Sea ice and pollution-modulated changes in Greenland ice core methanesulfonate and bromine

NASA Astrophysics Data System (ADS)

Maselli, Olivia J.; Chellman, Nathan J.; Grieman, Mackenzie; Layman, Lawrence; McConnell, Joseph R.; Pasteris, Daniel; Rhodes, Rachael H.; Saltzman, Eric; Sigl, Michael

2017-01-01

Reconstruction of past changes in Arctic sea ice extent may be critical for understanding its future evolution. Methanesulfonate (MSA) and bromine concentrations preserved in ice cores have both been proposed as indicators of past sea ice conditions. In this study, two ice cores from central and north-eastern Greenland were analysed at sub-annual resolution for MSA (CH3SO3H) and bromine, covering the time period 1750-2010. We examine correlations between ice core MSA and the HadISST1 ICE sea ice dataset and consult back trajectories to infer the likely source regions. A strong correlation between the low-frequency MSA and bromine records during pre-industrial times indicates that both chemical species are likely linked to processes occurring on or near sea ice in the same source regions. The positive correlation between ice core MSA and bromine persists until the mid-20th century, when the acidity of Greenland ice begins to increase markedly due to increased fossil fuel emissions. After that time, MSA levels decrease as a result of declining sea ice extent but bromine levels increase. We consider several possible explanations and ultimately suggest that increased acidity, specifically nitric acid, of snow on sea ice stimulates the release of reactive Br from sea ice, resulting in increased transport and deposition on the Greenland ice sheet.

Recovering Paleo-Records from Antarctic Ice-Cores by Coupling a Continuous Melting Device and Fast Ion Chromatography.

PubMed

Severi, Mirko; Becagli, Silvia; Traversi, Rita; Udisti, Roberto

2015-11-17

Recently, the increasing interest in the understanding of global climatic changes and on natural processes related to climate yielded the development and improvement of new analytical methods for the analysis of environmental samples. The determination of trace chemical species is a useful tool in paleoclimatology, and the techniques for the analysis of ice cores have evolved during the past few years from laborious measurements on discrete samples to continuous techniques allowing higher temporal resolution, higher sensitivity and, above all, higher throughput. Two fast ion chromatographic (FIC) methods are presented. The first method was able to measure Cl(-), NO3(-) and SO4(2-) in a melter-based continuous flow system separating the three analytes in just 1 min. The second method (called Ultra-FIC) was able to perform a single chromatographic analysis in just 30 s and the resulting sampling resolution was 1.0 cm with a typical melting rate of 4.0 cm min(-1). Both methods combine the accuracy, precision, and low detection limits of ion chromatography with the enhanced speed and high depth resolution of continuous melting systems. Both methods have been tested and validated with the analysis of several hundred meters of different ice cores. In particular, the Ultra-FIC method was used to reconstruct the high-resolution SO4(2-) profile of the last 10,000 years for the EDML ice core, allowing the counting of the annual layers, which represents a key point in dating these kind of natural archives.

High-resolution Greenland ice core data show abrupt climate change happens in few years.

PubMed

Steffensen, Jørgen Peder; Andersen, Katrine K; Bigler, Matthias; Clausen, Henrik B; Dahl-Jensen, Dorthe; Fischer, Hubertus; Goto-Azuma, Kumiko; Hansson, Margareta; Johnsen, Sigfús J; Jouzel, Jean; Masson-Delmotte, Valérie; Popp, Trevor; Rasmussen, Sune O; Röthlisberger, Regine; Ruth, Urs; Stauffer, Bernhard; Siggaard-Andersen, Marie-Louise; Sveinbjörnsdóttir, Arny E; Svensson, Anders; White, James W C

2008-08-01

The last two abrupt warmings at the onset of our present warm interglacial period, interrupted by the Younger Dryas cooling event, were investigated at high temporal resolution from the North Greenland Ice Core Project ice core. The deuterium excess, a proxy of Greenland precipitation moisture source, switched mode within 1 to 3 years over these transitions and initiated a more gradual change (over 50 years) of the Greenland air temperature, as recorded by stable water isotopes. The onsets of both abrupt Greenland warmings were slightly preceded by decreasing Greenland dust deposition, reflecting the wetting of Asian deserts. A northern shift of the Intertropical Convergence Zone could be the trigger of these abrupt shifts of Northern Hemisphere atmospheric circulation, resulting in changes of 2 to 4 kelvin in Greenland moisture source temperature from one year to the next.

Bipolar volcanic events in ice cores and the Toba eruption at 74 ka BP (Invited)

NASA Astrophysics Data System (ADS)

Svensson, A.

2013-12-01

Acidity spikes in Greenland and Antarctic ice cores are applied as tracers of past volcanic activity. Besides providing information on the timing and magnitude of past eruptions, the acidity spikes are also widely used for synchronization of ice cores. All of the deep Greenland ice cores are thus synchronized throughout the last glacial cycle based on volcanic markers. Volcanic matching of ice cores from the two Hemispheres is much more challenging but it is feasible in periods of favourable conditions. Over the last two millennia, where ice cores are precisely dated, some 50 bipolar volcanic events have thus been identified. In order for an eruption to express a bipolar fingerprint it generally needs to be a low latitude eruption with stratospheric injection. Sometimes tephra is associated with the ice-core acidity spikes, but most often there is no tephra present in the ice. As yet, an unknown eruption occurring in 1259 AD is the only event reported to have deposited tephra in both Greenland and Antarctica. During the last glacial period bipolar volcanic matching is very challenging and very little work has been done, but recent high-resolution ice core records have the potential to provide bipolar ice core matching for some periods. Recently, Greenland and Antarctic ice cores have been linked by acidity spikes in the time window of the most recent eruption (the YTT eruption) of the Indonesian Toba volcano that is situated close to equator in Sumatra. Ash from this Toba event is widespread over large areas in Asia and has been identified as far west as Africa, but no corresponding tephra has been found in polar ice cores despite several attempts. The age of the YTT eruption is well constrained by recent Ar-Ar dating to have occurred some 74 ka ago close to the Marine Isotope Stage 4/5 boundary and close to the onset of the cold Greenland Stadial 20 and the corresponding mild Antarctic Isotopic Maxima 19 and 20. Surprisingly, no single outstanding acidity spike can be associated with the YTT Toba eruption in Greenland or Antarctica. Instead, several large bipolar ice cores acidity spikes are occurring within a couple of centuries at the time of the YTT eruption. To complicate matters, the intensity of those acidity spikes varies greatly from ice core to ice core. At this point, it is therefore impossible to relate the Toba eruption to a single event in the ice cores. Probably there have been several large low-latitude eruptions occurring close to the time of the YTT or the Toba volcano itself had multiple large eruptions within centuries. Bipolar volcanic matching allows for an estimation of the climatic impact of eruptions on a global scale. In the case of Toba, there must have been a global cooling following the enormous eruption, but unfortunately at this depth the resolution of the ice core temperature proxies does not allow for an identification of short term events (<100 yr). A significant warming event in Antarctica following the period associated with the YTT shows, however, that Toba did not initiate a long-term global cooling (>100 yr). At the time of YTT it appears that the inter-hemispheric climate variability is governed by the bipolar seesaw pattern that is active throughout most of the last glacial period. Still, it is intriguing that Toba occurs right at the time when Greenland and much of the northern Hemisphere enters its most extreme cold stadial of the last glacial period.

An automated approach for annual layer counting in ice cores

NASA Astrophysics Data System (ADS)

Winstrup, M.; Svensson, A.; Rasmussen, S. O.; Winther, O.; Steig, E.; Axelrod, A.

2012-04-01

The temporal resolution of some ice cores is sufficient to preserve seasonal information in the ice core record. In such cases, annual layer counting represents one of the most accurate methods to produce a chronology for the core. Yet, manual layer counting is a tedious and sometimes ambiguous job. As reliable layer recognition becomes more difficult, a manual approach increasingly relies on human interpretation of the available data. Thus, much may be gained by an automated and therefore objective approach for annual layer identification in ice cores. We have developed a novel method for automated annual layer counting in ice cores, which relies on Bayesian statistics. It uses algorithms from the statistical framework of Hidden Markov Models (HMM), originally developed for use in machine speech recognition. The strength of this layer detection algorithm lies in the way it is able to imitate the manual procedures for annual layer counting, while being based on purely objective criteria for annual layer identification. With this methodology, it is possible to determine the most likely position of multiple layer boundaries in an entire section of ice core data at once. It provides a probabilistic uncertainty estimate of the resulting layer count, hence ensuring a proper treatment of ambiguous layer boundaries in the data. Furthermore multiple data series can be incorporated to be used at once, hence allowing for a full multi-parameter annual layer counting method similar to a manual approach. In this study, the automated layer counting algorithm has been applied to data from the NGRIP ice core, Greenland. The NGRIP ice core has very high temporal resolution with depth, and hence the potential to be dated by annual layer counting far back in time. In previous studies [Andersen et al., 2006; Svensson et al., 2008], manual layer counting has been carried out back to 60 kyr BP. A comparison between the counted annual layers based on the two approaches will be presented and their differences discussed. Within the estimated uncertainties, the two methodologies agree. This shows the potential for a fully automated annual layer counting method to be operational for data sections where the annual layering is unknown.

Changes of the Bacterial Abundance and Communities in Shallow Ice Cores from Dunde and Muztagata Glaciers, Western China

PubMed Central

Chen, Yong; Li, Xiang-Kai; Si, Jing; Wu, Guang-Jian; Tian, Li-De; Xiang, Shu-Rong

2016-01-01

In this study, six bacterial community structures were analyzed from the Dunde ice core (9.5-m-long) using 16S rRNA gene cloning library technology. Compared to the Muztagata mountain ice core (37-m-long), the Dunde ice core has different dominant community structures, with five genus-related groups Blastococcus sp./Propionibacterium, Cryobacterium-related., Flavobacterium sp., Pedobacter sp., and Polaromas sp. that are frequently found in the six tested ice layers from 1990 to 2000. Live and total microbial density patterns were examined and related to the dynamics of physical-chemical parameters, mineral particle concentrations, and stable isotopic ratios in the precipitations collected from both Muztagata and Dunde ice cores. The Muztagata ice core revealed seasonal response patterns for both live and total cell density, with high cell density occurring in the warming spring and summer months indicated by the proxy value of the stable isotopic ratios. Seasonal analysis of live cell density for the Dunde ice core was not successful due to the limitations of sampling resolution. Both ice cores showed that the cell density peaks were frequently associated with high concentrations of particles. A comparison of microbial communities in the Dunde and Muztagata glaciers showed that similar taxonomic members exist in the related ice cores, but the composition of the prevalent genus-related groups is largely different between the two geographically different glaciers. This indicates that the micro-biogeography associated with geographic differences was mainly influenced by a few dominant taxonomic groups. PMID:27847503

The WAIS Melt Monitor: An automated ice core melting system for meltwater sample handling and the collection of high resolution microparticle size distribution data

NASA Astrophysics Data System (ADS)

Breton, D. J.; Koffman, B. G.; Kreutz, K. J.; Hamilton, G. S.

2010-12-01

Paleoclimate data are often extracted from ice cores by careful geochemical analysis of meltwater samples. The analysis of the microparticles found in ice cores can also yield unique clues about atmospheric dust loading and transport, dust provenance and past environmental conditions. Determination of microparticle concentration, size distribution and chemical makeup as a function of depth is especially difficult because the particle size measurement either consumes or contaminates the meltwater, preventing further geochemical analysis. Here we describe a microcontroller-based ice core melting system which allows the collection of separate microparticle and chemistry samples from the same depth intervals in the ice core, while logging and accurately depth-tagging real-time electrical conductivity and particle size distribution data. This system was designed specifically to support microparticle analysis of the WAIS Divide WDC06A deep ice core, but many of the subsystems are applicable to more general ice core melting operations. Major system components include: a rotary encoder to measure ice core melt displacement with 0.1 millimeter accuracy, a meltwater tracking system to assign core depths to conductivity, particle and sample vial data, an optical debubbler level control system to protect the Abakus laser particle counter from damage due to air bubbles, a Rabbit 3700 microcontroller which communicates with a host PC, collects encoder and optical sensor data and autonomously operates Gilson peristaltic pumps and fraction collectors to provide automatic sample handling, melt monitor control software operating on a standard PC allowing the user to control and view the status of the system, data logging software operating on the same PC to collect data from the melting, electrical conductivity and microparticle measurement systems. Because microparticle samples can easily be contaminated, we use optical air bubble sensors and high resolution ice core density profiles to guide the melting process. The combination of these data allow us to analyze melt head performance, minimize outer-to-inner fraction contamination and avoid melt head flooding. The WAIS Melt Monitor system allows the collection of real-time, sub-annual microparticle and electrical conductivity data while producing and storing enough sample for traditional Coulter-Counter particle measurements as well long term acid leaching of bioactive metals (e.g., Fe, Co, Cd, Cu, Zn) prior to chemical analysis.

High-resolution 129I bomb peak profile in an ice core from SE-Dome site, Greenland.

PubMed

Bautista, Angel T; Miyake, Yasuto; Matsuzaki, Hiroyuki; Iizuka, Yoshinori; Horiuchi, Kazuho

2018-04-01

129 I in natural archives, such as ice cores, can be used as a proxy for human nuclear activities, age marker, and environmental tracer. Currently, there is only one published record of 129 I in ice core (i.e., from Fiescherhorn Glacier, Swiss Alps) and its limited time resolution (1-2 years) prevents the full use of 129 I for the mentioned applications. Here we show 129 I concentrations in an ice core from SE-Dome, Greenland, covering years 1956-1976 at a time resolution of ∼6 months, the most detailed record to date. Results revealed 129 I bomb peaks in years 1959, 1962, and 1963, associated to tests performed by the former Soviet Union, one year prior, in its Novaya Zemlya test site. All 129 I bomb peaks were observed in winter (1958.9, 1962.1, and 1963.0), while tritium bomb peaks, another prominent radionuclide associated with nuclear bomb testing, were observed in spring or summer (1959.3, and 1963.6; Iizuka et al., 2017). These results indicate that 129 I bomb peaks can be used as annual and seasonal age markers for these years. Furthermore, we found that 129 I recorded nuclear fuel reprocessing signals and that these can be potentially used to correct timing of estimated 129 I releases during years 1964-1976. Comparisons with other published records of 129 I in natural archives showed that 129 I can be used as common age marker and tracer for different types of records. Most notably, the 1963 129 I bomb peak can be used as common age marker for ice and coral cores, providing the means to reconcile age models and associated trends from the polar and tropical regions, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

Siple Dome ice reveals two modes of millennial CO2 change during the last ice age

PubMed Central

Ahn, Jinho; Brook, Edward J.

2014-01-01

Reconstruction of atmospheric CO2 during times of past abrupt climate change may help us better understand climate-carbon cycle feedbacks. Previous ice core studies reveal simultaneous increases in atmospheric CO2 and Antarctic temperature during times when Greenland and the northern hemisphere experienced very long, cold stadial conditions during the last ice age. Whether this relationship extends to all of the numerous stadial events in the Greenland ice core record has not been clear. Here we present a high-resolution record of atmospheric CO2 from the Siple Dome ice core, Antarctica for part of the last ice age. We find that CO2 does not significantly change during the short Greenlandic stadial events, implying that the climate system perturbation that produced the short stadials was not strong enough to substantially alter the carbon cycle. PMID:24781344

High resolution and high precision on line isotopic analysis of Holocene and glacial ice performed in the field

NASA Astrophysics Data System (ADS)

Gkinis, V.; Popp, T. J.; Johnsen, S. J.; Blunier, T.; Bigler, M.; Stowasser, C.; Schüpbach, S.; Leuenberger, D.

2010-12-01

Ice core records as obtained from polar ice caps provide a wealth of paleoclimatic information. One of the main features of ice cores is their potential for high temporal resolution. The isotopic signature of the ice, expressed through the relative abundances of the two heavy isotopologues H218O and HD16O, is a widely used proxy for the reconstruction of past temperature and accumulation. One step further the combined information obtained from these two isotopologues, commonly referred to as the deuterium excess, can be utilized to infer additional information about the source of the precipitated moisture. Until very recently isotopic analysis of polar ice was performed with isotope Ratio Mass Spectrometry (IRMS) in a discrete fashion resulting in a high workload related to the preparation of samples. Most important though the available temporal resolution of the ice core was in many cases not fully exploited. In order to overcome these limitations we have developed a system that interfaces a commercially available IR laser cavity ring-down spectrometer tailored for water isotope analysis to a stream of liquid water as extracted from a continuously melted ice rod. The system offers the possibility for simultaneous δ18O and δD analysis with a sample requirement of approximately 0.1 ml/min. The system has been deployed in the field during the NEEM ice core drilling project on 2009 and 2010. In this study we present actual on line measurements of Holocene and glacial ice. We also discuss how parameters as the melt rate, acquisition rate and integration time affect the obtained precision and resolution and we describe data analysis techniques that can improve these last two parameters. By applying spectral methods we are able to quantify the smoothing effects imposed by diffusion of the sample in the sample transfer lines and the optical cavity of the instrument. We demonstrate that with an acquisition rate of 0.2 Hz we are able to obtain a precision of 0.5‰ and 0.15‰ for δD and δ18O respectively. This is comparable to the performance of traditional IRMS systems for δD but slightly less precise for δ18O. With this acquisition rate the system’s 3db bandwidth is 0.006 Hz. With a melt rate equal to 3 cm/min, the latter translates to signals with wavelengths of 8.3 cm. We will comment on the quality of the acquired ice core data and their potential use for dating, paleotemperature reconstruction, isotopic firn diffusion and deuterium excess studies.

First continuous flow analysis results from the Greenland ReCAP project

NASA Astrophysics Data System (ADS)

Kjær, Helle Astrid

2016-04-01

The new Renland ice core was drilled in summer 2015 in Greenland and measured by means of Continuous flow analysis during the last 3 months of 2015. The Renland ice core was obtained as part of the ReCAP project, extending 584.11 meters to the bottom of the Renland ice cap located in east Greenland. The unique position on a mountain saddle above 2000 meters altitude, but close to the coast, ensures that the Renland ice core offers high accumulation, but also reaches far back in time. Preliminary results show that the record holds ice from the past warm interglacial period, the Eemian. The record was analyzed for multiple elements including the forest fire tracers NH4+ and black carbon, insoluble dust particles by means of Abakus laser particle counter and the dust ion Ca2+, sea salt Na and acidity useful for finding volcanic layers to date the core. Further H2O2, and the nutrients Fe and dissolved reactive phosphorus was analyzed as well as the temperature indicator δ18O all by means of continuous flow analysis (CFA). The core was melted at a rate of 3 cm/min providing a temporal resolution for most components determined sufficient to resolve annual layers through the Holocene. The glacial section is strongly thinned, but nonetheless due to the high resolution of the measurements all DO events could be identified. Below the glacial section another ˜20 meters of warm Eemian ice have been analysed. Here we present the first chemistry results as obtained by continuous flow analysis (CFA).

Leads and lags between the Antarctic temperature and carbon dioxide during the last deglaciation

NASA Astrophysics Data System (ADS)

Gest, Léa; Parrenin, Frédéric; Raynaud, Dominique; Fudge, Tyler J.

2017-04-01

To understand causal relationships in past climate variations, it is essential to have accurate chronologies of paleoclimate records. Ice cores in Antarctica provide important paleoclimate variables, such as local temperature and global atmospheric CO2. Unfortunately, temperature is recorded in the ice while CO2 is recorded in the enclosed air bubbles. The ages of the former and of the latter are different since air is trapped at 50-120 m below the surface. For the last deglacial warming, 18,000 to 11,000 years ago, Parrenin et al. (Science, 2013) inferred that CO2 and Antarctic temperature started to increase in phase while CO2 lagged temperature at the beginning of the Holocene period. However, this study suffers from various uncertainties that we tried to address in the current study. First, Antarctic temperature was inferred from a stack of 5 Antarctic ice cores that were not always accurately synchronized. Here we use a stack of 4 Antarctic ice cores which are all accurately synchronized thanks to volcanic peak matching. Second, Parrenin et al. (Science, 2013) used a relatively low-resolution CO2 record from the EPICA Dome C ice core. Here, we use the more recent and higher resolution CO2 record from the West Antarctic Ice Sheet Divide ice core. Third, the air trapping depth was deduced on the low accumulation EPICA Dome C ice core using the gravitational enrichment of the δ15N isotopes and assuming a zero convective depth, a hypothesis that was not proved. Here, we use the higher accumulation WAIS Divide ice core, where the ice-air age shift is one order of magnitude smaller, and therefore better constrained. Finally, we use an improved mathematical method to infer break points in the Antarctic temperature and atmospheric CO2 records. We find that, at the onset of the last deglaciation and the onset of the Bølling-Allerød period, the phasing between CO2 and Antarctic temperature is negligible within a range of 130 years. Then CO2 slightly leads by 200 ± 90 years at the onset of the Younger-Dryas period. Finally, Antarctic temperature significantly leads by 460 ± 95 years at the onset of the Holocene period. Our results further supports the hypothesis of no convective zone at EPICA Dome C during the last deglaciation, as assumed by Parrenin et al. (Climate of the past, 2012, On the gas-ice depth difference (Delta depth) along the EPICA Dome C ice core)

A Method for Continuous (239)Pu Determinations in Arctic and Antarctic Ice Cores.

PubMed

Arienzo, M M; McConnell, J R; Chellman, N; Criscitiello, A S; Curran, M; Fritzsche, D; Kipfstuhl, S; Mulvaney, R; Nolan, M; Opel, T; Sigl, M; Steffensen, J P

2016-07-05

Atmospheric nuclear weapons testing (NWT) resulted in the injection of plutonium (Pu) into the atmosphere and subsequent global deposition. We present a new method for continuous semiquantitative measurement of (239)Pu in ice cores, which was used to develop annual records of fallout from NWT in ten ice cores from Greenland and Antarctica. The (239)Pu was measured directly using an inductively coupled plasma-sector field mass spectrometer, thereby reducing analysis time and increasing depth-resolution with respect to previous methods. To validate this method, we compared our one year averaged results to published (239)Pu records and other records of NWT. The (239)Pu profiles from the Arctic ice cores reflected global trends in NWT and were in agreement with discrete Pu profiles from lower latitude ice cores. The (239)Pu measurements in the Antarctic ice cores tracked low latitude NWT, consistent with previously published discrete records from Antarctica. Advantages of the continuous (239)Pu measurement method are (1) reduced sample preparation and analysis time; (2) no requirement for additional ice samples for NWT fallout determinations; (3) measurements are exactly coregistered with all other chemical, elemental, isotopic, and gas measurements from the continuous analytical system; and (4) the long half-life means the (239)Pu record is stable through time.

First investigations of an ice core from Eisriesenwelt cave (Austria)

NASA Astrophysics Data System (ADS)

May, B.; Spötl, C.; Wagenbach, D.; Dublyansky, Y.; Liebl, J.

2010-09-01

Investigations into the genesis and dynamical properties of cave ice are essential for assessing the climate significance of these underground glaciers. We drilled an ice core through a 7.1 m thick ice body filling a large cavern of the dynamic ice cave Eisenriesenwelt (Austria). In addition to visual core inspections, quasi-continuous measurements at 2 cm resolution comprised particulate matter, stable water isotope (δ18O, δD) and electrolytic conductivity profiles supplemented by specifically selected samples analysed for tritium and radiocarbon. We found that recent ablation led to an almost complete loss of bomb derived tritium removing any ice accumulated, since at least, the early fifties leaving the actual ice surface even below the natural tritium level. The small particulate organic masses made radiocarbon dating inconclusive, though a crude estimate gave a maximum ice age in the order of several thousand years. The visual stratigraphy and all investigated parameters showed a clear dichotomy between the upper 4 m and the bottom 3 m of the core, which points to a substantial change in the ice formation process. Main features of the core comprise the changing appearance and composition of distinct cyro-calcite layers, a extremely low total ion content and a surprisingly high variability of the isotope signature. Co-isotope evaluation (δD versus δ18O) of the core in comparison with data from precipitation and karst spring water clearly indicate that ice formation is governed by (slow) freezing of dripping water.

First investigations of an ice core from Eisriesenwelt cave (Austria)

NASA Astrophysics Data System (ADS)

May, B.; Spötl, C.; Wagenbach, D.; Dublyansky, Y.; Liebl, J.

2011-02-01

Investigations into the genesis and dynamical properties of cave ice are essential for assessing the climate significance of these underground glaciers. We drilled an ice core through a 7.1 m-thick ice body filling a large cavern of the dynamic ice cave Eisenriesenwelt (Austria). In addition to visual core inspections, quasi-continuous measurements at 2 cm resolution comprised particulate matter, stable water isotope (δ18O, δD) and electrolytic conductivity profiles supplemented by specifically selected samples analyzed for tritium and radiocarbon. We found that recent ablation led to an almost complete loss of bomb-derived tritium removing any ice accumulated since, at least, the early fifties leaving the actual ice surface even below the natural tritium level. The small particulate organic masses rendered radiocarbon dating inconclusive, though a crude estimate gave a basal ice age in the order of several thousand years. The visual stratigraphy and all investigated parameters showed a clear dichotomy between the upper 2 m and the bottom 3 m of the core, which points to a substantial change in the ice formation process. Main features of the core comprise the changing appearance and composition of distinct cryocalcite layers, extremely low total ion content and a surprisingly high variability of the isotope signature. Co-isotope evaluation (δD versus δ18O) of the core in comparison with data from precipitation and karst spring water clearly indicate that ice formation is governed by (slow) freezing of dripping water.

On the use of δ18Oatm for ice core dating

NASA Astrophysics Data System (ADS)

Extier, Thomas; Landais, Amaelle; Bréant, Camille; Prié, Frédéric; Bazin, Lucie; Dreyfus, Gabrielle; Roche, Didier M.; Leuenberger, Markus

2018-04-01

Deep ice core chronologies have been improved over the past years through the addition of new age constraints. However, dating methods are still associated with large uncertainties for ice cores from the East Antarctic plateau where layer counting is not possible. Indeed, an uncertainty up to 6 ka is associated with AICC2012 chronology of EPICA Dome C (EDC) ice core, which mostly arises from uncertainty on the delay between changes recorded in δ18Oatm and in June 21st insolation variations at 65°N used for ice core orbital dating. Consequently, we need to enhance the knowledge of this delay to improve ice core chronologies. We present new high-resolution EDC δ18Oatm record (153-374 ka) and δO2/N2 measurements (163-332 ka) performed on well-stored ice to provide continuous records of δ18Oatm and δO2/N2 between 100 and 800 ka. The comparison of δ18Oatm with the δ18Ocalcite from East Asian speleothems shows that both signals present similar orbital and millennial variabilities, which may represent shifts in the InterTropical Convergence Zone position, themselves associated with Heinrich events. We thus propose to use the δ18Ocalcite as target for δ18Oatm orbital dating. Such a tuning method improves the ice core chronology of the last glacial inception compared to AICC2012 by reconciling NGRIP and mid-latitude climatic records. It is especially marked during Dansgaard-Oeschger 25 where the proposed chronology is 2.2 ka older than AICC2012. This δ18Oatm - δ18Ocalcite alignment method applied between 100 and 640 ka improves the EDC ice core chronology, especially over MIS 11, and leads to lower ice age uncertainties compared to AICC2012.

Santa Barbara Basin Study Extends Global Climate Record

NASA Astrophysics Data System (ADS)

Hopkins, Sarah; Kennett, James; Nicholson, Craig; Pak, Dorothy; Sorlien, Christopher; Behl, Richard; Normark, William; Sliter, Ray; Hill, Tessa; Schimmelmann, Arndt; Cannariato, Kevin

2006-05-01

A fundamental goal of Earth science is to understand the remarkable instability of late Quarternary global climate prior to the beginning of the Holocene, about 11,000 years ago. This unusual climate behavior was characterized by millennial-scale climate oscillations on suborbital timescales, and a distinctive `Sawtooth' pattern of very abrupt glacial and stadial terminations (within decades) followed by more gradual global cooling [e.g., Dansgaard et al., 1993; Hendy and Kennett, 1999]. The fact that both major (glacial) and minor (stadial) cooling periods in Earth's climate were terminated by similar abrupt warming episodes suggests a common mechanism driving such rapid changes in global climate. Understanding the causes of this instability is crucial given developing concerns about global warming, yet knowledge about this climate behavior has been essentially confined to the last 150,000 years or so, owing to the absence of available sequences of sufficient age and chronological resolution. The high-resolution paleoclimate record from the Greenland ice cores is limited to about 110 thousand years ago (ka), and although Antarctic ice cores now extend back to more than 740 ka [European Project for Ice Coring in Antarctica, 2004], these latter cores primarily provide information about high-latitude conditions at much lower resolution than is required to address abrupt climate change.

Establishing a Reliable Depth-Age Relationship for the Denali Ice Core

NASA Astrophysics Data System (ADS)

Wake, C. P.; Osterberg, E. C.; Winski, D.; Ferris, D.; Kreutz, K. J.; Introne, D.; Dalton, M.

2015-12-01

Reliable climate reconstruction from ice core records requires the development of a reliable depth-age relationship. We have established a sub-annual resolution depth-age relationship for the upper 198 meters of a 208 m ice core recovered in 2013 from Mt. Hunter (3,900 m asl), Denali National Park, central Alaska. The dating of the ice core was accomplished via annual layer counting of glaciochemical time-series combined with identification of reference horizons from volcanic eruptions and atmospheric nuclear weapons testing. Using the continuous ice core melter system at Dartmouth College, sub-seasonal samples have been collected and analyzed for major ions, liquid conductivity, particle size and concentration, and stable isotope ratios. Annual signals are apparent in several of the chemical species measured in the ice core samples. Calcium and magnesium peak in the spring, ammonium peaks in the summer, methanesulfonic acid (MSA) peaks in the autumn, and stable isotopes display a strong seasonal cycle with the most depleted values occurring during the winter. Thin ice layers representing infrequent summertime melt were also used to identify summer layers in the core. Analysis of approximately one meter sections of the core via nondestructive gamma spectrometry over depths from 84 to 124 m identified a strong radioactive cesium-137 peak at 89 m which corresponds to the 1963 layer deposited during extensive atmospheric nuclear weapons testing. Peaks in the sulfate and chloride record have been used for the preliminary identification of volcanic signals preserved in the ice core, including ten events since 1883. We are confident that the combination of robust annual layers combined with reference horizons provides a timescale for the 20th century that has an error of less than 0.5 years, making calibrations between ice core records and the instrumental climate data particularly robust. Initial annual layer counting through the entire 198 m suggests the Denali Ice Core record will span the past 1000 years.

High resolution water stable isotope profiles of abrupt climate transitions in Greenland ice with new observations from NEEM

NASA Astrophysics Data System (ADS)

Popp, T. J.; White, J. W. C.; Gkinis, V.; Vinther, B. M.; Johnsen, S. J.

2012-04-01

In 1989 Willi Dansgaard and others, using the DYE3 ice core, showed that the abrupt termination of the Younger Dryas expressed in water stable isotope ratios and deuterium excess was completed in less than 50 years. A few years later, using the GISP2 ice core, Richard Alley and others proposed that snow accumulation at the site doubled in as little as 1-3 years across the same climate transition at the end of the Younger Dryas. Over the next two decades, in large part due to such observations from Greenland ice cores, a paradigm of linked, abrupt changes in the North Atlantic region has been developed around North Atlantic deep water formation, North Atlantic sea ice extent, and widespread atmospheric circulation changes occurring repeatedly during the last glacial period in response to changing freshwater fluxes to the region, or perhaps other causes. More recently, with the NGRIP ice core, using a suite of high resolution proxy data, and in particular deuterium excess, it was observed again that certain features in the climate system can switch modes from one year to the next, while other proxies can take from decades to centuries to completely switch modes. Thus, an event seen in the proxy records such as the abrupt end of the Younger Dryas (or other interstadial events) may comprise multiple climatic or oceanic responses with different relative timing and duration which potentially follow a predictable sequence of events, in some cases separated by only a few years. Today, the search continues for these emerging patterns through isotopic and other highly resolvable proxy data series from ice cores. With the recent completion of the drilling at NEEM, many abrupt transitions have now been measured in detail over a geographic transect with drilling sites spanning from DYE3 in Southern Greenland, GISP2 in the central summit region, and up to NGRIP and NEEM in the far north. The anatomy of abrupt climate transitions can therefore be examined both spatially and temporally, where obtaining the highest possible temporal resolution is desirable to resolve patterns. A new method for measuring water stable isotope ratios has been developed during the NEEM project that allows us to measure a carefully controlled fraction of a continuously melted ice core section which is evaporated directly into Cavity Ring Down Laser Spectrometer in the Near-Infrared spectrum. In such a system the resolution can be maximized (and characterized) largely as a function of both the melt rate and minimizing subsequent mixing in the gas phase during analysis. These new detailed water isotope series from the NEEM ice core are examined with respect to the corresponding series from new and previously available series from the other ice cores. The emerging picture indicates that abrupt climate changes have both a temporal and geographic anatomy that can change from one event to the next in how they are recorded across Greenland. Together with modeling and chemical impurity data, these patterns we detect in the water stable isotope series will provide clues and constraints to the timing and origin of oceanic and atmospheric changes that make up an abrupt climate change.

Non-Target Analyses of organic compounds in ice cores using HPLC-ESI-UHRMS

NASA Astrophysics Data System (ADS)

Zuth, Christoph; Müller-Tautges, Christina; Eichler, Anja; Schwikowski, Margit; Hoffmann, Thorsten

2015-04-01

To study the global climatic and environmental changes it is necessary to know the environmental and especially atmospheric conditions of the past. By analysing climate archives, such as for example ice cores, unique environmental information can be obtained. In contrast to the well-established analysis of inorganic species in ice cores, organic compounds have been analysed in ice cores to a much smaller extent. Because of current analytical limitations it has become commonplace to focus on 'total organic carbon' measurements or specific classes of organic molecules, as no analytical methods exist that can provide a broad characterization of the organic material present[1]. On the one hand, it is important to focus on already known atmospheric markers in ice cores and to quantify, where possible, in order to compare them to current conditions. On the other hand, unfortunately a wealth of information is lost when only a small fraction of the organic material is examined. However, recent developments in mass spectrometry in respect to higher mass resolution and mass accuracy enable a new approach to the analysis of complex environmental samples. The qualitative characterization of the complex mixture of water soluble organic carbon (WSOC) in the ice using high-resolution mass spectrometry allows for novel insights concerning the composition and possible sources of aerosol derived WSOC deposited at glacier sites. By performing a non-target analysis of an ice core from the Swiss Alps using previous enrichment by solid-phase extraction (SPE) and high performance liquid chromatography coupled to electrospray ionization and ultra-high resolution mass spectrometry (HPLC-ESI-UHRMS) 475 elemental formulas distributed onto 659 different peaks were detected. The elemental formulas were classified according to their elemental composition into CHO-, CHON-, CHOS-, CHONS-containing compounds and 'others'. Several methods for the analysis of complex data sets of high resolution mass spectrometry were applied to the results of the non-target analysis. By various classifications in Van Krevelen plots[2], amino acids and degradation products of proteins as well as degradation products of lignins have been determined as the main components of the ice core. Furthermore, the majority of WSOC molecular formulas identified in this non-target analysis had molar H/C and O/C ratios similar to mono- and di-carboxylic acids and SOAs[3]. Studies of the carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol showed that a majority of the elemental formulas can be associated with the combustion of biomass as a major source of the WSOC[4]. References: [1] Grannas et al., J. Geophys Res.,2006, 111 [2] Sleighter, RL, Hatcher, PG, J. Mass Spectrom., 2007, 42, 559-574 [3] Wozniak et al., Atmos. Chem. Phys., 2008, 8, 5099-5111 [4] Kroll et al., Nature Chemistry, 2011, 3, 133-139

Historic CH4 Records from Antarctic and Greenland Ice Cores, Antarctic Firn Data, and Archived Air Samples from Cape Grim, Tasmania

DOE Data Explorer

Etheridge, D. M. [Division of Atmospheric Research, CSIRO, Aspendale, Victoria, Australia; Steele, L. P. [Division of Atmospheric Research, CSIRO, Aspendale, Victoria, Australia; Francey, R. J. [Division of Atmospheric Research, CSIRO, Aspendale, Victoria, Australia; Langenfelds, R. L. [Division of Atmospheric Research, CSIRO, Aspendale, Victoria, Australia

2002-01-01

The Antarctic CH4 records presented here are derived from three ice cores obtained at Law Dome, East Antarctica (66°44'S, 112°50'E, 1390 meters above mean sea level). Law Dome has many qualities of an ideal ice core site for the reconstruction of past concentrations of atmospheric gases; these qualities include: negligible melting of the ice sheet surface, low concentrations of impurities, regular stratigraphic layering undisturbed by wind stress at the surface or differential ice flow at depth, and a high snow accumulation rate. Further details on the site, drilling, and cores are provided by Etheridge et al. (1998), Etheridge et al. (1996), Etheridge and Wookey (1989), and Morgan et al. (1997). The two Greenland ice cores are from the Summit region (72°34' N, 37°37' W, 3200 meters above mean sea level). Lower snow accumulation rate there results in lower air-age resolution, and measurements presented here cover only the pre-industrial period (until 1885). More details about these measurements are presented in Etheridge et al. (1998). Additionally, this site contains firn data from Core DE08-2, and archived air samples from Cape Grim, Tasmania, for comparison.

The Late Holocene Atmospheric Methane Budget Reconstructed from Ice Cores

NASA Astrophysics Data System (ADS)

Mitchell, Logan E.

In this thesis I used a newly developed methane measurement line to make high-resolution, high-precision measurements of methane during the late Holocene (2800 years BP to present). This new measurement line is capable of an analytical precision of < 3 ppb using ˜120 g samples. The reduced sample size requirements as well as automation of a significant portion of the analysis process have enabled me to make >1500 discrete ice core methane measurements and construct the highest resolution records of methane available over the late Holocene. I first used a shallow ice core from WAIS Divide (WDC05A) to produce a 1000 year long methane record with a ˜9 year temporal resolution. This record confirmed the existence of multidecadal scale variations that were first observed in the Law Dome, Antarctica ice core. I then explored a range of paleoclimate archives for possible mechanistic connections with methane concentrations on multidecadal timescales. In addition, I present a detailed description of the analytical methods used to obtain high-precision measurements of methane including the effects of solubility and a new chronology for the WDC05A ice core. I found that, in general, the correlations with paleoclimate proxies for temperature and precipitation were low over a range of geographic regions. Of these, the highest correlations were found from 1400-1600 C.E. during the onset of the Little Ice Age and with a drought index in the headwater region of the major East Asian rivers. Large population losses in Asia and the Americas are also coincident with methane concentration decreases indicating that anthropogenic activities may have been impacting multidecadal scale methane variability. In the second component I extended the WAIS Divide record back to 2800 years B.P. and also measured methane from GISP2D over this time interval. These records allowed me to examine the methane Inter-Polar Difference (IPD) which is created by greater northern hemispheric sources. The IPD provides an important constraint on changes in the latitudinal distribution of sources. We used this constraint and an 8-box global methane chemical transport model to examine the Early Anthropogenic Hypothesis which posits that humans began influencing climate thousands of years ago by increasing greenhouse gas emissions and preventing the onset of the next ice age. I found that most of the increase in methane sources over this time came from tropical regions with a smaller contribution coming from the extratropical northern hemisphere. Based on previous modeling estimates of natural methane source changes, I found that the increase in the southern hemisphere tropical methane emissions was likely natural and that the northern hemispheric increase in methane emissions was likely due to anthropogenic activities. These results also provide new constraints on the total magnitude of pre-industrial anthropogenic methane emissions, which I found to be between the high and low estimates that have been previously published in the literature. For the final component of my thesis I assembled a coalition of scientists to investigate the effects of layering on the process of air enclosure in ice at WAIS Divide. Air bubbles are trapped in ice 60-100m below the surface of an ice sheet as snow compacts into solid ice in a region that is known as the Lock-In Zone (LIZ). The details of this process are not known and in the absence of direct measurements previous researchers have assumed it to be a smooth process. This project utilized high-resolution methane and air content measurements as well as density of ice, delta15N of N2, and bubble number density measurements to show that air entrapment is affected by high frequency (mm scale) layering in the density of ice within the LIZ. I show that previous parameterizations of the bubble closure process in firn models have not accounted for this variability and present a new parameterization which does. This has implications for interpreting rapid changes in trace gases measured in ice cores since variable bubble closure will impact the smoothing of those records. In particular it is essential to understand the details of this process as new high resolution ice core records from Antarctica and Greenland examine the relative timing between greenhouse gases and rapid climate changes. (Abstract shortened by UMI.)

High-resolution mineral dust and sea ice proxy records from the Talos Dome ice core

NASA Astrophysics Data System (ADS)

Schüpbach, S.; Federer, U.; Kaufmann, P. R.; Albani, S.; Barbante, C.; Stocker, T. F.; Fischer, H.

2013-12-01

In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years (ka) before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model, we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large-scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 ka. Our transport model applied on ice core data is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records also allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean during the transition from the Last Glacial Maximum to the Holocene (T1). While a former estimate based on the EPICA Dome C (EDC) record only suggested 20 ppm, we find that reduced dust induced iron fertilisation in the Southern Ocean may be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EPICA Dronning Maud Land (EDML) are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the Southern Ocean. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.

Continuous analysis of phosphate in a Greenland shallow ice core

NASA Astrophysics Data System (ADS)

Kjær, Helle Astrid; Svensson, Anders; Bigler, Matthias; Vallelonga, Paul; Kettner, Ernesto; Dahl-Jensen, Dorthe

2010-05-01

Phosphate is an important and sometimes limiting nutrient for primary production in the oceans. Because of deforestation and the use of phosphate as a fertilizer changes in the phosphate cycle have occurred over the last centuries. On longer time scales, sea level changes are thought to have also caused changes in the phosphate cycle. Analyzing phosphate concentrations in ice cores may help to gain important knowledge about those processes. In the present study, we attach a phosphate detection line to an existing continuous flow analysis (CFA) setup for ice core analysis at the University of Copenhagen. The CFA system is optimized for high-resolution measurements of insoluble dust particles, electrolytic melt water conductivity, and the concentrations of ammonium and sodium. For the phosphate analysis we apply a continuous and highly sensitive absorption method that has been successfully applied to determine phosphate concentrations of sea water (Zhang and Chi, 2002). A line of melt water from the CFA melt head (1.01 ml per minute) is combined with a molybdate blue reagent and an ascorbic acid buffer. An uncompleted reaction takes place in five meters of heated mixing coils before the absorption measurement at a wavelength of 710 nanometer takes place in a 2 m long liquid waveguide cell (LWCC) with an inner volume of 0.5 ml. The method has a detection limit of around 0.1 ppb and we are currently investigating a possible interference from molybdate reacting with silicates that are present in low amounts in the ice. Preliminary analysis of early Holocene samples from the NGRIP ice core show phosphate concentration values of a few ppb. In this study, we will attempt to determine past levels of phosphate in a shallow Northern Greenland firn core with an annual layer thickness of about 20 cm ice equivalent. With a melt speed of 2.5 cm ice per minute our method should allow the resolution of any seasonal variability in phosphate concentrations.

Annually resolved ice core records of tropical climate variability over the past ~1800 years.

PubMed

Thompson, L G; Mosley-Thompson, E; Davis, M E; Zagorodnov, V S; Howat, I M; Mikhalenko, V N; Lin, P-N

2013-05-24

Ice cores from low latitudes can provide a wealth of unique information about past climate in the tropics, but they are difficult to recover and few exist. Here, we report annually resolved ice core records from the Quelccaya ice cap (5670 meters above sea level) in Peru that extend back ~1800 years and provide a high-resolution record of climate variability there. Oxygen isotopic ratios (δ(18)O) are linked to sea surface temperatures in the tropical eastern Pacific, whereas concentrations of ammonium and nitrate document the dominant role played by the migration of the Intertropical Convergence Zone in the region of the tropical Andes. Quelccaya continues to retreat and thin. Radiocarbon dates on wetland plants exposed along its retreating margins indicate that it has not been smaller for at least six millennia.

Changes in Black Carbon Deposition to Antarctica from Two Ice Core Records, A.D. 1850-2000

NASA Technical Reports Server (NTRS)

Bisiaux, Marion M.; Edward, Ross; McConnell, Joseph R.; Curran, Mark A. J.; VanOmmen, Tas D.; Smith, Andrew M.; Neumann, Thomas A.; Pasteris, Daniel R.; Penner, Joyce E.; Taylor, Kendrick

2012-01-01

Continuous flow analysis was based on a steady sample flow and in-line detection of BC and other chemical substances as described in McConnell et al. (2007). In the cold room, previously cut one meter ice core sticks of 3x3cm, are melted continuously on a heated melter head specifically designed to eliminate contamination from the atmosphere or by the external parts of the ice. The melted ice from the most inner part of the ice stick is continuously pumped by a peristaltic pump and carried to a clean lab by Teflon lines. The recorded signal is continuous, integrating a sample volume of about 0.05 mL, for which the temporal resolution depends on the speed of melting, ice density and snow accumulation rate at the ice core drilling site. For annual accumulation derived from the WAIS and Law Dome ice cores, we assumed 3.1 cm water equivalent uncertainty in each year's accumulation from short scale spatial variability (glaciological noise) which was determined from several measurements of annual accumulation in multiple parallel ice cores notably from the WAIS Divide ice core site (Banta et al., 2008) and from South Pole site (McConnell et al., 1997; McConnell et al., 2000). Refractory black carbon (rBC) concentrations were determined using the same method as in (Bisiaux et al., 2011) and adapted to continuous flow measurements as described by (McConnell et al., 2007). The technique uses a single particle intracavity laser induced incandescence photometer (SP2, Droplet Measurement Technologies, Boulder, Colorado) coupled to an ultrasonic nebulizer/desolvation (CETAC UT5000) Flow Injection Analysis (FIA). All analyses, sample preparation etc, were performed in a class 100 cleanroom using anti contamination "clean techniques". The samples were not acidified.

Late Pleistocene and Holocene paleoclimate and alpine glacier fluctuations recorded by high-resolution grain-size data from an alpine lake sediment core, Wind River Range, Wyoming, USA

NASA Astrophysics Data System (ADS)

Thompson Davis, P.; Machalett, Björn; Gosse, John

2013-04-01

Varved lake sediments, which provide ideal high-resolution climate proxies, are not commonly available in many geographic areas over long time scales. This paper utilizes high-resolution grain-size analyses (n = 1040) from a 520-cm long sediment core from Lower Titcomb Lake (LTL), which lies just outside the type Titcomb Basin (TTB) moraines in the Wind River Range, Wyoming. The TTB moraines lie between Lower Titcomb Lake and Upper Titcomb Lake (UTL), about 3 km beyond, and 200 m lower than the modern glacier margin and Gannett Peak (Little Ice Age) moraines in the basin. Based on cosmogenic exposure dating, the TTB moraines are believed to be Younger Dryas (YD) age (Gosse et al., 1995) and lie in a geomorphic position similar to several other outer cirque moraines throughout the western American Cordillera. Until recently, many of these outer cirque moraines were believed to be Neoglacial age. The sediment core discussed here is one of five obtained from the two Titcomb Lakes, but is by the far the longest with the oldest sediment depositional record. Two AMS radiocarbon ages from the 445- and 455-cm core depths (about 2% loss on ignition, LOI) suggest that the lake basin may have been ice-free as early as 16.1 or even 16.8 cal 14C kyr, consistent with 10Be and 26Al exposure ages from boulders and bedrock surfaces outside the TTB moraines. The 257-cm depth in the core marks an abrupt transition from inorganic, sticky gray silt below (<1% LOI) to more organic, less sticky, light brown silt above (4-10% LOI). Eight AMS radiocarbon ages on bulk sediment and macrofossils date the transition to about 11.6 cal 14C kyr. Thus, sampling resolution above the transition is about 22.57 yr and below the transition is about 12.56 yr, consistent with a decreased sediment accumulation rate in LTL when Younger Dryas ice pulled back from the TTB moraines opening up UTL as a sediment depositional basin. The presented high-resolution grain size record reveals amplitudes and other structural features similar to delta 18O records from deep-lake ostracods in southern Germany, the Greenland ice core record, and speleothems in China. Major increases in the 2 - 8 µm grain size fraction indicative of increased glacier rock flour production between the 257 and 466 cm core depths appear to be roughly correlative with the YD-Alleröd-Bölling-Meiendorf-Heinrich 1 climate events recognized in other terrestrial records and Northern Atlantic Ocean marine cores, but provide much higher resolution than most of those records from a climate-sensitive alpine region in North America.

Integration of Tibetan Plateau ice-core temperature records and the influence of atmospheric circulation on isotopic signals in the past century

NASA Astrophysics Data System (ADS)

Yang, Xiaoxin; Yao, Tandong; Joswiak, Daniel; Yao, Ping

2014-05-01

Temperature signals in ice-core δ18O on the Tibetan Plateau (TP), particularly in the central and southern parts, continue to be debated because of the large scale of atmospheric circulation. This study presents ten ice-core δ18O records at an annual resolution, with four (Malan, Muztagata, Guliya, and Dunde) in the northern, three (Puruogangri, Geladaindong, Tanggula) in the central and three (Noijin Kangsang, Dasuopu, East Rongbuk) in the southern TP. Integration shows commonly increasing trends in δ18O in the past century, featuring the largest one in the northern, a moderate one in the central and the smallest one in the southern TP, which are all consistent with ground-based measurements of temperature. The influence of atmospheric circulation on isotopic signals in the past century was discussed through the analysis of El Niño/Southern Oscillation (ENSO), and of possible connections between sea surface temperature (SST) and the different increasing trends in both ice-core δ18O and temperature. Particularly, El Niño and the corresponding warm Bay of Bengal (BOB) SST enhance the TP ice-core isotopic enrichment, while La Niña, or corresponding cold BOB SST, causes depletion. This thus suggests a potential for reconstructing the ENSO history from the TP ice-core δ18O.

An 80-year summer temperature history from the Xiao Dongkemadi ice core in the central Tibetan Plateau and its association with atmospheric circulation

NASA Astrophysics Data System (ADS)

Li, Xiangying; Ding, Yongjian; Yu, Zhongbo; Mika, Sillanpää; Liu, Shiyin; Shangguan, Donghui; Lu, Chengyang

2015-02-01

The climate significance of oxygen isotopes from the central Tibetan Plateau (cTP) ice cores is a debated issue because of large scale atmospheric circulation. A high-resolution δ18O record was recovered from the Xiao Dongkemadi (XD) ice core, which expanded the spatial coverage of δ18O data in this region. Annual average δ18O correlated significantly with nearby MJJAS air temperatures, suggesting the δ18O can be used as a proxy to reconstruct regional climate change. The reconstructed temperature anomaly is related to the regional and global warming trends, and the greater warming amplitude since 1970s is related to the elevation dependency of the warming signal. The close relationship of the warming to variations in glacier mass balances and discharge reveal that recent warming has led to obvious glacier shrinkage and runoff increase. Correlation analysis suggests that monsoon and westerly moisture substantially influence the cTP ice core records, along with an increase in their level of contribution to the XD core accumulation in recent decades, and confirms a teleconnection of regional climate of the cTP ice cores with climate parameters in the Indian and North Atlantic Oceans.

A 62 ka record from the WAIS Divide ice core with annual resolution to 30 ka (so far)

NASA Astrophysics Data System (ADS)

Fudge, T. J.; Taylor, K.; McGwire, K.; Brook, E.; Sowers, T.; Steig, E.; White, J.; Vaughn, B.; Bay, R.; McConnell, J.; Waddington, E.; Conway, H.; Clow, G.; Cuffey, K.; Cole-Dai, J.; Ferris, D.; Severinghaus, J.

2012-04-01

Drilling of the West Antarctic Ice Sheet (WAIS) Divide ice core has been completed to a depth of 3400 m, about 60 meters above the bed. We present an annually resolved time scale for the most recent 30ka (to 2800 m) based on electrical conductivity measurements, called "timescale WDC06A-5". Below 2800 m the ice is dated by matching isotopes, methane, and/or dust records to other ice cores. Optical borehole logging provides stratigraphic ties to other cores for the bottom-most 75 m that was drilled in December 2011, and indicates the bottom-most ice has an age of 62 ka. The relatively young ice at depth is likely the result of basal melting. The inferred annual layer thickness of the deep ice is >1 cm, suggesting that annual layer counting throughout the entire core may be possible with continuous flow analysis of the ice core chemistry; however, the annual signal in the electrical measurements fades at about 30 ka. We compare the WDC06A-5 timescale through the glacial-interglacial transition with the Greenland GICC05 and GISP2 timescales via rapid variations in methane. We calculate a preliminary delta-age with: 1) accumulation rate inferred from the annual layer thicknesses and thinning functions computed with a 1-D ice flow model, and 2) surface temperature inferred from the low resolution d18O record and a preliminary borehole temperature profile. The WDC06A-5 timescale agrees with the GICC05 and GISP2 timescales to within decades at the 8.2k event and the ACR termination (Younger Dryas/Preboreal transition, 11.7 ka). This is within the delta-age and correlation uncertainties. At the rapid methane drop at ~12.8 ka, the WDC06A-5 timescale is ~150 years older than GICC05 and ~90 older than GISP2; while at ~14.8 ka, the timescales once again agree within the delta-age and correlation uncertainties. The cause of the age discrepancy at 12.8 ka is unclear. We also compare the WDC06A-5 timescale at Dansgaard-Oeschger events 3 and 4 (~27.5 and 29 ka) to the radiometrically-dated speolethem records from Hulu Cave, China (Larry Edwards and Hai Cheng, personal communication). To make such a comparison, we assume that the rapid variations in methane from the WAIS Divide core are synchronous with the rapid variations in d18O in the speleothem record. We find that the WDC06A-5 timescale is multiple hundreds of years older than the Hulu Cave record. As the GICC05 timescale is younger than the Hulu timescale, this puts the WDC06A-5 timescale even older than the GICC05. The uncertainties in the comparison are large both because of the uncertainty in the synchroneity of the ice core methane and speleothem isotope variations and because of the larger delta-age for the ice core in the glacial period. The timescale for the WAIS Divide core will be revised when the CFA results become available.

Multi-core, multi-constraint chronostratigraphic framework over past 50,000 years places high-resolution Gulf of Alaska ocean-ice-sediment history into a global framework

NASA Astrophysics Data System (ADS)

Mix, A. C.; Walczak, M.; Asahi, H.; Belanger, C. L.; Cowan, E. A.; Du, J.; Fallon, S.; Fifield, L. K.; Hobern, T.; Jaeger, J. M.; Jensen, B. J. L.; McKay, J. L.; Padman, J.; Ross, A.; Sharon, S.; Stoner, J. S.; Zellers, S.

2017-12-01

Development of precise chronologies extending older than late glacial time in the subpolar North Pacific has been notoriously difficult due to limited record length in sediment cores, poor carbonate preservation, and (in many cases) relatively low resolution records. This is a key gap in our understanding of Northern Hemisphere and global paleoclimate change, now addressed with results from IODP Expedition 341 in the Gulf of Alaska. Here we utilize marine core and drill sites (U1417, U1418, U1419, U1421 and co-located site-survey cores) some of which provide exceptionally high sustained sedimentation rates (up to 2 cm per year in extended glacial intervals). This facilitates a multifaceted approach to chronology development over the past 50,000 years including radiocarbon, foraminiferal stable isotopes and other geochemical proxies, sediment physical properties, sedimentology, and tephrochronology. Given high sedimentation rates and the superb preservation this provides, we have developed marine time series that rival the resolution of the polar ice core records, which allows us to compare radiocarbon-based chronologies with several strategies involving signal tuning. Such a multifaceted approach mitigates weaknesses in any of the individual methods and allows a rigorous analysis of uncertainties in ages and sediment accumulation rates. The resulting record reveals dynamic changes in the Cordilleran Ice Sheet and North Pacific Ocean and most importantly facilitates placing these records into the context of global climate changes. (We acknowledge the contributions of J. Addison and S. Praetorius, who were not listed as co-authors due to USGS submission rules).

