[Coupling coordination measurement of urbanization and eco-environment system in Huaihe River Basin of China based on fuzzy matter element theory].

PubMed

Guo, Yue-Ting; Xu, Jian-Gang

2013-05-01

Based on the statistical data of urbanization and eco-environment of 35 cities in the Huaihe River Basin of China in 2010, an index system of urbanization-eco-environment system was established by using fuzzy matter element theory, and the weight of each indicator was calculated by entropy method. The improved function of the coupling coordination degree of urbanization and eco-environment was constructed to measure this coupling coordination degree in the Huaihe River Basin. In 2010, the development level of urbanization subsystem in the Basin was lower than that of the eco-environment subsystem, and the integrated coordination index of urbanization and eco-environment was 0.186, indicating that there was a gap between the two types of indicators. The average coupling degree of urbanization and eco-environment was 0.475, indicating that the urbanization-eco-environment system was at antagonistic stage. There was a greater difference in the development level of urbanization subsystem, but a smaller difference in the development level of eco-environment subsystem among the cities. The average value of the coordination degree of all the cities was 0.706, indicating that the Huaihe River Basin was at high coordination coupling stage, and the integrated coherence and synergistic effect of urbanization and eco-environment construction in the Huaihe River Basin was higher.

Open-water and under-ice seasonal variations in trace element content and physicochemical associations in fluvial bed sediment.

PubMed

Doig, Lorne E; Carr, Meghan K; Meissner, Anna G N; Jardine, Tim D; Jones, Paul D; Bharadwaj, Lalita; Lindenschmidt, Karl-Erich

2017-11-01

Across the circumpolar world, intensive anthropogenic activities in the southern reaches of many large, northward-flowing rivers can cause sediment contamination in the downstream depositional environment. The influence of ice cover on concentrations of inorganic contaminants in bed sediment (i.e., sediment quality) is unknown in these rivers, where winter is the dominant season. A geomorphic response unit approach was used to select hydraulically diverse sampling sites across a northern test-case system, the Slave River and delta (Northwest Territories, Canada). Surface sediment samples (top 1 cm) were collected from 6 predefined geomorphic response units (12 sites) to assess the relationships between bed sediment physicochemistry (particle size distribution and total organic carbon content) and trace element content (mercury and 18 other trace elements) during open-water conditions. A subset of sites was resampled under-ice to assess the influence of season on these relationships and on total trace element content. Concentrations of the majority of trace elements were strongly correlated with percent fines and proxies for grain size (aluminum and iron), with similar trace element grain size/grain size proxy relationships between seasons. However, finer materials were deposited under ice with associated increases in sediment total organic carbon content and the concentrations of most trace elements investigated. The geomorphic response unit approach was effective at identifying diverse hydrological environments for sampling prior to field operations. Our data demonstrate the need for under-ice sampling to confirm year-round consistency in trace element-geochemical relationships in fluvial systems and to define the upper extremes of these relationships. Whether contaminated or not, under-ice bed sediment can represent a "worst-case" scenario in terms of trace element concentrations and exposure for sediment-associated organisms in northern fluvial systems. Environ Toxicol Chem 2017;36:2916-2924. © 2017 SETAC. © 2017 SETAC.

Analysis of river health variation under the background of urbanization based on entropy weight and matter-element model: A case study in Huzhou City in the Yangtze River Delta, China.

PubMed

Pan, Guangbo; Xu, Youpeng; Yu, Zhihui; Song, Song; Zhang, Yuan

2015-05-01

Maintaining the health of the river ecosystem is an essential ecological and environmental guarantee for regional sustainable development and one of the basic objectives in water resource management. With the rapid development of urbanization, the river health situation is deteriorating, especially in urban areas. The river health evaluation is a complex process that involves various natural and social components; eight eco-hydrological indicators were selected to establish an evaluation system, and the variation of river health status under the background of urbanization was explored based on entropy weight and matter-element model. The comprehensive correlative degrees of urban river health of Huzhou City in 2001, 2006 and 2010 were then calculated. The results indicated that river health status of the study area was in the direction of pathological trend, and the impact of limiting factors (such as Shannon's diversity index and agroforestry output growth rate) played an important role in river health. The variation of maximum correlative degree could be classified into stationary status, deterioration status, deterioration-to-improvement status, and improvement-to-deterioration status. There was a severe deterioration situation of river health under the background of urbanization. Copyright © 2015 Elsevier Inc. All rights reserved.

Dissolved and colloidal trace elements in the Mississippi River Delta outflow after Hurricanes Katrina and Rita

USGS Publications Warehouse

Shim, Moo-Joon; Swarzenski, Peter W.; Shiller, Alan M.

2012-01-01

The Mississippi River delta outflow region is periodically disturbed by tropical weather systems including major hurricanes, which can terminate seasonal bottom water hypoxia and cause the resuspension of shelf bottom sediments which could result in the injection of trace elements into the water column. In the summer of 2005, Hurricanes Katrina and Rita passed over the Louisiana Shelf within a month of each other. Three weeks after Rita, we collected water samples in the Mississippi River delta outflow, examining the distributions of trace elements to study the effect of Hurricanes Katrina and Rita. We observed limited stratification on the shelf and bottom waters that were no longer hypoxic. This resulted, for instance, in bottom water dissolved Mn being lower than is typically observed during hypoxia, but with concentrations still compatible with Mn–O2 trends previously reported. Interestingly, for no element were we able to identify an obvious effect of sediment resuspension on its distribution. In general, elemental distributions were compatible with previous observations in the Mississippi outflow system. Co and Re, which have not been reported for this system previously, showed behavior consistent with other systems: input for Co likely from desorption and conservative mixing for Re. For Cs, an element for which there is little information regarding its estuarine behavior, conservative mixing was also observed. Our filtration method, which allowed us to distinguish the dissolved (<0.02 μm) from colloidal (0.02–0.45 μm) phase, revealed significant colloidal fractions for Fe and Zn, only. For Fe, the colloidal phase was the dominant fraction and was rapidly removed at low salinity. Dissolved Fe, in contrast, persisted out to mid-salinities, being removed in a similar fashion to nitrate. This ability to distinguish the smaller Fe (likely dominantly organically complexed) from larger colloidal suspensates may be useful in better interpreting the bioavailablity of the Fe in estuarine systems.

Dissolved and colloidal trace elements in the Mississippi River delta outflow after Hurricanes Katrina and Rita

NASA Astrophysics Data System (ADS)

Shim, Moo-Joon; Swarzenski, Peter W.; Shiller, Alan M.

2012-07-01

The Mississippi River delta outflow region is periodically disturbed by tropical weather systems including major hurricanes, which can terminate seasonal bottom water hypoxia and cause the resuspension of shelf bottom sediments which could result in the injection of trace elements into the water column. In the summer of 2005, Hurricanes Katrina and Rita passed over the Louisiana Shelf within a month of each other. Three weeks after Rita, we collected water samples in the Mississippi River delta outflow, examining the distributions of trace elements to study the effect of Hurricanes Katrina and Rita. We observed limited stratification on the shelf and bottom waters that were no longer hypoxic. This resulted, for instance, in bottom water dissolved Mn being lower than is typically observed during hypoxia, but with concentrations still compatible with Mn-O2 trends previously reported. Interestingly, for no element were we able to identify an obvious effect of sediment resuspension on its distribution. In general, elemental distributions were compatible with previous observations in the Mississippi outflow system. Co and Re, which have not been reported for this system previously, showed behavior consistent with other systems: input for Co likely from desorption and conservative mixing for Re. For Cs, an element for which there is little information regarding its estuarine behavior, conservative mixing was also observed. Our filtration method, which allowed us to distinguish the dissolved (<0.02 μm) from colloidal (0.02-0.45 μm) phase, revealed significant colloidal fractions for Fe and Zn, only. For Fe, the colloidal phase was the dominant fraction and was rapidly removed at low salinity. Dissolved Fe, in contrast, persisted out to mid-salinities, being removed in a similar fashion to nitrate. This ability to distinguish the smaller Fe (likely dominantly organically complexed) from larger colloidal suspensates may be useful in better interpreting the bioavailablity of the Fe in estuarine systems.

Geochemistry of organic carbon and trace elements in boreal stratified lakes during different seasons

NASA Astrophysics Data System (ADS)

Moreva, O. Y.; Pokrovsky, O. S.; Shirokova, L. S.; Viers, J.

2008-12-01

Our knowledge of chemical fluxes in the system rock-soils-rivers-ocean of boreal and glacial landscapes is limited by the least studied part, i.e., the river water transformation between the lake and the river systems. Dissolved organic carbon (DOC), nutrients, major and trace elements are being leached from soil profile to the river but subjected to chemical transformation in the lakes due to phytoplankton and bacterial activity. As a result, many lakes in boreal regions are quite different in chemical composition compared to surrounding rivers and demonstrate important chemical stratification. The main processes responsible for chemical stratification in lakes are considered to be i) diffusion fluxes from the sediment to the bottom water accompanied by sulfate reduction and methanogenesis in the sediments and ii) dissolution/mineralization of precipitating organic matter (mineral fraction, detritus, plankton pellets) in the bottom layer horizons under anoxic conditions. Up to present time, distinguishing between two processes remains difficult. This paper is aimed at filling this gap via detailed geochemical analysis of DOC and trace elements in the water column profiles of three typical stratified lakes of Arkhangelsk region in Kenozersky National Parc (64° N) in winter (glacial) and in summer period. Concentration of most trace elements (Li, B, Al, Ti, V, Cr, Ni, Co, Zn, As, Rb, Sr, Y, Zr, Mo, Sb, Ba, REEs, Th, U) are not subjected to strong variations along the water column, despite the presence of strong or partial redox stratification. Apparently, these elements are not significantly controlled by production/mineralization processes and redox phenomena in the water column, or the influence of these processes is not pronounced under the control by the allochtonous river water input. In particularly, the stability of titanium and aluminum concentration along the depth profile and their independence of iron behavior suggest the important control by dissolved organic matter. Therefore, organo-ferric colloids controlling petrogenic elements speciation in soil and river waters are being replaced by autochthonous organic colloids in the lake system. The same observation is true for some heavy metals such as nickel, copper and zinc, whereas cobalt, as limiting component, is being strongly removed from the photic zone or it is coprecipitating with manganese hydroxide. Results of the present work allow quantitative evaluation of the role of redox processes in the bottom horizons and organic detritus degradation in the creation of chemical stratification of small lakes with high DOC concentration. Further insights on geochemical migration of trace elements in lakes require : i) study of colloidal speciation using in-situ dialysis; ii) monitoring the annual and seasonal dynamics of redox processes and TE concentration variation along the profile; iii) quantitative assessment of bacterial degradation of suspended OM and Mn and Fe redox reactions along the depth profile; iv) setting the sedimentary traps for evaluation of suspended material fluxes, and, v) thorough study of chemical composition of interstitial pore waters.

Metals geochemistry and mass export from the Mississippi-Atchafalaya River system to the Northern Gulf of Mexico.

PubMed

Reiman, Jeremy H; Xu, Y Jun; He, Songjie; DelDuco, Emily M

2018-08-01

Discharging 680 km 3 of freshwater annually to the Northern Gulf of Mexico (NGOM), the Mississippi-Atchafalaya River System (MARS) plays a significant role in transporting major and trace elements to the ocean. In this study, we analyzed total recoverable concentrations of thirty-one metals from water samples collected at five locations along the MARS during 2013-2016 to quantify their seasonal mass exports. The Atchafalaya River flows through a large swamp floodplain, allowing us to also test the hypothesis that floodplains function as a sink for metals. We found that the seven major elements (Ca, Na, Mg, Si, K, Al, and Fe) constituted 99% of the total annual mass load of metals (7.38 × 10 7 tons) from the MARS. Higher concentrations of Al, Ba, B, Ca, Fe, Mg, Mn, Ag, and Ti were found in the Mississippi River, while significantly higher Si and Na concentrations were found in the Atchafalaya River. Significant relationships were found between daily discharge and daily loads of Ba, Ca, Fe, K, Sr, and Ti in both rivers, while significant relationships were also found for Al, Mg, Mn, V, and Zn in the Atchafalaya River and B in the Mississippi River. Overall, the Mississippi River contributed 64-76% of the total annual loading of metals from the MARS to the NGOM. Daily loads of Al, Ba, B, Fe, Li, Mn, P, K, Si, Ag, Ti, V, and Zn regularly decreased upstream to downstream in the Atchafalaya River, partially accepting the initial hypothesis on metals transport in river floodplains. Copyright © 2018 Elsevier Ltd. All rights reserved.

Assessment of trace element impacts on agricultural use of water from the Dan River following the Eden coal ash release.

PubMed

Hesterberg, Dean; Polizzotto, Matthew L; Crozier, Carl; Austin, Robert E

2016-04-01

Catastrophic events require rapid, scientifically sound decision making to mitigate impacts on human welfare and the environment. The objective of this study was to analyze potential impacts of coal ash-derived trace elements on agriculture following a 35,000-tonne release of coal ash into the Dan River at the Duke Energy Steam Station in Eden, North Carolina. We performed scenario calculations to assess the potential for excessive trace element loading to soils via irrigation and flooding with Dan River water, uptake of trace elements by crops, and livestock consumption of trace elements via drinking water. Concentrations of 13 trace elements measured in Dan River water samples within 4 km of the release site declined sharply after the release and were equivalent within 5 d to measurements taken upriver. Mass-balance calculations based on estimates of soil trace-element concentrations and the nominal river water concentrations indicated that irrigation or flooding with 25 cm of Dan River water would increase soil concentrations of all trace elements by less than 0.5%. Calculations of potential increases of trace elements in corn grain and silage, fescue, and tobacco leaves suggested that As, Cr, Se, Sr, and V were elements of most concern. Concentrations of trace elements measured in river water following the ash release never exceeded adopted standards for livestock drinking water. Based on our analyses, we present guidelines for safe usage of Dan River water to diminish negative impacts of trace elements on soils and crop production. In general, the approach we describe here may serve as a basis for rapid assessment of environmental and agricultural risks associated with any similar types of releases that arise in the future. © 2015 SETAC.

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia; a summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

USGS Publications Warehouse

Skrobialowski, S.C.

1996-01-01

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

Hydraulic modeling of riverbank filtration systems with curved boundaries using analytic elements and series solutions

NASA Astrophysics Data System (ADS)

Bakker, Mark

2010-08-01

A new analytic solution approach is presented for the modeling of steady flow to pumping wells near rivers in strip aquifers; all boundaries of the river and strip aquifer may be curved. The river penetrates the aquifer only partially and has a leaky stream bed. The water level in the river may vary spatially. Flow in the aquifer below the river is semi-confined while flow in the aquifer adjacent to the river is confined or unconfined and may be subject to areal recharge. Analytic solutions are obtained through superposition of analytic elements and Fourier series. Boundary conditions are specified at collocation points along the boundaries. The number of collocation points is larger than the number of coefficients in the Fourier series and a solution is obtained in the least squares sense. The solution is analytic while boundary conditions are met approximately. Very accurate solutions are obtained when enough terms are used in the series. Several examples are presented for domains with straight and curved boundaries, including a well pumping near a meandering river with a varying water level. The area of the river bottom where water infiltrates into the aquifer is delineated and the fraction of river water in the well water is computed for several cases.

87Sr/86Sr and 143Nd/144Nd for disentangling anthropogenic and natural REE contributions in river water during flood events.

NASA Astrophysics Data System (ADS)

Hissler, Christophe; Stille, Peter; Pfister, Laurent

2017-04-01

The sustainable management of water resources is one of the greatest challenges of the 21st century. Water is a vital resource that is increasingly put under pressure from multiple perspectives. While the global population is on the rise, socio-economic development makes equally rapid progress - eventually compromising access to clean water bodies. Multiple pollution sources constitute an immediate threat to aquatic ecosystems and are likely to cause long lasting contaminations of water bodies that are critical for drinking and/or irrigation water production. There is a pressing need for an adequate quantification of anthropogenic impacts on the critical zone of river basins and the identification of the temporal dynamics of these impacts. As an example, despite the work done to assess the environmental impact of REE pollutions in larger river systems, we are still lacking information on the dynamics of these anthropogenic compounds in relation to rapid hydrological changes. Filling these knowledge gaps is a pre-requisite for the design and implementation of sustainable water resources management strategies. In order to better constrain the relative contributions of both anthropogenic and geogenic trace element sources we propose using a multitracer approach combining elemental and 87Sr/86Sr, 143Nd/144Nd, and 206Pb/207Pb isotopic ratios. The use of these three separate isotopic systems together with REE concentrations is new in the field of anthropogenic source identification in river systems. We observed enrichments in Anthropogenic Rare Earth Elements (AREE) for dissolved Gd and suspended Nd loads of river water. With increasing discharge, AREE anomalies progressively disappeared and gave way to the geogenic chemical signature of the basin in both dissolved and suspended loads. The isotopic data confirm these observations and shed new light on the trace elements sources. On the one hand, dissolved loads have peculiar isotopic characteristics and carry mainly limestone-derived and anthropogenic Sr and Nd as well as significant amounts of anthropogenic Pb. On the other hand, the results clearly indicate that anthropogenic contributions impact the suspended loads in all hydrological conditions. This study demonstrates that (i) the composition of the AREE pool is characteristic of a given river basin and controlled by the different anthropogenic contributions located in a specific study area and (ii) the anthropogenic contributions to the river may change not only Pb, but also Sr and Nd isotopic compositions in both dissolved and suspended loads. This is of importance for future provenance studies in the critical zone of polluted river basins.

General classification handbook for floodplain vegetation in large river systems

USGS Publications Warehouse

Dieck, Jennifer J.; Ruhser, Janis; Hoy, Erin E.; Robinson, Larry R.

2015-01-01

This handbook describes the General Wetland Vegetation Classification System developed as part of the U.S. Army Corps of Engineers’ Upper Mississippi River Restoration (UMRR) Program, Long Term Resource Monitoring (LTRM) element. The UMRR is a cooperative effort between the U.S. Army Corps of Engineers, U.S. Geological Survey, U.S. Fish and Wildlife Service, and the states of Illinois, Iowa, Minnesota, Missouri, and Wisconsin. The classification system consists of 31 general map classes and has been used to create systemic vegetation data layers throughout the diverse Upper Mississippi River System (UMRS), which includes the commercially navigable reaches of the Mississippi River from Minneapolis, Minnesota, in the north to Cairo, Illinois, in the south, the Illinois River, and navigable portions of the Kaskaskia, Black, St. Croix, and Minnesota Rivers. In addition, this handbook describes the evolution of the General Wetland Vegetation Classification System, discusses the process of creating a vegetation data layer, and describes each of the 31 map classes in detail. The handbook also acts as a pictorial guide to each of the map classes as they may appear in the field, as well as on color-infrared imagery. This version is an update to the original handbook published in 2004.

Determination of metal-based nanoparticles in the river Dommel in the Netherlands via ultrafiltration, HR-ICP-MS and SEM.

PubMed

Markus, A A; Krystek, P; Tromp, P C; Parsons, J R; Roex, E W M; Voogt, P de; Laane, R W P M

2018-08-01

We investigated the occurrence of metal-based nanoparticles in a natural system, the river Dommel in the Netherlands. The river itself is well-studied as far as hydrology and water quality is concerned, easily accessible and contains one major wastewater treatment plant discharging onto this river. We sampled water from various locations along the river and collected samples of influent, effluent and sewage sludge from the wastewater treatment plant. The sampling campaign was carried out in June 2015 and these samples were analysed for seven elements using high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS), ultrafiltration with a sequence of mesh sizes and scanning electron microscopy (SEM). From the results we conclude that there are indeed nanoparticles present in the treatment plant we studied, as we found titanium and gold particles in the influent and effluent. In the river water only 10 to 20% of the mass concentration of titanium, cerium and other elements we examined is made up of free, i.e. unattached, particles with a size smaller than 20 nm or of dissolved material. The rest is attached to natural colloids or is present as individual particles or clusters of smaller particles, as it could be filtered out with 450 nm ultrafilters. We found evidence that there is no appreciable anthropogenic emission of cerium into the river, based on the geochemical relationship between cerium and lanthanum. Besides, the effluent of the treatment plant has lower concentrations of some examined elements than the surface water upstream. The treatment plant discharges much less of these elements than estimated using previous publications. However, a potential diffuse source of titanium dioxide in the form of nanoparticles or of larger particles is their use in paints and coatings, as the concentration of titanium increased considerably in the urbanised area of the river Dommel. Copyright © 2018 Elsevier B.V. All rights reserved.

The influence of colloids on the geochemical behavior of metals in polluted water using as an example Yongdingxin River, Tianjin, China.

PubMed

Ren, Huimin; Liu, Huijuan; Qu, Jiuhui; Berg, Michael; Qi, Weixiao; Xu, Wei

2010-01-01

The role of colloids in estuarine and marine systems has been studied extensively in recent years, whereas less is known about the polluted freshwater system. Yongdingxin River is one of the major recipients of industrial effluents in Tianjin. This article evaluates the role of colloids in controlling geochemical behavior of Cu, Zn, Fe, Mn, Hg and Cr at the confluences between Yongdingxin River and its major tributaries Beijing Drainage River, Jinzhong River and Beitang Drainage River. Based on the distribution of metal partitioning among particulate (>0.22mum), colloidal (1kDa to 0.22mum) and truly dissolved (<1kDa) fractions, the metals can be assigned to the following groups: Group 1 - organic colloidal pool-borne elements Cu and Cr; Group 2 - inorganic colloidal pool-borne metals Fe and Mn; Group 3 - Zn and Hg characterized by varying complexation patterns. The distribution of metal partitioning among particulate, colloidal and truly dissolved fractions was influenced by anthropogenic input. In addition, the theoretical concentrations of elements in case of conservative mixing between the waters of Yongdingxin River and the waters of its tributaries were compared with the measured values to evaluate the geochemical role of colloids. The result showed that all of the metals presented a non-conservative mixing behavior. Addition of colloids resulted in the removal of metals from the water column to bed sediment during river water mixing, which was furthermore confirmed by the similar partition coefficient of metal concentration between colloid and sediment. Copyright 2009 Elsevier Ltd. All rights reserved.

From academic to applied: Operationalising resilience in river systems

NASA Astrophysics Data System (ADS)

Parsons, Melissa; Thoms, Martin C.

2018-03-01

The concept of resilience acknowledges the ability of societies to live and develop with dynamic environments. Given the recognition of the need to prepare for anticipated and unanticipated shocks, applications of resilience are increasing as the guiding principle of public policy and programs in areas such as disaster management, urban planning, natural resource management, and climate change adaptation. River science is an area in which the adoption of resilience is increasing, leading to the proposition that resilience may become a guiding principle of river policy and programs. Debate about the role of resilience in rivers is part of the scientific method, but disciplinary disunity about the ways to approach resilience application in policy and programs may leave river science out of the policy process. We propose six elements that need to be considered in the design and implementation of resilience-based river policy and programs: rivers as social-ecological systems; the science-policy interface; principles, capacities, and characteristics of resilience; cogeneration of knowledge; adaptive management; and the state of the science of resilience.

Grain-size distribution and selected major and trace element concentrations in bed-sediment cores from the Lower Granite Reservoir and Snake and Clearwater Rivers, eastern Washington and northern Idaho, 2010

USGS Publications Warehouse

Braun, Christopher L.; Wilson, Jennifer T.; Van Metre, Peter C.; Weakland, Rhonda J.; Fosness, Ryan L.; Williams, Marshall L.

2012-01-01

Fifty subsamples from 15 cores were analyzed for major and trace elements. Concentrations of trace elements were low, with respect to sediment quality guidelines, in most cores. Typically, major and trace element concentrations were lower in the subsamples collected from the Snake River compared to those collected from the Clearwater River, the confluence of the Snake and Clearwater Rivers, and Lower Granite Reservoir. Generally, lower concentrations of major and trace elements were associated with coarser sediments (larger than 0.0625 millimeter) and higher concentrations of major and trace elements were associated with finer sediments (smaller than 0.0625 millimeter).

Geochemical loading of suspended sediment carried by large monsoonal rivers in Burma

NASA Astrophysics Data System (ADS)

Robinson, R. A.; Tipper, E.; Bird, M. I.; Oo, N.

2013-12-01

The Irrawaddy and Salween rivers of Burma drain the most rapidly exhuming region in the Himalayas, the eastern syntaxis zone. These monsoonal rivers have catchment areas of 0.413 x 106 km2 and 0.272 x 106 km2, respectively, and approximately 95% of the Irrawaddy catchment lies within Burma, while the catchment of the Salween flows through China, Thailand and Burma. They are long rivers (~2000 and ~2800 km) which have steep and narrow bedrock gorges along much of their length, and different amounts of floodplain in their lower reaches. These rivers have been less studied than other large Asian systems because of political instability in Burma and restricted access. Based on available historical data, and field work in 2005-2008, Robinson et al. (2007) estimated that the Irrawaddy is likely to be the 3rd largest river globally in terms of sediment load and when the Irrawaddy and Salween estimated fluxes are combined, they together contribute 4.6 Mt/yr of particulate organic carbon (POC) and an additional 1.1Mt/yr of dissolved organic carbon (DOC) to the ocean. When estimated yields of total organic carbon are calculated, the Irrawaddy-Salween system ranks alongside the Amazon as one of the largest yields of organic carbon, and is higher than the yield for the Ganges-Brahmaptura (Bird et al., 2008). Here we present preliminary geochemical data for water and sediment from the Irrawaddy and Salween rivers, and demonstrate the variability in elemental concentrations of water between the rivers and the summer and winter monsoon seasons, and differences in suspended sediment geochemistry as a function of water depth. The variability and magnitude of weathering products carried by such significant systems need to be quantified in order to understand their contribution to global element cycling (Tipper et al., 2006) and sedimentary depocentres. Our data highlight that further study of the geochemistry of such large rivers will significantly improve our understanding of the processes controlling the transport of elements (including carbon) within the fluvial system and their export from land to the ocean, the degree of chemical weathering that occurs during transport, and how the sedimentary geochemistry of depocentres might be better interrogated to understand their record of chemical weathering and relationship to source and transport history. References Bird M.I., Robinson R.A.J., et al. (2008) A preliminary estimate of organic carbon transport by the Ayerawady (Irrawaddy) and Thanlwin (Salween) Rivers of Myanmar. Quaternary International, 186, 113-22. Robinson, R.A.J., Bird, M.I. et al. (2007) The Ayeyarwady River sediment budget to the Indian Ocean: the original 19th Century data revisited. Journal of Geology, 115, doi:10.1086/521607. Tipper E.T. et al. (2006) The short term climatic sensitivity of carbonate and silicate weathering fluxes: Insight from seasonal variations in river chemistry. Geochim. Cosmochim. Act. doi:10.1016/j.gca.2006.03.005.

Geochemistry of bed and suspended sediment in the Mississippi river system: provenance versus weathering and winnowing.

PubMed

Piper, D Z; Ludington, Steve; Duval, J S; Taylor, H E

2006-06-01

Stream-bed sediment for the size fraction less than 150 microm, examined in 14,000 samples collected mostly from minor tributaries to the major rivers throughout the Mississippi River drainage system, is composed of 5 mineral fractions identified by factor analysis-Al-silicate minerals, quartz, calcite and dolomite, heavy minerals, and an Fe-Mn fraction. The Al-silicate fraction parallels its distribution in the regolith, emphasizing the local sediment source as a primary control to its distribution. Quartz and the heavy-mineral fraction, and associated trace elements, exhibit a complementary distribution to that of the Al-silicate fraction, with a level of enrichment in the bed sediment that is achieved through winnowing and sorting. The carbonate fraction has a distribution suggesting its dissolution during transport. Trace elements partitioned onto the Fe-Mn, possibly amorphous oxyhydride, fraction are introduced to the streams, in part, through human activity. Except for the heavy-mineral fraction, these fractions are identified in suspended sediment from the Mississippi River itself. Although comparison of the tributary bed sediment with the riverine suspended sediment is problematic, the geochemistry of the suspended sediment seems to corroborate the interpretation of the geochemistry of the bed sediment.

Geochemistry of bed and suspended sediment in the Mississippi river system: Provenance versus weathering and winnowing

USGS Publications Warehouse

Piper, D.Z.; Ludington, S.; Duval, J.S.; Taylor, Howard E.

2006-01-01

Stream-bed sediment for the size fraction less than 150 ??m, examined in 14,000 samples collected mostly from minor tributaries to the major rivers throughout the Mississippi River drainage system, is composed of 5 mineral fractions identified by factor analysis-Al-silicate minerals, quartz, calcite and dolomite, heavy minerals, and an Fe-Mn fraction. The Al-silicate fraction parallels its distribution in the regolith, emphasizing the local sediment source as a primary control to its distribution. Quartz and the heavy-mineral fraction, and associated trace elements, exhibit a complementary distribution to that of the Al-silicate fraction, with a level of enrichment in the bed sediment that is achieved through winnowing and sorting. The carbonate fraction has a distribution suggesting its dissolution during transport. Trace elements partitioned onto the Fe-Mn, possibly amorphous oxyhydride, fraction are introduced to the streams, in part, through human activity. Except for the heavy-mineral fraction, these fractions are identified in suspended sediment from the Mississippi River itself. Although comparison of the tributary bed sediment with the riverine suspended sediment is problematic, the geochemistry of the suspended sediment seems to corroborate the interpretation of the geochemistry of the bed sediment.

Trace element transport in western Siberian rivers across a permafrost gradient

NASA Astrophysics Data System (ADS)

Pokrovsky, Oleg S.; Manasypov, Rinat M.; Loiko, Sergey V.; Krickov, Ivan A.; Kopysov, Sergey G.; Kolesnichenko, Larisa G.; Vorobyev, Sergey N.; Kirpotin, Sergey N.

2016-03-01

Towards a better understanding of trace element (TE) transport in permafrost-affected Earth surface environments, we sampled ˜ 60 large and small rivers (< 100 to ≤ 150 000 km2 watershed area) of the Western Siberian Lowland (WSL) during spring flood and summer and winter baseflow across a 1500 km latitudinal gradient covering continuous, discontinuous, sporadic and permafrost-free zones. Analysis of ˜ 40 major and TEs in the dissolved (< 0.45 µm) fraction allowed establishing main environmental factors controlling the transport of metals and TEs in rivers of this environmentally important region. No statistically significant effect of the basin size on most TE concentrations was evidenced. Two groups of elements were distinguished: (1) elements that show the same trend throughout the year and (2) elements that show seasonal differences. The first group included elements decreasing northward during all seasons (Sr, Mo, U, As, Sb) marking the underground water influence of river feeding. The elements of the second group exhibited variable behavior in the course of the year. A northward increase during spring period was mostly pronounced for Fe, Al, Co, Zn and Ba and may stem from a combination of enhanced leaching from the topsoil and vegetation and bottom waters of the lakes (spring overturn). A springtime northward decrease was observed for Ni, Cu, Zr and Rb. The increase in element concentration northward was observed for Ti, Ga, Zr and Th only in winter, whereas Fe, Al, rare earth elements (REEs), Pb, Zr, and Hf increased northward in both spring and winter, which could be linked to leaching from peat and transport in the form of Fe-rich colloids. A southward increase in summer was strongly visible for Fe, Ni, Ba, Rb and V, probably due to peat/moss release (Ni, Ba, Rb) or groundwater feeding (Fe, V). Finally, B, Li, Cr, V, Mn, Zn, Cd, and Cs did not show any distinct trend from S to N. The order of landscape component impact on TE concentration in rivers was lakes > bogs > forest. The lakes decreased export of Mn and Co in summer and Ni, Cu, and Rb in spring, presumably due to biotic processes. The lakes enriched the rivers in insoluble lithogenic elements in summer and winter, likely due to TE mobilization from unfrozen mineral sediments. The rank of environmental factors on TE concentration in western Siberian rivers was latitude (three permafrost zones) > season > watershed size. The effect of the latitude was minimal in spring for most TEs but highly visible for Sr, Mo, Sb and U. The main factors controlling the shift of river feeding from surface and subsurface flow to deep underground flow in the permafrost-bearing zone were the depth of the active (unfrozen) seasonal layer and its position in organic or mineral horizons of the soil profile. In the permafrost-free zone, the relative role of carbonate mineral-bearing base rock feeding versus bog water feeding determined the pattern of TE concentration and fluxes in rivers of various sizes as a function of season. Comparison of obtained TE fluxes in WSL rivers with those of other subarctic rivers demonstrated reasonable agreement for most TEs; the lithology of base rocks was the major factor controlling the magnitude of TE fluxes. Climate change in western Siberia and permafrost boundary migration will essentially affect the elements controlled by underground water feeding (DIC, alkaline earth elements (Ca, Sr), oxyanions (Mo, Sb, As) and U). The thickening of the active layer may increase the export of trivalent and tetravalent hydrolysates in the form of organo-ferric colloids. Plant litter-originated divalent metals present as organic complexes may be retained via adsorption on mineral horizon. However, due to various counterbalanced processes controlling element source and sinks in plant-peat-mineral soil-river systems, the overall impact of the permafrost thaw on TE export from the land to the ocean may be smaller than that foreseen with merely active layer thickening and permafrost boundary shift.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dupre, B.; Rousseau, D.; Gaillardet, J.

The Congo river Basin is the second largest drainage basin in the world, after the Amazon. The materials carried by its main rivers provide the opportunity to study the products of denudation of a large fraction of the upper continental crust of the African continent. This paper presents the chemical composition of the different phases carried in the Congo rivers and is followed by a companion paper, devoted to the modelling of major and trace elements. The Congo river between Bangui and Brazzaville as well as its main tributaries, including a few organic-rich rivers, also called Black Rivers, were sampledmore » during the 1989 high water stage. The three main phases (suspended load, dissolved load, and bedload) were analysed for twenty-five major and trace elements. Concentrations normalized to the upper continental crust show that in each river, suspended sediments and dissolved load are chemical complements for the most soluble elements (Ca, Na, Sr, K, Ba, Rb, and U). While these elements are enriched in the dissolved loads, they are considerably depleted in the corresponding suspended sediments. This is consistent with their high mobility during weathering. Another type of complementarity is observed for Zr and Hf between suspended sediments and bedload, related to the differential velocity of suspended sediments and zircons which are concentrated in bedloads. Compared to other rivers, absolute dissolved concentrations of Ca, Na, Sr, K, Ba, Rb, and U are remarkably low. Surprisingly, high dissolved concentrations are found in the Congo waters for other trace elements (e.g., REEs), especially in the Black rivers. On a world scale, these concentrations are among the highest measured in rivers and are shown to be pH dependent for a number of dissolved trace elements. The dissolved loads are systematically normalized to the suspended loads for each river, in order to remove the variations of the element abundances owing to source rock variations.« less

Element geochemical analysis of the contribution of aeolian sand to suspended sediment in desert stream flash floods.

PubMed

Jia, Xiaopeng; Wang, Haibing

2014-01-01

The interaction of wind and water in semiarid and arid areas usually leads to low-frequency flash flood events in desert rivers, which have adverse effects on river systems and ecology. In arid zones, many aeolian dune-fields terminate in stream channels and deliver aeolian sand to the channels. Although aeolian processes are common to many desert rivers, whether the aeolian processes contribute to fluvial sediment loss is still unknown. Here, we identified the aeolian-fluvial cycling process responsible for the high rate of suspended sediment transport in the Sudalaer desert stream in the Ordos plateau of China. On the basis of element geochemistry data analysis, we found that aeolian sand was similar to suspended sediment in element composition, which suggests that aeolian sand contributes to suspended sediment in flash floods. Scatter plots of some elements further confirm that aeolian sand is the major source of the suspended sediment. Factor analysis and the relation between some elements and suspended sediment concentration prove that the greater the aeolian process, the higher the suspended sediment concentration and the greater the contribution of aeolian sand to suspended sediment yield. We conclude that aeolian sand is the greatest contributor to flash floods in the Sudalaer desert stream.

Element Geochemical Analysis of the Contribution of Aeolian Sand to Suspended Sediment in Desert Stream Flash Floods

PubMed Central

Wang, Haibing

2014-01-01

The interaction of wind and water in semiarid and arid areas usually leads to low-frequency flash flood events in desert rivers, which have adverse effects on river systems and ecology. In arid zones, many aeolian dune-fields terminate in stream channels and deliver aeolian sand to the channels. Although aeolian processes are common to many desert rivers, whether the aeolian processes contribute to fluvial sediment loss is still unknown. Here, we identified the aeolian-fluvial cycling process responsible for the high rate of suspended sediment transport in the Sudalaer desert stream in the Ordos plateau of China. On the basis of element geochemistry data analysis, we found that aeolian sand was similar to suspended sediment in element composition, which suggests that aeolian sand contributes to suspended sediment in flash floods. Scatter plots of some elements further confirm that aeolian sand is the major source of the suspended sediment. Factor analysis and the relation between some elements and suspended sediment concentration prove that the greater the aeolian process, the higher the suspended sediment concentration and the greater the contribution of aeolian sand to suspended sediment yield. We conclude that aeolian sand is the greatest contributor to flash floods in the Sudalaer desert stream. PMID:25089295

Source apportionment of heavy metals and their ecological risk in a tropical river basin system.

PubMed

Kumar, Balwant; Singh, Umesh Kumar

2018-06-27

Surface water and sediment samples were collected from Ajay River basin to appraise the behavior of heavy metals with surrounding environments and their inter-elemental relationships. Parameters like pH and organic carbon are having a minimal role in heavy metal distribution while some elements like Fe and Cu showed great affinity for organic matter based on linear regression analysis (LRA). Ficklin diagram justified that river basin is not contaminated through acidic pollutants. The river basin is highly enriched with Cu, Cd, Pb, and Ni which were much higher than world average values, average shale standard, effect range low (ERL), and threshold effect level (TEL). PCA and LRA verified that Cu, Cd, Pb, and Ni were mainly derived from anthropogenic inputs, and others like Fe, Mn, Zn, and Co came from geogenic sources. Pollution indices revealed that river basin is moderately to highly contaminated by Cu, Cd, and Ni. Furthermore, Ajay River basin is under strong potential ecological risk based on the obtained value of risk index and probable effect level/effect range median quotient index. However, river basin is strongly influenced by lithological properties, diversified hydrogeological settings, mineralization and mobilization of subsurface materials, and urban and industrial effluents which are controlling the heavy metals.

[Variation characteristics and environmental significant of trace elements under rainfall condition in karst groundwater].

PubMed

Chen, Xue-Bin; Yang, Ping-Heng; Lan, Jia-Cheng; Mo, Xue; Shi, Yang

2014-01-01

Chemical dynamics of Qingmuguan karst groundwater system were continuously monitored during the rainfall events. A series of high-resolution concentrations data on trace elements, such as barium, strontium, iron, manganese, aluminum, and other major elements were acquired. Correlation analysis and analysis of concentration curve were employed to identify the sources and migration path of the trace elements. And the formation process of trace elements in groundwater was discussed with the geological background of underground river basin. Research shows that barium and strontium derived from carbonate dissolution appeared to be stored in features such as fissures and pores. These two ions were recharged into the underground river by diffusion during precipitation, which resulted in small changes in the their concentration. However total iron, total manganese and aluminum derived from soil erosion varied relatively widely with strong response to rainfall, attributing to the migration of total iron and aluminum with overland flow to recharge the subterranean river directly via sinkholes while total manganese via soil-rock porous media. The results showed that concentrations of all the five trace elements were below 1 mg x L(-1), and the highest concentrations of total iron, total manganese and aluminum exceeded the limit of drinking water. To some extent, the concentrations of total iron and aluminum may be an indicator for soil erosion and water quality.

Butterfly (Papilionoidea and Hesperioidea) assemblages associated with natural, exotic, and restored riparian habitats along the lower Colorado River, USA

USGS Publications Warehouse

Nelson, S.M.; Andersen, D.C.

1999-01-01

Butterfly assemblages were used to compare revegetated and natural riparian areas along the lower Colorado River. Species richness and correspondence analyses of assemblages showed that revegetated sites had fewer biological elements than more natural sites along the Bill Williams River. Data suggest that revegetated sites do not provide resources needed by some members of the butterfly assemblage, especially those species historically associated with the cottonwood/willow ecosystem. Revegetated sites generally lacked nectar resources, larval host plants, and closed canopies. The riparian system along the regulated river segment that contains these small revegetated sites also appears to have diminished habitat heterogeneity and uncoupled riparian corridors.Revegetated sites were static environments without the successional stages caused by flooding disturbance found in more natural systems. We hypothesize that revegetation coupled with a more natural hydrology is important for restoration of butterfly assemblages along the lower Colorado River. 

Optimal Design of River Monitoring Network in Taizihe River by Matter Element Analysis

PubMed Central

Wang, Hui; Liu, Zhe; Sun, Lina; Luo, Qing

2015-01-01

The objective of this study is to optimize the river monitoring network in Taizihe River, Northeast China. The situation of the network and water characteristics were studied in this work. During this study, water samples were collected once a month during January 2009 - December 2010 from seventeen sites. Futhermore, the 16 monitoring indexes were analyzed in the field and laboratory. The pH value of surface water sample was found to be in the range of 6.83 to 9.31, and the average concentrations of NH4 +-N, chemical oxygen demand (COD), volatile phenol and total phosphorus (TP) were found decreasing significantly. The water quality of the river has been improved from 2009 to 2010. Through the calculation of the data availability and the correlation between adjacent sections, it was found that the present monitoring network was inefficient as well as the optimization was indispensable. In order to improve the situation, the matter element analysis and gravity distance were applied in the optimization of river monitoring network, which were proved to be a useful method to optimize river quality monitoring network. The amount of monitoring sections were cut from 17 to 13 for the monitoring network was more cost-effective after being optimized. The results of this study could be used in developing effective management strategies to improve the environmental quality of Taizihe River. Also, the results show that the proposed model can be effectively used for the optimal design of monitoring networks in river systems. PMID:26023785

A geomorphological characterisation of river systems in South Africa: A case study of the Sabie River

NASA Astrophysics Data System (ADS)

Eze, Peter N.; Knight, Jasper

2018-06-01

Fluvial geomorphology affects river character, behaviour, evolution, trajectory of change and recovery potential, and as such affects biophysical interactions within a catchment. Water bodies in South Africa, in common with many other water-stressed parts of the world, are generally under threat due to increasing natural and anthropogenic influences including aridity, siltation and pollution, as well as climate and environmental change. This study reports on a case study to characterise the geomorphology of different river systems in South Africa, with the aim of better understanding their properties, controls, and implications for biophysical interactions including water quality, biodiversity (aquatic and riparian), and human activity within the catchment. The approach adopted is based on the River Styles® framework (RSF), a geomorphology-based approach developed for rivers in New Zealand and Australia, but applied here for the first time to South Africa. Based on analysis of remote sensing imagery, SRTM-2 digital topographic data and field observations on sites through the entire river system, six geomorphic elements were identified along the Sabie River, northeast South Africa (gorge, bedrock-forced meander, low-moderate sinuosity planform controlled sand bed, meandering sand bed, low sinuosity fine grained sand bed, and floodouts), using the RSF classification scheme and based on the RSF procedural tree of Brierley and Fryirs (2005). Previous geomorphological studies along the Sabie River have shown that different reaches respond differently to episodic floods; we use these data to link river geomorphological character (as defined by the RSF) to the hydrodynamic conditions and processes giving rise to such character. This RSF approach can be used to develop a new management approach for river systems that considers their functional biophysical behaviour within individual reaches, rather than considering them as homogeneous and uniform systems.

Dissolved and Colloidal Trace Elements in the Mississippi River Delta Outflow after Hurricanes Katrina and Rita

NASA Astrophysics Data System (ADS)

Shim, M.; Swarzenski, P. W.; Shiller, A. M.

2010-12-01

The Mississippi River (MR) plays an important role as a major fluvial source of dissolved and particulate materials for the Gulf of Mexico (GOM). This region is periodically disturbed by tropical weather systems including major hurricanes. Such storms have the potential to stir up the normally stratified water column of the Louisiana Shelf and thus can serve as a mechanism for the abrupt termination of seasonal bottom water hypoxia. Additionally, strong tropical systems can cause the resuspension of shelf bottom sediments which could result in the injection of trace elements into the water column. In the summer of 2005, two major hurricanes, Katrina and Rita, passed over the Louisiana Shelf within a month of each other. Three weeks after Rita, we participated in a survey of the waters of the Mississippi River delta outflow, examining the distributions of trace elements (including Ba, Co, Cr, Cs, Cu, Fe, Mn, Ni, Re, U, V, and Zn) in a comparison with previous results in this area. We indeed observed that there was limited stratification on the shelf and that bottom waters were no longer hypoxic. This resulted, for instance, in bottom water dissolved Mn being lower than is typically observed during hypoxia, but with concentrations still compatible with Mn-O2 trends previously reported. Interestingly, for no element were we able to identify an obvious effect of sediment resuspension on its distribution. In general, elemental distributions were compatible with previous observations in the Mississippi outflow system. Co and Re, which have not been reported for this system previously, showed behavior consistent with other systems: input for Co likely from desorption and conservative mixing for Re. For Cs, an element for which there is little information regarding its estuarine behavior, conservative mixing was also observed. Our filtration method, which allowed us to distinguish the dissolved (<0.02 µm) from colloidal (0.02 - 0.45 µm) phase, revealed significant colloidal fractions for Fe and Zn, only. For Fe, the colloidal phase was the dominant fraction and was rapidly removed at low salinity. Dissolved Fe, in contrast, persisted out to mid-salinities, being removed in a similar fashion to nitrate. This ability to distinguish the smaller Fe (likely dominantly organically complexed) from larger colloidal suspensates may be useful in better interpreting the bioavailablity of the Fe in estuarine systems.

Potential Effects of Hydroelectric Dam Development in the Mekong River Basin on the Migration of Siamese Mud Carp (Henicorhynchus siamensis and H. lobatus) Elucidated by Otolith Microchemistry

PubMed Central

Fukushima, Michio; Jutagate, Tuantong; Grudpan, Chaiwut; Phomikong, Pisit; Nohara, Seiichi

2014-01-01

The migration of Siamese mud carp (Henicorhynchus siamensis and H. lobatus), two of the most economically important fish species in the Mekong River, was studied using an otolith microchemistry technique. Fish and river water samples were collected in seven regions throughout the whole basin in Thailand, Laos and Cambodia over a 4 year study period. There was coherence between the elements in the ambient water and on the surface of the otoliths, with strontium (Sr) and barium (Ba) showing the strongest correlation. The partition coefficients were 0.409–0.496 for Sr and 0.055 for Ba. Otolith Sr-Ba profiles indicated extensive synchronized migrations with similar natal origins among individuals within the same region. H. siamensis movement has been severely suppressed in a tributary system where a series of irrigation dams has blocked their migration. H. lobatus collected both below and above the Khone Falls in the mainstream Mekong exhibited statistically different otolith surface elemental signatures but similar core elemental signatures. This result suggests a population originating from a single natal origin but bypassing the waterfalls through a passable side channel where a major hydroelectric dam is planned. The potential effects of damming in the Mekong River are discussed. PMID:25099147

Applying of Factor Analyses for Determination of Trace Elements Distribution in Water from River Vardar and Its Tributaries, Macedonia/Greece

PubMed Central

Popov, Stanko Ilić; Stafilov, Trajče; Šajn, Robert; Tănăselia, Claudiu; Bačeva, Katerina

2014-01-01

A systematic study was carried out to investigate the distribution of fifty-six elements in the water samples from river Vardar (Republic of Macedonia and Greece) and its major tributaries. The samples were collected from 27 sampling sites. Analyses were performed by mass spectrometry with inductively coupled plasma (ICP-MS) and atomic emission spectrometry with inductively coupled plasma (ICP-AES). Cluster and R mode factor analysis (FA) was used to identify and characterise element associations and four associations of elements were determined by the method of multivariate statistics. Three factors represent the associations of elements that occur in the river water naturally while Factor 3 represents an anthropogenic association of the elements (Cd, Ga, In, Pb, Re, Tl, Cu, and Zn) introduced in the river waters from the waste waters from the mining and metallurgical activities in the country. PMID:24587756

Biological and land use controls on the isotopic composition of aquatic carbon in the Upper Mississippi River Basin

NASA Astrophysics Data System (ADS)

Voss, Britta M.; Wickland, Kimberly P.; Aiken, George R.; Striegl, Robert G.

2017-08-01

Riverine ecosystems receive organic matter (OM) from terrestrial sources, internally produce new OM, and biogeochemically cycle and modify organic and inorganic carbon. Major gaps remain in the understanding of the relationships between carbon sources and processing in river systems. Here we synthesize isotopic, elemental, and molecular properties of dissolved organic carbon (DOC), particulate organic carbon (POC), and dissolved inorganic carbon (DIC) in the Upper Mississippi River (UMR) system above Wabasha, MN, including the main stem Mississippi River and its four major tributaries (Minnesota, upper Mississippi, St. Croix, and Chippewa Rivers). Our goal was to elucidate how biological processing modifies the chemical and isotopic composition of aquatic carbon pools during transport downstream in a large river system with natural and man-made impoundments. Relationships between land cover and DOC carbon-isotope composition, absorbance, and hydrophobic acid content indicate that DOC retains terrestrial carbon source information, while the terrestrial POC signal is largely replaced by autochthonous organic matter, and DIC integrates the influence of in-stream photosynthesis and respiration of organic matter. The UMR is slightly heterotrophic throughout the year, but pools formed by low-head navigation dams and natural impoundments promote a shift toward autotrophic conditions, altering aquatic ecosystem dynamics and POC and DIC compositions. Such changes likely occur in all major river systems affected by low-head dams and need to be incorporated into our understanding of inland water carbon dynamics and processes controlling CO2 emissions from rivers, as new navigation and flood control systems are planned for future river and water resources management.

Biological and land use controls on the isotopic composition of aquatic carbon in the Upper Mississippi River Basin

USGS Publications Warehouse

Voss, Britta; Wickland, Kimberly P.; Aiken, George R.; Striegl, Robert G.

2017-01-01

Riverine ecosystems receive organic matter (OM) from terrestrial sources, internally produce new OM, and biogeochemically cycle and modify organic and inorganic carbon. Major gaps remain in the understanding of the relationships between carbon sources and processing in river systems. Here we synthesize isotopic, elemental, and molecular properties of dissolved organic carbon (DOC), particulate organic carbon (POC), and dissolved inorganic carbon (DIC) in the Upper Mississippi River (UMR) system above Wabasha, MN, including the main stem Mississippi River and its four major tributaries (Minnesota, upper Mississippi, St. Croix, and Chippewa Rivers). Our goal was to elucidate how biological processing modifies the chemical and isotopic composition of aquatic carbon pools during transport downstream in a large river system with natural and man-made impoundments. Relationships between land cover and DOC carbon-isotope composition, absorbance, and hydrophobic acid content indicate that DOC retains terrestrial carbon source information, while the terrestrial POC signal is largely replaced by autochthonous organic matter, and DIC integrates the influence of in-stream photosynthesis and respiration of organic matter. The UMR is slightly heterotrophic throughout the year, but pools formed by low-head navigation dams and natural impoundments promote a shift towards autotrophic conditions, altering aquatic ecosystem dynamics and POC and DIC composition. Such changes likely occur in all major river systems affected by low-head dams and need to be incorporated into our understanding of inland water carbon dynamics and processes controlling CO2 emissions from rivers, as new navigation and flood control systems are planned for future river and water resources management.

Computer program for determination of concentrations of trace elements in components of water systems by nondestructive activation analysis (in German)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Slavic, I.; Draskovic, R.; Tasovac, T.

1973-03-01

A computer program for the determination of trace elements in components of the water systems bed material, suspended material, dissolved substances, plankton, algae) by nondestructive activation analysis was developed. Results of the determination of Cr, Sb, Sc, Fe, Co, Na, and La concentrations in suspended materials from the Danube river, obtained by interpretation of data with a CDC- 3600 computer (64 k words), are presented. (auth)

Trace metal distributions in the sediments from river-reservoir systems: case of the Congo River and Lake Ma Vallée, Kinshasa (Democratic Republic of Congo).

PubMed

Mwanamoki, Paola M; Devarajan, Naresh; Niane, Birane; Ngelinkoto, Patience; Thevenon, Florian; Nlandu, José W; Mpiana, Pius T; Prabakar, Kandasamy; Mubedi, Josué I; Kabele, Christophe G; Wildi, Walter; Poté, John

2015-01-01

The contamination of drinking water resources by toxic metals is a major problem in many parts of the world, particularly in dense populated areas of developing countries that lack wastewater treatment facilities. The present study characterizes the recent evolution with time of some contaminants deposited in the Congo River and Lake Ma Vallée, both located in the vicinity of the large city of Kinshasa, capital of Democratic Republic of Congo (DRC). Physicochemical parameters including grain size distribution, organic matter and trace element concentrations were measured in sediment cores sampled from Congo River (n = 3) and Lake Ma Vallée (n = 2). The maximum concentration of trace elements in sediment profiles was found in the samples from the sites of Pool Malebo, with the values of 107.2, 111.7, 88.6, 39.3, 15.4, 6.1 and 4.7 mg kg(-1) for Cr, Ni, Zn, Cu, Pb, As and Hg, respectively. This site, which is characterized by intense human activities, is especially well known for the construction of numerous boats that are used for regular navigation on Congo River. Concerning Lake Ma Vallée, the concentration of all metals are generally low, with maximum values of 26.3, 53.6, 16.1, 15.3, 6.5 and 1.8 mg kg(-1) for Cr, Ni, Zn, Cu, Pb and As, respectively. However, the comparison of the metal profiles retrieved from the different sampled cores also reveals specific variations. The results of this study point out the sediment pollution by toxic metals in the Congo River Basin. This research presents useful tools for the evaluation of sediment contamination of river-reservoir systems.

Geochemical disturbance of soil cover in the nonferrous mining centers of the Selenga River basin.

PubMed

Timofeev, Ivan V; Kosheleva, Natalia E

2017-08-01

The anthropogenic geochemical transformation of soil cover in large nonferrous mining centers of the Selenga River basin was assessed. The results of the geochemical survey of 2010-2012 revealed the spatial distribution patterns and abundances of 18 hazardous heavy metals and metalloids in the soils of Erdenet (Mongolia) and Zakamensk (Buryat republic, Russian Federation). In both cities, mining activities disturbed soil cover which accumulates Mo, Cu, As, Sb, W in Erdenet and Bi, W, Cd, Be, Pb, Mo, Sb in Zakamensk. Maximum accumulation of elements in Erdenet is restricted to the industrial zone. In Zakamensk, it has spread on ½ of the territory with the degree of multielemental pollution exceeding the extremely dangerous level by 16 times. The effect of mining centers on the state of the river system is local and does not spread to the Selenga River. Downstream from Erdenet, an artificial pool intercepts heavy metal and metalloid flows of the Erdenetii-Gol River. By contrast, downstream from the tailing dumps of the Dzhida tungsten-molybdenum plant the concentrations of ore elements W and Mo and their accessories Bi and Cd in the Modonkul River exceed background values by 146, 20, 57, and 21 times, respectively, decreasing by an order of magnitude 30 km downstream.

Review of rare earth element concentrations in oil shales of the Eocene Green River Formation

USGS Publications Warehouse

Birdwell, Justin E.

2012-01-01

Concentrations of the lanthanide series or rare earth elements and yttrium were determined for lacustrine oil shale samples from the Eocene Green River Formation in the Piceance Basin of Colorado and the Uinta Basin of Utah. Unprocessed oil shale, post-pyrolysis (spent) shale, and leached shale samples were examined to determine if oil-shale processing to generate oil or the remediation of retorted shale affects rare earth element concentrations. Results for unprocessed Green River oil shale samples were compared to data published in the literature on reference materials, such as chondritic meteorites, the North American shale composite, marine oil shale samples from two sites in northern Tibet, and mined rare earth element ores from the United States and China. The Green River oil shales had lower rare earth element concentrations (66.3 to 141.3 micrograms per gram, μg g-1) than are typical of material in the upper crust (approximately 170 μg g-1) and were also lower in rare earth elements relative to the North American shale composite (approximately 165 μg g-1). Adjusting for dilution of rare earth elements by organic matter does not account for the total difference between the oil shales and other crustal rocks. Europium anomalies for Green River oil shales from the Piceance Basin were slightly lower than those reported for the North American shale composite and upper crust. When compared to ores currently mined for rare earth elements, the concentrations in Green River oil shales are several orders of magnitude lower. Retorting Green River oil shales led to a slight enrichment of rare earth elements due to removal of organic matter. When concentrations in spent and leached samples were normalized to an original rock basis, concentrations were comparable to those of the raw shale, indicating that rare earth elements are conserved in processed oil shales.

Distribution of trace elements in sediment and soil from river Vardar Basin, Macedonia/Greece.

PubMed

Popov, Stanko Ilić; Stafilov, Trajče; Šajn, Robert; Tănăselia, Claudiu

2016-01-01

A systematic study was carried out to investigate the distribution of 59 elements in the sediment and soil samples collected from the river Vardar (Republic of Macedonia and Greece) and its major tributaries. The samples were collected from 28 sampling sites. Analyses were performed by inductively coupled plasma-mass spectrometry. R-mode factor analysis (FA) was used to identify and characterise element associations. Seven associations of elements were determined by the method of multivariate statistics. Every factor (Factors 1-3 and 6 and 7 as geogenic and Factors 4 and 5 as anthropogenic associations of elements) are examined and explained separately. The distribution of various elements showed that there is a presence of anthropogenic elements (Ag, Cd, Cu, Ge, Pb, Sn and Zn) introduced in the river sediments and soils from the mining, metallurgical, industrial and agricultural activities in Vardar River Basin, which covers most of the Republic of Macedonia and Central-northern part of Greece.

Trace elements transport in western Siberia rivers across a permafrost gradient

NASA Astrophysics Data System (ADS)

Pokrovsky, O. S.; Manasypov, R. M.; Loiko, S.; Krickov, I. A.; Kopysov, S. G.; Kolesnichenko, L. G.; Vorobyev, S. N.; Kirpotin, S. N.

2015-11-01

Towards a better understanding of trace element transport in permafrost-affected Earth surface environments, we sampled ∼ 60 large and small rivers (< 100 to ≤ 150 000 km2 watershed area) of Western Siberia Lowland (WSL) during spring flood and summer and winter base-flow across a 1500 km latitudinal gradient covering continuous, discontinuous, sporadic and permafrost-free zones. Analysis of ∼ 40 major and trace elements in dissolved (< 0.45 μm) fraction allowed establishing main environmental factors controlling the transport of metals and trace elements in rivers of this environmentally important region. No statistically significant effect of the basin size on most TE concentration was evidenced. Three category of trace elements were distinguished according to their concentration - latitude pattern: (i) increasing northward in spring and winter (Fe, Al, Ga (only winter), Ti (only winter), REEs, Pb, Zr, Hf, Th (only winter)), linked to leaching from peat and/or redox processes and transport in the form of Fe-rich colloids, (ii) decreasing northward during all seasons (Sr, Mo, U, As, Sb) marking the underground water influence of river feeding and (iii) elements without distinct trend from S to N whose variations within each latitude range were higher than the difference between latitudinal ranges (B, Li, Ti (except summer), Cr, V, Mn, Zn, Cd, Cs, Hf, Th). In addition to these general features, specific, northward increase during spring period was mostly pronounced for Fe, Mn, Co, Zn and Ba and may stem from a combination of enhanced leaching from the topsoil and vegetation and bottom waters of the lakes (spring overturn). A spring time northward decrease was observed for Ni, Cu, Zr, Rb. The southward increase in summer was strongly visible for Fe, Ni, Ba, Rb and V, probably due to peat/moss release (Ni, Ba, Rb) or groundwater feeding (Fe, V). The Principal Component Analysis demonstrated two main factors potentially controlling the ensemble of TE concentration variation. The first factor, responsible for 16-20 % of overall variation, included trivalent and tetravalent hydrolysates, Cr, V, and DOC and presumably reflected the presence of organo-mineral colloids, as also confirmed by previous studies in Siberian rivers. The 2nd factor (8-14 % variation) was linked to the latitude of the watershed and acted on elements affected by the groundwater feeding (DIC, Sr, Mo, As, Sb, U), whose concentration decreased significantly northward during all seasons. Overall, the rank of environmental factors on TE concentration in western Siberian rivers was latitude (3 permafrost zones) > season > watershed size. The effect of the latitude was minimal in spring for most TE but highly visible for Sr, Mo, Sb and U. The main factors controlling the shift of river feeding from surface and subsurface flow to deep underground flow in the permafrost-bearing zone were the depth of the active (unfrozen) seasonal layer and its position in organic or mineral horizons of the soil profile. In the permafrost-free zone, the relative role of carbonate mineral-bearing base rock feeding vs. bog water feeding determined the pattern of trace element concentration and fluxes in rivers of various size as a function of season. Comparison of obtained TE fluxes in WSL rivers with those of other subarctic rivers demonstrated reasonable agreement for most trace elements; the lithology of base rocks was the major factor controlling the magnitude of TE fluxes. The climate change in western Siberia and permafrost boundary migration will affect essentially the elements controlled by underground water feeding (DIC, alkaline-earth elements (Ca, Sr), oxyanions (Mo, Sb, As) and U). The thickening of the active layer may increase the export of trivalent and tetravalent hydrolysates in the form of organo-ferric colloids. Plant litter-originated divalent metals present as organic complexes may be retained via adsorption on mineral horizon. However, due to various counterbalanced processes controlling element source and sinks in plants - peat - mineral soil - river systems, the overall impact of the permafrost thaw on TE export from the land to the ocean may be smaller than that foreseen by merely active layer thickening and permafrost boundary shift.

Advancing towards functional environmental flows for temperate floodplain rivers.

PubMed

Hayes, Daniel S; Brändle, Julia M; Seliger, Carina; Zeiringer, Bernhard; Ferreira, Teresa; Schmutz, Stefan

2018-08-15

Abstraction, diversion, and storage of flow alter rivers worldwide. In this context, minimum flow regulations are applied to mitigate adverse impacts and to protect affected river reaches from environmental deterioration. Mostly, however, only selected instream criteria are considered, neglecting the floodplain as an indispensable part of the fluvial ecosystem. Based on essential functions and processes of unimpaired temperate floodplain rivers, we identify fundamental principles to which we must adhere to determine truly ecologically-relevant environmental flows. Literature reveals that the natural flow regime and its seasonal components are primary drivers for functions and processes of abiotic and biotic elements such as morphology, water quality, floodplain, groundwater, riparian vegetation, fish, macroinvertebrates, and amphibians, thus preserving the integrity of floodplain river ecosystems. Based on the relationship between key flow regime elements and associated environmental components within as well as adjacent to the river, we formulate a process-oriented functional floodplain flow (ff-flow) approach which offers a holistic conceptual framework for environmental flow assessment in temperate floodplain river systems. The ff-flow approach underlines the importance of emulating the natural flow regime with its seasonal variability, flow magnitude, frequency, event duration, and rise and fall of the hydrograph. We conclude that the ecological principles presented in the ff-flow approach ensure the protection of floodplain rivers impacted by flow regulation by establishing ecologically relevant environmental flows and guiding flow restoration measures. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

Simulation of an urban ground-water-flow system in the Menomonee Valley, Milwaukee, Wisconsin using analytic element modeling

USGS Publications Warehouse

Dunning, C.P.; Feinstein, D.T.

2004-01-01

A single-layer, steady-state analytic element model was constructed to simulate shallow ground-water flow in the Menomonee Valley, an old industrial center southwest of downtown Milwaukee, Wisconsin. Project objectives were to develop an understanding of the shallow ground-water flow system and identify primary receptors of recharge to the valley. The analytic element model simulates flow in a 18.3 m (60 ft) thick layer of estuarine and alluvial sediments and man-made fill that comprises the shallow aquifer across the valley. The thin, laterally extensive nature of the shallow aquifer suggests horizontal-flow predominates, thus the system can appropriately be modeled with the Dupuit-Forchheimer approximation in an analytic element model. The model was calibrated to the measured baseflow increase between two USGS gages on the Menomonee River, 90 head measurements taken in and around the valley during December 1999, and vertical gradients measured at five locations under the river and estuary in the valley. Recent construction of the Milwaukee Metropolitan Sewer District Inline Storage System (ISS) in the Silurian dolomite under the Menomonee Valley has locally lowered heads in the dolomite appreciably, below levels caused by historic pumping. The ISS is a regional hydraulic sink which removes water from the bedrock even during dry weather. The potential effect on flow directions in the shallow aquifer of dry-weather infiltration to the ISS was evaluated by adjusting the resistance of the line-sink strings representing the ISS in the model to allow infiltration from 0 to 100% of the reported 9,500 m3/d. The best fit to calibration targets was found between 60% (5,700 m3/d) and 80% (7,600 m3/d) of the reported dry-weather infiltration. At 60% infiltration, 65% of the recharge falling on the valley terminates at the ISS and 35% at the Menomonee River and estuary. At 80% infiltration, 73% of the recharge terminates at the ISS, and 27% at the river and estuary. Model simulations suggest that the ISS has an greater influence on the shallow ground-water flow in the eastern half of valley as compared to the western half. Preliminary three-dimensional simulations using the numerical MODFLOW code show good agreement with the single-layer simulation and supports its use in evaluating the shallow system. Copyright ASCE 2004.

Organochlorine compounds and trace elements in fish tissue and bed sediments in the lower Snake River basin, Idaho and Oregon

USGS Publications Warehouse

Clark, Gregory M.; Maret, Terry R.

1998-01-01

Fish-tissue and bed-sediment samples were collected to determine the occurrence and distribution of organochlorine compounds and trace elements in the lower Snake River Basin. Whole-body composite samples of suckers and carp from seven sites were analyzed for organochlorine compounds; liver samples were analyzed for trace elements. Fillets from selected sportfish were analyzed for organochlorine compounds and trace elements. Bed-sediment samples from three sites were analyzed for organochlorine compounds and trace elements. Twelve different organochlorine compounds were detected in 14 fish-tissue samples. All fish-tissue samples contained DDT or its metabolites. Concentrations of total DDT ranged from 11 micrograms per kilogram wet weight in fillets of yellow perch from C.J. Strike Reservoir to 3,633 micrograms per kilogram wet weight in a whole-body sample of carp from Brownlee Reservoir at Burnt River. Total DDT concentrations in whole-body samples of sucker and carp from the Snake River at C.J. Strike Reservoir, Snake River at Swan Falls, Snake River at Nyssa, and Brownlee Reservoir at Burnt River exceeded criteria established for the protection of fish-eating wildlife. Total PCB concentrations in a whole-body sample of carp from Brownlee Reservoir at Burnt River also exceeded fish-eating wildlife criteria. Concentrations of organochlorine compounds in whole-body samples, in general, were larger than concentrations in sportfish fillets. However, concentrations of dieldrin and total DDT in fillets of channel catfish from the Snake River at Nyssa and Brownlee Reservoir at Burnt River, and concentrations of total DDT in fillets of smallmouth bass and white crappie from Brownlee Reservoir at Burnt River exceeded a cancer risk screening value of 10-6 established by the U.S. Environmental Protection Agency. Concentrations of organochlorine compounds in bed sediment were smaller than concentrations in fish tissue. Concentrations of p,p'DDE, the only compound detected in all three bed-sediment samples, ranged from 1.1 micrograms per kilogram dry weight in C.J. Strike Reservoir to 11 micrograms per kilogram dry weight in Brownlee Reservoir at Burnt River. Data from this study, compared with data collected in the upper Snake River Basin from 1992 to 1994, indicates that, in general, organochlorine concentrations in fish tissue and bed sediment increased from the headwaters of the Snake River in Wyoming downstream to Brownlee Reservoir. The largest trace-element concentrations in fish tissue were in liver samples from carp from Brownlee Reservoir at Burnt River and suckers from the Boise River near Twin Springs. Concentrations of most trace elements were larger in livers than in the sport- fish fillets. However, mercury concentrations were generally larger in the sportfish fillets; they ranged from 0.08 microgram per gram wet weight in yellow perch from C.J. Strike Reservoir to 0.32 microgram per gram wet weight in channel catfish from Brownlee Reservoir at Burnt River. None of the trace-element concentrations in fillets exceeded median international standards or U.S. Food and Drug Administration action levels. Large trace-element concentrations in the upper Snake River Basin were reported in liver samples from suckers from headwater streams, probably a result of historical mining and weathering of metal-rich rocks. Concentrations of most trace elements in the bed-sediment samples were largest in Brownlee Reservoir at Mountain Man Lodge. Concentrations of arsenic, cadmium, chromium, copper, nickel, and zinc in bed sediment from the Mountain Man Lodge site exceeded either the threshold effect level or probable effect level established by the Canadian Government for the protection of benthic life. Arsenic, chromium, copper, and nickel concentrations in bed sediment from Brownlee Reservoir at Burnt River and chromium, copper, and nickel in bed sediment from C.J. Strike Reservoir also exceeded the threshold effect level.

Evaluating Local and Regional Sources of Trace Element Contamination in a Rural Sub Estuary of the Upper Chesapeake Bay

NASA Astrophysics Data System (ADS)

Krahforst, C.; Hartman, S.; Sherman, L.; Kehm, K.

2014-12-01

The distribution of trace elements (V, Cr, Co, Ni, Cu, Zn, As, Ag, Cd, Sn, Ba, W, Pb and U) along with Al and Fe and other sediment characteristics in surface sediment and sediment cores from the Chester River - a sub estuary of the Chesapeake Bay located in a predominantly agricultural watershed of Maryland's upper Eastern Shore, USA - have been determined in order to add to the understanding of contaminant transport and fate and inform management strategies designed to maintain or improve the ecological condition of estuaries. These analyses coupled with the comparison of elemental analysis of 210Pb - dated sediment cores, main stem water quality surveys, and a review of recent EPA National Coastal Condition Assessment sediment data from Chesapeake Bay provide added information about the roles of local and region scale processes on ecosystem condition. The high amount of suspended sediment in the Chester River (5-20 mg L-1) is an important factor controlling water quality conditions of the Chester River and a prime focus for environmental management of this system. Sources of suspended matter include local runoff, atmospheric deposition, local resuspension, and exchange with the Chesapeake Bay. In principle, each of these sources could be distinguished on the basis of chemical composition of surface sediment. Preliminary results from multivariate analytic models indicate that many of the elements investigated display significant covariance with Al (and other predominantly crustal signatures) which may indicate limited exogenic sources of contamination for sediments of this watershed. For example total Pb concentrations are mostly below the NOAA's low toxic effects level and lower than the median value of NCCA data for the upper Chesapeake suggesting that sediments have significant sources from within the watershed. Further, significant higher concentrations of Sn and Cu coincide with sediment collected in or near marinas and point to localized anthropogenic sources for these elements. Elemental enrichment values relative to Al of Chester River sediments are significantly lower than observations in sediments from Chesapeake Bay overall and may indicate that local watershed management strategies may be effective for improving water and habitat quality of the Chester River.

Source and fate of inorganic solutes in the Gibbon River, Yellowstone National Park, Wyoming, USA. II. Trace element chemistry

USGS Publications Warehouse

McCleskey, R. Blaine; Nordstrom, D. Kirk; Susong, David D.; Ball, James W.; Taylor, Howard E.

2010-01-01

The Gibbon River in Yellowstone National Park receives inflows from several geothermal areas, and consequently the concentrations of many trace elements are elevated compared to rivers in non-geothermal watersheds. Water samples and discharge measurements were obtained from the Gibbon River and its major tributaries near Norris Geyser Basin under the low-flow conditions of September 2006 allowing for the identification of solute sources and their downstream fate. Norris Geyser Basin, and in particular Tantalus Creek, is the largest source of many trace elements (Al, As, B, Ba, Br, Cs, Hg, Li, Sb, Tl, W, and REEs) to the Gibbon River. The Chocolate Pots area is a major source of Fe and Mn, and the lower Gibbon River near Terrace Spring is the major source of Be and Mo. Some of the elevated trace elements are aquatic health concerns (As, Sb, and Hg) and knowing their fate is important. Most solutes in the Gibbon River, including As and Sb, behave conservatively or are minimally attenuated over 29 km of fluvial transport. Some small attenuation of Al, Fe, Hg, and REEs occurs but primarily there is a transformation from the dissolved state to suspended particles, with most of these elements still being transported to the Madison River. Dissolved Hg and REEs loads decrease where the particulate Fe increases, suggesting sorption onto suspended particulate material. Attenuation from the water column is substantial for Mn, with little formation of Mn as suspended particulates.

Preface: Bridging the gap between theory and practice on the upper Mississippi River

USGS Publications Warehouse

Lubinski, Kenneth S.

1995-01-01

In July 1994, the Upper Mississippi River (UMR) served as a nexus for coalescing scientific information and management issues related to worldwide floodplain river ecosystems. The objective of the conference ‘Sustaining the Ecological Integrity of Large Floodplain Rivers: Application of Ecological Knowledge to River Management’, was to provide presentations of current ideas from the scientific community. To translate the many lessons learned on other river systems to operational decisions on the UMR, a companion workshop for managers and the general public was held immediately after the conference.An immediate local need for such sharing has existed for several years, as the U.S. Corps of Engineers is currently planning commercial navigation activities that will influence the ecological integrity of the river over the next half century. Recently, other equally important management issues have surfaced, including managing the river as an element of the watershed, and assessing its ecological value as a system instead of a collection of parts (Upper Mississippi River Conservation Committee, 1993). Regional and state natural resource agencies are becoming more convinced that they need to address these issues within their own authorities, however spatially limited, rather than relying on the U.S. Corps of Engineers to manage the ecosystem as an adjunct to its purpose of navigation support.

Hydrothermal element fluxes from Copahue, Argentina: A “beehive” volcano in turmoil

NASA Astrophysics Data System (ADS)

Varekamp, Johan C.; Ouimette, Andrew P.; Herman, Scott W.; Bermúdez, Adriana; Delpino, Daniel

2001-11-01

Copahue volcano erupted altered rock debris, siliceous dust, pyroclastic sulfur, and rare juvenile fragments between 1992 and 1995, and magmatic eruptions occurred in July October 2000. Prior to 2000, the Copahue crater lake, acid hot springs, and rivers carried acid brines with compositions that reflected close to congruent rock dissolution. The ratio between rock-forming elements and chloride in the central zone of the volcano-hydrothermal system has diminished over the past few years, reflecting increased water/rock ratios as a result of progressive rock dissolution. Magmatic activity in 2000 provided fresh rocks for the acid fluids, resulting in higher ratios between rock-forming elements and chloride in the fluids and enhanced Mg fluxes. The higher Mg fluxes started several weeks prior to the eruption. Model data on the crater lake and river element flux determinations indicate that Copahue volcano was hollowed out at a rate of about 20000 25000 m3/yr, but that void space was filled with about equal amounts of silica and liquid elemental sulfur. The extensive rock dissolution has weakened the internal volcanic structure, making flank collapse a volcanic hazard at Copahue.

Some aspects of water quality in a polluted lowland river in relation to the intracellular chemical levels in planktonic and epilithic diatoms.

PubMed

Tien, Chien-Jung

2004-04-01

Changes in elemental concentrations of diatoms and river water from the river Erh-Jen were determined using scanning electron microscopy energy-dispersive X-ray microanalysis and inductively coupled plasma mass spectrometry. Relatively large amounts of copper and lead found in both planktonic and epilithic diatoms implied these algae might play an important role in biogeochemical cycles and in the transfer of those elements to higher trophic levels in the aquatic environment. Changes in elemental concentrations within diatom cells were found to vary with other elements within cells and the same or different elements in water. Planktonic and epilithic cells showed different correlation patterns. For epilithic diatoms, negative correlations were found between concentrations of total phosphorus and phosphate in water and those of phosphorus within cells, and between concentrations of lead in water and in cells. Concentrations of chromium and mercury within planktonic cells and those of phosphorus, manganese and lead within epilithic ones were found to be easily influenced by other elements in river water, indicating appearance of the competitive manner on uptake of such elements by algal cells. Relatively high concentration factors (CFs) for cadmium, mercury and lead by diatoms in this study suggested they are good accumulators for these heavy metals. Significant negative corrections were found between the CFs of diatoms and the concentrations of elements in river water.

Multidisciplinary work on barium contamination of the karstic upper Kupa River drainage basin (Croatia and Slovenia); calling for watershed management.

PubMed

Francisković-Bilinski, S; Bilinski, H; Grbac, R; Zunić, J; Necemer, M; Hanzel, D

2007-02-01

The present work was designed as an extension of a previous study of a barium anomaly observed in stream sediments of the Kupa River. In its upper part the Kupa River drains a region underlain by a trans-boundary aquifer. The river is a significant water resource in a region of tourism, sport, and fishing in both Croatia and Slovenia. The contamination source is situated in Homer (Lokve), Croatia, where barite was mined until 10 years ago. The barium processing waste material (<3-mm fraction) was carelessly deposited in gardens, forests, and into a sinkhole, which has an underground link with the Kupica River, a tributary of the Kupa River. Barium waste and stream sediments were analyzed using comparative techniques: X-ray diffraction (XRD), X-ray fluorescence (XRF), Mössbauer spectroscopy, and grain size analysis. XRD of the waste material identified the major minerals quartz, barite, and dolomite and the Fe-containing minor minerals muscovite and goethite. Barite was identified as a minor or trace mineral in the Kupica River sediments. XRF analysis of the waste material has shown Ba and Fe to be the predominant elements, Ca and K to be minor elements, and Mn, Zn, Sr, Pb, Co, Cu, As, Zr, Rb, Y, and Mo to be trace elements. Mössbauer spectroscopy performed at room temperature (RT) was used to study iron minerals, particularly to obtain information on the valence status of Fe ions. Grain size analysis of the waste material (<63-microm fraction) has shown that it contains 23.5% clay-size material in comparison with 7-8% clay-size material in stream sediments. It is our aim to combine geochemical and medical methods to investigate the possible impact of waste disposal on human health in Lokve. At this stage of the work, concentrations of Ba and other toxic elements in the water compartment of the Kupica River (a source of drinking water) have not been monitored by Croatian Waters (name of the Croatian water authorities). The necessity of such measurements in future studies has been highlighted. A preliminary study of diseases diagnosed in Lokve shows that about 18% of the total inhabitants have serious medical problems. Diseases of the circulatory system, endocrine, nutritional, and metabolic diseases, neoplasms, and respiratory diseases predominate. This paper calls for further multidisciplinary research on the health effects of barium and trace elements, as well as for bioremediation of contaminated gardens and for watershed management of vulnerable karstic aquifers.

Direct evidence of the feedback between climate and nutrient, major, and trace element transport to the oceans

NASA Astrophysics Data System (ADS)

Eiriksdottir, Eydis Salome; Gislason, Sigurður Reynir; Oelkers, Eric H.

2015-10-01

Climate changes affect weathering, denudation and riverine runoff, and therefore elemental fluxes to the ocean. This study presents the climate effect on annual fluxes of 28 dissolved elements, and organic and inorganic particulate fluxes, determined over 26-42 year period in three glacial and three non-glacial river catchments located in Eastern Iceland. Annual riverine fluxes were determined by generating robust correlations between dissolved element concentrations measured from 1998 to 2003 and suspended inorganic matter concentrations measured from 1962 to 2002 with instantaneous discharge measured at the time of sampling in each of these rivers. These correlations were used together with measured average daily discharge to compute daily elemental fluxes. Integration of these daily fluxes yielded the corresponding annual fluxes. As the topography and lithology of the studied glacial and non-glacial river catchments are similar, we used the records of average annual temperature and annual runoff to examine how these parameters and glacier melting influenced individual element fluxes to the oceans. Significant variations were found between the individual elements. The dissolved fluxes of the more soluble elements, such as Mo, Sr, and Na are less affected by increasing temperature and runoff than the insoluble nutrients and trace elements including Fe, P, and Al. This variation between the elements tends to be more pronounced for the glacial compared to the non-glacial rivers. These observations are interpreted to stem from the stronger solubility control on the concentrations of the insoluble elements such that they are less affected by dilution. The dilution of the soluble elements by increasing discharge in the glacial rivers is enhanced by a relatively low amount of water-rock interaction; increased runoff due to glacial melting tend to be collected rapidly into river channels limiting water-rock interaction. It was found that the climate effect on particle transport from the glacial rivers is far higher than all other measured fluxes. This observation, together with the finding that the flux to the oceans of biolimiting elements such as P and Fe is dominated by particulates, suggests that particulate transport by melting glaciers have a relatively strong effect on the feedback between continental weathering, atmospheric chemistry, and climate regulation over geologic time.

The Distribution between the Dissolved and the Particulate Forms of 49 Metals across the Tigris River, Baghdad, Iraq

PubMed Central

Hamad, Samera Hussein; Schauer, James Jay; Shafer, Martin Merrill; Abed Al-Raheem, Esam; Satar, Hyder

2012-01-01

The distribution of dissolved and particulate forms of 49 elements was investigated along transect of the Tigris River (one of the major rivers of the world) within Baghdad city and in its major tributary (Diyala River) from 11 to 28 July 2011. SF-ICP-MS was used to measure total and filterable elements at 17 locations along the Tigris River transect, two samples from the Diyala River, and in one sample from the confluence of the two rivers. The calculated particulate forms were used to determine the particle-partition coefficients of the metals. No major changes in the elements concentrations down the river transect. Dissolved phases dominated the physical speciation of many metals (e.g., As, Mo, and Pt) in the Tigris River, while Al, Fe, Pb, Th, and Ti were exhibiting high particulate fractions, with a trend of particle partition coefficients of [Ti(40) > Th(35) > Fe(15) > Al(13) > Pb(4.5)] ∗ 106 L/kg. Particulate forms of all metals exhibited high concentrations in the Diyala River, though the partition coefficients were low due to high TSS (~270 mg/L). A comparison of Tigris with the major rivers of the world showed that Tigris quality in Baghdad is comparable to Seine River quality in Paris. PMID:23304083

Sediment and water chemistry of the San Juan River and Escalante River deltas of Lake Powell, Utah, 2010-2011

USGS Publications Warehouse

Hornewer, Nancy J.

2014-01-01

Recent studies have documented the presence of trace elements, organic compounds including polycyclic aromatic hydrocarbons, and radionuclides in sediment from the Colorado River delta and from sediment in some side canyons in Lake Powell, Utah and Arizona. The fate of many of these contaminants is of significant concern to the resource managers of the National Park Service Glen Canyon National Recreation Area because of potential health impacts to humans and aquatic and terrestrial species. In 2010, the U.S. Geological Survey began a sediment-core sampling and analysis program in the San Juan River and Escalante River deltas in Lake Powell, Utah, to help the National Park Service further document the presence or absence of contaminants in deltaic sediment. Three sediment cores were collected from the San Juan River delta in August 2010 and three sediment cores and an additional replicate core were collected from the Escalante River delta in September 2011. Sediment from the cores was subsampled and composited for analysis of major and trace elements. Fifty-five major and trace elements were analyzed in 116 subsamples and 7 composited samples for the San Juan River delta cores, and in 75 subsamples and 9 composited samples for the Escalante River delta cores. Six composited sediment samples from the San Juan River delta cores and eight from the Escalante River delta cores also were analyzed for 55 low-level organochlorine pesticides and polychlorinated biphenyls, 61 polycyclic aromatic hydrocarbon compounds, gross alpha and gross beta radionuclides, and sediment-particle size. Additionally, water samples were collected from the sediment-water interface overlying each of the three cores collected from the San Juan River and Escalante River deltas. Each water sample was analyzed for 57 major and trace elements. Most of the major and trace elements analyzed were detected at concentrations greater than reporting levels for the sediment-core subsamples and composited samples. Low-level organochlorine pesticides and polychlorinated biphenyls were not detected in any of the samples. Only one polycyclic aromatic hydrocarbon compound was detected at a concentration greater than the reporting level for one San Juan composited sample. Gross alpha and gross beta radionuclides were detected at concentrations greater than reporting levels for all samples. Most of the major and trace elements analyzed were detected at concentrations greater than reporting levels for water samples.

Evolution of Metallic Trace Elements in Contaminated River Sediments: Geochemical Variation Along River Linear and Vertical Profile

NASA Astrophysics Data System (ADS)

Kanbar, Hussein; Montarges-Pelletier, Emmanuelle; Mansuy-Huault, Laurence; Losson, Benoit; Manceau, Luc; Bauer, Allan; Bihannic, Isabelle; Gley, Renaud; El Samrani, Antoine; Kobaissi, Ahmad; Kazpard, Veronique; Villieras, Frédéric

2015-04-01

Metal pollution in riverine systems poses a serious threat that jeopardizes water and sediment quality, and hence river dwelling biota. Since those metallic pollutants can be transported for long distances via river flow, river management has become a great necessity, especially in times where industrial activities and global climate change are causing metal release and spreading (by flooding events). These changes are able to modify river hydrodynamics, and as a consequence natural physico-chemical status of different aquatic system compartments, which in turn alter metal mobility, availability and speciation. Vertical profiles of sediments hold the archive of what has been deposited for several tenths of years, thus they are used as a tool to study what had been deposited in rivers beds. The studied area lies in the Orne river, northeastern France. This river had been strongly modified physically and affected by steelmaking industrial activities that had boosted in the middle of the last century. This study focuses on several sites along the linear of the Orne river, as well as vertical profiles of sediments. Sediment cores were collected at sites where sedimentation is favoured, and in particular upstream two dams, built in the second half of the XXth century for industrial purposes. Sediment cores were sliced into 2-5cm layers, according to suitability, and analysed for physical and physico-chemical properties, elemental content and mineralogy. Data of the vertical profile in a sediment core is important to show the evolution of sediments as a function of depth, and hence age, in terms of nature, size and constituents. The physical properties include particle size distribution (PSD) and water content. In addition, the physico-chemical properties, such as pH and oxido-reduction potential (ORP) of interstitial water from undisturbed cores were also detected. Total elemental content of sediment and available ones of extracted interstitial waters was detected using ICP-MS and ICP-OES for trace and major elements respectively. Well crystallized minerals were detected by X-Ray Diffraction (XRD), while amorphous and poorly crystallized phases were identified with scanning and transmission electron microscope (SEM and TEM respectively), combined with Energy Dispersive X-Ray Spectroscopy (EDXS). Such microscopic techniques also provided information about metal carriers. To have an insight about the metal speciation at molecular level, X-Ray Absorption spectroscopy (XAS) was performed at Zn K-edge. The first analyses of Orne sediment cores evidenced different particle size distribution and sediment consolidation levels. Yet the cores showed that below a layer of apparently recent sediments (about 10-20 cm), lie highly contaminated ones. Zn and Pb content in deep sediment layers reach several thousands ppm, where they appeared mainly as Zn and Pb sulphides. Also, the high content of iron in deep sediments resulted in the presence of different iron phases: hematite, wuestite, magnetite, goethite, sulphides (pyrite), as well as undefined iron-silicate. In addition, interstitial waters contained high values of available metals (Zn: 500-35000 ppm, Pb: 150-5700 ppm, Cd: 1-10ppm), which might cause a greater concern than solid-bound metals, especially when river bed sediments are disturbed.

Complex Behavior of Contaminant Flux and the Ecology of the Lower Mississippi River

NASA Astrophysics Data System (ADS)

Barton, C. C.; Manheim, F. T.; De Cola, L.; Bollinger, J. E.; Jenkins, J. A.

2001-12-01

This presentation is an overview of a collaborative NSF/USGS/Tulane funded multi-scale study of the Lower Mississippi River system. The study examines the system in three major dimensional realms: space, time, and complexity (systems and their hierarchies). Researchers at Tulane University and the U.S. Geological Survey have initiated a collaborative effort to undertake the study of interacting elements which directly or indirectly affect the water quality, ecology and physical condition of the Mississippi River. These researchers include experts in the fields of water quality chemistry, geochemistry, hydrologic modeling, bioengineering, biology, fish ecology, statistics, complexity analysis, epidemiology, and computer science. Underlying this research are large databases that permit quantitative analysis of the system over the past 40 years. Results to date show that the variation in discharge and the contaminant flux scale independently both exhibit fractal scaling, the signature geometry of nonlinear dynamical and complex systems. Public perception is that the Lower Mississippi River is a health hazard, but for the past decade, traditional water quality measurements show that contaminants are within current regulatory guidelines for human consumption. This difference between public perception and scientific reality represents a complex scientific and social issue. The connections and feedback within the ecological system and the Mississippi River are few because engineering structures isolate the lower Mississippi River from its surroundings. Investigation of the connections and feedback between human health and the ecological health of the River and the surrounding region as well as perceptions of these states of health - holds promise for explaining epidemiological patterns of human disease.

Annual budget of Gd and related Rare Earth Elements in a river basin heavily disturbed by anthropogenic activities.

NASA Astrophysics Data System (ADS)

Hissler, Christophe; Stille, Peter; Guignard, Cédric; François Iffly, Jean; Pfister, Laurent

2014-05-01

The real environmental impact of micropollutants in river systems can be difficult to assess, essentially due to uncertainties in the estimation of the relative significance of both anthropogenic and natural sources. The natural geochemical background is characterized by important variations at global, regional or local scales. Moreover, elements currently considered to be undisturbed by human activities and used as tracers of continental crust derived material have become more and more involved in industrial or agricultural processes. The global production of lanthanides (REE), used in industry, medicine and agriculture, for instance, has increased exponentially from a few tons in 1950 to projected 185 kt in 2015. Consequently, these new anthropogenic contributions impact the natural cycle of the REE. Gd and related REE are now worldwide recognized as emergent micropollutants in river systems. Nevertheless, there is still a gap concerning their temporal dynamics in rivers and especially the quantification of both the anthropogenic and natural contributions in surface water. The acquisition of such quantitative information is of primordial interest because elements from both origins may present different bioavailability and toxicity levels. Working at the river basin scale allows for quantifying micropollutant fluxes. For this reason, we monitored water quality and discharge of the Alzette River (Luxembourg, Europe) over two complete hydrological cycles (2010-2013). The substantial contamination, is principally due to the steel industry in the basin, which has been active from 1875 until now, and to the related increase of urban areas. The particulate and dissolved fractions of river water were monitored using a multitracer approach (standard parameters for water quality including REE concentrations, Pb, Sr, Nd radiogenic isotopes) with two sampling setups (bi-weekly and flood event based sampling). This extensive sampling design allowed quantifying the annual budget of the REE in the particulate and dissolved fractions of the river water and the waste water treatment plant effluents. Enrichments in Gd have been observed for the dissolved fraction of the water during low water levels. This enrichment has not been detected in the surrounding soils of the basin and can be related to the effluents of the waste water treatment plants, which control the REE chemistry of the dissolved fraction during the low water period. When flood events occur, the Gd anomaly progressively disappears and gives way to the chemical signature of the basin soils. The REE and intense hydrological monitoring we performed at the same time allowed for the annual quantification of the anthropogenic vs. natural REE fluxes in the river water of this heavily polluted basin.

Stream-sediment geochemistry in mining-impacted streams : sediment mobilized by floods in the Coeur d'Alene-Spokane River system, Idaho and Washington

USGS Publications Warehouse

Box, Stephen E.; Bookstrom, Arthur A.; Ikramuddin, Mohammed

2005-01-01

Environmental problems associated with the dispersion of metal-enriched sediment into the Coeur d'Alene-Spokane River system downstream from the Coeur d'Alene Mining District in northern Idaho have been a cause of litigation since 1903, 18 years after the initiation of mining for lead, zinc, and silver. Although direct dumping of waste materials into the river by active mining operations stopped in 1968, metal-enriched sediment continues to be mobilized during times of high runoff and deposited on valley flood plains and in Coeur d'Alene Lake (Horowitz and others, 1993). To gauge the geographic and temporal variations in the metal contents of flood sediment and to provide constraints on the sources and processes responsible for those variations, we collected samples of suspended sediment and overbank deposits during and after four high-flow events in 1995, 1996, and 1997 in the Coeur d'Alene-Spokane River system with estimated recurrence intervals ranging from 2 to 100 years. Suspended sediment enriched in lead, zinc, silver, antimony, arsenic, cadmium, and copper was detected over a distance of more than 130 mi (the downstream extent of sampling) downstream of the mining district. Strong correlations of all these elements in suspended sediment with each other and with iron and manganese are apparent when samples are grouped by reach (tributaries to the South Fork of the Coeur d'Alene River, the South Fork of the Coeur d'Alene River, the main stem of the Coeur d'Alene River, and the Spokane River). Elemental correlations with iron and manganese, along with observations by scanning electron microscopy, indicate that most of the trace metals are associated with Fe and Mn oxyhydroxide compounds. Changes in elemental correlations by reach suggest that the sources of metal-enriched sediment change along the length of the drainage. Metal contents of suspended sediment generally increase through the mining district along the South Fork of the Coeur d'Alene River, decrease below the confluence of the North and South Forks, and then increase again downstream of the gradient flattening below Cataldo. Metal contents of suspended sediment in the Spokane River below Coeur d'Alene Lake were comparable to those of suspended sediment in the main stem of the Coeur d'Alene River above the lake during the 1997 spring runoff, but with somewhat higher Zn contents. Daily suspended-sediment loads were about 100 times larger in the 1996 flood (50-100-year recurrence interval) than in the smaller 1997 floods (2-5-year recurrence intervals). Significant differences in metal ratios and contents are also apparent between the two flood types. The predominant source of suspended sediment in the larger 1996 flood was previously deposited, metal-enriched flood-plain sediment, identified by its Zn/Pb ratio less than 1. Suspended sediment in the smaller 1997 floods had metal ratios distinct from those of the flood-plain deposits and was primarily derived from metal-enriched sediment stored within the stream channel, identified by a Zn/Pb ratio greater than 1. Sediment deposited during overbank flooding on the immediate streambank or natural levee of the river typically consists of sandy material with metal ratios and contents similar to those of the sandy streambed sediment in the adjacent river reach. Samples of overbank deposits in backlevee marshes collected after the 1996 flood have metal ratios similar to those of peak-flow suspended sediment in the same river reach, but generally lower metal contents.

Lower Mississippi River Environmental Program. Report 11. Forest Vegetation of the Leveed Floodplain of the Lower Mississippi River

DTIC Science & Technology

1988-02-01

species that are structurally appropriate to the understory category (such as Arundinaria gigantea and Sambucus * canadensis) were included in this...element descriptions below contain qualifications essential * to proper application of the system. Certain special considerations are dis- cussed that...similar sites this fac- tor is not used, since these areas have essentially been stabilized since the 1940’s (Tuttle and Pinner 1982); that is, no new

The impacts of Segura River (Spain) channelization on the coastal seabed.

PubMed

Aragonés, L; Pagán, J I; López, M P; García-Barba, J

2016-02-01

Human actions over rivers and coasts have generated great changes along seaboard. In order to know future development of those changes, it is necessary to understand the development of the coast during the past. When there is a complex morphologic system as a result of the combination of natural elements with human construction elements, the study of the abovementioned changes requires a wider perspective than the one provided by traditional two-dimensional methods. Thus, the Geographic Information Systems (GIS) become a suitable tool for that kind of studies. In this work, GIS are used to understand changes in bathymetry, sediments properties and transport, as well as surface variations of plant species occurred in the Segura River mouth (Spain) within a period of 17 years due to the channelization of the river low course. The methodology followed here implies the integration of data coming from different sources and with different formats in a GIS, what allows for a spatial analysis. Results obtained show the grain-size spatial distribution for every period of time studied, as well as bathymetry changes and seabed morphology. It can be concluded that the construction works carried out in the riverbed have affected sediment grain-size in the area. Clays have nearly disappeared and consequently there is a descent of seabed level that affects plant species, such as Posidonia oceanica. Copyright © 2015 Elsevier B.V. All rights reserved.

Assessing ecological water quality with macroinvertebrates and fish: a case study from a small Mediterranean river.

PubMed

Cheimonopoulou, Maria Th; Bobori, Dimitra C; Theocharopoulos, Ioannis; Lazaridou, Maria

2011-02-01

Biological elements, such as benthic macroinvertebrates and fish, have been used in assessing the ecological quality of rivers according to the requirements of the Water Framework Directive. However, the concurrent use of multiple organism groups provides a broader perspective for such evaluations, since each biological element may respond differently to certain environmental variables. In the present study, we assessed the ecological quality of a Greek river (RM4 type), during autumn 2003 and spring 2004 at 10 sites, with benthic macroinvertebrates and fish. Hydromorphological and physicochemical parameters, habitat structure, and riparian vegetation were also considered. Pollution sensitive macroinvertebrate taxa were more abundant at headwaters, which had good/excellent water quality according to the Hellenic Evaluation System (HES). The main river reaches possessed moderate water quality, while downstream sites were mainly characterised as having bad or poor water quality, dominated by pollution-tolerant macroinvertebrate taxa. Macroinvertebrates related strongly to local stressors as chemical degradation (ordination analysis CCA) and riparian quality impairment (bivariate analysis) while fish did not. Fish were absent from the severely impacted lower river reaches. Furthermore, external pathological signs were observed in fish caught at certain sites. A combined use of both macroinvertebrates and fish in biomonitoring programs is proposed for providing a safer assessment of local and regional habitat impairment.

Scaling issues in sustainable river basin management

NASA Astrophysics Data System (ADS)

Timmerman, Jos; Froebich, Jochen

2014-05-01

Sustainable river basin management implies considering the whole river basin when managing the water resources. Management measures target at dividing the water over different uses (nature, agriculture, industry, households) thereby avoiding calamities like having too much, too little or bad quality water. Water management measures are taken at the local level, usually considering the sub-national and sometimes national effects of such measures. A large part of the world's freshwater resources, however, is contained in river basins and groundwater systems that are shared by two or more countries. Sustainable river basin management consequently has to encompass local, regional, national and international scales. This requires coordination over and cooperation between these levels that is currently compressed into the term 'water governance' . Governance takes into account that a large number of stakeholders in different regimes (the principles, rules and procedures that steer management) contribute to policy and management of a resource. Governance includes the increasing importance of basically non-hierarchical modes of governing, where non-state actors (formal organizations like NGOs, private companies, consumer associations, etc.) participate in the formulation and implementation of public policy. Land use determines the run-off generation and use of irrigation water. Land use is increasingly determined by private sector initiatives at local scale. This is a complicating factor in the governance issue, as in comparison to former developments of large scale irrigation systems, planning institutions at state level have then less insight on actual water consumption. The water management regime of a basin consequently has to account for the different scales of water management and within these different scales with both state and non-state actors. The central elements of regimes include the policy setting (the policies and water management strategies), legal setting (national and international laws and agreements), the institutional setting (the formal networks), information management (the information collection and dissemination system), and financing systems (the public and private sources that cover the water management costs). These elements are usually designed for a specific level and are ideally aligned with the other levels. The presentation will go into detail on connecting the different elements of the water management regime between different levels as well as on the overarching governance issues that play a role and will present opportunities and limitations of the linking options.

Combining multitracing and 2D-modelling to identify the dynamic of heavy metals during flooding.

NASA Astrophysics Data System (ADS)

Hissler, C.; Hostache, R.; Matgen, P.; Tosheva, Z.; David, E.; Bates, P.; Stille, P.

