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Sample records for rubidium 78

  1. Discovery of interstellar rubidium

    NASA Technical Reports Server (NTRS)

    Jura, M.; Smith, W. H.

    1981-01-01

    Interstellar rubidium is detected through observations of the resonance line of Rb I at 7800 A towards zeta Oph. The abundance ratio of rubidium to potassium is estimated to be approximately solar, and if rubidium is generally found to have an abundance similar to potassium, it is indicated that the local interstellar medium is well mixed with a wide variety of the products of nucleosynthesis.

  2. Mineral Commodity Profiles -- Rubidium

    USGS Publications Warehouse

    Butterman, W.C.; Reese, R.G.

    2003-01-01

    Overview -- Rubidium is a soft, ductile, silvery-white metal that melts at 39.3 ?C. One of the alkali metals, it is positioned in group 1 (or IA) of the periodic table between potassium and cesium. Naturally occurring rubidium is slightly radioactive. Rubidium is an extremely reactive metal--it ignites spontaneously in the presence of air and decomposes water explosively, igniting the liberated hydrogen. Because of its reactivity, the metal and several of its compounds are hazardous materials, and must be stored and transported in isolation from possible reactants. Although rubidium is more abundant in the earth?s crust than copper, lead, or zinc, it forms no minerals of its own, and is, or has been, produced in small quantities as a byproduct of the processing of cesium and lithium ores taken from a few small deposits in Canada, Namibia, and Zambia. In the United States, the metal and its compounds are produced from imported raw materials by at least one company, the Cabot Corporation (Cabot, 2003). Rubidium is used interchangeably or together with cesium in many uses. Its principal application is in specialty glasses used in fiber optic telecommunication systems. Rubidium?s photoemissive properties have led to its use in night-vision devices, photoelectric cells, and photomultiplier tubes. It has several uses in medical science, such as in positron emission tomographic (PET) imaging, the treatment of epilepsy, and the ultracentrifugal separation of nucleic acids and viruses. A dozen or more other uses are known, which include use as a cocatalyst for several organic reactions and in frequency reference oscillators for telecommunications network synchronization. The market for rubidium is extremely small, amounting to 1 to 2 metric tons per year (t/yr) in the United States. World resources are vast compared with demand.

  3. Candlestick rubidium beam source

    NASA Astrophysics Data System (ADS)

    Walkiewicz, M. R.; Fox, P. J.; Scholten, R. E.

    2000-09-01

    We describe a long-lived, bright and intense rubidium atomic beam source based on a previously published recirculating candlestick design for sodium, with several modifications and enhancements. The device operates for thousands of hours without maintenance, with brightness of 1.9×1022 m-2 s-1 sr-1.

  4. Rubidium Rydberg linear macrotrimers

    NASA Astrophysics Data System (ADS)

    Samboy, Nolan; Côté, Robin

    2013-03-01

    We investigate the interaction between three rubidium atoms in highly excited (58p) Rydberg states lying along a common axis and calculate the potential energy surfaces between the three atoms. We find that three-body long-range potential wells exist in some of these surfaces, indicating the existence of very extended bound states that we label macrotrimers. We calculate the lowest vibrational eigenmodes and the resulting energy levels and show that the corresponding vibrational periods are rapid enough to be detected spectroscopically.

  5. The USNO rubidium fountains

    NASA Astrophysics Data System (ADS)

    Peil, Steven; Hanssen, James; Swanson, Thomas B.; Taylor, Jennifer; Ekstrom, Christopher R.

    2016-06-01

    Four rubidium fountains at the U.S. Naval Observatory (USNO) have been in operation for 4.5 years. Each fountain has demonstrated periods of stability marked by Total or Theo deviation below 10-16 Occasional frequency changes, on order of 1.5 times per year per fountain, introduce deviations from white-frequency noise behavior. Averaged together, the four fountains form an ensemble with a white-frequency noise level of 10-13 and excellent long-term stability as compared to the primary frequency standards contributing to TAI. Progress on using the clocks at USNO for improving limits on coupling of fundamental constants to gravity by measuring the universality of the gravitational redshift for different types of clocks is discussed.

  6. Urinary rubidium in breast cancers.

    PubMed

    Su, Yi; Chen, Li-Juan; He, Jian-Rong; Yuan, Xue-Jiao; Cen, Yu-Ling; Su, Feng-Xi; Tang, Lu-Ying; Zhang, Ai-Hua; Chen, Wei-Qing; Lin, Ying; Wang, Shen-Ming; Ren, Ze-Fang

    2011-11-20

    Rubidium is a putative anticancer agent, but no studies have been performed on the association of rubidium levels in biospecimen with breast cancer risk and the potential as a biomarker of the risk assessment. Survey data and urine specimens were collected from 240 women with incident invasive breast cancer before their treatments and 246 age-matched female controls between October 2009 and July 2010. Urinary concentrations of rubidium were determined by inductively coupled plasma mass spectrometry. Creatinine-adjusted levels [median (25th, 75th) ug/g] of rubidium in cases [2253.01(1606.81, 3110.46)] were significantly lower than that in the controls [2921.85 (2367.94, 4142.04)]. After adjustment for potential risk factors of breast cancer, women in the second and highest tertile decreased risk of breast cancer in a dose-dependent manner as compared with those in the lowest tertile [ORs and 95% CIs were 0.45 (0.27-0.73) and 0.22 (0.13-0.38), respectively]. The area under the receive-operating-characteristic curve for urinary rubidium level was 0.697 (95% CI: 0.650-0.743). The urinary levels of rubidium were significantly and inversely associated with risk of breast cancer and had potential to be a biomarker for breast cancer risk assessment. Copyright © 2011 Elsevier B.V. All rights reserved.

  7. Mirrorless Lasing in Optically Pumped Rubidium Vapor

    DTIC Science & Technology

    2013-03-01

    MIRRORLESS LASING IN OPTICALLY PUMPED RUBIDIUM VAPOR THESIS Ryan M. Richards AFIT-ENP...MIRRORLESS LASING IN OPTICALLY PUMPED RUBIDIUM VAPOR THESIS Presented to the Faculty Department of Physics Graduate School of...RELEASE; DISTRIBUTION IS UNLIMITED. v AFIT-ENP-13-M-41 MIRRORLESS LASING IN OPTICALLY PUMPED RUBIDIUM VAPOR Ryan M. Richards

  8. GPS Synchronized Disciplined Rubidium Frequency Standard

    DTIC Science & Technology

    1989-11-01

    GPS SYNCHRONIZED DISCIPLINED RUBIDIUM FREQUENCY STANDARD D. Earl Fossler TRAK Systems Div. of TRAK Microwave Tampa, Florida Abstract A...disciplined rubidium freqllency standard steered by the corrected 1 PPS output from a GPS timing receiver or other stable 1 PPS source can provide a low...used for many timing applications, disciplined rubidium frcqucncy standards arc rtot, in wide use. GPS timing receivers have bcen used for several

  9. Rubidium Atomic Clock for Galileo

    DTIC Science & Technology

    1999-12-01

    Rubidium Ultra-Stable Oscillator ( RUSO ) for space applications, was funded by ESA under its Technology Demonstration Programme (TDP-Il) in 1993. The...objective of such development was to manufacture and qualify a compact spaceborne RUSO for the Russian Radioastron mission (Radioastron is a Russian lead...via microwave links). The development activity for the RUSO was completed in 1995 leading to the manufacturing of 3 flight models and one EQM. The

  10. A GPS Disciplined Rubidium Clock

    DTIC Science & Technology

    1989-11-01

    A GPS DISCIPLINED RUBIDIUM CLOCK .Wayne Dewey. Kincmctrics/TrueTime 3243 Sarita Rosa Ave. Santa Rosa, CA 95407 Abstract Sub-microsecond timing ...accuracy during periods when no satellites are visible, a highly sta1,lc local time base is required. For those cases which require Cesililll oscillat...tcrxxr stability. INTRODUCTION In recerlt years, time syr~chronization requirements between rer-note sites has becorrie rrlora clr:rriiir~tilr

  11. Extraction of rubidium from natural resources

    NASA Astrophysics Data System (ADS)

    Ertan, Bengü

    2017-04-01

    Rubidium is a rare alkali metal in the first group of periodic table. It has some exclusive properties like softness, ductility, malleability, strong chemical and photo-emissive activity, low melting point, easy ionization. So it is used many of applications such that optical and laser technology, electronics, telecommunications, biomedical, space technology, academic research especially quantum mechanics-based computing devices. Attention of rubidium in relation to its uses will increase in the near future. Rubidium does not have any mineral that is the main component. It is produced as minor quantities from lithium or cesium-rich minerals and natural brines. However, there are a few researches on the extraction of rubidium from mine tailings. It is difficult extraction or concentration of rubidium from these resources. Because they require a series of physical and chemical treatments and cost expensive. Efficient, cheap and friendly of environment methods for the recovery of this metal are being investigated.

  12. Rubidium dimer destruction by a diode laser

    SciTech Connect

    Ban, T.; Aumiler, D.; Pichler, G.

    2005-02-01

    We observed rubidium dimer destruction by excitation of rubidium vapor with diode laser light tuned across the Rb D{sub 2} resonance line in a 2400 GHz tuning interval. The destruction was measured for rubidium atom concentrations in the (1-9)x10{sup 16} cm{sup -3} range, pump beam power up to 43 mW, and with a 5 Torr of the helium buffer gas. We discuss the physical mechanisms involved and specify the molecular pathways which may effectively lead to the observed dimer destruction.

  13. Rubidium-87 gas cell studies, phase 2

    NASA Technical Reports Server (NTRS)

    Vanier, J.

    1973-01-01

    A description is given of the development of a compact rubidium-87 maser. Data cover the electronic control system for the maser itself and a superhetrodyne receiver capable of locking a crystal oscillator to the maser signal.

  14. RUBIDIUM IN THE INTERSTELLAR MEDIUM

    SciTech Connect

    Walker, Kyle M.; Federman, S. R.; Knauth, David C.; Lambert, David L. E-mail: steven.federman@utoledo.ed E-mail: dll@astro.as.utexas.ed

    2009-11-20

    We present observations of interstellar rubidium toward o Per, zeta Per, AE Aur, HD 147889, chi Oph, zeta Oph, and 20 Aql. Theory suggests that stable {sup 85}Rb and long-lived {sup 87}Rb are produced predominantly by high-mass stars, through a combination of the weak s- and r-processes. The {sup 85}Rb/{sup 87}Rb ratio was determined from measurements of the Rb I line at 7800 A and was compared to the solar system meteoritic ratio of 2.59. Within 1sigma uncertainties, all directions except HD 147889 have Rb isotope ratios consistent with the solar system value. The ratio toward HD 147889 is much lower than the meteoritic value and similar to that toward rho Oph A; both lines of sight probe the Rho Ophiuchus Molecular Cloud. The earlier result was attributed to a deficit of r-processed {sup 85}Rb. Our larger sample suggests instead that {sup 87}Rb is enhanced in these two lines of sight. When the total elemental abundance of Rb is compared to the K elemental abundance, the interstellar Rb/K ratio is significantly lower than the meteoritic ratio for all the sight lines in this study. Available interstellar samples for other s- and r- process elements are used to help interpret these results.

  15. A rubidium clock for SEEK-TALK

    NASA Technical Reports Server (NTRS)

    Riley, W. J.

    1983-01-01

    The development of a tactical rubidium frequency standard (TRFS) for the SEEK-TALK program is discussed. This effort, which is entering the prototype stage, is directed toward the establishment of a production capability for miniature rubidium clocks of medium stability capable of fast warmup and extreme ruggedness for military avionics applications. The overall unit consists of an ultraminiature physics package and four plug-in circuit boards inside a 2 1/2-inch square by 4-inch box. This size is achieved without the extensive use of hybrid microcircuitry, yet is believed to be the smallest atomic frequency standard yet developed.

  16. Disciplined rubidium oscillator with GPS selective availability

    NASA Technical Reports Server (NTRS)

    Dewey, Wayne P.

    1993-01-01

    A U.S. Department of Defense decision for continuous implementation of GPS Selective Availability (S/A) has made it necessary to modify Rubidium oscillator disciplining methods. One such method for reducing the effects of S/A on the oscillator disciplining process was developed which achieves results approaching pre-S/A GPS. The Satellite Hopping algorithm used in minimizing the effects of S/A on the oscillator disciplining process is described, and the results of using this process to those obtained prior to the implementation of S/A are compared. Test results are from a TrueTime Rubidium based Model GPS-DC timing receiver.

  17. Disciplined rubidium oscillator with GPS selective availability

    NASA Technical Reports Server (NTRS)

    Dewey, Wayne P.

    1993-01-01

    A U.S. Department of Defense decision for continuous implementation of GPS Selective Availability (S/A) has made it necessary to modify Rubidium oscillator disciplining methods. One such method for reducing the effects of S/A on the oscillator disciplining process was developed which achieves results approaching pre-S/A GPS. The Satellite Hopping algorithm used in minimizing the effects of S/A on the oscillator disciplining process is described, and the results of using this process to those obtained prior to the implementation of S/A are compared. Test results are from a TrueTime Rubidium based Model GPS-DC timing receiver.

  18. Nonlinear Spectroscopy of Rubidium: An Undergraduate Experiment

    ERIC Educational Resources Information Center

    Jacques, V.; Hingant, B.; Allafort, A.; Pigeard, M.; Roch, J. F.

    2009-01-01

    In this paper, we describe two complementary nonlinear spectroscopy methods which both allow one to achieve Doppler-free spectra of atomic gases. First, saturated absorption spectroscopy is used to investigate the structure of the 5S[subscript 1/2] [right arrow] 5P[subscript 3/2] transition in rubidium. Using a slightly modified experimental…

  19. Nonlinear Spectroscopy of Rubidium: An Undergraduate Experiment

    ERIC Educational Resources Information Center

    Jacques, V.; Hingant, B.; Allafort, A.; Pigeard, M.; Roch, J. F.

    2009-01-01

    In this paper, we describe two complementary nonlinear spectroscopy methods which both allow one to achieve Doppler-free spectra of atomic gases. First, saturated absorption spectroscopy is used to investigate the structure of the 5S[subscript 1/2] [right arrow] 5P[subscript 3/2] transition in rubidium. Using a slightly modified experimental…

  20. Remote Frequency Measurement of TV 5 Rubidium

    DTIC Science & Technology

    2005-08-01

    measurements were then converted into a frequency drift rate by a program called “TV5 Test” written in Visual Basic . A rubidium clock at the WTTG...Counter and a Windows omputer running the “TV 5 Test” program. The new Visual Basic program used commands sent hrough the GPIB card to the Stanford

  1. Rubidium, salami and depression. You cannot have everything in life.

    PubMed

    Canavese, Caterina; Decostanzi, Ester; Bergamo, Daniela; Sabbioni, Enrico; Stratta, Piero

    2008-01-01

    Depression may induce malnutrition, but, as a paradoxical hypothesis, malnutrition may induce depression. This relationship, of course, depends on how we define malnutrition. Rubidium is a trace element strongly linked with depression, and is deficient in uremia sufferers. However, in uremic patients, rubidium deficiency is more evident during predialysis, as it is at least partially corrected during dialysis and after transplantation. It seems that diet restrictions might be the main cause of rubidium deficiency, as it is mainly found in red meat. If rubidium is found in salami, then the occasional slice could be more beneficial for people suffering from depression than taking a lot of medication. (c) 2008 S. Karger AG, Basel

  2. A rubidium clock for GPS. [breadboard model

    NASA Technical Reports Server (NTRS)

    Riley, W. J.

    1982-01-01

    The design objectives and approach; the more important design features; the signal parameters and error budget; and early test results in the development of a second-source rubidium frequency standard for use in the GPS navigation satellites are discussed. Tests of a breadboard version of the RFS show that the measured time-domain stability is within the goal specification. The results are uncorrected for the conribution of the reference and are probably limited by the reference stability in the medium term region. The Rb reference is bbetter in the medium term region, but the Cs reference is etter at 10,000 seconds and longer, probably because of the barometric sensitivity of the rubidium reference unit.

  3. Bioassay Method for Polyene Antibiotics Based on the Measurement of Rubidium Efflux from Rubidium-Loaded Yeast Cells

    PubMed Central

    Cosgrove, R. F.; Fairbrother, J. E.

    1977-01-01

    A bioassay method for the polyene antibiotics nystatin and amphotericin B is proposed based on the measurement of the efflux of rubidium ions from a rubidium-loaded yeast culture challenged with the antibiotics. For this purpose a major proportion of the intracellular K+ ions in a Saccharomyces cerevisiae culture has been substituted by Rb+ ions. The rubidium leakage is measured by atomic absorption spectrophotometry, and a straight-line, dose-response correlation has been obtained for both antibiotics. PMID:319752

  4. Rubidium 87 gas cell studies, phase 2. [design and characteristics of rubidium maser

    NASA Technical Reports Server (NTRS)

    Vanier, J.

    1974-01-01

    The design, development, and characteristics of a rubidium 87 maser are discussed. The design of a receiver capable of locking a crystal oscillator to the maser signal is reported. The subjects considered are: (1) maser construction, (2) maser control electronics, (3) the characteristics of the receiver, and (4) results of experimental maser tests.

  5. Pulsed filling of a dark magnetooptical trap for rubidium atoms

    SciTech Connect

    Chapovskii, Pavel L

    2006-03-31

    The parameters of a dark magnetooptical trap for rubidium atoms are measured. The rubidium atoms captured and cooled in the trap occupy a hyperfine level of the ground electronic state, which does not interact with cooling laser radiation. The pulsed filling of the trap is produced due to desorption of rubidium caused by irradiation by a short (1 ms) light pulse. The trap captures and cools 2.5x10{sup 8} rubidium atoms approximately for 0.2 s. The absorption spectra of a weak probe field by cold atoms are obtained, which demonstrate a good spectral resolution of the hyperfine structure in the excited state. This structure is completely hidden by the Doppler broadening in rubidium vapours at room temperature. (laser cooling)

  6. Rubidium-87 gas cell studies, phase 1

    NASA Technical Reports Server (NTRS)

    Vanier, J.

    1972-01-01

    The construction of a quartz bulb-quartz cavity type rubidium maser is described, and the results obtained with two of these masers are presented. The tuning characteristics, medium term stability, and short term stability are reported. It is concluded that the stability of the masers in the short term region is superior to any of the oscillators presently existing. On this basis it is believed that future development of the masers to reduce their size and improve their medium term stability is well justified.

  7. [82 Rubidium PET to replace myocardial scintigraphy].

    PubMed

    Hasbak, Philip; Kjær, Andreas

    2011-02-21

    Since the 1970's nuclear cardiology has mainly been based on the use of gamma camera technology. While gamma cameras have undergone a rapid development, the number of perfusion tracers has been limited. In parallel, cardiac positron emission tomography (PET) has only been performed with short-lived isotopes at centres with access to a cyclotron, and only including a very limited number of patients. The number of PET scanners has increased markedly in Denmark and with the introduction of generator-produced 82-Rubidium, this modality may replace the traditional cardial single photon emission computed tomography (SPECT).

  8. Cation exchange chromatographic elution and separation of rubidium

    SciTech Connect

    Mehta, V.P.; Khopkar, S.M.

    1982-01-01

    The systematic cation exchange chromatographic separation of rubidium on Dowex 50W-X8 was carried out with mineral acids and their salts as eluants.A selectivity scale for various eluants in terms of the elution constant was devised. Rubidium was separated from a large number of elements in binary mixtures by the process of gradient or selective elutions or selective sorption. The noteworthy feature of the method is the sequential separation of rubidium from alkali as well as alkaline earth elements.

  9. Using surface-bound rubidium ions for protein phasing

    PubMed Central

    Korolev, S.; Dementieva, I.; Sanishvili, R.; Minor, W.; Otwinowski, Z.; Joachimiak, A.

    2013-01-01

    Rubidium is a monovalent metal that can be used as a counterion in protein solutions. X-ray anomalous scattering from rubidium ions bound to the protein surface was used for phasing of the crystal structure of the hsp60 apical domain from Thermus thermophilus. Multiple-wavelength anomalous dispersion (MAD) data were collected from a crystal obtained from a solution containing 0.2 M rubidium salt. One molecule of protein (147 amino acids) binds one well ordered and one poorly ordered Rb atom. Phases calculated with the program SHARP were sufficient for automatic tracing and side-chain assignment using the program ARP/wARP. The data show that bound rubidium ions can be used to determine protein structures and to study the interaction of monovalent metal ions with proteins and other macromolecules. PMID:11418770

  10. Optical pumping of rubidium atoms in a parahydrogen matrix

    NASA Astrophysics Data System (ADS)

    Weinstein, Jonathan; Arnott, W. Patrick; Christy, Tim; Hartzell, Chase; Kanagin, Andrew; Momose, Takamasa; Patterson, David; Upadhyay, Sunil

    2016-05-01

    Building on prior work with rubidium atoms in a cryogenic argon matrix, we have grown solid parahydrogen crystals doped with rubidium atoms. Typical rubidium densities are on the order of 1017 cm-3. We have demonstrated optical pumping of the atomic spin of the implanted rubidium atoms; the measured spin polarization signals are roughly one order of magnitude larger than what was achieved in argon matrices. The combination of high atomic densities and optical addressability make this a promising experimental platform for applications such as magnetometry and fundamental physics measurements. Spin lifetimes (T1) on the order of 1 second have been observed. Progress towards measuring coherence times (T2) will be discussed. This material is based on work supported by the National Science Foundation under Grant No. PHY 1265905.

  11. Using surface-bound rubidium ions for protein phasing.

    PubMed

    Korolev, S; Dementieva, I; Sanishvili, R; Minor, W; Otwinowski, Z; Joachimiak, A

    2001-07-01

    Rubidium is a monovalent metal that can be used as a counterion in protein solutions. X-ray anomalous scattering from rubidium ions bound to the protein surface was used for phasing of the crystal structure of the hsp60 apical domain from Thermus thermophilus. Multiple-wavelength anomalous dispersion (MAD) data were collected from a crystal obtained from a solution containing 0.2 M rubidium salt. One molecule of protein (147 amino acids) binds one well ordered and one poorly ordered Rb atom. Phases calculated with the program SHARP were sufficient for automatic tracing and side-chain assignment using the program ARP/wARP. The data show that bound rubidium ions can be used to determine protein structures and to study the interaction of monovalent metal ions with proteins and other macromolecules.

  12. Two-element Zeeman slower for rubidium and lithium

    SciTech Connect

    Marti, G. Edward; Olf, Ryan; Vogt, Enrico; Oettl, Anton; Stamper-Kurn, Dan M.

    2010-04-15

    We demonstrate a two-element oven and Zeeman slower that produce simultaneous and overlapped slow beams of rubidium and lithium. The slower uses a three-stage design with a long, low-acceleration middle stage for decelerating rubidium situated between two short, high-acceleration stages for aggressive deceleration of lithium. This design is appropriate for producing high fluxes of atoms with a large mass ratio in a simple, robust setup.

  13. On the detection of rubidium in diffuse interstellar clouds

    NASA Technical Reports Server (NTRS)

    Federman, S. R.; Sneden, C.; Schempp, W. V.; Smith, W. H.

    1985-01-01

    A search for absorption from neutral rubidium at 7800 A was conducted. No evidence for absorption to a 3 sigma limit of less than 1.5 mA was seen in the diffuse interstellar gas toward the stars omicron Persei, zeta Persei, and zeta Ophiuchi. Present results do not confirm the detection by Jura and Smith (1981) toward zeta Oph. A possible reason for the discrepancy is presented. In light of the present measurements, the abundance of interstellar rubidium in reconsidered.

  14. Experimental vacuum squeezing in rubidium vapor via self-rotation

    SciTech Connect

    Ries, J.; Brezger, B.; Lvovsky, A. I.

    2003-08-01

    We report the generation of optical squeezed vacuum states by means of polarization self-rotation in rubidium vapor following a proposal by Matsko et al. [Phys. Rev. A 66, 043815 (2002)]. The experimental setup, involving in essence just a diode laser and a heated rubidium gas cell, is simple and easily scalable. A squeezing of (0.85{+-}0.05) dB was achieved.

  15. Optical pumping of rubidium atoms frozen in solid argon

    NASA Astrophysics Data System (ADS)

    Kanagin, Andrew N.; Regmi, Sameer K.; Pathak, Pawan; Weinstein, Jonathan D.

    2013-12-01

    We have grown crystals of solid argon doped with rubidium atoms. The spectrum of the implanted atoms depends on the crystal-growth temperature and annealing history. We have used optical pumping to polarize the spin state of the implanted atoms and polarization spectroscopy to detect the spin state and measure the spin-relaxation time. In addition to the desired optical pumping, we also observed modification of the absorption spectrum of the rubidium due to the applied light.

  16. Crystal structure of rubidium peroxide ammonia disolvate.

    PubMed

    Grassl, Tobias; Korber, Nikolaus

    2017-02-01

    The title compound, Rb2O2·2NH3, has been obtained as a reaction product of rubidium metal dissolved in liquid ammonia and glucuronic acid. As a result of the low-temperature crystallization, a disolvate was formed. To our knowledge, only one other solvate of an alkali metal peroxide is known: Na2O2·8H2O has been reported by Grehl et al. [Acta Cryst. (1995), C51, 1038-1040]. We determined the peroxide bond length to be 1.530 (11) Å, which is in accordance with the length reported by Bremm & Jansen [Z. Anorg. Allg. Chem. (1992), 610, 64-66]. One of the ammonia solvate molecules is disordered relative to a mirror plane, with 0.5 occupancy for the corresponding nitrogen atom.

  17. Crystal structure of rubidium peroxide ammonia disolvate

    PubMed Central

    Grassl, Tobias; Korber, Nikolaus

    2017-01-01

    The title compound, Rb2O2·2NH3, has been obtained as a reaction product of rubidium metal dissolved in liquid ammonia and glucuronic acid. As a result of the low-temperature crystallization, a disolvate was formed. To our knowledge, only one other solvate of an alkali metal peroxide is known: Na2O2·8H2O has been reported by Grehl et al. [Acta Cryst. (1995), C51, 1038–1040]. We determined the peroxide bond length to be 1.530 (11) Å, which is in accordance with the length reported by Bremm & Jansen [Z. Anorg. Allg. Chem. (1992), 610, 64–66]. One of the ammonia solvate molecules is disordered relative to a mirror plane, with 0.5 occupancy for the corresponding nitrogen atom. PMID:28217342

  18. Rubidium-rich asymptotic giant branch stars.

    PubMed

    García-Hernández, D A; García-Lario, P; Plez, B; D'Antona, F; Manchado, A; Trigo-Rodríguez, J M

    2006-12-15

    A long-debated issue concerning the nucleosynthesis of neutron-rich elements in asymptotic giant branch (AGB) stars is the identification of the neutron source. We report intermediate-mass (4 to 8 solar masses) AGB stars in our Galaxy that are rubidium-rich as a result of overproduction of the long-lived radioactive isotope (87)Rb, as predicted theoretically 40 years ago. This finding represents direct observational evidence that the (22)Ne(alpha,n)(25)Mg reaction must be the dominant neutron source in these stars. These stars challenge our understanding of the late stages of the evolution of intermediate-mass stars and would have promoted a highly variable Rb/Sr environment in the early solar nebula.

  19. Recovery of strontium activity from a strontium-82/rubidium-82 generator

    DOEpatents

    Taylor, Wayne A.; Phillips, Dennis R.; Sosnowski, Kenneth M.

    1999-10-12

    Strontium-82 is recovered from spent strontium-82/rubidium-82 generators to provide a source of strontium-82 for additional strontium-82/rubidium-82 generators. The process involves stripping of the strontium-82 from used strontium-82/rubidium-82 generators followed by purification of the strontium-82 material to remove additional metal contaminants to desired levels.

  20. Rubidium Atomic Line Filtered (RALF) Doppler Velocimetry

    NASA Astrophysics Data System (ADS)

    Fajardo, Mario; Molek, Christopher; Vesely, Annamaria

    2015-06-01

    We report the successful proof-of-concept demonstration of the Rubidium Atomic Line Filtered (RALF) Doppler velocimetry technique. RALF is a high-velocity and high-acceleration adaptation of the Global Doppler Velocimetry (GDV) method developed in the 1990s by aerodynamics researchers. Laser velocimetry techniques in common use within the shock physics community (e . g . VISAR, Fabry-Perot, PDV) decode the Doppler shift of light reflected from a moving surface via interference phenomena. In contrast, RALF employs a completely different physical principle: the frequency-dependent near-resonant optical transmission of a Rb/N2 gas cell, to convert the Doppler shift of reflected λ0 ~ 780.24 nm light directly into transmitted light intensity. The single-point RALF apparatus used in these experiments is fiber optic based, and incorporates a simultaneous PDV measurement channel as an ``internal standard'' for validation of the RALF results. Future plans include ``line-RALF'' experiments with streak camera detection, and two-dimensional surface velocity mapping using pulsed laser illumination and gated intensified CCD camera detection. [RW PA#4931

  1. Catalysis of Forster Resonances in Rubidium

    NASA Astrophysics Data System (ADS)

    Win, A. L.; Williams, W. D.; Sukenik, C. I.

    2016-05-01

    When two ultracold Rydberg atoms collide they may change their quantum state if the total electronic energy of the two atoms before and after the collision is about the same. This process can be made resonant by tuning the energy levels of the atoms with an electric field, via the Stark shift, so that the energy difference between incoming and outgoing channels vanishes. This condition is known as a ``Forster resonance.'' We have studied a particular Forster resonance in rubidium: 34p + 34p --> 34s + 35s, by investigating the time dependence of the state change in an ultracold environment. Furthermore, we have added 34d state atoms to the mix and observed an enhancement of 34s atom production. We attribute this enhancement to a catalysis effect whereby the 34d atoms alter the spatial distribution of 34p atoms that participate in the energy transfer interaction. We will present results from the experiment and compare them to model calculations. Present address: Department of Physics, Smith College, Northampton, MA.

  2. Radiation hardness of Efratom M-100 rubidium frequency standard

    NASA Technical Reports Server (NTRS)

    English, T. C.; Vorwerk, H.; Rudie, N. J.

    1983-01-01

    The effects of nuclear radiation on rubidium gas cell frequency standards and components are presented, including the results of recent tests where a continuously operating rubidium frequency standard (Effratom, Model M-100) was subjected to simultaneous neutron/gamma radiation. At the highest neutron fluence 7.5 10 to the 12th power n/sq cm and total dose 11 krad(Si) tested, the unit operated satisfactorily; the total frequency change over the 2 1/2 hour test period due to all causes, including repeated retraction from and insertion into the reactor, was less than 1 x 10 to the -10th power. The effects of combined neutron/gamma radiation on rubidium frequency standard physics package components were also studied, and the results are presented.

  3. Radiation hardness of Efratom M-100 rubidium frequency standard

    SciTech Connect

    English, T.C.; Vorwerk, H.; Rudie, N.J.

    1983-02-01

    The effects of nuclear radiation on rubidium gas cell frequency standards and components are presented, including the results of recent tests where a continuously operating rubidium frequency standard (Effratom, Model M-100) was subjected to simultaneous neutron/gamma radiation. At the highest neutron fluence 7.5 10 to the 12th power n/sq cm and total dose 11 krad(Si) tested, the unit operated satisfactorily. The total frequency change over the 2 1/2 hour test period due to all causes, including repeated retraction from and insertion into the reactor, was less than 1 x 10 to the -10th power. The effects of combined neutron/gamma radiation on rubidium frequency standard physics package components were also studied, and the results are presented.

  4. Optical Pumping of Rubidium Spin in a Solid Argon Matrix

    NASA Astrophysics Data System (ADS)

    Regmi, Sameer K.

    Using the matrix isolation technique we have trapped rubidium atoms inside a cryogenic solid argon crystal of thickness 200 mum. This weakly-interacting solid offers the experimental simplicity and high densities of solid-state systems, while allowing the implanted atoms to retain many of the properties of their gas-phase counterparts. As such, they are a promising environment for quantum information experiments, as well as sensors such as magnetometers. We spectroscopically observed narrow lines at 799 nm, 785 nm, and 747 nm, and investigated optical pumping of the implanted rubidium atoms. We observed that the absorption spectrum of the rubidium could be modified by incident laser light. This modification could be reversed by applying an additional light source. In addition, we were able to create spin polarization and measure a longitudinal spin relaxation time T1 of about 0.1 s.

  5. Separation of rubidium from irradiated aluminum-encapsulated uranium

    SciTech Connect

    Horwitz, E. P.; Schmitz, F. J.; Rokop, D. J.

    1982-01-01

    A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.

  6. Operational frequency stability of rubidium and cesium frequency standards

    NASA Technical Reports Server (NTRS)

    Lavery, J. E.

    1973-01-01

    The frequency stabilities under operational conditions of several commercially available rubidium and cesium frequency standards were determined from experimental data for frequency averaging times from 10 to the 7th power s and are presented in table and graph form. For frequency averaging times between 10 to the 5th power and 10 to the 7th power s, the rubidium standards tested have a stability of between 10 to the minus 12th power and 5 x 10 to the minus 12th power, while the cesium standards have a stability of between 2 x 10 to the minus 13th power and 5 x 10 to the minus 13th power.

  7. Simultaneous determination of potassium and rubidium content in yeast.

    PubMed

    Mulet, Jose M; Serrano, Ramón

    2002-11-01

    Rubidium is widely used as a potassium analogue in transport studies in yeast and other organisms. As rubidium (potassium) uptake is modulated by the internal potassium concentration, it is often necessary to determine both Rb(+) and K(+) concentrations in the same cell extract. Current methods based on atomic absorption/emission spectroscopy require separate analysis for each cation. Alternatively, unsafe radioactive isotopes can be used. Here we report a convenient, non-radioactive, HPLC/conductivity-based method that allows a complete analysis of both cations with a single injection from a cell extract. The increase in Rb(+) uptake during K(+) starvation in yeast is easily demonstrated with this method.

  8. Rubidium Spectroscopy with an External Cavity Diode Laser

    NASA Astrophysics Data System (ADS)

    Burgess, Charity; Smith, R. Seth

    2014-03-01

    A homebuilt external cavity diode laser (ECDL) was used to provide a very narrow range of laser wavelengths near 780 nm in order to study the structure of rubidium (Rb). The absorption spectrum of Rb was measured. This spectrum was subject to Doppler-broadening of the spectral lines. A technique known as Saturated Absorption Spectroscopy was employed to eliminate the effects of Doppler-broadening and to obtain a high resolution spectrum for Rubidium. The setup, operation, and performance of this system will be described. Research made possible by a REAL grant from Francis Marion University.

  9. Nonlinear transmission through a tapered fiber in rubidium vapor

    SciTech Connect

    Hendrickson, S. M.; Pittman, T. B.; Franson, J. D.

    2009-02-15

    Subwavelength-diameter tapered optical fibers surrounded by rubidium vapor can undergo a substantial decrease in transmission at high atomic densities due to the accumulation of rubidium atoms on the surface of the fiber. Here we demonstrate the ability to control these changes in transmission using light guided within the taper. We observe transmission through a tapered fiber that is a nonlinear function of the incident power. This effect can also allow a strong control beam to change the transmission of a weak probe beam.

  10. Positronium formation in positron-rubidium inelastic scattering

    NASA Astrophysics Data System (ADS)

    Abdel-Raouf, M. A.

    1988-04-01

    Eight partial cross sections of positron-rubidium ( 37Rb) inelastic scattering (corresponding to 0 ⩽ l⩽ 7, where l is the total angular momentum) are calculated at 25 values of the incident energy ranging from 0.1 to 1000 eV. The calculations are carried out using Clementi-Roetti's wavefunctions, and a combination of the coupled-static and frozen-core approximations. A comparison between the total positronium formation cross sections of the collisions of positrons with four different alkali atoms (lithium, sodium, potassium and rubidium) is presented.

  11. Spectrally resolved coherent transient signal for ultracold rubidium molecules

    NASA Astrophysics Data System (ADS)

    Eimer, F.; Weise, F.; Merli, A.; Birkner, S.; Sauer, F.; Wöste, L.; Lindinger, A.; Aç§Anoç§Lu, R.; Koch, C. P.; Salzmann, W.; Mullins, T.; Götz, S.; Wester, R.; Weidemüller, M.

    2009-09-01

    We present spectrally resolved pump-probe experiments on the photoassociation of ultracold rubidium atoms with shaped ultrashort laser pulses. The pump pulse causes a free-bound transition leading to a coherent transient signal of rubidium molecules in the first excited state. In order to achieve a high frequency resolution the bandwidth of the pump pulse is reduced to a few wavenumbers. The frequency dependence of the transient signal close to the D1 atomic resonance is investigated for characteristic pump-probe delay times. The observed spectra, which show a pronounced dip for pump-probe coincidence, are interpreted using quantum dynamical calculations.

  12. Rubidium atomic line filtered (RALF) Doppler velocimetry

    NASA Astrophysics Data System (ADS)

    Fajardo, Mario E.; Molek, Christopher D.; Vesely, Annamaria L.

    2017-01-01

    We report recent improvements to our Rubidium Atomic Line Filtered (RALF) Doppler velocimetry apparatus [M.E. Fajardo, C.D. Molek, and A.L. Vesely, J. Appl. Phys. 118, 144901 (2015)]. RALF is a high-velocity and high-acceleration adaptation of the Doppler Global Velocimetry method for measuring multi-dimensional velocity vector flow fields, which was developed in the 1990s by aerodynamics researchers [H. Komine, U.S. Patent #4,919,536]. Laser velocimetry techniques in common use within the shock physics community (e.g. VISAR, Fabry-Pérot, PDV) decode the Doppler shift of light reflected from a moving surface via interference phenomena. In contrast, RALF employs a completely different physical principle: the frequency-dependent near-resonant optical transmission of a Rb/N2 gas cell, to encode the Doppler shift of reflected λ0 ≈ 780.24 nm light directly onto the transmitted light intensity. Thus, RALF is insensitive to minor changes to the optical pathlengths and transit times of the Doppler shifted light, which promises a number of practical advantages in imaging velocimetry applications. The single-point RALF proof-of-concept apparatus described here is fiber optic based, and our most recent modifications include the incorporation of a larger bandwidth detection system, and a second 780 nm laser for simultaneous upshifted-PDV (UPDV) measurements. We report results for the laser driven launch of a 10-μm-thick aluminum flyer which show good agreement between the RALF and UPDV velocity profiles, within the limitations of the admittedly poor signal:noise ratio (SNR) RALF data.

  13. Discovery of rubidium, strontium, molybdenum, and rhodium isotopes

    SciTech Connect

    Parker, A.M.; Thoennessen, M.

    2012-07-15

    Currently, 31 rubidium, 35 strontium, 35 molybdenum, and 38 rhodium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  14. Dipole-dipole interaction between rubidium Rydberg atoms

    SciTech Connect

    Altiere, Emily; Fahey, Donald P.; Noel, Michael W.; Smith, Rachel J.; Carroll, Thomas J.

    2011-11-15

    Ultracold Rydberg atoms in a static electric field can exchange energy via the dipole-dipole interaction. The Stark effect shifts the energy levels of the atoms which tunes the energy exchange into resonance at specific values of the electric field (Foerster resonances). We excite rubidium atoms to Rydberg states by focusing either a 480 nm beam from a tunable dye laser or a pair of diode lasers into a magneto-optical trap. The trap lies at the center of a configuration of electrodes. We scan the electric field by controlling the voltage on the electrodes while measuring the fraction of atoms that interact. Dipole-dipole interaction spectra are presented for initially excited rubidium nd states for n=31 to 46 and for four different pairs of initially excited rubidium ns states. We also present the dipole-dipole interaction spectra for individual rubidium 32d (j, m{sub j}) fine structure levels that have been selectively excited. The data are compared to calculated spectra.

  15. Rubidium vapor laser pumped by two laser diode arrays.

    PubMed

    Zhdanov, Boris V; Stooke, Adam; Boyadjian, Gregory; Voci, Adam; Knize, R J

    2008-03-01

    Scaling of alkali lasers to higher powers requires using multiple diode lasers for pumping. The first (to our knowledge) results of a cw rubidium laser pumped by two laser diode arrays are presented. A slope efficiency of 53%, total optical efficiency of 46%, and output power of 17 W have been demonstrated.

  16. Observations on the Reliability of Rubidium Frequency Standards on Block 2/2A GPS Satellites

    NASA Technical Reports Server (NTRS)

    Dieter, Gary L.

    1996-01-01

    Currently, the block 2/2A Global Positioning System (GPS) satellites are equipped with two rubidium frequency standards. These frequency standards were originally intended to serve as the back-ups to two cesium frequency standards. As the constellation ages, the master Control Station is forced to initialize and increasing number or rubidium frequency standards. Unfortunately the operational use of these frequency standards has not lived up to initial expectations. Although the performance of these rubidium frequency standards has met and even exceeded GPS requirements, their reliability has not. The number of unscheduled outage times and the short operational lifetimes of the rubidium frequency standards compare poorly to the track record of the cesium frequency standards. Only a small number of rubidium frequency standards have actually been made operational. Of these, a large percentage have exhibited poor reliability. If this trend continues, it is unlikely that the rubidium frequency standards will help contribute to the navigation payload meeting program specification.

  17. Absorption Spectroscopy of Rubidium in an Alkali Metal Dispenser Cell and Bleached Wave Analysis

    DTIC Science & Technology

    2015-03-26

    ABSORPTION SPECTROSCOPY OF RUBIDIUM IN AN ALKALI METAL DISPENSER CELL AND BLEACHED WAVE ANALYSIS THESIS JAMES M. ROSENTHAL, 2 nd Lt...102 ABSORPTION SPECTROSCOPY OF RUBIDIUM IN AN ALKALI METAL DISPENSER CELL AND BLEACHED WAVE ANALYSIS THESIS Presented to the Faculty...SPECTROSCOPY OF RUBIDIUM IN AN ALKALI METAL DISPENSER CELL AND BLEACHED WAVE ANALYSIS James M. Rosenthal, BA 2 nd Lt, USAF Committee Membership

  18. Effects of rubidium chloride on the course of manic-depressive illness.

    PubMed Central

    Paschalis, C; Jenner, F A; Lee, C R

    1978-01-01

    Clinical studies of the effects of rubidium ions on the course of manic-depressive illness are reported. It seems that rubidium tends to increase the length of manic phases and possibly reduces the extremes of mood. Rubidium did not seem to produce any severe side effects in the dose administered, but it has a long biological half-life and caution is still required. Some details of the CSF, RBC, saliva and plasma and urine kinetics are also reported. PMID:349155

  19. [Electrone probe microanalysis of rubidium retention in myocell of rat heart during acute ischemia].

    PubMed

    Pogorelov, A G; Pogorelova, V N; Pogorelova, M A

    2012-01-01

    In the given investigation contents of potassium and its physiological analog, rubidium, are determined in cardiomyocyte. Applying Electron Probe Microanalysis (EPMA), cytoplasmic concentrations of elements (K, Rb) are measured. The data obtained exhibit that for initial acute ischemia phase the active transport is involved in the uptake of rubidium which competes with potassium entry in cardiac myocell. Then, deep deenergization leads to the intracellular potassium depletion and rubidium retention. This suggests that Rb+ is physiologically not complete analog for K+. Results of combined perfusion with and without rubidium allow us to hypothesize the appearance of cascade of ionic transports to compensate acute ischemic disturbances following the oxygen and substrate deficiency.

  20. Risk assessment visualization of rubidium compounds: comparison of renal and hepatic toxicities, in vivo.

    PubMed

    Usuda, Kan; Kono, Rei; Ueno, Takaaki; Ito, Yuichi; Dote, Tomotaro; Yokoyama, Hirotaka; Kono, Koichi; Tamaki, Junko

    2014-06-01

    Rubidium has been considered to be nontoxic. Its use includes thin film on glass deposition and as medical contrast medium. Recent technology innovations also involve the use of rubidium, but there is limited information about the biological effects of its various compounds. In the present risk assessment study, a series of rubidium compounds with different counter anions-acetate, bromide, carbonate, chloride, and fluoride-were orally administrated in a single dose to several groups of rats. Cumulative 24-h urine samples were obtained, and the levels of rubidium, fluoride, N-acetyl-β-D-glucosaminidase and creatinine were measured to evaluate possible acute renal effects. Daily samples of serum were also obtained to determine the levels of aspartate and alanine aminotransferases to assess possible acute hepatic effects. Urinary rubidium excretion recovery of 8.0-10.5% shows that urine can be a useful diagnostic tool for rubidium exposure. The present results reveal that rubidium shows different biological effects depending on the counter anion. A pattern of large significant NAG leakage and elevation of ALT observed in rats treated with anhydrous rubidium fluoride indicates renal and hepatic toxicities that can be attributed to fluoride. The techniques reported in this study will be of help to assess the potential risks of toxicity of rubidium compounds with a variety of anions.

  1. [Determination of high concentrations of rubidium chloride by ICP-OES].

    PubMed

    Zhong, Yuan; Sun, Bai; Li, Hai-jun; Wang, Tao; Li, Wu; Song, Peng-sheng

    2015-01-01

    The method of ICP-OES for the direct determination of high content of rubidium in rubidium chloride solutions was studied through mass dilution method and optimizing parameters of the instrument in the present paper. It can reduce the times of dilution and the error introduced by the dilution, and improve the accuracy of determination results of rubidium. Through analyzing the sensitivity of the three detection spectral lines for rubidium ion, linearly dependent coefficient and the relative errors of the determination results, the spectral line of Rb 780. 023 nm was chosen as the most suitable wavelength to measure the high content of rubidium in the rubidium chloride solutions. It was found that the instrument parameters of ICP-OES such as the atomizer flow, the pump speed and the high-frequency power are the major factors for the determination of rubidium ion in the rubidium chloride solutions. As we know instrument parameters of ICP-OES have an important influence on the atomization efficiency as well as the emissive power of the spectral lines of rubidium, they are considered as the significant factors for the determination of rubidium. The optimization parameters of the instrument were obtained by orthogonal experiments and further single factor experiment, which are 0. 60 L . min-1 of atomizer flow, 60 r . min-1 of pump speed, and 1 150 W of high-frequency power. The same experiments were repeated a week later with the optimization parameters of the instrument, and the relative errors of the determination results are less than 0. 5% when the concentration of rubidium chloride ranged from 0. 09% to 0. 18%. As the concentration of rubidium chloride is 0. 06%, the relative errors of the determination results are -1. 7%. The determination of lithium chloride and potassium chloride in the high concentration of the aqueous solutions was studied under the condition of similar instrument parameters. It was found by comparison that the determination results of lithium

  2. Clocks for airborne systems. [performance of rubidium oscillators

    NASA Technical Reports Server (NTRS)

    Houlding, N.

    1982-01-01

    The potential performance of compact oscillators, needed for the development of accurate clocks for future airborne systems (such as Identification Friend or Foe schemes), is addressed. In particular, extensive testing of rubidium oscillators manufactured by Efratom is discussed. The results indicate that an accuracy of better than 10 microseconds should be achievable in tactical aircraft provided that appropriate measures are adopted to counter the many environmental factors. In a favorable environment a stability of better than 5 x 10 to the -13th power for one day is achievable with present commercial units, but improvements are required to suit operation in an aircraft. With further development of rubidium controlled clocks the ultimate limitation on time accuracy in aircraft will probably be associated with time dissemination, maintenance difficulties and doctrinal hurdles.

  3. Resonant diffraction of synchrotron radiation in rubidium dihydrophosphate crystals

    SciTech Connect

    Mukhamedzhanov, E. Kh.; Kovalchuk, M. V.; Borisov, M. M.; Ovchinnikova, E. N.; Troshkov, E. V.; Dmitrienko, V. E.

    2010-03-15

    Purely resonant Bragg reflections 006, 55bar 0, and 666 in a rubidium dihydrophosphate (RbH{sub 2}PO{sub 4}) crystal at the K edge of rubidium have been experimentally and theoretically investigated. These reflections remain forbidden when the resonant dipole-dipole (E1E1) contribution to the resonant atomic factor is taken into account; they may be due to the dipole-quadrupole (E1E2) transitions as well as to the anisotropy atomic factor, which is caused by thermal atomic displacements (thermally induced contribution) and/or local jumps of hydrogen atoms. A numerical simulation showed that, at room temperature (experimental conditions), the thermally induced contribution to the 'forbidden' reflections is dominant.

  4. Ionization spectra of highly Stark-shifted rubidium Rydberg states

    NASA Astrophysics Data System (ADS)

    Grimmel, Jens; Stecker, Markus; Kaiser, Manuel; Karlewski, Florian; Torralbo-Campo, Lara; Günther, Andreas; Fortágh, József

    2017-07-01

    We report on the observation and numerical calculation of ionization spectra of highly Stark-shifted Rydberg states of rubidium beyond the classical ionization threshold. In the numerical calculations, a complex absorbing potential (CAP) allows us to predict the energy levels and ionization rates of Rydberg states in this regime. Our approach of adjusting the CAP to the external electric field reduces the number of free parameters from one per resonance to a single one. Furthermore, we have measured the ionization spectra of magneto-optically trapped rubidium atoms which are excited to principal quantum numbers of 43 and 70 at various electric fields. The emerging ions are detected using an ion optics. We find good agreement between the numerically and experimentally obtained spectra.

  5. Recycle Rate in a Pulsed, Optically Pumped Rubidium Laser

    SciTech Connect

    Miller, Wooddy S.; Sulham, Clifford V.; Holtgrave, Jeremy C.; Perram, Glen P.

    2010-10-08

    A pulsed, optically pumped rubidium laser operating in analogy to the diode pumped alkali laser (DPAL) system at pump intensities as high as 750 kW/cm{sup 2} has been demonstrated with output energies of up to 13 {mu}J/pulse. Output energy is dramatically limited by spin-orbit relaxation rates under these high intensity pump conditions. More than 250 photons are available for every rubidium atom in the pumped volume, requiring a high number of cycles per atom during the 2-8 ns duration of the pump pulse. At 550 Torr of ethane, the spin-orbit relaxation rate is too slow to effectively utilize all the incident pump photons. Indeed, a linear dependence of output energy on pump pulse duration for fixed pump energy is demonstrated.

  6. Extreme electron-phonon coupling in magnetic rubidium sesquioxide

    NASA Astrophysics Data System (ADS)

    de Groot, Robert; Attema, Jisk; Riyadi, S.; Blake, Greame; de Wijs, Gilles; Palstra, Thomas

    2008-03-01

    Rb2O3 is a black, opaque oxide. Early work suggests that the stability range of the sesquioxide phase in the rubidium-oxygen phase diagram is rather broad. Rb2O3 remains cubic down to the lowest temperature measured (5 K). The oxygens form dumbbells with interatomic distances in between those of peroxide and superoxide anions, and strong athermal motion persists down to low temperatures. [1] Electronic-structure calculations show that the dynamics at low temperature is caused by 6 phonon modes of zero frequency, which induce a very strong electron-phonon interaction. The softness of half of these modes is suppressed by the application of pressure. Calculated using the average oxygen positions, rubidium sesquioxide is a half-metallic ferromagnet. [2] [1] CR CHIM (11-13): 591-594 NOV 1999[2] JACS 127 (46): 16325-16328 NOV 23 2005

  7. Design and Preliminary Characterization of the USNO Rubidium Fountain

    DTIC Science & Technology

    2005-08-01

    Design and Preliminary Characterization of the USNO Rubidium Fountain Steven Peil, Scott Crane, Thomas B. Swanson, and Christopher R. Ekstrom Time ...and power servos are among the user-configurable electronics modules that we designed. Data acquisition and timing are executed with compact PCI...burden for the collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching

  8. X-ray spectrographic determination of cesium and rubidium

    USGS Publications Warehouse

    Axelrod, J.M.; Adler, I.

    1957-01-01

    An x-ray spectrographic method for the determination of rubidium and cesium was developed, using the internal-standard method and a four-channel flat-crystal spectrograph. The sensitivity is within 0.1% for cesia and 0.02% for rubidia; the precision is within 10% of the amount present. Results agree well with those obtained by flame photometry and by radio-activation.

  9. Electronically excited rubidium atom in a helium cluster or film

    NASA Astrophysics Data System (ADS)

    Leino, Markku; Viel, Alexandra; Zillich, Robert E.

    2008-11-01

    We present theoretical studies of helium droplets and films doped with one electronically excited rubidium atom Rb∗ (P2). Diffusion and path integral Monte Carlo approaches are used to investigate the energetics and the structure of clusters containing up to 14 helium atoms. The surface of large clusters is approximated by a helium film. The nonpair additive potential energy surface is modeled using a diatomic in molecule scheme. Calculations show that the stable structure of Rb∗Hen consists of a seven helium atom ring centered at the rubidium, surrounded by a tirelike second solvation shell. A very different structure is obtained when performing a "vertical Monte Carlo transition." In this approach, a path integral Monte Carlo equilibration starts from the stable configuration of a rubidium atom in the electronic ground state adsorbed to the helium surface after switching to the electronically excited surface. In this case, Rb∗Hen relaxes to a weakly bound metastable state in which Rb∗ sits in a shallow dimple. The interpretation of the results is consistent with the recent experimental observations [G. Auböck et al., Phys. Rev. Lett. 101, 035301 (2008)].

  10. [Determination of rubidium and cesium in chloride type oilfield water by flame atomic absorption spectrometry].

    PubMed

    Ye, Xiu-Shen; Zhang, Shan-Ying; Li, Hai-Jun; Li, Wu; Wu, Zhi-Jian

    2009-03-01

    Flame atomic absorption spectrometry (FAAS) was applied to the determination of rubidium and cesium in chloride type oilfield water by considering the interferences of the coexistent K+, Na+, Ca2+, and Mg2+ ions, Standard curve method and standard addition method were compared in the determination of rubidium and cesium in the simulated oilfield water and the real oilfield water from the Nanyishan region in Qaidam Basin. Although rubidium and cesium have similar physical-chemical properties, they present different characters during their analyses using the FAAS technique. When the standard addition method was used for the determination of rubidium and cesium in the simulated oilfield water, the results of rubidium were very poor, whereas the results of cesium were satisfactory. When the standard curve method was used for the determination of rubidium and cesium in the simulated oilfield water, the results of both rubidium and cesium were satisfactory within the linear ranges of the standard curves. For the real oilfield water, standard addition method is also only applicable for the determination of cesium with a recovery ranging from 90% to 110%. While standard curve method is applicable for the determination of both rubidium and cesium with a recovery ranging from 90% to 110%.

  11. The Kinetics of Ouabain Inhibition and the Partition of Rubidium Influx in Human Red Blood Cells

    PubMed Central

    Beauge, L. A.; Adragna, Norma

    1971-01-01

    In the development of ouabain inhibition of rubidium influx in human red blood cells a time lag can be detected which is a function of at least three variables: the concentrations of external sodium, rubidium, and ouabain. The inhibition is antagonized by rubidium and favored by sodium. Similar considerations could be applied to the binding of ouabain to membrane sites. The total influx of rubidium as a function of external rubidium concentration can be separated into two components: (a) a linear uptake not affected by external sodium or ouabain and not requiring an energy supply, and (b) a saturable component. The latter component, on the basis of the different effects of the aforementioned factors, can be divided into three fractions. The first is ouabain-sensitive, inhibited by external sodium at low rubidium, and requires an energy supply; this represents about 70–80% of the total uptake and is related to the active sodium extrusion mechanism. The second is ouabain-insensitive, activated by external sodium over the entire range of rubidium concentrations studied, and dependent on internal ATP; this represents about 15% of the total influx; it could be coupled to an active sodium extrusion or belong to a rubidium-potassium exchange. The third, which can be called residual influx, is ouabain-insensitive, unaffected by external sodium, and independent of internal ATP; this represents about 10–20% of the total influx. PMID:5553102

  12. Nerve fibre refractory period in patients treated with rubidium and lithium.

    PubMed Central

    Betts, R P; Paschalis, C; Jarratt, J A; Jenner, F A

    1978-01-01

    Nerve fibre refractory period distributions have been measured on the median nerves of six manic-depressive patients controlled with lithium carbonate, three chronic patients (two manic-depressives and one catatonic schizophrenic) controlled with rubidium chloride, and eight normal volunteers. Rubidium prolonged the refractory periods of all nerve fibres while lithium increased only the longer refractory periods. PMID:690649

  13. Structure of the hydrated and dimethyl sulfoxide solvated rubidium ions in solution.

    PubMed

    D'Angelo, Paola; Persson, Ingmar

    2004-05-31

    The structure of the hydrated and the dimethyl sulfoxide solvated rubidium ions in solution has been determined by means of large-angle X-ray scattering (LAXS) and extended X-ray absorption fine structure (EXAFS) studies. The models of the hydrated and dimethyl sulfoxide solvated rubidium ions fitting the experimental data best are square antiprisms with Rb-O bond distances of 2.98(2) and 2.98(3) A, respectively. The EXAFS data show a significant asymmetry in the Rb-O bond distance distribution with C(3) values of 0.0076 and 0.015 A(3), respectively. No second hydration sphere is observed around the hydrated rubidium ion. The dimethyl sulfoxide solvated rubidium ion displays a Rb-O-S bond angle of ca. 130 degrees, which is typical for a medium hard electron acceptor such as rubidium.

  14. Was Bijvoet right? Sodium rubidium (+)-tartrate tetrahydrate revisited.

    PubMed

    Lutz, Martin; Schreurs, Antoine M M

    2008-08-01

    The first determination of the absolute configuration of an organic compound was published in 1951 on sodium rubidium (+)-tartrate tetrahydrate, Na(+).Rb(+).C(4)H(4)O(6)(2-).4H(2)O, but the atomic coordinates are not available in the public literature. This structure has therefore been redetermined using current equipment. The most up-to-date techniques for the determination of the absolute configuration have been applied and the question posed in the title can be answered with an unequivocal 'yes'.

  15. Measurement of Rubidium Number Density Under Optically Thick Conditions

    DTIC Science & Technology

    2010-11-15

    Voigt profiles . A Voigt line shape is represented by equations 4.1 and 4.2. (4.1) gV oigt(λ, λFF ′) = 1 2π √ π ∫ ∞ −∞  ∆λL exp(−t2) (λ− λFF ′ − t ∆λD...various cell conditions of temperature and pressure were then fit to a pressure broadened Voigt profile thereby allowing the determination of the...broadened Voigt profile thereby allowing the determination of the rubidium number den- sity. 1. Background In recent years, alkali metals have garnered a

  16. Study on photoionization in a rubidium diode-pumped alkali laser gain medium with the optogalvanic method.

    PubMed

    Ge, Lun; Hua, Weihong; Wang, Hongyan; Yang, Zining; Xu, Xiaojun

    2013-01-15

    We use the optogalvanic method to calculate the concentration of rubidium ions produced by photoionization in a Rb diode-pumped alkali laser gain medium. With bias voltage added across the electrodes of a rubidium hollow cathode lamp, the measured optogalvanic current is 2.3×10(-7) A. Further study shows that the rubidium ion concentration is proportional to the pump intensity, and the drift velocity of rubidium ions is proportional to the bias voltage. When the photoionization process reaches dynamic equilibrium, the rubidium ion concentration will not increase with growing rubidium atom density. The calculated rubidium ion concentration is 1.5×10(5)-10(6) according to the experiment, and the ionization degree is less than 2.4×10(-7).

