Hinkley, T.K.

1992-01-01

Modern snowpack from central south Greenland was sampled in sub-seasonal increments and analysed for a suite of major, minor and trace rock-forming metals (K, Rb, Cs, Ca, Sr, Ba). There is a sharp seasonal concentration maximum for all six metals that comes in summer, later than mid-June. Metal concentrations in all other parts of the year's snowpack are up to 10 or more times smaller. The concentration maximum is preceded by low values in autumn-winter, very low values in early-mid-spring, and moderate-to-high values in late spring early summer; this pattern is seen consistently in three separate time stratigraphic intervals representing the same seasonal periods, spanning the time interval 1981-1984. The absolute concentration values of the snow strata representing the low-concentration portion of the year, autumn-winter-spring, may vary substantially from year to year, by a factor of two, or more. The finding that all rock-forming metals are at a sharp concentration maximum in late summer contrasts with the interpretations of several other studies in high-latitude northern regions. Those studies have reported a broad maximum of continental dust-associated metals in late winter and spring. However samples of the other studies have mostly come from regions farther to the north, and the analyses have emphasized industrial pollutant metals rather than the matched rock-forming suite of the present study. The metals measured were chosen to give information about the origin and identity of the rock and soil dusts, and sea salts, present as impurities in the snow. Metal ratios indicate that the dusts in the snowpacks are of continental origin and from ferromagnesian rocks. Source rock types for dusts in central south Greenland snow contrast with the felsic rock dusts of the Sierra Nevada, CA, annual snowpacks, and with the very felsic rock dusts in large south central Alaskan mountain glaciers. Samples in which masses of sea salt are much larger than those of rock dusts may be identified by small changes in metal ratios caused by moderate increases of K and Ca from marine sources, nearly unaccompanied by the minor and trace metals Rb, Cs and Ba, that are very rare in the oceans. A sampling frequency, such as that of the present study, that divides a year's accumulation into 8-10 subsamples is sufficient to reveal details of the time pattern of variation in proportions and concentrations of metals that give information about atmospheric deposition of important types of earth materials.Modern snowpack from central south Greenland was sampled in sub-seasonal increments and analyzed for a suite of major, minor and trace rock-forming metals (K, Rb, Cs, Ca, Sr, Ba). There is a sharp seasonal concentration maximum for all six metals that comes in summer, later than mid-June. Metal concentrations in all other parts of the year's snowpack are up to 10 or more times smaller. The concentration maximum is preceded by low values in autumn-winter, very low values in early-mid-spring, and moderate-to-high values in late spring-early summer; this pattern is seen consistently in three separate time stratigraphic intervals representing the same seasonal periods, spanning the time interval 1981-1984. The absolute concentration values of the snow strata representing the low-concentration portion of the year, autumn-winter-spring, may vary substantially from year to year, by a factor of two, or more. The finding that all rock-forming metals are at a sharp concentration maximum in late summer contrasts with the interpretations of several other studies in high-latitude northern regions. Those studies have reported a broad maximum of continental dust-associated metals in late winter and spring. However, samples of the other studies have mostly come from regions farther to the north, and the analyses have emphasized industrial pollutant metals rather than the matched rock-forming suite of the present study. The metals measured were chosen to give informati

Granitoids of the Ufalei block (South Urals): Sr-Nd isotope systematics, geodynamic position and genetic reconstructions

NASA Astrophysics Data System (ADS)

Ronkin, Yu. L.; Shardakova, G. Yu.; Maslov, A. V.; Shagalov, E. S.; Lepikhina, O. P.

2009-04-01

Petrogeochemical and isotopic-geochronological signatures in granitoids developed in structures with complex geological history represent an important feature for reconstructing paleogeodynamic settings. Granitoids are widespread in the western slope of the Urals, where the Uralian Orogen contacts via a collage of different-age blocks of the east European Platform. The Ufalei block located in the Central Urals megazone at the junction between the South and Middle Urals’ segments represents one such boundary structure with multistage geological evolution. The isotopic ages obtained by different methods for acid igneous rocks range from 1290 to 245 Ma. We determined close Rb-Sr and Sm-Nd ages (317 Ma) for granites of the Nizhnii Ufalei Massif. By their petrochemical parameters, granitoids and host granite-gneisses differ principally from each other: the former are close to subduction-related, while the latter, to continental-riftogenic varieties. The primary ratio (87Sr/86Sr)0 = 0.70428 and ɛNd ≈ +4 values indicate significant contribution of oceanic (island-arc?) material to the substrate, which served as a source for granites of the Nizhnii Ufalei Massif. Model Nd ages of granites vary from 641 to 550 Ma. Distinct oceanic rocks and varieties with such ages are missing from the surrounding structures. New isotopic dates obtained for ultramafic and mafic rocks from different zones of the Urals related to the Cadomian cycle imply development of unexposed Upper Riphean-Vendian “oceanic” rocks in the central part of the Ufalei block, which played a substantial role in the formation of the Nizhnii Ufalei granitoids. Such rocks could be represented, for example, by fragments of the Precambrian Timanide-type ophiolite association. The analysis of original materials combined with published data point to the heterogeneous composition and structure of the Ufalei block and a significant part of the western segment of the Central Uralian Uplift and extremely complex geological history of the region coupling the Uralian Orogen with the East European Platform in the present-day structure.

Shear zones of the Verkhoyansk fold-and-thrust belt, Northeast Russia

NASA Astrophysics Data System (ADS)

Fridovsky, Valery; Polufuntikova, Lena

2017-04-01

The Verkhoyansk fold-and-thrust belt is situated on the submerged eastern margin of the North Asian craton, and is largely composed of the Ediacaran - Middle Paleozoic carbonate and the Upper Paleozoic-Mesozoic terrigenous rocks. The Upper Carboniferous - Jurassic sediments constitute the Verkhoyansk terrigenous complex containing economically viable orogenic gold deposits. The structure of the belt is mainly controlled by thrusts and associated diagonal strike slips. Linear concentric folds are common all over the area of the belt. Shear zones with associated similar folds are confined to long narrow areas. Shear zones were formed during the early stages of the Oxfordian-Kimmeridgian collisional and accretionary events prior to the emplacement of large orogenic granitoid plutons. The main ore-controlling structures are shear zones associated with slaty cleavage, shear folds, mullion- and boudinage-structures, and transposition features. The shear zones are listric-type, and represent branches of a detachment structure, which is assumed to be present at the base of the Verkhoyansk fold-and-thrust belt. A vertical zonation of shear zones is correlated with the distance to the detachment. Changes in the dip angle of the shear zones (as indicated mainly by cleavage), structural paragenesis, the degree of microdeformation of the host rocks, and the type of ore-controlling structures can be clearly observed in the direction away from the detachment. Structural zoning is evidenced, among other things, by changing morphologic types of microstructures and by strain-indicators of the degree of rock metamorphism. Four morphologic types of microstructures are identified. The first platy-shear type is characterized by aggregate cleavage and the coefficient of deformation (Cd) of single grains from 1.0 to 2.0. Irregular angular fragments of variously oriented grains can be observed in thin sections. The second shear-cataclastic morphologic type (Cd from 2.0 to 3.0) exhibits combined aggregate and intergranular cleavage. The third cataclastic-segregation morphologic type (Cd from 3.0 to 4.5) is distinguished by a wide distribution of lentelliptical grains of rock-forming minerals in a finely-crystalline matrix and by intergranular cleavage. The rocks of the fourth segregation-striate morphologic type (Cd >5.0) contain lenticular segregations of quartz and feldspar in an intensely linearized mylonite groundmass.

Granulite-facies rocks in the Whatley Mill gneiss, Pine Mountain basement massif, Eastern Alabama

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daniell, N.; Salpas, P.A.

1993-03-01

The Pine Mountain basement massif is a granulite terrane exposed in a tectonic window through the Inner Piedmont of western Georgia and eastern Alabama. Investigations of the westernmost extent of the massif, the Whatley Mill Gneiss, have revealed four distinct lithologies: (1) an augen gneiss, the type lithology; (2) mylonite that develops in the shear zones cutting the unit; (3) a phaneritic rock showing weak to no foliation; (4) enclaves of biotite gneiss within the weakly-foliated rock. Additionally, the weakly-foliated rock comprises two distinct phases which are in sharp contact along curved and undulating boundaries: phase 1 is a coarser-grainedmore » rock; phase 2 is a finer-grained rock of the same mineralogy as phase 1 except it contains rare hypersthene. This first recorded observation of hypersthene unequivocally confirms the granulite-facies origin of the unit. Major and trace element compositions of the phase 1 rock are identical to those of the augen gneiss. The phase 2 rock, has a distinct composition with higher SiO[sub 2] and lower incompatible trace elements than the phase 1 rock. The enclaves display a range in major elements but higher incompatible elements than the other lithologies. Geochemical and petrologic relationships leads one to interpret: (1) the weakly-foliated rock retains many of its primary igneous features including its two phases and enclaves; (2) the two phases of the weakly-foliated rock arose as a result of injection of one magma (phase 2) into a cooler, crystal mush solidifying from another magma (phase 1); (3) the enclaves represent either autoliths of xenoliths; (4) the augen gneiss arose by isochemical deformation of the phase 1 rock.« less

Mars Exploration Rover APXS Results from Matijevic Hill

NASA Technical Reports Server (NTRS)

Cohen, B. A.; Clark, B. C.; Gellert, R.; Klingelhoefer, G.; Ming, D. W.; Mittlefehldt, D. W.; Morris, R. V.; Schrader, C. M.; Schroeder, C.; Yen, A. S.;

Correlation of Rock Spectra with Quantitative Morphologic Indices: Evidence for a Single Rock Type at the Mars Pathfinder Landing Site

NASA Technical Reports Server (NTRS)

Yingst, R. A.; Biedermann, K. L.; Pierre, N. M.; Haldemann, A. F. C.; Johnson, J. R.

2005-01-01

The Mars Pathfinder (MPF) landing site was predicted to contain a broad sampling of rock types varying in mineralogical, physical, mechanical and geochemical characteristics. Although rocks have been divided into several spectral categories based on Imager for Mars Pathfinder (IMP) visible/near-infrared data, efforts in isolating and classifying spectral units among MPF rocks and soils have met with varying degrees of success, as many factors influencing spectral signatures cannot be quantified to a sufficient level to be removed. It has not been fully determined which spectral categories stem from intrinsic mineralogical differences between rocks or rock surfaces, and which result from factors such as physical or chemical weathering. This has made isolation of unique rock mineralogies difficult. Morphology, like composition, is a characteristic tied to the intrinsic properties and geologic and weathering history of rocks. Rock morphologies can be assessed quantitatively and compared with spectral data, to identify and classify rock types at the MPF landing site. They can also isolate actual rock spectra from spectral types that are surficial in origin, as compositions associated with mantling dust or chemical coatings would presumably not influence rock morphology during weathering events. We previously reported on an initial classification of rocks using the quantitative morphologic indices of size, roundness, sphericity and elongation. Here, we compare this database of rock characteristics with associated rock surface spectra to improve our ability to discriminate between spectra associated with rock types and those from other sources.

Petrogenesis of postcollisional magmatism at Scheelite Dome, Yukon, Canada: Evidence for a lithospheric mantle source for magmas associated with intrusion-related gold systems

USGS Publications Warehouse

Mair, John L.; Farmer, G. Lang; Groves, David I.; Hart, Craig J.R.; Goldfarb, Richard J.

2011-01-01

The type examples for the class of deposits termed intrusion-related gold systems occur in the Tombstone-Tungsten belt of Alaska and Yukon, on the eastern side of the Tintina gold province. In this part of the northern Cordillera, extensive mid-Cretaceous postcollisional plutonism took place following the accretion of exotic terranes to the continental margin. The most cratonward of the resulting plutonic belts comprises small isolated intrusive centers, with compositionally diverse, dominantly potassic rocks, as exemplified at Scheelite Dome, located in central Yukon. Similar to other spatially and temporally related intrusive centers, the Scheelite Dome intrusions are genetically associated with intrusion-related gold deposits. Intrusions have exceptional variability, ranging from volumetrically dominant clinopyroxene-bearing monzogranites, to calc-alkaline minettes and spessartites, with an intervening range of intermediate to felsic stocks and dikes, including leucominettes, quartz monzonites, quartz monzodiorites, and granodiorites. All rock types are potassic, are strongly enriched in LILEs and LREEs, and feature high LILE/HFSE ratios. Clinopyroxene is common to all rock types and ranges from salite in felsic rocks to high Mg augite and Cr-rich diopside in lamprophyres. Less common, calcic amphibole ranges from actinolitic hornblende to pargasite. The rocks have strongly radiogenic Sr (initial 87Sr/86Sr from 0.711-0.714) and Pb isotope ratios (206Pb/204Pb from 19.2-19.7), and negative initial εNd values (-8.06 to -11.26). Whole-rock major and trace element, radiogenic isotope, and mineralogical data suggest that the felsic to intermediate rocks were derived from mafic potassic magmas sourced from the lithospheric mantle via fractional crystallization and minor assimilation of metasedimentary crust. Mainly unmodified minettes and spessartites represent the most primitive and final phases emplaced. Metasomatic enrichments in the underlying lithospheric mantle are attributes of the ancient North American cratonic margin that appear to be essential prerequisites to this style of postcollisional magmatism and associated gold-rich fluid exsolution. This type of magmatic hydrothermal activity occurs in a very specific tectonic setting that typically sets intrusion-related gold deposits apart from orogenic gold deposits, which are synorogenic in timing and have no consistent direct relationship to such diverse and contemporaneous lithospheric mantle-derived magmas, although they too are commonly sited adjacent to lithospheric boundaries.

Lunar Reconnaissance Orbiter Camera Observations Relating to Science and Landing Site Selection in South Pole-Aitken Basin for a Robotic Sample Return Mission

NASA Technical Reports Server (NTRS)

Jolliff, B. L.; Clegg-Watkins, R. N.; Petro, N. E.; Lawrence, S. L.

2016-01-01

The Moon's South Pole-Aitken basin (SPA) is a high priority target for Solar System exploration, and sample return from SPA is a specific objective in NASA's New Frontiers program. Samples returned from SPA will improve our understanding of early lunar and Solar System events, mainly by placing firm timing constraints on SPA formation and the post-SPA late-heavy bombardment (LHB). Lunar Reconnaissance Orbiter Camera (LROC) images and topographic data, especially Narrow Angle Camera (NAC) scale (1-3 mpp) morphology and digital terrain model (DTM) data are critical for selecting landing sites and assessing landing hazards. Rock components in regolith at a given landing site should include (1) original SPA impact-melt rocks and breccia (to determine the age of the impact event and what materials were incorporated into the melt); (2) impact-melt rocks and breccia from large craters and basins (other than SPA) that represent the post-SPA LHB interval; (3) volcanic basalts derived from the sub-SPA mantle; and (4) older, "cryptomare" (ancient buried volcanics excavated by impact craters, to determine the volcanic history of SPA basin). All of these rock types are sought for sample return. The ancient SPA-derived impact-melt rocks and later-formed melt rocks are needed to determine chronology, and thus address questions of early Solar System dynamics, lunar history, and effects of giant impacts. Surface compositions from remote sensing are consistent with mixtures of SPA impactite and volcanic materials, and near infrared spectral data distinguish areas with variable volcanic contents vs. excavated SPA substrate. Estimating proportions of these rock types in the regolith requires knowledge of the surface deposits, evaluated via morphology, slopes, and terrain ruggedness. These data allow determination of mare-cryptomare-nonmare deposit interfaces in combination with compositional and mineralogical remote sensing to establish the types and relative proportions of materials expected at a given site. Remote sensing compositions, e.g., FeO, also constrain the relative abundances of components. Landing-site assessments use crater and boulder distributions, and slope and terrain rugge

Rock and Soil Types at Pathfinder Landing Site

NASA Technical Reports Server (NTRS)

1997-01-01

Type areas of rocks and soils. (A) Dark rock type and bright soil type: Shown is the dark rock Barnacle Bill. Reflectance spectra typical of fresh basalt and APXS spectra indicating more silica-rich basaltic andesite compositions characterize this type. These rocks are typically the small boulders and intermediate-sized cobbles at the Pathfinder site. The bright soil type is very common and in this case comprises Barnacle Bill's wind tail and much of the surround soil area. This soil has a high reflectance and a strongly reddened spectrum indicative of oxidized ferric minerals. (B) Bright rock type: Shown is the bright rock Wedge. Reflectance spectra typical of weathered basalt and APXS spectra indicating basaltic compositions characterize this type. These rocks are typically larger than 1 meter in diameter and many display morphologies indicating flood deposition. (C) Pink rock type: Shown is the pink rock Scooby Doo. APXS and reflectance spectra indicate a composition and optical characteristics similar to the drift soil. However, the morphology of the pink rock type indicates a cemented or rocklike structure. This material may be a chemically cemented hardpan that underlies much of the Pathfinder site. (D) Dark soil type: The dark soil type is typically found on the windward sides of rocks or in rock-free areas like Photometry Flats (shown here) where the bright soil has been striped away by aeolian action or in open areas. Other locations include the Mermaid Dune. (E) Disturbed soil type: The darkening of disturbed soil relative to its parent material, bright soil, as a result of changes in soil texture and compaction caused by movement of the rover and retraction of the lander airbag. (F) Lamb-like soil type: This soil type shows reflectance and spectral characteristics intermediate between the bright and dark soils. Its distinguishing feature is a weak spectral absorption near 900 nanometers not seen in either the bright or dark soils.

NOTE: original caption as published in Science Magazine

Mars Pathfinder is the second in NASA's Discovery program of low-cost spacecraft with highly focused science goals. The Jet Propulsion Laboratory, Pasadena, CA, developed and manages the Mars Pathfinder mission for NASA's Office of Space Science, Washington, D.C. JPL is a division of the California Institute of Technology (Caltech).

Estimation of the radon production rate in granite rocks and evaluation of the implications for geogenic radon potential maps: A case study in Central Portugal.

PubMed

Pereira, A; Lamas, R; Miranda, M; Domingos, F; Neves, L; Ferreira, N; Costa, L

2017-01-01

The goal of this study was to estimate radon gas production rate in granitic rocks and identify the factors responsible for the observed variability. For this purpose, 180 samples were collected from pre-Hercynian and Hercynian rocks in north and central Portugal and analysed for a) 226 Ra activity, b) radon ( 222 Rn) per unit mass activity, and c) radon gas emanation coefficient. On a subset of representative samples from the same rock types were also measured d) apparent porosity and e) apparent density. For each of these variables, the values ranged as follows: a) 15 to 587 Bq kg -1 , b) 2 to 73 Bq kg -1 , c) 0.01 to 0.80, d) 0.3 to 11.4 % and e) 2530 to 2850 kg m -3 . Radon production rate varied between 40 to 1386 Bq m -3  h -1 . The variability observed was associated with geologically late processes of low and high temperature which led to the alteration of the granitic rock with mobilization of U and increase in radon 222 Rn gas emanation. It is suggested that, when developing geogenic radon potential maps, data on uranium concentration in soils/altered rock should be used, rather than data obtained from unaltered rock. Copyright © 2016 Elsevier Ltd. All rights reserved.

Classification of hydrogeologic areas and hydrogeologic flow systems in the basin and range physiographic province, southwestern United States

USGS Publications Warehouse

Anning, David W.; Konieczki, Alice D.

2005-01-01

The hydrogeology of the Basin and Range Physiographic Province in parts of Arizona, California, New Mexico, Utah, and most of Nevada was classified at basin and larger scales to facilitate information transfer and to provide a synthesis of results from many previous hydrologic investigations. A conceptual model for the spatial hierarchy of the hydrogeology was developed for the Basin and Range Physiographic Province and consists, in order of increasing spatial scale, of hydrogeologic components, hydrogeologic areas, hydrogeologic flow systems, and hydrogeologic regions. This hierarchy formed a framework for hydrogeologic classification. Hydrogeologic areas consist of coincident ground-water and surface-water basins and were delineated on the basis of existing sets of basin boundaries that were used in past investigations by State and Federal government agencies. Within the study area, 344 hydrogeologic areas were identified and delineated. This set of basins not only provides a framework for the classification developed in this report, but also has value for regional and subregional purposes of inventory, study, analysis, and planning throughout the Basin and Range Physiographic Province. The fact that nearly all of the province is delineated by the hydrogeologic areas makes this set well suited to support regional-scale investigations. Hydrogeologic areas are conceptualized as a control volume consisting of three hydrogeologic components: the soils and streams, basin fill, and consolidated rocks. The soils and streams hydrogeologic component consists of all surface-water bodies and soils extending to the bottom of the plant root zone. The basin-fill hydrogeologic component consists of unconsolidated and semiconsolidated sediment deposited in the structural basin. The consolidated-rocks hydrogeologic component consists of the crystalline and sedimentary rocks that form the mountain blocks and basement rock of the structural basin. Hydrogeologic areas were classified into 19 groups through a cluster analysis of 8 characteristics of each area's hydrologic system. Six characteristics represented the inflows and outflows of water through the soils and streams, basin fill, and consolidated rocks, and can be used to determine the hydrogeologic area's position in a hydrogeologic flow system. Source-, link-, and sink-type hydrogeologic areas have outflow but not inflow, inflow and outflow, and inflow but not outflow, respectively, through one or more of the three hydrogeologic components. Isolated hydrogeologic areas have no inflow or outflow through any of the three hydrogeologic components. The remaining two characteristics are indexes that represent natural recharge and discharge processes and anthropogenic recharge and discharge processes occurring in the hydrogeologic area. Of the 19 groups of hydrogeologic areas, 1 consisted of predominantly isolated-type hydrogeologic areas, 7 consisted of source-type hydrogeologic areas, 9 consisted of link-type hydrogeologic areas, and 2 consisted of sink-type hydrogeologic areas. Groups comprising the source-, link-, and sink-type hydrogeologic areas can be distinguished between each other on the basis of the hydrogeologic component(s) through which interbasin flow occurs, as well as typical values for the two indexes. Conceptual models of the hydrologic systems of a representative hydrogeologic area for each group were developed to help distinguish groups and to synthesize the variation in hydrogeologic systems in the Basin and Range Physiographic Province. Hydrogeologic flow systems consist of either a single isolated hydrogeologic area or a series of multiple hydrogeologic areas that are hydraulically connected through interbasin flows. A total of 54 hydrogeologic flow systems were identified and classified into 9 groups. One group consisted of single isolated hydrogeologic areas. The remaining eight groups consisted of multiple hydrogeologic areas and were distinguished o

Assessment of aggregate quality and petrographic properties' influence on rock quality: A case study from Nordland county, Norway

NASA Astrophysics Data System (ADS)

Kløve Keiding, Jakob; Erichsen, Eyolf; Heldal, Tom; Aslaksen Aasly, Kari

2017-04-01

Good access to construction materials is crucial for future infrastructure development and continued economic growth. In Norway >80 % of construction materials come from crushed aggregates and represent an growing share of the consumption. Although recycling to some extend can cover the need for construction materials, economic growth, increasing population and urbanization necessitates exploitation of new rock resources in Norway as well as many other parts of the world. Aggregates must fulfill a number of technical requirements to ensure high quality and long life expectancy of new roads, buildings and structures. Aggregates also have to be extracted near the consumer market. Particularly for road construction strict criteria are in place for wearing course for roads with high traffic density. Thus knowledge of mechanical rock quality is paramount for both exploitation as well as future resource and land-use planning but is often not assessed or mapped beyond the quarry scale. The Geological survey of Norway runs a database with information about crushed aggregate deposits from >1500 Norwegian quarries and sample sites. Here we use mechanical test analyses from the database to assess the aggregate quality in the Nordland county, Norway. Maps have been produced linking bed rock geology with rock quality parameters. The survey documents that the county is challenged in meeting the requirements for roads with high traffic density and especially in the middle parts of the county many samples have weak mechanical properties. This to some degree reflect that weak Cambro-Silurian rocks like phyllite, schist, carbonate and greenstone are abundant in Nordland. Typically mechanically stronger rock types such as gabbro, monzonite and granite are also exposed in large parts of the county, but are also characterized by relative poor or very variable mechanical test quality. Preliminary results indicate that many intrinsic parameters influence the mechanical rock strength, but variable degrees of deformation in the different tectonostratigraphic units exposed in Nordland affects the rock mechanical properties and is a prominent feature of our mapping. Unsurprisingly rock type, mineralogy, grain size and rock texture are all important factors that have a major control on the mechanical behaviour of the rocks. However, this assessment shows that there is an intricate interaction between these parameters and the resulting mechanical properties at present making it difficult to assess mechanical quality accurately only based on petrographic examination.

Chemical composition of rocks and soils at Taurus-Littrow

NASA Technical Reports Server (NTRS)

Rose, H. J., Jr.; Cuttitta, F.; Berman, S.; Brown, F. W.; Carron, M. K.; Christian, R. P.; Dwornik, E. J.; Greenland, L. P.

1974-01-01

Seventeen soils and seven rock samples were analyzed for major elements, minor elements, and trace elements. Unlike the soils at previous Apollo sites, which showed little difference in composition at each collection area, the soils at Taurus-Littrow vary widely. Three soil types are evident, representative of (1) the light mantle at the South Massif, (2) the dark mantle in the valley, and (3) the surface material at the North Massif. The dark-mantle soils are chemically similar to those at Tranquillitatis. Basalt samples from the dark mantle are chemically similar although they range from fine to coarse grained. It is suggested that they originated from the same source but crystallized at varying depths from the surface.

Major-element geochemistry of the Silent Canyon-Black Mountain peralkaline volcanic centers, northwestern Nevada Test Site: applications to an assessment of renewed volcanism

USGS Publications Warehouse

Crowe, Bruce M.; Sargent, Kenneth A.

1979-01-01

The Silent Canyon and Black Mountain volcanic centers are located in the northern part of the Nevada Test Site. The Silent Canyon volcanic center is a buried cauldron complex of Miocene age (13-15 m.y.). Black Mountain volcanic center is an elliptical-shaped cauldron complex of late Miocene age. The lavas and tuffs of the two centers comprise a subalkaline-peralkaline association. Rock types range from quartz normative subalkaline trachyte and rhyolite to peralkaline comendite. The Gold Flat Member of the Thirsty Canyon Tuff (Black Mountain) is a pantellerite. The major-element geochemistry of the Black Mountain-Silent Canyon volcanic centers differs in the total range and distribution of Si02, contents, the degree of peralkalinity (molecular Na2O+K2O>Al2O3) and in the values of total iron and alumina through the range of rock types. These differences indicate that the suites were unrelated and evolved from differing magma bodies. The Black Mountain volcanic cycle represents a renewed phase of volcanism following cessation of the Timber Mountain-Silent Canyon volcanic cycles. Consequently, there is a small but numerically incalculable probability of recurrence of Black Mountain-type volcanism within the Nevada Test Site region. This represents a potential risk with respect to deep geologic storage of high-level radioactive waste at the Nevada Test Site.

Estimating Tunnel Strain in the Weak and Schistose Rock Mass Influenced by Stress Anisotropy: An Evaluation Based on Three Tunnel Cases from Nepal

NASA Astrophysics Data System (ADS)

Panthi, Krishna Kanta; Shrestha, Pawan Kumar

2018-06-01

Total plastic deformation in tunnels passing through weak and schistose rock mass consists of both time-independent and time-dependent deformations. The extent of this total deformation is heavily influenced by the rock mass deformability properties and in situ stress condition prevailing in the area. If in situ stress is not isotropic, the deformation magnitude is not only different along the longitudinal alignment but also along the periphery of the tunnel wall. This manuscript first evaluates the long-term plastic deformation records of three tunnel projects from the Nepal Himalaya and identifies interlink between the time-independent and time-dependent deformations using the convergence law proposed by Sulem et al. (Int J Rock Mech Min Sci Geomech 24(3):145-154, 1987a, Int J Rock Mech Min Sci Geomech 24(3):155-164, 1987b). Secondly, the manuscript attempts to establish a correlation between plastic deformations (tunnel strain) and rock mass deformable properties, support pressure and in situ stress conditions. Finally, patterns of time-independent and time-dependent plastic deformations are also evaluated and discussed. The long-term plastic deformation records of 24 tunnel sections representing four different rock types of three different headrace tunnel cases from Nepal Himalaya are extensively used in this endeavor. The authors believe that the proposed findings will be a step further in analysis of plastic deformations in tunnels passing through weak and schistose rock mass and along the anisotropic stress conditions.

Geology of the Chesapeake and Ohio Canal National Historical Park and Potomac River Corridor, District of Columbia, Maryland, West Virginia, and Virginia

USGS Publications Warehouse

Southworth, Scott; Brezinski, David K.; Orndorff, Randall C.; Repetski, John E.; Denenny, Danielle M.

2008-01-01

The Chesapeake and Ohio Canal National Historical Park is 184.5 mi long and extends from Washington, D.C., to Cumberland, Md. The canal passes through three physiographic provinces including the Piedmont, Valley and Ridge, and the Blue Ridge; the map area also includes rocks of the Coastal Plain and Appalachian Plateaus provinces. Each province contains unique packages of rocks that influenced the character of the canal and towpath. The ages of the bedrock encountered along the length of the park range from Mesoproterozoic to Jurassic and represent a variety of tectonic and depositional environments. The different rock types and surficial deposits dictated the various construction methods for the canal, which was excavated in Quaternary flood-plain deposits as well as through bedrock. The ancient course of the Potomac River and the deposits it left behind also influenced the location of the canal and towpath. The engineers made good use of the many rock types to construct the locks, dams, aqueducts, and culverts that guided water from the Potomac River into the canal and maintained the water level as canal boats traveled between higher elevations in western Maryland to sea level in Washington, D.C. The canal and towpath provide a unique transect across the central Appalachian region for examining the rich geologic diversity and history.

Sr-Nd-Pb isotope systematics of the Permian volcanic rocks in the northern margin of the Alxa Block (the Shalazhashan Belt) and comparisons with the nearby regions: Implications for a Permian rift setting?

NASA Astrophysics Data System (ADS)

Shi, Guanzhong; Wang, Hua; Liu, Entao; Huang, Chuanyan; Zhao, Jianxin; Song, Guangzeng; Liang, Chao

2018-04-01

The petrogenesis of the Permian magmatic rocks in the Shalazhashan Belt is helpful for us to understand the tectonic evolution of the Central Asian Orogenic Belt (CAOB) in the northern margin of the Alxa Block. The Permian volcanic rocks in the Shalazhashan Belt include basalts, trachyandesites and trachydacites. Our study shows that two basalt samples have negative εNd(t) values (-5.4 to -1.5) and higher radiogenic Pb values, which are relevant to the ancient subcontinental lithospheric mantle. One basalt sample has positive εNd(t) value (+10) representing mafic juvenile crust and is derived from depleted asthenosphere. The trachyandesites are dated at 284 ± 3 Ma with εNd(t) = +2.7 to +8.0; ISr = 0.7052 to 0.7057, and they are generated by different degrees of mixing between mafic magmas and crustal melts. The trachydacites have high εNd(t) values and slightly higher ISr contents, suggesting the derivation from juvenile sources with crustal contamination. The isotopic comparisons of the Permian magmatic rocks of the Shalazhashan Belt, the Nuru-Langshan Belt (representing the northern margin of the Alxa Block), the Solonker Belt (Mandula area) and the northern margin of the North China Craton (Bayan Obo area) indicate that the radiogenic isotopic compositions have an increasingly evolved trend from the south (the northern margins of the Alxa Block and the North China Craton) to the north (the Shalazhashan Belt and the Solonker Belt). Three end-member components are involved to generate the Permian magmatic rocks: the ancient subcontinental lithospheric mantle, the mafic juvenile crust or newly underplated mafic rocks that were originated from depleted asthenosphere, and the ancient crust. The rocks correlative with the mafic juvenile crust or newly underplated mafic rocks are predominantly distributed along the Shalazhashan Belt and the Solonker Belt, and the rocks derived from ancient, enriched subcontinental lithospheric mantle are mainly distributed along the northern margins of the Alxa Block and the North China Craton. The magmatic rock types, isotopic features and their temporal, spatial distributions suggest an extensional regime probably related to rifting.

Deformation of the Songshugou ophiolite in the Qinling orogen

NASA Astrophysics Data System (ADS)

Sun, Shengsi; Dong, Yunpeng

2017-04-01

The Qinling orogen, middle part of the China Central Orogenic Belt, is well documented that was constructed by multiple convergences and subsequent collisions between the North China and South China Blocks mainly based on geochemistry and geochronology of ophiolites, magmatic rocks as well as sedimentary reconstruction. However, this model is lack of constraints from deformation of subduction/collision. The Songshugou ophiolite outcropped to the north of the Shangdan suture zone represents fragments of oceanic crust and upper mantle. Previous works have revealed that the ophiolite was formed at an ocean ridge and then emplaced in the northern Qinling belt. Hence, deformation of the ophiolite would provide constraints for the rifting and subduction processes. The ophiolite consists chiefly of metamorphosed mafic and ultramafic rocks. The ultramafic rocks contain coarse dunite, dunitic mylonite and harzburgite, with minor diopsidite veins. The mafic rocks are mainly amphibolite, garnet amphibolite and amphibole schist, which are considered to be eclogite facies and retrograde metamorphosed oceanic crust. Amphibole grains in the mafic rocks exhibit a strong shape-preferred orientation parallel to the foliation, which is also parallel to the lithologic contacts between mafic and ultramafic rocks. Electron backscattered diffraction (EBSD) analyses show strong olivine crystallographic preferred orientations (CPO) in dunite including A-, B-, and C-types formed by (010)[100], (010)[001] and (100)[001] dislocation slip systems, respectively. A-type CPO suggests high temperature plastic deformation in the upper mantle. In comparison, B-type may be restricted to regions with significantly high water content and high differential stress, and C-type may also be formed in wet condition with lower differential stress. Additionally, the dunite evolved into amphibolite facies metamorphism with mineral assemblages of olivine + talc + anthophyllite. Assuming a pressure of 1.5 GPa, which corresponds to equilibration in the spinel stability field, application of the olivine-spinel thermometer (Ballhaus et al., 1991) suggests temperature of 622 ± 22 °C. Amphibole schists display well-developed amphibole CPO with [100], [010] and [001] axes concentrate parallel to Z-, Y- and X-directions, respectively. The strong CPO of amphiboles could be interpreted as anisotropic growth and passive rigid-body rotation under various different stresses rather than results of dislocation creep. The Hbl + Pl thermometer (Holland and Blundy, 1994) constrains the equilibrium temperature to be 640 ± 34 °C for the amphibolite facies metamorphism. Zircons in light-color from the amphibolite with Th/U<0.1 and depletion of HREE yield a U-Pb age of 504 ± 10 Ma, representing the metamorphic age of eclogite. In comparison, the zircons in dark-color from amphibolite showing flat HREE patterns and negative abnormal of Eu give a U-Pb age of 489 ± 5.2 Ma, constraining the time of retrograde metamorphism of eclogite. Together with field investigation and regional geology, our new data propose that the A-type olivine CPO was formed in oceanic upper mantle with the spreading of Shangdan ocean before ca. 514 Ma. At ca. 504 Ma, the deep subduction of oceanic lithosphere endured eclogite facies metamorphism and induced B-type olivine CPO. Up to ca. 489 Ma, obduction of the fragments of metamorphosed oceanic lithosphere resulted in the C-type olivine CPO in dunite and amphibole CPO in the retrograded metamorphic eclogite.

Mineral potential modelling of gold and silver mineralization in the Nevada Great Basin - a GIS-based analysis using weights of evidence

USGS Publications Warehouse

Mihalasky, Mark J.

2001-01-01

The distribution of 2,690 gold-silver-bearing occurrences in the Nevada Great Basin was examined in terms of spatial association with various geological phenomena. Analysis of these relationships, using GIS and weights of evidence modelling techniques, has predicted areas of high mineral potential where little or no mining activity exists. Mineral potential maps for sedimentary (?disseminated?) and volcanic (?epithermal?) rock-hosted gold-silver mineralization revealed two distinct patterns that highlight two sets of crustal-scale geologic features that likely control the regional distribution of these deposit types. The weights of evidence method is a probability-based technique for mapping mineral potential using the spatial distribution of known mineral occurrences. Mineral potential maps predicting the distribution of gold-silver-bearing occurrences were generated from structural, geochemical, geomagnetic, gravimetric, lithologic, and lithotectonic-related deposit-indicator factors. The maps successfully predicted nearly 70% of the total number of known occurrences, including ~83% of sedimentary and ~60% of volcanic rock-hosted types. Sedimentary and volcanic rockhosted mineral potential maps showed high spatial correlation (an area cross-tabulation agreement of 85% and 73%, respectively) with expert-delineated mineral permissive tracts. In blind tests, the sedimentary and volcanic rock-hosted mineral potential maps predicted 10 out of 12 and 5 out of 5 occurrences, respectively. The key mineral predictor factors, in order of importance, were determined to be: geology (including lithology, structure, and lithotectonic terrane), geochemistry (indication of alteration), and geophysics. Areas of elevated sedimentary rock-hosted mineral potential are generally confined to central, north-central, and north-eastern Nevada. These areas form a conspicuous ?V?-shape pattern that is coincident with the Battle Mountain-Eureka (Cortez) and Carlin mineral trends and a segment of the Roberts Mountain thrust front, which bridges the southern ends of the trends. This pattern appears to delineate two well-defined, sub-parallel, northwest?southeast-trending crustal-scale structural zones. These features, here termed the ?Carlin? and ?Cortez? structural zones, are believed to control the regional-scale distribution of the sedimentary rock-hosted occurrences. Mineralizing processes were focused along these structural zones and significant ore deposits exist where they intersect other tectonic zones, favorable host rock-types, and (or) where appropriate physio-chemical conditions were present. The origin and age of the Carlin and Cortez structural zones are not well constrained, however, they are considered to be transcurrent features representing a long-lived, deep-crustal or mantle-rooted zone of weakness. Areas of elevated volcanic rock-hosted mineral potential are principally distributed along two broad and diffuse belts that trend (1) northwest-southeast across southwestern Nevada, parallel to the Sierra Nevada, and (2) northeast-southwest across northern Nevada, extending diagonally from the Sierra Nevada to southern Idaho. The first belt corresponds to the Walker Lane shear zone, a wide region of complex strike-slip faulting. The second, here termed the ?Humboldt shear(?) zone?, may represent a structural zone of transcurrent movement. Together, the Walker Lane and Humboldt shear(?) zones are believed to control the regional-scale distribution of volcanic rock-hosted occurrences. Volcanic rock-hosted mineralization was closely tied to the southward and westward migration of Tertiary magmatism across the region (which may have been mantle plume-driven). Both magmatic and mineralizing processes were localized and concentrated along these structural zones. The Humboldt shear(?) zone may have also affected the distribution of sedimentary rock-hosted mineralization along the Battle Mountain?Eureka (C

Interpretation of Gravimetric and Aeromagnetic Data of the Tecoripa Chart in Southeast Sonora, Mexico.

NASA Astrophysics Data System (ADS)

Martínez-Retama, S.; Montaño-Del Cid, M. A.

2015-12-01

The Tecoripa chart H12-D64 is located southeast of the state of Sonora, México, south of Arizona. The geology is represented by sedimentary rocks of the Ordovician and Triassic, volcanic rocks of the Upper Cretaceous and Tertiary, intrusive rocks from the Upper Cretaceous- Tertiary and sedimentary rocks of the Cenozoic. In this paper a gravimetric study was conducted to determine the configuration and depth of the basement and to develop a structural model of the subsurface. For this purpose a consistent gravimetric survey in 3 profiles was conducted. To complement this study, gravimetric data obtained by INEGI (96 gravimetric stations spaced every 4000 m) that correspond to a regional survey was also used. The two sets of data were corrected and processed with the WinGLink software. The profiles were then modeled using the Talwani method. 4 Profiles corresponding to the gravimetric survey and 5 data profiles from INEGI were modeled. Aeromagnetic data from the total field of Tecoripa chart were also processed. The digital information was integrated and processed by generating a data grid. Processes applied to data consisted of reduction to the pole, regional-residual separation and upward continuations. In general, the obtained structural models show intrusive bodies associated with well-defined high gravimetric and magnetic and low gravimetric and magnetic are associated with basins and sedimentary rocks. The obtained geological models show the basement represented by volcanic rocks of the Tarahumara Formation from the Upper Cretaceous which are in contact with sedimentary rocks from the Barranca Group from Upper Cretaceous and limestones from the Middle Ordovician. Both volcanic and sedimentary rocks are intruded by granodiorite- granite with ages of the Tertiary-Oligocene. Based on the superficial geology as well as in the configuration of the basement and the obtained structural model the existence of faults with NW-SE orientation that originate Horst and Graben type structures can be inferred. The basins have depths of 2,000 to 4,000m with sedimentary fillings from the Báucarit Formation and Quaternary sediments.

Major chemical characteristics of Mesozoic Coast Range ophiolite in California

USGS Publications Warehouse

Bailey, E.H.; Blake, Jr., M.C.

1974-01-01

Sixty-four major element analyses of rocks representative of the Coast Range ophiolite in California were compared with analyses of other onland ophiolite sequences and those of rocks from oceanic ridges. The rocks can be classed in five groups harzburgite-dunite, clinopyroxenite-wehrlite, gabbro, basalt-spilite, and keratophyre-quartz keratophyre which on various diagrams occupy nonoverlapping fields. The harzburgite-dunite from onland ophiolite and ocean ridges are comparable and very low in alkalies. Possible differentiation trends defined on AFM diagrams by other rocks from onland ophiolites and ocean ridges suggest two lines of descent: (1) A trend much like the calc-alkalic trend, though shifted somewhat toward higher iron, and (2) an iron-enrichment trend defined chiefly by the more iron-rich gabbros and amphibolite. MgO-variation diagrams for rocks from the Coast Range ophiolite further distinguish the iron-rich gabbros and amphibolite from the other rock groups and indicate that the iron enrichment, unlike that of the Skaergaard trend, is related to the formation of amphibole. Ophiolite sequences that include the most silicic rock types, such as quartz keratophyre, also exhibit the most pronounced dual lines of descent, suggesting that the silicic rocks and the amphibole-rich gabbros are somehow related. Although the major element chemistry of the Coast Range ophiolite is clearly like that of rocks dredged from oceanic ridges, it is not sufficiently diagnostic to discriminate among the choices of a spreading ridge, an interarc basin, or perhaps even the root zone of an island arc as the site of ophiolite formation.