Raman spectroscopy on ice cores from Greenland and Antarctica

NASA Astrophysics Data System (ADS)

Weikusat, C.; Kipfstuhl, S.

2012-04-01

Ice cores are invaluable archives for the reconstruction of the climatic history of the earth. Besides the analysis of various climatic processes from isotopes and chemical signatures they offer the unique possibility of directly extracting the past atmosphere from gaseous inclusions in the ice. Many aspects of the formation and alterations of these inclusions, e.g. the entrapment of air at the firn-ice-transition, the formation of crystalline gas hydrates (clathrates) from the bubbles or the structural relaxation during storage of the cores, need to be better understood to enable reliable interpretations of the obtained data. Modern micro Raman spectroscopy is an excellent tool to obtain high-quality data for all of these aspects. It has been productively used for phase identification of solid inclusions [1], investigation of air clathrates [2] and high-resolution measurements of N2/O2 mixing ratios inside individual air bubbles [3,4]. Detailed examples of the various uses of Raman spectroscopy will be presented along with practical information about the techniques required to obtain high-quality spectra. Retrieval and interpretation of quantitative data from the spectra will be explained. Future possibilities for advanced uses of Raman spectroscopy for ice core research will be discussed. [1] T. Sakurai et al., 2009, Direct observation of salts as micro-inclusions in the Greenland GRIP ice core. Journal of Glaciology, 55, 777-783. [2] F. Pauer et al., 1995, Raman spectroscopic study of nitrogen/oxygen ratio in natural ice clathrates in the GRIP ice core. Geophysical Research Letters, 22, 969-971. [3] T. Ikeda-Fukazawa et al., 2001, Variation in N2/O2 ratio of occluded air in Dome Fuji antarctic ice. Journal of Geophysical Research, 106, 17799-17810. [4] C. Weikusat et al., Raman spectroscopy of gaseous inclusions in EDML ice core: First results - microbubbles. Journal of Glaciology, accepted.

Are annual layers preserved in NorthGRIP Eemian ice?

NASA Astrophysics Data System (ADS)

Kettner, E.; Bigler, M.; Nielsen, M. E.; Steffensen, J. P.; Svensson, A.

2009-04-01

A newly developed setup for continuous flow analysis (CFA) of ice cores in Copenhagen is optimized for high resolution analysis of four components: Soluble sodium (mainly deriving from sea salt), soluble ammonium (related to biological processes and biomass burning events), insoluble dust particles (basically transported from Asian deserts to Greenland), and the electrolytic melt water conductivity (which is a bulk signal for all ionic constituents). Furthermore, we are for the first time implementing a flow cytometer to obtain high quality dust concentration and size distribution profiles based on individual dust particle measurements. Preliminary measurements show that the setup is able to resolve annual layers of 1 cm thickness. Ice flow models predict that annual layers in the Eemian section of the Greenland NorthGRIP ice core (130-115 ka BP) have a thickness of around 1 cm. However, the visual stratigraphy of the ice core indicates that the annual layering in the Eemian section may be disturbed by micro folds and rapid crystal growth. In this case study we will measure the impurity content of an Eemian segment of the NorthGRIP ice core with the new CFA setup. This will allow for a comparison to well-known impurity levels of the Holocene in both Greenland and Antarctic ice and we will attempt to determine if annual layers are still present in the ice.

Dating an 800,000 year Antarctic ice core record using the isotopic composition of trapped air

NASA Astrophysics Data System (ADS)

Dreyfus, Gabrielle Boissier

Here we measure the isotopic composition of air trapped in the European Project for Ice Coring in Antarctica Dome C (EDC) ice core, and use this geochemical information to improve the ice core agescale and our understanding of air enclosure processes. A first result is the detection of a flow anomaly in the bottom 500m of the EDC ice core using the delta18O of atmospheric oxygen (noted delta18Oatm). By tuning the measured delta18Oatm to the orbital precession signal, we correct the EDC agescale over 400-800 ka for flow-induced distortions in the duration of events. Uncertainty in delta 18Oatm phasing with respect to precession limits the accuracy of the tuned agescale to +/-6 ka. We use this improved agescale to date two 10Be peaks detected in the EDC ice core and associated with the Matuyama-Brunhes geomagnetic boundary. While the ice age of the "precursor" event agrees within uncertainty with the age of radioisotopically dated lavas, the volcanic age for the younger reversal is approximately 10 ka older than the mid-point of the 10 Be peak in the ice. Since 80% of the lavas recording the Matuyama-Brunhes reversal are located in the Central Pacific, the observed age difference may indicate that the magnetic field orientation at this location changed prior to the dipole intensity minimum recorded by the ice core 10Be, as suggested by recent geodynamo modeling. A particular challenge for ice core dating is accurately accounting for the age difference between the trapped air and surrounding ice. This gas age - ice age difference (noted Deltaage) depends on the age of the ice at the bottom of the firn. delta15N of N2 is constant in the atmosphere over the timescales considered here, so any deviation from atmospheric composition reflects fractionation processes in the firn. We show that delta15N is positively correlated with the ice deuterium content, a proxy for temperature, over the entire EDC record, and propose an accumulation-permeability-convection mechanism. While temporal resolution and noise in the available data limit our ability to constrain glacial Deltaage, these data suggest that delta15N may be used as a gas-phase climate proxy at EDC.

Measurements of ethane in Antarctic ice cores

NASA Astrophysics Data System (ADS)

Verhulst, K. R.; Fosse, E. K.; Aydin, K. M.; Saltzman, E. S.

2011-12-01

Ethane is one of the most abundant hydrocarbons in the atmosphere. The major ethane sources are fossil fuel production and use, biofuel combustion, and biomass-burning emissions and the primary loss pathway is via reaction with OH. A paleoatmospheric ethane record would be useful as a tracer of biomass-burning emissions, providing a constraint on past changes in atmospheric methane and methane isotopes. An independent biomass-burning tracer would improve our understanding of the relationship between biomass burning and climate. The mean annual atmospheric ethane level at high southern latitudes is about 230 parts per trillion (ppt), and Antarctic firn air measurements suggest that atmospheric ethane levels in the early 20th century were considerably lower (Aydin et al., 2011). In this study, we present preliminary measurements of ethane (C2H6) in Antarctic ice core samples with gas ages ranging from 0-1900 C.E. Samples were obtained from dry-drilled ice cores from South Pole and Vostok in East Antarctica, and from the West Antarctic Ice Sheet Divide (WAIS-D). Gases were extracted from the ice by melting under vacuum in a glass vessel sealed by indium wire and were analyzed using high resolution GC/MS with isotope dilution. Ethane levels measured in ice core samples were in the range 100-220 ppt, with a mean of 157 ± 45 ppt (n=12). System blanks contribute roughly half the amount of ethane extracted from a 300 g ice core sample. These preliminary data exhibit a temporal trend, with higher ethane levels from 0-900 C.E., followed by a decline, reaching a minimum between 1600-1700 C.E. These trends are consistent with variations in ice core methane isotopes and carbon monoxide isotopes (Ferretti et al., 2005, Wang et al., 2010), which indicate changes in biomass burning emissions over this time period. These preliminary data suggest that Antarctic ice core bubbles contain paleoatmospheric ethane levels. With further improvement of laboratory techniques it appears likely that a paleoatmospheric ethane record can be obtained from polar ice cores.

RICE ice core: Black Carbon reflects climate variability at Roosevelt Island, West Antarctica

NASA Astrophysics Data System (ADS)

Ellis, Aja; Edwards, Ross; Bertler, Nancy; Winton, Holly; Goodwin, Ian; Neff, Peter; Tuohy, Andrea; Proemse, Bernadette; Hogan, Chad; Feiteng, Wang

2015-04-01

The Roosevelt Island Climate Evolution (RICE) project successfully drilled a deep ice core from Roosevelt Island during the 2011/2012 and 2012/2013 seasons. Located in the Ross Ice Shelf in West Antarctica, the site is an ideal location for investigating climate variability and the past stability of the Ross Ice Shelf. Black carbon (BC) aerosols are emitted by both biomass burning and fossil fuels, and BC particles emitted in the southern hemisphere are transported in the atmosphere and preserved in Antarctic ice. The past record of BC is expected to be sensitive to climate variability, as it is modulated by both emissions and transport. To investigate BC variability over the past 200 years, we developed a BC record from two overlapping ice cores (~1850-2012) and a high-resolution snow pit spanning 2010-2012 (cal. yr). Consistent results are found between the snow pit profiles and ice core records. Distinct decadal trends are found with respect to BC particle size, and the record indicates a steady rise in BC particle size over the last 100 years. Differences in emission sources and conditions may be a possible explanation for changes in BC size. These records also show a significant increase in BC concentration over the past decade with concentrations rising over 1.5 ppb (1.5*10^-9 ng/g), suggesting a fundamental shift in BC deposition to the site.

All-flavour search for neutrinos from dark matter annihilations in the Milky Way with IceCube/DeepCore

DOE PAGES

Aartsen, M. G.; Abraham, K.; Ackermann, M.; ...

2016-09-28

We present the first IceCube search for a signal of dark matter annihilations in the Milky Way using all-flavour neutrino-induced particle cascades. The analysis focuses on the DeepCore sub-detector of IceCube, and uses the surrounding IceCube strings as a veto region in order to select starting events in the DeepCore volume. We use 329 live-days of data from IceCube operating in its 86-string configuration during 2011–2012. No neutrino excess is found, the final result being compatible with the background-only hypothesis. From this null result, we derive upper limits on the velocity-averaged self-annihilation cross-section, < σ A v > , formore » dark matter candidate masses ranging from 30 GeV up to 10 TeV, assuming both a cuspy and a flat-cored dark matter halo profile. For dark matter masses between 200 GeV and 10 TeV, the results improve on all previous IceCube results on < σ A v > , reaching a level of 10 - 23 cm 3 s - 1 , depending on the annihilation channel assumed, for a cusped NFW profile. The analysis demonstrates that all-flavour searches are competitive with muon channel searches despite the intrinsically worse angular resolution of cascades compared to muon tracks in IceCube.« less

All-flavour search for neutrinos from dark matter annihilations in the Milky Way with IceCube/DeepCore

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aartsen, M. G.; Abraham, K.; Ackermann, M.

We present the first IceCube search for a signal of dark matter annihilations in the Milky Way using all-flavour neutrino-induced particle cascades. The analysis focuses on the DeepCore sub-detector of IceCube, and uses the surrounding IceCube strings as a veto region in order to select starting events in the DeepCore volume. We use 329 live-days of data from IceCube operating in its 86-string configuration during 2011–2012. No neutrino excess is found, the final result being compatible with the background-only hypothesis. From this null result, we derive upper limits on the velocity-averaged self-annihilation cross-section, < σ A v > , formore » dark matter candidate masses ranging from 30 GeV up to 10 TeV, assuming both a cuspy and a flat-cored dark matter halo profile. For dark matter masses between 200 GeV and 10 TeV, the results improve on all previous IceCube results on < σ A v > , reaching a level of 10 - 23 cm 3 s - 1 , depending on the annihilation channel assumed, for a cusped NFW profile. The analysis demonstrates that all-flavour searches are competitive with muon channel searches despite the intrinsically worse angular resolution of cascades compared to muon tracks in IceCube.« less

Climate Proxies: An Inquiry-Based Approach to Discovering Climate Change on Antarctica

NASA Astrophysics Data System (ADS)

Wishart, D. N.

2016-12-01

An attractive way to advance climate literacy in higher education is to emphasize its relevance while teaching climate change across the curriculum to science majors and non-science majors. An inquiry-based pedagogical approach was used to engage five groups of students on a "Polar Discovery Project" aimed at interpreting the paleoclimate history of ice cores from Antarctica. Learning objectives and student learning outcomes were clearly defined. Students were assigned several exercises ranging from examination of Antarctic topography to the application of physical and chemical measurements as proxies for climate change. Required materials included base and topographic maps of Antarctica; graph sheets for construction of topographic cross-sectional profiles from profile lines of the Western Antarctica Ice Sheet (WAIS) Divide and East Antarctica; high-resolution photographs of Antarctic ice cores; stratigraphic columns of ice cores; borehole and glaciochemical data (i.e. anions, actions, δ18O, δD etc.); and isotope data on greenhouse gases (CH4, O2, N2) extracted from gas bubbles in ice cores. The methodology was to engage students in (2) construction of topographic profiles; (2) suggest directions for ice flow based on simple physics; (3) formulate decisions on suitable locations for drilling ice cores; (4) visual ice stratigraphy including ice layer counting; (5) observation of any insoluble particles (i.e. meteoritic and volcanic material); (6) analysis of borehole temperature profiles; and (7) the interpretation of several datasets to derive a paleoclimate history of these areas of the continent. The overall goal of the project was to improve the students analytical and quantitative skills; their ability to evaluate relationships between physical and chemical properties in ice cores, and to advance the understanding the impending consequences of climate change while engaging science, technology, engineering and mathematics (STEM). Student learning outcomes were assessed at the completion of the `Polar Discovery Project' for their curiosity, analytical strength, creativity, group collaboration, problem-solving, innovation, and interest in level climate change and the implications of the its effects on polar regions.

Atmospheric mercury deposition during the last 270 years--A glacial ice core record of natural and anthropogenic sources

USGS Publications Warehouse

Schuster, Paul F.; Krabbenhoft, David P.; Naftz, David L.; Cecil, L. DeWayne; Olson, Mark L.; DeWild, John F.; Susong, David D.; Green, Jaromy R.; Abbott, Michael L.

2002-01-01

Mercury (Hg) contamination of aquatic ecosystems and subsequent methylmercury bioaccumulation are significant environmental problems of global extent. At regional to global scales, the primary mechanism of Hg contamination is atmospheric Hg transport. Thus, a better understanding of the long-term history of atmospheric Hg cycling and quantification of the sources is critical for assessing the regional and global impact of anthropogenic Hg emissions. Ice cores collected from the Upper Fremont Glacier (UFG), Wyoming, contain a high-resolution record of total atmospheric Hg deposition (ca. 1720−1993). Total Hg in 97 ice-core samples was determined with trace-metal clean handling methods and low-level analytical procedures to reconstruct the first and most comprehensive atmospheric Hg deposition record of its kind yet available from North America. The record indicates major atmospheric releases of both natural and anthropogenic Hg from regional and global sources. Integrated over the past 270-year ice-core history, anthropogenic inputs contributed 52%, volcanic events 6%, and background sources 42%. More significantly, during the last 100 years, anthropogenic sources contributed 70% of the total Hg input. Unlike the 2−7-fold increase observed from preindustrial times (before 1840) to the mid-1980s in sediment-core records, the UFG record indicates a 20-fold increase for the same period. The sediment-core records, however, are in agreement with the last 10 years of this ice-core record, indicating declines in atmospheric Hg deposition.

Microshear in the deep EDML ice core analyzed using cryogenic EBSD

NASA Astrophysics Data System (ADS)

Kuiper, Ernst-Jan; Pennock, Gill; Drury, Martyn; Kipfstuhl, Sepp; Faria, Sérgio; Weikusat, Ilka

2017-04-01

Ice sheets play an important role in sea level evolution by storing large amounts of fresh water on land. The ice in an ice sheet flows from the interior of the ice sheet to the edges where it either melts or calves into the ocean. This flow of ice results from internal deformation of the ice aggregate. Dislocation creep is assumed to be the dominant deformation mechanism for polar ice and is grain size insensitive. Recently, a different deformation mechanism was identified in the deeper part of the EDML ice core (Antarctica) where, at a depth of 2385 meters, the grain size strongly decreases, the grain aspect ratio increase and, the inclination of the grain elongation changes (Faria et al., 2006; Weikusat et al., 2017). At this depth the borehole displacement increases strongly (Weikusat et al., 2017), which indicates a relatively high strain rate. Part of this EDML ice core section was studied using cryogenic electron backscattered diffraction (cryo-EBSD) (Weikusat et al, 2011). EBSD produces high resolution, full crystallographic (a-axis and c-axis) maps of the ice core samples. EBSD samples were taken from an ice core section at 2392.2 meter depth. This section was chosen for its very small grain size and the strongly aligned grain boundaries. The EBSD maps show a very low orientation gradient of <0.3° per millimetre inside the grains, which is 5-10 times lower than the orientation gradients found in other parts of the ice core. Furthermore, close to some grain boundaries, a relatively strong orientation gradient of 1°-2° per millimetre was found. The subgrain boundaries developed such that they elongate the sliding boundaries in order to accommodate the incompatibilities and maintain the strongly aligned grain boundary network. We identify the dominant deformation mechanism in this part of the ice core as grain boundary sliding accommodated by localized dislocation creep, which is a process similar to microshear (Drury and Humpreys, 1988). The existence of layers of soft ice has serious implications for ice core dating, related paleoclimate studies and ice flow modelling with respect to ice sheet mass balance and sea level predictions. References: - Drury and Humphreys, 1988. Microstructural shear criteria associated with grain boundary sliding during ductile deformation. J. of Struc. Geol. 10, 1, 83-89. - Faria et al., 2006. Is Antarctica like a birthday cake?, Max Planck Institute of Mathematics and the Sciences - Weikusat et al., 2011. Cryogenic EBSD on ice: preserving a stable surface in a low pressure SEM. J. Micros. 242, 3, 295-310. (doi: 10.1111/j.1365-2818.2010.03471.x) - Weikusat et al., 2017. Physical analysis of an Antarctic ice core-towards an integration of micro- and macrodynamics of polar ice. Phil. Trans. R. Soc. A 375, 2015347. (doi:10.1098/rsta.2015.0347)

The geochemical record in rock glaciers

USGS Publications Warehouse

Steig, E.J.; Fitzpatrick, J.J.; Potter, N.; Clark, D.H.

1998-01-01

A 9.5 m ice core was extracted from beneath the surficial debris cover of a rock glacier at Galena Creek, northwestern Wyoming. The core contains clean, bubble-rich ice with silty debris layers spaced at roughly 20 cm intervals. The debris layers are similar in appearance to those in typical alpine glaciers, reflecting concentration of debris by melting at the surface during the summer ablation season. Profiles of stable isotope concentrations and electrical conductivity measurements provide independent evidence for melting in association with debris layers. These observations are consistent with a glacial origin for the ice, substantiating the glacigenic model for rock glacier formation. The deuterium excess profile in the ice indicates that the total depth of meltwater infiltration is less than the thickness of one annual layer, suggesting that isotope values and other geochemical signatures are preserved at annual resolution. This finding demonstrates the potential for obtaining useful paleoclimate information from rock glacier ice.

Denali Ice Core MSA: A Record of North Pacific Primary Productivity

NASA Astrophysics Data System (ADS)

Polashenski, D.; Osterberg, E. C.; Winski, D.; Kreutz, K. J.; Wake, C. P.; Ferris, D. G.; Introne, D.; Campbell, S. W.

2017-12-01

The high nutrient, low chlorophyll region of the North Pacific is one of the most biologically productive marine ecosystems in the world and forms the basis of commercial, sport, and subsistence fisheries worth more than a billion dollars annually. Marine phytoplankton prove to be important both as the primary producers in these ecosystems and as a major source of biogenic sulfur emissions which have long been hypothesized to serve as a biological control on Earth's climate system. Despite their importance, the record of marine phytoplankton abundance and the flux of biogenic sulfur from these regions is not well constrained. In situ measurements of marine phytoplankton from oceanographic cruises over the past several decades are limited in both spatial and temporal resolution. Meanwhile, marine sediment records may provide insight on million year timescales, but lack decadal resolution due to slow sediment deposition rates and bioturbation. In this study, we aim to investigate changes in marine phytoplankton productivity of the northeastern subarctic Pacific Ocean (NSPO) over the twentieth century using the methanesulfonic acid (MSA) record from the Mt. Hunter ice cores drilled in Denali National Park, Alaska. These parallel, 208 meter long ice cores were drilled during the 2013 field season on the Mt. Hunter plateau (63° N, 151° W, 4,000 m above sea level). Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) modeling is used to identify likely source areas in the NSPO for MSA being transported to the core site. SeaWiFS satellite imagery allows for a direct comparison of chlorophyll a concentrations in these source areas with MSA concentrations in the core record through time. Our findings suggest that the Denali ice core MSA record reflects changes in the biological productivity of marine phytoplankton and shows a significant decline in MSA beginning in 1961. We investigate several hypotheses for potential mechanisms driving this MSA decline including iron limitation from windblown dust, copper toxicity, phytoplankton speciation change, and a change in moisture source using additional chemical records from the Denali ice core.

Roosevelt Island Climate Evolution Project (RICE): A 65 Kyr ice core record of black carbon aerosol deposition to the Ross Ice Shelf, West Antarctica.

NASA Astrophysics Data System (ADS)

Edwards, Ross; Bertler, Nancy; Tuohy, Andrea; Neff, Peter; Proemse, Bernedette; Feiteng, Wang; Goodwin, Ian; Hogan, Chad

2015-04-01

Emitted by fires, black carbon aerosols (rBC) perturb the atmosphere's physical and chemical properties and are climatically active. Sedimentary charcoal and other paleo-fire records suggest that rBC emissions have varied significantly in the past due to human activity and climate variability. However, few paleo rBC records exist to constrain reconstructions of the past rBC atmospheric distribution and its climate interaction. As part of the international Roosevelt Island Climate Evolution (RICE) project, we have developed an Antarctic rBC ice core record spanning the past ~65 Kyr. The RICE deep ice core was drilled from the Roosevelt Island ice dome in West Antarctica from 2011 to 2013. The high depth resolution (~ 1 cm) record was developed using a single particle intracavity laser-induced incandescence soot photometer (SP2) coupled to an ice core melter system. The rBC record displays sub-annual variability consistent with both austral dry-season and summer biomass burning. The record exhibits significant decadal to millennial-scale variability consistent with known changes in climate. Glacial rBC concentrations were much lower than Holocene concentrations with the exception of several periods of abrupt increases in rBC. The transition from glacial to interglacial rBC concentrations occurred over a much longer time relative to other ice core climate proxies such as water isotopes and suggests . The protracted increase in rBC during the transition may reflected Southern hemisphere ecosystem / fire regime changes in response to hydroclimate and human activity.

Towards multi-decadal to multi-millennial ice core records from coastal west Greenland ice caps

NASA Astrophysics Data System (ADS)

Das, Sarah B.; Osman, Matthew B.; Trusel, Luke D.; McConnell, Joseph R.; Smith, Ben E.; Evans, Matthew J.; Frey, Karen E.; Arienzo, Monica; Chellman, Nathan

2017-04-01

The Arctic region, and Greenland in particular, is undergoing dramatic change as characterized by atmospheric warming, decreasing sea ice, shifting ocean circulation patterns, and rapid ice sheet mass loss, but longer records are needed to put these changes into context. Ice core records from the Greenland ice sheet have yielded invaluable insight into past climate change both regionally and globally, and provided important constraints on past surface mass balance more directly, but these ice cores are most often from the interior ice sheet accumulation zone, at high altitude and hundreds of kilometers from the coast. Coastal ice caps, situated around the margins of Greenland, have the potential to provide novel high-resolution records of local and regional maritime climate and sea surface conditions, as well as contemporaneous glaciological changes (such as accumulation and surface melt history). But obtaining these records is extremely challenging. Most of these ice caps are unexplored, and thus their thickness, age, stratigraphy, and utility as sites of new and unique paleoclimate records is largely unknown. Access is severely limited due to their high altitude, steep relief, small surface area, and inclement weather. Furthermore, their relatively low elevation and marine moderated climate can contribute to significant surface melting and degradation of the ice stratigraphy. We recently targeted areas near the Disko Bay region of central west Greenland where maritime ice caps are prevalent but unsampled, as potential sites for new multi-decadal to multi-millennial ice core records. In 2014 & 2015 we identified two promising ice caps, one on Disko Island (1250 m. asl) and one on Nuussuaq Peninsula (1980 m. asl) based on airborne and ground-based geophysical observations and physical and glaciochemical stratigraphy from shallow firn cores. In spring 2015 we collected ice cores at both sites using the Badger-Eclipse electromechanical drill, transported by a medley of small fixed wing and helicopter aircraft, and working out of small tent camps. On Disko Island, despite high accumulation rates and ice thickness of 250 meters, drilling was halted twice due to the encounter of liquid water at depths ranging from 18-20 meters, limiting the depth of the final core to 21 m, providing a multi-decadal record (1980-2015.) On Nuussuaq Peninsula, we collected a 138 m ice core, almost to bedrock, representing a 2500 year record. The ice cores were subsequently analyzed using a continuous flow analysis system (CFA). Age-depth profiles and accumulation histories were determined by combining annual layer counting and an ice flow thinning model, both constrained by glaciochemical tie points to other well-dated Greenland ice core records (e.g. volcanic horizons and continuous heavy metal records). Here we will briefly provide an overview of the project and the new sites, and the novel dating methodology, and describe the latest stratigraphic, isotopic and glaciochemical results. We will also provide a particular focus on new regional climatological insight gained from our records during three climatically sensitive time periods: the late 20th & early 21st centuries; the Little Ice Age; and the Medieval Climate Anomaly.

Trends in North Pacific Ocean-Atmosphere Variability During the Common Era Inferred From a New Mt. Hunter (Denali, Alaska) 1200-Year Ice Core Stable Isotope Record

NASA Astrophysics Data System (ADS)

Kreutz, K. J.; Osterberg, E. C.; Winski, D.; Wake, C. P.; Campbell, S. W.; Introne, D.; Ferris, D. G.

2016-12-01

The mechanisms and outcomes of teleconnections between the tropical and North Pacific regions over the past 2000 years remain elusive. Correctly assessing the impact on the Aluetian Low, storm tracks, and general hydroclimate during the Medieval Climate Anomaly (MCA), transition to the Little Ice Age (LIA), and then into the 20th century likely requires a suite of high resolution paleoclimate data from the region. Here we present an ice core stable water isotope developed from two surface to bedrock ice cores recovered in 2013 from the high elevation Mt. Hunter plateau in Denali National Park, Alaska. The cores were processed using a continuous flow analysis (CFA) system, and dated using a combination of annual chemical and dust signals, and radioactive and volcanic horizons. The resulting annually-resolved timescale currently spans 2013-810AD. We analyzed 6000 stable water isotope samples for d18O, dD, and the derived deuterium excess (dxs) parameter, yielding a subannually resolved isotope record from 2013-1234AD, and 1-3 year resolution from 1233-810AD. We initially focus on the dxs record, as there are trends in the data that correspond to the large scale climate features of the Common Era. The dxs record shows decreased values during the MCA and a rise into the LIA, consistent with several other regional paleoclimate records. The most obvious feature of the dxs record is a pronounced decrease beginning in the mid 19th century and continuing to present. We note that this trend mirrors a rise in snow accumulation rate in the Denali ice core record, suggesting coherent changes in North Pacific climate dynamics over the past 150 years. Understanding the dxs record in terms of ocean source region temperature and/or relative humidity remains a challenge, and we discuss progress on interpreting the Denali isotope record and fitting these data into a broader paleoclimate context.

Improved methodologies for continuous-flow analysis of stable water isotopes in ice cores

NASA Astrophysics Data System (ADS)

Jones, Tyler R.; White, James W. C.; Steig, Eric J.; Vaughn, Bruce H.; Morris, Valerie; Gkinis, Vasileios; Markle, Bradley R.; Schoenemann, Spruce W.

2017-02-01

Water isotopes in ice cores are used as a climate proxy for local temperature and regional atmospheric circulation as well as evaporative conditions in moisture source regions. Traditional measurements of water isotopes have been achieved using magnetic sector isotope ratio mass spectrometry (IRMS). However, a number of recent studies have shown that laser absorption spectrometry (LAS) performs as well or better than IRMS. The new LAS technology has been combined with continuous-flow analysis (CFA) to improve data density and sample throughput in numerous prior ice coring projects. Here, we present a comparable semi-automated LAS-CFA system for measuring high-resolution water isotopes of ice cores. We outline new methods for partitioning both system precision and mixing length into liquid and vapor components - useful measures for defining and improving the overall performance of the system. Critically, these methods take into account the uncertainty of depth registration that is not present in IRMS nor fully accounted for in other CFA studies. These analyses are achieved using samples from a South Pole firn core, a Greenland ice core, and the West Antarctic Ice Sheet (WAIS) Divide ice core. The measurement system utilizes a 16-position carousel contained in a freezer to consecutively deliver ˜ 1 m × 1.3 cm2 ice sticks to a temperature-controlled melt head, where the ice is converted to a continuous liquid stream and eventually vaporized using a concentric nebulizer for isotopic analysis. An integrated delivery system for water isotope standards is used for calibration to the Vienna Standard Mean Ocean Water (VSMOW) scale, and depth registration is achieved using a precise overhead laser distance device with an uncertainty of ±0.2 mm. As an added check on the system, we perform inter-lab LAS comparisons using WAIS Divide ice samples, a corroboratory step not taken in prior CFA studies. The overall results are important for substantiating data obtained from LAS-CFA systems, including optimizing liquid and vapor mixing lengths, determining melt rates for ice cores with different accumulation and thinning histories, and removing system-wide mixing effects that are convolved with the natural diffusional signal that results primarily from water molecule diffusion in the firn column.

An annually resolved marine proxy record for the 8.2K cold event from the northern North Sea based on bivalve shells

NASA Astrophysics Data System (ADS)

Butler, Paul; Estrella-Martínez, Juan; Scourse, James

2017-04-01

The so-called 8.2K cold event is a rapid cooling of about 6° +/- 2° recorded in the Greenland ice core record and thought to be a consequence of a freshwater pulse from the Laurentide ice sheet which reduced deepwater formation in the North Atlantic. In the Greenland ice cores the event is characterized by a maximum extent of 159 years and a central event lasting for 70 years. As discussed by Thomas et al (QSR, 2007), the low resolution and dating uncertainty of much palaeoclimate data makes it difficult to determine the rates of change and causal sequence that characterise the event at different locations. We present here a bivalve shell chronology based on four shells of Arctica islandica from the northern North Sea which (within radiocarbon uncertainty) is coeval with the 8.2K event recorded in the Greenland ice cores. The years of death of each shell based on radiocarbon analysis and crossmatching are 8094, 8134, 8147, and 8208 yrs BP (where "present" = AD 1950), with an associated radiocarbon uncertainty of +/-80 yrs, and their longevities are 106, 122, 112 and 79 years respectively. The total length of the chronology is 192 years (8286 - 8094 BP +/- 80 yrs). The most noticeable feature of the chronology is an 60-year period of increasing growth which may correspond to a similar period of decreasing ice accumulation in the GRIP (central Greenland) ice core record. We tentatively suggest that this reflects increasing food supply to the benthos as summer stratification is weakened by colder seawater temperatures. Stable isotope analyses (results expected to be available when this abstract is presented), will show changes at annual and seasonal resolution, potentially giving a very detailed insight into the causal factors associated with the 8.2K event and its impact in the northern North Sea.

Seasonal variations in the sources of natural and anthropogenic lead deposited at the East Rongbuk Glacier in the high-altitude Himalayas.

PubMed

Burn-Nunes, Laurie; Vallelonga, Paul; Lee, Khanghyun; Hong, Sungmin; Burton, Graeme; Hou, Shugui; Moy, Andrew; Edwards, Ross; Loss, Robert; Rosman, Kevin

2014-07-15

Lead (Pb) isotopic compositions and concentrations, and barium (Ba) and indium (In) concentrations have been analysed at sub-annual resolution in three sections from a <110 m ice core dated to the 18th and 20th centuries, as well as snow pit samples dated to 2004/2005, recovered from the East Rongbuk Glacier in the high-altitude Himalayas. Ice core sections indicate that atmospheric chemistry prior to ~1,953 was controlled by mineral dust inputs, with no discernible volcanic or anthropogenic contributions. Eighteenth century monsoon ice core chemistry is indicative of dominant contributions from local Himalayan sources; non-monsoon ice core chemistry is linked to contributions from local (Himalayan), regional (Indian/Thar Desert) and long-range (North Africa, Central Asia) sources. Twentieth century monsoon and non-monsoon ice core data demonstrate similar seasonal sources of mineral dust, however with a transition to less-radiogenic isotopic signatures that suggests local and regional climate/environmental change. The snow pit record demonstrates natural and anthropogenic contributions during both seasons, with increased anthropogenic influence during non-monsoon times. Monsoon anthropogenic inputs are most likely sourced to South/South-East Asia and/or India, whereas non-monsoon anthropogenic inputs are most likely sourced to India and Central Asia. Copyright © 2014 Elsevier B.V. All rights reserved.

Cosmogenic 10Be Depth Profile in top 560 m of West Antarctic Ice Sheet Divide Ice Core

NASA Astrophysics Data System (ADS)

Welten, K. C.; Woodruff, T. E.; Caffee, M. W.; Edwards, R.; McConnell, J. R.; Bisiaux, M. M.; Nishiizumi, K.

2009-12-01

Concentrations of cosmogenic 10Be in polar ice samples are a function of variations in solar activity, geomagnetic field strength, atmospheric mixing and annual snow accumulation rates. The 10Be depth profile in ice cores also provides independent chronological markers to tie Antarctic to Greenland ice cores and to tie Holocene ice cores to the 14C dendrochronology record. We measured 10Be concentrations in 187 samples from depths of 0-560 m of the main WAIS Divide core, WDC06A. The ice samples are typically 1-2 kg and represent 2-4 m of ice, equivalent to an average temporal resolution of ~12 years, based on the preliminary age-depth scale proposed for the WDC core, (McConnell et al., in prep). Be, Al and Cl were separated using ion exchange chromatography techniques and the 10Be concentrations were measured by accelerator mass spectrometry (AMS) at PRIME lab. The 10Be concentrations range from 8.1 to 19.1 x 10^3 at/g, yielding an average of (13.1±2.1) x 10^3 at/g. Adopting an average snow accumulation rate of 20.9 cm weq/yr, as derived from the age-depth scale, this value corresponds to an average 10Be flux of (2.7±0.5) x 10^5 atoms/yr/cm2. This flux is similar to that of the Holocene part of the Siple Dome (Nishiizumi and Finkel, 2007) and Dome Fuji (Horiuchi et al. 2008) ice cores, but ~30% lower than the value of 4.0 x 10^5 atoms/yr/cm2 for GISP2 (Finkel and Nishiizumi, 1997). The periods of low solar activity, known as Oort, Wolf, Spörer, Maunder and Dalton minima, show ~20% higher 10Be concentrations/fluxes than the periods of average solar activity in the last millennium. The maximum 10Be fluxes during some of these periods of low solar activity are up to ~50% higher than average 10Be fluxes, as seen in other polar ice cores, which makes these peaks suitable as chronologic markers. We will compare the 10Be record in the WAIS Divide ice core with that in other Antarctic as well as Greenland ice cores and with the 14C treering record. Acknowledgment. This work was supported by NSF grants ANT-0538427, 0636815, 0636964 and 0739780. Finkel R. C. and Nishiizumi K. 1997. J. Geophys. Res. 102, 26,699-26,706. Horiuchi K., et al. 2008. Quatern. Geochron. 3, 253-261. Nishiizumi K. and Finkel R. C. 2007. Boulder, Colorado USA: National Snow and Ice Data Center. Digital media.

Ultra high resolution cation analysis of NGRIP deep ice via cryo-cell UV-laser-ablation ICPMS

NASA Astrophysics Data System (ADS)

Della Lunga, Damiano; Muller, Wolfgang; Olander Rasmussen, Sune; Svensson, Anders

2014-05-01

During glacial periods, Earth experienced abrupt climate change events that led to rapid natural warming/ cooling over a few years only (Steffensen et al., 2008). In order to investigate these rapid climate events especially in old thinned ice, highest spatial/time resolution analysis of climate proxies is required. A recently developed methodology at Royal Holloway University of London (Müller et al., 2011), which permits in situ chemical analysis of frozen ice with spatial (and thus time) resolution up to 0.1 mm (100 ?m) using cryo-cell UV-laser ablation inductively-coupled-plasma mass spectrometry (UV-LA-ICPMS), has been optimized and utilized for analysis of (major) elements indicative of dust and/or sea salt (e.g. Fe, Al, Ca, Mg, Na), while maintaining detection limits in the low(est) ppb-range. NGRIP samples of Greenland Stadial GS22 (~86 ka, depth of ~2690 m), representing a minor δ18O shift (of about ± 4) within the stadial phase of D-O event 22, have been selected and analysed. With a single storm-event resolution capability, seasonal, annual and multiannual periodicity of elements have been identified and will be presented with particular focus on the phasing of the climate proxies. Corresponding results include also an optimized UV-LA-ICPMS methodology, particularly with reference to depth-profiling, assessing contamination of the sample surface and standardization. Finally, the location and distribution of soluble and insoluble micro-inclusions in deep ice have also been assessed concerning the partitioning of elements between grain boundaries and grain interiors. Results show that impurities tend to be concentrated along boundaries in clear (winter) ice, whereas in cloudy bands ('dirtier' ice) they distribute equally between boundaries and interiors. References Müller, W., Shelley, J.M.G., Rasmussen, S.O., 2011. Direct chemical analysis of frozen ice cores by UV-laser ablation ICPMS. J. Anal. At. Spectrom. 26, 2391-2395. Steffensen, J.P., Andersen, K.K., Bigler, M., Clausen, H.B., Dahl-Jensen, D., Fischer, H., Goto-Azuma, K., Hansson, M., Johnsen, S.J., Jouzel, J., Masson-Delmotte, V., Popp, T., Rasmussen, S.O., Rothlisberger, R., Ruth, U., Stauffer, B., Siggaard-Andersen, M.L., Sveinbjornsdottir, A.E., Svensson, A., White, J.W.C., 2008. High-resolution Greenland Ice Core data show abrupt climate change happens in few years. Science 321, 680-684.

High-resolution continuous flow analysis setup for water isotopic measurement from ice cores using laser spectroscopy

NASA Astrophysics Data System (ADS)

Emanuelsson, B. D.; Baisden, W. T.; Bertler, N. A. N.; Keller, E. D.; Gkinis, V.

2014-12-01

Here we present an experimental setup for water stable isotopes (δ18O and δD) continuous flow measurements. It is the first continuous flow laser spectroscopy system that is using Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS; analyzer manufactured by Los Gatos Research - LGR) in combination with an evaporation unit to continuously analyze sample from an ice core. A Water Vapor Isotopic Standard Source (WVISS) calibration unit, manufactured by LGR, was modified to: (1) increase the temporal resolution by reducing the response time (2) enable measurements on several water standards, and (3) to reduce the influence from memory effects. While this setup was designed for the Continuous Flow Analysis (CFA) of ice cores, it can also continuously analyze other liquid or vapor sources. The modified setup provides a shorter response time (~54 and 18 s for 2013 and 2014 setup, respectively) compared to the original WVISS unit (~62 s), which is an improvement in measurement resolution. Another improvement compared to the original WVISS is that the modified setup has a reduced memory effect. Stability tests comparing the modified WVISS and WVISS setups were performed and Allan deviations (σAllan) were calculated to determine precision at different averaging times. For the 2013 modified setup the precision after integration times of 103 s are 0.060 and 0.070‰ for δ18O and δD, respectively. For the WVISS setup the corresponding σAllan values are 0.030, 0.060 and 0.043‰ for δ18O, δD and δ17O, respectively. For the WVISS setup the precision is 0.035, 0.070 and 0.042‰ after 103 s for δ18O, δD and δ17O, respectively. Both the modified setups and WVISS setup are influenced by instrumental drift with δ18O being more drift sensitive than δD. The σAllan values for δ18O of 0.30 and 0.18‰ for the modified (2013) and WVISS setup, respectively after averaging times of 104 s (2.78 h). The Isotopic Water Analyzer (IWA)-modified WVISS setup used during the 2013 Roosevelt Island Climate Evolution (RICE) ice core processing campaign achieved high precision measurements, in particular for δD, with high temporal resolution for the upper part of the core, where a seasonally resolved isotopic signal is preserved.

The Holocene Record of the Arctic Oscillation and a Possible Link to Solar Variability

NASA Astrophysics Data System (ADS)

Rand, J.; Darby, D. A.; Ortiz, J.; Cook, M. Y.; Keigwin, L.

2007-12-01

Detailed Fe grain provenance for a 19.9 meter long piston core (HLY02-JPC16) with about 17.5 m of Holocene sediment provides a sub-century scale resolution of the Arctic Oscillation (AO). The presence of Fe grains matched to Russian shelves fluctuates throughout this core, located 125 km north of Alaska in 1300 m water depth. High amounts of these Fe grains indicate a strong positive AO. While century scale fluctuations occur in the influx of Russian ice-rafted grains at this core site, a significant periodicity of about 1500 years exists that is similar to that of Be-10 in the Greenland ice cores. This begs the question as to how the AO might be linked to solar variations, especially such weak ones. The sources of sea ice rafting throughout the Holocene are compared to Modern sea ice samples and there is generally a good match. There is much greater heterogeneity in sources based on Fe grain provenance than other techniques for sourcing sea ice today. While the Laptev Sea is certainly an important sea ice entrainment area, it is by no means the only one and not even the most important over the long term. This distinction lies with northern Canadian sources, especially the Queen Elizabeth Islands facing the Arctic Ocean. The AO plays a major role in mixing sea ice from Russian and North American sources, especially during ++AO events. At these times, not only does the Trans Polar Drift swing closer to North America introducing sea ice from the Russian shelves such as the Laptev Sea to the Beaufort Gyre (BG), but it also aids in dragging some of the BG ice toward Fram Strait. This BG ice is a mix of North American and Russian ice and thus it is not surprising to find sediment from both sources in ice along the drift path of this ice moving toward Fram Strait.

Large-scale drivers of Caucasus climate variability in meteorological records and Mt El'brus ice cores

NASA Astrophysics Data System (ADS)

Kozachek, Anna; Mikhalenko, Vladimir; Masson-Delmotte, Valérie; Ekaykin, Alexey; Ginot, Patrick; Kutuzov, Stanislav; Legrand, Michel; Lipenkov, Vladimir; Preunkert, Susanne

2017-05-01

A 181.8 m ice core was recovered from a borehole drilled into bedrock on the western plateau of Mt El'brus (43°20'53.9'' N, 42°25'36.0'' E; 5115 m a.s.l.) in the Caucasus, Russia, in 2009 (Mikhalenko et al., 2015). Here, we report on the results of the water stable isotope composition from this ice core with additional data from the shallow cores. The distinct seasonal cycle of the isotopic composition allows dating by annual layer counting. Dating has been performed for the upper 126 m of the deep core combined with 20 m from the shallow cores. The whole record covers 100 years, from 2013 back to 1914. Due to the high accumulation rate (1380 mm w.e. year-1) and limited melting, we obtained isotopic composition and accumulation rate records with seasonal resolution. These values were compared with available meteorological data from 13 weather stations in the region and also with atmosphere circulation indices, back-trajectory calculations, and Global Network of Isotopes in Precipitation (GNIP) data in order to decipher the drivers of accumulation and ice core isotopic composition in the Caucasus region. In the warm season (May-October) the isotopic composition depends on local temperatures, but the correlation is not persistent over time, while in the cold season (November-April), atmospheric circulation is the predominant driver of the ice core's isotopic composition. The snow accumulation rate correlates well with the precipitation rate in the region all year round, which made it possible to reconstruct and expand the precipitation record at the Caucasus highlands from 1914 until 1966, when reliable meteorological observations of precipitation at high elevation began.

Assessment of local and regional climate signals in water stable isotopes and chemistry records from new high resolution shallow ice cores in Adélie Land, Antarctica

NASA Astrophysics Data System (ADS)

Goursaud, Sentia; Masson Delmotte, Valerie; Preunkert, Susanne; Legrand, Michel; Werner, Martin

2017-04-01

Documenting climatic variations in Antarctica is important to characterize natural climate variability and to provide a long-term context for recent changes. For this purpose, ice cores are unique archives providing a variety of proxy records. While water stable isotopes are commonly used to reconstruct past temperatures, their variability may also reflect changes in moisture origin and evaporation conditions. Further information on the origin of air masses can be obtained from aerosols, through the chemical analyses of ice cores. In high accumulation regions, such as the coastal Adélie Land area, the combination of water stable isotope and chemical records is crucial to date ice cores by annual layer counting and assess the associated uncertainty on annual accumulation rates, but may also help to unveil past changes in regional atmospheric circulation. In order to document accumulation in the area from Dumont d'Urville station to the central Antarctic plateau, towards Dome C, the Agence Nationale de la Recherche ASUMA project (Improving the Accuracy of the Surface Mass Balance of Antarctica, 2014-2018) initiated new field campaigns and was successful in obtaining a network of new shallow ice cores in a previously undocumented region. Here, we will present new results from two shallow ice cores drilled in Adélie Land, the S1C1 ice core (67.71 °S, 139.83 °E ,279 m a.s.l.) drilled in January 2007 and the TA192A ice core (66.78 °S, 139.56 °E, 602 m a.s.l.). We have dated the ice cores by combining multi-parameter annual layer counting using major ions and δ18O, as well as reference horizons. This allowed us to estimate very contrasted accumulation rates (respectively 21.8 ± 6.9 cm w.e. y-1 and 73.38±21.9 cm w.e. y-1), averaged respectively over the period from 1946 to 2006 and from 1998 to 2014 . As a result, we have reconstructed annual accumulation rates, isotopic and ion time series, and investigated their characteristics (mean values, trends and periodicities). The high accumulation rates enables us to compare the ice core seasonal variations in δ18O and deuterium excess with outputs from the ECHAM5-wiso atmospheric general circulation model equipped with water stable isotopes and nudged to ERA reanalyses. We have investigated through statistical analyses the relationships between inter-annual variations in our new ice core records with local climatic parameters (near-surface temperature, wind speed and direction, local sea-ice extent), and with large-scale modes of variability (ENSO and PSA2). The first results rule out any significant multi-decadal trend and evidence decadal periodicities already documented in instrumental records. Remarkable years identified in one shallow ice core do not coincide with those identified in the other ice core. No significant correlation with local or regional climate parameters is identified. This suggests that either the ice core signals are dominated by changes in regional atmospheric circulation or that they are strongly affected very local effects of deposition and post deposition, in an area marked by strong katabatic winds.

Glacier-derived permafrost ground ice, Bylot Island, Nunavut

NASA Astrophysics Data System (ADS)

Coulombe, S.; Fortier, D.; Lacelle, D.; Godin, E.; Veillette, A.

2014-12-01

Massive icy bodies are important components of permafrost geosystems. In situ freezing of water in the ground by ice-segregation processes forms most of these icy bodies. Other hypotheses for the origin of massive ice include the burial of ice (e.g. glacier, snow, lake, river, sea). The analysis of ground-ice characteristics can give numerous clues about the geomorphologic processes and the thermal conditions at the time when permafrost developed. Massive underground ice therefore shows a great potential as a natural archive of the earth's past climate. Identifying the origin of massive ice is a challenge for permafrost science since the different types of massive ice remain difficult to distinguish on the sole basis of field observations. There is actually no clear method to accurately assess the origin of massive ice and identification criteria need to be defined. The present study uses physico-chemical techniques to characterize buried glacier ice observed on Bylot Island, Nunavut. Combined to the analysis of cryostratigraphy, massive-ice cores crystallography and high-resolution imagery of the internal structure of the ice cores were obtained using micro-computed tomography techniques. These techniques are well suited for detailed descriptions (shape, size, orientation) of crystals, gas inclusions and sediment inclusions. Oxygen and hydrogen isotopes ratios of massive-ice cores were also obtained using common equilibrium technique. Preliminary results suggest the occurrence of two types of buried massive-ice of glacial origin similar to those found on contemporary glaciers: 1) Englacial ice: clear to whitish ice, with large crystals (cm) and abundant gas bubbles at crystal intersections; 2) Basal glacier ice: ice-rich, banded, micro-suspended to suspended cryostructures and ice-rich lenticular to layered cryostructures, with small ice crystals (mm) and a few disseminated gas bubbles. Glacier-derived permafrost contains antegenetic ice, which is ice that predates the aggradation of the permafrost. Remnants of glacier ice represent unique environmental archives and offer the possibility to reconstruct climate anterior to the formation of permafrost.

Archival processes of the water stable isotope signal in East Antarctic ice cores

NASA Astrophysics Data System (ADS)

Casado, Mathieu; Landais, Amaelle; Picard, Ghislain; Münch, Thomas; Laepple, Thomas; Stenni, Barbara; Dreossi, Giuliano; Ekaykin, Alexey; Arnaud, Laurent; Genthon, Christophe; Touzeau, Alexandra; Masson-Delmotte, Valerie; Jouzel, Jean

2018-05-01

The oldest ice core records are obtained from the East Antarctic Plateau. Water isotopes are key proxies to reconstructing past climatic conditions over the ice sheet and at the evaporation source. The accuracy of climate reconstructions depends on knowledge of all processes affecting water vapour, precipitation and snow isotopic compositions. Fractionation processes are well understood and can be integrated in trajectory-based Rayleigh distillation and isotope-enabled climate models. However, a quantitative understanding of processes potentially altering snow isotopic composition after deposition is still missing. In low-accumulation sites, such as those found in East Antarctica, these poorly constrained processes are likely to play a significant role and limit the interpretability of an ice core's isotopic composition. By combining observations of isotopic composition in vapour, precipitation, surface snow and buried snow from Dome C, a deep ice core site on the East Antarctic Plateau, we found indications of a seasonal impact of metamorphism on the surface snow isotopic signal when compared to the initial precipitation. Particularly in summer, exchanges of water molecules between vapour and snow are driven by the diurnal sublimation-condensation cycles. Overall, we observe in between precipitation events modification of the surface snow isotopic composition. Using high-resolution water isotopic composition profiles from snow pits at five Antarctic sites with different accumulation rates, we identified common patterns which cannot be attributed to the seasonal variability of precipitation. These differences in the precipitation, surface snow and buried snow isotopic composition provide evidence of post-deposition processes affecting ice core records in low-accumulation areas.

Detailed history of atmospheric trace elements from the Quelccaya ice core (Southern Peru) during the last 1200 years

NASA Astrophysics Data System (ADS)

Uglietti, C.; Gabrielli, P.; Thompson, L. G.

2013-12-01

The recent increase in trace element concentrations, for example Cr, Cu, Zn, Ag, Pb, Bi, and U, in polar snow and ice has provided compelling evidence of a hemispheric change in atmospheric composition since the nineteenth century. This change has been concomitant with the expansion of the Industrial Revolution and points towards an anthropogenic source of trace elements in the atmosphere. There are very few low latitude trace element ice core records and these are believed to be sensitive to perturbations of regional significance. To date, these records have not been used to document a preindustrial anthropogenic impact on atmospheric composition at low latitudes. Ice cores retrieved from the tropical Andes are particularly interesting because they have the potential to reveal detailed information about the evolution and environmental consequences of mineral exploitation related to the Pre Inca Civilizations, the Inca Empire (1438-1533 AD) and the subsequent Spanish invasion and dominance (1532-1833 AD). The chemical record preserved in the ice of the Quelccaya ice cap (southern Peruvian Andes) offers the exceptional opportunity to geochemically constrain the composition of the tropical atmosphere at high resolution over the last ~1200 years. Quantification of twenty trace elements (Ag, Al, As, Bi, Cd, Co, Cr, Cu, Fe, Mn, Mo, Pb, Rb, Sb, Sn, Ti, Tl, U, V, and Zn) was performed by ICP-SFMS over 105 m of the Quelccaya North Dome core (5600 m asl, 128.57 m) by analyzing 2450 samples. This provides the first atmospheric trace element record in South America spanning continuously and at high resolution for the time period between 1990 and 790 AD. Ag, As, Bi, Cd, Cr, Co, Cu, Mn, Mo, Sb, Sn, Pb and Zn show increases in concentration and crustal enrichment factor starting at different times between 1450 and 1550 AD, in concomitance with the expansions of the Inca Empire and, subsequently, the Spanish Empire well before the inception of the Industrial Revolution. This indicates that there have been additional anthropogenic sources that have impacted the South American atmosphere during the past ~550 years. Furthermore, As, Bi and Pb record shows, the two most significant increases have occurred in the 20th century, one beginning in ~1905 AD and peaking in the 1920s and the second beginning in ~1955 AD and peaking in the 1970s. Comparison with other trace element records from Greenland and Antarctica reveals concomitant peaks of different amplitude in Pb concentration and crustal enrichment factor, possibly pointing to an unexpected larger than regional scale significance for the Quelccaya ice core record during the last century. In conclusion, the Quelccaya ice core indicates that societal and industrial development influenced the atmospheric composition in South America, from different large scale sources, during the last ~550 years. This is the first time that a low latitude ice core record has been used to reconstruct pre-industrial anthropogenic forcing on the atmosphere.

Radio-echo sounding at Dome C, East Antarctica: A comparison of measured and modeled data

NASA Astrophysics Data System (ADS)

Winter, Anna; Eisen, Olaf; Steinhage, Daniel; Zirizzotti, Achille; Urbini, Stefano; Cavitte, Marie; Blankenship, Donald D.; Wolff, Eric

2016-04-01

The internal layering architecture of ice sheets, detected with radio-echo sounding (RES), contains clues to past ice-flow dynamics and mass balance. A common way of relating the recorded travel time of RES reflections to depth is by integrating a wave-speed distribution. This results in an increasing absolute error with depth. We present a synchronization of RES-internal layers of different radar systems (Alfred Wegener Institute, Center for Remote Sensing of Ice Sheets, Istituto Nazionale di Geofisica e Vulcanologia, British Antarctic Survey and University of Texas Institute for Geophysics) with ice-core records from the Antarctic deep drill site Dome C. Synthetic radar traces are obtained from measurements of ice-core density and conductivity with a 1D model of Maxwell's equations. The reflection peaks of the different radar systems' measurements are shifted by a wiggle-matching algorithm, so they match the synthetic trace. In this way, we matched pronounced internal reflections in the RES data to conductivity peaks with considerably smaller depth uncertainties, and assigned them with the ice-core age. We examine the differences in shifts and resolution of the different RES data to address the question of their comparability and combined analysis for an extensive age-depth distribution.

Arrival of Sulfate Aerosols from Iceland's Laki Eruption (1783-1784 AD) to the Greenland Ice Sheet: A Critical Ice Core Dating Tool

NASA Astrophysics Data System (ADS)

Wei, L.; Mosley-Thompson, E.

2006-12-01

The Laki (Iceland) volcanic event was a basaltic flood lava eruption lasting from June 8, 1783 to February 7, 1784. The timing of the arrival of the sulfate aerosols and volcanic fragments to the Greenland Ice Sheet (GIS) remains uncertain, but is important to confirm as the highly conductive sulfate layer has been consistently used as a time stratigraphic marker (1783 AD) in ice cores collected across Greenland. However, in the GISP2 ice core a few glass shards were found within the annual layer lying just below that containing the sulfate aerosols from Laki suggesting that the ash arrived first, in 1783, while the aerosols arrived the following year [Fiacco et al., 1994]. Additional published ice core results have neither confirmed nor refuted this observation. We have taken advantage of the accurately dated, high temporal resolution ice cores collected by PARCA (Program for Arctic Regional Climate Assessment) to (1) determine more precisely the timing of the arrival of Laki's sulfate aerosols and (2) assess the spatial variability of the excess sulfate contributed by Laki to the GIS. Our results indicate that the sulfate emitted from the Laki eruption most likely arrived on the GIS in the late summer or early fall of 1783 AD. This is also supported by contemporary weather logs and official reports of the appearance of Laki haze [Thordarson and Self, 2003]. The flux of Laki sulfate varies significantly over the GIS, largely as a function of the regional annual accumulation rate. Laki sulfate aerosols also arrived as a single pulse in most of the PARCA cores, suggesting that only a small fraction of the gases emitted from Laki reached the stratosphere. References: Fiacco, R.J.,et al., Atmospheric aerosol loading and transport due to the 1783-84 Laki eruption in Iceland, interpreted from ash particles and acidity in the GISP2 ice core, Quat. Res., 42, 231-240, 1994. Thordarson, T, and S. Self, Atmospheric and environmental effects of the 1783-1784 Laki eruption: A review and reassessment, J. Geophy. Res., 108, 4011-4039, 2003.