  17. Evidence for the ordered release of rubidium ions occluded within the Na,K-ATPase of mammalian kidney.

    PubMed Central

    Glynn, I M; Howland, J L; Richards, D E

    1985-01-01

    When Na,K-ATPase containing occluded rubidium ions is exposed to orthophosphate, in the presence of magnesium ions, there is a rapid release of half or all of the occluded ions. This behaviour is observed irrespective of whether the occluded-rubidium form of the enzyme is generated by putting the unphosphorylated enzyme in a sodium-free medium containing rubidium ions, or by allowing rubidium ions to catalyse the hydrolysis of phosphoenzyme made by adding ATP to enzyme suspended in a medium containing sodium and magnesium ions. The release of occluded rubidium ions by orthophosphate requires the presence of magnesium, presumably because phosphorylation is necessary. Whether the addition of orthophosphate causes the rapid release of all or of half of the occluded rubidium depends on whether free rubidium (or potassium, thallium or (probably) caesium ions) are present in the medium at the time the orthophosphate is added. In the absence of free ions of these species, all of the occluded rubidium is released. In their presence (in adequate concentration), only half of the occluded rubidium is released. The relative effectiveness of the different potassium congeners in preventing the rapid release of 50% of the occluded rubidium when orthophosphate is added is: thallium greater than rubidium greater than potassium greater than caesium. Lithium and sodium are ineffective even at high concentrations, and sodium ions strongly antagonize the effect of free rubidium ions. In a sodium-free, Tris medium, the concentration of free rubidium ions necessary for a half-maximal effect is about 30 microM. In a medium containing 250 microM-free rubidium, the concentration of sodium necessary to reduce the effect of free rubidium by 50% is about 500 microM. These figures are compatible with the hypothesis that the free rubidium or other ions act at the potassium-loading sites at the extracellular face of the pump. By starting with enzyme occluding unlabelled rubidium, and using 86Rb

  18. Cell rubidium uptake: a method for studying functional heterogeneity in the nephron

    SciTech Connect

    Beck, F.X.; Doerge, A.B.; Bluemner, E.G.; Giebisch, G.; Thurau, K.

    1988-03-01

    Rubidium uptake into individual tubule cells of rat renal cortex as measured by energy-dispersive X-ray microanalysis on freeze dried cryosections was used as an index of potassium transport. Over a 30 second period following intravenous infusion of rubidium (0.5 mmol/kg body wt) rubidium content increased in all cells. After 30 seconds, rubidium contents were (in mmol/kg dry wt): 225 +/- 8 in distal convoluted tubule cells, 156 +/- 7 in connecting tubule cells, 110 +/- 7 in principal cells, 86 +/- 4 in proximal tubule cells and 24 +/- 2 in intercalated cells (mean +/- SEM). When distal sodium and potassium transport were stimulated by hypertonic saline loading, rubidium uptake was selectively increased into distal convoluted tubule cells by 38%, into connecting tubule cells by 36%, and into principal cells by 52%. However, rubidium uptake into proximal tubule and into intercalated cells remained unchanged. The preferential uptake of rubidium into distal convoluted tubule cells, connecting tubule cells, and principal cells correlates well with the known transport functions of sodium and potassium, whereas intercalated cells are distinguished by low sodium and potassium transport activity.

  19. Predictions for collisional frequency shifts of ultracold rubidium atomic clocks

    NASA Astrophysics Data System (ADS)

    Kokkelmans, S. J. J. M. F.; Verhaar, B. J.; Heinzen, D. J.; Gibble, K.

    1997-04-01

    A few years ago atomic fountains using cold ^133Cs atoms led to a breakthrough in the field of atomic frequency standards(A. Clairon, C. Salomon, S. Guellati, and W. D. Phillips, Europhys. Lett. 16), 165 (1991); K. Gibble and S. Chu, Phys. Rev. Lett. 70, 1771 (1993).. It was soon found that the frequency shifts induced by collisions between atoms during their fountain orbit stand in the way to drawing the full benefits from this development. A possible way out is to switch to another atomic species(K. Gibble and B.J. Verhaar, Phys. Rev. A 52), 3370 (1995).. Recent experiments have made it possible to determine cold collision parameters for pairs of rubidium atoms with unprecedented accuracy(J.M. Vogels, C.C. Tsai, R.S. Freeland, S.J.J.M.F. Kokkelmans, B.J. Verhaar, and D.J. Heinzen (submitted).). Making use of these parameters we predict the collisional frequency shifts for a ^87Rb and a ^85Rb laser-cooled clock. Our results show the prospects for new atomic clocks based on ultracold rubidium to be promising.

  20. Pulsed high magnetic field measurement with a rubidium vapor sensor

    NASA Astrophysics Data System (ADS)

    George, S.; Bruyant, N.; Béard, J.; Scotto, S.; Arimondo, E.; Battesti, R.; Ciampini, D.; Rizzo, C.

    2017-07-01

    We present a new technique to measure pulsed magnetic fields based on the use of rubidium in gas phase as a metrological standard. We have therefore developed an instrument based on laser inducing transitions at about 780 nm (D2 line) in rubidium gas contained in a mini-cell of 3 mm × 3 mm cross section. To be able to insert such a cell in a standard high-field pulsed magnet, we have developed a fibred probe kept at a fixed temperature. Transition frequencies for both the π (light polarization parallel to the magnetic field) and σ (light polarization perpendicular to the magnetic field) configurations are measured by a commercial wavemeter. One innovation of our sensor is that in addition to the usual monitoring of the light transmitted by the Rb cell, we also monitor the fluorescence emission of the gas sample from a volume of 0.13 mm3. Our sensor has been tested up to about 58 T.

  1. Pulsed high magnetic field measurement with a rubidium vapor sensor.

    PubMed

    George, S; Bruyant, N; Béard, J; Scotto, S; Arimondo, E; Battesti, R; Ciampini, D; Rizzo, C

    2017-07-01

    We present a new technique to measure pulsed magnetic fields based on the use of rubidium in gas phase as a metrological standard. We have therefore developed an instrument based on laser inducing transitions at about 780 nm (D2 line) in rubidium gas contained in a mini-cell of 3 mm × 3 mm cross section. To be able to insert such a cell in a standard high-field pulsed magnet, we have developed a fibred probe kept at a fixed temperature. Transition frequencies for both the π (light polarization parallel to the magnetic field) and σ (light polarization perpendicular to the magnetic field) configurations are measured by a commercial wavemeter. One innovation of our sensor is that in addition to the usual monitoring of the light transmitted by the Rb cell, we also monitor the fluorescence emission of the gas sample from a volume of 0.13 mm(3). Our sensor has been tested up to about 58 T.

  2. Labeling Feral Spruce Budworm (Lepidoptera: Tortricidae) Populations With Rubidium.

    PubMed

    MacKinnon, Wayne; Eveleigh, Eldon; Silk, Peter; Forbes, Glen

    2016-04-01

    Rubidium (Rb) is a trace element that occurs naturally in low concentrations and is easily absorbed by plants, making it a useful tool for labeling insect defoliators, such as spruce budworm (Choristoneura fumiferana Clemens). Balsam fir trees (Abies balsamea (L.) Miller) injected with either 8 or 16 g per tree of rubidium chloride (RbCl) showed quick uptake and distribution throughout the crown, with no negative effects on tree shoot growth or spruce budworm survival and development. Adult spruce budworm that fed as larvae on trees injected with RbCl were clearly labeled, with significantly higher Rb concentrations than the background levels found in adults that fed as larvae on control trees. Rb concentrations in feral spruce budworm adults for both the 8 g (9 µg/g) and 16 g (25 µg/g) per tree treatments were at least five times lower than those in laboratory-reared adults on 1,000 µg/g RbCl diet (125 µg/g); survival, development, pupal weight, sex ratio, and mating status of spruce budworm were not adversely affected by Rb treatment. Egg masses laid by feral females that fed as larvae on Rb-labeled trees were also labeled with Rb. Injecting trees with RbCl is a viable technique for labeling feral spruce budworm populations to help distinguish local populations from immigrants to better evaluate the success of early intervention strategies such as mating disruption. © Crown copyright 2016.

  3. The Rubidium-Crystal Oscillator Hybrid Development Program

    NASA Technical Reports Server (NTRS)

    Vig, J. R.; Rosati, V. J.

    1984-01-01

    The rubidium-crystal oscillator hybrid (RbXO) will make precise time available to systems that lack the power required by atomic frequency standards. The RbXO consists of two subassemblies in separate enclosures. One contains a small rubidium frequency standard (RFS) without its internal oven-controlled crystal oscillator (OCXO), plus interface circuits. The second contains a low-power OCXO, and additional interface circuits. The OCXO is on continuously. Periodically, e.g., once a week, the user system applies power to the RFS. After the few necessary for the warmup of the RFS, the interface circuits adjust the frequency of the OCXO to the RFS reference, then shut off the RFS. The OCXO enclosure is separable from the RFS enclosure so that manpacks will be able to operate with minimum size, weight, and power consumption, while having the accuracy of the RFS for the duration of a mission. A prototype RbXO's RFS has operated successfully for 4200 on-off cycles. Parallel efforts on a Phase 2 RbXO development are in progress. Two sources for the RbXO are scheduled to be available during 1986.

  4. TF-4020A: TFL's new compact military rubidium standard

    NASA Astrophysics Data System (ADS)

    Eltsufin, E.; Stern, A.

    1992-06-01

    A military rubidium frequency standard model TF-4020A is described and analyzed. It is a compact (volume less than 500 cc) military rubidium standard and meets MIL-E-5400 (airborne electronic equipment) class 2 (-55 C to +71 C, 70,000 ft). The physics package shown is extremely small (87 cc) and comprises lamp and cavity subassembly and a twofold magnetic field. The oscillator is a miniature oven controlled crystal oscillator with a SC (Stress Compensated) cut crystal for a low vibration susceptibility. The main effort during the design process was concentrated on the design of reliable circuits: general reliability, stability and low susceptibility to external and internal influences like temperature, vibration and electromagnetic interference (EMI). Key features of the unit are: compact design; extremely small physics package (87 cc) with a special rugged design to withstand strong vibration; high stability over the wide operating temperature range of -55 C to +71 C; low susceptibility to EMI; low sensitivity to external DC and AC magnetic field; excellent short term stability of 7 x 10(exp -12)/square root of tau for tau greater than 0.1 s and less than 300 s; excellent long term stability of 1 x 10(exp -11) per month; and versatility to adopt versions without size increase.

  5. Compact microwave cavity for high performance rubidium frequency standards

    NASA Astrophysics Data System (ADS)

    Stefanucci, Camillo; Bandi, Thejesh; Merli, Francesco; Pellaton, Matthieu; Affolderbach, Christoph; Mileti, Gaetano; Skrivervik, Anja K.

    2012-10-01

    The design, realization, and characterization of a compact magnetron-type microwave cavity operating with a TE011-like mode are presented. The resonator works at the rubidium hyperfine ground-state frequency (i.e., 6.835 GHz) by accommodating a glass cell of 25 mm diameter containing rubidium vapor. Its design analysis demonstrates the limitation of the loop-gap resonator lumped model when targeting such a large cell, thus numerical optimization was done to obtain the required performances. Microwave characterization of the realized prototype confirmed the expected working behavior. Double-resonance and Zeeman spectroscopy performed with this cavity indicated an excellent microwave magnetic field homogeneity: the performance validation of the cavity was done by achieving an excellent short-term clock stability as low as 2.4 × 10-13 τ-1/2. The achieved experimental results and the compact design make this resonator suitable for applications in portable atomic high-performance frequency standards for both terrestrial and space applications.

  6. Compact microwave cavity for high performance rubidium frequency standards.

    PubMed

    Stefanucci, Camillo; Bandi, Thejesh; Merli, Francesco; Pellaton, Matthieu; Affolderbach, Christoph; Mileti, Gaetano; Skrivervik, Anja K

    2012-10-01

    The design, realization, and characterization of a compact magnetron-type microwave cavity operating with a TE(011)-like mode are presented. The resonator works at the rubidium hyperfine ground-state frequency (i.e., 6.835 GHz) by accommodating a glass cell of 25 mm diameter containing rubidium vapor. Its design analysis demonstrates the limitation of the loop-gap resonator lumped model when targeting such a large cell, thus numerical optimization was done to obtain the required performances. Microwave characterization of the realized prototype confirmed the expected working behavior. Double-resonance and Zeeman spectroscopy performed with this cavity indicated an excellent microwave magnetic field homogeneity: the performance validation of the cavity was done by achieving an excellent short-term clock stability as low as 2.4 × 10(-13) τ(-1/2). The achieved experimental results and the compact design make this resonator suitable for applications in portable atomic high-performance frequency standards for both terrestrial and space applications.

  7. Long-range interactions between rubidium and potassium Rydberg atoms

    NASA Astrophysics Data System (ADS)

    Samboy, Nolan

    2017-03-01

    We investigate the long-range, two-body interactions between rubidium and potassium atoms in highly excited (n =70 ) Rydberg states. After establishing properly symmetrized asymptotic basis states, we diagonalize an interaction Hamiltonian consisting of the standard Coulombic potential expansion and atomic fine structure to calculate electronic potential energy curves. We find that when both atoms are excited to either the 70 s state or the 70 p state, both the Ω =0+ symmetry interactions and the Ω =0- symmetry interactions demonstrate a deep potential well capable of supporting many bound levels; the sizes of the corresponding dimer states are of the order of 2.25 μ m . We establish n -scaling relations for the equilibrium separation Re and the dissociation energy De and find these relations to be consistent with similar calculations involving the homonuclear interactions between rubidium and cesium. We discuss the specific effects of ℓ mixing and the exact composition of the calculated potential well via the expansion coefficients of the asymptotic basis states. Finally, we apply a Landau-Zener treatment to show that the dimer states are stable with respect to predissociation.

  8. Rubidium atomic frequency standards for GPS Block IIR

    NASA Technical Reports Server (NTRS)

    Riley, William J.

    1990-01-01

    The Rubidium Atomic Frequency Standards (RAFS) were provided for the GPS Block IIR NAVSTAR satellites. These satellites will replenish and upgrade the space segment of the Global Positioning System in the mid 1990s. The GPS RAFS Rb clocks are the latest generation of the high-performance rubidium frequency standards. They offer an aging rate in the low pp 10(exp 14)/day range and a drift-corrected 1-day stability in the low pp 10(exp 14) range. The Block IIR version of these devices will have improved performance, higher reliability, smaller size, and greater radiation hardness. The GPS Block IIR atomic clocks have a natural frequency configuration whereby they output a frequency of about 13.4 MHz that is a submultiple of the atomic resonance of Rb (or Cs). The RAFS operates at a low, fixed C-field for increased stability. The GPS Block IIR RAFS design, including the changes and improvements made, and the test results obtained are described.

  9. Rubidium atomic frequency standards for GPS Block IIR

    NASA Technical Reports Server (NTRS)

    Riley, William J.

    1990-01-01

    The Rubidium Atomic Frequency Standards (RAFS) were provided for the GPS Block IIR NAVSTAR satellites. These satellites will replenish and upgrade the space segment of the Global Positioning System in the mid 1990s. The GPS RAFS Rb clocks are the latest generation of the high-performance rubidium frequency standards. They offer an aging rate in the low pp 10(exp 14)/day range and a drift-corrected 1-day stability in the low pp 10(exp 14) range. The Block IIR version of these devices will have improved performance, higher reliability, smaller size, and greater radiation hardness. The GPS Block IIR atomic clocks have a natural frequency configuration whereby they output a frequency of about 13.4 MHz that is a submultiple of the atomic resonance of Rb (or Cs). The RAFS operates at a low, fixed C-field for increased stability. The GPS Block IIR RAFS design, including the changes and improvements made, and the test results obtained are described.

  10. Measurement of the lifetime of rubidium atoms in a dark magneto-optical trap

    SciTech Connect

    Permyakova, O I; Yakovlev, A V; Chapovskii, P L

    2008-09-30

    The lifetimes of rubidium atoms in a dark magneto-optical trap are measured at different populations of the 'bright' and 'dark' hyperfine states of captured atoms. It is found that the lifetime of atoms in the trap decreases if they spend more time in the bright state. A simple explanation of this effect is proposed which is based on the increase in the transport cross section for collisions of thermal rubidium atoms surrounding the trap with cold rubidium atoms upon their electronic excitation. (laser cooling)

  11. Transmission degradation and preservation for tapered optical fibers in rubidium vapor.

    PubMed

    Lai, Meimei; Franson, James D; Pittman, Todd B

    2013-04-20

    The use of subwavelength diameter tapered optical fibers (TOFs) in warm rubidium vapor has recently been identified as a promising system for realizing ultralow-power nonlinear optical effects. However, at the relatively high atomic densities needed for many of these experiments, rubidium atoms accumulating on the TOF surface can cause a significant loss of overall transmission through the fiber. Here we report direct measurements of the time scale associated with this transmission degradation for various rubidium density conditions. Transmission is affected almost immediately after the introduction of rubidium vapor into the system, and declines rapidly as the density is increased. More significantly, we show how a heating element designed to raise the TOF temperature can be used to reduce this transmission loss and dramatically extend the effective TOF transmission lifetime.

  12. A kind of magnetron cavity used in rubidium atomic frequency standards

    NASA Astrophysics Data System (ADS)

    Shiyu, Yang; Jingzhong, Cui; Jianhui, Tu; Yaoting, Liang

    2011-12-01

    Research on the magnetron cavity used in the rubidium atomic frequency standards is developed, through which the main characteristic parameters of the magnetron cavity are studied, mainly including the resonant frequency, quality factor and oscillation mode. The resonant frequency and quality factor of the magnetron cavity were calculated, and the test results of the resonant frequency agreed well with the calculation theory. The test results also show that the resonant frequency of the magnetron cavity can be attenuated to 6.835 GHz, which is the resonant frequency of the rubidium atoms, and the Q-factor can be attenuated to 500-1000. The oscillation mode is a typical TE011 mode and is the correct mode needed for the rubidium atomic frequency standard. Therefore these derivative magnetron cavities meet the requirements of the rubidium atomic frequency standards well.

  13. A New Synchronized Miniature Rubidium Oscillator with an Auto-Adaptive Disciplining Filter

    DTIC Science & Technology

    2001-11-01

    33rd Annual Precise Time and Time Interval (PTTI) Meeting A NEW SYNCHRONIZED MINIATURE RUBIDIUM DISCIPLINING FILTER OSCILLATOR WITH AN AUTO...ADAPTIVE Pascal Rochat and Bernard Leuenberger Temex Neuchfitel Time SA, Switzerland Abstract A new rubidium line (SRO) integrating timing functions and... time interval measurements was developed using an auto-adaptive disciplining algorithm. This led to an ultra-stable time & frequency machine usable

  14. Optimization of a rubidium magnetometer based on nonlinear optical rotation

    NASA Astrophysics Data System (ADS)

    Chan, Lok Fai; Jacome, L. R.; Guttikonda, Srikanth; Bahr, Eric; Kimball, Derek

    2009-11-01

    Atomic spin polarization of alkali atoms in the ground state can survive thousands of collisions with paraffin-coated cell walls. The resulting long spin-relaxation times achieved in evacuated, paraffin-coated cells enable precise measurement of atomic spin precession and energy shifts of ground-state Zeeman sublevels. In the present work, nonlinear magneto-optical rotation with frequency-modulated light (FM NMOR) is used to measure magnetic-field-induced spin precession for rubidium atoms contained in a paraffin-coated cell. We discuss optimization of the shot-noise-projected magnetometer sensitivity and practical implementation of the Rb magnetometer. The magnetometer will be applied to searches for anomalous spin-dependent interactions of the proton.

  15. Nondegenerate four-wave mixing in rubidium vapor: Transient regime

    SciTech Connect

    Becerra, F. E.; Willis, R. T.; Rolston, S. L.; Orozco, L. A.; Carmichael, H. J.

    2010-10-15

    We investigate the transient response of the generated light from four-wave mixing (FWM) in the diamond configuration using a step-down field excitation. The transients show fast decay times and oscillations that depend on the detunings and intensities of the fields. A simplified model taking into account the thermal motion of the atoms, propagation, absorption, and dispersion effects shows qualitative agreement with the experimental observations with the energy levels in rubidium (5S{sub 1/2}, 5P{sub 1/2}, 5P{sub 3/2}, and 6S{sub 1/2}). The atomic polarization comes from all the contributions of different velocity classes of atoms in the ensemble modifying dramatically the total transient behavior of the light from FWM.

  16. Experimental evidence for two different dynamical regimes in liquid rubidium

    NASA Astrophysics Data System (ADS)

    Demmel, Franz; Morkel, Christoph

    2017-08-01

    We present evidence for changes in the dynamics of liquid rubidium with rising temperature. The thermal expansion of this liquid alkali metal shows a changing derivative with temperature in a temperature range of about 400-500 K. With neutron scattering the amplitude at the structure factor maximum demonstrates a changing slope with increasing temperature. A derived averaged structural relaxation time can be understood that an additional relaxation process sets in upon cooling. The deduced generalized viscosity and high frequency shear modulus indicate a change in dynamics in the same temperature range. All these findings point to a change in dynamics of the equilibrium liquid metal state with a dynamical crossover from a viscous to a fluid-like liquid metal well above the melting point.

  17. Demonstration of bicolor slow-light channelization in rubidium vapor

    SciTech Connect

    Bashkansky, Mark; Fatemi, Fredrik K.; Reintjes, John; Dutton, Zachary; Steiner, Michael

    2007-02-15

    We experimentally demonstrate a proof-of-principle of a previously proposed 'channelization' architecture for wideband slow-light propagation in atomic vapors using electromagnetically induced transparency (EIT). We use two optical frequencies to generate a sine wave signal which is delayed in rubidium vapor. The optical frequencies were tuned near the EIT resonances of two Zeeman sublevels, which are shifted from each other well beyond the EIT linewidth by a uniform magnetic field. We varied the Zeeman shift between these two levels (relative to the optical frequency splitting) and measured the delay versus Zeeman shift. Significant delays were observed and were in agreement with a theoretical model treating each Zeeman sublevel as part of an independent three-level system. We achieved delay of a signal with a bandwidth 16 times the EIT linewidth and confirmed our earlier theoretical models that delay occurs only when the optical spectral separation slightly exceeds the Zeeman splitting.

  18. Laser-pumped paraffin-coated cell rubidium frequency standard

    SciTech Connect

    Bandi, Thejesh; Affolderbach, Christoph; Mileti, Gaetano

    2012-06-15

    We have realized and studied a rubidium atomic frequency standard based on a paraffin-coated cell, exhibiting a short-term frequency stability <3 Multiplication-Sign 10{sup -12} {tau}{sup -1/2} between {tau} = 1 and 100 s. Characterization of the wall-coating is performed by measuring the T{sub 1} and T{sub 2} relaxation times. Perturbations of the medium- to long-term clock stability, due to variations in the laser-intensity, laser frequency, the microwave power shift, and the shifts due to temperature variations are measured and analyzed. A method for reducing the intensity light-shift by detuning the laser frequency and the resulting improvement in clock stability is demonstrated. This work is of relevance for further improvements on Rb cell standards using anti-relaxation wall-coating technology.

  19. Interactions of Rubidium and Metastable Argon at Ultracold Temperatures

    NASA Astrophysics Data System (ADS)

    Shaffer, M. K.

    2005-05-01

    We are investigating the interaction between ultracold rubidium (Rb) and ultracold metastable argon (Ar*) simultaneously confined in a dual species magneto-optical trap (MOT). We will report on recent quantitative measurements of the inter-species trap loss coefficients and present our preliminary results on photoassociative spectra of the Rb-Ar* complex. We will also report on studies of Penning and associative ionization in the MOT using a modified residual gas analyzer (RGA) as a detector. Finally, we will discuss the prospects for producing and spatially confining ultracold ground state RbAr, a weakly-bound van der Waals molecule. Support provided by the National Science Foundation and the Office of Naval Research.

  20. Hydrocarbon-free resonance transition 795-nm rubidium laser

    SciTech Connect

    Wu, S Q; Soules, T F; Page, R H; Mitchell, S C; Kanz, V K; Beach, R J

    2008-01-09

    An optical resonance transition rubidium laser (5{sup 2}P{sub 1/2} {yields} 5{sup 2}S{sub 1/2}) is demonstrated with a hydrocarbon-free buffer gas. Prior demonstrations of alkali resonance transition lasers have used ethane as either the buffer gas or a buffer gas component to promote rapid fine-structure mixing. However, our experience suggests that the alkali vapor reacts with the ethane producing carbon as one of the reaction products. This degrades long term laser reliability. Our recent experimental results with a 'clean' helium-only buffer gas system pumped by a Ti:sapphire laser demonstrate all the advantages of the original alkali laser system, but without the reliability issues associated with the use of ethane.

  1. Laser-pumped paraffin-coated cell rubidium frequency standard

    NASA Astrophysics Data System (ADS)

    Bandi, Thejesh; Affolderbach, Christoph; Mileti, Gaetano

    2012-06-01

    We have realized and studied a rubidium atomic frequency standard based on a paraffin-coated cell, exhibiting a short-term frequency stability <3 × 10-12 τ-1/2 between τ = 1 and 100 s. Characterization of the wall-coating is performed by measuring the T1 and T2 relaxation times. Perturbations of the medium- to long-term clock stability, due to variations in the laser-intensity, laser frequency, the microwave power shift, and the shifts due to temperature variations are measured and analyzed. A method for reducing the intensity light-shift by detuning the laser frequency and the resulting improvement in clock stability is demonstrated. This work is of relevance for further improvements on Rb cell standards using anti-relaxation wall-coating technology.

  2. High efficiency coherent optical memory with warm rubidium vapour

    PubMed Central

    Hosseini, M.; Sparkes, B.M.; Campbell, G.; Lam, P.K.; Buchler, B.C.

    2011-01-01

    By harnessing aspects of quantum mechanics, communication and information processing could be radically transformed. Promising forms of quantum information technology include optical quantum cryptographic systems and computing using photons for quantum logic operations. As with current information processing systems, some form of memory will be required. Quantum repeaters, which are required for long distance quantum key distribution, require quantum optical memory as do deterministic logic gates for optical quantum computing. Here, we present results from a coherent optical memory based on warm rubidium vapour and show 87% efficient recall of light pulses, the highest efficiency measured to date for any coherent optical memory suitable for quantum information applications. We also show storage and recall of up to 20 pulses from our system. These results show that simple warm atomic vapour systems have clear potential as a platform for quantum memory. PMID:21285952

  3. Experimental research of a chain of diode pumped rubidium amplifiers.

    PubMed

    Li, Yunfei; Hua, Weihong; Li, Lei; Wang, Hongyan; Yang, Zining; Xu, Xiaojun

    2015-10-05

    In this paper, we have set up a diode pumped rubidium MOPA system with a chain of two amplifiers. The experimental results show an amplified laser power of 26W with amplification factor of 16.3 and power extraction efficiency of 53% for a single amplifier, and an amplified laser power of 11W with amplification factor of 7.9 and power extraction efficiency of 26% for a chain of two amplifiers. The reason for lower performance of cascade amplification is mainly due to the limited total pump power, which will be not sufficient for efficient pumping when assigned from a single amplifier into two amplifiers. The situation could be well improved by increasing the seed laser power as well as the pump power for each amplifier to realize high efficient saturated amplification. Such MOPA configuration has the potential for scaling high beam quality alkali laser into high powers.

  4. Linewidth-tunable laser diode array for rubidium laser pumping

    SciTech Connect

    Li Zhiyong; Tan Rongqing; Xu Cheng; Li Lin

    2013-02-28

    To optimise the pump source for a high-power diodepumped rubidium vapour laser, we have designed a laser diode array (LDA) with a narrowed and tunable linewidth and an external cavity formed by two volume Bragg gratings (VBGs). Through controlling the temperature differences between the two VBGs, the LDA linewidth, which was 1.8 nm before mounting the two VBGs, was tunable from 100 pm to 0.2 nm, while the output power changed by no more than 4 %. By changing simultaneously the temperature in both VBGs, the centre wavelength in air of the linewidth-tunable LDA was tunable from 779.40 nm to 780.05 nm. (control of laser radiation parameters)

  5. Anomalous two-photon spectral features in warm rubidium vapor

    NASA Astrophysics Data System (ADS)

    Perrella, C.; Light, P. S.; Milburn, T. J.; Kielpinski, D.; Stace, T. M.; Luiten, A. N.

    2016-09-01

    We report observation of anomalous fluorescence spectral features in the environs of a two-photon transition in a rubidium vapor when excited with two different wavelength lasers that are both counterpropagating through the vapor. These features are characterized by an unusual trade-off between the detunings of the driving fields. Three different hypothetical processes are presented to explain the observed spectra: a simultaneous three-atom and four-photon collision, a four-photon excitation involving a light field produced via amplified spontaneous emission, and population pumping perturbing the expected steady-state spectra. Numerical modeling of each hypothetical process is presented, supporting the population pumping process as the most plausible mechanism.

  6. Comparison of absorption, fluorescence, and polarization spectroscopy of atomic rubidium

    NASA Astrophysics Data System (ADS)

    Ashman, Seth; Stifler, Cayla; Romero, Joaquin

    2015-05-01

    An ongoing spectroscopic investigation of atomic rubidium utilizes a two-photon, single-laser excitation process. Transitions accessible with our tunable laser include 5P1 / 2F' <-- 5S1 / 2 F and 5P3 / 2F' <-- 5S1 / 2 F . The laser is split into a pump and probe beam to allow for Doppler-free measurements of transitions between hyperfine levels. The pump and probe beams are overlapped in a counter-propagating geometry and the laser frequency scans over a transition. Absorption, fluorescence and polarization spectroscopy techniques are applied to this basic experimental setup. The temperature of the vapor cell and the power of the pump and probe beams have been varied to explore line broadening effects and signal-to-noise of each technique. This humble setup will hopefully grow into a more robust experimental arrangement in which double resonance, two-laser excitations are used to explore hyperfine state changing collisions between rubidium atoms and noble gas atoms. Rb-noble gas collisions can transfer population between hyperfine levels, such as 5P3 / 2 (F' = 3) <-- Collision 5P3 / 2 (F ' = 2) , and the probe beam couples 7S1 / 2 (F'' = 2) <-- 5P3 / 2 (F' = 3) . Polarization spectroscopy signal depends on the rate of population transfer due to the collision as well as maintaining the orientation created by the pump laser. Fluorescence spectroscopy relies only on transfer of population due to the collision. Comparison of these techniques yields information regarding the change of the magnetic sublevels, mF, during hyperfine state changing collisions.

  7. A prospective comparison of rubidium-82 PET and thallium-201 SPECT myocardial perfusion imaging utilizing a single dipyridamole stress in the diagnosis of coronary artery disease

    SciTech Connect

    Go, R.T.; Marwick, T.H.; MacIntyre, W.J.; Saha, G.B.; Neumann, D.R.; Underwood, D.A.; Simpfendorfer, C.C. )

    1990-12-01

    The purpose of the present study is to prospectively compare myocardial perfusion imaging with rubidium-82 ({sup 82}Rb) by positron emission tomography (PET) with thallium-201 ({sup 201}Tl) imaging by single-photon emission tomography (SPECT) by recording both studies with a single dipyridamole handgrip stress, and reading both sets of images with the same display technique. In a series of 202 patients with previous coronary arteriography, the sensitivity, specificity, and accuracy of {sup 82}Rb PET were 93%, 78%, and 90% and for {sup 201}Tl SPECT 76%, 80%, and 77%, respectively. When 70 patients with previous therapeutic interventions were excluded, the remaining 132 patients showed a sensitivity, specificity, and accuracy of 95%, 82% and 92% for {sup 82}Rb PET and 79%, 76%, and 78% for {sup 201}Tl SPECT. The improved contrast resolution of PET resulted in markedly superior images and a more confident identification of defects.

  8. Effects of external cesium and rubidium on outward potassium currents in squid axons.

    PubMed Central

    Clay, J R; Shlesinger, M F

    1983-01-01

    We have studied the effects of external cesium and rubidium on potassium conductance of voltage clamped squid axons over a broad range of concentrations of these ions relative to the external potassium concentration. Our primary novel finding concerning cesium is that relatively large concentrations of this ion are able to block a small, but statistically significant fraction of outward potassium current for potentials less than approximately 50 mV positive to reversal potential. This effect is relieved at more positive potentials. We have also found that external rubidium blocks outward current with a qualitatively similar voltage dependence. This effect is more readily apparent than the cesium blockade, occurring even for concentrations less than that of external potassium. Rubidium also has a blocking effect on inward current, which is relieved for potentials more than 20-40 mV negative to reversal, thereby allowing both potassium and rubidium ions to cross the membrane. We have described these results with a single-file diffusion model of ion permeation through potassium channels. The model analysis suggests that both rubidium and cesium ions exert their blocking effects at the innermost site of a two-site channel, and that rubidium competes with potassium ions for entry into the channel more effectively than does cesium under comparable conditions. PMID:6301576

  9. Membrane potential and conductance during transport of sodium, potassium and rubidium in frog muscle.

    PubMed

    Adrian, R H; Slayman, C L

    1966-06-01

    1. Muscles with high intracellular sodium concentrations can extrude sodium into solutions which contain 10 m-equiv/l. of either potassium or rubidium. Potassium or rubidium replaces the extruded intracellular sodium. These cation movements take place equally well when the external anion is chloride or sulphate, though muscles deteriorate if left for long periods in sulphate solutions.2. Measurements of intracellular potentials during extrusion of sodium into solutions containing potassium show:(a) an internal potential more negative than the potassium equilibrium potential (E(K)); at 20 degrees C the difference is nearly 20 mV.(b) that a difference between the membrane potential and E(K) is dependent on temperature and is abolished by 10(-5)M ouabain.(c) an internal potential which becomes more negative in the presence of 0.1% cocaine, a concentration of cocaine which substantially increases the membrane resistance to potassium movement. In the absence of potassium or rubidium no such hyperpolarization occurs.3. When muscles extrude into solutions which contain rubidium they have internal potentials which are 10-20 mV more negative than when extruding sodium into corresponding solutions containing potassium.4. Measurements of electrical conductance in the potassium solution suggest that the electrochemical potential difference for potassium ions may be large enough to account for the measured inward potassium movements during sodium extrusion. The reliability of the measurements does not, however, exclude the possibility that some part of the inward potassium movement is chemically linked to outward movement.5. Measurements of membrane conductance in solutions containing rubidium, and of net movements of rubidium in the presence and absence of ouabain, lead to the conclusion that at least 90% of the inward rubidium movement during sodium extrusion must be chemically linked to the sodium movement.6. The hyperpolarization during extrusion of sodium could be

  10. Membrane potential and conductance during transport of sodium, potassium and rubidium in frog muscle

    PubMed Central

    Adrian, R. H.; Slayman, C. L.

    1966-01-01

    1. Muscles with high intracellular sodium concentrations can extrude sodium into solutions which contain 10 m-equiv/l. of either potassium or rubidium. Potassium or rubidium replaces the extruded intracellular sodium. These cation movements take place equally well when the external anion is chloride or sulphate, though muscles deteriorate if left for long periods in sulphate solutions. 2. Measurements of intracellular potentials during extrusion of sodium into solutions containing potassium show: (a) an internal potential more negative than the potassium equilibrium potential (EK); at 20° C the difference is nearly 20 mV. (b) that a difference between the membrane potential and EK is dependent on temperature and is abolished by 10-5 M ouabain. (c) an internal potential which becomes more negative in the presence of 0·1% cocaine, a concentration of cocaine which substantially increases the membrane resistance to potassium movement. In the absence of potassium or rubidium no such hyperpolarization occurs. 3. When muscles extrude into solutions which contain rubidium they have internal potentials which are 10-20 mV more negative than when extruding sodium into corresponding solutions containing potassium. 4. Measurements of electrical conductance in the potassium solution suggest that the electrochemical potential difference for potassium ions may be large enough to account for the measured inward potassium movements during sodium extrusion. The reliability of the measurements does not, however, exclude the possibility that some part of the inward potassium movement is chemically linked to outward movement. 5. Measurements of membrane conductance in solutions containing rubidium, and of net movements of rubidium in the presence and absence of ouabain, lead to the conclusion that at least 90% of the inward rubidium movement during sodium extrusion must be chemically linked to the sodium movement. 6. The hyperpolarization during extrusion of sodium could be explained

  11. Rubidium-Strontium Formation Age of Allan Hills 84001 Carbonates

    NASA Technical Reports Server (NTRS)

    Borg, L. E.; Nyquist, L. E.; Shih, C.-Y.; Weismann, H.; Reese, Y.; Connelly, J. N.

    1998-01-01

    Our preferred age for the formation of carbonates in the martian meteorite ALH 84001 is 3.90 plus or minus 0.04 Ga for Lambda (Rubidium 87) equals 0.01402 Ga (exp -1), or 3.85 plus or minus 0.04 Ga for Lambda (Rubidium 87) = 0.0142 Ga(exponent -1). This age is determined by a three-point Rb-Sr isochron defined by leachates of high-graded carbonate-rich material. Major cation and especially phosphorous analyses of the leachates permit contributions from igneous whitlockite to be recognized for low-acidity leachates, and the corresponding data are omitted from the isochron. Data for the two highest acidity leachates plot close to the preferred isochron, but are omitted because we believe they contain contributions leached from the pyroxene substrate on which most of the carbonates are found. Nevertheless, the isochron age for all five highest-acidity leachates is 3.94 plus or minus 0.04 Ga, and is within error of the age obtained for the more restricted data set. All leachates used to define the isochron have major cation compositions that are singular to those obtained by microprobe analyses of the carbonate rosettes and are consistent with progressive digestion of the carbonates according to their composition. The age thus obtained for the carbonates is about 600 m.y. younger than the crystalization age of ALH 84001 determined by Sm-Nd analyses but is within error limits of the age of impact metamorphism inferred from the Rb-Sr and Ar-Ar systematics of silicates. which yield ages of 3.85 plus or minus 0.05 Ga and 4.05- 3.80 Ga to 4.3-3.8 Ga, respectively. Similarities between the carbonate crystallization age and the age of impact metamorphism as determined by Ar-Ar and Rb-Sr suggest that the carbonate formation is impact-related. Nevertheless, both high and low- temperature scenarios for the origin of the carbonates are possible.

  12. Rubidium-Strontium Formation Age of Allan Hills 84001 Carbonates

    NASA Technical Reports Server (NTRS)

    Borg, L. E.; Nyquist, L. E.; Shih, C.-Y.; Weismann, H.; Reese, Y.; Connelly, J. N.

    1998-01-01

    Our preferred age for the formation of carbonates in the martian meteorite ALH 84001 is 3.90 plus or minus 0.04 Ga for Lambda (Rubidium 87) equals 0.01402 Ga (exp -1), or 3.85 plus or minus 0.04 Ga for Lambda (Rubidium 87) = 0.0142 Ga(exponent -1). This age is determined by a three-point Rb-Sr isochron defined by leachates of high-graded carbonate-rich material. Major cation and especially phosphorous analyses of the leachates permit contributions from igneous whitlockite to be recognized for low-acidity leachates, and the corresponding data are omitted from the isochron. Data for the two highest acidity leachates plot close to the preferred isochron, but are omitted because we believe they contain contributions leached from the pyroxene substrate on which most of the carbonates are found. Nevertheless, the isochron age for all five highest-acidity leachates is 3.94 plus or minus 0.04 Ga, and is within error of the age obtained for the more restricted data set. All leachates used to define the isochron have major cation compositions that are singular to those obtained by microprobe analyses of the carbonate rosettes and are consistent with progressive digestion of the carbonates according to their composition. The age thus obtained for the carbonates is about 600 m.y. younger than the crystalization age of ALH 84001 determined by Sm-Nd analyses but is within error limits of the age of impact metamorphism inferred from the Rb-Sr and Ar-Ar systematics of silicates. which yield ages of 3.85 plus or minus 0.05 Ga and 4.05- 3.80 Ga to 4.3-3.8 Ga, respectively. Similarities between the carbonate crystallization age and the age of impact metamorphism as determined by Ar-Ar and Rb-Sr suggest that the carbonate formation is impact-related. Nevertheless, both high and low- temperature scenarios for the origin of the carbonates are possible.

  13. Excitation and emission spectra of rubidium in rare-gas thin-films.

    PubMed

    Gerhardt, Ilja; Sin, Kyungseob; Momose, Takamasa

    2012-07-07

    To understand the optical properties of atoms in solid state matrices, the absorption, excitation, and emission spectra of rubidium doped thin-films of argon, krypton, and xenon were investigated in detail. A two-dimensional spectral analysis extends earlier reports on the excitation and emission properties of rubidium in rare-gas hosts. We found that the doped crystals of krypton and xenon exhibit a simple absorption-emission relation, whereas rubidium in argon showed more complicated spectral structures. Our sample preparation employed in the present work yielded different results for the Ar crystal, but our peak positions were consistent with the prediction based on the linear extrapolation of Xe and Kr data. We also observed a bleaching behavior in rubidium excitation spectra, which suggests a population transfer from one to another spectral feature due to hole-burning. The observed optical response implies that rubidium in rare-gas thin-films is detectable with extremely high sensitivity, possibly down to a single atom level, in low concentration samples.

  14. Excitation and emission spectra of rubidium in rare-gas thin-films

    SciTech Connect

    Gerhardt, Ilja; Sin, Kyungseob; Momose, Takamasa

    2012-07-07

    To understand the optical properties of atoms in solid state matrices, the absorption, excitation, and emission spectra of rubidium doped thin-films of argon, krypton, and xenon were investigated in detail. A two-dimensional spectral analysis extends earlier reports on the excitation and emission properties of rubidium in rare-gas hosts. We found that the doped crystals of krypton and xenon exhibit a simple absorption-emission relation, whereas rubidium in argon showed more complicated spectral structures. Our sample preparation employed in the present work yielded different results for the Ar crystal, but our peak positions were consistent with the prediction based on the linear extrapolation of Xe and Kr data. We also observed a bleaching behavior in rubidium excitation spectra, which suggests a population transfer from one to another spectral feature due to hole-burning. The observed optical response implies that rubidium in rare-gas thin-films is detectable with extremely high sensitivity, possibly down to a single atom level, in low concentration samples.

  15. Glucose-induced activation of rubidium transport and water flux in sunflower root systems.

    PubMed

    Quintero, J M; Molina, R; Fournier, J M; Benlloch, M; Ramos, J

    2001-01-01

    Excised 20-d-old sunflower roots (Helianthus annuus L. cv. Sun-Gro 393) were used to study the effect of different sugars on rubidium and water fluxes. The roots sensed and absorbed glucose from the external medium inducing the activation of rubidium accumulated in the root (Rb(+) root), the flux of exuded rubidium (J(Rb)) and, to a lesser degree, the exudation rate (J(v)). These effects were also triggered by fructose, but not by 6-deoxyglucose (6-dG), a glucose analogue which is not a substrate for hexokinase (HXK). The effect of 2-deoxyglucose (2-dG), an analogue that is phosphorylated but not further metabolized, was complex, suggesting an inhibitory effect on solute transport to the xylem. The amounts of glucose required to activate rubidium and water fluxes were similar to those previously reported to regulate different processes in other plants (0.5--10 mM). When sorbitol was used instead of glucose, neither rubidium uptake (Rb(+) root plus J(Rb)) nor J(v) was activated. It is proposed that glucose present in the root plays an important signalling role in the regulation of Rb(+) (K(+)) and water transport in plant roots.

  16. Excitation and emission spectra of rubidium in rare-gas thin-films

    NASA Astrophysics Data System (ADS)

    Gerhardt, Ilja; Sin, Kyungseob; Momose, Takamasa

    2012-07-01

    To understand the optical properties of atoms in solid state matrices, the absorption, excitation, and emission spectra of rubidium doped thin-films of argon, krypton, and xenon were investigated in detail. A two-dimensional spectral analysis extends earlier reports on the excitation and emission properties of rubidium in rare-gas hosts. We found that the doped crystals of krypton and xenon exhibit a simple absorption-emission relation, whereas rubidium in argon showed more complicated spectral structures. Our sample preparation employed in the present work yielded different results for the Ar crystal, but our peak positions were consistent with the prediction based on the linear extrapolation of Xe and Kr data. We also observed a bleaching behavior in rubidium excitation spectra, which suggests a population transfer from one to another spectral feature due to hole-burning. The observed optical response implies that rubidium in rare-gas thin-films is detectable with extremely high sensitivity, possibly down to a single atom level, in low concentration samples.

  17. The effects of potassium and rubidium hydroxide on the alkali-silica reaction

    SciTech Connect

    Shomglin, K.; Turanli, L.; Wenk, H.-R.; Monteiro, P.J.M.; Sposito, G

    2003-11-01

    Expansion of mortar specimens prepared with an aggregate of mylonite from the Santa Rosa mylonite zone in southern California was studied to investigate the effect of different alkali ions on the alkali-silica reaction in concrete. The expansion tests indicate that mortar has a greater expansion when subjected to a sodium hydroxide bath than in a sodium-potassium-rubidium hydroxide bath. Electron probe microanalysis (EPMA) of mortar bars at early ages show that rubidium ions, used as tracer, were present throughout the sample by the third day of exposure. The analysis also shows a high concentration of rubidium in silica gel from mortar bars exposed to bath solutions containing rubidium. The results suggest that expansion of mortar bars using ASTM C 1260 does not depend on the diffusion of alkali ions. The results indicate that the expansion of alkali-silica gel depends on the type of alkali ions present. Alkali-silica gel containing rubidium shows a lower concentration of calcium, suggesting competition for the same sites.

  18. Influence of modulation frequency in rubidium cell frequency standards

    NASA Technical Reports Server (NTRS)

    Audoin, C.; Viennet, J.; Cyr, N.; Vanier, J.

    1983-01-01

    The error signal which is used to control the frequency of the quartz crystal oscillator of a passive rubidium cell frequency standard is considered. The value of the slope of this signal, for an interrogation frequency close to the atomic transition frequency is calculated and measured for various phase (or frequency) modulation waveforms, and for several values of the modulation frequency. A theoretical analysis is made using a model which applies to a system in which the optical pumping rate, the relaxation rates and the RF field are homogeneous. Results are given for sine-wave phase modulation, square-wave frequency modulation and square-wave phase modulation. The influence of the modulation frequency on the slope of the error signal is specified. It is shown that the modulation frequency can be chosen as large as twice the non-saturated full-width at half-maximum without a drastic loss of the sensitivity to an offset of the interrogation frequency from center line, provided that the power saturation factor and the amplitude of modulation are properly adjusted.

  19. Marking Drosophila suzukii (Diptera: Drosophilidae) With Rubidium or 15N.

    PubMed

    Klick, J; Yang, W Q; Bruck, D J

    2015-06-01

    Drosophila suzukii Matsumura (Diptera: Drosophilidae) has caused significant economic damage to berry and stone fruit production regions. Markers that are systemic in plants and easily transferred to target organisms are needed to track D. suzukii exploitation of host resources and trophic interactions. High and low concentrations of the trace element, rubidium (Rb), and the stable isotope, 15N, were tested to mark D. suzukii larvae feeding on fruits of enriched strawberry plants grown in containers under greenhouse conditions. Fly marker content and proportion of flies marked 1, 7, and 14 d after emergence from enriched fruits and fly dry mass were analyzed. Nearly 100% of the flies analyzed 14 d after emerging from 15N-enriched plants were marked, whereas only 30-75% and 0-3% were marked 14 d after emerging from high and low Rb concentration plants, respectively. Rapid Rb decay, strong 15N persistence, and the economics of using these markers in the field to elucidate D. suzukii pest ecology are discussed. © The Authors 2015. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  20. Crystal structure of rubidium methyl-diazo-tate.

    PubMed

    Grassl, Tobias; Korber, Nikolaus

    2017-02-01

    The title compound, Rb(+)·H3CN2O(-), has been crystallized in liquid ammonia as a reaction product of the reductive ammonolysis of the natural compound streptozocin. Elemental rubidium was used as reduction agent as it is soluble in liquid ammonia, forming a blue solution. Reductive bond cleavage in biogenic materials under kinetically controlled conditions offers a new approach to gain access to sustainably produced raw materials. The anion is nearly planar [dihedral angle O-N-N-C = -0.4 (2)°]. The Rb(+) cation has a coordination number of seven, and coordinates to five anions. One anion is bound via both its N atoms, one by both O and N, two anions are bound by only their O atoms, and the last is bound via the N atom adjacent to the methyl group. The diazo-tate anions are bridged by cations and do not exhibit any direct contacts with each other. The cations form corrugated layers that propagate in the (-101) plane.

  1. The system design of a rubidium maser frequency standard

    NASA Technical Reports Server (NTRS)

    Xiong, C. X.

    1984-01-01

    The Rubidium Maser Frequency Standard is a precision frequency source with excellent short-term stability. A type PBR-II Rb maser frequency standard was developed by the Beijing Institute of Radio Metrology and Measurement (BIRMM). The time-domain frequency stability (two-sample variance) of this frequency standard is less than 1/5 times 10 to the 13th power for t=10ms yields 1.0s, fh=1.0 KHz. Two PBR-II frequency standards were used as reference frequency sources in a frequency stability measurement system. Some important system characteristics for the PBR-II Rb maser frequency standard such as phase noise and frequency stability transfer characteristics are discussed. Furthermore, the design of the frequency standard for optimum frequency stability of the output signal; the choice of a voltage controlled crystal oscillator for the frequency standard; the design of the phase-locked loop; and the frequency stability test results on the PBR-II are discussed.

  2. Distribution of rubidium between sodic sanidine and natural silicic liquid

    USGS Publications Warehouse

    Noble, D.C.; Hedge, C.E.

    1970-01-01

    Phenocrysts of sodic sanidine from twelve upper Cenozoic units of silicic ash-flow tuff and lava from the Western United States contain from 0.25 to 0.45 the Rb present in the associated groundmass materials. The ratios of potassium to rubidium in the sanidines are, on the average, about four times greater than those of the groundmass. Separation of phenocrystic sanidine from salic melts provides an efficient method for raising the Rb content and lowering the K/Rb ratio of the melts, although the amount of differentiation probably is limited by continuous reequilibration of the alkalis between crystal and liquid phases through ion exchange. Syenites of cumulate origin will have appreciably lower Rb contents and higher K/Rb ratios than the melts from which they precipitated. Available data on the distribution of Rb between synthetic biotite and K-sanidine demonstrate that the separation of biotite probably will not deplete salic melts in Rb relative to K. ?? 1970 Springer-Verlag.

  3. Crystal structure of rubidium methyl­diazo­tate

    PubMed Central

    Grassl, Tobias; Korber, Nikolaus

    2017-01-01

    The title compound, Rb+·H3CN2O−, has been crystallized in liquid ammonia as a reaction product of the reductive ammonolysis of the natural compound streptozocin. Elemental rubidium was used as reduction agent as it is soluble in liquid ammonia, forming a blue solution. Reductive bond cleavage in biogenic materials under kinetically controlled conditions offers a new approach to gain access to sustainably produced raw materials. The anion is nearly planar [dihedral angle O—N—N—C = −0.4 (2)°]. The Rb+ cation has a coordination number of seven, and coordinates to five anions. One anion is bound via both its N atoms, one by both O and N, two anions are bound by only their O atoms, and the last is bound via the N atom adjacent to the methyl group. The diazo­tate anions are bridged by cations and do not exhibit any direct contacts with each other. The cations form corrugated layers that propagate in the (-101) plane. PMID:28217333

  4. Production of complex rubidium and cesium hydrogen sulfate‒phosphates

    NASA Astrophysics Data System (ADS)

    Komornikov, V. A.; Grebenev, V. V.; Makarova, I. P.; Selezneva, E. V.; Andreev, P. V.

    2016-07-01

    The solubility in the CsH2PO4‒CsHSO4‒H2O system at different temperatures (25, 50, and 75°C) is studied and the phase equilibria in the Rb3H(SO4)2‒RbH2PO4‒H2O system under isothermal conditions (at 25°C) are analyzed. The temperature and concentration conditions for forming Rb2(HSO4)(H2PO4), Rb4(HSO4)3(H2PO4), Cs4(HSO4)3(H2PO4), Cs3(HSO4)2(H2PO4), Cs2(HSO4)(H2PO4), and Cs6H(HSO4)3(H2PO4)4 compounds (the latter has been obtained for the first time) are determined. The conditions for growing large single crystals of complex acid rubidium and cesium salts are found.

  5. Transport of rubidium and strontium in detached wheat shoots

    SciTech Connect

    Feller, U.

    1986-04-01

    Rb is easily translocated in xylem and phloem (similar to K), while Sr is mobile in the xylem but rather immobile in the phloem. Wheat shoots from the field were cut 1 week after ear emergence below or above the uppermost node and incubated for 3 days standing in flasks with 2 mM rubidium chloride + 2 mM strontium chloride. In some plants the phloem flux to the ear was interrupted by steam-girdling below the ear. Rb and Sr were analyzed in the different parts of the shoots by atomic absorption spectroscopy. The Rb content in the ear depended remarkably on the treatment: 0.139 mg/ear were detected in shoots cut below the node (A), 0.015 mg/ear in shoots cut above the node (B), 0.019 mg/ear in shoots cut below the node after removing the flag leaf spread (C) and only 0.001 mg/ear in shoots cut below the node and steam-girdled below the ear (D). The Sr content was not drastically affected by these treatments: 0.278 (a), 0.317 (b), 0.356 (C) and 0.214 (D) mg/ear. These results suggest that Rb was transferred from the xylem to the phloem and translocated mainly with the phloem stream to the ear.

  6. Evidence for the ordered release of rubidium ions occluded within individual protomers of dog kidney Na+,K+-ATPase.

    PubMed Central

    Glynn, I M; Richards, D E

    1989-01-01

    1. When magnesium and orthophosphate are added to Na+,K+-ATPase containing occluded rubidium ions, and suspended in a medium containing free rubidium ions, only 50% of the occluded rubidium is released rapidly. This is because the release of occluded rubidium is ordered, and the replacement (by rubidium ions from the medium) of the first occluded rubidium ions to leave slows the departure of the remaining occluded ions. 2. Since the Na+,K+-ATPase probably exists in the membrane as a structural dimer, the ordered release might represent either the ordered emptying of the two halves of the dimer, or the ordered release of the two rubidium ions thought to be contained in each promoter. 3. The present experiments were designed to decide between these possibilities by examining the behaviour of Na+,K+-ATPase in which about half of the protomers had been randomly inactivated by pre-treatment either with fluorescein isothiocyanate or with alpha-chymotrypsin. 4. The results show that the release of rubidium ions from each protomer is ordered. PMID:2550627

  7. Longitudinal Spin Relaxation of Optically Pumped Rubidium Atoms in Solid Parahydrogen.

    PubMed

    Upadhyay, Sunil; Kanagin, Andrew N; Hartzell, Chase; Christy, Tim; Arnott, W Patrick; Momose, Takamasa; Patterson, David; Weinstein, Jonathan D

    2016-10-21

    We have grown crystals of solid parahydrogen using a single closed-cycle cryostat. We have doped the crystals with rubidium atoms at densities on the order of 10^{17}  cm^{-3} and used optical pumping to polarize the spin state of the implanted atoms. The optical spectrum of the rubidium atoms shows larger broadening than previous work in which the rubidium was implanted in solid argon or neon. However, the optical pumping behavior is significantly improved, with both a larger optical pumping signal and a longer longitudinal relaxation time. The spin relaxation time shows a strong dependence on orthohydrogen impurity levels in the crystal, as well as the applied magnetic field. Current performance is comparable to state-of-the-art solid state systems at comparable spin densities, with potential for improvement at higher parahydrogen purities.

  8. Operational stability of rubidium and cesium frequency standards. [analysis of equipment performance at NASA tracking stations

    NASA Technical Reports Server (NTRS)

    Lavery, J. E.

    1972-01-01

    In the course of testing various rubidium and cesium frequency standards under operational conditions for use in NASA tracking stations, about 55 unit-years of relative frequency measurements for averaging times from 10 to 10 to the 7th power have been accumulated at Goddard Space Flight Center (GSFC). Statistics on the behavior of rubidium and cesium standards under controlled laboratory conditions have been published, but it was not known to what extent the lesser controlled environments of NASA tracking stations affected the performance of the standards. The purpose of this report is to present estimates of the frequency stability of rubidium and cesium frequency standards under operational conditions based on the data accumulated at GSFC.

  9. Longitudinal Spin Relaxation of Optically Pumped Rubidium Atoms in Solid Parahydrogen

    NASA Astrophysics Data System (ADS)

    Upadhyay, Sunil; Kanagin, Andrew N.; Hartzell, Chase; Christy, Tim; Arnott, W. Patrick; Momose, Takamasa; Patterson, David; Weinstein, Jonathan D.

    2016-10-01

    We have grown crystals of solid parahydrogen using a single closed-cycle cryostat. We have doped the crystals with rubidium atoms at densities on the order of 1017 cm-3 and used optical pumping to polarize the spin state of the implanted atoms. The optical spectrum of the rubidium atoms shows larger broadening than previous work in which the rubidium was implanted in solid argon or neon. However, the optical pumping behavior is significantly improved, with both a larger optical pumping signal and a longer longitudinal relaxation time. The spin relaxation time shows a strong dependence on orthohydrogen impurity levels in the crystal, as well as the applied magnetic field. Current performance is comparable to state-of-the-art solid state systems at comparable spin densities, with potential for improvement at higher parahydrogen purities.

  10. Trapping of neutral rubidium with a macroscopic three-phase electric trap.

    PubMed

    Rieger, T; Windpassinger, P; Rangwala, S A; Rempe, G; Pinkse, P W H

    2007-08-10

    We trap neutral ground-state rubidium atoms in a macroscopic trap based on purely electric fields. For this, three electrostatic field configurations are alternated in a periodic manner. The rubidium is precooled in a magneto-optical trap, transferred into a magnetic trap, and then translated into the electric trap. The electric trap consists of six rod-shaped electrodes in cubic arrangement, giving ample optical access. Up to 10;{5} atoms have been trapped with an initial temperature of around 20 microkelvin in the three-phase electric trap. The observations are in good agreement with detailed numerical simulations.