Raman Spectroscopy for Mineral Identification and Quantification for in situ Planetary Surface Analysis: A Point Count Method

NASA Technical Reports Server (NTRS)

Haskin, Larry A.; Wang, Alian; Rockow, Kaylynn M.; Jolliff, Bradley L.; Korotev, Randy L.; Viskupic, Karen M.

1997-01-01

Quantification of mineral proportions in rocks and soils by Raman spectroscopy on a planetary surface is best done by taking many narrow-beam spectra from different locations on the rock or soil, with each spectrum yielding peaks from only one or two minerals. The proportion of each mineral in the rock or soil can then be determined from the fraction of the spectra that contain its peaks, in analogy with the standard petrographic technique of point counting. The method can also be used for nondestructive laboratory characterization of rock samples. Although Raman peaks for different minerals seldom overlap each other, it is impractical to obtain proportions of constituent minerals by Raman spectroscopy through analysis of peak intensities in a spectrum obtained by broad-beam sensing of a representative area of the target material. That is because the Raman signal strength produced by a mineral in a rock or soil is not related in a simple way through the Raman scattering cross section of that mineral to its proportion in the rock, and the signal-to-noise ratio of a Raman spectrum is poor when a sample is stimulated by a low-power laser beam of broad diameter. Results obtained by the Raman point-count method are demonstrated for a lunar thin section (14161,7062) and a rock fragment (15273,7039). Major minerals (plagioclase and pyroxene), minor minerals (cristobalite and K-feldspar), and accessory minerals (whitlockite, apatite, and baddeleyite) were easily identified. Identification of the rock types, KREEP basalt or melt rock, from the 100-location spectra was straightforward.

Cortlandtitic enclaves associated with calc-alkaline granites from Tapia-Asturias (Hercynian Belt, northwestern Spain)

NASA Astrophysics Data System (ADS)

Galán, G.; Suárez, O.

1989-10-01

Petrographic and mineralogical characteristics of amphibole-olivine- and pyroxene-bearing ultramafic rocks from Asturias (NW Spain) are dealt with in this paper. These rocks are of cortlandtitic type and occur as small rare enclaves in basic rocks related to Hercynian calc-alkaline, post-tectonic epizonal granites, in the northwest of the Iberian Peninsula. These particular ultramafic enclaves are characterized by poikilitic cumulate microtexture. Olivine (Fo 77-81), spinel, from chromite to pleonaste composition, enstatite, subordinated diopside and sulphides are included in large brown calcic amphibole crystals displaying an irregular zonation. Phlogopite and plagioclase are also found, in a much lower proportion, between the large amphibole crystals. Mineral assemblage and chemical composition of minerals indicate formation conditions of 1150°C, 7-8 kbar of Ptotal and PH 2O < Ptotal. These rocks could represent the earlier products of fractional crystallization from a hydrated high-alumina basalt involved in the genesis of the calc-alkaline granites. This basic magma would start crystallizing at a relatively deep level, carrying up the first products of its crystallization during its ascent.

Experimental results of temperature response to stress change: An indication of the physics of earthquake rupture propagation

NASA Astrophysics Data System (ADS)

Lin, W.; Yang, X.; Tadai, O.; Zeng, X.; Yeh, E. C.; Yu, C.; Hatakeda, K.; Xu, H.; Xu, Z.

2016-12-01

As a result of the earthquake rupture propagation, stress on the earthquake fault and in the hanging wall and in the footwall coseismically drops. Based on the thermo-elasticity theory, the temperature of rocks may change associated with coseismic stress change at the same time as their elastic deformation. This coseismic temperature change is one of the physics of earthquake rupture propagation, however has not been noted and expressly addressed before. To understand this temperature issue, we conducted laboratory experiments to quantitatively investigate temperatures response of rocks to rapid stress change of various typical rocks. Consequently, we developed a hydrostatic compression experimental equipment for rock samples with a high resolution temperature measuring system. This enable us to rapidly load and/or unload the confining pressure. As experimental rock samples, we collected 15 representative rocks from various scientific drilling projects and outcrops of earthquake faults, and quarries in the world. The rock types include sandstone, siltstone, limestone, granite, basalt, tuff etc. Based on the classical thermo-elastic theory, a conventional relationship between the temperature change (dT) of rock samples and the confining pressure change (dP) in the hydrostatic compression system under adiabatic condition can be expressed as a linear function. Therefore, we can measure the adiabatic pressure derivative of temperature (dT/dP) directly by monitoring changes of rock sample temperature and confining pressure during the rapidly loading and unloading processes. As preliminary results of the experiments, the data of 15 rock samples showed that i) the adiabatic pressure derivative of temperature (dT/dP) of most rocks are about 1.5 6.2 mK/MPa; ii) the dT/dP of sedimentary rocks is larger than igneous and metamorphic rocks; iii) a good linear correlation between dT/dP and the rock's bulk modulus was recognized.

Seismic Monitoring of Rock Falls in Yosemite National Park

NASA Astrophysics Data System (ADS)

Zimmer, V. L.; Stock, G. M.; Sitar, N.

2008-12-01

Between 1857 and 2007, more than 600 landslide events have been documented in Yosemite National Park, with the vast majority of events occurring as rock falls in Yosemite Valley. The conditions leading to and triggering rock fall are understood in approximately 50 percent of cases, but in the other 50 percent, there were no apparent triggers. Occasionally, large rock falls have been preceded by smaller events that, in retrospect, may have been precursors. Close range seismic monitoring presents an opportunity to study the conditions leading up to rock fall, as well as the mechanics of the actual rock fall as recorded seismically. During the winter of 2007-08, we conducted a rock fall seismic monitoring feasibility study in Yosemite Valley. A station consisting of an 8 Hz geophone and an accelerometer was placed on a ledge 1000 feet above the valley floor, in a historically active rock fall area known as the Three Brothers. At least two rock falls in this area were recorded by the instrumentation and witnessed by visitors, representing the first time rock falls have been recorded with seismic instrumentation in Yosemite Valley. Significant energy was recorded in a wide frequency range, from a few Hz to approximately 150 Hz, limited by the geophone response and attenuation of the signal due to distance to the source (400 m). Furthermore, there exists a weak signal approximately 5-10 seconds before the obvious rock fall signature. We hypothesize that the weak signal represents rock fall initiation manifesting as the first blocks sliding down the cliff face, while the stronger impulses represent these blocks impacting ledges and the bottom talus field. This study demonstrated that rock fall monitoring is feasible with seismic instrumentation, and serves as the catalyst for future studies using a network of sensors for more advanced analysis.

The Regolith of 4 Vesta - Inferences from Howardites

NASA Technical Reports Server (NTRS)

Mittlefehldt, D. W.; Herrin, J. S.; Cartwright, J. A.

2011-01-01

Asteroid 4 Vesta is quite likely the parent asteroid of the howardite, eucrite and diogenite meteorites - the HED clan. Eucrites and diogenites are the products of igneous processes; the former are basaltic composition rocks from flows, and shallow and deep intrusive bodies, whilst the latter are cumulate orthopyroxenites thought to have formed deep in the crust. Impact processes have excavated these materials and mixed them into a suite of polymict breccias. Howardites are polymict breccias composed mostly of clasts and mineral fragments of eucritic and diogenitic parentage, with neither end-member comprising more than 90% of the rock. Early work interpreted howardites as representing the lithified regolith of their parent asteroid. Recently, howardites have been divided into two subtypes; fragmental howardites, being a type of non-regolithic polymict breccia, and regolithic howardites, being lithified remnants of the active regolith of 4 Vesta. We are in the thralls of a collaborative investigation of the record of impact mixing contained within howardites, which includes studies of their mineralogy, petrology, bulk rock compositions, and bulk rock and clast noble gas contents. One goal of our investigation is to test the hypothesis that some howardites represent breccias formed from an ancient, well-mixed regolith on Vesta. Another is to use our results to further understand regolith processing on differentiated asteroids as compared to what has been learned from the Moon. We have made petrographic observations and electron microprobe analyses on 21 howardites and 3 polymict eucrites. We have done bulk rock analyses using X-ray fluorescence spectrometry and are completing inductively coupled plasma mass spectrometry analyses. Here, we discuss our petrologic and bulk compositional results in the context of regolith formation. Companion presentations describe the noble gas results and compositional studies of low-Ca pyroxene clasts.

Stress-Activated Electronic Charge Carriers in Igneous Rocks

NASA Astrophysics Data System (ADS)

Pan, C. T.; Jones, H. H.; Freund, F. T.

2006-12-01

Igneous rocks, when subjected to deviatory stress, turn into a battery. We report on gabbro (Shanxi, China) and anorthosite (Larvik, Norway). We use tiles, 30 x 30 x 0.9 cm3, and a pair of steel pistons, 4.4 cm diameter to subject a small off-center volume of ~10 cm3 to 10 MPa, about 5% failure strength. Instantly upon loading, two types of electronic charge carriers are activated in the stressed rock volume and a current begins to flow. One current leg is carried by holes, which flow from the stressed through the unstressed rock to the edges of the tile. The other current leg is carried by electrons, which flow from the stressed rock into the steel pistons and through the external wire to the edge, where they meet the holes. We have measured the impedance of the gabbro and anorthosite over the frequency range from <1 Hz to 10 MHz. We measured the impedence across the 10 cm3 volume between the two pistons and a similar volume outside the pistons in the path of the holes flowing to the edges of the tile: (1) before loading, (2) during loading. We obtain thus information about both types of charge carriers, electrons and holes. Both are associated with oxygen anions that changed their valence from 2- to 1- (peroxy). An O- among O2- represents a defect electron in the O2- sublattice, known as positive hole or p-hole for short. In unstressed rocks the O- exist in an electrically inactive form as O- pairs, chemically equivalent to peroxy links, O3X-OO-XO3 with X = Si4+, Al3+ etc. Stresses cause the peroxy links to break, allowing electrons from neighboring O2- to jump in and p-holes to jump out. The p-holes can spread through unstressed rocks using energy levels at the upper edge of the valence band.

Petrophysical, Lithological and Mineralogical Characteristics of the Shale Strata of the Volga- Ural Region

NASA Astrophysics Data System (ADS)

Morozov, Vladimir P.; Plotnikova, Irina N.; Pronin, Nikita V.; Nosova, Fidania F.; Pronina, Nailya R.

2014-05-01

The objects of the study are Upper Devonian carbonate rocks in the territory of South-Tatar arch and Melekess basin in the Volga- Urals region. We studied core material of Domanicoid facies from the sediments of Mendymski and Domanik horizons of middle substage of Frasnian stage of the Upper Devonian. Basic analytical research methods included the following: study of the composition, structural and textural features of the rocks, the structure of their voids, filter and reservoir properties and composition of the fluid. The complex research consisted of macroscopic description of the core material, optical microscopy analysis, radiographical analysis, thermal analysis, x-ray tomography, electron microscopy, gas-liquid chromatography, chromate-mass spectrometry, light hydrocarbons analysis using paraphase assay, adsorbed gases analysis, and thermal vacuum degassing method. In addition, we performed isotopic studies of hydrocarbons saturating shale rocks. Shale strata are mainly represented by carbonate-chert rocks. They consist mainly of calcite and quartz. The ratio of these rock-forming minerals varies widely - from 25 to 75 percent. Pyrite, muscovite, albite, and microcline are the most common inclusions. Calcareous and ferruginous dolomite (ankerite), as well as magnesian calcite are tracked down as secondary minerals. While performing the tests we found out that the walls of open fractures filled with oil are stacked by secondary dolomite, which should be considered as an indication moveable oil presence in the open-cut. Electron microscopy data indicate that all the studied samples have porosity - both carbonates and carbonate-siliceous rocks. Idiomorphism of the rock-forming grains and pores that are visible under a microscope bring us to that conclusion. The analysis of the images indicates that the type of reservoir is either porous or granular. The pores are distributed evenly in the volume of rock. Their size is very unstable and varies from 0.5 microns to 100 microns. The lowest value are observed in long carbonate-siliceous rocks, the highest values are found in carbonate rocks. The latter is caused by the fact that there is a very strong recrystallization of calcite and its dolomite substitution in carbonates. Open porosity ranges from 0.65 to 7.98 percent, average value is 4.1percent . Effective porosity has an average value of 0.44 percent, ranging from 0.22 to 1.97. Permeability varies from 0.043 to 1.49 mD, average value is 0,191 mD. Organic matter was found in all samples. Its content varies within the section. The fluctuation range of from 1.0 to 20 percent. The lowest content of carbonates is found in carbonates, while the highest is observed in carbonate-siliceous rocks with a high content of chalcedony. Average organic matter content is 5-7 percent. According to Rock-Eval studies of the core, the catagenetic maturity of organic matter corresponds to MK1 - MK2 degree. We found a connection between the type of organic matter and the composition of adsorbed gas. We also could see that the samples with humic organics present in their organic matter and can be characterized by a fair dominance of methane over other gases. There is a clear relationship between organic matter content and the intensity of the gas saturation of the rock. Organic matter is characteristic mainly of the most siliceous formations. In "pure" carbonates, which are represented by micro-layers with different capacities, OM is not observed at all or its content is quite low.

Geo-material surface modification of microchips using layer-by-layer (LbL) assembly for subsurface energy and environmental applications.

PubMed

Zhang, Y Q; Sanati-Nezhad, A; Hejazi, S H

2018-01-16

A key constraint in the application of microfluidic technology to subsurface flow and transport processes is the surface discrepancy between microchips and the actual rocks/soils. This research employs a novel layer-by-layer (LbL) assembly technology to produce rock-forming mineral coatings on microchip surfaces. The outcome of the work is a series of 'surface-mimetic micro-reservoirs (SMMR)' that represent multi-scales and multi-types of natural rocks/soils. For demonstration, the clay pores of sandstones and mudrocks are reconstructed by representatively coating montmorillonite and kaolinite in polydimethylsiloxane (PDMS) microchips in a wide range of channel sizes (width of 10-250 μm, depth of 40-100 μm) and on glass substrates. The morphological and structural properties of mineral coatings are characterized using a scanning electron microscope (SEM), optical microscope and profilometer. The coating stability is tested by dynamic flooding experiments. The surface wettability is characterized by measuring mineral oil-water contact angles. The results demonstrate the formation of nano- to micro-scale, fully-covered and stable mineral surfaces with varying wetting properties. There is an opportunity to use this work in the development of microfluidic technology-based applications for subsurface energy and environmental research.

Relationship between mineralogy and porosity in seals relevant to geologic CO2 Sequestration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swift, Alexander; Anovitz, Lawrence; Sheets, Julia

2014-01-01

Porosity and permeability are key petrophysical variables that link the thermal, hydrological, geochemical, and geomechanical properties of subsurface formations. The size, shape, distribution, and connectivity of rock pores dictate how fluids migrate into and through micro- and nano-environments, then wet and react with accessible solids. Three representative samples of cap rock from the Eau Claire Formation, the prospective sealing unit that overlies the Mount Simon Sandstone, a potential CO 2 storage formation, were interrogated with an array of complementary methods. neutron scattering, backscattered-electron imaging, energydispersive spectroscopy, and mercury porosimetry. Results are presented that detail variations between lithologic types in totalmore » and connected nano- to microporosity across more than five orders of magnitude. Pore types are identified and then characterized according to presence in each rock type, relative abundance, and surface area of adjacent minerals, pore and pore-throat diameters, and degree of connectivity. We observe a bimodal distribution of porosity as a function of both pore diameter and pore-throat diameter. The contribution of pores at the nano- and microscales to the total and the connected porosity is a distinguishing feature of each lithology observed. Pore:pore-throat ratios at each of these two scales diverge markedly, being almost unity at the nanoscale regime (dominated by illitic clay and micas), and varying by one and a half orders of magnitude at the microscale within a clastic mudstone.« less

Petrophysical Rock Typing of Unconventional Shale Plays: A Case Study for the Niobrara Formation of the Denver-Julesburg (DJ) Basin

NASA Astrophysics Data System (ADS)

Kamruzzaman, A.; Prasad, M.

2015-12-01

The hydrocarbon-rich mudstone rock layers of the Niobrara Formation were deposited in the shallow marine environment and have evolved as overmature oil- or gas-prone source and reservoir rocks. The hydrocarbon production from its low-porosity, nano-darcy permeability and interbedded chalk-marl reservoir intervals is very challenging. The post-diagenetic processes have altered the mineralogy and pore structure of its sourcing and producing rock units. A rock typing analysis in this play can help understand the reservoir heterogeneity significantly. In this study, a petrophysical rock typing workflow is presented for the Niobrara Formation by integrating experimental rock properties with geologic lithofacies classification, well log data and core study.Various Niobrara lithofacies are classified by evaluating geologic depositional history, sequence stratigraphy, mineralogy, pore structure, organic content, core texture, acoustic properties, and well log data. The experimental rock measurements are conducted on the core samples recovered from a vertical well from the Wattenberg Field of the Denver-Julesburg (DJ) Basin. Selected lithofacies are used to identify distinct petrofacies through the empirical analysis of the experimental data-set. The grouped petrofacies are observed to have unique mineralogical properties, pore characteristics, and organic contents and are labelled as discrete Niobrara rock types in the study area.Micro-textural image analysis (FESEM) is performed to qualitatively examine the pore size distribution, pore types and mineral composition in the matrix to confirm the classified rock units. The principal component analysis and the cluster analysis are carried out to establish the certainty of the selected rock types. Finally, the net-to-pay thicknesses of these rock units are compared with the cumulative production data from the field to further validate the chosen rock types.For unconventional shale plays, the rock typing information can be used to locate hydrocarbon sweetspots, facilitate the placement of the horizontal section of the wells along the sweetspots, and can augment engineers' abilities on suitable well placement considerations. It can also help enhancing the effectiveness of the hydraulic fracture stimulation and completion operation.

Petrographic and geochemical characterization of the Triassic and Jurassic magmatic and volcanic rocks of southeastern Ecuador

NASA Astrophysics Data System (ADS)

Villares, Fabián; Eguez, Arturo; Yanez, Ernesto

2014-05-01

Formely, the subandean zone in the southeastern Ecuador involved large volcanic and magmatic rocks included in the Misahualli Formation and Zamora batholith, both as expression of the Jurassic cal-alcaline volcanic arc. The aim of the project carried out by the INIGEMM (Instituto Nacional de Investigación Geológico Minero Metalúrgico) was discriminate the volcanic products including a continuous set going from basalts to ryolithes and volcanoclastic rocks. Geochemical characterization was done using representative 16 whole - rock chemical analysis. The oldest rocks of the investigated area called Pachicutza Unit, include greenish to black, massive basalts and basaltic andesites, locally showing pillows structures. The texture is aphanitic to microporphyritic with slight crystal growth of plagioclase and pyroxenes. The Unit include also local pyroclastic breccias and tuffs showing variable skarnification related to the intrusion of the jurassic Zamora Batholith. Two samples of basalts show tholeiitic affinity, corresponding to an N- MORB, probably representing an early stage in opening of a regional Triassic rift reported since Colombia to Peru in the Andes. These geochemical characteristics are similar to the amphibolites of Monte Olivo Unit in the Real Cordillera. The Jurassic large volcanic assembly of the Misahualli Formation was also differenciated. Basal volcanics include green, subporphyritic andesites and volcanic breccias possibly generated at an early stage of the volcanic arc, caused by a change of extensive to compressive regime. Continental volcano sedimentary and sedimentary rock were discriminate as Nueva Esperanza and Suarez Units, respectively. The volcanosedimentary sequence include massive to laminate tuffs and tuffites of intermediate composition. The sediments of the Suarez Unit include dominant conglomerats and sandstones of fluvial domain. The regional volcanic sequence is completed by the Las Peñas Unit that includes aphanitic to porphyritic andesites and coarse volcanic breccias. Three geochemical analysis of the lavas show andesitic composition, have medium to high-K calc-alkaline and represent the products of a subduction zone. All intrusions in the area were mapped as Zamora Batholith. Nevetheless, the field observations confirm a large Jurassic batholith but also other significant minor intrusion that intrudes the cretaceous sedimentary formations of the area. Thus, magmatic rocks in the area are named as Zamora batholithic complex. Petrography of the Zamora Batholith ranges from tonalite to monzo-granite with the same qualitative mineralogy. Rocks are composed by different proportions of plagioclase, amphibole, K-feldspar, quartz, biotite, opaques and epidote, as accessory minerals has zircon, sphene and apatite. Zamora Granitoids ranged from dioritic to granitic compositions ( 60.09 - . 73.6 wt % SiO2). The Zamora Granitoids have medium to high-K calc-alkaline and represent the products of a subduction zone. Products are generated within a magmatic arc in normal conditions of maturity. The Zamora Granitoids are I - type intrusions.

Matrix diffusion coefficients in volcanic rocks at the Nevada test site: influence of matrix porosity, matrix permeability, and fracture coating minerals.

PubMed

Reimus, Paul W; Callahan, Timothy J; Ware, S Doug; Haga, Marc J; Counce, Dale A

2007-08-15

Diffusion cell experiments were conducted to measure nonsorbing solute matrix diffusion coefficients in forty-seven different volcanic rock matrix samples from eight different locations (with multiple depth intervals represented at several locations) at the Nevada Test Site. The solutes used in the experiments included bromide, iodide, pentafluorobenzoate (PFBA), and tritiated water ((3)HHO). The porosity and saturated permeability of most of the diffusion cell samples were measured to evaluate the correlation of these two variables with tracer matrix diffusion coefficients divided by the free-water diffusion coefficient (D(m)/D*). To investigate the influence of fracture coating minerals on matrix diffusion, ten of the diffusion cells represented paired samples from the same depth interval in which one sample contained a fracture surface with mineral coatings and the other sample consisted of only pure matrix. The log of (D(m)/D*) was found to be positively correlated with both the matrix porosity and the log of matrix permeability. A multiple linear regression analysis indicated that both parameters contributed significantly to the regression at the 95% confidence level. However, the log of the matrix diffusion coefficient was more highly-correlated with the log of matrix permeability than with matrix porosity, which suggests that matrix diffusion coefficients, like matrix permeabilities, have a greater dependence on the interconnectedness of matrix porosity than on the matrix porosity itself. The regression equation for the volcanic rocks was found to provide satisfactory predictions of log(D(m)/D*) for other types of rocks with similar ranges of matrix porosity and permeability as the volcanic rocks, but it did a poorer job predicting log(D(m)/D*) for rocks with lower porosities and/or permeabilities. The presence of mineral coatings on fracture walls did not appear to have a significant effect on matrix diffusion in the ten paired diffusion cell experiments.

U.S.A. National Surface Rock Density Map - Part 2

NASA Astrophysics Data System (ADS)

Winester, D.

2016-12-01

A map of surface rock densities over the USA has been developed by the NOAA-National Geodetic Survey (NGS) as part of its Gravity for the Redefinition of the American Vertical Datum (GRAV-D) Program. GRAV-D is part of an international effort to generate a North American gravimetric geoid for use as the vertical datum reference surface. As a part of modeling process, it is necessary to eliminate from the observed gravity data the topographic and density effects of all masses above the geoid. However, the long-standing tradition in geoid modeling, which is to use an average rock density (e.g. 2.67 g/cm3), does not adequately represent the variety of lithologies in the USA. The U.S. Geological Survey has assembled a downloadable set of surface geologic formation maps (typically 1:100,000 to 1:500, 000 scale in NAD27) in GIS format. The lithologies were assigned densities typical of their rock type (Part 1) and these variety of densities were then rasterized and averaged over one arc-minute areas. All were then transformed into WGS84 datum. Thin layers of alluvium and some water bodies (interpreted to be less than 40 m thick) have been ignored in deference to underlying rocks. Deep alluvial basins have not been removed, since they represent significant fraction of local mass. The initial assumption for modeling densities will be that the surface rock densities extend down to the geoid. If this results in poor modeling, variable lithologies with depth can be attempted. Initial modeling will use elevations from the SRTM DEM. A map of CONUS densities is presented (denser lithologies are shown brighter). While a visual map at this scale does show detailed features, digital versions are available upon request. Also presented are some pitfalls of using source GIS maps digitized from variable reference sources, including the infamous `state line faults.'

Matrix diffusion coefficients in volcanic rocks at the Nevada test site: Influence of matrix porosity, matrix permeability, and fracture coating minerals

NASA Astrophysics Data System (ADS)

Reimus, Paul W.; Callahan, Timothy J.; Ware, S. Doug; Haga, Marc J.; Counce, Dale A.

2007-08-01

Diffusion cell experiments were conducted to measure nonsorbing solute matrix diffusion coefficients in forty-seven different volcanic rock matrix samples from eight different locations (with multiple depth intervals represented at several locations) at the Nevada Test Site. The solutes used in the experiments included bromide, iodide, pentafluorobenzoate (PFBA), and tritiated water ( 3HHO). The porosity and saturated permeability of most of the diffusion cell samples were measured to evaluate the correlation of these two variables with tracer matrix diffusion coefficients divided by the free-water diffusion coefficient ( Dm/ D*). To investigate the influence of fracture coating minerals on matrix diffusion, ten of the diffusion cells represented paired samples from the same depth interval in which one sample contained a fracture surface with mineral coatings and the other sample consisted of only pure matrix. The log of ( Dm/ D*) was found to be positively correlated with both the matrix porosity and the log of matrix permeability. A multiple linear regression analysis indicated that both parameters contributed significantly to the regression at the 95% confidence level. However, the log of the matrix diffusion coefficient was more highly-correlated with the log of matrix permeability than with matrix porosity, which suggests that matrix diffusion coefficients, like matrix permeabilities, have a greater dependence on the interconnectedness of matrix porosity than on the matrix porosity itself. The regression equation for the volcanic rocks was found to provide satisfactory predictions of log( Dm/ D*) for other types of rocks with similar ranges of matrix porosity and permeability as the volcanic rocks, but it did a poorer job predicting log( Dm/ D*) for rocks with lower porosities and/or permeabilities. The presence of mineral coatings on fracture walls did not appear to have a significant effect on matrix diffusion in the ten paired diffusion cell experiments.

Jurassic-Paleogene intra-oceanic magmatic evolution of the Ankara Mélange, North-Central Anatolia, Turkey

NASA Astrophysics Data System (ADS)

Sarifakioglu, E.; Dilek, Y.; Sevin, M.

2013-11-01

Oceanic rocks in the Ankara Mélange along the Izmir-Ankara-Erzincan suture zone (IAESZ) in North-Central Anatolia include locally coherent ophiolite complexes (~179 Ma and ~80 Ma), seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma), metamorphic rocks with ages of 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (~67-63 Ma). All but the arc rocks occur in a shaly-graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the Middle to Late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB) and island arc tholeiite (IAT) affinities showing moderate to significant LILE enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB) affinities. The arc-related volcanic rocks, lamprophyric dikes and syeno-dioritic plutons exhibit high-K shoshonitic to medium-to high-K calc-alkaline compositions with strong enrichment in LILE, REE and Pb, and initial ϵNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syeno-dioritic plutons) in the southern part. The Early to Late Jurassic and Late Cretaceous epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the Northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the seamount volcanic rocks indicate that the Northern Neotethys was an open ocean with its MORB-type oceanic lithosphere by the Early Triassic. The Latest Cretaceous-Early Paleocene island arc volcanic, dike and plutonic rocks with subalkaline to alkaline geochemical affinities represent intraoceanic magmatism that developed on and across the subduction-accretion complex above a N-dipping, southward-rolling subducted lithospheric slab within the Northern Neotethys. The Ankara Mélange thus exhibits the record of ~120-130 million years of oceanic magmatism in geological history of the Northern Neotethys.

Shear heating and metamorphism in subduction zones, 2. The seismic-aseismic transition at c. 50 km depth.

NASA Astrophysics Data System (ADS)

Castro, A. E.; Spear, F. S.; Kohn, M. J.

2017-12-01

Recent work demonstrates that shear heating, which is required for explaining fore-arc heat flow, reconciles thermal models with pressure-temperature (P-T) conditions determined from exhumed metamorphic rocks, i.e. exhumed rocks are representative of normal subduction. However, the range of subduction conditions on Earth (age, angle and rate of subducting plate, character of overriding plate, coefficient of friction, etc.) implies a ≥250 °C range of corresponding temperatures at the depth of the seismic-aseismic transition (SAT), which is consistently observed at 40-60 km in subduction zones worldwide. Here we show that the predicted rheologies and mineral stabilities for 3 common rock types fail to explain the global consistency of the SAT depth, and we propose that mechanical removal of the weakest rocks is required. Using either realistic thermal models, or P-T conditions recorded by exhumed metamorphic rocks, a substantial subset of depths corresponding with any single petrologic or rheological process falls outside the relatively restricted 40-60 km depth of the SAT. For example, a thermal weakening mechanism (the brittle-ductile transition) implies a wide range of depths, regardless of proposed T (e.g. 20-30 km (300 °C), 25-60 km (400 °C), 35 to >85 km (500 °C), etc). Similarly, individual dehydration reactions span a larger range of depths than observed for the SAT; for example, chlorite-out (metapelites: 35 to >85 km; metabasalts: 40 to >85 km), brucite-out (35-75 km) and serpentine/talc-out (50 to >80 km). The failure of a single petrologic and rheological trigger for these characteristic rocks to produce a consistent SAT depth implies that these rocks do not control the SAT, and consequently must not be abundant at depths below the SAT. That is, these hydrated, weak, and buoyant rocks must be squeezed out of the subduction system, although subduction of discontinuous blobs or lenses to greater depth, e.g. to feed arc volcanoes, may occur. The SAT instead may represent progressive strengthening of the subduction interface through mechanical exclusion of weak rocks and formation of stiffer minerals with increasing temperature and depth. Ultimately, as the strengths of the slab and mantle wedge converge at c. 80 km depth, mechanical coupling occurs, driving mantle wedge convection.

Role of replacement in the genesis of anorthosite in the Boehls Butte area, Idaho.

USGS Publications Warehouse

Hietanen, A.

1986-01-01

In this area in N Idaho, three large and numerous small lenses of layered to massive anorthosite consisting of two, and locally three, types of plagioclase with minor hornblende and mica occur in aluminium silicate-rich garnet mica schist. In most of this anorthosite, megacrysts of andesine with bytownite inclusions are embedded in a fine-grained groundmass of bytownite or anorthite; locally, labradorite occurs rather than andesine. Some labradorite laths show Carlsbad twinning and rims of andesine around anorthite inclusions. Along the contacts, lenses of fine-grained bytownite anorthosite with some hornblende or garnet and quartz are common. These lenses could represent calcic parent rocks converted to two-plagioclase rocks by partial replacement of bytownite by andesine. -R.A.H.

Petrological, geochemical, isotopic, and geochronological constraints for the Late Devonian-Early Carboniferous magmatism in SW Gondwana (27-32°LS): an example of geodynamic switching

NASA Astrophysics Data System (ADS)

Dahlquist, Juan A.; Alasino, Pablo H.; Basei, Miguel A. S.; Morales Cámera, Matías M.; Macchioli Grande, Marcos; da Costa Campos Neto, Mario

2018-04-01

We report a study integrating 13 new U-Pb LA-MC-ICP-MS zircon ages and Hf-isotope data from dated magmatic zircons together with complete petrological and whole-rock geochemistry data for the dated granitic rocks. Sample selection was strongly based on knowledge reported in previous investigations. Latest Devonian-Early Carboniferous granite samples were collected along a transect of 900 km, from the inner continental region (present-day Eastern Sierras Pampeanas) to the magmatic arc (now Western Sierras Pampeanas and Frontal Cordillera). Based on these data together with ca. 100 published whole-rock geochemical analyses we conclude that Late Devonian-Early Carboniferous magmatism at this latitude represents continuous activity (ranging from 322 to 379 Ma) on the pre-Andean margin of SW Gondwana, although important whole-rock and isotopic compositional variations occurred through time and space. Combined whole-rock chemistry and isotope data reveal that peraluminous A-type magmatism started in the intracontinental region during the Late Devonian, with subsequent development of synchronous Carboniferous peraluminous and metaluminous A-type magmatism in the retro-arc region and calc-alkaline magmatism in the western paleomargin. We envisage that magmatic evolution was mainly controlled by episodic fluctuations in the angle of subduction of the oceanic plate (between flat-slab and normal subduction), supporting a geodynamic switching model. Subduction fluctuations were relatively fast (ca. 7 Ma) during the Late Devonian and Early Carboniferous, and the complete magmatic switch-off and switch-on process lasted for 57 Ma. Hf T DM values of zircon (igneous and inherited) from some Carboniferous peraluminous A-type granites in the retro-arc suggest that Gondwana continental lithosphere formed during previous orogenies was partly the source of the Devonian-Carboniferous granitic magmas, thus precluding the generation of the parental magmas from exotic terranes.

Rockbursting Potential of Kimberlite: A Case Study of Diavik Diamond Mine

NASA Astrophysics Data System (ADS)

Leveille, Paul; Sepehri, Mohammadali; Apel, Derek B.

2017-12-01

The research described in this paper provides information about the rockbursting potential of kimberlite. Kimberlite is a diamond-bearing rock found in deposits around the world including northern Canada. This paper outlines three methods for the prediction of rockbursts based on the properties of a rock. The methods include the: strain energy index, strain energy density, and rock brittleness. Kimberlite samples collected from Diavik, a diamond mine in northern Canada, were tested to define the rock's uniaxial compressive strength, tensile strength, and hysteresis loop. The samples were separated into sub-rock types based on their descriptions from the mine geologists. The results indicate that it is possible to produce rockbursts in kimberlite. It was also observed that the sub-rock types had a range of rockbursting properties. Some types of kimberlite exhibited little to no potential for producing bursts, while other types potentially could produce violent bursts. The diverse nature of kimberlite indicates that the rockbursting properties of the rock should not be generalized and are dependent on the sub-rock type being encountered.

Mineral deposit densities for estimating mineral resources

USGS Publications Warehouse

Singer, Donald A.

2008-01-01

Estimates of numbers of mineral deposits are fundamental to assessing undiscovered mineral resources. Just as frequencies of grades and tonnages of well-explored deposits can be used to represent the grades and tonnages of undiscovered deposits, the density of deposits (deposits/area) in well-explored control areas can serve to represent the number of deposits. Empirical evidence presented here indicates that the processes affecting the number and quantity of resources in geological settings are very general across many types of mineral deposits. For podiform chromite, porphyry copper, and volcanogenic massive sulfide deposit types, the size of tract that geologically could contain the deposits is an excellent predictor of the total number of deposits. The number of mineral deposits is also proportional to the type’s size. The total amount of mineralized rock is also proportional to size of the permissive area and the median deposit type’s size. Regressions using these variables provide a means to estimate the density of deposits and the total amount of mineralization. These powerful estimators are based on analysis of ten different types of mineral deposits (Climax Mo, Cuban Mn, Cyprus massive sulfide, Franciscan Mn, kuroko massive sulfide, low-sulfide quartz-Au vein, placer Au, podiform Cr, porphyry Cu, and W vein) from 108 permissive control tracts around the world therefore generalizing across deposit types. Despite the diverse and complex geological settings of deposit types studied here, the relationships observed indicate universal controls on the accumulation and preservation of mineral resources that operate across all scales. The strength of the relationships (R 2=0.91 for density and 0.95 for mineralized rock) argues for their broad use. Deposit densities can now be used to provide a guideline for expert judgment or used directly for estimating the number of most kinds of mineral deposits.

An experimental study of the carbonation of serpentinite and partially serpentinised peridotites

NASA Astrophysics Data System (ADS)

Lacinska, Alicja M.; Styles, Michael T.; Bateman, Keith; Hall, Matthew; Brown, Paul D.

2017-06-01

In situ sequestration of CO2 in mantle peridotites has been proposed as a method to alleviate the amount of anthropogenic CO2 in the atmosphere. This study presents the results of eight-month long laboratory fluid-rock experiments on representative mantle rocks from the Oman-United Arab Emirates ophiolite to investigate this process. Small core samples (3 cm long) were reacted in wet supercritical CO2 and CO2-saturated brine at 100 bar and 70°C. The extent of carbonate formation, and hence the degree of carbon sequestration, varied greatly depending on rock type, with serpentinite (lizardite-dominated) exhibiting the highest capacity, manifested by the precipitation of magnesite MgCO3 and ferroan magnesite (Mg,Fe)CO3. The carbonate precipitation occurred predominantly on the surface of the core and subordinately within cross-cutting fractures. The extent of the CO2 reactions appeared to be principally controlled by the chemical and mineralogical composition of the rock, as well as the rock texture, with all these factors influencing the extent and rate of mineral dissolution and release of Mg and Fe for subsequent reaction with the CO2. It was calculated that ≈ 0.7 g of CO2 was captured by reacting ≈ 23 g of serpentinite, determined by the mass of magnesite formed. This equates to ≈ 30 kg CO2 per tonne of host rock, equivalent to ≈ 3% carbonation in half a year. However, recycling of carbonate present in veins within the original rock sample could mean that the overall amount is around 2%. The increased reactivity of serpentinite was associated with preferential dissolution of more reactive types of serpentine minerals and brucite, that were mainly present in the cross-cutting veins. The bulk of the serpentinite rock was little affected. This study, using relatively short term experiments, suggests that serpentinite might be a good host rock for CO2 sequestration, although long term experiments might prove that dunite and harzburgite could be an effective in an engineered system of CCSM. Wet scCO2 proved to be chemically aggressive than CO2-saturated brine and its ingress along fractures and grain boundaries resulted in greater host rock dissolution and subsequent carbonate precipitation.

Rock type discrimination techniques using Landsat and Seasat image data

NASA Technical Reports Server (NTRS)

Blom, R.; Abrams, M.; Conrad, C.

1981-01-01

Results of a sedimentary rock type discrimination project using Seasat radar and Landsat multispectral image data of the San Rafael Swell, in eastern Utah, are presented, which has the goal of determining the potential contribution of radar image data to Landsat image data for rock type discrimination, particularly when the images are coregistered. The procedure employs several images processing techniques using the Landsat and Seasat data independently, and then both data sets are coregistered. The images are evaluated according to the ease with which contacts can be located and rock units (not just stratigraphically adjacent ones) separated. Results show that of the Landsat images evaluated, the image using a supervised classification scheme is the best for sedimentary rock type discrimination. Of less value, in decreasing order, are color ratio composites, principal components, and the standard color composite. In addition, for rock type discrimination, the black and white Seasat image is less useful than any of the Landsat color images by itself. However, it is found that the incorporation of the surface textural measures made from the Seasat image provides a considerable and worthwhile improvement in rock type discrimination.

An evaluation of thematic mapper simulator data for the geobotanical discrimination of rock types in Southwest Oregon

NASA Technical Reports Server (NTRS)

Weinstock, K. J.; Morrissey, L. A.

1984-01-01

Rock type identification may be assisted by the use of remote sensing of associated vegetation, particularly in areas of dense vegetative cover where surface materials are not imaged directly by the sensor. The geobotanical discrimination of ultramafic parent materials was investigated and analytical techniques for lithologic mapping and mineral exploration were developed. The utility of remotely sensed data to discriminate vegetation types associated with ultramafic parent materials in a study area in southwest Oregon were evaluated. A number of specific objectives were identified, which include: (1) establishment of the association between vegetation and rock types; (2) examination of the spectral separability of vegetation types associated with rock types; (3) determination of the contribution of each TMS band for discriminating vegetation associated with rock types and (4) comparison of analytical techniques for spectrally classifying vegetation.

Shock metamorphism of planetary silicate rocks and sediments: Proposal for an updated classification system

NASA Astrophysics Data System (ADS)

Stöffler, Dieter; Hamann, Christopher; Metzler, Knut

2018-01-01

We reevaluate the systematics and geologic setting of terrestrial, lunar, Martian, and asteroidal "impactites" resulting from single or multiple impacts. For impactites derived from silicate rocks and sediments, we propose a unified and updated system of progressive shock metamorphism. "Shock-metamorphosed rocks" occur as lithic clasts or melt particles in proximal impactites at impact craters, and rarely in distal impactites. They represent a wide range of metamorphism, typically ranging from unshocked to shock melted. As the degree of shock metamorphism, at a given shock pressure, depends primarily on the mineralogical composition and the porosity of a rock or sediment sample, different shock classification systems are required for different types of planetary rocks and sediments. We define shock classification systems for eight rock and sediment classes which are assigned to three major groups of rocks and sediments (1) crystalline rocks with classes F, M, A, and U; (2) chondritic rocks (class C); and (3) sedimentary rocks and sediments with classes SR, SE, and RE. The abbreviations stand for felsic (F), mafic (M), anorthositic (A), ultramafic (U), sedimentary rocks (SR), unconsolidated sediments (SE), and regoliths (RE). In each class, the progressive stages of shock metamorphism are denominated S1 to Sx. These progressive shock stages are introduced as: S1-S7 for F, S1-S7 for M, S1-S6 for A, S1-S7 for U, S1-S7 for C, S1-S7 for SR, S1-S5 for SE, and S1-S6 for RE. S1 stands for "unshocked" and Sx (variable between S5 and S7) stands for "whole rock melting." We propose a sequence of symbols characterizing the degree of shock metamorphism of a sample, i.e., F-S1 to F-S7 with the option to add the tabulated pressure ranges (in GPa) in parentheses.

Petrology of unshocked crystalline rocks and shock effects in lunar rocks and minerals

USGS Publications Warehouse

Chao, E.C.T.; James, O.B.; Minkin, J.A.; Boreman, J.A.; Jackson, E.D.; Raleigh, C.B.

1970-01-01

On the basis of rock modes, textures, and mineralogy, unshocked crystalline rocks are classified into a dominant ilmenite-rich suite (subdivided into intersertal, ophitic, and hornfels types) and a subordinate feldspar-rich suite (subdivided into poikilitic and granular types). Weakly to moderately shocked rocks show high strain-rate deformation and solid-state transformation of minerals to glasses; intensely shocked rocks are converted to rock glasses. Data on an unknown calcium-bearing iron metasilicate are presented.

