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Sample records for rotational liquid drop

  1. On the Poincaré instability of a rotating liquid drop

    NASA Astrophysics Data System (ADS)

    Ivanyuk, F. A.; Pomorski, K.

    2013-05-01

    The stability of a rotating nuclear liquid drop against pear-like deformations is studied within the optimal shape theory of Strutinsky et al (1963 Nucl. Phys. 46 639). It is found that such a break-up of reflection symmetric shapes appears in light nuclei at high angular momenta when non-axial degrees of freedom are taken into account.

  2. Axisymmetric Liquid Hanging Drops

    ERIC Educational Resources Information Center

    Meister, Erich C.; Latychevskaia, Tatiana Yu

    2006-01-01

    The geometry of drops hanging on a circular capillary can be determined by numerically solving a dimensionless differential equation that is independent on any material properties, which enables one to follow the change of the height, surface area, and contact angle of drops hanging on a particular capillary. The results show that the application…

  3. On the Stability of Rotating Drops

    PubMed Central

    Nurse, A. K.; Coriell, S. R.; McFadden, G. B.

    2015-01-01

    We consider the equilibrium and stability of rotating axisymmetric fluid drops by appealing to a variational principle that characterizes the equilibria as stationary states of a functional containing surface energy and rotational energy contributions, augmented by a volume constraint. The linear stability of a drop is determined by solving the eigenvalue problem associated with the second variation of the energy functional. We compute equilibria corresponding to both oblate and prolate shapes, as well as toroidal shapes, and track their evolution with rotation rate. The stability results are obtained for two cases: (i) a prescribed rotational rate of the system (“driven drops”), or (ii) a prescribed angular momentum (“isolated drops”). For families of axisymmetric drops instabilities may occur for either axisymmetric or non-axisymmetric perturbations; the latter correspond to bifurcation points where non-axisymmetric shapes are possible. We employ an angle-arc length formulation of the problem which allows the computation of equilibrium shapes that are not single-valued in spherical coordinates. We are able to illustrate the transition from spheroidal drops with a strong indentation on the rotation axis to toroidal drops that do not extend to the rotation axis. Toroidal drops with a large aspect ratio (major radius to minor radius) are subject to azimuthal instabilities with higher mode numbers that are analogous to the Rayleigh instability of a cylindrical interface. Prolate spheroidal shapes occur if a drop of lower density rotates within a denser medium; these drops appear to be linearly stable. This work is motivated by recent investigations of toroidal tissue clusters that are observed to climb conical obstacles after self-assembly [Nurse et al., Journal of Applied Mechanics 79 (2012) 051013]. PMID:26958440

  4. Liquid drops on soft solids

    NASA Astrophysics Data System (ADS)

    Lubbers, Luuk A.; Weijs, Joost H.; Das, Siddhartha; Botto, Lorenzo; Andreotti, Bruno; Snoeijer, Jacco H.

    2014-03-01

    A sessile drop can elastically deform a substrate by the action of capillary forces. The typical size of the deformation is given by the ratio of surface tension and the elastic modulus, γ / E , which can reach up to 10-100 microns for soft elastomers. In this talk we theoretically show that the contact angles of drops on such a surface exhibit two transitions when increasing γ / E : (i) the microsocopic geometry of the contact line first develops a Neumann-like cusp when γ / E is of the order of few nanometers, (ii) the macroscopic angle of the drop is altered only when γ / E reaches the size of the drop. Using the same framework we then show that two neighboring drops exhibit an effective interaction, mediated by the deformation of the elastic medium. This is in analogy to the well-known Cheerios effect, where small particles at a liquid interface attract each other due to the meniscus deformations. Here we reveal the nature of drop-drop interactions on a soft substrate by combining numerical and analytical calculations.

  5. Magnetically focused liquid drop radiator

    DOEpatents

    Botts, Thomas E.; Powell, James R.; Lenard, Roger

    1986-01-01

    A magnetically focused liquid drop radiator for application in rejecting rgy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

  6. Magnetically focused liquid drop radiator

    DOEpatents

    Botts, T.E.; Powell, J.R.; Lenard, R.

    1984-12-10

    A magnetically focused liquid drop radiator for application in rejecting energy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

  7. The dynamics of free liquid drops

    NASA Technical Reports Server (NTRS)

    Wang, T. G.; Trinh, E. H.; Croonquist, A. P.; Elleman, D. D.

    1988-01-01

    The behavior of rotating and oscillating free liquid drops was studied by many investigators theoretically for many years. More recent numerical treatments have yielded predictions which are yet to be verified experimentally. The purpose is to report the results of laboratory work as well as that of the experiments carried out in space during the flight of Spacelab 3, and to compare it with the existing theoretical studies. Ground-based experiments were attempted as a first approximation to the ideal boundary conditions used by the theoretical treatments by neutralizing the overwhelming effects of the Earth's gravitational field with an outside supporting liquid and with the use of levitation technology. The viscous and inertial loading of such a suspending fluid was found to profoundly effect the results, but the information thus gathered has emphasized the uniqueness of the experimental data obtained in the low-gravity environment of space.

  8. Leidenfrost drops on a heated liquid pool

    NASA Astrophysics Data System (ADS)

    Maquet, L.; Sobac, B.; Darbois-Texier, B.; Duchesne, A.; Brandenbourger, M.; Rednikov, A.; Colinet, P.; Dorbolo, S.

    2016-09-01

    We show that a volatile liquid drop placed at the surface of a nonvolatile liquid pool warmer than the boiling point of the drop can be held in a Leidenfrost state even for vanishingly small superheats. Such an observation points to the importance of the substrate roughness, negligible in the case considered here, in determining the threshold Leidenfrost temperature. A theoretical model based on the one proposed by Sobac et al. [Phys. Rev. E 90, 053011 (2014), 10.1103/PhysRevE.90.053011] is developed in order to rationalize the experimental data. The shapes of the drop and of the liquid substrate are analyzed. The model notably provides scalings for the vapor film thickness profile. For small drops, these scalings appear to be identical to the case of a Leidenfrost drop on a solid substrate. For large drops, in contrast, they are different, and no evidence of chimney formation has been observed either experimentally or theoretically in the range of drop sizes considered in this study. Concerning the evaporation dynamics, the radius is shown to decrease linearly with time whatever the drop size, which differs from the case of a Leidenfrost drop on a solid substrate. For high superheats, the characteristic lifetime of the drops versus the superheat follows a scaling law that is derived from the model, but, at low superheats, it deviates from this scaling by rather saturating.

  9. Electro-hydrodynamic propulsion of counter-rotating Pickering drops

    NASA Astrophysics Data System (ADS)

    Dommersnes, P.; Mikkelsen, A.; Fossum, J. O.

    2016-07-01

    Insulating particles or drops suspended in carrier liquids may start to rotate with a constant frequency when subjected to a uniform DC electric field. This is known as the Quincke rotation electro-hydrodynamic instability. A single isolated rotating particle exhibit no translational motion at low Reynolds number, however interacting rotating particles may move relative to one another. Here we present a simple system consisting of two interacting and deformable Quincke rotating particle covered drops, i.e. deformable Pickering drops. The drops attract one another and spontaneously form a counter-rotating pair that exhibits electro-hydrodynamic driven propulsion at low Reynolds number flow.

  10. Spreading dynamics of superposed drops of two liquids on a spinning disk

    NASA Astrophysics Data System (ADS)

    Sahoo, Subhadarshinee; Orpe, Ashish; Doshi, Pankaj

    2016-11-01

    We have experimentally studied simultaneous spreading of two liquid drops, one engulfing the other, when rotated atop a horizontal spinning disk using flow visualization technique. A drop of high surface tension liquid is placed centrally on a horizontal disk followed by a drop of second liquid placed exactly above the first. The second liquid, of higher volume, lower surface tension and lower density than the first, engulfs the first drop completely. The disk is then rotated at a desired speed for a range of volume ratios of two liquids. The spreading behavior of both the drops is captured using a high speed camera. Such an arrangement of two liquids drops does not affect the spreading behavior of the outer liquid, but influences that of the inner liquid significantly. The drop spreads to a larger extent and breaks into more fingers as compared to the case where the same liquid is spreading in the absence of outer liquid. The fingering instability is achieved at earlier times with decreasing volume ratios, indicative of the increasing influence of the edge of outer liquid film being closer to that of the inner liquid. Further, sustained rotation of the disk leads to emanation of drops from the spreading drop travelling outwards through the fingers of outer liquid.

  11. Rotation of ultrasonically levitated glycerol drops

    NASA Technical Reports Server (NTRS)

    Biswas, A.; Leung, E. W.; Trinh, E. H.

    1991-01-01

    Ultrasonic levitation is used to suspend single millimeter-size glycerol drops in a rectangular chamber. Audio-frequency laterally standing waves set up in the chamber are used to torque the suspended drops. The shape evolution of the drop under the combined effect of centrifugal forces and the acoustic radiation stress, along with its angular velocity are monitored, using video imaging and light scattering techniques. The results show good qualitative agreement with the theoretically predicted shape evolution as a function of angular velocity.

  12. Spreading of liquid drops over porous substrates.

    PubMed

    Starov, V M; Zhdanov, S A; Kosvintsev, S R; Sobolev, V D; Velarde, M G

    2003-07-01

    The spreading of small liquid drops over thin and thick porous layers (dry or saturated with the same liquid) has been investigated in the case of both complete wetting (silicone oils of different viscosities) and partial wetting (aqueous SDS solutions of different concentrations). Nitrocellulose membranes of different porosity and different average pore size have been used as a model of thin porous layers, glass and metal filters have been used as a model of thick porous substrates. The first problem under investigation has been the spreading of small liquid drops over thin porous layers saturated with the same liquid. An evolution equation describing the drop spreading has been deduced, which showed that both an effective lubrication and the liquid exchange between the drop and the porous substrates are equally important. Spreading of silicone oils over different nitrocellulose microfiltration membranes was carried out. The experimental laws of the radius of spreading on time confirmed the theory predictions. The spreading of small liquid drops over thin dry porous layers has also been investigated from both theoretical and experimental points of view. The drop motion over a dry porous layer appears caused by the interplay of two processes: (a). the spreading of the drop over already saturated parts of the porous layer, which results in a growth of the drop base, and (b). the imbibition of the liquid from the drop into the porous substrate, which results in a shrinkage of the drop base and a growth of the wetted region inside the porous layer. As a result of these two competing processes the radius of the drop base goes through a maximum as time proceeds. A system of two differential equations has been derived to describe the time evolution of the radii of both the drop base and the wetted region inside the porous layer. This system includes two parameters, one accounts for the effective lubrication coefficient of the liquid over the wetted porous substrate, and

  13. Micro coulometric titration in a liquid drop.

    PubMed

    Kanyanee, Tinakorn; Fuekhad, Pongwasin; Grudpan, Kate

    2013-10-15

    Miniaturized coulometric titration in a liquid drop has been investigated. Assays of ascorbic acid and thiosulfate with iodine titration were chosen as models. Constant volumes of falling liquid drops containing sample or reagent are manipulated via gravimetrical force to move along a slope hydrophobic path and directed to stop or to move out from an electrode. Such manipulation is useful for delivery of sample and reagents, in a way of flow without tubing. Electrochemical generation of titrant, in this case, iodine, is started at the electrode and micro coulometric titration can be performed in a drop by applying constant current. Timing in the titration can be made via naked eye with a stopwatch or via recording with a webcam camera connecting to a computer to detect the change due to the blue color complex of the excess iodine and starch.

  14. Ultrasonic characterization of single drops of liquids

    DOEpatents

    Sinha, Dipen N.

    1998-01-01

    Ultrasonic characterization of single drops of liquids. The present invention includes the use of two closely spaced transducers, or one transducer and a closely spaced reflector plate, to form an interferometer suitable for ultrasonic characterization of droplet-size and smaller samples without the need for a container. The droplet is held between the interferometer elements, whose distance apart may be adjusted, by surface tension. The surfaces of the interferometer elements may be readily cleansed by a stream of solvent followed by purified air when it is desired to change samples. A single drop of liquid is sufficient for high-quality measurement. Examples of samples which may be investigated using the apparatus and method of the present invention include biological specimens (tear drops; blood and other body fluid samples; samples from tumors, tissues, and organs; secretions from tissues and organs; snake and bee venom, etc.) for diagnostic evaluation, samples in forensic investigations, and detection of drugs in small quantities.

  15. Behavior Of Evaporating Liquid Drops In Clusters

    NASA Technical Reports Server (NTRS)

    Bellan, Josette

    1990-01-01

    Report presents critical analysis of methods, developed for calculating behavior of evaporating liquid drops in dense and dilute clusters. Essential to understanding variety of physical and chemical phenomena occurring in combustion of sprayed fuels and in sprays used in agriculture, food industry, and painting. Presents insights on important aspects of two-phase flow.

  16. Ground based studies of the vibrational and rotational dynamics of acoustically levitated drops and shells

    NASA Technical Reports Server (NTRS)

    Trinh, E. H.; Leung, E.

    1990-01-01

    A substantial amount of experimental data can be gathered on the dynamics of acoustically positioned liquids in a ground-based laboratory and during short duration low-gravity parabolic flights of the KC-135. The preliminary results of a set of measurements of the static shape, of the vibrational spectrum, and the rotation equilibrium shapes of simple drops and liquid shells carried out using ultrasonic levitators working between 19 and 40 kHz is presented. The droplet diameter ranges between 1 and 5 mm, the surface tension of the liquid used varies between 25 and 70 dynes/cm, and the viscosity is changed between 1 to 1,000 cP. Of particular interest is the variation of the frequency of the fundamental mode of shape oscillation with various factors, and the effects of static drop shape deformation on the limit of stability of the axisymmetric shape of a drop in solid-body rotation.

  17. Rotationally Molded Liquid Crystalline Polymers

    NASA Technical Reports Server (NTRS)

    Rogers, Martin; Scribben, Eric; Baird, Donald; Hulcher, Bruce

    2002-01-01

    Rotational molding is a unique process for producing hollow plastic parts. Rotational molding offers low cost tooling and can produce very large parts with complicated shapes. Products made by rotational molding include water tanks with capacities up to 20,000 gallons, truck bed liners, playground equipment, air ducts, Nylon fuel tanks, pipes, toys, stretchers, kayaks, pallets, and many others. Thermotropic liquid crystalline polymers are an important class of engineering resins employed in a wide variety of applications. Thermotropic liquid crystalline polymers resins are composed of semirigid, nearly linear polymeric chains resulting in an ordered mesomorphic phase between the crystalline solid and the isotropic liquid. Ordering of the rigid rod-like polymers in the melt phase yields microfibrous, self-reinforcing polymer structures with outstanding mechanical and thermal properties. Rotational molding of liquid crystalline polymer resins results in high strength and high temperature hollow structures useful in a variety of applications. Various fillers and reinforcements can potentially be added to improve properties of the hollow structures. This paper focuses on the process and properties of rotationally molded liquid crystalline polymers. This paper will also highlight the interactions between academia and small businesses in developing new products and processes.

  18. Rotationally Molded Liquid Crystalline Polymers

    NASA Technical Reports Server (NTRS)

    Rogers, Martin; Stevenson, Paige; Scribben, Eric; Baird, Donald; Hulcher, Bruce

    2002-01-01

    Rotational molding is a unique process for producing hollow plastic parts. Rotational molding offers advantages of low cost tooling and can produce very large parts with complicated shapes. Products made by rotational molding include water tanks with capacities up to 20,000 gallons, truck bed liners, playground equipment, air ducts, Nylon fuel tanks, pipes, toys, stretchers, kayaks, pallets, and many others. Thermotropic liquid crystalline polymers are an important class of engineering resins employed in a wide variety of applications. Thermotropic liquid crystalline polymers resins are composed of semi-rigid, nearly linear polymeric chains resulting in an ordered mesomorphic phase between the crystalline solid and the isotropic liquid. Ordering of the rigid rod-like polymers in the melt phase yields microfibrous, self-reinforcing polymer structures with outstanding mechanical and thermal properties. Rotational molding of liquid crystalline polymer resins results in high strength and high temperature hollow structures useful in a variety of applications. Various fillers and reinforcements can potentially be added to improve properties of the hollow structures. This paper focuses on the process and properties of rotationally molded liquid crystalline polymers.

  19. Ultrasonic characterization of single drops of liquids

    DOEpatents

    Sinha, D.N.

    1998-04-14

    Ultrasonic characterization of single drops of liquids is disclosed. The present invention includes the use of two closely spaced transducers, or one transducer and a closely spaced reflector plate, to form an interferometer suitable for ultrasonic characterization of droplet-size and smaller samples without the need for a container. The droplet is held between the interferometer elements, whose distance apart may be adjusted, by surface tension. The surfaces of the interferometer elements may be readily cleansed by a stream of solvent followed by purified air when it is desired to change samples. A single drop of liquid is sufficient for high-quality measurement. Examples of samples which may be investigated using the apparatus and method of the present invention include biological specimens (tear drops; blood and other body fluid samples; samples from tumors, tissues, and organs; secretions from tissues and organs; snake and bee venom, etc.) for diagnostic evaluation, samples in forensic investigations, and detection of drugs in small quantities. 5 figs.

  20. Drop Impact on to Moving Liquid Pools

    NASA Astrophysics Data System (ADS)

    Muñoz-Sánchez, Beatriz Natividad; Castrejón-Pita, José Rafael; Castrejón-Pita, Alfonso Arturo; Hutchings, Ian M.

    2014-11-01

    The deposition of droplets on to moving liquid substrates is an omnipresent situation both in nature and industry. A diverse spectrum of phenomena emerges from this simple process. In this work we present a parametric experimental study that discerns the dynamics of the impact in terms of the physical properties of the fluid and the relative velocity between the impacting drop and the moving liquid pool. The behaviour ranges from smooth coalescence (characterized by little mixing) to violent splashing (generation of multiple satellite droplets and interfacial vorticity). In addition, transitional regimes such as bouncing and surfing are also found. We classify the system dynamics and show a parametric diagram for the conditions of each regime. This work was supported by the EPSRC (Grant EP/H018913/1), the Royal Society, Becas Santander Universidades and the International Relationships Office of the University of Extremadura.

  1. Impact dynamics of oxidized liquid metal drops

    NASA Astrophysics Data System (ADS)

    Xu, Qin; Brown, Eric; Jaeger, Heinrich M.

    2013-04-01

    With exposure to air, many liquid metals spontaneously generate an oxide layer on their surface. In oscillatory rheological tests, this skin is found to introduce a yield stress that typically dominates the elastic response but can be tuned by exposing the metal to hydrochloric acid solutions of different concentration. We systematically studied the normal impact of eutectic gallium-indium (eGaIn) drops under different oxidation conditions and show how this leads to two different dynamical regimes. At low impact velocity (or low Weber number), eGaIn droplets display strong recoil and rebound from the impacted surface when the oxide layer is removed. In addition, the degree of drop deformation or spreading during impact is controlled by the oxide skin. We show that the scaling law known from ordinary liquids for the maximum spreading radius as a function of impact velocity can still be applied to the case of oxidized eGaIn if an effective Weber number We is employed that uses an effective surface tension factoring in the yield stress. In contrast, no influence on spreading from different oxidations conditions is observed for high impact velocity. This suggests that the initial kinetic energy is mostly damped by bulk viscous dissipation. Results from both regimes can be collapsed in an impact phase diagram controlled by two variables, the maximum spreading factor Pm=R0/Rm, given by the ratio of initial to maximum drop radius, and the impact number K=We/Re4/5, which scales with the effective Weber number We as well as the Reynolds number Re. The data exhibit a transition from capillary to viscous behavior at a critical impact number Kc≈0.1.

  2. Rotating Molten Metallic Drops and Their Applications for Surface Tension Measurements

    NASA Technical Reports Server (NTRS)

    Rhim, W. K.; Ishikawa, T.

    1998-01-01

    Shapes and stability of rotating molten metal drops carrying net surface electric charges are experimentally investigated, and the feasibility of measureing surface tension based on drop rotation is examined.

  3. Flow visualization and characterization of evaporating liquid drops

    NASA Technical Reports Server (NTRS)

    Chao, David F. (Inventor); Zhang, Nengli (Inventor)

    2004-01-01

    An optical system, consisting of drop-reflection image, reflection-refracted shadowgraphy and top-view photography, is used to measure the spreading and instant dynamic contact angle of a volatile-liquid drop on a non-transparent substrate. The drop-reflection image and the shadowgraphy is shown by projecting the images of a collimated laser beam partially reflected by the drop and partially passing through the drop onto a screen while the top view photograph is separately viewed by use of a camera video recorder and monitor. For a transparent liquid on a reflective solid surface, thermocapillary convection in the drop, induced by evaporation, can be viewed nonintrusively, and the drop real-time profile data are synchronously recorded by video recording systems. Experimental results obtained from this technique clearly reveal that evaporation and thermocapillary convection greatly affect the spreading process and the characteristics of dynamic contact angle of the drop.

  4. Nucleation of Quantized Vortices from Rotating Superfluid Drops

    NASA Technical Reports Server (NTRS)

    Donnelly, Russell J.

    2001-01-01

    The long-term goal of this project is to study the nucleation of quantized vortices in helium II by investigating the behavior of rotating droplets of helium II in a reduced gravity environment. The objective of this ground-based research grant was to develop new experimental techniques to aid in accomplishing that goal. The development of an electrostatic levitator for superfluid helium, described below, and the successful suspension of charged superfluid drops in modest electric fields was the primary focus of this work. Other key technologies of general low temperature use were developed and are also discussed.

  5. Inverse Leidenfrost Effect: Levitating Drops on Liquid Nitrogen.

    PubMed

    Adda-Bedia, M; Kumar, S; Lechenault, F; Moulinet, S; Schillaci, M; Vella, D

    2016-05-03

    We explore the interaction between a liquid drop (initially at room temperature) and a bath of liquid nitrogen. In this scenario, heat transfer occurs through film-boiling: a nitrogen vapor layer develops that may cause the drop to levitate at the bath surface. We report the phenomenology of this inverse Leidenfrost effect, investigating the effect of the drop size and density by using an aqueous solution of a tungsten salt to vary the drop density. We find that (depending on its size and density) a drop either levitates or instantaneously sinks into the bulk nitrogen. We begin by measuring the duration of the levitation as a function of the radius R and density ρd of the liquid drop. We find that the levitation time increases roughly linearly with drop radius but depends weakly on the drop density. However, for sufficiently large drops, R ≥ Rc(ρd), the drop sinks instantaneously; levitation does not occur. This sinking of a (relatively) hot droplet induces film-boiling, releasing a stream of vapor bubbles for a well-defined length of time. We study the duration of this immersed-drop bubbling finding similar scalings (but with different prefactors) to the levitating drop case. With these observations, we study the physical factors limiting the levitation and immersed-film-boiling times, proposing a simple model that explains the scalings observed for the duration of these phenomena, as well as the boundary of (R,ρd) parameter space that separates them.

  6. Oblique drop impact onto a deep liquid pool

    NASA Astrophysics Data System (ADS)

    Gielen, Marise V.; Sleutel, Pascal; Benschop, Jos; Riepen, Michel; Voronina, Victoria; Lohse, Detlef; Snoeijer, Jacco H.; Versluis, Michel; Gelderblom, Hanneke

    2016-11-01

    While perpendicular drop impact onto a deep liquid pool is widely studied, the dynamics after oblique drop impact remain to be quantified. Here we study, for the first time, oblique drop impact experiments onto a deep liquid pool using ultrafast imaging. We quantify the splashing behavior and derive a model to describe the splashing threshold based on the impact angle and Weber number of the impacting drop. In addition, we study the cavity formation below the water surface and quantify the cavity depth and displacement. Based on the asymmetric cavity dynamics, we develop a method to predict the direction in which a jetted droplet can escape the cavity.

  7. Effect of Surfactants on Drop Coalescence at Liquid/liquid Interfaces

    NASA Astrophysics Data System (ADS)

    Weheliye, Weheliye Hashii; Dong, Teng; Angeli, Panagiota

    2016-11-01

    In this paper the coalescence of a drop with a liquid-liquid interface was investigated experimentally using Particle Image Velocimetry (PIV). Initially the drop rest on the interface was studied. It was found that during drop rest the interface deformed before rupture, and the deformation increased with increasing surfactant concentration. The results from PIV showed that two counter-rotating vortices formed inside the droplet during the rupture process which moved from the bottom to the top of the drop. The evolutions of vortices for three surfactant concentrations will be presented. The vortices moved faster in lower surfactant concentrations compared to the higher ones. The intensities of the vortices in different concentrations were also calculated. After the rupture, for low surfactant concentrations, the intensities increased with time and reached a maximum while at later times they decreased. At high surfactant concentrations, the increase and subsequent decrease in intensity was not as pronounced. The work is support by the MEMPHIS program and the University College London. The author Teng Dong would like to thank the Chinese Scholarship Council (CSC) for providing funds for his overseas research.

  8. Initiation of liquid-solid contact beneath an impacting drop

    NASA Astrophysics Data System (ADS)

    Rubinstein, Shmuel; Kolinski, John

    2015-11-01

    Before an impacting drop contacts the solid surface it must first drain the air beneath it. As a prelude to wetting, before any contact occurs, the impinging liquid confines the intervening air into a nanometers-thin film. Once liquid-solid contact initiates by the spontaneous formation of a liquid bridge, the fluid rapidly wicks through the thin film of air, permanently binding the drop to the surface. Here, we experimentally examine these initial stages in the formation of the liquid solid contact beneath the impacting drop. Fast TIR microscopy enables unprecedented spatial and temporal resolution of the wetting process beneath the impacting drop and permits 3-dimensional imaging of the real contact line as well as nanometer-resolution of the thin film of air separating the liquid from the solid.

  9. Scaling of liquid-drop impact craters in granular media

    NASA Astrophysics Data System (ADS)

    Zhao, Runchen; Zhang, Qianyun; Tjugito, Hendro; Gao, Ming; Cheng, Xiang

    Granular impact cratering by liquid drops is a ubiquitous phenomenon, directly relevant to many important natural and industrial processes such as soil erosion, drip irrigation, and dispersion of micro-organisms in soil. Here, by combining the high-speed photography with high precision laser profilometry, we investigate the liquid-drop impact dynamics on granular surfaces and monitor the morphology of resulting craters. Our experiments reveal novel scaling relations between the size of granular impact craters and important control parameters including the impact energy, the size of impinging drops and the degree of liquid saturation in a granular bed. Interestingly, we find that the scaling for liquid-drop impact cratering in dry granular media can be quantitatively described by the Schmidt-Holsapple scaling originally proposed for asteroid impact cratering. On the other hand, the scaling for impact craters in wet granular media can be understood by balancing the inertia of impinging drops and the strength of impacted surface. Our study sheds light on the mechanism governing liquid-drop impacts on dry/wet granular surfaces and reveals a remarkable analogy between familiar phenomena of raining and catastrophic asteroid strikes. Scaling of liquid-drop impact craters in granular media.

  10. Electrically rotating suspended films of polar liquids

    NASA Astrophysics Data System (ADS)

    Shirsavar, R.; Amjadi, A.; Tonddast-Navaei, A.; Ejtehadi, M. R.

    2011-02-01

    Controlled rotation of a suspended soap water film, simply generated by applying an electric field, has been reported recently. The film rotates when the applied electric field exceeds a certain threshold. In this study, we investigate the phenomenon in films made of a number of other liquids with various physical and chemical properties. Our measurements show that the intrinsic electrical dipole moments of the liquid molecules seems to be vital for the corresponding film rotation. All the investigated rotating liquids have a molecular electric dipole moment of above 1 Debye, while weakly polar liquids do not rotate. However, the liquids investigated here cover a wide range of physical parameters (e.g. viscosity, density, conductivity, etc.). So far, no significant correlation has been observed between the electric field thresholds and macroscopic properties of the liquids.

  11. Ultrasonic atomization of liquids in drop-chain acoustic fountains.

    PubMed

    Simon, Julianna C; Sapozhnikov, Oleg A; Khokhlova, Vera A; Crum, Lawrence A; Bailey, Michael R

    2015-03-01

    When focused ultrasound waves of moderate intensity in liquid encounter an air interface, a chain of drops emerges from the liquid surface to form what is known as a drop-chain fountain. Atomization, or the emission of micro-droplets, occurs when the acoustic intensity exceeds a liquid-dependent threshold. While the cavitation-wave hypothesis, which states that atomization arises from a combination of capillary-wave instabilities and cavitation bubble oscillations, is currently the most accepted theory of atomization, more data on the roles of cavitation, capillary waves, and even heat deposition or boiling would be valuable. In this paper, we experimentally test whether bubbles are a significant mechanism of atomization in drop-chain fountains. High-speed photography was used to observe the formation and atomization of drop-chain fountains composed of water and other liquids. For a range of ultrasonic frequencies and liquid sound speeds, it was found that the drop diameters approximately equalled the ultrasonic wavelengths. When water was exchanged for other liquids, it was observed that the atomization threshold increased with shear viscosity. Upon heating water, it was found that the time to commence atomization decreased with increasing temperature. Finally, water was atomized in an overpressure chamber where it was found that atomization was significantly diminished when the static pressure was increased. These results indicate that bubbles, generated by either acoustic cavitation or boiling, contribute significantly to atomization in the drop-chain fountain.

  12. Ultrasonic atomization of liquids in drop-chain acoustic fountains

    PubMed Central

    Simon, Julianna C.; Sapozhnikov, Oleg A.; Khokhlova, Vera A.; Crum, Lawrence A.; Bailey, Michael R.

    2015-01-01

    When focused ultrasound waves of moderate intensity in liquid encounter an air interface, a chain of drops emerges from the liquid surface to form what is known as a drop-chain fountain. Atomization, or the emission of micro-droplets, occurs when the acoustic intensity exceeds a liquid-dependent threshold. While the cavitation-wave hypothesis, which states that atomization arises from a combination of capillary-wave instabilities and cavitation bubble oscillations, is currently the most accepted theory of atomization, more data on the roles of cavitation, capillary waves, and even heat deposition or boiling would be valuable. In this paper, we experimentally test whether bubbles are a significant mechanism of atomization in drop-chain fountains. High-speed photography was used to observe the formation and atomization of drop-chain fountains composed of water and other liquids. For a range of ultrasonic frequencies and liquid sound speeds, it was found that the drop diameters approximately equalled the ultrasonic wavelengths. When water was exchanged for other liquids, it was observed that the atomization threshold increased with shear viscosity. Upon heating water, it was found that the time to commence atomization decreased with increasing temperature. Finally, water was atomized in an overpressure chamber where it was found that atomization was significantly diminished when the static pressure was increased. These results indicate that bubbles, generated by either acoustic cavitation or boiling, contribute significantly to atomization in the drop-chain fountain. PMID:25977591

  13. Acoustic forcing of a liquid drop

    NASA Technical Reports Server (NTRS)

    Lyell, M. J.

    1992-01-01

    The development of systems such as acoustic levitation chambers will allow for the positioning and manipulation of material samples (drops) in a microgravity environment. This provides the capability for fundamental studies in droplet dynamics as well as containerless processing work. Such systems use acoustic radiation pressure forces to position or to further manipulate (e.g., oscillate) the sample. The primary objective was to determine the effect of a viscous acoustic field/tangential radiation pressure forcing on drop oscillations. To this end, the viscous acoustic field is determined. Modified (forced) hydrodynamic field equations which result from a consistent perturbation expansion scheme are solved. This is done in the separate cases of an unmodulated and a modulated acoustic field. The effect of the tangential radiation stress on the hydrodynamic field (drop oscillations) is found to manifest as a correction to the velocity field in a sublayer region near the drop/host interface. Moreover, the forcing due to the radiation pressure vector at the interface is modified by inclusion of tangential stresses.

  14. Partial coalescence of sessile drops with different liquids

    NASA Astrophysics Data System (ADS)

    Borcia, Rodica; Bestehorn, Michael

    2014-11-01

    We examine numerically the interaction between two deformable drops consisting of two perfectly miscible liquids sitting on a solid substrate under a given contact angle. Driven by solutal Marangoni forces, several distinct coalescence regimes are achieved after the droplets collision. Phase diagrams for different control parameters are emphasized, which give predictions about drop behavior along the solid substrates, control of various interfacial effects, manipulations of tiny droplets in micro- and nano-fluidic devices without power supply, design of droplets or cleaning surfaces. This work was partially supported by Deutsche Forschungsgemeinschaft (DFG) under the project ``Dynamics of interfaces between drops with miscible liquids''.

  15. Liquid drops on vertical and inclined surfaces; I. An experimental study of drop geometry.

    PubMed

    ElSherbini, A I; Jacobi, A M

    2004-05-15

    Experiments have been conducted to investigate the geometric parameters necessary to describe the shapes of liquid drops on vertical and inclined plane surfaces. Two liquids and eight surfaces have been used to study contact angles, contact lines, profiles, and volumes of drops of different sizes for a range of surface conditions. The results show the contact-angle variation along the circumference of a drop to be best fit by a third-degree polynomial in the azimuthal angle. This contact-angle function is expressed in terms of the maximum and minimum contact angles of the drop, which are determined for various conditions. The maximum contact angle, thetamax, is approximately equal to the advancing contact angle, thetaA, of the liquid on the surface. As the Bond number, Bo, increases from 0 to a maximum, the minimum contact angle, thetamin, decreases almost linearly from the advancing to the receding angle. A general relation is found between thetamin/thetaA and Bo for different liquid-surface combinations. The drop contour can be described by an ellipse, with the aspect ratio increasing with Bo. These experimental results are valuable in modeling drop shape, as presented in Part II of this work.

  16. Rotating Molten Metallic Drops and Related Phenomena: A New Approach to the Surface Tension Measurement

    NASA Technical Reports Server (NTRS)

    Rhim, Won-Kyu; Ishikawa, Takehiko

    2000-01-01

    Molten aluminum and tin drops were levitated in a high vacuum by controlled electric fields, and they were systematically rotated by applying by a rotating magnetic field. When the evolution of the drop shape was measured as a function of rotation frequency, it agreed quantitatively well with the Brown and Scriven's theoretical prediction. The normalized rotation frequencies at the bifurcation point agreed with the predicted value 0.559, within 2%. An anomalous phenomenon which totally deviated from the prediction was observed in rotating molten tin drops when they were kept in a high rotation rate for several hours. No anomaly was observed in aluminum drops when they underwent similar condition. It was speculated that under the strong centrifugal force in the drop the tin isotopes must be separating. Since Al-27 is essentially the only naturally abundant isotope in the aluminum drops, the same anomaly is not expected. Based on the shape deformation of a rotating drop, an alternate approach to the surface tension measurement was verified. This new surface tension measurement technique was applied to a glassforming alloy, Zr(41.2)Ti(13.8)Cu(12.5)Ni(10.0)Be(22.5) in its highly viscous states. Also demonstrated in the paper was a use of a molten aluminum drop to verify the Busse's prediction of the influence of the drop rotation on the drop oscillation frequency.

  17. A comparative flow visualization study of thermocapillary flow in drops in liquid-liquid systems

    NASA Technical Reports Server (NTRS)

    Balasubramaniam, R.; Rashidnia, N.

    1991-01-01

    Experiments are performed to visualize thermocapillary flow in drops in an immiscible host liquid. The host liquid used is silicone oil. Drops of three different liquids are used, viz, vegetable oil, water-methanol mixture anad pure methanol. Clear evidence of thermocapillary flow is seen in vegetable oil drops. For a mixture of water and methanol (approximately 50-50 by weight), natural convection is seen to dominate the flow outside the drop. Pure methanol drops exhibit thermocapillary flow, but dissolve in silicone oil. A small amount of water added to pure methanol significantly reduces the dissolution. Flow oscillations occur in this system for both isothermal and non-isothermal conditions.

  18. Drop interaction with solid boundaries in liquid/liquid systems

    NASA Astrophysics Data System (ADS)

    Bordoloi, Ankur Deep

    The present experimental work was motivated primarily by the CO 2 sequestration process. In a possible scenario during this process, gravity driven CO2 bubbles coalesce at an interface near the rock surface. In another scenario, trapped CO2 fluid may escape from a porous matrix overcoming interfacial force inside a pore. Based on these potential scenarios, the current research was divided into two broad experimental studies. In the first part, coalescence at a quiescent interface of two analogous fluids (silicone oil and water/glycerin mixture) was investigated for water/glycerin drops with Bond number (Bo) ~7 and Ohnesorge number ~ 0.01 using high-speed imaging and time-resolved tomographic PIV. Two perturbation cases with a solid particle wetted in oil and water/glycerin placed adjacent to the coalescing drop were considered. The results were compared with coalescence of a single drop and that of a drop neighBored by a second drop of equivalent size. Each perturbing object caused an initial tilting of the drop, influencing its rupture location, subsequent film retraction and eventual collapse behavior. Once tilted, drops typically ruptured near their lowest vertical position which was located either toward or away from the perturbing object depending on the case. The trends in local retraction speed of the ruptured film and the overall dynamics of the collapsing drops were discussed in detail. In the second part, the motion of gravity driven drops (B o~0.8-11) through a confining orifice d/D<1) was studied using high speed imaging and planar PIV. Drops of water/glycerin, surrounded by silicone oil, fall toward and encounter the orifice plate after reaching terminal speed. The effects of surface wettability were investigated for Both round-edged and sharp-edged orifices. For the round-edged case, a thin film of surrounding oil prevented the drop fluid from contacting the orifice surface, such that the flow outcomes of the drops were independent of surface

  19. Thermally Driven Oscillations and Wave Motion of a Liquid Drop

    NASA Technical Reports Server (NTRS)

    Baumeister, K. J.; Hendricks, R. C.; Schoessow, G. J.

    1977-01-01

    In the state of Leidenfrost boiling, liquid drops are observed to vibrate in a variety of modal patterns. Theories are presented which predict the frequency of oscillation and show that the observed model patterns of drops correspond to the minimum energy oscillatory excitation state. High-speed photographic techniques were used to record these motions and substantiate the theories. An incipient temperature was also found for water drops in film boiling below which free oscillations do not exist. In addition to these oscillations, photographic sequences are presented which show that wave motion can exist along the circumference of the drop. Following the study of free oscillations, the system was mounted on a shaker table and the drop subjected to a range of forced frequencies and accelerations.

  20. Liquid-film coating on topographically patterned rotating cylinders

    NASA Astrophysics Data System (ADS)

    Li, Weihua; Carvalho, Marcio S.; Kumar, Satish

    2017-02-01

    The coating of discrete objects having surface topography is an important step in the manufacturing of a broad variety of products. To develop a fundamental understanding of this problem, we study liquid-film flow on rotating cylinders patterned with sinusoidal topographical features. The Stokes equations, augmented with a term accounting for centrifugal forces, are solved in a rotating reference frame using the Galerkin finite-element method (GFEM). A nonlinear evolution equation for the film thickness based on lubrication theory is also solved numerically and its predictions are compared to those from the GFEM calculations. When gravitational effects are negligible and the rotation rate is sufficiently low, liquid accumulates over the pattern troughs before merging to form multiple larger drops (located over troughs) whose number at steady state depends on the topography wavelength and rotation rate. When the rotation rate is sufficiently high, similar merging events occur, but liquid accumulates over the pattern crests at steady state. When gravitational forces become significant, it is possible to obtain a coating that closely conforms to the surface topography. The GFEM calculations are in agreement with predictions from the lubrication model provided the free-surface curvatures are sufficiently small. For sufficiently large pattern amplitude and film thickness, the GFEM calculations show that recirculation regions inside the troughs can appear and vanish as the cylinder rotates due to the variation of gravitational forces around the cylinder surface. This phenomenon, along with flow reversal over the crests, may strongly influence mixing, mass transport, and heat transport.

  1. Symmetric drop coalescence on an under-liquid substrate.

    PubMed

    Mitra, Surjyasish; Mitra, Sushanta K

    2015-09-01

    We have derived a modified one-dimensional lubrication equation to describe the early coalescence behavior of a symmetric sessile drop coalescence for under-liquid substrates, which takes into account the viscosities of both the drop and the surrounding medium. We found a time scale, which governs the process, and there exists a crossover time between the universal scaling of the bridge height growth h^{*}∼t^{*} (valid for both under-liquid and air) and a much slower bridge growth h^{*}∼t^{*}^{0.24} occurring at a later time. It is also found that the drop coalescence bridge profile has a self-similarity, which breaks up much earlier for under-liquid substrates as opposed to symmetric coalescence in air.

  2. Liquid drop spreading on surfaces: Initial regimes revisited

    NASA Astrophysics Data System (ADS)

    Mitra, Surjyasish; Mitra, Sushanta

    2016-11-01

    Liquid drop spreading on a given surface is fundamental towards technological processes like coating and paints, inkjet printing, surface characterization, etc. Though, the underlying dynamics is well understood, we have revisited this problem through experiments conducted on surfaces kept in air as well as immersed in water. It was found that the two key parameters that dictated the spreading process were drop-surrounding medium viscosity ratio and the characteristic viscous length scale. It was observed that irrespective of the drop liquid and surrounding liquid medium (air and water in this case), spreading always began in a regime dominated by drop viscosity, where the spreading radius scales as r t . However, the prefactor of the scaling observed was different for air (of the order of unity) and under-water (much less than unity). Following this initial regime, a second intermediate regime dominated by drop inertia (typically found for water drops spreading in air) was observed only when the characteristic viscous length scale favored such a transition. In this regime as well, a non-universal prefactor was noted for the scaling law, i.e., r t1/2. In all cases considered, the spreading process terminated in the Tanner's regime where the spreading radius scaled as r t1/10.

  3. Liquid drop impact cratering on a granular layer

    NASA Astrophysics Data System (ADS)

    Katsuragi, H.

    2010-12-01

    Granular impact cratering has been studied both in terms of planetary science and fundamental granular physics. Recent studies have revealed morphological scaling and dynamics of the granular impact cratering phenomenon. In all these studies, solid impactors have been used. However, the actual geophysical scale impactors might be melt. To mimic what happens when the impactor is melt, we performed simple drop granular impact experiment. A small (millimeter scale) water drop was dropped onto a granular layer (abrasives of micrometer grain size) at low impact speed (about meter/second). Then, various kinds of novel crater shapes were discovered depending on the experimental conditions. For instance, "sink type", "flat type", "ring type", and "bump type" craters were observed. We measured the characteristic time scale and length scale of the cratering, using a high speed camera and a laser profilometry system. From the experimental data, a simple scaling of the crater radius is proposed. The obtained scaling exponent is same as that of usual solid impact cratering. In the solid impactor case, the scaling exponent is derived from energy balance between impactor and ejecta. However, we found that the liquid drop deformation determines the scaling exponent in this experiment. We have also used glycerol and ethanol and their aqueous solutions, in order to examine the effect of viscosity and capillary force of liquid drops. A picture of the impacting drop is shown below. A water drop impacting onto a layer of abrasive.

  4. A liquid drop model for embedded atom method cluster energies

    NASA Technical Reports Server (NTRS)

    Finley, C. W.; Abel, P. B.; Ferrante, J.

    1996-01-01

    Minimum energy configurations for homonuclear clusters containing from two to twenty-two atoms of six metals, Ag, Au, Cu, Ni, Pd, and Pt have been calculated using the Embedded Atom Method (EAM). The average energy per atom as a function of cluster size has been fit to a liquid drop model, giving estimates of the surface and curvature energies. The liquid drop model gives a good representation of the relationship between average energy and cluster size. As a test the resulting surface energies are compared to EAM surface energy calculations for various low-index crystal faces with reasonable agreement.

  5. Liquid-drop-like model for cylindrical helium systems

    NASA Astrophysics Data System (ADS)

    Szybisz, Leszek

    2000-08-01

    Free liquid 4He at T=0 K with cylindrical symmetry is studied. The ground-state energy and chemical potential are computed by using a density functional approach. A liquid-drop-like model is formulated for analyzing the behavior of these observables as a function of the size of the systems. It is shown that such a model allows to get precise information about the asymptotic values of the energy per particle and surface tension.

  6. Drop impact on thin liquid films using TIRM

    NASA Astrophysics Data System (ADS)

    Pack, Min; Ying Sun Team

    2015-11-01

    Drop impact on thin liquid films is relevant to a number of industrial processes such as pesticide spraying and repellent surface research such as self-cleaning applications. In this study, we systematically investigate the drop impact dynamics on thin liquid films on plain glass substrates by varying the film thickness, viscosity and impact velocity. High speed imaging is used to track the droplet morphology and trajectory over time as well as observing instability developments at high Weber number impacts. Moreover, the air layer between the drop and thin film upon drop impact is probed by total internal reflection microscopy (TIRM) where the grayscale intensity is used to measure the air layer thickness and spreading radius over time. For low We impact on thick films (We ~ 10), the effect of the air entrainment is pronounced where the adhesion of the droplet to the wall is delayed by the air depletion and liquid film drainage, whereas for high We impact (We >100) the air layer is no longer formed and instead, the drop contact with the wall is limited only to the film drainage for all film thicknesses. In addition, the maximum spreading radius of the droplet is analyzed for varying thin film thickness and viscosity.

  7. Drop impact on liquid film: dynamics of interfacial gas layer

    NASA Astrophysics Data System (ADS)

    Tang, Xiaoyu; Saha, Abhishek; Law, Chung K.; Sun, Chao

    2016-11-01

    Drop impacting liquid film is commonly observed in many processes including inkjet printing and thermal sprays. Owing to the resistance from the interfacial gas layer trapped between the drop and film surface, impact may not always result in coalescence; and as such investigating the behavior of the interfacial gas layer is important to understand the transition between bouncing and merging outcomes. The gas layer is, however, not easily optically accessible due to its microscopic scale and curved interfaces. We report the measurement of this critical gas layer thickness between two liquid surfaces using high-speed color interferometry capable of measuring micron and submicron thicknesses. The complete gas layer dynamics for the bouncing cases can be divided into two stages: the approaching stage when the drop squeezes the gas layer at the beginning of the impact, and the rebounding stage when the drop retracts and rebounds from the liquid film. The approaching stage is found to be similar across wide range of conditions studied. However, for the rebounding stage, with increase of liquid film thickness, the evolution of gas layer changes dramatically, displaying a non-monotonic behavior. Such dynamics is analyzed in lights of various competing timescales.

  8. Trapped liquid drop at the end of capillary.

    PubMed

    Wang, Zhengjia; Yen, Hung-Yu; Chang, Cheng-Chung; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2013-10-01

    The liquid drop captured at the capillary end, which is observed in capillary valve and pendant drop technique, is investigated theoretically and experimentally. Because of contact line pinning of the lower meniscus, the lower contact angle is able to rise from the intrinsic contact angle (θ*) so that the external force acting on the drop can be balanced by the capillary force. In the absence of contact angle hysteresis (CAH), the upper contact angle remains at θ*. However, in the presence of CAH, the upper contact angle can descend to provide more capillary force. The coupling between the lower and upper contact angles determines the equilibrium shape of the captured drop. In a capillary valve, the pinned contact line can move across the edge as the pressure difference exceeds the valving pressure, which depends on the geometrical characteristic and wetting property of the valve opening. When CAH is considered, the valving pressure is elevated because the capillary force is enhanced by the receding contact angle. For a pendant drop under gravity, the maximal capillary force is achieved as the lower contact angle reaches 180° in the absence of CAH. However, in the presence of CAH, four regimes can be identified by three critical drop volumes. The lower contact angle can exceed 180°, and therefore the drop takes on the shape of a light bulb, which does not exist in the absence of CAH. The comparisons between Surface Evolver simulations and experiments are quite well.

  9. Drop coalescence and liquid flow in a single Plateau border

    NASA Astrophysics Data System (ADS)

    Cohen, Alexandre; Fraysse, Nathalie; Raufaste, Christophe

    2015-05-01

    We report a comprehensive study of the flow of liquid triggered by injecting a droplet into a liquid foam microchannel, also called a Plateau border. This drop-injected experiment reveals an intricate dynamics for the liquid redistribution, with two contrasting regimes observed, ruled either by inertia or viscosity. We devoted a previous study [A. Cohen et al., Phys. Rev. Lett. 112, 218303 (2014), 10.1103/PhysRevLett.112.218303] to the inertial imbibition regime, unexpected at such small length scales. Here we report other features of interest of the drop-injected experiment, related to the coalescence of the droplet with the liquid microchannel, to both the inertial and viscous regimes, and to the occurrence of liquid flow through the soap films as well as effects of the interfacial rheology. The transition between the two regimes is investigated and qualitatively accounted for. The relevance of our results to liquid foam drainage is tackled by considering the flow of liquid at the nodes of the network of interconnected microchannels. Extensions of our study to liquid foams are discussed.

  10. Direct numerical simulation of gaseous mixing layers laden with multicomponent-liquid drops: liquid-specific effects

    NASA Astrophysics Data System (ADS)

    Le Clercq, Patrick C.; Bellan, Josette

    2005-06-01

    A representation of multicomponent-liquid (MC-liquid) composition as a linear combination of two single-Gamma probability distribution functions (PDFs) is used to describe a large number of MC-liquid drops evaporating in a gas flow. The PDF, called the double-Gamma PDF, depends on the molar mass. The gas-phase conservation equations are written in an Eulerian frame and the drops are described in a Lagrangian frame. Gas conservation equations for mass, momentum, species and energy are combined with differential conservation equations for the first four moments of the gas-composition PDF and coupled to the perfect gas equation of state. Source terms in all conservation equations account for the gas/drop interaction. The drop governing equations encompass differential conservation statements for position, mass, momentum, energy and four moments of the liquid-composition PDF. Simulations are performed for a three-dimensional mixing layer whose lower stream is initially laden with drops colder than the surrounding gas. Initial perturbations excite the layer to promote the double pairing of its four initial spanwise vortices to an ultimate vortex. During the layer evolution, the drops heat and evaporate. The results address the layer evolution, and the state of the gas and drops when layers reach a momentum-thickness maximum past the double vortex pairing. Of interest is the influence of the liquid composition on the development of the vortical features of the flow, on the vortical state reached after the second pairing, and on the gas temperature and composition. The MC-liquid simulations are initiated with a single-Gamma PDF composition so as to explore the development of the double-Gamma PDF. Examination of equivalent simulations with n-decane, diesel and three kerosenes as the liquid, permits assessment of the single-species versus the MC-liquid aspect, and of mixture composition specific effects. Global layer growth and global rotational characteristics are

  11. Method of orientation control and experimental investigation using a liquid-drop micromanipulator

    NASA Astrophysics Data System (ADS)

    Zhang, Qin; Wang, Han; Gan, Yuming; Huang, Weijun; Aoyama, Hisayuki

    2017-04-01

    Orientation adjustment of the micro-component is the key but most difficult part of micro-assembly. In this paper, the mechanism and physical process for orientation adjustment of micro-components absorbed by a liquid-drop micromanipulator are analyzed. The transformation relationship between the orientation of micro-components and the shape of the liquid-drop micromanipulator tip is studied. The quantitative mapping relationship between the shape of the liquid-drop micromanipulator tip and the orientation of micro components is established. A method to quantitatively control the tilt and rotation of micro-components is presented, and the feasibility of the method is verified by experiment. The results show that the orientation of a micro-component absorbed by a liquid-drop micromanipulator varies with the orientation of the micromanipulator. Quantitative control of the orientation of the micro-component can be realized by changing the shape of micromanipulator tip by controlling the upward and downward movement of tungsten rods.

  12. Alcohol drops on miscible liquid: mixing or spreading?

    NASA Astrophysics Data System (ADS)

    Kim, Hyoungsoo; Muller, Koen; Shardt, Orest; Afkhami, Shahriar; Stone, Howard

    2016-11-01

    We studied how a sessile drop of alcohol behaves when placed on a fully miscible liquid. The dynamics of the subsequent mixing and spreading were captured by using a high-speed camera and investigated by varying parameters (e.g., surface tension, density, and viscosity). We observed that a deposited alcohol drop on a liquid bath remains as a floating lens shape, the alcohol liquid leaks out along the rim of the droplet, and it spreads axi-symmetrically along the bottom liquid interface. To visualize spreading and mixing features, we used time-resolved Particle Tacking Velocimetry and a Schlieren method. We observed a localized mixing flow at the rim of the floating droplet where the maximum flow speed is obtained, driven by a solutal Marangoni effect. Underneath the interface of the bath liquid, a viscous boundary layer develops while the alcohol liquid spreads along the radial direction. We also observed a finite quasi-steady interfacial flow velocity regime after the alcohol droplet touched the bottom liquid surface. In this regime, the flow speed linearly increases inside the floating lens, and outside the lens the flow speed decays along the r-direction with a power-law slope, Ur r - 1 / 2 . Physical arguments to support the observations will be discussed.

  13. Vapor condensation onto a non-volatile liquid drop

    NASA Astrophysics Data System (ADS)

    Inci, Levent; Bowles, Richard K.

    2013-12-01

    Molecular dynamics simulations of miscible and partially miscible binary Lennard-Jones mixtures are used to study the dynamics and thermodynamics of vapor condensation onto a non-volatile liquid drop in the canonical ensemble. When the system volume is large, the driving force for condensation is low and only a submonolayer of the solvent is adsorbed onto the liquid drop. A small degree of mixing of the solvent phase into the core of the particles occurs for the miscible system. At smaller volumes, complete film formation is observed and the dynamics of film growth are dominated by cluster-cluster coalescence. Mixing into the core of the droplet is also observed for partially miscible systems below an onset volume suggesting the presence of a solubility transition. We also develop a non-volatile liquid drop model, based on the capillarity approximations, that exhibits a solubility transition between small and large drops for partially miscible mixtures and has a hysteresis loop similar to the one observed in the deliquescence of small soluble salt particles. The properties of the model are compared to our simulation results and the model is used to study the formulation of classical nucleation theory for systems with low free energy barriers.

  14. Vapor condensation onto a non-volatile liquid drop

    SciTech Connect

    Inci, Levent; Bowles, Richard K.

    2013-12-07

    Molecular dynamics simulations of miscible and partially miscible binary Lennard–Jones mixtures are used to study the dynamics and thermodynamics of vapor condensation onto a non-volatile liquid drop in the canonical ensemble. When the system volume is large, the driving force for condensation is low and only a submonolayer of the solvent is adsorbed onto the liquid drop. A small degree of mixing of the solvent phase into the core of the particles occurs for the miscible system. At smaller volumes, complete film formation is observed and the dynamics of film growth are dominated by cluster-cluster coalescence. Mixing into the core of the droplet is also observed for partially miscible systems below an onset volume suggesting the presence of a solubility transition. We also develop a non-volatile liquid drop model, based on the capillarity approximations, that exhibits a solubility transition between small and large drops for partially miscible mixtures and has a hysteresis loop similar to the one observed in the deliquescence of small soluble salt particles. The properties of the model are compared to our simulation results and the model is used to study the formulation of classical nucleation theory for systems with low free energy barriers.

  15. Dynamics of drop coalescence on under-liquid substrates

    NASA Astrophysics Data System (ADS)

    Mitra, Surjyasish; Mitra, Sushanta

    2015-11-01

    Theoretical understanding of drop coalescence on under-liquid substrates is a challenging problem due to the presence of a surrounding viscous medium. Though, most work till date have focused on coalescence in air medium, the presence of a surrounding viscous medium is a significant extension to this classical coalescence problem. Such instances are often found in physical systems such as oil-spills, wetting of marine ecosystem, etc. In the present work, a modified one-dimensional lubrication equation has been developed to describe the early coalescence behavior of two symmetric sessile drops for under-liquid substrates, which takes into account the viscosities of both the drop and the surrounding medium. We found a new time scale which governs the process and there exist a cross-over time between the universal scaling of the bridge height growth \\hcirc ~ \\tcirc (valid for both under-liquid and air) and a much slower bridge growth \\hcirc ~\\tcirc 0 . 24 occurring at a later time. It is also found that the evolving bridge profile has a self-similarity, which breaks up much earlier for under-liquid substrates as opposed to symmetric coalescence in air.

  16. Active structuring of colloidal armour on liquid drops

    PubMed Central

    Dommersnes, Paul; Rozynek, Zbigniew; Mikkelsen, Alexander; Castberg, Rene; Kjerstad, Knut; Hersvik, Kjetil; Otto Fossum, Jon

    2013-01-01

    Adsorption and assembly of colloidal particles at the surface of liquid droplets are at the base of particle-stabilized emulsions and templating. Here we report that electrohydrodynamic and electro-rheological effects in leaky-dielectric liquid drops can be used to structure and dynamically control colloidal particle assemblies at drop surfaces, including electric-field-assisted convective assembly of jammed colloidal ‘ribbons’, electro-rheological colloidal chains confined to a two-dimensional surface and spinning colloidal domains on that surface. In addition, we demonstrate the size control of ‘pupil’-like openings in colloidal shells. We anticipate that electric field manipulation of colloids in leaky dielectrics can lead to new routes of colloidosome assembly and design for ‘smart armoured’ droplets. PMID:23811716

  17. A Partial Equilibrium Theory for Drops and Capillary Liquids

    SciTech Connect

    Searcy, Alan W.; Beruto, Dario T.; Barberis, Fabrizio

    2006-10-26

    The two-century old theory of Young and Laplace retains apowerful influence on surface and interface studies because itquantitatively predicts the height of rise of capillary liquids from thecontact angles of drops. But the classical theory does not acknowledgethat equilibrium requires separate minimization of partial free energiesof one-component liquids bonded to immiscible solids. We generalize atheorem of Gibbs and Curie to obtain a partial equilibrium (PE) theorythat does so and that also predicts the height of capillary rise fromcontact angles of drops. Published observations and our own measurementsof contact angles of water bonded to glass and Teflon surfaces supportthe conclusion of PE theory that contact angles of meniscuses and ofdrops are different dependent variables. PE theory provides thermodynamicand kinetic guidance to nanoscale processes that the classical theoryobscures, as illustrated by examples in our concludingsection.

  18. Coalescence of Immiscible Liquid Metal Drop on Graphene

    PubMed Central

    Li, Tao; Li, Jie; Wang, Long; Duan, Yunrui; Li, Hui

    2016-01-01

    Molecular dynamics simulations were performed to investigate the wetting and coalescence of liquid Al and Pb drops on four carbon-based substrates. We highlight the importance of the microstructure and surface topography of substrates in the coalescence process. Our results show that the effect of substrate on coalescence is achieved by changing the wettability of the Pb metal. Additionally, we determine the critical distance between nonadjacent Al and Pb films required for coalescence. These findings improve our understanding of the coalescence of immiscible liquid metals at the atomistic level. PMID:27667589

  19. Liquid drops and surface tension with smoothed particle applied mechanics

    NASA Astrophysics Data System (ADS)

    Nugent, S.; Posch, H. A.

    2000-10-01

    Smoothed particle applied mechanics (SPAM), also referred to as smoothed particle hydrodynamics, is a Lagrangian particle method for the simulation of continuous flows. Here we apply it to the formation of a liquid drop, surrounded by its vapor, for a van der Waals (vdW) fluid in two dimensions. The cohesive pressure of the vdW equation of state gives rise to an attractive, central force between the particles with an interaction range which is assumed to exceed the interaction range of all the other smoothed forces in the SPAM equations of motion. With this assumption, stable drops are formed, and the vdW phase diagram is well reproduced by the simulations. Below the critical temperature, the surface tension for equilibrated drops may be computed from the pressure excess in their centers. It agrees very well with the surface tension independently determined from the vibrational frequency of weakly excited drops. We also study strongly deformed drops performing large-amplitude oscillations, which are reminiscent of the oscillations of a large ball of water under microgravity conditions. In an appendix we comment on the limitations of SPAM by studying the violation of angular momentum conservation, which is a consequence of noncentral forces contributed by the full Newtonian viscous stress tensor.

  20. Laser capillary spectrophotometric acquisition of bivariate drop size and concentration data for liquid-liquid dispersion

    DOEpatents

    Tavlarides, L.L.; Bae, J.H.

    1991-12-24

    A laser capillary spectrophotometric technique measures real time or near real time bivariate drop size and concentration distribution for a reactive liquid-liquid dispersion system. The dispersion is drawn into a precision-bore glass capillary and an appropriate light source is used to distinguish the aqueous phase from slugs of the organic phase at two points along the capillary whose separation is precisely known. The suction velocity is measured, as is the length of each slug from which the drop free diameter is calculated. For each drop, the absorptivity at a given wavelength is related to the molar concentration of a solute of interest, and the concentration of given drops of the organic phase is derived from pulse heights of the detected light. This technique permits on-line monitoring and control of liquid-liquid dispersion processes. 17 figures.

  1. Laser capillary spectrophotometric acquisition of bivariate drop size and concentration data for liquid-liquid dispersion

    DOEpatents

    Tavlarides, Lawrence L.; Bae, Jae-Heum

    1991-01-01

    A laser capillary spectrophotometric technique measures real time or near real time bivariate drop size and concentration distribution for a reactive liquid-liquid dispersion system. The dispersion is drawn into a precision-bore glass capillary and an appropriate light source is used to distinguish the aqueous phase from slugs of the organic phase at two points along the capillary whose separation is precisely known. The suction velocity is measured, as is the length of each slug from which the drop free diameter is calculated. For each drop, the absorptivity at a given wavelength is related to the molar concentration of a solute of interest, and the concentration of given drops of the organic phase is derived from pulse heights of the detected light. This technique permits on-line monitoring and control of liquid-liquid dispersion processes.

  2. Single drop liquid-liquid-liquid microextraction of methamphetamine and amphetamine in urine.

    PubMed

    He, Yi; Kang, Youn-Jung

    2006-11-10

    Single drop liquid-liquid-liquid microextraction (LLLME) combined with high performance liquid chromatography (HPLC)-UV detection was investigated for the determination of a popular drug of abuse, methamphetamine (MAP), and its major metabolite, amphetamine (AP), in urine samples. The target compounds were extracted from NaOH modified sample solution to a thin layer of organic solvent membrane, and back-extracted to an acidic acceptor drop suspended on the tip of a 50-microL HPLC syringe in the aforementioned organic layer. This syringe was also used for direct injection after extraction. Factors affecting extraction efficiency were studied. At optimal conditions, the overall enrichment factor (EF) was 500-fold for AP and 730-fold for MAP, respectively. The method exhibited a wide linear range (1.0-1500 microg/L), low detection limit (0.5 microg/L), and good repeatability (RSD<5.0%) for both analytes. The feasibility of the method was demonstrated by the analysis of human urine samples.

  3. Hip Rotations Influence Electromyographic Activity of Gluteus Medius Muscle During Pelvic Drop Exercise.

    PubMed

    Monteiro, Renan Lima; Facchini, Joana Hoverter; de Freitas, Diego Galace; Callegaric, Bianca; Amado João, Sílvia Maria

    2016-08-24

    Pelvic drop exercises are often used to strengthen the gluteus medius muscle with the aim of increasing or prioritizing its recruitment. However, the effect of hip rotation on the performance of the action of the gluteus medius is unknown. The aim of the study was to evaluate the effect of hip rotation on the recruitment of the gluteus medius muscle, tensor fasciae latae and quadratus lumborum. Seventeen healthy subjects performed two sets of four repetitions of pelvic drop exercise in random order with lateral (PDLR), medial (PDMR) and neutral (PDN) rotation of the hip. The electromyographic activity of the gluteus medius muscle (GM), tensor fasciae latae (TFL) and quadratus lumborum (QL) were evaluated using surface electromyography (sEMG). The results showed significant increases in activation of the GM with medial and neutral rotation compared with lateral rotation (p = 0.03, p = 0.01, respectively) and there was no difference between medial and neutral rotation (p=1.00). There was no difference in electromyographic activity of the tensor fasciae latae and quadratus lumborum in any of the positions. The GM:TFL ratio was the same in all analyzed positions. Regarding the GM:QL ratio, there was a significant increase with medial rotation compared with lateral rotation (p=0.02). Pelvic drop exercises are more efficient for activating the gluteus medius when the hip is in medial rotation and neutral position.

  4. Liquid drops attract or repel by the inverted Cheerios effect

    PubMed Central

    Karpitschka, Stefan; Pandey, Anupam; Lubbers, Luuk A.; Weijs, Joost H.; Botto, Lorenzo; Das, Siddhartha; Andreotti, Bruno; Snoeijer, Jacco H.

    2016-01-01

    Solid particles floating at a liquid interface exhibit a long-ranged attraction mediated by surface tension. In the absence of bulk elasticity, this is the dominant lateral interaction of mechanical origin. Here, we show that an analogous long-range interaction occurs between adjacent droplets on solid substrates, which crucially relies on a combination of capillarity and bulk elasticity. We experimentally observe the interaction between droplets on soft gels and provide a theoretical framework that quantitatively predicts the interaction force between the droplets. Remarkably, we find that, although on thick substrates the interaction is purely attractive and leads to drop–drop coalescence, for relatively thin substrates a short-range repulsion occurs, which prevents the two drops from coming into direct contact. This versatile interaction is the liquid-on-solid analog of the “Cheerios effect.” The effect will strongly influence the condensation and coarsening of drops on soft polymer films, and has potential implications for colloidal assembly and mechanobiology. PMID:27298348

  5. A perspective on the interfacial properties of nanoscopic liquid drops

    NASA Astrophysics Data System (ADS)

    Malijevský, Alexandr; Jackson, George

    2012-11-01

    The structural and interfacial properties of nanoscopic liquid drops are assessed by means of mechanical, thermodynamical, and statistical mechanical approaches that are discussed in detail, including original developments at both the macroscopic level and the microscopic level of density functional theory (DFT). With a novel analysis we show that a purely macroscopic (static) mechanical treatment can lead to a qualitatively reasonable description of the surface tension and the Tolman length of a liquid drop; the latter parameter, which characterizes the curvature dependence of the tension, is found to be negative and has a magnitude of about a half of the molecular dimension. A mechanical slant cannot, however, be considered satisfactory for small finite-size systems where fluctuation effects are significant. From the opposite perspective, a curvature expansion of the macroscopic thermodynamic properties (density and chemical potential) is then used to demonstrate that a purely thermodynamic approach of this type cannot in itself correctly account for the curvature correction of the surface tension of liquid drops. We emphasize that any approach, e.g., classical nucleation theory, which is based on a purely macroscopic viewpoint, does not lead to a reliable representation when the radius of the drop becomes microscopic. The description of the enhanced inhomogeneity exhibited by small drops (particularly in the dense interior) necessitates a treatment at the molecular level to account for finite-size and surface effects correctly. The so-called mechanical route, which corresponds to a molecular-level extension of the macroscopic theory of elasticity and is particularly popular in molecular dynamics simulation, also appears to be unreliable due to the inherent ambiguity in the definition of the microscopic pressure tensor, an observation which has been known for decades but is frequently ignored. The union of the theory of capillarity (developed in the nineteenth

  6. Experimental comparison of measurement techniques for drop size distributions in liquid/liquid dispersions

    NASA Astrophysics Data System (ADS)

    Maaß, S.; Wollny, S.; Voigt, A.; Kraume, M.

    2011-02-01

    An online measurement technique for drop size distribution in stirred tank reactors is needed but has not yet been developed. Different approaches and different techniques have been published as the new standard during the last decade. Three of them (focus beam reflectance measurement, two-dimensional optical reflectance measurement techniques and a fiber optical FBR sensor) are tested, and their results are compared with trustful image analysis results from an in situ microscope. The measurement of drop sizes in liquid/liquid distribution is a major challenge for all tested measurement probes, and none provides exact results for the tested system of pure toluene/water compared to an endoscope. Not only the size analysis but also the change of the size over time gives unreasonable results. The influence of the power input on the drop size distribution was the only reasonable observation in this study. The FBR sensor was not applicable at all to the used system. While all three probes are based on laser back scattering, the general question of the usability of this principle for measuring evolving drop size distributions in liquid/liquid system is asked. The exterior smooth surface of droplets in such systems is leading to strong errors in the measurement of the size of the drops. That leads to widely divergent results. A different measurement principle should be used for online measurements of drop size distributions than laser back scattering.

  7. Instability of a rotating liquid ring

    NASA Astrophysics Data System (ADS)

    Zhao, Sicheng; Tao, Jianjun

    2013-09-01

    It is shown numerically that a rotating inviscid liquid ring has a temporally oscillating state, where the radius of the ring varies periodically because of the competition between the centrifugal force and the centripetal force caused by the surface tension. Stability analysis reveals that an enlarging or shrinking ring is unstable to a varicose-type mode, which is affected by both the radial velocity and the radius ratio between the cross section and the ring. Furthermore, uniform rotation of a ring leads to a traveling unstable mode, whose frequency is determined by a simple sinuous mode, while the surface shape is modulated by the varicose mode and twisted by the rotation-induced Coriolis force.