  11. Hyperfine structure measurement of rubidium atom and tunable diode laser stabilization by using Sagnac interferometer.

    PubMed

    Kim, Jin-Tae; Zhen, Liu; Kapitanov, Venedikt; Kim, Hyun Su; Park, Jong Rak; Park, Si-Hyun

    2006-11-01

    The Rubidium saturated absorption spectra for D2 transition lines are used to measure the Fabry-Perot interferometer free spectral range (FSR). The scale linearity of the laser frequency tuning is determined. The Sagnac interferometer has been used for the laser stabilization. The result shows that the laser frequency is stabilized upto sub-mega Herz level. Also the hyperfine structure [5(2)S(1/2) F = 3 --> F' = 2, 3, 4 5(2)P(3/2) 85Rb] of the rubidium atom has been measured by using the tilt locking method, which shows the same result as the conventional saturation spectroscopy.

  12. Resonance transition 795-nm Rubidium laser using 3He buffer gas

    SciTech Connect

    Wu, S S; Soules, T F; Page, R H; Mitchell, S C; Kanz, V K; Beach, R J

    2007-08-02

    We report the first demonstration of a 795-nm Rubidium resonance transition laser using a buffer gas consisting of pure {sup 3}He. This follows our recent demonstration of a hydrocarbon-free 795-nm Rubidium resonance laser which used naturally-occurring He as the buffer gas. Using He gas that is isotopically enriched with {sup 3}He yields enhanced mixing of the Rb fine-structure levels. This enables efficient lasing at reduced He buffer gas pressure, improving thermal management in high average power Rb lasers and enhancing the power scaling potential of such systems.

  13. Structural aspects of rubidium ion selectivity by tribenzo-21-crown-7

    SciTech Connect

    Bryan, J.C.; Sachleben, R.A.; Lavis, J.M.; Davis, M.C.; Burns, J.H.; Hay, B.P.

    1998-06-01

    The structural origins of the selectivity of rubidium ion over other alkali metal ions (Cs, Rb, Na, Re) by tribenzo-21-crown-7 is investigated from single-crystal X-ray diffraction. The structures reported here are the first reported for a tribenzo-21-crown-7, and the alkali metal ion complexes are the first reported structures of these ions with any 21-crown-7 ether. Different crown conformations are observed for each structure. Molecular mechanics calculations were performed on all conformers, and the results are related to the observed extraction selectivity for rubidium.

  14. Radiation trapping in rubidium optical pumping at low buffer-gas pressures

    SciTech Connect

    Rosenberry, M. A.; Reyes, J. P.; Gay, T. J.; Tupa, D.

    2007-02-15

    We have made a systematic study of rubidium optical pumping in a simple cylindrical cell geometry with a high-power 10 W diode laser array, low magnetic fields, and buffer-gas pressures of less than 50 torr. We have determined rubidium polarizations experimentally for H{sub 2}, N{sub 2}, He, and Ar buffer gases, with Rb number densities from 10{sup 12} to 10{sup 13} cm{sup -3}. Comparison to a relatively simple optical pumping model allows us to extract useful information about radiation trapping and quenching effects.

  15. Methods and evaluation of frequency aging in distributed-feedback laser diodes for rubidium atomic clocks

    NASA Astrophysics Data System (ADS)

    Matthey, Renaud; Affolderbach, Christoph; Mileti, Gaetano

    2011-09-01

    Distributed-feedback laser diodes emitting at 780nm have been evaluated, with respect to the aging of the injection current required for reaching the rubidium D2 resonance line. Results obtained for lasers operating in air and in vacuum for 9 months are reported. When operated at constant temperature, the laser current required for emission at the wavelength of the desired atomic resonance is found to decrease by 50 to 80μA per month. The impact of this result on the lifetime and long-term performances of laser-pumped rubidium atomic clocks is discussed.

  16. The metal-insulator phase transition in mixed potassium-rubidium electro-sodalites.

    PubMed

    Madsen, Georg K H

    2004-09-01

    The collapse under pressure of the antiferromagnetic ground state of the potassium-rubidium electro-sodalite is studied using the linearized augmented plane wave with local orbitals method. Special considerations needed for setting up this basis for systems such as the electro-sodalites are discussed. It is demonstrated that the magnetism collapses at a unit-cell volume similar to potassium electro-sodalite and rubidium electro-sodalite. A critical pressure of 8 GPa is predicted. The mechanism behind the collapse is a mixing of the F-center states with the highly diffuse unoccupied p states of the alkali atoms.

  17. Methods and evaluation of frequency aging in distributed-feedback laser diodes for rubidium atomic clocks.

    PubMed

    Matthey, Renaud; Affolderbach, Christoph; Mileti, Gaetano

    2011-09-01

    Distributed-feedback laser diodes emitting at 780 nm have been evaluated, with respect to the aging of the injection current required for reaching the rubidium D2 resonance line. Results obtained for lasers operating in air and in vacuum for 9 months are reported. When operated at constant temperature, the laser current required for emission at the wavelength of the desired atomic resonance is found to decrease by 50 to 80 μA per month. The impact of this result on the lifetime and long-term performances of laser-pumped rubidium atomic clocks is discussed.

  18. Microwave Field Strength Measurement in a Rubidium Clock Cavity via Adiabatic Rapid Passage.

    DTIC Science & Technology

    2014-09-26

    ber) Adiabatic rapid passage Atomic clocks * Microwave field strength AftFR7 ACT (Confna On r’ee side yf "*"myr a"d UeIIIIIIIIr blocek ember) Ridium...7 RD-A57 79 MICROWAE IELD STRENGTH MESUREMENT IN A RUBIDIUM / CLOCK CAVITY VIA ADIAB..(U) AEROSPACE CORP EL SEGUNDO CR CHEMISTRYAND PHYSICSLAB R P...OF STANOARLS-1963-A 9% % % -w-- w-- €,, .6 . k, . . . •i •• -• 0Microwave Field Strength Measurement N in a Rubidium Clock Cavity via 12 Adiabatic

  19. Measurement of the rubidium D2 natural transition linewidth

    NASA Astrophysics Data System (ADS)

    Schultz, Brad E.

    A new technique was developed to measure the natural linewidth of an optical transition. It tunes the frequency of a laser precisely across the resonance using an acousto-optic modulator. The transmission of the laser through a cloud of atoms was monitored using a CCD camera. This work studied the 5S1/2→5P3/2 transition or D2 line of 87Rb. The rubidium atoms were first cooled to a temperature of 50 muK using a magneto-optical trap. The transition linewidth was then given by the natural linewidth as the Doppler width is negligible at such low temperatures. Indeed, the observed lineshape was very well fit by a Lorentzian function. The full width at half maximum linewidth was examined as a function of the probe laser intensity and atom density. The natural linewidth was determined to be 6.069 +/- 0.016 MHz which corresponds to a lifetime of 26.22 +/- 0.07 nsec for the 5P 3/2 state. This lifetime is one of only a handful known to an accuracy of 3 parts in 103. It is in excellent agreement with results found using different experimental techniques. An important advantage of this technique is that it does not require a detector be placed relatively close to the atoms to be sensitive to fluorescence emitted into a large solid angle, as is the case with experiments that measure the temporal decay of fluorescence. All of the experimentally determined lifetimes for the 5P 3/2 state are about 1% less (3sigma) than the result of a relativistic many-body perturbation calculation.

  20. Microresonator Brillouin laser stabilization using a microfabricated rubidium cell.

    PubMed

    Loh, William; Hummon, Matthew T; Leopardi, Holly F; Fortier, Tara M; Quinlan, Frank; Kitching, John; Papp, Scott B; Diddams, Scott A

    2016-06-27

    We frequency stabilize the output of a miniature stimulated Brillouin scattering (SBS) laser to rubidium atoms in a microfabricated cell to realize a laser system with frequency stability at the 10-11 level over seven decades in averaging time. In addition, our system has the advantages of robustness, low cost and the potential for integration that would lead to still further miniaturization. The SBS laser operating at 1560 nm exhibits a spectral linewidth of 820 Hz, but its frequency drifts over a few MHz on the 1 hour timescale. By locking the second harmonic of the SBS laser to the Rb reference, we reduce this drift by a factor of 103 to the level of a few kHz over the course of an hour. For our combined SBS and Rb laser system, we measure a frequency noise of 4 × 104 Hz2/Hz at 10 Hz offset frequency which rapidly rolls off to a level of 0.2 Hz2/Hz at 100 kHz offset. The corresponding Allan deviation is ≤2 × 10-11 for averaging times spanning 10-4 to 103 s. By optically dividing the signal of the laser down to microwave frequencies, we generate an RF signal at 2 GHz with phase noise at the level of -76 dBc/Hz and -140 dBc/Hz at offset frequencies of 10 Hz and 10 kHz, respectively.

  1. Gating and flickery block differentially affected by rubidium in homomeric KCNQ1 and heteromeric KCNQ1/KCNE1 potassium channels.

    PubMed Central

    Pusch, M; Bertorello, L; Conti, F

    2000-01-01

    The voltage-gated potassium channel KCNQ1 associates with the small KCNE1 subunit to form the cardiac IKs delayed rectifier potassium current and mutations in both genes can lead to the long QT syndrome. KCNQ1 can form functional homotetrameric channels, however with drastically different biophysical properties compared to heteromeric KCNQ1/KCNE1 channels. We analyzed gating and conductance of these channels expressed in Xenopus oocytes using the two-electrode voltage-clamp and the patch-clamp technique and high extracellular potassium (K) and rubidium (Rb) solutions. Inward tail currents of homomeric KCNQ1 channels are increased about threefold upon substitution of 100 mM potassium with 100 mM rubidium despite a smaller rubidium permeability, suggesting an effect of rubidium on gating. However, the kinetics of tail currents and the steady-state activation curve are only slightly changed in rubidium. Single-channel amplitude at negative voltages was estimated by nonstationary noise analysis, and it was found that rubidium has only a small effect on homomeric channels (1.2-fold increase) when measured at a 5-kHz bandwidth. The apparent single-channel conductance was decreased after filtering the data at lower cutoff frequencies indicative of a relatively fast "flickery/block" process. The relative conductance in rubidium compared to potassium increased at lower cutoff frequencies (about twofold at 10 Hz), suggesting that the main effect of rubidium is to decrease the probability of channel blockage leading to an increase of inward currents without large changes in gating properties. Macroscopic inward tail currents of heteromeric KCNQ1/KCNE1 channels in rubidium are reduced by about twofold and show a pronounced sigmoidal time course that develops with a delay similar to the inactivation process of homomeric KCNQ1, and is indicative of the presence of several open states. The single channel amplitude of heteromers is about twofold smaller in rubidium than in

  2. Solid-state 87Rb NMR signatures for rubidium cations bound to a G-quadruplex.

    PubMed

    Ida, Ramsey; Wu, Gang

    2005-09-14

    We report the first solid-state 87Rb NMR characterization for rubidium cations bound to G-quartet structures formed by self-association of guanosine 5'-monophosphate and 5'-tert-butyl-dimethylsilyl-2', 3'-O-isopropylidene guanosine.

  3. Myocardial perfusion with rubidium-82. II. Effects of metaolic and pharmacologic interventions. [Dogs

    SciTech Connect

    Goldstein, R.A.; Mullani, N.A.; Marani, S.K.; Fisher,D.J.; Gould, K.L.; O'Brien, H.A. Jr.

    1983-10-01

    In order to validate a new method for quantifying coronary blood flow, a bolus of rubidium-82 (Rb-82) was injected intravenously into 28 open-chested dogs under a wide range of flow and physiologic conditions, using beta probes to monitor myocardial radioactivity. Extraction fraction and perfusion were measured using a functional model that separates the data into the free and trapped myocardial rubidium. Extraction and uptake of rubidium were lower during acidosis than during alkalosis and were unchanged by glucose-insulin, digoxin, or propranolol. Myocardial flow, as indicated by rubidium, correlated linearly with simultaneous measurements of flow by microspheres in the same sample volume over a wide range of flow (r = 0.97, n = 106, range 0.02 to 7.75 ml/min/g). Regional myocardial blood flow can be accurately determined using generator-produced Rb-82. Studies using current state-of-the-art, fast positron-emission tomographic cameras are required to determine the utility of this approach in man.

  4. Sodium and rubidium fluxes in rat red blood cells

    PubMed Central

    Beaugé, L. A.; Ortíz, Olga

    1971-01-01

    1. The Na content of rat red cells was found to be 4·40 m-mole/l. cells. When incubated in K(Rb)-free Na this value was doubled in 1 hr, whereas in K(Rb)-free choline it was reduced to about 35% in the same period of time. 2. In cells with elevated Na (13·70 m-mole/l.) the activation curve of Rb influx by external Rb reached the same Vmax in sodium as in choline. The shape of the curve was sigmoid in the first case (Km about 1·05 mM) and hyperbolic in the second (Km about 0·20 mM). 3. The activation curve of rubidium influx by internal sodium was linear at least up to 12 m-mole/l. cells with a slope of 0·84. From this concentration it could increase more steeply, though the data is insufficient to assure it. 4. In normal cells the efflux of Na in K(Rb)-free Na Ringer was 5·64 m-mole/l. cells. hr, and it was reduced to 4·32 m-mole by 10-4 M ouabain. This was accompanied by a reduction of Na influx by 4·14 m-mole, representing then a Na-Na ouabain-sensitive exchange mechanism. 5. At a concentration of 5 mM, external Rb increased Na efflux in 2·32 m-mole/l. cells. hr above the K(Rb)-free levels, and reduced Na influx by 2·13 m-mole. 6. It is proposed that the Na pump is able to operate even in the absence of external K(Rb), though at reduced rate and on a Na-Na exchange basis (Na is the only monovalent cation in the bathing solution). External K(Rb) would have two actions: to increase the rate of shuttling of the carrier (catalytic effect) and to switch the Na-Na to a Na-K(Rb) exchange. 7. These results raise a question of the real significance of the Na/K(Rb) `coupling' ratio and the K-free effect on the Na pump mechanism. PMID:5133948

  5. Rubidium and potassium levels are altered in Alzheimer's disease brain and blood but not in cerebrospinal fluid.

    PubMed

    Roberts, Blaine R; Doecke, James D; Rembach, Alan; Yévenes, L Fernanda; Fowler, Christopher J; McLean, Catriona A; Lind, Monica; Volitakis, Irene; Masters, Colin L; Bush, Ashley I; Hare, Dominic J

    2016-11-14

    Loss of intracellular compartmentalization of potassium is a biochemical feature of Alzheimer's disease indicating a loss of membrane integrity and mitochondrial dysfunction. We examined potassium and rubidium (a biological proxy for potassium) in brain tissue, blood fractions and cerebrospinal fluid from Alzheimer's disease and healthy control subjects to investigate the diagnostic potential of these two metal ions. We found that both potassium and rubidium levels were significantly decreased across all intracellular compartments in the Alzheimer's disease brain. Serum from over 1000 participants in the Australian Imaging, Biomarkers and Lifestyle Flagship Study of Ageing (AIBL), showed minor changes according to disease state. Potassium and rubidium levels in erythrocytes and cerebrospinal fluid were not significantly different according to disease state, and rubidium was slightly decreased in Alzheimer's disease patients compared to healthy controls. Our data provides evidence that contrasts the hypothesized disruption of the blood-brain barrier in Alzheimer's disease, with the systemic decrease in cortical potassium and rubidium levels suggesting influx of ions from the blood is minimal and that the observed changes are more likely indicative of an internal energy crisis within the brain. These findings may be the basis for potential diagnostic imaging studies using radioactive potassium and rubidium tracers.

  6. Optical cavity for enhanced parametric four-wave mixing in rubidium

    NASA Astrophysics Data System (ADS)

    Brekke, E.; Potier, S.

    2017-01-01

    We demonstrate the implementation of a ring cavity to enhance the efficiency of parametric four-wave mixing in rubidium. Using an input coupler with 95% reflectance, a finesse of 19.6$\\pm$0.5 is achieved with a rubidium cell inside. This increases the circulating intensity by a factor of 5.6$\\pm$0.5, and through two-photon excitation on the $5s_{1/2}\\rightarrow5d_{5/2}$ transition with a single excitation laser, up to 1.9$\\pm$0.3 mW of power at 420 nm is generated, 50 times what was previously generated with this scheme. The dependence of the output on Rb density and input power has been explored, suggesting the process may be approaching saturation. The blue output of the cavity also shows greatly improved spatial quality, combining to make this a promising source of 420 nm light for future experiments.

  7. Reversible light-controlled formation and evaporation of rubidium clusters in nanoporous silica.

    PubMed

    Burchianti, A; Bogi, A; Marinelli, C; Maibohm, C; Mariotti, E; Moi, L

    2006-10-13

    We observe reversible light assisted formation and evaporation of rubidium clusters embedded in nanoporous silica. Metallic nanoparticles are cyclically produced and evaporated by weak blue-green and near-infrared light, respectively. The atoms photodetached from the huge surface of the silica matrix build up clusters, whereas cluster evaporation is increased by induced surface plasmon excitation. Frequency tuning of light activates either one process or the other and the related changes of glass transparency become visible to the naked eye. We demonstrate that the porous silica, loaded with rubidium, shows memory of illumination sequences behaving as a rereadable and rewritable optical medium. These processes take place as a consequence of the strong confinement of atoms and particles at the nanoscale.

  8. Rubidium efflux as a tool for the pharmacological characterisation of compounds with BK channel opening properties.

    PubMed

    McKay, Neil G; Kirby, Robert W; Lawson, Kim

    2008-01-01

    This chapter describes a method of assaying rubidium (Rb(+)) efflux as a measure of potassium channel activity. In this assay, rubidium acts as a tracer for potassium movement across the cell membrane. HEK 293 cells expressing the alpha subunit of the human brain large-conductance, voltage-activated, calcium-sensitive potassium channel (BK channel) are loaded with Rb(+), washed, and then incubated under experimental conditions. The cell supernatant is removed, and the remaining cell monolayer lysed. These two samples contain Rb(+) that has moved out of the cell and Rb(+) that remains in the cell, respectively. Measurement of the Rb(+) content of these samples by flame atomic absorption spectrometry allows calculation of the percentage Rb(+) efflux and, depending on the experimental design, provides pharmacological data about the control and test compounds used. In this chapter, we describe the protocol and steps for optimisation and illustrate this with data obtained using NS1619, a well-characterised BK channel opener.

  9. Multi-line fiber laser system for cesium and rubidium atom interferometry

    NASA Astrophysics Data System (ADS)

    Diboune, Clément; Zahzam, Nassim; Bidel, Yannick; Cadoret, Malo; Bresson, Alexandre

    2017-07-01

    We present an innovative fiber laser system for both cesium and rubidium manipulation. The architecture is based on frequency conversion of two lasers at 1560 nm and 1878 nm. By taking advantage of existing fiber components at these wavelengths, we demonstrate an all fiber laser system delivering 350 mW at 780 nm for rubidium and 210 mW at 852 nm for cesium. This result highlights the promising nature of such laser system especially for Cs manipulation for which no fiber laser system has been reported. It offers new perspectives for the development of atomic instruments dedicated to onboard applications and opens the way to a new generation of atom interferometers involving three atomic species $^{85}$Rb, $^{87}$Rb and $^{133}$Cs for which we propose an original laser architecture.

  10. Multi-line fiber laser system for cesium and rubidium atom interferometry.

    PubMed

    Diboune, Clément; Zahzam, Nassim; Bidel, Yannick; Cadoret, Malo; Bresson, Alexandre

    2017-07-24

    We present an innovative multi-line fiber laser system for both cesium and rubidium manipulation. The architecture is based on frequency conversion of two lasers at 1560 nm and 1878 nm. By taking advantage of existing high performance fibered components at these wavelengths, we have demonstrated multi-line operation of an all fiber laser system delivering 350 mW at 780 nm for rubidium and 210 mW at 852 nm for cesium. This result highlights the promising nature of such laser system especially for Cs manipulation for which no fiber laser system has been reported. It offers new perspectives for the development of atomic instruments dedicated to onboard applications and opens the way to a new generation of atom interferometers involving three atomic species ((85)Rb, (87)Rb and (133)Cs) for which we propose an original laser architecture.

  11. The Suppression of the Late After-Potential in Rubidium-Containing Frog Muscle Fibers

    PubMed Central

    Hellam, D. C.; Goldstein, D. A.; Peachey, L. D.; Freygang, W. H.

    1965-01-01

    The late after-potential that follows trains of impulses in frog muscle fibers is virtually absent when most of the intracellular potassium is replaced by rubidium and the muscle is immersed in rubidium-containing Ringer's fluid. Its amplitude is also reduced in freshly dissected, potassium-containing muscle fibers that are immersed directly in Rb-Ringer's fluid. These findings are discussed in terms of the model for muscle membrane of Adrian and Freygang (1962 a, b) and in relation to the report of Adrian (1964) that Rb-containing muscle fibers do not exhibit the variations in potassium permeability as a function of membrane potential that are found in fibers with normal intracellular potassium concentration immersed in Ringer's fluid. PMID:5855505

  12. Autonomous Rubidium Clock Weak Frequency Jump Detector for Onboard Navigation Satellite System.

    PubMed

    Khare, Akshay; Arora, Rajat; Banik, Alak; Mehta, Sanjay D

    2016-02-01

    Frequency jumps are common in rubidium frequency sources. They affect the estimation of user position in navigational satellite systems. These jumps must be detected and corrected immediately as they have direct impact on the navigation system integrity. A novel weak frequency jump detector is proposed based on a Kalman filter with a multi-interval approach. This detector can be applied for both "sudden" and "slow" frequency transitions. In this detection method, noises of clock data are reduced by Kalman filtering, for accurate estimation of jump size with less latency. Analysis on in-orbit rubidium atomic frequency standard (RAFS) phase telemetry data shows that the detector can be used for fast detection and correction of weak frequency jumps. Furthermore, performance comparison of different existing frequency jump detection techniques with the proposed detector is discussed. A multialgorithm-based strategy is proposed depending on the jump size and latency for onboard navigation satellites having RAFS as the primary frequency source.

  13. Highly reliable optical system for a rubidium space cold atom clock.

    PubMed

    Ren, Wei; Sun, Yanguang; Wang, Bin; Xia, Wenbing; Qu, Qiuzhi; Xiang, Jingfeng; Dong, Zuoren; Lü, Desheng; Liu, Liang

    2016-05-01

    We describe a highly reliable optical system designed for a rubidium space cold atom clock (SCAC), presenting its design, key technologies, and optical components. All of the optical and electronic components are integrated onto an optimized two-sided 300  mm×290  mm×30  mm optical bench. The compact optical structure and special thermal design ensure that the optical system can pass all of the space environmental qualification tests including both thermal vacuum and mechanical tests. To verify its performance, the optical system is carefully checked before and after each test. The results indicate that this optical system is suitably robust for the space applications for which the rubidium SCAC was built.

  14. Mathematical simulation of heating effects in a static diode-pumped vapor rubidium cell

    NASA Astrophysics Data System (ADS)

    Zhang, Wei; Wang, You; Han, Juhong; Cai, He; Xue, Liangping; Wang, Hongyuan

    2015-02-01

    Diode-pumped alkali lasers (DPALs) have attracted a lot of interests in the recent years because of their high Stokes efficiency, good beam quality, compact size, and near-infrared emission wavelengths. Until now, the thermal features have been only analyzed in an open alkali cell. In this report, we established a mathematical model to examine the heating effect of a static sealed rubidium cell by means of a Finite Difference (FD) procedure. After assuming the absorption coefficient of the alkali vapor, the temperature distributions of a real sealed rubidium vapor cell have been acquired for different powers and beam waists of the pump. The analytic conclusions would be helpful in designing a feasible DPAL.

  15. Rubidium-cation conductivity of Rb3-2 x Pb x PO4 solid solutions

    NASA Astrophysics Data System (ADS)

    Shekhtman, G. Sh.; Burmakin, E. I.

    2017-07-01

    New Rb3PO4-based ceramic materials with high rubidium-cation conductivity in the Rb3-2 x Pb x PO4 system have been synthesized and studied. Introduction of Pb2+ cations leads to a sharp increase in the conductivity of rubidium orthophosphate due to formation of cation vacancies and, at temperatures 350-550°C, also due to the stabilization of high-temperature cubic modification Rb3PO4. At high temperatures, the electrolytes prepared have very high ion conductivity higher than 10-1 S cm-1 at 700°C, which is higher than the values previously obtained in similar systems with additions of tin and cadmium ions. The factors influencing the transport properties of the materials under study are discussed.

  16. Bis(calix[4]diquinone) receptors: cesium- and rubidium-selective redox-active ionophores.

    PubMed

    Webber, Philip R A; Beer, Paul D; Chen, George Z; Felix, Vitor; Drew, Michael G B

    2003-05-14

    A new class of redox-active ionophore comprised of two calix[4]diquinone moieties connected through either alkylene or pyridylene linkages has been developed. Spectroscopic and electrochemical investigations, X-ray crystal structure analyses, and molecular modeling studies show butylene- and propylene-linked members of this family of redox-active receptors exhibit remarkable selectivity preferences and substantial electrochemical recognition effects toward cesium and rubidium cations.

  17. Development of a sub-miniature rubidium oscillator for SEEKTALK application

    NASA Technical Reports Server (NTRS)

    Fruehauf, H.; Weidemann, W.; Jechart, E.

    1981-01-01

    Warm-up and size challenges to oscillator construction are presented as well as the problems involved in these tasks. The performance of M-100 military rubidium oscillator is compared to that of a subminiture rubididum oscillator (M-1000). Methods of achieving 1.5 minute warm-up are discussed as well as improvements in performance under adverse environmental conditions, including temperature, vibration, and magnetics. An attempt is made to construct an oscillator error budget under a set of arbitrary mission conditions.

  18. Coherence protection by the quantum Zeno effect and nonholonomic control in a Rydberg rubidium isotope

    SciTech Connect

    Brion, E.; Akulin, V. M.; Comparat, D.; Kebaili, N.; Pillet, P.; Dumer, I.; Harel, G.; Kurizki, G.; Mazets, I.

    2005-05-15

    The protection of the coherence of open quantum systems against the influence of their environment is a very topical issue. A scheme is proposed here which protects a general quantum system from the action of a set of arbitrary uncontrolled unitary evolutions. This method draws its inspiration from ideas of standard error correction (ancilla adding, coding and decoding) and the quantum Zeno effect. A demonstration of our method on a simple atomic system--namely, a rubidium isotope--is proposed.

  19. Frequency stability of maser oscillators operated with cavity Q. [hydrogen and rubidium masers

    NASA Technical Reports Server (NTRS)

    Tetu, M.; Tremblay, P.; Lesage, P.; Petit, P.; Audoin, C.

    1982-01-01

    The short term frequency stability of masers equipped with an external feedback loop to increase the cavity quality factor was studied. The frequency stability of a hydrogen and a rubidium maser were measured and compared with theoretical evaluation. It is shown that the frequency stability passes through an optimum when the cavity Q is varied. Long term fluctuations are discussed and the optimum mid term frequency stability achievably by small size active and passive H-masers is considered.

  20. Rubidium-strontium and potassium-argon age of lunar sample 15555.

    NASA Technical Reports Server (NTRS)

    Murthy, V. R.; Evensen, N. M.; Jahn, B. M.; Coscio, M. R., Jr.

    1972-01-01

    The lunar mare basalt 15555 from the edge of Hadley Rille has been dated at 3.3 b.y. by both rubidium-strontium and potassium-argon techniques. Age and trace element abundances closely resemble those of the Apollo 12 mare basalts. Data from lunar basalts obtained thus far indicate that they cannot be derived by simple fractionation from a homogeneous source.

  1. Absolute frequency measurement of rubidium 5S-7S two-photon transitions.

    PubMed

    Morzyński, Piotr; Wcisło, Piotr; Ablewski, Piotr; Gartman, Rafał; Gawlik, Wojciech; Masłowski, Piotr; Nagórny, Bartłomiej; Ozimek, Filip; Radzewicz, Czesław; Witkowski, Marcin; Ciuryło, Roman; Zawada, Michał

    2013-11-15

    We report the absolute frequency measurements of rubidium 5S-7S two-photon transitions with a cw laser digitally locked to an atomic transition and referenced to an optical frequency comb. The narrow, two-photon transition, 5S-7S (760 nm), insensitive to first-order in a magnetic field, is a promising candidate for frequency reference. The performed tests yielded more accurate transition frequencies than previously reported.

  2. Process for separation of zirconium-88, rubidium-83 and yttrium-88

    DOEpatents

    Heaton, Richard C.; Jamriska, Sr., David J.; Taylor, Wayne A.

    1994-01-01

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets is provided and includes dissolving the molybdenum target in a hydrogen peroxide solution to form a first ion-containing solution, passing the first ion-containing solution through a first cationic resin whereby ions selected from the group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium and rubidium remain in the first ion-containing solution while ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium and zirconium are selectively adsorbed by the first resin, contacting the first resin with an acid solution capable of stripping adsorbed ions from the first cationic exchange resin whereby the adsorbed ions are removed from the first resin to form a second ion-containing solution, evaporating the second ion-containing solution for time sufficient to remove substantially all of the acid and water from the second ion-containing solution whereby a residue remains, dissolving the residue from the evaporated second-ion containing solution in a dilute acid to form a third ion-containing solution, said third ion-containing solution having an acid molarity adapted to permit said ions to be adsorbed by a cationic exchange resin, passing the third ion-containing solution through a second cationic resin whereby the ions are adsorbed by the second resin, contacting the second resin with a dilute sulfuric acid solution whereby the adsorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, and zirconium are selectively removed from the second resin, and contacting the second resin with a dilute acid solution whereby the adsorbed strontium ions are selectively removed. Zirconium, rubidium, and yttrium radioisotopes can also be recovered with additional steps.

  3. Observation of coherent effects using a mode-locked rubidium laser

    NASA Astrophysics Data System (ADS)

    Zhang, Aihua; Sautenkov, Vladimir A.; Rostovtsev, Yuri V.; Welch, George R.

    2017-02-01

    We study a diode-pumped alkaline rubidium laser operating at the D 1-line transition. The mode-locked regime of laser operation using an active technique inside the laser cavity has been demonstrated. We have also experimentally shown that the mode-locked laser radiation can be used to observe coherent effects: the electromagnetically induced transparency and the nonlinear Faraday rotation in Rb vapor.

  4. Early In-Orbit Performance of GPS Block IIR Rubidium Clocks

    DTIC Science & Technology

    1997-12-01

    29th Annual Precwe Time and Time Interval (PTTI) Meeting EARLY IN-ORBIT PERFORMANCE OF GPS BLOCK IIR RUBIDIUM CLOCKS W.J. Riley EG&G Frequency...Products 35 Congress Street Salem, MA 01970 USA Tire f is t Block IIR GPS navigation satel&, placed in orbit on July 22, 1997, carried a new...RQFS) needed for the Block IIR GPS progrm Composite frequency and t k - plo& are presented for all &livered units, and more detailed acceptance test

  5. Rubidium marking technique for the European corn borer (Lepidoptera: Pyralidae) in corn

    SciTech Connect

    Legg, D.E.; Chiang, H.C.

    1984-04-01

    Laboratory and greenhouse experiments conducted in 1980 showed that rubidium (Rb) could be used to mark corn plants and emergent European corn borer (ECB), Ostrinia nubilalis (Huebner), moths. Rb had no adverse effects on pre-adult mortality, moth deformity, or fecundity. The best application method for marking ECB moths was an over-the-top + directed foliar spray to the corn plants. 14 references, 1 figure, 4 tables.

  6. Prognostic value of rubidium-82 positron emission tomography in patients after heart transplant.

    PubMed

    Mc Ardle, Brian A; Davies, Ross A; Chen, Li; Small, Gary R; Ruddy, Terrence D; Dwivedi, Girish; Yam, Yeung; Haddad, Haissam; Mielniczuk, Lisa M; Stadnick, Ellamae; Hessian, Renee; Guo, Ann; Beanlands, Rob S; deKemp, Robert A; Chow, Benjamin J W

    2014-11-01

    Cardiac allograft vasculopathy is a key prognostic determinant after heart transplant. Detection and risk stratification of patients with cardiac allograft vasculopathy are problematic. Positron emission tomography using rubidium-82 allows quantification of absolute myocardial blood flow and may have utility for risk stratification in this population. Patients with a history of heart transplant undergoing dipyridamole rubidium-82 positron emission tomography were prospectively enrolled. Myocardial perfusion and left ventricular ejection fraction were recorded. Absolute flow quantification at rest and after dipyridamole stress as well as the ratio of mean global flow at stress and at rest, termed myocardial flow reserve, were calculated. Patients were followed for all-cause death, acute coronary syndrome, and heart failure hospitalization. A total of 140 patients (81% men; median age, 62 years; median follow-up, 18.2 months) were included. There were 14 events during follow-up (9 deaths, 1 acute coronary syndrome, and 4 heart failure admissions). In addition to baseline clinical variables (estimated glomerular filtration rate, previously documented cardiac allograft vasculopathy), relative perfusion defects, mean myocardial flow reserve, and mean stress myocardial blood flow were significant predictors of adverse outcome. Abnormalities on rubidium-82 positron emission tomography were predictors of adverse events in heart transplant patients. Larger prospective studies are required to confirm these findings. © 2014 American Heart Association, Inc.

  7. Occlusion of rubidium ions by the sodium-potassium pump: its implications for the mechanism of potassium transport

    PubMed Central

    Glynn, I. M.; Richards, D. E.

    1982-01-01

    1. The occlusion of rubidium ions by Na, K-ATPase has been investigated by suspending enzyme prepared from pig kidney outer medulla in media containing low concentrations of 86Rb, forcing the suspensions rapidly through small columns of cation-exchange resin, and measuring the amounts of radioactivity emerging from the columns. 2. When the suspension media contained 2 mM-ATP or ADP, or 15 mM-NaCl, the amounts of radioactivity emerging from the columns were greatly (and similarly) reduced, presumably because both nucleotides and sodium ions stabilized the enzyme in the E1 form. (See p. 19 for definition of E1 and E2). The extra radioactivity carried through the columns when nucleotides and sodium were absent was taken as a measure of the amount of rubidium occluded within the enzyme (in the E2 form) when it emerged from the resin. 3. By varying the flow rate, and therefore the time spent by the enzyme on the resin, and relating this to the amount of radioactivity emerging from the columns, we have been able to estimate the rate constant for the conformational change (E2 → E1) that allows the occluded rubidium ions to escape. At 20 °C, and in the absence of nucleotides, it is about 0·1 S-1. 4. The rate constant for rubidium release was the same in a sodium-containing as in a potassium-containing medium. The opposite effects of sodium and potassium ions on the poise of the equilibrium between the E1 and the E2 forms of the enzyme must, therefore, be due solely to opposite effects of these ions on the rate of conversion of E1 to E2. 5. The rate constant for rubidium release was greatly increased by ATP and by ADP. Both nucleotides appeared to act at low-affinity sites and without phosphorylating the enzyme. 6. Orthovanadate, in the presence of magnesium ions, stabilized the enzyme in the occluded-rubidium (E2Rb) form. 7. Ouabain, in the presence of magnesium ions, prevented the occlusion of rubidium ions. 8. We have measured the amount of rubidium occluded by the

  8. A medium-throughput functional assay of KCNQ2 potassium channels using rubidium efflux and atomic absorption spectrometry.

    PubMed

    Scott, Clay W; Wilkins, Deidre E; Trivedi, Shephali; Crankshaw, Denis J

    2003-08-15

    Heterologous expression of KCNQ2 (Kv7.2) results in the formation of a slowly activating, noninactivating, voltage-gated potassium channel. Using a cell line that stably expresses KCNQ2, we developed a rubidium flux assay to measure the functional activity and pharmacological modulation of this ion channel. Rubidium flux was performed in a 96-well microtiter plate format; rubidium was quantified using an automated atomic absorption spectrometer to enable screening of 1000 data points/day. Cells accumulated rubidium at 37 degrees C in a monoexponential manner with t(1/2)=40min. Treating cells with elevated extracellular potassium caused membrane depolarization and stimulation of rubidium efflux through KCNQ2. The rate of rubidium efflux increased with increasing extracellular potassium: the t(1/2) at 50mM potassium was 5.1 min. Potassium-stimulated efflux was potentiated by the anticonvulsant drug retigabine (EC(50)=0.5 microM). Both potassium-induced and retigabine-facilitated efflux were blocked by TEA (IC(50)s=0.4 and 0.3mM, respectively) and the neurotransmitter release enhancers and putative cognition enhancers linopirdine (IC(50)s=2.3 and 7.1 microM, respectively) and XE991 (IC(50)s=0.3 and 0.9 microM, respectively). Screening a collection of ion channel modulators revealed additional inhibitors including clofilium (IC(50) = 27 microM). These studies extend the pharmacological profile of KCNQ2 and demonstrate the feasibility of using this assay system to rapidly screen for compounds that modulate the function of KCNQ2.

  9. Crystal Structure and Ionic Conductivity of Three Polymorphic Phases of Rubidium Trefluoromethyl Sulfonate, RbSO3CF3

    SciTech Connect

    Hildebrandt,L.; Dinnebier, R.; Jansen, M.

    2006-01-01

    The crystal structures of three polymorphic phases of rubidium trifluoromethyl sulfonate (RbSO{sub 3}CF{sub 3}, rubidium 'triflate') were solved from X-ray powder diffraction data. At room temperature, rubidium triflate crystallizes in the monoclinic space group Cm with lattice parameters of a = 19.9611(5) Angstroms, b = 23.4913(7) Angstroms, c = 5.1514(2) Angstroms, = 102.758(2); Z = 16. At T = 321 K, a first-order phase transition occurs toward a monoclinic phase in space group P2{sub 1} with lattice parameters at T = 344 K of a = 10.3434(5) Angstroms, b = 5.8283(3) Angstroms, c = 5.1982(3) Angstroms, = 104.278(6); Z = (2). At T = 461 K, another phase transition, this time of second order, occurs toward an orthorhombic phase in space group Cmcm with lattice parameters at T = 510 K of a = 5.3069(2) Angstroms, b = 20.2423(10) Angstroms, c = 5.9479(2) Angstroms; Z = 4. As a common feature within all three crystal structures of rubidium triflate, the triflate anions are arranged in double layers with the lipophilic CF{sub 3} groups facing each other. The rubidium ions are located between the SO{sub 3} groups. The general packing is similar to the packing in cesium triflate. Rubidium triflate can be classified as a solid electrolyte with a specific ionic conductivity of = 9.89 x 10{sup -9} S/cm at T = 384 K and = 3.84 x 10{sup -6} S/cm at T = 481 K.

  10. The physics of the environmental sensitivity of rubidium gas cell atomic frequency standards

    NASA Technical Reports Server (NTRS)

    Riley, William J.

    1990-01-01

    Environmental sensitivity is often the most significant limitation to the practical stability of rubidium frequency standards (RFS). For example, temperature sensitivity can cause a rapid frequency change of several parts in 10(exp 10) for a tactical RFS that has an aging of only 1 times 10(exp -11)/month. Other important environmental factors are barometric pressure, vibration, magnetic field, and nuclear radiation. The physical mechanisms that lie behind these environmental sensitivities are considered. These physical mechanisms are related to the performance of actual rubidium frequency standards. For the user of these devices, a better knowledge of the causes for Rb clock instability will aid in their testing and proper application. For the time frequency specialist, a review of these factors may prove useful toward improving RFS design. Some of the RFS environmental sensitivities are due to simple physical mechanisms like the effect of dc magnetic field on the Rb hyperfine resonance frequency. For these, an analysis can be based on physical principles and straightforward design factors. Other environment factors, like temperature sensitivity, are more complex combinations of many effects, both physical and practical, and the analysis often takes the form of an error budget with large unit-to-unit variations. Today's rubidium frequency standards span a wide performance range from small, inexpensive units with pp 10(exp 10) error budgets to larger, higher performance versions offering pp 10(exp 10) stabilities. For both extremes, however, environmental sensitivity can be the most significant performance limitation. Why this is the case and how to make improvements are discussed.

  11. On the Uptake of Materials by the Intact Liver THE CONCENTRATIVE TRANSPORT OF RUBIDIUM-86

    PubMed Central

    Goresky, Carl A.; Bach, Glen G.; Nadeau, Brita E.

    1973-01-01

    In this study we use the multiple indicator dilution technique to outline the kinetic mechanisms underlying the uptake of rubidium, a cation which, in the steady state, is concentrated by hepatic parenchymal cells. We inject a mixture of 51Cr-labeled red blood cells (a vascular reference substance), 22Na (which is confined to the extracellular space, the expected extravascular distribution space for rubidium, in the absence of cellular uptake), and 86Rb into the portal vein and obtain normalized outflow patterns, expressed as outflowing fractions of each injected mass per milliliter vs. time. The labeled red cell curve rises to the highest and earliest peak and decays rapidly. That for labeled sodium rises to a later and lower peak, and decays less rapidly. Its extrapolated recovery is equal to that for the red cells. The observed 86Rb curve consists of two parts: an early clearly defined peak of reduced area, related to the 22Na peak in timing; and a later tailing, obscured by recirculation, so that total outflow recovery cannot be defined (even though it would be expected to be the same). We model the concentrative uptake of 86Rb and find two corresponding outflow fractions: throughput material, which sweeps past the cell surface as a wave delayed with respect to the vascular reference (tracer which has not entered cells); and exchanging material (tracer which has entered cells and later returns to the circulation). We find that the outflow form of the rubidium curve, the presence of both a relatively clearly defined throughput component and a relatively prolonged low-in-magnitude tailing, is consequent to the concentrative character of the transport mechanism, to the presence of an influx rate constant many times the efflux rate constant. The modeling which we develop is general, and has potential application in situations where transport is nonconcentrative. Images PMID:4573355

  12. Rubidium influx into rat skeletal muscles in relation to electrical activity

    PubMed Central

    Kernan, R. P.; McDermott, Mary

    1973-01-01

    1. Rates of 86Rb influx were compared in vivo over 2, 4 and 6 hr periods in various tonic and phasic muscles of rat following its I.P. injection. During the 2 hr period its influx rate into soleus was about 4 times that of the vastus with the EDL muscles at an intermediate rate. Uptake by diaphragm was fastest reaching equilibrium within 2 hr. 2. Unilateral section of the sciatic nerve 48 hr before 86Rb injection reduced isotope uptake into soleus to about 50% of its contralateral control muscle over a 4 hr period. In EDL muscles on the other hand nerve section increased influx by about 75% of control in conscious rats and more than doubled influx in anaesthetized rats. 3. Tenotomy of soleus reduced 86Rb influx to 40% of control, but tenotomy in EDL was without effect in influx. 4. Uptake of urea into muscles within 5 min of its I.V. injection was used to determine the possibility of muscle blood flow determining 86Rb influx. Accumulation of urea was not significantly different in control and denervated EDL muscles nor between soleus and vastus muscles in anaesthetized rats, so it seems unlikely that blood flow is important here. 5. Membrane depolarization in response to addition of 30 mM rubidium to external bathing fluid was greater in the case of denervated than in control EDL muscles which was in keeping with the greater 86Rb influx seen in the former muscles. The ouabain sensitivity of rubidium-induced depolarization in the denervated EDL muscles would suggest, however, that rubidium enters the fibres actively. PMID:4747232

  13. The physics of the environmental sensitivity of rubidium gas cell atomic frequency standards

    NASA Technical Reports Server (NTRS)

    Riley, William J.

    1990-01-01

    Environmental sensitivity is often the most significant limitation to the practical stability of rubidium frequency standards (RFS). For example, temperature sensitivity can cause a rapid frequency change of several parts in 10(exp 10) for a tactical RFS that has an aging of only 1 times 10(exp -11)/month. Other important environmental factors are barometric pressure, vibration, magnetic field, and nuclear radiation. The physical mechanisms that lie behind these environmental sensitivities are considered. These physical mechanisms are related to the performance of actual rubidium frequency standards. For the user of these devices, a better knowledge of the causes for Rb clock instability will aid in their testing and proper application. For the time frequency specialist, a review of these factors may prove useful toward improving RFS design. Some of the RFS environmental sensitivities are due to simple physical mechanisms like the effect of dc magnetic field on the Rb hyperfine resonance frequency. For these, an analysis can be based on physical principles and straightforward design factors. Other environment factors, like temperature sensitivity, are more complex combinations of many effects, both physical and practical, and the analysis often takes the form of an error budget with large unit-to-unit variations. Today's rubidium frequency standards span a wide performance range from small, inexpensive units with pp 10(exp 10) error budgets to larger, higher performance versions offering pp 10(exp 10) stabilities. For both extremes, however, environmental sensitivity can be the most significant performance limitation. Why this is the case and how to make improvements are discussed.

  14. Kinetics of Alkaline Decomposition and Cyaniding of Argentian Rubidium Jarosite in NaOH Medium

    NASA Astrophysics Data System (ADS)

    Rodríguez, Eleazar Salinas; Sáenz, Eduardo Cerecedo; Ramírez, Marius; Cardona, Francisco Patiño; Labra, Miguel Pérez

    2012-10-01

    The alkaline decomposition of Argentian rubidium jarosite in NaOH media is characterized by an induction period and a progressive conversion period in which the sulfate and rubidium ions pass to the solution, leaving an amorphous iron hydroxide residue. The process is chemically controlled and the order of reaction with respect to hydroxide concentration in the range of 1.75 and 20.4 mol OH- m-3 is 0.94, while activation energy in the range of temperatures of 298 K to 328 K (25 °C to 55 °C) is 91.3 kJ mol-1. Cyaniding of Argentian rubidium jarosite in NaOH media presents a reaction order of 0 with respect to NaCN concentration (in the range of 5 to 41 mol m-3) and an order of reaction of 0.62 with respect to hydroxide concentration, in the range of 1.1 and 30 mol [OH-] m-3. In this case, the cyaniding process can be described, as in other jarosites, as the following two-step process: (1) a step (slow) of alkaline decomposition that controls the overall process followed by (2) a fast step of silver complexation. The activation energy during cyaniding in the range of temperatures of 298 K to 333 K (25 °C to 60 °C) is 43.5 kJ mol-1, which is characteristic of a process controlled by chemical reaction. These results are quite similar to that observed for several synthetic jarosites and that precipitated in a zinc hydrometallurgical plant (Industrial Minera México, San Luis Potosi).

  15. Potassium hydrogen trans-glutaconate monohydrate at 295, 245 and 40 K, and its rubidium analogue at 298 K.

    PubMed

    Kashino, S; Taka, J; Fukunaga, T; Ishida, H

    2001-05-01

    A centrosymmetric and short O-H.O hydrogen bond was found in isomorphic crystals of potassium hydrogen trans-glutaconate monohydrate (potassium hydrogen trans-pent-2-ene-1,5-dioate, K(+).C(5)H(5)O(4)(-).H(2)O), (I), and rubidium hydrogen trans-glutaconate monohydrate (rubidium hydrogen trans-pent-2-ene-1,5-dioate, Rb(+).C(5)H(5)O(4)(-).H(2)O), (II). The O.O distance at room temperature is 2.444 (3) A in (I), and 2.417 (4) A in (II). The O.O distance for (I) showed no significant decrease at low temperatures.

  16. Electromagnetically induced transparency in rubidium vapor prepared by a comb of short optical pulses

    SciTech Connect

    Sautenkov, Vladimir A.; Rostovtsev, Yuri V.; Ye, C.Y.; Welch, George R.; Kocharovskaya, Olga; Scully, Marlan O.

    2005-06-15

    It was shown by Kocharovskaya and Khanin [Sov. Phys. JETP 63, 945 (1986)] that a comb of optical pulses can induce a ground-state atomic coherence and change the optical response of an atomic medium. In our experiment, we studied the propagation of a comb of optical pulses produced by a mode-locked diode laser in rubidium atomic vapor. Electromagnetically induced transparency (EIT) was observed when the pulse repetition rate is a subharmonic of the hyperfine splitting of the ground state. The width of the EIT resonance is determined by the relaxation rate of the ground-state coherence. Possible applications to magnetometery, atomic clocks, and frequency chains are discussed.

  17. Review: comparison of PET rubidium-82 with conventional SPECT myocardial perfusion imaging

    PubMed Central

    Ghotbi, Adam A; Kjær, Andreas; Hasbak, Philip

    2014-01-01

    Nuclear cardiology has for many years been focused on gamma camera technology. With ever improving cameras and software applications, this modality has developed into an important assessment tool for ischaemic heart disease. However, the development of new perfusion tracers has been scarce. While cardiac positron emission tomography (PET) so far largely has been limited to centres with on-site cyclotron, recent developments with generator produced perfusion tracers such as rubidium-82, as well as an increasing number of PET scanners installed, may enable a larger patient flow that may supersede that of gamma camera myocardial perfusion imaging. PMID:24028171

  18. Temperature Dependent Rubidium-Helium Line Shapes and Fine Structure Mixing Rates

    DTIC Science & Technology

    2015-09-17

    was loaded into the circulator in a nitrogen purged dry box. This single charge of rubidium was not depleted or reacted during the 9 months of...the effective potential proposed by Müller and Meyer. The electric dipole polarizabilities were taken as 9.245 a.u. for the Rb+ core and 1.3838 a.u...of large diode arrays combines the best features of electrically driven lasers with the inherent thermal management advantages of a gas lasers

  19. A heated vapor cell unit for dichroic atomic vapor laser lock in atomic rubidium

    NASA Astrophysics Data System (ADS)

    McCarron, Daniel J.; Hughes, Ifan G.; Tierney, Patrick; Cornish, Simon L.

    2007-09-01

    The design and performance of a compact heated vapor cell unit for realizing a dichroic atomic vapor laser lock (DAVLL) for the D2 transitions in atomic rubidium is described. A 5 cm long vapor cell is placed in a double-solenoid arrangement to produce the required magnetic field; the heat from the solenoid is used to increase the vapor pressure and correspondingly the DAVLL signal. We have characterized experimentally the dependence of important features of the DAVLL signal on magnetic field and cell temperature. For the weaker transitions both the amplitude and gradient of the signal are increased by an order of magnitude.

  20. Degenerate mixtures of rubidium and ytterbium for engineering open quantum systems

    NASA Astrophysics Data System (ADS)

    Vaidya, Varun Dilip

    In the last two decades, experimental progress in controlling cold atoms and ions now allows us to manipulate fragile quantum systems with an unprecedented degree of precision. This has been made possible by the ability to isolate small ensembles of atoms and ions from noisy environments, creating truly closed quantum systems which decouple from dissipative channels. However in recent years, several proposals have considered the possibility of harnessing dissipation in open systems, not only to cool degenerate gases to currently unattainable temperatures, but also to engineer a variety of interesting many-body states. This thesis will describe progress made towards building a degenerate gas apparatus that will soon be capable of realizing these proposals. An ultracold gas of ytterbium atoms, trapped by a species-selective lattice will be immersed into a Bose-Einstein condensate (BEC) of rubidium atoms which will act as a bath. Here we describe the challenges encountered in making a degenerate mixture of rubidium and ytterbium atoms and present two experiments performed on the path to creating a controllable open quantum system. The first experiment will describe the measurement of a tune-out wavelength where the light shift of 87Rb vanishes. This wavelength was used to create a species-selective trap for ytterbium atoms. Furthermore, the measurement of this wavelength allowed us to extract the dipole matrix element of the 5s → 6p transition in 87Rb with an extraordinary degree of precision. Our method to extract matrix elements has found use in atomic clocks where precise knowledge of transition strengths is necessary to account for minute blackbody radiation shifts. The second experiment will present the first realization of a degenerate Bose-Fermi mixture of rubidium and ytterbium atoms. Using a three-color optical dipole trap (ODT), we were able to create a highly-tunable, species-selective potential for rubidium and ytterbium atoms which allowed us to use 87

  1. Electron and positron scattering on rubidium at 200 eV

    SciTech Connect

    Chin, J. H.; Ratnavelu, K.; Zhou, Y.

    2014-03-05

    The recent implementation of the coupled-channels-optical method (CCOM) [1,2], in the study of the electron and positron-Rubidium(Rb) scattering at intermediate energies [3,4], shows that the continuum effect remains important as the energy increases, even to 100 eV. Here, we study the effect of the continuum in electron and positron scattering on Rb at an even higher energy namely 200 eV. The total, elastic and inelastic integral and differential cross sections are therefore calculated and compared to the available experimental [5] and theoretical data [6,7].

  2. Spin noise spectroscopy of rubidium atomic gas under resonant and non-resonant conditions

    NASA Astrophysics Data System (ADS)

    Ma, Jian; Shi, Ping; Qian, Xuan; Li, Wei; Ji, Yang

    2016-11-01

    The spin fluctuation in rubidium atom gas is studied via all-optical spin noise spectroscopy (SNS). Experimental results show that the integrated SNS signal and its full width at half maximum (FWHM) strongly depend on the frequency detuning of the probe light under resonant and non-resonant conditions. The total integrated SNS signal can be well fitted with a single squared Faraday rotation spectrum and the FWHM dependence may be related to the absorption profile of the sample. Project supported by the National Natural Science Foundation of China (Grant Nos. 91321310 and 11404325) and the National Basic Research Program of China (Grant No. 2013CB922304).

  3. Interim results from the characterization testing of the Engineering Development (EDM) rubidium clocks for satellite applications

    NASA Technical Reports Server (NTRS)

    Powers, Edward D., Jr.; Danzy, Fredrick

    1990-01-01

    Some interim results from the environmental testing program to evaluate the Engineering Design Model (EDM) of the EG and G Spaceborne Rubidium Clock are presented. This effort is in support of the Global Positioning System (GPS) BLOCK IIR program and is intended to characterize the performance of EG and G design for BLOCK IIR satellite applications. Two EG and G EDM units are currently under test at NRL's Clock Test Facility to measure the long-term frequency stability, drift, and frequency versus temperature characteristics.

  4. Frequency shifts in a rubidium frequency standard due to coupling to another standard

    NASA Technical Reports Server (NTRS)

    Jaduszliwer, Bernardo; Cook, R. A.; Frueholz, R. P.

    1990-01-01

    Highly reliable timing system, such as used on board satellites, may incorporate a hot standby atomic clock besides the active one. RF couplings between them may affect the performance of the active clock. The effect of such couplings between two rubidium atomic clocks was investigated, and it was found that they will add an oscillatory term to the Allan Variance of the active clock, degrading its frequency stability, and that under certain circumstances they may also shift the active clock's operating frequency. These two effects are discussed in detail, and the level of isolation required to render them negligible is established.

  5. Evaluation of the rubidium efflux assay for preclinical identification of HERG blockade.

    PubMed

    Chaudhary, Khuram W; O'Neal, Janet M; Mo, Zun-Li; Fermini, Bernard; Gallavan, Robert H; Bahinski, Anthony

    2006-02-01

    Inhibition of the delayed-rectifier potassium channel current, human ether-a-go-go (hERG), by pharmaceutical agents can lead to acquired long QT syndrome and the generation of potentially lethal arrhythmias and sudden death. There remains an unmet need for higher-throughput assays to screen compounds in preclinical development for the potential to block hERG and cause QT prolongation. We evaluated the rubidium efflux assay for its ability to determine block of the hERG potassium channel. hERG-transfected human embryonic kidney-293 cells were cultured on 96-well assay plates and loaded with rubidium ion by incubating in media in which potassium was replaced by 5.4 mM Rb+. Cells were exposed to test compounds and then depolarized with a K+ channel opening buffer containing 50 mM K+. The supernatant was removed, and cells were lysed using 0.1% Triton X-100. Concentration-response curves were generated for test agents by determining the Rb+ efflux using a flame atomic absorption spectrometer. Multiple trials with cisapride yielded 50% inhibitory concentration values between 308.1 +/- 11 nM to 456.3 +/- 24 nM for inhibition of Rb+ efflux and a Z factor of 0.80 +/- 0.07 (n = 5 plates, 12 wells per plate). The values for inhibition of the hERG channel exhibited a rightward shift in potency as compared to those measured using electrophysiological techniques. In addition, we evaluated 19 blinded compounds at 10 microM in the Rb+ efflux assay, and compared results to those using patch clamp electrophysiology and the dofetilide displacement binding assay. The dofetilide displacement binding assay yielded a good correlation with electrophysiological measurements of hERG block. The rubidium efflux assay lacked sensitivity to consistently identify significant channel blockade. In conclusion, the rubidium efflux assay provides a higher-throughput means to identify potent hERG channel blocking agents, but lacks the sensitivity required to accurately determine the potency of

  6. Transient coherence oscillation induced by a detuned Raman field in a rubidium {lambda} system

    SciTech Connect

    Park, Sung Jong; Cho, Hyuck; Kwon, Taeg Yong; Lee, Ho Seong

    2004-02-01

    The temporal evolution of coherent population trapping (CPT) was observed in rubidium atomic vapor when sudden changes were made to the detuning of a weak Raman field. The subsequent creation and destruction of CPT are caused by the temporal oscillations of optically induced Raman coherence, with their period depending on the Raman detuning. The oscillating signal was observed over a time of order of tens of milliseconds, and the dependence of the relaxation time on the cell temperature and laser power were investigated. The main features of the experimental observations were well explained by the time-dependent density-matrix equations.

  7. Optimising a High-Stability CW Laser-Pumped Rubidium Gas-Cell Frequency Standard

    NASA Astrophysics Data System (ADS)

    Affolderbach, C.; Gruet, F.; Miletic, D.; Mileti, G.

    2009-04-01

    We report on our development of a compact and high-performance laser-pumped Rubidium atomic frequency standard. The clock design is based on optical-microwave double-resonance using cw optical pumping, and a physical realization as simple as possible. Main development goals are a short-term instability of ≤ 6 × 10-13 τ-1/2 and a flicker floor of ≤ 1 × 10-14 up to one day. Here we discuss our approaches for controlling the clock's main physical parameters in view of optimized frequency stability.

  8. A stable frequency comb directly referenced to rubidium electromagnetically induced transparency and two-photon transitions

    NASA Astrophysics Data System (ADS)

    Hou, Dong; Wu, Jiutao; Zhang, Shuangyou; Ren, Quansheng; Zhang, Zhigang; Zhao, Jianye

    2014-03-01

    We demonstrate an approach to create a stable erbium-fiber-based frequency comb at communication band by directly locking the combs to two rubidium atomic transitions resonances (electromagnetically induced transparency absorption and two-photon absorption), respectively. This approach directly transfers the precision and stability of the atomic transitions to the comb. With its distinguishing feature of compactness by removing the conventional octave-spanning spectrum and f-to-2f beating facilities and the ability to directly control the comb's frequency at the atomic transition frequency, this stable optical comb can be widely used in optical communication, frequency standard, and optical spectroscopy and microscopy.