High resolution HH-XRF scanning and XRD modelling as a tool in sedimentological analysis - A case study from the Enreca-3 core, Bach Long Vi Island, Vietnam

NASA Astrophysics Data System (ADS)

Rizzi, Malgorzata; Hemmingsen Schovsbo, Niels; Korte, Christoph; Bryld Wessel Fyhn, Michael

2017-04-01

To improve the understanding and interpretation of the depositional environment of a late Oligocene lacustrine organic rich oil-prone source rock succession, 2464 hand held (HH)-XRF measurements were made systematically on the 500 m long, continuous core from the fully cored Enreca-3 well. This core, drilled on the remote Bach Long Vi Island, northern Gulf of Tonkin, offshore Vietnam, represents a deep lake succession alternating between lacustrine pelagic dominated sediments interrupted by hyperpycnal turbidites, high density turbidites and debris flows [1, 2]. From a combined HH-XRF-XRD data set, multivariate data analysis and regression models are used to type the rock and to predict the XRD mineral composition based on HH-XRF composition. The rock types and the modelled mineral composition highlight the geochemical variations of the sediment and allows for direct comparison with sedimentological processes and facies changes. The modeling also depicts the cyclic alteration of rock types that are present on many different scales ranging from centimeters to hundreds of meters [1, 2]. The sedimentological and geochemical variations observed throughout the cored section reflects fluctuating paleoclimate, tectonism and hinterland condition controlling the depositional setting, which may provide a deeper understanding of the deposition of this and similar Paleogene syn-rift succession in the South China Sea region. It allows furthermore the development of a more generalized depositional model relevant for other deep-lacustrine syn-rift basins. [1] Petersen et al. (2014) Journal of Petroleum Geology, 37: 373-389. [2] Hovikoski et al. (2016) Journal of Sedimentary Research, 86(8): 982-1007.

The ratios of carbon and non-radiogenic helium and argon isotopes in the mantle and crustal rocks

NASA Technical Reports Server (NTRS)

Lokhov, K.; Levsky, L.

1994-01-01

The studies of the relations of carbon and primary isotopes of noble gases were carried out on the natural gases and on the mantle rocks from the mantle M-type sources, which represent the degassed mantle reservoir (MORB's). These works has the aim of estimation of the values of the C/3He ratios in the deep mantle fluids to determine the flux of the mantle CO2 on the basis of known flux of primary mantle 3He. It was found, that in the natural gases the values of the C/3He ratios fall into the range from 1 times E plus 6 to 1 times E plus 15, and in the fluids of MORB's are constant near 2 times E plus 9. We have studied the mantle rocks from the relatively undergassed mantle P minus type sources: continental; Baikal Rift (Siberia), Mongolia, Catalonia (Spain), Pannonia Depression (central Europe) and ocean; Spietzbergen isl., Hawaii isl., Canarian isl. It ws found, that in mantle xenolites and the host alkaline basalts from the continental rifts and ocean islands, the values of the C/3He ratios fall into the range from E plus 11 to E plus 15 (and this result needed to be explained; the higher carbon to helium ratios is relatively undergassed mantle reservoir compared with the degassed one, requires whether hilly compatibility of helium compared with carbon, whether additional flux of 3He to the degassed mantle reservoir). From the other hand it was found that in the mantle rocks from the sources of P minus and M minus types, continental carbonatites, the values of the C/36Ar ratios are constant in the range from E plus 9 to E plus 10, the close values have the MORB's also.

Contrasting cratonal provenances for upper Cretaceous Valle Group quartzite clasts, Baja California

USGS Publications Warehouse

Kimbrough, D.L.; Abbott, G.; Smith, D.P.; Mahoney, J.B.; Moore, Thomas E.; Gehrels, G.E.; Girty, G.H.; Cooper, John D.

2006-01-01

Late Cretaceous Valle Group forearcbasin deposits on the Vizcaino Peninsula of Baja California Sur are dominated by firstcycle arc-derived volcanic-plutonic detritus derived from the adjacent Peninsular Ranges batholith. Craton-derived quartzite clasts are a minor but ubiquitous component in Valle Group conglomerates. The source of these clasts has implications for tectonic reconstructions and sediment-dispersal paths along the paleo-North American margin. Three strongly contrasting types of quartzite are recognized based on petrology and detrital zircon U-Pb geochronology. The first type is ultramature quartz arenite with well-rounded, highly spherical zircon grains. Detrital zircon ages from this type are nearly all >1.8 Ga with age distributions that closely match the distinctive Middle-Late Ordovician Peace River arch detrital signature of the Cordilleran margin. This type has been previously recognized from prebatholithic rocks in northeast Baja California (San Felipe quartzite). A second quartzite type is subarkosic sandstone with strong affinity to southwestern North America; important features of the age spectra are ~1.0-1.2 Ga, 1.42 and 1.66 Ga peaks representing cratonal basement, 500-300 Ma grains interpreted as recycled Appalachian-derived grains, and 284- 232 Ma zircon potentially derived from the Early Permian-Middle Triassic east Mexico arc. This quartzite type could have been carried to the continental margin during Jurassic time as outboard equivalents of Colorado Plateau eolianites. The third quartzite type is quartz pebble conglomerate with significant ~900- 1400 Ma and ~450-650 Ma zircon components, as well as mid- and late Paleozoic grains. The source of this type of quartzite is more problematic but could match either upper Paleozoic strata in the Oaxaca terrane of southern Mexico or a southwestern North America source. The similarity of detrital 98 zircon spectra in all three Valle Group quartzite types to rocks of the adjacent Cordilleran margin support previous interpretations that Valle Group forearc basin sediments were deposited in proximity to rocks on the mainland of northwest Mexico and southwestern United States.

Cataclastic rocks of the San Gabriel fault—an expression of deformation at deeper crustal levels in the San Andreas fault zone

NASA Astrophysics Data System (ADS)

Anderson, J. Lawford; Osborne, Robert H.; Palmer, Donald F.

1983-10-01

The San Gabriel fault, a deeply eroded late Oligocene to middle Pliocene precursor to the San Andreas, was chosen for petrologic study to provide information regarding intrafault material representative of deeper crustal levels. Cataclastic rocks exposed along the present trace of the San Andreas in this area are exclusively a variety of fault gouge that is essentially a rock flour with a quartz, feldspar, biotite, chlorite, amphibole, epidote, and Fe-Ti oxide mineralogy representing the milled-down equivalent of the original rock (Anderson and Osborne, 1979; Anderson et al., 1980). Likewise, fault gouge and associated breccia are common along the San Gabriel fault, but only where the zone of cataclasis is several tens of meters wide. At several localities, the zone is extremely narrow (several centimeters), and the cataclastic rock type is cataclasite, a dark, aphanitic, and highly comminuted and indurated rock. The cataclastic rocks along the San Gabriel fault exhibit more comminution than that observed for gouge along the San Andreas. The average grain diameter for the San Andreas gouge ranges from 0.01 to 0.06 mm. For the San Gabriel cataclastic rocks, it ranges from 0.0001 to 0.007 mm. Whereas the San Andreas gouge remains particulate to the smallest grain-size, the ultra-fine grain matrix of the San Gabriel cataclasite is composed of a mosaic of equidimensional, interlocking grains. The cataclastic rocks along the San Gabriel fault also show more mineralogiec changes compared to gouge from the San Andreas fault. At the expense of biotite, amphibole, and feldspar, there is some growth of new albite, chlorite, sericite, laumontite, analcime, mordenite (?), and calcite. The highest grade of metamorphism is laumontite-chlorite zone (zeolite facies). Mineral assemblages and constrained uplift rates allow temperature and depth estimates of 200 ± 30° C and 2-5 km, thus suggesting an approximate geothermal gradient of ~50°C/km. Such elevated temperatures imply a moderate to high stress regime for the San Andreas, which is consistent with experimental rock failure studies. Moreover, these results suggest that the previously observed lack of heat flow coaxial with the fault zone may be the result of dissipation rather than low stress. Much of the mineralogy of the cataclastic rocks is still relict from the earlier igneous or metamorphic history of the protolith; porphyroclasts, even in the most deformed rocks, consist of relict plagioclase (oligoclase to andesine), alkali feldspar, quartz, biotite, amphibole, epidote, allanite, and Fe-Ti oxides (ilmenite and magnetite). We have found no significant development of any clay minerals (illite, kaolinite, or montmorillonite). For many sites, the compositions of these minerals directly correspond to the mineral compositions in rock types on one or both sides of the fault. Whole rock major and trace element chemistry coupled with mineral compositions show that mixing within the zone of cataclasis is not uniform, and that originally micaceous foliated, or physically more heterogeneous rock units may contribute a disproportionally large amount to the resultant intrafault material. As previously found for the gouge along the San Andreas, chemical mobility is not a major factor in the formation of cataclastic rocks of the San Gabriel fault. We see only minor changes for Si and alkalies; however, there is a marked mobility of Li, which is a probable result of the alteration and formation of new mica minerals. The gouge of the San Andreas and San Gabriel faults probably formed by cataclastic flow. There is some indication, presently not well constrained, that the fine-grained matrix of the cataclasite of from the San Gabriel fault formed in response to superplastic flow.

Spinel and plagioclase peridotites of the Nain ophiolite (Central Iran): Evidence for the incipient stage of oceanic basin formation

NASA Astrophysics Data System (ADS)

Pirnia, Tahmineh; Saccani, Emilio; Arai, Shoji

2018-06-01

The Nain ophiolites crop out along the western border of the central East Iran Microcontinent (CEIM) and consist of an ophiolitic mélange in which pargasite-bearing spinel and plagioclase mantle lherzolites are largely represented. Whole-rock and mineral chemistry data suggest that these rocks record the complex history of the asthenospheric and lithospheric mantle evolution. The spinel lherzolites have experienced low-degree ( 5%) partial melting and contain clinopyroxenes with positive Eu anomalies (Eu/Eu* = 1.10-1.48) suggesting that the partial melting occurred under oxidized conditions (fayalite-magnetite-quartz -0.8 to +1.3). The pargasite and coexisting clinopyroxene in these rocks are depleted in light rare earth elements (LREE) (mean chondrite-normalized CeN/SmN = 0.045). The depleted chemistry of this amphibole reflects metasomatism during interaction with H2O-rich subalkaline mafic melts, most likely concurrently with or after the partial melting of the spinel lherzolites. The plagioclase lherzolites were subsequently formed by the subsolidus recrystallization of spinel lherzolites under plagioclase facies conditions as a result of mantle uprising, as evidenced by: (1) the development of plagioclase rims around the spinels; (2) plagioclase + orthopyroxene exsolution textures within some clinopyroxene grains; (3) an increase in plagioclase modal content coupled with an increase in modal olivine and a decrease in modal pyroxene and pargasite; (4) coincident decreases in Al, Mg, and Ni, and increases in Cr, Ti, and Fe in spinel, as well as decreases in Al and Ca, and increases in Cr and Ti in pyroxene and pargasite; and (5) the identical whole rock compositions of the spinel and plagioclase lherzolites, which rules out a magmatic origin for the plagioclase in these units. The Nain lherzolites have similar whole-rock and mineral geochemical compositions to subcontinental peridotites that are typically representative of Iberia-type rifted continental margins and ocean-continent transition zones (OCTZ), suggesting that they formed during the early stages of the evolution of the Nain oceanic basin. This means that the Nain lherzolites represent the Triassic-Jurassic western border of the CEIM or alternatively an associated OCTZ.

Characterising the metamorphic discontinuity across the Main Central Thrust Zone of eastern-central Nepal

NASA Astrophysics Data System (ADS)

Wang, Jiamin; Zhang, Jinjiang; Wei, Chunjing; Rai, SantaMan; Wang, Meng; Qian, Jiahui

2015-04-01

The Main Central Thrust Zone (MCTZ) is a top-to-south shear zone that has exhumed the high-grade Himalayan metamorphic core during the orogeny. Identifying the location of the MCTZ is a major challenge and the characteristics of the metamorphic discontinuity remain under debate. To clarify this issue, petrologic and thermobarometric studies were carried out on metapelites and metapsammites that were collected from the basal Nyalam transect in eastern-central Nepal. Results reveal that the metamorphic discontinuity across the MCTZ is characterised by a continuous increase in peak P-T conditions toward higher structural levels, a relatively high field temperature gradient (25-50 °C km-1) and different types of P-T paths. Specifically, representative rocks in the MCTZ record sub-solidus peak conditions (637 ± 16 °C and 9.2 ± 1.0 kbar) and a hairpin-type P-T path. The lower GHC rocks record supra-solidus peak conditions (690 ± 32 °C and 10.3 + 1.1/-1.4 kbar) and a prograde loading path with a small segment of decompression. The presence of a high field pressure gradient across the MCTZ is debatable in the Nyalam transect due to the large uncertainties in pressure estimates. Comparison between obtained P-T results and model predictions indicates that a multiple thrusting process dominated exhumation of the MCTZ and lower GHC rocks, while crustal flow contributed partly to exhumation of the lower GHC rocks.

Age of Barrier Canyon-style rock art constrained by cross-cutting relations and luminescence dating techniques

PubMed Central

Pederson, Joel L.; Chapot, Melissa S.; Simms, Steven R.; Sohbati, Reza; Rittenour, Tammy M.; Murray, Andrew S.; Cox, Gary

2014-01-01

Rock art compels interest from both researchers and a broader public, inspiring many hypotheses about its cultural origin and meaning, but it is notoriously difficult to date numerically. Barrier Canyon-style (BCS) pictographs of the Colorado Plateau are among the most debated examples; hypotheses about its age span the entire Holocene epoch and previous attempts at direct radiocarbon dating have failed. We provide multiple age constraints through the use of cross-cutting relations and new and broadly applicable approaches in optically stimulated luminescence dating at the Great Gallery panel, the type section of BCS art in Canyonlands National Park, southeastern Utah. Alluvial chronostratigraphy constrains the burial and exhumation of the alcove containing the panel, and limits are also set by our related research dating both a rockfall that removed some figures and the rock’s exposure duration before that time. Results provide a maximum possible age, a minimum age, and an exposure time window for the creation of the Great Gallery panel, respectively. The only prior hypothesis not disproven is a late Archaic origin for BCS rock art, although our age result of A.D. ∼1–1100 coincides better with the transition to and rise of the subsequent Fremont culture. This chronology is for the type locality only, and variability in the age of other sites is likely. Nevertheless, results suggest that BCS rock art represents an artistic tradition that spanned cultures and the transition from foraging to farming in the region. PMID:25157162

3D pore-type digital rock modeling of natural gas hydrate for permafrost and numerical simulation of electrical properties

NASA Astrophysics Data System (ADS)

Dong, Huaimin; Sun, Jianmeng; Lin, Zhenzhou; Fang, Hui; Li, Yafen; Cui, Likai; Yan, Weichao

2018-02-01

Natural gas hydrate is being considered as an alternative energy source for sustainable development and has become a focus of research throughout the world. In this paper, based on CT scanning images of hydrate reservoir rocks, combined with the microscopic distribution of hydrate, a diffusion limited aggregation (DLA) model was used to construct 3D hydrate digital rocks of different distribution types, and the finite-element method was used to simulate their electrical characteristics in order to study the influence of different hydrate distribution types, hydrate saturation and formation of water salinity on electrical properties. The results show that the hydrate digital rocks constructed using the DLA model can be used to characterize the microscopic distribution of different types of hydrates. Under the same conditions, the resistivity of the adhesive hydrate digital rock is higher than the cemented and scattered type digital rocks, and the resistivity of the scattered hydrate digital rock is the smallest among the three types. Besides, the difference in the resistivity of the different types of hydrate digital rocks increases with an increase in hydrate saturation, especially when the saturation is larger than 55%, and the rate of increase of each of the hydrate types is quite different. Similarly, the resistivity of the three hydrate types decreases with an increase in the formation of water salinity. The single distribution hydrate digital rock constructed, combined with the law of microscopic distribution and influence of saturation on the electrical properties, can effectively improve the accuracy of logging identification of hydrate reservoirs and is of great significance for the estimation of hydrate reserves.

The main features of the Uralian Paleozoic magmatism and the epioceanic nature of the orogen

NASA Astrophysics Data System (ADS)

Fershtater, G. B.

2013-02-01

The 2000 km Uralian Paleozoic orogen is situated on the western flank of the Uralo-Mongolian folded belt. It is characterized by an abundant variety of magmatic rocks and related ore deposits. Uralian Paleozoic magmatism is entirely subduction-related. It is proposed that the Uralian orogen represents a cold mobile belt in which the mantle temperature was 200 to 500 °C cooler than in the adjacent areas; a situation which is similar to the modern West Pacific Triangle Zone including Indonesia, the Philippine Islands, and southern Asia. During the course of the geological evolution of the Uralian orogen, the nature of the magmatism has changed from basic rocks of indisputable mantle origin (460-390 Ma) to mantle-crust gabbro-granitic complexes (370-315 Ma) followed by pure crustal granite magmatism (290-250 Ma). This order in rock type and age reflects the evolution of Paleozoic magmatic complexes from the beginning of subduction to the final stages of the orogen development.

Anisotropy of diamagnetic susceptibility in Thassos marble: A comparison between measured and modeled data

NASA Astrophysics Data System (ADS)

de Wall, Helga; Bestmann, Michel; Ullemeyer, Klaus

2000-11-01

A study of shear zones within the calcite marble complex of the island of Thassos (Greece) shows that the low field anisotropy of magnetic susceptibility (AMS)-technique can be successfully applied to diamagnetic rocks for characterizing rock fabrics. The strain path involves both an early pure shear stage and a simple shear overprint that is documented by a transition from triaxial (neutral) to uniaxial (prolate) shapes of AMS ellipsoids. The maximum susceptibility is oriented perpendicular to the rock foliation, reflecting the preferred orientation of calcite c-axes in the protolith as well as in the mylonites. For three samples that represent different types of calcite fabrics, the AMS was recalculated from neutron and electron backscatter diffraction textural data. A comparison of the measured and modeled data shows a good coincidence for the orientation of the principal AMS axes and for the recalculated anisotropy data. Both measured and modeled data sets reflect the change from neutral to distinct prolate ellipsoids during progressive deformation.

Chemical mixing model studies of lunar orbital geochemical data - Apollo 16 and 17 highlands compositions

NASA Technical Reports Server (NTRS)

Spudis, P. D.; Hawke, B. R.

1982-01-01

Chemical mixing model studies of lunar geochemical data for the central and Taurus-Littrow lunar highlands were performed utilizing pristine highland rock types as end member compositions. The central highlands show considerable diversity in composition; anorthosite is the principal rock type in the Apollo 16/Descartes region, while norite predominates in the highlands west of the landing site. This change in crustal composition is coincident with a major color boundary seen in earth-based multispectral data and probably represents the presence of distinct geochemical provinces within the central highlands. The Taurus-Littrow highlands are dominated by norite; anorthosite is far less abundant than in the central highlands. This suggests that the impact target for the Serenitatis basin was different than that of the Nectaris basin and further strengthens the hypothesis that the lunar highlands are petrologically heterogeneous on a regional basis. It is suggested that the lunar highlands should be viewed in terms of geochemical provinces that have undergone distinct and complex igneous and impact histories.

The Friction Factor in the Forchheimer Equation for Rock Fractures

NASA Astrophysics Data System (ADS)

Zhou, Jia-Qing; Hu, Shao-Hua; Chen, Yi-Feng; Wang, Min; Zhou, Chuang-Bing

2016-08-01

The friction factor is an important dimensionless parameter for fluid flow through rock fractures that relates pressure head loss to average flow velocity; it can be affected by both fracture geometry and flow regime. In this study, a theoretical formula form of the friction factor containing both viscous and inertial terms is formulated by incorporating the Forchheimer equation, and a new friction factor model is proposed based on a recent phenomenological relation for the Forchheimer coefficient. The viscous term in the proposed formula is inversely proportional to Reynolds number and represents the limiting case in Darcy flow regime when the inertial effects diminish, whereas the inertial term is a power function of the relative roughness and represents a limiting case in fully turbulent flow regime when the fracture roughness plays a dominant role. The proposed model is compared with existing friction factor models for fractures through parametric sensitivity analyses and using experimental data on granite fractures, showing that the proposed model has not only clearer physical significance, but also better predictive performance. By accepting proper percentages of nonlinear pressure drop to quantify the onset of Forchheimer flow and fully turbulent flow, a Moody-type diagram with explicitly defined flow regimes is created for rock fractures of varying roughness, indicating that rougher fractures have a large friction factor and are more prone to the Forchheimer flow and fully turbulent flow. These findings may prove useful in better understanding of the flow behaviors in rock fractures and improving the numerical modeling of non-Darcy flow in fractured aquifers.

Environmentally Friendly, Rheoreversible, Hydraulic-fracturing Fluids for Enhanced Geothermal Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shao, Hongbo; Kabilan, Senthil; Stephens, Sean A.

Cost-effective creation of high-permeability reservoirs inside deep crystalline bedrock is the primary challenge for the feasibility of enhanced geothermal systems (EGS). Current reservoir stimulation entails adverse environmental impacts and substantial economic costs due to the utilization of large volumes of water “doped” with chemicals including rheology modifiers, scale and corrosion inhibitors, biocides, friction reducers among others where, typically, little or no information of composition and toxicity is disclosed. An environmentally benign, CO2-activated, rheoreversible fracturing fluid has recently been developed that significantly enhances rock permeability at effective stress significantly lower than current technology. We evaluate the potential of this novel fracturingmore » fluid for application on geothermal sites under different chemical and geomechanical conditions, by performing laboratory-scale fracturing experiments with different rock sources under different confining pressures, temperatures, and pH environments. The results demonstrate that CO2-reactive aqueous solutions of environmentally amenable Polyallylamine (PAA) represent a highly versatile fracturing fluid technology. This fracturing fluid creates/propagates fracture networks through highly impermeable crystalline rock at significantly lower effective stress as compared to control experiments where no PAA was present, and permeability enhancement was significantly increased for PAA compared to conventional hydraulic fracturing controls. This was evident in all experiments, including variable rock source/type, operation pressure and temperature (over the entire range for EGS applications), as well as over a wide range of formation-water pH values. This versatile novel fracturing fluid technology represents a great alternative to industrially available fracturing fluids for cost-effective and competitive geothermal energy production.« less

Comparison of natural gases accumulated in Oligocene strata with hydrous pyrolysis gases from Menilite Shales of the Polish Outer Carpathians

USGS Publications Warehouse

Kotarba, M.J.; Curtis, John B.; Lewan, M.D.

2009-01-01

This study examined the molecular and isotopic compositions of gases generated from different kerogen types (i.e., Types I/II, II, IIS and III) in Menilite Shales by sequential hydrous pyrolysis experiments. The experiments were designed to simulate gas generation from source rocks at pre-oil-cracking thermal maturities. Initially, rock samples were heated in the presence of liquid water at 330 ??C for 72 h to simulate early gas generation dominated by the overall reaction of kerogen decomposition to bitumen. Generated gas and oil were quantitatively collected at the completion of the experiments and the reactor with its rock and water was resealed and heated at 355 ??C for 72 h. This condition simulates late petroleum generation in which the dominant overall reaction is bitumen decomposition to oil. This final heating equates to a cumulative thermal maturity of 1.6% Rr, which represents pre-oil-cracking conditions. In addition to the generated gases from these two experiments being characterized individually, they are also summed to characterize a cumulative gas product. These results are compared with natural gases produced from sandstone reservoirs within or directly overlying the Menilite Shales. The experimentally generated gases show no molecular compositions that are distinct for the different kerogen types, but on a total organic carbon (TOC) basis, oil prone kerogens (i.e., Types I/II, II and IIS) generate more hydrocarbon gas than gas prone Type III kerogen. Although the proportionality of methane to ethane in the experimental gases is lower than that observed in the natural gases, the proportionality of ethane to propane and i-butane to n-butane are similar to those observed for the natural gases. ??13C values of the experimentally generated methane, ethane and propane show distinctions among the kerogen types. This distinction is related to the ??13C of the original kerogen, with 13C enriched kerogen generating more 13C enriched hydrocarbon gases than kerogen less enriched in 13C. The typically assumed linear trend for ??13C of methane, ethane and propane versus their reciprocal carbon number for a single sourced natural gas is not observed in the experimental gases. Instead, the so-called "dogleg" trend, exemplified by relatively 13C depleted methane and enriched propane as compared to ethane, is observed for all the kerogen types and at both experimental conditions. Three of the natural gases from the same thrust unit had similar "dogleg" trends indicative of Menilite source rocks with Type III kerogen. These natural gases also contained varying amounts of a microbial gas component that was approximated using the ????13C for methane and propane determined from the experiments. These approximations gave microbial methane components that ranged from 13-84%. The high input of microbial gas was reflected in the higher gas:oil ratios for Outer Carpathian production (115-1568 Nm3/t) compared with those determined from the experiments (65-302 Nm3/t). Two natural gas samples in the far western part of the study area had more linear trends that suggest a different organic facies of the Menilite Shales or a completely different source. This situation emphasizes the importance of conducting hydrous pyrolysis on samples representing the complete stratigraphic and lateral extent of potential source rocks in determining specific genetic gas correlations. ?? 2009 Elsevier Ltd.

Carbonate-silicate melt immiscibility, REE mineralising fluids, and the evolution of the Lofdal Intrusive Suite, Namibia

NASA Astrophysics Data System (ADS)

Bodeving, Sarah; Williams-Jones, Anthony E.; Swinden, Scott

2017-01-01

The Lofdal Intrusive Suite, Namibia, consists of calcio-carbonatite and silica-undersaturated alkaline intrusive rocks ranging in composition from phono-tephrite to phonolite (and nepheline syenite). The most primitive of these rocks is the phono-tephrite, which, on the basis of its Y/Ho and Nb/Ta ratios, is interpreted to have formed by partial melting of the mantle. Roughly linear trends in major and trace element contents from phono-tephrite to phonolite and nepheline syenite indicate that the latter two rock types evolved from the phono-tephrite by fractional crystallisation. The nepheline syenite, however, has a lower rare earth element (REE) content than the phonolite. The carbonatite has a primitive mantle-normalised REE profile roughly parallel to that of the silica-undersaturated alkaline igneous rocks, although the absolute REE concentrations are higher. Like the phono-tephrite, it also has a mantle Y/Ho ratio. However, the Nb/Ta and Zr/Hf ratios are significantly higher. Moreover, the carbonatite displays strong negative Ta, Zr and Hf anomalies on spidergrams, whereas the silicate rocks display positive anomalies for these elements. Significantly, this behaviour is predicted by the corresponding carbonatite-silicate melt partition coefficients, as is the behaviour of the REE. Based on these observations, we interpret the carbonatite to represent an immiscible liquid that exsolved from the phono-tephrite or possibly the phonolite melt. The result was a calcio-carbonatite that is enriched in the heavy REE (HREE) relative to most other carbonatites. Fluids released from the corresponding magma are interpreted to have been the source of the REE mineralisation that is currently the target of exploration. 2. The composition of feldspar in nepheline syenite, fenite, calcio-carbonatite and phonolite plotted on the feldspar ternary classification diagram modified after Schairer (1950) in terms of the components albite (Ab), orthoclase (Or) and anorthite (An). Note: ANO = anorthosite, SAN = sanidine, OLI = oligoclase, AND = andesine, LAB = labradorite, BYT = bytownite. 3. Composition of the Lofdal mica plotted on the biotite classification diagram of Rieder et al. (1998). 4. Clinopyroxene composition in nepheline syenite and calcio-carbonatite phenocrysts illustrated on the classification ternary for sodic pyroxenes (after Morimoto; 1989). Quad (Q) represents wollastonite, enstatite and ferrosilite of the Mg-Ca-Fe group of pyroxenes. 5. The range of carbonatite compositions illustrated on the carbonatite classification diagram of Gittins and Harmer (1997). 6. Composition of the Lofdal nepheline syenite on the plutonic Total-Alkali-Silica diagram of Wilson (1989). 7. a. A binary plot showing the concentration of Y versus that of Ho in bulk rock samples of the phono-tephrites, phonolites, nepheline syenites and carbonatites. The trend-line represents the mantle value of approximately 27.7 (Sun and McDonough, 1989). b. A binary plot showing the concentration of Nb versus that of Ta in bulk rock samples of the phono-tephrites, phonolites, nepheline syenites and carbonatites. The trend-line represents the mantle value of approximately 17.4 (Sun and McDonough, 1989). c. A binary plot showing the concentration of Zr versus that of Hf in bulk rock samples of the phono-tephrites, phonolites, nepheline syenites and carbonatites. The trend-line represents the mantle value of approximately 36.2 (Sun and McDonough, 1989). 8. A binary plot showing the concentration of K2O versus Na2O in nepheline syenite and fenite.

77 FR 23665 - Procurement List Proposed Additions

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-20

...: Services Service Type/Location: Mailroom Operations, Official Mail Distribution Center, 1 Rock Island Arsenal, Building 132, Rock Island, IL. NPA: The Arc of the Quad Cities Area, Rock Island, IL. Contracting Activity: Dept of the ARMY, W4MM USA Joint Munitions CMD, Rock Island, IL. Service Type/Location: Custodial...

The Cannery Formation--Devonian to Early Permian arc-marginal deposits within the Alexander Terrane, Southeastern Alaska

USGS Publications Warehouse

Karl, Susan M.; Layer, Paul W.; Harris, Anita G.; Haeussler, Peter J.; Murchey, Benita L.

2011-01-01

The Cannery Formation consists of green, red, and gray ribbon chert, siliceous siltstone, graywacke-chert turbidites, and volcaniclastic sandstone. Because it contains early Permian fossils at and near its type area in Cannery Cove, on Admiralty Island in southeastern Alaska, the formation was originally defined as a Permian stratigraphic unit. Similar rocks exposed in Windfall Harbor on Admiralty Island contain early Permian bryozoans and brachiopods, as well as Mississippian through Permian radiolarians. Black and green bedded chert with subordinate lenses of limestone, basalt, and graywacke near Kake on Kupreanof Island was initially correlated with the Cannery Formation on the basis of similar lithology but was later determined to contain Late Devonian conodonts. Permian conglomerate in Keku Strait contains chert cobbles inferred to be derived from the Cannery Formation that yielded Devonian and Mississippian radiolarians. On the basis of fossils recovered from a limestone lens near Kake and chert cobbles in the Keku Strait area, the age of the Cannery Formation was revised to Devonian and Mississippian, but this revision excludes rocks in the type locality, in addition to excluding bedded chert on Kupreanof Island east of Kake that contains radiolarians of Late Pennsylvanian and early Permian age. The black chert near Kake that yielded Late Devonian conodonts is nearly contemporaneous with black chert interbedded with limestone that also contains Late Devonian conodonts in the Saginaw Bay Formation on Kuiu Island. The chert cobbles in the conglomerate in Keku Strait may be derived from either the Cannery Formation or the Saginaw Bay Formation and need not restrict the age of the Cannery Formation, regardless of their source. The minimum age of the Cannery Formation on both Admiralty Island and Kupreanof Island is constrained by the stratigraphically overlying fossiliferous Pybus Formation, of late early and early late Permian age. Because bedded radiolarian cherts on both Admiralty and Kupreanof Islands contain radiolarians as young as Permian, the age of the Cannery Formation is herein extended to Late Devonian through early Permian, to include the early Permian rocks exposed in its type locality. The Cannery Formation is folded and faulted, and its stratigraphic thickness is unknown but inferred to be several hundred meters. The Cannery Formation represents an extended period of marine deposition in moderately deep water, with slow rates of deposition and limited clastic input during Devonian through Pennsylvanian time and increasing argillaceous, volcaniclastic, and bioclastic input during the Permian. The Cannery Formation comprises upper Paleozoic rocks in the Alexander terrane of southeastern Alaska. In the pre-Permian upper Paleozoic, the tectonic setting of the Alexander terrane consisted of two or more evolved oceanic arcs. The lower Permian section is represented by a distinctive suite of rocks in the Alexander terrane, which includes sedimentary and volcanic rocks containing early Permian fossils, metamorphosed rocks with early Permian cooling ages, and intrusive rocks with early Permian cooling ages, that form discrete northwest-trending belts. After restoration of 180 km of dextral displacement of the Chilkat-Chichagof block on the Chatham Strait Fault, these belts consist, from northeast to southwest, of (1) bedded chert, siliceous argillite, volcaniclastic turbidites, pillow basalt, and limestone of the Cannery Formation and the Porcupine Slate of Gilbert and others (1987); (2) greenschist-facies Paleozoic metasedimentary and metavolcanic rocks that have Permian cooling ages; (3) silty limestone and calcareous argillite interbedded with pillow basalt and volcaniclastic rocks of the Halleck Formation and the William Henry Bay area; and (4) intermediate-composition and syenitic plutons. These belts correspond to components of an accretionary complex, contemporary metamorphic rocks, forearc-basin deposits,

Brittleness Effect on Rock Fatigue Damage Evolution

NASA Astrophysics Data System (ADS)

Nejati, Hamid Reza; Ghazvinian, Abdolhadi

2014-09-01

The damage evolution mechanism of rocks is one of the most important aspects in studying of rock fatigue behavior. Fatigue damage evolution of three rock types (onyx marble, sandstone and soft limestone) with different brittleness were considered in the present study. Intensive experimental tests were conducted on the chosen rock samples and acoustic emission (AE) sensors were used in some of them to monitor the fracturing process. Experimental tests indicated that brittleness strongly influences damage evolution of rocks in the course of static and dynamic loading. AE monitoring revealed that micro-crack density induced by the applied loads during different stages of the failure processes increases as rock brittleness increases. Also, results of fatigue tests on the three rock types indicated that the rock with the most induced micro-cracks during loading cycles has the least fatigue life. Furthermore, the condition of failure surfaces of the studied rocks samples, subjected to dynamic and static loading, were evaluated and it was concluded that the roughness of failure surfaces is influenced by loading types and rock brittleness. Dynamic failure surfaces were rougher than static ones and low brittle rock demonstrate a smoother failure surface compared to high brittle rock.

Geochronological and geochemical constraints on the origin of the Yunzhug ophiolite in the Shiquanhe-Yunzhug-Namu Tso ophiolite belt, Lhasa Terrane, Tibetan Plateau

NASA Astrophysics Data System (ADS)

Zeng, Yun-Chuan; Xu, Ji-Feng; Chen, Jian-Lin; Wang, Bao-Di; Kang, Zhi-Qiang; Huang, Feng

2018-02-01

The formation of the Shiquanhe-Yunzhug-Namu Tso ophiolite mélange zone (SNMZ) within the Lhasa Terrane, Tibetan Plateau, is key to understanding the Mesozoic tectonic evolution of this terrane, which remains controversial. We show that the Yunzhug ophiolite in the central segment of the SNMZ formed at 150 Ma, based on U-Pb dating of zircons from a gabbroic sample in a well-developed sheeted dike complex. Geochemically, these mafic rocks are dominated by E-MORB-type compositions, along with minor amounts of rocks with P-MORB-type compositions. The samples also exhibit high εNd(t) values and lack negative Nb and Ta anomalies. Data for all the samples plot within the MORB array on a Th/Yb-Nb/Yb diagram. Therefore, these mafic rocks most likely formed in either a slow spreading oceanic setting or an embryonic ocean, and not in a back-arc basin as has been previously assumed. Taking into account the regional geology, we propose that the Yunzhug ophiolite is part of a distinct ophiolitic belt and represents material formed in an embryonic ocean within the Lhasa Terrane, which provides new insights into the Jurassic tectonic evolution of the Lhasa Terrane.

Strontium and neodymium isotope systematics of target rocks and impactites from the El'gygytgyn impact structure: Linking impactites and target rocks

NASA Astrophysics Data System (ADS)

Wegner, Wencke; Koeberl, Christian

2016-12-01

The 3.6 Ma El'gygytgyn structure, located in northeastern Russia on the Chukotka Peninsula, is an 18 km diameter complex impact structure. The bedrock is formed by mostly high-silica volcanic rocks of the 87 Ma old Okhotsk-Chukotka Volcanic Belt (OCVB). Volcanic target rocks and impact glasses collected on the surface, as well as drill core samples of bedrock and impact breccias have been investigated by thermal ionization mass spectrometry (TIMS) to obtain new insights into the relationships between these lithologies in terms of Nd and Sr isotope systematics. Major and trace element data for impact glasses are added to compare with the composition of target rocks and drill core samples. Sr isotope data are useful tracers of alteration processes and Nd isotopes reveal characteristics of the magmatic sources of the target rocks, impact breccias, and impact glasses. There are three types of target rocks mapped on the surface: mafic volcanics, dacitic tuff and lava of the Koekvun' Formation, and dacitic to rhyolitic ignimbrite of the Pykarvaam Formation. The latter represents the main contributor to the impact rocks. The drill core is divided into a suevite and a bedrock section by the Sr isotope data, for which different postimpact alteration regimes have been detected. Impact glasses from the present-day surface did not suffer postimpact hydrothermal alteration and their data indicate a coherent alteration trend in terms of Sr isotopes with the target rocks from the surface. Surprisingly, the target rocks do not show isotopic coherence with the Central Chukotka segment of the OCVB or with the Berlozhya magmatic assemblage (BMA), a late Jurassic felsic volcanic suite that crops out in the eastern part of the central Chukotka segment of the OCVB. However, concordance for these rocks exists with the Okhotsk segment of the OCVB. This finding argues for variable source magmas having contributed to the build-up of the OCVB.

Age revision of the Neotethyan arc migration into the southeast Urumieh-Dokhtar belt of Iran: Geochemistry and U-Pb zircon geochronology

NASA Astrophysics Data System (ADS)

Hosseini, Mohammad Reza; Hassanzadeh, Jamshid; Alirezaei, Saeed; Sun, Weidong; Li, Cong-Ying

2017-07-01

The Urumieh-Dokhtar magmatic belt of Central Iran runs parallel to the Zagros orogenic belt and has been resulted from Neotethys ocean subduction underneath Eurasia. The Bahr Aseman volcanic-plutonic complex (BAC), covering an area 2000 km2 in the Kerman magmatic belt (KMB) in the southern section of the Urumieh-Dokhtar belt, has long been considered as the earliest manifestation of extensive Cenozoic arc magmatism in KMB. The nature and timing of the magmatism, however, is poorly constrained. An area 1000 km2, in BAC and adjacent Razak volcaniclastic complex and Jebal Barez-type granitoids, was mapped and sampled for geochemistry and geochronology. Andesite and basaltic andesite are the main volcanic components in the study area; plutonic bodies vary from tonalite to quartz diorite, granodiorite and biotite-granite. The rocks in BAC display dominantly normal calc-alkaline character. On spider diagrams, the rocks are characterized by enrichments in LILE relative to HFSE and enrichments in LREE relative to HREE. These features suggest a subduction related setting for the BAC. LaN/YbN ratios for the intrusive and volcanic rocks range from 1.41 to 5.16 and 1.01 to 6.42, respectively. These values are lower than those for other known granitoids in KMB, namely the abyssal, dominantly Oligocene Jebal Barez-type (LaN/YbN = 1.66-9.98), and the shallow, dominantly late Miocene Kuh Panj-type (LaN/YbN = 12.97-36.04) granitoids. This suggests a less evolved magma source for the BAC igneous rocks. In Y vs. Nb and Th/Yb vs. La/Yb discrimination diagrams, an island-arc setting is defined for the BAC rocks. The rocks further plot in primitive island-arc domain in Nb vs. Rb/Zr and Y/Nb vs. TiO2 diagrams. The BAC volcanic and plutonic rocks yielded zircon U-Pb ages of 78.1 to 82.7 Ma and 77.5 to 80.8 Ma, respectively. Zircon U-Pb dating of volcanic rocks and granitoids from the adjacent Razak complex and the Jebal Barez-type granitoids indicated 48.2 Ma and 26.1 Ma ages, respectively, consistent with earlier works on similar rocks elsewhere in KMB. The new data allow a revision of the chronostratigraphy/tectonic history of KMB. In Late Cretaceous, a back arc rift developed extending from Nain to Baft (NB back arc) to the northeast of the Sanandaj-Sirjan magmatic arc. Along with shrinking of the Neotethys Ocean, the dip angle of the subducting slab decreased during the Late Cretaceous, and arc magmatism moved from the Sanandaj-Sirjan zone landward. Meanwhile, Bahr Aseman volcanic-plutonic complex formed as an island-arc in NB back arc rift. Later with arc shift, due to shallowing of subducted slab, magmatism moved toward continent leading to extensive volcanism in Kerman magmatic arc during Eocene and Oligocene, represented by volcanic-sedimentary Razak and Hezar Complexes, respectively.

Benchmark Design and Installation: A synthesis of Existing Information.

DTIC Science & Technology

1987-07-01

casings (15 ft deep) drilled to rock and filled with concrete. Disks - 1 . Set on vertically stable structures (e.g., dam monoliths). 2 . Set in rock ...Structural movement survey 1 . Rock outcrops (first choice) -- chiseled square on high point. 2 . Massive concrete structure (second choice) - cut square on...bolt marker (type 2 ). 58,. % %--"% %I 1 ± 4 -I,.- Table Cl. Recomnded benchmarks. Type of condition or terrain Type of markert Bedrock, rock outcrops

Gas cluster ion beam for the characterization of organic materials in submarine basalts as Mars analogs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sano, Naoko, E-mail: naoko.sano@ncl.ac.uk; Barlow, Anders J.; Cumpson, Peter J.

The solar system contains large quantities of organic compounds that can form complex molecular structures. The processing of organic compounds by biological systems leads to molecules with distinctive structural characteristics; thus, the detection and characterization of organic materials could lead to a high degree of confidence in the existence of extra-terrestrial life. Given the nature of the surface of most planetary bodies in the solar system, evidence of life is more likely to be found in the subsurface where conditions are more hospitable. Basalt is a common rock throughout the solar system and the primary rock type on Mars andmore » Earth. Basalt is therefore a rock type that subsurface life might exploit and as such a suitable material for the study of methods required to detect and analyze organic material in rock. Telluric basalts from Earth represent an analog for extra-terrestrial rocks where the indigenous organic matter could be analyzed for molecular biosignatures. This study focuses on organic matter in the basalt with the use of surface analysis techniques utilizing Ar gas cluster ion beams (GCIB); time of flight secondary ion mass spectrometry (ToF-SIMS), and x-ray photoelectron spectroscopy (XPS), to characterize organic molecules. Tetramethylammonium hydroxide (TMAH) thermochemolysis was also used to support the data obtained using the surface analysis techniques. The authors demonstrate that organic molecules were found to be heterogeneously distributed within rock textures. A positive correlation was observed to exist between the presence of microtubule textures in the basalt and the organic compounds detected. From the results herein, the authors propose that ToF-SIMS with an Ar GCIB is effective at detecting organic materials in such geological samples, and ToF-SIMS combined with XPS and TMAH thermochemolysis may be a useful approach in the study of extra-terrestrial organic material and life.« less

The petrogenesis of late Neoproterozoic mafic dyke-like intrusion in south Sinai, Egypt

NASA Astrophysics Data System (ADS)

Azer, M. K.; Abu El-Ela, F. F.; Ren, M.

