Multi-parameter monitoring of a freshwater submarine groundwater discharge in SW Greece

NASA Astrophysics Data System (ADS)

Karageorgis, A. P.; Papathanassiou, E.

2011-12-01

In 2006, we visited for the first time the area of Kalogria-Stoupa in Peloponnissos, SW Greece, and recorded several submarine groundwater discharges (SGDs), one of which was permanent and very active. The main SGD was easily identified as a wide turbulent gyre (diameter 25-60 m) visible at the sea surface from long distance. Preliminary measurements revealed that freshwater was flowing from the spring at 25 m-depth, and plans for monitoring and potential exploitation were scheduled. The SGD was monitored continuously (measurements every 30 min.) from July 2009 to July 2010 for conductivity, temperature, and flow velocity. An autonomous underwater gamma-ray detector (KATERINA) was used to monitor the radioactivity concentration of radon daughters. During summer, the outflowing water was brackish, with low velocities around 0.2 m s-1. After the first intense rainfalls in mid-October 2009, the SGD emanated steadily low salinity waters (<2), whereas flow velocities exceeded 1.2 m s-1. Estimating that the active discharge area was approx. 1 m2, the spring water discharge varied from 750 to 4.500 m3 h-1 over the year. In May 2010, salinity increased abruptly from 4 to 13 within a few hours, accompanied by a slight decrease of flow velocity. We attribute this change to over-pumping of the carstic aquifer for irrigation in the mainland. Until July 2010, salinity increased furthermore (>20), and then decreased gradually to values ~12. Temperature and salinity variability was very high during some periods, probably due to intense turbulence and in-situ mixing of groundwater and ambient seawater. Radon progenies average activities were proportional to the variations of groundwater discharge, whereas potassium exhibited inverse relationship. The instability of salinity, especially during the summer time, where freshwater would be most needed for irrigation, and in ideal conditions for drinking purposes, terminated any exploitation plans. In mid-July 2011, the SGD without any

Groundwater-level trends and forecasts, and salinity trends, in the Azraq, Dead Sea, Hammad, Jordan Side Valleys, Yarmouk, and Zarqa groundwater basins, Jordan

USGS Publications Warehouse

Goode, Daniel J.; Senior, Lisa A.; Subah, Ali; Jaber, Ayman

2013-01-01

Changes in groundwater levels and salinity in six groundwater basins in Jordan were characterized by using linear trends fit to well-monitoring data collected from 1960 to early 2011. On the basis of data for 117 wells, groundwater levels in the six basins were declining, on average about -1 meter per year (m/yr), in 2010. The highest average rate of decline, -1.9 m/yr, occurred in the Jordan Side Valleys basin, and on average no decline occurred in the Hammad basin. The highest rate of decline for an individual well was -9 m/yr. Aquifer saturated thickness, a measure of water storage, was forecast for year 2030 by using linear extrapolation of the groundwater-level trend in 2010. From 30 to 40 percent of the saturated thickness, on average, was forecast to be depleted by 2030. Five percent of the wells evaluated were forecast to have zero saturated thickness by 2030. Electrical conductivity was used as a surrogate for salinity (total dissolved solids). Salinity trends in groundwater were much more variable and less linear than groundwater-level trends. The long-term linear salinity trend at most of the 205 wells evaluated was not increasing, although salinity trends are increasing in some areas. The salinity in about 58 percent of the wells in the Amman-Zarqa basin was substantially increasing, and the salinity in Hammad basin showed a long-term increasing trend. Salinity increases were not always observed in areas with groundwater-level declines. The highest rates of salinity increase were observed in regional discharge areas near groundwater pumping centers.

Groundwater Discharges to Rivers in the Western Canadian Oil Sands Region

NASA Astrophysics Data System (ADS)

Ellis, J.; Jasechko, S.

2016-12-01

Groundwater discharges into rivers impacts the movement and fate of nutrients and contaminants in the environment. Understanding groundwater-surface water interactions is especially important in the western Canadian oil sands, where groundwater contamination risks are elevated and baseline water chemistry data is lacking, leading to substantial uncertainties about anthropogenic influences on local river quality. High salinity groundwater springs sourced from deep aquifers, comprised of Pleistocene-aged glacial meltwater, are known to discharge into many rivers in the oil sands. Understanding connections between deep aquifers and surficial waterways is important in order to determine natural inputs into these rivers and to assess the potential for injected wastewater or oil extraction fluids to enter surface waters. While these springs have been identified, their spatial distribution along rivers has not been fully characterized. Here we present river chemistry data collected along a number of major river corridors in the Canadian oil sands region. We show that saline groundwater springs vary spatially along the course of these rivers and tend to be concentrated where the rivers incise Devonian- or Cretaceous-aged aquifers along an evaporite dissolution front. Our results suggest that water sourced from Devonian aquifers may travel through bitumen-bearing Cretaceous units and discharge into local rivers, implying a strong groundwater-surface water connection in specialized locations. These findings indicate that oil sands process-affected waters that are injected at depth have the potential to move through these aquifers and reach the rivers at the surface at some time in the future. Groundwater-surface water interactions remain key to understanding the risks oil sands activities pose to aquatic ecosystems and downstream communities.

Characterizing preferential groundwater discharge through boils using temperature

NASA Astrophysics Data System (ADS)

Vandenbohede, A.; de Louw, P. G. B.; Doornenbal, P. J.

2014-03-01

In The Netherlands, preferential groundwater discharge trough boils is a key process in the salinization of deep polders. Previous work showed that boils also influence the temperature in the subsurface and of surface water. This paper elaborates on this process combining field observations with numerical modeling. As is the case for salinity, a distinct anomaly in the subsurface and surface water temperature can be attributed to boils. Lines of equal temperature are distorted towards the boil, which can be considered as an upconing of the temperature profile by analogy of the upconing of a fresh-saltwater interface. The zone of this distortion is limited to the immediate vicinity of the boil, being about 5 m in the aquitard which holds the boil's conduit, or maximum a few dozens of meters in the underlying aquifer. In the aquitard, heat transport is conduction dominated whereas this is convection dominated in the aquifer. The temperature anomaly differs from the salinity anomaly by the smaller radius of influence and faster time to reach a new steady-state of the former. Boils discharge water with a temperature equal to the mean groundwater temperature. This influences the yearly and diurnal variation of ditch water temperature in the immediate vicinity of the boil importantly but also the temperature in the downstream direction. Temporary nature of the boil (e.g. stability of the conduit, discharge rate), uncertainty on the 3D construction of the conduit and heterogeneity of the subsoil make it unlikely that temperature measurements can be interpreted further than a qualitative level.

Natural Attenuation of Chlorinated Solvent Ground-Water Plumes Discharging into Wetlands

DTIC Science & Technology

2003-09-01

ground water in highly saline wetlands (Swanson et al., 1984), and the distribution of marsh marigold (Caltha palustris L.) has been used to map...seeps and springs next to a lake and in wetlands in Minnesota (Rosenberry et al., 2000). Marsh marigold favors ground-water discharge areas across the

Submarine groundwater discharge and nutrient addition to the coastal zone and coral reefs of leeward Hawai'i

USGS Publications Warehouse

Street, J.H.; Knee, K.L.; Grossman, E.E.; Paytan, A.

2008-01-01

Multiple tracers of groundwater input (salinity, Si, 223Ra, 224Ra, and 226Ra) were used together to determine the magnitude, character (meteoric versus seawater), and nutrient contribution associated with submarine groundwater discharge across the leeward shores of the Hawai'ian Islands Maui, Moloka'i, and Hawai'i. Tracer abundances were elevated in the unconfined coastal aquifer and the nearshore zone, decreasing to low levels offshore, indicative of groundwater discharge (near-fresh, brackish, or saline) at all locations. At several sites, we detected evidence of fresh and saline SGD occurring simultaneously. Conservative estimates of SGD fluxes ranged widely, from 0.02-0.65??m3??m- 2 d- 1at the various sites. Groundwater nutrient fluxes of 0.04-40??mmol N m- 2 d- 1 and 0.01-1.6??mmol P m- 2 d- 1 represent a major source of new nutrients to coastal ecosystems along these coasts. Nutrient additions were typically greatest at locations with a substantial meteoric component in groundwater, but the recirculation of seawater through the aquifer may provide a means of transferring terrestrially-derived nutrients to the coastal zone at several sites. ?? 2007 Elsevier B.V. All rights reserved.

Biogeochemical transport in the Loxahatchee River estuary, Florida: The role of submarine groundwater discharge

USGS Publications Warehouse

Swarzenski, P.W.; Orem, W.H.; McPherson, B.F.; Baskaran, M.; Wan, Y.

2006-01-01

The distributions of dissolved organic carbon (DOC), Ba, U, and a suite of naturally occurring radionuclides in the U/Th decay series (222Rn, 223,224,226,228Ra) were studied during high- and low-discharge conditions in the Loxahatchee River estuary, Florida to examine the role of submarine groundwater discharge in estuarine transport. The fresh water endmember of this still relatively pristine estuary may reflect not only river-borne constituents, but also those advected during active groundwater/surface water (hyporheic) exchange. During both discharge conditions, Ba concentrations indicated slight non-conservative mixing. Such Ba excesses could be attributed either to submarine groundwater discharge or particle desorption processes. Estuarine dissolved organic carbon concentrations were highest at salinities closest to zero. Uranium distributions were lowest in the fresh water sites and mixed mostly conservatively with an increase in salinity. Suspended particulate matter (SPM) concentrations were generally lowest ( 28??dpm L- 1) at the freshwater endmember of the estuary and appear to identify regions of the river most influenced by the discharge of fresh groundwater. Activities of four naturally occurring isotopes of Ra (223,224,226,228Ra) in this estuary and select adjacent shallow groundwater wells yield mean estuarine water-mass transit times of less than 1 day; these values are in close agreement to those calculated by tidal prism and tidal frequency. Submarine groundwater discharge rates to the Loxahatchee River estuary were calculated using a tidal prism approach, an excess 226Ra mass balance, and an electromagnetic seepage meter. Average SGD rates ranged from 1.0 to 3.8 ?? 105??m3 d- 1 (20-74??L m- 2 d- 1), depending on river-discharge stage. Such calculated SGD estimates, which must include both a recirculated as well as fresh water component, are in close agreement with results obtained from a first-order watershed mass balance. Average submarine

Marine electrical resistivity imaging of submarine groundwater discharge: Sensitivity analysis and application in Waquoit Bay, Massachusetts, USA

USGS Publications Warehouse

Henderson, Rory; Day-Lewis, Frederick D.; Abarca, Elena; Harvey, Charles F.; Karam, Hanan N.; Liu, Lanbo; Lane, John W.

2010-01-01

Electrical resistivity imaging has been used in coastal settings to characterize fresh submarine groundwater discharge and the position of the freshwater/salt-water interface because of the relation of bulk electrical conductivity to pore-fluid conductivity, which in turn is a function of salinity. Interpretation of tomograms for hydrologic processes is complicated by inversion artifacts, uncertainty associated with survey geometry limitations, measurement errors, and choice of regularization method. Variation of seawater over tidal cycles poses unique challenges for inversion. The capabilities and limitations of resistivity imaging are presented for characterizing the distribution of freshwater and saltwater beneath a beach. The experimental results provide new insight into fresh submarine groundwater discharge at Waquoit Bay National Estuarine Research Reserve, East Falmouth, Massachusetts (USA). Tomograms from the experimental data indicate that fresh submarine groundwater discharge may shut down at high tide, whereas temperature data indicate that the discharge continues throughout the tidal cycle. Sensitivity analysis and synthetic modeling provide insight into resolving power in the presence of a time-varying saline water layer. In general, vertical electrodes and cross-hole measurements improve the inversion results regardless of the tidal level, whereas the resolution of surface arrays is more sensitive to time-varying saline water layer.

New types of submarine groundwater discharge from a saliferous clay formation - the case of the Dead Sea

NASA Astrophysics Data System (ADS)

Siebert, Christian; Broder, Merkel; Thomas, Pohl; Yossi, Yechieli; Eldat, Hazan; Danny, Ionescu; Ulf, Mallast

2017-04-01

Along the coastline of the hyper-saline and dramatically dropping Dead Sea, fresh to highly saline groundwaters discharge abundantly from dry falling lakebed. During its history, the level and hence salinity of the lake strongly fluctuated, resulting in the deposition of an alternating sequence of clayey and chemical sediments (mainly halite, carbonates and sulfates), intercalated by thick beds of halite and of coarse clastics around wadi outlets, respectively. Due to the asymmetrical shape of the lake's basin, these strata are deposited unequally along the eastern and western flank, why only groundwaters coming from the west have to pass thick layers of these sediments on their way into the lake. On the base of trace elements (REE), element ratios, stable and radioisotopes and microbiological findings, the observed onshore and offshore springs revealed, freshwaters discharge from both Cretaceous limestone aquifers and efficiently dissolve the easily soluble halite and flush the interstitial brines from the saliferous clay formation, immediately after entering the sedimentary strata. Abundant microbial activity result in the widespread production of sulfuric acid, accelerating erosion of carbonates and sulfates. These processes result in a fast and striking karstification of the strata, enabling groundwaters to transcendent the fresh/saltwater interface trough open pipes. As results, submarine groundwater discharge (SGD) occurs randomly and in addition to terrestrial, submarine sinkholes develop very quickly too. Due to the variable maturity of the flow paths, salinity and chemical composition of SGD shows an extremely wide range, from potable water to TDS of >250 g/l. Submarine emerging groundwaters with salinities even higher then that of the Dead Sea and distinctly different chemical and isotopic composition form outlets, which are not known elsewhere and represent a novel and unique type of SGD, only observed in the Dead Sea yet.

Geochemical and isotopic determination of deep groundwater contributions and salinity to the shallow groundwater and surface water systems, Mesilla Basin, New Mexico, Texas, and Mexico

NASA Astrophysics Data System (ADS)

Robertson, A.; Carroll, K. C.; Kubicki, C.; Purtshert, R.

2017-12-01

The Mesilla Basin/Conejos-Médanos aquifer system, extending from southern New Mexico to Chihuahua, Mexico, is a priority transboundary aquifer under the 2006 United States­-Mexico Transboundary Aquifer Assessment Act. Declining water levels, deteriorating water quality, and increasing groundwater use by municipal, industrial, and agricultural users on both sides of the international border raise concerns about long-term aquifer sustainability. Relative contributions of present-day and "paleo" recharge to sustainable fresh groundwater yields has not been determined and evidence suggests that a large source of salinity at the distal end of the Mesilla Basin is saline discharge from deep groundwater flow. The magnitude and distribution of those deep saline flow paths are not determined. The contribution of deep groundwater to discharge and salinity in the shallow groundwater and surface water of the Mesilla Basin will be determined by collecting discrete groundwater samples and analyzing for aqueous geochemical and isotopic tracers, as well as the radioisotopes of argon and krypton. Analytes include major ions, trace elements, the stable isotopes of water, strontium and boron isotopes, uranium isotopes, the carbon isotopes of dissolved inorganic carbon, noble gas concentrations and helium isotope ratios. Dissolved gases are extracted and captured from groundwater wells using membrane contactors in a process known as ultra-trace sampling. Gas samples are analyzed for radioisotope ratios of krypton by the ATTA method and argon by low-level counting. Effectiveness of the ultra-trace sampling device and method was evaluated by comparing results of tritium concentrations to the krypton-85 content. Good agreement between the analyses, especially in samples with undetectable tritium, indicates that the ultra-trace procedure is effective and confirms that introduction of atmospheric air has not occurred. The geochemistry data indicate a complex system of geochemical

Insights into the Groundwater Salinization Processes in Manas River Basin, Northwest China

NASA Astrophysics Data System (ADS)

Jin, M.; Liu, Y.; Liang, X.

2017-12-01

Manas River Basin (MRB) is a typical mountains-oasis-desert inland basin in northwest China, where groundwater salinization is threatening the local water use and the environment, but the groundwater salinization process is not clear. Based on groundwater flow system analysis by integrating flow fields, hydrochemical and isotopic characteristics, a deuterium excess analytical method was used to quantitatively assess salinization mechanism and calculate the contribution ratios of evapoconcentration effect to the salinities. 73 groundwater samples and 11 surface water samples were collected from the basin. Hydrochemical diagrams and δD and δ18O compositions indicated that evapoconcentration, mineral dissolution and transpiration, increased the groundwater salinities (i.e. total dissolved solids). The results showed that the average contribution ratios of evapoconcentration effect to the increased salinities were 5.8% and 32.7% in groundwater and surface water, respectively. From the piedmont plain to the desert plain, the evapoconcentration effect increased the average groundwater loss from 7% to 29%. However, it only increased slight salinity (0 - 0.27 g/L), as determined from the deuterium excess signals. Minerals dissolution and anthropogenic activities are the major cause of groundwater salinization problem. The results revealed that fresh water in the rivers directly and quickly infiltrated the aquifers in the piedmont area with evapoconcentration affected weakly, and the fresh water interacted with the sediments and dissolved soluble minerals, subsequently increasing the salinities. Combined with the groundwater stable isotopic compositions and hydrochemical evolution, the relationships between δ18O and Cl and salinities reveal the soil evaporites leaching by the vertical recharge (irrigation return flow and channels leakage) mainly affect the groundwater salinization processes in the middle alluvial-diluvial plain and the desert land. The saline water

Simulation of ground-water discharge to Biscayne Bay, southeastern Florida

USGS Publications Warehouse

Langevin, Christian David

2001-01-01

As part of the Place-Based Studies Program, the U.S. Geological Survey initiated a project in 1996, in cooperation with the U.S. Army Corps of Engineers, to quantify the rates and patterns of submarine ground-water discharge to Biscayne Bay. Project objectives were achieved through field investigations at three sites (Coconut Grove, Deering Estate, and Mowry Canal) along the coastline of Biscayne Bay and through the development and calibration of variable-density, ground-water flow models. Two-dimensional, vertical cross-sectional models were developed for steady-state conditions for the Coconut Grove and Deering Estate transects to quantify local-scale ground-water discharge patterns to Biscayne Bay. A larger regional-scale model was developed in three dimensions to simulate submarine ground-water discharge to the entire bay. The SEAWAT code, which is a combined version of MODFLOW and MT3D, was used to simulate the complex variable-density flow patterns. Field data suggest that ground-water discharge to Biscayne Bay relative to the shoreline is restricted to within 300 meters at Coconut Grove, 600 to 1,000 meters at Deering Estate, and 100 meters at Mowry Canal. The vertical cross-sectional models, which were calibrated to the field data using the assumption of steady state, tend to focus ground-water discharge to within 50 to 200 meters of the shoreline. With homogeneous distributions for aquifer parameters and a constant-concentration boundary for Biscayne Bay, the numerical models could not reproduce the lower ground-water salinities observed beneath the bay, which suggests that further research may be necessary to improve the accuracy of the numerical simulations. Results from the cross-sectional models, which were able to simulate the approximate position of the saltwater interface, suggest that longitudinal dispersivity ranges between 1 and 10 meters, and transverse dispersivity ranges from 0.1 to 1 meter for the Biscayne aquifer. The three

Numerical Study of Groundwater Flow and Salinity Distribution Cycling Controlled by Seawater/Freshwater Interaction in Karst Aquifer Using SEAWAT

NASA Astrophysics Data System (ADS)

Xu, Z.; Hu, B.

2017-12-01

The interest to predict seawater intrusion and salinity distribution in Woodville Karst Plain (WKP) has increased due to the huge challenge on quality of drinkable water and serious environmental problems. Seawater intrudes into the conduit system from submarine karst caves at Spring Creek Spring due to density difference and sea level rising, nowadays the low salinity has been detected at Wakulla Spring which is 18 km from coastal line. The groundwater discharge at two major springs and salinity distribution in this area is controlled by the seawater/freshwater interaction under different rainfall conditions: during low rainfall periods, seawater flow into the submarine spring through karst windows, then the salinity rising at the submarine spring leads to seawater further intrudes into conduit system; during high rainfall periods, seawater is pushed out by fresh water discharge at submarine spring. The previous numerical studies of WKP mainly focused on the density independent transport modeling and seawater/freshwater discharge at major karst springs, in this study, a SEAWAT model has been developed to fully investigate the salinity distribution in the WKP under repeating phases of low rainfall and high rainfall periods, the conduit system was simulated as porous media with high conductivity and porosity. The precipitation, salinity and discharge at springs were used to calibrate the model. The results showed that the salinity distribution in porous media and conduit system is controlled by the rainfall change, in general, the salinity distribution inland under low rainfall conditions is much higher and wider than the high rainfall conditions. The results propose a prediction on the environmental problem caused by seawater intrusion in karst coastal aquifer, in addition, provide a visual and scientific basis for future groundwater remediation.

From submarine to lacustrine groundwater discharge

USGS Publications Warehouse

Lewandowski, Jörg; Meinikmann, Karin; Pöschke, Franziska; Nützmann, Gunnar; Rosenberry, Donald O.

2017-01-01

Submarine groundwater discharge (SGD) and its role in marine nutrient cycling are well known since the last decade. The freshwater equivalent, lacustrine groundwater discharge (LGD), is often still disregarded, although first reports of LGD are more than 50 years old. We identify nine different reasons why groundwater has long been disregarded in both freshwater and marine environments such as invisibility of groundwater discharge, the size of the interface and its difficult accessibility. Although there are some fundamental differences in the hydrology of SGD and LGD, caused primarily by seawater recirculation that occurs only in cases of SGD, there are also a lot of similarities such as a focusing of discharge to near-shore areas. Nutrient concentrations in groundwater near the groundwater–surface water interface might be anthropogenically enriched. Due to spatial heterogeneity of aquifer characteristics and biogeochemical processes, the quantification of groundwater-borne nutrient loads is challenging. Both nitrogen and phosphorus might be mobile in near-shore aquifers and in a lot of case studies large groundwater-borne nutrient loads have been reported.

Examining Submarine Ground-Water Discharge into Florida Bay by using 222Rn and Continuous Resistivity Profiling

USGS Publications Warehouse

Swarzenski, Peter; Reich, Chris; Rudnick, David

2009-01-01

Estimates of submarine ground-water discharge (SGD) into Florida Bay remain one of the least understood components of a regional water balance. To quantify the magnitude and seasonality of SGD into upper Florida Bay, research activities included the use of the natural geochemical tracer, 222Rn, to examine potential SGD hotspots (222Rn surveys) and to quantify the total (saline + fresh water component) SGD rates at select sites (222Rn time-series). To obtain a synoptic map of the 222Rn distribution within our study site in Florida Bay, we set up a flow-through system on a small boat that consisted of a Differential Global Positioning System, a calibrated YSI, Inc CTD sensor with a sampling rate of 0.5 min, and a submersible pump (z = 0.5 m) that continuously fed water into an air/water exchanger that was plumbed simultaneously into four RAD7 222Rn air monitors. To obtain local advective ground-water flux estimates, 222Rn time-series experiments were deployed at strategic positions across hydrologic and geologic gradients within our study site. These time-series stations consisted of a submersible pump, a Solinist DIVER (to record continuous CTD parameters) and two RAD7 222Rn air monitors plumbed into an air/water exchanger. Repeat time-series 222Rn measurements were conducted for 3-4 days across several tidal excursions. Radon was also measured in the air during each sampling campaign by a dedicated RAD7. We obtained ground-water discharge information by calculating a 222Rn mass balance that accounted for lateral and horizontal exchange, as well as an appropriate ground-water 222Rn end member activity. Another research component utilized marine continuous resistivity profiling (CRP) surveys to examine the subsurface salinity structure within Florida Bay sediments. This system consisted of an AGI SuperSting 8 channel receiver attached to a streamer cable that had two current (A,B) electrodes and nine potential electrodes that were spaced 10 m apart. A separate DGPS

Saline Groundwater from Coastal Aquifers As a Source for Desalination.

PubMed

Stein, Shaked; Russak, Amos; Sivan, Orit; Yechieli, Yoseph; Rahav, Eyal; Oren, Yoram; Kasher, Roni

2016-02-16

Reverse osmosis (RO) seawater desalination is currently a widespread means of closing the gap between supply and demand for potable water in arid regions. Currently, one of the main setbacks of RO operation is fouling, which hinders membrane performance and induces pressure loss, thereby reducing system efficiency. An alternative water source is saline groundwater with salinity close to seawater, pumped from beach wells in coastal aquifers which penetrate beneath the freshwater-seawater interface. In this research, we studied the potential use of saline groundwater of the coastal aquifer as feedwater for desalination in comparison to seawater using fieldwork and laboratory approaches. The chemistry, microbiology and physical properties of saline groundwater were characterized and compared with seawater. Additionally, reverse osmosis desalination experiments in a cross-flow system were performed, evaluating the permeate flux, salt rejection and fouling propensities of the different water types. Our results indicated that saline groundwater was significantly favored over seawater as a feed source in terms of chemical composition, microorganism content, silt density, and fouling potential, and exhibited better desalination performance with less flux decline. Saline groundwater may be a better water source for desalination by RO due to lower fouling potential, and reduced pretreatment costs.

Hydrogeology, distribution, and volume of saline groundwater in the southern midcontinent and adjacent areas of the United States

USGS Publications Warehouse

Osborn, Noël I.; Smith, S. Jerrod; Seger, Christian H.

2013-01-01

The hydrogeology, distribution, and volume of saline water in 22 aquifers in the southern midcontinent of the United States were evaluated to provide information about saline groundwater resources that may be used to reduce dependency on freshwater resources. Those aquifers underlie six States in the southern midcontinent—Arkansas, Kansas, Louisiana, Missouri, Oklahoma, and Texas—and adjacent areas including all or parts of Alabama, Colorado, Florida, Illinois, Kentucky, Mississippi, Nebraska, New Mexico, South Dakota, Tennessee, and Wyoming and some offshore areas of the Gulf of Mexico. Saline waters of the aquifers were evaluated by defining salinity zones; digitizing data, primarily from the Regional Aquifer-System Analysis Program of the U.S. Geological Survey; and computing the volume of saline water in storage. The distribution of saline groundwater in the southern midcontinent is substantially affected by the hydrogeology and groundwater-flow systems of the aquifers. Many of the aquifers in the southern midcontinent are underlain by one or more aquifers, resulting in vertically stacked aquifers containing groundwaters of varying salinity. Saline groundwater is affected by past and present hydrogeologic conditions. Spatial variation of groundwater salinity in the southern midcontinent is controlled primarily by locations of recharge and discharge areas, groundwater-flow paths and residence time, mixing of freshwater and saline water, and interactions with aquifer rocks and sediments. The volume calculations made for the evaluated aquifers in the southern midcontinent indicate that about 39,900 million acre-feet (acre-ft) of saline water is in storage. About 21,600 million acre-ft of the water in storage is slightly to moderately saline (1,000–10,000 milligrams per liter [mg/L] dissolved solids), and about 18,300 million acre-ft is very saline (10,000–35,000 mg/L dissolved solids). The largest volumes of saline water are in the coastal lowlands (about

Assessing submarine groundwater discharge (SGD) and nitrate fluxes in highly heterogeneous coastal karst aquifers: Challenges and solutions

NASA Astrophysics Data System (ADS)

Montiel, Daniel; Dimova, Natasha; Andreo, Bartolomé; Prieto, Jorge; García-Orellana, Jordi; Rodellas, Valentí

2018-02-01

Groundwater discharge in coastal karst aquifers worldwide represents a substantial part of the water budget and is a main pathway for nutrient transport to the sea. Groundwater discharge to the sea manifests under different forms, making its assessment very challenging particularly in highly heterogeneous coastal systems karst systems. In this study, we present a methodology approach to identify and quantify four forms of groundwater discharge in a mixed lithology system in southern Spain (Maro-Cerro Gordo) that includes an ecologically protected coastal area comprised of karstic marble. We found that groundwater discharge to the sea occurs via: (1) groundwater-fed creeks, (2) coastal springs, (3) diffuse groundwater seepage through seabed sediments, and (4) submarine springs. We used a multi-method approach combining tracer techniques (salinity, 224Ra, and 222Rn) and direct measurements (seepage meters and flowmeters) to evaluate the discharge. Groundwater discharge via submarine springs was the most difficult to assess due to their depth (up to 15 m) and extensive development of the springs conduits. We determined that the total groundwater discharge over the 16 km of shoreline of the study area was at least 11 ± 3 × 103 m3 d-1 for the four types of discharge assessed. Groundwater-derived nitrate (NO3-) fluxes to coastal waters over ∼3 km (or 20%) in a highly populated and farmed section of Maro-Cerro Gordo was 641 ± 166 mol d-1, or ∼75% of the total NO3- loading in the study area. We demonstrate in this study that a multi-method approach must be applied to assess all forms of SGD and derived nutrient fluxes to the sea in highly heterogeneous karst aquifer systems.

Numerical Simulation of Ground-Water Salinization in the Arkansas River Corridor, Southwest Kansas

NASA Astrophysics Data System (ADS)

Whittemore, D. O.; Perkins, S.; Tsou, M.; McElwee, C. D.; Zhan, X.; Young, D. P.

2001-12-01

The salinity of ground water in the High Plains aquifer underlying the upper Arkansas River corridor in southwest Kansas has greatly increased during the last few decades. The source of the salinization is infiltration of Arkansas River water along the river channel and in areas irrigated with diverted river water. The saline river water is derived from southeastern Colorado where consumptive losses of water in irrigation systems substantially concentrate dissolved solids in the residual water. Before development of surface- and ground-water resources, the Arkansas River gained flow along nearly all of its length in southwest Kansas. Since the 1970's, ground-water levels have declined in the High Plains aquifer from consumptive use of ground water. The water-level declines have now changed the river to a generally losing rather than gaining system. We simulated ground-water flow in the aquifers underlying 126 miles of the river corridor using MODFLOW integrated with the GIS software ArcView (Tsou and Whittemore, 2001). There are two layers in the model, one for the Quaternary alluvial aquifer and the other for the underlying High Plains aquifer. We prepared a simulation for circa 1940 that represented conditions prior to substantial ground-water development, and simulations for 40 years into the future that were based on holding constant either average water use or average ground-water levels for the 1990's. Streamflows along the river computed from the model results illustrated the flow gains from ground-water discharge for circa 1940 and losses during the 1990's. We modeled the movement of salinity as particle tracks generated by MODPATH based on the MODFLOW solutions. The results indicate that during the next 40 years, saline water will move a substantial distance in the High Plains aquifer on the south side of the central portion of the river valley. The differences between the circa 1940 and 1990's simulations fit the observed data that show large increases in

Characterization of mechanisms and processes of groundwater salinization in irrigated coastal area using statistics, GIS, and hydrogeochemical investigations.

PubMed

Bouzourra, Hazar; Bouhlila, Rachida; Elango, L; Slama, Fairouz; Ouslati, Naceur

2015-02-01

Coastal aquifers are at threat of salinization in most parts of the world. This study was carried out in coastal shallow aquifers of Aousja-Ghar El Melh and Kalâat el Andalous, northeastern of Tunisia with an objective to identify sources and processes of groundwater salinization. Groundwater samples were collected from 42 shallow dug wells during July and September 2007. Chemical parameters such as Na(+), Ca(2+), Mg(2+), K(+), Cl(-), SO4 (2-), HCO3 (-), NO3 (-), Br(-), and F(-) were analyzed. The combination of hydrogeochemical, statistical, and GIS approaches was used to understand and to identify the main sources of salinization and contamination of these shallow coastal aquifers as follows: (i) water-rock interaction, (ii) evapotranspiration, (iii) saltwater is started to intrude before 1972 and it is still intruding continuously, (iv) irrigation return flow, (v) sea aerosol spray, and finally, (vi) agricultural fertilizers. During 2005/2006, the overexploitation of the renewable water resources of aquifers caused saline water intrusion. In 2007, the freshening of a brackish-saline groundwater occurred under natural recharge conditions by Ca-HCO3 meteoric freshwater. The cationic exchange processes are occurred at fresh-saline interfaces of mixtures along the hydraulic gradient. The sulfate reduction process and the neo-formation of clays minerals characterize the hypersaline coastal Sebkha environments. Evaporation tends to increase the concentrations of solutes in groundwater from the recharge areas to the discharge areas and leads to precipitate carbonate and sulfate minerals.

The importance of submarine groundwater discharge to the nearshore nutrient supply in the Gulf of Aqaba (Israel)

USGS Publications Warehouse

Shellenbarger, G.G.; Monismith, Stephen G.; Genin, A.; Paytan, A.