  9. Bright narrowband biphoton generation from a hot rubidium atomic vapor cell

    NASA Astrophysics Data System (ADS)

    Zhu, Lingbang; Guo, Xianxin; Shu, Chi; Jeong, Heejeong; Du, Shengwang

    2017-04-01

    We demonstrate the generation of high-quality narrowband biphotons from a Doppler-broadened hot rubidium atomic vapor cell. Choosing a double-Λ atomic energy level scheme for optimizing both spontaneous four-wave mixing nonlinear parametric interaction and electromagnetically induced transparency (EIT), we achieve a biphoton spectral brightness as high as 14 000 s-1 MHz-1. Meanwhile, we apply a spatially tailored optical pumping beam for reduction of the Raman noise and obtain a violation of the Cauchy-Schwarz inequality by a factor of 1023.

  10. Methane-based in situ temperature rise measurement in a diode-pumped rubidium laser.

    PubMed

    Wang, Rui; Yang, Zining; Wang, Hongyan; Xu, Xiaojun

    2017-02-15

    We measured active zone temperature rise of an operational diode-pumped rubidium laser non-perturbatively with methane-based near-infrared tunable diode laser spectroscopy (TDLAS). For a Rb+ methane diode-pumped alkali laser (DPAL), the temperature rise was obtained. Especially, the temperature differences (∼10  K) between lasing and un-lasing cases were well identified, which demonstrated a high sensitivity of the method. To our knowledge, this is the first demonstration of extending the methane-based TDLAS method to DPAL study.

  11. 28W average power hydrocarbon-free rubidium diode pumped alkali laser.

    PubMed

    Zweiback, Jason; Krupke, William F

    2010-01-18

    We present experimental results for a high-power diode pumped hydrocarbon-free rubidium laser with a scalable architecture. The laser consists of a liquid cooled, copper waveguide which serves to both guide the pump light and to provide a thermally conductive surface near the gain volume to remove heat. A laser diode stack, with a linewidth narrowed to approximately 0.35 nm with volume bragg gratings, is used to pump the cell. We have achieved 24W average power output using 4 atmospheres of naturally occurring helium ((4)He) as the buffer gas and 28W using 2.8 atmospheres of (3)He.

  12. Rubidium Recycling in a High Intensity Short Duration Pulsed Alkali Laser

    DTIC Science & Technology

    2010-03-01

    rubidium laser27 and a 48 W CW cesium laser .28 As time goes on the maximum output power of DPAL devices is 16 expected to rise with this research...greatly over the next couple of years. In 2007 Zhdanov and Knize demonstrated a 10 W CW cesium DPAL.11 This was followed in 2008 by a 17 W CW ...Encyclopedia of Optical Engineering, 901, 2003. 11. Boris Zhadanov and R. J. Knize. Diode-pumped 10 W continuous wave cesium laser . Optics Letters, 32:2167

  13. Measurement of the electric hyperfine coupling constant P/k in a uranyl rubidium nitrate crystal

    SciTech Connect

    Tambovtsev, D. I.

    2007-11-15

    New investigations with nuclei oriented in a single-crystal sample of uranyl rubidium nitrate required refining values of the constants that determine the degree of orientation. The results obtained from new measurements of the angular anisotropy of the emission of alpha particles from aligned {sup 233}U nuclei are presented in this article. A method for experimental-data treatment is described. New values of the hyperfine coupling constants for {sup 233}U and {sup 235}U are obtained with much smaller uncertainties.

  14. Power Enhancement of a Rubidium Vapor Laser With a Master Oscillator Power Amplifier (Postprint)

    DTIC Science & Technology

    2009-09-15

    Phys. Lett. 34, 655-658 (1979). 5 . W. F. Krupke, R. J. Beach, V. K. Kanz, and S. A. Payne, “Resonance transition 795-nm rubidium laser,” Opt. Lett...Kanz, and W. F. Krupke, “Multimode-diode-pumped gas (alkali-vapor) laser,” Opt. Lett. 31 , 353-355 (2006). 10. Y. Wang, T. Kasamatsu, Y.Zheng, H...OPTICS EXPRESS 8050 #94531 - $15.00 USD Received 7 Apr 2008; revised 4 May 2008; accepted 7 May 2008; published 19 May 2008 (DPAL) started rapidly gaining

  15. A heated vapor cell unit for dichroic atomic vapor laser lock in atomic rubidium.

    PubMed

    McCarron, Daniel J; Hughes, Ifan G; Tierney, Patrick; Cornish, Simon L

    2007-09-01

    The design and performance of a compact heated vapor cell unit for realizing a dichroic atomic vapor laser lock (DAVLL) for the D(2) transitions in atomic rubidium is described. A 5 cm long vapor cell is placed in a double-solenoid arrangement to produce the required magnetic field; the heat from the solenoid is used to increase the vapor pressure and correspondingly the DAVLL signal. We have characterized experimentally the dependence of important features of the DAVLL signal on magnetic field and cell temperature. For the weaker transitions both the amplitude and gradient of the signal are increased by an order of magnitude.

  16. A stable frequency comb directly referenced to rubidium electromagnetically induced transparency and two-photon transitions

    SciTech Connect

    Hou, Dong; Wu, Jiutao; Zhang, Shuangyou; Ren, Quansheng; Zhang, Zhigang; Zhao, Jianye

    2014-03-17

    We demonstrate an approach to create a stable erbium-fiber-based frequency comb at communication band by directly locking the combs to two rubidium atomic transitions resonances (electromagnetically induced transparency absorption and two-photon absorption), respectively. This approach directly transfers the precision and stability of the atomic transitions to the comb. With its distinguishing feature of compactness by removing the conventional octave-spanning spectrum and f-to-2f beating facilities and the ability to directly control the comb's frequency at the atomic transition frequency, this stable optical comb can be widely used in optical communication, frequency standard, and optical spectroscopy and microscopy.

  17. Potassium, rubidium, strontium, barium, and rare-Earth concentrations in lunar rocks and separated phases.

    PubMed

    Philpotts, J A; Schnetzler, C C

    1970-01-30

    Concentrations of potassium, rubidium, strontium, barium, and rareearth elements have been determined by mass spectrometric isotope dilution for eight Apollo 11 lunar samples and for some separated phases. Potassiumn and ritbidium are at chondritic levels, strontium at 15 times, and barium and rare earths at 30 to 100 times chondritic levels. There are trace element similarities between the lunar samples and basaltic achondrites, terrestrial dredge basalts and the bulk earth. The trace element data appear to be consistent with these lunar samples being the result of limited partial fusion of some material similar to the brecciated eucrite meteorites.

  18. A rubidium traced white-light etalon calibrator for MAROON-X

    NASA Astrophysics Data System (ADS)

    Stürmer, Julian; Seifahrt, Andreas; Schwab, Christian; Bean, Jacob L.

    2016-07-01

    We report on the construction and testing of a vacuum-gap Fabry-Perot etalon calibrator for high precision radial velocity spectrographs. The etalon is referenced against hyper fine transitions of rubidium to provide a precise wavelength calibrator for MAROON-X, a new fiber-fed, red-optical, high-precision radial-velocity spectrograph currently under construction for one of the twin 6.5m Magellan Telescopes in Chile. We demonstrate a turnkey system, ready to be installed at any current and next generation radial velocity spectrograph that requires calibration over a wide spectral band-pass. Uncertainties in the position of one etalon line are at the 10 cm s-1 level in individual measurements taken at 4 Hz. Our long-term stability is mainly limited by aging effects of the spacer material Zerodur, which imprints a 12 cm s-1 daily drift. However, as the etalon position is traced by the rubidium reference with a precision of <3 cm s-1 for integration times longer than 10s, we can fully account for this effect at the RV data reduction level.

  19. Rubidium Atoms on Helium Droplets: Analysis of AN Exotic Rydberg Complex

    NASA Astrophysics Data System (ADS)

    Lackner, Florian; Krois, Günter; Koch, Markus; Ernst, Wolfgang E.

    2012-06-01

    Rubidium atoms on the surface of superfluid helium droplets have been excited into Rydberg states. The excitation spectrum of the Rb-He_N system has been recorded from the 5^2D state manifold up to the ionization threshold by resonant three-photon-ionization time-of-flight spectroscopy. The observation of droplet size dependent shifts of excited states with respect to bare atom states is explained by a decreased quantum defect and a lowered ionization threshold. Within the scope of a Rydberg model we demonstrate that quantum defects and ionization thresholds are constant for each specific Rydberg series, which confirms the Rydberg character of excited Rubidium states on helium droplets. A set of six Rydberg series could be identified. Individual Rydberg states are observed with effective principle quantum numbers up to n* ≈ 19 and l ≤ 3, for which the expectation value of the electron orbital radius is about ten times larger than the droplet radius. M. Theisen, F. Lackner, G. Krois, and W.E. Ernst, J. Phys. Chem. Lett., 2, 2778-2782 (2011) F. Lackner, G. Krois, M. Theisen, M. Koch, and W.E. Ernst, Phys. Chem. Chem. Phys., 13, 18781-18788 (2011) J.E. Murphy, J.M. Berg, A.J. Merer, N.A. Harris, and R.W. Field, Phys. Rev. Lett. 65, 1861 (1990)

  20. Photoabsorption spectra of potassium and rubidium near the K-edge

    SciTech Connect

    Azuma, Y.; Berry, H.G.; Cowan, P.L.

    1995-08-01

    We have used a high-temperature circulating heat-pipe absorption cell together with monochromatized X-ray beams at the X24A and X23A2 beam lines at the NSLS to obtain photoabsorption spectra of potassium and rubidium at their K- and KM-edges. The photon-energy ranges lay near 3600 eV and 15200 eV, respectively. We have also obtained first measurements of the LII and LIII edges in cesium. Although the K-edge photoabsorptions of the rare gases have been studied, there is little previous work on other atomic vapors. Most of the edges and resonance peaks that we observed have now been identified using Dirac Hartree-Fock calculations. As a check, we have compared these results with those obtained previously in closed-shell rare-gas absorption spectra. The absolute energies were obtained through a calibration of the X24A systems using measurements of several metal L-edges in the 3200-5000 eV energy range. We found that the 4p resonance in potassium is significantly enhanced compared with the corresponding situation in argon. Likewise, the 5p resonance in krypton is unresolved from the background ionization cross section, whereas it is well resolved in rubidium. As suggested by Amusia, these enhancements may be due to the enhanced potential seen in the excited state of the alkali systems as a result of the presence of an s-electron which reduces the nuclear shielding.

  1. Breast milk concentration of rubidium in lactating mothers by instrumental neutron activation analysis method.

    PubMed

    Khatami, Seyedeh-Fatemeh; Parvaresh, Pouya; Parvaresh, Parviz; Madani Kouchak, Sara Sadat; Khorsandi, Jamshid

    2014-12-01

    Relatively little is known about the trace elements content of human milk from different countries. This has not been fully investigated especially among Iranian women. This study aimed to assess the concentration of Rubidium (Rb) as a poisonous trace element in transitional breast milk of lactating mothers living in Mashhad. Forty nursing mothers in early lactation 3 days to 15 days postpartum, free from any medical disorder and/or medication were randomly selected. We have applied Instrumental Neutron Activation Analysis (INAA) to assess the long-lived isotope trace element Rb in transitional milk of these economically moderate 18-39 year old Iranian women. The average concentration level of Rb was 32.176 ppm dry weight (min 8.660, max 107.210 ppm). No significant correlation was observed between Rb concentration and maternal weight and age (P=0.06, P=0.05 respectively) and newborns' weight, age and sex (P=0.07, P=0.2, P=0.2 respectively). Although the Rubidium concentration found in this study is among the highest reported in the literature, it could not be compared to other studies because of differences in analytical performance, state of lactation, and unavailable reference ranges, so this finding needs further investigations.

  2. RUBIDIUM AND CESIUM FLUXES IN MUSCLE AS RELATED TO THE MEMBRANE POTENTIAL

    PubMed Central

    Sjodin, Raymond A.

    1959-01-01

    The reduction of membrane potential in frog sartorius muscle produced by rubidium and cesium ions has been studied over a wide concentration range and compared with depolarization occasioned by potassium ions. The constant field theory of passive flux has been used to predict the potential changes observed. The potential data suggest certain permeability coefficient ratios and these are compared with ratios obtained from flux data using radioactive tracers. The agreement of the flux with the potential data is good if account is taken of the inhibition of potassium flux which occurs in the presence of rubidium and cesium ions. A high temperature dependence has been observed for cesium influx (Q10 = 2.5) which is correlated with the observation that cesium ions depolarize very little at low temperatures. The observations suggest that cesium ions behave more like sodium ions at low temperatures and more like potassium ions at room temperature with respect to their effect on the muscle cell resting potential. The constant field theory of passive ion flux appears to be in general agreement with the experimental results observed if account is taken of the dependence of permeability coefficients on the concentrations of ions used and of possible interactions between the permeabilities of ions. PMID:13654746

  3. Impact of pharmacological stress agent on patient motion during rubidium-82 myocardial perfusion PET/CT.

    PubMed

    Memmott, Matthew J; Tonge, Christine M; Saint, Kimberley J; Arumugam, Parthiban

    2017-01-04

    Patient motion has been demonstrated to have a significant impact on the quality and accuracy of rubidium-82 myocardial perfusion PET/CT. This study aimed to investigate the effect on patient motion of two pharmacological stressing agents, adenosine and regadenoson. Dynamic data were retrospectively analyzed in 90 patients undergoing adenosine (n = 30), incremental adenosine (n = 30), or regadenoson (n = 30) rubidium-82 myocardial perfusion PET/CT. Severity of motion was scored qualitatively using a four-point (0-3) scale and quantitatively using frame-to-frame pixel shifts. The type of motion, returning or non-returning, and the frame in which it occurred were also recorded. There were significant differences in both the qualitative and quantitative scores comparing regadenoson to adenosine (P = .025 and P < .001) and incremental adenosine (P = .014, P = .015), respectively. The difference in scores between adenosine and incremental adenosine was not significant. Where motion was present, significantly more adenosine patients were classed as non-returning (P = .018). The median frames for motion occurring were 12 for regadenoson and 14 for both adenosine cohorts. The choice of stressing protocol impacts significantly on patient motion. Patients stressed with regadenoson have significantly lower motion scores than those stressed with adenosine, using local protocols. This motion is more likely to be associated with a drift of the heart away from a baseline position, coinciding with the termination of infusion.

  4. Electric-field affected low-energy collisions between co-trapped ammonia and rubidium

    NASA Astrophysics Data System (ADS)

    Parazzoli, L. Paul

    This thesis describes the effect of an electric field on the interaction between rubidium and ammonia at 100 mK. The ability to study low energy interactions between molecules and atoms provides new tools to understand how the processes that govern these interactions work. For example, the use of external electric and magnetic fields provides tools to spatially orient molecules to show how this affects the dynamics of the interaction. The use of electric fields have been proposed to affect dipole-dipole interactions, however we have showed that the space-orienting effect of the field can have a significant effect even in the absence of dipole-dipole interaction. To measure this effect, we trap ammonia molecules in a single quantum state using an electrostatic trap. Rubidium atoms are trapped in a magnetic trap which is overlayed with the ammonia trap. The two samples then interact with minimal center of mass collision energy and we measure the elastic and inelastic cross sections by careful analysis of the ammonia trap-loss profile.

  5. Hydrothermal descriptive chemistry and single crystal structure determination of cesium and rubidium thorium fluorides.

    PubMed

    Underwood, Christopher C; Mann, Matthew; McMillen, Colin D; Kolis, Joseph W

    2011-11-21

    Two new cesium thorium fluorides and three new rubidium thorium fluorides have been synthesized hydrothermally and structurally characterized. The structures of two polymorphs of CsTh(3)F(13) are described in space group P6/mmm with a = 8.2608(14) and c = 8.6519(17) and space group Pmc2(1) with a = 8.1830(16), b = 7.5780(15), and c = 8.6244(17). The analogous orthorhombic compound RbTh(3)F(13), with a = 8.1805(16), b = 7.4378(15), and c = 8.6594(17) in space group Pmc2(1), is also reported. Two other rubidium thorium fluorides are also described: RbTh(2)F(9) crystallizes in the space group Pnma where a = 8.9101(18), b = 11.829(2), and c = 7.4048(15), and Rb(7)Th(6)F(31) crystallizes in the space group R3 where a = 15.609(2) and c = 10.823(2). Comparison of these materials was made on the basis of their structures and synthesis conditions. The formation of these species in hydrothermal fluids appears to be dependent upon the concentration of the alkali fluoride mineralizer solution and, thus, the ratio of alkali ions to thorium in the system.

  6. Breast Milk Concentration of Rubidium in Lactating Mothers by Instrumental Neutron Activation Analysis Method

    PubMed Central

    Khatami, Seyedeh-Fatemeh; Parvaresh, Pouya; Parvaresh, Parviz; Madani Kouchak, Sara Sadat; Khorsandi, Jamshid

    2014-01-01

    Objective: Relatively little is known about the trace elements content of human milk from different countries. This has not been fully investigated especially among Iranian women. This study aimed to assess the concentration of Rubidium (Rb) as a poisonous trace element in transitional breast milk of lactating mothers living in Mashhad. Methods: Forty nursing mothers in early lactation 3 days to 15 days postpartum, free from any medical disorder and/or medication were randomly selected. We have applied Instrumental Neutron Activation Analysis (INAA) to assess the long-lived isotope trace element Rb in transitional milk of these economically moderate 18–39 year old Iranian women. Findings: The average concentration level of Rb was 32.176 ppm dry weight (min 8.660, max 107.210 ppm). No significant correlation was observed between Rb concentration and maternal weight and age (P=0.06, P=0.05 respectively) and newborns’ weight, age and sex (P=0.07, P=0.2, P=0.2 respectively). Conclusion: Although the Rubidium concentration found in this study is among the highest reported in the literature, it could not be compared to other studies because of differences in analytical performance, state of lactation, and unavailable reference ranges, so this finding needs further investigations. PMID:26019773

  7. Construction and Implementation of a Low-Cost Rubidium Magneto-Optical Trap

    NASA Astrophysics Data System (ADS)

    Olson, Judith

    2011-03-01

    A low-cost magneto-optical trap (MOT) for ultra-cold atoms is a wonderful tool for undergraduate research and teaching laboratories that highlights many topics in modern physics. We researched and created such a MOT using two external-cavity diode lasers, two laser locking systems, optics, magnetic coils, and Rubidium vapor cells. At our undergraduate institution, we chose a combination of equipment that we fabricated ourselves together with some purchased items as an optimum balance between cost and building time. However, an emphasis was placed upon self-construction of components, such as machining the laser cavities and constructing the majority of the circuitry within the institution. The total cost of our MOT was about 25,000. We were successfully able to trap more than 10 million Rubidium atoms in 1 cubic centimeter. Such a MOT is a feasible addition to any undergraduate course of study. The theory of operation and construction methods of our MOT will be presented along with our first measurement results. Many thanks to Ithaca College and the Ithaca College Department of Physics.

  8. A non-invasive method of measuring concentrations of rubidium in rat skeletal muscle in vivo by 87Rb nuclear magnetic resonance spectroscopy: implications for the measurement of cation transport activity in vivo.

    PubMed

    Syme, P D; Dixon, R M; Allis, J L; Aronson, J K; Grahame-Smith, D G; Radda, G K

    1990-03-01

    1. We have used n.m.r. spectroscopy to measure rubidium concentrations in the skeletal muscle of live intact rats. Using a 1.9 T superconducting magnet and an ear-phone coil tuned to both protons (1H) and rubidium (87Rb), it was possible to make measurements of both tissue rubidium content and water content, and from these measurements to obtain the rubidium concentration. 2. The n.m.r. estimate of rubidium concentration in muscle in vivo was found to be a constant 31% (SEM 4%) of that estimated by flame atomic absorption spectroscopy in an extract of excised muscle. This is close to the predicted theoretical n.m.r. visibility of 33%. The visibility was constant for muscle rubidium concentrations ranging between 10 and 34 mmol/l. 3. Rubidium concentration measurement by this method is unaffected by variations in sample geometry, sample volume, tissue conductivity, coil tuning and amplifier gain. 4. By using this method to measure changes in tissue rubidium concentration with time in the same animal, it should now be possible to assess the activity of ion transport systems, such as sodium- and potassium-activated adenosine triphosphatase in vivo, by measuring the rates of change of tissue rubidium concentrations during the administration of rubidium salts. 5. This method could also be used to measure the absolute concentration of any n.m.r.-visible nucleus and could be applied to man.

  9. Accumulation of caesium and rubidium in vivo by red and white muscles of the rat

    PubMed Central

    Kernan, R. P.

    1969-01-01

    1. Rats were given drinking water containing either 20 mM-CsCl or 20 mM-RbCl for a period of 2 weeks. Samples of blood were then taken from the rats under anaesthetic. They were immediately centrifuged and the plasma taken for analysis. Soleus muscles, diaphragm, extensor digitorum longus, white gastrocnemius and vastus lateralis muscles were then taken from the dead animals and these and the plasma were analysed for potassium, and for caesium or rubidium by means of the flame photometer. 2. The concentrations of potassium and rubidium or caesium in the fibre water of these various muscles and in the samples of plasma water were then calculated. 3. It was found that the red muscles including soleus and diaphragm generally tended to accumulate caesium and rubidium to a greater extent than did the white muscles such as the white gastrocnemius and vastus lateralis. 4. When the concentration ratio [K]i/[K]o was divided into the ratio [Rb]i/[Rb]o for the different muscles, values of about 1·3 were obtained for the red muscles compared with values about 1·14 for white muscles. 5. When in the case of the caesium-treated rats the ratio [K]i/[K]o was divided into the ratio [Cs]i/[Cs]o values ranged from 1·94 ± 0·12 for the red soleus to 1·08 ± 0·09 for the white gastrocnemius. 6. When these values in the caesium-treated animals were plotted against the percentage of red fibres in the five muscle types (as obtained from the data of Sreter & Woo, 1963) the graph indicated that the white fibres had similar ionic gradients for Cs+ and K+ and that affinity for Cs+ was confined to the red fibres. 7. The membrane potential measured in soleus and extensor muscles immersed in plasma from the same animal was not significantly different from EK but was much less than ECs. 8. These results are interpreted in terms of permeability differences between the slow red fibres and white twitch fibres. PMID:5352044

  10. A rubidium Mx-magnetometer for measurements on solid state spins.

    PubMed

    Arnold, Daniel; Siegel, Steven; Grisanti, Emily; Wrachtrup, Jörg; Gerhardt, Ilja

    2017-02-01

    The detection of environmental magnetic fields is well established by optically pumped atomic magnetometers. Another focus of magnetometry can be the research on magnetic or spin-active solid-state samples. Here we introduce a simple and compact design of a rubidium-based Mx magnetometer, which allows for hosting solid-state samples. The optical, mechanical, and electrical design is reported, as well as simple measurements which introduce the ground-state spin-relaxation time, the signal-to-noise ratio of a measurement, and subsequently the overall sensitivity of the magnetometer. The magnetometer is optimized for the most sensitive operation with respect to laser power and magnetic field excitation at the Larmor frequency.

  11. Search for anomalous spin-mass coupling with a rubidium magnetometer

    NASA Astrophysics Data System (ADS)

    Lacey, Ian; Jacome, L. R.; Chan, Lok Fai; Muhsin, Sahar; Boyd, Alec; Bahr, Eric; Guttikonda, Srikanth; Kimball, Derek

    2009-11-01

    We report on progress of our experiment using a dual-isotope rubidium magnetometer to search for a hypothetical long-range coupling between Rb nuclear spins and the mass of the Earth. The valence electron dominates magnetic interactions and serves as a precise co-magnetometer for the nuclei in a simultaneous measurement of Rb-85 and Rb-87 spin precession frequencies, enabling accurate subtraction of magnetic perturbations. The construction and optimization of the apparatus is nearly complete, and we are now addressing several technical sources of noise and studying potential sources of systematic error. The optimized dual-isotope Rb magnetometer has sufficient shot- noise-projected sensitivity to improve experimental limits on long-range spin-mass couplings by an order of magnitude in general and by two orders of magnitude for the proton spin in particular.

  12. The phase transition of rubidium hydrogen carbonate, RbHCO3.

    PubMed

    Larvor, Carla; Stöger, Berthold

    2017-07-01

    Rubidium hydrogen carbonate, RbHCO3, features an order/disorder phase transition at TC = 245 K from the high-temperature (HT) disordered C2/m modification to the low-temperature (LT) C-1 modification. The crystal structures are characterized by [HCO3]2(2-) pairs of hydrogen carbonate groups connected by strong hydrogen bonding. The [HCO3]2(2-) pairs are connected by Rb(+) cations into a three-dimensional network. In HT-RbHCO3, the hydrogen atom is disordered. In LT-RbHCO3, ordering of the hydrogen atom leads to a translation-engleiche symmetry reduction of index 2. The lost reflections and rotations are retained as twin operations.

  13. Accumulation of myoinositol and rubidium ions in galactose-exposed rat lens

    SciTech Connect

    Kawaba, T.; Cheng, H.M.; Kinoshita, J.H.

    1986-10-01

    When rat lens is incubated in 30 mM galactose overnight, the extent of accumulation of rubidium ions (Rb) and myoinositol (MI) are affected, as well as the Na-K ATPase activity. Rb accumulation and Na-K ATPase activity are only slightly affected compared to the dramatic drop in MI accumulation. These changes are completely abolished by sorbinil, which blocks polyol formation, or by rendering the galactose medium hypertonic to offset the osmotic effect of polyol formation. On the other hand, the addition of excess MI to the galactose medium had no effect on correcting these changes. The results obtained are consistent with the polyol-osmotic theory of sugar cataract formation.

  14. High polarizability and pyroelectric effect in nonequilibrium nonpolar phases of rubidium dihydroarsenate and potash alum

    SciTech Connect

    Gavrilova, N.D.; Lotonov, A.M.

    1994-08-01

    In this work, the authors studied the thermodynamically nonequilibrium ferroelectriclike state formed under certain conditions in the nonpolar phases of dielectric crystals with hydrogen bonds. This state forms upon fast cooling of a crystal to temperature at which protons can move from their positions into interstices. Studied were the crystals of a ferroelectric: rubidium dihydroarsenate (RDA) with T{sub c}=110 Kelvin, potash alum, and a linear pyroelectric (barium nitrite monohydrate) over the temperature range 245-303 Kelvin. It was found that rapid cooling of some dielectric crystals with hydrogen bonds results in the formation of a metastable, ferroelectric-like state, which is likely to be associated with the formation and self-organization of a system of flickering dipoles caused by interstitial proton vacancies. Upon rapid cooling, the nonpolar phases of the crystals exhibit anomalous pyroelectric and dielectric properties resembling those of ferroelectrics below the Curie point.

  15. Frequency moments and elastic moduli of liquid rubidium at different temperatures

    NASA Astrophysics Data System (ADS)

    Patel, A. B.; Bhatt, N. K.; Thakore, B. Y.; Jani, A. R.

    2013-06-01

    To shed light on structural and vibrational dynamics of liquid rubidium (Rb) at different temperatures; a treatment of pseudopotential theory has been performed. The temperature dependence of structure factor and pair correlation functions has been determined using Percus-Yevick approximation consistent to the model potential used. In the present study, a modified empty core potential is employed to explain an electron-ion interaction. It consists of the full electron-ion interaction and a delta function which represents the orthogonalisation effect due to the s-core states in such sp-bonded metals. The temperature dependence of pair potential is achieved by using the damping factor exp(-αkBTr/2kF) in the pair potential. Expressions for phonon dispersions are derived using different frequency moments. Results for longitudinal phonon frequencies and various elastic moduli are obtained.

  16. Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance.

    PubMed

    Saliba, Michael; Matsui, Taisuke; Domanski, Konrad; Seo, Ji-Youn; Ummadisingu, Amita; Zakeeruddin, Shaik M; Correa-Baena, Juan-Pablo; Tress, Wolfgang R; Abate, Antonio; Hagfeldt, Anders; Grätzel, Michael

    2016-10-14

    All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb(+)) can be embedded into a "cation cascade" to create perovskite materials with excellent material properties. We achieved stabilized efficiencies of up to 21.6% (average value, 20.2%) on small areas (and a stabilized 19.0% on a cell 0.5 square centimeters in area) as well as an electroluminescence of 3.8%. The open-circuit voltage of 1.24 volts at a band gap of 1.63 electron volts leads to a loss in potential of 0.39 volts, versus 0.4 volts for commercial silicon cells. Polymer-coated cells maintained 95% of their initial performance at 85°C for 500 hours under full illumination and maximum power point tracking.

  17. High-precision masses of neutron-deficient rubidium isotopes using a Penning trap mass spectrometer

    SciTech Connect

    Kellerbauer, A.; Audi, G.; Guenaut, C.; Lunney, D.; Beck, D.; Herfurth, F.; Kluge, H.-J.; Weber, C.; Yazidjian, C.; Blaum, K.; Bollen, G.; Schwarz, S.; Herlert, A.; Schweikhard, L.

    2007-10-15

    The atomic masses of the neutron-deficient radioactive rubidium isotopes {sup 74-77,79,80,83}Rb have been measured with the Penning trap mass spectrometer ISOLTRAP. Using the time-of-flight cyclotron resonance technique, relative mass uncertainties ranging from 1.6x10{sup -8} to 5.6x10{sup -8} were achieved. In all cases, the mass precision was significantly improved as compared with the prior Atomic-Mass Evaluation; no significant deviations from the literature values were observed. The exotic nuclide {sup 74}Rb, with a half-life of only 65 ms, is the shortest-lived nuclide on which a high-precision mass measurement in a Penning trap has been carried out. The significance of these measurements for a check of the conserved-vector-current hypothesis of the weak interaction and the unitarity of the Cabibbo-Kobayashi-Maskawa matrix is discussed.

  18. Signatures of shape transitions in odd-A neutron-rich rubidium isotopes

    SciTech Connect

    Rodriguez-Guzman, R.; Sarriguren, P.; Robledo, L. M.

    2010-12-15

    The isotopic evolution of the ground-state nuclear shapes and the systematics of one-quasiproton configurations are studied in odd-A Rubidium isotopes. We use a self-consistent Hartree-Fock-Bogoliubov formalism based on the Gogny energy density functional with two parametrizations, D1S and D1M, and implemented with the equal-filling approximation. We find clear signatures of a sharp shape transition at N=60 in both the charge radii and spin parity of the ground states, which are robust, consistent with each other, and in agreement with experiment. We point out that the combined analysis of these two observables could be used to predict unambiguously new regions where shape transitions might develop.

  19. Solution-phase synthesis of rubidium lead iodide orthorhombic perovskite nanowires

    NASA Astrophysics Data System (ADS)

    Lim, Da-Hye; Ramasamy, Parthiban; Kwak, Do-Hyun; Lee, Jong-Soo

    2017-06-01

    Recently, metal halide perovskite nanocrystals have demonstrated outstanding properties in various optoelectronic applications. Cesium lead halides (CsPbX3) are the most studied perovskites in nanoscale dimensions. However, halide perovskite nanocrystals with other cations have rarely been reported. It is important to develop new perovskite compositions to further expand their application in various fields. In this paper, we first report the synthesis of colloidal rubidium lead iodide (RbPbI3) nanowires (NWs). RbPbI3 NWs have an orthorhombic crystal structure and are single-crystalline in nature. The diameter of the NWs is around 32 nm with lengths up to several tens of micrometers. RbPbI3 NWs absorb strongly below 450 nm. RbPbI3 devices exhibited good photoresponsive behavior, suggesting a potential use in optoelectronics.

  20. Trap loss in a metastable helium-rubidium magneto-optical trap

    SciTech Connect

    Byron, L. J.; Dall, R. G.; Truscott, A. G.

    2010-01-15

    We present results of the study of a simultaneously confined metastable helium (He*) and rubidium magneto-optical trap (MOT). By monitoring the trap decay of the {sup 87}Rb MOT with and without a He* MOT present, we find the light-assisted, two-body loss rate to be beta{sub Rb-He}{sup *}=(6+-2)x10{sup -10} cm{sup 3}/s. Moreover, we find that it is possible to create a large, robust {sup 87}Rb-He* MOT, opening the possibility of creating a {sup 87}Rb-He{sup *} Bose-Einstein condensate. This would be the first dual-species condensate incorporating an alkali metal ground-state atom and an excited-state noble gas atom.

  1. Dynamics of solvation and desolvation of rubidium attached to He nanodroplets

    SciTech Connect

    Vangerow, J. von; John, O.; Stienkemeier, F.; Mudrich, M.

    2015-07-21

    The real-time dynamics of photoexcited and photoionized rubidium (Rb) atoms attached to helium (He) nanodroplets is studied by femtosecond pump-probe mass spectrometry. While excited Rb atoms in the perturbed 6p-state (Rb{sup *}) desorb off the He droplets, Rb{sup +} photoions tend to sink into the droplet interior when created near the droplet surface. The transition from Rb{sup +} solvation to full Rb{sup *} desorption is found to occur at a delay time τ ∼ 600 fs for Rb{sup *} in the 6pΣ-state and τ ∼ 1200 fs for the 6pΠ-state. Rb{sup +}He ions are found to be created by directly exciting bound Rb{sup *}He exciplex states as well as by populating bound Rb{sup +}He-states in a photoassociative ionization process.

  2. Antiferromagnetism in a bosonic mixture of rubidium ({sup 87}Rb) and potassium ({sup 41}K)

    SciTech Connect

    Shrestha, Uttam

    2010-10-15

    We simulate the experimental possibility of observing antiferromagnetic (AF) order in bosonic mixtures of rubidium ({sup 87}Rb) and potassium ({sup 41}K) in a two-dimensional optical lattice in the presence of harmonic confinement. By tuning the interspecies interactions and the lattice heights, we have found the ground states, within the mean-field approximation, that interpolate from phase separation to AF order. For a moderate lattice height, the coexistence of the Mott and AF phases is possible for the Rb atoms whereas the K atoms remain in the AF-superfluid phase. This observation may provide an experimentally feasible route to hitherto unobserved AF order for {sup 87}Rb-{sup 41}K mixtures.

  3. Laboratory evaluation of rubidium as a long-lasting marker for bloodfeeding sand flies (Diptera: Psychodidae).

    PubMed

    Mascari, T M; Stout, R W; Foil, L D

    2012-01-01

    The objective of this study was to evaluate the use of the trace element rubidium (Rb) as a long-lasting systemic biomarker for bloodfeeding females of the sand fly Phlebotomus papatasi Scopoli. Baits containing Rb chloride were found to be palatable to hamsters in this study. We were able to detect Rb using a portable X-ray fluorescence analyzer in all sand flies that fed on Rb-treated hamsters for at least 14 d postbloodmeal. We also detected Rb in sand flies that took a bloodmeal from hamsters up to 10 d after the hamsters were withdrawn from a Rb-treated diet. Results of this study constitute proof of concept for the incorporation of Rb chloride into rodent baits for marking bloodfeeding sand flies, and suggest that Rb marking could be used as a technique for evaluating rodent-targeted sand fly control methods and in ecological studies on sand flies.

  4. Review: comparison of PET rubidium-82 with conventional SPECT myocardial perfusion imaging.

    PubMed

    Ghotbi, Adam A; Kjaer, Andreas; Hasbak, Philip

    2014-05-01

    Nuclear cardiology has for many years been focused on gamma camera technology. With ever improving cameras and software applications, this modality has developed into an important assessment tool for ischaemic heart disease. However, the development of new perfusion tracers has been scarce. While cardiac positron emission tomography (PET) so far largely has been limited to centres with on-site cyclotron, recent developments with generator produced perfusion tracers such as rubidium-82, as well as an increasing number of PET scanners installed, may enable a larger patient flow that may supersede that of gamma camera myocardial perfusion imaging. © 2013 The Authors. Clinical Physiology and Functional Imaging published by John Wiley & Sons Ltd on behalf of the Scandinavian Society of Clinical Physiology and Nuclear Medicine.

  5. Experimental study of linear magnetic dichroism in photoionization satellite transitions of atomic rubidium

    SciTech Connect

    Jaenkaelae, K.; Alagia, M.; Feyer, V.; Richter, R.; Prince, K. C.

    2011-11-15

    Laser orientation in the initial state has been used to study the properties of satellite transitions in inner-shell photoionization of rubidium atoms. The linear magnetic dichroism in the angular distribution (LMDAD) has been utilized to probe the continuum waves of orbital angular momentum conserving monopole, and angular momentum changing conjugate satellites, accompanying the 4p ionization of atomic Rb. We show experimentally that LMDAD of both types of satellite transitions is nonzero and that LMDAD of monopole satellites, measured as a function of photon energy, mimics the LMDAD of direct photoionization, whereas the LMDAD of conjugate transitions deviates drastically from that trend. The results indicate that conjugate transitions cannot be described theoretically without explicit inclusion of electron-electron interaction. The present data can thus be used as a very precise test of current models for photoionization.

  6. Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance

    NASA Astrophysics Data System (ADS)

    Saliba, Michael; Matsui, Taisuke; Domanski, Konrad; Seo, Ji-Youn; Ummadisingu, Amita; Zakeeruddin, Shaik M.; Correa-Baena, Juan-Pablo; Tress, Wolfgang R.; Abate, Antonio; Hagfeldt, Anders; Grätzel, Michael

    2016-10-01

    All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb+) can be embedded into a “cation cascade” to create perovskite materials with excellent material properties. We achieved stabilized efficiencies of up to 21.6% (average value, 20.2%) on small areas (and a stabilized 19.0% on a cell 0.5 square centimeters in area) as well as an electroluminescence of 3.8%. The open-circuit voltage of 1.24 volts at a band gap of 1.63 electron volts leads to a loss in potential of 0.39 volts, versus 0.4 volts for commercial silicon cells. Polymer-coated cells maintained 95% of their initial performance at 85°C for 500 hours under full illumination and maximum power point tracking.

  7. Pulse reshaping in nearly resonant interaction of femtosecond pulses with dense rubidium vapor

    NASA Astrophysics Data System (ADS)

    Vdović, Silvije; Skenderović, Hrvoje; Pichler, Goran

    2016-07-01

    Propagation of intense femtosecond pulses resonant with the atomic rubidium vapor results in phenomenon known as conical emission. The origin of this phenomenon is connected with self-phase modulation in time domain accompanied with spatial self-focusing for blue-detuned pulses. When the laser central wavelength is red-detuned the self-defocusing occurs. Using frequency-resolved optical gating measurements and simple modeling of pulse propagation within the linear dispersion theory it is shown that the retrieved phase of the propagated pulse, and the associated instantaneous frequency, shows evidence of both linear dispersion and self-phase modulation. These results are consistent with the theory of the intensity dependent nonlinear refraction index in medium where linear dispersion contributes significantly to pulse reshaping.

  8. Fractionation of potassium/rubidium by amphiboles: implications regarding mantle composition.

    PubMed

    Hart, S R; Aldrich, L T

    1967-01-20

    We show that the rubidium in amphiboles is generally depleted with respect to potassium. The K:Rb ratios of 50 analyzed amphiboles range from 100 to 5000, averaging 1120. This fractionation effect holds for potassium concentrations ranging from 0.05 to 1.5 percent. The K:Rb ratios of abyssal tholeiites do not place unambiguous limits on the K:Rb ratio of the upper mantle, since partial melting of a mantle material such as amphibole peridotite would produce a liquid with a K:Rb ratio higher than that in the initial material. Large-scale mineralogic control of distributions of trace elements in the mantle could produce trends with depth that are the reverse of trends normally attributed to differentiation processes.

  9. The physics of the environmental sensitivity of rubidium gas cell atomic frequency standards.

    PubMed

    Riley, W R

    1992-01-01

    The physical mechanisms behind environmental sensitivity are considered, and they are related to the performances of rubidium frequency standards (RFSs). Some of the RFS environmental sensitivities are due to simple physical mechanisms like the effect of DC magnetic field on the Rb hyperfine resonance frequency. For these, an analysis can be based on physical principles and straightforward design factors. Other environmental factors, like temperature sensitivity, are more complex combinations of many effects, both physical and practical, and the analysis often takes the form of an error budget, with large unit-to-unit variations. Today's RFSs span a wide performance range from small, inexpensive units with pp10(10) error budgets to larger, higher-performance versions offering pp10(14) stabilities. For both extremes, however, environmental sensitivity can be the most significant performance limitation. Why this is the case is explained, and some insight into how to make improvements is offered.

  10. Efficient light storage with reduced energy loss via nonlinear compensation in rubidium vapor

    NASA Astrophysics Data System (ADS)

    Wang, Gang; Zhou, Wei; Chen, Hong-Li; Xue, Yan; Wu, Jin-Hui; Xu, Huai-Liang; Gao, Jin-Yue

    2016-06-01

    We report an experimental demonstration of efficient light storage based on a modified technique of electromagnetically induced transparency in hot rubidium vapor. By introducing an auxiliary pump field to go beyond the Λ -type configuration, we find that the undesired four-wave mixing can be greatly suppressed to result in sufficiently reduced energy loss of a probe pulse. The light storage efficiency can be as high as  ∼80% within the storage time of 100 ns with the pump field applied, which is almost 6 times larger than that in the absence of the pump field. We may also amend the light storage efficiency in a linear way by increasing the optical depth of our atomic vapor even without saturation effect. We obtain, in fact, an amplified probe pulse via Raman gain during light storage and retrieval, which should have practical applications in classical and quantum information processing.

  11. Millimeter wave detection via Autler-Townes splitting in rubidium Rydberg atoms

    SciTech Connect

    Gordon, Joshua A. Holloway, Christopher L.; Schwarzkopf, Andrew; Anderson, Dave A.; Miller, Stephanie; Thaicharoen, Nithiwadee; Raithel, Georg

    2014-07-14

    In this paper, we demonstrate the detection of millimeter waves via Autler-Townes splitting in {sup 85}Rb Rydberg atoms. This method may provide an independent, atom-based, SI-traceable method for measuring mm-wave electric fields, which addresses a gap in current calibration techniques in the mm-wave regime. The electric-field amplitude within a rubidium vapor cell in the WR-10 wave guide band is measured for frequencies of 93.71 GHz and 104.77 GHz. Relevant aspects of Autler-Townes splitting originating from a four-level electromagnetically induced transparency scheme are discussed. We measured the E-field generated by an open-ended waveguide using this technique. Experimental results are compared to a full-wave finite element simulation.

  12. A rubidium Mx-magnetometer for measurements on solid state spins

    NASA Astrophysics Data System (ADS)

    Arnold, Daniel; Siegel, Steven; Grisanti, Emily; Wrachtrup, Jörg; Gerhardt, Ilja

    2017-02-01

    The detection of environmental magnetic fields is well established by optically pumped atomic magnetometers. Another focus of magnetometry can be the research on magnetic or spin-active solid-state samples. Here we introduce a simple and compact design of a rubidium-based Mx magnetometer, which allows for hosting solid-state samples. The optical, mechanical, and electrical design is reported, as well as simple measurements which introduce the ground-state spin-relaxation time, the signal-to-noise ratio of a measurement, and subsequently the overall sensitivity of the magnetometer. The magnetometer is optimized for the most sensitive operation with respect to laser power and magnetic field excitation at the Larmor frequency.

  13. Photoionization from the 5p {sup 2}P{sub 3/2} state of rubidium

    SciTech Connect

    Nadeem, Ali; Haq, S. U.

    2011-06-15

    We report two-step photoionization studies from the 5p {sup 2}P{sub 3/2} excited state of rubidium using two dye lasers simultaneously pumped by a common Nd:YAG laser in conjunction with a thermionic diode ion detector. The photoionization cross section at the first ionization threshold is measured as 18.8 {+-} 3 Mb and at excess energies of 0.013, 0.106, 0.229, and 0.329 eV is measured as 15, 13.6, 12.6, and 12.5 Mb, respectively. The measured value of the photoionization cross section at the threshold is used to calibrate the oscillator strengths of the 5p {sup 2}P{sub 3/2}{yields}nd {sup 2}D{sub 5/2} (22 {<=}n{<=} 52) Rydberg transitions.

  14. Elimination of the light shift in rubidium gas cell frequency standards using pulsed optical pumping

    NASA Technical Reports Server (NTRS)

    English, T. C.; Jechart, E.; Kwon, T. M.

    1978-01-01

    Changes in the intensity of the light source in an optically pumped, rubidium, gas cell frequency standard can produce corresponding frequency shifts, with possible adverse effects on the long-term frequency stability. A pulsed optical pumping apparatus was constructed with the intent of investigating the frequency stability in the absence of light shifts. Contrary to original expectations, a small residual frequency shift due to changes in light intensity was experimentally observed. Evidence is given which indicates that this is not a true light-shift effect. Preliminary measurements of the frequency stability of this apparatus, with this small residual pseudo light shift present, are presented. It is shown that this pseudo light shift can be eliminated by using a more homogeneous C-field. This is consistent with the idea that the pseudo light shift is due to inhomogeneity in the physics package (position-shift effect).

  15. Polarization squeezing at the audio frequency band for the Rubidium D_1 line

    NASA Astrophysics Data System (ADS)

    Wen, Xin; Han, Yashuai; Liu, Jinyu; He, Jun; Wang, Junmin

    2017-08-01

    A 2.8-dB polarization squeezing of the Stokes operator S2 for the rubidium D1 line (795 nm) is achieved, with the lowest squeezing band at an audio frequency of 2.6 kHz. Two methods are applied for improving the squeezing towards low frequencies: an orthogonal-polarized locking beam that precludes residual unwanted interference and quantum noise locking method that stabilizes the relative phase between the squeezed vacuum and the local oscillator. The squeezing level is limited by absorption-induced losses at short wavelengths, here is 397.5 nm. The generated polarization squeezed light can be used in a quantum enhanced magnetometer to increase the measurement sensitivity.

  16. The use of rubidium as a surrogate for potassium in combustion system imaging

    NASA Astrophysics Data System (ADS)

    Lengel, Russell K.; Linder, Jeffrey S.

    1990-06-01

    Laser-induced fluorescence (LIF) studies on rubidium (Rb) were initiated to determine if Rb would serve as a useful surrogate for potassium atoms in MHD combustion gas stream imaging. Supporting evidence for the use of Rb was observed in emission spectra from oil and coal-fired facilities and through knowledge of the elemental composition of coal. LIF images were obtained for an Rb-seeded laboratory burner with and without the presence of added K. The ability to obtain Rb images in the presence of K indicates that Rb is more suitable for MHD channel diagnostics than K, and that Rb is not effected by factors such as the large thermal emission and self-reversals observed from potassium.

  17. Ultralow-light-level all-optical transistor in rubidium vapor

    SciTech Connect

    Jing, Jietai Zhou, Zhifan; Liu, Cunjin; Qin, Zhongzhong; Fang, Yami; Zhou, Jun; Zhang, Weiping

    2014-04-14

    An all-optical transistor (AOT) is a device in which one light beam can efficiently manipulate another. It is the foundational component of an all-optical communication network. An AOT that can operate at ultralow light levels is especially attractive for its potential application in the quantum information field. Here, we demonstrate an AOT driven by a weak light beam with an energy density of 2.5 × 10{sup −5} photons/(λ{sup 2}/2π) (corresponding to 6  yJ/(λ{sup 2}/2π) and about 800 total photons) using the double-Λ four-wave mixing process in hot rubidium vapor. This makes it a promising candidate for ultralow-light-level optical communication and quantum information science.

  18. Pump-probe spectroscopy of cold rubidium atoms in an integrating sphere

    NASA Astrophysics Data System (ADS)

    Wang, Wen-Li; Dong, Ri-Chang; Deng, Jian-Liao; Wang, Yu-Zhu

    2016-05-01

    Absorption spectra of cold rubidium atoms in an integrating sphere under the influence of a diffuse laser field have been systematically investigated. A pronounced dispersionlike structure centered at the light-shifted pump frequency is observed with a subnatural linewidth. In particular, two clearly resolved absorption resonances on the 5 S1 /2(F =2 ) →5 P3 /2(F'=3 ) transitions occur with variable probe beam intensity, which is consistent with our proposed theoretical model. Based on the two absorption resonances,we measure the dependence of light shifts, from which we can directly extract the effective Rabi frequency in a diffuse laser field, on the probe laser intensity, pump laser intensity, and pump laser detuning. Our work helps to identify the physical mechanisms behind these spectral features and is beneficial for studying the corresponding effect in a cold sample.

  19. The blue light indicator in rubidium 5S-5P-5D cascade excitation

    NASA Astrophysics Data System (ADS)

    Raja, Waseem; Ali, Md. Sabir; Chakrabarti, Alok; Ray, Ayan

    2017-07-01

    The cascade system has played an important role in contemporary research areas related to fields like Rydberg excitation, four wave mixing and non-classical light generation, etc. Depending on the specific objective, co or counter propagating pump-probe laser experimental geometry is followed. However, the stepwise excitation of atoms to states higher than the first excited state deals with increasingly much fewer number of atoms even compared to the population at first excited level. Hence, one needs a practical indicator to study the complex photon-atom interaction of the cascade system. Here, we experimentally analyze the case of rubidium 5S → 5P → 5D as a specimen of two-step excitation and highlight the efficacy of monitoring one branch, which emits 420 nm, of associated cascade decay route 5D → 6P → 5S, as an effective monitor of the coherence in the system.

  20. 2011 investigation of internal contamination with radioactive strontium following rubidium Rb 82 cardiac PET scan.

    PubMed

    Pillai, Satish K; Chang, Arthur; Murphy, Matthew W; Buzzell, Jennifer; Ansari, Armin; Whitcomb, Robert C; Miller, Charles; Jones, Robert; Saunders, David P; Cavicchia, Philip; Watkins, Sharon M; Blackmore, Carina; Williamson, John A; Stephens, Michael; Morrison, Melissa; McNees, James; Murphree, Rendi; Buchanan, Martha; Hogan, Anthony; Lando, James; Nambiar, Atmaram; Torso, Lauren; Melnic, Joseph M; Yang, Lucie; Lewis, Lauren

    2014-01-01

    During routine screening in 2011, US Customs and Border Protection (CBP) identified 2 persons with elevated radioactivity. CBP, in collaboration with Los Alamos National Laboratory, informed the Food and Drug Administration (FDA) that these people could have increased radiation exposure as a result of undergoing cardiac Positron Emission Tomography (PET) scans several months earlier with rubidium Rb 82 chloride injection from CardioGen-82. We conducted a multistate investigation to assess the potential extent and magnitude of radioactive strontium overexposure among patients who had undergone Rb 82 PET scans. We selected a convenience sample of clinical sites in 4 states and reviewed records to identify eligible study participants, defined as people who had had an Rb 82 PET scan between February and July 2011. All participants received direct radiation screening using a radioisotope identifier able to detect the gamma energy specific for strontium-85 (514 keV) and urine bioassay for excreted radioactive strontium. We referred a subset of participants with direct radiation screening counts above background readings for whole body counting (WBC) using a rank ordering of direct radiation screening. The rank order list, from highest to lowest, was used to contact and offer voluntary enrollment for WBC. Of 308 participants, 292 (95%) had direct radiation screening results indistinguishable from background radiation measurements; 261 of 265 (98%) participants with sufficient urine for analysis had radioactive strontium results below minimum detectable activity. None of the 23 participants who underwent WBC demonstrated elevated strontium activity above levels associated with routine use of the rubidium Rb 82 generator. Among investigation participants, we did not identify evidence of strontium internal contamination above permissible levels. This investigation might serve as a model for future investigations of radioactive internal contamination incidents.

  1. The KLM + KLN Auger electron spectrum of rubidium in different matrices

    NASA Astrophysics Data System (ADS)

    Inoyatov, A. Kh; Kovalík, A.; Perevoshchikov, L. L.; Filosofov, D. V.; Vénos, D.; Lee, B. Q.; Ekman, J.; Baimukhanova, A.

    2017-08-01

    The KLM + KLN Auger electron spectrum of rubidium (Z = 37) emitted in the electron capture decay of radioactive 83Sr in a polycrystalline platinum matrix and also 85Sr in polycrystalline platinum and carbon matrices as well as in an evaporated layer onto a carbon backing were experimentally studied in detail for the first time using a combined electrostatic electron spectrometer. Energies, relative intensities, and natural widths of fifteen basic spectrum components were determined and compared with both theoretical predictions and experimental data for krypton (Z = 36). Relative spectrum line energies obtained from the semi-empirical calculations in intermediate coupling scheme were found to agree within 3σ with the measured values while disagreement with experiment exceeding 3σ was often observed for values obtained from our multiconfiguration Dirac-Hartree-Fock calculations. The absolute energy of the dominant spectrum component given by the semi-empirical approach agrees within 1σ with the measured value. Shifts of +(0.2 ± 0.2) and -(1.9 ± 0.2) eV were measured for the dominant KLM spectrum components between the 85Sr sources prepared by vacuum evaporation on and implanted into the carbon foil, respectively, relative to 85Sr implanted into the platinum foil. A value of (713 ± 2) eV was determined for the energy difference of the dominant components of the KLM + KLN Auger electron spectra of rubidium and krypton generated in the polycrystalline platinum matrix. From the detailed analysis of the measured data and available theoretical results, the general conclusion can be drawn that the proper description of the KLM + KLN Auger electron spectrum for Z around 37 should still be based on the intermediate coupling of angular momenta taking into account relativistic effects.

  2. Development of an HTS assay for Na+, K+-ATPase using nonradioactive rubidium ion uptake.

    PubMed

    Gill, Sikander; Gill, Rajwant; Wicks, David; Despotovski, Sasko; Liang, Dong

    2004-10-01

    A high-throughput screening (HTS) assay was developed for the Na(+),K(+)-ATPase channel in order to study rubidium uptake as a measure of the functional activity and modulation of this exchanger. The assay uses elemental rubidium as a tracer for K(+) ions. Three cell lines were used to study the exchanger, and the assay was performed in a 96-well microtiter plate format. Rb(+) uptake was carried by the CHO-K1 cells at 37 degrees C; the maximum ion influx was at 80 min of incubation of the cell line in the medium containing 5.4 mM RbCl. The cells were incubated in Rb(+) uptake buffer (5.4 mM) and with the pump blocker ouabain for 1, 2, and 3 h, respectively. A complete block of the Rb(+) uptake was observed with a 5 mM concentration of ouabain for all the three time intervals. The ouabain 50% inhibitory concentration (IC(50)) value for CHO-K1 cell line ATPase was observed to be 298 microM after 3 h of incubation. In addition, IC(50) values of 94 and 89 microM were observed at 30 min of incubation, indicating that the protocol shows reproducible results. A Z' factor higher than 0.7 was observed in the assays. These studies extend the profile of Na(+),K(+)-ATPases and demonstrate the feasibility of this HTS assay system to screen for compounds that pharmacologically modulate the function of Na(+),K(+)-ATPase.

  3. Story of Rubidium-82 and Advantages for Myocardial Perfusion PET Imaging.

    PubMed

    Chatal, Jean-François; Rouzet, François; Haddad, Ferid; Bourdeau, Cécile; Mathieu, Cédric; Le Guludec, Dominique

    2015-01-01

    Rubidium-82 has a long story, starting in 1954. After preclinical studies in dogs showing that myocardial uptake of this radionuclide was directly proportional to myocardial blood flow (MBF), clinical studies were performed in the 80s leading to an approval in the USA in 1989. From that time, thousands of patients have been tested and their results have been reported in three meta-analyses. Pooled patient-based sensitivity and specificity were, respectively, 0.91 and 0.90. By comparison with (99m)Tc-SPECT, (82)Rb PET had a much better diagnostic accuracy, especially in obese patients with body mass index ≥30 kg/m(2) (85 versus 67% with SPECT) and in women with large breasts. A great advantage of (82)Rb PET is its capacity to accurately quantify MBF. Quite importantly, it has been recently shown that coronary flow reserve is associated with adverse cardiovascular events independently of luminal angiographic severity. Moreover, coronary flow reserve is a functional parameter particularly useful in the estimate of microvascular dysfunction, such as in diabetes mellitus. Due to the very short half-life of rubidium-82, the effective dose calculated for a rest/stress test is roughly equivalent to the annual natural exposure and even less when stress-only is performed with a low activity compatible with a good image quality with the last generation 3D PET scanners. There is still some debate on the relative advantages of (82)Rb PET with regard to (99m)Tc-SPECT. For the last 10 years, great technological advances substantially improved performances of SPECT with its accuracy getting closer to this of (82)Rb/PET. Currently, the main advantages of PET are its capacity to accurately quantify MBF and to deliver a low radiation exposure.

  4. Elevated level of nitric oxide mediates the anti-depressant effect of rubidium chloride in mice.

    PubMed

    Kordjazy, Nastaran; Haj-Mirzaian, Arya; Amiri, Shayan; Ostadhadi, Sattar; Kordjazy, Mehdi; Sharifzadeh, Mohammad; Dehpour, Ahmad Reza

    2015-09-05

    Rubidium has been used to treat psychiatric conditions including depression. We examined the antidepressant activity of rubidium chloride (RbCl) in male mice and the possible interference of nitric oxide (NO) in this effect. Mouse forced swimming test (FST) and tail suspension test (TST) were used to evaluate the antidepressant-like effect of RbCl. These drugs were used in this study: N(G)-l-arginine methyl ester (l-NAME), a non-selective nitric oxide synthase (NOS) inhibitor, 7-Nitroindazole and aminoguanidine, selective neuronal and inducible NOS inhibitors, respectively, and l-arginine, an NO precursor. We studied the changes of serum and hippocampus nitrite level after different treatments. RbCl (30mg/kg), when administered 60min before the tests, significantly reduced the immobility time. Non-effective doses of l-NAME (10mg/kg) and aminoguanidine (50mg/kg), co-administered with the effective dose of RbCl (30mg/kg), reversed the anti-immobility effect of RbCl, while 7-NI (25mg/kg) could not prevent the diminishing effect of RbCl on immobility time. Moreover, co-administration of non-effective doses of l-arginine (750mg/kg) and RbCl (10mg/kg) decreased the immobility time. None of the mentioned treatments altered the locomotor activity of mice in open-field test. Nitrite level was significantly increased in serum and hippocampus of animals after RbCl (30mg/kg) administration and this nitrite level elevation was reversed by non-effective dose of l-NAME and aminoguanidine, but not 7-NI. Our data for the first time reveal the role of NO pathway in the antidepressant-like activity of RbCl, concluding that this effect results from elevation of NO through involvement of iNOS in mice. Copyright © 2015 Elsevier B.V. All rights reserved.

  5. Crystal Chemistry of the Potassium and Rubidium Uranyl Borate Families Derived from Boric Acid Fluxes

    SciTech Connect

    Wang, Shuao; Alekseev, Evgeny V.; Stritzinger, Jared T.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E.