2012-08-01

New field, petrographical and geochemical studies are presented here for the late Neoproterozoic Rimm intrusion (˜15 km long) exposed in the southern Sinai Peninsula, Egypt in the northernmost Arabian-Nubian Shield (ANS). Field relations indicate that the Rimm intrusion is younger than the surrounding metamorphic rocks and calc-alkaline syn-tectonic granodiorite and it was not affected by regional metamorphism. The anorogenic peralkaline granite of Gebel Serbal crosscuts the Rimm intrusion. The Rimm intrusion is made up of several consanguineous rock types with gradational contacts. It is composed chiefly of pyroxene-hornblende gabbro, hornblende gabbro and minor quartz diorite. The chemical composition of the mafic minerals indicated that the studied rocks derived from calc-alkaline mafic magma. Geochemically, the studied rocks are characterized by enrichment in LILE relative to HFSE and LREE relative to HREE [(Ce/Yb)N = 4.50-6.36]. Quartz diorite display slightly concave HREE pattern and slightly negative Eu-anomaly [(Eu/Eu*)n = 0.91] which may be the result of fractionation of amphibole and plagioclase from the source melt, respectively. The Rimm intrusion evolved from mafic mantle magma into different type rocks by fractional crystallization with minor crustal contamination. The initial magma corresponds to pyroxene-hornblende gabbro and the crystallization of hornblende was caused by slight H2O increase in magma after crystallization of near-liquidus clinopyroxene and Ca-rich plagioclase. Amphiboles geobarometer indicate that the gabbroic rocks of the Rimm intrusion crystallized at pressures between 4.8 and 6.4 Kb, while quartz diorite crystallized at 1.3-2.1 Kb. Crystallization temperatures range between 800 and 926 °C for the gabbros and between 667 and 784 °C for the quartz diorite. The Rimm intrusion represents a post-orogenic phase formed during the crustal thinning and extension of the Arabian-Nubian Shield.

Chemical composition of sedimentary rocks in California and Hawaii

USGS Publications Warehouse

Hill, Thelma P.

1981-01-01

A compilation of published chemical analyses of sedimentary rocks of the United States was undertaken by the U.S. Geological Survey in 1952 to make available scattered data that are needed for a wide range of economic and scientific uses. About 20,000-25,000 chemical analyses of sedimentary rocks in the United States have been published. This report brings together 2,312 of these analyses from California and Hawaii. The samples are arranged by general lithologic characteristics and locality. Indexes of stratigraphy, rock name, commercial uses, and minor elements are provided. The sedimentary rocks are classified into groups and into categories according to the chemical analyses. The groups (A through F2) are defined by a system similar to that proposed by Brian Mason in 1952, in which the main parameters are the three major components of sedimentary rocks: (1) uncombined silica, (2) clay (R203 ? 3Si02 ? nH20), and (3) calcium-magnesium carbonate. The categories are based on the degree of admixture of these three major components with other components, such as sulfate, phos- phate, and iron oxide. Common-rock, mixed-rock, and special-rock categories apply to rocks consisting of 85 percent or more, 50-84 percent, and less than 49 percent, respectively, of the three major components combined. Maps show distribution of sample localities by States; triangular diagrams show the lithologic characteristics and classification groups. Cumulative-frequency curves of each constituent in each classification group of the common-rock and mixed-rock categories are also included. The numerous analyses may not adequately represent the geochemical nature of the rock types and formations of the region because of sampling bias. Maps showing distribution of sample localities indicate that many of the localities are in areas where, for economic or other reasons, special problems attracted interest. Most of the analyzed rocks tended to be fairly simple in composition - mainly mixtures of just two of the three major components or a mixture of these and a fourth component such as phosphate, gypsum, or iron oxide.

Geophysical Characterization and Structural Model of the Santa ROSALÍA Aquifer, Sonora, MÉXICO

NASA Astrophysics Data System (ADS)

Martínez-Retama, S.; Montaño-Del Cid, M. A.

2017-12-01

The main objective of this work was to determine the morphology and depth of the basement, as well as the elaboration of a structural model for the Santa Rosalía aquifer, from the processing and interpretation of gravimetric and aeromagnetic data and its correlation with the Geology of the area. The study area is located in the central portion of the State of Sonora, Mexico. In general, the geology of the site is characterized by sedimentary, igneous and metamorphic rocks whose ages vary from the Precambrian to Recent. Chronologically, the geology of the study area consists of igneous and metamorphic rocks of Precambrian age, considered as a metamorphic complex. The Paleozoic is represented by a sequence of prebatolytic rocks. This sequence is intruded by rocks of the Upper Cretaceous. The Triassic-Jurassic periods consist of arenaceous units of the Barranca Group. The Cretaceous is constituted by the Tarahumara Formation, as well as granite bodies. The Quaternary is composed of alluvial deposits, which are overlain by sediments of Recent. In this work a gravimetric survey was performed, registering a total of 7 profiles. In addition, measured data from the National Institute of Statistics and Geography (INEGI) were used. The aeromagnetic study was carried out with data from the Mexican Geological Service (SGM). In order to reduce the ambiguity in the modeling process, a rock sampling was taken from the study area and its density and magnetic susceptibility were measured. Finally, two-dimensional models of gravimetric and magnetic profiles were made to obtain the structural model of the study area. The geological-structural models obtained show gravimetric anomalies (low)associated with sedimentary basins with depths of 800 m to 1,500 m., indicating the most susceptible áreas to water storage. The basement is represented by volcanic and granite rocks that are in contact with Paleozoic sedimentary rocks (Limestone) and in some areas with volcanic rocks of the Tarahumara Formation. In these models two types of sliding tectonic events were interpreted. In the first one a system of low-angle normal faulting related to the distensive event Basin and Range was interpreted. In the second, a series of high- angle normal faults, which form Horst and Grabens structures related to the opening of the Gulf of California were modeled.

Characterization of Martian Rock Shape for MER Airbag Drop Tests

NASA Astrophysics Data System (ADS)

Dimaggio, E. N.; Schroeder, R.; Castle, N.; Golombek, M.

2002-12-01

Rock distributions for the final platforms used in airbag drop tests are currently being designed for the Mars Exploration Rovers (MER) scheduled to launch in 2003. Like Mars Pathfinder (MPF), launched in 1996, MER will use a series of airbags to cushion its landing on the surface of Mars. Previous MER airbag drop tests have shown that sharp, angular (triangular) rocks >20 cm high may be hazardous. To aid in defining the rock distributions for the final airbag tests, images from the Viking Landers 1 and 2 and MPF were used to identify rocks that are >20 cm high, and characterize them as triangular, square or round. Approximately 33% of all rocks analyzed are triangular. Of the rocks analyzed that are ~20-60 cm high, ~14% are triangular. Most of these triangular rocks are small, ~20-30 cm high. Rock distributions of previous airbag platforms were similarly classified and show a greater percentage of triangular and square rocks that are ~20-60 cm high than at the landing sites. The burial of a rock (perched, partially buried or buried) was also considered because perched rocks may pose less of a threat to the airbags than those buried because perched rocks can be dislodged and roll during impact. Approximately 19% of all rocks analyzed, and ~19% of rocks that are ~20-60 cm high, are triangular and partially buried or buried. These data suggest that the platform rock distributions appropriately represented the risks to the airbags associated with triangular rocks. A similar percentage of >20 cm high triangular rocks will be added to the drop test platforms to represent landing site rock distributions.

Evolution and tectonic setting of the Malani - Nagarparkar Igneous Suite: A Neoproterozoic Silicic-dominated Large Igneous Province in NW India-SE Pakistan

NASA Astrophysics Data System (ADS)

de Wall, Helga; Pandit, Manoj K.; Donhauser, Ines; Schöbel, Stefan; Wang, Wei; Sharma, Kamal K.

2018-07-01

The Neoproterozoic Malani Igneous Suite (MIS) in NW India, along with analogous magmatic rocks from the adjoining Nagarparkar region in SE Pakistan can be collectively classified as a Silicic-dominated Large Igneous Province (SLIP). This magmatic event includes bimodal (predominantly felsic) volcanism, granite emplacement and felsic and mafic dyke intrusions. Felsic rocks have typical A-type affinity as indicated by high abundance of silica, alkali, high field strength and large ion lithophile element concentrations and low CaO and MgO contents. Their Nb negative anomalies and Zr-saturation parameters indicate significant crustal input and high temperature melting. Mafic volcanics and dykes show geochemical homogeneity and derivation from a depleted continental mantle source without any significant crustal contamination (low U and Th contents and no visible Nb anomaly). The region extending from the Mount Abu batholith in the east to Jaswantpura in the west (2700 km2), representing a transition from the metamorphic Sirohi terrane to the undeformed MIS, was evaluated through an integrated structural (including satellite image analysis), geochemical and geochronological study. During the initial stage (prior to 760 Ma) the granitic basement (Erinpura granites) and overlying Sirohi metasediments behaved in a brittle manner that led to development of linear fractures and NNE trending rift structures, and bimodal volcanic activity. Emplacement of voluminous granitic bodies in response to progressive extension of the crust is inferred during the more evolved second stage (younger than 760 Ma). Mirpur Granite, a representative of this younger granitic suite (Jalor type pink granite) has yielded 753 ± 9 Ma zircon, U-Pb, crystallization age. Granitic plutons mark regions of crustal extension, as seen in parallel alignment of plutonic bodies (Jaswantpura granitic belt) and parallel mafic dyke swarms (340°) transecting the granites. Structural analysis further identified an episode of crustal convergence which is documented in folding and faulting of the Sindreth Basin sequence and in tectonic overprint of early stage mafic rocks. Rifting and bimodal magmatic activity in MIS is coeval with similar rock types in Nagarparkar in SE Pakistan, further traceable into the Seychelles microplate and Central Madagascar. Considering the Neoproterozoic paleogeography and our observations, an extensional setting and an active continental margin position for MIS is inferred.

Petrogenesis and tectonic implications of Late Carboniferous A-type granites and gabbronorites in NW Iran: Geochronological and geochemical constraints

NASA Astrophysics Data System (ADS)

Moghadam, Hadi Shafaii; Li, Xian-Hua; Ling, Xiao-Xiao; Stern, Robert J.; Santos, Jose F.; Meinhold, Guido; Ghorbani, Ghasem; Shahabi, Shirin

2015-01-01

Carboniferous igneous rocks constitute volumetrically minor components of Iranian crust but preserve important information about the magmatic and tectonic history of SW Asia. Ghushchi granites and gabbronorites in NW Iran comprise a bimodal magmatic suite that intruded Ediacaran-Cambrian gneiss and are good representatives of carboniferous igneous activity. Precise SIMS U-Pb zircon ages indicate that the gabbronorites and granites were emplaced synchronously at ~ 320 Ma. Ghushchi granites show A-type magmatic affinities, with typical enrichments in alkalis, Ga, Zr, Nb and Y, depletion in Sr and P and fractionated REE patterns showing strong negative Eu anomalies. The gabbronorites are enriched in LREEs, Nb, Ta and other incompatible trace elements, and are similar in geochemistry to OIB-type rocks. Granites and gabbronorites have similar εNd(t) (+ 1.3 to + 3.4 and - 0.1 to + 4.4, respectively) and zircon εHf(t) (+ 1.7 to + 6.2 and + 0.94 to + 6.5, respectively). The similar variation in bulk rock εNd(t) and zircon εHf(t) values and radiometric ages for the granites and gabbronorites indicate a genetic relationship between mafic and felsic magmas, either a crystal fractionation or silicate liquid immiscibility process; further work is needed to resolve petrogenetic details. The compositional characteristics of the bimodal Ghushchi complex are most consistent with magmatic activity in an extensional tectonic environment. This extension may have occurred during rifting of Cadomian fragments away from northern Gondwana during early phases of Neotethys opening.

Petrology and geochemistry of lithic fragments separated from the Apollo 15 deep-drill core

NASA Technical Reports Server (NTRS)

Lindstrom, M. M.; Nielsen, R. L.; Drake, M. J.

1977-01-01

Petrological and geochemical analysis of lithic fragments separated from the Apollo 15 deep-drill core showed these fragments to fall into the essentially the same range of rock types as observed in surface soil samples and large rock samples. Three particles are singled out as being of special interest. One sample is a mare basalt containing extremely evolved phases. The particle may represent small-scale imperfect crystal/liquid separation in a lava flow. A green glass particle is not the ultramafic emerald green glass described from the Apollo 15 site, but rather an ANT-like light green color, and has a quite different chemical composition from the ultramafic variety. One mare basalt displays a positive Eu anomaly and is enriched in plagioclase relative to olivine plus pyroxene.

Μicro-Raman spectroscopy for the characterization of rock-art pigments from Abrigo del Águila (Badajoz - Spain)

NASA Astrophysics Data System (ADS)

Rosina, P.; Gomes, H.; Collado, H.; Nicoli, M.; Volpe, L.; Vaccaro, C.

2018-06-01

Micro-Raman spectroscopic technique allowed the characterization of organic and inorganic pigments of different colours sampled from a rock-art shelter named Abrigo del Aguila, located in the district of Badajoz, Cabeza del Buey (Extremadura - Spain). Micro-Raman analyses has been coupled with SEM observation and elemental analyses (EDS). The white and the black colours, used for non-representative figures, have been identified respectively as anatase and amorphous carbon, while two different type of red pigment has been found on figurative representations. The darker one, sampled, from a sun-figure, comprises an indeterminate organic compound beside of hematite. The second one, sampled from an anthropomorphic figure, is of a brilliant red and only hematite has been recognized in it.

A female black bear denning habitat model using a geographic information system

USGS Publications Warehouse

Clark, J.D.; Hayes, S.G.; Pledger, J.M.

1998-01-01

We used the Mahalanobis distance statistic and a raster geographic information system (GIS) to model potential black bear (Ursus americanus) denning habitat in the Ouachita Mountains of Arkansas. The Mahalanobis distance statistic was used to represent the standard squared distance between sample variates in the GIS database (forest cover type, elevation, slope, aspect, distance to streams, distance to roads, and forest cover richness) and variates at known bear dens. Two models were developed: a generalized model for all den locations and another specific to dens in rock cavities. Differences between habitat at den sites and habitat across the study area were represented in 2 new GIS themes as Mahalanobis distance values. Cells similar to the mean vector derived from the known dens had low Mahalanobis distance values, and dissimilar cells had high values. The reliability of the predictive model was tested by overlaying den locations collected subsequent to original model development on the resultant den habitat themes. Although the generalized model demonstrated poor reliability, the model specific to rock dens had good reliability. Bears were more likely to choose rock den locations with low Mahalanobis distance values and less likely to choose those with high values. The model can be used to plan the timing and extent of management actions (e.g., road building, prescribed fire, timber harvest) most appropriate for those sites with high or low denning potential. 

Structural Analysis: Folds Classification of metasedimentary rock in the Peninsular Malaysia

NASA Astrophysics Data System (ADS)

Shamsuddin, A.

2017-10-01

Understanding shear zone characteristics of deformation are a crucial part in the oil and gas industry as it might increase the knowledge of the fracture characteristics and lead to the prediction of the location of fracture zones or fracture swarms. This zone might give high influence on reservoir performance. There are four general types of shear zones which are brittle, ductile, semibrittle and brittle-ductile transition zones. The objective of this study is to study and observe the structural geometry of the shear zones and its implication as there is a lack of understanding, especially in the subsurface area because of the limitation of seismic resolution. A field study was conducted on the metasedimentary rocks (shear zone) which are exposed along the coastal part of the Peninsular Malaysia as this type of rock resembles the types of rock in the subsurface. The analysis in this area shows three main types of rock which are non-foliated metaquartzite and foliated rock which can be divided into slate and phyllite. Two different fold classification can be determined in this study. Layer 1 with phyllite as the main type of rock can be classified in class 1C and layer 2 with slate as the main type of rock can be classified in class 1A. This study will benefit in predicting the characteristics of the fracture and fracture zones.

Bedrock geologic map of the Montpelier and Barre West quadrangles, Washington and Orange Counties, Vermont

USGS Publications Warehouse

Walsh, Gregory J.; Kim, Jonathan; Gale, Marjorie H.; King, Sarah M.

2010-01-01

The bedrock geology of the Montpelier and Barre West quadrangles consists of Silurian and Devonian metasedimentary rocks of the Connecticut Valley-Gaspe synclinorium (CVGS) and metasedimentary, metavolcanic, and metaintrusive rocks of the Cambrian and Ordovician Moretown and Cram Hill Formations. Devonian granite dikes occur throughout the two quadrangles but are more abundant in the Silurian and Devonian rocks. The pre-Silurian rocks are separated from the rocks of the CVGS by the informally named 'Richardson Memorial Contact,' historically interpreted as either an unconformity or a fault. The results of this report represent mapping by G.J. Walsh, Jonathan Kim, and M.H. Gale from 2002 to 2005. S.M. King assisted Kim and Gale from 2002 to 2003. A.M. Satkoski (Indiana University) assisted Walsh, and L.R. Pascale (University of Vermont) and C.M. Orsi (Middlebury College) assisted Kim and Gale as summer interns in 2003. This study was designed to map the bedrock geology in the area. This map supersedes a preliminary map of the Montpelier quadrangle (Kim, Gale, and others, 2003). A companion study in the Barre West quadrangle (Walsh and Satkoski, 2005) determined the levels of naturally occurring radioactivity in the bedrock from surface measurements at outcrops during the course of 1:24,000-scale geologic mapping to identify which rock types were potential sources of radionuclides. Results of that study indicate that the carbonaceous phyllites in the CVGS have the highest levels of natural radioactivity.

Leperditicopid ostracodes from Ordovician rocks of Kentucky and nearby states and characteristic features of the order Leperditicopida

USGS Publications Warehouse

Berdan, J.M.

1984-01-01

Leperditicopid ostracodes from the Ordovician formations of Kentucky occur in micritic to fine-grained carbonate rocks believed to represent shallow-water facies. They are found at widely separated horizons in the Middle Ordovician High Bridge Group, the Middle and Upper Ordovician Lexington Limestone, and the Upper Ordovician Ashlock, Bull Fork, and Drakes Formations. In this sequence, the leperditicopes are represented by two genera of leperditiids, Eoleperditia Swartz, 1949 and Bivia Berdan, 1976, and six isochilinid genera, Isochilina Jones, 1858, Teichochilina Swartz, 1949, Ceratoleperditia Harris, 1960, Parabriartina n. gen., Kenodontochilina n. gen., and Saffordellina Bassler and Kellett, 1934; the type species of the hitherto poorly known genus Saffordellina, S. muralis (Ulrich and Bassler, 1923), is redescribed and refigured. In all, 18 taxa, of which 2 are in open nomenclature, are described and illustrated. In addition, the family Isochilinidae Swartz, 1949 is redefined to include genera without marginal brims and with straight ventral contact margins. The morphological characteristics of leperditicopid genera are discussed, and a table listing described genera and their diagnostic features is included.

Hydrothermal quartz formation during fluctuations of brittle shear-zone activity and fluid flow: grain growth and deformation structures of the Pfahl shear zone (Germany)

NASA Astrophysics Data System (ADS)

Yilmaz, T.; Prosser, G.; Liotta, D.; Kruhl, J. H.

2012-12-01

The Bavarian Pfahl shear zone is a WNW-ESE trending dextral strike-slip shear zone at the SW margin of the Bohemian Massif (Central Europe). It was discontinuously active during decreasing PT-conditions, i.e. from ductile to brittle, from the late-Carboniferous to the late-Cretaceous - Paleocene times. Triassic hydrothermal activity produced a 150 km long and 30-100 m wide quartz dyke along the main fault, surrounded by sheared basement rocks. Within a zone of >10 m metasomatism transformed the wall rocks to mostly kaolinite, chlorite and phyllosilicates. The quartz dyke exhibits a layered to lenticular and partly symmetric structure with different types of quartz masses, transected by a complex quartz vein network. This already indicates pulses of fluid flux and fragmentation during the lifetime of the shear zone. Analyses by optical microscopy, cathodoluminescence (CL) and SEM-EDX reveal at least four subsequent stages of quartz crystallization and fragmentation. (i) The oldest generation of quartz is represented by a homogeneous dark grey to reddish quartz mass made up by ~10-20 μm-sized crystals. It contains mm- to cm-sized angular wall-rock fragments, completely altered to kaolinite, indicating intense wall-rock alteration prior to the earliest event of silica precipitation. This rules out the possibility that the quartz mass developed from silicification of the wall rocks. This first type of quartz occurs as cm- to dm-large angular fragments in (ii) a light grey to pink quartz mass formed by ~10-50 μm-sized crystals. The different colours result from variable types and amounts of inclusions. Quartz of both generations shows random crystallographic orientations and complex inclusion structures. It probably developed during two fragmentation events and possibly from a silica gel precursor that crystallized after precipitation. (iii) The third quartz generation formed as a set of mm- to dm-wide veins roughly parallel to the trend of the Pfahl zone, crosscutting the first generations of fine-grained quartz mass and the wall rocks, in connection to intense fracturing and brecciation. The complex geometry of the vein sets points to multiple fluid injections and brecciation, as additionally indicated by coarse quartz with different inclusion and CL intensity. Temporal changes of strain rate are indicated by crystal plastic deformation structures in quartz, which overprint brittle structures. (iv) The fourth quartz generation occurs in mm- to dm-thick quartz veins, partly open as geodes, filling N-S oriented cm- to dm-spaced fractures that crosscut the earlier quartz masses and veins and extend at least several meters into the wall rock. They indicate the last activity of the shear-zone in a constant kinematic framework. Summarizing, the Pfahl shear zone shows brittle-ductile deformation during the long-term activity of a large-scale hydrothermal system. Consequently, it represents an excellent example where different generations of quartz precipitation can be connected to fluctuations of fluid flow and strain rate.

Petrogenesis of Cretaceous volcanic-intrusive complex from the giant Yanbei tin deposit, South China: Implication for multiple magma sources, tin mineralization, and geodynamic setting

NASA Astrophysics Data System (ADS)

Li, Qian; Zhao, Kui-Dong; Lai, Pan-Chen; Jiang, Shao-Yong; Chen, Wei

2018-01-01

The giant Yanbei tin ore deposit is the largest porphyry-type tin deposit in South China. The orebodies are hosted by the granite porphyry in the central part of the Yanbei volcanic basin in southern Jiangxi Province. The Yanbei volcanic-intrusive complex mainly consists of dacitic-rhyolitic volcanic rocks, granite, granite porphyry and diabase dikes. In previous papers, the granite porphyry was considered as subvolcanic rocks, which came from the same single magma chamber with the volcanic rocks. In this study, zircon U-Pb ages and Hf isotope data, as well as whole-rock geochemical and Sr-Nd isotopic compositions of different magmatic units in the Yanbei complex are reported. Geochronologic results show that various magmatic units have different formation ages. The dacite yielded a zircon U-Pb age of 143 ± 1 Ma, and the granite porphyry has the emplacement age of 138 ± 1 Ma. Diabase dikes which represented the final stage of magmatism, yielded a zircon U-Pb age of 128 ± 1 Ma. Distinctive whole rock Sr-Nd and zircon Hf isotopic compositions suggest that these magmatic units were derived from different magma sources. The volcanic rocks were mainly derived from the partial melting of Paleoproterozoic metasedimentary rocks without additions of mantle-derived magma. The granite porphyry has an A-type geochemical affinity, and was derived from remelting of Paleo-Mesoproterozoic crustal source with involvement of a subordinate mantle-derived magma. The granite porphyry is also a typical stanniferous granite with high F (4070-6090 ppm) and Sn (7-39 ppm) contents. It underwent strongly crystal fractionation of plagioclase, K-feldspar, and accessory minerals (like apatite, Fe-Ti oxides), which may contribute to the tin mineralization. The diabase was derived by partial melting of enriched lithospheric mantle which had been metasomatised by slab-derived fluids. The change of magmatic sources reflected an increasing extensional tectonic environment, perhaps induced by slab rollback of subducted paleo-Pacific plate.

Theory of wing rock

NASA Technical Reports Server (NTRS)

Hsu, C.-H.; Lan, C. E.

1985-01-01

Wing rock is one type of lateral-directional instabilities at high angles of attack. To predict wing rock characteristics and to design airplanes to avoid wing rock, parameters affecting wing rock characteristics must be known. A new nonlinear aerodynamic model is developed to investigate the main aerodynamic nonlinearities causing wing rock. In the present theory, the Beecham-Titchener asymptotic method is used to derive expressions for the limit-cycle amplitude and frequency of wing rock from nonlinear flight dynamics equations. The resulting expressions are capable of explaining the existence of wing rock for all types of aircraft. Wing rock is developed by negative or weakly positive roll damping, and sustained by nonlinear aerodynamic roll damping. Good agreement between theoretical and experimental results is obtained.

Classification of Broken Hill-Type Pb-Zn-Ag Deposits: A Refinement

NASA Astrophysics Data System (ADS)

Spry, P. G.; Teale, G. S.; Steadman, J. A.

2009-05-01

Broken Hill Hill-type Pb-Zn-Ag (BHT) deposits constitute some of the largest ore deposits in the world. The Broken Hill deposit is the largest accumulation of Pb, Zn, and Ag on Earth and the Cannington deposit is currently the largest silver deposit. Characteristic features of BHT deposits include: 1. high Pb+Zn+Ag values with Pb > Zn; 2. Metamorphism to amphibolite-granulite facies; 3. Paleo-to Mesoprotoerozoic clastic metasedimentary host rocks; 4. Sulfides that are spatially associated with bimodal (felsic and mafic) volcanic rocks, and stratabound gahnite- and garnet-bearing rocks and iron formations, 5. Stacked orebodies with characteristic Pb:Zn:Ag ratios and skarn-like Fe-Mn-Ca-F gangue assemblages, and the presence of Cu, Au, Bi, As, and Sb; and 6. Sulfur-poor assemblages. Broken Hill (Australia) has a prominent footwall feeder zone whereas other BHT deposits have less obvious alteration zones (footwall garnet spotting and stratabound alteration haloes). Deposits previously regarded in the literature as BHT deposits are Broken Hill, Cannington, Oonagalabie, Menninie Dam, and Pegmont (Australia), Broken Hill, Swartberg, Big Syncline, and Gamsberg (South Africa), Zinkgruvan (Sweden), Sullivan, Cottonbelt, and Foster River (Canada), and Boquira (Brazil). Of these deposits, only the Broken Hill (Australia, South Africa), Pinnacles, Cannington, Pegmont, and Swartberg deposits are BHT deposits. Another BHT deposit includes the Green Parrot deposit, Jervois Ranges (Northern Territory). The Foster River, Gamsberg, and Sullivan deposits are considered to be "SEDEX deposits with BHT affinities", and the Oonagalabie, Green Mountain (Colorado), and Zinkgruvan are "VMS deposits with BHT affinities". In the Broken Hill area (Australia), Corruga-type Pb-Zn-Ag deposits occur in calc-silicate rocks and possess some BHT characteristics; the Big Syncline, Cottonbelt, Menninie Dam, and Saxberget deposits are Corruga-type deposits. SEDEX deposits with BHT affinities, VMS deposits with BHT affinities, and Corruga-type deposits represent transitional deposits between BHT and SEDEX, VMS, and metamorphosed base metal calc-silicate deposits, respectively. Although the non-sulfide zinc deposits at Franklin Furnace and Sterling Hill, NJ, do not contain Pb, they resemble sulfur-poor BHT deposits.

Geological and geomechanical properties of the carbonate rocks at the eastern Black Sea Region (NE Turkey)

NASA Astrophysics Data System (ADS)

Ersoy, Hakan; Yalçinalp, Bülent; Arslan, Mehmet; Babacan, Ali Erden; Çetiner, Gözde

2016-11-01

Turkey located in the Alpine-Himalayan Mountain Belt has 35% of the natural stone reserves of the world and has good quality marble, limestone, travertine and onyx reserves especially in the western regions of the country. The eastern Black Sea Region with a 1.4 million meters cubes reserve has a little role on the natural stone production in the country. For this reason, this paper deals with investigation on the potential of carbonate stone in the region and determination of the geological and geo-mechanical properties of these rocks in order to provide economic contribution to the national economy. While the study sites are selected among the all carbonate rock sites, the importance as well as the representative of the sites were carefully considered for the region. After representative samples were analyzed for major oxide and trace element compositions to find out petrochemical variations, the experimental program conducted on rock samples for determination of both physical and strength properties of the carbonate rocks. The results of the tests showed that there are significant variations in the geo-mechanical properties of the studied rock groups. The density values vary from 2.48 to 2.70 gr/cm3, water absorption by weight values range from 0.07 to 1.15% and the apparent porosity of the carbonate rocks are between 0.19 and 3.29%. However, the values of the UCS shows variation from 36 to 80 MPa. Tensile and bending strength values range from 3.2 to 7.5 MPa and 6.0-9.2 MPa respectively. Although the onyx samples have the lowest values of apparent porosity and water absorption by weight, these samples do not have the highest values of UCS values owing to occurrence of the micro-cracks. The UCS values of the rock samples were also found after cycling tests However, the limestone samples have less than 5% deterioration after freezing-thawing and wetting-drying tests, but travertine and onyx samples have more than 15% deterioration. Exception of the apparent porosity values of travertine samples, all geo-mechanical properties of the studied carbonate rocks were determined in the acceptance values given by Turkish Standards Institute (TSE) for using as a natural dimension stone. After these investigations, it is anticipated that in the near future the number of quarries and factories will increase and more types of natural stones will be discovered in the eastern Black Sea Region and thus this will provide economic contribution to the economy of the country.

Jurassic-Paleogene intraoceanic magmatic evolution of the Ankara Mélange, north-central Anatolia, Turkey

NASA Astrophysics Data System (ADS)

Sarifakioglu, E.; Dilek, Y.; Sevin, M.

2014-02-01

Oceanic rocks in the Ankara Mélange along the Izmir-Ankara-Erzincan suture zone (IAESZ) in north-central Anatolia include locally coherent ophiolite complexes (∼ 179 Ma and ∼ 80 Ma), seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma), metamorphic rocks with ages of 256.9 ± 8.0 Ma, 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma indicating northern Tethys during the late Paleozoic through Cretaceous, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (∼ 67-63 Ma). All but the arc rocks occur in a shale-graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the middle to late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB) and island arc tholeiite (IAT) affinities showing moderate to significant large ion lithophile elements (LILE) enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB) affinities. The arc-related volcanic rocks, lamprophyric dikes and syenodioritic plutons exhibit high-K shoshonitic to medium- to high-K calc-alkaline compositions with strong enrichment in LILE, rare earth elements (REE) and Pb, and initial ɛNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syenodioritic plutons) in the southern part. The late Permian, Early to Late Jurassic, and Late Cretaceous amphibole-epidote schist, epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the seamount volcanic rocks indicate that the northern Neotethys was an open ocean with its MORB-type oceanic lithosphere by the early Triassic (or earlier). The latest Cretaceous-early Paleocene island arc volcanic, dike and plutonic rocks with subalkaline to alkaline geochemical affinities represent intraoceanic magmatism that developed on and across the subduction-accretion complex above a N-dipping, southward-rolling subducted lithospheric slab within the northern Neotethys. The Ankara Mélange thus exhibits the record of ∼ 120-130 million years of oceanic magmatism in geological history of the northern Neotethys.

Typical Geo-Hazards and Countermeasures of Mines in Yunnan Province, Southwest China

NASA Astrophysics Data System (ADS)

Cheng, Xianfeng; Qi, Wufu; Huang, Qianrui; Zhao, Xueqiong; Fang, Rong; Xu, Jun

2016-10-01

Mining-induced geo-hazards have caused enormous destruction and threat to mines. Known as the "kingdom of nonferrous metals" and located in Southwest China, Yunnan Province developed mining-induced geo-hazards well with characteristics of multiple types, widespread distribution and serious damage. Landslides and debris flows are two common sub-types of geohazards causing most serious damage in Yunnan, and some of them were very representative in the world. Two landslides and two debris flows were chosen to analyze deeply. Both Laojinshan Landslide and Sunjiaqing Landslide possess the characteristic of rock avalanches. The high sliding speed and long distance made the landslides translate into clastic flows with impact force and caused enormous destruction. Rainstorm and mining waste rock were two main factors to induce debris flows in Yunnan mines. Heishan valley debris flow of Dongchuan copper mine was a super large rainstorm type viscose debris flow with very low frequency, which brought a good caution to utilize valleys which looked an unlikely debris flow. Nandagou Valley of Jinding lead-zinc mine in Lanping County was a rainstorm stimulating, gully-type, high frequency and large scale debris flow, which was induced by mining activities. Many countermeasures have been used for Yunnan mines, including engineering treatment technology and ecological remediation, monitoring and forecasting, relocation and public administration.

Validation of a New Elastoplastic Constitutive Model Dedicated to the Cyclic Behaviour of Brittle Rock Materials

NASA Astrophysics Data System (ADS)

Cerfontaine, B.; Charlier, R.; Collin, F.; Taiebat, M.

2017-10-01

Old mines or caverns may be used as reservoirs for fuel/gas storage or in the context of large-scale energy storage. In the first case, oil or gas is stored on annual basis. In the second case pressure due to water or compressed air varies on a daily basis or even faster. In both cases a cyclic loading on the cavern's/mine's walls must be considered for the design. The complexity of rockwork geometries or coupling with water flow requires finite element modelling and then a suitable constitutive law for the rock behaviour modelling. This paper presents and validates the formulation of a new constitutive law able to represent the inherently cyclic behaviour of rocks at low confinement. The main features of the behaviour evidenced by experiments in the literature depict a progressive degradation and strain of the material with the number of cycles. A constitutive law based on a boundary surface concept is developed. It represents the brittle failure of the material as well as its progressive degradation. Kinematic hardening of the yield surface allows the modelling of cycles. Isotropic softening on the cohesion variable leads to the progressive degradation of the rock strength. A limit surface is introduced and has a lower opening than the bounding surface. This surface describes the peak strength of the material and allows the modelling of a brittle behaviour. In addition a fatigue limit is introduced such that no cohesion degradation occurs if the stress state lies inside this surface. The model is validated against three different rock materials and types of experiments. Parameters of the constitutive laws are calibrated against uniaxial tests on Lorano marble, triaxial test on a sandstone and damage-controlled test on Lac du Bonnet granite. The model is shown to reproduce correctly experimental results, especially the evolution of strain with number of cycles.

Geologic map of the Sauk River 30- by 60-minute quadrangle, Washington

USGS Publications Warehouse

Tabor, R.W.; Booth, D.B.; Vance, J.A.; Ford, A.B.

2002-01-01

Summary -- The north-south-trending regionally significant Straight Creek Fault roughly bisects the Sauk River quadrangle and defines the fundamental geologic framework of it. Within the quadrangle, the Fault mostly separates low-grade metamorphic rocks on the west from medium- to high-grade metamorphic rocks of the Cascade metamorphic core. On the west, the Helena-Haystack melange and roughly coincident Darrington-Devils Mountain Fault Zone separate the western and eastern melange belts to the southwest from the Easton Metamorphic Suite, the Bell Pass melange, and rocks of the Chilliwack Group, to the northeast. The tectonic melanges have mostly Mesozoic marine components whereas the Chilliwack is mostly composed of Late Paleozoic arc rocks. Unconformably overlying the melanges and associated rocks are Eocene volcanic and sedimentary rocks, mostly infaulted along the Darrington-Devils Mountain Fault Zone. These younger rocks and a few small Eocene granitic plutons represent an extensional tectonic episode. East of the Straight Creek Fault, medium to high-grade regional metamorphic rocks of the Nason, Chelan Mountains, and Swakane terranes have been intruded by deep seated, Late Cretaceous granodioritic to tonalitic plutons, mostly now orthogneisses. Unmetamorphosed mostly tonalitic intrusions on both sides of the Straight Creek fault range from 35 to 4 million years old and represent the roots of volcanoes of the Cascade Magmatic Arc. Arc volcanic rocks are sparsely preserved east of the Straight Creek fault, but dormant Glacier Peak volcano on the eastern margin of the quadrangle is the youngest member of the Arc. Deposits of the Canadian Ice Sheet are well represented on the west side of the quadrangle, whereas alpine glacial deposits are common to the east. Roughly 5000 years ago lahars from Glacier Peak flowed westward filling major valleys across the quadrangle.

In-Situ and Experimental Evidence for Acidic Weathering of Rocks and Soils on Mars

NASA Technical Reports Server (NTRS)

Hurowitz, J. A.; McLennan, S. M.; Tosca, N. J.; Arvidson, R. E.; Michalski, J. R.; Ming, D.; Schroeder, C.; Squyres, S. W.

2006-01-01

Experimental data for alteration of synthetic Martian basalts at pH=0-1 indicate that chemical fractionations at low pH are vastly different from those observed during terrestrial weathering. Rock analyses from Gusev crater are well described by the relationships apparent from low pH experimental alteration data. A model for rock surface alteration is developed which indicates that a leached alteration zone is present on rock surfaces at Gusev. This zone is not chemically fractionated to a large degree from the underlying rock interior, indicating that the rock surface alteration process has occurred at low fluid-to-rock ratio. The geochemistry of natural rock surfaces analyzed by APXS is consistent with a mixture between adhering soil/dust and the leached alteration zone. The chemistry of rock surfaces analyzed after brushing with the RAT is largely representative of the leached alteration zone. The chemistry of rock surfaces analyzed after grinding with the RAT is largely representative of the interior of the rock, relatively unaffected by the alteration process occurring at the rock surface. Elemental measurements from the Spirit, Opportunity, Pathfinder and Viking 1 landing sites indicate that soil chemistry from widely separated locations is consistent with the low-pH, low fluid to rock ratio alteration relationships developed for Gusev rocks. Soils are affected principally by mobility of FeO and MgO, consistent with alteration of olivine-bearing basalt and subsequent precipitation of FeO and MgO bearing secondary minerals as the primary control on soil geochemistry.

Rock Tea extract (Jasonia glutinosa) relaxes rat aortic smooth muscle by inhibition of L-type Ca(2+) channels.

PubMed

Valero, Marta Sofía; Oliván-Viguera, Aida; Garrido, Irene; Langa, Elisa; Berzosa, César; López, Víctor; Gómez-Rincón, Carlota; Murillo, María Divina; Köhler, Ralf

2015-12-01

In traditional herbal medicine, Rock Tea (Jasonia glutinosa) is known for its prophylactic and therapeutic value in various disorders including arterial hypertension. However, the mechanism by which Rock Tea exerts blood pressure-lowering actions has not been elucidated yet. Our aim was to demonstrate vasorelaxing effects of Rock Tea extract and to reveal its possible action mechanism. Isometric myography was conducted on high-K+-precontracted rings from rat thoracic aorta and tested extracts at concentrations of 0.5-5 mg/ml. Whole-cell patch-clamp experiments were performed in rat aortic vascular smooth muscle cells (line A7r5) to determine blocking effects on L-type Ca(2+) channels. Rock Tea extract relaxed the aorta contracted by high [K+] concentration dependently with an EC50 of ≈2.4 mg/ml and produced ≈75 % relaxation at the highest concentration tested. The L-type Ca(2+) channel blocker, verapamil (10(-6) M), had similar effects. Rock Tea extract had no effect in nominally Ca(2+)-free high-K(+) buffer but significantly inhibited contractions to re-addition of Ca(2+). Rock Tea extract inhibited the contractions induced by the L-type Ca(2+) channel activator Bay K 8644 (10(-5) M) and by phenylephrine (10(-6) M). Rock Tea extract and Y-27632 (10(-6) M), Rho-kinase inhibitor, had similar effects and the respective effects were not additive. Patch-clamp experiments demonstrated that Rock Tea extract (2.5 mg/ml) virtually abolished L-type Ca(2+) currents in A7r5. We conclude that Rock Tea extract produced vasorelaxation of rat aorta and that this relaxant effect is mediated by inhibition of L-type Ca(2+) channels. Rock Tea extracts may be of phytomedicinal value for prevention and adjuvant treatment of hypertension and other cardiovascular diseases.

Introduction to the Apollo collections. Part 1: Lunar igneous rocks

NASA Technical Reports Server (NTRS)

Mcgee, P. E.; Warner, J. L.; Simonds, C. H.

1977-01-01

The basic petrographic, chemical, and age data is presented for a representative suite of igneous rocks gathered during the six Apollo missions. Tables are given for 69 samples: 32 igneous rocks and 37 impactites (breccias). A description is given of 26 basalts, four plutonic rocks, and two pyroclastic samples. The textural-mineralogic name assigned each sample is included.

The Research on Tunnel Surrounding Rock Classification Based on Geological Radar and Probability Theory

NASA Astrophysics Data System (ADS)

Xiao Yong, Zhao; Xin, Ji Yong; Shuang Ying, Zuo

2018-03-01

In order to effectively classify the surrounding rock types of tunnels, a multi-factor tunnel surrounding rock classification method based on GPR and probability theory is proposed. Geological radar was used to identify the geology of the surrounding rock in front of the face and to evaluate the quality of the rock face. According to the previous survey data, the rock uniaxial compressive strength, integrity index, fissure and groundwater were selected for classification. The related theories combine them into a multi-factor classification method, and divide the surrounding rocks according to the great probability. Using this method to classify the surrounding rock of the Ma’anshan tunnel, the surrounding rock types obtained are basically the same as those of the actual surrounding rock, which proves that this method is a simple, efficient and practical rock classification method, which can be used for tunnel construction.

Osmium isotope and highly siderophile element systematics of lunar impact melt breccias: Implications for the late accretion history of the Moon and Earth

USGS Publications Warehouse

Puchtel, I.S.; Walker, R.J.; James, O.B.; Kring, D.A.