2012-04-01

Recent years have seen a growing awareness of the wider environmental significance of the sediment loads transported by rivers and streams. This includes the importance of suspended sediment in transporting heavy metals and the potential for these trace elements to be desorbed from the particles to the solution. That threaten the water quality and can cause severe impacts in downstream areas like wetlands and floodplains. Contemporary data on the sediment loads of rivers provide clear evidence of significant recent changes in the sediment fluxes and of several rivers in response to human activities. For instance, Trace elements (including heavy metals) that are currently considered to be undisturbed by human activities and used as tracers of continental crust derived material have become more and more involved in industrial processes. Mathematical models validated by in situ experimentations are the only available tool to predict the consequences of natural as well as man-induced environmental changes and impacts on sediment dynamics. They are approximate representations of complex natural systems and the evaluation of a model with respect to its ability to reproduce multiple criteria and behaviour of a real system is still problematic. Interactions between modellers and experimentalists improve significantly the interpretation of the modelling output and led to formulate more realistic assumptions on the behaviour of natural systems. The geochemical information, which appeared to be non-correlated with the hydrological standard parameters, provides new information and contributes to give an "orthogonal view" on the hydrologic system behaviour. Regarding the recent development in geochemical tracer applications in models, the multi-tracer approach (natural vs anthropogenic; elemental concentration-isotopic signature-radionuclide activity) may be a necessity to decrease significantly the uncertainties in sediment transport modelling. The objective of this study is to assess the risk of floodplain contamination in heavy metal due to river sediment deposition and to heavy metal partitioning between particulate and dissolved phases. We focus on a multidisciplinary approach combining environmental geochemistry (multitracing) and hydraulic modelling (using TELEMAC-2D). One important single flood event was selected to illustrate this innovative approach. During the entire flood, the river water was sampled every hour in order to collect the particulate and the dissolved fractions. All the tracers were analyzed in both fractions. An important set of hydrological and sedimentological data are used to reach a more efficient calibration of the TELEMAC modelling system. In addition to standard techniques of hydrochemistry, new approaches of in situ suspended sediment transport monitoring will help getting new insights on the hydraulic system behaviour.

Elements of an environmental decision support system for seasonal wetland salt management in a river basin subjected to water quality regulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Quinn, N.W.T.

Seasonally managed wetlands in the Grasslands Basin on the west-side of California's San Joaquin Valley provide food and shelter for migratory wildfowl during winter months and sport for waterfowl hunters during the annual duck season. Surface water supply to these wetlands contain salt which, when drained to the San Joaquin River during the annual drawdown period, can negatively impact water quality and cause concern to downstream agricultural riparian water diverters. Recent environmental regulation, limiting discharges salinity to the San Joaquin River and primarily targeting agricultural non-point sources, now also targets return flows from seasonally managed wetlands. Real-time water quality managementmore » has been advocated as a means of continuously matching salt loads discharged from agricultural, wetland and municipal operations to the assimilative capacity of the San Joaquin River. Past attempts to build environmental monitoring and decision support systems (EDSS's) to implement this concept have enjoyed limited success for reasons that are discussed in this paper. These reasons are discussed in the context of more general challenges facing the successful implementation of a comprehensive environmental monitoring, modelling and decision support system for the San Joaquin River Basin.« less

Trace element fluxes in sediments of an environmentally impacted river from a coastal zone of Brazil.

PubMed

da Silva, Yuri Jacques Agra Bezerra; Cantalice, José Ramon Barros; Singh, Vijay P; do Nascimento, Clístenes Williams Araújo; Piscoya, Victor Casimiro; Guerra, Sérgio M S

2015-10-01

Data regarding trace element concentrations and fluxes in suspended sediments and bedload are scarce. To fill this gap and meet the international need to include polluted rivers in future world estimation of trace element fluxes, this study aimed to determine the trace element fluxes in suspended sediment and bedload of an environmentally impacted river in Brazil. Water, suspended sediment, and bedload from both the upstream and the downstream cross sections were collected. To collect both the suspended sediment and water samples, we used the US DH-48. Bedload measurements were carried out using the US BLH 84 sampler. Concentrations of Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn were determined by inductively coupled plasma (ICP-OES). As and Hg were determined by an atomic absorption spectrophotometer (AA-FIAS). The suspended sediments contributed more than 99 % of the trace element flux. By far Pb and to a less extent Zn at the downstream site represents major concerns. The yields of Pb and Zn in suspended sediments were 4.20 and 2.93 kg km(2) year(-1), respectively. These yields were higher than the values reported for Pb and Zn for Tuul River (highly impacted by mining activities), 1.60 and 1.30 kg km(2) year(-1), respectively, as well as the Pb yield (suspended + dissolved) to the sea of some Mediterranean rivers equal to 3.4 kg km(2) year(-1). Therefore, the highest flux and yield of Pb and Zn in Ipojuca River highlighted the importance to include medium and small rivers-often overlooked in global and regional studies-in the future estimation of world trace element fluxes in order to protect estuaries and coastal zones.

Natural curiosities of the Bug river valley near Janów Podlaski as a chance of the specialized tourism development

NASA Astrophysics Data System (ADS)

Kusznerczuk, Marta

2009-01-01

This paper presents the most precious natural curiosities of the Bug river valley near Janów Podlaski (between Zaczopki and Gnojno). This area is protected as the landscape park - "Podlasie Bug Water Gap". The natural abiotic elements, among others geomorphological ones significantly conditioning unrepeatable charms of the Bug river valley landscape, are regarded as marginal in many papers concerning the unique values of this valley. The presented natural curiosities are arranged in genetic and chronological order. These main relief elements of the Bug river valley are associated with different morphogenetic processes, i.e. the gap formation, the Bug river metamorphosis and gully erosion. These elements can be a chance of the development of specialised tourism, which will influence the economic mobilization of this undeveloped region.

Determination of trace elements in the reproduction systems of some rare animals using pixe

NASA Astrophysics Data System (ADS)

Suqing, Chen; Nengming, Wang; Jianxuan, Chen; Dazhong, Zhang

In order to search for the significance of artificial feeding, reproduction and heredity, trace elements in the reproductive systems of some rare animals, including giant panda, lesser panda, marmot and river deer, have been determined. Typcial X-ray spectra of various samples are given. The elemental contents in ovary and testis of the giant panda and the lesser panda are calculated by means of yttrium as an internal standard. Elemental relative concentrations are calculated from peak areas in the spectra for thick samples. It is found that for the concentration of the elements Cr, Mn, Fe, Ni, Cu, As in the ovary there exist no significant different between the giant panda and the lesser panda. The concentration of Zn, however, shows a remakable difference. The importance of zinc in biological processes is discussed.

Water Quality in Surface Water: A Preliminary Assessment of Heavy Metal Contamination of the Mashavera River, Georgia

PubMed Central

Urushadze, Teo

2018-01-01

Water quality contamination by heavy metal pollution has severe effects on public health. In the Mashavera River Basin, an important agricultural area for the national food system in Georgia (e.g., vegetable, dairy and wine production), water contamination has multiple influences on the regional and country-wide health. With new industrial activities in the region, sediment extraction, and discharge of untreated wastewater into the river, its tributaries and irrigation canals, a comprehensive study of water quality was greatly needed. This study examined sediment and water samples from 17 sampling sites in the Mashavera River Basin during the high and low precipitation seasons. The results were characterized utilizing the Geo-accumulation Index (Igeo), Enrichment Factor (EF), Pollution Load index (PLI), Contamination Factor (CF) and Metal Index (MI). According to the CFs, Cu > Cd > Zn > Pb > Fe > Mn > Ni > Cr > Hg is the descending order for the content of all observed heavy metals in sediments collected in both seasons. Fe and As were additionally examined in water samples. Overall, As, Cd and Pb, all highly toxic elements, were found in high concentrations in downstream sample sites. According to these results, comprehensive monitoring with narrow intervals between sampling dates, more sample sites along all waterways, and proximate observation of multiple trace metal elements are highly recommended. Moreover, as the part of the water quality governance system, an immediate and sustainable collective action by all stakeholders to control the pollution level is highly recommended, as this issue is linked to the security of the national food system and poses a local public health risk. PMID:29597320

7. OBLIQUE VIEW OF NORTH PORTAL AND DOWNSTREAM SIDE OF ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. OBLIQUE VIEW OF NORTH PORTAL AND DOWNSTREAM SIDE OF BRIDGE, LOOKING WEST. Lights and illuminated sign on portal bracing were elements of an overheight load warning system designed to eliminate accidents of the type which damaged the bridge. However, the system was in place only on the north side of the bridge, controlling trucks approaching from Oregon. In theory, trucks with overheight, overwidth, or overweight loads from California would be controlled by the State's permit system. In fact, it was a 'permit' load originating in California, being hauled without the requisite permit which struck and damaged the bridge. - Smith River Bridge, CA State Highway 199 Spanning Smith River, Crescent City, Del Norte County, CA

The Evolution of Riparian Landscape Elements Following Upstream Regulation and Depletion on the Rio Grande

NASA Astrophysics Data System (ADS)

Everitt, B. L.

2006-12-01

In 1915 closure of Elephant Butte Dam in central New Mexico profoundly altered the hydrologic regime of the Rio Grande for 560 km downstream, and set in motion a cascade of interwoven geomorphic, biological, and cultural responses. Geomorphic response included shrinking of the width and depth of the channel, and an increase in sinuosity. Cultural responses included artificial channel modification on 320 km of the river within the boundaries of the original irrigation project, beginning in 1933. The pre-dam river and its flood plain consisted of a mosaic of geomorphic elements that formed a functional riverine landscape, and founded a diverse habitat for the plants, animals, and people that lived there. A preliminary comparison of the modern river with pre-dam topographic mapping permits identification of individual landscape elements, including overflow land (flood plain) both cultivated and uncultivated, with oxbows and back-swamps. The pre-dam channel included a low water thread and un-vegetated flood bars. From pre-dam description and photographs we can assume the usual complement of pools and riffles, point bars and undercut banks. Until dredged in the 1970s, the unmodified reach retained the entire suite of landscape elements, although in somewhat different proportions from the pre-dam river, and remained a functional riparian system. Channel sinuosity increased from 1.45 in 1910 to 1.7 in 1970, thus riverbank habitat increased by 1.17%. In 1970 undercut banks still provided protection for fish, and point bars generated by lateral migration still provided seed beds for pioneer species. The smaller shallower channel raised groundwater beneath the flood plain and retarded flood waves, creating a generally more mesic environment, although the river occasionally dries up, as it did prior to 1915. In contrast, an impoverished suite of landscape elements characterizes the channelized reach. Lateral stability precludes point bars and undercut banks. Bounding levees separate the channel from its former flood plain. All areas are impacted by heavy machinery during periodic channel maintenance. I conclude that the environmental degradation caused by artificial channel modification has far outweighed any generated by upstream hydrologic control.

Wind River watershed restoration, annual report November 2009 to October 2010.

USGS Publications Warehouse

Connolly, P.J.; Jezorek, I.G.

2011-01-01

This report summarizes work completed by U.S. Geological Survey’s Columbia River Research Laboratory (USGS-CRRL) in the Wind River subbasin during the period November 2009 through October 2010 under Bonneville Power Administration (BPA) contract 46102. Long term research in the Wind River has focused on assessments of steelhead/rainbow trout Oncorhynchus mykiss populations, interactions with introduced populations of spring Chinook salmon O. tshawytscha and brook trout Salvelinus fontinalis, and influences of habitat variables and habitat restoration on fish productivity. During the period covered by this report, we collected water temperature data to characterize variation within and among tributaries and mainstem sections in the Trout Creek watershed, and assisted Washington Department of Fish and Wildlife (WDFW) with smolt trapping and tagging of smolt and parr steelhead with passive integrated transponder (PIT) tags. We also continued to maintain and test efficacy of a passive integrated transponder tag interrogation system (PTIS) in Trout Creek for assessing the adult steelhead runsize. A statement of work (SOW) was submitted to BPA in October 2009 that outlined work to be performed by USGS-CRRL. The SOW was organized by work elements, with each describing a research task. This report summarizes the progress completed under each work element.

Hydrothermal element fluxes from Copahue, Argentina: A "beehive" volcano in turmoil

USGS Publications Warehouse

Varekamp, J.C.; Ouimette, A.P.; Herman, S.W.; Bermudez, A.; Delpino, D.

2001-01-01

Copahue volcano erupted altered rock debris, siliceous dust, pyroclastic sulfur, and rare juvenile fragments between 1992 and 1995, and magmatic eruptions occurred in July-October 2000. Prior to 2000, the Copahue crater lake, acid hot springs, and rivers carried acid brines with compositions that reflected close to congruent rock dissolution. The ratio between rock-forming elements and chloride in the central zone of the volcano-hydrothermal system has diminished over the past few years, reflecting increased water/rock ratios as a result of progressive rock dissolution. Magmatic activity in 2000 provided fresh rocks for the acid fluids, resulting in higher ratios between rock-forming elements and chloride in the fluids and enhanced Mg fluxes. The higher Mg fluxes started several weeks prior to the eruption. Model data on the crater lake and river element flux determinations indicate that Copahue volcano was hollowed out at a rate of about 20 000-25 000 m3/yr, but that void space was filled with about equal amounts of silica and liquid elemental sulfur. The extensive rock dissolution has weakened the internal volcanic structure, making flank collapse a volcanic hazard at Copahue.

Study of distribution of halcophile elements in the Black Sea area adjacent to Chorokhi river mouth

NASA Astrophysics Data System (ADS)

Gvakharia, V.; Machitadze, N.; Khargelia, R.; Girgvliani, D.; Khukhunia, T.; Elashvili, M.

2003-04-01

The river Chorokhi catchment areacomprises the mountainous regions of north-east Turkey and south-west Georgia. The catchment area totals 2000 km2. Annual quantity of the drift according to the various reference data makes 7-11 mil t. Amount of the drift material is conditioned by warm, humid climate and abundance of precipitation which is related to high denudation indices. It is well known that within the last 15-20 years exploitation of the deposits (Murguli, Çayeli, Lahanos, etc.) located in Artvini District of Turkey expanded. The Artvini deposits represent continuation of the south Caucasian province and, by the structure and ore composition are close to the well known deposits in Georgia (Madneuli, Merisi, etc.). Geochemistry and metalogenesis of the latter is well known to Georgian scholars. Terrigeneous material accumulated in the limits of withering horizons of various type of sulphate deposits is notable for specific composition. They are characterized with high content of halcophile elements which, because of they toxicity impose the risk to river and sea ecosystems. In the limits of mentioned areas of the coastal zone and in the limits of Batumi sea port content of halcophile metals (Cu, Zn, Pb, As) and their distribution by grain fractions the river and sea bottom sediments has been studied. Positive correlation of the mentioned elements in the sea bottom sediments is revealed. As well as the river and in particular the sea bottom sediments are good indicators of heavy metal pollution. It should be noted that the impact of Chorokhi River on ecological status of the Black Sea is less studied. No complex studies of ecology of the Chorokhi River itself are performed. The study of ecological status of the Chorokhi River basin as transboundary region is of great importance because of expanding development of industries on the both sides of the border, which calls forth increase in the impact on environment. In order to evaluate the current ecological status of the system properly we deem expedient to elaborate international program with participation of experts from Turkey, Georgia and other states.

Nitrogen distribution in a tropical urbanized estuarine system in northeastern Brazil.

PubMed

Dos Santos, Celimarcos Bezerra; Silva, Maria Aparecida Macêdo; de Souza, Marcelo F Landim; da Silva, Daniela Mariano Lopes

2018-01-08

Nitrogen enters estuaries mostly through fluvial discharge and tide, although anthropogenic sources are known to influence the amount of this element in these aquatic ecosystems. Thus, the objective of this work was to verify which river (Cachoeira, Fundão, and/or Santana) exerts greater influence on the distribution of dissolved N forms (Dissolved Organic Nitrogen and Dissolved Inorganic Nitrogen = NH 3 /NH 4 + , NO 2 - , and NO 3 - ) along a tropical urbanized estuarine system in northeastern Brazil. The studies estuarine system lies with in urban municipality, and the upper portion of the Cachoeira river estuary receives the treated effluent from this municipality through a sewage treatment station and untreated effluents from nearby villages. The selected sampling stations were located near the outfall of the rivers in the estuaries to the treatment plant and the villages. Of all the nitrogen forms, dissolved organic nitrogen (DON) prevailed in the estuarine system, followed by nitrate (NO 3 - ) as the main inorganic form. The highest concentrations were recorded in the fluvial portion and upper estuary of Cachoeira river in the dry season. Based on the N concentrations found in the estuarine system, Cachoeira river has the greatest anthropogenic influence due to the amount of untreated effluents from the villages and treated effluents from the sewage treatment plant (STP) in the upper portion of the estuary.

Accumulated state of the Yukon River watershed: part I critical review of literature.

PubMed

Dubé, Monique G; Muldoon, Breda; Wilson, Julie; Maracle, Karonhiakta'tie Bryan

2013-07-01

A consistent methodology for assessing the accumulating effects of natural and manmade change on riverine systems has not been developed for a whole host of reasons including a lack of data, disagreement over core elements to consider, and complexity. Accumulated state assessments of aquatic systems is an integral component of watershed cumulative effects assessment. The Yukon River is the largest free flowing river in the world and is the fourth largest drainage basin in North America, draining 855,000 km(2) in Canada and the United States. Because of its remote location, it is considered pristine but little is known about its cumulative state. This review identified 7 "hot spot" areas in the Yukon River Basin including Lake Laberge, Yukon River at Dawson City, the Charley and Yukon River confluence, Porcupine and Yukon River confluence, Yukon River at the Dalton Highway Bridge, Tolovana River near Tolovana, and Tanana River at Fairbanks. Climate change, natural stressors, and anthropogenic stresses have resulted in accumulating changes including measurable levels of contaminants in surface waters and fish tissues, fish and human disease, changes in surface hydrology, as well as shifts in biogeochemical loads. This article is the first integrated accumulated state assessment for the Yukon River basin based on a literature review. It is the first part of a 2-part series. The second article (Dubé et al. 2013a, this issue) is a quantitative accumulated state assessment of the Yukon River Basin where hot spots and hot moments are assessed outside of a "normal" range of variability. Copyright © 2012 SETAC.

SAR data for river ice monitoring. How to meet requirements?

NASA Astrophysics Data System (ADS)

Łoś, Helena; Osińska-Skotak, Katarzyna; Pluto-Kossakowska, Joanna

2017-04-01

Although river ice is a natural element of rivers regime it can lead to severe problems such as winter floods or damages of bridges and bank revetments. Services that monitor river ice condition are still often based on field observation. For several year, however, Earth observation data have become of a great interest, especially SAR images, which allows to observe ice and river condition independently of clouds and sunlight. One of requirements of an effective monitoring system is frequent and regular data acquisition. To help to meet this requirement we assessed an impact of selected SAR data parameters into automatic ice types identification. Presented work consists of two parts. The first one focuses on comparison of C-band and X-band data in terms of the main ice type detection. The second part contains an analysis of polarisation reduction from quad-pol to dual-pol data. As the main element of data processing we chose the supervised classification with maximum likelihood algorithm adapted to Wishart distribution. The classification was preceded by statistical analysis of radar signal obtained for selected ice types including separability measures. Two river were selected as areas of interest - the Peace River in Canada and the Vistula in Poland. The results shows that using data registered in both bands similar accuracy of classification into main ice types can be obtain. Differences appear with details e.g. thin initial ice. Classification results obtained from quad-pol and dual-pol data were similar while four classes were selected. With six classes, however, differences between polarisation types have been noticed.

Plan of study to quantify the hydrologic relations between the Rio Grande and the Santa Fe Group aquifer system near Albuquerque, central New Mexico

USGS Publications Warehouse

McAda, D.P.

1996-01-01

The Albuquerque Basin in central New Mexico covers an area of about 3,060 square miles. Ground water from the Santa Fe Group aquifer system of the Albuquerque Basin is the principal source of water for municipal, domestic, commercial, and industrial uses in the Albuquerque area, an area of about 410 square miles. Ground- water withdrawal in the basin has increased from about 97,000 acre-feet in 1970 to about 171,000 acre-feet in 1994. About 92 percent of the 1994 total was withdrawn in the Albuquerque area. Management of ground water in the Albuquerque Basin is related to the surface water in the Rio Grande. Because the aquifer system is hydraulically connected to the Rio Grande and water in the river is fully appropriated, the ability to reliably estimate the effects of ground-water withdrawals on flow in the river is important. This report describes the components of the Rio Grande/Santa Fe Group aquifer system in the Albuquerque area and the data availability and data and interpretation needs relating to those components, and presents a plan of study to quantify the hydrologic relations between the Rio Grande and the Santa Fe Group aquifer system. The information needs related to the components of the river/aquifer system are prioritized. Information that is necessary to improve the understanding or quantification of a component in the river/aquifer system is prioritized as essential. Information that could add additional understanding of the system, but would not be necessary to improve the quantification of the system, is prioritized as useful. The study elements are prioritized in the same manner as the information needs; study elements designed to provide information considered necessary to improve the quantification of the system are prioritized as essential, and those designed to provide information that would add additional understanding of the system, but would not be necessary to improve the quantification of the system, are prioritized as useful.

Applying of factor analyses for determination of trace elements distribution in water from Vardar and its tributaries, Macedonia/Greece.

PubMed

Popov, Stanko Ilić; Stafilov, Trajče; Sajn, Robert; Tănăselia, Claudiu; Bačeva, Katerina

2014-01-01

A systematic study was carried out to investigate the distribution of fifty-six elements in the water samples from river Vardar (Republic of Macedonia and Greece) and its major tributaries. The samples were collected from 27 sampling sites. Analyses were performed by mass spectrometry with inductively coupled plasma (ICP-MS) and atomic emission spectrometry with inductively coupled plasma (ICP-AES). Cluster and R mode factor analysis (FA) was used to identify and characterise element associations and four associations of elements were determined by the method of multivariate statistics. Three factors represent the associations of elements that occur in the river water naturally while Factor 3 represents an anthropogenic association of the elements (Cd, Ga, In, Pb, Re, Tl, Cu, and Zn) introduced in the river waters from the waste waters from the mining and metallurgical activities in the country.

Distribution and Geochemistry of Rare-Earth Elements in Rivers of Southern and Eastern Primorye (Far East of Russia)

NASA Astrophysics Data System (ADS)

Chudaev, O. V.; Bragin, I. V.; A, Kharitonova N.; Chelnokov, G. A.

2016-03-01

The distribution and geochemistry of rare earth elements (REE) in anthropogenic, technogenic and natural surface waters of southern and eastern Primorye, Far East of Russia, are presented in this study. The obtained results indicated that most of REE (up to 70%) were transported as suspended matter, ratio between dissolved and suspended forms varing from the source to the mouth of rivers. It is shown that all REE (except Ce) in the source of the rivers are predominantly presented in dissolved form, however, the content of light and heavy REE is different. Short-term enrichment of light rare earth elements (LREE) caused by REE-rich runoff from waste dumps and mining is neutralized by the increase in river flow rate. Rivers in urban areas are characterized by high content of LREE in dissolved form and very low in suspended one.

Geochemical baseline studies and relations between water quality and streamflow in the upper Blackfoot Watershed, Montana: data for July 1997-December 1998

USGS Publications Warehouse

Nagorski, Sonia A.; Moore, Johnnie N.; Smith, David B.

2001-01-01

We used ultraclean sampling techniques to study the solute (operationally defined as <0.2 ?m) surface water geochemistry at five sites along the Upper Blackfoot River and four sites along the Landers Fork, some in more detail and more regularly than others. We collected samples also from Hogum Creek, a tributary to the Blackfoot, from Copper Creek, a tributary to the Landers Fork, and from ground water seeps contributing to the flow along the Landers Fork. To better define the physical dynamics of the hydrologic system and to determine geochemical loads, we measured streamflow at all the sites where we took samples for water quality analysis. The Upper Blackfoot River, which drains historic mines ca. 20 Km upstream of the study area, had higher trace metal concentrations than did the Landers Fork, which drains the pristine Scapegoat Wilderness area. In both rivers, many of the major elements were inversely related to streamflow, and at some sites, several show a hysteresis effect in which the concentrations were lower on the rising limb of the hydrograph than on the falling limb. However, many of the trace elements followed far more irregular trends, especially in the Blackfoot River. Elements such as As, Cu, Fe, Mn, S, and Zn exhibited complex and variable temporal patterns, which included almost no response to streamflow differences, increased concentrations following a summer storm and at the start of snowmelt in the spring, and/or increased concentrations throughout the course of spring runoff. In summary, complex interactions between the timing and magnitude of streamflow with physical and chemical processes within the watershed appeared to greatly influence the geochemistry at the sites, and streamflow values alone were not good predictors of solute concentrations in the rivers.

Dissolved Strontium and Barium in Fresh and Saltwater: a 2-year Study in the Calcasieu River to the Gulf of Mexico

NASA Astrophysics Data System (ADS)

He, S.; Xu, Y. J.

2016-02-01

Strontium and barium to calcium ratios are often used as proxies for tracking animal movement across salinity gradients. As sea level rise continues, many estuarine rivers face saltwater intrusion, which may cause changes in mobility and distribution of these metals upstream. Despite intensive research on metal adsorption and desorption in marine systems, knowledge of the spatiotemporal distribution of these elements along estuarine rivers is still limited. In this study, we conducted an intensive monitoring of Sr and Ba dynamics along an 88-km long estuary, the Calcasieu River, which has been strongly affected by saltwater intrusion. Over the period from May 2013 to July 2015, we collected monthly water samples and performed in-situ water quality measurements at six sites from the upstream to the river mouth. Water samples were analyzed for dissolved Sr, Ba, and Ca concentrations. In-situ measurements of salinity, pH, water temperature, dissolved oxygen concentration, and specific conductance were taken. Our preliminary data showed that the Sr and Ca concentrations and the Sr/Ca ratio all increased significantly with decreasing distance to the Gulf of Mexico, while the Ba/Ca ratio decreased with decreasing distance to the Gulf. The spatial variation in Ba concentration was marginal. The Sr and Ca concentrations and ratios were positively related to salinity, while Ba/Ca was negatively related to salinity. All the elemental concentrations and ratios had considerable seasonal and interannual variations. There were significant differences among sampling months for all the elemental concentrations and ratios (p<0.05), and there were significant differences among sampling years for the Sr and Ca concentrations and the Ba/Ca ratio (p<0.05).

Geochemical behaviour of dissolved trace elements in a monsoon-dominated tropical river basin, Southwestern India.

PubMed

Gurumurthy, G P; Balakrishna, K; Tripti, M; Audry, Stéphane; Riotte, Jean; Braun, J J; Udaya Shankar, H N

2014-04-01

The study presents a 3-year time series data on dissolved trace elements and rare earth elements (REEs) in a monsoon-dominated river basin, the Nethravati River in tropical Southwestern India. The river basin lies on the metamorphic transition boundary which separates the Peninsular Gneiss and Southern Granulitic province belonging to Archean and Tertiary-Quaternary period (Western Dharwar Craton). The basin lithology is mainly composed of granite gneiss, charnockite and metasediment. This study highlights the importance of time series data for better estimation of metal fluxes and to understand the geochemical behaviour of metals in a river basin. The dissolved trace elements show seasonality in the river water metal concentrations forming two distinct groups of metals. First group is composed of heavy metals and minor elements that show higher concentrations during dry season and lesser concentrations during the monsoon season. Second group is composed of metals belonging to lanthanides and actinides with higher concentration in the monsoon and lower concentrations during the dry season. Although the metal concentration of both the groups appears to be controlled by the discharge, there are important biogeochemical processes affecting their concentration. This includes redox reactions (for Fe, Mn, As, Mo, Ba and Ce) and pH-mediated adsorption/desorption reactions (for Ni, Co, Cr, Cu and REEs). The abundance of Fe and Mn oxyhydroxides as a result of redox processes could be driving the geochemical redistribution of metals in the river water. There is a Ce anomaly (Ce/Ce*) at different time periods, both negative and positive, in case of dissolved phase, whereas there is positive anomaly in the particulate and bed sediments. The Ce anomaly correlates with the variations in the dissolved oxygen indicating the redistribution of Ce between particulate and dissolved phase under acidic to neutral pH and lower concentrations of dissolved organic carbon. Unlike other tropical and major world rivers, the effect of organic complexation on metal variability is negligible in the Nethravati River water.

Sr and Nd isotopes of suspended sediments from rivers of the Amazon basin

NASA Astrophysics Data System (ADS)

Hatting, Karina; Santos, Roberto V.; Sondag, Francis

2014-05-01

The Rb-Sr and Sm-Nd isotopic systems are important tools to constrain the provenance of sediment load in river systems. This study presents the isotopic composition of Sr and Nd isotopes and major and minor elements in suspended sediments from the Marañón-Solimões, Amazonas and Beni-Madeira rivers. The data were used to constrain the source region of the sediments and to better understand the main seasonal and spatial transport processes within the basin based on the variations of the chemical and isotopic signals. They also allow establishing a relationship between sediment concentrations and flow rate values. The study presents data collected during a hydrological year between 2009 and 2010. The Marañón-Solimões River presents low Sr isotopic values (0.7090-0.7186), broad EpslonNd(0) range (-15.17 to -8.09) and Nd model (TDM) ages varying from 0.99 to 1.81 Ga. Sources of sediments to the Marañón-Solimões River include recent volcanic rocks in northern Peru and Ecuador, as well as rocks with long crustal residence time and carbonates from the Marañón Basin, Peru. The Beni-Madeira River has more radiogenic Sr isotope values (0.7255-0.7403), more negative EpslonNd(0) values (-20.46 to -10.47), and older Nd isotope model ages (from 1.40 to 2.35 Ga) when compared to the Marañón-Solimões River. These isotope data were related to the erosion of Paleozoic and Cenozoic foreland basins that are filled with Precambrian sediments derived from the Amazonian Craton. These basins are located in Bolivian Subandina Zone. The Amazon River presents intermediate isotopic values when compared to those found in the Marañón-Solimões and Beni-Madeira rivers. Its Sr isotope ratios range between 0.7193 and 0.7290, and its EpslonNd(0) values varies between -11.09 and -9.51. The Nd isotope model ages of the suspended sediments vary between 1.28 and 1.77 Ga. Concentrations of soluble and insoluble elements indicate a more intense weathering activity in sediments of the Beni-Madeira River. This river has a larger difference in the Sr isotopic composition between the diluted and solid phases, which has been assigned to the high level of weathering of its sediment source area. In the Beni-Madeira River sub-basin dominates weathering of silicate rocks, while in the Marañón-Solimões River sub-basin there also weathering of carbonate and evaporitic rocks.

Preliminary panoramic study of river calm muscle using neodymium:yttrium-aluminum-garnet (Nd: YAG) laser-induced breakdown spectroscopy (LIBS)

NASA Astrophysics Data System (ADS)

Idris, N.; Lahna, K.; Usmawanda, T. N.; Herman; Ramli, M.; Hedwig, R.; Marpaung, A. M.; Kurniawan, K. H.

2018-04-01

A wide coverage spectral investigation on the muscle of river calm sample has been carried out using laser-induced breakdown spectroscopy for examining the overall profile of the emission spectra from the produced plasma. The basic apparatus of LIBS system used is a Nd-YAG laser and wide coverage optical multichannel analyzer (OMA) system. The river clam samples used is collected from Panga River in Aceh Jaya Regency, Aceh, Indonesia up streaming in a mountain of Gunong Ujeun, which is used as a location of the intensive traditional mining activity. Assuming that heavy metal accumulated in the clam muscle, LIBS experiments were carried out on the muscle of the calm. The sample used was fresh muscle sliced and attached to a copper plate. Plasma was generated by focusing the laser beam on the sample surface under air surrounding gas at 1 atmosphere. It is found that there are only major elements of host organic, namely C, H, O, N and the minor element of salts can be detected from fresh the clam sample when using a high pulse laser energy under air surrounding at high pressure of 1 atmosphere. There is no emission lines from any metal can be detected. Several experimental parameters were explored to study the panoramic dynamic of the emission spectra. It is found that the lower energy and the lower pressure is better for obtaining better emission spectra showing the possibility for determination of the analyte.

Forms of trace arsenic, cesium, cadmium, and lead transported into river water for the irrigation of Japanese paddy rice fields

NASA Astrophysics Data System (ADS)

Nakaya, Shinji; Chi, Hai; Muroda, Kengo; Masuda, Harue

2018-06-01

In this study, we focus on the behavior of geogenic, toxic trace elements, particularly As, Cs, Cd, and Pb, during their transportation in two rivers for irrigation commonly used in monsoon Asia; one river originates from an active volcano, Mt. Asama, and the other originates from a currently inactive volcano, Yatsugatake Mountains in Nagano, Japan. These rivers were investigated to understand the role of river water as a pollutant of rice and other aquatic plants (via irrigation) and aquatic animals. The results indicated that the behavior of toxic trace elements in river water are likely controlled by their interactions with particulate Fe, Al, and Ti compounds. The majority of Pb and Cd is transported as particulate matter with Fe, Al, and Ti, while the majority of As is transported in the dissolved form, predominantly as arsenate, with low abundance of particulate matter. Cs is transported either as the dissolved form or as particulate matter in both rivers. The investigated elements are transported in the rivers as particulate and dissolved forms, and the ratio of these forms is controlled by the pH and presence of particulate Fe, Al, and Ti phases in the river water. With respect to Cs in both rivers, the parameter governing the concentration and transportation of Cs, in the bimodal form (i.e., particulate and dissolved forms), through the river possibly shifts from sorption to pH by particulate Fe-Al-Ti, according to the abrupt increase in the concentration of Cs in the river. The chemical attraction of particulate Fe-Al-Ti for Cs is weaker than that for Pb and Cd, indicating that the lower electronegativity of Cs weakens the chemical attraction on a colloid for the competitive sorption with the other trace elements. The different relationships between As and Fe in the river and in the irrigation water and soil water, as well as those in paddy rice, suggested that As in paddy rice is not directly derived from As in the irrigation water from the river under flooding.

Status of metal levels and their potential sources of contamination in Southeast Asian rivers.

PubMed

Chanpiwat, Penradee; Sthiannopkao, Suthipong

2014-01-01

To assess the concentration and status of metal contaminants in four major Southeast Asian river systems, water were collected from the Tonle Sap-Bassac Rivers (Cambodia), Citarum River (Indonesia), lower Chao Phraya River (Thailand), and Saigon River (Vietnam) in both dry and wet seasons. The target elements were Be, Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Ag, Cd, Ba, Tl, and Pb and the concentrations exceeded the background metal concentrations by 1- to 88-fold. This distinctly indicates enrichment by human urban area activities. The results of a normalization technique used to distinguish natural from enriched metal concentrations confirmed contamination by Al, Cd, Co, Mn, Ni, Pb, and Zn. Cluster analysis revealed the probable source of metals contamination in most sampling sites on all rivers studied to be anthropogenic, including industrial, commercial, and residential activities. Stable lead isotopes analyses applied to track the sources and pathways of anthropogenic lead furthermore confirmed that anthropogenic sources of metal contaminated these rivers. Discharges of wastewater from both industrial and household activities were major contributors of Pb into the rivers. Non-point sources, especially road runoff and street dust, also contributed contamination from Pb and other metals.

Assessment of potentially harmful elements pollution in the Calore River basin (Southern Italy).

PubMed

Zuzolo, Daniela; Cicchella, Domenico; Catani, Vittorio; Giaccio, Lucia; Guagliardi, Ilaria; Esposito, Libera; De Vivo, Benedetto

2017-06-01

The geographical distribution of concentration values for harmful elements was determined in the Campania region, Italy. The study area consists of the drainage basin of the River Calore, a tributary of the river Volturno, the largest Southern Italian river. The results provide reliable analytical data allowing a quantitative assessment of the trace element pollution threat to the ecosystem and human health. Altogether 562 stream sediment samples were collected at a sampling density of 1 site per 5 km 2 . All samples were air-dried, sieved to <100 mesh fraction and analyzed for 37 elements after an aqua regia extraction by a combination of ICP-AES and ICP-MS. In addition to elemental analysis, gamma-ray spectrometry data were collected (a total of 562 measurements) using a hand-held Scintrex GRS-500 spectrometer. Statistical analyses were performed to show the single-element distribution and the distribution of elemental association factor scores resulting from R-mode factor analyses. Maps showing element distributions were made using GeoDAS and ArcGIS software. Our study showed that, despite evidence from concentrations of many elements for enrichment over natural background values, the spatial distribution of major and trace elements in Calore River basin is determined mostly by geogenic factors. The southwestern area of the basin highlighted an enrichment of many elements potentially harmful for human health and other living organisms (Al, Fe, K, Na, As, Cd, La, Pb, Th, Tl, U); however, these anomalies are due to the presence of pyroclastic and alkaline volcanic lithologies. Even where sedimentary lithologies occur, many harmful elements (Co, Cr, Mn, Ni) showed high concentration levels due to natural origins. Conversely, a strong heavy metal contamination (Pb, Zn, Cu, Sb, Ag, Au, Hg), due to an anthropogenic contribution, is highlighted in many areas characterized by the presence of road junctions, urban settlements and industrial areas. The enrichment factor of these elements is 3-4 times higher than the background values. The southwestern area of the basin is characterized by a moderate/high degree of contamination, just where the two busiest roads of the area run and the highest concentration of industries occurs.

Rare earth elements in fine-grained sediments of major rivers from the high-standing island of Taiwan

NASA Astrophysics Data System (ADS)

Li, Chuan-Shun; Shi, Xue-Fa; Kao, Shuh-Ji; Liu, Yan-Guang; Lyu, Hua-Hua; Zou, Jian-Jun; Liu, Sheng-Fa; Qiao, Shu-Qing

2013-06-01

Thirty-eight sediment samples from 15 primary rivers on Taiwan were retrieved to characterize the rare earth element (REE) signature of fluvial fine sediment sources. Compared to the three large rivers on the Chinese mainland, distinct differences were observed in the REE contents, upper continental crust normalized patterns and fractionation factors of the sediment samples. The average REE concentrations of the Taiwanese river sediments are higher than those of the Changjiang and Huanghe, but lower than the Zhujiang. Light rare earth elements (LREEs) are enriched relative to heavy rare earth elements (HREEs) with ratios from 7.48 to 13.03. We found that the variations in (La/Lu)UCC-(Gd/Lu)UCC and (La/Yb)UCC-(Gd/Yb)UCC are good proxies for tracing the source sediments of Taiwanese and Chinese rivers due to their distinguishable values. Our analyses indicate that the REE compositions of Taiwanese river sediments were primarily determined by the properties of the bedrock, and the intensity of chemical weathering in the drainage areas. The relatively high relief and heavy rainfall also have caused the REEs in the fluvial sediments from Taiwan to be transported to the estuaries down rivers from the mountains, and in turn delivered nearly coincidently to the adjacent seas by currents and waves. Our studies suggest that the REE patterns of the river sediments from Taiwan are distinguishable from those from the other sources of sediments transported into the adjacent seas, and therefore are useful proxies for tracing the provenances and dispersal patterns of sediments, as well as paleoenvironmental changes in the marginal seas.

Rare earth elements in river waters

NASA Technical Reports Server (NTRS)

Goldstein, Steven J.; Jacobsen, Stein B.

1988-01-01

To characterize the input to the oceans of rare earth elements (REE) in the dissolved and the suspended loads of rivers, the REE concentrations were measured in samples of Amazon, Indus, Mississippi, Murray-Darling, and Ohio rivers and in samples of smaller rivers that had more distinct drainage basin lithology and water chemistry. It was found that, in the suspended loads of small rivers, the REE pattern was dependent on drainage basin geology, whereas the suspended loads in major rivers had relatively uniform REE patterns and were heavy-REE depleted relative to the North American Shale composite (NASC). The dissolved loads in the five major rivers had marked relative heavy-REE enrichments, relative to the NASC and the suspended material, with the (La/Yb)N ratio of about 0.4 (as compared with the ratio of about 1.9 in suspended loads).

Improving catchment scale water quality modelling with continuous high resolution monitoring of metals in runoff

NASA Astrophysics Data System (ADS)

Saari, Markus; Rossi, Pekka; Blomberg von der Geest, Kalle; Mäkinen, Ari; Postila, Heini; Marttila, Hannu

2017-04-01

High metal concentrations in natural waters is one of the key environmental and health problems globally. Continuous in-situ analysis of metals from runoff water is technically challenging but essential for the better understanding of processes which lead to pollutant transport. Currently, typical analytical methods for monitoring elements in liquids are off-line laboratory methods such as ICP-OES (Inductively Coupled Plasma Optical Emission Spectroscopy) and ICP-MS (ICP combined with a mass spectrometer). Disadvantage of the both techniques is time consuming sample collection, preparation, and off-line analysis at laboratory conditions. Thus use of these techniques lack possibility for real-time monitoring of element transport. We combined a novel high resolution on-line metal concentration monitoring with catchment scale physical hydrological modelling in Mustijoki river in Southern Finland in order to study dynamics of processes and form a predictive warning system for leaching of metals. A novel on-line measurement technique based on micro plasma emission spectroscopy (MPES) is tested for on-line detection of selected elements (e.g. Na, Mg, Al, K, Ca, Fe, Ni, Cu, Cd and Pb) in runoff waters. The preliminary results indicate that MPES can sufficiently detect and monitor metal concentrations from river water. Water and Soil Assessment Tool (SWAT) catchment scale model was further calibrated with high resolution metal concentration data. We show that by combining high resolution monitoring and catchment scale physical based modelling, further process studies and creation of early warning systems, for example to optimization of drinking water uptake from rivers, can be achieved.

Geomorphic response to tectonically-induced ground deformation in the Wabash Valley

USGS Publications Warehouse

Fraser, G.S.; Thompson, T.A.; Olyphant, G.A.; Furer, L.; Bennett, S.W.

1997-01-01

Numerous low- to moderate-intensity earthquakes have been recorded in a zone of diffuse modern seismicity in southwest Indiana, southeast Illinois, and northernmost Kentucky. Structural elements within the zone include the Wabash Valley Fault System, the LaSalle Anticlinal Belt in western Illinois, and the Rough Creek-Shawneetown Fault System in northern Kentucky. The presence of seismically-induced liquefaction features in the near-surface alluvial sediments in the region indicates that strong ground motion has occurred in the recent geological past, but because the glacial and alluvial sediments in the Wabash Valley appear to be otherwise undisturbed, post-Paleozoic ground deformation resulting from movement on these structural elements has not yet been documented. Morphometric analysis of the land surface, detailed mapping of geomorphic elements in the valley, reconnaissance drilling of the Holocene and Pleistocene alluvium, and structural analysis of the bedrock underlying the valley were used to determine whether the geomorphology of the valley and the patterns of alluviation of the Wabash River were affected by surface deformation associated with the seismic zone during the late Pleistocene and Holocene. Among the observed features in the valley that can be attributed to deformation are: (1) tilting of the modern land surface to the west, (2) preferred channel migration toward the west side of the valley, with concomitant impact on patterns of soil development and sedimentation rate, (3) a convex longitudinal profile of the Wabash River where it crosses the LaSalle Anticlinal Belt, and (4) increased incision of the river into its floodplain downstream from the anticlinal belt.

Dissolved trace elements in a nitrogen-polluted river near to the Liaodong Bay in Northeast China.

PubMed

Bu, Hongmei; Song, Xianfang; Guo, Fen

2017-01-15

Dissolved trace element concentrations (Ba, Fe, Mn, Si, Sr, and Zn) were investigated in the Haicheng River near to the Liaodong Bay in Northeast China during 2010. Dissolved Ba, Fe, Mn, and Sr showed significant spatial variation, whereas dissolved Fe, Mn, and Zn displayed seasonal variations. Conditions such as water temperature, pH, and dissolved oxygen were found to have an important impact on redox reactions involving dissolved Ba, Fe, and Zn. Dissolved Fe and Mn concentrations were regulated by adsorption or desorption of Fe/Mn oxyhydroxides and the effects of organic carbon complexation on dissolved Ba and Sr were found to be significant. The sources of dissolved trace elements were found to be mainly from domestic sewage, industrial waste, agricultural surface runoff, and natural origin, with estimated seasonal and annual river fluxes established as important inputs of dissolved trace elements from the Haicheng River into the Liaodong Bay or Bohai Sea. Copyright © 2016 Elsevier Ltd. All rights reserved.

Multivariate analysis for source identification of pollution in sediment of Linggi River, Malaysia.

PubMed

Elias, Md Suhaimi; Ibrahim, Shariff; Samuding, Kamarudin; Rahman, Shamsiah Ab; Wo, Yii Mei; Daung, Jeremy Andy Dominic

2018-03-29

Rapid socioeconomic development in the Linggi River Basin has contributed to the significant increase of pollution discharge into the Linggi River and its adjacent coastal areas. The toxic element contents and distributions in the sediment samples collected along the Linggi River were determined using neutron activation analysis (NAA) and inductively coupled plasma-mass spectrometry (ICP-MS) techniques. The measured mean concentration of As, Cd, Pb, Sb, U, Th and Zn is relatively higher compared to the continental crust value of the respective element. Most of the elements (As, Cr, Fe, Pb, Sb and Zn) exceeded the freshwater sediment quality guideline-threshold effect concentration (FSQG-TEC) value. Downstream stations of the Linggi River showed that As concentrations in sediment exceeded the freshwater sediment quality guideline-probable effect concentration (FSQG-PEC) value. This indicates that the concentration of As will give an adverse effect to the growth of sediment-dwelling organisms. Generally, the Linggi River sediment can be categorised as unpolluted to strongly polluted and unpolluted to strongly to extremely polluted. The correlation matrix of metal-metal relationship, principle component analysis (PCA) and cluster analysis (CA) indicates that the pollution sources of Cu, Ni, Zn, Cd and Pb in sediments of the Linggi River originated from the industry of electronics and electroplating. Elements of As, Cr, Sb and Fe mainly originated from motor-vehicle workshops and metal work, whilst U and Th originated from natural processes such as terrestrial runoff and land erosion.

The influence of the Amazonian floodplain ecosystems on the trace element dynamics of the Amazon River mainstem (Brazil).

PubMed

Viers, Jérôme; Barroux, Guénaël; Pinelli, Marcello; Seyler, Patrick; Oliva, Priscia; Dupré, Bernard; Boaventura, Geraldo Resende

2005-03-01

The purpose of this paper is to forecast the role of riverine wetlands in the transfer of trace elements. One of the largest riverine wetlands in the world is the floodplain (várzea) of the Amazon River and its tributaries (Junk and Piedade, 1997). The central Amazon wetlands are constituted by a complex network of lakes and floodplains, named várzeas, that extend over more than 300,000 km2 (Junk, W.J., The Amazon floodplain--a sink or source for organic carbon? In Transport of Carbon and Minerals in Major World Rivers, edited by E.T. Degens, S. Kempe, R. Herrera, SCOPE/UNEP; 267-283, 1985.) and are among the most productive ecosystems in the world due to the regular enrichment in nutrients by river waters In order to understand if the adjacent floodplain of Amazon River have a significant influence on the trace element concentrations and fluxes of the mainstem, the concentrations of selected elements (i.e., Al, Mn, Fe, Co, Cu, Mo, Rb, Sr, Ba, and U) have been measured in the Amazon River water (Manacapuru Station, Amazonas State, Brazil) and in lake waters and plants (leaves) from a várzea(Ilha de Marchantaria, Amazonas State, Brazil) during different periods of the hydrological cycle. Four plant species (two perennial species: Pseudobombax munguba and Salix humboldtiana, and two annual herbaceous plants: Echinochloa polystachya and Eichhornia crassipes) were selected to represent the ecological functioning of the site. Time series obtained for dissolved Mn and Cu (<0.20 microm) in Amazon River water could not be explained by tributary mixing or instream processes only. Therefore, the contribution of the waters transiting the floodplains should be considered. These results suggest that the chemical composition of the waters draining these floodplains is controlled by reactions occurring at sediment-water and plant-water interfaces. Trace elements concentrations in the plants (leaves) vary strongly with hydrological seasonality. Based on the concentration data and the biological productivity of floodplain ecosystems, a first order approximation of trace element storage (permanent or temporary) in the vegetation of these floodplains was made. It was found that floodplain-mainstem elemental fluxes make a significant contribution to the dissolved flux of the Amazon River. This study is part of the Brazilian_French joint research program Hybam (Hydrology and Geochemistry of the Amazonian Basin).

Radioactivity in the environment; a case study of the Puerco and Little Colorado River basins, Arizona and New Mexico

USGS Publications Warehouse

Wirt, Laurie

1994-01-01

This report, written for the nontechnical reader, summarizes the results of a study from 1988-91 of the occurrence and transport of selected radionuclides and other chemical constituents in the Puerco and Little Colorado River basins, Arizona and New Mexico. More than two decades of uranium mining and the 1979 failure of an earthen dam containing mine tailings released high levels of radionuclides and other chemical constituents to the Puerco River, a tributary of the Little Colorado River. Releases caused public concern that ground water and streamflow downstream from mining were contaminated. Study findings show which radioactive elements are present, how these elements are distributed between water and sediment in the environment, how concentrations of radioactive elements vary naturally within basins, and how levels of radioactivity have changed since the end of mining. Although levels of radioactive elements and other trace elements measured in streamflow commonly exceed drinking-water standards, no evidence was found to indicate that the high concentrations were still related to uraniurn mining. Sediment radioactivity was higher at sample sites on streams that drain the eastern part of the Little Colorado River basin than that of samples from the western part. Radioactivity of suspended sediment measured in this study, therefore, represents natural conditions for the streams sampled rather than an effect of mining. Because ground water beneath the Puerco River channel is shallow, the aquifer is vulnerable to contamination. A narrow zone of ground water beneath the Puerco River containing elevated uranium concentrations was identified during the study. The highest concentrations were nearest the mines and in samples collected in the first few feet beneath the streambed. Natuxal radiation levels in a few areas of the underlying sedimentary aquifer not connected to the Puerco River also exceeded water quality standards. Water testing would enable those residents not using public water supplies to determine if their water is safe to use.

Aged organic carbon exported from the eastern margin of Tibetan Plateau

NASA Astrophysics Data System (ADS)

Wang, Jin; Hilton, Robert; Jin, Zhangdong; Zhang, Fei; Densmore, Alexander; Gröcke, Darren; Xu, Xiaomei; Feng, Xiaojuan

2017-04-01

Erosion of particulate organic carbon from the terrestrial biosphere (POCbiosphere) and sedimentary rocks (POCpetro) plays an important role in the global carbon cycle across a range of timescales. Knowledge of the age of POCbiosphere is of first order importance. Discharge of young POCbiosphere (i.e. decades old) by rivers is an export of recent productivity which is not well captured in ecosystem carbon budgets. Older POCbiosphere (centuries to millennia in age) can be eroded from deeper soils. If this aged POCbiosphere is oxidised during river transport, it represents a source of CO2 to the modern atmosphere. Previous work on the major Himalayan rivers has identified old POCbiosphere sourced from high elevations in the Tibetan Plateau, yet its regional significance remains unclear. Here we attempt to quantify the source of POC and age of POCbiosphere carried by rivers draining the eastern margin of Tibet. Using suspended sediment samples from 6 river gauging stations in the Min Jiang from 2005 to 2012, we measured the elemental composition (%OC and %N) and carbon isotopes (12C, 13C, 14C). In contrast to many other rivers, we find that the POCpetro is characterized by a large range of stable carbon isotope ratios, ranging from -26.2‰ to -13.2‰Ṫhis mixes with POCbiosphere and sets the bulk isotopic and elemental geochemistry. Using the radiocarbon content and an end member mixing model, we estimate that the age of POCbiosphereranged from modern to over 3000 14C years. Data from the high elevation tributaries of the Min Jiang support the notion that aged POCbiosphere is supplied into rivers draining the Tibetan Plateau. The annual POCbiosphere yields are significant (from 0.2 to 3.1 tC km-2 yr-1) and are set by the frequency of intense runoff events. Overall, our study highlights the need to better quantify the age of POCbiosphere in rivers and its fate in the river system.

Trace Elements in Bed Sediments and Biota from Streams in the Santee River Basin and Coastal Drainages, North and South Carolina, 1995-97

Treesearch

Thomas A. Abrahamsen

1999-01-01

Bed-sediment and tissue samples were collected and analyzed for the presence of trace elements from 25 sites in the Santee River Basin and coastal drainages study area during 1995-97 as part of the U.S. Geological Survey's National Water-Quality Assessment Program, Sediment trace-element priority-pollutant concentrations were compared among streams draining water-...

STUDY OF MERCURY OXIDATION BY SCR CATALYST IN AN ENTRAINED-FLOW REACTOR UNDER SIMULATED PRB CONDITIONS

EPA Science Inventory

A bench-scale entrained-flow reactor system was constructed for studying elemental mercury oxidation under selective catalytic reduction (SCR) reaction conditions. Simulated flue gas was doped with fly ash collected from a subbituminous Powder River Basin (PRB) coal-fired boiler ...

Integrated Hydro-geomorphological Monitoring System of the Upper Bussento river basin (Cilento and Vallo Diano Geopark, S-Italy)

NASA Astrophysics Data System (ADS)

Guida, D.; Cuomo, A.; Longobardi, A.; Villani, P.; Guida, M.; Guadagnuolo, D.; Cestari, A.; Siervo, V.; Benevento, G.; Sorvino, S.; Doto, R.; Verrone, M.; De Vita, A.; Aloia, A.; Positano, P.

2012-04-01

The Mediterranean river ecosystem functionings are supported by river-aquifer interactions. The assessment of their ecological services requires interdisciplinary scientific approaches, integrate monitoring systems and inter-institutional planning and management. This poster illustrates the Hydro-geomorphological Monitoring System build-up in the Upper Bussento river basin by the University of Salerno, in agreement with the local Basin Autorities and in extension to the other river basins located in the Cilento and Vallo Diano National Park (southern Italy), recently accepted in the European Geopark Network. The Monitoring System is based on a hierarchical Hydro-geomorphological Model (HGM), improved in a multiscale, nested and object-oriented Hydro-geomorphological Informative System (HGIS, Figure 1). Hydro-objects are topologically linked and functionally bounded by Hydro-elements at various levels of homogeneity (Table 1). Spatial Hydro-geomorpho-system, HG-complex and HG-unit support respectively areal Hydro-objects, as basin, sector and catchment and linear Hydro-objects, as river, segment, reach and section. Runoff initiation points, springs, disappearing points, junctions, gaining and water losing points complete the Hydro-systems. An automatic procedure use the Pfafstetter coding to hierarchically divide a terrain into arbitrarily small hydro-geomorphological units (basin, interfluve, headwater and no-contribution areas, each with a unique label with hierarchical topological properties. To obtain a hierarchy of hydro-geomorphological units, the method is then applied recursively on each basin and interbasin, and labels of the subdivided regions are appended to the existing label of the original region. The monitoring stations are ranked consequently in main, secondary, temporary and random and located progressively at the points or sections representative for the hydro-geomorphological responses by validation control and modeling calibration. The datasets are organized into a relational geodatabase supporting tracer testings, space-time analysis and hydrological modeling. At the moment, three main station for hourly streamflow measurements are located at the terminal sections of the main basin and the two main sub-basin; secondary stations for weekly discharge measurements are located along the Upper Bussento river segment, upstream and downstream of each river reach or tributary catchments or karst spring inflow. Temporary stations are located in the representative sections of the catchments to detect stream flow losses into alluvial beds or experimental parcels in the bare karst and forested sandstone headwaters. Streamflow measurements are combined with geochemical survey and water sampling for Radon activity concentration measurements. Results of measurement campains in Radon space-time distribution within the basin are given in other contribution of same EGU session. Monitoring results confirm the hourly, daily, weekly and monthly hydrological data and validate outcomes of semi-distributed hydrological models based on previously time series, allowing both academic consultants and institutional subject to extend the Integrated Hydro-geomorphological Monitoring System to the surrounding drainage areas of the Cilento and Vallo di Diano Geopark. Keywords: River-aquifer interaction, Upper Bussento river basin, monitoring system, hydro-geomorphology, semi-distributed hydrological model. Table 1: Comparative, hierarchical Hydro-morpho-climate entities Hierarchy levelArea (Km2) Scale Orography Entity Climate Entity Morfological Entity Areal Drainage Entity Linear Drainage Entity VIII 106 1:15E6 Orogen Macroscale α Morphological Region Hydrological Region VII 105 1:10E6 Chain Sistem Macroscale β Morphological Province Hydrological Province VI 104 1:5E5 Chain Mesoscale α Morphological Sistem Basin River V 103 1:2,5E5Chain Segment Mesoscale β Morphological Sub-systemSub-Basin Torrent IV 100 1:1,0E5Orographic Group Mesoscale γ Morphological Complex Basin Sector Mid Order Channel/ Segment III 10 1: 5E4 Orographic System Microscale αMorphological Unit Watershed Low Order Channel/ Reach II 1 1:2,5E3Orographic ComplexMicroscale βMorphological ComponentCatchment Transient Channel/ Pool I 10-2 1:5E3 Orographic Unit Microscale γMorphological Element Hollow Zero Order Channel PIC

12. LOG FOUNDATION ELEMENTS OF THE SAWMILL ADJACENT TO THE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. LOG FOUNDATION ELEMENTS OF THE SAWMILL ADJACENT TO THE CANAL, LOOKING EAST. BARREN AREA IN FOREGROUND IS DECOMPOSING SAWDUST. DIRT PILE IN BACKGROUND IS THE EDGE OF THE SUMMIT COUNTY LANDFILL. - Snake River Ditch, Headgate on north bank of Snake River, Dillon, Summit County, CO

Vertical Subsurface Flow Mixing and Horizontal Anisotropy in Coarse Fluvial Aquifers: Structural Aspects

NASA Astrophysics Data System (ADS)

Huggenberger, P.; Huber, E.

2014-12-01

Detailed descriptions of the subsurface heterogeneities in coarse fluvial aquifer gravel often lack in concepts to distinguish between the essence and the noise of a permeability structure and the ability to extrapolate site specific hydraulic information at the tens to several hundred meters scale. At this scale the heterogeneity strongly influences the anisotropies of the flow field and the mixing processes in groundwater. However, in many hydrogeological models the complexity of natural systems is oversimplified. Understanding the link between the dynamics of the surface processes of braided-river systems and the resulting subsurface sedimentary structures is the key to characterizing the complexity of horizontal and vertical mixing processes in groundwater. From the different depositional elements of coarse braided-river systems, the largest permeability contrasts can be observed in the scour-fills. Other elements (e.g. different types of gravel sheets) show much smaller variabilities and could be considered as a kind of matrix. Field experiments on the river Tagliamento (Northeast Italy) based on morphological observation and ground-penetrating radar (GPR) surveys, as well as outcrop analyses of gravel pit exposures (Switzerland) allowed us to define the shape, sizes, spatial distribution and preservation potential of scour-fills. In vertical sections (e.g. 2D GPR data, vertical outcrop), the spatial density of remnant erosional bounding surfaces of scours is an indicator for the dynamics of the braided-river system (lateral mobility of the active floodplain, rate of sediment net deposition and spatial distribution of the confluence scours). In case of combined low aggradation rate and low lateral mobility the deposits may be dominated by a complex overprinting of scour-fills. The delineation of the erosional bounding surfaces, that are coherent over the survey area, is based on the identification of angular discontinuities of the reflectors. Fence diagrams and horizontal time-slices from GPR data are used to construct simplified 3D hydraulic properties distribution models and to derive anisotropy patterns. On the basis of this work, conceptual models could be designed and implemented into numerical models to simulate the flow field and mixing in heterogeneous braided-river deposits.

Chemical fractionation of radionuclides and stable elements in aquatic plants of the Yenisei River.

PubMed

Bolsunovsky, Alexander

2011-09-01

The Yenisei River is contaminated with artificial radionuclides released by one of the Russian nuclear plants. The aquatic plants growing in the radioactively contaminated parts of the river contain artificial radionuclides. The aim of the study was to investigate accumulation of artificial radionuclides and stable elements by submerged plants of the Yenisei River and estimate the strength of their binding to plant biomass by using a new sequential extraction scheme. The aquatic plants sampled were: Potamogeton lucens, Fontinalis antipyretica, and Batrachium kauffmanii. Gamma-spectrometric analysis of the samples of aquatic plants has revealed more than 20 radionuclides. We also investigated the chemical fractionation of radionuclides and stable elements in the biomass and rated radionuclides and stable elements based on their distribution in biomass. The greatest number of radionuclides strongly bound to biomass cell structures was found for Potamogeton lucens and the smallest for Batrachium kauffmanii. For Fontinalis antipyretica, the number of distribution patterns that were similar for both radioactive isotopes and their stable counterparts was greater than for the other studied species. The transuranic elements (239)Np and (241)Am were found in the intracellular fraction of the biomass, and this suggested their active accumulation by the plants.

Transfer of chemical elements from a contaminated estuarine sediment to river water. A leaching assay

NASA Astrophysics Data System (ADS)

Abreu, Manuela; Peres, Sara; Magalhães, M. Clara F.

2014-05-01

Wastes of a former Portuguese steel industry were deposited during 40 years on the left bank of the Coina River, which flows into the estuary of the Tagus River near Lisbon. The aim of this study was to evaluate the release of the chemical elements from the contaminated sediment to the river water. A leaching experiment (four replicates) was performed using 1.6 kg/replicate of sediment from a landfill located in the Coina River bank, forming a lagoon subject to tidal influence. River water coming from this lagoon was collected during low tide. This water (200 mL) was added to the moist sediment, contained in cylindrical reactors, and was collected after 24 h of percolation. The leaching experiments were conducted for 77 days being leachates collected at time zero, after 28, 49 and 77 days with the sediment always moist. The sediment was characterized for: pH, electric conductivity (EC), total organic carbon (TOC), extractable phosphorus and potassium, mineral nitrogen, iron from iron oxides (crystalline and non-crystalline) and manganese oxides. Multi-elemental analysis was also made by ICP-INAA. Leachates and river water were analysed for pH, EC, hydrogencarbonate and sulfatetot by titrations, chloride by potentiometry, and multi-elemental composition by ICP-MS. The sediment presented pH=7.2, EC=18.5 dS/m, TOC=147.8 g/kg, high concentrations of extractable phosphorous (62.8 mg/kg) and potassium (1236.8 mg/kg), mineral nitrogen=11.3 mg/kg. The non-crystalline fraction of iron oxides corresponds to 99% (167.5 g Fe/kg) of the total iron oxides, and manganese from manganese oxides was low (52.7 mg/kg). Sediment is considered contaminated. It contained high concentrations (g/kg) of Zn (2.9), Pb (0.9), Cr (0.59), Cu (0.16), As (0.07), Cd (0.005), and Hg (0.001), which are above Canadian values for marine sediments quality guidelines for protection of aquatic life. River water had: pH=8.2, EC=28.6 dS/m, csulfate=1.23 g/L, and [Cl-]=251.6 mg/L. The concentrations of Cd (0.001 mg/L) and Hg (0.02 mg/L) were above Canadian water quality guidelines for protection of aquatic life. Leachates had pH≡7.9 and EC=38.7 dS/m (mean values), and high concentrations of hydrogencarbonate (723.7 mg/L), sulfatetot (1.8 g/L) and chloride (252.2 mg/L). Over the experiment, only pH (7.6-8.0) and EC (35.7-55.2 dS/m) values showed statistical differences, increasing over time. Regarding multi-elemental contamination, statistical differences were found between some elements concentrations (Co, Cu, Cr, Mn, Ni, Sb, U, V, W, Zn) in the leachates/kg of sediment collected after river water percolation in the four periods. However, only the concentrations of Ni (4.7-9.2 µg/kg), Sb (0.08-0.14 µg/kg), W (0.16-1.1 µg/kg) and Zn (1.72-5.74 µg/kg) have increased. The concentration of the elements in the leachates when compared to the same elements concentration in the sediments corresponds to a fraction lower than 1%. When comparing the concentrations of the elements in the leachates and in the river water used for sediments leaching, the values in leachates are in general lower, being the highest obtained for Ni, W and U, which correspond to 62, 61 and 50% of the river water values, respectively. Chemical elements transfer from sediments to river water can be considered very low.

Synthetic river valleys: Creating prescribed topography for form-process inquiry and river rehabilitation design

NASA Astrophysics Data System (ADS)

Brown, R. A.; Pasternack, G. B.; Wallender, W. W.

2014-06-01

The synthesis of artificial landforms is complementary to geomorphic analysis because it affords a reflection on both the characteristics and intrinsic formative processes of real world conditions. Moreover, the applied terminus of geomorphic theory is commonly manifested in the engineering and rehabilitation of riverine landforms where the goal is to create specific processes associated with specific morphology. To date, the synthesis of river topography has been explored outside of geomorphology through artistic renderings, computer science applications, and river rehabilitation design; while within geomorphology it has been explored using morphodynamic modeling, such as one-dimensional simulation of river reach profiles, two-dimensional simulation of river networks, and three-dimensional simulation of subreach scale river morphology. To date, no approach allows geomorphologists, engineers, or river rehabilitation practitioners to create landforms of prescribed conditions. In this paper a method for creating topography of synthetic river valleys is introduced that utilizes a theoretical framework that draws from fluvial geomorphology, computer science, and geometric modeling. Such a method would be valuable to geomorphologists in understanding form-process linkages as well as to engineers and river rehabilitation practitioners in developing design surfaces that can be rapidly iterated. The method introduced herein relies on the discretization of river valley topography into geometric elements associated with overlapping and orthogonal two-dimensional planes such as the planform, profile, and cross section that are represented by mathematical functions, termed geometric element equations. Topographic surfaces can be parameterized independently or dependently using a geomorphic covariance structure between the spatial series of geometric element equations. To illustrate the approach and overall model flexibility examples are provided that are associated with mountain, lowland, and hybrid synthetic river valleys. To conclude, recommended advances such as multithread channels are discussed along with potential applications.

Surface-water/ground-water interaction of the Spokane River and the Spokane Valley/Rathdrum Prairie aquifer, Idaho and Washington

USGS Publications Warehouse

Caldwell, Rodney R.; Bowers, Craig L.

2003-01-01

Although trace-element concentrations sometimes exceeded aquatic-life criteria in the water of the Spokane River and were elevated above national median values in the bed sediment, trace-element concentrations of all river and ground-water samples were at levels less than U.S. Environmental Protection Agency drinking-water standards. The Spokane River appears to be a source of cadmium, copper, zinc, and possibly lead in the near-river ground water. Dissolved cadmium, copper, and lead concentrations generally were less than 1 microgram per liter (µg/L) in the river water and ground water. During water year 2001, dissolved zinc concentrations were similar in water from near-river wells (17-71 µg/L) and the river water (22-66 µg/L), but were less than detection levels in wells farther from the river. Arsenic, found to be elevated in ground water in parts of the aquifer, does not appear to have a river source. Although the river does influence the ground-water chemistry in proximity to the river, it does not appear to adversely affect the ground-water quality to a level of human-health concern.

Spatial distribution of chemical constituents in the Kuskokwim River, Alaska

USGS Publications Warehouse

Wang, Bronwen

1999-01-01

The effects of lithologic changes on the water quality of the Kuskokwim River, Alaska, were evaluated by the U.S. Geological Survey in June 1997. Water, suspended sediments, and bed sediments were sampled from the Kusko-kwim River and from three tributaries, the Holitna River, Red Devil Creek, and Crooked Creek. Dissolved boron, chromium, copper, manganese, zinc, aluminum, lithium, barium, iron, antimony, arsenic, mercury, and strontium were detected. Dissolved manganese and iron concentrations were three and four times higher in the Holitna River than in the Kusko-kwim River. Finely divided ferruginous materials found in the graywacke and shale units of the Kuskokwim Group are the probable source of the iron. The highest concentrations of dissolved strontium and barium were found at McGrath, and the limestone present in the upper basin was the most probable source of strontium. The total mercury concentrations on the Kuskokwim River decreased downstream from McGrath. Dissolved mercury was 24 to 32 percent of the total concentration. The highest concentrations of total mercury, and of dissolved antimony and arsenic were found in Red Devil Creek. The higher concentrations from Red Devil Creek did not affect the main stem mercury transport because the tributary was small relative to the Kuskokwim River. In Red Devil Creek, total mercury exceeded the concentration at which the U.S. Environmental Protection Agency (USEPA) indicates that aquatic life is affected and dissolved arsenic exceeded the USEPA's drinking-water standard. Background mercury and antimony concentrations in bed sediments ranged from 0.09 to 0.15 micrograms per gram for mercury and from 1.6 to 2.1 micrograms per gram for antimony. Background arsenic concentrations were greater than 27 micrograms per gram. Sites near the Red Devil mercury mine had mercury and antimony concentrations greater than background concentrations. These concentrations probably reflect the proximity to the ore body and past mining. Crooked Creek had mercury concentrations greater than the background concentration. The transport of suspended sediment-associated trace elements was lower for all elements in the lower river than in the upper river, indicating storage of sediments and their associated metals within the river system.

Geochemistry of dissolved trace elements and heavy metals in the Dan River Drainage (China): distribution, sources, and water quality assessment.

PubMed

Meng, Qingpeng; Zhang, Jing; Zhang, Zhaoyu; Wu, Tairan

2016-04-01

Dissolved trace elements and heavy metals in the Dan River drainage basin, which is the drinking water source area of South-to-North Water Transfer Project (China), affect large numbers of people and should therefore be carefully monitored. To investigate the distribution, sources, and quality of river water, this study integrating catchment geology and multivariate statistical techniques was carried out in the Dan River drainage from 99 river water samples collected in 2013. The distribution of trace metal concentrations in the Dan River drainage was similar to that in the Danjiangkou Reservoir, indicating that the reservoir was significantly affected by the Dan River drainage. Moreover, our results suggested that As, Sb, Cd, Mn, and Ni were the major pollutants. We revealed extremely high concentrations of As and Sb in the Laoguan River, Cd in the Qingyou River, Mn, Ni, and Cd in the Yinhua River, As and Sb in the Laojun River, and Sb in the Dan River. According to the water quality index, water in the Dan River drainage was suitable for drinking; however, an exposure risk assessment model suggests that As and Sb in the Laojun and Laoguan rivers could pose a high risk to humans in terms of adverse health and potential non-carcinogenic effects.

Multi-isotope tracers to investigate processes in the Elbe, Weser and Ems river catchment using B, Mo, Sr, and Pb isotope ratios assessed by MC ICP-MS

NASA Astrophysics Data System (ADS)

Irrgeher, Johanna; Reese, Anna; Zimmermann, Tristan; Prohaska, Thomas; Retzmann, Anika; Wieser, Michael E.; Zitek, Andreas; Proefrock, Daniel

2017-04-01

Environmental monitoring of complex ecosystems requires reliable sensitive techniques based on sound analytical strategies to identify the source, fate and sink of elements and matter. Isotopic signatures can serve to trace pathways by making use of specific isotopic fingermarks or to distinguish between natural and anthropogenic sources. The presented work shows the potential of using the isotopic variation of Sr, Pb (as well-established isotopic systems), Mo and B (as novel isotopic system) assessed by MC ICP-MS in water and sediment samples to study aquatic ecosystem transport processes. The isotopic variation of Sr, Pb, Mo and B was determined in different marine and estuarine compartments covering the catchment of the German Wadden Sea and its main tributaries, the Elbe, Weser and Ems River. The varying elemental concentrations, the complex matrix and the expected small variations in the isotopic composition required the development and application of reliable analytical measurement approaches as well as suited metrological data evaluation strategies. Aquatic isoscapes were created using ArcGIS® by relating spatial isotopic data with geographical and geological maps. The elemental and isotopic distribution maps show large variation for different parameters and also reflect the numerous impact factors (e.g. geology, anthropogenic sources) influencing the catchment area.

Multi-temporal image analysis for river reach morphological changes identification

NASA Astrophysics Data System (ADS)

Giordan, Daniele; Franzi, Luca; Rinaldi, Stefano; Dutto, Furio; Baldo, Marco; Allasia, Paolo

2016-04-01

The study of river reach evolution can be very important for the definition of the level of risk of building and infrastructures that are located nearby. Usually, these studies are based on the use of aerial photos and/or LiDAR surveys that could be analyzed for the definition of the river reach boundaries and their evolution over the time. In the past, the typical approach was the use of aerial photo for the identification of main morphological elements of the river and the definition of their changes over the time. LiDAR systems introduced an important add value related to the possibility to acquire also a DTM of the studied area and not only an orthophoto. The comparison of DTMs acquired in different periods can be useful for the identification of the changes in altimetry that can be a very important element for the comprehension of the morphological evolution of the studied area. When a river reach is characterized by a frequent changes in time, a detailed investigation needs frequent surveys and mapping. In this frame the recourse to frequent use of LiDAR could be very expensive, and therefore other cheaper solutions can be preferable. The use of RPAS system can be considered a good means for the acquisition of orthophoto and digital surface models, expecially for limited portions of river reaches and for the most active sectors. The high resolution of the orthophoto and the DSM are two important products that can be used for the identification and the measurement of main morphological changer of a river reach. The combination of aerial photos, LiDAR surveys and RPAS acquisition has been tested on the Orco River, Piemonte region (NW Italy). Orco is a gravel multichannel river with several sectors characterized by a strong inclination to the wandering of the main channel. One of the most critical sector is located not far from the confluence with Po River, where the wandering of the main channel changed the direction of the main flux of the water that now risks to threatening the hamlet of Pratoregio. In 2007 the public administration (Regione Piemonte) financed the LiDAR survey on the Orco river, in collaboration with the Politecnico of Turin and the CNR-IRPI. Now, a RPAS survey of the reach nearby Pratoregio has been used to map the recent altimetric and planimetric evolution of the river, where the flood control works have been damaged by strong lateral river erosion. The RPAS dataset has been very useful to map the new shape of the river's channels to measure the volumetric changes of the river lateral bars and to obtain an updated 3D model useful for hydraulic numerical simulations. The aim of the survey is the identification of the best engineering solution tom manage the river and to protect the endangered areas. The availability of LiDAR and RPAS DSM has been also used to evaluate the accuracy of RPAS DSM and its limitations.

Baseline sediment trace metals investigation: Steinhatchee River estuary, Florida, Northeast Gulf of Mexico

USGS Publications Warehouse

Trimble, C.A.; Hoenstine, R.W.; Highley, A.B.; Donoghue, J.F.; Ragland, P.C.

1999-01-01

This Florida Geological Survey/U.S. Department of the Interior, Minerals Management Service Cooperative Study provides baseline data for major and trace metal concentrations in the sediments of the Steinhatchee River estuary. These data are intended to provide a benchmark for comparison with future metal concentration data measurements. The Steinhatchee River estuary is a relatively pristine bay located within the Big Bend Wildlife Management Area on the North Central Florida Gulf of Mexico coastline. The river flows 55 km through woodlands and planted pines before emptying into the Gulf at Deadman Harbor. Water quality in the estuary is excellent at present. There is minimal development within the watershed. The estuary is part of an extensive system of marshes that formed along the Florida Gulf coast during the Holocene marine transgression. Sediment accretion rate measurements range from 1.4 to 4.1 mm/yr on the basis of lead-210 measurements. Seventy-nine short cores were collected from 66 sample locations, representing four lithofacies: clay- and organic-rich sands, organic-rich sands, clean quartz sands, and oyster bioherms. Samples were analyzed for texture, total organic matter, total carbon, total nitrogen, clay mineralogy, and major and trace-metal content. Following these analyses, metal concentrations were normalized against geochemical reference elements (aluminum and iron) and against total weight percent organic matter. Metals were also normalized granulometrically against total weight percent fines (<0.062 mm). Concentrations were determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES) for all metals except mercury. Mercury concentrations were determined by cold-flameless atomic absorption spectrometry (AAS). Granulometric measurements were made by sieve and pipette analyses. Organic matter was determined by two methods: weight loss upon ignition and elemental analysis (by Carlo-Erba Furnace) of carbon and nitrogen. X-ray diffraction was used to determine clay mineralogy. Trace-metal concentrations were best correlated when normalized with respect to sediment aluminum concentrations. Normalizations indicate that most major and trace-metal concentrations fall within 95% prediction limits of the expected value. This finding suggests that little significant metal contamination occurred within this system prior to 1994 sediment sampling. Exceptions include lead, mercury, copper, zinc, potassium, and phosphorous. Lead and mercury are elements that generally enter this watershed through atmospheric deposition; thus, anomalous levels of these metals are not necessarily associated with activities within the watershed of the Steinhatchee River estuary. Anomalous concentrations of other metals such as zinc, copper, and phosphorous probably do originate within the Steinhatchee watershed. Copper failed to correlate well with any geochemical or granulometric normalizer, and this condition was not limited to a single facies or area within the estuary. This finding may indicate copper contamination in the system. Increased zinc and copper levels may be attributed to marine paints. Phosphorous levels also appeared to be elevated in a few locations in the two marsh facies sampled. This may be due to nutrient loading from two small communities, Jena and Steinhatchee, or from the application of this element in fertilizer to reduce moisture stress to young planted pines on tree farms within the watershed.The Florida Geological Survey/US Department of the Interior, Minerals Management Service Cooperative Study provides baseline data for major and trace metal concentrations in the sediments of the Steinhatchee River estuary. The data are intended to provide a benchmark for comparison with metal concentration data measurements. Seventy nine short cores were collected from 66 sample locations and analyzed. Metal concentrations were normalized against geochemical reference elements and against total weight percen

Sediment-quality assessment of Franklin D. Roosevelt Lake and the upstream reach of the Columbia River, Washington, 1992

USGS Publications Warehouse

Bortleson, Gilbert Carl; Cox, S.E.; Munn, M.D.; Schumaker, R.J.; Block, E.K.

2001-01-01

Elevated concentrations of trace elements were found in bed sediment of Lake Roosevelt and the Columbia River, its principal source of inflow. Trace-element concentrations in whole water samples did not exceed criteria for freshwater organisms. Bed sediments of Lake Roosevelt were analyzed for organic compounds associated with wood-pulp waste. Dioxins and furans were found in suspended sediment and water of the Columbia River. Abundance and diversity of benthic invertebrate communities were analyzed.

Defining chemical status of a temporary Mediterranean River.

PubMed

Skoulikidis, Nikolaos Th

2008-07-01

Although the majority of rivers and streams in the Mediterranean area are temporary, no particular attention is being paid for such systems in the Water Framework Directive (WFD). A typical temporal Mediterranean river, draining an intensively cultivated basin, was assessed for its chemical status. Elevated concentrations of nitrates and salts in river water as well as nutrients and heavy metals in river sediments have been attributed to agricultural land uses and practices and point sources of organic pollution. A scheme for the classification of the river's chemical status (within the ecological quality classification procedure) was applied by combining pollution parameters in groups according to related pressures. In light of the temporal hydrological regime and anthropogenic impacts, sediment chemical quality elements were considered, in addition to hydrochemical ones. Despite the extensive agricultural activities in the basin, the majority of the sites examined showed a good quality and only three of them were classified as moderate. For the classification of the chemical quality of temporary water bodies, there is a need to develop ecologically relevant salinity and sediment quality standards.

Trace elements in native and transplanted Fontinalis antipyretica and Platyhypnidium riparioides from rivers polluted by uranium mining.

PubMed

Kosior, Grzegorz; Steinnes, Eiliv; Samecka-Cymerman, Aleksandra; Lierhagen, Syverin; Kolon, Krzysztof; Dołhańczuk-Śródka, Agnieszka; Ziembik, Zbigniew

2017-03-01

The past uranium/polymetallic mining activities in the Sudety (SW Poland) left abandoned mines, pits, and dumps of waste rocks with trace elements and radionuclides which may erode or leach out and create a potential risk for the aquatic ecosystem, among others. In the present work four rivers affected by effluents from such mines were selected to evaluate the application of aquatic mosses for the bioindication of 56 elements. Naturally growing F. antipyretica and P. riparioides were compared with transplanted samples of the same species. The results demonstrate serious pollution of the examined rivers, especially with As, Ba, Fe, Mn, Pb, Ti, U and Zn, reaching extremely high concentrations in native moss samples. In the most polluted rivers native F. antipyretica and P. riparioides samples showed significantly higher concentrations of As, Ba, Cu, Fe, La, Nd, Ni, Pb, U and Zn than corresponding transplanted samples, whereas at less polluted sites a reverse situation was sometimes observed. Transplanted moss moved from clean to extremely polluted rivers probably protects itself against the accumulation of toxic elements by reducing their uptake. Selection of native or transplanted F. antipyretica and P. riparioides depended on the pollution load. Copyright © 2016. Published by Elsevier Ltd.

[Characteristics of heavy metal elements and their relationship with magnetic properties of river sediment from urban area in Lanzhou].

PubMed

Wang, Bo; Zhao, Shuang; Xia, Dun-sheng; Yu, Ye; Tian, Shi-li; Jia, Jia; Jiang, Xiao-rong

2011-05-01

The contents of As, Co, Cr, Cu, Ni, Pb, V and Zn in the surface sediments from 8 rivers in urban area in Lanzhou were monitored by ecological risk which was assessed by the potential ecological Håkanson index, and the index of geoaccumulation (Igeo), sediment enrichment factor (R), and environmental magnetism. The results showed that: (1) the potential ecological risk of heavy metals of As, Co, Ni, V in surface sediments from 8 rivers were low, which belonged to low ecological risk. But the risk of heave metals Cr, Pb, Zn in surface sediments from Yuer river was high, which belonged to middle ecological risk, and in downstream of Yuer river, the element of Cu belonged to high ecological risk. (2) The rivers in Lanzhou could be divided into four groups according to the heavy mental pollution degree: first type, such as Paihong river, Shier river, Yuer river and Shuimo river, called downstream concentrate type; second type, such as Qili river, called upstream concentrate type; third type, such as Luoguo river and Dasha river, called less affected type; fourth type, Lanni river, which polluted heavily in up and downstream; (3) The correlation analysis between magnetic parameters and element contents show that the parameters which mainly reflect the concentration of the magnetic minerals (X, SIRM, Ms) have close association with Cr, Ni, Pb, Zn, Cu, So we can infer that the magnetic minerals in deposits samples mainly came from electroplating effluent, motor vehicle emission, and domestic sewage. SIRM/X shows a strong correlation with Cr, Ni, Pb, Zn, indicating the distribution of anthropogenic particulates. (4) The magnetic minerals(X, SIRM, Ms) have a strong correlation with the geoaccumulation (Igeo) than potential ecological risk index and enrichment factor (R). These results suggest a possible approach for source identification of magnetic material in pollution studies and the validity of using magnetic measurements to mapping the polluted area.

Importance of nanoparticles and colloids from volcanic ash for riverine transport of trace elements to the ocean: evidence from glacial-fed rivers after the 2010 eruption of Eyjafjallajökull Volcano, Iceland.

PubMed

Tepe, Nathalie; Bau, Michael

2014-08-01

Volcanic ashes are often referenced as examples for natural nanoparticles, yet the particle size distribution <1000 nm is only rarely documented. We here report results of a geochemical study of glacial-fed rivers, glacial surface runoff, glacial base flow, and pure glacial meltwater from southern Iceland, that had been sampled 25 days after the explosive eruptions at Eyjafjallajökull in 2010. In addition to the dissolved concentrations of rare earth elements (REE), Zr, Hf, Nb, and Th in the 450 nm-filtered waters, we also studied the respective filter residues (river particulates >450 nm) and volcanic ash. In spite of the low solubilities and high particle-reactivities of the elements studied, most water samples show high dissolved concentrations, such as up to 971 ng/kg of Ce and 501 ng/kg of Zr. Except for the pure glacial meltwater and glacial base flow, all waters display the same shale-normalized REE patterns with pronounced light and heavy REE depletion and positive Eu anomalies. While such patterns are unusual for river waters, they are similar to those of the respective river particulates and the volcanic ash, though at different concentration levels. The distribution of dissolved Zr, Hf, Nb, and Th in the waters also matches that of filter residues and ash. This strongly suggests that in all 450 nm-filtered river waters, the elements studied are associated with solid ash particles smaller than 450 nm. This reveals that volcanic ash-derived nanoparticles and colloids are present in these glacial-fed rivers and that such ultrafine particles control the trace element distribution in the surface runoff. Subsequent to explosive volcanic eruptions, these waters provide terrigenous input from landmasses to estuaries, that is characterized by a unique trace element signature and that subsequent to modification by estuarine processes delivers a pulse of nutrients to coastal seawater in regions not affected by plume fall-out. Copyright © 2014 Elsevier B.V. All rights reserved.

Urban geometry effects on the microclimate of streets near the river

NASA Astrophysics Data System (ADS)

Park, C.; Lee, D. K.; Asawa, T.; Murakami, A.; Kim, H. G.; Jeong, W.

2016-12-01

These days, many urbans have undergone urban heat islands (UHIs) which mean urban areas have higher temperature than surrounding areas. Because of UHIs, extreme heat waves and tropical nights threaten citizen's health. For reducing UHI effects, UHIs mitigation strategies related with urban planning (cooling elements, urban geometry, and urban materials) are studied in many fields. Especially, cooling elements such as vegetation and water are important for making sustainable cities. However, while the each effects of cooling elements are known, combination effects between urban geometry and elements are not clearly defined. To determine which urban geometry is effective to decrease air temperature, we analyzed urban geometry effects on the microclimate of streets near the river. The urban streets located in commercial area near the Cheonggye River and they had different aspect ratio. For doing this, we used field measurement. Field measurement were takin in the sunny days of July and August 2016. Air temperature measurement used T-type thermometers with cylindrical tube and ventilation fan. Wind measurements used kestrel 4500 for wind speed and wind direction. We measured air temperature in the screen level and repeated three times an hour. Measurement results showed that large aspect ratio street show lower air temperature than small ones. And they received cooling effect farther than others from the river. This is because that cooling air flows well in the wide road streets. Large aspect ratio streets are effective to receive river's cooling air. These results can be used in the urban geometry planning near the river.

Indicating anthropogenic effectson urban water system - indicators and extension

NASA Astrophysics Data System (ADS)

Strauch, G.; Ufz-Team

2003-04-01

Urban water systems are polluted by diffusive and direct contribution of anthropogenic activities. Besides industrial contaminants like aromatic and chlorinated HC and other persistent organic compounds, the urban aquatic environment is increasingly polluted by low concentrated but high eco-toxic compounds as pharmaceuticals, fragrances, plasticizers which most have disrupt endocrine functions, and trace elements carried in by surface and sub-surface waste water and seeping processes. This contamination could have a longtime impact on the urban ecosystem and on the human health. The interdisciplinary project on risk assessment of water pollution was initiated to explore new methodologies for assessing human activities on the urban water system and processes among urban watersheds. In a first assumption we used a flow model concept with in- and output and surface water transport represented by the city of Halle, Germany, and the river Saale. The river Saale acts as surface water system collecting waste water inputs along the city traverse. We investigated the anthropogenic effect on the urban water system using the indicators hydrological parameters, compound specific pattern of complex organic substances and trace elements, isotopic signatures of water (H, O) and dissolved substances (sulfate, DIC, nitrate), pathogens, and microbiota. A first balance modeling showed that main ions are not very sensitive concerning the direct urban input into the river. Depending on the discharge of the river in high and low flood stages the load of dissolved matter has no specific urban effect. However, the concentration pattern of fragrances (tonalid, galaxolid) and endocrine disrupters (t-nonylphenol) point to a different pollution along the city traverse: downstream of the sewage plant a higher load was observed in comparison to the upstream passage. Furthermore, a degradation ability of fungi and bacteria occurred in the bank sediments could be detected in lab experiments concerning the fragrances, and endocrine disrupters (t-nonylphenol, phthalate). The Saale water samples contain components able to eco-toxic and immunomodulated effects as measured on the vitality and cytokine-secretion profile of human peripheral blood mononuclear cells (PBMC). Even fragrances caused such effects which are unknown so far. The study of assessing urban effects onto the water system is still under investigation.

Water-quality assessment of the Kentucky River Basin, Kentucky; distribution of metals and other trace elements in sediment and water, 1987-90

USGS Publications Warehouse

Porter, Stephen D.; White, Kevin D.; Clark, J.R.

1995-01-01

The U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program is designed to provide a nationally consistent description of the current status of water quality, to define water-quality trends, and to relate past and present water-quality conditions to natural features, uses of land and water, and other water-quality effects from human activities. The Kentucky River Basin is one of four NAWQA pilot projects that focused primarily on the quality of surface water. Water, sediment, and bedrock samples were collected in the Kentucky River Basin during 1987-90 for the purpose of (1) describing the spatial distribution, transport, and temporal variability of metals and other trace elements in streams of the basin; (2) estimating mean annual loads, yields, and trends of constituent concentrations and identifying potential causes (or sources) of spatial patterns; (3) providing baseline information for concentrations of metals in streambed and suspended sediments; (4) identifying stream reaches in the Kentucky River Basin with chronic water-quality problems; and (5) evaluating the merits of the NAWQA pilot study-approach for the assessment of metals and other trace elements in a river system. The spatial distribution of metals and other trace elements in streambed sediments of the Kentucky River Basin is associated with regional differences of geology, land use and cover, and the results of human activities. Median concentrations of constituents differed significantly among physiographic regions of the basin because of relations to bedrock geochemistry and land disturbance. Concentrations of potentially toxic metals were large in urban and industrial areas of the basin. Elevated concentrations of certain metals were also found in streambed sediments of the Knobs Region because of the presence of Devonian shale bedrock. Elevated concentrations of lead and zinc found in streambed sediments of the Bluegrass Region are likely associated with urban stormwater runoff, point-source discharges, and waste-management practices. Concentrations of cadmium, chromium, copper, mercury, and silver were elevated in streambed sediments downstream from wastewater-treatment plant discharges. Streambed-sediment concentrations of barium, chromium, and lithium were elevated in streams that receive brine discharges from oil production. Elevated concentrations of antimony, arsenic, molybdenum, selenium, strontium, uranium, and vanadium in streambed sediments of the Kentucky River Basin were generally associated with natural sources. Concentrations of metals and other trace elements in water samples from fixed stations (stations where water-quality samples were collected for 3.5 years) in the Kentucky River Basin were generally related to stream discharge and the concentration of suspended sediment, whereas constituent concentrations in the suspended-sediment matrix were indicative of natural and human sources. Estimated mean annual loads and yields for most metals and other trace elements were associated with the transport of suspended sediment. Land disturbance, such as surface mining and agriculture, contribute to increased transport of sediment in streams, thereby increasing concentrations of metals in water samples during periods of intense or prolonged rainfall and increased stream discharge. Concentrations of many metals and trace elements were reduced during low streamflow. Although total-recoverable and dissolved concentrations of certain metals and trace elements were large in streams affected by land disturbance, concentrations of constituents in the suspendedsediment matrix were commonly large in streams in the Knobs and Eastern Coal Field Regions (because of relations with bedrock geochemistry) and in streams that receive wastewater or oil-well-brine discharges. Concentrations and mean annual load estimates for aluminum, chromium, copper, iron, lead, manganese, and mercury were larger than those obtained from data collected by a State agency, probably because of differences in sample-collection methodology, the range of discharge associated with water-quality samples, and laboratory analytical procedures. However, concentrations, loads, and yields of arsenic, barium, and zinc were similar to those determined from the State data. Significant upward trends in the concentrations of aluminum, iron, magnesium, manganese, and zinc were indicated at one or more fixed stations in the Kentucky River Basin during the past 10 to 15 years. Upward trends for concentrations of aluminum, iron, and manganese were found at sites that receive drainage from coal mines in the upper Kentucky River Basin, whereas upward trends for zinc may be associated with urban sources. Water-quality criteria established by the U.S. Environmental Protection Agency (USEPA) or the State of Kentucky for concentrations of aluminum, beryllium, cadmium, chromium, copper, iron, manganese, nickel, silver, and zinc were exceeded at one or more fixed stations in the Kentucky River Basin. On a qualitative basis, dissolved concentrations of certain metals and trace elements were large during low streamflow at sites where (1) concentrations of these constituents in underlying streambed sediments were large, or (2) dissolvedoxygen concentrations were small. Concentrations of barium, lithium, and strontium were large during low streamflow, which indicates the influence of ground-water baseflows on the quality of surface water during low flow. The effects of point-source discharges, landfills, and other wastemanagement practices are somewhat localized in the Kentucky River Basin and are best indicated by the spatial distribution of metals and other trace elements in streambed sediments and in the suspended-sediment fraction of water samples at stream locations near the source. It was not possible to quantify the contribution of point sources to the total transport of metals and other trace elements at fixed stations because data were not available for wastewater effluents. Quantification of baseline concentrations of metals and other trace elements in streambed sediments provides a basis for the detection of water-quality changes that may result from improvements in wastewater treatment or the implementation of best-management practices for controlling contamination from nonpoint sources in the Kentucky River Basin.

Historical trace element distribution in sediments from the Mississippi River delta

USGS Publications Warehouse

Swarzenski, P.W.; Baskaran, M.; Rosenbauer, R.J.; Orem, W.H.

2006-01-01

Five sediment cores were collected on the shelf of the inner Mississippi Bight in June 2003 for a suite of radionuclides to establish geochronologies and trace elements to examine patterns of contaminant deposition and accumulation. Core sites were chosen to reflect a matrix of variable water depths, proximity to the Mississippi River mouth as the primary source for terrigenous particles, and extent and duration of summertime water column hypoxia. The vertical distribution of 239,240Pu and 210Pbxs (= 210Pbtotal - 226Ra) provided reliable geochronological age constraints to develop models for mass accumulation rates and historic trace element inputs and variations. Mass accumulation rates ranged from 0.27 to 0.87 g cm-2 yr-1 and were internally consistent using either 210Pbxs or 239,240Pu. Measured inventories of 137Cs, 239,240Pu, and 210Pbxs were compared to atmospheric deposition rates to quantify potential sediment focusing or winnowing. Observed variability in calculated mass accumulation rates may be attributed foremost to site-specific proximity to the river mouth (i.e., sediment source), variability in water depth, and enhanced sediment focusing at the Mississippi River canyon site. Trace element concentrations were first normalized to Al, and then Al-normalized enrichment factors (ANEF) were calculated based on preanthropogenic and crustal trace element abundances. These ANEFs were typically > 1 for V and Ba, while for most other elements studied, either no enrichment or depletion was observed. The enrichment of Ba may be related, in part, to the seasonal occurrence of oxygen-depleted subsurface waters off the Mississippi River delta, as well as being an ubiquitous by-product of the petroleum industry. ?? 2006 Estuarine Research Federation.

Lead Isotopic Source Signatures for Rains and River Waters in Taiwan

NASA Astrophysics Data System (ADS)

You, C.; Cheng, M.; Lee, M.; Lin, F.

2002-12-01

Lead isotopic compositions and Pb contents in rains and river waters are sensitive proxies for air-pollutant sources and their transport processes. We have collected more than 100 wet precipitations between 1998 and 2001 at Peng-Chia Yu, an offshore island in northern Taiwan, and two other cities, Taichung and Tainan, located at central and southern Taiwan. Additional 14 river waters collected along the Er-Ren-Shi River, Tainan were investigated for systematic comparison. All collected samples were analyzed for major ions (i.e., Cl, Na, Mg, Ca, SO4, NO3 and NH4) by ion chromatography, trace elements and Pb isotopes by ICP-MS (Element II) installed at NCKU. The Peng-Chia Yu rains show large seasonal variation in major ions where Na and Cl are much higher in the winter season. Significant industrial contributions of SO4, NH4 and nsCa are detected at Taichung and Tainan. Trace element results display a more complicated picture, suggesting mixing among seasalt, Asia continental dust, and atmospheric pollutant. These chemical data can be understood in terms of seasonal wind direction changes due to the Asian monsoon system. In winter, the northerly cold wind blow materials with high concentration of anthropogenic input (i.e., Pb and SO4) and dust source (i.e., Al and Ca) from the Asia continent. In contrast, the intertropical convergence zone (ITCZ) migrates northward and caused southwest monsoon prevail in the summer. The 208Pb/207Pb ratio shows consistent seasonal trends as that of Pb contents, possibly a result of mixing between Asia atmospheric sources and seasalt. For the Er-ren Shi River waters, Pb and Pb isotopic compositions vary systematically downstream. Pb concentrations decrease rapidly from 5200 ppt at upstream stations to a value of less than 50 ppt near the estuary whereas 208Pb/207Pb varied between 2.087 and 2.124. The 208Pb/206Pb vs. 1/Pb plot demonstrates a mixing trend between anthropogenic sources and seawater. These results demonstrate that Pb and Pb isotopes in rains and river waters can be used as useful tools for tracing air-borne pollutant sources and their transportation processes.

Contrasting impact of organic and inorganic nanoparticles and colloids on the behavior of particle-reactive elements in tropical estuaries: An experimental study

NASA Astrophysics Data System (ADS)

Merschel, Gila; Bau, Michael; Dantas, Elton Luiz

2017-01-01

Estuarine processes may affect the flux of dissolved organic carbon (DOC), iron and other particle-reactive elements such as the rare earth elements and yttrium (REY), into the ocean via salt-induced coagulation and subsequent removal of river-borne (nano-)particles and colloids. We experimentally assessed the impact of the admixture of seawater on DOC, Fe and REY associated with inorganic and organic nanoparticles and colloids (NPCs) present in tropical rivers, using Rio Solimões and Rio Negro, which are particularly rich in inorganic and organic NPCs, respectively, as river water endmembers. Similar to the conservative elements Sr, Rb and U, DOC behaves conservatively in all mixing experiments, whereas strong removal of Fe and REY (and preferential removal of light over heavy REY and of Ce relative to La and Pr) is confined to experiments with inorganic NPC-rich Rio Solimões water. This removal already occurs at very low salinity and is due to the aggregation of the inorganic NPCs. However, REY removal efficiency increases gradually with increasing salinity, which is in marked contrast to DOC-poor Arctic river waters from which REY removal at lowest salinity is significantly stronger. This suggests that the DOC concentrations in the water have a profound impact on the estuarine mixing behavior of particle-reactive elements. In marked contrast to the Rio Solimões mixing experiment, Fe and the REY in experiments with Rio Negro water behave similarly to DOC and mix conservatively with seawater, indicating that the organic NPCs, most of which are humic and fulvic acids, and their associated trace elements are much less susceptible to coagulation and estuarine removal than inorganic ones. Even at higher salinities, estuarine REY removal from inorganic NPC-rich Rio Solimões water significantly exceeds REY removal from organic NPC-rich Rio Negro water. Hence, the combination of higher element concentrations in and of less estuarine removal from organic NPC-rich rivers compared to inorganic NPC-rich rivers indicates that the former are a more important source of particle-reactive elements to the oceans than previously thought. This suggests that chemical complexation with organic ligands, such as humic and fulvic acids, may have a strong impact on the riverine flux and on the marine inventory of particle-reactive elements, and hence may play an important role for the isotopic composition of such elements in seawater.

Surface-water-quality assessment of the Yakima River basin in Washington; spatial and temporal distribution of trace elements in water, sediment, and aquatic biota, 1987-91; with a section on geology

USGS Publications Warehouse

Fuhrer, Gregory J.; Cain, Daniel J.; McKenzie, Stuart W.; Rinella, Joseph F.; Crawford, J. Kent; Skach, Kenneth A.; Hornberger, Michelle I.; Gannett, Marshall W.

1999-01-01

The report describes the distribution of trace elements in sediment, water, and aquatic biota in the Yakima River basin, Washington. Trace elements were determined from streambed sediment, suspended sediment, filtered and unfiltered water samples, aquatic insects, clams, fish livers, and fish fillets between 1987 and 1991. The distribution of trace elements in these media was related to local geology and anthropogenic sources. Additionally, annual and instantaneous loads were estimated for trace elements associated with suspended sediment and trace elements in filtered water samples. Trace elements also were screened against U.S. Environmental Protection Agency guidelines established for the protection of human health and aquatic life.

Wind River water restoration, Annual report November 2008 to October 2009.

USGS Publications Warehouse

Connolly, P.J.; Jezorek, I.G.; Munz, C.S.