  8. Coalescence of surfactant-laden drops in liquids

    NASA Astrophysics Data System (ADS)

    Nowak, Emilia; Simmons, Mark

    2015-11-01

    Whilst coalescence of droplets in air is much studied, the mechanism of merging surfactant-laden drops in other liquids is less well understood. The dynamics of the coalescence of droplets in presence of surfactants was investigated focusing on the curvature and progression of the width of the neck that bridges the drops (up to millimetres) as well as the mixing patterns and surface flows driven by Marangoni stresses. Coalescence of different composition droplets revealed difference in the curvature of the meniscus on either side of the growing bridge which was more pronounced for the lower viscosities of the surrounding oils and related to the different local values of the surface tension. With the aid of a dye present in one of the drops, the visualisation of bulk flow was possible and different patterns were observed with increasing viscosity of the surrounding oil that led to formation of `mushroom'-like structures inside the droplets. EPSRC Programme Grant, MEMPHIS, EP/K0039761/1.

  9. Non-axisymmetric shapes of a rotating drop in an immiscible system

    NASA Technical Reports Server (NTRS)

    Wang, T. G.; Tagg, R.; Cammack, L.; Croonquist, A. P.

    1982-01-01

    The nonaxisymmetric shapes of a rotating drop in an immiscible system were studied. Five basic families of shapes (axisymmetric, two-lobed, three-lobed, four-lobed, and toroidal) were observed. The sequence (axisymmetric to two-lobed to three-lobed to four-lobed to toroidal) seems to be linked to increasing spin-up velocity. For the axisymmetric case, direct comparisons of experiments with the theory of a free rotating drop were surprisingly good the equatorial area differs from theory by only 30%. Furthermore, the non-axisymmetric shapes are in good qualitative agreement with the theory, although the theory does not address the presence of an outer fluid.

  10. Suspension of Drops of a Liquid in a Column of Water.

    ERIC Educational Resources Information Center

    Ahmad, Jamil

    1995-01-01

    Describes a demonstration which creates the illusion of violating Archimedes Principle. The procedure involves two liquids with identical densities and produces drops of one liquid suspended in the middle of a column of the second liquid. (DDR)

  11. Drop deformation and breakup in a partially filled horizontal rotating cylinder

    NASA Astrophysics Data System (ADS)

    White, Andrew; Pereira, Caroline; Hyacinthe, Hyaquino; Ward, Thomas

    2014-11-01

    Drop deformation and breakup due to shear flow has been studied extensively in Couette devices as well as in gravity-driven flows. In these cases shear is generated either by the moving wall or the drop's motion. For such flows the drop shape remains unperturbed at low capillary number (Ca), deforms at moderate Ca , and can experience breakup as Ca --> 1 and larger. Here single drops of NaOH(aq) will be placed in a horizontal cylindrical rotating tank partially filled with vegetable oil resulting in 10-2 < Ca <101 . It will be shown that the reactive vegetable oil-NaOH(aq) system, where surfactants are produced in situ by saponification, can yield lower minimum surface tensions and faster adsorption than non-reactive surfactant systems. Oil films between the wall and drop as well as drop shape will be observed as rotation rates and NaOH(aq) concentration are varied. Results will be presented in the context of previous work on bubble and drop shapes and breakup. NSF CBET #1262718.

  12. Difficulties in applying laser technique to measure drop sizes in vertical and inclined Annular gas-liquid flows

    NASA Astrophysics Data System (ADS)

    Zaidi, Sohail H.

    1996-11-01

    Annular two phase flow is one of the most common regimes of gas/liquid flow found in industrial equipment. In this regime, the liquid flows in part as a film on the channel walls while the rest of the liquid is carried as drops by the gas flowing in the center of the channel. Detailed knowledge of the liquid drops particularly their sizes and velocities is essential in processes involving heat and mass transfer. This information is of great importance for the oil industry where inclined drilling has recently become a common practice. The effect of inclination on the drop sizes is still unknown and requires further investigation. Laser diffraction is one of the few available techniques which is widely used for the measurement of droplet size distribution. Although the technique is simple to use, it is not free from problems. This paper highlights the practical difficulties encountered when the technique was used to measure the drop size distribution in an inclinable flow column. The laser system was mounted on the rig and the flow column was rotated from vertical to horizontal position. Liquid drops appearing on the optical windows prohibited laser measurements. Other problems included the glass reflections and vibration when the rig was in operation. In this paper some practical suggestions have been made to overcome these problems and some useful results have been included.

  13. Marangoni stresses and drop breakup due to wall shear in a partially filled rotating cylinder

    NASA Astrophysics Data System (ADS)

    White, Andrew; Odesanya, Azeez; Ward, Thomas

    2015-11-01

    Drop deformation and breakup in a rotating cylinder partially filled with oil is studied. Experiments using a rotating cylinder are relatively new but we will demonstrate that they are analogous to studies involving tubes and other geometries. Surfactants are added to the drop phase in concentrations at and below the CMC while the rotation rate of the cylinder is varied. Of interest is the effect of interfacial surfactant transport on changes in oil film thickness, drop shape and the onset of tail streaming. Two Biot numbers comparing the importance of surfactant adsorption and desorption to convection of surfactant on the interface are estimated. As shown in previous work on drops and bubbles in tubes, the balance between surface convection, diffusion and adsorption can affect the placement of Marangoni stresses, resulting in thicker or thinner films than with clean surfaces. When surface convection is large, surfactant builds up at the tail and Marangoni stresses can lead to tail streaming when surface tensions are sufficiently small. Experimental results are compared to numerical simulations and to previous work on drops and bubbles in tubes. National Science Foundation (#1262718).

  14. Stochastic rotation dynamics for nematic liquid crystals

    SciTech Connect

    Lee, Kuang-Wu Mazza, Marco G.

    2015-04-28

    We introduce a new mesoscopic model for nematic liquid crystals (LCs). We extend the particle-based stochastic rotation dynamics method, which reproduces the Navier-Stokes equation, to anisotropic fluids by including a simplified Ericksen-Leslie formulation of nematodynamics. We verify the applicability of this hybrid model by studying the equilibrium isotropic-nematic phase transition and nonequilibrium problems, such as the dynamics of topological defects and the rheology of sheared LCs. Our simulation results show that this hybrid model captures many essential aspects of LC physics at the mesoscopic scale, while preserving microscopic thermal fluctuations.

  15. Evaporation dynamics of a liquid drop on a non-miscible liquid bath

    NASA Astrophysics Data System (ADS)

    Pirat, Christophe; Ramos-Canut, Stella; Caupin, Frederic; wetting Team

    2016-11-01

    When a liquid drop sits on a solid surface, it is well known that the wetting and evaporation properties strongly depend on the environmental and wetting conditions. In this experimental study, we investigate the coupled spreading-evaporation dynamics of a liquid drop, made of a mixture of water and ethanol, gently deposited on a non-miscible oil bath. After a fast spreading stage due to a positive spreading parameter, the drop starts to recede while the evaporation is going on. Subsequently, a Marangoni instability develops as alcohol evaporates faster than water. In particular, depending on the initial alcohol-water ratio, a set of rim instabilities takes place. Radial droplet ejections can be observed, with various droplet speeds, sizes and frequencies.

  16. Acoustic levitation of liquid drops: Dynamics, manipulation and phase transitions.

    PubMed

    Zang, Duyang; Yu, Yinkai; Chen, Zhen; Li, Xiaoguang; Wu, Hongjing; Geng, Xingguo

    2017-03-18

    The technique of acoustic levitation normally produces a standing wave and the potential well of the sound field can be used to trap small objects. Since no solid surface is involved it has been widely applied for the study of fluid physics, nucleation, bio/chemical processes, and various forms of soft matter. In this article, we survey the works on drop dynamics in acoustic levitation, focus on how the dynamic behavior is related to the rheological properties and discuss the possibility to develop a novel rheometer based on this technique. We review the methods and applications of acoustic levitation for the manipulation of both liquid and solid samples and emphasize the important progress made in the study of phase transitions and bio-chemical analysis. We also highlight the possible open areas for future research.

  17. Analysis of the free-fall behavior of liquid-metal drops in a gaseous atmosphere

    NASA Technical Reports Server (NTRS)

    Mccoy, J. Kevin; Markworth, Alan J.; Collings, E. W.; Brodkey, Robert S.

    1987-01-01

    The free-fall of a liquid-metal drop and heat transfer from the drop to its environment are described for both a gaseous atmosphere and vacuum. A simple model, in which the drop is assumed to fall rectilinearly with behavior like that of a rigid particle, is developed first, then possible causes of deviation from this behavior are discussed. The model is applied to describe solidification of drops in a drop tube. Possible future developments of the model are suggested.

  18. Flow in a differentially rotated cylindrical drop at moderate Reynolds number

    NASA Astrophysics Data System (ADS)

    Harriott, G. M.; Brown, R. A.

    1984-07-01

    Galerkin finite-element approximations are combined with computer-implemented perturbation methods for tracking families of solutions to calculate the steady axisymmetric flows in a differentially rotated cylindrical drop as a function of Reynolds number Re, drop aspect ratio and the rotation ratio between the two end disks. The flows for Reynolds numbers below 100 are primarily viscous and reasonably described by an asymptotic analysis. When the disks are exactly counter-rotated, multiple steady flows are calculated that bifurcate to higher values of Re from the expected solution with two identical secondary cells stacked symmetrically about the axial midplane. The new flows have two cells of different size and are stable beyond the critical value Re sub c. The slope of the locus of Re sub c for drops with aspect ratio up to 3 disagrees with the result for two disks of infinite radius computed assuming the similarity form of the velocity field. Changing the rotation ratio for exact counter-rotation ruptures the junction of the multiple flow fields into two separated flow families.

  19. Cooling and solidification of liquid-metal drops in a gaseous atmosphere

    NASA Technical Reports Server (NTRS)

    Mccoy, J. K.; Markworth, A. J.; Collings, E. W.; Brodkey, R. S.

    1992-01-01

    The free fall of a liquid-metal drop, heat transfer from the drop to its environment, and solidification of the drop are described for both gaseous and vacuum atmospheres. A simple model, in which the drop is assumed to fall rectilinearly, with behavior like that of a rigid particle, is developed to describe cooling behavior. Recalescence of supercooled drops is assumed to occur instantaneously when a specified temperature is passed. The effects of solidification and experimental parameters on drop cooling are calculated and discussed. Major results include temperature as a function of time, and of drag, time to complete solidification, and drag as a function of the fraction of the drop solidified.

  20. The investigation of liquid analysis method based on fiber micro-drop sensor

    NASA Astrophysics Data System (ADS)

    Sun, Weimin; Li, Xiaomei; Zeng, Youmin

    2007-01-01

    A portable and practical fiber micro-drop sensor, with which can determine the refractive index and the concentration of the liquid, has be designed and realized. The advantages of this sensors combines simplicity of structure, facility of operation, wide range of measurement and low price. Liquid drops formed at the tip of a liquid sensing head are measured by a fiber sensor. The fiber sensor works as follows: infrared light source is injected into the drop through an optical fiber and the total internal reflections and absorptions are detected by a photo detector. A drop speed independent one-dimensional waveform, fiber fingerprint drop trace (FFDT), is generated. Liquid surface tension, refractive index and dielectric constant can be estimated from the fingerprint. For the effective use of the sensor, a new on-line method of liquid drop analysis is proposed, which is used for liquid discrimination with the orderliness of the fiber fingerprint drop trace. To compare two fingerprints effectively, signal analysis is required. Comparing fiber fingerprint drop trace, which might cause peaks and valleys in the trace at almost the same wavelet, digital signals process is more intuitionist. Analyzing every part of the fingerprint drop trace with impactful signal analysis method, as Fast Fourier Transform algorithm and correlative analysis, some orderliness can be revealed. Colligating the orderliness, we can discriminate all kinds of liquids or their characteristic parameters, such as liquid concentration, refractive index and so on.

  1. Headspace single drop microextraction versus dispersive liquid-liquid microextraction using magnetic ionic liquid extraction solvents.

    PubMed

    An, Jiwoo; Rahn, Kira L; Anderson, Jared L

    2017-05-15

    A headspace single drop microextraction (HS-SDME) method and a dispersive liquid-liquid microextraction (DLLME) method were developed using two tetrachloromanganate ([MnCl4(2-)])-based magnetic ionic liquids (MIL) as extraction solvents for the determination of twelve aromatic compounds, including four polyaromatic hydrocarbons, by reversed phase high-performance liquid chromatography (HPLC). The analytical performance of the developed HS-SDME method was compared to the DLLME approach employing the same MILs. In the HS-SDME approach, the magnetic field generated by the magnet was exploited to suspend the MIL solvent from the tip of a rod magnet. The utilization of MILs in HS-SDME resulted in a highly stable microdroplet under elevated temperatures and long extraction times, overcoming a common challenge encountered in traditional SDME approaches of droplet instability. The low UV absorbance of the [MnCl4(2-)]-based MILs permitted direct analysis of the analyte enriched extraction solvent by HPLC. In HS-SDME, the effects of ionic strength of the sample solution, temperature of the extraction system, extraction time, stir rate, and headspace volume on extraction efficiencies were examined. Coefficients of determination (R(2)) ranged from 0.994 to 0.999 and limits of detection (LODs) varied from 0.04 to 1.0μgL(-1) with relative recoveries from lake water ranging from 70.2% to 109.6%. For the DLLME method, parameters including disperser solvent type and volume, ionic strength of the sample solution, mass of extraction solvent, and extraction time were studied and optimized. Coefficients of determination for the DLLME method varied from 0.997 to 0.999 with LODs ranging from 0.05 to 1.0μgL(-1). Relative recoveries from lake water samples ranged from 68.7% to 104.5%. Overall, the DLLME approach permitted faster extraction times and higher enrichment factors for analytes with low vapor pressure whereas the HS-SDME approach exhibited better extraction efficiencies for

  2. Do liquid drops roll or slide on inclined surfaces?

    PubMed

    Thampi, Sumesh P; Adhikari, Ronojoy; Govindarajan, Rama

    2013-03-12

    We study the motion of a two-dimensional droplet on an inclined surface, under the action of gravity, using a diffuse interface model which allows for arbitrary equilibrium contact angles. The kinematics of motion is analyzed by decomposing the gradient of the velocity inside the droplet into a shear and a residual flow. This decomposition helps in distinguishing sliding versus rolling motion of the drop. Our detailed study confirms intuition, in that rolling motion dominates as the droplet shape approaches a circle, and the viscosity contrast between the droplet and the ambient fluid becomes large. As a consequence of kinematics, the amount of rotation in a general droplet shape follows a universal curve characterized by geometry, and independent of Bond number, surface inclination and equilibrium contact angle, but determined by the slip length and viscosity contrast. Our results open the way toward a rational design of droplet-surface properties, both when rolling motion is desirable (as in self-cleaning hydrophobic droplets) and when it must be prevented (as in insecticide sprays on leaves).

  3. Drop Dynamics and Speciation in Isolation of Metals from Liquid Wastes by Reactive Scavenging

    SciTech Connect

    Arne J. Pearlstein; Alexander Scheeline

    2002-08-30

    Computational and experimental studies of the motion and dynamics of liquid drops in gas flows were conducted with relevance to reactive scavenging of metals from atomized liquid waste. Navier-Stoke's computations of deformable drops revealed a range of conditions from which prolate drops are expected, and showed how frajectiones of deformable drops undergoing deceleration can be computed. Experimental work focused on development of emission fluorescence, and scattering diagnostics. The instrument developed was used to image drop shapes, soot, and nonaxisymmetric departures from steady flow in a 22kw combustor

  4. Bifurcation analysis of the behavior of partially wetting liquids on a rotating cylinder

    NASA Astrophysics Data System (ADS)

    Lin, Te-Sheng; Rogers, Steven; Tseluiko, Dmitri; Thiele, Uwe

    2016-08-01

    We discuss the behavior of partially wetting liquids on a rotating cylinder using a model that takes into account the effects of gravity, viscosity, rotation, surface tension, and wettability. Such a system can be considered as a prototype for many other systems where the interplay of spatial heterogeneity and a lateral driving force in the proximity of a first- or second-order phase transition results in intricate behavior. So does a partially wetting drop on a rotating cylinder undergo a depinning transition as the rotation speed is increased, whereas for ideally wetting liquids, the behavior only changes quantitatively. We analyze the bifurcations that occur when the rotation speed is increased for several values of the equilibrium contact angle of the partially wetting liquids. This allows us to discuss how the entire bifurcation structure and the flow behavior it encodes change with changing wettability. We employ various numerical continuation techniques that allow us to track stable/unstable steady and time-periodic film and drop thickness profiles. We support our findings by time-dependent numerical simulations and asymptotic analyses of steady and time-periodic profiles for large rotation numbers.

  5. The Illustrated Topology of Liquid Drops during Formation

    ERIC Educational Resources Information Center

    Libii, Josue Njock

    2004-01-01

    High-speed photography can show that the shape often used for a newly forming drop is wrong. Knowledge of drop behaviour is important for inkjet printers, and a close look at the formation of drops as given here can enhance critical observation, thinking and analysis.

  6. Rheological properties, shape oscillations, and coalescence of liquid drops with surfactants

    NASA Technical Reports Server (NTRS)

    Apfel, R. E.; Holt, R. G.

    1990-01-01

    A method was developed to deduce dynamic interfacial properties of liquid drops. The method involves measuring the frequency and damping of free quadrupole oscillations of an acoustically levitated drop. Experimental results from pure liquid-liquid systems agree well with theoretical predictions. Additionally, the effects of surfactants is considered. Extension of these results to a proposed microgravity experiment on the drop physics module (DPM) in USML-1 are discussed. Efforts are also underway to model the time history of the thickness of the fluid layer between two pre-coalescence drops, and to measure the film thickness experimentally. Preliminary results will be reported, along with plans for coalescence experiments proposed for USML-1.

  7. Large bubble entrapment during drop impacts on a restricted liquid surface

    NASA Astrophysics Data System (ADS)

    Zou, Jun; Ji, Chen; Yuan, BaoGang; Ren, YuLiang; Ruan, XiaoDong; Fu, Xin

    2012-05-01

    The behavior of millimetric drops impacting on a gas-liquid interface restricted by surrounding walls is studied using a high-speed video camera. A novel phenomenon of large bubble entrapment is observed in experiments. It is found that the large bubble formation is not only dependent on the impact velocity of the drop, but also the shape of drop at the moment of contact with the liquid surface and the distance from the impact point to surrounding walls.

  8. Size Distribution and Velocity of Ethanol Drops in a Rocket Combustor Burning Ethanol and Liquid Oxygen

    NASA Technical Reports Server (NTRS)

    Ingebo, Robert D.

    1961-01-01

    Single jets of ethanol were studied photomicrographically inside a rocket chamber as they broke up into sprays of drops which underwent simultaneous acceleration and vaporization with chemical reaction occurring in the surrounding combustion gas stream. In each rocket test-firing, liquid oxygen was used as the oxidant. Both drop velocity and drop size distribution data were obtained from photomicrographs of the ethanol drops taken with an ultra-high speed tracking camera developed at NASA, Lewis Research Center.

  9. Analytical and experimental investigation of liquid double drop dynamics: Preliminary design for space shuttle experiments

    NASA Technical Reports Server (NTRS)

    1981-01-01

    The preliminary grant assessed the use of laboratory experiments for simulating low g liquid drop experiments in the space shuttle environment. Investigations were begun of appropriate immiscible liquid systems, design of experimental apparatus and analyses. The current grant continued these topics, completed construction and preliminary testing of the experimental apparatus, and performed experiments on single and compound liquid drops. A continuing assessment of laboratory capabilities, and the interests of project personnel and available collaborators, led to, after consultations with NASA personnel, a research emphasis specializing on compound drops consisting of hollow plastic or elastic spheroids filled with liquids.

  10. On-chip drop-to-drop liquid microextraction coupled with real-time concentration monitoring technique.

    PubMed

    Wijethunga, Pavithra A L; Nanayakkara, Yasith S; Kunchala, Praveen; Armstrong, Daniel W; Moon, Hyejin

    2011-03-01

    This paper demonstrates a novel drop-to-drop liquid-liquid micro-extraction (DTD-LLME) device, which is based on an electrowetting on dielectric (EWOD) digital microfluidic chip. Droplets of two immiscible liquids, one of which is an ionic liquid, are formed in nanoliter volumes, driven along electrodes, merged and mixed for extraction, and finally separated upon the completion of the extraction process. All the steps are carried out on a microfluidic chip using combined electrowetting and dielectrophoretic forces, which act on the droplet upon the application of electric potential. Specially, the phase separation of two immiscible nanoliter-scale liquid drops was achieved for the first time on an EWOD digital microfluidic chip. To study the on-chip extraction kinetics, an image-based concentration measurement technique with suitable color parameters was studied and compared with the typical UV absorption based technique. Finally, the effect of applied ac voltage frequency on the extraction kinetics was studied. The observations on DTD-LLME, particularly phase separation, are discussed. The image-based method was found to be applicable for precise concentration measurements with the right choice of the color parameter. Results from experiments on finding the frequency dependence on extraction kinetics demonstrate that the application of higher frequencies can be a factor in accelerating the extraction on the proposed microextraction device.

  11. Drop tower experiment for performance evaluation of gas-liquid equilibrium thruster for small spacecraft

    NASA Astrophysics Data System (ADS)

    Motooka, Norizumi; Yamamoto, Takayuki; Mori, Osamu; Okano, Yoshinobu; Kishino, Yoshihiro; Kawaguchi, Junichiro

    JAXA/ISAS is developing the gas-liquid equilibrium thruster for a small spacecraft. In small spacecrafts, the thruster system must be simple and its weight must be light. This thruster system uses HFC-134a (1,1,1,2-tetrafluoroethane) , a kind of liquefied gas, as propellant because of its harmlessness and ease of handling. And this thruster stores propellant as liquid in the tank and ejects propellant as gas using the gas-liquid equilibrium pressure to produce thrust, so the propellant tank only needs to resist the vapor pressure of propellant. In this thruster system, the porous metal is also equipped in the tank for the following performance advantages: (1) liquid fuel retention: The porous metal reduces sloshing problems which cause bad effects on spacecraft attitude by retaining liquid propellant inside the porous metal: (2) vapor-liquid separation: The porous metal also helps propellant separate gas from liquid by advancing propellant vaporization on its large surface area and retaining liquid propellant using its surface tension. In last autumn, we carried out the experiment to evaluate these two advantages of porous metal under micro gravity condition using 50 meters drop tower in Hokkaido, Japan. The system of this experiment divides into two different systems. The first one evaluates liquid propellant retention performance by adding disturbance to liquid propellant absorbed in porous metal. The disturbance is centrifugal force and angular acceleration worked on the liquid propellant by rotating propellant tank controlled by motor. A high speed camera records the behavior of the liquid propellant. The other one evaluates the ability of gas-liquid separation on the case of propellant ejection. In this evaluation, the parameters are full filling porous metal or some ullage in the tank, nozzle diameters and the filling ratio of liquid propellant in the tank. As for (1) liquid fuel retention, in all conducted cases without propellant ejection, liquid propellant

  12. On the coalescence of sessile drops with miscible liquids.

    PubMed

    Borcia, R; Bestehorn, M

    2011-08-01

    Sessile drops sitting on highly wettable solid substrates fuse in qualitatively different ways after contact, depending on the surface tension gradients between the mixing droplets. In early time evolution the drop coalescence can be fast or delayed (intermittent). In long time evolution a secondary drop formation can occur. We study numerically droplet dynamics during coalescence in two and three spatial dimensions, within a phase field approach. We discuss criteria to distinguish different coalescence regimes. A comparison with recent experiments will be done.

  13. Contact angles of liquid drops on super hydrophobic surfaces: understanding the role of flattening of drops by gravity.

    PubMed

    Extrand, C W; Moon, Sung In

    2010-11-16

    Measurement of contact angles on super hydrophobic surfaces by conventional methods can produce ambiguous results. Experimental difficulties in constructing tangent lines, gravitational distortion or erroneous assumptions regarding the extent of spreading can lead to underestimation of contact angles. Three models were used to estimate drop shape and perceived contact angles on completely nonwetting super hydrophobic surfaces. One of the models employed the classic numerical solutions from Bashforth and Adams. Additionally, two approximate models were derived as part of this work. All three showed significant distortion of microliter-sized drops and similar trends in perceived contact angles. Liquid drops of several microliters are traditionally used in sessile contact angle measurements. Drops of this size are expected to and indeed undergo significant flattening on super hydrophobic surfaces, even if the wetting interactions are minimal. The distortion is more pronounced if the liquid has a lesser surface tension or greater density. For surfaces that are completely nonwetting, underestimation of contact angles can be tens of degrees. Our modeling efforts suggest that accurate contact angle measurements on super hydrophobic surfaces would require very small sessile drops, on the order of hundreds of picoliters.

  14. Drop impact dynamics on liquid-infused superhydrophobic surfaces

    NASA Astrophysics Data System (ADS)

    Kim, Jeong-Hyun; Rothstein, Jonathan

    2015-11-01

    In this talk, we present a series of experiments investigating the drop impact dynamics on hydrophobic, air-infused and lubricant-infused superhydrophobic surfaces. To create the superhydrophobic surfaces, smooth Teflon (PTFE) surfaces were roughened by a 240-grit sandpaper. The immiscible and incompressible silicone oils with different viscosities were infused into features of the superhydrophobic surfaces by a skim coating technique. The spreading and retraction dynamics on a series of the tested surfaces will be presented. We will show that the maximal deformation of the drops on lubricant-infused surfaces grows with increasing viscosity ratio between a water drop and the infused oil. We will show that this increase in the maximal deformation with the viscosity ratio is consistent with increasing the velocity and the viscosity of the drops but the rims of the drops destabilize with increasing the drop velocity. Finally, we will demonstrate that increasing the viscosity of the infused oil induces higher viscous force at the contact line, resulting in reduction in the movement of the drops during retraction and corresponding increase in the final drop size.

  15. Vertical vibration dynamics of acoustically levitated drop containing two immiscible liquids

    NASA Astrophysics Data System (ADS)

    Zang, Duyang; Zhai, Zhicong; Li, Lin; Lin, Kejun; Li, Xiaoguang; Geng, Xingguo

    2016-09-01

    We have studied the levitation and oscillation dynamics of complex drops containing two immiscible liquids. Two types of drops, core-shell drop and abnormal-shaped drop, have been obtained depending on the levitation procedures. The oscillation dynamics of the drops have been studied using a high speed camera. It has been found that the oscillation of the abnormal-shaped drop has a longer oscillation period and decays much faster than that of the core-shell drop, which cannot be accounted for by the air resistance itself. The acoustic streaming induced by ultrasound may bring an additional force against the motion of the drop due to the Bernoulli effect. This is responsible for the enhanced damping during the oscillation in acoustic levitation.

  16. Flotation of Denser Liquid Drops on Lighter Liquids in Non-Neumann Condition: Role of Line Tension.

    PubMed

    George, D; Damodara, S; Iqbal, R; Sen, A K

    2016-10-11

    Flotation of a denser liquid drop on lighter liquid has been explained earlier via the Neumann triangle. We demonstrate the flotation of a denser liquid (water) drop on a lighter liquid in a pair that does not satisfy the Neumann triangle. We attribute this newly studied phenomenon to the role of line tension τ which prevents the water droplet from complete engulfment. A simple model is used to explain the underlying physics and to obtain critical line tension value for stable flotation. We establish line tension values for different liquids with water and show possible heterogeneous nucleation that contributes toward the variance of line tension values.

  17. Direct Numerical Simulation of Transitional Multicomponent-Species Gaseous and Multicomponent-Liquid Drop-Laden Mixing

    NASA Technical Reports Server (NTRS)

    Selle, Laurent C.; Bellan, Josette

    2006-01-01

    organization depend on the initial gas temperature, this being due to the drop/turbulence coupling. The vapor-composition mean molar mass and standard deviation distributions strongly correlate with the initial liquid-composition PDF; such a correlation only exists for the magnitude of the mean but not for that of the standard deviation. Unlike in pre-transitional situations, regions of large composition standard deviation no longer necessarily coincide with regions of large mean molar mass. The kinetic energy, rotational and composition characteristics, and dissipation are liquid specific and the variation among liquids is amplified with increasing free-stream gas temperature. Eulerian and Lagrangian statistics of gas-phase quantities show that the different. Observation framework may affect the perception of the flow characteristics. The gas composition, of which the first four moments are calculated, is shown to be close to, but distinct from a SGPDF. The PDF of the scalar dissipation rate is calculated for drop-laden layers and is shown to depart more significantly from the typically assumed Gaussian in gaseous flows than experimentally measured gaseous scalar dissipation rates, this being attributed to the increased heterogeneity due to drop/flow interactions.

  18. Evaporation of pure liquid sessile and spherical suspended drops: a review.

    PubMed

    Erbil, H Yildirim

    2012-01-15

    A sessile drop is an isolated drop which has been deposited on a solid substrate where the wetted area is limited by a contact line and characterized by contact angle, contact radius and drop height. Diffusion-controlled evaporation of a sessile drop in an ambient gas is an important topic of interest because it plays a crucial role in many scientific applications such as controlling the deposition of particles on solid surfaces, in ink-jet printing, spraying of pesticides, micro/nano material fabrication, thin film coatings, biochemical assays, drop wise cooling, deposition of DNA/RNA micro-arrays, and manufacture of novel optical and electronic materials in the last decades. This paper presents a review of the published articles for a period of approximately 120 years related to the evaporation of both sessile drops and nearly spherical droplets suspended from thin fibers. After presenting a brief history of the subject, we discuss the basic theory comprising evaporation of micrometer and millimeter sized spherical drops, self cooling on the drop surface and evaporation rate of sessile drops on solids. The effects of drop cooling, resultant lateral evaporative flux and Marangoni flows on evaporation rate are also discussed. This review also has some special topics such as drop evaporation on superhydrophobic surfaces, determination of the receding contact angle from drop evaporation, substrate thermal conductivity effect on drop evaporation and the rate evaporation of water in liquid marbles.

  19. Controlled drop emission by wetting properties in driven liquid filaments.

    PubMed

    Ledesma-Aguilar, R; Nistal, R; Hernández-Machado, A; Pagonabarraga, I

    2011-05-01

    The controlled formation of micrometre-sized drops is of great importance to many technological applications. Here we present a wetting-based destabilization mechanism of forced microfilaments on either hydrophilic or hydrophobic stripes that leads to the periodic emission of droplets. The drop emission mechanism is triggered above the maximum critical forcing at which wetting, capillarity, viscous friction and gravity can balance to sustain a stable driven contact line. The corresponding critical filament velocity is predicted as a function of the static wetting angle, which can be tuned through the substrate behaviour, and shows a strong dependence on the filament size. This sensitivity explains the qualitative difference in the critical velocity between hydrophilic and hydrophobic stripes, and accounts for previous experimental results of splashing solids. We demonstrate that this mechanism can be used to control independently the drop size and emission period, opening the possibility of highly monodisperse and flexible drop production techniques in open microfluidic geometries.

  20. Computations of the deformation and solidifcation of impinging liquid metal drops

    NASA Astrophysics Data System (ADS)

    Che, Judy; Tryggvason, Gretar; Ceccio, Steven

    1997-11-01

    The solidification of individual liquid metal drops impacting a cold wall, as well as the deposition of subsequent drops characterized by drop remelt, coalescence, and solidification, are simulated numerically. The numerical method fully couples fluid flow and heat transfer and is based on a single set of conservation equations written for all phases, allowing for arbitrary changes in material properties. Solidification is modeled as a stable, planar solid-liquid interface, which is valid for both pure and eutectic systems with no initial thermal undercooling. Using this technique, towers have been built by depositing drops on top of one another. Low Weber number simulations produce short, squat towers, while high Weber number cases generate tall, slender towers. Within a tower, each drop takes on a final shape based on the Peclet number and the non- dimensional freezing temperature. In some high Peclet number cases, divots freeze onto a drop's surface forming a pore at the axis of the tower. Supported by NASA.

  1. Multimode dynamics of a liquid drop over an inclined surface with a wettability gradient.

    PubMed

    Das, A K; Das, P K

    2010-06-15

    A liquid drop placed over a solid surface with a wettability gradient self-propels to minimize its surface energy. It can also climb an inclined plane if the applied gradient strength is high enough. We investigate the motion of liquid drops over an inclined gradient surface using a unique 3D computational technique. The technique combines diffuse interface in a smoothed particle hydrodynamics simulation to study the internal fluid structure and the contact line dynamics. Simulation results reveal that drop motion is dependent on its volume, surface inclination, and the strength of the wettability gradient. It has been demonstrated that, depending on these parameters, a drop can experience upward or downward motion or can remain stationary on the inclined plane. Finally, drop mobility maps which give an idea about the regimes of uphill and downhill movement of a drop over gradient surfaces have been proposed.

  2. Wettability-gradient-driven micropump for transporting discrete liquid drops

    NASA Astrophysics Data System (ADS)

    Bardaweel, Hamzeh K.; Zamuruyev, Konstantin; Delplanque, Jean-Pierre; Davis, Cristina E.

    2013-03-01

    In this paper, we report our efforts toward building a microelectromechanical system-based micropump. The micropump is driven by a wettability gradient and used to transport discrete drops. The gradient in wettability is distributed axisymmetrically, with hydrophobicity of the micropump surface decreasing radially toward the center. Both physical and chemical properties of the surface are altered to obtain the wettability gradient needed for driving the drops. The surface of the micropump is, first, patterned with pre-designed micro-features that define the roughness of the surface and, then, coated with a low-energy interface film. Results show that drops deposited on the surface of the micropump move, in a directional way, along the wettability gradient. The average velocity of the deposited drops is 5 mm s-1. Measured contact angles decrease gradually from 157.0° to 124.2° toward the center of the micropump surface. Maximum driving force exerted by the solid surface on the drops is 12.82 µN. The average size of the drops transported on the surface of the micropump is 2 µL.

  3. Evaporation of drops on two parallel fibers: influence of the liquid morphology and fiber elasticity.

    PubMed

    Duprat, Camille; Bick, Alison D; Warren, Patrick B; Stone, Howard A

    2013-06-25

    We investigate experimentally the evaporation of liquid accumulated on a pair of parallel fibers, rigid or flexible. The liquid wetting the fibers can adopt two distinct morphologies: a compact drop shape, whose evaporation dynamics is similar to that of an isolated aerosol droplet, or a long liquid column of constant cross-section, whose evaporation dynamics depends upon the aspect ratio of the column. We thus find that the evaporation rate is constant for drops, while it increases strongly for columns as the interfiber distance decreases, and we propose a model to explain this behavior. When the fibers are flexible, the transition from drops to columns can be induced by the deformation of the fibers because of the capillary forces applied by the drop. Thus, we find that the evaporation rate increases with increasing flexibility. Furthermore, complex morphology transitions occur upon drying, which results in spreading of the drop as it evaporates.

  4. An analysis of the sensitivity of pendant drops and liquid bridges to measure the interfacial tension

    NASA Astrophysics Data System (ADS)

    Ferrera, C.; Montanero, J. M.; Cabezas, M. G.

    2007-12-01

    Drop shape techniques, such as axisymmetric drop shape analysis, provide accurate measurements of the interfacial tension from images of pendant drops for a wide variety of experimental conditions. However, these techniques are known to fail when dealing with nearly spherical drop shapes, which may occur, for instance, when working with interfaces between liquids of similar densities and/or under microgravity. We analyzed the advantages of using liquid bridges close to the minimum volume stability limit instead of pendant drops to measure the interfacial tension under different experimental conditions. First, the sensitivity of both configurations to a variation of the interfacial tension is studied numerically as a function of the volume for several Bond numbers B. The results indicate that a liquid bridge close to the minimum volume stability limit is generally more sensitive than a pendant drop of the same volume, especially for small values of the density difference across the interface and/or gravity. This suggests that the use of liquid bridges may extend the range of applicability of drop shape techniques. To explore this possibility, synthetic images of both pendant drops and liquid bridges were generated and then processed by TIFA-AI. The results demonstrated that the use of liquid bridges enhances the range of Bond numbers for which drop shape techniques work satisfactorily. More specifically, similar accuracy is obtained from both configurations for B ~ 10-1, while the use of liquid bridges yields much better results for B ~ 10-2. Finally, experiments were conducted to partially validate the analysis based on synthetic images. Good agreement was found between the values determined from the real and synthetic images.

  5. Liquid drop technique for generation of organic glass and metal shells

    NASA Technical Reports Server (NTRS)

    Hendricks, C. D.

    1982-01-01

    It was found that liquid drop techniques are very useful in several diverse areas. For producing very uniform metallic, organic, inorganic and, on particular, glassy shells, the liquid jet method is the most reproducible and exceptionally useful of all the techniques studied. The technique of capillary wave synchronization of the break-up of single and multiple component jets was utilized to produce uniform sized liquid drops and solid particles, and hollow liquid and solid shells. The technique was also used to encapsulate a number of liquids in impermeable spherical shells. Highly uniform glass shells were made by generating uniform drops of glass forming materials in an aqueous solution, subsequently evaporating the water, and then fusing and blowing the remaining solids in a high temperature vertical tube furnace. Experimental results are presented and the critical problems in further research in this field are discussed.

  6. The production of drops by the bursting of a bubble at an air liquid interface

    NASA Technical Reports Server (NTRS)

    Darrozes, J. S.; Ligneul, P.

    1982-01-01

    The fundamental mechanism arising during the bursting of a bubble at an air-liquid interface is described. A single bubble was followed from an arbitrary depth in the liquid, up to the creation and motion of the film and jet drops. Several phenomena were involved and their relative order of magnitude was compared in order to point out the dimensionless parameters which govern each step of the motion. High-speed cinematography is employed. The characteristic bubble radius which separates the creation of jet drops from cap bursting without jet drops is expressed mathematically. The corresponding numerical value for water is 3 mm and agrees with experimental observations.

  7. Dynamic measurement of the force required to move a liquid drop on a solid surface.

    PubMed

    Pilat, D W; Papadopoulos, P; Schäffel, D; Vollmer, D; Berger, R; Butt, H-J

    2012-12-11

    We measured the forces required to slide sessile drops over surfaces. The forces were measured by means of a vertical deflectable capillary stuck in the drop. The drop adhesion force instrument (DAFI) allowed the investigation of the dynamic lateral adhesion force of water drops of 0.1 to 2 μL volume at defined velocities. On flat PDMS surfaces, the dynamic lateral adhesion force increases linearly with the diameter of the contact area of the solid-liquid interface and linearly with the sliding velocity. The movement of the drop relative to the surfaces enabled us to resolve the pinning of the three-phase contact line to individual defects. We further investigated a 3D superhydrophobic pillar array. The depinning of the receding part of the rim of the drop occurred almost simultaneously from four to five pillars, giving rise to peaks in the lateral adhesion force.

  8. Motion of liquid drops on surfaces induced by asymmetric vibration: role of contact angle hysteresis.

    PubMed

    Mettu, Srinivas; Chaudhury, Manoj K

    2011-08-16

    Hysteresis of wetting, like the Coulombic friction at solid/solid interface, impedes the motion of a liquid drop on a surface when subjected to an external field. Here, we present a counterintuitive example, where some amount of hysteresis enables a drop to move on a surface when it is subjected to a periodic but asymmetric vibration. Experiments show that a surface either with a negligible or high hysteresis is not conducive to any drop motion. Some finite hysteresis of contact angle is needed to break the periodic symmetry of the forcing function for the drift to occur. These experimental results are consistent with simulations, in which a drop is approximated as a linear harmonic oscillator. The experiment also sheds light on the effect of the drop size on flow reversal, where drops of different sizes move in opposite directions due to the difference in the phase of the oscillation of their center of mass.

  9. Flow Visualization in Evaporating Liquid Drops and Measurement of Dynamic Contact Angles and Spreading Rate

    NASA Technical Reports Server (NTRS)

    Zhang, Neng-Li; Chao, David F.

    2001-01-01

    A new hybrid optical system, consisting of reflection-refracted shadowgraphy and top-view photography, is used to visualize flow phenomena and simultaneously measure the spreading and instant dynamic contact angle in a volatile-liquid drop on a nontransparent substrate. Thermocapillary convection in the drop, induced by evaporation, and the drop real-time profile data are synchronously recorded by video recording systems. Experimental results obtained from this unique technique clearly reveal that thermocapillary convection strongly affects the spreading process and the characteristics of dynamic contact angle of the drop. Comprehensive information of a sessile drop, including the local contact angle along the periphery, the instability of the three-phase contact line, and the deformation of the drop shape is obtained and analyzed.

  10. Noncoalescence of sessile drops from different but miscible liquids: hydrodynamic analysis of the twin drop contour as a self-stabilizing traveling wave.

    PubMed

    Karpitschka, Stefan; Riegler, Hans

    2012-08-10

    Capillarity always favors drop fusion. Nevertheless, sessile drops from different but completely miscible liquids often do not fuse instantaneously upon contact. Rather, intermediate noncoalescence is observed. Two separate drop bodies, connected by a thin liquid neck, move over the substrate. Supported by new experimental data, a thin film hydrodynamic analysis of this state is presented. Presumably advective and diffusive volume fluxes in the neck region establish a localized and temporarily stable surface tension gradient. This induces a local surface (Marangoni) flow that stabilizes a traveling wave, i.e., the observed moving twin drop configuration. The theoretical predictions are in excellent agreement with the experimental findings.

  11. Assessing the accuracy of contact angle measurements for sessile drops on liquid-repellent surfaces.

    PubMed

    Srinivasan, Siddarth; McKinley, Gareth H; Cohen, Robert E

    2011-11-15

    Gravity-induced sagging can amplify variations in goniometric measurements of the contact angles of sessile drops on super-liquid-repellent surfaces. The very large value of the effective contact angle leads to increased optical noise in the drop profile near the solid-liquid free surface and the progressive failure of simple geometric approximations. We demonstrate a systematic approach to determining the effective contact angle of drops on super-repellent surfaces. We use a perturbation solution of the Bashforth-Adams equation to estimate the contact angles of sessile drops of water, ethylene glycol, and diiodomethane on an omniphobic surface using direct measurements of the maximum drop width and height. The results and analysis can be represented in terms of a dimensionless Bond number that depends on the maximum drop width and the capillary length of the liquid to quantify the extent of gravity-induced sagging. Finally, we illustrate the inherent sensitivity of goniometric contact angle measurement techniques to drop dimensions as the apparent contact angle approaches 180°.

  12. Effect of surface charge convection and shape deformation on the dielectrophoretic motion of a liquid drop

    NASA Astrophysics Data System (ADS)

    Mandal, Shubhadeep; Bandopadhyay, Aditya; Chakraborty, Suman

    2016-04-01

    The dielectrophoretic motion and shape deformation of a Newtonian liquid drop in an otherwise quiescent Newtonian liquid medium in the presence of an axisymmetric nonuniform dc electric field consisting of uniform and quadrupole components is investigated. The theory put forward by Feng [J. Q. Feng, Phys. Rev. E 54, 4438 (1996), 10.1103/PhysRevE.54.4438] is generalized by incorporating the following two nonlinear effects—surface charge convection and shape deformation—towards determining the drop velocity. This two-way coupled moving boundary problem is solved analytically by considering small values of electric Reynolds number (ratio of charge relaxation time scale to the convection time scale) and electric capillary number (ratio of electrical stress to the surface tension) under the framework of the leaky dielectric model. We focus on investigating the effects of charge convection and shape deformation for different drop-medium combinations. A perfectly conducting drop suspended in a leaky (or perfectly) dielectric medium always deforms to a prolate shape and this kind of shape deformation always augments the dielectrophoretic drop velocity. For a perfectly dielectric drop suspended in a perfectly dielectric medium, the shape deformation leads to either increase (for prolate shape) or decrease (for oblate shape) in the dielectrophoretic drop velocity. Both surface charge convection and shape deformation affect the drop motion for leaky dielectric drops. The combined effect of these can significantly increase or decrease the dielectrophoretic drop velocity depending on the electrohydrodynamic properties of both the liquids and the relative strength of the electric Reynolds number and electric capillary number. Finally, comparison with the existing experiments reveals better agreement with the present theory.

  13. Drop Fragmentation at Impact onto a Bath of an Immiscible Liquid

    NASA Astrophysics Data System (ADS)

    Lhuissier, H.; Sun, C.; Prosperetti, A.; Lohse, D.

    2013-06-01

    The impact of a drop onto a deep bath of an immiscible liquid is studied with emphasis on the drop fragmentation into a collection of noncoalescing daughter drops. At impact the drop flattens and spreads at the surface of the crater it transiently opens in the bath and reaches a maximum deformation, which gets larger with increasing impact velocity, before surface tension drives its recession. This recession can promote the fragmentation by two different mechanisms: At moderate impact velocity, the drop recession converges to the axis of symmetry to form a jet which then fragments by a Plateau-Rayleigh mechanism. At higher velocity the edge of the receding drop destabilizes and shapes into radial ligaments which subsequently fragment. For this latter mechanism the number N∝We3 and the size distribution of the daughter drops p(d)∝d-4 as a function of the impact Weber number We are explained on the basis of the observed spreading of the drop. The universality of this model for the fragmentation of receding liquid sheets might be relevant for other configurations.

  14. Rotational reorganization of doped cholesteric liquid crystalline films.

    PubMed

    Eelkema, Rienk; Pollard, Michael M; Katsonis, Nathalie; Vicario, Javier; Broer, Dirk J; Feringa, Ben L

    2006-11-08

    In this paper an unprecedented rotational reorganization of cholesteric liquid crystalline films is described. This rotational reorganization results from the conversion of a chiral molecular motor dopant to an isomer with a different helical twisting power, leading to a change in the cholesteric pitch. The direction of this reorganization is correlated to the sign of the change in helical twisting power of the dopant. The rotational reorganization of the liquid crystalline film was used to rotate microscopic objects 4 orders of magnitude larger than the bistable dopants in the film, which shows that molecular motors and switches can perform work. The surface of the doped cholesteric liquid crystalline films was found to possess a regular surface relief, whose periodicity coincides with typical cholesteric polygonal line textures. These surface features originate from the cholesteric superstructure in the liquid crystalline film, which in turn is the result of the presence of the chiral dopant. As such, the presence of the dopant is expressed in these distinct surface structures. A possible mechanism at the origin of the rotational reorganization of liquid crystalline films and the cholesteric surface relief is discussed.

  15. Transport Phenomena in Thin Rotating Liquid Films Including: Nucleate Boiling

    NASA Technical Reports Server (NTRS)

    Faghri, Amir

    2005-01-01

    In this grant, experimental, numerical and analytical studies of heat transfer in a thin liquid film flowing over a rotating disk have been conducted. Heat transfer coefficients were measured experimentally in a rotating disk heat transfer apparatus where the disk was heated from below with electrical resistance heaters. The heat transfer measurements were supplemented by experimental characterization of the liquid film thickness using a novel laser based technique. The heat transfer measurements show that the disk rotation plays an important role on enhancement of heat transfer primarily through the thinning of the liquid film. Experiments covered both momentum and rotation dominated regimes of the flow and heat transfer in this apparatus. Heat transfer measurements have been extended to include evaporation and nucleate boiling and these experiments are continuing in our laboratory. Empirical correlations have also been developed to provide useful information for design of compact high efficiency heat transfer devices. The experimental work has been supplemented by numerical and analytical analyses of the same problem. Both numerical and analytical results have been found to agree reasonably well with the experimental results on liquid film thickness and heat transfer Coefficients/Nusselt numbers. The numerical simulations include the free surface liquid film flow and heat transfer under disk rotation including the conjugate effects. The analytical analysis utilizes an integral boundary layer approach from which

  16. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity.

    PubMed

    Sigalotti, Leonardo Di G; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (T(s)≈0.96) is close to the theoretically derived value of T(s)=1 at zero ambient pressure for this vdW fluid.

  17. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity

    NASA Astrophysics Data System (ADS)

    Sigalotti, Leonardo Di G.; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (Ts≈0.96 ) is close to the theoretically derived value of Ts=1 at zero ambient pressure for this vdW fluid.

  18. Granular impact cratering by liquid drops: Understanding raindrop imprints through an analogy to asteroid strikes.

    PubMed

    Zhao, Runchen; Zhang, Qianyun; Tjugito, Hendro; Cheng, Xiang

    2015-01-13

    When a granular material is impacted by a sphere, its surface deforms like a liquid yet it preserves a circular crater like a solid. Although the mechanism of granular impact cratering by solid spheres is well explored, our knowledge on granular impact cratering by liquid drops is still very limited. Here, by combining high-speed photography with high-precision laser profilometry, we investigate liquid-drop impact dynamics on granular surface and monitor the morphology of resulting impact craters. Surprisingly, we find that despite the enormous energy and length difference, granular impact cratering by liquid drops follows the same energy scaling and reproduces the same crater morphology as that of asteroid impact craters. Inspired by this similarity, we integrate the physical insight from planetary sciences, the liquid marble model from fluid mechanics, and the concept of jamming transition from granular physics into a simple theoretical framework that quantitatively describes all of the main features of liquid-drop imprints in granular media. Our study sheds light on the mechanisms governing raindrop impacts on granular surfaces and reveals a remarkable analogy between familiar phenomena of raining and catastrophic asteroid strikes.

  19. Granular impact cratering by liquid drops: Understanding raindrop imprints through an analogy to asteroid strikes

    PubMed Central

    Zhao, Runchen; Zhang, Qianyun; Tjugito, Hendro; Cheng, Xiang

    2015-01-01

    When a granular material is impacted by a sphere, its surface deforms like a liquid yet it preserves a circular crater like a solid. Although the mechanism of granular impact cratering by solid spheres is well explored, our knowledge on granular impact cratering by liquid drops is still very limited. Here, by combining high-speed photography with high-precision laser profilometry, we investigate liquid-drop impact dynamics on granular surface and monitor the morphology of resulting impact craters. Surprisingly, we find that despite the enormous energy and length difference, granular impact cratering by liquid drops follows the same energy scaling and reproduces the same crater morphology as that of asteroid impact craters. Inspired by this similarity, we integrate the physical insight from planetary sciences, the liquid marble model from fluid mechanics, and the concept of jamming transition from granular physics into a simple theoretical framework that quantitatively describes all of the main features of liquid-drop imprints in granular media. Our study sheds light on the mechanisms governing raindrop impacts on granular surfaces and reveals a remarkable analogy between familiar phenomena of raining and catastrophic asteroid strikes. PMID:25548187

  20. The capacitive drop tensiometer - a novel multianalysing technique for measuring the properties of liquids

    NASA Astrophysics Data System (ADS)

    Wang, C. H.; Augousti, A. T.; Mason, J.; McMillan, N. D.

    1999-01-01

    A new instrumental method for measuring the physical properties of a liquid has been developed. The instrument, called a capacitive drop tensiometer (CDT), is based on the drop volume principle in combination with a capacitive transducer. A delivery head with a specialized wetting design was constructed for forming drops. The capacitive transducer uses the delivery head as one of its plates and a cylindrical ring plate, which surrounds the delivery head and the space occupied by the drop that is formed, as another. Excellent linearity is achieved by optimizing the design, with an accuracy of drop volume measurement of approximately 0957-0233/10/1/007/img6. The system is suitable for measuring both drops in equilibrium and those in the process of growing. Its capability of real-time measurement makes it particularly useful for volatile liquids, in which instance the measurement of drop volume using a flowmeter or a pump is no longer reliable. The CDT can also be used to determine concentration. It was found that the concentration curve is linear for aqueous glycerol solutions although not so for aqueous ethanol solutions. The CDT's ability to measure surface tension was also explored and experimental results are presented here.

  1. Turbulent convection in liquid metal with and without rotation.

    PubMed

    King, Eric M; Aurnou, Jonathan M

    2013-04-23

    The magnetic fields of Earth and other planets are generated by turbulent, rotating convection in liquid metal. Liquid metals are peculiar in that they diffuse heat more readily than momentum, quantified by their small Prandtl numbers, Pr < 1. Most analog models of planetary dynamos, however, use moderate Pr fluids, and the systematic influence of reducing Pr is not well understood. We perform rotating Rayleigh-Bénard convection experiments in the liquid metal gallium (Pr = 0.025) over a range of nondimensional buoyancy forcing (Ra) and rotation periods (E). Our primary diagnostic is the efficiency of convective heat transfer (Nu). In general, we find that the convective behavior of liquid metal differs substantially from that of moderate Pr fluids, such as water. In particular, a transition between rotationally constrained and weakly rotating turbulent states is identified, and this transition differs substantially from that observed in moderate Pr fluids. This difference, we hypothesize, may explain the different classes of magnetic fields observed on the Gas and Ice Giant planets, whose dynamo regions consist of Pr < 1 and Pr > 1 fluids, respectively.

  2. Turbulent convection in liquid metal with and without rotation

    PubMed Central

    King, Eric M.; Aurnou, Jonathan M.

    2013-01-01

    The magnetic fields of Earth and other planets are generated by turbulent, rotating convection in liquid metal. Liquid metals are peculiar in that they diffuse heat more readily than momentum, quantified by their small Prandtl numbers, . Most analog models of planetary dynamos, however, use moderate fluids, and the systematic influence of reducing is not well understood. We perform rotating Rayleigh–Bénard convection experiments in the liquid metal gallium over a range of nondimensional buoyancy forcing and rotation periods (E). Our primary diagnostic is the efficiency of convective heat transfer . In general, we find that the convective behavior of liquid metal differs substantially from that of moderate fluids, such as water. In particular, a transition between rotationally constrained and weakly rotating turbulent states is identified, and this transition differs substantially from that observed in moderate fluids. This difference, we hypothesize, may explain the different classes of magnetic fields observed on the Gas and Ice Giant planets, whose dynamo regions consist of and fluids, respectively. PMID:23569262

  3. Pool boiling from rotating and stationary spheres in liquid nitrogen

    NASA Technical Reports Server (NTRS)

    Cuan, Winston M.; Schwartz, Sidney H.

    1988-01-01

    Results are presented for a preliminary experiment involving saturated pool boiling at 1 atm from rotating 2 and 3 in. diameter spheres which were immersed in liquid nitrogen (LN2). Additional results are presented for a stationary, 2 inch diameter sphere, quenched in LN2, which were obtained utilizing a more versatile and complete experimental apparatus that will eventually be used for additional rotating sphere experiments. The speed for the rotational tests was varied from 0 to 10,000 rpm. The stationary experiments parametrically varied pressure and subcooling levels from 0 to 600 psig and from 0 to 50 F, respectively. During the rotational tests, a high speed photographic analysis was undertaken to measure the thickness of the vapor film surrounding the sphere. The average Nusselt number over the cooling period was plotted against the rotational Reynolds number. Stationary sphere results included local boiling heat transfer coefficients at different latitudinal locations, for various pressure and subcooling levels.

  4. Studies of rotating liquid floating zones on Skylab IV

    NASA Technical Reports Server (NTRS)

    Carruthers, J. R.; Gibson, E. G.; Klett, M. G.; Facemire, B. R.

    1975-01-01

    Liquid zones of water, soap solution and soap foam were deployed between two aligned circular disks which were free to rotate about the zone axis in the microgravity environment of Skylab IV. Such a configuration is of interest in the containerless handling of melts for possible future space processing crystal growth experiments. Three basic types of zone surface deformation and instability were observed for these rotational conditions; axisymmetric shape changes under single disk rotation, nonaxisymmetric, whirling, C-modes for long zones with equal rotation of both disks, and capillary wave phenomena for short zones with equal rotation of both disks. The sources of these instabilities and the conditions promoting them are analyzed in detail from video tape recordings of the Skylab experiments.

  5. Coarsening dynamics of binary liquids with active rotation.

    PubMed

    Sabrina, Syeda; Spellings, Matthew; Glotzer, Sharon C; Bishop, Kyle J M

    2015-11-21

    Active matter comprised of many self-driven units can exhibit emergent collective behaviors such as pattern formation and phase separation in both biological (e.g., mussel beds) and synthetic (e.g., colloidal swimmers) systems. While these behaviors are increasingly well understood for ensembles of linearly self-propelled "particles", less is known about the collective behaviors of active rotating particles where energy input at the particle level gives rise to rotational particle motion. A recent simulation study revealed that active rotation can induce phase separation in mixtures of counter-rotating particles in 2D. In contrast to that of linearly self-propelled particles, the phase separation of counter-rotating fluids is accompanied by steady convective flows that originate at the fluid-fluid interface. Here, we investigate the influence of these flows on the coarsening dynamics of actively rotating binary liquids using a phenomenological, hydrodynamic model that combines a Cahn-Hilliard equation for the fluid composition with a Navier-Stokes equation for the fluid velocity. The effect of active rotation is introduced though an additional force within the Navier-Stokes equations that arises due to gradients in the concentrations of clockwise and counter-clockwise rotating particles. Depending on the strength of active rotation and that of frictional interactions with the stationary surroundings, we observe and explain new dynamical behaviors such as "active coarsening" via self-generated flows as well as the emergence of self-propelled "vortex doublets". We confirm that many of the qualitative behaviors identified by the continuum model can also be found in discrete, particle-based simulations of actively rotating liquids. Our results highlight further opportunities for achieving complex dissipative structures in active materials subject to distributed actuation.

  6. Single-drop coacervative microextraction of organic compounds prior to liquid chromatography. Theoretical and practical considerations.

    PubMed

    López-Jiménez, Francisco José; Rubio, Soledad; Pérez-Bendito, Dolores

    2008-06-27

    Coacervates made of surfactant aggregates, namely aqueous and reverse micelles and vesicles, were firstly used as solvents in single-drop microextraction (SDME) and proposed for the extraction and concentration of chlorophenols prior to liquid chromatography. The formation of coacervate drops in the needle tip of conventional microsyringes depended on the type of intermolecular forces established between the surfactant headgroups making up the supramolecular aggregates; hydrogen bond interactions were strong enough to permit the formation of spherical drops. Stability of 1-50 microL coacervate drops was achieved by introducing the microsyringe needle tip in a PTFE rod, the end of which had been machined out with a heated flanging-tool to get circular flanges (diameters in the range 3.5-6 mm). The parameters affecting the efficiency of single-drop coacervative microextraction (SDCME) were investigated using vesicular coacervates as a solvent and 2-chlorophenol (CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP) and pentachlorophenol (PCP) as model analytes. Coacervative microextraction dynamics fit to the general rate equation of liquid-liquid extraction. The effect of variables such as extraction time, drop volume, stirring rate, pH and temperature, on the extraction of chlorophenols was similar to that described for organic solvent drops. Electrolyte concentrations above 0.1 M caused drop instability. Under the optimum conditions, detection limits were in the range 0.1-0.3 microg L(-1). The relative standard deviation was between 4.3 and 5.6 at 20 microg L(-1) spiked level. The method was applied to the determination of the four chlorophenols in wastewater, superficial water from a reservoir and groundwater and the recoveries were in the range 79 and 106% at 5-20 microg L(-1) spiked level.

  7. Diffuse-interface modeling of liquid-vapor coexistence in equilibrium drops using smoothed particle hydrodynamics.

    PubMed

    Sigalotti, Leonardo Di G; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

    2014-07-01

    We study numerically liquid-vapor phase separation in two-dimensional, nonisothermal, van der Waals (vdW) liquid drops using the method of smoothed particle hydrodynamics (SPH). In contrast to previous SPH simulations of drop formation, our approach is fully adaptive and follows the diffuse-interface model for a single-component fluid, where a reversible, capillary (Korteweg) force is added to the equations of motion to model the rapid but smooth transition of physical quantities through the interface separating the bulk phases. Surface tension arises naturally from the cohesive part of the vdW equation of state and the capillary forces. The drop models all start from a square-shaped liquid and spinodal decomposition is investigated for a range of initial densities and temperatures. The simulations predict the formation of stable, subcritical liquid drops with a vapor atmosphere, with the densities and temperatures of coexisting liquid and vapor in the vdW phase diagram closely matching the binodal curve. We find that the values of surface tension, as determined from the Young-Laplace equation, are in good agreement with the results of independent numerical simulations and experimental data. The models also predict the increase of the vapor pressure with temperature and the fitting to the numerical data reproduces very well the Clausius-Clapeyron relation, thus allowing for the calculation of the vaporization pressure for this vdW fluid.

  8. Tailored Ink For Piston-Driven Electrostatic Liquid Drop Modulator

    DOEpatents

    Wong, Raymond W.; Breton, Marcel P.; Bedford, Christine E.; Carreira, Leonard M.; Gooray, Arthur M.; Roller, George J.; Zavadil, Kevin; Galambos, Paul; Crowley, Joseph

    2005-04-19

    The present invention relates to an ink composition including water, a solvent, a solvent-soluble dye, and a surfactant, where the ink exhibits a stable liquid microemulsion phase at a first temperature and a second temperature higher than the first temperature and has a conductivity of at most about 200 .mu.S/cm and a dielectric constant of at least about 60, and methods of making such ink compositions. The present invention also relates to a method of making an ink composition for use in a microelectromechanical system-based fluid ejector. The method involves providing a solution or dispersion including a dye or a pigment and adding to the solution or dispersion an additive which includes a material that enhances dielectric permittivity and/or reduces conductivity under conditions effective to produce an ink composition having a conductivity of at most about 200 .mu.S/cm and a dielectric constant of at least about 60.

  9. Viscosity Measurement of Highly Viscous Liquids Using Drop Coalescence in Low Gravity

    NASA Technical Reports Server (NTRS)

    Antar, Basil N.; Ethridge, Edwin; Maxwell, Daniel

    1999-01-01

    The method of drop coalescence is being investigated for use as a method for determining the viscosity of highly viscous undercooled liquids. Low gravity environment is necessary in this case to minimize the undesirable effects of body forces and liquid motion in levitated drops. Also, the low gravity environment will allow for investigating large liquid volumes which can lead to much higher accuracy for the viscosity calculations than possible under 1 - g conditions. The drop coalescence method is preferred over the drop oscillation technique since the latter method can only be applied for liquids with vanishingly small viscosities. The technique developed relies on both the highly accurate solution of the Navier-Stokes equations as well as on data from experiments conducted in near zero gravity environment. In the analytical aspect of the method two liquid volumes are brought into contact which will coalesce under the action of surface tension alone. The free surface geometry development as well as its velocity during coalescence which are obtained from numerical computations are compared with an analogous experimental model. The viscosity in the numerical computations is then adjusted to bring into agreement of the experimental results with the calculations. The true liquid viscosity is the one which brings the experiment closest to the calculations. Results are presented for method validation experiments performed recently on board the NASA/KC-135 aircraft. The numerical solution for this validation case was produced using the Boundary Element Method. In these tests the viscosity of a highly viscous liquid, in this case glycerine at room temperature, was determined to high degree of accuracy using the liquid coalescence method. These experiments gave very encouraging results which will be discussed together with plans for implementing the method in a shuttle flight experiment.

  10. Effects of surface wettability and liquid viscosity on the dynamic wetting of individual drops.

    PubMed

    Chen, Longquan; Bonaccurso, Elmar

    2014-08-01

    In this paper, we experimentally investigated the dynamic spreading of liquid drops on solid surfaces. Drop of glycerol water mixtures and pure water that have comparable surface tensions (62.3-72.8 mN/m) but different viscosities (1.0-60.1 cP) were used. The size of the drops was 0.5-1.2 mm. Solid surfaces with different lyophilic and lyophobic coatings (equilibrium contact angle θ(eq) of 0°-112°) were used to study the effect of surface wettability. We show that surface wettability and liquid viscosity influence wetting dynamics and affect either the coefficient or the exponent of the power law that describes the growth of the wetting radius. In the early inertial wetting regime, the coefficient of the wetting power law increases with surface wettability but decreases with liquid viscosity. In contrast, the exponent of the power law does only depend on surface wettability as also reported in literature. It was further found that surface wettability does not affect the duration of inertial wetting, whereas the viscosity of the liquid does. For low viscosity liquids, the duration of inertial wetting corresponds to the time of capillary wave propagation, which can be determined by Lamb's drop oscillation model for inviscid liquids. For relatively high viscosity liquids, the inertial wetting time increases with liquid viscosity, which may due to the viscous damping of the surface capillary waves. Furthermore, we observed a viscous wetting regime only on surfaces with an equilibrium contact angle θ(eq) smaller than a critical angle θ(c) depending on viscosity. A scaling analysis based on Navier-Stokes equations is presented at the end, and the predicted θ(c) matches with experimental observations without any additional fitting parameters.

  11. Note: A top-view optical approach for observing the coalescence of liquid drops

    NASA Astrophysics Data System (ADS)

    Wang, Luhai; Zhang, Guifu; Wu, Haiyi; Yang, Jiming; Zhu, Yujian

    2016-02-01

    We developed a new device that is capable of top-view optical examination of the coalescence of liquid drops. The device exhibits great potential for visualization, particularly for the early stage of liquid bridge expansion, owing to the use of a high-speed shadowgraph technique. The fluid densities of the two approaching drops and that of the ambient fluid are carefully selected to be negligibly different, which allows the size of the generated drops to be unlimitedly large in principle. The unique system design allows the point of coalescence between two drops to serve as an undisturbed optical pathway through which to image the coalescence process. The proposed technique extended the dimensionless initial finite radius of the liquid bridge to 0.001, in contrast to 0.01 obtained for conventional optical measurements. An examination of the growth of the bridge radius for a water and oil-tetrachloroethylene system provided results similar to Paulsen's power laws of the inertially limited viscous and inertial regimes. Furthermore, a miniscule shift in the center of the liquid bridge was detected at the point of crossover between the two regimes, which can be scarcely distinguished with conventional side-view techniques.

  12. Theory of rotating electrohydrodynamic flows in a liquid film.

    PubMed

    Shiryaeva, E V; Vladimirov, V A; Zhukov, M Yu

    2009-10-01

    The mathematical model of rotating electrohydrodynamic flows in a thin suspended liquid film is proposed and studied. The flows are driven by the given difference of potentials in one direction and constant external electric field E(out) in another direction in the plane of a film. To derive the model, we employ the spatial averaging over the normal coordinate to a film that leads to the average Reynolds stress that is proportional to |E(out)|3. This stress generates tangential velocity in the vicinity of the edges of a film that, in turn, causes the rotational motion of a liquid. The proposed model is used to explain the experimental observations of the liquid film motor.

  13. A Study of the Measurement of Surface and Interfacial Tension by the Maximum Liquid Drop Volume Method.

    PubMed

    Pu, Bingyin; Chen, Donghao

    2001-03-15

    The maximum liquid drop volume (nu(max)) is measured using a back-suction technique with a micrometer syringe piston. The residual amount of liquid on the tip was determined and the tension data calculated from the theoretical correction factors are well in accordance with those from the falling drop volume (nu(f)). Copyright 2001 Academic Press.

  14. Electrical control of Faraday rotation at a liquid-liquid interface.

    PubMed

    Marinescu, Monica; Kornyshev, Alexei A; Flatté, Michael E

    2015-01-01

    A theory is developed for the Faraday rotation of light from a monolayer of charged magnetic nanoparticles at an electrified liquid-liquid interface. The polarization fields of neighboring nanoparticles enhance the Faraday rotation. At such interfaces, and for realistic sizes and charges of nanoparticles, their adsorption-desorption can be controlled with a voltage variation<1 V, providing electrovariable Faraday rotation. A calculation based on the Maxwell-Garnett theory predicts that the corresponding redistribution of 40 nm nanoparticles of yttrium iron garnet can switch a cavity with a quality factor larger than 10(4) for light of wavelength 500 nm at normal incidence.

  15. A steady state pressure drop model for screen channel liquid acquisition devices

    NASA Astrophysics Data System (ADS)

    Hartwig, J. W.; Darr, S. R.; McQuillen, J. B.; Rame, E.; Chato, D. J.

    2014-11-01

    This paper presents the derivation of a simplified one dimensional (1D) steady state pressure drop model for flow through a porous liquid acquisition device (LAD) inside a cryogenic propellant tank. Experimental data is also presented from cryogenic LAD tests in liquid hydrogen (LH2) and liquid oxygen (LOX) to compare against the simplified model and to validate the model at cryogenic temperatures. The purpose of the experiments was to identify the various pressure drop contributions in the analytical model which govern LAD channel behavior during dynamic, steady state outflow. LH2 pipe flow of LAD screen samples measured the second order flow-through-screen (FTS) pressure drop, horizontal LOX LAD outflow tests determined the relative magnitude of the third order frictional and dynamic losses within the channel, while LH2 inverted vertical outflow tests determined the magnitude of the first order hydrostatic pressure loss and validity of the full 1D model. When compared to room temperature predictions, the FTS pressure drop is shown to be temperature dependent, with a significant increase in flow resistance at LH2 temperatures. Model predictions of frictional and dynamic losses down the channel compare qualitatively with LOX LADs data. Meanwhile, the 1D model predicted breakdown points track the trends in the LH2 inverted outflow experimental results, with discrepancies being due to a non-uniform injection velocity across the LAD screen not accounted for in the model.

