Hydrochemical characteristics and groundwater evolution modeling in sedimentary rocks of the Tono mine, Japan

NASA Astrophysics Data System (ADS)

Sasamoto, Hiroshi; Yui, Mikazu; Arthur, Randolph C.

Based on geochemical data collected by Japan Nuclear Cycle Development Institute (JNC) in the Tono uranium mine, a conceptual groundwater evolution model developed by JNC is tested to evaluate whether equilibrium-based concepts of water-rock interaction are consistent with observed variations in the mineralogy and hydrochemistry of the Tono mine area. The chemical evolution of the groundwaters is modeled assuming local equilibrium for selected mineral-fluid reactions, taking into account the rainwater origin of these solutions. Results suggest that it is possible to interpret approximately the actual groundwater chemistry (i.e., pH, Eh, total dissolved concentrations of Si, Na, Ca, K, Al, carbonate and sulfate) if the following assumptions are adopted (a) CO 2 concentration in the gas phase contacting pore solutions in the overlying soil zone=10 -1 atm, and (b) minerals in the rock zone that control the solubility of respective elements in the groundwater include: chalcedony (Si), albite (Na), kaolinite (Al), calcite (Ca and carbonate), muscovite (K) and pyrite (Eh and sulfate). This result helps to build confidence in the use of simplified geochemical modeling techniques to develop an understanding of dominant geochemical reactions controlling groundwater chemistry in rocks similar to those that could be used for the geological disposal of radioactive wastes. It is noted, however, that the available field data may not be sufficient to adequately constrain parameters in the groundwater evolution model. In particular, more detailed information characterizing certain site properties are needed to improve the model. For this reason, a model that accounts for ion-exchange reactions among clay minerals, and which is based on the results of laboratory experiments, has also been evaluated in the present study. Further improvement of model considering ion-exchange reactions are needed in future, however.

Groundwater flow and hydrogeochemical evolution in the Jianghan Plain, central China

NASA Astrophysics Data System (ADS)

Gan, Yiqun; Zhao, Ke; Deng, Yamin; Liang, Xing; Ma, Teng; Wang, Yanxin

2018-05-01

Hydrogeochemical analysis and multivariate statistics were applied to identify flow patterns and major processes controlling the hydrogeochemistry of groundwater in the Jianghan Plain, which is located in central Yangtze River Basin (central China) and characterized by intensive surface-water/groundwater interaction. Although HCO3-Ca-(Mg) type water predominated in the study area, the 457 (21 surface water and 436 groundwater) samples were effectively classified into five clusters by hierarchical cluster analysis. The hydrochemical variations among these clusters were governed by three factors from factor analysis. Major components (e.g., Ca, Mg and HCO3) in surface water and groundwater originated from carbonate and silicate weathering (factor 1). Redox conditions (factor 2) influenced the geogenic Fe and As contamination in shallow confined groundwater. Anthropogenic activities (factor 3) primarily caused high levels of Cl and SO4 in surface water and phreatic groundwater. Furthermore, the factor score 1 of samples in the shallow confined aquifer gradually increased along the flow paths. This study demonstrates that enhanced information on hydrochemistry in complex groundwater flow systems, by multivariate statistical methods, improves the understanding of groundwater flow and hydrogeochemical evolution due to natural and anthropogenic impacts.

Geochemical evolution of groundwater in southern Bengal Basin: The example of Rajarhat and adjoining areas, West Bengal, India

NASA Astrophysics Data System (ADS)

Sahu, Paulami; Sikdar, P. K.; Chakraborty, Surajit

2016-02-01

Detailed geochemical analysis of groundwater beneath 1223 km2 area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: `excellent', `good' and `poor' and seven hydrochemical facies are assigned to three broad types: `fresh', `mixed' and `brackish' waters. The `fresh' water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich `brackish' groundwater represents freshening of modified connate water. The `mixed' type groundwater has possibly evolved due to hydraulic mixing of `fresh' and `brackish' waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.

A spring forward for hominin evolution in East Africa.

PubMed

Cuthbert, Mark O; Ashley, Gail M

2014-01-01

Groundwater is essential to modern human survival during drought periods. There is also growing geological evidence of springs associated with stone tools and hominin fossils in the East African Rift System (EARS) during a critical period for hominin evolution (from 1.8 Ma). However it is not known how vulnerable these springs may have been to climate variability and whether groundwater availability may have played a part in human evolution. Recent interdisciplinary research at Olduvai Gorge, Tanzania, has documented climate fluctuations attributable to astronomic forcing and the presence of paleosprings directly associated with archaeological sites. Using palaeogeological reconstruction and groundwater modelling of the Olduvai Gorge paleo-catchment, we show how spring discharge was likely linked to East African climate variability of annual to Milankovitch cycle timescales. Under decadal to centennial timescales, spring flow would have been relatively invariant providing good water resource resilience through long droughts. For multi-millennial periods, modelled spring flows lag groundwater recharge by 100 s to 1000 years. The lag creates long buffer periods allowing hominins to adapt to new habitats as potable surface water from rivers or lakes became increasingly scarce. Localised groundwater systems are likely to have been widespread within the EARS providing refugia and intense competition during dry periods, thus being an important factor in natural selection and evolution, as well as a vital resource during hominin dispersal within and out of Africa.

Groundwater hydrogeochemical characteristics in rehabilitated coalmine spoils

NASA Astrophysics Data System (ADS)

Gomo, M.; Masemola, E.

2016-04-01

The investigation aims to identify and describe hydrogeochemical processes controlling the evolution of groundwater chemistry in rehabilitated coalmine spoils and their overall influence on groundwater quality at a study area located in the Karoo basin of South Africa. A good understanding of the processes that controls the evolution of the mine water quality is vital for the planning, application and management of post-mining remedial actions. The study utilises scatter plots, statistical analysis, PHREEQC hydrogeochemical modelling, stoichiometric reaction ratios analysis, and the expanded Durov diagram as complimentary tools to interpret the groundwater chemistry data collected from monitoring boreholes from 1995 to 2014. Measured pH ranging between 6-8 and arithmetic mean of 7.32 shows that the groundwater system is characterised by circumneutral hydrogeochemical conditions period. Comparison of measured groundwater ion concentrations to theoretical reaction stoichiometry identifies Dolomite-Acid Mine Drainage (AMD) neutralisation as the main hydrogeochemical process controlling the evolution of the groundwater chemistry. Hydrogeochemical modelling shows that, the groundwater has temporal variations of calcite and dolomite saturation indices characterised by alternating cycles of over-saturation and under-saturation that is driven by the release of sulphate, calcium and magnesium ions from the carbonate-AMD neutralization process. Arithmetic mean concentrations of sulphate, calcium and magnesium are in the order of 762 mg/L, 141 mg/L and 108 mg/L. Calcium and magnesium ions contribute to very hard groundwater quality conditions. Classification based on total dissolved solids (TDS), shows the circumneutral water is of poor to unacceptable quality for drinking purposes. Despite its ability to prevent AMD formation and leaching of metals, the dolomite-AMD neutralisation process can still lead to problems of elevated TDS and hardness which mines should be aware of when developing water quality management plans.

Palaeo-modeling of coastal salt water intrusion during the Holocene: an application to the Netherlands

NASA Astrophysics Data System (ADS)

Delsman, J. R.; Hu-a-ng, K. R. M.; Vos, P. C.; de Louw, P. G. B.; Oude Essink, G. H. P.; Stuyfzand, P. J.; Bierkens, M. F. P.

2013-11-01

Management of coastal fresh groundwater reserves requires a thorough understanding of the present-day groundwater salinity distribution and its possible future development. However, coastal groundwater often still reflects a complex history of marine transgressions and regressions, and is only rarely in equilibrium with current boundary conditions. In addition, the distribution of groundwater salinity is virtually impossible to characterize satisfactorily, complicating efforts to model and predict coastal groundwater flow. A way forward may be to account for the historical development of groundwater salinity when modeling present-day coastal groundwater flow. In this paper, we construct a palaeo-hydrogeological model to simulate the evolution of groundwater salinity in the coastal area of the Netherlands throughout the Holocene. While intended as a perceptual tool, confidence in our model results is warranted by a good correspondence with a hydrochemical characterization of groundwater origin. Model results attest to the impact of groundwater density differences on coastal groundwater flow on millennial timescales and highlight their importance in shaping today's groundwater salinity distribution. Not once reaching steady-state throughout the Holocene, our results demonstrate the long-term dynamics of salinity in coastal aquifers. This stresses the importance of accounting for the historical evolution of coastal groundwater salinity when modeling present-day coastal groundwater flow, or when predicting impacts of e.g. sea level rise on coastal aquifers. Of more local importance, our findings suggest a more significant role of pre-Holocene groundwater in the present-day groundwater salinity distribution in the Netherlands than previously recognized. The implications of our results extend beyond understanding the present-day distribution of salinity, as the proven complex history of coastal groundwater also holds important clues for understanding and predicting the distribution of other societally relevant groundwater constituents.

Groundwater data network interoperability

USGS Publications Warehouse

Brodaric, Boyan; Booth, Nathaniel; Boisvert, Eric; Lucido, Jessica M.

2016-01-01

Water data networks are increasingly being integrated to answer complex scientific questions that often span large geographical areas and cross political borders. Data heterogeneity is a major obstacle that impedes interoperability within and between such networks. It is resolved here for groundwater data at five levels of interoperability, within a Spatial Data Infrastructure architecture. The result is a pair of distinct national groundwater data networks for the United States and Canada, and a combined data network in which they are interoperable. This combined data network enables, for the first time, transparent public access to harmonized groundwater data from both sides of the shared international border.

Socio-hydrologic perspectives of the co-evolution of humans and groundwater in Cangzhou, North China Plain

NASA Astrophysics Data System (ADS)

Han, S.; Tian, F.; Liu, Y.

2017-12-01

This study presents a historical analysis from socio-hydrologic perspectives of the coupled human-groundwater system of the Cangzhou region in the North China Plain. The history of the "pendulum swing" for water allocation between the economic development and aquifer environmental health of the system is divided into five eras (i.e., natural, exploitation, degradation and restoration, drought-triggered deterioration, and returning to the balance). The system evolution was interpreted using the Taiji-Tire model. Over-exploitation was considered as the main cause of aquifer depletion and the groundwater utilization pattern was affected by the varying groundwater table. The aquifer depletion enhanced the community sensitivity of humans toward environmental issues, and upgraded the social productive force for restoration. The evolution of the system was substantially impacted by two droughts. The drought in 1965 induced the system from natural condition to groundwater exploiting. The drought from 1997 to 2002 resulted a pulse in further groundwater abstraction and dramatic aquifer deterioration, and the community sensitivity increased rapidly and induced the social productive force to a tipping point. From then on, the system is returning the balance through new policies and water-saving technologies. Along with the establishment of a strict water resource management strategy and the launch of the South-to-North Water Diversion Project, further restorations of groundwater environment would be implemented. However, a comprehensive and coordinated drought management plan should be devised to avoid the irreversible change of the system.

Socio-hydrological perspectives of the co-evolution of humans and groundwater in Cangzhou, North China Plain

NASA Astrophysics Data System (ADS)

Han, Songjun; Tian, Fuqiang; Liu, Ye; Duan, Xianhui

2017-07-01

This paper presents a historical analysis from socio-hydrological perspectives of the coupled human-groundwater system of the Cangzhou region in the North China Plain (NCP). The history of the pendulum swing for water allocation between the economic development and aquifer environmental health of the system is divided into five eras (i.e., natural, exploitation, degradation and restoration, drought-triggered deterioration, and returning to equilibrium). The system's evolution was interpreted using the Taiji-Tire model. Over-exploitation was considered as the main cause of aquifer depletion, and the groundwater utilization pattern was affected by the varying groundwater table. The aquifer depletion enhanced community sensitivity toward environmental issues, and upgraded the social productive force for restoration. The evolution of the system was substantially impacted by two droughts. The drought in 1965 induced the system from natural conditions to groundwater exploiting. The drought from 1997 to 2002 resulted in a surge in further groundwater abstraction and dramatic aquifer deterioration, and community sensitivity increased rapidly and induced the social productive force to a tipping point. From then on, the system returns to equilibrium through new policies and water-saving technologies. Along with the establishment of a strict water resource management strategy and the launch of the South-to-North Water Diversion Project, further restoration of groundwater environment was implemented. However, a comprehensive and coordinated drought management plan should be devised to avoid irreversible change in the system.

Revised conceptualization of the North China Basin groundwater flow system: Groundwater age, heat and flow simulations

NASA Astrophysics Data System (ADS)

Cao, Guoliang; Han, Dongmei; Currell, Matthew J.; Zheng, Chunmiao

2016-09-01

Groundwater flow in deep sedimentary basins results from complex evolution processes on geological timescales. Groundwater flow systems conceptualized according to topography and/or groundwater table configuration generally assume a near-equilibrium state with the modern landscape. However, the time to reach such a steady state, and more generally the timescales of groundwater flow system evolution are key considerations for large sedimentary basins. This is true in the North China Basin (NCB), which has been studied for many years due to its importance as a groundwater supply. Despite many years of study, there remain contradictions between the generally accepted conceptual model of regional flow, and environmental tracer data. We seek to reconcile these contractions by conducting simulations of groundwater flow, age and heat transport in a three dimensional model, using an alternative conceptual model, based on geological, thermal, isotope and historical data. We infer flow patterns under modern hydraulic conditions using this new model and present the theoretical maximum groundwater ages under such a flow regime. The model results show that in contrast to previously accepted conceptualizations, most groundwater is discharged in the vicinity of the break-in-slope of topography at the boundary between the piedmont and central plain. Groundwater discharge to the ocean is in contrast small, and in general there are low rates of active flow in the eastern parts of the basin below the central and coastal plain. This conceptualization is more compatible with geochemical and geothermal data than the previous model. Simulated maximum groundwater ages of ∼1 Myrs below the central and coastal plain indicate that residual groundwater may be retained in the deep parts of the basin since being recharged during the last glacial period or earlier. The groundwater flow system has therefore probably not reached a new equilibrium state with modern-day hydraulic conditions. The previous hypothesis that regional groundwater flow from the piedmont groundwater recharge zone predominantly discharges at the coastline may therefore be false. A more reliable alternative might be to conceptualize deep groundwater below the coastal plains a hydrodynamically stagnant zone, responding gradually to landscape and hydrological change on geologic timescales. This study brings a new and original understanding of the groundwater flow system in an important regional basin, in the context of its geometry and evolution over geological timescales. There are important implications for the sustainability of the ongoing high rates of groundwater extraction in the NCB.

Hydrochemical processes and evolution of karst groundwater in the northeastern Huaibei Plain, China

NASA Astrophysics Data System (ADS)

Qian, Jiazhong; Peng, Yinxue; Zhao, Weidong; Ma, Lei; He, Xiaorui; Lu, YueHan

2018-06-01

Major ion geochemistry reveals that the hydrochemical evolutionary process of karst groundwater in the northeastern Huaibei Plain, China, consists of three sub-processes: the dissolution of dolomite, gypsum dissolution with dedolomitization, and mixing with overlying pore water. Understanding hydrochemical evolution has been an important topic in understanding the history, status, and dynamics of the groundwater flow system. The presented study found a hydrochemical boundary roughly corresponding to the thickness of overlying strata equating to 50 m depth, indicating two flow compartments participating in different hydrological cycles—a local shallow rapidly replenished compartment showing lower and more stable main ion concentrations, and a regional deep-flow compartment showing higher and sporadic concentrations of Na+, K+, Ca2+, Mg2+, Cl- and SO4 2-, as well as high total dissolved solids (TDS), total hardness, and sodium adsorption ratio (SAR). In areas with aquifers with low water transmitting ability, groundwater samples show a high chloride ratio and elevated TDS values, indicating salinization of groundwater due to stagnant water flows. Analyses of the data on the saturation indexes and mineral solutions, in tandem with trilinear diagram analysis and petrological observations, indicate that dedolomitization is the dominant process controlling the chemical characteristics of karst groundwater in the study area. Groundwater and pore-water mixing was also observed at the later evolutionary stage of groundwater flow, demonstrating frequent groundwater/pore-water interactions where groundwater is recharged by pore water due to lower groundwater level in the study area.

Evolution of Unsteady Groundwater Flow Systems

NASA Astrophysics Data System (ADS)

Liang, Xing; Jin, Menggui; Niu, Hong

2016-04-01

Natural groundwater flow is usually transient, especially in long time scale. A theoretical approach on unsteady groundwater flow systems was adopted to highlight some of the knowledge gaps in the evolution of groundwater flow systems. The specific consideration was focused on evolution of groundwater flow systems from unsteady to steady under natural and mining conditions. Two analytical solutions were developed, using segregation variable method to calculate the hydraulic head under steady and unsteady flow conditions. The impact of anisotropy ratio, hydraulic conductivity (K) and specific yield (μs) on the flow patterns were analyzed. The results showed that the area of the equal velocity region increased and the penetrating depth of the flow system decreased while the anisotropy ratio (ɛ = °Kx-/Kz--) increased. Stagnant zones were found in the flow field where the directions of streamlines were opposite. These stagnant zones moved up when the horizontal hydraulic conductivity increased. The results of the study on transient flow indicated a positive impact on hydraulic head with an increase of hydraulic conductivity, while a negative effect on hydraulic head was observed when the specific yield was enhanced. An unsteady numerical model of groundwater flow systems with annual periodic recharge was developed using MODFLOW. It was observed that the transient groundwater flow patterns were different from that developed in the steady flow under the same recharge intensity. The water table fluctuated when the recharge intensity altered. The monitoring of hydraulic head and concentration migration revealed that the unsteady recharge affected the shallow local flow system more than the deep regional flow system. The groundwater flow systems fluctuated with the action of one or more pumping wells. The comparison of steady and unsteady groundwater flow observation indicated that the unsteady flow patterns cannot be simulated by the steady model when the condition changes frequently. This study was financially supported by National Natural Science Foundation of China (U1403282 & 41272258).

Modelling the role of groundwater hydro-refugia in East African hominin evolution and dispersal

PubMed Central

Cuthbert, M. O.; Gleeson, T.; Reynolds, S. C.; Bennett, M. R.; Newton, A. C.; McCormack, C. J.; Ashley, G. M.

2017-01-01

Water is a fundamental resource, yet its spatiotemporal availability in East Africa is poorly understood. This is the area where most hominin first occurrences are located, and consequently the potential role of water in hominin evolution and dispersal remains unresolved. Here, we show that hundreds of springs currently distributed across East Africa could function as persistent groundwater hydro-refugia through orbital-scale climate cycles. Groundwater buffers climate variability according to spatially variable groundwater response times determined by geology and topography. Using an agent-based model, grounded on the present day landscape, we show that groundwater availability would have been critical to supporting isolated networks of hydro-refugia during dry periods when potable surface water was scarce. This may have facilitated unexpected variations in isolation and dispersal of hominin populations in the past. Our results therefore provide a new environmental framework in which to understand how patterns of taxonomic diversity in hominins may have developed. PMID:28556825

Modelling the role of groundwater hydro-refugia in East African hominin evolution and dispersal

NASA Astrophysics Data System (ADS)

Cuthbert, M. O.; Gleeson, T.; Reynolds, S. C.; Bennett, M. R.; Newton, A. C.; McCormack, C. J.; Ashley, G. M.

2017-05-01

Water is a fundamental resource, yet its spatiotemporal availability in East Africa is poorly understood. This is the area where most hominin first occurrences are located, and consequently the potential role of water in hominin evolution and dispersal remains unresolved. Here, we show that hundreds of springs currently distributed across East Africa could function as persistent groundwater hydro-refugia through orbital-scale climate cycles. Groundwater buffers climate variability according to spatially variable groundwater response times determined by geology and topography. Using an agent-based model, grounded on the present day landscape, we show that groundwater availability would have been critical to supporting isolated networks of hydro-refugia during dry periods when potable surface water was scarce. This may have facilitated unexpected variations in isolation and dispersal of hominin populations in the past. Our results therefore provide a new environmental framework in which to understand how patterns of taxonomic diversity in hominins may have developed.

Hydrogeologic considerations for an interstate ground-water compact on the Madison aquifer, northern Great Plains

USGS Publications Warehouse

Konikow, Leonard F.

1978-01-01

The development of an interstate ground-water compact for the Madison aquifer in the Northern Great Plains may provide a framework to allocate equitably this large ground-water resource while avoiding possible future interstate legal conflicts. However, some technical problems will have to be resolved first. A compact designed to regulate or to allocate the available ground water will have to be written in very precise, legally acceptable definitions. The required definitions may infer a degree of measurement accuracy that cannot be technically or economically provided. Therefore, a trade off may be required between preserving natural conditions and allowing beneficial use of the ground-water resource.

Estimation of palaeohydrochemical conditions using carbonate minerals

NASA Astrophysics Data System (ADS)

Amamiya, H.; Mizuno, T.; Iwatsuki, T.; Yuguchi, T.; Murakami, H.; Saito-Kokubu, Y.

2014-12-01

The long-term evolution of geochemical environment in deep underground is indispensable research subject for geological disposal of high-level radioactive waste, because the evolution of geochemical environment would impact migration behavior of radionuclides in deep underground. Many researchers have made efforts previously to elucidate the geochemical environment within the groundwater residence time based on the analysis of the actual groundwater. However, it is impossible to estimate the geochemical environment for the longer time scale than the groundwater residence time in this method. In this case, analysis of the chemical properties of secondary minerals are one of useful method to estimate the paleohydrochemical conditions (temperature, salinity, pH and redox potential). In particular, carbonate minerals would be available to infer the long-term evolution of hydrochemical for the following reasons; -it easily reaches chemical equilibrium with groundwater and precipitates in open space of water flowing path -it reflects the chemical and isotopic composition of groundwater at the time of crystallization We reviewed the previous studies on carbonate minerals and geochemical conditions in deep underground and estimated the hydrochemical characteristics of past groundwater by using carbonate minerals. As a result, it was found that temperature and salinity of the groundwater during crystallization of carbonate minerals were evaluated quantitatively. On the other hand, pH and redox potential can only be understood qualitatively. However, it is suggested that the content of heavy metal elements such as manganese, iron and uranium, and rare earth elements in the carbonate minerals are useful indicators for estimating redox potential. This study was carried out under a contract with METI (Ministry of Economy, Trade and Industry) as part of its R&D supporting program for developing geological disposal technology.

Hydrochemical evolution of regional groundwaters to playa brines in central Australia

NASA Astrophysics Data System (ADS)

Jankowski, J.; Jacobson, G.

A large-scale groundwater system in central Australia discharges to a chain of playas. Recharge in calcrete and fractured rock aquifers gives rise to relatively low-salinity HCO 3 Cl SO 4 groundwaters, which evolve through regional saline groundwaters, to highly saline playa brines. The hydrochemical evolution of the groundwaters follows the anionic sequence HCO 3 Cl SO 4 → ClbHCO 3SO 4 → ClSO 4HCO 3 → ClSO 4 → Cl. With increasing salinity, there is a relative increase in Na, K, Mg, Cl and SO 4; however, there is a relative decrease in HCO 3, Ca, and SiO 2 owing to the precipitation of carbonate, sulphate and silicate minerals, and the resultant brines are depleted in these ions. Significant chemical variation in the composition of playa brines is a result of complex processes of solution, evaporative concentration, precipitation and mineralogical change, including dolomitisation. Thermodynamic calculations based on the Pitzer equations have enabled a general model to be developed for these evolutionary processes in saline groundwaters up to the stage of halite saturation. At an early stage the regional groundwaters are saturated with respect to the carbonate minerals, dolomite first, then calcite. With increasing salinity, sulphate minerals begin to precipitate: saturation with respect to gypsum is attained at a chlorinity of 19‰, and saturation with respect to anhydrite is attained at 122‰. The playa brines attain saturation with respect to halite at a chlorinity of 144‰. Solute budgets based on a chloride concentration factor show that final playa brines are 178 times more concentrated than recharge groundwaters, and confirm the virtually complete loss of HCO 3, Ca and SiO 2 through precipitation. There are subtle differences in the hydrochemistry of different central Australian playa brines and also vis-à-vis playa brines described from other parts of the world. Most Australian playas have brines of the ClNa type with SO 4 and Mg also important. The generally accepted Hardie-Eugster model for brine evolution and mineral precipitation sequences has therefore been modified and extended. Three pathways are defined, following calcite precipitation, on the basis of the ratio of molar Ca to alkalinity; these pathways lead to saline waters with different compositions. Subsequent evolution of the brines depends on the ratios between molar SO 4, Mg, Ca and alkalinity.

Carbon dynamics in a Late Quaternary-age coastal limestone aquifer system undergoing saltwater intrusion.

PubMed

Bryan, Eliza; Meredith, Karina T; Baker, Andy; Andersen, Martin S; Post, Vincent E A

2017-12-31

This study investigates the inorganic and organic aspects of the carbon cycle in groundwaters throughout the freshwater lens and transition zone of a carbonate island aquifer and identifies the transformation of carbon throughout the system. We determined 14 C and 13 C carbon isotope values for both DIC and DOC in groundwaters, and investigated the composition of DOC throughout the aquifer. In combination with hydrochemical and 3 H measurements, the chemical evolution of groundwaters was then traced from the unsaturated zone to the deeper saline zone. The data revealed three distinct water types: Fresh (F), Transition zone 1 (T1) and Transition zone 2 (T2) groundwaters. The 3 H values in F and T1 samples indicate that these groundwaters are mostly modern. 14 C DOC values are higher than 14 C DIC values and are well correlated with 3 H values. F and T1 groundwater geochemistry is dominated by carbonate mineral recrystallisation reactions that add dead carbon to the groundwater. T2 groundwaters are deeper, saline and characterised by an absence of 3 H, lower 14 C DOC values and a different DOC composition, namely a higher proportion of Humic Substances relative to total DOC. The T2 groundwaters are suggested to result from either the slow circulation of water within the seawater wedge, or from old remnant seawater caused by past sea level highstands. While further investigations are required to identify the origin of the T2 groundwaters, this study has identified their occurrence and shown that they did not evolve along the same pathway as fresh groundwaters. This study has also shown that a combined approach using 14 C and 13 C carbon isotope values for both DIC and DOC and the composition of DOC, as well as hydrochemical and 3 H measurements, can provide invaluable information regarding the transformation of carbon in a groundwater system and the evolution of fresh groundwater recharge. Copyright © 2017 Elsevier B.V. All rights reserved.

Identifying the hydrochemical characteristics of rivers and groundwater by multivariate statistical analysis in the Sanjiang Plain, China

NASA Astrophysics Data System (ADS)

Cao, Yingjie; Tang, Changyuan; Song, Xianfang; Liu, Changming; Zhang, Yinghua

2016-06-01

Two multivariate statistical technologies, factor analysis (FA) and discriminant analysis (DA), are applied to study the river and groundwater hydrochemistry and its controlling processes in the Sanjiang Plain of the northeast China. Factor analysis identifies five factors which account for 79.65 % of the total variance in the dataset. Four factors bearing specific meanings as the river and groundwater hydrochemistry controlling processes are divided into two groups, the "natural hydrochemistry evolution" group and the "pollution" group. The "natural hydrochemistry evolution" group includes the salinity factor (factor 1) caused by rock weathering and the residence time factor (factor 2) reflecting the groundwater traveling time. The "pollution" group represents the groundwater quality deterioration due to geogenic pollution caused by elevated Fe and Mn (factor 3) and elevated nitrate (NO3 -) introduced by human activities such as agriculture exploitations (factor 5). The hydrochemical difference and hydraulic connection among rivers (surface water, SW), shallow groundwater (SG) and deep groundwater (DG) group are evaluated by the factor scores obtained from FA and DA (Fisher's method). It is showed that the river water is characterized as low salinity and slight pollution, and the shallow groundwater has the highest salinity and severe pollution. The SW is well separated from SG and DG by Fisher's discriminant function, but the SG and DG can not be well separated showing their hydrochemical similarities, and emphasize hydraulic connections between SG and DG.

Groundwater hydrochemistry in the active layer of the proglacial zone, Finsterwalderbreen, Svalbard

USGS Publications Warehouse

Cooper, R.J.; Wadham, J.L.; Tranter, M.; Hodgkins, R.; Peters, N.E.

2002-01-01

Glacial bulk meltwaters and active-layer groundwaters were sampled from the proglacial zone of Finsterwalderbreen during a single melt season in 1999, in order to determine the geochemical processes that maintain high chemical weathering rates in the proglacial zone of this glacier. Results demonstrate that the principle means of solute acquisition is the weathering of highly reactive moraine and fluvial active-layer sediments by supra-permafrost groundwaters. Active-layer groundwater derives from the thaw of the proglacial snowpack, buried ice and glacial bulk meltwaters. Groundwater evolves by sulphide oxidation and carbonate dissolution. Evaporation- and freeze-concentration of groundwater in summer and winter, respectively produce Mg-Ca-sulphate salts on the proglacial surface. Re-dissolution of these salts in early summer produces groundwaters that are supersaturated with respect to calcite. There is a pronounced spatial pattern to the geochemical evolution of groundwater. Close to the main proglacial channel, active layer sediments are flushed diurnally by bulk meltwaters. Here, Mg-Ca-sulphate deposits become exhausted in the early season and geochemical evolution proceeds by a combination of sulphide oxidation and carbonate dissolution. At greater distances from the channel, the dissolution of Mg-Ca-sulphate salts is a major influence and dilution by the bulk meltwaters is relatively minor. The influence of sulphate salt dissolution decreases during the sampling season, as these salts are exhausted and waters become increasingly routed by subsurface flowpaths. ?? 2002 Elsevier Science B.V. All rights reserved.

Temporal evolution of soil moisture statistical fractal and controls by soil texture and regional groundwater flow

NASA Astrophysics Data System (ADS)

Ji, Xinye; Shen, Chaopeng; Riley, William J.

2015-12-01

Soil moisture statistical fractal is an important tool for downscaling remotely-sensed observations and has the potential to play a key role in multi-scale hydrologic modeling. The fractal was first introduced two decades ago, but relatively little is known regarding how its scaling exponents evolve in time in response to climatic forcings. Previous studies have neglected the process of moisture re-distribution due to regional groundwater flow. In this study we used a physically-based surface-subsurface processes model and numerical experiments to elucidate the patterns and controls of fractal temporal evolution in two U.S. Midwest basins. Groundwater flow was found to introduce large-scale spatial structure, thereby reducing the scaling exponents (τ), which has implications for the transferability of calibrated parameters to predict τ. However, the groundwater effects depend on complex interactions with other physical controls such as soil texture and land use. The fractal scaling exponents, while in general showing a seasonal mode that correlates with mean moisture content, display hysteresis after storm events that can be divided into three phases, consistent with literature findings: (a) wetting, (b) re-organizing, and (c) dry-down. Modeling experiments clearly show that the hysteresis is attributed to soil texture, whose "patchiness" is the primary contributing factor. We generalized phenomenological rules for the impacts of rainfall, soil texture, groundwater flow, and land use on τ evolution. Grid resolution has a mild influence on the results and there is a strong correlation between predictions of τ from different resolutions. Overall, our results suggest that groundwater flow should be given more consideration in studies of the soil moisture statistical fractal, especially in regions with a shallow water table.

Assessment of Groundwater Susceptibility to Non-Point Source Contaminants Using Three-Dimensional Transient Indexes.

PubMed

Zhang, Yong; Weissmann, Gary S; Fogg, Graham E; Lu, Bingqing; Sun, HongGuang; Zheng, Chunmiao

2018-06-05

Groundwater susceptibility to non-point source contamination is typically quantified by stable indexes, while groundwater quality evolution (or deterioration globally) can be a long-term process that may last for decades and exhibit strong temporal variations. This study proposes a three-dimensional (3- d ), transient index map built upon physical models to characterize the complete temporal evolution of deep aquifer susceptibility. For illustration purposes, the previous travel time probability density (BTTPD) approach is extended to assess the 3- d deep groundwater susceptibility to non-point source contamination within a sequence stratigraphic framework observed in the Kings River fluvial fan (KRFF) aquifer. The BTTPD, which represents complete age distributions underlying a single groundwater sample in a regional-scale aquifer, is used as a quantitative, transient measure of aquifer susceptibility. The resultant 3- d imaging of susceptibility using the simulated BTTPDs in KRFF reveals the strong influence of regional-scale heterogeneity on susceptibility. The regional-scale incised-valley fill deposits increase the susceptibility of aquifers by enhancing rapid downward solute movement and displaying relatively narrow and young age distributions. In contrast, the regional-scale sequence-boundary paleosols within the open-fan deposits "protect" deep aquifers by slowing downward solute movement and displaying a relatively broad and old age distribution. Further comparison of the simulated susceptibility index maps to known contaminant distributions shows that these maps are generally consistent with the high concentration and quick evolution of 1,2-dibromo-3-chloropropane (DBCP) in groundwater around the incised-valley fill since the 1970s'. This application demonstrates that the BTTPDs can be used as quantitative and transient measures of deep aquifer susceptibility to non-point source contamination.

Infrastructure design integration to optimize structures and minimize groundwater impacts. Case of a bottom slab and groundwater by-pass integration in La Sagrera railway station, Spain.

NASA Astrophysics Data System (ADS)

Serrano Juan, Alejandro; Vázquez-Suñè, Enric; Pujades, Estanislao; Velasco, Violeta; Criollo, Rotman; Jurado, Anna

2016-04-01

Underground constructions search the most efficient solutions to increase safety, reduce impacts in both underground construction (such as bottom slab water pressures) and groundwater (such as groundwater barrier effect), reduce future maintenance processes and ensure that everything is implemented by the minimum cost. Even being all the previous solutions directly related to groundwater, independent solutions are usually designed to independently deal with each problem. This paper shows how with a groundwater by-pass design that enables the groundwater flow through the structure it is possible to provide an homogeneous distribution of the water pressures under the bottom slab and reduce the barrier effect produced by the structure. The new integrated design has been applied to the largest infrastructure of Barcelona: La Sagrera railway station. Through a hydrogeological model has been possible to test the project and the integrated designs in three different scenarios. This new solution resolves the barrier effect produced by the structure and optimizes the bottom slab, reducing considerably the costs and increasing safety during the construction phase.

Kinetic and mineralogic controls on the evolution of groundwater chemistry and 87Sr/86Sr in a sandy silicate aquifer, northern Wisconsin, USA

USGS Publications Warehouse

Bullen, T.D.; Krabbenhoft, D.P.; Kendall, C.

1996-01-01

Substantial flowpath-related variability of 87Sr/86Sr is observed in groundwaters collected from the Trout Lake watershed of northern Wisconsin. In the extensive shallow aquifer composed of sandy glacial outwash, groundwater is recharged either by seepage from lakes or by precipitation that infiltrates the inter-lake uplands. 87Sr/86Sr of groundwater derived mainly as seepage from a precipitation-dominated lake near the head of the watershed decreases with progressive water chemical evolution along its flowpath due primarily to enhanced dissolution of relatively unradiogenic plagioclase. In contrast, 87Sr/86Sr of groundwater derived mainly from precipitation that infiltrates upland areas is substantially greater than that of precipitation collected from the watershed, due to suppression of plagioclase dissolution together with preferential leaching of Sr from radiogenic phases such as K-feldspar and biotite. The results of a column experiment that simulated the effects of changing residence time of water in the aquifer sand indicate that mobile waters obtain relatively unradiogenic Sr, whereas stagnant waters obtain relatively radiogenic Sr. Nearly the entire range of strontium-isotope composition observed in groundwaters from the watershed was measured in the experimental product waters. The constant mobility of water along groundwater recharge flowpaths emanating from the lakes promotes the dissolution of relatively unradiogenic plagioclase, perhaps due to effective dispersal of clay mineral nuclei resulting from dissolution reactions. In contrast, episodic stagnation in the unsaturated zone along the upland recharge flowpaths suppresses plagioclase dissolution, perhaps due to accumulation of clay mineral nuclei on its reactive surfaces. Differences in redox conditions along these contrasting flowpaths probably enhance the observed differences in strontium isotope behavior. This study demonstrates that factors other than the calculated state of mineral saturation must be considered when attempting to simulate chemical evolution along flowpaths, and that reaction models must be able to incorporate changing contributions from reacting minerals in the calculations.

Effect of emplaced nZVI mass and groundwater velocity on PCE dechlorination and hydrogen evolution in water-saturated sand.

PubMed

Kim, Hye-Jin; Leitch, Megan; Naknakorn, Bhanuphong; Tilton, Robert D; Lowry, Gregory V

2017-01-15

The effect of nZVI mass loading and groundwater velocity on the tetrachloroethylene (PCE) dechlorination rate and the hydrogen evolution rate for poly(maleic acid-co-olefin) (MW=12K) coated nZVI was examined. In batch reactors, the PCE reaction rate constant (3.7×10 -4 Lhr -1 m -2 ) and hydrogen evolution rate constant (1.4 nanomolLhr -1 m -2 ) were independent of nZVI concentration above 10g/L, but the PCE dechlorination rate decreased and the hydrogen evolution rate increased for nZVI concentration below 10g/L. The nonlinearity between nZVI mass loading and PCE dechlorination and H 2 evolution was explained by differences in pH and E h at each nZVI mass loading; PCE reactivity increased when solution E h decreased, and the H 2 evolution rate increased with decreasing pH. Thus, nZVI mass loading of <5g/L yields lower reactivity with PCE and lower efficiency of Fe° utilization than for higher nZVI mass loading. The PCE dechlorination rate increased with increasing pore-water velocity, suggesting that mass transfer limits the reaction at low porewater velocity. Overall, this work suggests that design of nZVI-based reactive barriers for groundwater treatment should consider the non-linear effects of both mass loading and flow velocity on performance and expected reactive lifetime. Copyright © 2016 Elsevier B.V. All rights reserved.

Changes in sources and storage in a karst aquifer during a transition from drought to wet conditions

USGS Publications Warehouse

Wong, C.I.; Mahler, B.J.; Musgrove, M.; Banner, J.L.

2012-01-01

Understanding the sources and processes that control groundwater compositions and the timing and magnitude of groundwater vulnerability to potential surface-water contamination under varying meteorologic conditions is critical to informing groundwater protection policies and practices. This is especially true in karst terrains, where infiltrating surface water can rapidly affect groundwater quality. We analyzed the evolution of groundwater compositions (major ions and Sr isotopes) during the transition from extreme drought to wetconditions, and used inverse geochemical modeling (PHREEQC) to constrain controls on groundwater compositions during this evolution. Spring water and groundwater from two wells dominantly receiving diffuse and conduit flow (termed diffuse site and conduit site, respectively) in the Barton Springs segment of the Edwards aquifer (central Texas, USA) and surface water from losing streams that recharge the aquifer were sampled every 3–4 weeks during November 2008–March 2010. During this period, water compositions at the spring and conduit sites changed rapidly but there was no change at the diffuse site, illustrating the dual nature (i.e., diffuse vs. conduit) of flow in this karst system. Geochemical modeling demonstrated that, within a month of the onset of wetconditions, the majority of spring water and groundwater at the conduit site was composed of surface water, providing quantitative information on the timing and magnitude of the vulnerability of groundwater to potential surface-water contamination. The temporal pattern of increasing spring discharge and changing pattern of covariation between spring discharge and surface-water (steam) recharge indicates that that there were two modes of aquifer response—one with a small amount of storage and a second that accommodates more storage.

Sample support and resistivity imaging interpretation

NASA Astrophysics Data System (ADS)

Bentley, L. R.; Gharibi, M.

2003-04-01

Three-D Electrical Resistivity Imaging (ERI) is a powerful technique that can be used to improve site characterization. In order to integrate ERI with other site characterization measurements such as soil and water chemistry, it is necessary to understand the sample support of various data. We have studied a decommissioned sour gas processing plant which has experienced releases of glycol and amine. Ammonium and acetic acid are degradation products that cause elevated electrical conductivity (EC) in groundwater and soils.The site is underlain by glacial till that is fractured and has thin sand lenses. 3-D ERI inversion results, direct push tool EC and core EC from the same location are well correlated. However, groundwater EC from piezometer installations are poorly correlated with ERI EC. We hypothesize that the ERI, direct push and core EC are mainly meausuring relatively immobile pore water EC in the fine grain matrix. Piezometer water is derived from mobile groundwater that travels in preferred flow paths such as fractures and higher permeability sand lenses. Due to dewatering and other remediation efforts, the mobile groundwater can have a different chemistry, concentration and EC than the immobile pore water. Consequently, the sample support is different for the groundwater samples and the difference explains the poor correlation between ERI EC and groundwater sample EC. In this particular case, we have the potential to monitor the chemical evolution of the source areas, but cannot use ERI to monitor the chemical evolution of mobile groundwater.

Lateral Gene Transfer in a Heavy Metal-Contaminated-Groundwater Microbial Community

PubMed Central

Hemme, Christopher L.; Green, Stefan J.; Rishishwar, Lavanya; Prakash, Om; Pettenato, Angelica; Chakraborty, Romy; Deutschbauer, Adam M.; Van Nostrand, Joy D.; Wu, Liyou; He, Zhili; Jordan, I. King; Arkin, Adam P.; Kostka, Joel E.

2016-01-01

ABSTRACT Unraveling the drivers controlling the response and adaptation of biological communities to environmental change, especially anthropogenic activities, is a central but poorly understood issue in ecology and evolution. Comparative genomics studies suggest that lateral gene transfer (LGT) is a major force driving microbial genome evolution, but its role in the evolution of microbial communities remains elusive. To delineate the importance of LGT in mediating the response of a groundwater microbial community to heavy metal contamination, representative Rhodanobacter reference genomes were sequenced and compared to shotgun metagenome sequences. 16S rRNA gene-based amplicon sequence analysis indicated that Rhodanobacter populations were highly abundant in contaminated wells with low pHs and high levels of nitrate and heavy metals but remained rare in the uncontaminated wells. Sequence comparisons revealed that multiple geochemically important genes, including genes encoding Fe2+/Pb2+ permeases, most denitrification enzymes, and cytochrome c553, were native to Rhodanobacter and not subjected to LGT. In contrast, the Rhodanobacter pangenome contained a recombinational hot spot in which numerous metal resistance genes were subjected to LGT and/or duplication. In particular, Co2+/Zn2+/Cd2+ efflux and mercuric resistance operon genes appeared to be highly mobile within Rhodanobacter populations. Evidence of multiple duplications of a mercuric resistance operon common to most Rhodanobacter strains was also observed. Collectively, our analyses indicated the importance of LGT during the evolution of groundwater microbial communities in response to heavy metal contamination, and a conceptual model was developed to display such adaptive evolutionary processes for explaining the extreme dominance of Rhodanobacter populations in the contaminated groundwater microbiome. PMID:27048805

Agriculture and groundwater nitrate contamination in the Seine basin. The STICS-MODCOU modelling chain.

PubMed

Ledoux, E; Gomez, E; Monget, J M; Viavattene, C; Viennot, P; Ducharne, A; Benoit, M; Mignolet, C; Schott, C; Mary, B

2007-04-01

A software package is presented here to predict the fate of nitrogen fertilizers and the transport of nitrate from the rooting zone of agricultural areas to surface water and groundwater in the Seine basin, taking into account the long residence times of water and nitrate in the unsaturated and aquifer systems. Information on pedological characteristics, land use and farming practices is used to determine the spatial units to be considered. These data are converted into input data for the crop model STICS which simulates the water and nitrogen balances in the soil-plant system with a daily time-step. A spatial application of STICS has been derived at the catchment scale which computes the water and nitrate fluxes at the bottom of the rooting zone. These fluxes are integrated into a surface and groundwater coupled model MODCOU which calculates the daily water balance in the hydrological system, the flow in the rivers and the piezometric variations in the aquifers, using standard climatic data (rainfall, PET). The transport of nitrate and the evolution of nitrate contamination in groundwater and to rivers is computed by the model NEWSAM. This modelling chain is a valuable tool to predict the evolution of crop productivity and nitrate contamination according to various scenarios modifying farming practices and/or climatic changes. Data for the period 1970-2000 are used to simulate the past evolution of nitrogen contamination. The method has been validated using available data bases of nitrate concentrations in the three main aquifers of the Paris basin (Oligocene, Eocene and chalk). The approach has then been used to predict the future evolution of nitrogen contamination up to 2015. A statistical approach allowed estimating the probability of transgression of different concentration thresholds in various areas in the basin. The model is also used to evaluate the cost of the damage resulting of the treatment of drinking water at the scale of a groundwater management unit in the Seine river basin.

Hydrochemical evolution and groundwater flow processes in the Galilee and Eromanga basins, Great Artesian Basin, Australia: a multivariate statistical approach.

PubMed

Moya, Claudio E; Raiber, Matthias; Taulis, Mauricio; Cox, Malcolm E

2015-03-01

The Galilee and Eromanga basins are sub-basins of the Great Artesian Basin (GAB). In this study, a multivariate statistical approach (hierarchical cluster analysis, principal component analysis and factor analysis) is carried out to identify hydrochemical patterns and assess the processes that control hydrochemical evolution within key aquifers of the GAB in these basins. The results of the hydrochemical assessment are integrated into a 3D geological model (previously developed) to support the analysis of spatial patterns of hydrochemistry, and to identify the hydrochemical and hydrological processes that control hydrochemical variability. In this area of the GAB, the hydrochemical evolution of groundwater is dominated by evapotranspiration near the recharge area resulting in a dominance of the Na-Cl water types. This is shown conceptually using two selected cross-sections which represent discrete groundwater flow paths from the recharge areas to the deeper parts of the basins. With increasing distance from the recharge area, a shift towards a dominance of carbonate (e.g. Na-HCO3 water type) has been observed. The assessment of hydrochemical changes along groundwater flow paths highlights how aquifers are separated in some areas, and how mixing between groundwater from different aquifers occurs elsewhere controlled by geological structures, including between GAB aquifers and coal bearing strata of the Galilee Basin. The results of this study suggest that distinct hydrochemical differences can be observed within the previously defined Early Cretaceous-Jurassic aquifer sequence of the GAB. A revision of the two previously recognised hydrochemical sequences is being proposed, resulting in three hydrochemical sequences based on systematic differences in hydrochemistry, salinity and dominant hydrochemical processes. The integrated approach presented in this study which combines different complementary multivariate statistical techniques with a detailed assessment of the geological framework of these sedimentary basins, can be adopted in other complex multi-aquifer systems to assess hydrochemical evolution and its geological controls. Copyright © 2014 Elsevier B.V. All rights reserved.

New insights into nitrate dynamics in a karst groundwater system gained from in situ high-frequency optical sensor measurements

USGS Publications Warehouse

Opsahl, Stephen P.; Musgrove, MaryLynn; Slattery, Richard N.

2017-01-01

Understanding nitrate dynamics in groundwater systems as a function of climatic conditions, especially during contrasting patterns of drought and wet cycles, is limited by a lack of temporal and spatial data. Nitrate sensors have the capability for making accurate, high-frequency measurements of nitrate in situ, but have not yet been evaluated for long-term use in groundwater wells. We measured in situ nitrate continuously in two groundwater monitoring wells —one rural and one urban—located in the recharge zone of a productive karst aquifer in central Texas in order to resolve changes that occur over both short-term (hourly to daily) and long-term (monthly to yearly) periods. Nitrate concentrations, measured as nitrate-nitrogen in milligrams per liter (mg/L), during drought conditions showed little or no temporal change as groundwater levels declined. During aquifer recharge, extremely rapid changes in concentration occurred at both wells as documented by hourly data. At both sites, nitrate concentrations were affected by recharging surface water as evidenced by nitrate concentrations in groundwater recharge (0.8–1.3 mg/L) that were similar to previously reported values for regional recharging streams. Groundwater nitrate concentrations responded differently at urban and rural sites during groundwater recharge. Concentrations at the rural well (approximately 1.0 mg/L) increased as a result of higher nitrate concentrations in groundwater recharge relative to ambient nitrate concentrations in groundwater, whereas concentrations at the urban well (approximately 2.7 mg/L) decreased as a result of the dilution of higher ambient nitrate concentrations relative to those in groundwater recharge. Notably, nitrate concentrations decreased to as low as 0.8 mg/L at the urban site during recharge but postrecharge concentrations exceeded 3.0 mg/L. A return to higher nitrate concentrations postrecharge indicates mobilization of a localized source of elevated nitrate within the urbanized area of the aquifer. Changes in specific conductance were observed at both sites during groundwater recharge, and a significant correlation between specific conductance and nitrate (correlation coefficient [R] = 0.455) was evident at the urban site where large (3-fold) changes in nitrate occurred. Nitrate concentrations and specific conductance measured during a depth profile indicated that the water column was generally homogeneous as expected for this karst environment, but changes were observed in the most productive zone of the aquifer that might indicate some heterogeneity within the complex network of flow paths. Resolving the timing and magnitude of changes and characterizing fine-scale vertical differences would not be possible using conventional sampling techniques. The patterns observed in situ provided new insight into the dynamic nature of nitrate in a karst groundwater system.

Summary appraisals of the Nation's ground-water resources; South Atlantic Gulf region

USGS Publications Warehouse

Cederstrom, D.J.; Boswell, E.H.; Tarver, G.R.

1979-01-01

Ground-water problems generally are not severe. Critical situations are restricted to areas where large quantities of ground water are being withdrawn or where aquifers are contaminated by oil-field or industrial waste. Large withdrawals in coastal areas have caused some saltwater intrusion. In other localities, highly mineralized water may have migrated along fault zones to freshwater aquifers. Many of the present problems can be resolved or ameliorated by redistributing withdrawals or developing alternative water sources.

Application of groundwater residence time tracers and broad screening for micro-organic contaminants in the Indo-Gangetic aquifer system

NASA Astrophysics Data System (ADS)

Lapworth, Dan; Das, Prerona; Mukherjee, Abhijit; Petersen, Jade; Gooddy, Daren; Krishan, Gopal

2017-04-01

Groundwater abstracted from aquifers underlying urban centres across India provide a vital source of domestic water. Abstraction from municipal and private supplies is considerable and growing rapidly with ever increasing demand for water from expanding urban populations. This trend is set to continue. The vulnerability of deeper aquifers (typically >100 m below ground) used for domestic water to contamination migration from often heavily contaminated shallow aquifer systems has not been studies in detail in India. This paper focusses on the occurrence of micro-organic contaminants within sedimentary aquifers beneath urban centres which are intensively pumped for drinking water and domestic use. New preliminary results from a detailed case study undertaken across Varanasi, a city with an estimated population of ca. 1.5 million in Uttar Pradesh. Micro -organic groundwater quality status and evolution with depth is investigated through selection of paired shallow and deep sites across the city. These results are considered within the context of paired groundwater residence time tracers within the top 150m within the sedimentary aquifer system. Groundwater emerging contaminant results are compared with surface water quality from the Ganges which is also used for drinking water supply. Broad screening for >800 micro-organic compounds was undertaken. Age dating tools were employed to constrain and inform a conceptual model of groundwater recharge and contaminant evolution within the sedimentary aquifer system.

The 3-D structure of the Somma-Vesuvius volcanic complex (Italy) inferred from new and historic gravimetric data.

PubMed

Linde, Niklas; Ricci, Tullio; Baron, Ludovic; Shakas, Alexis; Berrino, Giovanna

2017-08-16

Existing 3-D density models of the Somma-Vesuvius volcanic complex (SVVC), Italy, largely disagree. Despite the scientific and socioeconomic importance of Vesuvius, there is no reliable 3-D density model of the SVVC. A considerable uncertainty prevails concerning the presence (or absence) of a dense body underlying the Vesuvius crater (1944 eruption) that is implied from extensive seismic investigations. We have acquired relative gravity measurements at 297 stations, including measurements in difficult-to-access areas (e.g., the first-ever measurements in the crater). In agreement with seismic investigations, the simultaneous inversion of these and historic data resolves a high-density body that extends from the surface of the Vesuvius crater down to depths that exceed 2 km. A 1.5-km radius horseshoe-shaped dense feature (open in the southwestern sector) enforces the existing model of groundwater circulation within the SVVC. Based on its volcano-tectonic evolution, we interpret volcanic structures that have never been imaged before.

Estimating 14C groundwater ages in a methanogenic aquifer

USGS Publications Warehouse

Aravena, Ramon; Wassenaar, Leonard I; Plummer, Niel

1995-01-01

This paper addresses the problem of 14C age dating of groundwaters in a confined regional aquifer affected by methanogenesis. Increasing CH4 concentrations along the groundwater flow system and 13C and 14C isotopic data for dissolved inorganic carbon, dissolved organic carbon, and CH4 clearly show the effect of methanogenesis on groundwater chemistry. Inverse reaction path modeling using NETPATH indicates the predominant geochemical reactions controlling the chemical evolution of groundwater in the aquifer are incongruent dissolution of dolomite, ion exchange, methanogenesis, and oxidation of sedimentary organic matter. Modeling of groundwater 14C ages using NETPATH indicates that a significant part of groundwater in the Alliston aquifer is less than 13,000 years old; however, older groundwater in the range of 15,000–23,000 years is also present in the aquifer. This paper demonstrates that 14C ages calculated using NETPATH, incorporating the effects of methanogenesis on the carbon pools, provide reasonable groundwater ages that were not possible by other isotopic methods.

Geochemical evolution processes and water-quality observations based on results of the National Water-Quality Assessment Program in the San Antonio segment of the Edwards aquifer, 1996-2006

USGS Publications Warehouse

Musgrove, MaryLynn; Fahlquist, Lynne; Houston, Natalie A.; Lindgren, Richard J.; Ging, Patricia B.

2010-01-01

As part of the National Water-Quality Assessment Program, the U.S. Geological Survey collected and analyzed groundwater samples during 1996-2006 from the San Antonio segment of the Edwards aquifer of central Texas, a productive karst aquifer developed in Cretaceous-age carbonate rocks. These National Water-Quality Assessment Program studies provide an extensive dataset of groundwater geochemistry and water quality, consisting of 249 groundwater samples collected from 136 sites (wells and springs), including (1) wells completed in the shallow, unconfined, and urbanized part of the aquifer in the vicinity of San Antonio (shallow/urban unconfined category), (2) wells completed in the unconfined (outcrop area) part of the regional aquifer (unconfined category), and (3) wells completed in and springs discharging from the confined part of the regional aquifer (confined category). This report evaluates these data to assess geochemical evolution processes, including local- and regional-scale processes controlling groundwater geochemistry, and to make water-quality observations pertaining to sources and distribution of natural constituents and anthropogenic contaminants, the relation between geochemistry and hydrologic conditions, and groundwater age tracers and travel time. Implications for monitoring water-quality trends in karst are also discussed. Geochemical and isotopic data are useful tracers of recharge, groundwater flow, fluid mixing, and water-rock interaction processes that affect water quality. Sources of dissolved constituents to Edwards aquifer groundwater include dissolution of and geochemical interaction with overlying soils and calcite and dolomite minerals that compose the aquifer. Geochemical tracers such as magnesium to calcium and strontium to calcium ratios and strontium isotope compositions are used to evaluate and constrain progressive fluid-evolution processes. Molar ratios of magnesium to calcium and strontium to calcium in groundwater typically increase along flow paths; results for samples of Edwards aquifer groundwater show an increase from shallow/urban unconfined, to unconfined, to confined groundwater categories. These differences are consistent with longer residence times and greater extents of water-rock interaction controlling fluid compositions as groundwater evolves from shallow unconfined groundwater to deeper confined groundwater. Results for stable isotopes of hydrogen and oxygen indicate specific geochemical processes affect some groundwater samples, including mixing with downdip saline water, mixing with recent recharge associated with tropical cyclonic storms, or mixing with recharge water than has undergone evaporation. The composition of surface water recharging the aquifer, as well as mixing with downdip water from the Trinity aquifer or the saline zone, also might affect water quality. A time-series record (1938-2006) of discharge at Comal Springs, one of the major aquifer discharge points, indicates an upward trend for nitrate and chloride concentrations, which likely reflects anthropogenic activities. A small number of organic contaminants were routinely or frequently detected in Edwards aquifer groundwater samples. These were the pesticides atrazine, its degradate deethylatrazine, and simazine; the drinking-water disinfection byproduct chloroform; and the solvent tetrachloroethene. Detection of these contaminants was most frequent in samples of the shallow/urban unconfined groundwater category and least frequent in samples of the unconfined groundwater category. Results indicate that the shallow/urban unconfined part of the aquifer is most affected by anthropogenic contaminants and the unconfined part of the aquifer is the least affected. The high frequency of detection for these anthropogenic contaminants aquifer-wide and in samples of deep, confined groundwater indicates that the entire aquifer is susceptible to water-quality changes as a result of anthropogenic activities. L

Comparative study of urban development and groundwater condition in coastal areas of Buenos Aires, Argentina

NASA Astrophysics Data System (ADS)

Rodrigues Capítulo, Leandro; Carretero, Silvina C.; Kruse, Eduardo E.

2017-08-01

The geomorphological evolution of a sand-dune barrier in Buenos Aires, Argentina, is analyzed as a factor regulating the fresh groundwater reserves available. The impact of geomorphological evolution and the consequences for the social and economic development of two coastal areas are assessed. This is one of the most important tourist destinations in the country; for study purposes, it was divided into a northern sector and a southern sector. In the southern sector, the exploitable groundwater is associated with the Holocene and upper Pleistocene geomorphological evolution, which generated three interrelated aquifer units, constituting a system whose useful thickness reaches at least 45 m. In contrast, the northern sector is restricted to two Holocene aquifer units, whose total thickness is on the order of 12 m. The morphological characteristics and the occurrence of the largest fresh groundwater reserves in the southern sector are indicators of better conditions for economic growth, which is mainly reflected on the expansion of real estate ventures. The relationships of transmissivity vs area of real estate ventures (Arev), and total water consumption vs Arev, are indicators for the sustainable management of the water resources. The approach chosen may be used by decision makers in other regions to assess the feasibility of future tourism projects on the basis of the availability of water resources associated with geomorphological features.

Strategic analysis of a water rights conflict in the south western United States.

PubMed

Philpot, Simone; Hipel, Keith; Johnson, Peter

2016-09-15

A strategic analysis of the ongoing conflict between Nevada and Utah, over groundwater allocation at Snake Valley, is carried out in order to investigate ways on how to resolve this dispute. More specifically, the Graph Model for Conflict Resolution is employed to formally model and analyze this conflict using the decision support system called GMCR+. The conflict analysis findings indicate that the dispute is enduring because of a lack of incentive and opportunity for any party to move beyond the present circumstances. Continued negotiations are not likely to resolve this conflict. A substantial change in the preferences or options of the disputants, or new governance tools will be required to move this conflict forward. This may hold lessons for future groundwater conflicts. It is, however, increasingly likely that the parties will require a third party intervention, such as equal apportionment by the US Supreme Court. Copyright © 2016 Elsevier Ltd. All rights reserved.

Arsenic pollution of groundwater in Vietnam exacerbated by deep aquifer exploitation for more than a century

PubMed Central

Winkel, Lenny H. E.; Trang, Pham Thi Kim; Lan, Vi Mai; Stengel, Caroline; Amini, Manouchehr; Ha, Nguyen Thi; Viet, Pham Hung; Berg, Michael

2011-01-01

Arsenic contamination of shallow groundwater is among the biggest health threats in the developing world. Targeting uncontaminated deep aquifers is a popular mitigation option although its long-term impact remains unknown. Here we present the alarming results of a large-scale groundwater survey covering the entire Red River Delta and a unique probability model based on three-dimensional Quaternary geology. Our unprecedented dataset reveals that ∼7 million delta inhabitants use groundwater contaminated with toxic elements, including manganese, selenium, and barium. Depth-resolved probabilities and arsenic concentrations indicate drawdown of arsenic-enriched waters from Holocene aquifers to naturally uncontaminated Pleistocene aquifers as a result of > 100 years of groundwater abstraction. Vertical arsenic migration induced by large-scale pumping from deep aquifers has been discussed to occur elsewhere, but has never been shown to occur at the scale seen here. The present situation in the Red River Delta is a warning for other As-affected regions where groundwater is extensively pumped from uncontaminated aquifers underlying high arsenic aquifers or zones. PMID:21245347

Long Term Water Level and Chemistry Evolution in Groundwater of the Mississippi Embayment, Arkansas, USA: Preliminary Results

NASA Astrophysics Data System (ADS)

Neumann, K.; Dowling, C. B.; Moraru, C.; Hannigan, R. E.

2008-12-01

The Mississippi Embayment, located in the southeastern U.S., is a syncline formed by the northward excursion of the Gulf of Coastal Plain. Structurally, the Mississippi Embayment is a hydrogeological basin consisting of six regional aquifers. These productive aquifers yield good-quality waters. The Mississippi Embayment Regional Ground Water Study group located at Arkansas State University compiled and organized the available water chemistry and groundwater level data from the USGS groundwater monitoring database. The uppermost unconfined horizon forms the Mississippi River Valley Alluvial Aquifer (ALVM), one of the largest unconfined aquifers in the world. The Holocene and Pleistocene ALVM is formed from sand, gravel, and loess. The majority of the groundwater wells (approximately 80%) are drilled in the ALVM. As the groundwater levels have fallen in the unconfined ALVM, more groundwater wells are drilled in the deeper aquifers-the Upper, Middle, and Lower Claiborne Aquifers. The Ecocene Upper Claiborne Aquifer protolith is sand, silt, and clay while the Eocene Middle Claiborne and Lower Claiborne aquifers are sand and minor clay. We focused our investigation of the spatial and temporal evolution of groundwater in the Arkansas section of the Mississippi Embayment by using wells with long term monitoring records (1928 - 2005). Overall, the groundwater levels of the unconfined aquifer (ALVM) have decreased; we have not yet evaluated the lower aquifer water level changes. Attention was paid to rock-water interactions along flowpaths in the ALVM and Upper Claiborne aquifers, and to temporal changes at specific sampling sites. The study is utilizing groundwater pH, cation, anion, and nutrient data in the programs AquaChem and PHREEQE to describe mineral and CO2 saturations in groundwater. First results indicate that the modeling allows the identification of different processes (CO2 pressure, calcite saturation) that control distinct geochemical provinces, e.g. urban regions and regions dominated by river water recharge.

Chemistry of groundwater discharge inferred from longitudinal river sampling

NASA Astrophysics Data System (ADS)

Batlle-Aguilar, J.; Harrington, G. A.; Leblanc, M.; Welch, C.; Cook, P. G.

2014-02-01

We present an approach for identifying groundwater discharge chemistry and quantifying spatially distributed groundwater discharge into rivers based on longitudinal synoptic sampling and flow gauging of a river. The method is demonstrated using a 450 km reach of a tropical river in Australia. Results obtained from sampling for environmental tracers, major ions, and selected trace element chemistry were used to calibrate a steady state one-dimensional advective transport model of tracer distribution along the river. The model closely reproduced river discharge and environmental tracer and chemistry composition along the study length. It provided a detailed longitudinal profile of groundwater inflow chemistry and discharge rates, revealing that regional fractured mudstones in the central part of the catchment contributed up to 40% of all groundwater discharge. Detailed analysis of model calibration errors and modeled/measured groundwater ion ratios elucidated that groundwater discharging in the top of the catchment is a mixture of local groundwater and bank storage return flow, making the method potentially useful to differentiate between local and regional sourced groundwater discharge. As the error in tracer concentration induced by a flow event applies equally to any conservative tracer, we show that major ion ratios can still be resolved with minimal error when river samples are collected during transient flow conditions. The ability of the method to infer groundwater inflow chemistry from longitudinal river sampling is particularly attractive in remote areas where access to groundwater is limited or not possible, and for identification of actual fluxes of salts and/or specific contaminant sources.

Chemical Evolution of Groundwater Near a Sinkhole Lake, Northern Florida: 2. Chemical Patterns, Mass Transfer Modeling, and Rates of Mass Transfer Reactions

NASA Astrophysics Data System (ADS)

Katz, Brian G.; Plummer, L. Niel; Busenberg, Eurybiades; Revesz, Kinga M.; Jones, Blair F.; Lee, Terrie M.

1995-06-01

Chemical patterns along evolutionary groundwater flow paths in silicate and carbonate aquifers were interpreted using solute tracers, carbon and sulfur isotopes, and mass balance reaction modeling for a complex hydrologic system involving groundwater inflow to and outflow from a sinkhole lake in northern Florida. Rates of dominant reactions along defined flow paths were estimated from modeled mass transfer and ages obtained from CFC-modeled recharge dates. Groundwater upgradient from Lake Barco remains oxic as it moves downward, reacting with silicate minerals in a system open to carbon dioxide (CO2), producing only small increases in dissolved species. Beneath and downgradient of Lake Barco the oxic groundwater mixes with lake water leakage in a highly reducing, silicate-carbonate mineral environment. A mixing model, developed for anoxic groundwater downgradient from the lake, accounted for the observed chemical and isotopic composition by combining different proportions of lake water leakage and infiltrating meteoric water. The evolution of major ion chemistry and the 13C isotopic composition of dissolved carbon species in groundwater downgradient from the lake can be explained by the aerobic oxidation of organic matter in the lake, anaerobic microbial oxidation of organic carbon, and incongruent dissolution of smectite minerals to kaolinite. The dominant process for the generation of methane was by the CO2 reduction pathway based on the isotopic composition of hydrogen (δ2H(CH4) = -186 to -234‰) and carbon (δ13C(CH4) = -65.7 to -72.3‰). Rates of microbial metabolism of organic matter, estimated from the mass transfer reaction models, ranged from 0.0047 to 0.039 mmol L-1 yr-1 for groundwater downgradient from the lake.

Discontinuous submarine groundwater discharge in a tidally influenced coastal aquifer

NASA Astrophysics Data System (ADS)

Abarca, E.; Karam, H.; Hemond, H.; Harvey, C. F.

2011-12-01

Ocean forces have a critical impact on the magnitude and temporal evolution of Submarine Groundwater Discharge (SGD). Here, we analyze the groundwater discharge response to changes in the tidal signal at Waquoit Bay, Cape Cod, Massachusetts. We present a conceptual and numerical model that predicts that both fresh and saltwater components of SGD are interrupted by rising tides. During that period, saltwater infiltration pushes freshwater down and landward. Freshwater is stored in the aquifer, increasing the groundwater head, and is released during the receding tide. Discontinuous freshwater discharge occurs during both neap and spring tidal cycles even though the total discharge is higher during a neap tidal cycle. Evidence of this interruption of SGD can be found in geophysical and temperature measurements of the intertidal subsurface zone at Waquoit Bay. The long-term temporal and spatial evolution of fresh and saltwater fluxes shows that freshwater discharge tracks the mean and minimum tide elevation. The intertidal saltwater discharge is controlled by the high tide elevation whereas the deep saltwater discharge increases with falling low tide elevation.

Impacts of Climate Change and of Anthropisation on Water Resources: from the Risk Assessment to Adaptation, the Case of the Seine Basin (including Paris, France)

NASA Astrophysics Data System (ADS)

Habets, F.; Viennot, P.; Thierion, C.; Vergnes, J. P.; Ait Kaci, A.; Caballero, Y.

2015-12-01

The Seine river, located in the temperate climate of northern France and flowing over a large sedimentary basins that hosts multilayer aquifers, is characterized by small temporal variations of its discharge. However, the presence of a megacity (Paris) and a wide area of intensive agriculture combined with climate change puts pressure on the water resources both in terms of quality and quantity. Previous research projects have estimated the impact of climate change on the water resource of the Seine basin, with the uncertainties associated to climate projections, hydrological models or downscaling methods. The water resource was projected to decrease by -14 % ± 10 % in 2050 and -28 +/-16% in 2100. This led to new studies that focus on the combined impact of climate change and adaptations. The tested adaptations are: a reduction of the groundwater abstractions, evolution of land use, development of small dams to « harvest water » or artificial recharge of aquifers. The communication of the results of these projects to stakeholders have led to the development on new indicators that better express the risk on the water resource management, especially for the groundwater. For instance maps of the evolution of piezometric head are difficult to interpret. To better express the risk evolution, a new indicator was defined: the evolution of the groundwater crisis duration, ie, the period when the charge of the aquifer is below the crisis piezometric level defined by the stakeholders. Such crisis piezometric levels are used to help defining the period when the groundwater abstraction should be reduced. Such maps are more efficient to communicate with water resources managers. This communication will focus on the results from the MEDDE Explore 2070 and ANR Oracle projects.

Recharge processes and vertical transfer investigated through long-term monitoring of dissolved gases in shallow groundwater

NASA Astrophysics Data System (ADS)

de Montety, V.; Aquilina, L.; Labasque, T.; Chatton, E.; Fovet, O.; Ruiz, L.; Fourré, E.; de Dreuzy, J. R.

2018-05-01

We investigated temporal variations and vertical evolution of dissolved gaseous tracers (CFC-11, CFC-12, SF6, and noble gases), as well as 3H/3He ratio to determine groundwater recharge processes of a shallow unconfined, hard-rock aquifer in an agricultural catchment. We sampled dissolved gas concentration at 4 locations along the hillslope of a small experimental watershed, over 6 hydrological years, between 2 and 6 times per years, for a total of 20 field campaigns. We collected groundwater samples in the fluctuation zone and the permanently saturated zone using piezometers from 5 to 20 m deep. The purpose of this work is i) to assess the benefits of using gaseous tracers like CFCs and SF6 to study very young groundwater with flows suspected to be heterogeneous and variable in time, ii) to characterize the processes that control dissolved gas concentrations in groundwater during the recharge of the aquifer, and iii) to understand the evolution of recharge flow processes by repeated measurement campaigns, taking advantage of a long monitoring in a site devoted to recharge processes investigation. Gas tracer profiles are compared at different location of the catchment and for different hydrologic conditions. In addition, we compare results from CFCs and 3H/3He analysis to define the flow model that best explains tracer concentrations. Then we discuss the influence of recharge events on tracer concentrations and residence time and propose a temporal evolution of residence times for the unsaturated zone and the permanently saturated zone. These results are used to gain a better understanding of the conceptual model of the catchment and flow processes especially during recharge events.

Hydrogeochemical characterization and groundwater quality assessment in intruded coastal brine aquifers (Laizhou Bay, China).

PubMed

Zhang, Xiaoying; Miao, Jinjie; Hu, Bill X; Liu, Hongwei; Zhang, Hanxiong; Ma, Zhen

2017-09-01

The aquifer in the coastal area of the Laizhou Bay is affected by salinization processes related to intense groundwater exploitation for brine resource and for agriculture irrigation during the last three decades. As a result, the dynamic balances among freshwater, brine, and seawater have been disturbed and the quality of groundwater has deteriorated. To fully understand the groundwater chemical distribution and evolution in the regional aquifers, hydrogeochemical and isotopic studies have been conducted based on the water samples from 102 observation wells. Groundwater levels and salinities in four monitoring wells are as well measured to inspect the general groundwater flow and chemical patterns and seasonal variations. Chemical components such as Na + , K + , Ca 2+ , Mg 2+ , Sr 2+ , Cl - , SO 4 2- , HCO 3 - , NO 3 - , F - , and TDS during the same period are analyzed to explore geochemical evolution, water-rock interactions, sources of salt, nitrate, and fluoride pollution in fresh, brackish, saline, and brine waters. The decreased water levels without typical seasonal variation in the southeast of the study area confirm an over-exploitation of groundwater. The hydrogeochemical characteristics indicate fresh-saline-brine-saline transition pattern from inland to coast where evaporation is a vital factor to control the chemical evolution. The cation exchange processes are occurred at fresh-saline interfaces of mixtures along the hydraulic gradient. Meanwhile, isotopic data indicate that the brine in aquifers was either originated from older meteoric water with mineral dissolution and evaporation or repeatedly evaporation of retained seawater with fresher water recharge and mixing in geological time. Groundwater suitability for drinking is further evaluated according to water quality standard of China. Results reveal high risks of nitrate and fluoride contamination. The elevated nitrate concentration of 560 mg/L, which as high as 28 times of the standard content in drinking water is identified in the south region. In addition, the nitrate and ammonia data of the Wei River suggests decreasing nitrification rate in the study area from inland to estuary. High fluoride concentration, larger than 1 mg/L, is also detected in an area of about 50% of the study region. The saltwater intrusion is analyzed to be responsible for part of dissolution of minerals containing fluoride. Therefore, water treatment before drinking is needed in urgent to reduce the health expose risk.

Groundwater chemistry characterization using multi-criteria approach: The upper Samalá River basin (SW Guatemala)

NASA Astrophysics Data System (ADS)

Bucci, Arianna; Franchino, Elisa; De Luca, Domenico Antonio; Lasagna, Manuela; Malandrino, Mery; Bianco Prevot, Alessandra; Hernández Sac, Humberto Osvaldo; Coyoy, Israel Macario; Sac Escobar, Edwin Osvaldo; Hernández, Ardany

2017-10-01

Improving understanding on groundwater chemistry is a key priority for water supply from groundwater resources, especially in developing countries. A hydrochemical study was performed in an area of SW Guatemala (Samalà River basin), where water supply to population is groundwater-based and no systematic studies on its groundwater resources have been performed so far. Traditional hydrochemical analyses on major ions and some trace elements metals coupled with chemometric approach were performed, including principal component analysis and hierarchical clustering analysis. Results evidence that chemical differentiation is linked to the spatial distribution of sampled waters. The most common hydrochemical facies, bicarbonate calcium and magnesium, is linked to infiltration of meteoric waters in recharge areas represented by highlands surrounding Xela caldera, a wide plateau where most of population is concentrated. This trend undergoes chemical evolution in proximity of active volcanic complexes in the southern area, with enrichment in sulphate, chloride and magnesium. Chemical evolution also occurs towards the centre of Xela caldera due to slow circulation in aquifer and consequent sodium enrichment due to ion exchange with the porous medium. Water quality did not reveal severe concerns, even though some sources of contamination could be identified; in particular, agriculture and urban wastewater could be responsible for observed threshold exceedances in nitrate and lead. This integrated multi-approach to hydrochemical data interpretation yielded to the achievement of important information that poses the basis for future groundwater protection in an area where main water features were almost unknown.

Simulation-Optimization Model for Seawater Intrusion Management at Pingtung Coastal Area, Taiwan

NASA Astrophysics Data System (ADS)

Huang, P. S.; Chiu, Y.

2015-12-01

In 1970's, the agriculture and aquaculture were rapidly developed at Pingtung coastal area in southern Taiwan. The groundwater aquifers were over-pumped and caused the seawater intrusion. In order to remedy the contaminated groundwater and find the best strategies of groundwater usage, a management model to search the optimal groundwater operational strategies is developed in this study. The objective function is to minimize the total amount of injection water and a set of constraints are applied to ensure the groundwater levels and concentrations are satisfied. A three-dimension density-dependent flow and transport simulation model, called SEAWAT developed by U.S. Geological Survey, is selected to simulate the phenomenon of seawater intrusion. The simulation model is well calibrated by the field measurements and replaced by the surrogate model of trained artificial neural networks (ANNs) to reduce the computational time. The ANNs are embedded in the management model to link the simulation and optimization models, and the global optimizer of differential evolution (DE) is applied for solving the management model. The optimal results show that the fully trained ANNs could substitute the original simulation model and reduce much computational time. Under appropriate setting of objective function and constraints, DE can find the optimal injection rates at predefined barriers. The concentrations at the target locations could decrease more than 50 percent within the planning horizon of 20 years. Keywords : Seawater intrusion, groundwater management, numerical model, artificial neural networks, differential evolution

Evolution of chemical and isotopic composition of inorganic carbon in a complex semi-arid zone environment: Consequences for groundwater dating using radiocarbon

NASA Astrophysics Data System (ADS)

Meredith, K. T.; Han, L. F.; Hollins, S. E.; Cendón, D. I.; Jacobsen, G. E.; Baker, A.

2016-09-01

Estimating groundwater age is important for any groundwater resource assessment and radiocarbon (14C) dating of dissolved inorganic carbon (DIC) can provide this information. In semi-arid zone (i.e. water-limited environments), there are a multitude of reasons why 14C dating of groundwater and traditional correction models may not be directly transferable. Some include; (1) the complex hydrological responses of these systems that lead to a mixture of different ages in the aquifer(s), (2) the varied sources, origins and ages of organic matter in the unsaturated zone and (3) high evaporation rates. These all influence the evolution of DIC and are not easily accounted for in traditional correction models. In this study, we determined carbon isotope data for; DIC in water, carbonate minerals in the sediments, sediment organic matter, soil gas CO2 from the unsaturated zone, and vegetation samples. The samples were collected after an extended drought, and again after a flood event, to capture the evolution of DIC after varying hydrological regimes. A graphical method (Han et al., 2012) was applied for interpretation of the carbon geochemical and isotopic data. Simple forward mass-balance modelling was carried out on key geochemical processes involving carbon and agreed well with observed data. High values of DIC and δ13CDIC, and low 14CDIC could not be explained by a simple carbonate mineral-CO2 gas dissolution process. Instead it is suggested that during extended drought, water-sediment interaction leads to ion exchange processes within the top ∼10-20 m of the aquifer which promotes greater calcite dissolution in saline groundwater. This process was found to contribute more than half of the DIC, which is from a mostly 'dead' carbon source. DIC is also influenced by carbon exchange between DIC in water and carbonate minerals found in the top 2 m of the unsaturated zone. This process occurs because of repeated dissolution/precipitation of carbonate that is dependent on the water salinity driven by drought and periodic flooding conditions. This study shows that although 14C cannot be directly applied as a dating tool in some circumstances, carbon geochemical/isotopic data can be useful in hydrological investigations related to identifying groundwater sources, mixing relations, recharge processes, geochemical evolution, and interaction with surface water.

Temporal Dynamics and Persistence of Spatial Patterns: from Groundwater to Soil Moisture to Transpiration

NASA Astrophysics Data System (ADS)

Blume, T.; Hassler, S. K.; Weiler, M.

2017-12-01

Hydrological science still struggles with the fact that while we wish for spatially continuous images or movies of state variables and fluxes at the landscape scale, most of our direct measurements are point measurements. To date regional measurements resolving landscape scale patterns can only be obtained by remote sensing methods, with the common drawback that they remain near the earth surface and that temporal resolution is generally low. However, distributed monitoring networks at the landscape scale provide the opportunity for detailed and time-continuous pattern exploration. Even though measurements are spatially discontinuous, the large number of sampling points and experimental setups specifically designed for the purpose of landscape pattern investigation open up new avenues of regional hydrological analyses. The CAOS hydrological observatory in Luxembourg offers a unique setup to investigate questions of temporal stability, pattern evolution and persistence of certain states. The experimental setup consists of 45 sensor clusters. These sensor clusters cover three different geologies, two land use classes, five different landscape positions, and contrasting aspects. At each of these sensor clusters three soil moisture/soil temperature profiles, basic climate variables, sapflow, shallow groundwater, and stream water levels were measured continuously for the past 4 years. We will focus on characteristic landscape patterns of various hydrological state variables and fluxes, studying their temporal stability on the one hand and the dependence of patterns on hydrological states on the other hand (e.g. wet vs dry). This is extended to time-continuous pattern analysis based on time series of spatial rank correlation coefficients. Analyses focus on the absolute values of soil moisture, soil temperature, groundwater levels and sapflow, but also investigate the spatial pattern of the daily changes of these variables. The analysis aims at identifying hydrologic signatures of the processes or landscape characteristics acting as major controls. While groundwater, soil water and transpiration are closely linked by the water cycle, they are controlled by different processes and we expect this to be reflected in interlinked but not necessarily congruent patterns and responses.

Inverse geochemical modeling of groundwater evolution with emphasis on arsenic in the Mississippi River Valley alluvial aquifer, Arkansas (USA)

USGS Publications Warehouse

Sharif, M.U.; Davis, R.K.; Steele, K.F.; Kim, B.; Kresse, T.M.; Fazio, J.A.

2008-01-01

Inverse geochemical modeling (PHREEQC) was used to identify the evolution of groundwater with emphasis on arsenic (As) release under reducing conditions in the shallow (25-30 m) Mississippi River Valley Alluvial aquifer, Arkansas, USA. The modeling was based on flow paths defined by high-precision (??2 cm) water level contour map; X-ray diffraction (XRD), scanning electron microscopic (SEM), and chemical analysis of boring-sediments for minerals; and detailed chemical analysis of groundwater along the flow paths. Potential phases were constrained using general trends in chemical analyses data of groundwater and sediments, and saturation indices data (MINTEQA2) of minerals in groundwater. Modeling results show that calcite, halite, fluorite, Fe oxyhydroxide, organic matter, H2S (gas) were dissolving with mole transfers of 1.40E - 03, 2.13E - 04, 4.15E - 06, 1.25E + 01, 3.11, and 9.34, respectively along the dominant flow line. Along the same flow line, FeS, siderite, and vivianite were precipitating with mole transfers of 9.34, 3.11, and 2.64E - 07, respectively. Cation exchange reactions of Ca2+ (4.93E - 04 mol) for Na+ (2.51E - 04 mol) on exchange sites occurred along the dominant flow line. Gypsum dissolution reactions were dominant over calcite dissolution in some of the flow lines due to the common ion effect. The concentration of As in groundwater ranged from <0.5 to 77 ??g/L. Twenty percent total As was complexed with Fe and Mn oxyhydroxides. The redox environment, chemical data of sediments and groundwater, and the results of inverse geochemical modeling indicate that reductive dissolution of Fe oxyhydroxide is the dominant process of As release in the groundwater. The relative rate of reduction of Fe oxyhydroxide over SO42 - with co-precipitation of As into sulfide is the limiting factor controlling dissolved As in groundwater. ?? 2007 Elsevier B.V. All rights reserved.

Hydrogeology and groundwater ecology: Does each inform the other?

NASA Astrophysics Data System (ADS)

Humphreys, W. F.

2009-02-01

The known, perceived and potential relationships between hydrogeology and groundwater ecology are explored, along with the spatial and temporal scale of these relations, the limit of knowledge and areas in need of research. Issues concerned with the subterranean part of the water cycle are considered from the perspective of the biology of those invertebrate animals that live, of necessity, in groundwater and the microbiological milieu essential for their survival. Groundwater ecosystems are placed in a hydrogeological context including the groundwater evolution along a flowpath, the significance of the biodiversity and of the ecosystem services potentially provided. This is considered against a background of three major components essential to the functioning of groundwater ecosystems, each of which can be affected by activities over which hydrogeologists often have control, and each, in turn, may have implications for groundwater management; these are, a place to live, oxygen and food (energy). New techniques and increasing awareness amongst hydrogeologists of the diversity and broad distribution of groundwater ecosystems offer new opportunities to develop cross disciplinary work between hydrogeologists and groundwater ecologists, already demonstrated to be a field for collaboration with broad benefits.

Spatial patterns and temporal dynamics of global scale climate-groundwater interactions

NASA Astrophysics Data System (ADS)

Cuthbert, M. O.; Gleeson, T. P.; Moosdorf, N.; Schneider, A. C.; Hartmann, J.; Befus, K. M.; Lehner, B.

2017-12-01

The interactions between groundwater and climate are important to resolve in both space and time as they influence mass and energy transfers at Earth's land surface. Despite the significance of these processes, little is known about the spatio-temporal distribution of such interactions globally, and many large-scale climate, hydrological and land surface models oversimplify groundwater or exclude it completely. In this study we bring together diverse global geomatic data sets to map spatial patterns in the sensitivity and degree of connectedness between the water table and the land surface, and use the output from a global groundwater model to assess the locations where the lateral import or export of groundwater is significant. We also quantify the groundwater response time, the characteristic time for groundwater systems to respond to a change in boundary conditions, and map its distribution globally to assess the likely dynamics of groundwater's interaction with climate. We find that more than half of the global land surface significantly exports or imports groundwater laterally. Nearly 40% of Earth's landmass has water tables that are strongly coupled to topography with water tables shallow enough to enable a bi-directional exchange of moisture with the climate system. However, only a small proportion (around 12%) of such regions have groundwater response times of 100 years or less and have groundwater fluxes that would significantly respond to rapid environmental changes over this timescale. We last explore fundamental relationships between aridity, groundwater response times and groundwater turnover times. Our results have wide ranging implications for understanding and modelling changes in Earth's water and energy balance and for informing robust future water management and security decisions.

Evolution of dissolved inorganic carbon in groundwater recharged by cyclones and groundwater age estimations using the 14C statistical approach

NASA Astrophysics Data System (ADS)

Meredith, K. T.; Han, L. F.; Cendón, D. I.; Crawford, J.; Hankin, S.; Peterson, M.; Hollins, S. E.

2018-01-01

The Canning Basin is the largest sedimentary basin in Western Australia and is located in one of the most cyclone prone regions of Australia. Despite its importance as a future resource, limited groundwater data is available for the Basin. The main aims of this paper are to provide a detailed understanding of the source of groundwater recharge, the chemical evolution of dissolved inorganic carbon (DIC) and provide groundwater age estimations using radiocarbon (14CDIC). To do this we combine hydrochemical and isotopic techniques to investigate the type of precipitation that recharge the aquifer and identify the carbon processes influencing 14CDIC, δ13CDIC, and [DIC]. This enables us to select an appropriate model for calculating radiocarbon ages in groundwater. The aquifer was found to be recharged by precipitation originating from tropical cyclones imparting lower average δ2H and δ18O values in groundwater (-56.9‰ and -7.87‰, respectively). Water recharges the soil zone rapidly after these events and the groundwater undergoes silicate mineral weathering and clay mineral transformation processes. It was also found that partial carbonate dissolution processes occur within the saturated zone under closed system conditions. Additionally, the processes could be lumped into a pseudo-first-order process and the age could be estimated using the 14C statistical approach. In the single-sample-based 14C models, 14C0 is the initial 14CDIC value used in the decay equation that considers only 14C decay rate. A major advantage of using the statistical approach is that both 14C decay and geochemical processes that cause the decrease in 14CDIC are accounted for in the calculation. The 14CDIC values of groundwater were found to increase from 89 pmc in the south east to around 16 pmc along the groundwater flow path towards the coast indicating ages ranging from modern to 5.3 ka. A test of the sensitivity of this method showed that a ∼15% error could be found for the oldest water. This error was low when compared to single-sample-based models. This study not only provides the first groundwater age estimations for the Canning Basin but is the first groundwater dating study to test the sensitivity of the statistical approach and provide meaningful error calculations for groundwater dating.

Lateral gene transfer in a heavy metal-contaminated-groundwater microbial community

DOE PAGES

Hemme, Christopher L.; Green, Stefan J.; Rishishwar, Lavanya; ...

2016-04-05

Here, unraveling the drivers controlling the response and adaptation of biological communities to environmental change, especially anthropogenic activities, is a central but poorly understood issue in ecology and evolution. Comparative genomics studies suggest that lateral gene transfer (LGT) is a major force driving microbial genome evolution, but its role in the evolution of microbial communities remains elusive.

Beach groundwater dynamics

NASA Astrophysics Data System (ADS)

Horn, Diane P.

2002-11-01

An understanding of the interaction between surface and groundwater flows in the swash zone is necessary to understand beach profile evolution. Coastal researchers have recognized the importance of beach watertable and swash interaction to accretion and erosion above the still water level (SWL), but the exact nature of the relationship between swash flows, beach watertable flow and cross-shore sediment transport is not fully understood. This paper reviews research on beach groundwater dynamics and identifies research questions which will need to be answered before swash zone sediment transport can be successfully modelled. After defining the principal terms relating to beach groundwater, the behavior, measurement and modelling of beach groundwater dynamics is described. Research questions related to the mechanisms of surface-subsurface flow interaction are reviewed, particularly infiltration, exfiltration and fluidisation. The implications of these mechanisms for sediment transport are discussed.

Can agricultural groundwater economies collapse? An inquiry into the pathways of four groundwater economies under threat

NASA Astrophysics Data System (ADS)

Petit, Olivier; Kuper, Marcel; López-Gunn, Elena; Rinaudo, Jean-Daniel; Daoudi, Ali; Lejars, Caroline

2017-09-01

The aim of this paper is to investigate the notion of collapse of agricultural groundwater economies using the adaptive-cycle analytical framework. This framework was applied to four case studies in southern Europe and North Africa to question and discuss the dynamics of agricultural groundwater economies. In two case studies (Saiss in Morocco and Clain basin in France), the imminent physical or socio-economic collapse was a major concern for stakeholders and the early signs of collapse led to re-organization of the groundwater economy. In the other two cases (Biskra in Algeria and Almeria in Spain), collapse was either not yet a concern or had been temporarily resolved through increased efficiency and access to additional water resources. This comparative analysis shows the importance of taking the early signs of collapse into account. These signs can be either related to resource depletion or to environmental and socio-economic impacts. Beyond these four case studies, the large number of groundwater economies under threat in (semi-)arid areas should present a warning regarding their possible collapse. Collapse can have severe and irreversible consequences in some cases, but it can also mean new opportunities and changes.

Fire and water: volcanology, geomorphology, and hydrogeology of the Cascade Range, central Oregon

Treesearch

Katharine V. Cashman; Natalia I. Deligne; Marshall W. Gannett; Gordon E. Grant; Anne Jefferson

2009-01-01

This field trip guide explores the interactions among the geologic evolution, hydrology, and fluvial geomorphology of the central Oregon Cascade Range. Key topics include the geologic control of hydrologic regimes on both the wet and dry sides of the Cascade Range crest, groundwater dynamics and interaction between surface and groundwater in young volcanic arcs, and...

Neural network approach to prediction of temperatures around groundwater heat pump systems

NASA Astrophysics Data System (ADS)

Lo Russo, Stefano; Taddia, Glenda; Gnavi, Loretta; Verda, Vittorio

2014-01-01

A fundamental aspect in groundwater heat pump (GWHP) plant design is the correct evaluation of the thermally affected zone that develops around the injection well. This is particularly important to avoid interference with previously existing groundwater uses (wells) and underground structures. Temperature anomalies are detected through numerical methods. Computational fluid dynamic (CFD) models are widely used in this field because they offer the opportunity to calculate the time evolution of the thermal plume produced by a heat pump. The use of neural networks is proposed to determine the time evolution of the groundwater temperature downstream of an installation as a function of the possible utilization profiles of the heat pump. The main advantage of neural network modeling is the possibility of evaluating a large number of scenarios in a very short time, which is very useful for the preliminary analysis of future multiple installations. The neural network is trained using the results from a CFD model (FEFLOW) applied to the installation at Politecnico di Torino (Italy) under several operating conditions. The final results appeared to be reliable and the temperature anomalies around the injection well appeared to be well predicted.

Depth-resolved abundance and diversity of arsenite-oxidizing bacteria in the groundwater of Beimen, a blackfoot disease endemic area of southwestern Taiwan.

PubMed

Das, Suvendu; Kar, Sandeep; Jean, Jiin-Shuh; Rathod, Jagat; Chakraborty, Sukalyan; Liu, Hsiao-Sheng; Bundschuh, Jochen

2013-12-01

The role of arsenite oxidizers in natural attenuation of arsenic pollution necessitates studies on their abundance and diversity in arsenic-contaminated aquifers. In this study, most probable number-polymerase chain reaction (MPN-PCR) and denaturing gradient gel electrophoresis (DGGE) was applied to monitor depth-wise abundance and diversity of aerobic arsenite oxidizers in arsenic-enriched groundwater of Beimen, southwestern Taiwan. The results revealed that the abundance of arsenite oxidizers ranged from 0.04 to 0.22, and the lowest ratio was observed in the most arsenic-enriched and comparatively more reduced groundwater (depth 200 m) of Beimen 1. The highest ratio was observed in the less arsenic-enriched and less reduced groundwater (depth 60 m) of Beimen 2B. DGGE profiles showed a shift in diversity of arsenite oxidizers, consisting of members of the Betaproteobacteria (61%), Alphaproteobacteria (28%) and Gammaproteobacteria (11%), depending on mainly arsenic concentration and redox level in groundwater. Groundwater with the lowest arsenic and highest dissolved oxygen at Beimen 2B harbored 78% of the arsenite oxidizers communities, while groundwater with the highest arsenic and lowest dissolved oxygen at Beimen 1 and Beimen-Jinhu harbored 17 and 22% of arsenite oxidizers communities, respectively. Pseudomonas sp. was found only in groundwater containing high arsenic at Beimen 1 and Beimen-Jinhu, while arsenite oxidizers belonging to Alpha- and Betaproteobacteria were dominated in groundwater containing low arsenic. Copyright © 2013 Elsevier Ltd. All rights reserved.

Identification of anthropogenic and natural inputs of sulfate into a karstic coastal groundwater system in northeast China: evidence from major ions, δ13CDIC and δ34SSO4

NASA Astrophysics Data System (ADS)

Han, Dongmei; Song, Xianfang; Currell, Matthew J.