2010-01-01

This report summarizes work completed by U.S. Geological Survey’s Columbia River Research Laboratory (USGS-CRRL) in the Wind River subbasin during the period November 2008 through October 2009 under Bonneville Power Administration (BPA) contract 41038. Long term research in the Wind River has focused on assessments of steelhead/rainbow trout Oncorhynchus mykiss populations, interactions with introduced populations of spring Chinook salmon O. tshawytscha and brook trout Salvelinus fontinalis, and influences of habitat variables on fish productivity. During this period, we collected water temperature data to characterize variation within and among tributaries and mainstem sections in the Trout Creek watershed, and assisted Washington Department of Fish and Wildlife with smolt trapping and tagging of smolt and parr steelhead with passive integrated transponder (PIT) tags. We also continued to maintain and test efficacy of a passive integrated transponder tag interrogation system (PTIS) in Trout Creek for assessing the adult steelhead runsize. We continued to maintain and download PTIS setups in the fish ladder at Hemlock Dam. These PTISs contributed information on movement and rearing of steelhead parr and smolts. A statement of work (SOW) was submitted to BPA in October 2009 that outlined work to be performed by USGS-CRRL. The SOW was organized by work elements, with each describing a research task. This report summarizes the progress completed under each work element.

The Grain-size Patchiness of Braided Gravel-Bed Streams - example of the Urumqi River (northeast Tian Shan, China)

NASA Astrophysics Data System (ADS)

Guerit, L.; Barrier, L.; Narteau, C.; Métivier, F.; Liu, Y.; Lajeunesse, E.; Gayer, E.; Meunier, P.; Malverti, L.; Ye, B.

2014-02-01

In gravel-bed rivers, sediments are often sorted into patches of different grain-sizes, but in braided streams, the link between this sorting and the channel morpho-sedimentary elements is still unclear. In this study, the size of the bed sediment in the shallow braided gravel-bed Urumqi River is characterized by surface-count and volumetric sampling methods. Three morpho-sedimentary elements are identified in the active threads of the river: chutes at flow constrictions, which pass downstream to anabranches and bars at flow expansions. The surface and surface-layer grain-size distributions of these three elements show that they correspond to only two kinds of grain-size patches: (1) coarse-grained chutes, coarser than the bulk river bed, and (2) finer-grained anabranches and bars, consistent with the bulk river bed. In cross-section, the chute patches are composed of one coarse-grained top layer, which can be interpreted as a local armour layer overlying finer deposits. In contrast, the grain size of the bar-anabranch patches is finer and much more homogeneous in depth than the chute patches. Those patches, which are features of lateral and vertical sorting associated to the transport dynamics that build braided patterns, may be typical of active threads in shallow gravel-bed rivers and should be considered in future works on sorting processes and their geomorphologic and stratigraphic results.

Lithogenic sources, composition and intra-annual variability of suspended particulate matter supplied from rivers to the Northern Galician Rias (Bay of Biscay)

NASA Astrophysics Data System (ADS)

Bernárdez, Patricia; Prego, Ricardo; Filgueiras, Ana Virginia; Ospina-Álvarez, Natalia; Santos-Echeandía, Juan; Álvarez-Vázquez, Miguel Angel; Caetano, Miguel

2017-12-01

Scarce research about small European rivers from non-human impacted areas to determine their natural background state has been undertaken. During the annual hydrological cycle of 2008-9 the patterns of particulate supply (SPM, POC, PON, Al, Cd, Co, Cr, Cu, Fe, Ni, Pb, V, Zn) from the rivers Sor, Mera Landro, Lourido and Landoi to the Northern Galician Rias (SW Bay of Biscay) were tackled. No differences in the composition of the SPM were detected for the studied rivers regarding Al, Fe and POC but the relative percentage of particulate trace elements (PTE) discriminate the rivers. So, Cr, Co and Ni in the Lourido, and Landoi rivers, and Cu in the Mera River, are controlled by watershed minerals of Ortegal Geological Complex while for the rest rivers PTE are by granitic and Ollo de Sapo bedrock watershed. Therefore, the imprint of PTE in the parental rocks of the river basins is reflected on the coastal sediments of the Rias. The main process controlling the dynamics and variations of chemical elements in the particulate form is the river discharge. This fact exemplifies that these rivers presents a natural behavior not being highly influenced by anthropogenic activities.

Floods, floodplains, delta plains — A satellite imaging approach

NASA Astrophysics Data System (ADS)

Syvitski, James P. M.; Overeem, Irina; Brakenridge, G. Robert; Hannon, Mark

2012-08-01

Thirty-three lowland floodplains and their associated delta plains are characterized with data from three remote sensing systems (AMSR-E, SRTM and MODIS). These data provide new quantitative information to characterize Late Quaternary floodplain landscapes and their penchant for flooding over the last decade. Daily proxy records for discharge since 2002 and for each of the 33 river systems can be derived with novel Advanced Microwave Scanning Radiometer (AMSR-E) methods. A descriptive framework based on analysis of Shuttle Radar Topography Mission (SRTM) data is used to capture the major landscape-scale floodplain elements or zones: 1) container valleys with their long and narrow pathways of largely sediment transit and bypass, 2) floodplain depressions that act as loci for frequent flooding and sediment storage, 3) zones of nodal avulsions common to many continental scale rivers, and often located seaward of container valleys, and 4) coastal floodplains and delta plains that offer both sediment bypass and storage but under the influence of marine processes. The SRTM data allow mapping of smaller-scale architectural elements in unprecedented systematic manner. Floodplain depressions were found to play a major role, which may largely be overlooked in conceptual floodplain models. Lastly, MODIS data (independently and combined with AMSR-E) allows the tracking of flood hydrographs and pathways and sedimentation patterns on a near-daily timescale worldwide. These remote-sensing data show that 85% of the studied major river systems experienced extensive flooding in the last decade. A new quantitative paradigm of floodplain processes, honoring the frequency and extent of floods, can be develop by careful analysis of these new remotely sensed data.

Pulses, linkages, and boundaries of coupled aquatic-terrestrial ecosystems

NASA Astrophysics Data System (ADS)

Tockner, K.

2009-04-01

Riverine floodplains are linked ecosystems where terrestrial and aquatic habitats overlap, creating a zone where they interact, the aquatic-terrestrial interface. The interface or boundary between aquatic and terrestrial habitats is an area of transition, contact or separation; and connectivity between these habitats may be defined as the ease with which organisms, matter or energy traverse these boundaries. Coupling of aquatic and terrestrial systems generates intertwining food webs, and we may predict that coupled systems are more productive than separated ones. For example, riparian consumers (aquatic and terrestrial) have alternative prey items external to their respective habitats. Such subsidized assemblages occupy a significant higher trophic position than assemblages in unsubsidized areas. Further, cross-habitat linkages are often pulsed; and even small pulses of a driver (e.g. short-term increases in flow) can cause major resource pulses (i.e. emerging aquatic insects) that control the recipient community. For example, short-term additions of resources, simulating pulsed inputs of aquatic food to terrestrial systems, suggest that due to resource partitioning and temporal separation among riparian arthropod taxa the resource flux from the river to the riparian zone increases with increasing riparian consumer diversity. I will discuss the multiple transfer and transformation processes of matter and organisms across aquatic-terrestrial habitats. Key landscape elements along river corridors are vegetated islands that function as instream riparian areas. Results from Central European rivers demonstrate that islands are in general more natural than fringing riparian areas, contribute substantially to total ecotone length, and create diverse habitats in the aquatic and terrestrial realm. In braided rivers, vegetated islands are highly productive landscape elements compared to the adjacent aquatic area. However, aquatic habitats exhibit a much higher decomposition capacity for coarse particulate organic matter. Therefore, linking habitats that differ in their capacity to produce, store, and transform organic matter and nutrients may increase the overall functional performance of the entire ecosystem. Finally, the relative extent and the spatiotemporal dynamics of dry and wet areas within a catchment may control greatly the capacity of the river network to efficiently retain nutrients and organic matter. All these findings provide new opportunities for the future management of riparian corridors.

One river, many stories

EPA Science Inventory

Interactive exhibition elements include opportunity to add stories, drawings, and place names to maps of the river; record & share your vision for the river with public television. The Duluth Art Institute will present the kick-off event for the month-long media focus around ...

Selected trace elements in the Sacramento River, California: occurrence and distribution.

PubMed

Taylor, H E; Antweiler, R C; Roth, D A; Alpers, C N; Dileanis, P

2012-05-01

The impact of trace elements from the Iron Mountain Superfund site on the Sacramento River and selected tributaries is examined. The concentration and distribution of many trace elements-including aluminum, arsenic, boron, barium, beryllium, bismuth, cadmium, cerium, cobalt, chromium, cesium, copper, dysprosium, erbium, europium, iron, gadolinium, holmium, potassium, lanthanum, lithium, lutetium, manganese, molybdenum, neodymium, nickel, lead, praseodymium, rubidium, rhenium, antimony, selenium, samarium, strontium, terbium, thallium, thulium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc, and zirconium-were measured using a combination of inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry. Samples were collected using ultraclean techniques at selected sites in tributaries and the Sacramento River from below Shasta Dam to Freeport, California, at six separate time periods from mid-1996 to mid-1997. Trace-element concentrations in dissolved (ultrafiltered [0.005-μm pore size]) and colloidal material, isolated at each site from large volume samples, are reported. For example, dissolved Zn ranged from 900 μg/L at Spring Creek (Iron Mountain acid mine drainage into Keswick Reservoir) to 0.65 μg/L at the Freeport site on the Sacramento River. Zn associated with colloidal material ranged from 4.3 μg/L (colloid-equivalent concentration) in Spring Creek to 21.8 μg/L at the Colusa site on the Sacramento River. Virtually all of the trace elements exist in Spring Creek in the dissolved form. On entering Keswick Reservoir, the metals are at least partially converted by precipitation or adsorption to the particulate phase. Despite this observation, few of the elements are removed by settling; instead the majority is transported, associated with colloids, downriver, at least to the Bend Bridge site, which is 67 km from Keswick Dam. Most trace elements are strongly associated with the colloid phase going downriver under both low- and high-flow conditions.

Characterization of the extent of Mercury Contamination in the Androscoggin River from a former Chlor-alkali Facility, Berlin, New Hampshire

NASA Astrophysics Data System (ADS)

Chalmers, A.; Marvin-Dipasquale, M. C.; Rosiu, C.; Luce, D.; Coles, J.; Zimmerman, M.; Smith, T.

2010-12-01

From the late 1800s to the 1960s a chlor-alkali plant was used to produce chlorine gas for the papermaking industry in Berlin, New Hampshire. During operation of the chlor-alkali facility, elemental mercury (Hg) was released to the environment, contaminating soils and the underlying fractured rock. Investigations have revealed that elemental Hg continues to seep through bedrock fractures into the adjacent Androscoggin River. This study evaluates the extent and transformation of Hg contamination in the Androscoggin River by comparing a reference site 17 kilometers above the former chlor-alkali facility to 5 sites ranging from 1 to 16 km downstream from the facility. Total and methyl Hg (THg and MeHg, respectively), among other analytes, were characterized in surface water, pore water, sediment and biological tissue samples at each site. Bed sediment was also assessed for bio-available (tin-reducible) inorganic Hg (II) and microbial MeHg production potential rates. Acid extractable ferrous iron, crystalline and amorphous (poorly crystalline) ferric iron, total reduced sulfur, particle size, and organic content in bed sediment was analyzed to help explain spatial differences in MeHg production rates and bio-available Hg (II) among sites. The information provided by this study will help evaluate the extent of Hg contamination in the Androscoggin River, will improve our understanding of the controls on MeHg production in the Androscoggin River system, and will be used by the U.S. Environmental Protection Agency to support remediation of the chlor-alkali facility site.

Selected elements and organic chemicals in bed sediment and fish tissue of the Tualatin River basin, Oregon, 1992-96

USGS Publications Warehouse

Bonn, Bernadine A.

1999-01-01

This report describes the results of a reconnaissance survey of elements and organic compounds found in bed sediment and fish tissue in streams of the Tualatin River Basin. The basin is in northwestern Oregon to the west of the Portland metropolitan area (fig. 1). The Tualatin River flows for about 80 miles, draining an area of about 712 square miles, before it enters the Willamette River. Land use in the basin changes from mostly forested in the headwaters, to mixed forest and agriculture, to predominately urban. The basin supports a growing population of more than 350,000 people, most of whom live in lower parts of the basin. Water quality in the Tualatin River and its tributaries is expected to be affected by the increasing urbanization of the basin.

Landscape evolution and agricultural land salinization in coastal area: A conceptual model.

PubMed

Bless, Aplena Elen; Colin, François; Crabit, Armand; Devaux, Nicolas; Philippon, Olivier; Follain, Stéphane

2018-06-01

Soil salinization is a major threat to agricultural lands. Among salt-affected lands, coastal areas could be considered as highly complex systems, where salinization degradation due to anthropogenic pressure and climate-induced changes could significantly alter system functioning. For such complex systems, conceptual models can be used as evaluation tools in a preliminary step to identify the main evolutionary processes responsible for soil and water salinization. This study aimed to propose a conceptual model for water fluxes in a coastal area affected by salinity, which can help to identify the relationships between agricultural landscape evolution and actual salinity. First, we conducted field investigations from 2012 to 2016, mainly based on both soil (EC 1/5 ) and water (EC w ) electrical conductivity survey. This allowed us to characterize spatial structures for EC 1/5 and EC w and to identify the river as a preponderant factor in land salinization. Subsequently, we proposed and used a conceptual model for water fluxes and conducted a time analysis (1962-2012) for three of its main constitutive elements, namely climate, river, and land systems. When integrated within the conceptual model framework, it appeared that the evolution of all constitutive elements since 1962 was responsible for the disruption of system equilibrium, favoring overall salt accumulation in the soil root zone. Copyright © 2017 Elsevier B.V. All rights reserved.

Comparison of single extraction procedures and the application of an index for the assessment of heavy metal bioavailability in river sediments.

PubMed

Sakan, Sanja; Popović, Aleksandar; Škrivanj, Sandra; Sakan, Nenad; Đorđević, Dragana

2016-11-01

Metals in sediments are present in different chemical forms which affect their ability to transfer. The objective of this body of work was to compare different extraction methods for the bioavailability evaluation of some elements, such as Ba, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Ni, Pb, V and Zn from Serbian river sediments. A bioavailability risk assessment index (BRAI) was used for the quantification of heavy metal bioavailability in the sediments. Actual and potential element availability was assessed by single extractions with mild (CaCl 2 and CH 3 COONH 4 ) and acidic (CH 3 COOH) extractants and complexing agents (EDTA). Aqua regia extraction was used for the determination of the pseudo-total element content in river sediments. In different single extraction tests, higher extraction of Cd, Cu, Zn and Pb was observed than for the other elements. The results of the single extraction tests revealed that there is a considerable chance of metal leaching from the sediments assessed in this study. When the BRAI was applied, the results showed a high risk of heavy metal bioavailability in Serbian river sediments.

Water, energy, and biogeochemical budget research at Sleepers River Research Watershed, Vermont

USGS Publications Warehouse

Shanley, James B.; Sundquist, E.T.; Kendall, Carol

1995-01-01

The U.S. Geological Survey has selected the Sleepers River Research Watershed (Sleepers River) near Danville, Vt., as one of five sites for the investigation of Water, Energy, and Biogeochemical Budgets (WEBB). Sleepers River was chosen because it is a well-designed outdoor laboratory with a long history of hydrologic data collection and research, and also because it provides an ideal opportunity for collaboration among the U.S. Geological Survey, other Federal agencies, and universities at the site. The multiple subwatersheds at Sleepers River present a unique opportunity to investigate hydrologic, energy, and biogeochemical processes over a variety of spatial scales. This WEBB study builds on fundamental research on process mechanisms and rates at the plot scale (in this case, a hillslope). Results then are scaled up to interpret the hydrochemical response of first- and higher- order basins. Five research elements make up the Sleepers River WEBB project. Individually, each of the five elements is designed to investigate specific WEBB processes (such as CO2 efflux through a snowpack), address specific WEBB issues (such as scaling and flowpaths), or apply specific WEBB approaches (such as integrated chemical and physical study of a hillslope). The research elements overlap so that many of the processes investigated will be assessed in more than one way, thus allowing independent verification of research results. For example, flowpath information will be derived separately by use of isotopic tracers, conservative chemical solutes, and soil-moisture fluxes. Collectively, the five elements constitute an integrated approach to a comprehensive understanding of WEBB processes needed for the prediction of the effects of global change.

Limitless Analytic Elements

NASA Astrophysics Data System (ADS)

Strack, O. D. L.

2018-02-01

We present equations for new limitless analytic line elements. These elements possess a virtually unlimited number of degrees of freedom. We apply these new limitless analytic elements to head-specified boundaries and to problems with inhomogeneities in hydraulic conductivity. Applications of these new analytic elements to practical problems involving head-specified boundaries require the solution of a very large number of equations. To make the new elements useful in practice, an efficient iterative scheme is required. We present an improved version of the scheme presented by Bandilla et al. (2007), based on the application of Cauchy integrals. The limitless analytic elements are useful when modeling strings of elements, rivers for example, where local conditions are difficult to model, e.g., when a well is close to a river. The solution of such problems is facilitated by increasing the order of the elements to obtain a good solution. This makes it unnecessary to resort to dividing the element in question into many smaller elements to obtain a satisfactory solution.

Groundwater flow in the Venice lagoon and remediation of the Porto Marghera industrial area (Italy)

NASA Astrophysics Data System (ADS)

Beretta, Giovanni Pietro; Terrenghi, Jacopo

2017-05-01

This study aims to determine the groundwater flow in a large area of the Venice (northeast Italy) lagoon that is under great anthropogenic pressure, which is influencing the regional flow in the surficial aquifer (about 30 m depth). The area presents several elements that condition the groundwater flow: extraction by means of drainage pumps and wells; tidal fluctuation; impermeable barriers that define part of the coastline, rivers and artificial channels; precipitation; recharge, etc. All the elements were studied separately, and then they were brought together in a numerical groundwater flow model to estimate the impact of each one. Identification of the impact of each element will help to optimise the characteristics of the Porto Marghera remediation systems. Longstanding industrial activity has had a strong impact on the soil and groundwater quality, and expensive and complex emergency remediation measures in problematic locations have been undertaken to ensure the continuity of industrial and maritime activities. The land reclamation and remediation works withdraw 56-74% of the water budget, while recharge from the river accounts for about 21-48% of the input. Only 21-42% of groundwater in the modelled area is derived from natural recharge sources, untouched by human activity. The drop of the piezometric level due to the realization of the upgradient impermeable barrier can be counteracted with the reduction of the pumping rate of the remediation systems.

Water Quality Assessment of the Buffalo River, Arkansas, United States

NASA Astrophysics Data System (ADS)

Bolin, K. L.; Ruhl, L. S.

2017-12-01

The Buffalo River was established as a National River by the U.S. Congress in 1972, and runs approximately 150 miles from Newton County, Arkansas to Baxter County where it joins the White River. The Buffalo National River is the one of the last free flowing rivers in the continental U.S. with a rich cultural and political history surrounding it. The geology surrounding the river can be characterized by its karst environment, which has led to the many caves, depressions, and sinkholes found along the river. Karst environments are more susceptible to groundwater pollution so drainage from septic systems is a major concern for towns along the river. There are also numerous abandoned mines in the Buffalo River watershed, especially in the Rush area, which was mined for lead and zinc. Additionally, an increase in livestock production in the area is also a concern for increased nitrate and phosphate, along with fertilizer runoff from agricultural areas. The purpose of this study was to determine the water quality changes along the Buffalo River from human and environmental influences. Samples at six different locations along the river were collected along with parameters such as pH, conductivity, salinity, and temperature during several trips in the summer of 2017. Water samples were analyzed for cations and anions by IC, trace metals by ICPMS, and Escherichia coli with agar plate colony counts. The results were used to map geochemical changes in the Buffalo River watershed, and calculate enrichment factors of constituents (like nitrate, phosphate, and trace elements) as the water flowed downstream.

Soft systems methodology and the ecosystem approach: a system study of the Cooum River and environs in Chennai, India.

PubMed

Bunch, Martin J

2003-02-01

This paper discusses the integration of soft systems methodology (SSM) within an ecosystem approach in research to support rehabilitation and management of the Cooum River and environs in Chennai, India. The Cooum is an extremely polluted urban stream. Its management is complicated by high rates of population growth, poverty, uncontrolled urban development, jurisdictional conflicts, institutional culture, flat topography, tidal action, blockage of the river mouth, and monsoon flooding. The situation is characterized by basic uncertainty about main processes and activities, and the nature of relationships among actors and elements in the system.SSM is an approach for dealing with messy or ill-structured problematic situations involving human activity. In this work SSM contributed techniques (such as "rich picture" and "CATWOE" tools) to description of the Cooum situation as a socioecological system and informed the approach itself at a theoretical level. Application of three general phases in SSM is discussed in the context of the Cooum River research: (1) problem definition and exploration of the problem situation, (2) development of conceptual models of relevant systems, and (3) the use of these to generate insight and stimulate debate about desirable and feasible change. Its use here gives weight to the statement by others that SSM would be a particularly appropriate methodology to operate the ecosystem approach. As well as informing efforts at management of the Cooum system, this work led the way to explore an adaptive ecosystem approach more broadly to management of the urban environment for human health in Chennai.

Distribution of trace elements in the aquatic ecosystem of the Thigithe river and the fish Labeo victorianus in Tanzania and possible risks for human consumption.

PubMed

Mataba, Gordian Rocky; Verhaert, Vera; Blust, Ronny; Bervoets, Lieven

2016-03-15

The aim of the present study was to assess the distribution of trace elements in the aquatic ecosystem of the Thigithe river. Samples of surface water, sediment and fish were collected up- and downstream of the North Mara Gold Mine (Tanzania) and following trace elements were analysed: As, Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn. Trace element concentrations in surface water were below or near the detection limit. Regarding the sediments, relative high concentrations of arsenic at all sites and high levels of mercury at a site downstream of the mine where artisanal mining is performed were observed. Trace element concentrations in Ningu fish tissues (Labeo victorianus) were comparable to slightly higher than levels in fishes from unpolluted environments. For none of the measured human health risk by consumption of fish from the Thigithe river is expected when the Tanzanian average amount of 17 g/day is consumed. However, for Hg and As the advised maximum daily consumption of Ningu fish was lower than 100g. As a result fishermen and people living along the shores of the river consuming more fish than the average Tanzanian fish consumption set by the FAO (2005) are possibly at risk. Copyright © 2015 Elsevier B.V. All rights reserved.

Trace Elements in Dominant Species of the Fenghe River, China: Their Relations to Environmental Factors.

PubMed

Yang, Yang; Zhou, Zhengchao; Bai, Yanying; Jiao, Wentao; Chen, Weiping

2016-07-01

The distribution of trace elements (TEs) in water, sediment, riparian soil and dominant plants was investigated in the Fenghe River, Northwestern China. The Fenghe River ecosystem was polluted with Cd, Cr, Hg and Pb. There was a high pollution risk in the midstream and downstream regions and the risk level for Cd was much higher than that of the other elements. The average values of bioconcentration coefficient for Cd and Zn were 2.21 and 1.75, respectively, indicating a large accumulation of Cd and Zn in the studied species. With broad ecological amplitudes, L. Levl. et Vant. Trin., and L. had the greatest TE concentrations in aboveground and belowground biomass of the studied species and were potential biomonitors or phytoremediators for the study area. Multivariate techniques including cluster analysis, correlation analysis, principal component analysis, and canonical correspondence analysis were used to analyze the relations between TE concentrations in plants and various environmental factors. The soil element concentration is the main factor determining the accumulation of TEs in plants. The co-release behavior of common pollutants and TEs drove the accumulation of Hg, Cd, and As in the studied plants. Significant enrichment of some elements in the Fenghe River has led to a decline in the biodiversity of plants. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

The Grain-size Patchiness of Braided Gravel-Bed Streams: Example of the Urumqi River (northeast Tian Shan, China)

NASA Astrophysics Data System (ADS)

Guerit, L.; Barrier, L.; Narteau, C.; Métivier, F.; Liu, Y.; Lajeunesse, E.; Gayer, E.; Malverti, L.; Meunier, P.; Ye, B.

2012-04-01

In gravel-beds rivers, sediments are sorted into patches of different grain-sizes. For single-thread streams, it has long been shown that this local granulometric sorting is closely linked to the channel morpho-sedimentary elements. For braided streams, this relation is still unclear. In such rivers, many observations of vertical sediment sorting has led to the definition of a surface and a subsurface layers. Because of this common stratification, methods for sampling gravel-bed rivers have been divided in two families. The surface layer is generally sampled by surface methods and the subsurface layer by volumetric methods. Yet, the equivalency between the two kind of techniques is still a key question. In this study, we characterized the grain-size distribution of the surface layer of the Urumqi River, a shallow braided gravel-bed river in China, by surface-count (Wolman grid-by-number) and volumetric (sieve-by-weight) sampling methods. An analysis of two large samples (212 grains and 3226 kg) show that these two methods are equivalent to characterize the river-bed surface layer. Then, we looked at the grain-size distributions of the river-bed morpho-sedimentary elements: (1) chutes at flow constrictions, which pass downstream to (2) anabranches and (3) bars at flow expansions. Using both sampling methods, we measured the diameter of more than 2300 grains and weight more than 6000 kg of grains larger than 4 mm. Our results show that the three morpho-sedimentary elements correspond only to two kinds of grain-size patches: (1) chutes composed of one coarse-grained top layer lying on finer deposits, and (2) anabranches and bars made up of finer-grained deposits more homogeneous in depth. On the basis of these quantitative observations, together with the concave or convex morphology of the different elements, we propose that chute patches form by erosion and transit with size-selective entrainment, whereas anabranch and bar patches rather develop and migrate by transit and deposition. These patch features may be typical of shallow braided gravel-bed rivers and should be considered in future works about on bedload transport processes and their geomorphologic and stratigraphic results.

[Relationship between groundwater quality index of nutrition element and organic matter in riparian zone and water quality in river].

PubMed

Hua-Shan, Xu; Tong-Qian, Zhao; Hong-Q, Meng; Zong-Xue, Xu; Chao-Hon, Ma

2011-04-01

Riparian zone hydrology is dominated by shallow groundwater with complex interactions between groundwater and surface water. There are obvious relations of discharge and recharge between groundwater and surface water. Flood is an important hydrological incident that affects groundwater quality in riparian zone. By observing variations of physical and chemical groundwater indicators in riparian zone at the Kouma section of the Yellow River Wetland, especially those took place in the period of regulation for water and sediment at the Xiaolangdi Reservoir, relationship between the groundwater quality in riparian zone and the flood water quality in the river is studied. Results show that there will be great risk of nitrogen, phosphorus, nitrate nitrogen and organic matter permeating into the groundwater if floodplain changes into farmland. As the special control unit of nitrogen pollution between rivers and artificial wetlands, dry fanning areas near the river play a very important role in nitrogen migration between river and groundwater. Farm manure as base fertilizer may he an important source of phosphorus leak and loss at the artificial wetlands. Phosphorus leaks into the groundwater and is transferred along the hydraulic gradient, especially during the period of regulation for water and sediment at the Xiaolangdi Reservoir. The land use types and farming systems of the riparian floodplain have a major impact on the nitrate nitrogen contents of the groundwater. Nitrogen can infiltrate and accumulate quickly at anaerobic conditions in the fish pond area, and the annual nitrogen achieves a relatively balanced state in lotus area. In those areas, the soil is flooded and at anaerobic condition in spring and summer, nitrogen infiltrates and denitrification significantly, but soil is not flooded and at aerobic condition in the autumn and winter, and during these time, a significant nitrogen nitrification process occurs. In the area between 50 m and 200 m from the river bank, which is the efficient microbial nitrogen purification unit, nitrification-denitrification is intensive. Farm manure is an important source of organic matter loss at the artificial wetlands. Floodplain has sandy soil texture, with high infiltration capacity and low water and fertilizer conservation ability. Such features are prone for the loss of surface soil nutrition and organic matter if agricultural activities taken place in these areas change the land use of wetlands and apply extensive fertilizer. The infiltrated nutrition elements and organic matter can pollute the groundwater and the river. Compared with the losses of nutrition element and organic matter caused by surface runoff, the infiltrated process is even more prominent. As typical floodplain groundwater-river ecotone, the area between 50 m and 200 m from the river bank is a momentous pollution purification unit. Rational protection for this region is critical for the conservation of water quality in the river and groundwater.

Organic carbon and nitrogen export from a tropical dam-impacted floodplain system

NASA Astrophysics Data System (ADS)

Zurbrügg, R.; Suter, S.; Lehmann, M. F.; Wehrli, B.; Senn, D. B.

2012-06-01

Tropical floodplains play an important role in organic matter transport, storage, and transformation between headwaters and oceans. However, the fluxes and quality of organic carbon (OC) and organic nitrogen (ON) in tropical river-floodplain systems are not well constrained. We explored the quantity and characteristics of dissolved and particulate organic matter (DOM and POM) in the Kafue River flowing through the Kafue Flats (Zambia). The Kafue Flats are a tropical dam-impacted river-floodplain system in the Zambezi River basin. During the flooding season, >80% of the Kafue River water passed through the floodplain, mobilizing large quantities of OC and ON, which resulted in a net export of 75 kg OC km-2 d-1 and 2.9 kg ON km-2 d-1, 80% of which was in the dissolved form. Mass budget estimates showed that ON export, denitrification, and burial caused an annual deficit of ~21 000 t N yr-1 in the Kafue Flats. A N isotope balance and the δ15N of DON and PON suggest that N-fixation must level out the large N losses. The elemental C:N ratio of ~20, the δ13C values of higher than -24‰, and spectroscopic properties (excitation-emission matrices) showed that DOM in the river was mainly of terrestrial origin. Despite a threefold increase in OC loads due to inputs from the floodplain, the river DOM characteristics remained relatively constant along the sampled 400-km river reach. This suggested that floodplain DOM had similar properties than DOM from the upstream reservoir. In contrast, based on its low δ13C of -29‰ and the C:N ratio of ~8, POM originated from phytoplankton production in the upstream reservoir and in the floodplain. While the reservoir had little impact on DOM properties, terrestrial POM was efficiently trapped and, instead, phytoplankton-derived POM was discharged to the downstream Kafue Flats.

Sediment cores as archives of historical changes in floodplain lake hydrology.

PubMed

Lintern, Anna; Leahy, Paul J; Zawadzki, Atun; Gadd, Patricia; Heijnis, Henk; Jacobsen, Geraldine; Connor, Simon; Deletic, Ana; McCarthy, David T

2016-02-15

Anthropogenic activities are contributing to the changing hydrology of rivers, often resulting in their degradation. Understanding the drivers and nature of these changes is critical for the design and implementation of effective mitigation strategies for these systems. However, this can be hindered by gaps in historical measured flow data. This study therefore aims to use sediment cores to identify historical hydrological changes within a river catchment. Sediment cores from two floodplain lakes (billabongs) in the urbanised Yarra River catchment (Melbourne, South-East Australia) were collected and high resolution images, trends in magnetic susceptibility and trends in elemental composition through the sedimentary records were obtained. These were used to infer historical changes in river hydrology to determine both average trends in hydrology (i.e., coarse temporal resolution) as well as discrete flood layers in the sediment cores (i.e., fine temporal resolution). Through the 20th century, both billabongs became increasingly disconnected from the river, as demonstrated by the decreasing trends in magnetic susceptibility, particle size and inorganic matter in the cores. Additionally the number of discrete flood layers decreased up the cores. These reconstructed trends correlate with measured flow records of the river through the 20th century, which validates the methodology that has been used in this study. Not only does this study provide evidence on how natural catchments can be affected by land-use intensification and urbanisation, but it also introduces a general analytical framework that could be applied to other river systems to assist in the design of hydrological management strategies. Copyright © 2015 Elsevier B.V. All rights reserved.

Vertical distribution of trace-element concentrations and occurrence of metallurgical slag particles in accumulated bed sediments of Lake Roosevelt, Washington, September 2002

USGS Publications Warehouse

Cox, S.E.; Bell, P.R.; Lowther, J.S.; Van Metre, P.C.

2005-01-01

Sediment cores were collected from six locations in Lake Roosevelt to determine the vertical distributions of trace-element concentrations in the accumulated sediments of Lake Roosevelt. Elevated concentrations of arsenic, cadmium, copper, lead, mercury, and zinc occurred throughout much of the accumulated sediments. Concentrations varied greatly within the sediment core profiles, often covering a range of 5 to 10 fold. Trace-element concentrations typically were largest below the surficial sediments in the lower one-half of each profile, with generally decreasing concentrations from the 1964 horizon to the surface of the core. The trace-element profiles reflect changes in historical discharges of trace elements to the Columbia River by an upstream smelter. All samples analyzed exceeded clean-up guidelines adopted by the Confederated Tribes of the Colville Reservation for cadmium, lead, and zinc and more than 70 percent of the samples exceeded cleanup guidelines for mercury, arsenic, and copper. Although 100 percent of the samples exceeded sediment guidelines for cadmium, lead, and zinc, surficial concentrations of arsenic, copper, and mercury in some cores were less than the sediment-quality guidelines. With the exception of copper, the trace-element profiles of the five cores collected along the pre-reservoir Columbia River channel typically showed trends of decreasing concentrations in sediments deposited after the 1964 time horizon. The decreasing concentrations of trace elements in the upper half of cores from along the pre-reservoir Columbia River showed a pattern of decreasing concentrations similar to reductions in trace-element loading in liquid effluent from an upstream smelter. Except for arsenic, trace-element concentrations typically were smaller at downstream reservoir locations along the pre-reservoir Columbia River. Trace-element concentration in sediments from the Spokane Arm of the reservoir showed distinct differences compared to the similarities observed in cores from along the pre-reservoir Columbia River. Particles of slag, which have physical and chemical characteristics of slag discharged to the Columbia River by a lead-zinc smelter upstream of the reservoir at Trail, British Columbia, were found in sediments of Lake Roosevelt. Slag particles are more common in the upstream reaches of the reservoir. The chemical composition of the interior matrix of slag collected from Lake Roosevelt closely approximated the reported elemental concentrations of fresh smelter slag, although evidence of slag weathering was observed. Exfoliation flakes were observed on the surface of weathered slag particles isolated from the core sediments. The concentrations of zinc on the exposed surface of slag grains were smaller than concentrations on interior surfaces. Weathering rinds also were observed in the cross section of weathered slag grains, indicating that the glassy slag material was undergoing hydration and chemical weathering. Trace elements observed in accumulated sediments in the middle and lower reaches of the reservoir are more likely due to the input from liquid effluent discharges compared to slag discharges from the upstream smelter.

The potential association between menta deformities and trace elements in Chironomidae (Diptera) taken from a heavy metal contaminated river.

PubMed

Martinez, E A; Moore, B C; Schaumloffel, J; Dasgupta, N

2002-04-01

Elevated morphological deformity rates in Chironomidae larvae have been attributed to such pollutants as oil tars, pesticides, organochlorines, and heavy metals. The potential of chironomids as biological indicators of heavy metal contamination and bioavailability in a contaminated ecosystem was assessed. Chironomid larvae and river sediment were collected from the Coeur d' Alene River system, Idaho, USA, contaminated with heavy metals from mining activities. Chironomid larvae collected at contaminated sites exhibited mouthpart deformity proportions between 3.8 and 10.3% compared to the control site of 0.9%. As, Cd, Cu, Ni, Pb, and Zn were determined in both larvae and sediment samples. Significant correlation between metal concentrations and deformity rates were observed for all metals except Ni. The data also suggests that feeding habits may influence differences in pollution tolerance among genera.

Characterisation of bed sediments and suspension of the river Po (Italy) during normal and high flow conditions.

PubMed

Davide, Vignati; Pardos, Michel; Diserens, Jérôme; Ugazio, Giancarlo; Thomas, Richard; Dominik, Janusz

2003-07-01

Grain-size distribution, major elements, nutrients and trace metals were determined in bed sediments and suspension collected at 10 representative sites along the river Po under normal and high flow conditions. Grain-size distribution and major element composition of suspension highlighted the presence of two distinct particle populations in the upper-middle Po (coarser particles, lower carbonate content) and in the lower Po (finer particles, higher carbonate content). This change partly reflects the geological differences between the two parts of the basin, and also the presence of a hydroelectric power plant at Isola Serafini (Piacenza). With respect to environmental quality issues, bed sediments and suspension provide similar results. A moderate nutrient pollution is found in all but the uppermost parts of the river basin, while the most significant inputs of trace metals appear to originate from the urban areas of Turin and Milan. Calculation of sediment enrichment factors identifies Cd, Cu, Hg and Zn as the most impacted elements by human activities. On the other hand, the high levels of Ni and Cr throughout the river seem to derive mainly from the presence of basic rocks in the upper and middle parts of the basin. Both nutrient and trace metal particulate concentrations substantially decrease under high flow conditions possibly due to "flushing" of contaminated bed sediments and resuspension of coarser material. Under normal flow conditions, water hydrochemistry and concentrations of some elements (As, Ca, Cr, Cu, K, Mg, Mn, Na, Ni, and Pb) in the dissolved phase (<0.45 microm) were also determined. Calculation of trace metals partition coefficients shows that the relative importance of the particulate and water phases varies in response to water hydrochemistry and suspended solid content, but that most elements achieve a conditional equilibrium in the lower stretches of the river Po. These results are the first of this kind reported for the whole river course and highlight the factors and mechanisms controlling the origin, mobility and fate of nutrients and trace metals in the river Po.

A saprobic index for biological assessment of river water quality in Brazil (Minas Gerais and Rio de Janeiro states).

PubMed

Junqueira, Marilia Vilela; Friedrich, Günther; Pereira de Araujo, Paulo Roberto

2010-04-01

Based upon several years of experience in investigations with macrozoobenthos in rivers in the states of Minas Gerais and Rio de Janeiro, a biological assessment system has been developed to indicate pollution levels caused by easily degradable organic substances from sewers. The biotic index presented here is aimed at determining water's saprobic levels and was, therefore, named the "Saprobic Index for Brazilian Rivers in Minas Gerais and Rio de Janeiro states" (ISMR). For this purpose, saprobic valences and weights have been established for 122 taxa of tropical macrozoobenthos. Investigations were carried out in little, medium sized and big rivers in mountains and plains. Through ISMR, a classification of water quality and the respective cartographic representation can be obtained. Data collection and treatment methods, as well as the limitations of the biotic index, are thoroughly described. ISMR can also be used as an element to establish complex multimetric indexes intended for an ecological integrity assessment, where it is essential to indicate organic pollution.

Tracing water and suspended matter in Raritan and Lower New York Bays using dissolved and particulate elemental concentrations

USGS Publications Warehouse

Paulson, A.J.

2005-01-01

The concentrations of 22 elements also were measured in the suspended matter of Raritan and Lower New York Bays and brackish water sources. The elemental composition of the suspended matter in surface and bottom waters was correlated with Fe concentrations, which ranged between 50 and 900 μmol g− 1. Statistical differences among the geographical regions were detected in the relationships of Ti, Ni, Co, As, and U with Fe, with particulate As being an especially strong geochemical indicator of Raritan River particles. The geochemical signatures of Lower New York Bay particles were similar to those of Upper New York Bay. The geochemical signatures of Raritan River particles were distinctly different than those of the Upper New York Bay, but the influence of Raritan River particles appeared to be limited to only inner Raritan Bay. This study illustrates the utility of trace elements for characterization of physical processes in complex estuaries.

Survey of chemical contaminants in the Hanalei River, Kaua'i, Hawai'i, 2001

USGS Publications Warehouse

Orazio, Carl E.; May, Thomas W.; Gale, Robert W.; Meadows, John C.; Brumbaugh, William G.; Echols, Kathy R.; Steiner, William W.M.; Berg, Carl J.

2007-01-01

The Hanalei River on the island of Kaua'i in Hawai'i was designated an American Heritage River in 1998, providing special attention to natural resource protection, economic revitalization, and historic and cultural preservation. Agricultural, urban, and tourism-related activities are potential sources of contamination within the Hanalei River watershed. The objective of this study was to measure certain persistent organic chemicals and elements in the Hanalei River.During a relatively low-flow period in December of 2001, samples of native Akupa sleeper fish (Eleotris sandwicensis), freshwater Asian clam (Corbicula fluminea), giant mud crab (Scylla serrata), surface water, and stream bed sediment were collected from a lower estuarine reach of the river near its mouth at Hanalei Bay and from an upper reach at the Hanalei National Wildlife Refuge. Samples were analyzed for residues of urban and agricultural chemicals including organochlorine pesticides, polychlorinated biphenyls, polycyclic aromatic hydrocarbons, and elements (including mercury, lead, cadmium, arsenic, and selenium). Organic contaminants were extracted from the samples with solvent, enriched, and then analyzed by gas chromatographic analysis with electron capture or mass spectrometric detection. Samples were acid-digested for semi-quantitative analysis for elements by inductively-coupled plasma-mass spectrometry and for quantitative analysis by atomic absorption spectrophotometry.Concentrations of organochlorine pesticides, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls in biota, surface water, and bed sediment sampled from the Hanalei River ranged from nondetectable to very low levels. Polychlorinated biphenyls were below detection in all samples. Dieldrin, the only compound detected in the water samples, was present at very low concentrations of 1-2 nanograms per liter. Akupa sleeper fish and giant mud crabs from the lower reach ranged from 1 to 5 nanograms per gram (wet weight) dieldrin and from less than 0.3 to 2.1 nanograms per gram total chlordane. Concentrations of individual polycyclic aromatic hydrocarbons in the lower reach bed sediments ranged from less than 1 to 190 nanograms per gram (dry weight). Relative concentrations (patterns) of the polycyclic aromatic hydrocarbons in one portion of a sediment sample indicated combustion sources. Concentrations of elements in the surface water, biota, and sediment samples were below toxicity thresholds of ecological concern. In summary, concentrations of the organic contaminants and elements targeted by this study of the Hanalei River in 2001 were below U.S. Environmental Protection Agency probable adverse effects levels for aquatic organisms.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jay, David A.

Long-term changes and fluctuations in river flow, water properties, tides, and sediment transport in the Columbia River and its estuary have had a profound effect on Columbia River salmonids and their habitat. Understanding the river-flow, temperature, tidal, and sediment-supply regimes of the Lower Columbia River (LCR) and how they interact with habitat is, therefore, critical to development of system management and restoration strategies. It is also useful to separate management and climate impacts on hydrologic properties and habitat. This contract, part of a larger project led by the National Oceanic and Atmospheric Administration (NOAA), consists of three work elements, onemore » with five tasks. The first work element relates to reconstruction of historic conditions in a broad sense. The second and third elements consist, respectively, of participation in project-wide integration efforts, and reporting. This report focuses on the five tasks within the historic reconstruction work element. It in part satisfies the reporting requirement, and it forms the basis for our participation in the project integration effort. The first task consists of several topics related to historic changes in river stage and tide. Within this task, the chart datum levels of 14 historic bathymetric surveys completed before definition of Columbia River Datum (CRD) were related to CRD, to enable analysis of these surveys by other project scientists. We have also modeled tidal datums and properties (lower low water or LLW, higher high water or HHW, mean water level or MWL, and greater diurnal tidal range or GDTR) as a function of river flow and tidal range at Astoria. These calculations have been carried for 10 year intervals (1940-date) for 21 stations, though most stations have data for only a few time intervals. Longer-term analyses involve the records at Astoria (1925-date) and Vancouver (1902-date). Water levels for any given river flow have decreased substantially (0.3-1.8 m, depending on river flow and tidal range), and tidal ranges have increased considerably (by a factor of 1.5 to 4 for most river-flow levels) since the 1900-1940 period at most stations, with the largest percentage changes occurring at upriver stations. These changes have been caused by a combination of changes in channel roughness, shape and alignment, changes in coastal tides, and (possibly) bed degradation. Tides are growing throughout the Northeast Pacific, and Astoria (Tongue Pt) has one of the most rapid rates of increase in tidal range in the entire Eastern Pacific, about 0.3m per century. More than half of this change appears to result from changes within the system, the rest from larger scale changes in coastal tides. Regression models of HHW have been used to estimate daily shallow water habitat (SWHA) available in a {approx}25 mile long reach of the system from Eagle Cliff to Kalama for 1925-2004 under four different scenarios (the four possible combinations of diked/undiked and observed flow/ virgin flow). More than 70% of the habitat in this reach has been lost (modern conditions vs. virgin flow with not dikes). In contrast, however, to the reach between Skamokawa and Beaver, selective dike removal (instead of a combination of dike removal and flow restoration) would suffice to increase spring SWHA. The second task consists of reconstruction of the hydrologic cycle before 1878, based on historic documents and inversion of tidal data collected before the onset of the historic flow record in 1878. We have a complete list of freshet times and peak flows for 1858-1877, and scattered freshet information for 1841-1857. Based on tidal data, we have reconstructed the annual flow cycles for 1870 and 1871; other time periods between 1854 and 1867 are under analysis. The three remaining tasks relate to post-1878 hydrologic conditions (flows, sediment supply and water temperature), and separation of the human and climate influences thereon. Estimated ob-served (sometimes routed), adjusted (corrected for reservoir manipulation) and virgin (corrected also for irrigation diversion) flows for 1878-2004 have been compiled for the Columbia River at The Dalles and Beaver, and for the Willamette River at Portland. Sediment transports for the ob-served, adjusted and virgin flows have been calculated for 1878-2004 for the Columbia River at Vancouver and Beaver, for the Willamette River at Portland, and for other west-side tributaries seaward of Vancouver. For Vancouver and Portland, it has been possible to estimate sand trans-port (including gravel), fine sediment transport and total load. Only total load can be estimated at Beaver, and only fine sediment transport can be determined for the west-side tributaries, except for the post-1980 period influenced by the 1980 eruption of Mt St. Helens. Changes in flows and sediment transport due to flow regulation, irrigation diversion, and climate have been estimated.« less

Occurrence and distribution of dissolved trace elements in the surface waters of the Yakima River basin, Washington

USGS Publications Warehouse

Hughes, Curt A.

2003-01-01

Instantaneous arsenic loads calculated for August 1999 were similar to mean monthly loads determined in August 1989 at two intensive fixed sites located on the Yakima main stem. In August 1999, arsenic loads increased twofold between the Yakima River at river mile 72 above Satus and the Yakima River at Kiona at river mile 29.9. The dissolved arsenic loads for the Yakima River at Euclid Bridge at river mile 55 near Grandview and Yakima River at Kiona were within 13 percent of the August 1989 levels.

Selenium and other elements in freshwater fishes from the irrigated San Joaquin Valley, California

USGS Publications Warehouse

Saiki, M.K.; Jennings, M.R.; May, T.W.

1992-01-01

Arsenic (As), chromium (Cr), mercury (Hg), and selenium (Se) were measured in composite whole-body samples of five fishes — bluegill (Lepomis macrochirus), common carp (Cyprinus carpio), mosquitofish (Gambusia affinis), largemouth bass (Micropterus salmoides), and Sacramento blackfish (Orthodon microlepidotus) — from the San Joaquin River system to determine if concentrations were elevated from exposure to agricultural subsurface (tile) drainage. Except for Cr, the concentrations of these elements in fishes from one or more sites were elevated; however, only Se approached concentrations that may adversely affect survival, growth, or reproduction in warm water fishes. Moreover, only Se among the four measured elements exhibited a geographic (spatial) pattern that coincided with known inflows of tile drainage to the San Joaquin River and its tributaries. Historical data from the Grassland Water District (Grasslands; a region exposed to concentrated tile drainage) suggested that concentrations of Se in fishes were at maximum during or shortly after 1984 and have been slightly lower since then. The recent decline of Se concentrations in fishes from the Grasslands could be temporary if additional acreages of irrigated lands in this portion of the San Joaquin Valley must be tile-drained to protect agricultural crops from rising groundwater tables.

Integrated Forecast-Decision Systems For River Basin Planning and Management

NASA Astrophysics Data System (ADS)

Georgakakos, A. P.

2005-12-01

A central application of climatology, meteorology, and hydrology is the generation of reliable forecasts for water resources management. In principle, effective use of forecasts could improve water resources management by providing extra protection against floods, mitigating the adverse effects of droughts, generating more hydropower, facilitating recreational activities, and minimizing the impacts of extreme events on the environment and the ecosystems. In practice, however, realization of these benefits depends on three requisite elements. First is the skill and reliability of forecasts. Second is the existence of decision support methods/systems with the ability to properly utilize forecast information. And third is the capacity of the institutional infrastructure to incorporate the information provided by the decision support systems into the decision making processes. This presentation discusses several decision support systems (DSS) using ensemble forecasting that have been developed by the Georgia Water Resources Institute for river basin management. These DSS are currently operational in Africa, Europe, and the US and address integrated water resources and energy planning and management in river basins with multiple water uses, multiple relevant temporal and spatial scales, and multiple decision makers. The article discusses the methods used and advocates that the design, development, and implementation of effective forecast-decision support systems must bring together disciplines, people, and institutions necessary to address today's complex water resources challenges.

A global model of carbon-nutrient interactions

NASA Technical Reports Server (NTRS)

Moore, Berrien, III; Gildea, Patricia; Vorosmarty, Charles; Mellilo, Jerry M.; Peterson, Bruce J.

1985-01-01

The global biogeochemical model presented has two primary objectives. First, it characterizes natural elemental cycles and their linkages for the four elements significant to Earth's biota: C, N, S, and P. Second, it describes changes in these cycles due to human activity. Global nutrient cycles were studied within the drainage basins of several major world rivers on each continent. The initial study region was the Mississippi drainage basin, concentrating on carbon and nitrogen. The model first establishes the nutrient budgets of the undisturbed ecosystems in a study region. It then uses a data set of land use histories for that region to document the changes in these budgets due to land uses. Nutrient movement was followed over time (1800 to 1980) for 30 ecosystems and 10 land use categories. A geographically referenced ecological information system (GREIS) was developed to manage the digital global data bases of 0.5 x 0.5 grid cells needed to run the model: potential vegetation, drainage basins, precipitation, runoff, contemporary land cover, and FAO soil maps of the world. The results show the contributions of land use categories to river nutrient loads on a continental scale; shifts in nutrient cycling patterns from closed, steady state systems to mobile transient or open, steady state systems; soil organic matter depletion patterns in U.S. agricultural lands; changing nutrient ratios due to land use changes; and the effect of using heavy fertilizer on aquatic systems.

Wetland Flow and Salinity Budgets and Elements of a Decision Support System toward Implementation of Real-Time Seasonal Wetland Salinity Management

DOE Office of Scientific and Technical Information (OSTI.GOV)

Quinn, N.W.T.; Ortega, R.; Rahilly, P.

2011-12-17

The project has provided science-based tools for the long-term management of salinity in drainage discharges from wetlands to the San Joaquin River. The results of the project are being used to develop best management practices (BMP) and a decision support system to assist wetland managers adjust the timing of salt loads delivered to the San Joaquin River during spring drawdown. Adaptive drainage management scheduling has the potential to improve environmental compliance with salinity objectives in the Lower San Joaquin River by reducing the frequency of violation of Vernalis salinity standards, especially in dry and critically dry years. The paired approachmore » to project implementation whereby adaptively managed and traditional practices were monitored in a side-by-side fashion has provided a quantitative measure of the impacts of the project on the timing of salt loading to the San Joaquin River. The most significant accomplishments of the project has been the technology transfer to wetland biologists, ditch tenders and water managers within the Grasslands Ecological Area. This “learning by doing” has build local community capacity within the Grassland Water District and California Department of Fish and Game providing these institutions with new capability to assess and effectively manage salinity within their wetlands while simultaneously providing benefits to salinity management of the San Joaquin River.« less

Selected trace elements in the Sacramento River, California: Occurrence and distribution

USGS Publications Warehouse

Taylor, Howard E.; Antweiler, Ronald C.; Roth, David A.; Dileanis, Peter D.; Alpers, Charles N.

2012-01-01

The impact of trace elements from the Iron Mountain Superfund site on the Sacramento River and selected tributaries is examined. The concentration and distribution of many trace elements—including aluminum, arsenic, boron, barium, beryllium, bismuth, cadmium, cerium, cobalt, chromium, cesium, copper, dysprosium, erbium, europium, iron, gadolinium, holmium, potassium, lanthanum, lithium, lutetium, manganese, molybdenum, neodymium, nickel, lead, praseodymium, rubidium, rhenium, antimony, selenium, samarium, strontium, terbium, thallium, thulium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc, and zirconium—were measured using a combination of inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry. Samples were collected using ultraclean techniques at selected sites in tributaries and the Sacramento River from below Shasta Dam to Freeport, California, at six separate time periods from mid-1996 to mid-1997. Trace-element concentrations in dissolved (ultrafiltered [0.005-μm pore size]) and colloidal material, isolated at each site from large volume samples, are reported. For example, dissolved Zn ranged from 900 μg/L at Spring Creek (Iron Mountain acid mine drainage into Keswick Reservoir) to 0.65 μg/L at the Freeport site on the Sacramento River. Zn associated with colloidal material ranged from 4.3 μg/L (colloid-equivalent concentration) in Spring Creek to 21.8 μg/L at the Colusa site on the Sacramento River. Virtually all of the trace elements exist in Spring Creek in the dissolved form. On entering Keswick Reservoir, the metals are at least partially converted by precipitation or adsorption to the particulate phase. Despite this observation, few of the elements are removed by settling; instead the majority is transported, associated with colloids, downriver, at least to the Bend Bridge site, which is 67 km from Keswick Dam. Most trace elements are strongly associated with the colloid phase going downriver under both low- and high-flow conditions.

Lake Biel Holocene sediment record before and after the Aare river deviation (1878 AD)

NASA Astrophysics Data System (ADS)

Jeannet, Alice; Corella, Juan Pablo; Kremer, Katrina; Girardclos, Stéphanie

2014-05-01

Lake sediments are excellent archives of environmental and climate changes as well as human impact on lake- and river-systems. Lake Biel is a medium-sized peri-alpine lake in Switzerland, with a maximum depth of 74 m, and lies at an altitude of 429 m a.s.l. Lake Biel, which formed during the Pleistocene by glacial erosion, is part of the Aare river system. Our study focuses on the south-west part of the lake basin where the lake sedimentation was originally (i.e. naturally) mainly controlled by autochthonous sedimentation. This area is currently under a strong influence of water and sediment input from this river catchment since the Aare river deviation through the Hagneck canal in 1878. A 10.05 m long composite sediment sequence, cored from a 52 m water depth in September 2011, was built from two long cores retrieved with the ETH Zurich/Eawag Uwitec system. A radiocarbon age model indicates that the retrieved sedimentary sequence spans the last 7500 years. The upper sediments were correlated to previous short core radionuclide stratigraphy for the 1.5 m upper part (Thevenon et al., 2013). Magnetic susceptibility and density were measured by Geotek MultiSensor Core Logger at 0.5 cm resolution. Granulometry was measured with a CILAS grain sizer every 10 cm, and X-ray fluorescence (XRF) was carried out using an Avaatech core scanner at 1-cm resolution. This technique provides semi-quantitative information of the sediment elemental composition and shows how runoff and river input (Ti, Al, Si) or redox conditions (Fe/Mn) vary through time. Lake Biel sediment record suggests marked environmental changes with runoff decrease linked to climate and vegetation change during Atlantic chronobiozone, as well as a complex climate-human impact during the 'La Tène' and Roman cultural times. The most prominent recorded feature is the 10-times increase of sediment rate that occurred after the Aare river deviation through the Hagneck canal into Lake Biel in 1878. This artificial new river input is also linked to a massive and sudden Ti increase, and inversely abrupt Ca decrease in XRF data. This record reveals the significant alteration in the sediment dynamics, and the lake oxygenation changes that the lake experienced when it shifted from a relatively closed basin to a river and delta-influenced basin. Thank you to Flavio S. Anselmetti, Christine Guido and Frédéric Arlaud for help coring on the field and Stefanie Wirth for help at Limnogeology Laboratory. This study, undertaken as a Master thesis, was financed by the Swiss National Foundation projects 121666 and 146889. Reference Thevenon F. et al. 2013. Human impact on the transport of terrigenous and anthropogenic elements to peri-alpine lakes (Switzerland) over the last decades. Aquatic Sciences 75: 413-424.

Multivariate statistical evaluation of dissolved trace elements and a water quality assessment in the middle reaches of Huaihe River, Anhui, China.

PubMed

Wang, Jie; Liu, Guijian; Liu, Houqi; Lam, Paul K S

2017-04-01

A total of 211 water samples were collected from 53 key sampling points from 5-10th July 2013 at four different depths (0m, 2m, 4m, 8m) and at different sites in the Huaihe River, Anhui, China. These points monitored for 18 parameters (water temperature, pH, TN, TP, TOC, Cu, Pb, Zn, Ni, Co, Cr, Cd, Mn, B, Fe, Al, Mg, and Ba). The spatial variability, contamination sources and health risk of trace elements as well as the river water quality were investigated. Our results were compared with national (CSEPA) and international (WHO, USEPA) drinking water guidelines, revealing that Zn, Cd and Pb were the dominant pollutants in the water body. Application of different multivariate statistical approaches, including correlation matrix and factor/principal component analysis (FA/PCA), to assess the origins of the elements in the Huaihe River, identified three source types that accounted for 79.31% of the total variance. Anthropogenic activities were considered to contribute much of the Zn, Cd, Pb, Ni, Co, and Mn via industrial waste, coal combustion, and vehicle exhaust; Ba, B, Cr and Cu were controlled by mixed anthropogenic and natural sources, and Mg, Fe and Al had natural origins from weathered rocks and crustal materials. Cluster analysis (CA) was used to classify the 53 sample points into three groups of water pollution, high pollution, moderate pollution, and low pollution, reflecting influences from tributaries, power plants and vehicle exhaust, and agricultural activities, respectively. The results of the water quality index (WQI) indicate that water in the Huaihe River is heavily polluted by trace elements, so approximately 96% of the water in the Huaihe River is unsuitable for drinking. A health risk assessment using the hazard quotient and index (HQ/HI) recommended by the USEPA suggests that Co, Cd and Pb in the river could cause non-carcinogenic harm to human health. Copyright © 2017 Elsevier B.V. All rights reserved.

Distribution and geochemistry of selected trace elements in the Sacramento River near Keswick Reservoir

USGS Publications Warehouse

Antweiler, Ronald C.; Taylor, Howard E.; Alpers, Charles N.

2012-01-01

The effect of heavy metals from the Iron Mountain Mines (IMM) Superfund site on the upper Sacramento River is examined using data from water and bed sediment samples collected during 1996-97. Relative to surrounding waters, aluminum, cadmium, cobalt, copper, iron, lead, manganese, thallium, zinc and the rare-earth elements (REE) were all present in high concentrations in effluent from Spring Creek Reservoir (SCR), which enters into the Sacramento River in the Spring Creek Arm of Keswick Reservoir. SCR was constructed in part to regulate the flow of acidic, metal-rich waters draining the IMM Superfund site. Although virtually all of these metals exist in SCR in the dissolved form, upon entering Keswick Reservoir they at least partially converted via precipitation and/or adsorption to the particulate phase. In spite of this, few of the metals settled out; instead the vast majority was transported colloidally down the Sacramento River at least to Bend Bridge, 67. km from Keswick Dam.The geochemical influence of IMM on the upper Sacramento River was variable, chiefly dependent on the flow of Spring Creek. Although the average flow of the Sacramento River at Keswick Dam is 250m 3/s (cubic meters per second), even flows as low as 0.3m 3/s from Spring Creek were sufficient to account for more than 15% of the metals loading at Bend Bridge, and these proportions increased with increasing Spring Creek flow.The dissolved proportion of the total bioavailable load was dependent on the element but steadily decreased for all metals, from near 100% in Spring Creek to values (for some elements) of less than 1% at Bend Bridge; failure to account for the suspended sediment load in assessments of the effect of metals transport in the Sacramento River can result in estimates which are low by as much as a factor of 100. ?? 2012.

Distribution and geochemistry of selected trace elements in the Sacramento River near Keswick Reservoir

USGS Publications Warehouse

Antweiler, Ronald C.; Taylor, Howard E.; Alpers, Charles N.

2012-01-01

The effect of heavy metals from the Iron Mountain Mines (IMM) Superfund site on the upper Sacramento River is examined using data from water and bed sediment samples collected during 1996-97. Relative to surrounding waters, aluminum, cadmium, cobalt, copper, iron, lead, manganese, thallium, zinc and the rare-earth elements (REE) were all present in high concentrations in effluent from Spring Creek Reservoir (SCR), which enters into the Sacramento River in the Spring Creek Arm of Keswick Reservoir. SCR was constructed in part to regulate the flow of acidic, metal-rich waters draining the IMM Superfund site. Although virtually all of these metals exist in SCR in the dissolved form, upon entering Keswick Reservoir they at least partially converted via precipitation and/or adsorption to the particulate phase. In spite of this, few of the metals settled out; instead the vast majority was transported colloidally down the Sacramento River at least to Bend Bridge, 67 km from Keswick Dam. The geochemical influence of IMM on the upper Sacramento River was variable, chiefly dependent on the flow of Spring Creek. Although the average flow of the Sacramento River at Keswick Dam is 250 m3/s (cubic meters per second), even flows as low as 0.3 m3/s from Spring Creek were sufficient to account for more than 15% of the metals loading at Bend Bridge, and these proportions increased with increasing Spring Creek flow. The dissolved proportion of the total bioavailable load was dependent on the element but steadily decreased for all metals, from near 100% in Spring Creek to values (for some elements) of less than 1% at Bend Bridge; failure to account for the suspended sediment load in assessments of the effect of metals transport in the Sacramento River can result in estimates which are low by as much as a factor of 100.

Investigation of Sediment Pathways and Concealed Sedimentological Features in Hidden River Cave, Kentucky

NASA Astrophysics Data System (ADS)

Feist, S.; Maclachlan, J. C.; Reinhardt, E. G.; McNeill-Jewer, C.; Eyles, C.

2016-12-01

Hidden River Cave is part of a cave system hydrogeologically related to Mammoth Cave in Kentucky and is a multi-level active cave system with 25km of mapped passages. Upper levels experience flow during flood events and lower levels have continuously flowing water. Improper industrial and domestic waste disposal and poor understanding of local hydrogeology lead to contamination of Hidden River Cave in the early 1940s. Previously used for hydroelectric power generation and as a source of potable water the cave was closed to the public for almost 50 years. A new sewage treatment plant and remediation efforts since 1989 have improved the cave system's health. This project focuses on sedimentological studies in the Hidden River Cave system. Water and sediment transport in the cave are being investigated using sediment cores, surface sediment samples and water level data. An Itrax core scanner is used to analyze sediment cores for elemental concentrations, magnetic susceptibility, radiography, and high resolution photography. Horizons of metal concentrations in the core allow correlation of sedimentation events in the cave system. Thecamoebian (testate amoebae) microfossils identified in surface samples allow for further constraint of sediment sources, sedimentation rates, and paleoclimatic analysis. Dive recorders monitor water levels, providing data to further understand the movement of sediment through the cave system. A general time constraint on the sediment's age is based on the presence of microplastic in the surface samples and sediment cores, and data from radiocarbon and lead-210 dating. The integration of various sedimentological data allows for better understanding of sedimentation processes and their record of paleoenvironmental change in the cave system. Sediment studies and methodologies from this project can be applied to other karst systems, and have important applications for communities living on karst landscapes and their water management policies.

Nano-mineralogy of suspended sediment during the beginning of coal rejects spill.

PubMed

Civeira, Matheus S; Ramos, Claudete G; Oliveira, Marcos L S; Kautzmann, Rubens M; Taffarel, Silvio R; Teixeira, Elba C; Silva, Luis F O

2016-02-01

Ultrafine and nanometric sediment inputs into river systems can be a major source of nutrients and hazardous elements and have a strong impact on water quality and ecosystem functions of rivers and lakes regions. However, little is known to date about the spatial distribution of sediment sources in most large scale river basins in South America. The objective of this work was to study the coal cleaning rejects (CCRs) spill that occurred from a CCRs impoundment pond into the Tubarão River, South Brazil, provided a unique occasion to study the importance and role of incidental nanoparticles associated with pollutant dispersal from a large-scale, acute aquatic pollution event. Multifaceted geochemical research by X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/(Energy Dispersive Spectroscopy) EDS/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM)/EDS, and Raman spectroscopy, provided an in-depth understanding of importance of a nano-mineralogy approach of Aqueous Pollution Scenarios. The electron beam studies showed the presence of a number of potentially hazardous elements (PHEs) in nanoparticles (amorphous and minerals). Some of the neoformed ultrafine/nanoparticles found in the contaminated sediments are the same as those commonly associated with oxidation/transformation of oxides, silicates, sulfides, and sulfates. These data of the secondary ultra/nanoparticles, puts in evidence their ability to control the mobility of PHEs, suggesting possible presentations in environmental technology, including recuperation of sensitive coal mine. The developed methodology facilitated the sediment transport of the catchment providing consistent results and suggesting its usefulness as a tool for temporary rivers management. Copyright © 2015 Elsevier Ltd. All rights reserved.

FINIFLUX: An implicit finite element model for quantification of groundwater fluxes and hyporheic exchange in streams and rivers using radon

NASA Astrophysics Data System (ADS)

Frei, S.; Gilfedder, B. S.

2015-08-01

A quantitative understanding of groundwater-surface water interactions is vital for sustainable management of water quantity and quality. The noble gas radon-222 (Rn) is becoming increasingly used as a sensitive tracer to quantify groundwater discharge to wetlands, lakes, and rivers: a development driven by technical and methodological advances in Rn measurement. However, quantitative interpretation of these data is not trivial, and the methods used to date are based on the simplest solutions to the mass balance equation (e.g., first-order finite difference and inversion). Here we present a new implicit numerical model (FINIFLUX) based on finite elements for quantifying groundwater discharge to streams and rivers using Rn surveys at the reach scale (1-50 km). The model is coupled to a state-of-the-art parameter optimization code Parallel-PEST to iteratively solve the mass balance equation for groundwater discharge and hyporheic exchange. The major benefit of this model is that it is programed to be very simple to use, reduces nonuniqueness, and provides numerically stable estimates of groundwater fluxes and hyporheic residence times from field data. FINIFLUX was tested against an analytical solution and then implemented on two German rivers of differing magnitude, the Salzach (˜112 m3 s-1) and the Rote Main (˜4 m3 s-1). We show that using previous inversion techniques numerical instability can lead to physically impossible negative values, whereas the new model provides stable positive values for all scenarios. We hope that by making FINIFLUX freely available to the community that Rn might find wider application in quantifying groundwater discharge to streams and rivers and thus assist in a combined management of surface and groundwater systems.

The protection of RIVERLIFE by mitigation of flood damages RIVERLIFE

NASA Astrophysics Data System (ADS)

Adler, M. J.

2003-04-01

The long-term development objective of the RIVERLIFE project is to contribute to sustainable human end economic development in the Timis-Bega river basin area as part of the Danube River Basin (DRB), through reinforcing the capacities of Romanian central and local authorities to develop effective mechanisms and tools for integrated river basin management in the Timis-Bega basin. The overall objective of the project is to assist the country in the EU enlargement and accession process to meet the EU requirements of water related Directives with emphasis on the EU Water Framework Directive (WFD). The specific objective of the project is to support the WFD implementation process at the level of a sub-unit within the limits of the DRB, through the development of a River Basin Management Plan (RBMP). The project will also facilitate the implementation of the Danube River Protection Convention (DRPC) as an essential element in the implementation of the Directive in the transboundary river basins. Expected outcomes in the recipient country consist of (i) responding to a real hazard problem, which affects the quality of life of many citizens, and (ii) improvement in the environmental conditions in the targeted areas. Flooding is one of the major natural hazards to human society and an important influence on social and economic development for Romania causing financially greater losses per annum on average than any other natural hazard. One key concept of the WFD is the coordination, organization and regulation of water management at the level of river basins. Therefore, river basin districts are shaped in such a way as to include not only the surface run-off through streams and rivers to the sea, but the total area of land and sea together with the associated groundwater and coastal waters. The concept allows even for the small river basins directly discharging into the sea to be combined into one river basin district. As a principle, the complex decisions on the use or interventions in the aquatic systems within the river basin district limits should take place in an integrated and co-coordinated approach as part of the RBMP. The process includes all RBMP plan development phases for Timis-Bega basin from planning and analysis phases to the assessment and the identification of respective programs of measures intended to achieve the defined environmental objectives for the respective river basin. The central administrative tool of the WFD is the River Basin Management Plan, around which all other elements are set. The river basin becomes the basic unit for all water planning and management interventions according with the physical and hydrological boundaries, but not necessary with its political and administrative limits.

The influence of distinct types of aquatic vegetation on the flow field

NASA Astrophysics Data System (ADS)

Valyrakis, Manousos; Barcroft, Stephen; Yagci, Oral

2014-05-01

The Sustainable management of fluvial systems dealing with flood prevention, erosion protection and restoration of rivers and estuaries requires implementation of soft/green-engineering methods. In-stream aquatic vegetation can be regarded as one of these as it plays an important role for both river ecology (function) and geomorphology (form). The goal of this research is to offer insight gained from pilot experimental studies on the effects of a number of different elements modeling instream, aquatic vegetation on the local flow field. It is hypothesized that elements of the same effective "blockage" area but of distinct characteristics (structure, porosity and flexibility), will affect both the mean and fluctuating levels of the turbulent flow to a different degree. The above hypothesis is investigated through a set of rigorous set of experimental runs which are appropriately designed to assess the variability between the interaction of aquatic elements and flow, both quantitatively and qualitatively. In this investigation three elements are employed to model aquatic vegetation, namely a rigid cylinder, a porous but rigid structure and a flexible live plant (Cupressus Macrocarpa). Firstly, the flow field downstream each of the mentioned elements was measured under steady uniform flow conditions employing acoustic Doppler velocimetry. Three-dimensional flow velocities downstream the vegetation element are acquired along a measurement grid extending about five-fold the element's diameter. These measurements are analyzed to develop mean velocity and turbulent intensity profiles for all velocity components. A detailed comparison between the obtained results is demonstrative of the validity of the above hypothesis as each of the employed elements affects in a different manner and degree the flow field. Then a flow visualization technique, during which fluorescent dye is injected upstream of the element and images are captured for further analysis and comparison, was employed to visualize the flow structures shed downstream the aquatic elements. This method allows to further observe qualitatively and visually identify the different characteristics of the eddies advected downstream, conclusively confirming the results of the aforementioned experimental campaign.

Organic compounds and trace elements in the Pocomoke River and its tributaries

USGS Publications Warehouse

Miller, Cherie V.; Foster, Gregory D.; Huff, Thomas B.; Garbarino, John R.

1999-01-01

In response to concern about recent blooms of the dinoflagellate, Pfiesteria piscicida, samples of sediment and water were collected from the lower Pocomoke River Basin and were screened for trace elements, pesticides, and other organic compounds. A large group of steroid and fatty acid methyl-ester compounds was detected in streamwater using gas chromatography/mass spectroscopy in scan mode. Some of these steroid compounds have been identified and further quantified in bed-sediment extracts. Spatial patterns of the concentrations of cholesterol suggest that these compounds are linked to the runoff of animal wastes into the river. Many of the organic compounds found in the Pocomoke River sediments have not yet been identified, but at least several are in the class of hormone compounds related to estradiols and have the potential to promote endocrine-disrupting effects in aquatic life. Particulate forms of arsenic and zinc are slightly elevated above normal levels for streams, but the sources for these elements are still undetermined. Several pesticides were found in low, parts-per-trillion concentrations, but were within the ranges commonly found in streams of this region.

Metagenomic exploration reveals a marked change in the river resistome and mobilome after treated wastewater discharges.

PubMed

Lekunberri, Itziar; Balcázar, José Luis; Borrego, Carles M

2018-03-01

Mobile genetic elements (MGEs) are key agents in the spread of antibiotic resistance genes (ARGs) across environments. Here we used metagenomics to compare the river resistome (collection of all ARGs) and mobilome (e.g., integrases, transposases, integron integrases and insertion sequence common region "ISCR" elements) between samples collected upstream (n = 6) and downstream (n = 6) of an urban wastewater treatment plant (UWWTP). In comparison to upstream metagenomes, downstream metagenomes showed a drastic increase in the abundance of ARGs, as well as markers of MGEs, particularly integron integrases and ISCR elements. These changes were accompanied by a concomitant prevalence of 16S rRNA gene signatures of bacteria affiliated to families encompassing well-known human and animal pathogens. Our results confirm that chronic discharges of treated wastewater severely impact the river resistome affecting not only the abundance and diversity of ARGs but also their potential spread by enriching the river mobilome in a wide variety of MGEs. Copyright © 2017 Elsevier Ltd. All rights reserved.

Trace element hydrochemistry indicating water contamination in and around the Yangbajing geothermal field, Tibet, China.

PubMed

Guo, Qinghai; Wang, Yanxin

2009-10-01

Thirty-eight water samples were collected at Yangbajing to investigate the water contamination resulting from natural geothermal water discharge and anthropogenic geothermal wastewater drainage. The results indicate that snow or snow melting waters, Yangbajing River waters and cold groundwaters are free from geothermal water-related contamination, whereas Zangbo river waters are contaminated by geothermal wastewaters. Moreover, there may exist geothermal springs under the riverbed of a tributary stream of Zangbo River as shown by its Cd, Li, Mo and Pb concentrations. The efforts made in this study show trace element hydrochemistry can well indicate water quality degradation related to geothermal water exploitation.

Effect of mining and related activities on the sediment trace element geochemistry of Lake Coeur D'Alene, Idaho, USA. Part I: Surface sediments

USGS Publications Warehouse

Horowitz, Arthur J.; Elrick, Kent A.; Cook, Robert B.

1993-01-01

During the summer of 1989 surface sediment samples were collected in Lake Coeur d'Alene, the Coeur d'Alene River and the St Joe River, Idaho, at a density of approximately one sample per square kilometre. Additional samples were collected from the banks of the South Fork of the Coeur d'Alene and the Coeur d'Alene Rivers in 1991. All the samples were collected to determine trace element concentrations, partitioning and distribution patterns, and to relate them to mining, mining related and discharge operations that have occurred in the Coeur d'Alene district since the 1880s, some of which are ongoing.Most of the surface sediments in Lake Coeur d'Alene north of Conkling Point and Carey Bay are substantially enriched in Ag, As, Cu, Cd, Hg, Pb, Sb and Zn relative to unaffected sediments in the southern portion of the lake near the St Joe River. All the trace element enriched sediments are extremely fine grained (mean grain sizes « 63 μm). Most of the enriched trace elements, based on both the chemical analyses of separated heavy and light mineral fractions and a two step sequential extraction procedure, are associated with an operationally defined Fe oxide phase; much smaller percentages are associated either with operationally defined organics/sulphides or refractory phases.The presence, concentration and distribution of the Fe oxides and heavy minerals indicates that a substantial portion of the enriched trace elements are probably coming from the Coeur d'Alene River, which is serving as a point source. Within the lake, this relatively simple point source pattern is complicated by a combination of (1) the formation of trace element rich authigenic Fe oxides that appear to have reprecipitated from material solubilized from anoxic bed sediments and (2) physical remobilization by currents and wind driven waves. The processes that have caused the trace element enrichment in the surface sediments of Lake Coeur d'Alene are likely to continue for the foreseeable future.

Using Elemental Abundances and Petrophysical Properties to Trace Sediment Transport in the Hudson River

NASA Astrophysics Data System (ADS)

Chang, C.; Kenna, T. C.; Nitsche, F. O.

2016-12-01

The IPCC predicts that the frequency and severity of storms worldwide will increase due to climate change, a growing concern for the highly populated coastal areas near the Hudson River estuary. Storms have the potential to change the river's sediment budget, and it is necessary to update the current understanding of the effect of storms on sediment dynamics. In 2011, Tropical Storm Lee and Hurricane Irene delivered over 2.7 million tons of sediment to the Hudson River including over 1.5 million tons from the Mohawk River, a freshwater tributary, in addition to record amounts contributed from other major tributaries. The goals of this project are to use sediment elemental compositions to trace the major tributaries contributing to this storm-deposited sediment and to determine where sediment is accumulating as a result of storm activity. Chemical analysis of over 800 archived sediment samples are compiled to provide a pre-storm background level. These samples are compared to newly deposited sediment and material from specific tributaries. Elemental abundances (K, Ca, Ti, Cr, Mn, Fe, Co, Cu, Zn, Rb, Sr, Zr, Pb, and U) are measured using a field portable X-Ray Fluorescence (XRF) unit and core scanning XRF unit. Bulk matrix density is measured using a pycnometer. The measurements are used to identify elemental signatures from tributary sediment and to trace the influence of specific tributaries on deposition through the river. Our results suggests measureable signatures in sediment from individual tributaries. The Mohawk River contributes high concentrations of Ca due to the calcite deposits in its watershed. XRF measurements also show the effect of human activity on sediment deposition; variations in Rb and Zr indicate changes in deposition due to dredging in Haverstraw Bay. The salt wedge front, where ocean and fresh water meets is evident in areas of below average matrix density. This project shows significant geochemical variability between sediment from different areas of the river, and indicates that XRF can be used to track sediment sources and deposition.

Characterizing suspended sediments from the Piracicaba River Basin by means of k0-INAA

NASA Astrophysics Data System (ADS)

França, E. J.; Fernandes, E. A. N.; Cavalca, I. P. O.; Fonseca, F. Y.; Camilli, L.; Rodrigues, V. S.; Bardini Junior, C.; Ferreira, J. R.; Bacchi, M. A.

2010-10-01

The inorganic chemical characterization of suspended sediments is of utmost relevance for the knowledge of the dynamics and movement of chemical elements in the aquatic and wet ecosystems. Despite the complexity of the effective design for studying this ecological compartment, this work has tested a procedure for analyzing suspended sediments by instrumental neutron activation analysis, k0 method ( k0-INAA). The chemical elements As, Ba, Br, Ca, Ce, Co, Cr, Cs, Eu, Fe, Hf, Hg, K, La, Mo, Na, Ni, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, Yb and Zn were quantified in the suspended sediment compartment by means of k0-INAA. When compared with World Average for rivers, high mass fractions of Fe (222,900 mg/kg), Ba (4990 mg/kg), Zn (1350 mg/kg), Cr (646 mg/kg), Co (74.5 mg/kg), Br (113 mg/kg) and Mo (31.9 mg/kg) were quantified in suspended sediments from the Piracicaba River, the Piracicamirim Stream and the Marins Stream. Results of the principal component analysis for standardized chemical element mass fractions indicated an intricate correlation among chemical elements evaluated, as a response of the contribution of natural and anthropogenic sources of chemical elements for ecosystems.

Trace elements in fish from the Arabian Gulf and the Shatt al-Arab river, Iraq

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abaychi, J.; Al-Saad, H.T.

1988-02-01

In the Arabian Gulf region, recently, vast industrial, agricultural, economic and social developments have taken place, in addition to an increase in population. This may enhance the magnitude of environmental pollution year by year. No detailed study has been undertaken to assess the concentrations of trace elements in commercial species of fish from the Arabian Gulf and the Shatt al-Arab River, despite the fact that fish are considered an essential part of the diet in the region. Therefore, an investigation was carried out on the concentration of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn in themore » following fish species from the Arabian Gulf: Tylosurus strongylurus, Eleutheoronema tetradactum, Pomadasys arel, Platycephalus indicus, Ilisha elongata, Thryssa hamiltonii, Arius thalassinus, Acanthophagrus luteus, Johnieops sina, Liza dussumeiri, Hilsa ilisha, Nematolosa nasus and Otoliths argenteus, and on species from the Shatt al-Arab River: Mesopotamichthys sharpeyi, Barbus xanthopterus, Barbus scheich, Aspius vorax, Cyprinus carpio, and Barbus grypus. Trace element levels in sediment samples from the area were also determined since sediments can accumulate different elements and may reflect the extent of pollution by these elements.« less

Characterization of particulate and dissolved phosphorus in tile and nearby riverine systems

NASA Astrophysics Data System (ADS)

Jiang, X.; Arai, Y.; David, M.; Gentry, L.

2017-12-01

In the Midwestern U.S., the drainage of agricultural land is predominantly managed by the tile drain system because of its poorly drain properties of clay rich indigenous soils. An accelerated subsurface flow of phosphorus (P) has recently been documented as a primary P transport path in contrast to the typical surface runoff events observed in the Eastern U.S. Recent studies suggested the important role of particulate P (PP) load in agricultural tile drainage water during high flow events. It was hypothesized that PP in the tile water is transported to riverine system contributing to the negative environmental impacts in the Midwestern U.S. In this study, correlation assessment of physicochemical properties of PP in agricultural tile drainage and nearby river samples after a storm event was conducted using a combination of 31P-nuclear magnetic resonance spectroscopy, P K-edge X-ray absorption near edge structure spectroscopy, X-ray diffraction, zetasizer, and transmission electron microscopy. Results show that significantly more colloidal (i.e. 1 nm- 2 µm) and silt-sized (i.e. > 2 µm) particles as well as higher dissolved total P (DTP) and dissolved reactive P (DRP) concentrations existed in river samples than tile samples. Tile and river samples showed similar zeta potential in each particle-size fraction and similar element distributions on colloidal fraction. However, colloidal P concentration and distribution are slightly different between tile and river samples: more colloidal total P and organic P existed in tile colloids than river colloids. The results of P speciation and mineralogical assessment will also be discussed.

Nutrient Dynamics of Estuarine Invertebrates Are Shaped by Feeding Guild Rather than Seasonal River Flow

PubMed Central

Ortega-Cisneros, Kelly; Scharler, Ursula M.

2015-01-01

This study aimed to determine the variability of carbon and nitrogen elemental content, stoichiometry and diet proportions of invertebrates in two sub-tropical estuaries in South Africa experiencing seasonal changes in rainfall and river inflow. The elemental ratios and stable isotopes of abiotic sources, zooplankton and macrozoobenthos taxa were analyzed over a dry/wet seasonal cycle. Nutrient content (C, N) and stoichiometry of suspended particulate matter exhibited significant spatio-temporal variations in both estuaries, which were explained by the variability in river inflow. Sediment particulate matter (%C, %N and C:N) was also influenced by the variability in river flow but to a lesser extent. The nutrient content and ratios of the analyzed invertebrates did not significantly vary among seasons with the exception of the copepod Pseudodiaptomus spp. (C:N) and the tanaid Apseudes digitalis (%N, C:N). These changes did not track the seasonal variations of the suspended or sediment particulate matter. Our results suggest that invertebrates managed to maintain their stoichiometry independent of the seasonality in river flow. A significant variability in nitrogen content among estuarine invertebrates was recorded, with highest % N recorded from predators and lowest %N from detritivores. Due to the otherwise general lack of seasonal differences in elemental content and stoichiometry, feeding guild was a major factor shaping the nutrient dynamics of the estuarine invertebrates. The nutrient richer suspended particulate matter was the preferred food source over sediment particulate matter for most invertebrate consumers in many, but not all seasons. The most distinct preference for suspended POM as a food source was apparent from the temporarily open/closed system after the estuary had breached, highlighting the importance of river flow as a driver of invertebrate nutrient dynamics under extreme events conditions. Moreover, our data showed that estuarine invertebrates concentrated C and N between 10–100 fold from trophic level I (POM) to trophic level II (detritivores/deposit feeders) and thus highlighted their importance not only as links to higher trophic level organisms in the food web, but also as providers of a stoichiometrically homeostatic food source for such consumers. As climate change scenarios for the east coast of South Africa predict increased rainfall as a higher number of rainy days and days with higher rainfall, our results suggest that future changes in rainfall and river inflow will have measurable effects on the nutrient content and stoichiometry of food sources and possibly also in estuarine consumers. PMID:26352433

Nutrient Dynamics of Estuarine Invertebrates Are Shaped by Feeding Guild Rather than Seasonal River Flow.

PubMed

Ortega-Cisneros, Kelly; Scharler, Ursula M

2015-01-01

This study aimed to determine the variability of carbon and nitrogen elemental content, stoichiometry and diet proportions of invertebrates in two sub-tropical estuaries in South Africa experiencing seasonal changes in rainfall and river inflow. The elemental ratios and stable isotopes of abiotic sources, zooplankton and macrozoobenthos taxa were analyzed over a dry/wet seasonal cycle. Nutrient content (C, N) and stoichiometry of suspended particulate matter exhibited significant spatio-temporal variations in both estuaries, which were explained by the variability in river inflow. Sediment particulate matter (%C, %N and C:N) was also influenced by the variability in river flow but to a lesser extent. The nutrient content and ratios of the analyzed invertebrates did not significantly vary among seasons with the exception of the copepod Pseudodiaptomus spp. (C:N) and the tanaid Apseudes digitalis (%N, C:N). These changes did not track the seasonal variations of the suspended or sediment particulate matter. Our results suggest that invertebrates managed to maintain their stoichiometry independent of the seasonality in river flow. A significant variability in nitrogen content among estuarine invertebrates was recorded, with highest % N recorded from predators and lowest %N from detritivores. Due to the otherwise general lack of seasonal differences in elemental content and stoichiometry, feeding guild was a major factor shaping the nutrient dynamics of the estuarine invertebrates. The nutrient richer suspended particulate matter was the preferred food source over sediment particulate matter for most invertebrate consumers in many, but not all seasons. The most distinct preference for suspended POM as a food source was apparent from the temporarily open/closed system after the estuary had breached, highlighting the importance of river flow as a driver of invertebrate nutrient dynamics under extreme events conditions. Moreover, our data showed that estuarine invertebrates concentrated C and N between 10-100 fold from trophic level I (POM) to trophic level II (detritivores/deposit feeders) and thus highlighted their importance not only as links to higher trophic level organisms in the food web, but also as providers of a stoichiometrically homeostatic food source for such consumers. As climate change scenarios for the east coast of South Africa predict increased rainfall as a higher number of rainy days and days with higher rainfall, our results suggest that future changes in rainfall and river inflow will have measurable effects on the nutrient content and stoichiometry of food sources and possibly also in estuarine consumers.

Evaluation of an operational water cycle prediction system for the Laurentian Great Lakes and St. Lawrence River

NASA Astrophysics Data System (ADS)

Fortin, Vincent; Durnford, Dorothy; Smith, Gregory; Dyck, Sarah; Martinez, Yosvany; Mackay, Murray; Winter, Barbara

2017-04-01

Environment and Climate Change Canada (ECCC) is implementing new numerical guidance products based on fully coupled numerical models to better inform the public as well as specialized users on the current and future state of various components of the water cycle, including stream flow and water levels. Outputs from this new system, named the Water Cycle Prediction System (WCPS), have been available for the Great Lakes and St. Lawrence River watershed since June 2016. WCPS links together ECCC's weather forecasting model, GEM, the 2-D ice model C-ICE, the 3-D lake and ocean model NEMO, and a 2-D hydrological model, WATROUTE. Information concerning the water cycle is passed between the models at intervals varying from a few minutes to one hour. It currently produces two forecasts per day for the next three days of the complete water cycle in the Great Lakes region, the largest freshwater lake system in the world. Products include spatially-varying precipitation, evaporation, river discharge, water level anomalies, surface water temperatures, ice coverage, and surface currents. These new products are of interest to water resources and management authority, flood forecasters, hydroelectricity producers, navigation, environmental disaster managers, search and rescue teams, agriculture, and the general public. This presentation focuses on the evaluation of various elements forecasted by the system, and weighs the advantages and disadvantages of running the system fully coupled.

Geochemical Dataset of the Rhone River Delta (Lake Geneva) Sediments - Disentangling Human Impacts from Climate Change

NASA Astrophysics Data System (ADS)

Silva, T. A.; Girardclos, S.; Loizeau, J. L.

2016-12-01

Lake sediment records are often the most complete continental archives. In the last 200 years, in addition to climatic variability, humans have strongly impacted lake watersheds around the world. During the 20th century the Rhone River and its watershed upstream Lake Geneva (Switzerland/France) have been subject to river channelization, dam construction, water flow regulation, water and sediment abstraction as well as various land use changes. Under the scope of the SEDFATE project (Swiss National Science Foundation nº147689) we address human and climatic impact on the sediment transfer from the Rhone River watershed to Lake Geneva. Nineteen short sediment cores were collected in the Rhone River delta area in May 2014. Cores have been scanned with MSCL and XRF, sub-sampled every 1cm and 8 cores were dated by radiometric methods (137Cs and 210Pb). Photographs taken right after core opening were used for lithological description and in addition to MSCL data were used to correlate cores. Core dating shows that mass accumulation rates decreased in the 1964-1986 interval and then increased again in the interval between 1986-2014. XRF elements and ratios, known to indicate detrital sources (Al, Al/Si, Fe, K, Mn, Rb, Si, Ti, Ti/Ca), show that clastic input diminished from 1964 to 1986 and re-increased to the present. Other elemental (Zr/Rb, Zr/K, Si/Ti) and geophysical data (magnetic susceptibility) combined with lithology identify density flow deposits vs hemipelagic sedimentation. Changes in frequency of these event deposits indicate changes in the sedimentation patterns in the Rhone River sublacustrine delta during the last century. From these results we hypothesize that a significant sediment amount was abstracted from the system after the major dam constructions in the 1950's and that, since the 1990's, a contrary signal is due to increased sediment loads that follows glacial melting due to global warming.

Hydrologic connectivity and the contribution of stream headwaters to ecological integrity at regional scales

USGS Publications Warehouse

Freeman, Mary C.; Pringle, C.M.; Jackson, C.R.

2007-01-01

Cumulatively, headwater streams contribute to maintaining hydrologic connectivity and ecosystem integrity at regional scales. Hydrologic connectivity is the water-mediated transport of matter, energy and organisms within or between elements of the hydrologic cycle. Headwater streams compose over two-thirds of total stream length in a typical river drainage and directly connect the upland and riparian landscape to the rest of the stream ecosystem. Altering headwater streams, e.g., by channelization, diversion through pipes, impoundment and burial, modifies fluxes between uplands and downstream river segments and eliminates distinctive habitats. The large-scale ecological effects of altering headwaters are amplified by land uses that alter runoff and nutrient loads to streams, and by widespread dam construction on larger rivers (which frequently leaves free-flowing upstream portions of river systems essential to sustaining aquatic biodiversity). We discuss three examples of large-scale consequences of cumulative headwater alteration. Downstream eutrophication and coastal hypoxia result, in part, from agricultural practices that alter headwaters and wetlands while increasing nutrient runoff. Extensive headwater alteration is also expected to lower secondary productivity of river systems by reducing stream-system length and trophic subsidies to downstream river segments, affecting aquatic communities and terrestrial wildlife that utilize aquatic resources. Reduced viability of freshwater biota may occur with cumulative headwater alteration, including for species that occupy a range of stream sizes but for which headwater streams diversify the network of interconnected populations or enhance survival for particular life stages. Developing a more predictive understanding of ecological patterns that may emerge on regional scales as a result of headwater alterations will require studies focused on components and pathways that connect headwaters to river, coastal and terrestrial ecosystems. Linkages between headwaters and downstream ecosystems cannot be discounted when addressing large-scale issues such as hypoxia in the Gulf of Mexico and global losses of biodiversity.

Carbon and nitrogen isotopic compositions of particulate organic matter in four large river systems across the United States

USGS Publications Warehouse

Kendall, C.; Silva, S.R.; Kelly, V.J.

2001-01-01

Riverine particulate organic matter (POM) samples were collected bi-weekly to monthly from 40 sites in the Mississippi, Colorado, Rio Grande, and Columbia River Basins (USA) in 1996-97 and analysed for carbon and nitrogen stable isotopic compositions. These isotopic compositions and C : N ratios were used to identify four endmember sources of POM: Plankton, fresh terrestrial plant material, aquatic plants, and soil organic material. This large-scale study also incorporated ancillary chemical and hydrologic data to refine and extend the interpretations of POM sources beyond the source characterizations that could be done solely with isotopic and elemental ratios. The ancillary data were especially useful for differentiating between seasonal changes in POM source materials and the effects of local nutrient sources and in-stream biogeochemical processes. Average values of ??13 C and C : N for all four river systems suggested that plankton is the dominant source of POM in these rivers, with higher percentages of plankton downstream of reservoirs. Although the temporal patterns in some rivers are complex, the low ??13C and C : N values in spring and summer probably indicate plankton blooms, whereas relatively elevated values in fall and winter are consistent with greater proportions of decaying aquatic vegetation and/or terrestrial material. Seasonal shifts in the ??13C of POM when the C : N remains relatively constant probably indicate changes in the relative rates of photosynthesis and respiration. Periodic inputs of plant detritus are suggested by C : N ratios >15, principally on the Columbia and Ohio Rivers. The ??15N and ??13C also reflect the importance of internal and external sources of dissolved carbon and nitrogen, and the degree of in-stream processing. Elevated ??15N values at some sites probably reflect inputs from sewage and/or animal waste. This information on the spatial and temporal variation in sources of POM in four major river systems should prove useful in future food web and nutrient transport studies.

Monitoring heavy metal concentrations in the sediments of the Moskva and Oka River system- Results of the Volga-Rhine-Project

NASA Astrophysics Data System (ADS)

Andresen, Höpke

2010-05-01

In the course of the Volga-Rhine-Project sediment, water and pore water samples were collected on the Volga as well as the Moskva and Oka river systems. The sampling area discussed here is located south east of the city of Moscow. Sediment samples were taken along the Moskva River between Moscow and the city of Kolomna, which is approximately 100 km to the southeast of Moscow and in the Oka River close to the confluence with the Moskva River (Kolomna). The first sampling campaign in this region took place in 1993, followed by further sampling in 1997 and 2007. For evaluation of sediment quality classification systems are often used. The geo-accumulation index proposed by Mueller (1979) is a classification system which consists of seven classes given by the following expression: I = log2×Cn- geo 1.5×Bn Where Cn = measured concentration; Bn = background value (Turekian & Wedepol 1961) of element n and 1.5 = background matrix correction factor. The geo-accumulation index consists of seven grades (0-6) which indicate the enrichment of an element compared to the background value. These grades range from 'not polluted' to 'very strongly polluted'. Another possibility to express sediment contamination is to evaluate the effects on the ecosystem. The lowest effect level (LEL) gives the concentrations of the heavy metals in sediment below which no effect on the majority of the sediment dwelling organisms is expected. The probable effect level (PEL) represents the concentration of heavy metals above which the organisms frequently will show adverse effects. Both of these approaches were used to evaluate the results of the Volga-Rhine-Project. In the last two decades the concentrations of heavy metals in the sediments decreased by up to 60%. In 1993 sediments revealed high concentrations of several heavy metals such as chromium, cadmium, lead, zinc, arsenic, nickel and cobalt, whereas in 2007 only two sediment samples were classified as 'very strongly polluted' regarding lead and cadmium concentrations. Additionally six other sediment samples were found to be 'strongly polluted' with cadmium, zinc and lead, respectively. Using the ecotoxicological approach on the sediments, chromium, cadmium and zinc are above the PEL, whereas the content of lead exceeds the LEL. Thus, these metals may still cause toxic effects on the fresh water system. Although the input of heavy metals into the river systems has clearly decreased during the last 20 years, there are still some locations where high concentrations of heavy metals are found, suggesting point sources. Especially cadmium still shows significantly higher concentrations than the background value in the entire sampling area. There are even two sampling points where the cadmium concentrations reach approximately 100x the background value. To determine the temporal variation of the heavy metal input, sediment cores were taken. Heavy metal concentrations increase with depth in the cores and show a maximum at a depth of about 35-40 cm. Some part of this increase may be a result of early diagenesis as well as a result of reduced heavy metal input. The nature of the decline of the heavy metal concentrations is still in progress. Despite all the improvements achieved in environmental protection in Russia, still some problems have to be addressed. Especially in urban areas like the Moscow region the number and the size of illegal dump sites is increasing dramatically, leading to strong inputs of heavy metals and other pollutants into the river systems, with consequences for the sensitive eco systems.

Design principles of water sensitive in settlement area on the river banks

NASA Astrophysics Data System (ADS)

Ryanti, E.; Hasriyanti, N.; Utami, W. D.

2018-03-01

This research will formulate the principle of designing settlement area of Kapuas River Pontianak with the approach of water sensitive concept of urban design (WSUD) the densely populated settlement area. By using a case study the approach that is a dense settlement area located on the banks of the river with literature study techniques to formulate the aspects considered and components that are set in the design, descriptive analysis with the rationalistic paradigm for identification characteristics of the settlement in the river banks areas with consideration of WSUD elements and formulate the principles of designing water-sensitive settlement areas. This research is important to do because the problems related to the water management system in the existing riverside settlement in Pontianak has not been maximal to do. So the primary of this research contains several objectives that will be achieved that is identifying the characteristics of riverside settlement area based on consideration of design aspects of the area that are sensitive to water and the principle of designing the area so that the existing problem structure will be formulated in relation to the community’s need for infrastructure in settlement environment and formulate and develop appropriate technology guidelines for integrated water management systems in riverside settlement areas and design techniques for water-sensitive settlements (WSUD).

Reconnaissance of chemical and biological quality in the Owyhee River from the Oregon State line to the Owyhee Reservoir, Oregon, 2001–02

USGS Publications Warehouse

Hardy, Mark A.; Maret, Terry R.; George, David L.

2004-01-01

The Owyhee River drains an extremely rugged and sparsely populated landscape in northern Nevada, southwestern Idaho, and eastern Oregon. Most of the segment between the Oregon State line and Lake Owyhee is part of the National Wild and Scenic Rivers System, and few water-quality data exist for evaluating environmental impacts. As a result, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, assessed this river segment to characterize chemical and biological quality of the river, identify where designated beneficial uses are met and where changes in stream quality occur, and provide data needed to address activities related to environmental impact assessments and Total Maximum Daily Loads. Water-quality issues identified at one or more sites were water temperature, suspended sediment, dissolved oxygen, pH, nutrients, trace elements, fecal bacteria, benthic invertebrate communities, and periphyton communities. Generally, summer water temperatures routinely exceeded Oregon's maximum 7-day average criteria of 17.8 degrees Celsius. The presence of few coldwater taxa in benthic invertebrate communities supports this observation. Suspended-sediment concentrations during summer base flow were less than 10 milligrams per liter (mg/L). Dissolved solids concentrations ranged from 46 to 222 mg/L, were highest during base flow, and tended to increase in a downstream direction. Chemical compositions of water samples indicated that large proportions of upland-derived water extend to the lower reaches of the study area during spring runoff. Dissolved fluoride and arsenic concentrations were highest during base flow and may be a result of geothermal springs discharging to the river. No dissolved selenium was detected. Upstream from the Rome area, spring runoff concentrations of suspended sediment ranged from 0 to 52 mg/L, and all except at the Three Forks site were typically below 20 mg/L. Stream-bottom materials from the North Fork Owyhee River, an area with no mines, were enriched with nine trace elements, which indicates that this basin may be a natural source of these elements. Near Rome, the part of the study area not included in the National Wild and Scenic Rivers System, land-use impacts resulted in elevated populations of Escherichia coli bacteria (E. coli) during base flow and elevated concentrations of nitrogen and phosphorus during spring runoff. Sites in this area had the highest numbers of benthic invertebrates; the fewest Ephemeroptera, Plecoptera, and Trichoptera taxa; and the highest Hilsenhoff Biotic Index scores. These results suggest degraded stream quality. Periphyton communities at sites in this area approached nuisance levels and could cause significant dissolved oxygen depletions and pH values that exceed Oregon's recommended criteria. Stream-bottom materials from Jordan Creek were enriched with mercury and manganese, which probably were ultimately caused by past mining in that basin. Below Crooked Creek, elevated suspended sediment concentrations (142 mg/L), phosphorus concentrations (0.23 mg/L), and E. coli populations (370 most probable number per 100 milliliters) during the largest spring runoff event could be the result of inputs at the lower end of Jordan Valley and (or) inputs from Crooked Creek. The New Zealand Mud Snail, a highly competitive gastropod introduced to the Snake River in the 1980s, was collected just downstream from the Crooked Creek confluence.