  16. Large charged drop levitation against gravity

    NASA Technical Reports Server (NTRS)

    Rhim, Won-Kyu; Chung, Sang Kun; Hyson, Michael T.; Trinh, Eugene H.; Elleman, Daniel D.

    1987-01-01

    A hybrid electrostatic-acoustic levitator that can levitate and manipulate a large liquid drop in one gravity is presented. To the authors' knowledge, this is the first time such large drops (up to 4 mm in diameter in the case of water) have been levitated against 1-gravity. This makes possible, for the first time, many new experiments both in space and in ground-based laboratories, such as 1)supercooling and superheating, 2) containerless crystal growth from various salt solutions or melts, 3) drop dynamics of oscillating or rotating liquid drops, 4) drop evaporation and Rayleigh bursting, and 5) containerless material processing in space. The digital control system, liquid drop launch process, principles of electrode design, and design of a multipurpose room temperature levitation chamber are described. Preliminary results that demonstrate drop oscillation and rotation, and crystal growth from supersaturated salt solutions are presented.

  17. Instability development of a viscous liquid drop impacting a smooth substrate.

    PubMed

    Xu, Lei

    2010-08-01

    We study the instability development during a viscous liquid drop impacting a smooth substrate, using high-speed photography. The onset time of the instability highly depends on the surrounding air pressure and the liquid viscosity: it decreases with air pressure with the power of minus two, and increases linearly with the liquid viscosity. From the real-time dynamics measurements, we construct a model which compares the destabilizing stress from air with the stabilizing stress from liquid viscosity. Under this model, our experimental results indicate that at the instability onset time, the two stresses balance each other. This model also illustrates the different mechanisms for the inviscid and viscous regimes previously observed: the inviscid regime is stabilized by the surface tension and the viscous regime is stabilized by the liquid viscosity.

  18. Rotation of a liquid crystal by the Casimir torque

    NASA Astrophysics Data System (ADS)

    Somers, David A. T.; Munday, Jeremy N.

    2015-03-01

    We present a calculation of the Casimir torque acting on a liquid crystal near a birefringent crystal. In this system, a liquid crystal bulk is uniformly aligned at one surface and is twisted at the other surface by a birefringent crystal, e.g., barium titanate. The liquid crystal is separated from the solid crystal by an isotropic, transparent material such as SiO2. By varying the thickness of the deposited layer, we can observe the effect of retardation on the torque (which differentiates it from the close-range van der Waals torque). We find that a barium titanate slab would cause 5CB (4 -cyano -4 '-pentylbiphenyl) liquid crystal to rotate by 10∘ through its bulk when separated by 35 nm of SiO2. The optical technique for measuring this twist is also outlined.

  19. Numerical simulation of drop impact on a liquid-liquid interface with a multiple marker front-capturing method

    NASA Astrophysics Data System (ADS)

    Coyajee, Emil; Boersma, Bendiks Jan

    2009-07-01

    The gravity-driven motion of a droplet impacting on a liquid-liquid interface is studied. The full Navier-Stokes equations are solved on a fixed, uniform grid using a finite difference/front-capturing method. For the representation of fluid-fluid interfaces, a coupled Level-Set/Volume-Of-Fluid method [M. Sussman, E.G. Puckett, A coupled Level-Set and Volume-of-Fluid method for computing 3D and axisymmetric incompressible two-phase flows, J. Comp. Phys. 162 (2000) 301-337] is used, in which we introduce the novel approach of describing separate interfaces with different marker functions. As a consequence, we prevent numerical coalescence of the droplet and the liquid-liquid interface without excessive (local) grid refinement. To validate our method, numerical simulations of the drop impact event are compared with experiments [Z. Mohamed-Kassim, E.K. Longmire, Drop impact on a liquid-liquid interface, Phys. Fluids 15 (2003) 3263-3273]. Furthermore, a comparison is made with the numerical results of [A. Esmaeeli, G. Tryggvason, Direct numerical simulations of bubbly flows. Part 2. Moderate Reynolds number arrays, J. Fluid Mech. 385 (1999) 325-358] for an array of rising bubbles. The investigation shows that the multiple marker approach successfully prevents numerical coalescence of interfaces and adequately captures the effect of surface tension.

  20. Pressure drop in fully developed, duct flow of dispersed liquid-vapor mixture at zero gravity

    NASA Technical Reports Server (NTRS)

    Sridhar, K. R.; Chao, B. T.; Soo, S. L.

    1990-01-01

    The dynamics of steady, fully developed dispersed liquid-vapor flow in a straight duct at 0-g is simulated by flowing water containing n-butyl benzoate droplets. Water and benzoate are immiscible and have identical density at room temperature. The theoretical basis of the simulation is given. Experiments showed that, for a fixed combined flow rate of water and benzoate, the frictional pressure drop is unaffected by large changes in the volume fraction of benzoate drops and their size distribution. Measured power spectra of the static wall pressure fluctuations induced by the turbulent water-benzoate flow also revealed that their dynamics is essentially unaltered by the presence of the droplets. These experimental findings, together with the theoretical analysis, led to the conclusion that the pressure drop in fully developed, dispersed liquid-vapor flow in straight ducts of constant cross section at 0-g is identical to that due to liquid flowing alone at the same total volumetric flow rate of the liquid-vapor mixture and, therefore, can be readily determined.

  1. Liquid management in low gravity using baffled rotating containers

    NASA Technical Reports Server (NTRS)

    Gans, R. F.

    1984-01-01

    Possible static configurations of liquids in rotating cylindrical containers with baffles evenly spaced in the axial direction are found. The force balance is among surface tension, centrifugal force and gravity. Two instabilities are found in this parameter space: type 1 is the inability of the liquid to form an interface attached to the baffles; type 2 is the inability for multi-baffled configurations to sustain interfaces between each pair of baffles. The type 1 analysis is confirmed through laboratory based equipment. Applications to orbiting containers are discussed.

  2. Liquid Motion in a Rotating Tank Experiment (LME)

    NASA Technical Reports Server (NTRS)

    Dodge, F. T.

    1992-01-01

    The Liquid Motion in Rotating Tank Experiment (LME) will investigate and quantify liquid motions occurring in spin-stabilized spacecraft; acquire representative data to validate ground-test scaling procedures; and obtain scientific understanding to formulate better analytical models. LME eliminates the limitations of ground testing. LME design is nearing the end of phase B: the breadboard hardware model has been completed; the load cells have been fabricated and tested; the experiment computer has been flight qualified; and other electronics have been breadboarded. Various aspects of this experiment are presented in viewgraph form.

  3. Investigation in Simulated Vertical Descent of the Characteristics of a Cargo-Dropping Device having Extensible Rotating Blades

    NASA Technical Reports Server (NTRS)

    Stone, Ralph W., Jr.; Hultz, Burton E.

    1949-01-01

    The characteristics of a cargo-dropping device having extensible rotating blades as load-carrying surfaces have been studied in simulated vertical descent in the Langley 20-foot free-spinning tunnel. The investigation included tests to determine the variation in vertical sinking speed with load. A study of the blade characteristics and of the test results indicated a method of dynamically balancing the blades to permit proper functioning of the device.

  4. Janus Gel Fabrication Using Liquid Drop Coalescence and Limited Mixing in the Hele-Shaw Geometry

    NASA Astrophysics Data System (ADS)

    Gonzalez, Brittany; Moran, Alexis; Lee, Donghee; Ryu, Sangjin

    2015-11-01

    Hydrogel substrates of tunable stiffness have been actively utilized for in vitro cell mechanobiology study. Here we present a new method to fabricate Janus polyacrylamide gel based on limited mixing between liquid drops coalescing in the Hele-Shaw geometry. Two pre-polymer drops with different concentrations were sandwiched and squeezed between two parallel glass surfaces. Once the drops coalesced in the decreased gap between the surfaces, gelation was initiated by UV light exposure with various time delays. AFM nano-indentation was utilized to map the Young's modulus of obtained gels. Fabricated Janus gels had two regions of different Young's moduli interfaced by the stiffness gradient zone, and the width of the gradient zone increased with the delay time. We acknowledge support from Bioengineering for Human Health grant from UNL and UNMC, and NSF REU grant for UNL.

  5. Single-drop liquid phase microextraction accelerated by surface acoustic wave.

    PubMed

    Zhang, Anliang; Zha, Yan

    2013-03-01

    A single-drop liquid phase microextraction method is presented, in which surface acoustic wave (SAW) is used for accelerating extraction speed. A pair of interdigital transducers with 27.5 MHz center frequency is fabricated on a 128° yx-LiNbO3 substrate. A radio frequency signal is applied to one of interdigital transducers to excite SAW. Plastic straw is filled with PDMS, leaving 1 mL for holding sample solution. Plastic straw with sample solution droplet is then dipping into extractant, into which SAW is radiated. Mass transportation from sample solution to extractant drop is accelerated due to acoustic streaming, and extraction time is decreased. An ionic liquid and an acid green-25 solution are used for extraction experiments. Results show that the extraction process is almost finished within 2 min, and extraction speed is increased with radio frequency signal power.

  6. Capillary flow as the cause of ring stains from dried liquid drops

    NASA Astrophysics Data System (ADS)

    Deegan, Robert D.; Bakajin, Olgica; Dupont, Todd F.; Huber, Greb; Nagel, Sidney R.; Witten, Thomas A.

    1997-10-01

    When a spilled drop of coffee dries on a solid surface, it leaves a dense, ring-like deposit along the perimeter (Fig. 1a). The coffee-initially dispersed over the entire drop-becomes concentrated into a tiny fraction of it. Such ring deposits are common wherever drops containing dispersed solids evaporate on a surface, and they influence processes such as printing, washing and coating. Ring deposits also provide a potential means to write or deposit a fine pattern onto a surface. Here we ascribe the characteristic pattern of the deposition to a form of capillary flow in which pinning of the contact line of the drying drop ensures that liquid evaporating from the edge is replenished by liquid from the interior. The resulting outward flow can carry virtually all the dispersed material to the edge. This mechanism predicts a distinctive power-law growth of the ring mass with time-a law independent of the particular substrate, carrier fluid or deposited solids. We have verified this law by microscopic observations of colloidal fluids.

  7. Impact of a single drop on the same liquid: formation, growth and disintegration of jets

    NASA Astrophysics Data System (ADS)

    Agbaglah, G. Gilou; Deegan, Robert

    2015-11-01

    One of the simplest splashing scenarios results from the impact of a single drop on on the same liquid. The traditional understanding of this process is that the impact generates a jet that later breaks up into secondary droplets. Recently it was shown that even this simplest of scenarios is more complicated than expected because multiple jets can be generated from a single impact event and there are bifurcations in the multiplicity of jets. First, we study the formation, growth and disintegration of jets following the impact of a drop on a thin film of the same liquid using a combination of numerical simulations and linear stability theory. We obtain scaling relations from our simulations and use these as inputs to our stability analysis. We also use experiments and numerical simulations of a single drop impacting on a deep pool to examine the bifurcation from a single jet into two jets. Using high speed X-ray imaging methods we show that vortex separation within the drop leads to the formation of a second jet long after the formation of the ejecta sheet.

  8. Getting in shape: molten wax drop deformation and solidification at an immiscible liquid interface.

    PubMed

    Beesabathuni, Shilpa N; Lindberg, Seth E; Caggioni, Marco; Wesner, Chris; Shen, Amy Q

    2015-05-01

    The controlled production of non-spherical shaped particles is important for many applications such as food processing, consumer goods, adsorbents, drug delivery, and optical sensing. In this paper, we investigated the deformation and simultaneous solidification of millimeter size molten wax drops as they impacted an immiscible liquid interface of higher density. By varying initial temperature and viscoelasticity of the molten drop, drop size, impact velocity, viscosity and temperature of the bath fluid, and the interfacial tension between the molten wax and bath fluid, spherical molten wax drops impinged on a cooling water bath and were arrested into non-spherical solidified particles in the form of ellipsoid, mushroom, disc, and flake-like shapes. We constructed cursory phase diagrams for the various particle shapes generated over a range of Weber, Capillary, Reynolds, and Stefan numbers, governed by the interfacial, inertial, viscous, and thermal effects. We solved a simplified heat transfer problem to estimate the time required to initiate the solidification at the interface of a spherical molten wax droplet and cooling aqueous bath after impact. By correlating this time with the molten wax drop deformation history captured from high speed imaging experiments, we elucidate the delicate balance of interfacial, inertial, viscous, and thermal forces that determine the final morphology of wax particles.

  9. Capillary Drop Penetration Method to Characterize the Liquid Wetting of Powders.

    PubMed

    Liu, Zhanjie; Wang, Yifan; Muzzio, Fernando J; Callegari, Gerardo; Drazer, German

    2017-01-10

    We present a method to characterize the wettability of powders, based on the penetration dynamics of a sessile drop deposited on a slightly compressed powder bed. First, we show that a direct comparison of the wetting properties of different liquids is possible without having to solve the three-dimensional liquid penetration problem, by considering the appropriate dimensionless variables. We show that the contact area between the sessile drop and the powder bed remains constant during most of the penetration process and demonstrate that as a result, the evolution of the dimensionless penetration volume is given by a universal function of the dimensionless time, with no dimensionless parameters. Then, using a reference liquid that completely wets the powder, it is possible to obtain an effective contact angle for a test liquid of interest, independent of other properties of the powder bed, such as permeability and a characteristic pore size. We apply the proposed method to estimate the contact angle of water with different powder blends, by using silicone oil as the reference liquid. Finally, to highlight the potential of the proposed method to characterize pharmaceutical powders, we consider a blend of lactose, acetaminophen, and a small amount of lubricant (magnesium stearate). The proposed method adequately captures a significant decrease in hydrophilicity that results from exposing the blend to excessive mixing, a well-known effect in the pharmaceutical industry.

  10. Spreading and mixing of drops on a miscible liquid of different surface tension

    NASA Astrophysics Data System (ADS)

    Afkhami, S.; Seric, I.; Kondic, L.; Kim, H.; Shardt, O.; Stone, H. A.

    2016-11-01

    We carry out Volume-of-Fluid based numerical simulations of a Marangoni-driven spreading of isopropyl alcohol (IPA) drops placed on water-air interface. The two fully miscible liquids create a spatially varying surface tension, leading to the spreading of the IPA drop on the water surface. We study the spreading of drops as IPA concentration is varied. In particular, we compute the spreading velocity and show that the scaling of the front position, L, with time, t, is given by L t 0 . 7 . We observe that while the surface tension difference between the two liquids controls the spreading velocity, it only slightly alters the power-law behavior for the range of considered IPA concentrations. We also provide detailed insight of the mixing of the IPA and water, and show the time evolution of liquid-air surface tension distribution. We show that the mixing results in a volume flux in a thin region on the surface, generating a vortical flow underneath the spreading front; we investigate the details of these flow patterns and show the time evolution of the circulation within the water. The numerical results are supported by new experimental observations reported separately.

  11. Single-drop impingement onto a wavy liquid film and description of the asymmetrical cavity dynamics

    NASA Astrophysics Data System (ADS)

    van Hinsberg, Nils Paul; Charbonneau-Grandmaison, Marie

    2015-07-01

    The present paper is devoted to an experimental investigation of the cavity formed upon a single-drop impingement onto a traveling solitary surface wave on a deep pool of the same liquid. The dynamics of the cavity throughout its complete expansion and receding phase are analyzed using high-speed shadowgraphy and compared to the outcomes of drop impingements onto steady liquid surface films having equal thickness. The effects of the surface wave velocity, amplitude and phase, drop impingement velocity, and liquid viscosity on the cavity's diameter and depth evolution are accurately characterized at various time instants. The wave velocity induces a distinct and in time increasing inclination of the cavity in the wave propagation direction. In particular for strong waves an asymmetrical distribution of the radial expansion and retraction velocity along the cavity's circumference is observed. A linear dependency between the absolute Weber number and the typical length and time scales associated with the cavity's maximum depth and maximum diameter is reported.

  12. Flow Straightener for a Rotating-Drum Liquid Separator

    NASA Technical Reports Server (NTRS)

    O'Coin, James R.; Converse, David G.; Rethke, Donald W.

    2004-01-01

    A flow straightener has been incorporated into a rotary liquid separator that originally comprised an inlet tube, a shroud plate, an impeller, an inner drum, an outer drum, a housing, a pitot tube, and a hollow shaft motor. As a consequence of the original geometry of the impeller, shroud, inner drum, and hollow shaft, swirl was created in the airflow inside the hollow shaft during operation. The swirl speed was large enough to cause a significant pressure drop. The flow straightener consists of vanes on the back side of the shroud plate. These vanes compartmentalize the inside of the inner drum in such a way as to break up the flow path and thereby stop the air from swirling; as a result, the air enters the hollow shaft with a predominantly axial velocity instead of a swirl. Tests of the rotary liquid separator at an airflow rate of 10 cu ft/min (0.0047 cu m/s) revealed that the dynamic pressure drop was 8 in. of water (approx.=2 kPa) in the absence of the flow straightener and was reduced to 1 in. of water (approx.=0.25 kPa) in the presence of the flow straightener.

  13. Liquid drops on a surface: Using density functional theory to calculate the binding potential and drop profiles and comparing with results from mesoscopic modelling

    NASA Astrophysics Data System (ADS)

    Hughes, Adam P.; Thiele, Uwe; Archer, Andrew J.

    2015-02-01

    The contribution to the free energy for a film of liquid of thickness h on a solid surface due to the interactions between the solid-liquid and liquid-gas interfaces is given by the binding potential, g(h). The precise form of g(h) determines whether or not the liquid wets the surface. Note that differentiating g(h) gives the Derjaguin or disjoining pressure. We develop a microscopic density functional theory (DFT) based method for calculating g(h), allowing us to relate the form of g(h) to the nature of the molecular interactions in the system. We present results based on using a simple lattice gas model, to demonstrate the procedure. In order to describe the static and dynamic behaviour of non-uniform liquid films and drops on surfaces, a mesoscopic free energy based on g(h) is often used. We calculate such equilibrium film height profiles and also directly calculate using DFT the corresponding density profiles for liquid drops on surfaces. Comparing quantities such as the contact angle and also the shape of the drops, we find good agreement between the two methods. We also study in detail the effect on g(h) of truncating the range of the dispersion forces, both those between the fluid molecules and those between the fluid and wall. We find that truncating can have a significant effect on g(h) and the associated wetting behaviour of the fluid.

  14. Application of dispersive liquid-liquid-solidified floating organic drop microextraction and ETAAS for the preconcentration and determination of indium.

    PubMed

    Ashrafzadeh Afshar, Elham; Taher, Mohammad Ali; Fazelirad, Hamid; Naghizadeh, Matin

    2017-03-01

    A new, simple and efficient method, including dispersive liquid-liquid-solidified floating organic drop microextraction and then electrothermal atomic absorption spectrometry, has been developed for the preconcentration and determination of ultratrace amounts of indium. The method was applied to preconcentrate the indium-1-(2-pyridylazo)-2-naphthol complex in 25 μL 1-undecanol. The various factors affecting the extraction efficiency, such as pH, type and volume of extraction solvent, type and volume of disperser solvent, sample volume, ionic strength, and ligand concentration, were investigated and optimized. Under the optimum conditions, an enrichment factor of 62.5, precision of ±4.75%, a detection limit of 55.6 ng L(-1), and for the calibration graph a linear range of 96.0-3360 ng L(-1) were obtained. The method was used for the extraction and determination of indium in water and standard samples with satisfactory results. Graphical Abstract Preconcentration of indium ions via liquid-liquid-solidified floating organic drop microextraction method and determination by ETAAS.

  15. Development of dispersive liquid-liquid microextraction based on solidification of floating organic drop for the determination of trace nickel.

    PubMed

    Wang, Yukun; Zhang, Jingwen; Zhao, Bin; Du, Xin; Ma, Jingjun; Li, Jingci

    2011-12-01

    A liquid-phase microextraction technique was developed using dispersive liquid-liquid microextraction based on solidification of floating organic drop combined with flame atomic absorption spectrometry, for the extraction and determination of trace amounts of nickel in water samples. Microextraction efficiency factors, such as the type and volume of extraction and dispersive solvents, pH, extraction time, the chelating agent amount, and ionic strength, were investigated and optimized. Under optimum conditions, the calibration graph was linear in the range of 4.23-250 μg L(-1) with a detection limit of 1.27 μg L(-1). The relative standard deviation for ten replicate measurements of 10 and 100 μg L(-1) of nickel were 3.21% and 2.55%, respectively. The proposed method was assessed through the analysis of certified reference water or recovery experiments.

  16. Micro-ball lens structure fabrication based on drop on demand printing the liquid mold

    NASA Astrophysics Data System (ADS)

    Zhu, Xiaoyang; Zhu, Li; Chen, Hejuan; Yang, Lijun; Zhang, Weiyi

    2016-01-01

    In this paper, we demonstrated a simple micro-ball lens array (MBLA) fabrication method using a drop-on-demand (DOD) droplet printing technique and liquid mold. The micro-ball droplet array on the hydrophobic surface is used as the liquid mold to fabricate the MBLA. The ultrahigh adhesion force between the micro-ball droplet and the substrate is ascribed to the Wenzel state of the micro-ball droplet, while the replication process with low position error is attributed to the ultrahigh adhesion force between the micro-ball droplet and the substrate and the high viscosity of the micro-ball droplet and polydimethylsiloxane (PDMS) liquid. The micro-ball lenses (MBLs) with a contact angle of 120° and 150° were fabricated and the important fabrication details were discussed. The optical performance and scanning electron microscope (SEM) data of the MBLs showed that the MBLs had high quality surface morphology and good optical performance.

  17. Headspace liquid-phase microextraction of methamphetamine and amphetamine in urine by an aqueous drop.

    PubMed

    He, Yi; Vargas, Angelica; Kang, Youn-Jung

    2007-04-25

    This study developed a headspace liquid-phase microextraction (LPME) method by using a single aqueous drop in combination with high performance liquid chromatography (HPLC)-UV detection for the determination of methamphetamine (MAP) and amphetamine (AP) in urine samples. The analytes, volatile and basic, were released from sample matrix into the headspace first, and then protonated and dissolved in an aqueous H(3)PO(4) drop hanging in the headspace by a HPLC syringe. After extraction, this drop was directly injected into HPLC. Parameters affecting extraction efficiency were investigated and optimized. This method showed good linearity in the investigated concentration range of 1.0-1500 microg L(-1), repeatability of the extraction (R.S.D.<5%, n=6), and low detection limits (0.3 microg L(-1) for both analytes). Enrichment factors of about 400-fold and 220-fold were achieved for MAP and AP, respectively, at optimum conditions. The feasibility of the method was demonstrated by analyzing human urine samples.

  18. Collision and coalescence of liquid drops in a dynamically active ambient fluid

    NASA Astrophysics Data System (ADS)

    Sambath, Krishnaraj; Subramani, Hariprasad; Basaran, Osman

    2012-11-01

    The fluid dynamics of the collision and coalescence of liquid drops has intrigued scientists and engineers for more than a century owing to its ubiquitousness in nature, e.g. raindrop coalescence, and industry, e.g. breaking of emulsions in the oil and gas industry. The complexity of the underlying dynamics, e.g. occurrence of hydrodynamic singularities, has required study of the problem at different scales - macroscopic, mesoscopic and molecular - using stochastic and deterministic methods. In this work, we adopt a multiscale, deterministic method to simulate the approach, collision, and eventual coalescence of two drops where the drops as well as the ambient fluid are incompressible, Newtonian fluids. The free boundary problem governing the dynamics consists of the Navier-Stokes system and associated initial and boundary conditions that have been augmented to account for the effects of disjoining pressure as the separation between the drops becomes of the order of a few hundred nanometers. This free boundary problem is solved by a Galerkin finite element-based algorithm. The approach and results to be reported build on earlier work by Leal and coworkers, and are used to identify conditions conducive for coalescence in terms of flow and fluid properties.

  19. Measurement of lateral adhesion forces at the interface between a liquid drop and a substrate.

    PubMed

    Tadmor, Rafael; Bahadur, Prashant; Leh, Aisha; N'guessan, Hartmann E; Jaini, Rajiv; Dang, Lan

    2009-12-31

    A novel instrument allows for the first time measurements of the lateral adhesion forces at a solid-liquid interface, f(parallel), in a way that is decoupled from the normal forces, f(perpendicular). We use it to measure how f(parallel) between a drop and a surface is influenced by different f(perpendicular) and different histories of drop resting periods on the surface prior to sliding, t(rest). The variation of f(parallel) with t(rest) is similar for different f(perpendicular) and always plateaus as t(rest)-->infinity. We show that the f(parallel) plateau value is higher when f(perpendicular) is lower. This seemingly counterintuitive result is in agreement with recent theories.

  20. Carbon dioxide in an ionic liquid: Structural and rotational dynamics

    NASA Astrophysics Data System (ADS)

    Giammanco, Chiara H.; Kramer, Patrick L.; Yamada, Steven A.; Nishida, Jun; Tamimi, Amr; Fayer, Michael D.

    2016-03-01

    Ionic liquids (ILs), which have widely tunable structural motifs and intermolecular interactions with solutes, have been proposed as possible carbon capture media. To inform the choice of an optimal ionic liquid system, it can be useful to understand the details of dynamics and interactions on fundamental time scales (femtoseconds to picoseconds) of dissolved gases, particularly carbon dioxide (CO2), within the complex solvation structures present in these uniquely organized materials. The rotational and local structural fluctuation dynamics of CO2 in the room temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EmimNTf2) were investigated by using ultrafast infrared spectroscopy to interrogate the CO2 asymmetric stretch. Polarization-selective pump probe measurements yielded the orientational correlation function of the CO2 vibrational transition dipole. It was found that reorientation of the carbon dioxide occurs on 3 time scales: 0.91 ± 0.03, 8.3 ± 0.1, 54 ± 1 ps. The initial two are attributed to restricted wobbling motions originating from a gating of CO2 motions by the IL cations and anions. The final (slowest) decay corresponds to complete orientational randomization. Two-dimensional infrared vibrational echo (2D IR) spectroscopy provided information on structural rearrangements, which cause spectral diffusion, through the time dependence of the 2D line shape. Analysis of the time-dependent 2D IR spectra yields the frequency-frequency correlation function (FFCF). Polarization-selective 2D IR experiments conducted on the CO2 asymmetric stretch in the parallel- and perpendicular-pumped geometries yield significantly different FFCFs due to a phenomenon known as reorientation-induced spectral diffusion (RISD), revealing strong vector interactions with the liquid structures that evolve slowly on the (independently measured) rotation time scales. To separate the RISD contribution to the FFCF from the structural spectral

  1. A new method for measuring the dynamic surface tension of complex-mixture liquid drops

    SciTech Connect

    Zhang, X.; Harris, M.T.; Basaran, O.A.

    1994-06-29

    A simple and accurate technique has been developed for measuring dynamic surface tension. The new technique is based on growing a drop at the end of a fine capillary into another immiscible fluid and can follow the changes in tension at a freshly formed interface during its entire period of evolution. When the relative importance of the surface tension force is large compared to gravitational and viscous forces, shapes of growing drops are sections of spheres and the difference in pressure between the interior and the exterior of the drop {triangle}p is related to the surface tension {sigma} and the radius of curvature R by the static Young-Laplace formula {triangle}p = 2{sigma}/R. In contrast to related work, the new technique can determine the surface tension of an interface with a surface age of a few to tens of milliseconds by measuring transient drop shapes and pressures in 1/6 to 1 millisecond. The capabilities of the new method are demonstrated by performing tension measurements on liquid systems that do not exhibit dynamic surface tension as well as ones that exhibit significant dynamic tension effects. Tension measurements made with surfactant-laden solutions show that variation of surface tension is nonmonotonic in time. In such systems, the dynamic behavior of surface tension is shown to depend upon both the rate of interfacial dilatation and that of surfactant transport. A maximum in the surface tension is attained when the lowering of the surfactant concentration on the drop interface due to its dilatation is balanced by the addition of fresh surfactant to the interface by convection and diffusion.

  2. Simple Verification of the Parabolic Shape of a Rotating Liquid and a Boat on Its Surface

    ERIC Educational Resources Information Center

    Sabatka, Z.; Dvorak, L.

    2010-01-01

    This article describes a simple and inexpensive way to create and to verify the parabolic surface of a rotating liquid. The liquid is water. The second part of the article deals with the problem of a boat on the surface of a rotating liquid. (Contains 1 table, 10 figures and 5 footnotes.)

  3. Dynamic response of a thin sessile drop of conductive liquid to an abruptly applied or removed electric field.

    PubMed

    Corson, L T; Mottram, N J; Duffy, B R; Wilson, S K; Tsakonas, C; Brown, C V

    2016-10-01

    We consider, both theoretically and experimentally, a thin sessile drop of conductive liquid that rests on the lower plate of a parallel-plate capacitor. We derive analytical expressions for both the initial deformation and the relaxation dynamics of the drop as the electric field is either abruptly applied or abruptly removed, as functions of the geometrical, electrical, and material parameters, and investigate the ranges of validity of these expressions by comparison with full numerical simulations. These expressions provide a reasonable description of the experimentally measured dynamic response of a drop of conductive ionic liquid 1-butyl-3-methyl imidazolium tetrafluoroborate.

  4. Dynamic response of a thin sessile drop of conductive liquid to an abruptly applied or removed electric field

    NASA Astrophysics Data System (ADS)

    Corson, L. T.; Mottram, N. J.; Duffy, B. R.; Wilson, S. K.; Tsakonas, C.; Brown, C. V.

    2016-10-01

    We consider, both theoretically and experimentally, a thin sessile drop of conductive liquid that rests on the lower plate of a parallel-plate capacitor. We derive analytical expressions for both the initial deformation and the relaxation dynamics of the drop as the electric field is either abruptly applied or abruptly removed, as functions of the geometrical, electrical, and material parameters, and investigate the ranges of validity of these expressions by comparison with full numerical simulations. These expressions provide a reasonable description of the experimentally measured dynamic response of a drop of conductive ionic liquid 1-butyl-3-methyl imidazolium tetrafluoroborate.

  5. Effect of ice contamination of liquid-nitrogen drops in film boiling

    NASA Technical Reports Server (NTRS)

    Schoessow, G. J.; Chmielewski, C. E.; Baumeister, K. J.

    1977-01-01

    Previously reported vaporization time data of liquid nitrogen drops in film boiling on a flat plate are about 30 percent shorter than predicted from standard laminar film boiling theory. This theory, however, had been found to successfully correlate the data for conventional fluids such as water, ethanol, benzene, or carbon tetrachloride. Experimental evidence that some of the discrepancy for cryogenic fluids results from ice contamination due to condensation is presented. The data indicate a fairly linear decrease in droplet evaporation time with the diameter of the ice crystal residue. After correcting the raw data for ice contamination along with convection, a comparison of theory with experiment shows good agreement.

  6. Effect of ice contamination on liquid-nitrogen drops in film boiling

    NASA Technical Reports Server (NTRS)

    Schoessow, G. J.; Chmielewski, C. E.; Baumeister, K. J.

    1977-01-01

    Previously reported vaporization time data of liquid nitrogen drops in film boiling on a flat plate are about 30 percent shorter than predicted from standard laminar film boiling theory. This theory, however, had been found to successfully correlate the data for conventional fluids such as water, ethanol, benzene, or carbon tetrachloride. This paper presents experimental evidence that some of the discrepancy for cryogenic fluids results from ice contamination due to condensation. The data indicate a fairly linear decrease in droplet evaporation time with the diameter of the ice crystal residue. After correcting the raw data for ice contamination along with convection, a comparison of theory with experiment shows good agreement.

  7. Capillary forces exerted by liquid drops caught between crossed cylinders. A 3-D meniscus problem with free contact line

    NASA Technical Reports Server (NTRS)

    Patzek, T. W.; Scriven, L. E.

    1982-01-01

    The Young-Laplace equation is solved for three-dimensional menisci between crossed cylinders, with either the contact line fixed or the contact angle prescribed, by means of the Galerkin/finite element method. Shapes are computed, and with them the practically important quantities: drop volume, wetted area, capillary pressure force, surface tension force, and the total force exerted by the drop on each cylinder. The results show that total capillary force between cylinders increases with decreasing contact angle, i.e. with better wetting. Capillary force is also increases with decreasing drop volume, approaching an asymptotic limit. However, the wetted area on each cylinder decreases with decreasing drop volume, which raises the question of the optimum drop volume to strive for, when permanent bonding is sought from solidified liquid. For then the strength of the bond is likely to depend upon the area of contact, which is the wetted area when the bonding agent was introduced in liquid form.

  8. Liquid-bridge breakup in contact-drop dispensing: Liquid-bridge stability with a free contact line.

    PubMed

    Akbari, Amir; Hill, Reghan J; van de Ven, Theo G M

    2015-08-01

    The static stability of weightless liquid bridges with a free contact line with respect to axisymmetric and nonaxisymmetric perturbations is studied. Constant-volume and constant-pressure stability regions are constructed in slenderness versus cylindrical volume diagrams for fixed contact angles. Bifurcations along the stability-region boundaries are characterized by the structure of axisymmetric bridge branches and families of equilibria. A wave-number definition is presented based on the pieces-of-sphere states at branch terminal points to classify equilibrium branches and identify branch connections. Compared with liquid bridges pinned at two equal disks, the free contact line breaks the equatorial and reflective symmetries, affecting the lower boundary of the constant-volume stability region where axisymmetric perturbations are critical. Stability is lost at transcritical bifurcations and turning points along this boundary. Our results furnish the maximum-slenderness stability limit for drop deposition on real surfaces when the contact angle approaches the receding contact angle.

  9. Liquid-bridge breakup in contact-drop dispensing: Liquid-bridge stability with a free contact line

    NASA Astrophysics Data System (ADS)

    Akbari, Amir; Hill, Reghan J.; van de Ven, Theo G. M.

    2015-08-01

    The static stability of weightless liquid bridges with a free contact line with respect to axisymmetric and nonaxisymmetric perturbations is studied. Constant-volume and constant-pressure stability regions are constructed in slenderness versus cylindrical volume diagrams for fixed contact angles. Bifurcations along the stability-region boundaries are characterized by the structure of axisymmetric bridge branches and families of equilibria. A wave-number definition is presented based on the pieces-of-sphere states at branch terminal points to classify equilibrium branches and identify branch connections. Compared with liquid bridges pinned at two equal disks, the free contact line breaks the equatorial and reflective symmetries, affecting the lower boundary of the constant-volume stability region where axisymmetric perturbations are critical. Stability is lost at transcritical bifurcations and turning points along this boundary. Our results furnish the maximum-slenderness stability limit for drop deposition on real surfaces when the contact angle approaches the receding contact angle.

  10. Preliminary drop-tower experiments on liquid-interface geometry in partially filled containers at zero gravity

    NASA Technical Reports Server (NTRS)

    Smedley, G.

    1990-01-01

    Plexiglass containers with rounded trapezoidal cross sections were designed and built to test the validity of Concus and Finn's existence theorem (1974, 1983) for a bounded free liquid surface at zero gravity. Experiments were carried out at the NASA Lewis two-second drop tower. Dyed ethanol-water solutions and three immiscible liquid pairs, with one liquid dyed, were tested. High-speed movies were used to record the liquid motion. Liquid rose to the top of the smaller end of the containers when the contact angle was small enough, in agreement with the theory. Liquid interface motion demonstrated a strong dependence on physical properties, including surface roughness and contamination.

  11. Pressure drop in fully developed, turbulent, liquid-vapor annular flows in zero gravity

    NASA Technical Reports Server (NTRS)

    Sridhar, K. R.; Chao, B. T.; Soo, S. L.

    1992-01-01

    The prediction of frictional pressure drop in fully developed, turbulent, annular liquid-vapor flows in zero gravity using simulation experiments conducted on earth is described. The scheme extends the authors' earlier work on dispersed flows. The simulation experiments used two immiscible liquids of identical density, namely, water and n-butyl benzoate. Because of the lack of rigorous analytical models for turbulent, annular flows, the proposed scheme resorts to existing semiempirical correlations. Results based on two different correlations are presented and compared. Others may be used. It was shown that, for both dispersed and annular flow regimes, the predicted frictional pressure gradients in 0-g are lower than those in 1-g under otherwise identical conditions. The physical basis for this finding is given.

  12. Effects of polymers on the rotational viscosities of nematic liquid crystals and dynamics of field alignment

    SciTech Connect

    Kim, D.

    1993-12-31

    Many of the important physical phenomena exhibited by the nematic phase, such as its unusual flow properties and its responses to the electric and the magnetic fields, can be discussed regarding it as a continous medium. The Leslie-Erickson dynamic theory has the six dissipative coefficients from continuum model of liquid crystal. Parodi showed that only five of them are independent, when Onsagar`s reciprocal relations are used. One of these, which has no counterpart in the isotropic liquids, is the rotational viscosity co-efficient, {gamma}{sub 1}. The main objective of this project is to study the rotational viscosities of selected micellar nematic systems and the effect of dissolved polymers in micellar and thermotropic liqud crystals. We used rotating magnetic field method which allows one to determine {gamma}{sub 1} and the anisotropic magnetic susceptibility, {chi}{sub a}. For the ionic surfactant liquid crystals of SDS and KL systems used in this study, the rotational viscosity exhibited an extraordinary drop after reaching the highest values {gamma}{sub 1} as the temperature was lowered. This behavior is not observed in normal liquid crystals. But this phenomena can be attributed to the existence of nematic biaxial phase below the rod-like nematic N{sub c} phase. The pretransitional increase in {gamma}{sub 1} near the disk-like nematic to smectic-A phase transition of the pure CsPFO/H{sub 2}O systems are better understood with the help of mean-field models of W.L. McMillan. He predicted a critical exponent {nu} = {1/2} for the divergence of {gamma}{sub 1}. The polymer (PEO, molecular weight = 10{sup 5}) dissolved in CsPFO/H{sub 2}O system (which has 0.6% critical polymer concentration), suppressed the nematic to lamellar smectic phase transition in concentrated polymer solutions (0.75% and higher). In dilute polymer solutions with lower than 0.3% polyethylene-oxide, a linear increase of {gamma}{sub 1} is observed, which agrees with Brochard theory.

  13. Bubble pinch-off and scaling during liquid drop impact on liquid pool

    NASA Astrophysics Data System (ADS)

    Ray, Bahni; Biswas, Gautam; Sharma, Ashutosh

    2012-08-01

    Simulations are performed to show entrapment of air bubble accompanied by high speed upward and downward water jets when a water drop impacts a pool of water surface. A new bubble entrapment zone characterised by small bubble pinch-off and long thick jet is found. Depending on the bubble and jet behaviour, the bubble entrapment zone is subdivided into three sub-regimes. The entrapped bubble size and jet height depends on the crater shape and its maximum depth. During the bubble formation, bubble neck develops an almost singular shape as it pinches off. The final pinch-off shape and the power law governing the pinching, rneck ∝ A(t0 - t)αvaries with the Weber number. Weber dependence of the function describing the radius of the bubble during the pinch-off only affects the coefficient A and not the power exponent α.

  14. Uptake of Nitric Acid, Dinitrogen Pentoxide, Ozone and The Nitrate Radical On A Single Liquid Drop

    NASA Astrophysics Data System (ADS)

    Schütze, M.; Herrmann, H.

    A novel technique for the investigation of uptake processes on gas-liquid interfaces will be presented. It allows the generation and analysis of single liquid drops inside a flow tube reactor. The in situ analysis of the drop is performed by broad band UV-VIS absorption spectroscopy. Using this set-up the uptake of nitric acid and dinitrogen pentoxide on pure water was measured by monitoring the occurrence of the nitrate band centered at a wavelength of 300 nm. The uptake of ozone on NaI solutions of various concentrations was followed by the formation of the triiodide ion which is a product of the oxidation of iodide by ozone. Using aqueous solutions of the dye Alizarin Red S, the uptake of the nitrate radical could be quantified. In order to extract information on fundamental parameters, e.g. the mass accommo- dation coefficients (= a) of the species, a computer model is applied. It solves the diffusion equation for the transport of gas phase species to the interface numerically. The result is a separation of the influence of this process on the rate of the overall uptake process. The mass accommodation coefficients a > 0.03, a = 0.011 and a > 0.02 were obtained for nitric acid, dinitrogen pentoxide and ozone, respectively.

  15. A continuous film-recirculable drop gas-liquid equilibration device. Measurement of trace gaseous ammonia

    PubMed

    Genfa; Dasgupta

    2000-07-15

    A miniature gas-liquid equilibrator or a gas collector, intended as a low-volume interface between a soluble gaseous sample and a liquid phase analyzer or between a liquid phase sample and a detector designed for use with gas samples, is described. This paper addresses the application of the device for the measurement of trace atmospheric ammonia. Gas collection occurs solely by diffusive sampling such that aerosol particles are not collected. The device essentially consists of a tube surrounded externally by a jacket. Gas flows through the jacket and contacts a liquid film flowing on the surface of the tube. The flowing film forms a drop at the tube terminus and is aspirated off through the inner bore of the tube. The collected analyte can be (a) directly sent to an analysis system or (b) preconcentrated on a suitable stationary phase; the preconcentrator effluent can be recycled, if desired. With a fluorometric flow injection analysis system harnessed to measure ammonia with such a collector, the limit of detection (LOD, S/N = 3) for a sample drawn for 18 min at 200 mL/min was 4.5 parts per trillion by volume, with the linear range extending up to 30 parts per billion.

  16. Turbulent Convection in a Rotating Sphere Filled With Liquid Metal

    NASA Astrophysics Data System (ADS)

    Nataf, H.; Aubert, J.; Cardin, P.; Brito, D.; Masson, J.

    2001-12-01

    Understanding the organization of turbulent convective motions in a rotating sphere would help building more realistic models of the geodynamo and solar dynamo. We have performed laboratory experiments using water and gallium as working fluids. We have examined the convective structures that form by following the time--variation of velocity profiles measured by Doppler ultrasonic velocimetry and investigated their dynamical behaviour by monitoring the amplitude of velocity as a function of the Prandtl, Rayleigh and Ekman numbers. Our most striking result is that a strong zonal flow develops in liquid gallium (Prandtl number of 0.025). It can be 2.5 times stronger than typical convective velocities. We explain this phenomenon by the high Reynolds numbers reached in these experiments, up to 2000, much larger than in the water experiments (less than 250). Our observations for gallium are well accounted for by a quasi--geostrophic inertial model, in which kinetic energy is injected at the convective scale and cascades up to a large zonal flow, whose amplitude is limited by friction on the outer sphere. This model predicts that the convective velocity U becomes independent of the two diffusivities (viscous and thermal) and scales as : $ U ~ D Ω ( (α g Q)/(ρ CP Ω 3 D2) )2/5 where D is the thickness of the liquid shell, \\Omega the rotation rate, Q the heat flux, g the gravity acceleration, and \\alpha, \\rho and C_P$ are the thermal expansion coefficient, the density and the heat capacity of the liquid. The sphericity also introduces a variation of velocity with radius. Both the scaling law and these radial variations are in very good agreement with the measured velocity profiles. In contrast, the zonal velocity does depend upon the viscosity of the liquid through friction on the outer boundary. This behaviour illustrates the crucial role of the spherical boundaries in controlling the organization of turbulence. Nevertheless, the motions remain essentially two

  17. A comprehensive analysis of the evaporation of a liquid spherical drop.

    PubMed

    Sobac, B; Talbot, P; Haut, B; Rednikov, A; Colinet, P

    2015-01-15

    In this paper, a new comprehensive analysis of a suspended drop of a pure liquid evaporating into air is presented. Based on mass and energy conservation equations, a quasi-steady model is developed including diffusive and convective transports, and considering the non-isothermia of the gas phase. The main original feature of this simple analytical model lies in the consideration of the local dependence of the physico-chemical properties of the gas on the gas temperature, which has a significant influence on the evaporation process at high temperatures. The influence of the atmospheric conditions on the interfacial evaporation flux, molar fraction and temperature is investigated. Simplified versions of the model are developed to highlight the key mechanisms governing the evaporation process. For the conditions considered in this work, the convective transport appears to be opposed to the evaporation process leading to a decrease of the evaporation flux. However, this effect is relatively limited, the Péclet numbers happening to be small. In addition, the gas isothermia assumption never appears to be valid here, even at room temperature, due to the large temperature gradient that develops in the gas phase. These two conclusions are explained by the fact that heat transfer from the gas to the liquid appears to be the step limiting the evaporation process. Regardless of the complexity of the developed model, yet excluding extremely small droplets, the square of the drop radius decreases linearly over time (R(2) law). The assumptions of the model are rigorously discussed and general criteria are established, independently of the liquid-gas couple considered.

  18. Not spreading in reverse: The dewetting of a liquid film into a single drop.

    PubMed

    Edwards, Andrew M J; Ledesma-Aguilar, Rodrigo; Newton, Michael I; Brown, Carl V; McHale, Glen

    2016-09-01

    Wetting and dewetting are both fundamental modes of motion of liquids on solid surfaces. They are critically important for processes in biology, chemistry, and engineering, such as drying, coating, and lubrication. However, recent progress in wetting, which has led to new fields such as superhydrophobicity and liquid marbles, has not been matched by dewetting. A significant problem has been the inability to study the model system of a uniform film dewetting from a nonwetting surface to a single macroscopic droplet-a barrier that does not exist for the reverse wetting process of a droplet spreading into a film. We report the dewetting of a dielectrophoresis-induced film into a single equilibrium droplet. The emergent picture of the full dewetting dynamics is of an initial regime, where a liquid rim recedes at constant speed and constant dynamic contact angle, followed by a relatively short exponential relaxation of a spherical cap shape. This sharply contrasts with the reverse wetting process, where a spreading droplet follows a smooth sequence of spherical cap shapes. Complementary numerical simulations and a hydrodynamic model reveal a local dewetting mechanism driven by the equilibrium contact angle, where contact line slip dominates the dewetting dynamics. Our conclusions can be used to understand a wide variety of processes involving liquid dewetting, such as drop rebound, condensation, and evaporation. In overcoming the barrier to studying single film-to-droplet dewetting, our results provide new approaches to fluid manipulation and uses of dewetting, such as inducing films of prescribed initial shapes and slip-controlled liquid retraction.

  19. Not spreading in reverse: The dewetting of a liquid film into a single drop

    PubMed Central

    Edwards, Andrew M. J.; Ledesma-Aguilar, Rodrigo; Newton, Michael I.; Brown, Carl V.; McHale, Glen

    2016-01-01

    Wetting and dewetting are both fundamental modes of motion of liquids on solid surfaces. They are critically important for processes in biology, chemistry, and engineering, such as drying, coating, and lubrication. However, recent progress in wetting, which has led to new fields such as superhydrophobicity and liquid marbles, has not been matched by dewetting. A significant problem has been the inability to study the model system of a uniform film dewetting from a nonwetting surface to a single macroscopic droplet—a barrier that does not exist for the reverse wetting process of a droplet spreading into a film. We report the dewetting of a dielectrophoresis-induced film into a single equilibrium droplet. The emergent picture of the full dewetting dynamics is of an initial regime, where a liquid rim recedes at constant speed and constant dynamic contact angle, followed by a relatively short exponential relaxation of a spherical cap shape. This sharply contrasts with the reverse wetting process, where a spreading droplet follows a smooth sequence of spherical cap shapes. Complementary numerical simulations and a hydrodynamic model reveal a local dewetting mechanism driven by the equilibrium contact angle, where contact line slip dominates the dewetting dynamics. Our conclusions can be used to understand a wide variety of processes involving liquid dewetting, such as drop rebound, condensation, and evaporation. In overcoming the barrier to studying single film-to-droplet dewetting, our results provide new approaches to fluid manipulation and uses of dewetting, such as inducing films of prescribed initial shapes and slip-controlled liquid retraction. PMID:27704042

  20. Energy Budget of Liquid Drop Impact at Maximum Spreading: Numerical Simulations and Experiments.

    PubMed

    Lee, Jae Bong; Derome, Dominique; Dolatabadi, Ali; Carmeliet, Jan

    2016-02-09

    The maximum spreading of an impinging droplet on a rigid surface is studied for low to high impact velocity, until the droplet starts splashing. We investigate experimentally and numerically the role of liquid properties, such as surface tension and viscosity, on drop impact using three liquids. It is found that the use of the experimental dynamic contact angle at maximum spreading in the Kistler model, which is used as a boundary condition for the CFD-VOF calculation, gives good agreement between experimental and numerical results. Analytical models commonly used to predict the boundary layer thickness and time at maximum spreading are found to be less correct, meaning that energy balance models relying on these relations have to be considered with care. The time of maximum spreading is found to depend on both the impact velocity and surface tension, and neither dependency is predicted correctly in common analytical models. The relative proportion of the viscous dissipation in the total energy budget increases with impact velocity with respect to surface energy. At high impact velocity, the contribution of surface energy, even before splashing, is still substantial, meaning that both surface energy and viscous dissipation have to be taken into account, and scaling laws depending only on viscous dissipation do not apply. At low impact velocity, viscous dissipation seems to play an important role in low-surface-tension liquids such as ethanol.

  1. Determining the Drag Coefficient of Rotational Symmetric Objects Falling through Liquids

    ERIC Educational Resources Information Center

    Houari, Ahmed

    2012-01-01

    I will propose here a kinematic approach for measuring the drag coefficient of rotational symmetric objects falling through liquids. For this, I will show that one can obtain a measurement of the drag coefficient of a rotational symmetric object by numerically solving the equation of motion describing its fall through a known liquid contained in a…

  2. Alpha and light nucleus emission within a generalized liquid drop model

    NASA Astrophysics Data System (ADS)

    Royer, G.; Bonilla, C.; Moustabchir, R.

    2002-11-01

    The potential energy governing the spontaneous α, C, O, F, Ne, Mg and Si emissions has been determined within a generalized liquid drop model including the proximity effects between the emitted light nucleus and the daughter one and taking into account empirically the experimental Q value. The decay path has been described by a quasi-molecular shape sequence leading rapidly to two spherical touching nuclei before crossing the barrier. The partial half-lives deduced from the WKB barrier penetration probabability are in very good agreement with experimental data and accurate analytical expressions are proposed. The partial half-lives of the Be, Li, He and H sub-barrier emissions have been calculated by adding an excitation energy to the Q value and new formulae are given.

  3. Determination of benzalkonium chloride in viscous ophthalmic drops of azithromycin by high-performance liquid chromatography *

    PubMed Central

    Shen, Yan; Xu, Sheng-jie; Wang, Shi-chun; Tu, Jia-sheng

    2009-01-01

    A high-performance liquid chromatography (HPLC) system was used in the reversed phase mode for the determination of benzalkonium chloride (BKC) in azithromycin viscous ophthalmic drops. A Venusil-XBP(L)-C18 (150 mm×4.6 mm, 5 μm) column was used at 50 °C. The mobile phase consisted of a mixture of methanol-potassium phosphate (16:5, v/v). Two sample preparation methods were compared. The results suggested that, compared with an extraction procedure, a deproteinization procedure was much quicker and more convenient. Using the deproteinization procedure for sample preparation, calibration curves were linear in the range 5.0~50 μg/ml. The within-day and inter-day coefficients of variation were less than 10%. The average recoveries were determined as 96.70%, 98.52%, and 97.96% at concentrations of 10.0, 30.0, and 50.0 μg/ml, respectively. Variability in precision did not exceed 5%. In conclusion, this HPLC method using a simple sample treatment procedure appears suitable for monitoring BKC content in azithromycin viscous ophthalmic drops. PMID:19946951

  4. Determination of benzalkonium chloride in viscous ophthalmic drops of azithromycin by high-performance liquid chromatography.

    PubMed

    Shen, Yan; Xu, Sheng-jie; Wang, Shi-chun; Tu, Jia-sheng

    2009-12-01

    A high-performance liquid chromatography (HPLC) system was used in the reversed phase mode for the determination of benzalkonium chloride (BKC) in azithromycin viscous ophthalmic drops. A Venusil-XBP(L)-C(18) (150 mmx4.6 mm, 5 microm) column was used at 50 degrees C. The mobile phase consisted of a mixture of methanol-potassium phosphate (16:5, v/v). Two sample preparation methods were compared. The results suggested that, compared with an extraction procedure, a deproteinization procedure was much quicker and more convenient. Using the deproteinization procedure for sample preparation, calibration curves were linear in the range 5.0 to approximately 50 microg/ml. The within-day and inter-day coefficients of variation were less than 10%. The average recoveries were determined as 96.70%, 98.52%, and 97.96% at concentrations of 10.0, 30.0, and 50.0 microg/ml, respectively. Variability in precision did not exceed 5%. In conclusion, this HPLC method using a simple sample treatment procedure appears suitable for monitoring BKC content in azithromycin viscous ophthalmic drops.

  5. Effects of Polymers on the Rotational Viscosities of Nematic Liquid Crystals and Dynamics of Field Alignment.

    NASA Astrophysics Data System (ADS)

    Kim, Du-Rim

    Many of the important physical phenomena exhibited by the nematic phase, such as its unusual flow properties and its responses to the electric and the magnetic fields, can be discussed regarding it as a continuous medium. The Leslie-Erickson dynamic theory has the six dissipative coefficients from continuum model of liquid crystal. Parodi showed that only five of them are independent, when Onsagar's reciprocal relations are used. One of these, which has no counterpart in the isotropic liquids, is the rotational viscosity coefficient, gamma_1. The main objective of this project is to study the rotational viscosities of selected micellar nematic systems and the effect of dissolved polymers in micellar and thermotropic liquid crystals. We used rotating magnetic field method which allows one to determine gamma _1 and the anisotropic magnetic susceptibility, chi_{a}. For the ionic surfactant liquid crystals of SDS and KL systems used in this study, the rotational viscosity exhibited an extraordinary drop after reaching the highest value gamma_1 as the temperature was lowered. This behavior is not observed in normal liquid crystals. But this phenomena can be attributed to the existence of nematic biaxial phase below the rod-like nematic N_{c} phase. The pretransitional increase in gamma _1 near the disk-like nematic to smectic -A phase transition of the pure CsPFO H_2O systems are better understood with the help of mean-field models of W. L. McMillan. He predicted a critical exponent nu = -{1over 2} for the divergence of gamma_1. The polymer (PEO, molecular weight = 10 ^5) dissolved in CsPFO H_2O system (which has 0.6% critical polymer concentration), suppressed the nematic to lamellar smectic phase transition in concentrated polymer solutions (0.75% and higher). In dilute polymer solutions with lower than 0.3% polyethylene-oxide, a linear increase of gamma_1 is observed, which agrees with Brochard theory. The polymer solutions in thermotropic liquid crystal solvents

  6. Manipulation of Contact Angles and Interfacial Lengths of Liquid Drops using Electro-Kinetic Techniques

    NASA Astrophysics Data System (ADS)

    Zhou, X.; Nolte, D. D.; Pyrak-Nolte, L. J.

    2014-12-01

    Traditionally, capillary pressure is determined by increasing or decreasing external fluid pressures to change the immiscible fluid saturation in a porous medium. The resulting saturation and interfacial area are then linked to the capillary pressure through constitutive equations. A key question is whether externally measured pressures are sensitive to changes in distributions that arise from internal changes in contact angles. As a first step in addressing this question, we investigated the effect of electro-kinetic manipulation on interfacial area and contact angles for a fixed saturation. An EWOD (electro-wetting on dielectric) technique was used to alter the contact angle of single 10 μL droplets of a 1M KCl-H2O solution. A liquid droplet was placed on a glass cover slip (18 mm x 18 mm) coated with a layer of silver (100 nm in thickness) to act as an electrode and then spin-coated with polyimide (a dielectric). A platinum wire was inserted into the droplet and connected to an AC voltage source. The glass plate electrode was connected to ground. Measurements were made for Vrms voltages between 0 to 300 V at a frequency of 50 Hz. Two CCD cameras were used to image changes in the shape of a droplet. One camera was placed on a microscope to capture a top view of a drop in order to measure changes in areal extent and the perimeter of the drop. The second camera imaged a drop from the side to measure contact angles and side-view areal extent and perimeter. At low voltages, the cosine of the contact angle, θ, after applying voltage was linearly dependent on Vrms2. Several experiments showed that the slope of the low-voltage relationship of cos θ vs Vrms2 remained constant for all trials. As the voltage increased, the contact angle saturated. From the side-view images, the contact angle and interfacial length decreased with increasing voltage. From the top-view images, the drop shape changed from circular to elliptical-to irregular as the voltage increased

  7. Cryo-electron microscopy of vitrified SV40 minichromosomes: the liquid drop model.

    PubMed Central

    Dubochet, J; Adrian, M; Schultz, P; Oudet, P

    1986-01-01

    The structure of SV40 minichromosomes has been studied by cryo-electron microscopy of vitrified thin layers of solution. In high-salt buffer (130 mM NaCl), freshly prepared minichromosomes are condensed into globules 30 nm or more in diameter. On the micrograph, they appear to be formed by the close packing of 10 nm granules which give rise to a 10 nm reflection in the optical diffractogram. The globules can adopt many different conformations. At high concentration, they fuse into a homogeneous 'sea' of closely packed 10 nm granules. In low-salt buffer (less than 10 mM NaCl), the globules open, first into 10 nm filaments, and then into nucleosome-strings. The 'liquid drop' model is proposed to explain the condensed structure of the minichromosome in high-salt buffer: nucleosomes stack specifically on top of one another, thus forming the 10 nm filaments. 10 nm filaments in turn, tend to aggregate laterally. Optimizing both these interactions results in the condensation of 10 nm filaments or portions thereof into a structure similar to that of a liquid. Some implications of this model for the structure of cellular chromatin are discussed. Images Fig. 1. Fig. 2. Fig. 3. Fig. 4. Fig. 6. Fig. 7. Fig. 8. Fig. 9. Fig. 11. Fig. 13. Fig. 14. PMID:3011410

  8. Encapsulation of liquids using a counter rotating twin screw extruder.

    PubMed

    Tackenberg, Markus W; Krauss, Ralph; Marmann, Andreas; Thommes, Markus; Schuchmann, Heike P; Kleinebudde, Peter

    2015-01-01

    Until now extrusion is not applied for pharmaceutical encapsulation processes, whereas extrusion is widely used for encapsulation of flavours within food applications. Based on previous mixing studies, a hot melt counter-rotating extrusion process for encapsulation of liquid active pharmaceutical ingredients (APIs) was investigated. The mixing ratio of maltodextrin to sucrose as matrix material was adapted in first extrusion trials. Then the number of die holes was investigated to decrease expansion and agglutination of extrudates to a minimum. At a screw speed of 180 min(-1) the product temperature was decreased below 142 °C, resulting in extrudates of cylindrical shape with a crystalline content of 9-16%. Volatile orange terpenes and the nonvolatile α-tocopherol were chosen as model APIs. Design of experiments were performed to investigate the influences of barrel temperature, powder feed rate, and API content on the API retentions. A maximum of 9.2% α-tocopherol was encapsulated, while the orange terpene encapsulation rate decreased to 6.0% due to evaporation after leaving the die. During 12 weeks of storage re-crystallization of sucrose occurred; however, the encapsulated orange terpene amount remained unchanged.

  9. A Study of the Measurement of Surface and Interfacial Tension by the Maximum Liquid Drop Volume Method.

    PubMed

    Pu, Bingyin; Chen, Donghao

    2001-03-15

    The maximum liquid drop volume (v(max)) is measured by using a back-suction micrometer syringe piston technique. Different very viscous liquids are measured by (v(max)) and (v(f)) methods to observe the effect of viscosity on tension measurement. No apparent viscosity effect was observed in surface tension data obtained by using Harkins-Brown factors and the theoretical correction factors in the viscosity range 5.9-100,900 mP. Copyright 2001 Academic Press.

  10. Faraday rotation dispersion microscopy imaging of diamagnetic and chiral liquids with pulsed magnetic field.

    PubMed

    Suwa, Masayori; Nakano, Yusuke; Tsukahara, Satoshi; Watarai, Hitoshi

    2013-05-21

    We have constructed an experimental setup for Faraday rotation dispersion imaging and demonstrated the performance of a novel imaging principle. By using a pulsed magnetic field and a polarized light synchronized to the magnetic field, quantitative Faraday rotation images of diamagnetic organic liquids in glass capillaries were observed. Nonaromatic hydrocarbons, benzene derivatives, and naphthalene derivatives were clearly distinguished by the Faraday rotation images due to the difference in Verdet constants. From the wavelength dispersion of the Faraday rotation images in the visible region, it was found that the resonance wavelength in the UV region, which was estimated based on the Faraday B-term, could be used as characteristic parameters for the imaging of the liquids. Furthermore, simultaneous acquisition of Faraday rotation image and natural optical rotation image was demonstrated for chiral organic liquids.

  11. Distant optical detection of small rotations and displacements by means of chiral liquid crystals

    SciTech Connect

    Shibaev, Petr V. E-mail: shibayev@fordham.edu; Troisi, Juliana; Reddy, Kathryn; Iljin, Andrey

    2014-01-15

    The paper describes novel chiral viscoelastic liquid crystalline mixtures and their application for the detection of small rotational displacements of two plates confining cholesteric liquid crystals (CLC). The mixtures are characterized by extremely high viscosities and stability of the selective reflection band (SRB) at ambient temperatures. Even a small rotation applied to the chiral liquid crystal (CLC) cell results in dramatic changes of the reflective properties of sandwiched CLC films. The angle and direction of rotation as well as the magnitude of CLC's shear deformation can be determined for a variety of experimental geometries, each of which is characterized by its own response function. The proposed model explains changes in the reflection spectra for different experimental geometries and relates them to the angle of rotation and magnitude of shear. The method was tested for a detection of small rotations from a distance of up to 50 m and allows for resolving small rotations of the order of fractions of degrees.

  12. Distant optical detection of small rotations and displacements by means of chiral liquid crystals

    NASA Astrophysics Data System (ADS)

    Shibaev, Petr V.; Iljin, Andrey; Troisi, Juliana; Reddy, Kathryn

    2014-01-01

    The paper describes novel chiral viscoelastic liquid crystalline mixtures and their application for the detection of small rotational displacements of two plates confining cholesteric liquid crystals (CLC). The mixtures are characterized by extremely high viscosities and stability of the selective reflection band (SRB) at ambient temperatures. Even a small rotation applied to the chiral liquid crystal (CLC) cell results in dramatic changes of the reflective properties of sandwiched CLC films. The angle and direction of rotation as well as the magnitude of CLC's shear deformation can be determined for a variety of experimental geometries, each of which is characterized by its own response function. The proposed model explains changes in the reflection spectra for different experimental geometries and relates them to the angle of rotation and magnitude of shear. The method was tested for a detection of small rotations from a distance of up to 50 m and allows for resolving small rotations of the order of fractions of degrees.

  13. Modulated exponential films generated by surface acoustic waves and their role in liquid wicking and aerosolization at a pinned drop

    NASA Astrophysics Data System (ADS)

    Taller, Daniel; Go, David B.; Chang, Hsueh-Chia

    2013-05-01

    The exponentially decaying acoustic pressure of scattered surface acoustic waves (SAWs) at the contact line of a liquid film pinned to filter paper is shown to sustain a high curvature conic tip with micron-sized modulations whose dimension grows exponentially from the tip. The large negative capillary pressure in the film, necessary for offsetting the large positive acoustic pressure at the contact line, also creates significant negative hydrodynamic pressure and robust wicking action through the paper. An asymptotic analysis of this intricate pressure matching between the quasistatic conic film and bulk drop shows that the necessary SAW power to pump liquid from the filter paper and aerosolize, expressed in terms of the acoustic pressure scaled by the drop capillary pressure, grows exponentially with respect to twice the acoustic decay constant multiplied by the drop length, with a universal preexponential coefficient. Global rapid aerosolization occurs at a SAW power twice as high, beyond which the wicking rate saturates.

  14. Modulated exponential films generated by surface acoustic waves and their role in liquid wicking and aerosolization at a pinned drop.

    PubMed

    Taller, Daniel; Go, David B; Chang, Hsueh-Chia

    2013-05-01

    The exponentially decaying acoustic pressure of scattered surface acoustic waves (SAWs) at the contact line of a liquid film pinned to filter paper is shown to sustain a high curvature conic tip with micron-sized modulations whose dimension grows exponentially from the tip. The large negative capillary pressure in the film, necessary for offsetting the large positive acoustic pressure at the contact line, also creates significant negative hydrodynamic pressure and robust wicking action through the paper. An asymptotic analysis of this intricate pressure matching between the quasistatic conic film and bulk drop shows that the necessary SAW power to pump liquid from the filter paper and aerosolize, expressed in terms of the acoustic pressure scaled by the drop capillary pressure, grows exponentially with respect to twice the acoustic decay constant multiplied by the drop length, with a universal preexponential coefficient. Global rapid aerosolization occurs at a SAW power twice as high, beyond which the wicking rate saturates.

  15. Flow pattern and pressure drop of vertical upward gas-liquid flow in sinusoidal wavy channels

    SciTech Connect

    Nilpueng, Kitti; Wongwises, Somchai

    2006-06-15

    Flow patterns and pressure drop of upward liquid single-phase flow and air-water two-phase flow in sinusoidal wavy channels are experimentally studied. The test section is formed by a sinusoidal wavy wall of 1.00 m length with a wave length of 67.20mm, an amplitude of 5.76mm. Different phase shifts between the side walls of the wavy channel of 0{sup o}, 90{sup o} and 180{sup o} are investigated. The flow phenomena, which are bubbly flow, slug flow, churn flow, and dispersed bubbly flow are observed and recorded by high-speed camera. When the phase shifts are increased, the onset of the transition from the bubbly flow to the churn flow shifts to a higher value of superficial air velocity, and the regions of the slug flow and the churn flow are smaller. In other words, the regions of the bubbly flow and the dispersed bubbly flow are larger as the phase shift increases. The slug flow pattern is only found in the test sections with phase shifts of 0{sup o} and 90{sup o}. Recirculating gas bubbles are always found in the troughs of the corrugations. The recirculating is higher when the phase shifts are larger. The relationship between the two-phase multipliers calculated from the measured pressure drops, and the Martinelli parameter is compared with the Lockhart-Martinelli correlation. The correlation in the case of turbulent-turbulent condition is shown to fit the data very well for the phase shift of 0{sup o} but shows greater deviation when the phase shifts are higher. (author)

  16. Effects of Evaporation/Condensation on Spreading and Contact Angle of a Volatile Liquid Drop

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Singh, Bhim S. (Technical Monitor)

    2000-01-01

    Effects of evaporation/condensation on spreading and contact angle were experimentally studied. A sessile drop of R-113 was tested at different vapor environments to determine the effects of evaporation/condensation on the evolution of contact diameter and contact angle of the drop. Condensation on the drop surface occurs at both the saturated and a nonsaturated vapor environments and promotes the spreading. When the drop is placed in the saturated vapor environment it tends to completely wetting and spreads rapidly. In a nonsaturated vapor environment, the evolution of the sessile drop is divided three stages: condensation-spreading stage, evaporation-retracting stage and rapid contracting stage. In the first stage the drop behaves as in the saturated environment. In the evaporation -retracting stage, the competition between spreading and evaporation of the drop determines the evolution characteristics of the contact diameter and the contact angle. A lower evaporation rate struggles against the spreading power to turn the drop from spreading to retracting with a continuous increase of the contact angle. The drop placed in open air has a much higher evaporation rate. The strong evaporation suppresses the spreading and accelerates the retraction of the drop with a linear decrease of the contact diameter. The contraction of the evaporating drops is gradually accelerated when the contact diameter decreases to 3 min and less till drying up, though the evaporation rate is gradually slowing down.