2006-01-01

We used two short-lived radium isotopes (223Ra, 224Ra) and a mass balance approach applied to the radium activities to determine the nutrient contribution of saline submarine groundwater discharge to the coastal waters of the northern Gulf of Aqaba (Israel). Radium isotope activities were measured along transects during two seasons at a site that lacked any obvious surficial water input. An onshore well and an offshore end member were also sampled. For all samples, nutrients and salinity data were collected. Radium isotope activities generally decreased with distance offshore and exhibited significant tidal variability, which is consistent with a shore-derived tidally influenced source. Submarine groundwater contributes only 1-2% of the water along this coast, but this groundwater provides 8-46% of the nutrients. This saline groundwater is derived predominately from tidally pumped seawater percolating through the unconfined coastal aquifer and leaching radium and nutrients. This process represents a significant source of nutrients to the oligotrophic nearshore reef. ?? 2006, by the American Society of Limnology and Oceanography, Inc.

Contributions of groundwater conditions to soil and water salinization

NASA Astrophysics Data System (ADS)

Salama, Ramsis B.; Otto, Claus J.; Fitzpatrick, Robert W.

Salinization is the process whereby the concentration of dissolved salts in water and soil is increased due to natural or human-induced processes. Water is lost through one or any combination of four main mechanisms: evaporation, evapotranspiration, hydrolysis, and leakage between aquifers. Salinity increases from catchment divides to the valley floors and in the direction of groundwater flow. Salinization is explained by two main chemical models developed by the authors: weathering and deposition. These models are in agreement with the weathering and depositional geological processes that have formed soils and overburden in the catchments. Five soil-change processes in arid and semi-arid climates are associated with waterlogging and water. In all represented cases, groundwater is the main geological agent for transmitting, accumulating, and discharging salt. At a small catchment scale in South and Western Australia, water is lost through evapotranspiration and hydrolysis. Saline groundwater flows along the beds of the streams and is accumulated in paleochannels, which act as a salt repository, and finally discharges in lakes, where most of the saline groundwater is concentrated. In the hummocky terrains of the Northern Great Plains Region, Canada and USA, the localized recharge and discharge scenarios cause salinization to occur mainly in depressions, in conjunction with the formation of saline soils and seepages. On a regional scale within closed basins, this process can create playas or saline lakes. In the continental aquifers of the rift basins of Sudan, salinity increases along the groundwater flow path and forms a saline zone at the distal end. The saline zone in each rift forms a closed ridge, which coincides with the closed trough of the groundwater-level map. The saline body or bodies were formed by evaporation coupled with alkaline-earth carbonate precipitation and dissolution of capillary salts. Résumé La salinisation est le processus par lequel la

Submarine fresh groundwater discharge into Laizhou Bay comparable to the Yellow River flux

PubMed Central

Wang, Xuejing; Li, Hailong; Jiao, Jiu Jimmy; Barry, D. A.; Li, Ling; Luo, Xin; Wang, Chaoyue; Wan, Li; Wang, Xusheng; Jiang, Xiaowei; Ma, Qian; Qu, Wenjing

2015-01-01

Near- and off-shore fresh groundwater resources become increasingly important with the social and economic development in coastal areas. Although large scale (hundreds of km) submarine groundwater discharge (SGD) to the ocean has been shown to be of the same magnitude order as river discharge, submarine fresh groundwater discharge (SFGD) with magnitude comparable to large river discharge is never reported. Here, we proposed a method coupling mass-balance models of water, salt and radium isotopes based on field data of 223Ra, 226Ra and salinity to estimate the SFGD, SGD. By applying the method in Laizhou Bay (a water area of ~6000 km2), we showed that the SFGD and SGD are 0.57 ~ 0.88 times and 7.35 ~ 8.57 times the annual Yellow River flux in August 2012, respectively. The estimate of SFGD ranges from 4.12 × 107 m3/d to 6.36 × 107 m3/d, while SGD ranges from 5.32 × 108 m3/d to 6.20 × 108 m3/d. The proportion of the Yellow River input into Laizhou Bay was less than 14% of the total in August 2012. Our method can be used to estimate SFGD in various coastal waters. PMID:25742712

Groundwater Salinity Simulation of a Subsurface Reservoir in Taiwan

NASA Astrophysics Data System (ADS)

Fang, H. T.

2015-12-01

The subsurface reservoir is located in Chi-Ken Basin, Pescadores (a group islands located at western part of Taiwan). There is no river in these remote islands and thus the freshwater supply is relied on the subsurface reservoir. The basin area of the subsurface reservoir is 2.14 km2 , discharge of groundwater is 1.27×106m3 , annual planning water supplies is 7.9×105m3 , which include for domestic agricultural usage. The annual average temperature is 23.3oC, average moisture is 80~85%, annual average rainfall is 913 mm, but ET rate is 1975mm. As there is no single river in the basin; the major recharge of groundwater is by infiltration. Chi-Ken reservoir is the first subsurface reservoir in Taiwan. Originally, the water quality of the reservoir is good. The reservoir has had the salinity problem since 1991 and it became more and more serious from 1992 until 1994. Possible reason of the salinity problem was the shortage of rainfall or the leakage of the subsurface barrier which caused the seawater intrusion. The present study aimed to determine the leakage position of subsurface barrier that caused the salinity problem. In order to perform the simulation for different possible leakage position of the subsurface reservoir, a Groundwater Modeling System (GMS) is used to define soils layer data, hydro-geological parameters, initial conditions, boundary conditions and the generation of three dimension meshes. A three dimension FEMWATER(Yeh , 1996) numerical model was adopted to find the possible leakage position of the subsurface barrier and location of seawater intrusion by comparing the simulation of different possible leakage with the observations. 1.By assuming the leakage position in the bottom of barrier, the simulated numerical result matched the observation better than the other assumed leakage positions. It showed that the most possible leakage position was at the bottom of the barrier. 2.The research applied three dimension FEMWATER and GMS as an interface

Eolian transport, saline lake basins, and groundwater solutes

USGS Publications Warehouse

Wood, Warren W.; Sanford, Ward E.

1995-01-01

Eolian processes associated with saline lakes are shown to be important in determining solute concentration in groundwater in arid and semiarid areas. Steady state mass balance analyses of chloride in the groundwater at Double Lakes, a saline lake basin in the southern High Plains of Texas, United States, suggest that approximately 4.5 × 105 kg of chloride is removed from the relatively small (4.7 km2) basin floor each year by deflation. This mass enters the groundwater down the wind gradient from the lake, degrading the water quality. The estimates of mass transport were independently determined by evaluation of solutes in the unsaturated zone and by solute mass balance calculations of groundwater flux. Transport of salts from the lake was confirmed over a short term (2 years) by strategically placed dust collectors. Results consistent with those at Double Lake were obtained from dune surfaces collected upwind and downwind from a sabkha near the city of Abu Dhabi in the United Arab Emirates. The eolian transport process provides an explanation of the degraded groundwater quality associated with the 30–40 saline lake basins on the southern half of the southern High Plains of Texas and New Mexico and in many other arid and semiarid areas.

Intensities of groundwater pollution and salinization in Asian coastal cities

NASA Astrophysics Data System (ADS)

Onodera, S. I.; Saito, M.; Tomozawa, Y.; Shimizu, Y.; Admajaya, F. T.

2017-12-01

To confirm groundwater pollution and salinization intensities in various coastal Asian cities, we compared hydrogeological and chemical data at Osaka, Manila, Bangkok, and Jakarta as a mega-city and at Okayama and Marugame in western Japan as a small city. The groundwater depressions with heavy use caused intrusions of surface pollutants to deeper zone, that is, the expansion and diffusion of pollution. In addition, groundwater pollution originated from old sewage systems was found, especially in Osaka which is a developed city. Groundwater salinization was caused by seawater intrusion and leaching of saline component in sediment under the condition with lower hydraulic head at the deep groundwater than the sea level with urbanization. The former process is the contribution of present seawater, on the other hand the later is the contribution of palaeo-seawater in alluvial clay layer. The saline content in groundwater were 3.0x1010 t in Bangkok, 2.2x108 t in Osaka, 5.2x107 t in Jakarta, and 3.6x106 t in Manila, respectively. The subject area is one order wider in Bangkok than in Osaka, and two orders wider than in Manila and Jakarta. Such huge saline accumulation in Bangkok would be due to the lowest groundwater potential in present as well as the largest subject area. Deeper groundwater potential in Osaka has recovered since 1970, whereas those in Manila and Jakarta are declining. In addition, we estimated the palaeo-seawater content under the mega-cities as total pore volume in the alluvial clay. These values were estimated to be 5.5x109 t in Bangkok, 2.1x108 t in Osaka, 9.0x107 t in Jakarta, and 8.0x107 t in Manila, respectively. The comparative results of accumulative contents and palaeo-values indicated that accumulative contents were more than the others in Bangkok and Osaka. These results suggest that seawater intrusion occurred as well as palaeo-water leaching in these cities. In addition, that shows the urbanization period is important to salinization

Tracing submarine groundwater discharge flux in Tolo Harbor, Hong Kong (China)

NASA Astrophysics Data System (ADS)

Liu, Yi; Jiao, Jiu Jimmy; Cheng, Ho Kwan

2018-02-01

Submarine groundwater discharge (SGD) is an important pathway for groundwater and associated chemicals to discharge to the sea. Groundwater levels monitored along a transect perpendicular to the shoreline are used to calculate SGD flux from the nearshore aquifer to Tolo Harbor, Hong Kong (China). The calculated SGD flux—recharge/discharge measured with Darcy's Law methods—agrees well with estimates based on geo-tracer techniques and seepage meter in Tolo Harbor during previous studies. The estimated freshwater SGD is 1.69-2.0 m2/d at the study site and 0.3 ± 0.04 cm/d for the whole of Tolo Harbor, which is comparable to the river discharge (0.25 ± 0.07 cm/d) and precipitation (0.45 ± 0.15 cm/d). The tide-driven SGD in the intertidal zone is 13.98-17.59 m2/d at the study site and 2.42 ± 0.56 cm/d for the whole of Tolo Harbor. The SGD occurring in the subtidal zone and the bottom of Tolo Harbor is 3.12 ± 4.63 cm/d. Fresh SGD accounts for 5% of the total SGD, while the rest ( 95%) is contributed by saline SGD driven by various forces. About 96% of the tide-driven SGD in the intertidal zone occurs in the ebbing tide period because the head difference between the groundwater level and sea level is great during this period. Tide-driven SGD in the spring tide is 1.2 times that during neap tide. The tidal fluctuation amplitude and tide-driven SGD in the intertidal zone are positively correlated to each other; thus, a spring neap variation of the tide-driven SGD is observed.

Minimal groundwater leakage restricts salinity in a hydrologically terminal basin of northwest Australia

NASA Astrophysics Data System (ADS)

Skrzypek, Grzegorz; Dogramaci, Shawan; Rouillard, Alexandra; Grierson, Pauline

2016-04-01

The Fortescue Marsh (FM) is one of the largest wetlands of arid northwest Australia (~1200 km2) and is thought to act as a terminal basin for the Upper Fortescue River catchment. Unlike the playa lake systems that predominate in most arid regions, where salinity is driven by inflow and evaporation of groundwater, the hydrological regime of the FM is driven by inundation from irregular cyclonic events [1]. Surface water of the FM is fresh to brackish and the salinity of the deepest groundwater (80 m b.g.l.) does not exceed 160 g/L; salt efflorescences are rarely present on the surface [2]. In this study, we tested the hypothesis that persistent but low rates of groundwater outflow have restricted the accumulation of salt in the FM over time. Using hydrological, hydrochemical data and dimensionless time evaporation modelling along with the water and salt budget, we calculated the time and the annual groundwater discharge volume that would be required to achieve and maintain the range of salinity levels observed in the Marsh. Groundwater outflow from alluvial and colluvial aquifers to the Lower Fortescue catchment is limited by an extremely low hydraulic gradient of 0.001 and is restricted to a relatively small 'alluvial window' of 0.35 km2 because of the elevation of the basement bedrock at the Marsh outflow. We show that if the Marsh was 100% "leakage free" i.e., a true terminal basin for the Upper Fortescue Catchment, the basin water would have achieved salt saturation after ~45 ka. This is not the case and only a very small outflow of saline groundwater of <2 GL/yr (<0.03% of the FM water volume) is needed to maintain the current salinity conditions. The minimum time required to develop the current hydrochemical composition of the water in the Marsh and the steady-state conditions for salt concentration is between 58 and 164 ka. This is a minimum age of the Marsh but it can be much older as nearly steady-state conditions could be maintained infinitely. Our

Impact of topography on groundwater salinization due to ocean surge inundation

NASA Astrophysics Data System (ADS)

Yu, Xuan; Yang, Jie; Graf, Thomas; Koneshloo, Mohammad; O'Neal, Michael A.; Michael, Holly A.

2016-08-01

Sea-level rise and increases in the frequency and intensity of ocean surges caused by climate change are likely to exacerbate adverse effects on low-lying coastal areas. The landward flow of water during ocean surges introduces salt to surficial coastal aquifers and threatens groundwater resources. Coastal topographic features (e.g., ponds, dunes, barrier islands, and channels) likely have a strong impact on overwash and salinization processes, but are generally highly simplified in modeling studies. To understand topographic impacts on groundwater salinization, we modeled a theoretical overwash event and variable-density groundwater flow and salt transport in 3-D using the fully coupled surface and subsurface numerical simulator, HydroGeoSphere. The model simulates the coastal aquifer as an integrated system considering overland flow, coupled surface and subsurface exchange, variably saturated flow, and variable-density groundwater flow. To represent various coastal landscape types, we simulated both synthetic fields and real-world coastal topography from Delaware, USA. The groundwater salinization assessment suggested that the topographic connectivity promoting overland flow controls the volume of aquifer that is salinized. In contrast, the amount of water that can be stored in surface depressions determines the amount of seawater that infiltrates the subsurface and the time for seawater to flush from the aquifer. Our study suggests that topography has a significant impact on groundwater salinization due to ocean surge overwash, with important implications for coastal land management and groundwater vulnerability assessment.

Fresh-water discharge salinity relations in the tidal Delaware River

USGS Publications Warehouse

Keighton, Walter B.

1966-01-01

Sustained flows of fresh water greater than 3,500, 4,400, and 5,300 cubic feet per second into the Delaware River estuary at Trenton, NJ assure low salinity at League Island, Eddystone, and Marcus Hook, respectively. When the discharge at Trenton is less than these critical values, salinity is very sensitive to change in discharge, so that a relatively small decrease in fresh-water discharge results in a relatively great increase in salinity. Comparison of the discharge-salinity relations observed for the 14-year period August 1949-December 1963 with relations proposed by other workers but based on other time periods indicate that such relations change with time and that salinity is affected not only by discharge but also by dredging; construction of breakwater, dikes, and tidal barriers; changing sea level; tidal elevation; tidal range; and wind intensity and direction.

Cl/Br ratios and chlorine isotope evidences for groundwater salinization and its impact on groundwater arsenic, fluoride and iodine enrichment in the Datong basin, China.

PubMed

Li, Junxia; Wang, Yanxin; Xie, Xianjun

2016-02-15

In order to identify the salinization processes and its impact on arsenic, fluoride and iodine enrichment in groundwater, hydrogeochemical and environmental isotope studies have been conducted on groundwater from the Datong basin, China. The total dissolved solid (TDS) concentrations in groundwater ranged from 451 to 8250 mg/L, and 41% of all samples were identified as moderately saline groundwater with TDS of 3000-10,000 mg/L. The results of groundwater Cl concentrations, Cl/Br molar ratio and Cl isotope composition suggest that three processes including water-rock interaction, surface saline soil flushing, and evapotranspiration result in the groundwater salinization in the study area. The relatively higher Cl/Br molar ratio in groundwater from multiple screening wells indicates the contribution of halite dissolution from saline soil flushed by vertical infiltration to the groundwater salinization. However, the results of groundwater Cl/Br molar ratio model indicate that the effect of saline soil flushing practice is limited to account for the observed salinity variation in groundwater. The plots of groundwater Cl vs. Cl/Br molar ratio, and Cl vs δ(37)Cl perform the dominant effects of evapotranspiration on groundwater salinization. Inverse geochemical modeling results show that evapotranspiration may cause approximately 66% loss of shallow groundwater to account for the observed hydrochemical pattern. Due to the redox condition fluctuation induced by irrigation activities and evapotranspiration, groundwater salinization processes have negative effects on groundwater arsenic enrichment. For groundwater iodine and fluoride enrichment, evapotranspiration partly accounts for their elevation in slightly saline water. However, too strong evapotranspiration would restrict groundwater fluoride concentration due to the limitation of fluorite solubility. Copyright © 2015. Published by Elsevier B.V.

Chemistry of groundwater discharge inferred from longitudinal river sampling

NASA Astrophysics Data System (ADS)

Batlle-Aguilar, J.; Harrington, G. A.; Leblanc, M.; Welch, C.; Cook, P. G.

2014-02-01

We present an approach for identifying groundwater discharge chemistry and quantifying spatially distributed groundwater discharge into rivers based on longitudinal synoptic sampling and flow gauging of a river. The method is demonstrated using a 450 km reach of a tropical river in Australia. Results obtained from sampling for environmental tracers, major ions, and selected trace element chemistry were used to calibrate a steady state one-dimensional advective transport model of tracer distribution along the river. The model closely reproduced river discharge and environmental tracer and chemistry composition along the study length. It provided a detailed longitudinal profile of groundwater inflow chemistry and discharge rates, revealing that regional fractured mudstones in the central part of the catchment contributed up to 40% of all groundwater discharge. Detailed analysis of model calibration errors and modeled/measured groundwater ion ratios elucidated that groundwater discharging in the top of the catchment is a mixture of local groundwater and bank storage return flow, making the method potentially useful to differentiate between local and regional sourced groundwater discharge. As the error in tracer concentration induced by a flow event applies equally to any conservative tracer, we show that major ion ratios can still be resolved with minimal error when river samples are collected during transient flow conditions. The ability of the method to infer groundwater inflow chemistry from longitudinal river sampling is particularly attractive in remote areas where access to groundwater is limited or not possible, and for identification of actual fluxes of salts and/or specific contaminant sources.

Abacus to determine soils salinity in presence of saline groundwater in arid zones case of the region of Ouargla

NASA Astrophysics Data System (ADS)

Fergougui, Myriam Marie El; Benyamina, Hind; Boutoutaou, Djamel

2018-05-01

In order to remedy the limit of salt intake to the soil surface, it is necessary to study the causes of the soil salinity and find the origin of these salts. The arid areas in the region of Ouargla lie on excessively mineralized groundwater whose level is near the soil surface (0 - 1.5 m). The topography and absence of a reliable drainage system led to the rise of the groundwater beside the arid climatic conditions contributed to the salinization and hydromorphy of the soils. The progress and stabilization of cultures yields in these areas can only occur if the groundwater is maintained (drained) to a depth of 1.6 m. The results of works done to the determination of soil salinity depend mainly on the groundwater's salinity, its depth and the climate.

Quantity and quality of groundwater discharge in a hypersaline lake environment

USGS Publications Warehouse

Anderson, R.B.; Naftz, D.L.; Day-Lewis, F. D.; Henderson, R.D.; Rosenberry, D.O.; Stolp, B.J.; Jewell, P.

2014-01-01

Geophysical and geochemical surveys were conducted to understand groundwater discharge to Great Salt Lake (GSL) and assess the potential significance of groundwater discharge as a source of selenium (Se). Continuous resistivity profiling (CRP) focusing below the sediment/water interface and fiber-optic distributed temperature sensing (FO-DTS) surveys were conducted along the south shore of GSL. FO-DTS surveys identified persistent cold-water temperature anomalies at 10 separate locations. Seepage measurements were conducted at 17 sites (mean seepage rate = 0.8 cm/day). High resistivity anomalies identified by the CRP survey were likely a mirabilite (Na2SO4·10H2O) salt layer acting as a semi-confining layer for the shallow groundwater below the south shore of the lake. Positive seepage rates measured along the near-shore areas of GSL indicate that a ∼1-m thick oolitic sand overlying the mirabilite layer is likely acting as a shallow, unconfined aquifer. Using the average seepage rate of 0.8 cm/day over an area of 1.6 km2, an annual Se mass loading to GSL of 23.5 kg was estimated. Determination of R/Ra values (calculated 3He/4He ratio over the present-day atmospheric 3He/4He ratio) 34S and δ18O isotopic values in samples of dissolved sulfate from the shallow groundwater below the mirabilite are almost identical to the isotopic signature of the mirabilite core material. The saturation index calculated for groundwater samples using PHREEQC indicates the water is at equilibrium with mirabilite. Water samples collected from GSL immediately off shore contained Se concentrations that were 3–4 times higher than other sampling sites >25 km offshore from the study site and may be originating from less saline groundwater seeps mixing with the more saline water from GSL. Additional evidence for mixing with near shore seeps is found in the δD and δ18O isotopic values and Br:Cl ratios. Geochemical modeling for a water sample collected in the vicinity of the study area

FRESHEM - Fresh-saline groundwater distribution in Zeeland (NL) derived from airborne EM

NASA Astrophysics Data System (ADS)

Siemon, Bernhard; van Baaren, Esther; Dabekaussen, Willem; Delsman, Joost; Gunnik, Jan; Karaoulis, Marios; de Louw, Perry; Oude Essink, Gualbert; Pauw, Pieter; Steuer, Annika; Meyer, Uwe

2017-04-01

In a setting of predominantly saline surface waters, the availability of fresh water for agricultural purposes is not obvious in Zeeland, The Netherlands. Canals and ditches are mainly brackish to saline due to saline seepage, which originates from old marine deposits and salt-water transgressions during historical times. The only available fresh groundwater is present in the form of freshwater lenses floating on top of the saline groundwater. This fresh groundwater is vital for agricultural, industrial, ecological, water conservation and drinking water functions. An essential first step for managing this fresh groundwater properly is to know the present spatial fresh-brackish-saline groundwater distribution. As traditional salinity monitoring is labour-intensive, airborne electromagnetics (AEM), which is fast and can cover large areas in short time, is an efficient alternative. A consortium of BGR, Deltares and TNO started FRESHEM Zeeland (FREsh Salt groundwater distribution by Helicopter ElectroMagnetic survey in the Province of Zeeland) in October 2014. Within 3x2 weeks of the first project year, the entire area of about 2000 km2 was surveyed using BGR's helicopter-borne geophysical system totalling to about 10,000 line-km. The HEM datasets of 17 subareas were carefully processed using advanced BGR in-house software and inverted to 2.5 Million resistivity-depth models. Ground truthing demonstrated that the large-scale HEM results fit very well with small-scale ground EM data (ECPT). Based on this spatial resistivity distribution, a 3D voxel model for Chloride concentration was derived for the entire province taking into account geological model data (GeoTOP) for the lithology correction and local in-situ groundwater measurements for the translation of water conductivity to Chloride concentration. The 3D voxel model enables stakeholders to implement spatial Chloride concentration in their groundwater models.

Impact of heterogeneity on groundwater salinization due to coastal pumping

NASA Astrophysics Data System (ADS)

Yu, X.; Michael, H. A.

2017-12-01

Groundwater abstraction causes and accelerates seawater intrusion in many coastal areas. In heterogeneous aquifers, preferential flow paths can lead to fast intrusion, while low permeability layers can serve as barriers. The extent to which different types of heterogeneous aquifers are vulnerable to pumping-induced seawater intrusion has not been well studied. Here we show that the connectedness of pumping location and local boundary condition drive salinization patterns. Salinization patterns in homogeneous aquifers were relatively simple and only related to the hydraulic properties and pumping rate. The salinization rates and patterns in heterogeneous aquifers were much more complicated and related to pumping location, rate and depth, preferential flow path locations, and local boundary conditions. An intrusion classification approach was developed with three types in homogeneous aquifers and four types in heterogeneous aquifers. After classification the main factors of salinized areas, intrusion rates and salinization time could be identified. The ranges of these salinization assessment criteria suggested different aspect of groundwater vulnerability in each class. We anticipate the classification approach to be a starting point for more comprehensive groundwater abstraction vulnerability assessment (including consideration of pumping rates, locations and depths, connectivity, preferential flow paths, etc.), which is critical for coastal water resources management.

Impact of Groundwater Salinity on Bioremediation Enhanced by Micro-Nano Bubbles

PubMed Central

Li, Hengzhen; Hu, Liming; Xia, Zhiran

2013-01-01

Micro-nano bubbles (MNBs) technology has shown great potential in groundwater bioremediation because of their large specific surface area, negatively charged surface, long stagnation, high oxygen transfer efficiency, etc. Groundwater salinity, which varies from sites due to different geological and environmental conditions, has a strong impact on the bioremediation effect. However, the groundwater salinity effect on MNBs’ behavior has not been reported. In this study, the size distribution, oxygen transfer efficiency and zeta potential of MNBs was investigated in different salt concentrations. In addition, the permeability of MNBs’ water through sand in different salt concentrations was studied. The results showed that water salinity has no influence on bubble size distribution during MNBs generation. MNBs could greatly enhance the oxygen transfer efficiency from inner bubbles to outer water, which may greatly enhance aerobic bioremediation. However, the enhancement varied depending on salt concentration. 0.7 g/L was found to be the optimal salt concentration to transfer oxygen. Moreover, MNBs in water salinity of 0.7 g/L had the minimum zeta potential. The correlation of zeta potential and mass transfer was discussed. The hydraulic conductivities of sand were similar for MNBs water with different salt concentrations. The results suggested that salinity had a great influence on MNBs performance, and groundwater salinity should be taken into careful consideration in applying MNBs technology to the enhancement of bioremediation. PMID:28788299

Initial studies of submarine groundwater discharge in Mississippi coastal waters

NASA Astrophysics Data System (ADS)

Shiller, A. M.; Moore, W. S.; Joung, D. J.; Box, H.; Ho, P.; Whitmore, L. M.; Gilbert, M.; Anderson, H.

2017-12-01

Submarine groundwater discharge (SGD) is a critical component of coastal ecosystems, affecting biogeochemistry and productivity. The SGD flux and effect on the ecosystem of the Mississippi (MS) Bight has not previously been studied. We have determined Ba, δ18O of water, and Ra-isotopes, together with nutrients, chlorophyll, and dissolved oxygen (DO) during multiple cruises from fall 2015 to summer 2016. Water isotope distributions (δ18O) show that, although the MS River Delta bounds the western side of the Bight, nonetheless, Mobile Bay and other local rivers are the Bight's dominant freshwater sources. But elevated dissolved Ba and Ra isotopes cannot be explained by river input. Spatially, SGD in the MS Bight occurs over a wide area, with hot spots near the barrier islands (e.g., Chandeleurs, Horn and Dauphin Islands) and the mouth of Mobile Bay, probably in association with old buried river channels, or dredged ship channels. Based on their high concentrations in saline groundwaters sampled on the barrier islands, the elevated Ba and Ra in MS Bight water are likely due to SGD. In subsurface waters, long-lived Ra isotopes were negatively correlated with DO during spring and summer 2016, suggesting direct discharge of DO-depleted groundwater and/or accumulation of SGD-derived Ra and microbial DO consumption under strongly stratified conditions. Our ongoing study suggests that seasonal variability in flushing, water stratification, and SGD input play important roles in biological production and bottom water hypoxia in the MS Bight.

Groundwater salinity in a floodplain forest impacted by saltwater intrusion

NASA Astrophysics Data System (ADS)

Kaplan, David A.; Muñoz-Carpena, Rafael

2014-11-01

Coastal wetlands occupy a delicate position at the intersection of fresh and saline waters. Changing climate and watershed hydrology can lead to saltwater intrusion into historically freshwater systems, causing plant mortality and loss of freshwater habitat. Understanding the hydrological functioning of tidally influenced floodplain forests is essential for advancing ecosystem protection and restoration goals, however finding direct relationships between hydrological inputs and floodplain hydrology is complicated by interactions between surface water, groundwater, and atmospheric fluxes in variably saturated soils with heterogeneous vegetation and topography. Thus, an alternative method for identifying common trends and causal factors is required. Dynamic factor analysis (DFA), a time series dimension reduction technique, models temporal variation in observed data as linear combinations of common trends, which represent unexplained common variability, and explanatory variables. DFA was applied to model shallow groundwater salinity in the forested floodplain wetlands of the Loxahatchee River (Florida, USA), where altered watershed hydrology has led to changing hydroperiod and salinity regimes and undesired vegetative changes. Long-term, high-resolution groundwater salinity datasets revealed dynamics over seasonal and yearly time periods as well as over tidal cycles and storm events. DFA identified shared trends among salinity time series and a full dynamic factor model simulated observed series well (overall coefficient of efficiency, Ceff = 0.85; 0.52 ≤ Ceff ≤ 0.99). A reduced multilinear model based solely on explanatory variables identified in the DFA had fair to good results (Ceff = 0.58; 0.38 ≤ Ceff ≤ 0.75) and may be used to assess the effects of restoration and management scenarios on shallow groundwater salinity in the Loxahatchee River floodplain.

Groundwater salinity in a floodplain forest impacted by saltwater intrusion.

PubMed

Kaplan, David A; Muñoz-Carpena, Rafael

2014-11-15

Coastal wetlands occupy a delicate position at the intersection of fresh and saline waters. Changing climate and watershed hydrology can lead to saltwater intrusion into historically freshwater systems, causing plant mortality and loss of freshwater habitat. Understanding the hydrological functioning of tidally influenced floodplain forests is essential for advancing ecosystem protection and restoration goals, however finding direct relationships between hydrological inputs and floodplain hydrology is complicated by interactions between surface water, groundwater, and atmospheric fluxes in variably saturated soils with heterogeneous vegetation and topography. Thus, an alternative method for identifying common trends and causal factors is required. Dynamic factor analysis (DFA), a time series dimension reduction technique, models temporal variation in observed data as linear combinations of common trends, which represent unexplained common variability, and explanatory variables. DFA was applied to model shallow groundwater salinity in the forested floodplain wetlands of the Loxahatchee River (Florida, USA), where altered watershed hydrology has led to changing hydroperiod and salinity regimes and undesired vegetative changes. Long-term, high-resolution groundwater salinity datasets revealed dynamics over seasonal and yearly time periods as well as over tidal cycles and storm events. DFA identified shared trends among salinity time series and a full dynamic factor model simulated observed series well (overall coefficient of efficiency, Ceff=0.85; 0.52≤Ceff≤0.99). A reduced multilinear model based solely on explanatory variables identified in the DFA had fair to good results (Ceff=0.58; 0.38≤Ceff≤0.75) and may be used to assess the effects of restoration and management scenarios on shallow groundwater salinity in the Loxahatchee River floodplain. Copyright © 2014 Elsevier B.V. All rights reserved.

What Controls Submarine Groundwater Discharge?

NASA Astrophysics Data System (ADS)

Martin, J. B.; Cable, J. E.; Cherrier, J.; Roy, M.; Smith, C. G.; Dorsett, A.

2008-05-01

Numerous processes have been implicated in controlling submarine groundwater discharge (SGD) to coastal zones since Ghyben, Herzberg and Dupuit developed models of fresh water discharge from coastal aquifers at the turn of the 19th century. Multiple empirical and modeling techniques have also been applied to these environments to measure the flow. By the mid-1950's, Cooper had demonstrated that dispersion across the fresh water-salt water boundary required salt water entrained into fresh water flow be balanced by recharge of salt water across the sediment-water interface seaward of the outflow face. Percolation of water into the beach face from wind and tidal wave run up and changes in pressure at the sediment-water interface with fluctuating tides have now been recognized, and observed, as processes driving seawater into the sediments. Within the past few years, variations in water table levels and the 1:40 amplification from density difference in fresh water and seawater have been implicated to pump salt water seasonally across the sediment- water interface. Salt water driven by waves, tides and seasonal water table fluctuations is now recognized as a component of SGD when it flows back to overlying surface waters. None of these processes are sufficiently large to provide measured volumes of SGD in Indian River Lagoon, Florida, however, because minimal tides and waves exist, flat topography and transmissive aquifers minimize fluctuations of the water table, and little water is entrained across the salt water-fresh water boundary. Nonetheless, the saline fraction of SGD represents more than 99% of the volume of total SGD in the Indian River Lagoon. This volume of saline SGD can be driven by the abundance of burrowing organisms in the lagoon, which pump sufficient amounts of water through the sediment- water interface. These bioirrigating organisms are ubiquitous at all water depths in sandy sediment and thus may provide one of the major sources of SGD world wide

Role of aquifer heterogeneity in fresh groundwater discharge and seawater recycling: An example from the Carmel coast, Israel

USGS Publications Warehouse

Weinstein, Y.; Burnett, W.C.; Swarzenski, P.W.; Shalem, Y.; Yechieli, Y.; Herut, B.