Elemental mercury in the atmosphere of a tropical Amazonian forest (French Guiana)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amouroux, D.; Wasserman, J.C.Tessier, E.; Donard, O.F.X.

1999-09-01

Gaseous atmospheric mercury was investigated at two sites of a tropical Amazonian forest (French Guiana) in the Petit Inini River basin and the Petit Saut Lake in June, 1998. Gaseous atmospheric mercury was identified as elemental mercury (Hg{sup 0}). Diurnal variation of atmospheric Hg{sup 0} in both studied aquatic environments were significantly correlated with air temperature and anticorrelated with relative humidity. Average Hg{sup 0} concentrations were higher above the Petit Inini River that the Petit Saut Lake. Background Hg{sup 0} concentrations in the Petit Inini River basin were higher than those observed in remote environments. These data suggest that goldmore » mining activity (i.e., Petit Inini River basin) may influence mercury mobilization in tropical forest ecosystems and that atmospheric transfer is a major pathway for mercury cycling in these environments.« less

Colloids in the River Inn

NASA Astrophysics Data System (ADS)

Ueckert, Martina; Baumann, Thomas

2014-05-01

In the light of an increasing number of technical applications using nanoparticles and reports of adverse effects of engineered nanoparticles, research on the occurrence and stability of particles in all compartments has to be intensified. Colloids in river water represent the geologic setting, environmental conditions, and the anthropogenic use in its catchment. The river not only acts as a sink for nanoparticles but also as the source term due to exchange in the hyporheic zone and in bank filtration setups. The concentration, size distribution and elemental composition of particles in the River Inn were studied from the source in the Swiss Alps to the river mouth at Passau. Samples were collected after each tributary from a sub-catchment and filtered on-site. The elemental composition was determined after acid digestion with ICP/MS. SEM/EDX analyses provided morphological and elemental information for single particles. A complementary chemical analysis of the river water was performed to assess the geochemical stability of indvidual particles. Particles in the upper, rural parts mainly reveal changes in the geological setting of the tributary catchments. Not unexpectedly, particles originating from crystalline rocks, were more stable than particles originating from calcareous rocks. Anthropogenic and industrial influences increase in the lower parts. This went together with a change of the size distribution, an increase of the number of organic particles, and a decrease of the microfauna. Interestingly, specific leisure activities in a sub-catchment, like extensive downhill skiing, manifest itself in the particle composition.

Metal concentrations in surface water and sediments from Pardo River, Brazil: human health risks.

PubMed

Alves, Renato I S; Sampaio, Carolina F; Nadal, Martí; Schuhmacher, Marta; Domingo, José L; Segura-Muñoz, Susana I

2014-08-01

Pardo River (Brazil) is suffering from an important anthropogenic impact due to the pressure of highly populated areas and the influence of sugarcane cultivation. The objective of the present study was to determine the levels of 13 trace elements (As, Be, Cd, Cr, Cu, Pb, Mn, Hg, Ni, Tl, Sn, V and Zn) in samples of surface water and sediments from the Pardo River. Furthermore, the human health risks associated with exposure to those metals through oral intake and dermal absorption were also evaluated. Spatial and seasonal trends of the data were closely analyzed from a probabilistic approach. Manganese showed the highest mean concentrations in both water and sediments, remarking the incidence of the agricultural activity and the geological characteristics within the basin. Thallium and arsenic were identified as two priority pollutants, being the most important contributors to the Hazard Index (HI). Since non-carcinogenic risks due to thallium exposure slightly exceeded international guidelines (HI>1), a special effort should be made on this trace element. However, the current concentrations of arsenic, a carcinogenic element, were in accordance to acceptable lifetime risks. Nowadays, there is a clear increasing growth in human population and economic activities in the Pardo River, whose waters have become a serious strategic alternative for the potential supply of drinking water. Therefore, environmental monitoring studies are required not only to assure that the current state of pollution of Pardo River does not mean a risk for the riverside population, but also to assess the potential trends in the environmental levels of those elements. Copyright © 2014 Elsevier Inc. All rights reserved.

Organochlorine compounds and trace elements in fish tissue and streambed sediment in the Mobile River Basin, Alabama, Mississippi, and Georgia, 1998

USGS Publications Warehouse

Zappia, Humbert

2002-01-01

During the summer of 1998, as part of the National Water-Quality Assessment Program, a survey was conducted to determine which organochlorine compounds and trace elements occur in fish tissues and streambed sediments in the Mobile River Basin, which includes parts of Alabama, Mississippi, Georgia, and Tennessee. The data collected were compared to guidelines related to wildlife, land use, and to 1991 and 1994 National Water-Quality Assessment Program Study-Unit data.Twenty-one sites were sampled in subbasins of the Mobile River Basin. The subbasins ranged in size from about 9 to 22,000 square miles and were dominated by either a single land use or a combination of land uses. The major land-use categories were urban, agriculture, and forest.Organochlorine compounds were widespread spatially in the Mobile River Basin. At least one organochlorine compound was reported at the majority of sampling sites (84 percent) and in a majority of whole-fish (80 percent) and streambed-sediment (52 percent) samples. Multiple organochlorine compounds were reported at 75 percent of the sites where fish tissues were collected and were reported at many of the streambed-sediment sampling sites (45 percent). The majority of concentrations reported, however, were less than 5 micrograms per kilogram in fish-tissue samples and less than 1 microgram per kilogram in streambed-sediment samples.The majority of trace elements analyzed in fish-liver tissue (86 percent) and streambed-sediment (98 percent) samples were reported during this study. Multiple trace elements were reported in all samples and at all sites.Based on comparisons of concentrations of organochlorine compounds and trace elements in fish-tissue and streambed-sediment samples in relation to National Academy of Science and National Academy of Engineering and Canadian tissue guidelines, probable-effects concentrations, and mean probable-effects concentration quotients for streambed sediment, the potential exists for adverse effects to wildlife at 15 (72 percent) of the sites sampled. The potential for adverse effects at these sites is because of the presence of residues or breakdown products related to polychlorinated biphenyls (PCB?s), chlordane, dichlorodiphenyltrichloroethane (DDT), chromium, lead, and zinc.The majority of compounds reported (65 percent) were chlordane, DDT, and PCB?s, or their breakdown products. Concentrations of chlordane and heptachlor epoxide in whole-fish tissue were positively correlated to the amount of urban land use in a basin. Total DDT concentrations in whole-fish tissues were positively correlated to agriculture.The relation of trace elements to land use is not as clear as the relation of organochlorine compounds to land use. This lack of clarity may be due to the possibility of geologic sources of trace elements in the Mobile River Basin and to the ubiquitous nature of many of these trace elements. However, there may be a correlation between the amount of urban land use and concentrations of antimony, cadmium, lead, and zinc in streambed-sediment samples from the Mobile River Basin.Fewer organochlorine compounds and trace elements were reported in samples from the Mobile River Basin than in samples collected during the 1991 and 1994 National Water-Quality Assessment Program studies. Of the organochlorine compounds analyzed nationally, 57 percent were reported in whole-fish tissue samples collected locally and 41 percent were reported in streambed-sediment samples collected locally, whereas 96 percent and 86 percent, respectively, were reported nationally. Of trace elements analyzed nationally, 86 percent were reported in fish-liver tissue locally and 95 percent were reported in streambed-sediment samples locally, whereas 95 percent and 98 percent, respectively, were reported nationally.In general, concentrations of organochlorine compounds and trace elements and the frequency with which they were reported in the Mobile River Basin are similar to or less than t

Summary of information on synthetic organic compounds and trace elements in tissue of aquatic biota, Clark Fork-Pend Oreille and Spokane River basins, Montana, Idaho, and Washington, 1974-96

USGS Publications Warehouse

Maret, Terry R.; Dutton, DeAnn M.

1999-01-01

As part of the Northern Rockies Intermontane Basins study of the National Water-Quality Assessment Program, data collected between 1974 and 1996 were compiled to describe contaminants in tissue of riverine species. Tissue-contaminant data from 11 monitoring programs and studies representing 28 sites in the study area were summarized. Tissue-contaminant data for most streams generally were lacking. Many studies have focused on and around mining-affected areas on the Clark Fork and Coeur d'Alene Rivers and their major tributaries. DDT and PCBs and their metabolites and congeners were the synthetic organic contaminants most commonly detected in fish tissue. Fish collected from the Spokane River in Washington contained elevated concentrations of PCB arochlors, some of which exceeded guidelines for the protection of human health and predatory wildlife. Tissue samples of fish from the Flathead River watershed contained higher-than-expected concentrations of PCBs, which might have resulted from atmospheric transport. Trace element concentrations in fish and macroinvertebrates collected in and around mining areas were elevated compared with background concentrations. Some cadmium, copper, lead, and mercury concentrations in fish tissue were elevated compared with results from other studies, and some exceeded guidelines. Macroinvertebrates from the Coeur d'Alene River contained higher concentrations of cadmium, lead, and zinc than did macroinvertebrates from other river systems in mining-affected areas. A few sportfish fillet samples, most from the Spokane River in Washington, were collected to assess human health risk. Concentrations of PCBs in these fillets exceeded screening values for the protection of human health. At present, there is no coordinated, long-term fish tissue monitoring program for rivers in the study area, even though contaminants are present in fish at levels considered a threat to human health. Development of a coordinated, centralized national data base for contaminants in fish tissue is needed. The National Water-Quality Assessment Program can provide a framework for other agencies to evaluate tissue contaminants in the Northern Rockies Intermontane Basins study area. As of 1996, there are no fish consumption advisories or fishing restrictions as a result of elevated contaminants on any rivers within the study area.

A multidisciplinary approach to reveal floodplain palaeohydrography in the surrounding of ancient Luna archaeological site (lower Magra River valley, NW Italy)

NASA Astrophysics Data System (ADS)

Bini, Monica; Bisson, Marina; Chelli, Alessandro; Pappalardo, Marta

2010-05-01

The Magra floodplain (NW Italy) is a coastal plain that was created during the last 2.5 millennia by the River Magra itself and by minor streams draining the southern slope of the Apuan Alps. The coastline progressively migrated from the mountain foothills to its present position, 2.5 km seaward. Available stratigraphical data suggest that the marine gulf that occupied the area before Bronze age gradually changed into a lagoon; this was finally separated from the open sea and became a complex of marshes that were finally silted up. All these environments provided opportunities for settlement and land use: early settlement is accounted for in the Iron Age by Ligurian people that were finally defeated by the Romans. In the 2nd century bC the roman colony of Luna (today Luni) was founded in the area. After the Imperial Age Luni gradually decayed and was finally abandoned in 1204. Post-Roman alluviation is thought to be partly responsible for the city decline and the survival of only scattered farmsteads in its surroundings. Settlement and land use history from Iron Age onward are thus tightly dependant from drainage network evolution in the area. Although historical maps provide some chronological constraints about the advance of the Magra floodplain it is still unknown how and when precisely the transformation of a lagoon environment into a dry land occurred. In particular no data are available about the position of the mouths of the Magra River and of the minor streams at Roman Times and little is known about channel migration since the Early Middle Ages and information about land reclamation are difficult to find because dispersed. In order to identify abandoned fluvial channels, a series of digital elaborations were applied to different types of Remotely-Sensed Images. In detail, the used data consist of satellite images (Landsat 7 - ETM) and airborne orthophotos (AIMA) covering a temporal interval of five years (from 1998 to 2002) and characterized by a spatial resolution of 30 and 1 m, respectively. The elaboration techniques chosen for our investigation include the classic visualisation in gray level mode, colour composition of different bands (natural and false), contrast enhancement, density slicing and filtering. These procedures allowed to improve the visual discrimination of buried fluvial features basing on the assumption that palaeo-river elements show unique characteristics in their spectral responses represented by image elements as tone/colour, brightness, shadow, shape, pattern and size. Using satellite images, the best results are obtained working with the infrared channels that are very sensitive to moisture content and with the panchromatic channel where the better spatial resolution (15 meters) combined to its spectral characteristics (visible and near infrared) enhances the detection of fluvial elements with sizes in width mayor than 15 meter. In this way it was possible recognize a palaeo-channel system of primary rank. Using orthophotos, signs of palaeo-river courses were recognized in natural or man-made features (e.g. forested areas or roads) characterized by a marked meandering pattern, in the presence of unjustified directional changes of cultivated terrains and, finally, in contiguous and narrow shadows that result well visible in the gray-tones images. Besides, the higher spatial resolution of these images (1 m) permitted to distinguish in detail palaeo-fluvial features that can represent a palaeo-drainage system of secondary rank. All detected elements were mapped and organized in a Geographic Information System (GIS). The consistence of highlighted features with plaeo-river channels was validated by means of historical maps and available stratigraphical and geophysical data. Our research provided valuable information useful to investigate the relationship between river channel migration and human settlement through time in the study area.

Isotopic tracing of the dissolved U fluxes of Himalayan rivers: implications for present and past U budgets of the Ganges-Brahmaputra system

NASA Astrophysics Data System (ADS)

Chabaux, François; Riotte, Jean; Clauer, Norbert; France-Lanord, Christian

2001-10-01

U activity ratios have been measured in the dissolved loads of selected rivers from the Himalayan range, in Central Nepal, and from the Bangladesh, as well as in some rain waters. A few European and Asian rivers have also been analyzed for their U activity ratios. The data confirm the negligible effect of rainwater on the budget of dissolved U in river waters. The results also indicate that rivers on each Himalayan structural unit have homogeneous and specific U isotope compositions: i) (234U/238U) activity ratios slightly lower than unity in the dissolved load of the streams draining the Tethyan Sedimentary Series (TSS); ii) values slightly higher than unity for waters from the High Himalaya Crystalline (HHC) and the Lesser Himalaya (LH); iii) systematically higher (234U/238U) activity ratios for waters from the Siwaliks. Thus, U activity ratios, in association with Sr isotopic ratios, can be used to trace the sources of dissolved fluxes carried by these rivers. Coupling of U with Sr isotope data shows (1) that the U carried by the dissolved load of the Himalayan rivers mainly originates from U-rich lithologies of the TSS in the northern formations of the Tibetan plateau; and (2) that the elemental U and Sr fluxes carried by the Himalayan rivers at the outflow of the highlands are fairly homogeneous at the scale of the Himalayan chain. Rivers flowing on the Indian plain define a different trend from that of the Himalayan rivers in the U-Sr isotopic diagram, indicating the contribution of a specific floodplain component to the U and Sr budgets of the Ganges and the Brahmaputra. The influence of this component remains limited to 10 to 15 percent for the U flux, but can contribute 35 to 55% of the Sr flux. The variations of the Sr and U fluxes of the Ganges-Brahmaputra river system in response to climatic variations have been estimated by assuming a temporary cut off of the chemical fluxes from high-altitude terrains during glacial episodes. This scenario would significantly decrease the dissolved U flux of the Ganges-Brahmaputra river system and increase its U activity ratio. Such a climatic dependence of the Himalayan U flux could induce a periodic variation of the mean U activity ratio of the world rivers on glacial-interglacial timescales

Assessment of the behavior of potentially toxic elements (PTEs) in soil from the Sarno River Basin through a compositional data analysis

NASA Astrophysics Data System (ADS)

Matar, Thiombane; Vivo Benedetto, De; Albanese, Stefano; Martín-Fernández, Josep-Antoni; Lima, Annamaria; Doherty, Angela

2017-04-01

The Sarno River Basin (south-west Italy), nestled between the Somma-Vesuvius volcanic complex and the limestone formations of the Campania-Apennine Chain, is one of the most polluted river basins in Europe due to a high rate of industrialization and intensive agriculture. Water from the Sarno River, which is heavily contaminated by the discharge of human and industrial waste, is partially used for irrigation on the agricultural fields surrounding it. We apply compositional data analysis on 319 samples collected during two field campaigns along the river course, and throughout the basin, to determine the level and potential origin (anthropogenic and/or geogenic) of the potentially toxic elements (PTEs). The concentrations of 53 elements determined by ICP-MS, and were subsequently log-transformed. Using a clr-biplot and principal factor analysis, the variability and the correlations between a subset of extracted variables (26 elements) were identified. Using both normalized raw data and clr-transformed coordinates, factor association interpolated maps were generated to better visualize the distribution and potential sources of the PTEs in the Sarno Basin. The underlying geology substrata appear to be associated with raised of levels of Na, K, P, Rb, Ba, V, Co, B, Zr, and Li, due to the presence of pyroclastic rocks from Mt. Somma-Vesuvius. Similarly, elevated Pb, Zn, Cd, and Hg concentrations are most likely related to both geological and anthropogenic sources, the underlying volcanic rocks and contamination from fossil fuel combustion associated with urban centers. Interpolated factors score maps and clr-biplot indicate a clear correlation between Ni and Cr in samples taken along the Sarno River, and Ca and Mg near the Solofra district. After considering nearby anthropogenic sources, the Ni and Cr are PTEs from the Solofra tannery industry, while Ca and Mg correlate to the underlying limestone-rich soils of the area. This study shows the applicability of the compositional data analysis transformations, which relates perfectly relationships and dependencies between elements which can be lost when univariate and classical multivariate analyses are employed on normal data. Keywords: Sarno basin, PTEs, compositional data analysis, centered-log Transformation (clr), Biplot, Factor analysis, ArcGIS

The volcanic acidification of glacial Lake Caviahue, Province of Neuquen, Argentina

NASA Astrophysics Data System (ADS)

Varekamp, Johan C.

2008-12-01

Lake Caviahue (northern Patagonia, Argentina) is a large glacial lake acidified by volcanic fluids from Copahue volcano. The lake and the feeding rivers were sampled annually from 1997 till early 2006, including the eruptive period of 2000. Lake Caviahue waters evolved over time, with the most concentrated waters in 2000 during the eruptive period, followed by gradual dilution that was interrupted by renewed acidification in 2003-2004. Inversion of the lake water data and application of a dynamic non-steady state model for the lake provides our best quantitative estimates for the variation in element fluxes over the 9-year period. The model flux results agree well with most of the measured fluxes. The Copahue hydrothermal system had gently declining element fluxes between 1997 and mid-1999, although the lake was still becoming more concentrated. About 2-3 months before the 2000 eruption, element fluxes increased strongly, but the hydrothermal fluxes almost shutoff directly after the main eruptive events. The fluxes of several elements recovered post-2001, with an increase in element fluxes in 2003-2004; the lake became more dilute between 2004 and 2006. The intrusion of new magma into the hydrothermal system just prior to the 2000 eruption led to enhanced water rock interaction, with higher concentrations of the rock forming elements in the fluids, and the hot spring flow rate increased as a result of the higher pressure in the reservoir. The fluids became saturated in alunite and jarosite, and they were already saturated with anhydrite. Precipitation of these minerals possibly led to a decreased permeability of the hydrothermal reservoir, leading to the strongly reduced element fluxes just after the eruption. In addition, K, Al and S were retained in the newly precipitated minerals as well, further diminishing their export. The acidification in 2003-2004 may have resulted from a new small intrusion of magma or resulted from seismic activity that created new permeability and fresh rock surfaces for water rock interaction. The volcano is a significant source of toxic trace elements such as F, As, B and Li as well as a nutrient (P) for the local watershed. Monitoring of the hydrothermal fluids in the river that drains Copahue, especially the S/Cl, Mg/Cl and Mg/K values as well as the magnitude of the element fluxes would provide the best information for eruption forecasting for this volcano.

Estimation of dynamic load of mercury in a river with BASINS-HSPF model

Treesearch

Ying Ouyang; John Higman; Jeff Hatten

2012-01-01

Purpose Mercury (Hg) is a naturally occurring element and a pervasive toxic pollutant. This study investigated the dynamic loads of Hg from the Cedar-Ortega Rivers watershed into the Lower St. Johns River (LSJR), Florida, USA, using the better assessment science integrating point and nonpoint sources (BASINS)-hydrologic simulation program - FORTRAN (HSPF) model....

Elemental contaminants in the livers and ingesta of four subpopulations of the American coot (Fulica americana): An herbivorous winter migrant in San Francisco Bay

USGS Publications Warehouse

Hui, C.A.

1998-01-01

Water birds with diets high in animal foods in the San Francisco Bay area are exposed to trace elements that are potentially health impairing. Water birds with herbivorous diets have been less thoroughly examined. The concentrations of trace elements in the livers and the esophageal contents of an herbivorous water bird, the American coot (Fulica americana) were measured to compare levels of contaminant exposure among different locations in the Bay system and with other water birds. A total of 39 coots were collected from four sites: Napa River and Mare Island Strait in the north, Berkeley in the middle, and Coyote Creek in the south. Livers of Berkeley samples differed significantly from those of Napa River and Mare Island Strait by their greater concentrations of As and B and lower concentrations of Cu, but they seemed to be within normal ranges for birds. Otherwise the concentrations of trace elements in the livers did not differ among sites. Ingesta samples from Berkeley differed from the other sites because they tended to be higher in Al, V, and Zn. In contrast to waterfowl, livers from the herbivorous coots in San Francisco Bay showed little exposure to Cd, Hg, Pb, or Se. Coot ingesta showed few samples with measurable levels of Cd, Hg, or Se and had low levels of Pb. The herbivorous diet of coots may shield them from exposure to such elements. However, high levels of V were present in coot livers and ingesta from all four sites, suggesting adaptation to this toxic element. Copyright (C) 1998 Elsevier Science Ltd.

Trace element distribution in waters of the northern catchment area of Lake Linneret, northern Israel

NASA Astrophysics Data System (ADS)

Sandler, A.; Brenner, I. B.; Halicz, L.

1988-02-01

Waters of the northern watershed of Lake Kineret, sampled during the period 1978 1983, were analyzed for their major and trace element contents. The trace element concentrations of the major water sources of the watershed (the Dan and Banias springs) represent background values. After emergence, the waters are subjected to human activity. In crossing the populated and cultivated Hula Basin in man-made canals, the major and trace element contents increase. In comparison to the trace element concentrations, those of the major elements have narrow ranges and small temporal fluctuations. Trace element concentrations varied by 3 orders of magnitude, and temporal variations were large but not neccessarily seasonal. Point sources of trace elements were urban effluents, fish pond wastes, and peat soil drainage. The trace element concentrations decrease in the waters of the last segment of the Jordan River. All measured trace elements were below the criteria levels established by regulatory agencies. Several, however, were of the same order of magnitude. Addition of wastes from enhanced recycling, and morphologic modification of the final course of the Jordan River could result in increase in the trace element concentrations in the water.

Platinum group elements in stream sediments of mining zones: The Hex River (Bushveld Igneous Complex, South Africa)

NASA Astrophysics Data System (ADS)

Almécija, Clara; Cobelo-García, Antonio; Wepener, Victor; Prego, Ricardo

2017-05-01

Assessment of the environmental impact of platinum group elements (PGE) and other trace elements from mining activities is essential to prevent potential environmental risks. This study evaluates the concentrations of PGE in stream sediments of the Hex River, which drains the mining area of the Bushveld Igneous Complex (South Africa), at four sampling points. Major, minor and trace elements (Fe, Ca, Al, Mg, Mn, V, Cr, Zn, Cu, As, Co, Ni, Cd, and Pb) were analyzed by FAAS and ETAAS in suspended particulate matter and different sediment fractions (<63, 63-500 and 500-2000 μm), and Pt, Pd, Rh, and Ir were measured by ICP-MS after removal of interfering elements (cation exchange resin 50W-DOWEX-X8). Procedures were blank-corrected and accuracy checked using reference materials. Nickel, Cr, Pt, Pd, Rh and Ir show concentrations 3-, 13- 18-, 28-, 48- and 44- fold the typical upper continental crust levels, respectively, although lower than concentrations reported for the parent rocks. The highest concentrations were observed closer to the mining area, decreasing with distance and in the <63 μm fraction, probably derived from atmospheric deposition and surface runoff of PGE-rich particles released from mining activities. Thus, mining activities are causing some disturbance of the surface PGE geochemical cycle, increasing the presence of PGE in the fine fraction of river sediments. We propose that indicators such as airborne particulate matter, and soil and river sediment quality, should be added to the protocols for evaluating the sustainability of mining activities.

Effluent trading in river systems through stochastic decision-making process: a case study.

PubMed

Zolfagharipoor, Mohammad Amin; Ahmadi, Azadeh

2017-09-01

The objective of this paper is to provide an efficient framework for effluent trading in river systems. The proposed framework consists of two pessimistic and optimistic decision-making models to increase the executability of river water quality trading programs. The models used for this purpose are (1) stochastic fallback bargaining (SFB) to reach an agreement among wastewater dischargers and (2) stochastic multi-criteria decision-making (SMCDM) to determine the optimal treatment strategy. The Monte-Carlo simulation method is used to incorporate the uncertainty into analysis. This uncertainty arises from stochastic nature and the errors in the calculation of wastewater treatment costs. The results of river water quality simulation model are used as the inputs of models. The proposed models are used in a case study on the Zarjoub River in northern Iran to determine the best solution for the pollution load allocation. The best treatment alternatives selected by each model are imported, as the initial pollution discharge permits, into an optimization model developed for trading of pollution discharge permits among pollutant sources. The results show that the SFB-based water pollution trading approach reduces the costs by US$ 14,834 while providing a relative consensus among pollutant sources. Meanwhile, the SMCDM-based water pollution trading approach reduces the costs by US$ 218,852, but it is less acceptable by pollutant sources. Therefore, it appears that giving due attention to stability, or in other words acceptability of pollution trading programs for all pollutant sources, is an essential element of their success.

Dispersion of inorganic contaminants in surface water in the vicinity of Potchefstroom

NASA Astrophysics Data System (ADS)

Manyatshe, A.; Fosso-Kankeu, E.; van der Berg, D.; Lemmer, N.; Waanders, F.; Tutu, H.

2017-08-01

Potchefstroom and the neighbouring cities rely mostly on the Mooi River and Vaal River for their water needs. These rivers flow through the gold mining areas and farms, and are therefore likely to be contaminated with substantial amounts of inorganic pollutants. Water was collected along the rivers network, streams, canals and dams in Potchefstroom and the vicinity. The samples were characterized for geochemical parameters, metals and anions concentrations. The results showed high concentrations of potentially toxic elements such as As (4.53 mg/L - 5.74 mg/L), Cd (0.25 mg/L - 0.7 mg/L), Pb (1.14 mg/L - 5.13 mg/L) and U (0.04 mg/L - 0.11 mg/L) which were predominantly found around the mining areas. Elevated concentrations of anions such SO42- and CN- were detected around mining areas while NO3- was dominant near farms. The relatively high levels of anions and metals in the surface water made it unfit for domestic or agricultural use. The study showed that contaminants in mining and agricultural facilities were potentially mobilised, thus impacting the nearby water systems.

Reactor-released radionuclides in Susquehanna River sediments

USGS Publications Warehouse

Olsen, C.R.; Larsen, I.L.; Cutshall, N.H.; Donoghue, J.F.; Bricker, O.P.; Simpson, H.J.

1981-01-01

Three Mile Island (TMI) and Peach Bottom (PB) reactors have introduced 137Cs, 134Cs, 60Co, 58Co and several other anthropogenic radionuclides into the lower Susquehanna River. Here we present the release history for these nuclides (Table 1) and radionuclide concentration data (Table 2) for sediment samples collected in the river and upper portions of the Chesapeake Bay (Fig. 1) within a few months after the 28 March 1979 loss-of-coolant-water problem at TMI. Although we found no evidence for nuclides characteristic of a ruptured fuel element, we did find nuclides characteristic of routine operations. Despite the TMI incident, more than 95% of the total 134Cs input to the Susquehanna has been a result of controlled low-level releases from the PB site. 134Cs activity released into the river is effectively trapped by sediments with the major zones of reactor-nuclide accumulation behind Conowingo Dam and in the upper portions of Chesapeake Bay. The reported distributions document the fate of reactor-released radionuclides and their extent of environmental contamination in the Susquehanna-Upper Chesapeake Bay System. ?? 1981 Nature Publishing Group.

The Snake River Plain Volcanic Province: Insights from Project Hotspot

NASA Astrophysics Data System (ADS)

Shervais, J. W.; Potter, K. E.; Hanan, B. B.; Jean, M. M.; Duncan, R. A.; Champion, D. E.; Vetter, S.; Glen, J. M. G.; Christiansen, E. H.; Miggins, D. P.; Nielson, D. L.

2017-12-01

The Snake River Plain (SRP) Volcanic Province is the best modern example of a time-transgressive hotspot track beneath continental crust. The SRP began 17 Ma with massive eruptions of Columbia River basalt and rhyolite. After 12 Ma volcanism progressed towards Yellowstone, with early rhyolite overlain by basalts that may exceed 2 km thick. The early rhyolites are anorogenic with dry phenocryst assemblages and eruption temperatures up to 950C. Tholeiitic basalts have major and trace element compositions similar to ocean island basalts (OIB). Project Hotspot cored three deep holes in the central and western Snake River Plain: Kimama (mostly basalt), Kimberly (mostly rhyolite), and Mountain Home (lake sediments and basaslt). The Kimberly core documents rhyolite ash flows up to 700 m thick, possibly filling a caldera or sag. Chemical stratigraphy in Kimama and other basalt cores document fractional crystallization in relatively shallow magma chambers with episodic magma recharge. Age-depth relations in the Kimama core suggest accumulation rates of roughly 305 m/Ma. Surface and subsurface basalt flows show systematic variations in Sr-Nd-Pb isotopes with distance from Yellowstone interpreted to reflect changes in the proportion of plume source and the underlying heterogeneous cratonic lithosphere, which varies in age, composition, and thickness from west to east. Sr-Nd-Pb isotopes suggest <5% lithospheric input into a system dominated by OIB-like plume-derived basalts. A major flare-up of basaltic volcanism occurred 75-780 ka throughout the entire SRP, from Yellowstone in the east to Boise in the west. The youngest western SRP basalts are transitional alkali basalts that range in age from circa 900 ka to 2 ka, with trace element and isotopic compositions similar to the plume component of Hawaiian basalts. These observations suggest that ancient SCLM was replaced by plume mantle after the North America passed over the hotspot in the western SRP, which triggered renewed basaltic volcanism throughout the system. This young volcanism supports an active geothermal system fueled by a shallow crustal sill complex that underlies most of the SRP today.

Contamination and ecological risk assessment of toxic trace elements in the Xi River, an urban river of Shenyang city, China.

PubMed

Lin, Chunye; He, Mengchang; Liu, Xitao; Guo, Wei; Liu, Shaoqing

2013-05-01

The objectives of this study were to assess the enrichment, contamination, and ecological risk posed by toxic trace elements in the sediments of the Xi River in the industrialized city of Shenyang, China. Surface sediment and sediment core were collected; analyzed for toxic trace elements; and assessed with an index of geoaccumulation (Igeo), enrichment factor (EF) value, potential ecological risk factor (Er), ecological risk index (RI), and probable effect concentration quotient (PECQ). Elemental concentrations (milligram per kilogram) were 8.5-637.9 for As, 6.5-103.9 for Cd, 12.2-21.9 for Co, 90.6-516.0 for Cr, 258.1-1,791.5 for Cu, 2.6-19.0 for Hg, 70.5-174.5 for Ni, 126.9-1,405.8 for Pb, 3.7-260.0 for Sb, 38.4-100.4 for V, and 503-4,929 for Zn. The Igeo, EF, Er, and PECQ indices showed that the contamination of Cd and Hg was more serious than that of As, Cr, Cu, Ni, Pb, Sb, and Zn, whereas the presence of Co and V might be primarily from natural sources. The Igeo index for Cr and Ni might underestimate the degree of contamination, potentially as a result of high concentrations of these elements in the shale. The RI index was higher than 600, indicating a notably high ecological risk of sediment for the river. The average PECQ for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn ranged from 1.4 to 4.1 for surface sediment and from 5.2 to 9.6 in the sediment cores, indicating a high potential for an adverse biological effect. It was concluded that the sediment in the Xi River was severely contaminated and should be remediated as a hazardous material.

Anthropogenic gadolinium anomalies and rare earth elements in the water of Atibaia River and Anhumas Creek, Southeast Brazil.

PubMed

de Campos, Francisco Ferreira; Enzweiler, Jacinta

2016-05-01

The concentrations of rare earth elements (REE), measured in water samples from Atibaia River and its tributary Anhumas Creek, Brazil, present excess of dissolved gadolinium. Such anthropogenic anomalies of Gd in water, already described in other parts of the world, result from the use of stable and soluble Gd chelates as contrast agents in magnetic resonance imaging. Atibaia River constitutes the main water supply of Campinas Metropolitan area, and its basin receives wastewater effluents. The REE concentrations in water samples were determined in 0.22-μm pore size filtered samples, without and after preconcentration by solid-phase extraction with bis-(2-ethyl-hexyl)-phosphate. This preconcentration method was unable to retain the anthropogenic Gd quantitatively. The probable reason is that the Gd chelates dissociate slowly in acidic media to produce the free ion that is retained by the phosphate ester. Strong correlations between Gd and constituents or parameters associated with effluents confirmed the source of most Gd in water samples as anthropogenic. The shale-normalized REE patterns of Atibaia River and Anhumas Creek water samples showed light and heavy REE enrichment trends, respectively. Also, positive Ce anomalies in many Atibaia River samples, as well as the strong correlations of the REE (except Gd) with terrigenous elements, imply that inorganic colloidal particles contributed to the REE measured values.

Studying the effect of the Semipalatinsk Test Site on radionuclide and elemental composition of water objects in the Irtysh River.

PubMed

Solodukhin, V; Аidarkhanov, A; Lukashenko, S; Gluchshenko, V; Poznyak, V; Lyahova, O

2015-06-01

The results of the field and laboratory studies of radiation and environmental state at the specific area of Irtysh River adjacent to the Semipalatinsk Test Site are provided. It was found that the radiation situation in this area is normal: equivalent dose of γ-radiation = (0.11-0.13) µSv h(-1). Determination of radionuclide composition of soil, bottom sediment and water samples was performed by the methods of instrumental γ-spectrometry, radiochemical analysis and the liquid scintillation β-spectrometry. It was found that concentrations of the studied natural and artificial radionuclides in these objects are very low; no contamination with radionuclides was detected in this segment of Irtysh River. The article provides the results of elemental composition determination for samples of soil and bottom sediment (by X-ray fluorescence method) and water samples (by inductively coupled plasma mass spectrometry method). It is shown that the content of some elements (Li, Be, B, V, Cu, Sr, Mo) in the water of Irtysh River increases downstream. The additional studies are required to explain this peculiarity. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Wind River Watershed Restoration, 2005-2006 Annual Report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jezorek, Ian G.; Connolly, Patrick J.; Munz, Carrie

2008-11-10

This report summarizes work completed by U.S. Geological Survey's Columbia River Research Laboratory (USGS-CRRL) in the Wind River subbasin during the period April 2005 through March 2006 under Bonneville Power Administration (BPA) contract 22095. During this period, we collected temperature, flow, and habitat data to characterize habitat condition and variation within and among tributaries and mainstem sections in the Wind River subbasin. We also conducted electrofishing and snorkeling surveys to determine juvenile salmonid populations within select study areas throughout the subbasin. Portions of this work were completed with additional funding from U.S. Fish and Wildlife Service (USFWS) and the Lowermore » Columbia Fish Enhancement Group (LCFEG). A statement of work (SOW) was submitted to BPA in March 2005 that outlined work to be performed by USGS-CRRL. The SOW was organized by work elements, with each describing a research task. This report summarizes the progress completed under each work element.« less

Streamflow, dissolved solids, suspended sediment, and trace elements, San Joaquin River, California, June 1985-September 1988

USGS Publications Warehouse

Hill, B.R.; Gilliom, R.J.

1993-01-01

The 1985-88 study period included hydrologic extremes throughout most of central California. Except for an 11-month period during and after the 1986 flood, San Joaquin River streamflows during 1985-88 were generally less than median for 1975-88. The Merced Tuolumne, and Stanislaus Rivers together comprised 56 to 69 percent of the annual San Joaquin River flow, Salt and Mud Sloughs together comprised 6 to 19 percent, the upper San Joaquin River comprised 2 to 25 percent, and unmeasured sources from agricultural discharges and ground water accounted for 13 to 20 percent. Salt and Mud Sloughs and the unmeasured sources contribute most of the dissolved-solids load. The Merced, Tuolumne, and Stanislaus Rivers greatly dilute dissolved-solids concentrations. Suspended-sediment concentration peaked sharply at more than 600 milligrams per liter during the flood of February 1986. Concentrations and loads varied seasonally during low-flow conditions, with concentrations highest during the early summer irrigation season. Trace elements present primarily in dissolved phases are arsenic, boron, lithium, molybdenum, and selenium. Boron concentrations exceeded the irrigation water-quality criterion of 750 micrograms per liter more than 75 percent of the time in Salt and Mud Sloughs and more than 50 percent of the time at three sites on the San Joaquin River. Selenium concentrations exceeded the aquatic-life criterion of 5 micrograms per liter more than 75 percent of the time in Salt Slough and more than 50 percent of the time in Mud Slough and in the San Joaquin River from Salt Slough to the Merced River confluence. Concentrations of dissolved solids, boron, and selenium usually are highest during late winter to early spring, lower in early summer, higher again in mid-to-late summer, and the lowest in autumn, and generally correspond to seasonal inflows of subsurface tile-drain water to Salt and Mud Sloughs. Trace elements present primarily in particulate phases are aluminum, chromium, copper, iron, manganese, nickel, and zinc, none of which cause significant water-quality problems in the river.

Heavy metals pollution status in surface sediments (rivers and artifical lakes, Serbia)

NASA Astrophysics Data System (ADS)

Sakan, Sanja; Đorđević, Dragana

2017-04-01

Potentially hazardous trace elements, often in literature referred as "heavy metals", are deemed serious pollutants due to their toxicity, persistence and non-degradability in the environment. These elements play an important role in extent of water pollution and threaten the health of populations and ecosystems. As the sink of heavy metals, sediment beds adsorb metals in quantities that are many times higher than those found in the water column in the long-term polluted water environment. It is believed that most of the metal content, as much as 90% in aquatic sediments is bound to sediments. Metal contamination in these sediments could be directly affect the river water quality, resulting in potential consequences to the sensitive lowest levels of the food chain and ultimately to human health. The objective of this research was the evaluation of heavy metal contamination level in sediments of the most important rivers and artificial lakes in Serbia. The heavy metal enrichment in studied sediments was conducted by using: determination of total metal content, sequential extraction procedure for the fractionation of studied elements, quantification of the metal enrichment degree in the sediments by calculating geo-accumulation indices, determination of actual and potential element availability and application of BRAI index for the assessment of heavy metal bioavailability. The sediments were found to be contaminated by heavy metals to various extents, mostly with Cd, Cu, and Zn. The significant variation in heavy metal distribution among samples collected in this large region, encompassing all Serbian watersheds, suggests the selective contamination of sediments by heavy metals. Elevated concentrations of elements in most cases were detected in samples of river sediments, since artificial lake reservoirs are usually built in rural areas, where the less anthropogenic pollution. Rivers often flow through the towns and these water basins less or more loaded micronutrients, toxic substances, organic or inorganic, waste materials, depending on the species and type of industrial processes that are often without the necessary technological and mandatory treatment directly discharged into them. Due to the potential risk of heavy metal pollution in studied sediments, pollution prevention and control measurements seems necessary, especially in areas where we found increased levels of these elements.

Effects of dam construction and increasing pollutants on the ecohydrological evolution of a shallow freshwater lake in the Yangtze floodplain.

PubMed

Zeng, Linghan; McGowan, Suzanne; Cao, Yanmin; Chen, Xu

2018-04-15

Large river-floodplain systems which provide a variety of societal, economic and biological benefits are undergoing extensive and intensive human disturbance. However, floodplain lakes responses to multiple stressors are poorly understood. The Yangtze River and its floodplain which provide water and food resources for more than 300 million people are an important region in China. Hydrological regulation as well as socio-economic development have brought profound negative influence on this ecologically important area. To improve understanding of decadal-scale responses of floodplain lakes to multiple stressors, lake sediment proxies including particle size, geochemical elements, diatoms and chironomids were analysed in a lead-210 dated core from Futou Lake. The analyses show that dams constructed in 1935 and the early 1970s stabilized hydrological conditions in Futou Lake and impeded the interaction with the Yangtze River, resulting in a decrease in major elements (e.g., Mg, Al, Fe) transported into the lake and an increase of macrophyte-related chironomids (C. sylvestris-type, P. penicillatus-type and Paratanytarsus sp.). After the late 1990s, further decreases in major elements and increases in median grain size are attributed to the erosion of the Yangtze riverbed and declining supply of major elements-enriched sediments from the upper Yangtze caused by the impoundment of the Three Gorges Dam. Chironomid and diatom assemblages indicate that hydrological stabilization caused by dam constructions stimulated the growth of macrophytes, which may be important in buffering against an ecosystem state change towards a phytoplankton-dominated and turbid state with ongoing eutrophication. However, a recent increase in Zn, TP and the emergence of eutrophic diatom and chironomid species indicate initial signs of water quality deterioration which may be related to the combined effects of hydrological stabilization and aquaculture. Over all, the sediment record from Futou Lake emphasizes the importance of interactions between hydrological change and pollutant loads in determining floodplain lake ecosystem state. Copyright © 2017 Elsevier B.V. All rights reserved.

Geochemical correlation and 40Ar/39Ar dating of the Kern River ash bed and related tephra layers: Implications for the stratigraphy of petroleum-bearing formations in the San Joaquin Valley, California

USGS Publications Warehouse

Baron, D.; Negrini, R.M.; Golob, E.M.; Miller, D.; Sarna-Wojcicki, A.; Fleck, R.J.; Hacker, B.; Erendi, A.

2008-01-01

The Kern River ash (KRA) bed is a prominent tephra layer separating the K and G sands in the upper part of the Kern River Formation, a major petroleum-bearing formation in the southern San Joaquin Valley (SSJV) of California. The minimum age of the Kern River Formation was based on the tentative major-element correlation with the Bishop Tuff, a 0.759??0.002 Ma volcanic tephra layer erupted from the Long Valley Caldera. We report a 6.12??0.05 Ma 40Ar/39Ar date for the KRA, updated major-element correlations, trace-element correlations of the KRA and geochemically similar tephra, and a 6.0??0.2 Ma 40Ar/39Ar age for a tephra layer from the Volcano Hills/Silver Peak eruptive center in Nevada. Both major and trace-element correlations show that despite the similarity to the Bishop Tuff, the KRA correlates most closely with tephra from the Volcano Hills/Silver Peak eruptive center. This geochemical correlation is supported by the radiometric dates which are consistent with a correlation of the KRA to the Volcano Hills/Silver Peak center but not to the Bishop Tuff. The 6.12??0.05 Ma age for the KRA and the 6.0??0.2 Ma age for the tephra layer from the Volcano Hills/Silver Peak eruptive center suggest that the upper age of the Kern River Formation is over 5 Ma older than previously thought. Re-interpreted stratigraphy of the SSJV based on the new, significantly older age for the Kern River Formation opens up new opportunities for petroleum exploration in the SSJV and places better constraints on the tectonostratigraphic development of the SSJV. ?? 2007 Elsevier Ltd and INQUA.

VIEW OF PDP TANK TOP, LEVEL 0’, WITH VERTICAL ELEMENTS ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW OF PDP TANK TOP, LEVEL 0’, WITH VERTICAL ELEMENTS IN BACKGROUND, LTR TANK TOP ON LEFT, AND SHEAVE RACK ELEMENTS AT TOP, LOOKING NORTH - Physics Assembly Laboratory, Area A/M, Savannah River Site, Aiken, Aiken County, SC

Trace elements in the Fontinalis antipyretica from rivers receiving sewage of lignite and glass sand mining industry.

PubMed

Kosior, Grzegorz; Samecka-Cymerman, Aleksandra; Kolon, Krzysztof; Brudzińska-Kosior, Anna; Bena, Waldemar; Kempers, Alexander J

2015-07-01

Intensive lignite and glass sand mining and industrial processing release waste which may contain elements hazardous to the aquatic ecosystem and constitute a potential risk to human health. Therefore, their levels must be carefully controlled. As a result, we examined the effects of sewage on the aquatic Fontinalis antipyretica moss in the Nysa Łużycka (lignite industry) and the Kwisa Rivers (glass sand industry). The Nysa Łużycka and the Kwisa Rivers appeared to be heavily polluted with As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn, which were reflected in the extremely high concentration of these elements in F. antipyretica along the studied watercourses. In the Nysa Łużycka, trace element composition in the moss species is affected by lignite industry with accumulation in its tissues of the highest concentrations of Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn, while samples from the Kwisa sites influenced by glass sand industry revealed the highest concentrations of As, V and Fe. The principal component and classification analysis classifies the concentration of elements in the aquatic F. antipyretica moss, thus enabling the differentiation of sources of water pollution in areas affected by mining industry.

Suspended matter and bottom deposits in the Mahury estuarine system (French Guiana): Environmental consequences

NASA Astrophysics Data System (ADS)

Jouanneau, J. M.; Pujos, M.

As part of a study carried out on the major rivers in French Guiana to identify and estimate the respective share of local rivers in the sedimentation of estuaries and the inshore continental shelf, results are reported on the Mahury after 2 periods of fieldwork carried out during one dry and one rainy season. The specific characteristics of the whole Mahury fluvio-estuarine system can be summed up as follows: the sands have invariable annual characteristics; they show evidence of a long history, first marine, then continental and finally fluviatile. They play little part in sedimentation on the continental shelf, and what part they do play is limited to the beaches. The fine sediments too have invariable annual characteristics. They fall, if we consider their mineralogical and elemental composition, on either side of a limit separating the fluviatile and estuarine zones. Here, the sediment stocks are respectively authigenic and allothogenic, while the clay association and elemental composition in the latter zone are evidence of an Amazonian origin. The contribution of the Mahury (Comté-Orapu) to fine estuarine sedimentation thus appears at present to be a very limited one, the Amazon being predominant over vast coastal areas, including the French Guiana estuaries.

The spatial and temporal trends of Cd, Cu, Hg, Pb and Zn in Seine River floodplain deposits (1994-2000)

USGS Publications Warehouse

Grosbois, C.; Meybeck, Michel; Horowitz, A.; Ficht, A.

2006-01-01

Fresh floodplain deposits (FD), from 11 key stations, covering the Seine mainstem and its major tributaries (Yonne, Marne and Oise Rivers), were sampled from 1994 to 2000. Background levels for Cd, Cu, Hg, Pb, and Zn were established using prehistoric FD and actual bed sediments collected in small forested sub-basins in the most upstream part of the basin. Throughout the Seine River Basin, FD contain elevated concentrations of Cd, Cu, Hg, Pb and Zn compared to local background values (by factors > twofold). In the Seine River Basin, trace element concentrations display substantial downstream increases as a result of increasing population densities, particularly from Greater Paris (10 million inhabitants), and reach their maxima at the river mouth (Poses). These elevated levels make the Seine one of the most heavily impacted rivers in the world. On the other hand, floodplain-associated trace element levels have declined over the past 7 years. This mirrors results from contemporaneous suspended sediment surveys at the river mouth for the 1984-1999 period. Most of these temporal declines appear to reflect reductions in industrial and domestic solid wastes discharged from the main Parisian sewage plant (Seine Aval). ?? 2005 Elsevier B.V. All rights reserved.

Concentrations of mercury and other trace elements in walleye, smallmouth bass, and rainbow trout in Franklin D. Roosevelt Lake and the upper Columbia River, Washington, 1994

USGS Publications Warehouse

Munn, M.D.; Cox, S.E.; Dean, C.J.

1995-01-01

Three species of sportfish--walleye, smallmouth bass, and rainbow trout--were collected from Franklin D. Roosevelt Lake and the upstream reach of the Columbia River within the state of Washington, to determine the concentrations of mercury and other selected trace elements in fish tissue. Concentrations of total mercury in walleye fillets ranged from 0.11 to 0.44 milligram per kilogram, with the higher concentrations in the larger fish. Fillets of smallmouth bass and rainbow trout also contained mercury, but generally at lower concentrations. Other selected trace elements were found in fillet samples, but the concentrations were generally low depending on species and the specific trace element. The trace elements cadmium, copper, lead, and zinc were found in liver tissue of these same species with zinc consistently present in the highest concentration.

Trace elements and organic compounds in sediment and fish tissue from the Great Salt Lake basins, Utah, Idaho, and Wyoming, 1998-99

USGS Publications Warehouse

Waddell, Kidd M.; Giddings, Elise M.

2004-01-01

A study to determine the occurrence and distribution of trace elements, organochlorine pesticides, polychlorinated biphenyls (PCBs), and semivolatile organic compounds in sediment and in fish tissue was conducted in the Great Salt Lake Basins study unit of the National Water-Quality Assessment (NAWQA) program during 1998-99. Streambed-sediment and fish-tissue samples were collected concurrently at 11 sites and analyzed for trace-element concentration. An additional four sites were sampled for streambed sediment only and one site for fish tissue only. Organic compounds were analyzed from streambed-sediment and fish-tissue samples at 15 sites concurrently.Bed-sediment cores from lakes, reservoirs, and Farmington Bay collected by the NAWQA program in 1998 and by other researchers in 1982 were used to examine historical trends in trace-element concentration and to determine anthropogenic sources of contaminants. Cores collected in 1982 from Mirror Lake, a high-mountain reference location, showed an enrichment of arsenic, cadmium, copper, lead, tin, and zinc in the surface sediments relative to the deeper sediments, indicating that enrichment likely began after about 1900. This enrichment was attributed to atmospheric deposition during the period of metal-ore mining and smelting. A core from Echo Reservoir, in the Weber River Basin, however, showed a different pattern of trace-element concentration that was attributed to a local source. This site is located downstream from the Park City mining district, which is the most likely historical source of trace elements. Cores collected in 1998 from Farmington Bay show that the concentration of lead began to increase after 1842 and peaked during the mid-1980s and has been in decline since. Recent sediments deposited during 1996-98 indicate a 41- to 62-percent reduction since the peak in the mid-1980s.The concentration of trace elements in streambed sediment was greatest at sites that have been affected by historic mining, including sites on Little Cottonwood Creek in the Jordan River basin, Silver Creek in the Weber River basin, and the Weber River below the confluence with Silver Creek. There was significant correlation of lead concentrations in streambed sediment and fish tissue, but other trace elements did not correlate well. Streambed sediment and fish tissue collected from sites in the Bear River basin, which is predominantly rangeland and agriculture, generally had low concentrations of most elements.Sediment-quality guidelines were used to assess the relative toxicity of streambed-sediment sites to aquatic communities. Sites affected by mining exceeded the Probable Effect Concentration (PEC), the concentration at which it is likely there will be a negative effect on the aquatic community, for arsenic, cadmium, copper, lead, silver, mercury, and zinc. Sites that were not affected by mining did not exceed these criteria. Concentrations of trace elements in samples collected from the Great Salt Lake Basins study unit (GRSL) are high compared to those of samples collected nationally with the NAWQA program. Nine of 15 streambed-sediment samples and 11 of 14 fish-tissue samples had concentrations of at least one trace element greater than the concentration of 90 percent of the samples collected nationally during 1993-2000.Organic compounds that were examined in streambed sediment and fish-tissue samples also were examined in bed-sediment cores. A bed-sediment core from Farmington Bay of Great Salt Lake showed an increase in total polycyclic aromatic hydrocarbon (PAH) concentrations coincident with the increase in population in Salt Lake Valley, which drains into this bay. Analysis of streambed-sediment samples showed that the highest concentrations of PAHs were detected at urban sites, including two sites in the lower Jordan River (the Jordan River flows into Farmington Bay), the Weber River at Ogden Bay, and the Provo River near Provo. Other organic compounds detected in streambed sediment in the lower Jordan River were PCBs, DDT compounds, and chlordane compounds.Organic compounds were detected more frequently in fish tissue than in streambed sediment. Chlordane compounds and PCBs were detected more frequently at urban sites. DDT compounds were detected at 13 of 15 sites including urban and agricultural sites. Concentrations of total DDT in fish tissue exceeded the guideline for protection of fish-eating wildlife at two urban sites. The concentration of organic compounds in the GRSL study unit is low compared with that of samples collected nationally.

Occurrence and distribution of contaminants in bottom sediment and water of the Barron River Canal, Big Cypress National Preserve, Florida

USGS Publications Warehouse

Miller, Ronald L.; McPherson, Benjamin F.

2001-01-01

Trace elements and organic contaminants in bottom-sediment samples collected from 10 sites on the Barron River Canal and from one site on the Turner River in October 1998 had patterns of distribution that indicated different sources. At some sites on the Barron River Canal, lead, copper, and zinc, normalized to aluminum, exceeded limits normally considered as background and may be enriched by human activities. Polynuclear aromatic hydrocarbons and p-cresol, normalized against organic carbon, had patterns of distribution that indicated local sources of input from a road or vehicular traffic or from an old creosote wood treatment facility. Phthalate esters and the traces elements arsenic, cadmium, and zinc were more widely distributed with the highest normalized concentrations occurring at the Turner River background site, probably due to the high percentage of fine sediment (74% less than 63 micrometers) and high organic carbon concentration (42%) at that site and the binding effect of organic carbon on trace elements and trace organic compounds. Low concentrations of pesticides or pesticide degradation products were detected in bottom sediment (DDD and DDE, each less than 3.5 µg/kg) and water (9 pesticides, each less than 0.06 µ/L), primarily in the northern reach of the Barron River Canal where agriculture is a likely source. Although a few contaminants approached criteria that would indicate adverse effects on aquatic life, none exceeded the criteria, but the potential synergistic effects of mixtures of contaminants found at most sites are not included in the criteria.

Understanding groundwater, surface water, and hyporheic zone biogeochemical processes in a Chalk catchment using fluorescence properties of dissolved and colloidal organic matter

NASA Astrophysics Data System (ADS)

Lapworth, D. J.; Gooddy, D. C.; Allen, D.; Old, G. H.

2009-09-01

Understanding groundwater-surface water (GW-SW) interaction in Chalk catchments is complicated by the degree of geological heterogeneity. At this study site, in southern United Kingdom, alluvial deposits in the riparian zone can be considered as a patchwork of varying grades and types with an equally varied lateral connectivity. Some display good connection with the river system and others good connection with the groundwater system and, by definition, poorer connectivity with the surface water. By coupling tangential flow fractionation (TFF) with fluorescence analysis we were able to characterize the organic matter in the river and hyporheic zone. There is a significant proportion of particulate and colloidal fluorescent organic matter (FOM) within the river system and at depth within the gravels beneath the river channel. At depth in the hyporheic zone, the surface water inputs are dampened by mixing with deeper groundwater FOM. The shallow (0-0.5 m below river bed) hyporheic zone is highly dynamic as a result of changing surface water inputs from upstream processes. Labile C in the form of protein-like FOM appears to be attenuated preferentially compared to fulvic-like fluorescence in the hyporheic zone compared to the adjacent gravel and sand deposits. These preliminary findings have important implications for understanding nutrient and trace element mobility and attenuation within the groundwater, surface water, and hyporheic zone of permeable Chalk catchments. Fluorescence analysis of dissolved organic matter has been shown to be a useful environmental tracer that can be used in conjunction with other methods to understand GW-SW processes within a permeable Chalk catchment.

Petroleum Systems and Geologic Assessment of Oil and Gas Resources in the Wind River Basin Province, Wyoming

USGS Publications Warehouse

,

2007-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the Wind River Basin Province which encompasses about 4.7 million acres in central Wyoming. The assessment is based on the geologic elements of each total petroleum system (TPS) defined in the province, including hydrocarbon source rocks (source-rock maturation, hydrocarbon generation, and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined three TPSs: (1) Phosphoria TPS, (2) Cretaceous-Tertiary TPS, and (3) Waltman TPS. Within these systems, 12 Assessment Units (AU) were defined and undiscovered oil and gas resources were quantitatively estimated within 10 of the 12 AUs.

Implementing an Integrated Commitment Management System at the Savannah River Site Tank Farms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blanchard, A.

1999-06-16

Recently, the Savannah River Site Tank Farms have been transitioning from pre-1990 Authorization Basis requirements to new 5480.22/.23 requirements. Implementation of the new Authorization Basis has resulted in more detailed requirements, a completely new set of implementing procedures, and the expectation of even more disciplined operations. Key to the success of this implementation has been the development of an Integrated Commitment Management System (ICMS) by Westinghouse Safety Management Solutions. The ICMS has two elements: the Authorization Commitment Matrix (ACM), and a Procedure Consistency Review methodology. The Authorization Commitment Matrix is a linking database, which ties requirements and implementing documents together.more » The associated Procedure Consistency Review process ensures that the procedures to be credited in the ACM do in fact correctly and completely meet all intended commitments. This Integrated Commitment Management System helps Westinghouse Safety Management Solutions and the facility operations and engineering organizations take ownership in the implementation of the requirements that have been developed.« less

Environmental setting of fixed sites in the western Lake Michigan drainages, Michigan and Wisconsin

USGS Publications Warehouse

Sullivan, D.J.; Peterson, E.M.; Richards, K.D.

1995-01-01

This report describes selected environmental- setting features for 11 fixed surface-water sites in the Western Lake Michigan Drainages study unit of the National Water-Quality Assessment Pro- gram. The study unit, which includes 10 major river systems draining to Lake Michigan, is bounded on the south by the Illinois State line and extends north to about 31 miles north of Escanaba, Mich. The fixed sites are on the following streams: Peshekee River, Popple River, Menominee River, Pensaukee River, Duck Creek, Tomorrow River, East River, Fox River, North Branch Milwaukee River, Lincoln Creek, and Milwaukee River. Drainage basins above these sites receive runoff from land uses and land covers, bedrock types, and surficial deposits representative of the main types of each of these characteristics in the study unit. Data types collected at the fixed sites include water chemistry; organic compounds and trace elements in streambed sediment and biological tissues; algal, benthic-invertebrate, and fish communities; and aquatic habitat. Field measurements include water temperature, pH, specific conductance, alkalinity, and dissolved oxygen. Results of water- quality field measurements indicate little variation in temperature among the fixed sites. Specific conductance and alkalinity were generally higher at sites underlain by carbonate bedrock than at sites underlain by igneous/metamorphic bedrock. Differences in pH among the fixed sites were less than those for specific conductance and alkalinity, but pH seemed to increase slightly from north to south. Dissolved-oxygen concentration varied more at agricultural sites than at forested and urban sites, perhaps because of higher nutrient inputs at agricultural sites. The information included in this report has been assembled as reference material for ongoing studies at the fixed sites.

Water quality in the lower Puyallup River valley and adjacent uplands, Pierce County, Washington

USGS Publications Warehouse

Ebbert, J.C.; Bortleson, Gilbert C.; Fuste, L.A.; Prych, E.A.

1987-01-01

The quality of most ground and surface water within and adjacent to the lower Puyallup River valley is suitable for most typical uses; however, some degradation of shallow groundwater quality has occurred. High concentrations of iron and manganese were found in groundwater, sampled at depths of < 40 ft, from wells tapping alluvial aquifers and in a few wells tapping deeper aquifers. Volatile and acid- and base/neutral-extractable organic compounds were not detected in either shallow or deep groundwater samples. The quality of shallow groundwater was generally poorer than that of deep water. Deep ground water (wells set below 100 ft) appears suitable as a supplementary water supply for fish-hatchery needs. Some degradation of water quality, was observed downstream from river mile 1.7 where a municipal wastewater-treatment plant discharges into the river. In the Puyallup River, the highest concentrations of most trace elements were found in bed sediments collected downstream from river mile 1.7. Median concentrations of arsenic, lead, and zinc were higher in bed sediments from small streams compared with those from the Puyallup River, possibly because the small stream drainages, which are almost entirely within developed areas, receive more urban runoff as a percentage of total flow. Total-recoverable trace-element concentrations exceeded water-quality criteria for acute toxicity in the Puyallup River and in some of the small streams. In most cases, high concentrations of total-recoverable trace elements occurred when suspended-sediment concentrations were high. Temperatures in all streams except Wapato Creek and Fife Dutch were within limits (18 C) for Washington State class A water. Minimum dissolved oxygen concentrations were relatively low at 5.6 and 2.0 mg/L, respectively, for Wapato Creek and Fife Dutch. The poorest surface-water quality, which can be characterized as generally unsuitable for fish, was in Fife Dutch, a manmade channel and therefore uncharacteristic of other small streams. (Author 's abstract)

A flood risk assessment and mapping for Riga city

NASA Astrophysics Data System (ADS)

Bethers, U.; Sennikovs, J.; Virbulis, J.; Timuhins, A.

2009-04-01

Riga (population ca. 800,000) is the capital of Latvia. The city is located at the southern coast of Gulf of Riga along the lower stretch of the River Daugava. The water bodies adjacent or within the territory of the city are the River Daugava itself, its connection (Bullupe) to another major river - Lielupe, several minor tributaries of the River Daugava, as well as an interconnected lake system of estuarine origin. The flow in the lower stretch of the River Daugava is regulated by Riga hydropower plant which is situated approx. 25 kilometers upstream the river mouth. The lowest 12 kilometers of the river channel is dredged to ensure the operation of the Riga Freeport. The aims of the study were (1) the identification of the flood risk situations, (2) the quantification of the flooding scenarious of different return periods, (3) the building and calibration of the hydrodynamical mathematical model for the domain potentially vulnerable for flooding, (4) the calculation of flood events with different return period, and (5) the detailed (horizontal accuracy around 10 m) of the potentially flooded areas. The combination of storm surges in the southern part of Gulf of Riga with unfavorable regime of hydropower plant operation was found as the most dangerous flooding situation. The time series of water level at the mouth of the River Daugava was analysed for more than 130 year long time period. The significant trend was found in the annual peak water level. Five significant storm events were found in time period 2001-2007 which roughly correspond to storm surges with return period once in 5, 10, 20, 50 and 100 years. The model storm events were created by scaling waterlevel and meteorological conditions during these selected events, and superposing them with hydropowerplant operation regime. The finite-element based shallow water model was built for the area, potentially vulnerable for flooding. Heterogeneous depth/terrain information from various sources was integrated in the model. The linear objects (watercourses, dams, etc.) of hydraulic importance were included in the model. The typical spatial resolution of approx. 50-100 m was reached with total number of finite elements around 250,000. The hydrodynamical model was calibrated on the basis of water level observations in 5 different locations during 5 selected real storm events. The hydrodynamics of the flood scenarious were calculated for the model storm situations. The importance of the dynamical modeling of flooded areas was shown for the domain with a complex channel system and typical length of storm event below 18 hours. The method for the mapping of the results of hydrodynamical calculations on the digital terrain map of much higher (10 m) spatial resolution was proposed and applied.

Aftermath of Uranium Ore Processing on Floodplains: Lasting Effects of Uranium on Soil and Microbes

NASA Astrophysics Data System (ADS)

Tang, H.; Boye, K.; Bargar, J.; Fendorf, S. E.

2016-12-01

A former uranium ore processing site located between the Wind River and the Little Wind River near the city of Riverton, Wyoming, has generated a uranium plume in the groundwater within the floodplain. Uranium is toxic and poses a threat to human health. Thus, controlling and containing the spread of uranium will benefit the human population. The primary source of uranium was removed from the processing site, but a uranium plume still exists in the groundwater. Uranium in its reduced form is relatively insoluble in water and therefore is retained in organic rich, anoxic layers in the subsurface. However, with the aid of microbes uranium becomes soluble in water which could expose people and the environment to this toxin, if it enters the groundwater and ultimately the river. In order to better understand the mechanisms controlling uranium behavior in the floodplains, we examined sediments from three sediment cores (soil surface to aquifer). We determined the soil elemental concentrations and measured microbial activity through the use of several instruments (e.g. Elemental Analyzer, X-ray Fluorescence, MicroResp System). Through the data collected, we aim to obtain a better understanding of how the interaction of geochemical factors and microbial metabolism affect uranium mobility. This knowledge will inform models used to predict uranium behavior in response to land use or climate change in floodplain environments.

Magma mixing and the generation of isotopically juvenile silicic magma at Yellowstone caldera inferred from coupling 238U–230Th ages with trace elements and Hf and O isotopes in zircon and Pb isotopes in sanidine

USGS Publications Warehouse

Stelten, Mark E.; Cooper, Kari M.; Vazquez, Jorge A.; Reid, Mary R.; Barfod, Gry H.; Wimpenny, Josh; Yin, Qing-Zhu

2013-01-01

The nature of compositional heterogeneity within large silicic magma bodies has important implications for how silicic reservoirs are assembled and evolve through time. We examine compositional heterogeneity in the youngest (~170 to 70 ka) post-caldera volcanism at Yellowstone caldera, the Central Plateau Member (CPM) rhyolites, as a case study. We compare 238U–230Th age, trace-element, and Hf isotopic data from zircons, and major-element, Ba, and Pb isotopic data from sanidines hosted in two CPM rhyolites (Hayden Valley and Solfatara Plateau flows) and one extracaldera rhyolite (Gibbon River flow), all of which erupted near the caldera margin ca. 100 ka. The Hayden Valley flow hosts two zircon populations and one sanidine population that are consistent with residence in the CPM reservoir. The Gibbon River flow hosts one zircon population that is compositionally distinct from Hayden Valley flow zircons. The Solfatara Plateau flow contains multiple sanidine populations and all three zircon populations found in the Hayden Valley and Gibbon River flows, demonstrating that the Solfatara Plateau flow formed by mixing extracaldera magma with the margin of the CPM reservoir. This process highlights the dynamic nature of magmatic interactions at the margins of large silicic reservoirs. More generally, Hf isotopic data from the CPM zircons provide the first direct evidence for isotopically juvenile magmas contributing mass to the youngest post-caldera magmatic system and demonstrate that the sources contributing magma to the CPM reservoir were heterogeneous in 176Hf/177Hf at ca. 100 ka. Thus, the limited compositional variability of CPM glasses reflects homogenization occurring within the CPM reservoir, not a homogeneous source.

Occurrence of Selected Nutrients, Trace Elements, and Organic Compounds in Streambed Sediment in the Lower Chena River Watershed near Fairbanks, Alaska, 2002-03

USGS Publications Warehouse

Kennedy, Ben W.; Hall, Cassidee C.

2009-01-01

In 2002-03, the U.S. Geological Survey collected samples of streambed sediment at 18 sites in the lower Chena River watershed for analysis of selected nutrients, traces elements, and organic compounds. The purpose of the project was to provide Federal, State, and local agencies as well as neighborhood committees, with information for consideration in plans to improve environmental conditions in the watershed. The exploratory sampling program included analysis of streambed sediment from the Chena River and Chena Slough, a tributary to the Chena River. Results were compared to streambed-sediment guidelines for the protection of aquatic life and to 2001-02 sediment data from Noyes Slough, a side channel of the lower Chena River. The median total phosphorus concentration in Chena Slough sediment samples, 680 milligrams per kilogram (mg/kg), was two orders of magnitude greater than median total phosphorus concentration in Chena River sediment samples of 5.2 mg/kg. Median concentrations of chloride and sulfate also were greater in Chena Slough samples. Low concentrations of nitrate were detected in most of the Chena Slough samples; nitrate concentrations were below method reporting limits or not detected in Chena River sediment samples. Streambed-sediment samples were analyzed for 24 trace elements. Arsenic, nickel, and zinc were the only trace elements detected in concentrations that exceeded probable-effect levels for the protection of aquatic life. Concentrations of arsenic in Chena Slough samples ranged from 11 to 70 mg/kg and concentrations in most of the samples exceeded the probable-effect guideline for arsenic of 17 mg/kg. Arsenic concentrations in samples from the Chena River ranged from 9 to 12 mg/kg. The background level for arsenic in the lower Chena River watershed is naturally elevated because of significant concentrations of arsenic in local bedrock and ground water. Sources of elevated concentrations of zinc in one sample, and of nickel in two samples, are unknown. With the exception of elevated arsenic levels in samples from Chena Slough, the occurrence and concentration of trace elements in the streambed sediments of Chena Slough and Chena River were similar to those in Noyes Slough sediment. Sediment samples were analyzed for 78 semivolatile organic compounds and 32 organochlorine pesticides and polychlorinated biphenyls (PCBs). Low concentrations of dimethylnaphthalene and p-Cresol were detected in most Chena Slough and Chena River sediment samples. The number of semivolatile organic compounds detected ranged from 5 to 21 in most Chena Slough sediment samples. In contrast, three or fewer semivolatile organic compounds were detected in Chena River sediment samples, most likely because chemical-matrix interference resulted in elevated reporting limits for organochlorine compounds in the Chena River samples. Low concentrations of fluoranthene, pyrene, and phenanthrene were detected in Chena Slough sediment. Relatively low concentrations of DDT or its degradation products, DDD and DDE, were detected in all Chena Slough samples. Concentrations of total DDT (DDT+DDD+DDE) in two Chena Slough sediment samples exceeded the effectsrange median aquatic-life criteria of 46.1 micrograms per kilogram (ug/kg). DDT concentrations in Chena River streambed-sediment samples were less than 20 ug/kg. Low concentrations of PCB were detected in two Chena Slough streambed-sediment samples. None of the concentrations of the polychlorinated biphenyls or semivolatile organic compounds for which the samples were analyzed exceeded available guidelines for the protection of aquatic life. With the exception of elevated total DDT in two Chena Slough samples, the occurrence and concentration of organochlorine compounds in Chena Slough and Chena River sediment were similar to those in samples collected from Noyes Slough in 2001-02.

Using Agent-Based Modeling to Enhance System-Level Real-time Control of Urban Stormwater Systems

NASA Astrophysics Data System (ADS)

Rimer, S.; Mullapudi, A. M.; Kerkez, B.

2017-12-01

The ability to reduce combined-sewer overflow (CSO) events is an issue that challenges over 800 U.S. municipalities. When the volume of a combined sewer system or wastewater treatment plant is exceeded, untreated wastewater then overflows (a CSO event) into nearby streams, rivers, or other water bodies causing localized urban flooding and pollution. The likelihood and impact of CSO events has only exacerbated due to urbanization, population growth, climate change, aging infrastructure, and system complexity. Thus, there is an urgent need for urban areas to manage CSO events. Traditionally, mitigating CSO events has been carried out via time-intensive and expensive structural interventions such as retention basins or sewer separation, which are able to reduce CSO events, but are costly, arduous, and only provide a fixed solution to a dynamic problem. Real-time control (RTC) of urban drainage systems using sensor and actuator networks has served as an inexpensive and versatile alternative to traditional CSO intervention. In particular, retrofitting individual stormwater elements for sensing and automated active distributed control has been shown to significantly reduce the volume of discharge during CSO events, with some RTC models demonstrating a reduction upwards of 90% when compared to traditional passive systems. As more stormwater elements become retrofitted for RTC, system-level RTC across complete watersheds is an attainable possibility. However, when considering the diverse set of control needs of each of these individual stormwater elements, such system-level RTC becomes a far more complex problem. To address such diverse control needs, agent-based modeling is employed such that each individual stormwater element is treated as an autonomous agent with a diverse decision making capabilities. We present preliminary results and limitations of utilizing the agent-based modeling computational framework for the system-level control of diverse, interacting stormwater elements.

Developing a shared understanding of the Upper Mississippi River: the foundation of an ecological resilience assessment

USGS Publications Warehouse

Bouska, Kristen; Houser, Jeff N.; De Jager, Nathan R.; Hendrickson, Jon S.

2018-01-01

The Upper Mississippi River System (UMRS) is a large and complex floodplain river ecosystem that spans the jurisdictions of multiple state and federal agencies. In support of ongoing ecosystem restoration and management by this broad partnership, we are undertaking a resilience assessment of the UMRS. We describe the UMRS in the context of an ecological resilience assessment. Our description articulates the temporal and spatial extent of our assessment of the UMRS, the relevant historical context, the valued services provided by the system, and the fundamental controlling variables that determine its structure and function. An important objective of developing the system description was to determine the simplest, adequate conceptual understanding of the UMRS. We conceptualize a simplified UMRS as three interconnected subsystems: lotic channels, lentic off-channel areas, and floodplains. By identifying controlling variables within each subsystem, we have developed a shared understanding of the basic structure and function of the UMRS, which will serve as the basis for ongoing quantitative evaluations of factors that likely contribute to the resilience of the UMRS. As we undertake the subsequent elements of a resilience assessment, we anticipate our improved understanding of interactions, feedbacks, and critical thresholds will assist natural resource managers to better recognize the system’s ability to adapt to existing and new stresses.

In Vitro Selection of a Single-Stranded DNA Molecular Recognition Element against the Pesticide Fipronil and Sensitive Detection in River Water

PubMed Central

Sooter, Letha J.

2017-01-01

Fipronil is a commonly used insecticide that has been shown to have environmental and human health risks. The current standard methods of detection for fipronil and its metabolites, such as GC-MS, are time consuming and labor intensive. In this study, a variant of systematic evolution of ligands by exponential enrichment (SELEX), was utilized to identify the first single-stranded DNA (ssDNA) molecular recognition element (MRE) that binds to fipronil with high affinity (Kd = 48 ± 8 nM). The selected MRE displayed low cross binding activity on various environmentally relevant, structurally unrelated herbicides and pesticides, in addition to broad-spectrum binding activity on major metabolites of fipronil and a structurally similar pesticide in prepared river samples. Additionally, a proof-of-principle fluorescent detection assay was developed by using the selected ssDNA MRE as a signal-reporting element, with a limit of detection of 105 nM in a prepared river water sample. PMID:29283416

Seasonal variations and environmental risk assessment of trace elements in the sediments of Uppanar River estuary, southern India.

PubMed

Gopal, V; Nithya, B; Magesh, N S; Jayaprakash, M

2018-04-01

Twenty four surface sediments were gathered from the Uppanar river estuary, southern India to evaluate the trace element contamination risk in the sediments. The circulation of organic matter and calcium carbonate were controlled by algal blooms and shell fragments. Moreover, the concentrations of iron and manganese in the estuarine sediments were possibly contributed by riverine sources and geogenic processes. The geoaccumulation index, enrichment factor and contamination factor reveals that the sediments were contaminated by copper and chromium. The pollution load index recommends that the estuarine sediments have the risk of pollution. The sediment pollution index highlights that the majority of the sediments are low polluted sediments. The potential ecological risk index discloses that the Uppanar river estuary is under moderate risk. The statistical analysis reveals that the organic matter content is managed by fine fractions and the majority of the trace elements are associated with each other having similar origin. Copyright © 2018 Elsevier Ltd. All rights reserved.

DEM Simulated Results And Seismic Interpretation of the Red River Fault Displacements in Vietnam

NASA Astrophysics Data System (ADS)

Bui, H. T.; Yamada, Y.; Matsuoka, T.

2005-12-01

The Song Hong basin is the largest Tertiary sedimentary basin in Viet Nam. Its onset is approximately 32 Ma ago since the left-lateral displacement of the Red River Fault commenced. Many researches on structures, formation and tectonic evolution of the Song Hong basin have been carried out for a long time but there are still remained some problems that needed to put into continuous discussion such as: magnitude of the displacements, magnitude of movement along the faults, the time of tectonic inversion and right lateral displacement. Especially the mechanism of the Song Hong basin formation is still in controversy with many different hypotheses due to the activation of the Red River fault. In this paper PFC2D based on the Distinct Element Method (DEM) was used to simulate the development of the Red River fault system that controlled the development of the Song Hong basin from the onshore to the elongated portion offshore area. The numerical results show the different parts of the stress field such as compress field, non-stress field, pull-apart field of the dynamic mechanism along the Red River fault in the onshore area. This propagation to the offshore area is partitioned into two main branch faults that are corresponding to the Song Chay and Song Lo fault systems and said to restrain the east and west flanks of the Song Hong basin. The simulation of the Red River motion also showed well the left lateral displacement since its onset. Though it is the first time the DEM method was applied to study the deformation and geodynamic evolution of the Song Hong basin, the results showed reliably applied into the structural configuration evaluation of the Song Hong basin.

Landscape-scale Habitat Templates and Life Histories of Endangered and Invasive Fish Species in Large Rivers of the Mid-Continent USA (Invited)

NASA Astrophysics Data System (ADS)

Jacobson, R. B.; Braaten, P. J.; Chapman, D.; DeLonay, A. J.

2013-12-01

Many fish species migrate through river systems to complete their life cycles, occupying specific habitats during specific life stages. Regional geomorphology sets a template for their habitat-use patterns and ontogenetic development. In large rivers of the Mid-continent USA, understanding of relations of fish life histories to landscape-scale habitat templates informs recovery of endangered species and prevention of spread of invasive species. The endangered pallid sturgeon has evolved in the Missouri-Mississippi river system over 150 Ma. Its present-day distribution probably results from extensive drainage re-arrangements during the Pleistocene, followed by contemporary fragmentation. The reproductive and early life-stage needs of pallid sturgeon encompass hundreds of km, as adults migrate upstream to spawn and free embryos and larvae disperse downstream. Spawning requires coarse, hard substrate for incubation of adhesive eggs but adult pallid sturgeon are found predominately over sand, indicating that coarse substrate is a critical but transient habitat need. Once hatched, free-embryos initiate 9-17 days of downstream dispersal that distributes them over several hundreds of km. Lotic conditions at the dispersal terminus are required for survival. Persistent recruitment failure has been attributed to dams and channelization, which have fragmented migration and dispersal corridors, altered flow regimes, and diminished rearing habitats. Key elements of the natural history of this species remain poorly understood because adults are rare and difficult to observe, while the earliest life stages are nearly undetectable. Recent understanding has been accelerated using telemetry and hydroacoustics, but such assessments occur in altered systems and may not be indicative of natural behaviors. Restoration activities attempt - within considerable uncertainty -- to restore elements of the habitat template where they are needed. In comparison, invasive Asian carps have been present in large rivers of the Mid-Continent for no more than 40 years and have experienced rapid population growth as they exploit the landscape. Asian carps also spawn in turbulent water over coarse substrate, but in contrast to sturgeon, their eggs are buoyant and drift downstream, hatching in the water column, followed by continued dispersal as free-embryos and larvae. Asian carp eggs and larvae may drift for 4 to 7 days, with dispersal of several hundreds of km, depending on prevailing water velocities. After the drift phase, young Asian carp need lentic habitats in channel margins, floodplains, or lakes, to feed and grow. Hence, Asian carps need a habitat template that combines upstream flowing water and downstream floodplain connectivity. Control strategies for Asian carp seek to minimize access to required template elements. Managing habitat templates for endangered and invasive species on the same landscape may be complementary or conflicting. Understanding of the species' ecology and the landscape-scale habitat template is necessary for effective management.

Changes in sediment-associated trace element concentrations in the Seine river basin (1994-2001)

USGS Publications Warehouse

Meybeck, Michel; Horowitz, A.J.; Grosbois, C.; Gueguen, Y.; ,

2003-01-01

In the 1980's, based on the concentrations of particulate-associated Hg, Cd, Pb, Cu and Zn relative to very low natural background levels, the Seine River Basin was one of the most impacted in the world. Over the past 20 years, there has been a general decline in these elevated concentrations that parallels declines in Paris sewage sludge trace element levels. Within the basin, marked differences in spatial and temporal geochemical patterns have been observed: (1) between major tributaries, (2) between trace elements, and (3) with stream order and population density, all of which illustrate the complexity of the geochemical processes ongoing in the basin.

Inventory of Physical and Cultural Elements, Middle Mississippi River Floodplain (River Reach - St. Louis, Missouri, to Cairo, Illinois)

DTIC Science & Technology

1975-01-01

Environmental Effects Laboratory in July 1971 *. the floodplain. This report was written by Mr. Stoll and CPT R. D. Brown, formerly of ESB. Directors of...Middle Mississippi River for 1971 « ’ It should be noted that these tables exclude Government em- ployees, railroad employees, and self-employed...pipeline. 180. A breakdown of 1971 cargo tonnage for commodity groups car- 1+1 ried on the Middle Mississippi River is presented in Table 19. Spe

3_D modeling using TLS and GPR techniques to characterize above and below-ground wood distribution in pyroclastic deposits along the Blanco River (Chilean Patagonia)

NASA Astrophysics Data System (ADS)

Valdebenito, Galo; Tonon, Alessia; Iroume, Andrés; Alvarado, David; Fuentes, Carlos; Picco, Lorenzo; Lenzi, Mario

2016-04-01

To date, the study of in-stream wood in rivers has been focused mainly on quantifying wood pieces deposited above the ground. However, in some particular river systems, the presence of buried dead wood can also represent an important component of wood recruitment and budgeting dynamics. This is the case of the Blanco River (Southern Chile) severely affected by the eruption of Chaitén Volcano occurred between 2008 and 2009. The high pyroclastic sediment deposition and transport affected the channel and the adjacent forest, burying wood logs and standing trees. The aim of this contribution is to assess the presence and distribution of wood in two study areas (483 m2 and 1989 m2, respectively) located along the lower streambank of the Blanco River, and covered by thick pyroclastic deposition up to 5 m. The study areas were surveyed using two different devices, a Terrestrial Laser Scanner (TLS) and a Ground Penetrating Radar (GPR). The first was used to scan the above surface achieving a high point cloud density (≈ 2000 points m-2) which allowed us to identify and measure the wood volume. The second, was used to characterize the internal morphology of the volcanic deposits and to detect the presence and spatial distribution of buried wood up to a depth of 4 m. Preliminary results have demonstrated differences in the numerousness and volume of above wood between the two study areas. In the first one, there were 43 wood elements, 33 standing trees and 10 logs, with a total volume of 2.96 m3 (109.47 m3 km-1), whereas the second one was characterized by the presence of just 7 standing trees and 11 wood pieces, for a total amount of 0.77 m3 (7.73 m3 km-1). The dimensions of the wood elements vary greatly according to the typology, standing trees show the higher median values in diameter and length (0.15 m and 2.91 m, respectively), whereas the wood logs were smaller (0.06 m and 1.12 m, respectively). The low dimensions of deposited wood can be probably connected to their origin, suggesting that these elements were generated by toppling and breaking of surrounding dead trees. Results obtained with the GPR confirm the ability of this instrument to localize the presence and distribution of buried wood. From the 3-D analysis it was possible to assess the spatial distribution and to estimate, as first approach, the volume of the buried wood which represents approximately 0.04% of the entire volcanic deposit. Further analysis will focus on additional GPR calibration with different wood sizes for a more accurate estimation of the volume. The knowledge of the overall wood amount stored in a fluvial system that can be remobilized over time, represent an essential factor to ensure better forest and river management actions.

Contribution of geophysical methods in the study of the floodplain structure (the Litavka River, the Czech Republic)

NASA Astrophysics Data System (ADS)

Kotková, Kristýna; Matys Grygar, Tomáš; Tůmová, Štěpánka; Elznicová, Jitka

2017-04-01

Mining and processing of polymetallic ores near the city of Příbram (the Czech Republic) have strongly impacted the fluvial system of the Litavka River. Beside of polymetallic mining during several hundred years with a peak between 1850 and 1950, the Litavka River was also influenced by uranium ore mining between 1948 and 1989. Severe contamination of the Litavka River system is known, but the alluvial architecture and specific distribution of contamination has not yet been satisfactorily described. However, such pieces of information are necessary for the predictions of the future behaviour of contaminants in the river system. We used geophysical methods for visualisation of subsurface layers of sediments and we have proved them very useful for the survey of the floodplain structure. It is especially advantageous when the surface topography of the floodplain does not reveal its internal structure, e.g. due to floodplain levelling by aggradation. Specifically, dipole electromagnetic profiling, also denoted electromagnetic induction sensing (DEMP) was used for quick detection of major heterogeneities in the floodplain structure. In addition, electrical resistivity tomography (ERT) was used for the exploration of lines across the heterogeneities shown by DEMP. This approach allows to choose the appropriate plan for the subsequent sampling in the floodplain to include all its structural (lithogenetic) units. Such rational strategy allows for reducing total amount of sampled sites without the risk of losing important information and production of false images. Both used geophysical tools and manual drill coring and the elemental analysis by handheld X-ray fluorescence spectrometry produced clear images of floodplain architecture and pollutant distribution. The internal structure of the Litavka River floodplain shows that lateral deposition and reworking of sediments played the main roles in the floodplain building. In the next centuries the lateral channel movement will rework contamination which is maximal in the current channel belt.

Trace elements and organic contaminants in stream sediments from the Red River of the North Basin

USGS Publications Warehouse

Brigham, M.E.; Tornes, L.H.

1996-01-01

To assess the presence and distribution of a variety of hydro-phobic chemicals in streams in the Red River of the North Basin, bottom sediments were analyzed for trace elements, organochlorines, and polycyclic aromatic hydrocarbons (PAHs). Glaciolacustrine clays and carbonate minerals are common in fine sediments of the region, and can help explain the distribution of many elements. Aluminum (Al), an indicator of glaciolacustrine clay minerals, correlates strongly (r>0.75, p<0.05) with Cr, Co, Fe, La, Li, K, Sc, and Ti; and moderately (0.55

Effect of irrigation pumpage during drought on karst aquifer systems in highly agricultural watersheds: example of the Apalachicola-Chattahoochee-Flint river basin, southeastern USA

NASA Astrophysics Data System (ADS)

Mitra, Subhasis; Srivastava, Puneet; Singh, Sarmistha

2016-09-01

In the Apalachicola-Chattahoochee-Flint (ACF) river basin in Alabama, Georgia, and Florida (USA), population growth in the city of Atlanta and increased groundwater withdrawal for irrigation in southwest Georgia are greatly affecting the supply of freshwater to downstream regions. This study was conducted to understand and quantify the effect of irrigation pumpage on the karst Upper Floridan Aquifer and river-aquifer interactions in the lower ACF river basin in southwest Georgia. The groundwater MODular Finite-Element model (MODFE) was used for this study. The effect of two drought years, a moderate and a severe drought year, were simulated. Comparison of the results of the irrigated and non-irrigated scenarios showed that groundwater discharge to streams is a major outflow from the aquifer, and irrigation can cause as much as 10 % change in river-aquifer flux. The results also show that during months with high irrigation (e.g., June 2011), storage loss (34 %), the recharge and discharge from the upper semi-confining unit (30 %), and the river-aquifer flux (31 %) are the major water components contributing towards the impact of irrigation pumpage in the study area. A similar scenario plays out in many river basins throughout the world, especially in basins in which underlying karst aquifers are directly connected to a nearby stream. The study suggests that improved groundwater withdrawal strategies using climate forecasts needs to be developed in such a way that excessive withdrawals during droughts can be reduced to protect streams and river flows.

INTELLIGENT COMPUTING SYSTEM FOR RESERVOIR ANALYSIS AND RISK ASSESSMENT OF THE RED RIVER FORMATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kenneth D. Luff

2002-06-30

Integrated software has been written that comprises the tool kit for the Intelligent Computing System (ICS). Luff Exploration Company is applying these tools for analysis of carbonate reservoirs in the southern Williston Basin. The integrated software programs are designed to be used by small team consisting of an engineer, geologist and geophysicist. The software tools are flexible and robust, allowing application in many environments for hydrocarbon reservoirs. Keystone elements of the software tools include clustering and neural-network techniques. The tools are used to transform seismic attribute data to reservoir characteristics such as storage (phi-h), probable oil-water contacts, structural depths andmore » structural growth history. When these reservoir characteristics are combined with neural network or fuzzy logic solvers, they can provide a more complete description of the reservoir. This leads to better estimates of hydrocarbons in place, areal limits and potential for infill or step-out drilling. These tools were developed and tested using seismic, geologic and well data from the Red River Play in Bowman County, North Dakota and Harding County, South Dakota. The geologic setting for the Red River Formation is shallow-shelf carbonate at a depth from 8000 to 10,000 ft.« less

INTELLIGENT COMPUTING SYSTEM FOR RESERVOIR ANALYSIS AND RISK ASSESSMENT OF THE RED RIVER FORMATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kenneth D. Luff

2002-09-30

Integrated software has been written that comprises the tool kit for the Intelligent Computing System (ICS). Luff Exploration Company is applying these tools for analysis of carbonate reservoirs in the southern Williston Basin. The integrated software programs are designed to be used by small team consisting of an engineer, geologist and geophysicist. The software tools are flexible and robust, allowing application in many environments for hydrocarbon reservoirs. Keystone elements of the software tools include clustering and neural-network techniques. The tools are used to transform seismic attribute data to reservoir characteristics such as storage (phi-h), probable oil-water contacts, structural depths andmore » structural growth history. When these reservoir characteristics are combined with neural network or fuzzy logic solvers, they can provide a more complete description of the reservoir. This leads to better estimates of hydrocarbons in place, areal limits and potential for infill or step-out drilling. These tools were developed and tested using seismic, geologic and well data from the Red River Play in Bowman County, North Dakota and Harding County, South Dakota. The geologic setting for the Red River Formation is shallow-shelf carbonate at a depth from 8000 to 10,000 ft.« less

Tokunaga river networks: New empirical evidence and applications to transport problems

NASA Astrophysics Data System (ADS)

Tejedor, A.; Zaliapin, I. V.

2013-12-01

The Tokunaga self-similarity has proven to be an important constraint for the observed river networks. Notably, various Horton laws are naturally satisfied by the Tokunaga networks, which makes this model of considerable interest for theoretical analysis and modeling of environmental transport. Recall that Horton self-similarity is a weaker property of a tree graph that addresses its principal branching; it is a counterpart of the power-law size distribution for system's elements. The stronger Tokunaga self-similarity addresses so-called side branching; it ensures that different levels of a hierarchy have the same probabilistic structure (in a sense that can be rigorously defined). We describe an improved statistical framework for testing self-similarity in a finite tree and estimating the related parameters. The developed inference is applied to the major river basins in continental United States and Iberian Peninsula. The results demonstrate the validity of the Tokunaga model for the majority of the examined networks with very narrow (universal) range of parameter values. Next, we explore possible relationships between the Tokunaga parameter anomalies (deviations from the universal values) and climatic and geomorphologic characteristics of a region. Finally, we apply the Tokunaga model to explore vulnerability of river networks, defined via reaction of the river discharge to a storm.

Organochlorine compounds and trace elements in fish tissue and ancillary data for the Connecticut, Housatonic, and Thames river basins study unit, 1992-94

USGS Publications Warehouse

Coles, J.F.

1996-01-01

Concentrations of organochlorine compounds and trace elements were assayed in fish tissue collected from the Connecticut, Housatonic, and Thames River Basins Study Unit, 1992-94. These data were collected to determine the occurrence and distribution of organochlorine compounds and trace elements in the study unit. Ancillary data included are land-use categories by percentage of the sampling-site basins and the size, gender, and age of the individual fish collected for this study. Concentrations of 28 organochlorine compounds in composited whole fish samples were measured at 32 sites, and concentrations of 22 trace elements in composited fish liver samples were measured at 14 of the 32 sites. Most frequently detected organochlorines were DDT related compounds at 31 sites, total PCBs at 28 sites, and chlordane related compounds at 25 sites. Concentrations of total PCBs in fish tissue were generally higher at the large river sites than at the smaller tributary sites. Concentrations of chlordane-related compounds in fish tissue were higher at sites from more urbanized basins than at sites from predominately agriculture and forested basins. Concentrations of the DDT related compounds were undifferentiated among sites comprising different land uses. Trace elements detected at all 14 sites included boron, copper, iron, manganese, molybdenum, selenium, and zinc. Trace elements detected at 10 or more sites included arsenic, mercury, silver, strontium, and vanadium. Antimony, beryllium, and uranium were not detected at any site.

Spatial characterization, risk assessment, and statistical source identification of the dissolved trace elements in the Ganjiang River-feeding tributary of the Poyang Lake, China.

PubMed

Zhang, Hua; Jiang, Yinghui; Wang, Min; Wang, Peng; Shi, Guangxun; Ding, Mingjun

2017-01-01

Surface water samples were collected from 20 sampling sites throughout the Ganjiang River during pre-monsoon, monsoon, and post-monsoon seasons, and the concentrations of dissolved trace elements were determined by inductively coupled plasma-mass spectrometry (ICP-MS) for the spatial and seasonal variations, risk assessment, source identification, and categorization for risk area. The result demonstrated that concentrations of the elements exhibited significant seasonality. The high total element concentrations were detected at sites close to the intensive mining and urban activities. The concentrations of the elements were under the permissible limits as prescribed by related standards with a few exceptions. The most of heavy metal pollution index (HPI) values were lower than the critical index limit, indicating the basically clean water used as habitat for aquatic life. As was identified as the priority pollutant of non-carcinogenic and carcinogenic concerns, and the inhabitants ingesting the surface water at particular site might be subjected to the integrated health risks for exposure to the mixed trace elements. Multivariate statistical analyses confirmed that Zn, As, Cd, and Tl were derived from mining and urban activities; V, Cd, and Pb exhibited mixed origin; and Co, Ni, and Cu mainly resulted from natural processes. Three categorized risk areas corresponded to high, moderate, and low risks, respectively. As a whole, the upstream of the Ganjiang River was identified as the high-risk area relatively.

Form drag in rivers due to small-scale natural topographic features: 1. Regular sequences

USGS Publications Warehouse

Kean, J.W.; Smith, J.D.

2006-01-01

Small-scale topographic features are commonly found on the boundaries of natural rivers, streams, and floodplains. A simple method for determining the form drag on these features is presented, and the results of this model are compared to laboratory measurements. The roughness elements are modeled as Gaussian-shaped features defined in terms of three parameters: a protrusion height, H; a streamwise length scale, ??; and a spacing between crests, ??. This shape is shown to be a good approximation to a wide variety of natural topographic bank features. The form drag on an individual roughness element embedded in a series of identical elements is determined using the drag coefficient of the individual element and a reference velocity that includes the effects of roughness elements further upstream. In addition to calculating the drag on each element, the model determines the spatially averaged total stress, skin friction stress, and roughness height of the boundary. The effects of bank roughness on patterns of velocity and boundary shear stress are determined by combining the form drag model with a channel flow model. The combined model shows that drag on small-scale topographic features substantially alters the near-bank flow field. These methods can be used to improve predictions of flow resistance in rivers and to form the basis for fully predictive (no empirically adjusted parameters) channel flow models. They also provide a foundation for calculating the near-bank boundary shear stress fields necessary for determining rates of sediment transport and lateral erosion.

Major factors influencing the elemental composition of surface estuarine sediments: the case of 15 estuaries in Portugal.

PubMed

Mil-Homens, M; Vale, C; Raimundo, J; Pereira, P; Brito, P; Caetano, M

2014-07-15

Upper sediments (0-5 cm) were sampled in 94 sites of water bodies of the fifteen Portuguese estuaries characterized by distinct settings of climate, topography and lithology, and marked by diverse anthropogenic pressures. Confined areas recognized as highly anthropogenic impacted, as well as areas dominated by erosion or frequently dredged were not sampled. Grain size, organic carbon (Corg), Al and trace elements (As, Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn) were determined. Normalisation of trace element concentrations to Al and Corg, correlations between elements and Principal Component Analysis (PCA) allowed identifying elemental associations and the relevance of grain-size, lithology and anthropogenic inputs on sediment chemical composition. Whereas grain-size is the dominant effect for the majority of the studied estuaries, the southern estuaries Mira, Arade and Guadiana are dominated by specific lithologies of their river basins, and anthropogenic effects are identified in Ave, Leça, Tagus and Sado. This study emphasizes how baseline values of trace elements in sediments may vary within and among estuarine systems. Copyright © 2014 Elsevier Ltd. All rights reserved.

Water-quality characteristics and ground water quantity of the Fraser River Watershed, Grand County, Colorado, 1998-2001

USGS Publications Warehouse

Bauch, Nancy J.; Bails, Jeffrey B.

2004-01-01

The U.S. Geological Survey, in cooperation with the Grand County Board of County Commissioners, conducted a 4-year study to assess ground- and surface-water-quality conditions and ground-water quantity in the 302-square-mile Fraser River watershed in north-central Colorado. The Fraser River flows north about 28 miles from the headwaters near the Continental Divide, through the towns of Winter Park, Fraser, Tabernash, and Granby, and is one of the major tributaries to the Upper Colorado River. Increasing urban development, as well as the seasonal influx of tourists, is placing more demands on the water resources in the Fraser River watershed. A ground-water sampling network of 11 wells was established to represent different aquifer systems (alluvial, Troublesome Formation, Precambrian granite), land uses (urban, nonurban), and areas with or without individual septic disposal system use. The well network was sampled for ground-water quality on a semiannual basis from August 1998 through September 2001. The sampling included field properties and the collection of water samples for analysis of major ions, trace elements, nutrients, dissolved organic carbon, bacteria, methylene blue active substances, and radon-222. One surface-water site, on the Fraser River just downstream from the town of Tabernash, Colorado, was sampled bimonthly from August 1998 through September 2001 to assess the cumulative effects of natural and human processes on water quality in the upper part of the Fraser River watershed. Surface-water-quality sampling included field properties and the collection of water-quality samples for analysis of major ions, trace elements, nutrients, organic carbon, and bacteria. Ground water was a calcium-bicarbonate type water and is suitable as a drinking-water, domestic, municipal, industrial, and irrigation source. In general, no widespread ground-water-quality problems were indicated. All pH values and concentrations of dissolved solids, chloride, fluoride, sulfate, nitrite, and nitrate in the ground-water samples met or were substantially less than U.S. Environmental Protection Agency drinking-water standards and health advisories or State of Colorado water-quality standards. Federal standards for turbidity and concentrations of iron, manganese, methylene blue active substances, and radon-222 were not met in water samples from at least one well. The only ground-water-quality concern assessed by this study is radon-222, which was detected in all radon- analyzed samples from 10 wells at levels exceeding the proposed U.S. Environmental Protection Agency drinking-water standard of 300 picocuries per liter. Concentrations of chloride, magnesium, and sulfate were statistically different (higher) in ground-water samples from wells completed in the alluvial aquifer, urbanized areas, and areas with individual septic disposal system use than those from wells completed in the Troublesome Formation, nonurban areas, and areas without individual septic disposal system use. Dissolved organic carbon concentrations were statistically higher in ground-water samples from wells completed in the alluvial aquifer and areas without individual septic disposal system use than those from wells completed in the Troublesome Formation and areas with individual septic disposal system use. Differences in dissolved organic-carbon concentrations between the latter category and areas without septic systems likely had no environmental significance. Surface water at the site Fraser River below Crooked Creek at Tabernash was a calcium-bicarbonate type water and is suitable as a drinking-water, residential, commercial, and irrigation resource. All pH values and concentrations of dissolved oxygen were within the State of Colorado instream water-quality standards, and all concentrations of chloride, sulfate, iron, manganese, un-ionized ammonia, nitrite, nitrate, and fecal coliform bacteria met State standards. Seasonal changes in the values or conc

Occurrence and transport of total mercury and methyl mercury in the Sacramento River Basin, California

USGS Publications Warehouse

Domagalski, Joseph L.