  17. Volumetric thermal measurements using thermo-liquid crystal (TLC) micro-particles in evaporating drops

    NASA Astrophysics Data System (ADS)

    Segura, Rodrigo; Marin, Alvaro Gomez; Kaehler, Christian

    2013-11-01

    Freely evaporating sessile droplets develop weak temperature gradients that can generate Marangoni flows at the drop's surface. Quantitative temperature measurements of small gradients at such scales are very difficult. In this work, a method to track the temperature of individual thermo-liquid crystal (TLC) particles is employed to extract the temperature field inside an evaporating droplet. TLC thermography has been investigated for several years but the low quality of individual TLC particles, as well as the methods used to extract temperature from their color appearance, has prevented the development of a reliable approach to track their temperature individually. In order to overcome these challenges, an emulsion of stable non-encapsulated TLC micro particles with a narrower size distribution than that of commercial encapsulated TLC solutions was used along with a multi-variable calibration approach, as opposed to the direct hue-temperature relationship usually implemented (Segura et al., Microfluid Nanofluid, 2012). In addition, an optimized color space was implemented as well as circular polarization filtering to remove background noise and improve signal-to-noise ratio. Using this technique, a 3D temperature-velocity field within a droplet could be simultaneously resolved.

  18. Progress Report on Rotating Liquid Liner Implosion Experiment, 1 June to 31 December 1975.

    DTIC Science & Technology

    A critical question in the use of imploding liner flux compression for controlled fusion has been the stability of the inner surface of the liner ...To study the problem experimentally, the existing NRL Imploding Liner Facility was modified to allow the implosion of rotating liquid metal liners ...Rotational stabilization of lthe inner surface of a decelerating liquid sodium-potassium liner has been demonstrated, with excellent circularity of the

  19. Direct analysis in real time mass spectrometry combined with single-drop liquid-liquid-liquid microextraction for the rapid analysis of multiple phytohormones in fruit juice.

    PubMed

    Bai, Yu; Zhang, Jialing; Bai, Yu; Liu, Huwei

    2012-06-01

    A rapid, simple, and efficient method for the fast determination of multiple phytohormones was developed in this work, based on single-drop liquid-liquid-liquid microextraction (SD-LLLME) combined with direct analysis in real-time mass spectrometry (DART-MS). Six phytohormones--indole-3-acetic acid (IAA), indole-3-butyric acid (IBA), jasmonic acid (JA), salicylic acid (SA), abscisic acid (ABA), and gibberellin A(3) (GA(3))--were analyzed simultaneously using this method, and the conditions employed for DART-MS and SD-LLLME were optimized systematically. Satisfactory results were obtained in terms of linearity (R (2) values for all phytohormones were 0.991-0.996), sensitivity (limits of detection were 0.65-72 ng/mL), and repeatability (RSD values were 6.9-14%). In addition, the proposed method was applied to determine the endogenous phytohormones in three kinds of fruit juice. Different concentrations of phytohormones were detected with satisfactory recoveries, and the whole analytical procedure took no more than 30 min. Therefore, this combination of SD-LLLME and DART-MS was shown to be a suitable and effective approach for the fast analysis of targets present at trace level concentrations in complex matrices.

  20. Rapid extraction and determination of amphetamines in human urine samples using dispersive liquid-liquid microextraction and solidification of floating organic drop followed by high performance liquid chromatography.

    PubMed

    Ahmadi-Jouibari, Toraj; Fattahi, Nazir; Shamsipur, Mojtaba

    2014-06-01

    A novel, rapid, simple and sensitive dispersive liquid-liquid microextraction method based on the solidification of floating organic drop (DLLME-SFO) combined with high-performance liquid chromatography-ultraviolet detection (HPLC-UV) was used to determine amphetamine and methamphetamine in urine samples. The factors affecting the extraction efficiency of DLLME-SFO such as the kind and volume of the extraction and the disperser solvents, effect of concentration of K2CO3 and extraction time were investigated and the optimal extraction conditions were established. Under the optimum conditions (extraction solvent: 30.0μl 1-undecanol; disperser solvent: 300μl acetonitrile; buffer concentration: 2% (w/v) K2CO3 and extraction time: 1min), calibration curves are linear in the range of 10-3000μgl(-1) and limit of detections (LODs) are in the range of 2-8μgl(-1). The relative standard deviations (RSDs) for 100μgl(-1) of amphetamine and methamphetamine in diluted urine are in the range of 6.2-7.8% (n=7). The method was successfully applied for the determination of amphetamine and methamphetamine in the actual urine samples. The relative recoveries of urine samples spiked with amphetamine and methamphetamine are 87.8-113.2%. The obtained results show that DLLME-SFO combined with HPLC-UV is a fast and simple method for the determination of amphetamine and methamphetamine in urine.

  1. New applications of liquid-crystal thermography in rotating turbomachinery heat transfer research

    NASA Technical Reports Server (NTRS)

    Blair, M. F.; Wagner, J. H.; Steuber, G. D.

    1991-01-01

    Two new liquid-crystal thermography techniques developed for use in rotating heat transfer experiments are described. In one experiment steady-state heat transfer data were obtained on the exterior surface of rotating turbine airfoil models. In the second study a transient technique was employed to obtain interior-surface heat transfer data in a rotating turbine blade coolant passage model. Sample data are presented in the form of photographs of the liquid-crystal temperature patterns and as contour maps and distributions of heat transfer on the rotor and coolant passage surfaces.

  2. Puddle jumping: Spontaneous ejection of large liquid droplets from hydrophobic surfaces during drop tower tests

    NASA Astrophysics Data System (ADS)

    Attari, B.; Weislogel, M.; Wollman, A.; Chen, Y.; Snyder, T.

    2016-10-01

    Large droplets and puddles jump spontaneously from sufficiently hydrophobic surfaces during routine drop tower tests. The simple low-cost passive mechanism can in turn be used as an experimental device to investigate dynamic droplet phenomena for drops up to 104 times larger than their normal terrestrial counterparts. We provide and/or confirm quick and qualitative design guides for such "drop shooters" as employed in drop tower tests including relationships to predict droplet ejection durations and velocities as functions of drop volume, surface texture, surface contour, wettability pattern, and fluid properties including contact angle. The latter is determined via profile image comparisons with numerical equilibrium interface computations. Water drop volumes of 0.04-400 ml at ejection speeds of -0.007-0.12 m/s are demonstrated herein. A sample application of the drop jump method is made to the classic problem of low-gravity phase change heat transfer for large impinging drops. Many other candidate problems might be identified by the reader.

  3. Determination of the liquid crystals phase transition temperatures using optical rotation effect

    NASA Astrophysics Data System (ADS)

    Niu, Xiao-ling; Liu, Wei-guo; Liu, Peng; Cai, Chang-long

    2011-11-01

    Using optical rotation effect, a sensitive, simple optical analytical system is developed for determining the phase transition temperatures of liquid crystals (LCs). When a monochromatic polarized light passes through LCs sample and analyzer, the light intensity changes with temperature. Especially, during the phase transition process, the intensity varies greatly due to optical rotation effect. The variation of light intensity versus variation of temperature curve shows the phase transition temperatures of LCs clearly. The phase transition temperatures of three cholesteric liquid crystals (ChLCs) and a nematic liquid crystals (NLCs) were detected by this method, and compared with those of the differential scanning calorimetry (DSC) and polarized light microscope (PLM) methods.

  4. Dynamics of liquid-crystalline magnetic suspensions in a rotating magnetic field.

    PubMed

    Boychuk, Alexey N; Makarov, Dmitriy V; Zakhlevnykh, Alexander N

    2016-10-01

    We theoretically study the dynamics of the orientational structure of a ferronematic liquid crystal with soft planar coupling between the director and the magnetization in a rotating magnetic field. We determine critical parameters characterizing the boundary between synchronous and asynchronous rotation regimes. We show that the magnetic impurity increases the stability threshold of an asynchronous rotation regime. The critical angular velocity, the angles of the director and the magnetization rotation in each regime of orientational structure rotation are found for rigid planar coupling. We obtain that in weak magnetic fields when the main mechanism of the field influence on a ferronematic liquid crystal is associated with the effect on the magnetic particles, the critical angular velocity is linearly dependent on the field strength, while in strong magnetic fields, when the influence of a field is determined by a diamagnetic mechanism, the critical velocity is quadratically dependent on the field strength.

  5. Liquid Motion in a Rotating Tank Experiment (LME)

    NASA Technical Reports Server (NTRS)

    Deffenbaugh, D. M.; Dodge, F. T.; Green, S. T.

    1998-01-01

    The Liquid Motion Experiment (LME), which flew on STS 84 in May 1997, was an investigation of liquid motions in spinning, nutating tanks. LME was designed to quantify the effects of such liquid motions on the stability of spinning spacecraft, which are known to be adversely affected by the energy dissipated by the liquid motions. The LME hardware was essentially a spin table which could be forced to nutate at specified frequencies at a constant cone angle, independently of the spin rate. Cylindrical and spherical test tanks, partially filled with liquids of different viscosities, were located at the periphery of the spin table to simulate a spacecraft with off-axis propellant tanks; one set of tanks contained generic propellant management devices (PMDs). The primary quantitative data from the flight tests were the liquid-induced torques exerted on the tanks about radial and tangential axes through the center of the tank. Visual recordings of the liquid oscillations also provided qualitative information. The flight program incorporated two types of tests: sine sweep tests, in which the spin rate was held constant and the nutation frequency varied over a wide range; and sine dwell test, in which both the spin rate and the nutation frequency were held constant. The sine sweep tests were meant to investigate all the prominent liquid resonant oscillations and the damping of the resonances, and the sine dwell tests were meant to quantify the viscous energy dissipation rate of the liquid oscillations for steady state conditions. The LME flight data were compared to analytical results obtained from two companion IR&D programs at Southwest Research Institute. The comparisons indicated that the models predicted the observed liquid resonances, damping, and energy dissipation rates for many test conditions but not for all. It was concluded that improved models and CFD simulations are needed to resolve the differences. This work is ongoing under a current IR&D program.

  6. Festoon instability of a drop of volatile insoluble liquid on the surface of other liquid under evaporation cooling conditions

    NASA Astrophysics Data System (ADS)

    Tarasov, O. A.; Gorbacheva, N. A.

    2007-02-01

    A festoon structure having the form of round hills has been observed at the periphery of a drop of o-oxylene or isooctane lying on the surface of a layer of hot water. On reaching a diameter of about 1 mm, festoons are ejected toward the drop center at a velocity of 1 2 mm/s. The growth of festoons is caused by thermocapillary flows, while their ejection is related to the capillary forces, which tend to decrease the free surface. This kind of stability substantially differs from the other known thermocapillary instabilities, since the ejection of festoons prevents the drop from spreading and thus prolongs its life.

  7. A Symmetry Breaking Experiment Aboard Mir and the Stability of Rotating Liquid Films

    NASA Technical Reports Server (NTRS)

    Concus, P.; Finn, R.; Gomes, D.; McCuan, J.; Weislogel, M.

    1999-01-01

    We discuss results from two parts of our study on the behavior of liquids under low-gravity conditions. The first concerns the Interface Configuration Experiment (ICE) aboard the Space Station Mir on the Mir-21/NASA-2 mission; for a certain 'exotic' container, distinct asymmetric liquid configurations are found as locally stable ones, even though the container itself is rotationally symmetric, in confirmation of mathematical results and numerical computations. The second investigation concerns the behavior of slowly rotating liquids; it is found that a rotating film instability observed previously in a physical experiment in 1-g, scaled to render gravity effects small, does not correspond to mathematical and computational results obtained for low gravity. These latter results are based on the classical equilibrium theory enhanced with a van der Waals potential of adhesion.

  8. Convergence of a cylindrical liquid shell and the formation of a bore in a rotating fluid

    NASA Astrophysics Data System (ADS)

    Kedrinskii, V. K.; Nikulin, V. V.

    1999-12-01

    This paper presents the results of experimental studies of a collapsing cylindrical cavity (the convergence of a liquid shell) in a rotating fluid as well as the formation and propagation of a jump (bore) at the interface. The basic parameters of the liquid shell dynamics for a pulsed one-dimensional load are estimated using the equation of cylindrical cavity pulsation in an unbounded fluid. The theoretical model of a rotationally symmetric hydraulic jump moving along the free surface of a hollow vortex is constructed. The jump is simulated by a discontinuous solution of the equations in the long-wave approximation for tornado-like and hollow vortices. For comparison with the experimental data, basic theoretical results are obtained for flows in a hollow vortex with constant circulation and axial velocity varying along the radius of the rotating liquid shell.

  9. HIGH-PRECISION MACLAURIN-BASED MODELS OF ROTATING LIQUID PLANETS

    SciTech Connect

    Hubbard, W. B.

    2012-09-01

    We present an efficient numerical self-consistent field method for calculating a gravitational model of a rotating liquid planet to spherical harmonic degree {approx}30 and a precision {approx}10{sup -12} in the external gravity field. The method's accuracy is validated by comparing results, for Jupiter rotation parameters, with the exact Maclaurin constant-density solution. The method can be generalized to non-constant density.

  10. Impingement of a drop train enhance the liquid infiltration into a closed end hole

    NASA Astrophysics Data System (ADS)

    Sanada, Toshiyuki; Yamaguchi, Eri; Muraki, Shunsuke

    2016-11-01

    Liquid infiltration is an important process for cleaning inside fine holes. However, it is difficult to infiltrate liquid into closed end holes having small diameter. Because the surface tension prevents the deformation of gas-liquid interface for entering them. In this study we observed the liquid infiltration process into a closed end hole by applying external pressure under two ways, i.e. gradual pressurization with a hand pump and impingement of a droplet train. As a result, it is found that the amount of dissolved air into liquid by applying pressure is small, and it has small effect for the liquid infiltration. In addition, it is also found that the high liquid infiltration rate can be achieved by applying a droplet train impact. It is observed that the trapped bubbles inside the holes were ejected by repetition of droplet impingement.

  11. A numerical and experimental study of three-dimensional liquid sloshing in a rotating spherical container

    NASA Technical Reports Server (NTRS)

    Chen, Kuo-Huey; Kelecy, Franklyn J.; Pletcher, Richard H.

    1992-01-01

    A numerical and experimental study of three dimensional liquid sloshing inside a partially-filled spherical container undergoing an orbital rotating motion is described. Solutions of the unsteady, three-dimensional Navier-Stokes equations for the case of a gradual spin-up from rest are compared with experimental data obtained using a rotating test rig fitted with two liquid-filled spherical tanks. Data gathered from several experiments are reduced in terms of a dimensionless free surface height for comparison with transient results from the numerical simulations. The numerical solutions are found to compare favorably with the experimental data.

  12. Behavior of a heavy cylinder in a horizontal cylindrical liquid-filled cavity at modulated rotation

    NASA Astrophysics Data System (ADS)

    Kozlov, Nikolai V.; Vlasova, Olga A.

    2016-10-01

    The behavior of a heavy cylindrical solid in a horizontal cylindrical cavity is experimentally investigated. The cavity is filled with a viscous liquid and rotates. Two rotation regimes are considered. The first one is steady rotation. A number of body motion regimes are found depending on the cavity rotation speed. The second regime is a modulated rotation, in which the rotation speed is varying periodically. It can be presented as a sum of steady rotation and librations. On the whole, three different cases of the body repulsion from the cavity wall are observed. In the first case, the repulsion occurs when the body slides over a rotating cavity wall. In the second case, the body being in the centrifuged state—when it rotates with the fluid—detaches from the cavity wall under the action of gravity. In the third case, at librations, the wall performs oscillations and the body is repulsed from the wall due to the nonlinear viscous interaction with the fluid.

  13. Nanofluid of zinc oxide nanoparticles in ionic liquid for single drop liquid microextraction of fungicides in environmental waters prior to high performance liquid chromatographic analysis.

    PubMed

    Amde, Meseret; Tan, Zhi-Qiang; Liu, Rui; Liu, Jing-Fu

    2015-05-22

    Using a nanofluid obtained by dispersing ZnO nanoparticles (ZnO NPs) in 1-hexyl-3-methylimidazolium hexafluorophosphate, new single drop microextraction method was developed for simultaneous extraction of three fungicides (chlorothalonil, kresoxim-methyl and famoxadone) in water samples prior to their analysis by high performance liquid chromatography (HPLC-VWD). The parameters affecting the extraction efficiency such as amount of ZnO NPs in the nanofluid, solvent volume, extraction time, stirring rate, pH and ionic strength of the sample solution were optimized. Under the optimized conditions, the limits of detection were in the range of 0.13-0.19ng/mL, the precision of the method assessed with intra-day and inter-day relative standard deviations were <4.82% and <7.04%, respectively. The proposed method was successfully applied to determine the three fungicides in real water samples including lake water, river water, as well as effluent and influent of wastewater treatment plant, with recoveries in the range of 74.94-96.11% at 5ng/mL spiking level. Besides to being environmental friendly, the high enrichment factor and the data quality obtained with the proposed method demonstrated its potential for application in multi residue analysis of fungicides in actual water samples.

  14. Dispersive liquid-liquid microextraction based on solidification of floating organic drop and high-performance liquid chromatography to the analysis of cocaine's major adulterants in human urine.

    PubMed

    Sena, Laís Cristina Santana; Matos, Humberto Reis; Dórea, Haroldo Silveira; Pimentel, Maria Fernanda; de Santana, Danielle Cristine Almeida Silva; de Santana, Fernando José Malagueño

    2017-02-01

    A simple method has been proposed for the determination of cocaine's major adulterants (caffeine, levamisole, lidocaine, phenacetin, diltiazem, and hydroxyzine) in human urine by dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO) in combination with high-performance liquid chromatography - photodiode array detector (HPLC-PDA). The reversed-phase chromatographic separation was obtained with a column C18 extended (250×4.6mm; 5μm; 80Å) in gradient elution mode using acetonitrile-trifluoroacetic acid 0.026% (v,v) (pH=2.5) at 1mLmin(-1) as mobile phase, at 25°C, and detection at 235nm. The analysis time was 25min. This condition had the best resolution factors (>1.15), retention factors (>0.68), number of plates (>2094.9), and separation factors (>1.05) for all targets, indicating a good separation. The kind of extraction and dispersive solvent were investigated for unifactorial design. The buffer pH, the volume of extraction and disperser solvent, and the amount of salt were optimized for full factorial design. Under optimum conditions, human urine samples were alkalized with 0.5M sodium phosphate buffer (pH 10) and added to sodium chloride (20%m/v). Acetonitrile (150μL) and 1-dodecanol (30μL) were used as dispersive and extraction solvent, respectively. The method presented linear range of 312.5-3125ngmL(-1) to caffeine and levamisole and 187.5-1875ngmL(-1) to lidocaine, phenacetin, diltiazem, and hydroxyzine. The limit of quantification was 187.5ngmL(-1) to lidocaine, phenacetin, diltiazem, and hydroxyzine and 312.5ngmL(-1) for caffeine and levamisole. The recovery mean values were between 6.0 and 42.6%. The method showed good precision and accuracy, with within- and between-run relative standard deviation and relative error less than 15%. The samples were stable after freeze-thaw cycle and short-term room temperature stability tests. Besides, this method was satisfactorily applied in urine of cocaine users. It

  15. Continuous Rotation of Achiral Nematic Liquid Crystal Droplets Driven by Heat Flux

    NASA Astrophysics Data System (ADS)

    Ignés-Mullol, Jordi; Poy, Guilhem; Oswald, Patrick

    2016-07-01

    Suspended droplets of cholesteric (chiral nematic) liquid crystals spontaneously rotate in the presence of a heat flux due to a temperature gradient, a phenomenon known as the Lehmann effect. So far, it is not clear whether this effect is due to the chirality of the phase and the molecules or only to the chirality of the director field. Here, we report the continuous rotation in a temperature gradient of nematic droplets of a lyotropic chromonic liquid crystal featuring a twisted bipolar configuration. The achiral nature of the molecular components leads to a random handedness of the spontaneous twist, resulting in the coexistence of droplets rotating in the two senses, with speeds proportional to the temperature gradient and inversely proportional to the droplet radius. This result shows that a macroscopic twist of the director field is sufficient to induce a rotation of the droplets, and that the phase and the molecules do not need to be chiral. This suggests that one can also explain the Lehmann rotation in cholesteric liquid crystals without introducing the Leslie thermomechanical coupling—only present in chiral mesophases. An explanation based on the Akopyan and Zeldovich theory of thermomechanical effects in nematics is proposed and discussed.

  16. Equilibrium shape and location of a liquid drop acoustically positioned in a resonant rectangular chamber

    NASA Technical Reports Server (NTRS)

    Jackson, H. W.; Barmatz, M.; Shipley, C.

    1988-01-01

    The effect of a standing wave field in a rectangular chamber on the shape and location of an acoustically positioned drop or bubble is calculated. The sample deformation and equilibrium position are obtained from an analysis of the spherical harmonic projections of the total surface stress tensor. The method of calculation relies on the assumed condition that the sample is only slightly distorted from a spherical form. The equilibrium location of a levitated drop is combined with a formula introduced by Hasegawa (1979) to calcualte the ka dependence of the radiation force function. The present theory is valid for large as well as small ka values. Calculations in the small ka limit agree with previous theories and experimental results. Examples are presented for nonplane-wave modes as well as plane-wave rectangular modes.

  17. The magnitude of lift forces acting on drops and bubbles in liquids flowing inside microchannels.

    PubMed

    Stan, Claudiu A; Ellerbee, Audrey K; Guglielmini, Laura; Stone, Howard A; Whitesides, George M

    2013-02-07

    Hydrodynamic lift forces offer a convenient way to manipulate particles in microfluidic applications, but there is little quantitative information on how non-inertial lift mechanisms act and compete with each other in the confined space of microfluidic channels. This paper reports measurements of lift forces on nearly spherical drops and bubbles, with diameters from one quarter to one half of the width of the channel, flowing in microfluidic channels, under flow conditions characterized by particle capillary numbers Ca(P) = 0.0003-0.3 and particle Reynolds numbers Re(P) = 0.0001-0.1. For Ca(P) < 0.01 and Re(P) < 0.01 the measured lift forces were much larger than predictions of deformation-induced and inertial lift forces found in the literature, probably due to physicochemical hydrodynamic effects at the interface of drops and bubbles, such as the presence of surfactants. The measured forces could be fit with good accuracy using an empirical formula given herein. The empirical formula describes the power-law dependence of the lift force on hydrodynamic parameters (velocity and viscosity of the carrier phase; sizes of channel and drop or bubble), and includes a numerical lift coefficient that depends on the fluids used. The empirical formula using an average lift coefficient of ~500 predicted, within one order of magnitude, all lift force measurements in channels with cross-sectional dimensions below 1 mm.

  18. Interactions between drops of molten Al-Li alloys and liquid water

    SciTech Connect

    Hyder, M.L.; Nelson, L.S.; Duda, P.M.; Hyndman, D.A.

    1993-08-01

    Sandia National Laboratories, at the request of the Savannah River Technology Center (SRTC), studied the interactions between single drops of molten aluminum-lithium alloys and water. Most experiments were performed with ``B`` alloy (3.1 w/o Li, balance A1). Objectives were to develop experimental procedures for preparing and delivering the melt drops and diagnostics for characterizing the interactions, measure hydrogen generated by the reaction between melt and water, examine debris recovered after the interaction, determine changes in the aqueous phase produced by the melt-water chemical reactions, and determine whether steam explosions occur spontaneously under the conditions studied. Although many H{sub 2} bubbles were generated after the drops entered the water, spontaneous steam explosions never occurred when globules of the ``B`` alloy at temperatures between 700 and 1000C fell freely through water at room temperature, or upon or during subsequent contact with submerged aluminum or stainless steel surfaces. Total amounts of H{sub 2} (STP) increased from about 2 to 9 cm{sup 3}/per gram of melt as initial melt temperature increased over this range of temperatures.

  19. A simple expression for pressure drops of water and other low molecular liquids in the flow through micro-orifices

    NASA Astrophysics Data System (ADS)

    Hasegawa, Tomiichi; Ushida, Akiomi; Narumi, Takatsune

    2015-12-01

    Flows are generally divided into two types: shear flows and shear-free elongational (extensional) flows. Both are necessary for a thorough understanding of the flow properties of a fluid. Shear flows are easy to achieve in practice, for example, through Poiseuille or Couette flows. Shear-free elongational flows are experimentally hard to achieve, resulting in an incomplete understanding of the flow properties of fluids in micro-devices. Nevertheless, flows through micro-orifices are useful for probing the properties of elongational flows at high elongational rates; although these flows exhibit shear and elongation, the elongation is dominant and the shear is negligible in the central region of the flows. We previously reported an anomalous reduction in pressure drops in the flows of water, a 50/50 mixture of glycerol and water, and silicone oils through micro-orifices. In the present paper, we rearrange the data presented in the previous paper and reveal a simple relationship where the pressure drop is proportional to the velocity through the micro-orifices, independent of the orifice diameter and the viscosity of the liquids tested. We explain our observations by introducing a "fluid element" model, in which fluid elements are formed on entering the orifice. The model is based on the idea that low molecular liquids, including water, generate strong elongational stress, similar to a polymer solution, in the flow through micro-orifices.

  20. Imaging rotational dynamics of nanoparticles in liquid by 4D electron microscopy

    NASA Astrophysics Data System (ADS)

    Fu, Xuewen; Chen, Bin; Tang, Jau; Hassan, Mohammed Th.; Zewail, Ahmed H.

    2017-02-01

    In real time and space, four-dimensional electron microscopy (4D EM) has enabled observation of transient structures and morphologies of inorganic and organic materials. We have extended 4D EM to include liquid cells without the time resolution being limited by the response of the detector. Our approach permits the imaging of the motion and morphological dynamics of a single, same particle on nanometer and ultrashort time scales. As a first application, we studied the rotational dynamics of gold nanoparticles in aqueous solution. A full transition from the conventional diffusive rotation to superdiffusive rotation and further to a ballistic rotation was observed with increasing asymmetry of the nanoparticle morphology. We explored the underlying physics both experimentally and theoretically according to the morphological asymmetry of the nanoparticles.

  1. Nuclear-deformation energies according to a liquid-drop model with a sharp surface

    SciTech Connect

    Blocki, J.; Swiatecki, W.J.

    1982-05-01

    We present an atlas of 665 deformation-energy maps and 150 maps of other properties of interest, relevant for nuclear systems idealized as uniformly charged drops endowed with a surface tension. The nuclear shapes are parametrized in terms of two spheres modified by a smoothly fitted quadratic surface of revolution and are specified by three variables: asymmetry, sphere separation, and a neck variable (that goes over into a fragment-deformation variable after scission). The maps and related tables should be useful for the study of macroscopic aspects of nuclear fission and of collisions between any two nuclei in the periodic table.

  2. How pinning and contact angle hysteresis govern quasi-static liquid drop transfer.

    PubMed

    Chen, H; Tang, T; Zhao, H; Law, K-Y; Amirfazli, A

    2016-02-21

    This paper presents both experimental and numerical simulations of liquid transfer between two solid surfaces with contact angle hysteresis (CAH). Systematic studies on the role of the advancing contact angle (θa), receding contact angle (θr) and CAH in determining the transfer ratio (volume of the liquid transferred onto the acceptor surface over the total liquid volume) and the maximum adhesion force (Fmax) were performed. The transfer ratio was found to be governed by contact line pinning at the end of the transfer process caused by CAH of surfaces. A map based on θr of the two surfaces was generated to identify the three regimes for liquid transfer: (I) contact line pinning occurs only on the donor surface, (II) contact line pinning occurs on both surfaces, and (III) contact line pinning occurs only on the acceptor surface. With this map, an empirical equation is provided which is able to estimate the transfer ratio by only knowing θr of the two surfaces. The value of Fmax is found to be strongly influenced by the contact line pinning in the early stretching stage. For symmetric liquid bridges between two identical surfaces, Fmax may be determined only by θa, only by θr, or by both θa and θr, depending on the magnitude of the contact angles. For asymmetric bridges, Fmax is found to be affected by the period when contact lines are pinned on both surfaces.

  3. Dispersive liquid-liquid microextraction based on the solidification of floating organic drop followed by ICP-MS for the simultaneous determination of heavy metals in wastewaters

    NASA Astrophysics Data System (ADS)

    Li, Yong; Peng, Guilong; He, Qiang; Zhu, Hui; Al-Hamadani, Sulala M. Z. F.

    2015-04-01

    In the present work, a dispersive liquid-liquid microextraction based on the solidification of floating organic drop (DLLME-SFO) combined with inductively coupled plasma mass spectrometry (ICP-MS) was developed for the determination of Pb, Co, Cu, Ni, Zn. The influences of analytical parameters, including pH, extraction solvent volume, disperser solvent volume, concentration of chelating agent on the quantitative recoveries of Pb, Co, Cu, Ni, Zn were investigated. The effect of the interfering ions on the analytes recovery was also investigated. Under the optimized conditions, the limits of detection were 0.97-2.18 ng L-1. The relative standard deviations (RSDs) were 2.62-4.51% (n = 7, C = 20 ng L-1). The proposed method was successfully applied for the analysis of ultra trace metals in wastewater samples.

  4. Picoliter Drop-On-Demand Dispensing for Multiplex Liquid Cell Transmission Electron Microscopy

    PubMed Central

    Patterson, Joseph P.; Parent, Lucas R.; Cantlon, Joshua; Eickhoff, Holger; Bared, Guido; Evans, James E.; Gianneschi, Nathan C.

    2017-01-01

    Liquid cell transmission electron microscopy (LCTEM) provides a unique insight into the dynamics of nanomaterials in solution. Controlling the addition of multiple solutions to the liquid cell remains a key hurdle in our ability to increase throughput and to study processes dependent on solution mixing including chemical reactions. Here, we report that a piezo dispensing technique allows for mixing of multiple solutions directly within the viewing area. This technique permits deposition of 50 pL droplets of various aqueous solutions onto the liquid cell window, before assembly of the cell in a fully controlled manner. This proof-of-concept study highlights the great potential of picoliter dispensing in combination with LCTEM for observing nanoparticle mixing in the solution phase and the creation of chemical gradients. PMID:27135268

  5. Picoliter Drop-On-Demand Dispensing for Multiplex Liquid Cell Transmission Electron Microscopy

    SciTech Connect

    Patterson, Joseph P.; Parent, Lucas R.; Cantlon, Joshua; Eickhoff, Holger; Bared, Guido; Evans, James E.; Gianneschi, Nathan C.

    2016-05-03

    Abstract

    Liquid cell transmission electron microscopy (LCTEM) provides a unique insight into the dynamics of nanomaterials in solution. Controlling the addition of multiple solutions to the liquid cell remains a key hurdle in our ability to increase throughput and to study processes dependent on solution mixing including chemical reactions. Here, we report that a piezo dispensing technique allows for mixing of multiple solutions directly within the viewing area. This technique permits deposition of 50 pL droplets of various aqueous solutions onto the liquid cell window, before assembly of the cell in a fully controlled manner. This proof-of-concept study highlights the great potential of picoliter dispensing in combination with LCTEM for observing nanoparticle mixing in the solution phase and the creation of chemical gradients.

  6. Experimental study of the stability and flow characteristics of floating liquid columns confined between rotating disks

    NASA Astrophysics Data System (ADS)

    Fowle, A. A.; Soto, L.; Strong, P. F.; Wang, C. A.

    1980-02-01

    A low Bond number simulation technique was used to establish the stability limits of cylindrical and conical floating liquid columns under conditions of isorotation, equal counter rotation, rotation of one end only, and parallel axis offset. The conditions for resonance in cylindrical liquid columns perturbed by axial, sinusoidal vibration of one end face are also reported. All tests were carried out under isothermal conditions with water and silicone fluids of various viscosities. A technique for the quantitative measurement of stream velocity within a floating, isothermal, liquid column confined between rotatable disks was developed. In the measurement, small, light scattering particles were used as streamline markers in common arrangement, but the capability of the measurement was extended by use of stereopair photography system to provide quantitative data. Results of velocity measurements made under a few selected conditions, which established the precision and accuracy of the technique, are given. The general qualitative features of the isothermal flow patterns under various conditions of end face rotation resulting from both still photography and motion pictures are presented.

  7. Experimental study of the stability and flow characteristics of floating liquid columns confined between rotating disks

    NASA Technical Reports Server (NTRS)

    Fowle, A. A.; Soto, L.; Strong, P. F.; Wang, C. A.

    1980-01-01

    A low Bond number simulation technique was used to establish the stability limits of cylindrical and conical floating liquid columns under conditions of isorotation, equal counter rotation, rotation of one end only, and parallel axis offset. The conditions for resonance in cylindrical liquid columns perturbed by axial, sinusoidal vibration of one end face are also reported. All tests were carried out under isothermal conditions with water and silicone fluids of various viscosities. A technique for the quantitative measurement of stream velocity within a floating, isothermal, liquid column confined between rotatable disks was developed. In the measurement, small, light scattering particles were used as streamline markers in common arrangement, but the capability of the measurement was extended by use of stereopair photography system to provide quantitative data. Results of velocity measurements made under a few selected conditions, which established the precision and accuracy of the technique, are given. The general qualitative features of the isothermal flow patterns under various conditions of end face rotation resulting from both still photography and motion pictures are presented.

  8. Contraction of an inviscid swirling liquid jet: Comparison with results for a rotating granular jet.

    NASA Astrophysics Data System (ADS)

    Weidman, P. D.; Kubitschek, J. P.

    2007-11-01

    In honor of the tercentenary of Leonhard Euler, we report a new solution of the Euler equations for the shape of an inviscid rotating liquid jet emanating from a tube of inner radius R0 aligned with gravity. Jet contraction is dependent on the exit swirl parameter χ0 = R0 φ0/U0 where φ0 and U0 are the uniform rotation rate and axial velocity of the liquid at the exit. The results reveal that rotation reduces the rate of jet contraction. In the limit χ0-> 0 one recovers the contraction profile for a non-rotating jet and the limit χ0->∞ gives a jet of constant radius. In contrast, experiments and a kinematic model for a rotating non-cohesive granular jet show that it expands rather than contracts when a certain small angular velocity is exceeded. The blossoming profiles are parabolic in nature. The model predicts a jet of uniform radius for χ0-> 0 and a jet with an initially horizontal trajectory in the limit χ0->∞.

  9. Effect of solute transfer and interfacial instabilities on scalar and velocity field around a drop rising in quiescent liquid channel

    NASA Astrophysics Data System (ADS)

    Khanwale, Makrand A.; Khadamkar, Hrushikesh P.; Mathpati, Channamallikarjun S.

    2015-11-01

    Physics of development of flow structures around the drop rising with solute transfer is highly influenced by the interfacial behaviour and is remarkably different than a particle rising under the same conditions. We report on the use of simultaneous particle image velocimetry-planar laser induced fluorescence technique to measure scalar and velocity fields around a drop rising in a quiescent liquid channel. The selected continuous phase is glycerol, and the drop consists of a mixture of toluene, acetone, and a dye rhodamine-6G, with acetone working as a interfacial tension depressant. The drop lies in the spherical region with Eötvös number, Eo = 1.95, Morton number, M = 78.20 and the particle Reynolds number being, Rep = 0.053. With Rep approaching that of creeping flow, we analyse the effect of interfacial instabilities solely, contrary to other investigations [M. Wegener et al., "Impact of Marangoni instabilities on the fluid dynamic behaviour of organic droplets," Int. J. Heat Mass Transfer 52, 2543-2551 (2009); S. Burghoff and E. Y. Kenig, "A CFD model for mass transfer and interfacial phenomena on single droplets," AIChE J. 52, 4071-4078 (2006); J. Wang et al., "Numerical simulation of the Marangoni effect on transient mass transfer from single moving deformable drops," AIChE J. 57, 2670-2683 (2011); R. F. Engberg, M. Wegener, and E. Y. Kenig, "The impact of Marangoni convection on fluid dynamics and mass transfer at deformable single rising droplets—A numerical study," Chem. Eng. Sci. 116, 208-222 (2014)] which account for turbulence as well as interfacial instabilities with Rep in the turbulent range. The velocity and concentration fields obtained are subjected to scale-wise energy decomposition using continuous wavelet transform. Scale-wise probability distribution functions of wavelet coefficients are calculated to check intermittent non-Gaussian behaviour for simultaneous velocity and scalar statistics. Multi-fractal singularity spectra for scalar

  10. Theoretical analysis of the oscillations of rotating liquid bridges under microgravity conditions

    NASA Astrophysics Data System (ADS)

    Acero, F. J.; Montanero, J. M.

    A liquid bridge can hold a significant liquid volume and provides a convenient way for its manipulation in microgravity conditions. Apart from their basic scientific interest, a liquid bridge can be considered as the simplest idealisation of the configuration appearing in the floating zone technique used for crystal growth and purification of high melting point materials. This has conferred to the study of liquid bridges a great interest not only in fluid mechanics but also in the field of material engineering. Even in space, the liquid bridge is susceptible to dynamic disturbances that may result from g-jitter, pulse-like accelerations due to a docking activity, crew movement or operation of equipment on the space station, and vibration of machines on board. These perturbations may excite oscillations of the free interface. Therefore it is important to know the natural frequencies and decay rates that characterize those oscillations. The presence of rotation in many artificial satellites and space stations provides a strong motivation for the study of its influence in the dynamics of liquid bridges. In this contribution, an analytical study of the small oscillation modes of rotating liquid columns is carried out. The analysis also includes the effect of an outer bath of similar density to that of the liquid column. However, to simplify the study, the ratio between viscous and capillary forces is assumed to be very small, so that a negligible amount of the oscillation energy is dissipated in the thin boundary layers existing at solid surfaces and fluid interfaces. The oscillation frequency ω depends on the rotation speed Ω due to the competition between the centrifugal and Coriolis inertial forces, and the restoring capillary force. If 2Ω<ω, the problem presents an elliptic character and the oscillation motion is a surface wave. For 2Ω>ω the motion becomes an internal wave (hyperbolic regime). The influence of the rotation speed on the axisymmetric and non

  11. Anomalous thermally induced pinning of a liquid drop on a solid substrate.

    PubMed

    Mettu, Srinivas; Kanungo, Mandakini; Law, Kock-Yee

    2013-08-27

    The effect of substrate temperature on the wetting and spreading behavior of a UV ink monomer has been studied as a surrogate for the ink on four different substrates: DTC (digital top coat)-coated BOPP (biaxial oriented polypropylene), Flexo-coated BOPP, DTC-coated SGE (semigloss elite) paper, and Flexo-coated SGE paper. Results show that the dynamic contact angles of the monomer decrease exponentially over time after contacting the surface, and the rate of spreading is consistently higher at 95 °C than at 22 °C. This observation indicates that spreading is controlled by the viscosity of the monomer as it decreases with temperature. An anomalous temperature effect is observed for the static contact angle on the DTC-coated BOPP substrate. The static contact angle at 95 °C is significantly larger than that at 22 °C (52° versus 30°). This is counterintuitive, as the surface tension of the monomer is shown to decease with increasing temperature. Microscopy (SEM and AFM) studies suggest that there is little interaction between the DTC coating solution and the BOPP substrate during the fast-drying coating process. This results in a smooth coated surface and, more importantly, voids between the BOPP nanofibers underneath the DTC coating. As the DTC-BOPP substrate is heated to 95 °C, fiber expansions occur. Microscopy results show that nanosized protrusions are formed on the DTC surface. We attribute it to fiber expansions in the vertical direction. Fiber expansions in the lateral direction causes little surface morphology change as the expanded materials only fill the voids laterally between the nanofiber network. We suggest that the protrusions on the surface create strong resistance to the wetting process and pin the monomer drop into a metastable wetting state. This interpretation is supported by the sliding angle and sessile drop height experiments.

  12. Flow patterns in a rotating horizontal cylinder partially filled with liquid

    NASA Astrophysics Data System (ADS)

    Kozlov, Victor; Polezhaev, Denis

    2015-07-01

    The dynamics of an annular layer of low-viscosity liquid inside a rapidly rotating horizontal cylinder is experimentally studied. Under gravity, the liquid performs forced azimuthal oscillations in the cavity frame. We examined the stability of the two-dimensional azimuthal flow and discovered two novel types of axisymmetric liquid flows. First, a large-scale axially symmetric flow is excited near the end walls. The inertial modes generated in the corner regions are proven to be responsible for such a flow. Second, a small-scale flow in the form of the Taylor-Gortler vortices appears due to the centrifugal instability of the oscillatory liquid flow. The spatial period of the vortices is in qualitative agreement with the data obtained in the experimental and numerical studies of cellular flow in librating containers.

  13. Coalescence of a Drop inside another Drop

    NASA Astrophysics Data System (ADS)

    Mugundhan, Vivek; Jian, Zhen; Yang, Fan; Li, Erqiang; Thoroddsen, Sigurdur

    2016-11-01

    Coalescence dynamics of a pendent drop sitting inside another drop, has been studied experimentally and in numerical simulations. Using an in-house fabricated composite micro-nozzle, a smaller salt-water drop is introduced inside a larger oil drop which is pendent in a tank containing the same liquid as the inner drop. On touching the surface of outer drop, the inner drop coalesces with the surrounding liquid forming a vortex ring, which grows in time to form a mushroom-like structure. The initial dynamics at the first bridge opening up is quantified using Particle Image Velocimetry (PIV), while matching the refractive index of the two liquids. The phenomenon is also numerically simulated using the open-source code Gerris. The problem is fully governed by two non-dimensional parameters: the Ohnesorge number and the diameter ratios of the two drops. The validated numerical model is used to better understand the dynamics of the phenomenon. In some cases a coalescence cascade is observed with liquid draining intermittently and the inner drop reducing in size.

  14. Influence of Solute Charge and Pyrrolidinium Ionic Liquid Alkyl Chain Length on Probe Rotational Reorientation Dynamics

    SciTech Connect

    Guo, Jianchang; Mahurin, Shannon Mark; Baker, Gary A; Hillesheim, Patrick C; Dai, Sheng; Shaw, Robert W

    2014-01-01

    In recent years, the effect of molecular charge on the rotational dynamics of probe solutes in room temperature ionic liquids (RTILs) has been a subject of growing interest. For the purpose of extending our understanding of charged solute behavior within RTILs, we have studied the rotational dynamics of three illustrative xanthene fluorescent probes within a series of N-alkylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([Cnmpyr][Tf2N]) RTILs with different n-alkyl chain lengths (n = 3, 4, 6, 8, or 10) using time-resolved fluorescence anisotropy decay. The rotational dynamics of the neutral probe rhodamine B dye lies between the stick and slip boundary conditions due to the influence of specific hydrogen bonding interactions. The rotation of the negatively-charged sulforhodamine 640 is slower than that of its positively-charged counterpart rhodamine 6G. An analysis based upon Stokes-Einstein-Debye hydrodynamics indicates that SR640 adheres to stick boundary conditions due to specific interactions, whereas the faster rotation of R6G is attributed to weaker electrostatic interactions. No dependence of the rotational dynamics on the solvent alkyl chain length was observed for any of the three dyes, suggesting that the specific interactions between dyes and RTILs are independent of this solvent parameter.

  15. Fluctuation emergence of bubbles under a rapid drop of pressure in a liquid

    NASA Astrophysics Data System (ADS)

    Pavlov, P. A.; Vinogradov, V. E.

    2015-07-01

    Explosive cavitation at the front of a negative-pressure pulse has been studied. Conditions for the emergence of bubbles by the mechanism of homogeneous fluctuation nucleation were identified. Those conditions feature a high rate of the phase transformation, with the vapor formation process being concentrated in time at the instant of attainment of a certain pressure. Under such conditions, the liquid cavitation strength is maximal, and its value can be predicted by the homogeneous nucleation theory. For implementing the regime with high nucleation frequency, a method based on passing a negative-pressure pulse across a region with locally heated liquid was employed. The cavitation kinetics was examined by monitoring the perturbation of the heat flow from a miniature heater. The experimental data were generalized using the theory of explosive vapor formation in shock boiling mode. A method for calculating the cavitation in the regime of the fluctuation emergence of bubbles was approbated.

  16. Numerical simulation of drop impact on a controlled falling liquid film

    NASA Astrophysics Data System (ADS)

    Che, Zhizhao; Adebayo, Idris; Xie, Zhihua; Pavlidis, Dimitrios; Salinas, Pablo; Matar, Omar

    2016-11-01

    We study the impact process of droplets falling obliquely on controlled films using a numerical simulation approach. This approach is based on a finite element discretisation of the Navier Stokes equations on fully unstructured anisotropic and adaptive meshes, which are capable of representing the underlying physics of multiphase problems accurately while also reducing computational effort. Liquid film control here is applied to ensure that droplet impact occurs on different, targeted regions of a controlled film surface viz. capillary waves preceding a large-amplitude wave, flat film regions, and wave humps. The outcomes of droplet impact on these different regions are then compared and the differences discussed. The effect of varying the film flow rate, droplet speed, and droplet size on a number of droplet impact outcomes is also studied and the results further compared with those from uncontrolled as well as quiescent liquid films. EPSRC UK Programme Grant MEMPHIS (EP/K003976/1).

  17. Crystal deposition patterns from evaporating sessile drops on superhydrophobic and liquid impregnated surfaces

    NASA Astrophysics Data System (ADS)

    McBride, Samantha; Dash, Susmita; Varanasi, Kripa; Varanasi Group Team

    2016-11-01

    Accelerated corrosion and scale buildup near oceans is partially due to deposition of salty sea mist onto ships, cars, and building structures. Many corrosion preventative measures are expensive, time intensive, and/or have negative impacts on the environment. One solution is the use of specific surfaces that are engineered for scale resistance. In this work, we show that we can delay crystallization and reduce scale adhesion on specifically engineered liquid impregnated surfaces (LIS). The low contact angle hysteresis of the LIS results in a sliding contact line of the saline droplet during evaporation, and the elevated energy barrier of the smooth liquid interface delays crystallization. Experiments conducted on surfaces with different wettability also demonstrate the corresponding influence in controlling salt crystal polymorphism.

  18. Splat-quench solidification of freely falling liquid-metal drops by impact on a planar substrate

    NASA Technical Reports Server (NTRS)

    Collings, E. W.; Markworth, A. J.; Mccoy, J. K.; Saunders, J. H.

    1990-01-01

    Results are presented of a study of the splat-quench solidification of small, freely falling liquid drops of the alloy Nitronic 40W, which were allowed to impact on a solid, planar, horizontal substrate. The principal variable was the substrate material, with substrates of copper, alumina and fused quartz being used. The shapes of the solidified splats were correlated with a simplified model for the energetics of the splatting process and with the thermal conductivity of the substrate. The measured results are qualitatively in agreement with theoretical predictions, and suggestions are offered for a more comprehensive model of splat-quench solidification. A relationship between sessile droplet diameter and parent wire diameter is also presented and discussed.

  19. A new coupling of ionic liquid based-single drop microextraction with tungsten coil electrothermal atomic absorption spectrometry

    NASA Astrophysics Data System (ADS)

    Wen, Xiaodong; Deng, Qingwen; Wang, Jiwei; Yang, Shengchun; Zhao, Xia

    2013-03-01

    In this work, an improved method of ionic liquid based-single drop microextraction (IL-SDME) preconcentration was firstly coupled with tungsten coil electrothermal atomic absorption spectrometry (W-coil ET-AAS) detection. The new coupling was developed and applied for the determination of ultra-trace cadmium. Experimental parameters influencing the performance of IL-SDME as well as instrumental conditions were studied systematically, including IL-drop volume, chelating agent concentration, pH, stirring rate and time, heating program of W-coil ET-AAS, flow rate of carrier gas. Under the optimal conditions, the limit of detection (LOD) for cadmium was 0.015 μg L-1 (sampling amount on W-coil was 10 μL). The sensitivity enhancement factor was 42, while the improvement factor of LOD was 33. The established method was applied to determine cadmium in standard reference materials of rice and real water samples successfully. The developed IL-SDME-W-coil ET-AAS coupling represents a simple, green and highly sensitive method for cadmium determination.

  20. Experiments on Heat Transfer in a Thin Liquid Film Flowing Over a Rotating Disk

    NASA Technical Reports Server (NTRS)

    Sankaran, Subramanian (Technical Monitor); Ozar, B.; Cetegen, B. M.; Faghri, A.

    2004-01-01

    An experimental study of heat transfer into a thin liquid film on a rotating heated disk is described. Deionized water was introduced at the center of a heated. horizontal disk with a constant film thickness and uniform radial velocity. Radial distribution of the disk surface temperatures was measured using a thermocouple/slip ring arrangement. Experiments were performed for a range of liquid flow rates between 3.01pm and 15.01pm. The angular speed of the disk was varied from 0 rpm to 500 rpm. The local heat transfer coefficient was determined based on the heat flux supplied to the disk and the temperature difference between the measured disk surface temperature and the liquid entrance temperature onto the disk. The local heat transfer coefficient was seen to increase with increasing flow rate as well as increasing angular velocity of the disk. Effect of rotation on heat transfer was largest for the lower liquid flow rates with the effect gradually decreasing with increasing liquid flow rates. Semi-empirical correlations are presented in this study for the local and average Nusselt numbers.

  1. Interfacial Tension between Water and Selected Superheated Liquids by Quadrupole Oscillations of Drops.

    DTIC Science & Technology

    1983-12-01

    Estimation of Surface and Interfacial Energies 4 J. Phys. Chem., vol. 61, pp. 904-909, 1957. 29. Shaw D.J. C r Introduction to Colloid and Surface ...Tension There is a need for a theory that predicts the interfacial tension between two liquids based on some other properties such as the surface ...in Internation Critical Tables, ed. E.W. Washburn Mcbraw-Hill, New York, vol. 4, pp. 436-437, 1928. 28. Girifalco , L.A., and Good , R.J. A

  2. Relaxation of rotational angular momentum of polar diatomic molecules in simple liquids

    SciTech Connect

    Padilla, A.; Perez, J.

    2007-03-15

    The relaxation processes of rotational angular momentum of polar diatomic molecules diluted in simple liquids are analyzed by applying a non-Markovian relaxation theory to the study of the binary time autocorrelation function of the angular momentum. This non-Markovian theory was previously applied to the study of the infrared and Raman spectroscopy, and also to the analysis of the rotational energy relaxation processes. We have obtained non-Markovian evolution equations for the two-time j-level angular momentum correlation components involved in the angular momentum correlation function. In these equations, the time-dependent angular momentum transfer rates and the pure orientational angular transfer rates are given in terms of the binary time autocorrelation function of the diatomic-solvent anisotropic interaction. The non-Markovian evolution equations converge to Markovian ones in the long time limit, reaching the angular momentum transfer rates in the usual time-independent form. Alternative time scales for the angular relaxation processes, relative to the individual rotational processes as well as to the global decay correlations, are introduced and analyzed. The theory is applied to the study of the angular momentum relaxation processes of HCl diluted in liquid SF{sub 6}, a system for which rotational energy relaxation and infrared and Raman spectroscopy was previously analyzed in the scope of the same theory.

  3. Oscillation-induced sand dunes in a liquid-filled rotating cylinder

    NASA Astrophysics Data System (ADS)

    Dyakova, Veronika; Kozlov, Victor; Polezhaev, Denis

    2016-12-01

    The dynamics of granular medium in a liquid-filled horizontal cylinder with a time-varying rotation rate is experimentally studied. When the cylinder is purely rotated, the granular medium develops an annular layer near the cylindrical wall. The interface between fluid and sand is smooth and axisymmetric. The time variation of the rotation rate initiates the azimuthal oscillation of the liquid in the cylinder's frame of reference and provokes the onset of quasisteady relief in the form of regular dunes. The stability of the axisymmetric sand surface and dynamics of regular dunes are examined. It is found that the ripple formation is provoked by the quasisteady instability of the Stokes boundary layer. In the range of high Reynolds numbers, the ripple formation occurs at a constant critical Shields number θc≃0.05 . The spatial period of the relief is not sensitive to the fluid viscosity and granule diameter; it is determined by the amplitude of oscillation and ratio between the oscillation frequency and mean rotation rate. Long-term experiments show that there are forward and backward azimuthal drifts of dunes. An initial analysis of the issues related to the dune migration is provided.

  4. Drop Tower Experiments on Non-isothermal Reorientation of Cryogenic Liquids

    NASA Astrophysics Data System (ADS)

    Kulev, Nikolai; Dreyer, Michael

    2010-10-01

    Capillary driven surface oscillations of liquid argon (Tsat = 87.3 K at 1,013 hPa) have been investigated in a partly filled right circular cylinder under non-isothermal boundary conditions. The oscillations take place during the reorientation from the normal gravity surface position towards a new position upon step reduction of gravity. The situation is similar to the end of thrust in a rocket tank when the cold propellant moves along the warmer tank wall driven by capillary forces. The aim was to investigate the influence of the temperature difference between the slightly subcooled cryogenic liquid and the superheated cylinder wall on the oscillations and their characteristics in a single-component, two-phase system. Axial wall temperature gradients of averaged 0.15 K/mm - 1.93 K/mm above the normal gravity surface position were implemented. A general dependence of the reorientation behavior on the gradient value was observed, concerning the apparent contact line behavior, the frequency and damping of the oscillations of the free surface center point, and the apparent contact angle. The behavior of the ullage pressure was found to follow the behavior of the contact line.

  5. How to reduce resistance to movement of alkane liquid drops across tilted surfaces without relying on surface roughening and perfluorination.

    PubMed

    Urata, Chihiro; Masheder, Benjamin; Cheng, Dalton F; Hozumi, Atsushi

    2012-12-21

    Alkylsilane-derived monolayer-covered surfaces generally display a reasonably good level of hydrophobicity but poor oleophobicity. Here, we demonstrate that the physical attributes of alkylsilane-derived surfaces (liquid-like or solid-like) are dependent on the alkyl chain length and density, and these factors subsequently have significant influence upon the dynamic dewetting behavior toward alkanes (C(n)H(2n+2), where n = 7-16). In this study, we prepared and characterized hybrid films through a simple sol-gel process based on the cohydrolysis and co-condensation of a mixture of a range of alkyltriethoxysilanes (C(n)H(2n+1)Si(OEt)(3), where n = 3, 6, 8, 10, 12, 14, 16, and 18) and tetramethoxysilane (TMOS). Surprisingly, when the carbon number (C(n)) of alkyl chain was 10 and below, the produced hybrid films were all smooth, highly transparent, and showed negligible contact angle (CA) hysteresis. On these hybrid surfaces, 5 μL drops of alkanes (n-hexadecane, n-dodecane, and n-decane) could move easily at low tilt angles (<5°) without pinning. On the other hand, when the C(n) exceeded 12, both transparency and mobility of probe liquids significantly worsened. In the former case, TMOS molecules played key roles in both forming continuous films (as a binder) and improving flexibility of alkyl chains (as a molecular spacer), resulting in the smooth liquid-like surfaces. Silylation of the hybrid film and subsequent dynamic CA measurements proved the presence of silanol groups on the outermost surfaces and demonstrated that the dynamic dewettability of hybrid films worsened as packing densities increased. Additionally, solvent effects (high affinity) between the alkyl chains and alkane liquids imparted a more liquid-like character to the surface. Thanks to these simple physical effects, the resistance to the alkane droplet motion across tilted surfaces was markedly reduced. With the longer carbon chains, the chain mobility was strictly inhibited by mutual interactions

  6. Special topics reports for the reference tandem mirror fusion breeder: liquid metal MHD pressure drop effects in the packed bed blanket. Vol. 1

    SciTech Connect

    McCarville, T.J.; Berwald, D.H.; Wong, C.P.C.

    1984-09-01

    Magnetohydrodynamic (MHD) effects which result from the use of liquid metal coolants in magnetic fusion reactors include the modification of flow profiles (including the suppression of turbulence) and increases in the primary loop pressure drop and the hydrostatic pressure at the first wall of the blanket. In the reference fission-suppressed tandem mirror fusion breeder design concept, flow profile modification is a relatively minor concern, but the MHD pressure drop in flowing the liquid lithium coolant through an annular packed bed of beryllium/thorium pebbles is directly related to the required first wall structure thickness. As such, it is a major concern which directly impacts fissile breeding efficiency. Consequently, an improved model for the packed bed pressure drop has been developed. By considering spacial averages of electric fields, currents, and fluid flow velocities the general equations have been reduced to simple expressions for the pressure drop. The averaging approach results in expressions for the pressure drop involving a constant which reflects details of the flow around the pebbles. Such details are difficult to assess analytically, and the constant may eventually have to be evaluated by experiment. However, an energy approach has been used in this study to bound the possible values of the constant, and thus the pressure drop. In anticipation that an experimental facility might be established to evaluate the undetermined constant as well as to address other uncertainties, a survey of existing facilities is presented.

  7. Liquid crystal chiroptical polarization rotators for the near-UV region: theory, materials, and device applications

    NASA Astrophysics Data System (ADS)

    Saulnier, D.; Taylor, B.; Marshall, K. L.; Kessler, T. J.; Jacobs, S. D.

    2013-09-01

    The helical structure of a chiral-nematic liquid crystal (CLC) material produces a number of interesting optical properties, including selective reflection and optical rotatory power. To take advantage of the high optical rotation near the selective reflection peak for applications in the UV, either large concentrations of chiral components or those possessing very large helical twisting powers (HTP's) are necessary. It is difficult to find chiral twisting agents with high HTP that do not degrade the UV transmission. We report what we believe to be the first experimental observation of extraordinarily high optical rotation (<30°/μm) in the near UV for a long-pitch (13.8-μm) CLC mixture composed of the low-birefringence nematic host ZLI-1646 doped with a low concentration (e.g., 1 wt%) of the chiral dopant CB 15. This experimental finding is verified theoretically using a mathematical model developed by Belyakov, which improves on de Vries' original model for optical rotation far from the selective reflection peak by taking into account the nonlinearity of optical rotatory power as a function of liquid crystal (LC) layer thickness. Using this model, the optical rotation at λ = 355 nm for the 1% CB 15/ZLI-1646 mixture is determined computationally, with the results in agreement with experimental data obtained by evaluating a series of wedged cells using an areal mapping, Hinds Exicor 450XT Mueller Matrix Polarimeter. This finding now opens a path to novel LC optics for numerous near-UV applications. One such envisioned application for this class of materials would be UV distributed polarization rotators (UV-DPR's) for largeaperture, high-peak-power lasers.

  8. Controlling the Mobility of the Fluid Interface of Moving Gas Bubbles or Liquid Drops by Using Micellar Solutions of Surfactants

    NASA Technical Reports Server (NTRS)

    Maldarelli, Charles; Papageorgiou, Demetrios

    1998-01-01

    Microgravity processes must rely on mechanisms other than buoyancy to move bubbles or droplets from one region to another in a continuous liquid phase. One suggested method is thermocapillary migration in which a temperature gradient is applied to the continuous phase. A significant and as yet unresolved impediment to the use of thermocapillary migration to direct bubble or drop motion is that these migrations can be significantly retarded by the adsorption onto the fluid particle surface of surface active impurities unavoidably present in the continuous or (if the particle is a liquid) droplet phases. The focus of our research was to develop a theory for remobilizing fluid particle interfaces retarded by a surfactant impurity in an effort to make more viable the use of thermocapillary migrations for the management of bubbles and drops in microgravity. We postulated that a surfactant at high bulk concentration which kinetically exchanges rapidly with the surface can restore interface mobility. The scaling arguments along with a discussion of the previous literature is reviewed in the context of the scaling framework. The specific objectives of the research were twofold. The first was to prove the remobilization theory by studying a model problem. As the mechanism for remobilization is independent of the force which drives the particle, the fluid particle shape and the presence of fluid inertia, we chose the simplest model consisting of a spherical bubble rising steadily by buoyancy in creeping flow. We solved the hydrodynamic and surfactant transport equations for rapid kinetic exchange to demonstrate that as the concentration increases, the Marangoni retardation at first increases (the low k behavior) and then decreases (the high k behavior). The second objective was to develop a method to determine the kinetic rate constants of a surfactant molecule, since this information is necessary to select surfactants which will exchange rapidly enough relative to the

  9. Dispersive liquid-liquid microextraction based on solidification of floating organic drop for preconcentration and determination of trace amounts of copper by flame atomic absorption spectrometry.

    PubMed

    Karadaş, Cennet; Kara, Derya

    2017-04-01

    A novel, simple, rapid, sensitive, inexpensive and environmentally friendly dispersive liquid-liquid microextraction method based on the solidification of a floating organic drop (DLLME-SFO) was developed for the determination of copper by flame atomic absorption spectrometry (FAAS). N-o-Vanillidine-2-amino-p-cresol was used as a chelating ligand and 1-undecanol was selected as an extraction solvent. The main parameters affecting the performance of DLLME-SFO, such as sample pH, volume of extraction solvent, extraction time, concentration of the chelating ligand, salt effect, centrifugation time and sample volume were investigated and optimized. The effect of interfering ions on the recovery of copper was also examined. Under the optimum conditions, the detection limit (3σ) was 0.93μgL(-1) for Cu using a sample volume of 20mL, yielding a preconcentration factor of 20. The proposed method was successfully applied to the determination of Cu in tap, river and seawater, rice flour and black tea samples as well as certified reference materials.

  10. Indirect spectrophotometric determination of ultra trace amounts of selenium based on dispersive liquid-liquid microextraction-solidified floating organic drop

    NASA Astrophysics Data System (ADS)

    Haji Shabani, Ali Mohammad; Dadfarnia, Shayessteh; Nozohor, Mahnaz

    2013-12-01

    A novel dispersive liquid-liquid microextraction-solidified floating organic drop (DLLME-SFOD) method combined with fiber optic-linear array detection spectrophotometry has been developed for the indirect determination of selenium. The method is based on the oxidation of the I- to iodine by inorganic Se(IV). The produced I2 reacts with the excess of I- ions in acidic media to give triiodide ions. The I3- is then extracted into 1-undecanol by DLLME-SFOD upon the formation of an ion pair with cetyltrimethylammonium cation. The extracted ion pair is determined by measuring its absorption at 360 nm. The absorbance signal is proportional to the selenium concentration in the aqueous phase. Under optimum conditions, the method provided an enrichment factor of 250 with a detection limit of 16.0 μg L-1 and a linear dynamic range of 40.0-1000.0 μg L-1. The relative standard deviation was found to be 2.1% (n = 7) at 100.0 μg L-1 concentration level. The method was successfully applied to the determination of selenium in water samples and selenium plus tablet.

  11. Preconcentration of organochlorine pesticides in aqueous samples by dispersive liquid-liquid microextraction based on solidification of floating organic drop after SPE with multiwalled carbon nanotubes.

    PubMed

    Mirzaei, Mohammad; Rakh, Mojgan

    2014-01-01

    SPE joined with dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO) as a novel technique combined with GC with electron-capture detection has been developed as a preconcentration technique for the determination of organochlorine pesticides (OCPs) in water samples. Aqueous samples were loaded onto multiwalled carbon nanotubes as sorbent. After the elution of the desired compounds from the sorbent by using acetone, the DLLME-SFO technique was performed on the obtained solution. Variables affecting the performance of both steps such as sample solution flow rate, breakthrough volume, type and volume of the elution, type and volume of extraction solvent and salt addition were studied and optimized. The new method provided an ultra enrichment factor (8280-28221) for nine OCPs. The calibration curves were linear in the range of 0.5-1000 ng/L, and the LODs ranged from 0.1-0.39 ng/L. The RSD, for 0.01 μg/L of OCPs, was in the range of 1.39-13.50% (n = 7). The recoveries of method in water samples were 70-113%.

  12. Solid-Phase Extraction Followed by Dispersive Liquid-Liquid Microextraction Based on Solidification of Floating Organic Drop for the Determination of Parabens.

    PubMed

    Hashemi, Beshare; Shamsipur, Mojtaba; Fattahi, Nazir

    2015-09-01

    A dispersive liquid-liquid microextraction based on solidification of floating organic drop method combined with solid-phase extraction (500-mg C18 sorbent) was developed for preconcentration and determination of some parabens. The experimental parameters influencing the extraction efficiency such as the type of extraction and disperser solvents, as well as their volumes, breakthrough volume, flow rate and salt addition were studied and optimized. The optimum experimental conditions found included: sample volume, 100 mL; KCl concentration, 1% (w/v); extraction solvent (1-undecanol) volume, 20 µL and disperser solvent (acetone) volume, 250 µL. Under the optimum experimental conditions, calibration graphs were linear in the range of 1-200 µg L(-1) with limits of detection ranged from 0.3 to 1.7 µg L(-1). The relative standard deviations were in the range of 1.2-3.1% (n = 5). The enrichment factors and absolute recoveries of parabens in different matrices were 245-1886 and 9.0-69.8%, respectively. The method was applied to the simultaneous determination of parabens in different matrices. The relative recoveries from water, shampoo and mouth rinse samples, which have been spiked at different levels of parabens, were 87.83-112.25%, 82.80-108.40% and 90.10-97.60%, respectively.

  13. Optimization of dispersive liquid-phase microextraction based on solidified floating organic drop combined with high-performance liquid chromatography for the analysis of glucocorticoid residues in food.

    PubMed

    Huang, Yuan; Zheng, Zhiqun; Huang, Liying; Yao, Hong; Wu, Xiao Shan; Li, Shaoguang; Lin, Dandan

    2017-05-10

    A rapid, simple, cost-effective dispersive liquid-phase microextraction based on solidified floating organic drop (SFOD-LPME) was developed in this study. Along with high-performance liquid chromatography, we used the developed approach to determine and enrich trace amounts of four glucocorticoids, namely, prednisone, betamethasone, dexamethasone, and cortisone acetate, in animal-derived food. We also investigated and optimized several important parameters that influenced the extraction efficiency of SFOD-LPME. These parameters include the extractant species, volumes of extraction and dispersant solvents, sodium chloride addition, sample pH, extraction time and temperature, and stirring rate. Under optimum experimental conditions, the calibration graph exhibited linearity over the range of 1.2-200.0ng/ml for the four analytes, with a reasonable linearity(r(2): 0.9990-0.9999). The enrichment factor was 142-276, and the detection limits was 0.39-0.46ng/ml (0.078-0.23μg/kg). This method was successfully applied to analyze actual food samples, and good spiked recoveries of over 81.5%-114.3% were obtained.

  14. Separation/preconcentration and determination of vanadium with dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO) and electrothermal atomic absorption spectrometry.

    PubMed

    Asadollahi, Tahereh; Dadfarnia, Shayessteh; Shabani, Ali Mohammad Haji

    2010-06-30

    A novel dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO) for separation/preconcentration of ultra trace amount of vanadium and its determination with the electrothermal atomic absorption spectrometry (ETAAS) was developed. The DLLME-SFO behavior of vanadium (V) using N-benzoyl-N-phenylhydroxylamine (BPHA) as complexing agent was systematically investigated. The factors influencing the complex formation and extraction by DLLME-SFO method were optimized. Under the optimized conditions: 100 microL, 200 microL and 25 mL of extraction solvent (1-undecanol), disperser solvent (acetone) and sample volume, respectively, an enrichment factor of 184, a detection limit (based on 3S(b)/m) of 7 ng L(-1) and a relative standard deviation of 4.6% (at 500 ng L(-1)) were obtained. The calibration graph using the preconcentration system for vanadium was linear from 20 to 1000 ng L(-1) with a correlation coefficient of 0.9996. The method was successfully applied for the determination of vanadium in water and parsley.

  15. Separation/preconcentration and determination of quercetin in food samples by dispersive liquid-liquid microextraction based on solidification of floating organic drop -flow injection spectrophotometry.

    PubMed

    Asadollahi, Tahereh; Dadfarnia, Shayessteh; Haji Shabani, Ali Mohammad; Amirkavei, Mooud

    2015-02-01

    A new dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFOD)-flow injection spectrophotometry (FI) method for the separation and preconcentration of trace amounts of quercetin was developed. 1-Undecanol and methanol was used as the extraction and disperser solvent, respectively. The factors influencing the extraction by DLLME-SFOD such as the volume of the extraction and disperser solvents, pH and concentration of salt were optimized. The optimal conditions were found to be; volume of the extraction solvent, 80 μL; the volume of the disperser solvent, 100 μL; and the pH of the sample, 3. The linear dynamic range and detection limit were 5.0 × 10(-8)-5.0 × 10(-7) mol L(-1) and 1 × 10(-8) mol L(-1), respectively. The relative standard deviation (R.S.D.) at 6.1 × 10(-8) mol L(-1) level of quercetin (n = 10) was found to be 2.8 %. The method was successfully applied to the determination of quercetin in the apple, grape, onion and tomato samples. Figureᅟ

  16. A link between structure, diffusion and rotations of hydrogen bonding tracers in ionic liquids.

    PubMed

    Araque, Juan C; Daly, Ryan P; Margulis, Claudio J

    2016-05-28

    When solutes are small compared to the size of the ions in an ionic liquid, energetic heterogeneities associated with charge enhanced (stiff) and charge depleted (soft) nanoenvironments are sampled. In a recent article [J. C. Araque et al., J. Phys. Chem. B 119(23), 7015-7029 (2015)], we explored large deviations from Stokes-Einstein translational diffusion caused by such a heterogeneity. The current article is set to explore the effect of soft and stiff solvent environments (i.e., structure) on OH-bond rotations in the case of water and small alcohols in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (Im1,2 (+)NTf2 (-)). Is solute rotational dynamics heterogeneous? If so, are solute rotations and translations coupled in the sense that stiff and soft solvent environments hinder or speed up both types of dynamics? For the systems studied here, there appears to be a clear connection between translations, rotations, and stiff/soft solvent environments. We also discuss interesting asymmetries of the correlation between solutes with anions and cations.