Climatic Teleconnections Recorded By Tropical Mountain Glaciers

NASA Astrophysics Data System (ADS)

Thompson, L. G.; Permana, D.; Mosley-Thompson, E.; Davis, M. E.

2014-12-01

Information from ice cores from the world's highest mountains in the Tropics demonstrates both local climate variability and a high degree of teleconnectivity across the Pacific basin. Here we examine recently recovered ice core records from glaciers near Puncak Jaya in Papua, Indonesia, which lie on the highest peak between the Himalayas and the South American Andes. These glaciers are located on the western side of the Tropical Pacific warm pool, which is the "center of action" for interannual climate variability dominated by El Niño-Southern Oscillation (ENSO). ENSO either directly or indirectly affects most regions of Earth and their populations. In 2010, two ice cores measuring 32.13 m and 31.25 m were recovered to bedrock from the East Northwall Firn ice field. Both have been analyzed in high resolution (~3 cm sample length, 1156 and 1606 samples, respectively) for stable isotopes, dust, major ions and tritium concentrations. To better understand the controls on the oxygen isotopic (δ18 O) signal for this region, daily rainfall samples were collected between January 2013 and February 2014 at five weather stations over a distance of ~90 km ranging from 9 meters above sea level (masl) on the southern coast up to 3945 masl. The calculated isotopic lapse rate for this region is 0.24 ‰/100m. Papua, Indonesian ice core records are compared to ice core records from Dasuopu Glacier in the central Himalayas and from Quelccaya, Huascarán, Hualcán and Coropuna ice fields in the tropical Andes of Peru on the eastern side of the Pacific Ocean. The composite of the annual isotopic time series from these cores is significantly (R2 =0.53) related to tropical Pacific sea surface temperatures (SSTs), reflecting the strong linkage between tropical Pacific SSTs associated with ENSO and tropospheric temperatures in the low latitudes. New data on the already well-documented concomitant loss of ice on Quelccaya, Kilimanjaro in eastern Africa and the ice fields near Puncak Jaya reinforce the hypothesis that large-scale tropical processes dominate recent tropical glacier retreat. The observed widespread melting of glaciers is consistent with model predictions of a vertical amplification of temperature, which is documented by increasing isotopic enrichment in ice cores from high elevation glaciers throughout the Tropics.

High-Resolution Physical Properties Logging of the AND-1B Sediment Core - Opportunity for Detecting High-Frequency Signals of Paleoenvironmental Changes

NASA Astrophysics Data System (ADS)

Niessen, F.; Magens, D.; Kuhn, G.; Helling, D.

2008-12-01

Within the ANDRILL-MIS Project, a more than 1200 m long sediment core, dating back to about 13 Ma, was drilled beneath McMurdo Ice Shelf near Ross Island (Antarctica) in austral summer 2006/07 with the purpose of contributing to a better understanding of the Late Cenozoic history of the Antarctic Ice Sheet. One way to approach past ice dynamics and changes in the paleoenvironment quantitatively, is the analysis of high- resolution physical properties obtained from whole-core multi-sensor core logger measurements in which lithologic changes are expressed numerically. This is especially applicable for the repeating sequences of diatomites and diamictites in the upper half of the core with a prominent cyclicity between 140-300 mbsf. Rather abrupt high-amplitude variations in wet-bulk density (WBD) and magnetic susceptibility (MS) reflect a highly dynamic depositional system, oscillating between two main end-member types: a grounded ice sheet and open marine conditions. For the whole core, the WBD signal, ranging from 1.4 kg/cu.m in the diatomites to 2.3 kg/cu.m in diamictites from the lower part of the core, represents the influence of three variables: (i) the degree of compaction seen as reduction of porosities with depth of about 30 % from top to bottom, (ii) the clast content with clasts being almost absent in diatomite deposits and (iii) the individual grain density (GD). GD itself strongly reflects the variety of lithologies as well as the influence of cement (mainly pyrite and carbonate) on the matrix grain density. The calculation of residual porosities demonstrates the strong imprint of glacial loading for especially diamictites from the upper 150 m, pointing to a significant thickness of the overriding Pleistocene ice sheet. MS on the other hand mainly documents a marine vs. terrestrial source of sediments where the latter can be divided into younger local material from the McMurdo Volcanic Province and basement clasts from the Transantarctic Mountains. Values range over several orders of magnitude from <10 (10-5 SI) in the diatomites to 8000 (10-5 SI) in single clasts (mainly dolerite). Synchronous minima and maxima in both WBD and MS support dramatic changes in the depositional environment, driven by oscillations in ice extent in response to global climate fluctuations on orbital timescales. Superimposed on this, small-amplitude variations of high frequency are found within diatomite units. A rhythmic pattern of probably millennial to centennial pacing proposes an additional non-orbital forcing as control on system dynamics, at least during interglacials.

Earth's Climate History from Glaciers and Ice Cores

NASA Astrophysics Data System (ADS)

Thompson, Lonnie

2013-03-01

Glaciers serve both as recorders and early indicators of climate change. Over the past 35 years our research team has recovered climatic and environmental histories from ice cores drilled in both Polar Regions and from low to mid-latitude, high-elevation ice fields. Those ice core -derived proxy records extending back 25,000 years have made it possible to compare glacial stage conditions in the Tropics with those in the Polar Regions. High-resolution records of δ18O (in part a temperature proxy) demonstrate that the current warming at high elevations in the mid- to lower latitudes is unprecedented for the last two millennia, although at many sites the early Holocene was warmer than today. Remarkable similarities between changes in the highland and coastal cultures of Peru and regional climate variability, especially precipitation, imply a strong connection between prehistoric human activities and regional climate. Ice cores retrieved from shrinking glaciers around the world confirm their continuous existence for periods ranging from hundreds to thousands of years, suggesting that current climatological conditions in those regions today are different from those under which these ice fields originated and have been sustained. The ongoing widespread melting of high-elevation glaciers and ice caps, particularly in low to middle latitudes, provides strong evidence that a large-scale, pervasive and, in some cases, rapid change in Earth's climate system is underway. Observations of glacier shrinkage during the 20th and 21st century girdle the globe from the South American Andes, the Himalayas, Kilimanjaro (Tanzania, Africa) and glaciers near Puncak Jaya, Indonesia (New Guinea). The history and fate of these ice caps, told through the adventure, beauty and the scientific evidence from some of world's most remote mountain tops, provide a global perspective for contemporary climate. NSF Paleoclimate Program

What can we learn about the dynamics of DO-events from studying the high resolution ice core records?

NASA Astrophysics Data System (ADS)

Ditlevsen, Peter

2017-04-01

The causes for and possible predictions of rapid climate changes are poorly understood. The most pronounced changes observed, beside the glacial terminations, are the Dansgaard-Oeschger events. Present day general circulation climate models simulating glacial conditions are not capable of reproducing these rapid shifts. It is thus not known if they are due to bifurcations in the structural stability of the climate or if they are induced by stochastic fluctuations. By analyzing a high resolution ice core record we exclude the bifurcation scenario, which strongly suggests that they are noise induced and thus have very limited predictability. Ref: Peter Ditlevsen, "Tipping points in the climate system", in Nonlinear and Stochastic Climate Dynamics, Cambridge University Press (C. Franzke and T. O'Kane, eds.) (2016) P. D. Ditlevsen and S. Johnsen, "Tipping points: Early warning and wishful thinking", Geophys. Res. Lett., 37, L19703, 2010

Surface mass balance of Greenland mountain glaciers and ice caps

NASA Astrophysics Data System (ADS)

Benson, R. J.; Box, J. E.; Bromwich, D. H.; Wahr, J. M.

2009-12-01

Mountain glaciers and ice caps contribute roughly half of eustatic sea-level rise. Greenland has thousands of small mountain glaciers and several ice caps > 1000 sq. km that have not been included in previous mass balance calculations. To include small glaciers and ice caps in our study, we use Polar WRF, a next-generation regional climate data assimilation model is run at grid resolution less than 10 km. WRF provides surface mass balance data at sufficiently high resolution to resolve not only the narrow ice sheet ablation zone, but provides information useful in downscaling melt and accumulation rates on mountain glaciers and ice caps. In this study, we refine Polar WRF to simulate a realistic surface energy budget. Surface melting is calculated in-line from surface energy budget closure. Blowing snow sublimation is computed in-line. Melt water re-freeze is calculated using a revised scheme. Our results are compared with NASA's Gravity Recovery and Climate Experiment (GRACE) and associated error is calculated on a regional and local scale with validation from automated weather stations (AWS), snow pits and ice core data from various regions along the Greenland ice sheet.

Chemistry of microparticles trapped in last glacial period ice of EPICA-DML deep ice core

NASA Astrophysics Data System (ADS)

Nedelcu, Aneta F.; Faria, Sérgio H.; Kipfstuhl, Sepp; Kuhs, Werner F.

2010-05-01

The EDML ice core, drilled within the framework of the European project for Ice Coring in Antarctica, (EPICA), in the interior of Dronning Maud Land, DML, Antarctica (at 75°S, 0°E), is the first deep ice core in the Atlantic sector of the Southern Ocean region that provides higher-resolution atmosphere and climate records for the last glacial period, when compared with other ice cores retrieved from the East Antarctic plateau [1]. The chemical impurities embedded in the ice matrix of an ice sheet are basic proxies for climate reconstruction, and their concentration and composition usually determine the occurrence of distinct (cloudy or clear) strata in the ice sheet structure. The easiest observable impurities in polar ice are air bubbles. But a considerable amount of the impurities trapped inside ice layers are observed as microscopic deposits of solid (soluble or insoluble) particles, not bigger than a few micra in size, called microinclusions. Layers of ice with a high content of (micro)inclusions are in general called cloudy bands and are considered to have been formed from the precipitations deposited during colder periods. Roughly, we expect that the colder the climate during the time the snow accumulated, the cloudier the ice stratum that forms afterwards [2]. Mainly by means of in-situ micro-Raman spectroscopy, it has been shown that in Antarctic glacial ice the soluble microinclusions occur mostly as sulphate and nitrate salts [3], while in Arctic ice more commonly as carbonate salts [4]. These findings could be explained in terms of different aerosol compositions determined by the specific regional environments and climatic conditions [5]. Regarding the insoluble particles that might exist in natural ice, with higher frequency in ice layers formed during glacial type stages, the general findings classify them in the (alumino)silicate mineralogical class [6]. Microinclusions existent in solid samples taken from clear and cloudy ice layers, corresponding to the Marine Isotope Stage 2 of the EDML deep ice core, were subjected to in-situ Raman scattering measurements. The overall results [7] resemble the observations [8] that a high content of sulphate anions could characterize the chemical composition of the aerosols arriving at the EDML ice core drilling site. Many microparticles provided a Raman signal different from what would be expected if only simple compounds were forming them (and dissimilar with those in [3]). For example, it resulted that in the same microinclusion nonequivalent sulphate groups are present (20% of all), or that sulphate and silicate anions coexist (10% of all). On the one hand, this can be explained by a simple post-depositional aggregation of very small inclusions of simple sulphate salts into microclusters. On the other hand the results might be interpreted in terms of aerosol chemistry, when a mixture of sulphate salts could have been already formed prior to deposition. This work will offer answers for questions related with the existence of a post-depositional alteration of the initial impurities deposited in the LGP ice at the EDML ice core drilling site. [1] EPICA community members (2006). One-to-one coupling of glacial climate variability in Greenland and Antarctica, Nature, 444, 195-198. [2] Faria, S.H., Freitag, J., Kipfstuhl, S. (2010) Polar ice structure and the integrity of ice-core paleoclimate records, Quaternary Sci. Rev., 29, 1-2, 338-351. [3] Ohno H., M. Igarashi, T. Hondoh. 2005. Salt inclusions in polar ice core: Location and chemical form of water-soluble impurities, Earth Planet.Sci. Lett., 232, 171-178. [4] Sakurai T., Iizuka Y., Horikawa S., Johnsen S., Dahl-Jensen D., Steffensen J.P., Hondoh T. (2009). Direct observation of salts as micro-inclusions in the Greenland GRIP ice core. J. Glaciol., 55, 193, 777-783. [5] Iizuka Y., Horikawa S., Sakurai T., Johnson S, Dahl-Jensen D., Steffensen J.P., Hondoh T. (2008). A relationship between ion balance and the chemical compounds of salt inclusions found in the Greenland Ice Core Project and Dome Fuji ice cores. J. Geophys. Res., 113, D7, D07303. [6] Iizuka, Y., Miyake T., Hirabayashi M., Suzuki T., Matoba S., Motoyama H., Fujii Y., Hondoh T. (2009). Constituent elements of insoluble and non-volatile particles during the Last Glacial Maximum exhibited in the Dome Fuji (Antarctica) ice core. J. Glaciol., 55, 191, 552-562. [7] Nedelcu A.F., Kipfstuhl S., Faria S.H., Kuhs W.F. Microinclusions in clear and cloudy (MIS2) EDML ice revealed by Raman spectroscopy. In preparation for J. Glaciol. [8] Weller R., Wagenbach D. (2007) Year-round chemical aerosol records in continental Antarctica obtained by automatic samplings. Tellus 59, 755-765.

Coherent Sea Ice Variations in the Nordic Seas and Abrupt Greenland Climate Changes over Dansgaard-Oeschger Cycles

NASA Astrophysics Data System (ADS)

Sadatzki, H.; Berben, S.; Dokken, T.; Stein, R.; Fahl, K.; Jansen, E.

2016-12-01

Rapid changes in sea ice extent in the Nordic Seas may have played a crucial role in controlling the abruptness of ocean circulation and climate changes associated with Dansgaard-Oeschger (D-O) cycles during the last glacial (Li et al., 2010; Dokken et al., 2013). To investigate the role of sea ice for abrupt climate changes, we produced a sea ice record from the Norwegian Sea Core MD99-2284 at a temporal resolution approaching that of ice core records, covering four D-O cycles at ca. 32-41 ka. This record is based on the sea ice diatom biomarker IP25, open-water phytoplankton biomarker dinosterol and semi-quantitative phytoplankton-IP25 (PIP25) estimates. A detailed tephrochronology of MD99-2284 corroborates the tuning-based age model and independently constrains the GS9/GIS8 transition, allowing for direct comparison between our sediment and ice core records. For cold stadials we find extremely low fluxes of total organic carbon, dinosterol and IP25, which points to a general absence of open-water phytoplankton and ice algae production under a near-permanent sea ice cover. For the interstadials, in turn, all biomarker fluxes are strongly enhanced, reflecting a highly productive sea ice edge situation and implying largely open ocean conditions for the eastern Nordic Seas. As constrained by three tephra layers, we observe that the stadial-interstadial sea ice decline was rapid and may have induced a coeval abrupt northward shift in the Greenland precipitation moisture source as recorded in ice cores. The sea ice retreat also facilitated a massive heat release through deep convection in the previously stratified Nordic Seas, generating atmospheric warming of the D-O events. We thus conclude that rapid changes in sea ice extent in the Nordic Seas amplified oceanic reorganizations and were a key factor in controlling abrupt Greenland climate changes over D-O cycles. Dokken, T.M. et al., 2013. Paleoceanography 28, 491-502 Li, C. et al., 2010. Journ. Clim. 23, 5457-5475

Towards a novel continuous sublimation extraction/laser spectroscopy method for greenhouse gas measurements in the oldest ice

NASA Astrophysics Data System (ADS)

Bereiter, Bernhard; Maechler, Lars; Schmitt, Jochen; Walther, Remo; Tuzson, Béla; Scheidegger, Philipp; Emmenegger, Lukas; Fischer, Hubertus

2017-04-01

Ice cores are unique archives of ancient air providing the only direct record of past greenhouse gases - key in reconstructing the roles of greenhouse gases in past climate changes. The European Partnership in Ice Core Sciences (EuroPICS) plans to drill an ice core extending over 1.5 Ma, nearly doubling the time span of the existing greenhouse record and covering the time period of the Mid Pleistocene Transition. The ice covering the time interval from 1-1.5 Ma is expected to be close to the bedrock and, due to glacial flow, extremely thinned. A 10,000 yr glacial/interglacial transition can be compressed in 1 m of ice. The targeted 100 yr resolution therefore constrains the sample size to 15-30 g containing only 1-2ml STP air. Within the deepSlice project we aim to unlock such atmospheric archives in extremely thinned ice by developing a novel coupled semi-continuous sublimation extraction/laser spectroscopy system. Vacuum sublimation, with an infrared source, has been chosen as extraction method as it allows 100% gas extraction of all gas species from ice without changing the isotopic composition of CO2. In order to reduce ice waste and accelerate sample throughput, we are building a sublimation extraction system that is able to continuously sublimate an ice-core section and subsequently collect discrete full air samples. For the gas analytics, we develop a custom-made mid-infrared laser spectrometer allowing simultaneous measurement of the CO2, CH4 and N2O concentrations as well as the isotopic composition of CO2 on air samples of only 1-2 ml STP. The two systems will be coupled via cryo-trapping of the sample air in dip tubes, followed by expansion of the sample air into the laser spectrometer. Due to the nondestructive laser technique, the air sample can be recollected and reused for further analytics.

Recent and past dust concentrations and fluxes from a developing array of Antarctic ice cores

NASA Astrophysics Data System (ADS)

McConnell, J. R.; Anschütz, H.; Baggenstos, D.; Das, S. B.; Isaksson, E. D.; Lawrence, R.; Layman, L.; Maselli, O.; Severinghaus, J. P.; Sigl, M.; Petit, J. R.; Grente, B.

2012-12-01

Continental dust is an important component of climate forcing, both because of its interaction with incoming solar and outgoing long wave radiation and because of its impact on albedo when deposited on bright surfaces such as fresh snow. Continental dust may also play an important role in ocean fertilization and carbon sequestration. Because the lifetime of dust aerosol in the atmosphere is only on the order of days to weeks, spatial and temporal variability in concentrations and fluxes is high and understanding of recent and long term changes is limited. Here we present and discuss detailed continuous, high depth resolution measurements of a range of dust proxies in a developing array of Antarctic ice cores. Included are traditional proxies such as non-sea-salt (nss) calcium and insoluble particle number and size distribution as well as less traditional proxies such as aluminum, vanadium, manganese, rare earth elements, and nss uranium which together provide important insights into how dust sources and transport may have changed in the past. The array includes a number of new shallow ice core records from East and West Antarctica spanning recent centuries to millennia, as well as Last Glacial Maximum to early Holocene records from the deep WAIS Divide and Taylor Glacier Horizontal ice cores.

Bacterial responses to environmental change on the Tibetan Plateau over the past half century.

PubMed

Liu, Yongqin; Priscu, John C; Yao, Tandong; Vick-Majors, Trista J; Xu, Baiqing; Jiao, Nianzhi; Santibáñez, Pamela; Huang, Sijun; Wang, Ninglian; Greenwood, Mark; Michaud, Alexander B; Kang, Shichang; Wang, Jianjun; Gao, Qun; Yang, Yunfeng

2016-06-01

Climate change and anthropogenic factors can alter biodiversity and can lead to changes in community structure and function. Despite the potential impacts, no long-term records of climatic influences on microbial communities exist. The Tibetan Plateau is a highly sensitive region that is currently undergoing significant alteration resulting from both climate change and increased human activity. Ice cores from glaciers in this region serve as unique natural archives of bacterial abundance and community composition, and contain concomitant records of climate and environmental change. We report high-resolution profiles of bacterial density and community composition over the past half century in ice cores from three glaciers on the Tibetan Plateau. Statistical analysis showed that the bacterial community composition in the three ice cores converged starting in the 1990s. Changes in bacterial community composition were related to changing precipitation, increasing air temperature and anthropogenic activities in the vicinity of the plateau. Collectively, our ice core data on bacteria in concert with environmental and anthropogenic proxies indicate that the convergence of bacterial communities deposited on glaciers across a wide geographical area and situated in diverse habitat types was likely induced by climatic and anthropogenic drivers. © 2015 Society for Applied Microbiology and John Wiley & Sons Ltd.

Eemian and penultimate transition reflected in the chemical ice core record from Dome C

NASA Astrophysics Data System (ADS)

Bigler, M.; Lambert, F.; Stauffer, B.; Röthlisberger, R.; Wolff, E. W.

2003-04-01

Within the scope of the European Project for Ice Coring in Antarctica (EPICA) chemical analyses have been done along the Dome C ice core. Among other substances, Ca2+, dust, Na+, NH_4{}+, NO_3{}- and electrolytical melt water conductivity have been measured at 1 cm resolution with the Bern Continuous Flow Analysis (CFA) system. Here we present new data from the Eemian and the preceding transition covering an age interval from approximately 180 kyr to 110 kyr before present. This sequence is compared with the Holocene and the last transition, mainly with emphasis on terrestrial and marine tracers. Concentration levels for the two periods compare quite well, but the general shape differs considerably. The changes in dust input to Dome C seemed to have been much more abrupt during the penultimate transition than during the last transition (18 to 15 kyr BP). This may reflect different conditions and/or processes in the dust source region.

A new 10Be record recovered from an Antarctic ice core: validity and limitations to record the solar activity

NASA Astrophysics Data System (ADS)

Baroni, Mélanie; Bard, Edouard; Aster Team

2015-04-01

Cosmogenic nuclides provide the only possibility to document solar activity over millennia. Carbon-14 (14C) and beryllium-10 (10Be) records are retrieved from tree rings and ice cores, respectively. Recently, 14C records have also proven to be reliable to detect two large Solar Proton Events (SPE) (Miyake et al., Nature, 2012, Miyake et al., Nat. Commun., 2013) that occurred in 774-775 A.D. and in 993-994 A.D.. The origin of these events is still under debate but it opens new perspectives for the interpretation of 10Be ice core records. We present a new 10Be record from an ice core from Dome C (Antarctica) covering the last millennium. The chronology of this new ice core has been established by matching volcanic events on the WAIS Divide ice core (WDC06A) that is the best dated record in Antarctica over the Holocene (Sigl et al., JGR, 2013, Sigl et al., Nat. Clim. Change, 2014). The five minima of solar activity (Oort, Wolf, Spörer, Maunder and Dalton) are detected and characterized by a 10Be concentration increase of ca. 20% above average in agreement with previous studies of ice cores drilled at South Pole and Dome Fuji in Antarctica (Bard et al., EPSL, 1997; Horiuchi et al., Quat. Geochrono., 2008) and at NGRIP and Dye3 in Greenland (Berggren et al., GRL, 2009). The high resolution, on the order of a year, allows the detection of the 11-year solar cycle. Sulfate concentration, a proxy for volcanic eruptions, has also been measured in the very same samples, allowing a precise comparison of both 10Be and sulfate profiles. We confirm the systematic relationship between stratospheric eruptions and 10Be concentration increases, first evidenced by observations of the stratospheric volcanic eruptions of Agung in 1963 and Pinatubo in 1991 (Baroni et al., GCA, 2011). This relationship is due to an increase in 10Be deposition linked to the role played by the sedimentation of volcanic aerosols. In the light of these new elements, we will discuss the limitations and possibilities of using a 10Be ice core record to detect SPE and the variations of past solar activity.

Abrupt Atmospheric Methane Increases Associated With Hudson Strait Heinrich Events

NASA Astrophysics Data System (ADS)

Rhodes, R.; Brook, E.; Chiang, J. C. H.; Blunier, T.; Maselli, O. J.; McConnell, J. R.; Romanini, D.; Severinghaus, J. P.

2015-12-01

The drivers of abrupt climate change during the Last Glacial Period are not well understood. While Dansgaard-Oeschger (DO) cycles are thought to be linked to variations in the strength of the Atlantic Meridional Ocean Circulation (AMOC), it is not clear how or if Heinrich Events—extensive influxes of icebergs into the North Atlantic Ocean that impacted global climate and biogeochemistry—are related. An enduring problem is the difficultly in dating iceberg rafted debris deposits that typically lack foraminifera. Here we present an ultra-high resolution record of methane from the West Antarctic Ice Sheet Divide ice core at unprecedented, continuous temporal resolution from 67.2-9.8 ka BP, which we propose constrains the timing of Heinrich events. Our methane record essentially mirrors Greenland ice core stable isotope variability across D-O events, except during Heinrich stadials 1, 2, 4 and 5. Partway through these stadials only, methane increases abruptly and rapidly, as at the onset of a D-O event but Greenland temperature exhibits no equivalent response. Speleothem records exhibit signatures of drought in the Northern extra-tropics and intensified monsoonal activity over South America at these times. We use a simple heuristic model to propose that cold air temperatures and extensive sea ice in the North, resulting from Heinrich events, caused extreme reorganization of tropical hydroclimate. This involved curtailment of the seasonal northerly migration of tropical rain belts, leading to intensification of rainfall over Southern Hemisphere tropical wetlands, thus allowing production of excess methane relative to a 'normal' Greenland stadial. We note that this mechanism can operate if AMOC is already in a slowed state when a Heinrich event occurs, as paleo-evidence suggests it was. Heinrich events and associated sea ice cover would therefore act to prolong the duration of this AMOC state. Our findings place the big four Heinrich events of Hudson Strait origin firmly within ice core chronologies and suggest that their impacts on AMOC and tropical hydroclimate persisted for 740-1520 yr.

Variability of Black Carbon Deposition to the East Antarctic Plateau, 1800-2000 AD

NASA Technical Reports Server (NTRS)

Bisiaux, M. M.; Edwards, R.; McConnell, J. R.; Albert, M. R.; Anschutz, H.; Neumann, T. A.; Isaksson, E.; Penner, J. E.

2012-01-01

Refractory black carbon aerosols (rBC) from biomass burning and fossil fuel combustion are deposited to the Antarctic ice sheet and preserve a history of emissions and long-range transport from low- and mid-latitudes. Antarctic ice core rBC records may thus provide information with respect to past combustion aerosol emissions and atmospheric circulation. Here, we present six East Antarctic ice core records of rBC concentrations and fluxes covering the last two centuries with approximately annual resolution (cal. yr. 1800 to 2000). The ice cores were drilled in disparate regions of the high East Antarctic ice sheet, at different elevations and net snow accumulation rates. Annual rBC concentrations were log-normally distributed and geometric means of annual concentrations ranged from 0.10 to 0.18 m cro-g/kg. Average rBC fluxes were determined over the time periods 1800 to 2000 and 1963 to 2000 and ranged from 3.4 to 15.5 m /a and 3.6 to 21.8 micro-g/sq m/a, respectively. Geometric mean concentrations spanning 1800 to 2000 increased linearly with elevation at a rate of 0.025 micro-g/kg/500 m. Spectral analysis of the records revealed significant decadal-scale variability, which at several sites was comparable to decadal ENSO variability.

Frozen Nature - A high-alpine ice core record reveals fire and vegetation dynamics in Western Europe over the past millennium

NASA Astrophysics Data System (ADS)

Brügger, S.; Gobet, E.; Sigl, M.; Osmont, D.; Schwikowski, M.; Tinner, W.

2017-12-01

Wild fires are an ecological disturbance agent across ecosystems, driving vegetation dynamics and resulting in disruption of habitats (Moritz et al. 2014).We analyze pollen and spores as proxies for vegetation composition, structure and agricultural activity, microscopic charcoal as a proxy for fire activity, and spheroidal carbonaceous particles (SCPs or soots) as a proxy for fossil fuel combustion which preserve in ice cores over millennia (Eichler et al. 2011).Our high-alpine ice core (4452 m a.s.l.) from Colle Gnifetti, Swiss Alps is located in the center of Western Europe, thus allowing to assess vegetation and societal responses to climatic change and wildfire disturbance on a subcontinental scale. The record covers the last millennium with an excellent chronological control (Jenk et al. 2009, Sigl et al. 2009), particularly over the most recent 200 years - the period that experienced important climatic changes and an increasing globalization of economy.The Colle Gnifetti record reflects large scale impacts such as extreme weather, societal innovations, agricultural crises and pollution of the industrial period in Western Europe. Pollution tracers occur in the record as early as 1750 AD and coincide with the shift to large-scale maize production in Northern Italy and with increased fire activity. Our multiproxy record may allow desentagling the role of climate and humans for vegetation composition and biomass burning. The attribution of causes may significantly advance our understanding of future vegetation and fire dynamics under global change conditions. To our knowledge we present the first long-term high-resolution palynological record of a high elevation ice core in Europe.REFERENCESEichler et al. (2011): An ice-core based history of Siberian forest fires since AD 1250. Quaternary Science Reviews, 30(9), 1027-1034.Jenk et al. (2009): A novel radiocarbon dating technique applied to an ice core from the Alps indicating late Pleistocene ages. Journal of Geophysical Research: Atmospheres, 114(D14).Moritz et al. (2014): Learning to coexist with wildfire. Nature, 515(7525), 58-66.Sigl et al. (2009): Towards radiocarbon dating of ice cores. Journal of Glaciology, 55(194), 985-996.

Glacigenic landforms and sediments of the Western Irish Shelf

NASA Astrophysics Data System (ADS)

McCarron, Stephen; Monteys, Xavier; Toms, Lee

2013-04-01

Vibrocoring of possible glacigenic landforms identified from high resolution bathymetric coverage of the Irish Shelf by the Irish National Seabed Survey (INSS) has provided several clusters of short (<3m) cores that, due to a regional post-glacial erosional event, comprise last glacial age stratigraphies. In addition, new shallow seismic data and sedimentological information from across the Western Irish Shelf provide new insights into aspects of the nature, timing and pattern of shelf occupation by grounded lobate extensions of the last Irish Ice Sheet. Restricted chronological control of deglacial sequences in several cores indicates that northern parts of the western mid-shelf (south of a prominent outer Donegal Bay ridge) were ice free by ~24 ka B.P., and that ice had also probably retreated from outer shelf positions (as far west as the Porcupine Bank) at or before this time.

Chemical compositions of sulfate and chloride salts over the last termination reconstructed from the Dome Fuji ice core, inland Antarctica

NASA Astrophysics Data System (ADS)

Oyabu, Ikumi; Iizuka, Yoshinori; Uemura, Ryu; Miyake, Takayuki; Hirabayashi, Motohiro; Motoyama, Hideaki; Sakurai, Toshimitsu; Suzuki, Toshitaka; Hondoh, Takeo

2014-12-01

The flux and chemical composition of aerosols impact the climate. Antarctic ice cores preserve the record of past atmospheric aerosols, providing useful information about past atmospheric environments. However, few studies have directly measured the chemical composition of aerosol particles preserved in ice cores. Here we present the chemical compositions of sulfate and chloride salts from aerosol particles in the Dome Fuji ice core. The analysis method involves ice sublimation, and the period covers the last termination, 25.0-11.0 thousand years before present (kyr B.P.), with a 350 year resolution. The major components of the soluble particles are CaSO4, Na2SO4, and NaCl. The dominant sulfate salt changes at 16.8 kyr B.P. from CaSO4, a glacial type, to Na2SO4, an interglacial type. The sulfate salt flux (CaSO4 plus Na2SO4) inversely correlates with δ18O in Dome Fuji over millennial timescales. This correlation is consistent with the idea that sulfate salt aerosols contributed to the last deglacial warming of inland Antarctica by reducing the aerosol indirect effect. Between 16.3 and 11.0 kyr B.P., the presence of NaCl suggests that winter atmospheric aerosols are preserved. A high NaCl/Na2SO4 fraction between 12.3 and 11.0 kyr B.P. indicates that the contribution from the transport of winter atmospheric aerosols increased during this period.

Capillary ion chromatography with on-column focusing for ultra-trace analysis of methanesulfonate and inorganic anions in limited volume Antarctic ice core samples.

PubMed

Rodriguez, Estrella Sanz; Poynter, Sam; Curran, Mark; Haddad, Paul R; Shellie, Robert A; Nesterenko, Pavel N; Paull, Brett

2015-08-28

Preservation of ionic species within Antarctic ice yields a unique proxy record of the Earth's climate history. Studies have been focused until now on two proxies: the ionic components of sea salt aerosol and methanesulfonic acid. Measurement of the all of the major ionic species in ice core samples is typically carried out by ion chromatography. Former methods, whilst providing suitable detection limits, have been based upon off-column preconcentration techniques, requiring larger sample volumes, with potential for sample contamination and/or carryover. Here, a new capillary ion chromatography based analytical method has been developed for quantitative analysis of limited volume Antarctic ice core samples. The developed analytical protocol applies capillary ion chromatography (with suppressed conductivity detection) and direct on-column sample injection and focusing, thus eliminating the requirement for off-column sample preconcentration. This limits the total sample volume needed to 300μL per analysis, allowing for triplicate sample analysis with <1mL of sample. This new approach provides a reliable and robust analytical method for the simultaneous determination of organic and inorganic anions, including fluoride, methanesulfonate, chloride, sulfate and nitrate anions. Application to composite ice-core samples is demonstrated, with coupling of the capillary ion chromatograph to high resolution mass spectrometry used to confirm the presence and purity of the observed methanesulfonate peak. Copyright © 2015 Elsevier B.V. All rights reserved.

Striking similarities in temporal changes to spring sea ice occurrence across the central Canadian Arctic Archipelago over the last 7000 years

NASA Astrophysics Data System (ADS)

Belt, Simon T.; Vare, Lindsay L.; Massé, Guillaume; Manners, Hayley R.; Price, John C.; MacLachlan, Suzanne E.; Andrews, John T.; Schmidt, Sabine

2010-12-01

A 7000 year spring sea ice record for Victoria Strait (ARC-4) and Dease Strait (ARC-5) in the Canadian Arctic Archipelago (CAA) has been determined by quantification of the sea ice diatom-derived biomarker IP 25 in two marine sediment piston cores obtained in 2005. The chronologies of the ARC-4 and ARC-5 cores were determined using a combination of 14C AMS dates obtained from macrobenthic fossils and magnetic susceptibility measurements. The ages of the tops of the piston cores were estimated by matching chemical and physical parameters with those obtained from corresponding box cores. These analyses revealed that, while the top of the ARC-4 piston core was estimated to be essentially modern (ca. 60 cal yr BP), a few hundred years of sediment appeared to be absent from the ARC-5 piston core. Downcore changes to IP 25 fluxes for both cores were interpreted in terms of variations in spring sea ice occurrence, and correlations between the individual IP 25 flux profiles for Victoria Strait, Dease Strait and Barrow Strait (reported previously) were shown to be statistically significant at both 50 and 100-year resolutions. The IP 25 data indicate lower spring sea ice occurrences during the early part of the record (ca. 7.0-3.0 cal kyr BP) and for parts of the late Holocene (ca. 1.5-0.8 cal kyr BP), especially for the two lower latitude study locations. In contrast, higher spring sea ice occurrences existed during ca. 3.0-1.5 cal kyr BP and after ca. 800 cal yr BP. The observation of, consecutively, lower and higher spring sea ice occurrence during two periods of the late Holocene, coincides broadly with the Medieval Warm Period and Little Ice Age epochs, respectively. The IP 25 data are complemented by particle size and mineralogical data, although these may alternatively reflect changes in sea level at the study sites. The IP 25 data are also compared to previous proxy-based determinations of palaeo sea ice and palaeoclimate for the CAA, including those based on bowhead whale remains and dinocyst assemblages. The spatial consistency in the proxy data which, most notably, indicates an increase in spring sea ice occurrence around 3 cal kyr BP, provides a potentially useful benchmark for the termination of the Holocene Thermal Maximum for the central CAA.

Late-glacial and Holocene history of changes in Quelccaya Ice Cap, Peru

NASA Astrophysics Data System (ADS)

Kelly, M. A.; Lowell, T. V.; Schaefer, J. M.; Finkel, R. C.

2008-12-01

Quelccaya Ice Cap in the southeastern Peruvian Andes (~13-14° S latitude) is an icon for climate change. Its rapidly receding outlet, Qori Kalis Glacier, has been monitored since the 1970's. Cores from Quelccaya Ice Cap provide high-resolution information about temperature and precipitation during the past 1,500 years. We extend the understanding of past changes in Quelccaya Ice Cap based on mapping and dating of glacial moraines and associated deposits. Our results include fifty 10Be ages of moraines and bedrock as well as twenty-nine 14C ages of organic material associated with moraines. These results form the basis of a chronology of changes in Quelccaya Ice Cap from ~16,000 yr BP to late Holocene time. Results from 10Be and 14C dating indicate that Quelccaya Ice Cap experienced a significant advance at 12,700-11,400 yr BP. Subsequent to this advance, the ice margin deposited at least three recessional moraine sets. Quelccaya Ice Cap receded to near its present-day margin by ~10,000 yr BP. Neoglacial advances began by ~3,000 yr BP and culminated with a maximum advance during the Little Ice Age. This chronology fits well with prior work which indicates a restricted Quelccaya Ice Cap during middle Holocene time. Moreover, the overlap between moraine and ice core data for the last 1,500 years provides a unique opportunity to assess the influences of temperature and precipitation on past ice cap extents.

Chronological refinement of an ice core record at Upper Fremont Glacier in south central North America

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schuster, Paul F.; White, David E.; Naftz, David L.

2000-02-27

The potential to use ice cores from alpine glaciers in the midlatitudes to reconstruct paleoclimatic records has not been widely recognized. Although excellent paleoclimatic records exist for the polar regions, paleoclimatic ice core records are not common from midlatitude locations. An ice core removed from the Upper Fremont Glacier in Wyoming provides evidence for abrupt climate change during the mid-1800s. Volcanic events (Krakatau and Tambora) identified from electrical conductivity measurements (ECM) and isotopic and chemical data from the Upper Fremont Glacier were reexamined to confirm and refine previous chronological estimates of the ice core. At a depth of 152 mmore » the refined age-depth profile shows good agreement (1736{+-}10 A.D.) with the {sup 14}C age date (1729{+-}95 A.D.). The {delta}{sup 18}O profile of the Upper Fremont Glacier (UFG) ice core indicates a change in climate known as the Little Ice Age (LIA). However, the sampling interval for {delta}{sup 18}O is sufficiently large (20 cm) such that it is difficult to pinpoint the LIA termination on the basis of {delta}{sup 18}O data alone. Other research has shown that changes in the {delta}{sup 18}O variance are generally coincident with changes in ECM variance. The ECM data set contains over 125,000 data points at a resolution of 1 data point per millimeter of ice core. A 999-point running average of the ECM data set and results from f tests indicates that the variance of the ECM data decreases significantly at about 108 m. At this depth, the age-depth profile predicts an age of 1845 A.D. Results indicate the termination of the LIA was abrupt with a major climatic shift to warmer temperatures around 1845 A.D. and continuing to present day. Prediction limits (error bars) calculated for the profile ages are {+-}10 years (90% confidence level). Thus a conservative estimate for the time taken to complete the LIA climatic shift to present-day climate is about 10 years, suggesting the LIA termination in alpine regions of central North America may have occurred on a relatively short (decadal) timescale. (c) 2000 American Geophysical Union.« less

Greenhouse to Icehouse Antarctic Paleoclimate and Ice History from George V Land and Adélie Land Shelf Sediments

NASA Astrophysics Data System (ADS)

Williams, T.; Escutia, C.; De Santis, L.; O'Brien, P.; Pekar, S. F.; Brinkhuis, H.; Domack, E. W.

2013-12-01

Along the George V and Adélie Land continental shelf of East Antarctica, shallowly-buried strata contain a record of Antarctica's climate and ice history from the lush forests of the Eocene greenhouse to the dynamic ice sheet margins of the Neogene. Short piston cores and dredges have recovered Early Cretaceous and Eocene organic-rich sediment at the seabed, and in 2010, IODP Expedition 318 recovered earliest Oligocene and early Pliocene subglacial and proglacial diamictites. However, challenging ice and drilling conditions from the JOIDES Resolution on the shelf resulted in poor core recovery and sites had to be abandoned before the stratigraphic targets could be reached. Therefore, in a new IODP drilling proposal submitted earlier this year, we propose to use the MeBo sea bed drill for improved core recovery and easier access to the shelf, and drill a stratigraphic transect of shallow (~80m) holes. To investigate the evolution of the Antarctic ice sheet in this sector, we target strata above and below regional erosional and downlap surfaces to date and characterize major episodes of ice sheet advance and retreat. These direct records of ice extent on the shelf can be set in the context of Southern Ocean records of temperature, ice-rafted debris (IRD) and latitudinal fluctuations of the opal belt, and hence we can relate ice sheet evolution to paleoclimate conditions. Targets include possible late Eocene precursor glaciations, the Eocene/Oligocene boundary erosion surface, Oligocene and Miocene ice extents, and ice margin fluctuations in the Pliocene. At the Cretaceous and Eocene proposed sites, marine and terrestrial temperature proxies and palynological records will provide information on high-latitude paleoenvironments and pole-equator temperature gradients. Here we present existing data from the area and the proposed new drill sites. The ice and climate history of the George V and Adélie Land margin can provide warm-world scenarios to help understand ice sheet instability in analogous future warm climates.

Interglacial Greenland aerosol deposition: comparison of continuous high resolution chemical ice core records from the Eemian and Holocene

NASA Astrophysics Data System (ADS)

Gfeller, Gideon; Bigler, Matthias; Schüpbach, Simon; Mini, Olivia; Leuenberger, Daiana; Fischer, Hubertus

2014-05-01

Earth's climate system has been oscillating over the last million years between cold glacials and warm interglacials, leaving the imprints of their climate states in form of isotopes variations and chemical impurities in polar ice caps. In the course of the North Greenland Eemian Ice Drilling (NEEM) project, the NEEM ice core has been entirely analysed in very high depth resolution with a Continuous Flow Analysis (CFA) system for the concentrations of chemical aerosol tracers in the ice. Only in the brittle ice zone (600-1100 m depth equivalent to the time interval 3000-8000 years before present) most of the ice had to be discarded due to multifractured core material. Based on the unique reconstructed age scale to unfold the stratigraphically disturbed part from about 2200 m depth downwards (NEEM community members, Nature, 2013), we are able to present the first Greenland chemistry record over the entire last interglacial, the so called Eemian period (about 128'000 to 115'000 years ago). As the Eemian is believed to have been 4 to 8 degrees C warmer than the modern climate, it can be used as an analogue for our present warming climate and, thus, contributes to a better understanding of processes causing natural variations. By means of the chemistry records we are able to assess the natural variability of Greenland Eemian climate and gain insight in its biogeochemical state. Here, short-term variability as well as long term trends of soluble chemical impurities in the Eemian are investigated and compared with those in the Holocene. Changes of organic processes in soils and biomass burning for example are assessed through soluble ammonium and nitrate concentrations. In comparison to the Holocene, ammonium concentrations were about 25% higher during the Eemian. Nitrate, on the other hand, shows about 25% lower concentrations. Sodium concentrations, reflecting changes in sea salt aerosol, are about 35% lower during the Eemian than during the Holocene. Calcium, generally regarded as a long range transport proxy, shows similar concentration during both periods.

Long-distance relationship between large-scale tropical SSTs and ice core-derived oxygen isotopic records in the Third Pole Region

NASA Astrophysics Data System (ADS)

Thompson, L. G.; Yao, T.; Mosley-Thompson, E. S.; Lin, P.

2012-12-01

The tropical hydrological cycle is a key factor coupling isotopic records from ice core, speleothem and lake records with tropical SSTs and the vertical amplification of temperature in the Tropics. Stable isotopic ratios, particularly of oxygen, preserved in glacier ice provide high resolution records of climate changes over long time periods. In polar ice sheets the isotopic signal is driven primarily by temperature while in low-latitudes it depends on a variety of hydrologic and thermal influences in the broad geographic region that supplies moisture to the mountain glaciers. The strong correlation between ice core-derived isotopic records throughout the low- and mid-latitudes and tropical SSTs likely reflects the dominance of tropical evaporation in the flux of water vapor to the atmosphere and provides a possible explanation for the large-scale isotopic links among low- and mid-latitude paleoclimate records. Many low- to mid-latitude ice fields provide continuous, annually-resolved proxy records of climatic and environmental variability recorded by many preserved and measurable parameters including oxygen and hydrogen isotopic ratios and net mass balance (accumulation). These records present an opportunity to examine the nature of climate variability in these regions in greater detail and to extract new information about long-distance relationships in the climate system. Understanding these relationships is essential for proper interpretation of the isotopic records archived in glaciers, lakes, speleothems and other paleo-archives in the Third Pole (TP) Region. Here we compare high resolution records from Dasuopu Glacier in the Himalaya, a speleothem record from Wanxiang Cave in Gansu Province on the TP and the annually resolved ice core records from the Quelccaya Ice Cap in the tropical Andes of South America. The purpose is to explore the role of long-distance processes in determining the isotopic composition of paleo archives on the TP. Running correlations between the Quelccaya and Dasuopu records over the last 500 years reveal that through time isotopes and net balance are both positively and negatively correlated over multi-decades scales while correlation of the annual values over the entire period is quite low. The annual isotopic records are strongly correlated with tropical Pacific SSTs (R2 = 0.55) reflecting the strong linkage between tropical Pacific SSTs associated with ENSO and tropospheric temperatures in the low latitudes. The well-documented contemporaneous loss of ice cover on Quelccaya, Naimona'nyi, Kilimanjaro in eastern Africa and the ice fields near Puncak Jaya in Papua, Indonesia likely reflects the dominance of large-scale processes. Moreover, such widespread melting is consistent with model predictions for a vertical amplification of temperature in the tropics and with increasing isotopic enrichment with elevation across the Third Pole Region over the last 100 years.

Multisite high resolution measurements of carbon monoxide along Greenland ice cores: evidence for in-situ production and potential for atmospheric reconstruction

NASA Astrophysics Data System (ADS)

Faïn, Xavier; Chappellaz, Jérôme; Rhodes, Rachael; Stowasser, Christopher; Blunier, Thomas; McConnell, Joseph; Brook, Edward; Desbois, Thibault; Romanini, Daniele

2014-05-01

Carbon monoxide (CO) is the principal sink for hydroxyl radicals (OH) in the troposphere. Consequently, changes in atmospheric CO levels can considerably perturb the oxidizing capacity of the atmosphere, affecting mixing ratios of a host of chemical species oxidized by OH, including methane. In addition, CO variations (and changes in its stable isotopic composition) are expected to be good tracers of changes in biomass burning emissions. Investigating past mixing ratios of carbon monoxide is thus a promising approach towards reducing uncertainty related to the past oxidative capacity of the atmosphere and biogeochemical cycling of methane. Recent developments in optical spectrometry (Optical Feedback Cavity Enhanced Absorption Spectrometry, OFCEAS), combined with continuous flow analysis (CFA) systems, allow efficient, precise measurements of CO concentrations in ice cores. Coupling our OFCEAS spectrometer with the CFA melter operated at DRI (Reno, USA) provided the first continuous CO measurements along the NEEM (Greenland) core covering the last 1800 yr at an unprecedented resolution. Although the most recent section of this record (i.e., since 1700 AD) agreed with existing discrete CO measurements from the Eurocore ice core and the deep NEEM firn, it was difficult to interpret in terms of atmospheric CO variation due to high frequency, high amplitudes spikes related to in-situ production (Faïn et al., Climate of the Past Discussion). During a recent 8-week analytical campaign, three different ice archives from Greenland were melted on the DRI CFA and analyzed continuously for CO with the OFCEAS spectrometer: (i) the D4 core (spanning the last 170 yr), (ii) the NEEM core (extending the existing record from 200 AD to 800 BC), and (iii) the Tunu core (spanning the last 1800 yr). Although in-situ production of CO is observed at all sites, these new records reveal different CO patterns and trends. This multisite approach allows us to better characterize the processes involved in CO in-situ production by evaluating the influence of site-specific factors such as surface accumulation rate (10, 22 and 41 cm ice yr-1 for Tunu, NEEM, and D4 respectively), surface temperature, or aerosols loading (with e.g., median black carbon concentration ranging from 0.9 to 2.3 ng g-1 among the investigated sites). However, a quantitative understanding of the past evolution of atmospheric CO above Greenland remains challenging due to the existence of these artifacts.

The Climate and Human Impacts of Major Explosive Volcanism AD670-730, A Multi-proxy Assessment

NASA Astrophysics Data System (ADS)

Gao, C.; Ludlow, F.

2013-12-01

Chronologically secure volcanic events can provide an important tool to improve ice core dating as well as our understanding of volcano-climate responses. However, there is a substantial lack of reference horizons for ice-core dating during the first millennium, excepting the Taupo (New Zealand, AD186×10) and Vesuvius (Italy, AD 79) eruptions. In this exploratory case-study, we use a total of 20 ice core records, 9 from the Arctic and 11 from the Antarctic, together with historical records to examine the occurrence and climatic impact of explosive volcanism, AD 670-730. Sulfate signals comparable in magnitude to the sizeable 1815 Tambora eruption are detected in all of the ice-core time series, with different cores attributing the timing of eruptions to AD 676×2, 688×2, or 700×2, respectively. Historical records of widespread frost damage, anomalously warm winters, drought, famine and mortality from Chinese, European and Middle Eastern chronicles suggest substantial climate and social perturbations during AD 677-685 and AD 699-709. The distinctive double-peak feature seen in the majority of the volcanic signals from both poles at AD 676×2 and AD 688×2 suggests that these signals may belong to the same eruption, with those cores dating the signals to c.AD 676 generally considered to have a more precise chronology. Combining the evidence from natural and historical anthropogenic records and taking into account uncertainties (e.g. resolution, dating accuracy) associated with individual ice cores, we propose that a (most-likely) low-latitude eruption took place around AD676, followed by another possible eruption around AD700, identifiable by the significant acidity in polar ice-caps and historical documents. Unique historical observations of 'blood rain' in Ireland (often associated with Saharan sand deposition, but also plausibly with iron and manganese-rich tephra falls) also suggest a high-latitude eruption (possibly Icelandic) at AD693, corresponding to a GISP2 volcanic signal at 690.7×2.5. Results from this study attempt to characterize and reduce uncertainties in ice-core volcanic reconstructions, and make a contribution towards establishing a new reference horizon for this relatively under-studied period.

An Ice Core Perspective on Aleutian Low Variability over the Common Era

NASA Astrophysics Data System (ADS)

Osterberg, E. C.; Winski, D.; Kreutz, K. J.; Wake, C. P.; Ferris, D. G.; Campbell, S.; Introne, D.

2016-12-01

The Aleutian Low (ALow) is the dominant feature of atmospheric circulation in the North Pacific, strongly influencing wintertime temperature, precipitation and wind patterns in Alaska and the Yukon Territory, as well as further downstream in North America via atmospheric teleconnections. Changes in ALow strength are known to impact marine ecosystems by contributing to the multi-decadal sea-surface temperature mode in the North Pacific known as the Pacific Decadal Oscillation (PDO). Meteorological records show that in addition to distinct PDO-like variability, the ALow has intensified over the 20th century. However, ALow variability prior to the instrumental period remains unclear due to generally poor correlations among published ALow and PDO reconstructions, including the Mt. Logan ice core ALow record. An improved understanding of past ALow variability is critical for evaluating natural ALow forcing mechanisms, placing the 20th century intensification in context, and improving ALow projections under increased anthropogenic forcing. Here we combine ALow-sensitive time series from the new Denali ice core and the Mt. Logan ice core to develop a high-resolution (1-3 year) multi-ice-core record of ALow variability over the past 1500 years. The Denali ice core was collected from the summit plateau (3900 m) of Mt. Hunter in 2013, and was sampled using the Dartmouth continuous melter system with discrete sampling for major ion (IC), trace element (ICP-MS), and stable isotope ratios (Picarro), as well as continuous flow analyses for dust size and concentration (Klotz Abakus). We focus here on the sea-salt sodium time series, and calibrate our record over the 20th century with reanalysis wind speed and pressure data. The Denali sodium record of ALow strength strongly resembles the Mt. Logan ALow record, with both showing a recent intensification of the ALow that started in the late 1600s and continues into the 20th century. Both records reveal that the ALow was stronger during the late 19th to 20th centuries than earlier in the last millennium, and both show a previous strong ALow period from ca. 500-900 AD. We compare our mutli-core ALow record to other ALow-sensitive ice core time series, as well as to ALow records from other proxy archives and General Circulation Models.

Reconstruction of Aerosol Concentration and Composition from Glacier Ice Cores

NASA Astrophysics Data System (ADS)

Vogel, Alexander; Dällenbach, Kaspar; El-Haddad, Imad; Wendl, Isabel; Eichler, Anja; Schwikowski, Margit

2017-04-01

Reconstruction of the concentration and composition of natural aerosol in an undisturbed atmosphere enables the evaluation of the understanding of aerosol-climate effects, which is currently based on highly uncertain emission inventories of the biosphere under pre-industrial conditions. Understanding of the natural state of the pre-industrial atmosphere and evaluating the atmospheric perturbations by anthropogenic emissions, and their potential feedbacks, is essential for accurate model predictions of the future climate (Boucher et al., 2013). Here, we present a new approach for the chemical characterization of the organic fraction preserved in cold-glacier ice cores. From this analysis historic trends of atmospheric organic aerosols are reconstructed, allowing new insights on organic aerosol composition and mass in the pre-industrial atmosphere, which can help to improve climate models through evaluation of our current understanding of aerosol radiative effects. We present results from a proof-of-principal study, analyzing an 800 year ice core record from the Lomonosovfonna glacier ice core, drilled in 2009 in Svalbard, Norway, using a setup that has until then only been applied on offline measurements of aerosol filter extracts (Dällenbach et al., 2016): The melted ice was nebulized and dried, such that aerosols are formed from the soluble and insoluble organic and inorganic compounds that are preserved in the ice. To improve the sensitivity, the aerosol stream was then enriched by the application of an online aerosol concentrator, before the aerosol was analyzed by electron ionization within a high resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). We were able to demonstrate that this setup is a quantitative method toward nitrate and sulfate when internal inorganic standards of NH415NO3 and (NH4)234SO4 are added to the sample. Comparison between AMS and IC measurements of nitrate and sulfate resulted in an excellent agreement. The analysis of the organic fraction, however, was biased by a source of organic contamination, likely introduced during sample storage. However, freshly prepared ice blanks showed no significant source or organics, and the calibration with an organic surrogate standard demonstrated that this technique is applicable for the analysis of newly prepared ice samples. Furthermore, we present first results of the method development towards organic molecular tracer analysis using solid phase extraction and liquid-chromatography coupled to ultra-high resolution mass spectrometry. References: Boucher, O., et al., Clouds and Aerosols: 7, in: Climate Change 2013: The Physical Science Basis., Cambridge University Press, 571-658, 2013. Dällenbach, K. R., et al., Atmos. Meas. Tech. 9, 23-39, 2016.

Insight into the latitudinal distribution of methane emissions throughout the Holocene from ice core methane records.

NASA Astrophysics Data System (ADS)

Sowers, T. A.; Vladimirova, D.; Blunier, T.

2017-12-01

During the preAnthropogenic era (prior to 1600AD) the interpolar CH4 gradient (IPG) is effectively dictated by the ratio of tropical to Pan Arctic CH4 emissions. IPG records from ice cores in Greenland and Antarctica provide fundamental information for assessing the latitudinal distribution of CH4 emissions and their relation to global climate change. We recently constructed a high-resolution (100yr) record of IPG changes throughout the Holocene using the ReCAP (E. Greenland) and WAIS (W. Antarctica) ice cores. Contemporaneous samples from both cores were analyzed on the same day to minimize analytical uncertainties associated with IPG reconstructions. CH4results from the WAIS core were indistinguishable from previous results suggesting our analytical scheme was intact (± 3ppb). Our reconstructed IPG showed early Holocene IPG values of 65ppb declining throughout the Holocene to values approximating 45 ppb during the latest portion of the Holocene (preAnthropogenic). We then utilized an eight box atmospheric methane box model (EBAMM) to quantify emission scenarios that agree with ice core CH4 records (concentration, IPG and isotopic composition). Our results are consistent with the idea that early Holocene peatland development in the PanArctic regions followed glacier retreat near the end of the last glacial termination contributing an additional 20Tg of CH4/yr relative to the late Holocene. In addition, we had to invoke elevated biomass burning emissions (40Tg/yr) during the early Holocene to account for the elevated d13CH4 values.

Phreatomagmatic eruptions under the West Antarctic Ice Sheet: potential hazard for ice sheet stability

NASA Astrophysics Data System (ADS)

Iverson, N. A.; Dunbar, N. W.; Lieb-Lappen, R.; Kim, E. J.; Golden, E. J.; Obbard, R. W.