1999-01-01

Mercury poses a water-quality problem for California's Sacramento River, a large river with a mean annual discharge of over 650 m3/s. This river discharges into the San Francisco Bay, and numerous fish species of the bay and river contain mercury levels high enough to affect human health if consumed. Two possible sources of mercury are the mercury mines in the Coast Ranges and the gold mines in the Sierra Nevada. Mercury was once mined in the Coast Ranges, west of the Sacramento River, and used to process gold in the Sierra Nevada, east of the river. The mineralogy of the Coast Ranges mercury deposits is mainly cinnabar (HgS), but elemental mercury was used to process gold in the Sierra Nevada. Residual mercury from mineral processing in the Sierra Nevada is mainly in elemental form or in association with oxide particles or organic matter and is biologically available. Recent bed-sediment sampling, at sites below large reservoirs, showed elevated levels of total mercury (median concentration 0.28 ??g/g) in every large river (the Feather, Yuba, Bear, and American rivers) draining the Sierra Nevada gold region. Monthly sampling for mercury in unfiltered water shows relatively low concentrations during the nonrainy season in samples collected throughout the Sacramento River Basin, but significantly higher concentrations following storm-water runoff. Measured concentrations, following storm-water runoff, frequently exceeded the state of California standards for the protection of aquatic life. Results from the first year of a 2-year program of sampling for methyl mercury in unfiltered water showed similar median concentrations (0.1 ng/l) at all sampling locations, but with apparent high seasonal concentrations measured during autumn and winter. Methyl mercury concentrations were not significantly higher in rice field runoff water, even though rice production involves the creation of seasonal wetlands: higher rates of methylation are known to occur in stagnant wetland environments that have high dissolved carbon.Mercury poses a water-quality problem for California's Sacramento River, a large river with a mean annual discharge of over 650 m3/s. This river discharges into the San Francisco Bay, and numerous fish species of the bay and river contain mercury levels high enough to affect human health if consumed. Two possible sources of mercury are the mercury mines in the Coast Ranges and the gold mines in the Sierra Nevada. Mercury was once mined in the Coast Ranges, west of the Sacramento River, and used to process gold in the Sierra Nevada east of the river. The mineralogy of the Coast Ranges mercury deposits is mainly cinnabar (HgS), but elemental mercury was used to process gold in the Sierra Nevada. Residual mercury from mineral processing in the Sierra Nevada is mainly in elemental form or in association with oxide particles or organic matter and is biologically available. Recent bed-sediment sampling, at sites below large reservoirs, showed elevated levels of total mercury (median concentration 0.28 ??g/g) in every large river (the Feather, Yuba, Bear, and American rivers) draining the Sierra Nevada gold region. Monthly sampling for mercury in unfiltered water shows relatively low concentrations during the nonrainy season in samples collected throughout the Sacramento River Basin, but significantly higher concentrations following storm-water runoff. Measured concentrations, following storm-water runoff, frequently exceeded the state of California standards for the protection of aquatic life. Results from the first year of a 2-year program of sampling for methyl mercury in unfiltered water showed similar median concentrations (0.1 ng/l) at all sampling locations, but with apparent high seasonal concentrations measured during autumn and winter. Methyl mercury concentrations were not significantly higher in rice field runoff water, even though rice production involves the creation of seasonal wetlands: higher rates of methylation a

Modelling river bank retreat by combining fluvial erosion, seepage and mass failure

NASA Astrophysics Data System (ADS)

Dapporto, S.; Rinaldi, M.

2003-04-01

Streambank erosion processes contribute significantly to the sediment yielded from a river system and represent an important issue in the contexts of soil degradation and river management. Bank retreat is controlled by a complex interaction of hydrologic, geotechnical, and hydraulic processes. The capability of modelling these different components allows for a full reconstruction and comprehension of the causes and rates of bank erosion. River bank retreat during a single flow event has been modelled by combining simulation of fluvial erosion, seepage, and mass failures. The study site, along the Sieve River (Central Italy), has been subject to extensive researches, including monitoring of pore water pressures for a period of 4 years. The simulation reconstructs fairly faithfully the observed changes, and is used to: a) test the potentiality and discuss advantages and limitations of such type of methodology for modelling bank retreat; c) quantify the contribution and mutual role of the different processes determining bank retreat. The hydrograph of the event is divided in a series of time steps. Modelling of the riverbank retreat includes for each step the following components: a) fluvial erosion and consequent changes in bank geometry; b) finite element seepage analysis; c) stability analysis by limit equilibrium method. Direct fluvial shear erosion is computed using empirically derived relationships expressing lateral erosion rate as a function of the excess of shear stress to the critical entrainment value for the different materials along the bank profile. Lateral erosion rate has been calibrated on the basis of the total bank retreat measured by digital terrestrial photogrammetry. Finite element seepage analysis is then conducted to reconstruct the saturated and unsaturated flow within the bank and the pore water pressure distribution for each time step. The safety factor for mass failures is then computed, using the pore water pressure distribution obtained by the seepage analysis, and the geometry of the upper bank is modified in case of failure.

Estimating the Submarine Groundwater Discharge Flux of Rare Earth Elements to the Indian River Lagoon, Fl, USA, Using the 1-D Vertical - Flow Equation

NASA Astrophysics Data System (ADS)

Chevis, D. A.; Johannesson, K. H.; Burdige, D.; Cable, J. E.; Martin, J. B.

2013-12-01

Understanding the sources and sinks of trace elements like the rare earth elements (REE) in the oceans has important implications for quantifying their global geochemical cycles, their application as paleoceanographic tracers, and in discerning the geochemical reactions that mobilize, sequester, and fractionate REEs in the environment. This understanding is critical for neodymium (Nd) because radiogenic Nd isotopes are commonly used in paleoceanographic studies over glacial-interglacial to million year time scales. The submarine groundwater discharge (SGD) flux of each REE for the Indian River Lagoon, Fl, USA, was calculated using a modified form of the 1-dimensional vertical-flow equation that accounts for diffusion, advection, and non-local mass transfer processes. The SGD REE flux is comprised of two sources: a near shore, heavy REE (HREE) enriched advective source chiefly composed of terrestrial SGD, and a light REE (LREE) and middle REE (MREE) enriched source that originates from reductive dissolution of Fe (III) oxides/hydroxides in the subterranean estuary. This SGD flux mixture of REE sources is subsequently transported by groundwater seepage and bioirrigation to the overlying lagoon water column. The total SGD flux of REEs reveals that the subterranean estuary of the Indian River Lagoon is a source for LREE and MREEs, and a sink for the HREEs, to the local coastal ocean. The calculated SGD flux of Nd presented in this study is estimated at 7.69×1.02 mmol/day, which is roughly equivalent to the effective local river flux to the Indian River Lagoon. Although our re-evaluated SGD flux of Nd to the Indian River Lagoon is lower than estimates in our previous work, it nonetheless represents a substantial input to the coastal ocean.

Dissolved indium and rare earth elements in three Japanese rivers and Tokyo Bay: Evidence for anthropogenic Gd and In

NASA Astrophysics Data System (ADS)

Nozaki, Yoshiyuki; Lerche, Dorte; Alibo, Dia Sotto; Tsutsumi, Makoto

2000-12-01

New data on the dissolved (<0.04 μm) rare earth elements (REEs) and In in the Japanese Ara, Tama, and Tone river-estuaries and Tokyo Bay are presented. Unique shale-normalized REE patterns with a distinct positive Gd anomalies and a strong heavy-REE enrichment were seen throughout the data. The dissolved Gd anomaly is caused by local anthropogenic input mainly due to recent use of Gado-pentetic acid as a medical agent for magnetic resonance imaging (MRI) in hospitals. The heavy-REE enrichment may be attributed to fractionation during weathering and transport in the upstream of the rivers, and only partially to removal of light- and middle-REE enriched river colloids by the use of a new ultrafiltration technique. Dissolved In concentrations in the Japanese rivers are extraordinarily high as compared to those in the pristine Chao Phraya river of Thailand reported elsewhere (Nozaki et al., in press). Like Gd, the high dissolved In in the study area can also be ascribed to recent use of In-containing organic compound, In(DTPA) 2- in medical diagnosis. Thus, in the highly populated and industrialized area, dissolved heavy metal concentrations in rivers and estuaries may be significantly perturbed by human activities and the fate of those anthropogenic soluble substances in the marine environment needs to be investigated further.

Abundance, distribution and bioavailability of major and trace elements in surface sediments from the Cai River estuary and Nha Trang Bay (South China Sea, Vietnam)

NASA Astrophysics Data System (ADS)

Koukina, S. E.; Lobus, N. V.; Peresypkin, V. I.; Dara, O. M.; Smurov, A. V.

2017-11-01

Major (Si, Al, Fe, Ti, Mg, Ca, Na, K, S, P), minor (Mn) and trace (Li, V, Cr, Co, Ni, Cu, Zn, As, Sr, Zr, Mo, Cd, Ag, Sn, Sb, Cs, Ba, Hg, Pb, Bi and U) elements, their chemical forms and the mineral composition, organic matter (TOC) and carbonates (TIC) in surface sediments from the Cai River estuary and Nha Trang Bay were first determined along the salinity gradient. The abundance and ratio of major and trace elements in surface sediments are discussed in relation to the mineralogy, grain size, depositional conditions, reference background and SQG values. Most trace-element contents are at natural levels and are derived from the composition of rocks and soils in the watershed. A severe enrichment of Ag is most likely derived from metal-rich detrital heavy minerals such as Ag-sulfosalts. Along the salinity gradient, several zones of metal enrichment occur in surface sediments because of the geochemical fractionation of the riverine material. The parts of actually and potentially bioavailable forms (isolated by four single chemical reagent extractions) are most elevated for Mn and Pb (up to 36% and 32% of total content, respectively). The possible anthropogenic input of Pb in the region requires further study. Overall, the most bioavailable parts of trace elements are associated with easily soluble amorphous Fe and Mn oxyhydroxides. The sediments are primarily enriched with bioavailable metal forms in the riverine part of the estuary. Natural (such as turbidities) and human-generated (such as urban and industrial activities) pressures are shown to influence the abundance and speciation of potential contaminants and therefore change their bioavailability in this estuarine system.

Towards a National Hydrological Forecasting system for Canada : Lessons Learned from the Great Lakes and St. Lawrence Prediction System

NASA Astrophysics Data System (ADS)

Fortin, V.; Durnford, D.; Gaborit, E.; Davison, B.; Dimitrijevic, M.; Matte, P.

2016-12-01

Environment and Climate Change Canada has recently deployed a water cycle prediction system for the Great Lakes and St. Lawrence River. The model domain includes both the Canadian and US portions of the watershed. It provides 84-h forecasts of weather elements, lake level, lake ice cover and surface currents based on two-way coupling of the GEM numerical weather prediction (NWP) model with the NEMO ocean model. Streamflow of all the major tributaries of the Great Lakes and St. Lawrence River are estimated by the WATROUTE routing model, which routes the surface runoff forecasted by GEM's land-surface scheme and assimilates streamflow observations where available. Streamflow forecasts are updated twice daily and are disseminated through an OGC compliant web map service (WMS) and a web feature service (WFS). In this presentation, in addition to describing the system and documenting its forecast skill, we show how it is being used by clients for various environmental prediction applications. We then discuss the importance of two-way coupling, land-surface and hillslope modelling and the impact of horizontal resolution on hydrological prediction skill. In the second portion of the talk, we discuss plans for implementing a similar system at the national scale, using what we have learned in the Great Lakes and St. Lawrence watershed. Early results obtained for the headwaters of the Saskatchewan River as well as for the whole Nelson-Churchill watershed are presented.

A Modern Analog to the Depositional Age Problem: Zircon and Apatite Fission Track and U-Pb Age Distributions by LA-ICP-MS

NASA Astrophysics Data System (ADS)

Donelick, H. M.; Donelick, M. B.; Donelick, R. A.

2012-12-01

Sand from three river systems in North Idaho (Snake River near Lewiston, Clearwater River near Lewiston and the Salmon River near White Bird) and two regional ash fall events (Mt. Mazama and Mt. St. Helens) were collected for zircon U-Pb detrital age analysis. Up to 120 grains of zircon per sample were ablated using a Resonetics M-50 193 nm ArF Excimer laser ablation (LA) system and the Pb, Th, and U isotopic signals were quantified using an Agilent 7700x quadrupole inductively coupled plasma-mass spectrometer (ICP-MS). Isotopic signals for major, minor, and trace elements, including all REEs, were also monitored. The youngest zircon U-Pb ages from the river samples were approximately 44 Ma; Cenozoic Idaho Batholith and Precambrian Belt Supergroup ages were well represented. Significant common Pb contamination of the Clearwater River sample (e.g., placer native Cu was observed in the sample) precluded detailed analysis of the zircon U-Pb ages but no interpretable ages <44 Ma were observed. Interestingly, not one of the river samples yielded zircon U-Pb ages near 0 Ma, despite all three catchment areas having received significant ash from Mt. St. Helens in 1980, and Mount Mazama 7,700 years ago, and no doubt other events during the Quaternary. Work currently in progress seeks to address bias against near 0 Ma ages in the catchment areas due to: a) small, local ash fall grain sizes and b) overwhelming number of older grains relative to the ash fall grains. Data from Mt. St. Helens ash from several localities near the mountain (Toutle River and Maple Flats, WA) and several far from the mountain (Spokane, WA; Princeton, ID; Kalispell, MT) and Mt. Mazama ash fall deposits near Lewiston, ID and Spokane, WA will be presented to address these possibilities. Additionally, fission track and U-Pb ages from apatites collected from these river and ash fall samples will also be shown to help constrain the problem.

Heavy Metal Pollution in a Soil-Rice System in the Yangtze River Region of China.

PubMed

Liu, Zhouping; Zhang, Qiaofen; Han, Tiqian; Ding, Yanfei; Sun, Junwei; Wang, Feijuan; Zhu, Cheng

2015-12-22

Heavy metals are regarded as toxic trace elements in the environment. Heavy metal pollution in soil or rice grains is of increasing concern. In this study, 101 pairs of soil and rice samples were collected from the major rice-producing areas along the Yangtze River in China. The soil properties and heavy metal (i.e., Cd, Hg, Pb and Cr) concentrations in the soil and rice grains were analyzed to evaluate the heavy metal accumulation characteristics of the soil-rice systems. The results showed that the Cd, Hg, Pb and Cr concentrations in the soil ranged from 0.10 to 4.64, 0.01 to 1.46, 7.64 to 127.56, and 13.52 to 231.02 mg·kg(-)¹, respectively. Approximately 37%, 16%, 60% and 70% of the rice grain samples were polluted by Cd, Hg, Pb, and Cr, respectively. The degree of heavy metal contamination in the soil-rice systems exhibited a regional variation. The interactions among the heavy metal elements may also influence the migration and accumulation of heavy metals in soil or paddy rice. The accumulation of heavy metals in soil and rice grains is related to a certain extent to the pH and soil organic matter (SOM). This study provides useful information regarding heavy metal accumulation in soil to support the safe production of rice in China. The findings from this study also provide a robust scientific basis for risk assessments regarding ecological protection and food safety.

Heavy Metal Pollution in a Soil-Rice System in the Yangtze River Region of China

PubMed Central

Liu, Zhouping; Zhang, Qiaofen; Han, Tiqian; Ding, Yanfei; Sun, Junwei; Wang, Feijuan; Zhu, Cheng

2015-01-01

Heavy metals are regarded as toxic trace elements in the environment. Heavy metal pollution in soil or rice grains is of increasing concern. In this study, 101 pairs of soil and rice samples were collected from the major rice-producing areas along the Yangtze River in China. The soil properties and heavy metal (i.e., Cd, Hg, Pb and Cr) concentrations in the soil and rice grains were analyzed to evaluate the heavy metal accumulation characteristics of the soil-rice systems. The results showed that the Cd, Hg, Pb and Cr concentrations in the soil ranged from 0.10 to 4.64, 0.01 to 1.46, 7.64 to 127.56, and 13.52 to 231.02 mg·kg−1, respectively. Approximately 37%, 16%, 60% and 70% of the rice grain samples were polluted by Cd, Hg, Pb, and Cr, respectively. The degree of heavy metal contamination in the soil-rice systems exhibited a regional variation. The interactions among the heavy metal elements may also influence the migration and accumulation of heavy metals in soil or paddy rice. The accumulation of heavy metals in soil and rice grains is related to a certain extent to the pH and soil organic matter (SOM). This study provides useful information regarding heavy metal accumulation in soil to support the safe production of rice in China. The findings from this study also provide a robust scientific basis for risk assessments regarding ecological protection and food safety. PMID:26703698

Late Quaternary Stratigraphic Architecture of the Santee River Delta, South Carolina, U.S.A.

NASA Astrophysics Data System (ADS)

Long, J. H.; Hanebuth, T. J. J.

2017-12-01

The Santee River of South Carolina is the second largest river in terms of drainage area and discharge in the eastern United States and forms the only river-fed delta on the country's Atlantic coast. Significant anthropogenic modifications to this system date back to the early 18th century with the extensive clearing of coastal wetland forest for rice cultivation. In the 1940's the construction of large upstream dams permanently altered the discharge of the Santee River. These modifications are likely documented within the sedimentary record of the Santee Delta as episodes of major environmental changes. The Piedmont-sourced Santee River system incised its valley to an estimated depth of 20 m during lower glacial sea level. Sedimentation during the subsequent Holocene transgression and highstand has filled much of this accommodation. The Santee system remains largely under-investigated with only a handful of studies completed in the 1970's and 1980's based on sediment cores and cuttings. Through the use of high frequency seismic profiles (0.5 - 24 kHz), sediment cores, and other field data, we differentiate depositional units, architectural elements, and bounding surfaces with temporal and spatial distributions reflecting the changing morphodynamics of this complex system at multiple scales. These lithosomes are preserved within both modern inshore and offshore settings and were deposited within a range of paralic environments by processes active on fluvial/estuarine bars, floodplains, marshes, tidal flats, spits, beach ridges, and in backbarrier settings. They are bound by surfaces ranging from diastems to regional, polygenetic, low-angle and channel-form erosional surfaces. Detailed descriptions of cores taken from within the upper 6 m of the modern lower delta plain document heterolithic, mixed-energy, organic-rich, largely aggradational sedimentation dating back to at least 5 ka cal BP. Offshore, stacked, sand-rich, progradational packages sit atop heterolithic paleochannel-fill successions contained within a framework of regionally extensive, erosional bounding surfaces. Ongoing work focuses on continued data acquisition and integration of inshore and offshore data sets into a coherent model for the Holocene evolution of the Santee Delta.

Water-quality investigation, Salinas River, California

USGS Publications Warehouse

Irwin, G.A.

1976-01-01

Concentrations of dissolved solids in the Salinas River, California, are variable and range from 164 to 494 milligrams per liter near Bradley and from 170 to 1,090 milligrams per liter near Spreckels. Higher concentrations near Spreckels are caused mainly by sewage inflow about 150 feet (50 meters) upstream. Concentrations of nitrogen, phosphorus, total organic carbon, selected trace elements, and pesticides also generally increase downstream from Pozo to Spreckels and are related to sewage effluent; however, high concentrations occur elsewhere in the river. Specific conductance and water discharge regression results indicate that relations were all significant at the 1-percent probability level at Paso Robles, Bradley, and Spreckels with the explained variance ranging from 66 to 74 percent. Concentations of nitrogen, phosphorus, total organic carbon, and trace elements are only infrequently related to water discharge. (Woodard-USGS)

Nutrient (N, P) budgets for the Red River basin (Vietnam and China)

NASA Astrophysics Data System (ADS)

Quynh, Le Thi Phuong; Billen, Gilles; Garnier, Josette; ThéRy, Sylvain; FéZard, CéDric; Minh, Chau Van

2005-06-01

In order to examine the degree of human-induced alteration of the nitrogen and phosphorus cycles at the scale of a tropical watershed of regional dimension, the budgets of these two elements were estimated in the four main sub-basins (Da, Lo, Thao, and Delta) of the Red River system (156 448 km2, Vietnam and China). The four sub-basins differ widely in population density (from 101 inhabitants km-2 in the upstream basins to more than 1000 inhabitants km-2 in the delta), land use, and agricultural practices. In terms of agricultural production, on the one hand, and consumption of food and feed on the other, the upstream sub-basins are autotrophic systems, exporting agricultural goods, while the delta is a heterotrophic system, depending on agricultural goods imports. The budget of the agricultural soils reveals great losses of nitrogen, mostly attributable to denitrification in rice paddy fields and of phosphorus, mostly caused by erosion. The budget of the drainage network shows high retention/elimination of nitrogen (from 62 to 77% in the upstream basins and 59% in the delta), and of phosphorus, with retention rates as high as 80% in the Da and Lo sub-basins which have large reservoirs in their downstream course (Hoa Binh on the Da and Thac Ba on the Lo). The total specific delivery estimated at the outlet of the whole Red River System is 855 kg km-2 yr-1 total N and 325 kg km-2 yr-1 total P. Nitrogen rather than phosphorus seems to be the potential limiting factor of algal growth in the plume of the Red River in Tonkin Bay.

Major ions, nutrients, and trace elements in the Mississippi River near Thebes, Illinois, July through September 1993

USGS Publications Warehouse

Taylor, Howard E.; Antweiler, Ronald C.; Brinton, Terry I.; Roth, David A.; Moody, John A.

1994-01-01

Extensive flooding in the upper Mississippi River Basin during summer 1993 had a significant effect on the water quality of the Mississippi River. To evaluate the change in temporal distribution and transport of dissolved constituents in the Mississippi River, six water samples were collected by a discharge-weighted method from July through September 1993 near Thebes, Illinois. Sampling at this location provided water-quality information from the upper Mississippi, the Missouri, and the Illinois River Basins. Dissolved major constituents that were analyzed in each of the samples included bicarbonate, calcium (Ca), carbonate (C03), chloride (Cl), dissolved organic carbon, magnesium (Mg), potassium (K), silica NOD, sodium (Na), and sulfate (S04). Dissolved nutrients included ammonium ion (NH4), nitrate (N03), nitrite (N02), and orthophosphate (P04) . Dissolved trace elements included aluminum (Al), arsenic (As), barium (Ba), boron (B), beryllium (Be), bromide (Br), cadmium (Cd), chromium (Cr), cobalt, (Co), copper (Cu), fluoride (F), iron (Fe), lead, lithium (Li), manganese (Mn), mercury (Hg), molybdenum (Mo), nickel (Ni), strontium (Sr), thallium, uranium (U), vanadium (V), and zinc (Zn). Other physical properties of water that were measured included specific conductance, pH and suspended-sediment concentration (particle size, less than 63 micrometers). Results of this study indicated that large quantities of dissolved constituents were transported through the river system. Generally, pH, alkalinity, and specific conductance and the concentrations of B, Br, Ca, Cl, Cr, K, Li, Mg, Mo, Na, S04, Sr, U, and V increased as water discharge decreased, while concentrations of F, Hg, and suspended sediment sharply decreased as water discharge decreased after the crest of the flood. Concentrations of other constituents, such as Al, As, Ba, Be, Co, Cu, Ni, N03, N02, NH4, P04, and Si02, varied with time as discharge decreased after the crest of the flood. For most constituents, the load transported during floods generally is much greater than that transported during low-flow conditions. How ever, for Cd, Cr, Fe, Mn, V, and Zn, loads increased substantially as water discharge decreased after the crest of the flood.

Facies architecture of the fluvial Missão Velha Formation (Late Jurassic-Early Cretaceous), Araripe Basin, Northeast Brazil: paleogeographic and tectonic implications

NASA Astrophysics Data System (ADS)

Fambrini, Gelson Luís; Neumann, Virgínio Henrique M. L.; Menezes-Filho, José Acioli B.; Da Silva-Filho, Wellington F.; De Oliveira, Édison Vicente

2017-12-01

Sedimentological analysis of the Missão Velha Formation (Araripe Basin, northeast Brazil) is the aim of this paper through detailed facies analysis, architectural elements, depositional systems and paleocurrent data. The main facies recognized were: (i) coarse-grained conglomeratic sandstones, locally pebbly conglomerates, with abundant silicified fossil trunks and several large-to-medium trough cross-stratifications and predominantly lenticular geometry; (ii) lenticular coarse-to-medium sandstones with some granules, abundant silicified fossil wood, and large-to-medium trough cross-stratifications, cut-and fill features and mud drapes on the foresets of cross-strata, (iii) poorly sorted medium-grained sandstones with sparse pebbles and with horizontal stratification, (iv) fine to very fine silty sandstones, laminated, interlayered with (v) decimetric muddy layers with horizontal lamination and climbing-ripple cross-lamination. Nine architectural elements were recognized: CH: Channels, GB: Gravel bars and bed forms, SB: Sand bars and bedforms, SB (p): sand bedform with planar cross-stratification, OF: Overbank flow, DA: Downstream-accretion macroforms, LS: Laminated sandsheet, LA: Lateral-accretion macroforms and FF: Floodplain fines. The lithofacies types and facies associations were interpreted as having been generated by alluvial systems characterized by (i) high energy perennial braided river systems and (ii) ephemeral river systems. Aeolian sand dunes and sand sheets generated by the reworking of braided alluvial deposits can also occur. The paleocurrent measurements show a main dispersion pattern to S, SE and SW, and another to NE/E. These features imply a paleodrainage flowing into the basins of the Recôncavo-Tucano-Jatobá.

DETERMINATION OF ELEMENTAL COMPOSITIONS BY HIGH RESOLUTION MASS SPECTROMETRY WITHOUT MASS CALIBRANTS

EPA Science Inventory

The Environmental Sciences Division (ESD) is investigating the possibility that pharmaceuticals and their metabolites are entering rivers and lakes via sewage treatment effluent. A recent review indicated that some of these compounds are present and have been found in rivers. C...

Evaluation of an alternate method for sampling benthic macroinvertebrates in low-gradient streams sampled as part of the National Rivers and Streams Assessment.

PubMed

Flotemersch, Joseph E; North, Sheila; Blocksom, Karen A

2014-02-01

Benthic macroinvertebrates are sampled in streams and rivers as one of the assessment elements of the US Environmental Protection Agency's National Rivers and Streams Assessment. In a 2006 report, the recommendation was made that different yet comparable methods be evaluated for different types of streams (e.g., low gradient vs. high gradient). Consequently, a research element was added to the 2008-2009 National Rivers and Streams Assessment to conduct a side-by-side comparison of the standard macroinvertebrate sampling method with an alternate method specifically designed for low-gradient wadeable streams and rivers that focused more on stream edge habitat. Samples were collected using each method at 525 sites in five of nine aggregate ecoregions located in the conterminous USA. Methods were compared using the benthic macroinvertebrate multimetric index developed for the 2006 Wadeable Streams Assessment. Statistical analysis did not reveal any trends that would suggest the overall assessment of low-gradient streams on a regional or national scale would change if the alternate method was used rather than the standard sampling method, regardless of the gradient cutoff used to define low-gradient streams. Based on these results, the National Rivers and Streams Survey should continue to use the standard field method for sampling all streams.

The Contribution of the Future SWOT Mission to Improve Simulations of River Stages and Stream-Aquifer Interactions at Regional Scale

NASA Astrophysics Data System (ADS)

Saleh, Firas; Filipo, Nicolas; Biancamaria, Sylvain; Habets, Florence; Rodriguez, Enersto; Mognard, Nelly

2013-09-01

The main objective of this study is to provide a realistic simulation of river stage in regional river networks in order to improve the quantification of stream-aquifer exchanges and better assess the associated aquifer responses that are often impacted by the magnitude and the frequency of the river stage fluctuations. This study extends the earlier work to improve the modeling of the Seine basin with a focus on simulating the hydrodynamics behavior of the Bassée alluvial wetland, a 120 km reach of the Seine River valley located south- east of Paris. The Bassée is of major importance for the drinking-water supply of Paris and surroundings, in addition to its particular hydrodynamic behavior due to the presence of a number of gravels. In this context, the understanding of stream-aquifer interactions is required for water quantity and quality preservation. A regional distributed process-based hydro(geo)logical model, Eau-Dyssée, is used. It aims at the integrated modeling of the hydrosystem to manage the various elements involved in the quantitative and qualitative aspects of water resources. Eau-Dyssée simulates pseudo 3D flow in aquifer systems solving the diffusivity equation with a finite difference numerical scheme. River flow is simulated with a Muskingum model. In addition to the in-stream discharge, a river stage estimate is needed to calculate the water exchange at the stream-aquifer interface using a conductance model. In this context, the future SWOT mission and its high-spatial resolution imagery can provide surface water level measurements at the regional scale that will permit to better characterize the Bassée complex hydro(geo)logical system and better assess soil water content. Moreover, the Bassée is considered as a potential target for the framework of the AirSWOT airborne campaign in France, 2013.

Trace levels of sewage effluent are sufficient to increase class 1 integron prevalence in freshwater biofilms without changing the core community.

PubMed

Lehmann, Katja; Bell, Thomas; Bowes, Michael J; Amos, Gregory C A; Gaze, Will H; Wellington, Elizabeth M H; Singer, Andrew C

2016-12-01

Most river systems are impacted by sewage effluent. It remains unclear if there is a lower threshold to the concentration of sewage effluent that can significantly change the structure of the microbial community and its mobile genetic elements in a natural river biofilm. We used novel in situ mesocosms to conduct replicated experiments to study how the addition of low-level concentrations of sewage effluent (nominally 2.5 ppm) affects river biofilms in two contrasting Chalk river systems, the Rivers Kennet and Lambourn (high/low sewage impact, respectively). 16S sequencing and qPCR showed that community composition was not significantly changed by the sewage effluent addition, but class 1 integron prevalence (Lambourn control 0.07% (SE ± 0.01), Lambourn sewage effluent 0.11% (SE ± 0.006), Kennet control 0.56% (SE ± 0.01), Kennet sewage effluent 1.28% (SE ± 0.16)) was significantly greater in the communities exposed to sewage effluent than in the control flumes (ANOVA, F = 5.11, p = 0.045) in both rivers. Furthermore, the difference in integron prevalence between the Kennet control (no sewage effluent addition) and Kennet sewage-treated samples was proportionally greater than the difference in prevalence between the Lambourn control and sewage-treated samples (ANOVA (interaction between treatment and river), F = 6.42, p = 0.028). Mechanisms that lead to such differences could include macronutrient/biofilm or phage/bacteria interactions. Our findings highlight the role that low-level exposure to complex polluting mixtures such as sewage effluent can play in the spread of antibiotic resistance genes. The results also highlight that certain conditions, such as macronutrient load, might accelerate spread of antibiotic resistance genes. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

Morphotectonics of the Jamini River basin, Bundelkhand Craton, Central India; using remote sensing and GIS technique

NASA Astrophysics Data System (ADS)

Prakash, K.; Mohanty, T.; Pati, J. K.; Singh, S.; Chaubey, K.

2017-11-01

Morphological and morphotectonic analyses have been used to obtain information that influence hydrographic basins, predominantly these are modifications of tectonic elements and the quantitative description of landforms. Discrimination of morphotectonic indices of active tectonics of the Jamini river basin consists the analyses of asymmetry factor, ruggedness number, basin relief, gradient, basin elongation ratio, drainage density analysis, and drainage pattern analysis, which have been completed for each drainage basin using remote sensing and GIS techniques. The Jamini river is one of the major tributaries of the Betwa river in central India. The Jamini river basin is divided into five subwatersheds viz. Jamrar, Onri, Sainam, Shahzad and Baragl subwatershed. The quantitative approach of watershed development of the Jamini river basin, and its four sixth (SW1-SW4) and one fifth (SW5) order subwatersheds, was carried out using Survey of India toposheets (parts of 54I, 54K, 54L, 54O, and 54P), Landsat 7 ETM+, ASTER (GDEM) data, and field data. The Jamini river has low bifurcation index which is a positive marker of tectonic imprint on the hydrographic network. The analyses show that the geomorphological progression of the study area was robustly influenced by tectonics. The analysis demonstrates to extensional tectonics system with the following alignments: NE-SW, NW-SE, NNE-SSW, ENE-WSW, E-W, and N-S. Three major trends are followed by lower order streams viz. NE-SW, NW-SE, and E-W directions which advocate that these tectonic trends were active at least up to the Late Pleistocene. The assessment of morphotectonic indices may be used to evaluate the control of active faults on the hydrographic system. The analysis points out westward tilting of the drainage basins with strong asymmetry in some reaches, marked elongation ratio of subwatersheds, and lower order streams having close alignment with lineaments (active faults). The study facilitated to considerate the function of active tectonism in the advancement of the basin.

Weathering processes and the composition of inorganic material transported through the orinoco river system, Venezuela and Colombia

USGS Publications Warehouse

Stallard, R.F.; Koehnken, L.; Johnsson, M.J.

1991-01-01

The composition of river-borne material in the Orinoco River system is related primarily to erosion regime, which in turn is related to tectonic setting; especially notable is the contrast between material derived from tectonically active mountain belts and that from stable cratonic regions. For a particular morpho-tectonic region, the compositional suites of suspended sediment, bed material, overback deposits, and dissolved phases are fairly uniform are are typically distinct from whose of other regions. For each region, a consistent set of chemical weathering reactions can be formulated to explain the composition of dissolved and solid loads. In developing these formulations, erosion on slopes and storage of solids in soils and alluvial sediments are important considerations. Compositionally verymature sediment is derived from areas of thick soils where erosion is transport limited and from areas where sediments are stored for extended periods of time in alluvial deposits. Compositionally immature sediments are derived from tectonically active mountain belts where erosion is weathering limited. Weathering-limited erosion also is important in the elevated parts of the Guayana Shield within areas of sleep topography. Compared to the mountain belts, sediments derived from elevated parts of the Shield are more mature. A greater degree of chemical weathering seems to be needed to erode the rock types typical of the Shield. The major-element chemistry and mineral composition of sediment delivered by the Orinoco River to the ocean are controlled by rivers that have their headwaters in mountain belts and cross the Llanos, a region of alluvial plains within the foreland basin. The composition of sediments in rivers that drain the Shield seems to be established primarily at the site of soil formation, whereas for rivers that drain the mountain belts, additional weathering occurs during s episodes of storage on alluvial plains as sediments are transported across the Llanos to the main stem of the Orinoco. After mixing into the main stem, there seems to be little subsequent alteration of sediment. ?? 1991.

Managing water quality under drought conditions in the Llobregat River Basin.

PubMed

Momblanch, Andrea; Paredes-Arquiola, Javier; Munné, Antoni; Manzano, Andreu; Arnau, Javier; Andreu, Joaquín

2015-01-15

The primary effects of droughts on river basins include both depleted quantity and quality of the available water resources, which can render water resources useless for human needs and simultaneously damage the environment. Isolated water quality analyses limit the action measures that can be proposed. Thus, an integrated evaluation of water management and quality is warranted. In this study, a methodology consisting of two coordinated models is used to combine aspects of water resource allocation and water quality assessment. Water management addresses water allocation issues by considering the storage, transport and consumption elements. Moreover, the water quality model generates time series of concentrations for several pollutants according to the water quality of the runoff and the demand discharges. These two modules are part of the AQUATOOL decision support system shell for water resource management. This tool facilitates the analysis of the effects of water management and quality alternatives and scenarios on the relevant variables in a river basin. This paper illustrates the development of an integrated model for the Llobregat River Basin. The analysis examines the drought from 2004 to 2008, which is an example of a period when the water system was quantitative and qualitatively stressed. The performed simulations encompass a wide variety of water management and water quality measures; the results provide data for making informed decisions. Moreover, the results demonstrated the importance of combining these measures depending on the evolution of a drought event and the state of the water resources system. Copyright © 2014 Elsevier B.V. All rights reserved.

The spatial relationship between human activities and C, N, P, S in soil based on landscape geochemical interpretation.

PubMed

Yu, Huan; He, Zheng-Wei; Kong, Bo; Weng, Zhong-Yin; Shi, Ze-Ming

2016-04-01

The development and formation of chemical elements in soil are affected not only by parent material, climate, biology, and topology factors, but also by human activities. As the main elements supporting life on earth system, the C, N, P, S cycles in soil have been altered by human activity through land-use change, agricultural intensification, and use of fossil fuels. The present study attempts to analyze whether and how a connection can be made between macroscopical control and microcosmic analysis, to estimate the impacts of human activities on C, N, P, S elements in soil, and to determine a way to describe the spatial relationship between C, N, P, S in soil and human activities, by means of landscape geochemical theories and methods. In addition, the disturbances of human activities on C, N, P, S are explored through the analysis of the spatial relationship between human disturbed landscapes and element anomalies, thereby determining the diversified rules of the effects. The study results show that the rules of different landscapes influencing C, N, P, S elements are diversified, and that the C element is closely related to city landscapes; furthermore, the elements N, P, and S are shown to be closely related to river landscapes; the relationships between mine landscapes and the elements C, N, P, S are apparent; the relationships between the elements C, N, P, S and road landscapes are quite close, which shows that road landscapes have significant effects on these elements. Therefore, the conclusion is drawn that the response mechanism analysis of human disturbance and soil chemical element aggregation is feasible, based on the landscape geochemical theories and methods. The spatial information techniques, such as remote sensing and geographic information systems, are effective for research on soil element migration.

Effects of urbanization and long-term rainfall on the occurrence of organic compounds and trace elements in reservoir sediment cores, streambed sediment, and fish tissue from the Santa Ana River basin, California, 1998

USGS Publications Warehouse

Burton, Carmen A.

2002-01-01

Organcochlorine compounds, semivolatile-organic compounds (SVOC), and trace elements were analyzed in reservoir sediment cores, streambed sediment, and fish tissue in the Santa Ana River Basin as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Three reservoirs were sampled in areas that have different degrees of urbanization. Streambed sediment and fish tissue collected at 12 sites were divided into two groups, urban and nonurban. More organochlorine compounds were detected in reservoir sediment cores, streambed sediment and fish tissue, and at higher concentrations at urban sites than at nonurban sites. At all sites, except West Street Basin, concentrations of organochlorine compounds were lower than the probable-effect concentration (PEC). At the highly urbanized West Street Basin, chlordane and p,p'-DDE exceeded the PEC throughout the historical record. The less stringent threshold-effect concentration (TEC) was exceeded for six compounds at eight sites. Most of the organochlorine compounds detected in streambed sediment and fish tissue were at urban sites on the Santa Ana River as opposed to its tributaries, suggesting accumulation and persistence in the river. More SVOCs were detected in reservoir sediment cores and streambed sediment, and at higher concentrations, at urban sites than at nonurban sites. At all the sites, except West Street Basin, concentrations of SVOCs were lower than the PEC. At West Street Basin, chrysene, pyrene, and total polycyclic-aromatic hydrocarbons exceeded the PEC throughout the historical record. The TEC was exceeded for 10 compounds at 3 sites. Most of the SVOCs were detected in streambed sediment at urban sites on tributaries to the Santa Ana River rather than the mainstem itself. The less frequent occurrence and lower concentrations in the Santa Ana River suggest that SVOCs are less persistent than organochlorine compounds, possibly as a result of volatization, gradation, or dilution. Most trace-element detections in reservoir sediment cores and streambed sediment were at urban sites, and the concentrations were generally higher than at nonurban sites. Lead and zinc exceeded their PECs at West Street Basin throughout the historical record; copper exceeded its PEC at Canyon Lake, an area of urban growth. The TEC was exceeded for 10 compounds at 11 sites. Frequency of detection and concentration did not differ between tributary and Santa Ana River sites, which may be attributed to the fact that trace elements occur naturally. Four trace elements (arsenic, copper, mercury, and selenium) had higher concentrations in fish tissue at nonurban sites than at urban sites. Concentrations decreased over time for organochlorine compounds at all three reservoirs, probably a result of the discontinued use of many of the compounds. Decreasing trends in SVOCs and trace elements were observed at West Street Basin, but increasing trends were observed at Canyon Lake. Concentrations of organochlorine compounds, SVOCs, and trace elements were higher during periods of above average rainfall at both West Street Basin and Canyon Lake.

Chemical hazards from acid crater lakes

NASA Astrophysics Data System (ADS)

van Bergen, M. J.; Sumarti, S.; Heikens, A.; Bogaard, T. A.; Hartiyatun, S.

2003-04-01

Acid crater lakes, which are hosted by a considerable number of active volcanoes, form a potential threat for local ecosystems and human health, as they commonly contain large amounts of dissolved chemicals. Subsurface seepage or overflow can lead to severe deterioration of the water quality of rivers and wells, as observations around several of these volcanoes have shown. The Ijen crater lake in East Java (Indonesia) is a striking example, as this reservoir of hyperacid (pH<0.5) sulphate, chloride and fluoride-rich water is the source of a ca. 50 km long acid river that transports substantial quantities of potentially toxic elements. A downstream trend of increasing pH from <1 to 2.5-4 is largely due to dilution with moderately acid springs (pH= ca. 4) and neutral tributaries (pH= ca. 7) inside the Ijen caldera. Geochemical controls that regulate element transport are subject to seasonal fluctuations in rainfall. Long-term monitoring has shown that fluoride levels pose some of the most severe environmental threats. Its concentration decreases from ca. 1300 mg/kg in the lake to ca. 10 mg/kg in a coastal area downstream, where virtually all of the river water is used for irrigating rice fields and other cropland. Apart from serious problems for agriculture, our survey of 55 drinking water wells in the irrigation area shows that 50% contain fluoride above the 1.5 ppm WHO limit, in line with the observation that dental fluorosis is widespread among the ca. 100,000 residents of the area. A conspicuous spatial correlation between fluoride concentrations and the irrigation system suggest that long-term (century) infiltration of irrigation water may have affected the quality of groundwater. Fluorosis is also a problem in some villages within the caldera, where well water sources may have a more direct subsurface connection with the lake system. From our observations we conclude that water-quality monitoring is especially needed for health reasons in volcanic areas where volatile elements, derived from passively degassing magma, are intercepted by (sub) surface water bodies.

Population genomic analysis suggests strong influence of river network on spatial distribution of genetic variation in invasive saltcedar across the southwestern United States

USGS Publications Warehouse

Lee, Soo-Rang; Jo, Yeong-Seok; Park, Chan-Ho; Friedman, Jonathan M.; Olson, Matthew S.

2018-01-01

Understanding the complex influences of landscape and anthropogenic elements that shape the population genetic structure of invasive species provides insight into patterns of colonization and spread. The application of landscape genomics techniques to these questions may offer detailed, previously undocumented insights into factors influencing species invasions. We investigated the spatial pattern of genetic variation and the influences of landscape factors on population similarity in an invasive riparian shrub, saltcedar (Tamarix L.) by analysing 1,997 genomewide SNP markers for 259 individuals from 25 populations collected throughout the southwestern United States. Our results revealed a broad-scale spatial genetic differentiation of saltcedar populations between the Colorado and Rio Grande river basins and identified potential barriers to population similarity along both river systems. River pathways most strongly contributed to population similarity. In contrast, low temperature and dams likely served as barriers to population similarity. We hypothesize that large-scale geographic patterns in genetic diversity resulted from a combination of early introductions from distinct populations, the subsequent influence of natural selection, dispersal barriers and founder effects during range expansion.

Effects of heavy metal pollution in the Pilcomayo river system Bolivia, on resident human populations

NASA Astrophysics Data System (ADS)

Hudson-Edwards, K. A.; Miller, J. R.; Presto, D.; Lechler, P. J.; Macklin, M. G.; Miners, J. S.; Turner, J. N.

2003-05-01

The Pilcomayo river in Bolivia drains the Potosi mining district and flows downstream, exposing indigenous populations, who rely on the river for drinking water, irrigation and fish, to elevated levels of toxic metals. A preliminary analysis of agricultural soil and crops from four riverside Pilcomayo communities has shown that many agricultural fields are contaminated with heavy metals (Ag, Cd, Cu, Pb, Sb, Zn) and arsenic(As) However, concentrations of these elements in most crops are within guideline values. Concentrations of metals and As in samples of drinking water are, for the most part, lower than concentrations in Pilcomayo river water taken at the respective communities, and the drinking water concentrations are within guideline values. Exceptions are Sb and As concentrations in two of the communities. In irrigation waters, Zn and Pb exceed recommended guideline values in two of the communities, and may lead to highZn and Pb values in some crops and soils. The work carried out to date suggests that the strategies used by these communities appear to considerably reduce their risks to exposure. Work is ongoing to develop more complex and effective strategies based on further geochemical analyses and social science surveys.

Two-Dimensional Flood-Inundation Model of the Flint River at Albany, Georgia

USGS Publications Warehouse

Musser, Jonathan W.; Dyar, Thomas R.

2007-01-01

Potential flow characteristics of future flooding along a 4.8-mile reach of the Flint River in Albany, Georgia, were simulated using recent digital-elevation-model data and the U.S. Geological Survey finite-element surface-water modeling system for two-dimensional flow in the horizontal plane (FESWMS-2DH). Simulated inundated areas, in 1-foot (ft) increments, were created for water-surface altitudes at the Flint River at Albany streamgage (02352500) from 192.5-ft altitude with a flow of 123,000 cubic feet per second (ft3/s) to 179.5-ft altitude with a flow of 52,500 ft3/s. The model was calibrated to match actual floods during July 1994 and March 2005 and Federal Emergency Management Administration floodplain maps. Continuity checks of selected stream profiles indicate the area near the Oakridge Drive bridge had lower velocities than other areas of the Flint River, which contributed to a rise in the flood-surface profile. The modeled inundated areas were mapped onto monochrome orthophoto imagery for use in planning for future floods. As part of a cooperative effort, the U.S. Geological Survey, the City of Albany, and Dougherty County, Georgia, conducted this study.

Mercury and other trace elements in Ohio River fish collected near coal-fired power plants: Interspecific patterns and consideration of consumption risks.

PubMed

Reash, Robin J; Brown, Lauren; Merritt, Karen

2015-07-01

Many coal-fired electric generating facilities in the United States are discharging higher loads of Hg, Se, and other chemicals to receiving streams due to the installation of flue gas desulfurization (FGD) air pollution control units. There are regulatory concerns about the potential increased uptake of these bioaccumulative trace elements into food webs. We evaluated the concentrations of As, total Hg (THg), methylmercury (MeHg), and Se in Ohio River fish collected proximal to coal-fired power plants, of which 75% operate FGD systems. Fillet samples (n = 50) from 6 fish species representing 3 trophic levels were analyzed. Geometric mean fillet concentrations of THg (wet wt), MeHg (wet wt), and Se (dry wt) in 3 species were 0.136, 0.1181, and 3.19 mg/kg (sauger); 0.123, 0.1013, and 1.56 mg/kg (channel catfish); and 0.127, 0.0914, and 3.30 mg/kg (hybrid striped bass). For all species analyzed, only 3 fillet samples (6% of total) had MeHg concentrations that exceeded the US Environmental Protection Agency (USEPA) human health criterion (0.3 mg/kg wet wt); all of these were freshwater drum aged ≥ 19 y. None of the samples analyzed exceeded the USEPA proposed muscle and whole body Se thresholds for protection against reproductive effects in freshwater fish. All but 8 fillet samples had a total As concentration less than 1.0 mg/kg dry wt. Mean Se health benefit values (HBVSe ) for all species were ≥ 4, indicating that potential Hg-related health risks associated with consumption of Ohio River fish are likely to be offset by adequate Se concentrations. Overall, we observed no measurable evidence of enhanced trace element bioaccumulation associated with proximity to power plant FGD facilities, however, some enhanced bioaccumulation could have occurred in the wastewater mixing zones. Furthermore, available evidence indicates that, due to hydraulic and physical factors, the main stem Ohio River appears to have low net Hg methylation potential. © 2015 SETAC.

Concentrations and Loads of Organic Compounds and Trace Elements in Tributaries to Newark and Raritan Bays, New Jersey

USGS Publications Warehouse

Wilson, Timothy P.; Bonin, Jennifer L.

2007-01-01

A study was undertaken to determine the concentrations and loads of sediment and chemicals delivered to Newark and Raritan Bays by five major tributaries: the Raritan, Passaic, Rahway, Elizabeth, and Hackensack Rivers. This study was initiated by the State of New Jersey as Study I-C of the New Jersey Toxics Reduction Workplan for the New York-New Jersey Harbor, working under the NY-NJ Harbor Estuary Program (HEP) Contaminant Assessment and Reduction Program (CARP). The CARP is a comprehensive effort to evaluate the levels and sources of toxic contaminants to the tributaries and estuarine areas of the NY-NJ Harbor, including Newark and Raritan Bays. The Raritan and Passaic Rivers are large rivers (mean daily discharges of 1,189 and 1,132 cubic feet per second (ft3/s), respectively), that drain large, mixed rural/urban basins. The Elizabeth and Rahway Rivers are small rivers (mean daily discharges of 25.9 and 49.1 ft3/s, respectively) that drain small, highly urbanized and industrialized basins. The Hackensack River drains a small, mixed rural/urban basin, and its flow is highly controlled by an upstream reservoir (mean daily discharge of 90.4 ft3/s). These rivers flow into urbanized estuaries and ultimately, to the Atlantic Ocean. Each of these tributaries were sampled during two to four storm events, and twice each during low-flow discharge conditions. Samples were collected using automated equipment installed at stations adjacent to U.S. Geological Survey streamflow-gaging stations near the heads-of-tide of these rivers. Large-volume (greater than 50 liters of water and a target of 1 gram of sediment), flow-weighted composite samples were collected for chemical analysis using filtration to collect suspended particulates and exchange resin (XAD-2) to sequester dissolved contaminants. Composite whole-water samples were collected for dissolved polycyclic aromatic hydrocarbons (PAH) and for trace element analysis. Additional discrete grab samples were collected throughout each event for trace-element analysis, and multiple samples were collected for suspended sediment (SS), particulate carbon (POC), and dissolved organic carbon (DOC) analysis. The suspended sediment and exchange resin were analyzed for 114 polychlorinated biphenyls (PCBs, by US EPA method 1668A, modified), seven 2,3,7,8-substituted chlorinated dibenzo-p-dioxins (CDD) and 10 dibenzo-p-difurans (CDF) (by US EPA method 1613), 24 PAHs (by low-resolution isotope dilution/mass-spectral methods), 27 organo-chlorine pesticides (OCPs) (by high resolution isotope dilution/mass-spectral methods), and the trace elements mercury (Hg), methyl-mercury (MeHg), lead (Pb), and cadmium (Cd). Isotope dilution methods using gas chromatography and high-and low-resolution mass spectral (GC/MS) detection were used to accurately identify and quantify organic compounds in the sediment and water phases. Trace elements were measured using inductively coupled plasma-mass spectrometry and cold-vapor atomic fluorescence spectrometry methods. The loads of sediment, carbon, and chemicals were calculated for each storm and low-flow event sampled. Because only a few storm events were sampled, yearly loads of sediment were calculated from rating curves developed using historical SS and POC data. The average annual loads of sediment and carbon were calculated for the period 1975-2000, along with the loads for the selected water years being modeled as part of the New York New Jersey Harbor Estuary Program CARP. Comparison of loads calculated using the rating curve method to loads measured during the sampled storm events indicated that the rating curve method likely underpredicts annual loads. Average annual loads of suspended sediment in the tributaries were estimated to be 395,000 kilograms per year (kg/yr) in the Hackensack River, 417,000 kg/yr in the Elizabeth River, 882,000 kg/yr in the Rahway River, 22,700,000 kg/yr in the Passaic River, and 93,100,000 kg/yr in the Raritan River. Averag

Groundwater-quality data from the eastern Snake River Plain Aquifer, Jerome and Gooding Counties, south-central Idaho, 2017

USGS Publications Warehouse

Skinner, Kenneth D.

2018-05-11

Groundwater-quality samples and water-level data were collected from 36 wells in the Jerome/Gooding County area of the eastern Snake River Plain aquifer during June 2017. The wells included 30 wells sampled for the U.S. Geological Survey’s National Water-Quality Assessment project, plus an additional 6 wells were selected to increase spatial distribution. The data provide water managers with the ability for an improved understanding of groundwater quality and flow directions in the area. Groundwater-quality samples were analyzed for nutrients, major ions, trace elements, and stable isotopes of water. Quality-assurance and quality-control measures consisted of multiple blank samples and a sequential replicate sample. All data are available online at the USGS National Water Information System.

The Research of John Edmond: A Brief History

NASA Astrophysics Data System (ADS)

Boyle, E. A.

2001-12-01

John Edmond left his undergraduate solution chemistry background in damp Scotland for the sunny shores of La Jolla, where Ed Goldberg attempted to interest him in sediment chemistry (his response upon seeing messy marine sediments was not enthusiastic). Charles Keeling also attempted to interest John in CO2 manometry (too many stopcocks to grease). So John evolved into one of those graduate students at Scripps who it was hard to tell from the faculty, and financed by an International Nickel Fellowship and the ONR grant of his nominal thesis supervisor Mel Peterson (who was moving into directorship of the Deep Sea Drilling Project), John parlayed a hot tip from L.G. Sillen on Gran titrations into a thesis on the CO2 system (alkalinity and SCO2) in seawater. He produced fine data coveted by SIO faculty members and set the stage for CO2 system efforts by the GEOSECS program. Perhaps influenced by a summer fellowship at WHOI working on trace elements in Eel Pond (with Derek Spencer), John became interested in oceanic trace metal distributions and collected water samples from the Southern Ocean. This work led to papers on the oceanic Si cycle and a GEOSECS-based study of the relationship between Ra, Ba, and Si. He also became interested in the role of particulate elemental transport in the ocean and river chemistry, and so he set his first batch of graduate students on investigators of oceanic trace metals, marine particle fluxes, and New England river and estuarine chemistry. This line of investigation also extended to studies of African lake chemistry in collaboration with Ray Weiss and Harmon Craig. These studies led John to develop a laboratory with a diverse set of tools for the elemental analysis of freshwater and seawater samples. At the same time, he was talking to heat flow geophysicists who were predicting that hydrothermal springs should be found on the seafloor at mid-ocean ridge crests. So it was no accident when he seized the opportunity to join his old SIO "Rancho Corliss" housemate on Alvin dives to the Galapagos Ridge and turned the discovery of warm springs there into a major geochemical tour de force. Hot springs would have been discovered without John, but their profound geochemical influence would have taken much longer to be unraveled without his scientific insight and the versatile analytical capabilities of his laboratory. The rest is history: extrapolation of 20\\deg C warm springs to 350\\deg C using Mg-T plots, discovery of the 21\\deg N black smokers, and many explorations of ridge crest hydrothermal activity. Partly out of a growing tedium with "stamp collecting", John stopped working in this field after a productive run of more than a decade, and turned his explorations to another major influence on ocean chemistry: the input from rivers. A long series of studies from uncontaminated rivers systems from the Amazon, Orinoco, Siberian, to Himalyan rivers ensued; this work set the tone for evaluations of influence of rivers on the chemical and isotopic composition of the oceans and their relation to weathering and climate. He continued this work up until his untimely death. A brief abstract and AGU talk cannot do justice to the diversity and brilliance of John Edmond's science, but it can at least serve as a reminder of what we have lost.

Assessment of Concentrations of Heavy Metals and Phthalates in Two Urban Rivers of the Northeast of Puerto Rico

PubMed Central

Ortiz-Colón, Ana I; Piñero-Santiago, Luis E; Rivera, Nilsa M; Sosa, María A

2016-01-01

Urbanization adjacent to rivers has increased in recent years and is considered a source of environmental contamination. The resulting increase in number of urban rivers in highly populated areas, such as the Caribbean island of Puerto Rico, has led to the appearance of synthetic as well as naturally occurring chemicals not previously observed nor regularly monitored in freshwater habitats. Some of these chemicals, such as heavy metals and plasticizers, have been shown to affect endocrine, respiratory, and nervous system function in animals and humans, even at relatively low concentrations. The purpose of this study was to measure concentrations of such emergent contaminants on rivers of urbanized areas on the northeast of Puerto Rico, as one element in the assessment of the impact of urbanism on water quality in these communities. To accomplish this, we used Inductively Coupled Plasma and Gas Chromatography Mass Spectrometry to measure amounts of heavy metals and phthalates, respectively, in superficial water of three rivers of Puerto Rico: Mameyes (non-urban), Río Piedras (urban river without a dam), and La Plata (urban river with a dam). The urban rivers had significantly higher concentrations of heavy metals arsenic, barium, cadmium, manganese, and antimony, when compared with the reference non-urban river. Manganese was the only metal found in concentrations higher than limits established by the EPA for drinking water. Of eight phthalates amenable to measurement with the chosen protocol and instrumentation, only dibutyl phthalate was detected, only in the La Plata river, and at concentrations ranging from 3 to 8 parts-per-billion. These findings suggest that urbanism close to rivers of Puerto Rico is likely having an impact on water quality and thus further study to identify the potential sources, as well as the inclusion of these emergent contaminants on the list of chemicals regularly monitored by government agencies is justified. PMID:27148470

Assessment of Concentrations of Heavy Metals and Phthalates in Two Urban Rivers of the Northeast of Puerto Rico.

PubMed

Ortiz-Colón, Ana I; Piñero-Santiago, Luis E; Rivera, Nilsa M; Sosa, María A

2016-03-20

Urbanization adjacent to rivers has increased in recent years and is considered a source of environmental contamination. The resulting increase in number of urban rivers in highly populated areas, such as the Caribbean island of Puerto Rico, has led to the appearance of synthetic as well as naturally occurring chemicals not previously observed nor regularly monitored in freshwater habitats. Some of these chemicals, such as heavy metals and plasticizers, have been shown to affect endocrine, respiratory, and nervous system function in animals and humans, even at relatively low concentrations. The purpose of this study was to measure concentrations of such emergent contaminants on rivers of urbanized areas on the northeast of Puerto Rico, as one element in the assessment of the impact of urbanism on water quality in these communities. To accomplish this, we used Inductively Coupled Plasma and Gas Chromatography Mass Spectrometry to measure amounts of heavy metals and phthalates, respectively, in superficial water of three rivers of Puerto Rico: Mameyes (non-urban), Río Piedras (urban river without a dam), and La Plata (urban river with a dam). The urban rivers had significantly higher concentrations of heavy metals arsenic, barium, cadmium, manganese, and antimony, when compared with the reference non-urban river. Manganese was the only metal found in concentrations higher than limits established by the EPA for drinking water. Of eight phthalates amenable to measurement with the chosen protocol and instrumentation, only dibutyl phthalate was detected, only in the La Plata river, and at concentrations ranging from 3 to 8 parts-per-billion. These findings suggest that urbanism close to rivers of Puerto Rico is likely having an impact on water quality and thus further study to identify the potential sources, as well as the inclusion of these emergent contaminants on the list of chemicals regularly monitored by government agencies is justified.

[Spatial variations of biogenic elements in coastal wetland sediments of the Jiulong River Estuary].

PubMed

Yu, Xiao-Qing; Yang, Jun; Liu, Le-Mian; Tian, Yuan; Yu, Zheng; Wang, Chang-Fu

2012-11-01

To reveal the spatial distribution of biogenic elements and their influencing factors in the typical subtropical coastal wetland, both surface and core sediment samples were collected from the Jiulong River Estuary, southeast China in summer 2009. The biogenic elements including carbon, nitrogen, phosphorus, sulfur (C, N, P, S) were determined by Element Analyzer and Flow Injection Analyzer. The concentrations of TC, TN, TP, and TS were (12.64 +/- 2.66) g x kg(-1), (1.57 +/- 0.29) g x kg(-1), (0.48 +/- 0.06) g x kg(-1), and (2.61 +/- 1.37) g x kg(-1), respectively. Further, these biogenic elements showed a distinct spatial pattern which closely related with the vegetation type and tide level. Values of TC, TN, TP in the surface sediment of mangrove vegetation zones were higher than those in the cord-grass and mudflat zones, while TC, TN, TP concentrations in the high tide level regions were higher than those in the middle and low tide level regions. The TS concentration was the highest in cord-grass vegetation and middle tidal level zones. The TC and TN values in sedimentary core decreased gradually with depth, and they were the highest in the mangrove sites, followed by cord-grass and mudflat sites at the same depth. In mudflat sedimentary core, the average content of TP was the lowest, whereas TS was the highest. Redundancy analysis revealed that vegetation type, pH and tide level were the main factors influencing the distribution of biogenic elements in surface sediments of the Jiulong River Estuary, by explaining 24.0%, 19.0% and 11.6% of total variation in the four biogenic elements (C, N, P and S), respectively.

Crevasse splay processes and deposits in an ancient distributive fluvial system: The lower Beaufort Group, South Africa

NASA Astrophysics Data System (ADS)

Gulliford, Alice R.; Flint, Stephen S.; Hodgson, David M.

2017-08-01

Up to 12% of the mud-prone, ephemeral distributive fluvial system stratigraphy in the Permo-Triassic lower Beaufort Group, South Africa, comprises tabular fine-grained sandstone to coarse-grained siltstone bodies, which are interpreted as proximal to distal crevasse splay deposits. Crevasse splay sandstones predominantly exhibit ripple to climbing ripple cross-lamination, with some structureless and planar laminated beds. A hierarchical architectural scheme is adopted, in which 1 m thick crevasse splay elements extend for tens to several hundreds of meters laterally, and stack with other splay elements to form crevasse splay sets up to 4 m thick and several kilometers in width and length. Paleosols and nodular horizons developed during periods, or in areas, of reduced overbank flooding are used to subdivide the stratigraphy, separating crevasse splay sets. Deposits from crevasse splays differ from frontal splays as their proximal deposits are much thinner and narrower, with paleocurrents oblique to the main paleochannel. In order for crevasse splay sets to develop, the parent channel belt and the location where crevasse splays form must stay relatively fixed during a period of multiple flood events. Beaufort Group splays have similar geometries to those of contemporary perennial rivers but exhibit more lateral variability in facies, which is interpreted to be the result of more extreme fluctuations in discharge regime. Sharp-based crevasse splay packages are associated with channel avulsion, but most are characterized by a gradual coarsening upward, interpreted to represent progradation. The dominance of progradational splays beneath channel belt deposits may be more characteristic of progradational stratigraphy in a distributive fluvial system rather than dominated by avulsion processes in a trunk river system. This stratigraphic motif may therefore be an additional criterion for recognition of distributive fluvial systems in the ancient record.

Temporal and spatial variations in the biogeochemical cycling of cobalt in two urban estuaries: Hudson River Estuary and San Francisco Bay

NASA Astrophysics Data System (ADS)

Tovar-Sánchez, Antonio; Sañudo-Wilhelmy, Sergio A.; Flegal, A. Russell

2004-08-01

Despite the fact that Co is an essential trace element for the growth of marine phytoplankton, there is very limited information on the cycling of this trace metal in the marine environment. We report here the distribution of dissolved (<0.4 μm) and particulate (>0.4 μm) Co in surface waters of the Hudson River Estuary (HRE) and San Francisco Bay (SFB). Samples were collected during several cruises (from 1990 to 1995 in SFB and from 1995 to 1997 in the HRE) along the whole salinity gradient. Dissolved Co concentrations (mean±1 standard deviation) were nearly identical in magnitude in both estuaries despite differences in climate, hydrography, riverine-flow conditions and land-usage (HRE=0.91±0.61 nM; SFB=1.12±0.69 nM). Dissolved Co levels in each system showed non-conservative distributions when plotted as a function of salinity, with increasing concentrations downstream from the riverine end-members. Desorption from suspended particulates and sewage inputs, therefore, seems to be the major processes responsible for the non-conservative behavior of Co observed. Mass balance estimates also indicated that most of the estuarine Co is exported out of both estuaries, indicating that they and other estuarine systems are principal sources of this essential trace element to the open ocean.

Organic carbon and nitrogen export from a tropical dam-impacted floodplain system

NASA Astrophysics Data System (ADS)

Zurbrügg, R.; Suter, S.; Lehmann, M. F.; Wehrli, B.; Senn, D. B.

2013-01-01

Tropical floodplains play an important role in organic matter transport, storage, and transformation between headwaters and oceans. However, the fluxes and quality of organic carbon (OC) and organic nitrogen (ON) in tropical river-floodplain systems are not well constrained. We explored the quantity and characteristics of dissolved and particulate organic matter (DOM and POM, respectively) in the Kafue River flowing through the Kafue Flats (Zambia), a tropical river-floodplain system in the Zambezi River basin. During the flooding season, > 80% of the Kafue River water passed through the floodplain, mobilizing large quantities of OC and ON, which resulted in a net export of 69-119 kg OC km-2 d-1 and 3.8-4.7 kg ON km-2 d-1, 80% of which was in the dissolved form. The elemental C : N ratio of ~ 20, the comparatively high δ13C values of -25‰ to -21‰, and its spectroscopic properties (excitation-emission matrices) showed that DOM in the river was mainly of terrestrial origin. Despite a threefold increase in OC loads due to inputs from the floodplain, the characteristics of the riverine DOM remained relatively constant along the sampled 410-km river reach. This suggests that floodplain DOM displayed properties similar to those of DOM leaving the upstream reservoir and implied that the DOM produced in the reservoir was relatively short-lived. In contrast, the particulate fraction was 13C-depleted (-29‰) and had a C : N ratio of ~ 8, which indicated that POM originated from phytoplankton production in the reservoir and in the floodplain, rather than from plant debris or resuspended sediments. While the upstream dam had little effect on the DOM pool, terrestrial particles were retained, and POM from algal and microbial sources was released to the river. A nitrogen mass balance over the 2200 km2 flooded area revealed an annual deficit of 15 500-22 100 t N in the Kafue Flats. The N isotope budget suggests that these N losses are balanced by intense N-fixation. Our study shows that the Kafue Flats are a significant local source of OC and ON to downstream ecosystems and illustrates how the composition of riverine OM can be altered by dams and floodplains in tropical catchments.

Colloids in the River Inn

NASA Astrophysics Data System (ADS)

Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas

2015-04-01

In the light of an increasing number of technical applications using nanoparticles and reports of adverse effects of engineered nanoparticles, research on the occurrence and stability of particles in all compartments has to be intensified. Colloids in river water represent the geologic setting, environmental conditions, and the anthropogenic use in its catchment. The river not only acts as a sink for nanoparticles but also as the source term due to exchange in the hyporheic zone and in bank filtration setups. The concentration, size distribution and elemental composition of particles in the River Inn were studied from the source in the Swiss Alps to the river mouth at Passau from 2008 to 2014. Samples were collected after each tributary from a sub-catchment and filtered on site using a new filtration device for gentle filtration. The elemental composition was determined after acid digestion with ICP/MS. SEM/EDX analysis provided morphological and elemental information for single particles. A complementary chemical analysis of the river water was performed to assess the geochemical stability of individual particles. As presented at EGU 2014, particles in the upper, rural parts mainly reveal changes in the geological setting of the tributary catchments. Not unexpectedly, particles originating from crystalline rocks, were more stable than particles originating from calcareous rocks. Anthropogenic and industrial influences increase in the lower parts. This went together with a change of the size distribution, an increase of the number of organic particles, and a decrease of the microfauna. Interestingly, specific leisure activities in a sub-catchment, like extensive downhill skiing, manifest itself in the particle composition. This general setting was validated in last year's sampling campaigns. An interesting change in on site parameters and hydrochemical composition was seen during all sampling campaigns at an inflow from the valley Kaunertal, Austria. Therefore, additional samples of the River Inn before and after the influx of the Faggenbach stream, Faggenbach stream itself and at an aqueous pressure gallery that discharges to the River Inn were taken and analyzed. Here the effect of construction activities at the power plant were clearly visible.

Two mantle sources, two plumbing systems: Tholeiitic and alkaline magmatism of the Maymecha River basin, Siberian flood volcanic province

USGS Publications Warehouse

Arndt, N.; Chauvel, C.; Czamanske, G.; Fedorenko, V.

1998-01-01

Rocks of two distinctly different magma series are found in a ???4000-m-thick sequence of lavas and tuffs in the Maymecha River basin which is part of the Siberian flood-volcanic province. The tholeiites are typical low-Ti continental flood basalts with remarkably restricted, petrologically evolved compositions. They have basaltic MgO contents, moderate concentrations of incompatible trace elements, moderate fractionation of incompatible from compatible elements, distinct negative Ta(Nb) anomalies, and ??Nd values of 0 to + 2. The primary magmas were derived from a relatively shallow mantle source, and evolved in large crustal magma chambers where they acquired their relatively uniform compositions and became contaminated with continental crust. An alkaline series, in contrast, contains a wide range of rock types, from meymechite and picrite to trachytes, with a wide range of compositions (MgO from 0.7 to 38 wt%, SiO2 from 40 to 69 wt%, Ce from 14 to 320 ppm), high concentrations of incompatible elements and extreme fractionation of incompatible from compatible elements (Al2O3/TiO2 ??? 1; Sm/Yb up to 11). These rocks lack Ta(Nb) anomalies and have a broad range of ??Nd values, from -2 to +5. The parental magmas are believed to have formed by low-degree melting at extreme mantle depths (>200 km). They bypassed the large crustal magma chambers and ascended rapidly to the surface, a consequence, perhaps, of high volatile contents in the primary magmas. The tholeiitic series dominates the lower part of the sequence and the alkaline series the upper part; at the interface, the two types are interlayered. The succession thus provides evidence of a radical change in the site of mantle melting, and the simultaneous operation of two very different crustal plumbing systems, during the evolution of this flood-volcanic province. ?? Springer-Verlag 1998.

Mixing as a driver of temporal variations in river hydrochemistry: 1. Insights from conservative tracers in the Andes-Amazon transition

NASA Astrophysics Data System (ADS)

Torres, Mark A.; Baronas, J. Jotautas; Clark, Kathryn E.; Feakins, Sarah J.; West, A. Joshua

2017-04-01

The response of hillslope processes to changes in precipitation may drive the observed changes in the solute geochemistry of rivers with discharge. This conjecture is most robust when variations in the key environmental factors that affect hillslope processes (e.g., lithology, erosion rate, and climate) are minimal across a river's catchment area. For rivers with heterogenous catchments, temporal variations in the relative contributions of different tributary subcatchments may modulate variations in solute geochemistry with runoff. In the absence of a dense network of hydrologic gauging stations, alternative approaches are required to distinguish between the different drivers of temporal variability in river solute concentrations. In this contribution, we apportion the water and solute fluxes of a reach of the Madre de Dios River (Peru) between its four major tributary subcatchments during two sampling campaigns (wet and dry seasons) using spatial variations in conservative tracers. Guided by the results of a mixing model, we identify temporal variations in solute concentrations of the main stem Madre de Dios that are due to changes in the relative contributions of each tributary. Our results suggest that variations in tributary mixing are, in part, responsible for the observed concentration-discharge (C-Q) relationships. The implications of these results are further explored by reanalyzing previously published C-Q data from this region, developing a theoretical model of tributary mixing, and, in a companion paper, comparing the C-Q behavior of a suite of major and trace elements in the Madre de Dios River system.

Elements patterns of soil and river sediments as a tracer of sediment migration

NASA Astrophysics Data System (ADS)

Dordevic, Dragana; Pétursdóttir, Þórunn; Halldórsson, Guðmundur; Sakan, Sanja; Škrivalj, Sandra; Finger, David Christian

2017-04-01

Iceland is the small island on the mid Atlantic ridge, with strong natural catastrophes, such as floods, droughts, landslides, storms and volcanic eruptions that can have devastating impacts on natural and build environment. Rangárvellir area next to Mt Hekla and the glacier Tindfjallajökul has impacted by severe erosion processes but also rich of surface water that play a crucial role in sediment transport processes in the watersheds of the two rivers Eystri-Rangá and Ytri-Rangá. Their sediments consist of various materials originating from volcanoes ash and lava. Difference of contents of various chemical components in sediments and surrounding soil could be bases for identification of erosion processes and watersheds connectivity. River sediment is accumulator of chemical constituents from water in water-sediment interaction, making it as an important material for investigation their migration routes. In order to develop of methods for investigating of sediment migration using their chemical patterns the STSM of Connecteur COST Action ES1306-34336 have been approved. Samples of river sediments and surrounding soils of the Eystri-Rangá and Ytri-Rangá rivers in watersheds of Rangárvellir area as well as primarily volcanic ash from Eyafjallajökull were taken. Sequential extraction of heavy metals and trace elements from collected samples has been applied using the optimized procedure proposed by European Community Bureau of reference (BCR) in the next fractions: 1) soluble in acid - metals that are exchangeable or associated with carbonates; 2) reducible fraction - metals associated with oxides of Fe and Mn; 3) oxidizable fraction - metals associated with organic matter and sulfides and 4) residual fraction - metals strongly associated with the crystalline structure of minerals. Extracted solutions have analyzed by ICP/OES on next elements: Al, As, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Sb, Si, Sr, V, Zn. Distributions of Si is the same in all investigated samples of soils, river sediments and volcanic ash pointing to the same their geochemical basis. Some elements like Li and partly B exist in the first phase of volcanic ash and river sediments but no in the first phases of soils as if they were already washed from them and adsorbed on the river sediments surfaces. In the first phase of volcanic ash P was found but no exists in the first phase of soil and river sediments. Total content of Bi is found only in silicate matrix while total contents of As is found only in organic/sulphide form in all investigated samples.

Form drag in rivers due to small-scale natural topographic features: 2. Irregular sequences

USGS Publications Warehouse

Kean, J.W.; Smith, J.D.

2006-01-01

The size, shape, and spacing of small-scale topographic features found on the boundaries of natural streams, rivers, and floodplains can be quite variable. Consequently, a procedure for determining the form drag on irregular sequences of different-sized topographic features is essential for calculating near-boundary flows and sediment transport. A method for carrying out such calculations is developed in this paper. This method builds on the work of Kean and Smith (2006), which describes the flow field for the simpler case of a regular sequence of identical topographic features. Both approaches model topographic features as two-dimensional elements with Gaussian-shaped cross sections defined in terms of three parameters. Field measurements of bank topography are used to show that (1) the magnitude of these shape parameters can vary greatly between adjacent topographic features and (2) the variability of these shape parameters follows a lognormal distribution. Simulations using an irregular set of topographic roughness elements show that the drag on an individual element is primarily controlled by the size and shape of the feature immediately upstream and that the spatial average of the boundary shear stress over a large set of randomly ordered elements is relatively insensitive to the sequence of the elements. In addition, a method to transform the topography of irregular surfaces into an equivalently rough surface of regularly spaced, identical topographic elements also is given. The methods described in this paper can be used to improve predictions of flow resistance in rivers as well as quantify bank roughness.

Trace elements retained in washed nuclear fuel reprocessing solvents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gray, L.W.; MacMurdo, K.W.

1979-09-01

Analysis of purified TBP extractant from solvent extraction processes at Savannah River Plant showed several stable elements and several long-lived radioisotopes. Stable elements Al, Na, Br, Ce, Hg, and Sm are found in trace quantities in the solvent. The only stable metallic element consistently found in the solvent was Al, with a concentration which varies from about 30 ppM to about 10 ppM. The halogens Br and Cl appear to be found in the solvent systems as organo halides. Radionuclides found were principally /sup 106/Ru, /sup 129/I, /sup 3/H, /sup 235/U, and /sup 239/Pu. The /sup 129/I concentration was aboutmore » 1 ppM in the first solvent extraction cycle of each facility. In the other cycles, /sup 129/I concentration varied from about 0.1 to 0.5 ppM. Both /sup 129/I and /sup 3/H appear to be in the organic solvent as a result of exchange with hydrogen.« less

Endocrine activity in an urban river system and the biodegradation of estrogen-like endocrine disrupting chemicals through a bio-analytical approach using DRE- and ERE-CALUX bioassays.

PubMed

Vandermarken, T; Croes, K; Van Langenhove, K; Boonen, I; Servais, P; Garcia-Armisen, T; Brion, N; Denison, M S; Goeyens, L; Elskens, M

2018-06-01

The Zenne River, crossing the Brussels region (Belgium) is an extremely urbanized river impacted by both domestic and industrial effluents. The objective of this study was to monitor the occurrence and activity of Endocrine Active Substances (EAS) in river water and sediments in the framework of the Environmental Quality Standards Directive (2008/105/EC and 2013/39/EU). Activities were determined using Estrogen and Dioxin Responsive Elements (ERE and DRE) Chemical Activated Luciferase Gene Expression (CALUX) bioassays. A potential contamination source of estrogen active compounds was identified in the river at an industrial area downstream from Brussels with a peak value of 938 pg E2 eq./L water (above the EQS of 0.4 ng/L) and 195 pg E2 eq./g sediment. Estrogens are more abundantly present in the sediments than in the dissolved phase. Principal Component Analysis (PCA) showed high correlations between Suspended Particulate Matter (SPM), Particulate (POC) and Dissolved Organic Carbon (DOC) and estrogenic EAS. The dioxin fractions comply with previous data and all were above the United States Environmental Protection Agency (US EPA) low-level risk, with one (42 pg TCDD eq./g sediment) exceeding the high-level risk value for mammals. The self-purifying ability of the Zenne River regarding estrogens was examined with an in vitro biodegradation experiment using the bacterial community naturally present in the river. Hill coefficient and EC 50 values (Effective Concentration at 50%) revealed a process of biodegradation in particulate and dissolved phase. The estrogenic activity was decreased by 80%, demonstrating the ability of self-purification of estrogenic compounds in the Zenne River. Copyright © 2018 Elsevier Ltd. All rights reserved.

Predictive Analysis of Geochemical Controls in an Alpine Stream

NASA Astrophysics Data System (ADS)

Jochems, A. P.; Sherson, L. R.; Crossey, L. J.; Karlstrom, K. E.

2010-12-01

Alpine watersheds are increasingly relied upon for use in the American West, necessitating a more complete understanding of annual hydrologic patterns and geologic influences on water chemistry. The Jemez River is a fifth order stream in central New Mexico that flows from its source in the Jemez Mountains to its confluence with the Rio Grande north of the town of Bernalillo. Designated uses of the Jemez River include domestic water supply, recreation, and agriculture. Geothermal uses are currently being considered as well. The river recharges shallow aquifer waters used by several communities, including tribal lands of the Jemez Pueblo. The hydrogeology of the Jemez system is characterized by geothermal inputs from the Baca hydrothermal system associated with the 1.2Ma Valles caldera, as well as groundwater and surface water interactions. Freshwater input from the Rio Guadalupe and several ephemeral tributaries also influences the water chemistry of the Jemez system. Fifteen sites along a 35 km reach of the river were sampled between 2006 and 2010. Discharge of the Jemez River ranged from 10-876 cfs over the study period. The annual hydrograph is affected by annual snowmelt in the Jemez Mountains as well as surges due to monsoonal rains in July and August. Geochemical data collected over this period include temperature, conductivity, pH, dissolved oxygen (D.O.), major ions, trace elements, and stable isotopes. Continuous records of temperature, conductivity, pH, D.O. and turbidity data were collected from a water quality sonde installed in March 2010. Geochemical modeling and time series analysis were performed using PHREEQC, Geochemist’s Workbench, and MATLAB. Empirical data collected during this study gave rise to several models describing the hydrology and geochemistry of the Jemez system. Our data suggest that springs are the primary contributors to dissolved load, and that solute loading from geothermal inputs is intensified by low flows observed on hydrographs during late winter, as well as on the falling limb of flow during summer. Cation and anion concentrations experience significant declines during periods of high flow, though loadings remain high. Solute concentrations were found to increase downstream regardless of season. Downstream increases take place abruptly where the river crosses fault systems that localize discharge of hot spring brines from the hydrothermal system. Analyses completed during the spring of 2010 indicate that arsenic greatly exceeds EPA drinking water standards at low flows (<30 cfs). TDS and sulfate concentrations in the Jemez also exceed these standards at similar discharge. Stable isotope analyses demonstrate contributions from geothermal systems, with isotopically enriched values of δ18O for thermal waters, and near-meteoric values for most river waters. A model predicting solute concentrations as a function of snowmelt demonstrates that the Jemez River is susceptible to significant degradation of water quality under scenarios of decreasing snowpack. Fluctuations in water chemistries of this system directly affect recreational use and water quality of the Jemez River and shallow aquifer recharge, and must be considered for any proposed domestic or municipal use in the future.

Geochemical data for core and bottom-sediment samples collected in 2007 from Grand Lake O' the Cherokees, northeast Oklahoma

USGS Publications Warehouse

Fey, David L.; Becker, Mark F.; Smith, Kathleen S.

2010-01-01

Grand Lake O' the Cherokees is a large reservoir in northeast Oklahoma, below the confluence of the Neosho and Spring Rivers, both of which drain the Tri-State Mining District to the north. The Tri-State district covers an area of 1,200 mi2 (3,100 km2) and comprises Mississippi Valley-type lead-zinc deposits. A result of 120 years of mining activity is an estimated 75 million tons of processed mine tailings (chat) remaining in the district. Concerns of sediment quality and the possibility of human exposure to cadmium and lead through eating fish have led to several studies of the sediments in the Tri-State district. In order to record the transport and deposition of metals from the Tri-State district by the Spring and Neosho Rivers into Grand Lake O' the Cherokees, the U.S. Geological Survey collected 11 sediment cores and 15 bottom-sediment samples in September 2007. Subsamples from five selected cores and the bottom-sediment samples were analyzed for major and trace elements and forms of carbon. The sediment samples collected from the sediment-water interface had larger average concentrations of zinc, cadmium, and lead than local background. The core collected from the Spring River had the largest concentrations of mining-related elements. A core collected just south of Twin Bridges State Park, at the confluence of the Spring and Neosho Rivers, showed a mixing zone with more mining-related elements coming from the Spring River side. The element zinc showed the most definitive patterns in graphs depicting concentration-versus-depth profiles. A core collected from the main body of the reservoir showed affected sediment down to a depth of 85 cm (33 in). This core and two others appear to have penetrated to below mining-affected sediment.

Tectonic Control of the Acid and Alkalinity Budgets of Chemical Weathering

NASA Astrophysics Data System (ADS)

Torres, M. A.; Dellinger, M.; Clark, K. E.; West, A. J.; Paris, G.; Bouchez, J.; Ponton, C.; Feakins, S. J.; Galy, V.; Hilton, R. G.; Adkins, J. F.

2016-12-01

The exchange of carbon between the rock reservoir and the ocean/atmosphere system modulates Earth's climate over geologic timescales. Central to our current conceptualization of this geologic C cycle is a mechanistic link between input and output fluxes that limits imbalances and prevents extreme variations in atmospheric pCO2. However, a quantitative understanding of how C cycle balance is maintained remains elusive due to the competition and co-variation between many distinct biogeochemical reactions. Here, we turn to river systems draining Andes/Amazon and other modern mountain ranges to inform our understanding of how major orogenies affect key C cycle fluxes.Globally, rivers draining active mountain ranges transport massive quantities of sulfate, alkalinity, and particulate organic carbon. Consequently, defining the exact effect of tectonic uplift on both atmospheric pCO2 and pO2 requires the careful partitioning of these fluxes between competing C and O cycle reactions. Using a suite of isotopic and trace element proxies, we find that the large mass fluxes exported by mountain rivers do not necessarily translate into a large C sink due to the oxidative weathering of trace reactive phases (e.g., pyrite). Our results also imply that mountain weathering may be an important O2 sink. The applicability and implications of these results are explored using reactive-transport modeling and a new carbonate-system framework for the links between C cycle reactions and atmospheric pCO2.

Spatial variation in total element concentration in soil within the Northern Great Plains coal region, and regional soil chemistry in Bighorn and Wind River basins, Wyoming and Montana

USGS Publications Warehouse

Severson, R.C.; Tidball, R.R.

1979-01-01

PART A: To objectively determine the changes in chemical character of an area subjected to mining and reclamation, prior information is needed. This study represents a broadscale inventory of total chemical composition of the surficial materials of the Northern Great Plains coal region (western North and South Dakota, eastern Montana, and northeastern Wyoming); data are given for 41 elements in A and C soil horizons. An unbalanced, nested, analysis-of-variance design was used to quantify variation in total content of elements between glaciated and unglaciated terrains, for four increasingly smaller geographic scales, and to quantify variation due to sample preparation and analysis. From this statistical study, reliable maps on a regional basis (>100 km) were prepared for C, K, and Rb in A and C soil horizons; for N a, Si, Th, D, and Zn in A-horizon soil; and for As, Ca, Ge, and Mg in C-horizon soil. The distribution of variance components for the remaining 29 elements did not permit the construction of reliable maps. Therefore, a baseline value for each of these elements is given as a measure of the total element concentration in the soils of the Northern Great Plains coal region. The baseline is expressed as the 95-percent range in concentration to be expected in samples of natural soils. PART B: A reconnaissance study of total concentrations of 38 elements in samples of soils (0-40 cm deep, composite) from the Bighorn and Wind River Basins of Montana and Wyoming indicates that the geographic variation for most elements occurs locally (5 km or less). However, in the Bighorn Basin, Zn exhibits significant regional variation (between geologic units); and in the Wind River Basin, AI, Cr, K, Mn, Mo, Ni, U, and V exhibit similar variation. For the remaining elements, the lack of regional variation suggests that a single summary statistic can be used to estimate a baseline value that reflects the range in concentration to be expected in samples of soils in each basin. The concentrations of most of these elements in both basins are not much different from those measured independently in the Powder River Basin of Wyoming or in the Western United States. In addition, data from an analysis of variance provide an estimate of the number of random samples within an area of specified size (10 km square, approximately a township) that are needed to prepare a reliable map of total element concentration in soils for each of the elements in each of the basins.

MERCURY OXIDATION PROMOTED BY A SELECTIVE CATALYTIC REDUCTION CATALYST UNDER SIMULATED POWDER RIVER BASIN COAL COMBUSTION CONDITIONS

EPA Science Inventory

A bench-scale reactor consisting of a natural gas burner and an electrically heated reactor housing a selective catalytic reduction (SCR) catalyst was constructed for studying elemental mercury oxidation under SCR conditions. A low sulfur Power River Basin (PRB) coal combustion ...

Synthetic River Valleys

NASA Astrophysics Data System (ADS)

Brown, R.; Pasternack, G. B.

2011-12-01

The description of fluvial form has evolved from anecdotal descriptions to artistic renderings to 2D plots of cross section or longitudinal profiles and more recently 3D digital models. Synthetic river valleys, artificial 3D topographic models of river topography, have a plethora of potential applications in fluvial geomorphology, and the earth sciences in general, as well as in computer science and ecology. Synthetic river channels have existed implicitly since approximately the 1970s and can be simulated from a variety of approaches spanning the artistic and numerical. An objective method of synthesizing 3D stream topography based on reach scale attributes would be valuable for sizing 3D flumes in the physical and numerical realms, as initial input topography for morphodynamic models, stream restoration design, historical reconstruction, and mechanistic testing of interactions of channel geometric elements. Quite simply - simulation of synthetic channel geometry of prescribed conditions can allow systematic evaluation of the dominant relationships between river flow and geometry. A new model, the control curve method, is presented that uses hierarchically scaled parametric curves in over-lapping 2D planes to create synthetic river valleys. The approach is able to simulate 3D stream geometry from paired 2D descriptions and can allow experimental insight into form-process relationships in addition to visualizing past measurements of channel form that are limited to two dimension descriptions. Results are presented that illustrate the models ability to simulate fluvial topography representative of real world rivers as well as how channel geometric elements can be adjusted. The testing of synthetic river valleys would open up a wealth of knowledge as to why some 3D attributes of river channels are more prevalent than others as well as bridging the gap between the 2D descriptions that have dominated fluvial geomorphology the past century and modern, more complete, 3D treatments.

Regional view of a Trans-African Drainage System.

PubMed

Abdelkareem, Mohamed; El-Baz, Farouk

2015-05-01

Despite the arid to hyperarid climate of the Great Sahara of North Africa, pluvial climates dominated the region. Radar data shed some light on the postulated Trans-African Drainage System and its relationship to active and inactive tributaries of the Nile basin. Interpretations of recent elevation data confirm a source of the river water from the Red Sea highlands did not connect the Atlantic Ocean across Tushka basin, highlands of Uwinate and Darfur, and Chad basin, but northward to the ancestral Nile Delta. Elements of topography and climate were considered. They show that the former segments of the Nile closely mirror present-day tributaries of the Nile basin in drainage geometry, landscape, and climate. A rainfall data interpolation scenario revealed that this basin received concurrent runoff from both flanks such as Gabgaba-Allaqi to the east and Tushka basin to the west, similar to present-day Sobat and White Nile tributaries, respectively. Overall the western tributaries such as those of Tushka basin and Howar lead to the Nile, which was (and still is) the biggest river system in Africa.

Regional view of a Trans-African Drainage System

PubMed Central

Abdelkareem, Mohamed; El-Baz, Farouk

2014-01-01

Despite the arid to hyperarid climate of the Great Sahara of North Africa, pluvial climates dominated the region. Radar data shed some light on the postulated Trans-African Drainage System and its relationship to active and inactive tributaries of the Nile basin. Interpretations of recent elevation data confirm a source of the river water from the Red Sea highlands did not connect the Atlantic Ocean across Tushka basin, highlands of Uwinate and Darfur, and Chad basin, but northward to the ancestral Nile Delta. Elements of topography and climate were considered. They show that the former segments of the Nile closely mirror present-day tributaries of the Nile basin in drainage geometry, landscape, and climate. A rainfall data interpolation scenario revealed that this basin received concurrent runoff from both flanks such as Gabgaba-Allaqi to the east and Tushka basin to the west, similar to present-day Sobat and White Nile tributaries, respectively. Overall the western tributaries such as those of Tushka basin and Howar lead to the Nile, which was (and still is) the biggest river system in Africa. PMID:26257941

Origin and depositional environment of fine-grained sediments since the last glacial maximum in the southeastern Yellow Sea: evidence from rare earth elements

NASA Astrophysics Data System (ADS)

Um, In Kwon; Choi, Man Sik; Lee, Gwang Soo; Chang, Tae Soo

2015-12-01

Despite the well-reconstructed seismic stratigraphy of the Holocene mud deposit in the southeastern Yellow Sea, known as the Heuksan mud belt (HMB), the provenances of these sediments and their depositional environments are unclear, especially for the fine-grained sediments. According to seismic data (extracted from another article in this special issue), the HMB comprises several sedimentary units deposited since the last glacial maximum. Based on analytical results on rare earth elements, fine-grained sediments in all sedimentary units can be interpreted as mixtures of sediments discharged from Chinese and Korean rivers. The proportions of fine-grained sediments from Chinese rivers (74.5 to 80.0%) were constant and higher than those from Korean rivers in all units. This fact demonstrates that all units have the same fine-grained sediment provenance: units III-b and III-a, located in the middle and northern parts of the HMB and directly deposited from Chinese rivers during the sea-level lowstand, could be the sediment source for units II-b and II-a. Unit I, while ambiguous, is of mixed origin combining reworked sediments from nearby mud deposits and Changjiang River-borne material with those of the Keum River. The results of this study indicate that at least 18.6% of bulk sediments in the HMB clearly originate from Chinese rivers, despite its location close to the southwestern coast of Korea.

Has irrigated water from Mahaweli River contributed to the kidney disease of uncertain etiology in the dry zone of Sri Lanka?

PubMed

Diyabalanage, Saranga; Abekoon, Sumith; Watanabe, Izumi; Watai, Chie; Ono, Yuko; Wijesekara, Saman; Guruge, Keerthi S; Chandrajith, Rohana

2016-06-01

The Mahaweli is the largest river basin in Sri Lanka that provides water to the dry zone region through multipurpose irrigation schemes . Selenium, arsenic, cadmium, and other bioimportant trace elements in surface waters of the upper Mahaweli River were measured using ICP-MS. Trace element levels were then compared with water from two other rivers (Maha Oya, Kalu Ganga) and from six dry zone irrigation reservoirs. Results showed that the trace metal concentrations in the Mahaweli upper catchment were detected in the order of Fe > Cu > Zn > Se > Cr > Mn > As > Ni > Co > Mo. Remarkably high levels of Ca, Cr, Co, Ni, Cu, As, and Se were observed in the Mahaweli Basin compared to other study rivers. Considerably high levels of Cr, Mn, Fe, Co, Ni, Cu, Zn, As, and Se were found in upstream tributaries of the Mahaweli River. Such metals possibly originated from phosphate and organic fertilizers that are heavily applied for tea and vegetable cultivations within the drainage basin. Cadmium that is often attributed to the etiology of unknown chronic kidney diseases in certain parts of the dry zone is much lower than previously reported levels. Decrease in these metals in the lower part of the Mahaweli River could be due to adsorption of trace metals onto sediment and consequent deposition in reservoirs.

The solution of non-linear hyperbolic equation systems by the finite element method

NASA Technical Reports Server (NTRS)

Loehner, R.; Morgan, K.; Zienkiewicz, O. C.

1984-01-01

A finite-element method for the solution of nonlinear hyperbolic systems of equations, such as those encountered in non-self-adjoint problems of transient phenomena in convection-diffusion or in the mixed representation of wave problems, is developed and demonstrated. The problem is rewritten in moving coordinates and reinterpolated to the original mesh by a Taylor expansion prior to a standard Galerkin spatial discretization, and it is shown that this procedure is equivalent to the time-discretization approach of Donea (1984). Numerical results for sample problems are presented graphically, including such shallow-water problems as the breaking of a dam, the shoaling of a wave, and the outflow of a river; compressible flows such as the isothermal flow in a nozzle and the Riemann shock-tube problem; and the two-dimensional scalar-advection, nonlinear-shallow-water, and Euler equations.

Inductively coupled plasma-mass spectrometry as an element-specific detector for field-flow fractionation particle separation

USGS Publications Warehouse

Taylor, Howard E.; Garbarino, John R.; Murphy, Deirdre M.; Beckett, Ronald

1992-01-01

An inductively coupled plasma-mass spectrometer was used for the quantitative measurement of trace elements In specific,submicrometer size-fraction particulates, separated by sedimentation field-flow fractionation. Fractions were collected from the eluent of the field-flow fractionation centrifuge and nebulized, with a Babington-type pneumatic nebulizer, into an argon inductively coupled plasma-mass spectrometer. Measured Ion currents were used to quantify the major, minor, and trace element composition of the size-separated colloidal (< 1-microm diameter) particulates. The composition of surface-water suspended matter collected from the Yarra and Darling rivers in Australia is presented to illustrate the usefulness of this tool for characterizing environmental materials. An adsorption experiment was performed using cadmium lon to demonstrate the utility for studying the processes of trace metal-suspended sediment interactions and contaminant transport in natural aquatic systems.

Dynamics of pollutant indicators during flood events in a small river under strong anthropogenic pressures

NASA Astrophysics Data System (ADS)

Brion, Natacha; Carbonnel, Vincent; Elskens, Marc; Claeys, Philippe; Verbanck, Michel A.

2017-04-01

In densely populated regions, human activities profoundly modify natural water circulation as well as water quality, with increased hydrological risks (floods, droughts,…) and chemical hazards (untreated sewage releases, industrial pollution,…) as consequence. In order to assess water and pollutants dynamics and their mass-balance in strongly modified river system, it is important to take into account high flow events as a significant fraction of water and pollutants loads may occur during these short events which are generally underrepresented in classical mass balance studies. A good example of strongly modified river systems is the Zenne river in and around the city of Brussels (Belgium).The Zenne River (Belgium) is a rather small but dynamic rain fed river (about 10 m3/s in average) that is under the influence of strong contrasting anthropogenic pressures along its stretch. While the upstream part of its basin is rather characterized by agricultural land-use, urban and industrial areas dominate the downstream part. In particular, the city of Brussels (1.1M inhabitants) discharges in the Zenne River amounts of wastewater that are large compared to the natural riverine flow. In order to assess water and pollutants dynamics and their mass-balance in the Zenne hydrographic network, we followed water flows and concentrations of several water quality tracers during several flood episodes with an hourly frequency and at different locations along the stretch of the River. These parameters were chosen as indicators of a whole range of pollutions and anthropogenic activities. Knowledge of the high-frequency pollutants dynamics during floods is required for establishing accurate mass-balances of these elements. We thus report here the dynamics of selected parameters during entire flood events, from the baseline to the decreasing phase and at hourly frequency. Dynamics at contrasting locations, in agricultural or urban environments are compared. In particular, the importance of combined sewer overflows are evaluated and discussed. Results from this study were obtained in the framework of the OSIRIS research project (INNOVIRIS Anticipate 2015-2019).

Rare earth elements in the aragonitic shell of freshwater mussel Corbicula fluminea and the bioavailability of anthropogenic lanthanum, samarium and gadolinium in river water.

PubMed

Merschel, Gila; Bau, Michael

2015-11-15

High-technology metals - such as the rare earth elements (REE) - have become emerging contaminants in the hydrosphere, yet little is known about their bioavailability. The Rhine River and the Weser River in Germany are two prime examples of rivers that are subjected to anthropogenic REE input. While both rivers carry significant loads of anthropogenic Gd, originating from contrast agents used for magnetic resonance imaging, the Rhine River also carries large amounts of anthropogenic La and lately Sm which are discharged into the river from an industrial point source. Here, we assess the bioavailability of these anthropogenic microcontaminants in these rivers by analyzing the aragonitic shells of the freshwater bivalve Corbicula fluminea. Concentrations of purely geogenic REE in shells of comparable size cover a wide range of about one order of magnitude between different sampling sites. At a given sampling site, geogenic REE concentrations depend on shell size, i.e. mussel age. Although both rivers show large positive Gd anomalies in their dissolved loads, no anomalous enrichment of Gd relative to the geogenic REE can be observed in any of the analyzed shells. This indicates that the speciations of geogenic and anthropogenic Gd in the river water differ from each other and that the geogenic, but not the anthropogenic Gd is incorporated into the shells. In contrast, all shells sampled at sites downstream of the industrial point source of anthropogenic La and Sm in the Rhine River show positive La and Sm anomalies, revealing that these anthropogenic REE are bioavailable. Only little is known about the effects of long-term exposure to dissolved REE and their general ecotoxicity, but considering that anthropogenic Gd and even La have already been identified in German tap water and that anthropogenic La and Sm are bioavailable, this should be monitored and investigated further. Copyright © 2015 Elsevier B.V. All rights reserved.

Concentrations and annual fluxes of sediment-associated chemical constituents from conterminous US coastal rivers using bed sediment data

USGS Publications Warehouse

Horowitz, Arthur J.; Stephens, Verlin C.; Elrick, Kent A.; Smith, James J.

2012-01-01

Coastal rivers represent a significant pathway for the delivery of natural and anthropogenic sediment-associated chemical constituents to the Atlantic, Pacific and Gulf of Mexico coasts of the conterminous USA. This study entails an accounting segment using published average annual suspended sediment fluxes with published sediment-associated chemical constituent concentrations for (1) baseline, (2) land-use distributions, (3) population density, and (4) worldwide means to estimate concentrations/annual fluxes for trace/major elements and total phosphorus, total organic and inorganic carbon, total nitrogen, and sulphur, for 131 coastal river basins. In addition, it entails a sampling and subsequent chemical analysis segment that provides a level of ‘ground truth’ for the calculated values, as well as generating baselines for sediment-associated concentrations/fluxes against which future changes can be evaluated. Currently, between 260 and 270 Mt of suspended sediment are discharged annually from the conterminous USA; about 69% is discharged from Gulf rivers (n = 36), about 24% from Pacific rivers (n = 42), and about 7% from Atlantic rivers (n = 54). Elevated sediment-associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges:Atlantic rivers (49%)>Pacific rivers (40%)>Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Hg, Pb, Zn) frequently occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated carbon and nutrient concentrations occur along both the Atlantic and Gulf coasts but are dominated by rivers in the urban northeast and by southeastern and Gulf coast (Florida) ‘blackwater’ streams. Elevated Ca, Mg, K, and Na distributions tend to reflect local petrology, whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have substantial natural as well as anthropogenic sources. Almost all the elevated sediment-associated chemical concentrations found in conterminous US coastal rivers are lower than worldwide averages.

Water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin; major and trace elements in water, sediment, and biota, 1978-90

USGS Publications Warehouse

Fitzpatrick, F.A.; Scudder, B.C.; Crawford, J.K.; Schmidt, A.R.; Sieverling, J.B.