2016-05-01

The hydrogeochemical processes controlling groundwater evolution in the Daweijia area of Dalian, northeast China, were characterised using hydrochemistry and isotopes of carbon and sulfur (δ13CDIC and δ34SSO4). The aim was to distinguish anthropogenic impacts as distinct from natural processes, with a particular focus on sulfate, which is found at elevated levels (range: 54.4 to 368.8 mg L-1; mean: 174.4 mg L-1) in fresh and brackish groundwater. The current investigation reveals minor seawater intrusion impact (not exceeding 5 % of the overall solute load), in contrast with extensive impacts observed in 1982 during the height of intensive abstraction. This indicates that measures to restrict groundwater abstraction have been effective. However, hydrochemical facies analysis shows that the groundwater remains in a state of ongoing hydrochemical evolution (towards Ca-Cl type water) and quality degradation (increasing nitrate and sulfate concentrations). The wide range of NO3 concentrations (74.7-579 mg L-1) in the Quaternary aquifer indicates considerable input of fertilisers and/or leakage from septic systems. Both δ13C (-14.5 to -5.9 permil) and δ34SSO4 (+5.4 to +13.1 permil) values in groundwater show increasing trends along groundwater flow paths. While carbonate minerals may contribute to increasing δ13CDIC and δ34SSO4 values in deep karstic groundwater, high loads of agricultural fertilisers reaching the aquifer via irrigation return flow are likely the main source of the dissolved sulfate in Quaternary groundwater, as shown by distinctive isotopic ratios and a lack of evidence for other sources in the major ion chemistry. According to isotope mass balance calculations, the fertiliser contribution to overall sulfate has reached an average of 62.1 % in the Quaternary aquifer, which has a strong hydraulic connection to the underlying carbonate aquifer. The results point to an alarming level of impact from the local intensive agriculture on the groundwater system, a widespread problem throughout China.

Identification of anthropogenic and natural inputs of sulfate into a karstic coastal groundwater system in northeast China: evidence from major ions, δ13CDIC and δ34SSO4

NASA Astrophysics Data System (ADS)

Han, D.; Song, X.; Currell, M. J.

2015-11-01

The hydrogeochemical processes controlling groundwater evolution in the Daweijia area of Dalian, northeast China, were characterized using hydrochemistry and isotopes of carbon and sulfur (δ13CDIC and δ34SSO4). The aim was to distinguish anthropogenic impacts as distinct from natural processes, with a particular focus on sulfate, which is found at elevated levels (range: 54.4 to 368.8 mg L-1; mean: 174.4 mg L-1) in fresh and brackish groundwater. The current investigation reveals minor seawater intrusion impact (not exceeding 5 % of overall solute load), in contrast with extensive impacts observed in 1982 during the height of intensive abstraction. This indicates that measures to restrict groundwater abstraction have been effective. However, hydrochemical facies analysis shows that the groundwater remains in a state of ongoing hydrochemical evolution (towards Ca-Cl type water) and quality degradation (increasing nitrate and sulphate concentrations). The wide range of NO3 concentrations (74.7-579 mg L-1) in the Quaternary aquifer indicates considerable input of fertilizers and/or leakage from septic systems. Both δ13C (-14.5 to -5.9 ‰) and δ34SSO4 (+5.4-+13.1 ‰) values in groundwater show increasing trends along groundwater flow paths. While carbonate minerals may contribute to increasing δ13CDIC and δ34SSO4 values in deep karstic groundwater, high loads of agricultural fertilizers reaching the aquifer via irrigation return flow are likely the main source of the dissolved sulfate in Quaternary groundwater, as shown by distinctive isotopic ratios and a lack of evidence for other sources in the major ion chemistry. According to isotope mass balance calculations, the fertilizer contribution to overall sulfate has reached an average of 62.1 % in the Quaternary aquifer, which has a strong hydraulic connection to the underlying carbonate aquifer. The results point to an alarming level of impact from the local intensive agriculture on the groundwater system, a widespread problem throughout China.

Water resources management strategies and its implications on hydrodynamic and hydrochemical changes of costal groundwater: Case of Grombalia shallow aquifer, NE Tunisia

NASA Astrophysics Data System (ADS)

Lachaal, Fethi; Chekirbane, Anis; Chargui, Sameh; Sellami, Haykel; Tsujimura, Maki; Hezzi, Hmida; Faycel, Jelassi; Mlayah, Ammar

2016-12-01

Information on groundwater quantity as well as quality is required by water managers and decision-makers for defining a sustainable management strategy. This requires a comprehensive assessment of the surface water and groundwater resources. This paper provides an assessment of water resources management strategy in the Grombalia region (Northeast Tunisia) and its impact on quantity and quality evolution of groundwater resources based on an approach that combines (i) hydro-climatic data, (ii) field monitoring, (iii) historic piezometric records, and (iv) geochemical and stable isotopes (δ18O and δ2H) analyses. We apply this approach to identify the origin of the various water resources and outline how the actual water management impact the quantity and quality of the groundwater in the region. As consequence of poor water resources management, the shallow groundwater levels have been disrupted: a groundwater rise is observed in the centre and a piezometric drawdown is observed in the upstream regions. Groundwater quality degradation was registered especially in the centre and downstream zones.

Investigating the effect of landfill leachates on the characteristics of dissolved organic matter in groundwater using excitation-emission matrix fluorescence spectra coupled with fluorescence regional integration and self-organizing map.

PubMed

He, Xiao-Song; Fan, Qin-Dong

2016-11-01

For the purpose of investigating the effect of landfill leachate on the characteristics of organic matter in groundwater, groundwater samples were collected near and in a landfill site, and dissolved organic matter (DOM) was extracted from the groundwater samples and characterized by excitation-emission matrix (EEM) fluorescence spectra combined with fluorescence regional integration (FRI) and self-organizing map (SOM). The results showed that the groundwater DOM comprised humic-, fulvic-, and protein-like substances. The concentration of humic-like matter showed no obvious variation for all groundwater except the sample collected in the landfill site. Fulvic-like substance content decreased when the groundwater was polluted by landfill leachates. There were two kinds of protein-like matter in the groundwater. One kind was bound to humic-like substances, and its content did not change along with groundwater pollution. However, the other kind was present as "free" molecules or else bound in proteins, and its concentration increased significantly when the groundwater was polluted by landfill leachates. The FRI and SOM methods both can characterize the composition and evolution of DOM in the groundwater. However, the SOM analysis can identify whether protein-like moieties was bound to humic-like matter.

The History of the M31 Disk from Resolved Stellar Populations as Seen by PHAT

NASA Astrophysics Data System (ADS)

Lewis, A. R.; Dalcanton, J. J.; Dolphin, A. E.; Weisz, D. R.; Williams, B. F.; PHAT Collaboration

2014-03-01

The Panchromatic Hubble Andromeda Treasury (PHAT) is an HST multi-cycle treasury program that is mapping the resolved stellar populations of ˜1/3 of M31 from the UV through the near-IR. These data provide color and luminosity information for more than 150 million stars in the M31 disk. We use stellar evolution models to fit the luminous main sequence to derive spatially-resolved recent star formation histories (SFHs) over large areas of M31 with 50-100 pc resolution. These include individual star-forming regions as well as quiescent portions of the disk. We use the gridded SFHs to create movies of star formation activity to study the evolution of individual star-forming events across the disk. Outside of the star-forming regions, we use our resolved stellar photometry to derive the full SFHs of larger regions. These allow us to probe spatial and temporal trends in age and metallicity across a large radial baseline, providing constraints on the global formation and evolution of the disk over a Hubble time. M31 is the only large disk galaxy that is close enough to obtain the photometry necessary for this type of spatially-resolved SFH mapping.

Evolution and enabling capabilities of spatially resolved techniques for the characterization of heterogeneously catalyzed reactions

DOE PAGES

Morgan, Kevin; Touitou, Jamal; Choi, Jae -Soon; ...

2016-01-15

The development and optimization of catalysts and catalytic processes requires knowledge of reaction kinetics and mechanisms. In traditional catalyst kinetic characterization, the gas composition is known at the inlet, and the exit flow is measured to determine changes in concentration. As such, the progression of the chemistry within the catalyst is not known. Technological advances in electromagnetic and physical probes have made visualizing the evolution of the chemistry within catalyst samples a reality, as part of a methodology commonly known as spatial resolution. Herein, we discuss and evaluate the development of spatially resolved techniques, including the evolutions and achievements ofmore » this growing area of catalytic research. The impact of such techniques is discussed in terms of the invasiveness of physical probes on catalytic systems, as well as how experimentally obtained spatial profiles can be used in conjunction with kinetic modeling. Moreover, some aims and aspirations for further evolution of spatially resolved techniques are considered.« less

Is there a geomorphic expression of interbasin groundwater flow in watersheds? Interactions between interbasin groundwater flow, springs, streams, and geomorphology.

DOE PAGES

Frisbee, Marty D.; Tysor, Elizabeth H.; Stewart-Maddox, Noah; ...

2016-02-13

Interbasin groundwater flow (IGF) can play a significant role in the generation and geochemical evolution of streamflow. However, it is exceedingly difficult to identify IGF, and to determine the location and quantity of water that is exchanged between watersheds. How does IGF affect landscape/watershed geomorphic evolution? Can geomorphic metrics be used to identify the presence of IGF? We examine these questions in two adjacent sedimentary watersheds in northern New Mexico using a combination of geomorphic/landscape metrics, springflow residence times, and spatial geochemical patterns. IGF is expressed geomorphically in the landscape placement of springs, and flow direction and shape of streammore » channels. Springs emerge preferentially on one side of stream valleys where landscape incision has intercepted IGF flowpaths. Stream channels grow toward the IGF source and show little bifurcation. In addition, radiocarbon residence times of springs decrease and the geochemical composition of springs changes as the connection to IGF is lost.« less

Is there a geomorphic expression of interbasin groundwater flow in watersheds? Interactions between interbasin groundwater flow, springs, streams, and geomorphology

NASA Astrophysics Data System (ADS)

Frisbee, Marty D.; Tysor, Elizabeth H.; Stewart-Maddox, Noah S.; Tsinnajinnie, Lani M.; Wilson, John L.; Granger, Darryl E.; Newman, Brent D.

2016-02-01

Interbasin groundwater flow (IGF) can play a significant role in the generation and geochemical evolution of streamflow. However, it is exceedingly difficult to identify IGF and to determine the location and quantity of water that is exchanged between watersheds. How does IGF affect landscape/watershed geomorphic evolution? Can geomorphic metrics be used to identify the presence of IGF? We examine these questions in two adjacent sedimentary watersheds in northern New Mexico using a combination of geomorphic/landscape metrics, springflow residence times, and spatial geochemical patterns. IGF is expressed geomorphically in the landscape placement of springs and flow direction and shape of stream channels. Springs emerge preferentially on one side of stream valleys where landscape incision has intercepted IGF flow paths. Stream channels grow toward the IGF source and show little bifurcation. In addition, radiocarbon residence times of springs decrease and the geochemical composition of springs changes as the connection to IGF is lost.

Impacts of changes in groundwater recharge on the isotopic composition and geochemistry of seasonally ice-covered lakes: insights for sustainable management

NASA Astrophysics Data System (ADS)

Arnoux, Marie; Barbecot, Florent; Gibert-Brunet, Elisabeth; Gibson, John; Noret, Aurélie

2017-11-01

Lakes are under increasing pressure due to widespread anthropogenic impacts related to rapid development and population growth. Accordingly, many lakes are currently undergoing a systematic decline in water quality. Recent studies have highlighted that global warming and the subsequent changes in water use may further exacerbate eutrophication in lakes. Lake evolution depends strongly on hydrologic balance, and therefore on groundwater connectivity. Groundwater also influences the sensitivity of lacustrine ecosystems to climate and environmental changes, and governs their resilience. Improved characterization of groundwater exchange with lakes is needed today for lake preservation, lake restoration, and sustainable management of lake water quality into the future. In this context, the aim of the present paper is to determine if the future evolution of the climate, the population, and the recharge could modify the geochemistry of lakes (mainly isotopic signature and quality via phosphorous load) and if the isotopic monitoring of lakes could be an efficient tool to highlight the variability of the water budget and quality. Small groundwater-connected lakes were chosen to simulate changes in water balance and water quality expected under future climate change scenarios, namely representative concentration pathways (RCPs) 4.5 and 8.5. Contemporary baseline conditions, including isotope mass balance and geochemical characteristics, were determined through an intensive field-based research program prior to the simulations. Results highlight that future lake geochemistry and isotopic composition trends will depend on four main parameters: location (and therefore climate conditions), lake catchment size (which impacts the intensity of the flux change), lake volume (which impacts the range of variation), and lake G index (i.e., the percentage of groundwater that makes up total lake inflows), the latter being the dominant control on water balance conditions, as revealed by the sensitivity of lake isotopic composition. Based on these model simulations, stable isotopes appear to be especially useful for detecting changes in recharge to lakes with a G index of between 50 and 80 %, but response is non-linear. Simulated monthly trends reveal that evolution of annual lake isotopic composition can be dampened by opposing monthly recharge fluctuations. It is also shown that changes in water quality in groundwater-connected lakes depend significantly on lake location and on the intensity of recharge change.

An inexpensive technique for the time resolved laser induced plasma spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahmed, Rizwan, E-mail: rizwan.ahmed@ncp.edu.pk; Ahmed, Nasar; Iqbal, J.

We present an efficient and inexpensive method for calculating the time resolved emission spectrum from the time integrated spectrum by monitoring the time evolution of neutral and singly ionized species in the laser produced plasma. To validate our assertion of extracting time resolved information from the time integrated spectrum, the time evolution data of the Cu II line at 481.29 nm and the molecular bands of AlO in the wavelength region (450–550 nm) have been studied. The plasma parameters were also estimated from the time resolved and time integrated spectra. A comparison of the results clearly reveals that the time resolved informationmore » about the plasma parameters can be extracted from the spectra registered with a time integrated spectrograph. Our proposed method will make the laser induced plasma spectroscopy robust and a low cost technique which is attractive for industry and environmental monitoring.« less

Understanding the carbon cycle in a Late Quaternary-age limestone aquifer system using radiocarbon of dissolved inorganic and organic carbon

NASA Astrophysics Data System (ADS)

Bryan, Eliza; Meredith, Karina T.; Baker, Andy; Andersen, Martin S.; Post, Vincent E. A.

2017-04-01

Estimating groundwater residence time is critical for our understanding of hydrogeological systems, for groundwater resource assessments and for the sustainable management of groundwater resources. Due to its capacity to date groundwater up to 30 thousand years old, as well as the ubiquitous nature of dissolved carbon (as organic and inorganic forms) in groundwater, 14C is the most widely used radiogenic dating technique in regional aquifers. However, the geochemistry of carbon in groundwater systems includes interaction with the atmosphere, biosphere and geosphere, which results in multiple sources and sinks of carbon that vary in time and space. Identifying these sources of carbon and processes relating to its release or removal is important for understanding the evolution of the groundwater and essential for residence time calculations. This study investigates both the inorganic and organic facets of the carbon cycle in groundwaters throughout a freshwater lens and mixing zone of a carbonate island aquifer and identifies the sources of carbon that contribute to the groundwater system. Groundwater samples were collected from shallow (5-20 m) groundwater wells on a small carbonate Island in Western Australia in September 2014 and analysed for major and minor ions, stable water isotopes (SWIs: δ18O, δ2H), 3H, 14C and 13C carbon isotope values of both DIC and DOC, and 3H. The composition of groundwater DOC was investigated by Liquid Chromatography-Organic Carbon Detection (LC-OCD) analysis. The presence of 3H (0.12 to 1.35 TU) in most samples indicates that groundwaters on the Island are modern, however the measured 14CDIC values (8.4 to 97.2 pmc) suggest that most samples are significantly older due to carbonate dissolution and recrystallisation reactions that are identified and quantified in this work. 14CDOC values (46.6 to 105.6 pMC) were higher than 14CDIC values and were well correlated with 3H values, however deeper groundwaters had lower 14CDOC values than expected. LC-OCD chromatography of these groundwaters were found to contain higher concentrations of humic substances, that are most likely attributed to the presence of paleosol horizons at depth in the limestone, which are a common feature in aeolianite deposits along the Western coast of Australia and are related to Quaternary sea level change. The paleosols likely contribute old organic matter to the deeper groundwaters, which may explain the lower 14CDOC values. This study has shown that a combined approach that utilises both DIC and DOC tracers, as well as 3H, is required to identify the sources and evolution of carbon in a groundwater system, as well as the processes that effect the application of 14C dating to groundwaters within a carbonate aquifer.

Paleoclimatic and deforestation effect on the chemical and isotopic composition of the coastal fresh groundwater resources of South-east Ivory Coast

NASA Astrophysics Data System (ADS)

Adiaffi, B.; Marlin, C.; Yei, O. M.-S.; Massault, M.; Noret, A.; Biemi, J.

2009-04-01

Since a half of century, the forest surface area of the South Ivory Coast has been decreased for the benefit of agriculture (15 000 km2 in 1993 versus 83 000 km2 in 1955-1958). This area also undergoes climate change. Vegetation cover has gradually changed from rainforests (C3 plants) to savanna (C4 plants) and agricultural plants. In the Abidjan area (5.00-6.00°N, 2.40-4.40°W), the mean rainfall amount and temperature value evolve during the 20th century (1912 mm/year and 26.3°C/year during the first decennial to 1613 mm/year and 26.9°C/year during the last ten years). The Paleoproterozoïc fractured bedrock (PB) and the Continental Terminal (CT) deposits groundwater are studied to show the climate change and deforestation effect on the area groundwater resources using stable isotopes (18O, 2H and 13C) contents, radiocarbon (14C) contents and chemical data on a set of 25 groundwater samples. The residence time of the groundwaters is estimated by the 14C using two models: (i) the model of well-mixed reservoir (WMR model) and (ii) the piston flow model (PF model). The range of the PB groundwater residence time (15 000 - 8 000 to ~ 300 - 100 a BP) for both models shows that the recharge has started at the beginning of the post-glacial period whereas the CT aquifer recharge is much more recent (from 300 a BP to today). The PB groundwater provides information about paleoclimatic conditions that occurred over the studied area during the late Pleistocene. It is demonstrated, through this study, that the evolution of vegetation cover (from forests to savanna and agriculture plants) is shown in groundwater by the trend in 13C content from old groundwater (confined bedrock groundwater: residence time of ~ 15 000 a BP) to the recent groundwater (unconfined bedrock groundwater and CT groundwater: residence times: ~ 300 a BP and lower than 100 a BP, respectively). The δ18O and δ2H values also increase with time from the beginning of the post-glacial period (~ 15 000 a BP) to the present day (< 100 a BP), showing the evolution of the climate from cold to warm conditions. This study has shown the paleoclimate effect on the water resources in Ivory Coast and are consistent with the results obtained by some authors in Western Africa (Ghana, Liberia, Mali and Niger).

In Situ Time-Resolved Measurements of Extension Twinning During Dynamic Compression of Polycrystalline Magnesium

NASA Astrophysics Data System (ADS)

Hustedt, C. J.; Lambert, P. K.; Kannan, V.; Huskins-Retzlaff, E. L.; Casem, D. T.; Tate, M. W.; Philipp, H. T.; Woll, A. R.; Purohit, P.; Weiss, J. T.; Gruner, S. M.; Ramesh, K. T.; Hufnagel, T. C.

2018-04-01

We report in situ time-resolved measurements of the dynamic evolution of the volume fraction of extension twins in polycrystalline pure magnesium and in the AZ31B magnesium alloy, using synchrotron x-ray diffraction during compressive loading at high strain rates. The dynamic evolution of the twinning volume fraction leads to a dynamic evolution of the texture. Although both the pure metal and the alloy had similar initial textures, we observe that the evolution of texture is slower in the alloy. We also measured the evolution of the lattice strains in each material during deformation which, together with the twin volume fractions, allows us to place some constraints on the relative contributions of dislocation-based slip and deformation twinning to the overall plastic deformation during the dynamic deformations.

Identification of hydrogeochemical processes and pollution sources of groundwater nitrate in Leiming Basin of Hainan island, Southern China

NASA Astrophysics Data System (ADS)

Shaowen, Y.; Zhan, Y., , Dr; Li, Q.

2017-12-01

Identifying the evolution of groundwater quality is important for the control and management of groundwater resources. The main aims of the present study are to identify the major factors affecting hydrogeochemistry of groundwater resources and to evaluate the potential sources of groundwater nitrate in Leiming basin using chemical and isotopic methods. The majority of samples belong to Na-Cl water type and are followed by Ca-HCO3 and mixed Ca-Na-HCO3. The δ18O and δ2H values in groundwater indicate that the shallow fissure groundwater is mainly recharged by rainfall. The evaporated surface water is another significant origin of groundwater. The weathering and dissolution of different rocks and minerals, input of precipitation, evaporation, ion exchange and anthropogenic activities, especially agricultural activities, influence the hydrogeochemistry of the study area. NO- 3 concentration in the groundwater varies from 0.7 to 51.7 mg/L and high values are mainly occurred in the densely populated area. The combined use of isotopic values and hydrochemical data suggests that the NO- 3 load in Leiming basin is not only derived from agricultural activities but also from other sources such as waste water and atmospheric deposition. Fertilizer is considered as the major source of NO- 3 in the groundwater in Leiming basin.

Applications of Groundwater Helium

USGS Publications Warehouse

Kulongoski, Justin T.; Hilton, David R.

2011-01-01

Helium abundance and isotope variations have widespread application in groundwater-related studies. This stems from the inert nature of this noble gas and the fact that its two isotopes ? helium-3 and helium-4 ? have distinct origins and vary widely in different terrestrial reservoirs. These attributes allow He concentrations and 3He/4He isotope ratios to be used to recognize and quantify the influence of a number of potential contributors to the total He budget of a groundwater sample. These are atmospheric components, such as air-equilibrated and air-entrained He, as well as terrigenic components, including in situ (aquifer) He, deep crustal and/or mantle He and tritiogenic 3He. Each of these components can be exploited to reveal information on a number of topics, from groundwater chronology, through degassing of the Earth?s crust to the role of faults in the transfer of mantle-derived volatiles to the surface. In this review, we present a guide to how groundwater He is collected from aquifer systems and quantitatively measured in the laboratory. We then illustrate the approach of resolving the measured He characteristics into its component structures using assumptions of endmember compositions. This is followed by a discussion of the application of groundwater He to the types of topics mentioned above using case studies from aquifers in California and Australia. Finally, we present possible future research directions involving dissolved He in groundwater.

Resolving hyporheic and groundwater components of streambed water flux

USGS Publications Warehouse

Bhaskar, Aditi S.; Harvey, Judson W.; Henry, Eric J.

2012-01-01

Hyporheic and groundwater fluxes typically occur together in permeable sediments beneath flowing stream water. However, streambed water fluxes quantified using the thermal method are usually interpreted as representing either groundwater or hyporheic fluxes. Our purpose was to improve understanding of co-occurring groundwater and hyporheic fluxes using streambed temperature measurements and analysis of one-dimensional heat transport in shallow streambeds. First, we examined how changes in hyporheic and groundwater fluxes affect their relative magnitudes by reevaluating previously published simulations. These indicated that flux magnitudes are largely independent until a threshold is crossed, past which hyporheic fluxes are diminished by much larger (1000-fold) groundwater fluxes. We tested accurate quantification of co-occurring fluxes using one-dimensional approaches that are appropriate for analyzing streambed temperature data collected at field sites. The thermal analytical method, which uses an analytical solution to the one-dimensional heat transport equation, was used to analyze results from a numerical heat transport model, in which hyporheic flow was represented as increased thermal dispersion at shallow depths. We found that co-occurring groundwater and hyporheic fluxes can be quantified in streambeds, although not always accurately. For example, using a temperature time series collected in a sandy streambed, we found that hyporheic and groundwater flow could both be detected when thermal dispersion due to hyporheic flow was significant compared to thermal conduction. We provide guidance for when thermal data can be used to quantify both hyporheic and groundwater fluxes, and we show that neglecting thermal dispersion may affect accuracy and interpretation of estimated streambed water fluxes.

Origin and evolution of groundwater in the semi-arid Kerdous Inlier in the Western Anti-Atlas, Morocco

NASA Astrophysics Data System (ADS)

Heiß, Laura; Bouchaou, Lhoussaine; Reichert, Barbara

2018-03-01

In the Kerdous Inlier, groundwater is the only source of drinking and irrigation water and sustainable management requires an understanding of the hydrogeological setting. In the lower Ait Mansour study site, the main aquifer is represented by a karstified and fractured sequence of Infra and Lower Cambrian carbonates. In the Ameln study site, fractured Neoproterozoic quartzites of the Jebel Lkest build the main aquifer. Isotopic signatures of groundwater indicated direct groundwater recharge in both study sites. In the Ait Mansour study site, isotopic composition implied recharge at high altitudes and groundwater flow in the SE direction. Two major flow paths were identified in the Ameln study site: a shallow and rapid movement until spring discharge at the hill slopes and another deeper one into the Ameln Valley. Hydrochemical facies at both study sites were of Ca-Mg-HCO3 type and derived from dolomite and plagioclase weathering. Increased NO3-, SO4^{2-}, and Cl- concentrations in groundwater indicated an anthropogenic influence.

Temporal-Spatial Evolution of Groundwater Nitrogen Pollution Over Seven Years in a Highly Urbanized City in the Southern China.

PubMed

He, Xiaorui; Qian, Jiazhong; Liu, Zufa; Lu, Yuehan; Ma, Lei; Zhao, Weidong; Kang, Bo

2017-12-01

Understanding the temporospatial variation in nitrogen pollution in groundwater and the associated controlling factors is important to establish management practices that ensure sustainable use of groundwater. In this study, we analyzed inorganic nitrogen content (nitrate, nitrite, and ammonium) in 1164 groundwater samples from shallow, middle-deep, and deep aquifers in Zhanjiang, a highly urbanized city in the southern China. Our data span a range of 7 years from 2005 to 2011. Results show that shallow aquifers had been heavily contaminated by nitrate and ammonium. Temporal patterns show that N contamination levels remained high and relatively stable over time in urban areas. This stability and high concentration is hypothesized as a result of uncontrolled, illicit sewer discharges from nearby business facilities. Groundwater in urban land and farmland displays systematic differences in geochemical characteristics. Collectively, our findings demonstrate the importance of continuously monitoring groundwater quality and strictly regulating sewage discharges in Zhanjiang.

Integrated groundwater data management

USGS Publications Warehouse

Fitch, Peter; Brodaric, Boyan; Stenson, Matt; Booth, Nathaniel; Jakeman, Anthony J.; Barreteau, Olivier; Hunt, Randall J.; Rinaudo, Jean-Daniel; Ross, Andrew

2016-01-01

The goal of a data manager is to ensure that data is safely stored, adequately described, discoverable and easily accessible. However, to keep pace with the evolution of groundwater studies in the last decade, the associated data and data management requirements have changed significantly. In particular, there is a growing recognition that management questions cannot be adequately answered by single discipline studies. This has led a push towards the paradigm of integrated modeling, where diverse parts of the hydrological cycle and its human connections are included. This chapter describes groundwater data management practices, and reviews the current state of the art with enterprise groundwater database management systems. It also includes discussion on commonly used data management models, detailing typical data management lifecycles. We discuss the growing use of web services and open standards such as GWML and WaterML2.0 to exchange groundwater information and knowledge, and the need for national data networks. We also discuss cross-jurisdictional interoperability issues, based on our experience sharing groundwater data across the US/Canadian border. Lastly, we present some future trends relating to groundwater data management.

A versatile method for groundwater vulnerability projections in future scenarios.

PubMed

Stevenazzi, Stefania; Bonfanti, Marianna; Masetti, Marco; Nghiem, Son V; Sorichetta, Alessandro

2017-02-01

Water scarcity and associated risks are serious societal problems. A major challenge for the future will be to ensure the short-term and long-term provision of accessible and safe freshwater to meet the needs of the rapidly growing human population and changes in land cover and land use, where conservation and protection play a key role. Through a Bayesian spatial statistical method, a time-dependent approach for groundwater vulnerability assessment is developed to account for both the recent status of groundwater contamination and its evolution, as required by the European Union (Groundwater Directive, 2006/118/EC). This approach combines natural and anthropogenic factors to identify areas with a critical combination of high levels and increasing trends of nitrate concentrations, together with a quantitative evaluation of how different future scenarios would impact the quality of groundwater resources in a given area. In particular, the proposed approach can determine potential impacts on groundwater resources if policies are maintained at the status quo or if new measures are implemented for safeguarding groundwater quality, as natural factors are changing under climatic or anthropogenic stresses. Copyright © 2016 Elsevier Ltd. All rights reserved.

Comparison and Correlation of Subsurface Media Properties Reflected in Both Extracted Soil Pore Water From Sectioned Cores and Homogenized Groundwater From Monitoring Wells

NASA Astrophysics Data System (ADS)

Moon, J. W.; Paradis, C. J.; von Netzer, F.; Dixon, E.; Majumder, E.; Joyner, D.; Zane, G.; Fitzgerald, K.; Xiaoxuan, G.; Thorgersen, M. P.; Lui, L.; Adams, B.; Brewer, S. S.; Williams, D.; Lowe, K. A.; Rodriguez, M., Jr.; Mehlhorn, T. L.; Pfiffner, S. M.; Chakraborty, R.; Arkin, A. P.; Terry, A. Y.; Wall, J. D.; Stahl, D. A.; Elias, D. A.; Hazen, T. C.

2017-12-01

Conventional monitoring wells have produced useful long-term data about the contaminants, carbon flux, microbial population and their evolution. The averaged homogenized groundwater matrix from these wells is insufficient to represent all media properties in subsurface. This pilot study investigated the solid, liquid and gas phases from soil core samples from both uncontaminated and contaminated areas of the ENIGMA field research site at Oak Ridge, Tennessee. We focused on a site-specific assessment with depth perspective that included soil structure, soil minerals, major and trace elements and biomass for the solid phase; centrifuged soil pore water including cations, anions, organic acid, pH and conductivity for the liquid phase; and gas (CO2, CH4, N2O) evolution over a 4 week incubation with soil and unfiltered groundwater. Pore water from soil core sections showed a correlation between contamination levels with depth and the potential abundance of sulfate- and nitrate-reducing bacteria based on the 2-order of magnitude decreased concentration. A merged interpretation with mineralogical consideration revealed a more complicated correlation among contaminants, soil texture, clay minerals, groundwater levels, and biomass. This sampling campaign emphasized that subsurface microbial activity and metabolic reactions can be influenced by a variety of factors but can be understood by considering the influence of multiple geochemical factors from all subsurface phases including water, air, and solid along depth rather than homogenized groundwater.

Characterization of the lowland coastal aquifer of Comacchio (Ferrara, Italy): Hydrology, hydrochemistry and evolution of the system

NASA Astrophysics Data System (ADS)

Giambastiani, B. M. S.; Colombani, N.; Mastrocicco, M.; Fidelibus, M. D.

2013-09-01

This study delineates the actual hydrogeochemistry and the geological evolution of an unconfined coastal aquifer located in a lowland setting in order to understand the drivers of the groundwater salinization. Physical aquifer parameterization highlights a vertical hydraulic gradient due to the presence of a heavy drainage system, which controls the hydrodynamics of this coastal area, forcing groundwater to flow from the bottom toward the top of the aquifer. As a consequence, relict seawater in stable density stratification, preserved within low permeability sediments in the deepest portion of the aquifer, has been drawn upward. The hydrogeochemical investigations allow identifying the role of seepage and water-sediment interactions in the aquifer salinization process and in the modification of groundwater chemistry. Mixing between freshwater and saltwater occurs; however, it is neither the only nor the dominant process driving groundwater hydrochemistry. In the aquifer several concurring and competing water-sediment interactions - as NaCl solution, ion-exchange, calcite and dolomite dissolution/precipitation, oxidation of organic matter, and sulfate bacterial reduction - are triggered by or overlap freshwater-saltwater mixing The hyper-salinity found in the deepest portion of the aquifer cannot be associated with present seawater intrusion, but suggests the presence of salt water of marine origin, which was trapped in the inter-basin during the Holocene transgression. The results of this study contribute to a better understanding of groundwater dynamics and salinization processes in this lowland coastal aquifer.

Hydrochemical and multivariate analysis of groundwater quality in the northwest of Sinai, Egypt.

PubMed

El-Shahat, M F; Sadek, M A; Salem, W M; Embaby, A A; Mohamed, F A

2017-08-01

The northwestern coast of Sinai is home to many economic activities and development programs, thus evaluation of the potentiality and vulnerability of water resources is important. The present work has been conducted on the groundwater resources of this area for describing the major features of groundwater quality and the principal factors that control salinity evolution. The major ionic content of 39 groundwater samples collected from the Quaternary aquifer shows high coefficients of variation reflecting asymmetry of aquifer recharge. The groundwater samples have been classified into four clusters (using hierarchical cluster analysis), these match the variety of total dissolvable solids, water types and ionic orders. The principal component analysis combined the ionic parameters of the studied groundwater samples into two principal components. The first represents about 56% of the whole sample variance reflecting a salinization due to evaporation, leaching, dissolution of marine salts and/or seawater intrusion. The second represents about 15.8% reflecting dilution with rain water and the El-Salam Canal. Most groundwater samples were not suitable for human consumption and about 41% are suitable for irrigation. However, all groundwater samples are suitable for cattle, about 69% and 15% are suitable for horses and poultry, respectively.

Modelling past hydrology of an interfluve area in the Campine region (NE Belgium)

NASA Astrophysics Data System (ADS)

Leterme, Bertrand; Beerten, Koen; Gedeon, Matej; Vandersteen, Katrijn

2015-04-01

This study aims at hydrological model verification of a small lowland interfluve area (18.6 km²) in NE Belgium, for conditions that are different than today. We compare the current state with five reference periods in the past (AD 1500, 1770, 1854, 1909 and 1961) representing important stages of landscape evolution in the study area. Historical information and proxy data are used to derive conceptual model features and boundary conditions specific to each period: topography, surface water geometry (canal, drains and lakes), land use, soils, vegetation and climate. The influence of landscape evolution on the hydrological cycle is assessed using numerical simulations of a coupled unsaturated zone - groundwater model (HYDRUS-MODFLOW). The induced hydrological changes are assessed in terms of groundwater level, recharge, evapotranspiration, and surface water discharge. HYDRUS-MODFLOW coupling allows including important processes such as the groundwater contribution to evapotranspiration. Major land use change occurred between AD 1854 and 1909, with about 41% of the study area being converted from heath to coniferous forest, together with the development of a drainage network. Results show that this led to a significant decrease of groundwater recharge and lowering of the groundwater table. A limitation of the study lies in the comparison of simulated past hydrology with appropriate palaeo-records. Examples are given as how some indicators (groundwater head, swamp zones) can be used to tend to model validation. Quantifying the relative impact of land use and climate changes requires running sensitivity simulations where the models using alternative land use are run with the climate forcing of other periods. A few examples of such sensitivity runs are presented in order to compare the influence of land use and climate change on the study area hydrology.

Institutions in transitioning peri-urban communities: spatial differences in groundwater access

NASA Astrophysics Data System (ADS)

Gomes, Sharlene L.; Hermans, Leon M.

2016-05-01

Urbanization creates challenges for water management in an evolving socio-economic context. This is particularly relevant in transitioning peri-urban areas like Khulna, Bangladesh where competing demands have put pressure on local groundwater resources. Users are unable to sufficiently meet their needs through existing institutions. These institutions provide the rules for service provision and act as guidelines for actors to resolve their water related issues. However, the evolving peri-urban context can produce fragmented institutional arrangements. For example in Khulna, water supply is based on urban and rural boundaries that has created water access issues for peri-urban communities. This has motivated local actors to manage their groundwater needs in various ways. General institutional theories are well developed in literature, yet little is known about institutions in transitioning peri-urban areas. Institutions that fail to adapt to changing dynamics run the risk of becoming obsolete or counter-productive, hence the need for investigating institutional change mechanisms in this context. This paper examines peri-urban case studies from Khulna using the Institutional Analysis and Development framework to demonstrate how institutions have contributed to spatial differences in groundwater access with local actors investing in formal and informal institutional change as a means of accessing groundwater.

Age and speciation of iodine in groundwater and mudstones of the Horonobe area, Hokkaido, Japan: Implications for the origin and migration of iodine during basin evolution

NASA Astrophysics Data System (ADS)

Togo, Yoko S.; Takahashi, Yoshio; Amano, Yuki; Matsuzaki, Hiroyuki; Suzuki, Yohey; Terada, Yasuko; Muramatsu, Yasuyuki; Ito, Kazumasa; Iwatsuki, Teruki

2016-10-01

This paper reports the concentration, speciation and isotope ratio (129I/127I) of iodine from both groundwater and host rocks in the Horonobe area, northern Hokkaido, Japan, to clarify the origin and migration of iodine in sedimentary rocks. Cretaceous to Quaternary sedimentary rocks deposited nearly horizontally in Tenpoku Basin and in the Horonobe area were uplifted above sea level during active tectonics to form folds and faults in the Quaternary. Samples were collected from the Pliocene Koetoi and late Miocene Wakkanai formations (Fms), which include diatomaceous and siliceous mudstones. The iodine concentration in groundwater, up to 270 μmol/L, is significantly higher than that of seawater, with the iodine enrichment factor relative to seawater reaching 800-1500. The iodine concentration in the rocks decreases from the Koetoi to Wakkanai Fms, suggesting that iodine was released into the water from the rocks of deeper formations. The iodine concentration in the rocks is sufficiently high for forming iodine-rich groundwater as found in this area. X-ray absorption near edge structure (XANES) analysis shows that iodine exists as organic iodine and iodide (I-) in host rocks, whereas it exists mainly as I- in groundwater. The isotope ratio is nearly constant for iodine in the groundwater, at [0.11-0.23] × 10-12, and it is higher for iodine in rocks, at [0.29-1.1] × 10-12, giving iodine ages of 42-60 Ma and 7-38 Ma, respectively. Some iodine in groundwater must have originated from Paleogene and even late Cretaceous Fms, which are also considered as possible sources of oil and gas, in view of the old iodine ages of the groundwater. The iodine ages of the rocks are older than the depositional ages, implying that the rocks adsorbed some iodine from groundwater, which was sourced from greater depths. The iodine concentration in groundwater decreases with decreasing chlorine concentration due to mixing of iodine-rich connate water and meteoric water. A likely scenario is that iodine-rich brine formed during the long-term basin evolution from the Cretaceous to Quaternary and that this brine was diluted by mixing with meteoric water during uplifting and denudation of the area.

Use of mineral/solution equilibrium calculations to assess the potential for carnotite precipitation from groundwater in the Texas Panhandle, USA

USGS Publications Warehouse

Ranalli, Anthony J.; Yager, Douglas B.

2016-01-01

This study investigated the potential for the uranium mineral carnotite (K2(UO2)2(VO4)2·3H2O) to precipitate from evaporating groundwater in the Texas Panhandle region of the United States. The evolution of groundwater chemistry during evaporation was modeled with the USGS geochemical code PHREEQC using water-quality data from 100 groundwater wells downloaded from the USGS National Water Information System (NWIS) database. While most modeled groundwater compositions precipitated calcite upon evaporation, not all groundwater became saturated with respect to carnotite with the system open to CO2. Thus, the formation of calcite is not a necessary condition for carnotite to form. Rather, the determining factor in achieving carnotite saturation was the evolution of groundwater chemistry during evaporation following calcite precipitation. Modeling in this study showed that if the initial major-ion groundwater composition was dominated by calcium-magnesium-sulfate (>70 precent Ca + Mg and >50 percent SO4 + Cl) or calcium-magnesium-bicarbonate (>70 percent Ca + Mg and <70 percent HCO3 + CO3) and following the precipitation of calcite, the concentration of calcium was greater than the carbonate alkalinity (2mCa+2 > mHCO3− + 2mCO3−2) carnotite saturation was achieved. If, however, the initial major-ion groundwater composition is sodium-bicarbonate (varying amounts of Na, 40–100 percent Na), calcium-sodium-sulfate, or calcium-magnesium-bicarbonate composition (>70 percent HCO3 + CO3) and following the precipitation of calcite, the concentration of calcium was less than the carbonate alkalinity (2mCa+2 < mHCO3- + 2mCO3−2) carnotite saturation was not achieved. In systems open to CO2, carnotite saturation occurred in most samples in evaporation amounts ranging from 95 percent to 99 percent with the partial pressure of CO2 ranging from 10−3.5 to 10−2.5 atm. Carnotite saturation occurred in a few samples in evaporation amounts ranging from 98 percent to 99 percent with the partial pressure of CO2 equal to 10−2.0 atm. Carnotite saturation did not occur in any groundwater with the system closed to CO2.

Geochemical evolution of groundwater salinity at basin scale: a case study from Datong basin, Northern China.

PubMed

Wu, Ya; Wang, Yanxin

2014-05-01

A hydrogeochemical investigation using integrated methods of stable isotopes ((18)O, (2)H), (87)Sr/(86)Sr ratios, Cl/Br ratios, chloride-mass balance, mass balance and hydrogeochemical modeling was conducted to interpret the geochemical evolution of groundwater salinity in Datong basin, northern China. The δ(2)H, δ(18)O ratios in precipitation exhibited a local meteoric water line of δ(2)H = 6.4 δ(18)O -5 (R(2) = 0.94), while those in groundwater suggested their meteoric origin in a historically colder climatic regime with a speculated recharge rate of less than 20.5 mm overall per year, in addition to recharge from a component of deep residual ancient lake water enriched with Br. According to the Sr isotope binary mixing model, the mixing of recharges from the Shentou karst springs (24%), the western margins (11%) and the eastern margins (65%) accounts for the groundwater from the deep aquifers of the down-gradient parts in the central basin is a possible mixing mechanism. In Datong, hydrolysis of silicate minerals is the most important hydrogeochemical process responsible for groundwater chemistry, in addition to dissolution of carbonate and evaporites. In the recharge areas, silicate chemical weathering is typically at the bisiallitization stage, while that in the central basin is mostly at the monosiallitization stage with limited evidence of being in equilibrium with gibbsite. Na exchange with bound Ca, Mg prevails at basin scale, and intensifies with groundwater salinity, while Ca, Mg exchange with bound Na locally occurs in the east pluvial and alluvial plains. Although groundwater salinity increases with the progress of water-rock/sediment interactions along the flow path, as a result of carbonate solubility control and continuous evapotranspiration, Na-HCO3 and Na-Cl-SO4 types of water are usually characterized respectively in the deep and the shallow aquifers of an inland basin with a silicate terrain in an arid climatic regime.

Geochemistry of mineral waters and associated gases of the Sakhalin Island (Far East of Russia)

NASA Astrophysics Data System (ADS)

Chelnokov, George A.; Bragin, Ivan V.; Kharitonova, Natalia A.

2018-04-01

Isotopic and chemical data on the mineral water, mud volcanoes fluid and associated gases from the biggest Russian island Sakhalin, together with previous stable isotope data (d18O, dD, 13C), allow elucidation of their origin and general evolution. The water fluid circulation is mainly related to marine environment inducing three distinct types: Na-HCO3-Cl alkali carbonate groundwaters, Na-Cl-HCO3 highly evolved saline and Na-Cl mature groundwaters, indicating different evolution. Chemical evolution of groundwater on Sakhalin Island demonstrated cation exchange and salinization as dominant evolutionary pathways. Isotopic composition of groundwaters varies from meteoric to metamorphic waters. These metamorphic waters consist of water hydration from the clay and seawater are traced in fluids of Yuzhno-Sakhalin mud volcano despite modification by mixing with meteoric waters and water-rock interaction processes. Fault systems that define the areas of highly mineralized water circulation appear to play a major role in the CO2 migration to the surface and CH4 generation. The δ13C(CO2) values have pointed that gas phase in high-pCO2 waters mostly consists of mantle-derived CO2. The carbon isotope signature of methane δ13C(CH4) and δD(CH4) indicates its distinct origin which is specified by tectonics. Methane manifestation in the south of the Sakhalin Island is mainly related to thermogenic reservoirs as they are more often dislocate by tectonics, and crossed by active and permeable faults. The sources of biogenous methane in the north of Sakhalin Island is related to younger and shallower reservoirs, and less affected by tectonic processes. The determinations of 222Rn have allowed observing that maximal radon flux is associated with high pCO2 waters.

Radial Growth of Self-Catalyzed GaAs Nanowires and the Evolution of the Liquid Ga-Droplet Studied by Time-Resolved in Situ X-ray Diffraction.

PubMed

Schroth, Philipp; Jakob, Julian; Feigl, Ludwig; Mostafavi Kashani, Seyed Mohammad; Vogel, Jonas; Strempfer, Jörg; Keller, Thomas F; Pietsch, Ullrich; Baumbach, Tilo

2018-01-10

We report on a growth study of self-catalyzed GaAs nanowires based on time-resolved in situ X-ray structure characterization during molecular-beam-epitaxy in combination with ex situ scanning-electron-microscopy. We reveal the evolution of nanowire radius and polytypism and distinguish radial growth processes responsible for tapering and side-wall growth. We interpret our results using a model for diameter self-stabilization processes during growth of self-catalyzed GaAs nanowires including the shape of the liquid Ga-droplet and its evolution during growth.

Simulation of future groundwater recharge using a climate model ensemble and SAR-image based soil parameter distributions - A case study in an intensively-used Mediterranean catchment.

PubMed

Herrmann, Frank; Baghdadi, Nicolas; Blaschek, Michael; Deidda, Roberto; Duttmann, Rainer; La Jeunesse, Isabelle; Sellami, Haykel; Vereecken, Harry; Wendland, Frank

2016-02-01

We used observed climate data, an ensemble of four GCM-RCM combinations (global and regional climate models) and the water balance model mGROWA to estimate present and future groundwater recharge for the intensively-used Thau lagoon catchment in southern France. In addition to a highly resolved soil map, soil moisture distributions obtained from SAR-images (Synthetic Aperture Radar) were used to derive the spatial distribution of soil parameters covering the full simulation domain. Doing so helped us to assess the impact of different soil parameter sources on the modelled groundwater recharge levels. Groundwater recharge was simulated in monthly time steps using the ensemble approach and analysed in its spatial and temporal variability. The soil parameters originating from both sources led to very similar groundwater recharge rates, proving that soil parameters derived from SAR images may replace traditionally used soil maps in regions where soil maps are sparse or missing. Additionally, we showed that the variance in different GCM-RCMs influences the projected magnitude of future groundwater recharge change significantly more than the variance in the soil parameter distributions derived from the two different sources. For the period between 1950 and 2100, climate change impacts based on the climate model ensemble indicated that overall groundwater recharge will possibly show a low to moderate decrease in the Thau catchment. However, as no clear trend resulted from the ensemble simulations, reliable recommendations for adapting the regional groundwater management to changed available groundwater volumes could not be derived. Copyright © 2015 Elsevier B.V. All rights reserved.

Groundwater Drought and Recovery: a Case Study from the United Kingdom

NASA Astrophysics Data System (ADS)

Peach, D.; McKenzie, A. A.; Bloomfield, J.

2012-12-01

An understanding of the processes leading to the onset, duration and end of hydrological droughts is necessary to help improve the management of stressed or scarce water resources during such periods. In particular, the role and use of groundwater during episodes of drought is crucially important, since groundwater can provide relatively resilient water supplies during early stages of drought but maybe highly susceptible to relatively persistent or sustained droughts. Nevertheless, groundwater is seldom considered in drought analyses, and compared with other types of hydrological drought there have been few studies to date. The few previous studies of groundwater droughts at catchment- and regional-scale have shown that catchment and aquifer characteristics exert a strong influence on the spatio-temporal development of groundwater droughts as water deficit propagates through the terrestrial water cycle. In this context, the relationships between hydrogeological heterogeneity, catchment engineering infrastructure (storage), and decisions related to water resource management during drought events all shape the evolution and consequences of groundwater droughts. Here we examine the evolution of a recent regionally significant two-year drought across the United Kingdom (UK) and use it to investigate these relationships. We identify the drivers, characterise the development and spatio-temporal extent of the groundwater drought. In particular, we focus on the unusually rapid end and recovery from drought during what would normally be a period of groundwater recession. The UK, and in particular southern England, relies extensively on groundwater for public water supply, agricultural and industrial use, as well as for sustaining river flows that are essential to ecosystem health. In normal years relatively consistent rainfall patterns prevail, recharging aquifers over winter when evapotranspiration is minimal. However, by March 2012 large parts of the southern UK had experienced accumulated rainfall deficiencies over 24 months or more. Such rainfall deficiencies could, on aver¬age, only be expected around once every 20 to 30 years. The rainfall deficiencies were disproportionately concentrated in the winter/spring periods leading to significant reductions in groundwater recharge over the winters of 2010-11 and particularly 2011-12. At it's height in March 2012 groundwater levels were at historically low levels with estimated overall storage in the Chalk aquifer, the principal aquifer in the UK, lower than at the same time in 1976, the previous benchmark drought for the UK. Natural base levels had been reached or closely approached at a number of index wells early in the hydrometric year and groundwater recession was expected to continue with the prospect of overall groundwater resources being comparable with, or below, the lowest in the last 100 years by the autumn of 2012. However, a significant change in weather in spring 2012 led to three months (April to June) of exceptional rainfall, mitigating the drought and leading to anomalous groundwater recharge at a time of year when soil moisture deficits are normally significant.

Effects of urbanization on groundwater evolution in an urbanizing watershed

NASA Astrophysics Data System (ADS)

Reyes, D.; Banner, J. L.; Bendik, N.

2011-12-01

The Jollyville Plateau Salamander (Eurycea tonkawae), a candidate species for listing under the Endangered Species Act, is endemic to springs and caves within the Bull Creek Watershed of Austin, Texas. Rapid urbanization endangers known populations of this salamander. Conservation strategies lack information on the extent of groundwater contamination from anthropogenic sources in this karst watershed. Spring water was analyzed for strontium (Sr) isotopes and major ions from sites classified as "urban" or "rural" based on impervious cover estimates. Previous studies have shown that the 87Sr/86Sr value of municipal water is significantly higher than values for natural streamwater, which are similar to those for the Cretaceous limestone bedrock of the region's watersheds. We investigate the application of this relationship to understanding the effects of urbanization on groundwater quality. The use of Sr isotopes as hydrochemical tracers is complemented by major ion concentrations, specifically the dominant ions in natural groundwater (Ca and HCO3) and the ions associated with the addition of wastewater (Na and Cl). To identify high priority salamander-inhabited springs for water quality remediation, we explore the processes controlling the chemical evolution of groundwater such as municipal water inputs, groundwater-soil interactions, and solution/dissolution reactions. 87Sr/86Sr values for water samples from within the watershed range from 0.70760 to 0.70875, the highest values corresponding to sites located in the urbanized areas of the watershed. Analyses of the covariation of Sr isotopes with major ion concentrations help elucidate controls on spring water evolution. Springs located in rural portions of the watershed have low 87Sr/86Sr, high concentrations of Ca and HCO3, and low concentrations of Na and Cl. This is consistent with small inputs of municipal water. Three springs located in urban portions of the watershed have high 87Sr/86Sr, low Ca and HCO3, and high Na and Cl. This is consistent with large inputs of municipal water. The other five springs located in urban portions have low 87Sr/86Sr, low concentrations of Ca and HCO3, and high concentrations of Na and Cl. This is reflects a process other than an input of municipal water. Groundwater interaction with soils generally results in higher Na concentrations relative to Ca. 87Sr/86Sr values in this scenario may increase or decrease, depending on the Sr isotope variability of the local soils. Alternatively, precipitation of calcite from groundwater would decrease the concentration of Ca without necessarily decreasing 87Sr/86Sr values. The results suggest more anthropogenic water in urban springs than rural springs. These data serve to identify sources of spring recharge, including better constraints on the location(s) of urban leakage.

Ground-water conditions in the central Virgin River basin, Utah

USGS Publications Warehouse

Cordova, R.M.; Sandberg, G.W.; McConkie, Wilson

1972-01-01

Water-rights problems have occurred in the central Virgin River basin and are expected to increase as development of the water resources increases. The Utah State Engineer needs a basic knowledge of ground-water conditions and of the relation of ground water to surface water as a first step to understanding and resolving the problems. Accordingly, the State Engineer requested the U. S. Geological Survey to make a ground-water investigation of the central Virgin River basin as part of the Statewide cooperative agreement with the Utah Department of Natural Resources. The investigation was begun July 1, 1968, and fieldwork was completed in August 1970. Detailed information was obtained for the principal aquifers and for recharge, movement, discharge, storage, utilization, and chemical quality of ground water. A progress report (Cordova, Sandberg, and McConkie, 1970) describes the general findings in the first year of the investigation.

Hydrogeological modelling as a tool for understanding rockslides evolution

NASA Astrophysics Data System (ADS)

Crosta, Giovanni B.; De Caro, Mattia; Frattini, Paolo; Volpi, Giorgio

2015-04-01

Several case studies of large rockslides have been presented in the literature showing dependence of displacement rate on seasonal and annual changes of external factors (e.g. rainfall, snowmelt, temperature oscillations) or on human actions (e.g. impounding of landslide toe by artificial lakes, toe excavation). The study of rockslide triggering can focus on either the initial failure or the successive reactivations driven by either meteo-climatic events or other perturbations (e.g. seismic, anthropic). A correlation between groundwater level oscillations and slope movements has been observed at many different sites and in very different materials and slope settings. This seasonal dynamic behavior generally shows a delay between perturbation (e.g., groundwater recharge and increase in water table level) and system reaction (e.g., increase in displacement rate). For this reason, groundwater modeling offers the means for assessing the oscillation of groundwater level which is a major input in rockslide and deep-seated gravitational slope deformation modelling, and that could explain both the initial failure event as well the successive reactivation or the continuous slow motion. Using a finite element software (FEFLOW, WASY GmbH) we developed 2D saturated/unsaturated and steady-state/transient groundwater flow models for two case studies for which a suitable dataset is available: the Vajont rockslide (from 1960 to October 9th 1963) and the Mt. de La Saxe rockslide (2009-2012, Aosta valley; Italian Western Alps). The transient models were implemented starting from hydraulic head distributions simulated in the previous steady-state models to investigate the groundwater fluctuation within the two chosen times interval (Vajont: 1960-1963 ; La Saxe: 2009-2012). Time series of infiltration resulting from precipitation, temperature, snowmelt data (La Saxe rockslide) and reservoir level (Vajont rockslide) were applied to the models. The assumptions made during the construction of the models, in particular the partition of the slope in different sectors with different hydraulic conductivities, are coherent with the geological, structural, hydrological and hydrogeological field and laboratory data. The sensitivity analysis shows that the hydraulic conductivity of some slope sectors (e.g. morphostructures, compressed or relaxed slope-toe, basal shear band) strongly influence the water table position and evolution. In transient models, the values of specific storage coefficient play a major control on the amplitude of groundwater level fluctuations, deriving from snowmelt or induced reservoir level rise. The calibrated groundwater flow-models are consistent with groundwater levels measured in the proximity of the piezometers aligned along the sections. The two examples can be considered important for a more advanced understanding of the evolution of rockslides and suggest the required set of data and modelling approaches both for seasonal and long term slope stability analyses. The use of the results of such analyses is reported, for both the case studies, in a companion abstract in session 3.7 where elasto-visco-plastic rheologies have been adopted for the shear band materials to replicate the available displacement time-series.

Simulating the impact of glaciations on continental groundwater flow systems: 1. Relevant processes and model formulation

NASA Astrophysics Data System (ADS)

Lemieux, J.-M.; Sudicky, E. A.; Peltier, W. R.; Tarasov, L.

2008-09-01

In the recent literature, it has been shown that Pleistocene glaciations had a large impact on North American regional groundwater flow systems. Because of the myriad of complex processes and large spatial scales involved during periods of glaciation, numerical models have become powerful tools to examine how ice sheets control subsurface flow systems. In this paper, the key processes that must be represented in a continental-scale 3-D numerical model of groundwater flow during a glaciation are reviewed, including subglacial infiltration, density-dependent (i.e., high-salinity) groundwater flow, permafrost evolution, isostasy, sea level changes, and ice sheet loading. One-dimensional hydromechanical coupling associated with ice loading and brine generation were included in the numerical model HydroGeoSphere and tested against newly developed exact analytical solutions to verify their implementation. Other processes such as subglacial infiltration, permafrost evolution, and isostasy were explicitly added to HydroGeoSphere. A specified flux constrained by the ice sheet thickness was found to be the most appropriate boundary condition in the subglacial environment. For the permafrost, frozen and unfrozen elements can be selected at every time step with specified hydraulic conductivities. For the isostatic adjustment, the elevations of all the grid nodes in each vertical grid column below the ice sheet are adjusted uniformly to account for the Earth's crust depression and rebound. In a companion paper, the model is applied to the Wisconsinian glaciation over the Canadian landscape in order to illustrate the concepts developed in this paper and to better understand the impact of glaciation on 3-D continental groundwater flow systems.

Non-targeted analysis of petroleum metabolites in groundwater using GC×GC-TOFMS.

PubMed

Mohler, Rachel E; O'Reilly, Kirk T; Zemo, Dawn A; Tiwary, Asheesh K; Magaw, Renae I; Synowiec, Karen A

2013-09-17

Groundwater at fuel release sites often contains nonpolar hydrocarbons that originate from both the fuel release and other environmental sources, as well as polar metabolites of petroleum biodegradation. These compounds, along with other polar artifacts, can be quantified as "total petroleum hydrocarbons" using USEPA Methods 3510/8015B, unless a silica gel cleanup step is used to separate nonpolar hydrocarbons from polar compounds prior to analysis. Only a limited number of these metabolites have been identified by traditional GC-MS methods, because they are difficult to resolve using single-column configurations. Additionally, the targeted use of derivatization limits the detection of many potential metabolites of interest. The objective of this research was to develop a nontargeted GC×GC-TOFMS approach to characterize petroleum metabolites in environmental samples gathered from fuel release sites. The method tentatively identified more than 760 unique polar compounds, including acids/esters, alcohols, phenols, ketones, and aldehydes, from 22 groundwater samples collected at five sites. Standards for 28 polar compounds indicate that effective limits of quantitation for most of these compounds in the groundwater samples range from 1 to 11 μg/L.

Groundwater recharge and agricultural contamination

USGS Publications Warehouse

Böhlke, J.K.

2002-01-01

Agriculture has had direct and indirect effects on the rates and compositions of groundwater recharge and aquifer biogeochemistry. Direct effects include dissolution and transport of excess quantities of fertilizers and associated materials and hydrologic alterations related to irrigation and drainage. Some indirect effects include changes in water–rock reactions in soils and aquifers caused by increased concentrations of dissolved oxidants, protons, and major ions. Agricultural activities have directly or indirectly affected the concentrations of a large number of inorganic chemicals in groundwater, for example NO3–, N2, Cl, SO42–, H+, P, C, K, Mg, Ca, Sr, Ba, Ra, and As, as well as a wide variety of pesticides and other organic compounds. For reactive contaminants like NO3–, a combination of chemical, isotopic, and environmental-tracer analytical approaches might be required to resolve changing inputs from subsequent alterations as causes of concentration gradients in groundwater. Groundwater records derived from multi-component hydrostratigraphic data can be used to quantify recharge rates and residence times of water and dissolved contaminants, document past variations in recharging contaminant loads, and identify natural contaminant-remediation processes. These data indicate that many of the world's surficial aquifers contain transient records of changing agricultural contamination from the last half of the 20th century. The transient agricultural groundwater signal has important implications for long-term trends and spatial heterogeneity in discharge.

The origin and evolution of safe-yield policies in the Kansas groundwater management districts

USGS Publications Warehouse

Sophocleous, M.

2000-01-01

The management of groundwater resources in Kansas continues to evolve. Declines in the High Plains aquifer led to the establishment of groundwater management districts in the mid-1970s and reduced streamflows prompted the enactment of minimum desirable streamflow standards in the mid-1980s. Nonetheless, groundwater levels and streamflows continued to decline, although at reduced rates compared to premid-1980s rates. As a result, "safe-yield" policies were revised to take into account natural groundwater discharge in the form of stream baseflow. These policies, although a step in the right direction, are deficient in several ways. In addition to the need for more accurate recharge data, pumping-induced streamflow depletion, natural stream losses, and groundwater evapotranspiration need to be accounted for in the revised safe-yield policies. Furthermore, the choice of the 90% flow-duration statistic as a measure of baseflow needs to be reevaluated, as it significantly underestimates mean baseflow estimated from baseflow separation computer programs; moreover, baseflow estimation needs to be refined and validated. ?? 2000 International Association for Mathematical Geology.

[Hydrogeochemical characteristics of a typical karst groundwater system in Chongqing].

PubMed

Yang, Ping-Heng; Lu, Bing-Qing; He, Qiu-Fang; Chen, Xue-Bin

2014-04-01

The two-year hydrologic process, hydrochemistry, and a portion of deltaD, delta18O of both the surface water at the inlet and the groundwater at the outlet, were investigated to identify the spatial and temporal variations of hydrogeochemistry in the Qingmuguan karst groundwater system. Research results show that there are wet and dry periods in the groundwater system owing to the striking influence of seasonal rainfall. The evolution of the chemical compositions in the groundwater is significantly influenced by the water and rock interaction, anthropogenic activities and rainwater dilution. The variations of the chemical compositions in the groundwater exhibit obvious spatiality and temporality. The deltaD and delta18O of the surface water beneath the local Meteoric Water Line of Chonqing indicate that the surface water is strongly evaporated. Furthermore, the deltaD and delta18O of the surface water are more positive in the dry period than in the wet period, showing a distinct seasonal effect. The deltaD and delta18O of the groundwater are quite stable and much negative compared with those of the surface water, which suggests that the rainwater recharge the groundwater via two pathways, one directly through sinkholes and the other via the vadose zone.

Mapping groundwater level and aquifer storage variations from InSAR measurements in the Madrid aquifer, Central Spain

NASA Astrophysics Data System (ADS)

Béjar-Pizarro, Marta; Ezquerro, Pablo; Herrera, Gerardo; Tomás, Roberto; Guardiola-Albert, Carolina; Ruiz Hernández, José M.; Fernández Merodo, José A.; Marchamalo, Miguel; Martínez, Rubén

2017-04-01

Groundwater resources are under stress in many regions of the world and the future water supply for many populations, particularly in the driest places on Earth, is threatened. Future climatic conditions and population growth are expected to intensify the problem. Understanding the factors that control groundwater storage variation is crucial to mitigate its adverse consequences. In this work, we apply satellite-based measurements of ground deformation over the Tertiary detritic aquifer of Madrid (TDAM), Central Spain, to infer the spatio-temporal evolution of water levels and estimate groundwater storage variations. Specifically, we use Persistent Scatterer Interferometry (PSI) data during the period 1992-2010 and piezometric time series on 19 well sites covering the period 1997-2010 to build groundwater level maps and quantify groundwater storage variations. Our results reveal that groundwater storage loss occurred in two different periods, 1992-1999 and 2005-2010 and was mainly concentrated in a region of ∼200 km2. The presence of more compressible materials in that region combined with a long continuous water extraction can explain this volumetric deficit. This study illustrates how the combination of PSI and piezometric data can be used to detect small aquifers affected by groundwater storage loss helping to improve their sustainable management.

Hydrochemical analysis to evaluate the seawater ingress in a small coral island of India.

PubMed

Banerjee, Pallavi; Singh, V S; Singh, Ajay; Prasad, R K; Rangarajan, R

2012-06-01

The sustainable development of the limited groundwater resources in the tropical island requires a thorough understanding of detail hydrogeological regime including the hydrochemical behavior of groundwater. Detail analysis of chemical data of groundwater helps in assessing the different groundwater zone affected by formation as well as sea water. Groundwater and saline water interaction is better understood using groundwater major ion chemistry over an island aquifer. Multivariate methods to analyze the geochemical data are used to understand geochemical evolution of groundwater. The methods are successfully used to group the data to evaluate influence of various environs in the study area. Various classification methods such as piper, correlation method, and salinity hazard measurements are also employed to critical study of geochemical characteristics of groundwater to identify vulnerable parts of the aquifer. These approaches have been used to successfully evaluate the aquifer zones of a tiny island off the west coast of India. The most part of island is found to be safe for drinking, however some parts of island are identified that are affected by sea water ingress and dissolution of formation minerals. The analysis has successfully leaded to identification of that part of aquifer on the island which needs immediate attention for restoration and avoids further deterioration.

Comparison of a vertically-averaged and a vertically-resolved model for hyporheic flow beneath a pool-riffle bedform

NASA Astrophysics Data System (ADS)

Ibrahim, Ahmad; Steffler, Peter; She, Yuntong

2018-02-01

The interaction between surface water and groundwater through the hyporheic zone is recognized to be important as it impacts the water quantity and quality in both flow systems. Three-dimensional (3D) modeling is the most complete representation of a real-world hyporheic zone. However, 3D modeling requires extreme computational power and efforts; the sophistication is often significantly compromised by not being able to obtain the required input data accurately. Simplifications are therefore often needed. The objective of this study was to assess the accuracy of the vertically-averaged approximation compared to a more complete vertically-resolved model of the hyporheic zone. The groundwater flow was modeled by either a simple one-dimensional (1D) Dupuit approach or a two-dimensional (2D) horizontal/vertical model in boundary fitted coordinates, with the latter considered as a reference model. Both groundwater models were coupled with a 1D surface water model via the surface water depth. Applying the two models to an idealized pool-riffle sequence showed that the 1D Dupuit approximation gave comparable results in determining the characteristics of the hyporheic zone to the reference model when the stratum thickness is not very large compared to the surface water depth. Conditions under which the 1D model can provide reliable estimate of the seepage discharge, upwelling/downwelling discharges and locations, the hyporheic flow, and the residence time were determined.

[Prokaryote diversity in water environment of land-ocean ecotone of Zhuhai City].

PubMed

Huang, Xiao-Lan; Chen, Jian-Yao; Zhou, Shi-Ning; Xie, Li-Chun; Fu, Cong-Sheng

2010-02-01

By constructing 16S rDNA clone library with PCR-RFLP, the prokaryote diversity in the seawater and groundwater of land-ocean ecotone of Zhuhai City was investigated, and the similarity and cluster analyses were implemented with the database of the sequences in Genbank. In the seawater, Proteobacteria was dominant, followed by Archaeon, Gemmatimonadetes, Candidate division OP3 and OP8, and Planctomycetes, etc.; while in the groundwater, Archaeon was dominant, followed by Proteobacteria, Sphingobacteria, Candidate division OP3, Actinobacterium, and Pseudomonas. The dominant taxa in the groundwater had high similarity to the unculturable groups of marine microorganisms. Large amount of bacteria capable of degrading organic matter and purifying water body existed in the groundwater, suggesting that after long-term evolution, the land-ocean ecotone of Zhuhai City had the characteristics of both land and ocean.

The Mojave River from sink to source: The 2018 Desert Symposium Field Trip Road Log

USGS Publications Warehouse

Miller, David; Reynolds, R.E.; Groover, Krishangi D.; Buesch, David C.; Brown, H. J.; Cromwell, Geoffrey; Densmore-Judy, Jill; Garcia, A.L.; Hughson, D.; Knott, J.R.; Lovich, Jeffrey E.

2018-01-01

The Mojave River evolved over the past few million years by “fill and spill” from upper basins near its source in the Transverse Ranges to lower basins. Each newly “spilled into” basin in the series? sustained a long-lived lake but gradually filled with Mojave River sediment, leading to spill to a yet lower elevation? basin. The Mojave River currently terminates at Silver Lake, near Baker, CA, but previously overflowed this terminus onward to Lake Manly in Death Valley during the last glacial cycle. The river’s origin and evolution are intricately interwoven with tectonic, climatic, and geomorphic processes through time, beginning with San Andreas fault interactions that created a mountain range across a former externally draining river. We will see and discuss the Mojave River’s predecessor streams and basins, its evolution as it lengthened to reach the central Mojave Desert, local and regional tectonic controls, groundwater flow, flood history, and support of isolated perennial stream reaches that host endemic species. In association with these subjects are supporting studies such as paleoclimate records, location and timing for groundwater and wetlands in the central Mojave Desert, and effects of modern water usage. The trip introduces new findings for the groundwater basin of Hinkley Valley, including an ongoing remediation project that provides a wealth of information on past and present river flow and associated development of the groundwater system.

Use of modflow drain package for simulating inter-basin transfer in abandoned coal mines

USGS Publications Warehouse

Kozar, Mark D.; McCoy, Kurt J.

2017-01-01

Simulation of groundwater flow in abandoned mines is difficult, especially where flux to and from mines is unknown or poorly quantified, and inter-basin transfer of groundwater occurs. A 3-year study was conducted in the Elkhorn area, West Virginia to better understand groundwater-flow processes and inter-basin transfer in above drainage abandoned coal mines. The study area was specifically selected, as all mines are located above the elevation of tributary receiving streams, to allow accurate measurements of discharge from mine portals and tributaries for groundwater model calibration. Abandoned mine workings were simulated in several ways, initially as a layer of high hydraulic conductivity bounded by lower permeability rock in adjacent strata, and secondly as rows of higher hydraulic conductivity embedded within a lower hydraulic conductivity coal aquifer matrix. Regardless of the hydraulic conductivity assigned to mine workings, neither approach to simulate mine workings could accurately reproduce the inter-basin transfer of groundwater from adjacent watersheds. To resolve the problem, a third approach was developed. The MODFLOW DRAIN package was used to simulate seepage into and through mine workings discharging water under unconfined conditions to Elkhorn Creek, North Fork, and tributaries of the Bluestone River. Drain nodes were embedded in a matrix of uniform hydraulic conductivity cells that represented the coal mine aquifer. Drain heads were empirically defined from well observations, and elevations were based on structure contours for the Pocahontas No. 3 mine workings. Use of the DRAIN package to simulate mine workings as an internal boundary condition resolved the inter-basin transfer problem, and effectively simulated a shift from a topographic- dominated to a dip-dominated flow system, by dewatering overlying unmined strata and shifting the groundwater drainage divide up dip within the Pocahontas No. 3 coal seam several kilometers into the adjacent Bluestone River Watershed. Model simulations prior to use of the DRAIN package for simulating mine workings produced estimated flows of 0.32 to 0.34 m3/s in each of the similar sized Elkhorn Creek and North Fork Watersheds, but failed to estimate inter-basin transfer of groundwater from the adjacent Bluestone River Watershed. The simulation of mine entries and discharge using the MODFLOW DRAIN package produced estimated flows of 0.46 and 0.26 m3/s for the Elkhorn Creek and North Fork watersheds respectively, which matched well measured flows for the respective watersheds of 0.47 and 0.26 m3/s.

The role of uplift and erosion in the persistence of saline groundwater in the shallow subsurface

NASA Astrophysics Data System (ADS)

Yager, R. M.; McCoy, K. J.; Voss, C. I.; Sanford, W. E.; Winston, R. B.

2017-04-01

In many regions of the world, the shallow (<300 m) subsurface is replenished with meteoric recharge within a few centuries or millennia, but in some regions saline groundwater persists despite abundant rainfall. Analyses of the flushing rate of shallow groundwater usually consider the permeability and recharge rate and a static landscape. The influence of landscape evolution can become important over millions of years, however. Here we present numerical simulations of fluid flow and transport in the top 1 km of a sedimentary foreland basin dominated by aquitards, where the rate of uplift and erosion (20 m Ma-1) balances that of meteoric flushing. Paleozoic age saline groundwater and brine persist at shallow depths that might otherwise have contained potable water. Similar hydrogeologic conditions, and uplift and erosion rates, likely exist in many other regions of the world, where a moving landscape has probably never been considered as an important contributor to groundwater quality.

The role of uplift and erosion in the persistence of saline groundwater in the shallow subsurface

USGS Publications Warehouse

Yager, Richard M.; McCoy, Kurt J.; Voss, Clifford I.; Sanford, Ward E.; Winston, Richard B.

2017-01-01

In many regions of the world, the shallow (<300 m) subsurface is replenished with meteoric recharge within a few centuries or millennia, but in some regions saline groundwater persists despite abundant rainfall. Analyses of the flushing rate of shallow groundwater usually consider the permeability and recharge rate and a static landscape. The influence of landscape evolution can become important over millions of years, however. Here we present numerical simulations of fluid flow and transport in the top 1 km of a sedimentary foreland basin dominated by aquitards, where the rate of uplift and erosion (20 m Ma−1) balances that of meteoric flushing. Paleozoic age saline groundwater and brine persist at shallow depths that might otherwise have contained potable water. Similar hydrogeologic conditions, and uplift and erosion rates, likely exist in many other regions of the world, where a moving landscape has probably never been considered as an important contributor to groundwater quality.

Isotopic and Hydrogeochemical Assessment of Groundwater quality of Punjab and Haryana, India.

NASA Astrophysics Data System (ADS)

Jyoti, V.; Douglas, E. M.; Hannigan, R.; Schaaf, C.; Moore, J.

2016-12-01

Punjab and Haryana lie in the semi-arid region of northwestern India and are characterized by a limited access to freshwater resources and an increasing dependence on groundwater resources to meet human demand, resulting in overexploitation. The objectives of the present study was to characterize groundwater recharge sources using stable isotopes of (δ2H) and (δ18O) and to trace geochemical evolution of groundwater using rare earth elements (REEs). Samples were collected from 30 different locations including shallow domestic handpumps, deep irrigation wells, surface water and rainwater. Samples were analyzed for stable isotopes of (δ2H) and (δ18O) using Isotope Ratio Mass Spectrometry (IRMS) and trace elements using Inductively Coupled Plasma Mass Spectrometry (ICPMS) at University of Massachusetts Boston. Precipitation, surface water and irrigation return flow were identified as the primary sources of recharge to groundwater. Sustainability of recharge sources is highly dependent on the glacier-fed rivers from the Himalayas that are already experiencing impacts from climate change. Geochemistry of REEs revealed geochemically evolved groundwater system with carbonate subsurface weathering as major hydrological processes. Enhanced dissolution of carbonates in the future can be a serious issue with extremely hard groundwater leaving scaly deposits inside pipes and wells. This would not only worsen the groundwater quality but would impose financial implications on the groundwater users in the community. If irrigated culture is to survive as an economically viable and environmentally sustainable activity in the region, groundwater management activities have to be planned at the regional scale.

Potential uses of pumped urban groundwater: a case study in Sant Adrià del Besòs (Spain)

NASA Astrophysics Data System (ADS)

Jurado, Anna; Vázquez-Suñé, Enric; Pujades, Estanislao

2017-09-01

Urban groundwater has often been over-exploited for industrial uses. Now, this usage tends to be reduced or the resource abandoned due to pollution and/or changes in land use. The use and the subsequent disuse of groundwater has resulted in rising water tables that damage underground structures (e.g., building basements and underground car parks and tunnels), leading to the need for additional pumping in urban areas. In the case of the underground parking lot of Sant Adrià del Besòs (Barcelona, NE Spain), large amounts of urban groundwater are pumped to avoid seepage problems. Can this pumped groundwater be used for other purposes (e.g., drinking water and urban irrigation) instead of wasting this valuable resource? To answer this question, it was necessary to quantify the groundwater recharge and to assess the evolution of groundwater quality. The limiting factor at this study site is the groundwater quality because ammonium and some metals (iron and manganese) are present at high concentrations. Hence, further treatment would be needed to meet drinking water requirements. The pumped groundwater could also be used for supplementing river flow for ecological benefit and/or for mitigating seawater intrusion problems. Currently, only a small amount of this urban groundwater is used for cleaning public areas and watering public gardens. This situation highlighted the urgent need to manage this resource in a responsible and more efficient manner, especially in moments of high water demand such as drought periods.

Hydrologic and Agent-based Modelling of Hydro-refugia in East Africa, Insights into the Importance of Water Resources in Hominin Evolution and Dispersal

NASA Astrophysics Data System (ADS)

Ashley, G. M.; Cuthbert, M. O.; Gleeson, T. P.; Reynolds, S. R.; Bennett, M. R.; Newton, A. C.; McCormack, C. J.

2017-12-01

Hominin evolution and climate variability have often been linked because of the apparent coincidence of climate fluctuations and speciation or extinctions, although the cause and effect of climate on natural selection is not clear. Climate in the EARS (East African Rift System) where most hominin first occurrences are located experienced an overall drying over the last 7 myr. Superimposed on this trend, Milankovitch cycles generated wet-dry precession cycles ( 23 kyr) that changed both water and food resource availability. During dry periods, lakes became more alkaline and rivers ephemeral but, groundwater, buffered from surface climate effects, remained a potential resource during the driest of times. The possibility of widespread groundwater sources hydro-refugia, such as springs, wetlands and groundwater-fed perennial streams has received little attention with respect to the paleoenvironmental context of hominin evolution or dispersal. We demonstrate that hydrogeological modelling of the modern landscape in East Africa coupled with ABM (agent-based modelling) of hominin movement yields new insight into potential correlates of hominin survival and dispersal. Digitized hydrological mapping of present day rivers, lakes and springs along the EARS (2000 km) from northern Tanzania to Ethiopia provided the modelling framework. Present day conditions are considered analogous to past dry periods; wet period conditions are an expanded hydrologic network including all surface water bodies. Our focus was on perennial springs discharging at 1,000 m3/y (volume to sustain a small wetland). 450 such springs occur and were found to be significantly controlled by geology, not just climate. The ABM was designed to determine if it was possible for humans to walk between hydro-refugia in 3 days. Four climate scenarios were run on ABM: wet, wet-to-dry, dry and dry-to-wet. During dry periods our results suggest that groundwater availability would have been critical to supporting isolated networks of hydro-refugia when potable surface water was scarce. As the climate got wetter modeled cross-rift dispersal potentially occurred before movement along the rift. The presence of groundwater hydro-refugia may help explain how some patterns of taxonomic diversity in hominins may have developed.

Hydrochemical and isotopic characteristics of groundwater in the northeastern Tennger Desert, northern China

NASA Astrophysics Data System (ADS)

Wang, Liheng; Dong, Yanhui; Xu, Zhifang; Qiao, Xiaojuan

2017-12-01

Groundwater is typically the only water source in arid regions, and its circulation processes should be better understood for rational resource exploitation. Stable isotopes and major ions were investigated in the northeastern Tengger Desert, northern China, to gain insights into groundwater recharge and evolution. In the northern mountains, Quaternary unconsolidated sediments, exposed only in valleys between hills, form the main aquifer, which is mainly made of aeolian sand and gravel. Most of the mountain groundwater samples plot along the local meteoric water line (LMWL), with a more depleted signature compared to summer precipitation, suggesting that mountain groundwater was recharged by local precipitation during winter. Most of the groundwater was fresh, with total dissolved solids less than 1 g/L; dominant ions are Na+, SO4 2- and Cl-, and all mineral saturation indices are less than zero. Evaporation, dissolution and cation exchange are the major hydrogeochemical processes. In the southern plains, however, the main aquifers are sandstone. The linear regression line of δD and δ 18O of groundwater parallels the LMWL but the intercept is lower, indicating that groundwater in the plains has been recharged by ancient precipitation rather than modern. Both calcite and dolomite phases in the plains groundwater are close to saturation, while gypsum and halite can still be dissolved into the groundwater. Different recharge mechanisms occur in the northern mountains and the southern plains, and the hydraulic connection between them is weak. Because of the limited recharge, groundwater exploitation should be limited as much as possible.

The effect of plastic strain on the evolution of crystallographic texture in Zircaloy-2

NASA Astrophysics Data System (ADS)

Ballinger, R. G.; Lucas, G. E.; Pelloux, R. M.

1984-09-01

The evolution of crystallographic texture during plastic deformation was investigated in Zircaloy-2 using X-ray and metallographic techniques. Inverse pole figures, the resolved fraction of basal poles, and the volume fraction of twinned material, were determined as a function of plastic strain for several strain paths and initial textures at 298 K and 623 K. Incremental transverse platic strain ratios ( R) were mesured as a function of plastic strain. Texture rotation occurs early in the deformation process, after as little as 1.5% plastic strain. For compressive plastic strains, the resolved fraction of basal poles increases in the direction parallel to the strain axis. For tensile plastic strains, the resolved fraction of basal poles decreases in the direction parallel to the strain axis. The rate of change of the resolved fraction of basal poles with plastic strain is a function of the initial resolved fraction of basal poles. The texture rotation can be explained by considering the operation of the principal tensile twinning systems, {101¯2}<1¯011>.

Field estimates of groundwater circulation depths in two mountainous watersheds in the western U.S. and the effect of deep circulation on solute concentrations in streamflow

NASA Astrophysics Data System (ADS)

Frisbee, Marty D.; Tolley, Douglas G.; Wilson, John L.

2017-04-01

Estimates of groundwater circulation depths based on field data are lacking. These data are critical to inform and refine hydrogeologic models of mountainous watersheds, and to quantify depth and time dependencies of weathering processes in watersheds. Here we test two competing hypotheses on the role of geology and geologic setting in deep groundwater circulation and the role of deep groundwater in the geochemical evolution of streams and springs. We test these hypotheses in two mountainous watersheds that have distinctly different geologic settings (one crystalline, metamorphic bedrock and the other volcanic bedrock). Estimated circulation depths for springs in both watersheds range from 0.6 to 1.6 km and may be as great as 2.5 km. These estimated groundwater circulation depths are much deeper than commonly modeled depths suggesting that we may be forcing groundwater flow paths too shallow in models. In addition, the spatial relationships of groundwater circulation depths are different between the two watersheds. Groundwater circulation depths in the crystalline bedrock watershed increase with decreasing elevation indicative of topography-driven groundwater flow. This relationship is not present in the volcanic bedrock watershed suggesting that both the source of fracturing (tectonic versus volcanic) and increased primary porosity in the volcanic bedrock play a role in deep groundwater circulation. The results from the crystalline bedrock watershed also indicate that relatively deep groundwater circulation can occur at local scales in headwater drainages less than 9.0 km2 and at larger fractions than commonly perceived. Deep groundwater is a primary control on streamflow processes and solute concentrations in both watersheds.

Distinct kinetics and mechanisms of mZVI particles aging in saline and fresh groundwater: H2 Evolution and surface passivation

NASA Astrophysics Data System (ADS)

Xin, Jia; Tang, Fenglin; Zheng, Xilai

2016-04-01

Application of microscale zero-valent iron (mZVI) is a promising technology for in-situ contaminated groundwater remediation. However, its longevity would be negatively impacted by surface passivation, especially in saline groundwater. In this study, the aging behaviors of mZVI particles were investigated in three media (milli-Q water, fresh groundwater and saline groundwater) using batch experiments to evaluate their potential corrosion and passivation performance in different field conditions. The results indicated that mZVI was reactive between 0-7 days exposure to water and then gradually lost reactivity over the next few hundred days. The patterns of kinetic curve were analogous among the three different media. In comparison, during the early phase (0-7 d), mZVI in saline groundwater showed a faster corrosion rate with a k value of 1.357, which was relatively higher than k values in milli-Q water and fresh groundwater. However, as the corrosion process further developed, the fastest corrosion rate was observed in milli-Q water followed with fresh groundwater and saline groundwater. These changes in reactivity provided evidence for different patterns and formation mechanisms of passive layers on mZVI in three media. The SEM-EDS analysis demonstrated that in the saline groundwater, a compact and even oxide film of carbonate green rust or Fe oxide (hydroxyl) species was formed immediately on the surface due to the high concentration and widely distributed bicarbonate and hardness, whereas in the fresh groundwater and milli-Q water, the passive layer was composed of loosely and unevenly distributed precipitates which much slowly formed as the iron corrosion proceeded. These findings provide insight into the molecular-scale mechanism of mZVI passivation by inorganic salts with particular implications in saline groundwater.

PUMa - modelling the groundwater flow in Baltic Sedimentary Basin

NASA Astrophysics Data System (ADS)

Kalvane, G.; Marnica, A.; Bethers, U.

2012-04-01

In 2009-2012 at University of Latvia and Latvia University of Agriculture project "Establishment of interdisciplinary scientist group and modelling system for groundwater research" is implemented financed by the European Social Fund. The aim of the project is to develop groundwater research in Latvia by establishing interdisciplinary research group and modelling system covering groundwater flow in the Baltic Sedimentary Basin. Researchers from fields like geology, chemistry, mathematical modelling, physics and environmental engineering are involved in the project. The modelling system is used as a platform for addressing scientific problems such as: (1) large-scale groundwater flow in Baltic Sedimentary Basin and impact of human activities on it; (2) the evolution of groundwater flow since the last glaciation and subglacial groundwater recharge; (3) the effects of climate changes on shallow groundwater and interaction of hydrographical network and groundwater; (4) new programming approaches for groundwater modelling. Within the frame of the project most accessible geological information such as description of geological wells, geological maps and results of seismic profiling in Latvia as well as Estonia and Lithuania are collected and integrated into modelling system. For example data form more then 40 thousands wells are directly used to automatically generate the geological structure of the model. Additionally a groundwater sampling campaign is undertaken. Contents of CFC, stabile isotopes of O and H and radiocarbon are the most significant parameters of groundwater that are established in unprecedented scale for Latvia. The most important modelling results will be published in web as a data set. Project number: 2009/0212/1DP/1.1.1.2.0/09/APIA/VIAA/060. Project web-site: www.puma.lu.lv

A multitracer approach for characterizing interactions between shallow groundwater and the hydrothermal system in the Norris Geyser Basin area, Yellowstone National Park

USGS Publications Warehouse

Gardner, W.P.; Susong, D.D.; Solomon, D.K.; Heasler, H.P.

2011-01-01

Multiple environmental tracers are used to investigate age distribution, evolution, and mixing in local- to regional-scale groundwater circulation around the Norris Geyser Basin area in Yellowstone National Park. Springs ranging in temperature from 3??C to 90??C in the Norris Geyser Basin area were sampled for stable isotopes of hydrogen and oxygen, major and minor element chemistry, dissolved chlorofluorocarbons, and tritium. Groundwater near Norris Geyser Basin is comprised of two distinct systems: a shallow, cool water system and a deep, high-temperature hydrothermal system. These two end-member systems mix to create springs with intermediate temperature and composition. Using multiple tracers from a large number of springs, it is possible constrain the distribution of possible flow paths and refine conceptual models of groundwater circulation in and around a large, complex hydrothermal system. Copyright 2011 by the American Geophysical Union.

Arsenic release and geochemical evolution of groundwater in an alluvial aquitard, West Bengal, India.

NASA Astrophysics Data System (ADS)

Desbarats, A. J.; Pal, T.; Mukherjee, P. K.; Beckie, R. D.

2017-12-01

According to the World Health Organization, contamination of groundwater by geogenic arsenic (As) represents the largest mass poisoning in history. At a field site in West Bengal, India, the source of As affecting a shallow aquifer was traced to silty sediments filling an abandoned river meander. Along with As-bearing phases, these sediments also contain 0.46 % organic carbon. The release of As within the channel fill is investigated using a geochemical mass balance model supported by detailed field observations of aqueous chemistry, sequential extraction analyses of sediment chemistry, and analyses of sediment mineralogy. The model explores the evolution of groundwater chemistry along a flow path extending from its recharge point in an abandoned channel pond, through the channel-fill sequence, to the underlying aquifer. Variations in groundwater composition within the host sediments are explained in terms of mineral weathering driven by organic carbon decay. The model yields reaction coefficients expressing amounts of minerals (and gases) reacting or precipitating along the flow path. Arsenic and phosphorus cycles appear closely linked as these species are hosted by goethite, Fe-rich chlorite, and vivianite. Arsenic is released through the rapid reductive dissolution of goethite and the slower weathering of chlorite. Concomitantly, some As is sequestered in precipitating vivianite. These competing processes reach equilibrium deeper in the channel-fill sequence as groundwater As concentrations stabilize. Using groundwater residence time in channel fill obtained from a numerical flow model and the calculated reaction coefficients, rates of organic carbon oxidation, goethite dissolution, and net As release are estimated at 1.15 mmol C L-1 a-1, 0.18 mmol L-1 a-1, and 4.57 10-4 mmol L-1 a-1, respectively. Fine-grained yet slightly permeable deposits such as channel-fill silts containing reactive organic carbon and As-bearing goethite and phyllosilicates are localized centers of intense chemical weathering conducive to As mobilization.

Water-Rock Interactions in the Peridotite Aquifer of the Oman-UAE Ophiolite: Strontium Isotopic Ratio and Geochemical Evolution of Groundwater

NASA Astrophysics Data System (ADS)

Bompard, Nicolas; Matter, Juerg; Teagle, Damon

2016-04-01

The peridotite aquifer in Wadi Tayin, Sultanate of Oman, is a perfect example of natural carbonation of ultramafic rocks. In situ mineral carbonation is considered the most safest and permanent option of CO2 Capture and Sequestration (CCS). However, the process itself is yet to be characterised and a better understanding of the mechanisms involved in natural mineral carbonation is needed before geo-engineering it. We used the 87Sr/86Sr system to follow the water-rock interactions along the groundwater flowpath in the peridotite aquifer and to determine the sources of divalent cations (Mg2+, Ca2+) required for mineral carbonation. The Sr-isotope data of groundwater show that the aquifer rocks are the main source for divalent cations (Mg2+, Ca2+ and Sr2+) and secondary carbonates are their main sink. The groundwater 87Sr/86Sr ratio evolves with its pH: from 87Sr/86Sr = 0.7087 (n=3) to 0.7082 (n=8) between pH 7 and 8, and from 0.7086 (n=6) at pH 9 to 0.07075 (n=9) at pH 11. This evolution seems to support a two-step model for the water-rock interactions in the peridotite aquifer. From pH 7 to 8, secondary Ca-carbonate precipitation buffers the pH rise resulting from peridotite serpentinisation. From pH 9 to 11, peridotite serpentinisation drives the pH to alkaline condition. The change from a Mg-rich to a Ca-rich groundwater at pH 9 seems to confirm the two-step model.

The chemical evolution of Kurnub Group palcowater in the Sinai-Negev province - A mass balance approach

USGS Publications Warehouse

Rosenthal, E.; Jones, B.F.; Weinberger, G.

1998-01-01

The chemical evolution of the Kurnub Group paleowater was studied starting from rainwater in recharge areas of the Sinai and along groundwater flowpaths leading to the natural outlets of this regional aquifer. This was achieved by investigating the chemical composition of groundwater, ionic ratios, degrees of saturation with common mineral species, normative analysis of dissolved salts and by modeling of rock/water interaction and mixing processes occurring along groundwater flow paths. The initial groundwater composition used is from the Nakhel well in Sinai. It evolves from desert rainwater percolating through typical Kurnub Group lithology in Sinai. This rainwater dissolves mainly gypsum, halite and dolomite together with smaller amounts of marine aerosol and K-feldspar. At the same time it precipitates calcite, SiO2, smectite and degasses CO2. Between the area of Nakhel and the northern Negev the chemistry of Kurnub Group waters is influenced by dissolution of halite and lesser amounts of gypsum of surficial origin in recharge areas, small amounts of feldspars and of dolomite cement in sandstones eroded from the Arabo-Nubian igneous massif of Sinai and organic degradation-derived CO2. Concomitantly, there is precipitation of calcite, smectite, SiO2 and probably analcime characteristic of sediments in continental closed basins. North of the Negev, the Kurnub Group fluids are diluted and altered by mixing with Judea Group aquifer groundwaters. On the E there is mixing with residual brines from the water body ancestral to the Dead Sea, prior to discharge into the Arava valley. Rock/water interaction indicated by NETPATH and PHREEQC modeling is in agreement with lithology and facies changes previously observed in the Kurnub Group sequence.

Impact of climate changes during the last 5 million years on groundwater in basement aquifers.

PubMed

Aquilina, Luc; Vergnaud-Ayraud, Virginie; Les Landes, Antoine Armandine; Pauwels, Hélène; Davy, Philippe; Pételet-Giraud, Emmanuelle; Labasque, Thierry; Roques, Clément; Chatton, Eliot; Bour, Olivier; Ben Maamar, Sarah; Dufresne, Alexis; Khaska, Mahmoud; Le Gal La Salle, Corinne; Barbecot, Florent

2015-09-22

Climate change is thought to have major effects on groundwater resources. There is however a limited knowledge of the impacts of past climate changes such as warm or glacial periods on groundwater although marine or glacial fluids may have circulated in basements during these periods. Geochemical investigations of groundwater at shallow depth (80-400 m) in the Armorican basement (western France) revealed three major phases of evolution: (1) Mio-Pliocene transgressions led to marine water introduction in the whole rock porosity through density and then diffusion processes, (2) intensive and rapid recharge after the glacial maximum down to several hundred meters depths, (3) a present-day regime of groundwater circulation limited to shallow depth. This work identifies important constraints regarding the mechanisms responsible for both marine and glacial fluid migrations and their preservation within a basement. It defines the first clear time scales of these processes and thus provides a unique case for understanding the effects of climate changes on hydrogeology in basements. It reveals that glacial water is supplied in significant amounts to deep aquifers even in permafrosted zones. It also emphasizes the vulnerability of modern groundwater hydrosystems to climate change as groundwater active aquifers is restricted to shallow depths.

Using radon-222 to study coastal groundwater/surface-water interaction in the Crau coastal aquifer (southeastern France)

NASA Astrophysics Data System (ADS)

Mayer, Adriano; Nguyen, Bach Thao; Banton, Olivier

2016-11-01

Radon has been used to determine groundwater velocity and groundwater discharge into wetlands at the southern downstream boundary of the Crau aquifer, southeastern France. This aquifer constitutes an important high-quality freshwater resource exploited for agriculture, industry and human consumption. An increase in salinity occurs close to the sea, highlighting the need to investigate the water balance and groundwater behavior. Darcy velocity was estimated using radon activities in well waters according to the Hamada "single-well method" (involving comparison with radon in groundwater in the aquifer itself). Measurements done at three depths (7, 15 and 21 m) provided velocity ranging from a few mm/day to more than 20 cm/day, with highest velocities observed at the 15-m depth. Resulting hydraulic conductivities agree with the known geology. Waters showing high radon activity and high salinity were found near the presumed shoreline at 3,000 years BP, highlighting the presence of ancient saltwater. Radon activity has also been measured in canals, rivers and ponds, to trace groundwater discharges and evaluate water balance. A model of the radon spatial evolution explains the observed radon activities. Groundwater discharge to surface water is low in pond waters (4 % of total inputs) but significant in canals (55 l/m2/day).