2007-01-01

A case study is shown in which the pattern of submarine groundwater discharge and of seawater recycling is controlled by local hydrogeological variability. The coastal aquifer in Dor Bay is composed of two units: a partly confined calcaranitic sandstone (Kurkar) and an overlying loose sand. Groundwater in the Kurkar has elevated activities of 222Rn (∼390 dpm/L) and relatively low 224Ra/223Ra activity ratios (3–4), while the sand groundwater is significantly less radiogenic (6–90 dpm/L) and shows higher 224Ra/223Ra ratios. Groundwater discharging from sand-covered areas of the bay has salinities of 16–31 and an average 222Rn activity of 168 dpm/L, which lies on a mixing line between Rn-rich Kurkar fresh water and Rn-poor seawater. Another key observation is that seawater infiltrates to some extent into onshore sand groundwater, while the fresh water within the submarine Kurkar can be traced up to 40 m offshore. This implies that while fresh water mainly discharges from the Kurkar unit, seawater recycling is limited to the loose sand, and that the discharge from sand-covered areas is a mixture of Kurkar water with recycled seawater. Advection rates from the bay floor were calculated from Rn time series and found to vary between 0 and 36 cm/d, correlating negatively with bay water depth. The average flux was 8.1 cm/d, and it did not seem to change much during March, May, and July 2006. The average amount of fresh water discharging to the bay was 5.0 m3/d per meter of shoreline. Radon activity in the sand groundwater also fluctuates due to influx of Kurkar-type groundwater.

Methodological study of submarine groundwater discharge from a karstic aquifer in the Western Mediterranean Sea

NASA Astrophysics Data System (ADS)

Mejías, Miguel; Ballesteros, Bruno J.; Antón-Pacheco, Carmen; Domínguez, José A.; Garcia-Orellana, Jordi; Garcia-Solsona, Ester; Masqué, Pere

2012-09-01

SummaryA multiproxy approach of complementary techniques is applied to localise and quantify submarine groundwater discharge (SGD) from El Maestrazgo Jurassic aquifer, an example of widespread carbonate coastal aquifer of the Western Mediterranean Sea (Castellón, Spain). Unconventional water resources are critical in this area where highly populated resorts have been developed. The aquifer has two main features of particular interest: a karstic system with a deep saturated zone reaching 450 m and with no significant surface discharge occurring within the continental area. On the other hand, SGD can alter the condition of coastal marine environments, reducing salinities and providing nutrients that can cause eutrophication and algal blooms. The applied combined techniques make it possible to detect groundwater outflows using airborne thermal infrared (TIR) images to monitor physico-chemical anomalies in the sea and to quantify the submarine groundwater discharges by means of direct measurements and radium isotopic analyses. Three main coastal areas affected by SGD and a submarine spring located at 3 km from the coast, which seems to be associated with tectonic discontinuities, were localised. The calculated fresh SGD from Ra isotopes, 375 Mm3 y-1, is in agreement with the mean aquifer recharge obtained by hydrogeological methods, 394 Mm3 y-1.

Salinization of groundwater around underground LPG storage caverns, Korea : statistical interpretation

NASA Astrophysics Data System (ADS)

Lee, J.; Chang, H.

2001-12-01

In this research, we investigate the reciprocal influence between groundwater flow and its salinization occurred in two underground cavern sites, using major ion chemistry, PCA for chemical analysis data, and cross-correlation for various hydraulic data. The study areas are two underground LPG storage facilities constructed in South Sea coast, Yosu, and West Sea coastal regions, Pyeongtaek, Korea. Considerably high concentration of major cations and anions of groundwaters at both sites showed brackish or saline water types. In Yosu site, some great chemical difference of groundwater samples between rainy and dry season was caused by temporal intrusion of high-saline water into propane and butane cavern zone, but not in Pyeongtaek site. Cl/Br ratios and δ 18O- δ D distribution for tracing of salinization source water in both sites revealed that two kind of saline water (seawater and halite-dissolved solution) could influence the groundwater salinization in Yosu site, whereas only seawater intrusion could affect the groundwater chemistry of the observation wells in Pyeongtaek site. PCA performed by 8 and 10 chemical ions as statistical variables in both sites showed that intensive intrusion of seawater through butane cavern was occurred at Yosu site while seawater-groundwater mixing was observed at some observation wells located in the marginal part of Pyeongtaek site. Cross-correlation results revealed that the positive relationship between hydraulic head and cavern operating pressure was far more conspicuous at propane cavern zone in both sites (65 ~90% of correlation coefficients). According to the cross-correlation results of Yosu site, small change of head could provoke massive influx of halite-dissolved solution from surface through vertically developed fracture networks. However in Pyeongtaek site, the pressure-sensitive observation wells are not completely consistent with seawater-mixed wells, and the hydraulic change of heads at these wells related to the

Machine Learning for Mapping Groundwater Salinity with Oil Well Log Data

NASA Astrophysics Data System (ADS)

Chang, W. H.; Shimabukuro, D.; Gillespie, J. M.; Stephens, M.

2016-12-01

An oil field may have thousands of wells with detailed petrophysical logs, and far fewer direct measurements of groundwater salinity. Can the former be used to extrapolate the latter into a detailed map of groundwater salinity? California Senate Bill 4, with its requirement to identify Underground Sources of Drinking Water, makes this a question worth answering. A well-known obstacle is that the basic petrophysical equations describe ideal scenarios ("clean wet sand") and even these equations contain many parameters that may vary with location and depth. Accounting for other common scenarios such as high-conductivity shaly sands or low-permeability diatomite (both characteristic of California's Central Valley) causes parameters to proliferate to the point where the model is underdetermined by the data. When parameters outnumber data points, however, is when machine learning methods are most advantageous. We present a method for modeling a generic oil field, where groundwater salinity and lithology are depth series parameters, and the constants in petrophysical equations are scalar parameters. The data are well log measurements (resistivity, porosity, spontaneous potential, and gamma ray) and a small number of direct groundwater salinity measurements. Embedded in the model are petrophysical equations that account for shaly sand and diatomite formations. As a proof of concept, we feed in well logs and salinity measurements from the Lost Hills Oil Field in Kern County, California, and show that with proper regularization and validation the model makes reasonable predictions of groundwater salinity despite the large number of parameters. The model is implemented using Tensorflow, which is an open-source software released by Google in November, 2015 that has been rapidly and widely adopted by machine learning researchers. The code will be made available on Github, and we encourage scrutiny and modification by machine learning researchers and hydrogeologists alike.

Continuous resistivity profiling to delineate submarine groundwater discharge - Examples and limitations

USGS Publications Warehouse

Day-Lewis, F. D.; White, E.A.; Johnson, C.D.; Lane, J.W.; Belaval, M.

2006-01-01

Aquifer-ocean interaction, saline intrusion, and submarine groundwater discharge (SGD) are emerging topics in hydrology and oceanography with important implications for water-resource management and estuarine ecology. Although the threat of saltwater intrusion has long been recognized in coastal areas, SGD has, until recently, received much less attention. It is clear that SGD constitutes a major nutrient flux to coastal waters, with implications for estuarine ecology, eutrophication, and loss of coral reefs; however, fundamental questions regarding SGD remain unanswered: What are the spatial and temporal distributions of SGD offshore? How do seasonal and storm-related variations in aquifer recharge affect SGD flux and nutrient loading? What controls do aquifer structure and heterogeneity impose? How are SGD and saline recirculation related? Geophysical methods can provide insights to help answer these questions and improve the understanding of this intriguing and environmentally relevant hydrologic phenomenon. ?? 2006 Society of Exploration Geophysicists.

Characterisation of the Subaquatic Groundwater Discharge That Maintains the Permanent Stratification within Lake Kivu; East Africa

PubMed Central

Ross, Kelly Ann; Gashugi, Elisée; Gafasi, Augustin; Wüest, Alfred; Schmid, Martin

2015-01-01

Warm and cold subaquatic groundwater discharge into Lake Kivu forms the large-scale density gradients presently observed in the lake. This structure is pertinent to maintaining the stratification that locks the high volume of gases in the deepwater. Our research presents the first characterisation of these inflows. Temperature and conductivity profiling was conducted from January 2010 to March 2013 to map the locations of groundwater discharge. Water samples were obtained within the lake at the locations of the greatest temperature anomalies observed from the background lake-profile. The isotopic and chemical signatures of the groundwater were applied to assess how these inflows contribute to the overall stratification. It is inferred that Lake Kivu’s deepwater has not been completely recharged by the groundwater inflows since its turnover that is speculated to have occurred within the last ~1000 yrs. Given a recent salinity increase in the lake constrained to within months of seismic activity measured beneath the basin, it is plausible that increased hydrothermal-groundwater inflows into the deep basin are correlated with episodic geologic events. These results invalidate the simple two-component end-member mixing regime that has been postulated up to now, and indicate the importance of monitoring this potentially explosive lake. PMID:25799098

Coastal groundwater discharge for the U.S. East and Gulf Coasts calculated with three-dimensional groundwater flow models

NASA Astrophysics Data System (ADS)

Befus, K. M.; Kroeger, K. D.; Smith, C. G.; Swarzenski, P. W.

2017-12-01

Fresh groundwater discharge to coastal environments contribute to the physical and chemical conditions of coastal waters. At regional scales, groundwater fluxes remain poorly constrained, representing uncertainty in both water and chemical budgets that have implications for downstream ecosystem health and for how human activities alter coastal hydrologic processes. Coastal groundwater discharges remain widely unconstrained due to the interconnectedness of highly heterogeneous hydrogeologic frameworks and hydrologic conditions. We use regional-scale, three-dimensional groundwater flow models with the best available hydrostratigraphic framework data to calculate the magnitude of groundwater discharging from coastal aquifers to coastal waterbodies along the eastern U.S. In addition, we constrain the inland areas that contribute to coastal groundwater discharges using particle tracking. We find that 27 km3/yr of groundwater enters coastal waters of the eastern U.S. and Gulf of Mexico and was over 175,000 km2. The contributing areas to coastal groundwater discharge extended kilometers inland and often were supplied by recharge occurring tens of kilometers inland. These results suggest that coastal groundwater discharges rely on larger contributing areas and potentially transport more dissolved constituents than previously calculated, which are important factors for constraining the role of groundwater in coastal chemical budgets and its impacts on coastal ecosystems.

Characterization of saline groundwater across the coastal aquifer of Israel as resource for desalination

NASA Astrophysics Data System (ADS)

Stein, Shaked; Russak, Amos; Sivan, Orit; Yechieli, Yospeh; Oren, Yoram; Kasher, Roni

2015-04-01

In arid countries with access to marine water seawater desalination is becoming an important water source in order to deal with the water scarcity and population growth. Seawater reverse osmosis (RO) facilities use open seawater intake, which requires pretreatment processes to remove particles in order to avoid fouling of the RO membrane. In small and medium size desalination facilities, an alternative water source can be saline groundwater in coastal aquifers. Using saline groundwater from boreholes near the shore as feed water may have the advantage of natural filtration and low organic content. It will also reduce operation costs of pretreatment. Another advantage of using groundwater is its availability in highly populated areas, where planning of large RO desalination plants is difficult and expensive due to real-estate prices. Pumping saline groundwater underneath the freshwater-seawater interface (FSI) might shift the interface towards the sea, thus rehabilitating the fresh water reservoirs in the aquifer. In this research, we tested the potential use of saline groundwater in the coastal aquifer of Israel as feed water for desalination using field work and desalination experiments. Specifically, we sampled the groundwater from a pumping well 100 m from the shore of Tel-Aviv and sea water from the desalination plant in Ashqelon, Israel. We used an RO cross flow system in a pilot plant in order to compare between the two water types in terms of permeate flux, permeate flux decline, salt rejection of the membrane and the fouling on the membrane. The feed, brine and fresh desalinated water from the outlet of the desalination system were chemically analyzed and compared. Field measurements of dissolved oxygen, temperature, pH and salinity were also conducted in situ. Additionally, SDI (silt density index), which is an important index for desalination, and total organic carbon that has a key role in organic fouling and development of biofouling, were measured and

Impacts of soil and groundwater salinization on tree crop performance in post-tsunami Aceh Barat, Indonesia

NASA Astrophysics Data System (ADS)

Marohn, C.; Distel, A.; Dercon, G.; Wahyunto; Tomlinson, R.; Noordwijk, M. v.; Cadisch, G.

2012-09-01

The Indian Ocean tsunami of December 2004 had far reaching consequences for agriculture in Aceh province, Indonesia, and particularly in Aceh Barat district, 150 km from the seaquake epicentre. In this study, the spatial distribution and temporal dynamics of soil and groundwater salinity and their impact on tree crops were monitored in Aceh Barat from 2006 to 2008. On 48 sampling points along ten transects, covering 40 km of coastline, soil and groundwater salinity were measured and related to mortality and yield depression of the locally most important tree crops. Given a yearly rainfall of over 3000 mm, initial groundwater salinity declined rapidly from over 10 to less than 2 mS cm-1 within two years. On the other hand, seasonal dynamics of the groundwater table in combination with intrusion of saline water into the groundwater body led to recurring elevated salinity, sufficient to affect crops. Tree mortality and yield depression in the flooded area varied considerably between tree species. Damage to coconut (65% trees damaged) was related to tsunami run-up height, while rubber (50% trees damaged) was mainly affected by groundwater salinity. Coconut yields (-35% in average) were constrained by groundwater Ca2+ and Mg2+, while rubber yields (-65% on average) were related to groundwater chloride, pH and soil sodium. These findings have implications on planting deep-rooted tree crops as growth will be constrained by ongoing oscillations of the groundwater table and salinity.

Groundwater salinization processes and reversibility of seawater intrusion in coastal carbonate aquifers

NASA Astrophysics Data System (ADS)

Han, Dongmei; Post, Vincent E. A.; Song, Xianfang

2015-12-01

Seawater intrusion (SWI) has led to salinization of fresh groundwater reserves in coastal areas worldwide and has forced the closure of water supply wells. There is a paucity of well-documented studies that report on the reversal of SWI after the closure of a well field. This study presents data from the coastal carbonate aquifer in northeast China, where large-scale extraction has ceased since 2001 after salinization of the main well field. The physical flow and concomitant hydrogeochemical processes were investigated by analyzing water level and geochemical data, including major ion chemistry and stable water isotope data. Seasonal water table and salinity fluctuations, as well as changes of δ2H-δ18O values of groundwater between the wet and dry season, suggest local meteoric recharge with a pronounced seasonal regime. Historical monitoring testifies of the reversibility of SWI in the carbonate aquifer, as evidenced by a decrease of the Cl- concentrations in groundwater following restrictions on groundwater abstraction. This is attributed to the rapid flushing in this system where flow occurs preferentially along karst conduits, fractures and fault zones. The partially positive correlation between δ18O values and TDS concentrations of groundwater, as well as high NO3- concentrations (>39 mg/L), suggest that irrigation return flow is a significant recharge component. Therefore, the present-day elevated salinities are more likely due to agricultural activities rather than SWI. Nevertheless, seawater mixing with fresh groundwater cannot be ruled out in particular where formerly intruded seawater may still reside in immobile zones of the carbonate aquifer. The massive expansion of fish farming in seawater ponds in the coastal zone poses a new risk of salinization. Cation exchange, carbonate dissolution, and fertilizer application are the dominant processes further modifying the groundwater composition, which is investigated quantitatively using hydrogeochemical

Hydrogeological controls on spatial patterns of groundwater discharge in peatlands

NASA Astrophysics Data System (ADS)

Hare, Danielle K.; Boutt, David F.; Clement, William P.; Hatch, Christine E.; Davenport, Glorianna; Hackman, Alex

2017-11-01

Peatland environments provide important ecosystem services including water and carbon storage, nutrient processing and retention, and wildlife habitat. However, these systems and the services they provide have been degraded through historical anthropogenic agricultural conversion and dewatering practices. Effective wetland restoration requires incorporating site hydrology and understanding groundwater discharge spatial patterns. Groundwater discharge maintains wetland ecosystems by providing relatively stable hydrologic conditions, nutrient inputs, and thermal buffering important for ecological structure and function; however, a comprehensive site-specific evaluation is rarely feasible for such resource-constrained projects. An improved process-based understanding of groundwater discharge in peatlands may help guide ecological restoration design without the need for invasive methodologies and detailed site-specific investigation. Here we examine a kettle-hole peatland in southeast Massachusetts historically modified for commercial cranberry farming. During the time of our investigation, a large process-based ecological restoration project was in the assessment and design phases. To gain insight into the drivers of site hydrology, we evaluated the spatial patterning of groundwater discharge and the subsurface structure of the peatland complex using heat-tracing methods and ground-penetrating radar. Our results illustrate that two groundwater discharge processes contribute to the peatland hydrologic system: diffuse lower-flux marginal matrix seepage and discrete higher-flux preferential-flow-path seepage. Both types of groundwater discharge develop through interactions with subsurface peatland basin structure, often where the basin slope is at a high angle to the regional groundwater gradient. These field observations indicate strong correlation between subsurface structures and surficial groundwater discharge. Understanding these general patterns may allow resource

Hydrogeologic controls on groundwater discharge and nitrogen loads in a coastal watershed

USGS Publications Warehouse

Russoniello, Chrtopher J.; Konikow, Leonard F.; Kroeger, Kevin D.; Fernandez, Cristina; Andres, A. Scott; Michael, Holly A.

2016-01-01

Submarine groundwater discharge (SGD) is a small portion of the global water budget, but a potentially large contributor to coastal nutrient budgets due to high concentrations relative to stream discharge. A numerical groundwater flow model of the Inland Bays Watershed, Delaware, USA, was developed to identify the primary hydrogeologic factors that affect groundwater discharge rates and transit times to streams and bays. The distribution of groundwater discharge between streams and bays is sensitive to the depth of the water table below land surface. Higher recharge and reduced hydraulic conductivity raised the water table and increased discharge to streams relative to bays compared to the Reference case (in which 66% of recharge is discharged to streams). Increases to either factor decreased transit times for discharge to both streams and bays compared to the Reference case (in which mean transit times are 56.5 and 94.3 years, respectively), though sensitivity to recharge is greater. Groundwater-borne nitrogen loads were calculated from nitrogen concentrations measured in discharging fresh groundwater and modeled SGD rates. These loads combined with long SGD transit times suggest groundwater-borne nitrogen reductions and estuarine water quality improvements will lag decades behind implementation of efforts to manage nutrient sources. This work enhances understanding of the hydrogeologic controls on and uncertainties in absolute and relative rates and transit times of groundwater discharge to streams and bays in coastal watersheds.

Role of solute-transport models in the analysis of groundwater salinity problems in agricultural areas

USGS Publications Warehouse

Konikow, Leonard F.

1981-01-01

Undesirable salinity increases occur in both groundwater and surface water and are commonly related to agricultural practices. Groundwater recharge from precipitation or irrigation will transport and disperse residual salts concentrated by evapotranspiration, salts leached from soil and aquifer materials, as well as some dissolved fertilizers and pesticides. Where stream salinity is affected by agricultural practices, the increases in salt load usually are attributable mostly to a groundwater component of flow. Thus, efforts to predict, manage, or control stream salinity increases should consider the role of groundwater in salt transport. Two examples of groundwater salinity problems in Colorado, U.S.A., illustrate that a model which simulates accurately the transport and dispersion of solutes in flowing groundwater can be (1) a valuable investigative tool to help understand the processes and parameters controlling the movement and fate of the salt, and (2) a valuable management tool for predicting responses and optimizing the development and use of the total water resource. ?? 1981.

Submarine Groundwater Discharge in the Coastal Zone

NASA Astrophysics Data System (ADS)

Bakti, Hendra

2018-02-01

Indonesia is one of the archipelagic countries that has the longest coastline in the world. Because it is located in the tropics, in general it has a very high rainfall. Each island has a different morphology which is composed of a variety of rocks with different hydrogeological properties. This natural condition allows for the presence of groundwater in different amount in each island. The difference in groundwater hydraulics gradients in aquifer continuous to the sea has triggered the discharge of groundwater to offshore known as submarine groundwater discharge (SGD). Its presence can be as seepage or submarine springs with components derived from land and sea and a mixture between them. The understanding of SGD phenomenon is very important because it can be useful as a source of clean water in coastal areas, affecting marine health, and improving marine environment.

Ecohydrology of the coastal wetlands of Yucatan Peninsula are related with the submarine groundwater discharges?

NASA Astrophysics Data System (ADS)

Herrera Silveira, J. A.; Morales-Ojeda, S. M.; Medina Gomez, I.; Kantun Manzano, C.; Caamal Sosa, J.; Marino-Tapia, I.; Adame, F.; Teutli Hernandez, C.

2013-05-01

Submarine groundwater discharge (SGD) contributes significantly in the structure and function of coastal ecosystems favoring nutrients and salinity gradients, and with these spatial variability of wetland types and rates of primary production. However, the connectivity between SGD and coastal wetlands remains largely unexplored, especially in the tropics and karstic regions. On the other hand, coastal wetlands could represents exceptionally large carbon (C) stocks, whose protection and restoration can constitute an effective mitigation strategy for climate change. The Yucatán Peninsula is a low-relief carbonate platform and karst geology that permits fast rainfall infiltration, minimal surface flow, and high SGD., which is characterized by a continuum of freshwater wetland, mangroves, seagrasses meadows and coral reefs. Our studies around the Yucatan coastal wetlands related with the ecohydrology, suggest strong connectivity between SGD and mangrove and seagrasses structure and function. Some of the results indicate that SGD are the main source of nitrate and silicate favoring salinity gradient along the coastal lagoons and bays like estuaries. Mangrove forests show the best structural developments where a spring of groundwater is located, these types of mangroves are called locally "petenes" and show large C stocks. Respect to seagrasses, high shoots density has been observed at sites characterized by low salinity and peak nutrients concentration. Further research on groundwater flows among human activities on inland activities, coastal wetlands and marine ecosystems are required in order to develop management strategies for mitigation and adaptation to global climate change

Mercury speciation and transport via submarine groundwater discharge at a southern California coastal lagoon system.

PubMed

Ganguli, P M; Conaway, C H; Swarzenski, P W; Izbicki, J A; Flegal, A R

2012-02-07

We measured total mercury (Hg(T)) and monomethylmercury (MMHg) concentrations in coastal groundwater and seawater over a range of tidal conditions near Malibu Lagoon, California, and used (222)Rn-derived estimates of submarine groundwater discharge (SGD) to assess the flux of mercury species to nearshore seawater. We infer a groundwater-seawater mixing scenario based on salinity and temperature trends and suggest that increased groundwater discharge to the ocean during low tide transported mercury offshore. Unfiltered Hg(T) (U-Hg(T)) concentrations in groundwater (2.2-5.9 pM) and seawater (3.3-5.2 pM) decreased during a falling tide, with groundwater U-Hg(T) concentrations typically lower than seawater concentrations. Despite the low Hg(T) in groundwater, bioaccumulative MMHg was produced in onshore sediment as evidenced by elevated MMHg concentrations in groundwater (0.2-1 pM) relative to seawater (∼0.1 pM) throughout most of the tidal cycle. During low tide, groundwater appeared to transport MMHg to the coast, resulting in a 5-fold increase in seawater MMHg (from 0.1 to 0.5 pM). Similarly, filtered Hg(T) (F-Hg(T)) concentrations in seawater increased approximately 7-fold during low tide (from 0.5 to 3.6 pM). These elevated seawater F-Hg(T) concentrations exceeded those in filtered and unfiltered groundwater during low tide, but were similar to seawater U-Hg(T) concentrations, suggesting that enhanced SGD altered mercury partitioning and/or solubilization dynamics in coastal waters. Finally, we estimate that the SGD Hg(T) and MMHg fluxes to seawater were 0.41 and 0.15 nmol m(-2) d(-1), respectively - comparable in magnitude to atmospheric and benthic fluxes in similar environments.

Mercury speciation and transport via submarine groundwater discharge at a southern California coastal lagoon system

USGS Publications Warehouse

Ganguli, P.M.; Conaway, C.H.; Swarzenski, P.W.; Izbicki, J.A.; Flegal, A.R.

2012-01-01

We measured total mercury (Hg T) and monomethylmercury (MMHg) concentrations in coastal groundwater and seawater over a range of tidal conditions near Malibu Lagoon, California, and used 222Rn-derived estimates of submarine groundwater discharge (SGD) to assess the flux of mercury species to nearshore seawater. We infer a groundwater-seawater mixing scenario based on salinity and temperature trends and suggest that increased groundwater discharge to the ocean during low tide transported mercury offshore. Unfiltered Hg T (U-Hg T) concentrations in groundwater (2.2-5.9 pM) and seawater (3.3-5.2 pM) decreased during a falling tide, with groundwater U-Hg T concentrations typically lower than seawater concentrations. Despite the low Hg T in groundwater, bioaccumulative MMHg was produced in onshore sediment as evidenced by elevated MMHg concentrations in groundwater (0.2-1 pM) relative to seawater (???0.1 pM) throughout most of the tidal cycle. During low tide, groundwater appeared to transport MMHg to the coast, resulting in a 5-fold increase in seawater MMHg (from 0.1 to 0.5 pM). Similarly, filtered Hg T (F-Hg T) concentrations in seawater increased approximately 7-fold during low tide (from 0.5 to 3.6 pM). These elevated seawater F-Hg T concentrations exceeded those in filtered and unfiltered groundwater during low tide, but were similar to seawater U-Hg T concentrations, suggesting that enhanced SGD altered mercury partitioning and/or solubilization dynamics in coastal waters. Finally, we estimate that the SGD Hg T and MMHg fluxes to seawater were 0.41 and 0.15 nmol m -2 d -1, respectively - comparable in magnitude to atmospheric and benthic fluxes in similar environments. ?? 2012 American Chemical Society.

Discovery and characterization of submarine groundwater discharge in the Siberian Arctic seas: a case study in the Buor-Khaya Gulf, Laptev Sea

NASA Astrophysics Data System (ADS)

Charkin, Alexander N.; Rutgers van der Loeff, Michiel; Shakhova, Natalia E.; Gustafsson, Örjan; Dudarev, Oleg V.; Cherepnev, Maxim S.; Salyuk, Anatoly N.; Koshurnikov, Andrey V.; Spivak, Eduard A.; Gunar, Alexey Y.; Ruban, Alexey S.; Semiletov, Igor P.

2017-10-01

It has been suggested that increasing terrestrial water discharge to the Arctic Ocean may partly occur as submarine groundwater discharge (SGD), yet there are no direct observations of this phenomenon in the Arctic shelf seas. This study tests the hypothesis that SGD does exist in the Siberian Arctic Shelf seas, but its dynamics may be largely controlled by complicated geocryological conditions such as permafrost. The field-observational approach in the southeastern Laptev Sea used a combination of hydrological (temperature, salinity), geological (bottom sediment drilling, geoelectric surveys), and geochemical (224Ra, 223Ra, 228Ra, and 226Ra) techniques. Active SGD was documented in the vicinity of the Lena River delta with two different operational modes. In the first system, groundwater discharges through tectonogenic permafrost talik zones was registered in both winter and summer. The second SGD mechanism was cryogenic squeezing out of brine and water-soluble salts detected on the periphery of ice hummocks in the winter. The proposed mechanisms of groundwater transport and discharge in the Arctic land-shelf system is elaborated. Through salinity vs. 224Ra and 224Ra / 223Ra diagrams, the three main SGD-influenced water masses were identified and their end-member composition was constrained. Based on simple mass-balance box models, discharge rates at sites in the submarine permafrost talik zone were 1. 7 × 106 m3 d-1 or 19.9 m3 s-1, which is much higher than the April discharge of the Yana River. Further studies should apply these techniques on a broader scale with the objective of elucidating the relative importance of the SGD transport vector relative to surface freshwater discharge for both water balance and aquatic components such as dissolved organic carbon, carbon dioxide, methane, and nutrients.

Hypoaigic influences on groundwater flux to a seasonally saline river

NASA Astrophysics Data System (ADS)

Trefry, M. G.; Svensson, T. J. A.; Davis, G. B.

2007-03-01

SummaryHypoaigic zones are aquifer volumes close to and beneath the shores of saline surface water bodies, and are characterized by the presence of time-dependent natural convection and chemical stratification. When transient and cyclic processes are involved there is significant potential for complex flow and reaction in the near-shore aquifer, presenting a unique challenge to pollutant risk assessment methodologies. This work considers the nature of some hypoaigic processes generated by the seasonally saline Canning River of Western Australia near a site contaminated by petroleum hydrocarbons. A dissolved hydrocarbon plume migrates within the shallow superficial aquifer to the nearby bank of the Canning River. Beneath the river bank a zone of complex fluid mixing is established by seasonal and tidal influences. Understanding this complexity and the subsequent ramifications for local biogeochemical conditions is critical to inferring the potential for degradation of advecting contaminants. A range of modelling approaches throws light on the overall topographic controls of discharge to the river, on the saline convection processes operating under the river bank, on the potential for fluid mixing, and on the various important time scales in the system. Saline distributions simulated within the aquifer hypoaigic zone are in at least qualitative agreement with previous field measurements at the site and are strongly affected by seasonal influences. Groundwater seepage velocities at the shoreline are found to be positively correlated with river salinity. Calculations of fluid age distributions throughout the system show sensitivity to dispersivity values; however, maximum fluid ages under the river appear to be diffusion limited to a few decades. The saline convection cell in the aquifer defines a zone of strong dispersive dilution of aged (many decades) deep aquifer fluids with relatively young (several months) riverine fluids. Seasonal recharge and river salinity

Study of quaternary aquifers in Ganga Plain, India: focus on groundwater salinity, fluoride and fluorosis.

PubMed

Misra, Anil Kumar; Mishra, Ajai

2007-06-01

In marginal and central alluvial plains (Ganga Plain) of India, the inland salinity is continuously increasing, canal network and arid to semi-arid climatic conditions that led to excessive evapotranspiration concentrates the salt in soil and thereby escalating the groundwater salinity. In Mat Tahsil, Mathura district (Ganga Plain) study on shallow and deep aquifer salinity and fluoride was carried out in August 2001 and 2004. Groundwater salinity in some parts is more then 4000 microOmega(-1)/cm. This region is severely affected by endemic fluorosis due to consumption of fluoride-contaminated water. Analysis of F(-), Na(+), K(+), Cl(-) and HCO(3)(-) was carried out at 30 sites of dugwells and borewells. Result shows that there is a variation and continuous escalation in the groundwater salinity and fluoride concentration in deep and shallow aquifers on the basis of analysis. Classification of salinity levels was carried out in 2001 and 2004. The deep aquifers (borewells) are found more saline as compare to the shallow aquifers (dugwells) while F(-), Na(+), K(+), Cl(-) and HCO(3)(-) shows high concentration in shallow aquifers. The fluoride concentration in the groundwater of these villages showed values from 0.1 to 2.5mg/l, severe enough to cause dental and skeletal fluorosis among the inhabitants, especially children of these villages. One of the major effects of inland salinity in this region is from saline groundwater, which is reaching the land surface and causing soil salinisations and water logging in the NE and SE parts of Mat block.

Groundwater discharge to wetlands driven by storm and flood events: Quantification using continuous Radon-222 and electrical conductivity measurements and dynamic mass-balance modelling

NASA Astrophysics Data System (ADS)

Gilfedder, B. S.; Frei, S.; Hofmann, H.; Cartwright, I.

2015-09-01

The dynamic response of groundwater discharge to external influences such as rainfall is an often neglected part of water and solute balances in wetlands. Here we develop a new field platform for long-term continuous 222Rn and electrical conductivity (EC) measurements at Sale Wetland, Australia to study the response of groundwater discharge to storm and flood events. The field measurements, combined with dynamic mass-balance modelling, demonstrate that the groundwater flux can increase from 3 to ∼20 mm d-1 following storms and up to 5 mm d-1 on the receding limb of floods. The groundwater pulses are likely produced by activation of local groundwater flow paths by water ponding on the surrounding flood plains. While 222Rn is a sensitive tracer for quantifying transient groundwater discharge, the mass-balance used to estimate fluxes is sensitive to parameterisation of gas exchange (k) with the atmosphere. Comparison of six equations for calculating k showed that, based on parameterisation of k alone, the groundwater flux estimate could vary by 58%. This work shows that neglecting transient processes will lead to errors in water and solute flux estimates based on infrequent point measurements. This could be particularly important for surface waters connected to contaminated or saline groundwater systems.

Impact of groundwater levels on evaporation and water-vapor fluxes in highly saline soils

NASA Astrophysics Data System (ADS)

Munoz, J. F.; Hernández, M. F.; Braud, I.; Gironas, J. A.; Suarez, F. I.