    2010-07-19

    The reaction of uranyl nitrate with a large excess of molten boric acid in the presence of potassium or rubidium nitrate results in the formation of three new potassium uranyl borates, K{sub 2}[(UO{sub 2}){sub 2}B{sub 12}O{sub 19}(OH){sub 4}]·0.3H{sub 2}O (KUBO-1), K[(UO{sub 2}){sub 2}B{sub 10}O{sub 15}(OH){sub 5}] (KUBO-2), and K[(UO{sub 2}){sub 2}B{sub 10}O{sub 16}(OH){sub 3}]·0.7H{sub 2}O (KUBO-3) and two new rubidium uranyl borates Rb{sub 2}[(UO{sub 2}){sub 2}B{sub 13}O{sub 20}(OH){sub 5}] (RbUBO-1) and Rb[(UO{sub 2}){sub 2}B{sub 10}O{sub 16}(OH){sub 3}]·0.7H{sub 2}O (RbUBO-2). The latter is isotypic with KUBO-3. These compounds share a common structural motif consisting of a linear uranyl, UO{sub 2}{sup 2+}, cation surrounded by BO{sub 3} triangles and BO{sub 4} tetrahedra to create an UO{sub 8} hexagonal bipyramidal environment around uranium. The borate anions bridge between uranyl units to create sheets. Additional BO{sub 3} triangles extend from the polyborate layers and are directed approximately perpendicular to the sheets. All of these compounds adopt layered structures. With the exception of KUBO-1, the structures are all centrosymmetric. All of these compounds fluoresce when irradiated with long-wavelength UV light. The fluorescence spectrum yields well-defined vibronically coupled charge-transfer features.

  6. The impact of prompt gamma compensation on myocardial blood flow measurements with rubidium-82 dynamic PET.

    PubMed

    Armstrong, Ian S; Memmott, Matthew J; Tonge, Christine M; Arumugam, Parthiban

    2016-09-13

    Rubidium-82 myocardial perfusion imaging is a well-established technique for assessing myocardial ischemia. With continuing interest on myocardial blood flow (MBF) and myocardial flow reserve (MFR) measurements, there is a requirement to fully appreciate the impact of technical aspects of the process. One such factor for rubidium-82 is prompt gamma compensation (PGC). This study aims to assess the impact of PGC on MBF and MFR calculated from dynamic Rb-82 data. Dynamic rest and stress images were acquired on a Siemens Biograph mCT and reconstructed with and without PGC in 50 patients (29 male). MBF and MFR were measured in the three main coronary territories as well as globally. With PGC, statistically significant reductions in MBF were observed in LAD (-6.9%), LCx (-4.8%), and globally (-6.5%) but only in obese patients. Significant increases in MBF were observed in RCA (+6.4%) in only nonobese patients. In very obese patients, differences of up to 40% in MBF were observed between PGC and non-PGC images. In nearly all cases, similar PGC differences were observed at stress and rest so there were no significant differences in MFR; however, in a small number of very obese patients, differences in excess of 20% were observed. PGC results in statistically significant changes in MBF, with the greatest reductions observed in the LAD and LCx territories of obese patients. In most cases, the impact on stress and rest data is of similar relative magnitudes and changes to MFR are small.

  7. Story of Rubidium-82 and Advantages for Myocardial Perfusion PET Imaging

    PubMed Central

    Chatal, Jean-François; Rouzet, François; Haddad, Ferid; Bourdeau, Cécile; Mathieu, Cédric; Le Guludec, Dominique

    2015-01-01

    Rubidium-82 has a long story, starting in 1954. After preclinical studies in dogs showing that myocardial uptake of this radionuclide was directly proportional to myocardial blood flow (MBF), clinical studies were performed in the 80s leading to an approval in the USA in 1989. From that time, thousands of patients have been tested and their results have been reported in three meta-analyses. Pooled patient-based sensitivity and specificity were, respectively, 0.91 and 0.90. By comparison with 99mTc-SPECT, 82Rb PET had a much better diagnostic accuracy, especially in obese patients with body mass index ≥30 kg/m2 (85 versus 67% with SPECT) and in women with large breasts. A great advantage of 82Rb PET is its capacity to accurately quantify MBF. Quite importantly, it has been recently shown that coronary flow reserve is associated with adverse cardiovascular events independently of luminal angiographic severity. Moreover, coronary flow reserve is a functional parameter particularly useful in the estimate of microvascular dysfunction, such as in diabetes mellitus. Due to the very short half-life of rubidium-82, the effective dose calculated for a rest/stress test is roughly equivalent to the annual natural exposure and even less when stress-only is performed with a low activity compatible with a good image quality with the last generation 3D PET scanners. There is still some debate on the relative advantages of 82Rb PET with regard to 99mTc-SPECT. For the last 10 years, great technological advances substantially improved performances of SPECT with its accuracy getting closer to this of 82Rb/PET. Currently, the main advantages of PET are its capacity to accurately quantify MBF and to deliver a low radiation exposure. PMID:26442267

  8. Optical frequency standard by using a 1560 nm diode laser locked to saturated absorption lines of rubidium vapor

    SciTech Connect

    Masuda, Shin; Seki, Atsushi; Niki, Shoji

    2007-07-20

    A robust, compact, highly accurate rubidium optical frequency standard module was developed to overcome the delicate performance of conventional frequency stabilized lasers. A frequency doubled1560 nm distributed feedback diode laser locked to a rubidium D2 saturated absorption line without using an optical amplifier was demonstrated, and dithering-free optical output was obtained. In addition, the sensitivity of the developed optical frequency standard to magnetic fields was investigated. We confirmed that the influence of the magnetic fields on the optical frequency standard can be almost negligible when using appropriate magnetic-shield films. As a result, the magnetic-field-insensitive optical frequency standard, which can be embedded in optical systems,exhibiting uncertainty less than at least 100 kHz, was successfully realized for the first time to the best of our knowledge.

  9. Effects of water concentration in the coating solution on the wall relaxation rate of octadecyltrichlorosilane coated rubidium vapor cells

    SciTech Connect

    Zhang, Guiying; Wei, Lihua; Wang, Meiling; Zhao, Kaifeng

    2015-01-28

    High quality anti-relaxation surface coatings for atomic vapor cells are essential for the preservation of atomic spin coherence and the enhancement of measurement sensitivity. In this paper, we studied the effects of water concentration in octadecyltrichlorosilane (OTS) coating solution on the relaxation rate and its reproducibility of OTS coated Rubidium vapor cells. We found that appropriate water concentration can improve the anti-relaxation performance of OTS coated cells.

  10. Rubidium-87/strontium-87 age of juvinas basaltic achondrite and early igneous activity in the solar system.

    PubMed

    Allégre, C J; Birck, J L; Fourcade, S; Semet, M P

    1975-02-07

    A (4.60+/-0.07)x10(9) year internal isochron has been drawn for the achondrite Juvinas by the rubidium-87/strontium-87 method. Earlier petrographic investigation of achondrites supplemented by a new ion microprobe study of Juvinas strongly suggest an igneous origin for this class of meteorites. The results thus indicate that igneous activity may have rapidly followed the formation of the achondrites' parent body 4.6x10(9) years ago.

  11. Activity of rubidium and cesium in soybean looper (Lepidoptera: Noctuidae): insect feeding on cotton and soybean measured by elemental markers.

    PubMed

    Jost, Douglas J; Pitre, Henry N

    2002-04-01

    Uptake and translocation of the elemental markers rubidium (Rb) and cesium (Cs) within adult soybean looper, Pseudoplusia includens (Walker), were determined using atomic absorption spectrophotometry in the laboratory in various feeding and mating treatments. Neonates were tested to determine marker transfer from male and female adults fed rubidium chloride (RbCl)-treated artificial nectar, cesium chloride (CsCI)-treated artificial nectar, or both. All females contained detectable levels of Rb, Cs, or both, which were obtained either through direct feeding or via spermatophores. Rubidium was present in females at significantly greater levels than Cs. No significant differences in Rb levels were observed between feeding or spermatophore acquisitions. Most neonates had significantly higher levels of Rb than Cs. In a field cage study to evaluate adult feeding and oviposition behavior on blooming cotton and blooming soybean treated with RbCl and CsCl, respectively, more eggs contained Rb than Cs, indicating greater feeding on cotton nectar than soybean nectar, regardless of the host plant upon which eggs were laid. Females laid more eggs on blooming soybean than on blooming cotton. Higher levels of Rb in cotton than Cs in soybean were recorded and may be attributed to initial elemental marker quantities available to the insects. This study provides the support for the generalized observations that soybean looper infestations in soybean can be related to feeding activities by adults in cotton.

  12. Photoassociation and coherent transient dynamics in the interaction of ultracold rubidium atoms with shaped femtosecond pulses. I. Experiment

    SciTech Connect

    Mullins, Terry; Salzmann, Wenzel; Goetz, Simone; Albert, Magnus; Eng, Judith; Wester, Roland; Weidemueller, Matthias; Weise, Fabian; Merli, Andrea; Weber, Stefan M.; Sauer, Franziska; Woeste, Ludger; Lindinger, Albrecht

    2009-12-15

    We experimentally investigate various processes present in the photoassociative interaction of an ultracold atomic sample with shaped femtosecond laser pulses as an detailed extension of previous work [W. Salzmann et al., Phys. Rev. Lett. 100, 233003 (2008)]. We demonstrate the photoassociation of pairs of rubidium atoms into electronically excited, bound molecular states using spectrally cut femtosecond laser pulses tuned below the rubidium D{sub 1} or D{sub 2} asymptote. Time-resolved pump-probe spectra reveal oscillations of the molecular formation rate, which are due to coherent transient dynamics in the electronic excitation. The oscillation frequency corresponds to the detuning of the spectral cut position to the asymptotic transition frequency of the rubidium D{sub 1} or D{sub 2} lines, respectively. Measurements of the molecular photoassociation signal as a function of the pulse energy reveal a nonlinear dependence and indicate a nonperturbative excitation process. Chirping the association laser pulse allowed us to change the phase of the coherent transients. Furthermore, a signature for molecules in the electronic ground state is found, which is attributed to molecule formation by femtosecond photoassociation followed by spontaneous decay. In a subsequent article [A. Merli et al., Phys. Rev. A 80, 063417 (2009)] quantum mechanical calculations are presented, which compare well with the experimental data and reveal further details about the observed coherent transient dynamics.

  13. catena-Poly[[diaqua-rubidium(I)](μ(2)-3-carboxy-pyrazine-2-carboxyl-ato)(μ(2)-pyrazine-2,3-dicarboxylic acid)].

    PubMed

    Tombul, Mustafa; Guven, Kutalmis

    2009-01-23

    The structural unit of the title compound, [Rb(C(6)H(3)N(2)O(4))(C(6)H(4)N(2)O(4))(H(2)O)(2)](n), consists of one rubidium cation, one hydrogen pyrazine-2,3-dicarboxyl-ate anion, one pyrazine-2,3-dicarboxylic acid mol-ecule and two water mol-ecules. This formulation is repeated twice in the asymmetric unit as the rubidium cation lies on an inversion centre. Each anion or acid mol-ecule is linked to two rubidium cations, while the rubidium cation has close contacts to four symmetry-equivalent organic ligands, with two different coordination modes towards this cation. In addition, each rubidium cation is coordinated by two water O atoms, raising the coordination number to eight. One of the carboxyl groups of the acid holds its H atom, which forms a hydrogen bond to a coordinated water mol-ecule. The other carboxyl group is deprotonated in half of the ligands and protonated in the other half, taking part in a strong O-H⋯O hydrogen bond disordered over an inversion centre. The stabil-ization of the crystal structure is further assisted by O-H⋯O and O-H⋯N hydrogen-bonding inter-actions involving the water mol-ecules and carboxyl-ate O atoms.

  14. catena-Poly[[diaqua­rubidium(I)](μ2-3-carboxy­pyrazine-2-carboxyl­ato)(μ2-pyrazine-2,3-dicarboxylic acid)

    PubMed Central

    Tombul, Mustafa; Guven, Kutalmis

    2009-01-01

    The structural unit of the title compound, [Rb(C6H3N2O4)(C6H4N2O4)(H2O)2]n, consists of one rubidium cation, one hydrogen pyrazine-2,3-dicarboxyl­ate anion, one pyrazine-2,3-dicarboxylic acid mol­ecule and two water mol­ecules. This formulation is repeated twice in the asymmetric unit as the rubidium cation lies on an inversion centre. Each anion or acid mol­ecule is linked to two rubidium cations, while the rubidium cation has close contacts to four symmetry-equivalent organic ligands, with two different coordination modes towards this cation. In addition, each rubidium cation is coordinated by two water O atoms, raising the coordination number to eight. One of the carboxyl groups of the acid holds its H atom, which forms a hydrogen bond to a coordinated water mol­ecule. The other carboxyl group is deprotonated in half of the ligands and protonated in the other half, taking part in a strong O—H⋯O hydrogen bond disordered over an inversion centre. The stabil­ization of the crystal structure is further assisted by O—H⋯O and O—H⋯N hydrogen-bonding inter­actions involving the water mol­ecules and carboxyl­ate O atoms. PMID:21581808

  15. A dual-isotope rubidium magnetometer for probing anomalous spin-dependent interactions of the proton

    NASA Astrophysics Data System (ADS)

    Lacey, Ian; Jacome, L. R.; Chan, Lok Fai; Peregrina, Rodrigo; Delcheva, Delyana; Kimball, Derek

    2010-03-01

    We report progress in our development of a dual-isotope rubidium magnetometer to be used to search for anomalous spin-dependent interactions of the proton, in particular a long-range coupling between proton spins and the mass of the Earth. The valence electron dominates magnetic interactions and serves as a precise co-magnetometer for the nuclei in a simultaneous measurement of Rb-85 and Rb-87 spin precession frequencies, enabling accurate subtraction of magnetic perturbations. Both Rb nuclei have valence protons, but in Rb-87 the proton spin is parallel to the nuclear spin and magnetic moment while for Rb-85 the proton spin is anti-parallel to the nuclear spin and magnetic moment. Thus anomalous interactions of the proton spin produce a differential shift between the Rb spin-precession frequencies, whereas many sources of systematic error produce common-mode shifts of the spin-precession frequencies which can be controlled through auxiliary measurements. The majority of recent searches for similar effects limit anomalous couplings of either the neutron or electron spin, so the proposed experiments search a parameter space to some degree, depending on the theoretical model, orthogonal to that constrained by previous experiments.

  16. Search for an anomalous spin-mass coupling with a dual isotope rubidium comagnetometer

    NASA Astrophysics Data System (ADS)

    Rios, Cesar; Valdez, Julian; Swiatlowski, Jerlyn; Kremer, Jackie; Kimball, Derek

    2012-11-01

    We discuss progress in our search for a hypothetical long-range coupling between rubidium (Rb) nuclear spins and the mass of the Earth. The experiment employs a dual-isotope Rb comagnetometer: the valence electron dominates magnetic interactions and serves as a precise magnetic field monitor for the nuclei in a simultaneous measurement of Rb-85 and Rb-87 spin precession frequencies, enabling accurate subtraction of magnetic perturbations. The nuclear structure of Rb makes the experiment particularly sensitive to non-magnetic, spin-dependent interactions of the proton. The majority of recent searches for similar effects limit anomalous couplings of either the neutron or electron spin, so the proposed experiment searches a parameter space to some degree, depending on the theoretical model, orthogonal to that constrained by previous experiments. We have begun to collect data and carry out in-depth analysis of systematic effects. The optimized dual-isotope Rb magnetometer has the sensitivity to improve experimental limits on long-range spin-mass couplings by an order of magnitude in general and by three orders of magnitude for the proton spin in particular.

  17. Miniature atomic scalar magnetometer for space based on the rubidium isotope (87)Rb.

    PubMed

    Korth, Haje; Strohbehn, Kim; Tejada, Francisco; Andreou, Andreas G; Kitching, John; Knappe, Svenja; Lehtonen, S John; London, Shaughn M; Kafel, Matiwos

    2016-08-01

    A miniature atomic scalar magnetometer based on the rubidium isotope (87)Rb was developed for operation in space. The instrument design implements both Mx and Mz mode operation and leverages a novel microelectromechanical system (MEMS) fabricated vapor cell and a custom silicon-on-sapphire (SOS) complementary metal-oxide-semiconductor (CMOS) integrated circuit. The vapor cell has a volume of only 1 mm(3) so that it can be efficiently heated to its operating temperature by a specially designed, low-magnetic-field-generating resistive heater implemented in multiple metal layers of the transparent sapphire substrate of the SOS-CMOS chips. The SOS-CMOS chip also hosts the Helmholtz coil and associated circuitry to stimulate the magnetically sensitive atomic resonance and temperature sensors. The prototype instrument has a total mass of fewer than 500 g and uses less than 1 W of power, while maintaining a sensitivity of 15 pT/√Hz at 1 Hz, comparable to present state-of-the-art absolute magnetometers.

  18. Phase Coexistence in the Mixed Crystal RUBIDIUM(1-X) Ammonium(x) Dihydrogen Arsenate

    NASA Astrophysics Data System (ADS)

    Pinto, Nicholas Joaquim

    1992-01-01

    A study of the coexistence phenomenon in mixed crystals of rubidium ammonium dihydrogen arsenate has been done. Coexistence in this study refers to the simultaneous presence of ferroelectric and proton glass phases as temperature is lowered below the ferroelectric phase transition temperature T_{c}. Such coexistence is found to exist in these mixed crystals only for small ammonium concentrations. Our results show that coexistence exists for lower ammonium concentration than previously suggested. A study was also done on crystals with larger ammonium concentrations that show pure proton glass behavior and the results compared with the coexistence phenomenon. Dielectric, spontaneous polarization and nuclear magnetic resonance experiments on mixed crystals with small ammonium concentrations show that at low temperatures there exists intimate coexistence of ferroelectric clusters with proton glass clusters below the glass transition temperature T_{g}. In the proton glass phase, we observe a spread of relaxation times due to the creation and annihilation of HAsO_4 and H_3AsO_4 pairs as they diffuse through the crystal. Spin lattice relaxation times for the acid deuterons in a 10% ammoniated sample show a broad T_1 minimum near the glass transition temperature which is characteristic of proton glasses. Field-cooling experiments were also done on the pure proton glass. The results are consistent with dielectric measurements, but the remanent polarization was found to be extremely small. This polarization was found to depend on the rate of heating and cooling the sample while performing the experiment.

  19. Solid-state ensemble of highly entangled photon sources at rubidium atomic transitions

    PubMed Central

    Keil, Robert; Zopf, Michael; Chen, Yan; Höfer, Bianca; Zhang, Jiaxiang; Ding, Fei; Schmidt, Oliver G.

    2017-01-01

    Semiconductor InAs/GaAs quantum dots grown by the Stranski–Krastanov method are among the leading candidates for the deterministic generation of polarization-entangled photon pairs. Despite remarkable progress in the past 20 years, many challenges still remain for this material, such as the extremely low yield, the low degree of entanglement and the large wavelength distribution. Here, we show that with an emerging family of GaAs/AlGaAs quantum dots grown by droplet etching and nanohole infilling, it is possible to obtain a large ensemble of polarization-entangled photon emitters on a wafer without any post-growth tuning. Under pulsed resonant two-photon excitation, all measured quantum dots emit single pairs of entangled photons with ultra-high purity, high degree of entanglement and ultra-narrow wavelength distribution at rubidium transitions. Therefore, this material system is an attractive candidate for the realization of a solid-state quantum repeater—among many other key enabling quantum photonic elements. PMID:28548092

  20. Quantitative myocardial blood flow with Rubidium-82 PET: a clinical perspective

    PubMed Central

    Hagemann, Christoffer E; Ghotbi, Adam A; Kjær, Andreas; Hasbak, Philip

    2015-01-01

    Positron emission tomography (PET) allows assessment of myocardial blood flow in absolute terms (ml/min/g). Quantification of myocardial blood flow (MBF) and myocardial flow reserve (MFR) extend the scope of conventional semi-quantitative myocardial perfusion imaging (MPI): e.g. in 1) identification of the extent of a multivessel coronary artery disease (CAD) burden, 2) patients with balanced 3-vessel CAD, 3) patients with subclinical CAD, and 4) patients with regional flow variance, despite of a high global MFR. A more accurate assessment of the ischemic burden in patients with intermediate pretest probability of CAD can support the clinical decision-making in treatment of CAD patients as a complementary tool to the invasive coronary angiography (CAG). Recently, several studies have proven Rubidium-82 (82Rb) PET’s long-term prognostic value by a significant association between compromised global MFR and major adverse cardiovascular events (MACE), and together with new diagnostic possibilities from measuring the longitudinal myocardial perfusion gradient, cardiac 82Rb PET faces a promising clinical future. This article reviews current evidence on quantitative 82Rb PET’s ability to diagnose and risk stratify CAD patients, while assessing the potential of the modality in clinical practice. PMID:26550537

  1. Robust surface doping of Bi2Se3 by rubidium intercalation.

    PubMed

    Bianchi, Marco; Hatch, Richard C; Li, Zheshen; Hofmann, Philip; Song, Fei; Mi, Jianli; Iversen, Bo B; El-Fattah, Zakaria M Abd; Löptien, Peter; Zhou, Lihui; Khajetoorians, Alexander A; Wiebe, Jens; Wiesendanger, Roland; Wells, Justin W

    2012-08-28

    Rubidium adsorption on the surface of the topological insulator Bi(2)Se(3) is found to induce a strong downward band bending, leading to the appearance of a quantum-confined two-dimensional electron gas state (2DEG) in the conduction band. The 2DEG shows a strong Rashba-type spin-orbit splitting, and it has previously been pointed out that this has relevance to nanoscale spintronics devices. The adsorption of Rb atoms, on the other hand, renders the surface very reactive, and exposure to oxygen leads to a rapid degrading of the 2DEG. We show that intercalating the Rb atoms, presumably into the van der Waals gaps in the quintuple layer structure of Bi(2)Se(3), drastically reduces the surface reactivity while not affecting the promising electronic structure. The intercalation process is observed above room temperature and accelerated with increasing initial Rb coverage, an effect that is ascribed to the Coulomb interaction between the charged Rb ions. Coulomb repulsion is also thought to be responsible for a uniform distribution of Rb on the surface.

  2. Extracardiac abnormalities on rubidium-82 cardiac positron emission tomography/computed tomography.

    PubMed

    Mirpour, Sahar; Khandani, Amir H

    2011-04-01

    The role of rubidium-82 (Rb) in recognizing extracardiac diseases is minimally investigated. The aim of this study was to evaluate the frequency and incremental added value of extracardiac findings on Rb cardiac positron emission tomography/computed tomography (PET/CT) studies. The study included all consecutive patients who were referred from July 2008 to June 2010 for Rb cardiac PET/CT to our institution. A blinded reader reviewed the images retrospectively to assess abnormal extracardiac PET findings. Images of 406 patients (142 men; 264 women) with a mean age±standard deviation of 59.72±12.93 years (range: 18-91 years) were reviewed. Incidental extracardiac abnormalities were found in 67 of 406 patients (16.5%). Among them, eight patients had malignant etiologies (1.9%). Incidental extracardiac findings were present in a significant portion of patients undergoing Rb cardiac PET/CT studies. Although most of the extracardiac findings on Rb cardiac PET/CT studies represented clinically known pathologies, these incidental findings on routine Rb cardiac PET/CT scans may have a significant clinical impact on a small number of patients, and offer the referring physician the chance to obtain additional clinically relevant information.

  3. A High-Throughput Screening Assay for NKCC1 Cotransporter Using Nonradioactive Rubidium Flux Technology.

    PubMed

    Gill, Sikander; Gill, Rajwant; Wen, Yang; Enderle, Thilo; Roth, Doris; Liang, Dong

    A high-throughput screening (HTS) assay was developed for cotransporter, NKCC1, which is a potential target for the treatment of diverse disorders. This nonradioactive rubidium flux assay coupled with ion channel reader series provides a working screen for this target expressed in human embryonic kidney (HEK) cell line. An eightfold window of detection was achieved with the optimized assay. This new functional assay offered a robust working model for NKCC1 in determining reliable and concordant rank orders of the test compounds supporting its sensitivity and specificity. The robustness of manual assay indicated by Z' of 0.9 qualified its amenability to automation. The Z' of 0.7 was displayed by automated assay employed in high-throughput screening of compound libraries against this target. Being electrically neutral, the NKCC1 screening is difficult to achieve by both manual and automated electrophysiological techniques. These techniques, although considered gold standard, suffer from their inherent problems of being too slow to be in high-throughput format and with high running costs. In addition to being a functional assay for NKCC1, it is nontoxic as compared with thallium flux assay, which is prone to generate high number of false-positive/false-negative rates because of its innate fluorescence issues.

  4. Capillary electrophoretic and computational study of the complexation of valinomycin with rubidium cation.

    PubMed

    Ehala, Sille; Dybal, Jirí; Makrlík, Emanuel; Kasicka, Václav

    2009-03-01

    This study is focused on the characterization of interactions of valinomycin (Val), a macrocyclic dodecadepsipeptide antibiotic ionophore, with rubidium cation, Rb(+). Capillary affinity electrophoresis was employed for the experimental evaluation of the strength of the Val-Rb(+) complex. The study involved the measurement of the change of effective electrophoretic mobility of Val at increasing concentration of Rb(+) cation in the BGE. From the dependence of Val effective electrophoretic mobility on the Rb(+) cation concentration in the BGE (methanolic solution of 100 mM Tris, 50 mM acetic acid, 0-1 mM RbCl), the apparent binding (stability) constant (K(b)) of the Val-Rb(+) complex in methanol was evaluated as log K(b)=4.63+/-0.27. According to the quantum mechanical density functional theory calculations employed to predict the most probable structure of Val-Rb(+) complex, Val is stabilized by strong non-covalent bond interactions of Rb(+) with six ester carbonyl oxygen atoms so that the position of the "central" Rb(+) cation in the Val cage is symmetric.

  5. Rubidium ions and the gating of delayed rectifier potassium channels of frog skeletal muscle.

    PubMed Central

    Spruce, A E; Standen, N B; Stanfield, P R

    1989-01-01

    1. Unitary currents were measured through delayed rectifier potassium channels of frog skeletal muscle, under conditions where either potassium or rubidium ions carried current. 2. Unitary currents were reduced in amplitude when Rb+ was the charge carrier, indicating that Rb+ permeated the channel less readily than did K+. On the other hand permeability ratios (PRb/PK) measured from the change in reversal potential upon ionic substitution were 0.92 for the external and 0.67 for the internal mouth of the channel. 3. Ensemble-averaged currents activated under depolarization along a similarly S-shaped time course whether K+ or Rb+ carried current, though slightly more slowly in Rb+. However, under repolarization to a negative level, tail currents were prolonged about tenfold in Rb+. 4. The duration of channel opening was substantially prolonged in Rb+. The distribution of open times was fitted by a single exponential whether K+ or Rb+ was the charge carrier, indicating a single open state. But the mean open time, averaged over all voltages investigated, was 2.65 times greater in Rb+. 5. The prolongation in Rb+ of tail currents under repolarization was associated with increases in the number of openings per burst and in the number of bursts during each tail. 6. The implications of these results for channel gating are discussed. It is argued that an early step in channel activation is more voltage dependent than later steps. PMID:2614736

  6. In-field labeling of western corn rootworm adults (Coleoptera: Chrysomelidae) with rubidium.

    PubMed

    Nowatzki, Timothy M; Niimi, Bradly; Warren, Kelli J; Putnam, Sean; Meinke, Lance J; Gosselin, David C; Harvey, F Edwin; Hunt, Thomas E; Siegfried, Blair D

    2003-12-01

    Field and laboratory studies were conducted in 2000 and 2001 to determine the feasibility of mass marking western corn rootworm adults, Diabrotica virgifera virgifera LeConte, with RbCl in the field. Results showed that application of rubidium (Rb) in solution to both the soil (1 g Rb/plant) and whorl (1 g Rb/plant) of corn plants was optimal for labeling western corn rootworm adults during larval development. Development of larvae on Rb-enriched corn with this technique did not significantly influence adult dry weight or survival. Rb was also highly mobile in the plant. Application of Rb to both the soil and the whorl resulted in median Rb concentrations in the roots (5,860 ppm) that were 150-fold greater than concentrations in untreated roots (38 ppm) 5 wk after treatment. Additionally, at least 90% of the beetles that emerged during the first 3 wk were labeled above the baseline Rb concentration (5 ppm dry weight) determined from untreated beetles. Because emergence was 72% complete at this time, a significant proportion of the population had been labeled. Results from laboratory experiments showed that labeled beetles remained distinguishable from unlabeled beetles for up to 4 d postemergence. The ability to efficiently label large numbers of beetles under field conditions and for a defined period with virtually no disruption of the population provides an unparalleled opportunity to conduct mark-recapture experiments for quantifying the short-range, intrafield movement of adult corn rootworms.

  7. Narrow-band N-resonance formed in thin rubidium atomic layers

    SciTech Connect

    Sargsyan, A.; Mirzoyan, R.; Sarkisyan, D.

    2012-11-15

    The narrow-band N-resonance formed in a {Lambda} system of D{sub 1}-line rubidium atoms is studied in the presence of a buffer gas (neon) and the radiations of two continuous narrow-band diode lasers. Special-purpose cells are used to investigate the dependence of the process on vapor column thickness L in millimeter, micrometer, and nanometer ranges. A comparison of the dependences of the N-resonance and the electromagnetically induced transparency (EIT) resonance on L demonstrates that the minimum (record) thickness at which the N-resonance can be detected is L = 50 {mu}m and that a high-contrast EIT resonance can easily be formed even at L Almost-Equal-To 800 nm. The N-resonance in a magnetic field for {sup 85}Rb atoms is shown to split into five or six components depending on the magnetic field and laser radiation directions. The results obtained indicate that levels F{sub g} = 2, 3 are initial and final in the N-resonance formation. The dependence of the N-resonance on the angle between the laser beams is analyzed, and practical applications are noted.

  8. In situ Raman probing of graphene over a broad doping range upon rubidium vapor exposure.

    PubMed

    Parret, Romain; Paillet, Matthieu; Huntzinger, Jean-Roch; Nakabayashi, Denise; Michel, Thierry; Tiberj, Antoine; Sauvajol, Jean-Louis; Zahab, Ahmed A

    2013-01-22

    We report in situ Raman scattering experiments on single-layer graphene (SLG) and Bernal bilayer graphene (BLG) during exposure to rubidium vapor. The G- and 2D-band evolutions with doping time are presented and analyzed. On SLG, the extended doping range scanned (up to about 10(14) electrons/cm(2)) allows the observation of three regimes in the evolution of the G-band frequency: a continuous upshift followed by a plateau and a downshift. Overall the measured evolution is interpreted as the signature of the competition between dynamic and adiabatic effects upon n-doping. Comparison of the obtained results with theoretical predictions indicates however that a substrate pinning effect occurs and inhibits charge-induced lattice expansion of SLG. At low doping, a direct link between electrostatic gating and Rb doping results is presented. For BLG, the added electrons are shown to be first confined in the top layer, but the system evolves with time toward a more symmetric repartition of the added electrons in both layers. The results obtained on BLG also confirm that the slope of the phonon dispersion close to the K point tends to be slightly reduced at low doping but suggest the occurrence of an unexpected increase of the phonon dispersion slope at higher electron concentration.

  9. Rubidium marking of Anopheles mosquitoes detectable by field-capable X-ray spectrometry.

    PubMed

    Wilkins, E E; Smith, S C; Roberts, J M; Benedict, M

    2007-06-01

    We present a mosquito marking technique suitable for mark-release-recapture that can be used with a hand-held, portable X-ray fluorescence (XRF) spectrometer, which is practical for field measurements. Third instar Anopheles gambiae Giles sensu stricto (Diptera: Culicidae) and Anopheles stephensi Liston larvae were cultured to pupation in water containing rubidium (Rb) Cl at concentrations up to 1000 p.p.m. Rb. Anopheles gambiae larvae survived to adulthood at concentrations as high as 1000 p.p.m. Rb but suffered pupal mortality and reduced adult longevity at high concentrations. We were able to culture An. stephensi at Rb concentrations as high as 300 p.p.m. The presence of Rb in adults was evaluated using a portable XRF analyser, and we were able to reliably detect Rb above background levels in 10-day-old females and 4-day-old males at concentrations causing minimal pupal or adult mortality. We observed that Rb marking was not permanent, and the concentration declined significantly as adults aged. The low cost of labelling with RbCl and the field portability of the spectrometer provide a useful means for labelling mosquitoes via breeding sites or in the laboratory for mark-release-recapture experiments.

  10. Quantification of rubidium as a trace element in beef using laser induced breakdown spectroscopy.

    PubMed

    Dixit, Y; Casado-Gavalda, Maria P; Cama-Moncunill, R; Markiewicz-Keszycka, Maria; Cama-Moncunill, X; Cullen, P J; Sullivan, Carl

    2017-08-01

    This study evaluates the potential of laser induced breakdown spectroscopy (LIBS) coupled with chemometrics to develop a quantification model for rubidium (Rb) in minced beef. A LIBSCAN 150 system was used to collect LIBS spectra of minced beef samples. Beef liver was used to spike the Rb levels in minced beef. All samples were dried, powdered and pelleted using a hydraulic press. Measurements were conducted by scanning 100 different locations with an automated XYZ sample chamber. Partial least squares regression (PLSR) was used to develop the calibration model, yielding a calibration coefficient of determination (Rc(2)) of 0.99 and a root mean square error of calibration (RMSEC) of 0.05ppm. The model also showed good results with leave-one-out cross validation, yielding a cross-validation coefficient of determination (Rcv(2)) of 0.90 and a root mean square error of cross-validation (RMSECV) of 0.22ppm. The current study shows the potential of LIBS as a rapid analysis tool for the meat processing industry. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. A waveguide frequency converter connecting rubidium-based quantum memories to the telecom C-band

    NASA Astrophysics Data System (ADS)

    Albrecht, Boris; Farrera, Pau; Fernandez-Gonzalvo, Xavier; Cristiani, Matteo; de Riedmatten, Hugues

    2014-02-01

    Coherently converting the frequency and temporal waveform of single and entangled photons will be crucial to interconnect the various elements of future quantum information networks. Of particular importance is the quantum frequency conversion of photons emitted by material systems able to store quantum information, so-called quantum memories. There have been significant efforts to implement quantum frequency conversion using nonlinear crystals, with non-classical light from broadband photon-pair sources and solid-state emitters. However, solid state quantum frequency conversion has not yet been achieved with long-lived optical quantum memories. Here we demonstrate an ultra-low-noise solid state photonic quantum interface suitable for connecting quantum memories based on atomic ensembles to the telecommunication fibre network. The interface is based on an integrated-waveguide nonlinear device. We convert heralded single photons at 780 nm from a rubidium-based quantum memory to the telecommunication wavelength of 1,552 nm, showing significant non-classical correlations between the converted photon and the heralding signal.

  12. Two-Photon Absorption Spectroscopy of Rubidium with a Dual-Comb Tequnique

    NASA Astrophysics Data System (ADS)

    Nishiyama, Akiko; Yoshida, Satoru; Hariki, Takuya; Nakajima, Yoshiaki; Minoshima, Kaoru

    2017-06-01

    Dual-comb spectroscopies have great potential for high-resolution molecular and atomic spectroscopies, thanks to the broadband comb spectrum consisting of dense narrow modes. In this study, we apply the dual-comb system to Doppler-free two-photon absorption spectroscopy. The outputs of two frequency combs excite several two-photon transitions of rubidium, and we obtained broadband Doppler-free spectra from dual-comb fluorescence signals. The fluorescence detection scheme circumvents the sensitivity limit which is effectively determined by the dynamic range of photodetectors in absorption-based dual-comb spectroscopies. Our system realized high-sensitive, Doppler-free high-resolution and broadband atomic spectroscopy. A part of observed spectra of 5S_{1/2} - 5D_{5/2} transition is shown in the figure. The hyperfine structures of the F" = 1 - F' = 3,2,1 transitions are fully-resolved and the spectral widths are approximately 5 MHz. The absolute frequency axis is precisely calibrated from comb mode frequencies which were stabilized to a GPS-disciplined clock. This work was supported by JST through the ERATO MINOSHIMA Intelligent Optical Synthesizer Project and Grant-in-Aid for JSPS Fellows (16J02345). A. Nishiyama, S. Yoshida, Y. Nakajima, H. Sasada, K. Nakagawa, A. Onae, K. and Minoshima, Opt. Express 24, 25894 (2016). A. Hipke, S. A. Meek, T. Ideguchi, T.W. Hänsch, and N. Picqué, Phys. Rev. A 90, 011805(R) (2014).

  13. Solid-state ensemble of highly entangled photon sources at rubidium atomic transitions

    NASA Astrophysics Data System (ADS)

    Keil, Robert; Zopf, Michael; Chen, Yan; Höfer, Bianca; Zhang, Jiaxiang; Ding, Fei; Schmidt, Oliver G.

    2017-05-01

    Semiconductor InAs/GaAs quantum dots grown by the Stranski-Krastanov method are among the leading candidates for the deterministic generation of polarization-entangled photon pairs. Despite remarkable progress in the past 20 years, many challenges still remain for this material, such as the extremely low yield, the low degree of entanglement and the large wavelength distribution. Here, we show that with an emerging family of GaAs/AlGaAs quantum dots grown by droplet etching and nanohole infilling, it is possible to obtain a large ensemble of polarization-entangled photon emitters on a wafer without any post-growth tuning. Under pulsed resonant two-photon excitation, all measured quantum dots emit single pairs of entangled photons with ultra-high purity, high degree of entanglement and ultra-narrow wavelength distribution at rubidium transitions. Therefore, this material system is an attractive candidate for the realization of a solid-state quantum repeater--among many other key enabling quantum photonic elements.

  14. Temperature dependence of de Gennes narrowing and transport properties of liquid rubidium: Experimental and simulation results

    NASA Astrophysics Data System (ADS)

    Bertolini, D.; Demmel, F.; Tani, A.

    2007-09-01

    Recent neutron scattering results [F. Demmel , Phys. Rev. B 73, 104207 (2006)] on the temperature dependence of de Gennes narrowing in liquid rubidium have stimulated a molecular dynamics (MD) study in the same temperature and density range. At the k value of the first peak of S(k) , the MD results agree very well with experimental data of Stilde (kmax,ω=0) , F(kmax,t=0) , and longitudinal viscosity ηL(kmax,ω=0) . Other transport properties, such as self-diffusion and shear viscosity, are also accurately reproduced. At k=0 , on the other hand, the MD results significantly underestimate the experimental values of bulk viscosity and thermal conductivity. For the latter, this is a well known deficiency of models which do not explicitly take into account the electronic contribution to thermal exchanges. However, the large difference between MD and macroscopic experimental data for bulk viscosity casts some doubts on its indirect calculation from sound absorption data. This contradictory result, which presumably extends to all alkali metals, is discussed in the light of various theoretical models.

  15. Test-Retest Repeatability of Myocardial Blood Flow Measurements using Rubidium-82 Positron Emission Tomography

    NASA Astrophysics Data System (ADS)

    Efseaff, Matthew

    Rubidium-82 positron emission tomography (PET) imaging has been proposed for routine myocardial blood flow (MBF) quantification. Few studies have investigated the test-retest repeatability of this method. Same-day repeatability of rest MBF imaging was optimized with a highly automated analysis program using image-derived input functions and a dual spillover correction (SOC). The effects of heterogeneous tracer infusion profiles and subject hemodynamics on test-retest repeatability were investigated at rest and during hyperemic stress. Factors affecting rest MBF repeatability included gender, suspected coronary artery disease, and dual SOC (p < 0.001). The best repeatability coefficient for same-day rest MBF was 0.20 mL/min/g using a six-minute scan-time, iterative reconstruction, dual SOC, resting rate-pressure-product (RPP) adjustment, and a left atrium image-derived input function. The serial study repeatabilities of the optimized protocol in subjects with homogeneous RPPs and tracer infusion profiles was 0.19 and 0.53 mL/min/g at rest and stress, and 0.95 for stress / rest myocardial flow reserve (MFR). Subjects with heterogeneous tracer infusion profiles and hemodynamic conditions had significantly less repeatable MBF measurements at rest, stress, and stress/rest flow reserve (p < 0.05).

  16. Electronically excited rubidium atom in helium clusters and films. II. Second excited state and absorption spectrum.

    PubMed

    Leino, Markku; Viel, Alexandra; Zillich, Robert E

    2011-01-14

    Following our work on the study of helium droplets and film doped with one electronically excited rubidium atom Rb(∗) ((2)P) [M. Leino, A. Viel, and R. E. Zillich, J. Chem. Phys. 129, 184308 (2008)], we focus in this paper on the second excited state. We present theoretical studies of such droplets and films using quantum Monte Carlo approaches. Diffusion and path integral Monte Carlo algorithms combined with a diatomics-in-molecule scheme to model the nonpair additive potential energy surface are used to investigate the energetics and the structure of Rb(∗)He(n) clusters. Helium films as a model for the limit of large clusters are also considered. As in our work on the first electronic excited state, our present calculations find stable Rb(∗)He(n) clusters. The structures obtained are however different with a He-Rb(∗)-He exciplex core to which more helium atoms are weakly attached, preferentially on one end of the core exciplex. The electronic absorption spectrum is also presented for increasing cluster sizes as well as for the film.

  17. Design and test of the microwave cavity in an optically-pumped Rubidium beam frequency standard

    NASA Astrophysics Data System (ADS)

    Liu, Chang; Wang, Yan-Hui

    2015-01-01

    We are developing a compact rubidium atomic beam frequency standard with optical pumping and detection. The cavity for microwave interrogation is an important part of the clock. The cavity in our design is a Ramsey-type, E-bend one, which is the same as the conventional method in most cesium beam clocks. Requirements for the design are proposed based on the frequency shift associated with the cavity. The basic structure of the cavity is given by theoretical analysis and detailed dimensions are determined by means of electromagnetic field simulation with the help of commercial software. The cavity is manufactured and fabricated successfully. The preliminary test result of the cavity is given, which is in good agreement with the simulation. The resonant frequency is 6.835 GHz, equal to the clock transition frequency of 87Rb, and the loaded quality factor is 500. These values are adjustable with posts outside the cavity. Estimations on the Ramsey line width and several frequency shifts are made. Project supported by the National Natural Science Foundation of China (Grant No. 11174015).

  18. Short-pulse photoassociation in rubidium below the D{sub 1} line

    SciTech Connect

    Koch, Christiane P.; Kosloff, Ronnie; Masnou-Seeuws, Francoise

    2006-04-15

    Photoassociation of two ultracold rubidium atoms and the subsequent formation of stable molecules in the singlet ground and lowest triplet states is investigated theoretically. The method employs laser pulses inducing transitions via excited states correlated to the 5S+5P{sub 1/2} asymptote. Weakly bound molecules in the singlet ground or lowest triplet state can be created by a single pulse while the formation of more deeply bound molecules requires a two-color pump-dump scenario. More deeply bound molecules in the singlet ground or lowest triplet state can be produced only if efficient mechanisms for both pump and dump steps exist. While long-range 1/R{sup 3} potentials allow for efficient photoassociation, stabilization is facilitated by the resonant spin-orbit coupling of the 0{sub u}{sup +} states. Molecules in the singlet ground state bound by a few wave numbers can thus be formed. This provides a promising first step toward ground-state molecules which are ultracold in both translational and vibrational degrees of freedom.

  19. Miniature atomic scalar magnetometer for space based on the rubidium isotope 87Rb

    NASA Astrophysics Data System (ADS)

    Korth, Haje; Strohbehn, Kim; Tejada, Francisco; Andreou, Andreas G.; Kitching, John; Knappe, Svenja; Lehtonen, S. John; London, Shaughn M.; Kafel, Matiwos

    2016-08-01

    A miniature atomic scalar magnetometer based on the rubidium isotope 87Rb was developed for operation in space. The instrument design implements both Mx and Mz mode operation and leverages a novel microelectromechanical system (MEMS) fabricated vapor cell and a custom silicon-on-sapphire (SOS) complementary metal-oxide-semiconductor (CMOS) integrated circuit. The vapor cell has a volume of only 1 mm3 so that it can be efficiently heated to its operating temperature by a specially designed, low-magnetic-field-generating resistive heater implemented in multiple metal layers of the transparent sapphire substrate of the SOS-CMOS chips. The SOS-CMOS chip also hosts the Helmholtz coil and associated circuitry to stimulate the magnetically sensitive atomic resonance and temperature sensors. The prototype instrument has a total mass of fewer than 500 g and uses less than 1 W of power, while maintaining a sensitivity of 15 pT/√Hz at 1 Hz, comparable to present state-of-the-art absolute magnetometers.

  20. A waveguide frequency converter connecting rubidium-based quantum memories to the telecom C-band.

    PubMed

    Albrecht, Boris; Farrera, Pau; Fernandez-Gonzalvo, Xavier; Cristiani, Matteo; de Riedmatten, Hugues

    2014-02-27

    Coherently converting the frequency and temporal waveform of single and entangled photons will be crucial to interconnect the various elements of future quantum information networks. Of particular importance is the quantum frequency conversion of photons emitted by material systems able to store quantum information, so-called quantum memories. There have been significant efforts to implement quantum frequency conversion using nonlinear crystals, with non-classical light from broadband photon-pair sources and solid-state emitters. However, solid state quantum frequency conversion has not yet been achieved with long-lived optical quantum memories. Here we demonstrate an ultra-low-noise solid state photonic quantum interface suitable for connecting quantum memories based on atomic ensembles to the telecommunication fibre network. The interface is based on an integrated-waveguide nonlinear device. We convert heralded single photons at 780 nm from a rubidium-based quantum memory to the telecommunication wavelength of 1,552 nm, showing significant non-classical correlations between the converted photon and the heralding signal.

  1. Investigation of cold rubidium Rydberg atoms in a magneto-optical trap

    SciTech Connect

    Tretyakov, D. B.; Beterov, I. I.; Entin, V. M.; Ryabtsev, I. I. Chapovsky, P. L.

    2009-03-15

    This paper reports on the results of experiments with cold rubidium Rydberg atoms in a magneto-optical trap. The specific feature of the experiments is the excitation of Rydberg atoms in a small volume within a cloud of cold atoms and the sorting of measured signals and spectra according to the number of detected Rydberg atoms. The effective lifetime of the 37P Rydberg state and its polarizability in a weak electric field are measured. The results obtained are in good agreement with theoretical calculations. It is demonstrated that the localization of the excitation volume in the vicinity of the zero-magnetic-field point makes it possible to improve the spectral resolution and to obtain narrow microwave resonances in Rydberg atoms without switching off the quadrupole magnetic field of the trap. The dependence of the amplitude of dipole-dipole interaction resonances in Rydberg atoms on the number of atoms is measured. This dependence exhibits a linear behavior and agrees with the theory for a weak dipole-dipole interaction.

  2. Quantum optical devices based on four-wave mixing in hot rubidium vapor

    NASA Astrophysics Data System (ADS)

    Fang, YaMi; Qin, ZhongZhong; Wang, HaiLong; Cao, LeiMing; Xin, Jun; Feng, JingLiang; Zhang, WeiPing; Jing, JieTai

    2015-06-01

    In this paper, we briefly review the recent experimental progresses in quantum optics based on four-wave mixing (FWM) processes in hot rubidium vapor, particularly our two recent experiments in quantum information. We have experimentally produced strong quantum correlations between three bright beams generated by two cascaded FWM processes. The intensity difference squeezing with the cascaded system is enhanced to (-7.0±0.1)dB from the (-5.5±0.1)dB/(-4.5±0.1)dB with only one FWM process. Also, this system can be easily extended to multiple modes using multiple FWM processes. Besides, we have also successfully realized a cascade all-optical transistor (AOT), which is driven by a very weak light beam about 800 photons in total. The required probe power for achieving a switching efficiency of 50% can be as low as 180 pW, and it can manipulate a light beam with power of 5.0×106 times more, which proves the cascade of the AOT. Both experiments may find wide applications in quantum information and optical communication.

  3. Experimental Generation of Multiple Quantum Correlated Beams from Hot Rubidium Vapor

    NASA Astrophysics Data System (ADS)

    Qin, Zhongzhong; Cao, Leiming; Wang, Hailong; Marino, A. M.; Zhang, Weiping; Jing, Jietai

    2014-07-01

    Quantum correlations and entanglement shared among multiple quantum modes are important for both fundamental science and the future development of quantum technologies. This development will also require an efficient quantum interface between multimode quantum light sources and atomic ensembles, which makes it necessary to implement multimode quantum light sources that match the atomic transitions. Here, we report on such a source that provides a method for generating quantum correlated beams that can be extended to a large number of modes by using multiple four-wave mixing (FWM) processes in hot rubidium vapor. Experimentally, we show that two cascaded FWM processes produce strong quantum correlations between three bright beams but not between any two of them. In addition, the intensity-difference squeezing is enhanced with the cascaded system to -7.0±0.1 dB from the -5.5±0.1/-4.5±0.1 dB squeezing obtained with only one FWM process. One of the main advantages of our system is that as the number of quantum modes increases, so does the total degree of quantum correlations. The proposed method is also immune to phase instabilities due to its phase insensitive nature, can easily be extended to multiple modes, and has potential applications in the production of multiple quantum correlated images.

  4. Does the light shift drive frequency aging in the rubidium atomic clock?

    PubMed

    Camparo, James

    2005-07-01

    Frequency aging in the rubidium (Rb) vapor-cell atomic clock plays a significant role in the device's timekeeping ability. Though many researchers have speculated on the physical mechanism(s) driving the linear, deterministic frequency change (i.e., deltaf(t)/fo = At), there is little unambiguous experimental data regarding the phenomenon. Here, long-term data were used from on-orbit global positioning system (GPS) Rb clocks to examine one postulated mechanism for frequency aging (i.e., the light-shift effect). Defining the light shift of the clock's fractional frequency as alphaI/Io, where alpha is the light-shift coefficient, we find that temporal variations of the relative light intensity, I/Io, cannot account for frequency aging. However, for the population of clocks considered here, we obtain the intriguing result that alpha/A = 1.7 +/- 1.5. Thus, it may be that frequency aging is driven by the light-shift effect through temporal variations of the light-shift coefficient.

  5. Measurements of myocardial flow vs. extraction of rubidium under varying physiological conditions

    SciTech Connect

    Budinger, T.F.; Yano, Y.; Moyer, B.R.; Twitchell, J.A.; Brennan, K.M.; Huesman, R.H.

    1984-01-01

    The relationship between myocardial rubidium extraction (E) and flow (F) are well described by the single capillary model E = (1-exp(-PS/F)) with a permeability surface product PS = 0.87 cc/min/gm. Some effects of alkalosis and acidosis have been reported. Here the authors investigate the effects of dipyridamole, norepinephrine-atropine, exsanguination, pacing, ouabain and calcium on extraction using Rb-82 PET and Rb-86 acute studies with microspheres in dogs. Thoracotomies were performed for left atrial microsphere infusion. Anesthesia was by N/sub 2/O and methoxyflurane. The degree of exsanguination, drug levels administered and pacing rates were sufficient to produce flow modifications. Extraction was calculated by dividing FE from Rb observations by F from microsphere data. These results of extraction vs. flow do not show a significant dependence on the method used for flow modification. There was less than a 20% change in FE after an infusion of 0.04 mg/kg ouabain over 5 minutes in 3 replicate studies each on 4 dogs. An important finding not previously explained in flow vs. extraction studies is the occurrence of extraction values greater than 1.0 which is possible only if the distribution opportunities of small cations are greater than that of microspheres. This is equivalent to the well known hematocrit effect in small channels.

  6. Positronium Formation Cross-Sections for Positron Scattering by Rubidium Atoms

    NASA Astrophysics Data System (ADS)

    El-Bakry, Salah Yaseen

    Cross-sections for positron-rubidium (37Rb) scattering have been calculated using the Clementi-Roetti wavefunctions and a combination of the coupled-static and frozen-core approximations. The total cross-sections, calculated with eight partial waves corresponding to the total angular momentum ℓ=0 to ℓ=7, are determined over a wide region of scattering energies ranging from 2.7 to 300 eV. The resulting total cross-sections are compared with experimental results and those calculated by other authors. Our total collisional cross-sections display a pronounced peak at 5 eV, nearly consistent with the measurements of Parikh et al. [Phys. Rev. A 47, 1535 (1993)] and also reveal another peak at 7 eV, consistent with the experimental cross-section of Stein et al.23 in the neighborhood of 7 eV. The oscillating behavior of our total collisional cross-sections supports the possible existence of resonance, especially at low energy region. The effect of positronium formation on the total collisional cross-sections diminishes when the incident energy is larger than 100 eV.

  7. Performance of the new Efratom optically pumped rubidium frequency standards and their possible application in space relativity experiments

    NASA Technical Reports Server (NTRS)

    Alley, C. O.; Williams, R.; Singh, G.; Mullendore, J.

    1972-01-01

    The characteristics of Efratom optically pumped rubidium frequency standards are discussed. The Efratom units were compared with cesium beam and hydrogen maser standards and showed a stability of approximately 5 times 10 to the minus 12th power over two one-week periods. Dependency of frequency upon the environmental parameters of pressure, magnetic field, temperature, supply voltage, and acceleration was measured. A package of three units with automatic phase comparison and recording was designed and constructed to allow a measurement of relativistic effects on time with high accuracy during space missions.

  8. Realization of low frequency and controllable-bandwidth squeezing based on a four-wave-mixing amplifer in rubidium vapor

    SciTech Connect

    Liu, Cunjin; Jing, Jietai; Zhou, Zhifan; Pooser, Raphael C; Hudelist, Florian; Zhang, Weiping

    2011-01-01

    We experimentally demonstrate the creation of two correlated beams generated by a nondegenerate four-wave-mixing amplifier at {lambda} = 795 nm in hot rubidium vapor. We achieve intensity difference squeezing at frequencies as low as 1.5 kHz which is so far the lowest frequency to observe squeezing in an atomic system. The squeezing spans from 5.5 to 16.5 MHz with a maximum squeezing of {approx}5 dB at 1 MHz. We can control the squeezing bandwidth by changing the pump power. Both low frequency and controllable bandwidth squeezing show great potential in sensitivity detection and precise control of the atom optics measurement.

  9. Analysis of the X-ray emission spectra of copper, germanium and rubidium plasmas produced at the Phelix laser facility

    NASA Astrophysics Data System (ADS)

    Comet, M.; Pain, J.-C.; Gilleron, F.; Piron, R.; Denis-Petit, D.; Méot, V.; Gosselin, G.; Morel, P.; Hannachi, F.; Gobet, F.; Tarisien, M.; Versteegen, M.

    2017-03-01

    We present the analysis of X-ray emission spectra of copper, germanium and rubidium plasmas measured at the Phelix laser facility. The laser intensity was around 6×1014 W.cm-2. The analysis is based on the hypothesis of an homogeneous plasma in local thermodynamic equilibrium using an effective temperature. This temperature is deduced from hydrodynamic simulations and collisional-radiative computations. Spectra are then calculated using the LTE opacity codes OPAMCDF and SCO-RCG and compared to experimental data.

  10. Characteristic oscillations in the coherent transients of ultracold rubidium molecules using red and blue detuned pulses for photoassociation

    NASA Astrophysics Data System (ADS)

    Weise, Fabian; Merli, Andrea; Eimer, Frauke; Birkner, Sascha; Sauer, Franziska; Wöste, Ludger; Lindinger, Albrecht; Salzmann, Wenzel; Mullins, Terence G.; Wester, Roland; Weidemüller, Matthias; Ağanoğlu, Ruzin; Koch, Christiane P.

    2009-11-01

    We investigate the interaction of femtosecond laser pulses with an ensemble of ultracold rubidium atoms by applying shaped excitation pulses with two different types of spectral filtering. Although the pulses, which are frequency filtered with a high pass, have no spectral overlap with molecular states, we observe coherent molecular transients. Similar transients obtained with nearly transform-limited pulses, where only the atomic resonance is removed, reveal two differing oscillatory components. The resulting transients are compared among themselves and supported with quantum dynamical simulations which indicate a photoassociation process. The effect is due to the strong field interaction of the pulse with the colliding atom pair.

  11. Clinical interpretation standards and quality assurance for the multicenter PET/CT trial rubidium-ARMI.

    PubMed

    Renaud, Jennifer M; Mylonas, Ilias; McArdle, Brian; Dowsley, Taylor; Yip, Kathy; Turcotte, Eric; Guimond, Jean; Trottier, Mikael; Pibarot, Philipe; Maguire, Conor; Lalonde, Lucille; Gulenchyn, Karen; Wisenberg, Gerald; Wells, R Glenn; Ruddy, Terrence; Chow, Benjamin; Beanlands, Rob S B; deKemp, Robert A

    2014-01-01

    Rubidium-ARMI ((82)Rb as an Alternative Radiopharmaceutical for Myocardial Imaging) is a multicenter trial to evaluate the accuracy, outcomes, and cost-effectiveness of low-dose (82)Rb perfusion imaging using 3-dimensional (3D) PET/CT technology. Standardized imaging protocols are essential to ensure consistent interpretation. Cardiac phantom qualifying scans were obtained at 7 recruiting centers. Low-dose (10 MBq/kg) rest and pharmacologic stress (82)Rb PET scans were obtained in 25 patients at each site. Summed stress scores, summed rest scores, and summed difference scores (SSS, SRS, and SDS [respectively] = SSS-SRS) were evaluated using 17-segment visual interpretation with a discretized color map. All scans were coread at the core lab (University of Ottawa Heart Institute) to assess agreement of scoring, clinical diagnosis, and image quality. Scoring differences greater than 3 underwent a third review to improve consensus. Scoring agreement was evaluated with intraclass correlation coefficient (ICC-r), concordance of clinical interpretation, and image quality using κ coefficient and percentage agreement. Patient (99m)Tc and (201)Tl SPECT scans (n = 25) from 2 centers were analyzed similarly for comparison to (82)Rb. Qualifying scores of SSS = 2, SDS = 2, were achieved uniformly at all imaging sites on 9 different 3D PET/CT scanners. Patient scores showed good agreement between core and recruiting sites: ICC-r = 0.92, 0.77 for SSS, SDS. Eighty-five and eighty-seven percent of SSS and SDS scores, respectively, had site-core differences of 3 or less. After consensus review, scoring agreement improved to ICC-r = 0.97, 0.96 for SSS, SDS (P < 0.05). The agreement of normal versus abnormal (SSS ≥ 4) and nonischemic versus ischemic (SDS ≥ 2) studies was excellent: ICC-r = 0.90 and 0.88. Overall interpretation showed excellent agreement, with a κ = 0.94. Image quality was perceived differently by the site versus core reviewers (90% vs. 76% good or better; P < 0

  12. Ultracold Mixtures of Rubidium and Ytterbium for Open Quantum System Engineering

    NASA Astrophysics Data System (ADS)

    Herold, Creston David

    Exquisite experimental control of quantum systems has led to sharp growth of basic quantum research in recent years. Controlling dissipation has been crucial in producing ultracold, trapped atomic samples. Recent theoretical work has suggested dissipation can be a useful tool for quantum state preparation. Controlling not only how a system interacts with a reservoir, but the ability to engineer the reservoir itself would be a powerful platform for open quantum system research. Toward this end, we have constructed an apparatus to study ultracold mixtures of rubidium (Rb) and ytterbium (Yb). We have developed a Rb-blind optical lattice at 423.018(7) nm, which will enable us to immerse a lattice of Yb atoms (the system) into a Rb BEC (superfluid reservoir). We have produced Bose-Einstein condensates of 170Yb and 174Yb, two of the five bosonic isotopes of Yb, which also has two fermionic isotopes. Flexible optical trapping of Rb and Yb was achieved with a two-color dipole trap of 532 and 1064 nm, and we observed thermalization in ultracold mixtures of Rb and Yb. Using the Rb-blind optical lattice, we measured very small light shifts of 87Rb BECs near the light shift zero-wavelengths adjacent the 6p electronic states, through a coherent series of lattice pulses. The positions of the zero-wavelengths are sensitive to the electric dipole matrix elements between the 5s and 6p states, and we made the first experimental measurement of their strength. By measuring a light shift, we were not sensitive to excited state branching ratios, and we achieved a precision better than 0.3%.