  17. Operating characteristics of rotating beds

    SciTech Connect

    Keyvani, M.; Gardner, N.C.

    1988-01-01

    Vapor-liquid contacting in high gravitational fields offers prospects for significant reductions in the physical size, capital, and operating costs of packed towers. Pressure drops, power requirements, mass transfer coefficients and liquid residence time distributions are reported for a rotating bed separator. The beds studied were rigid, foamed aluminum, with specific surface areas ranging from 650 to 3000 m{sup 2}/m{sup 2}. Gravitational fields were varied from 50 to 300g.

  18. The flow of a thin liquid film on a stationary and rotating disk. II - Theoretical prediction

    NASA Technical Reports Server (NTRS)

    Rahman, M. M.; Faghri, A.; Hankey, W. L.

    1990-01-01

    The existing theoretical models are improved and a systematic procedure to compute the free surface flow of a thin liquid film is suggested. The solutions for axisymmetric radial flow on a stationary horizontal disk and for the disk rotating around its axis are presented. The theoretical predictions are compared with the experimental data presented in Part I of this report. The analysis shows results for both supercritical and subcritical flows and the flow structure in the vicinity of a hydraulic jump which isolates these two flow types. The detailed flow structure in a hydraulic jump was computed and shown to contain regions of separation including a 'surface roller'. The effects of surface tension are found to be important near the outer edge of the disk where the fluid experiences a free fall. At other locations, the surface tension is negligible. For a rotating disk, the frictional resistance in the angular direction is found to be as important as that in the radial direction.

  19. High-resistance liquid-crystal lens array for rotatable 2D/3D autostereoscopic display.

    PubMed

    Chang, Yu-Cheng; Jen, Tai-Hsiang; Ting, Chih-Hung; Huang, Yi-Pai

    2014-02-10

    A 2D/3D switchable and rotatable autostereoscopic display using a high-resistance liquid-crystal (Hi-R LC) lens array is investigated in this paper. Using high-resistance layers in an LC cell, a gradient electric-field distribution can be formed, which can provide a better lens-like shape of the refractive-index distribution. The advantages of the Hi-R LC lens array are its 2D/3D switchability, rotatability (in the horizontal and vertical directions), low driving voltage (~2 volts) and fast response (~0.6 second). In addition, the Hi-R LC lens array requires only a very simple fabrication process.

  20. Capabilities and limitations of dispersive liquid-liquid microextraction with solidification of floating organic drop for the extraction of organic pollutants from water samples.

    PubMed

    Vera-Avila, Luz E; Rojo-Portillo, Tania; Covarrubias-Herrera, Rosario; Peña-Alvarez, Araceli

    2013-12-17

    Dispersive liquid-liquid microextraction with solidification of floating organic drop (DLLME-SFO) is one of the most interesting sample preparation techniques developed in recent years. Although several applications have been reported, the potentiality and limitations of this simple and rapid extraction technique have not been made sufficiently explicit. In this work, the extraction efficiency of DLLME-SFO for pollutants from different chemical families was determined. Studied compounds include: 10 polycyclic aromatic hydrocarbons, 5 pesticides (chlorophenoxy herbicides and DDT), 8 phenols and 6 sulfonamides, thus, covering a large range of polarity and hydrophobicity (LogKow 0-7, overall). After optimization of extraction conditions using 1-dodecanol as extractant, the procedure was applied for extraction of each family from 10-mL spiked water samples, only adjusting sample pH as required. Absolute recoveries for pollutants with LogKow 3-7 were >70% and recovery values within this group (18 compounds) were independent of structure or hydrophobicity; the precision of recovery was very acceptable (RSD<12%) and linear behavior was observed in the studied concentration range (r(2)>0.995). Extraction recoveries for pollutants with LogKow 1.46-2.8 were in the range 13-62%, directly depending on individual LogKow values; however, good linearity (r(2)>0.993) and precision (RSD<6.5%) were also demonstrated for these polar solutes, despite recovery level. DLLME-SFO with 1-dodecanol completely failed for extraction of compounds with LogKow≤1 (sulfa drugs), other more polar extraction solvents (ionic liquids) should be explored for highly hydrophilic pollutants.

  1. A New Open-Source Nuclear Equation of State Framework based on the Liquid-Drop Model with Skyrme Interactions

    NASA Astrophysics Data System (ADS)

    da Silva Schneider, Andre; Roberts, Luke; Ott, Christian

    2017-01-01

    The equation of state (EOS) of dense matter is an essential ingredient for numerical simulations of many astrophysical phenomena. We implement a modular open-source Fortran 90 code to construct the EOS of hot dense matter for astrophysical applications. For high density matter we use a non-relativistic liquid-drop description of nuclei that includes surface effects in a single nucleus approximation (SNA). The model is based on the work of Lattimer and Swesty and has been generalized to accommodate most Skyrme parametrizations available in the literature. Low density matter is described as an ensemble of nuclei in nuclear statistical equilibrium (NSE). The transition between the SNA and NSE regimes is performed via a continuous function that smoothly blends their Helmholtz free energy. To account for the existence of 2 solar mass neutron stars, we extend the formalism to allow for a stiffening of the EOS at densities above 3 times nuclear saturation density, where the properties of matter are presently poorly constrained. We study how different Skyrme parametrizations affect the EOS, neutron star mass-radius relationships, and the spherically symmetric collapse and post-bounce supernova evolution of massive stars.

  2. A New Open-Source Nuclear Equation of State Framework based on the Liquid-Drop Model with Skyrme Interactions

    NASA Astrophysics Data System (ADS)

    da Silva Schneider, Andre; Roberts, Luke F.; Ott, Christian D.

    2016-09-01

    The equation of state (EoS) of dense matter is an essential ingredient for numerical simulations of many astrophysical phenomena. We implement a modular open-source Fortran 90 code to construct EoS of hot dense matter for astrophysical applications. For high density matter we use a non-relativistic liquid-drop description of nuclei that includes surface effects in a single nucleus approximation (SNA). The model is based on the work of Lattimer and Swesty and has been generalized to accommodate most Skyrme parametrizations available in the literature. Low density matter is described as an ensemble of nuclei in nuclear statistical equilibrium (NSE). The transition between the two regimes is performed via a continuous function that smoothly blends their Helmholtz free energy. To account for the existence of 2 solar mass neutron stars, we extend the formalism to allow for a stiffening of the EoS at densities above 3 times nuclear saturation density, where the properties of matter are presently poorly constrained. We study how different Skyrme parametrizations affect the EoS, neutron star mass-radius relationships, and the spherically symmetric collapse and post-bounce supernova evolution of massive stars.

  3. Multipulse polarisation selective spectroscopy of rotational and vibrational responses of molecules in a liquid

    SciTech Connect

    Nikiforov, V G

    2013-02-28

    The amplitude control of time-resolved optical responses in a liquid is theoretically analysed under nonresonant irradiation of the system by a train of femtosecond pulses with parallel and orthogonal polarisations. The control parameters, specifying the excitation scenarios, are the duration of pulses, their relative intensities, polarisation, and the delays between the pulses. It is shown that the choice of specific excitation scenarios transfers the system into a state in which only one response is detected from a set of responses of coherent intramolecular Raman active vibrational modes, coherent molecular librations and orientational rotations. (laser spectroscopy)

  4. Rotational dynamics of coumarin-153 and 4-aminophthalimide in 1-ethyl-3-methylimidazolium alkylsulfate ionic liquids: effect of alkyl chain length on the rotational dynamics.

    PubMed

    Das, Sudhir Kumar; Sarkar, Moloy

    2012-01-12

    Rotational dynamics of two neutral organic solutes, coumarin-153 (C-153) and 4-aminophthalimide (AP), with only the latter having hydrogen-bond-donating ability, has been investigated in a series of 1-ethyl-3-methylimidazolium alkyl sulfate ionic liquids as a function of temperature. The ionic liquids differ only in the length of the linear alkyl side chain (alkyl = ethyl, butyl, hexyl, and octyl) on the anionic moiety. The present study has been undertaken to examine the role of alkyl side chains on the rotational dynamics of the two solutes in these ionic liquids. Analysis of the results using Stokes-Einstein-Debye hydrodynamic theory indicates that the rotational dynamics of C-153 lies between the stick and slip boundary condition in the ethyl analogue and finally reaches subslip condition as in case of the octyl substituent. The observed rotational behavior of C-153 has been explained on the basis of an increase in the size of the solvent, which offers lower friction for solute rotation. On the other hand, AP shows superstick behavior in the ethyl system and exceeds the stick limit in the octyl derivative. Superstick behavior of AP has been attributed to the specific hydrogen-bonding interaction between AP and the sulfate moiety. Proton NMR investigation confirms the hydrogen-bonding interaction between the N-H hydrogen of AP and the ionic liquid. The decrease in rotational coupling constant values for AP with increasing length of alkyl side chains has been attributed to the decrease in the solute-solvent-specific interaction with an increase in the alkyl side chain length on the sulfate moiety.

  5. Single-drop liquid-phase microextraction for the determination of hypericin, pseudohypericin and hyperforin in biological fluids by high performance liquid chromatography.

    PubMed

    Gioti, Eleni M; Skalkos, Dimitris C; Fiamegos, Yiannis C; Stalikas, Constantine D

    2005-11-04

    The analysis of hypericin, pseudohypericin (collectively called in this study hypericins) and hyperforin in biological fluids is reported using single-drop liquid-phase microextraction in conjunction with HPLC-UV-fluorescence detection. A new option for analysis of the active principle constituents in biological samples is proposed, reducing the steps required prior to analysis. There are several parameters which determine the mass transfer such as the extraction solvent, drop and sample volumes, extraction time and temperature, pH and ionic strength, stirring rate and depth of needle tip in the bulk solution. These parameters were chosen to optimize the performance in the current study. The method was validated with respect to precision, accuracy and specificity. The intra-day precision values were below 2.3% for the high concentration level of control samples and 6.2% for the low level. The respective inter-day precision values were calculated to be below 4.4 and 7.1%, respectively, for the two concentration levels. Accuracy of the method, calculated as relative error, ranged from -2.6 to 7.0%. It was demonstrated that as long as the extraction procedure is consistently applied, quantitative analysis is performed accurately and reproducibly in human urine and plasma samples. Limits of quantitation (LOQs) in urine were calculated to be 3, 6 and 12 ng/ml for pseudohypericin, hypericin and hyperforin, respectively. Slightly higher limits were measured in plasma, i.e. 5, 12 and 20 ng/ml, for the respective analytes.

  6. Instant freezing of impacting wax drops

    NASA Astrophysics Data System (ADS)

    Ponomarenko, Alexandre; Virot, Emmanuel; Rubinstein, Shmuel

    2015-11-01

    We present the impact of hot liquid drops of wax on surfaces whose temperature is below the solidifying temperature of the drops. During the fall the drops remain mostly liquid, but upon impact, their temperature quickly decreases resulting in the solidification of the drop. Depending on the impact energy, drops size and the temperature difference between the drop and the surface this results in plethora of solid shapes: simple lenses, triangular drops, spherical caps and popped popcorn shapes.

  7. Dispersive liquid-liquid microextraction method based on solidification of floating organic drop for extraction of organochlorine pesticides in water samples.

    PubMed

    Leong, Mei-I; Huang, Shang-Da

    2009-11-06

    A new simple and rapid dispersive liquid-liquid microextraction method has been developed for the extraction and analysis of organochlorine pesticides (OCPs) in water samples. The method is based on the solidification of a floating organic drop (DLLME-SFO) and is combined with gas chromatography/electron capture detection (GC/ECD). Very little solvent is required in this method. The disperser solvent (200microL acetonitrile) containing 10microL hexadecane (HEX) is rapidly injected by a syringe into the 5.0mL water sample. After centrifugation, the fine HEX droplets (6+/-0.5microL) float at the top of the screw-cap test tube. The test tube is then cooled in an ice bath. After 5min, the HEX solvent solidifies and is then transferred into a conical vial, where it melts quickly at room temperature, and 1microL of it is injected into a gas chromatograph for analysis. Under optimum conditions, the enrichment factors and extraction recoveries are high and range between 37-872 and 82.9-102.5%, respectively. The linear range is wide (0.025-20microgL(-1)), and the limits of detection are between 0.011 and 0.11microgL(-1) for most of the analytes. The relative standard deviation (RSD) for 1microgL(-1) of OCPs in water was in the range of 5.8-8.8%. The performance of the method was gauged by analyzing samples of lake and tap water.

  8. Dispersive liquid-liquid microextraction method based on solidification of floating organic drop combined with gas chromatography with electron-capture or mass spectrometry detection.

    PubMed

    Leong, Mei-I; Huang, Shang-Da

    2008-11-21

    A simple dispersive liquid-liquid microextraction (DLLME) method based on solidification of a floating organic drop (DLLME-SFO) technique combined with gas chromatography/electron-capture detection (GC/ECD) or gas chromatography/mass spectrometry (GC/MS) has been developed. The proposed method is simple, low in cost, and of high precision. It overcomes the most important problem in DLLME, the high-toxic solvent used. Halogenated organic compounds (HOCs) in water samples were determined as the model compounds. The parameters optimized for the DLLME-SFO technique were as follows: A mixture of 0.5 mL acetone, containing 10 microL 2-dodecanol (2-DD-OH), was rapidly injected by syringe into the 5 mL water sample. After centrifugation, the fine 2-DD-OH droplets (8+/-0.5 microL) were floated at the top of the screwcap test tube. The test tube was then cooled in an ice bath. After 5 min the 2-DD-OH solvent had solidified and was then transferred into a conical vial; it melted quickly at room temperature and 3 microL (for GC/ECD) or 2 microL (for GC/MS) of it was injected into a gas chromatograph for analysis. The limit of detection (LOD) for this technique was 0.005-0.05microgL(-1) for GC/ECD and was 0.005-0.047 microgL(-1) for GC/MS, respectively. The linear range of the calibration curve of DLLME-SFO was from 0.01 to 500 microgL(-1) with a coefficient of estimation (r2)>0.996 for GC/ECD and was from 0.02 to 500 microgL(-1) with a coefficient of estimation (r2)>0.996 for GC/MS.

  9. Low-density solvent-based dispersive liquid-liquid microextraction combined with single-drop microextraction for the fast determination of chlorophenols in environmental water samples by high performance liquid chromatography-ultraviolet detection.

    PubMed

    Li, Xiaoyi; Xue, Aifang; Chen, Hao; Li, Shengqing

    2013-03-08

    A new format of fast three-phase microextraction by combining low-density solvent-based dispersive liquid-liquid microextraction (DLLME) and single-drop microextraction (SDME) was for the first time developed for the determination of chlorophenols in environmental water samples. The extraction procedure includes a 2 min DLLME pre-extraction and a 10 min SDME back-extraction. A portion of low-density solvent (toluene) was used as organic phase and injected into the aqueous sample (donor phase) with methanol as disperser. The analytes were pre-extracted into the organic phase within 2 min. A thin layer of the organic phase formed on the top of the aqueous phase by a 2 min centrifugation. Then a drop of acceptor solution was introduced into the upper layer and SDME was carried out for the back-extraction. The stirring step typically involved in SDME and LLLME is avoided with the benefit of the high speed and efficiency of DLLME pre-extraction. After extraction, the acceptor drop was withdrawn and directly injected into a high performance liquid chromatography instrument with ultraviolet detection for analysis. Five chlorophenols, 4-chlorophenol, 2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, and pentachlorophenol, were selected as model compounds for developing and evaluating the method. Factors affecting extraction efficiency were studied, including the organic solvent, the disperser solvent, the composition of donor phase and acceptor phase, the volume of acceptor microdrop, and the extraction time. At optimal conditions, the method showed low detection limit (0.016-0.084 μg/L) for the five chlorophenols, good linearity (from 0.2-250 to 1.0-250 μg/L, depending on the analytes) and repeatability (RSD below 8.2, n=5). The simple, fast, and efficient feature of the proposed method was demonstrated by the analysis of chlorophenols in environmental water samples.

  10. Development of simultaneous measurement system of birefringence, optical rotational power, and transmission spectra for chiral liquid crystal phases

    NASA Astrophysics Data System (ADS)

    Feng, Zhengyu; Ishikawa, Ken

    2016-05-01

    A novel experimental setup used to measure the important optical properties of liquid crystal materials is proposed. The setup allows us to measure electric-field-induced birefringence, optical rotational power, and transmission spectra consecutively. This system can be widely applied to characterize liquid crystal materials including blue phases, ferroelectric liquid crystals, and other chiral phases. We adopted this system to study the phase transition behavior of a V-shape switching ferroelectric liquid crystal mixture and made an important correction of experimental results previously reported by Sandhya et al. [ Europhys. Lett. 90, 56005 (2010)]. This finding proves the advantage of this system compared with the measurement method using individual systems.

  11. Analysis of Hydrodynamics and Heat Transfer in a Thin Liquid Film Flowing over a Rotating Disk by Integral Method

    NASA Technical Reports Server (NTRS)

    Basu, S.; Cetegen, B. M.

    2005-01-01

    An integral analysis of hydrodynamics and heat transfer in a thin liquid film flowing over a rotating disk surface is presented for both constant temperature and constant heat flux boundary conditions. The model is found to capture the correct trends of the liquid film thickness variation over the disk surface and compare reasonably well with experimental results over the range of Reynolds and Rossby numbers covering both inertia and rotation dominated regimes. Nusselt number variation over the disk surface shows two types of behavior. At low rotation rates, the Nusselt number exhibits a radial decay with Nusselt number magnitudes increasing with higher inlet Reynolds number for both constant wall temperature and heat flux cases. At high rotation rates, the Nusselt number profiles exhibit a peak whose location advances radially outward with increasing film Reynolds number or inertia. The results also compare favorably with the full numerical simulation results from an earlier study as well as with the reported experimental results.

  12. Nano-electromechanical rotation of graphene and giant enhancement in dielectric anisotropy in a liquid crystal

    SciTech Connect

    Basu, Rajratan Kinnamon, Daniel; Garvey, Alfred

    2015-05-18

    A nematic liquid crystal (LC) is doped with dilute concentrations of pristine monolayer graphene (GP) flakes, and the LC + GP hybrids are found to exhibit a dramatic increase in the dielectric anisotropy. Electric field-dependent conductance studies reveal that the graphene flakes follow the nematic director that mechanically rotates on increasing an applied electric field. Further studies show that the π–π electron stacking, between the graphene's honeycomb structure and the LC's benzene rings, stabilizes pseudo-nematic domains that collectively amplify the dielectric anisotropy by improving the orientational order parameter in the nematic phase. These anisotropic domains interact with the external electric field, resulting in a nonzero dielectric anisotropy in the isotropic phase as well. The enhancement in dielectric anisotropy, due to the LC–graphene coupling, is found to have subsequent positive impacts on the LC's orientational threshold field and elasticity that allows the nematic director to respond quicker on switching the electric field off.

  13. Highly efficient pulse cleaner via nonlinear ellipse rotation in liquid CS2 for ultrashort pulses.

    PubMed

    Liu, H J; Sun, Q B; Huang, N; Wen, J; Wang, Z L

    2013-06-01

    A highly efficient pulse cleaner based on nonlinear ellipse rotation (NER) in a liquid medium of CS(2) is investigated for the temporal contrast enhancement of ultrashort pulses. In theory, a nonlinear transmissivity higher than 60% can be achieved with the temporal contrast improved by about four orders of magnitude, on the condition that the extinction ratio of the polarizer-analyzer pair is better than 10(4). In a proof of principle experiment, the cleaned pulses at the mJ level with total transmissivity as high as 30% are obtained via NER, in which the temporal contrast is enhanced by about three orders of magnitude. This provides a simple and feasible technology for improving the temporal contrast of an ultrashort and ultraintense laser system in the future.

  14. The motion of a thin liquid layer on the outer surface of a rotating cylinder

    NASA Astrophysics Data System (ADS)

    Morad, A. M.; Zhukov, M. Yu.

    2015-01-01

    We derive the shallow water equations describing the motion of a thin liquid film on the outer surface of a rotating cylinder. These equations are an analogue of the modified Boussinesq equations describing shallow water flows with constant vorticity. The standard multi-scale methods are employed to construct asymptotic equations in the long-wave approximation. These asymptotic equations are analyzed using the hodograph method. It is found that for the particular case of a dispersionless irrotational flow, the equations describing flows on the outer surface of a cylinder reduce to elliptic equations. Numerical evaluation of the exact solutions obtained shows that the asymptotic equations possess a rich variety of solutions representing various wave patterns.

  15. Electric field induced rotation of polymer cholesteric liquid crystal flakes: mechanisms and applications

    NASA Astrophysics Data System (ADS)

    Kosc, Tanya Z.; Marshall, Kenneth L.; Jacobs, Stephen D.; Lambropoulos, John C.

    2002-12-01

    Electric fields can induce motion of polymer cholesteric liquid crystal (pCLC) flakes suspended in a fluid medium. The platelet-shaped pCLC flakes with a Grandjean texture show strong selective reflection when lying flat in the plane of a conventional cell. As their orientation with respect to normally incident light changes, their selective reflection color shifts toward the blue and diminishes until the flakes are no longer easily visible beyond 7-12° of rotation. Reproducibility and control of motion has been observed in moderately conductive host fluid. Flakes in such hosts do not respond to a DC electric field, but they rotate 90° in an AC field within a given frequency band. The response times and frequency regions for motion depend partially on the field magnitude, the dielectric properties of the host fluid and the flake geometry. We observe flakes reorienting in less than 500 ms in an electric field of 0.17 Vrms/μm, while sub-second reorientation is seen in fields as low as 5x10-2 Vrms/μm. This response time is comparable with typical electronic-paper applications, but with a significantly lower electric field. Displays using pCLC flakes would not require backlighting, sheet polarizers, color filters or alignment layers. Numerous additional applications for pCLC flakes are envisioned, including filters, polarizers, and spatial light modulators.

  16. Characterization for Cassie-Wenzel wetting transition based on the force response in the process of squeezing liquid drops by two parallel superhydrophobic surfaces

    NASA Astrophysics Data System (ADS)

    Li, Jian

    2016-06-01

    Application of superhydrophobic surfaces is partly limited by the escaping of the entrapped air beneath the liquid sitting on the superhydrophobic surfaces, i.e., the so-called Cassie-Wenzel wetting transition. Here, to characterize this wetting transition, a linear force response relation with certain abnormal systematic deflection showing the wetting transition information is constructed for the process of squeezing the test liquid drop by two parallel structured (superhydrophobic) surfaces. The linear force response relation is validated by replotting the experimental data from the former work. And then the wetting transition information is investigated on a numerically generated force response curve with certain errors by taking into account the liquid pressure variation during the wetting transition. Results show that the wetting transition can cause an obvious bulge on the linear force response curve. We believe that this method has a potential application in characterizing the robustness of superhydrophobic surfaces.

  17. Comprehensive quantitative analysis of Chinese patent drug YinHuang drop pill by ultra high-performance liquid chromatography quadrupole time of flight mass spectrometry.

    PubMed

    Wong, Tin-Long; An, Ya-Qi; Yan, Bing-Chao; Yue, Rui-Qi; Zhang, Tian-Bo; Ho, Hing-Man; Ren, Tian-Jing; Fung, Hau-Yee; Ma, Dik-Lung; Leung, Chung-Hang; Liu, Zhong-Liang; Pu, Jian-Xin; Han, Quan-Bin; Sun, Han-Dong

    2016-06-05

    YinHuang drop pill (YHDP) is a new preparation, derived from the traditional YinHuang (YH) decoction. Since drop pills are one of the newly developed forms of Chinese patent drugs, not much research has been done regarding the quality and efficacy. This study aims to establish a comprehensive quantitative analysis of the chemical profile of YHDP. ultra high-performance liquid chromatography quadrupole time of flight mass spectrometry (UHPLC-Q-TOF-MS/MS) was used to identify 34 non-sugar small molecules including 15 flavonoids, 9 phenolic acids, 5 saponins, 1 iridoid, and 4 iridoid glycosides in YHDP samples, and 26 of them were quantitatively determined. Sugar composition of YHDP in terms of fructose, glucose and sucrose was examined via a high performance liquid chromatography-evaporative light scattering detector on an amide column (HPLC-NH2P-ELSD). Macromolecules were examined by high performance gel permeation chromatography coupled with ELSD (HPGPC-ELSD). The content of the drop pill's skeleton component PEG-4000 was also quantified via ultra-high performance liquid chromatography coupled with charged aerosol detector (UHPLC-CAD). The results showed that up to 73% (w/w) of YHDP could be quantitatively determined. Small molecules accounted for approximately 5%, PEG-4000 represented 68%, while no sugars or macromolecules were found. Furthermore, YHDP showed no significant differences in terms of daily dosage, compared to YinHuang granules and YinHuang oral liquid; however, it has a higher small molecules content compared to YinHuang lozenge.

  18. The Effect of Diluted Penetration Enhancer in Nebulized Mist versus Liquid Drop Preparation Forms on Retrobulbar Blood Flow in Healthy Human Subjects

    PubMed Central

    Primus, Sally; Januleviciene, Ingrida; Siesky, Brent; Gerber, Austin; Egan, Patrick; Amireskandari, Annahita; Siaudvytyte, Lina; Barsauskaite, Ruta; Harris, Alon

    2012-01-01

    The aim of this study was to compare the effects of nebulized mist and liquid drop applications on retrobulbar blood flow. A prospective, non-randomized clinical trial was used to collect data from 40 healthy human eyes. Color Doppler Imaging determined peak systolic (PSV) and end diastolic (EDV) blood flow velocities and resistance index (RI) in the ophthalmic artery after both applications. Measurements were taken at baseline and at 1 min post-treatment in both eyes with 5 min measurements in the treatment eye only. p values ≤ 0.05 were considered statistically significant. Mist application to treatment eye produced an increase in 1 min and 5 min PSV and EDV (0.001 < p < 0.03) and a decrease in 5 min RI (p = 0.01), with no significant changes in PSV, EDV or RI of control eye or in treatment eye 1 min RI (p > 0.05). Drop application to treatment eye produced an increase in PSV (p < 0.001) and EDV (p = 0.01) at 1 min, with an increase in control eye 1 min PSV and EDV (p = 0.03). There were no statistically significant changes in treatment eye PSV, EDV and RI after 5 min (p > 0.05). The use of nebulized mist may provide an effective alternative to liquid drop medication application. PMID:24300298

  19. Trace analysis of three antihistamines in human urine by on-line single drop liquid-liquid-liquid microextraction coupled to sweeping micellar electrokinetic chromatography and its application to pharmacokinetic study.

    PubMed

    Gao, Wenhua; Chen, Yunsheng; Chen, Gaopan; Xi, Jing; Chen, Yaowen; Yang, Jianying; Xu, Ning

    2012-09-01

    A rapid and efficient dual preconcentration method of on-line single drop liquid-liquid-liquid microextraction (SD-LLLME) coupled to sweeping micellar electrokinetic chromatography (MEKC) was developed for trace analysis of three antihistamines (mizolastine, chlorpheniramine and pheniramine) in human urine. Three analytes were firstly extracted from donor phase (4 mL urine sample) adjusted to alkaline condition (0.5 M NaOH). The unionized analytes were subsequently extracted into a drop of n-octanol layered over the urine sample, and then into a microdrop of acceptor phase (100 mM H(3)PO(4)) suspended from a capillary inlet. The enriched acceptor phase was on-line injected into capillary with a height difference and then analyzed directly by sweeping MEKC. Good linear relationships were obtained for all analytes in a range of 6.25 × 10(-6) to 2.5 × 10(-4)g/L with correlation coefficients (r) higher than 0.987. The proposed method achieved limits of detections (LOD) varied from 1.2 × 10(-7) to 9.5 × 10(-7)g/L based on a signal-to-noise of 3 (S/N=3) with 751- to 1372-fold increases in detection sensitivity for analytes, and it was successfully applied to the pharmacokinetic study of three antihistamines in human urine after an oral administration. The results demonstrated that this method was a promising combination for the rapid trace analysis of antihistamines in human urine with the advantages of operation simplicity, high enrichment factor and little solvent consumption.

  20. Two-phase flow boiling frictional pressure drop of liquid nitrogen in horizontal circular mini-tubes: Experimental investigation and comparison with correlations

    NASA Astrophysics Data System (ADS)

    Chen, Xingya; Chen, Shuangtao; Chen, Jun; Li, Jiapeng; Liu, Xiufang; Chen, Liang; Hou, Yu

    2017-04-01

    The two-phase flow boiling characteristics of liquid nitrogen (LN2) in horizontal circular mini-tubes were experimentally studied. Experiments were performed in a wide range of flow conditions, e.g. inlet pressure from 0.17 to 0.35 MPa, mass flux from 140 to 330 kg/m2 s, heat flux from 0.5 to 69.4 kW/m2 and tube diameters of 2.92 mm and 3.96 mm. The influences of mass flux, heat flux, and inlet pressure on the pressure drop were discussed. The results indicated that the pressure drop increases with the increasing mass flux and heat flux but decreases with the increasing inlet pressure. But the influence of heat flux on the frictional pressure drop of LN2 was weaker than mass flux and inlet pressure. The frictional pressure drop of two-phase flow of LN2 was compared with homogeneous model and several semi-empirical correlations. An improved correlation based on the Lockhart-Martinelli model, which used coefficient C as a function of Reynolds number and Weber number was proposed.

  1. Experiments on the Flow of a Thin Liquid Film Over a Horizontal Stationary and Rotating Disk Surface

    NASA Technical Reports Server (NTRS)

    Ozar, B.; Cetegen, B. M.; Faghri, A.

    2003-01-01

    Experiments on characterization of thin liquid films flowing over stationary and rotating disk surfaces are described. The thin liquid film was created by introducing deionized water from a flow collar at the center of an aluminum disk with a known initial film thickness and uniform radial velocity. Radial film thickness distribution was measured using a non-intrusive laser light interface reflection technique that enabled the measurement of the instantaneous film thickness over a finite segment of the disk. Experiments were performed for a range of flow rates between 3.01pm and 15.01pm, corresponding to Reynolds numbers based on the liquid inlet gap height and velocity between 238 and 1,188. The angular speed of the disk was varied from 0 rpm to 300 rpm. When the disk was stationary, a circular hydraulic jump was present in the liquid film. The liquid-film thickness in the subcritical region (down-stream of the hydraulic jump) was an order of magnitude greater than that in the supercritical region (upstream of the hydraulic jump) which was of the order of 0.3 mm. As the Reynolds number increased, the hydraulic jump migrated toward the edge of the disk. In the case of rotation, the liquid-film thickness exhibited a maximum on the disk surface. The liquid-film inertia and friction influenced the inner region where the film thickness progressively increased. The outer region where the film thickness decreased was primarily affected by the centrifugal forces. A flow visualization study of the thin film was also performed to determine the characteristics of the waves on the free surface. At high rotational speeds, spiral waves were observed on the liquid film. It was also determined that the angle of the waves which form on the liquid surface was a function of the ratio of local radial to tangential velocity.

  2. Mechanics of liquid helium in a partially filled rotating dewar in low gravity with application to Gravity Probe-B

    NASA Technical Reports Server (NTRS)

    Schafer, C. F.; Lowry, S. A.

    1983-01-01

    The Gravity Probe-B spacecraft is composed largely of a liquid helium dewar containing an experiment package. It is shown that an unsymmetric liquid helium distribution in the dewar can cause unacceptably high forces, gravitational and gravity gradient forces, at the experiment location. It is further shown that for the planned spacecraft configuration and operational parameters, it is very likely that the liquid helium distribution in the dewar will be unsymmetric. The required symmetry can be attained by using higher operational spacecraft rotation rates.

  3. Influence of the fluid structure on the binding potential: Comparing liquid drop profiles from density functional theory with results from mesoscopic theory.

    PubMed

    Hughes, Adam P; Thiele, Uwe; Archer, Andrew J

    2017-02-14

    For a film of liquid on a solid surface, the binding potential g(h) gives the free energy as a function of the film thickness h and also the closely related (structural) disjoining pressure Π=-∂g/∂h. The wetting behaviour of the liquid is encoded in the binding potential and the equilibrium film thickness corresponds to the value at the minimum of g(h). Here, the method we developed in the work of Hughes et al. [J. Chem. Phys. 142, 074702 (2015)], and applied with a simple discrete lattice-gas model, is used with continuum density functional theory (DFT) to calculate the binding potential for a Lennard-Jones fluid and other simple liquids. The DFT used is based on fundamental measure theory and so incorporates the influence of the layered packing of molecules at the surface and the corresponding oscillatory density profile. The binding potential is frequently input in mesoscale models from which liquid drop shapes and even dynamics can be calculated. Here we show that the equilibrium droplet profiles calculated using the mesoscale theory are in good agreement with the profiles calculated directly from the microscopic DFT. For liquids composed of particles where the range of the attraction is much less than the diameter of the particles, we find that at low temperatures g(h) decays in an oscillatory fashion with increasing h, leading to highly structured terraced liquid droplets.

  4. Influence of the fluid structure on the binding potential: Comparing liquid drop profiles from density functional theory with results from mesoscopic theory

    NASA Astrophysics Data System (ADS)

    Hughes, Adam P.; Thiele, Uwe; Archer, Andrew J.

    2017-02-01

    For a film of liquid on a solid surface, the binding potential g(h) gives the free energy as a function of the film thickness h and also the closely related (structural) disjoining pressure Π =-∂g /∂h . The wetting behaviour of the liquid is encoded in the binding potential and the equilibrium film thickness corresponds to the value at the minimum of g(h). Here, the method we developed in the work of Hughes et al. [J. Chem. Phys. 142, 074702 (2015)], and applied with a simple discrete lattice-gas model, is used with continuum density functional theory (DFT) to calculate the binding potential for a Lennard-Jones fluid and other simple liquids. The DFT used is based on fundamental measure theory and so incorporates the influence of the layered packing of molecules at the surface and the corresponding oscillatory density profile. The binding potential is frequently input in mesoscale models from which liquid drop shapes and even dynamics can be calculated. Here we show that the equilibrium droplet profiles calculated using the mesoscale theory are in good agreement with the profiles calculated directly from the microscopic DFT. For liquids composed of particles where the range of the attraction is much less than the diameter of the particles, we find that at low temperatures g(h) decays in an oscillatory fashion with increasing h, leading to highly structured terraced liquid droplets.

  5. Investigation of wetting characteristics of liquid iron on dense MgAION-based ceramics by X-ray sessile drop technique

    NASA Astrophysics Data System (ADS)

    Zhang, Z. T.; Matsushita, T.; Seetharaman, S.; Li, W. C.

    2006-06-01

    The wetting characteristics of liquid iron on dense MgAION-based composite ceramics were investigated using X-ray sessile drop technique. The contact angles were measured on substrates of different composites as functions of temperature and varying partial pressures of oxygen. The results with pure argon gas showed that contact angles kept almost constant in the temperature range 1823 to 1873 K. The contact angle was found to show a slight increase with increasing boron nitride (BN) content in MgAION-BN composites. These are attributed to the higher contact angle between BN substrate and liquid iron drop compared with that obtained for MgAION substrate. When the CO-CO2-Ar gas mixtures were introduced into the system, the contact angle showed an initial quick decrease followed by a slow decrease and then a period of nearly constant contact angle at a given temperature corresponding to the steady-state condition. Even in this case, BN seemed to cause an increase in the equilibrium contact angle. The equilibrium contact angle was found to decrease with increasing temperature. XRD results indicated that the substrate was oxidized and the oxidation products combined with FeO formed by the oxidation of the iron drop to from FeAl2O4 and Mg1-xFex) These were likely to form a ternary FeO-Al2O3-MgO slag or a quaternary slag by combining with B2O3. An interesting observation is that the iron drop moved away from the original site, probably due to the Marangoni effect.

  6. Dissociation of doubly charged clusters of lithium acetate: Asymmetric fission and breakdown of the liquid drop model: Dissociation of doubly charged clusters of lithium acetate

    SciTech Connect

    Shukla, Anil

    2016-06-08

    Unimolecular and collision-induced dissociation of doubly charged lithium acetate clusters, (CH3COOLi)nLi22+, demonstrated that Coulomb fission via charge separation is the dominant dissociation process with no contribution from the neutral evaporation processes for all such ions from the critical limit to larger cluster ions, although latter process have normally been observed in all earlier studies. These results are clearly in disagreement with the Rayleigh’s liquid drop model that has been used successfully to predict the critical size and explain the fragmentation behavior of multiply charged clusters.

  7. Drag on Sessile Drops

    NASA Astrophysics Data System (ADS)

    Milne, Andrew J. B.; Fleck, Brian; Nobes, David; Sen, Debjyoti; Amirfazli, Alidad; University of Alberta Mechanical Engineering Collaboration

    2013-11-01

    We present the first ever direct measurements of the coefficient of drag on sessile drops at Reynolds numbers from the creeping flow regime up to the point of incipient motion, made using a newly developed floating element differential drag sensor. Surfaces of different wettabilities (PMMA, Teflon, and a superhydrophobic surface (SHS)), wet by water, hexadecane, and various silicone oils, are used to study the effects of drop shape, and fluid properties on drag. The relation between drag coefficient and Reynolds number (scaled by drop height) varies slightly with liquid-solid system and drop volume with results suggesting the drop experiences increased drag compared to similar shaped solid bodies due to drop oscillation influencing the otherwise laminar flow. Drops adopting more spherical shapes are seen to experience the greatest force at any given airspeed. This indicates that the relative exposed areas of drops is an important consideration in terms of force, with implications for the shedding of drops in applications such as airfoil icing and fuel cell flooding. The measurement technique used in this work can be adapted to measure drag force on other deformable, lightly adhered objects such as dust, sand, snow, vesicles, foams, and biofilms. The authours acknowledge NSERC, Alberta Innovates Technology Futures, and the Killam Trusts.

  8. A new extended diffusion model for rotational motion of symmetric-top molecules in the liquid phase

    NASA Astrophysics Data System (ADS)

    Lascombe, J.; Besnard, M.; Maraval, P.

    1982-11-01

    In this paper, we present first a model called partially relaxed rotation model (PRR), to treat the reorientation motion of a symmetric top which rotates freely around its molecular axis with a tumbling motion relaxed according to a characteristic time τ 1. We show that this model can easily be extended to develop a 2τ model where both tumbling and spinning motion around the molecular axis are relaxed with a second characteristic time τ 2. As limiting cases one can obtain from the 2τ model, the Gordon-McClung and PRR models. Next, we illustrate the PPR and 2τ models by calculating Raman and infrared rotational spectral densities of liquid cyclopropane at room temperature. We also discuss in the PRR model the influence of the characteristic relaxation time τ 1, on the Raman rotational profile Î21( overlineν) Finally, we emphasize on the example of room-temperature liquid cyclopropane, the advantage of the PRR model to treat a E″ degenerated Raman profile with negligible Coriolis vibrational-rotational interaction. bl

  9. Large amplitude drop shape oscillations

    NASA Technical Reports Server (NTRS)

    Trinh, E. H.; Wang, T. G.

    1982-01-01

    An experimental study of large amplitude drop shape oscillation was conducted in immiscible liquids systems and with levitated free liquid drops in air. In liquid-liquid systems the results indicate the existence of familiar characteristics of nonlinear phenomena. The resonance frequency of the fundamental quadrupole mode of stationary, low viscosity Silicone oil drops acoustically levitated in water falls to noticeably low values as the amplitude of oscillation is increased. A typical, experimentally determined relative frequency decrease of a 0.5 cubic centimeters drop would be about 10% when the maximum deformed shape is characterized by a major to minor axial ratio of 1.9. On the other hand, no change in the fundamental mode frequency could be detected for 1 mm drops levitated in air. The experimental data for the decay constant of the quadrupole mode of drops immersed in a liquid host indicate a slight increase for larger oscillation amplitudes. A qualitative investigation of the internal fluid flows for such drops revealed the existence of steady internal circulation within drops oscillating in the fundamental and higher modes. The flow field configuration in the outer host liquid is also significantly altered when the drop oscillation amplitude becomes large.

  10. In-drop capillary spooling of spider capture thread inspires hybrid fibers with mixed solid–liquid mechanical properties

    PubMed Central

    Elettro, Hervé; Neukirch, Sébastien; Vollrath, Fritz; Antkowiak, Arnaud

    2016-01-01

    An essential element in the web-trap architecture, the capture silk spun by ecribellate orb spiders consists of glue droplets sitting astride a silk filament. Mechanically this thread presents a mixed solid–liquid behavior unknown to date. Under extension, capture silk behaves as a particularly stretchy solid, owing to its molecular nanosprings, but it totally switches behavior in compression to now become liquid-like: It shrinks with no apparent limit while exerting a constant tension. Here, we unravel the physics underpinning the unique behavior of this ”liquid wire” and demonstrate that its mechanical response originates in the shape-switching of the silk filament induced by buckling within the droplets. Learning from this natural example of geometry and mechanics, we manufactured programmable liquid wires that present previously unidentified pathways for the design of new hybrid solid–liquid materials. PMID:27185930

  11. In-drop capillary spooling of spider capture thread inspires hybrid fibers with mixed solid-liquid mechanical properties

    NASA Astrophysics Data System (ADS)

    Elettro, Hervé; Neukirch, Sébastien; Vollrath, Fritz; Antkowiak, Arnaud

    2016-05-01

    An essential element in the web-trap architecture, the capture silk spun by ecribellate orb spiders consists of glue droplets sitting astride a silk filament. Mechanically this thread presents a mixed solid-liquid behavior unknown to date. Under extension, capture silk behaves as a particularly stretchy solid, owing to its molecular nanosprings, but it totally switches behavior in compression to now become liquid-like: It shrinks with no apparent limit while exerting a constant tension. Here, we unravel the physics underpinning the unique behavior of this ”liquid wire” and demonstrate that its mechanical response originates in the shape-switching of the silk filament induced by buckling within the droplets. Learning from this natural example of geometry and mechanics, we manufactured programmable liquid wires that present previously unidentified pathways for the design of new hybrid solid-liquid materials.

  12. Local heat transfer measurement with liquid crystals on rotating surfaces including non-axisymmetric cases

    NASA Technical Reports Server (NTRS)

    Metzger, D. E.; Kim, Y. K.

    1993-01-01

    An overview and summary of test methods and results are given for the problem of measuring local heat transfer on rotating surfaces that model gas turbine engine disks. Disk cavity situations generically similar to those encountered in the high pressure stage disk cooling are considered, with cooling air supplied both at or near the wheel centerline as well as through single or multiple jets impinging outboard on the wheel near the blade attachment region. In some situations provision has been made for ingestion into the disk-cavity from the gas path region radially outboard of the disk. Local heat transfer rates in all cases are determined from the color display from a thin coating of encapsulated liquid crystals sprayed onto the disk, in conjunction with use of a video camera and computer vision system. For cases with axisymmetric disk surfaces, the coated surfaces are illuminated and viewed continuously, and detailed radial distributions of local Nusselt number are obtained. For non-axisymmetric disk surfaces, such as encountered in the vicinity of bolt heads, the disk is illuminated with stroboscopic light, and a method has been developed and used to synchronize the computer frame grabber with the illumination.

  13. Drop-on-demand sample introduction system coupled with the flowing atmospheric-pressure afterglow for direct molecular analysis of complex liquid microvolume samples.

    PubMed

    Schaper, J Niklas; Pfeuffer, Kevin P; Shelley, Jacob T; Bings, Nicolas H; Hieftje, Gary M

    2012-11-06

    One of the fastest developing fields in analytical spectrochemistry in recent years is ambient desorption/ionization mass spectrometry (ADI-MS). This burgeoning interest has been due to the demonstrated advantages of the method: simple mass spectra, little or no sample preparation, and applicability to samples in the solid, liquid, or gaseous state. One such ADI-MS source, the flowing atmospheric-pressure afterglow (FAPA), is capable of direct analysis of solids just by aiming the source at the solid surface and sampling the produced ions into a mass spectrometer. However, direct introduction of significant volumes of liquid samples into this source has not been possible, as solvent loads can quench the afterglow and, thus, the formation of reagent ions. As a result, the analysis of liquid samples is preferably carried out by analyzing dried residues or by desorbing small amounts of liquid samples directly from the liquid surface. In the former case, reproducibility of sample introduction is crucial if quantitative results are desired. In the present study, introduction of liquid samples as very small droplets helps overcome the issues of sample positioning and reduced levels of solvent intake. A recently developed "drop-on-demand" (DOD) aerosol generator is capable of reproducibly producing very small volumes of liquid (∼17 pL). In this paper, the coupling of FAPA-MS and DOD is reported and applications are suggested. Analytes representing different classes of substances were tested and limits of detections were determined. Matrix tolerance was investigated for drugs of abuse and their metabolites by analyzing raw urine samples and quantification without the use of internal standards. Limits of detection below 2 μg/mL, without sample pretreatment, were obtained.

  14. Stirring-controlled solidified floating solid-liquid drop microextraction as a new solid phase-enhanced liquid-phase microextraction method by exploiting magnetic carbon nanotube-nickel hybrid.

    PubMed

    Ghazaghi, Mehri; Mousavi, Hassan Zavvar; Shirkhanloo, Hamid; Rashidi, Alimorad

    2017-01-25

    A specific technique is introduced to overcome limitations of classical solidification of floating organic drop microextraction, such as tedious and time-consuming centrifuge step and using disperser solvent, by facile and efficient participation of solid and liquid phases. In this proposed method of stirring-controlled solidified floating solid-liquid drop microextraction (SC-SF-SLDME), magnetic carbon nanotube-nickel hybrid (MNi-CNT) as a solid part of the extractors are dispersed ultrasonically in sample solution, and the procedure followed by dispersion of liquid phase (1-undecanol) through high-rate stirring and easily recollection of MNi-CNT in organic solvent droplets through hydrophobic force. With the reduction in speed of stirring, one solid-liquid drop is formed on top of the solution. MNi-CNT acts as both extractor and the coalescence helper between organic droplets for a facile recollection. MNi-CNT was prepared by spray pyrolysis of nickel oleate/toluene mixture at 1000 °C. Four tyrosine kinase inhibitors were selected as model analytes and the effecting parameters were investigated. The results confirmed that magnetic nanoadsorbent has an important role in the procedure and complete collection of dispersed solvent is not achieved in the absence of the solid phase. Also, short extraction time exhibited success of the proposed method and effect of dispersed solid/liquid phases. The limits of quantification (LOQs) for imatinib, sunitinib, erlotinib, and nilotinib were determined to be as low as 0.7, 1.7, 0.6, and 1.0 μg L(-1), respectively. The intra-day precisions (RSDs) were lower than 4.5%. Method performance was investigated by determination of mentioned tyrosine kinase inhibitors (TKIs) in human serum and cerebrospinal fluid samples with good recoveries in the range of 93-98%.

  15. Summary report for ITER Task-T19: MHD pressure drop and heat transfer study for liquid metal systems

    SciTech Connect

    Reed, C.B.; Hua, T.Q.; Natesan, K.; Kirillov, I.R.; Vitkovski, I.V.; Anisimov, A.M.

    1995-03-01

    A key feasibility issue for the ITER Vanadium/Lithium breeding blanket is the question of insulator coatings. Design calculations show that an electrically insulating layer is necessary to maintain an acceptably low MHD pressure drop. To begin experimental investigations of the MHD performance of candidate insulator materials and the technology for putting them in place, a new test section was prepared. Aluminum oxide was chosen as the first candidate insulating material because it may be used in combination with NaK in the ITER vacuum vessel and/or the divertor. Details on the methods used to produce the aluminum oxide layer as well as the microstructures of the coating and the aluminide sublayer are presented and discussed. The overall MHD pressure drop, local MHD pressure gradient, local transverse MHD pressure difference, and surface voltage distributions in both the circumferential and the axial directions are reported and discussed. The positive results obtained here for high-temperature NaK have two beneficial implications for ITER. First, since NaK may be used in the vacuum vessel and/or the divertor, these results support the design approach of using electrically insulating coatings to substantially reduce MHD pressure drop. Secondly, while Al{sub 2}O{sub 3}/SS is not the same coating/base material combination which would be used in the advanced blanket, this work nonetheless shows that it is possible to produce a viable insulating coating which is stable in contact with a high temperature alkali metal coolant.

  16. The motion of bubbles inside drops in containerless processing

    NASA Technical Reports Server (NTRS)

    Shankar, N.; Annamalai, P.; Cole, R.; Subramanian, R. S.

    1982-01-01

    A theoretical model of thermocapillary bubble motion inside a drop, located in a space laboratory, due to an arbitrary axisymmetric temperature distribution on the drop surface was constructed. Typical results for the stream function and temperature fields as well as the migration velocity of the bubble were obtained in the quasistatic limit. The motion of bubbles in a rotating body of liquid was studied experimentally, and an approximate theoretical model was developed. Comparison of the experimental observations of the bubble trajectories and centering times with theoretical predictions lends qualified support to the theory.

  17. Flow pattern, pressure drop and void fraction of two-phase gas-liquid flow in an inclined narrow annular channel

    SciTech Connect

    Wongwises, Somchai; Pipathattakul, Manop

    2006-03-01

    Two-phase flow pattern, pressure drop and void fraction in horizontal and inclined upward air-water two-phase flow in a mini-gap annular channel are experimentally studied. A concentric annular test section at the length of 880mm with an outer diameter of 12.5mm and inner diameter of 8mm is used in the experiments. The flow phenomena, which are plug flow, slug flow, annular flow, annular/slug flow, bubbly/plug flow, bubbly/slug-plug flow, churn flow, dispersed bubbly flow and slug/bubbly flow, are observed and recorded by high-speed camera. A slug flow pattern is found only in the horizontal channel while slug/bubbly flow patterns are observed only in inclined channels. When the inclination angle is increased, the onset of transition from the plug flow region to the slug flow region (for the horizontal channel) and from the plug flow region to slug/bubbly flow region (for inclined channels) shift to a lower value of superficial air velocity. Small shifts are found for the transition line between the dispersed bubbly flow and the bubbly/plug flow, the bubbly/plug flow and the bubbly/slug-plug flow, and the bubbly/plug flow and the plug flow. The rest of the transition lines shift to a higher value of superficial air velocity. Considering the effect of flow pattern on the pressure drop in the horizontal tube at low liquid velocity, the occurrence of slug flow stops the rise of pressure drop for a short while, before rising again after the air velocity has increased. However, the pressure does not rise abruptly in the tubes with {theta}=30{sup o} and 60{sup o} when the slug/bubbly flow occurs. At low gas and liquid velocity, the pressure drop increases, when the inclination angles changes from horizontal to 30{sup o} and 60{sup o}. Void fraction increases with increasing gas velocity and decreases with increasing liquid velocity. After increasing the inclination angle from horizontal to {theta}=30{sup o} and 60{sup o}, the void fraction appears to be similar, with a

  18. [On-line coupling of ionic liquid-based single-drop microextraction and capillary electrophoresis for determination of three bromophenols in water samples].

    PubMed

    Zhang, Wenhui; Jiang, Tingfu; Lu, Zhihua; Wang, Yuanhong

    2013-07-01

    An ionic liquid-based single-drop microextraction (IL-SDME) procedure using IL as an extractant on-line coupled to capillary electrophoresis (CE) is proposed. The method is capable of quantifying trace amounts of bromophenols in water samples. The extraction parameters such as extraction solvent, extraction time, ionic liquid single-drop volume, ionic strength and organic solvent were systematically investigated. For the SDME of the three bromophenols, a [C4MIM] [ PF6,] microdrop was exposed for 8 min to the aqueous sample with 10% (w/w) NaCI and then was directly injected into a capillary column for analysis. Under the optimal conditions, good linear relationships were obtained in the concentration range of 1 - 100 mg/L with the correlation coefficients of 0. 993 9 - 0. 998 8 for the bromophenols. The detection limits of the three bromophenols were 0. 3 mg/L. The RSDs of peak areas of the standards were 5. 21%- 6.47% (n =6). And the enrichment factors for the three bromophenols were 115.8, 327.0 and 569. 8. The proposed method was applied to the determination of the three bromophenols in tap, river and lake waters with the recoveries of the three bromophenols in the range of 87.8% - 96.7%. The method is suitable for the quantification of bromophenols in water samples.

  19. Experimental study of the boiling mechanism of a liquid film flowing on the surface of a rotating disc

    SciTech Connect

    Kolokotsa, D.; Yanniotis, S.

    2010-11-15

    The boiling mechanism of a liquid film formed on the surface of a smooth horizontal rotating disc was studied using de-ionised water at 2 l/min flow rate, boiling under vacuum at 40 C and 5-10 C wall superheat. Visualization experiments were carried out and video films were taken for rotational speeds from 0 to 1000 rpm. It was observed that nucleate flow boiling prevails in the case of 0 rpm (stationary disc). Nucleate boiling was also observed at 100 and 200 rpm with the number of bubbles and the diameter of the bubbles decreasing as the rotational speed was increasing. At 600 and 1000 rpm rotational speeds, vapor bubbles were not observed. The results of visual observation were in agreement with bubble growth analysis which showed that at heat flux values of 40 kW/m{sup 2}, conditions for bubble growth are favorable at low rotational speeds (<200 rpm) but are unfavorable at high rotational speeds (1000 rpm). (author)

  20. Dynamics of solvation and rotational relaxation of Coumarin 153 in ionic liquid confined nanometer-sized microemulsions.

    PubMed

    Chakrabarty, Debdeep; Seth, Debabrata; Chakraborty, Anjan; Sarkar, Nilmoni

    2005-03-31

    The effects of confinement of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate on solvation dynamics and rotational relaxation of Coumarin 153 (C-153) in Triton X-100/cyclohexane microemulsions have been explored using steady-state and picosecond time-resolved emission spectroscopy. The steady-state and rotational relaxation data indicate that C-153 molecules are incorporated in the core of the microemulsions. The average rotational relaxation time increases with increase in w ([bmim][BF(4)]/[TX-100]) values. The solvent relaxation in the core of the microemulsion occurs on two different time scales and is almost insensitive to the increase in w values. The solvent relaxation is retarded in the pool of the microemulsions compared to the neat solvent. Though, the retardation is very small compared to several-fold retardation of the solvation time of the conventional solvent inside the pool of the microemulsions.

  1. Experimental evidence for nonaxisymmetric magnetorotational instability in a rotating liquid metal exposed to an azimuthal magnetic field.

    PubMed

    Seilmayer, Martin; Galindo, Vladimir; Gerbeth, Gunter; Gundrum, Thomas; Stefani, Frank; Gellert, Marcus; Rüdiger, Günther; Schultz, Manfred; Hollerbach, Rainer

    2014-07-11

    The azimuthal version of the magnetorotational instability (MRI) is a nonaxisymmetric instability of a hydrodynamically stable differentially rotating flow under the influence of a purely or predominantly azimuthal magnetic field. It may be of considerable importance for destabilizing accretion disks, and plays a central role in the concept of the MRI dynamo. We report the results of a liquid metal Taylor-Couette experiment that shows the occurrence of an azimuthal MRI in the expected range of Hartmann numbers.

  2. Container-scale hydrodynamic and magnetohydrodynamic modes in liquid metal rotating convection experiments with and without an imposed magnetic field

    NASA Astrophysics Data System (ADS)

    Ribeiro, A.

    2015-12-01

    Thermal convection, constrained by rapid rotation and/or large-scale magnetic fields, is observed almost everywhere in the universe: stars, galaxies, and planetary interiors. However, little is known about the essential behaviors of turbulent convection in liquid metals and even less is known about the essential dynamics of planetary cores and stellar convection zones inuenced by background rotation and imposed magnetic fields. To address this decit, we present novel results of a mixed laboratory-numerical investigation of Rayleigh-Benard convection in a cylindrical cavity subject to rotation and/or an imposed magnetic field, using the liquid metal gallium as the working fluid. A broad variety of cell-sized modes are observed experimentally and captured numerically and these modes can be either? steady, oscillatory, or precessing. This work shows that the convection-driven cell-sized modes that can develop in liquid metals are remarkably different from the canonical flows that develop in the fluids used in present day dynamo models.

  3. Beam coupling in hybrid photorefractive inorganic-cholesteric liquid crystal cells: Impact of optical rotation

    SciTech Connect

    Reshetnyak, V. Yu.; Pinkevych, I. P.; Sluckin, T. J.; Cook, G.; Evans, D. R.

    2014-03-14

    We develop a theoretical model to describe two-beam energy exchange in a hybrid photorefractive inorganic-cholesteric cell. A cholesteric layer is placed between two inorganic substrates. One of the substrates is photorefractive (Ce:SBN). Weak and strong light beams are incident on the hybrid cell. The interfering light beams induce a periodic space-charge field in the photorefractive window. This penetrates into the cholesteric liquid crystal (LC), inducing a diffraction grating written on the LC director. In the theory, the flexoelectric mechanism for electric field-director coupling is more important than the LC static dielectric anisotropy coupling. The LC optics is described in the Bragg regime. Each beam induces two circular polarized waves propagating in the cholesteric cell with different velocities. The model thus includes optical rotation in the cholesteric LC. The incident light beam wavelength can fall above, below, or inside the cholesteric gap. The theory calculates the energy gain of the weak beam, as a result of its interaction with the pump beam within the diffraction grating. Theoretical results for exponential gain coefficients are compared with experimental results for hybrid cells filled with cholesteric mixture BL038/CB15 at different concentrations of chiral agent CB15. Reconciliation between theory and experiment requires the inclusion of a phenomenological multiplier in the magnitude of the director grating. This multiplier is cubic in the space-charge field, and we provide a justification of the q-dependence of the multiplier. Within this paradigm, we are able to fit theory to experimental data for cholesteric mixtures with different spectral position of cholesteric gap relative to the wavelength of incident beams, subject to the use of some fitting parameters.

  4. Orientational dynamics of a ferronematic liquid crystal in a rotating magnetic field

    SciTech Connect

    Boychuk, A. N. Zakhlevnykh, A. N.; Makarov, D. V.

    2015-09-15

    The behavior of the orientational structure of a ferronematic in a rotating uniform magnetic field is investigated using the continual theory. The time-dependent system of equations describing the dynamics of the ferronematic is derived. The dependences of the angles of rotation of the director and of the magnetization of the ferronematic on the velocity of field rotation are determined for various values of the material parameters. Two regimes (synchronous and asynchronous) of rotation of the ferronematic structure are detected. In the synchronous regime, the director rotates with the frequency of the magnetic field and a constant phase delay. The asynchronous regime is characterized by a time-dependent phase delay. The dependence of the critical angular velocity of magnetic field rotation, which determines the boundary between the synchronous and asynchronous regimes, on the magnetic field strength is derived.

  5. Automation of static and dynamic non-dispersive liquid phase microextraction. Part 1: Approaches based on extractant drop-, plug-, film- and microflow-formation.

    PubMed

    Alexovič, Michal; Horstkotte, Burkhard; Solich, Petr; Sabo, Ján

    2016-02-04

    Simplicity, effectiveness, swiftness, and environmental friendliness - these are the typical requirements for the state of the art development of green analytical techniques. Liquid phase microextraction (LPME) stands for a family of elegant sample pretreatment and analyte preconcentration techniques preserving these principles in numerous applications. By using only fractions of solvent and sample compared to classical liquid-liquid extraction, the extraction kinetics, the preconcentration factor, and the cost efficiency can be increased. Moreover, significant improvements can be made by automation, which is still a hot topic in analytical chemistry. This review surveys comprehensively and in two parts the developments of automation of non-dispersive LPME methodologies performed in static and dynamic modes. Their advantages and limitations and the reported analytical performances are discussed and put into perspective with the corresponding manual procedures. The automation strategies, techniques, and their operation advantages as well as their potentials are further described and discussed. In this first part, an introduction to LPME and their static and dynamic operation modes as well as their automation methodologies is given. The LPME techniques are classified according to the different approaches of protection of the extraction solvent using either a tip-like (needle/tube/rod) support (drop-based approaches), a wall support (film-based approaches), or microfluidic devices. In the second part, the LPME techniques based on porous supports for the extraction solvent such as membranes and porous media are overviewed. An outlook on future demands and perspectives in this promising area of analytical chemistry is finally given.

  6. Ionic-liquid-assisted microwave distillation coupled with headspace single-drop microextraction followed by GC-MS for the rapid analysis of essential oil in Dryopteris fragrans.

    PubMed

    Jiao, Jiao; Gai, Qing-Yan; Wang, Wei; Luo, Meng; Zhao, Chun-Jian; Fu, Yu-Jie; Ma, Wei

    2013-12-01

    A rapid, green and effective miniaturized sample preparation technique, ionic-liquid-assisted microwave distillation coupled with headspace single-drop microextraction was developed for the extraction of essential oil from dried Dryopteris fragrans. 1-Ethyl-3-methylimidazolium acetate was the optimal ionic liquid as the destruction agent of plant cell walls and microwave absorption was medium. n-Heptadecane (2.0 μL) was adopted as the suspended microdrop solvent in the headspace for the extraction and concentration of essential oil. The optimal parameters of the proposed method were an irradiation power of 300 W, sample mass of 0.9 g, mass ratio of ionic liquids to sample of 2.8, extraction temperature of 79°C, and extraction time of 3.6 min. In comparison to the previous reports, the proposed technique could equally monitor all the essential oil components with no significant differences in a simple way, which was more rapid and required a much lower amount of sample.

  7. Drop dynamics

    NASA Technical Reports Server (NTRS)

    Elleman, D. D.

    1981-01-01

    The drop dynamics module is a Spacelab-compatible acoustic positioning and control system for conducting drop dynamics experiments in space. It consists basically of a chamber, a drop injector system, an acoustic positioning system, and a data collection system. The principal means of collecting data is by a cinegraphic camera. The drop is positioned in the center of the chamber by forces created by standing acoustic waves generated in the nearly cubical chamber (about 12 cm on a side). The drop can be spun or oscillated up to fission by varying the phse and amplitude of the acoustic waves. The system is designed to perform its experiments unattended, except for start-up and shutdown events and other unique events that require the attention of the Spacelab payload specialist.

  8. Liquid meniscus oscillation and drop ejection by ac voltage, pulsed dc voltage, and superimposing dc to ac voltages

    NASA Astrophysics Data System (ADS)

    Tran, Si Bui Quang; Byun, Doyoung; Nguyen, Vu Dat; Kang, Tae Sam

    2009-08-01

    The electrohydrodynamic (EHD) spraying technique has been utilized in applications such as inkjet printing and mass spectrometry technologies. In this paper, the role of electrical potential signals in jetting and on the oscillation of the meniscus is evaluated. The jetting and the meniscus oscillation behavior are experimentally investigated under ac voltage, ac voltage superimposed on dc voltage, and pulsed dc voltage. Based on this in-depth study of the meniscus behavior under various signals, the optimal signal is implemented to an EHD inkjet head for drop-on-demand operation. For applied ac voltage and ac voltage superimposed on dc voltage, the jetting phenomenon is a dynamic process due to sequential opposite sign signals. The jetting occurs at the end of the oscillation cycle, where the meniscus oscillates upward and arrives at its highest position.

  9. Comparison of short-range-order in liquid- and rotator-phase states of a simple molecular liquid: A reverse Monte Carlo and molecular dynamics analysis of neutron diffraction data

    SciTech Connect

    Pardo, Luis Carlos; Tamarit, Josep Lluis; Veglio, Nestor; Bermejo, Francisco Javier; Cuello, Gabriel Julio

    2007-10-01

    The short-range order (SRO) correlations in liquid- and rotator-phase states of carbon tetrachloride are revisited here. The correlation of some angular magnitudes is used to evaluate the positional and orientational correlations in the liquid as well as in the rotator phase. The results show significant similitudes in the relative position of the molecules surrounding a central one but striking differences in their relative orientations, which could explain the changes in SRO between the two phases and the puzzling behavior of the local density in the liquid and rotator phases.

  10. Determination of the steroid hormone levels in water samples by dispersive liquid-liquid microextraction with solidification of a floating organic drop followed by high-performance liquid chromatography.

    PubMed

    Chang, Chu-Chi; Huang, Shang-Da

    2010-03-03

    In this study, the steroid hormone levels in river and tap water samples were determined by using a novel dispersive liquid-liquid microextraction method based on the solidification of a floating organic drop (DLLME-SFO). Several parameters were optimized, including the type and volume of the extraction and dispersive solvents, extraction time, and salt effect. DLLME-SFO is a fast, cheap, and easy-to-use method for detecting trace levels of samples. Most importantly, this method uses less-toxic solvent. The correlation coefficient of the calibration curve was higher than 0.9991. The linear range was from 5 to 1000 microg L(-1). The spiked environmental water samples were analyzed using DLLME-SFO. The relative recoveries ranged from 87% to 116% for river water (which was spiked with 4 microg L(-1) for E1, 3 microg L(-1) for E2, 4 microg L(-1) for EE2 and 9 microg L(-1) for E3) and 89% to 102% for tap water (which was spiked with 6 microg L(-1) for E1, 5 microg L(-1) for E2, 6 microg L(-1) for EE2 and 10 microg L(-1) for E3). The detection limits of the method ranged from 0.8 to 2.7 microg L(-1) for spiked river water and 1.4 to 3.1 microg L(-1) for spiked tap water. The methods precision ranged from 8% to 14% for spiked river water and 7% to 14% for spiked tap water.

  11. Pool impacts of Leidenfrost drop

    NASA Astrophysics Data System (ADS)

    Darbois Texier, Baptiste; Maquet, Laurent; Dorbolo, Stephane; Dehandschoewercker, Eline; Pan, Zhao; Truscott, Tadd

    2015-11-01

    This work concerns the impact of a droplet made of a volatile liquid (typically HFE) on a pool of an other liquid (typically silicone oil) which temperature is above the boiling point of the drop. Depending on the properties of the two liquids and the impacting conditions, four different regimes are observed. For low impacting speeds, the droplet bounces on the surface of the bath and finally levitates above it in a Leidenfrost state. Such a regime occurs as soon as the pool temperature exceeds the boiling point of the drop. This observation means that there is no threshold in temperature for a Leidenfrost effect on a liquid surface contrary to the case of a solid substrate. For intermediate impacting velocities, the pinch-off of the surface of the pool entraps the drop in the liquid bulk. The entrapped drop is separated from the pool by a layer of its own vapour in a similar way of antibulles. For increasing impacting speeds, the vapour layer between the drop and the pool does not hold during the pinch-off event. The contact of the drop with the hot liquid provokes a sudden and intense evaporation. At very large impacting speeds, the drop rapidely contacts the pool, spreads and finally induces a hemi-spherical cavity. In the end, these four different regimes are summarized in a Froud-Weber diagram which boundaries are discussed.

  12. Drop shaped zinc oxide quantum dots and their self-assembly into dendritic nanostructures: Liquid assisted pulsed laser ablation and characterizations

    NASA Astrophysics Data System (ADS)

    Singh, Subhash C.; Gopal, Ram

    2012-01-01

    Complex nanostructures and nano-assemblies have exhibited their potential application in the fabrication of future molecular machines and molecular devices. Liquid phase pulsed laser ablation is an easy, versatile, environmental friendly and rapidly growing method for the synthesis of nanostructured materials. Nanosecond pulsed laser ablation of zinc rod placed on the bottom of glass vessel containing methanol is used to produce colloidal solution of drop shaped zinc oxide quantum dots and their self-assembly into various dendritic nanostructures. UV-vis absorption, diffuse reflectance, transmission electron microscopy, and photoluminescence spectroscopy techniques are used for the optical, microscopic, structural and defect diagnosis of obtained colloidal quantum dots and their nano-assemblies. The average length, width and aspect ratio of drop shaped zinc oxide quantum dots are 6 ± 2.4 nm, 3.5 ± 1.4 nm and 1.69 ± 0.4 nm, respectively. Careful investigation of assemblies shows that most of them have linear growth, i.e. growth in longitudinal direction is higher as compared to the transverse direction with three types of classifications as (i) linear axis symmetrical branching, (ii) linear axis asymmetrical branching and (iii) curvilinear axis asymmetrical branching. Photoluminescence spectrum has emission peaks in UV, violet, blue and green spectral region corresponding to the excitonic and various defect related emissions.