2008-01-01

To characterize the compositions of materials accreted to the Earth-Moon system between about 4.5 and 3.8 Ga, we have determined Os isotopic compositions and some highly siderophile element (HSE: Re, Os, Ir, Ru, Pt, and Pd) abundances in 48 subsamples of six lunar breccias. These are: Apollo 17 poikilitic melt breccias 72395 and 76215; Apollo 17 aphanitic melt breccias 73215 and 73255; Apollo 14 polymict breccia 14321; and lunar meteorite NWA482, a crystallized impact melt. Plots of Ir versus other HSE define excellent linear correlations, indicating that all data sets likely represent dominantly two-component mixtures of a low-HSE target, presumably endogenous component, and a high-HSE, presumably exogenous component. Linear regressions of these trends yield intercepts that are statistically indistinguishable from zero for all HSE, except for Ru and Pd in two samples. The slopes of the linear regressions are insensitive to target rock contributions of Ru and Pd of the magnitude observed; thus, the trendline slopes approximate the elemental ratios present in the impactor components contributed to these rocks. The 187Os/188Os and regression-derived elemental ratios for the Apollo 17 aphanitic melt breccias and the lunar meteorite indicate that the impactor components in these samples have close affinities to chondritic meteorites. The HSE in the Apollo 17 aphanitic melt breccias, however, might partially or entirely reflect the HSE characteristics of HSE-rich granulitic breccia clasts that were incorporated in the impact melt at the time of its creation. In this case, the HSE characteristics of these rocks may reflect those of an impactor that predated the impact event that led to the creation of the melt breccias. The impactor components in the Apollo 17 poikilitic melt breccias and in the Apollo 14 breccia have higher 187Os/188Os, Pt/Ir, and Ru/Ir and lower Os/Ir than most chondrites. These compositions suggest that the impactors they represent were chemically distinct from known chondrite types, and possibly represent a type of primitive material not currently delivered to Earth as meteorites. ?? 2008 Elsevier Ltd.

Prediction of carbonate rock type from NMR responses using data mining techniques

NASA Astrophysics Data System (ADS)

Gonçalves, Eduardo Corrêa; da Silva, Pablo Nascimento; Silveira, Carla Semiramis; Carneiro, Giovanna; Domingues, Ana Beatriz; Moss, Adam; Pritchard, Tim; Plastino, Alexandre; Azeredo, Rodrigo Bagueira de Vasconcellos

2017-05-01

Recent studies have indicated that the accurate identification of carbonate rock types in a reservoir can be employed as a preliminary step to enhance the effectiveness of petrophysical property modeling. Furthermore, rock typing activity has been shown to be of key importance in several steps of formation evaluation, such as the study of sedimentary series, reservoir zonation and well-to-well correlation. In this paper, a methodology based exclusively on the analysis of 1H-NMR (Nuclear Magnetic Resonance) relaxation responses - using data mining algorithms - is evaluated to perform the automatic classification of carbonate samples according to their rock type. We analyze the effectiveness of six different classification algorithms (k-NN, Naïve Bayes, C4.5, Random Forest, SMO and Multilayer Perceptron) and two data preprocessing strategies (discretization and feature selection). The dataset used in this evaluation is formed by 78 1H-NMR T2 distributions of fully brine-saturated rock samples from six different rock type classes. The experiments reveal that the combination of preprocessing strategies with classification algorithms is able to achieve a prediction accuracy of 97.4%.

Carboniferous continental arc in the Hegenshan accretionary belt: Constrains from plutonic complex in central Inner Mongolia

NASA Astrophysics Data System (ADS)

Wei, Ruihua; Gao, Yongfeng; Xu, Shengchuan; Santosh, M.; Xin, Houtian; Zhang, Zhenmin; Li, Weilong; Liu, Yafang

2018-05-01

The architecture and tectonic evolution of the Hegenshan accretionary belt in the Central Asian Orogenic Belt (CAOB) remains debated. Here we present an integrated study of zircon U-Pb isotopic ages, whole rock major-trace elements, and Sr-Nd-Pb isotopic data from the Hegenshan volcanic-plutonic belt in central Inner Mongolia. Field observations and zircon U-Pb ages allow us to divide the intrusive complex into an early phase at 329-306 Ma and a late phase at 304 to 299 Ma. The intrusive bodies belong to two magma series: calc-alkaline rocks with I-type affinity and A-type granites. The early intrusions are composed of granodiorite, monzogranite and porphyritic granite, and the late calc-alkaline intrusions include gabbro though diorite to granodiorite. The calc-alkaline intrusive rocks exhibit a well-defined compositional trend from gabbro to granite, reflecting continuous fractional crystallization. These rocks show obvious enrichment in LILEs and LREEs and relative depletion of HFSEs, typical of subduction-related magma. They also exhibit isotopic characteristics of mantle-derived magmas such as low initial 87Sr/86Sr (0.7029-0.7053), positive ɛNd(t) values (0.06-4.76) and low radiogenic Pb isotopic compositions ((206Pb/204Pb)I = 17.907-19.198, (207Pb/204Pb)I = 15.474-15.555, (208Pb/204Pb)I = 37.408-38.893). The marked consistency in geochemical and isotopic compositions between the intrusive rocks and the coeval Baoligaomiao volcanic rocks define a Carboniferous continental arc. Together with available regional data, we infer that this east-west trending continental arc was generated by northward subduction of the Hegenshan ocean during Carboniferous. The late alkali-feldspar granites and the high-Si rhyolites of the Baoligaomiao volcanic succession show similar geochemical compositions with high SiO2 and variable total alkali contents, and low TiO2, MgO and CaO. These rocks are characterized by unusually low Sr and Ba, and high abundances of Zr, Th, Nb, HREEs and Y, comparable to the features of typical A2-type granites including their high ratios of FeOT/MgO, Ga/Al and Y/Nb. Our study suggests that the A-type granite was derived from a distinct magma source rather than through fractional crystallization of the coeval calc-alkaline magmas. Their Nd-Pb isotopic compositions are similar to those of calc-alkaline arc rocks and are compatible with partial melting of pre-existing juvenile basaltic crust in the continental arc. Notably, the widespread eruptions of A2-type rhyolitic magmas (305.3 Ma-303.4 Ma) following a short period of magmatic quiescence was temporally and spatially associated with bimodal magmatism with mantle-derived gabbro-diorites and A-type granites (304.3 Ma-299.03 Ma) in the pre-existing arc volcanic-plutonic belt (329 Ma-306 Ma). Such a marked change in the magma affinity likely indicates subducted slab break-off resulting in a change of the regional stress field to an extensional setting within the Carboniferous continental arc that runs E-W for few thousands of kilometers. Thus, the onset of the late magmatism (305-299 Ma) likely represents the maximum age for the cessation of the northward subduction in the Hegenshan ophiolite-arc-accretion belt.

Complex Contact Angles Calculated from Capillary Rise Measurements on Rock Fracture Faces

NASA Astrophysics Data System (ADS)

Perfect, E.; Gates, C. H.; Brabazon, J. W.; Santodonato, L. J.; Dhiman, I.; Bilheux, H.; Bilheux, J. C.; Lokitz, B. S.

2017-12-01

Contact angles for fluids in unconventional reservoir rocks are needed for modeling hydraulic fracturing leakoff and subsequent oil and gas extraction. Contact angle measurements for wetting fluids on rocks are normally performed using polished flat surfaces. However, such prepared surfaces are not representative of natural rock fracture faces, which have been shown to be rough over multiple scales. We applied a variant of the Wilhelmy plate method for determining contact angle from the height of capillary rise on a vertical surface to the wetting of rock fracture faces by water in the presence of air. Cylindrical core samples (5.05 cm long x 2.54 cm diameter) of Mancos shale and 6 other rock types were investigated. Mode I fractures were created within the cores using the Brazilian method. Each fractured core was then separated into halves exposing the fracture faces. One fracture face from each rock type was oriented parallel to a collimated neutron beam in the CG-1D imaging instrument at ORNL's High Flux Isotope Reactor. Neutron radiography was performed using the multi-channel plate detector with a spatial resolution of 50 μm. Images were acquired every 60 s after a water reservoir contacted the base of the fracture face. The images were normalized to the initial dry condition so that the upward movement of water on the fracture face was clearly visible. The height of wetting at equilibrium was measured on the normalized images using ImageJ. Contact angles were also measured on polished flat surfaces using the conventional sessile drop method. Equilibrium capillary rise on the exposed fracture faces was up to 8.5 times greater than that predicted for polished flat surfaces from the sessile drop measurements. These results indicate that rock fracture faces are hyperhydrophilic (i.e., the height of capillary rise is greater than that predicted for a contact angle of zero degrees). The use of complex numbers permitted calculation of imaginary contact angles for such surfaces. This analysis yielded a continuum of contact angles (real above, and imaginary below, zero degrees) that can be used to investigate relationships with properties such surface roughness and porosity. It should be noted these are preliminary, unreplicated results and further research will be needed to verify them and refine the approach.

Preliminary results of thermal conductivity and elastic wave velocity measurements of various rock samples collected from outcrops in hanging wall of the Alpine Fault

NASA Astrophysics Data System (ADS)

Lin, W.; Tadai, O.; Shigematsu, N.; Nishikawa, O.; Mori, H.; Townend, J.; Capova, L.; Saito, S.; Kinoshita, M.

2015-12-01

The Alpine Fault is a mature active fault zone likely to rupture in the near future and DFDP aims to measure physical and chemical conditions within the fault. DFDP-2B borehole was drilled into hanging wall of the Alpine Fault. Downhole temperature measurements carried out in DFDP-2B borehole showed that the geothermal gradient in the hanging wall of the fault is very high, likely reaching to 130-150 °C/km (Sutherland et al., 2015 AGU Fall Meeting). To explain this abnormal feature, the determination of thermal properties of all the rock types in the hanging wall of the Alpine Fault is essential. To measure thermal properties and elastic wave velocities, we collected six typical rock block samples from outcrops in Stony creek and Gaunt creek. These include ultramylonite, mylonite, muscovite schist, garnet amphibolite, protomylonite and schist, which are representative of the hanging wall of the Alpine Fault. Their wet bulk densities are 2.7 - 2.8 g/cm3, and porosities are 1.4 - 3.0%. We prepared a pair of 4 cm cube specimens of each rock type with one flat plane parallel to the foliation. First, we measured thermal conductivity by the transient plane heat source (hot disc) method in a bulk mode, i.e. to deal with the rock as an isotropic material. However, several samples have clearly visible foliation and are likely to be anisotropic. Thus, the data measured in bulk mode provided an average value of the rocks in the range of approximately 2.4 - 3.2 W/mK. The next step will be to measure thermal conductivity in an anisotropic mode. We also measured P wave velocity (Vp) using the same samples, but in two directions, i.e. parallel and perpendicular to the foliation, respectively. Our preliminary results suggested that Vp is anisotropic in all the six rocks. Generally, Vp parallel to foliation is higher than that in the perpendicular direction. Vp in the parallel direction ranged in 5.5 - 6.0 km/s, whereas in the perpendicular direction it was 4.4 - 5.5 km/s. We thank the PIs and onsite staffs of the DFDP-2 project for their helps to collecting rock samples, and the financial support by JSPS (Japan-New Zealand Joint Research Program).

Plume magmatism and crustal growth at 2.9 to 3.0 Ga in the Steep Rock and Lumby Lake area, Western Superior Province

NASA Astrophysics Data System (ADS)

Tomlinson, K. Y.; Hughes, D. J.; Thurston, P. C.; Hall, R. P.

1999-01-01

The greenstone belts of the western Superior Province are predominantly 2.78 to 2.69 Ga and provide evidence of oceanic and arc volcanism during the accretionary phase of development of the Superior Province. There is also scattered evidence of Meso-Archean crust (predominantly 2.9 to 3.0 Ga) within the western Superior Province. The Meso-Archean greenstone belts commonly contain platformal sediments and unconformably overlie granitoid basement. The platformal sediments occur associated with komatiitic and tholeiitic volcanic rocks that suggest a history of magmatism associated with rifting during the Meso-Archean. The central Wabigoon Subprovince is a key area of Meso-Archean crust and in its southern portion comprises the Steep Rock, Finlayson and Lumby Lake greenstone belts. The Steep Rock greenstone belt unconformably overlies 3 Ga continental basement and contains platformal sediments succeeded by komatiitic and tholeiitic volcanic rocks. The Lumby Lake greenstone belt contains thick sequences of mafic volcanics, a number of komatiite horizons, and thin platformal sedimentary units. The two belts are joined by the predominantly mafic volcanic Finlayson greenstone belt. The volcanics throughout these three greenstone belts may be correlated to some extent and a range of basaltic and komatiite types is present. Al-undepleted komatiites present in the Lumby Lake greenstone belt have an Al 2O 3/TiO 2 ratio ranging from 14 to 27 and (Gd/Yb) N from 0.7 to 1.3. These are divided into basaltic komatiites with generally unfractionated mantle-normalised multi-element profiles, and spinifex-textured high-Mg basalts with slightly light REE enriched multi-element profiles and small negative Nb and Ta anomalies. The unfractionated basaltic komatiites represent high degree partial melts of the upper mantle whereas the spinifex-textured high-Mg basalts represent evolutionary products of the komatiite liquids following olivine and chromite fractionation and crustal contamination. Al-depleted komatiites are present in both the Lumby Lake and Steep Rock belts and have Al 2O 3/TiO 2 ratio ranges from 2.5 to 5. These display strong enrichment in the light REE and Nb and strong depletion in the heavy REE and Y ((Gd/Yb) N=2-4). They represent a deep mantle plume source generated from a high degree of partial melting in the majorite garnet stability field. The basaltic flows in all three greenstone belts are predominantly slightly light REE depleted and represent a slightly depleted upper mantle source. Basalts spatially associated with the unfractionated basaltic komatiites and the slightly light REE enriched spinifex-textured high-Mg basalts are also slightly enriched in light REE and have negative Nb and Ta anomalies. These basalts represent evolved products of the primitive basaltic komatiites and enriched spinifex-textured high-Mg basalts after further crustal contamination and olivine and clinopyroxene fractionation. The geochemical stratigraphy in the Lumby Lake belt is consistent with an ascending mantle plume model. The light REE depleted basalts were derived from upper mantle melted by an ascending mantle plume. These are overlain by the unfractionated basaltic komatiites and their evolutionary products which represent hotter plume head material derived from a mixture of plume mantle and entrained depleted upper mantle. In turn, these are overlain by strongly light REE and HFSE enriched komatiites that represent a deep plume source that has not been mixed with depleted mantle and are, therefore, likely to have been derived from a plume core or tail. Volcanism was protracted in these three greenstone belts lasting ca. 70 Ma and combined stratigraphic evidence from the Lumby Lake and Steep Rock belts suggests that more than one plume may have ascended and tapped the same mantle sources, over time, within the area. Plume magmatism and rifting of continental platforms thus appears to have been an important feature of crustal development in the Meso-Archean.

Garnet clinopyroxenite layers from the mantle sequences of the Northern Apennine ophiolites (Italy): Evidence for recycling of crustal material

NASA Astrophysics Data System (ADS)

Montanini, A.; Tribuzio, R.; Thirlwall, M.

2012-10-01

This study aims to define the origin of garnet clinopyroxenite layers from the mantle sequences of the External Ligurian ophiolites. These mantle sequences retain a subcontinental origin and were exposed at a Jurassic ocean-continent transition. The garnet clinopyroxenites are mafic rocks with Mg# values of 66-71. Their chondrite-normalised REE patterns are characterised by severe LREE depletion (CeN/SmN=0.1-0.2) and nearly flat (Type-A pyroxenites) to moderately enriched HREE (Type-B pyroxenites). In addition, Type-A pyroxenites display a small positive Eu anomaly. The whole-rock REE variations are paralleled by the garnet REE compositions. We attribute the major and trace element characteristics of the garnet clinopyroxenites to recycling of gabbroic protoliths that underwent partial melting under eclogite facies conditions. The garnet clinopyroxenites may represent variably evolved garnet+clinopyroxene cumulates formed by eclogite-derived melts. In an alternative hypothesis, Type-A and -B pyroxenites are residual rocks after eclogite melting and cumulates derived from the eclogite melts, respectively. The high pressure fractionation event that gave rise to the garnet clinopyroxenites is considered of Triassic age on the basis of Sm-Nd and Lu-Hf isotope correlations. The Nd-Hf isotopic compositions of the garnet clinopyroxenites in the Triassic (ɛNd=+4.7 to +7.6, ɛHf=+4.4 to +12.8) lie below the mantle array, in agreement with recycled ancient MOR-type material. The oxygen isotopic composition of garnet and clinopyroxene from the garnet clinopyroxenites (δ18O=+4.9‰ to +5.2‰) may be reconciled with subduction-related recycling of the lowermost oceanic crust, or delamination and foundering of underplated gabbros from the continental lithosphere. The potential involvement of the garnet clinopyroxenites in the melting processes that gave rise to the MOR-type oceanic crust in the Jurassic would account for the moderate Nd isotope variability and the garnet geochemical signature of the ophiolitic basalts.

Volcanic settings and their reservoir potential: An outcrop analog study on the Miocene Tepoztlán Formation, Central Mexico

NASA Astrophysics Data System (ADS)

Lenhardt, Nils; Götz, Annette E.

2011-07-01

The reservoir potential of volcanic and associated sedimentary rocks is less documented in regard to groundwater resources, and oil and gas storage compared to siliciclastic and carbonate systems. Outcrop analog studies within a volcanic setting enable to identify spatio-temporal architectural elements and geometric features of different rock units and their petrophysical properties such as porosity and permeability, which are important information for reservoir characterization. Despite the wide distribution of volcanic rocks in Mexico, their reservoir potential has been little studied in the past. In the Valley of Mexico, situated 4000 m above the Neogene volcanic rocks, groundwater is a matter of major importance as more than 20 million people and 42% of the industrial capacity of the Mexican nation depend on it for most of their water supply. Here, we present porosity and permeability data of 108 rock samples representing five different lithofacies types of the Miocene Tepoztlán Formation. This 800 m thick formation mainly consists of pyroclastic rocks, mass flow and fluvial deposits and is part of the southern Transmexican Volcanic Belt, cropping out south of the Valley of Mexico and within the two states of Morelos and Mexico State. Porosities range from 1.4% to 56.7%; average porosity is 24.8%. Generally, permeabilities are low to median (0.2-933.3 mD) with an average permeability of 88.5 mD. The lavas are characterized by the highest porosity values followed by tuffs, conglomerates, sandstones and tuffaceous breccias. On the contrary, the highest permeabilities can be found in the conglomerates, followed by tuffs, tuffaceous breccias, sandstones and lavas. The knowledge of these petrophysical rock properties provides important information on the reservoir potential of volcanic settings to be integrated to 3D subsurface models.

Volcanic glass in Cretaceous dacites and rhyolites of the Paraná Magmatic Province, southern Brazil: Characterization and quantification by XRD-Rietveld

NASA Astrophysics Data System (ADS)

Andrade, Fábio Ramos Dias de; Polo, Liza Angélica; Janasi, Valdecir de Assis; Carvalho, Flávio Machado de Souza

2018-04-01

Acidic rocks are a significant component of the Cretaceous Paraná Magmatic Province, occurring in different stratigraphic positions, and often forming deposits of complex and as yet poorly defined architecture. Vitrophyric varieties are surprisingly abundant for a volcanic sequence of this age, and are composed of predominant glass plus plagioclase (labradorite-andesine), pyroxenes (augite ± pigeonite and orthopyroxene), Ti-rich magnetite, and traces of apatite. Hypocrystalline rocks, largely derived from devitrification, additionally contain sanidine, cristobalite, and quartz. The negative correlation between the abundance of these minerals and the amount of glass suggests that these latter phases formed by devitrification. Modal analysis using a combined XRD Rietveld-RIR method detected glass contents between 0 and 85 wt% % in a set of representative samples of Palmas-type acidic rocks from southern Brazil with dacite to rhyolite composition. Modal compositions determined by XRD and by scanning electron microscope are in good agreement with each other, and were checked against whole-rock XRF chemical data. Water contents up to 4 wt% show a positive linear correlation with the amount of glass, and are inferred to be mostly secondary, as original (pre-eruptive) H2O dissolved in melts is inferred to have been < 1.5 wt% in all rocks. Glass is the only water bearing phase in the studied samples, which lack low temperature hydrated phases. Water loss during devitrification appears to have occurred along fractures, and was accompanied by Na loss and, in some samples, also Ca, Rb and Sr loss. The rapid and inexpensive method of modal analyses of glassy rocks developed here may be a useful tool for mapping acidic volcanic rocks in southern Paraná Magmatic Province, and also to identify the architecture of these deposits.

Three-dimensional distribution of igneous rocks near the Pebble porphyry Cu-Au-Mo deposit in southwestern Alaska: constraints from regional-scale aeromagnetic data

USGS Publications Warehouse

Anderson, Eric D.; Zhou, Wei; Li, Yaoguo; Hitzman, Murray W.; Monecke, Thomas; Lang, James R.; Kelley, Karen D.

2014-01-01

Aeromagnetic data helped us to understand the 3D distribution of plutonic rocks near the Pebble porphyry copper deposit in southwestern Alaska, USA. Magnetic susceptibility measurements showed that rocks in the Pebble district are more magnetic than rocks of comparable compositions in the Pike Creek–Stuyahok Hills volcano-plutonic complex. The reduced-to-pole transformation of the aeromagnetic data demonstrated that the older rocks in the Pebble district produce strong magnetic anomaly highs. The tilt derivative transformation highlighted northeast-trending lineaments attributed to Tertiary volcanic rocks. Multiscale edge detection delineated near-surface magnetic sources that are mostly outward dipping and coalesce at depth in the Pebble district. The total horizontal gradient of the 10-km upward-continued magnetic data showed an oval, deep magnetic contact along which porphyry deposits occur. Forward and inverse magnetic modeling showed that the magnetic rocks in the Pebble district extend to depths greater than 9 km. Magnetic inversion was constrained by a near-surface, 3D geologic model that is attributed with measured magnetic susceptibilities from various rock types in the region. The inversion results indicated that several near-surface magnetic sources with moderate susceptibilities converge with depth into magnetic bodies with higher susceptibilities. This deep magnetic source appeared to rise toward the surface in several areas. An isosurface value of 0.02 SI was used to depict the magnetic contact between outcropping granodiorite and nonmagnetic sedimentary host rocks. The contact was shown to be outward dipping. At depths around 5 km, nearly the entire model exceeded the isosurface value indicating the limits of nonmagnetic host material. The inversion results showed the presence of a relatively deep, northeast-trending magnetic low that parallels lineaments mapped by the tilt derivative. This deep low represents a strand of the Lake Clark fault.

World Map Showing Surface and Subsurface Distribution, and Lithologic Character of Middle and Late Neoproterozoic Rocks

USGS Publications Warehouse

Stewart, John H.

2007-01-01

INTRODUCTION The map was prepared to outline the basic information on where Neoproterozoic rocks are present in the World, and of the lithologic character of these rocks. The information provides a better understanding of major Neoproterozoic tectonic subdivisions useful in paleogeographic and plate tectonic reconstructions. The time frame of the map is within the middle and late Neoproterozoic from approximately 870 to 540 Ma and is after widespread Mesoproterozoic Grenville-age collisional events that are considered to have formed the hypothetical supercontinent of Rodinia. Much of the time represented by the map is interpreted to be during the fragmentation of Rodinia. The recognition of Neoproterozoic rocks is commonly difficult because of limited isotopic or paloeontological dating. Thus, some rocks shown on the map could be older or younger than the age indicated. However, at the scale of the map the the problem may be minor. Enough information seems to be available to indicate the general age of the rocks. Many of the successions contain diamictite deposits considered to be glaciogenic and dated as middle or late Neoproterozoic. These deposits thus show a rough correlation of middle and late Neoproterozoic rocks of the world. The map is a Richardson map projection, except for Antarctica which is a polar projection. The map was prepared from about 650 references, shown in the text linked below under 'Sources of Information', used to outline distribution patterns, determine rock types, and provide information on the regional and local geologic framework of the rocks. The focus of the references is on the geologic information needed to prepare the map. Other information, such as plate tectonic reconstructions or paleomagnetic studies is generally not included. The 'Sources of Information' lists references alphabetically for each of 14 regions. In brackets is a code for each area. These codes provide help in locating the specific regions in the references.

The Apollo 16 regolith - A petrographically-constrained chemical mixing model

NASA Technical Reports Server (NTRS)

Kempa, M. J.; Papike, J. J.; White, C.

1980-01-01

A mixing model for Apollo 16 regolith samples has been developed, which differs from other A-16 mixing models in that it is both petrographically constrained and statistically sound. The model was developed using three components representative of rock types present at the A-16 site, plus a representative mare basalt. A linear least-squares fitting program employing the chi-squared test and sum of components was used to determine goodness of fit. Results for surface soils indicate that either there are no significant differences between Cayley and Descartes material at the A-16 site or, if differences do exist, they have been obscured by meteoritic reworking and mixing of the lithologies.

Streamlined Archaeo-geophysical Data Processing and Integration for DoD Field Use

DTIC Science & Technology

2012-04-01

names can now be renamed and are, by default, named B1, B2, etc. It is hard to tell if Band buttons (B1, B2, etc.) are depressed or not. Contrast...consisted of a man-made depression surrounded by low ridges. That aspect of the fort’s layout is discussed further in Chapter 5. 4.1.5 SITE HISTORY...larger rocks, natural depressions representing concentrations of relatively magnetic topsoil, etc., (Bevan 1998). Pits are a common feature type, but

Microplastic Pollution in Table Salts from China.

PubMed

Yang, Dongqi; Shi, Huahong; Li, Lan; Li, Jiana; Jabeen, Khalida; Kolandhasamy, Prabhu

2015-11-17

Microplastics have been found in seas all over the world. We hypothesize that sea salts might contain microplastics, because they are directly supplied by seawater. To test our hypothesis, we collected 15 brands of sea salts, lake salts, and rock/well salts from supermarkets throughout China. The microplastics content was 550-681 particles/kg in sea salts, 43-364 particles/kg in lake salts, and 7-204 particles/kg in rock/well salts. In sea salts, fragments and fibers were the prevalent types of particles compared with pellets and sheets. Microplastics measuring less than 200 μm represented the majority of the particles, accounting for 55% of the total microplastics, and the most common microplastics were polyethylene terephthalate, followed by polyethylene and cellophane in sea salts. The abundance of microplastics in sea salts was significantly higher than that in lake salts and rock/well salts. This result indicates that sea products, such as sea salts, are contaminated by microplastics. To the best of our knowledge, this is the first report on microplastic pollution in abiotic sea products.

Pellet microfossils: Possible evidence for metazoan life in Early Proterozoic time

PubMed Central

Robbins, Eleanora Iberall; Porter, Karen Glaus; Haberyan, Kurt A.

1985-01-01

Microfossils resembling fecal pellets occur in acid-resistant residues and thin sections of Middle Cambrian to Early Proterozoic shale. The cylindrical microfossils average 50 × 110 μm and are the size and shape of fecal pellets produced by microscopic animals today. Pellets occur in dark gray and black rocks that were deposited in the facies that also preserves sulfide minerals and that represent environments analogous to those that preserve fecal pellets today. Rocks containing pellets and algal microfossils range in age from 0.53 to 1.9 gigayears (Gyr) and include Burgess Shale, Greyson and Newland Formations, Rove Formation, and Gunflint Iron-Formation. Similar rock types of Archean age, ranging from 2.68 to 3.8 Gyr, were barren of pellets. If the Proterozoic microfossils are fossilized fecal pellets, they provide evidence of metazoan life and a complex food chain at 1.9 Gyr ago. This occurrence predates macroscopic metazoan body fossils in the Ediacaran System at 0.67 Gyr, animal trace fossils from 0.9 to 1.3 Gyr, and fossils of unicellular eukaryotic plankton at 1.4 Gyr. Images PMID:16593599

Rock Cycle Roulette.

ERIC Educational Resources Information Center

Schmidt, Stan M.; Palmer, Courtney

2000-01-01

Introduces an activity on the rock cycle. Sets 11 stages representing the transitions of an earth material in the rock cycle. Builds six-sided die for each station, and students move to the stations depending on the rolling side of the die. Evaluates students by discussing several questions in the classroom. Provides instructional information for…

Molecular diversity of bacterial communities from subseafloor rock samples in a deep-water production basin in Brazil.

PubMed

von der Weid, Irene; Korenblum, Elisa; Jurelevicius, Diogo; Rosado, Alexandre Soares; Dino, Rodolfo; Sebastian, Gina Vasquez; Seldin, Lucy

2008-01-01

The deep subseafloor rock in oil reservoirs represents a unique environment in which a high oilcontamination and very low biomass can be observed. Sampling this environment has been a challenge owing to the techniques used for drilling and coring. In this study, the facilities developed by the Brazilian oil company PETROBRAS for accessing deep subsurface oil reservoirs were used to obtain rock samples at 2,822-2,828 m below the ocean floor surface from a virgin field located in the Atlantic Ocean, Rio de Janeiro. To address the bacterial diversity of these rock samples, PCR amplicons were obtained using the DNA from four core sections and universal primers for 16S rRNA and for APS reductase (aps) genes. Clone libraries were generated from these PCR fragments and 87 clones were sequenced. The phylogenetic analyses of the 16S rDNA clone libraries showed a wide distribution of types in the domain bacteria in the four core samples, and the majority of the clones were identified as belonging to Betaproteobacteria. The sulfate-reducing bacteria community could only be amplified by PCR in one sample, and all clones were identified as belonging to Gammaproteobacteria. For the first time, the bacterial community was assessed in such deep subsurface environment.

The thermal maturation degree of organic matter from source rocks revealed by wells logs including examples from Murzuk Basin, Libya

DOE Office of Scientific and Technical Information (OSTI.GOV)

Negoita, V.; Gheorghe, A.

1995-08-01

The customary technique used to know the organic matter quantity per rock volume it as well as the organic matter maturation stage is based on geochemical analyses accomplished on a preselected number of samples and cuttings drawn from boreholes during the drilling period. But the same objectives can be approached without any extra cost using the continuous measurements of well logs recorded in each well from the ground surface to the total depth. During the diagenetic stage, the identification of potential source rocks out of which no hydrocarbon have been generated may be carried out using a well logging suitemore » including Gamma Ray Spectrometry, the Compensated Neutron/Litho Density combination and a Dual Induction/Sonic Log. During the catagenetic stage the onset of oil generation brings some important changes in the organic matter structure as well as in the fluid distribution throughout the pore space of source rocks. The replacement of electric conductive water by electric non-conductive hydrocarbons, together with water and oil being expelled from source rocks represent a process of different intensities dependent of time/temperature geohistory and kerogen type. The different generation and expulsion scenarios of hydrocarbons taking place during the catagenetic and metagenetic stages of source rocks are very well revealed by Induction and Laterolog investigations. Several crossplots relating vitrinite reflectance, total organic carbon and log-derived physical parameters are illustrated and discussed. The field applications are coming from Murzuk Basin, where Rompetrol of Libya is operating.« less

The underwater photic environment of Cape Maclear, Lake Malawi: comparison between rock- and sand-bottom habitats and implications for cichlid fish vision.

PubMed

Sabbah, Shai; Gray, Suzanne M; Boss, Emmanuel S; Fraser, James M; Zatha, Richard; Hawryshyn, Craig W

2011-02-01

Lake Malawi boasts the highest diversity of freshwater fishes in the world. Nearshore sites are categorized according to their bottom substrate, rock or sand, and these habitats host divergent assemblages of cichlid fishes. Sexual selection driven by mate choice in cichlids led to spectacular diversification in male nuptial coloration. This suggests that the spectral radiance contrast of fish, the main determinant of visibility under water, plays a crucial role in cichlid visual communication. This study provides the first detailed description of underwater irradiance, radiance and beam attenuation at selected sites representing two major habitats in Lake Malawi. These quantities are essential for estimating radiance contrast and, thus, the constraints imposed on fish body coloration. Irradiance spectra in the sand habitat were shifted to longer wavelengths compared with those in the rock habitat. Beam attenuation in the sand habitat was higher than in the rock habitat. The effects of water depth, bottom depth and proximity to the lake bottom on radiometric quantities are discussed. The radiance contrast of targets exhibiting diffused and spectrally uniform reflectance depended on habitat type in deep water but not in shallow water. In deep water, radiance contrast of such targets was maximal at long wavelengths in the sand habitat and at short wavelengths in the rock habitat. Thus, to achieve conspicuousness, color patterns of rock- and sand-dwelling cichlids would be restricted to short and long wavelengths, respectively. This study provides a useful platform for the examination of cichlid visual communication.

The Resurrection Peninsula ophiolite

USGS Publications Warehouse

Nelson, Steven W.; Miller, M.L.; Dumoulin, Julie A.; Nelson, Steven W.; Hamilton, Thomas D.

1989-01-01

The Resurrection Peninsula forms the east side of Resurrection Bay (fig. 3). Relief ranges from 437 m (1,434 ft) at the southern end of the peninsula to more than 1,463 m (4,800 ft) opposite the head of the bay. All rock units composing the informally named Resurrection Peninsula ophiolite of Nelson and others (1987) are visible or accessible by boat."Ophiolite" has been a geologic term since 1827 (Coleman, 1977). The term "ophiolite" initially referred to the rock serpentinite; the Greek root "ophi" (meaning snake or serpent) alluded to the greenish, mottled, and shiny appearance of serpentinites. In 1927, Steinmann described a rock association in the Alps, sometimes known as the "Steinmann Trinity', consisting of serpentine, diabase and spilitic lavas, and chert. Recognition of this suite led to the idea that ophiolites represent submarine magmatism that took place early in the development of a eugeosyncline. In the early 1970s the Steinmann Trinity was reconsidered in light of the plate tectonic theory, new petrologic studies, and the recognition of abducted oceanic lithosphere in orogenic belts of the world. In 1972 at a Geological Society of America Penrose Conference (Anonymous, 1972) the term "ophiolite" was defined as a distinctive assemblage of mafic to ultramafic rocks, with no emphasis on their origin. A complete ophiolite should contain, from bottom to top:1) Tectonized ultramafic rocks (more or less serpentinized)2) Gabbro complex containing cumulus textures and commonly cumulus peridotites3) Mafic sheeted-dike complex, grading upward into;4) Submarine pillow lavas of basaltic composition. Common associated rock types include plagiogranite (Na-rich) and an overlying sedimentary section typically dominated by chert.

Paleoecology and paleoceanography of the Athel silicilyte, Ediacaran-Cambrian boundary, Sultanate of Oman.

PubMed

Stolper, D A; Love, G D; Bates, S; Lyons, T W; Young, E; Sessions, A L; Grotzinger, J P

2017-05-01

The Athel silicilyte is an enigmatic, hundreds of meters thick, finely laminated quartz deposit, in which silica precipitated in deep water (>~100-200 m) at the Ediacaran-Cambrian boundary in the South Oman Salt Basin. In contrast, Meso-Neoproterozoic sinks for marine silica were dominantly restricted to peritidal settings. The silicilyte is known to contain sterane biomarkers for demosponges, which today are benthic, obligately aerobic organisms. However, the basin has previously been described as permanently sulfidic and time-equivalent shallow-water carbonate platform and evaporitic facies lack silica. The Athel silicilyte thus represents a unique and poorly understood depositional system with implications for late Ediacaran marine chemistry and paleoecology. To address these issues, we made petrographic observations, analyzed biomarkers in the solvent-extractable bitumen, and measured whole-rock iron speciation and oxygen and silicon isotopes. These data indicate that the silicilyte is a distinct rock type both in its sedimentology and geochemistry and in the original biology present as compared to other facies from the same time period in Oman. The depositional environment of the silicilyte, as compared to the bounding shales, appears to have been more reducing at depth in sediments and possibly bottom waters with a significantly different biological community contributing to the preserved biomarkers. We propose a conceptual model for this system in which deeper, nutrient-rich waters mixed with surface seawater via episodic mixing, which stimulated primary production. The silica nucleated on this organic matter and then sank to the seafloor, forming the silicilyte in a sediment-starved system. We propose that the silicilyte may represent a type of environment that existed elsewhere during the Neoproterozoic. These environments may have represented an important locus for silica removal from the oceans. © 2017 John Wiley & Sons Ltd.

Processes of high-T fluid-rock interaction during gold mineralization in carbonate-bearing metasediments: the Navachab gold deposit, Namibia

NASA Astrophysics Data System (ADS)

Dziggel, A.; Wulff, K.; Kolb, J.; Meyer, F. M.

2009-08-01

The Navachab gold deposit in the Damara belt of central Namibia is hosted by a near-vertical sequence of amphibolite facies shelf-type metasediments, including marble, calc-silicate rock, and biotite schist. Petrologic and geochemical data were collected in the ore, alteration halos, and the wall rock to evaluate transport of elements and interaction between the wall rock and the mineralizing fluid. The semi-massive sulfide lenses and quartz-sulfide veins are characterized by a complex polymetallic ore assemblage, comprising pyrrhotite, chalcopyrite, sphalerite, and arsenopyrite, native bismuth, gold, bismuthinite, and bismuth tellurides. Mass balance calculations indicate the addition of up to several orders of magnitude of Au, Bi, As, Ag, and Cu. The mineralized zones also record up to eightfold higher Mn and Fe concentrations. The semi-massive sulfide lenses are situated in the banded calc-silicate rock. Petrologic and textural data indicate that they represent hydraulic breccias that contain up to 50 vol.% ore minerals, and that are dominated by a high-temperature (T) alteration assemblage of garnet-clinopyroxene-K-feldspar-quartz. The quartz-sulfide veins crosscut all lithological units. Their thickness and mineralogy is strongly controlled by the composition and rheological behavior of the wall rocks. In the biotite schist and calc-silicate rock, they are up to several decimeters thick and quartz-rich, whereas in the marble, the same veins are only a few millimeters thick and dominated by sulfides. The associated alteration halos comprise (1) an actinolite-quartz alteration in the biotite schist, (2) a garnet-clinopyroxene-K-feldspar-quartz alteration in the marble and calc-silicate rock, and (3) a garnet-biotite alteration that is recorded in all rock types except the marble. The hydrothermal overprint was associated with large-scale carbonate dissolution and a dramatic increase in CO2 in the ore fluid. Decarbonation of wall rocks, as well as a low REE content of the ore fluid resulted in the mobilization of the REE, and the decoupling of the LREE from the HREE. The alteration halos not only parallel the mineralized zones, but may also follow up single layers away from the mineralization. Alteration is far more pronounced facing upward, indicating that the rocks were steep when veining occurred. The petrologic and geochemical data indicate that the actinolite-quartz- and garnet-clinopyroxene-K-feldspar-quartz alterations formed in equilibrium with a fluid (super-) saturated in Si, and were mainly controlled by the composition of the wall rocks. In contrast, the garnet-biotite alteration formed by interaction with a fluid undersaturated in Si, and was mainly controlled by the fluid composition. This points to major differences in fluid-rock ratios and changes in fluid composition during alteration. The alteration systematics and geometry of the hydrothermal vein system are consistent with cyclic fluctuations in fluid pressure during fault valve action.

Digital Bedrock Compilation: A Geodatabase Covering Forest Service Lands in California

NASA Astrophysics Data System (ADS)

Elder, D.; de La Fuente, J. A.; Reichert, M.

2010-12-01

This digital database contains bedrock geologic mapping for Forest Service lands within California. This compilation began in 2004 and the first version was completed in 2005. Second publication of this geodatabase was completed in 2010 and filled major gaps in the southern Sierra Nevada and Modoc/Medicine Lake/Warner Mountains areas. This digital map database was compiled from previously published and unpublished geologic mapping, with source mapping and review from California Geological Survey, the U.S. Geological Survey and others. Much of the source data was itself compilation mapping. This geodatabase is huge, containing ~107,000 polygons and ~ 280,000 arcs. Mapping was compiled from more than one thousand individual sources and covers over 41,000,000 acres (~166,000 km2). It was compiled from source maps at various scales - from ~ 1:4,000 to 1:250,000 and represents the best available geologic mapping at largest scale possible. An estimated 70-80% of the source information was digitized from geologic mapping at 1:62,500 scale or better. Forest Service ACT2 Enterprise Team compiled the bedrock mapping and developed a geodatabase to store this information. This geodatabase supports feature classes for polygons (e.g, map units), lines (e.g., contacts, boundaries, faults and structural lines) and points (e.g., orientation data, structural symbology). Lookup tables provide detailed information for feature class items. Lookup/type tables contain legal values and hierarchical groupings for geologic ages and lithologies. Type tables link coded values with descriptions for line and point attributes, such as line type, line location and point type. This digital mapping is at the core of many quantitative analyses and derivative map products. Queries of the database are used to produce maps and to quantify rock types of interest. These include the following: (1) ultramafic rocks - where hazards from naturally occurring asbestos are high, (2) granitic rocks - increased erosion hazards, (3) limestone, chert, sedimentary rocks - paleontological resources (Potential Fossil Yield Classification maps), (4) calcareous rocks (cave resources, water chemistry), and (5) lava flows - lava tubes (more caves). Map unit groupings (e.g., belts, terranes, tectonic & geomorphic provinces) can also be derived from the geodatabase. Digital geologic mapping was used in ground water modeling to predict effects of tunneling through the San Bernardino Mountains. Bedrock mapping is used in models that characterize watershed sediment regimes and quantify anthropogenic influences. When combined with digital geomorphology mapping, this geodatabase helps to assess landslide hazards.

10 CFR 960.3-2-1 - Site screening for potentially acceptable sites.

Code of Federal Regulations, 2011 CFR

2011-01-01

... that contain rock formations of suitable depth, thickness, and lateral extent and have structural... require diversity of geohydrologic settings and rock types and consideration of regionality, as specified... provisions for diversity of geohydrologic settings, diversity of rock types, and regionality (§§ 960.3-1-1...

Alkaline magmatism in the Amambay area, NE Paraguay: The Cerro Sarambí complex

NASA Astrophysics Data System (ADS)

Gomes, C. B.; Velázquez, V. F.; Azzone, R. G.; Paula, G. S.