2014-12-01

Volcanic tephra layers have been seen in most ice cores in Antarctica. These tephra layers are deposited almost instantaneously across wide areas of ice sheets, creating horizons that can provide "pinning points" to adjust ice time scales that may otherwise be lacking detailed chronology. A combination of traditional particle morphology characterization by SEM with new non-destructive X-ray micro-computed tomography (Micro-CT) has been used to analyze selected coarse grained tephra in the West Antarctica Ice Sheet (WAIS) Divide WDC06A ice core. Micro-CT has the ability to image particles as small as 50µm in length (15µm resolution), quantifying both particle shape and size. The WDC06A contains hundreds of dusty layers of which 36 have so far been identified as primary tephra layers. Two of these tephra layers have been characterized as phreatomagmatic eruptions based on SEM imagery and are blocky and platy in nature, with rare magmatic particles. These layers are strikingly different in composition from the typical phonolitic and trachytic tephra produced from West Antarctic volcanoes. These two layers are coarser in grain size, with many particles (including feldspar crystals) exceeding 100µm in length. One tephra layer found at 3149.138m deep in the ice core is a coarse ~1mm thick basanitic tephra layer with a WDC06-7 ice core age of 45,381±2000yrs. The second layer is a ~1.3 cm thick zoned trachyandesite to trachydacite tephra found at 2569.205m deep with an ice core age 22,470±835yrs. Micro-CT analysis shows that WDC06A-3149.138 has normal grading with the largest particles at the bottom of the sample (~160μm). WDC06A-2569.205 has a bimodal distribution of particles with large particles at the top and bottom of the layer. These large particles are more spherical in shape at the base and become more irregular and finer grained higher in the layer, likely showing changes in eruption dynamics. The distinct chemistry as well as the blocky and large grain size of the two tephra lead us to believe that these eruptions are from volcanoes proximal to WAIS Divide and did not transport far because neither tephra was observed in the Byrd core (<100km away). It is likely that these tephra are sourced from volcanoes beneath the WAIS and have since been buried and if they were to erupt again, may contribute to ice sheet instability.

Atmospheric CO2 Over the Last 1000 Years: WAIS Divide Ice Core Record

NASA Astrophysics Data System (ADS)

Ahn, J.; Brook, E. J.

2009-04-01

How atmospheric CO2 varied over the last thousands years is of great interest because we may see not only natural, but also anthropogenic variations (Ruddiman, Climatic Change, 2003). The Law Dome ice cores reveal decadal to centennial variations in CO2 over the last 2000 years (MacFarling Meure et al., Geophys. Res. Lett., 2006). However, these variations have not yet been well confirmed in other ice core records. Here we use a newly drilled WAIS Divide ice core, which is ideal for this purpose because WAIS Divide has relatively high snow accumulation rate and small gas age distribution that allow us to observe decadal CO2 variations with minimal damping. We have started an extensive study of CO2 in WAIS Divide core. So far we have obtained data for 960-1940 A.D. from the WDC05-A core drilled in 2005-2006. 344 ice samples from 103 depths were analyzed and the standard error of the mean is ~0.8 ppm on average. Ancient air in 8~12 g of bubbly ice is liberated by crushing with steel pins at -35 °C and trapped in stainless steel tubes at -262 °C. CO2 mixing ratio in the extracted air is precisely determined using a gas chromatographic method. Details of the high-precision methods are described in Ahn et al. (J. of Glaciology, in press). Our new results show preindustrial atmospheric CO2 variability of ~ 10 ppm. The most striking feature of the record is a rapid atmospheric CO2 decrease of 7~8 ppm within ~20 years at ~ 1600 A.D. Considering the larger smoothing of gas records in the WAIS Divide relative to Law Dome, our results confirm the atmospheric CO2 decrease of ~10 ppm in Law Dome records observed at this time. However, this event is not significant in the Dronning Maud Land ice core (Siegenthaler et al., Tellus, 2005), probably due to more extensive smoothing of gas records in the core. Similar rapid changes of CO2 at other times in the WAIS Divide record need to be confirmed with higher resolution studies. We also found that our WAIS Divide CO2 data are slightly higher than those of Law Dome by 3~5 ppm over most of the record. It is not clear whether the offset is due to real variability in ice cores or an analytical offset. We are participating in international laboratory intercalibration to determine the origin of the offset. Several WDC05-A and Law Dome ice samples are shared and will be analyzed for data comparison with CSIRO (Australian Common Wealth Scientific and Research Organization).

A 60 Year Record of Atmospheric Aerosol Depositions Preserved in a High-Accumulation Dome Ice Core, Southeast Greenland

NASA Astrophysics Data System (ADS)

Iizuka, Yoshinori; Uemura, Ryu; Fujita, Koji; Hattori, Shohei; Seki, Osamu; Miyamoto, Chihiro; Suzuki, Toshitaka; Yoshida, Naohiro; Motoyama, Hideaki; Matoba, Sumito

2018-01-01

The Southeastern Greenland Dome (SE-Dome) has both a high elevation and a high accumulation rate (1.01 m we yr-1), which are suitable properties for reconstructing past environmental changes with a high time resolution. For this study, we measured the major ion fluxes in a 90 m ice core drilled from the SE-Dome region in 2015 and present the records of annual ion fluxes from 1957 to 2014. From 1970 to 2010, the trend of nonsea-salt (nss) SO42- flux decreases, whereas that for NH4+ increases, tracking well with the anthropogenic SOx and NH3 emissions mainly from North America. The result suggests that these fluxes reflect histories of the anthropogenic SOx and NH3 emissions. In contrast, the decadal trend of NO3- flux differs from the decreasing trend of anthropogenic NOx emissions. Although the cause of this discrepancy remains unclear, it may be related to changes in particle formation processes and chemical scavenging rates caused by an increase in sea salt and dust and/or a decrease in nssSO42-. We also find a high average NO3- flux (1.13 mmol m-2 yr-1) in the ice core, which suggests a negligible effect from postdepositional NO3- loss. Thus, the SE-Dome region is an excellent location for reconstructing nitrate fluxes. Over a decadal time scale, our NO3- flux record is similar to those from other ice cores in Greenland high-elevation sites, suggesting that NO3- concentration records from these ice cores are reliable.

Insights into accumulation variability over the last 2000 years at James Ross Island, Antarctic Peninsula

NASA Astrophysics Data System (ADS)

Massam, A.; Mulvaney, R.; McConnell, J.; Abram, N.; Arienzo, M. M.; Whitehouse, P. L.

2016-12-01

The James Ross Island ice core, drilled to 364 m on the northern tip of the Antarctic Peninsula, preserves a climate record that spans beyond the Holocene period to the end of the last glacial maximum (LGM). Reanalysis of the ice core using high-resolution continuous flow analysis (CFA) highlighted errors in the identification of events of known age that had been used to constrain the earlier chronology. The new JRI2 chronology is annual layer counted to 300 years, with the remaining profile reconstructed using a new age-depth model that is tied to age horizons identified in the annual-layer counted WAIS Divide ice core record. An accurate age-depth profile requires reliable known-age horizons along the ice core profile. In addition, these allow us to determine a solution for the accumulation history and rate of compaction due to vertical strain. The accuracy of the known-age constraints used in JRI2 allows only a small uncertainty in the reconstruction of the most recent 2000 years of accumulation variability. Independently, the surface temperature profile has been estimated from the stable water isotope profile and calibrated to borehole temperature observations. We present the accumulation, vertical thinning and temperature history interpreted from the James Ross Island ice core for the most recent 2000 years. JRI2 reconstructions show accumulation variability on a decadal to centennial timescale up to 20% from the present-day mean annual accumulation rate of 0.63 m yr-1. Analysis of the accumulation profile for James Ross Island offers insight into the sensitivity of accumulation to a change in surface temperature, as well as the reliability of the assumed relationship between accumulation and surface temperature in climate reconstructions using stable water isotope proxies.

Water isotopic ratios from a continuously melted ice core sample

NASA Astrophysics Data System (ADS)

Gkinis, V.; Popp, T. J.; Blunier, T.; Bigler, M.; Schüpbach, S.; Johnsen, S. J.

2011-06-01

A new technique for on-line high resolution isotopic analysis of liquid water, tailored for ice core studies is presented. We build an interface between an Infra Red Cavity Ring Down Spectrometer (IR-CRDS) and a Continuous Flow Analysis (CFA) system. The system offers the possibility to perform simultaneuous water isotopic analysis of δ18O and δD on a continuous stream of liquid water as generated from a continuously melted ice rod. Injection of sub μl amounts of liquid water is achieved by pumping sample through a fused silica capillary and instantaneously vaporizing it with 100 % efficiency in a home made oven at a temperature of 170 °C. A calibration procedure allows for proper reporting of the data on the VSMOW scale. We apply the necessary corrections based on the assessed performance of the system regarding instrumental drifts and dependance on humidity levels. The melt rates are monitored in order to assign a depth scale to the measured isotopic profiles. Application of spectral methods yields the combined uncertainty of the system at below 0.1 ‰ and 0.5 ‰ for δ18O and δD, respectively. This performance is comparable to that achieved with mass spectrometry. Dispersion of the sample in the transfer lines limits the resolution of the technique. In this work we investigate and assess these dispersion effects. By using an optimal filtering method we show how the measured profiles can be corrected for the smoothing effects resulting from the sample dispersion. Considering the significant advantages the technique offers, i.e. simultaneuous measurement of δ18O and δD, potentially in combination with chemical components that are traditionally measured on CFA systems, notable reduction on analysis time and power consumption, we consider it as an alternative to traditional isotope ratio mass spectrometry with the possibility to be deployed for field ice core studies. We present data acquired in the framework of the NEEM deep ice core drilling project in Greenland, during the 2010 field season.

Water isotopic ratios from a continuously melted ice core sample

NASA Astrophysics Data System (ADS)

Gkinis, V.; Popp, T. J.; Blunier, T.; Bigler, M.; Schüpbach, S.; Kettner, E.; Johnsen, S. J.

2011-11-01

A new technique for on-line high resolution isotopic analysis of liquid water, tailored for ice core studies is presented. We built an interface between a Wavelength Scanned Cavity Ring Down Spectrometer (WS-CRDS) purchased from Picarro Inc. and a Continuous Flow Analysis (CFA) system. The system offers the possibility to perform simultaneuous water isotopic analysis of δ18O and δD on a continuous stream of liquid water as generated from a continuously melted ice rod. Injection of sub μl amounts of liquid water is achieved by pumping sample through a fused silica capillary and instantaneously vaporizing it with 100% efficiency in a~home made oven at a temperature of 170 °C. A calibration procedure allows for proper reporting of the data on the VSMOW-SLAP scale. We apply the necessary corrections based on the assessed performance of the system regarding instrumental drifts and dependance on the water concentration in the optical cavity. The melt rates are monitored in order to assign a depth scale to the measured isotopic profiles. Application of spectral methods yields the combined uncertainty of the system at below 0.1‰ and 0.5‰ for δ18O and δD, respectively. This performance is comparable to that achieved with mass spectrometry. Dispersion of the sample in the transfer lines limits the temporal resolution of the technique. In this work we investigate and assess these dispersion effects. By using an optimal filtering method we show how the measured profiles can be corrected for the smoothing effects resulting from the sample dispersion. Considering the significant advantages the technique offers, i.e. simultaneuous measurement of δ18O and δD, potentially in combination with chemical components that are traditionally measured on CFA systems, notable reduction on analysis time and power consumption, we consider it as an alternative to traditional isotope ratio mass spectrometry with the possibility to be deployed for field ice core studies. We present data acquired in the field during the 2010 season as part of the NEEM deep ice core drilling project in North Greenland.

The Ross Sea Dipole - temperature, snow accumulation and sea ice variability in the Ross Sea region, Antarctica, over the past 2700 years

NASA Astrophysics Data System (ADS)

Bertler, Nancy A. N.; Conway, Howard; Dahl-Jensen, Dorthe; Emanuelsson, Daniel B.; Winstrup, Mai; Vallelonga, Paul T.; Lee, James E.; Brook, Ed J.; Severinghaus, Jeffrey P.; Fudge, Taylor J.; Keller, Elizabeth D.; Baisden, W. Troy; Hindmarsh, Richard C. A.; Neff, Peter D.; Blunier, Thomas; Edwards, Ross; Mayewski, Paul A.; Kipfstuhl, Sepp; Buizert, Christo; Canessa, Silvia; Dadic, Ruzica; Kjær, Helle A.; Kurbatov, Andrei; Zhang, Dongqi; Waddington, Edwin D.; Baccolo, Giovanni; Beers, Thomas; Brightley, Hannah J.; Carter, Lionel; Clemens-Sewall, David; Ciobanu, Viorela G.; Delmonte, Barbara; Eling, Lukas; Ellis, Aja; Ganesh, Shruthi; Golledge, Nicholas R.; Haines, Skylar; Handley, Michael; Hawley, Robert L.; Hogan, Chad M.; Johnson, Katelyn M.; Korotkikh, Elena; Lowry, Daniel P.; Mandeno, Darcy; McKay, Robert M.; Menking, James A.; Naish, Timothy R.; Noerling, Caroline; Ollive, Agathe; Orsi, Anaïs; Proemse, Bernadette C.; Pyne, Alexander R.; Pyne, Rebecca L.; Renwick, James; Scherer, Reed P.; Semper, Stefanie; Simonsen, Marius; Sneed, Sharon B.; Steig, Eric J.; Tuohy, Andrea; Ulayottil Venugopal, Abhijith; Valero-Delgado, Fernando; Venkatesh, Janani; Wang, Feitang; Wang, Shimeng; Winski, Dominic A.; Winton, V. Holly L.; Whiteford, Arran; Xiao, Cunde; Yang, Jiao; Zhang, Xin

2018-02-01

High-resolution, well-dated climate archives provide an opportunity to investigate the dynamic interactions of climate patterns relevant for future projections. Here, we present data from a new, annually dated ice core record from the eastern Ross Sea, named the Roosevelt Island Climate Evolution (RICE) ice core. Comparison of this record with climate reanalysis data for the 1979-2012 interval shows that RICE reliably captures temperature and snow precipitation variability in the region. Trends over the past 2700 years in RICE are shown to be distinct from those in West Antarctica and the western Ross Sea captured by other ice cores. For most of this interval, the eastern Ross Sea was warming (or showing isotopic enrichment for other reasons), with increased snow accumulation and perhaps decreased sea ice concentration. However, West Antarctica cooled and the western Ross Sea showed no significant isotope temperature trend. This pattern here is referred to as the Ross Sea Dipole. Notably, during the Little Ice Age, West Antarctica and the western Ross Sea experienced colder than average temperatures, while the eastern Ross Sea underwent a period of warming or increased isotopic enrichment. From the 17th century onwards, this dipole relationship changed. All three regions show current warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea but increasing in the western Ross Sea. We interpret this pattern as reflecting an increase in sea ice in the eastern Ross Sea with perhaps the establishment of a modern Roosevelt Island polynya as a local moisture source for RICE.

Solving the riddle of interglacial temperatures over the last 1.5 million years with a future IPICS "Oldest Ice" ice core

NASA Astrophysics Data System (ADS)

Fischer, Hubertus

2014-05-01

The sequence of the last 8 glacial cycles is characterized by irregular 100,000 year cycles in temperature and sea level. In contrast, the time period between 1.5-1.2 million years ago is characterized by more regular cycles with an obliquity periodicity of 41,000 years. Based on a deconvolution of deep ocean temperature and ice volume contributions to benthic δ18O (Elderfield et al., Science, 2012), it is suggested that glacial sea level became progressively lower over the last 1.5 Myr, while glacial deep ocean temperatures were very similar. At the same time many interglacials prior to the Mid Brunhes event showed significantly cooler deep ocean temperatures than the Holocene, while at the same time interglacial ice volume remained essentially the same. In contrast, interglacial sea surface temperatures in the tropics changed little (Herbert et al., Science,2010) and proxy reconstructions of atmospheric CO2 using δ11B in planktic foraminifera (Hönisch et al., Science, 2009) suggest that prior to 900,000 yr before present interglacial CO2 levels did not differ substantially from those over the last 450,000 years. Accordingly, the conundrum arises how interglacials can differ in deep ocean temperature without any obvious change in ice volume or greenhouse gas forcing and what caused the change in cyclicity of glacial interglacial cycles over the Mid Pleistocene Transition. Probably the most important contribution to solve this riddle is the recovery of a 1.5 Myr old ice core from Antarctica, which among others would provide an unambiguous, high-resolution record of the greenhouse gas history over this time period. Accordingly, the international ice core community, as represented by the International Partnership for Ice Core Science (IPICS), has identified such an 'Oldest Ice' ice core as one of the most important scientific targets for the future (http://www.pages.unibe.ch/ipics/white-papers). However, finding stratigraphically undisturbed ice, which covers this time period in Antarctica, is not an easy task. Based on a simple ice and heat flow model and glaciological observations (Fischer et al., Climate of the Past, 2013), we conclude that sites in the vicinity of major domes and saddle positions on the East Antarctic Plateau will most likely have such old ice in store and represent the best study areas for dedicated reconnaissance studies in the near future. In contrast to previous ice core drill site selections, however, significantly reduced ice thickness is required to avoid bottom melting. The most critical parameter is the largely unknown geothermal heat flux at the bottom of the ice sheet. For example for the geothermal heat flux and accumulation conditions at Dome C, an ice thickness lower than but close to about 2500 m would be required to find 1.5 My old ice. If sites with lower geothermal heat flux can be found, also a higher ice thickness is allowed, alleviating the problem of potential flow disturbances in the bottom-most ice to affect a 1.5 Myr climate record.

The role of seasonality of mineral dust concentration and size on glacial/interglacial dust changes in the EPICA Dronning Maud Land ice core

NASA Astrophysics Data System (ADS)

Wegner, Anna; Fischer, Hubertus; Delmonte, Barbara; Petit, Jean-Robert; Erhardt, Tobias; Ruth, Urs; Svensson, Anders; Vinther, Bo; Miller, Heinrich

2015-10-01

We present a record of particulate dust concentration and size distribution in subannual resolution measured on the European Project for Ice Coring in Antarctica (EPICA) Dronning Maud Land (EDML) ice core drilled in the Atlantic sector of the East Antarctic plateau. The record reaches from present day back to the penultimate glacial until 145,000 years B.P. with subannual resolution from 60,000 years B.P. to the present. Mean dust concentrations are a factor of 46 higher during the glacial (~850-4600 ng/mL) compared to the Holocene (~16-112 ng/mL) with slightly smaller dust particles during the glacial compared to the Holocene and with an absolute minimum in the dust size at 16,000 years B.P. The changes in dust concentration are mainly attributed to changes in source conditions in southern South America. An increase in the modal value of the dust size suggests that at 16,000 years B.P. a major change in atmospheric circulation apparently allowed more direct transport of dust particles to the EDML drill site. We find a clear in-phase relation of the seasonal variation in dust mass concentration and dust size during the glacial (r(conc,size) = 0.8) but no clear phase relationship during the Holocene (0 < r(conc,size) < 0.4). With a simple conceptual 1-D model describing the transport of the dust to the ice sheet using the size as an indicator for transport intensity, we find that the effect of the changes in the seasonality of the source emission strength and the transport intensity on the dust decrease over Transition 1 can significantly contribute to the large decrease of dust concentration from the glacial to the Holocene.

Primary spectrum and composition with IceCube/IceTop

NASA Astrophysics Data System (ADS)

Gaisser, Thomas K.; IceCube Collaboration

2016-10-01

IceCube, with its surface array IceTop, detects three different components of extensive air showers: the total signal at the surface, GeV muons in the periphery of the showers and TeV muons in the deep array of IceCube. The spectrum is measured with high resolution from the knee to the ankle with IceTop. Composition and spectrum are extracted from events seen in coincidence by the surface array and the deep array of IceCube. The muon lateral distribution at the surface is obtained from the data and used to provide a measurement of the muon density at 600 meters from the shower core up to 30 PeV. Results are compared to measurements from other experiments to obtain an overview of the spectrum and composition over an extended range of energy. Consistency of the surface muon measurements with hadronic interaction models and with measurements at higher energy is discussed.

Subsurface Ice Probe

NASA Technical Reports Server (NTRS)

Hecht, Michael; Carsey, Frank

2005-01-01

The subsurface ice probe (SIPR) is a proposed apparatus that would bore into ice to depths as great as hundreds of meters by melting the ice and pumping the samples of meltwater to the surface. Originally intended for use in exploration of subsurface ice on Mars and other remote planets, the SIPR could also be used on Earth as an alternative to coring, drilling, and melting apparatuses heretofore used to sample Arctic and Antarctic ice sheets. The SIPR would include an assembly of instrumentation and electronic control equipment at the surface, connected via a tether to a compact assembly of boring, sampling, and sensor equipment in the borehole (see figure). Placing as much equipment as possible at the surface would help to attain primary objectives of minimizing power consumption, sampling with high depth resolution, and unobstructed imaging of the borehole wall. To the degree to which these requirements would be satisfied, the SIPR would offer advantages over the aforementioned ice-probing systems.

A stratigraphic framework for abrupt climatic changes during the Last Glacial period based on three synchronized Greenland ice-core records: refining and extending the INTIMATE event stratigraphy

NASA Astrophysics Data System (ADS)

Rasmussen, Sune O.; Bigler, Matthias; Blockley, Simon P.; Blunier, Thomas; Buchardt, Susanne L.; Clausen, Henrik B.; Cvijanovic, Ivana; Dahl-Jensen, Dorthe; Johnsen, Sigfus J.; Fischer, Hubertus; Gkinis, Vasileios; Guillevic, Myriam; Hoek, Wim Z.; Lowe, J. John; Pedro, Joel B.; Popp, Trevor; Seierstad, Inger K.; Steffensen, Jørgen Peder; Svensson, Anders M.; Vallelonga, Paul; Vinther, Bo M.; Walker, Mike J. C.; Wheatley, Joe J.; Winstrup, Mai

2014-12-01

Due to their outstanding resolution and well-constrained chronologies, Greenland ice-core records provide a master record of past climatic changes throughout the Last Interglacial-Glacial cycle in the North Atlantic region. As part of the INTIMATE (INTegration of Ice-core, MArine and TErrestrial records) project, protocols have been proposed to ensure consistent and robust correlation between different records of past climate. A key element of these protocols has been the formal definition and ordinal numbering of the sequence of Greenland Stadials (GS) and Greenland Interstadials (GI) within the most recent glacial period. The GS and GI periods are the Greenland expressions of the characteristic Dansgaard-Oeschger events that represent cold and warm phases of the North Atlantic region, respectively. We present here a more detailed and extended GS/GI template for the whole of the Last Glacial period. It is based on a synchronization of the NGRIP, GRIP, and GISP2 ice-core records that allows the parallel analysis of all three records on a common time scale. The boundaries of the GS and GI periods are defined based on a combination of stable-oxygen isotope ratios of the ice (δ18O, reflecting mainly local temperature) and calcium ion concentrations (reflecting mainly atmospheric dust loading) measured in the ice. The data not only resolve the well-known sequence of Dansgaard-Oeschger events that were first defined and numbered in the ice-core records more than two decades ago, but also better resolve a number of short-lived climatic oscillations, some defined here for the first time. Using this revised scheme, we propose a consistent approach for discriminating and naming all the significant abrupt climatic events of the Last Glacial period that are represented in the Greenland ice records. The final product constitutes an extended and better resolved Greenland stratotype sequence, against which other proxy records can be compared and correlated. It also provides a more secure basis for investigating the dynamics and fundamental causes of these climatic perturbations.

Collaborative data-modelling approach to infer Oldest Ice sites in the vicinity of Concordia.

NASA Astrophysics Data System (ADS)

Ritz, Catherine; Cavitte, Marie; Corr, Hugh; Frezzotti, Massimo; Martin, Carlos; Mulvaney, Robert; Passalacqua, Olivier; Parrenin, Frederic; Roberts, Jason; Urbini, Stefano; Vittuari, Luca; Young, Duncan

2017-04-01

Recovering a 1.5 million years record of climate and greenhouse gases from Antarctica is a major objective of the ice core community. There is an agreement concerning the most important criteria to retrieve such old ice: low horizontal velocity; low accumulation rate and no (or very little) basal melting. These criteria indicate that such "Oldest Ice" could be found close to the divides of the East Antarctic Plateau and the region around the permanent station of Concordia (East Antarctica) appears to be amongst the few possible candidate sites. By 2015, this region was already relatively well documented because of the proximity of Concordia station and the fact that geophysical survey had been performed in the context of the EPICA drilling. However, the detection/selection of an appropriate drilling site requires to complete the geophysical data coverage and to develop modeling tools to make the best use of the data. This constitutes a major objective of the BE-OI (Beyond EPICA Oldest Ice) European Project and we present here the approach used to join data acquisition, interpretation and modeling as well as the current status of this collaborative work. The approach is based on several steps. 1) On the basis of existing data (essentially bedmap2) a broad region of interest was defined and airborne radar survey was performed in January 2016 by a UTIG/AAD team over a grid ( 40 x 100 km, resolution 1 km in one direction). 2) Interpretation of these data allowed to produce a high resolution bedrock map. Moreover, using the EPICA ice core data, it was possible to date internal layers back to 360 kyr all over the surveyed domain. 3) Ice flow and thermal inverse modeling extrapolated the age and its vertical gradient (vertical resolution) down to the bedrock and evaluated the associated basal melting (see Parrenin et al. Presentation) 4) smaller patches of interests (5 x 5 km) were defined from the model results (and related uncertainties), morphology of the internal layers and basal hydrology patterns (including sublgacial lakes) that can be inferred from the radar echoes, 5) these patches are now surveyed with a ground based radar with a very high horizontal resolution (250 m in both direction). Stations for ApRES measurements and strain net (GPS) are also set up. After revisit next year they will give information concerning ice flow. 6) the ultimate task will be to use the synthesis of all data/models to decide the precise drilling site for the fast drilling tool "Subglacior"

Mass Fluxes of Ice and Oxygen Across the Entire Lid of Lake Vostok from Observations of Englacial Radiowave Attenuation

NASA Astrophysics Data System (ADS)

Winebrenner, D. P.; Kintner, P. M. S.; MacGregor, J. A.

2017-12-01

Over deep Antarctic subglacial lakes, spatially varying ice thickness and the pressure-dependent melting point of ice result in areas of melting and accretion at the ice-water interface, i.e., the lake lid. These ice mass fluxes drive lake circulation and, because basal Antarctic ice contains air-clathrate, affect the input of oxygen to the lake, with implications for subglacial life. Inferences of melting and accretion from radar-layer tracking and geodesy are limited in spatial coverage and resolution. Here we develop a new method to estimate rates of accretion, melting, and the resulting oxygen input at a lake lid, using airborne radar data over Lake Vostok together with ice-temperature and chemistry data from the Vostok ice core. Because the lake lid is a coherent reflector of known reflectivity (at our radar frequency), we can infer depth-averaged radiowave attenuation in the ice, with spatial resolution 1 km along flight lines. Spatial variation in attenuation depends mostly on variation in ice temperature near the lid, which in turn varies strongly with ice mass flux at the lid. We model ice temperature versus depth with ice mass flux as a parameter, thus linking that flux to (observed) depth-averaged attenuation. The resulting map of melt- and accretion-rates independently reproduces features known from earlier studies, but now covers the entire lid. We find that accretion is dominant when integrated over the lid, with an ice imbalance of 0.05 to 0.07 km3 a-1, which is robust against uncertainties.

A High-Resolution Record of Warm Water Inflow and Iceberg Calving in Upernavik Isfjord During the Past 150 Years.

NASA Astrophysics Data System (ADS)

Vermassen, F.; Andresen, C. S.; Sabine, S.; Holtvoeth, J.; Cordua, A. E.; Wangner, D. J.; Dyke, L. M.; Kjaer, K. H.; Kokfelt, U.; Haubner, K.

2016-12-01

There is a growing body of evidence demonstrating that changes in warm water inflow to Greenlandic fjords are linked to the rapid retreat of marine-terminating outlet glaciers. This process is thought to be responsible for a substantial component of the increased mass loss from the Greenland Ice Sheet over the last two decades. Sediment cores from glaciated fjords provide high-resolution sedimentological and biological proxy records which can be used to evaluate the interplay of warm water inflow and glacier calving over recent time scales. In this study, multiple short cores ( 2 m) from Upernavik Isfjord, West Greenland, were analysed to establish a multi-proxy record of glacier behaviour and oceanographic conditions that spans the past 150 years. The down-core variation in the amount of ice-rafted debris reveals periods of increased glacier calving, and biomarker proxies are used to reconstruct variability in the inflow of warm, Atlantic-sourced water to the fjord. Measurements of the sortable silt grain size are used to reconstruct bottom-current strength; periods of vigorous current flow are assumed to be due to enhanced warm water inflow. Finally, a record of glacier terminus position changes, derived from historical observations and satellite imagery, allows comparison of our new proxy records with the retreat of the ice margin from 1849 onwards. We use these data to assess the relative importance of mechanisms controlling the (rapid) retreat of marine-terminating glaciers in Upernavik Isfjord.

A New Method for the Determination of Annual Sediment Fluxes from Varved Lake Sediments

NASA Astrophysics Data System (ADS)

Francus, P.; Massa, C.; Lapointe, F.

2013-12-01

Calculation of sediment mass accumulation rates instead of thickness accumulation is preferable for paleoclimatic reconstruction as it eliminates the effects of dilution and compaction. Annually laminated lake sediment sequences (varved) theoretically allow for the estimation of sediment fluxes at annual scale, but the calculation is limited by discrete bulk density measurements, often carried out at a much lower resolution (usually 1 cm) than the varves (ranging from 0.07 to 27.3 mm, average 1.84 mm according to Ojala et al. 2012). Since many years the development of automated logging instruments made available continuous and high resolution sediment property data, in a non-destructive fashion. These techniques can easily be used to extract the physical and chemical parameters of sediments at the varve scale (down to 100 μm). Here we present a robust method to calculate annual sediment fluxes from varved lake sediments by combining varves thickness measurements to core logging data, and provide an example for its applications. Several non-destructive densitometric methods applied to the Strathcona Lake sediment, northern Ellesmere Island, Canada (78°33'N; 82°05'W) were compared: Hounsfield Units from a CT-Scan, coherent/incoherent ratio and X-ray radiography (of both split core and sediment slabs, from an Itrax core Scanner), and gamma ray attenuation density. Core logging data were statistically compared to 400 discrete measurements of dry bulk density, wet bulk density and water content performed at 2 mm contiguous intervals. A very strong relationship was found between X-ray grey level on sediment slab and dry bulk density. Relative X-ray densities, at 100μm resolution, were then successfully calibrated against real densities. The final step consisted in binning the calibrated densities to the corresponding varve thickness and then to calculate the annual mass accumulation rates by multiplying the two parameters for each varve year. Strathcona Lake is located directly downstream of the Agassiz ice cap and contains laminated sediments whose accumulation is directly related to hydrological inputs generated by the melting of the ice cap. Over the last 65 years, annual sediment accumulation rates in Strathcona Lake documented an increase in high-energy hydrologic discharge events from 1990 to 2009. This timing is in agreement with evidence for an increase in the amount of melt on the adjacent Agassiz Ice Cap, as recorded in ice cores. A good correspondence was also found between annual mass accumulation rates and Eureka air temperature records, suggesting that temperature changes affected the extent of summer melting on the Agassiz Ice Cap, leading to high sediment yield to Strathcona Lake. Ojala, A.E.K., Francus, P., Zolitschka, B., Besonen, M. and Lamoureux, S.F. (2012) Characteristics of sedimentary varve chronologies - A review. Quaternary Science Reviews, 43, 45-60.

The response of the Okhotsk Sea environment to the orbital-millennium global climate changes during the Last Glacial Maximum, deglaciation and Holocene

NASA Astrophysics Data System (ADS)

Gorbarenko, Sergey A.; Artemova, Antonina V.; Goldberg, Evgeniy L.; Vasilenko, Yuriy P.

2014-05-01

Reconstruction of regional climate and the Okhotsk Sea (OS) environment for the Last Glacial Maximum (LGM), deglaciation and Holocene was performed on the basis of high-resolution records of ice rafted debris (IRD), СаСО3, opal, total organic carbon (TOС), biogenic Ba (Ba_bio) and redox sensitive element (Mn, Mo) content, and diatom and pollen results of four cores that form a north-southern transect. Age models of the studied cores were earlier established by AMS 14C data, oxygen-isotope chronostratigraphy and tephrochronology. According to received results, since 25 ka the regional climate and OS environmental conditions have changed synchronously with LGM condition, cold Heinrich event 1, Bølling-Allerød (BA) warming, Younger Dryas (YD) cooling and Pre-Boreal (PB) warming recorded in the Greenland ice core, North Atlantic sediment, and China cave stalagmites. Calculation of IRD MAR in sediment of north-south transect cores indicates an increase of sea ice formation several times in the glacial OS as compared to the Late Holocene. Accompanying ice formation, increased brine rejection and the larger potential density of surface water at the north shelf due to a drop of glacial East Asia summer monsoon precipitation and Amur River run off, led to strong enhancement of the role of the OS in glacial North Pacific Intermediate Water (NPIW) formation. The remarkable increase in OS productivity during BA and PB warming was probably related with significant reorganisation of the North Pacific deep water ventilation and nutrient input into the NPIW and OS Intermediate Water (OSIW). Seven Holocene OS millennial cold events based on the elevated values of the detrended IRD stack record over the IRD broad trend in the sediments of the studied cores have occurred synchronously with cold events recorded in the North Atlantic, Greenland ice cores and China cave stalagmites after 9 ka. Diatom production in the OS was mostly controlled by sea ice cover changes and surface water stratification induced by sea-ice melting; therefore significant opal accumulation in sediments of this basin begin from 4 to 6 ka ago simultaneously with a remarkable decrease of sea ice cover.

Controls on the East Asian monsoon during the last glacial cycle, based on comparison between Hulu Cave and polar ice-core records

NASA Astrophysics Data System (ADS)

Rohling, E. J.; Liu, Q. S.; Roberts, A. P.; Stanford, J. D.; Rasmussen, S. O.; Langen, P. L.; Siddall, M.

2009-12-01

Previous studies have suggested a sound chronological correlation between the Hulu Cave record (East Asian monsoon) and Greenland ice-core records, which implies a dominant control of northern hemisphere climate processes on monsoon intensity. We present an objective, straightforward statistical evaluation that challenges this generally accepted paradigm for sub-orbital variability. We propose a more flexible, global interpretation, which takes into account a broad range of variability in the signal structures in the Hulu Cave and polar ice-core records, rather than a limited number of major transitions. Our analysis employs the layer-counted Greenland Ice-Core Chronology 2005 (GICC05), which was developed for Greenland records and has since been applied - via methane synchronisation - to the high-resolution δ 18O ice series from EPICA Dronning Maud Land (EDML). The GICC05 chronology allows these ice-core records to be compared to the U-Th dated Hulu Cave record within relatively narrow (˜3%) bounds of age uncertainty. Following previous suggestions, our proposed interpretation suggests that the East Asian monsoon is influenced by a combination of northern hemisphere 'pull' (which is more intense during boreal warm periods), and southern hemisphere 'push' (which is more intense monsoon during austral cold periods). Our analysis strongly suggests a dominant control on millennial-scale monsoon variability by southern hemisphere climate changes during glacial times when the monsoon is weak overall, and control by northern hemisphere climate changes during deglacial and interglacial times when the monsoon is strong. The deduced temporally variable relationship with southern hemisphere climate records offers a statistically more plausible reason for the apparent coincidence of major East Asian monsoon transitions with northern hemisphere (Dansgaard-Oeschger, DO) climate events during glacial times, than the traditional a priori interpretation of strict northern hemisphere control.

Tree ring and ice core time scales around the Santorini eruption

NASA Astrophysics Data System (ADS)

Löfroth, Elin; Muscheler, Raimund; Aldahan, Ala; Possnert, Göran; Berggren, Ann-Marie

2010-05-01

When studying cosmogenic radionuclides in ice core and tree ring archives around the Santorini eruption a ~20 year discrepancy was found between the records (Muscheler 2009). In this study a new 10Be dataset from the NGRIP ice core is presented. It has a resolution of 7 years and spans the period 3752-3244 BP (1803-1295 BC). The NGRIP 10Be record and the previously published 10Be GRIP record were compared to the IntCal datasets to further investigate the discrepancy between the ice core and tree ring chronologies. By modelling the 14C production rate based on atmospheric 14C records a comparison could be made to the 10Be flux which is assumed to represent the 10Be production rate. This showed a time shift of ~23 years between the records. The sensitivity of the results to changes in important model parameters was evaluated. Uncertainties in the carbon cycle model cannot explain a substantial part of the timing differences. Potential influences of climate and atmospheric processes on the 10Be deposition were studied using δ18O from the respective cores and GISP2 ice core ion data. The comparison to δ18O revealed a small but significant correlation between 10Be flux and δ18O when the 14C-derived production signal was removed from the 10Be curves. The ion data, as proxies for atmospheric circulation changes, did not show any correlations to the 10Be record or the 10Be/14C difference. When including possible data uncertainties there is still a minimum discrepancy of ~10 years between the 10Be ice core and the 14C tree ring record. Due to lack of alternative explanations it is concluded that the ice core and/or the tree ring chronologies contains unaccounted errors in this range. This also reconciles the radiocarbon 1627-1600 BC (Friedrich et al., 2006) and ice core 1642±5 BC (Vinther et al., 2006) datings of the Santorini eruption. Friedrich, W.L., Kromer, B., Friedrich, M., Heinemeier, J., Pfeiffer, T., & Talamo, S., 2006: Santorini eruption radiocarbon dated to 1627-1600 BC. Science 312, 548-548. Muscheler, 2009: 14C and 10Be around 1650 cal BC. In Warburton, D.A., (ed.): Time's Up! Dating the Minoan Eruption of Santorini: acts of the Minoan Eruption Chronology Workshop, Sandbjerg November 2007: Monographs of the Danish Institute at Athens. Aarhus University Press, Aarhus. 298 pp. Vinther, B.M., Clausen, H.B., Johnsen, S.J., Rasmussen, S.O., Andersen, K.K., Buchardt, S.L., Dahl-Jensen, D., Seierstad, I.K., Siggaard-Andersen, M.L., Steffensen, J.P., Svensson, A., Olsen, J., & Heinemeier, J., 2006: A synchronized dating of three Greenland ice cores throughout the Holocene. Journal of Geophysical Research-Atmospheres 111, 11.

Deglacial-Holocene short-term variability in sea-ice distribution on the Eurasian shelf (Arctic Ocean) - An IP25 biomarker reconstruction.

NASA Astrophysics Data System (ADS)

Hörner, Tanja; Stein, Ruediger; Fahl, Kirsten

2016-04-01

Four well-dated sediment cores from the Eurasian continental shelf, i.e., the Kara Sea (Cores BP99/07 and BP00/07) and Laptev Sea (Cores PS51/154 and PS51/159), were selected for high-resolution reconstruction of past Arctic environmental conditions during the deglacial-Holocene time interval. These marginal seas are strongly affected by the post-glacial sea-level rise of about 120m. The major focus of our study was the reconstruction of the paleo-sea-ice distribution as sea-ice plays a key role within the modern and past climate system. For reconstruction of paleo-sea ice, the sea-ice proxy IP25 in combination with open-water phytoplankton biomarkers was used (for approach see Belt et al., 2007; Müller et al., 2009, 2011). In addition, specific sterols were determined to reconstruct changes in river run-off and biological production. The post-glacial sea-level rise is especially reflected in prominent decrease in terrigenous biomarkers. Deglacial variations in sea-ice cover sustained for thousand of years, mostly following climatic changes like the Bølling/Allerød (14.7-12.9 ka), Younger Dryas (12.9-11.6 ka) and Holocene warm phase (10-8 ka). Superimposed on a (Late) Holocene cooling trend, short-term fluctuations in sea-ice cover (on centennial scale) are distinctly documented in the distal/off-shore Core BP00/07 from the Kara Sea, less pronounced in the proximal/near-shore Core PS99/07 and in the Laptev Sea cores. Interestingly, this short-term variability in sea-ice cover correlates quite well to changes in Siberian river run-off (e.g., Stein et al. 2004), pointing to a direct linkage between precipitation (atmospheric circulation) and sea-ice formation. References Belt, S.T., Massé, G., Rowland, S.J., Poulin, M., Michel, C., LeBlanc, B., 2007. A novel chemical fossil of palaeo sea ice: IP25. Organic Geochemistry 38, 16-27. Müller, J., Masse, G., Stein, R., Belt, S.T., 2009. Variability of sea-ice conditions in the Fram Strait over the past 30,000 years. Nature Geoscience 2, 772-776. Müller, J., Wagner, A., Fahl, K., Stein, R., Prange, M., Lohmann, G., 2011. Towards quantitative sea ice reconstructions in the northern North Atlantic: A combined biomarker and numerical modelling approach. Earth and Planetary Science Letters 306, 137-148. Stein, R., Steinke, T., Dittmers, K., Fahl, K., Kraus, M., Matthiessen, J., Niessen, F., Pirrung, M., Polyakova, Ye., Achoster, F., Fqtterer, D.K., 2004. Terrigenous sediment supply and paleoenvironment of the Holocene Kara Sea. Quaternary Science Reviews, 23, 485-1511.

The tephrostratigraphy of Mt. Berlin volcano, Antarctica: Integrating blue ice tephra and ice core tephra records

NASA Astrophysics Data System (ADS)

Iverson, N. A.; Dunbar, N. W.; McIntosh, W. C.; Kurbatov, A.

2016-12-01

Reconstructing volcanic activity in Antarctica is difficult because of the limited outcrop exposure. However, ice is an excellent medium for sampling tephra, allowing for a more complete eruptive record than can be found in other depositional environments. Furthermore, because of low ambient temperature, glass shards trapped in ice remain unaltered and unhydrated. Mt. Berlin is an ice covered volcano in Marie Byrd Land, Antarctica, and, because of heavy glaciation, eruptive records on the volcano itself are sparse. Here, we present the integration of two different records of Mt. Berlin volcanism: the blue ice record found at Mt. Moulton (Dunbar et al., 2008) and the ice core record from the WAIS Divide ice core. Tephra from Mt. Berlin are also found in other ice and marine core records, and these have been correlated and integrated into the combined volcanic record. The Mt. Moulton blue ice area is located 30 km from Mt. Berlin and hosts a fabulous tephra record spanning the last 500 ka. A total of 36 tephra from Mt. Berlin were sampled in stratigraphic order and nine were directly dated by 40Ar/39Ar dating method. Twenty five tephra from WAIS Divide have been analyzed and are geochemically similar to Mt. Berlin with ice core ages dating back to 70 ka. The two tephra records were integrated using their respective timescales. In locations where the Mt. Moulton record does not have precise chronology, the δ18O records from Mt. Moulton (Popp, 2008) and WAIS (WAIS, 2015) were used to integrate the stratigraphy. In total 61 tephra from both ice sections provide an excellent record of the magmatic evolution of Mt. Berlin over the past 500 ka. EMP analyses on glass shards show a gradual change in Fe and S over time. Most of the other major elements remain relatively unchanged. The trend in Fe and S could be produced by progressive tapping of a single, stratified magma chamber, but the long duration of volcanism makes this unlikely. We instead favor small batches of progressively more primitive melts being generated over time. Thirty nine of the tephra have been erupted within the past 100 ka with the majority (25) of them being erupted between 40 ka and 20 ka. The resolution in eruptive frequency is unparalleled and provides many stratigraphic markers that can be correlated throughout West Antarctica, which are useful in climate research.

On the scalability of the Albany/FELIX first-order Stokes approximation ice sheet solver for large-scale simulations of the Greenland and Antarctic ice sheets

DOE PAGES

Tezaur, Irina K.; Tuminaro, Raymond S.; Perego, Mauro; ...

2015-01-01

We examine the scalability of the recently developed Albany/FELIX finite-element based code for the first-order Stokes momentum balance equations for ice flow. We focus our analysis on the performance of two possible preconditioners for the iterative solution of the sparse linear systems that arise from the discretization of the governing equations: (1) a preconditioner based on the incomplete LU (ILU) factorization, and (2) a recently-developed algebraic multigrid (AMG) preconditioner, constructed using the idea of semi-coarsening. A strong scalability study on a realistic, high resolution Greenland ice sheet problem reveals that, for a given number of processor cores, the AMG preconditionermore » results in faster linear solve times but the ILU preconditioner exhibits better scalability. In addition, a weak scalability study is performed on a realistic, moderate resolution Antarctic ice sheet problem, a substantial fraction of which contains floating ice shelves, making it fundamentally different from the Greenland ice sheet problem. We show that as the problem size increases, the performance of the ILU preconditioner deteriorates whereas the AMG preconditioner maintains scalability. This is because the linear systems are extremely ill-conditioned in the presence of floating ice shelves, and the ill-conditioning has a greater negative effect on the ILU preconditioner than on the AMG preconditioner.« less

Winter mass balance of Drangajökull ice cap (NW Iceland) derived from satellite sub-meter stereo images

NASA Astrophysics Data System (ADS)

Belart, Joaquín M. C.; Berthier, Etienne; Magnússon, Eyjólfur; Anderson, Leif S.; Pálsson, Finnur; Thorsteinsson, Thorsteinn; Howat, Ian M.; Aðalgeirsdóttir, Guðfinna; Jóhannesson, Tómas; Jarosch, Alexander H.

2017-06-01

Sub-meter resolution, stereoscopic satellite images allow for the generation of accurate and high-resolution digital elevation models (DEMs) over glaciers and ice caps. Here, repeated stereo images of Drangajökull ice cap (NW Iceland) from Pléiades and WorldView2 (WV2) are combined with in situ estimates of snow density and densification of firn and fresh snow to provide the first estimates of the glacier-wide geodetic winter mass balance obtained from satellite imagery. Statistics in snow- and ice-free areas reveal similar vertical relative accuracy (< 0.5 m) with and without ground control points (GCPs), demonstrating the capability for measuring seasonal snow accumulation. The calculated winter (14 October 2014 to 22 May 2015) mass balance of Drangajökull was 3.33 ± 0.23 m w.e. (meter water equivalent), with ∼ 60 % of the accumulation occurring by February, which is in good agreement with nearby ground observations. On average, the repeated DEMs yield 22 % less elevation change than the length of eight winter snow cores due to (1) the time difference between in situ and satellite observations, (2) firn densification and (3) elevation changes due to ice dynamics. The contributions of these three factors were of similar magnitude. This study demonstrates that seasonal geodetic mass balance can, in many areas, be estimated from sub-meter resolution satellite stereo images.

Radar Detection of Layering in Ice: Experiments on a Constructed Layered Ice Sheet

NASA Astrophysics Data System (ADS)

Carter, L. M.; Koenig, L.; Courville, Z.; Ghent, R. R.; Koutnik, M. R.

2016-12-01

The polar caps and glaciers of both Earth and Mars display internal layering that preserves a record of past climate. These layers are apparent both in optical datasets (high resolution images, core samples) and in ground penetrating radar (GPR) data. On Mars, the SHARAD (Shallow Radar) radar on the Mars Reconnaissance Orbiter shows fine layering that changes spatially and with depth across the polar caps. This internal layering has been attributed to changes in fractional dust contamination due to obliquity-induced climate variations, but there are other processes that can lead to internal layers visible in radar data. In particular, terrestrial sounding of ice sheets compared with core samples have revealed that ice density and composition differences account for the majority of the radar reflectors. The large cold rooms and ice laboratory facility at the U.S. Army Cold Regions Research and Engineering Laboratory (CRREL) provide us a unique opportunity to construct experimental ice sheets in a controlled setting and measure them with radar. In a CRREL laboratory, we constructed a layered ice sheet that is 3-m deep with a various snow and ice layers with known dust concentrations (using JSC Mars-1 basaltic simulant) and density differences. These ice sheets were profiled using a commercial GPR, at frequencies of 200, 400 and 900 MHz, to determine how the radar profile changes due to systematic and known changes in snow and ice layers, including layers with sub-wavelength spacing. We will report results from these experiments and implications for interpreting radar-detected layering in ice on Earth and Mars.

Thallium as a tracer for preindustrial volcanic eruptions in an ice core record from Illimani, Bolivia.

PubMed

Kellerhals, Thomas; Tobler, Leonhard; Brütsch, Sabina; Sigl, Michael; Wacker, Lukas; Gäggeler, Heinz W; Schwikowski, Margit

2010-02-01

Trace element records from glacier and ice sheet archives provide insights into biogeochemical cycles, atmospheric circulation changes, and anthropogenic pollution history. We present the first continuous high-resolution thallium (Tl) record, derived from an accurately dated ice core from tropical South America, and discuss Tl as a tracer for volcanic eruptions. We identify four prominent Tl peaks and propose that they represent signals from the massive explosive eruptions of the "unknown 1258" A.D. volcano, of Kuwae ( approximately 1450 A.D.), Tambora (1815 A.D.), and Krakatoa (1883 A.D.). The highly resolved record was obtained with an improved setup for the continuous analysis of trace elements in ice with inductively coupled plasma sector field mass spectrometry (ICP-SFMS). The new setup allowed for a stronger initial acidification of the meltwater and shorter tubing length, thereby reducing the risk of memory effects and losses of analytes to the capillary walls. With a comparison of the continuous method to the established conventional decontamination and analysis procedure for discrete samples, we demonstrate the accuracy of the continuous method for Tl analyses.

Detection of Organic Compounds in Ice Cores for Application to Palaeoclimate Reconstruction - Methodological Development

NASA Astrophysics Data System (ADS)

Giorio, C.; King, A. C. F.; Wolff, E. W.; Kalberer, M.; Thomas, E. R.; Mulvaney, R.

2016-12-01

Records of inorganic gases and particles trapped in ice core layers have provided some of the most important insights to our understanding of climate of the last 800,000 years. Organic compounds within the ice, however, are an un-tapped reservoir of information. In particular, two groups of compounds emitted from the terrestrial biosphere, fatty acids and terpene secondary oxidation aerosols (SOAs), display characteristics required for ice core paleoclimate reconstruction; emission rates depend on atmospheric states (e.g. temperature), compounds survive long-distance transport in the atmosphere to high altitudes and latitudes (Grannas et al., 2004; Fu et al., 2013 among others), and are shown to survive in ice layers up to 450 yrs old for fatty acids in Greenland (Kawamura et al., 1996) and 350 yrs for SOAs in Alaska (Pokhrel et al., 2015). Here, we aim to develop a single method for quantification of all compounds of interest over longer timescales and further locations using liquid chromatography (LC) ultrahigh resolution mass spectrometry (LTQ Orbitrap). Initial quantification of compound contamination from sources such as drilling fluids and storage bags, diffusing through outer ice core surfaces, suggests compound contamination is limited to the outer few mm's of ice over periods of a few months. Detection limits were in the order of 1-5 ppb for the compounds of interest, leading to the trial of pre-concentration methods using stir bar sorbtive extraction (SBSE) to facilitate detection of ppt concentration levels, as expected for these types of compounds based on previous analysis of snow samples (Pokhrel et al., 2015). Detection of these compounds seems highly viable, with promise for long-term records being achieved in the near future. Fu et al.(2013) Biogeosciences, 10(2), 653-667; Grannas et al.(2004) Global Biogeochem. Cycles, 18, GB1006; Kawamura et al.(1996) Geophys. Res. Lett., 23(19), 2665-2668; Pokhrel et al.(2015) Atmos. Environ., 130, 105-112.

Rapid shifts in South American montane climates driven by pCO2 and ice volume changes over the last two glacial cycles

NASA Astrophysics Data System (ADS)

Groot, M. H. M.; Bogotá, R. G.; Lourens, L. J.; Hooghiemstra, H.; Vriend, M.; Berrio, J. C.; Tuenter, E.; van der Plicht, J.; van Geel, B.; Ziegler, M.; Weber, S. L.; Betancourt, A.; Contreras, L.; Gaviria, S.; Giraldo, C.; González, N.; Jansen, J. H. F.; Konert, M.; Ortega, D.; Rangel, O.; Sarmiento, G.; Vandenberghe, J.; van der Hammen, T.; van der Linden, M.; Westerhoff, W.

2010-10-01

Tropical montane biome migration patterns in the northern Andes are found to be coupled to glacial-induced mean annual temperature (MAT) changes; however, the accuracy and resolution of current records are insufficient to fully explore their magnitude and rates of change. Here we present a ~60-year resolution pollen record over the past 284 000 years from Lake Fúquene (5° N) in Colombia. This record shows rapid and extreme MAT changes at 2540 m elevation of up to 10 ± 2 °C within a few hundred of years that concur with the ~100 and 41-kyr (obliquity) paced glacial cycles and North Atlantic abrupt climatic events as documented in ice cores and marine sediments. Using transient climate modelling experiments we demonstrate that insolation-controlled ice volume and greenhouse gasses are the major forcing agents causing the orbital MAT changes, but that the model simulations significantly underestimate changes in lapse rates and local hydrology and vegetation feedbacks within the studied region due to its low spatial resolution.

Dynamics, rate and nature of retreat of the British Irish Ice-Sheet offshore of NW Ireland following the Last Glacial Maximum

NASA Astrophysics Data System (ADS)

Weilbach, K.; O'Cofaigh, C.; Lloyd, J. M.; Benetti, S.; Dunlop, P.

2016-12-01

Recent studies of the British and Irish Ice Sheet (BIIS) have identified evidence of ice extending to the continental shelf edge along the western margin of the ice sheet off NW Ireland. While this advance is assumed to have occurred during the LGM, exact timing of maximum advance, and the timing and nature of the subsequent retreat is not well constrained. The location of the north-western sector of the BIIS adjacent to the North Atlantic makes this area ideal to study the ice sheet dynamics of a major marine terminating ice sheet, and the rate and nature of its retreat following the LGM. High resolution swath bathymetry and sub-bottom profiler (SBP) data along with sedimentological, micropalaeontological and geochronological investigations of sediment cores, collected across the NW Irish shelf, have been used to establish the extent, timing and nature of retreat of this sector of the BIIS. Swath bathymetry show glacial landforms on the shelf, and SBP-data along with twenty seven vibro-cores were collected in east-west oriented transects across a series of arcuate recessional moraines stretching from the shelf edge to Donegal Bay. These moraines record progressive still stands of a lobate ice margin during its retreat from the shelf edge, and are therefore ideal for the investigation of ice-sheet dynamics and chronology during retreat. Twenty two radiocarbon dates from foraminifera and macrofossils, sampled from the sediment cores, indicate that maximum ice sheet extent occurred around 26200 y cal BP, with an initial rapid retreat across the shelf. Visual logging, X-ray imagery, MSCL data and palaeoenvironmental analyses of the sediment cores, indicate that retreat happened in a glacimarine environment, and was punctuated by multiple stillstands and possible readvances across the mid and inner shelf, forming the arcuate moraines. The radiocarbon dates suggest that final retreat occurred after 17857 y. cal BP, which is consistent with onshore cosmogenic exposure ages from NW Ireland, showing de-glaciation around 17400 y cal BP.

First identification and characterization of Borrobol‐type tephra in the Greenland ice cores: new deposits and improved age estimates

PubMed Central

Davies, Siwan M.; Guðmundsdóttir, Esther R.; Abbott, Peter M.; Pearce, Nicholas J. G.