Groundwater Flow Processes and Human Impact along the Arid US-Mexican Border, Evidenced by Environmental Tracers: The Case of Tecate, Baja California.

PubMed

Mahlknecht, Jürgen; Daessle, Luis Walter; Esteller, Maria Vicenta; Torres-Martinez, Juan Antonio; Mora, Abrahan

2018-04-30

With the increasing population, urbanization and industry in the arid area of Tecate, there is a concomitant increase in contaminants being introduced into the Tecate River and its aquifer. This contamination is damaging the usable groundwater supply and making local residents and commercial enterprises increasingly dependent on imported water from the Colorado River basin. In this study we apply a suite of chemical and isotopic tracers in order to evaluate groundwater flow and assess contamination trends. Groundwater recharge occurs through mountain-block and mountain-front recharge at higher elevations of the ranges. Groundwater from the unconfined, alluvial aquifer indicates recent recharge and little evolution. The increase in salinity along the flow path is due to interaction with weathering rock-forming silicate minerals and anthropogenic sources such as urban wastewater, residual solids and agricultural runoff from fertilizers, livestock manure and/or septic tanks and latrines. A spatial analysis shows local differences and the impact of the infiltration of imported waters from the Colorado River basin. The general trend of impaired water quality has scarcely been documented in the last decades, but it is expected to continue. Since the groundwater system is highly vulnerable, it is necessary to protect groundwater sources.

Impacts of preferential flow on coastal groundwater-surface water interactions: The heterogeneous volcanic aquifer of Hawaii

NASA Astrophysics Data System (ADS)

Geng, X.; Kreyns, P.; Koneshloo, M.; Michael, H. A.

2017-12-01

Groundwater flow and salt transport processes are important for protection of coastal water resources and ecosystems. Geological heterogeneity has been recognized as a key factor affecting rates and patterns of groundwater flow and the evolution of subsurface salinity distributions in coastal aquifers. The hydrogeologic system of the volcanic Hawaiian Islands is characterized by lava flows that can form continuous, connected geologic structures in subsurface. Understanding the role of geological heterogeneity in aquifer salinization and water exchange between aquifers and the ocean is essential for effective assessment and management of water resources in the Hawaii islands. In this study, surface-based geostatistical techniques were adopted to generate geologically-realistic, statistically equivalent model realizations of the hydrogeologic system on the Big Island of Hawaii. The density-dependent groundwater flow and solute transport code SEAWAT was used to perform 3D simulations to investigate subsurface flow and salt transport through these random realizations. Flux across the aquifer-ocean interface, aquifer salinization, and groundwater flow pathways and associated transit times were quantified. Numerical simulations of groundwater pumping at various positions in the aquifers were also conducted, and associated impacts on saltwater intrusion rates were evaluated. Results indicate the impacts of continuous geologic features on large-scale groundwater processes in coastal aquifers.

Groundwater Flow Processes and Human Impact along the Arid US-Mexican Border, Evidenced by Environmental Tracers: The Case of Tecate, Baja California

PubMed Central

Daessle, Luis Walter; Esteller, Maria Vicenta; Torres-Martinez, Juan Antonio; Mora, Abrahan

2018-01-01

With the increasing population, urbanization and industry in the arid area of Tecate, there is a concomitant increase in contaminants being introduced into the Tecate River and its aquifer. This contamination is damaging the usable groundwater supply and making local residents and commercial enterprises increasingly dependent on imported water from the Colorado River basin. In this study we apply a suite of chemical and isotopic tracers in order to evaluate groundwater flow and assess contamination trends. Groundwater recharge occurs through mountain-block and mountain-front recharge at higher elevations of the ranges. Groundwater from the unconfined, alluvial aquifer indicates recent recharge and little evolution. The increase in salinity along the flow path is due to interaction with weathering rock-forming silicate minerals and anthropogenic sources such as urban wastewater, residual solids and agricultural runoff from fertilizers, livestock manure and/or septic tanks and latrines. A spatial analysis shows local differences and the impact of the infiltration of imported waters from the Colorado River basin. The general trend of impaired water quality has scarcely been documented in the last decades, but it is expected to continue. Since the groundwater system is highly vulnerable, it is necessary to protect groundwater sources. PMID:29710847

TRIADS: A phase-resolving model for nonlinear shoaling of directional wave spectra

NASA Astrophysics Data System (ADS)

Sheremet, Alex; Davis, Justin R.; Tian, Miao; Hanson, Jeffrey L.; Hathaway, Kent K.

2016-03-01

We investigate the performance of TRIADS, a numerical implementation of a phase-resolving, nonlinear, spectral model describing directional wave evolution in intermediate and shallow water. TRIADS simulations of shoaling waves generated by Hurricane Bill, 2009 are compared to directional spectral estimates based on observations collected at the Field Research Facility of the US Army Corps Of Engineers, at Duck, NC. Both the ability of the model to capture the processes essential to the nonlinear wave evolution, and the efficiency of the numerical implementations are analyzed and discussed.

Distinct kinetics and mechanisms of mZVI particles aging in saline and fresh groundwater: H2 evolution and surface passivation.

PubMed

Xin, Jia; Tang, Fenglin; Zheng, Xilai; Shao, Haibing; Kolditz, Olaf; Lu, Xin

2016-09-01

Application of microscale zero-valent iron (mZVI) is a promising technology for in-situ contaminated groundwater remediation; however, its longevity is negatively impacted by surface passivation, especially in saline groundwater. In this study, the aging behavior of mZVI particles was investigated in three media (milli-Q water, fresh groundwater and saline groundwater) using batch experiments to evaluate their potential corrosion and passivation performance under different field conditions. The results indicated that mZVI was reactive for 0-7 days of exposure to water and then gradually lost H2-generating capacity over the next hundred days in all of the tested media. In comparison, mZVI in saline groundwater exhibited the fastest corrosion rate during the early phase (0-7 d), followed by the sharpest kinetic constant decline in the latter phases. The SEM-EDS and XPS analyses demonstrated that in the saline groundwater, a thin and compact oxide film was immediately formed on the surface and significantly shielded the iron reactive site. Nevertheless, in fresh groundwater and milli-Q water, a passive layer composed of loosely and unevenly distributed precipitates slowly formed, with abundant reactive sites available to support continuous iron corrosion. These findings provide insight into the molecular-scale mechanism that governs mZVI passivation and provide implications for long-term mZVI application in saline contaminated groundwater. Copyright © 2016 Elsevier Ltd. All rights reserved.

Identifying the regional-scale groundwater-surface water interaction on the Sanjiang Plain, Northeast China.

PubMed

Wang, Xihua; Zhang, Guangxin; Xu, Y Jun; Sun, Guangzhi

2015-11-01

Assessment on the interaction between groundwater and surface water (GW-SW) can generate information that is critical to regional water resource management, especially for regions that are highly dependent on groundwater resources for irrigation. This study investigated such interaction on China's Sanjiang Plain (10.9 × 10(4) km(2)) and produced results to assist sustainable regional water management for intensive agricultural activities. Methods of hierarchical cluster analysis (HCA), principal component analysis (PCA), and statistical analysis were used in this study. One hundred two water samplings (60 from shallow groundwater, 7 from deep groundwater, and 35 from surface water) were collected and grouped into three clusters and seven sub-clusters during the analyses. The PCA analysis identified four principal components of the interaction, which explained 85.9% variance of total database, attributed to the dissolution and evolution of gypsum, feldspar, and other natural minerals in the region that was affected by anthropic and geological (sedimentary rock mineral) activities. The analyses showed that surface water in the upper region of the Sanjiang Plain gained water from local shallow groundwater, indicating that the surface water in the upper region was relatively more resilient to withdrawal for usage, whereas in the middle region, there was only a weak interaction between shallow groundwater and surface water. In the lower region of the Sanjiang Plain, surface water lost water to shallow groundwater, indicating that the groundwater was vulnerable to pollution by pesticides and fertilizers from terrestrial sources.

Origin and Evolution of Li-rich Brines at Clayton Valley, Nevada, USA

NASA Astrophysics Data System (ADS)

Munk, L. A.; Bradley, D. C.; Hynek, S. A.; Chamberlain, C. P.

2011-12-01

Lithium is the key component in Li-ion batteries which are the primary energy storage for electric/hybrid cars and most electronics. Lithium is also an element of major importance on a global scale because of interest in increasing reliance on alternative energy sources. Lithium brines and pegmatites are the primary and secondary sources, respectively of all produced Li. The only Li-brine in the USA that is currently in production exists in Clayton Valley, NV. The groundwater brines at Clayton Valley are located in a closed basin with an average evaporation rate of 142 cm/yr. The brines are pumped from six aquifer units that are composed of varying amounts of volcanic ash, gravel, salt, tufa, and fine-grained sediments. Samples collected include spring water, fresh groundwater, groundwater brine, and meteoric water (snow). The brines are classified as Na-Cl waters and the springs and fresh groundwater have a mixed composition and are more dilute than the brines. The Li content of the waters in Clayton Valley ranges from less than 1 μg/L (snow) up to 406.9 mg/L in the lower ash aquifer system (one of six aquifers in the basin). The cold springs surrounding Clayton Valley have Li concentrations of about 1 mg/L. A hot spring located just east of Clayton Valley contains 1.6 mg/L Li. The Li concentration of the fresh groundwater is less than 1 mg/L. Hot groundwater collected in the basin contain 30-40 mg/L Li. Water collected from a geothermal drilling north of Silver Peak, NV, had water with 4.9 mg/L Li at a depth of >1000m. The δD and δ18O isotopic signatures of fresh groundwater and brine form an evaporation path that extends from the global meteoric water line toward the brine from the salt aquifer system (the most isotopically enriched brine with ave. δD = -3.5, ave. δ18O = -67.0). This suggests that mixing of inflow water with the salt aquifer brine could have played an important role in the evolution of the brines. Along with mixing, evaporation appears to be an important process in the brine evolution. This is evident because of the increase in Na concentration as a function of enrichment in δD for most brine samples. In contrast the non-brine waters flowing into the basin show an increase in Na at relatively constant δD indicating little evaporation. The δD of clays sampled throughout a sediment core extending to 354 m below the surface show fluctuations that likely indicate warmer and cooler periods through time. Further investigation of the relationship of past climate and Li accumulation is in progress.

Evolution of agricultural water use in India: a systems approach

NASA Astrophysics Data System (ADS)

Hora, T.; Basu, N. B.

2016-12-01

Groundwater plays an important role in improving the resilience of agriculture practices by mitigating the risk associated with unreliable and seasonal rainfalls. This has been an important driver in satisfying the food demand for an ever increasing population across the world. However, the inability to manage this large but limited freshwater reserve has resulted in a sharp decline in water table levels, with India being at the forefront of this problem. This study looks at the temporal trajectory of groundwater extraction in India over a 40 year time span during which well irrigation has evolved to become a central component of agriculture there. Using a systems approach, we identify the regional hot-spots of unsustainable groundwater extraction and then analyze its relationship with the environmental, economic and social components of the region. Early results indicate that the state of Punjab has been overexploiting its groundwater resources since the early 1980's with a 22% jump in groundwater extraction after the introduction of a free electricity policy, with a concomitant reduction in the number of marginal farmers by 36%. This is in contrast with the state of Tamil Nadu, in which groundwater extraction is less severe, but the number of marginal farmers has increased.

Characterizing the Sensitivity of Groundwater Storage to Climate variation in the Indus Basin

NASA Astrophysics Data System (ADS)

Huang, L.; Sabo, J. L.

2017-12-01

Indus Basin represents an extensive groundwater aquifer facing the challenge of effective management of limited water resources. Groundwater storage is one of the most important variables of water balance, yet its sensitivity to climate change has rarely been explored. To better estimate present and future groundwater storage and its sensitivity to climate change in the Indus Basin, we analyzed groundwater recharge/discharge and their historical evolution in this basin. Several methods are applied to specify the aquifer system including: water level change and storativity estimates, gravity estimates (GRACE), flow model (MODFLOW), water budget analysis and extrapolation. In addition, all of the socioeconomic and engineering aspects are represented in the hydrological system through the change of temporal and spatial distributions of recharge and discharge (e.g., land use, crop structure, water allocation, etc.). Our results demonstrate that the direct impacts of climate change will result in unevenly distributed but increasing groundwater storage in the short term through groundwater recharge. In contrast, long term groundwater storage will decrease as a result of combined indirect and direct impacts of climate change (e.g. recharge/discharge and human activities). The sensitivity of groundwater storage to climate variation is characterized by topography, aquifer specifics and land use. Furthermore, by comparing possible outcomes of different human interventions scenarios, our study reveals human activities play an important role in affecting the sensitivity of groundwater storage to climate variation. Over all, this study presents the feasibility and value of using integrated hydrological methods to support sustainable water resource management under climate change.

Geochemical evolution of groundwater in the Mud Lake area, eastern Idaho, USA

USGS Publications Warehouse

Rattray, Gordon W.

2015-01-01

Groundwater with elevated dissolved-solids concentrations—containing large concentrations of chloride, sodium, sulfate, and calcium—is present in the Mud Lake area of Eastern Idaho. The source of these solutes is unknown; however, an understanding of the geochemical sources and processes controlling their presence in groundwater in the Mud Lake area is needed to better understand the geochemical sources and processes controlling the water quality of groundwater at the Idaho National Laboratory. The geochemical sources and processes controlling the water quality of groundwater in the Mud Lake area were determined by investigating the geology, hydrology, land use, and groundwater geochemistry in the Mud Lake area, proposing sources for solutes, and testing the proposed sources through geochemical modeling with PHREEQC. Modeling indicated that sources of water to the eastern Snake River Plain aquifer were groundwater from the Beaverhead Mountains and the Camas Creek drainage basin; surface water from Medicine Lodge and Camas Creeks, Mud Lake, and irrigation water; and upward flow of geothermal water from beneath the aquifer. Mixing of groundwater with surface water or other groundwater occurred throughout the aquifer. Carbonate reactions, silicate weathering, and dissolution of evaporite minerals and fertilizer explain most of the changes in chemistry in the aquifer. Redox reactions, cation exchange, and evaporation were locally important. The source of large concentrations of chloride, sodium, sulfate, and calcium was evaporite deposits in the unsaturated zone associated with Pleistocene Lake Terreton. Large amounts of chloride, sodium, sulfate, and calcium are added to groundwater from irrigation water infiltrating through lake bed sediments containing evaporite deposits and the resultant dissolution of gypsum, halite, sylvite, and bischofite.

Sensitivity of Simulated Warm Rain Formation to Collision and Coalescence Efficiencies, Breakup, and Turbulence: Comparison of Two Bin-Resolved Numerical Models

NASA Technical Reports Server (NTRS)

Fridlind, Ann; Seifert, Axel; Ackerman, Andrew; Jensen, Eric

2004-01-01

Numerical models that resolve cloud particles into discrete mass size distributions on an Eulerian grid provide a uniquely powerful means of studying the closely coupled interaction of aerosols, cloud microphysics, and transport that determine cloud properties and evolution. However, such models require many experimentally derived paramaterizations in order to properly represent the complex interactions of droplets within turbulent flow. Many of these parameterizations remain poorly quantified, and the numerical methods of solving the equations for temporal evolution of the mass size distribution can also vary considerably in terms of efficiency and accuracy. In this work, we compare results from two size-resolved microphysics models that employ various widely-used parameterizations and numerical solution methods for several aspects of stochastic collection.

Against the current— The Mojave River from sink to source: The 2018 Desert Symposium field trip road log

USGS Publications Warehouse

Miller, David; Reynolds, R.E.; Groover, Krishangi D.; Buesch, David C.; Brown, H. J.; Cromwell, Geoffrey; Densmore-Judy, Jill; Garcia, A.L.; Hughson, D.; Knott, J.R.; Lovich, Jeffrey E.

2018-01-01

The Mojave River evolved over the past few million years by “fill and spill” from upper basins near its source in the Transverse Ranges to lower basins. Each newly “spilled into” basin in the series? sustained a long-lived lake but gradually filled with Mojave River sediment, leading to spill to a yet lower elevation? basin. The Mojave River currently terminates at Silver Lake, near Baker, CA, but previously overflowed this terminus onward to Lake Manly in Death Valley during the last glacial cycle. The river’s origin and evolution are intricately interwoven with tectonic, climatic, and geomorphic processes through time, beginning with San Andreas fault interactions that created a mountain range across a former externally draining river. We will see and discuss the Mojave River’s predecessor streams and basins, its evolution as it lengthened to reach the central Mojave Desert, local and regional tectonic controls, groundwater flow, flood history, and support of isolated perennial stream reaches that host endemic species. In association with these subjects are supporting studies such as paleoclimate records, location and timing for groundwater and wetlands in the central Mojave Desert, and effects of modern water usage. The trip introduces new findings for the groundwater basin of Hinkley Valley, including an ongoing remediation project that provides a wealth of information on past and present river flow and associated development of the groundwater system.

Geochemical evolution of groundwater in the Western Delta region of River Godavari, Andhra Pradesh, India

NASA Astrophysics Data System (ADS)

Nageswara Rao, P. V.; Appa Rao, S.; Subba Rao, N.

2017-05-01

The present study on geochemical evolution of groundwater is taken up to assess the controlling processes of water chemistry in the Western Delta region of the River Godavari (Andhra Pradesh), which is one of the major rice-producing centers in India. The study region is underlain by coarse sand with black clay (buried channels), black silty clay of recent origin (floodplain) and gray/white fine sand of modern beach sediment of marine source (coastal zone), including brown silty clay with fine sand (paleo-beach ridges). Groundwater is mostly brackish and very hard. It is characterized by Na+ > Mg2+ > Ca2+:HCO3 - > Cl- > SO4 2- > NO3 -, Na+ > Mg2+ > Ca2+:Cl- > HCO3 - > SO4 2-, and Mg2+ > Na+ > Ca2+ > or < K+:HCO3 - > Cl- > or > SO4 2- facies. The ionic relations (Ca2+ + Mg2+:HCO3 -, Ca2+ + Mg2+:SO4 2- + HCO3 -, Na+ + K+:TC, Na+ + K+:Cl- + SO4 2-, HCO3 -:TC, HCO3 -:Ca2+ + Mg2+, Na+:Cl- and Na+:Ca2+) indicate that the rock weathering, mineral dissolution, evaporation and ion exchange are the processes to control the aquifer chemistry. Anthropogenic and marine sources are also the supplementary factors for brackish water quality. These observations are further supported by Gibbs mechanisms that control the water chemistry. Thus, the study suggests that the initial quality of groundwater of geogenic origin has been subsequently modified by the influences of anthropogenic and marine sources.

Groundwater geochemistry of a Mio-Pliocene aquifer in the northeastern Algerian Sahara (Djamaa region)

NASA Astrophysics Data System (ADS)

Houari, Idir Menad; Nezli, Imed Eddine; Belksier, Mohamed Salah

2018-05-01

The groundwater resources in the Northern Sahara are represented by two superimposed major aquifer systems: the Intercalary Continental (CI) and the Terminal Complex (CT). The waters of these aquifers pose serious physical and chemical quality problems; they are highly mineralized and very hard. The present work aims to describe the water's geochemical evolution of sand groundwater (Mio-Pliocene) of the Terminal Complex in the area of Djamaa, by the research of the relationship between water's chemical composition and lithology of aquifer formations through. The results obtained show that the water's chemistry is essentially governed by the dissolution of evaporate formations, which gives to, waters an excessive mineralization expressed by high concentrations of sulfates, chlorides and sodium.

How to spy on your neighbor's water consumption from space

NASA Astrophysics Data System (ADS)

Neely, W.; Borsa, A. A.; Burney, J. A.

2017-12-01

Dependence on groundwater has increased in the agricultural production regions of California's Central Valley due to recent and persistent droughts. To protect the long-term reliability of groundwater resources in California, the state passed the Sustainable Groundwater Management Act (SGMA) in September 2014. In situ observation of subsurface reservoir levels is ideal for monitoring aquifer health at a water district scale, but is limited by the low density of monitoring wells and temporal gaps between measurements. An alternative to well measurements relies on the fact that groundwater extraction may lead to surface subsidence due to the compaction of the aquifer at depth. Such surface displacements can be resolved using geodetic techniques. We present an integrative approach using Interferometric Synthetic Aperture Radar (InSAR) and continuous Global Positioning System (cGPS) station observations to characterize surface deformation related to extensive pumping at a farm-level resolution every 12-24 days. We demonstrate our technique in the southern Central Valley where we observe subsidence upwards of 25 cm/yr from late 2014 to early 2017. Our methods offer an inexpensive supplement to in situ measurements that allows for the detection and deterrence of water mismanagement.

A primary study on finding hot groundwater using infrared remote sensing

NASA Astrophysics Data System (ADS)

Qiao, Y.; Wu, Q.

Hot groundwater is a kind of valuable natural resources to be explored utilized. Shanxi Province, located in the eastern Loess Plateau of China, is rich in geothermal resources, most of which was found in irrigation well drilling or geological survey. Basic study is weak. Now new developed Remote Sensing technique provides geothermal study with an advanced way. Air-RS information of thermal infrared and dada from thermal channel of Meteorological Landset AVHRR has been used widely. A thermal infrared channel (TM6) was installed in the U. S. second Landset, Its resolving power of space is as high as 120 m, 10 times more t an one ofh AVHRR. A Landset earth recourses launched by China and Brazil (CBERS-1) in 1999, including a spectrum of thermal infrared. It is paid a great interested and attention to survey geothermal resources using thermal infrared. This article is a brief introduction of finding hot groundwater with on the bases of differences of thermal radiation of objects reflected by thermal infrared in the Landset, and treated with HIS colors changes. This study provides an advanced way widely used to exploit hot groundwater and to promote the development of tourism and geothermal medical in China.

Evolution at the tips: Asclepias phylogenomics and new perspectives on leaf surfaces.

PubMed

Fishbein, Mark; Straub, Shannon C K; Boutte, Julien; Hansen, Kimberly; Cronn, Richard C; Liston, Aaron

2018-03-01

Leaf surface traits, such as trichome density and wax production, mediate important ecological processes such as anti-herbivory defense and water-use efficiency. We present a phylogenetic analysis of Asclepias plastomes as a framework for analyzing the evolution of trichome density and presence of epicuticular waxes. We produced a maximum-likelihood phylogeny using plastomes of 103 species of Asclepias. We reconstructed ancestral states and used model comparisons in a likelihood framework to analyze character evolution across Asclepias. We resolved the backbone of Asclepias, placing the Sonoran Desert clade and Incarnatae clade as successive sisters to the remaining species. We present novel findings about leaf surface evolution of Asclepias-the ancestor is reconstructed as waxless and sparsely hairy, a macroevolutionary optimal trichome density is supported, and the rate of evolution of trichome density has accelerated. Increased sampling and selection of best-fitting models of evolution provide more resolved and robust estimates of phylogeny and character evolution than obtained in previous studies. Evolutionary inferences are more sensitive to character coding than model selection. © 2018 The Authors. American Journal of Botany is published by Wiley Periodicals, Inc. on behalf of the Botanical Society of America.

Sources and Residence Times of Groundwater in Shasta County, CA Determined by Isotopic Tracers

NASA Astrophysics Data System (ADS)

Peters, E.; Moran, J. E.; Deinhart, A.; Roberts, S. K.; Esser, B.; Visser, A.

2015-12-01

Large-volume springs are a significant source of water to communities in Shasta County. Aquifers in this region are developed in young volcanic formations and the age and flow of groundwater is not well characterized, making predicting the impact of drought and climate change on spring flow difficult. To better understand the water resources and the hydrogeology of the region and to better constrain the age of water produced by springs, we have sampled water from wells, springs, and streams for a suite of geochemical and isotopic tracers. We are using isotopic tracers because of the limited number of sampling points over a large area, leaving traditional hydrogeologic methods such as water levels and pump tests inadequate for a regional study. We analyzed samples for sulfur-35 (87.4 day half-life) and found detections in two springs, confirming the presence of a fraction of recently (1-2 years) recharged groundwater. Tritium (12.3 year half-life) activities show that some wells produce water recharged more than 5 decades ago, but most produce more recently recharged water. We will also report results for sodium-22 (2.6 year half-life), krypton-85 (10.8 year half-life), carbon-14 (5,730 year half-life), dissolved noble gases, stable isotopes of water, and helium isotopic composition. These isotopes are applied to determine the age (residence time) of groundwater over a broad age distribution, from less than one year to tens of thousands of years. These tracers should also provide information on aquifer volumes, help delineate groundwater flow, and help to identify recharge areas. A collection of groundwater ages from springs at high elevations to wells in the upper Sacramento Valley will help delineate groundwater flowpaths. Finally, groundwater residence times will help determine groundwater volume and recharge rates, and resolve questions related to drought vulnerability and effective adjustments in water resource management.

Irrational exuberance for resolved species trees.

PubMed

Hahn, Matthew W; Nakhleh, Luay

2016-01-01

Phylogenomics has largely succeeded in its aim of accurately inferring species trees, even when there are high levels of discordance among individual gene trees. These resolved species trees can be used to ask many questions about trait evolution, including the direction of change and number of times traits have evolved. However, the mapping of traits onto trees generally uses only a single representation of the species tree, ignoring variation in the gene trees used to construct it. Recognizing that genes underlie traits, these results imply that many traits follow topologies that are discordant with the species topology. As a consequence, standard methods for character mapping will incorrectly infer the number of times a trait has evolved. This phenomenon, dubbed "hemiplasy," poses many problems in analyses of character evolution. Here we outline these problems, explaining where and when they are likely to occur. We offer several ways in which the possible presence of hemiplasy can be diagnosed, and discuss multiple approaches to dealing with the problems presented by underlying gene tree discordance when carrying out character mapping. Finally, we discuss the implications of hemiplasy for general phylogenetic inference, including the possible drawbacks of the widespread push for "resolved" species trees. © 2015 The Author(s). Evolution © 2015 The Society for the Study of Evolution.

Quantification of the Dedolomitization Rate for Correction of Groundwater 14C Ages in Aquifers of the Sacramento Mountains, New Mexico

NASA Astrophysics Data System (ADS)

Morse, J. T.; Phillips, F. M.; Land, L. A.

2009-12-01

Ion chemistry of groundwater from the western part of the Roswell Basin, New Mexico, are consistent with groundwater quality evolution driven by dedolomitization. Measured, uncorrected, 14C values in groundwater yield an apparent residence time of 4700 years for the western part of the Roswell Basin. We have employed a simple model incorporating the changes in bicarbonate, magnesium and 14C along the flow-path to quantify the in-situ rate of dedolomitization and thereby to correct the 14C values for inorganic carbon dilution. The model yielded a corrected residence time of 1300 years at the distal end of the flowpath and a regional hydraulic conductivity of 5×10-4cm/s. Prior studies have inferred that underflow from the Sacramento Mountains constitutes an important component of recharge to the Artesian Aquifer of the Roswell Basin but it has not been possible to quantify this contribution. The information from the corrected 14C dating will allow an improved assessment of the groundwater resources available in this overstressed basin.

Argon concentration time-series as a tool to study gas dynamics in the hyporheic zone.

PubMed

Mächler, Lars; Brennwald, Matthias S; Kipfer, Rolf

2013-07-02

The oxygen dynamics in the hyporheic zone of a peri-alpine river (Thur, Switzerland), were studied through recording and analyzing the concentration time-series of dissolved argon, oxygen, carbon dioxide, and temperature during low flow conditions, for a period of one week. The argon concentration time-series was used to investigate the physical gas dynamics in the hyporheic zone. Differences in the transport behavior of heat and gas were determined by comparing the diel temperature evolution of groundwater to the measured concentration of dissolved argon. These differences were most likely caused by vertical heat transport which influenced the local groundwater temperature. The argon concentration time-series were also used to estimate travel times by cross correlating argon concentrations in the groundwater with argon concentrations in the river. The information gained from quantifying the physical gas transport was used to estimate the oxygen turnover in groundwater after water recharge. The resulting oxygen turnover showed strong diel variations, which correlated with the water temperature during groundwater recharge. Hence, the variation in the consumption rate was most likely caused by the temperature dependence of microbial activity.

Depth evolution of the Meirama pit lake, A Coruña, NW Spain

NASA Astrophysics Data System (ADS)

Delgado, Jordi; Juncosa-Rivera, Ricardo; Cereijo-Arango, José Luis; García-Morrondo, David; Muñoz-Ibáñez, Andrea; Grande-García, Elisa; Rodríguez-Cedrún, Borja

2016-04-01

The Meirama pit lake is a water mass in the process of controlled flooding that, by the end of December 2015, can be described as a steadily stratified meromictic system. The deepest portion of the lake (monimolimnion) is isolated regarding the annual mixing dynamics (December/January) of the upper water body (mixolimnion), for which the depth of mixing is restricted to a water column of 35-40 m thick. Due to the contrasting flooding history (access of groundwater at the beginning and mixed access of stream/groundwater (being dominant the stream water) the deepest portion of the lake is separated from the upper, non-mixed layer by a marked chemocline. Strictly speaking, the monimolimnion of a meromictic lake extends to the waters located beneath the mixed lake layer. In the case of the Meirama Lake the monimolimnion is internally stratified and made of two major water bodies. From hereafter the deep and upper monimolimnion will be identified as bottom and middle sections of the lake while the mixolimnion is referred to as the surface layer. The general characteristics and evolution of the Meirama Lake have been reported elsewhere. In this work we focus on a summary description of the chemical evolution of the monimolimnion of the lake based on data gathered between 2009 and 2015 from the still on-going monitoring survey. The chemical evolution of the monimolimnion of the lake differs significantly from that of the mixolimnion. In general, surface water is sensible to seasonal fluctuations due to weather conditions, rainfall and biogeochemical processes. The middle and bottom sections are not sensible, in general, to this effects and their evolution obeys to a number of internal processes. In the case of temperature we observe a nearly constant gradient increase (0.001 °C/day) in the middle and deep lake waters up to the beginning of 2012, where it remains constant. The rise in temperature is likely due to the heat provided by groundwater seepage whose temperature is above that of the lake water at the corresponding depth. Likewise, electrical conductance shows a similar constant-rate increasing rate (0.223 and 0.115 S/cm-day in the bottom and middle sections, respectively) whose origin we also associate with groundwater seepage. Based on a wide number of parameters (O2, Cl, SO4, NO3, NO2, NH4, Fe, Mn…) we observe that the monimolimnion of the lake, either in its bottom or middle layer is a rather dynamic (transient) geochemical system.

Investigation of temporal-resolved emission spectra of highly charged Al ions from laser-produced plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Su, M. G., E-mail: sumg@nwnu.edu.cn; Sun, D. X.; Dong, C. Z.

2016-03-15

Temporal evolution of extreme ultraviolet emission from laser-produced aluminum (Al) plasma has been experimentally and theoretically investigated. Al plasmas have been measured by using the temporal-spatially resolved laser-produced plasma technique. The emission lines can be identified from 2p-3s, 3d, 4s, 4d, 5d transition lines from Al{sup 3+} to Al{sup 6+} ions. In order to quickly diagnose the plasma, the assumptions of a normalized Boltzmann distribution among the excited states and a steady-state collisional-radiative model are used to estimate the values of electron temperature and electron density in plasma. We succeeded in reproducing the simulated spectra related to the different timemore » delays, which are in good agreement with experiments. Temporal evolution behavior of highly charged Al ions in plasma has been analyzed, and the exponential decay about electron temperature and electron density has been obtained. The results indicate that the temporal-spatially resolved measurement is essential for accurate understanding of evolution behavior of highly charged ions in laser-produced plasmas.« less

Rescuing degrading aquifers in the Central Coastal Plain of North Carolina (USA): Just process, effective groundwater management policy, and sustainable aquifers

NASA Astrophysics Data System (ADS)

Manda, Alex K.; Klein, Wendy A.

2014-07-01

Strategic management of degrading coastal aquifers in eastern North Carolina (USA) became imperative after a severe imbalance occurred between withdrawal and recharge rates. To ameliorate this growing problem, an aggressive water policy was developed through public input by creating the Central Coastal Plain Capacity Use Area (CCPCUA) to maintain beneficial use of groundwater resources. Insights from social psychology, and socio-legal studies are used to evaluate how procedural justice and public participation played major roles to resolving groundwater resource management problems. A mixed methods approach uses archival data and interviews with various rule-making participants to assess the process of stakeholder involvement that led to creation of the policy. In addition, data analysis techniques are utilized to evaluate the effects of the policy on aquifer health (through water levels) over a ˜10 year period. Results suggest that not only did a stakeholder group participate in a process that was deemed fair, understandable, and relatively easy to administer for users and regulators, but public participation resulted in an effective plan that ensures the long-term sustainable use of groundwater. Declining groundwater withdrawals and recovering water levels suggest that the rule is achieving its intended goal of protecting the aquifers from depletion and degradation. This paper touches on global themes that are essential to water demand and consumption, water management techniques, and water resources protection.

Novel S-35 Intrinsic Tracer Method for Determining Groundwater Travel Time near Managed Aquifer Recharge Facilities

NASA Astrophysics Data System (ADS)

Urióstegui, S. H.; Bibby, R. K.; Esser, B. K.; Clark, J. F.

2013-12-01

Identifying groundwater travel times near managed aquifer recharge (MAR) facilities is a high priority for protecting public and environmental health. For MAR facilities in California that incorporate tertiary wastewater into their surface-spreading recharge practices, the target subsurface residence time is >9 months to allow for the natural inactivation and degradation of potential contaminants (less time is needed for full advanced treated water). Established intrinsic groundwater tracer techniques such as tritium/helium-3 dating are unable to resolve timescales of <1 year. These limitations provide the motivation for evaluating a novel groundwater tracer method using a naturally occurring radioisotope of sulfur, sulfur-35 (S-35). After its production in the atmosphere by cosmic ray interaction with argon, S-35 enters the hydrologic cycle as dissolved sulfate through precipitation The short half-life of S-35 (3 months) is ideal for investigating recharge and transport of MAR groundwater on the <1 year timescale of interest to MAR managers. The method, however, has not been applied to MAR operations because of the difficulty in measuring S-35 with sufficient sensitivity in high-sulfate waters. We have developed a new method and have applied it at two southern California MAR facilities where groundwater travel times have previously been characterized using deliberate tracers: 1) Rio Hondo Spreading Grounds in Los Angeles County, and 2) Orange County Groundwater Recharge Facilities in Orange County. Reasonable S-35 travel times of <1 year were identified at both study sites. This method also identified seasonal patterns in subsurface travel times, which may not be revealed by a deliberate tracer study that is dependent on the hydrologic conditions during the tracer injection period.

An Excel Macro to Plot the HFE-Diagram to Identify Sea Water Intrusion Phases.

PubMed

Giménez-Forcada, Elena; Sánchez San Román, F Javier

2015-01-01

A hydrochemical facies evolution diagram (HFE-D) is a multirectangular diagram, which is a useful tool in the interpretation of sea water intrusion processes. This method note describes a simple method for generating an HFE-D plot using the spreadsheet software package, Microsoft Excel. The code was applied to groundwater from the alluvial coastal plain of Grosseto (Tuscany, Italy), which is characterized by a complex salinization process in which sea water mixes with sulfate or bicarbonate recharge water. © 2014, National GroundWater Association.

Variability of pesticides and nitrates concentrations along a river transect: chemical and isotopic evidence of groundwater - surface water interconnections

NASA Astrophysics Data System (ADS)

Baran, Nicole; Petelet-Giraud, Emmanuelle; Saplairoles, Maritxu

2015-04-01

Groundwater quality is increasingly monitored in Europe where various levels of nitrate and pesticide and/or metabolite contamination have been demonstrated (Loos et al., 2010, Stuart et al., 2012). The Groundwater Daughter Directive (2006/118/EC) to Water Framework Directive (WFD) particularly requires measures to prevent or limit inputs of pollutants into groundwater and compliance with good chemical status criteria (based on EU standards of nitrate and pesticides). The WFD mentioned the need to protect groundwater but also to have a particular regard to its impact and interrelationship with associated surface waters and directly dependent terrestrial Ecosystems. The Ariège river basin (SW France - 538 km²) is an alluvial plain under high agricultural pressure leading to a contamination of the aquifer by several pesticides and metabolites (Amalric et al., 2013). The Crieu is an allochtone river, crossing the plain (~ 10 km length) before joining the Ariège River. The Crieu is often dry in its middle section suggesting water leakage from surface water towards groundwater. At the opposite, the permanent flow observed downstream suggests an input of groundwater into surface water. In May 2014, while the Crieu flow was continuous through the plain, 7 river samples were collected and analyzed for pesticides, major ions, strontium concentration and isotopes. In situ measurements of electric conductivity were also performed as well as flow gauging. Two groundwaters close to the river were also sampled. The flow gauging measurements show a decreasing river discharge in the central area of the Crieu River, suggesting surface water leakage towards groundwater. Nevertheless, the electric conductivity increases along the river flow as well as some pesticides and nitrates concentrations. This chemical evolution of the river water is thus inconsistent with a simple water infiltration and another source of dissolved solutes is required to explain the increased of concentration. Finally, downstream the quantified pesticides were different from those observed in the upper part of the Crieu but similar to those observed in groundwater. Sr isotopes together with major elements and Sr concentrations allow to identify 3 distinct end-members to explain the river quality evolution : 1) surface water, 2) groundwater and 3) sub-surface water. On this basis, we first demonstrate that the contribution of the different end-members to the river flow is highly variable from upstream to downstream. Secondly, we evidence water exchanges between the river and the groundwater compartment and vice-versa. The combination of the isotopic and geochemical approaches was essential to understand the complex relations and exchanges between surface and ground-waters occurring in few kilometers along the Crieu River. This understanding allows the comprehension of spatial variability of surface water quality. This is of primary importance when to help water managers to select relevant sampling points to be monitored in the framework of the WFD. Amalric L., et al. (2013). International Journal of Environmental Analytical Chemistry, 93: 1660-1675 Loos R. et al. (2010). Water Research, 44: 4115-4126 Stuart M. et al. (2012). Science of the Total Environment, 416: 1-21.

Mitochondrial gene rearrangements confirm the parallel evolution of the crab-like form.

PubMed Central

Morrison, C L; Harvey, A W; Lavery, S; Tieu, K; Huang, Y; Cunningham, C W

2002-01-01

The repeated appearance of strikingly similar crab-like forms in independent decapod crustacean lineages represents a remarkable case of parallel evolution. Uncertainty surrounding the phylogenetic relationships among crab-like lineages has hampered evolutionary studies. As is often the case, aligned DNA sequences by themselves were unable to fully resolve these relationships. Four nested mitochondrial gene rearrangements--including one of the few reported movements of an arthropod protein-coding gene--are congruent with the DNA phylogeny and help to resolve a crucial node. A phylogenetic analysis of DNA sequences, and gene rearrangements, supported five independent origins of the crab-like form, and suggests that the evolution of the crab-like form may be irreversible. This result supports the utility of mitochondrial gene rearrangements in phylogenetic reconstruction. PMID:11886621

Groundwater quality from a part of Prakasam District, Andhra Pradesh, India

NASA Astrophysics Data System (ADS)

Subba Rao, N.

2018-03-01

Quality of groundwater is assessed from a part of Prakasam district, Andhra Pradesh, India. Groundwater samples collected from thirty locations from the study area were analysed for pH, electrical conductivity (EC), total dissolved solids (TDS), calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), bicarbonate ( {HCO}3^{ - } ), chloride (Cl-), sulphate ( {SO}4^{2 - } ), nitrate ( {NO}3^{ - } ) and fluoride (F-). The results of the chemical analysis indicate that the groundwater is alkaline in nature and are mainly characterized by Na+- {HCO}3^{ - } and Na+-Cl- facies. Groundwater chemistry reflects the dominance of rock weathering and is subsequently modified by human activities, which are supported by genetic geochemical evolution and hydrogeochemical relations. Further, the chemical parameters (pH, TDS, Ca2+, Mg2+, Na+, {HCO}3^{ - } , Cl-, {SO}4^{2 - } , {NO}3^{ - } and F-) were compared with the drinking water quality standards. The sodium adsorption ratio, percent sodium, permeability index, residual sodium carbonate, magnesium ratio and Kelly's ratio were computed and USSL, Wilcox and Doneen's diagrams were also used for evaluation of groundwater quality for irrigation. For industrial purpose, the pH, TDS, {HCO}3^{ - } , Cl- and {SO}4^{2 - } were used to assess the impact of incrustation and corrosion activities on metal surfaces. As a whole, it is observed that the groundwater quality is not suitable for drinking, irrigation and industrial purposes due to one or more chemical parameters exceeding their standard limits. Therefore, groundwater management measures were suggested to improve the water quality.

Anthropization of groundwater resources in the Mediterranean region: processes and challenges

NASA Astrophysics Data System (ADS)

Leduc, Christian; Pulido-Bosch, Antonio; Remini, Boualem

2017-09-01

A comprehensive overview is provided of processes and challenges related to Mediterranean groundwater resources and associated changes in recent decades. While most studies are focused thematically and/or geographically, this paper addresses different stages of groundwater exploitation in the region and their consequences. Examples emphasize the complex interactions between the physical and social dimensions of uses and evolution of groundwater. In natural conditions, Mediterranean groundwater resources represent a wide range of hydrogeological contexts, recharge conditions and rates of exploitation. They have been actively exploited for millennia but their pseudo-natural regimes have been considerably modified in the last 50 years, especially to satisfy agricultural demand (80% of total water consumption in North Africa), as well as for tourism and coastal cities. Climate variability affects groundwater dynamics but the various forms of anthropization are more important drivers of hydrological change, including changes in land use and vegetation, hydraulic works, and intense pumpings. These changes affect both the quantity and quality of groundwater at different scales, and modify the nature of hydrogeological processes, their location, timing, and intensity. The frequent cases of drastic overexploitation illustrate the fragility of Mediterranean groundwater resources and the limits of present forms of management. There is no easy way to maintain or recover sustainability, which is often threatened by short-term interests. To achieve this goal, a significant improvement in hydrogeological knowledge and closer collaboration between the various disciplines of water sciences are indispensable.

Analysis of Aquifer Response, Groundwater Flow, and PlumeEvolution at Site OU 1, Former Fort Ord, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jordan, Preston D.; Oldenburg, Curtis M.; Su, Grace W.

2005-02-24

This report presents a continuation from Oldenburg et al. (2002) of analysis of the hydrogeology, In-Situ Permeable Flow Sensor (ISPFS) results, aquifer response, and changes in the trichloroethylene (TCE) groundwater plume at Operational Unit 1 (OU 1) adjacent to the former Fritzsche Army Airfield at the former Fort Ord Army Base, located on Monterey Bay in northern Monterey County. Fuels and solvents were burned on a portion of OU 1 called the Fire Drill Area (FDA) during airport fire suppression training between 1962 and 1985. This activity resulted in soil and groundwater contamination in the unconfined A-aquifer. In the latemore » 1980's, soil excavation and bioremediation were successful in remediating soil contamination at the site. Shortly thereafter, a groundwater pump, treat, and recharge system commenced operation. This system has been largely successful at remediating groundwater contamination at the head of the groundwater plume. However, a trichloroethylene (TCE) groundwater plume extends approximately 3000 ft (900 m) to the northwest away from the FDA. In the analyses presented here, we augment our prior work (Oldenburg et al., 2002) with new information including treatment-system totalizer data, recent water-level and chemistry data, and data collected from new wells to discern trends in contaminant migration and groundwater flow that may be useful for ongoing remediation efforts. Some conclusions from the prior study have been modified based on these new analyses, and these are pointed out clearly in this report.« less

Time-resolved stimulated emission depletion and energy transfer dynamics in two-photon excited EGFP.

PubMed

Masters, T A; Robinson, N A; Marsh, R J; Blacker, T S; Armoogum, D A; Larijani, B; Bain, A J

2018-04-07

Time and polarization-resolved stimulated emission depletion (STED) measurements are used to investigate excited state evolution following the two-photon excitation of enhanced green fluorescent protein (EGFP). We employ a new approach for the accurate STED measurement of the hitherto unmeasured degree of hexadecapolar transition dipole moment alignment α 40 present at a given excitation-depletion (pump-dump) pulse separation. Time-resolved polarized fluorescence measurements as a function of pump-dump delay reveal the time evolution of α 40 to be considerably more rapid than predicted for isotropic rotational diffusion in EGFP. Additional depolarization by homo-Förster resonance energy transfer is investigated for both α 20 (quadrupolar) and α 40 transition dipole alignments. These results point to the utility of higher order dipole correlation measurements in the investigation of resonance energy transfer processes.

Experimental evaluation of rigor mortis. V. Effect of various temperatures on the evolution of rigor mortis.

PubMed

Krompecher, T

1981-01-01

Objective measurements were carried out to study the evolution of rigor mortis on rats at various temperatures. Our experiments showed that: (1) at 6 degrees C rigor mortis reaches full development between 48 and 60 hours post mortem, and is resolved at 168 hours post mortem; (2) at 24 degrees C rigor mortis reaches full development at 5 hours post mortem, and is resolved at 16 hours post mortem; (3) at 37 degrees C rigor mortis reaches full development at 3 hours post mortem, and is resolved at 6 hours post mortem; (4) the intensity of rigor mortis grows with increase in temperature (difference between values obtained at 24 degrees C and 37 degrees C); and (5) and 6 degrees C a "cold rigidity" was found, in addition to and independent of rigor mortis.

Modeling the hydrogeophysical response of lake talik evolution

USGS Publications Warehouse

Minsley, Burke J.; Wellman, Tristan; Walvoord, Michelle Ann; Revil, Andre

2014-01-01

Geophysical methods provide valuable information about subsurface permafrost and its relation to dynamic hydrologic systems. Airborne electromagnetic data from interior Alaska are used to map the distribution of permafrost, geological features, surface water, and groundwater. To validate and gain further insight into these field datasets, we also explore the geophysical response to hydrologic simulations of permafrost evolution by implementing a physical property relationship that connects geology, temperature, and ice saturation to changes in electrical properties.

Resolving the Evolution of Extant and Extinct Ruminants With High-Throughput Phylogenomics

USDA-ARS?s Scientific Manuscript database

The Pecorans (higher ruminants) are believed to have rapidly speciated in the Mid-Eocene, resulting in five distinct extant families; Antilocapridae, Giraffidae, Moschidae, Cervidae, and Bovidae. Due to the rapid radiation, the Pecoran phylogeny has proven difficult to resolve and eleven of the fift...

Long-Term Interactions of Streamflow Generation and River Basin Morphology

NASA Astrophysics Data System (ADS)

Huang, X.; Niemann, J.

2005-12-01

It is well known that the spatial patterns and dynamics of streamflow generation processes depend on river basin topography, but the impact of streamflow generation processes on the long-term evolution of river basins has not drawn as much attention. Fluvial erosion processes are driven by streamflow, which can be produced by Horton runoff, Dunne runoff, and groundwater discharge. In this analysis, we hypothesize that the dominant streamflow generation process in a basin affects the spatial patterns of fluvial erosion and that the nature of these patterns changes for storm events with differing return periods. Furthermore, we hypothesize that differences in the erosion patterns modify the topography over the long term in a way that promotes and/or inhibits the other streamflow generation mechanisms. In order to test these hypotheses, a detailed hydrologic model is imbedded into an existing landscape evolution model. Precipitation events are simulated with a Poisson process and have random intensities and durations. The precipitation is partitioned between Horton runoff and infiltration to groundwater using a specified infiltration capacity. Groundwater flow is described by a two-dimensional Dupuit equation for a homogeneous, isotropic, unconfined aquifer with an irregular underlying impervious layer. Dunne runoff occurs when precipitation falls on locations where the water table reaches the land surface. The combined hydrologic/geomorphic model is applied to the WE-38 basin, an experimental watershed in Pennsylvania that has substantial available hydrologic data. First, the hydrologic model is calibrated to reproduce the observed streamflow for 1990 using the observed rainfall as the input. Then, the relative roles of Horton runoff, Dunne runoff, and groundwater discharge are controlled by varying the infiltration capacity of the soil. For each infiltration capacity, the hydrologic and geomorphic behavior of the current topography is analyzed and the long-term evolution of the basin is simulated. The results indicate that the topography can be divided into three types of locations (unsaturated, saturated, and intermittently saturated) which control the patterns of streamflow generation for events with different return periods. The results also indicate that the streamflow generation processes can produce different geomorphic effective events at upstream and downstream locations. The model also suggests that a topography dominated by groundwater discharge evolves over a long period of time to a shape that tends to inhibit the development of saturated areas and Dunne runoff.

Hydrogeochemistry of groundwaters in and below the base of thick permafrost at Lupin, Nunavut, Canada

NASA Astrophysics Data System (ADS)

Stotler, Randy L.; Frape, Shaun K.; Ruskeeniemi, Timo; Ahonen, Lasse; Onstott, Tullis C.; Hobbs, Monique Y.

2009-06-01

SummaryShield fluids are commonly understood to evolve through water-rock interaction. However, fluids may also concentrate during ice formation. Very little is currently known about groundwater conditions beneath thick permafrost in crystalline environments. This paper evaluates three possible Shield fluid evolution pathways at a crystalline Shield location currently under 500+ meters of permafrost, including surfical cryogenic concentration of seawater, in situ cryogenic concentration and water-rock interaction. A primary goal of this study was to further scientific understanding of permafrost and its role in influencing deep flow system evolution, fluid movement and chemical evolution of waters in crystalline rocks. Precipitation, surface, permafrost and subpermafrost water samples were collected, as well as dissolved and free gas samples, fracture fillings and matrix fluid samples to characterize the site. Investigations of groundwater conditions beneath thick permafrost provides valuable information which can be applied to safety assessment of deep, underground nuclear waste repositories, effects of long-term mining in permafrost areas and understanding analogues to potential life-bearing zones on Mars. The study was conducted in the Lupin gold mine in Nunavut, Canada, located within the zone of continuous permafrost. Through-taliks beneath large lakes in the area provided potential hydraulic connections through the permafrost. Na-Cl and Na-Cl-SO 4 type permafrost waters were contaminated by mining activities, affecting the chloride and nitrate concentrations. High nitrate concentrations (423-2630 mg L -1) were attributed to remnants of blasting. High sulfate concentrations in the permafrost (578-5000 mg L -1) were attributed to naturally occurring and mining enhanced sulfide oxidation. Mine dewatering created an artificial hydraulic gradient, resulting in methane hydrate dissociation at depth. Less contaminated basal waters had medium sulfate concentrations and were Ca-Na dominated, similar to deeper subpermafrost waters. Subpermafrost waters had a wide range of salinities (2.6-40 g L -1). It was unclear from this investigation what impact talik waters would have on deep groundwaters in undisturbed environments. In situ cryogenic concentration due to ice and methane hydrate formation may have concentrated the remaining fluids, however there was no evidence that infiltration of cryogenically concentrated seawater occurred since the last glacial maximum. Matrix waters were dilute and unable to affect groundwater salinity. Fracture infillings were scarce, but calcite fluid inclusion microthermometry indicated a large range in salinities, potentially an additional source of salinity to the system.

A GIS-based model of potential groundwater yield zonation for a sandstone aquifer in the Juye Coalfield, Shangdong, China

NASA Astrophysics Data System (ADS)

Yin, Huiyong; Shi, Yongli; Niu, Huigong; Xie, Daolei; Wei, Jiuchuan; Lefticariu, Liliana; Xu, Shuanxiang

2018-02-01

Resolving the potential groundwater yield zonation of sandstone aquifers occurring at depths of several hundred meters has been an important and challenging objective of the hydrogeological research focused on preventing flood hazards in coal mines. Using accessible geological exploration data we put forward a method of predicting the spatial distribution of groundwater storage potential in sandstone aquifers from Permian-age coal deposits in Juye Coalfield, Shangdong, China. A Geological, Tectonic and Lithological Composition Index (GTLCI) model was created using the following parameters: sandstone depth and thickness, faults length density (FaLD), faults density (FaD), fault frequency density (FaFD), fault scale density (FaSD), variation coefficient of the slope (VCS) of the coal seam, intensity index of folds in horizontal direction (IIFoH), and lithological composition index (LCI). Each of these factors was subsequently divided into 5 classes. The analytic hierarchy process (AHP) and trapezoidal fuzzy number (TFN) method was applied to calculate the weight of the conditioning factor and their respective sub-classes. Groundwater yield potential contour map, which was initially constructed using the GTLCI values revealed four groundwater abundance zones. The map was further refined by taking into account hydrogeologic data collected during mining activities. The GTLCI model predictive success rate of 80% was explained by the limited number of boreholes available for validation. It is considered that the GTLCI model is effective at predicting zonation of groundwater yield in the sandstone aquifers from Permian- age coal deposits in Juye Coalfield, China.

Generation of 3-D hydrostratigraphic zones from dense airborne electromagnetic data to assess groundwater model prediction error

USGS Publications Warehouse

Christensen, Nikolaj K; Minsley, Burke J.; Christensen, Steen

2017-01-01

We present a new methodology to combine spatially dense high-resolution airborne electromagnetic (AEM) data and sparse borehole information to construct multiple plausible geological structures using a stochastic approach. The method developed allows for quantification of the performance of groundwater models built from different geological realizations of structure. Multiple structural realizations are generated using geostatistical Monte Carlo simulations that treat sparse borehole lithological observations as hard data and dense geophysically derived structural probabilities as soft data. Each structural model is used to define 3-D hydrostratigraphical zones of a groundwater model, and the hydraulic parameter values of the zones are estimated by using nonlinear regression to fit hydrological data (hydraulic head and river discharge measurements). Use of the methodology is demonstrated for a synthetic domain having structures of categorical deposits consisting of sand, silt, or clay. It is shown that using dense AEM data with the methodology can significantly improve the estimated accuracy of the sediment distribution as compared to when borehole data are used alone. It is also shown that this use of AEM data can improve the predictive capability of a calibrated groundwater model that uses the geological structures as zones. However, such structural models will always contain errors because even with dense AEM data it is not possible to perfectly resolve the structures of a groundwater system. It is shown that when using such erroneous structures in a groundwater model, they can lead to biased parameter estimates and biased model predictions, therefore impairing the model's predictive capability.

Generation of 3-D hydrostratigraphic zones from dense airborne electromagnetic data to assess groundwater model prediction error

NASA Astrophysics Data System (ADS)

Christensen, N. K.; Minsley, B. J.; Christensen, S.

2017-02-01

We present a new methodology to combine spatially dense high-resolution airborne electromagnetic (AEM) data and sparse borehole information to construct multiple plausible geological structures using a stochastic approach. The method developed allows for quantification of the performance of groundwater models built from different geological realizations of structure. Multiple structural realizations are generated using geostatistical Monte Carlo simulations that treat sparse borehole lithological observations as hard data and dense geophysically derived structural probabilities as soft data. Each structural model is used to define 3-D hydrostratigraphical zones of a groundwater model, and the hydraulic parameter values of the zones are estimated by using nonlinear regression to fit hydrological data (hydraulic head and river discharge measurements). Use of the methodology is demonstrated for a synthetic domain having structures of categorical deposits consisting of sand, silt, or clay. It is shown that using dense AEM data with the methodology can significantly improve the estimated accuracy of the sediment distribution as compared to when borehole data are used alone. It is also shown that this use of AEM data can improve the predictive capability of a calibrated groundwater model that uses the geological structures as zones. However, such structural models will always contain errors because even with dense AEM data it is not possible to perfectly resolve the structures of a groundwater system. It is shown that when using such erroneous structures in a groundwater model, they can lead to biased parameter estimates and biased model predictions, therefore impairing the model's predictive capability.

Optimizing water resources management in large river basins with integrated surface water-groundwater modeling: A surrogate-based approach

NASA Astrophysics Data System (ADS)

Wu, Bin; Zheng, Yi; Wu, Xin; Tian, Yong; Han, Feng; Liu, Jie; Zheng, Chunmiao

2015-04-01

Integrated surface water-groundwater modeling can provide a comprehensive and coherent understanding on basin-scale water cycle, but its high computational cost has impeded its application in real-world management. This study developed a new surrogate-based approach, SOIM (Surrogate-based Optimization for Integrated surface water-groundwater Modeling), to incorporate the integrated modeling into water management optimization. Its applicability and advantages were evaluated and validated through an optimization research on the conjunctive use of surface water (SW) and groundwater (GW) for irrigation in a semiarid region in northwest China. GSFLOW, an integrated SW-GW model developed by USGS, was employed. The study results show that, due to the strong and complicated SW-GW interactions, basin-scale water saving could be achieved by spatially optimizing the ratios of groundwater use in different irrigation districts. The water-saving potential essentially stems from the reduction of nonbeneficial evapotranspiration from the aqueduct system and shallow groundwater, and its magnitude largely depends on both water management schemes and hydrological conditions. Important implications for water resources management in general include: first, environmental flow regulation needs to take into account interannual variation of hydrological conditions, as well as spatial complexity of SW-GW interactions; and second, to resolve water use conflicts between upper stream and lower stream, a system approach is highly desired to reflect ecological, economic, and social concerns in water management decisions. Overall, this study highlights that surrogate-based approaches like SOIM represent a promising solution to filling the gap between complex environmental modeling and real-world management decision-making.

What Drives Saline Circulation Cells in Coastal Aquifers? An Energy Balance for Density-Driven Groundwater Systems

NASA Astrophysics Data System (ADS)

Harvey, C. F.; Michael, H. A.

2017-12-01

We formulate the energy balance for coastal groundwater systems and apply it to: (1) Explain the energy driving offshore saline circulation cells, and; (2) Assess the accuracy of numerical simulations of coastal groundwater systems. The flow of fresh groundwater to the ocean is driven by the loss of potential energy as groundwater drops from the elevation of the inland watertable, where recharge occurs, to discharge at sea level. This freshwater flow creates an underlying circulation cell of seawater, drawn into coastal aquifers offshore and discharging near shore, that adds to total submarine groundwater discharge. The saline water in the circulation cell enters and exits the aquifer through the sea floor at the same hydraulic potential. Existing theory explains that the saline circulation cell is driven by mixing of fresh and saline without any additional source of potential or mechanical power. This explanation raises a basic thermodynamic question: what is the source of energy that drives the saline circulation cell? Here, we resolve this question by building upon Hubbert's conception of hydraulic potential to formulate an energy balance for density-dependent flow and salt transport through an aquifer. We show that, because local energy dissipation within the aquifer is proportional to the square of the groundwater velocity, more groundwater flow may be driven through an aquifer for a given energy input if local variations in velocity are smoothed. Our numerical simulations of coastal groundwater systems show that dispersion of salt across the fresh-saline interface spreads flow over larger volumes of the aquifer, smoothing the velocity field, and increasing total flow and submarine groundwater discharge without consuming more power. The energy balance also provides a criterion, in addition to conventional mass balances, for judging the accuracy of numerical solutions of non-linear density-dependent flow problems. Our results show that some numerical simulations of saline circulation converge to excellent balances of both mass and energy, but that other simulations may poorly balance energy even after converging to a good mass balance. Thus, the energy balance can be used to identify incorrect simulations that pass convential mass balance criteria for accuracy.

Numerical analysis of stress effects on Frank loop evolution during irradiation in austenitic Fe&z.sbnd;Cr&z.sbnd;Ni alloy

NASA Astrophysics Data System (ADS)

Tanigawa, Hiroyasu; Katoh, Yutai; Kohyama, Akira

1995-08-01

Effects of applied stress on early stages of interstitial type Frank loop evolution were investigated by both numerical calculation and irradiation experiments. The final objective of this research is to propose a comprehensive model of complex stress effects on microstructural evolution under various conditions. In the experimental part of this work, the microstructural analysis revealed that the differences in resolved normal stress caused those in the nucleation rates of Frank loops on {111} crystallographic family planes, and that with increasing external applied stress the total nucleation rate of Frank loops was increased. A numerical calculation was carried out primarily to evaluate the validity of models of stress effects on nucleation processes of Frank loop evolution. The calculation stands on rate equuations which describe evolution of point defects, small points defect clusters and Frank loops. The rate equations of Frank loop evolution were formulated for {111} planes, considering effects of resolved normal stress to clustering processes of small point defects and growth processes of Frank loops, separately. The experimental results and the predictions from the numerical calculation qualitatively coincided well with each other.

Insights into the Groundwater Salinization Processes in Manas River Basin, Northwest China

NASA Astrophysics Data System (ADS)

Jin, M.; Liu, Y.; Liang, X.

2017-12-01

Manas River Basin (MRB) is a typical mountains-oasis-desert inland basin in northwest China, where groundwater salinization is threatening the local water use and the environment, but the groundwater salinization process is not clear. Based on groundwater flow system analysis by integrating flow fields, hydrochemical and isotopic characteristics, a deuterium excess analytical method was used to quantitatively assess salinization mechanism and calculate the contribution ratios of evapoconcentration effect to the salinities. 73 groundwater samples and 11 surface water samples were collected from the basin. Hydrochemical diagrams and δD and δ18O compositions indicated that evapoconcentration, mineral dissolution and transpiration, increased the groundwater salinities (i.e. total dissolved solids). The results showed that the average contribution ratios of evapoconcentration effect to the increased salinities were 5.8% and 32.7% in groundwater and surface water, respectively. From the piedmont plain to the desert plain, the evapoconcentration effect increased the average groundwater loss from 7% to 29%. However, it only increased slight salinity (0 - 0.27 g/L), as determined from the deuterium excess signals. Minerals dissolution and anthropogenic activities are the major cause of groundwater salinization problem. The results revealed that fresh water in the rivers directly and quickly infiltrated the aquifers in the piedmont area with evapoconcentration affected weakly, and the fresh water interacted with the sediments and dissolved soluble minerals, subsequently increasing the salinities. Combined with the groundwater stable isotopic compositions and hydrochemical evolution, the relationships between δ18O and Cl and salinities reveal the soil evaporites leaching by the vertical recharge (irrigation return flow and channels leakage) mainly affect the groundwater salinization processes in the middle alluvial-diluvial plain and the desert land. The saline water released from aquitards by continuous decline of water level due to over exploitation is an additional factor for groundwater salinization.

A synthesis of hydrochemistry with an integrated conceptual model for groundwater in the Hexi Corridor, northwestern China

NASA Astrophysics Data System (ADS)

Wang, Liheng; Dong, Yanhui; Xu, Zhifang

2017-09-01

Although many studies have investigated the recharge and evolution of groundwater in the Hexi Corridor, northwestern (NW) China, they describe individual sites such as Jinchang, Jiuquan, Dunhuang, and others. Considering the similarity of these sites, a systematic review of the entire Hexi Corridor is lacking. This paper compares and summarizes previous studies in the Hexi Corridor to provide a regional perspective of the isotopic characteristics and hydrochemical composition of groundwater. In unconfined aquifers, groundwater is recharged by snow and ice melt water from the Qilian Mountains; local precipitation can be neglected. Therefore, the groundwater belongs to a unique hydrological cycle model in the Hexi Corridor, referred to as snow and ice melt water-groundwater system. The dominant anion species changes from HCO3- in front of the mountains to SO42- in the middle basin and Cl- at the basin boundary along the groundwater flow direction, and TDS increases gradually owing to evaporation. A major hydrogeochemical process is the dissolution of minerals from the aquifer in the recharge area changing to cation exchange reactions in the discharge area. Confined groundwater was recharged mainly in the late Pleistocene and middle Holocene at colder temperatures than those of modern times; thus, it is non-renewable. In addition to dissolution, the hydrochemical composition of confined groundwater is also affected by cation exchange reactions. The hydrogeochemical categories of the confined groundwater are simple and stable. In the present study, a conceptual model is established on the basis of the analyses presented, which has important implications for water resource management in the Hexi Corridor. The inter-basin water allocation program should continue in order to achieve optimal utilization of water resources, but groundwater exploitation should be limited as much as possible. Additionally, on the basis of the review and integration of previous research, the regional groundwater cycle patterns in the Hexi Corridor are illustrated in the present study, and new research questions are identified for future work.

A methodology for space-time classification of groundwater quality.

PubMed

Passarella, G; Caputo, M C

2006-04-01

Safeguarding groundwater from civil, agricultural and industrial contamination is matter of great interest in water resource management. During recent years, much legislation has been produced stating the importance of groundwater as a source for drinking water supplies, underlining its vulnerability and defining the required quality standards. Thus, schematic tools, able to characterise the quality and quantity of groundwater systems, are of very great interest in any territorial planning and/or water resource management activity. This paper proposes a groundwater quality classification method which has been applied to a real aquifer, starting from several studies published by the Italian National Hydrogeologic Catastrophe Defence Group (GNDCI). The methodology is based on the concentration values of several parameters used as indexes of the natural hydro-chemical water condition and of potential man-induced modifications of groundwater quality. The resulting maps, although representative of the quality, do not include any information on its evolution in time. In this paper, this "stationary" classification method has been improved by crossing the quality classes with three indexes of temporal behaviour during recent years. It was then applied to data from monitoring campaigns, performed in spring and autumn, from 1990 to 1996, in the plain of Modena aquifer (central Italy). The results are reported in the form of space-time classification table and maps.

Hydrochemical characterization and pollution sources identification of groundwater in Salawusu aquifer system of Ordos Basin, China.

PubMed

Yang, Qingchun; Wang, Luchen; Ma, Hongyun; Yu, Kun; Martín, Jordi Delgado

2016-09-01

Ordos Basin is located in an arid and semi-arid region of northwestern China, which is the most important energy source bases in China. Salawusu Formation (Q3 s) is one of the most important aquifer systems of Ordos Basin, which is adjacent to Jurassic coalfield areas. A large-scale exploitation of Jurassic coal resources over ten years results in series of influences to the coal minerals, such as exposed to the oxidation process and dissolution into the groundwater due to the precipitation infiltration. Therefore, how these processes impact groundwater quality is of great concerns. In this paper, the descriptive statistical method, Piper trilinear diagram, ratios of major ions and canonical correspondence analysis are employed to investigate the hydrochemical evolution, determine the possible sources of pollution processes, and assess the controls on groundwater compositions using the monitored data in 2004 and 2014 (before and after large-scale coal mining). Results showed that long-term exploration of coal resources do not result in serious groundwater pollution. The hydrochemical types changed from HCO3(-)-CO3(2-) facies to SO4(2-)-Cl facies during 10 years. Groundwater hardness, nitrate and sulfate pollution were identified in 2014, which was most likely caused by agricultural activities. Copyright © 2016 Elsevier Ltd. All rights reserved.

Groundwater sapping valleys: Experimental studies, geological controls and implications to the interpretation of valley networks on Mars

NASA Technical Reports Server (NTRS)

Kochel, R. Craig

1988-01-01

An integrated approach using experimental laboratory models, field studies of terrestrial analogs, and remote studies of terrestrial field sites were applied to the goals of understanding the nature and morphology of valley networks formed by groundwater sapping. In spite of problems with scaling, the experimental studies provide valuable insights into concepts relating to the initiation, development, and evolution of valleys by groundwater sapping. These investigations are also aimed at developing geomorphic criteria for distinguishing valleys formed by surface runoff from those formed by groundwater sapping processes. Channels that were field classified as sapping vs. runoff were successfully distinguished using statistical analysis of their respective morphologies; therefore, it may be possible to use similar techniques to interpret channel genesis on Mars. The terrestrial and flume studies provide the ground truth dataset which can be used (and will be during the present year) to help interpret the genesis of valley networks on Mars.

Impact of fresh tailing deposition on the evolution of groundwater hydrogeochemistry at the abandoned Manitou mine site, Quebec, Canada.

PubMed

Maqsoud, Abdelkabir; Neculita, Carmen Mihaela; Bussière, Bruno; Benzaazoua, Mostafa; Dionne, Jean

2016-05-01

The abandoned Manitou mine site has produced acid mine drainage (AMD) for several decades. In order to limit the detrimental environmental impacts of AMD, different rehabilitation scenarios were proposed and analyzed. The selected rehabilitation scenario was to use fresh tailings from the neighboring Goldex gold mine as monolayer cover and to maintain an elevated water table. In order to assess the impact of the Goldex tailing deposition on the hydrogeochemistry of the Manitou mine site, a network of 30 piezometers was installed. These piezometers were used for continuous measurement of the groundwater level, as well as for water sampling campaigns for chemical quality monitoring, over a 3-year period. Hydrochemical data were analyzed using principal component analysis. Results clearly showed the benefic impact of fresh tailing deposition on the groundwater quality around the contaminated area. These findings were also confirmed by the evolution of electrical conductivity. In addition to the improvement of the physicochemical quality of water on the Manitou mine site, new tailing deposition induced an increase of water table level. However, at this time, the Manitou reactive tailings are not completely submerged and possible oxidation might still occur, especially after ceasing of the fresh tailing deposition. Therefore, complementary rehabilitation scenarios should still be considered.

THM large spatial-temporal model to simulate the past 2 Ma hydrogeological evolution of Paris Basin including natural tracer transport as part of site characterization for radwaste repository project Cigéo - France

NASA Astrophysics Data System (ADS)

Benabderrahmane, A., Sr.

2017-12-01

Hydrogeological site characterization for deep geological high level and intermediate level long lived radioactive waste repository cover a large time scale needed for safety analysis and calculation. Hydrogeological performance of a site relies also on the effects of geodynamic evolution as tectonic uplift, erosion/sedimentation and climate including glaciation on the groundwater flow and solute and heat transfer. Thermo-Hydro-Mechanical model of multilayered aquifer system of Paris Basin is developed to reproduce the present time flow and the natural tracer (Helium) concentration profiles based on the last 2 Ma of geodynamic evolution. Present time geological conceptual model consist of 27 layers at Paris Basin (Triassic-Tertiary) with refinement at project site scale (29 layers from Triassic to Portlandian). Target layers are the clay host formation of Callovo-Oxfrodian age (160 Ma) and the surrounding aquifer layers of Oxfordian and Dogger. Modelled processes are: groundwater flow, heat and solutes (natural tracers) transport, freezing and thawing of groundwater (expansion and retreat of permafrost), deformation of the multilayered aquifer system induced by differential tectonic uplift and the hydro-mechanical stress effect as caused by erosion of the outcropping layers. Numerical simulation considers a period from 2 Ma BP and up to the present. Transient boundary conditions are governed by geodynamic processes: (i) modification of the geometry of the basin and (ii) temperatures along the topography will change according to a series of 15 identical climate cycles with multiple permafrost (glaciation) periods. Numerical model contains 71 layers and 18 million cells. The solution procedure solves three coupled systems of equations, head, temperature and concentrations, by the use of a finite difference method, and by applying extensive parallel processing. The major modelling results related to the processes of importance for site characterization as hydraulic head distribution, flow velocity, heat and natural tracer transport impacted by geodynamic past evolution are discussed.

Experimental research on time-resolved evolution of cathode plasma expansion velocity in a long pulsed magnetically insulated coaxial diode

NASA Astrophysics Data System (ADS)

Zhu, Danni; Zhang, Jun; Zhong, Huihuang; Ge, Xingjun; Gao, Jingming

2018-02-01

Unlike planar diodes, separate research of the axial and radial plasma expansion velocities is difficult for magnetically insulated coaxial diodes. Time-resolved electrical diagnostic which is based on the voltage-ampere characteristics has been employed to study the temporal evolution of the axial and radial cathode plasma expansion velocities in a long pulsed magnetically insulated coaxial diode. Different from a planar diode with a "U" shaped profile of temporal velocity evolution, the temporal evolution trend of the axial expansion velocity is proved to be a "V" shaped profile. Apart from the suppression on the radial expansion velocity, the strong magnetic field is also conducive to slowing down the axial expansion velocity. Compared with the ordinary graphite cathode, the carbon velvet and graphite composite cathode showed superior characteristics as judged by the low plasma expansion velocity and long-term electrical stability as a promising result for applications where long-pulsed and reliable operation at high power is required.

Measurements and modelling of beach groundwater flow in the swash-zone: a review

NASA Astrophysics Data System (ADS)

Horn, Diane P.

2006-04-01

This paper reviews research on beach groundwater dynamics and identifies research questions which will need to be answered before swash zone sediment transport and beach profile evolution can be successfully modelled. Beach groundwater hydrodynamics are a result of combined forcing from the tide and waves at a range of frequencies, and a large number of observations exist which describe the shape and elevation of the beach watertable in response to tidal forcing at diurnal, semi-diurnal and spring-neap tidal frequencies. Models of beach watertable response to tidal forcing have been successfully validated; however, models of watertable response to wave forcing are less well developed and require verification. Improved predictions of swash zone sediment transport and beach profile evolution cannot be achieved unless the complex fluid and sediment interactions between the surface flow and the beach groundwater are better understood, particularly the sensitivity of sediment transport processes to flow perpendicular to the permeable bed. The presence of a capillary fringe, particularly when it lies just below the sand surface, has influences on beach groundwater dynamics. The presence of a capillary fringe can have a significant effect on the exchange of water between the ocean and the coastal aquifer, particularly in terms of the storage capacity of the aquifer. Field and laboratory observations have also shown that natural groundwater waves usually propagate faster and decay more slowly in aquifers with a capillary fringe, and observations which suggest that horizontal flows may also occur in the capillary zone have been reported. The effects of infiltration and exfiltration are generally invoked to explain why beaches with a low watertable tend to accrete and beaches with a high watertable tend to erode. However, the relative importance of processes such as infiltration losses in the swash, changes in the effective weight of the sediment, and modified shear stress due to boundary layer thinning, are not yet clear. Experimental work on the influence of seepage flows within sediment beds provides conflicting results concerning the effect on bed stability. Both modelling and experimental work indicates that the hydraulic conductivity of the beach is a critical parameter. However, hydraulic conductivity varies both spatially and temporally on beaches, particularly on gravel and mixed sand and gravel beaches. Another important, but poorly understood, consideration in beach groundwater studies is the role of air encapsulation during the wetting of beach sand.

Modelling Time-Resolved Two-Dimensional Electronic Spectroscopy of the Primary Photoisomerization Event in Rhodopsin

PubMed Central

2015-01-01

Time-resolved two-dimensional (2D) electronic spectra (ES) tracking the evolution of the excited state manifolds of the retinal chromophore have been simulated along the photoisomerization pathway in bovine rhodopsin, using a state-of-the-art hybrid QM/MM approach based on multiconfigurational methods. Simulations of broadband 2D spectra provide a useful picture of the overall detectable 2D signals from the near-infrared (NIR) to the near-ultraviolet (UV). Evolution of the stimulated emission (SE) and excited state absorption (ESA) 2D signals indicates that the S1 → SN (with N ≥ 2) ESAs feature a substantial blue-shift only after bond inversion and partial rotation along the cis → trans isomerization angle, while the SE rapidly red-shifts during the photoinduced skeletal relaxation of the polyene chain. Different combinations of pulse frequencies are proposed in order to follow the evolution of specific ESA signals. These include a two-color 2DVis/NIR setup especially suited for tracking the evolution of the S1 → S2 transitions that can be used to discriminate between different photochemical mechanisms of retinal photoisomerization as a function of the environment. The reported results are consistent with the available time-resolved pump–probe experimental data, and may be used for the design of more elaborate transient 2D electronic spectroscopy techniques. PMID:24794143

Neural Network approach to assess the thermal affected zone around the injection well in a groundwater heat pump system

NASA Astrophysics Data System (ADS)

Lo Russo, Stefano; Taddia, Glenda; Verda, Vittorio

2014-05-01

The common use of well doublets for groundwater-sourced heating or cooling results in a thermal plume of colder or warmer re-injected groundwater known as the Thermal Affected Zone(TAZ). The plumes may be regarded either as a potential anthropogenic geothermal resource or as pollution, depending on downstream aquifer usage. A fundamental aspect in groundwater heat pump (GWHP) plant design is the correct evaluation of the thermally affected zone that develops around the injection well. Temperature anomalies are detected through numerical methods. Crucial elements in the process of thermal impact assessment are the sizes of installations, their position, the heating/cooling load of the building, and the temperature drop/increase imposed on the re-injected water flow. For multiple-well schemes, heterogeneous aquifers, or variable heating and cooling loads, numerical models that simulate groundwater and heat transport are needed. These tools should consider numerous scenarios obtained considering different heating/cooling loads, positions, and operating modes. Computational fluid dynamic (CFD) models are widely used in this field because they offer the opportunity to calculate the time evolution of the thermal plume produced by a heat pump, depending on the characteristics of the subsurface and the heat pump. Nevertheless, these models require large computational efforts, and therefore their use may be limited to a reasonable number of scenarios. Neural networks could represent an alternative to CFD for assessing the TAZ under different scenarios referring to a specific site. The use of neural networks is proposed to determine the time evolution of the groundwater temperature downstream of an installation as a function of the possible utilization profiles of the heat pump. The main advantage of neural network modeling is the possibility of evaluating a large number of scenarios in a very short time, which is very useful for the preliminary analysis of future multiple installations. The neural network is trained using the results from a CFD model (FEFLOW) applied to the installation at Politecnico di Torino (Italy) under several operating conditions.

Long-term geochemical evolution of the near field repository: Insights from reactive transport modelling and experimental evidences

NASA Astrophysics Data System (ADS)

Arcos, David; Grandia, Fidel; Domènech, Cristina; Fernández, Ana M.; Villar, María V.; Muurinen, Arto; Carlsson, Torbjörn; Sellin, Patrik; Hernán, Pedro

2008-12-01

The KBS-3 underground nuclear waste repository concept designed by the Swedish Nuclear Fuel and Waste Management Co. (SKB) includes a bentonite buffer barrier surrounding the copper canisters and the iron insert where spent nuclear fuel will be placed. Bentonite is also part of the backfill material used to seal the access and deposition tunnels of the repository. The bentonite barrier has three main safety functions: to ensure the physical stability of the canister, to retard the intrusion of groundwater to the canisters, and in case of canister failure, to retard the migration of radionuclides to the geosphere. Laboratory experiments (< 10 years long) have provided evidence of the control exerted by accessory minerals and clay surfaces on the pore water chemistry. The evolution of the pore water chemistry will be a primordial factor on the long-term stability of the bentonite barrier, which is a key issue in the safety assessments of the KBS-3 concept. In this work we aim to study the long-term geochemical evolution of bentonite and its pore water in the evolving geochemical environment due to climate change. In order to do this, reactive transport simulations are used to predict the interaction between groundwater and bentonite which is simulated following two different pathways: (1) groundwater flow through the backfill in the deposition tunnels, eventually reaching the top of the deposition hole, and (2) direct connection between groundwater and bentonite rings through fractures in the granite crosscutting the deposition hole. The influence of changes in climate has been tested using three different waters interacting with the bentonite: present-day groundwater, water derived from ice melting, and deep-seated brine. Two commercial bentonites have been considered as buffer material, MX-80 and Deponit CA-N, and one natural clay (Friedland type) for the backfill. They show differences in the composition of the exchangeable cations and in the accessory mineral content. Results from the simulations indicate that pore water chemistry is controlled by the equilibrium with the accessory minerals, especially carbonates. pH is buffered by precipitation/dissolution of calcite and dolomite, when present. The equilibrium of these minerals is deeply influenced by gypsum dissolution and cation exchange reactions in the smectite interlayer. If carbonate minerals are initially absent in bentonite, pH is then controlled by surface acidity reactions in the hydroxyl groups at the edge sites of the clay fraction, although its buffering capacity is not as strong as the equilibrium with carbonate minerals. The redox capacity of the bentonite pore water system is mainly controlled by Fe(II)-bearing minerals (pyrite and siderite). Changes in the groundwater composition lead to variations in the cation exchange occupancy, and dissolution-precipitation of carbonate minerals and gypsum. The most significant changes in the evolution of the system are predicted when ice-melting water, which is highly diluted and alkaline, enters into the system. In this case, the dissolution of carbonate minerals is enhanced, increasing pH in the bentonite pore water. Moreover, a rapid change in the population of exchange sites in the smectite is expected due to the replacement of Na for Ca.

Long-term geochemical evolution of the near field repository: insights from reactive transport modelling and experimental evidences.

PubMed

Arcos, David; Grandia, Fidel; Domènech, Cristina; Fernández, Ana M; Villar, María V; Muurinen, Arto; Carlsson, Torbjörn; Sellin, Patrik; Hernán, Pedro

2008-12-12

The KBS-3 underground nuclear waste repository concept designed by the Swedish Nuclear Fuel and Waste Management Co. (SKB) includes a bentonite buffer barrier surrounding the copper canisters and the iron insert where spent nuclear fuel will be placed. Bentonite is also part of the backfill material used to seal the access and deposition tunnels of the repository. The bentonite barrier has three main safety functions: to ensure the physical stability of the canister, to retard the intrusion of groundwater to the canisters, and in case of canister failure, to retard the migration of radionuclides to the geosphere. Laboratory experiments (< 10 years long) have provided evidence of the control exerted by accessory minerals and clay surfaces on the pore water chemistry. The evolution of the pore water chemistry will be a primordial factor on the long-term stability of the bentonite barrier, which is a key issue in the safety assessments of the KBS-3 concept. In this work we aim to study the long-term geochemical evolution of bentonite and its pore water in the evolving geochemical environment due to climate change. In order to do this, reactive transport simulations are used to predict the interaction between groundwater and bentonite which is simulated following two different pathways: (1) groundwater flow through the backfill in the deposition tunnels, eventually reaching the top of the deposition hole, and (2) direct connection between groundwater and bentonite rings through fractures in the granite crosscutting the deposition hole. The influence of changes in climate has been tested using three different waters interacting with the bentonite: present-day groundwater, water derived from ice melting, and deep-seated brine. Two commercial bentonites have been considered as buffer material, MX-80 and Deponit CA-N, and one natural clay (Friedland type) for the backfill. They show differences in the composition of the exchangeable cations and in the accessory mineral content. Results from the simulations indicate that pore water chemistry is controlled by the equilibrium with the accessory minerals, especially carbonates. pH is buffered by precipitation/dissolution of calcite and dolomite, when present. The equilibrium of these minerals is deeply influenced by gypsum dissolution and cation exchange reactions in the smectite interlayer. If carbonate minerals are initially absent in bentonite, pH is then controlled by surface acidity reactions in the hydroxyl groups at the edge sites of the clay fraction, although its buffering capacity is not as strong as the equilibrium with carbonate minerals. The redox capacity of the bentonite pore water system is mainly controlled by Fe(II)-bearing minerals (pyrite and siderite). Changes in the groundwater composition lead to variations in the cation exchange occupancy, and dissolution-precipitation of carbonate minerals and gypsum. The most significant changes in the evolution of the system are predicted when ice-melting water, which is highly diluted and alkaline, enters into the system. In this case, the dissolution of carbonate minerals is enhanced, increasing pH in the bentonite pore water. Moreover, a rapid change in the population of exchange sites in the smectite is expected due to the replacement of Na for Ca.

A Methodology for Confirmatory Testing of Numerical Models of Groundwater Flow and Solute Transport in Fractured Crystalline Rock

NASA Astrophysics Data System (ADS)

Hartley, L.; Follin, S.; Rhen, I.; Selroos, J.

2008-12-01

Three-dimensional, regional, numerical models of groundwater flow and solute transport in fractured crystalline rock are used for two sites in Sweden that are considered for geological disposal of spent nuclear fuel. The models are used to underpin the conceptual modeling that is based on multi-disciplinary data and include descriptions of the geometry of geological features (deformation zones and fracture networks), transient hydrological and chemical boundary conditions, strong spatial heterogeneity in the hydraulic properties, density driven flow, solute transport including rock matrix diffusion, and mixing of different water types in a palaeo-hydrogeological perspective (last 10,000 years). From a credibility point of view, comparisons between measured and simulated data are important and provide a means to address our ability to understand complex hydrogeological systems, and hence what particular applications of a hydrogeological model of a physical system that are justified, e.g. in subsequent repository performance assessment studies. For instance, it has been suggested that an understanding of the hydrochemical evolution throughout geological time is a powerful tool to predict the future evolution of groundwater flow and its chemical composition. The general approach applied in the numerical modeling was to first parameterize the deformation zones and fracture networks hydraulically using fracture and inflow data from single-hole tests. Second, the confirmatory step relies on using essentially the same groundwater flow and solute transport model in terms of grid discretization and parameter settings for matching three types of independent field data: 1) large-scale cross-hole (interference) tests, 2) long-term monitoring of groundwater levels, and 3) hydrochemical composition of fracture water and matrix pore water in deep boreholes. We demonstrate here the modelling approach of the second step - confirmatory testing - using data from the site investigations undertaken at one of the sites in Sweden (Forsmark). Using the three types of data, a unified conceptual description of the groundwater system has been obtained. The integration of multi-disciplinary data and models in the confirmatory testing has provided a means to increase the level of confidence in the final site descriptive model. Specifically, discipline-specific data and models from hydrogeology (transmissivities, groundwater levels, hydraulic gradients), geology (genesis of structures, geometries), rock mechanics (principal stresses), hydrogeochemistry (fracture water and matrix pore water composition) and bedrock transport properties (flow wetted surface, advective residence time) have been utilized in the description of the groundwater system in the bedrock.

Dynamic evolution of light-induced orientation of dye-doped liquid crystals in liquid phase studied by time-resolved optically heterodyned optical Kerr effect technique.

PubMed

Yang, Pei; Liu, Liying; Xu, Lei

2008-02-28

Transient evolution of light-induced molecular reorientation both in 1-amino-anthraquinone (1AAQ) dye and azobenzene doped isotropic liquid crystals (LCs) were studied by time-resolved optically heterodyned optical Kerr effect method. The results give clear direct experimental proof that under short pulse (30 ps) excitation, LC molecules orientate toward the excitation light polarization direction in the 1AAQ/LC system. However, LC molecular orientation becomes orthogonal to the light polarization in azobenzene/LC system. Time-resolved excited-state absorption of 1AAQ and wavelength dependent excited-state absorption of azobenzene were also observed and their contributions to the early dynamics of the third order optical responses of the two systems were confirmed. A simplified two-level mean-field theory was derived to reveal the intensity dependence of orientation enhancement factor in azobenzene/LC system considering the photoisomerization process.

Time-resolved stimulated emission depletion and energy transfer dynamics in two-photon excited EGFP

NASA Astrophysics Data System (ADS)

Masters, T. A.; Robinson, N. A.; Marsh, R. J.; Blacker, T. S.; Armoogum, D. A.; Larijani, B.; Bain, A. J.

2018-04-01

Time and polarization-resolved stimulated emission depletion (STED) measurements are used to investigate excited state evolution following the two-photon excitation of enhanced green fluorescent protein (EGFP). We employ a new approach for the accurate STED measurement of the hitherto unmeasured degree of hexadecapolar transition dipole moment alignment ⟨α40 ⟩ present at a given excitation-depletion (pump-dump) pulse separation. Time-resolved polarized fluorescence measurements as a function of pump-dump delay reveal the time evolution of ⟨α40 ⟩ to be considerably more rapid than predicted for isotropic rotational diffusion in EGFP. Additional depolarization by homo-Förster resonance energy transfer is investigated for both ⟨α20 ⟩ (quadrupolar) and ⟨α40 ⟩ transition dipole alignments. These results point to the utility of higher order dipole correlation measurements in the investigation of resonance energy transfer processes.

Continental patterns of submarine groundwater discharge reveal coastal vulnerabilities.

PubMed

Sawyer, Audrey H; David, Cédric H; Famiglietti, James S

2016-08-12

Submarine groundwater discharge (SGD) delivers water and dissolved chemicals from continents to oceans, and its spatial distribution affects coastal water quality. Unlike rivers, SGD is broadly distributed and relatively difficult to measure, especially at continental scales. We present spatially resolved estimates of fresh (land-derived) SGD for the contiguous United States based on historical climate records and high-resolution hydrographic data. Climate controls regional patterns in fresh SGD, while coastal drainage geometry imparts strong local variability. Because the recharge zones that contribute fresh SGD are densely populated, the quality and quantity of fresh SGD are both vulnerable to anthropogenic disturbance. Our analysis unveils hot spots for contaminant discharge to marine waters and saltwater intrusion into coastal aquifers. Copyright © 2016, American Association for the Advancement of Science.

Geochemistry of Dissolved Organic Matter in a Spatially Highly Resolved Groundwater Petroleum Hydrocarbon Plume Cross-Section.

PubMed

Dvorski, Sabine E-M; Gonsior, Michael; Hertkorn, Norbert; Uhl, Jenny; Müller, Hubert; Griebler, Christian; Schmitt-Kopplin, Philippe

2016-06-07

At numerous groundwater sites worldwide, natural dissolved organic matter (DOM) is quantitatively complemented with petroleum hydrocarbons. To date, research has been focused almost exclusively on the contaminants, but detailed insights of the interaction of contaminant biodegradation, dominant redox processes, and interactions with natural DOM are missing. This study linked on-site high resolution spatial sampling of groundwater with high resolution molecular characterization of DOM and its relation to groundwater geochemistry across a petroleum hydrocarbon plume cross-section. Electrospray- and atmospheric pressure photoionization (ESI, APPI) ultrahigh resolution mass spectrometry (FT-ICR-MS) revealed a strong interaction between DOM and reactive sulfur species linked to microbial sulfate reduction, i.e., the key redox process involved in contaminant biodegradation. Excitation emission matrix (EEM) fluorescence spectroscopy in combination with Parallel Factor Analysis (PARAFAC) modeling attributed DOM samples to specific contamination traits. Nuclear magnetic resonance (NMR) spectroscopy evaluated the aromatic compounds and their degradation products in samples influenced by the petroleum contamination and its biodegradation. Our orthogonal high resolution analytical approach enabled a comprehensive molecular level understanding of the DOM with respect to in situ petroleum hydrocarbon biodegradation and microbial sulfate reduction. The role of natural DOM as potential cosubstrate and detoxification reactant may improve future bioremediation strategies.

Marine electrical resistivity imaging of submarine groundwater discharge: Sensitivity analysis and application in Waquoit Bay, Massachusetts, USA

USGS Publications Warehouse

Henderson, Rory; Day-Lewis, Frederick D.; Abarca, Elena; Harvey, Charles F.; Karam, Hanan N.; Liu, Lanbo; Lane, John W.

2010-01-01

Electrical resistivity imaging has been used in coastal settings to characterize fresh submarine groundwater discharge and the position of the freshwater/salt-water interface because of the relation of bulk electrical conductivity to pore-fluid conductivity, which in turn is a function of salinity. Interpretation of tomograms for hydrologic processes is complicated by inversion artifacts, uncertainty associated with survey geometry limitations, measurement errors, and choice of regularization method. Variation of seawater over tidal cycles poses unique challenges for inversion. The capabilities and limitations of resistivity imaging are presented for characterizing the distribution of freshwater and saltwater beneath a beach. The experimental results provide new insight into fresh submarine groundwater discharge at Waquoit Bay National Estuarine Research Reserve, East Falmouth, Massachusetts (USA). Tomograms from the experimental data indicate that fresh submarine groundwater discharge may shut down at high tide, whereas temperature data indicate that the discharge continues throughout the tidal cycle. Sensitivity analysis and synthetic modeling provide insight into resolving power in the presence of a time-varying saline water layer. In general, vertical electrodes and cross-hole measurements improve the inversion results regardless of the tidal level, whereas the resolution of surface arrays is more sensitive to time-varying saline water layer.

Assessment of Agricultural Water Management in Punjab, India using Bayesian Methods

NASA Astrophysics Data System (ADS)

Russo, T. A.; Devineni, N.; Lall, U.; Sidhu, R.

2013-12-01

The success of the Green Revolution in Punjab, India is threatened by the declining water table (approx. 1 m/yr). Punjab, a major agricultural supplier for the rest of India, supports irrigation with a canal system and groundwater, which is vastly over-exploited. Groundwater development in many districts is greater than 200% the annual recharge rate. The hydrologic data required to complete a mass-balance model are not available for this region, therefore we use Bayesian methods to estimate hydrologic properties and irrigation requirements. Using the known values of precipitation, total canal water delivery, crop yield, and water table elevation, we solve for each unknown parameter (often a coefficient) using a Markov chain Monte Carlo (MCMC) algorithm. Results provide regional estimates of irrigation requirements and groundwater recharge rates under observed climate conditions (1972 to 2002). Model results are used to estimate future water availability and demand to help inform agriculture management decisions under projected climate conditions. We find that changing cropping patterns for the region can maintain food production while balancing groundwater pumping with natural recharge. This computational method can be applied in data-scarce regions across the world, where agricultural water management is required to resolve competition between food security and changing resource availability.

Geophysical evaluation of groundwater potential in part of southwestern Basement Complex terrain of Nigeria

NASA Astrophysics Data System (ADS)

Bayewu, Olateju O.; Oloruntola, Moroof O.; Mosuro, Ganiyu O.; Laniyan, Temitope A.; Ariyo, Stephen O.; Fatoba, Julius O.