2011-07-01

The Early Cretaceous alkaline magmatism in the northeastern region of Paraguay (Amambay Province) is represented by stocks, plugs, dikes, and dike swarms emplaced into Carboniferous to Triassic-Jurassic sediments and Precambrian rocks. This magmatism is tectonically related to the Ponta Porã Arch, a NE-trending structural feature, and has the Cerro Sarambí and Cerro Chiriguelo carbonatite complexes as its most significant expressions. Other alkaline occurrences found in the area are the Cerro Guazú and the small bodies of Cerro Apuá, Arroyo Gasory, Cerro Jhú, Cerro Tayay, and Cerro Teyú. The alkaline rocks comprise ultramafic-mafic, syenitic, and carbonatitic petrographic associations in addition to lithologies of variable composition and texture occurring as dikes; fenites are described in both carbonatite complexes. Alkali feldspar and clinopyroxene, ranging from diopside to aegirine, are the most abundant minerals, with feldspathoids (nepheline, analcime), biotite, and subordinate Ti-rich garnet; minor constituents are Fe-Ti oxides and cancrinite as the main alteration product from nepheline. Chemically, the Amambay silicate rocks are potassic to highly potassic and have miaskitic affinity, with the non-cumulate intrusive types concentrated mainly in the saturated to undersaturated areas in silica syenitic fields. Fine-grained rocks are also of syenitic affiliation or represent more mafic varieties. The carbonatitic rocks consist dominantly of calciocarbonatites. Variation diagrams plotting major and trace elements vs. SiO 2 concentration for the Cerro Sarambí rocks show positive correlations for Al 2O 3, K 2O, and Rb, and negative ones for TiO 2, MgO, Fe 2O 3, CaO, P 2O 5, and Sr, indicating that fractional crystallization played an important role in the formation of the complex. Incompatible elements normalized to primitive mantle display positive spikes for Rb, La, Pb, Sr, and Sm, and negative for Nb-Ta, P, and Ti, as these negative anomalies are considerably more pronounced in the carbonatites. Chondrite-normalized REE patterns point to the high concentration of these elements and to the strong LRE/HRE fractionation. The Amambay rocks are highly enriched in radiogenic Sr and have TDM model ages that vary from 1.6 to 1.1 Ga, suggesting a mantle source enriched in incompatible elements by metasomatic events in Paleo-Mesoproterozoic times. Data are consistent with the derivation of the Cerro Sarambí rocks from a parental magma of lamprophyric (minette) composition and suggest an origin by liquid immiscibility processes for the carbonatites.

Architecture of ductile-type, hyper-extended passive margins: Geological constraints from the inverted Cretaceous basin of the North-Pyrenean Zone ('Chaînons Béarnais', Western Pyrenees)

NASA Astrophysics Data System (ADS)

Corre, Benjamin; Lagabrielle, Yves; Labaume, Pierre; Lahfid, Abdeltif; Boulvais, Philippe; Bergamini, Geraldine; Fourcade, Serge; Clerc, Camille

2017-04-01

Sub-continental lithospheric mantle rocks are exhumed at the foot of magma-poor distal passive margins as a response to extreme stretching of the continental crust during plate separation. Remnants of the Northern Iberian paleo-passive margin are now exposed in the North-Pyrenean Zone (NPZ) and represent field analogues to study the processes of continental crust thinning and subcontinental mantle exhumation. The NPZ results from the inversion of basins opened between the Iberia and Europa plates during Albo-Cenomanian times. In the western NPZ, the 'Chaînons Béarnais' ranges display a fold-and-thrust structure involving the Mesozoic sedimentary cover, decoupled from its continental basement and associated with peridotite bodies in tectonic contact with Palaeozoic basement lenses of small size. Continental extension developed under hot thermal conditions, as demonstrated by the syn-metamorphic Cretaceous ductile deformation affecting both the crustal basement and the allochthonous Mesozoic cover. In this study, we present structural and geochemical data providing constraints to reconstruct the evolution of the northern Iberia paleo-margin. Field work confirms that the pre-rift Mesozoic cover is intimately associated to mantle rocks and to thin tectonic lenses of crustal basement. It also shows that the pre-rift cover was detached from its bedrock at the Keuper evaporites level and was welded to mantle rocks during their exhumation at the foot of the hyper-extended margin. The crust/mantle detachment fault is a major shear zone characterized by anastomosed shear bands defining a plurimetric phacoidal fabric at the top of the serpentinized mantle. The detachment is marked by a layer of metasomatic rocks, locally 20 meters thick, made of talc-chlorite-pyrite-rich rocks that developped under greenschist facies conditions. Raman Spectroscopy on Carbonaceous Materials (RSCM), performed on the Mesozoic cover reveal that the entire sedimentary pile underwent temperatures ranging between 200°C and 480°C. We show that: (i) at the site of mantle rocks exhumation, the boudinaged pre-rift sediments have undergone drastic syn-metamorphic thinning with the genesis of a S0/S1 foliation and, (ii) the Paleozoic basement has been ductilely deformed, into thin tectonic lenses that remained welded to the exhumed mantle rocks. Therefore the overall crustal rheology appears dominated by shallow levels having a ductile behavior. This rheology is related to the presence of a thick pre- and syn-rift decoupled cover acting as an efficient thermal blanket. This new geological data set highlights important characteristics of ductile-type hyper-extended passive margin that cannot be obtained from the study of seismic lines. Finally, we stress that studying field analogues represents a major tool to better understand the mechanisms of extreme crustal thinning associated with mantle exhumation and their structural inheritance during tectonic inversion.

A Paleozoic Japan-type subduction-accretion system in the Beishan orogenic collage, southern Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Song, Dongfang; Xiao, Wenjiao; Windley, Brian F.; Han, Chunming; Tian, Zhonghua

2015-05-01

Magmatic arcs ascribed to oceanic lithosphere subduction played a dominant role in the construction of the accretionary Central Asian Orogenic Belt (CAOB). The Beishan orogenic collage, situated between the Tianshan Orogen to the west and the Inner Mongolia Orogen to the east, is a key area to understanding the subduction and accretionary processes of the southern CAOB. However, the nature of magmatic arcs in the Beishan and the correlation among different tectonic units along the southern CAOB are highly ambiguous. In order to investigate the subduction-accretion history of the Beishan and put a better spatial and temporal relationship among the tectonic belts along the southern CAOB, we carried out detailed field-based structural geology and LA-ICP-MS zircon U-Pb geochronological as well as geochemical studies along four cross-sections across crucial litho-tectonic units in the central segment of the Beishan, mainly focusing on the metamorphic assemblages and associated plutons and volcanic rocks. The results show that both the plutonic and volcanic rocks have geochemical characteristics similar to those of subduction-related rocks, which favors a volcanic arc setting. Zircons from all the plutonic rocks yield Phanerozoic ages and the plutons have crystallization ages ranging from 464 ± 2 Ma to 398 ± 3 Ma. Two volcanic-sedimentary rocks yield zircons with a wide age range from Phanerozoic to Precambrian with the youngest age peaks at 441 Ma and 446 Ma, estimated to be the time of formation of the volcanic rocks. These new results, combined with published data on ophiolitic mélanges from the central segment of the Beishan, favor a Japan-type subduction-accretion system in the Cambrian to Carboniferous in this part of the Paleo-Asian Ocean. The Xichangjing-Niujuanzi ophiolite probably represents a major suture zone separating different tectonic units across the Beishan orogenic collage, while the Xiaohuangshan-Jijitaizi ophiolitic mélange may represent a Carboniferous back-arc basin formed as a result of slab rollback ascribed to northward subduction of the Niujuanzi oceanic lithosphere. Subduction of this back-arc basin probably took place in the early Carboniferous, generating the widespread arc-related granitoids including adakitic plutons, and overlapping earlier arc assemblages. The Beishan orogenic collage is not the eastern extension of the Chinese Central Tianshan, but it was generated by the same north-dipping subduction system separated by the Xingxingxia transform fault, as revealed by available regional data. This contribution implies that in addition to fore-arc accretion, back-arc accretion ascribed to opening and closure of a back-arc basin may also have been a common process in the construction of the CAOB, resembling that of the Mesozoic-Cenozoic subduction-accretion system in the SW pacific.

The upper limit of maturity of natural gas generation and its implication for the Yacheng formation in the Qiongdongnan Basin, China

NASA Astrophysics Data System (ADS)

Su, Long; Zheng, Jianjing; Chen, Guojun; Zhang, Gongcheng; Guo, Jianming; Xu, Yongchang

2012-08-01

Vitrinite reflectance (VR, Ro%) measurements from residual kerogen of pyrolysis experiments were performed on immature Maoming Oil Shale substituted the samples for the gas-prone source rocks of Yacheng formation of the Qiongdongnan Basin in the South China Sea. The work was focused on determination an upper limit of maturity for gas generation (ULMGG) or "the deadline of natural gas generation". Ro values at given temperatures increase with increasing temperature and prolonged heating time, but ΔRo-value, given a definition of the difference of all values for VR related to higher temperature and adjacent lower temperature in open-system non-isothermal experiment at the heating rate of 20 °C/min, is better than VR. And representative examples are presented in this paper. It indicates that the range of natural gas generation for Ro in the main gas generation period is from 0.96% to 2.74%, in which ΔRo is in concordance with the stage for the onset and end of the main gas generation period corresponding to 0.02% up to 0.30% and from 0.30% up to 0.80%, respectively. After the main gas generation period of 0.96-2.74%, the evolution of VR approach to the ULMGG of the whole rock for type II kerogen. It is equal to 4.38% of VR, where the gas generation rates change little with the increase of maturation, ΔRo is the maximum of 0.83% corresponding to VR of 4.38%Ro, and the source rock does not nearly occur in the end process of hydrocarbon gas generation while Ro is over 4.38%. It shows that it is the same the ULMGG from the whole rock for type II kerogen as the method with both comparison and kinetics. By comparing to both the conclusions of pyrolysis experiments and the data of VR from the source rock of Yacheng formation on a series of selected eight wells in the shallow-water continental shelf area, it indicate that the most hydrocarbon source rock is still far from reaching ULMGG from the whole rock for type II kerogen. The source rock of Yacheng formation in the local areas of the deepwater continental slope basin have still preferable natural gas generative potential, especially in the local along the central depression belt (namely the Ledong, Lingshui, Songnan and Baodao sags from southwest to northeast) from the depocenter to both the margin and its adjacent areas. It help to evaluate the resource potential for oil and gas of the hydrocarbon source rock in the deepwater continental slope of the Qiongdongnan Basin or other basins with lower exploration in the northern of the South China Sea and to reduce the risk in exploration.

Composition and sources of atmospheric dusts in snow at 3200 meters in the St. Elias Range, southeastern Alaska, USA

USGS Publications Warehouse

Hinkley, T.K.

1994-01-01

Dusts in snow from the accumulation zone in the St. Elias Range appear from their chemical compositions to have come from terranes of rocks of ferromagnesian composition. These dusts, with respect to their composition and to the moderate degree of variation that occurs through a depositional year, are similar those deposited in Greenland. The high portion of the St. Elias Range is isolated from dominance by any local dust source terranes, because of altitude and the extent of the surrounding glacierized and snow-covered region. In Greenland the altitude is typically lower, but local sources are even less likely to dominate the character of the dusts deposited into the ice record there. The similar compositions and moderate compositional variations of dusts from these two places bear on the question of whether the dusts that are transported over long distances by the atmosphere under modern and glacial-period conditions are uniform and representative of a broad regional or even hemispheric background dust. The dusts in the snow were measured by means of a suite of major, minor, and trace rock-forming metals chosen to give information about rock types, their constituent minerals, degree of degradation (weathering), and energies of atmospheric uptake from source. The variations in amounts of rock dust through the year in the St. Elias Range snowpack have no time-stratigraphic correspondence to the also large variations in concentrations of other species that are not constituents of rock-derived dusts, such the anions chloride, sulfate, and nitrate; the highs and lows of the two types of materials are apparently completely independent. The structure revealed by the moderately fine-scale sampling of the present study (??? 10 increments/y) serves as a background for the interpretation of analysis of ice core samples, in which annual layers may be too compressed to permit analysis of sub-annual samples. ?? 1994.

Composition and sources of atmospheric dusts in snow at 3200 meters in the St. Elias Range, southeastern Alaska, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hinkley, T.K.

1994-08-01

Dusts in snow from the accumulation zone in the St. Elias Range appear from their chemical compositions to have come from terranes of rocks of ferromagnesian composition. These dusts, with respect to their composition and to the moderate degree of variation that occurs through a depositional year, are similar to those deposited in Greenland. The high portion of the St. Elias Range is isolated from dominance by any local dust source terranes, because of altitude and the extent of the surrounding glacierized and snow-covered region. In Greenland the altitude is typically lower, but local sources are even less likely tomore » dominate the character of the dusts deposited into the ice record there. The similar compositions and moderate compositional variations of dusts from these two places bear on the question of whether the dusts that are transported over long distances by the atmosphere under modern and glacial-period conditions are uniform and representative of a broad regional or even hemispheric background dust. The dusts in the snow were measured by means of a suite of major, minor, and track rock-forming metals chosen to give information about rock types, their constituent minerals, degree of degradation (weathering), and energies of atmospheric uptake from source. The variations in amounts of rock dust through the year in the St. Elias Range snowpack have no time-stratigraphic correspondence to the also-large variations in concentrations of other species that are not constituents of rock-derived dusts, such the anions chloride, sulfate, and nitrate; the highs and lows of the two types of materials are apparently completely independent. The structure revealed by the moderately fine-scale sampling of the present study ([approximately]10 increments/y) serves as a background for the interpretation of analysis of ice core samples, in which annual layers may be too compressed to permit analysis of sub-annual samples.« less

Geochronology and geochemistry of late Paleozoic-early Mesozoic igneous rocks of the Erguna Massif, NE China: Implications for the early evolution of the Mongol-Okhotsk tectonic regime

NASA Astrophysics Data System (ADS)

Li, Yu; Xu, Wen-Liang; Wang, Feng; Tang, Jie; Zhao, Shuo; Guo, Peng

2017-08-01

We undertook geochemical and geochronological studies on late Paleozoic-early Mesozoic igneous rocks from the Erguna Massif with the aim of constraining the early evolution of the Mongol-Okhotsk tectonic regime. Zircon crystals from nine representative samples are euhedral-subhedral, display oscillatory growth zoning, and have Th/U values of 0.14-6.48, indicating a magmatic origin. U-Pb dating of zircon using SIMS and LA-ICP-MS indicates that these igneous rocks formed during the Late Devonian (∼365 Ma), late Carboniferous (∼303 Ma), late Permian (∼256 Ma), and Early-Middle Triassic (246-238 Ma). The Late Devonian rhyolites, together with coeval A-type granites, formed in an extensional environment related to the northwestwards subduction of the Heihe-Nenjiang oceanic plate. Their positive εHf(t) values (+8.4 to +14.4) and Hf two-stage model ages (TDM2 = 444-827 Ma) indicate they were derived from a newly accreted continental crustal source. The late Carboniferous granodiorites are geochemically similar to adakites, and their εHf(t) values (+10.4 to +12.3) and Hf two-stage model ages (TDM2 = 500-607 Ma) suggest they were sourced from thickened juvenile lower crustal material, this thickening may be related to the amalgamation of the Erguna-Xing'an and Songnen-Zhangguangcai Range massifs. Rocks of the late Permian to Middle Triassic suite comprise high-K calc-alkaline monzonites, quartz monzonites, granodiorites, and monzogranites. These rocks are relatively enriched in light rare earth elements and large ion lithophile elements, and depleted in heavy rare earth elements and high field strength elements. They were emplaced, together with coeval porphyry-type ore deposits, along an active continental margin where the Mongol-Okhotsk oceanic plate was subducting beneath the Erguna Massif.

Strontium and neodymium isotopic evidence for the heterogeneous nature and development of the mantle beneath Afar (Ethiopia)

NASA Astrophysics Data System (ADS)

Betton, P. J.; Civetta, L.

1984-11-01

Neodymium isotope and REE analyses of recent volcanic rocks and spinel lherzolite nodules from the Afar area are reported. The 143Nd/ 144Nd ratios of the volcanic rocks range from 0.51286 to 0.51304, similar to the range recorded from Iceland. However, the 87Sr/ 86Sr ratios display a distinctly greater range (0.70328-0.70410) than those reported from the primitive rocks of Iceland. Whole rock samples and mineral separates from the spinel lherzolite nodules exhibit uniform 143Nd/ 144Nd ratios (ca. 0.5129) but varied 87Sr/ 86Sr ratios in the range 0.70427-0.70528. The Sr sbnd Nd isotope variations suggest that the volcanic rocks may have been produced by mixing between two reservoirs with distinct isotopic compositions. Two possible magma reservoirs in this area are the source which produced the "MORB-type" volcanics in the Red Sea and Gulf of Aden and the anomalous source represented by the nodule suite. The isotopic composition of the volcanics is compatible with mixing between these two reservoirs. It is shown that the anomalous source with a high 87Sr/ 86Sr ratio cannot have been produced by simple processes of partial melting and mixing within normal mantle. Instead the high 87Sr/ 86Sr is equated with a fluid phase. A primitive cognate fluid, subducted seawater or altered oceanic lithosphere may have been responsible for the generation of the source with a high 87Sr/ 86Sr ratio.

Heterogeneity in small aliquots of Apolllo 15 olivine-normative basalt: Implications for breccia clast studies

NASA Astrophysics Data System (ADS)

Lindstrom, Marilyn M.; Shervais, John W.; Vetter, Scott K.

1993-05-01

Most of the recent advances in lunar petrology are the direct result of breccia pull-apart studies, which have identified a wide array of new highland and mare basalt rock types that occur only as clasts within the breccias. These rocks show that the lunar crust is far more complex than suspected previously, and that processes such as magma mixing and wall-rock assimilation were important in its petrogenesis. These studies are based on the implicit assumption that the breccia clasts, which range in size from a few mm to several cm across, are representative of the parent rock from which they were derived. In many cases, the aliquot allocated for analysis may be only a few grain diameters across. While this problem is most acute for coarse-grained highland rocks, it can also cause considerable uncertainty in the analysis of mare basalt clasts. Similar problems arise with small aliquots of individual hand samples. Our study of sample heterogeneity in 9 samples of Apollo 15 olivine normative basalt (ONB) which exhibit a range in average grain size from coarse to fine are reported. Seven of these samples have not been analyzed previously, one has been analyzed by INAA only, and one has been analyzed by XRF+INAA. Our goal is to assess the effects of small aliquot size on the bulk chemistry of large mare basalt samples, and to extend this assessment to analyses of small breccia clasts.

Heterogeneity in small aliquots of Apolllo 15 olivine-normative basalt: Implications for breccia clast studies

NASA Technical Reports Server (NTRS)

Lindstrom, Marilyn M.; Shervais, John W.; Vetter, Scott K.

1993-01-01

Most of the recent advances in lunar petrology are the direct result of breccia pull-apart studies, which have identified a wide array of new highland and mare basalt rock types that occur only as clasts within the breccias. These rocks show that the lunar crust is far more complex than suspected previously, and that processes such as magma mixing and wall-rock assimilation were important in its petrogenesis. These studies are based on the implicit assumption that the breccia clasts, which range in size from a few mm to several cm across, are representative of the parent rock from which they were derived. In many cases, the aliquot allocated for analysis may be only a few grain diameters across. While this problem is most acute for coarse-grained highland rocks, it can also cause considerable uncertainty in the analysis of mare basalt clasts. Similar problems arise with small aliquots of individual hand samples. Our study of sample heterogeneity in 9 samples of Apollo 15 olivine normative basalt (ONB) which exhibit a range in average grain size from coarse to fine are reported. Seven of these samples have not been analyzed previously, one has been analyzed by INAA only, and one has been analyzed by XRF+INAA. Our goal is to assess the effects of small aliquot size on the bulk chemistry of large mare basalt samples, and to extend this assessment to analyses of small breccia clasts.

Dual origins for pantellerites, and other puzzles, at Mount Takahe volcano, Marie Byrd Land, West Antarctica

NASA Astrophysics Data System (ADS)

LeMasurier, Wesley; Choi, Sung Hi; Kawachi, Yosuke; Mukasa, Sam; Rogers, Nick

2018-01-01

Mt. Takahe is a large, late Quaternary trachyte shield volcano that rises through 2000 + m of the West Antarctic ice sheet. It is composed mostly of ne-trachyte, hy-ol-trachyte, and qz-trachyte flows, with subordinate basanite, intermediate rocks, and pantellerites. All rock types can be adequately modeled by fractional crystallization of basanite - the only basaltic rock exposed here. The ne-trachytes can be explained by a single stage of low-pressure fractionation near the base of the upper crust. Models of oversaturated rocks require a period of evolution at a depth of 35 km, below the stability field of plagioclase, where fractionation of kaersutite and associated high pressure minerals will yield silica oversaturated residual magmas. This is then followed by a period of fractionation at a depth of 3 km, where peralkalinity and Fe-enrichment are acquired. Pantellerite compositions span virtually the entire spectrum of peralkalinity, Fe-enrichment, LILE-enrichment, and SiO2 values, and seem to represent a range of residence times in upper crustal vs., upper mantle magma chambers. Mt. Takahe is unusual among Marie Byrd Land volcanoes for its geochemical anomalies. These include the lowest 143Nd/144Nd ratios in West Antarctica, and unusually high but unpredictable Ba values. These anomalies are believed to originate in a pre-85 Ma subduction mélange at the base of the lithosphere, which seems to be the source of Mt. Takahe basaltic rocks.

Zircon U-Pb, O, and Hf isotopic constraints on Mesozoic magmatism in the Cyclades, Aegean Sea, Greece

NASA Astrophysics Data System (ADS)

Fu, Bin; Bröcker, Michael; Ireland, Trevor; Holden, Peter; Kinsley, Leslie P. J.

2015-01-01

Compared to the well-documented Cenozoic magmatic and metamorphic rocks of the Cyclades, Aegean Sea, Greece, the geodynamic context of older meta-igneous rocks occurring in the marble-schist sequences and mélanges of the Cycladic Blueschist Unit is as yet not fully understood. Here, we report O-Hf isotopic compositions of zircons ranging in age from ca. 320 Ma to ca. 80 Ma from metamorphic rocks exposed on the islands of Andros, Ios, Sifnos, and Syros with special emphasis on Triassic source rocks. Ion microprobe (SHRIMP II) single spot oxygen isotope analysis of pre-Cretaceous zircons from various felsic gneisses and meta-gabbros representing both the marble-schist sequences and the mélanges of the study area yielded a large range in δ18O values, varying from 2.7 ‰ to 10.1 ‰ VSMOW, with one outlier at -0.4 %. Initial ɛHf values (-12.5 to +15.7) suggest diverse sources for melts formed between Late Carboniferous to Late Cretaceous time that record derivation from mantle and reworked older continental crust. In particular, variable δ18O and ɛHf( t) values for Triassic igneous zircons suggest that magmatism of this age is more likely rift- than subduction-related. The significant crustal component in 160 Ma meta-gabbros from Andros implies that some Jurassic gabbroic rocks of the Hellenides are not part of SSZ-type (supra-subduction zone) ophiolites that are common elsewhere along the margin of the Pelagonian zone.

Quantitative Relationships Linking Rock Strength to Channel Morphology: A Case Study in Central Arizona

NASA Astrophysics Data System (ADS)

Larimer, J. E.; Yanites, B.

2016-12-01

River morphology is a consequence of the erosive forces acting on the channel boundary and the resisting forces that limit erosion. For bedrock rivers, the erosive forces are generated by the stresses exerted by impacting sediment and flowing water, while the resisting forces are controlled by the internal strength regime of the local rock. We investigate the susceptibility of different rock types to different erosional processes (i.e. abrasion and plucking) and how changes in channel morphology reflect rock strength properties across lithologic boundaries. The bedrock rivers in the Prescott National Forest, AZ flow over a number of rock types with variable strength including sedimentary, igneous, and metamorphic lithologies providing a natural experiment to quantify the influence of rock strength on channel morphology. We collected bedrock samples and channel surveys from 12 different rock types. Rock-strength and rock-mass properties include compressive strength, tensile strength, fatigue strength, decimeter scale P-wave velocity (varies by 8-fold), Schmidt rebound value, fracture spacing, fracture aperture, and slake durability (as a proxy for weathering susceptibility. Morphological measurements include channel width, channel steepness (varies by 10-fold), and grain size distribution. To distinguish between the major mechanisms of erosion we measure bedrock surface roughness factor at the centimeter scale. Preliminary results show that channel steepness (ksn) increases with P-wave velocity while normalized channel width (kwn) decreases with P-wave velocity. We use these data to quantify scaling relationships of channel geometry with rock strength properties. We consider the results in the context of the driving mechanistic process to develop new quantitative understandings of how rock strength properties influence the efficiency of erosion processes and how rock strength is reflected in river morphology. By comparing the results among different rock types in a landscape subject to spatially consistent tectonic and climatic influence, our work seeks to advance process-based river erosion models through field and laboratory measurements.

Igneous activity, metamorphism, and deformation in the Mount Rogers area of SW Virginia and NW North Carolina: A geologic record of Precambrian tectonic evolution of the southern Blue Ridge Province

USGS Publications Warehouse

Tollo, Richard P.; Aleinikoff, John N.; Mundil, Roland; Southworth, C. Scott; Cosca, Michael A.; Rankin, Douglas W.; Rubin, Allison E.; Kentner, Adrienne; Parendo, Christopher A.; Ray, Molly S.

2012-01-01

Mesoproterozoic basement in the vicinity of Mount Rogers is characterized by considerable lithologic variability, including major map units composed of gneiss, amphibolite, migmatite, meta-quartz monzodiorite and various types of granitoid. SHRIMP U-Pb geochronology and field mapping indicate that basement units define four types of occurrences, including (1) xenoliths of ca. 1.33 to ≥1.18 Ga age, (2) an early magmatic suite including meta-granitoids of ca. 1185–1140 Ma age that enclose or locally intrude the xenoliths, (3) metasedimentary rocks represented by layered granofels and biotite schist whose protoliths were likely deposited on the older meta-granitoids, and (4) a late magmatic suite composed of younger, ca. 1075–1030 Ma intrusive rocks of variable chemical composition that intruded the older rocks. The magmatic protolith of granofels constituting part of a layered, map-scale xenolith crystallized at ca. 1327 Ma, indicating that the lithology represents the oldest, intact crust presently recognized in the southern Appalachians. SHRIMP U-Pb data indicate that periods of regional Mesoproterozoic metamorphism occurred at 1170–1140 and 1070–1020 Ma. The near synchroneity in timing of regional metamorphism and magmatism suggests that magmas were emplaced into crust that was likely at near-solidus temperatures and that melts might have contributed to the regional heat budget. Much of the area is cut by numerous, generally east- to northeast-striking Paleozoic fault zones characterized by variable degrees of ductile deformation and recrystallization. These high-strain fault zones dismember the terrane, resulting in juxtaposition of units and transformation of basement lithologies to quartz- and mica-rich tectonites with protomylonitic and mylonitic textures. Mineral assemblages developed within such zones indicate that deformation and recrystallization likely occurred at greenschist-facies conditions at ca. 340 Ma.

Classification and Distribution of Mars Pathfinder Rocks Using Quantitative Morphologic Indices

NASA Technical Reports Server (NTRS)

Yingst, R. A.; Biederman, K. L.; Monhead, A. M.; Haldemann, A. F. C.; Kowalczyk, M. R.

2004-01-01

The Mars Pathfinder (MPF) landing site was predicted to contain a broad sampling of rock types varying in mineralogical, physical, mechanical and geochemical characteristics. Although rocks have been divided into several spectral categories based on Imager for Mars Pathfinder visible/near-infrared spectra, it has not been fully determined which of these stem from intrinsic mineralogical differences between rocks or rock surfaces, and which result from factors such as physical or chemical weathering. This has made isolation of unique mineralogy's difficult. Efforts in isolating and classifying spectral units among MPF rocks and soils have met with varying degrees of success, and the current understanding is such that many factors influencing spectral signatures cannot be quantified to a sufficient level so they may be removed. The result is that fundamental questions regarding information needed to reveal the present and past interactions between the rocks and rock surfaces and the Martian environment remain unanswered. But it is possible to approach the issue of identifying distinct rock and rock surface types from a different angle.

Zygomycetes in Vesicular Basanites from Vesteris Seamount, Greenland Basin – A New Type of Cryptoendolithic Fungi

PubMed Central

Ivarsson, Magnus; Peckmann, Jörn; Tehler, Anders; Broman, Curt; Bach, Wolfgang; Behrens, Katharina; Reitner, Joachim; Böttcher, Michael E.; Norbäck Ivarsson, Lena

2015-01-01

Fungi have been recognized as a frequent colonizer of subseafloor basalt but a substantial understanding of their abundance, diversity and ecological role in this environment is still lacking. Here we report fossilized cryptoendolithic fungal communities represented by mainly Zygomycetes and minor Ascomycetes in vesicles of dredged volcanic rocks (basanites) from the Vesteris Seamount in the Greenland Basin. Zygomycetes had not been reported from subseafloor basalt previously. Different stages in zygospore formation are documented in the studied samples, representing a reproduction cycle. Spore structures of both Zygomycetes and Ascomycetes are mineralized by romanechite-like Mn oxide phases, indicating an involvement in Mn(II) oxidation to form Mn(III,VI) oxides. Zygospores still exhibit a core of carbonaceous matter due to their resistance to degradation. The fungi are closely associated with fossiliferous marine sediments that have been introduced into the vesicles. At the contact to sediment infillings, fungi produced haustoria that penetrated and scavenged on the remains of fragmented marine organisms. It is most likely that such marine debris is the main carbon source for fungi in shallow volcanic rocks, which favored the establishment of vital colonies. PMID:26181773

Diagenesis and evolution of microporosity of Middle-Upper Devonian Kee Scarp reefs, Norman Wells, Northwest Territories, Canada: Petrographic and chemical evidence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al-Aasm, I.S.; Azmy, K.K.

The Middle-Upper Devonian Kee Scarp reef complexes of Norman Wells, Northwest Territories, Canada, are oil-producing, stromatoporoid-dominated carbonates. Episodic increases in the rate of sea level rise produced multiple cycles of reef growth that exhibit backstepping characteristics. These carbonates, composed of invariably altered limestones, have original interskeletal, intraskeletal, and intergranular porosity, mostly occluded by nonferroan, dull luminescent cements. Secondary porosity, represented by micropores of various types, developed during diagenesis by aggrading neomorphism and dissolution. The micropores represent the main reservoir porosity in the Kee Scarp limestone. Petrographic, chemical, and isotopic studies of Kee Scarp reef components reveal a complex diagenetic historymore » involving marine fluids modified by increasing water/rock interaction and burial. Neomorphic stabilization of skeletal components caused further depletion in {gamma}{sup 18}O but very little change in {gamma}{sup 13}C, an argument for modification of the original marine fluids with increasing burial. Variations in magnitude of water/rock interaction with depth, facies changes, and porosity modifications probably exerted some control on fractionation and distribution of stable isotopes and trace elements in reef components.« less

Effect of Hydrothermal Alteration on Rock Properties in Active Geothermal Setting

NASA Astrophysics Data System (ADS)

Mikisek, P.; Bignall, G.; Sepulveda, F.; Sass, I.

2012-04-01

Hydrothermal alteration records the physical-chemical changes of rock and mineral phases caused by the interaction of hot fluids and wall rock, which can impact effective permeability, porosity, thermal parameters, rock strength and other rock properties. In this project, an experimental approach has been used to investigate the effects of hydrothermal alteration on rock properties. A rock property database of contrastingly altered rock types and intensities has been established. The database details horizontal and vertical permeability, porosity, density, thermal conductivity and thermal heat capacity for ~300 drill core samples from wells THM12, THM13, THM14, THM17, THM18, THM22 and TH18 in the Wairakei-Tauhara geothermal system (New Zealand), which has been compared with observed hydrothermal alteration type, rank and intensity obtained from XRD analysis and optical microscopy. Samples were selected from clay-altered tuff and intercalated siltstones of the Huka Falls Formation, which acts as a cap rock at Wairakei-Tauhara, and tuffaceous sandstones of the Waiora Formation, which is a primary reservoir-hosting unit for lateral and vertical fluid flows in the geothermal system. The Huka Falls Formation exhibits argillic-type alteration of varying intensity, while underlying Waiora Formations exhibits argillic- and propylithic-type alteration. We plan to use a tempered triaxial test cell at hydrothermal temperatures (up to 200°C) and pressures typical of geothermal conditions, to simulate hot (thermal) fluid percolation through the rock matrix of an inferred "reservoir". Compressibility data will be obtained under a range of operating (simulation reservoir) conditions, in a series of multiple week to month-long experiments that will monitor change in permeability and rock strength accompanying advancing hydrothermal alteration intensity caused by the hot brine interacting with the rock matrix. We suggest, our work will provide new baseline information concerning fluid-rock interaction processes in geothermal reservoirs, and their effects on rock properties, that will aid improved understanding of the evolution of high-temperature geothermal systems, provide constraints to parameterization of reservoir models and assist future well planning and design through prediction of rock properties in the context of drilling strategies.

Microbial life associated with low-temperature alteration of ultramafic rocks in the Leka ophiolite complex.

PubMed

Daae, F L; Økland, I; Dahle, H; Jørgensen, S L; Thorseth, I H; Pedersen, R B

2013-07-01

Water-rock interactions in ultramafic lithosphere generate reduced chemical species such as hydrogen that can fuel subsurface microbial communities. Sampling of this environment is expensive and technically demanding. However, highly accessible, uplifted oceanic lithospheres emplaced onto continental margins (ophiolites) are potential model systems for studies of the subsurface biosphere in ultramafic rocks. Here, we describe a microbiological investigation of partially serpentinized dunite from the Leka ophiolite (Norway). We analysed samples of mineral coatings on subsurface fracture surfaces from different depths (10-160 cm) and groundwater from a 50-m-deep borehole that penetrates several major fracture zones in the rock. The samples are suggested to represent subsurface habitats ranging from highly anaerobic to aerobic conditions. Water from a surface pond was analysed for comparison. To explore the microbial diversity and to make assessments about potential metabolisms, the samples were analysed by microscopy, construction of small subunit ribosomal RNA gene clone libraries, culturing and quantitative-PCR. Different microbial communities were observed in the groundwater, the fracture-coating material and the surface water, indicating that distinct microbial ecosystems exist in the rock. Close relatives of hydrogen-oxidizing Hydrogenophaga dominated (30% of the bacterial clones) in the oxic groundwater, indicating that microbial communities in ultramafic rocks at Leka could partially be driven by H2 produced by low-temperature water-rock reactions. Heterotrophic organisms, including close relatives of hydrocarbon degraders possibly feeding on products from Fischer-Tropsch-type reactions, dominated in the fracture-coating material. Putative hydrogen-, ammonia-, manganese- and iron-oxidizers were also detected in fracture coatings and the groundwater. The microbial communities reflect the existence of different subsurface redox conditions generated by differences in fracture size and distribution, and mixing of fluids. The particularly dense microbial communities in the shallow fracture coatings seem to be fuelled by both photosynthesis and oxidation of reduced chemical species produced by water-rock reactions. © 2013 John Wiley & Sons Ltd.

Effects of Climate on Co-evolution of Weathering Profiles and Hillscapes

NASA Astrophysics Data System (ADS)

Anderson, R. S.; Rajaram, H.; Anderson, S. P.

2017-12-01

Considerable debate revolves around the relative importance of rock type, tectonics, and climate in creating the architecture of the critical zone. It has recently been proposed that differences in the depths and patterns of weathering between landscapes in Colorado's Front Range and South Carolina's piedmont can be attributed to the state of stress in the rock imposed by the magnitude and orientation the regional stresses with respect to the ridgelines (St. Claire et al., 2016). We argue for the importance of the climate, and in particular, in temperate regions, the amount of recharge. We employ numerical models of hillslope evolution between bounding erosional channels, in which the degree of rock weathering governs the rate of transformation of rock to soil. As the water table drapes between the stream channels, fresh rock is brought into the weathering zone at a rate governed by the rate of incision of the channels. We track the chemical weathering of rock, represented by alteration of feldspar to clays, which in turn requires calculation of the concentration of reactive species in the water along hydrologic flow paths. We present results from analytic solutions to the flow field in which travel times can be efficiently assessed. Below the water table, flow paths are hyperbolic, taking on considerable lateral components as they veer toward the bounding channels that serve as drains to the hillslope. We find that if water is far from equilibrium with respect to weatherable minerals at the water table, as occurs in wet, slowly-eroding landscapes, deep weathering can occur well below the water table to levels approximating the base of the bounding channels. In dry climates, on the other hand, the weathering zone is limited to a shallow surface - parallel layer. These models capture the essence of the observed differences in depth to fresh rock in both wet and dry climates without appeal to the state of stress in the rock.

HPC simulations of grain-scale spallation to improve thermal spallation drilling

NASA Astrophysics Data System (ADS)

Walsh, S. D.; Lomov, I.; Wideman, T. W.; Potter, J.

2012-12-01

Thermal spallation drilling and related hard-rock hole opening techniques are transformative technologies with the potential to dramatically reduce the costs associated with EGS well drilling and improve the productivity of new and existing wells. In contrast to conventional drilling methods that employ mechanical means to penetrate rock, thermal spallation methods fragment rock into small pieces ("spalls") without contact via the rapid transmission of heat to the rock surface. State-of-the-art constitutive models of thermal spallation employ Weibull statistical failure theory to represent the relationship between rock heterogeneity and its propensity to produce spalls when heat is applied to the rock surface. These models have been successfully used to predict such factors as penetration rate, spall-size distribution and borehole radius from drilling jet velocity and applied heat flux. A properly calibrated Weibull model would permit design optimization of thermal spallation drilling under geothermal field conditions. However, although useful for predicting system response in a given context, Weibull models are by their nature empirically derived. In the past, the parameters used in these models were carefully determined from laboratory tests, and thus model applicability was limited by experimental scope. This becomes problematic, for example, if simulating spall production at depths relevant for geothermal energy production, or modeling thermal spallation drilling in new rock types. Nevertheless, with sufficient computational resources, Weibull models could be validated in the absence of experimental data by explicit small-scale simulations that fully resolve rock grains. This presentation will discuss how high-fidelity simulations can be used to inform Weibull models of thermal spallation, and what these simulations reveal about the processes driving spallation at the grain-scale - in particular, the role that inter-grain boundaries and micro-pores play in the onset and extent of spallation. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Mercury contamination in agricultural soils from abandoned metal mines classified by geology and mineralization.

PubMed

Kim, Han Sik; Jung, Myung Chae

2012-01-01

This survey aimed to compare mercury concentrations in soils related to geology and mineralization types of mines. A total of 16,386 surface soils (0~15 cm in depth) were taken from agricultural lands near 343 abandoned mines (within 2 km from each mine) and analyzed for Hg by AAS with a hydride-generation device. To meaningfully compare mercury levels in soils with geology and mineralization types, three subclassification criteria were adapted: (1) five mineralization types, (2) four valuable ore mineral types, and (3) four parent rock types. The average concentration of Hg in all soils was 0.204 mg kg(-1) with a range of 0.002-24.07 mg kg(-1). Based on the mineralization types, average Hg concentrations (mg kg(-1)) in the soils decreased in the order of pegmatite (0.250) > hydrothermal vein (0.208) > hydrothermal replacement (0.166) > skarn (0.121) > sedimentary deposits (0.045). In terms of the valuable ore mineral types, the concentrations decreased in the order of Au-Ag-base metal mines ≈ base metal mines > Au-Ag mines > Sn-W-Mo-Fe-Mn mines. For parent rock types, similar concentrations were found in the soils derived from sedimentary rocks and metamorphic rocks followed by heterogeneous rocks with igneous and metamorphic processes. Furthermore, farmland soils contained relatively higher Hg levels than paddy soils. Therefore, it can be concluded that soils in Au, Ag, and base metal mines derived from a hydrothermal vein type of metamorphic rocks and pegmatite deposits contained relatively higher concentrations of mercury in the surface environment.

The doctor-patient relationship in rock and roll music.

PubMed

Lazarus, Arthur

2006-01-01

An analysis of rock songs in which physicians are central characters, combined with archival events and commentary from the singers and songwriters, sheds light on doctor-patient relationships as seen through popular culture. Rock and roll music attributes special psychological significance to physicians. Musicians project their personal problems through love songs and songs that deal with sex, drugs, and death. In rock songs, physicians frequently represent a cure for lovesickness. Rock musicians often die prematurely from self-inflicted behaviors, reaffirming the connection between their music and the medical profession.

Microstructural controls on the macroscopic behavior of geo-architected rock samples

NASA Astrophysics Data System (ADS)

Mitchell, C. A.; Pyrak-Nolte, L. J.

2017-12-01

Reservoir caprocks, are known to span a range of mechanical behavior from elastic granitic units to visco-elastic shale units. Whether a rock will behave elastically, visco-elastically or plastically depends on both the compositional and textural or microsctructural components of the rock, and how these components are spatially distributed. In this study, geo-architected caprock fabrication was performed to develop synthetic rock to study the role of rock rheology on fracture deformations, fluid flow and geochemical alterations. Samples were geo-architected with Portland Type II cement, Ottawa sand, and different clays (kaolinite, illite, and Montmorillonite). The relative percentages of these mineral components are manipulated to generate different rock types. With set protocols, the mineralogical content, texture, and certain structural aspects of the rock were controlled. These protocols ensure that identical samples with the same morphological and mechanical characteristics are constructed, thus overcoming issues that may arise in the presence of heterogeneity and high anisotropy from natural rock samples. Several types of homogeneous geo-architected rock samples were created, and in some cases the methods were varied to manipulate the physical parameters of the rocks. Characterization of rocks that the samples exhibit good repeatability. Rocks with the same mineralogical content generally yielded similar compressional and shear wave velocities, UCS and densities. Geo-architected rocks with 10% clay in the matrix had lower moisture content and effective porosities than rocks with no clay. The process by which clay is added to the matrix can strongly affect the resulting compressive strength and physical properties of the geo-architected sample. Acknowledgment: This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Geosciences Research Program under Award Number (DE-FG02-09ER16022).

Enrichments of the mantle sources beneath the Southern Volcanic Zone (Andes) by fluids and melts derived from abraded upper continental crust

NASA Astrophysics Data System (ADS)

Holm, Paul Martin; Søager, Nina; Dyhr, Charlotte Thorup; Nielsen, Mia Rohde

2014-05-01

Mafic basaltic-andesitic volcanic rocks from the Andean Southern Volcanic Zone (SVZ) exhibit a northward increase in crustal components in primitive arc magmas from the Central through the Transitional and Northern SVZ segments. New elemental and Sr-Nd-high-precision Pb isotope data from the Quaternary arc volcanic centres of Maipo (NSVZ) and Infernillo and Laguna del Maule (TSVZ) are argued to reflect mainly their mantle source and its melting. For the C-T-NSVZ, we identify two types of source enrichment: one, represented by Antuco in CSVZ, but also present northward along the arc, was dominated by fluids which enriched a pre-metasomatic South Atlantic depleted MORB mantle type asthenosphere. The second enrichment was by melts having the characteristics of upper continental crust (UCC), distinctly different from Chile trench sediments. We suggest that granitic rocks entered the source mantle by means of subduction erosion in response to the northward increasingly strong coupling of the converging plates. Both types of enrichment had the same Pb isotope composition in the TSVZ with no significant component derived from the subducting oceanic crust. Pb-Sr-Nd isotopes indicate a major crustal compositional change at the southern end of the NSVZ. Modelling suggests addition of around 2 % UCC for Infernillo and 5 % for Maipo.