  13. On-line coupling of ionic liquid-based single-drop microextraction with capillary electrophoresis for sensitive detection of phenols.

    PubMed

    Wang, Qing; Qiu, Hongdeng; Li, Jing; Liu, Xia; Jiang, Shengxiang

    2010-08-13

    An ionic liquid-based single-drop microextraction (IL-SDME) procedure using IL as an extractant on-line coupled to capillary electrophoresis (CE) is proposed. The method is capable of quantifying trace amounts of phenols in environmental water samples. For the SDME of three phenols, a 2.40 nL IL microdrop was exposed for 10 min to the aqueous sample and then was directly injected into the capillary column for analysis. Extraction parameters such as the extraction time, the IL single-drop volume, pH of the sample solution, ionic strength, volume of the sample solution and the extraction temperature were systematically investigated. Detection limits to three phenols were less than 0.05 microg mL(-1), and their calibration curves were all linear (R(2) > or = 0.9994) in the range from 0.05 to 50 microg mL(-1). And enrichment factors for three phenols were 156, 107 and 257 without agitation, respectively. This method was then utilized to analyze two real environmental samples from Yellow River and tap water, obtaining satisfactory results. Compared with the usual SDME for CE, IL-SDME-CE is a simple, low-cost, fast and environmentally friendly preconcentration technique.

  14. Pressure Drop

    NASA Technical Reports Server (NTRS)

    Lawson, Mike

    2010-01-01

    Mike Lawson briefly discussed pressure drop for aerospace applications and presented short stories about adventures experienced while working at NASA and General Dynamics, including exposure to technologies like the Crew and Equipment Translation Aid (CETA) cart and the SWME.

  15. Dynamics of glass-forming liquids. VIII. Dielectric signature of probe rotation and bulk dynamics in branched alkanes.

    PubMed

    Shahriari, Shervin; Mandanici, Andrea; Wang, Li-Min; Richert, Ranko

    2004-11-08

    We have measured the dielectric relaxation of several glass forming branched alkanes with very low dielectric loss in the frequency range 50 Hz-20 kHz. The molecular liquids of this study are 3-methylpentane, 3-methylheptane, 4-methylheptane, 2,3-dimethylpentane, and 2,4,6-trimethylheptane. All liquids display asymmetric loss peaks typical of supercooled liquids and slow beta relaxations of similar amplitudes. As an unusual feature, deliberate doping with 2-ethyl-1-hexanol, 5-methyl-2-hexanol, 2-methyl-1-butanol, 1-propanol, or 2-methyltetrahydrofuran at the 1 wt % level generates additional relaxation peaks at frequencies below those of the alpha relaxation. The relaxation times of these sub-alpha-peaks increase systematically with the size of the dopant molecules. Because these features are spectrally separate from the bulk dynamics, the rotational behavior and effective dipole moments of the probes can be studied in detail. For the alcohol guest molecules, the large relative rotational time scales and small effective dipole moments are indicative of hydrogen bonded clusters instead of individual molecules.

  16. Gas Pressure-Drop Experiment

    ERIC Educational Resources Information Center

    Luyben, William L.; Tuzla, Kemal

    2010-01-01

    Most chemical engineering undergraduate laboratories have fluid mechanics experiments in which pressure drops through pipes are measured over a range of Reynolds numbers. The standard fluid is liquid water, which is essentially incompressible. Since density is constant, pressure drop does not depend on the pressure in the pipe. In addition, flow…

  17. Rapid analysis of Fructus forsythiae essential oil by ionic liquids-assisted microwave distillation coupled with headspace single-drop microextraction followed by gas chromatography-mass spectrometry.

    PubMed

    Jiao, Jiao; Ma, Dan-Hui; Gai, Qing-Yan; Wang, Wei; Luo, Meng; Fu, Yu-Jie; Ma, Wei

    2013-12-04

    A rapid, green and effective miniaturized sample preparation and analytical technique, i.e. ionic liquids-assisted microwave distillation coupled with headspace single-drop microextraction (ILAMD-HS-SDME) followed by gas chromatography-mass spectrometry (GC-MS) was developed for the analysis of essential oil (EO) in Fructus forsythiae. In this work, ionic liquids (ILs) were not only used as the absorption medium of microwave irradiation but also as the destruction agent of plant cell walls. 1-Ethyl-3-methylimidazolium acetate ([C2mim]OAc) was chosen as the optimal ILs. Moreover, n-heptadecane (2.0 μL) was selected as the appropriate suspended solvent for the extraction and concentration of EO. Extraction conditions of the proposed method were optimized using the relative peak area of EO constituents as the index, and the optimal operational parameters were obtained as follows: irradiation power (300 W), sample mass (0.7 g), mass ratio of ILs to sample (2.4), temperature (78°C) and time (3.4 min). In comparison to previous reports, the proposed method was faster and required smaller sample amount but could equally monitor all EO constituents with no significant differences.

  18. CONDENSED MATTER: STRUCTURE, THERMAL AND MECHANICAL PROPERTIES: Rotational viscosity of a liquid crystal mixture: a fully atomistic molecular dynamics study

    NASA Astrophysics Data System (ADS)

    Zhang, Ran; Peng, Zeng-Hui; Liu, Yong-Gang; Zheng, Zhi-Gang; Xuan, Li

    2009-10-01

    Fully atomistic molecular dynamics (MD) simulations at 293, 303 and 313 K have been performed for the four-component liquid crystal mixture, E7, using the software package Material Studio. Order parameters and orientational time correlation functions (TCFs) were calculated from MD trajectories. The rotational viscosity coefficients (RVCs) of the mixture were calculated using the Nemtsov-Zakharov and Fialkowski methods based on statistical-mechanical approaches. Temperature dependences of RVC and density were discussed in detail. Reasonable agreement between the simulated and experimental values was found.

  19. Investigations of levitated helium drops

    NASA Astrophysics Data System (ADS)

    Whitaker, Dwight Lawrence

    1999-11-01

    We report on the development of two systems capable of levitating drops of liquid helium. Helium drops of ˜20 mum have been levitated with the radiation pressure from two counter-propagating Nd:YAG laser beams. Drops are produced with a submerged piezoelectric transducer, and could be held for up to three minutes in our optical trap. Calculations show that Brillouin and Raman scattering of the laser light in the liquid helium produces a negligible rate of evaporation of the drop. Evaporation caused by the enhanced vapor pressure of the curved drop surfaces appears to be a significant effect limiting the drop lifetimes. Helium drops as large as 2 cm in diameter have been suspended in the earth's gravitational field with a magnetic field. A commercial superconducting solenoid provides the necessary field, field-gradient product required to levitate the drops. Drops are cooled to 0.5 K with a helium-3 refrigerator, and can be held in the trap indefinitely. We have found that when two or more drops are levitated in the same magnetic trap, the drops often remain in a state of apparent contact without coalescing. This effect is a result of the evaporation of liquid from between the two drops, and is found to occur only for normal fluid drops. We can induce shape oscillations in charged, levitated drops with an applied ac electric field. We have measured the resonance frequencies and damping rates for the l = 2 mode of oscillation as function of temperature. We have also developed a theory to describe the small amplitude shape oscillations of a He II drop surrounded by its saturated vapor. In our theory, we have considered two sets of boundary conditions---one where the drop does not evaporate and another in which the liquid and vapor are in thermodynamic equilibrium. We have found that both solutions give a frequency that agrees well with experiment, but that the data for the damping rate agree better with the solution without evaporation.

  20. Magnetic nanoparticles stimulation to enhance liquid-liquid two-phase mass transfer under static and rotating magnetic fields

    NASA Astrophysics Data System (ADS)

    Azimi, Neda; Rahimi, Masoud

    2017-01-01

    Rotating magnetic field (RMF) was applied on a micromixer to break the laminar flow and induce chaotic flow to enhance mass transfer between two-immiscible organic and aqueous phases. The results of RMF were compared to those of static magnetic field (SMF). For this purpose, experiments were carried out in a T-micromixer at equal volumetric flow rates of organic and aqueous phases. Fe3O4 nanoparticles were synthesized by co-precipitation technique and they were dissolved in organic phase. Results obtained from RMF and SMF were compared in terms of overall volumetric mass transfer coefficient (KLa) and extraction efficiency (E) at various Reynolds numbers. Generally, RMF showed higher effect in mass transfer characteristics enhancement compared with SMF. The influence of rotational speeds of magnets (ω) in RMF was investigated, and measurable enhancements of KLa and E were observed. In RMF, the effect of magnetic field induction (B) was investigated. The results reveal that at constant concentration of nanoparticles, by increasing of B, mass transfer characteristics will be enhanced. The effect of various nanoparticles concentrations (ϕ) within 0.002-0.01 (w/v) on KLa and E at maximum induction of RMF (B=76 mT) was evaluated. Maximum values of KLa (2.1±0.001) and E (0.884±0.001) were achieved for the layout of RMF (B=76 mT), ω=16 rad/s and MNPs concentration of 0.008-0.01 (w/v).

  1. Fuel Cells Using the Protic Ionic Liquid and Rotator Phase Solid Electrolyte Principles

    DTIC Science & Technology

    2008-02-13

    was obtained from Alfa Aesar. Anhydrous difluorophosphoric acid was obtained from SynQuest Labs Inc. Anhydrous formic acid (HFm, 98%) was obtained from...monoprotonated salt of hydrazine and formic acid . Viscosities. The viscosities measured on these liquids, shown in Figure 6 for the same representative series as...concept of ionic liquids, formed by proton transfer from Bronsted acid to Bronsted base, serving as the proton transport media in fuel cells is evaluated

  2. Cooling the two-dimensional short spherocylinder liquid to the tetratic phase: Heterogeneous dynamics with one-way coupling between rotational and translational hopping.

    PubMed

    Su, Yen-Shuo; I, Lin

    2015-07-01

    We numerically demonstrate the transition from the isotropic liquid to the tetratic phase with quasilong-range tetratic alignment order (i.e., with nearly parallel or perpendicular aligned rods), for the cold two-dimensional (2D) short spherocylinder system before crystallization and investigate the thermal assisted heterogeneous rotational and translational micromotions. Comparing with the 2D liquid of isotropic particles, spherocylinders introduce extra rotational degrees of freedom and destroy packing isotropy and the equivalence between rotational and translational motions. It is found that cooling leads to the stronger dynamical heterogeneity with more cooperative hopping and the stronger retardations of rotational hopping than translational hopping. Under topological constraints from nearly parallel and perpendicular rods of the tetratic phase, longitudinal and transverse translational hopping can occur without rotational hopping, but not the reverse. The empty space trailing a neighboring translational hopping patch is needed for triggering the patch rotational hopping with its translational motion into the empty space. It is the origin for the observed increasing separation of hopping time scales and the one-way coupling between rotational and translational hopping. Strips of longitudinally or transversely aligned rods can be ruptured and reconnected with neighboring strips through buckling, kink formation, and patch rotation, under the unbalanced torques or forces from their neighboring rods and thermal kicks.

  3. Solidification of floating organic drop liquid-phase microextraction cell fishing with gas chromatography-mass spectrometry for screening bioactive components from Amomum villosum Lour.

    PubMed

    Xue, Xue; Yang, Depo; Wang, Dongmei; Xu, Xinjun; Zhu, Longping; Zhao, Zhimin

    2015-04-01

    In this study, a novel solidification of floating organic drop liquid-phase microextraction cell fishing with gas chromatography-mass spectrometry (SFOD-LPME-CF-GC-MS) method was established and used to screen, isolate and analyze bioactive components from Amomum villosum Lour. extract. Through comparision of its effect on the models of normal cell and inflammatory cells, anti-inflammatory active components of essential oil from A. villosum Lour. were readily screened, and the components obtained are in agreement with related pharmacological articles. SFOD-LPME-CF-GC-MS was used to analyze the interaction of A. villosum Lour. extracts with normal and lipopolysaccharide-stimulated RAW264.7 macrophage cells. The effect of A. villosum Lour. essential oil extracts in the LPS-stimulated RAW264.7 model were also assessed in terms of cytotoxicity and nitric oxide production as an indication of bioactivity. Three potentially bioactive components were identified, demonstrating that SFOD-LPME-CF-GC-MS can be used successfully in the drug-screening process. This approach avoids the requirement for protein precipitation, but more importantly, generates a high concentration ratio, allowing analysis of trace components in traditional Chinese medicines. SFOD-LPME-CF-GC-MS is a simple, fast, effective and reliable method for the screening and analysis of bioactive components, and it can be extended to screen other bioactive components from TCMs.

  4. From basic physics to mechanisms of toxicity: the "liquid drop" approach applied to develop predictive classification models for toxicity of metal oxide nanoparticles.

    PubMed

    Sizochenko, Natalia; Rasulev, Bakhtiyor; Gajewicz, Agnieszka; Kuz'min, Victor; Puzyn, Tomasz; Leszczynski, Jerzy

    2014-11-21

    Many metal oxide nanoparticles are able to cause persistent stress to live organisms, including humans, when discharged to the environment. To understand the mechanism of metal oxide nanoparticles' toxicity and reduce the number of experiments, the development of predictive toxicity models is important. In this study, performed on a series of nanoparticles, the comparative quantitative-structure activity relationship (nano-QSAR) analyses of their toxicity towards E. coli and HaCaT cells were established. A new approach for representation of nanoparticles' structure is presented. For description of the supramolecular structure of nanoparticles the "liquid drop" model was applied. It is expected that a novel, proposed approach could be of general use for predictions related to nanomaterials. In addition, in our study fragmental simplex descriptors and several ligand-metal binding characteristics were calculated. The developed nano-QSAR models were validated and reliably predict the toxicity of all studied metal oxide nanoparticles. Based on the comparative analysis of contributed properties in both models the LDM-based descriptors were revealed to have an almost similar level of contribution to toxicity in both cases, while other parameters (van der Waals interactions, electronegativity and metal-ligand binding characteristics) have unequal contribution levels. In addition, the models developed here suggest different mechanisms of nanotoxicity for these two types of cells.

  5. Vortex-assisted surfactant-enhanced emulsification microextraction based on solidification of floating organic drop combined with high performance liquid chromatography for determination of naproxen and nabumetone.

    PubMed

    Asadi, Mohammad; Haji Shabani, Ali Mohammad; Dadfarnia, Shayessteh; Abbasi, Bijan

    2015-12-18

    A novel, rapid, simple and green vortex-assisted surfactant-enhanced emulsification microextraction method based on solidification of floating organic drop was developed for simultaneous separation/preconcentration and determination of ultra trace amounts of naproxen and nabumetone with high performance liquid chromatography-fluorescence detection. Some parameters influencing the extraction efficiency of analytes such as type and volume of extractant, type and concentration of surfactant, sample pH, KCl concentration, sample volume, and vortex time were investigated and optimized. Under optimal conditions, the calibration graph exhibited linearity in the range of 3.0-300.0ngL(-1) for naproxen and 7.0-300.0ngL(-1) for nabumetone with a good coefficient of determination (R(2)>0.999). The limits of detection were 0.9 and 2.1ngL(-1). The relative standard deviations for inter- and intra-day assays were in the range of 5.8-10.1% and 3.8-6.1%, respectively. The method was applied to the determination of naproxen and nabumetone in urine, water, wastewater and milk samples and the accuracy was evaluated through recovery experiments.

  6. Simultaneous extraction and quantification of lamotrigine, phenobarbital, and phenytoin in human plasma and urine samples using solidified floating organic drop microextraction and high-performance liquid chromatography.

    PubMed

    Asadi, Mohammad; Dadfarnia, Shayessteh; Haji Shabani, Ali Mohammad; Abbasi, Bijan

    2015-07-01

    A novel and simple method based on solidified floating organic drop microextraction followed by high-performance liquid chromatography with ultraviolet detection has been developed for simultaneous preconcentration and determination of phenobarbital, lamotrigine, and phenytoin in human plasma and urine samples. Factors affecting microextraction efficiency such as the type and volume of the extraction solvent, sample pH, extraction time, stirring rate, extraction temperature, ionic strength, and sample volume were optimized. Under the optimum conditions (i.e. extraction solvent, 1-undecanol (40 μL); sample pH, 8.0; temperature, 25°C; stirring rate, 500 rpm; sample volume, 7 mL; potassium chloride concentration, 5% and extraction time, 50 min), the limits of detection for phenobarbital, lamotrigine, and phenytoin were 1.0, 0.1, and 0.3 μg/L, respectively. Also, the calibration curves for phenobarbital, lamotrigine, and phenytoin were linear in the concentration range of 2.0-300.0, 0.3-200.0, and 1.0-200.0 μg/L, respectively. The relative standard deviations for six replicate extractions and determinations of phenobarbital, lamotrigine, and phenytoin at 50 μg/L level were less than 4.6%. The method was successfully applied to determine phenobarbital, lamotrigine, and phenytoin in plasma and urine samples.

  7. Negative vortices: The formation of vortex rings with reversed rotation in viscoelastic liquids

    NASA Astrophysics Data System (ADS)

    Palacios-Morales, Carlos; Barbosa, Christophe; Solorio, Francisco; Zenit, Roberto

    2015-05-01

    The formation process of vortex rings in a viscoelastic liquid is studied experimentally considering a piston-cylinder arrangement. Initially, a vortex ring begins to form as fluid is injected from the cylinder into the tank in a manner similar to that observed for Newtonian liquids. For later times, when the piston ceases its motion, the flow changes dramatically. A secondary vortex with reversed spinning direction appears and grows to be as large in size as the original one. The formation process is studied by contrasting the evolution with that obtained for Newtonian liquids with equivalent Reynolds numbers and stroke ratios. We argue that the reversing flow, or negative vortex, results from the combined action of shear and extension rates produced during the vortex formation, in a process similar to that observed behind ascending bubbles and falling spheres in viscoelastic media.

  8. Change of translational-rotational coupling in liquids revealed by field-cycling 1H NMR

    NASA Astrophysics Data System (ADS)

    Meier, R.; Schneider, E.; Rössler, E. A.

    2015-01-01

    Applying the field-cycling nuclear magnetic resonance technique, the frequency dependence of the 1H spin-lattice relaxation rate, R 1 ω = T1 - 1 ω , is measured for propylene glycol (PG) which is increasingly diluted with deuterated chloroform. A frequency range of 10 kHz-20 MHz and a broad temperature interval from 220 to about 100 K are covered. The results are compared to those of experiments, where glycerol and o-terphenyl are diluted with their deuterated counter-part. Reflecting intra- as well as intermolecular relaxation, the dispersion curves R 1 ω , x (x denotes mole fraction PG) allow to extract the rotational time constant τrot(T, x) and the self-diffusion coefficient D(T, x) in a single experiment. The Stokes-Einstein-Debye (SED) relation is tested in terms of the quantity D(T, x) τrot(T, x) which provides a measure of an effective hydrodynamic radius or equivalently of the spectral separation of the translational and the rotational relaxation contribution. In contrast to o-terphenyl, glycerol and PG show a spectral separation much larger than suggested by the SED relation. In the case of PG/chloroform mixtures, not only an acceleration of the PG dynamics is observed with increasing dilution but also the spectral separation of rotational and translational relaxation contributions continuously decreases. Finally, following a behavior similar to that of o-terphenyl already at about x = 0.6; i.e., while D(T, x) τrot(T, x) in the mixture is essentially temperature independent, it strongly increases with x signaling thus a change of translational-rotational coupling. This directly reflects the dissolution of the hydrogen-bond network and thus a change of solution structure.

  9. Cooperative-motion-induced structural evolution in dusty-plasma liquids with microheterogeneity: rupture, rotation, healing, and growth of ordered domains.

    PubMed

    Yang, Chi; Io, Chong-Wai; I, Lin

    2012-11-30

    The cooperative motion induced structural evolution of the liquid with microheterogeneity is investigated in quasi-2D dusty plasma liquids, through direct optical visualization. A novel bond-dynamics analysis is used to further classify the robust cooperative 2D clusters into static, rotating, and drifting patches, beyond the earlier findings of the cooperative hopping strings and bands. The relative motion between two adjacent clusters causes the formation of a fractal network with narrow shear strips along the cluster interface. The rotation of the large ordered patch through rupturing into multiple rotating patches followed by the healing process, and the growth to a larger ordered patch by aligning the different lattice orientations of the adjacent ordered domains through patch rupturing, rotation, drifting, and merging are the key processes for the microstructural evolution.

  10. Artificial tektites: an experimental technique for capturing the shapes of spinning drops

    NASA Astrophysics Data System (ADS)

    Baldwin, K. A.

    2014-12-01

    Tektites are small stones formed from rapidly cooling drops of molten rock ejected from high velocity asteroid impacts with the Earth, that freeze into a myriad of shapes during flight. Many splash-form tektites have an elongated or dumb-bell shape owing to their rotation prior to solidification[1]. Here we present a novel method for creating 'artificial tektites' from spinning drops of molten wax, using diamagnetic levitation to suspend the drops[2]. We find that the solid wax models produced this way are the stable equilibrium shapes of a spinning liquid droplet held together by surface tension. In addition to the geophysical interest in tektite formation, the stable equilibrium shapes of liquid drops have implications for many physical phenomena, covering a wide range of length scales, from nuclear physics (e.g. in studies of rapidly rotating atomic nuclei), to astrophysics (e.g. in studies of the shapes of astronomical bodies such as asteroids, rapidly rotating stars and event horizons of rotating black holes). For liquid drops bound by surface tension, analytical and numerical methods predict a series of stable equilibrium shapes with increasing angular momentum. Slowly spinning drops have an oblate-like shape. With increasing angular momentum these shapes become secularly unstable to a series of triaxial pseudo-ellipsoids that then evolve into a family of two-lobed 'dumb-bell' shapes as the angular momentum is increased still further. Our experimental method allows accurate measurements of the drops to be taken, which are useful to validate numerical models. This method has provided a means for observing tektite formation, and has additionally confirmed experimentally the stable equilibrium shapes of liquid drops, distinct from the equivalent shapes of rotating astronomical bodies. Potentially, this technique could be applied to observe the non-equilibrium dynamic processes that are also important in real tektite formation, involving, e.g. viscoelastic

  11. Translation-rotation decoupling and nonexponentiality in room temperature ionic liquids

    SciTech Connect

    Griffin, Phillip; Agapov, Alexander L; Sokolov, Alexei P

    2012-01-01

    Using a combination of light scattering techniques and broadband dielectric spectroscopy, we have measured the temperature dependence of structural relaxation time and self diffusion in three imidazolium-based room temperature ionic liquids: [bmim][NTf2], [bmim][PF6], and [bmim][TFA]. A detailed analysis of the results demonstrates that self diffusion decouples from structural relaxation in these systems as the temperature is decreased toward Tg. The degree to which the dynamics are decoupled, however, is shown to be surprisingly weak when compared to other supercooled liquids of similar fragility. In addition to the weak decoupling, we demonstrate that the temperature dependence of the structural relaxation time in all three liquids can be well described by a single Vogel-Fulcher-Tamann function over 13 decades in time from 10 11 s up to 102 s. Furthermore, the stretching of the structural relaxation is shown to be temperature independent over the same range of time scales, i.e., time temperature superposition is valid for these ionic liquids from far above the melting point down to the glass transition temperature.We suggest that these phenomena are interconnected and all result from the same underlying mechanism strong and directional intermolecular interactions.

  12. Faraday rotation dispersion measurements of diamagnetic organic liquids and simultaneous determination of natural optical rotatory dispersion using a pulsed magnetic field.

    PubMed

    Suwa, Masayori; Miyamoto, Kayoko; Watarai, Hitoshi

    2013-01-01

    We constructed an apparatus to measure the wavelength dispersion of the Faraday rotation in the visible region, and determined the Verdet constants of diamagnetic organic liquids, including aliphatic compounds, benzene derivatives, and naphthalene derivatives. These three groups were easily distinguished by the magnitudes of their Verdet constants. Based on the theory developed by Serber, we determined the enhancing effect of π*←π transitions on the visible-light Faraday rotation angles observed for aromatic compounds. Furthermore, we propose a novel approach for simultaneously observing Faraday rotation dispersion and natural optical rotatory dispersion.

  13. 49 CFR 178.810 - Drop test.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... design types and performed periodically as specified in § 178.801(e) of this subpart. (b) Special...). (2) Drop tests are to be performed with the solid or liquid to be transported or with a non-hazardous... substituted non-hazardous material used in the drop test for liquids must be similar to the hazardous...

  14. Exponential Decay of the Vorticity in the Steady-State Flow of a Viscous Liquid Past a Rotating Body

    NASA Astrophysics Data System (ADS)

    Deuring, Paul; Galdi, Giovanni P.

    2016-07-01

    Consider the flow of a Navier-Stokes liquid past a body rotating with a prescribed constant angular velocity, {ω}, and assume that the motion is steady with respect to a body-fixed frame. In this paper we show that the vorticity field associated to every "weak" solution corresponding to data of arbitrary "size" ( Leray Solution) must decay exponentially fast outside the wake region at sufficiently large distances from the body. Our result improves and generalizes in a non-trivial way famous results by Clark (Indiana Univ Math J 20:633-654, 1971) and Babenko and Vasil'ev (J Appl Math Mech 37:651-665, 1973) obtained in the case {ω=0}.

  15. Solvent and rotational relaxation study in ionic liquid containing reverse micellar system: A picosecond fluorescence spectroscopy study

    NASA Astrophysics Data System (ADS)

    Pramanik, Rajib; Sarkar, Souravi; Ghatak, Chiranjib; Rao, Vishal Govind; Sarkar, Nilmoni

    2011-08-01

    Room-temperature ionic liquid (RTIL), N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([P13][Tf2N]) have been used as polar solvent to form nonaqueous reverse micelle (RMs) with benzene by the aid of cationic surfactant BHDC. Dynamic light scattering (DLS) revealed the formation of the RTIL reverse micelle. Pulsed-field gradient spin echo NMR have been studied to measure the diffusion coefficients of neat [P13][Tf2N] and [P13][Tf2N] in reverse micelle which indicate RTIL containing reverse micelle is formed. Moreover, studies on solvent and rotational relaxation have been investigated in [P13][Tf2N]/BHDC/benzene RMs using steady-state and time-resolved fluorescence spectroscopy using coumarin 480 (C-480) fluorescence probe with variation of RTIL contents RMs.

  16. A novel dispersive liquid-liquid microextraction method based on solidification of floating organic drop for preconcentration of Pd(II) by graphite furnace atomic absorption spectrometry after complexation by a thienyl substituted 1,2-ethanediamine.

    PubMed

    Ragheb, Elham; Hashemi, Payman; Alizadeh, Kamal; Ganjali, Mohammad Reza

    2015-01-01

    A novel dispersive liquid-liquid microextraction method based on solidification of floating organic drop (DLLME-SFO) was developed for the preconcentration of ultratrace amounts of palladium (Pd)(II) before its determination by electrothermal atomic absorption spectrometry. Diphenyl ether (m.p. 26°C) was used for the first time as a heavier than water organic solvent in the developed method. Pd was complexed by N,N'-bis(thiophen-2-ylmethylene)ethane-1,2-diamine to be extracted into the dispersed diphenyl ether phase using acetonitril as the disperser solvent. Upon cooling and centrifugation, the organic solvent was sedimented at the bottomn and the aqueous phase was easily decantated. Some factors influencing the extraction efficiency of Pd(II) and its subsequent determination, including extraction and dispersive solvent type and volume, pH of sample solution, concentration of the chelating agent and salting out effect, were studied and optimized both with univariate and multivariate methods. Under the optimized conditions, the calibration graph exhibited linearity over a range of 10 - 120 μg L(-1). The enrichment factor was 83.3, the detection limit for Pd (3σ) was 47 ng L(-1) and the relative standard deviation was 3.2% (n = 10, 1 ng mL(-1)). The method was successfully applied to the determination of trace amounts of Pd(II) in water samples.

  17. Dispersive liquid-liquid microextraction based on solidification of floating organic drop combined with field-amplified sample injection in capillary electrophoresis for the determination of beta(2)-agonists in bovine urine.

    PubMed

    Us, Murat Faruk; Alshana, Usama; Lubbad, Ibrahim; Göğer, Nilgün G; Ertaş, Nusret

    2013-03-01

    Dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO) was for the first time combined with field-amplified sample injection (FASI) in CE to determine four β(2)-agonists (cimbuterol, clenbuterol, mabuterol, and mapenterol) in bovine urine. Optimum BGE consisted of 20 mM borate buffer and 0.1 mM SDS. Using salting-out extraction, β(2)-agonists were extracted into ACN that was then used as the disperser solvent in DLLME-SFO. Optimum DLLME-SFO conditions were: 1.0 mL ACN, 50 μL 1-undecanol (extraction solvent), total extraction time 1.5 min, no salt addition. Back extraction into an aqueous solution (pH 2.0) facilitated direct injection of β(2)-agonists into CE. Compared to conventional CZE, DLLME-SFO-FASI-CE achieved sensitivity enhancement factors of 41-1046 resulting in LODs in the range of 1.80-37.0 μg L(-1). Linear dynamic ranges of 0.15-10.0 mg L(-1) for cimbuterol and 15-1000 μg L(-1) for the other analytes were obtained with coefficients of determination (R(2)) ≥ 0.9901 and RSD% ≤5.5 (n = 5). Finally, the applicability of the proposed method was successfully confirmed by determination of the four β(2)-agonists in spiked bovine urine samples and accuracy higher than 96.0% was obtained.

  18. How to freeze drop oscillations with powders

    NASA Astrophysics Data System (ADS)

    Marston, Jeremy; Zhu, Ying; Vakarelski, Ivan; Thoroddsen, Sigurdur

    2012-11-01

    We present experiments that show when a water drop impacts onto a bed of fine, hydrophobic powder, the final form of the drop can be very different from the spherical form with which it impacts. For all drop impact speeds, the drop rebounds due to the hydrophobic nature of the powder. However, we observe that above a critical impact speed, the drop undergoes a permanent deformation to a highly non-spherical shape with a complete coverage of powder, thus creating a deformed liquid marble. This powder coating acts to freeze the drop oscillations during rebound.

  19. An octahedron model for oscillating, bouncing drops

    NASA Astrophysics Data System (ADS)

    Blanchette, Francois

    2016-11-01

    We present a model for oscillating and bouncing liquid drops. The model uses 6 point masses distributed as the vertices of an octahedron, connected by linear springs. We derive the physically relevant choice of parameters and use this model to study drops bouncing on solid surfaces, as well as drops bouncing on a nearly inviscid liquid surfaces. The surfaces may be stationary of subject to forced oscillations.

  20. Flue gas desulfurization by rotating beds

    SciTech Connect

    Gardner, N.; Keyvani, M.; Coskundeniz, A.

    1992-01-01

    The operating and mass transfer characteristics of rotating foam metal beds were studied to determine the potential for flue gas desulfurization. This is a final technical report on the work supported by DOE [number sign]FG22-87-PC79924. The report is divided into two sections, Part 1 deals primarily with the operating characteristics of rotating beds, and Part 2 covers the mass transfer characteristics of S0[sub 2] absorption in water-lime slurries. Rotating foam metal beds are in essence packed towers operated in high gravitational fields. The foam metal bed is in the form of a cylindrical donut, or torus, and is rotated to produced the high centrifugal forces. The liquid phase enters the bed at the inner surface of the torus and is pulled by the field through the bed. Gas flows countercurrent to the liquid. The bed packing can have a very large specific surface areas and not flood. Possible benefits include much smaller height of a transfer unit resulting in smaller equipment and supporting structures, reduced solvent inventory, faster response with improved process control, reduced pressure drop, and shorter startup and shut-down times. This work is concerned broadly with the operating characteristics of rotating beds, the objectives being to (1) determine the pressure drop through the rotating bed; (2) determine the power required to operate the beds, (3) investigate the residence time distribution of the liquid phase in the beds; and (4) determine the mass transfer coefficients of S0[sub 2] absorption. Three packings of differing specific surface areas were studied, with areas ranging from 656 to 2952 m[sub 2]/m[sub 3]. Liquid flow rates to 36 kg/s*m[sub 2], gas flow rate to 2.2 kg/s*m[sub 2], and gravitational fields to 300 g were covered in this study.

  1. From basic physics to mechanisms of toxicity: the ``liquid drop'' approach applied to develop predictive classification models for toxicity of metal oxide nanoparticles

    NASA Astrophysics Data System (ADS)

    Sizochenko, Natalia; Rasulev, Bakhtiyor; Gajewicz, Agnieszka; Kuz'min, Victor; Puzyn, Tomasz; Leszczynski, Jerzy

    2014-10-01

    Many metal oxide nanoparticles are able to cause persistent stress to live organisms, including humans, when discharged to the environment. To understand the mechanism of metal oxide nanoparticles' toxicity and reduce the number of experiments, the development of predictive toxicity models is important. In this study, performed on a series of nanoparticles, the comparative quantitative-structure activity relationship (nano-QSAR) analyses of their toxicity towards E. coli and HaCaT cells were established. A new approach for representation of nanoparticles' structure is presented. For description of the supramolecular structure of nanoparticles the ``liquid drop'' model was applied. It is expected that a novel, proposed approach could be of general use for predictions related to nanomaterials. In addition, in our study fragmental simplex descriptors and several ligand-metal binding characteristics were calculated. The developed nano-QSAR models were validated and reliably predict the toxicity of all studied metal oxide nanoparticles. Based on the comparative analysis of contributed properties in both models the LDM-based descriptors were revealed to have an almost similar level of contribution to toxicity in both cases, while other parameters (van der Waals interactions, electronegativity and metal-ligand binding characteristics) have unequal contribution levels. In addition, the models developed here suggest different mechanisms of nanotoxicity for these two types of cells.Many metal oxide nanoparticles are able to cause persistent stress to live organisms, including humans, when discharged to the environment. To understand the mechanism of metal oxide nanoparticles' toxicity and reduce the number of experiments, the development of predictive toxicity models is important. In this study, performed on a series of nanoparticles, the comparative quantitative-structure activity relationship (nano-QSAR) analyses of their toxicity towards E. coli and HaCaT cells were

  2. Electrohydrodynamics of a particle-covered drop

    NASA Astrophysics Data System (ADS)

    Ouriemi, Malika; Vlahovska, Petia

    2014-11-01

    We study the dynamics of a drop nearly-completely covered with a particle monolayer in a uniform DC electric field. The weakly conducting fluid system consists of a silicon oil drop suspended in castor oil. A broad range of particle sizes, conductivities, and shapes is explored. In weak electric fields, the presence of particles increases drop deformation compared to a particle-free drop and suppresses the electrohydrodynamic flow. Very good agreement is observed between the measured drop deformation and the small deformation theory derived for surfactant-laden drops (Nganguia et al., 2013). In stronger electric fields, where drops are expected to undergo Quincke rotation (Salipante and Vlahovska, 2010), the presence of the particles greatly decreases the threshold for rotation and the stationary tilted drop configuration observed for clean drop is replaced by a spinning drop with either a wobbling inclination or a very low inclination. These behaviors resemble the predicted response of rigid ellipsoids in uniform electric fields. At even stronger electric fields, the particles can form dynamic wings or the drop implodes. The similar behavior of particle-covered and surfactant-laden drops provides new insights into understanding stability of Pickering emulsions. Supported by NSF-CBET 1437545.

  3. Analytical and numerical modelling of Newtonian and non-Newtonian liquid in a rotational cross-flow MBR.

    PubMed

    Bentzen, T R; Ratkovich, N; Madsen, S; Jensen, J C; Bak, S N; Rasmussen, M R

    2012-01-01

    Fouling is the main bottleneck of the widespread use of MBR systems. One way to decrease and/or control fouling is by process hydrodynamics. This can be achieved by the increase of liquid cross-flow velocity. In rotational cross-flow MBR systems, this is attained by the spinning of, for example, impellers. Validation of the CFD (computational fluid dynamics) model was made against laser Doppler anemometry (LDA) tangential velocity measurements (error less than 8%) using water as a fluid. The shear stress over the membrane surface was inferred from the CFD simulations for water. However, activated sludge (AS) is a non-Newtonian liquid, for which the CFD model was modified incorporating the non-Newtonian behaviour of AS. Shear stress and area-weighted average shear stress relationships were made giving error less that 8% compared with the CFD results. An empirical relationship for the area-weighted average shear stress was developed for water and AS as a function of the angular velocity and the total suspended solids concentration. These relationships can be linked to the energy consumption of this type of systems.

  4. Forced Oscillations of Supported Drops

    NASA Technical Reports Server (NTRS)

    Wilkes, Edward D.; Basaran, Osman A.

    1996-01-01

    Oscillations of supported liquid drops are the subject of wide scientific interest, with applications in areas as diverse as liquid-liquid extraction, synthesis of ceramic powders, growing of pure crystals in low gravity, and measurement of dynamic surface tension. In this research, axisymmetric forced oscillations of arbitrary amplitude of viscous liquid drops of fixed volume which are pendant from or sessile on a rod with a fixed or moving contact line and surrounded by an inviscid ambient gas are induced by moving the rod in the vertical direction sinusiodally in time. In this paper, a preliminary report is made on the computational analysis of the oscillations of supported drops that have 'clean' interfaces and whose contact lines remain fixed throughout their motions. The relative importance of forcing to damping can be increased by either increasing the amplitude of rod motion A or Reynolds number Re. It is shown that as the ratio of forcing to damping rises, for drops starting from an initial rest state a sharp increase in deformation can occur when they are forced to oscillate in the vicinity of their resonance frequencies, indicating the incipience of hysteresis. However, it is also shown that the existence of a second stable limit cycle and the occurrence of hysteresis can be observed if the drop is subjected to a so-called frequency sweep, where the forcing frequency is first increased and then decreased over a suitable range. Because the change in drop deformation response is abrupt in the vicinity of the forcing frequencies where hysteresis occurs, it should be possible to exploit the phenomenon to accurately measure the viscosity and surface tension of the drop liquid.

  5. Identification of dominant flow structures in rapidly rotating convection of liquid metals using Dynamic Mode Decomposition

    NASA Astrophysics Data System (ADS)

    Horn, Susanne; Aurnou, Jonathan M.; Schmid, Peter J.

    2016-11-01

    We will present results from direct numerical simulations of rapidly rotating convection in a fluid with Pr 0 . 025 in cylindrical containers and Ekman numbers as low as 5 ×10-6 . In this system, the Coriolis force is the source of two types of inertial modes, the so-called wall modes, that also exist at moderate Prandtl numbers, and cylinder-filling oscillatory modes, that are a unique feature of small Prandtl number convection. The obtained flow fields were analyzed using the Dynamic Mode Decomposition (DMD). This technique allows to extract and identify the structures that govern the dynamics of the system as well as their corresponding frequencies. We have investigated both the regime where the flow is purely oscillatory and the regime where wall modes and oscillatory modes co-exist. In the purely oscillatory regime, high and low frequency oscillatory modes characterize the flow. When both types of modes are present, the DMD reveals that the wall-attached modes dominate the flow dynamics. They precess with a relatively low frequency in retrograde direction. Nonetheless, also in this case, high frequency oscillations have a significant contribution.

  6. Superconducting electromechanical rotating device having a liquid-cooled, potted, one layer stator winding

    DOEpatents

    Dombrovski, Viatcheslav V.; Driscoll, David I.; Shovkhet, Boris A.

    2001-01-01

    A superconducting electromechanical rotating (SER) device, such as a synchronous AC motor, includes a superconducting field winding and a one-layer stator winding that may be water-cooled. The stator winding is potted to a support such as the inner radial surface of a support structure and, accordingly, lacks hangers or other mechanical fasteners that otherwise would complicate stator assembly and require the provision of an unnecessarily large gap between adjacent stator coil sections. The one-layer winding topology, resulting in the number of coils being equal to half the number of slots or other mounting locations on the support structure, allows one to minimize or eliminate the gap between the inner radial ends of adjacent straight sections of the stator coilswhile maintaining the gap between the coil knuckles equal to at least the coil width, providing sufficient room for electrical and cooling element configurations and connections. The stator winding may be potted to the support structure or other support, for example, by a one-step VPI process relying on saturation of an absorbent material to fill large gaps in the stator winding or by a two-step process in which small gaps are first filled via a VPI or similar operation and larger gaps are then filled via an operation that utilizes the stator as a portion of an on-site mold.

  7. Influence of the organized structure of 1-alkyl-3-methylimidazolium-based ionic liquids on the rotational diffusion of an ionic solute.

    PubMed

    Gangamallaiah, V; Dutt, G B

    2013-08-29

    To understand the influence of organized structure of the ionic liquids on the rotational diffusion of a hydrogen bond donating ionic solute, reorientation times (τr) of rhodamine 110 (R110) have been measured in 1-alkyl-3-methylimidazolium ([Rmim+]) based ionic liquids with anions tetrafluoroborate ([BF4-]) and hexafluorophosphate ([PF6-]). The viscosity (η) was varied by changing the temperature (T) and also the alkyl chain length on the imidazolium cation (ethyl, butyl, hexyl, and octyl). It has been noticed that τr versus η/T plots contain two slopes corresponding to lower and higher values of η/T for ionic liquids with [BF4-] as well as [PF6-] anions. For lower values of η/T (<0.2 and <0.3 mPa s K(-1), respectively, for [Rmim+][BF4-] and [Rmim+][PF6-]), rotational diffusion of R110 follows Stokes-Einstein-Debye hydrodynamic theory with stick boundary condition due to specific interactions between the solute and the anions of the ionic liquids. In contrast, at higher η/T, the rotational diffusion of the solute is faster than the stick predictions and this trend could not be explained by the quasihydrodynamic theories of Gierer-Wirtz and Dote-Kivelson-Schwartz as well. Diminishing hydrogen bonding interactions between the solute and the anions, which transpire as a consequence of the organized structure of the ionic liquids, are responsible for the observed behavior.

  8. Hanging drop crystal growth apparatus

    NASA Technical Reports Server (NTRS)

    Naumann, Robert J. (Inventor); Witherow, William K. (Inventor); Carter, Daniel C. (Inventor); Bugg, Charles E. (Inventor); Suddath, Fred L. (Inventor)

    1990-01-01

    This invention relates generally to control systems for controlling crystal growth, and more particularly to such a system which uses a beam of light refracted by the fluid in which crystals are growing to detect concentration of solutes in the liquid. In a hanging drop apparatus, a laser beam is directed onto drop which refracts the laser light into primary and secondary bows, respectively, which in turn fall upon linear diode detector arrays. As concentration of solutes in drop increases due to solvent removal, these bows move farther apart on the arrays, with the relative separation being detected by arrays and used by a computer to adjust solvent vapor transport from the drop. A forward scattering detector is used to detect crystal nucleation in drop, and a humidity detector is used, in one embodiment, to detect relative humidity in the enclosure wherein drop is suspended. The novelty of this invention lies in utilizing angular variance of light refracted from drop to infer, by a computer algorithm, concentration of solutes therein. Additional novelty is believed to lie in using a forward scattering detector to detect nucleating crystallites in drop.

  9. Speciation of As(III) and As(V) in water samples by graphite furnace atomic absorption spectrometry after solid phase extraction combined with dispersive liquid-liquid microextraction based on the solidification of floating organic drop.

    PubMed

    Shamsipur, Mojtaba; Fattahi, Nazir; Assadi, Yaghoub; Sadeghi, Marzieh; Sharafi, Kiomars

    2014-12-01

    A solid phase extraction (SPE) coupled with dispersive liquid-liquid microextraction based on the solidification of floating organic drop (DLLME-SFO) method, using diethyldithiphosphate (DDTP) as a proper chelating agent, has been developed as an ultra preconcentration technique for the determination of inorganic arsenic in water samples prior to graphite furnace atomic absorption spectrometry (GFAAS). Variables affecting the performance of both steps were thoroughly investigated. Under optimized conditions, 100mL of As(ΙΙΙ) solution was first concentrated using a solid phase sorbent. The extract was collected in 2.0 mL of acetone and 60.0 µL of 1-undecanol was added into the collecting solvent. The mixture was then injected rapidly into 5.0 mL of pure water for further DLLME-SFO. Total inorganic As(III, V) was extracted similarly after reduction of As(V) to As(III) with potassium iodide and sodium thiosulfate and As(V) concentration was calculated by difference. A mixture of Pd(NO3)2 and Mg(NO3)2 was used as a chemical modifier in GFAAS. The analytical characteristics of the method were determined. The calibration graph was linear in the rage of 10-100 ng L(-1) with detection limit of 2.5 ng L(-1). Repeatability (intra-day) and reproducibility (inter-day) of method based on seven replicate measurements of 80 ng L(-1) of As(ΙΙΙ) were 6.8% and 7.5%, respectively. The method was successfully applied to speciation of As(III), As(V) and determination of the total amount of As in water samples and in a certified reference material (NIST RSM 1643e).

  10. Spin-Up Instability of a Levitated Molten Drop in MHD-Flow Transition to Turbulence

    NASA Technical Reports Server (NTRS)

    Abedian, B.; Hyers, R. W.; Curreri, Peter A. (Technical Monitor)

    2002-01-01

    When an alternating magnetic field interacts with induced eddy currents in a conducting body, there will be a repulsive force between the body and the driving coil system generating the field. This repulsive force is the basis of electromagnetic levitation, which allows containerless processing of different materials. The eddy currents in the conducting body also generate Joule heating. Axial rotation of electromagnetically levitated objects is a common observation in levitation systems and often an undesirable side effect of such experiments on 1-g and -g. There have been recent efforts to use magnetic damping and suppress this tendency of body rotation. The first report of rotation in EML drops was attributed to a slight asymmetry of the shape and location of the levitation coils could change the axis and speed of rotation. Other theories of sample rotation include a frequency difference in the traveling electromagnetic waves and a phase difference in two different applied fields of the same frequency. All of these different mechanisms share the following characteristics: the torque is small, constant for constant field strength, and very weakly dependent on the sample's temperature and phase (solid or liquid). During experiments on the MSL-1 (First Microgravity Science Laboratory) mission of the Space Shuttle (STS-83 and STS-94, April and July 1997), a droplet of palladium-silicon alloy was electromagnetically levitated for viscosity measurements. For the non-deforming droplet, the resultant MHD flow inside the drop is inferred from motion of impurities on the surface. These observations indicate formation of a pair of co-rotating toroidal flow structures inside the spheroidal levitated drop that undergo secondary flow instabilities. As rise in the fluid temperature rises, the viscosity falls and the internal flow accelerates and becomes oscillatory; and beyond a point in the experiments, the surface impurities exhibit non-coherent chaotic motion signifying

  11. Rotational and Translational Diffusion of Glass-Forming Ionic Liquids Confined in Nanoporous Silica

    NASA Astrophysics Data System (ADS)

    Iacob, Ciprian; Sangoro, Joshua; Runt, James; Kremer, Friedrich

    2014-03-01

    Charge transport and glassy dynamics of several classes of ionic liquids confined in uni-directional nanoporous silica membranes are investigated in a wide frequency and temperature range by a combination of Broadband Dielectric Spectroscopy (BDS), Pulsed Field Gradient Nuclear Magnetic Resonance (PFG NMR) and Fourier Transform Infrared spectroscopy (FTIR). Two opposite effects are observed: (i) surface effects - resulting from strong interactions between the host system (nanoporous silica membrane) and the guest molecules (ILs) lead to slower dynamics - which are significantly reduced upon pore surface modification through silanization of the pores, and (ii) confinement effects - arising from spatial restriction of the molecules in nanometric length-scales - leading to enhancement of molecular dynamics. A model assuming a reduced mobility of the adsorbed layer at the pore wall/IL interface is shown to provide a quantitative explanation for the remarkable decrease of effective transport quantities (such as diffusion coefficient, dc conductivity and consequently, the dielectric loss) of the ILs in non-silanized porous silica membranes.

  12. Rotational dynamics of benzene and water in an ionic liquid explored via molecular dynamics simulations and NMR T1 measurements

    NASA Astrophysics Data System (ADS)

    Yasaka, Yoshiro; Klein, Michael L.; Nakahara, Masaru; Matubayasi, Nobuyuki

    2012-02-01

    The rotational dynamics of benzene and water in the ionic liquid (IL) 1-butyl-3-methylimidazolium chloride are studied using molecular dynamics (MD) simulation and NMR T1 measurements. MD trajectories based on an effective potential are used to calculate the 2H NMR relaxation time, T1 via Fourier transform of the relevant rotational time correlation function, C2R(t). To compensate for the lack of polarization in the standard fixed-charge modeling of the IL, an effective ionic charge, which is smaller than the elementary charge is employed. The simulation results are in closest agreement with NMR experiments with respect to the temperature and Larmor frequency dependencies of T1 when an effective charge of ±0.5e is used for the anion and the cation, respectively. The computed C2R(t) of both solutes shows a bi-modal nature, comprised of an initial non-diffusive ps relaxation plus a long-time ns tail extending to the diffusive regime. Due to the latter component, the solute dynamics is not under the motional narrowing condition with respect to the prevalent Larmor frequency. It is shown that the diffusive tail of the C2R(t) is most important to understand frequency and temperature dependencies of T1 in ILs. On the other hand, the effect of the initial ps relaxation is an increase of T1 by a constant factor. This is equivalent to an "effective" reduction of the quadrupolar coupling constant (QCC). Thus, in the NMR T1 analysis, the rotational time correlation function can be modeled analytically in the form of aexp (-t/τ) (Lipari-Szabo model), where the constant a, the Lipari-Szabo factor, contains the integrated contribution of the short-time relaxation and τ represents the relaxation time of the exponential (diffusive) tail. The Debye model is a special case of the Lipari-Szabo model with a = 1, and turns out to be inappropriate to represent benzene and water dynamics in ILs since a is as small as 0.1. The use of the Debye model would result in an underestimation

  13. Experimentally probing the libration of interfacial water: the rotational potential of water is stiffer at the air/water interface than in bulk liquid.

    PubMed

    Tong, Yujin; Kampfrath, Tobias; Campen, R Kramer

    2016-07-21

    Most properties of liquid water are determined by its hydrogen-bond network. Because forming an aqueous interface requires termination of this network, one might expect the molecular level properties of interfacial water to markedly differ from water in bulk. Intriguingly, much prior experimental and theoretical work has found that, from the perspective of their time-averaged structure and picosecond structural dynamics, hydrogen-bonded OH groups at an air/water interface behave the same as hydrogen-bonded OH groups in bulk liquid water. Here we report the first experimental observation of interfacial water's libration (i.e. frustrated rotation) using the laser-based technique vibrational sum frequency spectroscopy. We find this mode has a frequency of 834 cm(-1), ≈165 cm(-1) higher than in bulk liquid water at the same temperature and similar to bulk ice. Because libration frequency is proportional to the stiffness of water's rotational potential, this increase suggests that one effect of terminating bulk water's hydrogen bonding network at the air/water interface is retarding rotation of water around intact hydrogen bonds. Because in bulk liquid water the libration plays a key role in stabilizing reaction intermediates and dissipating excess vibrational energy, we expect the ability to probe this mode in interfacial water to open new perspectives on the kinetics of heterogeneous reactions at aqueous interfaces.

  14. Solvent and rotational relaxation of Coumarin-153 in a micellar solution of a room-temperature ionic liquid, 1-butyl-3-methylimidazolium octyl sulfate, in ethylammonium nitrate

    NASA Astrophysics Data System (ADS)

    Rao, Vishal Govind; Ghatak, Chiranjib; Pramanik, Rajib; Sarkar, Souravi; Sarkar, Nilmoni

    2010-10-01

    We have investigated the micelle formation by room-temperature ionic liquid (RTIL), 1-butyl-3-methylimidazolium octyl sulfate (bmimOs) with another RTIL, ethyl ammonium nitrate (EAN). In addition, the effect of micelle formation on the solvation and rotational relaxation dynamics have been observed using steady-state and picoseconds time-resolved spectroscopy. Both the solvent and rotational relaxations of Coumarin-153 are retarded in the micelle compared to that of neat EAN. The increase in average solvation time on going from neat EAN to bmimOs-EAN micelle is very small compared to the increase in solvation time on going from pure water to water containing micelle.

  15. Rotational Collision Apparatus for Indoor Egg Drops

    NASA Astrophysics Data System (ADS)

    Halada, Richard

    2003-05-01

    Our units about momentum and energy are richly illustrated with applications to car crashes and explanations of such safety features as airbags and crumple zones. The main lab exercise, however, is an egg crash (car insurance rates being so much higher). Fairly standard rules apply: Students must devise an "egg-protection package" that will keep a teacher-supplied egg intact through two successive impacts. After the test, they must hand in a written analysis of the specific physics principles they employed, modifications they would make after seeing their project's actual performance, and suggestions for applying their protection system to auto safety.

  16. Patient Safety May Drop During Doc Rotations

    MedlinePlus

    ... Arora, an associate professor at the University of Chicago and co-author of an accompanying editorial. "Yes, ... Arora, M.D., MAPP, associate professor, University of Chicago; Dec. 6, 2016, Journal of the American Medical ...

  17. Exploding Water Drops

    NASA Astrophysics Data System (ADS)

    Reich, Gary

    2016-01-01

    Water has the unusual property that it expands on freezing, so that ice has a specific gravity of 0.92 compared to 1.0 for liquid water. The most familiar demonstration of this property is ice cubes floating in a glass of water. A more dramatic demonstration is the ice bomb shown in Fig. 1. Here a cast iron flask is filled with water and tightly stoppered. The flask is then cooled, either by leaving it outdoors in winter or by immersing it in a cryogenic fluid, until the water freezes. As the water freezes and expands, the pressure inside the flask increases dramatically, eventually becoming sufficient to fracture the metal walls of the enclosure. A related, but much less familiar, phenomenon is the explosive fracturing of small water drops upon freezing. That water drops can fracture in this way has been known for many years, and the phenomenon has been described in detail in the atmospheric sciences literature, where it is seen as relevant to the freezing of raindrops as they fall through cold air. Carefully controlled experiments have been done documenting how the character and frequency of fracture is affected by such variables as drop size, rate of cooling, chemistry of dissolved gases, etc. Here I describe instead a simple demonstration of fracture suitable for video analysis and appropriate for study at the introductory physics level. Readers may also be interested in other characteristics of freezing and fragmenting water drops, for example, charge separation upon fracture and the appearance of spikes and bulges on the surface.

  18. A Different Cone: Bursting Drops in Solids

    NASA Astrophysics Data System (ADS)

    Zhao, Xuanhe

    2013-03-01

    Drops in fluids tend to be spheres--a shape that minimizes surface energy. In thunderstorm clouds, drops can become unstable and emit thin jets when charged beyond certain limits. The instability of electrified drops in gases and liquids has been widely studied and used in applications including ink-jet printing, electrospinning nano-fibers, microfluidics and electrospray ionization. Here we report a different scenario: drops in solids become unstable and burst under sufficiently high electric fields. We find the instability of drops in solids morphologically resembles that in liquids, but the critical electric field for the instability follows a different scaling due to elasticity of solids. Our observations and theoretical models not only advance the fundamental understanding of electrified drops but also suggest a new failure mechanism of high-energy-density dielectric polymers, which have diverse applications ranging from capacitors for power grids and electric vehicles to muscle-like transducers for soft robots and energy harvesting.

  19. Rotational Diffusion of Charged and Nondipolar Solutes in Ionic Liquid-Organic Solvent Mixtures: Evidence for Stronger Specific Solute-Solvent Interactions in Presence of Organic Solvent.

    PubMed

    Prabhu, Sugosh R; Dutt, G B

    2015-08-20

    Rotational diffusion of a charged solute, rhodamine 110 (R110), and a nondipolar solute, 2,5-dimethyl-1,4-dioxo-3,6-diphenylpyrrolo[3,4-c]pyrrole (DMDPP), has been investigated in ionic liquids, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIM][Tf2N]) and 1-butyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate ([BMIM][FAP]), with 0.8 mole fraction of dibenzyl ether (DBE). This study has been undertaken to find out how specific interactions between the solute and the ionic liquid are affected upon dilution with a nondipolar solvent. It has been observed that at a given viscosity (η) and temperature (T), the reorientation times of R110 increase by 40-60% in the ionic liquid-organic solvent mixtures compared to ones in the corresponding neat ionic liquids. In the case of DMDPP, the influence of DBE is less pronounced, and its reorientation times increase by 25-50% at a given η/T. The addition of DBE weakens the numerous interactions prevailing between the cations and the anions of the ionic liquids, which results in stronger specific interactions between the solutes and the constituent ions, consequently leading to slower rotation of the solutes.

  20. Operating characteristics of rotating beds. Technical progress report for the third quarter 1988

    SciTech Connect

    Keyvani, M.; Gardner, N.C.

    1988-12-31

    Vapor-liquid contacting in high gravitational fields offers prospects for significant reductions in the physical size, capital, and operating costs of packed towers. Pressure drops, power requirements, mass transfer coefficients and liquid residence time distributions are reported for a rotating bed separator. The beds studied were rigid, foamed aluminum, with specific surface areas ranging from 650 to 3000 m{sup 2}/m{sup 2}. Gravitational fields were varied from 50 to 300g.

  1. Measurement of interfacial tension of immiscible liquid pairs in microgravity

    NASA Technical Reports Server (NTRS)

    Weinberg, Michael C.; Neilson, George F.; Baertlein, Carl; Subramanian, R. Shankar; Trinh, Eugene H.

    1994-01-01

    A discussion is given of a containerless microgravity experiment aimed at measuring the interfacial tension of immiscible liquid pairs using a compound drop rotation method. The reasons for the failure to execute such experiments in microgravity are described. Also, the results of post-flight analyses used to confirm our arguments are presented.

  2. The effect of CdSe/ZnS quantum dots on the rotational viscosity and charge carrier concentration of a nematic liquid crystal

    NASA Astrophysics Data System (ADS)

    Shcherbinin, D. P.; Konshina, E. A.; Solodkov, D. E.

    2015-08-01

    The addition of CdSe/ZnS quantum dots (QDs) with a core diameter of 3.5 nm at a concentration of 10 wt % leads to a 2.5-fold increase in the dynamic rotational viscosity of a 5CB nematic liquid crystal (NLC). A comparison of the diffusion currents in NLC cells filled with pure 5CB and a suspension with QDs shows evidence of an increase in the concentration of charge carriers in the latter case.

  3. Drop dynamics in space. [for space processing

    NASA Technical Reports Server (NTRS)

    Wang, T. G.; Saffren, M. M.; Elleman, D. D.

    1977-01-01

    Experiments to study the dynamics of liquid drops are being planned to be performed in the weightless environment of Spacelab. The liquids will range from superfluid helium through ordinary liquid to molten metals and glasses. The experiments will be conducted in a chamber now being developed which utilizes the forces and torques produced by acoustic waves excited within the chamber. None of the currently available facilities (drop towers, sounding rockets, or zero-g aircraft flights) can provide a sustained weightless environment, since the resulting zero-g periods are from 3 sec to 5 min. Spaceflight, however, will provide weightlessness for periods of one week, or more, allowing truly laboratory-like experiments to be conducted on free liquid drops and bubbles. In this paper we discuss both the drop dynamics experiments proposed for Spacelab and the acoustic chamber: its operation and current testing for these and other experiments.

  4. Drop spreading with random viscosity

    NASA Astrophysics Data System (ADS)

    Xu, Feng; Jensen, Oliver E.

    2016-10-01

    We examine theoretically the spreading of a viscous liquid drop over a thin film of uniform thickness, assuming the liquid's viscosity is regulated by the concentration of a solute that is carried passively by the spreading flow. The solute is assumed to be initially heterogeneous, having a spatial distribution with prescribed statistical features. To examine how this variability influences the drop's motion, we investigate spreading in a planar geometry using lubrication theory, combining numerical simulations with asymptotic analysis. We assume diffusion is sufficient to suppress solute concentration gradients across but not along the film. The solute field beneath the bulk of the drop is stretched by the spreading flow, such that the initial solute concentration immediately behind the drop's effective contact lines has a long-lived influence on the spreading rate. Over long periods, solute swept up from the precursor film accumulates in a short region behind the contact line, allowing patches of elevated viscosity within the precursor film to hinder spreading. A low-order model provides explicit predictions of the variances in spreading rate and drop location, which are validated against simulations.

  5. Dilating Eye Drops

    MedlinePlus

    ... Frequently Asked Questions Español Condiciones Chinese Conditions Dilating Eye Drops En Español Read in Chinese What are dilating eye drops? Dilating eye drops contain medication to enlarge ( ...

  6. Micro-explosion of compound drops

    NASA Astrophysics Data System (ADS)

    Chen, Chun-Kuei; Lin, Ta-Hui

    2014-08-01

    Introducing water into spray combustion systems, by either water-in-oil emulsification or supplementary water injection, is one of the major techniques for combustion improvement and NOx reduction. Plentiful researches are available on combustion of water-in-oil emulsion fuel drops. The emulsified liquid is a heterogeneous mixture of immiscible liquids. One component forms the continuous phase and the other component forms the discrete phase. The discrete phase consists of globules of the one fluid that are suspended in the continuous phase fluid. Water-in-oil emulsions are commonly considered for combustion applications because emulsions can result in micro-explosion, thereby reducing the average drop diameter to enhance liquid vaporization, and suppressing the formation of soot and NOx. However, the water addition generally does not exceed about 20% for smooth engine operations[!, 21. The combustion characteristics and micro-explosion of emulsion drop were studied by many researchers. The micro-explosion of water in fuel emulsion drops was caused by very fast growth of superheated water vapor bubbles, its superheat limits must be lower than the boiling point temperature of the fuel. These bubbles were primarily governed by the pressure difference between the superheated vapor and the liquid, and by the inertia imparted to the liquid by the motion of the bubble surface[3 6 In this study, we used a coaxial nozzle to generation the multi-component drop. The different type of water-in-oil fuel drops called the compound drops. Unlike an emulsion drop, a compound drop consists of a water core and a fuel shell, which can originate from the phase separation of emulsion[7, 81 or a water drop colliding with a fuel drop[9, 101 Burning and micro-explosion of compound drops have been found to be distinct from those of emulsion drops[9-111 Wang et al.[9 , 101 studied the combustion characteristics of collision merged alkane-water drops. The merged drops appeared in adhesive

  7. Interfacial Instabilities in Evaporating Drops

    NASA Astrophysics Data System (ADS)

    Moffat, Ross; Sefiane, Khellil; Matar, Omar

    2007-11-01

    We study the effect of substrate thermal properties on the evaporation of sessile drops of various liquids. An infra-red imaging technique was used to record the interfacial temperature. This technique illustrates the non-uniformity in interfacial temperature distribution that characterises the evaporation process. Our results also demonstrate that the evaporation of methanol droplets is accompanied by the formation of wave-trains in the interfacial temperature field; similar patterns, however, were not observed in the case of water droplets. More complex patterns are observed for FC-72 refrigerant drops. The effect of substrate thermal conductivity on the structure of the complex pattern formation is also elucidated.

  8. Rotational and Translational Dynamics of Rhodamine 6G in a Pyrrolidinium Ionic Liquid: A Combined Time-Resolved Fluorescence Anisotropy Decay and NMR Study

    SciTech Connect

    Guo, Jianchang; Han, Kee Sung; Mahurin, Shannon Mark; Baker, Gary A; Hillesheim, Patrick C; Dai, Sheng; Hagaman, Edward {Ed} W; Shaw, Robert W

    2012-01-01

    NMR spectroscopy and time-resolved fluorescence anisotropy decay (TRFAD) are two of the most commonly used methods to study solute-solvent interactions. However, only a few studies have been reported to date using a combined NMR and TRFAD approach to systematically investigate the overall picture of diffusional and rotational dynamics of both the solute and solvent. In this paper, we combined NMR and TRFAD to probe fluorescent rhodamine dyes in a pyrrolidinium-based room temperature ionic liquid (RTIL), an emergent environmentally-friendly solvent type used in several energy-related applications. A specific interaction of the R6G cation and [Tf2N]- anion was identified, resulting in near-stick boundary condition rotation of R6G in this RTIL. The diffusional rates of the R6G solute and [C4mpyr][Tf2N] solvent derived from 1H NMR suggest the rates are proportional to their corresponding hydrodynamic radii. The 1H and 13C NMR studies of self-rotational dynamics of [C4mpyr][Tf2N] showed that the self-rotational correlation time of [C4mpyr]+ is 47 2 ps at 300 K. At the same temperature, we find that the correlation time for N-CH3 rotation in [C4mpyr]+ is 77 2 ps, comparable to overall molecular reorientation. This slow motion is attributed to properties of the cation structure.

  9. Effect of baffle on slosh reaction forces in rotating liquid helium subjected to a lateral impulse in microgravity

    NASA Technical Reports Server (NTRS)

    Hung, R. J.; Long, Y. T.

    1995-01-01

    Sloshing dynamics within a partially filled rotating Dewar of superfluid He II are investigated in response to a lateral impulse. The study investigates several factors, including how the rotating bubble of superfluid He II reacts to the impulse in microgravity, how the amplitudes of slosh reaction forces act on the Dewar with various rotating speeds, how the frequencies of the sloshing modes excited differ in terms of differences in rotating speeds, and how the sloshing dynamics differ with and without a baffle. The numerical computation of sloshing dynamics is based on the noninertial frame spacecraft-bound coordinates. Results of the simulations are illustrated.

  10. Footprint geometry and sessile drop resonance

    NASA Astrophysics Data System (ADS)

    Chang, Chun-Ti; Daniel, Susan; Steen, Paul H.

    2017-03-01

    In this work, we examine experimentally the resonance of a sessile drop with a square footprint (square drop) on a flat plate. Two families of modal behaviors are reported. One family is identified with the modes of sessile drops with circular footprints (circular drop), denoted as "spherical modes." The other family is associated with Faraday waves on a square liquid bath (square Faraday waves), denoted as "grid modes." The two families are distinguished based on their dispersion behaviors. By comparing the occurrence of the modes, we recognize spherical modes as the characteristic of sessile drops, and grid modes as the constrained response. Within a broader context, we further discuss the resonance modes of circular sessile drops and free spherical drops, and we recognize various modal behaviors as surface waves under different extents of constraint. From these, we conclude that sessile drops resonate according to how wave-number selection by footprint geometry and capillarity compete. For square drops, a dominant effect of footprint constraint leads to grid modes; otherwise, the drops exhibit spherical modes, the characteristic of sessile drops on flat plates.

  11. Isoelectric focusing in a drop.

    PubMed

    Weiss, Noah G; Hayes, Mark A; Garcia, Antonio A; Ansari, Rafat R

    2011-01-04

    A novel approach to molecular separations is investigated using a technique termed droplet-based isoelectric focusing. Drops are manipulated discretely on a superhydrophobic surface, subjected to low voltages for isoelectric focusing, and split-resulting in a preparative separation. A universal indicator dye demonstrates the generation of stable, reversible pH gradients (3-10) in ampholyte buffers, and these gradients lead to protein focusing within the drop length. Focusing was visually characterized, spectroscopically verified, and assessed quantitatively by noninvasive light scattering measurements. It was found to correlate with a quantitative model based on 1D steady-state theory. This work illustrates that molecular separations can be deployed within a single open drop, and the differential fractions can be separated into new discrete liquid elements.

  12. Analysis of a Free Surface Film from a Controlled Liquid Impinging Jet over a Rotating Disk Including Conjugate Effects, with and without Evaporation

    NASA Technical Reports Server (NTRS)

    Sankaran, Subramanian (Technical Monitor); Rice, Jeremy; Faghri, Amir; Cetegen, Baki M.

    2005-01-01

    A detailed analysis of the liquid film characteristics and the accompanying heat transfer of a free surface controlled liquid impinging jet onto a rotating disk are presented. The computations were run on a two-dimensional axi-symmetric Eulerian mesh while the free surface was calculated with the volume of fluid method. Flow rates between 3 and 15 1pm with rotational speeds between 50 and 200 rpm are analyzed. The effects of inlet temperature on the film thickness and heat transfer are characterized as well as evaporative effects. The conjugate heating effect is modeled, and was found to effect the heat transfer results the most at both the inner and outer edges of the heated surface. The heat transfer was enhanced with both increasing flow rate and increasing rotational speeds. When evaporative effects were modeled, the evaporation was found to increase the heat transfer at the lower flow rates the most because of a fully developed thermal field that was achieved. The evaporative effects did not significantly enhance the heat transfer at the higher flow rates.