2017-12-01

The geophysical assessment of groundwater in Awa-Ilaporu, near Ago Iwoye southwestern Nigeria was carried out with the aim of delineating probable areas of high groundwater potential. The area falls within the Crystalline Basement Complex of southwestern Nigeria which is predominantly underlain by banded gneiss, granite gneiss and pegmatite. The geophysical investigation involves the very low frequency electromagnetic (VLF-EM) and Vertical Electrical Sounding (VES) methods. The VLF-EM survey was at 10 m interval along eight traverses ranging between 290 and 700 m in length using ABEM WADI VLF-EM unit. The VLF-EM survey was used to delineate areas with conductive/fractured zones. Twenty-three VES surveys were carried out with the use of Campus Ohmega resistivity meter at different location and at locations areas delineated as high conductive areas by VLF-EM survey. The result of VLF-EM survey along its traverse was used in delineating high conductive/fractured zones, it is, however, in agreement with the delineation of the VES survey. The VES results showed 3-4 geoelectric layers inferred as sandy topsoil, sandy clay, clayey and fractured/fresh basement. The combination of these two methods, therefore, helped in resolving the prospecting location for the groundwater yield in the study area.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC; Environmental Compliance Department Environment, Safety, and Health Division Y-12 National Security Complex

This document presents the Groundwater Protection Program (GWPP) management plan for the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12). The Y-12 GWPP functions as the primary point-of-contact for groundwater-related issues at Y-12, provides stewardship of the extensive network of groundwater monitoring wells at Y-12, and serves as a resource for technical expertise, support, and historical data for groundwater-related activities at Y-12. These organizational functions each serve the primary programmatic purpose of the GWPP, which is to ensure that groundwater monitoring activities within areas under Y-12 administrative control provide representative data in compliance with themore » multiple purposes of applicable state and federal regulations, DOE orders, and the corporate policies of BWXT Y-12, L.L.C. (hereafter referenced as BWXT), the Y-12 management and operations (M&O) contractor for DOE. This GWPP management plan addresses the requirements of DOE Order 450.1 (BWXT Y12 S/RID) regarding the implementation of a site-wide approach for groundwater protection at each DOE facility. Additionally, this plan is a ''living'' document that is reviewed annually, revised and reissued every three years, and is formatted to provide for updating individual sections independent of the rest of the document. Section 2 includes a short description of the groundwater system at Y-12, the history of groundwater monitoring at Y-12 and the corresponding evolution of the GWPP, and an overview of ongoing Y-12 groundwater monitoring activities. Section 3 describes the key elements of the GWPP management strategy. Organizational roles and responsibilities of GWPP personnel are outlined in Section 4. Section 5 presents an overview of the GWPP project plans for applicable programmatic elements. Section 6 lists the reports, plans, and documents that are referenced for technical and administrative details.« less

Chemical evolution of groundwater near a sinkhole lake, northern Florida: 1. Flow patterns, age of groundwater, and influence of lakewater leakage

USGS Publications Warehouse

Katz, Brian G.; Lee, Terrie M.; Plummer, Niel; Busenberg, Eurybiades

1995-01-01

Leakage from sinkhole lakes significantly influences recharge to the Upper Floridan aquifer in poorly confined sediments in northern Florida. Environmental isotopes (oxygen 18, deuterium, and tritium), chlorofluorocarbons (CFCs: CFC-11, CCl3F; CFC-12, CCl2F2; and CFC-113, C2Cl3F3), and solute tracers were used to investigate groundwater flow patterns near Lake Barco, a seepage lake in a mantled karst setting in northern Florida. Stable isotope data indicated that the groundwater downgradient from the lake contained 11–67% lake water leakage, with a limit of detection of lake water in groundwater of 4.3%. The mixing fractions of lake water leakage, which passed through organic-rich sediments in the lake bottom, were directly proportional to the observed methane concentrations and increased with depth in the groundwater flow system. In aerobic groundwater upgradient from Lake Barco, CFC-modeled recharge dates ranged from 1987 near the water table to the mid 1970s for water collected at a depth of 30 m below the water table. CFC-modeled recharge dates (based on CFC-12) for anaerobic groundwater downgradient from the lake ranged from the late 1950s to the mid 1970s and were consistent with tritium data. CFC-modeled recharge dates based on CFC-11 indicated preferential microbial degradation in anoxic waters. Vertical hydraulic conductivities, calculated using CFC-12 modeled recharge dates and Darcy's law, were 0.17, 0.033, and 0.019 m/d for the surficial aquifer, intermediate confining unit, and lake sediments, respectively. These conductivities agreed closely with those used in the calibration of a three-dimensional groundwater flow model for transient and steady state flow conditions.

A Black Hills-Madison Aquifer origin for Dakota Aquifer groundwater in northeastern Nebraska.

PubMed

Stotler, Randy; Harvey, F Edwin; Gosselin, David C

2010-01-01

Previous studies of the Dakota Aquifer in South Dakota attributed elevated groundwater sulfate concentrations to Madison Aquifer recharge in the Black Hills with subsequent chemical evolution prior to upward migration into the Dakota Aquifer. This study examines the plausibility of a Madison Aquifer origin for groundwater in northeastern Nebraska. Dakota Aquifer water samples were collected for major ion chemistry and isotopic analysis ((18)O, (2)H, (3)H, (14)C, (13)C, (34)S, (18)O-SO(4), (87)Sr, (37)Cl). Results show that groundwater beneath the eastern, unconfined portion of the study area is distinctly different from groundwater sampled beneath the western, confined portion. In the east, groundwater is calcium-bicarbonate type, with delta(18)O values (-9.6 per thousand to -12.4 per thousand) similar to local, modern precipitation (-7.4 per thousand to -10 per thousand), and tritium values reflecting modern recharge. In the west, groundwater is calcium-sulfate type, having depleted delta(18)O values (-16 per thousand to -18 per thousand) relative to local, modern precipitation, and (14)C ages 32,000 to more than 47,000 years before present. Sulfate, delta(18)O, delta(2)H, delta(34)S, and delta(18)O-SO(4) concentrations are similar to those found in Madison Aquifer groundwater in South Dakota. Thus, it is proposed that Madison Aquifer source water is also present within the Dakota Aquifer beneath northeastern Nebraska. A simple Darcy equation estimate of groundwater velocities and travel times using reported physical parameters from the Madison and Dakota Aquifers suggests such a migration is plausible. However, discrepancies between (14)C and Darcy age estimates indicate that (14)C ages may not accurately reflect aquifer residence time, due to mixtures of varying aged water.

Chemical Evolution of Groundwater Near a Sinkhole Lake, Northern Florida: 1. Flow Patterns, Age of Groundwater, and Influence of Lake Water Leakage

NASA Astrophysics Data System (ADS)

Katz, Brian G.; Lee, Terrie M.; Plummer, L. Niel; Busenberg, Eurybiades

1995-06-01

Leakage from sinkhole lakes significantly influences recharge to the Upper Floridan aquifer in poorly confined sediments in northern Florida. Environmental isotopes (oxygen 18, deuterium, and tritium), chlorofluorocarbons (CFCs: CFC-11, CCl3F; CFC-12, CCl2F2; and CFC-113, C2Cl3F3), and solute tracers were used to investigate groundwater flow patterns near Lake Barco, a seepage lake in a mantled karst setting in northern Florida. Stable isotope data indicated that the groundwater downgradient from the lake contained 11-67% lake water leakage, with a limit of detection of lake water in groundwater of 4.3%. The mixing fractions of lake water leakage, which passed through organic-rich sediments in the lake bottom, were directly proportional to the observed methane concentrations and increased with depth in the groundwater flow system. In aerobic groundwater upgradient from Lake Barco, CFC-modeled recharge dates ranged from 1987 near the water table to the mid 1970s for water collected at a depth of 30 m below the water table. CFC-modeled recharge dates (based on CFC-12) for anaerobic groundwater downgradient from the lake ranged from the late 1950s to the mid 1970s and were consistent with tritium data. CFC-modeled recharge dates based on CFC-11 indicated preferential microbial degradation in anoxic waters. Vertical hydraulic conductivities, calculated using CFC-12 modeled recharge dates and Darcy's law, were 0.17, 0.033, and 0.019 m/d for the surficial aquifer, intermediate confining unit, and lake sediments, respectively. These conductivities agreed closely with those used in the calibration of a three-dimensional groundwater flow model for transient and steady state flow conditions.

A simulation/optimization model for groundwater resources management in the Afram Plains area, Ghana

USGS Publications Warehouse

Yidana, S.M.

2008-01-01

A groundwater flow simulation model was developed using available hydrogeo logical data to A groundwater flow simulation model was developed using available hydrogeological data to describe groundwater flow in the Afram Plains area. A nonlinear optimization model was then developed and solved for the management of groundwater resources to meet irrigation and household needs. The objective was to maximize groundwater extraction for irrigation activities from the shallow aquifers of the southern Voltaian Sedimentary Basin that underly the area This would improve food security, raise the standard of living and ultimately alleviate poverty in the Afram Plains. The calibrated flow model is in tandem with the general hydrochemical evolution of groundwater in the area and fits the observed data with about a 98% degree of confidence. Groundwater resources may not be the limiting factor in the development of irrigated agriculture. Groundwater has tremendous potential to meet current and future irrigation needs. It was determined from this study that profit from maize irrigation in the Afram Plains area could rise from US$301, 000 in 2007 to over US$3.5 million by the end of the last management period (2013) as irrigation practice is improved, and the economic strength to increase the acreage for irrigation improves. Even with these margins of profit, the drawdown constraint was not reached in any of the management periods. It is expected that rechargefrom the irrigation water would reclaim the lost hydraulic head. The single significant constraint was the amount of land area that could be developed for irrigation in the area. The profit obtained per unit cubic meter of water used also improved over the same management period.

The stopped-drop method: a novel setup for containment-free and time-resolved measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiener, Andreas; Seifert, Soenke; Magerl, Andreas

2016-03-01

A novel setup for containment-free time-resolved experiments at a free-hanging drop is reported. Within a dead-time of 100 ms a drop of mixed reactant solutions is formed and the time evolution of a reaction can be followed from thereon by various techniques. As an example, a small-angle X-ray scattering study on the formation mechanism of EDTA-stabilized CdS both at a synchrotron and a laboratory X-ray source is presented here. While the evolution can be followed with one drop only at a synchrotron source, a stroboscopic mode with many drops is preferable for the laboratory source.

Mammalian evolution may not be strictly bifurcating.

PubMed

Hallström, Björn M; Janke, Axel

2010-12-01

The massive amount of genomic sequence data that is now available for analyzing evolutionary relationships among 31 placental mammals reduces the stochastic error in phylogenetic analyses to virtually zero. One would expect that this would make it possible to finally resolve controversial branches in the placental mammalian tree. We analyzed a 2,863,797 nucleotide-long alignment (3,364 genes) from 31 placental mammals for reconstructing their evolution. Most placental mammalian relationships were resolved, and a consensus of their evolution is emerging. However, certain branches remain difficult or virtually impossible to resolve. These branches are characterized by short divergence times in the order of 1-4 million years. Computer simulations based on parameters from the real data show that as little as about 12,500 amino acid sites could be sufficient to confidently resolve short branches as old as about 90 million years ago (Ma). Thus, the amount of sequence data should no longer be a limiting factor in resolving the relationships among placental mammals. The timing of the early radiation of placental mammals coincides with a period of climate warming some 100-80 Ma and with continental fragmentation. These global processes may have triggered the rapid diversification of placental mammals. However, the rapid radiations of certain mammalian groups complicate phylogenetic analyses, possibly due to incomplete lineage sorting and introgression. These speciation-related processes led to a mosaic genome and conflicting phylogenetic signals. Split network methods are ideal for visualizing these problematic branches and can therefore depict data conflict and possibly the true evolutionary history better than strictly bifurcating trees. Given the timing of tectonics, of placental mammalian divergences, and the fossil record, a Laurasian rather than Gondwanan origin of placental mammals seems the most parsimonious explanation.

Mammalian Evolution May not Be Strictly Bifurcating

PubMed Central

Hallström, Björn M.; Janke, Axel

2010-01-01

The massive amount of genomic sequence data that is now available for analyzing evolutionary relationships among 31 placental mammals reduces the stochastic error in phylogenetic analyses to virtually zero. One would expect that this would make it possible to finally resolve controversial branches in the placental mammalian tree. We analyzed a 2,863,797 nucleotide-long alignment (3,364 genes) from 31 placental mammals for reconstructing their evolution. Most placental mammalian relationships were resolved, and a consensus of their evolution is emerging. However, certain branches remain difficult or virtually impossible to resolve. These branches are characterized by short divergence times in the order of 1–4 million years. Computer simulations based on parameters from the real data show that as little as about 12,500 amino acid sites could be sufficient to confidently resolve short branches as old as about 90 million years ago (Ma). Thus, the amount of sequence data should no longer be a limiting factor in resolving the relationships among placental mammals. The timing of the early radiation of placental mammals coincides with a period of climate warming some 100–80 Ma and with continental fragmentation. These global processes may have triggered the rapid diversification of placental mammals. However, the rapid radiations of certain mammalian groups complicate phylogenetic analyses, possibly due to incomplete lineage sorting and introgression. These speciation-related processes led to a mosaic genome and conflicting phylogenetic signals. Split network methods are ideal for visualizing these problematic branches and can therefore depict data conflict and possibly the true evolutionary history better than strictly bifurcating trees. Given the timing of tectonics, of placental mammalian divergences, and the fossil record, a Laurasian rather than Gondwanan origin of placental mammals seems the most parsimonious explanation. PMID:20591845

Using 3D geological modelling and geochemical mixing models to characterise alluvial aquifer recharge sources in the upper Condamine River catchment, Queensland, Australia.

PubMed

Martinez, Jorge L; Raiber, Matthias; Cendón, Dioni I

2017-01-01

The influence of mountain front recharge on the water balance of alluvial valley aquifers located in upland catchments of the Condamine River basin in Queensland, Australia, is investigated through the development of an integrated hydrogeological framework. A combination of three-dimensional (3D) geological modelling, hydraulic gradient maps, multivariate statistical analyses and hydrochemical mixing calculations is proposed for the identification of hydrochemical end-members and quantification of the relative contributions of each end-member to alluvial aquifer recharge. The recognised end-members correspond to diffuse recharge and lateral groundwater inflows from three hydrostratigraphic units directly connected to the alluvial aquifer. This approach allows mapping zones of potential inter-aquifer connectivity and areas of groundwater mixing between underlying units and the alluvium. Mixing calculations using samples collected under baseflow conditions reveal that lateral contribution from a regional volcanic aquifer system represents the majority (41%) of inflows to the alluvial aquifer. Diffuse recharge contribution (35%) and inflow from two sedimentary bedrock hydrostratigraphic units (collectively 24%) comprise the remainder of major recharge sources. A detailed geochemical assessment of alluvial groundwater evolution along a selected flowpath of a representative subcatchment of the Condamine River basin confirms mixing as a key process responsible for observed spatial variations in hydrochemistry. Dissolution of basalt-related minerals and dolomite, CO 2 uptake, ion-exchange, precipitation of clay minerals, and evapotranspiration further contribute to the hydrochemical evolution of groundwater in the upland alluvial aquifer. This study highlights the benefits of undertaking an integrated approach that combines multiple independent lines of evidence. The proposed methods can be applied to investigate processes associated with inter-aquifer mixing, including groundwater contamination resulting from depressurisation of underlying geological units hydraulically connected to the shallower water reservoirs. Copyright © 2016 Elsevier B.V. All rights reserved.

Interests of long-term hydrogeological observatories for characterizing and modelling heterogeneous groundwater systems at multiple temporal and spatial scales: the example of Ploemeur, a crystalline rock aquifer (Brittany).

NASA Astrophysics Data System (ADS)

Bour, Olivier; Longuervergne, Laurent; Le Borgne, Tanguy; Lavenant, Nicolas; de Dreuzy, Jean-Raynald; Schuite, Jonathan; Labasque, Thierry; Aquilina, Luc; Davy, Philippe

2017-04-01

Characterizing groundwater flows and surface interactions in heterogeneous groundwater systems such as crystalline fractured rock is often extremely complex. In particular, hydraulic properties are highly variable while groundwater chemical properties may vary both in space and time, especially due to the impact of groundwater abstraction. Here, we show the interest of hydrological observatories and long-term monitoring for characterizing hydrological processes occurring in a crystalline rock aquifer. We present results from the site of Ploemeur (French Brittany) that belongs to the network of hydrogeological sites H+ and the research infrastructure OZCAR, and where interdisciplinary and integrated research at multiple temporal and spatial scales has been developed for almost twenty years. This outstandingly heterogeneous crystalline rock aquifer is also used for groundwater supply since 1991. In particular, we show how cross-borehole flowmeter tests, pumping tests and a frequency domain analysis of groundwater levels allow quantifying the hydraulic properties of the aquifer at different scales. In addition, groundwater temperature evolution was used as an excellent tracer for characterizing groundwater flow. At the site scale, measurements of ground surface deformation through long-base tiltmeters provide robust estimates of aquifer storage and allow identifying the active structures, including those acting during recharge process. Finally, a numerical model of the watershed scale that combines hydraulic data and groundwater ages confirms the geometry of this complex aquifer and the consistency of the different datasets. In parallel, this hydrological observatory is also used for developing hydrogeophysical methods and to characterize groundwater transport and biogeochemical reactivity in the sub-surface. The Ploemeur hydrogeological observatory is a good example of the interest of focusing research activities on a site during long-term as it provides a thorough understanding of both hydrological and biogeochemical processes that can be extended to many heterogeneous aquifers.

Influence of geology on groundwater-sediment interactions in arsenic enriched tectono-morphic aquifers of the Himalayan Brahmaputra river basin

NASA Astrophysics Data System (ADS)

Verma, Swati; Mukherjee, Abhijit; Mahanta, Chandan; Choudhury, Runti; Mitra, Kaushik

2016-09-01

The present study interprets the groundwater solute chemistry, hydrogeochemical evolution, arsenic (As) enrichment and aquifer characterization in Brahmaputra River Basin (BRB) involving three geologically and tectono-morphically distinct regions located in northeastern India. These study regions consist of the northwestern (NW) and the northern (N) region, both located along the western and eastern parts of Eastern Himalayas and the southern (S) region (near Indo-Burmese Range and Naga hills) of the Brahmaputra basin which show distinct tectonic settings and sediment provenances in the Himalayan orogenic belt. Stable isotopic composition (δ2H and δ18O) in groundwater suggests that some evaporation may have taken place through recharging of ground water in the study areas. The major-ion composition shows that groundwater composition of the NW and N parts are between Casbnd HCO3 and Casbnd Nasbnd HCO3 while the S-region is dominated by Nasbnd Casbnd HCO3 hydrochemical facies. The major mineralogical composition of aquifer sediments indicates the dominant presence of iron(Fe)-oxide and oxyhydroxides, mica (muscovite and biotite), feldspar, pyroxene, amphibole, abundance of quartz and clay minerals whereas clay is predominantly present in sediments of S-aquifers. These mafic minerals, aluminosilicates and clay minerals might offer available reactive surface for As-adsorption and co-precipitatation with amorphous Fe. These associated adsorbed and co-precipitated As might be released due to reductive dissolution of Fe-oxide and oxyhydroxides in groundwater. These minerals are assumed to be possible sources of As in groundwater. The stability diagrams of groundwater data suggest that solute might have been introduced into groundwater from weathering of K-feldspar, plagioclase, pyroxene of Himalayan rocks, the Siwalik Group and Eastern Syntaxes in NW and N-regions. However, basic cations might be derived from weathering of K-feldspar, plagioclase, pyroxene and olivine those being major constituents in a gabbroic complex (ophiolite) and basalt terrain in S-region. The aquifers of S-region are severely contaminated with dissolved As compared to NW and N regions. Almost more than 92% of groundwater samples in the southern part (maximum 5.53 μM or 415 μg/L) are enriched with As, which draws a distinct difference from the NW and N parts of BRB aquifers. The redox-sensitive solutes (i.e., Fe, Mn, HCO3- and TOC) are positively correlated with As in NW and N-parts; whereas EH shows negative to very weak positive correlation which suggests that a redox-dependent mobilization plays important role in As liberation in NW and N parts of the basin. However, As in southern aquifers is not showing any correlation or weak negative correlation with redox-sensitive solutes; suggesting that multiple reactions and hydrogeochemical processes and their interaction control As mobilization and fate in the S-region of BRB. The occurrence of high concentrations of arsenic in groundwater of Brahmaputra basin is described through a crustal recycling model and tectonic movement between the Indian-Eurasian plates and Burmese micro-continents. As-enriched groundwater in Himalayan foreland basin in the BRB is probably a result of crustal evolution through which As is subsequently mobilized from aquifer matrix to solution in groundwater by water-sediment reaction under favorable biogeochemical conditions. The results of the study indicate geological control (i.e. change in lithofacies, tectonic set-up) on groundwater chemistry and distribution of redox-sensitive solutes such as As.

Climate impact on groundwater systems: the past is the key to the future

NASA Astrophysics Data System (ADS)

van der Ploeg, Martine; Cendón, Dioni; Haldorsen, Sylvi; Chen, Jinyao; Gurdak, Jason; Tujchneider, Ofelia; Vaikmäe, Rein; Purtschert, Roland; Chkir Ben Jemâa, Najiba

2013-04-01

Groundwater is a significant part of the global hydrological cycle and supplies fresh drinking water to almost half of the world's population. While groundwater supplies are buffered against short-term effects of climate variability, they can be impacted over longer time scales through changes in precipitation, ,evaporation, recharge rate, melting of glaciers or permafrost, vegetation, and land-use. Moreover, uncontrolled groundwater extraction has and will lead to irreversible depletion of fresh water resources in many areas. The impact of climate variability and groundwater extraction on the resilience of groundwater systems is still not fully understood (Green et al. 2011). Groundwater stores environmental and climatic information acquired during the recharge process, which integrates different signals, like recharge temperature, origin of precipitation, and dissolved constituents. This information can be used to estimate palaeo recharge temperatures, palaeo atmospheric dynamics and residence time of groundwater within the aquifer (Stute et al. 1995, Clark and Fritz 1997, Collon et al. 2000, Edmunds et al. 2003, Cartwright et al. 2007, Kreuzer et al. 2009, Currell et al. 2010, Raidla et al. 2012, Salem et al. 2012). The climatic signals incorporated by groundwater during recharge have the potential to provide a regionally integrated proxy of climatic variations at the time of recharge. Groundwater palaeoclimate information is affected by diffusion-dispersion processes (Davison and Airey, 1982) and/or water-rock interaction (Clark and Fritz, 1997), making palaeoclimate information deduced from groundwater inherently a low resolution record. While the signal resolution can be limited, recharge follows major climatic events, and more importantly, shows how those aquifers and their associated recharge varies under climatic forcing. While the characterization of groundwater resources, surface-groundwater interactions and their link to the global water cycle are an important focus, little attention has been given to groundwater as a potential record of past climate variations. A groundwater system's history is vital to forecast its vulnerability under future and potentially adverse climatic changes. By processing groundwater information from vast regions and different continents, recharge and palaeoclimate can be correlated at a global scale. To successfully evaluate the sustainability of groundwater resources, "the past is the key to the future". To address the identified lack of palaeoclimatic data available from groundwater studies, a global collaboration has been set-up in 2011 called Groundwater@Global Palaeoclimate Signals (www.gw-gps.com), and has already more than 70 participants from 5 continents. Since 2012 G@GPS receives seed funding to support meetings by the International Geoscience Programme, the International Union for Quaternary Research and UNESCO-GRAPHIC International Hydrologic Project. This collaboration targets groundwater basins on five continents —Africa, America, Asia, Australia, Europe — containing vast groundwater resources with an estimated dependence of tens of millions of people. We will present G@GPS, show examples from groundwater basins, and discuss possibilities to integrate groundwater information from these basins. References Cartwright, I. et al. 2007. Consraining modern and historical recharge from bore hydrographs, 3H, 14C, and chloride concentrations: Applications to dual-porosity aquifers in dryland salinity areas, Murray Basin, Australia. J. Hydrol. 332: 69-92. Clark, I. and P. Fritz. 1997. Environmental isotopes in hydrogeology, Lewis Publishers. Collon, P. et al. 2000. 81Kr in the Great Artesian Basin, Australia: a new method for dating very old groundwater. Earth and Planetary Science Letters 182: 103-113. Currell, M. J. et al. 2010. Recharge history and controls on groundwater quality in the Yuncheng Basin, north China, J. Hydrol. 385: 216-229. Davison, M. R. and P. L. Airey. 1982. The effect of dispersion on the establishment of a paleoclimatic record from groundwater. J. Hydrol. 58: 131-147. Edmunds, W. M. et al. 2003. Groundwater evolution in the Continental Intercalaire aquifer of southern Algeria and Tunisia: trace element and isotopic indicators, Applied Geochemistry 18: 805-822. Green, T.R. et al. 2011. Beneath the surface of global change: Impacts of climate change on groundwater. J. Hydrol 405: 532-560. Kreuzer, A. M. et al. 2009. A record of temperature and monsoon intensity over the past 40 kyr from groundwater in the North China Plain, Chemical Geology 259: 168-180. Raidla, V., Kirsimäe, K., Vaikmäe, R., Kaup, E., and Martma, T., 2012, Carbon isotope systematics of the Cambrian-Vendian aquifer system in the northern Baltic Basin: Implications to the age and evolution of groundwater: Applied Geochemistry, v. 27(10), p. 2042-2052. Salem, S.B.H., Chkir, N., Zouari, K., Cognard-Plancq , A. L., Valles, V, and Marc, V., 2012, Natural and artificial recharge investigation in the Zéroud Basin,Central Tunisia: impact of Sidi Saad Dam storage. Environmental Earth Sciences, v., 66, p. 1099-1110. Stute M., Forster M., Frischkorn H., Serejo A., Clark J. F., Schlosser P., Broecker W. S., and Bonani G. (1995) Cooling of tropical Brazil (5 °C) during the Last Glacial Maximum. Science 269, 379-383.

Hydrogeochemical quality and suitability studies of groundwater in northern Bangladesh.

PubMed

Islam, M J; Hakim, M A; Hanafi, M M; Juraimi, Abdul Shukor; Aktar, Sharmin; Siddiqa, Aysha; Rahman, A K M Shajedur; Islam, M Atikul; Halim, M A

2014-07-01

Agriculture, rapid urbanization and geochemical processes have direct or indirect effects on the chemical composition of groundwater and aquifer geochemistry. Hydro-chemical investigations, which are significant for assessment of water quality, were carried out to study the sources of dissolved ions in groundwater of Dinajpur district, northern Bangladesh. The groundwater samplish were analyzed for physico-chemical properties like pH, electrical conductance, hardness, alkalinity, total dissolved solids and Ca2+, Mg2+, Na+, K+, CO3(2-), HCO3(-), SO4(2-) and Cl- ions, respectively. Based on the analyses, certain parameters like sodium adsorption ratio, soluble sodium percentage, potential salinity, residual sodium carbonate, Kelly's ratio, permeability index and Gibbs ratio were also calculated. The results showed that the groundwater of study area was fresh, slightly acidic (pH 5.3-6.4) and low in TDS (35-275 mg I(-1)). Ground water of the study area was found suitable for irrigation, drinking and domestic purposes, since most of the parameters analyzed were within the WHO recommended values for drinking water. High concentration of NO3- and Cl- was reported in areas with extensive agriculture and rapid urbanization. Ion-exchange, weathering, oxidation and dissolution of minerals were major geochemical processes governing the groundwater evolution in study area. Gibb's diagram showed that all the samples fell in the rock dominance field. Based on evaluation, it is clear that groundwater quality of the study area was suitable for both domestic and irrigation purposes.

The resolved history of galaxy evolution.

PubMed

Brinchmann, Jarle

2002-12-15

We briefly review the study of the evolution of galaxies from an observational point of view, with particular emphasis on the role of the Hubble Space Telescope in probing the evolution of the different morphological types of galaxy. We show how using the stellar mass of galaxies as a tracer of evolution can improve our understanding of the physical process taking place before turning our eyes towards the future and giving an overview of what we can expect from future advances in technology.

Remote Monitoring of Groundwater Overdraft Using GRACE and InSAR

NASA Astrophysics Data System (ADS)

Scher, C.; Saah, D.

2017-12-01

Gravity Recovery and Climate Experiment (GRACE) data paired with radar-derived analyses of volumetric changes in aquifer storage capacity present a viable technique for remote monitoring of aquifer depletion. Interferometric Synthetic Aperture Radar (InSAR) analyses of ground level subsidence can account for a significant portion of mass loss observed in GRACE data and provide information on point-sources of overdraft. This study summed one water-year of GRACE monthly mass change grids and delineated regions with negative water storage anomalies for further InSAR analyses. Magnitude of water-storage anomalies observed by GRACE were compared to InSAR-derived minimum volumetric changes in aquifer storage capacity as a result of measurable compaction at the surface. Four major aquifers were selected within regions where GRACE observed a net decrease in water storage (Central Valley, California; Mekong Delta, Vietnam; West Bank, occupied Palestinian Territory; and the Indus Basin, South Asia). Interferogram imagery of the extent and magnitude of subsidence within study regions provided estimates for net minimum volume of groundwater extracted between image acquisitions. These volumetric estimates were compared to GRACE mass change grids to resolve a percent contribution of mass change observed by GRACE likely due to groundwater overdraft. Interferograms revealed characteristic cones of depression within regions of net mass loss observed by GRACE, suggesting point-source locations of groundwater overdraft and demonstrating forensic potential for the use of InSAR and GRACE data in remote monitoring of aquifer depletion. Paired GRACE and InSAR analyses offer a technique to increase the spatial and temporal resolution of remote applications for monitoring groundwater overdraft in addition to providing a novel parameter - measurable vertical deformation at the surface - to global groundwater models.

Modeling Vegetation Growth Impact on Groundwater Recharge

NASA Astrophysics Data System (ADS)

Anurag, H.; Ng, G. H. C.; Tipping, R.

2017-12-01

Vegetation growth is affected by variability in climate and land-cover / land-use over a range of temporal and spatial scales. Vegetation also modifies water budget through interception and evapotranspiration and thus has a significant impact on groundwater recharge. Most groundwater recharge assessments represent vegetation using specified, static parameter, such as for leaf-area-index, but this neglects the effect of vegetation dynamics on recharge estimates. Our study addresses this gap by including vegetation growth in model simulations of recharge. We use NCAR's Community Land Model v4.5 with its BGC module (BGC is the new CLM4.5 biogeochemistry). It integrates prognostic vegetation growth with land-surface and subsurface hydrological processes and can thus capture the effect of vegetation on groundwater. A challenge, however, is the need to resolve uncertainties in model inputs ranging from vegetation growth parameters all the way down to the water table. We have compiled diverse data spanning meteorological inputs to subsurface geology and use these to implement ensemble model simulations to evaluate the possible effects of dynamic vegetation growth (versus specified, static vegetation parameterizations) on estimating groundwater recharge. We present preliminary results for select data-intensive test locations throughout the state of Minnesota (USA), which has a sharp east-west precipitation gradient that makes it an apt testbed for examining ecohydrologic relationships across different temperate climatic settings and ecosystems. Using the ensemble simulations, we examine the effect of seasonal to interannual variability of vegetation growth on recharge and water table depths, which has implications for predicting the combined impact of climate, vegetation, and geology on groundwater resources. Future work will include distributed model simulations over the entire state, as well as conditioning uncertain vegetation and subsurface parameters on remote sensing data and statewide water table records using data assimilation.

Geochemistry and the Understanding of Groundwater Systems

NASA Astrophysics Data System (ADS)

Glynn, P. D.; Plummer, L. N.; Weissmann, G. S.; Stute, M.

2009-12-01

Geochemical techniques and concepts have made major contributions to the understanding of groundwater systems. Advances continue to be made through (1) development of measurement and characterization techniques, (2) improvements in computer technology, networks and numerical modeling, (3) investigation of coupled geologic, hydrologic, geochemical and biologic processes, and (4) scaling of individual observations, processes or subsystem models into larger coherent model frameworks. Many applications benefit from progress in these areas, such as: (1) understanding paleoenvironments, in particular paleoclimate, through the use of groundwater archives, (2) assessing the sustainability (recharge and depletion) of groundwater resources, and (3) their vulnerability to contamination, (4) evaluating the capacity and consequences of subsurface waste isolation (e.g. geologic carbon sequestration, nuclear and chemical waste disposal), (5) assessing the potential for mitigation/transformation of anthropogenic contaminants in groundwater systems, and (6) understanding the effect of groundwater lag times in ecosystem-scale responses to natural events, land-use changes, human impacts, and remediation efforts. Obtaining “representative” groundwater samples is difficult and progress in obtaining “representative” samples, or interpreting them, requires new techniques in characterizing groundwater system heterogeneity. Better characterization and simulation of groundwater system heterogeneity (both physical and geochemical) is critical to interpreting the meaning of groundwater “ages”; to understanding and predicting groundwater flow, solute transport, and geochemical evolution; and to quantifying groundwater recharge and discharge processes. Research advances will also come from greater use and progress (1) in the application of environmental tracers to ground water dating and in the analysis of new geochemical tracers (e.g. compound specific isotopic analyses, noble gas isotopes, analyses of natural organic tracers), (2) in inverse geochemical and hydrological modeling, (3) in the understanding and simulation of coupled biological, geological, geochemical and hydrological processes, and (4) in the description and quantification of processes occurring at the boundaries of groundwater systems (e.g. unsaturated zone processes, groundwater/surface water interactions, impacts of changing geomorphology and vegetation). Improvements are needed in the integration of widely diverse information. Better techniques are needed to construct coherent conceptual frameworks from individual observations, simulated or reconstructed information, process models, and intermediate scale models. Iterating between data collection, interpretation, and the application of forward, inverse, and statistical modeling tools is likely to provide progress in this area. Quantifying groundwater system processes by using an open-system thermodynamic approach in a common mass- and energy-flow framework will also facilitate comparison and understanding of diverse processes.

Long-term groundwater storage changes and land subsidence development in the North China Plain (1971-2015)

NASA Astrophysics Data System (ADS)

Gong, Huili; Pan, Yun; Zheng, Longqun; Li, Xiaojuan; Zhu, Lin; Zhang, Chong; Huang, Zhiyong; Li, Zhiping; Wang, Haigang; Zhou, Chaofan

2018-04-01

The North China Plain (NCP) has been suffering from groundwater storage (GWS) depletion and land subsidence for a long period. This paper collects data on GWS changes and land subsidence from in situ groundwater-level measurements, literature, and satellite observations to provide an overview of the evolution of the aquifer system during 1971-2015 with a focus on the sub-regional variations. It is found that the GWS showed a prolonged declining rate of -17.8 ± 0.1 mm/yr during 1971-2015, with a negative correlation to groundwater abstraction before year 2000 and a positive correlation after 2000. Statistical correlations between subsidence rate and the GWS anomaly (GWSA), groundwater abstraction, and annual precipitation show that the land subsidence in three sub-regions (Beijing, Tianjin, and Hebei) represents different temporal variations due to varying driver factors. Continuous drought caused intensive GWS depletion (-76.1 ± 6.5 mm/yr) and land subsidence in Beijing during 1999-2012. Negative correlations between total groundwater abstraction and land subsidence exhibited after the 1980s indicate that it may be questionable to infer subsidence from regional abstraction data. Instead, the GWSA generally provides a reliable correlation with subsidence. This study highlights the spatio-temporal variabilities of GWS depletion and land subsidence in the NCP under natural and anthropogenic impacts, and the importance of GWS changes for understanding land subsidence development.

Groundwater Contamination by Uranium and Mercury at the Ridaura Aquifer (Girona, NE Spain)

PubMed Central

Navarro, Andrés; Font, Xavier; Viladevall, Manuel

2016-01-01

Elevated concentrations of uranium and mercury have been detected in drinking water from public supply and agricultural wells in alluvial and granitic aquifers of the Ridaura basin located at Catalan Coastal Ranges (CCR). The samples showed high concentrations of U above the U.S. standards and the World Health Organization regulations which set a maximum value of 30 µg/L. Further, high mercury concentrations above the European Drinking Water Standards (1 μg/L) were found. Spatial distribution of U in groundwater and geochemical evolution of groundwater suggest that U levels appear to be highest in granitic areas where groundwater has long residence times and a significant salinity. The presence of high U concentrations in alluvial groundwater samples could be associated with hydraulic connection through fractures between the alluvial system and deep granite system. According to this model, oxidizing groundwater moving through fractures in the leucocratic/biotitic granite containing anomalous U contents are the most likely to acquire high levels of U. The distribution of Hg showed concentrations above 1 μg/L in 10 alluvial samples, mainly located near the limit of alluvial aquifer with igneous rocks, which suggests a possible migration of Hg from granitic materials. Also, some samples showed Hg concentrations comprised between 0.9 and 1.5 μg/L, from wells located in agricultural areas. PMID:29051421

Groundwater Contamination by Uranium and Mercury at the Ridaura Aquifer (Girona, NE Spain).

PubMed

Navarro, Andrés; Font, Xavier; Viladevall, Manuel

2016-08-16

Elevated concentrations of uranium and mercury have been detected in drinking water from public supply and agricultural wells in alluvial and granitic aquifers of the Ridaura basin located at Catalan Coastal Ranges (CCR). The samples showed high concentrations of U above the U.S. standards and the World Health Organization regulations which set a maximum value of 30 µg/L. Further, high mercury concentrations above the European Drinking Water Standards (1 μg/L) were found. Spatial distribution of U in groundwater and geochemical evolution of groundwater suggest that U levels appear to be highest in granitic areas where groundwater has long residence times and a significant salinity. The presence of high U concentrations in alluvial groundwater samples could be associated with hydraulic connection through fractures between the alluvial system and deep granite system. According to this model, oxidizing groundwater moving through fractures in the leucocratic/biotitic granite containing anomalous U contents are the most likely to acquire high levels of U. The distribution of Hg showed concentrations above 1 μg/L in 10 alluvial samples, mainly located near the limit of alluvial aquifer with igneous rocks, which suggests a possible migration of Hg from granitic materials. Also, some samples showed Hg concentrations comprised between 0.9 and 1.5 μg/L, from wells located in agricultural areas.

Enhancing Groundwater Cost Estimation with the Interpolation of Water Tables across the United States

NASA Astrophysics Data System (ADS)

Rosli, A. U. M.; Lall, U.; Josset, L.; Rising, J. A.; Russo, T. A.; Eisenhart, T.

2017-12-01

Analyzing the trends in water use and supply across the United States is fundamental to efforts in ensuring water sustainability. As part of this, estimating the costs of producing or obtaining water (water extraction) and the correlation with water use is an important aspect in understanding the underlying trends. This study estimates groundwater costs by interpolating the depth to water level across the US in each county. We use Ordinary and Universal Kriging, accounting for the differences between aquifers. Kriging generates a best linear unbiased estimate at each location and has been widely used to map ground-water surfaces (Alley, 1993).The spatial covariates included in the universal Kriging were land-surface elevation as well as aquifer information. The average water table is computed for each county using block kriging to obtain a national map of groundwater cost, which we compare with survey estimates of depth to the water table performed by the USDA. Groundwater extraction costs were then assumed to be proportional to water table depth. Beyond estimating the water cost, the approach can provide an indication of groundwater-stress by exploring the historical evolution of depth to the water table using time series information between 1960 and 2015. Despite data limitations, we hope to enable a more compelling and meaningful national-level analysis through the quantification of cost and stress for more economically efficient water management.

Groundwater age for identification of baseline groundwater quality and impacts of land-use intensification - The National Groundwater Monitoring Programme of New Zealand

NASA Astrophysics Data System (ADS)

Morgenstern, Uwe; Daughney, Christopher J.

2012-08-01

SummaryWe identified natural baseline groundwater quality and impacts caused by land use intensification by relating groundwater chemistry with water age. Tritium, the most direct tracer for groundwater dating, including the time of water passage through the unsaturated zone, was overwhelmed over the recent decades by contamination from bomb-tritium from nuclear weapons testing in the early 1960s. In the Southern Hemisphere, this situation has changed now with the fading of the bomb-tritium, and tritium has become a tool for accurate groundwater dating. Tritium dating will become efficient also in the Northern Hemisphere over the next decade. Plotting hydrochemistry and field parameters versus groundwater age allowed us to identify those parameters that have increasing concentrations with age and are therefore from geological sources. These indicators for natural groundwater evolution are: Na, HCO3, SiO2, F, PO4, the redox-sensitive elements and compounds Fe, Mn, NH4, CH4, and pH and conductivity. In young groundwater that was recharged after the intensification of agriculture, nitrate, sulphate, CFC-11 and CFC-12, and pesticides are the most representative indicators for the impact of land-use intensification on groundwater quality, with 66% of the sites showing such an impact. Elevated concentrations of nitrate in oxic groundwater allowed us to reconstruct the timing and magnitude of the impact of land-use intensification on groundwater which in New Zealand occurred in two stages. Old pristine groundwater reflects the natural baseline quality. A transition to slightly elevated concentration due to low-intensity land-use was observed in groundwater recharged since around 1880. A sharp increase in nitrate and other agrochemicals due to high-intensity agriculture was observed in groundwater recharged since 1955. The threshold concentrations that distinguish natural baseline quality water from low-intensity land-use water, and low-intensity from high intensity land-use water, are 0.25 and 2.5 mg/L NO3-N, respectively. The change in groundwater quality from pristine baseline to low-intensity impact around 1880 coincides with the start of the meat export industry. The change in groundwater quality from low to high intensity landuse impact around 1955 coincides with the start of industrialised agriculture. No elevated levels of phosphate, a main compound in agricultural fertilisers and, together with nitrogen, a trigger of algae blooms in lakes, were found in young groundwater. This implies that fertiliser phosphate from non-point sources is still retained in the soil and has not yet reached the saturated groundwater systems. The source of elevated PO4, observed only in old groundwater, is therefore due purely to natural geochemical factors.

The Evolution of Groundwater Management Paradigms in Kansas, USA

NASA Astrophysics Data System (ADS)

Sophocleous, M. A.

2011-12-01

The purpose of this presentation is to trace the evolution of key water-related laws and management practices in Kansas, from the enactment of the Kansas Water Resources Appropriation Act of 1945 to the present, in order to highlight the state's efforts to create a more sustainable water future and in hopes that others will benefit from Kansas' experience. The 1945 Act provides the basic framework of water law (prior appropriation) in Kansas. Progression of groundwater management in the state encompasses local ground-water management districts (GMDs) and their water-management programs, minimum-streamflow and TMDL standards, water-use reporting and water metering programs, use of modified safe-yield policies in some GMDs, the subbasin water-resources-management program, the integrated resource planning/Aquifer Storage and Recovery project of the City of Wichita, the Central Kansas Water Bank, enhanced aquifer subunits management, and various water conservation programs. While these have all contributed to the slowing down of declines in groundwater levels in the High Plains aquifer and in associated ecosystems, they have not yet succeeded in halting those declines. Based on the assumption that the different management approaches have to operate easily within the prevailing water rights and law framework to succeed, a number of steps are suggested here that may help further halt the declines of the High Plains aquifer. These include eliminating the "use it or lose it" maxim in the prior-appropriation framework, broadening the definition of "beneficial use," regulating domestic and other "exempt" wells, encouraging voluntary "sharing the shortage" agreements, and determining to what extent water rights may be regulated in the public interest without a compensable "taking." Further necessary measures include determining to what extent water-rights holders might be subjected to reasonable dictates without having the security of their rights altered.

Groundwater Withdrawals under Drought: Reconciling GRACE and Models in the United States High Plains Aquifer

NASA Astrophysics Data System (ADS)

Nie, W.; Zaitchik, B. F.; Kumar, S.; Rodell, M.

2017-12-01

Advanced Land Surface Models (LSM) offer a powerful tool for studying and monitoring hydrological variability. Highly managed systems, however, present a challenge for these models, which typically have simplified or incomplete representations of human water use, if the process is represented at all. GRACE, meanwhile, detects the total change in water storage, including change due to human activities, but does not resolve the source of these changes. Here we examine recent groundwater declines in the US High Plains Aquifer (HPA), a region that is heavily utilized for irrigation and that is also affected by episodic drought. To understand observed decline in groundwater (well observation) and terrestrial water storage (GRACE) during a recent multi-year drought, we modify the Noah-MP LSM to include a groundwater pumping irrigation scheme. To account for seasonal and interannual variability in active irrigated area we apply a monthly time-varying greenness vegetation fraction (GVF) dataset to the model. A set of five experiments were performed to study the impact of irrigation with groundwater withdrawal on the simulated hydrological cycle of the HPA and to assess the importance of time-varying GVF when simulating drought conditions. The results show that including the groundwater pumping irrigation scheme in Noah-MP improves model agreement with GRACE mascon solutions for TWS and well observations of groundwater anomaly in the southern HPA, including Texas and Kansas, and that accounting for time-varying GVF is important for model realism under drought. Results for the HPA in Nebraska are mixed, likely due to misrepresentation of the recharge process. This presentation will highlight the value of the GRACE constraint for model development, present estimates of the relative contribution of climate variability and irrigation to declining TWS in the HPA under drought, and identify opportunities to integrate GRACE-FO with models for water resource monitoring in heavily irrigated regions.

Data-Conditioned Distributions of Groundwater Recharge Under Climate Change Scenarios

NASA Astrophysics Data System (ADS)

McLaughlin, D.; Ng, G. C.; Entekhabi, D.; Scanlon, B.

2008-12-01

Groundwater recharge is likely to be impacted by climate change, with changes in precipitation amounts altering moisture availability and changes in temperature affecting evaporative demand. This could have major implications for sustainable aquifer pumping rates and contaminant transport into groundwater reservoirs in the future, thus making predictions of recharge under climate change very important. Unfortunately, in dry environments where groundwater resources are often most critical, low recharge rates are difficult to resolve due to high sensitivity to modeling and input errors. Some recent studies on climate change and groundwater have considered recharge using a suite of general circulation model (GCM) weather predictions, an obvious and key source of uncertainty. This work extends beyond those efforts by also accounting for uncertainty in other land-surface model inputs in a probabilistic manner. Recharge predictions are made using a range of GCM projections for a rain-fed cotton site in the semi-arid Southern High Plains region of Texas. Results showed that model simulations using a range of unconstrained literature-based parameter values produce highly uncertain and often misleading recharge rates. Thus, distributional recharge predictions are found using soil and vegetation parameters conditioned on current unsaturated zone soil moisture and chloride concentration observations; assimilation of observations is carried out with an ensemble importance sampling method. Our findings show that the predicted distribution shapes can differ for the various GCM conditions considered, underscoring the importance of probabilistic analysis over deterministic simulations. The recharge predictions indicate that the temporal distribution (over seasons and rain events) of climate change will be particularly critical for groundwater impacts. Overall, changes in recharge amounts and intensity were often more pronounced than changes in annual precipitation and temperature, thus suggesting high susceptibility of groundwater systems to future climate change. Our approach provides a probabilistic sensitivity analysis of recharge under potential climate changes, which will be critical for future management of water resources.

Sources of water pollution and evolution of water quality in the Wuwei basin of Shiyang river, Northwest China.

PubMed

Ma, Jinzhu; Ding, Zhenyu; Wei, Guoxiao; Zhao, Hua; Huang, Tianming

2009-02-01

Based on surveys and chemical analyses, we performed a case study of the surface water and groundwater quality in the Wuwei basin, in order to understand the sources of water pollution and the evolution of water quality in Shiyang river. Concentrations of major chemical elements in the surface water were related to the distance downstream from the source of the river, with surface water in the upstream reaches of good quality, but the river from Wuwei city to the Hongya reservoir was seriously polluted, with a synthetic pollution index of 25. Groundwater quality was generally good in the piedmont with dominant bicarbonate and calcium ions, but salinity was high and nitrate pollution occurs in the northern part of the basin. Mineralization of the groundwater has changed rapidly during the past 20 years. There are 23 wastewater outlets that discharge a total of 22.4 x 10(6)m(3)y(-1) into the river from Wuwei city, which, combined with a reduction of inflow water, were found to be the major causes of water pollution. Development of fisheries in the Hongya reservoir since 2000 has also contributed to the pollution. The consumption of water must be decreased until it reaches the sustainable level permitted by the available resources in the whole basin, and discharge of wastes must also be drastically reduced.

Complex surface deformation monitoring and mechanism inversion over Qingxu-Jiaocheng, China with multi-sensor SAR images

NASA Astrophysics Data System (ADS)

Liu, Yuanyuan; Zhao, Chaoying; Zhang, Qin; Yang, Chengsheng

2018-02-01

Qingxu-Jiaocheng, China has been suffering severe land subsidence along with the development of ground fissure, which are controlled by local fault and triggered by groundwater withdrawal. With multi-sensor SAR images, we study the spatiotemporal evolution of ground deformation over Qingxu-Jiaocheng with an IPTA InSAR technique and assess the role of groundwater withdrawal to the observed deformation. Discrete GPS measurements are applied to verify the InSAR results. The RMSE of the differences between InSAR and GPS, i.e. ALOS and GPS and Envisat and GPS, are 5.7 mm and 6.3 mm in the LOS direction, respectively. The east-west and vertical components of the observed deformation from 2007 to 2010 are decomposed by using descending-track Envisat and ascending-track ALOS interferograms, indicating that the east-west component cannot be neglected when the deformation is large or the ground fissure is active. Four phases of land subsidence in the study region are successfully retrieved, and its spatiotemporal evolution is quantitatively analyzed. Lastly, a flat lying sill model with distributed contractions is implemented to model the InSAR deformation over Qingxu-Jiaocheng, which manifests that the ground deformation is mainly caused by groundwater withdrawal. This research provides new insights into the land subsidence monitoring and its mechanism inversion over Qingxu-Jiaocheng region.

Temporally resolved diagnosis of an atmospheric-pressure pulse-modulated argon surface wave plasma by optical emission spectroscopy

NASA Astrophysics Data System (ADS)

Chen, Chuan-Jie; Li, Shou-Zhe; Zhang, Jialiang; Liu, Dongping

2018-01-01

A pulse-modulated argon surface wave plasma generated at atmospheric pressure is characterized by means of temporally resolved optical emission spectroscopy (OES). The temporal evolution of the gas temperature, the electron temperature and density, the radiative species of atomic Ar, and the molecular band of OH(A) and N2(C) are investigated experimentally by altering the instantaneous power, pulse repetitive frequency, and duty ratio. We focused on the physical phenomena occurring at the onset of the time-on period and after the power interruption at the start of the time-off period. Meanwhile, the results are discussed qualitatively for an in-depth insight of its dynamic evolution.

Snake mitochondrial genomes: phylogenetic relationships and implications of extended taxon sampling for interpretations of mitogenomic evolution

PubMed Central

2010-01-01

Background Snake mitochondrial genomes are of great interest in understanding mitogenomic evolution because of gene duplications and rearrangements and the fast evolutionary rate of their genes compared to other vertebrates. Mitochondrial gene sequences have also played an important role in attempts to resolve the contentious phylogenetic relationships of especially the early divergences among alethinophidian snakes. Two recent innovative studies found dramatic gene- and branch-specific relative acceleration in snake protein-coding gene evolution, particularly along internal branches leading to Serpentes and Alethinophidia. It has been hypothesized that some of these rate shifts are temporally (and possibly causally) associated with control region duplication and/or major changes in ecology and anatomy. Results The near-complete mitochondrial (mt) genomes of three henophidian snakes were sequenced: Anilius scytale, Rhinophis philippinus, and Charina trivirgata. All three genomes share a duplicated control region and translocated tRNALEU, derived features found in all alethinophidian snakes studied to date. The new sequence data were aligned with mt genome data for 21 other species of snakes and used in phylogenetic analyses. Phylogenetic results agreed with many other studies in recovering several robust clades, including Colubroidea, Caenophidia, and Cylindrophiidae+Uropeltidae. Nodes within Henophidia that have been difficult to resolve robustly in previous analyses remained uncompellingly resolved here. Comparisons of relative rates of evolution of rRNA vs. protein-coding genes were conducted by estimating branch lengths across the tree. Our expanded sampling revealed dramatic acceleration along the branch leading to Typhlopidae, particularly long rRNA terminal branches within Scolecophidia, and that most of the dramatic acceleration in protein-coding gene rate along Serpentes and Alethinophidia branches occurred before Anilius diverged from other alethinophidians. Conclusions Mitochondrial gene sequence data alone may not be able to robustly resolve basal divergences among alethinophidian snakes. Taxon sampling plays an important role in identifying mitogenomic evolutionary events within snakes, and in testing hypotheses explaining their origin. Dramatic rate shifts in mitogenomic evolution occur within Scolecophidia as well as Alethinophidia, thus falsifying the hypothesis that these shifts in snakes are associated exclusively with evolution of a non-burrowing lifestyle, macrostomatan feeding ecology and/or duplication of the control region, both restricted to alethinophidians among living snakes. PMID:20055998

Effect of the environment on the hydrochemical characteristics of an alluvial aquifer following an exceptional multiyear drought (Mediterranean seashore, herault, France): Part II— Climatology and agronomy

NASA Astrophysics Data System (ADS)

Grillot, Jean-Claude; Chaffaut, Isabelle; Razack, Moumtaz

1988-04-01

The hydrochemical evolution of an alluvial groundwater located along the Mediterranean seashore is analyzed with respect to its agricultural and climatic environment, including degree of saturation of the soil; types of cultures, chemical fertilizers and phytosanitary treatments; selective irrigations of the cultivated areas; precipitations. It is shown that the environmental effect on the groundwater's vulnerability depends on two groups of factors: 1. Transfers from surface to groundwater of nitrates, chlorides, sulfates, and potassium, which are governed by: (a) the climatic conditions before the agricultural activities begin, (b) the kinds of agricultural activities and their distribution in time with respect to a given climatic context. Phenomena of retention and/or rapid diffusion are related to the sedimentary heterogeneities of the reservoir and to the differences of ternperatures between irrigation waters and precipitations.

The role of wellbore remediation on the evolution of groundwater quality from CO₂ and brine leakage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

Long-term storage of CO₂ in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO₂ mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strongmore » correlation between cumulative injected CO₂ mass and maximum plume pH volumes and a positive correlation between CO₂ flux, cumulative injected CO₂, and plume recovery times, with secondary dependence on permeability.« less

The role of wellbore remediation on the evolution of groundwater quality from CO₂ and brine leakage

DOE PAGES

Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

2014-12-31

Long-term storage of CO₂ in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO₂ mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strongmore » correlation between cumulative injected CO₂ mass and maximum plume pH volumes and a positive correlation between CO₂ flux, cumulative injected CO₂, and plume recovery times, with secondary dependence on permeability.« less

Multi-scale groundwater flow modeling during temperate climate conditions for the safety assessment of the proposed high-level nuclear waste repository site at Forsmark, Sweden

NASA Astrophysics Data System (ADS)

Joyce, Steven; Hartley, Lee; Applegate, David; Hoek, Jaap; Jackson, Peter

2014-09-01

Forsmark in Sweden has been proposed as the site of a geological repository for spent high-level nuclear fuel, to be located at a depth of approximately 470 m in fractured crystalline rock. The safety assessment for the repository has required a multi-disciplinary approach to evaluate the impact of hydrogeological and hydrogeochemical conditions close to the repository and in a wider regional context. Assessing the consequences of potential radionuclide releases requires quantitative site-specific information concerning the details of groundwater flow on the scale of individual waste canister locations (1-10 m) as well as details of groundwater flow and composition on the scale of groundwater pathways between the facility and the surface (500 m to 5 km). The purpose of this article is to provide an illustration of multi-scale modeling techniques and the results obtained when combining aspects of local-scale flows in fractures around a potential contaminant source with regional-scale groundwater flow and transport subject to natural evolution of the system. The approach set out is novel, as it incorporates both different scales of model and different levels of detail, combining discrete fracture network and equivalent continuous porous medium representations of fractured bedrock.

Mapping potential zones for groundwater recharge and its evaluation in arid environments using a GIS approach: Case study of North Gafsa Basin (Central Tunisia)

NASA Astrophysics Data System (ADS)

Mokadem, Naziha; Boughariou, Emna; Mudarra, Matías; Ben Brahim, Fatma; Andreo, Bartolome; Hamed, Younes; Bouri, Salem

2018-05-01

With the progressive evolution of industrial sector, agricultural, urbanization, population and drinking water supply, the water demand continuously increases which necessitates the planning of groundwater recharge particularly in arid and semi-arid regions. This paper gives a comprehensive review of various recharges studies in the North Gafsa basin (South Tunisia). This latter is characterized by a natural groundwater recharge that is deeply affected by the lack of precipitations. The aim of this study is to determine the recharge potential zones and to quantify (or estimate) the rainfall recharge of the shallow aquifers. The mapping of the potential recharge zones was established in North Gafsa basin, using geological and hydrological parameters such as slope, lithology, topography and stream network. Indeed, GIS provide tools to reclassify these input layers to produce the final map of groundwater potential zones of the study area. The final output map reveals two distinct zones representing moderate and low groundwater potential recharge. Recharge estimations were based on the four methods: (1) Chloride Method, (2) ERAS Method, (3) DGRE coefficient and (4) Fersi equations. Therefore, the overall results of the different methods demonstrate that the use of the DGRE method applying on the potential zones is more validated.

Influence of geochemical processes on hydrochemistry and irrigation suitability of groundwater in part of semi-arid Deccan Plateau, India

NASA Astrophysics Data System (ADS)

Vasu, Duraisamy; Singh, Surendra Kumar; Tiwary, Pramod; Sahu, Nisha; Ray, Sanjay Kumar; Butte, Pravin; Duraisami, Veppangadu Perumal

2017-11-01

Major ion geochemistry was used to characterise the chemical composition of groundwater in part of semi-arid Deccan plateau region to understand the geochemical evolution and to evaluate the groundwater quality for irrigation. The study area comprises peninsular gneissic complex of Archean age, younger granites and basaltic alluvium. Forty-nine georeferenced groundwater samples were collected and analysed for major ions. The ionic sequence based on relative proportions was Na+ > Mg2+ > Ca2+ > SO4 2- > HCO3 - > Cl- > CO3 2- > BO3 3- > K+. High Na+, Mg2+ and Ca2+ were generally associated with basaltic alluvial formation, whereas pH, electrical conductivity (EC) and total dissolved salts (TDS) were found to be higher in granitic formations. High standard deviation for EC, TDS, Na+, Ca2+ and Mg2+ indicated the dispersion of ionic concentration throughout the study area. Four major hydrochemical facies identified were Na-Mg-HCO3 type; Mg-Na-HCO3 type; Na-Mg-Ca-SO4 and Mg-Na-Ca-SO4 type. The graphical plots indicated that the groundwater chemistry was influenced by rock-water interaction, silicate weathering and reverse ion exchange. Sodium-dominated waters might have impeded the hydraulic properties of soils as a result of long-term irrigation.

Phylogenomics resolves the evolutionary chronicle of our squirting closest relatives.

PubMed

Giribet, Gonzalo

2018-04-27

A recent paper in BMC Biology has resolved the family relationships of sea squirts, one of our closest invertebrate relatives, by using a large phylogenomic data set derived from available genomes and newly generated transcriptomes. The work confirms previous ideas that ascidians (the sea squirts) are not monophyletic, as they include some pelagic jelly-like relatives, and proposes a chronogram for a group that has been difficult to resolve due to their accelerated genome evolution.See research article: https://bmcbiol.biomedcentral.com/articles/10.1186/s12915-018-0499-2.

Use of induced polarization to characterize the hydrogeologic framework of the zone of surface‐water/groundwater exchange at the Hanford 300 Area, WA

USGS Publications Warehouse

Slater, Lee; Ntarlagiannis, Dimitrios; Day-Lewis, Frederick D.; Mwakanyamale, Kisa; Lane, John W.; Ward, Andy; Versteeg, Roelof J.

2010-01-01

An extensive continuous waterborne electrical imaging (CWEI) survey was conducted along the Columbia River corridor adjacent to the U.S. Department of Energy (DOE) Hanford 300 Area, WA, in order to improve the conceptual model for exchange between surface water and U‐contaminated groundwater. The primary objective was to determine spatial variability in the depth to the Hanford‐Ringold (H‐R) contact, an important lithologic boundary that limits vertical transport of groundwater along the river corridor. Resistivity and induced polarization (IP) measurements were performed along six survey lines parallel to the shore (each greater than 2.5 km in length), with a measurement recorded every 0.5–3.0 m depending on survey speed, resulting in approximately 65,000 measurements. The H‐R contact was clearly resolved in images of the normalized chargeability along the river corridor due to the large contrast in surface area (hence polarizability) of the granular material between the two lithologic units. Cross sections of the lithologic structure along the river corridor reveal a large variation in the thickness of the overlying Hanford unit (the aquifer through which contaminated groundwater discharges to the river) and clearly identify locations along the river corridor where the underlying Ringold unit is exposed to the riverbed. Knowing the distribution of the Hanford and Ringold units along the river corridor substantially improves the conceptual model for the hydrogeologic framework regulating U exchange between groundwater and Columbia River water relative to current models based on projections of data from boreholes on land into the river.

Coral proxy record of decadal-scale reduction in base flow from Moloka'i, Hawaii

USGS Publications Warehouse

Prouty, Nancy G.; Jupiter, Stacy D.; Field, Michael E.; McCulloch, Malcolm T.

2009-01-01

Groundwater is a major resource in Hawaii and is the principal source of water for municipal, agricultural, and industrial use. With a growing population, a long-term downward trend in rainfall, and the need for proper groundwater management, a better understanding of the hydroclimatological system is essential. Proxy records from corals can supplement long-term observational networks, offering an accessible source of hydrologic and climate information. To develop a qualitative proxy for historic groundwater discharge to coastal waters, a suite of rare earth elements and yttrium (REYs) were analyzed from coral cores collected along the south shore of Moloka'i, Hawaii. The coral REY to calcium (Ca) ratios were evaluated against hydrological parameters, yielding the strongest relationship to base flow. Dissolution of REYs from labradorite and olivine in the basaltic rock aquifers is likely the primary source of coastal ocean REYs. There was a statistically significant downward trend (−40%) in subannually resolved REY/Ca ratios over the last century. This is consistent with long-term records of stream discharge from Moloka'i, which imply a downward trend in base flow since 1913. A decrease in base flow is observed statewide, consistent with the long-term downward trend in annual rainfall over much of the state. With greater demands on freshwater resources, it is appropriate for withdrawal scenarios to consider long-term trends and short-term climate variability. It is possible that coral paleohydrological records can be used to conduct model-data comparisons in groundwater flow models used to simulate changes in groundwater level and coastal discharge.

Assessing the cost of groundwater pollution: the case of diffuse agricultural pollution in the Upper Rhine valley aquifer.

PubMed

Rinaudo, J-D; Arnal, C; Blanchin, R; Elsass, P; Meilhac, A; Loubier, S

2005-01-01

This paper presents an assessment of the costs of diffuse groundwater pollution by nitrates and pesticides for the industrial and the drinking water sectors in the Upper Rhine valley, France. Pollution costs which occurred between 1988 and 2002 are described and assessed using the avoidance cost method. Geo-statistical methods (kriging) are then used to construct three scenarios of nitrate concentration evolution. The economic consequences of each scenario are then assessed. The estimates obtained are compared with the results of a contingent valuation study carried out in the same study area ten years earlier.

Using Bayesian methods to predict climate impacts on groundwater availability and agricultural production in Punjab, India

NASA Astrophysics Data System (ADS)

Russo, T. A.; Devineni, N.; Lall, U.

2015-12-01

Lasting success of the Green Revolution in Punjab, India relies on continued availability of local water resources. Supplying primarily rice and wheat for the rest of India, Punjab supports crop irrigation with a canal system and groundwater, which is vastly over-exploited. The detailed data required to physically model future impacts on water supplies agricultural production is not readily available for this region, therefore we use Bayesian methods to estimate hydrologic properties and irrigation requirements for an under-constrained mass balance model. Using measured values of historical precipitation, total canal water delivery, crop yield, and water table elevation, we present a method using a Markov chain Monte Carlo (MCMC) algorithm to solve for a distribution of values for each unknown parameter in a conceptual mass balance model. Due to heterogeneity across the state, and the resolution of input data, we estimate model parameters at the district-scale using spatial pooling. The resulting model is used to predict the impact of precipitation change scenarios on groundwater availability under multiple cropping options. Predicted groundwater declines vary across the state, suggesting that crop selection and water management strategies should be determined at a local scale. This computational method can be applied in data-scarce regions across the world, where water resource management is required to resolve competition between food security and available resources in a changing climate.

Investigating low flow process controls, through complex modelling, in a UK chalk catchment

NASA Astrophysics Data System (ADS)

Lubega Musuuza, Jude; Wagener, Thorsten; Coxon, Gemma; Freer, Jim; Woods, Ross; Howden, Nicholas

2017-04-01

The typical streamflow response of Chalk catchments is dominated by groundwater contributions due the high degree of groundwater recharge through preferential flow pathways. The groundwater store attenuates the precipitation signal, which causes a delay between the corresponding high and low extremes in the precipitation and the stream flow signals. Streamflow responses can therefore be quite out of phase with the precipitation input to a Chalk catchment. Therefore characterising such catchment systems, including modelling approaches, clearly need to reproduce these percolation and groundwater dominated pathways to capture these dominant flow pathways. The simulation of low flow conditions for chalk catchments in numerical models is especially difficult due to the complex interactions between various processes that may not be adequately represented or resolved in the models. Periods of low stream flows are particularly important due to competing water uses in the summer, including agriculture and water supply. In this study we apply and evaluate the physically-based Pennstate Integrated Hydrologic Model (PIHM) to the River Kennet, a sub-catchment of the Thames Basin, to demonstrate how the simulations of a chalk catchment are improved by a physically-based system representation. We also use an ensemble of simulations to investigate the sensitivity of various hydrologic signatures (relevant to low flows and droughts) to the different parameters in the model, thereby inferring the levels of control exerted by the processes that the parameters represent.

Evolution model of δ³⁴S and δ¹⁸O in dissolved sulfate in volcanic fan aquifers from recharge to coastal zone and through the Jakarta urban area, Indonesia.

PubMed

Hosono, Takahiro; Delinom, Robert; Nakano, Takanori; Kagabu, Makoto; Shimada, Jun

2011-06-01

The sources of sulfate in an aquifer system, and its formation/degradation via biogeochemical reactions, were investigated by determining sulfate isotope ratios (δ³⁴S(SO₄) and δ¹⁸O(SO₄) in dissolved sulfate in groundwater from the Jakarta Basin. The groundwater flow paths, water ages, and geochemical features are well known from previous studies, providing a framework for the groundwater chemical and isotopic data, which is supplemented with data for spring water, river water, hot spring water, seawater, detergents, and fertilizers within the basin. The sulfate isotope composition of groundwater samples varied widely from -2.9‰ to +33.4‰ for δ³⁴S(SO₄) and +4.9‰ to +17.8‰ for δ¹⁸O(SO₄) and changed systematically along its flow direction from the mountains north to the coastal area. The groundwater samples were classified into three groups showing (1) relatively low and narrow δ(34)S(SO₄) (+2.3‰ to +7.6‰) with low and varied δ¹⁸O(SO₄) (+4.9‰ to +12.9‰) compositions, (2) high and varied δ³⁴S(SO₄) (+10.2‰ to +33.4‰) with high δ¹⁸O(SO₄) (+12.4‰ to +17.3‰) compositions, and (3) low δ³⁴S(SO₄) (< +6.1‰) with high δ¹⁸O(SO₄) (up to +17.8‰) compositions. These three types of groundwater were observed in the terrestrial unconfined aquifer, the coastal unconfined and confined aquifers, and the terrestrial confined aquifer, respectively. A combination of field measurements, concentrations, and previously determined δ¹⁵N(NO₃) data, showed that the observed isotopic heterogeneity was mainly the result of contributions of pollutants from domestic sewage in the rural area, mixing of seawater sulfate that had experienced previous bacterial sulfate reduction in the coastal area, and isotopic fractionation during the formation of sulfate through bacterial disproportionation of elemental sulfur. Our results clearly support the hypothesis that human impacts are important factors in understanding the sulfur cycle in present-day subsurface environments. A general model of sulfate isotopic evolution along with groundwater flow has rarely been proposed, due to the complicated hydrogeological research setting that causes varied isotope ratios, although its understanding has recently received great attention. This pioneer study on a simple volcanic fan aquifer system with a well-understood groundwater flow mechanism provides a useful model for future studies. Copyright © 2011 Elsevier B.V. All rights reserved.

Time-Resolved In Situ Measurements During Rapid Alloy Solidification: Experimental Insight for Additive Manufacturing

NASA Astrophysics Data System (ADS)

McKeown, Joseph T.; Zweiacker, Kai; Liu, Can; Coughlin, Daniel R.; Clarke, Amy J.; Baldwin, J. Kevin; Gibbs, John W.; Roehling, John D.; Imhoff, Seth D.; Gibbs, Paul J.; Tourret, Damien; Wiezorek, Jörg M. K.; Campbell, Geoffrey H.

2016-03-01

Additive manufacturing (AM) of metals and alloys is becoming a pervasive technology in both research and industrial environments, though significant challenges remain before widespread implementation of AM can be realized. In situ investigations of rapid alloy solidification with high spatial and temporal resolutions can provide unique experimental insight into microstructure evolution and kinetics that are relevant for AM processing. Hypoeutectic thin-film Al-Cu and Al-Si alloys were investigated using dynamic transmission electron microscopy to monitor pulsed-laser-induced rapid solidification across microsecond timescales. Solid-liquid interface velocities measured from time-resolved images revealed accelerating solidification fronts in both alloys. The observed microstructure evolution, solidification product, and presence of a morphological instability at the solid-liquid interface in the Al-4 at.%Cu alloy are related to the measured interface velocities and small differences in composition that affect the thermophysical properties of the alloys. These time-resolved in situ measurements can inform and validate predictive modeling efforts for AM.

Time-Resolved In Situ Measurements During Rapid Alloy Solidification: Experimental Insight for Additive Manufacturing

DOE PAGES

McKeown, Joseph T.; Zweiacker, Kai; Liu, Can; ...

2016-01-27

In research and industrial environments, additive manufacturing (AM) of metals and alloys is becoming a pervasive technology, though significant challenges remain before widespread implementation of AM can be realized. In situ investigations of rapid alloy solidification with high spatial and temporal resolutions can provide unique experimental insight into microstructure evolution and kinetics that are relevant for AM processing. Hypoeutectic thin-film Al–Cu and Al–Si alloys were investigated using dynamic transmission electron microscopy to monitor pulsed-laser-induced rapid solidification across microsecond timescales. Solid–liquid interface velocities measured from time-resolved images revealed accelerating solidification fronts in both alloys. We observed microstructure evolution, solidification product, andmore » presence of a morphological instability at the solid–liquid interface in the Al–4 at.%Cu alloy are related to the measured interface velocities and small differences in composition that affect the thermophysical properties of the alloys. These time-resolved in situ measurements can inform and validate predictive modeling efforts for AM.« less

The effects of urbanization on groundwater quantity and quality in the Zahedan aquifer, southeast Iran

USGS Publications Warehouse

Khazaei, E.; Mackay, R.; Warner, J.W.

2004-01-01

This paper investigates the impacts of urban growth on groundwater quality and quantity in the Zahedan aquifer, which is the sole source of water supply for the city of Zahedan, Iran. The investigation is based on the collection of available historical data, supplemented by field and laboratory investigations. Groundwater levels in 40 wells were measured in December 2000. In addition, 102 water samples were taken in two periods during November and December 2000. Of these, 43 samples were analyzed for major ions, 32 samples were analyzed for nitrogen and phosphorus and the remainder for bacteriological contamination. The water level data show that there has been a general decline since 1977 due to over-abstraction. The magnitude of this decline has reached about 20 m in some places. However, in one area over the same period, a rise of about 3 m has been observed. This occurs as a result of the local hydrogeological conditions of shallow bedrock and relatively low permeability materials down stream of this area that limits the flow of groundwater towards the northeastern part of the aquifer. The general fall in groundwater levels has been accompanied by a change in the direction of the groundwater flow and an overall reduction of the areal extent of the saturated region of the aquifer. The city now has a serious problem such that even if the abstracted groundwater is rationed, water is not available for long periods because the demand far exceeds the supply. The heavy impact of urbanization on the groundwater quality is shown through the observed high nitrate (up to 295 mg/l as nitrate) and high phosphorus values (about 0.1 mg/l as P). Significant changes in the chloride concentration are also observed in two areas: increasing from 100 mg/l to 1,600 mg/l and from 2,000 mg/l to 4,000 mg/l, respectively. Furthermore, the bacteriological investigations show that 33 percent of the 27 collected groundwater samples are positive for total coliform and 11 percent of the samples contained fecal coliforms indicating that local sources are strongly influencing the observed chemical data. Greater depths to groundwater reduce the observation of coliform contamination. In general, the unplanned urban development in Zahedan has significantly degraded the region's water resources and significant actions such as upgrading the sewage waste disposal system, locating other sources of water supply, and strict groundwater management will all be needed to resolve the problems that have arisen.

Groundwater nitrate concentration evolution under climate change and agricultural adaptation scenarios: Prince Edward Island, Canada

NASA Astrophysics Data System (ADS)

Paradis, Daniel; Vigneault, Harold; Lefebvre, René; Savard, Martine M.; Ballard, Jean-Marc; Qian, Budong

2016-03-01

Nitrate (N-NO3) concentration in groundwater, the sole source of potable water in Prince Edward Island (PEI, Canada), currently exceeds the 10 mg L-1 (N-NO3) health threshold for drinking water in 6 % of domestic wells. Increasing climatic and socio-economic pressures on PEI agriculture may further deteriorate groundwater quality. This study assesses how groundwater nitrate concentration could evolve due to the forecasted climate change and its related potential changes in agricultural practices. For this purpose, a tridimensional numerical groundwater flow and mass transport model was developed for the aquifer system of the entire Island (5660 km2). A number of different groundwater flow and mass transport simulations were made to evaluate the potential impact of the projected climate change and agricultural adaptation. According to the simulations for year 2050, N-NO3 concentration would increase due to two main causes: (1) the progressive attainment of steady-state conditions related to present-day nitrogen loadings, and (2) the increase in nitrogen loadings due to changes in agricultural practices provoked by future climatic conditions. The combined effects of equilibration with loadings, climate and agricultural adaptation would lead to a 25 to 32 % increase in N-NO3 concentration over the Island aquifer system. The change in groundwater recharge regime induced by climate change (with current agricultural practices) would only contribute 0 to 6 % of that increase for the various climate scenarios. Moreover, simulated trends in groundwater N-NO3 concentration suggest that an increased number of domestic wells (more than doubling) would exceed the nitrate drinking water criteria. This study underlines the need to develop and apply better agricultural management practices to ensure sustainability of long-term groundwater resources. The simulations also show that observable benefits from positive changes in agricultural practices would be delayed in time due to the slow dynamics of nitrate transport within the aquifer system.

Towards sustainable groundwater management in Karst aquifers in semi-arid environments: Central West Bank, Palestine

NASA Astrophysics Data System (ADS)

Jebreen, H.; Banning, A.; Wohnlich, S.

2017-12-01

The Central West Bank (CWB) is characterized by karstified carbonate aquifers in the semiarid climate zone, where groundwater resources are frequently threatened by overexploitation and pollution. Despite often limited system knowledge, quantitative and qualitative factors such as groundwater recharge rate, aquifer parameters, flow and transport dynamics, anthropogenic impacts, and groundwater vulnerability need to be assessed. Therefore, sustainable groundwater use in the CWB is of critical importance. In the present study, we explore the scale of the groundwater problems in CWB as well as the possibility of sustainable management through different scenarios: 1) Managed aquifer recharge using a water balance model, stable isotopes (2H & 18O) and chloride mass balance, 2) Geochemical evolution and renewability of groundwater, and 3) Anthropogenic impacts. A total of 20 spring water samples were collected and analyzed for pH, electrical conductivity, total dissolved solids (TDS), hardness, major-ion chemistry (Cl-, HCO3-, SO42-, Na+, K+, Ca2+ and Mg2+), trace elements (Li, Be, Al, Ba, Tl, Pb, Bi, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Rb, Sr, Mo, Ag and Cd), microbiological data (total and fecal coliforms bacteria), and stable isotopes (2H & 18O). The results show a spatialized recharge rate, which ranges from 111-211 mm/year, representing 17-33 % of the long-term mean annual rainfall. The mean annual actual evapotranspiration was about 19-37 % of precipitation. The chemical composition of groundwater of the study area is strongly influenced by rock-water interaction, dissolution and deposition of carbonate and silicate minerals. Stable isotopes show that precipitation is the source of recharge to the groundwater system. All analyzed spring waters are suitable for irrigation but not for drinking purposes. This studýs results can serve as a basis for decision makers, and will lead to an increased understanding of the sustainable management of the Central West Bank aquifers.

The Evolution of Cooperation in Managed Groundwater Systems: An Agent-Based Modelling Approach

NASA Astrophysics Data System (ADS)

Castilla Rho, J. C.; Mariethoz, G.; Rojas, R. F.; Andersen, M. S.; Kelly, B. F.; Holley, C.

2014-12-01

Human interactions with groundwater systems often exhibit complex features that hinder the sustainable management of the resource. This leads to costly and persistent conflicts over groundwater at the catchment scale. One possible way to address these conflicts is by gaining a better understanding of how social and groundwater dynamics coevolve using agent-based models (ABM). Such models allow exploring 'bottom-up' solutions (i.e., self-organised governance systems), where the behaviour of individual agents (e.g., farmers) results in the emergence of mutual cooperation among groundwater users. There is significant empirical evidence indicating that this kind of 'bottom-up' approach may lead to more enduring and sustainable outcomes, compared to conventional 'top-down' strategies such as centralized control and water right schemes (Ostrom 1990). New modelling tools are needed to study these concepts systematically and efficiently. Our model uses a conceptual framework to study cooperation and the emergence of social norms as initially proposed by Axelrod (1986), which we adapted to groundwater management. We developed an ABM that integrates social mechanisms and the physics of subsurface flow. The model explicitly represents feedback between groundwater conditions and social dynamics, capturing the spatial structure of these interactions and the potential effects on cooperation levels in an agricultural setting. Using this model, we investigate a series of mechanisms that may trigger norms supporting cooperative strategies, which can be sustained and become stable over time. For example, farmers in a self-monitoring community can be more efficient at achieving the objective of sustainable groundwater use than government-imposed regulation. Our coupled model thus offers a platform for testing new schemes promoting cooperation and improved resource use, which can be used as a basis for policy design. Importantly, we hope to raise awareness of agent-based modelling as a new tool for studying complex human-groundwater systems.

Iron-sulfur mineralogy of Mars - Magmatic evolution and chemical weathering products

NASA Technical Reports Server (NTRS)

Burns, Roger G.; Fisher, Duncan S.

1990-01-01

Models are developed for the magmatic evolution and the oxidative weathering of sulfide minerals on Mars, based on petrogenetic associations among komatiitic rock types, Viking geochemical data, SNC meteorites, and terrestrial Fi-Ni deposits. The weathering model was tested by exposing komatiitic pyrrhotites and olivines to sulfuric acid solutions, with or without dissolved ferric iron, and identifying the reaction products by Moessbauer spectroscopy. The results suggest that, on Mars, acidic groundwater has induced oxidative weathering of pyrrhotite, yielding FeS2 and then FeOOH.

Estimation and impact assessment of input and parameter uncertainty in predicting groundwater flow with a fully distributed model

NASA Astrophysics Data System (ADS)

Touhidul Mustafa, Syed Md.; Nossent, Jiri; Ghysels, Gert; Huysmans, Marijke

2017-04-01

Transient numerical groundwater flow models have been used to understand and forecast groundwater flow systems under anthropogenic and climatic effects, but the reliability of the predictions is strongly influenced by different sources of uncertainty. Hence, researchers in hydrological sciences are developing and applying methods for uncertainty quantification. Nevertheless, spatially distributed flow models pose significant challenges for parameter and spatially distributed input estimation and uncertainty quantification. In this study, we present a general and flexible approach for input and parameter estimation and uncertainty analysis of groundwater models. The proposed approach combines a fully distributed groundwater flow model (MODFLOW) with the DiffeRential Evolution Adaptive Metropolis (DREAM) algorithm. To avoid over-parameterization, the uncertainty of the spatially distributed model input has been represented by multipliers. The posterior distributions of these multipliers and the regular model parameters were estimated using DREAM. The proposed methodology has been applied in an overexploited aquifer in Bangladesh where groundwater pumping and recharge data are highly uncertain. The results confirm that input uncertainty does have a considerable effect on the model predictions and parameter distributions. Additionally, our approach also provides a new way to optimize the spatially distributed recharge and pumping data along with the parameter values under uncertain input conditions. It can be concluded from our approach that considering model input uncertainty along with parameter uncertainty is important for obtaining realistic model predictions and a correct estimation of the uncertainty bounds.

Quantification of groundwater recharge in urban environments.

PubMed

Tubau, Isabel; Vázquez-Suñé, Enric; Carrera, Jesús; Valhondo, Cristina; Criollo, Rotman

2017-08-15

Groundwater management in urban areas requires a detailed knowledge of the hydrogeological system as well as the adequate tools for predicting the amount of groundwater and water quality evolution. In that context, a key difference between urban and natural areas lies in recharge evaluation. A large number of studies have been published since the 1990s that evaluate recharge in urban areas, with no specific methodology. Most of these methods show that there are generally higher rates of recharge in urban settings than in natural settings. Methods such as mixing ratios or groundwater modeling can be used to better estimate the relative importance of different sources of recharge and may prove to be a good tool for total recharge evaluation. However, accurate evaluation of this input is difficult. The objective is to present a methodology to help overcome those difficulties, and which will allow us to quantify the variability in space and time of the recharge into aquifers in urban areas. Recharge calculations have been initially performed by defining and applying some analytical equations, and validation has been assessed based on groundwater flow and solute transport modeling. This methodology is applicable to complex systems by considering temporal variability of all water sources. This allows managers of urban groundwater to evaluate the relative contribution of different recharge sources at a city scale by considering quantity and quality factors. The methodology is applied to the assessment of recharge sources in the Barcelona city aquifers. Copyright © 2017 Elsevier B.V. All rights reserved.

The Evolution of Human Intelligence and the Coefficient of Additive Genetic Variance in Human Brain Size

ERIC Educational Resources Information Center

Miller, Geoffrey F.; Penke, Lars

2007-01-01

Most theories of human mental evolution assume that selection favored higher intelligence and larger brains, which should have reduced genetic variance in both. However, adult human intelligence remains highly heritable, and is genetically correlated with brain size. This conflict might be resolved by estimating the coefficient of additive genetic…

Organic chemical evolution

NASA Technical Reports Server (NTRS)

Chang, S.

1981-01-01

The course of organic chemical evolution preceding the emergence of life on earth is discussed based on evidence of processes occurring in interstellar space, the solar system and the primitive earth. Following a brief review of the equilibrium condensation model for the origin and evolution of the solar system, consideration is given to the nature and organic chemistry of interstellar clouds, comets, Jupiter, meteorites, Venus and Mars, and the prebiotic earth. Major issues to be resolved in the study of organic chemical evolution on earth are identified regarding condensation and accretion in the solar nebula, early geological evolution, the origin and evolution of the atmosphere, organic production rates, organic-inorganic interactions, environmental fluctuations, phase separation and molecular selectivity.

Constraints in cancer evolution.

PubMed

Venkatesan, Subramanian; Birkbak, Nicolai J; Swanton, Charles

2017-02-08

Next-generation deep genome sequencing has only recently allowed us to quantitatively dissect the extent of heterogeneity within a tumour, resolving patterns of cancer evolution. Intratumour heterogeneity and natural selection contribute to resistance to anticancer therapies in the advanced setting. Recent evidence has also revealed that cancer evolution might be constrained. In this review, we discuss the origins of intratumour heterogeneity and subsequently focus on constraints imposed upon cancer evolution. The presence of (1) parallel evolution, (2) convergent evolution and (3) the biological impact of acquiring mutations in specific orders suggest that cancer evolution may be exploitable. These constraints on cancer evolution may help us identify cancer evolutionary rule books, which could eventually inform both diagnostic and therapeutic approaches to improve survival outcomes. © 2017 The Author(s); published by Portland Press Limited on behalf of the Biochemical Society.

Characterization of Land Surfaces with Satellite-borne Sensor

NASA Astrophysics Data System (ADS)

Qiao, Y.

Hot groundwater is a kind of valuable natural resources to be explored utilized. Shanxi Province, located in the eastern Loess Plateau of China, is rich in geothermal resources, most of which was found in irrigation well drilling or geological survey. Basic study is weak. Now new developed Remote Sensing technique provides geothermal study with an advanced way. Air-RS information of thermal infrared and dada from thermal channel of Meteorological Landset AVHRR has been used widely. A thermal infrared channel (TM6) was installed in the U.S. second Landset, Its resolving power of space is as high as 120m, 10 times more than one of AVHRR. A Landset earth recourses launched by China and Brazil (CBERS-1) in 1999, including a spectrum of thermal infrared. It is paid a great interested and attention to survey geothermal resources using thermal infrared. This article is a brief introduction of finding hot groundwater with on the bases of differences of thermal radiation of objects reflected by thermal infrared in the Landset, and treated with HIS colors changes. This study provides an advanced way widely used to exploit hot groundwater and to promote the development of tourism and geothermal medical in China.

Assessment of Hydrochemistry for Use as Groundwater Age Proxy

NASA Astrophysics Data System (ADS)

Beyer, Monique; Daughney, Chris; Jackson, Bethanna; Morgenstern, Uwe

2015-04-01

Groundwater dating can aid groundwater management by providing information on groundwater flow, mixing and residence-, storage- and exposure-time of groundwater in the subsurface. Groundwater age can be inferred from environmental tracers, such as tritium, SF6 and CFCs (CFC-12, -11 and -113). These tracers often need to be applied complementarily, since they have a restricted application range and ambiguous age interpretations can be obtained. Some tracers, such as the CFCs, will become of limited use in near future, due their fading out atmospheric concentration. As a consequence of these limitations, there is a need for additional, complementary tracers to ensure groundwater dating in future. Hydrochemistry parameters, such as the concentrations and ratios of major ions, appear to be promising candidates. Hydro-chemistry data at various spatial and temporal scales are widely available through local, regional and national groundwater monitoring programmes. Promising relationships between hydrochemistry parameters and groundwater residence time or aquifer depth have been found in near piston flow environments. However, most groundwater samples contain proportions of different aged water, due to mixing of water emerging from different flow lines during sampling or discharge, which complicates the establishment of hydrochemistry-time relationships in these environments. In this study, we establish a framework to infer hydrochemistry - (residence) time relationships in non-piston flow environments by using age information inferred from environmental tracer data and lumped parameter models (LPMs). The approach involves the generation of major element concentrations by 'classic' Monte Carlo simulation and subsequent comparison of simulated and observed element concentrations by means of an objective function to establish hydrochemistry-time relationships. The framework also allows for assessment of the hydrochemistry-time relationships with regards to their potential to further constrain the (often ambiguous) age interpretation inferred from environmental tracers. We apply the framework to age information (inferred from SF6 and tritium) and hydrochemistry observations from a groundwater system in the Wellington Region, New Zealand. We found that the strongest hydrochemistry-time relationships can be established for the concentration of silica, calcium, sodium and total dissolved solids. Mineral weathering kinetics inferred from these relationships agree with mineral weathering kinetics found in other groundwater environments. For 4 out of 9 sites, with previously ambiguous age interpretation, ambiguity can be resolved by using the established hydrochemistry-time relationships. There does not appear to be one hydrochemistry parameter which can constrain age information at all sites, but different parameters work at different sites. Further study is vital to better understand under what conditions hydrochemistry can be used as a complementary or alternative groundwater age tracer in various groundwater environments. Acknowledgements This study is part of a PhD supported by GNS Science as part of the Smart Aquifer Characterization program funded by the New Zealand Ministry for Science and Innovation (http://www.smart-project.info/).

High resolution spatial and temporal evolution of dissolved gases in groundwater during a controlled natural gas release experiment.

PubMed

Cahill, Aaron G; Parker, Beth L; Mayer, Bernhard; Mayer, K Ulrich; Cherry, John A

2018-05-01

Fugitive gas comprised primarily of methane (CH 4 ) with traces of ethane and propane (collectively termed C 1-3 ) may negatively impact shallow groundwater when unintentionally released from oil and natural gas wells. Currently, knowledge of fugitive gas migration, subsurface source identification and oxidation potential in groundwater is limited. To advance understanding, a controlled release experiment was performed at the Borden Research Aquifer, Canada, whereby 51m 3 of natural gas was injected into an unconfined sand aquifer over 72days with dissolved gases monitored over 323days. During active gas injection, a dispersed plume of dissolved C 1-3 evolved in a depth discrete and spatially complex manner. Evolution of the dissolved gas plume was driven by free-phase gas migration controlled by small-scale sediment layering and anisotropy. Upon cessation of gas injection, C 1-3 concentrations increased to the greatest levels observed, particularly at 2 and 6m depths, reaching up to 31.5, 1.5 and 0.1mg/L respectively before stabilizing and persisting. At no time did groundwater become fully saturated with natural gas at the scale of sampling undertaken. Throughout the experiment the isotopic composition of injected methane (δ 13 C of -42.2‰) and the wetness parameter (i.e. the ratio of C 1 to C 2+ ) constituted excellent tracers for the presence of fugitive gas at concentrations >2mg/L. At discrete times C 1-3 concentrations varied by up to 4 orders of magnitude over 8m of aquifer thickness (e.g. from <0.01 to 30mg/L for CH 4 ), while some groundwater samples lacked evidence of fugitive gas, despite being within 10m of the injection zone. Meanwhile, carbon isotope ratios of dissolved CH 4 showed no evidence of oxidation. Our results show that while impacts to aquifers from a fugitive gas event are readily detectable at discrete depths, they are spatially and temporally variable and dissolved methane has propensity to persist. Copyright © 2017 Elsevier B.V. All rights reserved.

Effect of Submarine Groundwater Discharge on Relict Arctic Submarine Permafrost and Gas Hydrate

NASA Astrophysics Data System (ADS)

Frederick, J. M.; Buffett, B. A.

2014-12-01

Permafrost-associated gas hydrate deposits exist at shallow depths within the sediments of the circum-Arctic continental shelves. Degradation of this shallow water reservoir has the potential to release large quantities of methane gas directly to the atmosphere. Gas hydrate stability and the permeability of the shelf sediments to gas migration is closely linked with submarine permafrost. Submarine permafrost extent depends on several factors, such as the lithology, sea level variations, mean annual air temperature, ocean bottom water temperature, geothermal heat flux, and the salinity of the pore water. The salinity of the pore water is especially relevant because it partially controls the freezing point for both ice and gas hydrate. Measurements of deep pore water salinity are few and far between, but show that deep off-shore sediments are fresh. Deep freshening has been attributed to large-scale topographically-driven submarine groundwater discharge, which introduces fresh terrestrial groundwater into deep marine sediments. We investigate the role of submarine ground water discharge on the salinity field and its effects on the seaward extent of relict submarine permafrost and gas hydrate stability on the Arctic shelf with a 2D shelf-scale model based on the finite volume method. The model tracks the evolution of the temperature, salinity, and pressure fields given imposed boundary conditions, with latent heat of water ice and hydrate formation included. The permeability structure of the sediments is coupled to changes in permafrost. Results show that pore fluid is strongly influenced by the permeability variations imposed by the overlying permafrost layer. Groundwater discharge tends to travel horizontally off-shore beneath the permafrost layer and the freshwater-saltwater interface location displays long timescale transient behavior that is dependent on the groundwater discharge strength. The seaward permafrost extent is in turn strongly influenced by the salinity field and location of the freshwater-saltwater transition. Our results suggest that the role of salt transport and its effect on permafrost evolution can provide context for the interpretation of recent permafrost maps and methane observations in the Arctic.

Combined use of groundwater dating, chemical, and isotopic analyses to resolve the history and fate of nitrate contamination in two agricultural watersheds, Atlantic coastal plain, Maryland

USGS Publications Warehouse

Böhlke, J.K.; Denver, J.M.

1995-01-01

The history and fate of groundwater nitrate (NO3−) contamination were compared in 2 small adjacent agricultural watersheds in the Atlantic coastal plain by combined use of chronologic (CCl2F2, 3H), chemical (dissolved solids, gases), and isotopic (δ15N,δ13C, δ34S) analyses of recharging groundwaters, discharging groundwaters, and surface waters. The results demonstrate the interactive effects of changing agricultural practices, groundwater residence times, and local geologic features on the transfer of NO3− through local flow systems. Recharge dates of groundwaters taken in 1990–1992 from the surficial aquifer in the Chesterville Branch and Morgan Creek watersheds near Locust Grove, Maryland, ranged from pre-1940 to the late 1980’s. When corrected for localized denitrification by use of dissolved gas concentrations, the dated waters provide a 40-year record of the recharge rate of NO3−, which increased in both watersheds by a factor of 3–6, most rapidly in the 1970's. The increase in groundwater NO3− over time was approximately proportional to the documented increase in regional N fertilizer use, and could be accounted for by oxidation and leaching of about 20–35% of the fertilizer N. Groundwaters discharging upward beneath streams in both watersheds had measured recharge dates from pre-1940 to 1975, while chemical data for second-order reaches of the streams indicated average groundwater residence times in the order of 20+ years. At the time of the study, NO3− discharge rates were less than NO3− recharge rates for at least two reasons: (1) discharge of relatively old waters with low initial NO3− concentrations, and (2) local denitrification. In the Chesterville Branch watershed, groundwaters remained oxic throughout much of the surficial aquifer and discharged relatively unaltered to the stream, which had a relatively high NO3−concentration (9–10 mg/L as N). In the Morgan Creek watershed, groundwaters were largely reduced and denitrified before discharging to the stream, which had a relatively low NO3−concentration (2–3 mg/L as N). Chemical and isotopic data indicate that quantitative denitrification occurred within buried calcareous glauconitic marine sediments that are present at relatively shallow depths beneath the Morgan Creek watershed. NO3− removal by forests, wetlands, and shallow organic-rich soils in near-stream environments was largely avoided by groundwaters that followed relatively deep flow paths before converging and discharging rapidly upward to the streams.