The ammonium content in the Malayer igneous and metamorphic rocks (Sanandaj-Sirjan Zone, Western Iran)

NASA Astrophysics Data System (ADS)

Ahadnejad, Vahid; Hirt, Ann Marie; Valizadeh, Mohammad-Vali; Bokani, Saeed Jabbari

2011-04-01

The ammonium (NH4+) contents of the Malayer area (Western Iran) have been determined by using the colorimetric method on 26 samples from igneous and metamorphic rocks. This is the first analysis of the ammonium contents of Iranian metamorphic and igneous rocks. The average ammonium content of metamorphic rocks decreases from low-grade to high-grade metamorphic rocks (in ppm): slate 580, phyllite 515, andalusite schist 242. In the case of igneous rocks, it decreases from felsic to mafic igneous types (in ppm): granites 39, monzonite 20, diorite 17, gabbro 10. Altered granitic rocks show enrichment in NH4+ (mean 61 ppm). The high concentration of ammonium in Malayer granites may indicate metasedimentary rocks as protoliths rather than meta-igneous rocks. These granitic rocks (S-types) have high K-bearing rock-forming minerals such as biotite, muscovite and K-feldspar which their potassium could substitute with ammonium. In addition, the high ammonium content of metasediments is probably due to inheritance of nitrogen from organic matter in the original sediments. The hydrothermally altered samples of granitic rocks show highly enrichment of ammonium suggesting external sources which intruded additional content by either interaction with metasedimentary country rocks or meteoritic solutions.

Applicability of ERTS-1 to Montana geology

NASA Technical Reports Server (NTRS)

Weidman, R. M. (Principal Investigator)

1973-01-01

The author has identified the following significant results. Geologic maps of four test sites were compiled at 1/250,000. Band 7 prints enlarged to 1/500,000 scale are the best for the purpose, and negative prints provide a valuable supplement. More than 100 mapped lineaments represent most of the major faults of the area and a large number of suspected faults, including many of northeast trend. Under ideal conditions dip slopes may be recognized, laccoliths outlined, and axial traces drawn for narrow, plunging folds. Use of ERTS-1 imagery will greatly facilitate construction of a needed tectonic map of Montana. From ERTS-1 imagery alone, it was possible to identify up-turned undivided Paleozoic and Mesozoic strata and to map the boundaries of mountain glaciation, intermontane basins, a volcanic field, and an area of granitic rocks. It was also possible to outline clay pans associated with bentonite. However, widespread recognition of gross rock types will be difficult.

Preliminary petrographic description and geologic implications of the Apollo 17 Station 7 boulder consortium samples

USGS Publications Warehouse

Chao, E.C.T.; Minkin, J.A.; Thompson, C.L.

1974-01-01

Preliminary petrographic description and mineral composition of four hand samples (77135, 77115, 77075 and 77215) are presented. 77135, 77115, and 77075 all crystallized from fragment-laden melts; they are similar in textures but differ in grain size. 77135 and 77115 are pigeonite feldspathic basalts. On the basis of geologic and petrographic evidence, 77115 and 77075 are related; they formed, cooled, and consolidated before being engulfed in the vesicular 77135. The impact or igneous origin of the melts from which these rocks crystallized cannot be determined. 77215 is a shocked, strongly sheared and granulated microbreccia consisting of three major lithologies dominated by mineral clasts of orthopyroxene and calcic plagioclase. The orthopyroxene clasts contain coarse exsolved blebs of augite, suggesting a deep-seated origin. The major, minor, and trace element compositions of 77135, 77115, and 77075 are in general similar. They represent a major highland rock type, perhaps more important than anorthosites. ?? 1974.

Soap-stone in architecture of North European cities. A nomination as a candidate for a Global Heritage Stones Resource

NASA Astrophysics Data System (ADS)

Bulakh, Andrey

2016-04-01

Soap stone represents soft Proterozoic rock type from the deposit Nunnalahti situated on the western shore of the big Lake Pielinen in Eastern Finland. It consists of talc (40 - 50 %), magnesite MgCO3 (40 - 50 %), chlorite (5 - 8 %), dolomite, calcite, etc. The colour of the stone is very spectacular and varies from yellow and brownish-yellow to grey, greenish grey. The soft stone is a highly workable material for a sculptor's chisel. It was one of the most popular ornamental rocks used architecture of the Modern style in St Petersburg, Helsinki, Turku, Tampere and other North European cities lately in the XIX-th centuries. Examples are given and discussed. References: Bulakh, A.G., Abakumova, N.B., and Romanovsky, J.V. St Petersburg: a History in Stone. 2010. Print House of St Petersburg State University. 173 p. (In English).

New technologies of mining stratal minerals and their computation

NASA Astrophysics Data System (ADS)

Beysembayev, K. M.; Reshetnikova, O. S.; Nokina, Z. N.; Teliman, I. V.; Asmagambet, D. K.

2018-03-01

The paper considers the systems of flat and volumetric modeling of controlling long-wall faces for schemes with rock collapse of the immediate and main roof and smooth lowering of the remaining layers, as well as in forming a vault over the face. Stress distributions are obtained for the reference pressure zone. They are needed for recognizing the active state of the long-wall face in the feedback mode. The project of the system “support - lateral rocks” is represented by a multidimensional network base. Its connections reflect the elements of the system or rocks, workings, supports with nodes and parts. The connections reflect the logic of the operation of machines, assemblies and parts, and the types of their mechanical connections. At the nodes of the base, there are built-in systems of object-oriented programming languages. This allows combining spatial elements of the system into a simple neural network.

Clastic sedimentary rocks of the Michipicoten Volcanic-sedimentary belt, Wawa, Ontario

NASA Technical Reports Server (NTRS)

Ojakangas, R. W.

1983-01-01

The Wawa area, part of the Michipicoten greenstone belt, contains rock assemblages representative of volcanic sedimentary accumulations elsewhere on the shield. Three mafic to felsic metavolcanic sequences and cogenetic granitic rocks range in age from 2749 + or - 2Ma to 2696 + or - 2Ma. Metasedimentary rocks occur between the metavolcanic sequences. The total thickness of the supracrustal rocks may be 10,000 m. Most rocks have been metamorphosed under greenschist conditions. The belt has been studied earlier and is currently being remapped by Sage. The sedimentrologic work has been briefly summarized; two mainfacies associations of clastic sedimentary rocks are present - a Resedimented (Turbidite) Facies Association and a Nonmarine (Alluvial Fan Fluvial) Facies Association.

Tales from the tomb: the microbial ecology of exposed rock surfaces.

PubMed

Brewer, Tess E; Fierer, Noah

2018-03-01

Although a broad diversity of eukaryotic and bacterial taxa reside on rock surfaces where they can influence the weathering of rocks and minerals, these communities and their contributions to mineral weathering remain poorly resolved. To build a more comprehensive understanding of the diversity, ecology and potential functional attributes of microbial communities living on rock, we sampled 149 tombstones across three continents and analysed their bacterial and eukaryotic communities via marker gene and shotgun metagenomic sequencing. We found that geographic location and climate were important factors structuring the composition of these communities. Moreover, the tombstone-associated microbial communities varied as a function of rock type, with granite and limestone tombstones from the same cemeteries harbouring taxonomically distinct microbial communities. The granite and limestone-associated communities also had distinct functional attributes, with granite-associated bacteria having more genes linked to acid tolerance and chemotaxis, while bacteria on limestone were more likely to be lichen associated and have genes involved in photosynthesis and radiation resistance. Together these results indicate that rock-dwelling microbes exhibit adaptations to survive the stresses of the rock surface, differ based on location, climate and rock type, and seem pre-disposed to different ecological strategies (symbiotic versus free-living lifestyles) depending on the rock type. © 2017 Society for Applied Microbiology and John Wiley & Sons Ltd.

Petrogenesis of the western highlands of the moon - Evidence from a diverse group of whitlockite-rich rocks from the Fra Mauro formation

NASA Technical Reports Server (NTRS)

Snyder, Gregory A.; Taylor, Lawrence A.; Liu, Yun-Gang; Schmitt, Roman A.

1992-01-01

A group of KREEPy basalts has been discovered in Apollo 14 soils. These samples exhibit similarities to both HA and VHK basalts, albeit with much higher REE abundances, and contain up to 2 vol pct whitlockite and can be explained by assimilation of a K-, REE- and P-rich fluids by an original HA or VHK basalt. This KREEP component could have been produced late in the evolution of the lunar magma ocean and is similar in composition to QMD at Apollo 14. Two rocks have trace element compositions that are representative of actual KREEP. One of the samples appears to be petrographically pristine and could represent an actual KREEP basalt rock. Five subophitic high-Al basalts represent sampling of either a slowly cooled impact melt sheet or, more likely, the same basalt flow. Two 'quasi-pristine' highland rocks confirm the postulate of a connection between KREEP and the alkali suite. A newly discovered alkali anorthosite is a plagioclase cumulate with about 15 percent trapped KREEPy liquid.

The Tuscarora Au-Ag district: Eocene volcanic-hosted epithermal deposits in the Carlin gold region, Nevada

USGS Publications Warehouse

Castor, S.B.; Boden, D.R.; Henry, C.D.; Cline, J.S.; Hofstra, A.H.; McIntosh, W.C.; Tosdal, R.M.; Wooden, J.P.

2003-01-01

The Tuscarora mining district contains the oldest and the only productive Eocene epithermal deposits in Nevada. The district is a particularly clear example of association of low-sulfidation deposits with igneous activity and structure, and it is unusual in that it consists of two adjoining but physically and chemically distinct types of low-sulfidation deposits. Moreover, Tuscarora deposits are of interest because they formed contemporaneously with nearby, giant Carlin-type gold deposits. The Tuscarora deposits formed within the 39.9 to 39.3 Ma Tuscarora volcanic field, along and just outside the southeastern margin of the caldera-like Mount Blitzen volcanic center. Both deposit types formed at 39.3 Ma, contemporaneous with the only major intrusive activity in the volcanic field. No deposits are known to have formed during any of the intense volcanic phases of the field. Intrusions were the apparent heat source, and structures related to the Mount Blitzen center were conduits for hydrothermal circulation. The ore-forming fluids interacted dominantly with Eocene igneous rocks. The two deposit types occur in a northern silver-rich zone that is characterized by relatively high Ag/Au ratios (110-150), narrow alteration zones, and quartz and carbonate veins developed mostly in intrusive dacite, and in a southern gold-rich zone that is typified by relatively low Ag/Au ratios (4-14), more widespread alteration, and quartz-fissure and stockwork veins commonly developed in tuffaceous sedimentary rocks. The deposit types have similar fluid inclusion and Pb and S isotope characteristics but different geochemical signatures. Quartz veins from both zones have similar thermal and paragenetic histories and contain fluid inclusions that indicate that fluids cooled from between 260?? and 230??C to less than 200??C. Fluid boiling may have contributed to precious-metal deposition. Veins in both zones have relatively high As and Sb and low Bi, Te, and W. The silver zone has high Ca, Pb, Mn, Zn, Cd, Tl, and Se. The gold zone has high Hg and Mo. A few samples from an area of overlap between the two zones share chemical characteristics of both deposit types. The deposit types could represent a single zoned or evolving system in which hydrothermal fluids rose along structures within the silver zone, preferentially deposited Ag and base metals, and then spread into the gold zone. Alternatively, the deposit types could represent two distinct but temporally indistinguishable hydrothermal cells that only narrowly overlapped spatially. As noted in previous studies, the hydrothermal fluids that generated the Tuscarora and other epithermal deposits could have evolved from Carlin-type fluids by boiling and mixing with meteoric water. If so, the Tuscarora deposit may represent epithermal conditions above Carlin-type deposits, and Carlin-type deposits may lie beneath the district.

Geo-structural modelling for potential large rock slide in Machu Picchu

NASA Astrophysics Data System (ADS)

Spizzichino, D.; Delmonaco, G.; Margottini, C.; Mazzoli, S.

2009-04-01

The monumental complex of the Historical Sanctuary of Machu Picchu, declared as World Heritage Site by UNESCO in 1983, is located in the Andean chain at approx. 80 km from Cuzco (Peru) and at an elevation of 2430 m a.s.l. along the Urubamba River Valley. From a geological point of view, the Machu Picchu granitoid pluton, forming part of the larger "Quillabamba granite", is one of a series of plutons intruded along the axial zone of the high Eastern Cordillera Permo-Liassic rift system including a variety of rock types, dominantly granites and granodiorites. The most evident structures at the outcrop scale consist of planar joint sets that may be variably reactivated and exhibiting 4 main orientations. At present, the site is affected by geological risk due to frequent landslides that threaten security and tourist exploitation. In the last years, the international landslide scientific community has promoted a multi-discipline joint programme mainly finalised to slope deformation monitoring and analysis after the warning, launched in 2001, of a potential collapse of the citadel, caused by a huge rock slide. The contribute of the Italian research team was devoted to implement a landslide risk analysis and an innovative remote sensing techniques. The main scope of this work is to present the implementation of a geo-structural modelling aimed at defining present and potential slope stability conditions of the Machu Picchu Citadel. Data have been collected by geological, structural and geomechanical field surveys and laboratory tests in order to reconstruct the geomorphological evolution of the area. Landslide types and evolution are strictly controlled by regional tectonic uplift and structural setting. Several slope instability phenomena have been identified and classified according to mechanism, material involved and state of activity. Rock falls, debris flows, rock slides and debris slides are the main surveyed landslide types. Rock slides and rock falls may produce blocks with dimensions variable from 10-1 to 102m3 that form the toe accumulation on steeper slopes. The area of the citadel has also been interpreted as affected by a deep mass movement (>100m) that, if confirmed by the present day monitoring systems, could be referred to a deep-seated gravitational slope deformation (DSGSD), probably of the type of the compound bi-planar sagging (CB) described by Hutchinson (1988). The analysis of active strain processes (e.g. tension cracks) along with the damage pattern surveyed on archaeological structures (e.g. sinking, swelling, tilting) suggest that the potential failure of a large rock slide may be located at a depth of ca. 30m. The various data sets have been integrated in order to obtain a general geo-structural and geotechnical model (strength and deformation parameters, seismic input) of the citadel at the slope scale. This represents a first step in implementing a slope stability analysis capable of reconstructing present and potential landslide evolution under static and dynamic conditions. This multi-discipline study, based on geological and structural analysis integrated with geotechnical and geomechanical interpretation, will aid defining actual landslide hazard and risk levels, indispensable for the design of low impact mitigation measures to be applied at Machu Picchu Citadel.

How do subcritical cracking rates and styles influence rock erosion? A test case from the Blue Ridge Mountains of Virginia.

NASA Astrophysics Data System (ADS)

Eppes, M. C.; Hancock, G. S.; Dewers, T. A.; Chen, X.; Eichhubl, P.

2017-12-01

There is a disconnect between measured rates of rock erosion and regolith production and our understanding of the factors and processes that drive them. Here we examine the mechanical weathering (cracking) characteristics of natural, bare bedrock outcrops characterized by 10Be derived erosion rates that vary from 2 to 40 m/my in the Blue Ridge Mountains, VA. Observed erosion rate variance generally correlates with rock type; we seek to characterize and quantify to what extent the mechanical weathering properties of the different rock types drive erosion rates. We assert that subcritical cracking constitutes the primary mechanism by which the outcrops increase their porosity and subsequently weather and erode. We therefore hypothesize that rock parameters that control rates and styles of subcritical cracking set the outcrop erosion rates. For each outcrop, we measured crack characteristics along transects: for every crack >2 cm length, we measured its length, width, orientation, and weathering characteristics (rounded vs sharp edges); and we measured the thickness of all `steps' (spallation remnants) encountered in the transects. For most outcrops, we collected surface samples in order to characterize their mineralogy and microcracking characteristics through thin section analysis. For each rock type, we collected samples for which we measured fracture toughness, as well as the subcritical crack growth index under different moisture conditions. Preliminary analysis of the field crack data indicates that each rock type (granite, sandstone, quartzite) is characterized by unique macro- and micro-scale crack characteristics consistent with known generic subcritical cracking parameters for those rocks. Crack density and length correlate with erosion rates in faster eroding rock types, but not slowly eroding ones. Overall, we hope these data will help to shed light on the driving and limiting factors for the mechanical production of porosity in rock at and near Earth's surface.

Microstructures in naturally deformed Upper Rotliegend salt rocks from Northern Germany

NASA Astrophysics Data System (ADS)

Henneberg, Mareike; Hammer, Jörg; Mertineit, Michael

2017-04-01

Permian and Meso-/Cenozoic salt formations are represented in wide parts of the German geologic underground (Reinhold & Hammer 2016). They are of interest for cavern storage of oil and gas as well as of renewable energies (in form of compressed air or hydrogen). For industrial exploration purposes, more detailed data about the composition, barrier properties, as well as the genesis and deformation of the rocks is needed. In central Northern Germany, salt rocks from the Upper Rotliegend are implemented in diapir structures together with salt formations from the Zechstein. Rotliegend salt rocks are characterized by halite that contains patches of detrital material which account for 5 to 60 vol.% of the rock. They show a characteristic red to purple color. Drill cores containing Rotliegend halite rocks from different locations were investigated in this study by using petrographical and microstructural methods. The halite shows different fabric types: (i) euhedral to hypidiomorphic grains with grain sizes up to several millimeters, (ii) polygonal grains with smaller grain sizes between 0.1 and 3 mm, and (iii) fibrous halite. Halite grain boundaries are decorated with fluid inclusions, especially around the contact to detrital material. Subgrains in halite are abundant in all investigated samples and show average sizes between 140 µm and 217 µm. These correspond to average differential stresses of 1 MPa to 1.45 MPa (Carter et al. 1993, Schléder & Urai 2005). The detrital material consists of clasts of quartz, feldspar, mica, carbonates and metal oxides with grain sizes of clay to silt fraction. In some samples, the detrital components show internal deformation by folding and fracturing. Depending on the location, different quantities of authigenic evaporite minerals, like carbonate and anhydrite, formed. Fractures are filled with halite, anhydrite and celestine. The different types of halite fabric are an indication of locally different deformational behavior of the rocks, which depends mainly on the amount and type of detrital material. The observed subgrain formation points to intracrystalline dislocation creep as a deformation mechanism, which has occurred in different types of halite fabric. However, the high amount of fluid inclusions around material boundaries also point to an interaction of the different material components, which locally might have enhanced fluid based grain boundary migration during deformation. It is still to be investigated, how the overall rheological behavior of Rotliegend halite is influenced by the detrital components. Carter, N.L., Horseman, S.T., Russel, J.E. & Handin, J. 1993. Rheology of rocksalt. J. Struct. Geol., 15 (9-10), 1257-1271. Reinhold, K. & Hammer, J. 2016. Steinsalzlager in den salinaren Formationen Deutschlands. Z. Dt. Ges. Geowiss. 167, 167-190. Schléder, Z. & Urai, J.L. 2005. Microstructual evolution of deformation-modified primary halite from the Middle Triassic Röt Formation at Hengelo. The Netherlands, Int. J. Earth Sci. 94, 941-955.

Petrography and petrology of Smoky Butte intrusives, Garfield County, Montana

USGS Publications Warehouse

Matson, Robert E.

1960-01-01

The Smoky Butte intrusives are located in T. 18 N., R. 36 E. Garfield County, Montana on the extreme eastern edge of the petrographic province of Central Montana. They consist of dikes and plugs arranged in linear, en-echelon pattern with a northeast trend and intrude the Tullock member (Paleocene age) of the Fort Union formation. Extrusive rocks are absent. The rocks are potassium-rich volcanic types showing a disequilibrium mineral assemblage consisting of sanidine, leucite, biotite, olivine, pyroxene, magnetite plus. ilmenite, apatite, calcite, quartz, and a yellowish to dark greenish glassy groundmass. Two chemical analyses of Smoky Butte rocks show high magnesium, potassium, titanium, and phosphorous and low aluminum and sodium content. The two norm calculations show that the rocks are oversaturated with 1.3 and 3.1 per-cent excess silica. Because of the peculiar nature of the Smoky Butte rocks, descriptive names have been applied to them. They are divided into six different types. Three periods of intrusion are proposed for Smoky Butte quarry where three rock types crop out. Other evidence for multiple injection occurs in several multiple dikes. The upper contact of the intrusion is visible on a few plugs and dikes. Smoky Butte rocks show some similarities to the undersaturated potassium-rich rocks of the Highwood and Bearpaw Mountains of Montana, the rocks of the Leucite Hills of Wyoming, and the oversaturated rocks of the West Kimberly District of Australia.

Spatial thermal radiometry contribution to the Massif Armoricain and the Massif Central France litho-structural study

NASA Technical Reports Server (NTRS)

Scanvic, J. Y. (Principal Investigator)

1980-01-01

Thermal zones delimited on HCMM images, by visual interpretation only, were correlated with geological units and carbonated rocks, granitic, and volcanic rocks were individualized rock signature is evolutive parameter and some distinctions were made by addition of day, night and seasonal thermal image interpretation. This analysis also demonstrated that forest cover does not mask the underlying rocks thermal signature. Thermal linears are associated with known tectonics but the observed thermal variations from day to night and from one to another represent a promising concept to be studied in function of neotectonics and hydrogeology. The thermal anomalies discovered represent a potential interest which is to be evaluated. Significant results were obtained in the Mont Dore area and additional geological targets were defined in the Paris Basin and the Montmarault granite.

Modeling rock specimens through 3D printing: Tentative experiments and prospects

NASA Astrophysics Data System (ADS)

Jiang, Quan; Feng, Xiating; Song, Lvbo; Gong, Yahua; Zheng, Hong; Cui, Jie

2016-02-01

Current developments in 3D printing (3DP) technology provide the opportunity to produce rock-like specimens and geotechnical models through additive manufacturing, that is, from a file viewed with a computer to a real object. This study investigated the serviceability of 3DP products as substitutes for rock specimens and rock-type materials in experimental analysis of deformation and failure in the laboratory. These experiments were performed on two types of materials as follows: (1) compressive experiments on printed sand-powder specimens in different shapes and structures, including intact cylinders, cylinders with small holes, and cuboids with pre-existing cracks, and (2) compressive and shearing experiments on printed polylactic acid cylinders and molded shearing blocks. These tentative tests for 3DP technology have exposed its advantages in producing complicated specimens with special external forms and internal structures, the mechanical similarity of its product to rock-type material in terms of deformation and failure, and its precision in mapping shapes from the original body to the trial sample (such as a natural rock joint). These experiments and analyses also successfully demonstrate the potential and prospects of 3DP technology to assist in the deformation and failure analysis of rock-type materials, as well as in the simulation of similar material modeling experiments.

Rheological stratification of the Hormuz Salt Formation in Iran - microstructural study of the dirty and pure rock salts from the Kuh-e-Namak (Dashti) salt diapir

NASA Astrophysics Data System (ADS)

Závada, Prokop; Desbois, Guillaume; Urai, Janos; Schulmann, Karel; Rahmati, Mahmoud; Lexa, Ondrej; Wollenberg, Uwe

2014-05-01

Significant viscosity contrasts displayed in flow structures of a mountain namakier (Kuh-e-Namak - Dashti), between 'weak' terrestrial debris bearing rock salt types and 'strong' pure rock salt types are questioned for deformation mechanisms using detailed quantitative microstructural study including crystallographic preferred orientation (CPO) mapping of halite grains. While the solid impurity rich ("dirty") rock salts contain disaggregated siltstone and dolomite interlayers, "clean" salts (debris free) reveal microscopic hematite and remnants of abundant fluid inclusions in non-recrystallized cores of porphyroclasts. Although flow in both, the recrystallized dirty and clean salt types is accommodated by combined mechanisms of pressure-solution creep (PS), grain boundary sliding (GBS) and dislocation creep accommodated grain boundary migration (GBM), their viscosity contrasts are explained by significantly slower rates of intergranular diffusion and piling up of dislocations at hematite inclusions in clean salt types. Porphyroclasts of clean salts deform by semi-brittle and plastic mechanisms with intra-crystalline damage being induced also by fluid inclusions that explode in the crystals at high fluid pressures. Boudins of clean salt types with coarse grained and original sedimentary microstructure suggest that clean rock salts are associated with dislocation creep dominated power law flow in the source layer and the diapiric stem. Rheological contrasts between both rock salt classes apply in general for the variegated and terrestrial debris rich ("dirty") Lower Hormuz and the "clean" rock salt forming the Upper Hormuz, respectively, and suggest that large strain rate gradients likely exist along horizons of mobilized salt types of different composition and microstructure.

The vernon supersuite: Mesoproterozoic A-type granitoid rocks in the New Jersey highlands

USGS Publications Warehouse

Volkert, R.A.; Drake, Avery A.

1998-01-01

Abundant Mesoproterozoic A-type granitoid rocks of two intrusive suites underlie approximately 50 percent of the New Jersey Highlands. These rocks, the Byram Intrusive and Lake Hopatcong Intrusive Suites, consist of granite, alaskite, quartz monzonite, monzonite, and minor pegmatite. Byram and Lake Hopatcong rocks, although different mineralogically, are similar geochemically and contain overlapping abundances of most major and trace elements. Petrographic relationships, geochronology, field relationships, and geochemical similarities support a comagmatic origin for both suites. They constitute the here named Vernon Supersuite.

General Approach for Rock Classification Based on Digital Image Analysis of Electrical Borehole Wall Images

NASA Astrophysics Data System (ADS)

Linek, M.; Jungmann, M.; Berlage, T.; Clauser, C.

2005-12-01

Within the Ocean Drilling Program (ODP), image logging tools have been routinely deployed such as the Formation MicroScanner (FMS) or the Resistivity-At-Bit (RAB) tools. Both logging methods are based on resistivity measurements at the borehole wall and therefore are sensitive to conductivity contrasts, which are mapped in color scale images. These images are commonly used to study the structure of the sedimentary rocks and the oceanic crust (petrologic fabric, fractures, veins, etc.). So far, mapping of lithology from electrical images is purely based on visual inspection and subjective interpretation. We apply digital image analysis on electrical borehole wall images in order to develop a method, which augments objective rock identification. We focus on supervised textural pattern recognition which studies the spatial gray level distribution with respect to certain rock types. FMS image intervals of rock classes known from core data are taken in order to train textural characteristics for each class. A so-called gray level co-occurrence matrix is computed by counting the occurrence of a pair of gray levels that are a certain distant apart. Once the matrix for an image interval is computed, we calculate the image contrast, homogeneity, energy, and entropy. We assign characteristic textural features to different rock types by reducing the image information into a small set of descriptive features. Once a discriminating set of texture features for each rock type is found, we are able to discriminate the entire FMS images regarding the trained rock type classification. A rock classification based on texture features enables quantitative lithology mapping and is characterized by a high repeatability, in contrast to a purely visual subjective image interpretation. We show examples for the rock classification between breccias, pillows, massive units, and horizontally bedded tuffs based on ODP image data.

The Age and Geodynamic Evolution of the Metamorphic sole rocks from Izmir-Ankara-Erzıncan suture zone (Northern-Turkey)

NASA Astrophysics Data System (ADS)

Melih Çörtük, Rahmi; Faruk Çelik, Ömer; Özkan, Mutlu; Sherlock, Sarah C.; Marzoli, Andrea; Altıntaş, İsmail Emir; Topuz, Gültekin

2016-04-01

The İzmir-Ankara-Erzincan suture zone in northern Turkey is one of the major tectonic zones separating the Pontides to the North from the Anatolide-Tauride block and Kı rşehir Massif to the South. The accretionary complex of the İzmir-Ankara-Erzincan suture zone, near Artova, is composed mainly of peridotites with varying degree serpentinization, metamorphic rocks, basalt, sandstones, pelagic and neritic limestones. The metamorphic rocks are represented by amphibolite, garnet micaschit, calc-schist and marble. The metamorphic rocks were interpreted as the metamorphic sole rocks. Because; (i) They are tectonically located beneath the serpentinized peridotites. (ii) Foliation planes of both the amphibolites and mantle tectonites are parallel to each other. (iii) The metamorphic rocks are crosscut by non-metamorphic dolerite dikes which exhibite Nb and Ta depletion relative to Th enrichment on the N-MORB normalized multi-element spider diagram. The dolerite dikes display flat REE patterns (LaN/YbN=0.85-1.24). These geochemical signatures of the dolerite dikes are indicative of subduction component during their occurrences. Geochemical observations of the amphibolites suggest E-MORB- and OIB-like signatures (LaN/SmN= 1.39-3.14) and their protoliths are represented by basalt and alkali basaltic rocks. Amphiboles from the amphibolites are represented by calcic amphiboles (magnesio-hornblende, tchermakite and tremolite) and they yielded 40Ar-39Ar ages between 157.8 ± 3.6 Ma and 139 ± 11 Ma. These cooling ages were interpreted to be the intra-oceanic subduction/thrusting time of the İzmir-Ankara-Erzincan oceanic domain. This study was funded by TÜBİTAK (Project no: 112Y123).

The geochemistry of carbonatites revisited: Two major types of continental carbonatites and their trace-element signatures

NASA Astrophysics Data System (ADS)

Chakhmouradian, A.

2009-04-01

There have been several attempts to systematize the geochemistry of carbonatites, most recently by Samoilov (1984), Nelson et al. (1988), Woolley and Kempe (1989), and Rass (1998). These studies revealed a number of important geochemical characteristics that can be used to track the evolutionary history of these rocks, distinguish them from modally similar metamorphic parageneses, and aid in mineral exploration for rare earths, niobium and other resources commonly associated with carbonatites. Important breakthroughs in the understanding of carbonatite petrogenesis and numerous reports of new carbonatite localities made in the past two decades lay the ground for a critical re-assessment of the geochemistry of these rocks. A new representative database of whole-rock carbonatite analyses was compiled from the post-1988 literature and various unpublished sources. The database contains 820 analyses encompassing calcio-, magnesio- and ferrocarbonatites from 174 localities (ca. one-third of the total number of carbonatites known worldwide) reduced to ca. 350 analyses following the approach of Woolley and Kempe (1989). Carbonatites emplaced in oceanic settings (e.g., Cape Verde), ophiolite belts (e.g., Oman), or those of uncertain tectonic affinity (e.g., El Picacho in Mexico) were not included. Two major types of continental carbonatites can be distinguished on the basis of their geological setting and trace-element geochemistry: (1) carbonatites emplaced in rifts and smaller-scale extensional structures developed in stable Archean cratons or paleo-orogenic belts, and (2) carbonatites emplaced in collisional settings following the orogenesis. In both settings, the most common and best-studied type of carbonatite is calcite carbonatite (predominantly intrusive with a small percentage of extrusive occurrences), which accounts for 62% of the analyses included in the database. Both types of carbonatite are typically associated with alkaline silicate lithologies (meleigites, nepheline syenites, etc.), but those associated with type-1 rocks are typically Na-rich and silica-undersaturated, whereas type-2 carbonatites are associated with K-rich silica-saturated to undersaturated syenites. Type-1 carbonatites are notably different from their type-2 counterparts in showing higher abundances of high-field-strength elements (HFSE = Ti, Zr, Hf, Nb, Ta), Rb, U and V, but lower levels of Sr, Ba, Pb, rare-earth elements, F and S. Key element ratios are also different in the two carbonatite types; in particular, Rb/K, Nb/Ta, Zr/Hf and Ga/Al values are consistently higher in type-1 samples. Notably, some element ratios (e.g., Co/Ni and Y/Ho) are very similar in both groups. Type-2 carbonatites commonly show a 13C-depleted signature relative to the "primary carbonatite" range (Deines, 1989). The observed differences in geological setting and geochemistry indicate the existence of two distinct carbonatite sources in the subcontinental lithosphere: amphibole-bearing lherzolite producing type-1 rocks (cf. Chakhmouradian, 2006), and subducted oceanic crust (rutile-bearing eclogite?) yielding type-2 melts depleted in HFSE, but enriched in light carbon, large-ion-incompatible elements, F and S. References: Chakhmouradian, A.R. (2006) High-field-strength elements in carbonatitic rocks: Geochemistry, crystal chemistry and significance for constraining the sources of carbonatites. Chem. Geol., 235, 138-160. Deines, P. (1989) Stable isotope variations in carbonatites. In: Carbonatites: Genesis and Evolution (K. Bell, Ed.). Unwin Hyman, London, 301-359. Nelson, D.R., Chivas, A.R., Chappell, B.V. and McCulloch, M.T. (1988) Geochemical and isotopic systematic in carbonatites and implications for the evolution of ocean-island sources. Geochim. Cosmochim. Acta, 52, 1-17. Rass, I.T. (1998) Geochemical features of carbonatite indicative of the composition, evolution, and differentiation of their mantle magmas. Geochem. Int., 36, 107-116. Samoilov, V.S. (1984) Geochemistry of Carbonatites. Nauka, Moscow (in Russ.). Woolley, A.R. and Kempe, D.R.C. (1989) Carbonatites: nomenclature, average chemical compositions, and element distribution. In: Carbonatites: Genesis and Evolution (K. Bell, Ed.). Unwin Hyman, London, 1-14.

Rocks and geology in the San Francisco Bay region

USGS Publications Warehouse

Stoffer, Philip W.

2002-01-01

The landscape of the San Francisco Bay region is host to a greater variety of rocks than most other regions in the United States. This introductory guide provides illustrated descriptions of 46 common and important varieties of igneous, sedimentary, and metamorphic rock found in the region. Rock types are described in context of their identification qualities, how they form, and where they occur in the region. The guide also provides discussion about of regional geology, plate tectonics, the rock cycle, the significance of the selected rock types in relation to both earth history and the impact of mineral resources on the development in the region. Maps and text also provide information where rocks, fossils, and geologic features can be visited on public lands or in association with public displays in regional museums, park visitor centers, and other public facilities.

Chronological evidence that the Moon is either young or did not have a global magma ocean.

PubMed

Borg, Lars E; Connelly, James N; Boyet, Maud; Carlson, Richard W

2011-08-17

Chemical evolution of planetary bodies, ranging from asteroids to the large rocky planets, is thought to begin with differentiation through solidification of magma oceans many hundreds of kilometres in depth. The Earth's Moon is the archetypical example of this type of differentiation. Evidence for a lunar magma ocean is derived largely from the widespread distribution, compositional and mineralogical characteristics, and ancient ages inferred for the ferroan anorthosite (FAN) suite of lunar crustal rocks. The FANs are considered to be primary lunar flotation-cumulate crust that crystallized in the latter stages of magma ocean solidification. According to this theory, FANs represent the oldest lunar crustal rock type. Attempts to date this rock suite have yielded ambiguous results, however, because individual isochron measurements are typically incompatible with the geochemical make-up of the samples, and have not been confirmed by additional isotopic systems. By making improvements to the standard isotopic techniques, we report here the age of crystallization of FAN 60025 using the (207)Pb-(206)Pb, (147)Sm-(143)Nd and (146)Sm-(142)Nd isotopic systems to be 4,360 ± 3 million years. This extraordinarily young age requires that either the Moon solidified significantly later than most previous estimates or the long-held assumption that FANs are flotation cumulates of a primordial magma ocean is incorrect. If the latter is correct, then much of the lunar crust may have been produced by non-magma-ocean processes, such as serial magmatism.

Geologic framework of oil and gas genesis in main sedimentary basins from Romania Oprea Dicea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ionescu, N.; Morariu, C.D.

1991-03-01

Oil and gas fields located in Moldavic nappes are encompassed in Oligocene and lower Miocene formations, mostly in the marginal folds nappe, where Kliwa Sandstone sequences have high porosity, and in the Black Sea Plateau. The origin of the hydrocarbon accumulations from the Carpathian foredeep seems to be connected to the Oligocene-lower Miocene bituminous formations of the marginal folds and sub-Carpathian nappes. In the Gethic depression, the hydrocarbon accumulations originate in Oligocene and Miocene source rocks and host in structural, stratigraphical, and lithological traps. The accumulations connected with tectonic lines that outline the areal extension of the Oligocene, Miocene, andmore » Pliocene formations are in the underthrusted Moesian platform. The hydrocarbon accumulations related to the Carpathian foreland represent about 40% of all known accumulations in Romania. Most of them are located in the Moesian platform. In this unit, the oil and gas fields present a vertical distribution at different stratigraphic levels, from paleozoic to Neogene, and in all types of reservoirs, suggesting multicycles of oleogenesis, migration, accumulation, and sealing conditions. The hydrocarbon deposits known so far on the Black Sea continental plateau are confined in the Albian, Cenomanian, Turonian-Senonian, and Eocene formations. The traps are of complex type structural, lithologic, and stratigraphic. The reservoirs are sandstones, calcareous sandstones, limestones, and sands. The hydrocarbon source rocks are pelitic and siltic Oligocene formations. Other older source rocks are probably Cretaceous.« less

Chronological evidence that the Moon is either young or did not have a global magma ocean

NASA Astrophysics Data System (ADS)

Borg, Lars E.; Connelly, James N.; Boyet, Maud; Carlson, Richard W.

2011-09-01

Chemical evolution of planetary bodies, ranging from asteroids to the large rocky planets, is thought to begin with differentiation through solidification of magma oceans many hundreds of kilometres in depth. The Earth's Moon is the archetypical example of this type of differentiation. Evidence for a lunar magma ocean is derived largely from the widespread distribution, compositional and mineralogical characteristics, and ancient ages inferred for the ferroan anorthosite (FAN) suite of lunar crustal rocks. The FANs are considered to be primary lunar flotation-cumulate crust that crystallized in the latter stages of magma ocean solidification. According to this theory, FANs represent the oldest lunar crustal rock type. Attempts to date this rock suite have yielded ambiguous results, however, because individual isochron measurements are typically incompatible with the geochemical make-up of the samples, and have not been confirmed by additional isotopic systems. By making improvements to the standard isotopic techniques, we report here the age of crystallization of FAN 60025 using the 207Pb-206Pb, 147Sm-143Nd and 146Sm-142Nd isotopic systems to be 4,360+/-3 million years. This extraordinarily young age requires that either the Moon solidified significantly later than most previous estimates or the long-held assumption that FANs are flotation cumulates of a primordial magma ocean is incorrect. If the latter is correct, then much of the lunar crust may have been produced by non-magma-ocean processes, such as serial magmatism.

Burial of Undersea Pipes and Cables State-of-the Art Assessment,

DTIC Science & Technology

1976-01-01

rippable rocks." The biggest rippers can penetrate to a depth of over 6 ft, but working to this kind of depth in a single...34-’ " ....... ......................... •". . "-.’...........".-’-.. ... .--. ’’""’"..- % . . . ... ,.. types of rippers and tractors classify various rock types as " rippable ," "marginal," or "non- rippable " depending on seismic...highest velocity for consistently rippable conditions, and in some types of rock the same limit would occur at less

Chemical, mineralogical and textural systematics of non-mare melt rocks: Implications for lunar impact and volcanic processes

NASA Technical Reports Server (NTRS)

Irving, A. J.

1975-01-01

Based on a synthesis of chemical data for over 200 samples, the nonmare rocks with fine grained melt textures can be classified into 7 major groups: anorthositic basalts, troctolitic basalts, VHA basalts, Apollo 14-type KREEP basalts, Apollo 15-type KREEP basalts, Apollo 17-type KREEP basalts, and aluminous mare basalts. Review of chemical, mineralogical, textural and experimental evidence leads to preferred hypotheses for the origins of these rocks; those hypotheses are discussed in detail.

A new laboratory approach to shale analysis using NMR relaxometry

USGS Publications Warehouse

Washburn, Kathryn E.; Birdwell, Justin E.; Baez, Luis; Beeney, Ken; Sonnenberg, Steve

2013-01-01

Low-field nuclear magnetic resonance (LF-NMR) relaxometry is a non-invasive technique commonly used to assess hydrogen-bearing fluids in petroleum reservoir rocks. Measurements made using LF-NMR provide information on rock porosity, pore-size distributions, and in some cases, fluid types and saturations (Timur, 1967; Kenyon et al., 1986; Straley et al., 1994; Brown, 2001; Jackson, 2001; Kleinberg, 2001; Hurlimann et al., 2002). Recent improvements in LF-NMR instrument electronics have made it possible to apply methods used to measure pore fluids to assess highly viscous and even solid organic phases within reservoir rocks. T1 and T2 relaxation responses behave very differently in solids and liquids; therefore the relationship between these two modes of relaxation can be used to differentiate organic phases in rock samples or to characterize extracted organic materials. Using T1-T2 correlation data, organic components present in shales, such as kerogen and bitumen, can be examined in laboratory relaxometry measurements. In addition, implementation of a solid-echo pulse sequence to refocus T2 relaxation caused by homonuclear dipolar coupling during correlation measurements allows for improved resolution of solid-phase protons. LF-NMR measurements of T1 and T2 relaxation time distributions were carried out on raw oil shale samples from the Eocene Green River Formation and pyrolyzed samples of these shales processed by hydrous pyrolysis and techniques meant to mimic surface and in-situ retorting. Samples processed using the In Situ Simulator approach ranged from bitumen and early oil generation through to depletion of petroleum generating potential. The standard T1-T2 correlation plots revealed distinct peaks representative of solid- and liquid-like organic phases; results on the pyrolyzed shales reflect changes that occurred during thermal processing. The solid-echo T1 and T2 measurements were used to improve assessment of the solid organic phases, specifically kerogen, thermally degraded kerogen, and char. Integrated peak areas from the LF-NMR results representative of kerogen and bitumen were found to be well correlated with S1 and S2 parameters from Rock-Eval programmed pyrolysis. This study demonstrates that LFNMR relaxometry can provide a wide range of information on shales and other reservoir rocks that goes well beyond porosity and pore-fluid analysis.

Impact of Magmatism on the Geodynamic Evolution of Southern Georgia on the Example of the Lesser Caucasus Artvin-Bolnisi Block.