1995-01-01

The distribution of 22 major and trace elements was examined in water, sediment, and biota in the upper Illinois River Basin in Illinois, Indiana, and Wisconsin as part of a pilot National Water-Quality Assessment project done by the U.S. Geological Survey from 1987 through 1990. The 22 elements are aluminum, antimony, arsenic, barium, beryllium, boron, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, molybdenum, nickel, phosphorus, selenium, silver, strontium, vanadium, and zinc. Concentrations of U.S. Environmental Protection Agency (USEPA) priority pollutants among the 22 elements were elevated in the Chicago area in all three aquatic components (water, sediment, and biota). Further, some of the priority pollutants also were found at elevated concentrations in biota in agricultural areas in the basin. Cadmium, chromium, copper, iron, lead, mercury, silver, and zinc concentrations in water exceeded USEPA acute or chronic water-quality criteria at several sites in the Chicago area. Correlations among concentra- tions of elements in water, sediment, and biota were found, but the correlation analysis was hindered by the large proportion of observations less than the minimum reporting level in water. Those sites where water-quality criteria were sometimes exceeded were not always the same sites where concentrations in biota were the largest. This relation indicates that accumulation of these pollutants in biota is confounded by complex geochemical and biological processes that differ throughout the upper Illinois River Basin.

Concentration distribution and assessment of several heavy metals in sediments of west-four Pearl River Estuary

NASA Astrophysics Data System (ADS)

Wang, Shanshan; Cao, Zhimin; Lan, Dongzhao; Zheng, Zhichang; Li, Guihai

2008-09-01

Grain size parameters, trace metals (Co, Cu, Ni, Pb, Cr, Zn, Ba, Zr and Sr) and total organic matter (TOM) of 38 surficial sediments and a sediment core of west-four Pearl River Estuary region were analyzed. The spacial distribution and the transportation procession of the chemical element in surficial sediments were studied mainly. Multivariate statistics are used to analyses the interrelationship of metal elements, TOM and the grain size parameters. The results demonstrated that terrigenous sediment taken by the rivers are main sources of the trace metal elements and TOM, and the lithology of parent material is a dominating factor controlling the trace metal composition in the surficial sediment. In addition, the hydrodynamic condition and landform are the dominating factors controlling the large-scale distribution, while the anthropogenic input in the coastal area alters the regional distribution of heavy metal elements Co, Cu, Ni, Pb, Cr and Zn. The enrichment factor (EF) analysis was used for the differentiation of the metal source between anthropogenic and naturally occurring, and for the assessment of the anthropogenic influence, the deeper layer content of heavy metals were calculated as the background values and Zr was chosen as the reference element for Co, Cu, Ni, Pb, Cr and Zn. The result indicate prevalent enrichment of Co, Cu, Ni, Pb and Cr, and the contamination of Pb is most obvious, further more, the peculiar high EF value sites of Zn and Pb probably suggest point source input.

Sediment quality in the north coastal basin of Massachusetts, 2003

USGS Publications Warehouse

Breault, Robert F.; Ashman, Mary S.; Heath, Douglas

2004-01-01

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, completed a reconnaissance-level study of bottom-sediment quality in selected lakes, rivers, and estuaries in the North Coastal Basin of Massachusetts. Bottom-sediment grab samples were collected from 20 sites in the North River, Lake Quannapowitt, Saugus River, Mill River, Shute Brook, Sea Plane Basin, Pines River, and Bear Creek. The samples were tested for various types of potentially harmful contaminants? including 33 elements, 17 polyaromatic hydrocarbons (PAHs), 22 organochlorine pesticides, and 7 polychlorinated biphenyl (PCB) mixtures (Aroclors)?to benthic organisms (bottom-dwelling) and humans. The results were compared among sampling sites, to background concentrations, and to concen-trations measured in other urban rivers, and sediment-quality guidelines were used to predict toxicity at the sampling sites to benthic organisms and humans. Because there are no standards for human toxicity for aquatic sediment, standards for contaminated upland soil were used. Contaminant concentrations measured in sediment collected from the North Coastal Basin generally were equal to or greater than concentrations in sediment from uncontaminated rivers throughout New England. Contaminants in North Coastal Basin sediment with elevated concentrations (above back-ground levels) included arsenic, chromium, copper, lead, nickel, and zinc, some of the PAHs, dichlorodiphenyltrichloro-ethane (DDT) and its metabolites, and dieldrin. No PCBs were measured above the detection limits. Measured concentrations of arsenic, chromium, and lead were also generally greater than those measured in other urban rivers throughout the conter-minous United States. With one exception (arsenic), local con-centrations measured in sediment samples collected from the North Coastal Basin were lower than concentrations measured in sediment collected from two of three urban rivers draining to Boston Harbor. The probable toxicity to benthic organisms ranged from about 33 to 91 percent across the study area. Of the elements analyzed, antimony, arsenic, beryllium, and lead exceeded the soil standards for risk to human health. Of the PAHs analyzed, four also exceeded soil standards. Organochlorine pesticide concentrations, however, were not high enough relative to the soil standards to pose a risk to human health. Some trace element and some organic compound concentrations in bottom sediment may be toxic to aquatic organisms and may pose a risk to human health.

Analysis of discontinuities across thin inhomogeneities, groundwater/surface water interactions in river networks, and circulation about slender bodies using slit elements in the Analytic Element Method

USDA-ARS?s Scientific Manuscript database

Groundwater and surface water contain interfaces across which hydrologic functions are discontinuous. Thin elements with high hydraulic conductivity in a porous media focus groundwater, which flows through such inhomogeneities and causes an abrupt change in stream function across their interfaces, a...

Agro-ecological analysis for the EU water framework directive: an applied case study for the river contract of the Seveso basin (Italy).

PubMed

Bocchi, Stefano; La Rosa, Daniele; Pileri, Paolo

2012-10-01

The innovative approach to the protection and management of water resources at the basin scale introduced by the European Union water framework directive (WFD) requires new scientific tools. WFD implementation also requires the participation of many stakeholders (administrators, farmers and citizens) with the aim of improving the quality of river waters and basin ecosystems through cooperative planning. This approach encompasses different issues, such as agro-ecology, land use planning and water management. This paper presents the results of a methodology suggested for implementing the WFD in the case of the Seveso river contract in Italy, one of the recent WFD applications. The Seveso basin in the Lombardy region has been one of the most rapidly urbanizing areas in Italy over the last 50 years. First, land use changes in the last 50 years are assessed with the use of historical aerial photos. Then, elements of an ecological network along the river corridor are outlined, and different scenarios for enhancing existing ecological connections are assessed using indicators from graph theory. These scenarios were discussed in technical workshops with involved stakeholders of the river contract. The results show a damaged rural landscape, where urbanization processes have decimated the system of linear green features (hedges/rows). Progressive reconnections of some of the identified network nodes may significantly increase the connectivity and circuitry of the study area.

Organic Geochemistry of Sediments in Nearshore Areas of the Mississippi and Atchafalaya Rivers: I. General Organic Characterization

USGS Publications Warehouse

Orem, William H.; Rosenbauer, Robert J.; Swarzenski, Peter W.; Lerch, Harry E.; Corum, Margo D.; Bates, Anne L.

2007-01-01

This report presents results on the general organic characteristics of sediment cores collected from the coastal zone of the Mississippi River system, including distributions of the important nutrient elements (C, N, P, and S). This was part of a larger study conducted from 2001-2005 to examine the delivery of sediment-associated contaminants to the Gulf of Mexico by the Mississippi River system, funded by the USGS Coastal and Marine Geology Program. Companion reports emphasize organic contaminants (Rosenbauer and others, 2006), and metals (Swarzenski and others, 2006). The level of contamination within the deltaic system of the Mississippi River system was determined through the collection of sediment cores from interdistributary bays, and offshore in the Gulf of Mexico, including the zone of hypoxia. Results provide the basis for reconstructing contaminant inventories from which to develop historic perspectives on nutrient loading and hypoxia, and to better understand how sediment-hosted contaminants either directly or indirectly move through biota and ultimately affect ecosystem health. Concentrations of C, N, P, and S in sediments varied by a factor of 10 between sites, and in down core profiles. Nearshore cores collected in 2001 proved to have erratic downcore C, N, P, and S profiles and sediment deposition rates, suggesting a high energy regime controlled more by variability in river flow rather than by geochemical processes and reactions within the system. These results focused further coring activities further offshore. Atomic C/N ratios suggest that organic matter deposited at all sites is a mix of microbial (algal) and terrestrial (vascular plant) remains, but with algal material dominant. Concentrations of total sulfur in sediments from cores in the zone of hypoxia were often higher than those in nearby zones with oxic water columns. Corresponding atomic C/S ratios were typically lower in sediments from sites in the zone of hypoxia compared to nearby sites with oxic water columns, and thus atomic C/S values may be useful as a proxy for identifying sites impacted by hypoxic conditions in the water column and for examining historical trends in hypoxia. At one site examined in this study, maximum hypoxic conditions were observed in the mid 1960's. The organic elemental composition (C, N, P, and S) of sediments was also used to guide sample selection for contaminant analysis, and to normalize the contaminant data to organic C content of the sediments. Dissolved hydrocarbon gases in sediments showed a dominance of methane, but identifiable concentrations of ethane and hexane, and trace concentrations of propane, butane, and pentane were also detected. All dissolved gases except hexane were dominated by 'bound' gas, gas released only after agitation of the sediment in a blender. Hexane, in contrast was observed mostly as free gas, determined by headspace analysis.

Mixing zone hydrodynamics in a large confluence: a case study of the Snake and Clearwater Rivers confluence

NASA Astrophysics Data System (ADS)

Shehata, M. M.; Petrie, J.

2015-12-01

Confluences are a basic component in all fluvial systems, which are often characterized by complex flow and sediment transport patterns. Addressing confluences, however, started only recently in parallel with new advances of flow measurement tools and computational techniques. A limited number of field studies exist investigating flow hydrodynamics through confluences, particularly for large confluences with central zone widths of 100 m or greater. Previous studies have indicated that the size of the confluent rivers and the post-confluence zone may impact flow and sediment transport processes in the confluence zone, which consequently could impact the biodiversity within the river network. This study presents the results of a field study conducted at the confluence of the Snake and the Clearwater rivers near the towns of Clarkston, WA and Lewiston, ID (average width of 700 m at the confluence center). This confluence supports many different and, sometimes, conflicting purposes including commercial navigation, recreation, and fish and wildlife conservation. The confluence properties are affected by dredging operations carried out periodically to maintain the minimum water depth required for safe flow conveyance and navigation purposes. Also, a levee system was constructed on the confluence banks as an extra flood control measure. In the recent field work, an Acoustic Doppler Current Profiler was used to measure water velocity profiles at cross sections in the confluence region. Fixed and moving vessel measurements were taken at selected locations to evaluate both the spatial and temporal variation in velocity throughout the confluence. The confluence bathymetry was surveyed with a multi-beam sonar to investigate existent bed morphological elements. The results identify the velocity pattern in the mixing zone between the two rivers. The present findings are compared to previous studies on small confluences to demonstrate the influence of scale on flow processes.

Occurrence, distribution, and transport of pesticides, trace elements, and selected inorganic constituents into the Salton Sea Basin, California, 2001-2002

USGS Publications Warehouse

LeBlanc, Lawrence A.; Schroeder, Roy A.; Orlando, James L.; Kuivila, Kathyrn M.

2004-01-01

A study of pesticide distribution and transport within the Salton Sea Basin, California, was conducted from September 2001 to October 2002. Sampling for the study was done along transects for the three major rivers that flow into the Salton Sea Basin: the New and Alamo Rivers at the southern end of the basin and the Whitewater River at the northern end. Three stations were established on each river: an outlet station approximately 1 mile upstream of the river discharge, a near-shore station in the river delta, and off-shore station in the Salton Sea. Water and suspended and bed sediments were collected at each station in October 2001, March-April 2002, and September 2002, coinciding with peak pesticide applications in the fall and spring. Fourteen current-use pesticides were detected in the water column. Concentrations of dissolved pesticides typically decreased from the outlets to the sea in all three rivers, consistent with the off-shore transport of pesticides from the rivers to the sea. Dissolved concentrations ranged from the limits of detection to 151 nanograms per liter (ng/L); however, diazinon, eptam (EPTC), and malathion were detected at much higher concentrations (940?3,830 ng/L) at the New and Alamo River outlet and near-shore stations. Concentrations of carbaryl, dacthal, diazinon, and eptam were higher during the two fall sampling periods, whereas concentrations of atrazine, carbofuran, and trifluralin were higher during the spring. Current-use pesticides also were detected on suspended and bed sediments in concentrations ranging from method detection limits to 106 ng/g (nanograms per gram). Chlorpyrifos, dacthal, eptam, trifluralin, and DDE were the most frequently detected pesticides on sediments from all three rivers. The number and concentrations of pesticides associated with suspended sediments frequently were similar for the river outlet and near-shore sites, consistent with the downstream transport of sediment-associated pesticides out of the rivers. Seasonal trends in pesticide concentration were similar to those for dissolved concentrations in fall 2001 and spring 2002, but not in fall 2002. Generally, the pesticides detected in the suspended sediments were the same pesticides detected in the bed sediments, and concentrations were similar, especially at the Alamo River outlet site in spring 2002 and fall 2002. Pesticides generally were not detected in sediments from the off-shore sites; however, the samples from these sites also had greater incidences of matrix interference during analysis. Sediment-associated pesticide concentrations were above equilibrium in water, suggesting a bound fraction of sediment-associated pesticides that are resistant to desorption. Concentrations of trace elements and other inorganic constituents in suspended sediments collected during the fall 2001 followed expected trends with dilution of river-derived minerals owing to highly organic autochthonous production within the Salton Sea Basin. However, calculation of enrichment ratios provided evidence for the bioconcentration of several trace elements, notably selenium in the off-shore biota.

Interaction of the sea breeze with a river breeze in an area of complex coastal heating

NASA Technical Reports Server (NTRS)

Zhong, Shiyuan; Takle, Eugene S.; Leone, John M., Jr.

1991-01-01

The interaction of the sea-breeze circulation with a river-breeze circulation in an area of complex coastal heating (east coast of Florida) was studied using a 3D finite-element mesoscale model. The model simulations are compared with temperature and wind fields observed on a typical fall day during the Kennedy Space Center Atmospheric Boundary Layer Experiment. The results from numerical experiments designed to isolate the effect of the river breeze indicate that the convergence in the sea-breeze front is suppressed when it passes over the cooler surface of the rivers.

SLURRY MIX EVAPORATOR BATCH ACCEPTABILITY AND TEST CASES OF THE PRODUCT COMPOSITION CONTROL SYSTEM WITH THORIUM AS A REPORTABLE ELEMENT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, T.

2010-10-07

The Defense Waste Processing Facility (DWPF), which is operated by Savannah River Remediation, LLC (SRR), has recently begun processing Sludge Batch 6 (SB6) by combining it with Frit 418 at a nominal waste loading (WL) of 36%. A unique feature of the SB6/Frit 418 glass system, as compared to the previous glass systems processed in DWPF, is that thorium will be a reportable element (i.e., concentrations of elemental thorium in the final glass product greater than 0.5 weight percent (wt%)) for the resulting wasteform. Several activities were initiated based upon this unique aspect of SB6. One of these was anmore » investigation into the impact of thorium on the models utilized in DWPF's Product Composition and Control System (PCCS). While the PCCS is described in more detail below, for now note that it is utilized by Waste Solidification Engineering (WSE) to evaluate the acceptability of each batch of material in the Slurry Mix Evaporator (SME) before this material is passed on to the melter. The evaluation employs models that predict properties associated with processability and product quality from the composition of vitrified samples of the SME material. The investigation of the impact of thorium on these models was conducted by Peeler and Edwards [1] and led to a recommendation that DWPF can process the SB6/Frit 418 glass system with ThO{sub 2} concentrations up to 1.8 wt% in glass. Questions also arose regarding the handling of thorium in the SME batch acceptability process as documented by Brown, Postles, and Edwards [2]. Specifically, that document is the technical bases of PCCS, and while Peeler and Edwards confirmed the reliability of the models, there is a need to confirm that the current implementation of DWPF's PCCS appropriately handles thorium as a reportable element. Realization of this need led to a Technical Task Request (TTR) prepared by Bricker [3] that identified some specific SME-related activities that the Savannah River National Laboratory (SRNL) was requested to conduct. SRNL issued a Task Technical and Quality Assurance (TT&QA) plan [4] in response to the SRR request. The conclusions provided in this report are that no changes need to be made to the SME acceptability process (i.e., no modifications to WSRC-TR-95-00364, Revision 5, are needed) and no changes need to be made to the Product Composition Control System (PCCS) itself (i.e. the spreadsheet utilized by Waste Solidification Engineering (WSE) for acceptability decisions does not require modification) in response to thorium becoming a reportable element for DWPF operations. In addition, the inputs and results for the two test cases requested by WSE for use in confirming the successful activation of thorium as a reportable element for DWPF operations during the processing of SB6 are presented in this report.« less

Assessment of the Effectiveness and Effects of Land Disposal Methodologies of Waste Water Management.

DTIC Science & Technology

1972-01-14

conditions that inhibit nitrification should be avoided. Potassium: Potassium is a very mobile and dynamic element in both soil and plant systems. It...deposits from aerial sources. I i conclusion, lead is fixed in soils and not readily mobilized . Soils should retain several hundred mg/i against leaching...is one of these. These are relatively large molecules and are strongly retained by river muds, etc. They can be expected to be of very limited mobility

Integrating Water Quality and River Rehabilitation Management - A Decision-Analytical Perspective

NASA Astrophysics Data System (ADS)

Reichert, P.; Langhans, S.; Lienert, J.; Schuwirth, N.

2009-04-01

Integrative river management involves difficult decisions about alternative measures to improve their ecological state. For this reason, it seems useful to apply knowledge from the decision sciences to support river management. We discuss how decision-analytical elements can be employed for designing an integrated river management procedure. An important aspect of this procedure is to clearly separate scientific predictions of the consequences of alternatives from objectives to be achieved by river management. The key elements of the suggested procedure are (i) the quantitative elicitation of the objectives from different stakeholder groups, (ii) the compilation of the current scientific knowledge about the consequences of the effects resulting from suggested measures in the form of a probabilistic mathematical model, and (iii) the use of these predictions and valuations to prioritize alternatives, to uncover conflicting objectives, to support the design of better alternatives, and to improve the transparency of communication about the chosen management strategy. The development of this procedure led to insights regarding necessary steps to be taken for rational decision-making in river management, to guidelines about the use of decision-analytical techniques for performing these steps, but also to new insights about the application of decision-analytical techniques in general. In particular, the consideration of the spatial distribution of the effects of measures and the potential added value of connected rehabilitated river reaches leads to favoring measures that have a positive effect beyond a single river reach. As these effects only propagate within the river network, this results in a river basin oriented management concept as a consequence of a rational decision support procedure, rather than as an a priori management paradigm. There are also limitations to the support that can be expected from the decision-analytical perspective. It will not provide the societal values that are driving prioritization in river management, it will only support their elicitation and rational use. This is particularly important for the assessment of micro-pollutants because of severe limitations in scientific knowledge of their effects on river ecosystems. This makes the influence of pollution by micro-pollutants on prioritization of measures strongly dependent on the weight of the precautionary principle relative to other societal objectives of river management.

Improving governance action by an advanced water modelling system applied to the Po river basin in Italy

NASA Astrophysics Data System (ADS)

Alessandrini, Cinzia; Del Longo, Mauro; Pecora, Silvano; Puma, Francesco; Vezzani, Claudia

2013-04-01

In spite of the historical abundance of water due to rains and to huge storage capacity provided by alpine lakes, Po river basin, the most important Italian water district experienced in the past ten years five drought/water scarcity events respectively in 2003, 2006, 2007 and 2012 summers and in the 2011-2012 winter season. The basic approach to these crises was the observation and the post-event evaluation; from 2007 an advanced numerical modelling system, called Drought Early Warning System for the Po River (DEWS-Po) was developed, providing advanced tools to simulate the hydrological and anthropic processes that affect river flows and allowing to follow events with real-time evaluations. In early 2012 the same system enabled also forecasts. Dews-Po system gives a real-time representation of water distribution across the basin, characterized by high anthropogenic pressure, optimizing with specific tools water allocation in competing situations. The system represents an innovative approach in drought forecast and in water resource management in the Po basin, giving deterministic and probabilistic meteorological forecasts as input to a chain for numerical distributed modelling of hydrological and hydraulic simulations. The system architecture is designed to receive in input hydro-meteorological actually observed and forecasted variables: deterministic meteorological forecasts with a fifteen days lead time, withdrawals data for different uses, natural an artificial reservoirs storage and release data. The model details are very sharp, simulating also the interaction between Adriatic sea and Po river in the delta area in terms of salt intrusion forecasting. Calculation of return period through run-method and of drought stochastic-indicators are enabled to assess the characteristics of the on-going and forecasted event. An Inter-institutional Technical Board is constituted within the Po River Basin Authority since 2008 and meets regularly during water crises to act decisions regarding water management in order to prevent major impacts. The Board is made of experts from public administrations with a strong involvement of stakeholders representative of different uses. The Dews- Po was intensively used by the Technical Board as decision support system during the 2012 summer event, providing tools to understand the on-going situation of water availability and use across the basin, helping to evaluate water management choices in an objective way, through what-if scenarios considering withdrawals reduction and increased releases from regulated Alpine lakes. A description of the use of Dews- Po system within the Technical Board is given, especially focusing on those elements, prone to be considered "good management indicators", which proved to be most useful in ensuring the success of governance action. Strength and improvement needs of the system are then described

Content and distribution of trace metals in pristine permafrost environments of Northeastern Siberia, Russia

NASA Astrophysics Data System (ADS)

Antcibor, I.; Eschenbach, A.; Kutzbach, L.; Bolshiyanov, D.; Pfeiffer, E.-M.

2012-04-01

Arctic regions are one of the most sensitive areas with respect to climatic changes and human impacts. Research is required to discover how the function of permafrost soils as a buffering system for metal pollutants could change in response to the predicted changes. The goal of this work is to determine the background levels of trace metals in the pristine arctic ecosystems of the Lena River Delta in Northeastern Siberia and to evaluate the possible effect of human impacts on this arctic region. The Lena River Delta represents areas with different dominating geomorphologic processes that can generally be divided between accumulation and erosion sites. Frequent changes of the river water level create different periods of sedimentation and result in the formation of stratified soils and sediment layers which are dominated either by mineral substrates with allochthonous organic matter or pure autochthonous peat. The deposited sediments that have formed the delta islands are mostly composed of sand fractions; therefore the buffering effects of clay materials can be neglected. Samoylov Island is representative of the south-central and eastern modern delta surfaces of the Lena River Delta and is selected as a pilot study site. We determined total element contents of Fe, Mn, Zn, Cd, Ni, Cu, As, Pb, Co and Hg in soil horizons from different polygonal elevated rims, polygonal depressed centers and the middle floodplain. High gravimetric concentrations (related to dry mass of soil material) of Mn and Fe are found within all soil profiles and vary from 0.14 to 1.39 g kg-1 and from 10.7 to 41.2 g kg-1, respectively. While the trace element concentrations do not exceed typical crustal abundances, the maximum values of most of the metals are observed within the soil profile situated at the middle floodplain. This finding suggests that apart from the parent material the second potential source of trace metals is due to allochthonous substance input during annual flooding of the middle floodplain. Correlation analysis between element concentrations, grain-size distribution and carbon content revealed a direct dependence of the element distribution within all soil profiles on its mineralogical composition. Based on the obtained results we suggest that there are negligible atmospheric depositions caused by human activity on the investigation site. Therefore this data can provide a point of comparison against man-made influences on permafrost-affected landscapes and also on similar pristine areas in the Arctic region.

Trace elements and organic compounds in streambed sediment and aquatic biota from the Sacramento River Basin, California, October and November 1995

USGS Publications Warehouse

MacCoy, Dorene E.; Domagalski, Joseph L.

1999-01-01

Elevated levels of trace elements and hydrophobic organic compounds were detected in streambed sediments and aquatic biota [Asiatic clam (Corbicula fluminea) or bottom-feeding fish] of the Sacramento River Basin, California, during October and November 1995. Trace elements detected included cadmium, copper, mercury, lead, and zinc. Elevated levels of cadmium, copper, and zinc in the upper Sacramento River are attributed to a mining land use, and elevated levels of zinc and lead in an urban stream, and possibly in the lower Sacramento River, are attributed to urban runoff processes. Elevated levels of mercury in streambed sediment are attributed to either past mercury mining or to the use of mercury in past gold mining operations. Mercury mining was an important land use within the Coast Ranges in the past and gold mining was an important land use of the Sierra Nevada in the past. Mercury was the only trace element found in elevated levels in the tissue of aquatic biota, and those levels also could be attributed to either mining or urban runoff. Hydrophobic organic compounds also were detected in streambed sediments and aquatic biota. The most frequently detected compounds were DDT and its breakdown products, dieldrin, oxychlordane, and toxaphene. Differences were found in the types of compounds detected at agricultural sites and the urban site. Although both types of sites had measurable concentrations of DDT or its breakdown products, the urban site also had measurable concentrations of pesticides used for household pest control. Few semivolatile compounds were detected in the streambed sediments of any site. The semivolatile compound p-cresol, a coal-tar derivative associated with road maintenance, was found in the highest concentration.

Mercury speciation, fluxes, and fate in the volcanically acidified fluids of Copahue volcano, Argentina

NASA Astrophysics Data System (ADS)

Kading, T.; Varekamp, J. C.; Andersson, M.; Balcom, P.; Mason, R. P.

2010-12-01

The behavior of mercury in volcanic acid springs and acidified rivers is poorly known, despite the potential impact this vector of contamination has on local surface and ground water quality. Mercury was measured in a volcanically acidified river system (pH<1 - 3), the Rio Agrio in the Neuquen province of Argentina, which discharges into a large glacial lake (Lake Caviahue, pH 2.2-3.0). The Hg concentration ranged from 2 - 600 pM throughout the fluvial system. Mercury in the hot, hyperacidic source fluids was dominated by dissolved ionic species, with only 2% of total mercury as dissolved elemental mercury, and 11% being particulate bound. The Hg flux from the volcano, determined from river water flux measurements and Hg concentrations, was modest and varied between the 3/2008 and 3/2009 sampling campaigns resp. from 0.7 to 1.1 moles/year. The Hg:S ratio of the acid fluids was ~10-8, several orders of magnitude lower than that typically found in volcanic plumes and fumaroles. The small Hg flux and low Hg:S values suggest that the system is either inherently Hg-poor or has lost Hg through vapor loss deeper in the hydrothermal system. Support for the latter comes from high Hg concentrations in geothermal vents and mudpots on the flank of the mountain (24 - 55 ppm Hg). Mercury concentrations decreased conservatively downstream in the river as based on Hg/Cl and Hg/SO4. Non-conservative depletion occurs in the less acidic Lake Caviahue, suggesting that mercury is removed from the water column by sorption to organic matter or other phases. Mercury analyses of a short lake sediment core confirm this (Hg = 0.01 to 0.70 ppm). No evidence was found for preferential uptake of mercury by jarosite, schwertmannite, or goethite, although the latter two phases precipitate in the most distal and Hg-depleted section of the fluvial system.

Publications - GMC 411 | Alaska Division of Geological & Geophysical

Science.gov Websites

outcrop samples from the 2001 DGGS Salcha River-Pogo project, Big Delta Quadrangle, Alaska Authors . Quadrangle(s): Big Delta Bibliographic Reference Newberry, R.J., 2012, Whole-rock and trace element analyses of two amphibolite outcrop samples from the 2001 DGGS Salcha River-Pogo project, Big Delta Quadrangle

Hydrology of area 25, Eastern Region, Interior Coal Province, Illinois

USGS Publications Warehouse

Zuehls, E.E.; Ryan, G.L.; Peart, D.B.; Fitzgerald, K.K.

1981-01-01

The eastern region of the Interior Coal Province has been divided into 11 hydrologic study areas. Area 25, located in west-central Illinois, includes the Spoon River and small tributaries to the Illinois River. Pennsylvanian age rocks underlie most of the study area. Illinois, with the largest reserves of bituminous coal, is second only to Montana in total coal reserves. Loess soils cover most of the study area. Agriculture is the dominant land use. Surface water provides 97% of all the water used. Precipitation averages 34 to 35 inches. Water-quality data has been collected at over 31 sites. Analysis for specific conductance, pH, alkalinity, iron, manganese, sulfate and many trace elements and other water-quality constituents have been completed. These data are available from computer storage through the National Water Data Storage and Retrieval System (WATSTORE). (USGS)

Identifying structural elements needed for development of a predictive life-history model for pallid and shovelnose sturgeons

USGS Publications Warehouse

Wildhaber, Mark L.; DeLonay, A.J.; Papoulias, D.M.; Galat, D.L.; Jacobson, R.B.; Simpkins, D.G.; Braaten, P.J.; Korschgen, C.E.; Mac, M.J.

2011-01-01

Intensive management of the Missouri and Mississippi Rivers has resulted in dramatic changes to the river systems and their biota. These changes have been implicated in the decline of the pallid sturgeon (Scaphirhynchus albus), which has been listed as a United States federal endangered species. The sympatric shovelnose sturgeon (S. platorynchus) is more common and widespread but has also been in decline. The decline of pallid sturgeon is considered symptomatic of poor reproductive success and low or no recruitment. In order to organize information about these species and provide a basis for future development of a predictive model to help guide recovery efforts, we present an expert-vetted, conceptual life-history framework that incorporates the factors that affect reproduction, growth, and survival of shovelnose and pallid sturgeons.

The Saale-Project -A multidisciplinary approach towards sustainable integrative catchment management -

NASA Astrophysics Data System (ADS)

Bongartz, K.; Flügel, W. A.

2003-04-01

In the joint research project “Development of an integrated methodology for the sustainable management of river basins The Saale River Basin example”, coordinated by the Centre of Environmental Research (UFZ), concepts and tools for an integrated management of large river basins are developed and applied for the Saale river basin. The ultimate objective of the project is to contribute to the holistic assessment and benchmarking approaches in water resource planning, as required by the European Water Framework Directive. The study presented here deals (1) with the development of a river basin information and modelling system, (2) with the refinement of a regionalisation approach adapted for integrated basin modelling. The approach combines a user friendly basin disaggregation method preserving the catchment’s physiographic heterogeneity with a process oriented hydrological basin assessment for scale bridging integrated modelling. The well tested regional distribution concept of Response Units (RUs) will be enhanced by landscape metrics and decision support tools for objective, scale independent and problem oriented RU delineation to provide the spatial modelling entities for process oriented and distributed simulation of vertical and lateral hydrological transport processes. On basis of this RUs suitable hydrological modelling approaches will be further developed with strong respect to a more detailed simulation of the lateral surface and subsurface flows as well as the channel flow. This methodical enhancement of the well recognised RU-concept will be applied to the river basin of the Saale (Ac: 23 179 km2) and validated by a nested catchment approach, which allows multi-response-validation and estimation of uncertainties of the modelling results. Integrated modelling of such a complex basin strongly influenced by manifold human activities (reservoirs, agriculture, urban areas and industry) can only be achieved by coupling the various modelling approaches within a well defined model framework system. The latter is interactively linked with a sophisticated geo-relational database (DB) serving all research teams involved in the project. This interactive linkage is a core element comprising an object-oriented, internet-based modelling framework system (MFS) for building interdisciplinary modelling applications and offering different analysis and visualisation tools.

Iowa Flood Information System: Towards Integrated Data Management, Analysis and Visualization

NASA Astrophysics Data System (ADS)

Demir, I.; Krajewski, W. F.; Goska, R.; Mantilla, R.; Weber, L. J.; Young, N.

2012-04-01

The Iowa Flood Information System (IFIS) is a web-based platform developed by the Iowa Flood Center (IFC) to provide access to flood inundation maps, real-time flood conditions, flood forecasts both short-term and seasonal, flood-related data, information and interactive visualizations for communities in Iowa. The key element of the system's architecture is the notion of community. Locations of the communities, those near streams and rivers, define basin boundaries. The IFIS provides community-centric watershed and river characteristics, weather (rainfall) conditions, and streamflow data and visualization tools. Interactive interfaces allow access to inundation maps for different stage and return period values, and flooding scenarios with contributions from multiple rivers. Real-time and historical data of water levels, gauge heights, and rainfall conditions are available in the IFIS by streaming data from automated IFC bridge sensors, USGS stream gauges, NEXRAD radars, and NWS forecasts. Simple 2D and 3D interactive visualizations in the IFIS make the data more understandable to general public. Users are able to filter data sources for their communities and selected rivers. The data and information on IFIS is also accessible through web services and mobile applications. The IFIS is optimized for various browsers and screen sizes to provide access through multiple platforms including tablets and mobile devices. The IFIS includes a rainfall-runoff forecast model to provide a five-day flood risk estimate for around 500 communities in Iowa. Multiple view modes in the IFIS accommodate different user types from general public to researchers and decision makers by providing different level of tools and details. River view mode allows users to visualize data from multiple IFC bridge sensors and USGS stream gauges to follow flooding condition along a river. The IFIS will help communities make better-informed decisions on the occurrence of floods, and will alert communities in advance to help minimize damage of floods. This presentation provides an overview and live demonstration of the tools and interfaces in the IFIS developed to date to provide a platform for one-stop access to flood related data, visualizations, flood conditions, and forecast.

Iowa Flood Information System

NASA Astrophysics Data System (ADS)

Demir, I.; Krajewski, W. F.; Goska, R.; Mantilla, R.; Weber, L. J.; Young, N.

2011-12-01

The Iowa Flood Information System (IFIS) is a web-based platform developed by the Iowa Flood Center (IFC) to provide access to flood inundation maps, real-time flood conditions, flood forecasts both short-term and seasonal, flood-related data, information and interactive visualizations for communities in Iowa. The key element of the system's architecture is the notion of community. Locations of the communities, those near streams and rivers, define basin boundaries. The IFIS provides community-centric watershed and river characteristics, weather (rainfall) conditions, and streamflow data and visualization tools. Interactive interfaces allow access to inundation maps for different stage and return period values, and flooding scenarios with contributions from multiple rivers. Real-time and historical data of water levels, gauge heights, and rainfall conditions are available in the IFIS by streaming data from automated IFC bridge sensors, USGS stream gauges, NEXRAD radars, and NWS forecasts. Simple 2D and 3D interactive visualizations in the IFIS make the data more understandable to general public. Users are able to filter data sources for their communities and selected rivers. The data and information on IFIS is also accessible through web services and mobile applications. The IFIS is optimized for various browsers and screen sizes to provide access through multiple platforms including tablets and mobile devices. The IFIS includes a rainfall-runoff forecast model to provide a five-day flood risk estimate for around 500 communities in Iowa. Multiple view modes in the IFIS accommodate different user types from general public to researchers and decision makers by providing different level of tools and details. River view mode allows users to visualize data from multiple IFC bridge sensors and USGS stream gauges to follow flooding condition along a river. The IFIS will help communities make better-informed decisions on the occurrence of floods, and will alert communities in advance to help minimize damage of floods. This presentation provides an overview of the tools and interfaces in the IFIS developed to date to provide a platform for one-stop access to flood related data, visualizations, flood conditions, and forecast.

Flood Risk Management in Iowa through an Integrated Flood Information System

NASA Astrophysics Data System (ADS)

Demir, Ibrahim; Krajewski, Witold

2013-04-01

The Iowa Flood Information System (IFIS) is a web-based platform developed by the Iowa Flood Center (IFC) to provide access to flood inundation maps, real-time flood conditions, flood forecasts both short-term and seasonal, flood-related data, information and interactive visualizations for communities in Iowa. The key element of the system's architecture is the notion of community. Locations of the communities, those near streams and rivers, define basin boundaries. The IFIS provides community-centric watershed and river characteristics, weather (rainfall) conditions, and streamflow data and visualization tools. Interactive interfaces allow access to inundation maps for different stage and return period values, and flooding scenarios with contributions from multiple rivers. Real-time and historical data of water levels, gauge heights, and rainfall conditions are available in the IFIS by streaming data from automated IFC bridge sensors, USGS stream gauges, NEXRAD radars, and NWS forecasts. Simple 2D and 3D interactive visualizations in the IFIS make the data more understandable to general public. Users are able to filter data sources for their communities and selected rivers. The data and information on IFIS is also accessible through web services and mobile applications. The IFIS is optimized for various browsers and screen sizes to provide access through multiple platforms including tablets and mobile devices. The IFIS includes a rainfall-runoff forecast model to provide a five-day flood risk estimate for around 1100 communities in Iowa. Multiple view modes in the IFIS accommodate different user types from general public to researchers and decision makers by providing different level of tools and details. River view mode allows users to visualize data from multiple IFC bridge sensors and USGS stream gauges to follow flooding condition along a river. The IFIS will help communities make better-informed decisions on the occurrence of floods, and will alert communities in advance to help minimize damage of floods. This presentation provides an overview and live demonstration of the tools and interfaces in the IFIS developed to date to provide a platform for one-stop access to flood related data, visualizations, flood conditions, and forecast.

Identification of heavy metals on vegetables at the banks of Kaligarang river using neutron analysis activation method

NASA Astrophysics Data System (ADS)

Yulianti, D.; Marwoto, P.; Fianti

2018-03-01

This research aims to determine the type, concentration, and distribution of heavy metals in vegetables on the banks river Kaligarang using Neutron Analysis Activation (NAA) Method. The result is then compared to its predefined threshold. Vegetable samples included papaya leaf, cassava leaf, spinach, and water spinach. This research was conducted by taking a snippet of sediment and vegetation from 4 locations of Kaligarang river. These snippets are then prepared for further irradiated in the reactor for radioactive samples emiting γ-ray. The level of γ-ray energy determines the contained elements of sample that would be matched to Neutron Activation Table. The results showed that vegetablesat Kaligarang are containing Cr-50, Co-59, Zn-64, Fe-58, and Mn-25, and well distributed at all research locations. Furthermore, the level of the detected metal elements is less than the predefined threshold.

The spatial distribution of major and trace elements in the surface sediments from the northeastern Beibu Gulf, South China Sea

NASA Astrophysics Data System (ADS)

Ge, Q.; Xue, Z. G.

2017-12-01

Major and trace elements contents and grain size were analyzed for surface sediments retrieved from the northeastern Beibu (Tonkin) Gulf. The study area was divided into four zones: Zone I locates in the northeastern coastal area of the gulf, which received large amount of the fluvial materials from local rivers; Zone II locates in the center of the study area, where surface sediments is from multiple sources; Zone III locates in the Qiongzhou Strait, which is dominated by material from the Pearl River and Hainan Island; Zone IV locates in the southwest of the study area, and the sediments mainly originated from the Red River. Statistical analyses of sediment geochemical characteristics reveal that grain size is the leading factor for elementary distribution, which is also influenced by hydrodynamics, mineral composition of terrigenous sediments, anthropogenic activity, and authigenic components.

Surface water quality assessment of the Upper Illinois River basin in Illinois, Indiana, and Wisconsin : geochemical data for fine-fraction streambed sediment from high- and low-order streams, 1987

USGS Publications Warehouse

Colman, John A.; Sanzolone, R.F.

1991-01-01

Geochemical data are presented from a synoptic survey of 46 elements in fine-fraction streambed sediments of the Upper Illinois River Basin during the fall of 1987. The survey was a component study of the Illinois pilot project of the U.S. Geological Survey's National Water-Quality Assessment program. Most of the sampling sites were randomly chosen--135 on main stems of rivers and 238 on first- and second-order streams. In addition, 196 samples were collected for quality-assurance and special-study purposes. The report includes element concentration data and summary-statistics tables of percentiles, nested analysis of variance, and correlation coefficients. All concentration data are included in tabular form and can be selected by map reference number, latitude and longitude, or remark code indicating purpose for collecting sample.

Environmental background values of trace elements in sediments from the Jiaozhou Bay catchment, Qingdao, China.

PubMed

Xu, Fangjian; Liu, Zhaoqing; Yuan, Shengqiang; Zhang, Xilin; Sun, Zhilei; Xu, Feng; Jiang, Zuzhou; Li, Anchun; Yin, Xuebo

2017-08-15

Selected trace elements (As, Cr, Zn, Cu, Cd, Co, Pb and Ni) in 76 surface sediment samples collected from the rivers and the intertidal zone of Jiaozhou Bay (JZB) were evaluated to assess their environmental background values in the JZB catchment. Overall, the sediment quality in the area meets the China Marine Sediment Quality criteria. The background values (ranges) of the elements As, Cr, Zn, Cu, Cd, Co, Pb and Ni were, respectively, 8.28 (4.10-12.46), 67.96 (38.40-97.52), 56.80 (16.42-196.51), 19.13 (5.71-64.06), 0.10 (0.02-0.42), 6.51 (2.08-20.40), 17.97 (12.26-55.84) and 20.69 (10.43-30.95)mg/kg. The background values of most of the trace elements were lower than those in Chinese soil, the upper continental crust, global shales and global preindustrial sediments. The results may assist in defining future coastal and river management measures specifically targeted at monitoring trace element contamination in the JZB catchment. Copyright © 2017 Elsevier Ltd. All rights reserved.

Balancing between retention and flushing in river networks--optimizing nutrient management to improve trophic state.

PubMed

Honti, Márk; Istvánovics, Vera; Kovács, Adám S

2010-09-15

River basin management can frequently involve decisive situations, when conflicting interests must be resolved. In the Zala River catchment (Western Hungary) local efforts to improve water quality by reducing algal biomass are not always harmonized with the requirement of sustaining the same objective in its recipient, Lake Balaton. The PhosFate catchment model is a GIS tool designed to estimate the spatial variability and fate of diffuse phosphorus emission during transport. Besides diffuse pollution, a simplified annual hydrologic balance is also calculated. A new module was added to PhosFate that tracked the development of entrained algae during their travel downstream. The extended model was used to simulate the current average algal concentrations in the river network. The numerous small reservoirs and impoundments on the tributaries of the Zala River were identified as the key elements in determining algal biomass, since they fundamentally increase the water residence time (WRT) in the system. Without reservoirs, the short WRT in the drainage network would successfully prevent the development of suspended algal biomass despite the fairly high SRP concentrations. However, the removal of such standing waters is impossible for socio-economic reasons and reducing the overall P load to Lake Balaton would also require increasing WRT in the system. As a resolution to these conflicting interests, a hybrid management strategy was designed to simultaneously reach both goals: (i) switching from WRT to P limitation in reservoirs responsible for most of algal growth, and (ii) optimized deployment of buffer zones and the introduction of best agricultural practices on the remaining majority of the catchment to reduce the overall P load. The suggested management approach could be applied in other river catchments too, due to the extensive presence of reservoirs and impoundments in many stream networks. Copyright 2010 Elsevier B.V. All rights reserved.

Biogeochemical features of aquatic plants in the Selenga River delta

NASA Astrophysics Data System (ADS)

Shinkareva, Galina; Lychagin, Mikhail

2014-05-01

The Selenga River system provides more than a half of the Lake Baikal total inflow. The river collects a significant amount of pollutants (e.g. heavy metals) from the whole basin. These substances are partially deposited within the Selenga delta, and partially are transported further to the lake. A generous amount of aquatic plants grow in the delta area according to its favorable conditions. This vegetation works as a specific biofilter. It accumulates suspended particles and sorbs some heavy metals from the water. The study aimed to reveal the species of macrophytes which could be mostly important for biomonitoring according to their chemical composition. The field campaign took place in the Selenga River delta in July-August of 2011 (high water period) and in June of 2012 (low water period). 14 species of aquatic plants were collected: water starwort Callitriche hermaphroditica, small yellow pond lily Nuphar pumila, pondweeds Potamogeton crispus, P. pectinatus, P. friesii, broadleaf cattail Typha latifolia, hornwort or coontail Ceratophyllum demersum, arrowhead Sagittaria natans, flowering rush (or grass rush) Butomus umbellatus, reed Phragmites australis, parrot's feather Myriophyllum spicatum, the common mare's tail Hippuris vulgaris, Batrachium trichophyllum, canadian waterweed Elodea canadensis. The samples were dried, grinded up and digested in a mixture of HNO3 and H2O2. The chemical composition of the plant material was defined using ICP-MS and ICP-AES methods. Concentrations of Fe, Mn, Cr, Ni, Cu, B, Zn, V, Co, As, Mo, Pb, and U were considered. The study revealed that Potamogeton pectinatus and Myriophyllum spicatum concentrate elements during both high and low water periods. Conversely the Butomus umbellatus and Phragmites australis contain small amount of heavy metals. The reed as true grasses usually accumulates fewer amounts of elements than other macrophytes. To compare biogeochemical specialization of different species we suggest to use concentration ratio relatively Phragmites australis as a background content. This factor showed that Nuphar pumila and Ceratophyllum demersum are acting like concentrators in comparison with the reed. According to this ratio, the mostly accumulated elements in aquatic plants in 2011 were V, Co, As, U, and in 2012 - Cu, As, Bi. Differences in chemical composition are due to different water periods. During the high water period in 2011 a large amount of soil particles after the heavy rains were taken into the flow from the river banks and then deposited within the delta. The transportation of suspended particles during the low water period of 2012 was significantly less.

Metal and metalloid distribution in different environmental compartments of the middle Xingu River in the Amazon, Brazil.

PubMed

Ribeiro, Danielle Regina Gomes; Faccin, Henrique; Molin, Thaís Ramos Dal; de Carvalho, Leandro Machado; Amado, Lílian Lund

2017-12-15

Concentrations of As, Cd, Cu, Cr, Pb, Hg, and Ni were analyzed during rainy and dry seasons in water, sediment, soil, and two fish species. The analysis took place at four points in the Xingu River, one point in the Fresco River, and two mining pits in the southeastern area of the Eastern Amazon, Brazil. In the water, the total concentration of As (>0.14μg/L) was higher than the local reference values at all sampling points and in both seasons. Ordination analysis (PCA) highlighted As and Cu elements in the water. PERMANOVA showed that the metals behaved differently in the water throughout the monitored season and between sampling points. The sites with mining activity were the regions that were the most contaminated by metals. Samples of sediment (Ni>18mg/kg and Cr>37.30mg/kg) and soil (Pb>72mg/kg, Cr>75mg/kg and Ni>30mg/Kg) showed concentrations above the recommended by local legislation. Metal values in the muscle of both fish species were relatively low at all sampling points and in both monitored seasons. Concentrations in water, sediment, and soil showed that some points of the Xingu River, Fresco River and mining pits are contaminated by trace elements, mainly As, Hg, Cr, Pb, and Ni. This was the first study about trace elements in the Middle Xingu River, which leads us to conclude that rainfall and cassiterite mining activities strongly influence the mobilization of metals, especially in abiotic compartments. However, the fish analyzed did not exhibit relevant levels of contamination. This indicates low risk for human consumption. Additionally, results highlight the need to establish local criteria to define contamination limits for different metals while taking into account local geochemistry particularities and biome diversity. Copyright © 2017 Elsevier B.V. All rights reserved.

Movements of Diadromous Fish in Large Unregulated Tropical Rivers Inferred from Geochemical Tracers

PubMed Central

Walther, Benjamin D.; Dempster, Tim; Letnic, Mike; McCulloch, Malcolm T.

2011-01-01

Patterns of migration and habitat use in diadromous fishes can be highly variable among individuals. Most investigations into diadromous movement patterns have been restricted to populations in regulated rivers, and little information exists for those in unregulated catchments. We quantified movements of migratory barramundi Lates calcarifer (Bloch) in two large unregulated rivers in northern Australia using both elemental (Sr/Ba) and isotope (87Sr/86Sr) ratios in aragonitic ear stones, or otoliths. Chemical life history profiles indicated significant individual variation in habitat use, particularly among chemically distinct freshwater habitats within a catchment. A global zoning algorithm was used to quantify distinct changes in chemical signatures across profiles. This algorithm identified between 2 and 6 distinct chemical habitats in individual profiles, indicating variable movement among habitats. Profiles of 87Sr/86Sr ratios were notably distinct among individuals, with highly radiogenic values recorded in some otoliths. This variation suggested that fish made full use of habitats across the entire catchment basin. Our results show that unrestricted movement among freshwater habitats is an important component of diadromous life histories for populations in unregulated systems. PMID:21494693

Geomorphological reference condition definition as a basis for river restoration and river management: the example of Oiartzun, Oria and Urumea River basins (Basque Country)

NASA Astrophysics Data System (ADS)

Ibisate, Askoa; Ollero, Alfredo; Sáenz de Olazagoitia, Ana; Acín, Vanesa; Granado, David; Herrero, Xabier; Horacio, Jesús

2017-04-01

The application of hydrogeomorphology as a tool for river management and decision making on reference condition definition for river restoration is presented. Water Framework Directive (2000/60/CE) requires the identification of reference conditions and attainable target images, to achieve the good ecological status, taking into account the direct and indirect changes in the basin and river course. Data collection was done through an exhaustive fieldwork and GIS tools. Based on geomorphological homogeneous river reaches identification (waterfall, bedrock, step-pool, cascade, coluvial, run, riffle-pool, heavily modified), the hydrogeomorphological assessment of all of them in relation to its "natural" condition allowed the identification of those with a good or very good hydrogeomorphological condition, considered as reference condition. The loss of hydrogeomorphological quality was closely linked to sociodemographical pressure, due to artificial elements in the river course, floodplain and land use changes on the basin. The assessment done based on pressures and impacts allowed the proposal of specific restoration objectives which facilitated the identification of the elements that degrade the hydrogeomorphological quality of the reaches, and helped the identification of specific restoration actions. In addition it was possible to set the reaches with the potentiality of being restored, those reversible and those that due to its high degradation were considered irreversible, and therefore not able to be restored, except for some rehabilitation or mitigation measures. The application in two basins, Oria and Oiartzun, concluded that 36% of the reaches could recover their geomorphological good status and a 40% could be considered as reference condition for other reaches. This geomorphological based reference condition definition could be linked and complete with ecological data.

Organic carbon, and major and trace element dynamic and fate in a large river subjected to poorly-regulated urban and industrial pressures (Sebou River, Morocco).

PubMed

Hayzoun, H; Garnier, C; Durrieu, G; Lenoble, V; Le Poupon, C; Angeletti, B; Ouammou, A; Mounier, S

2015-01-01

An annual-basis study of the impacts of the anthropogenic inputs from Fez urban area on the water geochemistry of the Sebou and Fez Rivers was conducted mostly focusing on base flow conditions, in addition to the sampling of industrial wastewater characteristic of the various pressures in the studied environment. The measured trace metals dissolved/particulate partitioning was compared to the ones predicted using the WHAM-VII chemical speciation code. The Sebou River, upstream from Fez city, showed a weakly polluted status. Contrarily, high levels of major ions, organic carbon and trace metals were encountered in the Fez River and the Sebou River downstream the Fez inputs, due to the discharge of urban and industrial untreated and hugely polluted wastewaters. Trace metals were especially enriched in particles with levels even exceeding those recorded in surface sediments. The first group of elements (Al, Fe, Mn, Ti, U and V) showed strong inter-relationships, impoverishment in Fez particles/sediments and stable partition coefficient (Kd), linked to their lithogenic origin from Sebou watershed erosion. Conversely, most of the studied trace metals/metalloids, originated from anthropogenic sources, underwent significant changes of Kd and behaved non-conservatively in the Sebou/Fez water mixing. Dissolved/particulate partitioning was correctly assessed by WHAM-VII modeling for Cu, Pb and Zn, depicting significant differences in chemical speciation in the Fez River when compared to that in the Sebou River. The results of this study demonstrated that a lack of compliance in environmental regulations certainly explained this poor status. Copyright © 2014 Elsevier B.V. All rights reserved.

Transport and distribution of trace elements and other selected inorganic constituents by suspended particulates in the Salton Sea Basin, California, 2001

USGS Publications Warehouse

LeBlanc, L.A.; Schroeder, R.A.

2008-01-01

In order to examine the transport of contaminants associated with river-derived suspended particles in the Salton Sea, California, large volume water samples were collected in transects established along the three major rivers emptying into the Salton Sea in fall 2001. Rivers in this area carry significant aqueous and particulate contaminant loads derived from irrigation water associated with the extensive agricultural activity, as well as wastewater from small and large municipalities. A variety of inorganic constituents, including trace metals, nutrients, and organic carbon were analyzed on suspended material isolated from water samples collected at upriver, near-shore, and off-shore sites established on the Alamo, New, and Whitewater rivers. Concentration patterns showed expected trends, with river-borne metals becoming diluted by organic-rich algal particles of lacustrine origin in off-shore stations. More soluble metals, such as cadmium, copper, and zinc showed a more even distribution between sites in the rivers and off-shore in the lake basin. General distributional trends of trace elements between particulate and aqueous forms were discerned by combining metal concentration data for particulates from this study with historical aqueous metals data. Highly insoluble trace metals, such as iron and aluminum, occurred almost entirely in the particulate phase, while major cations and approximately 95% of selenium were transported in the soluble phase. Evidence for greater reducing conditions in the New compared to the Alamo River was provided by the greater proportion of reduced (soluble) manganese in the New River. Evidence of bioconcentration of selenium and arsenic within the lake by algae was provided by calculating "enrichment" concentration ratios from metal concentrations on the algal-derived particulate samples and the off-shore sites. ?? 2008 Springer Science+Business Media B.V.

Chemotherapeutic Studies on Schistosomiasis and Clinical, Epidemiological and Immunological Studies on Malaria in Amazonas, Brazil, along the Ituxi River. Report Number VII.

DTIC Science & Technology

1980-10-01

Chemotherapeutic Studies on Schistosomiasis and Clinical, Epidemio- logical and Immunological Studies on Malaria in Amazonas ,- Brazil,.Along the Ituxi River...30 Sep 80. logical Studies on Malaria in Amazonas , Brazil, Along the Ituxi River. S. PERFORMING ORGANIZATION 14AME AND0 ADDRESS I0. PROGRAM ELEMENT...DDT-sprayed and unsprayed houses and analysis of the results relative to the incidence of malaria in the Amazonas study area.Efforts with the in vitro

Structural and elemental analysis of bottom sediments from the Paraíba do Sul River (SE, Brazil) by analytical microscopy

NASA Astrophysics Data System (ADS)

Miguens, Flávio Costa; Oliveira, Martha Lima de; Ferreira, Amanda de Oliveira; Barbosa, Laís Rodrigues; Melo, Edésio José Tenório de; Carvalho, Carlos Eduardo Veiga de

2016-03-01

The Paraíba do Sul River (PSR) is a medium-sized river that flows through the Minas Gerais, São Paulo and Rio de Janeiro Brazilian states the three most developed states in Brazil. Industrial parks and cities have historically been established along the river basin. The waters of PSR are used in agriculture, industry and human consumption of over 20 million people, including Rio de Janeiro City. Furthermore, the river receives effluent from these activities: agricultural runoff, industrial waste, and domestic sewage. Therefore, PSR has been considered polluted, particularly by heavy metals. In order to assess heavy metals in bottom sediments grains of the PSR, to infer their elemental composition, and to characterize individual sediment grains morphology, a non-destructive methodology - X-ray microanalyses (Scanning Electron Microscope coupled to Energy Dispersive X-rays Spectrometer/SEM/EDS) - was used. Heavy metals - Cr, Mn, Ni, Cu, Zn, Zr, Ag, Ba, Au, La, Ce, Nd, Th, Y, Sn, Os and Pb - were detected by SEM/EDS in bottom sediment grains from PSR, predominantly in grains with equivalent diameter ≤10 μm. They occurred as silicates, oxides (hydro-oxides), sulfides, carbonates, sulfates, phosphates and chlorides. All detected heavy metals occurred as, at least, one kind of soluble metal compound, mainly due to ionic exchange from silicates, with the exception of Ag, which was chloride, sulfate or metallic as Os, Au and Pb. These results corroborate heavy metal PSR pollution and food chain risk, considering that near-shore continental shelf is free of heavy metals contamination. Our results also give support to the hypothesis that the PSR estuary can act as a trap for these elements.

Surface-water-quality assessment of the upper Illinois River basin in Illinois, Indiana, and Wisconsin; spatial distribution of geochemicals in the fine fraction of streambed sediment, 1987

USGS Publications Warehouse

Fitzpatrick, Faith A.; Arnold, Terri L.; Colman, John A.

1998-01-01

Geochemical data for the upper Illinois River Basin are presented for concentrations of 39 elements in streambed sediment collected by the U.S. Geological Survey in the fall of 1987. These data were collected as part of the pilot phase of the National Water-Quality Assessment Program. A total of 372 sites were sampled, with 238 sites located on first- and second-order streams, and 134 sites located on main stems. Spatial distribution maps and exceedance probability plots are presented for aluminum, antimony, arsenic, barium, beryllium, boron, cadmium, calcium, carbon (total, inorganic, and organic), cerium, chromium, cobalt, copper, gallium, iron, lanthanum, lead, lithium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, niobium, phosphorus, potassium, scandium, selenium, silver, sodium, strontium, sulfur, thorium, titanium, uranium, vanadium, yttrium, and zinc. For spatial distribution maps, concentrations of the elements are grouped into four ranges bounded by the minimum concentration, the 10th, 50th, and 90th percentiles, and the maximum concentrations. These ranges were selected to highlight streambed sediment with very low or very high element concentrations relative to the rest of the streambed sediment in the upper Illinois River Basin. Exceedance probability plots for each element display the differences, if any, in distributions between high- and low-order streams and may be helpful in determining differences between background and elevated concentrations.

Trace elements in seep waters along Whitewood Creek, South Dakota, and their toxicity to fathead minnows

USGS Publications Warehouse

Hamilton, S.J.; Buhl, K.J.

2000-01-01

Whitewood Creek, located in the Black Hills of southwestern South Dakota, has a long history of contamination from mining activity. Gold exploration began in the 1870s, and has continued since that time. Whitewood Creek received direct releases of tailings from 1870 to 1977 from Gold Run Creek in Lead, SD. It has been estimated that approximately 100 million to 1 billion tons of mining, milling, and ore processing wastes have been released by mining activity in the last century in to Whitewood Creek, the Belle Fourche river, and the Cheyenne River (Fox Consultants, Inc. 1984). Tailings deposition has altered the geomorphology of Whitewood Creek, and deposits up to 4.6 m. deep, have become stabilized by vegetation. Several other streams in the Black Hills also have been adversely affected by mining operations (Rahn 1996).As water leaches through rock strata that are disturbed by surface and subsurface mining, it dissolves inorganic elements and carries them to the groundwater.  Groundwater movement through the extensive tailings deposits in the Whitewood Creek valley enter the creek at various seeps along its downstream course to the Belle Fourche river, and the Belle Fourche River itself, which empties into the Cheyenne River and eventually into Lake Oahe.

Water quality of streams in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-2001

USGS Publications Warehouse

Tornes, Lan H.

2005-01-01

Data for the Red River of the North (Red River) Basin in Minnesota, North Dakota, and South Dakota were analyzed to determine whether the water quality of streams in the basin is adequate to meet future needs. For the Red River at Emerson, Manitoba, site, pH values, water temperatures, and dissolved-oxygen concentrations generally were within the criteria established for the protection of aquatic life. Dissolved-solids concentrations ranged from 245 to 1,100 milligrams per liter. Maximum sulfate and chloride concentrations were near, but did not exceed, the established secondary maximum contaminant level. The trace elements considered potentially harmful generally were at concentrations that were less than the established guidelines, standards, and criteria. The concentrations of lead that were detected may have occurred as a result of sample contamination.  For the Red River upstream from Emerson, Manitoba, sites, pH and other field values rarely exceeded the criteria established for the protection of aquatic life. Many constituent concentrations for the Red River below Fargo, N. site exceeded water-quality guidelines, standards, and criteria. However, the trace-element exceedances could be natural or could be related to pollution or sample contamination. Many of the tributaries in the western part of the Red River Basin had median specific-conductance values that were greater than 1,000 microsiemens per centimeter. Sulfate concentrations occasionally exceeded the established drinking-water standard. Median arsenic concentrations were 6 micrograms per liter or less, and maximum concentrations rarely exceeded the 10-microgram-per-liter drinking-water standard that is scheduled to take effect in 2006. The small concentrations of lead, mercury, and selenium that occasionally were detected may have been a result of sample contamination or other factors. The tributaries in the eastern part of the Red River Basin had median specific-conductance values that were less than 1,000 microsiemens per centimeter.  Concentrations of pesticides that were detected and that had regulatory limits were less than the cited water-quality guidelines, standards, and criteria. Concentrations of compounds that were detected generally were less than the sediment- quality standards and criteria. The data considered in this report generally provide a good baseline from which to evaluate changes in water-quality conditions. However, because many of the trace elements detected, including lead and mercury, may have been the result of sample contamination, additional data are needed to confirm that trace-element concentrations generally are low. Concentrations of major ions, including sulfate, and specific conductance may continue to approach drinking-water standards during periods of low flow because the streams, particularly those in the western part of the basin, are sustained mostly by ground-water discharge that generally has large dissolved-solids concentrations.

Water-quality assessment of the Sacramento River basin, California : water quality of fixed sites, 1996-1998

USGS Publications Warehouse

Domagalski, Joseph L.; Dileanis, Peter D.

2000-01-01

Water-quality samples were collected from 12 sites in the Sacramento River Basin, Cali-fornia, from February 1996 through April 1998. Field measurements (dissolved oxygen, pH, specific conductance, alkalinity, and water tem-perature) were completed on all samples, and laboratory analyses were done for suspended sediments, nutrients, dissolved and particulate organic carbon, major ions, trace elements, and mercury species. Samples were collected at four types of locations on the Sacramento River?large tributaries to the Sacramento River, agricul-tural drainage canals, an urban stream, and a flood control channel. The samples were collected across a range of flow conditions representative of those sites during the timeframe of the study. The water samples from the Sacramento River indi-cate that specific conductance increases slightly downstream but that the water quality is indicative of dilute water. Water temperature of the Sacramento River increases below Shasta Lake during the spring and summer irrigation season owing to diversion of water out of the river and subsequent lower flow. All 12 sites had generally low concentrations of nutrients, but chlorophyll concentrations were not measured; therefore, the actual consequences of nutrient loading could not be adequately assessed. Concentrations of dis-solved organic carbon in samples from the Sacramento River and the major tributaries were generally low; the formation of trihalomethanes probably does not currently pose a problem when water from the Sacramento River and its major tributaries is chlorinated for drinking-water purposes. However, dissolved organic carbon concentrations were higher in the urban stream and in agricultural drainage canals, but were diluted upon mixing with the Sacramento River. The only trace element that currently poses a water-quality problem in the Sacramento River is mercury. A federal criterion for the protection of aquatic life was exceeded during this study, and floodwater concentrations of mercury were mostly higher than the criterion. Exceedances of water-quality standards happened most frequently during winter when suspended-sediment concen-trations also were elevated. Most mercury is found in association with suspended sediment. The greatest loading or transport of mercury out of the Sacramento River Basin to the San Francisco Bay occurs in the winter and principally follows storm events.

Assessment of Subyearling Chinook Salmon Survival through the Federal Hydropower Projects in the Main-Stem Columbia River

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skalski, J. R.; Eppard, M. B.; Ploskey, Gene R.

2014-07-11

High survival through hydropower projects is an essential element in the recovery of salmonid populations in the Columbia River. It is also a regulatory requirement under the 2008 Federal Columbia River Power System (FCRPS) Biological Opinion (BiOp) established under the Endangered Species Act. It requires dam passage survival to be ≥0.96 and ≥0.93 for spring and summer outmigrating juvenile salmonids, respectively, and estimated with a standard error ≤ 0.015. An innovative virtual/paired-release design was used to estimate dam passage survival, defined as survival from the face of a dam to the tailrace mixing zone. A coordinated four-dam study was conductedmore » during the 2012 summer outmigration using 14,026 run-of-river subyearling Chinook salmon surgically implanted with acoustic micro-transmitter (AMT) tags released at 9 different locations, and monitored on 14 different detection arrays. Each of the four estimates of dam passage survival exceeded BiOp requirements with values ranging from 0.9414 to 0.9747 and standard errors, 0.0031 to 0.0114. Two consecutive years of survival estimates must meet BiOp standards in order for a hydropower project to be in compliance with recovery requirements for a fish stock.« less

Uranium transport in the Walker River Basin, California and Nevada

USGS Publications Warehouse

Benson, L.V.; Leach, D.L.

1979-01-01

During the summer of 1976 waters from tributaries, rivers, springs and wells were sampled in the Walker River Basin. Snow and sediments from selected sites were also sampled. All samples were analyzed for uranium and other elements. The resulting data provide an understanding of the transport of uranium within a closed hydrologic basin as well as providing a basis for the design of geochemical reconnaissance studies for the Basin and Range Province of the Western United States. Spring and tributary data are useful in locating areas containing anomalous concentrations of uranium. However, agricultural practices obscure the presence of known uranium deposits and render impossible the detection of other known deposits. Uranium is extremely mobile in stream waters and does not appear to sorb or precipitate. Uranium has a long residence time (2500 years) in the open waters of Walker Lake; however, once it crosses the sediment-water interface, it is reduced to the U(IV) state and is lost from solution. Over the past two million years the amount of uranium transported to the terminal point of the Walker River system may have been on the order of 4 ?? 108 kg. This suggests that closed basin termini are sites for significant uranium accumulations and are, therefore, potential sites of uranium ore deposits. ?? 1979.

Documenting the use of the Long Term Resource Monitoring element’s fish monitoring methodologies throughout the Midwest

USGS Publications Warehouse

Solomon, Levi E.; Casper, Andrew F.

2016-08-16

The Upper Mississippi River Restoration (UMRR) Program’s Long Term Resource Monitoring (LTRM) element is designed to monitor and assess long term trends in the Upper Mississippi River System (UMRS). To accomplish this, standardized methods are used that allow for comparisons across pools and rivers. In recent years, other projects and other agencies have adopted the LTRM fish methodologies for use outside the UMRR. To determine how widespread the use of the Fish Component’s methods are, a twelve question survey was delivered via SurveyMonkey.com through the states comprising the American Fisheries Society (AFS) North Central Division and the Upper Mississippi River Conservation Committee. Approximately 2,000 professionals were reached with ≈11 percent participating. Results indicate that nearly all (95 percent) respondents use standardized methods in their sampling and 48 percent are familiar with the LTRM fish methodologies. Roughly one-third (35 percent) of all respondents have used the methods in the past and most (78 percent) of those have modified the methods to suit the information needs specific to their fishery. Results indicate that the LTRM methods have indeed spread outside the UMRR and are now a well-known and potentially widely used technique to sample fish communities.

Trace element accumulation and trophic relationships in aquatic organisms of the Sundarbans mangrove ecosystem (Bangladesh).

PubMed

Borrell, Asunción; Tornero, Victoria; Bhattacharjee, Dola; Aguilar, Alex

2016-03-01

The Sundarbans forest is the largest and one of the most diverse and productive mangrove ecosystems in the world. Located at the northern shoreline of the Bay of Bengal in the Indian Ocean and straddling India and Bangladesh, the mangrove forest is the result of three primary river systems that originate further north and northwest. During recent decades, the Sundarbans have been subject to increasing pollution by trace elements caused by the progressive industrialization and urbanization of the basins of these three rivers. As a consequence, animals and plants dwelling downstream in the mangroves are exposed to these pollutants in varying degrees, and may potentially affect human health when consumed. The aim of the present study was to analyse the concentrations of seven trace elements (Zn, Cu, Cr, Hg, Pb, Cd and As) in 14 different animal and plant species collected in the Sundarbans in Bangladesh to study their transfer through the food web and to determine whether their levels in edible species are acceptable for human consumption. δ(15)N values were used as a proxy of the trophic level. A decrease in Zn, Cu, Pb and Cd levels was observed with increasing trophic position. Trace element concentrations measured in all organisms were, in general, lower than the concentrations obtained in other field studies conducted in the same region. When examined with respect to accepted international standards, the concentrations observed in fish and crustaceans were generally found to be safe for human consumption. However, the levels of Zn in Scylla serrata and Cr and Cd in Harpadon nehereus exceeded the proposed health advisory levels and may be of concern for human health. Copyright © 2015 Elsevier B.V. All rights reserved.

Analysis of stream quality in the Yampa River Basin, Colorado and Wyoming

USGS Publications Warehouse

Wentz, Dennis A.; Steele, Timothy Doak

1980-01-01

Historic data show no significant water-temperature changes since 1951 for the Little Snake or Yampa Rivers, the two major streams of the Yampa River basin in Colorado and Wyoming. Regional analyses indicate that harmonic-mean temperature is negatively correlated with altitude. No change in specific conductance since 1951 was noted for the Little Snake River; however, specific conductance in the Yampa River has increaed 14 % since that time and is attributed to increased agricultural and municipal use of water. Site-specific relationships between major inorganic constituents and specific conductance for the Little Snake and Yampa Rivers were similar to regional relationships developed from both historic and recent (1975) data. These relationships provide a means for estimating concentrations of major inorganic constituents from specific conductance, which is easily measured. Trace-element and nutrient data collected from August 1975 through September 1976 at 92 sites in the Yampa River basin indicate that water-quality degradation occurred upstream from 3 sites. The degradation resulted from underground drainage from pyritic materials that probably are associated with coal at one site, discharge from powerplant cooling-tower blowdown water at a second site, and runoff from a small watershed containing a gas field at the third site. Ambient concentrations of dissolved and total iron and manganese frequently exceeded proposed Colorado water-quality standards. The concentrations of many dissolved and total trace elements and nutrients were greatest during March 1976. These were associated with larger suspended-sediment concentrations and smaller pH values than at other times of the year. (USGS)

Hydrology and Glacier-Lake-Outburst Floods (1987-2004) and Water Quality (1998-2003) of the Taku River near Juneau, Alaska

USGS Publications Warehouse

Neal, Edward G.

2007-01-01

The Taku River Basin originates in British Columbia, Canada, and drains an area of 6,600 square miles at the U.S. Geological Survey's Taku River gaging station. Several mines operated within the basin prior to 1957, and mineral exploration has resumed signaling potential for future mining developments. The U.S. Geological Survey in cooperation with the Douglas Indian Association, Alaska Department of Environmental Conservation, and the U.S. Environmental Protection Agency conducted a water-quality and flood-hydrology study of the Taku River. Water-quality sampling of the Taku River from 1998 through 2003 established a baseline for assessing potential effects of future mining operations on water quality. The annual mean discharge of the Taku River is 13,700 cubic feet per second. The monthly mean discharge ranges from a minimum of 1,940 cubic feet per second in February to a maximum of 34,400 cubic feet per second in June. Nearly 90 percent of the annual discharge is from May through November. The highest spring discharges are sourced primarily from snowmelt and moderate discharges are sustained throughout the summer by glacial meltwaters. An ice cover usually forms over the Taku River in December persisting through the winter into March and occasionally into April. Glacier-lake-outburst floods originating from two glacier-dammed lakes along the margin of the Tulsequah Glacier in British Columbia, Canada, are the source of the greatest peak discharges on the Taku River. The largest flood during the period of record was 128,000 cubic feet per second on June 25, 2004, resulting from an outburst of Lake No Lake. Lake No Lake is the larger of the two lakes. The outburst-flood contribution to peak discharge was 80,000 cubic feet per second. The volume discharged from Lake No Lake is relatively consistent indicating drainage may be triggered when the lake reaches a critical stage. This suggests prediction of the timing of these outburst floods might be possible if lake-stage data were available. Further increases in the volume of Lake No Lake are unlikely as all tributary glaciers have retreated out of the lake basin. Decreasing outburst-flood volumes from Tulsequah Lake suggests a continued decline in the volume of this lake. Physical and chemical parameters and concentrations of basic water-quality constituents indicate good water quality. Samples collected at the Taku River gaging station contained low concentrations of trace elements in the dissolved phase. Trace elements sampled were within acceptable limits when compared with the Alaska Department of Environmental Conservation aquatic-life criteria for fresh waters. The highest concentrations of total trace elements sampled were collected during glacial-outburst floods and likely are associated with suspended sediments. Total trace-element concentrations generally increase with increasing water discharge, although a high correlation for all constituents sampled does not always exist.

Results of chemical and isotopic analyses of sediment and water from alluvium of the Canadian River near a closed municipal landfill, Norman, Oklahoma

USGS Publications Warehouse

Breit, George N.; Tuttle, Michele L.W.; Cozzarelli, Isabelle M.; Christenson, Scott C.; Jaeschke, Jeanne B.; Fey, David L.; Berry, Cyrus J.

2005-01-01

Results of physical and chemical analyses of sediment and water collected near a closed municipal landfill at Norman, Oklahoma are presented in this report. Sediment analyses are from 40 samples obtained by freeze-shoe coring at 5 sites, and 14 shallow (depth <1.3 m) sediment samples. The sediment was analyzed to determine grain size, the abundance of extractable iron species and the abundances and isotopic compositions of forms of sulfur. Water samples included pore water from the freeze-shoe core, ground water, and surface water. Pore water from 23 intervals of the core was collected and analyzed for major and trace dissolved species. Thirteen ground-water samples obtained from wells within a few meters of the freeze-shoe core sites and one from the landfill were analyzed for major and trace elements as well as the sulfur and oxygen isotope composition of dissolved sulfate. Samples of surface water were collected at 10 sites along the Canadian River from New Mexico to central Oklahoma. These river-water samples were analyzed for major elements, trace elements, and the isotopic composition of dissolved sulfate.

Patterns of Bacterial and Archaeal Gene Expression through the Lower Amazon River

DOE Office of Scientific and Technical Information (OSTI.GOV)

Satinsky, Brandon M.; Smith, Christa B.; Sharma, Shalabh

Analysis of metatranscriptomic and metagenomic datasets from the lower reaches of the Amazon River between Obidos and the river mouth revealed microbial transcript and gene pools dominated by Actinobacteria, Thaumarchaeota, Bacteroidetes, Acidobacteria, Betaproteobacteria, and Planctomycetes. Three mainstem stations spanning a 625 km reach had similar gene expression patterns (transcripts gene copy-1) across a diverse suite of element cycling genes, but two tributary-influenced stations at the mouth of the Tapajos River and near the Tocantins River at Belem had distinct transcriptome composition and expression ratios, particularly for genes encoding light-related energy capture (higher) and iron acquisition and ammonia oxidation (lower). Environmentalmore » parameters that were useful predictors of gene expression ratios included concentrations of lignin phenols, suspended sediments, nitrate, phosphate, and particulate organic carbon and nitrogen. Similar to the gene expression data, these chemical properties reflected highly homogeneous mainstem stations punctuated by distinct tributary- influenced stations at Tapajos and Belem. Although heterotrophic processes were expected to dominate in the lower Amazon, transcripts from photosynthetic bacteria were abundant in tributary-influenced regions, and transcripts from Thaumarcheota taxa genetically capable of chemosynthetic ammonia oxidation accounted for up to 21% of the transcriptome at others. Based on regressions of transcript numbers against gene numbers, expression ratios of Thaumarchaeota populations were largely unchanged within the mainstem, suggesting a relatively minor role for gene regulation. These quantitative gene and transcript inventories detail a diverse array of energy acquisition strategies and metabolic capabilities for bacteria and archaea populations of the world’s largest river system.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oldham, D.W.

Commercial quantities of gas have been produced from shallow sandstone reservoirs of the Tongue River Member of the Fort Union Formation (Paleocene) in the Wyoming portion of the Powder River Basin. The two largest accumulations discovered to date, Oedekoven and Chan pools, were drilled on prospects which invoked differential compaction as a mechanism for gas entrapment and prospect delineation. Coal-sourced bacterial gas may have accumulated in localized structural highs early in the burial history of lenticular sand bodies and associated sediments. Structural relief is due to the compaction contrast between sand and stratigraphically equivalent fine-grained sediments. A shallow gas playmore » targeting sandstones as potential reservoirs was initiated in the Recluse area in response as sources for bacterial gas, and the presence of lenticular sandstones that may have promoted the development of compaction structures early in the burial process, to which early-formed bacterial gas migrated. Prospects were ranked based on a number of geologic elements related to compaction-induced trap development. Drilling of the Oedekoven prospect, which possessed all prospect elements, led to the discovery and development of the Oedekoven Fort Union gas pool, which has produced nearly 2 BCF of gas from a depth of 340 ft. Production figures from the Oedekoven and Chan pools demonstrate the commercial gas potential of Fort Union sandstone reservoirs in the Powder River Basin. The shallow depths of the reservoirs, coupled with low drilling and completion costs, an abundance of subsurface control with which to delineate prospects, and an existing network of gas-gathering systems, make them attractive primary targets in shallow exploration efforts as well as secondary objectives in deeper drilling programs.« less

Biological and associated water-quality data for lower Olmos Creek and upper San Antonio River, San Antonio, Texas, April - September 1989

USGS Publications Warehouse

Taylor, R. Lynn; Ferreira, Rodger F.

1995-01-01

Biological and associated water-quality data were collected from lower Olmos Creek and upper San Antonio River in San Antonio, Texas, during April-September 1989. Benthic macroinvertebrate, periphyton, and phytoplankton communities were sampled at three sites along the Olmos Creek/San Antonio River system. Total mean densities of benthic macroinvertebrates for the three sites ranged from 670 to 10,000 organisms per square meter. The most abundant macroinvertebrates were the class Insecta (insects). Total densities of periphyton ranged from 2,900 to 110,000 cells per square millimeter. Cyanophyta (blue-green algae) and Bacillariophyta (diatoms) were the predominant periphyton organisms. Total densities of phyto- plankton ranged from 5,000 to 47,000 cells per square milliliter. Blue-green algae accounted for more than one- half of the phytoplankton in each sample. Hardness ranged from 160 to 250 milligrams per liter as calcium carbonate, and alkalinity ranged from 130 to 220 milligrams per liter as calcium carbonate. The largest dissolved nitrite concentration was 0.038 milligram per liter. The largest total phosphorus concentration was 0.150 milligram per liter, over one-half of which was dissolved orthophosphate. Total aluminum and total iron were the only trace elements in water to exceed the reporting threshold by large concen- trations. Total aluminum concentrations ranged from 70 to 280 micrograms per liter, and total iron concentrations ranged from 70 to 340 micrograms per liter. Lead was the most prominent trace element in bottom-material samples, with concentrations ranging from 30 to 230 micrograms per gram.

Cycling of Redox-Sensitive Trace Elements in the Lower Mississippi River Delta as a Function of River Stage and Sediment Heterogeneity

NASA Astrophysics Data System (ADS)

Telfeyan, K.; Breaux, A.; Kim, J.; Johannesson, K. H.; Kolker, A.; Cable, J. E.

2015-12-01

Telfeyan, K.1, Johannesson, K.H.1, Breaux, A.M.2,1, Kim, J.3, Kolker, A.S.2,1, Cable, J.E.31 Department of Earth and Environmental Sciences, Tulane University, New Orleans, LA, USA 2 Louisiana Universities Marine Consortium, Cocoderie, LA, USA 3 Department of Marine Sciences, University of North Carolina, Chapel Hill, NC, USA The Mississippi River drains 40% of the continental United States and discharges 0.1 Pg sediment and an average of 18,400 m3 s-1 water annually to the Gulf of Mexico1. The flow of groundwater through the Mississippi River Delta (MRD) to the Gulf, however, has been largely understudied and is typically overlooked in MRD biogeochemical studies. Previous work demonstrated that sand-rich paleochannels that maintain a hydrologic connection to the Mississippi River could transport riverine water to the MRD2. We present data from biogeochemical surveys at 2 sites in the lower MRD to explore the effects of river-derived submarine groundwater discharge on the biogeochemistry of MRD wetlands. Lac des Allemands is a fresh water lake and Myrtle Grove is a brackish canal with variable salinities. Both are surrounded by extensive wetlands. Over the course of a year, surface water, shallow pore water, and deeper groundwaters were sampled to understand the cycling of redox-sensitive trace elements (Fe, Mn, V, As) and the potential supply from groundwater to surface water bodies. Major ion chemistry suggests that both Lac des Allemands and Myrtle Grove Canal receive river-derived terrestrial water at their heads, the flux of which varies as a function of river stage. However, the lateral flow through adjacent wetlands is altered as a function of sediment heterogeneity. Evidence for sulfate reduction exists in the near-surface sediment and at depth where a continuous vertical organic matter layer exists. In sand-rich layers, iron reduction buffers redox conditions, and V varies inversely with dissolved Fe. Concentrations of V and As are much greater in near-surface pore waters than in deeper groundwaters and in surface waters, suggesting that the subterranean estuary serves as a sink of these redox-sensitive trace elements. [1] Bianchi and Allison (2009) PNAS 1068085-8092. [2] Kolker et al. (2013) Journal of Hydrology 498 319-334.

Dissolved molybdenum and uranium in the Three Rivers of eastern Tibet

NASA Astrophysics Data System (ADS)

Noh, H.; Huh, Y.

2006-12-01

Three large rivers - the Chang Jiang (Yangtze), Mekong (Lancang Jiang) and Salween (Nu Jiang) - originate in eastern Tibet and run in close parallel over 300 km near the eastern Himalayan syntaxis. They flow across suture zones and faults generated by the collision of India and Eurasia. Sixty-five water samples were collected in summer of 1999 to 2004 and nine in winter of 2002 to 2003. The complex geologic makeup of the Three Rivers region (TRR) results in widely varying major and trace element compositions of the dissolved load. Two redox-sensitive elements, molybdenum (Mo) and uranium (U) were analyzed by ICP-MS, as potential proxies for weathering of sedimentary organic carbon and resultant generation of atmospheric carbon dioxide. Additionally, Mo constitutes an essential co-enzyme for biology. Mo concentration ranges from 0.76 to 21.3 nmol/kg (average: 6.24 nmol/kg, average of global rivers: ~5 nmol/kg (Martin and Meybeck, 1979)), and U concentration varies from 2.86 to 10.7 nmol/kg (average: 3.12 nmol/kg, average of global rivers: ~1 nmol/kg (Palmer and Edmond, 1993)). The highest values of Mo and U are observed in the headwater tributary sample of the Chang Jiang, where evaporite dissolution is dominant. Statistical analyses show that Mo is closely correlated with U (r = 0.713, p < 0.01) indicating similar source of Mo and U to river waters in the TRR. Inverse correlation with Si/total anions ratio suggests that their sources are non-silicate minerals. The correlation with sulfate supports the use Mo and U as proxies for weathering of reduced organic-rich sediments (Mo and SO4: r = 0.383, p < 0.01; U and SO4: r = 0.508, p < 0.01). Among the parameters tested (basin area, elevation, relief, slope, T, precipitation, potential-evapotranspiration, normalized difference vegetation index (NDVI), population density), best positive correlation (r>0.5) is shown between U and basin elevation, and negative correlation is shown between U and temperature, precipitation and potential- evapotranspiration. Martin J.-M. and Meybeck M. (1979) Elemental mass-balance of material carried by major world rivers. Mar. Chem. 7, 173-206. Palmer M. R. and Edmond J. M. (1993) Uranium in river water. Geochim. Cosmochim. Acta 57, 4947-4955.

Evaluation of an alternate method for sampling benthic macroinvertebrates in low-gradient streams sampled as part of the National Rivers and Streams Assessment

EPA Science Inventory

Benthic macroinvertebrates are sampled in streams and rivers as one of the assessment elements of the U.S. Environmental Protection Agency’s National Aquatic Resource Surveys. In a 2006 report, the recommendation was made that different yet comparable methods be evaluated for di...

Trace element fractionation and transport in boreal rivers and soil porewaters of permafrost-dominated basaltic terrain in Central Siberia

NASA Astrophysics Data System (ADS)

Pokrovsky, O. S.; Schott, J.; Dupré, B.

2006-07-01

The chemical status of ˜40 major and trace elements (TE) and organic carbon (OC) in pristine boreal rivers draining the basaltic plateau of Central Siberia (Putorana) and interstitial solutions of permafrost soils was investigated. Water samples were filtered in the field through progressively decreasing pore size (5 μm → 0.22 μm → 0.025 μm → 10 kDa → 1 kDa) using cascade frontal filtration technique. Most rivers and soil porewaters exhibit 2-5 times higher than the world average concentration of dissolved (i.e., <0.22 μm) iron (0.03-0.4 mg/L), aluminum (0.03-0.4 mg/L), OC (10-20 mg/L) and various trace elements that are usually considered as immobile in weathering processes (Ti, Zr, Ga, Y, REEs). Ultrafiltration revealed strong relationships between concentration of TE and that of colloidal Fe and Al. According to their partition during filtration and association with colloids, two groups of elements can be distinguished: (i) those weakly dependent on ultrafiltration and that are likely to be present as truly dissolved inorganic species (Li, Na, K, Si, Mn, Mo, Rb, Cs, As, Sb) or, partially (20-30%) associated with small size Fe- and Al-colloids (Ca, Mg, Sr, Ba) and to small (<1-10 kDa) organic complexes (Co, Ni, Cu, Zn), and (ii) elements strongly associated with colloidal iron and aluminum in all ultrafiltrates largely present in 1-100 kDa fraction (Ga, Y, REEs, Pb, V, Cr, Ti, Ge, Zr, Th, U). TE concentrations and partition coefficients did not show any detectable variations between different colloidal fractions for soil porewaters, suprapermafrost flow and surface streams. TE concentration measurements in river suspended particles demonstrated significant contribution (i.e., ⩾30%) of conventionally dissolved (<0.22 μm) forms for usually "immobile" elements such as divalent transition metals, Cd, Pb, V, Sn, Y, REEs, Zr, Hf, Th. The Al-normalized accumulation coefficients of TE in vegetation litter compared to basalts achieve 10-100 for B, Mn, Zn, As, Sr, Sn, Sb, and the larch litter degradation is able to provide the major contribution to the annual dissolved flux of most trace elements. It is hypothesized that the decomposition of plant litter in the topsoil horizon leads to Fe(III)-, Al-organic colloids formation and serves as an important source of elements in downward percolating fluids.

Tipping Points in Texas Rivers

NASA Astrophysics Data System (ADS)

Phillips, Jonathan

2016-04-01

Anticipating geomorphic tipping points requires that we learn from the past. Major geomorphic changes in coastal plain rivers of Texas resulting in river metamorphosis or regime shifts were identified, and the major driving factors determined. Nine fluvial tipping points were identified from contemporary observations, historical records, and Quaternary reconstructions. Two of the tipping points (between general aggrading and degrading valley states) are associated with reversals in a fundamental system control (sea-level). One (stable or aggrading vs. degrading channels) is associated with an abrupt change in sediment supply due to dam construction, and two others (changes from meandering to anastomosing channel patterns, and different anastomosis styles) are similarly related to changes in sediment supply and/or transport capacity, but with additional elements of historical contingency. Three tipping points are related to avulsions. One, from a regime dominated to reoccupation of former channels to one dominated by progradation into flood basins, is driven by progressive long term filling of incised valleys. Another, nodal avulsions, are driven by disturbances associated with tectonics or listric faults. The third, avulsions and related valley metamorphosis in unfilled incised valleys, is due to fundamental dynamical instabilities within the fluvial system. This synthesis and analysis suggests that geomorphic tipping points are sometimes associated with general extrinsic or intrinsic (to the fluvial system) environmental change, independent of any disturbances or instabilities. Others are associated with natural (e.g., tectonic) or human (dams) disturbances, and still others with intrinsic geomorphic instabilities. This suggests that future tipping points will be equally diverse with respect to their drivers.

A heuristic simulation model of Lake Ontario circulation and mass balance transport

USGS Publications Warehouse

McKenna, J.E.; Chalupnicki, M.A.

2011-01-01

The redistribution of suspended organisms and materials by large-scale currents is part of natural ecological processes in large aquatic systems but can contribute to ecosystem disruption when exotic elements are introduced into the system. Toxic compounds and planktonic organisms spend various lengths of time in suspension before settling to the bottom or otherwise being removed. We constructed a simple physical simulation model, including the influence of major tributaries, to qualitatively examine circulation patterns in Lake Ontario. We used a simple mass balance approach to estimate the relative water input to and export from each of 10 depth regime-specific compartments (nearshore vs. offshore) comprising Lake Ontario. Despite its simplicity, our model produced circulation patterns similar to those reported by more complex studies in the literature. A three-gyre pattern, with the classic large counterclockwise central lake circulation, and a simpler two-gyre system were both observed. These qualitative simulations indicate little offshore transport along the south shore, except near the mouths of the Niagara River and Oswego River. Complex flow structure was evident, particularly near the Niagara River mouth and in offshore waters of the eastern basin. Average Lake Ontario residence time is 8 years, but the fastest model pathway indicated potential transport of plankton through the lake in as little as 60 days. This simulation illustrates potential invasion pathways and provides rough estimates of planktonic larval dispersal or chemical transport among nearshore and offshore areas of Lake Ontario. ?? 2011 Taylor & Francis.

Lead isotope exchange between dissolved and fluvial particulate matter: a laboratory study from the Johor River estuary

NASA Astrophysics Data System (ADS)

Chen, Mengli; Boyle, Edward A.; Lee, Jong-Mi; Nurhati, Intan; Zurbrick, Cheryl; Switzer, Adam D.; Carrasco, Gonzalo

2016-11-01

Atmospheric aerosols are the dominant source of Pb to the modern marine environment, and as a result, in most regions of the ocean the Pb isotopic composition of dissolved Pb in the surface ocean (and in corals) matches that of the regional aerosols. In the Singapore Strait, however, there is a large offset between seawater dissolved and coral Pb isotopes and that of the regional aerosols. We propose that this difference results from isotope exchange between dissolved Pb supplied by anthropogenic aerosol deposition and adsorbed natural crustal Pb on weathered particles delivered to the ocean by coastal rivers. To investigate this issue, Pb isotope exchange was assessed through a closed-system exchange experiment using estuarine waters collected at the Johor River mouth (which discharges to the Singapore Strait). During the experiment, a known amount of dissolved Pb with the isotopic composition of NBS-981 (206Pb/207Pb = 1.093) was spiked into the unfiltered Johor water (dissolved and particulate 206Pb/207Pb = 1.199) and the changing isotopic composition of the dissolved Pb was monitored. The mixing ratio of the estuarine and spike Pb should have produced a dissolved 206Pb/207Pb isotopic composition of 1.161, but within a week, the 206Pb/207Pb in the water increased to 1.190 and continued to increase to 1.197 during the next two months without significant changes of the dissolved Pb concentration. The kinetics of isotope exchange was assessed using a simple Kd model, which assumes multiple sub-reservoirs within the particulate matter with different exchange rate constants. The Kd model reproduced 56% of the observed Pb isotope variance. Both the closed-system experiment and field measurements imply that isotope exchange can be an important mechanism for controlling Pb and Pb isotopes in coastal waters. A similar process may occur for other trace elements. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

Accumulation and release of 241Am by a macrophyte of the Yenisei River (Elodea canadensis).

PubMed

Bolsunovsky, A; Zotina, T; Bondareva, L

2005-01-01

The source of radioactive contamination of the Yenisei River floodplain, including contamination with transuranic elements, is the Mining-and-Chemical Combine of the Russian Ministry of Atomic Energy, which has for many years been producing weapons-grade plutonium. Transuranic elements have been detected not only in the soil and sediment of the river but also in the biomass of aquatic plants. This work is an investigation of accumulation and release of 241Am by a submerged macrophyte of the Yenisei River (Elodea canadensis) in laboratory experiments. In 2000-2003, laboratory experiments were carried out with biomass of E. canadensis Mich. and filtered river water. The samples were collected from the Yenisei River upstream of the discharge of the Combine's radioactive effluent. The experiments showed that 241Am is accumulated by Elodea biomass: the activity concentration of 241Am can reach 3280+/-240 Bq/g, with the concentration factor for 241Am 16 600+/-2200l/kg. Results of chemical fractionation have proved that in the course of 241Am accumulation by Elodea biomass, 241Am tightly bound to biomass increases from 11% to 27% of the total 241Am in the biomass. Release of 241Am from the decaying Elodea biomass has been evaluated experimentally. By the end of the experiment (lasting up to 127 days), the Elodea plants had lost up to 65% of their initial 241Am activity and the rate of 241Am release into the water environment reached 23 Bq/day.

Mineralogical controls on mobility of rare earth elements in acid mine drainage environments.

PubMed

Soyol-Erdene, T O; Valente, T; Grande, J A; de la Torre, M L

2018-08-01

Rare earth elements (REE) were analyzed in river waters, acid mine waters, and extracts of secondary precipitates collected in the Iberian Pyrite Belt. The obtained concentrations of the REE in river water and mine waters (acid mine drainage - AMD) were in the range of 0.57 μg/L (Lu) and 2579 μg/L (Ce), which is higher than previously reported in surface waters from the Iberian Pyrite Belt, but are comparable with previous findings from AMD worldwide. Total REE concentrations in river waters were ranged between 297 μg/L (Cobica River) and 7032 μg/L (Trimpancho River) with an average of 2468 μg/L. NASC (North American Shale Composite) normalized REE patterns for river and acid mine waters show clear convex curvatures in middle-REE (MREE) with respect to light- and heavy-REE. During the dissolution experiments of AMD-precipitates, heavy-REE and middle-REE generate the most enriched patterns in the solution. A small number of precipitates did not display MREE enrichment (an index Gd n /Lu n  < 1.0) in NASC normalized pattern and produced relatively lower REE concentrations in extracts. Additionally, very few samples, which mainly contained aluminum sulfates, e.g., pickeringite and alunogen, displayed light-REE enrichment relative to heavy-REE (HREE). In general, the highest retention of REE occurs in samples enriched in magnesium (epsomite or hexahydrite) and aluminum sulfates, mainly pickeringite. Copyright © 2018 Elsevier Ltd. All rights reserved.

Mobility of nutrients and trace metals during weathering in the late Archean

NASA Astrophysics Data System (ADS)

Hao, Jihua; Sverjensky, Dimitri A.; Hazen, Robert M.

2017-08-01

The evolution of the geosphere and biosphere depends on the availability of bio-essential nutrients and trace metals. Consequently, the chemical and isotopic variability of trace elements in the sedimentary record have been widely used to infer the existence of early life and fluctuations in the near-surface environment on the early Earth, particularly fluctuations in the redox state of the atmosphere. In this study, we applied late Archean weathering models (Hao et al., 2017), developed to estimate the behavior of major elements and the composition of late Archean world average river water, to explore the behavior of nutrient and trace metals and their potential for riverine transport. We focused on P, Mn, Cr, and Cu during the weathering of olivine basalt. In our standard late Archean weathering model (pCO2,g = 10-1.5 bars, pH2,g = 10-5.0 bars), crustal apatite was totally dissolved by the acidic rainwater during weathering. Our model quantitatively links the pCO2,g of the atmosphere to phosphate levels transported by rivers. The development of late Archean river water (pH = 6.4) resulted in riverine phosphate of at least 1.7 μmolar, much higher than at the present-day. At the end of the early Proterozoic snowball Earth event when pCO2,g could be 0.01-0.10 bars, river water may have transported up to 70 μmolar phosphate, depending on the availability of apatite, thereby stimulating high levels of oxygenic photosynthesis in the marine environment. Crustal levels of Mn in olivine dissolved completely during weathering, except at large extents of weathering where Mn was stored as a component of a secondary carbonate mineral. The corresponding Mn content of river water, about 1.2 μmolar, is higher than in modern river water. Whiffs of 10-5 mole O2 gas or HNO3 kg-1 H2O resulted in the formation of pyrolusite (MnO2) and abundant hematite and simultaneous dramatic decreases in the concentration of Mn(II) in the river water. Chromite dissolution resulted in negligible dissolved Cr in Archean river water. However, amorphous Cr(OH)3 representing easily-weatherable Cr-bearing minerals dissolved totally during the weathering simulations, resulting in concentrations of Cr(III) in the river water of up to 0.14 μmolar, higher than at the present-day. Late Archean weathering of accessory chalcopyrite produced chalcocite and bornite, and extremely low concentrations of Cu (<10-15 molar) because of the low solubilities of the copper sulfides. However, pulses of either O2,g or HNO3 produced native copper, chalcocite, and bornite, much more hematite, and river water containing levels of dissolved Cu comparable to the present-day. Copper mineralogy predicted by weathering models might provide a new correlation with evidence from studies of copper mineral evolution. Overall, our results implied that the redox state of the atmosphere, the pH of surface waters, and the availability of easily-weatherable minerals are all important factors controlling the dissolution of trace elements in river water. Interpretation of the sedimentary signatures of trace elements should consider not only the redox state but also the pH and availability of accessory minerals.

Cause of the chalcophile trace element enrichments marking the Holocene to Anthropocene transition in northern Chesapeake Bay sediments

NASA Astrophysics Data System (ADS)

Dolor, Marvourneen K.; Helz, George R.; McDonough, William F.

2012-04-01

In Chesapeake Bay sediments, concentrations of 15 chalcophile trace elements, half rarely determined in estuaries, display historical profiles having remarkably similar features. All element concentrations rose more or less simultaneously in the 1920-1940 interval, creating a chemostratigraphic marker of the Holocene to Anthropocene transition. Subsequently, concentration maxima occurred at ˜20-year intervals, suggesting a link to a documented climate cycle of similar period. These elements' correlated profiles suggest that sediments approximate binary mixtures of one lithogenic and one multi-element anthropogenic component. The latter component is characterized by these mass ratios (±standard error): Co/Zn 0.071 ± 0.003 Cu/Zn 0.147 ± 0.007 Ag/Zn 0.0030 ± 0.0002 Cd/Zn 0.0050 ± 0.0004 In/Zn 0.00031 ± 0.00004 Sn/Zn 0.019 ± 0.002 Sb/Zn 0.0040 ± 0.0002 Te/Zn 0.00059 ± 0.00003 Tl/Zn 0.0016 ± 0.0002 Pb/Zn 0.242 ± 0.013 Bi/Zn 0.00087 ± 0.00005 Where comparisons are possible, these ratios differ from those of contaminants in the harbor of the region's principal industrial city, Baltimore, but are surprisingly similar to those in sediment contaminants from the Susquehanna River, the Bay's chief tributary. Thus both the anthropogenic and the lithogenic components in the Bay's central channel appear to originate in the river basin. Many chalcophile element ratios in the anthropogenic component are similar to those in regional aerosols. If cumulative aerosol deposition on soils in the river basin is the source of the anthropogenic component, then the above ratios could be a regional anthropogenic signature that should be looked for more widely. Unlike Mo, the enrichment of these chalcophile elements in the Bay's sediments is not controlled by seasonal anoxia; Mo apparently possesses a unique capacity to record past redox information about estuaries owing to its high seawater concentration.