Resolving phylogenetic incongruence to articulate homology and phenotypic evolution: a case study from Nematoda

PubMed Central

Ragsdale, Erik J.; Baldwin, James G.

2010-01-01

Modern morphology-based systematics, including questions of incongruence with molecular data, emphasizes analysis over similarity criteria to assess homology. Yet detailed examination of a few key characters, using new tools and processes such as computerized, three-dimensional ultrastructural reconstruction of cell complexes, can resolve apparent incongruence by re-examining primary homologies. In nematodes of Tylenchomorpha, a parasitic feeding phenotype is thus reconciled with immediate free-living outgroups. Closer inspection of morphology reveals phenotypes congruent with molecular-based phylogeny and points to a new locus of homology in mouthparts. In nematode models, the study of individually homologous cells reveals a conserved modality of evolution among dissimilar feeding apparati adapted to divergent lifestyles. Conservatism of cellular components, consistent with that of other body systems, allows meaningful comparative morphology in difficult groups of microscopic organisms. The advent of phylogenomics is synergistic with morphology in systematics, providing an honest test of homology in the evolution of phenotype. PMID:20106846

Metagenomic Insights into Evolution of a Heavy Metal-Contaminated Groundwater Microbial Community

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hemme, Christopher L.; Deng, Ye; Gentry, Terry J.

2010-02-15

Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents (~;;50 years) have resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying ?- and ?-proteobacterial populations. The resulting community is over-abundant inmore » key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could be a key mechanism in rapidly responding and adapting to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.« less

Metagenomic insights into evolution of heavy metal-contaminated groundwater microbial community

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hemme, C.L.; Deng, Y.; Gentry, T.J.

2010-07-01

Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents ({approx}50 years) has resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying {gamma}- and {beta}-proteobacterial populations. The resulting community is overabundant inmore » key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could have a key function in rapid response and adaptation to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.« less

Reversible adsorption and flushing of arsenic in a shallow, Holocene aquifer of Bangladesh

PubMed Central

Radloff, Kathleen A.; Zheng, Yan; Stute, Martin; Weinman, Beth; Bostick, Benjamin; Mihajlov, Ivan; Bounds, Margaret; Rahman, M. Moshiur; Huq, M. Rezaul; Ahmed, Kazi M.; Schlosser, Peter; van Geen, Alexander

2015-01-01

The spatial heterogeneity of dissolved arsenic (As) concentrations in shallow groundwater of the Bengal Basin has been attributed to transport of As (and reactive carbon) from external sources or to the release of As from within grey sand formations. We explore the latter scenario in this detailed hydrological and geochemical study along a 300 m transect of a shallow aquifer extending from a groundwater recharge area within a sandy channel bar to its discharge into a nearby stream. Within the 10–20 m depth range, groundwater ages along the transect determined by the 3H–3He method increase from <10 yr in the recharge area to a maximum of 40 yr towards the stream. Concentrations of groundwater As within the same grey sands increase from 10 to 100 to ∼500 µg/L along this transect. Evidence of reversible adsorption of As between the groundwater and sediment was obtained from a series of push–pull experiments, traditional batch adsorption experiments, and the accidental flooding of a shallow monitoring well. Assuming reversible adsorption and a distribution coefficient, Kd, of 0.15–1.5 L/kg inferred from these observations, a simple flushing model shows that the increase in As concentrations with depth and groundwater age at this site, and at other sites in the Bengal and Red River Basins, can be attributed to the evolution of the aquifer over 100–1000 years as aquifer sands are gradually flushed of their initial As content. A wide range of As concentrations can thus be maintained in groundwater with increases with depth governed by the history of flushing and local recharge rates, without external inputs of reactive carbon or As from other sources. PMID:28458447

Patterns and rates of ground-water flow on Long Island, New York

USGS Publications Warehouse

Buxton, Herbert T.; Modica, Edward

1992-01-01

Increased ground-water contamination from human activities on Long Island has prompted studies to define the pattern and rate of ground-water movement. A two-dimensional, fine-mesh, finite-element model consisting of 11,969 nodes and 22,880 elements was constructed to represent ground-water flow along a north-south section through central Long Island. The model represents average hydrologic conditions within a corridor approximately 15 miles wide. The model solves discrete approximations of both the potential and stream functions. The resulting flownet depicts flow paths and defines the vertical distribution of flow within the section. Ground-water flow rates decrease with depth. Sixty-two percent of the water flows no deeper than the upper glacial (water-table) aquifer, 38 percent enters the underlying Magothy aquifer, and only 3.1 percent enters the Lloyd aquifer. The limiting streamlines for flow to the Magothy and Lloyd aquifers indicate that aquifer recharge areas are narrow east-west bands through the center of the island. The recharge area of the Magothy aquifer is only 5.4 miles wide; that of the Lloyd aquifer is less than 0.5 miles. The distribution of ground-water traveltime and a flownet are calculated from model results; both are useful in the investigation of contaminant transport or the chemical evolution of ground water within the flow system. A major discontinuity in traveltime occurs across the streamline which separates the flow subsystems of the two confined aquifers. Water that reaches the Lloyd aquifer attains traveltimes as high as 10,000 years, whereas water that has not penetrated deeper than the Magothy aquifer attains traveltimes of only 2,000 years. The finite-element approach used in this study is particularly suited to ground-water systems that have complex hydrostratigraphy and cross-sectional symmetry.

Investigation of the geochemical evolution of groundwater under agricultural land: A case study in northeastern Mexico

NASA Astrophysics Data System (ADS)

Ledesma-Ruiz, Rogelio; Pastén-Zapata, Ernesto; Parra, Roberto; Harter, Thomas; Mahlknecht, Jürgen

2015-02-01

Zona Citrícola is an important area for Mexico due to its citriculture activity. Situated in a sub-humid to humid climate adjacent to the Sierra Madre Oriental, this valley hosts an aquifer system that represents sequences of shales, marls, conglomerates, and alluvial deposits. Groundwater flows from mountainous recharge areas to the basin-fill deposits and provides base flows to supply drinking water to the adjacent metropolitan area of Monterrey. Recent studies examining the groundwater quality of the study area urge the mitigation of groundwater pollution. The objective of this study was to characterize the physical and chemical properties of the groundwater and to assess the processes controlling the groundwater's chemistry. Correlation was used to identify associations among various geochemical constituents. Factor analysis was applied to identify the water's chemical characteristics that were responsible for generating most of the variability within the dataset. Hierarchical cluster analysis was employed in combination with a post-hoc analysis of variance to partition the water samples into hydrochemical water groups: recharge waters (Ca-HCO3), transition zone waters (Ca-HCO3-SO4 to Ca-SO4-HCO3) and discharge waters (Ca-SO4). Inverse geochemical models of these groups were developed and constrained using PHREEQC to elucidate the chemical reactions controlling the water's chemistry between an initial (recharge) and final water. The primary reactions contributing to salinity were the following: (1) water-rock interactions, including the weathering of evaporitic rocks and dedolomitization; (2) dissolution of soil gas carbon dioxide; and (3) input from animal/human wastewater and manure in combination with by denitrification processes. Contributions from silicate weathering to salinity ranged from less important to insignificant. The findings suggest that it may not be cost-effective to regulate manure application to mitigate groundwater pollution.

Groundwater modelling as a tool for the European Water Framework Directive (WFD) application: The Llobregat case

NASA Astrophysics Data System (ADS)

Vázquez-Suñé, E.; Abarca, E.; Carrera, J.; Capino, B.; Gámez, D.; Pool, M.; Simó, T.; Batlle, F.; Niñerola, J. M.; Ibáñez, X.

The European Water Framework Directive establishes the basis for Community action in the field of water policy. Water authorities in Catalonia, together with users are designing a management program to improve groundwater status and to assess the impact of infrastructures and city-planning activities on the aquifers and their associated natural systems. The objective is to describe the role of groundwater modelling in addressing the issues raised by the Water Framework Directive, and its application to the Llobregat Delta, Barcelona, Spain. In this case modelling was used to address Water Framework Directive in the following: (1) Characterisation of aquifers and the status of groundwater by integration of existing knowledge and new hydrogeological information. Inverse modelling allowed us to reach an accurate description of the paths and mechanisms for the evolution of seawater intrusion. (2) Quantification of groundwater budget (mass balance). This is especially relevant for those terms that are difficult to asses, such as recharge from river infiltration during floods, which we have found to be very important. (3) Evaluation of groundwater-related environmental needs in aquatic ecosystems. The model allows quantifying groundwater input under natural conditions, which can be used as a reference level for stressed conditions. (4) Evaluation of possible impacts of territory planning (Llobregat river course modification, new railway tunnels, airport and docks enlargement, etc.). (5) Definition of management areas. (6) The assessment of possible future scenarios combined with optimization processes to quantify sustainable pumping rates and design measures to control seawater intrusion. The resulting model has been coupled to a user-friendly interface to allow water managers to design and address corrective measures in an agile and effective way.

From Points to Patterns - Functional Relations between Groundwater Connectivity and Catchment-scale Streamflow Response

NASA Astrophysics Data System (ADS)

Rinderer, M.; McGlynn, B. L.; van Meerveld, I. H. J.

2016-12-01

Groundwater measurements can help us to improve our understanding of runoff generation at the catchment-scale but typically only provide point-scale data. These measurements, therefore, need to be interpolated or upscaled in order to obtain information about catchment scale groundwater dynamics. Our approach used data from 51 spatially distributed groundwater monitoring sites in a Swiss pre-alpine catchment and time series clustering to define six groundwater response clusters. Each of the clusters was characterized by distinctly different site characteristics (i.e., Topographic Wetness Index and curvature), which allowed us to assign all unmonitored locations to one of these clusters. Time series modeling and the definition of response thresholds (i.e., the depth of more transmissive soil layers) allowed us to derive maps of the spatial distribution of active (i.e., responding) locations across the catchment at 15 min time intervals. Connectivity between all active locations and the stream network was determined using a graph theory approach. The extent of the active and connected areas differed during events and suggests that not all active locations directly contributed to streamflow. Gate keeper sites prevented connectivity of upslope locations to the channel network. Streamflow dynamics at the catchment outlet were correlated to catchment average connectivity dynamics. In a sensitivity analysis we tested six different groundwater levels for a site to be considered "active", which showed that the definition of the threshold did not significantly influence the conclusions drawn from our analysis. This study is the first one to derive patterns of groundwater dynamics based on empirical data (rather than interpolation) and provides insight into the spatio-temporal evolution of the active and connected runoff source areas at the catchment-scale that is critical to understanding the dynamics of water quantity and quality in streams.

Modelling the distribution of tritium in groundwater across South Africa to assess the vulnerability and sustainability of groundwater resources in response to climate change

NASA Astrophysics Data System (ADS)

van Rooyen, Jared; Miller, Jodie; Watson, Andrew; Butler, Mike

2017-04-01

Groundwater is critical for sustaining human populations, especially in semi-arid to arid areas, where surface water availability is low. Shallow groundwater is usually abstracted for this purpose because it is the easiest to access and assumed to be renewable and regularly recharged by precipitation. Renewable, regularly recharged groundwater is also called modern groundwater, ie groundwater that has recently been in contact with the atmosphere. Tritium can be used to determine whether or not a groundwater resource is modern because the half-life of tritium is only 12.36 years and tritium is dominantly produced in the upper atmosphere and not in the rock mass. For this reason, groundwater with detectable tritium activities likely has a residence age of less than 50 years. In this study, tritium activities in 277 boreholes distributed across South Africa were used to develop a national model for tritium activity in groundwater in order to establish the extent of modern groundwater across South Africa. The tritium model was combined with modelled depth to water using 3079 measured static water levels obtained from the National Groundwater Archive and validated against a separate set of 40 tritium activities along the west coast of South Africa. The model showed good agreement with the distribution of rainfall which has been previously documented across the globe (Gleeson et al., 2015), although the arid Karoo basin in south west South Africa shows higher than expected tritium levels given the very low regional precipitation levels. To assess the vulnerability of groundwater to degradation in quality and quantity, the tritium model was incorporated into a multi-criteria evaluation (MCE) model which incorporated other indicators of groundwater stress including mean annual precipitation, mean annual surface temperature, electrical conductivity (as a proxy for groundwater salinization), potential evaporation, population density and cultivated land usage. The MCE model was then forward projected using predicted climate change from the ECHAM5/MPI-OM model for SRES high emission scenario A2. The resultant groundwater vulnerability map for South Africa indicates that groundwater across large parts of western South Africa, particularly along the west coast and Northern Cape regions, is extremely vulnerable to deterioration in both quality and quantity and this deterioration is most strongly linked to mean annual precipitation and potential evaporation. Accordingly, the west coast region of South Africa is now, and will remain in the future, the most vulnerable region to climate change in South Africa. Further investigation of the predicted evolution of climate, biodiversity and agricultural capacity in this region will be critical for developing sustainable groundwater management protocols. Gleeson, T., Befus, K.M., Jasechko, S., Luijendijk, E., and Bayani Cardenas, M., 2016. The global volume and distribution of modern groundwater. Nature Geosciences, 9, 161-167.

Investigations of infiltration processes from flooded areas by column experiments

NASA Astrophysics Data System (ADS)

Mohrlok, U.; Bethge, E.; Golalipour, A.

2009-04-01

In case of inundation of flood plains during flood events there is an increased risk of groundwater contamination due to infiltration of increasingly polluted river water. Specifically in densely populated regions, this groundwater may be used as source for drinking water supply. For the evaluation of this a detailed quantitative understanding of the infiltration processes under such conditions is required. In this context the infiltration related to a flood event can be described by three phases. The first phase is defined by the saturation of the unsaturated soils. Within the second phase infiltration takes place under almost saturated conditions determined by the hydraulic load of the flood water level. The drainage of the soils due to falling groundwater table is characterizing the third phase. Investigations by soil columns gave a detailed insight into the infiltration processes caused by flooding. Inflow at the soil top was established by a fixed water table fed by a Mariotte bottle. Free outflow and a groundwater table were used as lower boundary condition. Inflow and outflow volume were monitored. The evolution of the matrix pressure was observed by micro-tensiometers installed at several depths within the soil column. The flow processes during phase one and two were characterized by a tracer test. Some of the experiments were repeated in order to study the influence of preliminary events. Main results were a difference in infiltration due to the lower boundary condition with regard to inflow rate, outflow dynamics and matrix pressure evolution which is directly related to the water content evolution. Further, the influence of preliminary events was different for the different boundary conditions. A replacement of pre-event water could be observed which was confirmed by volume balances calculated for the infiltration experiments. Although these water balances were almost closed significant dynamics of the matrix pressure remained in soil column in the drainage phase. The detailed analysis of the hydraulic conditions and the flow rates provided an estimate of the unsaturated hydraulic conductivity that could be related to the degree of saturation. Numerical simulations were not able to reproduce these conditions. These results could be used to estimate time scales of flow and solute transport in soils caused by flood events.

Chromosomal Evolution in Chiroptera

PubMed Central

Sotero-Caio, Cibele G.; Baker, Robert J.; Volleth, Marianne

2017-01-01

Chiroptera is the second largest order among mammals, with over 1300 species in 21 extant families. The group is extremely diverse in several aspects of its natural history, including dietary strategies, ecology, behavior and morphology. Bat genomes show ample chromosome diversity (from 2n = 14 to 62). As with other mammalian orders, Chiroptera is characterized by clades with low, moderate and extreme chromosomal change. In this article, we will discuss trends of karyotypic evolution within distinct bat lineages (especially Phyllostomidae, Hipposideridae and Rhinolophidae), focusing on two perspectives: evolution of genome architecture, modes of chromosomal evolution, and the use of chromosome data to resolve taxonomic problems. PMID:29027987

Water, energy, and biogeochemical budgets investigation at Panola Mountain research watershed, Stockbridge, Georgia; a research plan

USGS Publications Warehouse

Huntington, T.G.; Hooper, R.P.; Peters, N.E.; Bullen, T.D.; Kendall, Carol

1993-01-01

The Panola Mountain Research Watershed (PMRW), located in the Panola Mountain State Conservation Park near Stockbridge, Georgia has been selected as a core research watershed under the Water, Energy and Biogeochemical Budgets (WEBB) research initiative of the U.S. Geological Survey (USGS) Global Climate Change Program. This research plan describes ongoing and planned research activities at PMRW from 1984 to 1994. Since 1984, PMRW has been studied as a geochemical process research site under the U.S. Acid Precipitation Thrust Program. Research conducted under this Thrust Program focused on the estimation of dry atmospheric deposition, short-term temporal variability of streamwater chemistry, sulfate adsorption characteristics of the soils, groundwater chemistry, throughfall chemistry, and streamwater quality. The Acid Precipitation Thrust Program continues (1993) to support data collection and a water-quality laboratory. Proposed research to be supported by the WEBB program is organized in 3 interrelated categories: streamflow generation and water-quality evolution, weathering and geochemical evolution, and regulation of soil-water chemistry. Proposed research on streamflow generation and water-quality evolution will focus on subsurface water movement, its influence in streamflow generation, and the associated chemical changes of the water that take place along its flowpath. Proposed research on weathering and geochemical evolution will identify the sources of cations observed in the streamwater at Panola Mountain and quantify the changes in cation source during storms. Proposed research on regulation of soil-water chemistry will focus on the poorly understood processes that regulate soil-water and groundwater chemistry. (USGS)

Hydrogeochemical characterization of fluoride rich groundwater of Wailpalli watershed, Nalgonda District, Andhra Pradesh, India.

PubMed

Reddy, A G S; Reddy, D V; Rao, P N; Prasad, K Maruthy

2010-12-01

The groundwater of Nalgonda district is well known for its very high fluoride content for the past five decades. Many researchers have contributed their scientific knowledge to unravel causes for fluoride enrichment of groundwater. In the present paper, an attempt has been made to relate the high fluoride content in the groundwater to hydrogeochemical characterization of the water in a fracture hard rock terrain--the Wailpally watershed. Groundwater samples collected from all the major geomorphic units in pre- and post-monsoon seasons were analyzed for its major ion constituents such as Ca(2+), Mg(2+), Na(+), K(+), CO3-, HCO3-, Cl(-), SO4(-2), NO3-, and F(-). The groundwaters in the watershed have the average fluoride content of 2.79 mg/l in pre-monsoon and 2.83 mg/l in post-monsoon. Fluoride concentration in groundwater does not show perceptible change neither with time nor in space. The ionic dominance pattern is in the order of Na(+) > Ca(2+) > Mg(2+) > K(-) among cations and HCO3- Cl(-) > SO4(-2) NO3- F(-) among anions in pre-monsoon. In post-monsoon, Mg replaces Ca(2+) and NO3- takes the place of SO4(-2). The Modified Piper diagram reflect that the water belong to Ca(+2)-Mg(+2)-HCO3- to Na(+)-HCO3- facies. Negative chloralkali indices in both the seasons prove that ion exchange between Na(+) and K(+) in aquatic solution took place with Ca(+2) and Mg(+2) of host rock. The interpretation of plots for different major ions and molar ratios suggest that weathering of silicate rocks and water-rock interaction is responsible for major ion chemistry of groundwater in Wailpally watershed. Chemical characteristics and evolution of this fluoride-contaminated groundwater is akin to normal waters of other hard rock terrain; hence, it can be concluded that aquifer material play an important role in the contribution of fluoride in to the accompanying water. High fluoride content in groundwater can be attributed to the continuous water-rock interaction during the process of percolation with fluoride-bearing country rocks under arid, low precipitation, and high evapotranspiration conditions.

Regional transport modelling for nitrate trend assessment and forecasting in a chalk aquifer.

PubMed

Orban, Philippe; Brouyère, Serge; Batlle-Aguilar, Jordi; Couturier, Julie; Goderniaux, Pascal; Leroy, Mathieu; Maloszewski, Piotr; Dassargues, Alain

2010-10-21

Regional degradation of groundwater resources by nitrate has become one of the main challenges for water managers worldwide. Regulations have been defined to reverse observed nitrate trends in groundwater bodies, such as the Water Framework Directive and the Groundwater Daughter Directive in the European Union. In such a context, one of the main challenges remains to develop efficient approaches for groundwater quality assessment at regional scale, including quantitative numerical modelling, as a decision support for groundwater management. A new approach combining the use of environmental tracers and the innovative 'Hybrid Finite Element Mixing Cell' (HFEMC) modelling technique is developed to study and forecast the groundwater quality at the regional scale, with an application to a regional chalk aquifer in the Geer basin in Belgium. Tritium data and nitrate time series are used to produce a conceptual model for regional groundwater flow and contaminant transport in the combined unsaturated and saturated zones of the chalk aquifer. This shows that the spatial distribution of the contamination in the Geer basin is essentially linked to the hydrodynamic conditions prevailing in the basin, more precisely to groundwater age and mixing and not to the spatial patterns of land use or local hydrodispersive processes. A three-dimensional regional scale groundwater flow and solute transport model is developed. It is able to reproduce the spatial patterns of tritium and nitrate and the observed nitrate trends in the chalk aquifer and it is used to predict the evolution of nitrate concentrations in the basin. The modelling application shows that the global inertia of groundwater quality is strong in the basin and trend reversal is not expected to occur before the 2015 deadline fixed by the European Water Framework Directive. The expected time required for trend reversal ranges between 5 and more than 50 years, depending on the location in the basin and the expected reduction in nitrate application. To reach a good chemical status, nitrate concentrations in the infiltrating water should be reduced as soon as possible below 50mg/l; however, even in that case, more than 50 years is needed to fully reverse upward trends. Copyright © 2010 Elsevier B.V. All rights reserved.

Evolution of the global water cycle on Mars: The geological evidence

NASA Technical Reports Server (NTRS)

Baker, V. R.; Gulick, V. C.

1993-01-01

The geological evidence for active water cycling early in the history of Mars (Noachian geological system or heavy bombardment) consists almost exclusively of fluvial valley networks in the heavily cratered uplands of the planet. It is commonly assumed that these landforms required explanation by atmospheric processes operating above the freezing point of water and at high pressure to allow rainfall and liquid surface runoff. However, it has also been documented that nearly all valley networks probably formed by subsurface outflow and sapping erosion involving groundwater outflow prior to surface-water flow. The prolonged ground-water flow also requires extensive water cycling to maintain hydraulic gradients, but is this done via rainfall recharge, as in terrestrial environments?

Response and recovery of a pristine groundwater ecosystem impacted by toluene contamination - A meso-scale indoor aquifer experiment

NASA Astrophysics Data System (ADS)

Herzyk, Agnieszka; Fillinger, Lucas; Larentis, Michael; Qiu, Shiran; Maloszewski, Piotr; Hünniger, Marko; Schmidt, Susanne I.; Stumpp, Christine; Marozava, Sviatlana; Knappett, Peter S. K.; Elsner, Martin; Meckenstock, Rainer; Lueders, Tillmann; Griebler, Christian

2017-12-01

Microbial communities are the driving force behind the degradation of contaminants like aromatic hydrocarbons in groundwater ecosystems. However, little is known about the response of native microbial communities to contamination in pristine environments as well as their potential to recover from a contamination event. Here, we used an indoor aquifer mesocosm filled with sandy quaternary calciferous sediment that was continuously fed with pristine groundwater to study the response, resistance and resilience of microbial communities to toluene contamination over a period of almost two years, comprising 132 days of toluene exposure followed by nearly 600 days of recovery. We observed an unexpectedly high intrinsic potential for toluene degradation, starting within the first two weeks after the first exposure. The contamination led to a shift from oxic to anoxic, primarily nitrate-reducing conditions as well as marked cell growth inside the contaminant plume. Depth-resolved community fingerprinting revealed a low resistance of the native microbial community to the perturbation induced by the exposure to toluene. Distinct populations that were dominated by a small number of operational taxonomic units (OTUs) rapidly emerged inside the plume and at the plume fringes, partially replacing the original community. During the recovery period physico-chemical conditions were restored to the pristine state within about 35 days, whereas the recovery of the biological parameters was much slower and the community composition inside the former plume area had not recovered to the original state by the end of the experiment. These results demonstrate the low resilience of sediment-associated groundwater microbial communities to organic pollution and underline that recovery of groundwater ecosystems cannot be assessed solely by physico-chemical parameters.

Final report : site reclassification investigation for Courtland, Kansas.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Dennis, C. B.; Environmental Science Division

2006-01-31

The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), formerly operated a grain storage facility in Courtland, Kansas. Prior to 1986, commercial grain fumigants containing carbon tetrachloride were commonly used by the CCC/USDA and the grain industry to preserve stored grain. In 1999, the Kansas Department of Health and Environment (KDHE) identified the former CCC/USDA operation as the likely source of carbon tetrachloride found in groundwater east of the former CCC/USDA facility in Courtland. Sampling by the KDHE in April 1998 had found carbon tetrachloride in the Garman residence lawn and garden well at amore » concentration of 2.1 {micro}g/L and in the Hoard residence lawn and garden well at a concentration of 0.5 {micro}g/L. Subsequent soil and groundwater sampling by the KDHE at the former CCC/USDA facility found no indication of a continuing source, and subsequent sampling of the affected wells showed generally declining contaminant levels. At the request of the KDHE and the CCC/USDA, Argonne National Laboratory prepared a Work Plan for Groundwater Sampling for Potential Site Reclassification, Courtland, Kansas (Argonne 2004). The objective of the proposed work was to conduct a single groundwater monitoring event and collect information necessary to update the status of the previously detected groundwater contamination, in support of an evaluation of appropriate actions for reclassification of the status of this site from active to resolved, under the Intergovernmental Agreement between the KDHE and the USDA's Farm Service Agency (FSA). The reclassification would be in accordance with the KDHE's Reclassification Plan (Policy No. BERRS-024, online at http://www.kdhe.state.ks.us/pdf/ber/scp/reclass.pdf). The KDHE approved the Work Plan on August 8, 2005. Sampling was conducted on September 7, 2005.« less

Response and recovery of a pristine groundwater ecosystem impacted by toluene contamination - A meso-scale indoor aquifer experiment.

PubMed

Herzyk, Agnieszka; Fillinger, Lucas; Larentis, Michael; Qiu, Shiran; Maloszewski, Piotr; Hünniger, Marko; Schmidt, Susanne I; Stumpp, Christine; Marozava, Sviatlana; Knappett, Peter S K; Elsner, Martin; Meckenstock, Rainer; Lueders, Tillmann; Griebler, Christian

2017-12-01

Microbial communities are the driving force behind the degradation of contaminants like aromatic hydrocarbons in groundwater ecosystems. However, little is known about the response of native microbial communities to contamination in pristine environments as well as their potential to recover from a contamination event. Here, we used an indoor aquifer mesocosm filled with sandy quaternary calciferous sediment that was continuously fed with pristine groundwater to study the response, resistance and resilience of microbial communities to toluene contamination over a period of almost two years, comprising 132days of toluene exposure followed by nearly 600days of recovery. We observed an unexpectedly high intrinsic potential for toluene degradation, starting within the first two weeks after the first exposure. The contamination led to a shift from oxic to anoxic, primarily nitrate-reducing conditions as well as marked cell growth inside the contaminant plume. Depth-resolved community fingerprinting revealed a low resistance of the native microbial community to the perturbation induced by the exposure to toluene. Distinct populations that were dominated by a small number of operational taxonomic units (OTUs) rapidly emerged inside the plume and at the plume fringes, partially replacing the original community. During the recovery period physico-chemical conditions were restored to the pristine state within about 35days, whereas the recovery of the biological parameters was much slower and the community composition inside the former plume area had not recovered to the original state by the end of the experiment. These results demonstrate the low resilience of sediment-associated groundwater microbial communities to organic pollution and underline that recovery of groundwater ecosystems cannot be assessed solely by physico-chemical parameters. Copyright © 2017 Elsevier B.V. All rights reserved.

Filtering methods in tidal-affected groundwater head measurements: Application of harmonic analysis and continuous wavelet transform

NASA Astrophysics Data System (ADS)

Sánchez-Úbeda, Juan Pedro; Calvache, María Luisa; Duque, Carlos; López-Chicano, Manuel

2016-11-01

A new methodology has been developed to obtain tidal-filtered time series of groundwater levels in coastal aquifers. Two methods used for oceanography processing and forecasting of sea level data were adapted for this purpose and compared: HA (Harmonic Analysis) and CWT (Continuous Wavelet Transform). The filtering process is generally comprised of two main steps: the detection and fitting of the major tide constituents through the decomposition of the original signal and the subsequent extraction of the complete tidal oscillations. The abilities of the optional HA and CWT methods to decompose and extract the tidal oscillations were assessed by applying them to the data from two piezometers at different depths close to the shoreline of a Mediterranean coastal aquifer (Motril-Salobreña, SE Spain). These methods were applied to three time series of different lengths (one month, one year, and 3.7 years of hourly data) to determine the range of detected frequencies. The different lengths of time series were also used to determine the fit accuracies of the tidal constituents for both the sea level and groundwater heads measurements. The detected tidal constituents were better resolved with increasing depth in the aquifer. The application of these methods yielded a detailed resolution of the tidal components, which enabled the extraction of the major tidal constituents of the sea level measurements from the groundwater heads (e.g., semi-diurnal, diurnal, fortnightly, monthly, semi-annual and annual). In the two wells studied, the CWT method was shown to be a more effective method than HA for extracting the tidal constituents of highest and lowest frequencies from groundwater head measurements.

Hydrological and geochemical processes constraining groundwater salinity in wetland areas related to evaporitic (karst) systems. A case study from Southern Spain

NASA Astrophysics Data System (ADS)

Gil-Márquez, J. M.; Barberá, J. A.; Andreo, B.; Mudarra, M.

2017-01-01

Chemical and isotopic evolution of groundwater in an evaporite karst plateau (including wetland areas and saline to hyper-saline springs) located at S Spain was studied. Physicochemical parameters, major ions and stable isotopes were analyzed in rain, brine spring, wetland and leakage water samples, from which the most common mineral saturation indexes were computed and geochemical and isotopic modelling were performed. Results show an apparent relationship between the elevation of brine springs and their water mineralization, indicating that drainage at higher altitude may be associated to gravity-driven flows, since brackish groundwater is isotopically fractionated due to evaporation. On the other hand, the lower altitude springs could drain deeper flows with longer residence time, resulting in highly mineralized and warmer (briny) groundwater. The dissolution of halite and gypsum has proved to be the main geochemical processes, which are favored by the great ionic strength of groundwater. Calcite precipitation occurs in brackish waters draining wetlands, being boosted by common ion effect (when CaSO4 waters are present) and solute concentration caused by evaporation. Modelling results strongly support the hypothesis that most of the selected springs geochemically evolve in a common (S-N) flowpath. The methods used in this research contribute to a better understanding of the hydrogeological processes occurring in the studied evaporitic system, but also in equivalent hydrological environments worldwide.

Assessment of groundwater and soil quality degradation using multivariate and geostatistical analyses, Dakhla Oasis, Egypt

NASA Astrophysics Data System (ADS)

Masoud, Alaa A.; El-Horiny, Mohamed M.; Atwia, Mohamed G.; Gemail, Khaled S.; Koike, Katsuaki

2018-06-01

Salinization of groundwater and soil resources has long been a serious environmental hazard in arid regions. This study was conducted to investigate and document the factors controlling such salinization and their inter-relationships in the Dakhla Oasis (Egypt). To accomplish this, 60 groundwater samples and 31 soil samples were collected in February 2014. Factor analysis (FA) and hierarchical cluster analysis (HCA) were integrated with geostatistical analyses to characterize the chemical properties of groundwater and soil and their spatial patterns, identify the factors controlling the pattern variability, and clarify the salinization mechanism. Groundwater quality standards revealed emergence of salinization (av. 885.8 mg/L) and extreme occurrences of Fe2+ (av. 17.22 mg/L) and Mn2+ (av. 2.38 mg/L). Soils were highly salt-affected (av. 15.2 dS m-1) and slightly alkaline (av. pH = 7.7). Evaporation and ion-exchange processes governed the evolution of two main water types: Na-Cl (52%) and Ca-Mg-Cl (47%), respectively. Salinization leads the chemical variability of both resources. Distinctive patterns of slight salinization marked the northern part and intense salinization marked the middle and southern parts. Congruence in the resources clusters confirmed common geology, soil types, and urban and agricultural practices. Minimizing the environmental and socioeconomic impacts of the resources salinization urges the need for better understanding of the hydrochemical characteristics and prediction of quality changes.

Rapid decadal evolution in the groundwater arsenic content of Kolkata, India and its correlation with the practices of her dwellers.

PubMed

Malakar, Arindam; Islam, Samirul; Ali, Md Ashif; Ray, Sugata

2016-10-01

Increasing arsenic contamination in the groundwater is one of the biggest environmental challenges that the Bengal delta is facing today. Groundwater is still the main source of water for a large number of population in this region and therefore, significant presence of toxic arsenic has a direct consequence on human lives here. Moreover, arsenic also enters into the food chain through the consumed agricultural products grown in this area. Therefore, acquiring knowledge about the ever-changing map of arsenic contamination and employing adequate protective measures are of utmost importance. Here, we present a comprehensive municipal ward-wise map of the arsenic content of the shallow groundwater table of Kolkata-the most important and highly population dense city of the delta. Comparison with previously available data reveals a rapid change and the grim situation for the city. Our study suggests that it should be an immediate task of the administration to extend treated water service to the whole population of the city for direct consumption, and artificial recharge and maximum rainwater replenishment need to be taken up with utmost urgency to avoid intrusion of toxicity in biological food chains via agricultural products. We hope our study would drive the city planners to reconsider the existing urbanization and development plans of all the cities, placed over arsenic-contaminated groundwater aquifers.

Unraveling the controls on biogeomorphic succession: the influence of groundwater, soil and geomorphic setting on bio-geomorphic channel evolution

NASA Astrophysics Data System (ADS)

Bätz, Nico; Verrecchia, Eric P.; Lane, Stuart N.

2017-04-01

Braided rivers are characterized by high rates of morphological change. However, despite the potential for frequent disturbance, vegetated patches may develop within this system and influence long-term channel dynamics and channel patterns through the "engineering effects" of biogeomorphic succession. The stabilizing effect of developing vegetation on morphological change has been widely shown by flume experiments and (historic) aerial pictures analysis. Thus, there is a balance between disturbance and stabilization, mediated through biogeomorphic succession, that may determine the long-term geomorphic and biogeomorphic evolution of the river. Research has addressed how changes in disturbance frequency affect river channel pattern, but much less has been done to understand what influences the rate of biogeomorphic succession and how it affects river morphodynamics. This study explores the complex pattern of ambient conditions in braided river systems driving the rate of biogeomorphic succession. In particular, we focus on the interplay between groundwater access, soil formation, disturbance frequency and geomorphic setting, in defining what drives vegetation succession rates and its long-term implications on channel pattern evolution. We studied these feedbacks in a transitional gravel-bed river system (braided, wandering, meandering) close to Geneva (Switzerland) - the Allondon River. Results show that, at the beginning of the succession, humification plays a negative role on local ambient conditions necessary for sprouting. Successful vegetation establishment is then related positively to humification, but also to higher disturbance rates. The third biogeomorphic phase, with the highest feedbacks on river morphology, appears to be mainly driven by groundwater access, which in turn defines the rates of humification in this gravelly environment. This in turn defines the decadal morphological response of the channel after a reduction in disturbance frequency over the last 50 years. Overall, these results show how the functioning and the developing ecosystem at local scale affect the ecosystem resilience at a larger scale, and thus affects the long-term geomorphological river response.

Examining Basin-Scale Water and Climate Relations across the Pampa del Tamarugal, Atacama Desert through Spatial Analysis of Hydrogen, Carbon and Oxygen Isotopes in Tree Rings

NASA Astrophysics Data System (ADS)

Olson, E. J.; Dodd, J. P.; Rivera, M. A.

2016-12-01

Arid regions are extremely sensitive to variations hydroclimate. However, our understanding of past hydroclimate variations in these regions is often limited by a paucity of spatially resolved proxy data. The Atacama Desert of northern Chile is one of the driest regions on Earth, and hydroclimatic processes in the Atacama Desert may be a useful proxy for understanding the implications of expanding global aridity. In order to assess the ability of tree-ring isotope studies to record changes in hydrology and terrestrial climate in the Atacama Desert, oxygen (δ18O), carbon (δ13C) and hydrogen (δ2H) isotope values in tree rings of Prosopis tamarugo are analyzed for the modern period (1954-2014) when anthropogenic change to regional groundwater levels have been most notable. Samples of wood cellulose were collected throughout the Pampa del Tamarugal basin from 14 individuals and used to create an interpolated surface of isotope variations. The isotope data were then compared to groundwater depth from well monitoring data provided by the Dirección de General de Agua of Chile. There is a significant correlation between groundwater level and isotope values with best agreement occurring during the past two decades for δ18O (r = 0.58), δ13C (r = 0.55), and δ2H (r = 0.66) values. This spatial correlation analysis reveals that tree ring a-cellulose isotope values are a suitable proxy for reconstructing groundwater depth in the Pampa del Tamarugal Basin. A stepwise multiregression analysis between δ18O values of cellulose and several other environmental variables including groundwater level, relative humidity, and temperature suggest that groundwater depth is the dominate control of variation in the modern δ18O tree ring record. The response of tree cellulose to the hydroclimate in this region suggests that tree ring isotope variations may be used to reconstruct past hydroclimate conditions in arid regions throughout the globe.

Analysis of the groundwater monitoring controversy at the Pavillion, Wyoming natural gas field.

PubMed

Stephens, Daniel B

2015-01-01

The U.S. Environmental Protection Agency (EPA) was contacted by citizens of Pavillion, Wyoming 6 years ago regarding taste and odor in their water wells in an area where hydraulic fracturing operations were occurring. EPA conducted a field investigation, including drilling two deep monitor wells, and concluded in a draft report that constituents associated with hydraulic fracturing had impacted the drinking water aquifer. Following extensive media coverage, pressure from state and other federal agencies, and extensive technical criticism from industry, EPA stated the draft report would not undergo peer review, that it would not rely on the conclusions, and that it had relinquished its lead role in the investigation to the State of Wyoming for further investigation without resolving the source of the taste and odor problem. Review of the events leading up to EPA's decision suggests that much of the criticism could have been avoided through improved preproject planning with clear objectives. Such planning would have identified the high national significance and potential implications of the proposed work. Expanded stakeholder involvement and technical input could have eliminated some of the difficulties that plagued the investigation. However, collecting baseline groundwater quality data prior to initiating hydraulic fracturing likely would have been an effective way to evaluate potential impacts. The Pavillion groundwater investigation provides an excellent opportunity for improving field methods, report transparency, clarity of communication, and the peer review process in future investigations of the impacts of hydraulic fracturing on groundwater. © 2014, National Ground Water Association.

How Jordan and Saudi Arabia are avoiding a tragedy of the commons over shared groundwater

NASA Astrophysics Data System (ADS)

Müller, Marc F.; Müller-Itten, Michèle C.; Gorelick, Steven M.

2017-07-01

Transboundary aquifers are ubiquitous and strategically important to global food and water security. Yet these shared resources are being depleted at an alarming rate. Focusing on the Disi aquifer, a key nonrenewable source of groundwater shared by Jordan and Saudi Arabia, this study develops a two-stage game that evaluates optimal transboundary strategies of common-pool resource exploitation under various assumptions. The analysis relies on estimates of agricultural water use from satellite imagery, which were obtained using three independent remote sensing approaches. Drawdown response to pumping is simulated using a 2-D regional aquifer model. Jordan and Saudi Arabia developed a buffer-zone strategy with a prescribed minimum distance between each country's pumping centers. We show that by limiting the marginal impact of pumping decisions on the other country's pumping costs, this strategy will likely avoid an impeding tragedy of the commons for at least 60 years. Our analysis underscores the role played by distance between wells and disparities in groundwater exploitation costs on common-pool overdraft. In effect, if pumping centers are distant enough, a shared aquifer no longer behaves as a common-pool resource and a tragedy of the commons can be avoided. The 2015 Disi aquifer pumping agreement between Jordan and Saudi Arabia, which in practice relies on a joint technical commission to enforce exclusion zones, is the first agreement of this type between sovereign countries and has a promising potential to avoid conflicts or resolve potential transboundary groundwater disputes over comparable aquifer systems elsewhere.

Altered Landscapes and Groundwater Sustainability — Exploring Impacts with Induced Polarization, DC Resistivity, and Thermal Tracing

NASA Astrophysics Data System (ADS)

Eddy-Miller, C.; Caldwell, R.; Wheeler, J.; McCarthy, P.; Binley, A. M.; Constantz, J. E.; Stonestrom, D. A.

2009-12-01

Anthropogenically impacted landscapes constitute rising proportions of the Earth’s surface that are characterized by generally elevated nutrient and sediment loadings concurrent with increased consumptive water withdrawals. In recent years a growing number of hydraulically engineered riparian habitat restoration projects have attempted to ameliorate negative impacts of land use on groundwater-surface water systems resulting, e.g., from agricultural practices and urban development. Often the nature of groundwater-surface water interactions in pre- and minimally altered systems is poorly known, making it difficult to assess the impacts of land use and restoration projects on groundwater sustainability. Traditional assessments of surface water parameters (flow, temperature, dissolved oxygen, biotic composition, etc.) can be complemented by hydraulic and thermal measurements to better understand the important role played by groundwater-surface water interactions. Hydraulic and thermal measurements are usually limited to point samples, however, making non-invasive and spatially extensive geophysical characterizations an attractive additional tool. Groundwater-surface water interactions along the Smith River, a tributary to the Missouri River in Montana, and Fish Creek and Flat Creek, tributaries to the Snake River in Wyoming, are being examined using a combination of hydraulic measurements, thermal tracing, and electrical-property imaging. Ninety-two direct-current (DC) resistivity and induced polarization cross sections were obtained at stream transects covering a wide variety of hydrogeologic settings ranging from shallow bedrock to thick alluvial sequences, nature of groundwater-surface water interactions (always gaining, always losing, or seasonally varying) and anthropogenic impacts (minimal low-intensity agriculture to major landscape engineering, including channel reconstruction). DC resistivity and induced polarization delineated mutually distinct features related to hydraulic architecture. For example, induced polarization imaging resolved channel-edge muck deposits that are presumed to be sites of low hydraulic conductivity, chemical reduction, and metal accumulation. DC resistivity delineated bedrock-alluvium contacts and showed potential for tracking changes in salinization. While electrical properties cannot substitute for hydraulic and thermal data, the addition of relatively rapidly acquired, spatially extensive resistivity and induced polarization imaging offers synergistic opportunities for interpretive hydrologic investigations.

Proglacial Hydrogeology of the Cordillera Blanca (Peru): Integrating Field Observations with Hydrogeophysical Inversions to Inform Groundwater Flow Simulations and Conceptual Models

NASA Astrophysics Data System (ADS)

Glas, R. L.; Lautz, L.; McKenzie, J. M.; Moucha, R.; Mark, B. G.

2017-12-01

Geological and depositional conditions of the glaciated Cordillera Blanca in Peru have given way to proglacial aquifer systems that contribute substantially to regional streams and rivers, particularly during the dry season. As glacial retreat accelerates, the dry season water budget will be increasingly dominated by groundwater inputs, although predictions of future groundwater quantities require estimations of groundwater storage capacity, aquifer extents, and groundwater residence time. We present a characterization of the sediment structure in a prototypical proglacial valley in the central portion of the range, the Quilcayhuanca Valley. Northern and Central valleys of the Cordillera Blanca feature ubiquitous talus deposits that line the steep granite walls, and have become partially buried beneath lacustrine sediments deposited in proglacial lake beds. The portion of the talus still exposed near the valley walls provides recharge to deeper portions of the valley aquifers that underlie lacustrine clay, resulting in a confined aquifer system that is connected to the surface via perennial springs. Seismic refraction surveys reveal an interface separating relatively slow ( 400-800 m/s) and fast ( 2500 m/s) p-wave velocities. The depth of this refractor coincides with the depth to buried talus observed in drilling records. Electrical resistivity tomography profiles of the same transect show depths near the buried talus to be relatively conductive (10-100 Ωm). At these depths, we hypothesize that electrical conductance is elevated by saturated clay particles in the sediment matrix of the talus deposit. The resistivity models all show a more resistive ( 700 Ω m) region at depth, likely corresponding to a more hydraulically conductive material. The resistive zone is interpreted to be a deeper portion of a buried talus deposit that did not accumulate clay in the matrix. Other possibilities include a thick deposit of gravelly glacial outwash, or a relatively clay-poor glacial till. We present a groundwater modeling framework to resolve the nature of the sediments in deeper layers, where geophysical data become less certain. Sediment permeability estimates will allow for more refined predictions of groundwater storage volume in buried talus aquifers, which are likely prevalent throughout the range.

Groundwater nitrate concentration evolution under climate change and agricultural adaptation scenarios: Prince Edward Island, Canada

NASA Astrophysics Data System (ADS)

Paradis, D.; Vigneault, H.; Lefebvre, R.; Savard, M. M.; Ballard, J.-M.; Qian, B.

2015-08-01

Nitrate (N-NO3) concentration in groundwater, the sole source of potable water in Prince Edward Island (PEI, Canada), currently exceeds the 10 mg L-1 (N-NO3) health threshold for drinking water in 6 % of domestic wells. Increasing climatic and socio-economic pressures on PEI agriculture may further deteriorate groundwater quality. This study assesses how groundwater nitrate concentrations could evolve due to the forecasted climate change and its related potential changes in agricultural practices. For this purpose, a tridimensional numerical groundwater flow and mass transport model was developed for the aquifer system of the entire Island (5660 km2). A number of different groundwater flow and mass transport simulations were made to evaluate the potential impact of the projected climate change and agricultural adaptation. According to the simulations for year 2050, N-NO3 concentration would increase due to two main causes: (1) the progressive attainment of steady-state conditions related to present-day nitrogen loadings, and (2) the increase in nitrogen loadings due to changes in agricultural practices provoked by future climatic conditions. The combined effects of equilibration with loadings, climate and agricultural adaptation would lead to a 25 to 32 % increase in N-NO3 concentration over the Island aquifer system. Climate change alone (practices maintained at their current level) would contribute only 0 to 6 % to that increase according to the various climate scenarios. Moreover, simulated trends in groundwater N-NO3 concentration suggest that an increased number of domestic wells (more than doubling) would exceed the nitrate drinking water criteria. This study underlines the need to develop and apply better agricultural management practices to ensure sustainability of long-term groundwater resources. The simulations also show that observable benefits from positive changes in agricultural practices would be delayed in time due to the slow dynamics of nitrate transport within the aquifer system.

Is it worth protecting groundwater from diffuse pollution with agri-environmental schemes? A hydro-economic modeling approach.

PubMed

Hérivaux, Cécile; Orban, Philippe; Brouyère, Serge

2013-10-15

In Europe, 30% of groundwater bodies are considered to be at risk of not achieving the Water Framework Directive (WFD) 'good status' objective by 2015, and 45% are in doubt of doing so. Diffuse agricultural pollution is one of the main pressures affecting groundwater bodies. To tackle this problem, the WFD requires Member States to design and implement cost-effective programs of measures to achieve the 'good status' objective by 2027 at the latest. Hitherto, action plans have mainly consisted of promoting the adoption of Agri-Environmental Schemes (AES). This raises a number of questions concerning the effectiveness of such schemes for improving groundwater status, and the economic implications of their implementation. We propose a hydro-economic model that combines a hydrogeological model to simulate groundwater quality evolution with agronomic and economic components to assess the expected costs, effectiveness, and benefits of AES implementation. This hydro-economic model can be used to identify cost-effective AES combinations at groundwater-body scale and to show the benefits to be expected from the resulting improvement in groundwater quality. The model is applied here to a rural area encompassing the Hesbaye aquifer, a large chalk aquifer which supplies about 230,000 inhabitants in the city of Liege (Belgium) and is severely contaminated by agricultural nitrates. We show that the time frame within which improvements in the Hesbaye groundwater quality can be expected may be much longer than that required by the WFD. Current WFD programs based on AES may be inappropriate for achieving the 'good status' objective in the most productive agricultural areas, in particular because these schemes are insufficiently attractive. Achieving 'good status' by 2027 would demand a substantial change in the design of AES, involving costs that may not be offset by benefits in the case of chalk aquifers with long renewal times. Copyright © 2013 Elsevier Ltd. All rights reserved.

Strontium isotopes as tracers of water-rocks interactions, mixing processes and residence time indicator of groundwater within the granite-carbonate coastal aquifer of Bonifacio (Corsica, France).

PubMed

Santoni, S; Huneau, F; Garel, E; Aquilina, L; Vergnaud-Ayraud, V; Labasque, T; Celle-Jeanton, H

2016-12-15

This study aims at identifying the water-rock interactions and mixing rates within a complex granite-carbonate coastal aquifer under high touristic pressure. Investigations have been carried out within the coastal aquifer of Bonifacio (southern Corsica, France) mainly composed of continental granitic weathering products and marine calcarenite sediments filling a granitic depression. A multi-tracer approach combining physico-chemical parameters, major ions, selected trace elements, stable isotopes of the water molecule and 87 Sr/ 86 Sr ratios measurements is undertaken for 20 groundwater samples during the low water period in November 2014. 5 rock samples of the sedimentary deposits and surrounding granites are also analysed. First, the water-rock interactions processes governing the groundwater mineralization are described in order to fix the hydrogeochemical background. Secondly, the flow conditions are refined through the quantification of inter aquifer levels mixing, and thirdly, the kinetics of water-rock interaction based on groundwater residence time from a previous study using CFCs and SF 6 are quantified for the two main flow lines. A regional contrast in the groundwater recharge altitude allowed the oxygene-18 to be useful combined with the 87 Sr/ 86 Sr ratios to differentiate the groundwater origins and to compute the mixing rates, revealing the real extension of the watershed and the availability of the resource. The results also highlight a very good correlation between the groundwater residence time and the spatial evolution of 87 Sr/ 86 Sr ratios, allowing water-rock interaction kinetics to be defined empirically for the two main flow lines through the calcarenites. These results demonstrate the efficiency of strontium isotopes as tracers of water-rock interaction kinetics and by extension their relevance as a proxy of groundwater residence time, fundamental parameter documenting the long term sustainability of the hydrosystem. Copyright © 2016 Elsevier B.V. All rights reserved.

Groundwater intensive use and mining in south-eastern peninsular Spain: Hydrogeological, economic and social aspects.

PubMed

Custodio, Emilio; Andreu-Rodes, José Miguel; Aragón, Ramón; Estrela, Teodoro; Ferrer, Javier; García-Aróstegui, José Luis; Manzano, Marisol; Rodríguez-Hernández, Luis; Sahuquillo, Andrés; Del Villar, Alberto

2016-07-15

Intensive groundwater development is a common circumstance in semiarid and arid areas. Often abstraction exceeds recharge, thus continuously depleting reserves. There is groundwater mining when the recovery of aquifer reserves needs more than 50years. The MASE project has been carried out to compile what is known about Spain and specifically about the south-eastern Iberian Peninsula and the Canary Islands. The objective was the synthetic analysis of available data on the hydrological, economic, managerial, social, and ethical aspects of groundwater mining. Since the mid-20th century, intensive use of groundwater in south-eastern Spain allowed extending and securing the areas with traditional surface water irrigation of cash crops and their extension to former dry lands, taking advantage of good soils and climate. This fostered a huge economic and social development. Intensive agriculture is a main activity, although tourism plays currently an increasing economic role in the coasts. Many aquifers are relatively high yielding small carbonate units where the total groundwater level drawdown may currently exceed 300m. Groundwater storage depletion is estimated about 15km(3). This volume is close to the total contribution of the Tagus-Segura water transfer, but without large investments paid for with public funds. Seawater desalination complements urban supply and part of cash crop cultivation. Reclaimed urban waste water is used for irrigation. Groundwater mining produces benefits but associated to sometimes serious economic, administrative, legal and environmental problems. The use of an exhaustible vital resource raises ethical concerns. It cannot continue under the current legal conditions. A progressive change of water use paradigm is the way out, but this is not in the mind of most water managers and politicians. The positive and negative results observed in south-eastern Spain may help to analyse other areas under similar hydrogeological conditions in a less advanced stage of water use evolution. Copyright © 2016 Elsevier B.V. All rights reserved.

Geochemical and Sr isotopic variations in groundwaters of the Edwards aquifer, central Texas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oetting, G.C.; Banner, J.L.; Sharp, J.M. Jr.

1992-01-01

The regionally-extensive Edwards aquifer of central Texas lies on the northwestern edge of the Gulf of Mexico Basin. The aquifer system is composed primarily of lower Cretaceous marine limestones and dolostones with minor evaporitic and siliciclastic confining units of the Edwards Group and associated formations. The eastern and southern boundaries of the freshwater aquifer are defined by an abrupt change in groundwater salinity that is known as the badwater line. Variation in the isotopic composition and concentration of Sr in the mineral phases and waters in this aquifer system provide means to examine groundwater evolution processes. Models of simultaneous variationsmore » in Sr isotopes and major and trace ions are used to constrain processes of groundwater-rock interaction and groundwater mixing. Geochemical variations were examined in Edwards carbonate host rocks and groundwaters in Williamson and Bell Counties. Groundwaters were sampled along and across the badwater line, and range in salinity from 320--2,630 mg/l total dissolved solids. Major ion distributions in the water samples demonstrate a hydrochemical facies transition from Ca-HCO[sub 3] freshwaters to Na-Cl-SO[sub 4]-HCO[sub 3] badwaters. Both water types show a wide range of [sup 87]Sr/[sup 86]Sr values: Ca-HCO[sub 3] waters range from values of 0.7078--0.7093, and Na-Cl-SO[sub 4]-HCO[sub 3] waters range from values of 0.7087--0.7097. The Sr isotope compositions for both water groups are significantly greater than their host marine carbonates ([approximately]0.7075). The high Sr isotopic compositions indicate an extraformational source of Sr in both hydrochemical facies. Fluid mixing processes involving a freshwater and at least two badwater endmembers are required to account for variations in elemental and isotopic compositions in the groundwaters. Mineral-solution reactions may operate during and/or subsequent to mixing to produce the compositional variability observed in some intermediate waters.« less

Environmental risk assessment of the emerging EDCs contaminants from rural soil and aqueous sources: Analytical and modelling approaches.

PubMed

Song, Xiaoming; Wen, Yujuan; Wang, Yuanyuan; Adeel, Muhammad; Yang, Yuesuo

2018-05-01

The emerging endocrine disrupting chemicals posed high risk and much uncertainty to eco-environment and human health. An analytical method, developed for the simultaneous determination of five steroid estrogens in groundwater and soil based upon solid phase extraction and gas chromatography-mass spectrometry, was applied to investigate the distribution of estrone and 17β-estradiol around Shenyang City with particular focus on penetrating from surface to groundwater in this study. Mean concentrations of the estrone and 17β-estradiol were 55.1 ng L -1 and 56.1 ng L -1 in groundwater, 32.5 ng g -1 and 23.1 ng g -1 in soil, respectively. The distribution of estrone and 17β-estradiol were similar in groundwater, the concentration in the west of the site center was relatively low, and the surroundings were relatively high. The concentration of estrone was changed less, but 17β-estradiol was significantly increased in silt and silty sand layers in vadose zone profiles. Both estrone and 17β-estradiol concentrations changed abruptly at the interface of layers. Incorporating the temporal and spatial evolution of physical-chemical-biological environmental parameters at the sites, sorption and biodegradation were suggested the controlling roles in the fate and transport of SEs in the soil-groundwater system. The Ecological risk quotients values of both soil and groundwater indicated a very high ecological risk associated with SEs, but the non-carcinogenic harm quotients did not exceed the acceptable level of non-carcinogenic human health risk. Copyright © 2018 Elsevier Ltd. All rights reserved.

Sub-Millisecond Time Resolved X-ray Surface Diffraction During Pulsed Laser Deposition

NASA Astrophysics Data System (ADS)

Tischler, J. Z.; Larson, B. C.; Eres, Gyula; Rouleau, C. M.; Lowndes, D. H.; Yoon, M.; Zschack, P.

2001-03-01

The initial crystallization and evolution of the SrTiO3 (001) surface during homoeptaxial pulsed laser deposition growth of SrTiO3 was studied using time resolved surface x-ray diffraction with a time resolution down to 200 μ s. Measurements performed at the UNICAT undulator line at the Advanced Photon Source indicated prompt formation of epitaxial SrTiO3 bi-layers down to our limiting time resolution. The subsequent evolution of the surface occurred on a much greater time scale, and was studied both by measurements of surface truncation rod intensities and by measurements of diffuse scattering near the rod. The effect of temperature and correlation with in-plane order will also be discussed.

Effect of the environment on the hydrochemical characteristics of an alluvial aquifer following an exceptional multiyear drought (Mediterranean Seashore, Hérault, France): Part II—Climatology and agronomy

NASA Astrophysics Data System (ADS)

Grillot, Jean-Claude; Chaffaut, Isabelle; Razack, Moumtaz

1988-04-01

The hydrochemical evolution of an alluvial groundwater located along the Mediterranean seashore is analyzed with respect to its agricultural and climatic environment, including degree of saturation of the soil; types of cultures, chemical fertilizers and phytosanitary treatments; selective irrigations of the cultivated areas; precipitations. It is shown that the environmental effect on the groundwater's vulnerability depends on two groups of factors: 1. Transfers from surface to groundwater of nitrates, chlorides, sulfates, and potassium, which are governed by: (a) the climatic conditions before the agricultural activities begin, (b) the kinds of agricultural activities and their distribution in time with respect to a given climatic context. Phenomena of retention of and/or rapid diffusion are related to the sedimentary heterogeneities of the reservoir and to the differences of temperatures between irrigation waters and precipitations. 2. Cationic exchanges related to the presence of clays of Montmorillonite-Kaolinite type.

Structural evolution of detonation carbon in Composition B-3 by X-ray scattering

NASA Astrophysics Data System (ADS)

Firestone, Millicent; Dattelbaum, Dana; Gustavsen, Richard; Podlesak, David; Jensen, Brian; Watkins, Erik; Ringstrand, Bryan; Willey, Trevor; Lauderbach, Lisa; Hodgin, Ralph; Bagge-Hansen, Michael; van Buuren, Tony; Graber, Tim

2015-06-01

High explosive detonation products are primarily composed of solid carbon products. Prior electron microscopy studies have revealed that detonation carbon can contain a variety of unique carbon particles possessing novel morphologies, including core-shell, onions and ribbons. Despite these observations very little is known on what conditions leads to the production of novel carbon nanoparticles. A fuller understanding on conditions that generate such novel carbon materials would greatly benefit from time-resolved studies that probe particle formation and evolution through and beyond the chemical reaction zone. Here, we report initial experiments employing time-resolved X-ray scattering measurements to monitor the detonation carbon products formed from Composition B-3 (60% TNT, 40% RDX). Time-resolved SAXS (TRSAXS) studies were performed at the Dynamic Compression Sector (DCS, Sector 35) at the Advanced Photon Source (Argonne National Laboratory). In-situ formation of solid carbon behind the detonation front was probed on the nanosecond time scale. Analysis of the scattering patterns using model independent methods (Porod and Guinier) yielded insights into particle morphology and interfaces.

Internet Portal For A Distributed Management of Groundwater

NASA Astrophysics Data System (ADS)

Meissner, U. F.; Rueppel, U.; Gutzke, T.; Seewald, G.; Petersen, M.

The management of groundwater resources for the supply of German cities and sub- urban areas has become a matter of public interest during the last years. Negative headlines in the Rhein-Main-Area dealt with cracks in buildings as well as damaged woodlands and inundated agriculture areas as an effect of varying groundwater levels. Usually a holistic management of groundwater resources is not existent because of the complexity of the geological system, the large number of involved groups and their divergent interests and a lack of essential information. The development of a network- based information system for an efficient groundwater management was the target of the project: ?Grundwasser-Online?[1]. The management of groundwater resources has to take into account various hydro- geological, climatic, water-economical, chemical and biological interrelations [2]. Thus, the traditional approaches in information retrieval, which are characterised by a high personnel and time expenditure, are not sufficient. Furthermore, the efficient control of the groundwater cultivation requires a direct communication between the different water supply companies, the consultant engineers, the scientists, the govern- mental agencies and the public, by using computer networks. The presented groundwater information system consists of different components, especially for the collection, storage, evaluation and visualisation of groundwater- relevant information. Network-based technologies are used [3]. For the collection of time-dependant groundwater-relevant information, modern technologies of Mobile Computing have been analysed in order to provide an integrated approach in the man- agement of large groundwater systems. The aggregated information is stored within a distributed geo-scientific database system which enables a direct integration of simu- lation programs for the evaluation of interactions in groundwater systems. Thus, even a prognosis for the evolution of groundwater states can be given. In order to gener- ate reports automatically, technologies are utilised. The visualisation of geo-scientific databases in the internet considering their geographic reference is performed with internet map servers. According to the communication of the map server with the un- derlying geo-scientific database, it is necessary that the demanded data can be filtered interactively in the internet browser using chronological and logical criteria. With re- gard to public use the security aspects within the described distributed system are of 1 major importance. Therefore, security methods for the modelling of access rights in combination with digital signatures have been analysed and implemented in order to provide a secure data exchange and communication between the different partners in the network 2

Defining a conceptual model for the coastal aquifers of Mediterranean islands, an example from Corsica (France)

NASA Astrophysics Data System (ADS)

Santoni, Sebastien; Garel, Emilie; Huneau, Frederic

2016-04-01

A hydrochemical and isotope study was conducted to identify the flow paths, the recharge areas and the geochemical processes governing the evolution of groundwater in a Mediterranean carbonate coastal aquifer. The study is expected to improve the hydrogeological conceptual model based on environmental tracer investigations tools to characterise and quantify the aquifer system of Bonifacio. The groundwater resource represents the unique drinking water resource of the southern Corsica and the region faces a high pressures over the groundwater resource during the touristic period (2,000,000 tourists per year). A well-documented description of the geology and structure of this basin was the starting point for a detailed hydrogeochemical and isotopic study at the aquifer scale. A hydrochemical (physico-chemical parameters, major ions) and isotope (δ2H, δ18O, 3H) survey of rainwater and groundwater has been carried out monthly during almost two years. A local meteoric water line has been defined and marine, terrestrial and anthropogenic influences on the recharge water hydrochemistry have been described. Preferential recharge during autumn/winter of rainfall is observed and a depletion in the isotopic signature for some groundwater samples suggests a recharge in higher altitude from the surrounding granites. A modification of the input signal during infiltration through the unsaturated zone appears and the groundwater hydrochemistry displays differential variations in time and space, with the presence of inertial water bodies in the lower aquifer mainly. In this context, CFCs (CFC-11, CFC-12, CFC-113) and SF6 were used to evaluate groundwater residence time. CFCs have been relevant despite the presence of a deep unsaturated zone and the computed rate of groundwater renewal is pluriannual to multi-decadal. Natural SF6 was found in granites and has been used as a direct tracer of groundwater origin, highlighting its role in the aquifer lateral recharge. Strontium isotopes (87Sr/86Sr) were used to improve knowledge of groundwater mineralization and mixing processes. The use 87Sr/86Sr vs δ18O was relevant and helped confirming and quantifying the granitic contribution to the aquifer recharge. To improve the quantification of the water balance terms, submarine groundwater discharges have been studied using aerial infrared images in conjunction with Radon and Radium isotopes (222Rn, 223,224Ra).

Chemical characteristics of groundwater and assessment of groundwater quality in Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India.

PubMed

Rao, N Subba; Rao, P Surya; Reddy, G Venktram; Nagamani, M; Vidyasagar, G; Satyanarayana, N L V V

2012-08-01

Study on chemical characteristics of groundwater and impacts of groundwater quality on human health, plant growth, and industrial sector is essential to control and improve the water quality in every part of the country. The area of the Varaha River Basin is chosen for the present study, where the Precambrian Eastern Ghats underlain the Recent sediments. Groundwater quality is of mostly brackish and very hard, caused by the sources of geogenic, anthropogenic, and marine origin. The resulting groundwater is characterized by Na(+) > Mg(2+) > Ca(2+) : [Formula: see text] > Cl(-) > [Formula: see text], Na(+) > Mg(2+) > Ca(2+) : [Formula: see text] > Cl(-) > [Formula: see text] > [Formula: see text], Na(+) > Mg(2+) > Ca(2+) : [Formula: see text] > Cl(-), and Na(+) > Mg(2+) > Ca(2+) : Cl(-) > [Formula: see text] > [Formula: see text] facies, following the topographical and water flow-path conditions. The genetic geochemical evolution of groundwater ([Formula: see text] and Cl(-)-[Formula: see text] types under major group of [Formula: see text]) and the hydrogeochemical signatures (Na(+)/Cl(-), >1 and [Formula: see text]/Cl(-), <1) indicate that the groundwater is of originally fresh quality, but is subsequently modified to brackish by the influences of anthropogenic and marine sources, which also supported by the statistical analysis. The concentrations of total dissolved solids (TDS), TH, Mg(2+), Na(+), K(+), [Formula: see text], Cl(-), [Formula: see text], and F(-) are above the recommended limits prescribed for drinking water in many locations. The quality of groundwater is of mostly moderate in comparison with the salinity hazard versus sodium hazard, the total salt concentration versus percent sodium, the residual sodium carbonate, and the magnesium hazard, but is of mostly suitable with respect to the permeability index for irrigation. The higher concentrations of TDS, TH, [Formula: see text], Cl(-), and [Formula: see text] in the groundwater cause the undesirable effects of incrustation and corrosion in many locations. Appropriate management measures are, therefore, suggested to improve the groundwater quality.

Resolving runaway electron distributions in space, time, and energy

NASA Astrophysics Data System (ADS)

Paz-Soldan, C.; Cooper, C. M.; Aleynikov, P.; Eidietis, N. W.; Lvovskiy, A.; Pace, D. C.; Brennan, D. P.; Hollmann, E. M.; Liu, C.; Moyer, R. A.; Shiraki, D.

2018-05-01

Areas of agreement and disagreement with present-day models of runaway electron (RE) evolution are revealed by measuring MeV-level bremsstrahlung radiation from runaway electrons (REs) with a pinhole camera. Spatially resolved measurements localize the RE beam, reveal energy-dependent RE transport, and can be used to perform full two-dimensional (energy and pitch-angle) inversions of the RE phase-space distribution. Energy-resolved measurements find qualitative agreement with modeling on the role of collisional and synchrotron damping in modifying the RE distribution shape. Measurements are consistent with predictions of phase-space attractors that accumulate REs, with non-monotonic features observed in the distribution. Temporally resolved measurements find qualitative agreement with modeling on the impact of collisional and synchrotron damping in varying the RE growth and decay rate. Anomalous RE loss is observed and found to be largest at low energy. Possible roles for kinetic instability or spatial transport to resolve these anomalies are discussed.

Towards resolving Lamiales relationships: insights from rapidly evolving chloroplast sequences

PubMed Central

2010-01-01

Background In the large angiosperm order Lamiales, a diverse array of highly specialized life strategies such as carnivory, parasitism, epiphytism, and desiccation tolerance occur, and some lineages possess drastically accelerated DNA substitutional rates or miniaturized genomes. However, understanding the evolution of these phenomena in the order, and clarifying borders of and relationships among lamialean families, has been hindered by largely unresolved trees in the past. Results Our analysis of the rapidly evolving trnK/matK, trnL-F and rps16 chloroplast regions enabled us to infer more precise phylogenetic hypotheses for the Lamiales. Relationships among the nine first-branching families in the Lamiales tree are now resolved with very strong support. Subsequent to Plocospermataceae, a clade consisting of Carlemanniaceae plus Oleaceae branches, followed by Tetrachondraceae and a newly inferred clade composed of Gesneriaceae plus Calceolariaceae, which is also supported by morphological characters. Plantaginaceae (incl. Gratioleae) and Scrophulariaceae are well separated in the backbone grade; Lamiaceae and Verbenaceae appear in distant clades, while the recently described Linderniaceae are confirmed to be monophyletic and in an isolated position. Conclusions Confidence about deep nodes of the Lamiales tree is an important step towards understanding the evolutionary diversification of a major clade of flowering plants. The degree of resolution obtained here now provides a first opportunity to discuss the evolution of morphological and biochemical traits in Lamiales. The multiple independent evolution of the carnivorous syndrome, once in Lentibulariaceae and a second time in Byblidaceae, is strongly supported by all analyses and topological tests. The evolution of selected morphological characters such as flower symmetry is discussed. The addition of further sequence data from introns and spacers holds promise to eventually obtain a fully resolved plastid tree of Lamiales. PMID:21073690

Evaluation of the effects of precipitation on ground-water levels from wells in selected alluvial aquifers in Utah and Arizona, 1936-2005

USGS Publications Warehouse

Gardner, Philip M.; Heilweil, Victor M.

2009-01-01

Increased withdrawals from alluvial aquifers of the southwestern United States during the last half-century have intensified the effects of drought on ground-water levels in valleys where withdrawal for irrigation is greatest. Furthermore, during wet periods, reduced withdrawals coupled with increased natural recharge cause rising ground-water levels. In order to manage water resources more effectively, analysis of ground-water levels under the influence of natural and anthropogenic stresses is useful. This report evaluates the effects of precipitation patterns on ground-water levels in areas of Utah and Arizona that have experienced different amounts of ground-water withdrawal. This includes a comparison of water-level records from basins that are hydrogeologically and climatologically similar but have contrasting levels of ground-water development. Hydrologic data, including records of ground-water levels, basin-wide annual ground-water withdrawals, and precipitation were examined from two basins in Utah (Milford and central Sevier) and three in Arizona (Aravaipa Canyon, Willcox, and Douglas). Most water-level records examined in this study from basins experiencing substantial ground-water development (Milford, Douglas, and Willcox) showed strong trends of declining water levels. Other water-level records, generally from the less-developed basins (central Sevier and Aravaipa Canyon) exhibited trends of increasing water levels. These trends are likely the result of accumulating infiltration of unconsumed irrigation water. Water-level records that had significant trends were detrended by subtraction of a low-order polynomial in an attempt to eliminate the variation in the water-level records that resulted from ground-water withdrawal or the application of water for irrigation. After detrending, water-level residuals were correlated with 2- to 10-year moving averages of annual precipitation from representative stations for the individual basins. The water-level residual time series for each well was matched with the 2- to 10-year moving average of annual precipitation with which it was best correlated and the results were compared across basins and hydrologic settings. Analysis of water-level residuals and moving averages of annual precipitation indicate that ground-water levels in the Utah basins respond more slowly to precipitation patterns than those from the Arizona basins. This is attributed to the dominant mechanism of recharge that most directly influences the respective valley aquifers. Substantial recharge in the Utah basins likely originates as infiltrating snowmelt in the mountain block far from the valley aquifer, whereas mountain-front recharge and streambed infiltration of runoff are the dominant recharge mechanisms operating in the Arizona basins. It was determined that the fraction of water-level variation caused by local precipitation patterns becomes more difficult to resolve with increasing effects of ground-water pumping, especially from incomplete records. As the demand for ground water increases in the southwestern United States, long-term records of ground-water levels have the potential to provide valuable information about the precipitation-driven variation in water levels, which has implications to water management related to water availability.

Aquifer configuration and geostructural links control the groundwater quality in thin-bedded carbonate-siliciclastic alternations of the Hainich CZE, central Germany

NASA Astrophysics Data System (ADS)

Kohlhepp, Bernd; Lehmann, Robert; Seeber, Paul; Küsel, Kirsten; Trumbore, Susan E.; Totsche, Kai U.

2017-12-01

The quality of near-surface groundwater reservoirs is controlled, but also threatened, by manifold surface-subsurface interactions. Vulnerability studies typically evaluate the variable interplay of surface factors (land management, infiltration patterns) and subsurface factors (hydrostratigraphy, flow properties) in a thorough way, but disregard the resulting groundwater quality. Conversely, hydrogeochemical case studies that address the chemical evolution of groundwater often lack a comprehensive analysis of the structural buildup. In this study, we aim to reconstruct the actual spatial groundwater quality pattern from a synoptic analysis of the hydrostratigraphy, lithostratigraphy, pedology and land use in the Hainich Critical Zone Exploratory (Hainich CZE). This CZE represents a widely distributed yet scarcely described setting of thin-bedded mixed carbonate-siliciclastic strata in hillslope terrains. At the eastern Hainich low-mountain hillslope, bedrock is mainly formed by alternated marine sedimentary rocks of the Upper Muschelkalk (Middle Triassic) that partly host productive groundwater resources. Spatial patterns of the groundwater quality of a 5.4 km long well transect are derived by principal component analysis and hierarchical cluster analysis. Aquifer stratigraphy and geostructural links were deduced from lithological drill core analysis, mineralogical analysis, geophysical borehole logs and mapping data. Maps of preferential recharge zones and recharge potential were deduced from digital (soil) mapping, soil survey data and field measurements of soil hydraulic conductivities (Ks). By attributing spatially variable surface and subsurface conditions, we were able to reconstruct groundwater quality clusters that reflect the type of land management in their preferential recharge areas, aquifer hydraulic conditions and cross-formational exchange via caprock sinkholes or ascending flow. Generally, the aquifer configuration (spatial arrangement of strata, valley incision/outcrops) and related geostructural links (enhanced recharge areas, karst phenomena) control the role of surface factors (input quality and locations) vs. subsurface factors (water-rock interaction, cross-formational flow) for groundwater quality in the multi-layered aquifer system. Our investigation reveals general properties of alternating sequences in hillslope terrains that are prone to forming multi-layered aquifer systems. This synoptic analysis is fundamental and indispensable for a mechanistic understanding of ecological functioning, sustainable resource management and protection.

The hydrogeochemistry of argillaceous rock formations at the Horonobe URL site, Japan

NASA Astrophysics Data System (ADS)

Hama, K.; Kunimaru, T.; Metcalfe, R.; Martin, A. J.

A hydrogeochemical investigation is being carried out as part of the Horonobe underground research laboratory (URL) project in Japan. The main aims are to: (1) investigate an actual example of a geological environment in a sedimentary rock formation in Japan; and (2) to confirm the reliability of generic technologies that may in future be applied during the geological disposal of high level radioactive waste. The main rock formations being characterized are the marine Wakkanai and Koetoi Formations (Miocene to Pliocene), consisting dominantly of siliceous shales (porcelanites) and diatomaceous shales respectively. These formations are located within the Tempoku Basin, within a back-arc tectonic setting. Rock sequences of this kind occur widely in Japan and throughout the northern Pacific region. However, prior to the present study, there was relatively little information concerning the processes controlling in situ chemical conditions and groundwater flow in such settings. Chemical data was obtained for both pumped waters and squeezed porewaters in order to characterize the hydrogeochemistry of these argillaceous rock formations. The in situ chemical conditions, residence time of the groundwaters and the evolution processes of the groundwaters were investigated. Generally, at each locality studied, shallower groundwaters are fresh and have Na-HCO 3 dominated chemistry. Deeper groundwaters are saline (TDS up to about 22,000 mg/l) and have Na-Cl dominated chemistry. However, lateral gradients in salinity are also recognized, with salinity contours in the Na-Cl dominated saline water (having TDS > 10,000 mg/l) probably varying in elevation by at least 250 m. Further investigations are required to confirm the origins of the groundwater salinity, but the Na-Cl dominated groundwater chemistry is provisionally explained as a consequence of the dilution of fossil seawater, accompanied by diagenetic water-rock reactions. The vertical and lateral salinity gradients can potentially be used to test the validity of coupled groundwater flow models. A conceptual model is tentatively suggested in which the spatial distribution and frequency of fractures helps to control the spatial distribution of groundwater salinity. Future investigations will clarify the timing of flow, the flow directions and the characteristics of the flow paths.

Mapping groundwater quality distinguishing geogenic and anthropogenic contribution using NBL

NASA Astrophysics Data System (ADS)

Preziosi, Elisabetta; Ducci, Daniela; Condesso de Melo, Maria Teresa; Parrone, Daniele; Sellerino, Mariangela; Ghergo, Stefano; Oliveira, Joana; Ribeiro, Luis

2015-04-01

Groundwaters are threatened by anthropic activities and pollution is interesting a large number of aquifers worldwide. Qualitative and quantitative monitoring is required to assess the status and track its evolution in time and space especially where anthropic pressures are stronger. Up to now, groundwater quality mapping has been performed separately from the assessment of its natural status, i.e. the definition of the natural background level of a particular element in a particular area or groundwater body. The natural background level (NBL) of a substance or element allows to distinguish anthropogenic pollution from contamination of natural origin in a population of groundwater samples. NBLs are the result of different atmospheric, geological, chemical and biological interaction processes during groundwater infiltration and circulation. There is an increasing need for the water managers to have sound indications on good quality groundwater exploitation. Indeed the extension of a groundwater body is often very large, in the order of tens or hundreds of square km. How to select a proper location for good quality groundwater abstraction is often limited to a question of facility for drilling (access, roads, authorizations, etc.) or at the most related to quantitative aspects driven by geophysical exploration (the most promising from a transmissibility point of view). So how to give indications to the administrators and water managers about the exploitation of good quality drinking water? In the case of anthropic contamination, how to define which area is to be restored and to which threshold (e.g. background level) should the concentration be lowered through the restoration measures? In the framework of a common project between research institutions in Italy (funded by CNR) and Portugal (funded by FCT), our objective is to establish a methodology aiming at merging together 1) the evaluation of NBL and 2) the need to take into account the drinking water standards with a spatial analysis. We compare diverse case studies using geochemical maps built by kriging in which we interpolate the conditional probability of exceeding the reference value (i.e. the drinking water standard) OR the local natural background level. The resulting maps provide a useful reference for management purposes.

Flow paths in the Edwards aquifer, northern Medina and northeastern Uvalde counties, Texas, based on hydrologic identification and geochemical characterization and simulation

USGS Publications Warehouse

Clark, Allan K.; Journey, Celeste A.

2006-01-01

The U.S. Geological Survey, in cooperation with the San Antonio Water System, conducted a 4-year study during 2001– 04 to identify major ground-water flow paths in the Edwards aquifer in northern Medina and northeastern Uvalde Counties, Texas. The study involved use of geologic structure, surfacewater and ground-water data, and geochemistry to identify ground-water flow paths. Relay ramps and associated faulting in northern Medina County appear to channel ground-water flow along four distinct flow paths that move water toward the southwest. The northwestern Medina flow path is bounded on the north by the Woodard Cave fault and on the south by the Parkers Creek fault. Water moves downdip toward the southwest until the flow encounters a cross fault along Seco Creek. This barrier to flow might force part or most of the flow to the south. Departure hydrographs for two wells and discharge departure for a streamflow-gaging station provide evidence for flow in the northwestern Medina flow path. The north-central Medina flow path (northern part) is bounded by the Parkers Creek fault on the north and the Medina Lake fault on the south. The adjacent north-central Medina flow path (southern part) is bounded on the north by the Medina Lake fault and on the south by the Diversion Lake fault. The north-central Medina flow path is separated into a northern and southern part because of water-level differences. Ground water in both parts of the northcentral Medina flow path moves downgradient (and down relay ramp) from eastern Medina County toward the southwest. The north-central Medina flow path is hypothesized to turn south in the vicinity of Seco Creek as it begins to be influenced by structural features. Departure hydrographs for four wells and Medina Lake and discharge departure for a streamflow-gaging station provide evidence for flow in the north-central Medina flow path. The south-central Medina flow path is bounded on the north by the Seco Creek and Diversion Lake faults and on the south by the Haby Crossing fault. Because of bounding faults oriented northeast-southwest and adjacent flow paths directed south by other geologic structures, the south-central Medina flow path follows the configuration of the adjacent flow paths—oriented initially southwest and then south. Immediately after turning south, the south-central Medina flow path turns sharply east. Departure hydrographs for four wells and discharge departure for a streamflow-gaging station provide evidence for flow in the south-central Medina flow path. Statistical correlations between water-level departures for 11 continuously monitored wells provide additional evidence for the hypothesized flow paths. Of the 55 combinations of departure dataset pairs, the stronger correlations (those greater than .6) are all among wells in the same flow path, with one exception. Simulations of compositional differences in water chemistry along a hypothesized flow path in the Edwards aquifer and between ground-water and surface-water systems near Medina Lake were developed using the geochemical model PHREEQC. Ground-water chemistry for samples from five wells in the Edwards aquifer in the northwestern Medina flow path were used to evaluate the evolution of ground-water chemistry in the northwestern Medina flow path. Seven simulations were done for samples from pairs of these wells collected during 2001–03; three of the seven yielded plausible models. Ground-water samples from 13 wells were used to evaluate the evolution of ground-water chemistry in the north-central Medina flow path (northern and southern parts). Five of the wells in the most upgradient part of the flow path were completed in the Trinity aquifer; the remaining eight were completed in the Edwards aquifer. Nineteen simulations were done for samples from well pairs collected during 1995–2003; eight of the 19 yielded plausible models. Ground-water samples from seven wells were used to evaluate the evolution of ground-water chemistry in the south-central Medina flow path. One well was the Trinity aquifer end-member well upgradient from all flow paths, and another was a Trinity aquifer well in the most upgradient part of the flow path; all other wells were completed in the Edwards aquifer. Nine simulations were done for samples from well pairs collected during 1996–2003; seven of the nine yielded plausible models. The plausible models demonstrate that the four hypothesized flow paths can be partially supported geochemically. 

Political economy of the energy-groundwater nexus in India: exploring issues and assessing policy options

NASA Astrophysics Data System (ADS)

Shah, Tushaar; Giordano, Mark; Mukherji, Aditi

2012-08-01

Indian agriculture is trapped in a complex nexus of groundwater depletion and energy subsidies. This nexus is the product of past public policy choices that initially offered opportunities to India's small-holder-based irrigation economy but has now generated in its wake myriad economic, social, and environmental distortions. Conventional `getting-the-price-right' solutions to reduce these distortions have consistently been undermined by the invidious political economy that the nexus has created. The historical evolution of the nexus is outlined, the nature and scale of the distortions it has created are explored, and alternative approaches which Indian policy makers can use to limit, if not eliminate, the damaging impacts of the distortions, are analysed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Narasimhan, T.N.

That Charles V. Theis has a unique position in the history of goundwater hydrology is well attested by this conference, which seeks to pay tribute to his memory. Theis made his noteworthy contribution on unsteady groundwater flow during a period when exciting progress was being made in many disciplines closely related to groundwater hydrology. It is therefore appropriate that we use this opportunity provided by the Theis commemoration to reflect upon the evolution of ideas in hydrogeology during a score of years extending from the early 1920s to the early 1940s. Such a reflection is worthwhile, not only to getmore » a historical sense for the development of those ideas, but also to place the contribution of Theis in perspective with other distinguished contributions of that period.« less

Spatiotemporal evolution of water storage changes in India from the updated GRACE-derived gravity records

NASA Astrophysics Data System (ADS)

Panda, Dileep K.; Wahr, John

2016-01-01

Investigating changes in terrestrial water storage (TWS) is important for understanding response of the hydrological cycle to recent climate variability worldwide. This is particularly critical in India where the current economic development and food security greatly depend on its water resources. We use 129 monthly gravity solutions from NASA's Gravity Recovery and Climate Experiment (GRACE) satellites for the period of January 2003 to May 2014 to characterize spatiotemporal variations of TWS and groundwater storage (GWS). The spatiotemporal evolution of GRACE data reflects consistent patterns with that of several hydroclimatic variables and also shows that most of the water loss has occurred in the northern parts of India. Substantial GWS depletion at the rate of 1.25 and 2.1 cm yr-1 has taken place, respectively in the Ganges Basin and Punjab state, which are known as the India's grain bowl. Of particular concern is the Ganges Basin's storage loss in drought years, primarily due to anthropogenic groundwater withdrawals that sustain rice and wheat cultivation. We estimate these losses to be approximately 41, 44, and 42 km3 in 2004, 2009, and 2012, respectively. The GWS depletions that constitute about 90% of the observed TWS loss are also influenced by a marked rise in temperatures since 2008. A high degree of correspondence between GRACE-derived GWS and in situ groundwater levels from observation well validates the results. This validation increases confidence level in the application of GRACE observations in monitoring large-scale storage changes in intensely irrigated areas in India and other regions around the world.

An initial examination of tungsten geochemistry along groundwater flow paths

NASA Astrophysics Data System (ADS)

Dave, H. B.; Johannesson, K. H.

2008-12-01

Groundwater samples were collected along groundwater flow paths from the Upper Floridan (Florida), Carrizo Sand (Texas), and the Aquia (Maryland) aquifers and analyzed for tungsten (W) concentrations by high- resolution inductively couple plasma mass spectrometry. At each well head, groundwater samples were also analyzed for pH, specific conductance, temperature, alkalinity, dissolved oxygen (DO), oxidation-reduction potential (Eh), dissolved iron speciation, and dissolved sulfide [S(-II)] concentrations. Sediment samples from the Carrizo Sand and Aquia aquifers were also collected and subjected to sequential extractions to provide additional insights into the solid-phase speciation of W in these aquifers. Tungsten concentrations varied along the groundwater flow paths chiefly in response to changing pH, and to a lesser extent, variations in the redox conditions. For groundwater from the Carrizo Sand aquifer, W ranges between 3.64 and 1297 pmol/kg, exhibiting the lowest values proximal to the recharge zone. Tungsten concentrations progressively increase along the flow path, reaching 1297 pmol/kg in the sulfidic groundwaters located approximately 60 km downgradient from the recharge area. Tungsten is strongly correlated with S(-II) concentrations and pH in Carrizo groundwaters (r = 0.95 and 0.78, respectively). Within the Aquia aquifer, however, W generally occurs at lower concentrations than the Carrizo (14 to 184 pmol/kg; mean = 80 pmol/kg), and shows no systematic trends along the flow path (e.g., r = 0.08 and 0.4 for W vs. S(-II) and pH, respectively). Our data are consistent with the increase in W concentrations in Carrizo groundwaters reflecting, in part, pH-related desorption, which has been shown to be substantial for pH greater than 8. Moreover, because of the broad similarities in the chemistry of W and Mo, which forms thiomolybdates in sulfidic waters, we suggest that thiotungstate complexes may form in sulfidic groundwaters, thus partially explaining the elevated W in sulfidic waters of the Carrizo aquifer. We propose that the substantially lower W concentrations in Aquia groundwaters reflect the fact that these waters are suboxic and have not undergone sulfate reduction. Hence, the evolution of W concentrations in the Aquia aquifer is consistent with conservative behavior in these generally oxic to suboxic groundwaters. In summary, our data indicate that pH related adsorption/desorption reactions are the key factors controlling W concentrations in oxic and sub-oxic waters, whereas formation of thiotungstate complexes may be important in sulfidic/anoxic waters.

Evaluation of a Model-Based Groundwater Drought Indicator in the Conterminous U.S.

NASA Technical Reports Server (NTRS)

Li, Bailing; Rodell, Matthew

2015-01-01

Monitoring groundwater drought using land surface models is a valuable alternative given the current lack of systematic in situ measurements at continental and global scales and the low resolution of current remote sensing based groundwater data. However, uncertainties inherent to land surface models may impede drought detection, and thus should be assessed using independent data sources. In this study, we evaluated a groundwater drought index (GWI) derived from monthly groundwater storage output from the Catchment Land Surface Model (CLSM) using a GWI similarly derived from in situ groundwater observations. Groundwater observations were obtained from unconfined or semi-confined aquifers in eight regions of the central and northeastern U.S. Regional average GWI derived from CLSM exhibited strong correlation with that from observation wells, with correlation coefficients between 0.43 and 0.92. GWI from both in situ data and CLSM was generally better correlated with the Standard Precipitation Index (SPI) at 12 and 24 month timescales than at shorter timescales, but it varied depending on climate conditions. The correlation between CLSM derived GWI and SPI generally decreases with increasing depth to the water table, which in turn depends on both bedrock depth (a CLSM parameter) and mean annual precipitation. The persistence of CLSM derived GWI is spatially varied and again shows a strong influence of depth to groundwater. CLSM derived GWI generally persists longer than GWI derived from in situ data, due at least in part to the inability of coarse model inputs to capture high frequency meteorological variability at local scales. The study also showed that groundwater can have a significant impact on soil moisture persistence where the water table is shallow. Soil moisture persistence was estimated to be longer in the eastern U.S. than in the west, in contrast to previous findings that were based on models that did not represent groundwater. Assimilation of terrestrial water storage data from the Gravity Recovery and Climate Experiment (GRACE) satellite mission improved the correlation between CLSM based regional average GWI and that based on in situ data in six of the eight regions. Practical issues regarding the application of GRACE assimilated groundwater storage for drought detection are discussed. An important conclusion of this study is that model parameters that control the depth to the water table, including bedrock depth, strongly influence the evolution and persistence of simulated groundwater and require careful configuration for drought monitoring.

Dynamics of monochromatically generated nonequilibrium phonons in LaF3:Pr3+

NASA Astrophysics Data System (ADS)

Tolbert, W. A.; Dennis, W. M.; Yen, W. M.

1990-07-01

The temporal evolution of nonequilibrium phonon populations in LaF3:Pr3+ is investigated at low temperatures (1.8 K) utilizing pulsed, tunable, monochromatic generation and time-resolved, tunable, narrow-band detection. High occupation number, narrow-band phonon populations are generated via far-infrared pumping of defect-induced one-phonon absorption. Time-resolved, frequency-selective detection is provided by optical sideband absorption. Nonequilibrium phonon decay times are measured and attributed to anharmonic decay.

Differential depth distribution of microbial function and putative symbionts through sediment-hosted aquifers in the deep terrestrial subsurface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Probst, Alexander J.; Ladd, Bethany; Jarett, Jessica K.

An enormous diversity of previously unknown bacteria and archaea has been discovered recently, yet their functional capacities and distributions in the terrestrial subsurface remain uncertain. Here, we continually sampled a CO 2-driven geyser (Colorado Plateau, Utah, USA) over its 5-day eruption cycle to test the hypothesis that stratified, sandstone-hosted aquifers sampled over three phases of the eruption cycle have microbial communities that differ both in membership and function. Genome-resolved metagenomics, single-cell genomics and geochemical analyses confirmed this hypothesis and linked microorganisms to groundwater compositions from different depths. Autotrophic Candidatus “Altiarchaeum sp.” and phylogenetically deep-branching nanoarchaea dominate the deepest groundwater. Amore » nanoarchaeon with limited metabolic capacity is inferred to be a potential symbiont of the Ca. “Altiarchaeum”. Candidate Phyla Radiation bacteria are also present in the deepest groundwater and they are relatively abundant in water from intermediate depths. During the recovery phase of the geyser, microaerophilic Fe- and S-oxidizers have high in situ genome replication rates. Autotrophic Sulfurimonas sustained by aerobic sulfide oxidation and with the capacity for N 2 fixation dominate the shallow aquifer. Overall, 104 different phylum-level lineages are present in water from these subsurface environments, with uncultivated archaea and bacteria partitioned to the deeper subsurface.« less

Differential depth distribution of microbial function and putative symbionts through sediment-hosted aquifers in the deep terrestrial subsurface

DOE PAGES

Probst, Alexander J.; Ladd, Bethany; Jarett, Jessica K.; ...

2018-01-29

An enormous diversity of previously unknown bacteria and archaea has been discovered recently, yet their functional capacities and distributions in the terrestrial subsurface remain uncertain. Here, we continually sampled a CO 2-driven geyser (Colorado Plateau, Utah, USA) over its 5-day eruption cycle to test the hypothesis that stratified, sandstone-hosted aquifers sampled over three phases of the eruption cycle have microbial communities that differ both in membership and function. Genome-resolved metagenomics, single-cell genomics and geochemical analyses confirmed this hypothesis and linked microorganisms to groundwater compositions from different depths. Autotrophic Candidatus “Altiarchaeum sp.” and phylogenetically deep-branching nanoarchaea dominate the deepest groundwater. Amore » nanoarchaeon with limited metabolic capacity is inferred to be a potential symbiont of the Ca. “Altiarchaeum”. Candidate Phyla Radiation bacteria are also present in the deepest groundwater and they are relatively abundant in water from intermediate depths. During the recovery phase of the geyser, microaerophilic Fe- and S-oxidizers have high in situ genome replication rates. Autotrophic Sulfurimonas sustained by aerobic sulfide oxidation and with the capacity for N 2 fixation dominate the shallow aquifer. Overall, 104 different phylum-level lineages are present in water from these subsurface environments, with uncultivated archaea and bacteria partitioned to the deeper subsurface.« less

Failures no More: The Radical Consequences of Realistic Stellar Feedback for Dwarf Galaxies, the Milky Way, and Reionization

NASA Astrophysics Data System (ADS)

Hopkins, Philip F.