NASA Astrophysics Data System (ADS)

Sadradze, Nino; Adamia, Shota; Zakariadze, Guram; Beridze, Tamara; Khutsishvili, Sophio

2017-04-01

The Georgian region occupies the central part of the collisional zone between the Eurasian and Africa-Arabian continents and is actually a collage of lithospheric fragments of the Tethyan Ocean and its northern and southern continental margins. Magmatic evolution is an important event in the formation and development of the geological structure of Southern Georgia, where several reliably dated volcanogenic and volcanogenic-sedimentary formations are established. The region represents a modern analogue of continental collision zone, where subduction-related volcanic activity lasted from Paleozoic to the end of Paleogene. After the period of dormancy in the Early-Middle Miocene starting from the Late Miocene and as far as the end of the Pleistocene, primarily subaerial volcanic eruptions followed by formation of volcanic highlands and plateaus occurred in the reigon. The Upper Miocene to Holocene volcanic rocks are related to the transverse Van-Transcaucasian uplift and belong to post-collisional calc- alkaline basalt-andesite-dacite-rhyolite series. A system of island arc and intra-arc rift basins (Artvin-Bolnisi and Achara-Trialeti) have been interpreted as characteristic of the pre-collisional stage of the region development, while syn- post-collisional geodynamic events have been attributed to intracontinental stage. Outcrops of the postcollisional magmatic rocks are exposed along the boundaries of the major tectonic units of the region. The Artvin-Bolnisi unit forms the northwestern part of the Lesser Caucasus and represents an island arc domain of so called the Somkheto-Karabakh Island Arc or Baiburt-Garabagh-Kapan belt. It was formed mainly during the Jurassic-Eocene time interval on the southern margin of the Eurasian plate by nort-dipping subduction of the Neotethys Ocean and subsequent collision to the Anatolia-Iranian continental plate. The Artvin-Bolnisi unit, including the Bolnisi district, was developing as a relatively uplifted island arc-type unit with suprasubduction extrusive and intrusive events. Volcanogenic complexes are characterized by variable lateral and vertical regional stratigraphic relationships and are subdivided into several formations, dominated by volcanic rocks: basalts, andesites, dacites, and rhyolites of calc-alkaline-subalkaline series. Volcanic rocks are of shallow-marine to subaerial type. The peculiarities of magmatic activity and geodynamic development of the region stipulated synchronous formation of significant base and precious metals deposits of the Bolnisi ore district.

Architecture of ductile-type passive margins: Geological constraints from the inverted Cretaceous basin of the North-Pyrenean Zone (`Chaînons Béarnais', Western Pyrenees)

NASA Astrophysics Data System (ADS)

Corre, B.; Lagabrielle, Y.; Labaume, P.; Lahfid, A.; Boulvais, P.; Bergamini, G.; Fourcade, S.; Clerc, C. N.; Asti, R.

2017-12-01

Subcontinental lithospheric mantle rocks are exhumed at the foot of magma-poor distal passive margins as a response to extreme stretching of the continental crust. The North-Pyrenean Zone (NPZ) exposes remnants of such extremely stretched paleo-passive margin that represent field analogues to study the processes of continental crust thinning and mantle exhumation. The NPZ results from the inversion of basins opened between the Iberia and Europa plates during Albo-Cenomanian times. The Chaînons Béarnais belt displays a fold-and-thrust structure involving the Mesozoic sedimentary cover associated with peridotite bodies in tectonic contact with Paleozoic basement lenses of small size. Continental extension developed under hot thermal conditions, as demonstrated by the syn-metamorphic Cretaceous ductile deformation affecting both the crustal basement and the Mesozoic cover. In this study, we present structural and geochemical data providing constraints to reconstruct the evolution of this paleo-margin. Field work confirms that the Mesozoic cover is intimately associated with mantle rocks and thin tectonic lenses of middle crust. Micro-structural studies show that the greenschist facies ductile deformation in the crust produced a mylonitic foliation which is always parallel to the crust/mantle contact. The crust/mantle detachment fault is a major shear zone characterized by anastomosed shear bands. It also shows that the pre-rift cover was detached from its bedrock at the Keuper evaporites level and was welded to mantle rocks during their exhumation at the foot of the margin. We show that: (i) the boudinaged pre-rift sediments have undergone drastic syn-metamorphic thinning with the genesis of a S0/S1 foliation and, (ii) the Paleozoic basement has been ductilely deformed, into thin tectonic lenses that remained welded to the exhumed mantle rocks. The ductile behavior is related to the presence of a thick pre- and syn-rift cover acting as an efficient thermal blanket. This new geological data set highlights important characteristics of ductile-type hyper-extended passive margin. Finally, we stress that studying field analogues represents a major tool to better understand the mechanisms of crustal thinning associated with mantle exhumation and their structural inheritance during tectonic inversion.

Evaluation of kinetic uncertainty in numerical models of petroleum generation

USGS Publications Warehouse

Peters, K.E.; Walters, C.C.; Mankiewicz, P.J.

2006-01-01

Oil-prone marine petroleum source rocks contain type I or type II kerogen having Rock-Eval pyrolysis hydrogen indices greater than 600 or 300-600 mg hydrocarbon/g total organic carbon (HI, mg HC/g TOC), respectively. Samples from 29 marine source rocks worldwide that contain mainly type II kerogen (HI = 230-786 mg HC/g TOC) were subjected to open-system programmed pyrolysis to determine the activation energy distributions for petroleum generation. Assuming a burial heating rate of 1??C/m.y. for each measured activation energy distribution, the calculated average temperature for 50% fractional conversion of the kerogen in the samples to petroleum is approximately 136 ?? 7??C, but the range spans about 30??C (???121-151??C). Fifty-two outcrop samples of thermally immature Jurassic Oxford Clay Formation were collected from five locations in the United Kingdom to determine the variations of kinetic response for one source rock unit. The samples contain mainly type I or type II kerogens (HI = 230-774 mg HC/g TOC). At a heating rate of 1??C/m.y., the calculated temperatures for 50% fractional conversion of the Oxford Clay kerogens to petroleum differ by as much as 23??C (127-150??C). The data indicate that kerogen type, as defined by hydrogen index, is not systematically linked to kinetic response, and that default kinetics for the thermal decomposition of type I or type II kerogen can introduce unacceptable errors into numerical simulations. Furthermore, custom kinetics based on one or a few samples may be inadequate to account for variations in organofacies within a source rock. We propose three methods to evaluate the uncertainty contributed by kerogen kinetics to numerical simulations: (1) use the average kinetic distribution for multiple samples of source rock and the standard deviation for each activation energy in that distribution; (2) use source rock kinetics determined at several locations to describe different parts of the study area; and (3) use a weighted-average method that combines kinetics for samples from different locations in the source rock unit by giving the activation energy distribution for each sample a weight proportional to its Rock-Eval pyrolysis S2 yield (hydrocarbons generated by pyrolytic degradation of organic matter). Copyright ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

Excess Ar in biotites from the Broderick Falls (Webuye) area, western Kenya: implications for the tectonothermal history of the Mozambique Belt and its Archaean foreland

NASA Astrophysics Data System (ADS)

Shibata, K.; Suwa, K.; Uchiumi, S.; Agata, T.

1996-10-01

RbSr whole rock and KAr mineral age determinations were made on rocks from the Broderick Falls (Webuye) area, western Kenya. Granitic rocks yielded a RbSr whole rock isochron age of 2555 ± 101 Ma with an initial {87Sr}/{86Sr} ratio of 0.70121 ± 0.00038. This age represents the time of granitoid emplacement. KAr mineral ages range from 574 to 3420 Ma, which is very variable with respect to mineral type and locality. Mylonitic granodiorite very close to the Nandi Escarpment gave a KAr age of 916 Ma from biotite, suggesting the time of the activity of the Nandi Fault, which may be an earlier phase of the Pan-African Orogeny. Ages of biotites in a zone between 4 and 6 km northeast of the Nandi Fault are anomalously high compared to those of coexisting hornblende and the RbSr isochron age, confirming the existence of excess 40Ar in biotite. Excess 40Ar was probably introduced into biotite under the appropriate temperature conditions prevailing near the Nandi Fault. Taramite, a rare sodic-calcic amphibole, was found in a cordierite-biotite gneiss of the Kavirondian Supergroup and gave a typical Pan-African KAr age of 574 Ma. The last Pan-African metamorphism occurred in the terrane east of the Surongai Thrust.

Database Dictionary for Ethiopian National Ground-Water Database (ENGDA) Data Fields

DTIC Science & Technology

2007-01-01

Coarse Sand Fine Sand Fine-Grained Sandstone Fractured Igneous and Metamorphic Rock Gravel Karst Limestone, Dolomite Medium Sand Medium-Grained...Coarse Sand; Fine Sand; Fine-Grained Sandstone; Fractured Igneous and Metamorphic Rock; Gravel; Karst Limestone/ Dolomite ; Medium Sand; Medium...aquifer lithology (rock type; Babcock and other, 2004). - 20 - Data Type: List, 1-character code C Consolidated porous sedimentary I Fractured

Geology and Our Environment. Environmental Education Curriculum. Revised.

ERIC Educational Resources Information Center

Topeka Public Schools, KS.

Rocks, and the soil formed from rock, play a major role in determining such particulars as the type of crops that can be grown in a specific area and the type of housing that can be constructed. Also, rocks may supply fuel and building materials, and provide information about the history of an area. This unit is constructed to expose secondary…

Possible Diagenetic Connection Between the Dark Fe-rich Rocks at Gale Crater, Mars, and the Felsic JakeM Class Rocks

NASA Astrophysics Data System (ADS)

Gellert, R.; Berger, J. A.; Boyd, N.; O'Connell-Cooper, C.; Desouza, E.; Schmidt, M. E.; Thompson, L. M.; VanBommel, S.; Yen, A. S.; Arvidson, R. E.; Edgett, K. S.; Grotzinger, J. P.

2016-12-01

During its >13 km traverse so far, the Mars rover Curiosity encountered several dark, fine-grained float rocks. The first example investigated with the APXS, Et_Then (Sol 91), was found near the landing site. It has an enigmatic composition with very high 27% FeO, elevated Na and K, and low Mg. A boulder with nearly identical chemistry, called Secure (Sol 560), was found near the Kimberley waypoint, some 5 km southwest. Both rocks have a unique enrichment in Ga of about 70 ppm, significantly greater than the typical 20 ppm or lower that represents approximately the detection limit for Ga with the APXS. While the origin of these loose float rocks is still under discussion, a recent measurement of a boulder another 7 km southwest on lower Mount Sharp might shed light on the formation process. Two targets, named Sonneblom and Zambezi (Sols 1407 and 1409), were measured on a dark gray boulder in a blocky deposit overlying Murray formation mudstones. They share many of the compositional characteristics of the felsic Jake_M class rocks, also found along Curiosity's traverse, which have elevated alkaline elements and very low Cr, Ni, and Zn. The key difference relative to the original Jake_M rock is the higher Fe and Si and lower Al. Sonneblom and Zambezi are similar to several isolated rocks encountered earlier during the traverse and nearly identical to Oscar (Sol 515). The three rock classes, Jake_M, Oscar and Et_Then, all occurring as isolated float rocks separated by >10 km, seem to form a mixing line between Jake_M proper and Et_Then as endmembers, adding increasing amounts of iron oxides and possibly SiO2 as cement to fragments of Jake_M-like material. Another curious piece of evidence is that the rocks Sonneblom, Zambezi and Oscar have uniquely elevated Ga of about 40 ppm as well, connecting them to Et_Then. Whereas in-depth textural comparison of all these chemically related rocks is pending, based on the compositional trends these erosion-resistant rocks might have been part of an extensive formation that incorporated the felsic material into varying amounts of iron oxides and SiO2 as cement. A connection to the hematite ridge, expected to be reached in the near future with the rover on its traverse up Mount Sharp, could be possible as well. The elevated Fe/Mn ratio of Secure- and Oscar-type rocks indicates an elevated Fe3+ abundance.

Modeling oil generation with time-temperature index graphs based on the Arrhenius equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hunt, J.M.; Lewan, M.D.; Hennet, R.J.C.

1991-04-01

The time and depth of oil generation from petroleum source rocks containing type II kerogens can be determined using time-temperature index (TTI) graphs based on the Arrhenius equation. Activation energies (E) and frequency factors (A) used in the Arrhenius equation were obtained from hydrous pyrolysis experiments on rock samples in which the kerogens represent the range of type II kerogen compositions encountered in most petroleum basins. The E and A values obtained were used to construct graphs that define the beginning and end of oil generation for most type II kerogens having chemical compositions in the range of these standards.more » Activation energies of these standard kerogens vary inversely with their sulfur content. The kerogen with the highest sulfur content had the lowest E value and was the fastest in generating oil, whereas the kerogen with the lowest sulfur content had the highest E value and was the slowest in generating oil. These standard kerogens were designated as types IIA, B, C, and D on the basis of decreasing sulfur content and corresponding increasing time-temperature requirements for generating oil. The {Sigma}TTI{sub ARR} values determined graphically with these type II kerogen standards in two basin models were compared with a computer calculation using 2,000 increments. The graphical method came within {plus minus} 3% of the computer calculation. As type II kerogens are the major oil generators in the world, these graphs should have wide application in making preliminary evaluations of the depth of the oil window in exploration areas.« less

Fluid and mass transfer at subduction interfaces-The field metamorphic record

NASA Astrophysics Data System (ADS)

Bebout, Gray E.; Penniston-Dorland, Sarah C.

2016-01-01

The interface between subducting oceanic slabs and the hanging wall is a structurally and lithologically complex region. Chemically disparate lithologies (sedimentary, mafic and ultramafic rocks) and mechanical mixtures thereof show heterogeneous deformation. These lithologies are tectonically juxtaposed at mm to km scales, particularly in more intensely sheared regions (mélange zones, which act as fluid channelways). This juxtaposition, commonly in the presence of a mobile fluid phase, offers up huge potential for mass transfer and related metasomatic alteration. Fluids in this setting appear capable of transporting mass over scales of kms, along flow paths with widely varying geometries and P-T trajectories. Current models of arc magmatism require km-scale migration of fluids from the interface into mantle wedge magma source regions and implicit in these models is the transport of any fluids generated in the subducting slab along and ultimately through the subduction interface. Field and geochemical studies of high- and ultrahigh-pressure metamorphic rocks elucidate the sources and compositions of fluids in subduction interfaces and the interplay between deformation and fluid and mass transfer in this region. Recent geophysical studies of the subduction interface - its thickness, mineralogy, density, and H2O content - indicate that its rheology greatly influences the ways in which the subducting plate is coupled with the hanging wall. Field investigation of the magnitude and styles of fluid-rock interaction in metamorphic rocks representing "seismogenic zone" depths (and greater) yields insight regarding the roles of fluids and elevated fluid pore pressure in the weakening of plate interface rocks and the deformation leading to seismic events. From a geochemical perspective, the plate interface contributes to shaping the "slab signature" observed in studies of the composition of arc volcanic rocks. Understanding the production of fluids with hybridized chemical/isotopic compositions could improve models aimed at identifying the relative contributions of end-member rock reservoirs through analyses of arc volcanic rocks. Production of rocks rich in hydrous minerals, along the subduction interface, could stabilize H2O to great depths in subduction zones and influence deep-Earth H2O cycling. Enhancement of decarbonation reactions and dissolution by fluid infiltration facilitated by deformation at the interface could influence the C flux from subducting slabs entering the sub-arc mantle wedge and various forearc reservoirs. In this paper, we consider records of fluid and mass transfer at localities representing various depths and structural expressions of evolving paleo-interfaces, ranging widely in structural character, the rock types involved (ultramafic, mafic, sedimentary), and the rheology of these rocks. We stress commonalities in styles of fluid and mass transfer as related to deformation style and the associated geometries of fluid mobility at subduction interfaces. Variations in thermal structure among individual margins will lead to significant differences in not only the rheology of subducting rocks, and thus seismicity, but also the profiles of devolatilization and melting, through the forearc and subarc, and the element/mineral solubilities in any aqueous fluids or silicate melts that are produced. One key factor in considering fluid and mass transfer in the subduction interface, influencing C cycling and other chemical additions to arcs, is the uncertain degree to which sub-crustal ultramafic rocks in downgoing slabs are hydrated and release H2O-rich fluids.

Petrogenesis of the Alaskan-type mafic-ultramafic complex in the Makkah quadrangle, western Arabian Shield, Saudi Arabia

NASA Astrophysics Data System (ADS)

Habtoor, Abdelmonem; Ahmed, Ahmed Hassan; Harbi, Hesham

2016-10-01

The Makkah quadrangle is a part of the Jeddah terrane in the Precambrian basement, Western Arabian Shield of Saudi Arabia. Gabal Taftafan mafic-ultramafic complex lies within the central part of the Makkah quadrangle. The Taftafan mafic-ultramafic complex is a well-differentiated rock association which comprises of dunite core, hornblende- and plagioclase-bearing peridotites, troctolite, clinopyroxenite and marginal gabbro, in a distinctive zonal structure. The bulk-rock geochemistry of the Taftafan mafic-ultramafic rocks is characterized by a tholeiitic/sub-alkaline affinity with high Mg in the ultramafic core (0.84) and is systematically decreased towards the marginal gabbro (0.60). The patterns of trace elements show enrichment in the fluid-mobile elements (Sr, Ba) and a pronounced negative Nb anomaly which reflect a hydrous parental magma generated in a subduction tectonic setting. The mafic-ultramafic rocks of the Taftafan complex have low total rare earth elements (REE) displaying sub-parallel patterns leading to the assumption that these rocks are comagmatic and are formed by fractional crystallization from a common magma type. The platinum-group elements (PGE) content of all rock types in the Taftafan complex is very low, with ∑ PPGE > ∑ IPGE; displaying slightly positive slopes of the PGE distribution patterns. The chemistry of ferromagnesian minerals is characterized by a high forsterite (Fo) olivine with wide range (Fo91-67), from ultramafic core to the marginal gabbro, Ca-rich diopsidic clinopyroxene, and calcic hornblende. Orthopyroxene is almost absent from all rock types, or very rare when present. Hornblende and Ca-plagioclase possess the longest crystallization history since they are present in almost all rock types of the complex. Spinels in the dunite and hornblende-bearing peridotite core show homogeneous composition with intermediate Cr# (0.53-0.67). Plagioclase-bearing peridotite and troctolite have two exsolved types of spinel; Al-rich and Fe-rich varieties. All spinel varieties in the mafic-ultramafic rocks have high Fe3 + and TiO2 contents. The estimated melt composition in equilibrium with Gabal Taftafan complex is mostly similar to that of the SSZ boninitic magmas. The Taftafan mafic-ultramafic rocks show many similarities with the Alaskan-type mafic-ultramafic complexes, including the internal zonal lithology, bulk rock geochemistry, and mineral chemistry. Thus, it is neither related to a fragment of ophiolite sequence nor to the stratiform mafic-ultramafic intrusion. The location of the Taftafan complex along a major fracture zone parallel to the suture between Jeddah and Asir terranes in addition to the aforementioned striking similarities to the Alaskan-type complexes, suggests a formation in subduction-related setting from a common hydrous mafic magma.

Organic metamorphism in the California petroleum basins; Chapter A, Rock-Eval and vitrinite reflectance

USGS Publications Warehouse

Price, Leigh C.; Pawlewicz, Mark J.; Daws, Ted A.

1999-01-01

The results of ROCK-EVAL and vitrinite reflectance analyses of a large sample base from more than 70 wells located in three oil-rich California petroleum basins are reported. The cores from these wells have a wide range of present-day burial temperatures (40 ? to 220 ? C). The rocks in these basins were deposited under highly variable conditions, sometimes resulting in substantially different organic matter (OM) types in rocks tens of meters vertically apart from each other in one well. The kinetic response of these different OM types to equivalent wellknown burial histories is a pivotal point of this study. In the Los Angeles and Ventura Basins, rock organic-richness significantly increased with depth, as did kerogen hydrogen content, and the percentage of fine-grained versus coarsegrained rocks. The shales in these basins are perceived as containing primarily hydrogen-rich amorphous OM. In actuality, the shallowest 2,000 to 3,000 m of rocks in the basins, and at least the upper 6,000 m of rocks in parts of the Los Angeles Basin central syncline, are dominated by type III/IV OM. In the Los Angeles Basin, mainstage hydrocarbon (HC) generation commences in the type III/IV OM at present-day burial temperatures of 85 ? to 110 ? C, most likely around 100 ? C, and is largely complete by 220 ? C. In the Southern San Joaquin Valley Basin, mainstage HC generation commences in type III/IV OM at 150 ? C and is also largely complete by 220 ? C. In the Ventura Basin, mainstage HC generation commences above 140 ? C in type III/IV OM. The apparent lower temperatures for commencement of HC generation in the Los Angeles Basin are attributed to the fact that parts of the basin were cooled from maximal burial temperatures by increased meteoric water flows during the last glaciations. All aspects of organic metamorphism, including mainstage HC generation, are strongly suppressed in rocks with hydrogenrich OM in these basins. For example, ROCK-EVAL data suggest that mainstage HC generation has not commenced in rocks with hydrogen-rich OM at present-day temperatures of 198?C. This observation is attributed to much stronger bonds in hydrogen- rich OM compared to types III and IV OM and, therefore, significantly higher burial temperatures are required to break these bonds. This difference in OM kinetics has profound ramifications for petroleum-geochemical exploration models. Organic-matter characteristics inherited from original depositional conditions were overlaid on, and at times confused interpretation of, characteristics from organic metamorphism in all study areas. In all the basins examined in this study, immature fine-grained rocks occasionally had high to very high carbon-normalized concentrations of pre-generation indigenous bitumen. This unusual characteristic may be due to unique depositional conditions in these basins.

Petrogenesis and tectonic significance of the late Triassic mafic dikes and felsic volcanic rocks in the East Kunlun Orogenic Belt, Northern Tibet Plateau

NASA Astrophysics Data System (ADS)

Hu, Yan; Niu, Yaoling; Li, Jiyong; Ye, Lei; Kong, Juanjuan; Chen, Shuo; Zhang, Yu; Zhang, Guorui

2016-02-01

We present zircon U-Pb ages and geochemical data on the late Triassic mafic dikes (diabase) and felsic volcanic rocks (rhyolite and rhyolitic tuffs) in the East Kunlun Orogenic Belt (EKOB). These rocks give a small age window of 228-218 Ma. The mafic dikes represent evolved alkaline basaltic melts intruding ~ 8-9 Myrs older and volumetrically more abundant A-type granite batholith. Their rare earth element (REE) and multi-element patterns are similar to those of the present-day ocean island basalts (OIBs) except for a weak continental crustal signature (i.e., enrichment of Rb and Pb and weak depletion of Nb, Ta and Ti). Their trace element characteristics together with the high 87Sr/86Sr (0.7076-0.7104), low εNd(t) (- 2.18 to - 3.46), low εHf(t) (- 2.85 to - 4.59) and variable Pb isotopic ratios are consistent with melts derived from metasomatized subcontinental lithospheric mantle with crustal contamination. The felsic volcanic rocks are characterized by high LREE/HREE (e.g., [La/Yb]N of 5.71-17.00) with a negative Eu anomaly and strong depletion in Sr and P, resembling the model upper continental crust (UCC). Given the high 87Sr/86Sr (0.7213-0.7550) and less negative εNd(t) (- 3.83 to - 5.09) and εHf(t) (- 3.06 to - 3.83) than the UCC plus the overlapping isotopes with the mafic dikes and high Nb-Ta rhyolites, the felsic volcanic rocks are best interpreted as resulting from melting-induced mixing with 45-50% crustal materials and 50-55% mantle-derived mafic melts probably parental to the mafic dikes. Such mantle-derived melts underplated and intruded the deep crust as juvenile crustal materials. Partial melting of such juvenile crust produced felsic melts parental to the felsic volcanic rocks in the EKOB. We hypothesize that the late Triassic mafic dikes and felsic volcanic rocks are associated with post-collisional extension and related orogenic collapse. Such processes are probably significant in causing asthenospheric upwelling, decompression melting, induced melting of the prior metasomatized mantle lithosphere and the existing crust. This work represents our ongoing effort in understanding the origin of the juvenile crust and continental crustal accretion through magmatism in the broad context of orogenesis from seafloor subduction to continental collision and to post-collisional processes.

Chronology of early Archaean granite-greenstone evolution in the Barberton Mountain Land, South Africa, based on precise dating by single zircon evaporation.

PubMed

Krüner, A; Byerly, G R; Lowe, D R

1991-04-01

We report precise 207Pb/206Pb single zircon evaporation ages for low-grade felsic metavolcanic rocks within the Onverwacht and Fig Tree Groups of the Barberton Greenstone Belt (BGB), South Africa, and from granitoid plutons bordering the belt. Dacitic tuffs of the Hooggenoeg Formation in the upper part of the Onverwacht Group yield ages between 3445 +/- 3 and 3416 +/- 5 Ma and contain older crustal components represented by a 3504 +/- 4 Ma old zircon xenocryst. Fig Tree dacitic tuffs and agglomerates have euhedral zircons between 3259 +/- 5 and 3225 +/- 3 Ma in age which we interpret to reflect the time of crystallization. A surprisingly complex xenocryst population in one sample documents ages from 3323 +/- 4 to 3522 +/- 4 Ma. We suspect that these xenocrysts were inherited, during the passage of the felsic melts to the surface, from various sources such as greenstones and granitoid rocks now exposed in the form of tonalite-trondhjemite plutons along the southern and western margins of the BGB, and units predating any of the exposed greenstone or intrusive rocks. Several of the granitoids along the southern margin of the belt have zircon populations with ages between 3490 and 3440 Ma. coeval with or slightly older than Onverwacht felsic volcanism, while the Kaap Valley pluton along the northwestern margin of the belt is coeval with Fig Tree dacitic volcanism. These results emphasize the comagmatic relationships between greenstone felsic volcanic units and the surrounding plutonic suites. Some of the volcanic plutonic units contain zircon xenocrysts older than any exposed rocks. These indicate the existence of still older units, possibly stratigraphically lower and older portions of the greenstone sequence itself, older granitoid intrusive rocks, or bodies of older, unrelated crustal material. Our data show that the Onverwacht and Fig Tree felsic units have distinctly different ages and therefore do not represent a single, tectonically repeated unit as proposed by others. Unlike the late Archaean Abitibi greenstone belt in Canada, which formed over about 30 Ma. exposed rocks in the BGB formed over a period of at least 220 Ma. The complex zircon populations encountered in this study imply that conventional multigrain zircon dating may not accurately identify the time of felsic volcanic activity in ancient greenstones. A surprising similarity in rock types, tectonic evolution, and ages of the BGB in the Kaapvaal craton of southern Africa and greenstones in the Pilbara Block of Western Australia suggests that these two terrains may have been part of a larger crustal unit in early Archaean times.

Ultrasonic characterization of granites obtained from industrial quarries of Extremadura (Spain).

PubMed

del Río, L M; López, F; Esteban, F J; Tejado, J J; Mota, M; González, I; San Emeterio, J L; Ramos, A

2006-12-22

The industry of ornamental rocks, such as granites, represents one of the most important industrial activities in the region of Extremadura, SW Spain. A detailed knowledge of the intrinsic properties of this natural stone and its environmental evolution is a required goal in order to fully characterize its quality. In this work, two independent NDT acoustic techniques have been used to measure the acoustic velocity of longitudinal waves in different prismatic granitic-samples of industrial quarries. A low-frequency transceiver set-up, based on a high-voltage BPV Steinkamp instrument and two 50 kHz probes, has been used to measure pulse travel times by ultrasonic through-transmission testing. In complementary fashion, an Erudite MK3 test equipment with an electromagnetic vibrator and two piezoelectric sensors has also been employed to measure ultrasonic velocity by means of a resonance-based method, using the same types of granite varieties. In addition, a comprehensive set of physical/mechanical properties have also been analyzed, according to Spanish regulations in force, by means of alternative methods including destructive techniques such as strength, porosity, absorption, etc. A large number of samples, representing the most important varieties of granites from quarries of Extremadura, have been analyzed using the above-mentioned procedures. Some results obtained by destructive techniques have been correlated with those found using ultrasonic techniques. Our experimental setting allowed a complementary characterization of granite samples and a thorough validation of the different techniques employed, thus providing the industry of ornamental rocks with a non-destructive tool that will facilitate a more detailed insight on the properties of the rocks under study.

Geology and metallogeny of the Ar Rayn terrane, eastern Arabian shield: Evolution of a Neoproterozoic continental-margin arc during assembly of Gondwana within the East African orogen

USGS Publications Warehouse

Doebrich, J.L.; Al-Jehani, A. M.; Siddiqui, A.A.; Hayes, T.S.; Wooden, J.L.; Johnson, P.R.

2007-01-01

The Neoproterozoic Ar Rayn terrane is exposed along the eastern margin of the Arabian shield. The terrane is bounded on the west by the Ad Dawadimi terrane across the Al Amar fault zone (AAF), and is nonconformably overlain on the east by Phanerozoic sedimentary rocks. The terrane is composed of a magmatic arc complex and syn- to post-orogenic intrusions. The layered rocks of the arc, the Al Amar group (>689 Ma to ???625 Ma), consist of tholeiitic to calc-alkaline basaltic to rhyolitic volcanic and volcaniclastic rocks with subordinate tuffaceous sedimentary rocks and carbonates, and are divided into an eastern and western sequence. Plutonic rocks of the terrane form three distinct lithogeochemical groups: (1) low-Al trondhjemite-tonalite-granodiorite (TTG) of arc affinity (632-616 Ma) in the western part of the terrane, (2) high-Al TTG/adakite of arc affinity (689-617 Ma) in the central and eastern part of the terrane, and (3) syn- to post-orogenic alkali granite (607-583 Ma). West-dipping subduction along a trench east of the terrane is inferred from high-Al TTG/adakite emplaced east of low-Al TTG. The Ar Rayn terrane contains significant resources in epithermal Au-Ag-Zn-Cu-barite, enigmatic stratiform volcanic-hosted Khnaiguiyah-type Zn-Cu-Fe-Mn, and orogenic Au vein deposits, and the potential for significant resources in Fe-oxide Cu-Au (IOCG), and porphyry Cu deposits. Khnaiguiyah-type deposits formed before or during early deformation of the Al Amar group eastern sequence. Epithermal and porphyry deposits formed proximal to volcanic centers in Al Amar group western sequence. IOCG deposits are largely structurally controlled and hosted by group-1 intrusions and Al Amar group volcanic rocks in the western part of the terrane. Orogenic gold veins are largely associated with north-striking faults, particularly in and near the AAF, and are presumably related to amalgamation of the Ar Rayn and Ad Dawadimi terranes. Geologic, structural, and metallogenic characteristics of the Ar Rayn terrane are analogous to the Andean continental margin of Chile, with opposite subduction polarity. The Ar Rayn terrane represents a continental margin arc that lay above a west-dipping subduction zone along a continental block represented by the Afif composite terrane. The concentration of epithermal, porphyry Cu and IOCG mineral systems, of central arc affiliation, along the AAF suggests that the AAF is not an ophiolitic suture zone, but originated as a major intra-arc fault that localized magmatism and mineralization. West-directed oblique subduction and ultimate collision with a land mass from the east (East Gondwana?) resulted in major transcurrent displacement along the AAF, bringing the eastern part of the arc terrane to its present exposed position, juxtaposed across the AAF against a back-arc basin assemblage represented by the Abt schist of the Ad Dawadimi terrane. Our findings indicate that arc formation and accretionary processes in the Arabian shield were still ongoing into the latest Neoproterozoic (Ediacaran), to about 620-600 Ma, and lead us to conclude that evolution of the Ar Rayn terrane (arc formation, accretion, syn- to postorogenic plutonism) defines a final stage of assembly of the Gondwana supercontinent along the northeastern margin of the East African orogen. ?? 2007 Elsevier B.V. All rights reserved.

Preliminary geologic map of the Bowen Mountain quadrangle, Grand and Jackson Counties, Colorado

USGS Publications Warehouse

Cole, James C.; Braddock, William A.; Brandt, Theodore R.

2011-01-01

The map shows the geology of an alpine region in the southern Never Summer Mountains, including parts of the Never Summer Wilderness Area, the Bowen Gulch Protection Area, and the Arapaho National Forest. The area includes Proterozoic crystalline rocks in fault contact with folded and overturned Paleozoic and Mesozoic sedimentary rocks and Upper Cretaceous(?) and Paleocene Middle Park Formation. The folding and faulting appears to reflect a singular contractional deformation (post-Middle Park, so probably younger than early Eocene) that produced en echelon structural uplift of the Proterozoic basement of the Front Range. The geologic map indicates there is no through-going \\"Never Summer thrust\\" fault in this area. The middle Tertiary structural complex was intruded in late Oligocene time by basalt, quartz latite, and rhyolite porphyry plugs that also produced minor volcanic deposits; these igneous rocks are collectively referred to informally as the Braddock Peak intrusive-volcanic complex whose type area is located in the Mount Richthofen quadrangle immediately north (Cole and others, 2008; Cole and Braddock, 2009). Miocene boulder gravel deposits are preserved along high-altitude ridges that probably represent former gravel channels that developed during uplift and erosion in middle Tertiary time.

The oldest rock of Ivory Coast

NASA Astrophysics Data System (ADS)

Kouamelan, Alain Nicaise; Djro, Sagbrou Chérubin; Allialy, Marc Ephrem; Paquette, Jean-Louis; Peucat, Jean-Jacques

2015-03-01

The tonalitic gneiss of Balmer (TGB), in the SASCA area of south-western Ivory Coast, previously dated at 3141 ± 2 Ma using the single zircon evaporation method, is regarded as a relic of Archean rock within the Paleoproterozoic (Birimian) formation of the West African Craton (WAC). We present new geochronological data for the TGB using the laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) method. We obtain a U-Pb age of 3207 ± 7 Ma for abundant zircons extracted from the tonalitic gneiss, and interpret this age as that of the magmatic protolith because of the igneous-type homogeneous zircon population. Certain magmatic zircon edges and some round zircons define an upper intercept age of 3155 ± 17 Ma which could represent overgrowths during gneissification. It appears that the TGB was not affected by the events posterior to its genesis, i.e. the Liberian (2.9-2.7 Ga) and Eburnean (2.4-2.0 Ga) events. Additionally, the TGB proves to be a juvenile Leonian rock, as indicated by the Nd model age of 3456 Ma, and could also constitute the protolith of the granulitic grey gneisses and charnockites of the Man area, which are 150-400 Ma younger.

The mafic-ultramafic complex of Aniyapuram, Cauvery Suture Zone, southern India: Petrological and geochemical constraints for Neoarchean suprasubduction zone tectonics

NASA Astrophysics Data System (ADS)

Yellappa, T.; Venkatasivappa, V.; Koizumi, T.; Chetty, T. R. K.; Santosh, M.; Tsunogae, T.

2014-12-01

Several Precambrian mafic-ultramafic complexes occur along the Cauvery Suture Zone (CSZ) in Southern Granulite Terrain, India. Their origin, magmatic evolution and relationship with the associated high-grade rocks have not been resolved. The Aniyapuram Mafic-Ultramafic Complex (AMUC), the focus of the present study in southern part of the CSZ, is dominantly composed of peridotites, pyroxenites, gabbros, metagabbros/mafic granulites, hornblendites, amphibolites, plagiogranites, felsic granulites and ferruginous cherts. The rock types in the AMUC are structurally emplaced within hornblende gneiss (TTG) basement rocks and are highly deformed. The geochemical signature of the amphibolites indicates tholeiitic affinity for the protolith with magma generation in island arc-setting. N-MORB normalized pattern of the amphibolites show depletion in HFS-elements (P, Zr, Sm, Ti, and Y) and enrichment of LIL-elements (Rb, Ba, Th, Sr) with negative Nb anomalies suggesting involvement of subduction component in the depleted mantle source and formation in a supra-subduction zone tectonic setting. Our new results when correlated with the available age data suggest that the lithological association of AMUC represent the remnants of the Neoarchean oceanic lithosphere.

The Accotink Schist, Lake Barcroft Metasandstone, and Popes Head Formation; keys to an understanding of the tectonic evolution of the northern Virginia Piedmont

USGS Publications Warehouse

Drake, Avery Ala; Lyttle, Peter T.

1981-01-01

The newly named Accotink Schist and Lake Barcroft Metasandstone of the Eastern Fairfax sequence are the structurally lowest metamorphic rocks in the northernmost Piedmont of Virginia. The Accotink consists of beds of pelitic schist that have thin basal intervals containing graded, very fine grained metasiltstone, as well as interbeds of metasandstone like that in the overlying Lake Barcroft Metasandstone. The unit is characterized by the Bouma turbidite sequences Te and Tde and can be assigned to turbidite facies D and E. The thickness of the Accotink is not known because its base is not exposed. The Accotink Schist grades up into the Lake Barcroft Metasandstone, which consists of two types of metasandstone. Type I metaarenite is quartzofeldspathic granofels which forms thick sequences of amalgamated beds that can best be described as belonging to the Bouma turbidite sequence Ta and to turbidite facies B 2 . Type II metagraywacke of the Lake Barcroft Metasandstone consists of micaceous metagraywacke in thin to medium beds, which can be described as belonging to the Buoma turbidite sequences Tabe and (or) Tae and to turbidite facies C. The Lake Barcroft Metasandstone appears to be about 400 m thick. It and the Accotink Schist are thought to represent a coarsening-upward sequence of an outer submarine-fan association of rocks. The Eastern Fairfax sequence is overlain by the Sykesville Formation. We believe that this contact is a movement surface upon which the Sykesville was emplaced by subaqueous sliding. The Sykesville contains isoclinally folded fragments, thought to be rip-ups, of Accotink and Lake Barcroft rocks. The Eastern Fairfax sequence is intruded by rocks of the Occoquan Granite batholith, which contains pendants of isoclinally folded schist and metagraywacke. Mter intrusion, the metasedimentary and plutonic rocks were folded together. Gamet and chlorite porphyroblasts within the Eastern Fairfax sequence appear to be related to the emplacement of the batholith. The minimum age of the Eastern Fairfax sequence is that of the Occoquan Granite batholith, currently thought to be about 560 m.y. The sequence, then, is considered to be of Early Cambrian age or older. The Accotink Schist and Lake Barcroft Metasandstone have some lithic similarity to the Loch Raven Schist and Oella Formation of Crowley (1976) of the Baltimore area, but a correlation is very uncertain at this time. The newly named Popes Head Formation overlies all other metasedimentary and transported meta-igneous rocks in northernmost Virginia west ofthe Occoquan Granite batholith and is intruded by the batholith. The Popes Head consists of a lower Old Mill Branch Metasiltstone Member and an upper Station Hills Phyllite Member. The Old Mill Branch consists largely of alternating coarser and finer grained strata that are mostly fine- to very fine grained, mineralogically quite mature graded metasiltstone, which can be described as belonging to Bouma turbidite sequence Tbde and (or) Tde, more rarely Tcde. The metasiltstone contains interbedded intervals in which both felsic and mafic metatuff contain pristine euhedral crystals of igneous minerals. We believe that the metatuff represents ash-fall deposits. The Old Mill Branch appears to be about 730 m thick. The Old Mill Branch grades up into the Station Hills Phyllite Member, which consists of thin- to medium-bedded pelitic phyllite and smaller amounts of very fine grained metasiltstone. The metasiltstone beds are graded, and many phyllite beds appear to have basal in- tervals containing graded, very fine grained metasiltstone. These beds can be described as belonging to Bouma turbidite sequence Tde. The Station Hills has intervals containing chlorite-rich phyllite, which probably represents mafic metatuff. No felsic metatuff has been recognized. The top of the Station Hills is not known, neither therefore, is its thickness. This unit appears to have a maximum thickness of about 300 m in northern

Nonlinear Spatial Inversion Without Monte Carlo Sampling

NASA Astrophysics Data System (ADS)

Curtis, A.; Nawaz, A.

2017-12-01

High-dimensional, nonlinear inverse or inference problems usually have non-unique solutions. The distribution of solutions are described by probability distributions, and these are usually found using Monte Carlo (MC) sampling methods. These take pseudo-random samples of models in parameter space, calculate the probability of each sample given available data and other information, and thus map out high or low probability values of model parameters. However, such methods would converge to the solution only as the number of samples tends to infinity; in practice, MC is found to be slow to converge, convergence is not guaranteed to be achieved in finite time, and detection of convergence requires the use of subjective criteria. We propose a method for Bayesian inversion of categorical variables such as geological facies or rock types in spatial problems, which requires no sampling at all. The method uses a 2-D Hidden Markov Model over a grid of cells, where observations represent localized data constraining the model in each cell. The data in our example application are seismic properties such as P- and S-wave impedances or rock density; our model parameters are the hidden states and represent the geological rock types in each cell. The observations at each location are assumed to depend on the facies at that location only - an assumption referred to as `localized likelihoods'. However, the facies at a location cannot be determined solely by the observation at that location as it also depends on prior information concerning its correlation with the spatial distribution of facies elsewhere. Such prior information is included in the inversion in the form of a training image which represents a conceptual depiction of the distribution of local geologies that might be expected, but other forms of prior information can be used in the method as desired. The method provides direct (pseudo-analytic) estimates of posterior marginal probability distributions over each variable, so these do not need to be estimated from samples as is required in MC methods. On a 2-D test example the method is shown to outperform previous methods significantly, and at a fraction of the computational cost. In many foreseeable applications there are therefore no serious impediments to extending the method to 3-D spatial models.

A new heat flux model for the Antarctic Peninsula incorporating spatially variable upper crustal radiogenic heat production

NASA Astrophysics Data System (ADS)

Burton-Johnson, A.; Halpin, J. A.; Whittaker, J. M.; Graham, F. S.; Watson, S. J.

2017-06-01

A new method for modeling heat flux shows that the upper crust contributes up to 70% of the Antarctic Peninsula's subglacial heat flux and that heat flux values are more variable at smaller spatial resolutions than geophysical methods can resolve. Results indicate a higher heat flux on the east and south of the Peninsula (mean 81 mW m-2) where silicic rocks predominate, than on the west and north (mean 67 mW m-2) where volcanic arc and quartzose sediments are dominant. While the data supports the contribution of heat-producing element-enriched granitic rocks to high heat flux values, sedimentary rocks can be of comparative importance dependent on their provenance and petrography. Models of subglacial heat flux must utilize a heterogeneous upper crust with variable radioactive heat production if they are to accurately predict basal conditions of the ice sheet. Our new methodology and data set facilitate improved numerical model simulations of ice sheet dynamics.