2018-01-01

ABSTRACT Contiguous sampling of ice spanning key intervals of the deglaciation from the Greenland ice cores of NGRIP, GRIP and NEEM has revealed three new silicic cryptotephra deposits that are geochemically similar to the well‐known Borrobol Tephra (BT). The BT is complex and confounded by the younger closely timed and compositionally similar Penifiler Tephra (PT). Two of the deposits found in the ice are in Greenland Interstadial 1e (GI‐1e) and an older deposit is found in Greenland Stadial 2.1 (GS‐2.1). Until now, the BT was confined to GI‐1‐equivalent lacustrine sequences in the British Isles, Sweden and Germany, and our discovery in Greenland ice extends its distribution and geochemical composition. However, the two cryptotephras that fall within GI‐1e ice cannot be separated on the basis of geochemistry and are dated to 14358 ± 177 a b2k and 14252 ± 173 a b2k, just 106 ± 3 years apart. The older deposit is consistent with BT age estimates derived from Scottish sites, while the younger deposit overlaps with both BT and PT age estimates. We suggest that either the BT in Northern European terrestrial sequences represents an amalgamation of tephra from both of the GI‐1e events identified in the ice‐cores or that it relates to just one of the ice‐core events. A firm correlation cannot be established at present due to their strong geochemical similarities. The older tephra horizon, found within all three ice‐cores and dated to 17326 ± 319 a b2k, can be correlated to a known layer within marine sediment cores from the North Iceland Shelf (ca. 17179‐16754 cal a BP). Despite showing similarities to the BT, this deposit can be distinguished on the basis of lower CaO and TiO2 and is a valuable new tie‐point that could eventually be used in high‐resolution marine records to compare the climate signals from the ocean and atmosphere. PMID:29576671

Measurements of acetylene in air extracted from polar ice cores

NASA Astrophysics Data System (ADS)

Nicewonger, M. R.; Aydin, M.; Montzka, S. A.; Saltzman, E. S.

2016-12-01

Acetylene (ethyne) is a non-methane hydrocarbon emitted during combustion of fossil fuels, biofuels, and biomass. The major atmospheric loss pathway of acetylene is oxidation by hydroxyl radical with a lifetime estimated at roughly two weeks. The mean annual acetylene levels over Greenland and Antarctica are 250 ppt and 20 ppt, respectively. Firn air measurements suggest atmospheric acetylene is preserved unaltered in polar snow and firn. Atmospheric reconstructions based on firn air measurements indicate acetylene levels rose significantly during the twentieth century, peaked near 1980, then declined to modern day levels. This historical trend is similar to that of other fossil fuel-derived non-methane hydrocarbons. In the preindustrial atmosphere, acetylene levels should primarily reflect emissions from biomass burning. In this study, we present the first measurements of acetylene in preindustrial air extracted from polar ice cores. Air from fluid and dry-drilled ice cores from Summit, Greenland and WAIS-Divide Antarctica is extracted using a wet-extraction technique. The ice core air is analyzed using gas chromatography and high-resolution mass spectrometry. Between 1400 to 1800 C.E., acetylene levels over Greenland and Antarctica varied between roughly 70-120 ppt and 10-30 ppt, respectively. The preindustrial Greenland acetylene levels are significantly lower than modern levels, reflecting the importance of northern hemisphere fossil fuel sources today. The preindustrial Antarctic acetylene levels are comparable to modern day levels, indicating similar emissions in the preindustrial atmosphere, likely from biomass burning. The implications of the preindustrial atmospheric acetylene records from both hemispheres will be discussed.

9,400 years of cosmic radiation and solar activity from ice cores and tree rings

PubMed Central

Steinhilber, Friedhelm; Beer, Jürg; Brunner, Irene; Christl, Marcus; Fischer, Hubertus; Heikkilä, Ulla; Kubik, Peter W.; Mann, Mathias; McCracken, Ken G.; Miller, Heinrich; Miyahara, Hiroko; Oerter, Hans

2012-01-01

Understanding the temporal variation of cosmic radiation and solar activity during the Holocene is essential for studies of the solar-terrestrial relationship. Cosmic-ray produced radionuclides, such as 10Be and 14C which are stored in polar ice cores and tree rings, offer the unique opportunity to reconstruct the history of cosmic radiation and solar activity over many millennia. Although records from different archives basically agree, they also show some deviations during certain periods. So far most reconstructions were based on only one single radionuclide record, which makes detection and correction of these deviations impossible. Here we combine different 10Be ice core records from Greenland and Antarctica with the global 14C tree ring record using principal component analysis. This approach is only possible due to a new high-resolution 10Be record from Dronning Maud Land obtained within the European Project for Ice Coring in Antarctica in Antarctica. The new cosmic radiation record enables us to derive total solar irradiance, which is then used as a proxy of solar activity to identify the solar imprint in an Asian climate record. Though generally the agreement between solar forcing and Asian climate is good, there are also periods without any coherence, pointing to other forcings like volcanoes and greenhouse gases and their corresponding feedbacks. The newly derived records have the potential to improve our understanding of the solar dynamics and to quantify the solar influence on climate. PMID:22474348

9,400 years of cosmic radiation and solar activity from ice cores and tree rings.

PubMed

Steinhilber, Friedhelm; Abreu, Jose A; Beer, Jürg; Brunner, Irene; Christl, Marcus; Fischer, Hubertus; Heikkilä, Ulla; Kubik, Peter W; Mann, Mathias; McCracken, Ken G; Miller, Heinrich; Miyahara, Hiroko; Oerter, Hans; Wilhelms, Frank

2012-04-17

Understanding the temporal variation of cosmic radiation and solar activity during the Holocene is essential for studies of the solar-terrestrial relationship. Cosmic-ray produced radionuclides, such as (10)Be and (14)C which are stored in polar ice cores and tree rings, offer the unique opportunity to reconstruct the history of cosmic radiation and solar activity over many millennia. Although records from different archives basically agree, they also show some deviations during certain periods. So far most reconstructions were based on only one single radionuclide record, which makes detection and correction of these deviations impossible. Here we combine different (10)Be ice core records from Greenland and Antarctica with the global (14)C tree ring record using principal component analysis. This approach is only possible due to a new high-resolution (10)Be record from Dronning Maud Land obtained within the European Project for Ice Coring in Antarctica in Antarctica. The new cosmic radiation record enables us to derive total solar irradiance, which is then used as a proxy of solar activity to identify the solar imprint in an Asian climate record. Though generally the agreement between solar forcing and Asian climate is good, there are also periods without any coherence, pointing to other forcings like volcanoes and greenhouse gases and their corresponding feedbacks. The newly derived records have the potential to improve our understanding of the solar dynamics and to quantify the solar influence on climate.

CALICE: Calibrating Plant Biodiversity in Glacier Ice

NASA Astrophysics Data System (ADS)

Festi, Daniela; Cristofori, Antonella; Vernesi, Cristiano; Zerbe, Stefan; Wellstein, Camilla; Maggi, Valter; Oeggl, Klaus

2017-04-01

The objective of the project is to reconstruct plant biodiversity and its trend archived in Alpine glacier ice by pollen and eDNA (environmental DNA) during the last five decades by analyzing a 40 m ice core. For our study we chose the Adamello glacier (Trentino - Südtirol, Lombardia) because of i) the good preservation conditions for pollen and eDNA in ice, ii) the thickness of the ice cap (270m) and iii) the expected high time resolution. The biodiversity estimates gained by pollen analysis and eDNA will be validated by historical biodiversity assessments mainly based on vegetation maps, aerial photos and vegetation surveys in the catchment area of the Adamello glacier for the last five decades. This historical reconstruction of biodiversity trends will be performed on a micro-, meso- and macro-scale (5, 20-50 and 50-100 Km radius, respectively). The results will serve as a calibration data set on biodiversity for future studies, such as the second step of the coring by the POLLiCE research consortium (pollice.fmach.it). In fact, arrangements are currently been made to drill the complete ice cap and retrieve a 270 m thick core which has the potential to cover a time span of minimum 400 years up to several millennia. This second stage will extend the time scale and enable the evaluation of dissimilarity/similarity of modern biodiversity in relation to Late Holocene trends. Finally, we believe this case study has the potential to be applied in other glaciated areas to evaluate biodiversity for large regions (e.g. central Asian mountain ranges, Tibet and Tian Shan or the Andes).

Micro-investigation of EPICA Dome C bottom ice: evidence of long term in situ processes involving acid-salt interactions, mineral dust, and organic matter

NASA Astrophysics Data System (ADS)

de Angelis, M.; Tison, J.-L.; Morel-Fourcade, M.-C.; Susini, J.

2013-10-01

The EPICA Dome C ice core (EDC) reached a final depth of 3260 m, at a maximum height of about 15 m above the ice-bedrock interface in December 2004. We present here data gained from a detailed investigation of selected samples of the deeper part of the core located below 3200 m and referred to as bottom ice. This part of the core has been poorly investigated so far mainly because there are significant challenges in interpreting paleo-records that were very likely modified by long term in situ processes. Our study combines high resolution ion chromatography, high resolution synchrotron X-Ray micro-fluorescence (micro XRF), scanning, and transmission electron microscopy. Our aim was to identify the long term physico-chemical processes at work close to the bedrock, to determine how they have altered the initial registers, and, ultimately to extract information on the very ancient Antarctic environment. The ubiquitous presence of nanometer iron oxide crystals at the surface of wind-borne dust aggregates containing also large amount of organic matter raises the possibility that the consolidation of windborne dust clusters formed during ice recrystallization could be related to microbial iron reduction and, thus, to the progressive reactivation of dormant bacterial activity in warming ice. Inclusions of size and number density increasing with depth observed in the 12 last meters (3248-3260 m) contain liquid and solid species, among them marine biogenic acids, numerous wind-borne dust aggregates and clusters of large reversible calcium carbonate particles precipitated once the inclusion was formed and often covered by secondary gypsum. The refreezing of slush lenses is discussed as a potential cause of the formation of such heterogeneous and complex mixtures. In addition to the very fine micrometer size minerals windborne from extra-Antarctic continental sources and often accreted in large aggregates, single medium size particles (a few to ca 20 μm and among them organic debris) are commonly encountered. Their size, surface shape, and mineralogy suggest that aerosol transport from Antarctic ice-free areas played a significant role at the time EDC bottom ice was formed. Concentrations and concentration ratios of biogenic sulfur species also advocate for the strengthening of peri-Antarctic meteorological patterns that favor the inland penetration of disturbed flow carrying local material. Very large well preserved mineral particles several tens of micrometers in diameter, and biotope relics in deeper ice close to 3260 m likely come from the sub-glacial environment.

Greenhouse Gas Concentration Records Extended Back to 800,000 Years From the EPICA Dome C Ice Core

NASA Astrophysics Data System (ADS)

Chappellaz, J.; Luethi, D.; Loulergue, L.; Barnola, J.; Bereiter, B.; Blunier, T.; Jouzel, J.; Lefloch, M.; Lemieux, B.; Masson-Delmotte, V.; Raynaud, D.; Schilt, A.; Siegenthaler, U.; Spahni, R.; Stocker, T.

2007-12-01

The deep ice core recovered from Dome Concordia in the framework of EPICA, the European Project for Ice Coring in Antarctica, has extended the record of Antarctic climate history back to 800,000 years [Jouzel et al., 2007]. We present the current status of measurements of CO2, CH4 and N2O on air trapped in the bubbles of the Dome C ice core. CO2 is measured in two laboratories using different techniques (laser absorption spectroscopy or gas chromatography on samples of 8 and 40 g of ice which are mechanically crushed or milled, respectively). CH4 and N2O are extracted using a melt-refreeze technique and then measured by gas chromatography (in two laboratories for CH4). The greenhouse gas concentrations have now been measured on the lowest 200 m of the Dome C core, going back to Marine Isotope Stage 20 (MIS 20) as verified by a consistent gas age/ice age difference determined at termination IX [Jouzel et al., 2007]. The atmospheric CO2 concentration mostly lagged the Antarctic temperature with a rather strong correlation throughout the eight and a half glacial cycles, but with significantly lower CO2 values between 650 and 750 kyr BP. Its lowest level ever measured in ice cores (172 ppmv) is observed during MIS 16 (minimum centered at 667 kyr BP according to the EDC3 chronology) redetermining the natural span of CO2 to 172-300 ppmv. With 2245 individual measurements, the CH4 concentration is now reconstructed over 800,000 years from a single core, with an average time resolution of 380 years. Spectral analyses of the CH4 signal show an increasing contribution of precession during the last four climatic cycles compared with the four older ones, suggesting an increasing impact of low latitudes sources/sinks. Millennial scale features in this very detailed signal allows us to compare their occurrence with ice volume reconstructions and the isotopic composition of precipitation over the East Antarctic plateau. N2O is still affected by glaciological artefacts involving dust content in the ice, and its exact temporal evolution remains to be deciphered. These measurements represent the basis of the so-called "EPICA Challenge" [Wolff et al., 2005]: they will put the climate and carbon cycle modelers under the challenge of fully understanding how orbital parameters and climate system configurations could have built such tight coupling between atmospheric composition and natural climate change during the late Quaternary. Jouzel et al., Science 317, 793-796, 10 August 2007 Wolff et al., EOS 86, N°38, 341-345, 20 September 2005

Determining Greenland Ice Sheet Accumulation Rates from Radar Remote Sensing

NASA Technical Reports Server (NTRS)

Jezek, Kenneth C.

2002-01-01

An important component of NASA's Program for Arctic Regional Climate Assessment (PARCA) is a mass balance investigation of the Greenland Ice Sheet. The mass balance is calculated by taking the difference between the areally Integrated snow accumulation and the net ice discharge of the ice sheet. Uncertainties in this calculation Include the snow accumulation rate, which has traditionally been determined by interpolating data from ice core samples taken from isolated spots across the ice sheet. The sparse data associated with ice cores juxtaposed against the high spatial and temporal resolution provided by remote sensing , has motivated scientists to investigate relationships between accumulation rate and microwave observations as an option for obtaining spatially contiguous estimates. The objective of this PARCA continuation proposal was to complete an estimate of surface accumulation rate on the Greenland Ice Sheet derived from C-band radar backscatter data compiled in the ERS-1 SAR mosaic of data acquired during, September-November, 1992. An empirical equation, based on elevation and latitude, is used to determine the mean annual temperature. We examine the influence of accumulation rate, and mean annual temperature on C-band radar backscatter using a forward model, which incorporates snow metamorphosis and radar backscatter components. Our model is run over a range of accumulation and temperature conditions. Based on the model results, we generate a look-up table, which uniquely maps the measured radar backscatter, and mean annual temperature to accumulation rate. Our results compare favorably with in situ accumulation rate measurements falling within our study area.

Modern foraminifera assemblages in the Amundsen Sea Embayment

NASA Astrophysics Data System (ADS)

Ewa Jernas, Patrycja; Kuhn, Gerhard; Hillenbrand, Claus-Dieter; Lander Rasmussen, Tine; Forwick, Matthias; Mackensen, Andreas; Schröder, Michael; Smith, James; Klages, Johann Philipp

2015-04-01

The West Antarctic Ice Sheet (WAIS) is considered the most unstable part of the Antarctic Ice Sheet. As the WAIS is mostly grounded below sea level, its stability is of great concern. A collapse of large parts of the WAIS would result in a significant global sea-level rise. At present, the WAIS shows dramatic ice loss in its Amundsen Sea sector, especially in Pine Island Bay. Pine Island Glacier (PIG) is characterised by fast flow, major thinning and rapid grounding-line retreat. Its mass los over recent decades is generally attributed to melting caused by the inflow of warm Circumpolar Deep Water (CDW). Future melting of PIG may result in a sea level tipping point, because it could trigger widespread collapse of the WAIS, especially when considering ongoing climate change. Our research project aims to establish proxies (integration of foraminifera, sediment properties and oceanographic data) for modern environmental conditions by analysing seafloor surface sediments along a transect from the glacier proximal settings to the middle-outer shelf in the eastern Amundsen Sea Embayment. These proxies will then be applied on sediment records spanning the Holocene back to the Last Glacial Maximum for reconstructing spatial and temporal variations of CDW upwelling and ice-ocean interactions during the past c. 23,000 years. We will present preliminary results from the analyses of ten short marine sediment cores (multi and box cores) collected during expeditions JR179 (2008) and ANT-XXVI/3 (2010) along a transect from inner Pine Island Bay to the middle-outer shelf part of the Abbot Palaeo-Ice Stream Trough at water depths ranging from 458 m (middle shelf) to 1444 m (inner shelf). The sediment cores are currently investigated for distribution patterns of planktonic and benthic foraminifera and grain-size distribution at 1 cm resolution. Core tops (0-10 cm) were stained with Rose Bengal for living benthic foraminifera investigations. The chronology of the cores will be based on 210Pb and calibrated 14C dates. First results reveal the presence of living benthic foraminifera in surface sediments of all investigated cores suggesting that modern seabed surfaces were recovered. Moreover, a core retrieved from a water depth of 793 m in the Abbot Palaeo-Ice Stream Trough shows particularly high abundances of planktonic foraminifera Neogloboquadrina pachyderma.

Spatial Variability of Climate Signatures Recorded in an Array of Shallow Firn Cores from the Western Greenland Percolation Zone

NASA Astrophysics Data System (ADS)

Thundercloud, Z. R.; Osterberg, E. C.; Ferris, D. G.; Graeter, K.; Lewis, G.; Hawley, R. L.; Marshall, H. P.

2016-12-01

Greenland ice cores provide seasonally to annually resolved proxy records of past temperature, accumulation and atmospheric circulation. Most Greenland ice cores have been collected from the dry snow zone at elevations greater than 2500 m to produce records of North Atlantic paleoclimate over the last full glacial cycle. Ice cores collected from more costal regions, however, provide the opportunity to develop regional-scale records of climate conditions along ice sheet margins where recent temperature and precipitation changes have been larger than those in the ice sheet interior. These cores are more readily comparable to lake sediment and landscape (i.e. moraine) records from the ice sheet margin, and are potentially more sensitive to sea-ice variability due to the proximity to the coast. Here we present major ion and stable isotope records from an array of firn cores (40-55 year records) collected in the western Greenland percolation zone, and assess the spatial variability of ice core statistical relationships with the North Atlantic Oscillation (NAO) and Baffin Bay sea ice extent. Seven cores were collected from elevations of 2100-2500 m along a 400-km segment of the ice sheet from Dye-2 to Milcent as part of the Greenland Traverse for Accumulation and Climate Studies (GreenTrACS) project from May-June 2016. They were sampled by a continuous melter system at Dartmouth College, and analyzed using Dionex ion chromatographs and a Picarro L2130-i laser ring-down spectrometer. We focus on the signature of the NAO and Baffin Bay sea ice extent in the sea-salt, dust, deuterium excess (d-excess), and methanesulfonic acid (MSA) firn core records, and assess the special variability of these climate-ice core relationships across the study area. Climate reanalysis data indicate that NAO-ice core correlations should be stronger at lower elevation in the percolation zone than high in the dry snow zone. Our results will provide valuable insight into the sensitivity of Greenland ice core paleoclimate reconstructions to the specific ice core location, and thereby aid in site selection for deeper ice cores that could span the Holocene.

Rapid coupling between ice volume and polar temperature over the past 150,000 years.

PubMed

Grant, K M; Rohling, E J; Bar-Matthews, M; Ayalon, A; Medina-Elizalde, M; Ramsey, C Bronk; Satow, C; Roberts, A P

2012-11-29

Current global warming necessitates a detailed understanding of the relationships between climate and global ice volume. Highly resolved and continuous sea-level records are essential for quantifying ice-volume changes. However, an unbiased study of the timing of past ice-volume changes, relative to polar climate change, has so far been impossible because available sea-level records either were dated by using orbital tuning or ice-core timescales, or were discontinuous in time. Here we present an independent dating of a continuous, high-resolution sea-level record in millennial-scale detail throughout the past 150,000 years. We find that the timing of ice-volume fluctuations agrees well with that of variations in Antarctic climate and especially Greenland climate. Amplitudes of ice-volume fluctuations more closely match Antarctic (rather than Greenland) climate changes. Polar climate and ice-volume changes, and their rates of change, are found to covary within centennial response times. Finally, rates of sea-level rise reached at least 1.2 m per century during all major episodes of ice-volume reduction.

An ultra-high resolution last deglacial marine sediment records of the Northwest Atlantic Ocean

NASA Astrophysics Data System (ADS)

Rashid, H.; Piper, D.; Marche, B.; Vermooten, M.; Lazar, K.; Brockway, B.

2016-12-01

Lack of high sedimentation rate records of past changes pertaining to the late Pleistocene Laurentide ice-sheet (LIS) dynamics has prevented efforts to differentiate the various forcings in modulating abrupt climate changes. Here, we present an ultra-high resolution sediment record spanning approximately 1,500 km of the Eastern Canadian continental margin. The new record comprises four sediment cores which were collected from the northwest Labrador Sea (i.e., Saglek Bank) to southwestern Flemish Pass to the southeast Grand Banks in outer shelf and slope settings. Fifty new 14C-accelerator mass spectrometric dates were obtained to construct the stratigraphy. The total sediment thickness of the new record is 41 m covering the past 26 ka with 1.58/ka mean sediment rate, the highest sediment rate ever reported from the Northwest Atlantic Ocean for this time interval. Further, the temporal resolution of the record varies from a couple of decades to centuries depending on the time interval. X-ray fluorescence (XRF) data in conjunction with physical properties of sediments and petrology allowed us to distinguish sediment delivered by major ice-streams of the LIS namely the Hudson Strait, Hopedale Saddle, and Cumberland Sound ice streams. Heinrich layers 1 and 2 are well identified by their Labrador Sea specific characteristics. The so-called Younger Dryas equivalent Heinrich layer H0 was identified in these cores but the timing of onset of H0 has an offset by nearly 1,000 years with that of the 12.9 ka, suggesting that the YD event was not initiated by the Hudson Strait compared to other Heinrich events.

High-Resolution NU-WRF Simulations of a Deep Convective-Precipitation System During MC3E. Part 1; Comparisons Between Goddard Microphysics Schemes and Observations

NASA Technical Reports Server (NTRS)

Tao, Wei-Kuo; Wu, Di; Lang, Stephen; Chern, Jiundar; Peters-Lidard, Christa; Fridlind, Ann; Matsui, Toshihisa

2015-01-01

The Goddard microphysics scheme was recently improved by adding a 4th ice class (frozen dropshail). This new 4ICE scheme was implemented and tested in the Goddard Cumulus Ensemble model (GCE) for an intense continental squall line and a moderate,less-organized continental case. Simulated peak radar reflectivity profiles were improved both in intensity and shape for both cases as were the overall reflectivity probability distributions versus observations. In this study, the new Goddard 4ICE scheme is implemented into the regional-scale NASA Unified - Weather Research and Forecasting model (NU-WRF) and tested on an intense mesoscale convective system that occurred during the Midlatitude Continental Convective Clouds Experiment (MC3E). The NU42WRF simulated radar reflectivities, rainfall intensities, and vertical and horizontal structure using the new 4ICE scheme agree as well as or significantly better with observations than when using previous versions of the Goddard 3ICE (graupel or hail) schemes. In the 4ICE scheme, the bin microphysics-based rain evaporation correction produces more erect convective cores, while modification of the unrealistic collection of ice by dry hail produces narrow and intense cores, allowing more slow-falling snow to be transported rearward. Together with a revised snow size mapping, the 4ICE scheme produces a more horizontally stratified trailing stratiform region with a broad, more coherent light rain area. In addition, the NU-WRF 4ICE simulated radar reflectivity distributions are consistent with and generally superior to those using the GCE due to the less restrictive open lateral boundaries

Atmospheric depositions of black carbon, inorganic pollutants and mineral dust from the Ortles, Eastern European Alps ice cores during the last 3000 years

NASA Astrophysics Data System (ADS)

Bertò, Michele; Barbante, Carlo; Gabrielli, Paolo; Gabrieli, Jacopo; Spolaor, Andrea; Dreossi, Giuliano; Laj, Paolo; Zanatta, Marco; Stenni, Barbara

2017-04-01

Reconstructions of the atmospheric content of black carbon, heavy metals and mineral dust covering millennial time scales are rare, particularly in the European region. Evaluating the human impact on the environment through mining and industrial activities, road traffic, biomass and coal burning, and the naturally emitted aerosols atmospheric load, is important to know the degree of contaminations and the quality of melting water, the radiative effect on the glacier's radiative balance, the atmospheric aerosols' climatic impacts and the recent decades pollutions emissions policies' efficiencies. Four ice cores were drilled in 2011 from the "Alto dell'Ortles" (3859 m), the highest glacier of the Mt. Ortles massif (South Tirol, Italy). Three 74 m long ice cores were dated by mean of 210Pb, tritium, beta emissions and 14C analyses following also the new dating technique based on filtering the ice for extracting the carbonaceous component of the deposited aerosols. The depth-age curve was obtained by using a Monte Carlo based empirical fitting model (COPRA). The basal ice of core#2 and #3 was dated back to about 7000 years b.p., whereas that of core#1, about one meter shorter, to 3000 years before present. Below the firn-ice transition, at a depth of about 24 m, the borehole temperature revealed the presence of well-preserved cold ice (Gabrielli et al, 2012). The O and H stable isotopes profiles describe well the atmospheric warming as well as the low temperatures recorded during the Little Ice Age (LIA). The proximity of the "Alto dell'Ortles" to densely industrialized areas (Po Valley) makes these ice cores specifically suited for reconstructing the anthropogenic impacts in the Eastern European Alpine region over the last 3 millennia. The ice core#1 was analyzed with a "Continuous Flow Analysis" system (CFA). The separation between internal and external parts of the core prevents any kind of contamination. The core was melted at about 2.5 cm min-1 and simultaneous analyses of conductivity, dust concentration and size distribution (from 0.8 to 80 μm), trace elements with Inductive Coupled Plasma Mass Spectrometer (ICP-MS, Agilent 7500) and refractory black carbon (rBC) with the Single Particle Soot Photometer (SP2, Droplet Measurement Technologies) were performed. A fraction of the melt water was collected by an auto-sampler. More than 1000 samples were analyzed discreetly with a CRC-ICP-MS (with the highest resolution of about 3 cm). The rBC shows significant variability over the last century peaking in concentrations of about 10 ng g-1 from the 1920s to the 1970s, whereas very low values characterized the period from 1000 BC to 1850 AD. The seasonality appears to be preserved even in the firn temperate part of the core as argued from the comparison with the water stable isotopes ratios (δO18). The overall determined trace elements are Li, Na, Mg, Al, K, Ca, Ti, V, Cr, Mn, Fe, Co, Cu, Zn, As, Se, Sr, Ag, Cd, Sb, Te, I, Cs, Ba, Hg, Tl, Pb, Bi, U. The Enrichment Factors (EF) for the crustal elements didn't show any particular trend. While mining and smelting activities appeared to be the most significant heavy metals sources before the 19th century, other anthropogenic heavy metals strongly increased from the onset of the Industrial Revolutions.

Constraining recent lead pollution sources in the North Pacific using ice core stable lead isotopes

NASA Astrophysics Data System (ADS)

Gross, B. H.; Kreutz, K. J.; Osterberg, E. C.; McConnell, J. R.; Handley, M.; Wake, C. P.; Yalcin, K.

2012-08-01

Trends and sources of lead (Pb) aerosol pollution in the North Pacific rim of North America from 1850 to 2001 are investigated using a high-resolution (subannual to annual) ice core record recovered from Eclipse Icefield (3017 masl; St. Elias Mountains, Canada). Beginning in the early 1940s, increasing Pb concentration at Eclipse Icefield occurs coevally with anthropogenic Pb deposition in central Greenland, suggesting that North American Pb pollution may have been in part or wholly responsible in both regions. Isotopic ratios (208Pb/207Pb and 206Pb/207Pb) from 1970 to 2001 confirm that a portion of the Pb deposited at Eclipse Icefield is anthropogenic, and that it represents a variable mixture of East Asian (Chinese and Japanese) emissions transported eastward across the Pacific Ocean and a North American component resulting from transient meridional atmospheric flow. Based on comparison with source material Pb isotope ratios, Chinese and North American coal combustion have likely been the primary sources of Eclipse Icefield Pb over the 1970-2001 time period. The Eclipse Icefield Pb isotope composition also implies that the North Pacific mid-troposphere is not directly impacted by transpolar atmospheric flow from Europe. Annually averaged Pb concentrations in the Eclipse Icefield ice core record show no long-term trend during 1970-2001; however, increasing208Pb/207Pb and decreasing 206Pb/207Pb ratios reflect the progressive East Asian industrialization and increase in Asian pollutant outflow. The post-1970 decrease in North American Pb emissions is likely necessary to explain the Eclipse Icefield Pb concentration time series. When compared with low (lichen) and high (Mt. Logan ice core) elevation Pb data, the Eclipse ice core record suggests a gradual increase in pollutant deposition and stronger trans-Pacific Asian contribution with rising elevation in the mountains of the North Pacific rim.

High-resolution sedimentary effects of post-Little Ice Age glacial recession in Hornsund (Svalbard) - insights from chirp and core data

NASA Astrophysics Data System (ADS)

Dominiczak, Aleksander; Szczuciński, Witold; Moskalik, Mateusz; Forwick, Matthias

2017-04-01

As a result of global warming from the end of the Little Ice Age a fast withdrawal and loss of mass of many glaciers have been observed. The retreat has been particularly rapid in case of tidewater glaciers of Spitsbergen, where in an effect a new bays were formed and serve as glaciomarine sediment accumulation areas. The new depocenters in emerging bays are characterized by high sediment accumulation rates. Analysis and quantitative assessment of the processes occurring in these bays can enhance a better understanding of the dynamics of glaciers recession and bio-geochemical processes occurring in the fjords. This is particularly important because the subpolar fjords may be important storage for organic carbon on a global scale (Smith at al. 2015). In order to obtain a detailed high-resolution record of sedimentation history in the post Little Ice Age bays, 30 gravity cores and 18 box cores were collected along with detail seism acoustic surveys (Chirp) during three cruises on board of R/V Helmar Hansen in 2007, 2014 and 2015. The sediment cores revealed two major types of sediments: subglacial till and overlying laminated glacimarine mud with abundant ice rafted debris. The sediment accumulation rate of the latter is estimated to be on average in order of 1 to 5 cm per year. The periods of increase ice rafting are likely related to surge events. The dense Chirp survey grid spatial changeability in the post-Little Ice Age sediment cover. The amount and lithology of sediments in different parts of the bays also helped to link glacier dynamics with sedimentary effect. Our results confirms that despite similarities in lithology there are significant differences in sediment accumulation rates, probably driven by changes in accommodation spaces and sediment delivery. The record is also affected by effects of glacier surges. However, analyses of historical data enhanced the interpretation of sedimentary record and provide hints to identify the specific processes and events in the sedimentary record. The study was funded by Polish National Science Centre grant No. 2013/10/E/ST10/00166. We kindly acknowledge help of the captain and crew of R/V Helmer Hanssen as well as onboard scientific party. Smith, R. W., Bianchi, T. S., Allison, M., Savage, C., & Galy, V. (2015). High rates of organic carbon burial in fjord sediments globally. Nature Geoscience, 8(6), 450-453.

Characterization of winter foraging locations of Adélie penguins along the Western Antarctic Peninsula, 2001-2002

NASA Astrophysics Data System (ADS)

Erdmann, Eric S.; Ribic, Christine A.; Patterson-Fraser, Donna L.; Fraser, William R.

2011-07-01

In accord with the hypotheses driving the Southern Ocean Global Ocean Ecosystems Dynamics (SO GLOBEC) program, we tested the hypothesis that the winter foraging ecology of a major top predator in waters off the Western Antarctic Peninsula (WAP), the Adélie penguin ( Pygoscelis adeliae), is constrained by oceanographic features related to the physiography of the region. This hypothesis grew from the supposition that breeding colonies in the WAP during summer are located adjacent to areas of complex bathymetry where circulation and upwelling processes appear to ensure predictable food resources. Therefore, we tested the additional hypothesis that these areas continue to contribute to the foraging strategy of this species throughout the non-breeding winter season. We used satellite telemetry data collected as part of the SO GLOBEC program during the austral winters of 2001 and 2002 to characterize individual penguin foraging locations in relation to bathymetry, sea ice variability within the pack ice, and wind velocity and divergence (as a proxy for potential areas with cracks and leads). We also explored differences between males and females in core foraging area overlap. Ocean depth was the most influential variable in the determination of foraging location, with most birds focusing their effort on shallow (<200 m) waters near land and on mixed-layer (200-500 m) waters near the edge of deep troughs. Within-ice variability and wind (as a proxy for potential areas with cracks and leads) were not found to be influential variables, which is likely because of the low resolution satellite imagery and model outputs that were available. Throughout the study period, all individuals maintained a core foraging area separated from other individuals with very little overlap. However, from a year with light sea ice to one with heavy ice cover (2001-2002), we observed an increase in the overlap of individual female foraging areas with those of other birds, likely due to restricted access to the water column, reduced prey abundance, or higher prey concentration. Male birds maintained separate core foraging areas with the same small amount of overlap, showing no difference in overlap between the years. While complex bathymetry was an important physical variable influencing the Adélie penguin's foraging, the analysis of sea ice data of a higher resolution than was available for this study may help elucidate the role of sea ice in affecting Adélie penguin winter foraging behavior within the pack ice.

Characterization of winter foraging locations of Adélie penguins along the Western Antarctic Peninsula, 2001–2002

USGS Publications Warehouse

Erdmann, Eric S.; Ribic, Christine; Patterson-Fraser, Donna L.; Fraser, William R.

2011-01-01

In accord with the hypotheses driving the Southern Ocean Global Ocean Ecosystems Dynamics (SO GLOBEC) program, we tested the hypothesis that the winter foraging ecology of a major top predator in waters off the Western Antarctic Peninsula (WAP), the Adélie penguin (Pygoscelis adeliae), is constrained by oceanographic features related to the physiography of the region. This hypothesis grew from the supposition that breeding colonies in the WAP during summer are located adjacent to areas of complex bathymetry where circulation and upwelling processes appear to ensure predictable food resources. Therefore, we tested the additional hypothesis that these areas continue to contribute to the foraging strategy of this species throughout the non-breeding winter season. We used satellite telemetry data collected as part of the SO GLOBEC program during the austral winters of 2001 and 2002 to characterize individual penguin foraging locations in relation to bathymetry, sea ice variability within the pack ice, and wind velocity and divergence (as a proxy for potential areas with cracks and leads). We also explored differences between males and females in core foraging area overlap. Ocean depth was the most influential variable in the determination of foraging location, with most birds focusing their effort on shallow (<200 m) waters near land and on mixed-layer (200–500 m) waters near the edge of deep troughs. Within-ice variability and wind (as a proxy for potential areas with cracks and leads) were not found to be influential variables, which is likely because of the low resolution satellite imagery and model outputs that were available. Throughout the study period, all individuals maintained a core foraging area separated from other individuals with very little overlap. However, from a year with light sea ice to one with heavy ice cover (2001–2002), we observed an increase in the overlap of individual female foraging areas with those of other birds, likely due to restricted access to the water column, reduced prey abundance, or higher prey concentration. Male birds maintained separate core foraging areas with the same small amount of overlap, showing no difference in overlap between the years. While complex bathymetry was an important physical variable influencing the Adélie penguin's foraging, the analysis of sea ice data of a higher resolution than was available for this study may help elucidate the role of sea ice in affecting Adélie penguin winter foraging behavior within the pack ice.

A common and optimized age scale for Antarctic ice cores

NASA Astrophysics Data System (ADS)

Parrenin, F.; Veres, D.; Landais, A.; Bazin, L.; Lemieux-Dudon, B.; Toye Mahamadou Kele, H.; Wolff, E.; Martinerie, P.

2012-04-01

Dating ice cores is a complex problem because 1) there is a age shift between the gas bubbles and the surrounding ice 2) there are many different ice cores which can be synchronized with various proxies and 3) there are many methods to date the ice and the gas bubbles, each with advantages and drawbacks. These methods fall into the following categories: 1) Ice flow (for the ice) and firn densification modelling (for the gas bubbles); 2) Comparison of ice core proxies with insolation variations (so-called orbital tuning methods); 3) Comparison of ice core proxies with other well dated archives; 4) Identification of well-dated horizons, such as tephra layers or geomagnetic anomalies. Recently, an new dating tool has been developped (DATICE, Lemieux-Dudon et al., 2010), to take into account all the different dating information into account and produce a common and optimal chronology for ice cores with estimated confidence intervals. In this talk we will review the different dating information for Antarctic ice cores and show how the DATICE tool can be applied.

Atmospheric CO2 and abrupt climate change on submillennial timescales

NASA Astrophysics Data System (ADS)

Ahn, Jinho; Brook, Edward

2010-05-01

How atmospheric CO2 varies and is controlled on various time scales and under various boundary conditions is important for understanding how the carbon cycle and climate change are linked. Ancient air preserved in ice cores provides important information on past variations in atmospheric CO2. In particular, concentration records for intervals of abrupt climate change may improve understanding of mechanisms that govern atmospheric CO2. We present new multi-decadal CO2 records that cover Greenland stadial 9 (between Dansgaard-Oeschger (DO) events 8 and 9) and the abrupt cooling event at 8.2 ka. The CO2 records come from Antarctic ice cores but are well synchronized with Greenland ice core records using new high-resolution CH4 records,precisely defining the timing of CO2 change with respect to abrupt climate events in Greenland. Previous work showed that during stadial 9 (40~38 ka), CO2 rose by about 15~20 ppm over around 2,000 years, and at the same time temperatures in Antarctica increased. Dust proxies indicate a decrease in dust flux over the same period. With more detailed data and better age controls we now find that approximately half of the CO2 increase during stadial 9 occurred abruptly, over the course of decades to a century at ~39.6 ka. The step increase of CO2 is synchronous with a similar step increase of Antarctic isotopic temperature and a small abrupt change in CH4, and lags after the onset of decrease in dust flux by ~400 years. New atmospheric CO2 records at the well-known ~8.2 ka cooling event were obtained from Siple Dome ice core, Antarctica. Our preliminary CO2 data span 900 years and include 19 data points within the 8.2 ka cooling event, which persisted for ~160 years (Thomas et al., Quarternary Sci. Rev., 2007). We find that CO2 increased by 2~4 ppm during that cooling event. Further analyses will improve the resolution and better constrain the CO2 variability during other times in the early Holocene to determine if the variations observed during at 8.2 ka event are significant.

Trace Element Determination from the Guliya Ice Core to Characterize Aerosol Deposition over the Western Tibetan Plateau during the Last 500 Years

NASA Astrophysics Data System (ADS)

Sierra Hernandez, R.; Gabrielli, P.; Beaudon, E.; Wegner, A.; Thompson, L. G.

2014-12-01

The Tibetan Plateau or Third Pole covers over 5 million km2, and has ~46,000 glaciers that collectively contain one of the Earth's largest stores of fresh water. The Guliya ice cap located in the western Kunlun Shan on the Qinghai-Tibetan Plateau, China, is the largest (> 200 km2) ice cap in the subtropical zone. In 1992, a 308.6 m ice core to bedrock was recovered from the Guliya ice cap. The deepest 20 meters yielded the first record extending back through the last glacial cycle found outside of the Polar Regions. Because of its continental location on the northwestern side of the Tibetan Plateau, the atmospheric circulation over the Guliya ice cap is dominated by westerly air flow from the Eurasian region. Therefore the site is expected to be unaffected by the fallout of anthropogenic trace metals originating from the inner Asian continent and rather may serve to characterize trace metal emissions from the western countries. Here we present preliminary results of the determination of 29 trace elements, Rb, Sr, Nb, Mo, Ag, Cd, Sn, Sb, Cs, Ba, Ta, Tl, Pb, Bi, U, Li, Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, and As, from Guliya ice core samples spanning the period 1500 - 1992 AD at seasonal (1750-1992 AD) and annual (1500-1750 AD) resolution. This Guliya trace element record will complement the developing records from the Dasuopu glacier, central Himalaya, and from the Puruogangri ice cap in the western Tanggula Shan in central Tibetan Plateau, which in contrast to Guliya are influenced by the monsoon. We investigate the possible sources both natural and anthropogenic of atmospheric trace elements and their fluxes over the Tibetan Plateau during the last 500 years.

A tephra lattice for Greenland and a reconstruction of volcanic events spanning 25-45 ka b2k

NASA Astrophysics Data System (ADS)

Bourne, A. J.; Cook, E.; Abbott, P. M.; Seierstad, I. K.; Steffensen, J. P.; Svensson, A.; Fischer, H.; Schüpbach, S.; Davies, S. M.

2015-06-01

Tephra layers preserved within the Greenland ice-cores are crucial for the independent synchronisation of these high-resolution records to other palaeoclimatic archives. Here we present a new and detailed tephrochronological framework for the time period 25,000-45,000 a b2k that brings together results from 4 deep Greenland ice-cores. In total, 99 tephra deposits, the majority of which are preserved as cryptotephra, are described from the NGRIP, NEEM, GRIP and DYE-3 records. The major element signatures of single glass shards within these deposits indicate that 93 are basaltic in composition all originating from Iceland. Specifically, 43 originate from Grimsvötn, 20 are thought to be sourced from the Katla volcanic system and 17 show affinity to the Kverkfjöll system. Robust geochemical characterisations, independent ages derived from the GICC05 ice-core chronology, and the stratigraphic positions of these deposits relative to the Dansgaard-Oeschger climate events represent a key framework that provides new information on the frequency and nature of volcanic events in the North Atlantic region between GS-3 and GI-12. Of particular importance are 19 tephra deposits that lie on the rapid climatic transitions that punctuate the last glacial period. This framework of well-constrained, time-synchronous tie-lines represents an important step towards the independent synchronisation of marine, terrestrial and ice-core records from the North Atlantic region, in order to assess the phasing of rapid climatic changes during the last glacial period.

IceAge: Chemical Evolution of Ices during Star Formation

NASA Astrophysics Data System (ADS)

McClure, Melissa; Bailey, J.; Beck, T.; Boogert, A.; Brown, W.; Caselli, P.; Chiar, J.; Egami, E.; Fraser, H.; Garrod, R.; Gordon, K.; Ioppolo, S.; Jimenez-Serra, I.; Jorgensen, J.; Kristensen, L.; Linnartz, H.; McCoustra, M.; Murillo, N.; Noble, J.; Oberg, K.; Palumbo, M.; Pendleton, Y.; Pontoppidan, K.; Van Dishoeck, E.; Viti, S.

2017-11-01

Icy grain mantles are the main reservoir for volatile elements in star-forming regions across the Universe, as well as the formation site of pre-biotic complex organic molecules (COMs) seen in our Solar System. We propose to trace the evolution of pristine and complex ice chemistry in a representative low-mass star-forming region through observations of a: pre-stellar core, Class 0 protostar, Class I protostar, and protoplanetary disk. Comparing high spectral resolution (R 1500-3000) and sensitivity (S/N 100-300) observations from 3 to 15 um to template spectra, we will map the spatial distribution of ices down to 20-50 AU in these targets to identify when, and at what visual extinction, the formation of each ice species begins. Such high-resolution spectra will allow us to search for new COMs, as well as distinguish between different ice morphologies,thermal histories, and mixing environments. The analysis of these data will result in science products beneficial to Cycle 2 proposers. A newly updated public laboratory ice database will provide feature identifications for all of the expected ices, while a chemical model fit to the observed ice abundances will be released publically as a grid, with varied metallicity and UV fields to simulate other environments. We will create improved algorithms to extract NIRCAM WFSS spectra in crowded fields with extended sources as well as optimize the defringing of MIRI LRS spectra in order to recover broad spectral features. We anticipate that these resources will be particularly useful for astrochemistry and spectroscopy of fainter, extended targets like star forming regions of the SMC/LMC or more distant galaxies.

Investigating the Microscopic Location of Trace Elements in High-Alpine Glacier Ice

NASA Astrophysics Data System (ADS)

Avak, Sven Erik; Birrer, Mario; Laurent, Oscar; Guillong, Marcel; Wälle, Markus; Jenk, Theo Manuel; Bartels-Rausch, Thorsten; Schwikowski, Margit; Eichler, Anja

2017-04-01

Past changes in atmospheric pollution can be reconstructed from high-alpine ice core trace element records (Schwikowski et al., 2004). Percolation of meltwater alters the information originally stored in these environmental archives. Eichler et al. (2001) suggested that the preservation of major ions with respect to meltwater percolation depends on their location in the crystal ice lattice, i.e. grain boundaries versus grain interiors. Other studies have also focused on the effect of meltwater on organic pollutant concentrations as well as on stable isotope profiles in ice cores, whereas no information exists about trace elements. Here, we investigate for the first time the effect of the microscopic location of anthropogenic, dust and volcanic related trace elements on the behavior during meltwater percolation by using two different approaches. On the one hand we assess the microscopic location of trace elements indirectly by analyzing trace element concentrations in a high-alpine ice core, which has been shown to be affected by an inflow of meltwater, using discrete inductively coupled plasma mass spectrometry (ICP-MS). Impurities located at grain boundaries are prone to be removed by meltwater and tend to be depleted in the affected section of the record whereas those incorporated into the ice interior are preserved and not disturbed in the record. In the second approach we work towards a direct quantification of differences in concentrations of trace elements between ice grain boundaries and grain interiors in samples both from unaffected and affected sections of this ice core. Therefore we use cryocell laser ablation (LA) ICP-MS, which is the method of choice for the direct in situ chemical analysis of trace elements at a sub-millimeter resolution in glacier ice (Reinhardt et al., 2001, Della Lunga et al., 2014, Sneed et al., 2015). We will present first results of both approaches with regard to the evaluation of the potential of trace elements as environmental proxies in glaciers partially affected by melting. References Della Lunga, D., Müller, W., Rasmussen, S. O. & Svensson, A. 2014: Location of cation impurities in NGRIP deep ice revealed by cryo-cell UV-laser-ablation ICPMS, Journal of Glaciology, 60, 970-988. Eichler, A., Schwikowski, M., Gäggeler, H. W. 2001: Meltwater-induced relocation of chemical species in Alpine firn, Tellus B, 53, 192-203. Reinhardt, H., Kriews, M., Miller, H., Schrems, O., Lüdke, C., Hoffmann, E. & Skole, J. 2001: Laser ablation inductively coupled plasma mass spectrometry: a new tool for trace element analysis in ice cores, Fresenius' Journal of Analytical Chemistry, 370, 629-636. Schwikowski, M., Barbante, C., Doering, T., Gäggeler, H. W., Boutron, C., Schotterer, U., Tobler, L., van de Velde, K., Ferrari, C., Cozzi, G., Rosman, K., Cescon, P. 2004: Post-17th-Century Changes of European Lead Emissions Recorded in High-Altitude Alpine Snow and Ice, Environmental Science & Technology, 38, 957-964. Sneed, S. B., Mayewski, P. A., Sayre, W. G., Handley, M. J., Kurbatov, A. V., Taylor, K. C., Bohleber, P., Wagenbach, D., Erhardt, T. & Spaulding, N. E. 2015: New LA-ICP-MS cryocell and calibration technique for sub-millimeter analysis of ice cores, Journal of Glaciology, 61, 233-242.

In-situ observation of bubble trapping in polar firn

NASA Astrophysics Data System (ADS)

Florian Schaller, Christoph; Freitag, Johannes; Sowers, Todd; Vinther, Bo; Weinhart, Alexander; Eisen, Olaf

2017-04-01

The air trapped in polar ice cores is not a direct record of past atmospheric composition but is strongly influenced by the process of firnification as bubbles are only sealed at a certain point, when the respective horizontal layer reaches a so called "critical" porosity. In order to investigate this process, we performed high-resolution (approximately 25 μm) 3D-XCT measurements of the complete lock-in zone for two polar ice cores representing opposite extremes of the temperature and accumulation rate range: B53, close to Dome Fuji, East Antarctica and RECAP_S2, Renland, Greenland. For every 1m core segment, we scanned a minimum number of five sections of approximately 3.5cm height of the full core diameter with a focus on homogenous layers. This allows us to non-destructively deduce detailed profiles of open and closed porosity on a solid statistical basis. For each of the cores individually, we find that the trapping of bubbles in a single layer is solely determined by its total porosity and thereby independent of depth. We can confirm the existence of a distinct Schwander-type relation of closed and total porosity. Even though the two cores deviate from each other significantly in critical porosity, 0.0907 for B53 compared to 0.1025 for RECAP_S2, we observe many similarities. We hypothesize, that the determining factors of bubble trapping are the average size and variability of pore space structures. This could potentially allow the reconstruction of past close-off porosities from the remaining pore structures in deep ice, e.g. from bubble number densities.

Precise interpolar phasing of abrupt climate change during the last ice age.

PubMed

2015-04-30

The last glacial period exhibited abrupt Dansgaard-Oeschger climatic oscillations, evidence of which is preserved in a variety of Northern Hemisphere palaeoclimate archives. Ice cores show that Antarctica cooled during the warm phases of the Greenland Dansgaard-Oeschger cycle and vice versa, suggesting an interhemispheric redistribution of heat through a mechanism called the bipolar seesaw. Variations in the Atlantic meridional overturning circulation (AMOC) strength are thought to have been important, but much uncertainty remains regarding the dynamics and trigger of these abrupt events. Key information is contained in the relative phasing of hemispheric climate variations, yet the large, poorly constrained difference between gas age and ice age and the relatively low resolution of methane records from Antarctic ice cores have so far precluded methane-based synchronization at the required sub-centennial precision. Here we use a recently drilled high-accumulation Antarctic ice core to show that, on average, abrupt Greenland warming leads the corresponding Antarctic cooling onset by 218 ± 92 years (2σ) for Dansgaard-Oeschger events, including the Bølling event; Greenland cooling leads the corresponding onset of Antarctic warming by 208 ± 96 years. Our results demonstrate a north-to-south directionality of the abrupt climatic signal, which is propagated to the Southern Hemisphere high latitudes by oceanic rather than atmospheric processes. The similar interpolar phasing of warming and cooling transitions suggests that the transfer time of the climatic signal is independent of the AMOC background state. Our findings confirm a central role for ocean circulation in the bipolar seesaw and provide clear criteria for assessing hypotheses and model simulations of Dansgaard-Oeschger dynamics.

A New Multielement Method for LA-ICP-MS Data Acquisition from Glacier Ice Cores.

PubMed

Spaulding, Nicole E; Sneed, Sharon B; Handley, Michael J; Bohleber, Pascal; Kurbatov, Andrei V; Pearce, Nicholas J; Erhardt, Tobias; Mayewski, Paul A

2017-11-21

To answer pressing new research questions about the rate and timing of abrupt climate transitions, a robust system for ultrahigh-resolution sampling of glacier ice is needed. Here, we present a multielement method of LA-ICP-MS analysis wherein an array of chemical elements is simultaneously measured from the same ablation area. Although multielement techniques are commonplace for high-concentration materials, prior to the development of this method, all LA-ICP-MS analyses of glacier ice involved a single element per ablation pass or spot. This new method, developed using the LA-ICP-MS system at the W. M. Keck Laser Ice Facility at the University of Maine Climate Change Institute, has already been used to shed light on our flawed understanding of natural levels of Pb in Earth's atmosphere.

Tropical Glaciers in the Common Era: Papua, Indonesia, Quelccaya Ice Cap, Peru and Kilimanjaro, Tanzania

NASA Astrophysics Data System (ADS)

Thompson, L. G.; Mosley-Thompson, E. S.; Davis, M. E.

2011-12-01

High-resolution ice core stratigraphic records of δ18O (temperature proxy) demonstrate that the current warming at high elevations in mid- to lower latitudes is unprecedented for at least the last two millennia, although at many sites the Early Holocene was much warmer than at present. Here we discuss the interaction of El Niño-Southern Oscillation (ENSO) variability and warming trends as recorded in ice core records from high-altitude tropical glaciers and the implications of the warming trends for the future of these glaciers. ENSO has strong impacts on meteorological phenomena that either directly or indirectly affect most regions on the planet and their populations, particularly throughout the Tropics. Here we examine similarities and differences among ice core records from Papua (Indonesia), Quelccaya Ice Cap (Peru) and Kilimanjaro (Tanzania). Quelccaya, Earth's largest tropical ice cap, has provided continuous, annually-resolved proxy records of climatic and environmental variability preserved in many measurable parameters, especially oxygen and hydrogen isotopic ratios (δ18O, δD) and the net mass balance (accumulation) spanning the last 1800 years. The remarkable similarity between changes in the highland and coastal cultures of Peru and climate variability in the Andes, especially with regard to precipitation, implies a strong connection between prehistoric human activities and climate in this region. The well-documented ice loss on Quelccaya, Kilimanjaro in eastern Africa and the ice fields near Puncak Jaya in Papua, Indonesia presents a possible analog for glacier response in the tropics during the Holocene. The ongoing melting of these ice fields is consistent with model predictions of a vertical amplification of temperature in the Tropics. A sequence of over 50 recently exposed, rooted, soft-bodied plant deposits collected between 2002 and 2011 from the retreating margins of the Quelccaya ice cap provide a longer term perspective for the recent glacier retreat. The ongoing glacier retreat in the Tropics and associated loss of natural resources has dire implications for people living in these areas. These recent changes are examined in the context of the Common Era from a glacier derived paleoclimate perspective as recorded in the glaciers on the world's highest mountains.

Reconstruction of the Final Phases of Activity and Retreat of the North Sea Lobe Ice Stream during the Late Devensian

NASA Astrophysics Data System (ADS)

Grimoldi, E.; Roberts, D. H.; Evans, D. J. A.; Stewart, H. A.; Sejrup, H. P.; Hjelstuen, B. O. B.; Haflidason, H.; Clark, C.

2016-12-01

The deglacial history of the former eastern margin of the last British and Irish Ice Sheet (BIIS) is still poorly understood, particularly in the western North Sea basin. The North Sea Lobe (NSL) affected the area, although gaps remain in our knowledge of the geomorphological and sedimentary imprint that the ice stream left on the seafloor and, more importantly, of its way of final retreat. In this work we analyse new high-resolution multibeam bathymetry, 2D seismic profiles and five vibro-cores, collected in the western North Sea in collaboration with the Britice-Chrono project, and provide new insights on the seafloor geomorphology and acoustic and lithological facies that characterize the Quaternary sediments of the area. The presence of bedrock-cored lineations orientated WNW-ESE to NW-SE indicates that the NSL was fed by the Forth ice stream which moved offshore from southern Scotland. Moraine ridges and two grounding zone wedges, perpendicular to the lineations, suggest that the NSL underwent different phases of stillstand/readvance and retreated towards the north-west. Five acoustic facies (AF) were identified, four of which are found on top of pre-Quaternary strata (AF 1), though their lateral extension is discontinuous. They are interpreted to represent glacigenic diamicts (AF 2 and 3), that are overlain by glacimarine (AF 4) and by Holocene deposits (AF 5). The vibro-cores penetrate in depth until reaching the top of AF 3. This facies correlates to the diamictic sediments observed in the cores, which are characterized by soft silts and clays and abundant clasts. The glacimarine sediments generally appear as highly laminated silts and clays with dropstones that usually become less frequent going upwards in the cores. These sediments are also characterized by foraminifera species associated with glacial environments. Foraminifera tests were dated within the galcimarine sequences in two cores and will help constrain the timing of ice retreat. By compiling all the available datasets, we suggest that the NSL flew sub-parallel to the coasts of eastern England during the Late Devensian and underwent different phases of stillstands/readvances that indicate a slow retreat towards land.

Glacial-marine sediments record ice-shelf retreat during the late Holocene in Beascochea Bay on the western margin of the Antarctic Peninsula

NASA Astrophysics Data System (ADS)

Hardin, L. A.; Wellner, J. S.