2016-06-01

Many of the most fundamental unsolved questions in star and galaxy formation revolve around star formation and "feedback" from massive stars, in-extricably linking galaxy formation and stellar evolution. I'll present simulations with un-precedented resolution of Milky-Way (MW) mass galaxies, followed cosmologically to redshift zero. For the first time, these simulations resolve the internal structure of small dwarf satellites around a MW-like host, with detailed models for stellar evolution including radiation pressure, supernovae, stellar winds, and photo-heating. I'll show that, without fine-tuning, these feedback processes naturally resolve the "missing satellites," "too big to fail," and "cusp-core" problems, and produce realistic galaxy populations. At high redshifts however, the realistic ISM structure predicted, coupled to standard stellar population models, naively leads to the prediction that only ~1-2% of ionizing photons can ever escape galaxies, insufficient to ionize the Universe. But these models assume all stars are single: if we account for binary evolution, the escape fraction increases dramatically to ~20% for the small, low-metallicity galaxies believed to ionize the Universe.

Star clusters in evolving galaxies

NASA Astrophysics Data System (ADS)

Renaud, Florent

2018-04-01

Their ubiquity and extreme densities make star clusters probes of prime importance of galaxy evolution. Old globular clusters keep imprints of the physical conditions of their assembly in the early Universe, and younger stellar objects, observationally resolved, tell us about the mechanisms at stake in their formation. Yet, we still do not understand the diversity involved: why is star cluster formation limited to 105M⊙ objects in the Milky Way, while some dwarf galaxies like NGC 1705 are able to produce clusters 10 times more massive? Why do dwarfs generally host a higher specific frequency of clusters than larger galaxies? How to connect the present-day, often resolved, stellar systems to the formation of globular clusters at high redshift? And how do these links depend on the galactic and cosmological environments of these clusters? In this review, I present recent advances on star cluster formation and evolution, in galactic and cosmological context. The emphasis is put on the theory, formation scenarios and the effects of the environment on the evolution of the global properties of clusters. A few open questions are identified.

Thermal footprints in groundwater of central European cities

NASA Astrophysics Data System (ADS)

Bayer, P.; Menberg, K.; Blum, P.

2014-12-01

Atmospheric thermal pollution in densely populated areas is recognized as a severe problem with consequences for human health, and considerable efforts are being taken to mitigate heat stress in cities. However, anthropogenic activities also influence the thermal environment beneath the ground level, with commonly growing temperatures that affect groundwater ecology and geothermal use efficiency. In our work, we identify the controlling mechanisms for the long-term evolution of such urban heat islands. The shallow groundwater temperatures in several central European cities such as Cologne, Karlsruhe, Munich, Berlin and Zurich were mapped at high spatial and temporal resolution. Thermal anomalies were found to be highly heterogeneous with local hot spots showing temperatures of more than 20°C. Accordingly, these urban regions show a considerable groundwater warming in comparison to undisturbed temperatures of 8-11°C. Examination of potential heat sources by analytical modelling reveals that increased ground surface temperatures and basements of buildings act as dominant drivers for the anthropogenic heat input into the groundwater. The factors are revealed to be case-specific and they may have pronounced local or regional effects. Typical local factors are for example buried district heating networks. In selected cities we find that the average urban heat flux is around one order of magnitude higher than the elevated ground heat flux due to recent climate change. Additionally, such as observed in Zurich, naturally controlled temperature variations can be substantial and they are shown to wash out anthropogenic thermal footprints.

Springwater geochemistry at Honey Creek State Natural Area, central Texas: Implications for surface water and groundwater interaction in a karst aquifer

NASA Astrophysics Data System (ADS)

Musgrove, M.; Stern, L. A.; Banner, J. L.

2010-06-01

SummaryA two and a half year study of two adjacent watersheds at the Honey Creek State Natural Area (HCSNA) in central Texas was undertaken to evaluate spatial and temporal variations in springwater geochemistry, geochemical evolution processes, and potential effects of brush control on karst watershed hydrology. The watersheds are geologically and geomorphologically similar, and each has springs discharging into Honey Creek, a tributary to the Guadalupe River. Springwater geochemistry is considered in a regional context of aquifer components including soil water, cave dripwater, springwater, and phreatic groundwater. Isotopic and trace element variability allows us to identify both vadose and phreatic groundwater contributions to surface water in Honey Creek. Spatial and temporal geochemical data for six springs reveal systematic differences between the two watersheds. Springwater Sr isotope values lie between values for the limestone bedrock and soils at HCSNA, reflecting a balance between these two primary sources of Sr. Sr isotope values for springs within each watershed are consistent with differences between soil compositions. At some of the springs, consistent temporal variability in springwater geochemistry (Sr isotopes, Mg/Ca, and Sr/Ca values) appears to reflect changes in climatic and hydrologic parameters (rainfall/recharge) that affect watershed processes. Springwater geochemistry was unaffected by brush removal at the scale of the HCSNA study. Results of this study build on previous regional studies to provide insight into watershed hydrology and regional hydrologic processes, including connections between surface water, vadose groundwater, and phreatic groundwater.

Multidimensional Time-Resolved Spectroscopy of Vibrational Coherence in Biopolyenes

NASA Astrophysics Data System (ADS)

Buckup, Tiago; Motzkus, Marcus

2014-04-01

Multidimensional femtosecond time-resolved vibrational coherence spectroscopy allows one to investigate the evolution of vibrational coherence in electronic excited states. Methods such as pump-degenerate four-wave mixing and pump-impulsive vibrational spectroscopy combine an initial ultrashort laser pulse with a nonlinear probing sequence to reinduce vibrational coherence exclusively in the excited states. By carefully exploiting specific electronic resonances, one can detect vibrational coherence from 0 cm-1 to over 2,000 cm-1 and map its evolution. This review focuses on the observation and mapping of high-frequency vibrational coherence for all-trans biological polyenes such as β-carotene, lycopene, retinal, and retinal Schiff base. We discuss the role of molecular symmetry in vibrational coherence activity in the S1 electronic state and the interplay of coupling between electronic states and vibrational coherence.

Time-resolved structural dynamics of thin metal films heated with femtosecond optical pulses.

PubMed

Chen, Jie; Chen, Wei-Kan; Tang, Jau; Rentzepis, Peter M

2011-11-22

We utilize 100 fs optical pulses to induce ultrafast disorder of 35- to 150-nm thick single Au(111) crystals and observe the subsequent structural evolution using 0.6-ps, 8.04-keV X-ray pulses. Monitoring the picosecond time-dependent modulation of the X-ray diffraction intensity, width, and shift, we have measured directly electron/phonon coupling, phonon/lattice interaction, and a histogram of the lattice disorder evolution, such as lattice breath due to a pressure wave propagating at sonic velocity, lattice melting, and recrystallization, including mosaic formation. Results of theoretical simulations agree and support the experimental data of the lattice/liquid phase transition process. These time-resolved X-ray diffraction data provide a detailed description of all the significant processes induced by ultrafast laser pulses impinging on thin metallic single crystals.

Pulse retrieval algorithm for interferometric frequency-resolved optical gating based on differential evolution.

PubMed

Hyyti, Janne; Escoto, Esmerando; Steinmeyer, Günter

2017-10-01

A novel algorithm for the ultrashort laser pulse characterization method of interferometric frequency-resolved optical gating (iFROG) is presented. Based on a genetic method, namely, differential evolution, the algorithm can exploit all available information of an iFROG measurement to retrieve the complex electric field of a pulse. The retrieval is subjected to a series of numerical tests to prove the robustness of the algorithm against experimental artifacts and noise. These tests show that the integrated error-correction mechanisms of the iFROG method can be successfully used to remove the effect from timing errors and spectrally varying efficiency in the detection. Moreover, the accuracy and noise resilience of the new algorithm are shown to outperform retrieval based on the generalized projections algorithm, which is widely used as the standard method in FROG retrieval. The differential evolution algorithm is further validated with experimental data, measured with unamplified three-cycle pulses from a mode-locked Ti:sapphire laser. Additionally introducing group delay dispersion in the beam path, the retrieval results show excellent agreement with independent measurements with a commercial pulse measurement device based on spectral phase interferometry for direct electric-field retrieval. Further experimental tests with strongly attenuated pulses indicate resilience of differential-evolution-based retrieval against massive measurement noise.

Hydrochemistry of surface water and groundwater in the shale bedrock, Cross River Basin and Niger Delta Region, Nigeria

NASA Astrophysics Data System (ADS)

Nganje, T. N.; Hursthouse, A. S.; Edet, Aniekan; Stirling, D.; Adamu, C. I.

2017-05-01

Water chemistry in the shale bedrock of the Cretaceous-Tertiary of the Cross River and Niger Delta hydrological basins has been investigated using major ions. To carry out a characterization of the water bearing units, 30 and 16 representatives surface and groundwater samples were collected. The evolution of the water is characterized by enhanced content of sodium, calcium and sulphate as a result of leaching of shale rock. The spatial changes in groundwater quality of the area shows an anomalous concentrations of ions in the central parts, while lower values characterize the eastern part of the basin covering Ogoja, Ikom and Odukpani areas. The values of total dissolved solids (TDS) and ions increases down gradient in the direction of groundwater flow. The dissolution of halite and gypsum explains part of the contained Na+, Ca2+, Cl- and SO4 2-, but other processes such as ion exchange, silicate weathering and pyrite oxidation also contribute to water composition. The assessment with contamination indicators such as TDS, hardness, chloride, nitrate and sulphate indicates that the water in area is suitable for human consumption in some locations. Modelling using MINTEQA2 program shows that the water from all the shale water bearing units are under saturated with respect to gypsum.

Distributed Temperature Sensing - a Useful Tool for Investigation of Surface Water - Groundwater Interaction

NASA Astrophysics Data System (ADS)

Vogt, T.; Hahn-Woernle, L.; Sunarjo, B.; Thum, T.; Schneider, P.; Schirmer, M.; Cirpka, O. A.

2009-04-01

In recent years, the transition zone between surface water bodies and groundwater, known as the hyporheic zone, has been identified as crucial for the ecological status of the open-water body and the quality of groundwater. The hyporheic exchange processes vary both in time and space. For the assessment of water quality of both water bodies reliable models and measurements of the exchange rates and their variability are needed. A wide range of methods and technologies exist to estimate water fluxes between surface water and groundwater. Due to recent developments in sensor techniques and data logging work on heat as a tracer in hydrological systems advances, especially with focus on surface water - groundwater interactions. Here, we evaluate the use of Distributed Temperature Sensing (DTS) for the qualitative and quantitative investigation of groundwater discharge into and groundwater recharge from a river. DTS is based on the temperature dependence of Raman scattering. Light from a laser pulse is scattered along an optical fiber of up to several km length, which is the sensor of the DTS system. By sampling the the back-scattered light with high temporal resolution, the temperature along the fiber can be measured with high accuracy (0.1 K) and high spatial resolution (1 m). We used DTS at a test side at River Thur in North-East Switzerland. Here, the river is loosing and the aquifer is drained by two side-channels, enabling us to test DTS for both, groundwater recharge from the river and groundwater discharge into the side-channels. For estimation of seepage rates, we measured highly resolved vertical temperature profiles in the river bed. For this application, we wrapped an optical fiber around a piezometer tube and measured the temperature distribution along the fiber. Due to the wrapping, we obtained a vertical resolution of approximately 5 mm. We analyzed the temperature time series by means of Dynamic Harmonic Regression as presented by Keery et al. (2007). From the travel time and attenuation of the diurnal time signal, we estimated the apparent velocity and diffusivity of temperature propagation, which then can be used to quantify infiltration rates. A particular strength of the new measuring technique lies in the high spatial and temporal resolution, enabling us to detect non-uniformity and temporal changes in vertical water fluxes. In the side-channels, we have laterally laid out optical fibers to detect zones of groundwater discharge. As groundwater temperatures differ from river temperatures, local exfiltration of groundwater leads to a local change of the temperature at the river bottom. A limitation of lateral DTS data is that exchange rates cannot directly be quantified. Therefore, we used DTS for streambed temperature mapping. Then certain exfiltration zones undergo further investigation using time series of streambed temperature profiles obtained in piezometers. J. Keery, A. Binley, N. Crook and J.W.N. Smith (2007) Temporal and spatial variability of groundwater-surface water fluxes: Development and application of an analytical method using temperature time series, Journal of Hydrology, 336, 1-16.

Helium isotope studies in the Mojave Desert, California: Implications for groundwater chronology and regional seismicity

USGS Publications Warehouse

Kulongoski, J.T.; Hilton, David R.; Izbicki, J.A.

2003-01-01

We report helium isotope and concentration results for groundwaters from the western Mojave River Basin (MRB), 130 km east of Los Angeles, CA. The basin lies adjacent to the NW-SE trending San Andreas Fault (SAF) system. Samples were collected along two groundwater flowpaths that originate in the San Gabriel Mountains and discharge to the Mojave River located ???32 km to the northeast. Additional groundwater samples were collected from Mojave River Deposits underlying the Mojave River. The primary objective of this study is to identify and quantify crustal and mantle helium contributions to the regional groundwater system. A total of 27 groundwaters, sampled previously for chemistry and isotope systematics (including 14C activity) have measured helium concentrations that increase along flowpaths from 9.9??10-8 to 1.0??10-4 cm3 STP g-1 H2O. Concomitantly, 3He/4He ratios decrease from 0.84RA to 0.11RA (RA equals the 3He/4He ratio in air=1.4??10-6). We did not record 3He/4He ratios equivalent to crustal-production values (???0.02RA) in any sample. Dissolved helium concentrations were resolved into components associated with solubility equilibration, air entrainment, mantle-derivation, in-situ production within the aquifer, and extraneous crustal fluxes. All samples contained the first four components, but only older samples had the superimposed effects of helium derived from a crustal flux. The radiogenic He component has chronological significance, and good concordance between 4He and 14C ages for younger groundwaters (<25,000 year) demonstrates the integrity of the 4 He-chronometer in this setting. Helium-rich waters could also be dated with the 4He technique, but only by first isolating the whole crustal flux (3-10??10-6 cm3 STP cm-2 year-1). Mantle-derived 3He (3Hem) is present in all MRB samples irrespective of distance from the SAF. However, regional-aquifer groundwaters near the terminus of the flowpath have a significantly greater content of mantle-derived 3He in comparison with more modern samples. We propose that faults in the basin other than the SAF may be an additional source of mantle-derived helium. The large range in 3He m concentrations may be related to fault activity; however, groundwaters with lower and more constant 3Hem contents may indicate that seismic activity along the SAF has been relatively constant for the past 30,000 years, demonstrating that ancient groundwaters may serve as an archive for paleo-seismic events. ?? 2003 Elsevier B.V. All rights reserved. All rights reserved.

Groundwater Resources Evolution in Degrading Permafrost Environments: A Small Catchment-Scale Study in Northern Quebec, Canada

NASA Astrophysics Data System (ADS)

Molson, John; Lemieux, Jean-Michel; Fortier, Richard; Therrien, Rene; Ouellet, Michel; Barth, Johannes; van Geldern, Robert; Cochand, Marion; Sottas, Jonathan; Murray, Renaud; Banville, David

2015-04-01

A two square kilometre catchment in a discontinuous permafrost zone near the Inuit community of Umiujaq on the eastern shore of Hudson Bay in Northern Quebec, Canada, is being investigated to determine the impact of permafrost degradation on groundwater resources. The catchment, which became deglaciated about 7500 years ago, lies in a valley which includes about 30-40 m of glacial-fluvial and marine Quaternary sediments. Permafrost mounds at the site extend from a few meters below ground surface to depths of about 10-30 m. Instrumentation has been installed to measure groundwater levels and temperature, as well as groundwater and surface water geochemistry, isotope signatures (including δ18O and 3H) and stream flow. Preliminary groundwater isotope data reflect depleted δ18O signals that differ from expected values for local groundwater, possibly representing permafrost thaw. In addition, stable water isotopes indicate evaporation from shallow thermokarst lakes. Meteorological conditions including air temperatures, precipitation and snowpack are also being monitored. Near-surface geophysical surveys using electrical resistivity tomography (ERT), induced polarization tomography (IPT), georadar and seismic refraction tomography have been carried out to characterize the catchment and to build a 3D geological site model. A numerical model of coupled groundwater flow and heat transport, including thermal advection, conduction, freeze-thaw and latent heat, is being developed for the site to help develop the conceptual model and to assess future impacts of permafrost degradation due to climate warming. The model (Heatflow/3D) includes nonlinear functions for the temperature-dependent unfrozen moisture content and relative permeability, and has been tested against analytical solutions and using benchmarks developed by the INTERFROST modelling consortium. A conceptual 2D vertical-plane model including several permafrost mounds along a 1 km section shows dynamic seasonal behavior with preferential melting from below due to sub-permafrost horizontal groundwater flow and upward flow to surface water through taliks. Under current environmental conditions, the simulations suggest the remaining permafrost in the basin could completely thaw within 50 years. The long-term monitoring program in the catchment will help develop optimal investigative methods for monitoring hydrogeological systems and groundwater resources under permafrost-degrading conditions, and will help determine how new groundwater resources may become available for northern communities as permafrost thaws and recharge to aquifers increases.

Mineralogical Evidence for the Palaeohydrogeological Stability of a Deep Groundwater System in Fractured Rock, in West Cumbria, Northwest England

NASA Astrophysics Data System (ADS)

Milodowski, A. E.; Gillespie, M. R.; Chenery, S. R. N.; Naden, J.; Shaw, R. P.

2014-12-01

An important requirement of the safety assessment for a geological disposal facility (GDF) for radioactive waste is to be able to demonstrate the long-term chemical stability of the groundwater system at repository depth over the long period of time during which the waste will be a hazard, typically up to one million years. Of particular concern in the UK is the potential for oxidising groundwater to penetrate to repository depth during periods of glaciation, thereby increasing the mobility of some transuranic radionuclides.Between 1990 and 1998, United Kingdom Nirex Limited carried out geological investigations into the suitability of a potential site in the Sellafield area of NW England, for a GDF for L/ILW. As part of these investigations, detailed petrological analysis of fracture mineralisation in 23 deep boreholes identified a complex sequence of mineralisation events referred to as ME1-ME9. The distribution of the ME9 calcite mineralisation correlates closely with present-day groundwater flows. The ME9 calcite has been studied in more detail to understand the evolution of the deep groundwater system. The morphology and growth zoning characteristics of the calcites reflects the groundwater chemistry. Freshwater calcites display c-axis flattened to equant crystals, and are non-ferroan and strongly zoned with Mn-rich and Mn-free bands. Deeper saline-zone calcites display c-axis elongated crystals, with high Mn:Fe and low Mn:Fe growth zones. Calcite in the transition zone between the saline and fresh groundwater display saline-type cores overgrown by freshwater-type calcite, indicating a small depression of the position of the transition zone during the growth of the calcites. Sr isotope ratios and fluid inclusion chemistry confirm a link between ME9 calcite and the present regional groundwater system. Modelling of the oxygen isotope data indicates that some growth zones in the ME9 calcite precipitated from groundwater potentially containing a significant proportion of glacially-recharged water, and that this may have reached depths of up to 1000 m. However, the chemical (REE,Fe and Mn) compositions of the ME9 calcite show that despite the potential contribution of glacially-recharged water to the deep groundwater system, conditions at repository depth (< 500 m) have continually remained reducing.

The changing trend in nitrate concentrations in major aquifers due to historical nitrate loading from agricultural land across England and Wales from 1925 to 2150.

PubMed

Wang, L; Stuart, M E; Lewis, M A; Ward, R S; Skirvin, D; Naden, P S; Collins, A L; Ascott, M J

2016-01-15

Nitrate is necessary for agricultural productivity, but can cause considerable problems if released into aquatic systems. Agricultural land is the major source of nitrates in UK groundwater. Due to the long time-lag in the groundwater system, it could take decades for leached nitrate from the soil to discharge into freshwaters. However, this nitrate time-lag has rarely been considered in environmental water management. Against this background, this paper presents an approach to modelling groundwater nitrate at the national scale, to simulate the impacts of historical nitrate loading from agricultural land on the evolution of groundwater nitrate concentrations. An additional process-based component was constructed for the saturated zone of significant aquifers in England and Wales. This uses a simple flow model which requires modelled recharge values, together with published aquifer properties and thickness data. A spatially distributed and temporally variable nitrate input function was also introduced. The sensitivity of parameters was analysed using Monte Carlo simulations. The model was calibrated using national nitrate monitoring data. Time series of annual average nitrate concentrations along with annual spatially distributed nitrate concentration maps from 1925 to 2150 were generated for 28 selected aquifer zones. The results show that 16 aquifer zones have an increasing trend in nitrate concentration, while average nitrate concentrations in the remaining 12 are declining. The results are also indicative of the trend in the flux of groundwater nitrate entering rivers through baseflow. The model thus enables the magnitude and timescale of groundwater nitrate response to be factored into source apportionment tools and to be taken into account alongside current planning of land-management options for reducing nitrate losses. Copyright © 2015 The Authors. Published by Elsevier B.V. All rights reserved.

Groundwater sapping processes, Western Desert, Egypt.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luo, W.; Arvidson, R.E.; Sultan, M.

1997-01-01

Depressions of the Western Desert of Egypt (specifically, Kharga, Farafra, and Kurkur regions) are mainly occupied by shales that are impermeable, but easily erodible by rainfall and runoff, whereas the surrounding plateaus are composed of limestones that are permeable and more resistant to fluvial erosion under semiarid to arid conditions. Scallop-shaped escarpment edges and stubby-looking channels that cut into the plateau units are suggestive of slumping of limestones by ground-water sapping at the limestone-shale interfaces, removal of slump blocks by weathering and fluvial erosion, and consequent scarp retreat. Spring-derived tufa deposits found near the limestone escarpments provide additional evidence formore » possible ground-water sapping during previous wet periods. A computer simulation model was developed to quantify the ground-water sapping processes, using a cellular automata algorithm with coupled surface runoff and ground-water flow for a permeable, resistant layer over an impermeable, friable unit. Erosion, deposition, slumping, and generation of spring-derived tufas were parametrically modeled. Simulations using geologically reasonable parameters demonstrate that relatively rapid erosion of the shales by surface runoff, ground-water sapping, and slumping of the limestones, and detailed control by hydraulic conductivity inhomogeneities associated with structures explain the depressions, escarpments, and associated landforms and deposits. Using episodic wet pulses, keyed by {delta}{sup 18}O deep-sea core record, the model produced tufa ages that are statistically consistent with the observed U/Th tufa ages. This result supports the hypothesis that northeastern African wet periods occurred during interglacial maxima. The {delta}{sup 18}O-forced model also replicates the decrease in fluvial and sapping activity over the past million years, as northeastern Africa became hyperarid. The model thus provides a promising predictive tool for studying long-term landform evolution that involves surface and subsurface processes and climatic change.« less

Chemical and isotopic evidence for hydrogeochemical processes occurring in the Lincolnshire Limestone

NASA Astrophysics Data System (ADS)

Bishop, Philip K.; Lloyd, John W.

1990-12-01

Over 150 groundwater samples from the Lincolnshire Limestone have been analysed for pH, major ions and δ 13C ratios. Where possible, field E h and iodide concentrations were measured and methane concentrations were determined for 12 samples. Stable isotope ratios were determined for soil and rock carbonate samples. A system of zonation allows the division of hydrogeochemical processes occurring in the aquifer. The use of hydrochemical and isotope data in modelling exercises enables the re-evaluation and possible enhancement of the understanding of hydrogeochemical processes. The carbonate chemistry of outcrop groundwaters is explained by calcite saturation being achieved under open-system conditions in the soil zone. δ 13C ratios in the range - 15.99 to - 10.57‰ may be generated from a stoichiometric reaction with possible additional partial and/or simultaneous exchange with soil CO 2 or carbonate. The isotopic composition of soil carbonate shows the effects of precipitation from soil waters. The incongruent dissolution of primary depositional limestone carbonate results in increasing magnesium and strontium concentrations and increasing δ 13C ratios for the groundwaters with flow down the hydraulic gradient. As a result of incongruent dissolution, secondary calcite may be precipitated onto fissure surfaces. Significant nitrate and sulphate reduction in non-saline groundwaters is not supported by the results of hydrochemical and isotope modelling exercises. However, sulphate reduction and methane fermentation may be affecting the isotopic and chemical compositions of saline groundwaters. Sodium-calcium ion exchange leads to limited calcite dissolution deep in the aquifer, but the evolution of these groundwaters is confused by the uncertain effects of oxidation of organic carbon and mixing with a saline end-member solution.

Assessing Sea Level Rise Impacts on the Surficial Aquifer in the Kennedy Space Center Region

NASA Astrophysics Data System (ADS)

Xiao, H.; Wang, D.; Hagen, S. C.; Medeiros, S. C.; Warnock, A. M.; Hall, C. R.

2014-12-01

Global sea level rise in the past century due to climate change has been seen at an average rate of approximately 1.7-2.2 mm per year, with an increasing rate over the next century. The increasing SLR rate poses a severe threat to the low-lying land surface and the shallow groundwater system in the Kennedy Space Center in Florida, resulting in saltwater intrusion and groundwater induced flooding. A three-dimensional groundwater flow and salinity transport model is implemented to investigate and evaluate the extent of floods due to rising water table as well as saltwater intrusion. The SEAWAT model is chosen to solve the variable-density groundwater flow and salinity transport governing equations and simulate the regional-scale spatial and temporal evolution of groundwater level and chloride concentration. The horizontal resolution of the model is 50 m, and the vertical domain includes both the Surficial Aquifer and the Floridan Aquifer. The numerical model is calibrated based on the observed hydraulic head and chloride concentration. The potential impacts of sea level rise on saltwater intrusion and groundwater induced flooding are assessed under various sea level rise scenarios. Based on the simulation results, the potential landward movement of saltwater and freshwater fringe is projected. The existing water supply wells are examined overlaid with the projected salinity distribution map. The projected Surficial Aquifer water tables are overlaid with data of high resolution land surface elevation, land use and land cover, and infrastructure to assess the potential impacts of sea level rise. This study provides useful tools for decision making on ecosystem management, water supply planning, and facility management.

The Colorado River and its deposits downstream from Grand Canyon in Arizona, California, and Nevada

USGS Publications Warehouse

Crow, Ryan S.; Block, Debra L.; Felger, Tracey J.; House, P. Kyle; Pearthree, Philip A.; Gootee, Brian F.; Youberg, Ann M.; Howard, Keith A.; Beard, L. Sue

2018-02-05

Understanding the evolution of the Colorado River system has direct implications for (1) the processes and timing of continental-scale river system integration, (2) the formation of iconic landscapes like those in and around Grand Canyon, and (3) the availability of groundwater resources. Spatial patterns in the position and type of Colorado River deposits, only discernible through geologic mapping, can be used to test models related to Colorado River evolution. This is particularly true downstream from Grand Canyon where ancestral Colorado River deposits are well-exposed. We are principally interested in (1) regional patterns in the minimum and maximum elevation of each depositional unit, which are affected by depositional mechanism and postdepositional deformation; and (2) the volume of each unit, which reflects regional changes in erosion, transport efficiency, and accommodation space. The volume of Colorado River deposits below Grand Canyon has implications for groundwater resources, as the primary regional aquifer there is composed of those deposits. To this end, we are presently mapping Colorado River deposits and compiling and updating older mapping. This preliminary data release shows the current status of our mapping and compilation efforts. We plan to update it at regular intervals in conjunction with ongoing mapping.

Steel Sheet Piles - Applications and Elementary Design Issues

NASA Astrophysics Data System (ADS)

Sobala, Dariusz; Rybak, Jarosław

2017-10-01

High-intensity housing having been carried out in town’s centres causes that many complex issues related to earthworks and foundations must be resolved. Project owners are required to ensure respective number of parking bays, which in turn demands 2-3 storeys of underground car parks. It is especially difficult to fulfil in dense buildings of old town areas where apart from engineering problems, very stringent requirements of heritage conservator supervision are also raised. The problems with ensuring stability of excavation sidewalls need to be, at the same time, dealt with analysis of foundations of neighbouring structures, and possible strengthening them at the stages of installing the excavation protection walls, progressing the excavations and constructing basement storeys. A separate problem refers to necessity of constructing underground storeys below the level of local groundwater. This requires long-term lowering of water table inside excavation while at possibly limited intervention in hydrological regime beyond the project in progress. In river valleys such “hoarding off” the excavation and cutting off groundwater leads to temporary or permanent disturbances of groundwater run-off and local swellings. Traditional way to protect vertical fault and simultaneously to cut-off groundwater inflow consists in application of steel sheet pilings. They enable to construct monolithic reinforced concrete structures of underground storeys thus ensuring both their tightness and high rigidity of foundation. Depending on situation, steel sheet pilings can be in retrieving or staying-in-place versions. This study deals with some selected aspects of engineering design and fabrication of sheet piling for deep excavations and underground parts of buildings.

Dynamic surface water-groundwater exchange and nitrogen transport in the riparian aquifer of a tidal river

NASA Astrophysics Data System (ADS)

Sawyer, A. H.; Barnes, R.; Wallace, C.; Knights, D.; Tight, D.; Bayer, M.

2017-12-01

Tides in coastal rivers can propagate tens to hundreds of kilometers inland and drive large daily changes in water and nitrogen exchange across the sediment-water interface. We use field observations and numerical models to illuminate hydrodynamic controls on nitrogen export from the riparian aquifer to a fresh, tidal reach of White Clay Creek (Delaware, USA). In the banks, an aerobic zone with high groundwater nitrate concentrations occurs near the fluctuating water table. Continuous depth-resolved measurements of redox potential suggest that this zone is relatively stable over tidal timescales but moves up or down in response to storms. The main source of dissolved oxygen is soil air that is imbibed in the zone of water table fluctuations, and the source of nitrate is likely nitrification of ammonium produced locally from the mineralization of organic matter in floodplain soils. Much of the nitrate is removed by denitrification along oscillating flow paths towards the channel. Within centimeters of the sediment-water interface, denitrification is limited by the mixing of groundwater with oxygen-rich river water. Our models predict that the benthic zones of tidal rivers play an important role in removing new nitrate inputs from discharging groundwater but may be less effective at removing nitrate from river water. Nitrate removal and production rates are expected to vary significantly along tidal rivers as permeability, organic matter content, tidal range vary. It is imperative that we understand nitrogen dynamics along tidal rivers and their role in nitrogen export to the coast.

What can we learn from in-soil imaging of a live plant: X-ray Computed Tomography and 3D numerical simulation of root-soil system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Xiaofan; Varga, Tamas; Liu, Chongxuan

Plant roots play a critical role in plant-soil-microbe interactions that occur in the rhizosphere. X-ray Computed Tomography (XCT) has been proven to be an effective tool for non-invasive root imaging and analysis. A combination of XCT, open-source software, and in-house developed code was used to non-invasively image a prairie dropseed (Sporobolus heterolepis) specimen, segment the root data to obtain a 3D image of the root structure, and extract quantitative information from the 3D data, respectively. Based on the explicitly-resolved root structure, pore-scale computational fluid dynamics (CFD) simulations were applied to numerically investigate the root-soil-groundwater system. The plant root conductivity, soilmore » hydraulic conductivity and transpiration rate were shown to control the groundwater distribution. Furthermore, the coupled imaging-modeling approach demonstrates a realistic platform to investigate rhizosphere flow processes and would be feasible to provide useful information linked to upscaled models.« less

What can we learn from in-soil imaging of a live plant: X-ray Computed Tomography and 3D numerical simulation of root-soil system

DOE PAGES

Yang, Xiaofan; Varga, Tamas; Liu, Chongxuan; ...

2017-05-04

Plant roots play a critical role in plant-soil-microbe interactions that occur in the rhizosphere. X-ray Computed Tomography (XCT) has been proven to be an effective tool for non-invasive root imaging and analysis. A combination of XCT, open-source software, and in-house developed code was used to non-invasively image a prairie dropseed (Sporobolus heterolepis) specimen, segment the root data to obtain a 3D image of the root structure, and extract quantitative information from the 3D data, respectively. Based on the explicitly-resolved root structure, pore-scale computational fluid dynamics (CFD) simulations were applied to numerically investigate the root-soil-groundwater system. The plant root conductivity, soilmore » hydraulic conductivity and transpiration rate were shown to control the groundwater distribution. Furthermore, the coupled imaging-modeling approach demonstrates a realistic platform to investigate rhizosphere flow processes and would be feasible to provide useful information linked to upscaled models.« less

Potential for Small Unmanned Aircraft Systems applications for identifying groundwater-surface water exchange in a meandering river reach

USGS Publications Warehouse

Pai, H.; Malenda, H.; Briggs, Martin A.; Singha, K.; González-Pinzón, R.; Gooseff, M.; Tyler, S.W.; ,

2017-01-01

The exchange of groundwater and surface water (GW-SW), including dissolved constituents and energy, represents a critical yet challenging characterization problem for hydrogeologists and stream ecologists. Here, we describe the use of a suite of high spatial-resolution remote-sensing techniques, collected using a small unmanned aircraft system (sUAS), to provide novel and complementary data to analyze GW-SW exchange. sUAS provided centimeter-scale resolution topography and water surface elevations, which are often drivers of exchange along the river corridor. Additionally, sUAS-based vegetation imagery, vegetation-top elevation, and normalized difference vegetation index (NDVI) mapping indicated GW-SW exchange patterns that are difficult to characterize from the land surface and may not be resolved from coarser satellite-based imagery. We combined these data with estimates of sediment hydraulic conductivity to provide a direct estimate of GW “shortcutting” through meander necks, which was corroborated by temperature data at the riverbed interface.

Potential for Small Unmanned Aircraft Systems Applications for Identifying Groundwater-Surface Water Exchange in a Meandering River Reach

NASA Astrophysics Data System (ADS)

Pai, H.; Malenda, H. F.; Briggs, M. A.; Singha, K.; González-Pinzón, R.; Gooseff, M. N.; Tyler, S. W.

2017-12-01

The exchange of groundwater and surface water (GW-SW), including dissolved constituents and energy, represents a critical yet challenging characterization problem for hydrogeologists and stream ecologists. Here we describe the use of a suite of high spatial resolution remote sensing techniques, collected using a small unmanned aircraft system (sUAS), to provide novel and complementary data to analyze GW-SW exchange. sUAS provided centimeter-scale resolution topography and water surface elevations, which are often drivers of exchange along the river corridor. Additionally, sUAS-based vegetation imagery, vegetation-top elevation, and normalized difference vegetation index mapping indicated GW-SW exchange patterns that are difficult to characterize from the land surface and may not be resolved from coarser satellite-based imagery. We combined these data with estimates of sediment hydraulic conductivity to provide a direct estimate of GW "shortcutting" through meander necks, which was corroborated by temperature data at the riverbed interface.

Energy-resolved coherent diffraction from laser-driven electronic motion in atoms

NASA Astrophysics Data System (ADS)

Shao, Hua-Chieh; Starace, Anthony F.

2017-10-01

We investigate theoretically the use of energy-resolved ultrafast electron diffraction to image laser-driven electronic motion in atoms. A chirped laser pulse is used to transfer the valence electron of the lithium atom from the ground state to the first excited state. During this process, the electronic motion is imaged by 100-fs and 1-fs electron pulses in energy-resolved diffraction measurements. Simulations show that the angle-resolved spectra reveal the time evolution of the energy content and symmetry of the electronic state. The time-dependent diffraction patterns are further interpreted in terms of the momentum transfer. For the case of incident 1-fs electron pulses, the rapid 2 s -2 p quantum beat motion of the target electron is imaged as a time-dependent asymmetric oscillation of the diffraction pattern.

Risk Assessment of Mineral Groundwater Near Rogaška Slatina

NASA Astrophysics Data System (ADS)

Trcek, Branka; Leis, Albrecht

2017-10-01

Groundwater resources of mineral and thermo-mineral water are invaluable for planning a sustainable spatial and economic development of the Rogaška Slatina area, which requires a protection of this natural heritage. Numerous previous investigations of Rogaška groundwaters were subjects to balneology and to demands for larger exploitation quantities, that is why information are missing that are essential for definition of the Rogaška fractured aquifer system with mineral and thermo-mineral water and for its protection. The isotopic investigations of groundwaters stored in the Rogaška Slatina fractured aquifer system were performed aiming at answering open questions on the groundwater recharge and dynamics, on connections between different types of aquifers and on solute transport. Environmental isotopes 2H, 18O, 3H, 13C of dissolved inorganic carbon and 14C were analysed in mineral, thermo-mineral and spring waters. Results indicated the source and mechanism of groundwater recharge, its renewability, a transit time distribution, hydraulic interrelationships, the groundwater origin and its evolution due to effects of water-rock interaction. The mean residence time estimates of mineral and thermo- mineral water in the aquifer are between 3400 and 14000 years. On the other hand, the mixing processes between younger and older waters or mineral and spring waters are reflected as well as waters that infiltrated predominantly after the 1960s. These suggest the vulnerability of the research systems to man-made impacts. The presented results coupled with available information on a physical hydrogeology and water chemistry asses the optimal balance between the environmental protection and economic use of mineral water resources in the study area. They are essential for the protection strategy development of mineral and thermo-mineral water in the Rogaška Slatina area bringing together the state administration and local authorities and stakeholders.

Interannual climate variability and spatially heterogeneous improvement of agricultural management impede detection of a decreasing trend in nitrate pollution in an agricultural catchment

NASA Astrophysics Data System (ADS)

Fovet, Ophélie; Dupas, Rémi; Durand, Patrick; Gascuel-Odoux, Chantal; Gruau, Gérard; Hamon, Yannick; Petitjean, Patrice

2016-04-01

Despite widespread implementation of the nitrate directive in the European Union since the 1990s, the impact on nitrate concentration in rivers is limited (Bouraoui and Grizzetti, 2011). To assess whether this lack of response is due to the long time lags of nitrate transfer or to inadequate programs of measure, long term river and groundwater monitoring data are necessary. This study analyses 15 years of daily nitrate concentration data at the outlet of an intensively farmed catchment in Western France (Kervidy-Naizin, 5 km²) and quarterly nitrate concentration data in the groundwater of two hillslopes equipped with piezometers (Kerroland and Gueriniec) within the same catchment. In this catchment groundwater contribution to annual stream flow is dominant. The objectives of this study were to i) disentangle the influence of interannual climate variability and improvement of agricultural practices (i.e. reduction in N surplus) in the stream chemistry and ii) discuss the reasons for slow catchment recovery from nitrate pollution by comparing trends in groundwater and stream concentrations. Analysis of stream data showed that flow-weighted mean annual concentration at the outlet of the Kervidy-Naizin catchment has decreased by 1.2 mg NO3- l-1 yr-1 from 1999 to 2015. This decrease was slow but significant (p value < 0.01) even though interannual climate variability (i.e. annual cumulated runoff) added noise to the signal: i) deviation in the linear model of nitrate decrease with time was negatively correlated with annual runoff (r = -0.54, p < 0.01) and ii) local minimums in the nitrate time series were coincident with local maximums in the annual runoff. Thus high runoff during wet years led to dilution of the nitrate originating from groundwater, which added variability to the signal of linear decrease in stream concentration. Analysis of groundwater data showed a significant and sharp decrease in nitrate concentration in the Kerroland piezometer transect (4.0 mg NO3- l-1 yr-1) and no significant evolution in the Gueriniec piezometer transect, from 1999 to 2015. This contrasting evolution of groundwater nitrate concentration between the two transects was consistent with data on soil surface nitrogen surplus, with a balanced fertilisation in the Kerroland transect (N surplus close to 0 kg N ha-1 yr-1) and excessive fertilisation in the Gueriniec transect (N surplus > 100 kg N ha-1 yr-1). We conclude that, despite the lags due to pluri annual nitrate transfer through the unsaturated and satured zones in catchments of Western France, significant decrease in nitrate concentration in groundwater and streams should be visible within less than 10 years after implementation of an efficient program of measures. Spatial heterogeneity in the implementation of programs of measures (i.e. reduction of N surplus) is a likely cause of slow, sometimes undetectable, reduction in nitrate concentration. Bouraoui, F., and Grizzetti, B.: Long term change of nutrient concentrations of rivers discharging in European seas, The Science of the total environment, 409, 4899-4916, 10.1016/j.scitotenv.2011.08.015, 2011.

DOE Office of Scientific and Technical Information (OSTI.GOV)

David, M.-L.; Pailloux, F.; Mauchamp, V.

The understanding of the mechanisms of helium bubble formation and evolution in materials requires the quantitative determination of several key quantities such as the helium density in the bubbles. Helium nanobubbles of about 16 nm in diameter were created in silicon by helium implantation at high fluence and subsequent annealing. Individual nanobubbles were analyzed by spatially resolved Electron Energy-loss Spectroscopy (EELS). We report on the in situ probing of helium desorption from the nanobubbles under electron irradiation. This opens new perspectives for a more accurate determination of the helium density through spatially resolved EELS.

Stochastic 2-D galaxy disk evolution models. Resolved stellar populations in the galaxy M33

NASA Astrophysics Data System (ADS)

Mineikis, T.; Vansevičius, V.

We improved the stochastic 2-D galaxy disk models (Mineikis & Vansevičius 2014a) by introducing enriched gas outflows from galaxies and synthetic color-magnitude diagrams of stellar populations. To test the models, we use the HST/ACS stellar photometry data in four fields located along the major axis of the galaxy M33 (Williams et al. 2009) and demonstrate the potential of the models to derive 2-D star formation histories in the resolved disk galaxies.

Time-resolved explosion of intense-laser-heated clusters.

PubMed

Kim, K Y; Alexeev, I; Parra, E; Milchberg, H M

2003-01-17

We investigate the femtosecond explosive dynamics of intense laser-heated argon clusters by measuring the cluster complex transient polarizability. The time evolution of the polarizability is characteristic of competition in the optical response between supercritical and subcritical density regions of the expanding cluster. The results are consistent with time-resolved Rayleigh scattering measurements, and bear out the predictions of a recent laser-cluster interaction model [H. M. Milchberg, S. J. McNaught, and E. Parra, Phys. Rev. E 64, 056402 (2001)

Spatio-temporally resolved spectral measurements of laser-produced plasma and semiautomated spectral measurement-control and analysis software

NASA Astrophysics Data System (ADS)

Cao, S. Q.; Su, M. G.; Min, Q.; Sun, D. X.; O'Sullivan, G.; Dong, C. Z.

2018-02-01

A spatio-temporally resolved spectral measurement system of highly charged ions from laser-produced plasmas is presented. Corresponding semiautomated computer software for measurement control and spectral analysis has been written to achieve the best synchronicity possible among the instruments. This avoids the tedious comparative processes between experimental and theoretical results. To demonstrate the capabilities of this system, a series of spatio-temporally resolved experiments of laser-produced Al plasmas have been performed and applied to benchmark the software. The system is a useful tool for studying the spectral structures of highly charged ions and for evaluating the spatio-temporal evolution of laser-produced plasmas.

Data analysis and hydrological modelling of frozen ground, shallow groundwater formation and river flow co-evolution at small watersheds of Russia in continuous, discontinuous permafrost and the zone of seasonal ground freezing

NASA Astrophysics Data System (ADS)

Lebedeva, Luidmila; Semenova, Olga

2015-04-01

Frozen ground distribution and its properties control the presence of aquifuge and aquifers. Correct representation of interactions between infiltrating water, ground ice, permafrost or seasonal freezing table and river flow is challenging for hydrological modelling in cold regions. Observational data of ground water levels, thawing depths in different landscapes or topographical units and meteorological information with high temporal and spatial resolution are required to analyze seasonal and interannual evolution of groundwater in active layer and its linkage to river flow. Such data are extremely rare in vast and remote regions of Russia. There are few historical datasets inherited from former USSR containing unique collection of long-term daily observations of water fluxes, frozen ground characteristics and groundwater levels. The data from three water balance stations were employed in our study with overall goal to analyze co-evolution of thawing layer, shallow groundwater and river flow by data processing and process-based modelling. Three instrumented small watersheds are situated in continuous, discontinuous permafrost zones and at the territory with seasonally frozen ground. They present different climates, landscapes and geology. The Kolyma water-balance station is located in mountainous region of continuous permafrost in North-Eastern Russia. The watershed area of 22 km2 is covered by bare rocks, mountain tundra, sparse larch forest and wet larch forest depending on slope aspect and inclination. The Bomnak water-balance station (22 km2) is situated in discontinuous permafrost zone in upper part of the Amur River basin and characterized by unmerged permafrost. Dominant landscapes are birch forest and bogs. The Pribaltiyskaya water-balance station (40 km2) located in Latvia is characterized by seasonally frozen ground and is covered by mixed forest and arable land. Process-based Hydrograph model was employed in the study. The model was developed specifically for cold regions. It describes all essential processes of land hydrological cycle including detailed algorithm of water and heat dynamics in soil accounting for water phase change. The model parameters relate to basin characteristics and could be assessed in the field. It allows avoiding parameters calibration and transferring model parameterization schemes to ungauged basins in similar conditions. The model was applied and tested against internal states of watersheds (snow, soil thawing/freezing, etc.) and runoff. Different role of frozen ground in formation of shallow groundwater and river flow in continuous, discontinuous and non-permafrost area is highlighted by comparative analysis of observations and simulations in three studied basins. The changes of fractional input of surface and subsurface components into river flow during warm seasons were assessed for each watershed. We concluded that verified hydrological model with meaningful parameters that adequately describe river flow formation and internal hydrological processes and ground freezing/thawing in the catchment could be used in scenario simulations, future predictions and transferring the results between scales.

Scale separation for multi-scale modeling of free-surface and two-phase flows with the conservative sharp interface method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, L.H., E-mail: Luhui.Han@tum.de; Hu, X.Y., E-mail: Xiangyu.Hu@tum.de; Adams, N.A., E-mail: Nikolaus.Adams@tum.de

In this paper we present a scale separation approach for multi-scale modeling of free-surface and two-phase flows with complex interface evolution. By performing a stimulus-response operation on the level-set function representing the interface, separation of resolvable and non-resolvable interface scales is achieved efficiently. Uniform positive and negative shifts of the level-set function are used to determine non-resolvable interface structures. Non-resolved interface structures are separated from the resolved ones and can be treated by a mixing model or a Lagrangian-particle model in order to preserve mass. Resolved interface structures are treated by the conservative sharp-interface model. Since the proposed scale separationmore » approach does not rely on topological information, unlike in previous work, it can be implemented in a straightforward fashion into a given level set based interface model. A number of two- and three-dimensional numerical tests demonstrate that the proposed method is able to cope with complex interface variations accurately and significantly increases robustness against underresolved interface structures.« less

The contribution of human activities to dissolved inorganic carbon fluxes in a karst underground river system: evidence from major elements and δ¹³C(DIC) in Nandong, Southwest China.

PubMed

Jiang, Yongjun

2013-09-01

Generally, the DIC in karst groundwater is dominantly derived from carbonate dissolution by carbonic acid. However, recently increases in the inorganic carbon flux have been linked to human activities, which nitric and sulfuric acids may contribute to carbonate dissolution. In order to quantify the sources and fluxes of DIC, and evaluate the carbon isotopic evolution of groundwater in Southwest China, the carbonate dissolution by carbonic, sulfuric and nitric acids was evaluated by hydrochemistry and δ¹³C(DIC)of groundwater. The results show that: (1) groundwater collected from residential and agricultural areas, showed higher DIC concentrations and δ¹³C(DIC) than those in groundwater collected from forested and grass land areas; (2) the contributions of carbonate dissolution by carbonic acid to total DIC concentrations in groundwater collected from forested and grass land areas averaged 99%; (3) the contributions of carbonate dissolution by carbonic acid to total DIC concentrations in groundwater, collected from residential and agricultural areas, varied from 40% to 77% with a mean percentage of 62%; (4) while the contributions of carbonate dissolution by sulfuric and nitric acids to total DIC concentrations in groundwater, collected from residential and agricultural areas, varied from 23% to 60% with a mean percentage of 38%; and (5) the δ¹³C(DIC) approaching a value of around -14‰, with a molar ratio between (Ca²⁺+Mg²⁺) and HCO₃⁻ of around 0.5 in groundwater, indicated that the carbonate was dissolved by soil CO₂ from C₃ vegetation under open system conditions. While the δ¹³C(DIC) varying from -5‰ to -11‰, with a variational molar ratio between (Ca²⁺+Mg²⁺) and HCO₃⁻ of 0.5 to 0.8 in groundwater, indicated that carbonate dissolution was controlled by soil CO₂ (from C₃ vegetation), HNO₃ and H₂SO₄. Also, this study indicated that the amount of soil or atmospheric CO₂ consumed during carbonate weathering should be critically evaluated when sulfuric or nitric acids are involved. Thus, not only the exports of inorganic carbon have been enhanced, but also the concentrations of nitrate and sulfate in karst groundwater have been elevated due to carbonate dissolution by sulfuric or nitric acid. Copyright © 2013 Elsevier B.V. All rights reserved.

Tracing organic matter composition and distribution and its role on arsenic release in shallow Cambodian groundwaters

NASA Astrophysics Data System (ADS)

Lawson, Michael; Polya, David A.; Boyce, Adrian J.; Bryant, Charlotte; Ballentine, Christopher J.

2016-04-01

Biogeochemical processes that utilize dissolved organic carbon are widely thought to be responsible for the liberation of arsenic from sediments to shallow groundwater in south and southeast Asia. The accumulation of this known carcinogen to hazardously high concentrations has occurred in the primary source of drinking water in large parts of densely populated countries in this region. Both surface and sedimentary sources of organic matter have been suggested to contribute dissolved organic carbon in these aquifers. However, identification of the source of organic carbon responsible for driving arsenic release remains enigmatic and even controversial. Here, we provide the most extensive interrogation to date of the isotopic signature of ground and surface waters at a known arsenic hotspot in Cambodia. We present tritium and radiocarbon data that demonstrates that recharge through ponds and/or clay windows can transport young, surface derived organic matter into groundwater to depths of 44 m under natural flow conditions. Young organic matter dominates the dissolved organic carbon pool in groundwater that is in close proximity to these surface water sources and we suggest this is likely a regional relationship. In locations distal to surface water contact, dissolved organic carbon represents a mixture of both young surface and older sedimentary derived organic matter. Ground-surface water interaction therefore strongly influences the average dissolved organic carbon age and how this is distributed spatially across the field site. Arsenic mobilization rates appear to be controlled by the age of dissolved organic matter present in these groundwaters. Arsenic concentrations in shallow groundwaters (<20 m) increase by 1 μg/l for every year increase in dissolved organic carbon age compared to only 0.25 μg/l for every year increase in dissolved organic carbon age in deeper (>20 m) groundwaters. We suggest that, while the rate of arsenic release is greatest in shallow aquifer sediments, arsenic release also occurs in deeper aquifer sediments and as such remains an important process in controlling the spatial distribution of arsenic in the groundwaters of SE Asia. Our findings suggest that any anthropogenic activities that alter the source of groundwater recharge or the timescales over which recharge takes place may also drive changes in the natural composition of dissolved organic carbon in these groundwaters. Such changes have the potential to influence both the spatial and temporal evolution of the current groundwater arsenic hazard in this region.

Groundwater Protection Program Management Plan For The U.S. Department Of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental, LLC

2009-09-01

This document presents the Groundwater Protection Program (GWPP) management plan for the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12). The Y-12 GWPP functions as the primary point-of-contact for groundwater-related issues at Y-12, provides stewardship of the extensive network of groundwater monitoring wells at Y-12, and serves as a resource for technical expertise, support, and historical data for groundwater-related activities at Y-12. These organizational functions each serve the primary programmatic purpose of the GWPP, which is to ensure that groundwater monitoring activities within areas under Y-12 administrative control provide representative data in compliance with themore » multiple purposes of applicable state and federal regulations, DOE orders, and the corporate policies of Babcock & Wilcox Technical Services Y-12 LLC (hereafter referenced as B&W Y-12), the Y-12 management and operations (M&O) contractor for DOE. B&W Y-12 is a new corporate name, assumed in January 2007, for the company formerly known as BWXT Y-12, L.L.C., hereafter referenced as BWXT. This GWPP management plan addresses the requirements of DOE Order 450.1A Environmental Protection Program (hereafter referenced as DOE O 450.1A), which emphasize a site-wide approach for groundwater protection at each DOE facility through implementation of groundwater surveillance monitoring. Additionally, this plan addresses the relevant and applicable GWPP elements and goals described in the DOE O 450.1A technical guidance documents issued in June 2004 (DOE 2004) and May 2005 (DOE 2005). This GWPP management plan is a 'living' document that is reviewed annually, revised and reissued every three years, and is formatted to provide for updating individual sections independent of the rest of the document. Section 2 includes a short description of the groundwater system at Y-12, the history of groundwater monitoring at Y-12 and the corresponding evolution of the GWPP, and an overview of ongoing Y-12 groundwater monitoring activities. Section 3 describes the key elements of the GWPP management strategy. Organizational roles and responsibilities of GWPP personnel are outlined in Section 4. Section 5 presents an overview of the GWPP project plans for applicable programmatic elements. Section 6 lists the reports, plans, and documents that are referenced for technical and administrative details.« less

Microstructural evolution associated with martensitic transformation in Ni-Mn-Ga alloy

NASA Astrophysics Data System (ADS)

Li, Z.; Zhang, Y.; Esling, C.; Zhao, X.; Zuo, L.

2015-04-01

Based on the spatially resolved electron backscatter diffraction technique, the microstructural evolution accompanying the martensitic transformation (austenite to 7M martensite) and the intermartensitic transformation (7M martensite to NM martensite) was studied on a polycrystalline Ni53Mn22Ga25 alloy. Results show that the 7M martensite plate groups transformed from initial austenite have a diamond-shape with four twin-related variants. The 7M to NM intermartensitic transformation was accompanied by the thickening of martensite plates. With the experimental results, the characteristics of microstructural evolution during the phase transformations were further analyzed.

Resolving runaway electron distributions in space, time, and energy

DOE PAGES

Paz-Soldan, Carlos; Cooper, C. M.; Aleynikov, P.; ...

2018-05-01

Areas of agreement and disagreement with present-day models of RE evolution are revealed by measuring MeV-level bremsstrahlung radiation from runaway electrons (REs) with a pinhole camera. Spatially-resolved measurements localize the RE beam, reveal energy-dependent RE transport, and can be used to perform full two-dimensional (energy and pitch-angle) inversions of the RE phase space distribution. Energy-resolved measurements find qualitative agreement with modeling on the role of collisional and synchrotron damping in modifying the RE distribution shape. Measurements are consistent with predictions of phase-space attractors that accumulate REs, with non-monotonic features observed in the distribution. Temporally-resolved measurements find qualitative agreement with modelingmore » on the impact of collisional and synchrotron damping in varying the RE growth and decay rate. Anomalous RE loss is observed and found to be largest at low energy. As a result, possible roles for kinetic instability or spatial transport to resolve these anomalies are discussed.« less

Resolving runaway electron distributions in space, time, and energy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paz-Soldan, Carlos; Cooper, C. M.; Aleynikov, P.

Areas of agreement and disagreement with present-day models of RE evolution are revealed by measuring MeV-level bremsstrahlung radiation from runaway electrons (REs) with a pinhole camera. Spatially-resolved measurements localize the RE beam, reveal energy-dependent RE transport, and can be used to perform full two-dimensional (energy and pitch-angle) inversions of the RE phase space distribution. Energy-resolved measurements find qualitative agreement with modeling on the role of collisional and synchrotron damping in modifying the RE distribution shape. Measurements are consistent with predictions of phase-space attractors that accumulate REs, with non-monotonic features observed in the distribution. Temporally-resolved measurements find qualitative agreement with modelingmore » on the impact of collisional and synchrotron damping in varying the RE growth and decay rate. Anomalous RE loss is observed and found to be largest at low energy. As a result, possible roles for kinetic instability or spatial transport to resolve these anomalies are discussed.« less

The curved 14C vs. δ13C relationship in dissolved inorganic carbon: A useful tool for groundwater age- and geochemical interpretations

USGS Publications Warehouse

Han, Liang-Feng; Plummer, Niel; Aggarwal, Pradeep

2014-01-01

Determination of the 14C content of dissolved inorganic carbon (DIC) is useful for dating of groundwater. However, in addition to radioactive decay, the 14C content in DIC (14CDIC) can be affected by many geochemical and physical processes and numerous models have been proposed to refine radiocarbon ages of DIC in groundwater systems. Changes in the δ13C content of DIC (δ13CDIC) often can be used to deduce the processes that affect the carbon isotopic composition of DIC and the 14C value during the chemical evolution of groundwater. This paper shows that a curved relationship of 14CDIC vs. δ13CDIC will be observed for groundwater systems if (1) the change in δ13C value in DIC is caused by a first-order or pseudo-first-order process, e.g. isotopic exchange between DIC and solid carbonate, (2) the reaction/process progresses with the ageing of the groundwater, i.e. with decay of 14C in DIC, and (3) the magnitude of the rate of change in δ13C of DIC is comparable with that of 14C decay. In this paper, we use a lumped parameter method to derive a model based on the curved relationship between 14CDICand δ13CDIC. The derived model, if used for isotopic exchange between DIC and solid carbonate, is identical to that derived by Gonfiantini and Zuppi (2003). The curved relationship of 14CDIC vs. δ13CDIC can be applied to interpret the age of the DIC in groundwater. Results of age calculations using the method discussed in this paper are compared with those obtained by using other methods that calculate the age of DIC based on adjusted initial radiocarbon values for individual samples. This paper shows that in addition to groundwater age interpretation, the lumped parameter method presented here also provides a useful tool for geochemical interpretations, e.g. estimation of apparent rates of geochemical reactions and revealing the complexity of the geochemical environment.

The role of critical zone processes in the evolution of the Prairie Pothole Region wetlands

USGS Publications Warehouse

Goldhaber, Martin B.; Mills, Christopher T.; Stricker, Craig A.; Morrison, Jean M.

2011-01-01

The Prairie Pothole Region, which occupies 900,000 km2 of the north central USA and south central Canada, is one of the most important ecosystems in North America. It is characterized by millions of small wetlands whose chemistry is highly variable over short distances. The study involved the geochemistry of surface sediments, wetland water, and groundwater in the Cottonwood Lakes area of North Dakota, USA, whose 92 ha includes the dominant wetland hydrologic settings. The data show that oxygenated groundwater interacting with pyrite resident in a component of surficial glacial till derived from the marine Pierre Shale Formation has, over long periods of time, focused SO 4 2 - -bearing fluids from upland areas to topographically low areas. In these low areas, SO 4 2 - -enriched groundwater and wetlands have evolved, as has the CaSO4 mineral gypsum. Sulfur isotope data support the conclusion that isotopically light pyrite from marine shale is the source of SO 4 2 - . Literature data on wetland water composition suggests that this process has taken place over a large area in North Dakota.

Groundwater Discharge along a Channelized Coastal Plain Stream

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaSage, Danita M; Sexton, Joshua L; Mukherjee, Abhijit

In the Coastal Plain of the southeastern USA, streams have commonly been artificially channelized for flood control and agricultural drainage. However, groundwater discharge along such streams has received relatively little attention. Using a combination of stream- and spring-flow measurements, spring temperature measurements, temperature profiling along the stream-bed, and geologic mapping, we delineated zones of diffuse and focused discharge along Little Bayou Creek, a channelized, first-order perennial stream in western Kentucky. Seasonal variability in groundwater discharge mimics hydraulic-head fluctuations in a nearby monitoring well and spring-discharge fluctuations elsewhere in the region, and is likely to reflect seasonal variability in recharge. Diffusemore » discharge occurs where the stream is incised into the semi-confined regional gravel aquifer, which is comprised of the Mounds Gravel. Focused discharge occurs upstream where the channel appears to have intersected preferential pathways within the confining unit. Seasonal fluctuations in discharge from individual springs are repressed where piping results in bank collapse. Thereby, focused discharge can contribute to the morphological evolution of the stream channel.« less

The role of critical zone processes in the evolution of the Prairie Pothole Region wetlands

USGS Publications Warehouse

Goldhaber, M.B.; Mills, C.; Stricker, C.A.; Morrison, J.M.

2011-01-01

The Prairie Pothole Region, which occupies 900,000 km2 of the north central USA and south central Canada, is one of the most important ecosystems in North America. It is characterized by millions of small wetlands whose chemistry is highly variable over short distances. The study involved the geochemistry of surface sediments, wetland water, and groundwater in the Cottonwood Lakes area of North Dakota, USA, whose 92 ha includes the dominant wetland hydrologic settings. The data show that oxygenated groundwater interacting with pyrite resident in a component of surficial glacial till derived from the marine Pierre Shale Formation has, over long periods of time, focused SO2-4-bearing fluids from upland areas to topographically low areas. In these low areas, SO2-4-enriched groundwater and wetlands have evolved, as has the CaSO4 mineral gypsum. Sulfur isotope data support the conclusion that isotopically light pyrite from marine shale is the source of SO2-4. Literature data on wetland water composition suggests that this process has taken place over a large area in North Dakota.

Water-rock interaction and geochemistry of groundwater from the Ain Azel aquifer, Algeria.

PubMed

Belkhiri, Lazhar; Mouni, Lotfi; Tiri, Ammar

2012-02-01

Hydrochemical, multivariate statistical, and inverse geochemical modeling techniques were used to investigate the hydrochemical evolution within the Ain Azel aquifer, Algeria. Cluster analysis based on major ion contents defined 3 main chemical water types, reflecting different hydrochemical processes. The first group water, group 1, has low salinity (mean EC = 735 μS/cm). The second group waters are classified as Cl-HCO(3)-alkaline earth type. The third group is made up of water samples, the cation composition of which is dominated by Ca and Mg with anion composition varying from dominantly Cl to dominantly HCO(3) plus SO(4). The varifactors obtained from R-mode FA indicate that the parameters responsible for groundwater quality variations are mainly related to the presence and dissolution of some carbonate, silicate, and evaporite minerals in the aquifer. Inverse geochemical modeling along groundwater flow paths indicates the dominant processes are the consumption of CO(2), the dissolution of dolomite, gypsum, and halite, along with the precipitation of calcite, Ca-montmorillonite, illite, kaolinite, and quartz. © Springer Science+Business Media B.V. 2011

Characterization and Remediation of Chlorinated Volatile Organic Contaminants in the Vadose Zone: An Overview of Issues and Approaches

PubMed Central

Brusseau, Mark L.; Carroll, Kenneth C.; Truex, Michael J.; Becker, David J.

2014-01-01

Contamination of vadose-zone systems by chlorinated solvents is widespread, and poses significant potential risk to human health through impacts on groundwater quality and vapor intrusion. Soil vapor extraction (SVE) is the presumptive remedy for such contamination, and has been used successfully for innumerable sites. However, SVE operations typically exhibit reduced mass-removal effectiveness at some point due to the impact of poorly accessible contaminant mass and associated mass-transfer limitations. Assessment of SVE performance and closure is currently based on characterizing contaminant mass discharge associated with the vadose-zone source, and its impact on groundwater or vapor intrusion. These issues are addressed in this overview, with a focus on summarizing recent advances in our understanding of the transport, characterization, and remediation of chlorinated solvents in the vadose zone. The evolution of contaminant distribution over time and the associated impacts on remediation efficiency will be discussed, as will the potential impact of persistent sources on groundwater quality and vapor intrusion. In addition, alternative methods for site characterization and remediation will be addressed. PMID:25383058

Water-quality assessment of part of the Upper Mississippi River basin, Minnesota and Wisconsin - Ground-water quality along a flow system in the Twin Cities metropolitan area, Minnesota, 1997-98

USGS Publications Warehouse

Andrews, William J.; Stark, James R.; Fong, Alison L.; Fallon, James D.

2005-01-01

Although land use had substantial effects on ground-water quality, the distribution of contaminants in the aquifer also is affected by complex combinations of factors and processes that include sources of natural and anthropogenic contaminants, three-dimensional advective flow, physical and hydrologic settings, age and evolution of ground water, and transformation of chemical compounds along the flow system. Compounds such as nitrate and dissolved oxygen were greatest in water samples from the upgradient end of the flow system and near the water table. Specific conductance and dissolved solids increased along the flow system and with depth due to increase in residence time in the flow system and dissolution of aquifer materials.

Unambiguous demonstration of soliton evolution in slow-light silicon photonic crystal waveguides with SFG-XFROG.

PubMed

Li, Xiujian; Liao, Jiali; Nie, Yongming; Marko, Matthew; Jia, Hui; Liu, Ju; Wang, Xiaochun; Wong, Chee Wei

2015-04-20

We demonstrate the temporal and spectral evolution of picosecond soliton in the slow light silicon photonic crystal waveguides (PhCWs) by sum frequency generation cross-correlation frequency resolved optical grating (SFG-XFROG) and nonlinear Schrödinger equation (NLSE) modeling. The reference pulses for the SFG-XFROG measurements are unambiguously pre-characterized by the second harmonic generation frequency resolved optical gating (SHG-FROG) assisted with the combination of NLSE simulations and optical spectrum analyzer (OSA) measurements. Regardless of the inevitable nonlinear two photon absorption, high order soliton compressions have been observed remarkably owing to the slow light enhanced nonlinear effects in the silicon PhCWs. Both the measurements and the further numerical analyses of the pulse dynamics indicate that, the free carrier dispersion (FCD) enhanced by the slow light effects is mainly responsible for the compression, the acceleration, and the spectral blue shift of the soliton.

Room-temperature ultrafast nonlinear spectroscopy of a single molecule

NASA Astrophysics Data System (ADS)

Liebel, Matz; Toninelli, Costanza; van Hulst, Niek F.

2018-01-01

Single-molecule spectroscopy aims to unveil often hidden but potentially very important contributions of single entities to a system's ensemble response. Albeit contributing tremendously to our ever growing understanding of molecular processes, the fundamental question of temporal evolution, or change, has thus far been inaccessible, thus painting a static picture of a dynamic world. Here, we finally resolve this dilemma by performing ultrafast time-resolved transient spectroscopy on a single molecule. By tracing the femtosecond evolution of excited electronic state spectra of single molecules over hundreds of nanometres of bandwidth at room temperature, we reveal their nonlinear ultrafast response in an effective three-pulse scheme with fluorescence detection. A first excitation pulse is followed by a phase-locked de-excitation pulse pair, providing spectral encoding with 25 fs temporal resolution. This experimental realization of true single-molecule transient spectroscopy demonstrates that two-dimensional electronic spectroscopy of single molecules is experimentally within reach.

Importance of Resolving the Spectral Support of Beam-plasma Instabilities in Simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shalaby, Mohamad; Broderick, Avery E.; Chang, Philip

2017-10-20

Many astrophysical plasmas are prone to beam-plasma instabilities. For relativistic and dilute beams, the spectral support of the beam-plasma instabilities is narrow, i.e., the linearly unstable modes that grow with rates comparable to the maximum growth rate occupy a narrow range of wavenumbers. This places stringent requirements on the box-sizes when simulating the evolution of the instabilities. We identify the implied lower limits on the box size imposed by the longitudinal beam plasma instability, i.e., typically the most stringent condition required to correctly capture the linear evolution of the instabilities in multidimensional simulations. We find that sizes many orders ofmore » magnitude larger than the resonant wavelength are typically required. Using one-dimensional particle-in-cell simulations, we show that the failure to sufficiently resolve the spectral support of the longitudinal instability yields slower growth and lower levels of saturation, potentially leading to erroneous physical conclusion.« less

The shock-heated atmosphere of an asymptotic giant branch star resolved by ALMA

NASA Astrophysics Data System (ADS)

Vlemmings, Wouter; Khouri, Theo; O'Gorman, Eamon; De Beck, Elvire; Humphreys, Elizabeth; Lankhaar, Boy; Maercker, Matthias; Olofsson, Hans; Ramstedt, Sofia; Tafoya, Daniel; Takigawa, Aki

2017-12-01

Our current understanding of the chemistry and mass-loss processes in Sun-like stars at the end of their evolution depends critically on the description of convection, pulsations and shocks in the extended stellar atmosphere1. Three-dimensional hydrodynamical stellar atmosphere models provide observational predictions2, but so far the resolution to constrain the complex temperature and velocity structures seen in the models has been lacking. Here we present submillimetre continuum and line observations that resolve the atmosphere of the asymptotic giant branch star W Hydrae. We show that hot gas with chromospheric characteristics exists around the star. Its filling factor is shown to be small. The existence of such gas requires shocks with a cooling time longer than commonly assumed. A shocked hot layer will be an important ingredient in current models of stellar convection, pulsation and chemistry at the late stages of stellar evolution.

Climate change impact assessment in Veneto and Friuli Plain groundwater. Part II: a spatially resolved regional risk assessment.

PubMed

Pasini, S; Torresan, S; Rizzi, J; Zabeo, A; Critto, A; Marcomini, A

2012-12-01

Climate change impact assessment on water resources has received high international attention over the last two decades, due to the observed global warming and its consequences at the global to local scale. In particular, climate-related risks for groundwater and related ecosystems pose a great concern to scientists and water authorities involved in the protection of these valuable resources. The close link of global warming with water cycle alterations encourages research to deepen current knowledge on relationships between climate trends and status of water systems, and to develop predictive tools for their sustainable management, copying with key principles of EU water policy. Within the European project Life+ TRUST (Tool for Regional-scale assessment of groundwater Storage improvement in adaptation to climaTe change), a Regional Risk Assessment (RRA) methodology was developed in order to identify impacts from climate change on groundwater and associated ecosystems (e.g. surface waters, agricultural areas, natural environments) and to rank areas and receptors at risk in the high and middle Veneto and Friuli Plain (Italy). Based on an integrated analysis of impacts, vulnerability and risks linked to climate change at the regional scale, a RRA framework complying with the Sources-Pathway-Receptor-Consequence (SPRC) approach was defined. Relevant impacts on groundwater and surface waters (i.e. groundwater level variations, changes in nitrate infiltration processes, changes in water availability for irrigation) were selected and analyzed through hazard scenario, exposure, susceptibility and risk assessment. The RRA methodology used hazard scenarios constructed through global and high resolution model simulations for the 2071-2100 period, according to IPCC A1B emission scenario in order to produce useful indications for future risk prioritization and to support the addressing of adaptation measures, primarily Managed Artificial Recharge (MAR) techniques. Relevant outcomes from the described RRA application highlighted that potential climate change impacts will occur with different extension and magnitude in the case study area. Particularly, qualitative and quantitative impacts on groundwater will occur with more severe consequences in the wettest and in the driest scenario (respectively). Moreover, such impacts will likely have little direct effects on related ecosystems - croplands, forests and natural environments - lying along the spring area (about 12% of croplands and 2% of natural environments at risk) while more severe consequences will indirectly occur on natural and anthropic systems through the reduction in quality and quantity of water availability for agricultural and other uses (about 80% of agricultural areas and 27% of groundwater bodies at risk). Copyright © 2012 Elsevier B.V. All rights reserved.

Source and movement of helium in the eastern Morongo groundwater Basin: The influence of regional tectonics on crustal and mantle helium fluxes

USGS Publications Warehouse

Kulongoski, J.T.; Hilton, David R.; Izbicki, J.A.

2005-01-01

We assess the role of fracturing and seismicity on fluid-driven mass transport of helium using groundwaters from the eastern Morongo Basin (EMB), California, USA. The EMB, located ???200 km east of Los Angeles, lies within a tectonically active region known as the Eastern California Shear Zone that exhibits both strike-slip and extensional deformation. Helium concentrations from 27 groundwaters range from 0.97 to 253.7 ?? 10-7 cm3 STP g-1 H2O, with corresponding 3He/4He ratios falling between 1.0 and 0.26 RA (where RA is the 3He/4He ratio of air). All groundwaters had helium isotope ratios significantly higher than the crustal production value of ???0.02 RA. Dissolved helium concentrations were resolved into components associated with solubility equilibration, air entrainment, in situ production within the aquifer, and extraneous fluxes (both crustal and mantle derived). All samples contained a mantle helium-3 (3Hem) flux in the range of 4.5 to 1351 ?? 10-14 cm3 STP 3He cm-2 yr-1 and a crustal flux (J0) between 0.03 and 300 ?? 10-7 cm3 STP 4He cm-2 yr-1. Groundwaters from the eastern part of the basin contained significantly higher 3Hem and deep crustal helium-4 (4Hedc) concentrations than other areas, suggesting a localized source for these components. 4Hedc and 3Hem are strongly correlated, and are associated with faults in the basin. A shallow thermal anomaly in a >3,000 m deep graben in the eastern basin suggests upflow of fluids through active faults associated with extensional tectonics. Regional tectonics appears to drive large scale crustal fluid transport, whereas episodic hydrofracturing provides an effective mechanism for mantle-crust volatile transport identified by variability in the magnitude of degassing fluxes (3Hem and J0) across the basin. Copyright ?? 2005 Elsevier Ltd.

Anthropogenic wetlands due to over-irrigation of desert areas: a challenging hydrogeological investigation with extensive geophysical input from TEM and MRS measurements

NASA Astrophysics Data System (ADS)

Behroozmand, Ahmad Ali; Teatini, Pietro; Bjergsted Pedersen, Jesper; Auken, Esben; Tosatto, Omar; Vest Christiansen, Anders

2017-03-01

During the last century, many large irrigation projects were carried out in arid lands worldwide. Despite a tremendous increase in food production, a common problem when characterizing these zones is land degradation in the form of waterlogging. A clear example of this phenomenon is in the Nubariya depression in the Western Desert of Egypt. Following the reclamation of desert lands for agricultural production, an artificial brackish and contaminated pond started to develop in the late 1990s, which at present extends for about 2.5 km2. The available data provide evidence of a simultaneous general deterioration of the groundwater system. An extensive hydrogeophysical investigation was carried out in this challenging environment using magnetic resonance sounding (MRS) and ground-based time-domain electromagnetic (TEM) techniques with the following main objectives: (1) understanding the hydrological evolution of the area; (2) characterizing the hydrogeological setting; and (3) developing scenarios for artificial aquifer remediation and recharge. The integrated interpretation of the geophysical surveys provided a hydrogeological picture of the upper 100 m sedimentary setting in terms of both lithological distribution and groundwater quality. The information is then used to set up (1) a regional groundwater flow and (2) a local density-dependent flow and transport numerical model to reproduce the evolution of the aquifer system and develop a few scenarios for artificial aquifer recharge using the treated water provided by a nearby wastewater treatment plant. The research outcomes point to the hydrological challenges that emerge for the effective management of water resources in reclaimed desert areas, and they highlight the effectiveness of using advanced geophysical and modeling methodologies.

Anthropogenic wetlands due to over-irrigation of desert areas; A challenging hydrogeological investigation with extensive geophysical input

NASA Astrophysics Data System (ADS)

Behroozmand, A. A.; Teatini, P.; Pedersen, J. B. B.; Auken, E.; Tosatto, O.; Christiansen, A. V.

2015-12-01

During the last century, many large irrigation projects have been initiated in arid lands worldwide. Despite a tremendous increase in food production, a common problem when characterizing these zones is land degradation in form of waterlogging. As results, large volumes of water are lost due to surplus irrigation in regions where water availability is extremely challenging for both population survival and economic development. The Nubariya depression, Western Desert (Egypt), is a clear example of this mechanism. Following the reclamation of desert lands for agricultural production, an artificial brackish and contaminated lake developed in the area in the late 1990s and presently extends for about 2.5 km2. Available data provide evidence of a simultaneous general deterioration of the groundwater system. With the main objectives of understanding the hydrological evolution of the area, characterizing the hydrogeological setting and developing scenarios for artificial aquifer remediation and recharge, an extensive hydrogeophysical investigation was carried out in this challenging environment using Magnetic Resonance Sounding (MRS, also called surface NMR) and ground-based Transient EM (TEM). The integrated interpretation of the geophysical surveys, properly calibrated with a number of boreholes, provides a clear hydrogeological picture of the upper 100 m sedimentary structure, in terms of both lithology and groundwater quality. The information is then used to set up a regional groundwater flow and a local density-dependent flow and transport numerical model to reproduce the past evolution of the aquifer system and develop a few scenarios for artificial aquifer recharge using the treated waters provided by a nearby waste-water treatment plant. The research outcomes point the hydrological challenges that emerge for an effective management of water resources in reclaimed desert areas and highlight the effectiveness of integrating advanced geophysical and modeling methodologies.

Geochemical evolution of groundwater in the Culebra dolomite near the Waste Isolation Pilot Plant, southeastern New Mexico, USA

USGS Publications Warehouse

Siegel, M.D.; Anderholm, S.

1994-01-01

The Culebra Dolomite Member of the Rustler Formation, a thin (10 m) fractured dolomite aquifer, lies approximately 450 m above the repository horizon of the Waste Isolation Pilot Plant (WIPP) in southeastern New Mexico, USA. Salinities of water in the Culebra range roughly from 10,000 to 200,000 mg/L within the WIPP site. A proposed model for the post-Pleistocene hydrochemical evolution of the Culebra tentatively identifies the major sources and sinks for many of the groundwater solutes. Reaction-path simulations with the PHRQPITZ code suggest that the Culebra dolomite is a partial chemical equilibrium system whose composition is controlled by an irreversible process (dissolution of evaporites) and equilibrium with gypsum and calcite. Net geochemical reactions along postulated modern flow paths, calculated with the NETPATH code, include dissolution of halite, carbonate and evaporite salts, and ion exchange. R-mode principal component analysis revealed correlations among the concentrations of Si, Mg, pH, Li, and B that are consistent with several clay-water reactions. The results of the geochemical calculations and mineralogical data are consistent with the following hydrochemical model: 1. (1) solutes are added to the Culebra by dissolution of evaporite minerals 2. (2) the solubilities of gypsum and calcite increase as the salinity increases; these minerals dissolve as chemical equilibrium is maintained between them and the groundwater 3. (3) equilibrium is not maintained between the waters and dolomite; sufficient Mg is added to the waters by dissolution of accessory carnallite or polyhalite such that the degree of dolomite supersaturation increases with ionic strength 4. (4) clays within the fractures and rock matrix exert some control on the distribution of Li, B, Mg, and Si via sorption, ion exchange, and dissolution. ?? 1994.

Modeling the impact of the nitrate contamination on groundwater at the groundwater body scale : The Geer basin case study (Invited)

NASA Astrophysics Data System (ADS)

Brouyere, S.; Orban, P.; Hérivaux, C.

2009-12-01

In the next decades, groundwater managers will have to face regional degradation of the quantity and quality of groundwater under pressure of land-use and socio-economic changes. In this context, the objectives of the European Water Framework Directive require that groundwater be managed at the scale of the groundwater body, taking into account not only all components of the water cycle but also the socio-economic impact of these changes. One of the main challenges remains to develop robust and efficient numerical modeling applications at such a scale and to couple them with economic models, as a support for decision support in groundwater management. An integrated approach between hydrogeologists and economists has been developed by coupling the hydrogeological model SUFT3D and a cost-benefit economic analysis to study the impact of agricultural practices on groundwater quality and to design cost-effective mitigation measures to decrease nitrate pressure on groundwater so as to ensure the highest benefit to the society. A new modeling technique, the ‘Hybrid Finite Element Mixing Cell’ approach has been developed for large scale modeling purposes. The principle of this method is to fully couple different mathematical and numerical approaches to solve groundwater flow and solute transport problems. The mathematical and numerical approaches proposed allows an adaptation to the level of local hydrogeological knowledge and the amount of available data. In combination with long time series of nitrate concentrations and tritium data, the regional scale modelling approach has been used to develop a 3D spatially distributed groundwater flow and solute transport model for the Geer basin (Belgium) of about 480 km2. The model is able to reproduce the spatial patterns of nitrate concentrations together nitrate trends with time. The model has then been used to predict the future evolution of nitrate trends for two types of scenarios: (i) a “business as usual scenario” where current polluting pressures remain the same and (ii) two contrasted scenarios that simulate the implementation of programs of measures aiming at reaching good chemical status. The results of the hydrogeological model under the “business as usual scenario” have been used to assess the cost for the society of the continuous degradation of the groundwater quality. The results of the hydrogeological model under the two contrasted scenarios have been used to assess the economical benefit as avoided damage resulting from the decrease in the nitrate load. A cost-benefit analysis has been thus performed to assess the programme of mitigation measures which provides the largest benefits at the lowest cost.

The evolution of 17O-excess in surface water of the arid environment during recharge and evaporation.

PubMed

Surma, J; Assonov, S; Herwartz, D; Voigt, C; Staubwasser, M

2018-03-21

This study demonstrates the potential of triple O-isotopes to quantify evaporation with recharge on a salt lake from the Atacama Desert, Chile. An evaporative gradient was found in shallow ponds along a subsurface flow-path from a groundwater source. Total dissolved solids (TDS) increased by 177 g/l along with an increase in δ 18 O by 16.2‰ and in δD by 65‰. 17 O-excess decreased by 79 per meg, d-excess by 55‰. Relative humidity (h), evaporation over inflow (E/I), the isotopic composition of vapor ( * R V ) and of inflowing water ( * R WI ) determine the isotope distribution in 17 O-excess over δ 18 O along a well-defined evaporation curve as the classic Craig-Gordon model predicts. A complementary on-site simple (pan) evaporation experiment over a change in TDS, δ 18 O, and 17 O-excess by 392 g/l, 25.0‰, and -130 per meg, respectively, was used to determine the effects of sluggish brine evaporation and of wind turbulence. These effects translate to uncertainty in E/I rather than h. The local composition of * R V relative to * R WI pre-determines the general ability to resolve changes in h. The triple O-isotope system is useful for quantitative hydrological balancing of lakes and for paleo-humidity reconstruction, particularly if complemented by D/H analysis.

Genesis and transport of hexavalent chromium in the system ophiolitic rocks - groundwater

NASA Astrophysics Data System (ADS)

Shchegolikhina, Anastasia; Guadagnini, Laura; Guadagnini, Alberto

2015-04-01

Our study aims at contributing to the quantification and characterization of chromium transport processes from host rocks and soil matrices to groundwater. We focus on dissolved hexavalent chromium detected in groundwaters of geological regions with ophiolitic rocks (ophiolites and serpentinites) inclusions due to its critical ecological impact. (Oze et al., 2004). Despite the large number of analyses on the occurrence of high concentrations of hazardous hexavalent chromium ions in natural waters, only few studies were performed with the objective of identifying and investigating the geochemical reactions which could occur in the natural system rock - groundwater - dissolved chromium (Fantoni et al., 2002, Stephen and James, 2004, Lelli et al., 2013). In this context, there is a need for integration of results obtained from diverse studies in various regions and settings to improve our knowledge repository. Our theoretical analyses are grounded and driven by practical scenarios detected in subsurface reservoirs exploited for civil and industrial use located in the Emilia-Romagna region (Italy). Available experimental datasets are complemented with data from other international regional-scale settings (Altay mountains region, Russia). Modeling of chromium transformation and migration particularly includes characterization of the multispecies geochemical system. A key aspect of our study is the analysis of the complex competitive sorption processes governing heavy metal evolution in groundwater. The results of the research allow assessing the critical qualitative features of the mechanisms of hexavalent chromium ion mobilization from host rocks and soils and the ensuing transformation and migration to groundwater under the influence of diverse environmental factors. The study is then complemented by the quantification of the main sources of uncertainty associated with prediction of heavy metal contamination levels in the groundwater system explored. Fantoni, D., Brozzo, G., Canepa, M., Cipolli, F., Marini, L., Ottonello, G., Zuccolini, M., 2002. Natural hexavalent chromium in groundwaters interacting with ophiolitic rocks. Environmental Geology 42, 871-882. Lelli, M., Grassi, S., Amadori, M., Franceschini, F., 2013. Natural Cr(VI) contamination of groundwater in the Cecina coastal area and its inner sectors (Tuscany, Italy). Environmental Earth Sciences 71, 3907-3919. Oze, C., Fendorf, S., Bird, D.K., Coleman, R.G., 2004. Chromium geochemistry of serpentine soils. International Geology Review 46, 97-126. Stephen, M.T., James, A.J., 2004. Overview of chromium (VI) in the environment. Chromium (VI) Handbook. CRC Press, pp. 21.

Hydrogeochemical characterisation of groundwater in a small watershed in a discontinuous permafrost zone.

NASA Astrophysics Data System (ADS)

Cochand, Marion; Molson, John; Barth, Johannes A. C.; van Geldern, Robert; Lemieux, Jean-Michel; Fortier, Richard; Therrien, René

2017-04-01

Impacts of climate change can already be seen in northern regions. However, the influence of increasing temperature and permafrost degradation on groundwater dynamics is still poorly understood. This study aims to improve knowledge on hydrogeological interactions in degrading permafrost environments using hydrogeochemical characterisation of groundwater. This study is being conducted in a small 2-km2 watershed, in a discontinuous permafrost zone located close to the Inuit community of Umiujaq, on the eastern shore of Hudson Bay in northern Québec, Canada. Two aquifers are being investigated, an unconfined shallow sandy aquifer located in the upper part of the watershed, and a deeper confined aquifer in sands and gravels located below the permafrost mounds. Precipitation, stream and surface water as well as ice-rich permafrost lenses were also sampled during field investigations. Various hydrogeochemical tracers including major ions, water stable isotopes (δ18OH2O and δ2HH2O), carbon phases (DIC, DOC, POC), their stable carbon isotopes (δ13C) and dating tracers (radiocarbon, tritium-helium and CFC/SF6) were analyzed. This characterisation has contributed to further understanding groundwater origin, evolution and residence time in the watershed. Preliminary results show that groundwater has a mainly Ca-HCO3 geochemical signature, typical for young and poorly evolved water. Furthermore, sample mineralisation is low, and is likely linked to limited bedrock weathering caused by short residence times, slow reaction rates as well as low levels of dissolved CO2 due to suppressed biological activity in the catchment. Inter-annual variation of major ions in the deeper aquifer is low. All groundwater samples have significant tritium concentrations, around 8.5 TU, reflecting modern recharge. Ice-rich permafrost lenses within the top four meters of permafrost have a water stable isotope signature close to modern precipitation and groundwater. This indicates that either recharge conditions of permafrost ice were similar to current conditions, or freeze-thaw cycles have drawn modern water into the permafrost mounds. The stream appears to be fed by groundwater exfiltrating at the base of permafrost mounds in the lower part of the watershed. Linking this hydrogeochemical characterisation to groundwater and thermal modelling at the watershed and permafrost mound scales will improve our knowledge on hydrogeological interactions in degrading permafrost environments.

Spectral reconstruction analysis for enhancing signal-to-noise in time-resolved spectroscopies

NASA Astrophysics Data System (ADS)

Wilhelm, Michael J.; Smith, Jonathan M.; Dai, Hai-Lung

2015-09-01

We demonstrate a new spectral analysis for the enhancement of the signal-to-noise ratio (SNR) in time-resolved spectroscopies. Unlike the simple linear average which produces a single representative spectrum with enhanced SNR, this Spectral Reconstruction analysis (SRa) improves the SNR (by a factor of ca. 0 . 6 √{ n } ) for all n experimentally recorded time-resolved spectra. SRa operates by eliminating noise in the temporal domain, thereby attenuating noise in the spectral domain, as follows: Temporal profiles at each measured frequency are fit to a generic mathematical function that best represents the temporal evolution; spectra at each time are then reconstructed with data points from the fitted profiles. The SRa method is validated with simulated control spectral data sets. Finally, we apply SRa to two distinct experimentally measured sets of time-resolved IR emission spectra: (1) UV photolysis of carbonyl cyanide and (2) UV photolysis of vinyl cyanide.

Characterizing the Resolved M6 Dwarf Twin LP 318-218AB

NASA Astrophysics Data System (ADS)

Moreno Hilario, Elizabeth; Burgasser, Adam J.; Bardalez Gagliuffi, Daniella; Tamiya, Tomoki

2017-01-01

The lowest-mass stars and brown dwarfs are among the most common objects in the Milky Way Galaxy, but theories of their formation and evolution remain poorly constrained. Binary systems are important for understanding the formation of these objects and for making direct orbit and mass measurements to validate evolutionary theories. We report the discovery of LP 318-218, a high proper motion late M dwarf, as a near equal-brightness binary system with a separation of 0.72 arcseconds. Resolved near-infrared spectroscopy confirms the components as nearly identical M6 twins. We using our resolved photometry and spectroscopy to estimate the distance, projected separation and tangential velocity of the system, and confirm common proper motion. We also perform atmosphere model fits to the resolved spectra to assess their physical properties. We place LP 318-218 in context with other widely-separated late M dwarf binaries.

Scaling the Morphology of Sapping and Pressurized Groundwater Experiments to Martian Valleys

NASA Astrophysics Data System (ADS)

Marra, W. A.; Kleinhans, M. G.

2013-12-01

Various valleys exist on Mars, which shows the former existence of fluvial activity and thus liquid water at the surface. Although these valleys show similarities with some valleys on Earth, many morphological features are unique for Mars or are very rare on Earth. Therefore, we lack knowledge about the formative processes of these enigmatic valleys. In this study, we explored possible groundwater scenarios for the formation of these valleys using flume experiments, as there are no pure Earth analogues for these systems. We aim to infer their formative processes from morphological properties. A series of flume experiments were carried out in a 4x6x1 m experimental setup, where we observed the valley formation as result from seeping groundwater by both local and distal groundwater sources and by pressurized groundwater release. Time-lapse imagery and DEMs of the experiments show the morphological development, associated processes, and landscape evolution. Indicators of the processes where we particularly looked at were changes in valley slope, cross-sectional shape, the relations between valley dimensions, and regional landscape properties as drainage density and valley size distributions. Hydrological modelling assists in scaling the observed experimental features to real-world systems. Additionally, we looked at valleys on Earth in the Atacama Desert, at Box canyon in Idaho, valleys around Kohala on Hawaii and Apalachicola bluffs in Florida to test the applicability of our methods to real-world systems. In the seeping groundwater valleys, valleys develop due to a combination of mass-wasting failures, mudflows and fluvial flow. The latter two processes are expressed in the final morphology by a break in slope. The mass wasting processes result in U-shaped valleys, which are more pronounced in distal groundwater cases. However, in real-world cases of similar shaped valleys, the cross-sectional shape seems strongly influenced by the strength of the material as well. Groundwater flow piracy of multiple valleys within one system are characterized by equal ratios of width and length development, a property that is absent in case of a local groundwater source which does not induce flow piracy. In case of pressurized groundwater release, the sediment surface in the source area fractured and pits developed due to high groundwater pressure. The resulting valley head consisted of feather-shaped converging flow features. Scaling of the non-fluvial features that relate to groundwater pressure is possible by using hydrological modelling of groundwater pressure and geophysical modelling of the behaviour of the material under such pressures. Our results on sapping valley formation, combined with insights from multiple terrestrial sites of similar valleys contribute to the discussion of some enigmatic valleys on Mars. We provide several quantitative morphological measures, which directly relate to the formative process, which is valuable in linking morphology to the formative process. Our results on pressurized groundwater release prove a long-standing hypothesis on the formation on some of the largest valleys observed in our solar system. In both cases, the insights in the formative processes enable us to quantify the amount of water required for the formation of groundwater-induced Martian valleys.

The Evolution of Reproduction within Testudinata as Evidenced by the Fossil Record

NASA Astrophysics Data System (ADS)

Lawver, Daniel Ryan

Although known from every continent except Antarctica and having a fossil record ranging from the Middle Jurassic to the Pleistocene, fossil turtle eggs are relatively understudied. In this dissertation I describe four fossil specimens, interpret paleoecology and conduct cladistic analyses in order to investigate the evolution of turtle reproduction. Fossil eggshell descriptions primarily involve analysis by scanning electron and polarized light microscopy, as well as cathodoluminescence to determine the degree of diagenetic alteration. Carapace lengths and gas conductance are estimated in order to investigate the ecology of the adults that produced fossil turtle eggs and clutches, as well as their incubation environments, respectively. Cladistic analyses of turtle egg and reproductive characters permit assessment of the usefulness of these characters for determining phylogenetic relationships of fossil specimens and the evolution of reproduction in turtles. Specimens described here include 1) Testudoolithus oosp. from the Late Cretaceous of Madagascar, 2) a clutch of eggs (some containing late stage embryos and at least one exhibiting multilayer eggshell) from the Late Cretaceous Judith River Formation of Montana and named Testudoolithus zelenitskyae oosp. nov., 3) an egg contained within an adult Basilemys nobilis from the Late Cretaceous Kaiparowits Formation of Utah, and 4) a clutch of Meiolania platyceps eggs from the Pleistocene of Lord Howe Island, Australia. Meiolania platyceps eggs are named Testudoolithus lordhowensis oosp. nov. and provide valuable information on the origin of aragonite eggshell composition and nesting behaviors. Cladistic analyses utilizing egg and reproductive characters are rarely performed on taxa outside of Dinosauria. My analyses demonstrate that morphological data produces poorly resolved trees in which only the clades Adocia and Trionychia are resolved and all other turtles form a large polytomy. However, when combined with molecular data, egg and reproductive characters have more resolving potential towards the top of trees. This poor resolution is likely due to homoplasy in the form of character reversals, convergent evolution, and/or from the limited number of informative characters.

Study of particle evolution from Composition B-3 detonation by time-resolved small angle x-ray scattering

NASA Astrophysics Data System (ADS)

Huber, R.; Podlesak, D.; Dattelbaum, D.; Firestone, M.; Gustavsen, R.; Jensen, B.; Ringstrand, B.; Watkins, E.; Bagge-Hansen, M.; Hodgin, R.; Lauderbach, L.; Willey, T.; van Buuren, T.; Graber, T.; Rigg, P.; Sinclair, N.; Seifert, S.