2012-12-01

In aquifers of arid and hyper-arid zones, such as those occurring in the Chilean Andes high plateau, it is important to determine both the quantity and location of water discharges at the temporal scales of interest to close the basin's water budget and thus, to manage the water resource properly. In zones where shallow aquifers are the main source of water, overexploitation of the water resource changes the dynamics of water, heat and solute transport in the vadose zone. As aquifers are exploited, fluctuations in depth to groundwater are exacerbated. These fluctuations modify both soil structure and evaporation from the ground, which is typically the most important discharge from the water budget and is very difficult to estimate. Therefore, a correct quantification of evaporation from these soils is essential to improve the accuracy of the water balance estimation. The objective of this study was to investigate the evaporation processes and water-vapor fluxes in a soil column filled with a saline soil from the Salar del Huasco basin, Chile. Water content, electrical conductivity and temperature at different depths in the soil profile were monitored to determine the liquid and vapor fluxes within the soil column. The results showed that evaporation is negligible when the groundwater table is deeper than 1 m. For shallower groundwater levels, evaporation increases in an exponential fashion reaching a value of 3 mm/day when the groundwater table is near the surface of the ground. These evaporation rates are on the same order of magnitude than the field measurements, but slightly lower due to the controlled conditions maintained in the laboratory. Isothermal fluid fluxes were predominant over the non-isothermal fluid and water vapor fluxes. The net flux for all the phreatic levels tested in the laboratory showed different behaviors, with ascending or descending flows as a consequence of changes in water content and temperature distribution within the soil. It was

Submarine Ground Water Discharge and Fate Along the Coast of Kaloko-Honokohau National Historical Park, Hawai'i:Part 2, Spatial and Temporal Variations in Salinity, Radium-Isotope Activity, and Nutrient Concentrations in Coastal Waters, December 2003-April 2006

USGS Publications Warehouse

Knee, Karen; Street, Joseph; Grossman, Eric E.; Paytan, Adina

2008-01-01

The aquatic resources of Kaloko-Honokohau National Historical Park, including rocky shoreline, fishponds, and anchialine pools, provide habitat to numerous plant and animal species and offer recreational opportunities to local residents and tourists. A considerable amount of submarine groundwater discharge was known to occur in the park, and this discharge was suspected to influence the park's water quality. Thus, the goal of this study was to characterize spatial and temporal variations in the quality and quantity of groundwater discharge in the park. Samples were collected in December 2003, November 2005, and April 2006 from the coastal ocean, beach pits, three park observation wells, anchialine pools, fishponds, and Honokohau Harbor. The activities of two Ra isotopes commonly used as natural ground-water tracers (223Ra and 224Ra), salinity, and nutrient concentrations were measured. Fresh ground water composed a significant proportion (8-47 volume percent) of coastal-ocean water. This percentage varied widely between study sites, indicating significant spatial variation in submarine groundwater discharge at small (meter to kilometer) scales. Nitrate + nitrite, phosphate, and silica concentrations were significantly higher in nearshore coastal-ocean samples relative to samples collected 1 km or more offshore, and linear regression showed that most of this difference was due to fresh ground-water discharge. High-Ra-isotope-activity, higher-salinity springs were a secondary source of nutrients, particularly phosphate, at Honokohau Harbor and Aiopio Fishtrap. Salinity, Ra-isotope activity, and nutrient concentrations appeared to vary in response to the daily tidal cycle, although little seasonal variation was observed, indicating that submarine ground-water discharge may buffer the park's water quality against the severe seasonal changes that would occur in a system where freshwater inputs were dominated by rivers and runoff. Ra-isotope-activity ratios indicated

Submarine groundwater discharge and solute transport under a transgressive barrier island

NASA Astrophysics Data System (ADS)

Evans, Tyler B.; Wilson, Alicia M.

2017-04-01

Many recent investigations of groundwater dynamics in beaches employed groundwater models that assumed isotropic, numerically-convenient hydrogeological conditions. Real beaches exhibit local variability with respect to stratigraphy, sediment grain size and associated topographic profile, so that groundwater flow may diverge significantly from idealized models. We used a combination of hydrogeologic field methods and a variable-density, saturated-unsaturated, transient groundwater flow model to investigate SGD and solute transport under Cabretta Beach, a small transgressive barrier island seaward of Sapelo Island, Georgia. We found that the inclusion of real beach heterogeneity drove important deviations from predictions based on theoretical beaches. Cabretta Beach sustained a stronger upper saline plume than predicted due to the presence of a buried silty mud layer beneath the surface. Infiltration of seawater was greater for neap tides than for spring tides due to variations in beach slope. The strength of the upper saline plume was greatest during spring tides, contrary to recent model predictions. The position and width of the upper saline plume was highly dynamic through the lunar cycle. Our results suggest that field measurements of salinity gradients may be useful for estimating rates of tidally and density driven recirculation through the beach. Finally, our results indicate that several important biogeochemical cycles recently studied at Cabretta Beach were heavily influenced by groundwater flow and associated solute transport.

Fingerprinting groundwater salinity sources in the Gulf Coast Aquifer System, USA

NASA Astrophysics Data System (ADS)

Chowdhury, Ali H.; Scanlon, Bridget R.; Reedy, Robert C.; Young, Steve

2018-02-01

Understanding groundwater salinity sources in the Gulf Coast Aquifer System (GCAS) is a critical issue due to depletion of fresh groundwater and concerns for potential seawater intrusion. The study objective was to assess sources of groundwater salinity in the GCAS using ˜1,400 chemical analyses and ˜90 isotopic analyses along nine well transects in the Texas Gulf Coast, USA. Salinity increases from northeast (median total dissolved solids (TDS) 340 mg/L) to southwest (median TDS 1,160 mg/L), which inversely correlates with the precipitation distribution pattern (1,370- 600 mm/yr, respectively). Molar Cl/Br ratios (median 540-600), depleted δ2H and δ18O (-24.7‰, -4.5‰) relative to seawater (Cl/Br ˜655 and δ2H, δ18O 0‰, 0‰, respectively), and elevated 36Cl/Cl ratios (˜100), suggest precipitation enriched with marine aerosols as the dominant salinity source. Mass balance estimates suggest that marine aerosols could adequately explain salt loading over the large expanse of the GCAS. Evapotranspiration enrichment to the southwest is supported by elevated chloride concentrations in soil profiles and higher δ18O. Secondary salinity sources include dissolution of salt domes or upwelling brines from geopressured zones along growth faults, mainly near the coast in the northeast. The regional extent and large quantities of brackish water have the potential to support moderate-sized desalination plants in this location. These results have important implications for groundwater management, suggesting a current lack of regional seawater intrusion and a suitable source of relatively low TDS water for desalination.

Composition and fluxes of submarine groundwater along the Caribbean coast of the Yucatan Peninsula

NASA Astrophysics Data System (ADS)

Null, Kimberly A.; Knee, Karen L.; Crook, Elizabeth D.; de Sieyes, Nicholas R.; Rebolledo-Vieyra, Mario; Hernández-Terrones, Laura; Paytan, Adina

2014-04-01

Submarine groundwater discharge (SGD) to the coastal environment along the eastern Yucatan Peninsula, Quintana Roo, Mexico was investigated using a combination of tracer mass balances and analytical solutions. Two distinct submarine groundwater sources including water from the unconfined surficial aquifer discharging at the beach face and water from a deeper aquifer discharging nearshore through submarine springs (ojos) were identified. The groundwater of nearshore ojos was saline and significantly enriched in short-lived radium isotopes (223Ra, 224Ra) relative to the unconfined aquifer beach face groundwater. We estimated SGD from ojos using 223Ra and used a salinity mass balance to estimate the freshwater discharge at the beach face. Analytical calculations were also used to estimate wave set-up and tidally driven saline seepage into the surf zone and were compared to the salinity-based freshwater discharge estimates. Results suggest that average SGD from ojos along the Yucatan Peninsula Caribbean coast is on the order of 308 m3 d-1 m-1 and varies between sampling regions. Higher discharge was observed in the southern regions (568 m3 d-1 m-1) compared to the north (48 m3 d-1 m-1). Discharge at the beach face was in the range of 3.3-8.5 m3 d-1 m-1 for freshwater and 2.7 m3 d-1 m-1 for saline water based on the salinity mass balance and wave- and tidally-driven discharge, respectively. Although discharge from the ojos was larger in volume than discharge from the unconfined aquifer at the beach face, dissolved inorganic nitrogen (DIN) was significantly higher in beach groundwater; thus, discharge of this unconfined beach aquifer groundwater contributed significantly to total DIN loading to the coast. DIN fluxes were up to 9.9 mol d-1 m-1 from ojos and 2.1 mol d-1 m-1 from beach discharge and varied regionally along the 500 km coastline sampled. These results demonstrate the importance of considering the beach zone as a significant nutrient source to coastal waters

Computer programs for describing the recession of ground-water discharge and for estimating mean ground-water recharge and discharge from streamflow records-update

USGS Publications Warehouse

Rutledge, A.T.

1998-01-01

The computer programs included in this report can be used to develop a mathematical expression for recession of ground-water discharge and estimate mean ground-water recharge and discharge. The programs are intended for analysis of the daily streamflow record of a basin where one can reasonably assume that all, or nearly all, ground water discharges to the stream except for that which is lost to riparian evapotranspiration, and where regulation and diversion of flow can be considered to be negligible. The program RECESS determines the master reces-sion curve of streamflow recession during times when all flow can be considered to be ground-water discharge and when the profile of the ground-water-head distribution is nearly stable. The method uses a repetitive interactive procedure for selecting several periods of continuous recession, and it allows for nonlinearity in the relation between time and the logarithm of flow. The program RORA uses the recession-curve displacement method to estimate the recharge for each peak in the streamflow record. The method is based on the change in the total potential ground-water discharge that is caused by an event. Program RORA is applied to a long period of record to obtain an estimate of the mean rate of ground-water recharge. The program PART uses streamflow partitioning to estimate a daily record of base flow under the streamflow record. The method designates base flow to be equal to streamflow on days that fit a requirement of antecedent recession, linearly interpolates base flow for other days, and is applied to a long period of record to obtain an estimate of the mean rate of ground-water discharge. The results of programs RORA and PART correlate well with each other and compare reasonably with results of the corresponding manual method.

Nested-scale discharge and groundwater level monitoring to improve predictions of flow route discharges and nitrate loads

NASA Astrophysics Data System (ADS)

van der Velde, Y.; Rozemeijer, J. C.; de Rooij, G. H.; van Geer, F. C.; Torfs, P. J. J. F.; de Louw, P. G. B.

2010-10-01

Identifying effective measures to reduce nutrient loads of headwaters in lowland catchments requires a thorough understanding of flow routes of water and nutrients. In this paper we assess the value of nested-scale discharge and groundwater level measurements for predictions of catchment-scale discharge and nitrate loads. In order to relate field-site measurements to the catchment-scale an upscaling approach is introduced that assumes that scale differences in flow route fluxes originate from differences in the relationship between groundwater storage and the spatial structure of the groundwater table. This relationship is characterized by the Groundwater Depth Distribution (GDD) curve that relates spatial variation in groundwater depths to the average groundwater depth. The GDD-curve was measured for a single field site (0.009 km2) and simple process descriptions were applied to relate the groundwater levels to flow route discharges. This parsimonious model could accurately describe observed storage, tube drain discharge, overland flow and groundwater flow simultaneously with Nash-Sutcliff coefficients exceeding 0.8. A probabilistic Monte Carlo approach was applied to upscale field-site measurements to catchment scales by inferring scale-specific GDD-curves from hydrographs of two nested catchments (0.4 and 6.5 km2). The estimated contribution of tube drain effluent (a dominant source for nitrates) decreased with increasing scale from 76-79% at the field-site to 34-61% and 25-50% for both catchment scales. These results were validated by demonstrating that a model conditioned on nested-scale measurements simulates better nitrate loads and better predictions of extreme discharges during validation periods compared to a model that was conditioned on catchment discharge only.

Submarine Groundwater Discharge and Fate Along the Coast of Kaloko-Honokohau National Historical Park, Island of Hawai`i; Part 3, Spatial and Temporal Patterns in Nearshore Waters and Coastal Groundwater Plumes, December 2003-April 2006

USGS Publications Warehouse

Grossman, Eric E.; Logan, Joshua B.; Presto, M. Katherine; Storlazzi, Curt D.

2010-01-01

During seven surveys between December 2003 and April 2006, 1,045 depth profiles of surface water temperature and salinity were collected to examine variability in water column properties and the influence of submarine groundwater discharge (SGD) on the nearshore waters and coral reef complex of Kaloko-Honokohau National Historical Park, Island of Hawai`i. This effort was made to characterize the variability in nearshore water properties with seasonality and hydrodynamic forcing (tides, winds, and waves) and to determine the spatial and vertical extent of influence of SGD plumes on the Park's marine biological resources. The results of this study reveal that nearshore waters of the Park were persistently influenced by plumes of submarine groundwater discharge that are generally colder, less saline, and more concentrated in nutrients than the surrounding seawater. These plumes extended between 100 and 1,000 m offshore to depths ranging between 1 and 5 m and often contained several million to hundreds of millions of gallons of brackish water. In essence, the Park's nearshore, like much of the arid west coast of Hawai`i, is estuarine. Although the groundwater plumes were persistent over the years studied, their spatial extent and volume varied tidally, seasonally, and annually. In one season, April 2004, an inverse relation of decreasing salinity with increasing temperature was found in the upper 5 m of the water column, unlike the other seasons, when surface water temperature and salinity were positively correlated. These data provide the first comprehensive record of nearshore water column properties within the Park boundaries and a baseline for detecting and assessing future conditions. Various resort, industrial, and municipal developments, either planned or under construction around the Park, will require significant groundwater supplies and will likely alter groundwater quantity and quality. The flux and quality of groundwater through the National Park are

Groundwater Discharge along a Channelized Coastal Plain Stream

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaSage, Danita M; Sexton, Joshua L; Mukherjee, Abhijit

In the Coastal Plain of the southeastern USA, streams have commonly been artificially channelized for flood control and agricultural drainage. However, groundwater discharge along such streams has received relatively little attention. Using a combination of stream- and spring-flow measurements, spring temperature measurements, temperature profiling along the stream-bed, and geologic mapping, we delineated zones of diffuse and focused discharge along Little Bayou Creek, a channelized, first-order perennial stream in western Kentucky. Seasonal variability in groundwater discharge mimics hydraulic-head fluctuations in a nearby monitoring well and spring-discharge fluctuations elsewhere in the region, and is likely to reflect seasonal variability in recharge. Diffusemore » discharge occurs where the stream is incised into the semi-confined regional gravel aquifer, which is comprised of the Mounds Gravel. Focused discharge occurs upstream where the channel appears to have intersected preferential pathways within the confining unit. Seasonal fluctuations in discharge from individual springs are repressed where piping results in bank collapse. Thereby, focused discharge can contribute to the morphological evolution of the stream channel.« less

Mathematical modelling of surface water-groundwater flow and salinity interactions in the coastal zone

NASA Astrophysics Data System (ADS)

Spanoudaki, Katerina; Kampanis, Nikolaos A.

2014-05-01

surface water-groundwater model IRENE (Spanoudaki et al., 2009; Spanoudaki, 2010) has been modified in order to simulate surface water-groundwater flow and salinity interactions in the coastal zone. IRENE, in its original form, couples the 3D, non-steady state Navier-Stokes equations, after Reynolds averaging and with the assumption of hydrostatic pressure distribution, to the equations describing 3D saturated groundwater flow of constant density. A semi-implicit finite difference scheme is used to solve the surface water flow equations, while a fully implicit finite difference scheme is used for the groundwater equations. Pollution interactions are simulated by coupling the advection-diffusion equation describing the fate and transport of contaminants introduced in a 3D turbulent flow field to the partial differential equation describing the fate and transport of contaminants in 3D transient groundwater flow systems. The model has been further developed to include the effects of density variations on surface water and groundwater flow, while the already built-in solute transport capabilities are used to simulate salinity interactions. Initial results show that IRENE can accurately predict surface water-groundwater flow and salinity interactions in coastal areas. Important research issues that can be investigated using IRENE include: (a) sea level rise and tidal effects on aquifer salinisation and the configuration of the saltwater wedge, (b) the effects of surface water-groundwater interaction on salinity increase of coastal wetlands and (c) the estimation of the location and magnitude of groundwater discharge to coasts. Acknowledgement The work presented in this paper has been funded by the Greek State Scholarships Foundation (IKY), Fellowships of Excellence for Postdoctoral Studies (Siemens Program), 'A simulation-optimization model for assessing the best practices for the protection of surface water and groundwater in the coastal zone', (2013 - 2015). References

Groundwater salinization in the Saloum (Senegal) delta aquifer: minor elements and isotopic indicators.

PubMed

Faye, Serigne; Maloszewski, Piotr; Stichler, Willibald; Trimborn, Peter; Cissé Faye, Seynabou; Bécaye Gaye, Cheikh

2005-05-01

The hydrochemistry of minor elements bromide (Br), boron (B), strontium (Sr), environmental stable isotopes (18O and 2H) together with major-ion chemistry (chloride, sodium, calcium) has been used to constrain the source(s), relative age, and processes of salinization in the Continental Terminal (CT) aquifer in the Saloum (mid-west Senegal) region. Seventy-one groundwater wells which include 24 wells contaminated by saltwater and three sites along the hypersaline Saloum River were sampled to obtain additional information on the hydrochemical characteristics of the groundwater defined in previous studies. Use of Br against Cl confirms the Saloum River saline water intrusion up to a contribution of 7% into the aquifer. In addition to this recent intrusion, a relatively ancient intrusion of the Saloum River water which had reached at least as far as 20 km south from the source was evidenced. The high molar ratio values of Sr/Cl and Sr/Ca indicate an additional input of strontium presumably derived from carbonate precipitation/dissolution reactions and also via adsorption reactions. The variable B concentrations (7-650 microg/L) found in the groundwater samples were tested against the binary mixing model to evaluate the processes of salinization which are responsible for the investigated system. Sorption of B and depletion of Na occur as the Saloum river water intrudes the aquifer (salinization) in the northern part of the region, whereas B desorption and Na enrichment occur as the fresh groundwater flushing displaces the saline waters in the coastal strip (refreshening). In the central zone where ancient intrusion prevailed, the process of freshening of the saline groundwater is indicated by the changes in major-ion chemistry as well as B desorption and Na enrichment. In addition to these processes, stable isotopes reveal that mixing with recently infiltrating waters and evaporation contribute to the changes in isotopic signature.

Impact of hydrogeological factors on groundwater salinization due to ocean-surge inundation

NASA Astrophysics Data System (ADS)

Yang, Jie; Zhang, Huichen; Yu, Xuan; Graf, Thomas; Michael, Holly A.

2018-01-01

Ocean surges cause seawater inundation of coastal inland areas. Subsequently, seawater infiltrates into coastal aquifers and threatens the fresh groundwater resource. The severity of resulting salinization can be affected by hydrogeological factors including aquifer properties and hydrologic conditions, however, little research has been done to assess these effects. To understand the impacts of hydrogeological factors on groundwater salinization, we numerically simulated an ocean-surge inundation event on a two-dimensional conceptual coastal aquifer using a coupled surface-subsurface approach. We varied model permeability (including anisotropy), inland hydraulic gradient, and recharge rate. Three salinization-assessment indicators were developed, based on flushing time, depth of salt penetration, and a combination of the two, weighted flushing time, with which the impact of hydrogeological factors on groundwater vulnerability to salinization were quantitatively assessed. The vulnerability of coastal aquifers increases with increasing isotropic permeability. Low horizontal permeability (kx) and high vertical permeability (kz) lead to high aquifer vulnerability, and high kx and low kz lead to low aquifer vulnerability. Vulnerability decreases with increasing groundwater hydraulic gradient and increasing recharge rate. Additionally, coastal aquifers with a low recharge rate (R ≤ 300 mm yr-1) may be highly vulnerable to ocean-surge inundation. This study shows how the newly introduced indicators can be used to quantitatively assess coastal aquifer vulnerability. The results are important for global vulnerability assessment of coastal aquifers to ocean-surge inundation.

Skeletal myopathy in juvenile barramundi, Lates calcarifer (Bloch), cultured in potassium-deficient saline groundwater.

PubMed

Partridge, G J; Creeper, J

2004-09-01

Saline groundwater is being pumped from a number of locations in rural Western Australia to prevent secondary salinity impacting farmland, rural infrastructure and areas with high conservation value. Aquaculture may offset the costs of groundwater pumping, and the suitability of groundwater for finfish aquaculture is being assessed through bioassays. There are marked spatial variations in the ionic composition of saline ground water in Western Australia and this paper describes two bioassays investigating a saline, potassium-deficient water source that resulted in mortalities in juvenile barramundi, Lates calcarifer (Bloch). Histopathological examination revealed severe degeneration and necrosis of skeletal muscles, marked hyperplasia of branchial chloride cells and renal tubular necrosis. Clinical chemistry findings included hypernatraemia and hyperchloridaemia of the blood plasma and lowered muscle potassium levels. It is concluded that the principal cause of death was skeletal myopathy induced by low water potassium levels.

Integral Analysis of Field Work and Laboratory Electrical Resistivity Imaging for Saline Water Intrusion Prediction in Groundwater

NASA Astrophysics Data System (ADS)

Zawawi, M. H.; Zahar, M. F.; Hashim, M. M. M.; Hazreek, Z. A. M.; Zahari, N. M.; Kamaruddin, M. A.

2018-04-01

Saline water intrusion is a serious threat to the groundwater as many part of the world utilize groundwater as their main source of fresh water supply. The usage of high salinity level of water as drinking water can lead to a very serious health hazard towards human. Saline water intrusion is a process by which induced flow of seawater into freshwater aquifer along the coastal area. It might happen due to human action and/or by natural event. The climate change and rise up of sea level may speed up the saline water intrusion process. The conventional method for distinguishing and checking saltwater interference to groundwater along the coast aquifers is to gather and test the groundwater from series of observation wells (borehole) with an end goal to give the important information about the hydrochemistry data to conclude whether the water in the well are safe to consume or not. An integrated approach of field and laboratory electrical resistivity investigation is proposed for indicating the contact region between saline and fresh groundwater. It was found that correlation for both soilbox produced almost identical curvilinear trends for 2% increment of seawater tested using sand sample. This project contributes towards predicting the saline water intrusion to the groundwater by non-destructive test that can replaced the conventional method of groundwater monitoring using series of boreholes in the coastal area

Numerical Analysis of Ground-Water Flow and Salinity in the Ewa Area, Oahu, Hawaii

USGS Publications Warehouse

Oki, Delwyn S.; Souza, William R.; Bolke, Edward I.; Bauer, Glenn R.

1996-01-01

The coastal plain in the Ewa area of southwestern Oahu, Hawaii, is part of a larger, nearly continuous sedimentary coastal plain along Oahu's southern coast. The coastal sediments are collectively known as caprock because they impede the free discharge of ground water from the underlying volcanic aquifers. The caprock is a layered sedimentary system consisting of interbedded marine and terrestrial sediments of both high and low permeability. Before sugarcane cultivation ended in late 1994, shallow ground water from the upper limestone unit, which is about 60 to 200 feet thick, was used primarily for irrigation of sugarcane. A cross-sectional ground-water flow and transport model was used to evaluate the hydrogeologic controls on the regional flow system in the Ewa area. Controls considered were: (1) overall caprock hydraulic conductivity, (2) stratigraphic variations of hydraulic conductivity in the caprock, and (3) recharge. In addition, the effects of a marina excavation were evaluated. Within the caprock, variations in hydraulic conductivity, caused by caprock stratigraphy or discontinuities of the stratigraphic units, are a major control on the direction of ground-water flow and the distribution of water levels and salinity. Model results also show that a reduction of recharge will result in increased salinity throughout the caprock with the greatest change in the upper limestone layer. In addition, the model indicates that excavation of an ocean marina will lower water levels in the upper limestone layer. Results of cross-sectional modeling confirm the general ground-water flow pattern that would be expected in the layered sedimentary system in the Ewa caprock. Ground-water flow is: (1) predominantly upward in the low-permeability sedimentary units, and (2) predominantly horizontal in the high-permeability sedimentary units.

Transient groundwater dynamics in a coastal aquifer: The effects of tides, the lunar cycle, and the beach profile

NASA Astrophysics Data System (ADS)

Abarca, Elena; Karam, Hanan; Hemond, Harold F.; Harvey, Charles F.

2013-05-01

Detailed field measurements are combined with a numerical modeling to characterize the groundwater dynamics beneath the discharge zone at Waquoit Bay, Massachusetts. Groundwater salinity values revealed a saline circulation cell that overlaid the discharging freshwater and grew and disappeared with the lunar cycle. The cell was initiated by a greater bay water infiltration during the new moon when high tides overtopped the mean high-tide mark, flooding the flatter beach berm and inundating a larger area of the beach. The dynamics of this cell were further characterized by a tracer test and by constructing a density-dependent flow model constrained to salinity and head data. The numerical model captured the growing and diminishing behavior of the circulation cell and provided the estimates of freshwater and saline water fluxes and travel times. Furthermore, the model enabled quantification of the relationship between the characteristics of the observed tidal cycle (maximum, minimum, and mean tidal elevations) and the different components of the groundwater circulation (freshwater discharge, intertidal saline cycling, and deep saline cycling). We found that (1) recharge to the intertidal saline cell is largely controlled by the high-tide elevation; (2) freshwater discharge is positively correlated to the low-tide elevation, whereas deep saline discharge from below the discharging freshwater is negatively correlated to the low-tide elevation. So, when the low-tide elevation is relatively high, more freshwater discharges and less deep saltwater discharges. In contrast when low tides are very low, less freshwater discharges and more deep salt water discharges; (3) offshore inflow of saline water is largely insensitive to tides and the lunar cycle.

Discontinuous submarine groundwater discharge in a tidally influenced coastal aquifer

NASA Astrophysics Data System (ADS)

Abarca, E.; Karam, H.; Hemond, H.; Harvey, C. F.

2011-12-01

Ocean forces have a critical impact on the magnitude and temporal evolution of Submarine Groundwater Discharge (SGD). Here, we analyze the groundwater discharge response to changes in the tidal signal at Waquoit Bay, Cape Cod, Massachusetts. We present a conceptual and numerical model that predicts that both fresh and saltwater components of SGD are interrupted by rising tides. During that period, saltwater infiltration pushes freshwater down and landward. Freshwater is stored in the aquifer, increasing the groundwater head, and is released during the receding tide. Discontinuous freshwater discharge occurs during both neap and spring tidal cycles even though the total discharge is higher during a neap tidal cycle. Evidence of this interruption of SGD can be found in geophysical and temperature measurements of the intertidal subsurface zone at Waquoit Bay. The long-term temporal and spatial evolution of fresh and saltwater fluxes shows that freshwater discharge tracks the mean and minimum tide elevation. The intertidal saltwater discharge is controlled by the high tide elevation whereas the deep saltwater discharge increases with falling low tide elevation.

The Role of Frozen Soil in Groundwater Discharge Predictions for Warming Alpine Watersheds

NASA Astrophysics Data System (ADS)

Evans, Sarah G.; Ge, Shemin; Voss, Clifford I.; Molotch, Noah P.

2018-03-01

Climate warming may alter the quantity and timing of groundwater discharge to streams in high alpine watersheds due to changes in the timing of the duration of seasonal freezing in the subsurface and snowmelt recharge. It is imperative to understand the effects of seasonal freezing and recharge on groundwater discharge to streams in warming alpine watersheds as streamflow originating from these watersheds is a critical water resource for downstream users. This study evaluates how climate warming may alter groundwater discharge due to changes in seasonally frozen ground and snowmelt using a 2-D coupled flow and heat transport model with freeze and thaw capabilities for variably saturated media. The model is applied to a representative snowmelt-dominated watershed in the Rocky Mountains of central Colorado, USA, with snowmelt time series reconstructed from a 12 year data set of hydrometeorological records and satellite-derived snow covered area. Model analyses indicate that the duration of seasonal freezing in the subsurface controls groundwater discharge to streams, while snowmelt timing controls groundwater discharge to hillslope faces. Climate warming causes changes to subsurface ice content and duration, rerouting groundwater flow paths but not altering the total magnitude of future groundwater discharge outside of the bounds of hydrologic parameter uncertainties. These findings suggest that frozen soil routines play an important role for predicting the future location of groundwater discharge in watersheds underlain by seasonally frozen ground.

The role of frozen soil in groundwater discharge predictions for warming alpine watersheds

USGS Publications Warehouse

Evans, Sarah G.; Ge, Shemin; Voss, Clifford I.; Molotch, Noah P.

2018-01-01

Climate warming may alter the quantity and timing of groundwater discharge to streams in high alpine watersheds due to changes in the timing of the duration of seasonal freezing in the subsurface and snowmelt recharge. It is imperative to understand the effects of seasonal freezing and recharge on groundwater discharge to streams in warming alpine watersheds as streamflow originating from these watersheds is a critical water resource for downstream users. This study evaluates how climate warming may alter groundwater discharge due to changes in seasonally frozen ground and snowmelt using a 2‐D coupled flow and heat transport model with freeze and thaw capabilities for variably saturated media. The model is applied to a representative snowmelt‐dominated watershed in the Rocky Mountains of central Colorado, USA, with snowmelt time series reconstructed from a 12 year data set of hydrometeorological records and satellite‐derived snow covered area. Model analyses indicate that the duration of seasonal freezing in the subsurface controls groundwater discharge to streams, while snowmelt timing controls groundwater discharge to hillslope faces. Climate warming causes changes to subsurface ice content and duration, rerouting groundwater flow paths but not altering the total magnitude of future groundwater discharge outside of the bounds of hydrologic parameter uncertainties. These findings suggest that frozen soil routines play an important role for predicting the future location of groundwater discharge in watersheds underlain by seasonally frozen ground.

Implications of deep drainage through saline clay for groundwater recharge and sustainable cropping in a semi-arid catchment, Australia

NASA Astrophysics Data System (ADS)

Timms, W. A.; Young, R. R.; Huth, N.

2012-04-01

thick clay dominated vadose zone. This is in contrast to regional groundwater modelling that assumes annual recharge of 0.5% of rainfall. Importantly, it was found that leaching from episodic deep drainage could not cause discharge of saline groundwater in the area, since the water table was several meters below the incised river bed.

Implications of deep drainage through saline clay for groundwater recharge and sustainable cropping in a semi-arid catchment, Australia

NASA Astrophysics Data System (ADS)

Timms, W. A.; Young, R. R.; Huth, N.

2011-11-01

groundwater modelling that assumes annual recharge of 0.5% of rainfall. Importantly, it was found that leaching from episodic deep drainage could not cause discharge of saline groundwater in the area, since the water table was several meters below the incised river bed.

Assessing the Impact of Topography on Groundwater Salinization Due to Storm Surge Inundation

NASA Astrophysics Data System (ADS)

Yu, X.; Yang, J.; Graf, T.; Koneshloo, M.; O'Neal, M. A.; Michael, H. A.

2015-12-01

The sea-level rise and increase in the frequency and intensity of coastal storms due to climate change are likely to exacerbate adverse effects of storm surges on low-lying coastal areas. The landward flow of water during storm surges introduces salt to surficial coastal aquifers and threatens groundwater resources. Coastal topography (e.g. ponds, dunes, canals) likely has a strong impact on overwash and salinization processes, but is generally highly simplified in modeling studies. To understand the topographic impacts on groundwater salinization, we modeled overwash and variable-density groundwater flow and salt transport in 3D using the fully coupled surface and subsurface numerical simulator, HydroGeoSphere. The model simulates the coastal aquifer as an integrated system considering processes such as overland flow, coupled surface and subsurface exchange, variably saturated flow, and variable-density flow. To represent various coastal landscape types, we started with realistic coastal topography from Delaware, USA, and then generated synthetic fields with differing shore-perpendicular connectivity and surface depressions. The groundwater salinization analysis suggested that the topographic connectivity promoting overland flow controls the volume of aquifer that is salinized. In contrast, depression storage of surface water mainly controls the time for infiltrated salt to flush from the aquifer. The results indicate that for a range of synthetic conditions, topography increases the flushing time of salt by 20-300% relative to an equivalent "simple slope" in which topographic variation is absent. Our study suggests that topography have a significant impact on overwash salinization, with important implications for land management at local scales and groundwater vulnerability assessment at regional to global scales.

Observations of nearshore groundwater discharge: Kahekili Beach Park submarine springs, Maui, Hawaii

USGS Publications Warehouse

Swarzenski, Peter W.; Dulai, H.; Kroeger, K.D.; Smith, C.G.; Dimova, N.; Storlazzi, C. D.; Prouty, N.G.; Gingerich, S.B.; Glenn, C. R.