  13. Initial human experience with Rubidium-82 renal PET/CT imaging.

    PubMed

    Tahari, Abdel K; Bravo, Paco E; Rahmim, Arman; Bengel, Frank M; Szabo, Zsolt

    2014-02-01

    Preclinical data have shown that Rubidium-82 chloride ((82)Rb) is a radiotracer with high first pass extraction and slow washout in the kidneys. The goal of this study was to investigate the feasibility of human kidney imaging with (82)Rb positron emission tomography (PET) and obtain quantitative data of its uptake non-invasively. Eight healthy volunteers underwent dynamic PET/CT imaging with (82)Rb. A preprogrammed pump was used to insure reproducible injections. Tissue time activity curves were generated from the renal cortex. An input function was derived from the left ventricular blood pool (LVBP), the descending thoracic aorta and the abdominal aorta. Renal blood flow was estimated by applying a two-compartment kinetic model. Results obtained with different input functions were compared. Radiotracer accumulation was rapid and reached a plateau within 15-30 s after the bolus entered the kidneys. The derived K1 and k2 parameters were reproducible using input functions obtained from diverse vascular locations. K1 averaged 1.98 ± 0.14 mL/min/g. The average k2 was 0.35 ± 0.11/min. Correlation between K1 values obtained from the LVBP from different bed positions when the kidneys and abdominal aorta were in the same field of view was excellent (R = 0.95). Non-invasive quantitative human kidney imaging with (82)Rb PET is feasible. Advantages of renal PET with (82)Rb include excellent image quality with high image resolution and contrast. (82)Rb has potential as a clinical renal imaging agent in humans. © 2013 The Royal Australian and New Zealand College of Radiologists.

  14. Rubidium-82 PET imaging is feasible in a rat myocardial infarction model.

    PubMed

    Ghotbi, Adam Ali; Clemmensen, Andreas; Kyhl, Kasper; Follin, Bjarke; Hasbak, Philip; Engstrøm, Thomas; Ripa, Rasmus Sejersten; Kjaer, Andreas

    2017-07-18

    Small-animal myocardial infarct models are frequently used in the assessment of new cardioprotective strategies. A validated quantification of perfusion using a non-cyclotron-dependent PET tracer would be of importance in monitoring response to therapy. We tested whether myocardial PET perfusion imaging is feasible with Rubidium-82 ((82)Rb) in a small-animal scanner using a rat myocardial infarct model. 18 Sprague-Dawley rats underwent permanent coronary artery ligation (infarct group), and 11 rats underwent ischemia-reperfusion (reperfusion group) procedure. (82)Rb-PET and magnetic resonance imaging (MRI) were conducted before and after the intervention. Perfusion was compared to both left ventricle ejection fraction (LVEF) and infarct size assessed by MRI. Follow-up global (82)Rb-uptake correlated significantly with infarct size (infarct group: r = -0.81, P < 0.001 and reperfusion group: r = -0.61, P = 0.04). Only (82)Rb-uptake in the infarct group correlated with LVEF. At follow-up, a higher segmental (82)Rb-uptake in the infarct group was associated with better wall motion (β = 0.034, CI [0.028;0.039], P < 0.001, R (2) = 0.30), and inversely associated with scar transmurality (β = -2.4 [-2.6; -2.2], P < 0.001, R (2) = 0.59). The associations were similar for the reperfusion group. (82)Rb-PET is feasible in small animal scanners despite the long positron range and enables fast and time-efficient myocardial perfusion imaging in rat models.

  15. Early risk stratification using Rubidium-82 positron emission tomography in STEMI patients.

    PubMed

    Ghotbi, Adam Ali; Hasbak, Philip; Nepper-Christensen, Lars; Lønborg, Jacob; Atharovski, Kiril; Christensen, Thomas; Holmvang, Lene; Engstrøm, Thomas; Ripa, Rasmus Sejersten; Kjær, Andreas

    2017-07-17

    Assessment of infarct size after myocardial infarction is predictive of subsequent morphological changes and clinical outcome. This study aimed to assess subacute post-intervention Rubidium-82 ((82)Rb)-PET imaging in predicting left ventricle ejection fraction, regional wall motion, and final infarct size by CMR at 3-months after STEMI. STEMI patients undergoing percutaneous coronary intervention were included prospectively. Rest-only (82)Rb-PET perfusion imaging was performed at median 36 hours [IQR: 22 to 50] after the treatment. The extent of hypoperfusion and absolute blood flow (mL·min·g) were estimated on a global and a 17-segment model with dedicated software. At 3-months follow-up patients completed the CMR functional and late gadolinium enhancement imaging. 42 patients were included, but only 35 had follow-up CMR and constituted the study population. Absolute blood flow was significantly lower in the infarct-related territory compared to remote myocardium, P < .005. Extent of hypoperfusion correlated with final infarct size, r = 0.58, P < .001, while blood flow correlated with ejection fraction, r = 0.41, P < .05. In linear mixed models, higher subacute absolute blood flow (β = 4.6, confidence interval [3.5; 5.2], P < .001, R (2) = 0.67) was associated with greater wall motion. Segmental extent of subacute hypoperfusion (β = 0.43 [0.38; 0.49], P < .001, R (2) = 0.58) was associated with the degree of late gadolinium enhancement at 3-months. Subacute rest-only (82)Rb-PET is feasible following STEMI and seems predictive of myocardial function and infarct size at 3-months.

  16. Effects of rubidium on responses to potassium channel openers in rat isolated aorta.

    PubMed Central

    Greenwood, I. A.; Weston, A. H.

    1993-01-01

    1. In a physiological salt solution (PSS) in which potassium (K) was replaced by rubidium (Rb), segments of rat aorta precontracted with 20 mM RbCl were fully relaxed by K-channel openers with an order of potency levcromakalim > cromakalim > aprikalim > RP 49356. These relaxations were inhibited by glibenclamide. 2. Segments of rat aorta bathed in normal PSS and precontracted with 20 mM KCl were also relaxed by these K-channel openers with an order of potency levcromakalim > cromakalim > aprikalim > RP 49356. These relaxations were glibenclamide-sensitive. However, the absolute potencies of the K-channel openers were approximately four times greater in normal PSS than in RbPSS. 3. In RbPSS, minoxidil sulphate relaxed segments of aorta precontracted with 20 mM RbCl by approximately 20% whereas in normal PSS it fully relaxed those contracted with 20 mM KCl. 4. In RbPSS, levcromakalim-induced relaxation of aortic segments precontracted with 20 mM RbCl was initially well-maintained but then faded by approximately 60% of the initial relaxation to a new, stable level. Subsequent exposure to RP 49356 or to higher concentrations of levcromakalim was without further relaxant effect. Similar changes were observed when RP 49356 was the initial relaxant and tissues were exposed to either RP 49356 or levcromakalim. In normal PSS, levcromakalim- or RP 49356-induced relaxation of contractions produced by 20 mM KCl was well-maintained. 5. In RbPSS, minoxidil sulphate-induced relaxation of aortic segments precontracted with 20 mM RbCl was well-maintained. Subsequent exposure to either levcromakalim or to RP 49356 produced further tissue relaxation.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:8401946

  17. Regadenoson pharmacologic rubidium-82 PET: a comparison of quantitative perfusion and function to dipyridamole.

    PubMed

    Cullom, S James; Case, James A; Courter, Staci A; McGhie, A Iain; Bateman, Timothy M

    2013-02-01

    Dipyridamole is used for stress (82)rubidium chloride ((82)RbCl) PET because of its long hyperemic duration. Regadenoson has advantages of a fixed dose and favorable symptom profile, but its mean maximal hyperemia is only 2.3 minutes. To determine its suitability for (82)RbCl PET, we imaged subjects using a regadenoson protocol based on its hyperemic response and compared the images in the same subjects having dipyridamole PET. In 32 subjects (23 M), we assessed visually by blinded interpretation and quantitatively compared summed stress and difference scores, total perfusion deficit (TPD), LVEF, LV volumes, and change in stress-rest function. Linear correlation and Bland-Altman analysis of the paired measurements were applied for evaluation of differences. Paired t test and Pearson's correlation were applied for testing of significance. The images were interpreted the same by visual assessment. Twenty-six (26) subjects had reversible defects; by quantitation the SSS was 12.9 ± 7.0 and 14.1 ± 6.4 (P = .23) and SDS was 7.0 ± 6.8 versus 7.6 ± 6.2 (P = .40) for dipyridamole and regadenoson, respectively. Six (6) subjects had <5% likelihood of CAD and were normal by both. All paired measurements showed a high positive correlation between regadenoson and dipyridamole; stress segmental perfusion Reg = 0.93Dip + 4.4, r = 0.88; TPD Reg = 0.94Dip + 0.41, r = 0.93; LVEF Reg = 0.92Dip + 4.7, r = 0.95; stress minus rest LVEF Reg = 0.87Dip - 0.99, r = 0.82. Regadenoson stress (82)RbCl PET perfusion defect and cardiac function measurements are visually and quantitatively equivalent to dipyridamole studies and can be obtained with the clinical advantages of regadenoson.

  18. RUBIDIUM ABUNDANCES IN THE GLOBULAR CLUSTERS NGC 6752, NGC 1904, AND NGC 104 (47 Tuc)

    SciTech Connect

    D'Orazi, Valentina; Lugaro, Maria; Campbell, Simon W.; Bragaglia, Angela; Carretta, Eugenio; Gratton, Raffaele G.; Lucatello, Sara; D'Antona, Francesca

    2013-10-10

    Large star-to-star variations of the abundances of proton-capture elements, such as Na and O, in globular clusters (GCs) are interpreted as the effect of internal pollution resulting from the presence of multiple stellar populations. To better constrain this scenario, we investigate the abundance distribution of the heavy element rubidium (Rb) in NGC 6752, NGC 1904, and NGC 104 (47 Tuc). Combining the results from our sample with those in the literature, we found that Rb exhibits no star-to-star variations, regardless of cluster metallicity, with the possible intriguing, although very uncertain, exception of the metal-rich bulge cluster NGC 6388. If no star-to-star variations can be confirmed for all GCs, this finding implies that the stellar source of the proton-capture element variations must not have produced significant amounts of Rb. This element is observed to be enhanced at extremely high levels in intermediate-mass asymptotic giant branch (IM-AGB) stars in the Magellanic Clouds (i.e., at a metallicity similar to 47 Tuc and NGC 6388). This fact may present a challenge to this popular candidate polluter, unless the mass range of the observed IM-AGB stars does not participate in the formation of the second-generation stars in GCs. A number of possible solutions are available to resolve this conundrum, including the fact that the Magellanic Cloud observations are very uncertain and may need to be revised. The fast rotating massive stars scenario would not face this potential problem as the slow mechanical winds of these stars during their main-sequence phase do not carry any Rb enhancements; however, these candidates face even bigger issues such as the production of Li and the close overlap with core-collapse supernova timescales. Observations of Sr, Rb, and Zr in metal-rich clusters such as NGC 6388 and NGC 6441 are sorely needed to clarify the situation.

  19. High-temperature phase transitions, spectroscopic properties, and dimensionality reduction in rubidium thorium molybdate family.

    PubMed

    Xiao, Bin; Gesing, Thorsten M; Kegler, Philip; Modolo, Giuseppe; Bosbach, Dirk; Schlenz, Hartmut; Suleimanov, Evgeny V; Alekseev, Evgeny V

    2014-03-17

    Four new rubidium thorium molybdates have been synthesized by high-temperature solid-state reactions. The crystal structures of Rb8Th(MoO4)6, Rb2Th(MoO4)3, Rb4Th(MoO4)4, and Rb4Th5(MoO4)12 were determined using single-crystal X-ray diffraction. All these compounds construct from MoO4 tetrahedra and ThO8 square antiprisms. The studied compounds adopt the whole range of possible structure dimensionalities from zero-dimensional (0D) to three-dimensional (3D): finite clusters, chains, sheets, and frameworks. Rb8Th(MoO4)6 crystallizes in 0D containing clusters of [Th(MoO4)6](8-). The crystal structure of Rb2Th(MoO4)3 is based upon one-dimensional chains with configuration units of [Th(MoO4)3](2-). Two-dimensional sheets occur in compound Rb4Th(MoO4)4, and a 3D framework with channels formed by thorium and molybdate polyhedra has been observed in Rb4Th5(MoO4)12. The Raman and IR spectroscopic properties of these compounds are reported. Temperature-depended phase transition effects were observed in Rb2Th(MoO4)3 and Rb4Th(MoO4)4 using thermogravimetry-differential scanning calorimetry analysis and high-temperature powder diffraction methods.

  20. Rubidium extraction from seawater brine by an integrated membrane distillation-selective sorption system.

    PubMed

    Naidu, Gayathri; Jeong, Sanghyun; Johir, Md Abu Hasan; Fane, Anthony G; Kandasamy, Jaya; Vigneswaran, Saravanamuthu

    2017-10-15

    The ultimate goal of seawater reverse osmosis (SWRO) brine management is to achieve minimal liquid discharge while recovering valuable resources. The suitability of an integrated system of membrane distillation (MD) with sorption for the recovery of rubidium (Rb(+)) and simultaneous SWRO brine volume reduction has been evaluated for the first time. Polymer encapsulated potassium copper hexacyanoferrate (KCuFC(PAN)) sorbent exhibited a good selectivity for Rb(+) sorption with 10-15% increment at 55 °C (Langmuir Qmax = 125.11 ± 0.20 mg/g) compared to at 25 °C (Langmuir Qmax = 108.71 ± 0.20 mg/g). The integrated MD-KCuFC(PAN) system with periodic membrane cleaning, enabled concentration of SWRO brine to a volume concentration factor (VCF) of 2.9 (65% water recovery). A stable MD permeate flux was achieved with good quality permeate (conductivity of 15-20 μS/cm). Repeated cycles of MD-KCuFC(PAN) sorption with SWRO brine enabled the extraction of 2.26 mg Rb(+) from 12 L of brine (equivalent to 1.9 kg of Rb/day, or 0.7 tonne/yr from a plant producing 10,000 m(3)/day brine). KCuFC(PAN) showed a high regeneration and reuse capacity. NH4Cl air stripping followed by resorcinol formaldehyde (RF) resin filtration enabled to recover Rb(+) from the desorbed solution. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Economic analysis of clinical positron emission tomography of the heart with rubidium-82

    SciTech Connect

    Gould, K.L.; Goldstein, R.A.; Mullani, N.A.

    1989-05-01

    This report describes a cost analysis for clinical positron emission tomography (PET) of the heart using generator produced rubidium-82 (/sup 82/Rb). Considered sequentially are the clinical problem, current noninvasive radionuclide methods, positron emission tomograph, and the cost of PET per study. Also analyzed are the costs of PET versus thallium imaging in the management of chest pain, for screening asymptomatic men at high risk for coronary artery disease and for evaluating myocardial viability after myocardial infarction or thrombolytic therapy. Noninvasive assessment of coronary artery stenosis and myocardial ischemia/viability in symptomatic or asymptomatic subjects remains a major medical problem because the sensitivity and specificity of thallium imaging are only 70-85% and 50-70%, respectively, in recent studies. Cardiac positron imaging has an accuracy for noninvasive diagnosis of coronary artery disease in symptomatic or asymptomatic patients with a sensitivity and specificity of 95-98%. It can also be used for assessing physiologic stenosis severity, for imaging myocardial infarction and viability, for assessing effects of interventions such as thrombolysis, percutaneous transluminal coronary angioplasty (PTCA) or bypass surgery on myocardial perfusion, metabolism or coronary flow reserve, for assessing collateral function noninvasively in man, and for diagnosing cardiomyopathy not due to coronary artery disease. Although the cost for cardiac PET with /sup 82/Rb may be modestly higher than for /sup 201/Tl, the greater diagnostic yield of PET results in comparable or lower overall medical management costs than no diagnostic tests/interventions and lower overall costs compared to thallium imaging for evaluating patients with chest pain, asymptomatic high risk males, and patients after acute myocardial infarction/thrombolysis for myocardial viability.

  2. Measurement of Na-K-ATPase-mediated rubidium influx in single segments of rat nephron

    SciTech Connect

    Cheval, L.; Doucet, A. )

    1990-07-01

    To determine the functioning rate of Na-K-ATPase in the rat nephron, a micromethod was developed to measure the rate of rubidium uptake in single nephron segments microdissected from collagenase-treated kidneys. Because the hydrolytic activity of Na-K-ATPase displayed the same apparent affinity for K and Rb ions, whereas the Vmax elicited by K was higher than that in the presence of Rb, experiments were performed in the presence of cold Rb plus 86Rb. Before the assay, tubules were preincubated for 10 min at 37 degrees C to restore the normal transmembrane cation gradients. 86Rb uptake was measured after washing out extracellular cations by rinsing the tubules in ice-cold choline chloride solution containing Ba2+. Rb uptake increased quasi-linearly as a function of incubation time up to 30 s in the thick ascending limb, 1 min in the proximal convoluted tubule, and 5 min in the collecting tubule, and reached an equilibrium after 5-30 min. The initial rates of Rb uptake increased in a saturable fashion as Rb concentration in the medium rose from 0.25 to 5 mM. In medullary thick ascending limb, the initial rate of Rb uptake was inhibited by greater than 90% by 2.5 mM ouabain and by 10(-5) M of the metabolic inhibitor carbonyl cyanide trifluoromethoxyphenylhydrazone. Correlation of Na-K-ATPase hydrolytic activity at Vmax and initial rates of ouabain-sensitive Rb uptake in the successive segments of nephron indicates that in intact cells the pump works at approximately 20-30% of its Vmax. Increasing intracellular Na concentration by tubule preincubation in a Rb- and K-free medium increased the initial rates of Rb intake up to the Vmax of the hydrolytic activity of the pump.

  3. [Chronic administration of lithium and rubidium in rats. General behavior, explorative behavior and electric activity of the brain].

    PubMed

    Sopranzi, N

    1993-03-01

    We have studied the rat under chronic treatment with lithium carbonate and rubidium chloride both given ip. For a four week period we have recorded, once a week, weight, rectal temperature, tail-flick, motor co-ordination and general activity in a one-arm radial maze and in a Boissier-Simon table. At the end of the fourth week surface (SEEG) and deep EEGrams (DEEG: hippocampus, amygdala) were recorded from treated and control animals. FFT (Hanning window) was performed both for SEEG and DEEG. The findings are: 1) No changes in weight, rectal temperature, tail-flick and motor coordination (rotarod). 2) In the one-arm maze and in the Boissier-Simon table rubidium is in contrast to the effects of lithium, it causes increased activity and aggression 3) the EEGrams were analyzed by means of FFT as power in preselected bands of frequency. The results, on the whole, suggest, since these two ions have opposite effects on brain norepinephrine metabolism, that they may be useful in the treatment of PMD.

  4. The nature of ion exchange selectivity of phenol-formaldehyde sorbents with respect to cesium and rubidium ions

    NASA Astrophysics Data System (ADS)

    Kargov, S. I.; Shelkovnikova, L. A.; Ivanov, V. A.

    2012-05-01

    The structure of aqua complexes of alkali metal ions Me+(H2O) n , n = 1-6, where Me is Li, Na, K, Rb, and Cs, and complexes of 2,6-dimethylphenolate anion (CH3)2PhO- selected as a model of the elementary unit of phenol-formaldehyde ion exchanger with hydrated alkali metal cations Me+(H2O) n , n = 0-5, was studied by the density functional method. The energies of successive hydration of the cations and the energies of binding of alkali metal hydrated cations with (CH3)2PhO- depending on the number of water molecules n were calculated. It was shown that the dimethylphenolate ion did not have specific selectivity with respect to cesium and rubidium ions. The energies of hydration and the energies of binding of alkali metal cations with (CH3)2PhO- decreased in the series Li+ > Na+ > K+ > Rb+ > Cs+ as n increased. The conclusion was drawn that the reason for selectivity of phenol-formaldehyde and other phenol compounds with respect to cesium and rubidium ions was the predomination of the ion dehydration stage in the transfer from an aqueous solution to the phenol phase compared with the stage of binding with ion exchange groups.

  5. Evaluation of the frequency stability of a VCSEL locked to a micro-fabricated Rubidium vapour cell

    NASA Astrophysics Data System (ADS)

    Di Francesco, J.; Gruet, F.; Schori, C.; Affolderbach, C.; Matthey, R.; Mileti, G.; Salvadé, Y.; Petremand, Y.; De Rooij, N.

    2010-04-01

    We present our evaluation of a compact laser system made of a 795 nm VCSEL locked to the Rubidium absorption line of a micro-fabricated absorption cell. The spectrum of the VCSEL was characterised, including its RIN, FM noise and line-width. We optimised the signal-to-noise ratio and determined the frequency shifts versus the cell temperature and the incident optical power. The frequency stability of the laser (Allan deviation) was measured using a high-resolution wavemeter and an ECDL-based reference. Our results show that a fractional instability of <= 10-9 may be reached at any timescale between 1 and 100'000 s. The MEMS cell was realised by dispensing the Rubidium in a glass-Silicon preform which was then, sealed by anodic bonding. The overall thickness of the reference cell is 1.5 mm. No buffer gas was added. The potential applications of this compact and low-consumption system range from optical interferometers to basic laser spectroscopy. It is particularly attractive for mobile and space instruments where stable and accurate wavelength references are needed.

  6. Near infrared rubidium 62P3/2,1/2→62S1/2 laser

    NASA Astrophysics Data System (ADS)

    Moran, Paul J.; Richards, Ryan M.; Rice, Christopher A.; Perram, Glen P.

    2016-09-01

    An optically pumped near infrared rubidium (Rb) pulsed, mirrorless laser has been demonstrated in a heat pipe along both the 62P3/2-62S1/2 transition at 2.73 μm and the 62P1/2-62S1/2 transition at 2.79 μm. The bleached limit, slope efficiency, and maximum laser output energy of the near infrared Rb laser scale linearly with increasing Rb density, contrary to prior results. Previously, a maximum output energy of ~5 nJ had been observed before a rollover occurred in the scaling of output energy with rubidium concentration. In this experiment, the maximum laser output energy observed was ~100 nJ, with no indication of any scaling limitation. A maximum slope efficiency of 1.7×10-4 was observed. A small percentage of the pump photons were absorbed even at the maximum Rb density attainable in the heat pipe, indicating that laser efficiency could be scaled to near the quantum efficiency. Additionally, the hyperfine structure and absorption spectral profile of the 52S1/2-62P1/2 and 52S1/2-62P3/2 (blue) pump transitions were studied using a cw pump source.

  7. Crystal structure and superconductivity of rubidium tungsten bronzes Rb{sub x}WO{sub 3} prepared by a hybrid microwave method

    SciTech Connect

    Guo Juan Dong Cheng; Yang Lihong; Chen Hong

    2008-04-01

    The rubidium tungsten bronzes Rb{sub x}WO{sub 3} have been prepared from Rb{sub 2}CO{sub 3}, WO{sub 3} and W powders using hybrid microwave method. The single hexagonal phase samples can be obtained as actual rubidium content x in the range of 0.21-0.33, and their lattice parameters a and c linearly drop and rise with the increase of rubidium content respectively. For samples with x = 0.14, 0.16, 0.18, the superconducting transition temperature T{sub c} from resistivity measurements does not change with the rubidium content, while T{sub c} from susceptibility measurements shows a decrease from 5.3 K for x = 0.14 to 4.8 K for x = 0.18. The charge density wave (CDW) transition appears in Rb{sub 0.21}WO{sub 3}, Rb{sub 0.23}WO{sub 3} and Rb{sub 0.25}WO{sub 3} at about 200-260 K. The CDW transition is most obvious in Rb{sub 0.23}WO{sub 3} which shows the lowest degree of crystallization among the samples.

  8. Coherent optical transients observed in rubidium atomic line filtered Doppler velocimetry experiments

    NASA Astrophysics Data System (ADS)

    Fajardo, Mario E.; Molek, Christopher D.; Vesely, Annamaria L.

    2015-10-01

    We report the first successful results from our novel Rubidium Atomic Line Filtered (RALF) Doppler velocimetry apparatus, along with unanticipated oscillatory signals due to coherent optical transients generated within pure Rb vapor cells. RALF is a high-velocity and high-acceleration extension of the well-known Doppler Global Velocimetry (DGV) technique for constructing multi-dimensional flow velocity vector maps in aerodynamics experiments [H. Komine, U.S. Patent No. 4,919,536 (24 April 1990)]. RALF exploits the frequency dependence of pressure-broadened Rb atom optical absorptions in a heated Rb/N2 gas cell to encode the Doppler shift of reflected near-resonant (λ0 ≈ 780.24 nm) laser light onto the intensity transmitted by the cell. The present RALF apparatus combines fiber optic and free-space components and was built to determine suitable operating conditions and performance parameters for the Rb/N2 gas cells. It yields single-spot velocities of thin laser-driven-flyer test surfaces and incorporates a simultaneous Photonic Doppler Velocimetry (PDV) channel [Strand et al., Rev. Sci. Instrum. 77, 083108 (2006)] for validation of the RALF results, which we demonstrate here over the v = 0 to 1 km/s range. Both RALF and DGV presume the vapor cells to be simple Beer's Law optical absorbers, so we were quite surprised to observe oscillatory signals in experiments employing low pressure pure Rb vapor cells. We interpret these oscillations as interference between the Doppler shifted reflected light and the Free Induction Decay (FID) coherent optical transient produced within the pure Rb cells at the original laser frequency; this is confirmed by direct comparison of the PDV and FID signals. We attribute the different behaviors of the Rb/N2 vs. Rb gas cells to efficient dephasing of the atomic/optical coherences by Rb-N2 collisions. The minimum necessary N2 buffer gas density ≈0.3 amagat translates into a smallest useful velocity range of 0 to 2 km/s, which can

  9. Crystal structure of ammonium octacyanomolybdate(IV) and rubidium octacyanomolybdate(IV)

    SciTech Connect

    Semenishin, D.I.; Glovyak, T.; Mys'kiv, M.G.

    1985-11-01

    The crystal structure of ammonium octacyanomolybdate(IV) and rubidium octacyanomolybdate(IV) has been determined by the single-crystal method on a Syntex P2/sub 1/ automatic diffractometer: ((NH/sub 4/)/sub 4/ Mo(CN)/sub 4/) 0.5H/sub 2/O (I) (space group Pma2, a = 15.550(3), b = 14.118(3), c = 7.438(1) A, Z = 4, R = 0.062) and Rb/sub 4/(Mo(CN)/sub 8/). 3H/sub 2/O (II) (space group P4/sub 1/2/sub 1/2, a = 9.300(10, c = 21.807(3) A, Z = 4, R = 0.065). The Mo atoms in structure I occupy two special positions (2(b) and 2(c)) and are each surrounded by eight CN ligands. The mean value of the Mo-C distances for Mo(1) is equal to 2.216 A, and the corresponding value for Mo(2) is 2.235 A. The mean Mo-N lengths are practically identical in both molybdenum anions and are equal to 3.353 A. The mean values of the C identical with N bond lengths in the Mo(1) and Mo(2) anions are 1.118 and 1.137 A, respectively. The MoCn angles vary from 175.0 to 178.4/sup 0/. The coordination sphere of the Mo(1) atom corresponds to a dodecahedron with a single twofold symmetry axis, and the coordination polyhedron of the Mo(2) atom in an antiprism of m symmetry. In structure II the Mo-C distances are within the 2.130-2.160-A range, and the Mo-N distances range from 3.290 to 3.307 A. The MoCN angles vary from 176.0 to 179.3/sup 0/, and the coordination polyhedron of (MoC/sub 8/) is a dodecahedron of 2 symmetry. The existence of two types of coordination of Mo in structure I is presently the only example among the structurally studied octahyanomolybdates(IV).

  10. Rubidium Abundances in the Globular Clusters NGC 6752, NGC 1904, and NGC 104 (47 Tuc)

    NASA Astrophysics Data System (ADS)

    D'Orazi, Valentina; Lugaro, Maria; Campbell, Simon W.; Bragaglia, Angela; Carretta, Eugenio; Gratton, Raffaele G.; Lucatello, Sara; D'Antona, Francesca

    2013-10-01

    Large star-to-star variations of the abundances of proton-capture elements, such as Na and O, in globular clusters (GCs) are interpreted as the effect of internal pollution resulting from the presence of multiple stellar populations. To better constrain this scenario, we investigate the abundance distribution of the heavy element rubidium (Rb) in NGC 6752, NGC 1904, and NGC 104 (47 Tuc). Combining the results from our sample with those in the literature, we found that Rb exhibits no star-to-star variations, regardless of cluster metallicity, with the possible intriguing, although very uncertain, exception of the metal-rich bulge cluster NGC 6388. If no star-to-star variations can be confirmed for all GCs, this finding implies that the stellar source of the proton-capture element variations must not have produced significant amounts of Rb. This element is observed to be enhanced at extremely high levels in intermediate-mass asymptotic giant branch (IM-AGB) stars in the Magellanic Clouds (i.e., at a metallicity similar to 47 Tuc and NGC 6388). This fact may present a challenge to this popular candidate polluter, unless the mass range of the observed IM-AGB stars does not participate in the formation of the second-generation stars in GCs. A number of possible solutions are available to resolve this conundrum, including the fact that the Magellanic Cloud observations are very uncertain and may need to be revised. The fast rotating massive stars scenario would not face this potential problem as the slow mechanical winds of these stars during their main-sequence phase do not carry any Rb enhancements; however, these candidates face even bigger issues such as the production of Li and the close overlap with core-collapse supernova timescales. Observations of Sr, Rb, and Zr in metal-rich clusters such as NGC 6388 and NGC 6441 are sorely needed to clarify the situation. Based on observations taken with ESO telescopes under program 085.D-0205(A).

  11. Capture and ionization detection of laser-cooled rubidium atoms with a charged suspended carbon nanotube

    NASA Astrophysics Data System (ADS)

    Ristroph, Trygve Gibbens

    The capture and ionization of neutral rubidium atoms with a positively charged suspended carbon nanotube is realized. The electric field surrounding the nanotube polarizes and pulls atoms into the highly singular attractive inverse square potential. Atoms are ionized by the nanotube, and Rb+ ions are ejected radially and subsequently detected individually. The entire process of capture, ionization, and ion-detection reveals a rich set of behavior, probing the dynamics of laser-cooled atoms as well as nanotube and ionization physics. When the device is used as an atom detector, the cold-atom ionization signal replicates time-dependent features in the instantaneous atom beam density on sub-millisecond time scales. This time resolution allows a time-of-flight measurement of atom velocity, corroborated with a laser absorption measurement. Position sensitivity on the 200 micron scale is demonstrated, as the detector is scanned to map out the atom beam transverse mode profile, a capability otherwise forbidden by the system's optical access. A measurement of the nanotube ionization cross-section as a function of atomic velocity and charging voltage shows the capture process is dominated by an inverse square potential energy. The cross-section reveals an inverse velocity scaling, consistent with the prediction. The analogous charging voltage measurement shows a linear scaling in voltage with measured and predicted slopes in agreement. Sending current through the nanotube changes the voltage offset of the cross-section versus voltage curve. This suggests that the ionization occurs in close proximity to the nanotube surface and is therefore sensitive to its electronic and mechanical properties. Theoretical foundations are developed to describe the capture and ionization physics involved in observing the quantization of atomic orbital angular momentum with the detector. For experimentally accessible parameters, the observation of the quantized conductance of neutral atoms is

  12. Coherent optical transients observed in rubidium atomic line filtered Doppler velocimetry experiments

    SciTech Connect

    Fajardo, Mario E. Molek, Christopher D.; Vesely, Annamaria L.

    2015-10-14

    We report the first successful results from our novel Rubidium Atomic Line Filtered (RALF) Doppler velocimetry apparatus, along with unanticipated oscillatory signals due to coherent optical transients generated within pure Rb vapor cells. RALF is a high-velocity and high-acceleration extension of the well-known Doppler Global Velocimetry (DGV) technique for constructing multi-dimensional flow velocity vector maps in aerodynamics experiments [H. Komine, U.S. Patent No. 4,919,536 (24 April 1990)]. RALF exploits the frequency dependence of pressure-broadened Rb atom optical absorptions in a heated Rb/N{sub 2} gas cell to encode the Doppler shift of reflected near-resonant (λ{sub 0} ≈ 780.24 nm) laser light onto the intensity transmitted by the cell. The present RALF apparatus combines fiber optic and free-space components and was built to determine suitable operating conditions and performance parameters for the Rb/N{sub 2} gas cells. It yields single-spot velocities of thin laser-driven-flyer test surfaces and incorporates a simultaneous Photonic Doppler Velocimetry (PDV) channel [Strand et al., Rev. Sci. Instrum. 77, 083108 (2006)] for validation of the RALF results, which we demonstrate here over the v = 0 to 1 km/s range. Both RALF and DGV presume the vapor cells to be simple Beer's Law optical absorbers, so we were quite surprised to observe oscillatory signals in experiments employing low pressure pure Rb vapor cells. We interpret these oscillations as interference between the Doppler shifted reflected light and the Free Induction Decay (FID) coherent optical transient produced within the pure Rb cells at the original laser frequency; this is confirmed by direct comparison of the PDV and FID signals. We attribute the different behaviors of the Rb/N{sub 2} vs. Rb gas cells to efficient dephasing of the atomic/optical coherences by Rb-N{sub 2} collisions. The minimum necessary N{sub 2} buffer gas density ≈0.3 amagat translates into a smallest

  13. Effect of buffer gas on an electromagnetically induced transparency in a ladder system using thermal rubidium vapor

    SciTech Connect

    Sargsyan, Armen; Sarkisyan, David; Krohn, Ulrich; Keaveney, James; Adams, Charles

    2010-10-15

    We report on the observation of electromagnetically induced transparency in a ladder system in the presence of a buffer gas. In particular, we study the 5S{sub 1/2}-5P{sub 3/2}-5D{sub 5/2} transition in thermal rubidium vapor with a neon buffer gas at a pressure of 6 Torr. In contrast to the line-narrowing effect of buffer gas on {Lambda} systems, we show that the presence of the buffer gas leads to an additional broadening of (34{+-}5) MHz, which suggests a cross section for Rb(5D{sub 5/2})-Ne of {sigma}{sub k}{sup (D)}=(23{+-}4)x10{sup -19} m{sup 2}. However, in the limit where the coupling Rabi frequency is larger than the collisional dephasing, a strong transparency feature can still be observed.

  14. Amplified spontaneous emission measurement of a line-narrowed, tunable, Ti:Al2O3 amplifier using rubidium absorption

    NASA Technical Reports Server (NTRS)

    Barnes, James C.; Barnes, Norman P.; Lockard, George E.; Cross, Patricia L.

    1989-01-01

    Amplified spontaneous emission, ASE, generated by a Ti:Al2O3 laser amplifier has been measured as a function of pump energy, and thus gain, using the atomic absorption of rubidium, Rb, gas at 0.780 micron. By tuning the Ti:Al2O3 laser, the Rb cell could selectively absorb the narrow spectral bandwidth laser radiation while transmitting the wide spectral bandwidth ASE. Transmission of laser amplifier pulses through a Rb absorption cell, measured at various temperatures, thus allows the measurement of the weak ASE in the vicinity of the strong laser pulse. A model for the transmission of Rb as a function of temperature and wavelength has been developed. The measured transmissions are in good agreement with the transmission model predictions.

  15. Potassium, rubidium, strontium, thorium, uranium, and the ratio of strontium-87 to strontium-86 in oceanic tholeiitic basalt

    USGS Publications Warehouse

    Tatsumoto, M.; Hedge, C.E.; Engel, A.E.J.

    1965-01-01

    The average concentrations of potassium, rubidium, strontium, thorium, and uranium in oceanic tholeiitic basalt are (in parts per million) K, 1400; Rb, 1.2; Sr, 120; Th, 0.2; and U, 0.1. The ratio Sr87 to Sr86 is about 0.702, that of K to U is 1.4 ?? 104, and of Th to U is 1.8. These amounts of K, Th, U, and radiogenic Sr87 are less than in other common igneous rocks. The ratios of Th to U and Sr87 to Sr 86 suggest that the source region of the oceanic tholeiites was differentiated from the original mantle material some time in the geologic past.

  16. Spectral anomalies of the light-induced drift of rubidium atoms caused by the velocity dependence of transport collision frequencies

    NASA Astrophysics Data System (ADS)

    Parkhomenko, A. I.; Shalagin, A. M.

    2014-02-01

    The spectral features of the light-induced drift (LID) velocity for rubidium atoms (85Rb and 87Rb) in an argon buffer medium and in binary buffer mixtures of noble gases (Ne + Ar, Ne + Kr, Ne + Xe, He + Ar, He + Kr, and He + Xe) have been investigated theoretically. A strong temperature dependence of the spectral shape of the LID signal for Rb atoms in an Ar atmosphere is predicted in the temperature range 450 K < T < 800 K. It is shown that the anomalous LID of Rb atoms in binary buffer mixtures of noble gases can be observed at almost any temperature (including the room one) depending on the fractions of neon or helium in these mixtures. The results obtained enable a highly accurate testing of the interatomic interaction potentials used to calculate the drift velocity for anomalous LID in LID experiments.

  17. Skeletal muscle blood flow in vivo: detection with rubidium-82 and effects of glucose, insulin, and exercise

    SciTech Connect

    Mossberg, K.A.; Mullani, N.; Gould, K.L.; Taegtmeyer, H.

    1987-07-01

    In order to assess the effects of glucose, insulin, and exercise on skeletal muscle blood flow in vivo, we measured positron emission from the thigh muscle of anesthetized rabbits after simultaneous aortic bolus injection of /sup 82/Rb and radiolabeled microspheres (15 micron diameter). Estimates of flow with /sup 82/Rb were based on first-pass regional extraction of /sup 82/Rb by skeletal muscle. Flow estimates were made serially as a function of variations in plasma glucose and insulin and changing the muscle contractile state by electrical stimulation. Flow ranged from 3.1 ml/min/100 g at rest to 71 ml/min/100 g during stimulation. There was good agreement between the two methods of flow measurement over the entire range of flows (r = 0.96 at a slope of 0.90). Flow measured by either method did not vary significantly from baseline over a range of plasma glucose from 5 to 30 mM and plasma insulin from 0 to 20 microU/ml. When flow was increased up to 20-fold by electrical stimulation there was a decrease in extraction of /sup 82/Rb proportional to the increase in flow. However, at pharmacologic levels of insulin (greater than 150 microU/ml) flow was increased twofold as measured by radiolabeled microspheres, but not as measured by rubidium. There was no apparent decrease in extraction of /sup 82/Rb with high insulin. The discrepancy between the microsphere measured flow and rubidium measured flow with high plasma insulin levels can be explained by the assumption that the expected decrease in the extraction fraction was counteracted by an increase in Na+/K+-ATPase activity. It is concluded that the first-pass flow model gives valid estimates of skeletal muscle blood flow in vivo with /sup 82/Rb, provided that plasma insulin levels are normal.

  18. [Distribution of rubidium, cesium, beryllium, strontium, and barium in blood and urine in general Chinese population].

    PubMed

    Ding, Chunguang; Pan, Yajuan; Zhang, Aihua; Zhu, Chun; Liu, Deye; Xu, Guang; Zheng, Yuxin; Yan, Huifang

    2015-12-01

    To investigate the distribution of rubidium (Rb), cesium (Cs), beryllium (Be), strontium (Sr), and barium (Ba) in blood and urine in general Chinese population. A total of 18 120 subjects aged 6~60 years were enrolled from 24 regions in 8 provinces in Eastern, Central, and Western China from 2009 to 2010 based on the method of cluster random sampling. Questionnaire survey was conducted to collect the data on living environment and health status. Blood and urine samples were collected from these subjects, and the levels of Rb, Cs, Be, Sr, and Ba in these samples were determined by inductively coupled plasma mass spectrometry. The distribution of these elements in blood and urine in male or female subjects living in different regions was analyzed statistically. In the general Chinese population, the concentration of Be in the whole blood was below the detection limit (0.06 μg/L); the geometric mean (GM) of Ba in the whole blood was below the detection limit (0.45 μg/L), with the 95th percentile (P95)of 1.37 μg/L; the GMs (95% CI)of Rb, Cs, and Sr in the whole blood were 2 374(2 357~2 392) μg/L, 2.01 (1.98~2.05) μg/L, and 23.5 (23.3~23.7) μg/L, respectively; in males and females, the GMs (95%CI)of blood Rb, Cs, and Sr were 2 506 (2 478~2 533) μg/L and 2 248 (2 227~2 270) μg/L, 1.88 (1.83~1.94) μg/L and 2.16 (2.11~2.20) μg/L, and 23.4 (23.1~23.7) μg/L and 23.6 (23.3~23.9) μg/L, respectively(P<0.01, P>0.05, and P>0.05). In the general Chinese population, the GM of urine Be was below the detection limit (0.06 μg/L), while the GMs (95%CI)of urine Rb, Cs, Sr, and Ba were 854 (836~873) μg/L, 3.65 (3.56~3.74) μg/L, 39.5 (38.4~40.6) μg/L, and 1.10 (1.07~1.12) μg/L, respectively; in males and females, the GMs (95%CI)of urine Rb, Cs, Sr, and Ba were 876 (849~904) μg/L and 832 (807~858) μg/L, 3.83 (3.70~3.96) μg/L and 3.47 (3.35~3.60) μg/L, 42.5 (40.9~44.2) μg/L and 36.6 (35.1~38.0) μg/L, and 1.15 (1.12~1.19) μg/L and 1.04 (1.01~1.07) μg/L, respectively

  19. Molecular dynamics simulation of the structure and thermodynamic properties of liquid rubidium at pressures of up to 10 GPa and temperatures of up to 3500 K

    NASA Astrophysics Data System (ADS)

    Belashchenko, D. K.

    2016-09-01

    The models of rubidium at temperatures of up to 3500 K, degrees of compression of up to Y = V/ V 0 = 0.3, and pressures of up to 32 GPa were constructed by molecular dynamics (MD) using the interparticle potential EAM. The thermodynamic properties of the MD models agree satisfactorily with experiment in the range of parameters under study at rubidium densities higher than 0.86 g/cm3. The behavior of the models in the range of the van der Waals loop was analyzed; the calculated critical temperature of rubidium T c is ˜2250 ± 25 K, density ˜0.41 g/cm3, pressure ˜0.019 GPa, and compressibility factor Z = pV/ RT ≈ 0.137. The states with the unity factor Z = 1 were observed at pressures of up to 0.30 GPa (at ˜3000 K); the temperature dependence of the density of the models with Z = 1 is nearly linear, and the Boyle temperature is T B ≈ 10160 K. The ratio T c/ T B = 0.221 is close to this value for cesium (0.23) and mercury (0.276). In the temperature and pressure ranges under study, the inversion of the Joule-Thomson coefficient did not take place, but should be observed at pressures of ⩽0.3 GPa and elevated temperatures. It was found that the diffusion coefficient D( T) dependences do not straighten in the usually used coordinates within wide temperature ranges. It was concluded that the structure of the liquid smoothly changes when the rubidium models are compressed and this reveals in the change of the degree of asymmetry of the first peak of the radial distribution function.

  20. Characterization of a hERG screen using the IonWorks HT: comparison to a hERG rubidium efflux screen.

    PubMed

    Sorota, Steve; Zhang, Xue-Song; Margulis, Michael; Tucker, Kristal; Priestley, Tony

    2005-02-01

    The introduction of parallel patch clamp instruments offers the promise of moderate-throughput, high-fidelity voltage clamp for drug screening assays. One such device, the IonWorks HT (Molecular Devices, Sunnyvale, CA), was evaluated and compared to conventional human ethera- go-go-related gene (hERG) patch clamp data and an alternative functional screen based on rubidium flux. Data generated by the IonWorks HT and rubidium assays were compared to determine if either offered superior predictive value compared to conventional patch clamp. Concentration-effect curves for a panel of known hERG blockers were shifted to higher concentrations on the IonWorks HT compared to conventional voltage clamp determinations. The magnitude of the potency shifts was compound-specific and ranged from no shift (e.g., quinidine) to over 200-fold (astemizole). When the extreme value for astemizole was disregarded, the potency shift for 13 other known reference standards was 12-fold or less, with an average shift of fivefold. The same subset of compounds in the rubidium efflux assay exhibited an average potency shift of 12-fold. To provide a simulation of how the IonWorks HT assay might perform in a single concentration screening mode, a panel of test compounds was evaluated. The IonWorks HT screen did not outperform the rubidium efflux screen in predicting conventional voltage clamp measurements. The most likely explanation appears to rest with variable and compound-specific potency shifts in the IonWorks HT assay. The variable potency shifts make it difficult to select a screening concentration that meets the criterion of a high positive predictive value while avoiding false-positives.

  1. A physics package for rubidium atomic frequency standard with a short-term stability of 2.4 × 10-13 τ-1/2

    NASA Astrophysics Data System (ADS)

    Hao, Qiang; Li, Wenbing; He, Shengguo; Lv, Jianfeng; Wang, Pengfei; Mei, Ganghua

    2016-12-01

    In this article, a new type of physics package with high signal to noise ratio for a rubidium atomic frequency standard is reported. To enhance the clock transition signal, a slotted tube microwave cavity with a field orientation factor of 0.93 and an absorption cell with the diameter of 30 mm were utilized in design of the cavity-cell assembly. Based on the spectral analysis of the three commonly used rubidium spectral lamps, the spectral lamp filled with Xe gas was chosen as the optical pumping source for its small line shape distortion. To suppress the shot noise of the signal, a band pass interference filter was used to filter out Xe spectral lines from the pumping light. A desk system of the rubidium frequency standard with the physics package was realized, and the short-term stability of the system was predicted and tested. The measured result is 2.4 × 10-13 τ-1/2 up to 100 s averaging time, in good agreement with the predicted one.

  2. Observation of the 5 p3 /2→6 p3 /2 electric-dipole-forbidden transition in atomic rubidium using optical-optical double-resonance spectroscopy

    NASA Astrophysics Data System (ADS)

    Ponciano-Ojeda, F.; Hernández-Gómez, S.; López-Hernández, O.; Mojica-Casique, C.; Colín-Rodríguez, R.; Ramírez-Martínez, F.; Flores-Mijangos, J.; Sahagún, D.; Jáuregui, R.; Jiménez-Mier, J.

    2015-10-01

    Direct evidence of excitation of the 5 p3 /2→6 p3 /2 electric-dipole-forbidden transition in atomic rubidium is presented. The experiments were performed in a room-temperature rubidium cell with continuous-wave external cavity diode lasers. Optical-optical double-resonance spectroscopy with counterpropagating beams allows the detection of the nondipole transition free of Doppler broadening. The 5 p3 /2 state is prepared by excitation with a laser locked to the maximum F cyclic transition of the D2 line, and the forbidden transition is produced by excitation with a 911 nm laser. Production of the forbidden transition is monitored by detection of the 420 nm fluorescence that results from decay of the 6 p3 /2 state. Spectra with three narrow lines (≈13 MHz FWHM) with the characteristic F -1 , F , and F +1 splitting of the 6 p3 /2 hyperfine structure in both rubidium isotopes were obtained. The results are in very good agreement with a direct calculation that takes into account the 5 s →5 p3 /2 preparation dynamics, the 5 p3 /2→6 p3 /2 nondipole excitation geometry, and the 6 p3 /2→5 s1 /2 decay. The comparison also shows that the electric-dipole-forbidden transition is a very sensitive probe of the preparation dynamics.

  3. Determination of traces of rubidium in high purity cesium chloride by electrothermal atomic absorption spectrometry (ETAAS) using boric acid as a modifier.

    PubMed

    Dash, K; Thangavel, S; Chaurasia, S C; Arunachalam, J

    2007-02-12

    The use of boric acid as a modifier for the determination of trace amount of rubidium in high purity cesium chloride matrix by electrothermal atomic absorption is described. It was found that the negative influence of the chloride matrix could not be eliminated using stabilized temperature platform (STPF) alone. Due to the high dissociation energy (D(0)=427 kJ mol(-1)) of rubidium chloride, it was difficult to dissociate in the gas phase and hence is lost. Elimination of interferences was achieved by the addition of boric acid as a chemical modifier. Diluted cesium chloride samples (5%, m/v) were analyzed applying the standard addition method. The characteristic mass of 24 pg was obtained. The detection limit of the proposed method is around 26 ng g(-1). The developed method was applied to the determination of traces of rubidium in high purity cesium chloride samples. The data obtained by this method were in good agreement with those obtained by other independent method like FAAS.

  4. Synthesis of novel ion-imprinted polymeric nanoparticles based on dibenzo-21-crown-7 for the selective pre-concentration and recognition of rubidium ions.

    PubMed

    Hashemi, Beshare; Shamsipur, Mojtaba

    2015-12-01

    In this work, we report the first application of ion-imprinted technology via precipitation polymerization for simple and practical determination of rubidium ions. The rubidium-ion-imprinted polymer nanoparticles were prepared using dibenzo-21-crown-7 as a selective ligand, methacrylic acid as functional monomer, ethylene glycol dimethacrylate as cross linker, and 2,2'-azobisisobutyronitrile as radical initiator. The resulting powder material was characterized using scanning electron microscopy, which showed colloidal nanoparticles of 100-200 nm in diameter and slightly irregular in shape. The maximum adsorption capacity of the ion imprinted particles was 63.36 μmol/g. The experimental conditions such as nature and concentration of eluent, pH, adsorption and desorption times, weight of the polymer material, aqueous phase and desorption agent volumes were also studied. Finally, selectivity of the prepared IIP particles toward rubidium ion was investigated in the presence of some foreign metal ions. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. On-orbit frequency stability analysis of the GPS NAVSTAR-1 quartz clock and the NAVSTARs-6 and -8 rubidium clocks

    NASA Technical Reports Server (NTRS)

    Mccaskill, T. B.; Buisson, J. A.; Reid, W. G.

    1984-01-01

    An on-orbit frequency stability performance analysis of the GPS NAVSTAR-1 quartz clock and the NAVSTARs-6 and -8 rubidium clocks is presented. The clock offsets were obtained from measurements taken at the GPS monitor stations which use high performance cesium standards as a reference. Clock performance is characterized through the use of the Allan variance, which is evaluated for sample times of 15 minutes to two hours, and from one day to 10 days. The quartz and rubidium clocks' offsets were corrected for aging rate before computing the frequency stability. The effect of small errors in aging rate is presented for the NAVSTAR-8 rubidium clock's stability analysis. The analysis includes presentation of time and frequency residuals with respect to linear and quadratic models, which aid in obtaining aging rate values and identifying systematic and random effects. The frequency stability values were further processed with a time domain noise process analysis, which is used to classify random noise process and modulation type.

  6. A physics package for rubidium atomic frequency standard with a short-term stability of 2.4 × 10(-13) τ(-1/2).

    PubMed

    Hao, Qiang; Li, Wenbing; He, Shengguo; Lv, Jianfeng; Wang, Pengfei; Mei, Ganghua

    2016-12-01

    In this article, a new type of physics package with high signal to noise ratio for a rubidium atomic frequency standard is reported. To enhance the clock transition signal, a slotted tube microwave cavity with a field orientation factor of 0.93 and an absorption cell with the diameter of 30 mm were utilized in design of the cavity-cell assembly. Based on the spectral analysis of the three commonly used rubidium spectral lamps, the spectral lamp filled with Xe gas was chosen as the optical pumping source for its small line shape distortion. To suppress the shot noise of the signal, a band pass interference filter was used to filter out Xe spectral lines from the pumping light. A desk system of the rubidium frequency standard with the physics package was realized, and the short-term stability of the system was predicted and tested. The measured result is 2.4 × 10(-13) τ(-1/2) up to 100 s averaging time, in good agreement with the predicted one.

  7. Comparison of rubidium-82 myocardial blood flow quantification with coronary calcium score for evaluation of coronary artery stenosis.

    PubMed

    Meintjes, Marguerite; Sathekge, Mike; Makanjee, Chandra R; Dickson, John C; Endozo, Raymond; Rheeder, Paul; Bomanji, Jamshed

    2016-02-01

    PET myocardial perfusion imaging (MPI) is the standard technique for assessing myocardial function, but provides limited information on the anatomy of cardiac structures whereas the coronary artery calcium (CAC) score provides information on calcified plaque burden and the anatomical structure of the coronary arteries. The aim of this study was to determine the relationship between quantitative myocardial blood flow (MBF), CAC, and coronary artery disease (CAD). This work also aims to determine whether MBF quantification and/or CAC add value to relative MPI, and aid in the reclassification of patients with CAD. This way, a 'gatekeeper' study could be identified to predict coronary artery stenosis and improve our clinical service. Rubidium-82 PET/CT MPI, calcium score, and computed tomographic coronary angiography imaging were performed in 128 patients with known or suspected CAD. The presence of ischemia was assessed from qualitative reporting of rubidium-82 MPI, and using the same data, quantitative values of MBF and coronary flow reserve (CFR) were derived. Calcium score images were quantitatively analyzed and categorized into three groups defined by CAC values of 0, 1-400, and >400. Significant stenosis was classified as stenosis of 50% or more on computed tomographic angiography. A total of 120 patients were included in the final analysis (77 men, 43 women). Our results showed an inverse correlation between stress MBF, CFR, and the percentage stenosis as well as an inverse correlation compared with CAC. A direct correlation between CAC and the percentage stenosis was observed, indicating that an increase in coronary calcification in individual coronary arteries is related to the severity of the coronary stenosis. These results proved that the addition of stress MBF to relative MPI (32%) resulted in a significantly higher sensitivity (48%, P=0.002), which increased significantly more with the addition of CFR (58%, P≤0.001). The further addition of CAC resulted

  8. Kinetics of rubidium-82 after coronary occlusion and reperfusion. Assessment of patency and viability in open-chested dogs.

    PubMed Central

    Goldstein, R A

    1985-01-01

    Currently available noninvasive techniques are unable to rapidly assess artery patency and tissue viability during acute myocardial infarction. In prior studies, rubidium-82 (Rb-82), a short-lived positron emitter obtained from a generator, was validated as an indicator of flow with a model that included the rate constants for transfer into and out of the cell. Accordingly, in the current study, 20 open-chested dogs with experimental infarction were studied serially at base line, after coronary occlusion, and at reperfusion. Time-activity curves acquired with beta probes on the epicardial surface were used to measure flow and net transfer of rubidium. Flow decreased to 0.41 +/- 0.08 ml/min per gram during occlusion and increased to 2.73 +/- 0.56 ml/min per gram in potentially viable ischemic tissue, whereas flows were 0.32 +/- 0.08 during occlusion (P less than 0.05 vs. viable) and 1.58 ml/min per gram (P less than 0.002 vs. viable) in irreversibly injured tissue. The transfer rate constant for Rb-82, kT, at base line was +1.22 +/- 0.60 X 10(-3) s-1 and did not change significantly during occlusion in viable vs. nonviable samples (+1.41 +/- 1.27 vs. +0.93 +/- 1.51 X 10(-3) s-1, respectively), except that 4 out of 11 nonviable tissue samples had negative kTs. At reperfusion, viable myocardial samples were all positive (+1.26 +/- 1.58 X 10(-3) s-1), whereas all irreversibly injured tissues had a negative kT, indicating leakage of tracer (-1.50 +/- 1.10 X 10(-3) s-1, P less than 0.001). This study suggests that Rb-82 time-activity curves can be useful to determine patency of an infarct related artery and potential viability after reperfusion during myocardial infarction. Images PMID:3988934

  9. Effects of replacing medium sodium by choline, caesium, or rubidium, on water and ion contents of renal cortical slices

    PubMed Central

    Hughes, Pauline M.; Macknight, Anthony D. C.

    1977-01-01

    1. Renal cortical slices from rat, rabbit, and guinea-pig were incubated in media in which choline, caesium or rubidium replaced sodium. 2. Slices of rabbit and guinea-pig renal cortex incubated in oxygenated choline Ringer decreased in volume initially and did not swell over 3 hr at 25° C. There was a steady loss of potassium. Inhibition of metabolism (N2 + 1 mM iodoacetamide) caused some swelling. Ouabain, 10 mM, in choline Ringer affected neither loss of potassium nor tissue water content. 3. Slices of rat renal cortex similarly incubated in choline Ringer swelled over 3 hr at 25° C whether or not metabolism was inhibited; ouabain (15 mM) affected neither tissue potassium loss nor tissue water content. 4. Incubation in choline Ringer containing either 0·2 mM p-chloromercuribenzoic acid, or 1 mM ethacrynic acid increased the tissue water content of guinea-pig renal cortical slices. 5. Depletion of cellular potassium (by preliminary incubation in oxygenated potassium-free sodium Ringer with 10 mM ouabain at 30° C) resulted in increased tissue water content when rabbit renal cortical slices were subsequently incubated in oxygenated choline Ringer at 25° C for 3 hr. 6. There was no evidence of energy-dependent extrusion of water or ions from either equilibrated rat or rabbit renal cortical slices leached at 0·5° C and then reincubated at 25° C in choline Ringer. 7. Rat and guinea-pig renal cortical slices leached at 0.5° C and reincubated at 25° C swelled in rubidium Ringer and in caesium Ringer. There was no evidence of energy-dependent water or ion extrusion when metabolism was restored after leaching in either of these media. Metabolizing rat slices but not guinea-pig slices swelled faster than slices whose metabolism was inhibited. 8. These results lend no support to the mechano-chemical hypothesis which ascribes cellular volume regulation to a contractile mechanism squeezing isotonic extracellular fluid from the cells. Instead it is suggested that

  10. Progress toward a search for anomalous spin-mass couplings with a dual-isotope rubidium magnetometer

    NASA Astrophysics Data System (ADS)

    Valdez, Julian; Lacey, Ian; Peregrinaramirez, Rodrigo; Jackson Kimball, Derek

    2011-05-01

    We report progress in our development of a dual-isotope rubidium magnetometer to be used to search for a long-range coupling between proton spins and the mass of the Earth. The valence electron dominates magnetic interactions and serves as a precise co-magnetometer for the nuclei in a simultaneous measurement of Rb-85 and Rb-87 spin precession frequencies, enabling accurate subtraction of magnetic perturbations. Both Rb nuclei have valence protons, but in Rb-87 the proton spin is parallel to the nuclear spin and magnetic moment while for Rb-85 the proton spin is anti-parallel to the nuclear spin and magnetic moment. Thus anomalous interactions of the proton spin produce a differential shift between the Rb spin-precession frequencies, whereas many sources of systematic error produce common-mode shifts of the spin-precession frequencies which can be controlled through auxiliary measurements. We discuss significant enhancement of the sensitivity through the use of new alkene-based antirelaxation coatings, and methods to control systematic effects due to light shifts, collisions, and the gyro-compass effect. This work is supported by the National Science Foundation under grant PHY-0969666.