River network and watershed morphology analysis with potential implications towards basin classification

NASA Astrophysics Data System (ADS)

Bugaets, Andrey; Gartsman, Boris; Bugaets, Nadezhda

2013-04-01

Generally, the investigation of river network composition and watersheds morphology (fluvial geomorphology), constituting one of the key patterns of land surface, is a fundamental question of Earth Sciences. Recent ideas in this research field are the equilibrium and optimal, in the sense of minimum energy expenditure, river network evolution under constant or slowly varying conditions (Rodriguez-Iturbe, Rinaldo, 1997). It follows to such network behavior as self-similarity, self-affinity and self-organization. That is to say, under relatively stable conditions the river systems tend to some "good composed" form and vice-versa. Lately appearing global free available detailed DEM covers involve new possibilities in this research field. We develop new methodology and program package for river network structure and watershed morphology detailed analysis on the base of ArcMap tools. Different characteristics of river network (e.g. ordering, coefficients of Horton's laws, Shannon entropy, fractal dimension) and basin morphology (e.g. diagrams of average elevation, slope, width and energy index against distance to outlet along streams) could be calculated to find a good indicators of intensity and non-equilibrium of watershed evolution. Watersheds are non-conservative systems in which energy is dissipated by transporting water and sediment in geomorphic adjustment of the slopes and channels. The problem of estimating the amount of energy expenditure associated with overcoming surface and system resistance is extremely complicated to solve. A simplification on a river network scale is to consider energy expenditure to be primarily associated with friction of the fluid. We propose a new technique to analyze the catchment landforms based on so-called "energy function" that is a distribution of total energy index against distance from outlet. As potential energy of water on the hillslopes is transformed into kinetic energy of the flowing fluid-sediment mixture in the runoff process, the energy is dissipated from the system. The rate of energy dissipation is defined as the work that a fluid element needs to perform to overcome friction at the unit area. Appling the product of local slope and watershed area, i.e. calculating the total energy index at the different distance from outlet, one gets the watershed "energy function" E(x). Application results indicate that the proposed method could be used for watersheds classification, regionalization and paleoreconstructions. NASA-SRTM DEM of 3" resolution has been employed to analyze the 24 watersheds within Amur River Basin with area 20-70 thousand km2 (7-8 order). The study was carried out, in particular, to assess the limitation of SRTM DEM data, especially in flat terrains. The study also revealed that some of regularities investigated are described satisfactorily by well-known simplest model of drainage networks, so-called Peano's basin.

Long-term macroinvertebrate response to flow abstraction at Alpine water intakes

NASA Astrophysics Data System (ADS)

Gabbud, Chrystelle; Savioz, Amélie; Lane, Stuart

2016-04-01

The natural flow hydrological characteristics of Alpine streams, dominated by snowmelt and glacier melt, have been established for many years. More recently, the ecosystems that they sustain have been described and explained, following the hydrological, biochemical, morphodynamic, and biotic elements specific to Alpine streams. However, natural Alpine flow regimes may be strongly modified by hydroelectric power production, which impacts upon both river discharge and sediment transfer, and hence on downstream flora and fauna. These kinds of impacts are well studied where river are regulated by dams, with sediments retained behind walls, but they are much less focus on water intakes, whose storage capacity is very smaller and thus have to flush flow and sediment regularly. Here we focus on the impacts of flow abstraction on macroinvertebrates, the most widely ecological group used in freshwater biomonitoring as they act typically as indicators of environmental health. Some key generalizations can be made. For instance, in European glacially fed river systems, Plecoptera, Chironomidae, Ephemeroptera, Simuliidae, and Diptera are the main taxa found in spring as they are better adapted to cold conditions. Petts and Bickerton (1994) published macroinvertebrate samples from the upper part of the glacial stream system the Borgne d'Arolla (Valais, Switzerland), highlighting that: (1) taxa variability and productivity decline in the river because of flow abstraction, (2) 60 % of the communities were provided by tributaries, (3) there is migration upstream of the species in response to the passage from a dominant ice-melt to a snow-melt regime, (4) the colonisation is difficult because of a significant modification of the habitat in the river by sediment transport, until it becomes warmer, clearer and more stable further downstream. In order to establish the long-term impacts of flow abstraction upon instream ecology where sediment delivery is maintained but transport capacity is reduced, and to determine if the above trends are accelerated, maintained or reversed, we revisited the study of Petts and Bickerton (1994) by repeating transects of interest for both the river and the tributaries during summer 2015. Based on macroinvertebrate sampling, determinations and statistics, preliminary results show that these trends have been maintained, with macroinvertebrate presence restricted to zones immediately downstream of unregulated tributaries. Despite the river having been protected as an alluvial zone of national importance since the 1990s, there is no evidence of life in the river except in isolated tributary-fed hotspots. The data suggest that restoring this kind of system will need new approaches to manage sediment, ones that environmental flows alone are unlikely to be able to address. Reference Petts GE, Bickerton MA (1994). Influence of water abstraction on the macroinvertebrate community gradient within a glacial stream system: La Borgne d'Arolla, Valais, Switzerland. Freshwater Biology, 32:375-386.

Groundwater salinization in the Saloum (Senegal) delta aquifer: minor elements and isotopic indicators.

PubMed

Faye, Serigne; Maloszewski, Piotr; Stichler, Willibald; Trimborn, Peter; Cissé Faye, Seynabou; Bécaye Gaye, Cheikh

2005-05-01

The hydrochemistry of minor elements bromide (Br), boron (B), strontium (Sr), environmental stable isotopes (18O and 2H) together with major-ion chemistry (chloride, sodium, calcium) has been used to constrain the source(s), relative age, and processes of salinization in the Continental Terminal (CT) aquifer in the Saloum (mid-west Senegal) region. Seventy-one groundwater wells which include 24 wells contaminated by saltwater and three sites along the hypersaline Saloum River were sampled to obtain additional information on the hydrochemical characteristics of the groundwater defined in previous studies. Use of Br against Cl confirms the Saloum River saline water intrusion up to a contribution of 7% into the aquifer. In addition to this recent intrusion, a relatively ancient intrusion of the Saloum River water which had reached at least as far as 20 km south from the source was evidenced. The high molar ratio values of Sr/Cl and Sr/Ca indicate an additional input of strontium presumably derived from carbonate precipitation/dissolution reactions and also via adsorption reactions. The variable B concentrations (7-650 microg/L) found in the groundwater samples were tested against the binary mixing model to evaluate the processes of salinization which are responsible for the investigated system. Sorption of B and depletion of Na occur as the Saloum river water intrudes the aquifer (salinization) in the northern part of the region, whereas B desorption and Na enrichment occur as the fresh groundwater flushing displaces the saline waters in the coastal strip (refreshening). In the central zone where ancient intrusion prevailed, the process of freshening of the saline groundwater is indicated by the changes in major-ion chemistry as well as B desorption and Na enrichment. In addition to these processes, stable isotopes reveal that mixing with recently infiltrating waters and evaporation contribute to the changes in isotopic signature.

A Study of the Effect of Hysteresis on Transient Seepage in Levees

NASA Astrophysics Data System (ADS)

Tracy, F. T.; Walshire, L. A.; Corcoran, M. K.

2016-12-01

The capability of modeling hysteresis in soils is not often provided in commercial 2-D finite element seepage programs. However, hysteresis can be important in the modeling process. This research shows the effect of hysteresis on transient seepage results for a generic levee common to the southeastern United States where moisture content and hydraulic conductivity curves for the unsaturated zone are modeled using van Genuchten drying curves only, wetting curves only, and hysteresis. Quantities measured are (1) a levee saturation coefficient that is zero when the river is at initial conditions and one when steady-state has been achieved at the maximum river elevation, (2) the pore pressure at the toe of the levee beneath the confining layer, and (3) flow rate through the downstream flux section. A model for switching from the wetting curve to the drying curve and visa versa for hysteresis has been implemented in a 2-D finite element program to perform the described research. The levee system is considered homogeneous in this study. The hydrograph of the river for a 20-foot levee begins at -5 ft, goes up at 1 ft/day until it reaches 17.5 ft, remains for 10 days, and then descends at 1 ft/day until the river reaches -5 ft again, giving a simulation time of 55 days. Saturated hydraulic conductivity values of 0.01, 0.001, and 0.0001 cm/sec were considered. Values of the three output variables for wetting only, drying only, and hysteresis curves for the 55 days were collected, and closeness coefficients in terms of percentages were defined and computed from the collected data. It was found that the closeness coefficient was as high as 24.61% for levee saturation coefficient, 5.15% for pore pressure, and 119.93% for flow rate. Clearly, it is important to consider hysteresis in the modeling process.

The Quequén Salado river basin: Geology and biochronostratigraphy of the Mio-Pliocene boundary in the southern Pampean plain, Argentina

NASA Astrophysics Data System (ADS)

Beilinson, E.; Gasparini, G. M.; Tomassini, R. L.; Zárate, M. A.; Deschamps, C. M.; Barendregt, R. W.; Rabassa, J.

2017-07-01

The Quequén Salado river basin has been the focus of several contributions since the first decades of the XX century, namely dealing with the general geological features of the deposits and with the vertebrate remains. In this paper, the Neogene geological history documented by the Quequén Salado river exposures is reconstructed by means of stratigraphic, sedimentological and paleomagnetic studies along with the paleontological analysis of vertebrate remains. The study area is a crucial setting not only to better understand the evolution of the southern Pampas basin during the late Miocene-early Pliocene interval, but also to test the validity of the biochronologic and biostratigraphic schemes, especially the "Irenense". A geological model for the Quequén Salado river valley is proposed: a case of downcutting and headward erosion that contributes with a coherent interpretation to explain the spatial distribution of facies and fossil taxa: the younger in the distal sector of the Quequén Salado middle basin and the older in the lower basin. The sedimentary record is believed to represent the distal reaches of a distributary fluvial system that drained from the Ventania ranges. The stratigraphic section of Paso del Indio Rico results a key stratigraphic site to fully understand the stratigraphic nature of the boundary between the Miocene and the Pliocene (the Huayquerian and Montehermosan stages/ages). In this sense, two stratigraphically superposed range zones have been recognized in the area: Xenodontomys ellipticus Range Zone (latest Miocene-early Pliocene; late Huayquerian), and Eumysops laeviplicatus Range Zone (early Pliocene; Montehermosan). Taking into account the available geological and paleontological evidences, the "Irenense" would not represent a valid biostratigraphic unit, since, according to the geological model here proposed, it would be represented by elements of the Xenodontomys ellipticus Range Zone in the lower QS basin and by elements of the Eumysops laeviplicatus Range Zone in the middle QS basin.

Development of river sediment monitoring in Croatia

NASA Astrophysics Data System (ADS)

Frančišković-Bilinski, Stanislav; Bilinski, Halka; Mlakar, Marina; Maldini, Krešimir

2017-04-01

Establishment of regular river sediment monitoring, in addition to water monitoring, is very important. Unlike water, which represents the current state of a particular watercourse, sediment represents a sort of record of the state of pollution in the long run. Sediment monitoring is crucial to gain a real insight into the status of pollution of particular watercourses and to determine trends over a longer period of time. First scientific investigations of river sediment geochemistry in Croatia started 1989 in the Krka River estuary [1], while first systematic research of a river basin in Croatia was performed 2005 in Kupa River drainage basin [2]. Up to now, several detailed studies of both toxic metals and organic pollutants have been conducted in this drainage basin and some other rivers, also Croatian scientists participated in river sediment research in other countries. In 2008 Croatian water authorities (Hrvatske Vode) started preliminary sediment monitoring program, what was successfully conducted. In the first year of preliminary program only 14 stations existed, while in 2014 number of stations increased to 21. Number of monitored watercourses and of analysed parameters also increased. Current plan is to establish permanent monitoring network of river sediments throughout the state. The goal is to set up about 80 stations, which will cover all most important and most contaminated watercourses in all parts of the country [3]. Until the end of the year 2016, regular monitoring was conducted at 31 stations throughout the country. Currently the second phase of sediment monitoring program is in progress. At the moment parameters being determined on particular stations are not uniform. From inorganic compounds it is aimed to determine Cd, Pb, Ni, Hg, Cu, Cr, Zn and As on all stations. The ratio of natural concentrations of those elements vs. anthropogenic influence is being evaluated on all stations. It was found that worse situation is with Ni, Hg and Cr, who have significant anthropogenic concentrations on several locations. With other studied elements situation is much better and anthropogenic influence is not so significant. Based on own research and experience and comparing them with existing sediment quality criteria worldwide, within the current phase of monitoring program it is aimed to propose threshold values for mentioned elements, what would be base for Croatian National legislative on sediment quality. [1] Prohić, E. and Juračić, M. (1989): Heavy metals in sediments - Problems concerning determination of the anthropogenic influence. Study in the Krka River Estuary, Eastern Adriatic Coast, Yugoslavia. Environmental Geology Water Science, 13(2), 145-151. [2] Franči\\vsković-Bilinski, S. (2005): Geochemistry of stream sediments in Kupa River drainage basin [In Croatian] / Doctoral thesis. University of Zagreb, Croatia. [3] Franči\\vsković-Bilinski, S., Bilinski, H., Maldini, K. (2015): Establishing of monitoring of river sediments in Croatia. Contaminated sediments: Environmental Chemistry, Ecotoxicology and Engineering - Program and Abstract Book, Congressi Stefano Franscini, Ascona, Switzerland, 73-73.

Concentrations of arsenic, cadmium, copper, lead, selenium, and zinc in fish from the Mississippi River Basin, 1995

USGS Publications Warehouse

Schmitt, Christopher J.

2004-01-01

Fish were collected in late 1995 from 34 National Contaminant Biomonitoring Program (NCBP) stations and 12 National Water Quality Assessment Program (NAWQA) stations in the Mississippi River basin (MRB), and in late 1996 from a reference site in West Virginia. The NCBP sites represented key points (dams, tributaries, etc.) in the largest rivers of the MRB. The NAWQA sites were typically on smaller rivers and were selected to represent dominant land uses in their watersheds. The West Virginia site, which is in an Eastern U.S. watershed adjacent to the MRB, was selected to document elemental concentrations in fish used for other aspects of a larger study and to provide additional contemporaneous data on background elemental concentrations. At each site four samples, each comprising (nominally) 10 adult common carp (Cyprinus carpio, `carp') or black bass (Micropterus spp., `bass') of the same sex, were collected. The whole fish were composited by station, species, and gender for analysis of arsenic (As), lead (Pb), and selenium (Se) by atomic absorption spectroscopy and for cadmium (Cd), copper (Cu), and zinc (Zn) by inductively-coupled plasma emission spectroscopy. Concentrations of most of the elements examined were lower in both carpand bass from the reference site, a small impoundment located in a rural area, than from the NCBP and NAWQA sites on rivers and larger impoundments. In contrast, there were few overall differences between NCBP sites NAWQA sites. The 1995 results generally confirmed the continued weathering and re-distribution of these elemental contaminants in the MRB; concentrations declined or were unchanged from 1984–1986 to 1995 at most NCBP sites, thus continuing two-decade trends. Exceptions were Se at Station 77 (Arkansas R. at John Martin Reservoir, CO), where concentrations have been elevated historically and increased slightly (to 3.8–4.7 μg g-1 in bass and carp); and Pb, Cd, and Zn at Station 67 (Allegheny R. at Natrona, PA), where levels of these metals were high in the past and increased from 1986 to 1995.

The mosaic accessory gene structures of the SXT/R391-like integrative and conjugative elements derived from Vibrio spp. isolated from aquatic products and environment in the Yangtze River estuary, China

PubMed Central

2013-01-01

Background The emergence, resurgence and spread of human food-borne pathogenic Vibrios are one of the major contributors to disease burden and mortality particularly in developing countries with disputable sanitary conditions. Previous research on pathogenic Vibrio cholerae and Vibrio parahaemolitycus derived from clinical samples has proposed links between acquisition of virulence and multiple drug resistance traits and intercellular transmissibility of mobile genetic elements in the environment. To date, very few information is available on environmental Vibrio isolates. In this study, we characterized eleven Vibrio strains bearing the SXT/R391-like integrative and conjugative elements (ICEs) derived from aquatic products and environment in the Yangtze River Estuary, China. Results The eleven Vibrio strains were isolated in 2010 to 2011, and taxonomically identified, which included six Vibrio cholerae, three Vibrio parahaemolyticus, one Vibrio alginolyticus and one Vibrio natriegens. Most of the strains displayed strong resistance phenotypes to ampicillin, mercury and chromium. The majority of their ICEs, which belong to S and R exclusion system groups, contain ICEs-chromosome junction sequences and highly conserved core-genes required for ICE transfer. However, comparative sequence analysis uncovered interesting diversity in their mosaic accessory gene structures, which carry many novel genes that have not been described in any known ICEs to date. In addition, antibiotic resistance was transmitted by ICEVchChn6 and ICEVpaChn1 from V. cholerae, V. parahaemolyticus to E. coli MG1655 via conjugation, respectively. Our data also revealed that the ICEs characterized in this study are phylogenetically distant from most of the SXT/R391 ICEs reported previously, which may represent a novel cluster likely shaped by the ecological environment in the Yangtze River Estuary, China. Conclusions This study constitutes the first investigation of ICEs-positive Vibrio spp. in the Yangze River Estuary, China. The newly identified ICEs were characterized with mosaic accessory gene structures and many novel genes. The results demonstrated self-transmissibility of antibiotic resistance mediated by two of the ICEs from V. cholerae, V. parahaemolyticus to E. coli via conjugation, respectively. Our results also revealed that the ICEs examined in this study may represent a novel cluster in the SXT/R391 family. PMID:24074349

Rare Earth Element Behavior During Incongruent Weathering and Varying Discharge Conditions in Silicate Dominated River Systems: The Australian Victorian Alps

NASA Astrophysics Data System (ADS)

Hagedorn, K. B.; Cartwright, I.

2008-12-01

The distribution of rare earth elements (REE) and trace elements was measured by ICP-MS on fresh, slightly weathered and weathered granite and surface water samples from a network of 11 pristine rivers draining the Australian Victorian Alps during (i) high and (ii) low discharge conditions. River water REE concentrations are largely derived from atmospheric precipitation (rain, snow), as indicated by similar Chondrite normalized REE patterns (higher LREE over HREE; negative Ce anomalies, positive Eu anomalies) and similar total REE concentrations during both dry and wet seasons. Calculations based on the covariance between REE and Cl concentrations and oxygen and hydrogen isotopes indicate precipitation input coupled with subsequent evaporation may account for 30% o 100% of dissolved REE in stream waters. The dissolved contribution to the granitic substratum to stream water comes mainly from the transformation of plagioclase to smectite, kaolinite and gibbsite and minor apatite dissolution. However, since most REE of the regional granite are present in accessory minerals (titanite, zircon, etc.) they do not significantly contribute to the river REE pool. REE concentrations drop sharply downstream as a result of dilution and chemical attenuation. A trend of downstream enrichment of the heavier REE is due to selective partitioning of the lighter REE (as both free REE or REECO3 complexes) to hydrous oxides of suspended Al which, in turn, is controlled by a downstream increase of pH to values > 6.1 (for free REE) and > 7.3 (for REECO3 complexes). Although most circumneutral waters were supersaturated with REE phosphate compounds, precipitation of LnPO4 is not believed to have been a dominant process because the predicted phosphate fractionation pattern is inconsistent with the observed trends. Negative saturation indices of hydrous ferric oxides also militate against surface complexation onto goethite. Instead, REE attenuation most likely resulted from adsorption onto hydrous aluminium oxide. Seasonally, higher total REE concentrations during the dry season are due to longer residence time of water within rock fractures as well as high rainfall REE concentrations which, for the summer of 2007, might be related to organic carbon rich dust released after bushfires in the region. Lower pH values and low oxidation potentials at that time also contribute to raise REE concentrations through desorption.

Scientific Drilling in the Snake River Plain: Past, Present, and Future

NASA Astrophysics Data System (ADS)

Shervais, J. W.; Hanan, B. B.; Hughes, S. S.; Geist, D.; Vetter, S. K.

2006-12-01

The Snake River-Yellowstone volcanic province has long been linked to the concept of lithospheric drift over a fixed mantle thermal anomaly or hotspot. This concept is reinforced by seismic tomography that images this anomaly to depths around 500 km, but alternative proposals still present a serious challenge. Basaltic volcanism spans a significant age range and basaltic volcanism in the western SRP lies well off the hotspot track and cannot be related directly to the hotspot in any simple way. The plume-track age progression is documented by rhyolite volcanic centers, but even these represent extended time periods that overlap in age with adjacent centers. Scientific drilling projects carried out over the last two decades have made significant contributions to our understanding of both basaltic and rhyolitic volcanism associated with the Snake River-Yellowstone hotspot system. Because these drill holes also intercept sedimentary interbeds or, in the case of the western SRP, thick sections of Pliocene and Pleistocene sediments, they have also contributed to our understanding of basin formation by thermal collapse in the wake of the hotspot passage or by rifting, paleoclimate of the interior west, and groundwater systems in volcanic rocks. Many of these drill holes are associated with the Idaho National Laboratory (INL) in the eastern plain; others were drilled for geothermal or petroleum exploration. The latter include older holes that were not instrumented or logged in detail, but which still provide valuable stratigraphic controls. We focus here on the result of basalt drilling, which have been high-lighted in recent publications. Basaltic volcanism in the Snake River plain is dominated by olivine tholeiites that have major and trace element characteristics of ocean island basalt: the range in MgO is similar to MORB, but Ti, Fe, P, K, Sr, Zr and LREE/HREE ratios are all higher. Recent studies of basalts from the drill holes show that they evolved by fractionation in a mid-crustal sill complex that has been imaged seismically. Further, the chemical and isotopic systematics of these basalts require assimilation of consanguineous mafic material inferred to represent previously intruded sills. Major and trace element modeling suggest formation of the primary melts by melting of a source similar to E- MORB source. Trace element systematics document mixing between a plume-like source and a more depleted source that is not DMM. A similar more depleted source is inferred for Hawaii, suggesting that it is not continental lithosphere. Future scientific drilling in the SRP is the focus of Project HOTSPOT, a multi-disciplinary initiative that seeks to document time-space variations in the SRP-Yellowstone volcanic system. A workshop sponsored by the International Continental Drilling Program was held in May 2006 to develop a targeted program of scientific drilling that examines the entire plume-lithosphere system across a major lithospheric boundary, with holes targeting basalt, rhyolite, and sediments. These drill holes will complement geophysical studies of continental dynamics (e.g., Earthscope), as well as current studies centered on Yellowstone. Additional components of a targeted drilling program include studies of lacustrine sediments that document paleoclimate change in North America during the Pliocene—Pleistocene and fluid flow at deeper crustal levels.

Mechanisms of nutrient retention and its relation to flow connectivity in river-floodplain corridors

USGS Publications Warehouse

Larsen, Laurel; Harvey, Judson; Maglio, Morgan M.

2015-01-01

Understanding heterogeneity or patchiness in the distribution of vegetation and retention of C and nutrients in river corridors is critical for setting priorities for river management and restoration. Several mechanisms of spatial differentiation in nutrient retention in river and floodplain corridors have been recognized, but few studies have distinguished their relative importance or established their role in long-term geomorphic change, nutrient retention, and connectivity with downstream systems. We evaluated the ability of 3 mechanisms (evapotranspiration focusing [EF], differential hydrologic exchange [DHE], and particulate nutrient redistribution [PNR]) to explain spatial patterns of P retention and function in the Everglades (Florida, USA). We used field measurements in sloughs and on slightly higher, more densely vegetated ridges to quantify P fluxes attributable to the 3 mechanisms. EF does not explain Everglades nutrient retention or P concentrations on ridges and in sloughs. However, DHE resulting from different periods of groundwater–surface-water connectivity across topographic elements is the primary cause of elevated P concentrations on ridges and completely explains interpatch differences in long-term P accumulation rates. With historical flow velocities, which were an order of magnitude higher than at present, PNR would have further increased the interpatch difference in long-term P retention rates nearly 2-fold. In conclusion, DHE and PNR are the dominant drivers of nutrient patchiness in the Everglades and are hypothesized to be important in P-limited river and floodplain corridors globally.

Delineation and validation of river network spatial scales for water resources and fisheries management.

PubMed

Wang, Lizhu; Brenden, Travis; Cao, Yong; Seelbach, Paul

2012-11-01

Identifying appropriate spatial scales is critically important for assessing health, attributing data, and guiding management actions for rivers. We describe a process for identifying a three-level hierarchy of spatial scales for Michigan rivers. Additionally, we conduct a variance decomposition of fish occurrence, abundance, and assemblage metric data to evaluate how much observed variability can be explained by the three spatial scales as a gage of their utility for water resources and fisheries management. The process involved the development of geographic information system programs, statistical models, modification by experienced biologists, and simplification to meet the needs of policy makers. Altogether, 28,889 reaches, 6,198 multiple-reach segments, and 11 segment classes were identified from Michigan river networks. The segment scale explained the greatest amount of variation in fish abundance and occurrence, followed by segment class, and reach. Segment scale also explained the greatest amount of variation in 13 of the 19 analyzed fish assemblage metrics, with segment class explaining the greatest amount of variation in the other six fish metrics. Segments appear to be a useful spatial scale/unit for measuring and synthesizing information for managing rivers and streams. Additionally, segment classes provide a useful typology for summarizing the numerous segments into a few categories. Reaches are the foundation for the identification of segments and segment classes and thus are integral elements of the overall spatial scale hierarchy despite reaches not explaining significant variation in fish assemblage data.

The effect of mining on the sediment - trace element geochemistry of cores from the Cheyenne River arm of Lake Oahe, South Dakota, U.S.A.

USGS Publications Warehouse

Horowitz, A.J.; Elrick, K.A.; Callender, E.

1988-01-01

Six cores, ranging in length from 1 to 2 m, were collected in the Cheyenne River arm of Lake Oahe, South Dakota, to investigate potential impacts from gold-mining operations around Lead, South Dakota. Sedimentation rates in the river arm appear to be event-dominated and rapid, on the order of 6-7 cm yr.-1. All the chemical concentrations in the core samples fall within the wide ranges previously reported for the Pierre Shale of Cretaceous age and with the exception of As, generally are similar to bed sediment levels in the Cheyenne River, Lake Oahe and Foster Bay. Based on the downcore distribution of Mn, it appears that reducing conditions exist in the sediment column of the river arm below 2-3 cm. The reducing conditions do not appear to be severe enough to produce differentiation of Fe and Mn throughout the sediment column in the river arm. Cross-correlations for high-level metal-bearing strata within the sediment column can be made for several strata and for several cores; however, cross-correlations for all the high-level metal-bearing strata are not feasible. As is the only element which appears enriched in the core samples compared to surface sediment levels. Well-crystallized arsenopyrite was found in high-As bearing strata from two cores and probably was transported in that form from reducing sediment-storage sites in the banks or floodplains of Whitewood Creek and the Belle Fourche River. It has not oxidized due to the reducing conditions in the sediment column of the Cheyenne River arm. Some As may also be transported in association with Fe- and Mn-oxides and -hydroxides, remobilized under the reducing conditions in the river arm, and then reprecipitated in authigenic sulfide phases. In either case, the As appears to be relatively immobile in the sediment column. ?? 1988.

RiverHeath: Neighborhood Loop Geothermal Exchange System

DOE Office of Scientific and Technical Information (OSTI.GOV)

Geall, Mark

2016-07-11

The goal of the RiverHeath project is to develop a geothermal exchange system at lower capital infrastructure cost than current geothermal exchange systems. The RiverHeath system features an innovative design that incorporates use of the adjacent river through river-based heat exchange plates. The flowing water provides a tremendous amount of heat transfer. As a result, the installation cost of this geothermal exchange system is lower than more traditional vertical bore systems. Many urban areas are located along rivers and other waterways. RiverHeath will serve as a template for other projects adjacent to the water.

Identification and on-line monitoring of reduced sulphur species (RSS) by voltammetry in oxic waters.

PubMed

Superville, Pierre-Jean; Pižeta, Ivanka; Omanović, Dario; Billon, Gabriel

2013-08-15

Based on automatic on-line measurements on the Deûle River that showed daily variation of a peak around -0.56V (vs Ag|AgCl 3M), identification of Reduced Sulphur Species (RSS) in oxic waters was performed applying cathodic stripping voltammetry (CSV) with the hanging mercury drop electrode (HMDE). Pseudopolarographic studies accompanied with increasing concentrations of copper revealed the presence of elemental sulphur S(0), thioacetamide (TA) and reduced glutathione (GSH) as the main sulphur compounds in the Deûle River. In order to resolve these three species, a simple procedure was developed and integrated in an automatic on-line monitoring system. During one week monitoring with hourly measurements, GSH and S(0) exhibited daily cycles whereas no consequential pattern was observed for TA. Copyright © 2013 Elsevier B.V. All rights reserved.

Water Quality in the Nation's Streams and Aquifers Overview of Selected Findings, 1991-2001

USGS Publications Warehouse

Hamilton, Pixie A.; Miller, Timothy L.; Myers, Donna N.

2004-01-01

This report accompanies the publication of the last 15 of 51 river basin and aquifer assessments by the USGS National Water-Quality Assessment (NAWQA) Program during 1991?2001. It highlights selected water-quality findings of regional and national interest through examples from river basins and aquifer systems across the Nation. Forthcoming reports in the USGS series ?The Quality of Our Nation?s Waters? will present comprehensive national syntheses of information collected in the 51 study units on pesticides in water, sediment, and fish; volatile organic compounds in major aquifers used for domestic and public supply; nutrients and trace elements in streams and ground water; and aquatic ecology. This report, summaries of the 51 water-quality assessments, and a 1999 national synthesis of information on nutrients and pesticides, are available free of charge as USGS Circulars and on the World Wide Web at http://water.usgs.gov/nawqa/nawqa_sumr.html.

Organization of the sleep-related neural systems in the brain of the river hippopotamus (Hippopotamus amphibius): A most unusual cetartiodactyl species.

PubMed

Dell, Leigh-Anne; Patzke, Nina; Spocter, Muhammad A; Bertelsen, Mads F; Siegel, Jerome M; Manger, Paul R

2016-07-01

This study provides the first systematic analysis of the nuclear organization of the neural systems related to sleep and wake in the basal forebrain, diencephalon, midbrain, and pons of the river hippopotamus, one of the closest extant terrestrial relatives of the cetaceans. All nuclei involved in sleep regulation and control found in other mammals, including cetaceans, were present in the river hippopotamus, with no specific nuclei being absent, but novel features of the cholinergic system, including novel nuclei, were present. This qualitative similarity relates to the cholinergic, noradrenergic, serotonergic, and orexinergic systems and is extended to the γ-aminobutyric acid (GABA)ergic elements of these nuclei. Quantitative analysis reveals that the numbers of pontine cholinergic (259,578) and noradrenergic (127,752) neurons, and hypothalamic orexinergic neurons (68,398) are markedly higher than in other large-brained mammals. These features, along with novel cholinergic nuclei in the intralaminar nuclei of the dorsal thalamus and the ventral tegmental area of the midbrain, as well as a major expansion of the hypothalamic cholinergic nuclei and a large laterodorsal tegmental nucleus of the pons that has both parvocellular and magnocellular cholinergic neurons, indicates an unusual sleep phenomenology for the hippopotamus. Our observations indicate that the hippopotamus is likely to be a bihemispheric sleeper that expresses REM sleep. The novel features of the cholinergic system suggest the presence of an undescribed sleep state in the hippopotamus, as well as the possibility that this animal could, more rapidly than other mammals, switch cortical electroencephalographic activity from one state to another. J. Comp. Neurol. 524:2036-2058, 2016. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

Semi-volatile organic compounds and trace elements in the Yangtze River source of drinking water.

PubMed

Wu, Bing; Zhang, Xuxiang; Zhang, Xiaolin; Yasun, Aishangjiang; Zhang, Yan; Zhao, Dayong; Ford, Tim; Cheng, Shupei

2009-08-01

Determination of 24 semi-volatile organic compounds (SVOCs) and 24 trace elements in water samples was conducted in order to investigate the quality of the Nanjing source of drinking water taken from Yangtze River. The total concentrations of SVOCs and trace elements were in the range of 1,951-11,098 ng/l and 51,274-72,384 microg/l, respectively. No significant seasonal changes were found for the pollutants' concentrations. A primary health risk assessment was carried out to evaluate potential health effects. Risk quotients involving carcinogenic effects for benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, dibenz(a,h)anthracene, bis(2-ethylhexyl)phthalate and arsenic were >1 under the worst-case scenario. The results of this study demonstrate the importance of further studies on the environmental health effects of exposure to the source water.

Selected well and ground-water chemistry data for the Boise River Valley, southwestern Idaho, 1990-95

USGS Publications Warehouse

Parliman, D.J.; Boyle, Linda; Nicholls, Sabrina

1996-01-01

Water samples were collected from 903 wells in the Boise River Valley, Idaho, from January 1990 through December 1995. Selected well information and analyses of 1,357 water samples are presented. Analyses include physical properties ad concentrations of nutrients, bacteria, major ions, selected trace elements, radon-222, volatile organic compounds, and pesticides.

Seasonal assessment of trace element contamination in intertidal sediments of the meso-macrotidal Hooghly (Ganges) River Estuary with a note on mercury speciation.

PubMed

Mondal, Priyanka; de Alcântara Mendes, Rosivaldo; Jonathan, M P; Biswas, Jayanta Kumar; Murugan, Kadarkarai; Sarkar, Santosh Kumar

2018-02-01

The spatial and seasonal distribution of trace elements (TEs) (n=16) in surficial sediment were examined along the Hooghly River Estuary (~175km), India. A synchronous elevation of majority of TEs concentration (mgkg -1 ) was encountered during monsoon with the following descending order: Al (67070); Fe (31300); Cd (5.73); Cr (71.17); Cu (29.09); Mn (658.74); Ni (35.89). An overall low and homogeneous concentration of total Hg (T Hg =17.85±4.98ngg -1 ) was recorded in which methyl mercury (MeHg) shared minor fraction (8-31%) of the T Hg . Sediment pollution indices, viz. geo-accumulation index (I geo ) and enrichment factor (EF) for Cd (I geo =1.92-3.67; EF=13.83-31.17) and Ba (I geo =0.79-5.03; EF=5.79-108.94) suggested high contamination from anthropogenic sources. From factor analysis it was inferred that TEs primarily originated from lithogenic sources. This study would provide the latest benchmark of TE pollution along with the first record of MeHg in this fluvial system which recommends reliable monitoring to safeguard geochemical health of this stressed environment. Copyright © 2017 Elsevier Ltd. All rights reserved.

Wind River Watershed Restoration: Annual report April 2006 to March 2007

USGS Publications Warehouse

Connolly, Patrick J.; Jezorek, Ian G.; Munz, Carrie S.

2007-01-01

This report summarizes work completed by U.S. Geological Survey’s Columbia River Research Laboratory (USGS-CRRL) in the Wind River subbasin during the period April 2006 through March 2007 under Bonneville Power Administration (BPA) contract 26922. During this period, we collected temperature, flow, and habitat data to characterize physical habitat condition and variation within and among tributaries and mainstem sections in the Wind River subbasin. We also conducted electrofishing and snorkeling surveys to determine juvenile salmonid populations within select study areas throughout the subbasin. Portions of this work were completed with additional funding from U.S. Fish and Wildlife Service (USFWS) and the Lower Columbia Fish Enhancement Group (LCFEG). Funding from USFWS was for work to contribute to a study of potential interactions between introduced Chinook salmon Oncorhynchus tshawytscha and wild steelhead O. mykiss. Funding from LCFEG was for work to evaluate the effects of nutrient enrichment in small streams. A statement of work (SOW) was submitted to BPA in March 2006 that outlined work to be performed by USGS-CRRL. The SOW was organized by work elements, with each describing a research task. This report summarizes the progress completed under each work element.

Wind River Watershed Restoration, 2006-2007 Annual Report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Connolly, Patrick J.; Jezorek, Ian G.; Munz, Carrie S.

2008-11-04

This report summarizes work completed by U.S. Geological Survey's Columbia River Research Laboratory (USGS-CRRL) in the Wind River subbasin during the period April 2006 through March 2007 under Bonneville Power Administration (BPA) contract 26922. During this period, we collected temperature, flow, and habitat data to characterize physical habitat condition and variation within and among tributaries and mainstem sections in the Wind River subbasin. We also conducted electrofishing and snorkeling surveys to determine juvenile salmonid populations within select study areas throughout the subbasin. Portions of this work were completed with additional funding from U.S. Fish and Wildlife Service (USFWS) and themore » Lower Columbia Fish Enhancement Group (LCFEG). Funding from USFWS was for work to contribute to a study of potential interactions between introduced Chinook salmon Oncorhynchus tshawytscha and wild steelhead O. mykiss. Funding from LCFEG was for work to evaluate the effects of nutrient enrichment in small streams. A statement of work (SOW) was submitted to BPA in March 2006 that outlined work to be performed by USGS-CRRL. The SOW was organized by work elements, with each describing a research task. This report summarizes the progress completed under each work element.« less

Toxicity and bioavailability of metals in the Missouri River adjacent to a lead refinery

USGS Publications Warehouse

Chapman, Duane C.; Allert, Ann L.; Fairchild, James F.; May, Thomas W.; Schmitt, Christopher J.; Callahan, Edward V.

2001-01-01

This study is an evaluation of the potential environmental impacts of contaminated groundwater from the ASARCO metals refining facility adjacent to the Missouri River in Omaha, Nebraska. Surface waters, sediments, and sediment pore waters were collected from the Burt-Izard drain, which transects the facility, and from the Missouri River adjacent to the facility. Groundwater was also collected from the facility. Waters and sediments were analyzed for inorganic contaminants, and the toxicity of the waters was evaluated with the Ceriodaphnia dubia 7-day test. Concentrations of several elemental contaminants were highly elevated in the groundwater, but not in river sediment pore waters. Lead concentrations were moderately elevated in whole sediment at one site, but lead concentrations in pore waters were low due to apparent sequestration by acid-volatile sulfides. The groundwater sample was highly toxic to C. dubia, causing 100% mortality. Even at the lowest groundwater concentration tested (6.25%) C. dubia survival was reduced; however, at that concentration, reproduction was not significantly different from upstream porewater reference samples. Sediment pore waters were not toxic, except reproduction in pore water collected from one downstream site was somewhat reduced. The decrease in reproduction could not be attributed to measured elemental contaminants.

Graph Theory-Based Technique for Isolating Corrupted Boundary Conditions in Continental-Scale River Network Hydrodynamic Simulation

NASA Astrophysics Data System (ADS)

Yu, C. W.; Hodges, B. R.; Liu, F.

2017-12-01

Development of continental-scale river network models creates challenges where the massive amount of boundary condition data encounters the sensitivity of a dynamic nu- merical model. The topographic data sets used to define the river channel characteristics may include either corrupt data or complex configurations that cause instabilities in a numerical solution of the Saint-Venant equations. For local-scale river models (e.g. HEC- RAS), modelers typically rely on past experience to make ad hoc boundary condition adjustments that ensure a stable solution - the proof of the adjustment is merely the sta- bility of the solution. To date, there do not exist any formal methodologies or automated procedures for a priori detecting/fixing boundary conditions that cause instabilities in a dynamic model. Formal methodologies for data screening and adjustment are a critical need for simulations with a large number of river reaches that draw their boundary con- dition data from a wide variety of sources. At the continental scale, we simply cannot assume that we will have access to river-channel cross-section data that has been ade- quately analyzed and processed. Herein, we argue that problematic boundary condition data for unsteady dynamic modeling can be identified through numerical modeling with the steady-state Saint-Venant equations. The fragility of numerical stability increases with the complexity of branching in river network system and instabilities (even in an unsteady solution) are typically triggered by the nonlinear advection term in Saint-Venant equations. It follows that the behavior of the simpler steady-state equations (which retain the nonlin- ear term) can be used to screen the boundary condition data for problematic regions. In this research, we propose a graph-theory based method to isolate the location of corrupted boundary condition data in a continental-scale river network and demonstrate its utility with a network of O(10^4) elements. Acknowledgement: This research is supported by the National Science Foundation un- der grant number CCF-1331610.

Evidence for major input of riverine organic matter into the ocean

USGS Publications Warehouse

Cao, Xiaoyan; Aiken, George R.; Butler, Kenna D.; Huntington, Thomas G.; Balch, William M.; Mao, Jingdong; Schmidt-Rohr, Klaus

2018-01-01

The changes in the structure of XAD-8 isolated dissolved organic matter (DOM) samples along a river (Penobscot River) to estuary (Penobscot Bay) to ocean (across the Gulf of Maine) transect and from the Pacific Ocean were investigated using selective and two dimensional (2D) nuclear magnetic resonance (NMR) spectroscopy coupled with elemental and carbon isotope analysis. The results provide important insights into the nature of relatively stable structures in the river-to-ocean continuum and the enigma of the fate of terrestrial DOM in the marine system. First, lignin and carboxyl-rich alicyclic molecules (CRAMs), which are indistinguishable from mass spectrometry, were clearly differentiated with NMR spectroscopy. NMR unambiguously showed that CRAMs persisted along the river-to-ocean transect and in the Pacific Ocean, while lignin residues dramatically decreased in abundance from the river to the coastal ocean and the Pacific Ocean. The results challenge a previous conclusion that lignin-derived compounds are refractory and can accumulate in the coastal ocean. The loss of terrestrial plant-derived aromatic compounds such as lignin and tannin residues throughout the sequence of riverine, coastal, and open ocean DOM extracts could also partially explain the decreasing organic carbon recovery by XAD-8 isolation and the change in carbon stable isotope composition from riverine DOM (δ13C −27.6‰) to ocean DOM (δ13C −23.0‰) extracts. The observation, from advanced NMR, of similar CRAM molecules in XAD-8 isolated DOM samples from the Penobscot River to the Penobscot Bay and from the ocean refutes a previous conclusion that XAD-isolated DOM samples from seawater and river are distinctly different. The alicyclic structural features of CRAMs and their presence as the major structural units in DOM extracts from the Penobscot River to Gulf of Maine transect, together with the deduced old 14C age of CRAMs in the ocean, imply that terrestrial CRAMs may persist on timescales long enough to be transported into the ocean.

Modelling of river plume dynamics in Öre estuary (Baltic Sea) with Telemac-3D hydrodynamic model

NASA Astrophysics Data System (ADS)

Sokolov, Alexander

2016-04-01

The main property of river plumes is their buoyancy, fresh water discharged by rivers is less dense than the receiving, saline waters. To study the processes of plume formation in case of river discharge into a brackish estuary where salinity is low (3.5 - 5 psu) a three dimensional hydrodynamic model was applied to the Öre estuary in the Baltic Sea. This estuary is a small fjord-like bay in the north part of the Baltic Sea. Size of the bay is about 8 by 8 km with maximum depth of 35 metres. River Öre has a small average freshwater discharge of 35 m3/s. But in spring during snowmelt the discharge can be many times higher. For example, in April 2015 the discharge increased from 8 m3/s to 160 m3/s in 18 days. To study river plume dynamics a finite element based three dimensional baroclinic model TELEMAC - 3D is used. The TELEMAC modelling suite is developed by the National Laboratory of Hydraulics and Environment (LNHE) of Electricité de France (EDF). Modelling domain was approximated by an unstructured mesh with element size varies from 50 to 500 m. In vertical direction a sigma-coordinate with 20 layers was used. Open sea boundary conditions were obtained from the Baltic Sea model HIROMB-BOOS using COPERNICUS marine environment monitoring service. Comparison of modelling results with observations obtained by BONUS COCOA project's field campaign in Öre estuary in 2015 shows that the model plausible simulate river plume dynamics. Modelling of age of freshwater is also discussed. This work resulted from the BONUS COCOA project was supported by BONUS (Art 185), funded jointly by the EU and the Swedish Research Council Formas.

Source Identification and Apportionment of Trace Elements in Soils in the Yangtze River Delta, China.

PubMed

Shao, Shuai; Hu, Bifeng; Fu, Zhiyi; Wang, Jiayu; Lou, Ge; Zhou, Yue; Jin, Bin; Li, Yan; Shi, Zhou

2018-06-12

Trace elements pollution has attracted a lot of attention worldwide. However, it is difficult to identify and apportion the sources of multiple element pollutants over large areas because of the considerable spatial complexity and variability in the distribution of trace elements in soil. In this study, we collected total of 2051 topsoil (0⁻20 cm) samples, and analyzed the general pollution status of soils from the Yangtze River Delta, Southeast China. We applied principal component analysis (PCA), a finite mixture distribution model (FMDM), and geostatistical tools to identify and quantitatively apportion the sources of seven kinds of trace elements (chromium (Cr), cadmium (Cd), mercury (Hg), copper (Cu), zinc (Zn), nickel (Ni), and arsenic (As)) in soil. The PCA results indicated that the trace elements in soil in the study area were mainly from natural, multi-pollutant and industrial sources. The FMDM also fitted three sub log-normal distributions. The results from the two models were quite similar: Cr, As, and Ni were mainly from natural sources caused by parent material weathering; Cd, Cu, and Zu were mainly from mixed sources, with a considerable portion from anthropogenic activities such as traffic pollutants, domestic garbage, and agricultural inputs, and Hg was mainly from industrial wastes and pollutants.

Techniques and equipment required for precise stream gaging in tide-affected fresh-water reaches of the Sacramento River, California

USGS Publications Warehouse

Smith, Winchell

1971-01-01

Current-meter measurements of high accuracy will be required for calibration of an acoustic flow-metering system proposed for installation in the Sacramento River at Chipps Island in California. This report presents an analysis of the problem of making continuous accurate current-meter measurements in this channel where the flow regime is changing constantly in response to tidal action. Gaging-system requirements are delineated, and a brief description is given of the several applicable techniques that have been developed by others. None of these techniques provides the accuracies required for the flowmeter calibration. A new system is described--one which has been assembled and tested in prototype and which will provide the matrix of data needed for accurate continuous current-meter measurements. Analysis of a large quantity of data on the velocity distribution in the channel of the Sacramento River at Chipps Island shows that adequate definition of the velocity can be made during the dominant flow periods--that is, at times other than slack-water periods--by use of current meters suspended at elevations 0.2 and 0.8 of the depth below the water surface. However, additional velocity surveys will be necessary to determine whether or not small systematic corrections need be applied during periods of rapidly changing flow. In the proposed system all gaged parameters, including velocities, depths, position in the stream, and related times, are monitored continuously as a boat moves across the river on the selected cross section. Data are recorded photographically and transferred later onto punchcards for computer processing. Computer programs have been written to permit computation of instantaneous discharges at any selected time interval throughout the period of the current meter measurement program. It is anticipated that current-meter traverses will be made at intervals of about one-half hour over periods of several days. Capability of performance for protracted periods was, consequently, one of the important elements in system design. Analysis of error sources in the proposed system indicates that errors in individual computed discharges can be kept smaller than 1.5 percent if the expected precision in all measured parameters is maintained.

A Comparative Study Environmental and Radiological Causes Of Cancer In River Nile State, Sudan

NASA Astrophysics Data System (ADS)

Hamid, Eyad; Khair, Hatim

The causes of cancer in River Nile state are differ between environmental and radiological, this paper tried to make comparison between the two causes, to determine the real cause behind the large rising of cancer cases in this state, considering the daily habits for the patients and the possible contamination in the natural resources around them. The noticeable thing that most of cancer cases are might be due to the high concentration of nitrate pollutant detected in natural resources such as drinking water; also by looking to the radioactive elements we see there's high concentration of some radioactive elements specially the K-40 which found in Portulaca Oleracea.

Benchmark model correction of monitoring system based on Dynamic Load Test of Bridge

NASA Astrophysics Data System (ADS)

Shi, Jing-xian; Fan, Jiang

2018-03-01

Structural health monitoring (SHM) is a field of research in the area, and it’s designed to achieve bridge safety and reliability assessment, which needs to be carried out on the basis of the accurate simulation of the finite element model. Bridge finite element model is simplified of the structural section form, support conditions, material properties and boundary condition, which is based on the design and construction drawings, and it gets the calculation models and the results.But according to the design and specification requirements established finite element model due to its cannot fully reflect the true state of the bridge, so need to modify the finite element model to obtain the more accurate finite element model. Based on Da-guan river crossing of Ma - Zhao highway in Yunnan province as the background to do the dynamic load test test, we find that the impact coefficient of the theoretical model of the bridge is very different from the coefficient of the actual test, and the change is different; according to the actual situation, the calculation model is adjusted to get the correct frequency of the bridge, the revised impact coefficient found that the modified finite element model is closer to the real state, and provides the basis for the correction of the finite model.

Reach-scale characterization of large woody debris in a low-gradient, Midwestern U.S.A. river system

NASA Astrophysics Data System (ADS)

Martin, Derek J.; Pavlowsky, Robert T.; Harden, Carol P.

2016-06-01

Addition of large woody debris (LWD) to rivers has increasingly become a popular stream restoration strategy, particularly in river systems of the Midwestern United States. However, our knowledge of LWD dynamics is mostly limited to high gradient montane river systems, or coastal river systems. The LWD-related management of low-gradient, Midwestern river systems is thus largely based on higher gradient analogs of LWD dynamics. This research characterizes fluvial wood loads and investigates the relationships between fluvial wood, channel morphology, and sediment deposition in a relatively low-gradient, semiconfined, alluvial river. The LWD and channel morphology were surveyed at nine reaches along the Big River in southeastern Missouri to investigate those relationships in comparison to other regions. Wood loads in the Big River are low (3-114 m3/100 m) relative to those of higher gradient river systems of the Pacific Northwest, but high relative to lower-gradient river systems of the Eastern United States. Wood characteristics such as size and orientation suggest that the dominant LWD recruitment mechanism in the Big River is bank erosion. Also, ratios of wood geometry to channel geometry show that the Big River maintains a relatively high wood transport capacity for most of its length. Although LWD creates sites for sediment storage, the overall impact on reach-scale sediment storage in the Big River is low (< 4.2% of total in-channel storage). However, wood loads, and thus opportunities for sediment storage, have the potential to grow in the future as Midwestern riparian forests mature. This study represents the first of its kind within this particular type of river system and within this region and thus serves as a basis for understanding fluvial wood dynamics in low-gradient river systems of the Midwestern United States.

Syringe filtration methods for examining dissolved and colloidal trace element distributions in remote field locations

NASA Technical Reports Server (NTRS)

Shiller, Alan M.

2003-01-01

It is well-established that sampling and sample processing can easily introduce contamination into dissolved trace element samples if precautions are not taken. However, work in remote locations sometimes precludes bringing bulky clean lab equipment into the field and likewise may make timely transport of samples to the lab for processing impossible. Straightforward syringe filtration methods are described here for collecting small quantities (15 mL) of 0.45- and 0.02-microm filtered river water in an uncontaminated manner. These filtration methods take advantage of recent advances in analytical capabilities that require only small amounts of waterfor analysis of a suite of dissolved trace elements. Filter clogging and solute rejection artifacts appear to be minimal, although some adsorption of metals and organics does affect the first approximately 10 mL of water passing through the filters. Overall the methods are clean, easy to use, and provide reproducible representations of the dissolved and colloidal fractions of trace elements in river waters. Furthermore, sample processing materials can be prepared well in advance in a clean lab and transported cleanly and compactly to the field. Application of these methods is illustrated with data from remote locations in the Rocky Mountains and along the Yukon River. Evidence from field flow fractionation suggests that the 0.02-microm filters may provide a practical cutoff to distinguish metals associated with small inorganic and organic complexes from those associated with silicate and oxide colloids.

[Ecological risk evaluation of heavy metals of the typical dredged mud in Shanghai].

PubMed

Tang, Qing-Li; Cheng, Jin-Ping; Gao, Hao-Min; Yao, Lei; Jiang, Zhen-Yi; Wu, Yang; Xie, Cui-Song; Liang, Hai; Wang, He; Pi, Shuai-Shuai; Yu, Zhao-Yi

2013-04-01

In order to discuss the potential ecological risk of heavy metals of the typical dredged mud in Shanghai, the Hakanson potential ecological risks method was used to analyse and assess the potential ecological risks of heavy metals, including Hg, Cd, Cu, Pb, As,Cr and Zn in dredged mud from the following three areas-the dock apron of Huangpu River, the mouth of the Yangtze River and inland waterways. The results showed that the mean values of ecological risk index (Er(i)) of the seven heavy metals are 20.05, 17.49, 8.82, 5.71, 4.68, 1.74 and 1.13, respectively, all of which belonged to the low ecological risk; Cd (one location in inland waterways) and Hg (three locations in the mouth of the Yangtze River and one location in inland waterways) are the most hazardous elements, with the Er(i) > 40, which belonged to the medium ecological risk or the high ecological risk, and other elements belonged to the low ecological risk. From the results of ecological risk indices(ERI) of the heavy metals in Shanghai dredged mud, the risk of the heavy metals belonged to the low ecological risk. The ERI of inland waterways, the mouth of the Yangtze River and the dock apron of the Huangpu River were 81.4, 57.7 and 52.5, respectively, which all belong to the low ecological risk.

Spatial characterization of dissolved trace elements and heavy metals in the upper Han River (China) using multivariate statistical techniques.

PubMed

Li, Siyue; Zhang, Quanfa

2010-04-15

A data matrix (4032 observations), obtained during a 2-year monitoring period (2005-2006) from 42 sites in the upper Han River is subjected to various multivariate statistical techniques including cluster analysis, principal component analysis (PCA), factor analysis (FA), correlation analysis and analysis of variance to determine the spatial characterization of dissolved trace elements and heavy metals. Our results indicate that waters in the upper Han River are primarily polluted by Al, As, Cd, Pb, Sb and Se, and the potential pollutants include Ba, Cr, Hg, Mn and Ni. Spatial distribution of trace metals indicates the polluted sections mainly concentrate in the Danjiang, Danjiangkou Reservoir catchment and Hanzhong Plain, and the most contaminated river is in the Hanzhong Plain. Q-model clustering depends on geographical location of sampling sites and groups the 42 sampling sites into four clusters, i.e., Danjiang, Danjiangkou Reservoir region (lower catchment), upper catchment and one river in headwaters pertaining to water quality. The headwaters, Danjiang and lower catchment, and upper catchment correspond to very high polluted, moderate polluted and relatively low polluted regions, respectively. Additionally, PCA/FA and correlation analysis demonstrates that Al, Cd, Mn, Ni, Fe, Si and Sr are controlled by natural sources, whereas the other metals appear to be primarily controlled by anthropogenic origins though geogenic source contributing to them. 2009 Elsevier B.V. All rights reserved.

Real-time 4D ERT monitoring of river water intrusion into a former nuclear disposal site using a transient warping-mesh water table boundary (Invited)

NASA Astrophysics Data System (ADS)

Johnson, T.; Hammond, G. E.; Versteeg, R. J.; Zachara, J. M.

2013-12-01

The Hanford 300 Area, located adjacent to the Columbia River in south-central Washington, USA, is the site of former research and uranium fuel rod fabrication facilities. Waste disposal practices at site included discharging between 33 and 59 metric tons of uranium over a 40 year period into shallow infiltration galleries, resulting in persistent uranium contamination within the vadose and saturated zones. Uranium transport from the vadose zone to the saturated zone is intimately linked with water table fluctuations and river water intrusion driven by upstream dam operations. As river stage increases, the water table rises into the vadose zone and mobilizes contaminated pore water. At the same time, river water moves inland into the aquifer, and river water chemistry facilitates further mobilization by enabling uranium desorption from contaminated sediments. As river stage decreases, flow moves toward the river, ultimately discharging contaminated water at the river bed. River water specific conductance at the 300 Area varies around 0.018 S/m whereas groundwater specific conductance varies around 0.043 S/m. This contrast provides the opportunity to monitor groundwater/river water interaction by imaging changes in bulk conductivity within the saturated zone using time-lapse electrical resistivity tomography. Previous efforts have demonstrated this capability, but have also shown that disconnecting regularization constraints at the water table is critical for obtaining meaningful time-lapse images. Because the water table moves with time, the regularization constraints must also be transient to accommodate the water table boundary. This was previously accomplished with 2D time-lapse ERT imaging by using a finely discretized computational mesh within the water table interval, enabling a relatively smooth water table to be defined without modifying the mesh. However, in 3D this approach requires a computational mesh with an untenable number of elements. In order to accommodate the water table boundary in 3D, we propose a time-lapse warping mesh inversion, whereby mesh elements that traverse the water table are modified to generate a smooth boundary at the known water table position, enabling regularization constraints to be accurately disconnected across the water table boundary at a given time. We demonstrate the approach using a surface ERT array installed adjacent to the Columbia River at the 300 Area, consisting of 352 electrodes and covering an area of approximately 350 m x 350 m. Using autonomous data collection, transmission, and filtering tools coupled with high performance computing resources, the 4D imaging process is automated and executed in real time. Each time lapse survey consists of approximately 40,000 measurements and 4 surveys are collected and processed per day from April 1st , 2013 to September 30th, 2013. The data are inverted on an unstructured tetrahedral mesh that honors LiDAR-based surface topography and is comprised of approximately 905,000 elements. Imaging results show the dynamic 4D extent of river water intrusion, and are validated with well-based fluid conductivity measurements at each monitoring well within the imaging domain.

A new approach to comprehensive quantification of linear landscape elements using biotope types on a regional scale

NASA Astrophysics Data System (ADS)

Hirt, Ulrike; Mewes, Melanie; Meyer, Burghard C.

The structure of a landscape is highly relevant for research and planning (such as fulfilling the requirements of the Water Framework Directive - WFD - and for implementation of comprehensive catchment planning). There is a high potential for restoration of linear landscape elements in most European landscapes. By implementing the WFD in Germany, the restoration of linear landscape elements could be a valuable measure, for example to reduce nutrient input into rivers. Despite this importance of landscape structures for water and nutrients fluxes, biodiversity and the appearance of a landscape, specific studies of the linear elements are rare for larger catchment areas. Existing studies are limited because they either use remote sensing data, which does not adequately differentiate all types of linear landscape elements, or they focus only on a specific type of linear element. To address these limitations, we developed a framework allowing comprehensive quantification of linear landscape elements for catchment areas, using publicly available biotope type data. We analysed the dependence of landscape structures on natural regions and regional soil characteristics. Three data sets (differing in biotopes, soil parameters and natural regions) were generated for the catchment area of the middle Mulde River (2700 km 2) in Germany, using overlay processes in geographic information systems (GIS), followed by statistical evaluation. The linear landscape components of the total catchment area are divided into roads (55%), flowing water (21%), tree rows (14%), avenues (5%), and hedges (2%). The occurrence of these landscape components varies regionally among natural units and different soil regions. For example, the mixed deciduous stands (3.5 m/ha) are far more frequent in foothills (6 m/ha) than in hill country (0.9 m/ha). In contrast, fruit trees are more frequent in hill country (5.2 m/ha) than in the cooler foothills (0.5 m/ha). Some 70% of avenues, and 40% of tree rows, are discontinuous; in contrast, only 20% of hedges are discontinuous. Using our innovative framework, comprehensive information about landscape elements can now be obtained for regional applications. This approach can be applied to other regions and is highly relevant for landscape planning, erosion control, protection of waters and preservation of biotopes and species.

Is trace element concentration correlated to parasite abundance? A case study in a population of the green frog Pelophylax synkl. hispanicus from the Neto River (Calabria, southern Italy).

PubMed

De Donato, Carlo; Barca, Donatella; Milazzo, Concetta; Santoro, Raffaella; Giglio, Gianni; Tripepi, Sandro; Sperone, Emilio

2017-06-01

Bioaccumulation of 13 trace elements in the livers of 38 Pelophylax sinkl. hispanicus (Ranidae) and its helminth communities were studied and compared among three sites, each with a different degree of pollution along River Neto (south Italy) during September, 2014. Trace element concentrations in water and liver were measured using inductively coupled plasma mass spectrometry. For most elements, the highest concentration was recorded in the frogs inhabiting the third site, the one with the highest degree of pollution. The trend of trace element concentration in the liver can be represented as follows: Cu > Zn > Mn > Se > Cr. Concentrations of some elements in water and liver samples were significantly different among the three sites and this is evidenced by the bioaccumulation in the frogs. Four species of helminths, all belonging to Nematoda, were found: Rhabdias sp., Oswaldocruzia filiformis (Goeze, 1782), Cosmocerca ornata (Dujarden, 1845), Seuratascaris numidica (Seurat, 1917). The parasite survey presents an important difference of prevalence and average number of helminths in frogs between the three sites. Correlating parasitological and ecotoxicological data showed a strong positive correlation between prevalence and number of parasites with some trace elements such as Mn, Co, Ni, As, Se, and Cd.

Water and Sediment Quality in the Yukon River Basin, Alaska, During Water Year 2001

USGS Publications Warehouse

Schuster, Paul F.

2003-01-01

Overview -- This report contains water-quality and sediment-quality data from samples collected in the Yukon River Basin during water year 2001 (October 2000 through September 2001). A broad range of chemical and biological analyses from three sets of samples are presented. First, samples were collected throughout the year at five stations in the basin (three on the mainstem Yukon River, one each on the Tanana and Porcupine Rivers). Second, fecal indicators were measured on samples from drinking-water supplies collected near four villages. Third, sediment cores from five lakes throughout the Yukon Basin were sampled to reconstruct historic trends in the atmospheric deposition of trace elements and hydrophobic organic compounds.

a Baseline Study of Physico-Chemical Parameters and Trace Metals in Waters of Manakudy, South-West Coast of India

NASA Astrophysics Data System (ADS)

Subramanian, M.; Muthumanikkam, J.

2013-05-01

The transport of trace metals from the land to ocean has a number of different routes and efficiencies. The sources of toxic elements into the rivers to be debouched into the sea through estuaries are either weathered naturally from the soils and rocks or introduced anthropogenically from point or non-point sources, in labile form or in particulate form. However, recent studies indicate that the transport of trace elements to the aquatic environment is much more complex than what has been thought. The chemistry and ecology of an estuarine system are entirely different from the fluvial as well as the marine system. Estuarine environment is characterized by a constantly changing mixture of salt and freshwater. In the present study area Manakudy estuary is situated about 8 kilometres north west of Kanyakumari (Latitude N 08 05 21.8 and Longitude E 077 29 03.7). To gain a better understanding of the geochemical behavior of physico-chemical parameters and trace elements in the estuary and to examine variations in associated chemical changes, 20 water samples were collected throughout the Manakudy estuary, a minor river in south-western India. These samples, collected in typical dry season during 2012, were analyzed for physico-chemical parameters, dissolved major and trace elements. Our results show that dissolved Na, Mg, Ca and Cl behave conservatively along the salinity gradient. The concentration of nutrients is normal and they are due to the higher organic activity in soils as well as faster rates of chemical weathering reaction in the source region. The concentration of major ions is due to tidal influence and it increases with salinity and the nutrients do behave non-conservatively due to biogenic removal. The conservative behaviour of the trace metals with salinity has been strongly affected by the introduction of these metals by external sources. Even though the trace metals in the contaminated water have been removed and incorporated in sediments due to flocculation, the concentration of these metals did not decrease. S.MUTHUSAMY M.sc.,M.phil., RESEARCH SCHOLAR UNIVERSITY OF MADRAS CHENNAI,TAMILNADU INDIA

Improved methods for distribution loss evaluation. Volume 1: analytic and evaluative techniques. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flinn, D.G.; Hall, S.; Morris, J.

This volume describes the background research, the application of the proposed loss evaluation techniques, and the results. The research identified present loss calculation methods as appropriate, provided care was taken to represent the various system elements in sufficient detail. The literature search of past methods and typical data revealed that extreme caution in using typical values (load factor, etc.) should be taken to ensure that all factors were referred to the same time base (daily, weekly, etc.). The performance of the method (and computer program) proposed in this project was determined by comparison of results with a rigorous evaluation ofmore » losses on the Salt River Project system. This rigorous evaluation used statistical modeling of the entire system as well as explicit enumeration of all substation and distribution transformers. Further tests were conducted at Public Service Electric and Gas of New Jersey to check the appropriateness of the methods in a northern environment. Finally sensitivity tests indicated data elements inaccuracy of which would most affect the determination of losses using the method developed in this project.« less

Abundance, size distributions and trace-element binding of organic and iron-rich nanocolloids in Alaskan rivers, as revealed by field-flow fractionation and ICP-MS

NASA Astrophysics Data System (ADS)

Stolpe, Björn; Guo, Laodong; Shiller, Alan M.; Aiken, George R.

2013-03-01

Water samples were collected from six small rivers in the Yukon River basin in central Alaska to examine the role of colloids and organic matter in the transport of trace elements in Northern high latitude watersheds influenced by permafrost. Concentrations of dissolved organic carbon (DOC), selected elements (Al, Si, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Ba, Pb, U), and UV-absorbance spectra were measured in 0.45 μm filtered samples. 'Nanocolloidal size distributions' (0.5-40 nm, hydrodynamic diameter) of humic-type and chromophoric dissolved organic matter (CDOM), Cr, Mn, Fe, Co, Ni, Cu, Zn, and Pb were determined by on-line coupling of flow field-flow fractionation (FFF) to detectors including UV-absorbance, fluorescence, and ICP-MS. Total dissolved and nanocolloidal concentrations of the elements varied considerably between the rivers and between spring flood and late summer base flow. Data on specific UV-absorbance (SUVA), spectral slopes, and the nanocolloidal fraction of the UV-absorbance indicated a decrease in aromaticity and size of CDOM from spring flood to late summer. The nanocolloidal size distributions indicated the presence of different 'components' of nanocolloids. 'Fulvic-rich nanocolloids' had a hydrodynamic diameter of 0.5-3 nm throughout the sampling season; 'organic/iron-rich nanocolloids' occurred in the <8 nm size range during the spring flood; whereas 'iron-rich nanocolloids' formed a discrete 4-40 nm components during summer base flow. Mn, Co, Ni, Cu and Zn were distributed between the nanocolloid components depending on the stability constant of the metal (+II)-organic complexes, while stronger association of Cr to the iron-rich nanocolloids was attributed to the higher oxidation states of Cr (+III or +IV). Changes in total dissolved element concentrations, size and composition of CDOM, and occurrence and size of organic/iron and iron-rich nanocolloids were related to variations in their sources from either the upper organic-rich soil or the deeper mineral layer, depending on seasonal variations in hydrological flow patterns and permafrost dynamics.

Annual suspended sediment and trace element fluxes in the Mississippi, Columbia, Colorado, and Rio Grande drainage basins

USGS Publications Warehouse

Horowitz, A.J.; Elrick, K.A.; Smith, J.J.

2001-01-01

Suspended sediment, sediment-associated, total trace element, phosphorus (P), and total organic carbon (TOC) fluxes were determined for the Mississippi, Columbia, Rio Grande, and Colorado Basins for the study period (the 1996, 1997, and 1998 water years) as part of the US Geological Survey's redesigned National Stream Quality Accounting Network (NASQAN) programme. The majority (??? 70%) of Cu, Zn, Cr, Ni, Ba, P, As, Fe, Mn, and Al are transported in association with suspended sediment; Sr transport seems dominated by the dissolved phase, whereas the transport of Li and TOC seems to be divided equally between both phases. Average dissolved trace element levels are markedly lower than reported during the original NASQAN programme; this seems due to the use of 'clean' sampling, processing, and analytical techniques rather than to improvements in water quality. Partitioning between sediment and water for Ag, Pb, Cd, Cr, Co, V, Be, As, Sb, Hg, and Ti could not be estimated due to a lack of detectable dissolved concentrations in most samples. Elevated suspended sediment-associated Zn levels were detected in the Ohio River Basin and elevated Hg levels were detected in the Tennessee River, the former may affect the mainstem Mississippi River, whereas the latter probably do not. Sediment-associated concentrations of Ag, Cu, Pb, Zn, Cd, Cr, Co, Ba, Mo, Sb, Hg, and Fe are markedly elevated in the upper Columbia Basin, and appear to be detectable (Zn, Cd) as far downstream as the middle of the basin. These elevated concentrations seem to result from mining and/or mining-related activities. Consistently detectable concentrations of dissolved Se were found only in the Colorado River Basin. Calculated average annual suspended sediment fluxes at the mouths of the Mississippi and Rio Grande Basins were below, whereas those for the Columbia and Colorado Basins were above previously published annual values. Downstream suspended sediment-associated and total trace element fluxes increase in the Mississippi and Columbia Basins, whereas fluxes markedly decrease in the Colorado Basin. No consistent pattern in trace element fluxes was detected in the Rio Grande Basin.

A finite-element model study of the impact of the proposed I-326 crossing on flood stages of the Congaree River near Columbia, South Carolina

USGS Publications Warehouse

Lee, J.K.; Bennett, C. S.

1981-01-01

A two-dimensional finite element surface water model was used to study the hydraulic impact of the proposed Interstate Route 326 crossing of the Congaree River near Columbia, SC. The finite element model was assessed as a potential operational tool for analyzing complex highway crossings and other modifications of river flood plains. Infrared aerial photography was used to define regions of homogeneous roughness in the flood plain. Finite element networks approximating flood plain topography were designed using elements of three roughness types. High water marks established during an 8-yr flood that occurred in October 1976 were used to calibrate the model. The maximum flood of record, an approximately 100-yr flood that occurred in August 1908, was modeled in three cases: dikes on the right bank, dikes on the left bank, and dikes on both banks. In each of the three cases, simulations were performed both without and with the proposed highway embankments in place. Detailed information was obtained about backwater effects upstream from the proposed highway embankments, changes in flow distribution resulting from the embankments, and local velocities in the bridge openings. On the basis of results from the model study, the South Carolina Department of Highways and Public Transportation changed the design of several bridge openings. A simulation incorporating the new design for the case with dikes on the left bank indicated that both velocities in the bridge openings and backwater were reduced. A major problem in applying the model was the difficulty in predicting the network detail necessary to avoid local errors caused by roughness discontinuities and large depth gradients. (Lantz-PTT)

Analytical Results for 42 Fluvial Tailings Cores and 7 Stream Sediment Samples from High Ore Creek, Northern Jefferson County, Montana

USGS Publications Warehouse

Fey, David L.; Church, Stan E.

1998-01-01

Metal-mining related wastes in the Boulder River basin study area in northern Jefferson County, Montana have been implicated in their detrimental effects on water quality with regard to acid-generation and toxic-metal solubility. Sediments, fluvial tailings and water from High Ore Creek have been identified as significant contributors to water quality degradation of the Boulder River below Basin, Montana. A study of 42 fluvial tailings cores and 7 stream sediments from High Ore Creek was undertaken to determine the concentrations of environmentally sensitive elements (i.e. Ag, As, Cd, Cu, Pb, Zn) present in these materials, and the mineral phases containing those elements. Two sites of fluvial deposition of mine-waste contaminated sediment on upper High Ore Creek were sampled using a one-inch soil probe. Forty-two core samples were taken producing 247 subsamples. The samples were analyzed by ICP-AES (inductively coupled-plasma atomic emission spectroscopy) using a total mixed-acid digestion. Results of the core analyses show that the elements described above are present at very high concentrations (to 22,000 ppm As, to 460 ppm Ag, to 900 ppm Cd, 4,300 ppm Cu, 46,000ppm Pb, and 50,000 ppm Zn). Seven stream-sediment samples were also analyzed by ICP-AES for total element content and for leachable element content. Results show that the sediment of High Ore Creek has elevated levels of ore-related metals throughout its length, down to the confluence with the Boulder River, and that the metals are, to a significant degree, contained in the leachable phase, namely the hydrous amorphous iron- and manganese-hydroxide coatings on detrital sediment particles.

Deconvolution of trace element (As, Cr, Mo, Th, U) sources and pathways to surface waters of a gold mining-influenced watershed.

PubMed

Grosbois, C; Schäfer, J; Bril, H; Blanc, G; Bossy, A

2009-03-01

The Upper Isle River (SW France) drains the second most productive gold-mining district of France. A high resolution survey during one hydrological year of As, Cl(-), Cr, Fe, Mn, Mo, SO(4)(2-), Th and U dissolved concentrations in surface water aimed to better understand pathways of trace element export to the river system downstream from the mining district. Dissolved concentrations of As (up to 35000 ng/L) and Mo (up to 292 ng/L) were about 3-fold higher than the regional dissolved background and showed a negative logarithmic relation with discharge. Dissolved concentrations of Cr (up to 483 ng/L), Th (up to 48 ng/L) and U (up to 184 ng/L) increased with discharge. Geochemical relationships between molar ratios in surface water, geochemical background as well as rain- and groundwater data were combined. The contrasting behavior of distinct element groups was explained by a scenario involving three seasonal components: (i) The high flow component is poorly concentrated in As and Mo but highly concentrated in Cr, Th, U. This has been attributed to diffuse sources such as water-soil interactions, atmospheric inputs, bedrock and bed sediment weathering. Although this component probably also includes a contribution by weathering of sulfide veins, this signal is masked by dilution. (ii) One low flow component presents high SO(4)(2-), Fe, As and Mo and moderate Cr, Th and U concentrations. This component has been attributed to point sources such as mine gallery effluents, mining waste weathering and groundwater inputs from natural and/or mining-induced sulfide oxidation in the ore deposit. (iii) A second low flow component showing high As plus Mo concentrations associated with very low SO(4)(2-), Fe, Cr, Th and U concentrations, probably reflects trace element scavenging by ferric oxyhydroxide formation in the adjacent aquifer. This is supported by the decrease of Fe, Cr, Th and U in surface waters. Flux estimates suggest contrasting element-specific impacts on annual dissolved fluxes. Runoff may account for the major part of annual dissolved As, Mo, Th and U fluxes in the Upper Isle River. Inputs related to sulfide oxidation respectively contributed approximately 30% and approximately 24% to annual As and Mo fluxes. The formation of ferric oxyhydroxides strongly retained Cr, Th and U during the low flow, limiting their dissolved concentrations in surface waters. If this process may eventually decrease As mobility, its impact on dissolved As concentrations in surface water may be limited or/and counterbalanced by As release during sulfide oxidation.

Studies on the content of heavy metals in Aries River using ICP-MS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Voica, Cezara, E-mail: Cezara.Voica@itim-cj.ro; Kovacs, Melinda, E-mail: Cezara.Voica@itim-cj.ro; Feher, Ioana, E-mail: Cezara.Voica@itim-cj.ro

2013-11-13

Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-miningmore » area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)« less

Spatio-temporal distribution and environmental risk of sedimentary heavy metals in the Yangtze River Estuary and its adjacent areas.

PubMed

Chen, Bin; Liu, Jian; Qiu, Jiandong; Zhang, Xilin; Wang, Shuang; Liu, Jinqing

2017-03-15

Twenty-five surface sediments and one sediment core sample were collected from the study area. Grain size, major elements, and heavy metals were determined. The content of fine-grained sediments (silt and clay), as well as the concentrations of major elements and heavy metals, showed seaward decreasing trends, with high content in the coastal areas of the East China Sea (ECS) and south west of Jeju Island. Low enrichment factor (EF) and geoaccumulation index (Igeo) values were found, indicating that the ecological risk of heavy metals was low. The EF values obtained from the high-resolution sedimentary records of heavy metals in the Yangtze River Estuary could be divided into Stage 1 (1950s to the late 1970s) and Stage 2 (late 1970s to the current sampling day), which coincided with economic development of the Yangtze River Basin, implementation of environmental protection, and impoundment of the Three Gorges Dam. Copyright © 2016. Published by Elsevier Ltd.

Distribution, sources, and fluxes of heavy metals in the Pearl River Delta, South China.

PubMed

Geng, Junjie; Wang, Yiping; Luo, Hanjin

2015-12-30

Riverine samples were collected at various locations in the Pearl River Delta (PRD) to determine the concentrations of heavy metals (Cr, Ni, Cu, Mn, Zn, Cd, and Pb) in time and space and to estimate the fluxes of heavy metals to the coastal waters off South China. Most of the elements exhibit clear temporal and spatial trends. Principal component analysis shows that surface erosion is the major factor affecting metal concentrations in particulates in the PRD. Natural geology is an important source of these heavy metals. The annual fluxes of Cr, Ni, Cu, Mn, Zn, Cd, and Pb in upstream and downstream were 445, 256, 241, 3293, 1279, 12, and 317 t/year and 1823, 1144, 1786, 15,634, 6183, 74, and 2017 t/year, respectively. A comparison indicated that the annual fluxes of Mn accounted for 1.3% of the global river fluxes, whereas other elements contribute <1%. Copyright © 2015 Elsevier Ltd. All rights reserved.

Accumulation of heavy metals and trace elements in fluvial sediments received effluents from traditional and semiconductor industries

PubMed Central

Hsu, Liang-Ching; Huang, Ching-Yi; Chuang, Yen-Hsun; Chen, Ho-Wen; Chan, Ya-Ting; Teah, Heng Yi; Chen, Tsan-Yao; Chang, Chiung-Fen; Liu, Yu-Ting; Tzou, Yu-Min

2016-01-01

Metal accumulation in sediments threatens adjacent ecosystems due to the potential of metal mobilization and the subsequent uptake into food webs. Here, contents of heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn) and trace elements (Ga, In, Mo, and Se) were determined for river waters and bed sediments that received sewage discharged from traditional and semiconductor industries. We used principal component analysis (PCA) to determine the metal distribution in relation to environmental factors such as pH, EC, and organic matter (OM) contents in the river basin. While water PCA categorized discharged metals into three groups that implied potential origins of contamination, sediment PCA only indicated a correlation between metal accumulation and OM contents. Such discrepancy in metal distribution between river water and bed sediment highlighted the significance of physical-chemical properties of sediment, especially OM, in metal retention. Moreover, we used Se XANES as an example to test the species transformation during metal transportation from effluent outlets to bed sediments and found a portion of Se inventory shifted from less soluble elemental Se to the high soluble and toxic selenite and selenate. The consideration of environmental factors is required to develop pollution managements and assess environmental risks for bed sediments. PMID:27681994

Accumulation of heavy metals and trace elements in fluvial sediments received effluents from traditional and semiconductor industries.

PubMed

Hsu, Liang-Ching; Huang, Ching-Yi; Chuang, Yen-Hsun; Chen, Ho-Wen; Chan, Ya-Ting; Teah, Heng Yi; Chen, Tsan-Yao; Chang, Chiung-Fen; Liu, Yu-Ting; Tzou, Yu-Min

2016-09-29

Metal accumulation in sediments threatens adjacent ecosystems due to the potential of metal mobilization and the subsequent uptake into food webs. Here, contents of heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn) and trace elements (Ga, In, Mo, and Se) were determined for river waters and bed sediments that received sewage discharged from traditional and semiconductor industries. We used principal component analysis (PCA) to determine the metal distribution in relation to environmental factors such as pH, EC, and organic matter (OM) contents in the river basin. While water PCA categorized discharged metals into three groups that implied potential origins of contamination, sediment PCA only indicated a correlation between metal accumulation and OM contents. Such discrepancy in metal distribution between river water and bed sediment highlighted the significance of physical-chemical properties of sediment, especially OM, in metal retention. Moreover, we used Se XANES as an example to test the species transformation during metal transportation from effluent outlets to bed sediments and found a portion of Se inventory shifted from less soluble elemental Se to the high soluble and toxic selenite and selenate. The consideration of environmental factors is required to develop pollution managements and assess environmental risks for bed sediments.

Accumulation of heavy metals and trace elements in fluvial sediments received effluents from traditional and semiconductor industries

NASA Astrophysics Data System (ADS)

Hsu, Liang-Ching; Huang, Ching-Yi; Chuang, Yen-Hsun; Chen, Ho-Wen; Chan, Ya-Ting; Teah, Heng Yi; Chen, Tsan-Yao; Chang, Chiung-Fen; Liu, Yu-Ting; Tzou, Yu-Min

2016-09-01

Metal accumulation in sediments threatens adjacent ecosystems due to the potential of metal mobilization and the subsequent uptake into food webs. Here, contents of heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn) and trace elements (Ga, In, Mo, and Se) were determined for river waters and bed sediments that received sewage discharged from traditional and semiconductor industries. We used principal component analysis (PCA) to determine the metal distribution in relation to environmental factors such as pH, EC, and organic matter (OM) contents in the river basin. While water PCA categorized discharged metals into three groups that implied potential origins of contamination, sediment PCA only indicated a correlation between metal accumulation and OM contents. Such discrepancy in metal distribution between river water and bed sediment highlighted the significance of physical-chemical properties of sediment, especially OM, in metal retention. Moreover, we used Se XANES as an example to test the species transformation during metal transportation from effluent outlets to bed sediments and found a portion of Se inventory shifted from less soluble elemental Se to the high soluble and toxic selenite and selenate. The consideration of environmental factors is required to develop pollution managements and assess environmental risks for bed sediments.

Physical, chemical, and biological data for detailed study of the Sun River Irrigation Project, Freezout Lake Wildlife Management Area, and Benton Lake National Wildlife Refuge, west-central Montana, 1990-92, with selected data for 1987-89

USGS Publications Warehouse

Lambing, J.H.; Nimick, D.A.; Knapton, J.R.; Palawski, D.U.

1994-01-01

Physical chemical, and biological data were collected in the lower Sun River area of west-central Montana during 1990-92 as part of a U.S. Department of the Interior detailed study of the extent, magnitude, sources, and potential biological impacts of contaminants associated with irrigation drainage. Physical and chemical data were collected from areas within and near the Sun River Irrigation Project and from wetland areas receiving irrigation drainage. Biological data were collected from areas in and near Freezout Lake Wildlife Management Area and Benton Lake National Wildlife Refuge. Additional biological data were collected previously during 1987-89 as part of a U.S. Fish and Wildlife Service program. This report presents data for selenium and other potentially toxic constituents in solid-phase, water, and biological media. Data consist of concentrations of major and trace elements in soil and drill cores; concen- trations of major ions, nutrients, and trace elements in ground water and surface water; and trace-element concentrations in bottom sediment and biological tissue. Hydrogeologic data for domestic and test wells and daily streamflow data for selected sites also are included.

Physical, chemical, and biological characteristics of the Boise River from Veterans Memorial Parkway, Boise to Star, Idaho, October 1987 to March 1988

USGS Publications Warehouse

Frenzel, S.A.

1988-01-01

Physical, chemical, and biological characteristics of the Boise River were examined from October 1987 to March 1988 to determine whether trace elements in effluents from two Boise wastewater treatment facilities were detrimental to aquatic communities. Cadmium, chromium, hexavalent chromium, cyanide, lead, nickel, and silver concentrations in the Boise River were less than or near analytical detection levels and were less than chronic toxicity criteria when detectable. Arsenic, copper, and zinc were detected in concentrations less than chronic toxicity criteria. Concentrations of trace elements in bottom material generally were small and could not be attributed to effluents from wastewater treatment facilities. From October to December 1987, mean density of benthic invertebrates colonizing artificial substrates was from 6,100 individuals/substrate downstream from the West Boise wastewater treatment facility to 14,000 individuals per substrate downstream from the Lander Street wastewater treatment facility. From January to March 1988 , mean density of benthic invertebrates colonizing artificial substrates was from 7,100 individuals per substrate downstream from the West Boise facility to 10,000 individuals per substrate near Star. Insect communities upstream and downstream from the wastewater treatment facilities were strongly associated, and coeffients of community loss indicated that effluents had benign enriching effects. Distribution of mayflies indicates that trace-element concentrations in effluents did not adversely affect intolerant organisms in the Boise River. Condition factor of whitefish was significantly increased downstream from the Lander Street wastewater treatment facility and was significantly decreased downstream from the West Boise wastewater treatment facility.

Environmental change in Yatsushiro tidal flat and the Kuma River (SW Kyushu, Japan) between 2002 and the present

NASA Astrophysics Data System (ADS)

Young, S. M.; Ishiga, H.

2012-12-01

The chemical compositions of sediments from Yatsushiro tidal flat, Kuma River, and Arase dam (south west Kyushu, Japan) have been determined to examine changes between 2002 and 2012. In 2002 sediment supply to the bay from the Kuma River was restricted by the Arase dam; however in 2010 the dam was opened, allowing resumption of natural sediment transport. Abundances of 24 elements in Yatsushiro tidal flat sediments (n=22), suspended solids in the bay (n=6), Kuma River stream sediments (n=5) and suspended solids (n=2) were determined by XRF. Ripple marks in the Yatsushiro tidal flat indicate inflow of coarser material from the reinvigorated river. Bulk chemical composition of the tidal flat sediments has changed since 2002, with marked decreases in As, Zn and total sulfur, and lesser and more variable decrease in Pb. Mn values are higher in the northern tidal flats, suggesting anoxic conditions in the sediments at those sites. Suspended solids in both the Kuma River and Yatsushiro Bay have very low values of heavy metals, indicating low absorption and dilution by high organic matter contents. Sediments behind the Arase dam in 2002 had high abundances of most of the elements analyzed. However, abundances in Kuma River stream sediments at similar locations have fallen since the dam was opened in 2010. Kuma River sediments are characteristically coarser than those in Yatsushiro Bay, except at three locations. The river sediments are relatively uniform in composition, with ranges of 72.27-75.35 wt% SiO2 and 12.09-14.01 wt% Al2O3, compared to 55.40-77.89 and 11.61-21.44 respectively for Yatsushiro Bay tidal flat sediments. Average values in both suites are similar to UCC. Decreased heavy metal contents in the bay sediments after opening of the dam is attributed to dilution by previously impounded quartz and feldspar. Restoration of natural sediment transport has thus bought about a favorable environmental change. Key words: Yatsushiro bay, Kuma River, Geochemistry, Tidal flat, Environmental change.

Regional baseline geochemistry and environmental effects of gold placer mining operations on the Fortymile River, eastern Alaska: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1998

USGS Publications Warehouse

Wanty, Richard B.; Wang, Bronwen; Vohden, Jim; Briggs, Paul H.; Meier, Allen L.

2000-01-01

A systematic water-quality study of the Fortymile River and many of its major tributaries in eastern Alaska was conducted in June of 1997 and 1998. Surface-water samples were collected for chemical analyses to establish regional baseline geochemistry values and to evaluate the possible environmental effects of suction-dredge placer gold mining and bulldozer-operated placer gold mining (commonly referred to as “cat mining”). In general, the water quality of the Fortymile River is very good, with low total dissolved solids and only two cases in which the concentration of any element exceeded primary or secondary drinking-water quality standards. In both cases, iron exceeded secondary drinking-water limits. At the time this work was conducted, only a handful of suction dredges were operating on the lower Fortymile River, and cat mining was being conducted along Uhler Creek and Canyon Creek, two major tributaries to the river. Based on the water-quality and turbidity data, the suction dredges have no apparent impact on the Fortymile River system, although possible effects on biota have not been evaluated in this study. In contrast, the cat-mining operations in Canyon Creek appear to have a dramatic impact on water quality and stream-bed morphology, based on the field water-quality and turbidity measurements, on comparisons to adjacent unmined drainages, and on field observations of stream-bed morphology. The cat mining in Uhler Creek appears to have had less impact, perhaps because the main stream channel was not as heavily disrupted by the bulldozers, and the stability of the channel was mostly preserved.

Chemical composition of modern and fossil Hippopotamid teeth and implications for paleoenvironmental reconstructions and enamel formation: 1. major and minor element variation

NASA Astrophysics Data System (ADS)

Brügmann, G.; Krause, J.; Brachert, T. C.; Kullmer, O.; Schrenk, F.; Ssemmanda, I.; Mertz, D. F.

2011-05-01

Bioapatite in mammalian teeth is readily preserved in continental sediments and represents a very important archive for reconstructions of environment and climate evolution. This project intends to provide a detailed data base of major, minor and trace element and isotope tracers for tooth apatite using a variety of microanalytical techniques. The aim is to identify specific sedimentary environments and to improve our understanding on the interaction between internal metabolic processes during tooth formation and external nutritional control and secondary alteration effects. Here, we use the electron microprobe, to determine the major and minor element contents of fossil and modern molar enamel, cement and dentin from hippopotamids. Most of the studied specimens are from different ecosystems in Eastern Africa, representing modern and fossil lakustrine (Lake Kikorongo, Lake Albert, and Lake Malawi) and modern fluvial environments of the Nile River system. Secondary alteration effects in particular FeO, MnO, SO3 and F concentrations, which are 2 to 10 times higher in fossil than in modern enamel; secondary enrichments in fossil dentin and cement are even higher. In modern and fossil enamel, along sections perpendicular to the enamel-dentin junction (EDJ) or along cervix-apex profiles, P2O5 and CaO contents and the CaO/P2O5 ratios are very constant (StdDev ~1 %). Linear regression analysis reveals very tight control of the MgO (R2∼0.6), Na2O and Cl variation (for both R2>0.84) along EDJ-outer enamel rim profiles, despite large concentration variations (40 % to 300 %) across the enamel. These minor elements show well defined distribution patterns in enamel, similar in all specimens regardless of their age and origin, as the concentration of MgO and Na2O decrease from the enamel-dentin junction (EDJ) towards the outer rim, whereas Cl displays the opposite variation. Fossil enamel from hippopotamids which lived in the saline Lake Kikorongo have a much higher MgO/Na2O ratio (∼1.11) than those from the Neogene fossils of Lake Albert (MgO/Na2O∼0.4), which was a large fresh water lake like those in the western Branch of the East African Rift System today. Similarly, the MgO/Na2O ratio in modern enamel from the White Nile River (∼0.36), which has a Precambrian catchment of dominantly granite and gneisses and passes through several saline zones, is higher than that from the Blue Nile River, whose catchment is the Neogene volcanic Ethiopian Highland (MgO/Na2O∼0.22). Thus, particularly MgO/Na2O might be a sensitive fingerprint for environments where river and lake water have suffered strong evaporation. Enamel formation in mammals takes place at successive mineralization fronts within a confined chamber where ion and molecule transport is controlled by the surrounding enamel organ. During the secretion and maturation phases the epithelium generates different fluid composition, which in principle, should determine the final composition of enamel apatite. This is supported by co-linear relationships between MgO, Cl and Na2O which can be interpreted as binary mixing lines. However, if maturation starts after secretion is completed the observed element distribution can only be explained by recrystallization of existing and addition of new apatite during maturation. Perhaps the initial enamel crystallites precipitating during secretion and the newly formed bioapatite crystals during maturation equilibrate with a continuously evolving fluid. During crystallization of bioapatite the enamel fluid becomes continuously depleted in MgO and Na2O, but enriched in Cl which results in the formation of MgO, and Na2O-rich, but Cl-poor bioapatite near the EDJ and MgO- and Na2O-poor, but Cl-rich bioapatite at the outer enamel rim. The linkage between lake and river water composition, bioavailability of elements for plants, animal nutrition and tooth formation is complex and multifaceted. The quality and limits of the MgO/Na2O and other proxies have to be established with systematic investigations relating chemical distribution patterns to sedimentary environment and to growth structures developing as secretion and maturation proceed during tooth formation.

Chemical composition of modern and fossil Hippopotamid teeth and implications for paleoenvironmental reconstructions and enamel formation - Part 1: Major and minor element variation

NASA Astrophysics Data System (ADS)

Brügmann, G.; Krause, J.; Brachert, T. C.; Kullmer, O.; Schrenk, F.; Ssemmanda, I.; Mertz, D. F.

2012-01-01

Bioapatite in mammalian teeth is readily preserved in continental sediments and represents a very important archive for reconstructions of environment and climate evolution. This project provides a comprehensive data base of major, minor and trace element and isotope tracers for tooth apatite using a variety of microanalytical techniques. The aim is to identify specific sedimentary environments and to improve our understanding on the interaction between internal metabolic processes during tooth formation and external nutritional control and secondary alteration effects. Here, we use the electron microprobe to determine the major and minor element contents of fossil and modern molar enamel, cement and dentin from Hippopotamids. Most of the studied specimens are from different ecosystems in Eastern Africa, representing modern and fossil lacustrine (Lake Kikorongo, Lake Albert, and Lake Malawi) and modern fluvial environments of the Nile River system. Secondary alteration effects - in particular FeO, MnO, SO3 and F concentrations - are 2 to 10 times higher in fossil than in modern enamel; the secondary enrichment of these components in fossil dentin and cement is even higher. In modern and fossil enamel, along sections perpendicular to the enamel-dentin junction (EDJ) or along cervix-apex profiles, P2O5 and CaO contents and the CaO/P2O5 ratios are very constant (StdDev ∼1%). Linear regression analysis reveals tight control of the MgO (R2∼0.6), Na2O and Cl variation (for both R2>0.84) along EDJ-outer enamel rim profiles, despite large concentration variations (40% to 300%) across the enamel. These minor elements show well defined distribution patterns in enamel, similar in all specimens regardless of their age and origin, as the concentration of MgO and Na2O decrease from the enamel-dentin junction (EDJ) towards the outer rim, whereas Cl displays the opposite trend. Fossil enamel from Hippopotamids which lived in the saline Lake Kikorongo have a much higher MgO/Na2O ratio (∼1.11) than those from the Neogene fossils of Lake Albert (MgO/Na2O∼0.4), which was a large fresh water lake like those in the western Branch of the East African Rift System today. Similarly, the MgO/Na2O ratio in modern enamel from the White Nile River (∼0.36), which has a Precambrian catchment of dominantly granites and gneisses and passes through several saline zones, is higher than that from the Blue Nile River, whose catchment is the Neogene volcanic Ethiopian Highland (MgO/Na2O∼0.22). Thus, particularly MgO/Na2O might be a sensitive fingerprint for environments where river and lake water have suffered strong evaporation. Enamel formation in mammals takes place at successive mineralization fronts within a confined chamber where ion and molecule transport is controlled by the surrounding enamel organ. During the secretion and maturation phases the epithelium generates different fluid composition, which in principle, should determine the final composition of enamel apatite. This is supported by co-linear relationships between MgO, Cl and Na2O which can be interpreted as binary mixing lines. However, if maturation starts after secretion is completed, the observed element distribution can only be explained by equilibration of existing and addition of new apatite during maturation. It appears the initial enamel crystallites precipitating during secretion and the newly formed bioapatite crystals during maturation equilibrate with a continuously evolving fluid. During crystallization of bioapatite the enamel fluid becomes continuously depleted in MgO and Na2O, but enriched in Cl which results in the formation of MgO, and Na2O-rich, but Cl-poor bioapatite near the EDJ and MgO- and Na2O-poor, but Cl-rich bioapatite at the outer enamel rim. The linkage between lake and river water compositions, bioavailability of elements for plants, animal nutrition and tooth formation is complex and multifaceted. The quality and limits of the MgO/Na2O and other proxies have to be established with systematic investigations relating chemical distribution patterns to sedimentary environment and to growth structures developing as secretion and maturation proceed during tooth formation.

The Asian clam Corbicula fluminea as a biomonitor of trace element contamination: Accounting for different sources of variation using an hierarchical linear model

USGS Publications Warehouse

Shoults-Wilson, W. A.; Peterson, J.T.; Unrine, J.M.; Rickard, J.; Black, M.C.

2009-01-01

In the present study, specimens of the invasive clam, Corbicula fluminea, were collected above and below possible sources of potentially toxic trace elements (As, Cd, Cr, Cu, Hg, Pb, and Zn) in the Altamaha River system (Georgia, USA). Bioaccumulation of these elements was quantified, along with environmental (water and sediment) concentrations. Hierarchical linear models were used to account for variability in tissue concentrations related to environmental (site water chemistry and sediment characteristics) and individual (growth metrics) variables while identifying the strongest relations between these variables and trace element accumulation. The present study found significantly elevated concentrations of Cd, Cu, and Hg downstream of the outfall of kaolin-processing facilities, Zn downstream of a tire cording facility, and Cr downstream of both a nuclear power plant and a paper pulp mill. Models of the present study indicated that variation in trace element accumulation was linked to distance upstream from the estuary, dissolved oxygen, percentage of silt and clay in the sediment, elemental concentrations in sediment, shell length, and bivalve condition index. By explicitly modeling environmental variability, the Hierarchical linear modeling procedure allowed the identification of sites showing increased accumulation of trace elements that may have been caused by human activity. Hierarchical linear modeling is a useful tool for accounting for environmental and individual sources of variation in bioaccumulation studies. ?? 2009 SETAC.

Fate and transport of trace metals and rare earth elements in the Snake River, an AMD/ARD-impacted watershed. Montezuma, Colorado USA.

NASA Astrophysics Data System (ADS)

McKnight, D. M.; Rue, G.

2017-12-01

Recent research in Snake River Watershed, located near the historic boomtown of Montezuma and adjacent the Continental Divide in the Colorado Rocky Mountains, has revealed the distinctive occurrence of rare earth elements (REE) at high concentrations. Here the weathering of the mineralized lithology naturally generates acid rock drainage (ARD) in addition to drainage recieved from abandoned mine adits throughout the area, results in aqueous REE concentrations three orders of magnitude higher than in most major rivers. The dominant mechanism responsible for this enrichment; their dissolution from secondary and accessory mineral stocks, abundant in REEs, promoted by the low pH waters generated from geochemical weathering of disseminated sulfide minerals. While REEs behave conservatively in acidic conditions, as well as in the presence of stabilizing ligands such as sulfate, downstream circumneutral inputs from pristine streams and a rising pH are resulting in observed fractional losses of heavy rare earth elements as well as partitioning towards colloidal and solid phases. These finding in combination with the established role of dissolved organic matter (DOM) in binding with both trace metals and REEs, suggest that competitive interactions, complexation, and scavenging are likely contributing to these proportional losses. However, outstanding questions yet remain regarding the effects of an increasing flux of trace metals as well as REEs from the Snake River Watershed into Dillon Reservoir, a major drinking water supply for the City of Denver, in part due to hydroclimatological drivers that are enhancing geochemical weathering and reducing groundwater recharge in alpine areas across the Colorado Rockies. Based on these findings also we seek to broaden this body of work to further investigate the behavior of rare earth elements (REE) in other aquatic environment as well the influence of trace metals, DOM, and pH in altering their reactivity and subsequent watershed transport.

Trace element and isotopic composition of apatite in carbonatites from the Blue River area (British Columbia, Canada) and mineralogy of associated silicate rocks

NASA Astrophysics Data System (ADS)

Mitchell, Roger; Chudy, Thomas; McFarlane, Christopher R. M.; Wu, Fu-Yuan

2017-08-01

Apatites from the Verity, Fir, Gum, Howard Creek and Felix carbonatites of the Blue River (British Columbia, Canada) area have been investigated with respect to their paragenesis, cathodoluminescence, trace element and Sr-Nd isotopic composition. Although all of the Blue River carbonatites were emplaced as sills prior to amphibolite grade metamorphism and have undergone deformation, in many instances magmatic textures and mineralogy are retained. Attempts to constrain the U-Pb age of the carbonatites by SIMS, TIMS and LA-ICP-MS studies of zircon and titanite were inconclusive as all samples investigated have experienced significant Pb loss during metamorphism. The carbonatites are associated with undersaturated calcite-titanite amphibole nepheline syenite only at Howard Creek although most contain clasts of disaggregated phoscorite-like rocks. Apatite from each intrusion is characterized by distinct, but wide ranges, in trace element composition. The Sr and Nd isotopic compositions define an array on a 87Sr/86Sr vs²Nd diagram at 350 Ma indicating derivation from depleted sub-lithospheric mantle. This array could reflect mixing of Sr and Nd derived from HIMU and EM1 mantle sources, and implies that depleted mantle underlies the Canadian Cordillera. Although individual occurrences of carbonatites in the Blue River region are mineralogically and geochemically similar they are not identical and thus cannot be considered as rocks formed from a single batch of parental magma at the same stage of magmatic evolution. However, a common origin is highly probable. The variations in the trace element content and isotopic composition of apatite from each occurrence suggest that each carbonatite represents a combination of derivation of the parental magma(s) from mineralogically and isotopically heterogeneous depleted mantle sources coupled with different stages of limited differentiation and mixing of these magmas. We do not consider these carbonatites as primary direct partial melts of the sub-lithospheric mantle which have ascended from the asthenosphere without modification of their composition.