2016-01-01

Study regionThe study region encompasses the nearshore, coastal waters off west Maui, Hawaii. Here abundant groundwater—that carries with it a strong land-based fingerprint—discharges into the coastal waters and over a coral reef.Study focusCoastal groundwater discharge is a ubiquitous hydrologic feature that has been shown to impact nearshore ecosystems and material budgets. A unique combined geochemical tracer and oceanographic time-series study addressed rates and oceanic forcings of submarine groundwater discharge at a submarine spring site off west Maui, Hawaii.New hydrological insights for the regionEstimates of submarine groundwater discharge were derived for a primary vent site and surrounding coastal waters off west Maui, Hawaii using an excess 222Rn (t1/2 = 3.8 d) mass balance model. Such estimates were complemented with a novel thoron (220Rn,t1/2 = 56 s) groundwater discharge tracer application, as well as oceanographic time series and thermal infrared imagery analyses. In combination, this suite of techniques provides new insight into the connectivity of the coastal aquifer with the near-shore ocean and examines the physical drivers of submarine groundwater discharge. Lastly, submarine groundwater discharge derived constituent concentrations were tabulated and compared to surrounding seawater concentrations. Such work has implications for the management of coastal aquifers and downstream nearshore ecosystems that respond to sustained constituent loadings via this submarine route.

Coastal hazards and groundwater salinization on low coral islands.

NASA Astrophysics Data System (ADS)

Terry, James P.; Chui, T. F. May

2016-04-01

Remote oceanic communities living on low-lying coral islands (atolls) without surface water rely for their survival on the continuing viability of fragile groundwater resources. These exist in the form of fresh groundwater lenses (FGLs) that develop naturally within the porous coral sand and gravel substrate. Coastal hazards such as inundation by high-energy waves driven by storms and continuing sea-level rise (SLR) are among many possible threats to viable FGL size and quality on atolls. Yet, not much is known about the combined effects of wave washover during powerful storms and SLR on different sizes of coral island, nor conversely how island size influences lens resilience against damage. This study investigates FGL damage by salinization (and resilience) caused by such coastal hazards using a modelling approach. Numerical modelling is carried out to generate steady-state FGL configurations at three chosen island sizes (400, 600 and 800 m widths). Steady-state solutions reveal how FGL dimensions are related in a non-linear manner to coral island size, such that smaller islands develop much more restricted lenses than larger islands. A 40 cm SLR scenario is then imposed. This is followed by transient simulations to examine storm-induced wave washover and subsequent FGL responses to saline damage over a 1 year period. Smaller FGLs display greater potential for disturbance by SLR, while larger and more robust FGLs tend to show more resilience. Further results produce a somewhat counterintuitive finding: in the post-SLR condition, FGL vulnerability to washover salinization may actually be reduced, owing to the thinner layer of unsaturated substrate lying above the water table into which saline water can infiltrate during a storm event. Nonetheless, combined washover and SLR impacts imply overall that advancing groundwater salinization may lead to some coral islands becoming uninhabitable long before they are completely submerged by sea-level rise, thereby calling

Overview of groundwater management approaches at salinisation risk

NASA Astrophysics Data System (ADS)

Polemio, Maurizio; Zuffianò, Livia Emanuela

2013-04-01

All natural waters contain dissolved minerals from interactions with atmospheric and soil gases, mixing with other solutions, and/or interactions with the biosphere and lithosphere. In many cases, these processes result in natural waters containing solute or salinity above concentrations recommended for a specified use, which creates significant social and economic problems. Groundwater salinisation can be caused by natural phenomena and anthropogenic activities. For the former case, we can distinguish terrestrial and marine phenomena. Approximately 16% of the total area of continental earth is potentially involved in groundwater salinisation. Seawater intrusion can be considered to be the primary phenomenon to be studied in terms of groundwater salinisation. Three schematic approaches to the protection of groundwater via salinisation mitigation and/or groundwater salinity improvement are described based on the classifications of the primary salinisation sources and focusing on the effect of seawater intrusion. The complexity of these approaches generally increases due to difficulties caused by groundwater quality and quantity degradation and increased demand for quality water. In order from the lowest to the highest complexity, these approaches are the engineering approach, the discharge management approach, and the water and land management approach. The engineering approach is realised on the local or detailed scale with the purpose of controlling the salinisation, optimising the well discharge with specific technical solutions and/or completing works to improve the quality and/or quantity of the discharged fresh groundwater. The discharge management approach encompasses at least an entire coastal aquifer and defines rules concerning groundwater utilisation and well discharge. The water and land management approach should be applied on the regional scale. Briefly, this approach becomes necessary when one or more need creates an overall framework of high

Geospatial database of estimates of groundwater discharge to streams in the Upper Colorado River Basin

USGS Publications Warehouse

Garcia, Adriana; Masbruch, Melissa D.; Susong, David D.

2014-01-01

The U.S. Geological Survey, as part of the Department of the Interior’s WaterSMART (Sustain and Manage America’s Resources for Tomorrow) initiative, compiled published estimates of groundwater discharge to streams in the Upper Colorado River Basin as a geospatial database. For the purpose of this report, groundwater discharge to streams is the baseflow portion of streamflow that includes contributions of groundwater from various flow paths. Reported estimates of groundwater discharge were assigned as attributes to stream reaches derived from the high-resolution National Hydrography Dataset. A total of 235 estimates of groundwater discharge to streams were compiled and included in the dataset. Feature class attributes of the geospatial database include groundwater discharge (acre-feet per year), method of estimation, citation abbreviation, defined reach, and 8-digit hydrologic unit code(s). Baseflow index (BFI) estimates of groundwater discharge were calculated using an existing streamflow characteristics dataset and were included as an attribute in the geospatial database. A comparison of the BFI estimates to the compiled estimates of groundwater discharge found that the BFI estimates were greater than the reported groundwater discharge estimates.

Groundwater discharge and hydrologic partition of the lakes in desert environment: Insights from stable 18O/2H and radium isotopes

NASA Astrophysics Data System (ADS)

Luo, Xin; Jiao, Jiu Jimmy; Wang, Xu-sheng; Liu, Kun; Lian, Ergang; Yang, Shouye

2017-03-01

Studies of isotope characteristics of lake water in a desert can provide important information on groundwater discharge and hydrologic partition of the lakes in the desert. This paper presents the investigation of 18O and 2H stable isotopes and radiogenic radium of different water endmembers in three representative lakes of Badain-E, Badain-W and Sumujilin-S in the Badain Jaran Desert (BJD), the fourth largest desert in the world. A stable 18O and 2H isotopic buildup model is constructed to classify the hydrologic conditions of the desert lakes by estimating the ratio between groundwater discharge rate (Fin) and lake surface evaporation (E). Then the radium mass balance models are developed to quantify Fin. Based on the obtained Fin/E and Fin, Badain-E, Badain-W and Sumujilin-S are classified as flowing through, terminal and desiccating lakes, respectively, and their hydrologic partition is obtained. The groundwater discharge rate of Badain-E, Badain-W and Sumujilin-S, is estimated to be 8-10 mm d-1, 4-5 mm d-1, and 7-8 mm d-1, respectively. The total groundwater discharge to the lake areas in the BJD is about 1.68 × 105 m3 d-1. The flow-through condition explains the existence of the fresh lakes, while the terminal and desiccating conditions lead to the lake salinization over time. This study represents the first attempt to couple both stable and radium isotopic approaches to investigate the groundwater discharge and hydrologic partition of desert lakes in the BJD and is instructional to lake studies in other deserts in the world.

Groundwater Discharge of Legacy Nitrogen to River Networks: Linking Regional Groundwater Models to Streambed Groundwater-Surface Water Exchange and Nitrogen Processing

NASA Astrophysics Data System (ADS)

Barclay, J. R.; Helton, A. M.; Briggs, M. A.; Starn, J. J.; Hunt, A.

2017-12-01

Despite years of management, excess nitrogen (N) is a pervasive problem in many aquatic ecosystems. More than half of surface water in the United States is derived from groundwater, and widespread N contamination in aquifers from decades of watershed N inputs suggest legacy N discharging from groundwater may contribute to contemporary N pollution problems in surface waters. Legacy N loads to streams and rivers are controlled by both regional scale flow paths and fine-scale processes that drive N transformations, such as groundwater-surface water exchange across steep redox gradients that occur at stream bed interfaces. Adequately incorporating these disparate scales is a challenge, but it is essential to understanding legacy N transport and making informed management decisions. We developed a regional groundwater flow model for the Farmington River, a HUC-8 basin that drains to the Long Island Sound, a coastal estuary that suffers from elevated N loads despite decades of management, to understand broad patterns of regional transport. To evaluate and refine the regional model, we used thermal infrared imagery paired with vertical temperature profiling to estimate groundwater discharge at the streambed interface. We also analyzed discharging groundwater for multiple N species to quantify fine scale patterns of N loading and transformation via denitrification at the streambed interface. Integrating regional and local estimates of groundwater discharge of legacy N to river networks should improve our ability to predict spatiotemporal patterns of legacy N loading to and transformation within surface waters.

Groundwater flow in a coastal peatland and its influence on submarine groundwater discharge

NASA Astrophysics Data System (ADS)

Ptak, T.; Ibenthal, M.; Janssen, M.; Massmann, G.; Lenartz, B.

2017-12-01

Coastal peatlands are characterized by intense interactions between land and sea, comprising both a submarine discharge of fresh groundwater and inundations of the peatland with seawater. Nutrients and salts can influence the biogeochemical processes both in the shallow marine sediments and in the peatland. The determination of flow direction and quantity of groundwater flow are therefore elementary. Submarine groundwater discharge (SGD) has been reported from several locations in the Baltic. The objective of this study is to quantify the exchange of fresh and brackish water across the shoreline in a coastal peatland in Northeastern Germany, and to assess the influence of a peat layer extending into the Baltic Sea. Below the peatland, a shallow fine sand aquifer differs in depth and is limited downwards by glacial till. Water level and electrical conductivity (EC) are permanently measured in different depths at eight locations in the peatland. First results indicate a general groundwater flow direction towards the sea. Electrical conductivity measurements suggest different permeabilities within the peat layer, depending on its thickness and degradation. Near the beach, EC fluctuates partially during storm events due to seawater intrusion and reverse discharge afterwards. The groundwater flow will be verified with a 3D model considering varying thicknesses of the aquifer. Permanent water level and electrical conductivity readings, meteorological data and hydraulic conductivity from slug tests and grain size analysis are the base for the calibration of the numerical model.

Salinity of deep groundwater in California: Water quantity, quality, and protection.

PubMed

Kang, Mary; Jackson, Robert B

2016-07-12

Deep groundwater aquifers are poorly characterized but could yield important sources of water in California and elsewhere. Deep aquifers have been developed for oil and gas extraction, and this activity has created both valuable data and risks to groundwater quality. Assessing groundwater quantity and quality requires baseline data and a monitoring framework for evaluating impacts. We analyze 938 chemical, geological, and depth data points from 360 oil/gas fields across eight counties in California and depth data from 34,392 oil and gas wells. By expanding previous groundwater volume estimates from depths of 305 m to 3,000 m in California's Central Valley, an important agricultural region with growing groundwater demands, fresh [<3,000 ppm total dissolved solids (TDS)] groundwater volume is almost tripled to 2,700 km(3), most of it found shallower than 1,000 m. The 3,000-m depth zone also provides 3,900 km(3) of fresh and saline water, not previously estimated, that can be categorized as underground sources of drinking water (USDWs; <10,000 ppm TDS). Up to 19% and 35% of oil/gas activities have occurred directly in freshwater zones and USDWs, respectively, in the eight counties. Deeper activities, such as wastewater injection, may also pose a potential threat to groundwater, especially USDWs. Our findings indicate that California's Central Valley alone has close to three times the volume of fresh groundwater and four times the volume of USDWs than previous estimates suggest. Therefore, efforts to monitor and protect deeper, saline groundwater resources are needed in California and beyond.

Salinity of deep groundwater in California: Water quantity, quality, and protection

PubMed Central

Kang, Mary; Jackson, Robert B.

2016-01-01

Deep groundwater aquifers are poorly characterized but could yield important sources of water in California and elsewhere. Deep aquifers have been developed for oil and gas extraction, and this activity has created both valuable data and risks to groundwater quality. Assessing groundwater quantity and quality requires baseline data and a monitoring framework for evaluating impacts. We analyze 938 chemical, geological, and depth data points from 360 oil/gas fields across eight counties in California and depth data from 34,392 oil and gas wells. By expanding previous groundwater volume estimates from depths of 305 m to 3,000 m in California’s Central Valley, an important agricultural region with growing groundwater demands, fresh [<3,000 ppm total dissolved solids (TDS)] groundwater volume is almost tripled to 2,700 km3, most of it found shallower than 1,000 m. The 3,000-m depth zone also provides 3,900 km3 of fresh and saline water, not previously estimated, that can be categorized as underground sources of drinking water (USDWs; <10,000 ppm TDS). Up to 19% and 35% of oil/gas activities have occurred directly in freshwater zones and USDWs, respectively, in the eight counties. Deeper activities, such as wastewater injection, may also pose a potential threat to groundwater, especially USDWs. Our findings indicate that California’s Central Valley alone has close to three times the volume of fresh groundwater and four times the volume of USDWs than previous estimates suggest. Therefore, efforts to monitor and protect deeper, saline groundwater resources are needed in California and beyond. PMID:27354527

Using thermal-infrared imagery to delineate ground-water discharge

USGS Publications Warehouse

Banks, W.S.L.; Paylor, R.L.; Hughes, W.B.

1996-01-01

On March 8 and 9, 1992, a thermal-infrared-multispectral scanner (TIMS) was flown over two military ordnance disposal facilities at the Edgewood Area of Aberdeen Proving Ground, Maryland. The data, collected bythe National Aeronautics and Space Administration, in cooperation with the U.S. Army and the U.S. Geological Survey, were used to locate ground-water discharge zones in surface water. The images from the flight show areas where ground-water discharge is concentrated, as well as areas of diffuse discharge. Concentrated discharge is predominant in isolated or nearly isolated ponds and creeks in the study area. Diffuse dicharge is found near parts of the shoreline where the study area meets the surrounding estuaries of the Chesapeake Bay and the Gunpowder River. The average temperature for surface water, measured directly in the field, and the average temperature, calculated from atmospherically corrected TIMS images, was 10.6??C (Celsius) at the first of two sites. Potentiometric surface maps of both field sites show discharge toward the nontidal marshes, the estuaries which surround the field sites, and creeks which drain into the estuaries. The average measured temperature of ground water at both sites was 10.7??C. The calculated temperature from the TIMS imagery at both sites where ground-water discharge is concentrated within a surface-water body is 10.4??C. In the estuaries which surround the field sites, field measurements of temperature were made resulting in an average temperature of 9.0??C. The average calculated TIMS temperature from the estuaries was 9.3??C. Along the shoreline at the first site and within 40 to 80 meters of the western and southern shores of the second site, water was 1?? to 2??C warmer than water more than 80 meters away. The pattern of warmer water grading to cooler water in an offshore direction could result from diffuse ground-water discharge. Tonal differences in the TIMS imagery could indicate changes in surface

Geochemical and geophysical examination of submarine groundwater discharge and associated nutrient loading estimates into Lynch Cove, Hood Canal, WA

USGS Publications Warehouse

Swarzenski, P.W.; Simonds, F.W.; Paulson, A.J.; Kruse, S.; Reich, C.

2007-01-01

Geochemical tracer data (i.e., 222Rn and four naturally occurring Ra isotopes), electromagnetic (EM) seepage meter results, and high-resolution, stationary electrical resistivity images were used to examine the bi-directional (i.e., submarine groundwater discharge and recharge) exchange of a coastal aquifer with seawater. Our study site for these experiments was Lynch Cove, the terminus of Hood Canal, WA, where fjord-like conditions dramatically limit water column circulation that can lead to recurring summer-time hypoxic events. In such a system a precise nutrient budget may be particularly sensitive to groundwater-derived nutrient loading. Shore-perpendicular time-series subsurface resistivity profiles show clear, decimeter-scale tidal modulation of the coastal aquifer in response to large, regional hydraulic gradients, hydrologically transmissive glacial terrain, and large (4-5 m) tidal amplitudes. A 5-day 222Rn time-series shows a strong inverse covariance between 222Rn activities (0.5−29 dpm L-1) and water level fluctuations, and provides compelling evidence for tidally modulated exchange of groundwater across the sediment/water interface. Mean Rn-derived submarine groundwater discharge (SGD) rates of 85 ± 84 cm d-1 agree closely in the timing and magnitude with EM seepage meter results that showed discharge during low tide and recharge during high tide events. To evaluate the importance of fresh versus saline SGD, Rn-derived SGD rates (as a proxy of total SGD) were compared to excess 226Ra-derived SGD rates (as a proxy for the saline contribution of SGD). The calculated SGD rates, which include a significant (>80%) component of recycled seawater, are used to estimate associated nutrient (NH4+, Si, PO43-, NO3 + NO2, TDN) loads to Lynch Cove. The dissolved inorganic nitrogen (DIN = NH4 + NO2 + NO3) SGD loading estimate of 5.9 × 104 mol d-1 is 1−2 orders of magnitude larger than similar estimates derived from atmospheric deposition and surface water runoff

Groundwater seepage controls salinity in a hydrologically terminal basin of semi-arid northwest Australia

NASA Astrophysics Data System (ADS)

Skrzypek, Grzegorz; Dogramaci, Shawan; Rouillard, Alexandra; Grierson, Pauline F.

2016-11-01

Very small groundwater outflows have the potential to significantly impact the hydrochemistry and salt accumulation processes of notionally terminal basins in arid environments. However, this limited groundwater outflow can be very difficult to quantify using classical water budget calculations due to large uncertainties in estimates of evaporation and evapotranspiration rates from the surface of dry lake beds. In this study, we used a dimensionless time evaporation model to estimate the range of groundwater outflow required to maintain salinity levels observed at the Fortescue Marsh (FM), one of the largest wetlands of semi-arid northwest Australia (∼1100 km2). The groundwater outflow from aquifers underlying the FM to the Lower Fortescue catchment is constrained by an extremely low hydraulic gradient of <0.0001 and a small 'alluvial outlet' of 0.35 km2 because of relatively high bedrock elevation. However, FM groundwater salinity is far below saturation with respect to halite (TDS < 160 g/L), episodic flood water is fresh to brackish, and salt efflorescences are very sparse and evident only when the FM is dry. We show that if the FM was 100% "leakage free" i.e., a true terminal basin, groundwater would have achieved halite saturation (>300 g/L) after ∼45 ka. We calculated that only a very small seepage of ∼2G L/yr (∼0.03% of the FM water volume) is sufficient to maintain current salinity conditions. The minimum time required to develop the current hydrochemical groundwater composition under the FM ranges from ∼60 to ∼165 ka. We conclude that a dimensionless time evaporation model versus inflow over outflow ratio model is likely more suitable than classical water budget calculations for determining outflow from large saline lakes and to estimate groundwater seepage from hydrologically terminal basins.

Isotopic Techniques for Assessment of Groundwater Discharge to the Coastal Ocean

DTIC Science & Technology

2003-09-30

estimates of the pore water Rn activity. The red line (based on an average groundwater concentration of 170 dpm/L) is considered our best estimate and...Isotopic Techniques For Assessment of Groundwater Discharge to the Coastal Ocean William C. Burnett Department of Oceanography Florida State...evaluating the influence of submarine groundwater discharge (SGD) into the ocean. Our long-term goal is to develop geochemical tools (e.g., radon and

The origin and mechanisms of salinization of the Lower Jordan River

USGS Publications Warehouse

Farber, E.; Vengosh, A.; Gavrieli, I.; Marie, Amarisa; Bullen, T.D.; Mayer, B.; Holtzman, R.; Segal, M.; Shavit, U.

2004-01-01

The chemical and isotopic (87Sr/86Sr, ??11B, ??34Ssulfate, ??18Owater, ??15Nnitrate) compositions of water from the Lower Jordan River and its major tributaries between the Sea of Galilee and the Dead Sea were determined in order to reveal the origin of the salinity of the Jordan River. We identified three separate hydrological zones along the flow of the river: (1) A northern section (20 km downstream of its source) where the base flow composed of diverted saline and wastewaters is modified due to discharge of shallow sulfate-rich groundwater, characterized by low 87Sr/86Sr (0.7072), ??34Ssulfate (-2???), high ??11B (???36???), ??15Nnitrate (???15???) and high ??18Owater (-2 to-3???) values. The shallow groundwater is derived from agricultural drainage water mixed with natural saline groundwater and discharges to both the Jordan and Yarmouk rivers. The contribution of the groundwater component in the Jordan River flow, deduced from mixing relationships of solutes and strontium isotopes, varies from 20 to 50% of the total flow. (2) A central zone (20-50 km downstream from its source) where salt variations are minimal and the rise of 87Sr/86Sr and SO4/Cl ratios reflects predominance of eastern surface water flows. (3) A southern section (50-100 km downstream of its source) where the total dissolved solids of the Jordan River increase, particularly during the spring (70-80 km) and summer (80-100 km) to values as high as 11.1 g/L. Variations in the chemical and isotopic compositions of river water along the southern section suggest that the Zarqa River (87Sr/86Sr???0.70865; ??11B???25???) has a negligible affect on the Jordan River. Instead, the river quality is influenced primarily by groundwater discharge composed of sulfate-rich saline groundwater (Cl-=31-180 mM; SO4/Cl???0.2-0.5; Br/Cl???2-3??10-3; 87Sr/86Sr???0.70805; ??11B???30???; ??15Nnitrate ???17???, ??34Ssulfate=4-10???), and Ca-chloride Rift valley brines (Cl-=846-1500 mM; Br/Cl???6-8??10-3; 87Sr/86Sr???0

A hydrological budget (2002-2008) for a large subtropical wetland ecosystem indicates marine groundwater discharge accompanies diminished freshwater flow

USGS Publications Warehouse

Saha, Amartya K.; Moses, Christopher S.; Price, Rene M.; Engel, Victor; Smith, Thomas J.; Anderson, Gordon

2012-01-01

Water budget parameters are estimated for Shark River Slough (SRS), the main drainage within Everglades National Park (ENP) from 2002 to 2008. Inputs to the water budget include surface water inflows and precipitation while outputs consist of evapotranspiration, discharge to the Gulf of Mexico and seepage losses due to municipal wellfield extraction. The daily change in volume of SRS is equated to the difference between input and outputs yielding a residual term consisting of component errors and net groundwater exchange. Results predict significant net groundwater discharge to the SRS peaking in June and positively correlated with surface water salinity at the mangrove ecotone, lagging by 1 month. Precipitation, the largest input to the SRS, is offset by ET (the largest output); thereby highlighting the importance of increasing fresh water inflows into ENP for maintaining conditions in terrestrial, estuarine, and marine ecosystems of South Florida.

Investigation of groundwater-seawater interactions: a review

NASA Astrophysics Data System (ADS)

Purwoarminta, A.; Moosdorf, N.; Delinom, R. M.

2018-02-01

This paper is to review how to investigate the interactions between groundwater and seawater. Those interactions divide into two, which are submarine groundwater discharge and seawater intrusion. This investigation is important because the interactions can give impact to coastal aquifer and marine ecosystem. On land, fresh groundwater is vulnerable to seawater disturbance. Coastal aquifer is under pressure from abstraction caused by population, industry, and agriculture. The pumping can induce seawater intrusion and land subsidence. Then in marine, seawater mixes with freshwater and it decreases salinity. Low salinity will influence marine ecosystem. The ecosystem will be disturbed by groundwater discharge if that water is contaminated. Based on the argue investigation of groundwater-seawater interactions is important and must be accurate because the results are used for coastal water management. To investigate the interactions data, i.e., lithology, pumping tests, hydrochemical data, sea level rise estimates, precipitation data, geophysics, environmental isotopes, and drilling information, should be compiled. The interaction can feed a model to determine how much groundwater extraction happening on coastal areas to prevent seawater intrusion and land subsidence. Water resources management on coasts should consider groundwater-seawater interactions.

Salty or Sweet: Exploring the Challenges of Groundwater Salinization Within a Sustainability Framework

NASA Astrophysics Data System (ADS)

Basu, N. B.; Van Meter, K. J.; Tate, E.

2012-12-01

In semi-arid to arid landscapes under intensive irrigation, groundwater salinization can be a persistent and critical problem, leading to reduced agricultural productivity, limited access to fresh drinking water, and ultimately desertification. It is estimated that in India alone, problems of salinity are now affecting over 6 million hectares of agricultural land. In villages of the Mewat district of Haryana in Northern India, subsistence-level farming is the primary source of income, and farming families live under serious threat from increasing salinity levels, both in terms of crop production and adequate supplies of drinking water. The Institute for Rural Research and Development (IRRAD), a non-governmental organization (NGO) working in Mewat, has taken an innovative approach in this area to problems of groundwater salinization, using check dams and rainwater harvesting ponds to recharge aquifers in the freshwater zones of upstream hill areas, and to create freshwater pockets within the saline groundwater zones of down-gradient areas. Initial, pilot-scale efforts have led to apparent success in raising groundwater levels in freshwater zones and changing the dynamics of encroaching groundwater salinity, but the expansion of such efforts to larger-scale restoration is constrained by the availability of adequate resources. Under such resource constraints, which are typical of international development work, it becomes critical to utilize a decision-analysis framework to quantify both the immediate and long-term effectiveness and sustainability of interventions by NGOs such as IRRAD. In the present study, we have developed such a framework, linking the climate-hydrological dynamics of monsoon driven systems with village-scale socio-economic attributes to evaluate the sustainability of current restoration efforts and to prioritize future areas for intervention. We utilize a multi-dimensional metric that takes into account both physical factors related to water

Remaining uncertainties in the use of Rn-222 as a quantitative tracer of submarine groundwater discharge

USGS Publications Warehouse

Burnett, W.C.; Santos, I.R.; Weinstein, Y.; Swarzenski, P.W.; Herut, B.

2007-01-01

Research performed in many locations over the past decade has shown that radon is an effective tracer for quantifying submarine groundwater discharge (SGD). The technique works because both fresh and saline groundwaters acquire radon from the subterranean environment and display activities that are typically orders of magnitude greater than those found in coastal seawaters. However, some uncertainties and unanswered problems remain. We focus here on three components of the mass balance, each of which has some unresolved issues: (1) End-member radon - what to do if groundwater Rn measurements are highly variable? (2) Atmospheric evasion -do the standard gas exchange equations work under high-energy coastal mixing scenarios? And (3) "mixing" losses - are there other significant radon losses (e.g. recharge of coastal waters into the aquifer) besides those attributed to mixing with lower-activity waters offshore? We address these issues using data sets collected from several different types of coastal environment. Copyright ?? 2007 IAHS Press.

Screening for Groundwater Contaminants Discharging to Urban Streams

NASA Astrophysics Data System (ADS)

Roy, J. W.; Bickerton, G.; Voralek, J.

2009-05-01

Groundwater contaminated with urban pollutants can adversely affect freshwater aquatic ecosystems where it discharges to streams, lakes or wetlands. Generally such occurrences have been revealed following the discovery of contaminated groundwater plumes at a particular site or from wells in the area. Thus, this contaminant pathway tends to be dealt with on a site-specific and aquifer-focused basis. In contrast, surface water contaminant monitoring typically relies on bulk water concentrations from one or a small set of locations, thus ignoring the spatial variation in contaminant loading, potential losses to sediment or the atmosphere, and the full range of benthic components of the aquatic ecosystem. There are few studies outlining the extent of this contamination from the perspective of the surface water body's deeper benthic community, which might be expected to experience the greatest contaminant concentrations, on more than a local-scale. In this study, we report on an approach to stream-reach-screening for urban contaminants in discharging groundwater, with the focus on detection rather than accurate quantification. The methodology consists of a drive-point technique for sampling groundwater from below the stream bed (e.g. typically 50 cm) along a chosen reach at intervals of about 10 m. Groundwater samples were then analyzed for a wide range of common urban contaminants and general chemistry. This screening method was performed in three urban settings in Canada with known groundwater contamination, covering sections of about 140 to >500 m. The known contaminant plumes at each site were detected and roughly delineated. In addition, potential areas of previously-unknown groundwater contamination were also identified at each site. Contaminants included BTEX and other petroleum hydrocarbons, various chlorinated solvent compounds, nitrate, 1,4-dioxane, MTBE and elevated chloride (likely indicating road salt). These preliminary findings suggest that this approach

Impact Of Groundwater Discharge On Contaminant Behavior In Sediments

EPA Science Inventory

The discharge of groundwater into surface water may influence the concentrations and availability of contaminants in sediments. There are three predominant pathways by which groundwater may affect the characteristics of contaminated sediments: 1) direct contribution of contamin...

Regulated and unregulated halogenated disinfection byproduct formation from chlorination of saline groundwater.

PubMed

Szczuka, Aleksandra; Parker, Kimberly M; Harvey, Cassandra; Hayes, Erin; Vengosh, Avner; Mitch, William A

2017-10-01

Coastal utilities exploiting mildly saline groundwater (<150 mg/L chloride) may be challenged by disinfection byproduct (DBP) formation, a concern likely to increase with sea-level rise. Groundwater from North Carolina coastal aquifers is characterized by large variations in concentrations of halides (bromide up to 10,600 μg/L) and dissolved organic carbon (up to 5.7 mg-C/L). Formation of 33 regulated and unregulated halogenated DBPs, including trihalomethanes (THMs), haloacetic acids (HAAs), haloacetonitriles, haloacetamides, and haloacetaldehydes, was measured after simulated chlorination of 24 coastal North Carolina groundwater samples under typical chlorination conditions. Results of chlorination simulation show that THM levels exceeded the Primary Maximum Contaminant Levels in half of the chlorinated samples. Addition of halides to a low salinity groundwater (110 mg/L chloride) indicated that elevated bromide triggered DBP formation, but chloride was not a critical factor for their formation. DBP speciation, but not overall molar formation, was strongly correlated with bromide variations in the groundwater. THMs and HAAs dominated the measured halogenated DBPs on a mass concentration basis. When measured concentrations were weighted by metrics of toxic potency, haloacetonitriles, and to a lesser degree, haloacetaldehydes and HAAs, were the predominant contributors to calculated DBP-associated toxicity. For some samples exhibiting elevated ammonia concentrations, the addition of chlorine to form chloramines in situ significantly reduced halogenated DBP concentrations and calculated toxicity. HAAs dominated the calculated toxicity of chloraminated waters. Reverse osmosis treatment of saline groundwater (chloride >250 mg/L) can reduce DBP formation by removing halides and organic precursors. However, we show that in a case where reverse osmosis permeate is blended with a separate raw groundwater, the residual bromide level in the permeate could still exceed

Estimating the Change of Groundwater Salinization in the Central North China Plain for Sustainable Groundwater Utilization

NASA Astrophysics Data System (ADS)

Zhan, Y.; He, X.; Zheng, C.; Guo, Z.

2017-12-01

Due to the growing demand of food supplies and limited freshwater resources, North China Plain (NCP) is highly dependent on the groundwater resources. Groundwater overdraft has made NCP a closed hydrologic basin, where the connection between surface and groundwater has been cut off, which can lead to salt accumulation in the groundwater system. Thus it is imperative to investigate the overall salt balance in the region for sustainable utilization of groundwater resources, as well as to better understand the salt accumulating processes caused by groundwater pumping and return flow. The central plain of NCP (excluding the piedmont plain and coastal plain) is selected in the present study, where the groundwater salt content is mainly controlled by precipitation, irrigation, groundwater pumping and rock-water interaction in vertical direction; therefore, a conceptual 1-D mixing model is developed for salt balance calculation, where the salt content is expressed by the concentration of Total Dissolved Solid (TDS) in groundwater. Geological structures and regional water balance data are obtained from numerical groundwater models previously developed in the area. The simulation starts in year 1900 with a 50-year time step and groundwater vertical flow velocity starting with 2 m/y. TDS concentration is then calculated through salt input and output in each layer, with consideration of soil salt accumulation, change of precipitation, rock-water interaction etc. The results suggest that in a closed hydrologic basin, groundwater pumping and return flow will gradually increase salt content in the groundwater body from upper layers to lower layers resulting from the flushing of salt accumulated in the top soil layer. After two time steps, the model is able to reproduce the observed TDS concentration in present time with reasonable accuracy; and after six time steps, which correspond to 300 years, the whole central plain of NCP will be under the influence of high salinity, which

Fully integrated physically-based numerical modelling of impacts of groundwater extraction on surface and irrigation-induced groundwater interactions: case study Lower River Murray, Australia

NASA Astrophysics Data System (ADS)

Alaghmand, S.; Beecham, S.; Hassanli, A.