  13. Drop motion induced by vertical vibrations

    NASA Astrophysics Data System (ADS)

    Sartori, Paolo; Quagliati, Damiano; Varagnolo, Silvia; Pierno, Matteo; Mistura, Giampaolo; Magaletti, Francesco; Massimo Casciola, Carlo

    2015-11-01

    We have studied the motion of liquid drops on an inclined plate subject to vertical vibrations. The liquids comprised distilled water and different aqueous solutions of glycerol, ethanol and isopropanol spanning the range 1-39 mm2 s-1 in kinematic viscosities and 40-72 mN m-1 in surface tension. At sufficiently low oscillating amplitudes, the drops are always pinned to the surface. Vibrating the plate above a certain amplitude yields sliding of the drop. Further increasing the oscillating amplitude drives the drop upward against gravity. In the case of the most hydrophilic aqueous solutions, this motion is not observed and the drop only slides downward. Images taken with a fast camera show that the drop profile evolves in a different way during sliding and climbing. In particular, the climbing drop experiences a much bigger variation in its profile during an oscillating period. Complementary numerical simulations of 2D drops based on a diffuse interface approach confirm the experimental findings. The overall qualitative behavior is reproduced suggesting that the contact line pinning due to contact angle hysteresis is not necessary to explain the drop climbing.

  14. Flue gas desulfurization by rotating beds. Final technical report

    SciTech Connect

    Gardner, N.; Keyvani, M.; Coskundeniz, A.

    1992-12-01

    The operating and mass transfer characteristics of rotating foam metal beds were studied to determine the potential for flue gas desulfurization. This is a final technical report on the work supported by DOE {number_sign}FG22-87-PC79924. The report is divided into two sections, Part 1 deals primarily with the operating characteristics of rotating beds, and Part 2 covers the mass transfer characteristics of S0{sub 2} absorption in water-lime slurries. Rotating foam metal beds are in essence packed towers operated in high gravitational fields. The foam metal bed is in the form of a cylindrical donut, or torus, and is rotated to produced the high centrifugal forces. The liquid phase enters the bed at the inner surface of the torus and is pulled by the field through the bed. Gas flows countercurrent to the liquid. The bed packing can have a very large specific surface areas and not flood. Possible benefits include much smaller height of a transfer unit resulting in smaller equipment and supporting structures, reduced solvent inventory, faster response with improved process control, reduced pressure drop, and shorter startup and shut-down times. This work is concerned broadly with the operating characteristics of rotating beds, the objectives being to (1) determine the pressure drop through the rotating bed; (2) determine the power required to operate the beds, (3) investigate the residence time distribution of the liquid phase in the beds; and (4) determine the mass transfer coefficients of S0{sub 2} absorption. Three packings of differing specific surface areas were studied, with areas ranging from 656 to 2952 m{sub 2}/m{sub 3}. Liquid flow rates to 36 kg/s*m{sub 2}, gas flow rate to 2.2 kg/s*m{sub 2}, and gravitational fields to 300 g were covered in this study.

  15. Mathematical modeling of electro-rotation spectra of small particles in liquid solutions: application to human erythrocyte aggregates.

    PubMed

    Zehe, A; Ramírez, A; Starostenko, O

    2004-02-01

    Electro-rotation can be used to determine the dielectric properties of cells, as well as to observe dynamic changes in both dielectric and morphological properties. Suspended biological cells and particles respond to alternating-field polarization by moving, deforming or rotating. While in linearly polarized alternating fields the particles are oriented along their axis of highest polarizability, in circularly polarized fields the axis of lowest polarizability aligns perpendicular to the plane of field rotation. Ellipsoidal models for cells are frequently applied, which include, beside sphere-shaped cells, also the limiting cases of rods and disks. Human erythrocyte cells, due to their particular shape, hardly resemble an ellipsoid. The additional effect of rouleaux formation with different numbers of aggregations suggests a model of circular cylinders of variable length. In the present study, the induced dipole moment of short cylinders was calculated and applied to rouleaux of human erythrocytes, which move freely in a suspending conductive medium under the effect of a rotating external field. Electro-rotation torque spectra are calculated for such aggregations of different length. Both the maximum rotation speeds and the peak frequencies of the torque are found to depend clearly on the size of the rouleaux. While the rotation speed grows with rouleaux length, the field frequency nu(p) is lowest for the largest cell aggregations where the torque shows a maximum.

  16. Drop impact on a fiber

    NASA Astrophysics Data System (ADS)

    Kim, Sung-Gil; Kim, Wonjung

    2016-04-01

    We present the results of a combined experimental and theoretical investigation of drop impact on a thin fiber. Using high-speed videography, we analyze the dynamics of droplet collision with a fiber. Based on the systematic experiments, we identify three outcomes of collision: capturing, single drop falling, and splitting. The outcomes are presented in a regime map, where the regime boundaries are explained through a scale analysis of forces. We also measure the liquid retention on the fiber after the droplet impact. By considering a liquid film on the fiber, we develop a mechanical model that predicts the residual water mass. Our model reveals that the residual mass depends critically on the fiber thickness and less on the impact speed. Our study can be extended to predicting the remaining droplet, critical problems in air filtration, water collection, and fiber coating.

  17. Numerical and experimental analysis of a thin liquid film on a rotating disk related to development of a spacecraft absorption cooling system

    NASA Technical Reports Server (NTRS)

    Faghri, Amir; Swanson, Theodore D.

    1989-01-01

    The numerical and experimental analysis of a thin liquid film on a rotating and a stationary disk related to the development of an absorber unit for a high capacity spacecraft absorption cooling system, is described. The creation of artificial gravity by the use of a centrifugal field was focused upon in this report. Areas covered include: (1) One-dimensional computation of thin liquid film flows; (2) Experimental measurement of film height and visualization of flow; (3) Two-dimensional computation of the free surface flow of a thin liquid film using a pressure optimization method; (4) Computation of heat transfer in two-dimensional thin film flow; (5) Development of a new computational methodology for the free surface flows using a permeable wall; (6) Analysis of fluid flow and heat transfer in a thin film in the presence and absence of gravity; and (7) Comparison of theoretical prediction and experimental data. The basic phenomena related to fluid flow and heat transfer on rotating systems reported here can also be applied to other areas of space systems.

  18. NMR T{sub 1} relaxation time measurements and calculations with translational and rotational components for liquid electrolytes containing LiBF{sub 4} and propylene carbonate

    SciTech Connect

    Richardson, P. M. Voice, A. M. Ward, I. M.

    2013-12-07

    Longitudinal relaxation (T{sub 1}) measurements of {sup 19}F, {sup 7}Li, and {sup 1}H in propylene carbonate/LiBF{sub 4} liquid electrolytes are reported. Comparison of T{sub 1} values with those for the transverse relaxation time (T{sub 2}) confirm that the measurements are in the high temperature (low correlation time) limit of the T{sub 1} minimum. Using data from pulsed field gradient measurements of self-diffusion coefficients and measurements of solution viscosity measured elsewhere, it is concluded that although in general there are contributions to T{sub 1} from both translational and rotational motions. For the lithium ions, this is mainly translational, and for the fluorine ions mainly rotational.

  19. Determination of triazine herbicides in cereals using dynamic microwave-assisted extraction with solidification of floating organic drop followed by high-performance liquid chromatography.

    PubMed

    Wang, Hui; Li, Guijie; Zhang, Yiqun; Chen, Haiyan; Zhao, Qi; Song, Weitao; Xu, Yang; Jin, Haiyan; Ding, Lan

    2012-04-13

    A simple and cost-effective method of dynamic microwave-assisted extraction (DMAE) combined with solidification of floating organic drop (SFO) was developed for determining the five triazine herbicides in cereals. The approach combines the advantages of DMAE and SFO technique, and up to 15 samples can be treated simultaneously in 16 min. Firstly, triazine herbicides were extracted with 1 mL of methanol containing 90 μL of 1-dodecanol and following with 10 mL of water under the action of microwave energy. After that, 1.5 g sodium chloride was added into the obtained extract, and the mixture was centrifuged and cooled. The 1-dodecanol drop which contained the target analytes was solidified and transferred for analysis by HPLC-UV. Limits of detection of the five triazines obtained were in the range of 1.1-1.5 ng g(-1). Relative standard deviations of intra- and inter-day tests ranging from 5% to 7% were obtained. The method was successfully applied to the analysis of ten cereals and the recoveries of the triazines for the spiked samples were in the range of 80-102%. The proposed method is an alternative approach to the analysis of triazine herbicides in complex solid samples, being more rapid and simpler compared with the traditional extraction method.

  20. Use of volatile organic solvents in headspace liquid-phase microextraction by direct cooling of the organic drop using a simple cooling capsule.

    PubMed

    Ghiasvand, Ali Reza; Yazdankhah, Fatemeh; Hajipour, Somayeh

    2016-08-01

    A low-cost and simple cooling-assisted headspace liquid-phase microextraction device for the extraction and determination of 2,6,6-trimethyl-1,3 cyclohexadiene-1-carboxaldehyde (safranal) in Saffron samples, using volatile organic solvents, was fabricated and evaluated. The main part of the cooling-assisted headspace liquid-phase microextraction system was a cooling capsule, with a Teflon microcup to hold the extracting organic solvent, which is able to directly cool down the extraction phase while the sample matrix is simultaneously heated. Different experimental factors such as type of organic extraction solvent, sample temperature, extraction solvent temperature, and extraction time were optimized. The optimal conditions were obtained as: extraction solvent, methanol (10 μL); extraction temperature, 60°C; extraction solvent temperature, 0°C; and extraction time, 20 min. Good linearity of the calibration curve (R(2) = 0.995) was obtained in the concentration range of 0.01-50.0 μg/mL. The limit of detection was 0.001 μg/mL. The relative standard deviation for 1.0 μg/mL of safranal was 10.7% (n = 6). The proposed cooling-assisted headspace liquid-phase microextraction device was coupled (off-line) to high-performance liquid chromatography and used for the determination of safranal in Saffron samples. Reasonable agreement was observed between the results of the cooling-assisted headspace liquid-phase microextraction high-performance liquid chromatography method and those obtained by a validated ultrasound-assisted solvent extraction procedure.

  1. Investigation of drop coalescence using tomographic PIV

    NASA Astrophysics Data System (ADS)

    Ortiz-Duenas, Cecilia; Kim, Jungyong; Longmire, Ellen

    2008-11-01

    High-speed tomographic PIV was used to obtain evolving volumetric velocity fields of the coalescence of single drops and two side-by-side drops through liquid/liquid interfaces. Reynolds numbers (Re=ρsUσD/μs) based on surface tension velocity (Uσ=D/tσ) and surrounding ambient fluid were 8-10, and the viscosity ratio between the fluid drop and surrounding fluid was 0.14. The coalescence process investigated is driven by gravity and thus the initial drops are non-spherical and the interface is deformed by the drops. Previously, Mohamed-Kassim & Longmire (2004) showed that under these conditions, the film rupture typically occurs off-axis, and therefore the flow is three-dimensional. For a single drop, volumetric velocity vector fields are used to characterize the asymmetric film rupture occurring for 0drop into a vortex ring are relatively axisymmetric. For two side-by-side drops, the first drop to coalesce ruptures off-axis on the side closest to the second drop. The volumetric velocity and vorticity fields indicate an asymmetric collapse of the drop for 0.1drop while the capillary waves are axisymmetric.

  2. Numerical simulation of fluid flow and heat transfer in a thin liquid film over a stationary and rotating disk and comparison with experimental data

    NASA Technical Reports Server (NTRS)

    Faghri, Amir; Swanson, Theodore D.

    1990-01-01

    In the first section, improvements in the theoretical model and computational procedure for the prediction of film height and heat-transfer coefficient of the free surface flow of a radially-spreading thin liquid film adjacent to a flat horizontal surface of finite extent are presented. Flows in the presence and absence of gravity are considered. Theoretical results are compared to available experimental data with good agreement. In the presence of gravity, a hydraulic jump is present, isolating the flow into two regimes: supercritical upstream from the jump and subcritical downstream of it. In this situation, the effects of surface tension are important near the outer edge of the disk where the fluid experiences a free fall. A region of flow separation is present just downstream of the jump. In the absence of gravity, no hydraulic jump or separated flow region is present. The variation of the heat-transfer coefficient for flows in the presence and absence of gravity are also presented. In the second section, the results of a numerical simulation of the flow field and associated heat transfer coefficients are presented for the free surface flow of a thin liquid film adjacent to a horizontal rotating disk. The computation was performed for different flow rates and rotational velocities using a 3-D boundary-fitted coordinate system. Since the geometry of the free surface is unknown and dependent on flow rate, rate of rotation, and other parameters, an iterative procedure had to be used to ascertain its location. The computed film height agreed well with existing experimental measurements. The flow is found to be dominated by inertia near the entrance and close to the free surface and dominated by centrifugal force at larger radii and adjacent to the disk. The rotation enhances the heat transfer coefficient by a significant amount.

  3. A model for liquid film in steam turbine

    NASA Astrophysics Data System (ADS)

    Simon, Amelie; Marcelet, Meryem; Herard, Jean-Marc; Dorey, Jean-Marc; Lance, Michel

    2015-11-01

    Wetness in steam turbines induces losses and erosion. Drops are created due to the fast expansion of the steam (homogeneous nucleation) and the impurities in the steam (heterogeneous nucleation). The droplets grow and some among them settle on the blade leading to a thin liquid film. This film may then be atomized into coarse water drops which crash on the following blades. The liquid film configuration is a thin film on a curved surface, created by the drop deposit and under high steam friction. In steam turbines, the liquid film is subject to high rotational effect (rotor) and/or to negative gravity. Moreover, due to interfacial instabilities, some drops are torn off from the film. The retained approach is an integral formulation of the Navier-Stokes equation (or shallow water equation) with specific terms. The derivation of these equations requires some closure laws for the convection contributions, the Coriolis terms and for terms related to the additional mass coming from the drops deposit. Once chosen, mathematical and mechanical analyses are performed (hyperbolicity, entropy, galilean and rotational invariance). A two-dimensional code has been developed based on finite volume method to simulate numerically this liquid film model for steam turbines.

  4. An experimental study of dynamics of drop formation

    SciTech Connect

    Zhang, X.; Basaran, O.A.

    1995-06-01

    A liquid being ejected from a nozzle emanates from it as discrete, uniformly sized drops when the flow rate is sufficiently low. In this paper, an experimental study is presented of the dynamics of a viscous liquid drop that is being formed directly at the tip of a vertical tube into ambient air. The evolution in time of the drop shape and volume is monitored with a time resolution of 1/12 to 1 ms. Following the detachment of the previous drop, the profile of the new growing drop at first changes from spherical to pear-shaped. As time advances, the throat of the pear-shaped drop takes on the appearance of a liquid thread that connects the bottom portion of the drop that is about to detach to the rest of the liquid that is pendant from the tube. The focus here is on probing the effects of physical and geometric parameters on the universal features of drop formation, paying special attention to the development, extension, and breakup of the liquid thread and the satellite drops that are formed subsequent to its breakup. The role of surfactants in modifying the dynamics of drop formation is also studied. The effects of finite inertial, capillary, viscous, and gravitational forces are all accounted for to classify drastically different formation dynamics and to elucidate the fate of satellite drops following thread rupture.

  5. Chiroptical detection during liquid chromatography 7. The rotation angle/absorbance ratio of chiral molecules. Its possible use for on-line analysis during preparative separations of enantiomers.

    PubMed

    Brandl, F; Pustet, N; Mannschreck, A

    2001-02-16

    The rotation angle/absorbance ratios C+ = alpha+/A+ and C- = a-/A-, determined via detection by a polarimeter and a photometer, were checked for the first time with reference to their use for on-line analysis during preparative separations. For this purpose, (+)-, (-)- and (+/-)-carvones were investigated by liquid chromatography (LC) on microcrystalline tribenzoylcellulose. It turned out that the ratios C+ and C- depend only slightly upon concentration (Table 1). Overlapped peaks of enantiomers were successfully submitted to computer deconvolution (e.g. Fig. 2, bottom). A procedure for on-line analysis during preparative LC is proposed.

  6. Eye Drop Tips

    MedlinePlus

    ... Involved News About Us Donate In This Section Eye Drop Tips en Español email Send this article ... the reach of children. Steps For Putting In Eye Drops: Start by tilting your head backward while ...

  7. Attracting Water Drops

    NASA Video Gallery

    Astronauts Cady Coleman and Ron Garan perform the Attracting Water Drops experiment from Chabad Hebrew Academy in San Diego, Calif. This research determines if a free-floating water drop can be att...

  8. A rapid and selective method for simultaneous determination of six toxic phenolic compounds in mainstream cigarette smoke using single-drop microextraction followed by liquid chromatography-tandem mass spectrometry.

    PubMed

    Saha, Subhrakanti; Mistri, Rajib; Ray, Bidhan Chandra

    2013-11-01

    Cigarette smoke contains several toxic phenolic compounds, measurements of which are essential from a public health standpoint. This article describes a simple and selective analytical method for quantitative determination of six toxic phenolic compounds (phenol, catechol, resorcinol, hydroquinone, o-cresol, and p-cresol) from mainstream cigarette smoke using single-drop microextraction in combination with liquid chromatography-tandem mass spectrometry. Single-drop microextraction was applied prior to analysis by liquid chromatography-tandem mass spectrometry for the extraction and preconcentration of target phenolic compounds from raw cigarette smoke extract. The effects of the extraction solvent, sampling time, solution pH, salt addition, sample agitation rate, and temperature on the extraction efficiency were examined and optimized. The identification of each analyte was established by chromatographic retention times, analyte-specific fragmentation patterns, and relative peak area ratios of two product/precursor ion pairs. Analytical parameters such as the detection limit, relative recovery, reproducibility, linearity, and enrichment factor were evaluated under the optimized experimental conditions. 1-Decanol was selected as the extraction solvent and the limits of detection were found to be in the range of 0.05-0.3 ng mL(-1) using an extraction time of 12 min. Gradient chromatographic conditions were optimized for the separation of the six phenolic compounds in a run time of 10 min including reequilibration of the column. The present method for determination of phenolic compounds from mainstream cigarette smoke is simple and specific and shows good reproducibility, with relative standard deviations less than 10% for all targeted phenolics.

  9. Transport Powder and Liquid Samples by Surface Acoustic Waves

    NASA Technical Reports Server (NTRS)

    Bao, Xiaoqi; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Louyeh, Sahar

    2009-01-01

    Sample transport is an important requirement for In-situ analysis of samples in NASA planetary exploration missions. Tests have shown that powders or liquid drops on a surface can be transported by surface acoustic waves (SAW) that are generated on the surface using interdigital transducers. The phenomena were investigated experimentally and to generate SAWs interdigital electrodes were deposited on wafers of 128 deg rotated Y-cut LiNbO?. Transporting capability of the SAW device was tested using particles of various sizes and drops of various viscosities liquids. Because of different interaction mechanisms with the SAWs, the powders and the liquid drops were observed to move in opposite directions. In the preliminary tests, a speed of 180 mm/s was achieved for powder transportation. The detailed experimental setup and results are presented in this paper. The transporting mechanism can potentially be applied to miniaturize sample analysis system or " lab-on-chip" devices.

  10. Motility of active fluid drops on surfaces

    NASA Astrophysics Data System (ADS)

    Khoromskaia, Diana; Alexander, Gareth P.

    2015-12-01

    Drops of active liquid crystal have recently shown the ability to self-propel, which was associated with topological defects in the orientation of active filaments [Sanchez et al., Nature 491, 431 (2013), 10.1038/nature11591]. Here, we study the onset and different aspects of motility of a three-dimensional drop of active fluid on a planar surface. We analyze theoretically how motility is affected by orientation profiles with defects of various types and locations, by the shape of the drop, and by surface friction at the substrate. In the scope of a thin drop approximation, we derive exact expressions for the flow in the drop that is generated by a given orientation profile. The flow has a natural decomposition into terms that depend entirely on the geometrical properties of the orientation profile, i.e., its bend and splay, and a term coupling the orientation to the shape of the drop. We find that asymmetric splay or bend generates a directed bulk flow and enables the drop to move, with maximal speeds achieved when the splay or bend is induced by a topological defect in the interior of the drop. In motile drops the direction and speed of self-propulsion is controlled by friction at the substrate.

  11. Influence of aqueous electrolytes on the wetting behavior of hydrophobic solid polymers-low-rate dynamic liquid/fluid contact angle measurements using axisymmetric drop shape analysis.

    PubMed

    Welzel, Petra B; Rauwolf, Cordula; Yudin, Olexandr; Grundke, Karina

    2002-07-01

    The interaction of inorganic ions with low-energy hydrophobic surfaces was examined using model systems of solid polymers without ionizable functional surface groups in aqueous electrolyte solutions. Low-rate dynamic contact angle measurements with captive bubbles in conjunction with axisymmetric drop shape analysis (ADSA) were performed to study the influence of electrolyte ions (in the aqueous test solutions) on the wettability of the polymers. When various types of ions were used, no significant change in advancing and receding contact angles was observed. The contact angle hysteresis was small. The zeta potential of the model polymers in aqueous electrolyte solutions was determined from streaming potential measurements. The variation of the zeta potential at different pH levels indicates preferential adsorption of hydroxyl ions at this interface. However, the presence of electrolytes at the interface between water and the different model polymers did not influence the macroscopic contact angle. The results may suggest the absence of any specific interaction between the ions and the solid polymer, as this should result in changes of hydrophobicity. Similar to the air/water interface, the composition and the potential of the polymer/water interface are obviously determined predominantly by the aqueous phase with only slight influence from the solid phase.

  12. A rotating two-phase gas/liquid flow for pressure reduction in underwater plasma arc welding

    SciTech Connect

    Steinkamp, H.; Creutz, M.; Mewes, D.; Bartzsch, J.

    1994-12-31

    Plasma arc welding processes are used in off-shore industry for the construction and maintenance in the wet surrounding of underwater structures and pipelines. In greater water depth the density of the plasma gas increase because of the greater hydrostatic pressure. This causes an increase of the conductive heat losses to the wet surrounding. To keep up the energy flux to the workpiece a pressure reduction is favorable against the surrounding. To keep up the energy flux to the workpiece a pressure reduction is favorable against the surrounding. The plasma arc has to burn in a locally dry area. This requirement can be fulfilled by a rotating disc placed above the workpiece. In the gap between the lower end of the cylinder and the workpiece a rotating two-phase flow is maintained. The flow around the rotating disc is experimentally investigated. The rotating disc is placed above the surface of the workpiece which is simulated by a flat plate. Water is forced out of the cylinder due to centrifugal forces set up by the rotating disc and flat plate. The velocity distribution in the flow is measured by Laser-Doppler-Anemometry. The phase distribution in the two-phase flow in the gap is measured by local electrical probes. The static pressure in the gaseous atmosphere is reduced in comparison to the hydrostatic pressure of the surrounding water. The pressure reduction is given by the void fraction, the phase distribution and the volume flow rates of both phases in the gap as well as by the speed of revolution and the design of the disc and the work surface. Apart from the investigations on the fluid dynamics, the method to reduce the pressure was technically proved. Experiments were carried out under water with a plasma MIG welder.

  13. Bubble, Drop and Particle Unit (BDPU)

    NASA Technical Reports Server (NTRS)

    1998-01-01

    This section of the Life and Microgravity Spacelab (LMS) publication includes the following articles entitled: (1) Oscillatory Thermocapillary Instability; (2) Thermocapillary Convection in Multilayer Systems; (3) Bubble and Drop Interaction with Solidification Front; (4) A Liquid Electrohydrodynamics Experiment; (5) Boiling on Small Plate Heaters under Microgravity and a Comparison with Earth Gravity; (6) Thermocapillary Migration and Interactions of Bubbles and Drops; and (7) Nonlinear Surface Tension Driven Bubble Migration

  14. Program calculates two-phase pressure drop

    SciTech Connect

    Blackwell, W.W.

    1980-11-24

    Analysts have developed a program for determining the two-phase pressure drop in piping. Written for the TI-59 programmable calculator used with a PC-100C printer, the program incorporates several unique features: it calculates single-phase as well as two-phase pressure drops, has a 10-20 s execution time, permits the operating data to be changed easily, and includes an option for calculating the estimated surface tension of paraffinic hydrocarbon liquids.

  15. Undercooling of acoustically levitated molten drops

    NASA Technical Reports Server (NTRS)

    Ohsaka, K.; Trinh, E. H.; Glicksman, M. E.

    1990-01-01

    It was observed that the acoustically levitated molten SCN (succinonitrile) drops can generally be undercooled to a degree where the impurities in the drop are responsible for the nucleation of the solid phase. However, it was also observed that ultrasound occasionally terminates undercooling of the levitated drops by initiating the nucleation of the solid at an undercooling level which is lower than that found for the nucleation catalyzed by the impurities in the drop. This premature nucleation can be explained by thermodynamic considerations which predict an increase in effective undercooling of the liquid upon the collapse of cavities. Pre-existing gas microbubbles which grow under the influence of ultrasound are suggested as the source of cavitation. The highly undercooled SCN drops can be utilized to measure the growth velocity of the solid in the deeply undercooled region including the hypercooled region.

  16. Universality in freezing of an asymmetric drop

    NASA Astrophysics Data System (ADS)

    Ismail, Md Farhad; Waghmare, Prashant R.

    2016-12-01

    We present the evidence of universality in conical tip formation during the freezing of arbitrary-shaped sessile droplets. The focus is to demonstrate the relationship between this universality and the liquid drop shape. We observe that, in the case of asymmetric drops, this universal shape is achieved when the tip reconfigures by changing its location, which subsequently alters the frozen drop shape. The proposed "two-triangle" model quantifies the change in the tip configuration as a function of the asymmetry of the drop that shows a good agreement with the experimental evidence. Finally, based on the experimental and theoretical exercise, we propose the scaling dependence between the variations in the tip configuration and the asymmetry of the drop.

  17. Particle-drop Impact in Midair

    NASA Astrophysics Data System (ADS)

    Amirfazli, Alidad; Strzebin, Stefan; Peise, Oliver; Chevrollier, David

    2011-11-01

    For the first time the impact of a drop and particle in the mid-air is studied, which is a fundamental physical phenomenon relevant to many applications involving a fluidized bed and a liquid jet, e.g. drug particle coating, and upgrading of heavy oil. To date it has not been clear what happens when a particle and drop collide in midair. An apparatus was build to allow deterministic impact of a particle and drop to occur in midair. Using high speed imaging the impact of three different particles with water drops is studied at different relative velocities. Possible collision outcomes are elucidated in terms of particle-drop diameter ratio, Weber number, and particle wettability. Three distinct regimes of bonding, ripping and coating, and shattering are identified and discussed in this novel study. The differences between on-axis versus off-axis impact is also briefly discussed. NSERC & Canada Research Chairs.

  18. Viscosity Measurement Using Drop Coalescence in Microgravity

    NASA Technical Reports Server (NTRS)

    Antar, Basil N.; Ethridge, Edwin C.; Maxwell, Daniel; Curreri, Peter A. (Technical Monitor)

    2002-01-01

    We present in here validation studies of a new method for application in microgravity environment which measures the viscosity of highly viscous undercooled liquids using drop coalescence. The method has the advantage of avoiding heterogeneous nucleation at container walls caused by crystallization of undercooled liquids during processing. Homogeneous nucleation can also be avoided due to the rapidity of the measurement using this method. The technique relies on measurements from experiments conducted in near zero gravity environment as well as highly accurate analytical formulation for the coalescence process. The viscosity of the liquid is determined by allowing the computed free surface shape relaxation time to be adjusted in response to the measured free surface velocity for two coalescing drops. Results are presented from two sets of validation experiments for the method which were conducted on board aircraft flying parabolic trajectories. In these tests the viscosity of a highly viscous liquid, namely glycerin, was determined at different temperatures using the drop coalescence method described in here. The experiments measured the free surface velocity of two glycerin drops coalescing under the action of surface tension alone in low gravity environment using high speed photography. The liquid viscosity was determined by adjusting the computed free surface velocity values to the measured experimental data. The results of these experiments were found to agree reasonably well with the known viscosity for the test liquid used.

  19. Void fraction and phase distribution of a rotating two-phase gas-liquid flow around a plasma arc under water

    SciTech Connect

    Steinkamp, H.; Mewes, D.

    1994-12-31

    Plasma arc welding processes are used in off-shore industry for construction and maintenance in the wet surrounding of underwater structures and pipelines. In greater water depth the density of the plasma gas increase because of the greater hydrostatic pressure. This causes the increase of conductive heat losses to the wet surrounding. To keep up the energy flux to the workpiece to be welded, the plasma arc has to burn in a local dry area with an inside pressure of 1 bar. This requirement can be fulfilled by a rotating cylinder with a liquid film flowing down the inner wall. The flow around the rotating cylinder to create a local dry area around the plasma arc under water is experimentally investigated. The rotating cylinder is placed above the work surface which is simulated by a flat plate. According to the centrifugal forces of the rotating flow inside the gap between the lower end of the cylinder and the flat plate the water is forced out of the cylinder. The velocity distribution in the flow is measured by Laser-Doppler anemometry. The phase distribution in the two-phase flow in the gap is measured by local electrical probes. The static pressure inside the gaseous atmosphere is reduced in comparison to the hydrostatic pressure of the surrounding water. The pressure reduction is given by the void fraction, the phase distribution and the volume flow rates of both phases in the gap as well as by the speed of revolution and the design of the cylinder and the work surface. The influence of these parameters on the heat transfer from the workpiece to the two-phase flow regime is also investigated.

  20. Thermocapillary Convection in Bubbles and Drops

    NASA Technical Reports Server (NTRS)

    Balassubramaniam; Subramanian, R. Shankar

    2003-01-01

    When bubbles or drops are present in an immiscible liquid in reduced gravity and the temperature of the liquid is non-uniform, a thermocapillary stress is generated at the interface due to the variation of interfacial tension with temperature. The resulting flow propels the drop freely suspended in the liquid towards warmer regions, so as to minimize the interfacial energy. In this presentation, we will focus on the effect of convective transport of momentum and energy, that are characterized by the Reynolds number and the Marangoni number, respectively. The results of asymptotic analyses for the speed of the drop for low and large values of these parameters will be discussed. These predictions as well as those from numerical simulations will be compared with reduced gravity experimental results obtained from experiments performed aboard the space shuttle.

  1. Drops can bounce from perfectly hydrophilic surfaces

    NASA Astrophysics Data System (ADS)

    Kolinski, J. M.; Mahadevan, L.; Rubinstein, S. M.

    2014-10-01

    Drops are well known to rebound from superhydrophobic surfaces and from liquid surfaces. Here, we show that drops can also rebound from a superhydrophilic solid surface such as an atomically smooth mica sheet. However, the coefficient of restitution CR associated with this process is significantly lower than that associated with rebound from superhydrophobic surfaces. A direct imaging method allows us to characterize the dynamics of the deformation of the drop in entering the vicinity of the surface. We find that drop bouncing occurs without the drop ever touching the solid and there is a nanometer-scale film of air that separates the liquid and solid, suggesting that shear in the air film is the dominant source of dissipation during rebound. Furthermore, we see that any discrete nanometer-height defects on an otherwise hydrophilic surface, such as treated glass, completely inhibits the bouncing of the drop, causing the liquid to wet the surface. Our study adds a new facet to the dynamics of droplet impact by emphasizing that the thin film of air can play a role not just in the context of splashing but also bouncing, while highlighting the role of rare surface defects in inhibiting this response.

  2. Electrohydrodynamic removal of particles from drop surfaces.

    PubMed

    Nudurupati, S; Janjua, M; Singh, P; Aubry, N

    2009-07-01

    A uniform electric field is used for cleaning drops of the particles they often carry on their surface. In a first step, particles migrate to either the drop's poles or equator. This is due to the presence of an electrostatic force for which an analytical expression is derived. In a second step, particles concentrated near the poles are released into the ambient liquid via tip streaming, and those near the equator are removed by stretching the drop and breaking it into several droplets. In the latter case, particles are all concentrated in a small middle daughter droplet.

  3. Change of translational-rotational coupling in liquids revealed by field-cycling {sup 1}H NMR

    SciTech Connect

    Meier, R.; Schneider, E.; Rössler, E. A.

    2015-01-21

    Applying the field-cycling nuclear magnetic resonance technique, the frequency dependence of the {sup 1}H spin-lattice relaxation rate, R{sub 1}(ω)=T{sub 1}{sup −1}(ω), is measured for propylene glycol (PG) which is increasingly diluted with deuterated chloroform. A frequency range of 10 kHz–20 MHz and a broad temperature interval from 220 to about 100 K are covered. The results are compared to those of experiments, where glycerol and o-terphenyl are diluted with their deuterated counter-part. Reflecting intra- as well as intermolecular relaxation, the dispersion curves R{sub 1}(ω,x) (x denotes mole fraction PG) allow to extract the rotational time constant τ{sub rot}(T, x) and the self-diffusion coefficient D(T, x) in a single experiment. The Stokes-Einstein-Debye (SED) relation is tested in terms of the quantity D(T, x) τ{sub rot}(T, x) which provides a measure of an effective hydrodynamic radius or equivalently of the spectral separation of the translational and the rotational relaxation contribution. In contrast to o-terphenyl, glycerol and PG show a spectral separation much larger than suggested by the SED relation. In the case of PG/chloroform mixtures, not only an acceleration of the PG dynamics is observed with increasing dilution but also the spectral separation of rotational and translational relaxation contributions continuously decreases. Finally, following a behavior similar to that of o-terphenyl already at about x = 0.6; i.e., while D(T, x) τ{sub rot}(T, x) in the mixture is essentially temperature independent, it strongly increases with x signaling thus a change of translational-rotational coupling. This directly reflects the dissolution of the hydrogen-bond network and thus a change of solution structure.

  4. A dead-zone free ⁴He atomic magnetometer with intensity-modulated linearly polarized light and a liquid crystal polarization rotator.

    PubMed

    Wu, T; Peng, X; Lin, Z; Guo, H

    2015-10-01

    We demonstrate an all-optical (4)He atomic magnetometer experimental scheme based on an original Bell-Bloom configuration. A single intensity-modulated linearly polarized laser beam is used both for generating spin polarization within a single (4)He vapor and probing the spin precessing under a static magnetic field. The transmitted light signal from the vapor is then phase-sensitively detected at the modulation frequency and its harmonics, which lead to the atomic magnetic resonance signals. Based on this structure, a liquid crystal is added in our magnetometer system and constitutes a polarization rotator. By controlling the voltage applied on the liquid crystal, the light linear polarization vector can be kept perpendicular with the ambient magnetic field direction, which in turn provides the maximum resonance signal amplitude. Moreover, the system exhibits a magnetic-field noise floor of about 2pT/√Hz, which is not degraded due to the presence of the liquid crystal and varying magnetic field direction. The experiment results prove that our method can eliminate the dead-zone effect, improve the system spatial isotropy, and thus be suitable in mobile applications.

  5. Drop splash on a smooth, dry surface

    NASA Astrophysics Data System (ADS)

    Riboux, Guillaume; Gordillo, Jose Manuel; Korobkin, Alexander

    2013-11-01

    It is our purpose here to determine the conditions under which a drop of a given liquid with a known radius R impacting against a smooth impermeable surface at a velocity V, will either spread axisymmetrically onto the substrate or will create a splash, giving rise to usually undesired star-shaped patterns. In our experimental setup, drops are generated injecting low viscosity liquids falling under the action of gravity from a stainless steel hypodermic needle. The experimental observations using two high speed cameras operating simultaneously and placed perpendicularly to each other reveal that, initially, the drop deforms axisymmetrically, with A (T) the radius of the wetted area. For high enough values of the drop impact velocity, a thin sheet of liquid starts to be ejected from A (T) at a velocity Vjet > V for instants of time such that T >=Tc . If Vjet is above a certain threshold, which depends on the solid wetting properties as well as on the material properties of both the liquid and the atmospheric gas, the rim of the lamella dewets the solid to finally break into drops. Using Wagner's theory we demonstrate that A (T) =√{ 3 RVT } and our results also reveal that Tc We - 1 / 2 =(ρV2 R / σ) - 1 / 2 and Vjet We 1 / 4 .

  6. Development of revolving drop surface tensiometer.

    PubMed

    Mitani, S; Sakai, K

    2012-01-01

    A revolving drop surface tensiometer, which measures the surface tension of a small amount of liquid, is proposed. A remarkable feature of this device is that while using the pendant drop method, it employs a centrifugal force to deform the liquid droplet. The centrifugal force induces a large distortion of the droplet, which enables an accurate measurement of the surface tension to be made. In our experimental setup, the centrifugal force can be increased so that the apparent acceleration becomes up to 100 times larger than that due to gravity, and the capability of this method to measure surface tensions was demonstrated with ethylene glycol.

  7. Transformation of the bridge during drop separation

    NASA Astrophysics Data System (ADS)

    Chashechkin, Yu. D.; Prokhorov, V. E.

    2016-05-01

    The geometry of flows during separation of pendant drops of liquids with significantly different physical properties (alcohol, water, glycerin, oil) has been studied by high-speed video recording. The dynamics of the processes involving the formation of bridges of two characteristic shapes—slightly nonuniform in thickness and with thinning of the upper and lower ends—has been investigated. It has been shown that the shape change of the separated bridge has a number of stages determined by the properties of the liquid. As a result, the bridge is transformed into a small drop—a satellite drop.

  8. Influence of high voltage electric fields applied across a horizontal liquid-liquid interface on the rate of metal extraction using a rotating diffusion cell

    SciTech Connect

    Kuipa, P.K.; Hughes, M.A.

    1999-09-01

    The effect of an applied electrical field across a plane liquid-liquid interface on the rate of metal extraction using hydroxyoximes and dialkylphosphoric acids as extractants is examined. The results indicate that applied electric fields have no marked influence on the observed rate of metal extraction when aliphatic hydrocarbons are employed as the diluents in the organic phase. Increases in mass transfer rates of up to 250% were observed when mixtures of octanol and an aliphatic hydrocarbon were employed as the diluent in the organic phase. The mechanism of transfer is thought to be a combination of movement of charges in the bulk of the nonconducting organic phase and electrohydrodynamic flows due to local variations in the effective interfacial tension as a result of the applied electric fields.

  9. Total Gaussian curvature, drop shapes and the range of applicability of drop shape techniques.

    PubMed

    Saad, Sameh M I; Neumann, A Wilhelm

    2014-02-01

    Drop shape techniques are used extensively for surface tension measurement. It is well-documented that, as the drop/bubble shape becomes close to spherical, the performance of all drop shape techniques deteriorates. There have been efforts quantifying the range of applicability of drop techniques by studying the deviation of Laplacian drops from the spherical shape. A shape parameter was introduced in the literature and was modified several times to accommodate different drop constellations. However, new problems arise every time a new configuration is considered. Therefore, there is a need for a universal shape parameter applicable to pendant drops, sessile drops, liquid bridges as well as captive bubbles. In this work, the use of the total Gaussian curvature in a unified approach for the shape parameter is introduced for that purpose. The total Gaussian curvature is a dimensionless quantity that is commonly used in differential geometry and surface thermodynamics, and can be easily calculated for different Laplacian drop shapes. The new definition of the shape parameter using the total Gaussian curvature is applied here to both pendant and constrained sessile drops as an illustration. The analysis showed that the new definition is superior and reflects experimental results better than previous definitions, especially at extreme values of the Bond number.

  10. Drop Ejection From an Oscillating Rod

    NASA Technical Reports Server (NTRS)

    Wilkes, E. D.; Basaran, O. A.

    1999-01-01

    The dynamics of a drop of a Newtonian liquid that is pendant from or sessile on a solid rod that is forced to undergo time-periodic oscillations along its axis is studied theoretically. The free boundary problem governing the time evolution of the shape of the drop and the flow field inside it is solved by a method of lines using a finite element algorithm incorporating an adaptive mesh. When the forcing amplitude is small, the drop approaches a limit cycle at large times and undergoes steady oscillations thereafter. However, drop breakup is the consequence if the forcing amplitude exceeds a critical value. Over a wide range of amplitudes above this critical value, drop ejection from the rod occurs during the second oscillation period from the commencement of rod motion. Remarkably, the shape of the interface at breakup and the volume of the primary drop formed are insensitive to changes in forcing amplitude. The interface shape at times close to and at breakup is a multi-valued function of distance measured along the rod axis and hence cannot be described by recently popularized one-dimensional approximations. The computations show that drop ejection occurs without the formation of a long neck. Therefore, this method of drop formation holds promise of preventing formation of undesirable satellite droplets.

  11. Characterization of maleic acid/anhydride copolymer films by low-rate dynamic liquid-fluid contact angle measurements using axisymmetric drop shape analysis.

    PubMed

    Uhlmann, Petra; Skorupa, Sebastian; Werner, Carsten; Grundke, Karina

    2005-07-05

    Thin films of alternating maleic acid/anhydride copolymers (poly(octadecene-alt-maleic acid/anhydride), POMA; poly(propene-alt-maleic acid/anhydride), PPMA; poly(styrene-alt-maleic acid/anhydride), PSMA) were studied to unravel the influence of the comonomer characteristics in the backbone on the surface-energetic properties of the copolymer films in the dry state and in contact with aqueous solutions. Water contact angle measurements revealed a graduation of the wettability of the dry hydrolyzed and annealed copolymer films that was dependent on the comonomer unit. It ranged from moderately hydrophilic (PPMA, annealed gamma(sv) = 39.9 mJ/m2) to very hydrophobic (POMA, annealed, gamma(sv) = 18.4 mJ/m2) surfaces. Liquid-fluid contact angle measurements using captive air bubbles were performed in different aqueous media (pure water, phosphate-buffered saline, and 10(-)(3) M KCl of two different pH values (pH = 3 and pH = 10) to study the copolymer films in their hydrated states relevant for biointerfacial phenomena. It was found that the graduation of the wettability of the copolymer films in the dry state is overall maintained upon immersion in aqueous solutions. The dependence of the wettability on the pH value of the aqueous medium could be related to the (de)protonation of the carboxylic groups.

  12. Size of the top jet drop produced by bubble bursting

    NASA Astrophysics Data System (ADS)

    Ghabache, Elisabeth; Séon, Thomas

    2016-09-01

    As a bubble bursts at a liquid-air interface, a tiny liquid jet rises and can release the so-called jet drops. In this paper the size of the top jet drop produced by a bubble bursting is investigated experimentally. We determine and discuss the first scaling law enabling the determination of the top jet drop size as a function of the corresponding mother bubble radius and the liquid properties (viscosity, surface tension, and density), along with its regime of existence. Furthermore, with the aim of decoupling experimentally the effects of bubble collapse and jet dynamics on the drop detachment, we propose a scaling providing the top drop size only as a function of the jet velocity and liquid parameters. In particular, this allows us to untangle the intricate roles of viscosity, gravity, and surface tension in the end pinching of the bubble bursting jet.

  13. Interplay between the static ordering and dynamical heterogeneities determining the dynamics of rotation and ordinary liquid phases in 1,6-anhydro-β-D-glucose

    NASA Astrophysics Data System (ADS)

    Madejczyk, O.; Kaminski, K.; Kaminska, E.; Jurkiewicz, K.; Tarnacka, M.; Burian, A.; Paluch, M.

    2017-02-01

    In this letter, we reported thorough the structural and molecular dynamics studies on 1,6-anhydro-β-D-glucose, the second compound reported so far that is capable to form rotator and supercooled liquid phases. In contrast to the data presented for ethanol, temperature dependences of structural dynamics in both phases are very comparable. On the other hand, X ray measurements revealed unusually long range ordering/correlations between molecules in the ODIC (d ≈ 95 Å) and supercooled phases (d ≈ 30–40 Å) of this carbohydrate. Our consideration clearly demonstrated that the interplay between length scales of static range ordering and dynamical heterogeneities as well as internal molecular arrangement seem to be the key to understanding the molecular dynamics of different materials characterized by varying degree of disorder in the vicinity of the glass transition temperature.

  14. Interplay between the static ordering and dynamical heterogeneities determining the dynamics of rotation and ordinary liquid phases in 1,6-anhydro-β-D-glucose

    PubMed Central

    Madejczyk, O.; Kaminski, K.; Kaminska, E.; Jurkiewicz, K.; Tarnacka, M.; Burian, A.; Paluch, M.

    2017-01-01

    In this letter, we reported thorough the structural and molecular dynamics studies on 1,6-anhydro-β-D-glucose, the second compound reported so far that is capable to form rotator and supercooled liquid phases. In contrast to the data presented for ethanol, temperature dependences of structural dynamics in both phases are very comparable. On the other hand, X ray measurements revealed unusually long range ordering/correlations between molecules in the ODIC (d ≈ 95 Å) and supercooled phases (d ≈ 30–40 Å) of this carbohydrate. Our consideration clearly demonstrated that the interplay between length scales of static range ordering and dynamical heterogeneities as well as internal molecular arrangement seem to be the key to understanding the molecular dynamics of different materials characterized by varying degree of disorder in the vicinity of the glass transition temperature. PMID:28165065

  15. Liquid Oxygen Rotating Friction Ignition Testing of Aluminum and Titanium with Monel and Inconel for Rocket Engine Propulsion System Contamination Investigation

    NASA Technical Reports Server (NTRS)

    Peralta, S.; Rosales, Keisa R.; Stoltzfus, Joel M.

    2009-01-01

    Metallic contaminant was found in the liquid oxygen (LOX) pre-valve screen of the shuttle main engine propulsion system on two orbiter vehicles. To investigate the potential for an ignition, NASA Johnson Space Center White Sands Test Facility performed (modified) rotating friction ignition testing in LOX. This testing simulated a contaminant particle in the low-pressure oxygen turbo pump (LPOTP) and the high-pressure oxygen turbo pump (HPOTP) of the shuttle main propulsion system. Monel(R) K-500 and Inconel(R) 718 samples represented the LPOTP and HPOTP materials. Aluminum foil tape and titanium foil represented the contaminant particles. In both the Monel(R) and Inconel(R) material configurations, the aluminum foil tape samples did not ignite after 30 s of rubbing. In contrast, all of the titanium foil samples ignited regardless of the rubbing duration or material configuration. However, the titanium foil ignitions did not propagate to the Monel and Inconel materials.

  16. Effects of rotation and magnetic field on the onset of convective instability in a liquid layer due to buoyancy and surface tension

    NASA Technical Reports Server (NTRS)

    Sarma, G. S. R.

    1982-01-01

    Thermocapillary stability characteristics of a horizontal liquid layer heated from below rotating about a vertical axis and subjected to a uniform vertical magnetic field are analyzed under a variety of thermal and electromagnetic boundary conditions. Results based on analytical solutions to the pertinent eigenvalue problems are discussed in the light of earlier work on special cases of the more general problem considered here to show in particular the effects of the heat transfer, nonzero curvature and gravity waves at the two-fluid interface. Although the expected stabilizing action of the Coriolis and Lorentz force fields in this configuration are in evidence the optimal choice of an appropriate range for the relevant parameters is shown to be critically dependent on the interfacial effects mentioned above.

  17. Protic ionic liquid-induced changes in the properties of aqueous triton X-100-CTAB surfactant solution: Solvent and rotational relaxation studies

    NASA Astrophysics Data System (ADS)

    Rao, Vishal Govind; Brahmachari, Udita; Mandal, Sarthak; Ghosh, Surajit; Banerjee, Chiranjib; Sarkar, Nilmoni

    2012-11-01

    We have investigated the effect of protic ionic liquid, N,N-Dimethylethanolammonium formate (DAF) addition on Triton X-100-cetyltrimethylammonium bromide (CTAB) mixed micellar solution. We have shown the effect of DAF addition on the size and zeta potential of the mixed micellar aggregates using dynamic light scattering measurements. The steady-state and time-resolved fluorescence spectroscopy have been used to investigate the effect of increasing CTAB/Triton X-100 ratio and DAF addition on the solvent and rotational relaxation of Coumarin-153 in CTAB-Triton X-100 mixed micellar solutions. The average solvation time decreases with increasing CTAB/Triton X-100 ratio and increases with the addition of DAF.

  18. Probing the Interaction between a DNA Nucleotide (Adenosine-5'-Monophosphate Disodium) and Surface Active Ionic Liquids by Rotational Relaxation Measurement and Fluorescence Correlation Spectroscopy.

    PubMed

    Roy, Arpita; Banerjee, Pavel; Dutta, Rupam; Kundu, Sangita; Sarkar, Nilmoni

    2016-10-02

    This article demonstrates the interaction of a deoxyribonucleic acid (DNA) nucleotide, adenosine-5'-monophosphate disodium (AMP) with a cationic surface active ionic liquid (SAIL) 1-dodecyl-3-methylimidazoium chloride (C12mimCl) and an anionic SAIL, 1-butyl-3-methylimidazolium n-octylsulfate ([C4mim][C8SO4]). Dynamic light scattering (DLS) measurements and 1H NMR (nuclear magnetic resonance) studies indicate that substantial interaction is taking place among the DNA nucleotide, AMP and the SAILs. Moreover, cryogenic transmission electron microscopy (cryo-TEM) suggests that SAILs containing micellar assemblies are transformed into larger micellar assemblies in presence of DNA nucleotide. Additionally, the rotational motion of two oppositely charged molecules, Rhodamine 6G perchlorate (R6G) and Fluorescein sodium salt (Fl-Na) have been monitored in these aggregates. The rotational motion of R6G and Fl-Na differs significantly between SAILs micelles, and SAILs-AMP containing larger micellar aggregates. The effect of negatively charged DNA nucleotide (AMP) addition into the cationic and anionic SAILs is more prominent for the cationic charged molecule R6G than that of anionic probe Fl-Na due to the favourable electrostatic interaction between the AMP and cationic R6G. Moreover, the influence of the anionic DNA nucleotide on the cationic and anionic SAIL micelles is monitored through the variation of the lateral diffusion motion of oppositely charged probe molecules (R6G and Fl-Na) inside these aggregates. This variation in diffusion coefficient values also suggests that interaction pattern of these oppositely charged probes are different within the SAILs-nucleotide containing aggregates. Therefore, both rotational and translational diffusion measurements confirm that the DNA nucleotide (AMP) renders more rigid microenvironment within the micellar solution of SAILs.

  19. Experimental Investigation of Pendant and Sessile Drops in Microgravity

    NASA Astrophysics Data System (ADS)

    Zhu, Zhi-Qiang; Brutin, David; Liu, Qiu-Sheng; Wang, Yang; Mourembles, Alexandre; Xie, Jing-Chang; Tadrist, Lounes

    2010-09-01

    The experiments regarding the contact angle behavior of pendant and sessile evaporating drops were carried out in microgravity environment. All the experiments were performed in the Drop Tower of Beijing, which could supply about 3.6 s of microgravity (free-fall) time. In the experiments, firstly, drops were injected to create before microgravity. The wettability at different surfaces, contact angles dependance on the surface temperature, contact angle variety in sessile and pendant drops were measured. Different influence of the surface temperature on the contact angle of the drops were found for different substrates. To verify the feasibility of drops creation in microgravity and obtain effective techniques for the forthcoming satellite experiments, we tried to inject liquid to create bigger drop as soon as the drop entering microgravity condition. The contact angle behaviors during injection in microgravity were also obtained.

  20. On the derivation of Young's equation for sessile drops: nonequilibrium effects due to evaporation.

    PubMed

    Butt, Hans-Jürgen; Golovko, Dmytro S; Bonaccurso, Elmar

    2007-05-17

    Sessile liquid drops have a higher vapor pressure than planar liquid surfaces, as quantified by Kelvin's equation. In classical derivations of Young's equation, this fact is often not taken into account. For an open system, a sessile liquid drop is never in thermodynamic equilibrium and will eventually evaporate. Practically, for macroscopic drops the time of evaporation is so long that nonequilibrium effects are negligible. For microscopic drops evaporation cannot be neglected. When a liquid is confined to a closed system, real equilibrium can be established. Experiments on the evaporation of water drops confirm the calculations.

  1. Modeling Evaporation of Drops of Different Kerosenes

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth

    2007-01-01

    A mathematical model describes the evaporation of drops of a hydrocarbon liquid composed of as many as hundreds of chemical species. The model is intended especially for application to any of several types of kerosenes commonly used as fuels. The concept of continuous thermodynamics, according to which the chemical composition of the evaporating multicomponent liquid is described by use of a probability distribution function (PDF). However, the present model is more generally applicable than is its immediate predecessor.

  2. Diffusion Of Mass In Evaporating Multicomponent Drops

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth G.

    1992-01-01

    Report summarizes study of diffusion of mass and related phenomena occurring in evaporation of dense and dilute clusters of drops of multicomponent liquids intended to represent fuels as oil, kerosene, and gasoline. Cluster represented by simplified mathematical model, including global conservation equations for entire cluster and conditions on boundary between cluster and ambient gas. Differential equations of model integrated numerically. One of series of reports by same authors discussing evaporation and combustion of sprayed liquid fuels.

  3. On the effect of mantle conductivity on the super-rotating jets near the liquid core surface

    NASA Astrophysics Data System (ADS)

    Mizerski, K. A.; Bajer, K.

    2007-03-01

    We consider hydromagnetic Couette flows in planar and spherical geometries with strong magnetic field (large Hartmann number, M≫1). The highly conducting bottom boundary is in steady motion that drives the flow. The top boundary is stationary and is either a highly conducting thin shell or a weakly conducting thick mantle. The magnetic field, B+b, is a combination of the strong, force-free background B and a perturbation b induced by the flow. This perturbation generates strong streamwise electromagnetic stress inside the fluid which, in some regions, forms a jet moving faster than the driving boundary. The super-velocity, in the spherical geometry called super-rotation, is particularly prominent in the region where the 'grazing' line of B has a point of tangent contact with the top boundary and where the Hartmann layer is singular. This is a consequence of topological discontinuity across that special field line. We explain why the magnitude of super-rotation already present when the top wall is insulating [Dormy, E., Jault, D., Soward, A.M., 2002. A super-rotating shear layer in magnetohydrodynamic spherical Couette flow. J. Fluid Mech. 452, 263-291], considerably increases when that wall is even slightly conducting. The asymptotic theory is valid when either the thickness of the top wall is small, δ˜M-1 and its conductivity is high, ɛ˜1 or when δ˜1 and ɛ˜M-1. The theory predicts the super-velocity enhancement of the order of δM in the first case and ɛM in the second case. We also numerically solve the planar problem outside the asymptotic regime, for ɛ=1 and δ=1, and find that with the particular B that we chose the peak super-velocity scales like M0.33. This scaling is different from M0.6 found in spherical geometry [Hollerbach, R., Skinner, S., 2001. Instabilities of magnetically induced shear layers and jets. Proc. R. Soc. Lond. A 457, 785-802].

  4. Drop spreading with random viscosity

    PubMed Central

    2016-01-01

    We examine theoretically the spreading of a viscous liquid drop over a thin film of uniform thickness, assuming the liquid’s viscosity is regulated by the concentration of a solute that is carried passively by the spreading flow. The solute is assumed to be initially heterogeneous, having a spatial distribution with prescribed statistical features. To examine how this variability influences the drop’s motion, we investigate spreading in a planar geometry using lubrication theory, combining numerical simulations with asymptotic analysis. We assume diffusion is sufficient to suppress solute concentration gradients across but not along the film. The solute field beneath the bulk of the drop is stretched by the spreading flow, such that the initial solute concentration immediately behind the drop’s effective contact lines has a long-lived influence on the spreading rate. Over long periods, solute swept up from the precursor film accumulates in a short region behind the contact line, allowing patches of elevated viscosity within the precursor film to hinder spreading. A low-order model provides explicit predictions of the variances in spreading rate and drop location, which are validated against simulations. PMID:27843398

  5. Thermocapillary motion of deformable drops

    NASA Astrophysics Data System (ADS)

    Haj-Hariri, Hossein; Shi, Qingping; Borhan, Ali

    1994-08-01

    The thermocapillary motion of initially spherical drops/bubbles driven by a constant temperature gradient in an unbounded liquid medium is simulated numerically. Effects of convection of momentum and energy, as well as shape deformations, are addressed. The method used is based on interface tracking on a base cartesian grid, and uses a smeared color or indicator function for the determination of the surface topology. Quad-tree adaptive refinement of the cartesian grid is implemented to enhance the fidelity of the surface tracking. It is shown that convection of energy results in a slowing of the drop, as the isotherms get wrapped around the front of the drop. Shape deformation resulting from inertial effects affect the migration velocity. The physical results obtained are in agreement with the existing literature. Furthermore, remarks are made on the sensitivity of the calculated solutions to the smearing of the fluid properties. Analysis and simulations show that the migration velocity depends very strongly on the smearing of the interfacial force whereas it is rather insensitive to the smearing of other properties, hence the adaptive grid.

  6. Youth Crime Drop. Report.

    ERIC Educational Resources Information Center

    Butts, Jeffrey A.

    This report examines the recent drop in violent crime in the United States, discussing how much of the decrease seen between 1995-99 is attributable to juveniles (under age 18 years) and older youth (18-24 years). Analysis of current FBI arrest data indicates that not only did America's violent crime drop continue through 1999, but falling youth…

  7. Drop Tower Physics

    ERIC Educational Resources Information Center

    Dittrich, William A.

    2014-01-01

    The drop towers of yesteryear were used to make lead shot for muskets, as described in "The Physics Teacher" in April 2012. However, modern drop towers are essentially elevators designed so that the cable can "break" on demand, creating an environment with microgravity for a short period of time, currently up to nine seconds at…

  8. Numerical heat transfer during partially-confined, confined, and free liquid jet impingement with rotation and chemical mechanical planarization process modeling

    NASA Astrophysics Data System (ADS)

    Lallave Cortes, Jorge C.

    This work presents the use of numerical modeling for the analysis of transient and steady state liquid jet impingement for cooling application of electronics, and energy dissipation during a CMP process under the influence of a series of parameters that controls the transport phenomena mechanism. Seven thorough studies were done to explore how the flow structure and conjugated heat transfer in both the solid and fluid regions was affected by adding a secondary rotational flow during the jet impingement process. Axis-symmetrical numerical models of round jets with a spinning or static nozzle were developed using the following configurations: confined, partially-confined, and free liquid jet impingement on a rotating or stationary uniformly heated disk of finite thickness and radius. Calculations were done for various materials, namely copper, silver, Constantan, and silicon with a solid to fluid thermal conductivity ratio covering a range of 36.91.2222, at different laminar Reynolds numbers ranging from 220 to 2,000, under a broad rotational rate range of 0 to 1,000 RPM (Ekman number=infinity--3.31x10--5), nozzle-to-plate spacing (beta=0.25.5.0), dimensionless disk thicknesses (b/dn=0.167.1.67), confinement ratio (rp/rd=0.2.0.75), and Prandtl number (1.29.124.44) using NH3, H2O, FC.77 and MIL.7808 as working fluids. An engineering correlation relating the average Nusselt number with the above parameters was developed for the prediction of system performance. The simulation results compared reasonably well with previous experimental studies. The second major contribution of this research was the development of a three dimensional CMP model that shows the temperature distributions profile as an index of energy dissipation at the wafer and pad surfaces, and slurry interface. A finite element analysis was done with FIDAP 8.7.4 package under the influence of physical parameters, such as slurry flow rates (0.5.1.42 cc/s), polishing pressures (17.24.41.37 kPa), pad

  9. Electric field induced deformation of sessile drops

    NASA Astrophysics Data System (ADS)

    Corson, Lindsey; Tsakonas, Costas; Duffy, Brian; Mottram, Nigel; Brown, Carl; Wilson, Stephen

    2014-11-01

    The ability to control the shape of a drop with the application of an electric field has been exploited for many technological applications including measuring surface tension, producing an optical display device, and optimising the optical properties of microlenses. In this work we consider, both theoretically and experimentally, the deformation of pinned sessile drops with contact angles close to either 0° or 90° resting on the lower substrate inside a parallel plate capacitor due to an A.C. electric field. Using both asymptotic and numerical approaches we obtain predictive equations for the static and dynamic drop shape deformations as functions of the key experimental parameters (drop size, capacitor plate separation, electric field magnitude and contact angle). The asymptotic results agree well with the experimental results for a range of liquids. We gratefully acknowledge the financial support of EPSRC via research Grants EP/J009865 and EP/J009873.

  10. 49 CFR 178.965 - Drop test.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... tests are to be performed with the solid or liquid to be transported or with a non-hazardous material... Large Packaging design types and performed periodically as specified in § 178.955(e) of this subpart. (b... § 178.960(d). (d) Test method. (1) Samples of all Large Packaging design types must be dropped onto...

  11. 49 CFR 178.965 - Drop test.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... tests are to be performed with the solid or liquid to be transported or with a non-hazardous material... Large Packaging design types and performed periodically as specified in § 178.955(e) of this subpart. (b... § 178.960(d). (d) Test method. (1) Samples of all Large Packaging design types must be dropped onto...

  12. 49 CFR 178.603 - Drop test.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... specific gravity of 0.95 for testing at −18 °C (0 °F) or lower are considered acceptable test liquids. Test... specific gravity not exceeding 1.2, drop height must be determined according to packing group, as follows...: 0.8 m (2.6 feet). (ii) Where the materials to be transported have a specific gravity exceeding...

  13. Rotating bubble membrane radiator

    DOEpatents

    Webb, Brent J.; Coomes, Edmund P.

    1988-12-06

    A heat radiator useful for expelling waste heat from a power generating system aboard a space vehicle is disclosed. Liquid to be cooled is passed to the interior of a rotating bubble membrane radiator, where it is sprayed into the interior of the bubble. Liquid impacting upon the interior surface of the bubble is cooled and the heat radiated from the outer surface of the membrane. Cooled liquid is collected by the action of centrifical force about the equator of the rotating membrane and returned to the power system. Details regarding a complete space power system employing the radiator are given.

  14. Interaction of Drops on a Soft Substrate

    NASA Astrophysics Data System (ADS)

    Lubbers, Luuk A.; Weijs, Joost H.; Das, Siddhartha; Botto, Lorenzo; Andreotti, Bruno; Snoeijer, Jacco H.

    2013-11-01

    A sessile drop can elastically deform a substrate by the action of capillary forces. The typical size of the deformation is given by the ratio of surface tension and the elastic modulus, γ / E , which can reach up to 10-100 microns for soft elastomers. In this talk we theoretically show that the contact angles of drops on such a surface exhibit two transitions when increasing γ / E : (i) the microsocopic geometry of the contact line first develops a Neumann-like cusp when γ / E is of the order of few nanometers, (ii) the macroscopic angle of the drop is altered only when γ / E reaches the size of the drop. Using the same framework we then show that two neighboring drops exhibit an effective interaction, mediated by the deformation of the elastic medium. This is in analogy to the well-known Cheerios effect, where small particles at a liquid interface attract eachother due to the meniscus deformations. Here we reveal the nature of drop-drop interactions on a soft substrate by combining numerical and analytical calculations.

  15. Vibration-induced drop atomization and bursting

    NASA Astrophysics Data System (ADS)

    James, A. J.; Vukasinovic, B.; Smith, Marc K.; Glezer, A.

    2003-02-01

    A liquid drop placed on a vibrating diaphragm will burst into a fine spray of smaller secondary droplets if it is driven at the proper frequency and amplitude. The process begins when capillary waves appear on the free surface of the drop and then grow in amplitude and complexity as the acceleration amplitude of the diaphragm is slowly increased from zero. When the acceleration of the diaphragm rises above a well-defined critical value, small secondary droplets begin to be ejected from the free-surface wave crests. Then, quite suddenly, the entire volume of the drop is ejected from the vibrating diaphragm in the form of a spray. This event is the result of an interaction between the fluid dynamical process of droplet ejection and the vibrational dynamics of the diaphragm. During droplet ejection, the effective mass of the drop diaphragm system decreases and the resonance frequency of the system increases. If the initial forcing frequency is above the resonance frequency of the system, droplet ejection causes the system to move closer to resonance, which in turn causes more vigorous vibration and faster droplet ejection. This ultimately leads to drop bursting. In this paper, the basic phenomenon of vibration-induced drop atomization and drop bursting will be introduced, demonstrated, and characterized. Experimental results and a simple mathematical model of the process will be presented and used to explain the basic physics of the system.

  16. Instabilities of volatile films and drops

    NASA Astrophysics Data System (ADS)

    Murisic, Nebojsa

    2008-12-01

    We report on instabilities during spreading of volatile liquids, with emphasis on the novel instability observed when isopropyl alcohol (IPA) is deposited on a monocrystalline silicon (Si) wafer. This instability is characterized by emission of drops ahead of the expanding front, with each drop followed by smaller, satellite droplets, forming the structures which we nickname "octopi" due to their appearance. A less volatile liquid, or a substrate of larger heat conductivity, suppress this instability. In addition, we examine the spreading of drops of water (DIW)-IPA mixtures on both Si wafers and plain glass slides, and describe the variety of contact line instabilities which appear. We find that the decrease of IPA concentration in mixtures leads to transition from "octopi" to mushroom-like instabilities. Through manipulation of our experimental set up, we also find that the mechanism responsible for these instabilities appears to be mostly insensitive to both the external application of convection to the gas phase, and the doping of the gas phase with vapor in order to create the saturated environment. In order to better understand the "octopi" instability, we develop a theoretical model for evaporation of a pure liquid drop on a thermally conductive solid substrate. This model includes all relevant physical effects, including evaporation, thermal conductivity in both liquid and solid, (thermocapillary) Marangoni effect, vapor recoil, disjoining pressure, and gravity. The crucial ingredient in this problem is the evaporation model, since it influences both the motion of the drop contact line, and the temperature profiles along the liquid-solid and liquid-gas interfaces. We consider two evaporation models: the equilibrium "lens" model and the non-equilibrium one-sided (NEOS) model. Along with the assumption of equilibrium at the liquid-gas interface, the "lens" model also assumes that evaporation proceeds in a (vapor) diffusion-limited regime, therefore bringing

  17. Direct observation of drops on slippery lubricant-infused surfaces.

    PubMed

    Schellenberger, Frank; Xie, Jing; Encinas, Noemí; Hardy, Alexandre; Klapper, Markus; Papadopoulos, Periklis; Butt, Hans-Jürgen; Vollmer, Doris

    2015-10-14

    For a liquid droplet to slide down a solid planar surface, the surface usually has to be tilted above a critical angle of approximately 10°. By contrast, droplets of nearly any liquid "slip" on lubricant-infused textured surfaces - so termed slippery surfaces - when tilted by only a few degrees. The mechanism of how the lubricant alters the static and dynamic properties of the drop remains elusive because the drop-lubricant interface is hidden. Here, we image the shape of drops on lubricant-infused surfaces by laser scanning confocal microscopy. The contact angle of the drop-lubricant interface with the substrate exceeds 140°, although macroscopic contour images suggest angles as low as 60°. Confocal microscopy of moving drops reveals fundamentally different processes at the front and rear. Drops recede via discrete depinning events from surface protrusions at a defined receding contact angle, whereas the advancing contact angle is 180°. Drops slide easily, as the apparent contact angles with the substrate are high and the drop-lubricant interfacial tension is typically lower than the drop-air interfacial tension. Slippery surfaces resemble superhydrophobic surfaces with two main differences: drops on a slippery surface are surrounded by a wetting ridge of adjustable height and the air underneath the drop in the case of a superhydrophobic surface is replaced by lubricant in the case of a slippery surface.

  18. Elasto-electro-capillarity: drop equilibrium on a charged, elastic solid.

    PubMed

    Jing, Haoyuan; Sinha, Shayandev; Das, Siddhartha

    2017-01-18

    We present a study here on elasto-electro-capillarity - for the first time, the matter of drop equilibrium on a soft (elastic and incompressible) and charged solid has been studied. Charges on the elastic solid induce an electric double layer or EDL at the solid-drop interface. Our analysis accounts for the electrostatic wetting contribution of the EDL in the overall energy balance. Our results reveal that (a) with an increase in "softness", the equilibrium solid-liquid contact angles show transition from the EDL-modified Young's law (rigid limit) to the EDL-modified Neumann's law (soft limit); (b) the EDL effects invariably enhance solid deformation and lower the apparent contact angle made by the drop with the undeformed solid; (c) the solid contact angles increase and the cusp made by the deformed solid undergoes enhanced rotation due to the EDL effects; and (d) the EDL effects are more prominent for the case where the solid-vapor surface energy exceeds the solid-liquid surface energy. The fact that the EDL effects invariably decrease the overall wetting energy of the system, thereby supporting a larger increase in the elastic energy associated with a larger solid deformation, explains all these findings and establishes that surface charges enhance the "softness" of a soft surface in the context of elastocapillarity.