2017-06-01

High explosive (HE) detonations produce an assortment of gases (CO, CO2, N2) and solid carbon products (nanodiamond, graphite). The evolution of solid carbon particles, within the chemical reaction zone, help to propel the detonation wave forward. Due to the violent nature and short reaction times during HE detonations, experimental observation are limited. Through time-resolved small angle x-ray scattering (TRSAXS) we are able to observed nanocarbon formation on nanosecond time scales. This TRSAXS setup is the first of its kind in the United States at Argonne National Laboratory at the Advanced Photon Source in the Dynamic Compression Sector. From the empirical and analytical analysis of the x-ray scattering of an in-line detonation we are able to temporally follow morphology and size. Two detonation geometries were studied for the HE Comp B-3 (40% TNT/60% RDX), producing steady and overdriven conditions. Steady wave particle evolution plateaued by 2 microseconds, where overdriven condition particle size decreases at the collision of the two shock fronts then plateaus. Post detonation soot is also analyzed to confirm size and shape of nanocarbon formation from Comp B-3 detonations. LA-UR-17-21443.

Time-resolved X-Ray Absorption Spectroscopy of a Cobalt-Based Hydrogen Evolution System for Artificial Photosynthesis

NASA Astrophysics Data System (ADS)

Moonshiram, Dooshaye; Gimbert, Carolina; Lehmann, Carl; Southworth, Stephen; Llobet, Antoni; Argonne National Laboratory Team; Institut Català d'Investigació Química Collaboration

2015-03-01

Production of cost-effective hydrogen gas through solar power is an important challenge of the Department of Energy among other global industry initiatives. In natural photosynthesis, the oxygen evolving complex(OEC) can carry out four-electron water splitting to hydrogen with an efficiency of around 60%. Although, much progress has been carried out in determining mechanistic pathways of the OEC, biomimetic approaches have not duplicated Nature's efficiency in function. Over the past years, we have witnessed progress in developments of light harvesting modules, so called chromophore/catalytic assemblies. In spite of reportedly high catalytic activity of these systems, quantum yields of hydrogen production are below 40 % when using monochromatic light. Proper understanding of kinetics and bond making/breaking steps has to be achieved to improve efficiency of hydrogen evolution systems. This project shows the timing implementation of ultrafast X-ray absorption spectroscopy to visualize in ``real time'' the photo-induced kinetics accompanying a sequence of redox reactions in a cobalt-based molecular photocatalytic system. Formation of a Co(I) species followed by a Co(III) hydride species all the way towards hydrogen evolution is shown through time-resolved XANES.

Speleothems in the desert: Glimpses of the Pleistocene history of the Death Valley Regional Groundwater Flow System, Nevada and California

NASA Astrophysics Data System (ADS)

Spötl, Christoph; Dublyansky, Yuri; Moseley, Gina; Wendt, Kathleen; Edwards, Larry; Scholger, Robert; Woodhead, Jon

2016-04-01

Death Valley in eastern California holds North Americás record for the deepest, hottest and driest place. Despite these unfavourable boundary conditions speleothems are present in this hyperarid depression and the surrounding deserts and provide unique insights into long-term regional climate change and landscape evolution of this tectonically and geomorphologically highly active region. Most of the speleothems are inactive and exposed due to tectonic uplift and erosion. They differ from common speleothems, because the majority formed under phreatic conditions as part of a regional groundwater flow system that is still active today. Data from three sites will be discussed illustrating the spectrum of speleothem deposits and their modes of formation. At Devils Hole, the thermal aquifer and the associated subaqueous and water-table speleothems can be directly accessed and provide a record reaching back about 1 million years. At Travertine Point, close to modern discharge points of this large groundwater flow system, phreatic speleothems form near-vertical veins up to about 2 m wide showing evidence of high flow rates along these fractures, which are connected to fossil spring tufa deposits. Finally, outcrops along Titus Canyon expose several generations of speleothems documenting the progressive lowering of the regional groundwater table. The youngest calcite generation records the transition towards vadose conditions 500-400 ka ago.

Groundwater Depletion in the Middle East from GRACE with Implications for Transboundary Water Management in the Tigris-Euphrates-Western Iran Region

NASA Technical Reports Server (NTRS)

Voss, Katalyn A.; Famiglietti, James S.; Lo, MinHui; De Linage, Caroline; Rodell, Matthew; Swenson, Sean C.

2013-01-01

In this study, we use observations from the Gravity Recovery and Climate Experiment (GRACE) satellite mission to evaluate freshwater storage trends in the north-central Middle East, including portions of the Tigris and Euphrates River Basins and western Iran, from January 2003 to December 2009. GRACE data show an alarming rate of decrease in total water storage of approximately -27.2 plus or minus 0.6 millimeters per year equivalent water height, equal to a volume of 143.6 cubic kimometers during the course of the study period. Additional remote-sensing information and output from land surface models were used to identify that groundwater losses are the major source of this trend. The approach used in this study provides an example of ''best current capabilities'' in regions like the Middle East, where data access can be severely limited. Results indicate that the region lost 17.3 plus or minus 2.1 millimeters per year equivalent water height of groundwater during the study period, or 91.3 plus or minus 10.9 cubic kilometers in volume. Furthermore, results raise important issues regarding water use in transboundary river basins and aquifers, including the necessity of international water use treaties and resolving discrepancies in international water law, while amplifying the need for increased monitoring for core components of the water budget.

Groundwater Depletion in the Middle East from GRACE with Implications for Transboundary Water Management in the Tigris-Euphrates-Western Iran Region

NASA Technical Reports Server (NTRS)

Voss, Katalyn; Famiglietti, James S.; Lo, MinHui; de Linage, Caroline; Rodell, Matthew; Swenson, Sean C.

2013-01-01

In this study, we use observations from the Gravity Recovery and Climate Experiment (GRACE) satellite mission to evaluate freshwater storage trends in the north-central Middle East, including portions of the Tigris and Euphrates River Basins and western Iran, from January 2003 to December 2009. GRACE data show an alarming rate of decrease in total water storage of approximately -27.2 plus or minus 0.6 mm per yr equivalent water height, equal to a volume of 143.6 cubic kilometers during the course of the study period. Additional remote-sensing information and output from land surface models were used to identify that groundwater losses are the major source of this trend. The approach used in this study provides an example of ''best current capabilities'' in regions like the Middle East, where data access can be severely limited. Results indicate that the region lost 17.3 plus or minus 2.1 mm per yr equivalent water height of groundwater during the study period, or 91.3 plus or minus 10.9 cubic kilometers in volume. Furthermore, results raise important issues regarding water use in transboundary river basins and aquifers, including the necessity of international water use treaties and resolving discrepancies in international water law, while amplifying the need for increased monitoring for core components of the water budget

Groundwater depletion in the Middle East from GRACE with implications for transboundary water management in the Tigris-Euphrates-Western Iran region

NASA Astrophysics Data System (ADS)

Voss, Katalyn A.; Famiglietti, James S.; Lo, MinHui; de Linage, Caroline; Rodell, Matthew; Swenson, Sean C.

2013-02-01

In this study, we use observations from the Gravity Recovery and Climate Experiment (GRACE) satellite mission to evaluate freshwater storage trends in the north-central Middle East, including portions of the Tigris and Euphrates River Basins and western Iran, from January 2003 to December 2009. GRACE data show an alarming rate of decrease in total water storage of approximately -27.2±0.6 mm yr-1 equivalent water height, equal to a volume of 143.6 km3 during the course of the study period. Additional remote-sensing information and output from land surface models were used to identify that groundwater losses are the major source of this trend. The approach used in this study provides an example of "best current capabilities" in regions like the Middle East, where data access can be severely limited. Results indicate that the region lost 17.3±2.1 mm yr-1 equivalent water height of groundwater during the study period, or 91.3±10.9 km3 in volume. Furthermore, results raise important issues regarding water use in transboundary river basins and aquifers, including the necessity of international water use treaties and resolving discrepancies in international water law, while amplifying the need for increased monitoring for core components of the water budget.

Radar interferometry offers new insights into threats to the Angkor site.

PubMed

Chen, Fulong; Guo, Huadong; Ma, Peifeng; Lin, Hui; Wang, Cheng; Ishwaran, Natarajan; Hang, Peou

2017-03-01

The conservation of World Heritage is critical to the cultural and social sustainability of regions and nations. Risk monitoring and preventive diagnosis of threats to heritage sites in any given ecosystem are a complex and challenging task. Taking advantage of the performance of Earth Observation technologies, we measured the impacts of hitherto imperceptible and poorly understood factors of groundwater and temperature variations on the monuments in the Angkor World Heritage site (400 km 2 ). We developed a two-scale synthetic aperture radar interferometry (InSAR) approach. We describe spatial-temporal displacements (at millimeter-level accuracy), as measured by high-resolution TerraSAR/TanDEM-X satellite images, to provide a new solution to resolve the current controversy surrounding the potential structural collapse of monuments in Angkor. Multidisciplinary analysis in conjunction with a deterioration kinetics model offers new insights into the causes that trigger the potential decline of Angkor monuments. Our results show that pumping groundwater for residential and touristic establishments did not threaten the sustainability of monuments during 2011 to 2013; however, seasonal variations of the groundwater table and the thermodynamics of stone materials are factors that could trigger and/or aggravate the deterioration of monuments. These factors amplify known impacts of chemical weathering and biological alteration of temple materials. The InSAR solution reported in this study could have implications for monitoring and sustainable conservation of monuments in World Heritage sites elsewhere.

A Unified Experimental Approach for Estimation of Irrigationwater and Nitrate Leaching in Tree Crops

NASA Astrophysics Data System (ADS)

Hopmans, J. W.; Kandelous, M. M.; Moradi, A. B.

2014-12-01

Groundwater quality is specifically vulnerable in irrigated agricultural lands in California and many other(semi-)arid regions of the world. The routine application of nitrogen fertilizers with irrigation water in California is likely responsible for the high nitrate concentrations in groundwater, underlying much of its main agricultural areas. To optimize irrigation/fertigation practices, it is essential that irrigation and fertilizers are applied at the optimal concentration, place, and time to ensure maximum root uptake and minimize leaching losses to the groundwater. The applied irrigation water and dissolved fertilizer, as well as root growth and associated nitrate and water uptake, interact with soil properties and fertilizer source(s) in a complex manner that cannot easily be resolved. It is therefore that coupled experimental-modeling studies are required to allow for unraveling of the relevant complexities that result from typical field-wide spatial variations of soil texture and layering across farmer-managed fields. We present experimental approaches across a network of tree crop orchards in the San Joaquin Valley, that provide the necessary soil data of soil moisture, water potential and nitrate concentration to evaluate and optimize irrigation water management practices. Specifically, deep tensiometers were used to monitor in-situ continuous soil water potential gradients, for the purpose to compute leaching fluxes of water and nitrate at both the individual tree and field scale.

Radar interferometry offers new insights into threats to the Angkor site

PubMed Central

Chen, Fulong; Guo, Huadong; Ma, Peifeng; Lin, Hui; Wang, Cheng; Ishwaran, Natarajan; Hang, Peou

2017-01-01

The conservation of World Heritage is critical to the cultural and social sustainability of regions and nations. Risk monitoring and preventive diagnosis of threats to heritage sites in any given ecosystem are a complex and challenging task. Taking advantage of the performance of Earth Observation technologies, we measured the impacts of hitherto imperceptible and poorly understood factors of groundwater and temperature variations on the monuments in the Angkor World Heritage site (400 km2). We developed a two-scale synthetic aperture radar interferometry (InSAR) approach. We describe spatial-temporal displacements (at millimeter-level accuracy), as measured by high-resolution TerraSAR/TanDEM-X satellite images, to provide a new solution to resolve the current controversy surrounding the potential structural collapse of monuments in Angkor. Multidisciplinary analysis in conjunction with a deterioration kinetics model offers new insights into the causes that trigger the potential decline of Angkor monuments. Our results show that pumping groundwater for residential and touristic establishments did not threaten the sustainability of monuments during 2011 to 2013; however, seasonal variations of the groundwater table and the thermodynamics of stone materials are factors that could trigger and/or aggravate the deterioration of monuments. These factors amplify known impacts of chemical weathering and biological alteration of temple materials. The InSAR solution reported in this study could have implications for monitoring and sustainable conservation of monuments in World Heritage sites elsewhere. PMID:28275729

Hydrologic models and analysis of water availability in Cuyama Valley, California

USGS Publications Warehouse

Hanson, R.T.; Flint, Lorraine E.; Faunt, Claudia C.; Gibbs, Dennis R.; Schmid, Wolfgang

2014-01-01

Changes in population, agricultural development practices (including shifts to more water-intensive crops), and climate variability are placing increasingly larger demands on available water resources, particularly groundwater, in the Cuyama Valley, one of the most productive agricultural regions in Santa Barbara County. The goal of this study was to produce a model capable of being accurate at scales relevant to water management decisions that could be considered in the evaluation of the sustainable water supply. The Cuyama Valley Hydrologic Model (CUVHM) was designed to simulate the most important natural and human components of the hydrologic system, including components dependent on variations in climate, thereby providing a reliable assessment of groundwater conditions and processes that can inform water users and help to improve planning for future conditions. Model development included a revision of the conceptual model of the flow system, construction of a precipitation-runoff model using the Basin Characterization Model (BCM), and construction of an integrated hydrologic flow model with MODFLOW-One-Water Hydrologic Flow Model (MF-OWHM). The hydrologic models were calibrated to historical conditions of water and land use and, then, used to assess the use and movement of water throughout the Valley. These tools provide a means to understand the evolution of water use in the Valley, its availability, and the limits of sustainability. The conceptual model identified inflows and outflows that include the movement and use of water in both natural and anthropogenic systems. The groundwater flow system is characterized by a layered geologic sedimentary sequence that—in combination with the effects of groundwater pumping, natural recharge, and the application of irrigation water at the land surface—displays vertical hydraulic-head gradients. Overall, most of the agricultural demand for water in the Cuyama Valley in the initial part of the growing season is supplied by groundwater, which is augmented by precipitation during wet winter and spring seasons. In addition, the amount of groundwater used for irrigation varies from year to year in response to climate variation and can increase dramatically in dry years. Model simulation results, however, also indicated that irrigation may have been less efficient during wet years. Agricultural pumpage is a major component to simulated outflow that is often poorly recorded. Therefore, an integrated, coupled farm-process model is used to estimate historical pumpage for water-balance subregions that evolved with the development of groundwater in the Valley from 1949 through 2010. The integrated hydrologic model includes these water-balance subregions and delineates natural, municipal, and agricultural land use; streamflow networks; and groundwater flow systems. The redefinition of the geohydrologic framework (including the internal architecture of the sedimentary units) and incorporation of these units into the simulation of the regional groundwater flow system indicated that faults have compartmentalized the alluvial deposits into subregions, which have responded differently to regional groundwater flow, locations of recharge, and the effects of development. The Cuyama Valley comprises nine subregions grouped into three regional zones, the Main, Ventucopa Uplands, and Sierra Madre Foothills, which are fault bounded, represent different proportions of the three alluvial aquifers, and have different water quality. The CUVHM uses MF-OWHM to simulate and assess the use and movement of water, including the evolution of land use and related water-balance regions. The model is capable of being accurate at annual to interannual time frames and at subregional to valley-wide spatial scales, which allows for analysis of the groundwater hydrologic budget for the water years 1950–2010, as well as potential assessment of the sustainable use of groundwater. Simulated changes in storage over time showed that significant withdrawals from storage generally occurred not only during drought years (1976–77 and 1988–92) but also during the early stages of industrial agriculture, which was initially dominated by alfalfa production. Since the 1990s, agriculture has shifted to more water-intensive crops. Measured and simulated groundwater levels indicated substantial declines in selected subregions, mining of groundwater that is thousands to tens of thousands of years old, increased groundwater storage depletion, and land subsidence. Most of the recharge occurs in the upland regions of Ventucopa and Sierra Madre Foothills, and the largest fractions of pumpage and storage depletion occur in the Main subregion. The long-term imbalance between inflows and outflows resulted in simulated overdraft (groundwater withdrawals in excess of natural recharge) of the groundwater basin over the 61-year period of 1949–2010. Changes in storage varied considerably from year to year, depending on land use, pumpage, and climate conditions. Climatically driven factors can greatly affect inflows, outflows, and water use by more than a factor of two between wet and dry years. Although precipitation during inter-decadal wet years previously replenished the basin, the water use and storage depletion have lessened the effects of these major recharge events. Simulated and measured water-level altitudes indicated the presence of large areas where depressed water levels have resulted in large desaturated zones in the younger and Older Alluvium layers in the Main-zone subregions. The results of modeled projection of the base-case scenario 61 years into the future indicated that current supply-and-demand are unsustainable and will result in additional groundwater-level declines and related storage depletion and land subsidence. The reduced-supply and reduced-demand projections reduced groundwater storage depletion but may not allow for sustainable agriculture under current demands, agricultural practices, and land use.

Multi-modeling assessment of recent changes in groundwater resource: application to the semi-arid Haouz plain (Central Morocco)

NASA Astrophysics Data System (ADS)

Fakir, Younes; Brahim, Berjamy; Page Michel, Le; Fathallah, Sghrer; Houda, Nassah; Lionel, Jarlan; Raki Salah, Er; Vincent, Simonneaux; Said, Khabba

2015-04-01

The Haouz plain (6000 km2) is a part of the Tensift basin located in the Central Morocco. The plain has a semi-arid climate (250 mm/y of rainfall) and is bordered in the south by the High-Atlas mountains. Because the plain is highly anthropized, the water resources face heavy demands from various competing sectors, including agriculture (over than 273000 ha of irrigated areas), water supply for more than 2 million inhabitants and about 2 millions of tourists annually. Consequently the groundwater is being depleted on a large area of the plain, with problems of water scarcity which pose serious threats to water supplies and to sustainable development. The groundwater in the Haouz plain was modeled previously by MODFLOW (USGS groundwater numerical modeling) with annual time steps. In the present study a multi-modeling approach is applied. The aim is to enhance the evaluation of the groundwater pumping for irrigation, one of the most difficult data to estimate, and to improve the water balance assessment. In this purpose, two other models were added: SAMIR (Satellite Estimation of Agricultural Water Demand) and WEAP (integrated water resources planning). The three models are implemented at a monthly time step and calibrated over the 2001-2011 period, corresponding to 120 time steps. This multi-modeling allows assessing the evolution of water resources both in time and space. The results show deep changes during the last years which affect generally the water resources and groundwater particularly. These changes are induced by a remarkable urbanism development, succession of droughts, intensive agriculture activities and weak management of irrigation and water resources. Some indicators of these changes are as follow: (i) the groundwater table decrease varies between 1 to 3m/year, (ii) the groundwater depletion during the last ten year is equivalent to 50% of the lost reserves during 40 years, (iii) the annual groundwater deficit is about 100 hm3, (iv) the renewable water resources per capita are around 500 m3/year, (v) the agriculture takes 80% of the total water demand (vi) the net consumptive use of groundwater by agriculture represents 55 % of the total water consumed by agriculture. Consequently a strategy for water management for sustainable use is a pressing concern. In this frame, the multi-modeling system is expected to be a decision support system for present and future water resources management alternatives in the Haouz plain.

Flow pattern and residence time of groundwater within the south-eastern Taoudeni sedimentary basin (Burkina Faso, Mali)

NASA Astrophysics Data System (ADS)

Huneau, F.; Dakoure, D.; Celle-Jeanton, H.; Vitvar, T.; Ito, M.; Traore, S.; Compaore, N. F.; Jirakova, H.; Le Coustumer, P.

2011-10-01

SummaryThe knowledge about groundwater flow conditions within the Southeastern Taoudeni Basin Aquifer shared by Burkina Faso and Mali is relatively limited with very little information on potentiometric heads, recharge processes, residence time and water quality. A better evaluation of groundwater resources in this area is a strategic point for water resources management in the entire Soudano-Sahelian region which endures since the beginning of the twentieth century a continuous decrease in precipitation amount. This paper provides a transboundary synthesis using water ( 18O, 2H and 3H) and carbon isotopes ( 13C and 14C) in conjunction with hydrogeological and hydrochemical data. The objectives are to improve the conceptual model of groundwater recharge and flow within this sandstone reservoir, and to assess the changes in the aquifer due to water abstraction and recent climate changes including an insight into Sahelian aquifers palaeorecharge processes. The local meteoric water line for the Bobo-Dioulasso station is proposed: δ 2H = 8.0 (±0.5)δ 18O + 10.2 (±2.1). Two main tendencies can be derived from groundwater chemistry. First, a slight evolution from the Ca-Mg-HCO 3 type towards a Na-K-HCO 3 type that indicates developed interactions between groundwater and clay minerals related to the residence time of groundwater. A second tendency towards Cl-NO 3-SO 4-HCO 3 water types indicates the anthropogenic influence on groundwater related to the poor sanitary conditions observed around wells. The carbon-14 activity measured on the TDIC varies between 0.3 and 122 pmC, so our record contains samples covering a wide period from Actual to Pleistocene suggesting a continuous recharge of the system through time even if the Sahel region has endured many different climate phases which have influenced the infiltration and recharge processes. All groundwater samples have stable isotope compositions in the range of the present day regional and global meteoric water line which suggests that the sampled groundwater was not significantly affected by evaporation during recharge. Evolved waters are depleted relative to unevolved samples by 1.5-2‰ in δ 18O and 10-15‰ in δ 2H. The whole dataset support the hypothesis of a largely unified homogeneous aquifer system with a multilayered structure but it also points out the very low renewability of the resource and a strong anthropogenic contamination of the shallowest horizons.

Maximum likelihood Bayesian model averaging and its predictive analysis for groundwater reactive transport models

USGS Publications Warehouse

Curtis, Gary P.; Lu, Dan; Ye, Ming

2015-01-01

While Bayesian model averaging (BMA) has been widely used in groundwater modeling, it is infrequently applied to groundwater reactive transport modeling because of multiple sources of uncertainty in the coupled hydrogeochemical processes and because of the long execution time of each model run. To resolve these problems, this study analyzed different levels of uncertainty in a hierarchical way, and used the maximum likelihood version of BMA, i.e., MLBMA, to improve the computational efficiency. This study demonstrates the applicability of MLBMA to groundwater reactive transport modeling in a synthetic case in which twenty-seven reactive transport models were designed to predict the reactive transport of hexavalent uranium (U(VI)) based on observations at a former uranium mill site near Naturita, CO. These reactive transport models contain three uncertain model components, i.e., parameterization of hydraulic conductivity, configuration of model boundary, and surface complexation reactions that simulate U(VI) adsorption. These uncertain model components were aggregated into the alternative models by integrating a hierarchical structure into MLBMA. The modeling results of the individual models and MLBMA were analyzed to investigate their predictive performance. The predictive logscore results show that MLBMA generally outperforms the best model, suggesting that using MLBMA is a sound strategy to achieve more robust model predictions relative to a single model. MLBMA works best when the alternative models are structurally distinct and have diverse model predictions. When correlation in model structure exists, two strategies were used to improve predictive performance by retaining structurally distinct models or assigning smaller prior model probabilities to correlated models. Since the synthetic models were designed using data from the Naturita site, the results of this study are expected to provide guidance for real-world modeling. Limitations of applying MLBMA to the synthetic study and future real-world modeling are discussed.

Phylogenetic and Genomic Analyses Resolve the Origin of Important Plant Genes Derived from Transposable Elements.

PubMed

Joly-Lopez, Zoé; Hoen, Douglas R; Blanchette, Mathieu; Bureau, Thomas E

2016-08-01

Once perceived as merely selfish, transposable elements (TEs) are now recognized as potent agents of adaptation. One way TEs contribute to evolution is through TE exaptation, a process whereby TEs, which persist by replicating in the genome, transform into novel host genes, which persist by conferring phenotypic benefits. Known exapted TEs (ETEs) contribute diverse and vital functions, and may facilitate punctuated equilibrium, yet little is known about this process. To better understand TE exaptation, we designed an approach to resolve the phylogenetic context and timing of exaptation events and subsequent patterns of ETE diversification. Starting with known ETEs, we search in diverse genomes for basal ETEs and closely related TEs, carefully curate the numerous candidate sequences, and infer detailed phylogenies. To distinguish TEs from ETEs, we also weigh several key genomic characteristics including repetitiveness, terminal repeats, pseudogenic features, and conserved domains. Applying this approach to the well-characterized plant ETEs MUG and FHY3, we show that each group is paraphyletic and we argue that this pattern demonstrates that each originated in not one but multiple exaptation events. These exaptations and subsequent ETE diversification occurred throughout angiosperm evolution including the crown group expansion, the angiosperm radiation, and the primitive evolution of angiosperms. In addition, we detect evidence of several putative novel ETE families. Our findings support the hypothesis that TE exaptation generates novel genes more frequently than is currently thought, often coinciding with key periods of evolution. © The Author 2016. Published by Oxford University Press on behalf of the Society for Molecular Biology and Evolution.

Internal constitution and evolution of the moon.

NASA Technical Reports Server (NTRS)

Solomon, S. C.; Toksoz, M. N.

1973-01-01

The composition, structure and evolution of the moon's interior are narrowly constrained by a large assortment of physical and chemical data. Models of the thermal evolution of the moon that fit the chronology of igneous activity on the lunar surface, the stress history of the lunar lithosphere implied by the presence of mascons, and the surface concentrations of radioactive elements, involve extensive differentiation early in lunar history. This differentiation may be the result of rapid accretion and large-scale melting or of primary chemical layering during accretion; differences in present-day temperatures for these two possibilities are significant only in the inner 1000 km of the moon and may not be resolvable.

Gamma-ray luminosity and photon index evolution of FSRQ blazars and contribution to the gamma-ray background

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singal, J.; Ko, A.; Petrosian, V., E-mail: jsingal@richmond.edu

We present the redshift evolutions and distributions of the gamma-ray luminosity and photon spectral index of flat spectrum radio quasar (FSRQ) type blazars, using non-parametric methods to obtain the evolutions and distributions directly from the data. The sample we use for analysis consists of almost all FSRQs observed with a greater than approximately 7σ detection threshold in the first-year catalog of the Fermi Gamma-ray Space Telescope's Large Area Telescope, with redshifts as determined from optical spectroscopy by Shaw et al. We find that FSQRs undergo rapid gamma-ray luminosity evolution, but negligible photon index evolution, with redshift. With these evolutions accountedmore » for we determine the density evolution and luminosity function of FSRQs and calculate their total contribution to the extragalactic gamma-ray background radiation, resolved and unresolved, which is found to be 16(+10/–4)%, in agreement with previous studies.« less

Simulation of Groundwater Flow in the Coastal Plain Aquifer System of Virginia

USGS Publications Warehouse

Heywood, Charles E.; Pope, Jason P.

2009-01-01

The groundwater model documented in this report simulates the transient evolution of water levels in the aquifers and confining units of the Virginia Coastal Plain and adjacent portions of Maryland and North Carolina since 1890. Groundwater withdrawals have lowered water levels in Virginia Coastal Plain aquifers and have resulted in drawdown in the Potomac aquifer exceeding 200 feet in some areas. The discovery of the Chesapeake Bay impact crater and a revised conceptualization of the Potomac aquifer are two major changes to the hydrogeologic framework that have been incorporated into the groundwater model. The spatial scale of the model was selected on the basis of the primary function of the model of assessing the regional water-level responses of the confined aquifers beneath the Coastal Plain. The local horizontal groundwater flow through the surficial aquifer is not intended to be accurately simulated. Representation of recharge, evapotranspiration, and interaction with surface-water features, such as major rivers, lakes, the Chesapeake Bay, and the Atlantic Ocean, enable simulation of shallow flow-system details that influence locations of recharge to and discharge from the deeper confined flow system. The increased density of groundwater associated with the transition from fresh to salty groundwater near the Atlantic Ocean affects regional groundwater flow and was simulated with the Variable Density Flow Process of SEAWAT (a U.S. Geological Survey program for simulation of three-dimensional variable-density groundwater flow and transport). The groundwater density distribution was generated by a separate 108,000-year simulation of Pleistocene freshwater flushing around the Chesapeake Bay impact crater during transient sea-level changes. Specified-flux boundaries simulate increasing groundwater underflow out of the model domain into Maryland and minor underflow from the Piedmont Province into the model domain. Reported withdrawals accounted for approximately 75 percent of the total groundwater withdrawn from Coastal Plain aquifers during the year 2000. Unreported self-supplied withdrawals were simulated in the groundwater model by specifying their probable locations, magnitudes, and aquifer assignments on the basis of a separate study of domestic-well characteristics in Virginia. The groundwater flow model was calibrated to 7,183 historic water-level observations from 497 observation wells with the parameter-estimation codes UCODE-2005 and PEST. Most water-level observations were from the Potomac aquifer system, which permitted a more complex spatial distribution of simulated hydraulic conductivity within the Potomac aquifer than was possible for other aquifers. Zone, function, and pilot-point approaches were used to distribute assigned hydraulic properties within the aquifer system. The good fit (root mean square error = 3.6 feet) of simulated to observed water levels and reasonableness of the estimated parameter values indicate the model is a good representation of the physical groundwater flow system. The magnitudes and temporal and spatial distributions of residuals indicate no appreciable model bias. The model is intended to be useful for predicting changes in regional groundwater levels in the confined aquifer system in response to future pumping. Because the transient release of water stored in low-permeability confining units is simulated, drawdowns resulting from simulated pumping stresses may change substantially through time before reaching steady state. Consequently, transient simulations of water levels at different future times will be more accurate than a steady-state simulation for evaluating probable future aquifer-system responses to proposed pumping.

Isotopic composition (oxygen and hydrogen) of groundwater in Norway - a review of current knowledge and future perspectives

NASA Astrophysics Data System (ADS)

Kracht, O.

2012-04-01

A review of current knowledge and available data covering the stable isotope composition of groundwater in Norway is presented. Furthermore, the future challenge of obtaining systematic background datasets and of integrating isotopes into the mainstream of hydrogeological observation programmes is discussed. I will summarize our experiences gained from different preliminary studies and will try to identify relationships to existing datasets, historical registrations, and networks on precipitation data. The study of transient effects in hydrological cycles is highly topical as these are supposed to provide means for investigating the effects of climate change and increasing human activities. From a hydrogeological point of view, is critical to establish suitable tools for the large scale observation of changes in groundwater recharge and depletion, their likely controls, and the expected nature of responses to changing climate, urbanization and other human activities. In this context, stable isotopes (δ18O and δ2H of water) can provide an expedient instrument to investigate the general hydrological setting, connections, and pathways of various scale aquifer systems. However, we are up to now missing an expedient background dataset on hydrogeological and hydrological stable isotopes observations for mainland Norway. Against this background, during years 2010 and 2011 the Geological Survey of Norway (NGU) organized two nation-wide sampling campaigns on the stable isotope composition of modern groundwater. These pilot studies aimed to obtain a first overview about the data ranges and natural variations to be expected. We used stations from the existing Norwegian Groundwater Monitoring Network (Landsomfattende Grunnvannsnett, LGN) to collect samples of groundwater at 55 different locations throughout Norway. As a main characteristic of these two datasets, all δ18O and δ2H values of the "LGN series" were well correlated and plotted close to the global meteoric water line. This essentially documents the in principal exclusively meteoric origin of these waters, and indicates that the LGN groundwaters investigated shared the same type of origin: (i) evaporation from the ocean, and (ii) isotopic enrichment by rainout (continental effect). Conversely this also indicates that other processes (re-evaporation, admixture of water with a different genesis, etc.) did not have significant influence in this dataset. In parallel, two more detailed local application studies have been conducted in unconsolidated glaciofluvial aquifers in S-Norway (eastern part of the Gardermoen / Øvre Romerike Aquifer in Akershus county, and glaciofluvial deposits at the Granli waterworks of Kongsvinger in Hedmark county). In these investigations, detailed vertical profiles obtained with multi level sampling devices displayed systematic vertical evolution of groundwater isotopic composition, and it is demonstrated how an extended local dataset can enable to discuss the discrimination between different groundwater / surface water influences, and supports the planning of groundwater exploitations and groundwater water resources management.

Addressing the [O III] / Hβ offset in metal poor star forming galaxies found in the RESOLVE survey and ECO catalog

NASA Astrophysics Data System (ADS)

Richardson, Chris T.; Kannappan, Sheila; Moffett, Amanda J.; RESOLVE survey team

2018-06-01

Metal poor star forming galaxies sit on the far left wing of the BPT diagram just below traditional demarcation lines. The basic approach to reproducing their emission lines by coupling photoionization models to stellar population synthesis models underestimates the observed [O III] / Hβ ratio by a factor 0.3-0.5 dex. We classified galaxies as metal poor in the REsolved Spectroscopy of a Local VolumE (RESOLVE) survey and the Environmental COntext (ECO) catalog by using the IZI code based off of Bayesian inference. We used a variety of stellar population synthesis codes to generate SEDs covering a range of starburst ages and metallicities including both secular and binary stellar evolution. Here, we show that multiple SPS codes can produce SEDs hard enough to reduce the offset assuming that simple, and perhaps unjustified, nebular conditions hold. Adopting more realistic nebular conditions shows that, despite the recent emphasis placed on binary evolution to fit high O III ratios, none of our SEDs can reduce the offset. We propose several new solutions including using ensembles of nebular clouds and improved microphysics to address this issue. This work is supported by National Science Foundation awards OCI-1053575, though XSEDE award TG-AST140040, and NSF awards AST-0955368 and CISE/ACI-1156614.

Geochemical and microbiological assessment of groundwater status: a case study

NASA Astrophysics Data System (ADS)

Preziosi, E.; Del Bon, A.; Amalfitano, S.; Fazi, S.; Zoppini, A.; Parrone, D.; Ghergo, S.

2012-04-01

The qualitative status of the groundwater resources is drawing increasingly attention in relation to the requirements of the European legislative framework. The monitoring strategies are developed by considering the chemical processes affecting groundwater quality. However, despite the use of biological indicators is a common practice for the qualitative assessment of surface waters, a similar approach is hardly being taken into account by policy makers for ground waters. Aquifers are key environments due to the ecosystem capability to ameliorate water quality, e.g. through the natural biodegradation of chemical contaminants. The objective of this research was to characterize a porous water table aquifer from a geochemical and microbiological point of view, aiming to link the hydrogeochemical properties to distribution patterns of the free-living microbial communities. The broader perspective is to integrate the role of microorganisms in the groundwater evolution processes, with new insights in the knowledge of the different microbial communities inhabiting different aquifer typologies. Moreover, microbiological parameters that could be used as a valuable indicator of groundwater quality are sought. A field-scale analysis was performed along the southern Sabatini Mounts aquifer (Central Italy, 50 sampling sites), in an area of about 340 square km, where Pleistocene volcanic products overlay Pleistocene gravel and silt-clay layers, the latter being much more widespread in the downgradient part of the study area. The selected aquifer is contaminated by natural origin elements such as arsenic and fluoride, as well as by human activities, both diffuse (agriculture) and localized, especially in the downgradient part of the aquifer (e.g. landfills, quarries, oil deposits). The main physicochemical parameters of ground waters were determined in situ (redox status, pH, conductivity, T, DO, alkalinity) and in laboratory by ionic chromatography and mass spectrometry (major and trace elements, including arsenic). Total bacterial abundance and vitality (live/dead cell ratio) was determined by combining Flow Cytometry with a double staining fluorescence assay, while the microbial community composition was analyzed through hybridization techniques (CARD-FISH). The hydrogeochemical characterization defined an arsenic rich, mainly alkaline-earth bicarbonate type, which evolves downgradiently towards a more calcium rich water. The variability of bacterial abundance was nonetheless high and the percentage of dead bacterial cells shows a significant correlation with the arsenic concentration. In addition, differences of the taxa along the flow path were detected with an increasing abundance of Delta-Proteobacteria in the more anoxic sites. Overall, our results highlighted that a multidisciplinary approach, which combines geochemical and microbiological surveys, can describe more appropriately ground water status and the evolution processes in the aquifer.

The French network of hydrogeological sites H+

NASA Astrophysics Data System (ADS)

Davy, P.; Le Borgne, T.; Bour, O.; Gautier, S.; Porel, G.; Bodin, J.; de Dreuzy, J.; Pezard, P.

2008-12-01

For groundwater issues (potential leakages in waste repository, aquifer management "), the development of modeling techniques is far ahead of the actual knowledge of aquifers. This raises two fundamental issues: 1) which and how much data are necessary to make predictions accurate enough for aquifer management issues; 2) which models remain relevant to describe the heterogeneity and complexity of geological systems. The French observatory H+ was created in 2002 with the twofold motivation of acquiring a large database for validating models of heterogeneous aquifers, and of surveying groundwater quality evolution in the context of environmental changes. H+ is a network of 4 sites (Ploemeur, Brittany, France; HES Poitiers, France; Cadarache, France; Campos, Mallorca, Spain) with different geological, climatic, and economic contexts. All of them are characterized by a highly heterogeneous structure (fractured crystalline basement for Ploemeur, karstified and fractured limestone for Poitiers, Cadarache and Mallorca), which is far to be taken into account by basic models. Ploemeur is exploited as a tap-water plant for a medium-size coastal city (15,000 inhabitants) for 20 years. Each site is developed for long term investigation and monitoring. They involves a dense network of boreholes, detailed geological and geophysical surveys, periodic campaigns and/or permanent measurements of groundwater flow, water chemistry, geophysical signals (including ground motions), climatic parameter, etc. Several large-scale flow experiments are scheduled per year to investigate the aquifer structure with combined geophysical, hydrogeological, and geochemical instruments. All this information is recorded in a database that has been developed to improve the sustainability and quality of data, and to be used as a collaborative tool for both site researchers and modelers. This project lasts now for 5 years. It is a short time to collect the amount of information necessary to apprehend the complexity of aquifers; but it is already enough to obtain a few important scientific results about the very nature of the flow heterogeneity, the origin and residence time of water elements, the kinetic of geochemical processes, etc. We have also developed new methods to investigate aquifers (in-situ flow measurements, flow experiment designs, groundwater dating, versatile in-situ probes, etc.). This experience aiming at building up long term knowledge appears extremely useful to address critical issues related to groundwater aquifers: the structure and occurrence of productive aquifer in crystalline basement, the assessment of aquifer protection area in the context of highly heterogeneous flow, the biochemical reactivity processes, the long term evolution of both water quantity and quality in the context of significant environmental changes, for instance.

Integrated Research Methods for Applied Urban Hydrogeology of Karst Sites

NASA Astrophysics Data System (ADS)

Epting, J.; Romanov, D. K.; Kaufmann, G.; Huggenberger, P.

2008-12-01

Integrated and adaptive surface- and groundwater monitoring and management in urban areas require innovative process-oriented approaches. To accomplish this, it is necessary to develop and combine interdisciplinary instruments that facilitate adequately quantifying cumulative effects on groundwater flow regimes. While the characterization and modeling of flow in heterogeneous and fractured media has been investigated intensively, there are no well-developed long-term hydrogeological research sites for gypsum karst. Considering that infrastructures in karst regions, particularly in gypsum, are prone to subsidence, severe problems can arise in urban areas. In the 1880's, a river dam was constructed on gypsum-containing rock, Southeast of Basel, Switzerland. Over the last 30 years, subsidence of the dam and an adjacent highway has been observed. Surface water infiltrates upstream of the dam, circulates in the gravel deposits and in the weathered bedrock around and beneath the dam and exfiltrates downstream into the river. These processes enhance karstification processes in the soluble units of the gypsum. As a result an extended weathering zone within the bedrock and the development of preferential flow paths within voids and conduits can be observed. To prevent further subsidence, construction measures were conducted in two major project phases in 2006 and 2007. The highway was supported by a large number of pillars embedded in the non- weathered rock and by a sealing pile wall, to prevent infiltrating river water circulating around the dam and beneath the foundation of the highway. To safeguard surface and subsurface water resources during the construction measures, an extensive observation network was set up. Protection schemes and geotechnical investigations that are necessary for engineering projects often provide "windows of opportunity", bearing the possibility to change perceptions concerning the sustainable development of water resources and coordinate future measures. Theories describing the evolution of karst systems are mainly based on conceptual models. Although these models are based on fundamental and well established physical and chemical principles that allow studying important processes from initial small scale fracture networks to the mature karst, systems for monitoring the evolution of karst phenomena are rare. Integrated process-oriented investigation methods are presented, comprising the combination of multiple data sources (lithostratigraphic information of boreholes, extensive groundwater monitoring, dye tracer tests, geophysics) with high-resolution numerical groundwater modeling and model simulations of karstification below the dam. Subsequently, different scenarios evaluated the future development of the groundwater flow regime, the karstification processes as well as possible remediation measures. The approach presented assists in optimizing investigation methods, including measurement and monitoring technologies with predictive character for similar subsidence problems within karst environments in urban areas.

Lithological Influences on Occurrence of High-Fluoride Waters in The Central Kenya Rift

NASA Astrophysics Data System (ADS)

Olaka, L. A.; Musolff, A.; Mulch, A.; Olago, D.; Odada, E. O.

2013-12-01

Within the East African rift, groundwater recharge results from the complex interplay of geology, land cover, geomorphology, climate and on going volcano-tectonic processes across a broad range of spatial and temporal scales. The interrelationships between these factors create complex patterns of water availability, reliability and quality. The hydrochemical evolution of the waters is further complex due to the different climatic regimes and geothermal processes going on in this area. High fluoridic waters within the rift have been reported by few studies, while dental fluorosis is high among the inhabitants of the rift. The natural sources of fluoride in waters can be from weathering of fluorine bearing minerals in rocks, volcanic or fumarolic activities. Fluoride concentration in water depends on a number of factors including pH, temperature, time of water-rock formation contact and geochemical processes. Knowledge of the sources and dispersion of fluoride in both surface and groundwaters within the central Kenya rift and seasonal variations between wet and dry seasons is still poor. The Central Kenya rift is marked by active tectonics, volcanic activity and fumarolic activity, the rocks are majorly volcanics: rhyolites, tuffs, basalts, phonolites, ashes and agglomerates some are highly fractured. Major NW-SE faults bound the rift escarpment while the rift floor is marked by N-S striking faults We combine petrographic, hydrochemistry and structural information to determine the sources and enrichment pathways of high fluoridic waters within the Naivasha catchment. A total of 120 water samples for both the dry season (January-February2012) and after wet season (June-July 2013) from springs, rivers, lakes, hand dug wells, fumaroles and boreholes within the Naivasha catchment are collected and analysed for fluoride, physicochemical parameters and stable isotopes (δ2 H, δ18 O) in order to determine the origin and evolution of the waters. Additionally, 30 soil and rock samples were also collected and analysed for fluoride, and rock samples were subjected to petrographic investigations and X-ray diffraction. The fluoride levels in surface and groundwater for the dry season range from 0.019 - 50.14 mg/L, on average above the WHO permissible limit. The high fluoride occurs both in the lake and groundwater. Preliminary petrographic studies show considerable fluoride in micas. The study is on-going and plans to present the relative abundances of fluoride in the lithology as the sources and the fluoride enrichment pathways of the groundwater within the Central Kenya rift.

Structure-Preserving Variational Multiscale Modeling of Turbulent Incompressible Flow with Subgrid Vortices

NASA Astrophysics Data System (ADS)

Evans, John; Coley, Christopher; Aronson, Ryan; Nelson, Corey

2017-11-01

In this talk, a large eddy simulation methodology for turbulent incompressible flow will be presented which combines the best features of divergence-conforming discretizations and the residual-based variational multiscale approach to large eddy simulation. In this method, the resolved motion is represented using a divergence-conforming discretization, that is, a discretization that preserves the incompressibility constraint in a pointwise manner, and the unresolved fluid motion is explicitly modeled by subgrid vortices that lie within individual grid cells. The evolution of the subgrid vortices is governed by dynamical model equations driven by the residual of the resolved motion. Consequently, the subgrid vortices appropriately vanish for laminar flow and fully resolved turbulent flow. As the resolved velocity field and subgrid vortices are both divergence-free, the methodology conserves mass in a pointwise sense and admits discrete balance laws for energy, enstrophy, and helicity. Numerical results demonstrate the methodology yields improved results versus state-of-the-art eddy viscosity models in the context of transitional, wall-bounded, and rotational flow when a divergence-conforming B-spline discretization is utilized to represent the resolved motion.

Goodbye to 'one by one' genetics

PubMed Central

Theologis, Athanasios

2001-01-01

The completion of the Arabidopsis thaliana (mustard weed) genome sequence constitutes a major breakthrough in plant biology. It will revolutionize how we answer questions about the biology and evolution of plants as well as how we confront and resolve world-wide agricultural problems. PMID:11305933

The Importance of Capturing Topographic Features for Modeling Groundwater Flow and Transport in Mountainous Watersheds

NASA Astrophysics Data System (ADS)

Wang, C.; Gomez-Velez, J. D.; Wilson, J. L.

2017-12-01

Groundwater plays a key role in runoff generation and stream water chemistry from reach to watershed scales. The spatial distribution of ridges and streams can influence the spatial patterns of groundwater recharge and drainage, specially in mountainous terrains where these features are more prominent. However, typical modeling efforts simplify or ignore some of these features due to computational limitations without a systematic investigation of the implications for flow and transport within the watershed. In this study, we investigate the effect of capturing key topographic features on modeled groundwater flow and transport characteristics in a mountainous watershed. We build model scenarios of different topographic complexity levels (TCLs) to capture different levels of representation of streams and ridges in the model. Modeled baseflow and groundwater mean residence time (MRT) are used to quantify the differences among TCLs. Our results show that capturing the streams and ridges has a significant influence on simulated groundwater flow and transport patterns. Topographic complexity controls the proportion of baseflow generated from local, intermediate, and regional flow paths, thus influencing the amount and MRT of basefow flowing into streams of different Horton-Strahler orders. We further simulate the concentration of solute exported into streams from subsurface chemical weathering. The concentration of chemical weathering products in streams is less sensitive to model TCL due to the thermodynamic constraint on the equilibrium concentration of the chemical weathering. We also tested the influence of geology on the effect of TCL. The effect of TCL is consistent under different geological conditions; however, it is enhanced in models with low hydraulic conductivity because more of the flow is forced into shallow and local flow paths. All of these changes can affect our ability to interpret environmental tracer data and predict bio- and geo-chemical evolution of stream water in mountainous watersheds.

Salinization of groundwater in arid and semi-arid zones: an example from Tajarak, western Iran

NASA Astrophysics Data System (ADS)

Jalali, Mohsen

2007-06-01

Study of the groundwater samples from Tajarak area, western Iran, was carried out in order to assess their chemical compositions and suitability for agricultural purposes. All of the groundwaters are grouped into two categories: relatively low mineralized of Ca-HCO3 and Na-HCO3 types and high mineralized waters of Na-SO4 and Na-Cl types. The chemical evolution of groundwater is primarily controlled by water-rock interactions mainly weathering of aluminosilicates, dissolution of carbonate minerals and cation exchange reactions. Calculated values of pCO2 for the groundwater samples range from 2.34 × 10-4 to 1.07 × 10-1 with a mean value of 1.41 × 10-2 (atm), which is above the pCO2 of the earth’s atmosphere (10-3.5). The groundwater is oversaturated with respect to calcite, aragonite and dolomite and undersaturated with respect to gypsum, anhydrite and halite. According to the EC and SAR the most dominant classes (C3-S1, C4-S1 and C4-S2) were found. With respect to adjusted SAR (adj SAR), the sodium (Na+) content in 90% of water samples in group A is regarded as low and can be used for irrigation in almost all soils with little danger of the development of harmful levels of exchangeable Na+, while in 40 and 37% of water samples in group B the intensity of problem is moderate and high, respectively. Such water, when used for irrigation will lead to cation exchange and Na+ is adsorbed on clay minerals while calcium (Ca2+) and magnesium (Mg2+) are released to the liquid phase. The salinity hazard is regarded as medium to high and special management for salinity control is required. Thus, the water quality for irrigation is low, providing the necessary drainage to avoid the build-up of toxic salt concentrations.

Groundwater controls on river channel pattern

NASA Astrophysics Data System (ADS)

Bätz, Nico; Colombini, Pauline; Cherubini, Paolo; Lane, Stuart N.

2017-04-01

Braided rivers are characterized by high rates of morphological change. However, despite the potential for frequent disturbance, vegetated patches may develop within this system and influence long-term channel dynamics and channel patterns through the "engineering effects" of vegetation. The stabilizing effect of developing vegetation on morphological change has been widely shown by flume experiments and (historic) aerial pictures analysis. Thus, there is a balance between disturbance and stabilization, mediated through vegetation, that may determine the long-term geomorphic and biogeomorphic evolution of the river. It follows that with a change in disturbance frequency relative to the rate of vegetation establishment, a systematic geomorphological shift could occur. Research has addressed how changes in disturbance frequency affect river channel pattern, but has rarely addressed the way in which the stabilizing effects of biogeomorphic succession interact with disturbance frequency to maintain a river in a more dynamic or a less dynamic state. Here, we quantify how the interplay between groundwater access, disturbance frequency and vegetation succession, drive changes in channel pattern. We studied this complex interplay on a transitional gravel-bed river system (braided, wandering, meandering) close to Geneva (Switzerland) - the Allondon River. Dendroecological analysis demonstrate that vegetation growth is driven by groundwater access. Groundwater access conditions the rate of vegetation stabilization at the sub-reach scale and, due to a reduction in flood-related disturbance frequency over the last 50 years, drives a change in channel pattern. Where groundwater is shallower, vegetation encroachment rates were high and as flood-related disturbance decreased, the river has shifted towards a meandering state. Where groundwater was deeper, vegetation growth was limited by water-access and thus vegetation encroachment rates were low. Even though there was a reduction in flood disturbance, it was still sufficient to maintain a wandering/braided state. Thus, it appears that access to groundwater can control river channel pattern through its impact upon the "engineering effects" of vegetation. The results are important for river management as they highlight the non-linearity of developing vegetation in dynamic alluvial floodplains and the importance of considering the wider environmental setting and associated feedbacks between biotic and abiotic river components in defining long-term geomorphological river response.

An Optimization Principle for Deriving Nonequilibrium Statistical Models of Hamiltonian Dynamics

NASA Astrophysics Data System (ADS)

Turkington, Bruce

2013-08-01

A general method for deriving closed reduced models of Hamiltonian dynamical systems is developed using techniques from optimization and statistical estimation. Given a vector of resolved variables, selected to describe the macroscopic state of the system, a family of quasi-equilibrium probability densities on phase space corresponding to the resolved variables is employed as a statistical model, and the evolution of the mean resolved vector is estimated by optimizing over paths of these densities. Specifically, a cost function is constructed to quantify the lack-of-fit to the microscopic dynamics of any feasible path of densities from the statistical model; it is an ensemble-averaged, weighted, squared-norm of the residual that results from submitting the path of densities to the Liouville equation. The path that minimizes the time integral of the cost function determines the best-fit evolution of the mean resolved vector. The closed reduced equations satisfied by the optimal path are derived by Hamilton-Jacobi theory. When expressed in terms of the macroscopic variables, these equations have the generic structure of governing equations for nonequilibrium thermodynamics. In particular, the value function for the optimization principle coincides with the dissipation potential that defines the relation between thermodynamic forces and fluxes. The adjustable closure parameters in the best-fit reduced equations depend explicitly on the arbitrary weights that enter into the lack-of-fit cost function. Two particular model reductions are outlined to illustrate the general method. In each example the set of weights in the optimization principle contracts into a single effective closure parameter.

Assessment of parametric uncertainty for groundwater reactive transport modeling,

USGS Publications Warehouse

Shi, Xiaoqing; Ye, Ming; Curtis, Gary P.; Miller, Geoffery L.; Meyer, Philip D.; Kohler, Matthias; Yabusaki, Steve; Wu, Jichun

2014-01-01

The validity of using Gaussian assumptions for model residuals in uncertainty quantification of a groundwater reactive transport model was evaluated in this study. Least squares regression methods explicitly assume Gaussian residuals, and the assumption leads to Gaussian likelihood functions, model parameters, and model predictions. While the Bayesian methods do not explicitly require the Gaussian assumption, Gaussian residuals are widely used. This paper shows that the residuals of the reactive transport model are non-Gaussian, heteroscedastic, and correlated in time; characterizing them requires using a generalized likelihood function such as the formal generalized likelihood function developed by Schoups and Vrugt (2010). For the surface complexation model considered in this study for simulating uranium reactive transport in groundwater, parametric uncertainty is quantified using the least squares regression methods and Bayesian methods with both Gaussian and formal generalized likelihood functions. While the least squares methods and Bayesian methods with Gaussian likelihood function produce similar Gaussian parameter distributions, the parameter distributions of Bayesian uncertainty quantification using the formal generalized likelihood function are non-Gaussian. In addition, predictive performance of formal generalized likelihood function is superior to that of least squares regression and Bayesian methods with Gaussian likelihood function. The Bayesian uncertainty quantification is conducted using the differential evolution adaptive metropolis (DREAM(zs)) algorithm; as a Markov chain Monte Carlo (MCMC) method, it is a robust tool for quantifying uncertainty in groundwater reactive transport models. For the surface complexation model, the regression-based local sensitivity analysis and Morris- and DREAM(ZS)-based global sensitivity analysis yield almost identical ranking of parameter importance. The uncertainty analysis may help select appropriate likelihood functions, improve model calibration, and reduce predictive uncertainty in other groundwater reactive transport and environmental modeling.

Chemical evolution of groundwater in the Wilcox aquifer of the northern Gulf Coastal Plain, USA

NASA Astrophysics Data System (ADS)

Haile, Estifanos; Fryar, Alan E.

2017-12-01

The Wilcox aquifer is a major groundwater resource in the northern Gulf Coastal Plain (lower Mississippi Valley) of the USA, yet the processes controlling water chemistry in this clastic aquifer have received relatively little attention. The current study combines analyses of solutes and stable isotopes in groundwater, petrography of core samples, and geochemical modeling to identify plausible reactions along a regional flow path ˜300 km long. The hydrochemical facies evolves from Ca-HCO3 upgradient to Na-HCO3 downgradient, with a sequential zonation of terminal electron-accepting processes from Fe(III) reduction through SO4 2- reduction to methanogenesis. In particular, decreasing SO4 2- and increasing δ34S of SO4 2- along the flow path, as well as observations of authigenic pyrite in core samples, provide evidence of SO4 2- reduction. Values of δ13C in groundwater suggest that dissolved inorganic carbon is contributed both by oxidation of sedimentary organic matter and calcite dissolution. Inverse modeling identified multiple plausible sets of reactions between sampled wells, which typically involved cation exchange, pyrite precipitation, CH2O oxidation, and dissolution of amorphous Fe(OH)3, calcite, or siderite. These reactions are consistent with processes identified in previous studies of Atlantic Coastal Plain aquifers. Contrasts in groundwater chemistry between the Wilcox and the underlying McNairy and overlying Claiborne aquifers indicate that confining units are relatively effective in limiting cross-formational flow, but localized cross-formational mixing could occur via fault zones. Consequently, increased pumping in the vicinity of fault zones could facilitate upward movement of saline water into the Wilcox.

Application of Differential Evolutionary Optimization Methodology for Parameter Structure Identification in Groundwater Modeling

NASA Astrophysics Data System (ADS)

Chiu, Y.; Nishikawa, T.

2013-12-01

With the increasing complexity of parameter-structure identification (PSI) in groundwater modeling, there is a need for robust, fast, and accurate optimizers in the groundwater-hydrology field. For this work, PSI is defined as identifying parameter dimension, structure, and value. In this study, Voronoi tessellation and differential evolution (DE) are used to solve the optimal PSI problem. Voronoi tessellation is used for automatic parameterization, whereby stepwise regression and the error covariance matrix are used to determine the optimal parameter dimension. DE is a novel global optimizer that can be used to solve nonlinear, nondifferentiable, and multimodal optimization problems. It can be viewed as an improved version of genetic algorithms and employs a simple cycle of mutation, crossover, and selection operations. DE is used to estimate the optimal parameter structure and its associated values. A synthetic numerical experiment of continuous hydraulic conductivity distribution was conducted to demonstrate the proposed methodology. The results indicate that DE can identify the global optimum effectively and efficiently. A sensitivity analysis of the control parameters (i.e., the population size, mutation scaling factor, crossover rate, and mutation schemes) was performed to examine their influence on the objective function. The proposed DE was then applied to solve a complex parameter-estimation problem for a small desert groundwater basin in Southern California. Hydraulic conductivity, specific yield, specific storage, fault conductance, and recharge components were estimated simultaneously. Comparison of DE and a traditional gradient-based approach (PEST) shows DE to be more robust and efficient. The results of this work not only provide an alternative for PSI in groundwater models, but also extend DE applications towards solving complex, regional-scale water management optimization problems.

Groundwater nitrate pollution and climate change: learnings from a water balance-based analysis of several aquifers in a western Mediterranean region (Catalonia).

PubMed

Mas-Pla, Josep; Menció, Anna

2018-04-11

Climate change will affect the dynamics of the hydrogeological systems and their water resources quality; in particular nitrate, which is herein taken as a paradigmatic pollutant to illustrate the effects of climate change on groundwater quality. Based on climatic predictions of temperature and precipitation for the horizon of 2021 and 2050, as well as on land use distribution, water balances are recalculated for the hydrological basins of distinct aquifer systems in a western Mediterranean region as Catalonia (NE Spain) in order to determine the reduction of available water resources. Besides the fact that climate change will represent a decrease of water availability, we qualitatively discuss the modifications that will result from the future climatic scenarios and their impact on nitrate pollution according to the geological setting of the selected aquifers. Climate effects in groundwater quality are described according to hydrological, environmental, socio-economic, and political concerns. Water reduction stands as a major issue that will control stream-aquifer interactions and subsurface recharge, leading to a general modification of nitrate in groundwater as dilution varies. A nitrate mass balance model provides a gross estimation of potential nitrate evolution in these aquifers, and it points out that the control of the fertilizer load will be crucial to achieve adequate nitrate content in groundwater. Reclaimed wastewater stands as local reliable resource, yet its amount will only satisfy a fraction of the loss of available resources due to climate change. Finally, an integrated management perspective is necessary to avoid unplanned actions from private initiatives that will jeopardize the achievement of sustainable water resources exploitation under distinct hydrological scenarios.

Building factorial regression models to explain and predict nitrate concentrations in groundwater under agricultural land

NASA Astrophysics Data System (ADS)

Stigter, T. Y.; Ribeiro, L.; Dill, A. M. M. Carvalho

2008-07-01

SummaryFactorial regression models, based on correspondence analysis, are built to explain the high nitrate concentrations in groundwater beneath an agricultural area in the south of Portugal, exceeding 300 mg/l, as a function of chemical variables, electrical conductivity (EC), land use and hydrogeological setting. Two important advantages of the proposed methodology are that qualitative parameters can be involved in the regression analysis and that multicollinearity is avoided. Regression is performed on eigenvectors extracted from the data similarity matrix, the first of which clearly reveals the impact of agricultural practices and hydrogeological setting on the groundwater chemistry of the study area. Significant correlation exists between response variable NO3- and explanatory variables Ca 2+, Cl -, SO42-, depth to water, aquifer media and land use. Substituting Cl - by the EC results in the most accurate regression model for nitrate, when disregarding the four largest outliers (model A). When built solely on land use and hydrogeological setting, the regression model (model B) is less accurate but more interesting from a practical viewpoint, as it is based on easily obtainable data and can be used to predict nitrate concentrations in groundwater in other areas with similar conditions. This is particularly useful for conservative contaminants, where risk and vulnerability assessment methods, based on assumed rather than established correlations, generally produce erroneous results. Another purpose of the models can be to predict the future evolution of nitrate concentrations under influence of changes in land use or fertilization practices, which occur in compliance with policies such as the Nitrates Directive. Model B predicts a 40% decrease in nitrate concentrations in groundwater of the study area, when horticulture is replaced by other land use with much lower fertilization and irrigation rates.

Attenuation mechanisms of N-nitrosodimethylamine at an operating intercept and treat groundwater remediation system.

PubMed

Gunnison, D; Zappi, M E; Teeter, C; Pennington, J C; Bajpai, R

2000-04-03

The North Boundary Containment System (NBCS), an intercept-and-treat system, was established at Rocky Mountain Arsenal (RMA), Commerce City, CO, to remove low-level organic contaminants from a groundwater plume exiting RMA to the north and northwest. N-nitrosodimethylamine (NDMA) was detected in groundwater collected from the dewatering and recharge zones of the NBCS system. Concern over the fate of NDMA, in terms of potentially exiting the boundaries of the arsenal, prompted an investigation to evaluate potential attenuation mechanisms for NDMA within the alluvial aquifer system and within the NBCS itself. Groundwater, soil, and granular activated carbon (GAC) samples were taken from key locations in the NBCS system. Soil and GAC samples were assayed for sorption kinetics and for adsorption and desorption properties using 14C-labeled NDMA. NDMA biodegradation experiments were conducted by following 14CO(2) evolution from 14C-labeled NDMA in soils and GAC samples under aerobic and anaerobic conditions. The sorptive capacity of the site soils for NDMA was insignificant. Furthermore, the adsorption of the NDMA by the soil was almost completely reversible. Evaluation of the degradation potential of the native microbial consortia indicated a high level of NDMA mineralization when measured using bench-scale microcosms. The native consortia had capability to mineralize the NDMA under both aerobic and anaerobic incubations, indicating facultative characteristics. Testing of the local groundwater chemistry revealed that the area of the aquifer of interest was microaerobic and neutral in pH. These conditions were optimal for NDMA removal. While sorption was insignificant, degradation was a significant attenuation mechanism, which may be the reason that no NDMA has migrated off-site. This gives rise to the potential of a long-term sink for attenuating NDMA within the recharge zone of the treatment system.

Sorption and mineralization of S-metolachlor and its ionic metabolites in soils and vadose zone solids: consequences on groundwater quality in an alluvial aquifer (Ain Plain, France).

PubMed

Baran, Nicole; Gourcy, Laurence

2013-11-01

This study characterizes the transfer of S-metolachlor (SMOC) and its metabolites, metolachlor ethane sulfonic acid (MESA) and metolachlor oxanilic acid (MOXA) to the alluvial aquifer. Sorption and mineralization of SMOC and its two ionic metabolites were characterized for cultivated soils and solids from the vadose (unsaturated) zone in the Ain Plain (France). Under sterile soil conditions, the absence of mineralization confirms the importance of biotic processes in SMOC degradation. There is some adsorption and mineralization of the parent molecule and its metabolites in the unsaturated zone, though less than in soils. For soils, the MESA adsorption constant is statistically higher than that of MOXA and the sorption constants of the two metabolites are significantly lower than that of SMOC. After 246 days, for soils, maximums of 26% of the SMOC, 30% of the MESA and 38% of the MOXA were mineralized. This partly explains the presence of these metabolites in the groundwater at concentrations generally higher than those of the parent molecule for MESA, although there is no statistical difference in the mineralization of the 3 molecules. The laboratory results make it possible to explain the field observations made during 27 months of groundwater quality monitoring (monthly sampling frequency). The evolution of both metabolite concentrations in the groundwater is directly related to recharge dynamics; there is a positive correlation between concentrations and the groundwater level. The observed lag of several months between the signals of the parent molecule and those of the metabolites is probably due to greater sorption of the parent molecule than of its metabolites and/or to degradation kinetics. © 2013.

Modeling rock weathering in small watersheds

NASA Astrophysics Data System (ADS)

Pacheco, Fernando A. L.; Van der Weijden, Cornelis H.

2014-05-01

Many mountainous watersheds are conceived as aquifer media where multiple groundwater flow systems have developed (Tóth, 1963), and as bimodal landscapes where differential weathering of bare and soil-mantled rock has occurred (Wahrhaftig, 1965). The results of a weathering algorithm (Pacheco and Van der Weijden, 2012a, 2014), which integrates topographic, hydrologic, rock structure and chemical data to calculate weathering rates at the watershed scale, validated the conceptual models in the River Sordo basin, a small watershed located in the Marão cordillera (North of Portugal). The coupling of weathering, groundwater flow and landscape evolution analyses, as accomplished in this study, is innovative and represents a remarkable achievement towards regionalization of rock weathering at the watershed scale. The River Sordo basin occupies an area of approximately 51.2 km2 and was shaped on granite and metassediment terrains between the altitudes 185-1300 m. The groundwater flow system is composed of recharge areas located at elevations >700 m, identified on the basis of δ18O data. Discharge cells comprehend terminations of local, intermediate and regional flow systems, identified on the basis of spring density patterns, infiltration depth estimates based on 87Sr/86Sr data, and spatial distributions of groundwater pH and natural mineralization. Intermediate and regional flow systems, defined where infiltration depths >125 m, develop solely along the contact zone between granites and metassediments, because fractures in this region are profound and their density is very large. Weathering is accelerated where rocks are covered by thick soils, being five times faster relative to sectors of the basin where rocks are covered by thin soils. Differential weathering of bare and soil-mantled rock is also revealed by the spatial distribution of calculated aquifer hydraulic diffusivities and groundwater travel times.

Hydrochemical Impacts of CO2 Leakage on Fresh Groundwater: a Field Scale Experiment

NASA Astrophysics Data System (ADS)

Lions, J.; Gal, F.; Gombert, P.; Lafortune, S.; Darmoul, Y.; Prevot, F.; Grellier, S.; Squarcioni, P.

2013-12-01

One of the questions related to the emerging technology for Carbon Geological Storage concerns the risk of CO2 migration beyond the geological storage formation. In the event of leakage toward the surface, the CO2 might affect resources in neighbouring formations (geothermal or mineral resources, groundwater) or even represent a hazard for human activities at the surface or in the subsurface. In view of the preservation of the groundwater resources mainly for human consumption, this project studies the potential hydrogeochemical impacts of CO2 leakage on fresh groundwater quality. One of the objectives is to characterize the bio-geochemical mechanisms that may impair the quality of fresh groundwater resources in case of CO2 leakage. To reach the above mentioned objectives, this project proposes a field experiment to characterize in situ the mechanisms that could impact the water quality, the CO2-water-rock interactions and also to improve the monitoring methodology by controlled CO2 leakage in shallow aquifer. The tests were carried out in an experimental site in the chalk formation of the Paris Basin. The site is equipped with an appropriate instrumentation and was previously characterized (8 piezometers, 25 m deep and 4 piezairs 11 m deep). The injection test was preceded by 6 months of monitoring in order to characterize hydrodynamics and geochemical baselines of the site (groundwater, vadose and soil). Leakage into groundwater is simulated via the injection of a small quantity of food-grade CO2 (~20 kg dissolved in 10 m3 of water) in the injection well at a depth of about 20 m. A plume of dissolved CO2 is formed and moves downward according to the direction of groundwater flow and probably by degassing in part to the surface. During the injection test, hydrochemical monitoring of the aquifer is done in situ and by sampling. The parameters monitored in the groundwater are the piezometric head, temperature, pH and electrical conductivity. Analysis on water samples provide chemical elements (major, minor and trace metals), dissolved gases, microbiological diversity and isotopes (13C). The evolution of the composition of the groundwater in terms of major elements, trace elements and isotope signatures is interpreted in terms of geochemical mechanisms, and the water-rock-CO2 interactions are characterized. Modification of the chemical composition of water in the aquifer due to CO2 injection is assessed in term of groundwater quality i.e. metal element release and the possibility of exceeding references and quality of water for human consumption. One outcome of the CIPRES project will be to highlight mechanisms that can impact groundwater quality when a CO2 leakage occurs and to propose recommendations to prevent or/and eliminate negative effects and any risks to the environment and human health. This project is partially funded by the French Research Agency (ANR).

Resolving the relationships of Paleocene placental mammals.

PubMed

Halliday, Thomas J D; Upchurch, Paul; Goswami, Anjali

2017-02-01

The 'Age of Mammals' began in the Paleocene epoch, the 10 million year interval immediately following the Cretaceous-Palaeogene mass extinction. The apparently rapid shift in mammalian ecomorphs from small, largely insectivorous forms to many small-to-large-bodied, diverse taxa has driven a hypothesis that the end-Cretaceous heralded an adaptive radiation in placental mammal evolution. However, the affinities of most Paleocene mammals have remained unresolved, despite significant advances in understanding the relationships of the extant orders, hindering efforts to reconstruct robustly the origin and early evolution of placental mammals. Here we present the largest cladistic analysis of Paleocene placentals to date, from a data matrix including 177 taxa (130 of which are Palaeogene) and 680 morphological characters. We improve the resolution of the relationships of several enigmatic Paleocene clades, including families of 'condylarths'. Protungulatum is resolved as a stem eutherian, meaning that no crown-placental mammal unambiguously pre-dates the Cretaceous-Palaeogene boundary. Our results support an Atlantogenata-Boreoeutheria split at the root of crown Placentalia, the presence of phenacodontids as closest relatives of Perissodactyla, the validity of Euungulata, and the placement of Arctocyonidae close to Carnivora. Periptychidae and Pantodonta are resolved as sister taxa, Leptictida and Cimolestidae are found to be stem eutherians, and Hyopsodontidae is highly polyphyletic. The inclusion of Paleocene taxa in a placental phylogeny alters interpretations of relationships and key events in mammalian evolutionary history. Paleocene mammals are an essential source of data for understanding fully the biotic dynamics associated with the end-Cretaceous mass extinction. The relationships presented here mark a critical first step towards accurate reconstruction of this important interval in the evolution of the modern fauna. © 2015 The Authors. Biological Reviews published by John Wiley & Sons Ltd on behalf of Cambridge Philosophical Society.

New isotopic evidence for the origin of groundwater from the Nubian Sandstone Aquifer in the Negev, Israel

USGS Publications Warehouse

Vengosh, A.; Hening, S.; Ganor, J.; Mayer, B.; Weyhenmeyer, C.E.; Bullen, T.D.; Paytan, A.

2007-01-01

The geochemistry and isotopic composition (H, O, S, Osulfate, C, Sr) of groundwater from the Nubian Sandstone (Kurnub Group) aquifer in the Negev, Israel, were investigated in an attempt to reconstruct the origin of the water and solutes, evaluate modes of water-rock interactions, and determine mean residence times of the water. The results indicate multiple recharge events into the Nubian sandstone aquifer characterized by distinctive isotope signatures and deuterium excess values. In the northeastern Negev, groundwater was identified with deuterium excess values of ???16???, which suggests local recharge via unconfined areas of the aquifer in the Negev anticline systems. The ??18OH2O and ??2H values (-6.5??? and -35.4???) of this groundwater are higher than those of groundwater in the Sinai Peninsula and southern Arava valley (-7.5??? and -48.3???) that likewise have lower deuterium excess values of ???10???. Based on the geochemical differences between groundwater in the unconfined and confined zones of the aquifer, a conceptual geochemical model for the evolution of the groundwater in the Nubian sandstone aquifer has been reconstructed. The isotopic composition of shallow groundwater from the unconfined zone indicates that during recharge oxidation of pyrite to SO4 (??34SSO4 ???-13???; ??18OSO4 ???+7.7???) and dissolution of CaCO3 (87Sr/86Sr ???0.70787; ??13CDIC = -3.7???) occur. In the confined zone of the aquifer, bacterial SO4 reduction removes a significant part of dissolved SO42 -, thereby modifying its isotopic composition (??34SSO4 ???-2???; ??18OSO4 ???+8.5???) and liberating dissolved inorganic C that contains little or no radiocarbon (14C-free) with low ??13CDIC values (<-12???). In addition to local recharge, the Sr and S isotopic data revealed contribution of external groundwater sources to the Nubian Sandstone aquifer, resulting in further modifications of the groundwater chemical and isotopic signatures. In the northeastern Negev, it is shown that SO4-rich groundwater from the underlying Jurassic aquifer contributes significantly to the salt budget of the Nubian Sandstone aquifer. The unique chemical and isotopic composition of the Jurassic groundwater (??34SSO4 ??? +14???; ??18OSO4 ??? 14???; 87Sr/86Sr ???0.70764) is interpreted as reflecting dissolution of Late Triassic marine gypsum deposits. In the southern Arava Valley the authors postulate that SO4-rich groundwater with distinctively high Br/Cl (3 ?? 10-3) low 87Sr/86Sr (0.70734), and high ??34SSO4 values (+15???) is derived from mixing with underlying brines from the Paleozoic units. The radiocarbon measurements reveal low 14C activities (0.2-5.8 pmc) in both the northeastern Negev and southern Arava Valley. Taking into account dissolution of carbonate rocks and bacterial SO4 reduction in the unconfined area, estimated mean residence times of groundwater in the confined zone in the northeastern Negev are on the order of 21-38 ka, which suggests recharge predominantly during the last glacial period. The 14C signal in groundwater from the southern Arava Valley is equally low but due to evidence for mixing with external water sources the residence time estimates are questionable. ?? 2007 Elsevier Ltd. All rights reserved.

Estimates of residence time and related variations in quality of ground water beneath Submarine Base Bangor and vicinity, Kitsap County, Washington

USGS Publications Warehouse

Cox, S.E.

2003-01-01

Estimates of residence time of ground water beneath Submarine Base Bangor and vicinity ranged from less than 50 to 4,550 years before present, based on analysis of the environmental tracers tritium, chlorofluorocarbons (CFCs), and carbon-14 (14C), in 33 ground-water samples collected from wells tapping the ground-water system. The concentrations of multiple environmental tracers tritium, CFCs, and 14C were used to classify ground water as modern (recharged after 1953), pre-modern (recharged prior to 1953), or indeterminate. Estimates of the residence time of pre-modern ground water were based on evaluation of 14C of dissolved inorganic carbon present in ground water using geochemical mass-transfer modeling to account for the interactions of the carbon in ground water with carbon of the aquifer sediments. Ground-water samples were obtained from two extensive aquifers and from permeable interbeds within the thick confining unit separating the sampled aquifers. Estimates of ground-water residence time for all ground-water samples from the shallow aquifer were less than 45 years and were classified as modern. Estimates of the residence time of ground water in the permeable interbeds within the confining unit ranged from modern to 4,200 years and varied spatially. Near the recharge area, residence times in the permeable interbeds typically were less than 800 years, whereas near the discharge area residence times were in excess of several thousand years. In the deeper aquifers, estimates of ground-water residence times typically were several thousand years but ranged from modern to 4,550 years. These estimates of ground-water residence time based on 14C were often larger than estimates of ground-water residence time developed by particle-tracking analysis using a ground-water flow model. There were large uncertainties?on the order of 1,000-2,000 years?in the estimates based on 14C. Modern ground-water tracers found in some samples from large-capacity production wells screened in the deeper aquifer may be the result of preferential ground-water pathways or induced downward flow caused by pumping stress. Spatial variations in water quality were used to develop a conceptual model of chemical evolution of ground water. Stable isotope ratios of deuterium and oxygen-18 in the 33 ground-water samples were similar, indicating similar climatic conditions and source of precipitation recharge for all of the sampled ground water. Oxidation of organic matter and mineral dissolution increased the concentrations of dissolved inorganic carbon and common ions in downgradient ground waters. However, the largest concentrations were not found near areas of ground-water discharge, but at intermediate locations where organic carbon concentrations were greatest. Dissolved methane, derived from microbial methanogenesis, was present in some ground waters. Methanogenesis resulted in substantial alteration of the carbon isotopic composition of ground water. The NETPATH geochemical model code was used to model mass-transfers of carbon affecting the 14C estimate of ground-water residence time. Carbon sources in ground water include dispersed particulate organic matter present in the confining unit separating the two aquifers and methane present in some ground water. Carbonate minerals were not observed in the lithologic material of the ground-water system but may be present, because they have been found in the bedrock of stream drainages that contribute sediment to the study area.

[Spontaneous liver rupture in a patient with choledocholithiasis resolved by ERCP].

PubMed

Bahena-Aponte, Jesús A; Ramírez de Aguilar, Guillermo; Torres Carrillo, Juan Carlos; Espino Urbina, Luis; Sánchez González, Jesús A

2016-01-01

We present the case of a 34 years old female patient who presents with abdominal pain and elevated total and direct bilirrubins, so she underwent ERCP Reporting: a) successful sphincterotomy without complications, b) choledocholithias is endoscopically resolved, c) secondary cholangitis. She developed significant abdominal pain at 72 h, with hypovolemic shock and peritoneal irritation. She was taken to the surgery, finding a grade III liver laceration. This one was resolved with liver raffia and packing, during the same operative time cholecystectomy was performed. A second look was performed at 24 h, achieving adequate control of bleeding after placing hemostatic (Nexstat®). The patient developed a subdiaphragmatic abscess which needed drainage by another laparotomy. After which the patient had a satisfactory evolution, so she was discharged.

Hydrogeological behaviour of the Fuente-de-Piedra playa lake and tectonic origin of its basin (Malaga, southern Spain)

NASA Astrophysics Data System (ADS)

Rodriguez-Rodriguez, Miguel; Martos-Rosillo, Sergio; Pedrera, Antonio

2016-12-01

Changes in the quantity of groundwater input due to water extraction for irrigation and urban supply has modified the water balance in the Fuente de Piedra playa lake. We have analysed the hydrogeology of the playa-lake system and developed a water-level model by means of a simple long-term water balance and piezometric analysis. In addition, a tectonic model is proposed to explain the endorheic basin development that led to the formation of the playa. Upright folds developed since the late Miocene and density-driven subsidence favoured the setting-up of and endorheic system located between the Atlantic and the Mediterranean basins in the Quaternary. The underlying low permeability rocks beneath the playa form a very stable aquitard with highly saline groundwater that prevents groundwater recharge of the lake into the aquitard. The hydrological modelling allowed us to simulate the evolution of the wáter level under a scenario of unaltered conditions during a 13-year period, showing that the percentage of days with dry conditions varies from 24.8% of the time under altered conditions to 14.9% as far as an unaltered scenario is concerned.

Hybrid Multiscale Simulation of Hydrologic and Biogeochemical Processes in the River-Groundwater Interaction Zone

NASA Astrophysics Data System (ADS)

Yang, X.; Scheibe, T. D.; Chen, X.; Hammond, G. E.; Song, X.

2015-12-01

The zone in which river water and groundwater mix plays an important role in natural ecosystems as it regulates the mixing of nutrients that control biogeochemical transformations. Subsurface heterogeneity leads to local hotspots of microbial activity that are important to system function yet difficult to resolve computationally. To address this challenge, we are testing a hybrid multiscale approach that couples models at two distinct scales, based on field research at the U. S. Department of Energy's Hanford Site. The region of interest is a 400 x 400 x 20 m macroscale domain that intersects the aquifer and the river and contains a contaminant plume. However, biogeochemical activity is high in a thin zone (mud layer, <1 m thick) immediately adjacent to the river. This microscale domain is highly heterogeneous and requires fine spatial resolution to adequately represent the effects of local mixing on reactions. It is not computationally feasible to resolve the full macroscale domain at the fine resolution needed in the mud layer, and the reaction network needed in the mud layer is much more complex than that needed in the rest of the macroscale domain. Hence, a hybrid multiscale approach is used to efficiently and accurately predict flow and reactive transport at both scales. In our simulations, models at both scales are simulated using the PFLOTRAN code. Multiple microscale simulations in dynamically defined sub-domains (fine resolution, complex reaction network) are executed and coupled with a macroscale simulation over the entire domain (coarse resolution, simpler reaction network). The objectives of the research include: 1) comparing accuracy and computing cost of the hybrid multiscale simulation with a single-scale simulation; 2) identifying hot spots of microbial activity; and 3) defining macroscopic quantities such as fluxes, residence times and effective reaction rates.

Transport of Nitrogen and Phosphorus from Onsite Wastewater Treatment Systems to Shallow Groundwater

NASA Astrophysics Data System (ADS)

Toor, G.

2014-12-01

The knowledge about the nutrients transport from the vadose zone of onsite wastewater treatment systems (commonly called septic systems) is crucial to protect groundwater quality as 25% of US population uses septic systems to discharge household wastewater. For example, our preliminary data showed that about 47% of applied water was recovered at 60-cm below drainfield of septic systems. This implies that contaminants present in wastewater, if not attenuated in the vadose zone, can be transported to shallow groundwater. This presentation will focus on the biophysical and hydrologic controls on the transport of nitrogen (N) and phosphorus (P) from the vadose of two conventional (drip dispersal, gravel trench) and an advanced (with aerobic and anaerobic medias) system. These systems were constructed using two rows of drip pipe (37 emitters/mound) placed 0.3 m apart in the center of 6 m x 0.6 m drainfield. Each system received 120 L of wastewater per day. During 20-month period (May 2012 to December 2013), soil-water samples were collected from the vadose zone using suction cup lysimeters installed at 0.30, 0.60, and 1.05 m depth and groundwater samples were collected from piezometers installed at 3-3.30 m depth below the drainfield. A complimentary 1-year study using smaller drainfields (0.5 m long, 0.9 m wide, 0.9 m high) was conducted to obtain better insights in the vadose zone. A variety of instruments (multi-probe sensors, suction cup lysimeters, piezometers, tensiometers) were installed in the vadose zones. Results showed that nitrification controlled N evolution in drainfield and subsequent transport of N plumes (>10 mg/L) into groundwater. Most of the wastewater applied soluble inorganic P (>10 mg/L) was quickly attenuated in the drainfield due to fixation (sorption, precipitation) in the vadose zone (<0.10 mg/L), which was further reduced to <0.05 mg/L in groundwater. The hydrologic controls (primarily rainfall during June-September) facilitated transport of N, but not P, to shallow groundwater. The advanced system was extremely effective as it removed >95% N from wastewater, but was less effective at removing P. This presentation will conclude with importance of better septic system design and soil-based processes in reducing N and P transport to groundwater and protecting water quality in aquifers.

Effect of Monsoon on spatio-temporal variation of groundwater chemistry and stable isotopic signatures: insights for concomitant arsenic mobilization in West Bengal, India

NASA Astrophysics Data System (ADS)

Majumder, S.; Datta, S.; Nath, B.; Neidhardt, H.; Roman-Ross, G.; Berner, Z.; Hidalgo, M.; Chatterjee, D.; Sarkar, S.

2017-12-01

Large-scale groundwater abstraction was hypothesized to be one of the important factors controlling release and distribution of arsenic (As) in aquifers of Bengal Basin. In this study, we studied the groundwater/surface water geochemistry of two different geomorphic domains within the Chakdaha Block, West Bengal, to identify potential influences of groundwater withdrawal on the hydrochemical evolution of the aquifer. This has been done as a function of different water inputs (monsoon rain, irrigation and downward percolation from surface water impoundments) to the groundwater system and associated As mobilization. A low-land flood plain (with relatively more reducing aquifer) and a natural levee (less reducing aquifer) have been chosen for this purpose. The stable isotopic signatures of oxygen (δ18O) and hydrogen (δ2H) falls sub-parallel to the Global Meteoric Water Line (GMWL), with precipitation and subsequent evaporation seems to be the major controlling factor on the water isotopic composition. This shows a contribution of evaporation influenced water, derived from various surface water bodies, pointing at large-scale groundwater withdrawal helping drawdown of the evaporated surface water. In case of flood plain wells, the stable isotope composition and the Cl/Br molar ratio in local groundwater have revealed vertical recharge within the flood plain area to be the major recharge process, especially during the post-monsoon season. However, both evaporation and vertical mixing are visibly controlling the groundwater recharge in the natural levee area. A possible inflow of organic carbon to the aquifer during the monsoonal recharge process is noticeable, with an increase in dissolved organic carbon (DOC) concentration from 1.33 to 6.29 mg/L on passing from pre- to post-monsoon season. Concomitant increase in AsT, Fe(II) and HCO3- during the post monsoon season, being more pronounced in the flood plain samples, indicates a possible initial episode of reductive dissolution of As-rich Fe-oxihydroxides. The subsequent increase in As(III) (> 200%) proportions relative to the overall concentration of AsT (7%), may refer to anaerobic microbial degradation of DOC coupled with the reduction of As(V) to As(III) without triggering additional As release from the aquifer sediments.

Investigating Groundwater Depletion and Aquifer Degradation in Central Valley California from Space

NASA Astrophysics Data System (ADS)

Ojha, C.; Shirzaei, M.; Werth, S.; Argus, D. F.

2017-12-01

The Central Valley in California includes one of the world's largest and yet most stressed aquifer systems. The large demand for groundwater, accelerated by population growth and extreme droughts, has been depleting the region's groundwater resources for decades. However, the lack of dense monitoring networks and inaccurate information on geophysical aquifer response pose serious challenges to water management efforts in the area and put the groundwater at high risk. Here, we performed a joint analysis of large SAR interferometric data sets acquired by ALOS L-band satellite in conjunction with the groundwater level observations across the Central Valley. We used 420 L-band SAR images acquired on the ascending orbit track during period Dec 24, 2006 - Jan 1, 2010, and generated more than 1600 interferograms with a pixel size of 100 m × 100 m. We also use data from 1600 observational wells providing continuous measurements of groundwater level within the study period for our analysis. We find that in the south and near Tulare Lake, north of Tule and south of Kaweah basin in San Joaquin valley, the subsidence rate is greatest at up to 20-25 cm/yr, while in Sacramento Valley the subsidence rate is lower at 1-3 cm/yr. From the characterization of the elastic and inelastic storage coefficients, we find that Kern, Tule, Tulare, Kaweah and Merced basins in the San Joaquin Valley are more susceptible to permanent compaction and aquifer storage loss. Kern County shows 0.23%-1.8% of aquifer storage loss during the study period, and has higher percentage loss than adjacent basins such as Tule and Tulare Lake with 0.15%-1.2% and 0.2 %-1.5% loss, respectively. Overall, we estimate that the aquifers across the valley lost a total of 28 km3 of groundwater and 2% of their storage capacity during the study period. Our unique observational evidence including valley-wide estimate of mechanical properties of aquifers and model results will not only facilitate monitoring water deficits and estimating water storage variations, but is also useful to water managers, policy makers, and the communities living in water-stressed regions for development and management plans. Ongoing analysis using data from Envisat, Sentinel-1 and Radarasat-1 satellites will further play a key role is characterizing the evolution of groundwater resources.

Groundwater Dynamics in Fossil Fractured Carbonate Aquifers in Eastern Arabian Peninsula

NASA Astrophysics Data System (ADS)

Farag, A. Z. A.; Heggy, E.; Helal, M.; Thirunavukkarasu, D.; Scabbia, G.; Palmer, E. M.

2017-12-01

The Eastern Arabian Peninsula, notably the Qatar Peninsula, represents one of the highest natural groundwater discharge areas for the Arabian platform fossil aquifer system. Groundwater flow dynamics in these aquifers trace the paleoclimatic conditions that have prevailed the Arabian Peninsula during the Quaternary. In such settings, connections between aquifers strongly affect the flow dynamics, water quality and availability as well as karst formation and landscape evolution. Geological structures such as folds, faults and fractures are central to aquifer connectivity, yet their role on groundwater flow is poorly understood. Herein, we performed a detailed mapping of exposed and buried structural features in Qatar using Landsat, Sentinel and ALOS-PalSAR scenes, correlated with field and laboratory measurements to understand their role in aquifer connectivity and groundwater dynamics. Our results suggest that E-W oriented fold-related faults act as vertical conduits along which artesian upward leakages from the deep aquifers (e.g. Aruma and Umm er Radhuma) take place into the shallower aquifers (e.g. Rus and Dammam). Evidence includes: (1) the high potentiometric surfaces of deep aquifers (6 to 25 m amsl) compare to the shallower aquifers (2-3 m amsl for the same region); (2) anomalous elevation of groundwater levels and steeper hydraulic gradients in densely faulted regions; (3) mixed isotopic composition in shallow aquifers (δ18O: -5 to -2 ‰, δ2H: -40 to -10 ‰) between reported deep fossil waters (δ18O: -6.3 ‰, δ2H: -55 ‰) and modern meteoric waters (weighted average: δ18O: -0.6 ‰, δ2H: 4 ‰); (4) abundant meso-crystalline fibrous gypsum veins along fault zones in the Dammam Formation (up to 28 m amsl) in southern Qatar where the anhydritic member of the Rus Formation predominates the subsurface leading to gypsum oversaturation of groundwater. The similarity of crystal morphology (platy crystals under SEM), mineralogical compositions from XRD analysis and geologic setting suggest a common genesis from elevated groundwater along faults during wet climatic periods. The present study suggests that ascending gaseous-rich deep waters along faults in Qatar is degrading the water quality and causing dissolution of carbonates and evaporites leading to strong karstification with abundant collapse features.

Interaction of coastal urban groundwater with infrastructure due to tidal variation

NASA Astrophysics Data System (ADS)

Su, X.; Prigiobbe, V.

2017-12-01

The urbanization of coastal areas has been increasing during the last century. For these areas, groundwater is one of major source of potable water for the population, the industry, and the agriculture, with an average demand of 30 m3/s [1,2]. Simultaneously, the rate of sea-level rise has been recorded to be approximately 40 mm/yr [3], with potential negative consequences on the coastal groundwater. As the sea-level rises, sea-water intrusion into potable aquifers may become more important [4] and the water table of the shallow aquifer underneath the coastal areas may rise [5]. Therefore, the water quality of the aquifer decreases and interaction between the shallow aquifer and infrastructure may occur. In particular, in the latter case, disruptive events may become more frequent, such as infiltration of groundwater into damaged sewer causing discharge of untreated sewage (combined sewer overflows, CSOs). Here, a study is presented on the modeling of urban groundwater in coastal areas to identify the cause of frequent CSOs in dry weather conditions, i.e., CSOs are not expected to occur. The evolution of the water table was described in response of tidal variation to quantify the interaction between the shallow aquifer and an aging sewer. The watershed of the city of Hoboken (NJ), at the estuary of Hudson river, was implemented in MODFLOW. The model was built using dataset from various sources. Geostatistic was applied to create the aquifer geology and measurements of the water table from monitoring wells within the urban area were used as boundary conditions and model validation. Preliminary results of the simulations are shown the figure, where the water table over a period of 7 months was calculated. The groundwater model with the sewer will help identifying the parts of the network that might be submerged by the groundwater and, therefore, subjected to infiltration. Combining groundwater and sewer modeling with the hydrograph separation method [6], the model prediction of infiltration will be validated. References [1] Pimentel et al. BioScience, 54, 909-918, 2004. [2] Owolabi Glob. Ini., 11, 69-87, 2017. [3] Milne Astro. Geophys., 49, 224-228, 2008 [4] Vzquez-Su et al. Hydro. J. 13, 522-533, 2005. [5] Gburek et al. Ground Water, 37,175-184, 1999. [6] Prigiobbe and Giulianelli. Water Sci.Tech. 60, 727-735, 2009.

Structural Changes in PEO-PPO-PEO Gels Induced by Methylparaben and Dexamethasone Observed Using Time-Resolved SAXS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meznarich, Norman A.K.; Juggernauth, K Anne; Batzli, Kiersten M

2011-11-17

Aqueous solutions of polyoxyethylene-polyoxypropylene-polyoxyethylene (PEO-PPO-PEO) triblock copolymers (commercially available as Pluronic surfactants) micellize and structurally arrange into cubic quasicrystalline lattices as their temperature is raised. This structural evolution is seen macroscopically as a gelation, and the presence of these ordered phases can be controlled through both polymer concentration and temperature. The presence of added solutes within the dispersions can also affect the onset and kinetics of structure formation. Here we investigate the structures formed in Pluronic F127 solutions ranging from 20 to 30% with two pharmaceutical additives [methylparaben (MP) and dexamethasone (DX)] using small-angle X-ray scattering (SAXS). We observe bothmore » the progressive evolution and breakdown of these structures as the temperature is increased from 0 to 80 °C. Additionally, we conducted time-resolved SAXS measurements to elucidate the kinetics of the structural evolution. On the basis of the evolution of scattering peaks as the samples were being heated, we suggest that added MP changes the nucleation behavior of fcc phases within the sample from a heterogeneous process to a more homogeneous distribution of nucleated species. MP and DX also stabilize the micelle lattices, allowing them to persevere at higher temperatures. We observed the unusual result that the presence of DX caused the primary peaks of the structure factor to be suppressed, while preserving the higher order peaks. The primary peaks reappeared at the highest temperatures tested.« less

The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF)

DOE PAGES

Frenje, J. A.; Hilsabeck, T. J.; Wink, C. W.; ...

2016-08-02

The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (T i), yield (Y n), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate datamore » with a time resolution of ~20 ps and energy resolution of ~100 keV for total neutron yields above ~10 16. Lastly, at lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ~20 ps.« less

Time-resolved x-ray diffraction and electrical resistance measurements of structural phase transitions in zirconium

DOE PAGES

Velisavljevic, N.; Sinogeikin, S.; Saavedra, R.; ...

2014-05-07

Here, we have designed a portable pressure controller module to tune compression rates and maximum pressures attainable in a standard gas-membrane diamond anvil cell (DAC). During preliminary experiments, performed on zirconium (Zr) metal sample, pressure jumps of up to 80 GPa were systematically obtained in less than 0.2s (resulting in compression rate of few GPa/s up to more than 400 GPa/s). In-situ x-ray diffraction and electrical resistance measurements were performed simultaneously during this rapid pressure increase to provide the first time resolved data on α → ω → β structural evolution in Zr at high pressures. Direct control of compressionmore » rates and peak pressures, which can be held for prolonged time, allows for investigation of structural evolution and kinetics of structural phase transitions of materials under previously unexplored compression rate-pressure conditions that bridge traditional static and shock/dynamic experimental platforms.« less

The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF).