2013-07-01

Combination of reduction in the frequency, duration and magnitude of natural floods, rising saline water-table in floodplains and excessive evapotranspiration have led to an irrigation-induced groundwater mound forced the naturally saline groundwater onto the floodplain in the Lower River Murray. It is during the attenuation phase of floods that these large salt accumulations are likely to be mobilised and will discharge into the river. The Independent Audit Group for Salinity highlighted this as the most significant risk in the Murray-Darling Basin. South Australian government and catchment management authorities have developed salt interception schemes (SIS). This is to pump the highly saline groundwater from the floodplain aquifer to evaporation basins in order to reduce the hydraulic gradient that drives the regional saline groundwater towards the River Murray. This paper investigates the interactions between a river (River Murray in South Australia) and a saline semi-arid floodplain (Clarks Floodplain) significantly influenced by groundwater lowering (Bookpurnong SIS). Results confirm that groundwater extraction maintain a lower water-table and more fresh river water flux to the saline floodplain aquifer. In term of salinity, this may lead to less amount of solute stored in the floodplain aquifer. This occurs through two mechanisms; extracting some of the solute mass from the system and changing the floodplain groundwater regime from a losing to gaining one. Finally, it is shown that groundwater extraction is able to remove some amount of solute stored in the unsaturated zone and mitigate the floodplain salinity risk.

Estimated ground-water discharge by evapotranspiration from Death Valley, California, 1997-2001

USGS Publications Warehouse

DeMeo, Guy A.; Laczniak, Randell J.; Boyd, Robert A.; Smith, J. LaRue; Nylund, Walter E.

2003-01-01

The U.S. Geological Survey, in cooperation with the National Park Service and Inyo County, Calif., collected field data from 1997 through 2001 to accurately estimate the amount of annual ground-water discharge by evapotranspiration (ET) from the floor of Death Valley, California. Multispectral satellite-imagery and National Wetlands Inventory data are used to delineate evaporative ground-water discharge areas on the Death Valley floor. These areas are divided into five general units where ground-water discharge from ET is considered to be significant. Based upon similarities in soil type, soil moisture, vegetation type, and vegetation density; the ET units are salt-encrusted playa (21,287 acres), bare-soil playa (75,922 acres), low-density vegetation (6,625 acres), moderate-density vegetation (5,019 acres), and high-density vegetation (1,522 acres). Annual ET was computed for ET units with micrometeorological data which were continuously measured at six instrumented sites. Total ET was determined at sites that were chosen for their soil- and vegetated-surface conditions, which include salt-encrusted playa (extensive salt encrustation) 0.17 feet per year, bare-soil playa (silt and salt encrustation) 0.21 feet per year, pickleweed (pickleweed plants, low-density vegetation) 0.60 feet per year, Eagle Borax (arrowweed plants and salt grass, moderate-density vegetation) 1.99 feet per year, Mesquite Flat (mesquite trees, high-density vegetation) 2.86 feet per year, and Mesquite Flat mixed grasses (mixed meadow grasses, high-density vegetation) 3.90 feet per year. Precipitation, flooding, and ground-water discharge satisfy ET demand in Death Valley. Ground-water discharge is estimated by deducting local precipitation and flooding from cumulative ET estimates. Discharge rates from ET units were not estimated directly because the range of vegetation units far exceeded the five specific vegetation units that were measured. The rate of annual ground-water discharge by ET for

Seawater-groundwater exchange and nutrients carried by submarine groundwater discharge in different types of wetlands at Jiaozhou Bay, China

NASA Astrophysics Data System (ADS)

Qu, Wenjing; Li, Hailong; Huang, Hao; Zheng, Chunmiao; Wang, Chaoyue; Wang, Xuejing; Zhang, Yan

2017-12-01

In Jiaozhou Bay, there are four wetland types, including sandy beaches, mud flats, tidal marshes, and estuarine intertidal zones. Four typical transects representing each of the wetland types were selected to investigate the flow dynamics, seawater-groundwater exchange and nutrients carried by submarine groundwater discharge (SGD). Based on field measurements of groundwater heads and salinity along each transect, the SGD averaged over the observation period was estimated using generalized Darcy's law. The SGD along the four transects ranges from 3.6 × 10-3 to 7.6 cm/d with the maximum occurring at the sandy beach. The SGD rate has a good correlation with the hydraulic conductivities of the wetland sediments. There is a positive correlation between the ratio of NO3-N/DIN and SGD rates. The SGD-associated nutrient output rate ranges from 3.3 × 10-2 to 9.5 mmol/m2/d for DIN (dissolved inorganic nitrogen), and from 6.2 × 10-5 to 1.8 × 10-2 mmol/m2/d for DIP (dissolved inorganic phosphorus). Compared to the nutrients delivered by the river, nutrients carried by SGD provide a more important source for the phosphate-limited environment to plankton in Jiaozhou Bay.

Interaction between shallow groundwater, saline surface water and contaminant discharge at a seasonally and tidally forced estuarine boundary

NASA Astrophysics Data System (ADS)

Westbrook, S. J.; Rayner, J. L.; Davis, G. B.; Clement, T. P.; Bjerg, P. L.; Fisher, S. J.

2005-02-01

This paper presents findings from a 2-year field investigation of a dissolved hydrocarbon groundwater plume flowing towards a tidally and seasonally forced estuarine river system in Perth, Western Australia. Samples collected from transects of multiport wells along the riverbank and into the river, enabled mapping of the fine scale (0.5 m) vertical definition of the hydrocarbon plume and its longitudinal extent. Spear probing beneath the river sediments and water table, and transient monitoring of multiport wells (electrical conductivity) was also carried out to define the zone of mixing between river water and groundwater (the hyporheic zone) and its variability. The results showed that groundwater seepage into the estuarine surface sediments occurred in a zone less than 10 m from the high tide mark, and that this distance and the hyporheic transition zone were influenced by tidal fluctuations and infiltration of river water into the sediments. The dissolved BTEXN (benzene, toluene, ethylbenzene, the xylene isomers and naphthalene) distributions indicated the behaviour of the hydrocarbon plume at the groundwater/surface water transition zone to be strongly influenced by edge-focussed discharge. Monitoring programs and risk assessment studies at similar contaminated sites should therefore focus efforts within the intertidal zone where contaminants are likely to impact the surface water and shallow sediment environments.

Airborne EM, Lithology and in-situ Data Used for Quantizing Groundwater Salinity in Zeeland (NL)

NASA Astrophysics Data System (ADS)

Meyer, U.; Siemon, B.; van Baaren, E.; Dabekaussen, W.; Delsman, J. R.; Karaoulis, M.; Gunnink, J.; Pauw, P.; Vermaas, T.

2017-12-01

In a setting of predominantly saline surface waters in Zeeland, the Netherlands, the only available shallow fresh groundwater is present in the form of freshwater lenses floating on top of the saline groundwater. This fresh water is vital for agricultural, industrial, ecological, water conservation and drinking water functions. An essential first step for managing the usable water properly is to know the present spatial fresh-brackish-saline groundwater distribution. As traditional salinity monitoring is labor-intensive, airborne electromagnetics, which is fast and can cover large areas in short time, is an efficient alternative. A consortium of BGR, Deltares and TNO conducted FRESHEM Zeeland (FREsh Salt groundwater distribution by Helicopter ElectroMagnetic survey in the Province of Zeeland) in 2014-17. An area of more than 2000 square km was surveyed using BGR's helicopter-borne geophysical system totaling to about 9,600 line-km. The HEM data, after inversion to 2.5 Million resistivity-depth models for each of the three 1D inversion procedures applied (Marquardt single site, smooth and sharp laterally constrained inversion), served as base-line information for further interpretation. A probabilistic Monte Carlo approach combines HEM resistivities, 3D lithology model data (GeoTOP), laboratory results (formation factor and surface conductivity) and local in-situ groundwater measurements for the translation of resistivity to Chloride concentration. The resulting 3D voxel model enables stakeholders to implement spatial Chloride concentration in their groundwater models.

Improving Estimation of Submarine Groundwater Discharge Using Radium and Radon Tracers: Application in Jiaozhou Bay, China

NASA Astrophysics Data System (ADS)

Zhang, Yan; Li, Hailong; Xiao, Kai; Wang, Xuejing; Lu, Xiaoting; Zhang, Meng; An, An; Qu, Wenjing; Wan, Li; Zheng, Chunmiao; Wang, Xusheng; Jiang, Xiaowei

2017-10-01

Radium and radon mass balance models have been widely used to quantify submarine groundwater discharge (SGD) in the coastal areas. However, the losses of radium or radon in seawater caused by recirculated saline groundwater discharge (RSGD) are ignored in most of the previous studies for tracer-based models and this can lead to an underestimation of SGD. Here we present an improved method which considers the losses of tracers caused by RSGD to enhance accuracy in estimating SGD and SGD-associated material loadings. Theoretical analysis indicates that neglecting the losses of tracers induced by RSGD would underestimate the SGD by a percentage approximately equaling the tracer activity ratio of nearshore seawater to groundwater. The data analysis of previous typical case studies shows that the existing old models underestimated the SGD by 1.9-93%, with an average of 32.2%. The method is applied in Jiaozhou Bay (JZB), North China, which is experiencing significant environmental pollution. The SGD flux into JZB estimated by the improved method is ˜1.44 and 1.34 times of that estimated by the old method for 226Ra mass balance model and 228Ra mass balance model, respectively. Both SGD and RSGD fluxes are significantly higher than the discharge rate of Dagu River (the largest one running into JZB). The fluxes of nutrients and metals through SGD are comparable to or even higher than those from local rivers, which indicates that SGD is an important source of chemicals into JZB and has important impact on marine ecological system.

Simulating Salt Movement using a Coupled Salinity Transport Model in a Variably Saturated Agricultural Groundwater System

NASA Astrophysics Data System (ADS)

Tavakoli Kivi, S.; Bailey, R. T.; Gates, T. K.

2017-12-01

Salinization is one of the major concerns in irrigated agricultural fields. Increasing salinity concentrations are due principally to a high water table that results from excessive irrigation, canal seepage, and a lack of efficient drainage systems, and lead to decreasing crop yield. High groundwater salinity loading to nearby river systems also impacts downstream areas, with saline river water diverted for application on irrigated fields. To assess the different strategies for salt remediation, we present a reactive transport model (UZF-RT3D) coupled with a salinity equilibrium chemistry module for simulating the fate and transport of salt ions in a variably-saturated agricultural groundwater system. The developed model accounts not for advection, dispersion, nitrogen and sulfur cycling, oxidation-reduction, sorption, complexation, ion exchange, and precipitation/dissolution of salt minerals. The model is applied to a 500 km2 region within the Lower Arkansas River Valley (LARV) in southeastern Colorado, an area acutely affected by salinization in the past few decades. The model is tested against salt ion concentrations in the saturated zone, total dissolved solid concentrations in the unsaturated zone, and salt groundwater loading to the Arkansas River. The model now can be used to investigate salinity remediation strategies.

Estimation of Shallow Groundwater Discharge and Nutrient Load into a River

Treesearch

Ying Ouyang

2012-01-01

Pollution of rivers with excess nutrients due to groundwater discharge, storm water runoff, surface loading,and atmospheric deposition is an increasing environmental concern worldwide. While the storm water runoff and surface loading of nutrients into many rivers have been explored in great detailed, the groundwater discharge of nutrients into the rivers has not yet...

Impact of submarine groundwater discharge heat-flux on the coastal area

NASA Astrophysics Data System (ADS)

Yamada, M.; Sugimoto, R.; Honda, H.

2016-12-01

Various studies regarding submarine groundwater discharge (SGD) have been performed. Although SGD has been recognized as an important pathway for nutrients transport from land to coastal ocean, SGD also supplies other chemical compositions as well as heat in the form of thermal energy. Especially, there is a difference in water temperatures of SGD and seawater, since groundwater temperature is almost constant throughout the year and seawater temperature varies. However, it is not clear that how much heat energy is supplied by SGD and its associated impacts on coastal ecosystems. Several studies assessing the impact of drainage water from the power plants have indicated that the water temperature has a significant impact on the coastal ecosystems. It highlights the need for assessing the impact of SGD on coastal ecosystems not only by considering the nutrient influx but also by giving equal importance to inflow water temperatures. To investigate this hypothesis, we undertook a study in a coastal area of Obama Bay, Fukui Prefecture, Japan.In Obama Bay, SGD rate has been estimated using 222Rn and salinity mass balance model (Sugimoto et al., 2016). We calculated the heat quantity from SGD by using the formula [E = Q * Cp * ΔT], where, E is the heat quantity from SGD; Q is the SGD rate from Sugimoto et al. (2016); Cp is the specific heat at constant pressure; and ΔT is the difference between seawater and groundwater temperatures. Additionally, we investigated the temperature distribution of sea-bed near the coastal area. Based the finding of this study, we provide detailed insights into the heat impacts of SGD in the coastal areas. The following results are obtained from this study: The SGD resulted in hot and cold heat influx to the coastal areas during winter and summer seasons, respectively. Although SGD rate is observed much less than the river discharge, cold heat flux from SGD was greater than the river during summer. SGD resulted in lowering the sea water

The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

USGS Publications Warehouse

Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Mathew; Clark, Jordan F.

2018-01-01

Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

NASA Astrophysics Data System (ADS)

Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Matthew; Clark, Jordan F.

2018-02-01

Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

Bank storage buffers rivers from saline regional groundwater: an example from the Avon River Australia

NASA Astrophysics Data System (ADS)

Gilfedder, Benjamin; Hofmann, Harald; Cartwrighta, Ian

2014-05-01

Groundwater-surface water interactions are often conceptually and numerically modeled as a two component system: a groundwater system connected to a stream, river or lake. However, transient storage zones such as hyporheic exchange, bank storage, parafluvial flow and flood plain storage complicate the two component model by delaying the release of flood water from the catchment. Bank storage occurs when high river levels associated with flood water reverses the hydraulic gradient between surface water and groundwater. River water flows into the riparian zone, where it is stored until the flood water recede. The water held in the banks then drains back into the river over time scales ranging from days to months as the hydraulic gradient returns to pre-flood levels. If the frequency and amplitude of flood events is high enough, water held in bank storage can potentially perpetually remain between the regional groundwater system and the river. In this work we focus on the role of bank storage in buffering river salinity levels against saline regional groundwater on lowland sections of the Avon River, Victoria, Australia. We hypothesize that the frequency and magnitude of floods will strongly influence the salinity of the stream water as banks fill and drain. A bore transect (5 bores) was installed perpendicular to the river and were instrumented with head and electrical conductivity loggers measuring for two years. We also installed a continuous 222Rn system in one bore. This data was augmented with long-term monthly EC from the river. During high rainfall events very fresh flood waters from the headwaters infiltrated into the gravel river banks leading to a dilution in EC and 222Rn in the bores. Following the events the fresh water drained back into the river as head gradients reversed. However the bank water salinities remained ~10x lower than regional groundwater levels during most of the time series, and only slightly above river water. During 2012 SE Australia

Combined time-series resistivity and geochemical tracer techniques to examine submarine groundwater discharge at Dor Beach, Israel

USGS Publications Warehouse

Swarzenski, P.W.; Burnett, W.C.; Greenwood, W.J.; Herut, B.; Peterson, R.; Dimova, N.; Shalem, Y.; Yechieli, Y.; Weinstein, Y.

2006-01-01

A high-resolution, stationary geophysical and geochemical survey was conducted at Dor Beach, Israel, to examine the shallow coastal hydrogeology and its control on the exchange of submarine groundwater with the shallow Mediterranean Sea. Time-series resistivity profiles using a new 56 electrode (112-m long) marine cable produced detailed profiles of the fresh water/salt water interface and the subtle response of this interface to tidal excursions and other forcing factors. Such information, when ground-truthed with representative pore water salinities and formation resistivity values, can provide unique information of the extent and rates of submarine groundwater discharge (SGD). Time-series 222Rn measurements of the adjacent coastal water column complemented these geophysical techniques and were modeled to yield integrated advective flow rates across the sediment/water interface, which at Dor Beach ranged from about 0 to 30 cm day-1 (mean = 7.1 cm d-1), depending on the tidal range. Such results suggest that the underlying hydrogeologic framework at Dor is favorable for substantial SGD. Extrapolating these SGD estimates across a 100-m wide coastal zone implies that the Rn-derived SGD rate would equal ???7.1 m3 d-1 per m of shoreline, and that the source of this discharging groundwater is a complex mixture of fresh groundwater derived from the upland Kurkar deposits, as well as locally recycled seawater. Copyright 2006 by the American Geophysical Union.

Mapping Submarine Groundwater Discharge - how to investigate spatial discharge variability on coastal and beach scales

NASA Astrophysics Data System (ADS)

Stieglitz, T. C.; Burnett, W. C.; Rapaglia, J.

2008-12-01

Submarine groundwater discharge (SGD) is now increasingly recognized as an important component in the water balance, water quality and ecology of the coastal zone. A multitude of methods are currently employed to study SGD, ranging from point flux measurements with seepage meters to methods integrating over various spatial and temporal scales such as hydrological models, geophysical techniques or surface water tracer approaches. From studies in a large variety of hydrogeological settings, researchers in this field have come to expect that SGD is rarely uniformly distributed. Here we discuss the application of: (a) the mapping of subsurface electrical conductivity in a discharge zone on a beach; and (b) the large-scale mapping of radon in coastal surface water to improving our understanding of SGD and its spatial variability. On a beach scale, as part of intercomparison studies of a UNESCO/IAEA working group, mapping of subsurface electrical conductivity in a beach face have elucidated the non-uniform distribution of SGD associated with rock fractures, volcanic settings and man-made structures (e.g., piers, jetties). Variations in direct point measurements of SGD flux with seepage meters were linked to the subsurface conductivity distribution. We demonstrate how the combination of these two techniques may complement one another to better constrain SGD measurements. On kilometer to hundred kilometer scales, the spatial distribution and regional importance of SGD can be investigated by mapping relevant tracers in the coastal ocean. The radon isotope Rn-222 is a commonly used tracer for SGD investigations due to its significant enrichment in groundwater, and continuous mapping of this tracer, in combination with ocean water salinity, can be used to efficiently infer locations of SGD along a coastline on large scales. We use a surface-towed, continuously recording multi-detector setup installed on a moving vessel. This tool was used in various coastal environments, e

The limited and localized flow of fresh groundwater to the world's oceans

NASA Astrophysics Data System (ADS)

Luijendijk, E.; Gleeson, T. P.; Moosdorf, N.

2017-12-01

Submarine groundwater discharge, the flow of fresh or saline groundwater to oceans [Burnett et al., 2003], may be a significant contributor to the water and chemical budgets of the world's oceans [Taniguchi et al., 2002] potentially buffering ocean acidification with groundwater alkalinity and is arguably the most uncertain component of the global groundwater budget [Alley et al., 2002]. The fresh component of submarine groundwater discharge is critical due to its high solute and nutrient load, and has been quantified locally and but only roughly estimated globally using significant assumptions. Here we show that that fresh submarine groundwater discharge is an insignificant water contributor to global oceans (0.05% of the total input) but that the freshwater discharge may still be an important chemical and nutrient contributor especially around distinct hotspots. The first spatially-explicit, physically-based global estimate of fresh submarine groundwater discharge was derived by combining density-dependent numerical groundwater models and a geospatial analysis of global coastal watersheds to robustly simulate the partitioning of onshore and offshore groundwater discharge. Although fresh submarine groundwater discharge is an insignificant part of fresh coastal groundwater discharge, results are consistent with previous estimates of significant recirculated seawater discharging as groundwater as well as quantifying the significant near-shore terrestrial discharge, a flux that has so far been overlooked in global hydrological studies and that affects coastal water budgets, evapotranspiration and ecosystems.

Estimating discharge of shallow groundwater by transpiration from greasewood in the Northern Great Basin

USGS Publications Warehouse

Nichols, William D.

1993-01-01

Evapotranspiration from bare soil and phreatophytes is a principal mechanism of groundwater discharge in arid and semiarid regions of the midwestern and western United States including the Great Basin. The imbalance between independent estimates of groundwater recharge from precipitation and of groundwater discharge based on estimates of groundwater evapotranspiration leads to large uncertainties in groundwater budgets. Few studies have addressed this problem. Energy budget micrometeorological field studies were conducted in a stand of sparse-canopy greasewood growing in an area of shallow groundwater in the western Great Basin during the summer of 1989. The data were used to calculate above-canopy fluxes of sensible and latent heat using the energy budget-Bowen ratio method. The calculated energy budget fluxes were used, with soil surface and plant canopy temperature measurements, to calibrate and apply a two-component, energy-combination model that partitions the energy and heat fluxes between bare soil and the canopy. This permitted the separation of evaporation from the soil and transpiration from greasewood. The calibrated model was used to estimate daily transpiration of groundwater by greasewood growing in an area with a depth to water of about 2 m. The daily rate of groundwater discharge by transpiration during July and August was estimated to be 2.4 mm. A period of 100 days for groundwater discharge at this rate was assumed to estimate an annual discharge of groundwater of 24 cm at the study site.

Probability analysis of the relation of salinity to freshwater discharge in the St. Sebastian River, Florida

USGS Publications Warehouse

Wicklein, S.M.; Gain, W.S.

1999-01-01

The St. Sebastian River lies in the southern part of the Indian River basin on the east coast of Florida. Increases in freshwater discharge due to urbanization and changes in land use have reduced salinity in the St. Sebastian River and, consequently, salinity in the Indian River, affecting the commercial fishing industry. Wind, water temperature, tidal flux, freshwater discharge, and downstream salinity all affect salinity in the St. Sebastian River estuary, but freshwater discharge is the only one of these hydrologic factors which might be affected by water-management practices. A probability analysis of salinity conditions in the St. Sebastian River estuary, taking into account the effects of freshwater discharge over a period from May 1992 to March 1996, was used to determine the likelihood (probability) that salinities, as represented by daily mean specific- conductance values, will fall below a given threshold. The effects of freshwater discharge on salinities were evaluated with a simple volumetric model fitted to time series of measured specific conductance, by using nonlinear optimization techniques. Specific-conductance values for two depths at monitored sites represent stratified flow which results from differences in salt concentration between freshwater and saltwater. Layering of freshwater and saltwater is assumed, and the model is applied independently to each layer with the assumption that the water within the layer is well mixed. The model of specific conductance as a function of discharge (a salinity response model) was combined with a model of residual variation to produce a total probability model. Flow distributions and model residuals were integrated to produce a salinity distribution and determine differences in salinity probabilities as a result of changes in water-management practices. Two possible management alternatives were analyzed: stormwater detention (reducing the peak rate of discharge but not reducing the overall flow volume) and

Quantification of submarine groundwater discharge and its short-term dynamics by linking time-variant end-member mixing analysis and isotope mass balancing (222-Rn)

NASA Astrophysics Data System (ADS)

Petermann, Eric; Knöller, Kay; Stollberg, Reiner; Scholten, Jan; Rocha, Carlos; Weiß, Holger; Schubert, Michael

2017-04-01

Submarine groundwater discharge (SGD) plays a crucial role for the water quality of coastal waters due to associated fluxes of nutrients, organic compounds and/or heavy-metals. Thus, the quantification of SGD is essential for evaluating the vulnerability of coastal water bodies with regard to groundwater pollution as well as for understanding the matter cycles of the connected water bodies. Here, we present a scientific approach for quantifying discharge of fresh groundwater (GWf) and recirculated seawater (SWrec), including its short-term temporal dynamics, into the tide-affected Knysna estuary, South Africa. For a time-variant end-member mixing analysis we conducted time-series observations of radon (222Rn) and salinity within the estuary over two tidal cycles in combination with estimates of the related end-members for seawater, river water, GWf and SWrec. The mixing analysis was treated as constrained optimization problem for finding an end-member mixing ratio that simultaneously fits the observed data for radon and salinity best for every time-step. Uncertainty of each mixing ratio was quantified by Monte Carlo simulations of the optimization procedure considering uncertainty in end-member characterization. Results reveal the highest GWf and SWrec fraction in the estuary during peak low tide with averages of 0.8 % and 1.4 %, respectively. Further, we calculated a radon mass balance that revealed a daily radon flux of 4.8 * 108 Bq into the estuary equivalent to a GWf discharge of 29.000 m3/d (9.000-59.000 m3/d for 25th-75th percentile range) and a SWrec discharge of 80.000 m3/d (45.000-130.000 m3/d for 25th-75th percentile range). The uncertainty of SGD reflects the end-member uncertainty, i.e. the spatial heterogeneity of groundwater composition. The presented approach allows the calculation of mixing ratios of multiple uncertain end-members for time-series measurements of multiple parameters. Linking these results with a tracer mass balance allows conversion

Distinct kinetics and mechanisms of mZVI particles aging in saline and fresh groundwater: H2 Evolution and surface passivation

NASA Astrophysics Data System (ADS)

Xin, Jia; Tang, Fenglin; Zheng, Xilai

2016-04-01

Application of microscale zero-valent iron (mZVI) is a promising technology for in-situ contaminated groundwater remediation. However, its longevity would be negatively impacted by surface passivation, especially in saline groundwater. In this study, the aging behaviors of mZVI particles were investigated in three media (milli-Q water, fresh groundwater and saline groundwater) using batch experiments to evaluate their potential corrosion and passivation performance in different field conditions. The results indicated that mZVI was reactive between 0-7 days exposure to water and then gradually lost reactivity over the next few hundred days. The patterns of kinetic curve were analogous among the three different media. In comparison, during the early phase (0-7 d), mZVI in saline groundwater showed a faster corrosion rate with a k value of 1.357, which was relatively higher than k values in milli-Q water and fresh groundwater. However, as the corrosion process further developed, the fastest corrosion rate was observed in milli-Q water followed with fresh groundwater and saline groundwater. These changes in reactivity provided evidence for different patterns and formation mechanisms of passive layers on mZVI in three media. The SEM-EDS analysis demonstrated that in the saline groundwater, a compact and even oxide film of carbonate green rust or Fe oxide (hydroxyl) species was formed immediately on the surface due to the high concentration and widely distributed bicarbonate and hardness, whereas in the fresh groundwater and milli-Q water, the passive layer was composed of loosely and unevenly distributed precipitates which much slowly formed as the iron corrosion proceeded. These findings provide insight into the molecular-scale mechanism of mZVI passivation by inorganic salts with particular implications in saline groundwater.

Characterization of the Spatial and Temporal Variations of Submarine Groundwater Discharge Using Electrical Resistivity and Seepage Measurements

NASA Astrophysics Data System (ADS)

Durand, Josephine Miryam Kalyanie

Submarine groundwater discharge (SGD) encompasses all fluids crossing the sediment/ocean interface, regardless of their origin, composition or driving forces. SGD provides a pathway for terrestrial contaminants that can significantly impact coastal ecosystems. Overexploitation of groundwater resources can decrease SGD which favors seawater intrusion at depth. Understanding SGD is therefore crucial for water quality and resource management. Quantifying SGD is challenging due to its diffuse and heterogeneous nature, in addition to significant spatio-temporal variations at multiple scales. In this thesis, an integrated approach combining electrical resistivity (ER) surveys, conductivity and temperature point measurements, seepage rates using manual and ultrasonic seepage meters, and pore fluid salinities was used to characterize SGD spatio-temporal variations and their implications for contaminant transport at several locations on Long Island, NY. The influence of surficial sediments on SGD distribution was investigated in Stony Brook Harbor. A low-permeability mud layer, actively depositing in the harbor, limits SGD at the shoreline, prevents mixing with seawater and channels a significant volume of freshwater offshore. SGD measured at locations without mud is high and indicates significant mixing between porewater and seawater. A 2D steady-state density-difference numerical model of the harbor was developed using SEAWAT and was validated by our field observations. Temporal variations of SGD due to semi-diurnal tidal forcing were studied in West Neck Bay, Shelter Island, using a 12-hr time-lapse ER survey together with continuous salinity and seepage measurements in the intertidal zone. The observed dynamic patterns of groundwater flux and salinity distribution disagree with published standard transient state numerical models, suggesting the need for developing more specific models of non-homogeneous anisotropic aquifers. SGD distribution and composition were

The Slow Moving Threat of Groundwater Salinization: Mechanisms, Costs, and Adaptation Strategies

NASA Astrophysics Data System (ADS)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2016-12-01

Population growth, the Green Revolution, and climate uncertainties have accelerated overdraft in groundwater basins worldwide, which in some regions is converting these basins into closed hydrologic systems, where the dominant exits for water are evapotranspiration and pumping. Irrigated agricultural basins are particularly at risk to groundwater salinization, as naturally occurring (i.e., sodium, potassium, chloride) and anthropogenic (i.e., nitrate fertilizers) salts leach back into the water table through the root zone, while a large portion of pumped groundwater leaves the system as it is evapotranspired by crops. Decreasing water quality associated with increases in Total Dissolved Solids (TDS) has been documented in aquifers across the United States in the past half century. This study suggests that the increase in TDS in aquifers can be partially explained by closed basin hydrogeology and rock-water interactions leading to groundwater salinization. This study will present: (1) a report on historical water quality in the Tulare basin, (2) a forward simulation of salt balance in Tulare Basin based on the Department of Water Resources numerical model C2VSim, and a simple mixing model, (3) an economic analysis forecasting the cost of desalination under varying degrees of managed groundwater recharge where the basin is gradually filled, avoiding hydraulic closure.

On the origin of saline soils at Blackspring Ridge, Alberta, Canada

NASA Astrophysics Data System (ADS)

Stein, Richard; Schwartz, Franklin W.

1990-09-01

Problems of soil salinity occur at Blackspring Ridge, Alberta, in four different settings. The most seriously affected area is at the base of the ridge where salinity appears as severe salt crusting on the surface, salt-tolerant vegetation, and areas of poor or no crop production. Blackspring Ridge is a structural bedrock high that is underlain by Upper Cretaceous sediment of the Horseshoe Canyon Formation. Bedrock is overlain by fluvial, glacial, lacustrine, and aeolian sediment. Piezometric data indicate that groundwater is recharged on and along the upper flanks of Blackspring Ridge and discharges in southern parts of a lacustrine plain that surrounds the ridge. Hydraulic conductivity data, water-level fluctuations, stable isotopes, and hydrochemical data indicate that the fractured near-surface bedrock and overlying thin-drift sediment constitute a zone of active groundwater flow within which salts are generated and transported. Water discharging from this shallow system evaporates and forms saline areas at the base of the ridge. The most seriously affected areas on the lacustrine plain coincide with places where the water table is less than 1.5m from the ground surface. A high water table occurs locally because of the changing topology of geologic units, and lows in the topographic surface that focus groundwater and surface water flows. Some proportion of the shallow groundwater salinized by evaporation is also transported down the flow system where it mixes with unevaporated water. Surface water, from snowmelt and precipitation events, dissolves salt that was deposited at the surface by evaporating groundwater and redistributes the salt to areas of lower elevation.

Management scenarios for the Jordan River salinity crisis

USGS Publications Warehouse

Farber, E.; Vengosh, A.; Gavrieli, I.; Marie, Amarisa; Bullen, T.D.; Mayer, B.; Holtzman, R.; Segal, M.; Shavit, U.

2005-01-01

Recent geochemical and hydrological findings show that the water quality of the base flow of the Lower Jordan River, between the Sea of Galilee and the Dead Sea, is dependent upon the ratio between surface water flow and groundwater discharge. Using water quality data, mass-balance calculations, and actual flow-rate measurements, possible management scenarios for the Lower Jordan River and their potential affects on its salinity are investigated. The predicted scenarios reveal that implementation of some elements of the Israel-Jordan peace treaty will have negative effects on the Jordan River water salinity. It is predicted that removal of sewage effluents dumped into the river (???13 MCM/a) will significantly reduce the river water's flow and increase the relative proportion of the saline groundwater flux into the river. Under this scenario, the Cl content of the river at its southern point (Abdalla Bridge) will rise to almost 7000 mg/L during the summer. In contrast, removal of all the saline water (16.5 MCM/a) that is artificially discharged into the Lower Jordan River will significantly reduce its Cl concentration, to levels of 650-2600 and 3000-3500 mg/L in the northern and southern areas of the Lower Jordan River, respectively. However, because the removal of either the sewage effluents or the saline water will decrease the river's discharge to a level that could potentially cause river desiccation during the summer months, other water sources must be allocated to preserve in-stream flow needs and hence the river's ecosystem. ?? 2005 Elsevier Ltd. All rights reserved.

Distinct kinetics and mechanisms of mZVI particles aging in saline and fresh groundwater: H2 evolution and surface passivation.