  11. Planar positron imaging of rubidium-82 for myocardial infarction: A comparison with thallium-201 and regional wall motion

    SciTech Connect

    Williams, K.A.; Ryan, J.W.; Resnekov, L.; Stark, V.; Peterson, E.L.; Gustafson, G.C.; Martin, W.B.; Freier, P.A.; Harper, P.V. )

    1989-09-01

    Rubidium-82 (Rb-82) is a generator-produced, short half-life (76 seconds) positron emitting potassium analog. Using a mobile gamma camera equipped with a rotating tungsten collimator and high-energy shielding, we examined the use of Rb-82 in the coronary care unit and clinical laboratory for detection of perfusion defects due to myocardial infarction. We studied 31 subjects, 10 patients with acute myocardial infarction, 12 with remote myocardial infarction, and nine controls. Rb-82 images were compared with Tl-201 and regional wall motion for detection of infarct-related arteries. Of the 22 patients with myocardial infarction, 16 were identified with Rb-82 and Tl-201. In nine control subjects, eight were normal with each method. Correlation between Rb-82 and Tl-201 defect scores was excellent. Sensitivity and specificity for infarct-related arteries were similar for Rb-82, Tl-201, and wall motion imaging. Thus planar Rb-82 imaging can detect MI reliably in the coronary care unit and in the clinical laboratory.

  12. Effect of photoions on the line shape of the Foerster resonance lines and microwave transitions in cold rubidium Rydberg atoms

    SciTech Connect

    Tretyakov, D. B.; Beterov, I. I.; Entin, V. M.; Yakshina, E. A.; Ryabtsev, I. I.; Dyubko, S. F.; Alekseev, E. A.; Pogrebnyak, N. L.; Bezuglov, N. N.; Arimondo, E.

    2012-01-15

    Experiments are carried out on the spectroscopy of the Foerster resonance lines Rb(37P) + Rb(37P) {yields} Rb(37S) + Rb(38S) and microwave transitions nP {yields} n Prime S, n Prime D between Rydberg states of cold rubidium atoms in a magneto-optical trap (MOT). Under ordinary conditions, all spectra exhibit a linewidth of 2-3 MHz irrespective of the interaction time between atoms or between atoms and microwave radiation, although the limit resonance width should be determined by the inverse interaction time. The analysis of experimental conditions has shown that the main source of line broadening is the inhomogeneous electric field of cold photoions that are generated under the excitation of initial nP Rydberg states by broadband pulsed laser radiation. The application of an additional electric-field pulse that rapidly extracts photoions produced by a laser pulse leads to a considerable narrowing of lines of microwave resonances and the Foerster resonance. Various sources of line broadening in cold Rydberg atoms are analyzed.

  13. Elements in rice on the Swedish market: part 2. Chromium, copper, iron, manganese, platinum, rubidium, selenium and zinc.

    PubMed

    Jorhem, L; Astrand, C; Sundstrom, B; Baxter, M; Stokes, P; Lewis, J; Grawe, K P

    2008-07-01

    A survey of the levels of some essential and non-essential trace elements in different types of rice available on the Swedish retail market was carried out in 2001-03. The types of rice included long and short grain, brown, white, and parboiled white. The mean levels found were: chromium (Cr) = 0.008 mg kg(-1), copper (Cu) = 1.9 mg kg(-1), iron (Fe) = 4.7 mg kg(-1), manganese (Mn) = 16 mg kg(-1), platinum (Pt) < 0.0003 mg kg(-1), rubidium (Rb) = 3.3 mg kg(-1), selenium (Se) =0.1 mg kg(-1); and zinc (Zn) = 15 mg kg(-1). Inductively coupled plasma-mass spectrometry (ICP-MS) was used for the determination of Pt, Rb, and Se, after acid digestion. All other elements were determined using atomic absorption spectrometry (AAS) after dry ashing. Intake calculations were performed and it was concluded that rice may contribute considerably to the daily requirements of the essential elements Cu, Fe, Mn, Se, and Zn if rice consumption is high. The levels of some elements, e.g. Fe and Mn, were significantly higher in brown compared with white rice.

  14. Encapsulation of ammonium molybdophosphate and zirconium phosphate in alginate matrix for the sorption of rubidium(I).

    PubMed

    Krys, Pawel; Testa, Flaviano; Trochimczuk, Andrzej; Pin, Christian; Taulemesse, Jean-Marie; Vincent, Thierry; Guibal, Eric

    2013-11-01

    Ammonium molybdophosphate and Phozir (alone or in combination) have been encapsulated in alginate beads for the synthesis of rubidium sorbents. SEM and SEM-EDX analyses confirm the homogeneity of the sorbents in terms of composition and metal binding. AMP sorbent is less sensitive to pH than Phozir, and optimum pH is close to pH 3 for the binding of Rb(I). The Langmuir equation fitted well sorption isotherms and the maximum sorption capacities were in the range 0.65-0.74 mmol Rb g(-1). The resistance to intraparticle diffusion contributes to control uptake kinetics (effect of particle size) though the presence of solid inorganic particles reduces the impact of drying alginate capsules (preventing the collapse of the porous structure during the drying step). Breakthrough curves demonstrate the potential of these sorbents for the dynamic sorption of Rb(I) while using ammonium chloride (combined to nitric acid) allows recovering Rb(I) from loaded sorbents.

  15. Highly accurate Michelson type wavelength meter that uses a rubidium stabilized 1560 nm diode laser as a wavelength reference

    SciTech Connect

    Masuda, Shin; Kanoh, Eiji; Irisawa, Akiyoshi; Niki, Shoji

    2009-08-01

    We investigated the accuracy limitation of a wavelength meter installed in a vacuum chamber to enable us to develop a highly accurate meter based on a Michelson interferometer in 1550 nm optical communication bands. We found that an error of parts per million order could not be avoided using famous wavelength compensation equations. Chromatic dispersion of the refractive index in air can almost be disregarded when a 1560 nm wavelength produced by a rubidium (Rb) stabilized distributed feedback (DFB) diode laser is used as a reference wavelength. We describe a novel dual-wavelength self-calibration scheme that maintains high accuracy of the wavelength meter. The method uses the fundamental and second-harmonic wavelengths of an Rb-stabilized DFB diode laser. Consequently, a highly accurate Michelson type wavelength meter with an absolute accuracy of 5x10{sup -8} (10 MHz, 0.08 pm) over a wide wavelength range including optical communication bands was achieved without the need for a vacuum chamber.

  16. Rubidium-traced white-light etalon calibrator for radial velocity measurements at the cm s-1 level

    NASA Astrophysics Data System (ADS)

    Stürmer, Julian; Seifahrt, Andreas; Schwab, Christian; Bean, Jacob L.

    2017-04-01

    We report on the construction and testing of a vacuum-gap Fabry-Pérot etalon calibrator for high precision radial velocity spectrographs. Our etalon is traced against a rubidium frequency standard to provide a cost effective, yet ultra precise wavelength reference. We describe here a turn-key system working at 500 to 900 nm, ready to be installed at any current and next-generation radial velocity spectrograph that requires calibration over a wide spectral bandpass. Where appropriate, we have used off-the-shelf, commercial components with demonstrated long-term performance to accelerate the development timescale of this instrument. Our system combines for the first time the advantages of passively stabilized etalons for optical and near-infrared wavelengths with the laser-locking technique demonstrated for single-mode fiber etalons. We realize uncertainties in the position of one etalon line at the 10 cm s-1 level in individual measurements taken at 4 Hz. When binning the data over 10 s, we are able to trace the etalon line with a precision of better than 3 cm s-1. We present data obtained during a week of continuous operation where we detect (and correct for) the predicted, but previously unobserved shrinking of the etalon Zerodur spacer corresponding to a shift of 13 cm s-1 per day.

  17. Measuring frequency changes due to microwave power variations as a function of C-field setting in a rubidium frequency standard

    NASA Technical Reports Server (NTRS)

    Sarosy, E. B.; Johnson, Walter A.; Karuza, Sarunas K.; Voit, Frank J.

    1992-01-01

    It has been shown in previous studies that in some cesium frequency standards there exist certain C-field settings that minimize frequency changes that are due to variations in the microwave power. In order to determine whether similar results could be obtained with rubidium (Rb) frequency standards (clocks), we performed a similar study, using a completely automated measurement system, on a commercial Rb standard. From our measurements we found that changing the microwave power to the filter cell resulted in significant changes in frequency, and that the magnitude of these frequency changes at low C-field levels went to zero and decreased as the C-field was increased.

  18. Rubidium chloride tolerant callus cultures of rice (Oryza sativa L.) accumulate more potassium and cross tolerate to other salts.

    PubMed

    Naga Amrutha, R; Jogeswar, G; Srilaxmi, P; Kavi Kishor, P B

    2007-09-01

    Callus cultures from salt tolerant (CSR-10) and susceptible (Swarnadhan) varieties of Oryza sativa L. were established in Murashige and Skoog's (MS) medium containing lethal concentrations (50 mM) of rubidium chloride (RbCl) as a selective agent. While 95-100% cells were viable in callus cultures grown without RbCl, viability was 75% in 50 mM RbCl selected cultures. Growth of RbCl selected calli in presence of salt was comparable to that of callus grown without it. Cells tolerant to RbCl showed more vacuoles and accumulated more K(+) in comparison with their corresponding controls. Suspension cultures were established and uptake of (86)Rb(+) was measured at 10 and 20 min intervals, which revealed a linear relationship between the absorption of K(+) and time. Callus cultures (560-day-old) tolerant to 50 mM RbCl regenerated shoots with 35-40% frequencies in both the varieties, but the same age-old callus grown in the medium devoid of RbCl did not show any organogenesis. Callus cultures that are tolerant to 50 mM RbCl when exposed to 25 mM LiCl, 50 mM NaCl, 50 mM KCl and 25 mM CsCl also exhibited cross tolerance in both the varieties. This is the first time that a callus line of rice resistant to RbCl was raised and shown to accumulate a major cation K(+ )and also an increased influx of it.

  19. Rubidium content in autopsy liver tissue samples from Greenlandic Inuit and Danes measured by X-ray fluorescence spectrometry.

    PubMed

    Milman, Nils; Laursen, Jens; Byg, Keld-Erik; Pedersen, Henning S; Mulvad, Gert

    2006-01-01

    The biological function of rubidium (Rb) is unknown, but this alkali metal probably has a normal biologic role. To measure the content of Rb in liver tissue samples from Greenlandic Inuit using X-ray fluorescence spectrometry, and compare the results with those obtained in liver samples from ethnic Danes. Observational, descriptive survey on environmental pathology. The setting was related to forensic medicine and hospitalised care in Nuuk, Ilulissat and Copenhagen. Normal liver tissue was obtained at autopsy from 50 Greenlandic Inuit (27 men) with a median age of 61 years (range 23-83) and from 42 Danes (31 men) with a median age of 38 years (range 16-83). Liver Rb content in Inuit was not significantly different compared with Danes. There was no significant gender difference in liver Rb content either in Inuit or in Danes. The content of Rb given as median (5-95 percentile) was 0.1837mmol/kg dry liver (0.1041-0.3147) in Inuit, and 0.1965mmol/kg dry liver (0.0799-0.2815) in Danes (p=0.6). There was an inverse correlation between liver Rb content and age in Inuit (r(s)=-0.45, p=0.002) but not in Danes. Median hepatic Rb index (Rb content in micromol/kg dry weight divided by age in years) in Inuit was 3.05 and in Danes 4.21 (p=0.02). The correlations between liver Rb and liver potassium content were: Inuit r(s)=0.28, p=0.07; Danes r(s)=0.25, p=0.08; combined series r(s)=0.34, p=0.01. Inuit have liver Rb levels, which are quite similar to the levels found in Danes. In Inuit, liver Rb content appears to decrease with age.

  20. Validation of an atomic absorption rubidium ion efflux assay for KCNQ/M-channels using the ion Channel Reader 8000.

    PubMed

    Wang, Kewei; McIlvain, Beal; Tseng, Eugene; Kowal, Dianne; Jow, Flora; Shen, Ru; Zhang, Howard; Shan, Qin Jennifer; He, Lan; Chen, Diana; Lu, Qiang; Dunlop, John

    2004-10-01

    M-channels (M-current), encoded by KCNQ2/3 K(+) channel genes, have emerged as novel drug targets for a number of neurological disorders. The lack of direct high throughput assays combined with the low throughput of conventional electrophysiology (EP) has impeded rapid screening and evaluation of K(+)-channel modulators. Development of a sensitive and efficient assay for the direct measurement of M-current activity is critical for identifying novel M-channel modulators and subsequent investigation of their therapeutic potential. Using a stable CHO cell line expressing rat KCNQ2/3 K(+) channels confirmed by EP, we have developed and validated a nonradioactive rubidium (Rb(+)) efflux assay in a 96-well plate format. The Rb(+) efflux assay directly measures the activity of functional channels by atomic absorption spectroscopy using the automated Ion Channel Reader (ICR) 8000. The stimulated Rb(+) efflux from KCNQ2/3-expressing cells was blocked by the channel blockers XE991 and linopirdine with IC(50) values of 0.15 microM and 1.3 microM, respectively. Twelve compounds identified as KCNQ2/3 openers were further assessed in this assay, and their EC(50) values were compared with those obtained with EP. A higher positive correlation coefficient between these two assays (r = 0.60) was observed than that between FlexStation membrane potential and EP assays (r = 0.23). To simplify the assay and increase the throughput, we demonstrate that EC(50) values obtained by measuring Rb(+) levels in the supernatant are as robust and consistent as those obtained from the ratio of Rb(+) in supernatant/lysate. By measuring the supernatant only, the throughput of ICR8000 in an eight-point titration is estimated to be 40 compounds per day, which is suitable for a secondary confirmation assay.

  1. Comparison of rubidium-82 positron emission tomography and thallium-201 SPECT imaging for detection of coronary artery disease

    SciTech Connect

    Stewart, R.E.; Schwaiger, M.; Molina, E.; Popma, J.; Gacioch, G.M.; Kalus, M.; Squicciarini, S.; al-Aouar, Z.R.; Schork, A.; Kuhl, D.E. )

    1991-06-15

    The diagnostic performance of rubidium-82 (Rb-82) positron emission tomography (PET) and thallium-201 (Tl-201) single-photon emission-computed tomography (SPECT) for detecting coronary artery disease was investigated in 81 patients (52 men, 29 women). PET studies using 60 mCi of Rb-82 were performed at baseline and after intravenous infusion of 0.56 mg/kg dipyridamole in conjunction with handgrip stress. Tl-201 SPECT was performed after dipyridamole-handgrip stress and, in a subset of patients, after treadmill exercise. Sensitivity, specificity and overall diagnostic accuracy were assessed using both visually and quantitatively interpreted coronary angiograms. The overall sensitivity, specificity and accuracy of PET for detection of coronary artery disease (greater than 50% diameter stenosis) were 84, 88 and 85%, respectively. In comparison, the performance of SPECT revealed a sensitivity of 84%, specificity of 53% (p less than 0.05 vs PET) and accuracy of 79%. Similar results were obtained using either visual or quantitative angiographic criteria for severity of coronary artery disease. In 43 patients without prior myocardial infarction, the sensitivity for detection of disease was 71 and 73%, respectively, similar for both PET and SPECT. There was no significant difference in diagnostic performance between imaging modalities when 2 different modes of stress (exercise treadmill vs intravenous dipyridamole plus handgrip) were used with SPECT imaging. Thus, Rb-82 PET provides improved specificity compared with Tl-201 SPECT for identifying coronary artery disease, most likely due to the higher photon energy of Rb-82 and attenuation correction provided by PET. However, post-test referral cannot be entirely excluded as a potential explanation for the lower specificity of Tl-201 SPECT.

  2. Limitation on the accelerating gradient of a wakefield excited by an ultrarelativistic electron beam in rubidium plasma

    NASA Astrophysics Data System (ADS)

    Vafaei-Najafabadi, N.; Marsh, K. A.; Clayton, C. E.; An, W.; Mori, W. B.; Joshi, C.; Lu, W.; Adli, E.; Corde, S.; Clarke, C. I.; Litos, M.; Green, S. Z.; Gessner, S.; Frederico, J.; Fisher, A. S.; Wu, Z.; Walz, D.; Hogan, M. J.

    2016-10-01

    We have investigated the viability of using plasmas formed by ionization of high Z, low ionization potential element rubidium (Rb) for beam-driven plasma wakefield acceleration. The Rb vapor column confined by argon (Ar) buffer gas was used to reduce the expected limitation on the beam propagation length due to head erosion that was observed previously when a lower Z but higher ionization potential lithium vapor was used. However, injection of electrons into the wakefield due to ionization of Ar buffer gas and nonuniform ionization of Rb1 + to Rb2 + was a possible concern. In this paper we describe experimental results and the supporting simulations which indicate that such ionization of Ar and Rb1 + in the presence of combined fields of the beam and the wakefield inside the wake does indeed occur. Some of this charge accumulates in the accelerating region of the wake leading to the reduction of the electric field—an effect known as beam loading. The beam-loading effect is quantified by determining the average transformer ratio ⟨R ⟩ which is the maximum energy gained divided by the maximum energy lost by the electrons in the bunch used to produce the wake. ⟨R ⟩ is shown to depend on the propagation length and the quantity of the accumulated charge, indicating that the distributed injection of secondary Rb electrons is the main cause of beam loading in this experiment. The average transformer ratio is reduced from 1.5 to less than 1 as the excess charge from secondary ionization increased from 100 to 700 pC. The simulations show that while the decelerating field remains constant, the accelerating field is reduced from its unloaded value of 82 to 46 GeV /m due to this distributed injection of dark current into the wake.

  3. Low-light-level nonlinear optics with rubidium atoms in hollow-core photonic band-gap fibers

    NASA Astrophysics Data System (ADS)

    Bhagwat, Amar Ramdas

    Low-light-level optical nonlinearities are of significant interest for performing operations such as single-photon switching and quantum non-demolition measurements on single-photons. To evoke strong nonlinearities from single-photons, one can enhance the matter-photon interaction using strongly nonlinear materials such as alkali vapors in combination with an appropriate geometry such as a waveguide, which provides a long interaction length while maintaining a small light mode area. We demonstrate for the first time that such a system can be experimentally realized by loading rubidium vapor inside a hollow-core photonic band-gap fiber. Using the technique of light-induced atomic desorption in this geometry, we have generated optical depths greater than 1000. As a proof of principle, we demonstrate electromagnetically induced transparency (EIT) with control powers 1000 times lower than those used for hot vapor cells in a focused beam geometry. Working with such a high aspect ratio geometry requires us to identify and measure the various sources of decoherence via spectroscopy of desorbed atoms in the fiber. Using such techniques, we also estimate the temperature of the desorbing atoms inside the fiber. The desorption mechanism is studied, and we show that pulsed desorption beams of the right amplitude and duration can be used for generating precisely controlled optical depths. Finally, we investigate the use of various buffer gas techniques for increasing the effective transverse path of the atoms as they move across the fiber in order to reduce their ground state decoherence and map this effect as a function of buffer gas pressure.

  4. Identification of X-ray spectra in the Na-like to O-like rubidium ions in the range of 3.8-7.3 Å

    NASA Astrophysics Data System (ADS)

    Denis-Petit, D.; Comet, M.; Bonnet, T.; Hannachi, F.; Gobet, F.; Tarisien, M.; Versteegen, M.; Gosselin, G.; Méot, V.; Morel, P.; Pain, J.-Ch.; Gilleron, F.; Frank, A.; Bagnoud, V.; Blazevic, A.; Dorchies, F.; Peyrusse, O.; Cayzac, W.; Roth, M.

    2014-11-01

    The X-rays emitted by a rubidium plasma source created by the PHELIX laser at an intensity of about 6×1014 W/cm2 were studied. The lines have been measured using Bragg crystals in the wavelength range between 3.8 and 7.3 Å and identified by means of a numerical method developed to describe highly charged rubidium ions in LTE plasma. The experimental plasma temperature, density and charge state distributions have been estimated using non-LTE codes such as CHIVAS and AVERROES. The LTE plasma temperature and density used in the calculations are those allowing to reproduce the calculated NLTE charge state distribution. In order to optimize the use of computational resources, a criterion is established to select the configurations contributing most to the spectra among all those obtained in detailed level accounting based on the MCDF code. Seventy Rb X-rays have been identified among which forty-nine are reported for the first time. The capabilities of our method are demonstrated by the good agreement of our identifications with previously published data when available.

  5. Myocardial metabolism of fluorodeoxyglucose compared to cell membrane integrity for the potassium analogue rubidium-82 for assessing infarct size in man by PET

    SciTech Connect

    Gould, K.L.; Yoshida, K.; Hess, M.J.; Haynie, M.; Mullani, N.; Smalling, R.W. )

    1991-01-01

    Potassium loss from damaged myocardial cells is linearly related to CPK enzyme loss reflecting extent of necrosis. The potassium analog, rubidium-82 (82Rb), is extracted after i.v. injection and retained in viable myocardium but is not trapped or washed out of necrotic regions. To compare myocardial cell metabolism with membrane dysfunction as indicators of necrosis/viability, 43 patients with evolving myocardial infarction and coronary arteriography had positron emission tomography using fluorodeoxyglucose (FDG) and the potassium analog 82Rb. Percent of heart showing FDG defects and 82Rb washout on sequential images indicating failure to retain the potassium analogue were visually assessed and quantified by automated software. Infarct size based on rubidium kinetics correlated closely with size and location on FDG images (visual r = 0.93, automated r = 0.82), suggesting that loss of cell membrane integrity for trapping the potassium analog 82Rb parallels loss of intracellular glucose metabolism, both comparable quantitative markers of myocardial necrosis/viability.

  6. Myocardial blood flow assessment with 82rubidium-PET imaging in patients with left bundle branch block

    PubMed Central

    Falcão, Andréa; Chalela, William; Giorgi, Maria Clementina; Imada, Rodrigo; Soares, José; Do Val, Renata; Oliveira, Marco Antonio; Izaki, Marisa; Filho, Roberto Kalil; Meneghetti, José C

    2015-01-01

    OBJECTIVES: Perfusion abnormalities are frequently seen in Single Photon Emission Computed Tomography (SPECT) when a left bundle branch block is present. A few studies have shown decreased coronary flow reserve in the left anterior descending territory, regardless of the presence of coronary artery disease. OBJECTIVE: We sought to investigate rubidium-82 (82Rb) positron emission tomography imaging in the assessment of myocardial blood flow and coronary flow reserve in patients with left bundle branch block. METHODS: Thirty-eight patients with left bundle branch block (GI), median age 63.5 years, 22 (58%) female, 12 with coronary artery disease (≥70%; GI-A) and 26 with no evidence of significant coronary artery disease (GI-B), underwent rest-dipyridamole stress 82Rb-positron emission tomography with absolute quantitative flow measurements using Cedars-Sinai software (mL/min/g). The relative myocardial perfusion and left ventricular ejection fraction were assessed in 17 segments. These parameters were compared with those obtained from 30 patients with normal 82Rb-positron emission tomography studies and without left bundle branch block (GII). RESULTS: Stress myocardial blood flow and coronary flow reserve were significantly lower in GI than in GII (p<0.05). The comparison of coronary flow reserve between GI-A and GI-B showed that it was different from the global coronary flow reserve (p<0.05) and the stress flow was significantly lower in the anterior than in the septal wall for both groups. Perfusion abnormalities were more prevalent in GI-A (p=0.06) and the left ventricular ejection fraction was not different between GI-A and GI-B, whereas it was lower in GI than in GII (p<0.001). CONCLUSION: The data confirm that patients with left bundle branch block had decreased myocardial blood flow and coronary flow reserve and coronary flow reserve assessed by 82Rb-positron emission tomography imaging may be useful in identifying coronary artery disease in patients with

  7. Efficiency of rubidium marking in Aedes albopictus (Diptera: Culicidae): preliminary evaluation on persistence of egg labeling, survival, and fecundity of marked female.

    PubMed

    Maciel-de-Freitas, Rafael; Gonçalves, Jaylei Monteiro; Lourenço-de-Oliveira, Ricardo

    2004-12-01

    Rubidium chloride (RbCl) has been used for the study of vector biology and behavior, although the efficacy of marking, egg production, and survivorship of marked females have been poorly studied. Four concentrations of RbCl were tested, among which 0.025 M was the best for marking Aedes albopictus: more than 80% of egg batches of females fed once with blood containing RbCl were marked; Rb-marked egg batches, interspersed with non marked ones were recovered until 61 days after a blood meal containing RbCl followed by non marked meals; RbCl was essentially detected in the abdomen of marked females, whose egg production and survivorship did not differ from non marked ones, at least in the three weeks following the Rb-marked blood meal.

  8. Theoretical study of alkali cation-benzene complexes: potential energy surfaces and binding energies with improved results for rubidium and cesium.

    PubMed

    Coletti, Cecilia; Re, Nazzareno

    2006-05-25

    High level ab initio quantum chemical calculations have been carried out on the binding of alkali metal to benzene with special attention to heavier metals for which the agreement between the most recent theoretical investigations and the experimental bond dissociation energies (BDEs) is not very good. We performed BSSE-corrected geometry optimizations employing the MP2 level of theory with large basis sets and a modified Stuttgart RSC 1997 basis set for rubidium and cesium and carried out single point energy calculations at the MP4 level, obtaining, also for the latter metals, BDE values in good agreement with the experimental results. Furthermore, in view of the development of empirical correction terms to force fields to describe cation-pi interactions, we evaluated the potential energy surface along the benzene symmetry axis and discussed the role of the BSSE correction on the accuracy of our results.

  9. Ultralow frequency Stokes and anti-Stokes Raman spectroscopy of single living cells and microparticles using a hot rubidium vapor filter.

    PubMed

    Lin, Jinda; Li, Yong-qing

    2014-01-01

    We report on ultralow frequency Stokes and anti-Stokes Raman spectroscopy of single living cells and microsized particles in an aqueous medium with a frequency shift down to 10 cm(-1) by the combination of a hot rubidium (Rb) vapor filter, a confocal pinhole, and optical trapping. A single frequency-stabilized diode laser beam at 780.2 nm is used to optically trap and excite a single living cell or microparticle, and the Rayleigh scattering light from the particle is effectively blocked with a Rb vapor cell and a confocal pinhole. Ultralow frequency Raman spectra of the trapped cells or microparticles in both Stokes and anti-Stokes regions are then measured with a single-stage CCD spectrograph.

  10. Threshold behavior in electron-transfer collisions between rubidium atoms and C2F5Cl or C2F5I molecules.

    PubMed

    Jia, Beike; Harris, Sean; Lewis, Larry L; Zhan, Jiping; Brooks, Philip R

    2005-10-20

    Rubidium atoms are accelerated in a high-temperature expansion of hydrogen to produce beams with energies high enough to observe collisional ionization with a cross beam. The speed of the atoms is directly measured by time-of-flight techniques, and the positive and negative ions produced are detected in separate mass spectrometers and detected in coincidence. Chloroperfluoroethane produces C(2)F(5)(-) and Cl(-) ions, whereas iodoperfluoroethane produces I(-), C(2)F(5)(-), and C(2)F(5)I(-) ions. When the measured speed distributions are used, the signal versus energy may be deconvolved to yield thresholds and electron affinities (EAs). The EA for C(2)F(5)I is measured to be 0.96 +/- 0.1 eV. Anomalously high EA values result for C(2)F(5) apparently because C(2)F(5)(-) is produced by parts per million concentrations of Rb(2).

  11. The Thermochemical Measurements on Rubidium Compounds: A Comparison of Measured Values with Those Predicted from the NBS Tables of Chemical and Thermodynamic Properties

    NASA Astrophysics Data System (ADS)

    Parker, V. B.; Evans, W. H.; Nuttall, R. L.

    1987-01-01

    This report presents the assessed thermochemical measurements on rubidium compounds upon which the property values, Δf H0, Δf G0, S0, C0p, and H0(T)-H0(0) at 298.15 K and Δf H0(0 K) recommended in the ``NBS Tables of Chemical Thermodynamic Properties'' are based. Included in this set of thermochemical measurements, or thermochemical reaction catalog, is a comparison of the observed values for the processes in question with those predicted (calculated) from the recommended property values in the forementioned tables. The evaluator's initially assigned uncertainties on the experimental measurements and final estimated reliabilities on the recommended process values are given. This paper illustrates the evaluation procedure used in preparing the full set of recommended data in the ``NBS Tables of Chemical Thermodynamic Properties''.

  12. Real-time measurement of temperature rise in a pulsed diode pumped rubidium vapor laser by potassium tracing atom based absorption spectroscopy.

    PubMed

    Zhao, Xiaofan; Yang, Zining; Hua, Weihong; Wang, Hongyan; Xu, Xiaojun

    2017-03-20

    In this paper, we first propose and demonstrate a novel tracing atom based absorption spectroscopy method for the real-time measurement of the temperature rise inside the pump region of a pulsed diode pumped alkali laser (DPAL). By artificially adding potassium atoms into the gain medium of an operational rubidium laser, the information of the temperature rise can be obtained from the variation of the potassium absorption signal. Some important influencing factors are studied. Typical results show that, as the pump power (2 ms duration) increases from 22 W to 92 W, the temperature rise increases from 103 K to 227 K. As the pulse duration increases from 1ms to 5 ms, the temperature rise increases from 128 K to 314 K, and the heat relaxation time increases from 3.8 ms to 8.1 ms. The method is favored for its ability for real-time detection and high sensitivity, which provides a useful way for DPAL diagnostics.

  13. Accuracy in the isotope dilution mass spectrometry of uranium in rubidium uranium sulphate Rb[sub 2]U(SO[sub 4])[sub 3

    SciTech Connect

    Ramakumar, K.L.; Jeyakumar, S.; Raman, V.A.; Gnanayyan, L.; Rao, R.; Saxena, M.K.; Kavimandan, V.D.; Jain, H.C. )

    1993-05-01

    Problems encountered in the determination of uranium in rubidium uranium sulphate (Rb[sub 2]U(SO[sub 4])[sub 3]) employing isotope dilution thermal ionization mass spectrometry (ID-TIMS) are discussed. The positive bias of 0.2 to 0.3% in the determination of uranium in Rb[sub 2]U(SO[sub 4])[sub 3] by ID-TIMS with respect to the stoichiometric composition has been resolved by modifying the chemical exchange procedures. The concentration of uranium in Rb[sub 2]U(SO[sub 4])[sub 3] could be determined with an accuracy better than 0.1% employing the HClO[sub 4] treatment for proper isotopic exchange between the spike and sample isotopes. 12 refs., 1 fig., 5 tabs.

  14. Synthesis and structural characterization of a new rubidium borosulfate, Rb{sub 5}BS{sub 4}O{sub 16}

    SciTech Connect

    Dong, Lingyun; Pan, Shilie; Wang, Ying; Yu, Hongwei; Lin, Xiaoxia; Han, Shujuan

    2015-03-15

    Highlights: • Rb{sub 5}BS{sub 4}O{sub 16} has been synthesized using (NH{sub 4}){sub 2}SO{sub 4} as a source of sulfate ions for the first time. • Zero-dimensional anion groups, [B(SO{sub 4}){sub 4}]{sup 5−}, exist in the title compound. • Spectral properties and thermal analysis of Rb{sub 5}BS{sub 4}O{sub 16} were reported. - Abstract: A new rubidium borosulfate, Rb{sub 5}BS{sub 4}O{sub 16}, has been synthesized using (NH{sub 4}){sub 2}SO{sub 4} as a source of sulfate ions for the first time. The compound crystallizes in the space group P4{sub 3}2{sub 1}2 (No. 96) of the tetragonal system with a = 10.148(4) Å, c = 16.689(14) Å, V = 1718.8(17) Å{sup 3}, and Z = 4. Zero-dimensional anion groups, [B(SO{sub 4}){sub 4}]{sup 5−}, a central BO{sub 4} tetrahedron sharing all its four vertices with neighboring sulfate tetrahedra, exist in the title compound, and then the rubidium atoms are situated in the voids of the resulting structure. The IR spectrum confirms the presence of BO{sub 4} and SO{sub 4} units. The UV–vis-NIR diffuse reflectance spectrum exhibits a band gap of about 3.99 eV. The TG-DSC analysis suggests that Rb{sub 5}BS{sub 4}O{sub 16} is an incongruent melting compound.

  15. Rubidium-strontium geochronology and plate-tectonic evolution of the southern part of the Arabian Shield

    USGS Publications Warehouse

    Fleck, Robert J.; Greenwood, W.R.; Hadley, D.G.; Anderson, R.E.; Schmidt, D.L.

    1980-01-01

    Rubidium-strontium studies of Precambrian volcanic and plutonic rocks of the Arabian Shield document an early development of the Arabian craton between 900 and 680 m.y. (million years) ago. Geologic studies indicate an island-arc environment characterized by andesitic (dioritic) magmas, volcaniclastic sedimentation, rapid deposition, and contemporaneous deformation along north or northwest-trending axes. Magmatic trends show consistent variation in both composition and geographic location as a function of age. The oldest units belong to an assemblage of basaltic strata exposed in western Saudi Arabia that yield an age of 1165:!:110 m.y. The oldest andesitic strata studied yield an age of 912:!:76 m.y. The earliest plutonic units are diorite to trondhjemite batholiths that range from 800 to 9,00 m.y. in age and ,occur along the western and southern parts of Saudi Arabia. Younger plutonic units, 680 to 750 m.y. in age, range from quartz diorite to granodiodte and become more abundant in the central and northeastern parts of the Arabian Shield. Initial 'Sr/ 86 Sr ratios for both dioritic groups range from 0.7023 to 0.7030 and average 0.7027. The absence of sialic detritus in sedimentary units and the evidence for an island-arc environment suggest the early development of the Arabian craton at a convergent plate margin between plates of oceanic lithosphere. Active subduction apparently extended from at least 900 m.y. to about 680 m.y. Subsequent to this subduction-related magmatism and tectonism, called the Hijaz tectonic cycle, the Arabian craton was sutured to the late Precambrian African plate in a collisional event. This period of orogeny, represented in Arabia and eastern Africa by the Mozambiquian or Pan-African event, extended from some time before 650 m.y. to at least 540 m.y. and perhaps 520 m.y. B.P. Although the tectonic processes of subduction and continental collision during the 900+ to 500-m.y. period require similar directions of plate convergence, the

  16. Rubidium gas cell studies

    NASA Technical Reports Server (NTRS)

    Vanier, J.

    1971-01-01

    The stability of Rb-87 optically pumped masers and Rb gas cells is examined. Descriptions are given of the technical procedures used in construction and the changes made to solve the problems encountered in the electronics of the systems.

  17. Positron-rubidium scattering

    NASA Technical Reports Server (NTRS)

    Mceachran, R. P.; Horbatsch, M.; Stauffer, A. D.

    1990-01-01

    A 5-state close-coupling calculation (5s-5p-4d-6s-6p) was carried out for positron-Rb scattering in the energy range 3.7 to 28.0 eV. In contrast to the results of similar close-coupling calculations for positron-Na and positron-K scattering the (effective) total integrated cross section has an energy dependence which is contrary to recent experimental measurements.

  18. A Portable Rubidium Fountain

    DTIC Science & Technology

    2010-11-01

    and K. Gibble, 2004, “Phase variations in microwave cavities for atomic clocks,” Metrologia , 41, 376-378. [7] S. R. Jefferts, J. H. Shirley, N...phase errors in atomic clocks,” Metrologia , 47, 534-551. 42 nd Annual Precise Time and Time Interval (PTTI) Meeting 320

  19. 47 CFR 78.115 - Modulation limits.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... remote control 78.51 Operation, Time of 78.55 Operation, Unattended 78.53 Operator and station licenses... Part 78 78.1 Q R Records of station 78.69 Remote control operation 78.51 Rules in other Parts 78.3... Contents of 78.15 Dismissal of 78.21 Objections to 78.22 Signing of 78.16 Assignment or transfer of control...

  20. Assessment of a protocol for routine simultaneous myocardial blood flow measurement and standard myocardial perfusion imaging with rubidium-82 on a high count rate positron emission tomography system.

    PubMed

    Tout, Deborah; Tonge, Christine M; Muthu, Sivakumar; Arumugam, Parthiban

    2012-11-01

    High count rate positron emission tomography (PET) systems offer the potential for accurate myocardial blood flow (MBF) quantification during first-pass dynamic imaging in conjunction with standard rubidium-82 (Rb-82) PET myocardial perfusion imaging (MPI). We investigate the feasibility of this using a Siemens Biograph mCT. Current routine clinical PET MPI is performed with 1480 MBq (40 mCi) Rb-82. Dynamic first-pass images from 217 consecutive patients were reviewed for evidence of detector saturation, indicating that count rate limits had been exceeded. Phantom acquisitions in the presence of high count rates were performed to assess the effect of detector saturation on quantitative accuracy. Accurate MBF quantification and perfusion imaging using current protocols was successful in 85% of clinical cases. Detector block saturation was observed in 15% of cases, and phantom acquisitions indicate that saturation may have an adverse effect on quantitative accuracy. Visualization of transit or pooling of Rb-82 in the vessels in the axilla was the most consistent feature when saturation occurred. Reduction of administered activity to 1110 MBq (30 mCi) and subsequent evaluation of 159 patients ensured successful MBF quantification while maintaining good diagnostic quality perfusion imaging in 99% of cases. MBF quantification and good-quality standard perfusion imaging can be performed on a high count rate PET system using a single-acquisition protocol. The administered activity requires optimization and we recommend 1110 MBq for PET MPI with a Biograph mCT.

  1. Trace analysis of doxylamine succinate in animal feed, human, urine, and wastewater by GC using a rubidium-sensitized nitrogen detector.

    PubMed

    Thompson, H C; Holder, C L; Bowman, M C

    1982-08-01

    Doxylamine succinate, a drug used as a sleep-inducing agent, an antihistamine, and in a therapeutic formulation taken by pregnant women as an antinauseant, was scheduled for toxicological evaluation as part of a structure activity relationship study, with rats and mice, because a deficiency of such data exists with regard to many antihistamines. Analytical chemical procedures that ensure proper concentration, homogeneity, and stability of the drug in dosed feed, as well as the safety of personnel and the environment, were prerequisites for the toxicological tests. GC methods using a rubidium-sensitized nitrogen detector were developed for analysis of doxylamine succinate in animal feed, human urine, and wastewater at levels as low as 1 ppm, 100 ppb, and 100 ppb, respectively. Sample extracts were cleaned up by liquid-liquid partitioning, followed by additional cleanup on a column of silica gel. Data are presented concerning the stability of the drug in animal feed, extraction efficiencies, and the use of the silica gel cleanup column to separate the caffeine interference from doxylamine in extracts of human urine. Partition values and ancillary data concerning analysis of the drug in feed, by HPLC at levels as low as 10 ppm, are also reported.

  2. Control of electronic magnetic state population via light polarization in the 5p 3/2 \\rightarrow 6p 3/2 electric quadrupole transition in atomic rubidium

    NASA Astrophysics Data System (ADS)

    Mojica-Casique, C.; Ponciano-Ojeda, F.; Hernández-Gómez, S.; López-Hernández, O.; Flores-Mijangos, J.; Ramírez-Martínez, F.; Sahagún, D.; Jáuregui, R.; Jiménez-Mier, J.

    2017-01-01

    Doppler-free optical double-resonance spectroscopy is used to study the 5{s}1/2\\to 5{p}3/2\\to 6{p}3/2 excitation sequence in room-temperature rubidium atoms. This involves a 5{s}1/2\\to 5{p}3/2 electric dipole preparation step followed by the 5{p}3/2\\to 6{p}3/2 electric quadrupole excitation. A detailed experimental and theoretical study of the dependance on the excitation beams polarization from the 420 nm decay fluorescence (6{p}3/2\\to 5{s}1/2) is presented. When a circularly polarized preparation beam is used, it produces a strongly oriented 5{p}3/2 intermediate state. In this case a linear quadrupole excitation beam transfers the oriented state to the 6{p}3/2 hyperfine states. For linearly polarized preparation and quadrupole excitation beams the spectra of the 6{p}3/2 hyperfine lines follow a cosine squared dependence on the angle between the polarization directions. As a consequence, it is shown that the choice of polarization configuration allows direct use of the electric quadrupole transition selection rules to control the populations of the 6{p}3/2 hyperfine magnetic sublevels in the absence of external fields. This is achieved by independently enhancing or suppressing either {{Δ }}{M}F=+/- 1 or ±2 electric quadrupole transitions.

  3. The action of acetylcholine and other drugs on the efflux of potassium and rubidium from smooth muscle of the guinea-pig intestine

    PubMed Central

    Burgen, A S V; Spero, L

    1997-01-01

    A method is described for measuring continuously the efflux of potassium or rubidium from smooth muscle of the guinea-pig. Muscarinic drugs cause at maximum a 100-fold increase in the efflux rate, due to a direct increase in permeability and only to a minor extent secondary to depolarization. With acetylcholine the dose response curve for producing efflux is displaced to 1,000 times higher concentrations than that for contraction. The shift varies with different agonists. The efflux and contractile responses to agonists are antagonized to an equivalent extent by atropine and several other reversible antagonists but benzhexol has a relatively greater effect on efflux. An estimate of spare receptors was obtained with benzilylcholine mustard and was similar for both responses. Dibenamine and local anaesthetics led to a parallel shift of the contraction dose response curve but a depression without shift in the efflux response. The most satisfactory explanation of these results is that there are two types of the muscarinic receptor in the smooth muscle of the guinea-pig intestine. PMID:9142413

  4. Coherent excitation of the 5D{sub 5/2} level of ultra-cold rubidium atoms with short laser pulses

    SciTech Connect

    Snigirev, S A; Golovizin, A A; Vishnyakova, G A; Akimov, A V; Sorokin, V N; Kolachevskii, N N

    2012-08-31

    We demonstrate the use of stimulated Raman adiabatic passage (STIRAP) for population transfer from the ground state to the 5D{sub 5/2} level (5S{sub 1/2} {yields} 5P{sub 3/2} {yields} 5D{sub 5/2}) in laser-cooled {sup 87}Rb atoms and examine the influence of the time delay between laser pulses, pulse height, pulse duration and frequency detuning from resonance on the efficiency of Rb atom excitation to the 5D{sub 5/2} level. In our experiments, the pulse duration was varied widely (30 - 200 ns), which allowed us to assess the effect of spontaneous decay on the population of the 5D{sub 5/2} level (natural lifetime, 300 ns). We performed numerical calculations with allowance for spontaneous decay from the 5P{sub 3/2} and 5D{sub 5/2} levels and compared the results to experimental data, which allowed the population of the 5D{sub 5/2} level to be determined. The maximum population of the 5D{sub 5/2} level in the region under excitation was 80 % of the total number of rubidium atoms. (cooling of atoms)

  5. A novel assay of cell rubidium uptake using graphite furnace atomic absorption: application to rats on a magnesium-deficient diet.

    PubMed

    Zhen, Yueying; Franz, Kay B; Graves, Steven W

    2005-05-01

    The [Na,K]ATPase or sodium pump (SP) is a ubiquitous membrane cation transport system. Because of its potential participation in the pathophysiology of essential hypertension and cataract formation, the SP is under active investigation to detail its function and control. In this paper, we describe a novel, nonradioactive method of measuring SP ion transport activity in intact red blood cells (RBCs) using graphite furnace atomic absorption measurement of rubidium ion (Rb) uptake. This method provided sensitivity comparable to radioactive techniques, as assessed by experiments with human red blood cells (RBC) and ouabain, a known SP inhibitor, but this analytical approach eliminates the use of radioisotopes common to other Rb uptake assay methods. As a demonstration of its broader utility, the assay was used to assess the effects of dietary magnesium intake on SP-mediated ion transport in the RBCs of diet-controlled rats. Rats on 7 weeks of a magnesium-deficient (MgD) diet showed significant reductions in serum magnesium concentration, although levels remained in the lower region of the reference interval for healthy, magnesium replete animals. Red cell Rb uptake was significantly reduced in cells from the magnesium-restricted animals, demonstrating the sensitivity of Rb uptake to reduced magnesium intake, despite serum levels that fell within the reported normal range, and the utility of this Rb uptake assay in measuring physiological changes in SP function.

  6. Pyroelectric Properties of Potassium and Rubidium Titanyl-Arsenate Single Crystals in the Temperature Range of 4.2-300 K

    SciTech Connect

    Shaldin, Yu. V.; Matyjasik, S.; Novikova, N. E.; Tseitlin, M.; Mozhaev, E.; Roth, M.

    2010-11-15

    The temperature dependences of the pyroelectric coefficients of KTiOAsO{sub 4} and RbTiOAsO{sub 4} single crystals grown by flux crystallization have been investigated in the temperature range of 4.2-300 K. With an increase in temperature, superionic conductivity first arises in KTiOAsO4 (at T > 200 K) and then (at T > 270 K) in RbTiOAsO{sub 4}. This conductivity is much higher in the samples polarized at T = 4.2 K. An exponential change in the crystal resistivity along the polar direction is simultaneously observed. The results of measurements in the range of 4.2-200 K indicate larger values of pyroelectric coefficients when compared with potassium and rubidium titanyl-phosphate crystals. A correlation between the pyroelectric coefficients and a change in the lattice constants at isomorphic substitutions of K atoms for Rb and P atoms for As has been revealed within the symmetry approach.

  7. Non-isothermal kinetics of the dehydration reaction of 3-nitro-1,2,4-triazol-5-one rubidium and cesium complexes.

    PubMed

    Ma, Haixia; Song, Jirong; Xiao, Heming; Hu, Rongzu; Wang, Huali; Jin, Penggang; Wang, Yuan

    2006-02-06

    3-Nitro-1,2,4-triazol-5-one (NTO) rubidium and cesium complexes were synthesized by mixing the aqueous solution of NTO and their respective metal carbonates. Their thermal decomposition and the non-isothermal kinetics of the dehydration reaction were studied under the non-isothermal condition by DSC and TG-DTG methods. The kinetic parameters were obtained from analysis of the DSC and TG-DTG curves by Kissinger method, Ozawa method, the differential method and the integral method. The most probable mechanism functions for the dehydration reaction of the title complexes were suggested by comparing the kinetic parameters. The dehydration decomposition reaction of RbNTO.H2O and CsNTO.H2O appears to be the same as Avrami-Erofeev equation: f(alpha) = (5/2)(1-alpha)[-ln(1-alpha)](3/5), G(alpha)=[-ln(1-alpha)](2/5), n = 2/5. The critical temperature of thermal explosion is 240.88 degrees C for RbNTO.H2O and 246.27 degrees C for CsNTO.H2O.

  8. Accidental Conical Intersections in Mixed Trimers of Potassium and Rubidium: a Vibronic Analysis of the 4^4B_2 and 3^4A_1 States

    NASA Astrophysics Data System (ADS)

    Hauser, A. W.; Auböck, G.; Callegari, C.; Ernst, W. E.

    2010-06-01

    We compare the 3^4A_1 and 4^4B_2 states of homonuclear and heteronuclear alkali trimers formed of potassium and rubidium. The Multireference Rayleigh Schrödinger Perturbation Theory of second order is applied to obtain the corresponding adiabatic potential energy surfaces. In the case of homonuclear trimers these pairs of states correspond to the two branches of the E×{}e Jahn-Teller distorted 2^4E^' state. For heteronuclear trimers, the vibrational modes Q_x and Q_y are no longer degenerate, but the two electronic states still show a conical intersection at obtuse (KRb_2) or acute (K_2Rb) isosceles geometries. Spectroscopic consequences of this situation are discussed, vibronic spectra are predicted and compared to LIF spectra obtained in helium droplet isolation spectroscopy experiments of our group. J. Nagl, G. Auböck, A.W. Hauser, O. Allard, C. Callegari and W.E. Ernst, Phys. Rev. Lett. 100, 063001 (2008) J. Nagl, G. Auböck, A.W. Hauser, O. Allard, C. Callegari and W.E. Ernst, J. Chem. Phys. 128, 154320 (2008)

  9. A partial proton transfer in hydrogen bond O-H···O in crystals of anhydrous potassium and rubidium complex chloranilates.

    PubMed

    Biliškov, Nikola; Kojić-Prodić, Biserka; Mali, Gregor; Molčanov, Krešimir; Stare, Jernej

    2011-04-14

    Hydrogen bonding and proton transfer in the solid state are studied on the crystals of isostructural anhydrous potassium and rubidium complex chloranilates by variable-temperature single crystal X-ray diffraction, solid state (1)H NMR and IR spectroscopies, and periodic DFT calculations of equilibrium geometries, proton potentials, and NMR chemical shifts. Their crystal structures reveal neutral molecules of chloranilic acid and its dianions connected into a chain by O-H···O hydrogen bond. A strong hydrogen bond with a large-amplitude movement of the proton with NMR shift of 13-17 ppm and a broad continuum in IR spectra between 1000 and 500 cm(-1) were observed. Periodic DFT calculations suggest that proton transfer is energetically more favorable if it occurs within a single pair of chloranilate dianion and chloranilic acid molecule but not continuously along the chains of long periodicity. The calculated chemical shifts confirm the assumption that the weak resonance signals observed at lower magnetic fields pertain to the case when the proton migrates to the acceptor side of the hydrogen bond. The detected situation can be described by a partial proton transfer.

  10. Trace analysis of doxylamine succinate in animal feed, human urine, and wastewater by GC using a rubidium-sensitized nitrogen detector

    SciTech Connect

    Thompson, H.C. Jr.; Holder, C.L.; Bowman, M.C.

    1982-08-01

    Doxylamine succinate, a drug used as a sleep-inducing agent, an antihistamine, and in a therapeutic formulation taken by pregnant women as an antinauseant, was scheduled for toxicological evaluation as part of a structure activity relationship study, with rats and mice, because a deficiency of such data exists with regard to many antihistamines. Analytical chemical procedures that ensure proper concentration, homogeneity, and stability of the drug in dosed feed, as well as the safety of personnel and the environment, were prerequisites for the toxicological tests. GC methods using a rubidium-sensitized nitrogen detector were developed for analysis of doxylamine succinate in animal feed, human urine, and wastewater at levels as low as 1 ppm, 100 ppb, and 100 ppb, respectively. Sample extracts were cleaned up by liquid-liquid partitioning, followed by additional cleanup on a column of silica gel. Data are presented concerning the stability of the drug in animal feed, extraction efficiencies, and the use of the silica gel cleanup column to separate the caffeine interference from doxylamine in extracts of human urine. Partition values and ancillary data concerning analysis of the drug in feed, by HPLC at levels as low as 10 ppm, are also reported.

  11. Atomic and electronic structures of rubidium adsorption on Si(001)(2 x 1) surface: Comparison with Cs/Si(001) surface

    SciTech Connect

    Xiao, H Y.; Zu, Xiaotao; Zhang, Yanfeng; Gao, Fei

    2006-04-21

    First-principles calculations based on DFT-GGA method have been performed on rubidium adsorption on Si(001)(2?1) surface. The atomic and electronic structures of Si(001)(2?1)-Rb have been calculated and compared with those of Cs adsorption (J.Chem. Phys.122 (2005) 174704). It turns out that the saturation coverage of Rb is one monolayer rather than half a monolayer, similar to that of Cs adsorption. Comparison of Rb on Si(001)(2?1) with Cs adsorption showed that at saturation coverage larger alkali metal (AM) atom leads to stronger AM-AM interaction and weaker AM-Si interaction. However, for low coverage of 0.25 and 0.5 ML the Rb-Si interaction is surprisingly weaker than Cs-Si interaction. Further detailed analysis suggested that this is a consequence of depolarization effect with decreasing AM size below 1 ML coverage. For the saturation coverage the dispersion curves show that the surface is of semi-conducting character. This result does not support the direct and inverse angle-resolved photoemission investigation where a metallization is observed at saturation coverage.

  12. Enthalpies of the dissolution and dilution of aqueous solutions of rubidium and cesium diclofenac at 293.15-318.15 K

    NASA Astrophysics Data System (ADS)

    Manin, N. G.; Perlovich, G. L.; Fini, A.

    2014-03-01

    Enthalpies of the dissolution and dilution of aqueous solutions of rubidium and cesium diclofenac (RbDC and CsDC) are measured at 293.15, 298.15, 308.15, and 318.15 K at concentrations of water of less than 0.1 mol/kg. The heat capacity of RbDC and CsDC crystal salts is determined. Changes in the thermodynamic properties of both a solution and its components vs. concentration and temperature is considered. An increase in the endothermicity of the dissolution of RbDC and CsDC with a rise in temperature is noted. It is shown that the dissolution of both RbDC and CsDC electrolytes in water is determined by the contribution from entropy. It is shown that in aqueous solutions of RbDC and CsDC, the degree of binding of water molecules is higher than in pure water at temperatures below 303.15 K.

  13. Cessna UC-78 Bobcat

    NASA Technical Reports Server (NTRS)

    1944-01-01

    Cessna UC-78 Bobcat: Known by some as the 'Double-breasted Cub, ' the Cessna UC-78 Bobcat was the Cessna model T-50 produced for the Air Corps during World War II as a light personnel transport. Versions were also ordered to train pilots on multi-engine aircraft. This example served with the NACA at Langley from the summer 1944 until summer 1945.

  14. Observing and preventing rubidium runaway in a direct-infusion xenon-spin hyperpolarizer optimized for high-resolution hyper-CEST (chemical exchange saturation transfer using hyperpolarized nuclei) NMR.

    PubMed

    Witte, C; Kunth, M; Rossella, F; Schröder, L

    2014-02-28

    Xenon is well known to undergo host-guest interactions with proteins and synthetic molecules. As xenon can also be hyperpolarized by spin exchange optical pumping, allowing the investigation of highly dilute systems, it makes an ideal nuclear magnetic resonance probe for such host molecules. The utility of xenon as a probe can be further improved using Chemical Exchange Saturation Transfer using hyperpolarized nuclei (Hyper-CEST), but for highly accurate experiments requires a polarizer and xenon infusion system optimized for such measurements. We present the design of a hyperpolarizer and xenon infusion system specifically designed to meet the requirements of Hyper-CEST measurements. One key element of this design is preventing rubidium runaway, a chain reaction induced by laser heating that prevents efficient utilization of high photon densities. Using thermocouples positioned along the pumping cell we identify the sources of heating and conditions for rubidium runaway to occur. We then demonstrate the effectiveness of actively cooling the optical cell to prevent rubidium runaway in a compact setup. This results in a 2-3-fold higher polarization than without cooling, allowing us to achieve a polarization of 25% at continuous flow rates of 9 ml/min of (129)Xe. The simplicity of this design also allows it to be retrofitted to many existing polarizers. Combined with a direction infusion system that reduces shot-to-shot noise down to 0.56% we have captured Hyper-CEST spectra in unprecedented detail, allowing us to completely resolve peaks separated by just 1.62 ppm. Due to its high polarization and excellent stability, our design allows the comparison of underlying theories of host-guest systems with experiment at low concentrations, something extremely difficult with previous polarizers.

  15. Observing and preventing rubidium runaway in a direct-infusion xenon-spin hyperpolarizer optimized for high-resolution hyper-CEST (chemical exchange saturation transfer using hyperpolarized nuclei) NMR

    SciTech Connect

    Witte, C.; Kunth, M.; Rossella, F.; Schröder, L.

    2014-02-28

    Xenon is well known to undergo host-guest interactions with proteins and synthetic molecules. As xenon can also be hyperpolarized by spin exchange optical pumping, allowing the investigation of highly dilute systems, it makes an ideal nuclear magnetic resonance probe for such host molecules. The utility of xenon as a probe can be further improved using Chemical Exchange Saturation Transfer using hyperpolarized nuclei (Hyper-CEST), but for highly accurate experiments requires a polarizer and xenon infusion system optimized for such measurements. We present the design of a hyperpolarizer and xenon infusion system specifically designed to meet the requirements of Hyper-CEST measurements. One key element of this design is preventing rubidium runaway, a chain reaction induced by laser heating that prevents efficient utilization of high photon densities. Using thermocouples positioned along the pumping cell we identify the sources of heating and conditions for rubidium runaway to occur. We then demonstrate the effectiveness of actively cooling the optical cell to prevent rubidium runaway in a compact setup. This results in a 2–3-fold higher polarization than without cooling, allowing us to achieve a polarization of 25% at continuous flow rates of 9 ml/min of {sup 129}Xe. The simplicity of this design also allows it to be retrofitted to many existing polarizers. Combined with a direction infusion system that reduces shot-to-shot noise down to 0.56% we have captured Hyper-CEST spectra in unprecedented detail, allowing us to completely resolve peaks separated by just 1.62 ppm. Due to its high polarization and excellent stability, our design allows the comparison of underlying theories of host-guest systems with experiment at low concentrations, something extremely difficult with previous polarizers.

  16. Observing and preventing rubidium runaway in a direct-infusion xenon-spin hyperpolarizer optimized for high-resolution hyper-CEST (chemical exchange saturation transfer using hyperpolarized nuclei) NMR

    NASA Astrophysics Data System (ADS)

    Witte, C.; Kunth, M.; Rossella, F.; Schröder, L.