PubMed

Frenje, J A; Hilsabeck, T J; Wink, C W; Bell, P; Bionta, R; Cerjan, C; Gatu Johnson, M; Kilkenny, J D; Li, C K; Séguin, F H; Petrasso, R D

2016-11-01

The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (T i ), yield (Y n ), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate data with a time resolution of ∼20 ps and energy resolution of ∼100 keV for total neutron yields above ∼10 16 . At lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ∼20 ps.

Structural evolution of detonation carbon in composition B by X-ray scattering

NASA Astrophysics Data System (ADS)

Firestone, Millicent A.; Dattelbaum, Dana M.; Podlesak, David W.; Gustavsen, Richard L.; Huber, Rachel C.; Ringstrand, Bryan S.; Watkins, Erik B.; Jensen, Brian; Willey, Trevor; Lauderbauch, Lisa; Hodgin, Ralph; Bagge-Hansen, Michael; van Buuren, Tony; Seifert, Sönke; Graber, Timothy

2017-01-01

Products evolved during the detonation of high explosives are primarily a collection of molecular gases and solid carbon condensates. Electron microscopy studies have revealed that detonation carbon (soot) can contain a variety of unique carbon particles possessing novel morphologies, such as carbon onions and ribbons. Despite these observations very little is known about the conditions that leads to the production of these novel carbon nanoparticles. A fuller understanding on conditions that generate such nanoparticles would greatly benefit from time-resolved studies that probe particle formation and evolution through and beyond the chemical reaction zone. Herein, we report initial results employing time-resolved X-ray scattering (TRSAXS) measurements to monitor nanosecond time-scale carbon products formed from detonating Composition B (60% TNT, 40% RDX). These studies were performed at the Dynamic Compression Sector (DCS, Sector 35) at the Advanced Photon Source (Argonne National Laboratory). Analysis of the collected scattering patterns reveals the presence of fractal multi-layered carbon condensates.

Direct measurement of the thickness-dependent electronic band structure of MoS2 using angle-resolved photoemission spectroscopy.

PubMed

Jin, Wencan; Yeh, Po-Chun; Zaki, Nader; Zhang, Datong; Sadowski, Jerzy T; Al-Mahboob, Abdullah; van der Zande, Arend M; Chenet, Daniel A; Dadap, Jerry I; Herman, Irving P; Sutter, Peter; Hone, James; Osgood, Richard M

2013-09-06

We report on the evolution of the thickness-dependent electronic band structure of the two-dimensional layered-dichalcogenide molybdenum disulfide (MoS2). Micrometer-scale angle-resolved photoemission spectroscopy of mechanically exfoliated and chemical-vapor-deposition-grown crystals provides direct evidence for the shifting of the valence band maximum from Γ to K, for the case of MoS2 having more than one layer, to the case of single-layer MoS2, as predicted by density functional theory. This evolution of the electronic structure from bulk to few-layer to monolayer MoS2 had earlier been predicted to arise from quantum confinement. Furthermore, one of the consequences of this progression in the electronic structure is the dramatic increase in the hole effective mass, in going from bulk to monolayer MoS2 at its Brillouin zone center, which is known as the cause for the decreased carrier mobility of the monolayer form compared to that of bulk MoS2.

The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frenje, J. A., E-mail: jfrenje@psfc.mit.edu; Wink, C. W.; Gatu Johnson, M.

The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (T{sub i}), yield (Y{sub n}), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate datamore » with a time resolution of ∼20 ps and energy resolution of ∼100 keV for total neutron yields above ∼10{sup 16}. At lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ∼20 ps.« less

Phylogenetic ecology at world scale, a new fusion between ecology and evolution.

PubMed

Westoby, Mark

2006-07-01

One fusion between ecology and evolution is well established, under the title of population biology. The years 2006-2020 will see a new fusion, likely to prove equally creative. Inputs from ecology to this second fusion will be worldwide data sets for ecological traits across many species. Inputs from evolution will be phylogenetic trees with well-resolved topology and with increasingly tight geological dates for each branch point. There will be unification of two aims: first to explain the spread of different ways of making a living, across the range of present-day species; and second, to narrate the evolutionary history that has led up to present-day ecology.

Early animal evolution: emerging views from comparative biology and geology

NASA Technical Reports Server (NTRS)

Knoll, A. H.; Carroll, S. B.

1999-01-01

The Cambrian appearance of fossils representing diverse phyla has long inspired hypotheses about possible genetic or environmental catalysts of early animal evolution. Only recently, however, have data begun to emerge that can resolve the sequence of genetic and morphological innovations, environmental events, and ecological interactions that collectively shaped Cambrian evolution. Assembly of the modern genetic tool kit for development and the initial divergence of major animal clades occurred during the Proterozoic Eon. Crown group morphologies diversified in the Cambrian through changes in the genetic regulatory networks that organize animal ontogeny. Cambrian radiation may have been triggered by environmental perturbation near the Proterozoic-Cambrian boundary and subsequently amplified by ecological interactions within reorganized ecosystems.

Observation of Rayleigh-Taylor-instability evolution in a plasma with magnetic and viscous effects

DOE PAGES

Adams, Colin S.; Moser, Auna L.; Hsu, Scott C.

2015-11-06

We present time-resolved observations of Rayleigh-Taylor-instability (RTI) evolution at the interface between an unmagnetized plasma jet colliding with a stagnated, magnetized plasma. The observed instability growth time (~10μs) is consistent with the estimated linear RTI growth rate calculated using experimentally inferred values of density (~10 14cm–3) and deceleration (~10 9 m/s 2). The observed mode wavelength (≳1 cm) nearly doubles within a linear growth time. Furthermore, theoretical estimates of magnetic and viscous stabilization and idealized magnetohydrodynamic simulations including a physical viscosity model both suggest that the observed instability evolution is subject to magnetic and/or viscous effects.

Multiple recharge processes to heterogeneous Mediterranean coastal aquifers and implications on recharge rates evolution in time

NASA Astrophysics Data System (ADS)

Santoni, S.; Huneau, F.; Garel, E.; Celle-Jeanton, H.

2018-04-01

Climate change is nowadays widely considered to have major effects on groundwater resources. Climatic projections suggest a global increase in evaporation and higher frequency of strong rainfall events especially in Mediterranean context. Since evaporation is synonym of low recharge conditions whereas strong rainfall events are more favourable to recharge in heterogeneous subsurface contexts, a lack of knowledge remains then on the real ongoing and future drinking groundwater supply availability at aquifers scale. Due to low recharge potential and high inter-annual climate variability, this issue is strategic for the Mediterranean hydrosystems. This is especially the case for coastal aquifers because they are exposed to seawater intrusion, sea-level rise and overpumping risks. In this context, recharge processes and rates were investigated in a Mediterranean coastal aquifer with subsurface heterogeneity located in Southern Corsica (France). Aquifer recharge rates from combining ten physical and chemical methods were computed. In addition, hydrochemical and isotopic investigations were carried out through a monthly two years monitoring combining major ions and stable isotopes of water in rain, runoff and groundwater. Diffuse, focused, lateral mountain system and irrigation recharge processes were identified and characterized. A predominant focused recharge conditioned by subsurface heterogeneity is evidenced in agreement with variable but highly favourable recharge rates. The fast water transfer from the surface to the aquifer implied by this recharge process suggests less evaporation, which means higher groundwater renewal and availability in such Mediterranean coastal aquifers.

A new investigation on the water isotopes in the Badain Jaran Desert, China, for inferring water origination

NASA Astrophysics Data System (ADS)

Wu, X.; Wang, Y.; Wang, X. S.; Hu, B.

2017-12-01

Stable isotope δ2H, δ18O and d-excess values of water have previously been used to study the hydraulic connection of groundwater between the surrounding areas such as Heihe River Basin, Qilian Mountain and the Badain Jaran desert (BJD), China. We choose to focus on the effects of strong evaporation on the isotopic characteristics of water in the desert to better understand the origin of water in the BJD. A series of evaporation experiments were conducted in the desert to examine how it may change during evaporation and infiltration under local environmental conditions. Evaporation from open water was monitored in two experiments using local groundwater and lake water, respectively. And evaporation of soil water was observed in three pits which were excavated to different depths below a flat ground surface to install the evaporation-infiltration systems. Water samples were also collected from lakes, a spring and local unconfined aquifer for analyses of stable hydrogen and oxygen isotope ratios, and d-excess values in the BJD. The results show that water isotope contents became progressively enriched along an evaporation line, and the d-excess values decreased with the evaporation. The strong relationship of d-excess and δ18O values was observed from both the experiments and the water samples of groundwater and lakes, which is considered to be a signature of strong evaporation. Also, all the values of groundwater and lake water samples fall along with the evaporation line established through the evaporation experiments, indicating that lakes and groundwater in the study area have evolved from meteoric precipitation under modern or similar to modern climatic conditions. Analysis of a few previously published d-excess and δ18O values of groundwater from the BJD, Lake Eyre Basin, Australia, and Jabal Hafit mountain, United Arab Emirates reveals strong relationships between the two, suggesting similar recharge processes as observed in the BJD. This study demonstrated that the characteristic water isotopic patterns resulting from evaporation could be utilized to help resolve ambiguities in the interpretation of water isotope data in terms of recharge sources, especially, in the arid regions, such as the central Australia and the deserts of United Arab Emirates.

ARPES study of the evolution of band structure and charge density wave properties in RTe3 ( R=Y , La, Ce, Sm, Gd, Tb, and Dy)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hussain, Zahid; Brouet, Veronique; Yang, Wanli

2008-01-16

We present a detailed angle-resolved photoemission spectroscopy (ARPES) investigation of the RTe3 family, which sets this system as an ideal"textbook" example for the formation of a nesting driven charge density wave (CDW). This family indeed exhibits the full range of phenomena that can be associated to CDWinstabilities, from the opening of large gaps on the best nested parts of Fermi surface (up to 0.4 eV), to the existence of residual metallic pockets. ARPES is the best suited technique to characterize these features, thanks to its unique ability to resolve the electronic structure in k space. An additional advantage of RTe3more » is that theband structure can be very accurately described by a simple two dimensional tight-binding (TB) model, which allows one to understand and easily reproduce many characteristics of the CDW. In this paper, we first establish the main features of the electronic structure by comparing our ARPES measurements with the linear muffin-tinorbital band calculations. We use this to define the validity and limits of the TB model. We then present a complete description of the CDW properties and of their strong evolution as a function of R. Using simple models, we are able to reproduce perfectly the evolution of gaps in k space, the evolution of the CDW wave vector with R, and the shape of the residual metallic pockets. Finally, we give an estimation of the CDWinteraction parameters and find that the change in the electronic density of states n (EF), due to lattice expansion when different R ions are inserted, has the correct order of magnitude to explain the evolution of the CDW properties.« less

The role of the uncertainty in assessing future scenarios of water shortage in alluvial aquifers

NASA Astrophysics Data System (ADS)

Romano, Emanuele; Camici, Stefania; Brocca, Luca; Moramarco, Tommaso; Guyennon, Nicolas; Preziosi, Elisabetta

2015-04-01

There are many evidences that the combined effects of variations in precipitation and temperature due to climate change can result in a significant change of the recharge to groundwater at different time scales. A possible reduction of effective infiltration can result in a significant decrease, temporary or permanent, of the availability of the resource and, consequently, the sustainable pumping rate should be reassessed. In addition to this, one should also consider the so called indirect impacts of climate change, resulting from human intervention (e.g. augmentation of abstractions) which are feared to be even more important than the direct ones in the medium term: thus, a possible increase of episodes of shortage (i.e. the inability of the groundwater system to completely supply the water demand) can result both from change in the climate forcing and change in the demand. In order to assess future scenarios of water shortage a modelling chain is often used. It includes: 1) the use of General Circulation Models to estimate changes in temperature and precipitation; 2) downscaling procedures to match modeling scenarios to the observed meteorological time series; 3) soil-atmosphere modelling to estimate the time variation of the recharge to the aquifer; 4) groundwater flow models to simulate the water budget and piezometric head evolution; 5) future scenarios of groundwater quantitative status that include scenarios of demand variation. It is well known that each of these processing steps is affected by an intrinsic uncertainty that propagates through the whole chain leading to a final uncertainty on the piezometric head scenarios. The estimate of such an uncertainty is a key point for a correct management of groundwater resources, in case of water shortage due to prolonged droughts as well as for planning purposes. This study analyzes the uncertainty of the processing chain from GCM scenarios to its impact on an alluvial aquifer in terms of exploitation sustainability. To this goal, three GCMs (ECHAM5, PCM and CCSM3) and two downscaling methods (Linear Rescaling and Quantile Mapping) are used to generate future scenarios of precipitation and temperature; the Thornthwaite-Mather soil water balance model is used to estimate the recharge to the aquifer; the evolution in time of the piezometric heads is estimated through a numerical model developed using the MODFLOW2005 code. Finally, different scenarios of water demand are applied. Final results show that the uncertainty due to the groundwater flow model calibration/validation in steady-state conditions is comparable to that arising from the whole processing chain from the GCM choice to the effective infiltration estimates. Simulations in transient conditions show the high impact of the uncertainty related to the calibration of the storage coefficient, that significantly drives the resilience of the system, thus the ability of the aquifer to sustain the demand during the periods of prolonged drought.

Concentration-Discharge Relations in the Critical Zone: Implications for Resolving Critical Zone Structure, Function, and Evolution

NASA Astrophysics Data System (ADS)

Chorover, Jon; Derry, Louis A.; McDowell, William H.

2017-11-01

Critical zone science seeks to develop mechanistic theories that describe critical zone structure, function, and long-term evolution. One postulate is that hydrogeochemical controls on critical zone evolution can be inferred from solute discharges measured down-gradient of reactive flow paths. These flow paths have variable lengths, interfacial compositions, and residence times, and their mixing is reflected in concentration-discharge (C-Q) relations. Motivation for this special section originates from a U.S. Critical Zone Observatories workshop that was held at the University of New Hampshire, 20-22 July 2015. The workshop focused on resolving mechanistic CZ controls over surface water chemical dynamics across the full range of lithogenic (e.g., nonhydrolyzing and hydrolyzing cations and oxyanions) and bioactive solutes (e.g., organic and inorganic forms of C, N, P, and S), including dissolved and colloidal species that may cooccur for a given element. Papers submitted to this special section on "concentration-discharge relations in the critical zone" include those from authors who attended the workshop, as well as others who responded to the open solicitation. Submissions were invited that utilized information pertaining to internal, integrated catchment function (relations between hydrology, biogeochemistry, and landscape structure) to help illuminate controls on observed C-Q relations.

Layer-by-Layer Evolution of a Two-Dimensional Electron Gas Near an Oxide Interface

NASA Astrophysics Data System (ADS)

Chang, Young Jun; Moreschini, Luca; Bostwick, Aaron; Gaines, Geoffrey A.; Kim, Yong Su; Walter, Andrew L.; Freelon, Byron; Tebano, Antonello; Horn, Karsten; Rotenberg, Eli

2013-09-01

We report the momentum-resolved measurement of a two-dimensional electron gas at the LaTiO3/SrTiO3 interface by angle-resolved photoemission spectroscopy (ARPES). Thanks to an advanced sample preparation technique, the orbital character of the conduction electrons and the electronic correlations can be accessed quantitatively as each unit cell layer is added. We find that all of these quantities change dramatically with distance from the interface. These findings open the way to analogous studies on other heterostructures, which are traditionally a forbidden field for ARPES.

Dissolution-induced preferential flow in a limestone fracture.

PubMed

Liu, Jishan; Polak, Amir; Elsworth, Derek; Grader, Avrami

2005-06-01

Flow in a rock fracture is surprisingly sensitive to the evolution of flow paths that develop as a result of dissolution. Net dissolution may either increase or decrease permeability uniformly within the fracture, or may form a preferential flow path through which most of the injected fluid flows, depending on the prevailing ambient mechanical and chemical conditions. A flow-through test was completed on an artificial fracture in limestone at room temperature under ambient confining stress of 3.5 MPa. The sample was sequentially circulated by water of two different compositions through the 1500 h duration of the experiment; the first 935 h by tap groundwater, followed by 555 h of distilled water. Measurements of differential pressures between the inlet and the outlet, fluid and dissolved mass fluxes, and concurrent X-ray CT imaging and sectioning were used to characterize the evolution of flow paths within the limestone fracture. During the initial circulation of groundwater, the differential pressure increased almost threefold, and was interpreted as a net reduction in permeability as the contacting asperities across the fracture are removed, and the fracture closes. With the circulation of distilled water, permeability initially reduces threefold, and ultimately increases by two orders of magnitude. This spontaneous switch from net decrease in permeability, to net increase occurred with no change in flow rate or applied effective stress, and is attributed to the evolving localization of flow path as evidenced by CT images. Based on the X-ray CT characterizations, a flow path-dependent flow model was developed to simulate the evolution of flow paths within the fracture and its influence on the overall flow behaviors of the injected fluid in the fracture.

Tampa Bay as a model estuary for examining the impact of human activities on biogeochemical processes: an introduction

USGS Publications Warehouse

Swarzenski, Peter W.; Baskaran, Mark; Henderson, Carl S.; Yates, Kim

2007-01-01

Tampa Bay is a shallow, Y-shaped coastal embayment that is located along the center of the Florida Platform – an expansive accumulation of Cretaceous–Tertiary shallow-water carbonates and evaporites that were periodically exposed during glacio–eustatic sea level fluctuations. As a consequence, extensive karstification likely had a controlling impact on the geologic evolution of Tampa Bay. Despite its large aerial size (∼ 1000 km2), Tampa Bay is relatively shallow (mean depth = 4 m) and its watershed (6700 km2) is among the smallest in the Gulf of Mexico. About 85% of all freshwater inflow (mean = 63 m3 s-1) to the bay is carried by four principal tributaries (Orlando et al., 1993). Groundwater makes up an important component of baseflow of these coastal streams and may also be important in delivering nutrients and other constituents to the bay proper by submarine groundwater discharge.

An ecologic study of peat landforms in Canada and Alaska

NASA Technical Reports Server (NTRS)

Glaser, P. H.

1986-01-01

The role of groundwater and surface runoff in controlling the water chemistry and development of peat landforms in northern Minnesota are described. The LANDSAT imagery taken duing spring break-up are particularly valuable in identifying potential zones of groundwater discharge. The vascular floras of raised bogs in eastern North Americas demonstrating the remarkabe uniformity of the ombrotrophic flora over broad geographic regions are described. The evolution of peat landforms in the major boreal peatlands of eastern America is examined. The LANDSAT imagery is used to determine the area of patterned to featureless peatlands, the area of ombrotrophic bog relative to minerotrophic fen, and the relative size and degree of streamlining of island landforms entirely composed of peat. Such measurements can be used to assess the role of climate, time, and hydrology in controlling the formation of peatland patterns across broad geographic regions.

Hydrochemistry and groundwater system of the Zerka Ma'in-Zara thermal field, Jordan

NASA Astrophysics Data System (ADS)

Rimawi, Omar; Salameh, Elias

1988-03-01

A groundwater flow model through the different geological successions from the Upper Cretaceous through the Lower Cretaceous Sandstone and older units is presented in this paper. The model is supported by the hydrochemical evolution of water types from the recharge areas in the highlands to discharge sites of thermal water at the slopes overlooking the Dead Sea. The thermal water discharged in the Zerka Ma'in-Zara areas consists of three end members mixed in different ratios with a component of old (many thousands of years) thermal water undersaturated in carbonate minerals and containing hundreds of milligrams per liter of free CO 2. The release of CO 2 gas upon discharge renders the water oversaturated with respect to carbonate minerals which results in aragonite precipitation. The elevated temperature of the water in the reservoir (73-82°C) is attributed to the presence of a heat-storing layer topping the aquifer.

Formation of Box Canyon, Idaho, by megaflood: implications for seepage erosion on Earth and Mars.

PubMed

Lamb, Michael P; Dietrich, William E; Aciego, Sarah M; Depaolo, Donald J; Manga, Michael

2008-05-23

Amphitheater-headed canyons have been used as diagnostic indicators of erosion by groundwater seepage, which has important implications for landscape evolution on Earth and astrobiology on Mars. Of perhaps any canyon studied, Box Canyon, Idaho, most strongly meets the proposed morphologic criteria for groundwater sapping because it is incised into a basaltic plain with no drainage network upstream, and approximately 10 cubic meters per second of seepage emanates from its vertical headwall. However, sediment transport constraints, 4He and 14C dates, plunge pools, and scoured rock indicate that a megaflood (greater than 220 cubic meters per second) carved the canyon about 45,000 years ago. These results add to a growing recognition of Quaternary catastrophic flooding in the American northwest, and may imply that similar features on Mars also formed by floods rather than seepage erosion.

Arsenic Contaminated Groundwater and Its Treatment Options in Bangladesh

PubMed Central

Jiang, Jia-Qian; Ashekuzzaman, S. M.; Jiang, Anlun; Sharifuzzaman, S. M.; Chowdhury, Sayedur Rahman

2012-01-01

Arsenic (As) causes health concerns due to its significant toxicity and worldwide presence in drinking water and groundwater. The major sources of As pollution may be natural process such as dissolution of As-containing minerals and anthropogenic activities such as percolation of water from mines, etc. The maximum contaminant level for total As in potable water has been established as 10 µg/L. Among the countries facing As contamination problems, Bangladesh is the most affected. Up to 77 million people in Bangladesh have been exposed to toxic levels of arsenic from drinking water. Therefore, it has become an urgent need to provide As-free drinking water in rural households throughout Bangladesh. This paper provides a comprehensive overview on the recent data on arsenic contamination status, its sources and reasons of mobilization and the exposure pathways in Bangladesh. Very little literature has focused on the removal of As from groundwaters in developing countries and thus this paper aims to review the As removal technologies and be a useful resource for researchers or policy makers to help identify and investigate useful treatment options. While a number of technological developments in arsenic removal have taken place, we must consider variations in sources and quality characteristics of As polluted water and differences in the socio-economic and literacy conditions of people, and then aim at improving effectiveness in arsenic removal, reducing the cost of the system, making the technology user friendly, overcoming maintenance problems and resolving sludge management issues. PMID:23343979

Arsenic contaminated groundwater and its treatment options in Bangladesh.

PubMed

Jiang, Jia-Qian; Ashekuzzaman, S M; Jiang, Anlun; Sharifuzzaman, S M; Chowdhury, Sayedur Rahman

2012-12-20

Arsenic (As) causes health concerns due to its significant toxicity and worldwide presence in drinking water and groundwater. The major sources of As pollution may be natural process such as dissolution of As-containing minerals and anthropogenic activities such as percolation of water from mines, etc. The maximum contaminant level for total As in potable water has been established as 10 µg/L. Among the countries facing As contamination problems, Bangladesh is the most affected. Up to 77 million people in Bangladesh have been exposed to toxic levels of arsenic from drinking water. Therefore, it has become an urgent need to provide As-free drinking water in rural households throughout Bangladesh. This paper provides a comprehensive overview on the recent data on arsenic contamination status, its sources and reasons of mobilization and the exposure pathways in Bangladesh. Very little literature has focused on the removal of As from groundwaters in developing countries and thus this paper aims to review the As removal technologies and be a useful resource for researchers or policy makers to help identify and investigate useful treatment options. While a number of technological developments in arsenic removal have taken place, we must consider variations in sources and quality characteristics of As polluted water and differences in the socio-economic and literacy conditions of people, and then aim at improving effectiveness in arsenic removal, reducing the cost of the system, making the technology user friendly, overcoming maintenance problems and resolving sludge management issues.

Efficient geostatistical inversion of transient groundwater flow using preconditioned nonlinear conjugate gradients

NASA Astrophysics Data System (ADS)

Klein, Ole; Cirpka, Olaf A.; Bastian, Peter; Ippisch, Olaf

2017-04-01

In the geostatistical inverse problem of subsurface hydrology, continuous hydraulic parameter fields, in most cases hydraulic conductivity, are estimated from measurements of dependent variables, such as hydraulic heads, under the assumption that the parameter fields are autocorrelated random space functions. Upon discretization, the continuous fields become large parameter vectors with O (104 -107) elements. While cokriging-like inversion methods have been shown to be efficient for highly resolved parameter fields when the number of measurements is small, they require the calculation of the sensitivity of each measurement with respect to all parameters, which may become prohibitive with large sets of measured data such as those arising from transient groundwater flow. We present a Preconditioned Conjugate Gradient method for the geostatistical inverse problem, in which a single adjoint equation needs to be solved to obtain the gradient of the objective function. Using the autocovariance matrix of the parameters as preconditioning matrix, expensive multiplications with its inverse can be avoided, and the number of iterations is significantly reduced. We use a randomized spectral decomposition of the posterior covariance matrix of the parameters to perform a linearized uncertainty quantification of the parameter estimate. The feasibility of the method is tested by virtual examples of head observations in steady-state and transient groundwater flow. These synthetic tests demonstrate that transient data can reduce both parameter uncertainty and time spent conducting experiments, while the presented methods are able to handle the resulting large number of measurements.

Time-resolved transillumination and optical tomography

NASA Astrophysics Data System (ADS)

de Haller, Emmanuel B.

1996-01-01

In response to an invitation by the editor-in-chief, I would like to present the current status of time-domain imaging. With exciting new photon diffusion techniques being developed in the frequency domain and promising optical coherence tomography, time-resolved transillumination is in constant evolution and the subject of passionate discussions during the numerous conferences dedicated to this subject. The purpose of time-resolved optical tomography is to provide noninvasive, high-resolution imaging of the interior of living bodies by the use of nonionizing radiation. Moreover, the use of visible to near-infrared wavelength yields metabolic information. Breast cancer screening is the primary potential application for time-resolved imaging. Neurology and tissue characterization are also possible fields of applications. Time- resolved transillumination and optical tomography should not only improve diagnoses, but the welfare of the patient. As no overview of this technique has yet been presented to my knowledge, this paper briefly describes the various methods enabling time-resolved transillumination and optical tomography. The advantages and disadvantages of these methods, as well as the clinical challenges they face are discussed. Although an analytic and computable model of light transport through tissues is essential for a meaningful interpretation of the transillumination process, this paper will not dwell on the mathematics of photon propagation.

Reconstructing human evolution: Achievements, challenges, and opportunities

PubMed Central

Wood, Bernard

2010-01-01

This contribution reviews the evidence that has resolved the branching structure of the higher primate part of the tree of life and the substantial body of fossil evidence for human evolution. It considers some of the problems faced by those who try to interpret the taxonomy and systematics of the human fossil record. How do you to tell an early human taxon from one in a closely related clade? How do you determine the number of taxa represented in the human clade? How can homoplasy be recognized and factored into attempts to recover phylogeny? PMID:20445105

Infrared circumstellar shells - Origins, and clues to the evolution of massive stars

NASA Technical Reports Server (NTRS)

Stencel, Robert E.; Pesce, Joseph E.; Bauer, Wendy Hagen

1989-01-01

The infrared fluxes, spatial and spectral characteristics for a sample of 111 supergiant stars of spectral types F0 through M5 are tabulated, and correlations examined with respect to the nature of their circumstellar envelopes. One-fourth of these objects were spatialy resolved by IRAS at 60 microns and possess extended circumstellar shell material, with implied expansion ages of about 10 to the 5th yr. Inferences about the production of dust, mass loss, and the relation of these characteristics of the evolution of massive stars, are discussed.

Preliminary investigation of the effects of sea-level rise on groundwater levels in New Haven, Connecticut

USGS Publications Warehouse

Bjerklie, David M.; Mullaney, John R.; Stone, Janet R.; Skinner, Brian J.; Ramlow, Matthew A.

2012-01-01

Global sea level rose about 0.56 feet (ft) (170 millimeters (mm)) during the 20th century. Since the 1960s, sea level has risen at Bridgeport, Connecticut, about 0.38 ft (115 mm), at a rate of 0.008 ft (2.56 mm + or - 0.58 mm) per year. With regional subsidence, and with predicted global climate change, sea level is expected to continue to rise along the northeast coast of the United States through the 21st century. Increasing sea levels will cause groundwater levels in coastal areas to rise in order to adjust to the new conditions. Some regional climate models predict wetter climate in the northeastern United States under some scenarios. Scenarios for the resulting higher groundwater levels have the potential to inundate underground infrastructure in lowlying coastal cities. New Haven is a coastal city in Connecticut surrounded and bisected by tidally affected waters. Monitoring of water levels in wells in New Haven from August 2009 to July 2010 indicates the complex effects of urban influence on groundwater levels. The response of groundwater levels to recharge and season varied considerably from well to well. Groundwater temperatures varied seasonally, but were warmer than what was typical for Connecticut, and they seem to reflect the influence of the urban setting, including the effects of conduits for underground utilities. Specific conductance was elevated in many of the wells, indicating the influence of urban activities or seawater in Long Island Sound. A preliminary steady-state model of groundwater flow for part of New Haven was constructed using MODFLOW to simulate current groundwater levels (2009-2010) and future groundwater levels based on scenarios with a rise of 3 ft (0.91 meters (m)) in sea level, which is predicted for the end of the 21st century. An additional simulation was run assuming a 3-ft rise in sea level combined with a 12-percent increase in groundwater recharge. The model was constructed from existing hydrogeologic information for the New Haven area and from new information on groundwater levels collected during October 2009-June 2010. For the scenario with a 3-ft rise in sea level and no increase in recharge, simulated groundwater levels near the coast rose 3 ft; this increased water level tapered off toward a discharge area at the only nontidal stream in the study area. Simulated stream discharge increased at the nontidal stream because of the increased gradient. Although groundwater levels rose, the simulated difference between the groundwater levels in the aquifer and the increased sea level declined, indicating that the depth to the interface between freshwater and saltwater may possibly decline. Simulated water levels were affected by rise in sea level even in areas where the water table was at 17-24 ft (5.2-7.3 m) above current (2011) sea level. For the scenario with increased recharge, simulated groundwater levels were as much as an additional foot higher at some locations in the study area. The results of this preliminary investigation indicate that groundwater levels in coastal areas can be expected to rise and may rise higher if groundwater recharge also increases. This finding has implications for the disposal of stormwater through infiltration, a low-impact development practice designed to improve water quality and reduce overland peak discharge. Other implications include increased risk of basement flooding and increased groundwater seepage into underground sewer pipes and utility corridors in some areas. These implications will present engineering challenges to New Haven and Yale University. The preliminary model developed for this study can be the starting point for further simulation of future alternative scenarios for sea-level rise and recharge. Further simulations could identify those areas of New Haven where infrastructure may be at greatest risk from rising levels of groundwater. The simulations described in this report have limitations due to the preliminary scope of the work. Approaches to improve simulations include but are not limited to incorporating: * The variable density of seawater into the model in order to understand the current and future location of the interface between freshwater and saltwater; * Collection of additional data in order to better resolve temporal and spatial patterns in water levels in the aquifer; * Improved estimates of recharge through direct and indirect measurements of freshwater discharge from the study area; and * Transient simulations for greater understanding of the amount of time required for water levels and the position of the interface between freshwater and saltwater to adjust to changes in sea level and recharge.

Phase Reconstruction from FROG Using Genetic Algorithms[Frequency-Resolved Optical Gating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Omenetto, F.G.; Nicholson, J.W.; Funk, D.J.

1999-04-12

The authors describe a new technique for obtaining the phase and electric field from FROG measurements using genetic algorithms. Frequency-Resolved Optical Gating (FROG) has gained prominence as a technique for characterizing ultrashort pulses. FROG consists of a spectrally resolved autocorrelation of the pulse to be measured. Typically a combination of iterative algorithms is used, applying constraints from experimental data, and alternating between the time and frequency domain, in order to retrieve an optical pulse. The authors have developed a new approach to retrieving the intensity and phase from FROG data using a genetic algorithm (GA). A GA is a generalmore » parallel search technique that operates on a population of potential solutions simultaneously. Operators in a genetic algorithm, such as crossover, selection, and mutation are based on ideas taken from evolution.« less

Time-resolved resonance fluorescence spectroscopy for study of chemical reactions in laser-induced plasmas.

PubMed

Liu, Lei; Deng, Leimin; Fan, Lisha; Huang, Xi; Lu, Yao; Shen, Xiaokang; Jiang, Lan; Silvain, Jean-François; Lu, Yongfeng

2017-10-30

Identification of chemical intermediates and study of chemical reaction pathways and mechanisms in laser-induced plasmas are important for laser-ablated applications. Laser-induced breakdown spectroscopy (LIBS), as a promising spectroscopic technique, is efficient for elemental analyses but can only provide limited information about chemical products in laser-induced plasmas. In this work, time-resolved resonance fluorescence spectroscopy was studied as a promising tool for the study of chemical reactions in laser-induced plasmas. Resonance fluorescence excitation of diatomic aluminum monoxide (AlO) and triatomic dialuminum monoxide (Al 2 O) was used to identify these chemical intermediates. Time-resolved fluorescence spectra of AlO and Al 2 O were used to observe the temporal evolution in laser-induced Al plasmas and to study their formation in the Al-O 2 chemistry in air.

The point-spread function measure of resolution for the 3-D electrical resistivity experiment

NASA Astrophysics Data System (ADS)

Oldenborger, Greg A.; Routh, Partha S.

2009-02-01

The solution appraisal component of the inverse problem involves investigation of the relationship between our estimated model and the actual model. However, full appraisal is difficult for large 3-D problems such as electrical resistivity tomography (ERT). We tackle the appraisal problem for 3-D ERT via the point-spread functions (PSFs) of the linearized resolution matrix. The PSFs represent the impulse response of the inverse solution and quantify our parameter-specific resolving capability. We implement an iterative least-squares solution of the PSF for the ERT experiment, using on-the-fly calculation of the sensitivity via an adjoint integral equation with stored Green's functions and subgrid reduction. For a synthetic example, analysis of individual PSFs demonstrates the truly 3-D character of the resolution. The PSFs for the ERT experiment are Gaussian-like in shape, with directional asymmetry and significant off-diagonal features. Computation of attributes representative of the blurring and localization of the PSF reveal significant spatial dependence of the resolution with some correlation to the electrode infrastructure. Application to a time-lapse ground-water monitoring experiment demonstrates the utility of the PSF for assessing feature discrimination, predicting artefacts and identifying model dependence of resolution. For a judicious selection of model parameters, we analyse the PSFs and their attributes to quantify the case-specific localized resolving capability and its variability over regions of interest. We observe approximate interborehole resolving capability of less than 1-1.5m in the vertical direction and less than 1-2.5m in the horizontal direction. Resolving capability deteriorates significantly outside the electrode infrastructure.

Adaptive multiresolution modeling of groundwater flow in heterogeneous porous media

NASA Astrophysics Data System (ADS)

Malenica, Luka; Gotovac, Hrvoje; Srzic, Veljko; Andric, Ivo

2016-04-01

Proposed methodology was originally developed by our scientific team in Split who designed multiresolution approach for analyzing flow and transport processes in highly heterogeneous porous media. The main properties of the adaptive Fup multi-resolution approach are: 1) computational capabilities of Fup basis functions with compact support capable to resolve all spatial and temporal scales, 2) multi-resolution presentation of heterogeneity as well as all other input and output variables, 3) accurate, adaptive and efficient strategy and 4) semi-analytical properties which increase our understanding of usually complex flow and transport processes in porous media. The main computational idea behind this approach is to separately find the minimum number of basis functions and resolution levels necessary to describe each flow and transport variable with the desired accuracy on a particular adaptive grid. Therefore, each variable is separately analyzed, and the adaptive and multi-scale nature of the methodology enables not only computational efficiency and accuracy, but it also describes subsurface processes closely related to their understood physical interpretation. The methodology inherently supports a mesh-free procedure, avoiding the classical numerical integration, and yields continuous velocity and flux fields, which is vitally important for flow and transport simulations. In this paper, we will show recent improvements within the proposed methodology. Since "state of the art" multiresolution approach usually uses method of lines and only spatial adaptive procedure, temporal approximation was rarely considered as a multiscale. Therefore, novel adaptive implicit Fup integration scheme is developed, resolving all time scales within each global time step. It means that algorithm uses smaller time steps only in lines where solution changes are intensive. Application of Fup basis functions enables continuous time approximation, simple interpolation calculations across different temporal lines and local time stepping control. Critical aspect of time integration accuracy is construction of spatial stencil due to accurate calculation of spatial derivatives. Since common approach applied for wavelets and splines uses a finite difference operator, we developed here collocation one including solution values and differential operator. In this way, new improved algorithm is adaptive in space and time enabling accurate solution for groundwater flow problems, especially in highly heterogeneous porous media with large lnK variances and different correlation length scales. In addition, differences between collocation and finite volume approaches are discussed. Finally, results show application of methodology to the groundwater flow problems in highly heterogeneous confined and unconfined aquifers.

A plastid phylogeny and character evolution of the Old World fern genus Pyrrosia (Polypodiaceae) with the description of a new genus: Hovenkampia (Polypodiaceae).

PubMed

Zhou, Xin-Mao; Zhang, Liang; Chen, Cheng-Wei; Li, Chun-Xiang; Huang, Yao-Moan; Chen, De-Kui; Lu, Ngan Thi; Cicuzza, Daniele; Knapp, Ralf; Luong, Thien Tam; Nitta, Joel H; Gao, Xin-Fen; Zhang, Li-Bing

2017-09-01

The Old World fern genus Pyrrosia (Polypodiaceae) offers a rare system in ferns to study morphological evolution because almost all species of this genus are well studied for their morphology, anatomy, and spore features, and various hypotheses have been proposed in terms of the phylogeny and evolution in this genus. However, the molecular phylogeny of the genus lags behind. The monophyly of the genus has been uncertain and a modern phylogenetic study of the genus based on molecular data has been lacking. In the present study, DNA sequences of five plastid markers of 220 accessions of Polypodiaceae representing two species of Drymoglossum, 14 species of Platycerium, 50 species of Pyrrosia, and the only species of Saxiglossum (subfamily Platycerioideae), and 12 species of other Polypodiaceae representing the remaining four subfamilies are used to infer a phylogeny of the genus. Major results and conclusions of this study include: (1) Pyrrosia as currently circumscribed is paraphyletic in relation to Platycerium and can be divided into two genera: Pyrrosia s.s. and Hovenkampia (gen. nov.), with Hovenkampia and Platycerium forming a strongly supported clade sister to Pyrrosia s.s.; (2) Subfamily Platycerioideae should contain three genera only, Hovenkampia, Platycerium, and Pyrrosia s.s.; (3) Based on the molecular phylogeny, macromorphology, anatomical features, and spore morphology, four major clades in the genus are identified and three of the four are further resolved into four, four, and six subclades, respectively; (4) Three species, P. angustissima, P. foveolata, and P. mannii, not assigned to any groups by Hovenkamp (1986) because of their unusual morphology, each form monospecific clades; (5) Drymoglossum is not monophyletic and those species previously assigned to this genus are resolved in two different subclades; (6) Saxiglossum is resolved as the first lineage in the Niphopsis clade; and (7) The evolution of ten major morphological characters in the subfamily is inferred based on the phylogeny and various morphological synapomorphies for various clades and subclades are identified. Copyright © 2017 Elsevier Inc. All rights reserved.

Towards high-resolution mantle convection simulations

NASA Astrophysics Data System (ADS)

Höink, T.; Richards, M. A.; Lenardic, A.

2009-12-01

The motion of tectonic plates at the Earth’s surface, earthquakes, most forms of volcanism, the growth and evolution of continents, and the volatile fluxes that govern the composition and evolution of the oceans and atmosphere are all controlled by the process of solid-state thermal convection in the Earth’s rocky mantle, with perhaps a minor contribution from convection in the iron core. Similar processes govern the evolution of other planetary objects such as Mars, Venus, Titan, and Europa, all of which might conceivably shed light on the origin and evolution of life on Earth. Modeling and understanding this complicated dynamical system is one of the true “grand challenges” of Earth and planetary science. In the past three decades much progress towards understanding the dynamics of mantle convection has been made, with the increasing aid of computational modeling. Numerical sophistication has evolved significantly, and a small number of independent codes have been successfully employed. Computational power continues to increase dramatically, and with it the ability to resolve increasingly finer fluid mechanical structures. Yet, the perhaps most often cited limitation in numerical modeling based publications is still the limitation of computing power, because the ability to resolve thermal boundary layers within the convecting mantle (e.g., lithospheric plates), requires a spatial resolution of ~ 10 km. At present, the largest supercomputing facilities still barely approach the power to resolve this length scale in mantle convection simulations that include the physics necessary to model plate-like behavior. Our goal is to use supercomputing facilities to perform 3D spherical mantle convection simulations that include the ingredients for plate-like behavior, i.e. strongly temperature- and stress-dependent viscosity, at Earth-like convective vigor with a global resolution of order 10 km. In order to qualify to use such facilities, it is also necessary to demonstrate good parallel efficiency. Here we will present two kinds of results: (1) scaling properties of the community code CitcomS on DOE/NERSC's supercomputer Franklin for up to ~ 6000 processors, and (2) preliminary simulations that illustrate the role of a low-viscosity asthenosphere in plate-like behavior in mantle convection.

The Evolution of a Japanese Theory of Conflict Management and Implications for Japanese Foreign Policy

DTIC Science & Technology

2001-12-01

This thesis explores whether there is a uniquely Japanese method of conflict management Given the delicate balance of stability in Northeast Asia...Japanese leadership needs to use conflict management tools to resolve territorial claims with the governments of China, Russia, and South Korea, Given

Effective Student Motivation Commences with Resolving "Dissatisfiers"

ERIC Educational Resources Information Center

Prescott, Ann; Simpson, Edward

2004-01-01

The evolution in students' expectations based on Maslow's theory of human motivation shows a transition from expectations having an effect upon motivation towards those providing a satisfactory experience. Maslow's argument was that once the lower level needs, such as physiological and safety needs, are met other higher needs emerge. In the…

Evolutions of Advanced Stamping CAE — Technology Adventures and Business Impact on Automotive Dies and Stamping

NASA Astrophysics Data System (ADS)

Wang, Chuantao (C. T.)

2005-08-01

In the past decade, sheet metal forming and die development has been transformed to a science-based and technology-driven engineering and manufacturing enterprise from a tryout-based craft. Stamping CAE, especially the sheet metal forming simulation, as one of the core components in digital die making and digital stamping, has played a key role in this historical transition. The stamping simulation technology and its industrial applications have greatly impacted automotive sheet metal product design, die developments, die construction and tryout, and production stamping. The stamping CAE community has successfully resolved the traditional formability problems such as splits and wrinkles. The evolution of the stamping CAE technology and business demands opens even greater opportunities and challenges to stamping CAE community in the areas of (1) continuously improving simulation accuracy, drastically reducing simulation time-in-system, and improving operationalability (friendliness), (2) resolving those historically difficult-to-resolve problems such as dimensional quality problems (springback and twist) and surface quality problems (distortion and skid/impact lines), (3) resolving total manufacturability problems in line die operations including blanking, draw/redraw, trim/piercing, and flanging, and (4) overcoming new problems in forming new sheet materials with new forming techniques. In this article, the author first provides an overview of the stamping CAE technology adventures and achievements, and industrial applications in the past decade. Then the author presents a summary of increasing manufacturability needs from the formability to total quality and total manufacturability of sheet metal stampings. Finally, the paper outlines the new needs and trends for continuous improvements and innovations to meet increasing challenges in line die formability and quality requirements in automotive stamping.

Comparative analyses of plastid genomes from fourteen Cornales species: inferences for phylogenetic relationships and genome evolution.

PubMed

Fu, Chao-Nan; Li, Hong-Tao; Milne, Richard; Zhang, Ting; Ma, Peng-Fei; Yang, Jing; Li, De-Zhu; Gao, Lian-Ming

2017-12-08

The Cornales is the basal lineage of the asterids, the largest angiosperm clade. Phylogenetic relationships within the order were previously not fully resolved. Fifteen plastid genomes representing 14 species, ten genera and seven families of Cornales were newly sequenced for comparative analyses of genome features, evolution, and phylogenomics based on different partitioning schemes and filtering strategies. All plastomes of the 14 Cornales species had the typical quadripartite structure with a genome size ranging from 156,567 bp to 158,715 bp, which included two inverted repeats (25,859-26,451 bp) separated by a large single-copy region (86,089-87,835 bp) and a small single-copy region (18,250-18,856 bp) region. These plastomes encoded the same set of 114 unique genes including 31 transfer RNA, 4 ribosomal RNA and 79 coding genes, with an identical gene order across all examined Cornales species. Two genes (rpl22 and ycf15) contained premature stop codons in seven and five species respectively. The phylogenetic relationships among all sampled species were fully resolved with maximum support. Different filtering strategies (none, light and strict) of sequence alignment did not have an effect on these relationships. The topology recovered from coding and noncoding data sets was the same as for the whole plastome, regardless of filtering strategy. Moreover, mutational hotspots and highly informative regions were identified. Phylogenetic relationships among families and intergeneric relationships within family of Cornales were well resolved. Different filtering strategies and partitioning schemes do not influence the relationships. Plastid genomes have great potential to resolve deep phylogenetic relationships of plants.

Cascading disasters in the huge coastal aquifer of Salento (Apulia region, Southern Italy) ensuing droughts

NASA Astrophysics Data System (ADS)

Parisi, Alessandro; Fidelibus, Maria Dolores

2017-04-01

Physical extremes can be distinguished in "sudden physical extremes" (e.g. earthquakes, tsunami) and "progressive physical extremes" (e.g. drought, desertification, landslides). They differ for frequency, intensity, spatial extent, duration and timing of occurrence. If a physical extreme, by interacting with human systems, induces negative consequences, its outcome can be a "disaster". The disasters are, in both above cases, characterized by a few phases: physical extreme occurrence, emergency, response, and recovery. However, in the case of a progressive physical extreme, the disaster develops with an overlap in the time of the above-mentioned phases. When the events are repetitive, the emergency planning (which follows a cycle) succeeds with preparedness and mitigation with the intent of reducing the risk. Both the sudden and progressive physical extremes produce cascading effects of consequences on social, environmental and economic systems. Disasters consequent to sudden and progressive extremes show, however, some differences, mainly attributable to the "visibility" of the effects and to their time scale of evolution. As matter of fact, a disaster consequent to a progressive physical extreme produces "emerging signals" that are often invisible. Moreover, the emergency phase can arise with a time delay compared to the occurrence of the physical extreme, depending on the spatial scale of impacted system. The above differences allow defining "creeping disasters" the potential disasters related to progressive physical extremes. This study deals with some peculiar "cascading disasters" consequent to drought, which is the main "creeping disaster", namely the groundwater drought and the consequent salinization of coastal aquifers. In regional flow systems, their effects are invisible in the immediate to common people (and often even to managers) because of the concealed nature of groundwater; moreover, they are difficult to assess because of the shift over time of their evolution compared to the promptness of surface effects. The study area is the Salento coastal karstic aquifer (Apulia region, Southern Italy), where the groundwater flows according to a regional flow system. It has been subject to successive meteorological droughts between 1960 and 2010. The groundwater monitoring performed during this period, even with some gaps, allows identifying time lags between superficial effects and underground system response, potential tipping points, and emerging signals of the cascading disasters.

Sinkhole hazard assessment in Lesina Marina area (Apulia, Italy)

NASA Astrophysics Data System (ADS)

Canora, F.; Caporale, F.; D'Angella, A.; Fidelibus, D.; Gutierrez, F.; Pellicani, R.; Spilotro, G.

2012-04-01

In "Lesina Marina" area, located in the north-western part of the Apulia region (Italy), near the Adriatic coast, sinkhole phenomena are particularly widespread and constitute a risk for the built-up area. These phenomena are due to the structure of the evaporitic rocks located in the study area and to the groundwater regime, influenced by the presence of a channel that connects the sea to the lagoon. The complex sea-channel-lagoon system produces an inland flow towards the channel modulated by the tide with a variable width according to the rules of the coastal aquifers. Further studies have been carried out in order to clarify the context and the causes of this instability phenomenon. A procedure for the sinkhole susceptibility and hazard assessment has been performed, in order to evaluate the spatial distribution of the most unstable areas and the potential spatio-temporal evolution of the phenomenon. The sinkhole susceptibility model has been created in GIS by assessing the spatial relationship between the sinkhole inventory map and a series of thematic maps relative to instability factors. The thematic layers selected for the study are nine and cover geometrical features of the surface, of the gypsum rockhead and of the incoherent soil cover, groundwater and daily and seasonal groundwater level variations. Daily groundwater variation in a semiconfined coastal aquifer can be related to the permeability and to the void structures of the evaporitic mass. In the years subsequent to 1980, when the first reports of the presence of sinkholes are dated, the evolution of these instabilities in terms of their number and of their increase of extension has been monitored with repeated surveys. These data were used for susceptibility model validation and to define the hazard model. The selected layers revealed to be very useful in describing and mapping the hazard coming from suffusion sinkholes in the study area. The sinkhole hazard assessment is carried out, according to previous methodologies, by spatio-temporal probability (frequency) of new sinkholes in each susceptibility class. The sinkhole hazard mapping in this area will provide a useful tool for planning, development, management and recovery of areas affected by the instability and constitutes a useful basis to plan sustainable risk mitigation measures.

The Resolved Stellar Populations Early Release Science Program

NASA Astrophysics Data System (ADS)

Gilbert, Karoline; Weisz, Daniel; Resolved Stellar Populations ERS Program Team

2018-06-01

The Resolved Stellar Populations Early Release Science Program (PI D. Weisz) will observe Local Group targets covering a range of stellar density and star formation histories, including a globular cluster, and ultra-faint dwarf galaxy, and a star-forming dwarf galaxy. Using observations of these diverse targets we will explore a broad science program: we will measure star formation histories, the sub-solar stellar initial mass function, and proper motions, perform studies of evolved stars, and map extinction in the target fields. Our observations will be of high archival value for other science such as calibrating stellar evolution models, studying variable stars, and searching for metal-poor stars. We will determine optimal observational setups and develop data reduction techniques that will be common to JWST studies of resolved stellar populations. We will also design, test, and release point spread function (PSF) fitting software specific to NIRCam and NIRISS, required for the crowded stellar regime. Prior to the Cycle 2 Call for Proposals, we will release PSF fitting software, matched HST and JWST catalogs, and clear documentation and step-by-step tutorials (such as Jupyter notebooks) for reducing crowded stellar field data and producing resolved stellar photometry catalogs, as well as for specific resolved stellar photometry science applications.

Indications for the past redox environments in deep groundwaters from the isotopic composition of carbon and oxygen in fracture calcite, Olkiluoto, SW Finland.

PubMed

Sahlstedt, Elina; Karhu, Juha A; Pitkanen, Petteri

2010-09-01

In paleohydrogeological studies, the geochemical and isotope geochemical composition of fracture calcites can be utilised to gain information about the evolution of the composition of deep groundwaters in crystalline bedrock. The aim of our study was to investigate the latest hydrogeochemical evolution of groundwaters in the crystalline bedrock at Olkiluoto, which is the planned site for deep geological disposal of spent nuclear fuel. Samples were collected from drill cores intercepting water-conducting fractures at the upper ~500 m of the bedrock. The latest fracture calcite generations were identified using optical microscopy and electron microprobe. They occur as thin ~10-200 μm crusts or small euhedral crystals on open fracture surfaces. These latest calcite fillings were carefully sampled and analysed for the isotopic composition on carbon and oxygen. In addition, fluid inclusion homogenisation temperatures were determined on selected calcite samples. Fluid inclusion data indicated a low temperature of formation for the latest fracture calcite fillings. The δ(18)O values of calcite in these fracture fillings vary only slightly, from-7.3 to-11.5 ‰ (Vienna Pee Dee Belemnite, VPDB), whereas the δ(13)C values fluctuate widely, from-30 to+31 ‰ (VPDB). The δ(13)C values of latest calcite fillings show a systematic pattern with depth, with high and variable δ(13)C values below 50 m. The high δ(13)C values indicate active methanogenesis during the formation of the latest calcite fillings. In contrast, the present-day methanic redox environment is restricted to depths below 200-300 m. It is possible that the shift in the redox environment at Olkiluoto has occurred during infiltration of SO2-(4)-rich marine waters, the latest of such events being the infiltration of brackish waters of the Littorina Sea stage of the Baltic Sea at ~8000-3000 BP.

Bordetella pertussis evolution in the (functional) genomics era

PubMed Central

Belcher, Thomas; Preston, Andrew

2015-01-01

The incidence of whooping cough caused by Bordetella pertussis in many developed countries has risen dramatically in recent years. This has been linked to the use of an acellular pertussis vaccine. In addition, it is thought that B. pertussis is adapting under acellular vaccine mediated immune selection pressure, towards vaccine escape. Genomics-based approaches have revolutionized the ability to resolve the fine structure of the global B. pertussis population and its evolution during the era of vaccination. Here, we discuss the current picture of B. pertussis evolution and diversity in the light of the current resurgence, highlight import questions raised by recent studies in this area and discuss the role that functional genomics can play in addressing current knowledge gaps. PMID:26297914

Compositional Variations of Paleogene and Neogene Tephra From the Northern Izu-Bonin-Mariana Arc

NASA Astrophysics Data System (ADS)

Tepley, F. J., III; Barth, A. P.; Brandl, P. A.; Hickey-Vargas, R.; Jiang, F.; Kanayama, K.; Kusano, Y.; Li, H.; Marsaglia, K. M.; McCarthy, A.; Meffre, S.; Savov, I. P.; Yogodzinski, G. M.

2014-12-01

A primary objective of IODP Expedition 351 was to evaluate arc initiation processes of the Izu-Bonin-Mariana (IBM) volcanic arc and its compositional evolution through time. To this end, a single thick section of sediment overlying oceanic crust was cored in the Amami Sankaku Basin where a complete sediment record of arc inception and evolution is preserved. This sediment record includes ash and pyroclasts, deposited in fore-arc, arc, and back-arc settings, likely associated with both the ~49-25 Ma emergent IBM volcanic arc and the evolving Ryukyu-Kyushu volcanic arc. Our goal was to assess the major element evolution of the nascent and evolving IBM system using the temporally constrained record of the early and developing system. In all, more than 100 ash and tuff layers, and pyroclastic fragments were selected from temporally resolved portions of the core, and from representative fractions of the overall core ("core catcher"). The samples were prepared to determine major and minor element compositions via electron microprobe analyses. This ash and pyroclast record will allow us to 1) resolve the Paleogene evolutionary history of the northern IBM arc in greater detail; 2) determine compositional variations of this portion of the IBM arc through time; 3) compare the acquired data to an extensive whole rock and tephra dataset from other segments of the IBM arc; 4) test hypotheses of northern IBM arc evolution and the involvement of different source reservoirs; and 5) mark important stratigraphic markers associated with the Neogene volcanic history of the adjacent evolving Ryukyu-Kyushu arc.

Adaptive evolution in the Arabidopsis MADS-box gene family inferred from its complete resolved phylogeny

PubMed Central

Martínez-Castilla, León Patricio; Alvarez-Buylla, Elena R.

2003-01-01

Gene duplication is a substrate of evolution. However, the relative importance of positive selection versus relaxation of constraints in the functional divergence of gene copies is still under debate. Plant MADS-box genes encode transcriptional regulators key in various aspects of development and have undergone extensive duplications to form a large family. We recovered 104 MADS sequences from the Arabidopsis genome. Bayesian phylogenetic trees recover type II lineage as a monophyletic group and resolve a branching sequence of monophyletic groups within this lineage. The type I lineage is comprised of several divergent groups. However, contrasting gene structure and patterns of chromosomal distribution between type I and II sequences suggest that they had different evolutionary histories and support the placement of the root of the gene family between these two groups. Site-specific and site-branch analyses of positive Darwinian selection (PDS) suggest that different selection regimes could have affected the evolution of these lineages. We found evidence for PDS along the branch leading to flowering time genes that have a direct impact on plant fitness. Sites with high probabilities of having been under PDS were found in the MADS and K domains, suggesting that these played important roles in the acquisition of novel functions during MADS-box diversification. Detected sites are targets for further experimental analyses. We argue that adaptive changes in MADS-domain protein sequences have been important for their functional divergence, suggesting that changes within coding regions of transcriptional regulators have influenced phenotypic evolution of plants. PMID:14597714

The source of groundwater and solutes to Many Devils Wash at a former uranium mill site in Shiprock, New Mexico

USGS Publications Warehouse

Robertson, Andrew J.; Ranalli, Anthony J.; Austin, Stephen A.; Lawlis, Bryan R.

2016-04-21

The Shiprock Disposal Site is the location of the former Navajo Mill (Mill), a uranium ore-processing facility, located on a terrace overlooking the San Juan River in the town of Shiprock, New Mexico. Following the closure of the Mill, all tailings and associated materials were encapsulated in a disposal cell built on top of the former Mill and tailings piles. The milling operations, conducted at the site from 1954 to 1968, created radioactive tailings and process-related wastes that are now found in the groundwater. Elevated concentrations of constituents of concern—ammonium, manganese, nitrate, selenium, strontium, sulfate, and uranium—have also been measured in groundwater seeps in the nearby Many Devils Wash arroyo, leading to the inference that these constituents originated from the Mill. These constituents have also been reported in groundwater that is associated with Mancos Shale, the bedrock that underlies the site. The objective of this report is to increase understanding of the source of water and solutes to the groundwater beneath Many Devils Wash and to establish the background concentrations for groundwater that is in contact with the Mancos Shale at the site. This report presents evidence on three working hypotheses: (1) the water and solutes in Many Devils Wash originated from the operations at the former Mill, (2) groundwater in deep aquifers is upwelling under artesian pressure to recharge the shallow groundwater beneath Many Devils Wash, and (3) the groundwater beneath Many Devils Wash originates as precipitation that infiltrates into the shallow aquifer system and discharges to Many Devils Wash in a series of springs on the east side of the wash. The solute concentrations in the shallow groundwater of Many Devils Wash would result from the interaction of the water and the Mancos Shale if the source of water was upwelling from deep aquifers or precipitation.In order to compare the groundwater from various wells to groundwater that has been affected by Mill activities, a classification system was developed to determine which wells were most likely to have been affected. Affects to groundwater by the Mill were determined by using the reported uranium alpha activity ratios measured in groundwater samples, along with the concentration of the uranium and the location of the wells relative to the Mill. Activity ratios of 1.2 or less were determined to be the most reliable indicator of Mill-affected groundwater. Wells with samples that had a reported activity ratio of 1.2 or less were classified as Mill affected. To compare groundwater with background water-quality, data from groundwater seeps and springs in the Upper Eagle Nest Arroyo and Salt Creek Wash, located north of the San Juan River, are also presented and analyzed.Based on groundwater elevations and tritium concentrations measured in wells located between the disposal cell and Many Devils Wash, Mill water is not likely to reach Many Devils Wash. The tritium concentrations also indicate that groundwater from the Mill has not substantially affected Many Devils Wash in the past. Upwelling from deep aquifers was also determined to be an unlikely source, primarily by comparing the composition of the stable isotopes of water in the shallow groundwater with those reported in groundwater samples from the deeper aquifers. The stable-isotope compositions of the shallow groundwater around the site are enriched relative to the San Juan River and local meteoric lines, which suggests that most of the shallow groundwater has been influenced by evaporation and therefore was recharged at the surface. Several observations indicate that focused recharge is the likely source of groundwater in the area of Many Devils Wash. The visible erosional features in Many Devils Wash provide evidence of piping and groundwater sapping, and the distribution and type of vegetation in Many Devils Wash suggest that the focused recharge of precipitation is occurring. The estimated recharge from precipitation was calculated to be 0.0008 inches per year (in/yr) by using the mass-balance approach from reported seep discharge and 0.0011 in/yr using the chloride mass-balance approach.A conceptual model of groundwater quality beneath Many Devils Wash is presented to explain the source of solutes in the groundwater beneath Many Devils Wash. The major-ion concentrations and geochemical evolution in the groundwater beneath Many Devils Wash and across the study area support the conceptual model that the underlying Mancos Shale is the source of solutes. Differences in the major-ion composition between groundwater samples collected around the site, result from the degree of weathering to the Mancos Shale. The cation distribution appears to be an indicator of effects from the Mill, with samples from the Mill-affected wells largely having a calcium/magnesium-sulfate composition that resembles the reported compositions of more weathered shale; however, that composition could change if the Mill-processed water flowed into areas where the Mancos Shale was less weathered. On the basis of the widespread presence of uranium in the Mancos Shale and the distribution of aqueous uranium in the analog sites and other sites in the region, it appears likely that uranium in the groundwater of Many Devils Wash is naturally sourced from the Mancos Shale.

Geochemical Signature of Natural Water Recharge in the Jungar Basin and Its Response to Climate.

PubMed

Zhu, Bingqi; Yu, Jingjie; Rioual, Patrick

2016-01-01

This paper analyzed the physico-chemical characteristics of natural waters in a drainage system of the Jungar Basin, northwestern China to identify chemical evolution and recharge mechanisms of natural waters in an arid environment. The waters studied are different in mineralization, but are typically carbonate rivers and alkaline in nature. No Cl-dominated water type occurs, indicating an early stage of water evolution. Regolith and geomorphological parameters controlling ground-surface temperature may play a large role in the geological evolution of the water. Three main morphological and hydrological units are reflected in water physico-chemistry. Climate influences the salinization of natural waters substantially. Direct recharge from seasonal snow and ice-melt water and infiltration of rain to the ground are significant recharge processes for natural waters, but recharge from potential deep groundwater may be less important. The enrichment of ions in lakes has been mainly caused by evaporation rather than through the quality change of the recharged water.

Assessment of the hydrologic setting and mass transport within Saharan and Arabian Aquifers using GRACE, geochemical, geophysical and subsurface data

NASA Astrophysics Data System (ADS)

Sultan, M.; Sturchio, N. C.; Ahmed, M.; Saleh, S.; Mohamed, A.; Abuabdullah, M. M.; Emil, M. K.; Bettadpur, S. V.; Save, H.; Fathy, K.; Chouinard, K.

2016-12-01

A better understanding of the hydrologic setting, mass transport, origin, evolution, utilization, sustainability, and paleo-climatic recharge conditions of Saharan and Arabian aquifers was achieved by integrating observation from monthly (04/2002 to 03/2016) Gravity Recovery and Climate Experiment (GRACE)-derived Terrestrial Water Storage (TWS) from multiple GRACE solutions (mascons and spherical harmonic fields) with others from geochemical (solute chemistry), isotopic (O, H, Sr), geochronologic (Chlorine-36, Krypton-81), geophysical (aerogravity and aeromagnetic), and subsurface data. The investigated aquifers are: (1) Nubian Sandstone Aquifer System (NSAS; area: 2×106 km2) in northeast Africa and, (2) Mega Aquifer System (MAS; area: 1.1×106 km2) in Arabia. Our findings indicate the NSAS and MAS were largely recharged in previous wet climatic Pleistocene periods, as evidenced by the groundwater ages (up to 1 million years), yet they receive modest local recharge during interleaving dry periods in areas of relatively high (≥ 20 mm/yr) precipitation. In Sudan and Chad (southern NSAS), the average annual precipitation (AAP) is 95 mm/yr and the recharge is estimated at 3.2 x 109 m3/yr ( 7% of AAP); in the southwest parts of the MAS, the recharge at the foothills of the Red Sea mountains is 1.8 x 109 m3/yr (10% of AAP). Uplifts and/or shear zones orthogonal to groundwater flow impede the south to north flow in the NSAS as evidenced by the large differences in GRACE-derived TWS trends, groundwater ages, and isotopic compositions on either side of the east-west trending Uweinat-Aswan uplift. Similarly west to east groundwater flow in the MAS is impeded and impounded up-gradient from the N-S and/or NW-SE trending basement structures, reactivated during Red Sea opening. Shear zones subparallel to groundwater flow act as preferred flow pathways, as is the case with the NE-SW trending Pelusium shear zone which channels groundwater from the Kufra sub-basin (Libya) towards the Dakhla sub-basin (Egypt). Areas targeted for agricultural expansion are those that show none to minimal depletions in GRACE derived TWS trends (e.g., NSAS: northern sections; MAS: areas proximal to Red Sea Hills in the Empty Quarter) and others within, or proximal to, preferred pathways for groundwater flow (e.g., Pelusium shear zone).

Investigating the salinization and freshening processes of coastal groundwater resources in Urmia aquifer, NW Iran.

PubMed

Amiri, Vahab; Nakhaei, Mohammad; Lak, Razyeh; Kholghi, Majid

2016-04-01

This paper presents the results of an assessment about interaction between Urmia Lake (UL) and coastal groundwater in the Urmia aquifer (UA). This aquifer is the most significant contributor to the freshwater supply of the coastal areas. The use of hydrochemical facies can be very useful to identify the saltwater encroachment or freshening phases in the coastal aquifers. In this study, the analysis of salinization/freshening processes was carried out through the saturation index (SI), ionic deltas (Δ), binary diagrams, and hydrochemical facies evolution (HFE) diagram. Based on the Gibbs plot, the behavior of the major ions showed that the changes in the chemical composition of the groundwater are mainly controlled by the water-soil/rock interaction zone and few samples are relatively controlled by evaporation. A possible explanation for this phenomenon is that the deposited chloride and sulfate particles can form the minor salinity source in some coastal areas when washed down by precipitation. The SI calculations showed that all groundwater samples, collected in these periods, show negative saturation indices, which indicate undersaturation with respect to anhydrite, gypsum, and halite. In addition, except in a few cases, all other samples showed the undersaturation with respect to the carbonate minerals such as aragonite, calcite, and dolomite. Therefore, these minerals are susceptible to dissolution. In the dry season, the SI calculations showed more positive values with respect to dolomite, especially in the northern part of UA, which indicated a higher potential for precipitation and deposition of dolomite. The percentage of saltwater in the groundwater samples of Urmia plain was very low, ranging between 0.001 and 0.79 % in the wet season and 0.0004 and 0.81 % in the dry season. The results of HFE diagram, which was taken to find whether the aquifer was in the saltwater encroachment phase or in the freshening phase, indicated that except for a few wells near the coast, there is very little hydraulic interaction between UA and UL. In this coastal area, most of the samples that were collected repeatedly in both wet and dry seasons showed the same hydrochemical facies, which suggested that the seasonal groundwater fluctuations cannot significantly change the chemical composition of groundwater.

Airborne electromagnetic imaging of discontinuous permafrost

USGS Publications Warehouse

Minsley, B.J.; Abraham, J.D.; Smith, B.D.; Cannia, J.C.; Voss, C.I.; Jorgenson, M.T.; Walvoord, Michelle Ann; Wylie, B.K.; Anderson, L.; Ball, L.B.; Deszcz-Pan, M.; Wellman, T.P.; Ager, T.A.

2012-01-01

The evolution of permafrost in cold regions is inextricably connected to hydrogeologic processes, climate, and ecosystems. Permafrost thawing has been linked to changes in wetland and lake areas, alteration of the groundwater contribution to streamflow, carbon release, and increased fire frequency. But detailed knowledge about the dynamic state of permafrost in relation to surface and groundwater systems remains an enigma. Here, we present the results of a pioneering ∼1,800 line-kilometer airborne electromagnetic survey that shows sediments deposited over the past ∼4 million years and the configuration of permafrost to depths of ∼100 meters in the Yukon Flats area near Fort Yukon, Alaska. The Yukon Flats is near the boundary between continuous permafrost to the north and discontinuous permafrost to the south, making it an important location for examining permafrost dynamics. Our results not only provide a detailed snapshot of the present-day configuration of permafrost, but they also expose previously unseen details about potential surface – groundwater connections and the thermal legacy of surface water features that has been recorded in the permafrost over the past ∼1,000 years. This work will be a critical baseline for future permafrost studies aimed at exploring the connections between hydrogeologic, climatic, and ecological processes, and has significant implications for the stewardship of Arctic environments.

Reactive transport modelling of groundwater chemistry in a chalk aquifer at the watershed scale

NASA Astrophysics Data System (ADS)

Mangeret, A.; De Windt, L.; Crançon, P.

2012-09-01

This study investigates thermodynamics and kinetics of water-rock interactions in a carbonate aquifer at the watershed scale. A reactive transport model is applied to the unconfined chalk aquifer of the Champagne Mounts (France), by considering both the chalk matrix and the interconnected fracture network. Major element concentrations and main chemical parameters calculated in groundwater and their evolution along flow lines are in fair agreement with field data. A relative homogeneity of the aquifer baseline chemistry is rapidly reached in terms of pH, alkalinity and Ca concentration since calcite equilibrium is achieved over the first metres of the vadose zone. However, incongruent chalk dissolution slowly releases Ba, Mg and Sr in groundwater. Introducing dilution effect by rainwater infiltration and a local occurrence of dolomite improves the agreement between modelling and field data. The dissolution of illite and opal-CT, controlling K and SiO2 concentrations in the model, can be approximately tackled by classical kinetic rate laws, but not the incongruent chalk dissolution. An apparent kinetic rate has therefore been fitted on field data by inverse modelling: 1.5 × 10- 5 molchalk L - 1water year - 1. Sensitivity analysis indicates that the CO2 partial pressure of the unsaturated zone is a critical parameter for modelling the baseline chemistry over the whole chalk aquifer.

Chemical and isotopic constrains on the origin of brine and saline groundwater in Hetao plain, Inner Mongolia.

PubMed

Liu, Jun; Chen, Zongyu; Wang, Lijuan; Zhang, Yilong; Li, Zhenghong; Xu, Jiaming; Peng, Yurong

2016-08-01

The origin and evolution of brine and saline groundwater have always been a challenged work for geochemists and hydrogeologists. Chemical and isotopic data of brine and saline waters were used to trace the sources of salinity and therefore to understand the transport mechanisms of groundwater in Xishanzui, Inner Mongolia. Both Cl/Br (molar) versus Na/Br (molar) and Cl (meq/L) versus Na (meq/L) indicated that salinity was from halite dissolution or at least a significant impact by halite dissolution. The logarithmic plot of the concentration trends of Cl (mg/L) versus Br (mg/L) for the evaporation of seawater and the Qinghai Salt Lake showed that the terrestrial halite dissolution was the dominated contribution for the salinity of this brine. The stable isotope ratios of hydrogen and oxygen suggested that the origin of brine was from paleorecharge water which experienced mixing of modern water in shallow aquifer. δ(37)Cl values ranged from -0.02 to 3.43 ‰ (SMOC), and reflecting mixing of different sources. The Cl isotopic compositions suggest that the dissolution of halite by paleometeoric water had a great contribution to the salinity of brine, and the contributions of the residual seawater and the dissolution of halite by the Yellow River water could be excluded.

Hydrogeochemical processes in the Plio-Quaternary Remila aquifer (Khenchela, Algeria)

NASA Astrophysics Data System (ADS)

Aouidane, Laiche; Belhamra, Mohamed

2017-06-01

The Remila Plain is a synclinal structure in northeast Algeria, situated within a semi-arid climate zone and composed of Mio-Pliocene-Quaternary deposits. Within the syncline, the Plio-Quaternary aquifer is the main source of drinking water for cattle and for agricultural irrigation water. This work aims to investigate the origin of groundwater mineralization and to identify the primary hydrogeochemical processes controlling groundwater evolution in the Remila aquifer. A total of 86 water samples from boreholes were analyzed for major, minor and stable isotopes (18O, 2H) over three seasons: first during low water levels in 2013, second during high water levels in 2014 and third for stable isotopes during low water levels in 2015. The analysis showed that the aquifer is controlled by five principal geochemical processes: (I) the dissolution of evaporite rocks, (II) cation exchange and reverse exchange reactions, (III) congruent dissolution of carbonates (calcite, dolomite) coupled with the dissolution of gypsum and calcite precipitation, (IV) sulfate reduction under anaerobic conditions, and (V) saltwater intrusion in the northeastern Sabkha plains. The 18O and deuterium concentrations in groundwater are very low, indicating that the aquifer is recharged by evaporated rainfall originating from the north slope of the Aurès Mountains which confirms that the aquifer is recharged in the southern part of the plain.

Single-Walled Carbon Nanotubes, Carbon Nanofibers and Laser-Induced Incandescence

NASA Technical Reports Server (NTRS)

Schubert, Kathy (Technical Monitor); VanderWal, Randy L.; Ticich, Thomas M.; Berger, Gordon M.; Patel, Premal D.

2004-01-01

Laser induced incandescence applied to a heterogeneous, multi-element reacting flows is characterized by a) temporally resolved emission spectra, time-resolved emission at selected detection wavelengths and fluence dependence. Laser fluences above 0.6 Joules per square centimeter at 1064 nm initiate laser-induced vaporization, yielding a lower incandescence intensity, as found through fluence dependence measurements. Spectrally derived temperatures show that values of excitation laser fluence beyond this value lead to a super-heated plasma, well above the vaporization of temperature of carbon. The temporal evolution of the emission signal at these fluences is consistent with plasma dissipation processes, not incandescence from solid-like structures.

Relaxation of water infiltration pulses observed with GPR

NASA Astrophysics Data System (ADS)

Hantschel, Lisa; Hemmer, Benedikt; Roth, Kurt

2017-04-01

We observe the relaxation of infiltration pulses in sandy soil with ground-penetrating radar (GPR). The spatial distribution of water in the infiltration area and its temporal evolution is represented by ordinary reflections at layer boundaries as well as multiple reflections at the wetting front and the pulse boundaries. The structure of these highly resolved signals are reproduced by numerical simulations of electromagnetic wave propagation. The temporally highly resolved electrical fields reveal the origin also of complex reflection signals. The usage of these more complex signals might allow a more detailed representation of the infiltration process by direct analysis as well as in combination with inversion techniques.

Transcriptome sequences resolve deep relationships of the grape family.

PubMed

Wen, Jun; Xiong, Zhiqiang; Nie, Ze-Long; Mao, Likai; Zhu, Yabing; Kan, Xian-Zhao; Ickert-Bond, Stefanie M; Gerrath, Jean; Zimmer, Elizabeth A; Fang, Xiao-Dong

2013-01-01

Previous phylogenetic studies of the grape family (Vitaceae) yielded poorly resolved deep relationships, thus impeding our understanding of the evolution of the family. Next-generation sequencing now offers access to protein coding sequences very easily, quickly and cost-effectively. To improve upon earlier work, we extracted 417 orthologous single-copy nuclear genes from the transcriptomes of 15 species of the Vitaceae, covering its phylogenetic diversity. The resulting transcriptome phylogeny provides robust support for the deep relationships, showing the phylogenetic utility of transcriptome data for plants over a time scale at least since the mid-Cretaceous. The pros and cons of transcriptome data for phylogenetic inference in plants are also evaluated.

Influence of the paleogeographic evolution on the groundwater salinity in a coastal aquifer. Cabo de Gata aquifer, SE Spain

NASA Astrophysics Data System (ADS)

Vallejos, A.; Sola, F.; Yechieli, Y.; Pulido-Bosch, A.

2018-02-01

The groundwater of the Cabo de Gata detritic aquifer, in southeastern Spain, exhibit salinities of between 70-726 mmol/L of Cl- (brackish-salt to hypersaline waters). We have investigated the causes of the high salinity anomaly, which at certain points exceeds that of present-day seawater (600 mmol/L). Two hypotheses are considered as possible sources for the saline water: (1) The deeper, more saline groundwater date back to an old marine intrusion that occurred at the end of the last Ice Age (14-17 ka), when seawater salinity was higher than in the present day. This hypothesis is supported by the values of 14C measured in this water (∼6-10 pmc), which indicate old water of up to 17 ka. However, the values of 18O and 2H are lower than would be expected. (2) The water is the result of mixing between fresh groundwater and seawater. The latter explanation agrees well with the low values of 18O and 2H. This mixture is later subject to evaporation, explaining its high salinity. Hydrogeochemical modelling was carried out for the most saline samples, assuming such mixing between freshwater and seawater followed by evaporation, and the results show a very good agreement between the measured and simulated values. According to the model calculation, the original mixture contained approximately 60% seawater and its volume subsequently was reduced through evaporation by around 30%. This mixing and evaporation could occur during the Flandrian Transgression (6000-8000 y), when this area accommodated a coastal lagoon.

Coupling a three-dimensional subsurface flow model with a land surface model to simulate stream-aquifer-land interactions

NASA Astrophysics Data System (ADS)

Huang, M.; Bisht, G.; Zhou, T.; Chen, X.; Dai, H.; Hammond, G. E.; Riley, W. J.; Downs, J.; Liu, Y.; Zachara, J. M.

2016-12-01

A fully coupled three-dimensional surface and subsurface land model is developed and applied to a site along the Columbia River to simulate three-way interactions among river water, groundwater, and land surface processes. The model features the coupling of the Community Land Model version 4.5 (CLM4.5) and a massively-parallel multi-physics reactive tranport model (PFLOTRAN). The coupled model (CLM-PFLOTRAN) is applied to a 400m×400m study domain instrumented with groundwater monitoring wells in the Hanford 300 Area along the Columbia River. CLM-PFLOTRAN simulations are performed at three different spatial resolutions over the period 2011-2015 to evaluate the impact of spatial resolution on simulated variables. To demonstrate the difference in model simulations with and without lateral subsurface flow, a vertical-only CLM-PFLOTRAN simulation is also conducted for comparison. Results show that the coupled model is skillful in simulating stream-aquifer interactions, and the land-surface energy partitioning can be strongly modulated by groundwater-river water interactions in high water years due to increased soil moisture availability caused by elevated groundwater table. In addition, spatial resolution does not seem to impact the land surface energy flux simulations, although it is a key factor for accurately estimating the mass exchange rates at the boundaries and associated biogeochemical reactions in the aquifer. The coupled model developed in this study establishes a solid foundation for understanding co-evolution of hydrology and biogeochemistry along the river corridors under historical and future hydro-climate changes.

Stratigraphic and structural controls on groundwater flow in an outcropping fossil fan delta: the case of Sant Llorenç del Munt range (NE Spain)

NASA Astrophysics Data System (ADS)

Anglés, Marc; Folch, Albert; Oms, Oriol; Maestro, Eudald; Mas-Pla, Josep

2017-12-01

Hydrogeological models of mountain regions present the opportunity to understand the role of geological factors on groundwater resources. The effects of sedimentary facies and fracture distribution on groundwater flow and resource exploitation are studied in the ancient fan delta of Sant Llorenç de Munt (central Catalonia, Spain) by integrating geological field observations (using sequence stratigraphy methods) and hydrogeological data (pumping tests, hydrochemistry and environmental isotopes). A comprehensive analysis of data portrays the massif as a single unit, constituted by different compartments determined by specific layers and sets of fractures. Two distinct flow systems—local and regional—are identified based on pumping test analysis as well as hydrochemical and isotopic data. Drawdown curves derived from pumping tests indicate that the behavior of the saturated layers, whose main porosity is given by the fracture network, corresponds to a confined aquifer. Pumping tests also reflect a double porosity within the system and the occurrence of impervious boundaries that support a compartmentalized model for the whole aquifer system. Hydrochemical data and associated spatial evolution show the result of water-rock interaction along the flow lines. Concentration of magnesium, derived from dolomite dissolution, is a tracer of the flow-path along distinct stratigraphic units. Water stable isotopes indicate that evaporation (near a 5% loss) occurs in a thick unsaturated zone within the massif before infiltration reaches the water table. The hydrogeological analysis of this outcropping system provides a methodology for the conceptualization of groundwater flow in similar buried systems where logging and hydrogeological information are scarce.

Giant hub Src and Syk tyrosine kinase thermodynamic profiles recapitulate evolution

NASA Astrophysics Data System (ADS)

Phillips, J. C.

2017-10-01

Thermodynamic scaling theory, previously applied mainly to small proteins, here analyzes quantitative evolution of the titled functional network giant hub enzymes. The broad domain structure identified homologically is confirmed hydropathically using amino acid sequences only. The most surprising results concern the evolution of the tyrosine kinase globular surface roughness from avians to mammals, which is first order, compared to the evolution within mammals from rodents to humans, which is second order. The mystery of the unique amide terminal region of proto oncogene tyrosine protein kinase is resolved by the discovery there of a rare hydroneutral septad targeting cluster, which is paralleled by an equally rare octad catalytic cluster in tyrosine kinase in humans and a few other species (cat and dog). These results, which go far towards explaining why these proteins are among the largest giant hubs in protein interaction networks, use no adjustable parameters.

TIME EVOLUTION OF KELVIN–HELMHOLTZ VORTICES ASSOCIATED WITH COLLISIONLESS SHOCKS IN LASER-PRODUCED PLASMAS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuramitsu, Y.; Moritaka, T.; Mizuta, A.

2016-09-10

We report experimental results on Kelvin–Helmholtz (KH) instability and resultant vortices in laser-produced plasmas. By irradiating a double plane target with a laser beam, asymmetric counterstreaming plasmas are created. The interaction of the plasmas with different velocities and densities results in the formation of asymmetric shocks, where the shear flow exists along the contact surface and the KH instability is excited. We observe the spatial and temporal evolution of plasmas and shocks with time-resolved diagnostics over several shots. Our results clearly show the evolution of transverse fluctuations, wavelike structures, and circular features, which are interpreted as the KH instability andmore » resultant vortices. The relevant numerical simulations demonstrate the time evolution of KH vortices and show qualitative agreement with experimental results. Shocks, and thus the contact surfaces, are ubiquitous in the universe; our experimental results show general consequences where two plasmas interact.« less

Sample descriptions and geophysical logs for cored well BP-3-USGS, Great Sand Dunes National Park and Preserve, Alamosa County, Colorado

USGS Publications Warehouse

Grauch, V.J.S.; Skipp, Gary L.; Thomas, Jonathan V.; Davis, Joshua K.; Benson, Mary Ellen

2015-01-01

BP-3-USGS was sited to test hypotheses developed from geophysical studies and to answer questions about the history and evolution of Pliocene and Pleistocene Lake Alamosa, which is represented by lacustrine deposits sampled by the well. The findings reported here represent a basis from which future studies can answer these questions and address other important scientific questions in the San Luis Valley regarding geologic history and climate change, groundwater hydrology, and geophysical interpretation.

Exploring Groundwater origin for theater-headed valleys on the walls of Ius Chasma based on geomorphological analogy to the Saharan Plateaus

NASA Astrophysics Data System (ADS)

Farag, A. Z. A.; Heggy, E.; Mohamed, R.

2017-12-01

Understanding the origin and evolution of Martian fluvial landforms constrains the ambiguities associated to the variability of paleoclimatic and hydrological conditions. Despite of the significance of understanding the mechanism of formation of theater-headed valleys (THV) in Valles Mariners, where abundant distribution of seasonal liquid water flow is reported, their origin remains debatable. The original groundwater sapping hypothesis is challenged by the capability of springs to cut canyons into massive rocks and alternatively mega-floods and landslides were suggested. On Earth however, widespread THV cutting through the carbonate plateaus in the Sahara are confirmed to be of long-lasting groundwater processes based on recent isotopic, geochemical and hydrogeological evidences. Geomorphological characterizations of the THV in both the Sahara and in Valles Marineris suggest similar settings including: (1) widespread and dense occurrence along the length of escarpments, (2) low relief floors, (3) association with extensive faulting, and (4) lack of well-developed stream networks and small upstream contributing areas. The above suggest that both the Martian and the Saharan THV to be of groundwater origins. Herein, we constraint the geomorphological, lithological and textural characteristics of THV in El Diffa and El-Merir plateaus in the Eastern Sahara as a limited analog to the THV in Ius Chasma using structural and textural mapping derived from ALOS PalSAR scenes and similar settings on Mars using SHARAD, MOLA and HIRISE images. These observations are correlated with several in-situ field and laboratory measurements for hardness, granulometry and channel morphology to support the common phenomenology. Preliminary findings show that in both sets of THV, we observe a spatial confinement of boulders to the sidewalls with relatively finer grains along the channel courses, and association with large-scale hydrated sulphates along the sidewalls and channel bottoms. These findings support the hypothesis that long-lasting groundwater processes have contributed to the formation of these valleys on Mars rather than intensive short-lived processes. Moreover, disintegration of rocky materials arising from groundwater salt weathering could have played a major role in carving the THV.

Geophysical Characterization of Groundwater-Fault Dynamics at San Andreas Oasis

NASA Astrophysics Data System (ADS)

Faherty, D.; Polet, J.; Osborn, S. G.

2017-12-01

The San Andreas Oasis has historically provided a reliable source of fresh water near the northeast margin of the Salton Sea, although since the recent completion of the Coachella Canal Lining Project and persistent drought in California, surface water at the site has begun to disappear. This may be an effect of the canal lining, however, the controls on groundwater are complicated by the presence of the Hidden Springs Fault (HSF), a northeast dipping normal fault that trends near the San Andreas Oasis. Its surface expression is apparent as a lineation against which all plant growth terminates, suggesting that it may form a partial barrier to subsurface groundwater flow. Numerous environmental studies have detailed the chemical evolution of waters resources at San Andreas Spring, although there remains a knowledge gap on the HSF and its relation to groundwater at the site. To better constrain flow paths and characterize groundwater-fault interactions, we have employed resistivity surveys near the surface trace of the HSF to generate profiles of lateral and depth-dependent variations in resistivity. The survey design is comprised of lines installed in Wenner Arrays, using an IRIS Syscal Kid, with 24 electrodes, at a maximum electrode spacing of 5 meters. In addition, we have gathered constraints on the geometry of the HSF using a combination of ground-based magnetic and gravity profiles, conducted with a GEM walking Proton Precession magnetometer and a Lacoste & Romberg gravimeter. Seventeen gravity measurements were acquired across the surface trace of the fault. Preliminary resistivity results depict a shallow conductor localized at the oasis and discontinuous across the HSF. Magnetic data reveal a large contrast in subsurface magnetic susceptibility that appears coincident with the surface trace and trend of the HSF, while gravity data suggests a shallow, relatively high density anomaly centered near the oasis. These data also hint at a second, previously undocumented fault bounding the opposite margin of the oasis and trending subparallel to the HSF. We thus speculate that the Hidden Springs Fault and this possible secondary fault act as partial barriers to lateral subsurface flow and form a structural wedge, localizing groundwater beneath the oasis.

Monitoring the evolution and migration of a methane gas plume in an unconfined sandy aquifer using time-lapse GPR and ERT.

PubMed

Steelman, Colby M; Klazinga, Dylan R; Cahill, Aaron G; Endres, Anthony L; Parker, Beth L

2017-10-01

Fugitive methane (CH 4 ) leakage associated with conventional and unconventional petroleum development (e.g., shale gas) may pose significant risks to shallow groundwater. While the potential threat of stray (CH 4 ) gas in aquifers has been acknowledged, few studies have examined the nature of its migration and fate in a shallow groundwater flow system. This study examines the geophysical responses observed from surface during a 72day field-scale simulated CH 4 leak in an unconfined sandy aquifer at Canadian Forces Base Borden, Canada, to better understand the transient behaviour of fugitive CH 4 gas in the subsurface. Time-lapse ground-penetrating radar (GPR) and electrical resistivity tomography (ERT) were used to monitor the distribution and migration of the gas-phase and assess any impacts to groundwater hydrochemistry. Geophysical measurements captured the transient formation of a CH 4 gas plume emanating from the injector, which was accompanied by an increase in total dissolved gas pressure (P TDG ). Subsequent reductions in P TDG were accompanied by reduced bulk resistivity around the injector along with an increase in the GPR reflectivity along horizontal bedding reflectors farther downgradient. Repeat temporal GPR reflection profiling identified three events with major peaks in reflectivity, interpreted to represent episodic lateral CH 4 gas release events into the aquifer. Here, a gradual increase in P TDG near the injector caused a sudden lateral breakthrough of gas in the direction of groundwater flow, causing free-phase CH 4 to migrate much farther than anticipated based on groundwater advection. CH 4 accumulated along subtle permeability boundaries demarcated by grain-scale bedding within the aquifer characteristic of numerous Borden-aquifer multi-phase flow experiments. Diminishing reflectivity over a period of days to weeks suggests buoyancy-driven migration to the vadose zone and/or CH 4 dissolution into groundwater. Lateral and vertical CH 4 migration was primarily governed by subtle, yet measurable heterogeneity and anisotropy in the aquifer. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

Seasonal variations and cycling of nitrous oxide using nitrogen isotopes and concentrations from an unsaturated zone of a floodplain

NASA Astrophysics Data System (ADS)

Bill, M.; Conrad, M. E.; Kolding, S.; Williams, K. H.; Tokunaga, T. K.

2014-12-01

Nitrous oxide (N2O) concentrations and isotope ratios of 15N to 14N of N2O in the vadose zone mainly depend on atmospheric deposition, symbiotic or non-symbiotic N2 fixation, and nitrification/denitrification processes in underlying groundwater. In an effort to quantify N2O seasonal variations, cycling and N budgets in an alluvial aquifer in western Colorado (Rifle, CO), the concentrations and nitrogen stable isotopes of N2O within the pore space of partially saturated sediments have been monitored over the 2013-2014 years. Vertically resolved profiles spanning from 0m to 3m depth were sampled at 0.5m increments at a periodicity of one month. At each of the profile locations, N2O concentrations decreased from 3m depth to the surface. The maximum concentrations were observed at the interface between the unsaturated zone and groundwater, with minimum values observed in the near surface samples. The d15N values tend to increase from the unsaturated zone/groundwater interface to the surface. Both variation of N2O concentrations and d15N values suggest that denitrification is the main contribution to N2O production and both parameters exhibited a strong seasonal variation. The maximum concentrations (~10ppmv) were observed at the beginning of summer, during the annual maximum in water table elevation. The minimum N2O concentrations were observed in the period from January to May and coincided with low water table elevations. Additionally, nitrogen concentrations and d15N values of the shallowest sediments within the vertical profiles do not show variation, suggesting that the main source of N2O is associated with groundwater denitrification, with the shallower, partially saturated sediments acting as a sink for N2O.

Maximum likelihood Bayesian model averaging and its predictive analysis for groundwater reactive transport models

DOE PAGES

Lu, Dan; Ye, Ming; Curtis, Gary P.

2015-08-01

While Bayesian model averaging (BMA) has been widely used in groundwater modeling, it is infrequently applied to groundwater reactive transport modeling because of multiple sources of uncertainty in the coupled hydrogeochemical processes and because of the long execution time of each model run. To resolve these problems, this study analyzed different levels of uncertainty in a hierarchical way, and used the maximum likelihood version of BMA, i.e., MLBMA, to improve the computational efficiency. Our study demonstrates the applicability of MLBMA to groundwater reactive transport modeling in a synthetic case in which twenty-seven reactive transport models were designed to predict themore » reactive transport of hexavalent uranium (U(VI)) based on observations at a former uranium mill site near Naturita, CO. Moreover, these reactive transport models contain three uncertain model components, i.e., parameterization of hydraulic conductivity, configuration of model boundary, and surface complexation reactions that simulate U(VI) adsorption. These uncertain model components were aggregated into the alternative models by integrating a hierarchical structure into MLBMA. The modeling results of the individual models and MLBMA were analyzed to investigate their predictive performance. The predictive logscore results show that MLBMA generally outperforms the best model, suggesting that using MLBMA is a sound strategy to achieve more robust model predictions relative to a single model. MLBMA works best when the alternative models are structurally distinct and have diverse model predictions. When correlation in model structure exists, two strategies were used to improve predictive performance by retaining structurally distinct models or assigning smaller prior model probabilities to correlated models. Since the synthetic models were designed using data from the Naturita site, the results of this study are expected to provide guidance for real-world modeling. Finally, limitations of applying MLBMA to the synthetic study and future real-world modeling are discussed.« less

Bomb fall-out 236U as a global oceanic tracer using an annually resolved coral core

PubMed Central

Winkler, Stephan R.; Steier, Peter; Carilli, Jessica

2012-01-01

Anthropogenic 236U (t½=23.4 My) is an emerging isotopic ocean tracer with interesting oceanographic properties, but only with recent advances in accelerator mass spectrometry techniques is it now possible to detect the levels from global fall-out of nuclear weapons testing across the water column. To make full use of this tracer, an assessment of its input into the ocean over the past decades is required. We captured the bomb-pulse of 236U in an annually resolved coral core record from the Caribbean Sea. We thereby establish a concept which gives 236U great advantage – the presence of reliable, well-resolved chronological archives. This allows studies of not only the present distribution pattern, but gives access to the temporal evolution of 236U in ocean waters over the past decades. PMID:23564966

Time-resolved two-window measurement of Wigner functions for coherent backscatter from a turbid medium

NASA Astrophysics Data System (ADS)

Reil, Frank; Thomas, John E.

2002-05-01

For the first time we are able to observe the time-resolved Wigner function of enhanced backscatter from a random medium using a novel two-window technique. This technique enables us to directly verify the phase-conjugating properties of random media. An incident divergent beam displays a convergent enhanced backscatter cone. We measure the joint position and momentum (x, p) distributions of the light field as a function of propagation time in the medium. The two-window technique allows us to independently control the resolutions for position and momentum, thereby surpassing the uncertainty limit associated with Fourier transform pairs. By using a low-coherence light source in a heterodyne detection scheme, we observe enhanced backscattering resolved by path length in the random medium, providing information about the evolution of optical coherence as a function of penetration depth in the random medium.