PubMed

Xin, Jia; Tang, Fenglin; Zheng, Xilai; Shao, Haibing; Kolditz, Olaf; Lu, Xin

2016-09-01

Application of microscale zero-valent iron (mZVI) is a promising technology for in-situ contaminated groundwater remediation; however, its longevity is negatively impacted by surface passivation, especially in saline groundwater. In this study, the aging behavior of mZVI particles was investigated in three media (milli-Q water, fresh groundwater and saline groundwater) using batch experiments to evaluate their potential corrosion and passivation performance under different field conditions. The results indicated that mZVI was reactive for 0-7 days of exposure to water and then gradually lost H2-generating capacity over the next hundred days in all of the tested media. In comparison, mZVI in saline groundwater exhibited the fastest corrosion rate during the early phase (0-7 d), followed by the sharpest kinetic constant decline in the latter phases. The SEM-EDS and XPS analyses demonstrated that in the saline groundwater, a thin and compact oxide film was immediately formed on the surface and significantly shielded the iron reactive site. Nevertheless, in fresh groundwater and milli-Q water, a passive layer composed of loosely and unevenly distributed precipitates slowly formed, with abundant reactive sites available to support continuous iron corrosion. These findings provide insight into the molecular-scale mechanism that governs mZVI passivation and provide implications for long-term mZVI application in saline contaminated groundwater. Copyright © 2016 Elsevier Ltd. All rights reserved.

Relationships between groundwater, surface water, and soil salinity in Polder 32, Southwest Bangladesh

NASA Astrophysics Data System (ADS)

Fry, D. C.; Ayers, J. C.

2014-12-01

In the coastal areas of Southwest Bangladesh polders are surrounded by tidal channels filled with brackish water. In the wet season, farmers create openings in the embankments to irrigate rice paddies. In the dry season, farmers do the same to create saline shrimp ponds. Residents on Polder 32, located within the Ganges-Brahmaputra-Meghna delta system, practice these seasonal farming techniques. Soils in the area are entisols, being sediment recently deposited, and contain mostly silt-sized particles. Brackish water in brine shrimp ponds may deposit salt in the soil, causing soil salinization. However, saline connate groundwater could also be contributing to soil salinization. Groundwater, surface water (fresh water pond, rice paddy and tidal channel water) and soil samples have been analyzed via inductively coupled plasma optical emission spectroscopy, inductively coupled plasma mass spectroscopy and ion chromatography in an attempt to correlate salinity measurements with each other in order to determine major sources of soil salinity. Multiple parameters, including distances of samples from tidal channels, inland streams, shrimp ponds and tube wells were measured to see if spatial correlations exist. Similarly, values from wet and dry seasons were compared to quantify temporal variations. Salt content in many soil samples were found to be high enough to significantly decrease rice yields. Continued soil salinization can decrease these yields even more, leading to farmers not producing enough food to sustain their families.

Isotopic Techniques for Assessment of Groundwater Discharge to the Coastal Ocean

DTIC Science & Technology

2002-09-30

of the groundwater tracer. This may then be divided by the estimated groundwater Ra concentration to derive a water flux. 3...residence times of coastal waters . If one assumes that the source of short-lived radium isotopes is groundwater with a constant isotopic composition...Isotopic Techniques for Assessment of Groundwater Discharge to the Coastal Ocean William C. Burnett Department of Oceanography Florida State

Sea Surface Salinity Variability in Response to the Congo River Discharge

NASA Astrophysics Data System (ADS)

Moller, D.; Chao, Y.; Farrara, J. D.; Schumann, G.; Andreadis, K.

2014-12-01

Sea surface salinity (SSS) variability associated with the Congo River discharge is examined using Aquarius satellite-retrieved SSS data and vertical profiles of salinity measured by the Argo floats. The Congo River plume can be clearly identified in the Aquarius SSS data with a westward extension of 500 to 1000 km off the coast of the Democratic Republic of Congo (DRC). The peak amplitude of the SSS variability associated with the Congo River discharge exceeds 2.0 psu. Using the first two years of Aquarius data, a well-defined seasonal cycle is described: maximum fresh-water anomalies are found in the boreal winter and spring seasons. The fresh-water anomalies during the 2012-2013 winter and spring seasons are significantly fresher than the 2011-2012 winter and spring seasons. Vertical profiles of salinity derived from the Argo floats reveal that these fresh-water anomalies can be traced to 40 meters below the sea surface. Combining the Aquarius SSS data with the Argo vertical profiles of salinity, the 3D volume of these fresh-water anomalies can be inferred and used to estimate the Congo River discharge. Reasonably good agreement is found between the Congo River discharge as observed by a stream gauge at Kinshasa and that estimated from the combined Aquarius and Argo data, indicating that Aquarius data can be used to close the fresh-water budget between the coastal ocean and the Congo River. The precipitation minus evaporation portion of the freshwater flux is found to play a secondary role in this region.

Flow and discharge of groundwater from a snowmelt-affected sandy beach

NASA Astrophysics Data System (ADS)

Chaillou, G.; Lemay-Borduas, F.; Larocque, M.; Couturier, M.; Biehler, A.; Tommi-Morin, G.

2018-02-01

The study is based on a complex and unique data set of water stable isotopes (i.e., δ18O and δ2H), radon-222 activities (i.e., 222Rn) and groundwater levels to better understand the interaction of fresh groundwater and recirculated seawater in a snowmelt-affected subterranean estuary (STE) in a boreal region (Îles-de-la-Madeleine, Qc, Canada). By using a combination of hydrogeological and marine geochemical approaches, the objective was to analyze and quantify submarine groundwater discharge processes through a boreal beach after the snow melt period, in early June. The distribution of δ18O and δ2H in beach groundwater showed that inland fresh groundwater contributed between 97 and 30% of water masses presented within the STE. A time series of water table levels during the 16 days of the study indicated that tides propagated as a dynamic wave limiting the mass displacement of seawater within the STE. This up-and-down movement of the water table (∼10-30 cm) induced the vertical infiltration of seawater at the falling tide. At the front of the beach, a radon-based mass balance calculated with high-resolution 222Rn survey estimated total SGD of 3.1 m3/m/d at the discharge zone and a mean flow to 1.5 m3/m/d in the bay. The nearshore discharge agreed relatively well with Darcy fluxes calculated at the beach face. Fresh groundwater makes up more than 50% of the total discharge during the measuring campaign. These results indicate that beaches in boreal and cold regions could be important sources of freshwater originate and groundwater-borne solutes and contaminants to the marine environment after the snowmelt.

Nearshore morphology, benthic structure, hydrodynamics, and coastal groundwater discharge near Kahekili Beach Park, Maui, Hawaii

USGS Publications Warehouse

Swarzenski, Peter W.; Storlazzi, Curt D.; Presto, M. Katherine; Gibbs, Ann E.; Smith, Christopher G.; Dimova, Natasha T.; Dailer, Meghan L.; Logan, Joshua B.

2012-01-01

This report presents a brief summary of recent fieldwork conducted off Kahekili Beach Park, Maui, Hawaii, the site of the newly established U.S. Coral Reef Task Force priority study area at Kaanapali and the Hawaii Department of Land and Natural Resources, Division of Aquatic Resources, Kahekili Herbivore Fisheries Management Area (HFMA). The goals of this fieldwork are to provide new baseline information to help guide future studies and to provide first insights into rates and drivers of coastal groundwater discharge and associated constituent loadings into the priority study area's coastal waters. This study presents the first swath acoustic mapping information, in situ oceanographic instrument measurements, and coastal groundwater discharge estimates at this site based on the submarine groundwater discharge tracer radon-222 (222Rn). Coastal groundwater discharge rates ranged from about 22 to 50 centimeters per day, depending on proximity of the sampling mooring to the primary discharge vent. The water chemistry of the discharging groundwater was at times dramatically different than ambient seawater. For example, at the primary vent site at Kahekili, the concentrations of total dissolved nitrogen (TDN), dissolved silicate (DSi), and total dissolved phosphorus (TDP) in the discharging groundwater were 43.75 micromolar (μM), 583.49 μM, and 12.04 μM, respectively. These data extend our basic understanding of the morphology, benthic structure, and oceanographic setting of this vent site and provide a first estimate of the magnitude and physical forcings of submarine groundwater discharge and associated trace metals and nutrient loads here.

Characterization of a suspected terrestrial deep groundwater discharge area on the Canadian Precambrian Shield

NASA Astrophysics Data System (ADS)

Sheppard, Marsha I.; Thibault, D. H.; Milton, G. M.; Reid, J. A. K.; Smith, P. A.; Stevens, K.

1995-03-01

Underground storage and disposal of hazardous wastes require an understanding of groundwater flow and the ability to locate recharge and discharge. Usually, recharge and discharge occur at a transition zone where dispersion/advection, molecular diffusion and biogeochemical processes control the fate of a contaminants leaving an underground facility. Appropriate landscape modelling for risk assessment cannot proceed until this interface is well defined and groundwater discharge can be mapped. Although discharge locations have traditionally been thought of as aquatic, the presence of animal licks suggests the possibility of terrestrial discharge. We have characterized a suspected terrestrial discharge, a well-used deer lick, (1) physically, through surficial mapping, and vegetation and soil profile analyses; (2) geophysically, through magnetic and very low-frequency electromagnetic tilt-angle surveys; (3) hydrogeologically, through water-table elevation measurements; (4) geochemically, through overburden analyses for 238U, 226Ra, 210Pb, Na, tritium, Cl and 36{Cl}/{Cl} atom ratios, as well as pore-water and groundwater analyses for pH, electrical conductivity (EC) and major anions and cations; and (5) thermally, through overburden-rock interface temperatures. Halophytic plants and sedges contained more Na, Cl and 238U than averages reported in the literature. Lineament alignment, coincident with elevated groundwater EC, supported the presence and position of a subsurface fracture. Groundwater chemistry suggested that interfering runoff from a nearby ridge masked the chemical signatures expected of deep groundwater but attest to the weak and possibly ephemeral nature of this discharge. Interpretation of the geochemical data was supported by solute transport modelling. Good agreement between the predictions using an unsaturated soil model, a simple wetland compartment model and the observed profile implied that evapotranspiration, seasonal water-table fluctuations and

Modeling Effects of Groundwater Basin Closure, and Reversal of Closure, on Groundwater Quality

NASA Astrophysics Data System (ADS)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2017-12-01

Population growth, the expansion of agriculture, and climate uncertainties have accelerated groundwater pumping and overdraft in aquifers worldwide. In many agricultural basins, a water budget may be stable or not in overdraft, yet disconnected ground and surface water bodies can contribute to the formation of a "closed" basin, where water principally exits the basin as evapotranspiration. Although decreasing water quality associated with increases in Total Dissolved Solids (TDS) have been documented in aquifers across the United States in the past half century, connections between water quality declines and significant changes in hydrologic budgets leading to closed basin formation remain poorly understood. Preliminary results from an analysis with a regional-scale mixing model of the Tulare Lake Basin in California indicate that groundwater salinization resulting from open to closed basin conversion can operate on a decades-to-century long time scale. The only way to reverse groundwater salinization caused by basin closure is to refill the basin and change the hydrologic budget sufficiently for natural groundwater discharge to resume. 3D flow and transport modeling, including the effects of heterogeneity based on a hydrostratigraphic facies model, is used to explore rates and time scales of groundwater salinization and its reversal under different water and land management scenarios. The modeling is also used to ascertain the extent to which local and regional heterogeneity need to be included in order to appropriately upscale the advection-dispersion equation in a basin scale groundwater quality management model. Results imply that persistent managed aquifer recharge may slow groundwater salinization, and complete reversal may be possible at sufficiently high water tables.

Submarine groundwater discharges create unique benthic communities in a coastal sandy marine environment

NASA Astrophysics Data System (ADS)

Leitão, Francisco; Encarnação, João; Range, Pedro; Schmelz, Rüdiger M.; Teodósio, Maria A.; Chícharo, Luís

2015-09-01

In this study we assessed the small-scale effects of submarine groundwater discharges (SGD) on macrofaunal assemblages associated with shallow sandy sediments along the south coast of Portugal. Corer samples were collected in a (1) subtidal seep, (2) at the edge of the seep (periphery) and (3) in the surrounding area. Community structure varied across areas, with diversity, species richness and evenness generally low at seep relatively to the surrounding area. Community composition within the seep was reduced to a small number of taxa, although total abundance was similar between seeps and surrounding areas. The seep was characterized by a distinct hydrological environment, with lower salinity and pH, relative to the surroundings sandy areas. More than 93% of the benthic macrofauna in the seep was dominated by Lumbricillus lineatus (enchytraeid oligochaetes). This study is the first to record the presence of this euryaline species in Portuguese marine waters. In the surrounding area Spionidae Polychaetes and Bathyporeia sp. (Amphipoda) were the most frequent and abundant taxa. These findings provide evidence for a direct association between SGD effect and the composition of benthic marine assemblages. The patchy habitat created by groundwater seep allowed euryhaline species with short and fast recruitment times to occur in a fully marine environment. Whether this pattern is consistent, or only occurs when smooth favorable sea conditions are not superimposed on the groundwater effect remains uncertain.

Hydrogeochemical and isotopic evidences of groundwater salinization in coastal aquifers: A case study in Jeju volcanic island, Korea

NASA Astrophysics Data System (ADS)

Kim, Y.; Lee, D.; Lee, K.; Koh, D.; Lee, S.; Park, W.; Koh, G.; Woo, N.

2001-12-01

In order to clearly identify the origin of saline groundwaters in the eastern part of Jeju volcanic island, Korea the hydrogeochemical and isotopic studies have been carried out for 18 observation wells located in east and southeast coastal regions. The total dissolved solid (TDS) contents of groundwater samples are highly variable (77 to 21,782 mg/L). Most of the groundwaters in the study area are classified into Na-Cl type except a few samples showing Ca-Cl type. Hydrochemical characteristics based on bivariate and triangular diagrams of major ions show that the changes of chemical compositions of groundwaters were mainly controlled by the salinization process linked to cation-exchange reactions. The oxygen, hydrogen, sulfur, and strontium isotopic data explicitly show a simple mixing trend of groundwater and seawater. Using two-components fractional mixing model on the basis of 18O contents as well as Br and Cl contents, the proportion of seawater in fresh groundwater was quantitatively determined as high as 60 %. Sr isotopic compositions and Br/Cl ratios strongly suggest that the source of groundwater salinization is present-day seawater intrusion rather than paleoseawater or formation water, which can also be supported by the I/Cl ratios. The highly permeable aquifers in the east coastal region characterized by low hydraulic gradient and recharge rate and high hydraulic conductivity comparing with other regions are advantageous to the groundwater salinization. Based on the Cl, ¥ä18O, and 87Sr/86Sr it was determined that seawater has intruded into inland 2.5 km from coastline.

Groundwater salinity and hydrochemical processes in the volcano-sedimentary aquifer of La Aldea, Gran Canaria, Canary Islands, Spain.

PubMed

Cruz-Fuentes, Tatiana; Cabrera, María del Carmen; Heredia, Javier; Custodio, Emilio

2014-06-15

The origin of the groundwater salinity and hydrochemical conditions of a 44km(2) volcano-sedimentary aquifer in the semi-arid to arid La Aldea Valley (western Gran Canaria, Spain) has been studied, using major physical and chemical components. Current aquifer recharge is mainly the result of irrigation return flows and secondarily that of rainfall infiltration. Graphical, multivariate statistical and modeling tools have been applied in order to improve the hydrogeological conceptual model and identify the natural and anthropogenic factors controlling groundwater salinity. Groundwater ranges from Na-Cl-HCO3 type for moderate salinity water to Na-Mg-Cl-SO4 type for high salinity water. This is mainly the result of atmospheric airborne salt deposition; silicate weathering, and recharge incorporating irrigation return flows. High evapotranspiration produces significant evapo-concentration leading to relative high groundwater salinity in the area. Under average conditions, about 70% of the water used for intensive agricultural exploitation in the valley comes from three low salinity water runoff storage reservoirs upstream, out of the area, while the remaining 30% derives from groundwater. The main alluvial aquifer behaves as a short turnover time reservoir that adds to the surface waters to complement irrigation water supply in dry periods, when it reaches 70% of irrigation water requirements. The high seasonality and intra-annual variability of water demand for irrigation press on decision making on aquifer use by a large number of aquifer users acting on their own. Copyright © 2014 Elsevier B.V. All rights reserved.

Development, evolution, and destruction of the saline mineral area of Eocene Lake Uinta, Piceance Basin, western Colorado

USGS Publications Warehouse

Johnson, Ronald C.; Brownfield, Michael E.

2015-01-01

Leaching of saline minerals began sometime after the Green River Formation was lithified enough to allow collapse breccias to form. Leaching is ongoing today, indicated by the discharge of highly saline water from a series of springs in the northern part of the basin. Groundwater invasion and saline mineral dissolution is commonly incomplete in areas that lack fractures, leaving behind pockets of unleached saline minerals in otherwise leached intervals. Today, the base of the leached zone slopes toward the north and toward the area where the brines are being discharged.

A Geochemical and Geophysical Assessment of Coastal Groundwater Discharge at Select Sites in Maui and O’ahu, Hawai’i

USGS Publications Warehouse

Swarzenski, Peter W.; Storlazzi, Curt; M.L. Dalier,; C.R. Glenn,; C.G. Smith,

2015-01-01

Based on the submarine groundwater discharge tracer 222Rn, coastal groundwater discharge rates ranged from about 22–50 cm per day at Kahekili, a site in the Ka’anapali region north of Lahaina in west Maui, while at Black Point in Maunalua Bay along southern O’ahu, coastal groundwater discharge rates ranged up to 700 cm per day, although the mean discharge rate at this site was 60 cm per day. The water chemistry of the discharging groundwater can be dramatically different than ambient seawater at both coastal sites. For example, at Kahekili the average concentrations of dissolved inorganic nitrogen (DIN), dissolved silicate (DSi) and total dissolved phosphorus (TDP) were roughly 188-, 36-, and 106-times higher in the discharging groundwater relative to ambient seawater, respectively. Such data extend our basic understanding of the physical controls on coastal groundwater discharge and provide an estimate of the magnitude and physical forcings of submarine groundwater discharge and associated trace metal and nutrient loads conveyed by this submarine route.

Salinization of the soil solution decreases the further accumulation of salt in the root zone of the halophyte Atriplex nummularia Lindl. growing above shallow saline groundwater.

PubMed

Alharby, Hesham F; Colmer, Timothy D; Barrett-Lennard, Edward G

2018-01-01

Water use by plants in landscapes with shallow saline groundwater may lead to the accumulation of salt in the root zone. We examined the accumulation of Na + and Cl - around the roots of the halophyte Atriplex nummularia Lindl. and the impacts of this increasing salinity for stomatal conductance, water use and growth. Plants were grown in columns filled with a sand-clay mixture and connected at the bottom to reservoirs containing 20, 200 or 400 mM NaCl. At 21 d, Na + and Cl - concentrations in the soil solution were affected by the salinity of the groundwater, height above the water table and the root fresh mass density at various soil depths (P < 0.001). However, by day 35, the groundwater salinity and height above the water table remained significant factors, but the root fresh mass density was no longer significant. Regression of data from the 200 and 400 mM NaCl treatments showed that the rate of Na + accumulation in the soil increased until the Na + concentration reached ~250 mM within the root zone; subsequent decreases in accumulation were associated with decreases in stomatal conductance. Salinization of the soil solution therefore had a feedback effect on further salinization within the root zone. © 2017 John Wiley & Sons Ltd.

Applications of radon and radium isotopes to determine submarine groundwater discharge and flushing times in Todos os Santos Bay, Brazil.

PubMed

Hatje, Vanessa; Attisano, Karina Kammer; de Souza, Marcelo Friederichs Landim; Mazzilli, Barbara; de Oliveira, Joselene; de Araújo Mora, Tamires; Burnett, William C

2017-11-01

Todos os Santos Bay (BTS) is the 2nd largest bay in Brazil and an important resource for the people of the State of Bahia. We made measurements of radon and radium in selected areas of the bay to evaluate if these tracers could provide estimates of submarine groundwater discharge (SGD) and flushing times of the Paraguaçu Estuary and BTS. We found that there were a few areas along the eastern and northeastern shorelines that displayed relatively high radon and low salinities, indicating possible sites of enhanced SGD. A time-series mooring over a tidal cycle at Marina do Bonfim showed a systematic enrichment of the short-lived radium isotopes 223 Ra and 224 Ra during the falling tide. Assuming that the elevated radium isotopes were related to SGD and using measured radium activities from a shallow well at the site, we estimated groundwater seepage at about 70 m 3 /day per unit width of shoreline. Extrapolating to an estimated total shoreline length provided a first approximation of total (fresh + saline) SGD into BTS of 300 m 3 /s, about 3 times the average river discharge into the bay. Just applying the shoreline lengths from areas identified with high radon and reduced salinity results in a lower SGD estimate of 20 m 3 /s. Flushing times of the Paraguaçu Estuary were estimated at about 3-4 days based on changing radium isotope ratios from low to high salinities. The flushing time for the entire BTS was also attempted using the same approach and resulted in a surprisingly low value of only 6-8 days. Although physical oceanographic models have proposed flushing times on the order of months, a simple tidal prism calculation provided results in the range of 4-7 days, consistent with the radium approach. Based on these initial results, we recommend a strategy for refining both SGD and flushing time estimates. Copyright © 2017 Elsevier Ltd. All rights reserved.

Empirical quantification of lacustrine groundwater discharge - different methods and their limitations

NASA Astrophysics Data System (ADS)

Meinikmann, K.; Nützmann, G.; Lewandowski, J.

2015-03-01

Groundwater discharge into lakes (lacustrine groundwater discharge, LGD) can be an important driver of lake eutrophication. Its quantification is difficult for several reasons, and thus often neglected in water and nutrient budgets of lakes. In the present case several methods were applied to determine the expansion of the subsurface catchment, to reveal areas of main LGD and to identify the variability of LGD intensity. Size and shape of the subsurface catchment served as a prerequisite in order to calculate long-term groundwater recharge and thus the overall amount of LGD. Isotopic composition of near-shore groundwater was investigated to validate the quality of catchment delineation in near-shore areas. Heat as a natural tracer for groundwater-surface water interactions was used to find spatial variations of LGD intensity. Via an analytical solution of the heat transport equation, LGD rates were calculated from temperature profiles of the lake bed. The method has some uncertainties, as can be found from the results of two measurement campaigns in different years. The present study reveals that a combination of several different methods is required for a reliable identification and quantification of LGD and groundwater-borne nutrient loads.

Evaluation of effects of changes in canal management and precipitation patterns on salinity in Biscayne Bay, Florida, using an integrated surface-water/groundwater model

USGS Publications Warehouse

Lohmann, Melinda A.; Swain, Eric D.; Wang, John D.; Dixon, Joann

2012-01-01

Biscayne National Park, located in Biscayne Bay in southeast Florida, is one of the largest marine parks in the country and sustains a large natural marine fishery where numerous threatened and endangered species reproduce. In recent years, the bay has experienced hypersaline conditions (salinity greater than 35 practical salinity units) of increasing magnitude and duration. Hypersalinity events were particularly pronounced during April to August 2004 in nearshore areas along the southern and middle parts of the bay. Prolonged hypersaline conditions can cause degradation of water quality and permanent damage to, or loss of, brackish nursery habitats for multiple species of fish and crustaceans as well as damage to certain types of seagrasses that are not tolerant of extreme changes in salinity. To evaluate the factors that contribute to hypersalinity events and to test the effects of possible changes in precipitation patterns and canal flows into Biscayne Bay on salinity in the bay, the U.S. Geological Survey constructed a coupled surface-water/groundwater numerical flow model. The model is designed to account for freshwater flows into Biscayne Bay through the canal system, leakage of salty bay water into the underlying Biscayne aquifer, discharge of fresh and salty groundwater from the Biscayne aquifer into the bay, direct effects of precipitation on bay salinity, indirect effects of precipitation on recharge to the Biscayne aquifer, direct effects of evapotranspiration (ET) on bay salinity, indirect effects of ET on recharge to the Biscayne aquifer, and maintenance of mass balance of both water and solute. The model was constructed using the Flow and Transport in a Linked Overland/Aquifer Density Dependent System (FTLOADDS) simulator, version 3.3, which couples the two-dimensional, surface-water flow and solute-transport simulator SWIFT2D with the density-dependent, groundwater flow an solute-transport simulator SEAWAT. The model was calibrated by a trial

Characterizing hydrology and the importance of ground-water discharge in natural and constructed wetlands

USGS Publications Warehouse

Hunt, Randall J.; Walker, John F.; Krabbenhoft, David P.

1999-01-01

Although considered the most important component for the establishment and persistence of wetlands, hydrology has been hard to characterize and linkages between hydrology and other environmental conditions are often poorly understood. In this work, methods for characterizing a wetland’s hydrology from hydrographs were developed, and the importance of ground water to the physical and geochemical conditions in the root zone was investigated. Detailed sampling of nearly continuous hydrographs showed that sites with greater ground-water discharge had higher water tables and more stable hydrographs. Subsampling of the continuous hydrograph failed to characterize the sites correctly, even though the wetland complex is located in a strong regional ground-water-discharge area. By comparing soil-moisture-potential measurements to the water-table hydrograph at one site, we noted that the amount of root-zone saturation was not necessarily driven by the water-table hydrograph but can be a result of other soil parameters (i.e., soil texture and associated capillary fringe). Ground-water discharge was not a significant determinant of maximum or average temperatures in the root zone. High ground-water discharge was associated with earliest date of thaw and shortest period of time that the root zone was frozen, however. Finally, the direction and magnitude of shallow ground-water flow was found to affect the migration and importance of a geochemical species. Areas of higher ground-water discharge had less downward penetration of CO2 generated in the root zone. In contrast, biotically derived CO2 was able to penetrate the deeper ground-water system in areas of ground-water recharge. Although ground-water flows are difficult to characterize, understanding these components is critical to the success of wetland restoration and creation efforts.

234U— 238U— 230Th— 232Th systematics in saline groundwaters from central Missouri

NASA Astrophysics Data System (ADS)

Banner, Jay L.; Wasserburg, G. J.; Chen, James H.; Moore, Clyde H.

1990-12-01

Saline groundwaters with 4.7 to 26‰ total dissolved solids were sampled from springs and artesian wells in Mississippian and Ordovician carbonates and sandstones in central Missouri. U—Th isotopic variations provide a means of evaluating processes of water-rock interaction and fluid mixing and estimating the time scales of element transport. Recently developed mass spectrometric techniques are used to make isotopic measurements on small-volume groundwater samples (0.1-4 l) with high precision (e.g., < ±5% for 234U/ 238U activity ratios). The groundwaters have a wide range of 238U concentrations, 50 × 10 -12 to 200 × 10 -12 g/g; 234U/ 234U activity ratios, 2.15-16.0; 232Th concentrations, 0.10 × 10 -12 to 33 × 10 -12 g/g; and 230Th concentrations, 0.91 × 10 -17 to 26 × 10 -17 g/g. Unfiltered and filtered (0.4 μm, 0.1 μm) aliquots of a saline sample have the same isotopic composition and concentration of U, indicating that 234U and 238U occur almost entirely as dissolved species. The concentration of 232Th is up to seven times lower in filtered vs. unfiltered aliquots, indicating that 232Th is predominantly associated with particulates in the groundwaters. In contrast, most of the 230Th is in solution. Previous geochemical studies indicate that: (1) the saline waters originated as meteoric recharge and evolved through halite dissolution, reactions with silicates and saline-dilute mixing processes during a long-distance flow history; and (2) interaction with limestone and dolomite aquifer rocks in central Missouri has been limited. A consistent relationship between U/Ca and 234U/ 238U activity ratio is observed in the groundwaters and provides constraints on the U/Ca ratios and 234U/ 238U activity ratios of end-member reservoirs and on the processes of isotopic exchange in this water-rock system. Model calculations that simulate (1) saline-dilute groundwater mixing and (2) limited extents of dissolution of carbonate aquifer minerals by the groundwaters

A geochemical approach to determine sources and movement of saline groundwater in a coastal aquifer

USGS Publications Warehouse

Anders, Robert; Mendez, Gregory O.; Futa, Kiyoto; Danskin, Wesley R.

2014-01-01

Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major-ions, the chemical composition is classified as Na-Ca-Cl-SO4, Na-Cl, or Na-Ca-Cl type water. δ2H and δ18O values range from −47.7‰ to −12.8‰ and from −7.0‰ to −1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. 87Sr/86Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. 3H and 14C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher-elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest-to-southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers.

Development and application of a conceptual hydrologic model to predict soil salinity within modern Tunisian oases

NASA Astrophysics Data System (ADS)

Askri, Brahim; Bouhlila, Rachida; Job, Jean Olivier

2010-01-01

SummaryIn modern oases situated in the south of Tunisia, secondary salination of irrigated lands is a crucial problem. The visible salt deposits and soil salination processes are the consequence of several factors including the excessive use of saline irrigation water, seepage from earthen canal systems, inefficient irrigation practices and inadequate drainage. Understanding the mechanism of the secondary salination is of interest in order to maintain existing oases, and thus ensure the sustainability of date production in this part of the country. Therefore, a conceptual, daily, semi-distributed hydrologic model (OASIS_MOD) was developed to analyse the impact of irrigation management on the water table fluctuation, soil salinity and drain discharge, and to evaluate measures to control salinity within an oasis ecosystem. The basic processes incorporated in the model are irrigation, infiltration, percolation to the shallow groundwater, soil evaporation, crop transpiration, groundwater flow, capillary rise flux, and drain discharge. OASIS_MOD was tested with data collected in a parcel of farmland situated in the Segdoud oasis, in the south-west of Tunisia. The calibration results showed that groundwater levels were simulated with acceptable accuracy, since the differences between the simulated and measured values are less than 0.22 m. However, the model under-predicted some water table peaks when irrigation occurs due to inconsistencies in the irrigation water data. The validation results showed that deviations between observed and simulated groundwater levels have increased to about 0.5 m due to under-estimation of groundwater inflow from an upstream palm plantation. A long-term simulation scenario revealed that the soil salinity and groundwater level have three types of variability in time: a daily variability due to irrigation practices, seasonal fluctuation due to climatic conditions and annual variability explained by the increase in cultivated areas. The

Origin and distribution of saline groundwaters in the upper Miocene aquifer system, coastal Rhodope area, northeastern Greece

NASA Astrophysics Data System (ADS)

Petalas, C. P.; Diamantis, I. B.

1999-06-01

This paper describes the origins and distribution of saline groundwaters in the coastal area of Rhodope, Greece. The aquifer system includes two aquifers within coarse-grained alluvial sediments in the coastal part of the study area. Two major water-quality groups occur in the study area, namely Ca2+-rich saline groundwater and Ca2+-poor, almost fresh groundwater. The main process controlling the groundwater chemistry is the exchange of calcium and sodium between the aquifer matrix and intruding seawater. The natural salt water in the study area is probably residual water that infiltrated the aquifer system during repeated marine transgressions in late Pleistocene time. Seawater intrusion into the coastal aquifer system occurs as a result of overpumping in two seawater wedges separated vertically by a low-permeability layer. The rate of intrusion averages 0.8 m/d and is less than expected due to a decline of the aquifer's permeability at the interface with the seawater. The application of several hydrochemical techniques (Piper and Durov diagrams; Na+/Cl-, Ca2+/Cl-, Mg2+/Cl-, and Br-/Cl- molar ratios; Ca2+/Mg2+ weight ratio; and chloride concentrations), combined with field observations, may lead to a better explanation of the origin of the saline groundwater.

Intertidal and submarine groundwater discharge on the west coast of Ireland

NASA Astrophysics Data System (ADS)

R., R.; | T., Cave; Henry

2011-05-01

Submarine Groundwater Discharge is now a phenomenon of global interest, as studies show that it represents both a significant proportion of the fresh water input to the ocean, and a significant contribution to the loads of many substances. At present, little monitoring of groundwater in Ireland is carried out at its point of entry to seawater, and consequently the volumes of fresh water, and the loads of nutrients and contaminants being carried into Irish coastal waters by submarine and intertidal groundwater discharge (SiGD), are unknown. SiGD is the principal source of fresh water entering Irish coastal waters between the major west coast estuaries of the Corrib and the Shannon. Calculations of the volume of submarine SiGD delivered to southern Galway bay in winter indicate it equals 10-25% of the discharge of the R. Corrib, and that its nutrient load may be of the same order of magnitude as that from the R. Corrib. This coastal karst area includes important commercial shellfish waters, which may be strongly impacted by SiGD.

Drought-induced recharge promotes long-term storage of porewater salinity beneath a prairie wetland

NASA Astrophysics Data System (ADS)

Levy, Zeno F.; Rosenberry, Donald O.; Moucha, Robert; Mushet, David M.; Goldhaber, Martin B.; LaBaugh, James W.; Fiorentino, Anthony J.; Siegel, Donald I.