    2014-02-01

    Xenon is well known to undergo host-guest interactions with proteins and synthetic molecules. As xenon can also be hyperpolarized by spin exchange optical pumping, allowing the investigation of highly dilute systems, it makes an ideal nuclear magnetic resonance probe for such host molecules. The utility of xenon as a probe can be further improved using Chemical Exchange Saturation Transfer using hyperpolarized nuclei (Hyper-CEST), but for highly accurate experiments requires a polarizer and xenon infusion system optimized for such measurements. We present the design of a hyperpolarizer and xenon infusion system specifically designed to meet the requirements of Hyper-CEST measurements. One key element of this design is preventing rubidium runaway, a chain reaction induced by laser heating that prevents efficient utilization of high photon densities. Using thermocouples positioned along the pumping cell we identify the sources of heating and conditions for rubidium runaway to occur. We then demonstrate the effectiveness of actively cooling the optical cell to prevent rubidium runaway in a compact setup. This results in a 2-3-fold higher polarization than without cooling, allowing us to achieve a polarization of 25% at continuous flow rates of 9 ml/min of 129Xe. The simplicity of this design also allows it to be retrofitted to many existing polarizers. Combined with a direction infusion system that reduces shot-to-shot noise down to 0.56% we have captured Hyper-CEST spectra in unprecedented detail, allowing us to completely resolve peaks separated by just 1.62 ppm. Due to its high polarization and excellent stability, our design allows the comparison of underlying theories of host-guest systems with experiment at low concentrations, something extremely difficult with previous polarizers.

  17. EPR and ENDOR studies of point defects in the nonlinear optical crystals rubidium titanium oxide phosphate and potassium titanium oxide arsenate

    NASA Astrophysics Data System (ADS)

    Jiang, Yongquan

    Four studies of point defects RbTiOPO4 and KTiOAsO4 crystals are described in this dissertation. In the first study, electron paramagnetic resonance (EPR) and electronnuclear double resonance (ENDOR) are used to characterize the complex hyperfine patterns exhibited by the primary radiation-induced trapped hole center in single crystals of RbTiOPO4 (commonly referred to as RTP). These defects are produced at 77 K by irradiating with x rays, and they are destroyed by raising the temperature above approximately 170 K. In this center, the hole resides on a bridging oxygen ion located between two titanium ions and is stabilized by a nearby rubidium vacancy. Hyperfine splittings from interactions with one rubidium neighbor and one phosphorus neighbor are resolved in the EPR spectra. The ENDOR spectra show one larger phosphorus interaction and four smaller phosphorus interactions. Principal values and principal axis directions for this larger phosphorus interaction are obtained from the ENDOR angular dependence. In the second study, the dominant Ti3+ trapped electron center in flux-grown RbTiOPO4 crystals is characterized using EPR and ENDOR. This center is produced during an x-ray irradiation at room temperature when a Ti4+ ion traps an electron and becomes a Ti3+ ion, and it is best studied in the 30 to 40 K range. The EPR spectrum contains a three-line hyperfine pattern from two nearly equivalent neighboring 31P nuclei, along with hyperfine lines from the 47,49Ti nuclei. The g matrix, determined from the angular dependence of the EPR spectrum, has principal values of 1.819, 1.889, and 1.947. Hyperfine matrices for four 31P nuclei are obtained from the angular dependence of the ENDOR spectrum (two of these are resolved in the EPR spectrum). The proposed model for this defect is a Ti3+ ion adjacent to an oxygen vacancy. Analogies are made to a similar Ti3+ center in KTiOPO4 (KTP) crystals. In the third study, the primary trapped hole and trapped electron centers in

  18. Conversion of bright magneto-optical resonances into dark resonances at fixed laser frequency for D2 excitation of atomic rubidium

    NASA Astrophysics Data System (ADS)

    Auzinsh, M.; Berzins, A.; Ferber, R.; Gahbauer, F.; Kalvans, L.; Mozers, A.; Opalevs, D.

    2012-03-01

    Nonlinear magneto-optical resonances on the hyperfine transitions belonging to the D2 line of rubidium were changed from bright to dark resonances by changing the laser power density of the single exciting laser field or by changing the vapor temperature in the cell. In one set of experiments atoms were excited by linearly polarized light from an extended cavity diode laser with polarization vector perpendicular to the light's propagation direction and magnetic field, and laser-induced fluorescence was observed along the direction of the magnetic field, which was scanned. A low-contrast bright resonance was observed at low laser power densities when the laser was tuned to the Fg=2→Fe=3 transition of 87Rb and near to the Fg=3→Fe=4 transition of 85Rb. The bright resonance became dark as the laser power density was increased above 0.6 mW/cm2 or 0.8 mW/cm2, respectively. When the Fg=2→Fe=3 transition of 87Rb was excited with circularly polarized light in a second set of experiments, a bright resonance was observed, which became dark when the temperature was increased to around 50∘C. The experimental observations at room temperature could be reproduced with good agreement by calculations based on a theoretical model, although the theoretical model was not able to describe measurements at elevated temperatures, where reabsorption was thought to play a decisive role. The model was derived from the optical Bloch equations and included all nearby hyperfine components, averaging over the Doppler profile, mixing of magnetic sublevels in the external magnetic field, and a treatment of the coherence properties of the exciting radiation field.

  19. Correlations between potassium, rubidium and cesium ((133)Cs and (137)Cs) in sporocarps of Suillus variegatus in a Swedish boreal forest.

    PubMed

    Vinichuk, M; Rosén, K; Johanson, K J; Dahlberg, A

    2011-04-01

    An analysis of sporocarps of ectomycorrhizal fungi Suillus variegatus assessed whether cesium ((133)Cs and (137)Cs) uptake was correlated with potassium (K) or rubidium (Rb) uptake. The question was whether intraspecific correlations of Rb, K and (133)Cs mass concentrations with (137)Cs activity concentrations in sporocarps were higher within, rather than among, different fungal species, and if genotypic origin of sporocarps within a population affected uptake and correlation. Sporocarps (n = 51) from a Swedish forest population affected by the fallout after the Chernobyl accident were studied. The concentrations were 31.9 ± 6.79 g kg(-1) for K (mean ± SD, dwt), 0.40 ± 0.09 g kg(-1) for Rb, 8.7 ± 4.36 mg kg(-1) for (133)Cs and 63.7 ± 24.2 kBq kg(-1) for (137)Cs. The mass concentrations of (133)Cs correlated with (137)Cs activity concentrations (r = 0.61). There was correlation between both (133)Cs concentrations (r = 0.75) and (137)Cs activity concentrations (r = 0.44) and Rb, but the (137)Cs/(133)Cs isotopic ratio negatively correlated with Rb concentration. Concentrations of K and Rb were weakly correlated (r = 0.51). The (133)Cs mass concentrations, (137)Cs activity concentrations and (137)Cs/(133)Cs isotopic ratios did not correlate with K concentrations. No differences between, within or, among genotypes in S. variegatus were found. This suggested the relationships between K, Rb, (133)Cs and (137)Cs in sporocarps of S. variegatus is similar to other fungal species. Copyright © 2011 Elsevier Ltd. All rights reserved.

  20. Quantification of myocardial perfusion using cardiac magnetic resonance imaging correlates significantly to rubidium-82 positron emission tomography in patients with severe coronary artery disease: a preliminary study.

    PubMed

    Qayyum, Abbas A; Hasbak, Philip; Larsson, Henrik B W; Christensen, Thomas E; Ghotbi, Adam A; Mathiasen, Anders B; Vejlstrup, Niels G; Kjaer, Andreas; Kastrup, Jens

    2014-07-01

    Aim was to compare absolute myocardial perfusion using cardiac magnetic resonance imaging (CMRI) based on Tikhonov's procedure of deconvolution and rubidium-82 positron emission tomography (Rb-82 PET). Fourteen patients with coronary artery stenosis underwent rest and adenosine stress imaging by 1.5-Tesla MR Scanner and a mCT/PET 64-slice Scanner. CMRI were analyzed based on Tikhonov's procedure of deconvolution without specifying an explicit compartment model using our own software. PET images were analyzed using standard clinical software. CMRI and PET data was compared with Spearman's rho and Bland-Altman analysis. CMRI results were strongly and significantly correlated with PET results for the absolute global myocardial perfusion differences (r=0.805, p=0.001) and for global myocardial perfusion reserve (MPR) (r=0.886, p<0.001). At vessel territorial level, CMRI results were also significantly correlated with absolute PET myocardial perfusion differences (r=0.737, p<0.001) and MPR (r=0.818, p<0.001). Each vessel territory had similar strong correlation for absolute myocardial perfusion differences (right coronary artery (RCA): r=0.787, p=0.001; left anterior descending artery (LAD): r=0.796, p=0.001; left circumflex artery (LCX): r=0.880, p<0.001) and for MPR (RCA: r=0.895, p<0.001; LAD: r=0.886, p<0.001; LCX: r=0.886, p<0.001). On a global and vessel territorial basis, CMRI-measured absolute myocardial perfusion differences and MPR were strongly and significantly correlated with the Rb-82 PET findings. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

  1. Accumulation of potassium, rubidium and caesium (133Cs and 137Cs in various fractions of soil and fungi in a Swedish forest.

    PubMed

    Vinichuk, M; Taylor, A F S; Rosén, K; Johanson, K J

    2010-05-15

    Radiocaesium ((137)Cs) was widely deposited over large areas of forest in Sweden as a result of the Chernobyl accident in 1986 and many people in Sweden eat wild fungi and game obtained from these contaminated forests. In terms of radioisotope accumulation in the food chain, it is well known that fungal sporocarps efficiently accumulate radiocaesium ((137)Cs), as well as the alkali metals potassium (K), rubidium (Rb) and caesium (Cs). The fungi then enhance uptake of these elements into host plants. This study compared the accumulation of these three alkali metals in bulk soil, rhizosphere, soil-root interface, fungal mycelium and sporocarps of mycorrhizal fungi in a Swedish forest. The soil-root interface was found to be distinctly enriched in K and Rb compared with the bulk soil. Potassium concentrations increased in the order: bulk soil

  2. Normal Myocardial Flow Reserve in HIV-Infected Patients on Stable Antiretroviral Therapy: A Cross-Sectional Study Using Rubidium-82 PET/CT.

    PubMed

    Knudsen, Andreas; Christensen, Thomas E; Ghotbi, Adam Ali; Hasbak, Philip; Lebech, Anne-Mette; Kjær, Andreas; Ripa, Rasmus Sejersten

    2015-10-01

    Studies have found HIV-infected patients to be at increased risk of myocardial infarction, which may be caused by coronary microvascular dysfunction. For the first time among HIV-infected patients, we assessed the myocardial flow reserve (MFR) by Rubidium-82 (82Rb) positron emission tomography (PET), which can quantify the coronary microvascular function. MFR has proved highly predictive of future coronary artery disease and cardiovascular events in the general population.In a prospective cross-sectional study, HIV-infected patients all receiving antiretroviral therapy (ART) with full viral suppression and HIV-uninfected controls were scanned using 82Rb PET/computed tomography at rest and adenosine-induced stress, thereby obtaining the MFR (stress flow/rest flow), stratified into low ≤1.5, borderline >1.5 to 2.0, or normal >2.0.Fifty-six HIV-infected patients and 25 controls were included. The HIV-infected patients had a mean age of 53 years (range 37-68 years) with 23% active smokers. The controls had a mean age of 52 years (range 36-68 years) and 26% active smokers. In the HIV-infected group 73% had a normal MFR, 17% borderline, and 10% low values of MFR. Among controls these values were 71%, 19%, and 10%, respectively (P = 0.99). However, the HIV-infected group had lower values of stress myocardial blood flow (MBF) (2.63 ± 0.09 mL/g/min vs 2.99 ± 0.14 mL/g/min; P = 0.03). We found no evidence of decreased MFR as assessed by 82Rb PET among HIV-infected patients on stable ART with full viral suppression compared with HIV-uninfected controls. We did notice a decreased MBF during stress.

  3. Testing of conductivity/calcium and rubidium/strontium ratios as indicators of the chemical stability of a river: comparison with a biological indicator.

    PubMed

    Nirel, P M V; Lazzarotto, J

    2005-01-01

    It is customary to detect pollution in a water flow by monitoring the increase of sensitive elements concentrations (NH4+, PO4(3-), NO3-...). However, concentrations are dependent on the flow rate and these compounds are not conservative, implying a concentration decrease downstream leading to false negative diagnosis of pollution impact. The use of elemental ratios of conservative compounds should diminish these pitfalls. We then thought of the chi/Ca (conductivity/calcium) and Rb/Sr (rubidium/strontium) ratios as water chemical stability indicators to clearly identify and discriminate point from diffuse pollutions. This hypothesis has been tested on 12 brooks located in the basin of Lake Geneva, during 2 hydrological years. The results were compared to the observed land use of the watershed and a biological indicator: the Pollution Sensitivity Index (PSI). The PSI is calculated from diatom taxonomy and evaluates biological quality with a grade ranging from 0 to 20 (bad to excellent). The main results of the research can be summarized as follows. The pollution signal is observable far downstream of the pollution site. Both chi/Ca and Rb/Sr ratios are water quality indicators expressing the stability of water chemistry. They can both be used to detect diffuse and point pollution impact. These indicators provide complementary information: chi/Ca variations increase in case of point pollution; Rb/Sr variations increase when diffuse pollutions occur. The results obtained with the indicators chi/Ca and Rb/Sr agree with biological indicator and observation of the land use. chi/Ca and Rb/Sr ratios represent important tools to identify and discriminate point source pollution from diffuse pollution.

  4. Crystal structures of the potassium and rubidium salts of (3,5-di-chloro-phen-oxy)acetic acid: two isotypic coordination polymers.

    PubMed

    Smith, Graham

    2015-10-01

    The two-dimensional coordination polymeric structures of the hydrated potassium and rubidium salts of (3,5-di-chloro-phen-oxy)acetic acid (3,5-D), namely, poly[μ-aqua-bis-[μ3-2-(3,5-di-chloro-phen-oxy)acetato]-dipotassium], [K2(C8H5Cl2O3)2(H2O)] n , and poly[μ-aqua-bis-[μ3-2-(3,5-di-chloro-phen-oxy)acetato]-dirubidium], [Rb2(C8H5Cl2O3)2(H2O)] n , respectively, have been determined and are described. The two compounds are isotypic and the polymeric structure is based on centrosymmetric dinuclear bridged complex units. The irregular six-coordination about the alkali cations comprises a bridging water mol-ecule lying on a twofold rotation axis, the phen-oxy O-atom donor and a triple bridging carboxyl-ate O atom of the oxo-acetate side chain of the 3,5-D ligand, and the second carb-oxy-ate O-atom donor also bridging. The K-O and Rb-O bond-length ranges are 2.7238 (15)-2.9459 (14) and 2.832 (2)-3.050 (2) Å, respectively, and the K⋯K and Rb⋯Rb separations in the dinuclear units are 4.0214 (7) and 4.1289 (6) Å, respectively. Within the layers which lie parallel to (100), the coordinating water mol-ecule forms an O-H⋯O hydrogen bond to the single bridging carboxyl-ate O atom.

  5. 47 CFR Alphabetical Index - Part 78

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Part 78 Index Alphabetical Index... SERVICE Technical Regulations Modulation limits. Pt. 78, Index Alphabetical Index—Part 78 A Antenna... Changes in equipment 78.109 Conditions for license 78.27 Coordination, frequencies 78.36 Cross reference...

  6. 47 CFR 78.115 - Modulation limits.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false Modulation limits. 78.115 Section 78.115... SERVICE Technical Regulations § 78.115 Modulation limits. (a) If amplitude modulation is employed... maintenance of towers 78.63 Limitations, Power 78.101 Limits of modulation 78.115 M Maintenance and lighting...

  7. Large volume injection in ion chromatography Separation of rubidium and strontium for on-line inductively coupled plasma mass spectrometry determination of strontium isotope ratios.

    PubMed

    García-Ruiz, Silvia; Moldovan, Mariella; García Alonso, J Ignacio

    2007-05-18

    Large volume injection, up to 5 mL, was evaluated and optimised for the on-line ion chromatographic separation of Rb and Sr before ICP-MS measurement of Sr isotope ratios. Flat-topped chromatographic peaks, ideally suited for multicollector ICP-MS isotope ratio measurements, could be obtained when the composition of the mobile phase (nitric acid and 18-crown-6 ether) was identical to the matrix of the sample. Under those conditions rubidium eluted at the dead volume of the column while strontium produced a flat-topped transient signal with several minutes of stable plateau. On-line data acquisition during several minutes at the plateau of Sr signal allowed high precision Sr isotope ratio measurement. The developed procedure was evaluated for Sr isotope ratio measurements on different types of samples, including cider, apples, apple leaves, and soil extracts, in the frame of a long-term project aiming at origin authentication using strontium isotope ratio measurements. It was observed that sample matrix caused broadening of the strontium chromatographic peak and loss of flat-topped peak profile. Under those circumstances the addition of the complexing crown-ether 18-crown-6 both to samples and chromatographic eluent provided two distinct advantages. First, a drastic increase in the retention of strontium was observed which could be modulated by increasing the concentration of nitric acid in the eluent up to 900 mM. This increase in the eluent HNO(3) concentration allowed the application of the method to acid soil digests and other high acidity samples. Second, the matrix of the sample did not affect any more the chromatographic peak profile and similar chromatographic separations could be obtained for samples and standards maintaining the flat-topped Sr peak profile. Sample preparation consisted of a simple 1:10 dilution of the cider or pre-treated solid samples by adding HNO(3) (900 mM) and 18-crown-6 ether (5mM) to obtain similar composition in the sample solution

  8. Potential for quantification of regionally altered myocardial perfusion by analysis of rubidium and thallium mean transit times in the rabbit heart

    SciTech Connect

    Marshall, R.C.; Taylor, S.E.; Powers-Risius, P.

    1995-05-01

    Quantitative estimation of regionally altered perfusion could result in improved clinical care for patients with coronary artery disease. We hypothesized that myocardial blood flow (F) and mean transit time (T{sub mtt}) should vary reciprocally for potassium analogs, such as rubidium and thallium, based on the relationship V{sub d}/F=T{sub mtt}. Twelve isolated blood-perfused rabbit hearts were studied at flows ranging from 0.7 to 2.92 ml/gm min{sup -1}. Bolus injections of Rb-83, Tl-201 and I-125 albumin were followed by subsequent venous ampling for 20 to 30 minutes. T{sub mtt} was estimated using two methods which compensate for the dispersion of the bolus in the blood vessels. In Method A, the I-125 albumin venous concentration curve was convolved with a Dirac delta function and one or more exponentials, and fit to the Rb-83 and Tl-201 venous concentration curves. Mean transit times of the Rb-83 and Tl-201 were computed as the weighted sums of the fitted components. In B, all three venous concentration curves were extrapolated by fitting a straight line to the tail of the semi-log plot of each curve. Extrapolated curves were then normalized to unit area, weighted by time, and numerically integrated to obtain gross mean transit times. Net mean transit times for Rb-83 and Tl-201 were then obtained by subtracting the gross mean transit time for I-125 albumin from those for Rb-83 and Tl-201. T{sub mtt} ranged from 4.0 to 15.5 min for Rb-83 and 6.0 to 29.7 min for Tl-=201. Correlations between 1/T{sub mtt} and F for Tl-201 were y = 0.064x - 0.005, r = 0.87 (Method A) and y = 0.049x + 0.011, r = 0.80 (Method B). The correlation for Rb-83 and Method B was y = 0.07x + 0.03, r = 0.89 which was significantly superior to Method A. Results are consistent with the hypothesis that F and T{sub mtt} vary inversely and suggest that T{sub mtt} could be used to quantitatively estimate regional perfusion in vivo after subtraction of the mean transit time of the input function.

  9. The structures of the isomorphous potassium and rubidium salts of 4-nitrobenzoic acid and an overview of the metal complex stereochemistries of the alkali metal salt series with this ligand.

    PubMed

    Smith, Graham

    2015-06-01

    4-Nitrobenzoic acid (PNBA) has proved to be a useful ligand for the preparation of metal complexes but the known structures of the alkali metal salts of PNBA do not include the rubidium salt. The structures of the isomorphous potassium and rubidium polymeric coordination complexes with PNBA, namely poly[μ2-aqua-aqua-μ3-(4-nitrobenzoato)-potassium], [K(C7H4N2O2)(H2O)2]n, (I), and poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-rubidium], [Rb(C7H4N2O2)(H2O)2]n, (II), have been determined. In (I), the very distorted KO6 coordination sphere about the K(+) centres in the repeat unit comprise two bridging nitro O-atom donors, a single bridging carboxylate O-atom donor and two water molecules, one of which is bridging. In Rb complex (II), the same basic MO6 coordination is found in the repeat unit, but it is expanded to RbO9 through a slight increase in the accepted Rb-O bond-length range and includes an additional Rb-O(carboxylate) bond, completing a bidentate O,O'-chelate interaction, and additional bridging Rb-O(nitro) and Rb-O(water) bonds. The comparative K-O and Rb-O bond-length ranges are 2.7352 (14)-3.0051 (14) and 2.884 (2)-3.182 (2) Å, respectively. The structure of (II) is also isomorphous, as well as isostructural, with the known structure of the nine-coordinate caesium 4-nitrobenzoate analogue, (III), in which the Cs-O bond-length range is 3.047 (4)-3.338 (4) Å. In all three complexes, common basic polymeric extensions are found, including two different centrosymmetric bridging interactions through both water and nitro groups, as well as extensions along c through the para-related carboxylate group, giving a two-dimensional structure in (I). In (II) and (III), three-dimensional structures are generated through additional bridges involving the nitro and water O atoms. In all three structures, the two water molecules are involved in similar intra-polymer O-H...O hydrogen-bonding interactions to both carboxylate and water O-atom acceptors. A

  10. Atomic frequency reference at 1033 nm for ytterbium (Yb)-doped fiber lasers and applications exploiting a rubidium (Rb) 5S_1/2 to 4D_5/2 one-colour two-photon transition

    NASA Astrophysics Data System (ADS)

    Roy, Ritayan; Condylis, Paul C.; Johnathan, Yik Jinen; Hessmo, Björn

    2017-04-01

    We demonstrate a two-photon transition of rubidium (Rb) atoms from the ground state (5$S_{1/2}$) to the excited state (4$D_{5/2}$), using a home-built ytterbium (Yb)-doped fiber amplifier at 1033 nm. This is the first demonstration of an atomic frequency reference at 1033 nm as well as of a one-colour two-photon transition for the above energy levels. A simple optical setup is presented for the two-photon transition fluorescence spectroscopy, which is useful for frequency stabilization for a broad class of lasers. This spectroscopy has potential applications in the fiber laser industry as a frequency reference, particularly for the Yb-doped fiber lasers. This two-photon transition also has applications in atomic physics as a background- free high- resolution atom detection and for quantum communication, which is outlined in this article.

  11. 47 CFR 78.115 - Modulation limits.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Modulation limits. 78.115 Section 78.115... SERVICE Technical Regulations § 78.115 Modulation limits. (a) If amplitude modulation is employed, negative modulation peaks shall not exceed 100 percent modulation. Pt. 78, Index Alphabetical Index—Part 78...

  12. 47 CFR 78.115 - Modulation limits.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Modulation limits. 78.115 Section 78.115... SERVICE Technical Regulations § 78.115 Modulation limits. (a) If amplitude modulation is employed, negative modulation peaks shall not exceed 100 percent modulation. Pt. 78, Index Alphabetical Index—Part 78...

  13. An ultra-stable optical frequency standard for telecommunication purposes based upon the 5S1/2 → 5D5/2 two-photon transition in rubidium

    NASA Astrophysics Data System (ADS)

    Terra, Osama; Hussein, Hatem

    2016-02-01

    In this study, we report the development of a frequency standard for optical fiber communication applications based on a two-photon transition in rubidium at 385.2 THz. This standard kills two birds with one stone in the sense it is capable of providing us with two highly stable serviceable wavelengths at 778.1 and 1556.2 nm. In this system, we exploit the narrow line-width of a fiber laser emitting at 1556.2 nm in conjunction with an erbium-doped fiber amplifier to generate a sufficient second harmonic laser beam at 778.1 nm in a periodically polled lithium niobate waveguide mixer in order to probe and frequency-lock the laser to the 5S1/2 ( F g = 3)-5D5/2 ( F e = 5) hyperfine two-photon transition component in 85Rb. The metrological performance of the standard is evaluated with the aid of an optical frequency comb synthesizer. Allan variance measurement shows a stability of 4 × 10-12 at 1 s (limited by the comb stability), reaching a floor of 6.8 × 10-13 at 1000 s. After correction of all the major systematic frequency shifts including the light shift, the absolute frequency is found to be 385 285 142 374.0 (5.0) kHz. Moreover, the absolute frequencies of most of the hyperfine components of the 5S1/2-5D5/2 transition of the two naturally existing rubidium isotopes are measured using a femtosecond frequency comb synthesizer after stabilizing a laser on each component.

  14. 40 CFR 78.7 - [Reserved

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false 78.7 Section 78.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPEAL PROCEDURES § 78.7 ...

  15. 40 CFR 78.7 - [Reserved

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false 78.7 Section 78.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPEAL PROCEDURES § 78.7...

  16. 78 FR 44279 - Regulatory Agenda

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-23

    ... From the Federal Register Online via the Government Publishing Office ] Vol. 78 Tuesday, No. 141 July 23, 2013 Part XI Department of Justice Semiannual Regulatory Agenda #0;#0;Federal Register / Vol. 78 , No. 141 / Tuesday, July 23, 2013 / Unified Agenda#0;#0; ] DEPARTMENT OF JUSTICE 8 CFR Ch. V 21...

  17. 46 CFR 78.47-1 - Application.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... § 78.47-90, shall apply to all vessels contracted for on or after November 19, 1952. Vessels contracted for prior to November 19, 1952, shall meet the requirements of § 78.47-90. (b) ... 46 Shipping 3 2010-10-01 2010-10-01 false Application. 78.47-1 Section 78.47-1 Shipping...

  18. Insights into gas-phase structural conformers of hydrated rubidium and cesium cations, M(+)(H2O)(n)Ar (M = Rb, Cs; n = 3-5), using infrared photodissociation spectroscopy.

    PubMed

    Ke, Haochen; van der Linde, Christian; Lisy, James M

    2014-02-27

    Infrared photodissociation (IRPD) spectra of M(+)(H2O)nAr (M = Rb, Cs; n = 3-5) with simultaneous monitoring of [Ar] and [Ar+H2O] fragmentation channels are reported. The comparison between the spectral features in the two channels and corresponding energy analysis provide spectral assignments of the stable structural conformers and insight into the competition between ion-water electrostatic and water-water hydrogen bonding interactions. Results show that as the level of hydration increases, the water-water interaction exhibits the tendency to dominate over the ion-water interaction. Cyclic water tetramer and water pentamer substructures appear in Cs(+)(H2O)4Ar and Cs(+)(H2O)5Ar systems, respectively. However, cyclic water tetramer and pentamer structures were not observed for Rb(+)(H2O)4Ar and Rb(+)(H2O)5Ar systems, respectively, due to the stronger influence of the rubidium ion-water electrostatic interaction. The energy analysis, including the available internal energy and the IR photon energy, helped provide an experimental estimate of water binding energies.

  19. High-lying electronic states of the rubidium dimer—Ab initio predictions and experimental observation of the 5 1 Σu + and 51Πu states of Rb2 by polarization labelling spectroscopy

    NASA Astrophysics Data System (ADS)

    Jastrzebski, Wlodzimierz; Kowalczyk, Pawel; Szczepkowski, Jacek; Allouche, Abdul-Rahman; Crozet, Patrick; Ross, Amanda J.

    2015-07-01

    Two-colour polarization labelling experiments have been used to explore the excitation spectrum of the rubidium dimer in the region 25 500-27 000 cm-1, probing two mutually interacting states, identified from ab initio calculations as the 5 1 Σu + and 51Πu states whose atomic dissociation products are Rb(5s) + Rb(5d). Treating the rather irregular progressions observed in the excitation spectra as transitions to single states with (numerous) local perturbations, we propose spectroscopic parameters and potential energy curves to describe the investigated levels. Observations cover more than 20 vibrational levels in the inner minima of both the 51Πu and 5 1 Σu + states. Analysis was guided by ab initio calculations performed to describe the 1,3Λg,u electronic states of Rb2 up to the Rb(5s) + Rb(5f) atomic asymptote. The theoretical potential energy curves are given in ASCII format in an electronic supplement to this paper.

  20. STS-78 Mission Insignia

    NASA Technical Reports Server (NTRS)

    1996-01-01

    The STS-78 patch links past with present to tell the story of its mission and science through a design imbued with the strength and vitality of the 2-dimensional art of North America's northwest coast Indians. Central to the design is the space Shuttle whose bold lines and curves evoke the Indian image for the eagle, a native American symbol of power and prestige as well as the national symbol of the United States. The wings of the Shuttle suggest the wings of the eagle whose feathers, indicative of peace and friendship in Indian tradition, are captured by the U forms, a characteristic feature of Northwest coast Indian art. The nose of the Shuttle is the strong downward curve of the eagle's beak, and the Shuttle's forward windows, the eagle's eyes, represented through the tapered S forms again typical of this Indian art form. The basic black and red atoms orbiting the mission number recall the original NASA emblem while beneath, utilizing Indian ovoid forms, the major mission scientific experiment package LMS (Life and Materials Sciences) housed in the Shuttle's cargo bay is depicted in a manner reminiscent of totem-pole art. This image of a bird poised for flight, so common to Indian art, is counterpointed by an equally familiar Tsimshian Indian symbol, a pulsating sun with long hyperbolic rays, the symbol of life. Within each of these rays are now encased crystals, the products of this mission's 3 major, high-temperature materials processing furnaces. And as the sky in Indian lore is a lovely open country, home of the Sun Chief and accessible to travelers through a hole in the western horizon, so too, space is a vast and beckoning landscape for explorers launched beyond the horizon. Beneath the Tsimshian sun, the colors of the earth limb are appropriately enclosed by a red border representing life to the Northwest coast Indians. The Indian colors of red, navy blue, white, and black pervade the STS-78 path. To the right of the Shuttle-eagle, the constellation

  1. STS-78 Mission Insignia

    NASA Technical Reports Server (NTRS)

    1996-01-01

    The STS-78 patch links past with present to tell the story of its mission and science through a design imbued with the strength and vitality of the 2-dimensional art of North America's northwest coast Indians. Central to the design is the space Shuttle whose bold lines and curves evoke the Indian image for the eagle, a native American symbol of power and prestige as well as the national symbol of the United States. The wings of the Shuttle suggest the wings of the eagle whose feathers, indicative of peace and friendship in Indian tradition, are captured by the U forms, a characteristic feature of Northwest coast Indian art. The nose of the Shuttle is the strong downward curve of the eagle's beak, and the Shuttle's forward windows, the eagle's eyes, represented through the tapered S forms again typical of this Indian art form. The basic black and red atoms orbiting the mission number recall the original NASA emblem while beneath, utilizing Indian ovoid forms, the major mission scientific experiment package LMS (Life and Materials Sciences) housed in the Shuttle's cargo bay is depicted in a manner reminiscent of totem-pole art. This image of a bird poised for flight, so common to Indian art, is counterpointed by an equally familiar Tsimshian Indian symbol, a pulsating sun with long hyperbolic rays, the symbol of life. Within each of these rays are now encased crystals, the products of this mission's 3 major, high-temperature materials processing furnaces. And as the sky in Indian lore is a lovely open country, home of the Sun Chief and accessible to travelers through a hole in the western horizon, so too, space is a vast and beckoning landscape for explorers launched beyond the horizon. Beneath the Tsimshian sun, the colors of the earth limb are appropriately enclosed by a red border representing life to the Northwest coast Indians. The Indian colors of red, navy blue, white, and black pervade the STS-78 path. To the right of the Shuttle-eagle, the constellation

  2. Modeling Starspots on Kepler-78

    NASA Astrophysics Data System (ADS)

    Mayo, Andrew; Vanderburg, Andrew; Dumusque, Xavier; Johnson, John A.

    2016-01-01

    Kepler-78 is a late G-type star which hosts Kepler-78b, an Earth-sized planet in an 8.5 hour orbit. The mass of Kepler-78b has been measured using the radial velocity technique, but this measurement is complicated by significant stellar activity, especially starspots. We present a new method for modeling starspots by applying a Markov Chain Monte Carlo process to the SOAP 2.0 starspot model. We apply this method to all available data simultaneously, including measurements of radial velocity, bisector span, and full width at half maximum. We recover the mass of Kepler-78b with excellent agreement to previous mass estimates. We also characterize the starspots of Kepler-78, constraining the latitude, longitude, size, and temperature of each spot group, and finding evidence of starspot evolution. Importantly, using both radial velocity measurements and line shape diagnostics seems to break the degeneracy between spot size and spot temperature. If this is correct, we also find that the starspots are warmer than one would expect of a G-type star. Our method of modeling starspots will allow us to better understand the surface phenomena of stars, as well as the properties of their planetary systems.

  3. Discrimination of the effects of saturation and optical pumping in velocity-dependent pump-probe spectroscopy of rubidium: A simple analytical study

    SciTech Connect

    Noh, Heung-Ryoul; Moon, Geol; Jhe, Wonho

    2010-12-15

    This paper presents a simple analytical theory for the velocity-dependent pump-probe laser spectroscopy of {sup 87}Rb and {sup 85}Rb atoms where the pump and the probe beams are circularly or linearly polarized. The analytical solutions of the line shapes of the velocity-selective optical pumping spectroscopy [G. Moon and H. R. Noh, Phys. Rev. A 78, 032506 (2008)] and saturated absorption spectroscopy [G. Moon and H. R. Noh, J. Opt. Soc. Am. B 25, 701 (2008); 27, 1741 (2010)] obtained in the previous reports, expressed as a sum of several Lorentzian functions, could be approximated as one (or in some cases, two) Lorentzian function(s). In particular, the contributions of the saturation and optical pumping effects could be discriminated explicitly in these simple analytical solutions, which is not possible in existing theories such as Nakayama's model. The simple analytical results for the saturation spectroscopy were compared with experimental results, and good agreement between them was observed.

  4. 21 CFR 558.78 - Bacitracin zinc.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Bacitracin zinc. 558.78 Section 558.78 Food and... in Animal Feeds § 558.78 Bacitracin zinc. (a) Specifications. Type A medicated articles containing bacitracin zinc equivalent to 10, 25, 40, or 50 grams per pound bacitracin. (b) Approvals. See No. 046573 in...

  5. 21 CFR 558.78 - Bacitracin zinc.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Bacitracin zinc. 558.78 Section 558.78 Food and... in Animal Feeds § 558.78 Bacitracin zinc. (a) Specifications. Type A medicated articles containing bacitracin zinc equivalent to 10, 25, 40, or 50 grams per pound bacitracin. (b) Approvals. See No. 046573 in...

  6. 21 CFR 558.78 - Bacitracin zinc.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Bacitracin zinc. 558.78 Section 558.78 Food and... in Animal Feeds § 558.78 Bacitracin zinc. (a) Specifications. Type A medicated articles containing bacitracin zinc equivalent to 10, 25, 40, or 50 grams per pound bacitracin. (b) Approvals. See No. 046573 in...

  7. 21 CFR 558.78 - Bacitracin zinc.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Bacitracin zinc. 558.78 Section 558.78 Food and... in Animal Feeds § 558.78 Bacitracin zinc. (a) Specifications. Type A medicated articles containing bacitracin zinc equivalent to 10, 25, 40, or 50 grams per pound bacitracin. (b) Approvals. See No. 046573 in...

  8. 42 CFR 460.78 - Dietary services.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 4 2012-10-01 2012-10-01 false Dietary services. 460.78 Section 460.78 Public...) PACE Administrative Requirements § 460.78 Dietary services. (a) Meal requirements. (1) Except as... meals that meet the participant's daily nutritional and special dietary needs. Each meal must meet the...

  9. 22 CFR 62.78 - Termination.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Termination. 62.78 Section 62.78 Foreign Relations DEPARTMENT OF STATE PUBLIC DIPLOMACY AND EXCHANGES EXCHANGE VISITOR PROGRAM Student and Exchange Visitor Information System (SEVIS) § 62.78 Termination. An exchange visitor who willfully or...

  10. 22 CFR 62.78 - Termination.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 22 Foreign Relations 1 2014-04-01 2014-04-01 false Termination. 62.78 Section 62.78 Foreign Relations DEPARTMENT OF STATE PUBLIC DIPLOMACY AND EXCHANGES EXCHANGE VISITOR PROGRAM Student and Exchange Visitor Information System (SEVIS) § 62.78 Termination. An exchange visitor who willfully or...

  11. 22 CFR 62.78 - Termination.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 22 Foreign Relations 1 2011-04-01 2011-04-01 false Termination. 62.78 Section 62.78 Foreign Relations DEPARTMENT OF STATE PUBLIC DIPLOMACY AND EXCHANGES EXCHANGE VISITOR PROGRAM Student and Exchange Visitor Information System (SEVIS) § 62.78 Termination. An exchange visitor who willfully or...

  12. 22 CFR 62.78 - Termination.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 22 Foreign Relations 1 2012-04-01 2012-04-01 false Termination. 62.78 Section 62.78 Foreign Relations DEPARTMENT OF STATE PUBLIC DIPLOMACY AND EXCHANGES EXCHANGE VISITOR PROGRAM Student and Exchange Visitor Information System (SEVIS) § 62.78 Termination. An exchange visitor who willfully or...

  13. 22 CFR 62.78 - Termination.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 22 Foreign Relations 1 2013-04-01 2013-04-01 false Termination. 62.78 Section 62.78 Foreign Relations DEPARTMENT OF STATE PUBLIC DIPLOMACY AND EXCHANGES EXCHANGE VISITOR PROGRAM Student and Exchange Visitor Information System (SEVIS) § 62.78 Termination. An exchange visitor who willfully or...

  14. 40 CFR 78.2 - General.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false General. 78.2 Section 78.2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPEAL PROCEDURES § 78.2 General. (a) Definitions. (1) The terms used in this subpart with regard to a decision of the...

  15. 40 CFR 78.2 - General.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false General. 78.2 Section 78.2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPEAL PROCEDURES § 78.2 General. Part 72 of this chapter, including §§ 72.2 (definitions), 72.3 (measurements...

  16. 40 CFR 78.4 - Filings.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Filings. 78.4 Section 78.4 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPEAL PROCEDURES § 78.4 Filings. (a) All original filings made under this part shall be signed by the person making the...

  17. 40 CFR 78.4 - Filings.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Filings. 78.4 Section 78.4 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPEAL PROCEDURES § 78.4 Filings. (a)(1) All original filings made under this part shall be signed by the person making...

  18. 40 CFR 78.11 - Intervenors.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Intervenors. 78.11 Section 78.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPEAL PROCEDURES § 78.11 Intervenors. (a) Within 30 days (or other shorter, reasonable period established by the...

  19. 9 CFR 78.14 - Rodeo cattle.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 9 Animals and Animal Products 1 2014-01-01 2014-01-01 false Rodeo cattle. 78.14 Section 78.14... Interstate Movement of Cattle Because of Brucellosis § 78.14 Rodeo cattle. (a) Rodeo cattle that are test... of interstate movement: Provided, however, That: The official test is not required for rodeo cattle...

  20. 7 CFR 948.78 - Accounting.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Accounting. 948.78 Section 948.78 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Marketing Agreements... Order Regulating Handling Expenses and Assessments § 948.78 Accounting. (a) If, at the end of a fiscal...

  1. 44 CFR 78.4 - Applicant eligibility.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 44 Emergency Management and Assistance 1 2010-10-01 2010-10-01 false Applicant eligibility. 78.4 Section 78.4 Emergency Management and Assistance FEDERAL EMERGENCY MANAGEMENT AGENCY, DEPARTMENT OF... ASSISTANCE § 78.4 Applicant eligibility. (a) The State is eligible to apply for grants for...

  2. 47 CFR 78.36 - Frequency coordination.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Frequency coordination. 78.36 Section 78.36... SERVICE Applications and Licenses § 78.36 Frequency coordination. (a) Coordination of all frequency... less than 30 days if the parties agree. Coordination of all frequency assignments for all mobile...

  3. 7 CFR 3201.78 - Blast media.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 15 2013-01-01 2013-01-01 false Blast media. 3201.78 Section 3201.78 Agriculture... Items § 3201.78 Blast media. (a) Definition. Abrasive particles sprayed forcefully to clean, remove... qualifying biobased blast media. By that date, Federal agencies that have the responsibility for drafting or...

  4. 7 CFR 3201.78 - Blast media.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 15 2014-01-01 2014-01-01 false Blast media. 3201.78 Section 3201.78 Agriculture... Items § 3201.78 Blast media. (a) Definition. Abrasive particles sprayed forcefully to clean, remove... qualifying biobased blast media. By that date, Federal agencies that have the responsibility for drafting or...

  5. 46 CFR 78.37-1 - Application.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 3 2012-10-01 2012-10-01 false Application. 78.37-1 Section 78.37-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Logbook Entries § 78.37-1 Application. (a) Except as specifically noted, the provisions of this subpart shall apply to all...

  6. 46 CFR 78.36-1 - Application.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 3 2012-10-01 2012-10-01 false Application. 78.36-1 Section 78.36-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Work Vests § 78.36-1 Application. (a) Provisions of this subpart shall apply to all vessels inspected and certificated in...

  7. 46 CFR 78.47-1 - Application.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 3 2012-10-01 2012-10-01 false Application. 78.47-1 Section 78.47-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Markings for Fire and Emergency Equipment, Etc. § 78.47-1 Application. (a) The provisions of this subpart with the exception of...

  8. 46 CFR 78.17-1 - Application.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 3 2012-10-01 2012-10-01 false Application. 78.17-1 Section 78.17-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Tests, Drills, and Inspections § 78.17-1 Application. (a) Except as specifically noted, the provisions of this subpart shall...

  9. 46 CFR 78.50-1 - Application.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 3 2012-10-01 2012-10-01 false Application. 78.50-1 Section 78.50-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Markings on Vessels § 78.50-1 Application. (a) The provisions of this subpart shall apply to all vessels except as...

  10. 47 CFR 78.23 - Equipment tests.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Equipment tests. 78.23 Section 78.23... SERVICE Applications and Licenses § 78.23 Equipment tests. (a) Following the grant of a CARS license, the... Commission, conduct equipment tests for the purpose of such adjustments and measurements as may be...

  11. 47 CFR 78.23 - Equipment tests.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false Equipment tests. 78.23 Section 78.23... SERVICE Applications and Licenses § 78.23 Equipment tests. (a) Following the grant of a CARS license, the... Commission, conduct equipment tests for the purpose of such adjustments and measurements as may be necessary...

  12. 9 CFR 78.1 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 9 Animals and Animal Products 1 2014-01-01 2014-01-01 false Definitions. 78.1 Section 78.1 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE INTERSTATE TRANSPORTATION OF ANIMALS (INCLUDING POULTRY) AND ANIMAL PRODUCTS BRUCELLOSIS General Provisions § 78.1 Definitions. The following terms are...

  13. 32 CFR 78.6 - Responsibilities.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 32 National Defense 1 2014-07-01 2014-07-01 false Responsibilities. 78.6 Section 78.6 National Defense Department of Defense OFFICE OF THE SECRETARY OF DEFENSE PERSONNEL, MILITARY AND CIVILIAN VOLUNTARY STATE TAX WITHHOLDING FROM RETIRED PAY § 78.6 Responsibilities. (a) The Assistant Secretary...

  14. 32 CFR 78.6 - Responsibilities.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 1 2010-07-01 2010-07-01 false Responsibilities. 78.6 Section 78.6 National Defense Department of Defense OFFICE OF THE SECRETARY OF DEFENSE PERSONNEL, MILITARY AND CIVILIAN VOLUNTARY STATE TAX WITHHOLDING FROM RETIRED PAY § 78.6 Responsibilities. (a) The Assistant Secretary...

  15. 45 CFR 78.1 - Applicability.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 45 Public Welfare 1 2010-10-01 2010-10-01 false Applicability. 78.1 Section 78.1 Public Welfare... BENEFITS § 78.1 Applicability. This part is applicable to any decision to deny Federal benefits, under... or possession of a controlled substance as defined by the Controlled Substances Act, 21 U.S.C. 802. ...

  16. 45 CFR 78.1 - Applicability.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 45 Public Welfare 1 2012-10-01 2012-10-01 false Applicability. 78.1 Section 78.1 Public Welfare... BENEFITS § 78.1 Applicability. This part is applicable to any decision to deny Federal benefits, under... or possession of a controlled substance as defined by the Controlled Substances Act, 21 U.S.C. 802. ...

  17. 44 CFR 78.3 - Responsibilities.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 44 Emergency Management and Assistance 1 2010-10-01 2010-10-01 false Responsibilities. 78.3 Section 78.3 Emergency Management and Assistance FEDERAL EMERGENCY MANAGEMENT AGENCY, DEPARTMENT OF... ASSISTANCE § 78.3 Responsibilities. (a) Federal. The Administrator will allocate available funds to each...

  18. 44 CFR 78.3 - Responsibilities.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 44 Emergency Management and Assistance 1 2013-10-01 2013-10-01 false Responsibilities. 78.3 Section 78.3 Emergency Management and Assistance FEDERAL EMERGENCY MANAGEMENT AGENCY, DEPARTMENT OF... ASSISTANCE § 78.3 Responsibilities. (a) Federal. The Administrator will allocate available funds to each...

  19. 32 CFR 78.6 - Responsibilities.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 32 National Defense 1 2011-07-01 2011-07-01 false Responsibilities. 78.6 Section 78.6 National Defense Department of Defense OFFICE OF THE SECRETARY OF DEFENSE PERSONNEL, MILITARY AND CIVILIAN VOLUNTARY STATE TAX WITHHOLDING FROM RETIRED PAY § 78.6 Responsibilities. (a) The Assistant Secretary...

  20. 32 CFR 78.6 - Responsibilities.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 1 2013-07-01 2013-07-01 false Responsibilities. 78.6 Section 78.6 National Defense Department of Defense OFFICE OF THE SECRETARY OF DEFENSE PERSONNEL, MILITARY AND CIVILIAN VOLUNTARY STATE TAX WITHHOLDING FROM RETIRED PAY § 78.6 Responsibilities. (a) The Assistant Secretary...

  1. 46 CFR 78.30-15 - Watchmen.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Watchmen. 78.30-15 Section 78.30-15 Shipping COAST GUARD..., Patrolmen, and Watchmen § 78.30-15 Watchmen. (a) The provisions of this section shall apply to all vessels... applicable at all times when passengers are on board. (b) During the nighttime, a suitable number of watchmen...

  2. 78 FR 49306 - Proposed Collection; Comment Request

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-13

    ... reporting requirements under Sections 12(b), 12(g), 13(a), and 15(d) (15 U.S.C. 78l(b), 78l(g), 78m(a) and... agency, including whether the information will have practical utility; (b) the accuracy of the...

  3. 40 CFR 98.78 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Definitions. 98.78 Section 98.78 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.78 Definitions. All terms used in this subpart have the...

  4. 40 CFR 98.78 - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Definitions. 98.78 Section 98.78 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.78 Definitions. All terms used in this subpart have the...

  5. 9 CFR 78.4 - [Reserved

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false 78.4 Section 78.4 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE INTERSTATE TRANSPORTATION OF ANIMALS (INCLUDING POULTRY) AND ANIMAL PRODUCTS BRUCELLOSIS General Provisions § 78.4...

  6. 43 CFR 2.78 - [Reserved

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 1 2012-10-01 2011-10-01 true 2.78 Section 2.78 Public Lands: Interior Office of the Secretary of the Interior RECORDS AND TESTIMONY; FREEDOM OF INFORMATION ACT Privacy Act § 2.78...

  7. 47 CFR 78.105 - Antenna systems.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Antenna systems. 78.105 Section 78.105... SERVICE Technical Regulations § 78.105 Antenna systems. (a) For fixed stations operating in the 12.7-13.2... directional antennas that meet the performance standards indicated in the following table. (i) Stations...

  8. 47 CFR 78.105 - Antenna systems.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Antenna systems. 78.105 Section 78.105... SERVICE Technical Regulations § 78.105 Antenna systems. (a) For fixed stations operating in the 12.7-13.2... directional antennas that meet the performance standards indicated in the following table. (i) Stations...

  9. 47 CFR 78.105 - Antenna systems.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Antenna systems. 78.105 Section 78.105... SERVICE Technical Regulations § 78.105 Antenna systems. (a) For fixed stations operating in the 12.7-13.2... directional antennas that meet the performance standards indicated in the following table. (i) Stations...

  10. 7 CFR 948.78 - Accounting.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 8 2013-01-01 2013-01-01 false Accounting. 948.78 Section 948.78 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (MARKETING AGREEMENTS... Order Regulating Handling Expenses and Assessments § 948.78 Accounting. (a) If, at the end of a...

  11. 7 CFR 948.78 - Accounting.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 8 2014-01-01 2014-01-01 false Accounting. 948.78 Section 948.78 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (MARKETING AGREEMENTS... Order Regulating Handling Expenses and Assessments § 948.78 Accounting. (a) If, at the end of a...

  12. 45 CFR 81.78 - Evidence.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 45 Public Welfare 1 2014-10-01 2014-10-01 false Evidence. 81.78 Section 81.78 Public Welfare... 80 OF THIS TITLE Hearing Procedures § 81.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  13. 45 CFR 81.78 - Evidence.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 45 Public Welfare 1 2010-10-01 2010-10-01 false Evidence. 81.78 Section 81.78 Public Welfare... 80 OF THIS TITLE Hearing Procedures § 81.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  14. 45 CFR 81.78 - Evidence.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 45 Public Welfare 1 2013-10-01 2013-10-01 false Evidence. 81.78 Section 81.78 Public Welfare... 80 OF THIS TITLE Hearing Procedures § 81.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  15. 45 CFR 81.78 - Evidence.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 45 Public Welfare 1 2012-10-01 2012-10-01 false Evidence. 81.78 Section 81.78 Public Welfare... 80 OF THIS TITLE Hearing Procedures § 81.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  16. 34 CFR 101.78 - Evidence.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 34 Education 1 2014-07-01 2014-07-01 false Evidence. 101.78 Section 101.78 Education Regulations... PRACTICE AND PROCEDURE FOR HEARINGS UNDER PART 100 OF THIS TITLE Hearing Procedures § 101.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  17. 34 CFR 101.78 - Evidence.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 34 Education 1 2012-07-01 2012-07-01 false Evidence. 101.78 Section 101.78 Education Regulations... PRACTICE AND PROCEDURE FOR HEARINGS UNDER PART 100 OF THIS TITLE Hearing Procedures § 101.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  18. 45 CFR 81.78 - Evidence.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 45 Public Welfare 1 2011-10-01 2011-10-01 false Evidence. 81.78 Section 81.78 Public Welfare... 80 OF THIS TITLE Hearing Procedures § 81.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  19. 34 CFR 101.78 - Evidence.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 34 Education 1 2010-07-01 2010-07-01 false Evidence. 101.78 Section 101.78 Education Regulations... PRACTICE AND PROCEDURE FOR HEARINGS UNDER PART 100 OF THIS TITLE Hearing Procedures § 101.78 Evidence. Irrelevant, immaterial, unreliable, and unduly repetitious evidence will be excluded....

  20. 48 CFR 452.236-78 - [Reserved

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 4 2011-10-01 2011-10-01 false 452.236-78 Section 452.236-78 Federal Acquisition Regulations System DEPARTMENT OF AGRICULTURE CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Texts of Provisions and Clauses 452.236-78...

  1. 9 CFR 78.34 - Other movements.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Other movements. 78.34 Section 78.34... Interstate Movement of Swine Because of Brucellosis § 78.34 Other movements. The Administrator may, upon request in specific cases, permit the movement in interstate commerce of swine not otherwise provided for...

  2. 9 CFR 78.13 - Other movements.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Other movements. 78.13 Section 78.13... Interstate Movement of Cattle Because of Brucellosis § 78.13 Other movements. The Administrator may, upon request in specific cases, permit the interstate movement of cattle not otherwise provided for in this...

  3. 33 CFR 401.78 - Required information.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Required information. 401.78 Section 401.78 Navigation and Navigable Waters SAINT LAWRENCE SEAWAY DEVELOPMENT CORPORATION, DEPARTMENT OF TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations Information and Reports § 401.78 Required...

  4. 46 CFR 78.36-1 - Application.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Application. 78.36-1 Section 78.36-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Work Vests § 78.36-1 Application. (a) Provisions of this subpart shall apply to all vessels inspected and certificated in...

  5. 46 CFR 78.36-10 - Use.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Use. 78.36-10 Section 78.36-10 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Work Vests § 78.36-10 Use. (a) Approved buoyant work vests are considered to be items of safety apparel and may be carried aboard vessels...

  6. 46 CFR 78.36-10 - Use.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 3 2011-10-01 2011-10-01 false Use. 78.36-10 Section 78.36-10 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Work Vests § 78.36-10 Use. (a) Approved buoyant work vests are considered to be items of safety apparel and may be carried aboard...

  7. 46 CFR 78.36-10 - Use.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 3 2013-10-01 2013-10-01 false Use. 78.36-10 Section 78.36-10 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Work Vests § 78.36-10 Use. (a) Approved buoyant work vests are considered to be items of safety apparel and may be carried aboard...

  8. 46 CFR 78.36-10 - Use.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 3 2014-10-01 2014-10-01 false Use. 78.36-10 Section 78.36-10 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS OPERATIONS Work Vests § 78.36-10 Use. (a) Approved buoyant work vests are considered to be items of safety apparel and may be carried aboard...

  9. 40 CFR 98.78 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Definitions. 98.78 Section 98.78 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.78 Definitions. All terms used in this subpart have...

  10. 40 CFR 98.78 - Definitions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Definitions. 98.78 Section 98.78 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.78 Definitions. All terms used in this subpart have...

  11. 40 CFR 98.78 - Definitions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Definitions. 98.78 Section 98.78 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.78 Definitions. All terms used in this subpart have...

  12. 47 CFR 78.115 - Modulation limits.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Modulation limits. 78.115 Section 78.115... SERVICE Technical Regulations § 78.115 Modulation limits. (a) If amplitude modulation is employed, negative modulation peaks shall not exceed 100 percent modulation. [37 FR 3292, Feb. 12, 1972, as amended...

  13. 47 CFR 78.65 - Additional orders.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false Additional orders. 78.65 Section 78.65 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.65 Additional orders. In case the rules of this part do...

  14. 47 CFR 78.61 - Operator requirements.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Operator requirements. 78.61 Section 78.61 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.61 Operator requirements. (a) Except in cases where a...

  15. 47 CFR 78.53 - Unattended operation.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Unattended operation. 78.53 Section 78.53 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.53 Unattended operation. (a) A CARS station may be...

  16. 47 CFR 78.101 - Power limitations.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Power limitations. 78.101 Section 78.101 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.101 Power limitations. (a) On any authorized frequency, the...

  17. 47 CFR 78.57 - Station inspection.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Station inspection. 78.57 Section 78.57 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.57 Station inspection. The station and all records required...

  18. 47 CFR 78.29 - License period.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false License period. 78.29 Section 78.29 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.29 License period. Licenses for CARS stations will be issued for...

  19. 47 CFR 78.23 - Equipment tests.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Equipment tests. 78.23 Section 78.23 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.23 Equipment tests. (a) Following the grant of a CARS license,...

  20. 47 CFR 78.23 - Equipment tests.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Equipment tests. 78.23 Section 78.23 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.23 Equipment tests. (a) Following the grant of a CARS license,...

  1. 47 CFR 78.29 - License period.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false License period. 78.29 Section 78.29 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.29 License period. Licenses for CARS stations will be issued for...

  2. 47 CFR 78.69 - Station records.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Station records. 78.69 Section 78.69 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.69 Station records. Each licensee of a CARS station...

  3. 47 CFR 78.111 - Frequency tolerance.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Frequency tolerance. 78.111 Section 78.111 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.111 Frequency tolerance. Stations in this service shall maintain...

  4. 47 CFR 78.57 - Station inspection.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Station inspection. 78.57 Section 78.57 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.57 Station inspection. The station and all records required...

  5. 47 CFR 78.69 - Station records.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Station records. 78.69 Section 78.69 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.69 Station records. Each licensee of a CARS station...

  6. 47 CFR 78.111 - Frequency tolerance.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Frequency tolerance. 78.111 Section 78.111 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.111 Frequency tolerance. Stations in this service shall maintain...

  7. 47 CFR 78.69 - Station records.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Station records. 78.69 Section 78.69 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.69 Station records. Each licensee of a CARS station...

  8. 47 CFR 78.101 - Power limitations.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false Power limitations. 78.101 Section 78.101 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.101 Power limitations. (a) On any authorized frequency, the...

  9. 47 CFR 78.61 - Operator requirements.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Operator requirements. 78.61 Section 78.61 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.61 Operator requirements. (a) Except in cases where a...

  10. 47 CFR 78.36 - Frequency coordination.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false Frequency coordination. 78.36 Section 78.36 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.36 Frequency coordination. (a) Coordination of all...

  11. 47 CFR 78.61 - Operator requirements.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Operator requirements. 78.61 Section 78.61 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.61 Operator requirements. (a) Except in cases where a...

  12. 47 CFR 78.23 - Equipment tests.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Equipment tests. 78.23 Section 78.23 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.23 Equipment tests. (a) Following the grant of a CARS license,...

  13. 47 CFR 78.65 - Additional orders.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Additional orders. 78.65 Section 78.65 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.65 Additional orders. In case the rules of this part do...

  14. 47 CFR 78.53 - Unattended operation.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Unattended operation. 78.53 Section 78.53 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.53 Unattended operation. (a) A CARS station may be...

  15. 47 CFR 78.36 - Frequency coordination.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Frequency coordination. 78.36 Section 78.36 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.36 Frequency coordination. (a) Coordination of all...

  16. 47 CFR 78.29 - License period.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false License period. 78.29 Section 78.29 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.29 License period. Licenses for CARS stations will be issued for...

  17. 47 CFR 78.29 - License period.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false License period. 78.29 Section 78.29 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.29 License period. Licenses for CARS stations will be issued for...

  18. 47 CFR 78.29 - License period.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false License period. 78.29 Section 78.29 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE Applications and Licenses § 78.29 License period. Licenses for CARS stations will be issued for...

  19. 47 CFR 78.65 - Additional orders.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Additional orders. 78.65 Section 78.65 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.65 Additional orders. In case the rules of this part do...

  20. 47 CFR 78.61 - Operator requirements.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false Operator requirements. 78.61 Section 78.61 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES CABLE TELEVISION RELAY SERVICE General Operating Requirements § 78.61 Operator requirements. (a) Except in cases where a...