2010-12-01

Beascochea Bay has an overall rapid rate of sedimentation due to retreating fast-flowing ice, and thus contains high-resolution records of Antarctica’s glacial and climate history. Beascochea Bay is a 16 km long by 8 km wide bay located on the western margin of the Antarctica Peninsula, centered between Anvers Island and Renaud Island, but open to the Bellingshausen Sea. Currently, three tidewater glaciers draining the Bruce Plateau of Graham Land enter into the fjords of Beascochea Bay, releasing terrigenous sediments which have left a record of the fluctuations of the Antarctic Peninsula Ice Cap since the grounded ice decoupled from the seafloor after the last glacial maximum. These three glaciers have played a significant role in providing sediment to the main basin, allowing a detailed sediment facies analysis to be conducted from eight sediment cores which were collected during the austral summer of 2007. Pebbly silty clay sediment cores, along with 3.5 kHz seismic data and multibeam swath bathymetry data, are integrated to reconstruct a glacial retreat timeline for the middle to late Holocene, which can be compared to the recent retreat rates over the last century. Paleoenvironment of deposition is determined by mapping lateral facies changes from the side fjords (proximal) to the outer basin (distal), as each region records the transition from glacial-marine sediments to open-marine sediments. As the ice retreated from the outer basin to the inner basin, and most recently leaving the side fjords, each facies deposited can be age-constrained by radiocarbon, 210Pb, and 137Cs dating methods. A distinct 137Cs signal is readily seen in two kasten cores from a side fjord and the inner basin of Beascochea Bay. This dating method revealed an average sedimentation rate of 2.7 mm per year for approximately the last century, which is comparable to 210Pb rates obtained in other studies. Lithology variations in each sediment core record indications of ice-shelf influence in Beascochea Bay throughout the Holocene deglaciation. The distinctively laminated sub-ice shelf facies can be clearly seen in the x-rays of these cores, and can be easily distinguished from the poorly sorted glacial-marine facies and the greenish finer-grained facies deposited in open-marine conditions. A 14 m long sediment core taken from the outer basin of Beascochea Bay recovered the greatest length of sediment and dates back to the middle Holocene. X-rays of this core show a possible mid-Holocene retreat of the ice shelf followed by intermittent advance and retreat that precedes the most recent retreat. The inner basin of Beascochea Bay has been without an ice shelf for the last 200 years, based on the sedimentation rates of the last century projected downcore.

Characteristics of Dust Deposition at High Elevation Sites in Caucasus Over the Past 190 years Recorded in Ice Cores.

NASA Astrophysics Data System (ADS)

Kutuzov, Stanislav; Ginot, Patrick; Mikhaenko, Vladimir; Krupskaya, Victoria; Legrand, Michel; Preunkert, Suzanne; Polukhov, Alexey; Khairedinova, Alexandra

2017-04-01

The nature and extent of both radiative and geochemical impacts of mineral dust on snow pack and glaciers depend on physical and chemical properties of dust particles and its deposition rates. Ice cores can provide information about amount of dust particles in the atmosphere and its characteristic and also give insights on strengths of the dust sources and its changes in the past. A series of shallow ice cores have been obtained in Caucasus mountains, Russia in 2004 - 2015. A 182 meter ice core has been recovered at the Western Plateau of Mt. Elbrus (5115 m a.s.l.) in 2009. The ice cores have been dated using stable isotopes, NH4+ and succinic acid data with the seasonal resolution. Samples were analysed for chemistry, concentrations of dust and black carbon, and particle size distributions. Dust mineralogy was assessed by XRD. Individual dust particles were analysed using SEM. Dust particle number concentration was measured using the Markus Klotz GmbH (Abakus) implemented into the CFA system. Abakus data were calibrated with Coulter Counter multisizer 4. Back trajectory cluster analysis was used to assess main dust source areas. It was shown that Caucasus region experiencing influx of mineral dust from the Sahara and deserts of the Middle East. Mineralogy of dust particles of desert origin was significantly different from the local debris material and contained large proportion of calcite and clay minerals (kaolinite, illite, palygorskite) associated with material of desert origin. Annual dust flux in the Caucasus Mountains was estimated as 300 µg/cm2 a-1. Particle size distribution depends on individual characteristics of dust deposition event and also on the elevation of the drilling site. The contribution of desert dust deposition was estimated as 35-40 % of the total dust flux. Average annual Ca2+ concentration over the period from 1824 to 2013 was of 150 ppb while some of the strong dust deposition events led to the Ca2+ concentrations reaching 4400 ppb. An increase of dust and Ca2+ concentration was registered since the beginning of XX century. The ice core record depicts also a prominent increase of dust concentration in 1980's which may be related to the increase of dust sources strength in North Africa.

A stratigraphic framework for naming and robust correlation of abrupt climatic changes during the last glacial period based on three synchronized Greenland ice core records

NASA Astrophysics Data System (ADS)

Rasmussen, Sune O.

2014-05-01

Due to their outstanding resolution and well-constrained chronologies, Greenland ice core records have long been used as a master record of past climatic changes during the last interglacial-glacial cycle in the North Atlantic region. As part of the INTIMATE (INtegration of Ice-core, MArine and TErrestrial records) project, protocols have been proposed to ensure consistent and robust correlation between different records of past climate. A key element of these protocols has been the formal definition of numbered Greenland Stadials (GS) and Greenland Interstadials (GI) within the past glacial period as the Greenland expressions of the characteristic Dansgaard-Oeschger events that represent cold and warm phases of the North Atlantic region, respectively. Using a recent synchronization of the NGRIP, GRIP, and GISP2 ice cores that allows the parallel analysis of all three records on a common time scale, we here present an extension of the GS/GI stratigraphic template to the entire glacial period. This is based on a combination of isotope ratios (δ18O, reflecting mainly local temperature) and calcium concentrations (reflecting mainly atmospheric dust loading). In addition to the well-known sequence of Dansgaard-Oeschger events that were first defined and numbered in the ice core records more than two decades ago, a number of short-lived climatic oscillations have been identified in the three synchronized records. Some of these events have been observed in other studies, but we here propose a consistent scheme for discriminating and naming all the significant climatic events of the last glacial period that are represented in the Greenland ice cores. This is a key step aimed at promoting unambiguous comparison and correlation between different proxy records, as well as a more secure basis for investigating the dynamics and fundamental causes of these climatic perturbations. The work presented is under review for publication in Quaternary Science Reviews. Author team: S.O. Rasmussen, M. Bigler, S.P.E. Blockley, T. Blunier, S.L. Buchardt, H.B. Clausen;, I. Cvijanovic, D. Dahl-Jensen, S.J. Johnsen;, H. Fischer, V. Gkinis, M. Guillevic, W.Z. Hoek, J.J. Lowe, J. Pedro, T. Popp, I.K. Seierstad, J.P. Steffensen, A.M. Svensson, P. Vallelonga, B.M. Vinther, M.J.C. Walker, J.J. Wheatley, and M. Winstrup (ased).

Post-glacial variations of sea ice cover and river discharge in the western Laptev Sea (Arctic Ocean) - a high-resolution study over the last 18 ka

NASA Astrophysics Data System (ADS)

Hörner, Tanja; Stein, Ruediger; Fahl, Kirsten

2015-04-01

Here, we provide a high-resolution reconstruction of sea-ice cover variations in the western Laptev Sea, a crucial area in terms of sea-ice production in the Arctic Ocean and a region characterized by huge river discharge. Furthermore, the shallow Laptev Sea was strongly influenced by the post-glacial sea-level rise that should also be reflected in the sedimentary records. The sea Ice Proxy IP25 (Highly-branched mono-isoprenoid produced by sea-ice algae; Belt et al., 2007) was measured in two sediment cores from the western Laptev Sea (PS51/154, PS51/159) that offer a high-resolution composite record over the last 18 ka. In addition, sterols are applied as indicator for marine productivity (brassicasterol, dinosterol) and input of terrigenous organic matter by river discharge into the ocean (campesterol, ß-sitosterol). The sea-ice cover varies distinctly during the whole time period and shows a general increase in the Late Holocene. A maximum in IP25 concentration can be found during the Younger Dryas. This sharp increase can be observed in the whole circumarctic realm (Chukchi Sea, Bering Sea, Fram Strait and Laptev Sea). Interestingly, there is no correlation between elevated numbers of ice-rafted debris (IRD) interpreted as local ice-cap expansions (Taldenkova et al. 2010), and sea ice cover distribution. The transgression and flooding of the shelf sea that occurred over the last 16 ka in this region, is reflected by decreasing terrigenous (riverine) input, reflected in the strong decrease in sterol (ß-sitosterol and campesterol) concentrations. References Belt, S.T., Massé, G., Rowland, S.J., Poulin, M., Michel, C., LeBlanc, B., 2007. A novel chemical fossil of palaeo sea ice: IP25. Organic Geochemistry 38 (1), 16e27. Taldenkova, E., Bauch, H.A., Gottschalk, J., Nikolaev, S., Rostovtseva, Yu., Pogodina, I., Ya, Ovsepyan, Kandiano, E., 2010. History of ice-rafting and water mass evolution at the northern Siberian continental margin (Laptev Sea) during Late Glacial and Holocene times. Quaternary Science Reviews 29 (27-28), 3919-3935.

High-resolution record of last post-glacial variations of sea-ice cover and river discharge in the western Laptev Sea (Arctic Ocean)

NASA Astrophysics Data System (ADS)

Stein, R. H.; Hörner, T.; Fahl, K.

2014-12-01

Here, we provide a high-resolution reconstruction of sea-ice cover variations in the western Laptev Sea, a crucial area in terms of sea-ice production in the Arctic Ocean and a region characterized by huge river discharge. Furthermore, the shallow Laptev Sea was strongly influenced by the post-glacial sea-level rise that should also be reflected in the sedimentary records. The sea Ice Proxy IP25 (Highly-branched mono-isoprenoid produced by sea-ice algae; Belt et al., 2007) was measured in two sediment cores from the western Laptev Sea (PS51/154, PS51/159) that offer a high-resolution composite record over the last 18 ka. In addition, sterols are applied as indicator for marine productivity (brassicasterol, dinosterol) and input of terrigenous organic matter by river discharge into the ocean (campesterol, ß-sitosterol). The sea-ice cover varies distinctly during the whole time period and shows a general increase in the Late Holocene. A maximum in IP25 concentration can be found during the Younger Dryas. This sharp increase can be observed in the whole circumarctic realm (Chukchi Sea, Bering Sea, Fram Strait and Laptev Sea). Interestingly, there is no correlation between elevated numbers of ice-rafted debris (IRD) interpreted as local ice-cap expansions (Taldenkova et al. 2010), and sea ice cover distribution. The transgression and flooding of the shelf sea that occurred over the last 16 ka in this region, is reflected by decreasing terrigenous (riverine) input, reflected in the strong decrease in sterol (ß-sitosterol and campesterol) concentrations. ReferencesBelt, S.T., Massé, G., Rowland, S.J., Poulin, M., Michel, C., LeBlanc, B., 2007. A novel chemical fossil of palaeo sea ice: IP25. Organic Geochemistry 38 (1), 16e27. Taldenkova, E., Bauch, H.A., Gottschalk, J., Nikolaev, S., Rostovtseva, Yu., Pogodina, I., Ya, Ovsepyan, Kandiano, E., 2010. History of ice-rafting and water mass evolution at the northern Siberian continental margin (Laptev Sea) during Late Glacial and Holocene times. Quaternary Science Reviews 29 (27-28), 3919-3935.

Historic records of organic compounds from a high Alpine glacier: influences of biomass burning, anthropogenic emissions, and dust transport

NASA Astrophysics Data System (ADS)

Müller-Tautges, C.; Eichler, A.; Schwikowski, M.; Pezzatti, G. B.; Conedera, M.; Hoffmann, T.

2016-01-01

Historic records of α-dicarbonyls (glyoxal, methylglyoxal), carboxylic acids (C6-C12 dicarboxylic acids, pinic acid, p-hydroxybenzoic acid, phthalic acid, 4-methylphthalic acid), and ions (oxalate, formate, calcium) were determined with annual resolution in an ice core from Grenzgletscher in the southern Swiss Alps, covering the time period from 1942 to 1993. Chemical analysis of the organic compounds was conducted using ultra-high-performance liquid chromatography (UHPLC) coupled to electrospray ionization high-resolution mass spectrometry (ESI-HRMS) for dicarbonyls and long-chain carboxylic acids and ion chromatography for short-chain carboxylates. Long-term records of the carboxylic acids and dicarbonyls, as well as their source apportionment, are reported for western Europe. This is the first study comprising long-term trends of dicarbonyls and long-chain dicarboxylic acids (C6-C12) in Alpine precipitation. Source assignment of the organic species present in the ice core was performed using principal component analysis. Our results suggest biomass burning, anthropogenic emissions, and transport of mineral dust to be the main parameters influencing the concentration of organic compounds. Ice core records of several highly correlated compounds (e.g., p-hydroxybenzoic acid, pinic acid, pimelic, and suberic acids) can be related to the forest fire history in southern Switzerland. P-hydroxybenzoic acid was found to be the best organic fire tracer in the study area, revealing the highest correlation with the burned area from fires. Historical records of methylglyoxal, phthalic acid, and dicarboxylic acids adipic acid, sebacic acid, and dodecanedioic acid are comparable with that of anthropogenic emissions of volatile organic compounds (VOCs). The small organic acids, oxalic acid and formic acid, are both highly correlated with calcium, suggesting their records to be affected by changing mineral dust transport to the drilling site.

The variability of the isotopic signal during the last Glacial as seen from the ultra-high resolution NEEM and NorthGRIP ice cores.

NASA Astrophysics Data System (ADS)

Gkinis, Vasileios; Møllesøe Vinther, Bo; Terkelsen Holme, Christian; Capron, Emilie; Popp, Trevor James; Olander Rasmussen, Sune

2017-04-01

The continuity and high resolution available in polar ice core records constitutes them an excellent tool for the study of the stadial-interstadial transitions, notably through the study of the water isotopic composition of polar precipitation (δ18O, δD ). The quest for the highest resolution possible has resulted in experimental sampling and analysis techniques that have yielded data sets with a potential to change the current picture on the climatic signals of the last Glacial. Specifically, the ultra-high resolution δ18O signals from the NorthGRIP and NEEM ice cores, present a variability at multi-annual and decadal time scales, whose interpretation gives rise to further puzzling though interesting questions and an obvious paradox. By means of simple firn isotope diffusion and densification calculations, we firstly demonstrate that the variability of observed signals is unlikely to be due to post depositional effects that are known to occur on the surface of the Greenland ice cap and alter the δ18O composition of the precipitated snow. Assuming specific values for the δ18O sensitivity to temperature (commonly referred to as the δ18O slope), we estimate that the temperature signal during the stadials has a variability that extents from interstadial to extremely cold levels with peak-to-peak fluctuations of almost 35 K occurring in a few years. Similarly, during interstadial phases the temperature varies rapidly from stadial to Holocene levels while the signal variability shows a maximum during the LGM, with magnitudes of up to 15‰ that translate to ≈ 50 K when a δ18O slope of 0.3‰K-1 is used. We assess the validity of these results and comment on the stability of the δ18O slope. Driven by a simple logical queue, we conclude that the observed δ18O variability reflects a climatic signal although not necessarily attributed 100% to temperature changes. From this we can assume that there occur climatic mechanisms during the previously thought stable stadial phases that allow for swift changes, with magnitudes comparable if not greater to that of the stadial-interstadial transitions. We are thus tempted to propose that rapid climate change is the normal mode of climate during the last Glacial and that some of the mechanisms associated with the stadial-interstadial transitions are possibly in play also during other, phenomenally more stable times of the Glacial climate record.

IceChrono1: a probabilistic model to compute a common and optimal chronology for several ice cores

NASA Astrophysics Data System (ADS)

Parrenin, F.; Bazin, L.; Capron, E.; Landais, A.; Lemieux-Dudon, B.; Masson-Delmotte, V.

2015-05-01

Polar ice cores provide exceptional archives of past environmental conditions. The dating of ice cores and the estimation of the age-scale uncertainty are essential to interpret the climate and environmental records that they contain. It is, however, a complex problem which involves different methods. Here, we present IceChrono1, a new probabilistic model integrating various sources of chronological information to produce a common and optimized chronology for several ice cores, as well as its uncertainty. IceChrono1 is based on the inversion of three quantities: the surface accumulation rate, the lock-in depth (LID) of air bubbles and the thinning function. The chronological information integrated into the model are models of the sedimentation process (accumulation of snow, densification of snow into ice and air trapping, ice flow), ice- and air-dated horizons, ice and air depth intervals with known durations, depth observations (depth shift between synchronous events recorded in the ice and in the air) and finally air and ice stratigraphic links in between ice cores. The optimization is formulated as a least squares problem, implying that all densities of probabilities are assumed to be Gaussian. It is numerically solved using the Levenberg-Marquardt algorithm and a numerical evaluation of the model's Jacobian. IceChrono follows an approach similar to that of the Datice model which was recently used to produce the AICC2012 (Antarctic ice core chronology) for four Antarctic ice cores and one Greenland ice core. IceChrono1 provides improvements and simplifications with respect to Datice from the mathematical, numerical and programming point of views. The capabilities of IceChrono1 are demonstrated on a case study similar to the AICC2012 dating experiment. We find results similar to those of Datice, within a few centuries, which is a confirmation of both IceChrono1 and Datice codes. We also test new functionalities with respect to the original version of Datice: observations as ice intervals with known durations, correlated observations, observations as air intervals with known durations and observations as mixed ice-air stratigraphic links. IceChrono1 is freely available under the General Public License v3 open source license.

Unravelling source regions of ice rafted debris within three NE Atlantic marine sediment cores during the deglacial interval: a multi-proxy approach

NASA Astrophysics Data System (ADS)

Small, David; Hibbert, Fiona; Austin, Bill

2010-05-01

Ice-rafted debris (IRD) within marine sediments of the North Atlantic provide an important archive of glacial activity on adjacent landmasses and attest to the activity of multiple calving ice margins during the last glacial cycle. IRD records therefore provide a means to reconstruct ice sheet dynamics and their interaction with the climate system, providing evidence of both the source of the ice and the location of melting (e.g. Ruddiman, 1977; Bond and Lotti, 1995). The complex interaction of the circum-Atlantic ice sheets and limitations of individual techniques often hinders firm source designations (i.e. IRD may be derived from multiple sources which cannot be differentiated by, for example, visual characterisation). Initial work identified diagnostic grain types that could be attributed to source areas of palaeo ice-sheets (eg: Bond & Lotti 1995) however, for the BIS, "diagnostic" basalt may be derived from sources to the east and west of the cores (Hibbert et al 2009, Scourse et al 2009). We therefore, utilise a multi-proxy approach to investigate the deglacial dynamics of the last British Ice Sheet (BIS) using inter alia lithic characterisation, fluxes of IRD to the core sites, magnetic susceptibility and a magnetic un-mixing model. A novel application of major element geochemistry of garnets contained within ice-rafted debris of the three high resolution marine sediment cores is presented. Garnets can be used to infer provenance (e.g. Oliver 2001) as major element composition may be assigned to specific metamorphic terranes. The IRD present within these cores is believed to be predominantly sourced from the BIS (cf: Knutz et al 2001, Hibbert et al 2009). This assertion is tested through multiple analytical techniques used and replication of records across the Hebridean shelf into the deep ocean. References • Bond, G.C. & Lotti, R., 1995. Iceberg discharges into the North Atlantic on millennial timescales during the last glaciation. Science 267. pp. 1005-1010. • Hibbert, F.D., Austin, W.E.N., Leng, M.J. and Gatliff, R.W., 2009. British Ice Sheet Dynamics inferred from North Atlantice ice-rafted debris records spanning the last 175,000 years. Journal of Quaternary Science. ISSN 0267-8179. • Knutz, P.C., Austin, W.E.N. and Jones, E.J.W., 2001. Millenial-scale depositional cycles related to British Ice Sheet variability and North Atlantic paleocirculation since 45kyr B.P., Barra Fan, U.K. margin. Paleoceanography 16. pp.53-64. • Oliver, G.J.H., 2001. Reconstruction of the Grampian episode in Scotland: it's place in the Caledonian Orogeny. Tectonphysics 332. pp.23-49. • Ruddiman, W.F., 1977. Late Quaternary deposition of ice-rafted sand in the sub-polar North Atlantic (lat 40° to 65°). Geological Society of America Bulletin 88. pp.1813-1821. • Scourse, J.D., Haapaniemi, A.I., Colmenero-Hidalgo, E., Peck, V.L., Hall, I.R., Austin, W.E.N., Knutz, P.C. and Zahn, R., 2009. Growth, dynamics and deglaciation of the last British-Irish Ice Sheet: the deep-sea ice-rafted detritus record. Quaternary Science Reviews 28. pp.3066-3084.

Deep Radiostratigraphy of the East Antarctic Plateau: Connecting the Dome C and Vostok Ice Core Sites

NASA Technical Reports Server (NTRS)

Cavitte, Marie G. P.; Blankenship, Donald D.; Young, Duncan A.; Schroeder, Dustin M.; Parrenin, Frederic; Lemeur, Emmanuel; Macgregor, Joseph A.; Siegert, Martin J.

2016-01-01

Several airborne radar-sounding surveys are used to trace internal reflections around the European Project for Ice Coring in Antarctica Dome C and Vostok ice core sites. Thirteen reflections, spanning the last two glacial cycles, are traced within 200 km of Dome C, a promising region for million-year-old ice, using the University of Texas Institute for Geophysics High-Capacity Radar Sounder. This provides a dated stratigraphy to 2318 m depth at Dome C. Reflection age uncertainties are calculated from the radar range precision and signal-to-noise ratio of the internal reflections. The radar stratigraphy matches well with the Multichannel Coherent Radar Depth Sounder (MCoRDS) radar stratigraphy obtained independently. We show that radar sounding enables the extension of ice core ages through the ice sheet with an additional radar-related age uncertainty of approximately 1/3-1/2 that of the ice cores. Reflections are extended along the Byrd-Totten Glacier divide, using University of Texas/Technical University of Denmark and MCoRDS surveys. However, core-to-core connection is impeded by pervasive aeolian terranes, and Lake Vostok's influence on reflection geometry. Poor radar connection of the two ice cores is attributed to these effects and suboptimal survey design in affected areas. We demonstrate that, while ice sheet internal radar reflections are generally isochronal and can be mapped over large distances, careful survey planning is necessary to extend ice core chronologies to distant regions of the East Antarctic ice sheet.

Spontaneous abrupt climate change due to an atmospheric blocking-sea-ice-ocean feedback in an unforced climate model simulation.

PubMed

Drijfhout, Sybren; Gleeson, Emily; Dijkstra, Henk A; Livina, Valerie

2013-12-03

Abrupt climate change is abundant in geological records, but climate models rarely have been able to simulate such events in response to realistic forcing. Here we report on a spontaneous abrupt cooling event, lasting for more than a century, with a temperature anomaly similar to that of the Little Ice Age. The event was simulated in the preindustrial control run of a high-resolution climate model, without imposing external perturbations. Initial cooling started with a period of enhanced atmospheric blocking over the eastern subpolar gyre. In response, a southward progression of the sea-ice margin occurred, and the sea-level pressure anomaly was locked to the sea-ice margin through thermal forcing. The cold-core high steered more cold air to the area, reinforcing the sea-ice concentration anomaly east of Greenland. The sea-ice surplus was carried southward by ocean currents around the tip of Greenland. South of 70 °N, sea ice already started melting and the associated freshwater anomaly was carried to the Labrador Sea, shutting off deep convection. There, surface waters were exposed longer to atmospheric cooling and sea surface temperature dropped, causing an even larger thermally forced high above the Labrador Sea. In consequence, east of Greenland, anomalous winds changed from north to south, terminating the event with similar abruptness to its onset. Our results imply that only climate models that possess sufficient resolution to correctly represent atmospheric blocking, in combination with a sensitive sea-ice model, are able to simulate this kind of abrupt climate change.

Permafrost as palaeo-environmental archive - potentials and limitations

NASA Astrophysics Data System (ADS)

Schirrmeister, L.; Wetterich, S.; Meyer, H.; Grosse, G.; Schwamborn, G.; Siegert, C.

2009-04-01

Since 1994, the Periglacial Research Group of the Alfred Wegener Institute is studying permafrost sequences of the Beringian landmass. The study sites in Siberia cover lake banks on Taymyr Peninsula, coastal sites at the Laptev and the East Siberian Seas, locations in the Lena Delta, at the lower Kolyma river, the middle Lena and the lower Aldan rivers, and the catchment area of the El'gygytgyn crater lake in Chukotka. In Alaska, permafrost tunnels near Fairbanks and Barrow, and coastal sites on the Seward Peninsula coast were studied. In addition, Canadian sites on Herschel Island in the Beaufort Sea and at the adjacent coast of the Yukon plain were studied. Subsurface exposures like tunnels and cellars provided the opportunity for three-dimensional studies of sedimentary and ground ice features, relatively ‘clean' field conditions for in-situ experiments, monitoring procedures, and detailed and repeatable sampling. Permafrost cores were drilled in order to study inaccessible sequences below the terrain surface and shelf sea floor. Cores were transported and stored frozen for further high-resolution analysis. Reference core sections were preserved for subsequent later studies. Terrestrial sediment cores are highly localized records, sometimes problematic in extrapolating horizons in inhomogeneous sediments like ground ice-deformed permafrost deposits, and drill campaigns are usually cost intensive and logistical challenging. Coastal permafrost cliffs often naturally expose large cross sections trough modern and ancient landscapes. Contrary to cores, they provide an opportunity to study the wider context of depositional environments and ground ice features. Due to the relative easy access to coasts and the recurring natural exposure of cliffs by thermo-abrasive wave action they are very convenient study objects for regional comparisons and correlation of past environmental conditions. Finally, palaeogeographical reconstructions are also guided by remote sensing-based analyses of geomorphological surface patterns, like Yedoma hills, thermokarst depressions, pingos or thermoerosional valleys. We generally relied on a multidisciplinary approach to study permafrost sequences in order to use the rich palaeo-environmental information stored in these frozen records. Cryofacies analysis describes both sediment and ice structures that allow interpretation of freezing conditions, thaw events, temperature regimes, and the local accumulation conditions. Ground ice bodies were sampled by ice screw and chain saw for analysis of hydrochemical and stable isotope composition. Several ground ice types were classified. The interaction between ice, sediment, and cryosoil were determined. The isotope signatures of sub-vertically layered ice wedges contain information about temperature variations, evaporation conditions and precipitation sources during different periods of ice wedge formation. The stratigraphy of the permafrost sequences was determined by lithostratigraphical classifications and geochronological results. Numerous sediment parameters were measured for differentiation between horizons in individual exposures, for local and regional stratigraphic correlation of permafrost sequences as well as for reconstruction of accumulation and transport conditions. Age determinations were carried out by radiocarbon analyses on organic remains, isochron uranium-thorium disequilibria technique on peats, optical stimulated luminescence on clastic sediments, and 36Cl/Cl stable isotope ratios measurements in ground ice. For palaeo-ecological reconstructions various fossil bioindicators were studied including pollen, plant macro-remains, insects, ostracods, testate amoebae, diatoms, chironomids, and mammal bones of the so-called mammoth fauna. By combining these data sets, we assembled a complex picture of the climate, landscape and vegetation dynamics of the studied regions during the Quaternary past. Derived palaeo-information includes mean annual air temperatures, mean winter temperatures, mean Juli temperatures, precipitation, humidity, soil climate and chemistry, hydrology and hydrochemistry of waters). The general potential of permafrost archives includes spatial (circumarctic, high arctic to boreal zones) and temporal (Mid Pleistocene to modern) environmental gradients. Lateral cross sections contain information about permafrost degradation during interglacial periods, the aggradation of ice-rich sequences during stadial and interstadial periods, and extreme changes in periglacial hydrology during the late Quaternary. The spatial reconstruction of ancient landscapes is possible by detailed study of kilometer-long coastal exposures. Temporally relative high resolution (about 50 years) isotope data from ice wedges reflect the Late Pleistocene to Holocene climate transition. Using transfer functions for pollen, plant macro remains or chironomids, the numerical estimation of palaeo-climate data (temperature and precipitation) is possible. The limitations of permafrost archives are the frequent lack of continuous sequences due to thermokarst or thermo-erosion events. Local stratigraphies are sometimes difficult to correlate on a regional scale because of permafrost degradation and neotectonic influence on the accumulative/erosive environment in some regions. Until now there are still uncertainties for comparing different geochronological methods, some of them related to unknown influences of permafrost processes on chemical and physical parameters important to the age determination technique. Due to strong cryoturbation patterns and sometimes challenging sampling situations on near-vertical frozen exposures the geochronological resolution in permafrost sequences is usually lower than in lacustrine sequences or glacial ice cores. Eventually, as for any other archive, we need to consider the effect of local versus regional signals derived from the palaeo-ecological interpretation of fossil records.

Toward an integrated ice core chronology using relative and orbital tie-points

NASA Astrophysics Data System (ADS)

Bazin, L.; Landais, A.; Lemieux-Dudon, B.; Toyé Mahamadou Kele, H.; Blunier, T.; Capron, E.; Chappellaz, J.; Fischer, H.; Leuenberger, M.; Lipenkov, V.; Loutre, M.-F.; Martinerie, P.; Parrenin, F.; Prié, F.; Raynaud, D.; Veres, D.; Wolff, E.

2012-04-01

Precise ice cores chronologies are essential to better understand the mechanisms linking climate change to orbital and greenhouse gases concentration forcing. A tool for ice core dating (DATICE [developed by Lemieux-Dudon et al., 2010] permits to generate a common time-scale integrating relative and absolute dating constraints on different ice cores, using an inverse method. Nevertheless, this method has only been applied for a 4-ice cores scenario and for the 0-50 kyr time period. Here, we present the bases for an extension of this work back to 800 ka using (1) a compilation of published and new relative and orbital tie-points obtained from measurements of air trapped in ice cores and (2) an adaptation of the DATICE inputs to 5 ice cores for the last 800 ka. We first present new measurements of δ18Oatm and δO2/N2 on the Talos Dome and EPICA Dome C (EDC) ice cores with a particular focus on Marine Isotopic Stages (MIS) 5, and 11. Then, we show two tie-points compilations. The first one is based on new and published CH4 and δ18Oatm measurements on 5 ice cores (NorthGRIP, EPICA Dronning Maud Land, EDC, Talos Dome and Vostok) in order to produce a table of relative gas tie-points over the last 400 ka. The second one is based on new and published records of δO2/N2, δ18Oatm and air content to provide a table of orbital tie-points over the last 800 ka. Finally, we integrate the different dating constraints presented above in the DATICE tool adapted to 5 ice cores to cover the last 800 ka and show how these constraints compare with the established gas chronologies of each ice core.

Historical Isotopic Temperature Record from the Vostok Ice Core (420,000 years BP-present)

DOE Data Explorer

Petit, J. R. [Laboratoire de Glaciogie et Geophysique de l'Environnement; Raynaud, D. [Laboratoire de Glaciogie et Geophysique de l'Environnement; Lorius, C. [Laboratoire de Glaciogie et Geophysique de l'Environnement; Jouzel, J. [Laboratoire des Sciences du Climat et de l'Environnement; Delaygue, G. [Laboratoire des Sciences du Climat et de l'Environnement; Barkov, N. I. [Arctic and Antarctic Research Inst. (AARI), St. Petersburg (Russian Federation); Kotlyakov, V. M. [Institute of Geography, Russia

2000-01-01

Because isotopic fractions of the heavier oxygen-18 (18O) and deuterium (D) in snowfall are temperature-dependent and a strong spatial correlation exists between the annual mean temperature and the mean isotopic ratio (18O or δD) of precipitation, it is possible to derive ice-core climate records. The record presented by Jouzel et al. (1987) was the first ice core record to span a full glacial-interglacial cycle. That record was based on an ice core drilled at the Russian Vostok station in central east Antarctica. The 2083-m ice core was obtained during a series of drillings in the early 1970s and 1980s and was the result of collaboration between French and former-Soviet scientists. Drilling continued at Vostok and was completed in January 1998, reaching a depth of 3623 m, the deepest ice core ever recovered (Petit et al. 1997, 1999). The resulting core allows the ice core record of climate properties at Vostok to be extended to ~420 kyr BP.

A review of sea ice proxy information from polar ice cores

NASA Astrophysics Data System (ADS)

Abram, Nerilie J.; Wolff, Eric W.; Curran, Mark A. J.

2013-11-01

Sea ice plays an important role in Earth's climate system. The lack of direct indications of past sea ice coverage, however, means that there is limited knowledge of the sensitivity and rate at which sea ice dynamics are involved in amplifying climate changes. As such, there is a need to develop new proxy records for reconstructing past sea ice conditions. Here we review the advances that have been made in using chemical tracers preserved in ice cores to determine past changes in sea ice cover around Antarctica. Ice core records of sea salt concentration show promise for revealing patterns of sea ice extent particularly over glacial-interglacial time scales. In the coldest climates, however, the sea salt signal appears to lose sensitivity and further work is required to determine how this proxy can be developed into a quantitative sea ice indicator. Methane sulphonic acid (MSA) in near-coastal ice cores has been used to reconstruct quantified changes and interannual variability in sea ice extent over shorter time scales spanning the last ˜160 years, and has potential to be extended to produce records of Antarctic sea ice changes throughout the Holocene. However the MSA ice core proxy also requires careful site assessment and interpretation alongside other palaeoclimate indicators to ensure reconstructions are not biased by non-sea ice factors, and we summarise some recommended strategies for the further development of sea ice histories from ice core MSA. For both proxies the limited information about the production and transfer of chemical markers from the sea ice zone to the Antarctic ice sheets remains an issue that requires further multidisciplinary study. Despite some exploratory and statistical work, the application of either proxy as an indicator of sea ice change in the Arctic also remains largely unknown. As information about these new ice core proxies builds, so too does the potential to develop a more comprehensive understanding of past changes in sea ice and its role in both long and short-term climate changes.

Ice Core Perspective on Mercury Pollution during the Past 600 Years.

PubMed

Beal, Samuel A; Osterberg, Erich C; Zdanowicz, Christian M; Fisher, David A

2015-07-07

Past emissions of the toxic metal mercury (Hg) persist in the global environment, yet these emissions remain poorly constrained by existing data. Ice cores are high-resolution archives of atmospheric deposition that may provide crucial insight into past atmospheric Hg levels during recent and historical time. Here we present a record of total Hg (HgT) in an ice core from the pristine summit plateau (5340 m asl) of Mount Logan, Yukon, Canada, representing atmospheric deposition from AD 1410 to 1998. The Colonial Period (∼1603-1850) and North American "Gold Rush" (1850-1900) represent minor fractions (8% and 14%, respectively) of total anthropogenic Hg deposition in the record, with the majority (78%) occurring during the 20th Century. A period of maximum HgT fluxes from 1940 to 1975 coincides with estimates of enhanced anthropogenic Hg emissions from commercial sources, as well as with industrial emissions of other toxic metals. Rapid declines in HgT fluxes following peaks during the Gold Rush and the mid-20th Century indicate that atmospheric Hg deposition responds quickly to reductions in emissions. Increasing HgT fluxes from 1993 until the youngest samples in 1998 may reflect the resurgence of Hg emissions from unregulated coal burning and small-scale gold mining.

Continuous methane record of abrupt climate change 10-68 ka: sighting Heinrich events in the ice core record

NASA Astrophysics Data System (ADS)

Rhodes, Rachael; Brook, Edward; Chiang, John; Blunier, Thomas; Cheng, Hai; Edwards, R. Lawrence; Maselli, Olivia; McConnell, Joseph; Romanini, Daniele; Severinghaus, Jeffrey; Sowers, Todd; Stowasser, Christopher

2014-05-01

The Last Glacial period was punctuated by millennial scale abrupt climate changes - Dansgaard-Oeschger (D-O) cycles and Heinrich events. Controls on the magnitude and frequency of these climate perturbations, and how they may be inter-related, remain unclear. Specific problems include the difficulty of dating Heinrich sediment layers and local bias of key paleoclimate archives. We present a highly detailed and precise record of ice core methane (CH4), a globally integrated signal, which resolves climatic features in unprecedented resolution. Abrupt CH4 increases are resolved in Heinrich Stadials (HS) 1, 2, 4 and 5 where, in contrast to all D-O cycles, there are no concurrent abrupt changes in Greenland temperature. Using modern-day tropical rainfall variability as an analog, we propose that strong cooling in the North Atlantic severely restricted the northerly range of the Intertropical Convergence Zone (ITCZ), leading to an enhanced wet season over Southern Hemisphere tropical land areas, and consequently driving production of excess CH4 in tropical wetlands. Our findings place four Heinrich events firmly within ice core chronologies and suggest maximum durations of 778 to 1606 yr. CH4 anomalies are only associated with Heinrich events of Hudson Strait provenance, indicating that the tropical impacts of Heinrich events were not uniform.

Rapid Access Ice Drill: A New Tool for Exploration of the Deep Antarctic Ice Sheets and Subglacial Geology

NASA Astrophysics Data System (ADS)

Goodge, J. W.; Severinghaus, J. P.

2014-12-01

The Rapid Access Ice Drill (RAID) will penetrate the Antarctic ice sheets in order to core through deep ice, the glacial bed, and into bedrock below. This new technology will provide a critical first look at the interface between major ice caps and their subglacial geology. Currently in construction, RAID is a mobile drilling system capable of making several long boreholes in a single field season in Antarctica. RAID is interdisciplinary and will allow access to polar paleoclimate records in ice >1 Ma, direct observation at the base of the ice sheets, and recovery of rock cores from the ice-covered East Antarctic craton. RAID uses a diamond rock-coring system as in mineral exploration. Threaded drill-pipe with hardened metal bits will cut through ice using reverse circulation of Estisol for pressure-compensation, maintenance of temperature, and removal of ice cuttings. Near the bottom of the ice sheet, a wireline bottom-hole assembly will enable diamond coring of ice, the glacial bed, and bedrock below. Once complete, boreholes will be kept open with fluid, capped, and made available for future down-hole measurement of thermal gradient, heat flow, ice chronology, and ice deformation. RAID will also sample for extremophile microorganisms. RAID is designed to penetrate up to 3,300 meters of ice and take sample cores in less than 200 hours. This rapid performance will allow completion of a borehole in about 10 days before moving to the next drilling site. RAID is unique because it can provide fast borehole access through thick ice; take short ice cores for paleoclimate study; sample the glacial bed to determine ice-flow conditions; take cores of subglacial bedrock for age dating and crustal history; and create boreholes for use as an observatory in the ice sheets. Together, the rapid drilling capability and mobility of the drilling system, along with ice-penetrating imaging methods, will provide a unique 3D picture of the interior Antarctic ice sheets.

A new set-up for simultaneous high-precision measurements of CO2, δ13C-CO2 and δ18O-CO2 on small ice core samples

NASA Astrophysics Data System (ADS)

Jenk, Theo Manuel; Rubino, Mauro; Etheridge, David; Ciobanu, Viorela Gabriela; Blunier, Thomas

2016-08-01

Palaeoatmospheric records of carbon dioxide and its stable carbon isotope composition (δ13C) obtained from polar ice cores provide important constraints on the natural variability of the carbon cycle. However, the measurements are both analytically challenging and time-consuming; thus only data exist from a limited number of sampling sites and time periods. Additional analytical resources with high analytical precision and throughput are thus desirable to extend the existing datasets. Moreover, consistent measurements derived by independent laboratories and a variety of analytical systems help to further increase confidence in the global CO2 palaeo-reconstructions. Here, we describe our new set-up for simultaneous measurements of atmospheric CO2 mixing ratios and atmospheric δ13C and δ18O-CO2 in air extracted from ice core samples. The centrepiece of the system is a newly designed needle cracker for the mechanical release of air entrapped in ice core samples of 8-13 g operated at -45 °C. The small sample size allows for high resolution and replicate sampling schemes. In our method, CO2 is cryogenically and chromatographically separated from the bulk air and its isotopic composition subsequently determined by continuous flow isotope ratio mass spectrometry (IRMS). In combination with thermal conductivity measurement of the bulk air, the CO2 mixing ratio is calculated. The analytical precision determined from standard air sample measurements over ice is ±1.9 ppm for CO2 and ±0.09 ‰ for δ13C. In a laboratory intercomparison study with CSIRO (Aspendale, Australia), good agreement between CO2 and δ13C results is found for Law Dome ice core samples. Replicate analysis of these samples resulted in a pooled standard deviation of 2.0 ppm for CO2 and 0.11 ‰ for δ13C. These numbers are good, though they are rather conservative estimates of the overall analytical precision achieved for single ice sample measurements. Facilitated by the small sample requirement, replicate measurements are feasible, allowing the method precision to be improved potentially. Further, new analytical approaches are introduced for the accurate correction of the procedural blank and for a consistent detection of measurement outliers, which is based on δ18O-CO2 and the exchange of oxygen between CO2 and the surrounding ice (H2O).

Methanesulfonic acid (MSA) migration in polar ice: data synthesis and theory

NASA Astrophysics Data System (ADS)

Osman, Matthew; Das, Sarah B.; Marchal, Olivier; Evans, Matthew J.

2017-11-01

Methanesulfonic acid (MSA; CH3SO3H) in polar ice is a unique proxy of marine primary productivity, synoptic atmospheric transport, and regional sea-ice behavior. However, MSA can be mobile within the firn and ice matrix, a post-depositional process that is well known but poorly understood and documented, leading to uncertainties in the integrity of the MSA paleoclimatic signal. Here, we use a compilation of 22 ice core MSA records from Greenland and Antarctica and a model of soluble impurity transport in order to comprehensively investigate the vertical migration of MSA from summer layers, where MSA is originally deposited, to adjacent winter layers in polar ice. We find that the shallowest depth of MSA migration in our compilation varies over a wide range (˜ 2 to 400 m) and is positively correlated with snow accumulation rate and negatively correlated with ice concentration of Na+ (typically the most abundant marine cation). Although the considered soluble impurity transport model provides a useful mechanistic framework for studying MSA migration, it remains limited by inadequate constraints on key physico-chemical parameters - most notably, the diffusion coefficient of MSA in cold ice (DMS). We derive a simplified version of the model, which includes DMS as the sole parameter, in order to illuminate aspects of the migration process. Using this model, we show that the progressive phase alignment of MSA and Na+ concentration peaks observed along a high-resolution West Antarctic core is most consistent with 10-12 m2 s-1 < DMS < 10-11 m2 s-1, which is 1 order of magnitude greater than the DMS values previously estimated from laboratory studies. More generally, our data synthesis and model results suggest that (i) MSA migration may be fairly ubiquitous, particularly at coastal and (or) high-accumulation regions across Greenland and Antarctica; and (ii) can significantly change annual and multiyear MSA concentration averages. Thus, in most cases, caution should be exercised when interpreting polar ice core MSA records, although records that have undergone severe migration could still be useful for inferring decadal and lower-frequency climate variability.

Decadal-Scale Response of the Antarctic Ice sheet to a Warming Ocean using the POPSICLES Coupled Ice Sheet-Ocean model

NASA Astrophysics Data System (ADS)

Martin, D. F.; Asay-Davis, X.; Cornford, S. L.; Price, S. F.; Ng, E. G.; Collins, W.

2015-12-01

We present POPSICLES simulation results covering the full Antarctic Ice Sheet and the Southern Ocean spanning the period from 1990 to 2010. We use the CORE v. 2 interannual forcing data to force the ocean model. Simulations are performed at 0.1o(~5 km) ocean resolution with adaptive ice sheet resolution as fine as 500 m to adequately resolve the grounding line dynamics. We discuss the effect of improved ocean mixing and subshelf bathymetry (vs. the standard Bedmap2 bathymetry) on the behavior of the coupled system, comparing time-averaged melt rates below a number of major ice shelves with those reported in the literature. We also present seasonal variability and decadal melting trends from several Antarctic regions, along with the response of the ice shelves and the consequent dynamic response of the grounded ice sheet.POPSICLES couples the POP2x ocean model, a modified version of the Parallel Ocean Program, and the BISICLES ice-sheet model. POP2x includes sub-ice-shelf circulation using partial top cells and the commonly used three-equation boundary layer physics. Standalone POP2x output compares well with standard ice-ocean test cases (e.g., ISOMIP) and other continental-scale simulations and melt-rate observations. BISICLES makes use of adaptive mesh refinement and a 1st-order accurate momentum balance similar to the L1L2 model of Schoof and Hindmarsh to accurately model regions of dynamic complexity, such as ice streams, outlet glaciers, and grounding lines. Results of BISICLES simulations have compared favorably to comparable simulations with a Stokes momentum balance in both idealized tests (MISMIP-3d) and realistic configurations.The figure shows the BISICLES-computed vertically-integrated grounded ice velocity field 5 years into a 20-year coupled full-continent Antarctic-Southern-Ocean simulation. Submarine melt rates are painted onto the surface of the floating ice shelves. Grounding lines are shown in green.

Consistently dated records from three Greenland ice cores reveal regional millennial-scale isotope gradients with possible Heinrich Event imprint

NASA Astrophysics Data System (ADS)

Seierstad, Inger K.; Rasmussen, Sune O.

2014-05-01

We here present records from the NGRIP, GRIP and GISP2 ice cores tied to the same chronology for the past 104 ka at an unprecedented time resolution. The three ice cores have been linked by matching distinct peaks in volcanic proxy records and other impurity records from the three ice cores, assuming that these layers of elevated impurity content represent the same, instantaneous event in the past at all three sites. In total there are more than 900 identified marker horizons between the three cores including previously published match points, of which we introduce a minor revision. Our matching is independently confirmed by new and existing volcanic ash layers (tephra). The depth-depth relationship from the detailed matching is used to transfer the most recent and widely used Greenland ice core chronology, the GICC05modelext timescale, to the two Summit cores, GRIP and GISP2. Furthermore, we provide gas chronologies for the Summit cores that are consistent with the GICC05modelext timescale by utilizing both existing and new unpublished gas data. A comparison of the GICC05modelext and the former GISP2 timescale reveals major discrepancies in short time intervals during the glacial section. We detect a pronounced change in the relative annual layer thickness between the two Summit sites and NGRIP across the Last Glacial termination and early-to-mid Holocene, which can be explained by a relative accumulation increase at NGRIP compared to the Summit region as response to the onset of the Holocene and the climatic optimum. Between stadials and interstadials we infer that the accumulation contrast typically was nearly 10% greater at Summit compared to at NGRIP. The δ18O temperature-proxy records from NGRIP, GRIP and GISP2 are generally very similar and display a synchronous behavior at climate transitions, but the δ18O differences between Summit and NGRIP is slowly changing over the last glacial-interglacial cycle superimposed by abrupt millennial-to centennial scale anomalies. We suggest that the latitudinal δ18O gradient during the glacial is result of 1) relatively higher degree of precipitation with a Pacific signature at NGRIP, 2) increased summer bias at Summit, and 3) enhanced Raleigh distillation process due to and increased source-to-site distance, and we conclude that this is governed by North American Ice Sheet (NAIS) volume and North Atlantic sea-ice extent and/or sea-surface temperatures (SST) at orbital timescales, while changing sea-ice extent and SSTs are the driving mechanisms on shorter timescales. We assert that δ18O difference maxima can be linked to Heinrich Events, which is associated with southwards expansion of polar waters and low SSTs in the North Atlantic, and ths propose a direct link between the marine realm and the Greenland ice core records. The work presented is under review for publication in Quaternary Science Reviews. Author team: I.K. Seierstad, P. Abbott, M. Bigler, T. Blunier, A. Bourne, E. Brook, S.L. Buchardt, C. Buizert, H.B. Clausen, E. Cook, D. Dahl-Jensen, S.Davies, M. Guillevic, S.J. Johnsen, D.S. Pedersen, T.J. Popp, S.O. Rasmussen, J. Severinghaus, A. Svensson, B.M. Vinther (deceased).

The IceAge ERS Program: Probing Building blocks of Life During the JWST Era

NASA Astrophysics Data System (ADS)

McClure, Melissa K.; Boogert, Adwin; Linnartz, Harold; Beck, Tracy L.; van Dishoeck, Ewine; Egami, Eiichi; Garrod, Robin; Gordon, Karl D.; Palumbo, Maria Elisabetta; Brown, Wendy; Fraser, Helen; Ioppolo, Sergio; Jimenez-Serra, Izaskun; McCoustra, Martin; Noble, Jennifer; Pendleton, Yvonne J.; Pontoppidan, Klaus; Viti, Serena; Chiar, Jean E.; Caselli, Paola; Bailey, John Ira; Jorgensen, Jes; Kristensen, Lars; Murillo, Nadia; Oberg, Karin I.; IceAge ERS Team Collaborators

2018-06-01

Icy grain mantles are the main reservoir for volatile elements in star-forming regions across the Universe, as well as the formation site of pre-biotic complex organic molecules (COMs) seen in our Solar System. Through the IceAge Early Release Science program, we will trace the evolution of pristine and complex ice chemistry in a representative low-mass star-forming region through observations of a: pre-stellar core, Class 0 protostar, Class I protostar, and protoplanetary disk. Comparing high spectral resolution (R~1500-3000) and sensitivity (S/N~100-300) observations from 3 to 15 micron to template spectra, we will map the spatial distribution of ices down to ~20-50 AU in these targets to identify when, and at what visual extinction, the formation of each ice species begins. Such high-resolution spectra will allow us to search for new COMs, as well as distinguish between different ice morphologies, thermal histories, and mixing environments.The analysis of these data will result in science products beneficial to Cycle 2 proposers. A newly updated public laboratory ice database will provide feature identifications for all of the expected ices, while a chemical model fit to the observed ice abundances will be released publically as a grid, with varied metallicity and UV fields to simulate other environments. We will create improved algorithms to extract NIRCAM WFSS spectra in crowded fields with extended sources as well as optimize the defringing of MIRI LRS spectra in order to recover broad spectral features. We anticipate that these resources will be particularly useful for astrochemistry and spectroscopy of fainter, extended targets like star forming regions of the SMC/LMC or more distant galaxies.

Constraining recent lead pollution sources in the North Pacific using ice core stable lead isotopes

NASA Astrophysics Data System (ADS)

Kreutz, K. J.; Osterberg, E. C.; Gross, B.; Handley, M.; Wake, C. P.; Yalcin, K.

2009-12-01

Trends and sources of lead aerosol pollution in the North Pacific boundary layer from 1970-2001 are investigated using a high-resolution ice core record recovered from Eclipse Icefield (3017 masl; St. Elias Mountains, Canada). Average Pb concentrations in the ice core are enriched 31.8 times above crustal values based on ratios with five crustal reference elements (La, Ce, Pr, Al and Ti), indicating that >90% of the Pb deposited is anthropogenic. Isotopic analyses (208Pb/207Pb and 206Pb/207Pb) confirm that the Pb deposited at Eclipse Icefield is predominantly anthropogenic. Annually averaged Pb concentrations range from 25.6 ng/l to 96.7 ng/l (67.6 ng/l mean) and show no long term trend for the 1970-2001 period, contrary to other ice core records from the North Atlantic and the North Pacific. The stable Pb isotope ratio (208Pb/207Pb and 206Pb/207Pb) field indicates that recent Eclipse Icefield Pb pollution represents a variable mixture of North American, Central Eurasian and Asian (Chinese and Japanese) emissions transported across the Pacific basin, with Chinese coal combustion likely being the primary source. Increasing 208Pb/207Pb and 206Pb/207Pb ratios from the 1970’s through 2001 reflect the progressive East Asian industrialization concurrent with a decrease in Eurasian Pb emissions. We compare Pb isotope results from the Eclipse Icefield to data recently acquired from Denali National Park, where snowpit samples were collected from the Kahiltna Pass region (3048 masl). Pb isotope data from both sites are used to evaluate the relative importance of Asian emissions at similar altitudes yet different latitudes.

Mid-twentieth century increases in anthropogenic Pb, Cd and Cu in central Asia set in hemispheric perspective using Tien Shan ice core

NASA Astrophysics Data System (ADS)

Grigholm, B.; Mayewski, P. A.; Aizen, V.; Kreutz, K.; Wake, C. P.; Aizen, E.; Kang, S.; Maasch, K. A.; Handley, M. J.; Sneed, S. B.

2016-04-01

High-resolution major and trace element (Al, As, Ca, Cd, Co, Cr, Cu, Fe, Li, Mn, Na, Pb, S, Ti, and V) ice core records from Inilchek glacier (5120 m above sea level) on the northwestern margin of the Tibetan Plateau provide the first multi-decadal ice core record spanning the period 1908-1995 AD in central Tien Shan. The trace element records reveal pronounced temporal baseline trends and concentration maxima characteristic of post-1950 anthropogenic emissions. Examination of Pb, Cd and Cu concentrations, along with non-crustal calculation estimates (i.e. excess (ex) and enrichment factor (EF)), reveal that discernable anthropogenic inputs began during the 1950s and rapidly increased to the late-1970s and early 1980s, by factors up to of 5, 6 and 3, respectively, relative to a 1910-1950 means. Pb, Cd and Cu concentrations between the 1950s-1980s are reflective of large-scale Soviet industrial and agricultural development, including the growth of production and/or consumption of the non-ferrous metals, coal and phosphate fertilizers. NOAA HYSPLIT back-trajectory frequency analysis suggests pollutant sources originating primarily from southern Kazakhstan (e.g. Shymkent and Balkhash) and the Fergana Valley (located in Kazakhstan, Uzbekistan and Kyrgyzstan). Inilchek ice core Pb, Cd and Cu reveals declines during the 1980s concurrent with Soviet economic declines, however, due to the rapid industrial and agricultural growth of western China, Pb, Cd and Cu trends increase during the 1990s reflecting a transition from primarily central Asian sources to emission sources from western China (e.g. Xinjiang Province).

10Be evidence for the Matuyama-Brunhes geomagnetic reversal in the EPICA Dome C ice core.

PubMed

Raisbeck, G M; Yiou, F; Cattani, O; Jouzel, J

2006-11-02

An ice core drilled at Dome C, Antarctica, is the oldest ice core so far retrieved. On the basis of ice flow modelling and a comparison between the deuterium signal in the ice with climate records from marine sediment cores, the ice at a depth of 3,190 m in the Dome C core is believed to have been deposited around 800,000 years ago, offering a rare opportunity to study climatic and environmental conditions over this time period. However, an independent determination of this age is important because the deuterium profile below a depth of 3,190 m depth does not show the expected correlation with the marine record. Here we present evidence for enhanced 10Be deposition in the ice at 3,160-3,170 m, which we interpret as a result of the low dipole field strength during the Matuyama-Brunhes geomagnetic reversal, which occurred about 780,000 years ago. If correct, this provides a crucial tie point between ice cores, marine cores and a radiometric timescale.

Precise interpolar phasing of abrupt climate change during the last ice age

USGS Publications Warehouse

,; Buizert, Christo; Adrian, Betty M.; Ahn, Jinho; Albert, Mary; Alley, Richard B.; Baggenstos, Daniel; Bauska, Thomas K.; Bay, Ryan C.; Bencivengo, Brian B.; Bentley, Charles R.; Brook, Edward J.; Chellman, Nathan J.; Clow, Gary D.; Cole-Dai, Jihong; Conway, Howard; Cravens, Eric; Cuffey, Kurt M.; Dunbar, Nelia W.; Edwards, Jon S.; Fegyveresi, John M.; Ferris, Dave G.; Fitzpatrick, Joan J.; Fudge, T. J.; Gibson, Chris J.; Gkinis, Vasileios; Goetz, Joshua J.; Gregory, Stephanie; Hargreaves, Geoffrey Mill; Iverson, Nels; Johnson, Jay A.; Jones, Tyler R.; Kalk, Michael L.; Kippenhan, Matthew J.; Koffman, Bess G.; Kreutz, Karl; Kuhl, Tanner W.; Lebar, Donald A.; Lee, James E.; Marcott, Shaun A.; Markle, Bradley R.; Maselli, Olivia J.; McConnell, Joseph R.; McGwire, Kenneth C.; Mitchell, Logan E.; Mortensen, Nicolai B.; Neff, Peter D.; Nishiizumi, Kunihiko; Nunn, Richard M.; Orsi, Anais J.; Pasteris, Daniel R.; Pedro, Joel B.; Pettit, Erin C.; Price, P. Buford; Priscu, John C.; Rhodes, Rachael H.; Rosen, Julia L.; Schauer, Andrew J.; Schoenemann, Spruce W.; Sendelbach, Paul J.; Severinghaus, Jeffrey P.; Shturmakov, Alexander J.; Sigl, Michael; Slawny, Kristina R.; Souney, Joseph M.; Sowers, Todd A.; Spencer, Matthew K.; Steig, Eric J.; Taylor, Kendrick C.; Twickler, Mark S.; Vaughn, Bruce H.; Voigt, Donald E.; Waddington, Edwin D.; Welten, Kees C.; Wendricks, Anthony W.; White, James W. C.; Winstrup, Mai; Wong, Gifford J.; Woodruff, Thomas E.