  19. Blazed vector grating liquid crystal cells with photocrosslinkable polymeric alignment films fabricated by one-step polarizer rotation method

    NASA Astrophysics Data System (ADS)

    Kawai, Kotaro; Kuzuwata, Mitsuru; Sasaki, Tomoyuki; Noda, Kohei; Kawatsuki, Nobuhiro; Ono, Hiroshi

    2014-12-01

    Blazed vector grating liquid crystal (LC) cells, in which the directors of low-molar-mass LCs are antisymmetrically distributed, were fabricated by one-step exposure of an empty glass cell inner-coated with a photocrosslinkable polymer LC (PCLC) to UV light. By adopting a LC cell structure, twisted nematic (TN) and homogeneous (HOMO) alignments were obtained in the blazed vector grating LC cells. Moreover, the diffraction efficiency of the blazed vector grating LC cells was greatly improved by increasing the thickness of the device in comparison with that of a blazed vector grating with a thin film structure obtained in our previous study. In addition, the diffraction efficiency and polarization states of ±1st-order diffracted beams from the resultant blazed vector grating LC cells were controlled by designing a blazed pattern in the alignment films, and these diffraction properties were well explained on the basis of Jones calculus and the elastic continuum theory of nematic LCs.

  20. Bursting drops in solid dielectrics caused by high voltages.

    PubMed

    Wang, Qiming; Suo, Zhigang; Zhao, Xuanhe

    2012-01-01

    Fluid drops tend to be spheres--a shape that minimizes surface energy. In thunderstorm clouds, drops can become unstable and emit thin jets when charged beyond certain limits. The instability of electrified drops in gases and liquids has been widely studied and used in applications including ink-jet printing, electrospinning nanofibers, microfluidics and electrospray ionization. Here we report a different scenario: drops in solids become unstable and burst under sufficiently high electric fields. We find the instability of drops in solids morphologically resembles that in liquids, but the critical electric field for the instability follows a different scaling due to elasticity of solids. Our observations and theoretical models not only advance the fundamental understanding of electrified drops, but also suggest a new failure mechanism of high energy density dielectric polymers, which have diverse applications ranging from capacitors for power grids and electric vehicles to muscle-like transducers for soft robots and energy harvesting.

  1. Bursting Drops in Solid Dielectrics Caused by High Voltages

    PubMed Central

    Wang, Qiming; Suo, Zhigang

    2013-01-01

    Drops in fluids tend to be spheres—a shape that minimizes surface energy. In thunderstorm clouds, drops can become unstable and emit thin jets when charged beyond certain limits. The instability of electrified drops in gases and liquids has been widely studied and used in applications including ink-jet printing, electrospinning nano-fibers, microfluidics and electrospray ionization. Here we report a different scenario: drops in solids become unstable and burst under sufficiently high electric fields. We find the instability of drops in solids morphologically resembles that in liquids, but the critical electric field for the instability follows a different scaling due to elasticity of solids. Our observations and theoretical models not only advance the fundamental understanding of electrified drops but also suggest a new failure mechanism of high-energy-density dielectric polymers, which have diverse applications ranging from capacitors for power grids and electric vehicles to muscle-like transducers for soft robots and energy harvesting. PMID:23093194

  2. Viscosity Measurement via Drop Coalescence: A Space Station Experiment

    NASA Technical Reports Server (NTRS)

    Antar, Basil; Ethridge, Edwin C.

    2010-01-01

    The concept of using low gravity experimental data together with CFD simulations for measuring the viscosity of highly viscous liquids was recently validated on onboard the International Space Station (ISS). A series of microgravity tests were conducted for this purpose on the ISS in July, 2004 and in May of 2005. In these experiments two liquid drops were brought manually together until they touched and were allowed to coalesce under the action of the capillary force alone. The coalescence process was recorded photographically from which the contact radius speed of the merging drops was measured. The liquid viscosity was determined by fitting the measured data with accurate numerical simulation of the coalescence process. Several liquids were tested and for each liquid several drop diameters were employed. Experimental and numerical results will be presented in which the viscosity of several highly viscous liquids were determined using this technique.

  3. Viscosity Measurement using Drop Coalescence in Microgravity

    NASA Technical Reports Server (NTRS)

    Antar, Basil N.; Ethridge, Edwin; Maxwell, Daniel

    1999-01-01

    We present in here details of a new method, using drop coalescence, for application in microgravity environment for determining the viscosity of highly viscous undercooled liquids. The method has the advantage of eliminating heterogeneous nucleation at container walls caused by crystallization of undercooled liquids during processing. Also, due to the rapidity of the measurement, homogeneous nucleation would be avoided. The technique relies on both a highly accurate solution to the Navier-Stokes equations as well as on data gathered from experiments conducted in near zero gravity environment. The liquid viscosity is determined by allowing the computed free surface shape relaxation time to be adjusted in response to the measured free surface velocity of two coalescing drops. Results are presented from two validation experiments of the method which were conducted recently on board the NASA KC-135 aircraft. In these tests the viscosity of a highly viscous liquid, such as glycerine at different temperatures, was determined to reasonable accuracy using the liquid coalescence method. The experiments measured the free surface velocity of two glycerine drops coalescing under the action of surface tension alone in low gravity environment using high speed photography. The free surface velocity was then compared with the computed values obtained from different viscosity values. The results of these experiments were found to agree reasonably well with the calculated values.

  4. Microjetting from wave focusing on oscillating drops

    NASA Astrophysics Data System (ADS)

    Thoroddsen, S. T.; Etoh, T. G.; Takehara, K.

    2007-05-01

    We present experimental observations of microjetting from an oscillating drop. The jet is generated by the focusing of axisymmetric capillary waves that overturn and collide at an apex of the drop. These jets are up to two orders of magnitude smaller than the original drops. We present two widely different configurations that produce such microjets. The first occurs on a satellite drop, produced by the pinch-off of a water drop from a vertical nozzle. The large oscillations following the contraction of the satellite bridge focus waves at the bottom, sending out a 30μm jet at 9.9m/s. The second jet arises when a water drop, containing surfactants, falls onto and passes through a hemispherical soap film. The gentle deformation of the drop creates a surface wave that focuses at its top, shooting out a tiny jet and entrapping a small bubble inside the drop. This jet is 16±5μm in diameter and emerges at 6.3m/s. In this configuration, the soap film wraps around the drop and acts as a sensor of the air flow, revealing that the liquid jet is preceded by a localized faster-moving air jet. The jetting in both configurations is quite robust and occurs even for slightly asymmetric conditions. These microjets appear for much lower values of the Reynolds and Weber numbers than previously observed, suggesting that free-surface jetting is not limited to the inviscid capillary-inertial regime, which has been the focus of much of the theoretical work.

  5. Drop Tower Workshop

    NASA Technical Reports Server (NTRS)

    Urban, David

    2013-01-01

    Ground based microgravity facilities are an important proving ground for space experiments, ground-based research and space hardware risk mitigation. An overview of existing platforms will be discussed with an emphasis on drop tower capabilities. The potential for extension to partial gravity conditions will be discussed. Input will be solicited from attendees for their potential to use drop towers in the future and the need for enhanced capabilities (e.g. partial gravity)

  6. Large Eddy Simulation of jets laden with evaporating drops

    NASA Technical Reports Server (NTRS)

    Leboissetier, A.; Okong'o, N.; Bellan, J.

    2004-01-01

    LES of a circular jet laden with evaporating liquid drops are conducted to assess computational-drop modeling and three different SGS-flux models: the Scale Similarity model (SSC), using a constant coefficient calibrated on a temporal mixing layer DNS database, and dynamic-coefficient Gradient and Smagorinsky models.

  7. Reducing the contact time of a bouncing drop.

    PubMed

    Bird, James C; Dhiman, Rajeev; Kwon, Hyuk-Min; Varanasi, Kripa K

    2013-11-21

    Surfaces designed so that drops do not adhere to them but instead bounce off have received substantial attention because of their ability to stay dry, self-clean and resist icing. A drop striking a non-wetting surface of this type will spread out to a maximum diameter and then recoil to such an extent that it completely rebounds and leaves the solid material. The amount of time that the drop is in contact with the solid--the 'contact time'--depends on the inertia and capillarity of the drop, internal dissipation and surface-liquid interactions. And because contact time controls the extent to which mass, momentum and energy are exchanged between drop and surface, it is often advantageous to minimize it. The conventional approach has been to minimize surface-liquid interactions that can lead to contact line pinning; but even in the absence of any surface interactions, drop hydrodynamics imposes a minimum contact time that was conventionally assumed to be attained with axisymmetrically spreading and recoiling drops. Here we demonstrate that it is possible to reduce the contact time below this theoretical limit by using superhydrophobic surfaces with a morphology that redistributes the liquid mass and thereby alters the drop hydrodynamics. We show theoretically and experimentally that this approach allows us to reduce the overall contact time between a bouncing drop and a surface below what was previously thought possible.

  8. Drop dynamics on a stretched viscoelastic filament: An experimental study

    NASA Astrophysics Data System (ADS)

    Peixinho, Jorge; Renoult, Marie-Charlotte; Crumeyrolle, Olivier; Mutabazi, Innocent

    2016-11-01

    Capillary pressure can destabilize a thin liquid filament during breakup into a succession of drops. Besides, the addition of a linear, high molecular weight, flexible and soluble polymer is enough to modify the morphology of this instability. In the time period preceding the breakup, the development of beads-on-a-string structures where drops are connected by thin threads is monitored. The drops dynamics involve drop formation, drop migration and drop coalescence. Experiments using a high-speed camera on stretched bridges of viscoelastic polymeric solutions were conducted for a range of viscosities and polymer concentrations. The rheological properties of the solutions are also quantified through conventional shear rheology and normal stress difference. The overall goal of this experimental investigation is to gain more insight into the formation and time evolution of the drops. The project BIOENGINE is co-financed by the European Union with the European regional development fund and by the Normandie Regional Council.

  9. Delayed Frost Growth on Jumping-Drop Superhydrophobic Surfaces

    SciTech Connect

    Boreyko, Jonathan B; Collier, Pat

    2013-01-01

    Self-propelled jumping drops are continuously removed from a condensing superhydrophobic surface to enable a micrometric steady-state drop size. Here, we report that subcooled condensate on a chilled superhydrophobic surface are able to repeatedly jump off the surface before heterogeneous ice nucleation occurs. Frost still forms on the superhydrophobic surface due to ice nucleation at neighboring edge defects, which eventually spreads over the entire surface via an inter-drop frost wave. The growth of this inter-drop frost front is shown to be up to three times slower on the superhydrophobic surface compared to a control hydrophobic surface, due to the jumping-drop effect dynamically minimizing the average drop size and surface coverage of the condensate. A simple scaling model is developed to relate the success and speed of inter-drop ice bridging to the drop size distribution. While other reports of condensation frosting on superhydrophobic surfaces have focused exclusively on liquid-solid ice nucleation for isolated drops, these findings reveal that the growth of frost is an inter-drop phenomenon that is strongly coupled to the wettability and drop size distribution of the surface. A jumping-drop superhydrophobic condenser was found to be superior to a conventional dropwise condenser in two respects: preventing heterogeneous ice nucleation by continuously removing subcooled condensate, and delaying frost growth by minimizing the success of interdrop ice bridge formation.

  10. Rain Drop Charge Sensor

    NASA Astrophysics Data System (ADS)

    S, Sreekanth T.

    begin{center} Large Large Rain Drop Charge Sensor Sreekanth T S*, Suby Symon*, G. Mohan Kumar (1) , S. Murali Das (2) *Atmospheric Sciences Division, Centre for Earth Science Studies, Thiruvananthapuram 695011 (1) D-330, Swathi Nagar, West Fort, Thiruvananthapuram 695023 (2) Kavyam, Manacaud, Thiruvananthapuram 695009 begin{center} ABSTRACT To study the inter-relations with precipitation electricity and precipitation microphysical parameters a rain drop charge sensor was designed and developed at CESS Electronics & Instrumentation Laboratory. Simultaneous measurement of electric charge and fall speed of rain drops could be done using this charge sensor. A cylindrical metal tube (sensor tube) of 30 cm length is placed inside another thick metal cover opened at top and bottom for electromagnetic shielding. Mouth of the sensor tube is exposed and bottom part is covered with metal net in the shielding cover. The instrument is designed in such a way that rain drops can pass only through unhindered inside the sensor tube. When electrically charged rain drops pass through the sensor tube, it is charged to the same magnitude of drop charge but with opposite polarity. The sensor tube is electrically connected the inverted input of a current to voltage converter operational amplifier using op-amp AD549. Since the sensor is electrically connected to the virtual ground of the op-amp, the charge flows to the ground and the generated current is converted to amplified voltage. This output voltage is recorded using a high frequency (1kHz) voltage recorder. From the recorded pulse, charge magnitude, polarity and fall speed of rain drop are calculated. From the fall speed drop diameter also can be calculated. The prototype is now under test running at CESS campus. As the magnitude of charge in rain drops is an indication of accumulated charge in clouds in lightning, this instrument has potential application in the field of risk and disaster management. By knowing the charge

  11. Ionic liquids intercalated in montmorillonite as the sorptive phase for the extraction of low-polarity organic compounds from water by rotating-disk sorptive extraction.

    PubMed

    Fiscal-Ladino, Jhon A; Obando-Ceballos, Mónica; Rosero-Moreano, Milton; Montaño, Diego F; Cardona, Wilson; Giraldo, Luis F; Richter, Pablo

    2017-02-08

    Montmorillonite (MMT) clays were modified by the intercalation into their galleries of ionic liquids (IL) based on imidazolium quaternary ammonium salts. This new eco-materials exhibited good features for use as a sorptive phase in the extraction of low-polarity analytes from aqueous samples. Spectroscopic analyses of the modified clays were conducted and revealed an increase in the basal spacing and a shifting of the reflection plane towards lower values as a consequence of the effective intercalation of organic cations into the MMT structure. The novel sorbent developed herein was assayed as the sorptive phase in rotating-disk sorptive extraction (RDSE), using polychlorinated biphenyls (PCBs), representative of low-polarity pollutants, as model analytes. The final determination was made by gas chromatography with electron capture detection. Among the synthetized sorptive phases, the selected system for analytical purposes consisted of MMT modified with the 1-hexadecyl-3-methylimidazolium bromide (HDMIM-Br) IL. Satisfactory analytical features were achieved using a sample volume of 5 mL: the relative recoveries from a wastewater sample were higher than 80%, the detection limits were between 3 ng L(-1) and 43 ng L(-1), the precision (within-run precision) expressed as the relative standard deviation ranged from 2% to 24%, and the enrichment factors ranged between 18 and 28. Using RDSE, the extraction efficiency achieved for the selected MMT-HDMIM-Br phase was compared with other commercial solid phases/supports, such as polypropylene, polypropylene with 1-octanol (as a supported liquid membrane), octadecyl (C18) and octyl (C8), and showed the highest response for all the studied analytes. Under the optimized extraction conditions, this new device was applied in the analysis of the influent of a wastewater treatment plant in Santiago (Chile), demonstrating its applicability through the good recoveries and precision achieved with real samples.

  12. Modeling evaporation of sessile drops with moving contact lines.

    PubMed

    Murisic, N; Kondic, L

    2008-12-01

    We consider evaporation of pure liquid drops on a thermally conductive substrate. Two commonly used evaporative models are considered: one that concentrates on the liquid phase in determining the evaporative flux and the other one that centers on the gas-vapor phase. A single governing equation for the evolution of drop thickness, including both models, is developed. We show how the derived governing equation can be used to predict which evaporation model is appropriate for different considered experimental conditions.

  13. Quantitative testing of robustness on superomniphobic surfaces by drop impact.

    PubMed

    Nguyen, Thi Phuong Nhung; Brunet, Philippe; Coffinier, Yannick; Boukherroub, Rabah

    2010-12-07

    The quality of a liquid-repellent surface is quantified by both the apparent contact angle θ(0) that a sessile drop adopts on it and the value of the liquid pressure threshold the surface can withstand without being impaled by the liquid, hence maintaining a low-friction condition. We designed surfaces covered with nanowires obtained by the vapor-liquid-solid (VLS) growth technique that are able to repel most of the existing nonpolar liquids including those with very low surface tension as well as many polar liquids with moderate to high surface tension. These superomniphobic surfaces exhibit apparent contact angles ranging from 125 to 160° depending on the liquid. We tested the robustness of the surfaces against impalement by carrying out drop impact experiments. Our results show how this robustness depends on Young's contact angle θ(0) related to the surface tension of the liquid and that the orientational growth of nanowires is a favorable factor for robustness.

  14. Dielectrophoresis of a surfactant-laden viscous drop

    NASA Astrophysics Data System (ADS)

    Mandal, Shubhadeep; Bandopadhyay, Aditya; Chakraborty, Suman

    2016-06-01

    The dielectrophoresis of a surfactant-laden viscous drop in the presence of non-uniform DC electric field is investigated analytically and numerically. Considering the presence of bulk-insoluble surfactants at the drop interface, we first perform asymptotic solution for both low and high surface Péclet numbers, where the surface Péclet number signifies the strength of surface convection of surfactants as compared to the diffusion at the drop interface. Neglecting fluid inertia and interfacial charge convection effects, we obtain explicit expression for dielectrophoretic drop velocity for low and high Péclet numbers by assuming small deviation of drop shape from sphericity and small deviation of surfactant concentration from the equilibrium uniform distribution. We then depict a numerical solution, assuming spherical drop, for arbitrary values of Péclet number. Our analyses demonstrate that the asymptotic solution shows excellent agreement with the numerical solution in the limiting conditions of low and high Péclet numbers. The present analysis shows that the flow-induced redistribution of the surfactants at the drop interface generates Marangoni stress, owing to the influence of the surfactant distribution on the local interfacial tension, at the drop interface and significantly alters the drop velocity at steady state. For a perfectly conducting/dielectric drop suspended in perfectly dielectric medium, Marangoni stress always retards the dielectrophoretic velocity of the drop as compared with a surfactant-free drop. For a leaky dielectric drop suspended in another leaky dielectric medium, in the low Péclet number limit, depending on the electrical conductivity and permittivity of both the liquids, the Marangoni stress may aid or retard the dielectrophoretic velocity of the drop. The Marangoni stress also has the ability to move the drop in the opposite direction as compared with a surfactant-free drop. This non-intuitive reverse motion of the drop is

  15. Millikan "oil drop" stabilized by growth.

    PubMed

    Sun, L K; Gertler, A W; Reiss, H

    1979-01-26

    A diffusion cloud chamber has been used to qualitatively study some dynamic properties of liquid drops by suspending them in an electric field at the plane of saturation (p/ps = 1, where p is the actual partial pressure of the vapor at a given elevation and ps is the equilibrium pressure at that temperature characteristic of that elevation). By varying the strength of the electric field, it is possible to change the size of the suspended droplets and even, if desired, to isolate a single drop.

  16. Electrohydrodynamic removal of particles from drop surfaces

    NASA Astrophysics Data System (ADS)

    Nudurupati, S.; Janjua, M.; Singh, P.; Aubry, N.

    2009-07-01

    A uniform electric field is used for cleaning drops of the particles they often carry on their surface. In a first step, particles migrate to either the drop’s poles or equator. This is due to the presence of an electrostatic force for which an analytical expression is derived. In a second step, particles concentrated near the poles are released into the ambient liquid via tip streaming, and those near the equator are removed by stretching the drop and breaking it into several droplets. In the latter case, particles are all concentrated in a small middle daughter droplet.

  17. Headspace-single drop microextraction (HS-SDME) in combination with high-performance liquid chromatography (HPLC) to evaluate the content of alkyl- and methoxy-phenolic compounds in biomass smoke.

    PubMed

    Rincón, Arturo A; Pino, Verónica; Ayala, Juan H; Afonso, Ana M

    2011-09-15

    The content of ten phenolic compounds present in four different biomass smoke materials: rock rose (Cistus monpelienisis), prickly pear (Opuntia ficus indica), pine needles (Pinus canariensis), and almonds skin (Prunus dulcis), have been evaluated. The sampling method mainly consisted of a trap alkaline solution to solubilize the phenols, and was optimized by an experimental design. Average sampling efficiencies of 78.1% and an average precision value of 10.6% (as relative standard deviation, RSD), were obtained for the selected group of phenols. The trapped phenolates were further analyzed by a headspace-single drop microextraction (HS-SDME) procedure, in combination with high-performance liquid chromatography (HPLC) with UV detection. The optimum variables for the HS-SDME method were: 1-decanol as extractant solvent, 3.5 μL of microdrop volume, 2 mL of sample volume, a pH value of 2, saturation of NaCl, an extraction temperature of 60°C, and an extraction time of 25 min. The optimized HS-SDME method presented detection limits ranging from 0.35 to 5.8 μg mL(-1), RSD values ranging from 0.7 to 7.4%, and an average relative recovery (RR) of 99.8% and an average standard deviation of 5.2. The average content of phenolic compounds in the biomass materials studied were 70, 161, 206 and 252 mg kg(-1) of biomass for prickly pear, almonds skin, rock rose, and pine needles, respectively. The main components of the smokes were vanillin, phenol and methoxyphenols, in all smoking materials studied.

  18. Nanofluid Drop Evaporation: Experiment, Theory, and Modeling

    NASA Astrophysics Data System (ADS)

    Gerken, William James

    Nanofluids, stable colloidal suspensions of nanoparticles in a base fluid, have potential applications in the heat transfer, combustion and propulsion, manufacturing, and medical fields. Experiments were conducted to determine the evaporation rate of room temperature, millimeter-sized pendant drops of ethanol laden with varying amounts (0-3% by weight) of 40-60 nm aluminum nanoparticles (nAl). Time-resolved high-resolution drop images were collected for the determination of early-time evaporation rate (D2/D 02 > 0.75), shown to exhibit D-square law behavior, and surface tension. Results show an asymptotic decrease in pendant drop evaporation rate with increasing nAl loading. The evaporation rate decreases by approximately 15% at around 1% to 3% nAl loading relative to the evaporation rate of pure ethanol. Surface tension was observed to be unaffected by nAl loading up to 3% by weight. A model was developed to describe the evaporation of the nanofluid pendant drops based on D-square law analysis for the gas domain and a description of the reduction in liquid fraction available for evaporation due to nanoparticle agglomerate packing near the evaporating drop surface. Model predictions are in relatively good agreement with experiment, within a few percent of measured nanofluid pendant drop evaporation rate. The evaporation of pinned nanofluid sessile drops was also considered via modeling. It was found that the same mechanism for nanofluid evaporation rate reduction used to explain pendant drops could be used for sessile drops. That mechanism is a reduction in evaporation rate due to a reduction in available ethanol for evaporation at the drop surface caused by the packing of nanoparticle agglomerates near the drop surface. Comparisons of the present modeling predictions with sessile drop evaporation rate measurements reported for nAl/ethanol nanofluids by Sefiane and Bennacer [11] are in fairly good agreement. Portions of this abstract previously appeared as: W. J

  19. Coalescence and noncoalescence of sessile drops: impact of surface forces.

    PubMed

    Karpitschka, Stefan; Hanske, Christoph; Fery, Andreas; Riegler, Hans

    2014-06-17

    Due to capillarity, sessile droplets of identical liquids will instantaneously fuse when they come in contact at their three-phase lines. However, with drops of different, completely miscible liquids, instantaneous coalescence can be suppressed. Instead, the drops remain in a state of noncoalescence for some time, with the two drop bodies connected only by a thin neck. The reason for this noncoalescence is the surface tension difference, Δγ, between the liquids. If Δγ is sufficiently large, then it induces a sufficiently strong Marangoni flow, which keeps the main drop bodies temporarily separated. Studies with spreading drops have revealed that the boundary between instantaneous coalescence and noncoalescence is sharp (Karpitschka, S.; Riegler, H. J. Fluid. Mech. 2014, 743, R1). The boundary is a function of two parameters only: Δγ and Θ(a), the arithmetic mean of the contact angles in the moment of drop-drop contact. It appears plausible that surface forces (the disjoining pressure) could also influence the coalescence behavior. However, in experiments with spreading drops, surface forces always promote coalescence and their influence might be obscured. Therefore, we present here coalescence experiments with partially wetting liquids and compare the results to the spreading case. We adjust different equilibrium contact angles (i.e., different surface forces) with different substrate surface coatings. As for spreading drops, we observe a sharp boundary between regimes of coalescence and noncoalescence. The boundary follows the same power law relation for both partially and completely wetting cases. Therefore, we conclude that surface forces have no significant, explicit influence on the coalescence behavior of sessile drops from different miscible liquids.

  20. An investigation of the structure and bond rotational potential of some fluorinated ethanes by NMR spectroscopy of solutions in nematic liquid crystalline solvents

    NASA Astrophysics Data System (ADS)

    Emsley, J. W.; Longeri, M.; Merlet, D.; Pileio, G.; Suryaprakash, N.

    2006-06-01

    NMR spectra of 1,2-dibromo-1,1-difluoroethane and 1-bromo-2-iodo-tetrafluoroethane dissolved in nematic liquid crystalline solvents have been analysed to yield the magnitudes and signs of the scalar couplings, Jij, and total anisotropic couplings, Tij, between all the 1H, 19F, and 13C nuclei, except for those between two 13C nuclei. The values obtained for Tij in principle contain a contribution from Jijaniso, the component along the static applied magnetic field of the anisotropic part of the electron-mediated spin-spin coupling. Neglecting this contribution allows partially averaged dipolar couplings, Dij, to be extracted from the Tij, and these were used to determine the structure, orientational order, and the conformational distribution generated by rotation about the C-C bond. The values obtained are compared with the results of calculations by ab initio and density functional methods. The differences found are no greater than those obtained for similar compounds which do not contain fluorine, so that there is no definitive evidence for significant contributions from JCFaniso or JFFaniso in the two compounds studied.

  1. A rotating disk apparatus for assessing the biodegradation of polycyclic aromatic hydrocarbons transferring from a non-aqueous phase liquid to solutions of surfactant Brij 35.

    PubMed

    Bernardez, Letícia A

    2009-04-01

    A rotating disk apparatus was used to investigate the biodegradation of PAHs from non-aqueous phase liquids to solutions of Brij 35. The mass transfer of PAHs in absence of surfactant solution was not large enough to replenish the degraded PAHs. The addition of surfactant resulted in an overall enhancement of biodegradation rates compared to that observed in pure aqueous solution. This is because surfactant partition significant amount of PAHs into the bulk phase, where uptake occurs but the supply of PAHs to the aqueous phase through micellar solubilization at latter period limited biodegradation rates. It was demonstrated the relationship between biodegradation rate and surfactant dose and the mechanisms controlling the mass transfer of PAH from NAPLs. The satisfactory comparison of the experimental data with the predictions of a model, which parameters were determined from independent solubilization and dissolution experiments and based on the main assumption that the solutes must be present in the true aqueous phase to be degraded, allows us to conclude the absence of direct uptake of PAHs by bacteria.

  2. Microemulsions with surfactant TX100, cyclohexane, and an ionic liquid investigated by conductance, DLS, FTIR measurements, and study of solvent and rotational relaxation within this microemulsion.

    PubMed

    Pramanik, Rajib; Sarkar, Souravi; Ghatak, Chiranjib; Rao, Vishal Govind; Setua, Palash; Sarkar, Nilmoni

    2010-06-10

    Room-temperature ionic liquids (RTILs), N,N,N-trimethyl-N-propyl ammonium bis(trifluoromethanesulfonyl) imide ([N(3111)][Tf(2)N]), were substituted for polar water and formed nonaqueous microemulsions with cyclohexane by the aid of nonionic surfactant TX-100. The phase behavior of the ternary system was investigated, and microregions of [N(3111)][Tf(2)N]-in-cyclohexane (IL/O), bicontinuous, and cyclohexane-in-[N(3111)][Tf(2)N] (O/IL) were identified by traditional electrical conductivity measurements. Dynamic light scattering (DLS) revealed the formation of the IL microemulsions. The FTIR study of O-H stretching band of TX100 also supports this finding. The dynamics of solvent and rotational relaxation have been investigated in [N(3111)][Tf(2)N]/TX100/cyclohexane microemulsions using steady-state and time-resolved fluorescence spectroscopy as a tool and coumarin 480 (C-480) as a fluorescence probe. The size of the microemulsions increases with gradual addition of [N(3111)][Tf(2)N], which revealed from DLS measurement. This leads to the faster collective motions of cation and anions of [N(3111)][Tf(2)N], which contributes to faster solvent relaxation in microemulsions.

  3. Effects of 1-butyl-3-methyl imidazolium tetrafluoroborate ionic liquid on Triton X-100 aqueous micelles: solvent and rotational relaxation studies.

    PubMed

    Pramanik, Rajib; Sarkar, Souravi; Ghatak, Chiranjib; Rao, Vishal Govind; Mandal, Sarthak; Sarkar, Nilmoni

    2011-06-02

    The effect of added room-temperature ionic liquids on the nature of water molecules in the palisade layer of a Triton X-100 (TX-100) micelle has been investigated using solvation and rotational relaxation studies of coumarin 153 in the presence of different wt % of [bmim][BF(4)] and thus to understand the changes in micellar palisade layer, especially the entrapped water structures in the palisade layer. It has been observed that in the presence of added [bmim][BF(4)] the solvation dynamics becomes faster. It has previously been demonstrated (Behera et al. J. Chem. Phys.2007, 127, 184501) that in the present micellar systems, in the presence of [bmim][BF(4)] micellar size and aggregation number (N(agg)) decreases giving rise to more water molecules penetrating in to the micellar phase which results in increased microfluidity. In accordance with solvation dynamics results, fluorescence anisotropy studies also indicate an increased microfluidity for the palisade layer of the TX-100 micelle with the added [bmim][BF(4)]. Wobbling-in-cone analysis of the anisotropy data also supports this finding.

  4. Drying drops of blood

    NASA Astrophysics Data System (ADS)

    Brutin, David; Sobac, Benjamin; Loquet, Boris; Sampol, José.

    2010-11-01

    The drying of a drop of human blood is fascinating by the complexity of the physical mechanisms that occur as well as the beauty of the phenomenon which has never been previously evidenced in the literature. The final stage of full blood evaporation reveals for a healthy person the same regular pattern with a good reproducibility. Other tests on anemia and hyperlipidemic persons were performed and presented different patterns. By means of digital camera, the influence of the motion of red blood cells (RBCs) which represent about 50% of the blood volume, is revealed as well as its consequences on the final stages of drying. The mechanisms which lead to the final pattern of dried blood drops are presented and explained on the basis of fluid and solid mechanics in conjunction with the principles of hematology. Our group is the first to evidence that the specific regular patterns characteristic of a healthy individual do not appear in a dried drop of blood from a person with blood disease. Blood is a complex colloidal suspension for which the flow motion is clearly non-Newtonian. When drops of blood evaporate, all the colloids are carried by the flow motion inside the drop and interact.

  5. Complex Drop Impact Morphology.

    PubMed

    Grishaev, Viktor; Iorio, Carlo Saverio; Dubois, Frank; Amirfazli, A

    2015-09-15

    The aim of this work is to understand the changes in the observed phenomena during particle-laden drop impact. The impact of millimeter-size drops was investigated onto hydrophilic (glass) and hydrophobic (polycarbonate) substrates. The drops were dispersions of water and spherical and nearly iso-dense hydrophobic particles with diameters of 200 and 500 μm. The impact was studied by side and bottom view images in the range 150 ≤ We ≤ 750 and 7100 ≤ Re ≤ 16400. The particles suppressed the appearance of singular jetting and drop partial rebound but promoted splashing, receding breakup, and rupture. The drops with 200 μm particles spread in two phases: fast and slow, caused by inertial and capillary forces, respectively. Also, the increase in volume fraction of 200 μm particle led to a linear decrease in the maximum spreading factor caused by the inertia force on both hydrophilic and hydrophobic substrates. The explanation of this reduction was argued to be the result of energy dissipation through frictional losses between particles and the substrate.

  6. Surface and Bulk Oscillations of Sessile Drops: Clearing Up Confusion and Understanding Wind Sheared Drops

    NASA Astrophysics Data System (ADS)

    Milne, Andrew J. B.; Defez Garcia, Beatriz; Cabrerizo Vilchez, Miguel; Amirfazli, Alidad

    2011-11-01

    Sessile drop oscillations are studied in the presence of a shearing airflow, and varying body force. The various possibilities for analysis, (center of mass or drop surface oscillations) are elucidated through presenting a unifying analysis framework based on wavenumber, frequency, and fluid properties. This work examines a range of fluid properties in a single study for the first time. A dispersion relation is found relating the frequency of centroid oscillation and capillary-gravity wave number, depending on the ratio (surface tension/liquid density)1/2, drop size- 3 / 2 and contact angle. The effects of contact angle are more complex than previously suggested simplifications, or analytic solutions for axisymetric drops and must at present be treated empirically. The growth of sessile drop oscillations is linear at low air velocities and exponential at higher air velocities. This is explained by drawing analogies to drops experiencing a varying body force, and to wind driven capillary-gravity waves on lakes, respectively. Liquid viscosity retards the growth of the waves, and has other important effects.

  7. Dynamics of Aqueous Foam Drops

    NASA Technical Reports Server (NTRS)

    Akhatov, Iskander; McDaniel, J. Gregory; Holt, R. Glynn

    2001-01-01

    We develop a model for the nonlinear oscillations of spherical drops composed of aqueous foam. Beginning with a simple mixture law, and utilizing a mass-conserving bubble-in-cell scheme, we obtain a Rayleigh-Plesset-like equation for the dynamics of bubbles in a foam mixture. The dispersion relation for sound waves in a bubbly liquid is then coupled with a normal modes expansion to derive expressions for the frequencies of eigenmodal oscillations. These eigenmodal (breathing plus higher-order shape modes) frequencies are elicited as a function of the void fraction of the foam. A Mathieu-like equation is obtained for the dynamics of the higher-order shape modes and their parametric coupling to the breathing mode. The proposed model is used to explain recently obtained experimental data.

  8. Small drops from large nozzles

    NASA Astrophysics Data System (ADS)

    Castrejon-Pita, Alfonso Arturo; Said Mohamed, Ahmed; Castrejon-Pita, Jose Rafael; Herrada, Miguel Angel

    2015-11-01

    We report experimental and numerical results of the generation of drops which are significantly smaller than the nozzle from which they are generated. The system consists of a cylindrical reservoir and two endplates. One plate is a thin metal sheet with a small orifice in its centre which acts as the nozzle. The other end consists of a piston which moves by the action of an elecromechanical actuator which in turn is driven by sine-shape pull-mode pulses. The meniscus (formed at the nozzle) is thus first overturned, forming a cavity. This cavity collapses and a thin and fast jet emerges from its centre. Under appropriate conditions the tip of this jet breaks up and produces a single diminutive drop. A good agreement between the experimental and numerical results was found. Also, a series of experiments were performed in order to study the effects that the pulse amplitude and width, together with variations in the liquid properties, have over the final size of the droplet. Based on these experiments, a predictive law for the droplet size has been derived. This work was funded by the Royal Society (University Research Fellowship and Research Grant), the John Fell Fund (Oxford University Press), the Ministry of Science and Education (DPI2013-46485 Spain), and the Junta de Andalucia (P08-TEP-31704128 Spain).

  9. Theoretical Exploration of Barrel-Shaped Drops on Cactus Spines.

    PubMed

    Luo, Cheng

    2015-11-03

    To survive an arid environment, desert cacti are capable of harvesting water from fog by transporting condensed water drops using their spines. Cactus spines have a conical shape. In this work, on the basis of the difference of liquid pressure, a new theoretical model has been developed for a barrel-shaped liquid drop on a conical wire. This model is further simplified to interpret the effects of contact angles, conical angle, surface microgrooves, and gravity on the drop movement along a cactus spine.

  10. Studies of the Stability and Dynamics of Levitated Drops

    NASA Technical Reports Server (NTRS)

    Anikumar, A.; Lee, Chun Ping; Wang, T. G.

    1996-01-01

    This is a review of our experimental and theoretical studies relating to equilibrium and stability of liquid drops, typically of low viscosity, levitated in air by a sound field. The major emphasis here is on the physical principles and understanding behind the stability of levitated drops. A comparison with experimental data is also given, along with some fascinating pictures from high-speed photography. One of the aspects we shall deal with is how a drop can suddenly burst in an intense sound field; a phenomenon which can find applications in atomization technology. Also, we are currently investigating the phenomenon of suppression of coalescence between drops levitated in intense acoustic fields.

  11. The origin of star-shaped oscillations of Leidenfrost drops

    NASA Astrophysics Data System (ADS)

    Ma, Xiaolei; Burton, Justin C.

    We experimentally investigate the oscillations of Leidenfrost drops of water, liquid nitrogen, ethanol, methanol, acetone and isopropyl alcohol. The drops levitate on a cushion of evaporated vapor over a hot, curved surface which keeps the drops stationary. We observe star-shaped modes along the periphery of the drop, with mode numbers n = 2 to 13. The number of observed modes is sensitive to the properties of the liquid. The pressure oscillation frequency in the vapor layer under the drop is approximately twice that of the drop frequency, which is consistent with a parametric forcing mechanism. However, the Rayleigh and thermal Marangoni numbers are of order 10,000, indicating that convection should play a dominating role as well. Surprisingly, we find that the wavelength and frequency of the oscillations only depend on the thickness of the liquid, which is twice the capillary length, and do not depend on the mode number, substrate temperature, or the substrate curvature. This robust behavior suggests that the wavelength for the oscillations is set by thermal convection inside the drop, and is less dependent on the flow in the vapor layer under the drop

  12. Drops in Space: Super Oscillations and Surfactant Studies

    NASA Technical Reports Server (NTRS)

    Apfel, Robert E.; Tian, Yuren; Jankovsky, Joseph; Shi, Tao; Chen, X.; Holt, R. Glynn; Trinh, Eugene; Croonquist, Arvid; Thornton, Kathyrn C.; Sacco, Albert, Jr.; Coleman, Catherine; Leslie, Fred W.; Matthiesen, David H.

    1996-01-01

    An unprecedented microgravity observation of maximal shape oscillations of a surfactant-bearing water drop the size of a ping pong ball was observed during a mission of Space Shuttle Columbia as part of the second United States Microgravity Laboratory-USML-2 (STS-73, October 20-November 5, 1995). The observation was precipitated by the action of an intense sound field which produced a deforming force on the drop. When this deforming force was suddenly reduced, the drop executed nearly free and axisymmetric oscillations for several cycles, demonstrating a remarkable amplitude of nonlinear motion. Whether arising from the discussion of modes of oscillation of the atomic nucleus, or the explosion of stars, or how rain forms, the complex processes influencing the motion, fission, and coalescence of drops have fascinated scientists for centuries. Therefore, the axisymmetric oscillations of a maximally deformed liquid drop are noteworthy, not only for their scientific value but also for their aesthetic character. Scientists from Yale University, the Jet Propulsion Laboratory (JPL) and Vanderbilt University conducted liquid drop experiments in microgravity using the acoustic positioning/manipulation environment of the Drop Physics Module (DPM). The Yale/JPL group's objectives were to study the rheological properties of liquid drop surfaces on which are adsorbed surfactant molecules, and to infer surface properties such as surface tension, Gibb's elasticity, and surface dilatational viscosity by using a theory which relies on spherical symmetry to solve the momentum and mass transport equations.

  13. Drop by Drop, Liter by Liter

    ERIC Educational Resources Information Center

    Science Scope, 2004

    2004-01-01

    It can be found as a solid, liquid, or gas. It is cohesive, colorless, tasteless, odorless, and has a pH of 7. These are some of the properties of pure water. Life without water would be unimaginable. Water is one of the most important substances for organisms on Earth. It is so important as a means of sustaining life that its existence is one of…

  14. The surface temperature of free evaporating drops

    NASA Astrophysics Data System (ADS)

    Borodulin, V. Y.; Letushko, V. N.; Nizovtsev, M. I.; Sterlyagov, A. N.

    2016-10-01

    Complex experimental and theoretical investigation of heat and mass transfer processes was performed at evaporation of free liquid drops. For theoretical calculation the emission-diffusion model was proposed. This allowed taking into account the characteristics of evaporation of small droplets, for which heat and mass transfer processes are not described in the conventional diffusion model. The calculation results of evaporation of droplets of different sizes were compared using two models: the conventional diffusion and emission-diffusion models. To verify the proposed physical model, the evaporation of droplets suspended on a polypropylene fiber was experimentally investigated. The form of droplets in the evaporation process was determined using microphotographing. The temperature was measured on the surfaces of evaporating drops using infrared thermography. The experimental results have showed good agreement with the numerical data for the time of evaporation and the temperature of evaporating drops.

  15. Capillary-inertial colloidal catapults upon drop coalescence

    NASA Astrophysics Data System (ADS)

    Chavez, Roger L.; Liu, Fangjie; Feng, James J.; Chen, Chuan-Hua

    2016-07-01

    Surface energy released upon drop coalescence is known to power the self-propelled jumping of liquid droplets on superhydrophobic solid surfaces, and the jumping droplets can additionally carry colloidal payloads toward self-cleaning. Here, we show that drop coalescence on a spherical particle leads to self-propelled launching of the particle from virtually any solid surface. The main prerequisite is an intermediate wettability of the particle, such that the momentum from the capillary-inertial drop coalescence process can be transferred to the particle. By momentum conservation, the launching velocity of the particle-drop complex is proportional to the capillary-inertial velocity based on the drop radius and to the fraction of the liquid mass in the total mass. The capillary-inertial catapult is not only an alternative mechanism for removing colloidal contaminants, but also a useful model system for studying ballistospore launching.

  16. Capillary-inertial colloidal catapults upon drop coalescence.

    PubMed

    Chavez, Roger L; Liu, Fangjie; Feng, James J; Chen, Chuan-Hua

    2016-07-04

    Surface energy released upon drop coalescence is known to power the self-propelled jumping of liquid droplets on superhydrophobic solid surfaces, and the jumping droplets can additionally carry colloidal payloads toward self-cleaning. Here, we show that drop coalescence on a spherical particle leads to self-propelled launching of the particle from virtually any solid surface. The main prerequisite is an intermediate wettability of the particle, such that the momentum from the capillary-inertial drop coalescence process can be transferred to the particle. By momentum conservation, the launching velocity of the particle-drop complex is proportional to the capillary-inertial velocity based on the drop radius and to the fraction of the liquid mass in the total mass. The capillary-inertial catapult is not only an alternative mechanism for removing colloidal contaminants, but also a useful model system for studying ballistospore launching.

  17. Tunable transport of drops on a vibrating inclined fiber

    NASA Astrophysics Data System (ADS)

    Bick, Alison; Boulogne, François; Sauret, Alban; Stone, Howard A.

    2015-11-01

    Transport of liquid drops in fibrous media occurs in various engineering systems such as fog harvesting or cleaning of textiles. The ability to tune or to control liquid movement can increase the system efficiency and enable new engineering applications. In this letter, we experimentally investigate how partially wetting drops on a single fiber can be manipulated by vibrating the fiber. We show that a sliding motion along the fiber or a dripping of the drop can be triggered by standing waves. We identify the conditions on the drop volume, the fiber tilt angle, and the amplitude and frequency of oscillations to observe these different behaviors. Finally, we experimentally illustrate that vibrations can be used to control the transport and the collection of water drops along a fiber using a combination of the sliding and dripping transitions.

  18. Highly undercooled W and Re drops in an ultrahigh-vacuum drop tube

    SciTech Connect

    Vinet, B.; Cortella, L.; Favier, J.J. ); Desre, P. )

    1991-01-07

    The Grenoble drop tube first experiments and results on pure W and Re droplets are presented. High absolute amounts of undercooling have been reached (530 K for W and 975 K for Re). The solidified samples are single crystals in the case of W and polycrystals in the case of Re. The liquid-solid interfacial energy is derived from these experiments.

  19. Initial drop size and velocity distributions for airblast coaxial atomizers

    NASA Technical Reports Server (NTRS)

    Eroglu, H.; Chigier, N.

    1991-01-01

    Phase Doppler measurements were used to determine initial drop size and velocity distributions after a complete disintegration of coaxial liquid jets. The Sauter mean diameter (SMD) distribution was found to be strongly affected by the structure and behavior of the preceding liquid intact jet. The axial measurement stations were determined from the photographs of the coaxial liquid jet at very short distances (1-2 mm) downstream of the observed break-up locations. Minimum droplet mean velocities were found at the center, and maximum velocities were near the spray boundary. Size-velocity correlations show that the velocity of larger drops did not change with drop size. Drop rms velocity distributions have double peaks whose radial positions coincide with the maximum mean velocity gradients.

  20. Heat Transfer Characteristics of Liquid-Driven Swirl Boiling Liquid/Gas Separator under Reduced Gravity

    NASA Astrophysics Data System (ADS)

    Oinuma, Ryoji; Nguyen, Ngoc; Dickes, Neil; Kurwitz, Richard C.; Best, Frederick R.

    2009-03-01

    Under reduced gravity conditions, conventional gravity-assisted steam generators do not function properly and shear-driven or swirl type of devices must be used. Once-through boilers with special inserts such as twisted-tapes or swirl devices and rotating boilers have been previously studied. The once-through boiler requires a liquid-vapor phase separator due to the inability to vaporize all liquid completely to avoid burn-out. These devices also encounter instabilities due to the sudden formation or collapse of vapor. The rotating boiler requires a large power input to operate and has less reliability due to moving parts and dynamic seals at high temperature. A liquid-driven vortex boiling separator is categorized as a shear-driven boiler, but creates centripetal-driven buoyancy forces to form a gas-liquid vortex by injecting liquid tangentially along the inner wall of the cylinder rather than rotating the body itself. The vortex boiling separator eliminates the disadvantages of devices mentioned above, having a low pressure drop, no moving parts and generating dry vapor at its outlet. Texas A&M University carried out a reduced gravity flight experiment on the NASA C-9 aircraft to investigate the heat transfer characteristics and performance based on similar devices developed at Texas A&M.

  1. Solvent and rotational relaxation of coumarin-153 and coumarin-480 in ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) modified sodium 1,4-bis(2-ethylhexyl) sulfosuccinate (NaAOT) micelle

    NASA Astrophysics Data System (ADS)

    Rao, Vishal Govind; Banerjee, Chiranjib; Mandal, Sarthak; Ghosh, Surajit; Sarkar, Nilmoni

    2013-02-01

    Understanding ion transport dynamics, structure of surfactant aggregates in ionic liquids or ionic liquid/water solutions are quite interesting and potentially important due to widespread applications of surfactant-based systems. In this manuscript we have investigated the effect of 1-butyl-3-methylimidazolium tetrafluoroborate (bmimBF4) addition on solvent and rotational relaxation of coumarin-153 (C-153) and coumarin-480 (C-480) in aqueous solution of sodium 1,4-bis(2-ethylhexyl) sulfosuccinate (NaAOT) using steady state and picosecond time resolved fluorescence spectroscopy. The strong adsorption of the bmim+ at the interface and the role of the ionic liquid particularly the cation bmim+ in the modification of the interfacial geometry were probed by the analysis of decay parameters and the rotational relaxation parameters. Since the addition of the NaAOT in water-bmimBF4 mixture above critical micellar concentration (48 mM, obtained from observing pyrene fluorescence) causes strong adsorption of the ionic liquid particularly the cation bmim+, the average solvation time, particularly the slow component increases significantly. More importantly we have found the probe dependent solvation dynamics due to the different location of the probe molecules, C-153 and C-480. C-153 being hydrophobic in nature resides in the stern layer and the adsorption of the bmim+ at the interface modifies stern layer more effectively. So we have observed more pronounced change in solvation dynamics in case of C-153 compared to that in case of C-480. The fluorescence anisotropy decays of the probe molecules were found to be biexponential in nature. The anisotropy decay was interpreted by using a model which consists of the wobbling (rotational) and translational diffusion of the dye coupled with the rotational motion of the micelle as a whole.

  2. Control of Drop Motion by Mechanical Vibrations

    NASA Astrophysics Data System (ADS)

    Bestehorn, Michael

    2014-11-01

    Since the first experimental observations of Michael Faraday in 1831 it is known that a vibrating liquid may show an instability of its flat free surface with respect to oscillating regular surface patterns. We study thin liquid films on a horizontal substrate in the long wave approximation. The films are parametrically excited by mechanical horizontal or inclined oscillations. Inertia effects are taken into account and the standard thin film formulation is extended by a second equation for the vertically averaged mass flux. The films can be additionally unstable by Van der Waals forces on a partially wetting substrate, leading to the formation of drops. These drops can be manipulated by the vibrations to move in a desired direction. Linear results based on a damped complex valued Mathieu equation as well as fully nonlinear results using a reduced model will be presented, for more details see.

  3. Interface solidification of impinging metal drops

    NASA Astrophysics Data System (ADS)

    de Ruiter, Jolet; Soto, Dan; Varanasi, Kripa

    2016-11-01

    Molten metal droplet deposition is important in manufacturing techniques such as spray deposition and metal inkjet printing. Key parameters are the final splat morphology and its adhesion to the base substrate. How to control these parameters is still poorly understood, since droplet deformation, cooling and solidification happen simultaneously. Here, we studied the contact patch formed between the metal drop and the base substrate, varying the thermal properties and the initial temperature of the substrate, and the initial temperature of the drop. We identify various scenarios for interface solidification, including smooth liquid-spread contact patches, entrapment of air pockets, and transient re-melting of the interface. The transitions between various scenarios can be rationalized from the interfacial temperature estimated by heat conduction, and taking into account the flow of liquid metal.

  4. Sliding viscoelastic drops on slippery surfaces

    NASA Astrophysics Data System (ADS)

    Xu, H.; Clarke, A.; Rothstein, J. P.; Poole, R. J.

    2016-06-01

    We study the sliding of drops of constant-viscosity dilute elastic liquids (Boger fluids) on various surfaces caused by sudden surface inclination. For smooth or roughened hydrophilic surfaces, such as glass or acrylic, there is essentially no difference between these elastic liquids and a Newtonian comparator fluid (with identical shear viscosity, surface tension, and static contact angle). In contrast for embossed polytetrafluoroethylene superhydrophobic surfaces, profound differences are observed: the elastic drops slide at a significantly reduced rate and complex branch-like patterns are left on the surface by the drop's wake including, on various scales, beads-on-a-string like phenomena. Microscopy images indicate that the strong viscoelastic effect is caused by stretching filaments of fluid from isolated islands, residing at pinning sites on the surface pillars, of the order ˜30 μm in size. On this scale, the local strain rates are sufficient to extend the polymer chains, locally increasing the extensional viscosity of the solution, retarding the drop and leaving behind striking branch-like structures on much larger scales.

  5. An evaporation model of multicomponent solution drops

    NASA Astrophysics Data System (ADS)

    Sartori, Silvana; Liñán, Amable; Lasheras, Juan C.

    2010-11-01

    Solutions of polymers are widely used in the pharmaceutical industry as tablets coatings. These allow controlling the rate at which the drug is delivered, taste or appearance. The coating is performed by spraying and drying the tablets at moderate temperatures. The wetting of the coating solution on the pill's surface depends on the droplet Webber and Re numbers, angle of impact and on the rheological properties of the droplet. We present a model for the evaporation of multicomponent solutions droplets in a hot air environment with temperatures substantially lower than the boiling temperature of the solvent. As the liquid vaporizes from the surface the fluid in the drop increases in concentration, until reaching its saturation point. After saturation, precipitation occurs uniformly within the drop. As the surface regresses, a compacting front formed by the precipitate at its maximum packing density advances into the drop, while the solute continues precipitating uniformly. This porous shell grows fast due to the double effect of surface regression and precipitation. The evaporation rate is determined by the rates at which heat is transported to the droplet surface and at which liquid vapor diffuses away from it. When the drop is fully compacted, the evaporation is drastically reduced.

  6. Drops with non-circular footprints

    NASA Astrophysics Data System (ADS)

    Ravazzoli, Pablo D.; González, Alejandro G.; Diez, Javier A.

    2016-04-01

    In this paper we study the morphology of drops formed on partially wetting substrates, whose footprint is not circular. These drops are consequence of the breakup processes occurring in thin films when anisotropic contact line motions take place. The anisotropy is basically due to the hysteresis of the contact angle since there is a wetting process in some parts of the contact line, while a dewetting occurs in other parts. Here, we obtain a characteristic drop shape from the rupture of a long liquid filament sitting on a solid substrate. We analyze its shape and contact angles by means of goniometric and refractive techniques. We also find a non-trivial steady state solution for the drop shape within the long wave approximation (lubrication theory), and we compare most of its features with experimental data. This solution is presented both in Cartesian and polar coordinates, whose constants must be determined by a certain group of measured parameters. Besides, we obtain the dynamics of the drop generation from numerical simulations of the full Navier-Stokes equation, where we emulate the hysteretic effects with an appropriate spatial distribution of the static contact angle over the substrate.

  7. Nuclear magnetic resonance study on rotational dynamics of water and benzene in a series of ionic liquids: Anion and cation effects

    NASA Astrophysics Data System (ADS)

    Kimura, Hiroshi; Yasaka, Yoshiro; Nakahara, Masaru; Matubayasi, Nobuyuki

    2012-11-01

    The rotational correlation times (τ2R) for polar water (D2O) molecule and apolar benzene (C6D6) molecule were determined in ionic liquids (ILs) by means of the 2H (D) NMR spin-lattice relaxation time (T1) measurements. The solvent IL was systematically varied to elucidate the anion and cation effects separately. Five species, bis(trifluoromethylsulfonyl)imide (TFSI-), trifluoromethylsulfonate (TfO-), hexafluorophosphate (PF6-), chloride (Cl-), and formate (HCOO-), were examined for the anion effect against a fixed cation species of 1-butyl-3-methyl-imidazolium (bmim+). Four species, bmim+, N-methyl-N-butylpyrrolidinium (bmpy+), N,N,N-trimethyl-N-propylammonium (N1,1,1,3+), and P,P,P-trihexyl-P-tetradecylphosphonium (P6,6,6,14+), were employed for the cation effect against a fixed anion species of TFSI-. The τ2R ratio of water to benzene, expressed as τW/B, was used as a probe to characterize the strength of Coulombic solute-solvent interaction in ILs beyond the hydrodynamic limit based on the excluded-volume effect. The τW/B value was found to strongly depend on the anion species, and the solute dynamics are sensitive not only to the size but also to the chemical structure of the component anion. The cation effect was rather weak, in contrast. The largest and most hydrophobic P6,6,6,14+ cation was exceptional and a large τW/B was observed, indicating a unique solvation structure in [P6,6,6,14+]-based ILs.

  8. Data acquisition in a high-speed rotating frame for New Mexico Institute of Mining and Technology liquid sodium αω dynamo experiment

    NASA Astrophysics Data System (ADS)

    Si, Jiahe; Colgate, Stirling A.; Li, Hui; Martinic, Joe; Westpfahl, David

    2013-10-01

    New Mexico Institute of Mining and Technology liquid sodium αω-dynamo experiment models the magnetic field generation in the universe as discussed in detail by Colgate, Li, and Pariev [Phys. Plasmas 8, 2425 (2001)]. To obtain a quasi-laminar flow with magnetic Reynolds number Rm ˜ 120, the dynamo experiment consists of two co-axial cylinders of 30.5 cm and 61 cm in diameter spinning up to 70 Hz and 17.5 Hz, respectively. During the experiment, the temperature of the cylinders must be maintained to 110 °C to ensure that the sodium remains fluid. This presents a challenge to implement a data acquisition (DAQ) system in such high temperature, high-speed rotating frame, in which the sensors (including 18 Hall sensors, 5 pressure sensors, and 5 temperature sensors, etc.) are under the centrifugal acceleration up to 376g. In addition, the data must be transmitted and stored in a computer 100 ft away for safety. The analog signals are digitized, converted to serial signals by an analog-to-digital converter and a field-programmable gate array. Power is provided through brush/ring sets. The serial signals are sent through ring/shoe sets capacitively, then reshaped with cross-talk noises removed. A microcontroller-based interface circuit is used to decode the serial signals and communicate with the data acquisition computer. The DAQ accommodates pressure up to 1000 psi, temperature up to more than 130 °C, and magnetic field up to 1000 G. First physics results have been analyzed and published. The next stage of the αω-dynamo experiment includes the DAQ system upgrade.

  9. Regularities of interaction between drops of UHV coolants and surfaces of traps of frameless heat removal systems in space

    NASA Astrophysics Data System (ADS)

    Koroteev, A. A.; Bondareva, N. V.; Nagel, Yu. A.; Filatov, N. I.; Baidenko, I. V.

    2016-11-01

    The regularities of interaction of drops of ultra-high vacuum liquid working media of space drop emitters with surfaces of trapping devices were considered. Their comparison with the characteristics of the interaction of drops of distilled water was performed. The achievability of trapping regimes without secondary drop formation in space was justified.

  10. Impact of particle laden drops onto surfaces of various wettability

    NASA Astrophysics Data System (ADS)

    Grishaev, Viktor; Iorio, Carlo Saverio; Amirfazli, Alidad

    2013-11-01

    Understanding characteristics of the impact of complex drops (liquid and solid particles) onto substrates is important for many applications, e.g. for additive manufacturing. Complex drops (diameter ~ 3.8 mm) were produced using polyethylene microspheres dispersed in deionized water. Drop impact was investigated on substrates with different wettability (contact angles <5° and 95°) using high-speed cameras and image processing methods. By varying speed of the drops (1.7 to 3.7 m/s), diameter of the particles (200 and 500 μm) and particles volume fraction (0 to 35 %), the influence of these variables on the impact dynamics of the drop and the distribution of particles after the impact was studied. For hydrophilic substrate, drops with 200 μm particles are arranged in a ring after the impact. For hydrophobic substrate, drops can split into several drops depending on drop velocity, size and volume fraction of particles. Also, the dynamics of drop spreading was elucidated.

  11. Drop tube technical tasks

    NASA Technical Reports Server (NTRS)

    Workman, G. L.

    1986-01-01

    Criteria, using fundamental thermochemical dynamics, were developed to assist a scientist using the Drop Tube Facility in designing a good experiment. The types of parameters involved in designing the experiments include the type of furnace, the type of atmosphere, and in general which materials are better behaved than others as determined by past experience in the facility. One of the major advantages of the facility lies in its ability to provide large undercoolings in the cooling curve during the drops. A beginning was to consider the effect of oxygen and other gases upon the amount of undercooling observed. The starting point of the thermochemistry was given by Ellingham and later transformed into what is known as the Richardson Chart. The effect of surface oxidations upon the nucleation phenomena can be observed in each specimen.

  12. Electrostatic drops in orbit

    NASA Astrophysics Data System (ADS)

    Rodriguez, Isabel J.; Schmidt, Erin; Weislogel, Mark M.; Pettit, Donald

    2016-11-01

    We present what we think are the first intentional electrostatic orbits in the near-weightless environment of a drop tower. Classical physics problems involving Coulombic forces in orbital mechanics have traditionally been confined to thought experiments due to practical terrestrial experimental limitations, namely, the preponderance of gravity. However, the use of a drop tower as an experimental platform can overcome this challenge for brief periods. We demonstrate methanol-water droplets in orbit around a variety of charged objects- some of which can be used to validate special cases of N-body systems. Footage collected via a high-speed camera is analyzed and orbital trajectories are compared with existing theoretical predictions. Droplets of diameters 0.5 to 2mm in a variety of obits are observed. Due to the repeatability of drop tower initial conditions and effective low-g environment, such experiments may be used to construct empirical analogues and confirm analyses toward the benefit of other fields including space and planetary science. NASA Cooperative Agreement NNX12A047A, Portland State LSAMP, Robert E. McNair Scholars Program.

  13. Electrohydrodynamic deformation of drops and bubbles at large Reynolds numbers

    NASA Astrophysics Data System (ADS)

    Schnitzer, Ory

    2015-11-01

    In Taylor's theory of electrohydrodynamic drop deformation by a uniform electric field, inertia is neglected at the outset, resulting in fluid velocities that scale with E2, E being the applied-field magnitude. When considering strong fields and low viscosity fluids, the Reynolds number predicted by this scaling may actually become large, suggesting the need for a complementary large-Reynolds-number analysis. Balancing viscous and electrical stresses reveals that the velocity scales with E 4 / 3. Considering a gas bubble, the external flow is essentially confined to two boundary layers propagating from the poles to the equator, where they collide to form a radial jet. Remarkably, at leading order in the Capillary number the unique scaling allows through application of integral mass and momentum balances to obtain a closed-form expression for the O (E2) bubble deformation. Owing to a concentrated pressure load at the vicinity of the collision region, the deformed profile features an equatorial dimple which is non-smooth on the bubble scale. The dynamical importance of internal circulation in the case of a liquid drop leads to an essentially different deformation mechanism. This is because the external boundary layer velocity attenuates at a short distance from the interface, while the internal boundary-layer matches with a Prandtl-Batchelor (PB) rotational core. The dynamic pressure associated with the internal circulation dominates the interfacial stress profile, leading to an O (E 8 / 3) deformation. The leading-order deformation can be readily determined, up to the PB constant, without solving the circulating boundary-layer problem. To encourage attempts to verify this new scaling, we shall suggest a favourable experimental setup in which inertia is dominant, while finite-deformation, surface-charge advection, and gravity effects are negligible.

  14. Axisymmetric model of drop spreading on a horizontal surface

    NASA Astrophysics Data System (ADS)

    Mistry, Aashutosh; Muralidhar, K.

    2015-09-01

    Spreading of an initially spherical liquid drop over a textured surface is analyzed by solving an integral form of the governing equations. The mathematical model extends Navier-Stokes equations by including surface tension at the gas-liquid boundary and a force distribution at the three phase contact line. While interfacial tension scales with drop curvature, the motion of the contact line depends on the departure of instantaneous contact angle from its equilibrium value. The numerical solution is obtained by discretizing the spreading drop into disk elements. The Bond number range considered is 0.01-1. Results obtained for sessile drops are in conformity with limiting cases reported in the literature [J. C. Bird et al., "Short-time dynamics of partial wetting," Phys. Rev. Lett. 100, 234501 (2008)]. They further reveal multiple time scales that are reported in experiments [K. G. Winkels et al., "Initial spreading of low-viscosity drops on partially wetting surfaces," Phys. Rev. E 85, 055301 (2012) and A. Eddi et al., "Short time dynamics of viscous drop spreading," Phys. Fluids 25, 013102 (2013)]. Spreading of water and glycerin drops over fully and partially wetting surfaces is studied in terms of excess pressure, wall shear stress, and the dimensions of the footprint. Contact line motion is seen to be correctly captured in the simulations. Water drops show oscillations during spreading while glycerin spreads uniformly over the surface.

  15. Drop size distribution and air velocity measurements in air assist swirl atomizer sprays

    NASA Technical Reports Server (NTRS)

    Mao, C.-P.; Oechsle, V.; Chigier, N.

    1987-01-01

    Detailed measurements of mean drop size (SMD) and size distribution parameters have been made using a Fraunhofer diffraction particle sizing instrument in a series of sprays generated by an air assist swirl atomizer. Thirty-six different combinations of fuel and air mass flow rates were examined with liquid flow rates up to 14 lbm/hr and atomizing air flow rates up to 10 lbm/hr. Linear relationships were found between SMD and liquid to air mass flow rate ratios. SMD increased with distance downstream along the center line and also with radial distance from the axis. Increase in obscuration with distance downstream was due to an increase in number density of particles as the result of deceleration of drops and an increase in the exposed path length of the laser beam. Velocity components of the atomizing air flow field measured by a laser anemometer show swirling jet air flow fields with solid body rotation in the core and free vortex flow in the outer regions.

  16. Rotating Vesta

    NASA Video Gallery

    Astronomers combined 146 exposures taken by NASA's Hubble SpaceTelescope to make this 73-frame movie of the asteroid Vesta's rotation.Vesta completes a rotation every 5.34 hours.› Asteroid and...

  17. Impact of water drops on small targets

    NASA Astrophysics Data System (ADS)

    Rozhkov, A.; Prunet-Foch, B.; Vignes-Adler, M.

    2002-10-01

    The collision of water drops against small targets was studied experimentally by means of a high-speed photography technique. The drop impact velocity was about 3.5 m/s. Drop diameters were in the range of 2.8-4.0 mm. The target was a stainless steel disk of 3.9 mm diameter. The drop spread beyond the target like a central cap surrounded by a thin, slightly conical lamella bounded by a thicker rim. By mounting a small obstacle near the target, surface-tension driven Mach waves in the flowing lamella were generated, which are formally equivalent to the familiar compressibility driven Mach waves in gas dynamics. From the measurement of the Mach angle, the values of some flow parameters could be obtained as functions of time, which provided insight into the flow structure. The liquid flowed from the central cap to the liquid rim through the thin lamella at constant momentum flux. At a certain stage of the process, most of the liquid accumulated in the rim and the internal part of the lamella became metastable. In this situation, a rupture wave propagating through the metastable internal part of the lamella caused the rim to retract while forming outwardly directed secondary jets. The jets disintegrated into secondary droplets due to the Savart-Plateau-Rayleigh instability. Prior to the end of the retraction, an internal circular wave of rupture was formed. It originated at the target and then it propagated to meet the retracting rim. Their meeting resulted in a crown of tiny droplets. A theoretical analysis of the ejection process is proposed.

  18. A posterirori study of models for large eddy simulations of drop-laden flows

    NASA Technical Reports Server (NTRS)

    Leboissetier, A.; Okong'o, N. A.; Bellan, J.

    2003-01-01

    Large Eddy Simulation (LES) is conducted of a three-dimensional temporal mixing layer whose stream is initially laden with liquid drops which may evaporate during the simulation. The gas-phase equations are written in Eulerian frame for two perfect gas species (carrier gas and vapor emanating from the drops), while the liquid-phase equations are written in a Lagrangian frame.

  19. Leidenfrost Drop on a Step

    NASA Astrophysics Data System (ADS)

    Lagubeau, Guillaume; Le Merrer, Marie; Clanet, Christophe; Quere, David

    2008-11-01

    When deposited on a hot plate, a water droplet evaporates quickly. However, a vapor film appears under the drop above a critical temperature, called Leidenfrost temperature, which insulates the drop from its substrate. Linke & al (2006) reported a spontaneous movement of such a drop, when deposited on a ratchet. We study here the case of a flat substrate decorated with a single micrometric step. The drop is deposited on the lower part of the plate and pushed towards the step at small constant velocity. If the kinetic energy of the drop is sufficient, it can climb up the step. In that case, depending on the substrate temperature, the drop can either be decelerated or accelerated by the step. We try to understand the dynamics of these drops, especially the regime where they accelerate. Taking advantage of this phenomenon, we could then build a multiple-step setup, making it possible for a Leidenfrost drop to climb stairs.

  20. Validation of an All-Pressure Fluid Drop Model: Heptane Fluid Drops in Nitrogen

    NASA Technical Reports Server (NTRS)

    Harstad, K.; Bellan, J.; Bulzan, Daniel L. (Technical Monitor)

    2000-01-01

    Despite the fact that supercritical fluids occur both in nature and in industrial situations, the fundamentals of their behavior is poorly understood because supercritical fluids combine the characteristics of both liquids and gases, and therefore their behavior is not intuitive. There are several specific reasons for the lack of understanding: First, data from (mostly optical) measurements can be very misleading because regions of high density thus observed are frequently identified with liquids. A common misconception is that if in an experiment one can optically identify "drops" and "ligaments", the observed fluid must be in a liquid state. This inference is incorrect because in fact optical measurements detect any large change (i.e. gradients) in density. Thus, the density ratio may be well below Omicron(10(exp 3)) that characterizes its liquid/gas value, but the measurement will still identify a change in the index of refraction providing that the change is sudden (steep gradients). As shown by simulations of supercritical fluids, under certain conditions the density gradients may remain large during the supercritical binary fluids mixing, thus making them optically identifiable. Therefore, there is no inconsistency between the optical observation of high density regions and the fluids being in a supercritical state. A second misconception is that because a fluid has a liquid-like density, it is appropriate to model it as a liquid. However, such fluids may have liquid-like densities while their transport properties differ from those of a liquid. Considering that the critical pressure of most fuel hydrocarbons used in Diesel and gas turbine engines is in the range of 1.5 - 3 MPa, and the fact that the maximum pressure attained in these engines is about 6 Mps, it is clear that the fuel in the combustion chamber will experience both subcritical and supercritical conditions. Studies of drop behavior over a wide range of pressures were performed in the past