The surface sediment types and their rare earth element characteristics from the continental shelf of the northern south China sea

NASA Astrophysics Data System (ADS)

Wang, Shuhong; Zhang, Nan; Chen, Han; Li, Liang; Yan, Wen

2014-10-01

The grain size as well as some major and trace elements, including rare earth element (REE), for 273 surface sediment samples collected from the continental shelf of the northern South China Sea were analyzed in this study. The sediment types are mainly sandy silt and silt, making up 60% of the whole samples, and secondly are mud, sandy mud, muddy sand and silty sand, making up 28% of the whole samples, based on grain-size in which the Folk's classification was used. The total REE content (ΣREE) show a wide variation from 21 ppm to 244 ppm with an average value of 155 ppm, which similar to the average ΣREE of the China loess, but much different from that in deep-sea clay, showing a significant terrigenous succession. The REE contents in different sediment types vary greatly, mainly enriching in silt, sandy silt, mud and sandy mud. The REE distribution contours parallel to the coastal, presenting like strips and their contents gradually reduce with increasing distance from the coast. The high content of the western Pearl River Mouth, Shang/Xiachuan Islands and Hailing Bay might be regarded to the coastal current developed from the east to the west along to the Pearl River Mouth in the northern South China Sea. But the chondrite-normalized REE patterns in various sediment types have no difference, basically same as those of coastal rivers and upper crust. They all show relative enrichments in light rare earth element (LREE), noticeable negative Eu anomaly and no Ce anomaly, indicating that those sediments are terrigenous sediments and from the same source region. Further analysis suggest that the sedimentary environment in the study area is relatively stable and granite widely distributed in the South China mainland is the main source of REE, which are transported mainly by the Pearl River. The late diagenesis has little effect on the REE.

Thickness of Weathering Profiles:Relaying Tectonic Signal to Biogeochemical Cycles

NASA Astrophysics Data System (ADS)

Yoo, K.; Weinman, B. A.; Hurst, M. D.; Mudd, S. M.; Gabet, E. J.; Attal, M.; Maher, K.

2011-12-01

Generation and transport of sediment across hillslopes and rivers are closely tied to mechanisms that produce and remove weathered material; in uplands this production and transport controls the thicknesses of weathering profiles. These processes, by controlling the residence time of minerals in the weathering profiles, further regulate the interactions between these minerals and largely biologically cycled elements like carbon and calcium. Here, we present and discuss the thicknesses of colluvial soils and underlying saprolites along three hillslopes that are subject to different rates of basal channel incision. Our field site is within a tributary basin to the Middle Folk Feather River in the Northern Sierra Nevada of California where the river has been down cutting through an uplifting granitic batholith over the past five to ten million years. Conventional modeling predicts that colluvial soil thickness declines with increasing denudation rates. Contrary to this expectation, intensive measurements of colluvial soil thickness show largely consistent values across the three hillslopes examined. This finding, in combination with the abrupt transitions to partial or full bare-rock landscapes with further increase in slope curvature or greater proximity to the Middle Folk Feather River, suggests that the mechanisms of soil production are capable of keeping pace with physical erosion rate until a certain threshold erosion rate is reached. We observe, however, that thicknesses of the underlying saprolite and the morphology (eg., color and texture) and geochemistry (eg., elemental concentration and extraction chemistry of iron) of both colluvial soil and saprolite materials vary systematically with the total denudation rates. This finding further allows us to build a simple relationship to describe and predict how the changes in erosion rates translate to the soils' capacity to store biologically cycled elements within rooting depths. Therefore, geomorphic and geochemical processes that control the thicknesses of weathering profiles, by determining their turn over time as well, relay the tectonic signal to the cycles of biologically relevant elements.

Red River of the North, Reconnaissance Report: Bois de Sioux-Mustinka Rivers Subbasin.

DTIC Science & Technology

1980-12-01

24 Climate . . . . . . . . . . . . . . . . . . . . 24 WaeorSy pp.................... 28 Water Supply . . .• 28 Cultural Elements . . . . 32...favored rough fish populations. Additionally, algal blooms and high turbidities have tended to limit habitat and spawning sites for game and pan fish...point where algal blooms occur in summer and early fall. Causative factors include (1) nutrients in runoff from surrounding farmlands; (2) run- off from

Anthropogenic Increase Of Soil Erosion In The Gangetic Plain Revealed By Geochemical Budget Of Erosion

NASA Astrophysics Data System (ADS)

Galy, V.; France-Lanord, C.; Galy, A.; Gaillardet, J.

2007-12-01

Tectonic and climatic factors are the key natural variables controlling the erosion through complex interactions. Nonetheless, over the last few hundred years, human activity also exerts a dominant control in response to extensive land use. The geochemical budget of erosion allows the balance between the different erosion processes to be quantified. The chemical composition of river sediment results from the chemical composition of the source rock modified by (1) weathering reactions occurring during erosion and (2) physical segregation during transport. If erosion is at steady state, the difference between the chemical composition of source rocks and that of river sediments must therefore be counterbalanced by the dissolved flux. However, climatic variations or anthropic impact can induce changes in the erosion distribution in a given basin resulting in non steady state erosion. Using a mass balance approach, the comparison of detailed geochemical data on river sediments with the current flux of dissolved elements allows the steady state hypothesis to be tested. In this study, we present a geochemical budget of weathering for the Ganga basin, one of the most densely populated basin in the world, based on detailed sampling of Himalayan rivers and of the Ganga in the delta. Sampling includes depth profile in the river, to assess the variability generated by transport processes. Himalayan river sediments are described by the dilution of an aluminous component (micas + clays + feldspars) by quartz. Ganga sediments on the other hand correspond to the mixing of bedload, similar to coarse Himalayan sediments, with an aluminous component highly depleted in alkaline elements. Compared with the dissolved flux, the depletion of alkaline elements in Ganga sediments shows that the alkaline weathering budget is imbalanced. This imbalance results from an overabundance of fine soil material in the Ganga sediment relative to other less weathered material directly derived from Himalaya. Based on the average composition of the suspended load and of floodplain soils, we estimate that 250x106 t/yr i.e. 5 t/ha/yr is eroded from soil surfaces of the Ganga floodplain. This enhanced soil erosion is likely triggered by intense deforestation and change in land use due to increasing human activity in the basin.

Storm water contamination and its effect on the quality of urban surface waters.

PubMed

Barałkiewicz, Danuta; Chudzińska, Maria; Szpakowska, Barbara; Świerk, Dariusz; Gołdyn, Ryszard; Dondajewska, Renata

2014-10-01

We studied the effect of storm water drained by the sewerage system and discharged into a river and a small reservoir, on the example of five catchments located within the boundaries of the city of Poznań (Poland). These catchments differed both in terms of their surface area and land use (single- and multi-family housing, industrial areas). The aim of the analyses was to explain to what extent pollutants found in storm water runoff from the studied catchments affected the quality of surface waters and whether it threatened the aquatic organisms. Only some of the 14 studied variables and 22 chemical elements were important for the water quality of the river, i.e., pH, TSS, rain intensity, temperature, conductivity, dissolved oxygen, organic matter content, Al, Cu, Pb, Zn, Fe, Cd, Ni, Se, and Tl. The most serious threat to biota in the receiver came from the copper contamination of storm water runoff. Of all samples below the sewerage outflow, 74% exceeded the mean acute value for Daphnia species. Some of them exceeded safe concentrations for other aquatic organisms. Only the outlet from the industrial area with the highest impervious surface had a substantial influence on the water quality of the river. A reservoir situated in the river course had an important influence on the elimination of storm water pollution, despite the very short residence time of its water.

The water quality of the LOCAR Pang and Lambourn catchments

NASA Astrophysics Data System (ADS)

Neal, C.; Jarvie, H. P.; Wade, A. J.; Neal, M.; Wyatt, R.; Wickham, H.; Hill, L.; Hewitt, N.

The water quality of the Pang and Lambourn, tributaries of the River Thames, in south-eastern England, is described in relation to spatial and temporal dimensions. The river waters are supplied mainly from Chalk-fed aquifer sources and are, therefore, of a calcium-bicarbonate type. The major, minor and trace element chemistry of the rivers is controlled by a combination of atmospheric and pollutant inputs from agriculture and sewage sources superimposed on a background water quality signal linked to geological sources. Water quality does not vary greatly over time or space. However, in detail, there are differences in water quality between the Pang and Lambourn and between sites along the Pang and the Lambourn. These differences reflect hydrological processes, water flow pathways and water quality input fluxes. The Pang’s pattern of water quality change is more variable than that of the Lambourn. The flow hydrograph also shows both a cyclical and "uniform pattern" characteristic of aquifer drainage with, superimposed, a series of "flashier" spiked responses characteristic of karstic systems. The Lambourn, in contrast, shows simpler features without the "flashier" responses. The results are discussed in relation to the newly developed UK community programme LOCAR dealing with Lowland Catchment Research. A descriptive and box model structure is provided to describe the key features of water quality variations in relation to soil, unsaturated and groundwater flows and storage both away from and close to the river.

The importance of colloids and mires for the transport of uranium isotopes through the Kalix River watershed and Baltic Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Porcelli, D.; Wasserburg, G.J.; Andersson, P.S.

The importance of colloids and organic deposits for the transport of uranium isotopes from continental source regions and through the estuarine environment was investigated in the mire-rich Kalix River drainage basin in northern Sweden and the Baltic Sea. Ultrafiltration techniques were used to separate uranium and other elements associated with colloids > 10 kD and >3 kD from {open_quotes}solute{close_quotes} uranium and provided consistent results and high recovery rates for uranium as well as for other elements from large volume samples. Uranium concentrations in 0.45 {mu}m-filtered Kalix River water samples increased by a factor of 3 from near the headwaters inmore » the Caledonides to the river mouth while major cation concentrations were relatively constant. {sup 234}U {sup 238}U ratios were high ({delta}{sup 234}U = 770-1500) throughout the basin, without showing any simple pattern, and required a supply of {sup 234}U-rich water. Throughout the Kalix River, a large fraction (30-90%) of the uranium is carried by >10 kD colloids, which is compatible with uranium complexation with humic acids. No isotopic differences were found between colloid-associated and solute uranium. Within the Baltic Sea, about half of the uranium is removed at low salinities. The proportion that is lost is equivalent to that of river-derived colloid-bound uranium, suggesting that while solute uranium behaves conservatively during estuarine mixing, colloid-bound uranium is lost due to rapid flocculation of colloidal material. The association of uranium with colloids therefore may be an important parameter in determining uranium estuarine behavior. Mire peats in the Kalix River highly concentrate uranium and are potentially a significant source of recoil {sup 234}U to the mirewaters and river waters. However, mirewater data clearly demonstrate that only small {sup 234}U/{sup 238}U shifts are generated relative to inflowing groundwater. 63 refs., 8 figs., 3 tabs.« less

The quality of rivers: From pristine stage to global pollution

NASA Astrophysics Data System (ADS)

Meybeck, Michel; Helmer, Richard

1989-12-01

River water quality is highly variable by nature due to environmental conditions such as basin lithology, vegetation and climate. In small watersheds spatial variations extend over orders of magnitude for most major elements and nutrients, while this variability is an order of magnitude lower for major basins. A standard river water for use as reference is therefore not applicable. As a consequence natural waters can possibly be unfit for various human uses, even including drinking. The Water Quality (WQ) concept has greatly evolved since the beginning of the century in accordance with expanding water uses and analytical developments. Even in well developed countries the dissolved heavy metal measurements in rivers are not very reliable while dissolved organic micro-pollutants are even rarely analysed routinely. Major WQ problems have been identified according to river basin size, including organic pollution, salinity, total suspended solids, heavy metals, eutrophication, nitrate, organic micro-pollutants, acidification. They generally occurred in this order over a period of about 100 years in the industrialized countries. Historical records of WQ are rare but can be established indirectly through studies of lake sediments. When proper control action is taken at an early stage, numerous examples of WQ recovery have been found in rivers for most of the common pollution problems. Future WQ problems will mostly derive from mine tailings and toxic waste disposal in both developed and developing countries, industrial accidents and organic micropollutants which emerge faster than our analytical capacities. The newly industrializing countries will face all the above-mentioned problems within a very short time period without having the means to cope with them one at a time. River studies point out the global alteration of the biogeochemical cycles of many major elements and nutrients (S, Na, K, N, P). For heavy metals such as lead, present estimates of global river loads emphasize the role of interim storage on land, thus delaying downstream pollution problems.

Trace elements in Corbicula fluminea from the San Joaquin River, California

USGS Publications Warehouse

Leland, H.V.; Scudder, B.C.

1990-01-01

(i) Trace element concentrations in soft tissue of the benthic bivalve, Corbicula fluminea, from the San Joaquin River and its major tributaries were examined during the primary irrigation season in relation to the spatial variation in concentrations of major, minor and trace constituents in riverwater and sediments. (ii) Selenium concentrations in Corbicula from perennial flow reaches of the San Joaquin River and its major tributaries varied directly with the solute (??? 0.45 ??m) Se concentrations of riverwater. Elevated concentrations occurred in clams from sites with substantial discharge originating as subsurface drainage and irrigation return flows. Both tissue and solute Se concentrations declined from June through the end of the primary irrigation season. (iii) Arsenic concentrations in Corbicula from perennial flow reaches of the San Joaquin River varied directly with the HNO3-extractable (pH 2) As:Fe ratio of suspended matter, providing evidence that sorption to oxyhydroxide surfaces is an important control on the biological availability of As. However, Corbicula from several tributaries draining alluvium derived from the Sierra Nevada had lower As concentrations than would be predicted by the relation developed for perennial flow sites of the San Joaquin River. Arsenic concentrations in Corbicula from the Tuolumne and Merced Rivers and upstream reaches of the San Joaquin River were higher than in clams from the downstream perennial flow reaches of the San Joaquin River. Concentrations of As in clams from downstream perennial flow reaches of the San Joaquin River increased from June through the end of the primary irrigation season. (iv) Mercury concentrations in Corbicula were elevated in upstream reaches of the San Joaquin River, in the Merced and Tuolumne Rivers, and in tributaries draining the Coast Ranges. Mean Cd and Cu concentrations in Corbicula were elevated in the Merced and Tuolumne Rivers, Orestimba Creek and a perennial flow reach of the San Joaquin River which receives water directly from the Delta Mendota Canal. Concentrations of Ni in clams from the San Joaquin River decreased downstream of the Delta Mendota Pool. (v) Boron and Mo were not accumulated by Corbicula despite high solute concentrations (means as high as 2960 ??g B l-1 and 9 ??g Mo l-1) in riverwater during the primary irrigation season. This bivalve may not be an appropriate bioindicator of B and Mo enrichment. Concentrations of Cr, Pb, Ag, V and Zn in Corbicula exhibited little geographic variability in the drainage. (vi) Regression analysis revealed no clear evidence of synergistic or antagonistic interactions among As, Cd, Cu, Hg, Ni and Se in their uptake by Corbicula.

Sediment tracing in the upper Hunter catchment using elemental and mineralogical compositions: Implications for catchment-scale suspended sediment (dis)connectivity and management

NASA Astrophysics Data System (ADS)

Fryirs, Kirstie; Gore, Damian

2013-07-01

River bed colmation layers clog the interstices of gravel-bed rivers, impeding the vertical exchange of water and nutrients that drives ecosystem function in the hyporheic zone. In catchments where fine-grained sediment supply has increased since human disturbance, understanding sediment provenance and the (dis)connectivity of supply allows practitioners to target sediment source problems and treat them within catchment management plans. Release of alluvial fine-grained sediment from channel bank erosion since European settlement has resulted in the formation of a colmation layer along the upper Hunter River at Muswellbrook, eastern Australia. X-ray fluorescence spectrometry (XRF) and X-ray diffractometry (XRD) are used to determine the elemental and mineralogical signatures of colmation layer and floodplain sediment sources across this 4480 km2 catchment. This sediment tracing technique is used to construct a picture of how suspended sediment supply and (dis)connectivity operates in this catchment. In this system, the primary source areas are subcatchments in which sediments are stored largely in partly confined floodplain pockets, but from which sediment supply is unimpeded and directly connected to the receiving reach. Subcatchments in which alluvial sediment storage is significant — and which contain large, laterally unconfined valleys — are essentially 'switched off' or disconnected from the receiving reach. This is because large sediment sinks act to trap fine-grained sediment before it reaches the receiving reach, forming a buffer along the sediment conveyor belt. Given the age structure of floodplains in the receiving reach, this pattern of source area contributions and (dis)connectivity must have occurred throughout the Holocene.

Ages and Nd, Sr isotopic systematics in the Sierran foothills ophiolite belt, CA: the Smartville and Feather River complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shaw, H.F.; Niemeyer, S.

1985-01-01

Sm-Nd dating has shown the Kings-Kaweah ophiolite to be approx. 480 My old. Its Nd, Sr, and Pb isotopic compositions require an unusually old depleted mantle source. Samples from the Smartville and Feather River complexes have been analyzed in a search for similar highly depleted, early Paleozoic ophiolites in the northern foothills ophiolite belt. Six whole rocks from Smartville, encompassing representative lithologies, plus plagioclase and pyroxene mineral separates define a 183 +/- 22 My Sm-Nd isochron. This age, interpreted as the igneous age, is older than, but within error of, approx. 160 My U-Pb ages previously obtained from plagiogranite zirconmore » analyses. One diabase with unusually high Rb/Sr yields a depleted mantle Sr model age of 200 +/- 25 My, consistent with the Sm-ND age. These compositions are clearly oceanic in character but do not discriminate among possible tectonic settings for the formation of the Smartville complex. Sm-Nd data for flaser gabbros and related rocks from Feather River scatter about an approx. 230 My errorchron with element of/sub Nd/(T) = +6.3 to +8.7. Initial /sup 87/Sr//sup 86/Sr ranges from 0.7028 to 0.7031. These results indicate a complex history with initial isotopic heterogeneities and/or disturbances of the isotopic systems. If primary, the element of/sub Nd/ (T) values are somewhat low, suggesting a possible arc origin for these rocks. Neither the Smartville nor Feather R. complexes appear to be related to the Kings-Kaweah ophiolite which, so far, is unique among foothill ophiolites in having an early Paleozoic age and a clear MORB, as opposed to arc or marginal basin, isotopic signature.« less

Spatial distribution of polycyclic aromatic hydrocarbon and polychlorinated biphenyl sources in the Nakdong River Estuary, South Korea.

PubMed

Lee, Jun H; Woo, Han J; Jeong, Kap S; Kang, Jeong W; Choi, Jae U; Jeong, Eun J; Park, Kap S; Lee, Dong H

2017-10-15

Our research team investigated the elemental composition and the presence of various toxic organic compounds, such as polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), in estuary surface sediments to trace the spatial distribution of the sources of pollution deposited in Nakdong River, Busan, South Korea. The spatial patterns of elemental composition and toxic organic compounds were determined from the measurements of total organic carbon (TOC), total nitrogen, total sulfur, PAHs, and PCBs. The sediments had TOC contents of between 0.02 and 1.80 wt% (avg. 0.34 wt%), depending on the amount of clay-sized particles. The concentrations of PAHs and PCBs (10.8-167.7 ng g -1 dry wt and 197.0-754.0 pg g -1 dry wt, respectively) in surface sediments revealed different spatial patterns for these compounds, suggesting that they partially originated from the combustion of fossil fuels and from the use of commercial PCB products at adjacent industrial complexes. Although these concentrations were far below the Sediment Quality Guideline (SQG) of the National Oceanic and Atmospheric Administration (NOAA), the sediments at one site contained PCBs at concentrations close to the response level (754.0 pg g -1 dry wt), and were dominated by low-molecular-weight PAHs. The PAHs and PCBs in Nakdong River Estuary sediments were likely to have originated from the combustion of fossil fuels and biomass at the adjacent industrial complexes. The primarily analyzed results determined that PAHs originated from the combustion of fossil fuels and biomass, and overall concentrations were related to the contributions of individual PAHs in most sediment samples. Based on the SQG of the NOAA, our results indicate that the anthropogenic activity should be considered on the future-sustainable management of this estuary system.

Just Around the Riverbend: Seasonal hydrologic controls on dynamic hyporheic zone redox biogeochemistry

NASA Astrophysics Data System (ADS)

Saup, C. M.; Sawyer, A. H.; Williams, K. H.; Wilkins, M.

2017-12-01

Upland rivers host exceptionally strong linkages between the terrestrial and aquatic elemental cycles. The weathering of mineral phases, coupled with degradation of organic matter and anthropogenic influences can result in the export of carbon, metals, and nutrients in upland fluvial systems, often decreasing downstream water quality with negative impacts on both human usage and ecosystem functioning. Within these fluvial networks, zones of hyporheic mixing—regions within the riverbed where surface water and groundwater mix—are thought to represent hotspots of biogeochemical activity, thus exerting significant control over elemental cycling and solute export. To investigate how the deeper exchange of oxic river water into the riverbed during snowmelt-driven peak discharge affects microbial degradation (oxidation) of carbon pools, depth resolved pore water samples were recovered from multiple locations around a representative meander on the East River near Crested Butte, CO. At each location, a series of temperature and redox probes were installed in the riverbed to track the extent of hyporheic mixing and the impact of this process on riverbed biogeochemistry. We complemented this real-time data with discrete samples collected during peak flow, intermediate flow, and base flow at a 10 cm resolution over 70 cm vertical profiles for a suite of microbiological and geochemical analyses. Results revealed elevated pore fluid concentrations of dissolved metals and recalcitrant DOC species under reducing conditions induced by base flow, while regions that were more influenced by down-welling oxic surface water hosted distinct microbial communities and lower metal concentrations. Overall, our results indicate that mixing-driven vertical redox gradients exert a strong control on biogeochemical processing in riverbeds, with implications for downstream water quality and solute export from watersheds.

[Environmental geochemical baseline of heavy metals in soils of the Ili river basin and pollution evaluation].

PubMed

Zhao, Xin-Ru; Nasier, Telajin; Cheng, Yong-Yi; Zhan, Jiang-Yu; Yang, Jian-Hong

2014-06-01

Environmental geochemical baseline models of Cu, Zn, Pb, As, Hg were established by standardized method in the ehernozem, chestnut soil, sierozem and saline soil from the Ili river valley region. The theoretical baseline values were calculated. Baseline factor pollution index evaluation method, environmental background value evaluation method and heavy metal cleanliness evaluation method were used to compare soil pollution degrees. The baseline factor pollution index evaluation showed that As pollution was the most prominent among the four typical types of soils within the river basin, with 7.14%, 9.76%, 7.50% of sampling points in chernozem, chestnut soil and sierozem reached the heavy pollution, respectively. 7.32% of sampling points of chestnut soil reached the permitted heavy metal Pb pollution index in the chestnut soil. The variation extent of As and Pb was the largest, indicating large human disturbance. Environmental background value evaluation showed that As was the main pollution element, followed by Cu, Zn and Pb. Heavy metal cleanliness evaluation showed that Cu, Zn and Pb were better than cleanliness level 2 and Hg was the of cleanliness level 1 in all four types of soils. As showed moderate pollution in sierozem, and it was of cleanliness level 2 or better in chernozem, chestnut soil and saline-alkali soil. Comparing the three evaluation systems, the baseline factor pollution index evaluation more comprehensively reflected the geochemical migration characteristics of elements and the soil formation processes, and the pollution assessment could be specific to the sampling points. The environmental background value evaluation neglected the natural migration of heavy metals and the deposition process in the soil since it was established on the regional background values. The main purpose of the heavy metal cleanliness evaluation was to evaluate the safety degree of soil environment.

Designing and Implementation of River Classification Assistant Management System

NASA Astrophysics Data System (ADS)

Zhao, Yinjun; Jiang, Wenyuan; Yang, Rujun; Yang, Nan; Liu, Haiyan

2018-03-01

In an earlier publication, we proposed a new Decision Classifier (DCF) for Chinese river classification based on their structures. To expand, enhance and promote the application of the DCF, we build a computer system to support river classification named River Classification Assistant Management System. Based on ArcEngine and ArcServer platform, this system implements many functions such as data management, extraction of river network, river classification, and results publication under combining Client / Server with Browser / Server framework.

American River Hydrologic Observatory

NASA Astrophysics Data System (ADS)

Glaser, S. D.; Bales, R. C.; Conklin, M. H.

2016-12-01

We have set up fourteen large wireless sensor networks to measure hydrologic parameters over physiographical representative regions of the snow-dominated portion of the river basin. This is perhaps the largest wireless sensor network in the world. Each network covers about a 1 km2 area and consists of about 45 elements. We measure snow depth, temperature humidity soil moisture and temperature, and solar radiation in real time at ten locations per site, as opposed to the traditional once-a-month snow course. As part of the multi-PI SSCZO, we have installed a 62-node wireless sensor network to measure snow depth, temperature humidity soil moisture and temperature, and solar radiation in real time. This network has been operating for approximately six years. We are now installing four large wireless sensor networks to measure snow depth, temperature humidity soil moisture and temperature, and solar radiation in East Branch of the North Fork of the Feather River, CA. The presentation will discuss the planning and operation of the networks as well as some unique results. It will also present information about the networking hardware designed for these installations, which has resulted in a start-up, Metronome Systems.

A Numerical Modeling Study of Mesodinium Bloom Formation and Retention in a River-Dominated Mesotidal Estuary

NASA Astrophysics Data System (ADS)

Spitz, Y. H.; Cervantes, B.

2016-02-01

The Columbia River estuary experiences extensive seasonal red-colored blooms caused by a mixotrophic ciliate of the genus Mesodinium. Although the blooms are non-toxic, they have a significant influence on the levels of nutrients, light and oxygen in the estuary. Mesodinium spp. displays very particular physiology that makes it one of few planktonic species able to thrive in a highly flushed system: a high growth rate due to its ability to photosynthesize using the photosynthetic organelles of its preys, and complex vertical migration patterns. Knowledge of the migration pattern is based on limited observations of Mesodinium behavior in culture and recent in-situ measurements collected in the Columbia River estuary. A more comprehensive understanding is needed of the mechanisms allowing Mesodinium spp. to be retained and experience rapid growth. To this end, we extended the finite element circulation model SELFE to include a 5-component behavioral model that simulates the relationships between nutrients, detritus, Mesodinium spp. and its cryptophyte prey. We then used the model to investigate various migration patterns and growth scenarios to determine their role in the formation and retention of the Mesodinium spp. bloom in the brackish water of the estuary.

Volatile Element Fluxes at Copahue Volcano, Argentina

NASA Astrophysics Data System (ADS)

Varekamp, J. C.

2002-05-01

Copahue volcano has a crater lake and acid hot springs that discharge into the Rio Agrio river system. These fluids are very concentrated (up to 6 % sulfate), rich in rock-forming elements (up to 2000 ppm Mg) and small spheres of native sulfur float in the crater lake. The stable isotope composition of the waters (delta 18O =-2.1 to + 3.6 per mille; delta D = -49 to -26 per mille) indicates that the hot spring waters are at their most concentrated about 70% volcanic brine and 30 % glacial meltwater. The crater lake waters have similar mixing proportions but added isotope effects from intense evaporation. Further dilution of the waters in the Rio Agrio gives values closer to local meteoric waters (delta 18O = -11 per mille; delta D = -77 per mille), whereas evaporation in closed ponds led to very heavy water (up to delta 18O = +12 per mille). The delta 34S value of dissolved sulfate is +14.2 per mille, whereas the native sulfur has values of -8.2 to -10.5 per mille. The heavy sulfate probably formed when SO2 disproportionated into bisulfate and native sulfur at about 300 C. We measured the sulfate fluxes in the Rio Agrio, which ranged from 20-40 kilotons S/year. The whole system was releasing sulfur at an equivalent rate of about 250-650 tons SO2/day. From the river flux sulfur values and the stochiometry of the disproportionation reaction we calculated the rate of liquid sulfur storage inside the volcano (6000 m3/year). During the eruptions of 1995/2000, large amounts of that stored liquid sulfur were ejected as pyroclastic sulfur. The calculated rate of rock dissolution (from rock- forming element fluxes in the Rio Agrio) suggests that the void space generated by rock dissolution is largely filled by native sulfur and silica. The S/Cl ratio in the hydrothermal fluids is about 2, whereas glass inclusions have S/Cl = 0.2, indicating the strong preferential degassing of sulfur.

Future of Hydroinformatics: Towards Open, Integrated and Interactive Online Platforms

NASA Astrophysics Data System (ADS)

Demir, I.; Krajewski, W. F.

2012-12-01

Hydroinformatics is a domain of science and technology dealing with the management of information in the field of hydrology (IWA, 2011). There is the need for innovative solutions to the challenges towards open information, integration, and communication in the Internet. This presentation provides an overview of the trends and challenges in the future of hydroinformatics, and demonstrates an information system, Iowa Flood Information System (IFIS), developed within the light of these challenges. The IFIS is a web-based platform developed by the Iowa Flood Center (IFC) to provide access to flood inundation maps, real-time flood conditions, flood forecasts both short-term and seasonal, flood-related data, information and interactive visualizations for communities in Iowa. The key element of the system's architecture is the notion of community. Locations of the communities, those near streams and rivers, define basin boundaries. The IFIS provides community-centric watershed and river characteristics, weather (rainfall) conditions, and streamflow data and visualization tools. Interactive interfaces allow access to inundation maps for different stage and return period values, and flooding scenarios with contributions from multiple rivers. Real-time and historical data of water levels, gauge heights, and rainfall conditions are available in the IFIS by streaming data from automated IFC bridge sensors, USGS stream gauges, NEXRAD radars, and NWS forecasts. 2D and 3D interactive visualizations in the IFIS make the data more understandable to general public. Users are able to filter data sources for their communities and selected rivers. The data and information on IFIS is also accessible through web services and mobile applications. The IFIS is optimized for various browsers and screen sizes to provide access through multiple platforms including tablets and mobile devices. The IFIS includes a rainfall-runoff forecast model to provide a five-day flood risk estimate for more than 1000 communities in Iowa. Multiple view modes in the IFIS accommodate different user types from general public to researchers and decision makers by providing different level of tools and details. River view mode allows users to visualize data from multiple IFC bridge sensors and USGS stream gauges to follow flooding condition along a river. The IFIS will help communities make better-informed decisions on the occurrence of floods, and will alert communities in advance to help minimize damage of floods.

Characterization of Surface Water and Groundwater Quality in the Lower Tano River Basin Using Statistical and Isotopic Approach.

NASA Astrophysics Data System (ADS)

Edjah, Adwoba; Stenni, Barbara; Cozzi, Giulio; Turetta, Clara; Dreossi, Giuliano; Tetteh Akiti, Thomas; Yidana, Sandow

2017-04-01

Adwoba Kua- Manza Edjaha, Barbara Stennib,c,Giuliano Dreossib, Giulio Cozzic, Clara Turetta c,T.T Akitid ,Sandow Yidanae a,eDepartment of Earth Science, University of Ghana Legon, Ghana West Africa bDepartment of Enviromental Sciences, Informatics and Statistics, Ca Foscari University of Venice, Italy cInstitute for the Dynamics of Environmental Processes, CNR, Venice, Italy dDepartment of Nuclear Application and Techniques, Graduate School of Nuclear and Allied Sciences University of Ghana Legon This research is part of a PhD research work "Hydrogeological Assessment of the Lower Tano river basin for sustainable economic usage, Ghana, West - Africa". In this study, the researcher investigated surface water and groundwater quality in the Lower Tano river basin. This assessment was based on some selected sampling sites associated with mining activities, and the development of oil and gas. Statistical approach was applied to characterize the quality of surface water and groundwater. Also, water stable isotopes, which is a natural tracer of the hydrological cycle was used to investigate the origin of groundwater recharge in the basin. The study revealed that Pb and Ni values of the surface water and groundwater samples exceeded the WHO standards for drinking water. In addition, water quality index (WQI), based on physicochemical parameters(EC, TDS, pH) and major ions(Ca2+, Na+, Mg2+, HCO3-,NO3-, CL-, SO42-, K+) exhibited good quality water for 60% of the sampled surface water and groundwater. Other statistical techniques, such as Heavy metal pollution index (HPI), degree of contamination (Cd), and heavy metal evaluation index (HEI), based on trace element parameters in the water samples, reveal that 90% of the surface water and groundwater samples belong to high level of pollution. Principal component analysis (PCA) also suggests that the water quality in the basin is likely affected by rock - water interaction and anthropogenic activities (sea water intrusion). This was confirm by further statistical analysis (cluster analysis and correlation matrix) of the water quality parameters. Spatial distribution of water quality parameters, trace elements and the results obtained from the statistical analysis was determined by geographical information system (GIS). In addition, the isotopic analysis of the sampled surface water and groundwater revealed that most of the surface water and groundwater were of meteoric origin with little or no isotopic variations. It is expected that outcomes of this research will form a baseline for making appropriate decision on water quality management by decision makers in the Lower Tano river Basin. Keywords: Water stable isotopes, Trace elements, Multivariate statistics, Evaluation indices, Lower Tano river basin.

The use of portable instruments for mapping contaminants in the floodplain of the Ploucnice River (Czech Republic)

NASA Astrophysics Data System (ADS)

Elznicova, Jitka; Sikora, Martin; Slaba, Eva; Popelka, Jan; Hosek, Michal; Matys Grygar, Tomas

2015-04-01

The Ploucnice River (the Czech Republic) was contaminated by uranium mining in the areas of Hamr na Jezere and Straz pod Ralskem mainly in 1971-1987. The pollutants are now deposited all over the floodplain of the river. In 2005 the aerial mapping of radioactive pollution in the floodplain of the Ploucnice River was performed at a height of 80 m above the ground in grid 250 x 250 m. That survey showed uneven, highly localised deposition of gamma-emitting nuclides along nearly the entire reach of the Ploucnice River. We studied several of those radioactivity hotspots 10-25 km downstream from the uranium mining area in aim to understand the reasons for that heterogeneity. The contamination of the floodplain was analysed mainly by two portable (handheld) instruments. The gamma-spectrometer DISA 400A was used for measuring the total surface gamma activity (main target nuclide was Ra-226). Very effective was also the use of portable X-ray fluorescence spectrometer (XRF) Olympus Innov-X (DELTA Premium), which provides fast analysis of more than 30 elements, such as pollutants (Ba, Ni, Pb, U and Zn) and grain-size sensitive lithogenic elements (Al, Si, Zr, Rb). Besides pollution mapping, XRF also allows for mapping sediment lithology using Al/Si or Rb/Zr element ratios (both proportional to the percentage of fine fraction). The field gamma spectrometry and XRF was performed with points 2-30 meters spaced, which revealed that hotspots according to low resolution (250 m) aerial mapping is composed of one or several strongly polluted areas with sizes up to several tens of metres. Similarly heterogeneous was also the distribution of sediment lithology in the floodplain. In some cases, micromorphology of the floodplain, formed mainly by the past meander abandonments and channel shifts was responsible for the heterogeneity of the pollution. To understand the floodplain development we used old maps and aerial photographs. The Czech Republic has an extensive archive of historical aerial photos from 1938 and then from 1953 to the present with 5 or 10 years intervals. The maximal contamination was found in places where there was a meander cuts shortly after a flood (>Q50) in1981. Additionally we used digital elevation model (DEM), created from a laser scanning (LIDAR) dataset DMR 5G obtained in 2010 with nominal altitudinal precision of 0.18 m in open terrain and 0.3 in forested terrain. Our study demonstrated that very detailed, high-resolution analysis of pollution distribution in the floodplain, achievable by portable analytical instruments and interpreted on the base of micro-geomorphology analysis, help to better understand the sedimentation patterns and sediment reworking in fluvial systems.

Pollutant fates in fluvial systems: on need of individual approach to each case study

NASA Astrophysics Data System (ADS)

Matys Grygar, Tomas; Elznicova, Jitka; Novakova, Tereza

2015-04-01

To outline the pollutant fates in fluvial systems it is necessary to combine two main kinds of knowledge: sedimentation and erosion patterns of each individual river with spatio-temporal resolution higher than in most fluvial geomorphology/sedimentology studies and timing and way how the pollutants have entered the fluvial system. Most of these aspects are commonly neglected in environmental geochemistry, a domain to which pollution studies apparently belong. In fact, only when these two main components are established (at least in a qualitative manner), we can start reading (interpretation) of the fluvial sedimentary archives, e.g., decipher the way how the primary pollution signal has been distorted during passing through the fluvial system. We conducted empirical studies on Czech rivers impacted by pollution (by risk elements). We learnt how individual (site-specific) are the main processes responsible for the primary pollution input, spread through each fluvial system and inevitable secondary pollution ("lagged pollution improvement signal"). We will discuss main features of the story on pollutant fates in three different fluvial systems, which have not been impacted by "hard" river engineering and still undergo natural fluvial processes: 1. the Ohre (the Eger) impacted by production of Hg and its compounds, historical mining of Pb and more recent U ore processing, 2. the Ploucnice impacted by U mining, and 3. the Litavka, impacted by Pb-Zn(-Sb) mining and smelting. The Ohre is specific by most pollution having been temporarily deposited in an active channel, only minor reworking of older fluvial deposits diluting pollution during downstream transport, and pollution archives existing practically only in the form of lateral accretion deposits. The deposits of archive value are rare and can be revealed by detailed study of historical maps and well-planned field analysis, best using portable analytical instruments (XRF). The Ploucnice is specific by only transient deposition in a channel belt and subsequent secondary pollution via physical mobilisation, most pollution storing in the floodplain in a surprisingly heterogeneous manner - in hotspots with a size comparable to fragments of abandoned channels (from a few to few tens of metres). The hotspots are hence best revealed by well-designed field analysis using portable instruments (gamma spectrometry or XRF). The Litavka is specific because most pollution is in its floodplain in the form of anthropogenic alluvium, a very thick vertical accretion body of "artificial" material added to the river system in the amount exceeding its normal transport capacity. That situation favours secondary pollution by chemical mobilisation of pollutants under low river discharges revealed by geochemical analysis. Our case studies show that simple "rules" such as continuous decay of pollutant concentrations downstream from the pollution source, existence of a continuous blanket of polluted overbank fines in floodplain, simple change of the pollution extent with growing distance from the river channel and as a consequence of extreme floods, or simple recipes such as low-density sampling to trace point pollution sources are too simplistic to be applicable in real polluted fluvial systems. Each river system represents a nearly unique combination of individual geomorphic processes, and each pollution has been specific by the mode how it entered the fluvial system. We will not offer "magic tools" in our contribution. In literature we can find all pieces we need for the jigsaw puzzle - pollutants fates in fluvial systems. The question is why so rarely researchers put them together. We would like to encourage them to do so.

Impacts of anthropogenic pressures on the water quality of the Gironde Estuary (SW France) from the Urban Agglomeration of Bordeaux: spatial characterization and inputs of trace metal elements (Ag, As, Cd, Cu, Pb and Zn)

NASA Astrophysics Data System (ADS)

Kessaci, Kahina; Coynel, Alexandra; Blanc, Gérard; Deycard, Victoria N.; Derriennic, Hervé; Schäfer, Jörg

2014-05-01

Recent European legislation (2000/60/CE) has listed eight trace metal elements as priority toxic substances for water quality. Urban metal inputs into hydrosystems are of increasing interest to both scientists and managers facing restrictive environmental protection policies, population increase and changing metal applications. The Gironde Estuary (SW France; 625 km2) is known for its metal/metalloid pollution originating from industrial (e.g. Cd, Zn, Cu, As, Ag, Hg) or agricultural sources (e.g. Cu) in the main fluvial tributaries (Garonne and Dordogne Rivers). However, little peer-reviewed scientific work has addressed the impact of urban sources on the Gironde Estuary, especially the Urban Agglomeration of Bordeaux (~1 million inhabitants) located on the downstream branch of the Garonne River. In this study, a snapshot sampling campaign was performed in 2011 for characterizing the spatial distribution of dissolved and particulate metal/metalloid (As, Ag, Cd, Pb, Zn, Cu) concentrations in three suburban watersheds: the Jalle of Blanquefort (330 km2), Eau Bourde (140 km2), and Peugue (112 km2). Furthermore, particulate metal Enrichment Factors (EF) were calculated using local geochemical background measured at the bottom of a sediment core (492 cm). Results indicated that metal concentrations displayed a high spatial variability depending on the suburban watershed and the studied element. Local concentrations anomalies were observed for: (i) As in the Eau Bourde River in dissolved (4.2 μg/l) and particulate phases (246 mg/kg; EF= 20) and attributed to a nearby industrial incinerator; (ii) Zn in the Peugue River with maximum dissolved and particulate concentrations of 87 μg/l and 1580 mg/kg (EF=17), respectively, probably due to urban habitation runoff; (iii) Ag in the Jalle of Blanquefort River with high dissolved (74 ng/l) and particulate concentrations (33.7 mg/kg; EF=117) due to industrial activities in the downstream part. Based on hydro-geochemical monitoring of both suburban rivers and local wastewater treatment plants (WWTPs), we present a first estimate of metal/metalloid fluxes and compare them to the respective loads in the Garonne River. Our results suggest that suburban metal inputs may significantly increase metal concentrations and fluxes in the fluvial Gironde Estuary, especially for Ag due to inputs exported by WWTPS and the Jalle of Blanquefort River.

Floods and Fluvial Wood

NASA Astrophysics Data System (ADS)

Comiti, F.

2014-12-01

Several studies have recently addressed the complex interactions existing at various spatial scales among riparian vegetation, channel morphology and wood storage. The majority of these investigations has been carried out in relatively natural river systems, focusing mostly on the long-term vegetation-morphology dynamics under "equilibrium" conditions. Little is still known about the role of flood events - of different frequency/magnitude - on several aspects of such dynamics, e.g. entrainment conditions of in-channel wood, erosion rates of vegetation from channel margins and from islands, transport distances of wood elements of different size along the channel network. Even less understood is how the river's evolutionary trajectory may affect these processes, and thus the degree to which conceptual models derivable from near-natural systems could be applicable to human-disturbed channels. Indeed, the different human pressures - present on most river basins worldwide - have greatly impaired the morphological and ecological functions of fluvial wood, and the attempts to "restore" in-channel wood storage are currently carried out without a sufficient understanding of wood transport processes occurring during floods. On the other hand, the capability to correctly predict the magnitude of large wood transport during large floods is now seen as crucial - especially in mountain basins - for flood hazard mapping, as is the identification of the potential wood sources (e.g. landslides, floodplains, islands) for the implementation of sound and effective hazard mitigation measures. The presentation will first summarize the current knowledge on fluvial wood dynamics and modelling at different spatial and temporal scales, with a particular focus on mountain rivers. The effects of floods of different characteristics on vegetation erosion and wood transport will be then addressed presenting some study cases from rivers in the European Alps and in the Italian Apennines featuring different degrees of human alteration. Finally, several conclusions about the applicability of wood transport modelling and on rationale vegetation/wood management strategies will be drawn.

Tracing Anthropogenic Salinity Inputs to the Semi-arid Rio Grande River: A Multi-isotope Tracer (U, S, B and Sr) Approach

NASA Astrophysics Data System (ADS)

Garcia, S.; Nyachoti, S. K.; Ma, L.; Szynkiewicz, A.; McIntosh, J. C.

2015-12-01

High salinity in the Rio Grande has led to severe reductions in crop productivity and accumulation of salts in soils. These pressing issues exist for other arid rivers worldwide. Salinity contributions to the Rio Grande have not been adequately quantified, especially from agriculture, urban activities, and geological sources. Here, we use major element concentrations and U, S, B, Sr isotopic signatures to fingerprint the salinity sources. Our study area focuses on a 200 km long stretch of the Rio Grande from Elephant Butte Reservoir, NM to El Paso, TX. River samples were collected monthly from 2014 to 2015. Irrigation drains, groundwater wells, city drains and wastewater effluents were sampled as possible anthropogenic salinity end-members. Major element chemistry, U, S and Sr isotope ratios in the Rio Grande waters suggest multiple salinity inputs from geological, agricultural, and urban sources. Natural upwelling of groundwater is significant for the Rio Grande near Elephant Butte, as suggested by high TDS values and high (234U/238U), 87Sr/86Sr, δ34S ratios. Agricultural activities (e.g. flood irrigation, groundwater pumping, fertilizer use) are extensive in the Mesilla Valley. Rio Grande waters from this region have characteristic lower (234U/238U), 87Sr/86Sr, and δ34S ratios, with possible agricultural sources from use of fertilizers and gypsum. Agricultural practices during flood irrigation also intensify evaporation of Rio Grande surface water and considerably increase water salinity. Shallow groundwater signatures were also identified at several river locations, possibly due to the artificial pumping of local groundwater for irrigation. Impacts of urban activities to river chemistry (high NO3 and B concentrations) were evident for locations downstream to Las Cruces and El Paso wastewater treatment plants, supporting the use of the B isotope as an urban salinity tracer. This study improves our understanding of human impacts on water quality and elemental cycles.

Diurnal cycles control the fate of contaminants at an Andean river confluence impacted by legacy mining

NASA Astrophysics Data System (ADS)

Pasten, P.; Guerra, P. A.; Simonson, K.; Bonilla, C.; Pizarro, G. E.; Escauriaza, C. R.; González, C.

2014-12-01

The importance of hydrologic-geochemical interactions in arid environments is a controlling factor in quality and quantity of water available for human consumption and agriculture. When acid drainage affects these watersheds, water quality is gravely degraded. Despite its effect on watersheds, the relationship between time changes in hydrological variables and water quality in arid regions has not been studied thoroughly. Temporal variations in acid drainage can control when the transport of toxic elements is increased. We performed field work at the Azufre River (pH 2, E.C~10.9 mS/cm) and Caracarani River (pH 8.7, E.C~1.2 mS/cm) confluence, located in the Northern Chilean Altiplano (at 4000 m asl). We registered stream flowrates (total flowrate~430 L/s), temperature and electric conductivity (E.C) hourly using in-stream data loggers during one year. We also measured turbidity and pH during one field survey at different distances from the junction, as a proxy of the formation of iron-aluminum particles that cycle trace elements in these environments. We found turbidity-pH diurnal cycles were caused by upstream hourly changes in upstream flowrate: when the Caracarani River flowrate reached its daily peak, particle formation occurred, while the dissolution of particles occurred when the Azufre River reached its maximum value. This last process occurred due to upstream freeze-thaw cycles. This study shows how the dynamics of natural confluences determines chemical transport. The formation of particles enriched in toxic elements can promote settling as a natural attenuation process, while their dissolution will produce their release and transport long distances downstream. It is important to consider time as an important variable in water quality monitoring and in water management infrastructure where pulses of contamination can have potentially negative effects in its use. Acknowledgements: Funding was provided by "Proyecto Fondecyt 1130936" and "CONICYT/FONDAP 15110020".

Accumulation of as, pb, and cu associated with the recent sedimentary processes in the colorado delta, South of the United States-Mexico boundary.

PubMed

Daesslé, L W; Lugo-Ibarra, K C; Tobschall, H J; Melo, M; Gutiérrez-Galindo, E A; García-Hernández, J; Alvarez, L G

2009-05-01

Sediment cores from the Colorado River (CR) remnant delta were used to assess the changing sedimentation and pollutant deposition processes in response to extensive human manipulation of the river. The cores are formed of alternating layers of clays and silts, with isolated sandy horizons. The clayey units are interpreted as periods of flood flows into this low gradient and meandering estuary after dam construction in the United States. The geochemistry of these sediments is particular because of the association of MnO with CaO rather than with the Fe(2)O(3)-rich clays. Past pollution of the CR delta by As, and probably also Pb and Cu, is recorded in some cores. Enrichment factors (EFs) >1 for these elements and their statistical association suggest anthropogenic inputs. The most likely sources for these element enrichments (especially As) are the arsenate-based pesticides used intensively in the area during the first half of the 20th century. The transport of these elements from the nearby agricultural lands into the present river reaches appears to have been driven in part by flooding events of the CR. Flushing by river and tide flows appear to be responsible of a lower pollutant deposition in the CR compared to the adjacent Hardy River (HR). Arsenic in the buried clay units of the HR has concentrations above the probable toxic effect level (PEL) for dwelling organisms, with maximum concentrations of 30 microg g(-1). Excess (210)Pb activities ((210)Pb(xs)) indicate that fluxes of this unsupported atmospheric isotope were not constant in this estuarine environment. However, the presence of (210)Pb(xs) does indicate that these sediments accumulated during the last ~100 years. Aproximate sediment ages were estimated from the correlation of historic flooding events with the interpretation of the stratigraphic record. They are in fair agreement with the reported onset of DDT metabolites at the bottom of one core.

Flood-deposited wood debris and its contribution to heterogeneity and regeneration in a semi-arid riparian landscape.

PubMed

Pettit, Neil E; Naiman, Robert J

2005-09-01

We investigated whether large woody debris (LWD) piles create nodes of environmental resources that contribute to the recovery of riparian vegetation and that also augment the heterogeneity and resilience of the riverine system. River and riparian systems are typified by a large degree of heterogeneity and complex interactions between abiotic and biotic elements. Disturbance such as floods re-distribute the resources, such as LWD, and thereby add greater complexity to the system. We examined this issue on a semi-arid savanna river where approximately a 100-year return interval flood in 2000 uprooted vegetation and deposited substantial LWD. We investigated the micro-environment within the newly established LWD piles and compared this with conditions at adjacent reference sites containing no LWD. We found soil nutrient concentrations to be significantly higher in LWD piles compared with the reference plots (total N +19%, available P +51%, and total C +36%). Environmental variables within LWD piles and reference sites varied with landscape position in the river-riparian landscape and with LWD pile characteristics. Observed differences were generally between piles located in the terrestrial and riparian areas as compared to piles located on the macro-channel floor. After 3 years the number and cover of woody species were significantly higher when associated with LWD piles, regardless of landscape position or pile type. We conclude that LWD piles formed after large floods act as resource nodes by accumulating fine sediments and by retaining soil nutrients and soil moisture. The subsequent influence of LWD deposition on riparian heterogeneity is discerned at several spatial scales including within and between LWD piles, across landscape positions and between channel types. LWD piles substantially influence the initial developmental of riparian vegetation as the system regenerates following large destructive floods.

Nitrogen budget in a lowland coastal area within the Po River basin (northern Italy): multiple evidences of equilibrium between sources and internal sinks.

PubMed

Castaldelli, Giuseppe; Soana, Elisa; Racchetti, Erica; Pierobon, Enrica; Mastrocicco, Micol; Tesini, Enrico; Fano, Elisa Anna; Bartoli, Marco

2013-09-01

Detailed studies on pollutants genesis, path and transformation are needed in agricultural catchments facing coastal areas. Here, loss of nutrients should be minimized in order to protect valuable aquatic ecosystems from eutrophication phenomena. A soil system N budget was calculated for a lowland coastal area, the Po di Volano basin (Po River Delta, Northern Italy), characterized by extremely flat topography and fine soil texture and bordering a network of lagoon ecosystems. Main features of this area are the scarce relevance of livestock farming, the intense agriculture, mainly sustained by chemical fertilizers, and the developed network of artificial canals with long water residence time. Average nitrogen input exceeds output terms by ~60 kg N ha(-1) year(-1), a relatively small amount if compared to sub-basins of the same hydrological system. Analysis of dissolved inorganic nitrogen in groundwater suggests limited vertical loss and no accumulation of this element, while a nitrogen mass balance in surface waters indicates a net and significant removal within the watershed. Our data provide multiple evidences of efficient control of the nitrogen excess in this geographical area and we speculate that denitrification in soil and in the secondary drainage system performs this ecosystemic function. Additionally, the significant difference between nitrogen input and nitrogen output loads associated to the irrigation system, which is fed by the N-rich Po River, suggests that this basin metabolizes part of the nitrogen excess produced upstream. The traditionally absent livestock farming practices and consequent low use of manure as fertilizer pose the risk of excess soil mineralization and progressive loss of denitrification capacity in this area.

Market Anatomy of a Drought: Modeling Barge and Corn Market Adaptation to Reduced Rainfall and Low Mississippi River Water Levels During the 2012 Midwestern U.S. Drought

NASA Astrophysics Data System (ADS)

Foster, B.; Characklis, G. W.; Thurman, W. N.

2015-12-01

In mid 2012, a severe drought swept across the Midwest, the heartland of corn production in the U.S. When the drought persisted into late Fall, corn markets were affected in two distinct ways: (1) reduced rainfall led to projected and actual corn yields that were lower than expected and (2) navigation restrictions, a result of low water levels on the Mississippi River, disrupted barge transportation, the most common and inexpensive mode for moving corn to many markets. Both (1) and (2) led to significant financial losses, but due to the complexity of the economic system and the coincidence of two different market impacts, the size of the role that low water levels played wass unclear. This is important, as losses related to low water levels are used to justify substantial investments in dredging activities on the Mississippi River. An "engineering" model of the system, suggests that low water levels should drive large increases in barge and corn prices, while some econometric models suggest that water levels explain very little of the changes in barge rates and corn prices. Employing a model that integrates both the engineering and economic elements of the system indicates that corn prices and barge rates during the drought display spatial and temporal behavior that is difficult to explain using either the engineering or econometric models alone. This integrated model accounts for geographic and temporal variations in drought impacts and identifies unique market responses to four different sets of conditions over the drought's length. Results illustrate that corn and barge price responses during the drought were a product of comingled, but distinct, reactions to both supply changes and navigation disruptions. Results also provide a more structured description of how the economic system that governs corn allocation interacts with the Mississippi River system during drought. As both public and private parties discuss potential managerial or infrastructural methods for keeping shipping channels open during drought, the results of this work should help them to decide how different interventions might benefit or hurt barge operators and/or corn sellers.

The cost of noncooperation in international river basins

NASA Astrophysics Data System (ADS)

Tilmant, A.; Kinzelbach, W.

2012-01-01

In recent years there has been a renewed interest for water supply enhancement strategies in order to deal with the exploding demand for water in some regions, particularly in Asia and Africa. Within such strategies, reservoirs, especially multipurpose ones, are expected to play a key role in enhancing water security. This renewed impetus for the traditional supply-side approach to water management may indeed contribute to socioeconomic development and poverty reduction if the planning process considers the lessons learned from the past, which led to the recommendations by the World Commission on Dams and other relevant policy initiatives. More specifically, the issues dealing with benefit sharing within an efficient and equitable utilization of water resources are key elements toward the successful development of those river basins. Hence, there is a need for improved coordination and cooperation among water users, sectors, and riparian countries. However, few studies have explicitly tried to quantify, in monetary terms, the economic costs of noncooperation, which we believe to be important information for water managers and policy makers, especially at a time when major developments are planned. In this paper we propose a methodology to assess the economic costs of noncooperation when managing large-scale water resources systems involving multiple reservoirs, and where the dominant uses are hydropower generation and irrigated agriculture. An analysis of the Zambezi River basin, one of the largest river basins in Africa that is likely to see major developments in the coming decades, is carried out. This valuation exercise reveals that the yearly average cost of noncooperation would reach 350 million US$/a, which is 10% of the annual benefits derived from the system.

Defining river types in a Mediterranean area: a methodology for the implementation of the EU Water Framework Directive.

PubMed

Munné, Antoni; Prat, Narcís

2004-11-01

The Water Framework Directive (WFD), approved at the end of 2000 by the European Union, proposes the characterization of river types through two classification systems (A and B) (Annex II of the WFD), thereby obtaining comparable reference sites and improving the management of aquatic systems. System A uses fixed categories of three parameters to classify rivers: three altitude ranges, four basin size ranges, and three geological categories. In the other hand, System B proposes to establish river types analyzing different factors considered as obligatory and optional. Here, we tested Systems A and B in the Catalan River Basin District (NE Spain). The application of System A results in 26 river types: 8 in the Pyrenees and 18 in the Iberic-Macaronesian ecoregions. This number would require the establishment of a complex management system and control of the ecological status in a relatively small river basin district. We propose a multivariant system to synthesize the environmental descriptors and to define river types using System B. We use five hydrological, seven morphological, five geological, and two climatic variables to discriminate among river types. This method results in fewer river type categories than System A but is expected to achieve the same degree of differentiation because of the large number of descriptors considered. Two levels are defined in our classification method using System B. Five "river types," defined at large scale (1:1,000,000), are mainly discriminated by annual runoff coefficient, air temperature, and discharge. This level is useful and could facilitate comparisons of results among European river basin districts. The second level defines 10 "subtypes of river management," mainly discriminated by geology in the basin and flow regime. This level is more adequate at local scale (1:250,000) and provides a useful tool for management purposes in relatively small and heterogeneous river basin districts.

The water quality of the River Enborne, UK: insights from high-frequency monitoring

NASA Astrophysics Data System (ADS)

Halliday, Sarah; Skeffington, Richard; Wade, Andrew; Bowes, Mike; Gozzard, Emma; Palmer-Felgate, Elizabeth; Newman, Johnathan; Jarvie, Helen; Loewenthal, Matt

2014-05-01

The River Enborne is a rural lowland catchment, impacted by agricultural runoff, and septic tank and sewage treatment works (STWs) discharges. Between November 2009 and February 2012, the river was instrumented with in situ analytical equipment to take hourly measurements of total reactive phosphorus (TRP), using a Systea Micromac C; nitrate, using a Hach Lange Nitratax; and pH, chlorophyll, dissolved oxygen, conductivity, turbidity and water temperature, using a YSI 6600 Multi-parameter sonde. In addition, weekly 'grab samples' were also collected and analysed for a wide range of chemical determinands including major ions, nutrients, and trace elements. The catchment land use is largely agricultural, with wheat the dominant crop, and the average population density is 123 persons per sq. km. The river water is largely derived from calcareous groundwater, with a mean calcium concentration of 68.5 mg/l, and high nitrogen and phosphorus concentrations, with mean nitrate and TRP concentrations of 3.96 mg/l-N and 0.17 mg/l-P respectively. A mass-balance for the catchment demonstrated that agricultural fertiliser is the dominant source of annual loads of both nitrogen and phosphorus, accounting for 77 % and 84 % respectively. However, the concentration data show that sewage effluent discharges have a disproportionate effect on the river nitrogen and phosphorus dynamics, with the diurnal STW discharge signal discernable in the high-frequency nutrient dynamics. The nutrient dynamics and correlation structure of the data indicate a substantial contribution of groundwater and agricultural runoff to stream nitrate concentrations, whereas discharges from septic tank systems and sewage treatment works are a more important source of phosphorus. The high-frequency turbidity and conductivity dynamics reveal key information about the seasonal changes controlling the system dynamics, with marked differences in diurnal conductivity dynamics at the onset of riparian shading linked to the decreased importance of the photosynthetically-driven cycle of bicarbonate concentration. Only 4 % of the phosphorus input and 9 % of the nitrogen input is exported from the catchment by the river, highlighting the importance of catchment process understanding in predicting nutrient concentrations. High-frequency monitoring will be a key to developing this vital process understanding.

Do predator-prey relationships on the river bed affect fine sediment ingress?

NASA Astrophysics Data System (ADS)

Mathers, Kate; Rice, Stephen; Wood, Paul

2016-04-01

Ecosystem engineers are organisms that alter their physical environment and thereby influence the flow of resources through ecosystems. In rivers, several ecosystem engineers are also important geomorphological agents that modify fluvial sediment dynamics. By altering channel morphology and bed material characteristics, such modifications can affect the availability of habitats for other organisms, with implications for ecosystem health and wider community composition. In this way geomorphological and ecological systems are intimately interconnected. This paper focuses on one element of this intricate abiotic-biotic coupling: the interaction between fine sediment ingress into the river bed and the predator-prey relationships of aquatic organisms living on and in the river bed. Signal crayfish (Pacifastacus leniusculus) have been shown to modify fine sediment fluxes in rivers, but their effect on fine sediment ingress into riverbeds remains unclear. Many macroinvertebrate taxa have adapted avoidance strategies to avoid predation by crayfish, with one example being the freshwater shrimp (Gammarus pulex) which relies on open interstitial spaces within subsurface sediments as a refuge from crayfish predation. Fine sedimentation that fills gravelly frameworks may preclude access to those spaces, therefore leaving freshwater shrimp susceptible to predation. Ex-situ experiments were conducted which sought to examine: i) if freshwater shrimps and signal crayfish, alone and in combination, influenced fine sediment infiltration rates; and ii) whether modifications to substratum composition, specifically the introduction of fine sediment, modified predator-prey interactions. The results demonstrate that crayfish are significant geomorphic agents and that fine sediment ingress rates were significantly enhanced in their presence compared to control conditions or the presence of only freshwater shrimps. The combination of both organisms (i.e. allowing the interaction between predator and prey) resulted in intermediate fine sediment infiltration rates. The results suggest that reductions in prey availability may enhance crayfish foraging behaviour and therefore their impact on fine sediment ingress into river beds. Consequently, as invading species become more established and prey resources are depleted, the implications of invasive crayfish on fine sediment dynamics may become more prominent. These experiments demonstrate the importance of abiotic-biotic coupling in fluvial systems for both geomorphological and ecological understanding.

Analysis of water control in an underground mine under strong karst media influence (Vazante mine, Brazil)

NASA Astrophysics Data System (ADS)

Ninanya, Hugo; Guiguer, Nilson; Vargas, Eurípedes A.; Nascimento, Gustavo; Araujo, Edmar; Cazarin, Caroline L.

2018-05-01

This work presents analysis of groundwater flow conditions and groundwater control measures for Vazante underground mine located in the state of Minas Gerais, Brazil. According to field observations, groundwater flow processes in this mine are highly influenced by the presence of karst features located in the near-surface terrain next to Santa Catarina River. The karstic features, such as caves, sinkholes, dolines and conduits, have direct contact with the aquifer and tend to increase water flow into the mine. These effects are more acute in areas under the influence of groundwater-level drawdown by pumping. Numerical analyses of this condition were carried out using the computer program FEFLOW. This program represents karstic features as one-dimensional discrete flow conduits inside a three-dimensional finite element structure representing the geologic medium following a combined discrete-continuum approach for representing the karst system. These features create preferential flow paths between the river and mine; their incorporation into the model is able to more realistically represent the hydrogeological environment of the mine surroundings. In order to mitigate the water-inflow problems, impermeabilization of the river through construction of a reinforced concrete channel was incorporated in the developed hydrogeological model. Different scenarios for channelization lengths for the most critical zones along the river were studied. Obtained results were able to compare effectiveness of different river channelization scenarios. It was also possible to determine whether the use of these impermeabilization measures would be able to reduce, in large part, the elevated costs of pumping inside the mine.

Metals in fish from the Upper Benue River and lakes Geriyo and Njuwa in northeastern Nigeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eromosele, C.O.; Eromosele, I.C.; Muktar, S.L.M.

Lakes Geriyo and Njuwa occupy natural depressions near the upper Benue River in northeastern Nigeria. The lakes are flooded by the river during the rainy season spanning the months of May to September. Fishing activities on the lakes and river provide fish for consumption by the local communities. Industrial activity around the upper Benue River and the lakes is low and there is no information on other activities with the potential for polluting the Benue River as it flows from neighboring Cameroon. However, an unconfirmed report indicated high levels of lead in the upper Benue River, generally speculated as arisingmore » from biogeometrical factors. Trace elements, some of which are toxic, may accumulate in edible marine organisms to levels which may be deleterious to human health. For the upper Benue River and its associate lakes, Geriyo and Njuwa, there is yet no report of a systematic study to assess the levels of metals in fish found in these waters. This paper presents the results of a study on metal levels in fish collected from Lakes Geriyo and Njuwa and upper Benue River in northeastern Nigeria. 7 refs., 1 fig., 2 tabs.« less

Two Reactive Zones within Riverbank Aquifers Impact the Accumulation of Arsenic within Permeable Natural Reactive Barrier

NASA Astrophysics Data System (ADS)

Knappett, P.; Myers, K.; Jewell, K.; Berube, M.; Datta, S.; Hossain, A.; Hosain, A.; Lipsi, M.; Ahmed, K. M.

2017-12-01

River stage fluctuations drives river water, rich oxidants, into riverbanks aquifers. When these aquifers are rich in dissolved iron (Fe), iron oxides (FeOOH) precipitate, creating a reactive surface upon which toxic elements such as arsenic (As) may sorb. These Permeable Natural Reactive Barriers (PNRBs) have been studied on the Meghna River. The lack of understanding of what controls their formation and fate could result in dangerous consequences. Pumping of riverbank aquifers for irrigation could re-mobilize toxic concentrations of As into drinking water aquifers. It is important to understand the hydrological, geochemical and biological processes controlling the properties of PNRBs. To this end, monitoring wells and drive-point piezometers were installed orthogonal to the Meghna River in Bangladesh. The dimensions of the shallow aquifer was mapped with Electrical Resistivity Tomography (ERT). The monitoring wells and a river gage were instrumented with pressure transducers to record water level fluctuations. Groundwater flows towards the river for most of the year but reverses under the influence of local irrigation pumping in the late dry season and rapidly rising river stage in the early monsoon. Semi-diurnal tides in the dry season have an amplitude of 80 cm. Declining concentrations of conservative dissolved ions towards the river indicated a zone of dilution from river water extending up to 50 m from the river's dry season edge. Dissolved As was produced as groundwater passed through this dilution zone until the final 20 m where As was abruptly removed from solution. This location coincided with a PNRB with enriched solid-phase Fe and Mn within the upper 3 m of sediment. 16S bacterial community DNA was sequenced from the wells and drive-point piezometers to map the distribution of Fe and As reducers and oxidizers. The richest overall biodiversity was found within the PNRB zone. It contained the most oxidizing and reducing species. This evidence suggests that transient river levels drive mixing between oxidizing and reducing agents in Hyporheic Zones (HZs). When the shallow aquifers are rich in dissolved concentrations of Fe and As, this mixing results in the accumulation of solid-phase Fe and As. This is likely a general process affecting other oxide-forming metals and toxic elements they bind.

Information Summary, Area of Concern: Grand Calumet River, Indiana

DTIC Science & Technology

1991-03-01

Indiana Harbor and Adjacent Lake Michigan (Source Rl, Table 4) 10 Concentrations of 26 Major, Minor and Trace Elements in Sediments from Indiana Harbor...2 Dec 84 (Source R39, Table 2) 68 Concentrations of Major, Minor , and Trace Elements in Fish and Crayfish from Indiana Harbor and Adjacent Lake...Table 21b) 71 Catch per Unit Effort in Crayfish Traps (Source Rl, Table 21c) 72 Concentratiors of Major, Minor , and Trace Elements in Periphyton and

The role of water chemistry and geomorphic control in the presence of Didymosphenia geminata in Quebec

NASA Astrophysics Data System (ADS)

Gillis, C.; Gabor, R. S.; Cullis, J. D.; Ran, L.; Hassan, M. A.

2010-12-01

Didymosphenia geminata (didymo), an invasive diatom, was first officially observed and identified in the Matapedia River in Eastern Quebec in July 2006. This Atlantic salmon fishing river has several characteristics shown to favor didymo's ability to form thick, extensive benthic mats, including stable flow and oligotrophic nutrient conditions. Since the incursion, rapid colonization and inter-catchment transfer processes were observed, notably in surrounding watersheds on the Gaspé Peninsula as well as in northern New-Brunswick. All affected watersheds share favorable characteristics for didymo growth, including high light, low nutrient waters, and stable substrate. The nearby North Shore of the St. Lawrence, which also contains rivers with conditions that would favor didymo growth, has not yet shown didymo presence. This system provides a comparison to identify necessary parameters for didymo growth, with differences primarily due to geology-driven water chemistry. Pre-incursion water chemistry was compared between the two regions. Rivers in the region where didymo is present displayed a high alkalinity and corresponding higher pH, due to increases concentrations of magnesium and calcium, than rivers in regions where didymo has not appeared. Also, rivers with didymo show a lower amount of color-causing compounds, such as organic carbon, and clearer water, which supports the theory that high light levels encourage didymo growth. In addition to water chemistry, channel morphology, bed stability and flow patterns are also believed to be key elements in determining the presence of this benthic diatom. In 2007, channel morphology, bed texture, bankfull depth and width, local bed slope and didymo presence were surveyed on a 65 km stretch of the Matapedia River. Relative frequency of didymo presence showed that didymo blooms are most likely to appear in cobble-riffles than in any other morphologies. In fact, cobble riffles promote didymo establishment due to shallow waters which offer high solar radiation as well as stable riverbed. Both water chemistry and geomorphic factors appear to control Didymosphenia geminata spatial patterns and occurrence.

Effects of an Extreme Flood on Trace Elements in River Water-From Urban Stream to Major River Basin.

PubMed

Barber, Larry B; Paschke, Suzanne S; Battaglin, William A; Douville, Chris; Fitzgerald, Kevin C; Keefe, Steffanie H; Roth, David A; Vajda, Alan M

2017-09-19

Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the South Platte River, Colorado, USA. Weekly time-series water samples were collected from 3 urban source waters (municipal tap water, streamwater, and wastewater treatment facility effluent) under normal-flow and flood conditions. In addition, water samples were collected during the flood at 5 locations along the South Platte River and from 7 tributaries along the Colorado Front Range. Samples were analyzed for 54 major and trace elements. Specific chemical tracers, representing different natural and anthropogenic sources and geochemical behaviors, were used to compare streamwater composition before and during the flood. The results differentiate hydrological processes that affected water quality: (1) in the upper watershed, runoff diluted most dissolved constituents, (2) in the urban corridor and lower watershed, runoff mobilized soluble constituents accumulated on the landscape and contributed to stream loading, and (3) flood-induced groundwater discharge mobilized soluble constituents stored in the vadose zone.

Numerical Estimation of the Outer Bank Resistance Characteristics in AN Evolving Meandering River

NASA Astrophysics Data System (ADS)

Wang, D.; Konsoer, K. M.; Rhoads, B. L.; Garcia, M. H.; Best, J.

2017-12-01

Few studies have examined the three-dimensional flow structure and its interaction with bed morphology within elongate loops of large meandering rivers. The present study uses a numerical model to simulate the flow pattern and sediment transport, especially the flow close to the outer-bank, at two elongate meandering loops in Wabash River, USA. The numerical grid for the model is based on a combination of airborne LIDAR data on floodplains and the multibeam data within the river channel. A Finite Element Method (FEM) is used to solve the non-hydrostatic RANS equation using a K-epsilon turbulence closure scheme. High-resolution topographic data allows detailed numerical simulation of flow patterns along the outer bank and model calibration involves comparing simulated velocities to ADCP measurements at 41 cross sections near this bank. Results indicate that flow along the outer bank is strongly influenced by large resistance elements, including woody debris, large erosional scallops within the bank face, and outcropping bedrock. In general, patterns of bank migration conform with zones of high near-bank velocity and shear stress. Using the existing model, different virtual events can be simulated to explore the impacts of different resistance characteristics on patterns of flow, sediment transport, and bank erosion.

Effects of an extreme flood on trace elements in river water—From urban stream to major river basin

USGS Publications Warehouse

Barber, Larry B.; Paschke, Suzanne; Battaglin, William A.; Douville, Chris; Fitzgerald, Kevin C.; Keefe, Steffanie H.; Roth, David A.; Vajda, Alan M.

2017-01-01

Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the South Platte River, Colorado, USA. Weekly time-series water samples were collected from 3 urban source waters (municipal tap water, streamwater, and wastewater treatment facility effluent) under normal-flow and flood conditions. In addition, water samples were collected during the flood at 5 locations along the South Platte River and from 7 tributaries along the Colorado Front Range. Samples were analyzed for 54 major and trace elements. Specific chemical tracers, representing different natural and anthropogenic sources and geochemical behaviors, were used to compare streamwater composition before and during the flood. The results differentiate hydrological processes that affected water quality: (1) in the upper watershed, runoff diluted most dissolved constituents, (2) in the urban corridor and lower watershed, runoff mobilized soluble constituents accumulated on the landscape and contributed to stream loading, and (3) flood-induced groundwater discharge mobilized soluble constituents stored in the vadose zone.

Surface Hydrology in Global River Basins in the Off-Line Land-Surface GEOS Assimilation (OLGA) System

NASA Technical Reports Server (NTRS)

Bosilovich, Michael G.; Yang, Runhua; Houser, Paul R.

1998-01-01

Land surface hydrology for the Off-line Land-surface GEOS Analysis (OLGA) system and Goddard Earth Observing System (GEOS-1) Data Assimilation System (DAS) has been examined using a river routing model. The GEOS-1 DAS land-surface parameterization is very simple, using an energy balance prediction of surface temperature and prescribed soil water. OLGA uses near-surface atmospheric data from the GEOS-1 DAS to drive a more comprehensive parameterization of the land-surface physics. The two global systems are evaluated using a global river routing model. The river routing model uses climatologic surface runoff from each system to simulate the river discharge from global river basins, which can be compared to climatologic river discharge. Due to the soil hydrology, the OLGA system shows a general improvement in the simulation of river discharge compared to the GEOS-1 DAS. Snowmelt processes included in OLGA also have a positive effect on the annual cycle of river discharge and source runoff. Preliminary tests of a coupled land-atmosphere model indicate improvements to the hydrologic cycle compared to the uncoupled system. The river routing model has provided a useful tool in the evaluation of the GCM hydrologic cycle, and has helped quantify the influence of the more advanced land surface model.

System understanding as a basis for sustainable decision-making. A science - school collaboration within the Sparkling Science project "Traisen w3"

NASA Astrophysics Data System (ADS)

Poppe, Michaela; Böck, Kerstin; Loach, Andreas; Scheikl, Sigrid; Zitek, Andreas; Heidenreich, Andrea; Kurz-Aigner, Roman; Schrittwieser, Martin; Muhar, Susanne

2016-04-01

Equipping young people with the skills to participate successfully in increasingly complex environments and societies is a central issue of policy makers around the world. Only the understanding of complex socio-environmental systems establishes a basis for making decisions leading to sustainable development. However, OECD Pisa studies indicated, that only a low percentage of 15-year-old students was able to solve straightforward problems. Additionally, students get less interested in natural science education. In Austria "Sparkling Science" projects funded by the Federal Ministry of Science, Research and Economy in Austria target at integrating science with school learning by involving young people into scientific research for the purpose of developing new and engaging forms of interactive, meaningful learning. Within the Sparkling Science Project "Traisen.w3" scientists work together with 15 to 18-year-old students of an Austrian Secondary School over two years to identify and evaluate ecosystem services within the catchment of the river Traisen. One of the aims of the project is to foster system understanding of the youths by multi-modal school activities. To support the development of causal systems thinking, students developed qualitative causal models on processes in the catchment of the river Traisen with an interactive, hierarchically structured learning environment that was developed within the EU-FP7 project "DynaLearn" (http://www.dynalearn.eu) based on qualitative reasoning. Students worked in small groups and were encouraged to interlink entities, processes and simulate the results of the proposed interactions of hydrological, biological, ecological, spatial and societal elements. Within this setting collaborative problem solving competency through sharing knowledge, understanding and different perspectives was developed. Additionally, in several school workshops the ecosystem services concept was used as communication tool to show the multifunctionality of river catchments and to highlight the necessity of a sustainable use. Furthermore a field mapping of a restored and an anthropogenically altered section of the river Traisen was performed by the students in collaboration with the scientists. It aimed on the surveying of specific parameters relevant for the identification of cultural and ecological ecosystem services. To investigate the effects of the different forms of learning on youths' factual, regional and system knowledge, tests were conducted before and after the school activities. The evaluation results of the pre- and post-tests proved that the multi-modal school activities lead to a significantly higher students' knowledge of environmental processes in river landscapes. The analyses of the students` model scenarios for the river catchment Traisen revealed a clear students` understanding of relationships of anthropogenic impacts, morphological and ecological river states and restoration measures. Students` feedback showed high enthusiasm for field work and the application of theoretical knowledge in their regional context. Summarizing, the involvement of secondary school students in the research project "Traisen.w3" can be seen as a successful example of how students` system thinking and motivation for learning can be increased. Ensuring that young people are proficient in system knowledge and understanding also in relation to their own surrounding environment makes it more likely that sustainable considerations are soundly addressed in the future.

Concentrations and Distribution of Slag-Related Trace Elements and Mercury in Fine-Grained Beach and Bed Sediments of Lake Roosevelt, Washington, April-May 2001

USGS Publications Warehouse

Majewski, Michael S.; Kahle, Sue C.; Ebbert, James C.; Josberger, Edward G.

2003-01-01

A series of studies have documented elevated concentrations of trace elements such as arsenic, cadmium, copper, lead, mercury, and zinc in the water, bed sediment, or fish of Lake Roosevelt and the upstream reach of the Columbia River. Elevated concentrations of some trace elements in this region are largely attributable to the transport of slag and metallurgical waste discharged into the Columbia River from a smelter in Canada. Although most recent studies have focused on contamination levels in water, bed sediment, and fish, there is growing concern in the region over the potential threat of airborne contaminants to human health. In response to these concerns, the U.S. Geological Survey conducted an assessment of trace-element concentrations in the relatively shallow fine-grained sediment along the shore of Lake Roosevelt that is exposed annually during periods of reservoir drawdown. During each winter and spring, the water level of Lake Roosevelt is lowered as much as about 80 feet to provide space to capture high river flows from spring runoff, exposing vast expanses of lake-bottom sediment for a period of several months. Upon drying, these exposed areas provide an extremely large source for wind-blown dust. This study concluded that trace elements associated with slag and metallurgical waste are present in the fine-grained fraction (less than 63 micrometers) of bed sediments along the length of Lake Roosevelt, and as such, could be components of the airborne dust resulting from exposure, drying, and wind mobilization of the sediments exposed during the annual drawdowns of the reservoir. Trace-element concentrations in the surficial bed sediment varied, but the major components in slag?arsenic, cadmium, copper, lead, and zinc?showed generally pronounced gradients of decreasing concentrations from near the International Border to the Grand Coulee Dam. The results of this study provide base-line information needed to plan and conduct air monitoring of trace elements in wind-blown dust along Lake Roosevelt.

78 FR 12344 - Wekiva River System Advisory Management Committee Meetings (FY2013)

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-22

... River System Advisory Management Committee. DATES: The meetings are scheduled for: April 3, 2013; June 4... meeting will result in decisions and steps that advance the Wekiva River System Advisory Management... Wekiva River System Advisory Management Committee, National Park Service, 5342 Clark Road, PMB 123...

Reconnaissance of chemical and physical characteristics of selected bottom sediments of the Caloosahatchee River and estuary, tributaries, and contiguous bays, Lee County, Florida, July 20-30, 1998

USGS Publications Warehouse

Fernandez, Mario; Marot, M.E.; Holmes, C.W.

1999-01-01

This report summarizes a reconnaissance study, conducted July 20-30, 1998, of chemical and physical characteristics of recently deposited bottom sediments in the Caloosahatchee River and Estuary. Recently deposited sediments were identified using an isotopic chronometer, Beryllium-7 (7Be), a short-lived radioisotope. Fifty-nine sites were sampled in an area that encompasses the Caloosahatchee River (River) about three miles upstream from the Franklin Lock (S-79), the entire tidally affected length of the river (estuary), and the contiguous water bodies of Matlacha Pass, San Carlos Bay, Estero Bay, Tarpon Bay, and Pine Island Sound in Lee County, Florida. Bottom sediments were sampled for 7Be at 59 sites. From the results of the 7Be analysis, 30 sites were selected for physical and chemical analysis. Sediments were analyzed for particle size, total organic carbon (TOC), trace elements, and toxic organic compounds, using semiquantitative methods for trace elements and organic compounds. The semiquantitative scans of trace elements indicated that cadmium, copper, lead, and zinc concentrations, when normalized to aluminum, were above the natural background range at 24 of 30 sites. Particle size and TOC were used to characterize sediment deposition patterns and organic content. Pesticides, polychlorinated biphenyls (PCBs), and carcinogenic polycyclic aromatic hydrocarbons (CaPAHs) were determined at 30 sites using immunoassay analysis. The semiquantitative immunoassay analyses of toxic organic compounds indicated that all of the samples contained DDT, cyclodienes as chlordane (pesticides), and CaPAHs. PCBs were not detected. Based on analyses of the 30 sites, sediments at 10 of these sites were analyzed for selected trace elements and toxic organic compounds, including pesticides, PCBs, and PAHs, using quantitative laboratory procedures. No arsenic or cadmium was detected. Zinc was detected at two sites with concentrations greater than the lower limit of the range of sediment contaminant concentrations that are usually or always associated with adverse effects (Florida Department of Environmental Protection's Sediment Quality Assessment Guidelines). Organochlorine pesticides were detected at four sites at concentrations below the reporting limits; there were no organophosphorus pesticides or PCBs detected. PAHs were detected at eight sites; however, only four sites had concentrations above the reporting limit.

Estimating Nitrogen Loading in the Wabash River Subwatershed Using a GIS Schematic Processing Network in Support of Sustainable Watershed Management Planning

EPA Science Inventory

The Wabash River is a tributary of the Ohio River. This river system consists of headwaters and small streams, medium river reaches in the upper Wabash watershed, and large river reaches in the lower Wabash watershed. A large part of the river system is situated in agricultural a...

Documenting utility of paddlefish otoliths for quantification of metals using inductively coupled plasma mass spectrometry

USGS Publications Warehouse

Long, James M.; Schaffler, James J.

2013-01-01

RATIONALE The otoliths of the inner ear of fishes record the environment of their surrounding water throughout their life. For paddlefish (Polyodon spathula), otoliths have not been routinely used by scientists since their detriments were outlined in the early 1940s. We sought to determine if paddlefish otoliths were useful for resolving elemental information contained within. METHODS Adult paddlefish were collected from two wild, self-sustaining populations in Oklahoma reservoirs in the Arkansas River basin. Juveniles were obtained from a hatchery in the Red River basin of Oklahoma. Otoliths were removed and laser ablation, inductively coupled plasma mass spectrometry (ICP-MS) was used to quantify eight elements (Li, Mg, Mn, Rb, Sr, Y, Ba, and Pb) along the core and edge portions, which were analyzed for differences between otolith regions and among paddlefish sources. RESULTS Differences were found among samples for six of the eight elements examined. Otoliths from Red River basin paddlefish born in a hatchery had significantly lower amounts of Mg and Mn, but higher levels of Rb than otoliths from wild paddlefish in the Arkansas River basin. Concentrations of Y, Sr, and Ba were reduced on the edges of adult paddlefish from both reservoirs compared with the cores. CONCLUSIONS This research shows the utility of using an ICP-MS analysis of paddlefish otoliths. Future research that seeks to determine sources of paddlefish production, such as which reservoir tributaries are most important for reproduction or what proportion of the population is composed of wild versus hatchery-produced individuals, appears promising. Published in 2013. This article is a U.S. Government work and is in the public domain in the USA.

H, C, O, and N stable isotopes to decipher climate feedbacks in a mountainous watershed (East River, Colorado)

NASA Astrophysics Data System (ADS)

Bill, M.; Conrad, M. E.; Beller, H. R.; Bouskill, N.; Brodie, E.; Brown, W.; Carroll, R. W. H.; Kim, Y.; Nico, P. S.; Sorensen, P. O.; Tokunaga, T. K.; Wan, J.; Williams, K. H.

2017-12-01

Temperature and precipitation variability in response to climate change affects water cycling of a watershed and can potentially impact water quality, water availability, elemental and molecular fluxes, and biogeochemical processes. Here we report the application of light stable isotopic analysis to a large multidisciplinary project addressing watershed function. The study area is charaterized by a snow-dominated headwater catchment of the Colorado River (East River, Colorado). We are measuring H, C, O, and N stable isotopes in an effort to differentiate natural and climate induced perturbations to the hydrologic cycle on C and N cycling in a moutainous watershed. Water H and O stable isotopes of rain, snow, ground and surface water are being used to constrain source contributions to streamflow. H and O isotopes of water together with elemental concentations were used in end-member mixing analysis (EMMA) to chararacterize and quantify downstream flow. Results indicate runoff is dominated by snowmelt (66±13%) and to a lessor extent groundwater (26±11%) with sources moving toward near equal contributions during baseflow (45%). We are also using C and N stable isotopes in conjunction with elemental concentations to characterize leaf litter and to estimate nutrient inputs and decomposition rates. C and N isotopes are being used to characterize watershed soils, soil biomass, and sedimentary rocks to constrain carbon fluxes to the rivers and the atmosphere. We are analyzing variations of C, O, and N stable isotopes of CO2, N2O and CH4 greenhouse gases in different temperature, precipitation, and hydrological regimes to connect climate change with biogeochemical fluxes between the watershed and the atmosphere.

Strontium and Trace Metals in the Mississippi River Mixing Zone

NASA Astrophysics Data System (ADS)

Xu, Y.; Marcantonio, F.

2001-12-01

Strontium is generally believed to be a conservative element, i.e., it is assumed that dissolved Sr moves directly from rivers through estuaries to the ocean. More recently, however, detailed sampling of rivers suggests a weak non-conservative behavior for Sr. Here, we present dissolved and suspended load Sr and trace metal data for samples retrieved along salinity transects in the estuarine mixing zone of the Mississippi River. Our cruises took place during times representing high, falling, and low Mississippi River discharge. Sr concentration and isotopic composition were analyzed for both dissolved particulate loads. Selected particle-reactive or redox-sensitive trace metals (Mn, Fe, U, V, Mo, Ti, and Pb) were analyzed simultaneously. In the dissolved load, Sr showed conservative behavior in both high- and low- discharge periods. Non-conservative behavior of Sr predominated during falling discharge in the summer. Significant positive correlations were found between Sr, Mo and Ti. U and V distributions were found to be essentially controlled by mixing of river water and seawater, but with significantly lower riverine concentrations during high-flow stage. Particulate element concentrations can be quite variable and heterogeneous. In this study, strong correlations were found between particulate Mn (and Fe) concentrations and particulate concentrations of Ti, U, V, and Pb. No such correlations with Mn (or Fe) were found for particulate Sr and Mo. There is a vast hypoxic zone along the coast of Louisiana in the Gulf of Mexico that exists during the summer months. Based on the Sr isotope systematics and the relationships between Sr and trace metals, we believe that this eutrophication may contribute to the non-conservative behaviors of Sr and other trace metals. We discuss the potential implications of this hypothesis on the Sr mass balance of present-day and past seawater.

Hazard assessment of selenium and other trace elements in wild larval razorback sucker from the Green River, Utah

USGS Publications Warehouse

Hamilton, S.J.; Muth, R.T.; Waddell, B.; May, T.W.

2000-01-01

Contaminant investigations of the Green River in northeastern Utah have documented selenium contamination at sites receiving irrigation drainage. The Green River provides critical habitat for four endangered fishes including the largest extant riverine population of endangered razorback sucker. Although 2175 larval razorback suckers were collected from the river between 1992 and 1996, very few juveniles have been captured within recent decades. Selenium concentrations were measured in larval razorback suckers collected from five sites in the Green River (Cliff Creek, Stewart Lake Drain, Sportsman's Drain, Greasewood Corral, and Old Charlie Wash) to assess the potential for adverse effects on recruitment of larvae to the juvenile stage and the adult population. Larvae from all sites contained mean selenium concentrations ranging from 4.3 to 5.8 ??g/g. These values were at or above the proposed toxic threshold of 4 ??g/g for adverse biological effects in fish, which was derived from several laboratory and field studies with a wide range of fish species. At two sites, Cliff Creek and Stewart Lake Drain, selenium concentrations in larvae increased over time as fish grew, whereas selenium concentrations decreased as fish grew at Sportsman's Drain. Evaluation of a 279-larvae composite analyzed for 61 elements demonstrated that selenium and, to a lesser extent, vanadium were elevated to concentrations reported to be toxic to a wide range of fish species. Elevated selenium concentrations in larval razorback suckers from the five sites suggest that selenium contamination may be widespread in the Green River, and that survival and recruitment of larvae to the juvenile stage may be limited due to adverse biological effects. Selenium contamination may be adversely affecting the reproductive success and recruitment of endangered razorback sucker.

Crustal processes of the Mid-Ocean Ridge

USGS Publications Warehouse

Ballard, Richard D.; Craig, H.; Edmond, J.; Einaudi, M.; Holcomb, R.; Holland, H.D.; Hopson, C.A.; Luyendyk, B.P.; Macdonald, K.; Morton, J.; Orcutt, J.; Sleep, N.

1981-01-01

Independent geological and geophysical investigations of the Mid-Ocean Ridge system have begun to focus on the nature of the magma chamber system underlying its central axis. Thermal models predict the existence of a steady-state chamber beneath a thin crustal lid ranging in thickness from 2 to 13 kilometers. The only aspect of the system that these models fail to account for is the extremely slow spreading rates. Seismological studies reveal the existence of a low-velocity zone beneath segments of the East Pacific Rise, which is thought to correspond to a chamber system having a half-width of approximately 5 to 10 kilometers. These estimates compare favorably with those derived separately through petrological investigations of deep-sea drilling results, various sampling programs, and field and laboratory studies of ophiolites. The chamber is thought to be wing-shaped and to remain continuously open; it is thought to be fed from the center while simultaneously solidifying at the sides as spreading carries the two halves apart. Progressive fractionation occurs by crystal settling coupled with repeated replenishment and magma mixing in an open steady-state system. Near-bottom studies reveal that the zone of extrusion above the chamber is narrow, but its eruptive history is cyclic in nature, in conflict with the predictions of a steady-state model. On-bottom gravity data at 21 ??N on the East Pacific Rise reveal a negative gravity anomaly that may be related to the uppermost part of the chamber. The anomaly is only 2 kilometers wide and 1 kilometer below the sea floor. This feature may be associated with a short-term upper magma reservoir. The cyclic volcanic activity is directly related to the active phase of hydrothermal circulation responsible for the observed negative thermal anomaly. The volume of water associated with this circulation is equal to the entire ocean volume passing through the accretion zone approximately every 8 million years. This is about 0.5 percent of the world's rivers, but the effective transport rates of elements are comparable to those of rivers in that anomalies for individual elements are frequently between 100 and 1000 times the average river composition. The degree of subsurface dilution determines the final exit temperature and composition of the hydrothermal fluids, ranging from manganese domination at extreme dilution to iron at intermediate levels to sulfide deposition when low dilution occurs. The discovery of massive sulfide deposits on the East Pacific Rise is destined to have a profound impact on our understanding of ore-forming processes. Whether it will have any economic significance remains to be seen. Copyright ?? 1981 AAAS.

Crustal processes of the mid-ocean ridge.

PubMed

1981-07-03

Independent geological and geophysical investigations of the Mid-Ocean Ridge system have begun to focus on the nature of the magma chamber system underlying its central axis. Thermal models predict the existence of a steady-state chamber beneath a thin crustal lid ranging in thickness from 2 to 13 kilometers. The only aspect of the system that these models fail to account for is the extremely slow spreading rates. Seismological studies reveal the existence of a low-velocity zone beneath segments of the East Pacific Rise, which is thought to correspond to a chamber system having a half-width of approximately 5 to 10 kilometers. These estimates compare favorably with those derived separately through petrological investigations of deep-sea drilling results, various sampling programs, and field and laboratory studies of ophiolites. The chamber is thought to be wing-shaped and to remain continuously open; it is thought to be fed from the center while simultaneously solidifying at the sides as spreading carries the two halves apart. Progressive fractionation occurs by crystal settling coupled with repeated replenishment and magma mixing in an open steady-state system. Near-bottom studies reveal that the zone of extrusion above the chamber is narrow, but its eruptive history is cyclic in nature, in conflict with the predictions of a steady-state model. On-bottom gravity data at 21 degrees N on the East Pacific Rise reveal a negative gravity anomaly that may be related to the uppermost part of the chamber. The anomaly is only 2 kilometers wide and 1 kilometer below the sea floor. This feature may be associated with a short-term upper magma reservoir. The cyclic volcanic activity is directly related to the active phase of hydrothermal circulation responsible for the observed negative thermal anomaly. The volume of water associated with this circulation is equal to the entire ocean volume passing through the accretion zone approximately every 8 million years. This is about 0.5 percent of the world's rivers, but the effective transport rates of elements are comparable to those of rivers in that anomalies for individual elements are frequently between 100 and 1000 times the average river composition. The degree of subsurface dilution determines the final exit temperature and composition of the hydrothermal fluids, ranging from manganese domination at extreme dilution to iron at intermediate levels to sulfide deposition when low dilution occurs. The discovery of massive sulfide deposits on the East Pacific Rise is destined to have a profound impact on our understanding of ore-forming processes. Whether it will have any economic significance remains to be seen.

A comprehensive analysis of the content of heavy rare-earth elements and platinum in snow samples to assess the ecological hazard of air pollution in urban areas

NASA Astrophysics Data System (ADS)

Vinokurov, S. F.; Tarasova, N. P.; Trunova, A. N.; Sychkova, V. A.

2017-07-01

Snow samples from the territory of the Setun River Valley Wildlife Sanctuary are analyzed for the content of rare-earth elements, heavy metals, and other hazardous elements by the inductively coupled plasma mass-spectrometry method. The changes in the concentrations of rare-earth elements, Pt, Pd, and indicator ratios of elements in the solid fractions of snow are revealed. A trend toward a decrease in the content of several elements northeastward of the Moscow Ring Road (MRR) is established. The level of seasonal atmospheric contamination of the area under study is assessed, and a possible source is identified.

Biomonitoring of Environmental Status and Trends (BEST) Program: Environmental contaminants and their effects on fish in the Yukon River Basin

USGS Publications Warehouse

Hinck, Jo Ellen; Bartish, Timothy M.; Blazer, Vicki; Denslow, Nancy D.; Gross, Tim S.; Myers, Mark S.; Anderson, Patrick J.; Orazio, Carl E.; Tillitt, Donald E.

2004-01-01

This project collected, examined, and analyzed 217 fish representing three species at 10 stations in the U.S. portion of the Yukon River Basin (YRB) from May to October 2002. Four sampling sites were located on the Yukon River; two were located on the Porcupine River, and one site was on each of the Ray, Tanana, Tolavana, and Innoko Rivers. Norther pike (Esox lucius), longnose sucker (Catostomus catostomus), and burbot (Lota lota) were weighed and measured, and examined in the field for external and internal lesions, and liver, spleen, and gonads were weighed to compute somatic indices. Selected tissues and fluids were collected and preserved for analysis of fish health and reproductive biomarkers. Composite samples of whole fish from each station were grouped by species and gender and analyzed for organochlorines and elemental contaminants and for dioxin-like activity using H4IIE rat hepatoma cell bioassay.

Assessment of sediments in the riverine impoundments of national wildlife refuges in the Souris River Basin, North Dakota

USGS Publications Warehouse

Tangen, Brian A.; Laubhan, Murray K.; Gleason, Robert A.

2014-01-01

Accelerated sedimentation of reservoirs and riverine impoundments is a major concern throughout the United States. Sediments not only fill impoundments and reduce their effective life span, but they can reduce water quality by increasing turbidity and introducing harmful chemical constituents such as heavy metals, toxic elements, and nutrients. U.S. Fish and Wildlife Service national wildlife refuges in the north-central part of the United States have documented high amounts of sediment accretion in some wetlands that could negatively affect important aquatic habitats for migratory birds and other wetland-dependent wildlife. Therefore, information pertaining to sediment accumulation in refuge impoundments potentially is important to guide conservation planning, including future management actions of individual impoundments. Lands comprising Des Lacs, Upper Souris, and J. Clark Salyer National Wildlife Refuges, collectively known as the Souris River Basin refuges, encompass reaches of the Des Lacs and Souris Rivers of northwestern North Dakota. The riverine impoundments of the Souris River Basin refuges are vulnerable to sedimentation because of the construction of in-stream dams that interrupt and slow river flows and because of post-European settlement land-use changes that have increased the potential for soil erosion and transport to rivers. Information regarding sediments does not exist for these refuges, and U.S. Fish and Wildlife Service personnel have expressed interest in assessing refuge impoundments to support refuge management decisions. Sediment cores and surface sediment samples were collected from impoundments within Des Lacs, Upper Souris, and J. Clark Salyer National Wildlife Refuges during 2004–05. Cores were used to estimate sediment accretion rates using radioisotope (cesium-137 [137Cs], lead-210 [210Pb]) dating techniques. Sediment cores and surface samples were analyzed for a suite of elements and agrichemicals, respectively. Examination of core characteristics along the depth profile suggests that there has been regular sediment mixing and removal, as well as non-uniform sediment deposition with time. Estimated mean accretion rates based on the three methods of determination (two time markers for 137Cs, 210Pb) ranged from 0.22–0.35 centimeters per year, and approximately 70 percent of cores had less 137Cs than expected. Concentrations of sediment-associated elements generally were within reported reference ranges, and all agrichemicals analyzed were below detection limits. Results suggest that there does not appear to be widespread sediment accumulation in impoundments of the Souris River Basin refuges. In addition, there were no identifiable patterns among sedimentation rates from the upstream (Des Lacs, Upper Souris) to the downstream (J. Clark Salyer) refuges. There were, however, apparent upstream to downstream patterns of increased concentrations of some elements (for example, aluminum, boron, and vanadium) that may warrant further exploration. Future related monitoring and research efforts should focus on areas with high potential for sediment accumulation, such as upstream areas adjacent to dams, to identify potential sediment problems before they become too severe. Further, assessments of suspended sediments transported in the Des Lacs and Souris Rivers would augment interpretation of sedimentation data by identifying potential sediment sources and areas with the greatest potential for accumulation.

Raccoons (Procyon lotor) as Sentinels of Trace Element Contamination and Physiological Effects of Exposure to Coal Fly Ash

DOE PAGES

Hernandez, Felipe; Oldenkamp, Ricki E.; Webster, Sarah; ...

2016-12-08

Anthropogenic pollutants disrupt global biodiversity, and terrestrial sentinels of pollution can provide a warning system for ecosystem-wide contamination. This study sought to assess whether raccoons (Procyon lotor) are sentinels of local exposure to trace element contaminants at a coal fly ash site and whether exposure resulted in health impairment or changes in the intestinal helminth communities. We compared trace element accumulation and the impact on health responses and intestinal helminth communities of raccoons inhabiting contaminated and reference sites of the U.S. Department of Energy’s Savannah River Site (South Carolina, USA). Data on morphometry, hematology, histopathology, helminth community and abundance, andmore » liver trace element burdens were collected from 15 raccoons captured adjacent to a coal fly ash basin and 11 raccoons from a comparable uncontaminated site nearby. Of eight trace elements analyzed, Cu, As, Se, and Pb were elevated in raccoons from the contaminated site. Raccoons from the contaminated site harbored higher helminth abundance than animals from the reference site and that abundance was positively associated with increased Cu concentrations. While we found changes in hematology associated with increased Se exposure, we did not find physiological or histological changes associated with higher levels of contaminants. Our results suggest that raccoons and their intestinal helminths act as sentinels of trace elements in the environment associated with coal fly ash contamination.« less

Cycling of oxyanion-forming trace elements in groundwaters from a freshwater deltaic marsh

NASA Astrophysics Data System (ADS)

Telfeyan, Katherine; Breaux, Alexander; Kim, Jihyuk; Kolker, Alexander S.; Cable, Jaye E.; Johannesson, Karen H.

2018-05-01

Pore waters and surface waters were collected from a freshwater system in southeastern Louisiana to investigate the geochemical cycling of oxyanion-forming trace elements (i.e., Mo, W, As, V). A small bayou (Bayou Fortier) receives input from a connecting lake (Lac des Allemands) and groundwater input at the head approximately 5 km directly south of the Mississippi River. Marsh groundwaters exchange with bayou surface water but are otherwise relatively isolated from outside hydrologic forcings, such as tides, storms, and effects from local navigation canals. Rather, redox processes in the marsh groundwaters appear to drive changes in trace element concentrations. Elevated dissolved S(-II) concentrations in marsh groundwaters suggest greater reducing conditions in the late fall and winter as compared to the spring and late summer. The data suggest that reducing conditions in marsh groundwaters initiate the dissolution of Fe(III)/Mn(IV) oxide/hydroxide minerals, which releases adsorbed and/or co-precipitated trace elements into solution. Once in solution, the fate of these elements is determined by complexation with aqueous species and precipitation with iron sulfide minerals. The trace elements remain soluble in the presence of Fe(III)- and SO42-- reducing conditions, suggesting that either kinetic limitations or complexation with aqueous ligands obfuscates the correlation between V and Mo sequestration in sediments with reducing or euxinic conditions.