2015-01-01

The last glacial period exhibited abrupt Dansgaard–Oeschger climatic oscillations, evidence of which is preserved in a variety of Northern Hemisphere palaeoclimate archives1. Ice cores show that Antarctica cooled during the warm phases of the Greenland Dansgaard–Oeschger cycle and vice versa2, 3, suggesting an interhemispheric redistribution of heat through a mechanism called the bipolar seesaw4, 5, 6. Variations in the Atlantic meridional overturning circulation (AMOC) strength are thought to have been important, but much uncertainty remains regarding the dynamics and trigger of these abrupt events7, 8, 9. Key information is contained in the relative phasing of hemispheric climate variations, yet the large, poorly constrained difference between gas age and ice age and the relatively low resolution of methane records from Antarctic ice cores have so far precluded methane-based synchronization at the required sub-centennial precision2, 3,10. Here we use a recently drilled high-accumulation Antarctic ice core to show that, on average, abrupt Greenland warming leads the corresponding Antarctic cooling onset by 218 ± 92 years (2σ) for Dansgaard–Oeschger events, including the Bølling event; Greenland cooling leads the corresponding onset of Antarctic warming by 208 ± 96 years. Our results demonstrate a north-to-south directionality of the abrupt climatic signal, which is propagated to the Southern Hemisphere high latitudes by oceanic rather than atmospheric processes. The similar interpolar phasing of warming and cooling transitions suggests that the transfer time of the climatic signal is independent of the AMOC background state. Our findings confirm a central role for ocean circulation in the bipolar seesaw and provide clear criteria for assessing hypotheses and model simulations of Dansgaard–Oeschger dynamics.

OMIP contribution to CMIP6: experimental and diagnostic protocol for the physical component of the Ocean Model Intercomparison Project

NASA Astrophysics Data System (ADS)

Griffies, Stephen M.; Danabasoglu, Gokhan; Durack, Paul J.; Adcroft, Alistair J.; Balaji, V.; Böning, Claus W.; Chassignet, Eric P.; Curchitser, Enrique; Deshayes, Julie; Drange, Helge; Fox-Kemper, Baylor; Gleckler, Peter J.; Gregory, Jonathan M.; Haak, Helmuth; Hallberg, Robert W.; Heimbach, Patrick; Hewitt, Helene T.; Holland, David M.; Ilyina, Tatiana; Jungclaus, Johann H.; Komuro, Yoshiki; Krasting, John P.; Large, William G.; Marsland, Simon J.; Masina, Simona; McDougall, Trevor J.; Nurser, A. J. George; Orr, James C.; Pirani, Anna; Qiao, Fangli; Stouffer, Ronald J.; Taylor, Karl E.; Treguier, Anne Marie; Tsujino, Hiroyuki; Uotila, Petteri; Valdivieso, Maria; Wang, Qiang; Winton, Michael; Yeager, Stephen G.

2016-09-01

The Ocean Model Intercomparison Project (OMIP) is an endorsed project in the Coupled Model Intercomparison Project Phase 6 (CMIP6). OMIP addresses CMIP6 science questions, investigating the origins and consequences of systematic model biases. It does so by providing a framework for evaluating (including assessment of systematic biases), understanding, and improving ocean, sea-ice, tracer, and biogeochemical components of climate and earth system models contributing to CMIP6. Among the WCRP Grand Challenges in climate science (GCs), OMIP primarily contributes to the regional sea level change and near-term (climate/decadal) prediction GCs.OMIP provides (a) an experimental protocol for global ocean/sea-ice models run with a prescribed atmospheric forcing; and (b) a protocol for ocean diagnostics to be saved as part of CMIP6. We focus here on the physical component of OMIP, with a companion paper (Orr et al., 2016) detailing methods for the inert chemistry and interactive biogeochemistry. The physical portion of the OMIP experimental protocol follows the interannual Coordinated Ocean-ice Reference Experiments (CORE-II). Since 2009, CORE-I (Normal Year Forcing) and CORE-II (Interannual Forcing) have become the standard methods to evaluate global ocean/sea-ice simulations and to examine mechanisms for forced ocean climate variability. The OMIP diagnostic protocol is relevant for any ocean model component of CMIP6, including the DECK (Diagnostic, Evaluation and Characterization of Klima experiments), historical simulations, FAFMIP (Flux Anomaly Forced MIP), C4MIP (Coupled Carbon Cycle Climate MIP), DAMIP (Detection and Attribution MIP), DCPP (Decadal Climate Prediction Project), ScenarioMIP, HighResMIP (High Resolution MIP), as well as the ocean/sea-ice OMIP simulations.

Tracing Marine Cryptotephras in the North Atlantic during the Last Glacial Period

NASA Astrophysics Data System (ADS)

Abbott, Peter; Davies, Siwan; Griggs, Adam; Bourne, Anna

2017-04-01

Tephrochronology is a powerful technique that can be utilised for the independent correlation and synchronisation of disparate palaeoclimatic records from different depositional environments. There is a high potential to utilise this technique to integrate ice, marine and terrestrial records to study climatic phasing within the North Atlantic region due to the high eruptive frequency of Icelandic volcanic systems. However, until now North Atlantic marine records have been relatively understudied. Here we report on investigations to define a tephra framework integrating new studies of cryptotephra horizons within a wide network of North Atlantic marine cores with horizons identified in prior work. This framework has the potential to underpin the correlation of the marine records to the Greenland ice-core records and European terrestrial sequences. Tephrochronological investigations were conducted on 13 marine sequences from a range of locations and depositional settings using cryptotephra extraction techniques, including density and magnetic separation, to gain high resolution glass shard concentration profiles and rigorous single-shard major element geochemical analysis to characterise identified deposits. Cryptotephras with an Icelandic source were identified in many records and displayed diversity in shard concentration profiles and the geochemical homo/heterogeneity of shards within the deposits. These differences reflect spatial and temporal variability in the operation of a range of transport processes, e.g. airfall, sea-ice and iceberg rafting, and post-depositional processes, e.g. bioturbation and secondary redeposition. The operation of these processes within the marine environment can potentially impart a temporal delay on tephra deposition and hamper the placement of the isochron, therefore, it is crucial to assess their influence. To aid this assessment a range of deposit types with common transport and depositional histories have been defined. Spatial patterns in the occurrence of these deposit types have been detected, the dominant controls at different sites explored and key regions of the North Atlantic with a greater likelihood for preserving isochronous deposits identified. Overall, these investigations have allowed a framework of isochronous marine cryptotephras to be defined for the last glacial period. The most widespread deposit is the rhyolitic phase of North Atlantic Ash Zone II, identified in 9 of the marine sequences and providing a direct tie-line to the Greenland ice-cores records. The framework is dominated by horizons with a basaltic composition, predominantly sourced from the Icelandic Grímsvötn volcanic system but horizons with Katla, Hekla, Kverkfjöll, Veidivötn and Vestmannaeyjar like compositions have also been isolated. Correlations to horizons in the Greenland ice-core tephra framework are being explored, however, this is a challenging process due to the large number of horizons with similar geochemical signatures in the records and the difference in temporal resolution and stratigraphic control between the ice and marine sequences.

Ice cores and SeaRISE: What we do (and don't) know

NASA Technical Reports Server (NTRS)

Alley, Richard B.

1991-01-01

Ice core analyses are needed in SeaRISE to learn what the West Antarctic ice sheet and other marine ice sheets were like in the past, what climate changes led to their present states, and how they behave. The major results of interest to SeaRISE from previous ice core analyses in West Antarctic are that the end of the last ice age caused temperature and accumulation rate increases in inland regions, leading to ice sheet thickening followed by thinning to the present.

WATSON: Detecting organic material in subsurface ice using deep-UV fluorescence and Raman spectroscopy

NASA Astrophysics Data System (ADS)

Eshelman, E.; Wanger, G.; Manatt, K.; Malaska, M.; Willis, M.; Abbey, W.; Doloboff, I.; Beegle, L. W.; DeFlores, L. P.; Priscu, J. C.; Lane, A. L.; Carrier, B. L.; Mellerowicz, B.; Kim, D.; Paulsen, G.; Zacny, K.; Bhartia, R.

2017-12-01

Future astrobiological missions to Europa and other ocean worlds may benefit from next-generation instrumentation capable of in situ organic and life detection in subsurface ice environments. WATSON (Wireline Analysis Tool for in Situ Observation of Northern ice sheets) is an instrument under development at NASA's Jet Propulsion Laboratory. WATSON contains high-TRL instrumentation developed for SHERLOC, the Mars 2020 deep-UV fluorescence and Raman spectrometer, including a 248.6 nm NeCu hollow cathode laser as an excitation source. In WATSON, these technologies provide spectroscopic capabilities highly sensitive to many organic compounds, including microbes, in an instrument package approximately 1.2 m long with a 101.6 mm diameter, designed to accommodate a 108 mm ice borehole. Interrogation into the ice wall with a laser allows for a non-destructive in situ measurement that preserves the spatial distribution of material within the ice. We report on a successful deployment of WATSON to Kangerlussuaq, Greenland, where the instrument was lowered to a 4.5 m depth in a hand-cored hole on the Kangerlussuaq sector of the Greenland ice sheet. Motorized stages within the instrument were used to raster a laser across cm-scale regions of the interior surface of the borehole, obtaining fluorescence spectral maps with a 200 µm spatial resolution and a spectral range from 265 nm to 440 nm. This region includes the UV emission bands of many aromatic compounds and microbes, and includes the water and ice Raman O-H stretching modes. We additionally report on experiments designed to inform an early-2018 deployment to Kangerlussuaq where WATSON will be incorporated into a Honeybee Robotics planetary deep drill, with a goal of drilling to a depth of 100 m and investigating the distribution of organic material within the ice sheet. These experiments include laboratory calibrations to determine the sensitivity to organic compounds embedded in ice at various depths, as well as analysis of ice cores obtained during the deployment and returned for subsequent study.

The 1500m South Pole Ice Core: Recovering a 40 Ka Environmental Record

NASA Technical Reports Server (NTRS)

Casey, Kimberly Ann; Neumann, Thomas Allen; Fudge, T. J.; Neumann, T. A.; Steig, E. J.; Cavitte, M. G. P.; Blankenship, D. D.

2014-01-01

Supported by the US National Science Foundation, a new 1500 m, approximately 40 ka old ice core will be recovered from South Pole during the 2014/15 and 2015/16 austral summer seasons using the new US Intermediate Depth Drill. The combination of low temperatures, relatively high accumulation rates and low impurity concentrations at South Pole will yield detailed records of ice chemistry and trace atmospheric gases. The South Pole ice core will provide a climate history record of a unique area of the East Antarctic plateau that is partly influenced by weather systems that cross the West Antarctic ice sheet. The ice at South Pole flows at approximately 10m a(exp-1) and the South Pole ice-core site is a significant distance from an ice divide. Therefore, ice recovered at depth originated progressively farther upstream of the coring site. New ground-penetrating radar collected over the drill site location shows no anthropogenic influence over the past approximately 50 years or upper 15 m. Depth-age scale modeling results show consistent and plausible annual-layer thicknesses and accumulation rate histories, indicating that no significant stratigraphic disturbances exist in the upper 1500m near the ice-core drill site.

IceChrono1: a probabilistic model to compute a common and optimal chronology for several ice cores

NASA Astrophysics Data System (ADS)

Parrenin, Frédéric; Bazin, Lucie; Capron, Emilie; Landais, Amaëlle; Lemieux-Dudon, Bénédicte; Masson-Delmotte, Valérie

2016-04-01

Polar ice cores provide exceptional archives of past environmental conditions. The dating of ice cores and the estimation of the age scale uncertainty are essential to interpret the climate and environmental records that they contain. It is however a complex problem which involves different methods. Here, we present IceChrono1, a new probabilistic model integrating various sources of chronological information to produce a common and optimized chronology for several ice cores, as well as its uncertainty. IceChrono1 is based on the inversion of three quantities: the surface accumulation rate, the Lock-In Depth (LID) of air bubbles and the thinning function. The chronological information integrated into the model are: models of the sedimentation process (accumulation of snow, densification of snow into ice and air trapping, ice flow), ice and air dated horizons, ice and air depth intervals with known durations, Δdepth observations (depth shift between synchronous events recorded in the ice and in the air) and finally air and ice stratigraphic links in between ice cores. The optimization is formulated as a least squares problem, implying that all densities of probabilities are assumed to be Gaussian. It is numerically solved using the Levenberg-Marquardt algorithm and a numerical evaluation of the model's Jacobian. IceChrono follows an approach similar to that of the Datice model which was recently used to produce the AICC2012 chronology for 4 Antarctic ice cores and 1 Greenland ice core. IceChrono1 provides improvements and simplifications with respect to Datice from the mathematical, numerical and programming point of views. The capabilities of IceChrono is demonstrated on a case study similar to the AICC2012 dating experiment. We find results similar to those of Datice, within a few centuries, which is a confirmation of both IceChrono and Datice codes. We also test new functionalities with respect to the original version of Datice: observations as ice intervals with known durations, correlated observations, observations as gas intervals with known durations and observations as mixed ice-air stratigraphic links. IceChrono1 is freely available under the GPL v3 open source license.

The effect of changing wind forcing on Antarctic ice shelf melting in high-resolution, global sea ice-ocean simulations with the Accelerated Climate Model for Energy (ACME)

NASA Astrophysics Data System (ADS)

Asay-Davis, Xylar; Price, Stephen; Petersen, Mark; Wolfe, Jonathan

2017-04-01

The capability for simulating sub-ice shelf circulation and submarine melting and freezing has recently been added to the U.S. Department of Energy's Accelerated Climate Model for Energy (ACME). With this new capability, we use an eddy permitting ocean model to conduct two sets of simulations in the spirit of Spence et al. (GRL, 41, 2014), who demonstrate increased warm water upwelling along the Antarctic coast in response to poleward shifting and strengthening of Southern Ocean westerly winds. These characteristics, symptomatic of a positive Southern Annular Mode (SAM), are projected to continue into the 21st century under anthropogenic climate change (Fyfe et al., J. Clim., 20, 2007). In our first simulation, we force the climate model using the standard CORE interannual forcing dataset (Large and Yeager; Clim. Dyn., 33, 2009). In our second simulation, we force our climate model using an altered version of CORE interannual forcing, based on the latter half of the full time series, which we take as a proxy for a future climate state biased towards a positive SAM. We compare ocean model states and sub-ice shelf melt rates with observations, exploring sources of model biases as well as the effects of the two forcing scenarios.

Prospects for reconstructing paleoenvironmental conditions from organic compounds in polar snow and ice

USGS Publications Warehouse

Giorio, Chiara; Kehrwald, Natalie; Barbante, Carlo; Kalberer, Markus; King, Amy C.F.; Thomas, Elizabeth R.; Wolff, Eric W.; Zennaro, Piero

2018-01-01

Polar ice cores provide information about past climate and environmental changes over periods ranging from a few years up to 800,000 years. The majority of chemical studies have focused on determining inorganic components, such as major ions and trace elements as well as on their isotopic fingerprint. In this paper, we review the different classes of organic compounds that might yield environmental information, discussing existing research and what is needed to improve knowledge. We also discuss the problems of sampling, analysis and interpretation of organic molecules in ice. This review highlights the great potential for organic compounds to be used as proxies for anthropogenic activities, past fire events from different types of biomass, terrestrial biogenic emissions and marine biological activity, along with the possibility of inferring past temperature fluctuations and even large-scale climate variability. In parallel, comprehensive research needs to be done to assess the atmospheric stability of these compounds, their ability to be transported long distances in the atmosphere, and their stability in the archive in order to better interpret their fluxes in ice cores. In addition, specific decontamination procedures, analytical methods with low detection limits (ng/L or lower), fast analysis time and low sample requests need to be developed in order to ensure a good time resolution in the archive.

Prospects for reconstructing paleoenvironmental conditions from organic compounds in polar snow and ice

NASA Astrophysics Data System (ADS)

Giorio, Chiara; Kehrwald, Natalie; Barbante, Carlo; Kalberer, Markus; King, Amy C. F.; Thomas, Elizabeth R.; Wolff, Eric W.; Zennaro, Piero

2018-03-01

Polar ice cores provide information about past climate and environmental changes over periods ranging from a few years up to 800,000 years. The majority of chemical studies have focused on determining inorganic components, such as major ions and trace elements as well as on their isotopic fingerprint. In this paper, we review the different classes of organic compounds that might yield environmental information, discussing existing research and what is needed to improve knowledge. We also discuss the problems of sampling, analysis and interpretation of organic molecules in ice. This review highlights the great potential for organic compounds to be used as proxies for anthropogenic activities, past fire events from different types of biomass, terrestrial biogenic emissions and marine biological activity, along with the possibility of inferring past temperature fluctuations and even large-scale climate variability. In parallel, comprehensive research needs to be done to assess the atmospheric stability of these compounds, their ability to be transported long distances in the atmosphere, and their stability in the archive in order to better interpret their fluxes in ice cores. In addition, specific decontamination procedures, analytical methods with low detection limits (ng/L or lower), fast analysis time and low sample requests need to be developed in order to ensure a good time resolution in the archive.

Rise in central west Greenland surface melt unprecedented over the last three centuries

NASA Astrophysics Data System (ADS)

Trusel, Luke; Das, Sarah; Osman, Matthew; Evans, Matthew; Smith, Ben; McConnell, Joe; Noël, Brice; van den Broeke, Michiel

2017-04-01

Greenland Ice Sheet surface melting has intensified and expanded over the last several decades and is now a leading component of ice sheet mass loss. Here, we constrain the multi-century temporal evolution of surface melt across central west Greenland by quantifying layers of refrozen melt within well-dated firn and ice cores collected in 2014 and 2015, as well as from a core collected in 2004. We find significant agreement among ice core, satellite, and regional climate model melt datasets over recent decades, confirming the fidelity of the ice core melt stratigraphy as a reliable record of past variability in the magnitude of surface melt. We also find a significant correlation between the melt records derived from our new 100-m GC-2015 core (2436 m.a.s.l.) and the older (2004) 150-m D5 core (2472 m.a.s.l.) located 50 km to the southeast. This agreement demonstrates the robustness of the ice core-derived melt histories and the potential for reconstructing regional melt evolution from a single site, despite local variability in melt percolation and refreeze processes. Our array of upper percolation zone cores reveals that although the overall frequency of melt at these sites has not increased, the intensification of melt over the last three decades is unprecedented within at least the last 365 years. Utilizing the regional climate model RACMO 2.3, we show that this melt intensification is a nonlinear response to warming summer air temperatures, thus underscoring the heightened sensitivity of this sector of Greenland to further climate warming. Finally, we examine spatial correlations between the ice core melt records and modeled melt fields across the ice sheet to assess the broader representation of each ice core record. This analysis reveals wide-ranging significant correlations, including to modeled meltwater runoff. As such, our ice core melt records may furthermore offer unique, observationally-constrained insights into past variability in ice sheet mass loss.

Spontaneous abrupt climate change due to an atmospheric blocking–sea-ice–ocean feedback in an unforced climate model simulation

PubMed Central

Drijfhout, Sybren; Gleeson, Emily; Dijkstra, Henk A.; Livina, Valerie

2013-01-01

Abrupt climate change is abundant in geological records, but climate models rarely have been able to simulate such events in response to realistic forcing. Here we report on a spontaneous abrupt cooling event, lasting for more than a century, with a temperature anomaly similar to that of the Little Ice Age. The event was simulated in the preindustrial control run of a high-resolution climate model, without imposing external perturbations. Initial cooling started with a period of enhanced atmospheric blocking over the eastern subpolar gyre. In response, a southward progression of the sea-ice margin occurred, and the sea-level pressure anomaly was locked to the sea-ice margin through thermal forcing. The cold-core high steered more cold air to the area, reinforcing the sea-ice concentration anomaly east of Greenland. The sea-ice surplus was carried southward by ocean currents around the tip of Greenland. South of 70°N, sea ice already started melting and the associated freshwater anomaly was carried to the Labrador Sea, shutting off deep convection. There, surface waters were exposed longer to atmospheric cooling and sea surface temperature dropped, causing an even larger thermally forced high above the Labrador Sea. In consequence, east of Greenland, anomalous winds changed from north to south, terminating the event with similar abruptness to its onset. Our results imply that only climate models that possess sufficient resolution to correctly represent atmospheric blocking, in combination with a sensitive sea-ice model, are able to simulate this kind of abrupt climate change. PMID:24248352

Implications of high amplitude atmospheric CO2 fluctuations on past millennium climate change

NASA Astrophysics Data System (ADS)

van Hoof, Thomas; Kouwenberg, Lenny; Wagner-Cremer, Friederike; Visscher, Henk

2010-05-01

Stomatal frequency analysis of leaves of land plants preserved in peat and lake deposits can provide a proxy record of pre-industrial atmospheric CO2 concentration complementary to measurements in Antarctic ice cores. Stomatal frequency based CO2 trends from the USA and NW European support the presence of significant CO2 variability during the first half of the last millennium (Kouwenberg et al., 2005; Wagner et al., 2004; van Hoof et al., 2008). The timing of the most significant perturbation in the stomata records (1200 AD) is in agreement with an observed CO2 fluctuation in the D47 Antarctic ice-core record (Barnola et al., 1995; van Hoof et al., 2005). The amplitude of the stomatal frequency based CO2 changes (> 34ppmv) exceeds the maximum amplitude of CO2 variability in the D47 ice core (< 10 ppmv). A modelling experiment taking into account firn-densification based smoothing processes in the D47 ice core proved, however, that the amplitude difference between the stomata record and the D47 ice-core can be explained by natural smoothing processes in the ice (van Hoof et al., 2005). This observation gives credence to the existence of high-amplitude CO2 fluctuations during the last millennium and suggests that high resolution ice core CO2 records should be regarded as a smoothed representation of the atmospheric CO2 signal. In the present study, potential marine and terrestrial sources and sinks associated with the observed atmospheric CO2 perturbation will be discussed. The magnitude of the observed CO2 variability implies that inferred changes in CO2 radiative forcing are of a similar magnitude as variations ascribed to other forcing mechanisms (e.g. solar forcing and volcanism), therefore challenging the IPCC concept of CO2 as an insignificant preindustrial climate forcing factor. References Barnola J.M., M. Anklin, J. Porcheron, D. Raynaud, J. Schwander and B. Stauffer 1995. CO2 evolution during the last millennium as recorded by Antarctic and Greenland ice. Tellus, v 47B, p. 264-272 Kouwenberg L.L.R., F. Wagner, W.M. Kürschner and H. Visscher 2005. Atmospheric CO2 fluctuations during the last Millennium reconstructed by stomatal frequency analysis of Tsuga heterophylla needles. Geology, v. 33, no.1, pp. 33-36 van Hoof T.B., K.A. Kaspers, F. Wagner, R.S.W. van de Wal, W.M. Kürschner and H. Visscher 2005. Atmospheric CO2 during the 13th century AD: reconciliation of data from ice core measurements and stomatal frequency analysis. Tellus B, v. 57, pp. 351-355 van Hoof T.B., F. Wagner-Cremer, W.M. K Kürschner and H. Visscher 2008. A role for atmospheric CO2 in preindustrial climate forcing. Proceedings of the National Academy of Sciences of the USA, v. 105, no. 41, pp. 15815-15818 Wagner F., L.L.R. Kouwenberg, T.B. van Hoof and H. Visscher 2004. Reproducibility of Holocene atmospheric CO2 records based on stomatal frequency. Quartenary Science Reviews. V. 23, pp. 1947-1954

An ocean-ice coupled response during the last glacial: a view from a marine isotopic stage 3 record south of the Faeroe Shetland Gateway

NASA Astrophysics Data System (ADS)

Zumaque, J.; Eynaud, F.; Zaragosi, S.; Marret, F.; Matsuzaki, K. M.; Kissel, C.; Roche, D. M.; Malaizé, B.; Michel, E.; Billy, I.; Richter, T.; Palis, E.

2012-12-01

The rapid climatic variability characterising the Marine Isotopic Stage (MIS) 3 (~60-30 cal ka BP) provides key issues to understand the atmosphere-ocean-cryosphere dynamics. Here we investigate the response of sea-surface paleoenvironments to the MIS3 climatic variability through the study of a high resolution oceanic sedimentological archive (core MD99-2281, 60°21' N; 09°27' W; 1197 m water depth), retrieved during the MD114-IMAGES (International Marine Global Change Study) cruise from the southern part of the Faeroe Bank. This sector was under the proximal influence of European ice sheets (Fennoscandian Ice Sheet to the East, British Irish Ice Sheet to the South) during the last glacial and thus probably responded to the MIS3 pulsed climatic changes. We conducted a multi-proxy analysis of core MD99-2281, including magnetic properties, x-ray fluorescence measurements, characterisation of the coarse (>150 μm) lithic fraction (grain concentration) and the analysis of selected biogenic proxies (assemblages and stable isotope ratio of calcareous planktonic foraminifera, dinoflagellate cyst - e.g. dinocyst - assemblages). Results presented here are focussed on the dinocyst response, this proxy providing the reconstruction of past sea-surface hydrological conditions, qualitatively as well as quantitatively (e.g. transfer function sensu lato). Our study documents a very coherent and sensitive oceanic response to the MIS3 rapid climatic variability: strong fluctuations, matching those of stadial/interstadial climatic oscillations as depicted by Greenland ice cores, are recorded in the MD99-2281 archive. Proxies of terrigeneous and detritical material suggest increases in continental advection during Greenland Stadials (including Heinrich events), the latter corresponding also to southward migrations of polar waters. At the opposite, milder sea-surface conditions seem to develop during Greenland Interstadials. After 30 ka, reconstructed paleohydrological conditions evidence strong shifts in SST: this increasing variability seems consistent with the hypothesised coalescence of the British and Fennoscandian ice sheets at that time, which could have directly influenced sea-surface environments in the vicinity of core MD99-2281.

An Ocean - ice coupled response during the last glacial: zooming on the marine isotopic stage 3 south of the Faeroe Shetland Gateway

NASA Astrophysics Data System (ADS)

Zumaque, J.; Eynaud, F.; Zaragosi, S.; Marret, F.; Matsuzaki, K. M.; Kissel, C.; Roche, D. M.; Malaizé, B.; Michel, E.; Billy, I.; Richter, T.; Palis, E.

2012-08-01

The rapid climatic variability characterising the Marine Isotopic Stage (MIS) 3 (~ 60-30 CAL-ka BP) provides key issues to understand the atmosphere-ocean-cryosphere dynamics. Here we investigate the response of sea-surface paleoenvironments to the MIS3 climatic variability through the study of a high resolution oceanic sedimentological archive (core MD99-2281, 60°21' N; 09°27' W; 1197 m water depth), retrieved during the MD114-IMAGES (International Marine Global Change Study) cruise from the Southern part of the Faeroe Bank. This sector was under the proximal influence of European Ice Sheets (Fennoscandian Ice Sheet to the East, British Irish Ice Sheet to the South) and thus probably recorded their response to the MIS3 pulsed climatic changes. We conducted a multi-proxy analysis on core MD99-2281, including magnetic properties, X-Ray Fluorescence measurements, characterisation of the coarse (> 150 μm) lithic fraction (grain concentration) and the analysis of selected biogenic proxies (assemblages and stable isotope ratio of calcareous planktonic foraminifera, dinoflagellate cyst - e.g. dinocyst - assemblages). Results presented here are focussed on the dinocyst response, this proxy providing the reconstruction of past sea-surface hydrological conditions, qualitatively as well as quantitatively (e.g. transfer function sensu lato). Our study documents a very coherent and sensitive oceanic response to the MIS3 rapid climatic variability: strong fluctuations, matching those of stadial/interstadial climatic oscillations as depicted by Greenland Ice Cores, are recorded in the MD99-2281 archive. Proxies of terrigeneous and detritical material typify increases in continental advection during Greenland Stadials (including Heinrich events), the latter corresponding also to southward migrations of polar waters. At the opposite, milder sea-surface conditions seem to develop during Greenland Interstadials. After 30 ka, reconstructed paleohydrological conditions evidence strong shifts in SST: this increasing variability seems consistent with the hypothesised coalescence of the British and Fennoscandian ice sheets at that time, which could have directly influenced sea-surface environments in the vicinity of core MD99-2281.

An Optical Dye Method for Continuous Determination of Acidity in Ice Cores.

PubMed

Kjær, Helle Astrid; Vallelonga, Paul; Svensson, Anders; Elleskov L Kristensen, Magnus; Tibuleac, Catalin; Winstrup, Mai; Kipfstuhl, Sepp

2016-10-04

The pH of polar ice is important for the stability and mobility of impurities in ice cores and can be strongly influenced by volcanic eruptions or anthropogenic emissions. We present a simple optical method for continuous determination of acidity in ice cores based on spectroscopically determined color changes of two common pH-indicator dyes, bromophenol blue, and chlorophenol red. The sealed-system method described here is not equilibrated with CO 2 , making it simpler than existing methods for pH determination in ice cores and offering a 10-90% peak response time of 45 s and a combined uncertainty of 9%. The method is applied to Holocene ice core sections from Greenland and Antarctica and compared to standard techniques such as electrical conductivity measurement (ECM) conducted on the solid ice, and electrolytic meltwater conductivity, EMWC. Acidity measured in the Greenland NGRIP ice core shows good agreement with acidity calculated from ion chromatography. Conductivity and dye-based acidity H dye + are found to be highly correlated in the Greenland NEGIS firn core (75.38° N, 35.56° W), with all signals greater than 3σ variability coinciding with either volcanic eruptions or possible wild fire activity. In contrast, the Antarctic Roosevelt Island ice core (79.36° S, 161.71° W) features an anticorrelation between conductivity and H dye + , likely due to strong influence of marine salts.

Nitrate flux on the Ross Ice Shelf, Antarctica and its relation to solar cosmic rays

NASA Astrophysics Data System (ADS)

Zeller, Edward J.; Dreschhoff, Gisela A. M.; Laird, Claude M.

1986-11-01

Nitrate flux has been determined in the snow sequence deposited at Windless Bight on the Ross Ice Shelf (Antarctica). The data were obtained from on-site analysis of nitrate concentrations from a glaciological pit and a firn core spanning the time interval from midwinter 1971 to January 1986. The high resolution data can be combined with precipitation records collected from adjacent areas to provide a record of nitrate flow. The resulting time series contains a signal which corresponds to the two major solar events of 1972 and 1984. The concentration and flux profiles may be useful in studies of Antarctic ozone depletion.

Surface studies of water isotopes in Antarctica for quantitative interpretation of deep ice core data

NASA Astrophysics Data System (ADS)

Landais, Amaelle; Casado, Mathieu; Prié, Frédéric; Magand, Olivier; Arnaud, Laurent; Ekaykin, Alexey; Petit, Jean-Robert; Picard, Ghislain; Fily, Michel; Minster, Bénédicte; Touzeau, Alexandra; Goursaud, Sentia; Masson-Delmotte, Valérie; Jouzel, Jean; Orsi, Anaïs

2017-07-01

Polar ice cores are unique climate archives. Indeed, most of them have a continuous stratigraphy and present high temporal resolution of many climate variables in a single archive. While water isotopic records (δD or δ18O) in ice cores are often taken as references for past atmospheric temperature variations, their relationship to temperature is associated with a large uncertainty. Several reasons are invoked to explain the limitation of such an approach; in particular, post-deposition effects are important in East Antarctica because of the low accumulation rates. The strong influence of post-deposition processes highlights the need for surface polar research programs in addition to deep drilling programs. We present here new results on water isotopes from several recent surface programs, mostly over East Antarctica. Together with previously published data, the new data presented in this study have several implications for the climatic reconstructions based on ice core isotopic data: (1) The spatial relationship between surface mean temperature and mean snow isotopic composition over the first meters in depth can be explained quite straightforwardly using simple isotopic models tuned to d-excess vs. δ18O evolution in transects on the East Antarctic sector. The observed spatial slopes are significantly higher (∼ 0.7-0.8‰·°C-1 for δ18O vs. temperature) than seasonal slopes inferred from precipitation data at Vostok and Dome C (0.35 to 0.46‰·°C-1). We explain these differences by changes in condensation versus surface temperature between summer and winter in the central East Antarctic plateau, where the inversion layer vanishes in summer. (2) Post-deposition effects linked to exchanges between the snow surface and the atmospheric water vapor lead to an evolution of δ18O in the surface snow, even in the absence of any precipitation event. This evolution preserves the positive correlation between the δ18O of snow and surface temperature, but is associated with a much slower δ18O-vs-temperature slope than the slope observed in the seasonal precipitation. (3) Post-deposition effects clearly limit the archiving of high-resolution (seasonal) climatic variability in the polar snow, but we suggest that sites with an accumulation rate of the order of 40 kg.m-2.yr-1 may record a seasonal cycle at shallow depths.

Biomarker-based reconstruction of late Holocene sea-ice variability: East versus West Greenland continental shelf.

NASA Astrophysics Data System (ADS)

Kolling, H. M.; Stein, R. H.; Fahl, K.

2016-12-01

Sea is a critical component of the climate system and its role is not yet fully understood e.g. the recent rapid decrease in sea ice is not clearly reflected in climate models. This illustrates the need for high-resolution proxy-based sea-ice reconstructions going beyond the time scale of direct measurements in order to understand the processes controlling present and past natural variability of sea ice on short time scales. Here we present the first comparison of two high-resolution biomarker records from the East and West Greenland Shelf for the late Holocene. Both areas are highly sensitive to sea-ice changes as they are influenced by the East Greenland Current, the main exporter of Arctic freshwater and sea ice. On the East Greenland Shelf, we do not find any clear evidence for a long-term increase of sea ice during the late Holocene Neoglacial. This sea-ice record seems to be more sensitive to short-term climate events, such as the Roman Warm Period, the Dark Ages, the Medieval Warm Period and the Little Ice Age. In contrary, the West Greenland Shelf record shows a strong and gradual increase in sea ice concentration and a reduction in marine productivity markers starting near 1.6 ka. In general, the increase in sea ice seems to follow the decreasing solar insolation trend. Short-term events are not as clearly pronounced as on the East Greenland Shelf. A comparison to recently published foraminiferal records from the same cores (Perner et al., 2011, 2015) illuminates the differences of biomarker and micropaleontoligical proxies. It seems that the general trend is reflected in both proxies but the signal of small-scale events is preserved rather differently, pointing towards different environmental requirements of the species behind both proxies. References: Perner, K., et al., 2011. Quat. Sci. Revs. 30, 2815-2826 Perner, K., et al., 2015. Quat. Sci. Revs. 129, 296-307

Ice Core Records of Recent Northwest Greenland Climate

NASA Astrophysics Data System (ADS)

Osterberg, E. C.; Wong, G. J.; Ferris, D.; Lutz, E.; Howley, J. A.; Kelly, M. A.; Axford, Y.; Hawley, R. L.

2014-12-01

Meteorological station data from NW Greenland indicate a 3oC temperature rise since 1990, with most of the warming occurring in fall and winter. According to remote sensing data, the NW Greenland ice sheet (GIS) and coastal ice caps are responding with ice mass loss and margin retreat, but the cryosphere's response to previous climate variability is poorly constrained in this region. We are developing multi-proxy records (lake sediment cores, ice cores, glacial geologic data, glaciological models) of Holocene climate change and cryospheric response in NW Greenland to improve projections of future ice loss and sea level rise in a warming climate. As part of our efforts to develop a millennial-length ice core paleoclimate record from the Thule region, we collected and analyzed snow pit samples and short firn cores (up to 21 m) from the coastal region of the GIS (2Barrel site; 76.9317o N, 63.1467o W, 1685 m el.) and the summit of North Ice Cap (76.938o N, 67.671o W, 1273 m el.) in 2011, 2012 and 2014. The 2Barrel ice core record has statistically significant relationships with regional spring and fall Baffin Bay sea ice extent, summertime temperature, and annual precipitation. Here we evaluate relationships between the 2014 North Ice Cap firn core glaciochemical record and climate variability from regional instrumental stations and reanalysis datasets. We compare the coastal North Ice Cap record to more inland records from 2Barrel, Camp Century and NEEM to evaluate spatial and elevational gradients in recent NW Greenland climate change.

Paleoclimatic significance of insoluble microparticle records from Canadian Arctic and Greenland ice cores

NASA Astrophysics Data System (ADS)

Zdanowicz, Christian Michel

1999-10-01

The past and present variability of climate in the Arctic region is investigated using ice core records of atmospheric dust (microparticles) and volcanic aerosols developed from the Canadian Arctic and Greenland. A high- resolution, 10 4-year long proxy record of atmospheric dust deposition is developed from an ice core (P95) drilled through the Penny Ice Cap, Baffin Island. Snowpit studies indicate that dust deposited on the Penny Ice Cap are representative of background mineral aerosol, and demonstrate that the variability of dust fallout is preserved in the P95 core at multi-annual to longer time scales. The P95 dust record reveals a significant increase in dust deposition on the Penny Ice Cap between ca 7500-5000 yr ago. This increase was driven by early to mid-/late Holocene transformations in the Northern Hemisphere landscape (ice cover retreat, postglacial land emergence) and climate (transition to colder, drier conditions) that led to an expansion of sources and enhanced eolian activity. Comparison between dust records in the P95 and GISP2 (Greenland) ice cores shows an increasing divergence between the two records beginning ca 7500 years ago. The effects of Northern Hemisphere atmospheric circulation and snow cover extent on atmospheric dust deposition in the Arctic are evaluated by comparing the P95 dust record with observational data. Changes in dust deposition are strongly linked to modes of the Northern Hemisphere winter circulation. Most prominently, an inverse relationship between the P95 dust record and the intensity of the winter Siberian High accounts for over 50% of the interannual variance of these two parameters over the period 1899-1995. On inter- to multi- annual time scales, the P95 dust record is significantly anticorrelated with variations in spring, and to a lesser extent fall, snow cover extent in the mid-latitude interior regions of Eurasia and North America. These relationships account for an estimated 10 to 20% of variance in the P95 dust record. An empirical orthogonal function (EOF) analysis is used to investigate patterns of temporal covariance among insoluble microparticles and major ions deposited in the GISP2 and P95 ice cores. Dust and major ions covary strongly in the GISP2 late glacial record but are uncorrelated in both the GISP2 and P95 Holocene records. Companion EOF analyses of the Holocene records identify distinctive covariance patterns among microparticles and/or major ions that are associated with certain aerosols types or with source-specific air masses reaching the Arctic, providing further evidence of increased regional-scale climatic and atmospheric variability over the last ~ 12,000 years. The atmospheric and climatic impact of the early Holocene eruption of Mount Mazama (Crater Lake, Oregon) is evaluated from the GISP2 ice core record of volcanically- derived sulfate and ash particles. The calendrical age of the eruption is determined to be 7627 +/- 150 cal yr B.P. The GISP2 sulfate record suggests a total stratospheric aerosol loading between 88 and 224 Mt spread over a ~ 6-year period following the eruption. From these figures, the Mount Mazama eruption is estimated to have depressed temperature by ~ 0.6 to 0.7°C at mid- to high northern latitudes. (Abstract shortened by UMI.)

Age, origin and evolution of Antarctic debris-covered glaciers: Implications for landscape evolution and long-term climate change

NASA Astrophysics Data System (ADS)

Mackay, Sean Leland

Antarctic debris-covered glaciers are potential archives of long-term climate change. However, the geomorphic response of these systems to climate forcing is not well understood. To address this concern, I conducted a series of field-based and numerical modeling studies in the McMurdo Dry Valleys of Antarctica (MDV), with a focus on Mullins and Friedman glaciers. I used data and results from geophysical surveys, ice-core collection and analysis, geomorphic mapping, micro-meteorological stations, and numerical-process models to (1) determine the precise origin and distribution of englacial and supraglacial debris within these buried-ice systems, (2) quantify the fundamental processes and feedbacks that govern interactions among englacial and supraglacial debris, (3) establish a process-based model to quantify the inventory of cosmogenic nuclides within englacial and supraglacial debris, and (4) isolate the governing relationships between the evolution of englacial /supraglacial debris and regional climate forcing. Results from 93 field excavations, 21 ice cores, and 24 km of ground-penetrating radar data show that Mullins and Friedman glaciers contain vast areas of clean glacier ice interspersed with inclined layers of concentrated debris. The similarity in the pattern of englacial debris bands across both glaciers, along with model results that call for negligible basal entrainment, is best explained by episodic environmental change at valley headwalls. To constrain better the timing of debris-band formation, I developed a modeling framework that tracks the accumulation of cosmogenic 3He in englacial and supraglacial debris. Results imply that ice within Mullins Glacier increases in age non-linearly from 12 ka to ˜220 ka in areas of active flow (up to >> 1.6 Ma in areas of slow-moving-to-stagnant ice) and that englacial debris bands originate with a periodicity of ˜41 ka. Modeling studies suggest that debris bands originate in synchronicity with changes in obliquity-paced, total integrated summer insolation. The implication is that the englacial structure and surface morphology of some cold-based, debris-covered glaciers can preserve high-resolution climate archives that exceed the typical resolution of Antarctic terrestrial deposits and moraine records.

Late Quaternary paleoceanographic changes in the southwestern Okhotsk Sea: Evidence from geochemical, radiolarian, and diatom records

NASA Astrophysics Data System (ADS)

Okazaki, Yusuke; Takahashi, Kozo; Katsuki, Kota; Ono, Ayumu; Hori, Joichi; Sakamoto, Tatsuhiko; Uchida, Masao; Shibata, Yasuyuki; Ikehara, Minoru; Aoki, Kaori

2005-08-01

High-resolution analyses of geochemical parameters (biogenic opal, calcium carbonate, organic carbon, and nitrogen) and microfossil assemblages (diatoms and radiolarians) on Core MD01-2412 clarified detailed paleoceanographic changes such as sea-ice cover and biological production in the southwestern Okhotsk Sea during the last 115 kyr. An age model of Core MD01-2412 was established based on δ 18O stratigraphy, accelerator mass spectrometer (AMS) 14C, and tephrochronology. Sea-ice history reconstructed by siliceous microplankton records indicated that the present sea-ice condition was formed during the last 8 kyr. Only during Marine Isotope Stage (MIS) 2 was the duration of sea-ice cover in this region much longer than that of today (4-5 months a year). Two diatom species, Thalassionema nitzschioides and Fragilariopsis doliolus, revealed that the Soya Warm Current Water (SWCW) flowed into the Okhotsk Sea near the site of Core MD01-2412 during the last 12-14 kyr and during MIS 5a, and was associated with sea-level rise. Biological productivity rapidly increased during MIS 1, associated with sea-ice retreat. Two major increases of organic carbon (OC) contents (wt%) and C org/N ratios were observed, and the timings of these events were 15.8-16.7 ka (Event 1) and 13.1-13.6 ka (Event 2). Corresponding to these events, the abundance of Cycladophora davisiana, an intermediate water dwelling radiolarian species, increased. This high C. davisiana abundance can be correlated to the input of terrestrial organic matter from the submerged shelf to the intermediate water. Apart from the radiolarians, the production of diatoms in the surface waters was suppressed by the development of well-stratified surface water along with sea-ice melting during the early Holocene. Diatom production increased gradually during the last 10 kyr with enhanced vertical mixing.

High-resolution continuous-flow analysis setup for water isotopic measurement from ice cores using laser spectroscopy

NASA Astrophysics Data System (ADS)

Emanuelsson, B. D.; Baisden, W. T.; Bertler, N. A. N.; Keller, E. D.; Gkinis, V.

2015-07-01

Here we present an experimental setup for water stable isotope (δ18O and δD) continuous-flow measurements and provide metrics defining the performance of the setup during a major ice core measurement campaign (Roosevelt Island Climate Evolution; RICE). We also use the metrics to compare alternate systems. Our setup is the first continuous-flow laser spectroscopy system that is using off-axis integrated cavity output spectroscopy (OA-ICOS; analyzer manufactured by Los Gatos Research, LGR) in combination with an evaporation unit to continuously analyze water samples from an ice core. A Water Vapor Isotope Standard Source (WVISS) calibration unit, manufactured by LGR, was modified to (1) enable measurements on several water standards, (2) increase the temporal resolution by reducing the response time and (3) reduce the influence from memory effects. While this setup was designed for the continuous-flow analysis (CFA) of ice cores, it can also continuously analyze other liquid or vapor sources. The custom setups provide a shorter response time (~ 54 and 18 s for 2013 and 2014 setup, respectively) compared to the original WVISS unit (~ 62 s), which is an improvement in measurement resolution. Another improvement compared to the original WVISS is that the custom setups have a reduced memory effect. Stability tests comparing the custom and WVISS setups were performed and Allan deviations (σAllan) were calculated to determine precision at different averaging times. For the custom 2013 setup the precision after integration times of 103 s is 0.060 and 0.070 ‰ for δ18O and δD, respectively. The corresponding σAllan values for the custom 2014 setup are 0.030, 0.060 and 0.043 ‰ for δ18O, δD and δ17O, respectively. For the WVISS setup the precision is 0.035, 0.070 and 0.042 ‰ after 103 s for δ18O, δD and δ17O, respectively. Both the custom setups and WVISS setup are influenced by instrumental drift with δ18O being more drift sensitive than δD. The σAllan values for δ18O are 0.30 and 0.18 ‰ for the custom 2013 and WVISS setup, respectively, after averaging times of 104 s (2.78 h). Using response time tests and stability tests, we show that the custom setups are more responsive (shorter response time), whereas the University of Copenhagen (UC) setup is more stable. More broadly, comparisons of different setups address the challenge of integrating vaporizer/spectrometer isotope measurement systems into a CFA campaign with many other analytical instruments.

Initial Continuous Chemistry Results From The Roosevelt Island Ice Core (RICE)

NASA Astrophysics Data System (ADS)

Kjær, H. A.; Vallelonga, P. T.; Simonsen, M. F.; Neff, P. D.; Bertler, N. A. N.; Svensson, A.; Dahl-Jensen, D.

2014-12-01

The Roosevelt Island ice core (79.36° S, -161.71° W) was drilled in 2011-13 at the top of the Roosevelt Island ice dome, a location surrounded by the Ross ice shelf. The RICE ice core provides a unique opportunity to look into the past evolution of the West Antarctic Ice sheet. Further the site has high accumulation; 0.26 m of ice equivalent is deposited annually allowing annual layer determination for many chemical parameters. The RICE core was drilled to bedrock and has a total length of 763 metres. Preliminary results derived from water isotopes suggest that the oldest ice reaches back to the Eemian, with the last glacial being compressed in the bottom 60 metres. We present preliminary results from the RICE ice core including continuous measurements of acidity using an optical dye method, insoluble dust particles, conductivity and calcium. The core was analyzed at the New Zealand National Ice Core Research Facility at GNS Science in Wellington. The analytical set up used to determine climate proxies in the ice core was a modified version of the Copenhagen CFA system (Bigler et al., 2011). Key volcanic layers have been matched to those from the WAIS record (Sigl et al., 2013). A significant anti-correlation between acidity and calcium was seen in the Holocene part of the record. Due to the proximity to the ocean a large fraction of the calcium originates from sea salt and is in phase with total conductivity and sodium. In combination with the insoluble dust record, calcium has been apportioned into ocean-related and dust-related sources. Variability over the Holocene is presented and attributed to changing inputs of marine and dust aerosols.

Holocene history of drift ice in the northern North Atlantic: Evidence for different spatial and temporal modes

USGS Publications Warehouse

Moros, M.; Andrews, John T.; Eberl, D.D.; Jansen, E.

2006-01-01

We present new high-resolution proxy data for the Holocene history of drift ice off Iceland based on the mineralogy of the <2-mm sediment fraction using quantitative X-ray diffraction. These new data, bolstered by a comparison with published proxy records, point to a long-term increasing trend in drift ice input into the North Atlantic from 6 to 5 ka toward the present day at sites influenced by the cold east Greenland Current. This feature reflects the late Holocene Neoglacial or cooling period recorded in ice cores and further terrestrial archives on Greenland. In contrast, a decrease in drift ice during the same period is recorded at sites underlying the North Atlantic Drift, which may reflect a warming of this region. The results document that Holocene changes in iceberg rafting and sea ice advection did not occur uniformly across the North Atlantic. Centennial-scale climate variability in the North Atlantic region over the last ???4 kyr is linked to the observed changes in drift ice input. Increased drift ice may have played a role in the increase of cold intervals during the late Holocene, e.g., the Little Ice Age cooling. Copyright 2006 by the American Geophysical Union.

Orbitally resolved records of Oligocene ice-sheet dynamics and deep-water chemistry from ODP Site 689 (Maud Rise, Weddell Sea)

NASA Astrophysics Data System (ADS)

Bohaty, Steven M.; Huck, Claire E.; Liebrand, Diederik; Röhl, Ursula; Wilson, Paul; van de Flierdt, Tina; Pälike, Heiko

2016-04-01

The early stages of the modern 'Icehouse' climate state first developed in the Oligocene following rapid global cooling and the onset of Antarctic glaciation at the Eocene-Oligocene Transition (34 Ma). However, the size and stability of the early Antarctic ice sheets that existed during the Oligocene under atmospheric CO2 levels higher than present day are poorly known. Here we report on an ongoing investigation of Oligocene (hemi)pelagic drillcores recovered at Ocean Drilling Program (ODP) Site 689, drilled on Maud Rise in the eastern Weddell Sea in late 1980s (Leg 113). Shipboard physical properties data were not routinely collected from pre-Quaternary cores at this site, and the lack of continuous composite sections and supporting data has previously been a considerable hindrance to high-resolution paleoceanographic studies. New high-resolution XRF scanning, discrete magnetic susceptibility, and benthic foraminiferal stable isotope records were collected from the upper Eocene-upper Oligocene interval of ODP Sites 689. The XRF datasets allow compositing of Holes 689B and 689D, which fortuitously contain offset cores throughout the sequence. Although condensed in two intervals, Site 689 contains a complete ~12-Myr record spanning Chron C17n.1n to Chron C8n.1n (~37 to 25 Ma). The composited records from Sites 689 exhibit prominent orbital-scale cyclicity in XRF-derived iron/calcium ratios, enabling development of an astronomical age model and detailed reconstruction of carbonate dissolution intensity of South Atlantic deep waters. These composited and well-dated records from Site 689 will, for the first-time, provide an Oligocene pelagic reference section for the Southern Ocean and serve as stratigraphic stepping stone between proximal Antarctic shelf records and high-resolution proxy records from lower latitude locations. Further development of high-resolution benthic foraminiferal and detrital neodymium isotope records at Site 689 will address the timing and frequency of East Antarctic ice-sheet advance and retreat events during cool intervals of the mid Oligocene and the onset of warming in the latest Oligocene. These data will both inform and test model results of ice-sheet behaviour and stability during different climatic phases of the Oligocene.

Atmospheric CO2 variations on millennial-scale during MIS 6

NASA Astrophysics Data System (ADS)

Shin, Jinhwa; Grilli, Roberto; Chappellaz, Jérôme; Teste, Grégory; Nehrbass-Ahles, Christoph; Schmidely, Loïc; Schmitt, Jochen; Stocker, Thomas; Fischer, Hubertus

2017-04-01

Understanding natural carbon cycle / climate feedbacks on various time scales is highly important for predicting future climate changes. Paleoclimate records of Antarctic temperatures, relative sea level and foraminiferal isotope and pollen records in sediment cores from the Portuguese margin have shown climate variations on millennial time scale over the Marine Isotope Stage 6 (MIS 6; from approximately 135 to 190 kyr BP). These proxy data suggested iceberg calving in the North Atlantic result in cooling in the Northern hemisphere and warming in Antarctica by changes in the Atlantic Meridional Overturning Circulation, which is explained by a bipolar see-saw trend in the ocean (Margari et al., 2010). Atmospheric CO2 reconstruction from Antarctic ice cores can provide key information on how atmospheric CO2 concentrations are linked to millennial-scale climate changes. However, existing CO2 records cannot be used to address this relationship because of the lack of suitable temporal resolution. In this work, we will present a new CO2 record with an improved time resolution, obtained from the Dome C ice core (75˚ 06'S, 123˚ 24'E) spanning the MIS 6 period, using dry extraction methods. We will examine millennial-scale features in atmospheric CO2, and their possible links with other proxies covering MIS 6. Margari, V., Skinner, L. C., Tzedakis, P. C., Ganopolski, A., Vautravers, M., and Shackleton, N. J.: The nature of millennial scale climate variability during the past two glacial periods, Nat.Geosci., 3, 127-131, 2010.

Visual-Stratigraphic Dating of the GISP2 Ice Core: Basis, Reproducibility, and Application

NASA Technical Reports Server (NTRS)

Alley, R. B.; Shuman, C. A.; Meese, D. A.; Gow, A. J.; Taylor, K. C.; Cuffey, K. M.; Fitzpatrick, J. J.; Grootes, P. M.; Zielinski, G. A.; Ram, M.;

Visual-stratigraphic dating of the GISP2 ice core: Basis, reproducibility, and application

NASA Astrophysics Data System (ADS)

Alley, R. B.; Shuman, C. A.; Meese, D. A.; Gow, A. J.; Taylor, K. C.; Cuffey, K. M.; Fitzpatrick, J. J.; Grootes, P. M.; Zielinski, G. A.; Ram, M.; Spinelli, G.; Elder, B.

1997-11-01

Annual layers are visible in the Greenland Ice Sheet Project 2 ice core from central Greenland, allowing rapid dating of the core. Changes in bubble and grain structure caused by near-surface, primarily summertime formation of hoar complexes provide the main visible annual marker in the Holocene, and changes in "cloudiness" of the ice correlated with dustiness mark Wisconsinan annual cycles; both markers are evident and have been intercalibrated in early Holocene ice. Layer counts are reproducible between different workers and for one worker at different times, with 1% error over century-length times in the Holocene. Reproducibility is typically 5% in Wisconsinan ice-age ice and decreases with increasing age and depth. Cumulative ages from visible stratigraphy are not significantly different from independent ages of prominent events for ice older than the historical record and younger than approximately 50,000 years. Visible observations are not greatly degraded by "brittle ice" or many other core-quality problems, allowing construction of long, consistently sampled time series. High accuracy requires careful study of the core by dedicated observers.

The design and performance of IceCube DeepCore

NASA Astrophysics Data System (ADS)

Abbasi, R.; Abdou, Y.; Abu-Zayyad, T.; Ackermann, M.; Adams, J.; Aguilar, J. A.; Ahlers, M.; Allen, M. M.; Altmann, D.; Andeen, K.; Auffenberg, J.; Bai, X.; Baker, M.; Barwick, S. W.; Bay, R.; Bazo Alba, J. L.; Beattie, K.; Beatty, J. J.; Bechet, S.; Becker, J. K.; Becker, K.-H.; Benabderrahmane, M. L.; BenZvi, S.; Berdermann, J.; Berghaus, P.; Berley, D.; Bernardini, E.; Bertrand, D.; Besson, D. Z.; Bindig, D.; Bissok, M.; Blaufuss, E.; Blumenthal, J.; Boersma, D. J.; Bohm, C.; Bose, D.; Böser, S.; Botner, O.; Brown, A. M.; Buitink, S.; Caballero-Mora, K. S.; Carson, M.; Chirkin, D.; Christy, B.; Clevermann, F.; Cohen, S.; Colnard, C.; Cowen, D. F.; Cruz Silva, A. H.; D'Agostino, M. V.; Danninger, M.; Daughhetee, J.; Davis, J. C.; De Clercq, C.; Degner, T.; Demirörs, L.; Descamps, F.; Desiati, P.; de Vries-Uiterweerd, G.; DeYoung, T.; Díaz-Vélez, J. C.; Dierckxsens, M.; Dreyer, J.; Dumm, J. P.; Dunkman, M.; Eisch, J.; Ellsworth, R. W.; Engdegård, O.; Euler, S.; Evenson, P. A.; Fadiran, O.; Fazely, A. R.; Fedynitch, A.; Feintzeig, J.; Feusels, T.; Filimonov, K.; Finley, C.; Fischer-Wasels, T.; Fox, B. D.; Franckowiak, A.; Franke, R.; Gaisser, T. K.; Gallagher, J.; Gerhardt, L.; Gladstone, L.; Glüsenkamp, T.; Goldschmidt, A.; Goodman, J. A.; Góra, D.; Grant, D.; Griesel, T.; Groß, A.; Grullon, S.; Gurtner, M.; Ha, C.; Haj Ismail, A.; Hallgren, A.; Halzen, F.; Han, K.; Hanson, K.; Heinen, D.; Helbing, K.; Hellauer, R.; Hickford, S.; Hill, G. C.; Hoffman, K. D.; Hoffmann, B.; Homeier, A.; Hoshina, K.; Huelsnitz, W.; Hülß, J.-P.; Hulth, P. O.; Hultqvist, K.; Hussain, S.; Ishihara, A.; Jacobi, E.; Jacobsen, J.; Japaridze, G. S.; Johansson, H.; Kampert, K.-H.; Kappes, A.; Karg, T.; Karle, A.; Kenny, P.; Kiryluk, J.; Kislat, F.; Klein, S. R.; Köhne, J.-H.; Kohnen, G.; Kolanoski, H.; Köpke, L.; Koskinen, D. J.; Kowalski, M.; Kowarik, T.; Krasberg, M.; Kroll, G.; Kurahashi, N.; Kuwabara, T.; Labare, M.; Laihem, K.; Landsman, H.; Larson, M. J.; Lauer, R.; Lünemann, J.; Madsen, J.; Marotta, A.; Maruyama, R.; Mase, K.; Matis, H. S.; Meagher, K.; Merck, M.; Mészáros, P.; Meures, T.; Miarecki, S.; Middell, E.; Milke, N.; Miller, J.; Montaruli, T.; Morse, R.; Movit, S. M.; Nahnhauer, R.; Nam, J. W.; Naumann, U.; Nygren, D. R.; Odrowski, S.; Olivas, A.; Olivo, M.; O'Murchadha, A.; Panknin, S.; Paul, L.; Pérez de los Heros, C.; Petrovic, J.; Piegsa, A.; Pieloth, D.; Porrata, R.; Posselt, J.; Price, P. B.; Przybylski, G. T.; Rawlins, K.; Redl, P.; Resconi, E.; Rhode, W.; Ribordy, M.; Richman, M.; Rodrigues, J. P.; Rothmaier, F.; Rott, C.; Ruhe, T.; Rutledge, D.; Ruzybayev, B.; Ryckbosch, D.; Sander, H.-G.; Santander, M.; Sarkar, S.; Schatto, K.; Schmidt, T.; Schönwald, A.; Schukraft, A.; Schultes, A.; Schulz, O.; Schunck, M.; Seckel, D.; Semburg, B.; Seo, S. H.; Sestayo, Y.; Seunarine, S.; Silvestri, A.; Spiczak, G. M.; Spiering, C.; Stamatikos, M.; Stanev, T.; Stezelberger, T.; Stokstad, R. G.; Stößl, A.; Strahler, E. A.; Ström, R.; Stüer, M.; Sullivan, G. W.; Swillens, Q.; Taavola, H.; Taboada, I.; Tamburro, A.; Tepe, A.; Ter-Antonyan, S.; Tilav, S.; Toale, P. A.; Toscano, S.; Tosi, D.; van Eijndhoven, N.; Vandenbroucke, J.; Van Overloop, A.; van Santen, J.; Vehring, M.; Voge, M.; Walck, C.; Waldenmaier, T.; Wallraff, M.; Walter, M.; Weaver, Ch.; Wendt, C.; Westerhoff, S.; Whitehorn, N.; Wiebe, K.; Wiebusch, C. H.; Williams, D. R.; Wischnewski, R.; Wissing, H.; Wolf, M.; Wood, T. R.; Woschnagg, K.; Xu, C.; Xu, D. L.; Xu, X. W.; Yanez, J. P.; Yodh, G.; Yoshida, S.; Zarzhitsky, P.; Zoll, M.

2012-05-01

The IceCube neutrino observatory in operation at the South Pole, Antarctica, comprises three distinct components: a large buried array for ultrahigh energy neutrino detection, a surface air shower array, and a new buried component called DeepCore. DeepCore was designed to lower the IceCube neutrino energy threshold by over an order of magnitude, to energies as low as about 10 GeV. DeepCore is situated primarily 2100 m below the surface of the icecap at the South Pole, at the bottom center of the existing IceCube array, and began taking physics data in May 2010. Its location takes advantage of the exceptionally clear ice at those depths and allows it to use the surrounding IceCube detector as a highly efficient active veto against the principal background of downward-going muons produced in cosmic-ray air showers. DeepCore has a module density roughly five times higher than that of the standard IceCube array, and uses photomultiplier tubes with a new photocathode featuring a quantum efficiency about 35% higher than standard IceCube PMTs. Taken together, these features of DeepCore will increase IceCube's sensitivity to neutrinos from WIMP dark matter annihilations, atmospheric neutrino oscillations, galactic supernova neutrinos, and point sources of neutrinos in the northern and southern skies. In this paper we describe the design and initial performance of DeepCore.

The Design and Performance of IceCube DeepCore

NASA Technical Reports Server (NTRS)

Stamatikos, M.

2012-01-01

The IceCube neutrino observatory in operation at the South Pole, Antarctica, comprises three distinct components: a large buried array for ultrahigh energy neutrino detection, a surface air shower array, and a new buried component called DeepCore. DeepCore was designed to lower the IceCube neutrino energy threshold by over an order of magnitude, to energies as low as about 10 GeV. DeepCore is situated primarily 2100 m below the surface of the icecap at the South Pole, at the bottom center of the existing IceCube array, and began taking pbysics data in May 2010. Its location takes advantage of the exceptionally clear ice at those depths and allows it to use the surrounding IceCube detector as a highly efficient active veto against the principal background of downward-going muons produced in cosmic-ray air showers. DeepCore has a module density roughly five times higher than that of the standard IceCube array, and uses photomultiplier tubes with a new photocathode featuring a quantum efficiency about 35% higher than standard IceCube PMTs. Taken together, these features of DeepCore will increase IceCube's sensitivity to neutrinos from WIMP dark matter annihilations, atmospheric neutrino oscillations, galactic supernova neutrinos, and point sources of neutrinos in the northern and southern skies. In this paper we describe the design and initial performance of DeepCore.

Antarctic Circumpolar Current Dynamics and Their Relation to Antarctic Ice Sheet and Perennial Sea-Ice Variability in the Central Drake Passage During the Last Climate Cycle

NASA Astrophysics Data System (ADS)

Kuhn, G.; Wu, S.; Hass, H. C.; Klages, J. P.; Zheng, X.; Arz, H. W.; Esper, O.; Hillenbrand, C. D.; Lange, C.; Lamy, F.; Lohmann, G.; Müller, J.; McCave, I. N. N.; Nürnberg, D.; Roberts, J.; Tiedemann, R.; Timmermann, A.; Titschack, J.; Zhang, X.

2017-12-01

The evolution of the Antarctic Ice Sheet during the last climate cycle and the interrelation to global atmospheric and ocean circulation remains controversial and plays an important role for our understanding of ice sheet response to modern global warming. The timing and sequence of deglacial warming is relevant for understanding the variability and sensitivity of the Antarctic Ice Sheet to climatic changes, and the continuing rise of atmospheric greenhouse gas concentrations. The Antarctic Ice Sheet is a pivotal component of the global water budget. Freshwater fluxes from the ice sheet may affect the Antarctic Circumpolar Current (ACC), which is strongly impacted by the westerly wind belt in the Southern Hemisphere (SHWW) and constricted to its narrowest extent in the Drake Passage. The flow of ACC water masses through Drake Passage is, therefore, crucial for advancing our understanding of the Southern Ocean's role in global meridional overturning circulation and global climate change. In order to address orbital and millennial-scale variability of the Antarctic ice sheet and the ACC, we applied a multi-proxy approach on a sediment core from the central Drake Passage including grain size, iceberg-rafted debris, mineral dust, bulk chemical and mineralogical composition, and physical properties. In combination with already published and new sediment records from the Drake Passage and Scotia Sea, as well as high-resolution data from Antarctic ice cores (WDC, EDML), we now have evidence that during glacial times a more northerly extent of the perennial sea-ice zone decreased ACC current velocities in the central Drake Passage. During deglaciation the SHWW shifted southwards due to a decreasing temperature gradient between subtropical and polar latitudes caused by sea ice and ice sheet decline. This in turn caused Southern Hemisphere warming, a more vigorous ACC, stronger Southern Ocean ventilation, and warm Circumpolar Deep Water (CDW) upwelling on Antarctic shelves resulting in increased ice shelf melting. Stronger upwelling is associated with a rise in atmospheric carbon dioxide to reach a threshold at which full deglaciation could become inevitable.

Recent Increases in Snow Accumulation and Decreases in Sea-Ice Concentration Recorded in a Coastal NW Greenland Ice Core

NASA Astrophysics Data System (ADS)

Osterberg, E. C.; Thompson, J. T.; Wong, G. J.; Hawley, R. L.; Kelly, M. A.; Lutz, E.; Howley, J.; Ferris, D. G.

2013-12-01

A significant rise in summer temperatures over the past several decades has led to widespread retreat of the Greenland Ice Sheet (GIS) margin and surrounding sea ice. Recent observations from geodetic stations and GRACE show that ice mass loss progressed from South Greenland up to Northwest Greenland by 2005 (Khan et al., 2010). Observations from meteorological stations at the U.S. Thule Air Force Base, remote sensing platforms, and climate reanalyses indicate a 3.5C mean annual warming in the Thule region and a 44% decrease in summer (JJAS) sea-ice concentrations in Baffin Bay from 1980-2010. Mean annual precipitation near Thule increased by 12% over this interval, with the majority of the increase occurring in fall (SON). To improve projections of future ice loss and sea-level rise in a warming climate, we are currently developing multi-proxy records (lake sediment cores, ice cores, glacial geologic data, glaciological models) of Holocene climate variability and cryospheric response in NW Greenland, with a focus on past warm periods. As part of our efforts to develop a millennial-length ice core paleoclimate record from the Thule region, we collected and analyzed snow pit samples and short firn cores (up to 20 m) from the coastal region of the GIS (2Barrel site; 76.9317 N, 63.1467 W) and the summit of North Ice Cap (76.938 N, 67.671 W) in 2011 and 2012, respectively. The 2Barrel ice core was sampled using a continuous ice core melting system at Dartmouth, and subsequently analyzed for major anion and trace element concentrations and stable water isotope ratios. Here we show that the 2Barrel ice core spanning 1990-2010 records a 25% increase in mean annual snow accumulation, and is positively correlated (r = 0.52, p<0.01) with ERA-Interim precipitation. The 2Barrel annual sea-salt Na concentration is strongly correlated (r = 0.5-0.8, p<0.05) with summer and fall sea-ice concentrations in northern Baffin Bay near Thule (Figure 1). We hypothesize that the positive correlation represents a significant Na contribution from frost flowers growing on fall frazil ice. Ongoing analyses will evaluate the relationship between MSA concentrations and sea ice extent. Our results show that a deep ice core collected from this dynamic and climate-sensitive region of NW Greenland would produce a valuable record of late Holocene climate and sea ice extent.

Rapid changes in ice core gas records - Part 1: On the accuracy of methane synchronisation of ice cores

NASA Astrophysics Data System (ADS)

Köhler, P.

2010-08-01

Methane synchronisation is a concept to align ice core records during rapid climate changes of the Dansgaard/Oeschger (D/O) events onto a common age scale. However, atmospheric gases are recorded in ice cores with a log-normal-shaped age distribution probability density function, whose exact shape depends mainly on the accumulation rate on the drilling site. This age distribution effectively shifts the mid-transition points of rapid changes in CH4 measured in situ in ice by about 58% of the width of the age distribution with respect to the atmospheric signal. A minimum dating uncertainty, or artefact, in the CH4 synchronisation is therefore embedded in the concept itself, which was not accounted for in previous error estimates. This synchronisation artefact between Greenland and Antarctic ice cores is for GRIP and Byrd less than 40 years, well within the dating uncertainty of CH4, and therefore does not calls the overall concept of the bipolar seesaw into question. However, if the EPICA Dome C ice core is aligned via CH4 to NGRIP this synchronisation artefact is in the most recent unified ice core age scale (Lemieux-Dudon et al., 2010) for LGM climate conditions of the order of three centuries and might need consideration in future gas chronologies.

Spatio-Temporal Variability of Recent Snow Accumulation Across the West Antarctic Ice Sheet Divide Using Ultra-High Frequency Radar and Shallow Firn Cores

NASA Astrophysics Data System (ADS)

Keeler, D. G.; Rupper, S.; Forster, R. R.; Miège, C.; Brewer, S.; Koenig, L.

2017-12-01

The West Antarctic Ice Sheet (WAIS) could be a substantial source of future sea level rise, with 3+ meters of potential increase stored in the ice sheet. Adequate predictions of WAIS contributions, however, depend on well-constrained surface mass balance estimates for the region. Given the sparsity of available data, such estimates are tenuous. Although new data are periodically added, further research (both to collect more data and better utilize existing data) is critical to addressing these issues. Here we present accumulation data from 9 shallow firn cores and 600 km of Ku band radar traces collected as part of the Satellite Era Antarctic Traverse (SEAT) 2011/2012 field season. Using these data, combined with similar data collected during the SEAT 2010/2011 field season, we investigate the spatial variability in accumulation across the WAIS Divide and surrounding regions. We utilize seismic interpretation and 3D visualization tools to investigate the extent and variations of laterally continuous internal horizons in the radar profiles, and compare the results to nearby firn cores. Previous results show that clearly visible, laterally continuous horizons in radar returns in this area do not always represent annual accumulation isochrones, but can instead represent multi-year or sub-annual events. The automated application of Bayesian inference techniques to averaged estimates of multiple adjacent radar traces, however, can estimate annually-resolved independent age-depth scales for these radar data. We use these same automated techniques on firn core isotopic records to infer past snow accumulation rates, allowing a direct comparison with the radar-derived results. Age-depth scales based on manual annual-layer counting of geochemical and isotopic species from these same cores provide validation for the automated approaches. Such techniques could theoretically be applied to additional radar/core data sets in polar regions (e.g. Operation IceBridge), thereby increasing the number of high resolution accumulation records available in these data-sparse regions. An increased understanding of the variability in magnitude and past rates of surface mass balance can provide better constraints on sea level projections and more precise context for present-day and future observations in these regions.

Aerosol deposition (trace elements and black carbon) over the highest glacier of the Eastern European Alps during the last centuries

NASA Astrophysics Data System (ADS)

Bertò, Michele; Barbante, Carlo; Gabrieli, Jacopo; Gabrielli, Paolo; Spolaor, Andrea; Dreossi, Giuliano; Laj, Paolo; Zanatta, Marco; Ginot, Patrick; Fain, Xavier

2016-04-01

Ice cores are an archive of a wide variety of climatic and environmental information from the past, retaining them for hundreds of thousands of years. Anthropogenic pollutants, trace elements, heavy metals and major ions, are preserved as well providing insights on the past atmospheric circulations and allowing evaluating the human impact on the environment. Several ice cores were drilled in glaciers at mid and low latitudes, as in the European Alps. The first ice cores drilled to bedrock in the Eastern Alps were retrieved during autumn 2011 on the "Alto dell`Ortles glacier", the uppermost glacier of the Ortles massif (3905m, South Tirol, Italy), in the frame of the "Ortles Project". A preliminary dating of the core suggests that it should cover at least 300-400 years. Despite the summer temperature increase of the last decades this glacier still contain cold ice. Indeed, O and H isotopes profiles well describe the atmospheric warming as well as the low temperatures recorded during the Little Ice Age (LIA). Moreover, this glacier is located close to densely populated and industrialized areas and can be used for reconstructing for the first time past and recent air pollution and the human impact in the Eastern European Alps. The innermost part of the core is under analysis by means of a "Continuous Flow Analysis" system. This kind of analysis offers a high resolution in data profiles. The separation between the internal and the external parts of the core avoid any kind of contamination. An aluminum melting head melts the core at about 2.5 cm min-1. Simultaneous analyses of conductivity, dust concentration and size distribution (from 0.8 to 80 μm), trace elements with Inductive Coupled Plasma Mass Spectrometer (ICP-MS, Agilent 7500) and refractory black carbon (rBC) with the Single Particle Soot Photometer (SP2, Droplet Measurement Technologies) are performed. A fraction of the melt water is collected by an auto-sampler for further analysis. The analyzed elements are Li, Na, Mg, Al, K, Ca, Ti, V, Mn, Fe, Ni, Cu, Zn, Rb, Ag, Cd, Sb, I, Ba, Pt, Tl, Pb and U. Trace elements concentrations in the Ortles snow are related to the emissions from the Po Valley, one of the most polluted region of Europe. The results show an increase in the concentration of many heavy metals due to anthropogenic emissions, mainly from the onset of the Industrial Revolution. rBC is one of the most important aerosol species affecting the climate system, particularly the glaciers, by modifying the radiative energy balance. A significant increase of rBC was found in the ice identifying this kind of aerosol as a responsible in forcing the end of the LIA.

IceChrono v1: a probabilistic model to compute a common and optimal chronology for several ice cores

NASA Astrophysics Data System (ADS)

Parrenin, Frédéric

2015-04-01

Polar ice cores provide exceptional archives of past environmental conditions. The dating of ice cores is essential to interpret the paleo records that they contain, but it is a complicated problem since it involves different dating methods. Here I present IceChrono v1, a new probabilistic model to combine different kinds of chronological information to obtain a common and optimized chronology for several ice cores, as well as its uncertainty. It is based on the inversion of three quantities: the surface accumulation rate, the Lock-In Depth (LID) of air bubbles and the vertical thinning function. The chronological information used are: models of the sedimentation process (accumulation of snow, densification of snow into ice and air trapping, ice flow), ice and gas dated horizons, ice and gas dated depth intervals, Δdepth observations (depth shift between synchronous events recorded in the ice and in the air), stratigraphic links in between ice cores (ice-ice, air-air or mix ice-air and air-ice links). The optimization problem is formulated as a least squares problems, that is, all densities of probabilities are assumed gaussian. It is numerically solved using the Levenberg-Marquardt algorithm and a numerical evaluation of the model's Jacobian. IceChrono is similar in scope to the Datice model, but has differences from the mathematical, numerical and programming point of views. I apply IceChrono on an AICC2012-like experiment and I find similar results than Datice within a few centuries, which is a confirmation of both IceChrono and Datice codes. IceChrono v1 is freely available under the GPL v3 open source license.

A Tale of Two Forcings: Present-Day Coupled Antarctic Ice-sheet/Southern Ocean dynamics using the POPSICLES model.

NASA Astrophysics Data System (ADS)

Martin, Daniel; Asay-Davis, Xylar; Cornford, Stephen; Price, Stephen; Ng, Esmond; Collins, William

2015-04-01

We present POPSICLES simulation results covering the full Antarctic Ice Sheet and the Southern Ocean spanning the period 1990 to 2010 resulting from two different choices of climate forcing: a 'normal-year' climatology and the CORE v. 2 interannual forcing data (Large and Yeager 2008). Simulations are performed at 0.1o (~5 km) ocean resolution and adaptive ice sheet resolution as fine as 500 m. We compare time-averaged melt rates below a number of major ice shelves with those reported by Rignot et al. (2013) as well as other recent studies. We also present seasonal variability and decadal melting trends from several Antarctic regions, along with the response of the ice shelves and consequent dynamics of the grounded ice sheet. POPSICLES couples the POP2x ocean model, a modified version of the Parallel Ocean Program (Smith and Gent, 2002), and the BISICLES ice-sheet model (Cornford et al., 2012). POP2x includes sub-ice-shelf circulation using partial top cells (Losch, 2008) and boundary layer physics following Holland and Jenkins (1999), Jenkins (2001), and Jenkins et al. (2010). Standalone POP2x output compares well with standard ice-ocean test cases (e.g., ISOMIP; Losch, 2008) and other continental-scale simulations and melt-rate observations (Kimura et al., 2013; Rignot et al., 2013). BISICLES makes use of adaptive mesh refinement and a 1st-order accurate momentum balance similar to the L1L2 model of Schoof and Hindmarsh (2009) to accurately model regions of dynamic complexity, such as ice streams, outlet glaciers, and grounding lines. Results of BISICLES simulations have compared favorably to comparable simulations with a Stokes momentum balance in both idealized tests (MISMIP-3d; Pattyn et al., 2013) and realistic configurations (Favier et al. 2014).

Synchronous volcanic eruptions and abrupt climate change ∼17.7 ka plausibly linked by stratospheric ozone depletion

PubMed Central

McConnell, Joseph R.; Burke, Andrea; Dunbar, Nelia W.; Köhler, Peter; Thomas, Jennie L.; Chellman, Nathan J.; Maselli, Olivia J.; Sigl, Michael; Adkins, Jess F.; Baggenstos, Daniel; Burkhart, John F.; Brook, Edward J.; Buizert, Christo; Cole-Dai, Jihong; Fudge, T. J.; Knorr, Gregor; Graf, Hans-F.; Grieman, Mackenzie M.; Iverson, Nels; McGwire, Kenneth C.; Mulvaney, Robert; Paris, Guillaume; Rhodes, Rachael H.; Saltzman, Eric S.; Steffensen, Jørgen Peder; Taylor, Kendrick C.; Winckler, Gisela

2017-01-01

Glacial-state greenhouse gas concentrations and Southern Hemisphere climate conditions persisted until ∼17.7 ka, when a nearly synchronous acceleration in deglaciation was recorded in paleoclimate proxies in large parts of the Southern Hemisphere, with many changes ascribed to a sudden poleward shift in the Southern Hemisphere westerlies and subsequent climate impacts. We used high-resolution chemical measurements in the West Antarctic Ice Sheet Divide, Byrd, and other ice cores to document a unique, ∼192-y series of halogen-rich volcanic eruptions exactly at the start of accelerated deglaciation, with tephra identifying the nearby Mount Takahe volcano as the source. Extensive fallout from these massive eruptions has been found >2,800 km from Mount Takahe. Sulfur isotope anomalies and marked decreases in ice core bromine consistent with increased surface UV radiation indicate that the eruptions led to stratospheric ozone depletion. Rather than a highly improbable coincidence, circulation and climate changes extending from the Antarctic Peninsula to the subtropics—similar to those associated with modern stratospheric ozone depletion over Antarctica—plausibly link the Mount Takahe eruptions to the onset of accelerated Southern Hemisphere deglaciation ∼17.7 ka. PMID:28874529

Synchronous volcanic eruptions and abrupt climate change ∼17.7 ka plausibly linked by stratospheric ozone depletion.

PubMed

McConnell, Joseph R; Burke, Andrea; Dunbar, Nelia W; Köhler, Peter; Thomas, Jennie L; Arienzo, Monica M; Chellman, Nathan J; Maselli, Olivia J; Sigl, Michael; Adkins, Jess F; Baggenstos, Daniel; Burkhart, John F; Brook, Edward J; Buizert, Christo; Cole-Dai, Jihong; Fudge, T J; Knorr, Gregor; Graf, Hans-F; Grieman, Mackenzie M; Iverson, Nels; McGwire, Kenneth C; Mulvaney, Robert; Paris, Guillaume; Rhodes, Rachael H; Saltzman, Eric S; Severinghaus, Jeffrey P; Steffensen, Jørgen Peder; Taylor, Kendrick C; Winckler, Gisela

2017-09-19

Glacial-state greenhouse gas concentrations and Southern Hemisphere climate conditions persisted until ∼17.7 ka, when a nearly synchronous acceleration in deglaciation was recorded in paleoclimate proxies in large parts of the Southern Hemisphere, with many changes ascribed to a sudden poleward shift in the Southern Hemisphere westerlies and subsequent climate impacts. We used high-resolution chemical measurements in the West Antarctic Ice Sheet Divide, Byrd, and other ice cores to document a unique, ∼192-y series of halogen-rich volcanic eruptions exactly at the start of accelerated deglaciation, with tephra identifying the nearby Mount Takahe volcano as the source. Extensive fallout from these massive eruptions has been found >2,800 km from Mount Takahe. Sulfur isotope anomalies and marked decreases in ice core bromine consistent with increased surface UV radiation indicate that the eruptions led to stratospheric ozone depletion. Rather than a highly improbable coincidence, circulation and climate changes extending from the Antarctic Peninsula to the subtropics-similar to those associated with modern stratospheric ozone depletion over Antarctica-plausibly link the Mount Takahe eruptions to the onset of accelerated Southern Hemisphere deglaciation ∼17.7 ka.

Decoupled evolution of temperature and precipitation in western Germany during the Last Interglacial reconstructed from a precisely dated speleothem

NASA Astrophysics Data System (ADS)

Scholz, Denis; Hoffmann, Dirk; Spötl, Christoph; Hopcroft, Peter; Mangini, Augusto; Richter, Detlef K.

2010-05-01

We present high-resolution stable oxygen and carbon isotope (δ18O and δ13C) as well as trace element profiles for stalagmite HBSH-1 from Hüttenbläserschachthöhle, western Germany. The chronology was established by MC-ICPMS 230Th/U-dating, and the high U-content of the stalagmite allowed determination of very precise 230Th/U-ages although using very small sample sizes. The beginning and end of individual growth phases of the stalagmite could, thus, be determined very accurately. Stalagmite HBSH-1 grew during the penultimate interglacial (MIS 7), the Last Interglacial (MIS 5) and the Holocene. The major part of the sample (40 cm) grew between 130 and 80 ka providing a climate record with decadal to centennial resolution for this period. The record shows three growth interruptions during MIS 5 coinciding with Greenland Stadials 25, 24 and 22, as recorded in the NGRIP ice core (North Greenland Ice Core Project members, 2004). The end of the MIS 5 growth phase coincides with GS 21. This shows that stalagmite growth in this area is a very sensitive proxy for northern hemisphere cooling. Correlation of the absolutely dated stalagmite record with Greenland ice cores may provide a tool to improve the chronology of the Greenland Stadials. The δ18O profile of stalagmite HBSH-1 shows a distinct similarity during MIS 5 with the NGRIP ice core and a sea surface temperature record from the Iberian Margin (Martrat et al., 2007). This suggests that stalagmite δ18O mainly reflects past temperature variability. Stalagmite HBSH-1 consists of aragonite rather than calcite, which is probably a result of pronounced prior calcite precipitation in the epikarst above the cave (Fairchild and Treble, 2009). In this case, the δ13C signal rather reflects changes in past precipitation than temperature. The δ13C record of HBSH-1 shows three pronounced negative peaks during MIS 5, in agreement with the three MIS 5 warm phases, MIS 5e, 5c and 5a. During the Last Interglacial, however, the evolution of δ18O and δ13C, and thus temperature and precipitation, is opposite. Whereas the δ18O signal suggests the warmest temperatures around 125 ka followed by a gradual decrease, the δ13C signal indicates wetter conditions towards the end of the Last Interglacial. The decoupling of temperature and precipitation during this time period is also seen in a series of snapshot simulations performed using a fast coupled ocean-atmosphere general circulation model. This behaviour can be explained by the influence of varying solar insolation patterns (in response to changing orbital configuration) on atmospheric dynamics and the resulting influence on storm activity in the region. References Fairchild, I. J. and Treble, P. C., 2009. Trace elements in speleothems as recorders of environmental change. Quaternary Science Reviews 28, 449-468. Martrat, B., Grimalt, J. O., Shackleton, N. J., de Abreu, L., Hutterli, M. A., and Stocker, T. F., 2007. Four climate cycles of recurring deep and surface water destabilizations on the Iberian Margin. Science 317, 502-507. North Greenland Ice Core Project members, 2004. High-resolution record of Northern Hemisphere climate extending into the last interglacial period. Nature 431, 147-151.

Determination of lead isotopes in a new Greenland deep ice core at the sub-picogram per gram level by thermal ionization mass spectrometry using an improved decontamination method.

PubMed

Han, Changhee; Burn-Nunes, Laurie J; Lee, Khanghyun; Chang, Chaewon; Kang, Jung-Ho; Han, Yeongcheol; Hur, Soon Do; Hong, Sungmin

2015-08-01

An improved decontamination method and ultraclean analytical procedures have been developed to minimize Pb contamination of processed glacial ice cores and to achieve reliable determination of Pb isotopes in North Greenland Eemian Ice Drilling (NEEM) deep ice core sections with concentrations at the sub-picogram per gram level. A PL-7 (Fuso Chemical) silica-gel activator has replaced the previously used colloidal silica activator produced by Merck and has been shown to provide sufficiently enhanced ion beam intensity for Pb isotope analysis for a few tens of picograms of Pb. Considering the quantities of Pb contained in the NEEM Greenland ice core and a sample weight of 10 g used for the analysis, the blank contribution from the sample treatment was observed to be negligible. The decontamination and analysis of the artificial ice cores and selected NEEM Greenland ice core sections confirmed the cleanliness and effectiveness of the overall analytical process. Copyright © 2015 Elsevier B.V. All rights reserved.

Arctic Interglacial Warmth - can Beringian paleoclimate records inform us concerning the transition we are now in?

NASA Astrophysics Data System (ADS)

Brigham-Grette, J.

2011-12-01

Contemporary change cannot be evaluated without the perspective of past rates of change in concert with a complete evaluation of associated feedbacks and forcings. Paleoclimate studies offer the only valid context for evaluating trajectories and dynamics in the climate system especially in a warming world driven by anthropogenic CO2. "If it happened before it could happen again" and it is with this adage that most of the paleoclimate community is now screaming déjà vu. The present rate of global scale warming is unprecedented within the resolution of paleorecords. High resolution terrestrial studies (lakes, tree rings and ice cores) of the last 2 ka across the Arctic clearly show that the wholesale warming of the past few decades is unprecedented and likely forced by increases in green house gas emissions. Emerging evidence of earlier warm periods over the past few million years inform us about the sensitivity of the arctic system to change, particularly the rates and magnitudes of warmth that directly impact the seasonal extent and existence of sea ice, the melt of glacial systems and changes in sea level. While there is some consensus about the rapid response of the sea-ice albedo feedback processes, it still remains difficult to model. Large changes in seasonal ice across the Arctic have been documented for parts of the early Holocene due to insolation forcing and sea ice was arguably less extensive during MIS 5e (125ka), and several other interglacials. Along with less sea ice there are data to suggest large northward range extensions of marine flora and fauna that likely accompanied changes in water mass structure. Sustained warmth during the Pliocene (especially 3.0 to 3.6 Ma) suggests several intervals when summer sea ice was absent and even the presence of winter sea ice is debated. While different research groups have each produced a variety estimates for pCO2 in mid Pliocene ranging from 280 ppm to 400 ppm, most agree that pCO2 may have been like today in the 350 to 400 ppm range as a major forcing factor. New continuous interglacial records from the Lake El'gygytgyn core (central Chukotka) correlative with well-known marine isotopic stages 5e, 9, 11 and 31, which each differ in character, presumably due to orbital forcing and feedbacks. Because many of these warm episodes at Lake El'gygytgyn surpass the warmth of the last interglacial when the Greenland Ice Sheet is thought to have been smaller than today, these new data will contribute to modeling efforts that test the vulnerability of Arctic sea ice and the Greenland Ice Sheet to global warming.

Water ingress detection in honeycomb sandwich panels by passive infrared thermography using a high-resolution thermal imaging camera

NASA Astrophysics Data System (ADS)

Ibarra-Castanedo, C.; Brault, L.; Marcotte, F.; Genest, M.; Farley, V.; Maldague, X.

2012-06-01

Water ingress in honeycomb structures is of great concern for the civil and military aerospace industries. Pressure and temperature variations during take-off and landing produce considerable stress on aircraft structures, promoting moisture ingress (by diffusion through fibers or by direct ingress through voids, cracks or unsealed joints) into the core. The presence of water (or other fluids such as kerosene, hydraulic fluid and de-icing agents) in any of its forms (gas vapor, liquid or ice) promotes corrosion, cell breakage, and induce composite layer delaminations and skin disbonds. In this study, testing specimens were produced from unserviceable parts from military aircraft. In order to simulate atmospheric conditions during landing, selected core areas were filled with measured quantities of water and then frozen in a cold chamber. The specimens were then removed from the chamber and monitored for over 20 minutes as they warm up using a cooled high-resolution infrared camera. Results have shown that detection and quantification of water ingress on honeycomb sandwich structures by passive infrared thermography is possible using a HD mid-wave infrared cameras for volumes of water as low as 0.2 ml and from a distance as far as 20 m from the target.

Dust Records in Ice Cores from the Tibetan Plateau

NASA Astrophysics Data System (ADS)

Wang, N.; Yao, T.; Thompson, L. G.

2014-12-01

Dust plays an important role in the Earth system, and it usually displays largely spatial and temporal variations. It is necessary for us to reconstruct the past variations of dust in different regions to better understand the interactions between dust and environments. Ice core records can reveal the history of dust variations. In this paper, we used the Guliya, Dunde, Malan and Dasuopu ice cores from the Tibetan Plateau to study the spatial distribution, the seasonal variations and the secular trends of dust. It was found that the mean dust concentration was higher by one or two order of magnitudes in the Guliya and Dunde ice cores from the northern Tibetan Plateau than in the Dasuopu ice core from the southern Tibetan Plateau. During the year, the highest dust concentration occurs in the springtime in the northern Tibetan Plateau while in the non-monsoon season in the southern Tibetan Plateau. Over the last millennium, the Dasuopu ice core record shows that the 1270s~1380s and 1870s~1990s were the two epochs with high dust concentration. However, the Malan ice core from the northern Tibetan Plateau indicates that high dust concentration occurred in the 1130s~1550s and 1770s~1940s. Interestingly, climatic and environmental records of the ice cores from the Tibetan Plateau reflected that the correlation between dust concentration and air temperature was strongly positive in the southern Plateau while negative in the northern Plateau over the last millennium. This implies that climatic and environmental changes existed considerable differences in the different parts of the Plateau. Moreover, four Asian megadroughts occurred in 1638~1641, 1756~1758, 1790~1796 and 1876~1878, which caused more than tens millions people died, were revealed clearly by dust record in the Dasuopu ice core.

Initial results from geophysical surveys and shallow coring of the Northeast Greenland Ice Stream (NEGIS)

NASA Astrophysics Data System (ADS)

Vallelonga, P.; Christianson, K.; Alley, R. B.; Anandakrishnan, S.; Christian, J. E. M.; Dahl-Jensen, D.; Gkinis, V.; Holme, C.; Jacobel, R. W.; Karlsson, N. B.; Keisling, B. A.; Kipfstuhl, S.; Kjær, H. A.; Kristensen, M. E. L.; Muto, A.; Peters, L. E.; Popp, T.; Riverman, K. L.; Svensson, A. M.; Tibuleac, C.; Vinther, B. M.; Weng, Y.; Winstrup, M.

2014-07-01

The Northeast Greenland Ice Stream (NEGIS) is the sole interior Greenlandic ice stream. Fast flow initiates near the summit dome, and the ice stream terminates approximately 1000 km downstream in three large outlet glaciers that calve into the Greenland Sea. To better understand this important system, in the summer of 2012 we drilled a 67 m firn core and conducted ground-based radio-echo sounding (RES) and active-source seismic surveys at a site approximately 150 km downstream from the onset of streaming flow (NEGIS firn core, 75°37.61' N, 35°56.49' W). The site is representative of the upper part of the ice stream, while also being in a crevasse-free area for safe surface operations. Annual cycles were observed for insoluble dust, sodium and ammonium concentrations and for electrolytic conductivity, allowing a seasonally resolved chronology covering the past 400 yr. Annual layer thicknesses averaged 0.11 m ice equivalent (i.e.) for the period 1607-2011, although accumulation varied between 0.08 and 0.14 m i.e., likely due to flow-related changes in surface topography. Tracing of RES layers from the NGRIP (North Greenland Ice Core Project) ice core site shows that the ice at NEGIS preserves a climatic record of at least the past 51 kyr. We demonstrate that deep ice core drilling in this location can provide a reliable Holocene and late-glacial climate record, as well as helping to constrain the past dynamics and ice-lithosphere interactions of the Greenland Ice Sheet.

Dating of 30m ice cores drilled by Japanese Antarctic Research Expedition and environmental change study

NASA Astrophysics Data System (ADS)

Motoyama, H.; Suzuki, T.; Fukui, K.; Ohno, H.; Hoshina, Y.; Hirabayashi, M.; Fujita, S.

2017-12-01

1. Introduction It is possible to reveal the past climate and environmental change from the ice core drilled in polar ice sheet and glaciers. The 54th Japanese Antarctic Research Expedition conducted several shallow core drillings up to 30 m depth in the inland and coastal areas of the East Antarctic ice sheet. Ice core sample was cut out at a thickness of about 5 cm in the cold room of the National Institute of Polar Research, and analyzed ion, water isotope, dust and so one. We also conducted dielectric profile measurement (DEP measurement). The age as a key layer of large-scale volcanic explosion was based on Sigl et al. (Nature Climate Change, 2014). 2. Inland ice core Ice cores were collected at the NDF site (77°47'14"S, 39°03'34"E, 3754 m.a.s.l.) and S80 site (80°00'00"S, 40°30'04"E, 3622 m.a.s.l.). Dating of ice core was done as follows. Calculate water equivalent from core density. Accumulate water equivalent from the surface. Approximate the relation of depth - cumulative water equivalent by a quartic equation. We determined the key layer with nssSO42 - peak corresponding to several large volcanic explosions. The accumulation rate was kept constant between the key layers. As a result, NDF was estimated to be around 1360 AD and S80 was estimated to be around 1400 AD in the deepest ice core. 3. Coastal ice core An ice core was collected at coastal H15 sites (69°04'10"S, 40°44'51"E, 1030 m.a.s.l.). Dating of ice core was done as follows. Calculate water equivalent from ice core density. Accumulate water equivalent from the surface. Approximate the relation of depth - cumulative water equivalent by a quartic equation. Basically we decided to summer (December) and winter (June) due to the seasonal change of the water isotope (δD or δ18O). In addition to the seasonal change of isotope, confirm the following. Maximum of SO42- / Na +, which is earlier in time than the maximum of water isotope. Maximum of MSA at about the same time as the maximum of the water isotope. Na+ is maximal immediately after the local maximum of the water isotope. The deepest age was estimated to be around 1940 AD. 4. Example of results In the inland area, the annual average surface mass balance decreased from 1450 to 1850 AD, but it has increased since 1850 AD. The annual mass balance of coastal H15 is consistent with the result of snow stake measurement.

Cool Science Explains a Warming World: Using Ice Core Science to Bridge the Gap Between Researchers and the K-12 Classroom

NASA Astrophysics Data System (ADS)

Huffman, L. T.

2017-12-01

Changing ice has urgent implications for people around the world. The Ice Drilling Program Office (IDPO) provides scientific leadership and oversight of ice coring and drilling activities funded by the US National Science Foundation and also has goals to enhance education and communication of current research information. In a time when misinformation is rampant and climate change science is suspect, it is essential that students receive accurate scientific information and engage in learning activities that model complex ideas through engaging and age appropriate ways, while also learning to validate and recognize reliable sources. The IDPO Education and Outreach (EO) office works to create resources, activities and professional development that bridge the gap between ice core science research and educators and their students. Ice core science is on the cutting edge of new discoveries about climate change and understanding better the past to predict the future. Hands-on inquiry activities based on ice core data allow teachers to lead their students to new discoveries about climate secrets hidden deep in the ice. Capitalizing on the inherent interest in the extremes of the Polar Regions, IDPO materials engage students in activities aligned with NGSS standards. Ice drilling technologies make an ideal platform for intertwining engineering concepts and practices with science research to meet the SEP (Science and Engineering Practices) in the NGSS. This session will highlight how the IDPO EO office has built a community of ice core scientists willing to take part in education and outreach projects and events and share some of the resources available to K-12 educators. We will highlight some of the successes and lessons learned as we continually evolve our work toward more effective science education and communication highlighting ice core and climate change science.

Glaciological reconstruction of Holocene ice margins in northwestern Greenland

NASA Astrophysics Data System (ADS)

Birkel, S. D.; Osterberg, E. C.; Kelly, M. A.; Axford, Y.

2014-12-01

The past few decades of climate warming have brought overall margin retreat to the Greenland Ice Sheet. In order to place recent and projected changes in context, we are undertaking a collaborative field-modeling study that aims to reconstruct the Holocene history of ice-margin fluctuation near Thule (~76.5°N, 68.7°W), and also along the North Ice Cap (NIC) in the Nunatarssuaq region (~76.7°N, 67.4°W). Fieldwork reported by Kelly et al. (2013) reveals that ice in the study areas was less extensive than at present ca. 4700 (GIS) and ca. 880 (NIC) cal. years BP, presumably in response to a warmer climate. We are now exploring Holocene ice-climate coupling using the University of Maine Ice Sheet Model (UMISM). Our approach is to first test what imposed climate anomalies can afford steady state ice margins in accord with field data. A second test encompasses transient simulation of the Holocene, with climate boundary conditions supplied by existing paleo runs of the Community Climate System Model version 4 (CCSM4), and a climate forcing signal derived from Greenland ice cores. In both cases, the full ice sheet is simulated at 10 km resolution with nested domains at 0.5 km for the study areas. UMISM experiments are underway, and results will be reported at the meeting.

WCRP's Climate and Cryosphere (CliC) Project: Climate Change and Middle and Low Latitude Glaciers

NASA Astrophysics Data System (ADS)

Dick, C. A.; Clic Project, W.

2004-12-01

The newest World Climate Research Programme (WCRP) Core Project, the Climate and Cryosphere (CliC) Project, is concerned with all aspects of the interactions between the cryosphere and climate. The cryosphere, defined as those portions of the Earth's surface where water exists in solid form, is an integral part of the climate system, both responding to, and influencing climate change. The cryosphere also provides many of the best indicators of climate variability and change. In addition to a range of direct physical indicators (e.g., snow/sea ice/glacier extent and thickness, river and lake freeze-up/break-up dates, etc.), ice cores from glaciers, ice caps and ice sheets have been shown to contain a wealth of information about past climate and environmental conditions. Ice cores are of particular value, since they often come from areas that are remote and poorly observed, yet have a major effect on the climate of the rest of the globe. General Circulation Models (GCMs) usually predict that the Earth's polar regions will warm fastest with the increasing levels of atmospheric greenhouse gases. However, models also indicate that continental interiors should warm more quickly than marine areas at non-polar latitudes. In fact, while some areas in the Arctic and Antarctic have warmed rapidly over the last few decades, it has generally been in the middle and low latitudes that the greatest effects of climate change have been observed. Particularly obvious has been the widespread retreat of glaciers. This retreat, and the warming which it implies, will have not only important scientific consequences but also socio-economic consequences in areas where glacier melt-water is an important component of the water supply. Glaciers preserve records of climate and the environment through both the isotopic composition of the water molecules, and through the chemicals 'trapped' in the snow, firn and ice layers. In polythermal (i.e., cold) glaciers where only limited melt occurs, the isotopic and chemical signals remain largely undisturbed, and ice cores can provide excellent high resolution records of past conditions. In temperate glaciers, where the ice is at its pressure melting point throughout, diffusion processes are much more rapid, and summer melt and run-off can drastically alter the chemical composition. Much of the climatic and environmental information is destroyed. This presentation will discuss the very serious concern that so many middle and low latitude glaciers are retreating and warming. The CliC Project recognizes an urgent need to recover ice cores from all non-polar glaciated regions before warming affects the glaciers and removes the information they contain. Without such information our ability to understand the climate changes that have occurred in the world's mountainous regions will be restricted, and our ability to model and predict future climate will be severely impaired.

Paleoenvironmental changes during the past 2000 years, evidence from Kongsfjorden, Svalbard

NASA Astrophysics Data System (ADS)

Jernas, P.; Kristensen, D.; Koc, N.; Skirbekk, K.

2009-04-01

Over the past decades the Arctic has received more attention due to the rapid warming that is more pronounced there than elsewhere on the globe. Instrumental time series are too short to capture the range of natural variability in the Arctic and we therefore have to rely on proxy records to describe the whole range of natural variability. In this context the late-Holocene climate variations are particularly important because natural forcings and the Earth's boundary conditions have been approximately similar to those operating today. Documenting past natural climate variability has therefore a vital role to play in understanding the present climate and predicting future change. Here we present a high resolution marine record from Kongsfjorden covering the last c. 2000 years. The core site is located in Kongsfjorden situated on the western coast of Spitsbergen (Svalbard). We focus on this region because it lies along the path of inflow of warmer and saline subsurface waters via the West Spitsbergen Current which is one of the important heat sources for the Arctic Ocean. This current is a major regulator of environmental changes and for example sea-ice distribution in the west Svalbard area. Therefore quantification of it's spatially and temporally variations through time are essential for understanding past environmental and climate changes. We have investigated faunal variations in benthic foraminifera from the upper 60 cm (covering the last two millennia) of a gravity core (510 cm total length) sampled with one-cm density. Chronology of the gravity core is established by AMS radiocarbon dating. The core was in addition investigated for grain size analysis and x-ray. The sediment analysis and x-ray show the upper part of the core contains large amounts of IRD from 7 cm - 25 cm corresponding to an age of 150-700 cal yr. It indicates that abundant icebergs melted over the core site depositing IRD. Further down core (1000-1800 cal yr) there is a significant dominance of fine grained sediment and decrease in ice rafting indicating less influence from glaciers. The foraminiferal species composition show decreasing content of agglutinated foraminifera down core caused by their low preservation potential. For this core site it confirms the importance of calcareous foraminifera as a fossil record tool. The two dominant species in the core are Elphidium excavatum and Nonionellina labradorica. During the last 2000 years the percentage of E. excavatum shows a general tendency to decrease while N. labradorica increases toward present. Elphidium excavatum is typical for arctic glaciomarine environments close to glaciers and ice caps, indicating harsh conditions (cold bottom waters temperatures, lower salinity) and probably extensive ice cover. Nonionellina labradorica indicates the vicinity of oceanographic fronts and high productivity. Another species Islandiella spp., often associated with increased productivity and presence of the sea ice edge, shows significant increase in percentage from 1000 to 800 cal yr BP. From 600 to 400 cal yr BP Bucella spp. start to decline suggesting increased sea ice cover and diminished influence of the Coastal Current on the inner shelf of Svalbard.

Using Radar and Seismic Methods for the Determination of Ice Column Properties and Basal Conditions at Jakobshavn Isbrae and the NEEM Drill Site

NASA Astrophysics Data System (ADS)

Velez Gonzalez, Jose A.

The development of preferred crystal orientation fabrics (COF) within the ice column can have a strong influence on the flow behavior of an ice sheet or glacier. Typically, COF information comes from ice cores. Observations of anisotropic seismic wave propagation and backscatter variation as a function of antenna orientation in GPR measurements have been proposed as methods to detect COF. For this investigation I evaluate the effectiveness of the GPR and seismic methods to detect COF by conducting a seismic and GPR experiment at the North Greenland Eemian Ice Drilling facility (NEEM) ice core location, where COF data is available. The seismic experiment was conducted 6.5 km North West of the NEEM facility and consisted of three multi-offset seismic gathers. The results of the anisotropy analysis conducted at NEEM yielded mean c-axes distributed over a conical region of I angle of 30 to 32 degrees. No internal ice reflectors were imaged. Direct COF measurements collected in the ice core are in agreement with the results from the seismic anisotropy analysis. The GPR experiment covered an area of 100 km2 and consisted of parallel, perpendicular, oblique and circular (radius: 35 m) acquisition patterns. Results show evidence for COF for the entire 100 km2 area. Furthermore, for the first time it was possible to image three different COF (random, disk and single maxima) and their respective transition zones. The interpretation of the GPR experiment showed a strong correlation with the ice core measurements. Glacier basal drag is also an important, and difficult to predict, property that influences glacier flow. For this investigation I re-processed a 10 km-long high-resolution reflection seismic line at Jakobshavn Isbrae, Greenland, using an iterative velocity determination approach for optimizing sub-glacier imaging. The resultant line imaged a sub-glacier sediment layer ranging in thickness between 35 and 200 meters. I interpret three distinct seismic facies based on the geometry of the reflectors as a basal till layer, accreted sediments and re-worked till. The basal till and accreted sediments vary in thickness between 4 and 93 meters and are thought to be water-saturated actively-deforming sub-glacier sediments. A polarity reversal observed at one location along the ice-sediment interface suggests the presence of water saturated sediments or water ponding 2-4 m thick spanning approximately 240 m across. Using information from the seismic line (bed geometry, ice thickness, till thickness) as well as information available for the area of study (ice surface elevation and ice flow velocity) we evaluate the effect of sub-glacier sediment viscosity on the basal drag using a linearly viscous model and the assumption of a deforming bed. Basal drag values estimated for the study area fall within the range of physically acceptable values. However, the analysis revealed that the assumption of a deforming bed might not be compatible for the area of study given the presence of water at the ice/bed interface.

Greenland records of aerosol source and atmospheric lifetime changes from the Eemian to the Holocene.

PubMed

Schüpbach, S; Fischer, H; Bigler, M; Erhardt, T; Gfeller, G; Leuenberger, D; Mini, O; Mulvaney, R; Abram, N J; Fleet, L; Frey, M M; Thomas, E; Svensson, A; Dahl-Jensen, D; Kettner, E; Kjaer, H; Seierstad, I; Steffensen, J P; Rasmussen, S O; Vallelonga, P; Winstrup, M; Wegner, A; Twarloh, B; Wolff, K; Schmidt, K; Goto-Azuma, K; Kuramoto, T; Hirabayashi, M; Uetake, J; Zheng, J; Bourgeois, J; Fisher, D; Zhiheng, D; Xiao, C; Legrand, M; Spolaor, A; Gabrieli, J; Barbante, C; Kang, J-H; Hur, S D; Hong, S B; Hwang, H J; Hong, S; Hansson, M; Iizuka, Y; Oyabu, I; Muscheler, R; Adolphi, F; Maselli, O; McConnell, J; Wolff, E W

2018-04-16

The Northern Hemisphere experienced dramatic changes during the last glacial, featuring vast ice sheets and abrupt climate events, while high northern latitudes during the last interglacial (Eemian) were warmer than today. Here we use high-resolution aerosol records from the Greenland NEEM ice core to reconstruct the environmental alterations in aerosol source regions accompanying these changes. Separating source and transport effects, we find strongly reduced terrestrial biogenic emissions during glacial times reflecting net loss of vegetated area in North America. Rapid climate changes during the glacial have little effect on terrestrial biogenic aerosol emissions. A strong increase in terrestrial dust emissions during the coldest intervals indicates higher aridity and dust storm activity in East Asian deserts. Glacial sea salt aerosol emissions in the North Atlantic region increase only moderately (50%), likely due to sea ice expansion. Lower aerosol concentrations in Eemian ice compared to the Holocene are mainly due to shortened atmospheric residence time, while emissions changed little.

Variability in Organic-Carbon Sources and Sea-Ice Coverage North of Iceland (Subarctic) During the Past 15,000 Years

NASA Astrophysics Data System (ADS)

Xiao, X.; Zhao, M.; Knudsen, K. L.; Eiriksson, J.; Gudmundsdottir, E. R.; Jiang, H.; Guo, Z.

2017-12-01

Sea ice, prevailing in the polar region and characterized by distinct seasonal and interannual variability, plays a pivotal role in Earth's climate system (Thomas and Dieckmann, 2010). Studies of spatial and temporal changes in modern and past sea-ice occurrence may help to understand the processes controlling the recent decrease in Arctic sea-ice cover. Here, we determined the concentrations of sea-ice diatom-derived biomarker "IP25" (monoene highly-branched isoprenoid with 25 carbon atom; Belt et al., 2007), phytoplankton-derived biomarker brassicasterol and terrigenous biomarker long-chain n-alkanols in a sediment core from the North Icelandic shelf to reconstruct the high-resolution sea-ice variability and the organic-matter sources during the past 15,000 years. During the Bølling/Allerød, the North Icelandic shelf was characterized by extensive spring sea-ice cover linked to reduced flow of warm Atlantic Water and dominant Polar water influence; the input of terrestrial and sea-ice organic matters was high while the marine organic matter derived from phytoplankton productivity was low. Prolonged sea-ice cover with occasional occurrence of seasonal sea ice prevailed during the Younger Dryas interrupted by a brief interval of enhanced Irminger Current; the organic carbon input from sea-ice productivity, terrestrial matter and phytoplankton productivity all decreased. The seasonal sea ice decreased gradually from the Younger Dryas to the onset of the Holocene corresponding to increasing insolation. Therefore, the sea-ice productivity decreased but the phytoplankton productivity increased during this time interval. The biomarker records from this sediment core give insights into the variability in sea ice and organic-carbon sources in the Arctic marginal area during the last deglacial and Holocene. References Belt, S.T., Massé, G., Rowland, S.J., Poulin, M., Michel, C., LeBlanc, B., 2007. A novel chemical fossil of palaeo sea ice: IP25. Org. Geochem. 38, 16-27. Knudsen, K.L. and Eiriksson, J., 2002. Application of tephrochronology to the timing and correlation of palaeoceanographic events recorded in Holocene and Late Glacial shelf sediments off North Iceland. Marine Geology 191, 165-188. Thomas, D. N. and Dieckmann, G. S., 2010. Sea Ice, Blackwell Publ., Oxford, U. K.

Preparing for Exascale: Towards convection-permitting, global atmospheric simulations with the Model for Prediction Across Scales (MPAS)

NASA Astrophysics Data System (ADS)

Heinzeller, Dominikus; Duda, Michael G.; Kunstmann, Harald

2017-04-01

With strong financial and political support from national and international initiatives, exascale computing is projected for the end of this decade. Energy requirements and physical limitations imply the use of accelerators and the scaling out to orders of magnitudes larger numbers of cores then today to achieve this milestone. In order to fully exploit the capabilities of these Exascale computing systems, existing applications need to undergo significant development. The Model for Prediction Across Scales (MPAS) is a novel set of Earth system simulation components and consists of an atmospheric core, an ocean core, a land-ice core and a sea-ice core. Its distinct features are the use of unstructured Voronoi meshes and C-grid discretisation to address shortcomings of global models on regular grids and the use of limited area models nested in a forcing data set, with respect to parallel scalability, numerical accuracy and physical consistency. Here, we present work towards the application of the atmospheric core (MPAS-A) on current and future high performance computing systems for problems at extreme scale. In particular, we address the issue of massively parallel I/O by extending the model to support the highly scalable SIONlib library. Using global uniform meshes with a convection-permitting resolution of 2-3km, we demonstrate the ability of MPAS-A to scale out to half a million cores while maintaining a high parallel efficiency. We also demonstrate the potential benefit of a hybrid parallelisation of the code (MPI/OpenMP) on the latest generation of Intel's Many Integrated Core Architecture, the Intel Xeon Phi Knights Landing.

Ice Core Investigations

ERIC Educational Resources Information Center

Krim, Jessica; Brody, Michael

2008-01-01

What can glaciers tell us about volcanoes and atmospheric conditions? How does this information relate to our understanding of climate change? Ice Core Investigations is an original and innovative activity that explores these types of questions. It brings together popular science issues such as research, climate change, ice core drilling, and air…

Snow contribution to first-year and second-year Arctic sea ice mass balance north of Svalbard

NASA Astrophysics Data System (ADS)

Granskog, Mats A.; Rösel, Anja; Dodd, Paul A.; Divine, Dmitry; Gerland, Sebastian; Martma, Tõnu; Leng, Melanie J.

2017-03-01

The salinity and water oxygen isotope composition (δ18O) of 29 first-year (FYI) and second-year (SYI) Arctic sea ice cores (total length 32.0 m) from the drifting ice pack north of Svalbard were examined to quantify the contribution of snow to sea ice mass. Five cores (total length 6.4 m) were analyzed for their structural composition, showing variable contribution of 10-30% by granular ice. In these cores, snow had been entrained in 6-28% of the total ice thickness. We found evidence of snow contribution in about three quarters of the sea ice cores, when surface granular layers had very low δ18O values. Snow contributed 7.5-9.7% to sea ice mass balance on average (including also cores with no snow) based on δ18O mass balance calculations. In SYI cores, snow fraction by mass (12.7-16.3%) was much higher than in FYI cores (3.3-4.4%), while the bulk salinity of FYI (4.9) was distinctively higher than for SYI (2.7). We conclude that oxygen isotopes and salinity profiles can give information on the age of the ice and enables distinction between FYI and SYI (or older) ice in the area north of Svalbard.