2018-02-01

Subsurface storage of sulfate salts allows closed-basin wetlands in the semiarid Prairie Pothole Region (PPR) of North America to maintain moderate surface water salinity (total dissolved solids [TDS] from 1 to 10 g L-1), which provides critical habitat for communities of aquatic biota. However, it is unclear how the salinity of wetland ponds will respond to a recent shift in mid-continental climate to wetter conditions. To understand better the mechanisms that control surface-subsurface salinity exchanges during regional dry-wet climate cycles, we made a detailed geoelectrical study of a closed-basin prairie wetland (P1 in the Cottonwood Lake Study Area, North Dakota) that is currently experiencing record wet conditions. We found saline lenses of sulfate-rich porewater (TDS > 10 g L-1) contained in fine-grained wetland sediments 2-4 m beneath the bathymetric low of the wetland and within the currently ponded area along the shoreline of a prior pond stand (c. 1983). During the most recent drought (1988-1993), the wetland switched from a groundwater discharge to recharge function, allowing salts dissolved in surface runoff to move into wetland sediments beneath the bathymetric low of the basin. However, groundwater levels during this time did not decline to the elevation of the saline lenses, suggesting these features formed during more extended paleo-droughts and are stable in the subsurface on at least centennial timescales. We hypothesize a "drought-induced recharge" mechanism that allows wetland ponds to maintain moderate salinity under semiarid climate. Discharge of drought-derived saline groundwater has the potential to increase the salinity of wetland ponds during wet climate.

Quantifying groundwater discharge through fringing wetlands to estuaries: Seasonal variability, methods comparison, and implications for wetland-estuary exchange

USGS Publications Warehouse

Tobias, C.R.; Harvey, J.W.; Anderson, I.C.

2001-01-01

Because groundwater discharge along coastal shorelines is often concentrated in zones inhabited by fringing wetlands, accurately estimating discharge is essential for understanding its effect on the function and maintenance of these ecosystems. Most previous estimates of groundwater discharge to coastal wetlands have been temporally limited and have used only a single approach to estimate discharge. Furthermore, groundwater input has not been considered as a major mechanism controlling pore-water flushing. We estimated seasonally varying groundwater discharge into a fringing estuarine wetland using three independent methods (Darcy's Law, salt balance, and Br- tracer). Seasonal patterns of discharge predicted by both Darcy's Law and the salt balance yielded similar seasonal patterns with discharge maxima and minima in spring and early fall, respectively. They differed, however, in the estimated magnitude of discharge by two- to fourfold in spring and by 10-fold in fall. Darcy estimates of mean discharge ranged between -8.0 and 80 L m-2 d-1, whereas the salt balance predicted groundwater discharge of 0.6 to 22 L m-2 d-1. Results from the Br- tracer experiment estimated discharge at 16 L m-2 d-t, or nearly equal to the salt balance estimate at that time. Based upon the tracer test, pore-water conductivity profiles, and error estimates for the Darcy and salt balance approaches, we concluded that the salt balance provided a more certain estimate of groundwater discharge at high flow (spring). In contrast, the Darcy method provided a more reliable estimate during low flow (fall). Groundwater flushing of pore water in the spring exported solutes to the estuary at rates similar to tidally driven surface exchange seen in previous studies. Based on pore-water turnover times, the groundwater-driven flux of dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NH4+ to the estuary was 11.9, 1.6, and 1.3 g C or g N m-2 wetland for the 90 d encompassing peak

The integrated impacts of natural processes and human activities on groundwater salinization in the coastal aquifers of Beihai, southern China

NASA Astrophysics Data System (ADS)

Li, Qinghua; Zhang, Yanpeng; Chen, Wen; Yu, Shaowen

2018-03-01

Salinization in coastal aquifers is usually related to both seawater intrusion and water-rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl-, Na+, Ca2+, Mg2+ and SO4 2- ), as well as the isotopic content and ratios (2H, 18O, 87Sr/86Sr and 13C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.

Tidal pumping as a driver of groundwater discharge to a back barrier salt marsh ecosystem

NASA Astrophysics Data System (ADS)

Carter, M. L.; Viso, R. F.; Peterson, R. N.; Hill, J. C.

2013-12-01

Submarine groundwater discharge (SGD) typically consists of both terrestrial groundwater and recirculated seawater and has been shown to be a significant pathway of dissolved substances to the coastal zone. The fresh and saline water mixture in the subsurface creates a salinity gradient that can impact biogeochemical processes. Located along the South Atlantic Bight, Georgia's coastline is an approximately 100-mile stretch of complex primary and secondary barrier islands resulting from geologic interactions driven by long-term sea level rise and retreat, accretion, seasonal tidal events, storm overwash, and wave driven erosion. Our study site is located in the Duplin River near Sapelo Island, GA and is part of the Georgia Coastal Ecosystems Long Term Ecosystem Research (GCE-LTER) program. This area is considered mesotidal (2-4m) and tidal pumping may be a dominating process in controlling SGD rates. The Duplin River is connected to the Atlantic Ocean through Doboy Sound to the south. To the north, the river terminates in extensive salt marsh and therefore has no overland freshwater input. Previous studies show a salinity gradient within the Duplin River indicating that SGD must be present as a source of brackish water. To place constraints on SGD processes, we employ a combination of geochemical and geophysical techniques to determine the magnitude of SGD in the Duplin River. Together these techniques permit a more complete understanding of the groundwater system. Three time series stations at the upper, mid and lower reaches of the Duplin River were deployed in June of 2013 to measure groundwater influences during daily and fortnightly tidal cycles. At each station, continuous radon-222 measurements were conducted at 30 minute intervals along with measurements of water level, temperature and conductivity using standard hydrological data loggers. During this period, eight time series resistivity profiles using a 56 electrode (110m long) cable were recorded to

A geochemical approach to determine sources and movement of saline groundwater in a coastal aquifer.

PubMed

Anders, Robert; Mendez, Gregory O; Futa, Kiyoto; Danskin, Wesley R

2014-01-01

Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major-ions, the chemical composition is classified as Na-Ca-Cl-SO4, Na-Cl, or Na-Ca-Cl type water. δ(2)H and δ(18)O values range from -47.7‰ to -12.8‰ and from -7.0‰ to -1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. (87)Sr/(86)Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. (3)H and (14)C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher-elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest-to-southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers. © 2013, National Ground Water Association.

Hydrogeochemical features of groundwater of semi-confined coastal aquifer in Amol-Ghaemshahr plain, Mazandaran Province, Northern Iran.

PubMed

Khairy, Houshang; Janardhana, M R

2013-11-01

Hydrogeochemical data of groundwater from the semi-confined aquifer of a coastal two-tier aquifer in Amol-Ghaemshahr plain, Mazandaran Province, Northern Iran reveal salinization of the fresh groundwater (FGW). The saline groundwater zone is oriented at an angle to both Caspian Sea coastline and groundwater flow direction and extends inland from the coastline for more than 40 km. Spearman's rank correlation coefficient matrices, factor analysis data, and values of C ratio, chloro-alkaline indices, and Na(+)/Cl(-) molar ratio indicate that the ionic load in the FGW is derived essentially from carbonic acid-aided weathering of carbonates and aluminosilicate minerals, relict connate saline water, and ion exchange reactions. Saline groundwater samples (SGWS) (n = 20) can be classified into two groups. SGWS of group 1 (n = 17) represent the saline groundwater zone below the Caspian Sea level, and salinization is attributed essentially to (1) lateral intrusion of Caspian seawater as a consequence of (a) excessive withdrawal of groundwater from closely spaced bore wells located in the eastern part of the coastal zone and (b) imbalance between recharge and discharge of the two-tier aquifer and (2) upconing of paleobrine (interfaced with FGW) along deep wells. SGWS of this group contain, on average, 7.9% of saltwater, the composition of which is similar to that of Caspian seawater. SGWS of group 2 (n = 3) belong to the saline groundwater zone encountered above the Caspian Sea level, and salinization of the groundwater representing these samples is attributed to irrigation return flow (n = 2) and inflow of saline river water (n = 1).

The role of uplift and erosion in the persistence of saline groundwater in the shallow subsurface

NASA Astrophysics Data System (ADS)

Yager, R. M.; McCoy, K. J.; Voss, C. I.; Sanford, W. E.; Winston, R. B.

2017-04-01

In many regions of the world, the shallow (<300 m) subsurface is replenished with meteoric recharge within a few centuries or millennia, but in some regions saline groundwater persists despite abundant rainfall. Analyses of the flushing rate of shallow groundwater usually consider the permeability and recharge rate and a static landscape. The influence of landscape evolution can become important over millions of years, however. Here we present numerical simulations of fluid flow and transport in the top 1 km of a sedimentary foreland basin dominated by aquitards, where the rate of uplift and erosion (20 m Ma-1) balances that of meteoric flushing. Paleozoic age saline groundwater and brine persist at shallow depths that might otherwise have contained potable water. Similar hydrogeologic conditions, and uplift and erosion rates, likely exist in many other regions of the world, where a moving landscape has probably never been considered as an important contributor to groundwater quality.

The role of uplift and erosion in the persistence of saline groundwater in the shallow subsurface

USGS Publications Warehouse

Yager, Richard M.; McCoy, Kurt J.; Voss, Clifford I.; Sanford, Ward E.; Winston, Richard B.

2017-01-01

In many regions of the world, the shallow (<300 m) subsurface is replenished with meteoric recharge within a few centuries or millennia, but in some regions saline groundwater persists despite abundant rainfall. Analyses of the flushing rate of shallow groundwater usually consider the permeability and recharge rate and a static landscape. The influence of landscape evolution can become important over millions of years, however. Here we present numerical simulations of fluid flow and transport in the top 1 km of a sedimentary foreland basin dominated by aquitards, where the rate of uplift and erosion (20 m Ma−1) balances that of meteoric flushing. Paleozoic age saline groundwater and brine persist at shallow depths that might otherwise have contained potable water. Similar hydrogeologic conditions, and uplift and erosion rates, likely exist in many other regions of the world, where a moving landscape has probably never been considered as an important contributor to groundwater quality.

The distribution and origins of extremely acidic saline groundwaters in the south of Western Australia - Groundwater and digital mapping datasets provide new insights

NASA Astrophysics Data System (ADS)

Lillicrap, Adam M.; Biermann, Vera; George, Richard J.; Gray, David J.; Oldham, Carolyn E.

2018-01-01

Some of the largest extents of naturally occurring acidic waters are found across southern Australia. The origins of these systems remain poorly understood with many hypotheses for their genesis. Australian government agency groundwater datasets and mapping data (vegetation, geology, regolith and soils) for south-western Australia, unavailable to previous researchers, were statistically analysed to better understand the origins of acidic groundwater and guide additional fieldwork to study the origins of acidic saline groundwater. The groundwater data showed a distinct bimodal distribution in pH; the 'acid' population had a median pH of 3.5 and the larger 'non-acid' population had a median pH of 6.6. Acidic groundwater became progressively more common further from the coast towards the drier internally drained regions. Acidic groundwater was mostly confined to the lower slopes and valley floors with localised controls on distribution. Paradoxically, subsoil alkalinity within the internally drained inland regions had the strongest correlation with acidic groundwater (r2 = 0.85). Vegetation was also a strong predictor of acidic groundwater. Acidic groundwater had the highest occurrence under Eucalyptus woodlands and shrublands that grew on alkaline calcareous soils. Pre-clearing soil data in areas with acidic saline groundwater showed that the upper 1 m of the unsaturated zone had a pH around 8 while the pH at depths greater than 5 m decreased to <4. Based on the observations it is proposed that biogenic formation of calcareous soils occurs in the upper 1 m of the profile, calcium is sourced from the deeper profile where the root biota exchanges calcium for hydrogen ions to maintain charge balance. Iron is mobilised from the upper soil profile and concentrates lower in the profile at depths >1.5 m. There, the iron is reduced around roots and the alkalinity generated by microbial iron reduction is removed by biogenic calcification processes. The iron moves in solution

Semi-Permeable Paleochannels as Conduits for Submarine Groundwater Discharge to the Coast in Barataria Bay, Louisiana

NASA Astrophysics Data System (ADS)

Breaux, A.; Kolker, A.; Telfeyan, K.; Kim, J.; Johannesson, K. H.; Cable, J. E.

2014-12-01

Many studies have focused on hydrological and geochemical fluxes to the ocean from land to the ocean via submarine groundwater discharge (SGD), however few have assessed these contributions of SGD in deltaic settings. The Mississippi River delta is the largest delta in North America, and the magnitude of groundwater that discharges from the river into its delta is relatively unknown. Hydrological budgets indicate that there is a large magnitude of surface water lost in the Mississippi's delta as the river flows into the Gulf of Mexico. Recent evidence in our study indicates that paleochannels, or semi-permeable buried sandy bodies that were former distributaries of the river, allow for water to discharge out of the Mississippi's main channel and into its delta driven by a difference in hydraulic head between the river and the lower lying coastal embayments. Our study uses geophysical data, including sonar and resistivity methods, to detect the location of these paleochannels in Barataria Bay, a coastal bay located in the Mississippi Delta. High resolution CHIRP sonar data shows that these paleochannel features are ubiquitous in the Mississippi Delta, whereas resistivity data indicates that lower salinity water is found during high river flow in bays proximate to the river. Sediment core analysis is also used to characterize the area of study, as well as further understand the regional geology of the Mississippi Delta and estimate values of permeability and hydraulic conductivity of sediments taken from two locations in Barataria Bay. The geophysical and sediment core data will likewise be used to contextualize geochemical data collected in the field, which includes an assessment of major cations and anions, as well as in situ Rn-222 activities, a method that has been proven to be useful as a tracer of groundwater movement. The results may be useful in understanding the potential global magnitude of hydrological and geochemical fluxes of other large rivers with

Is the Taklimakan Desert Highway Shelterbelt Sustainable to Long-Term Drip Irrigation with High Saline Groundwater?

PubMed Central

Zhang, Jianguo; Xu, Xinwen; Li, Shengyu; Zhao, Ying; Zhang, Afeng; Zhang, Tibin; Jiang, Rui

2016-01-01

Freshwater resources are scarce in desert regions. Highly saline groundwater of different salinity is being used to drip irrigate the Taklimakan Desert Highway Shelterbelt with a double-branch-pipe system controlling the irrigation cycles. In this study, to evaluate the dynamics of soil moisture and salinity under the current irrigation system, soil samples were collected to a 2-m depth in the shelterbelt planted for different years and irrigated with different groundwater salinities, and soil moisture and salinity were analyzed. The results showed that both depletion of soil moisture and increase of topsoil salinity occurred simultaneously during one irrigation cycle. Soil moisture decreased from 27.4% to 2.4% for a 15-day irrigation cycle and from 26.4% to 2.7% for a 10-day-cycle, respectively. Topsoil electrical conductivity (EC) increased from 0.64 to 3.32 dS/m and 0.70 to 3.99 dS/m for these two irrigation cycles. With increased shelterbelt age, profiled average soil moisture (0–200 cm) reduced from 12.8% (1-year) to 7.1% (10-year); however, soil moisture in 0–20-cm increased, while topsoil salinity decreased. In addition, irrigation salinity mainly affected soil salinity in the 0–20-cm range. We conclude that water supply with the double-branch-pipe is a feasible irrigation method for the Taklimakan Desert Highway Shelterbelt, and our findings provide a model for shelterbelt construction and sustainable management when using highly saline water for irrigation in analogous habitats. PMID:27711244

Coupling End-Member Mixing Analysis and Isotope Mass Balancing (222-Rn) for Differentiation of Fresh and Recirculated Submarine Groundwater Discharge Into Knysna Estuary, South Africa

NASA Astrophysics Data System (ADS)

Petermann, E.; Knöller, K.; Rocha, C.; Scholten, J.; Stollberg, R.; Weiß, H.; Schubert, M.

2018-02-01

Quantification of submarine groundwater discharge (SGD) is essential for evaluating the vulnerability of coastal water bodies to groundwater pollution and for understanding water body material cycles response due to potential discharge of nutrients, organic compounds, or heavy metals. Here we present an environmental tracer-based methodology for quantifying SGD into Knysna Estuary, South Africa. Both components of SGD, (1) fresh, terrestrial (FSGD) and (2) saline, recirculated (RSGD), were differentiated. We conducted an end-member mixing analysis for radon (222Rn) and salinity time series of estuary water over two tidal cycles to determine fractions of seawater, riverwater, FSGD, and RSGD. The mixing analysis was treated as a constrained optimization problem for finding the end-member mixing ratio that is producing the best fit to observations at every time step. Results revealed highest FSGD and RSGD fractions in the estuary during peak low tide. Over a 24 h time series, the portions of FSGD and RSGD in the estuary water were 0.2% and 0.8% near the estuary mouth and the FSGD/RSGD ratio was 1:3.3. We determined a median FSGD of 41,000 m³ d-1 (1.4 m³ d-1 per m shoreline) and a median RSGD of 135,000 m³ d-1 (4.5 m³ d-1 per m shoreline) which suggests that SGD exceeds river discharge by a factor of 1.0-2.1. By comparison to other sources, this implies that SGD is responsible for 28-73% of total DIN fluxes into Knysna Estuary.

Continental degassing of 4He by surficial discharge of deep groundwater

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aggarwal, Pradeep K.; Matsumoto, Takuya; Sturchio, Neil C.

2014-12-01

Radiogenic He-4 is produced by the decay of uranium and thorium in the Earths mantle and crust. From here, it is degassed to the atmosphere(1-5) and eventually escapes to space(1,5,6). Assuming that all of the He-4 produced is degassed, about 70% of the total He-4 degassed from Earth comes from the continental crust(2,-5,7). However, the outgoing flux of crustal He-4 has not been directly measured at the Earths surface(2) and the migration pathways are poorly understood(2-4,7,8). Here we present measurements of helium isotopes and the long-lived cosmogenic radio-isotope Kr-81 in the deep, continental-scale Guarani aquifer in Brazil and show thatmore » crustal He-4 reaches the atmosphere primarily by the surficial discharge of deep groundwater. We estimate that He-4 in Guarani groundwater discharge accounts for about 20% of the assumed global flux from continental crust, and that other large aquifers may account for about 33%. Old groundwater ages suggest that He-4 in the Guarani aquifer accumulates over half- to one-million-year timescales. We conclude that He-4 degassing from the continents is regulated by groundwater discharge, rather than episodic tectonic events, and suggest that the assumed steady state between crustal production and degassing of He-4, and its resulting atmospheric residence time, should be re-examined« less

Using radon-222 to study coastal groundwater/surface-water interaction in the Crau coastal aquifer (southeastern France)

NASA Astrophysics Data System (ADS)

Mayer, Adriano; Nguyen, Bach Thao; Banton, Olivier

2016-11-01

Radon has been used to determine groundwater velocity and groundwater discharge into wetlands at the southern downstream boundary of the Crau aquifer, southeastern France. This aquifer constitutes an important high-quality freshwater resource exploited for agriculture, industry and human consumption. An increase in salinity occurs close to the sea, highlighting the need to investigate the water balance and groundwater behavior. Darcy velocity was estimated using radon activities in well waters according to the Hamada "single-well method" (involving comparison with radon in groundwater in the aquifer itself). Measurements done at three depths (7, 15 and 21 m) provided velocity ranging from a few mm/day to more than 20 cm/day, with highest velocities observed at the 15-m depth. Resulting hydraulic conductivities agree with the known geology. Waters showing high radon activity and high salinity were found near the presumed shoreline at 3,000 years BP, highlighting the presence of ancient saltwater. Radon activity has also been measured in canals, rivers and ponds, to trace groundwater discharges and evaluate water balance. A model of the radon spatial evolution explains the observed radon activities. Groundwater discharge to surface water is low in pond waters (4 % of total inputs) but significant in canals (55 l/m2/day).

The magnitude and origin of groundwater discharge to eastern U.S. and Gulf of Mexico coastal waters

USGS Publications Warehouse

Befus, Kevin; Kroeger, Kevin D.; Smith, Christopher G.; Swarzenski, Peter W.

2017-01-01

Fresh groundwater discharge to coastal environments contributes to the physical and chemical conditions of coastal waters, but the role of coastal groundwater at regional to continental scales remains poorly defined due to diverse hydrologic conditions and the difficulty of tracking coastal groundwater flow paths through heterogeneous subsurface materials. We use three-dimensional groundwater flow models for the first time to calculate the magnitude and source areas of groundwater discharge from unconfined aquifers to coastal waterbodies along the entire eastern U.S. We find that 27.1 km3/yr (22.8–30.5 km3/yr) of groundwater directly enters eastern U.S. and Gulf of Mexico coastal waters. The contributing recharge areas comprised ~175,000 km2 of U.S. land area, extending several kilometers inland. This result provides new information on the land area that can supply natural and anthropogenic constituents to coastal waters via groundwater discharge, thereby defining the subterranean domain potentially affecting coastal chemical budgets and ecosystem processes.

Ground-water discharge determined from estimates of evapotranspiration, Death Valley regional flow system, Nevada and California

USGS Publications Warehouse

Laczniak, Randell J.; Smith, J. LaRue; Elliott, Peggy E.; DeMeo, Guy A.; Chatigny, Melissa A.; Roemer, Gaius J.

2001-01-01

The Death Valley regional flow system (DVRFS) is one of the larger ground-water flow systems in the southwestern United States and includes much of southern Nevada and the Death Valley region of eastern California. Centrally located within the ground-water flow system is the Nevada Test Site (NTS). The NTS, a large tract covering about 1,375 square miles, historically has been used for testing nuclear devices and currently is being studied as a potential repository for the long-term storage of high-level nuclear waste generated in the United States. The U.S. Department of Energy, as mandated by Federal and State regulators, is evaluating the risk associated with contaminants that have been or may be introduced into the subsurface as a consequence of any past or future activities at the NTS. Because subsurface contaminants can be transported away from the NTS by ground water, components of the ground-water budget are of great interest. One such component is regional ground-water discharge. Most of the ground water leaving the DVRFS is limited to local areas where geologic and hydrologic conditions force ground water upward toward the surface to discharge at springs and seeps. Available estimates of ground-water discharge are based primarily on early work done as part of regional reconnaissance studies. These early efforts covered large, geologically complex areas and often applied substantially different techniques to estimate ground-water discharge. This report describes the results of a study that provides more consistent, accurate, and scientifically defensible measures of regional ground-water losses from each of the major discharge areas of the DVRFS. Estimates of ground-water discharge presented in this report are based on a rigorous quantification of local evapotranspiration (ET). The study identifies areas of ongoing ground-water ET, delineates different ET areas based on similarities in vegetation and soil-moisture conditions, and determines an ET rate for

Influence of Coastal Submarine Groundwater Discharges on Seagrass Communities in a Subtropical Karstic Environment.

PubMed

Kantún-Manzano, C A; Herrera-Silveira, J A; Arcega-Cabrera, F

2018-01-01

The influence of coastal submarine groundwater discharges (SGD) on the distribution and abundance of seagrass meadows was investigated. In 2012, hydrological variability, nutrient variability in sediments and the biotic characteristics of two seagrass beds, one with SGD present and one without, were studied. Findings showed that SGD inputs were related with one dominant seagrass species. To further understand this, a generalized additive model (GAM) was used to explore the relationship between seagrass biomass and environment conditions (water and sediment variables). Salinity range (21-35.5 PSU) was the most influential variable (85%), explaining why H. wrightii was the sole plant species present at the SGD site. At the site without SGD, GAM could not be performed since environmental variables could not explain a total variance of > 60%. This research shows the relevance of monitoring SGD inputs in coastal karstic areas since they significantly affect biotic characteristics of seagrass beds.

Groundwater discharge to the Mississippi River and groundwater balances for the Interstate 94 Corridor surficial aquifer, Clearwater to Elk River, Minnesota, 2012–14

USGS Publications Warehouse

Smith, Erik A.; Lorenz, David L.; Kessler, Erich W.; Berg, Andrew M.; Sanocki, Chris A.

2017-12-13

The Interstate 94 Corridor has been identified as 1 of 16 Minnesota groundwater areas of concern because of its limited available groundwater resources. The U.S. Geological Survey, in cooperation with the Minnesota Department of Natural Resources, completed six seasonal and annual groundwater balances for parts of the Interstate 94 Corridor surficial aquifer to better understand its long-term (next several decades) sustainability. A high-precision Mississippi River groundwater discharge measurement of 5.23 cubic feet per second per mile was completed at low-flow conditions to better inform these groundwater balances. The recharge calculation methods RISE program and Soil-Water-Balance model were used to inform the groundwater balances. For the RISE-derived recharge estimates, the range was from 3.30 to 11.91 inches per year; for the SWB-derived recharge estimates, the range was from 5.23 to 17.06 inches per year.Calculated groundwater discharges ranged from 1.45 to 5.06 cubic feet per second per mile, a ratio of 27.7 to 96.4 percent of the measured groundwater discharge. Ratios of groundwater pumping to total recharge ranged from 8.6 to 97.2 percent, with the longer-term groundwater balances ranging from 12.9 to 19 percent. Overall, this study focused on the surficial aquifer system and its interactions with the Mississippi River. During the study period (October 1, 2012, through November 30, 2014), six synoptic measurements, along with continuous groundwater hydrographs, rainfall records, and a compilation of the pertinent irrigation data, establishes the framework for future groundwater modeling efforts.

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

USGS Publications Warehouse

Banoeng-Yakubo, B.; Yidana, S.M.; Nti, E.

2009-01-01

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ??18O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ??18O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low

Using radon-222 for tracing groundwater discharge into an open-pit lignite mining lake--a case study.

PubMed

Schmidt, Axel; Schubert, Michael

2007-12-01

Groundwater discharge into an open pit lignite mining lake was investigated using radon-222 as a naturally occurring environmental tracer. The chosen study site was a meromictic lake, i.e., a water body that is divided horizontally into two separate layers--the upper mixolimnion (with seasonal mixing) and the lower monimolimnion (without seasonal mixing). For the estimation of groundwater discharge rates into the lake, a simple box model including all radon sinks and sources related to each layer was applied. Two field investigations were performed. During the October campaign, the total groundwater discharge into the lake was found to be 18.9 and 0.7 m(3) d(-1) for the mixolimnion and monimolimnion, respectively. During the December campaign, the groundwater discharge into the mixolimnion was 15.0 m(3) d(-1), whereas no discharge at all was observed into the monimolimnion. Based on the given water volumes, the residence time of lake water was 5.3 years for the monimolimnion and varies between 0.9 and 1.1 years for the mixolimnion. The investigation confirmed radon to be a useful environmental tracer for groundwater and surface water interactions in meromictic lake environments.

Quantifying time-varying ground-water discharge and recharge in wetlands of the northern Florida Everglades

USGS Publications Warehouse

Choi, J.; Harvey, J.W.

2000-01-01

Developing a more thorough understanding of water and chemical budgets in wetlands depends in part on our ability to quantify time-varying interactions between ground water and surface water. We used a combined water and solute mass balance approach to estimate time-varying ground-water discharge and recharge in the Everglades Nutrient Removal project (ENR), a relatively large constructed wetland (1544 hectare) built for removing nutrients from agricultural drainage in the norther Everglades in South Florida, USA. Over a 4-year period (1994 through 1998), ground-water recharge averaged 13.4 hectare-meter per day (ha-m/day) or 0.9 cm/day, which is approximately 31% of surface water pumped into the ENR for treatment. In contrast, ground-water discharge was much smaller (1.4 ha-m/day, or 0.09 cm/day, or 2.8% of water input to ENR for treatment). Using a water-balance approach alone only allowed net ground-water exchange (discharge - recharge) to be estimated (-12 ?? 2.4 ha-ma/day). Disharge and recharge were individually determined by combining a chloride mass balance with the water balance. For a variety of reasons, the ground-water discharge estimated by the combined mass balance approach was not reliable (1.4 ?? 37 ha-m/day). As a result, ground-water interactions could only be reliably estimated by comparing the mass-balance results with other independent approaches, including direct seepage-meter measurements and previous estimates using ground-water modeling. All three independent approaches provided similar estimates of average ground-water recharge, ranging from 13 to 14 ha-m/day. There was also relatively good agreement between ground-water discharge estimates for the mass balance and seepage meter methods, 1.4 and 0.9 ha-m/day, respectively. However, ground-water-flow modeling provided an average discharge estimate that was approximately a factor of four higher (5.4 ha-m/day) than the other two methods. Our study developed an initial understanding of how the

Evapotranspiration Dynamics and Effects on Groundwater Recharge and Discharge at the Tuba City, Arizona, Disposal Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

None, None

The U.S. Department of Energy Office of Legacy Management is evaluating groundwater flow and contaminant transport at a former uranium mill site near Tuba City, Arizona. We estimated effects of temporal and spatial variability in evapotranspiration (ET) on recharge and discharge within a groundwater model domain (GMD) as part of this evaluation. We used remote sensing algorithms and precipitation (PPT) data to estimate ET and the ET/PPT ratios within the 3531 hectare GMD. For the period from 2000 to 2012, ET and PPT were nearly balanced (129 millimeters per year [mm yr -1] and 130 mm yr -1, respectively; ET/PPTmore » = 0.99). However, seasonal and annual variability in ET and PPT were out of phase, and spatial variability in vegetation differentiated discharge and recharge areas within the GMD. Half of ET occurred during spring and early summer when PPT was low, and about 70% of PPT arriving in fall and winter was discharged as plant transpiration in the spring and summer period. Vegetation type and health had a significant effect on the site water balance. Plant cover and ET were significantly higher (1) during years of lighter compared to years of heavier grazing pressure, and (2) on rangeland protected from grazing compared to rangeland grazed by livestock. Heavy grazing increased groundwater recharge (PPT > ET over the 13-year period). Groundwater discharge (ET > PPT over the 13-year period) was highest in riparian phreatophyte communities but insignificant in desert phreatophyte communities impacted by heavy grazing. Grazing management in desert upland and phreatophyte communities may result in reduced groundwater recharge, increased groundwater discharge, and could be used to influence local groundwater flow.« less

Potential effects of existing and proposed groundwater withdrawals on water levels and natural groundwater discharge in Snake Valley and surrounding areas, Utah and Nevada

USGS Publications Warehouse

Masbruch, Melissa D.; Brooks, Lynette E.

2017-04-14

Several U.S. Department of Interior (DOI) agencies are concerned about the cumulative effects of groundwater development on groundwater resources managed by, and other groundwater resources of interest to, these agencies in Snake Valley and surrounding areas. The new water uses that potentially concern the DOI agencies include 12 water-right applications filed in 2005, totaling approximately 8,864 acre-feet per year. To date, only one of these applications has been approved and partially developed. In addition, the DOI agencies are interested in the potential effects of three new water-right applications (UT 18-756, UT 18-758, and UT 18-759) and one water-right change application (UT a40687), which were the subject of a water-right hearing on April 19, 2016.This report presents a hydrogeologic analysis of areas in and around Snake Valley to assess potential effects of existing and future groundwater development on groundwater resources, specifically groundwater discharge sites, of interest to the DOI agencies. A previously developed steady-state numerical groundwater-flow model was modified to transient conditions with respect to well withdrawals and used to quantify drawdown and capture (withdrawals that result in depletion) of natural discharge from existing and proposed groundwater withdrawals. The original steady-state model simulates and was calibrated to 2009 conditions. To investigate the potential effects of existing and proposed groundwater withdrawals on the groundwater resources of interest to the DOI agencies, 10 withdrawal scenarios were simulated. All scenarios were simulated for periods of 5, 10, 15, 30, 55, and 105 years from the start of 2010; additionally, all scenarios were simulated to a new steady state to determine the ultimate long-term effects of the withdrawals. Capture maps were also constructed as part of this analysis. The simulations used to develop the capture maps test the response of the system, specifically the reduction of natural

Soil disturbance as a driver of increased stream salinity in a semiarid watershed undergoing energy development

USGS Publications Warehouse

Bern, Carleton R.; Clark, Melanie L.; Schmidt, Travis S.; Holloway, JoAnn M.; Mcdougal, Robert

2015-01-01

Salinization is a global threat to the quality of streams and rivers, but it can have many causes. Oil and gas development were investigated as one of several potential causes of changes in the salinity of Muddy Creek, which drains 2470 km2 of mostly public land in Wyoming, U.S.A. Stream discharge and salinity vary with seasonal snowmelt and define a primary salinity-discharge relationship. Salinity, measured by specific conductance, increased substantially in 2009 and was 53-71% higher at low discharge and 33-34% higher at high discharge for the years 2009-2012 compared to 2005-2008. Short-term processes (e.g., flushing of efflorescent salts) cause within-year deviations from the primary relation but do not obscure the overall increase in salinity. Dissolved elements associated with increased salinity include calcium, magnesium, and sulfate, a composition that points to native soil salts derived from marine shales as a likely source. Potential causes of the salinity increase were evaluated for consistency by using measured patterns in stream chemistry, slope of the salinity-discharge relationship, and inter-annual timing of the salinity increase. Potential causes that were inconsistent with one or more of those criteria included effects from precipitation, evapotranspiration, reservoirs, grazing, irrigation return flow, groundwater discharge, discharge of energy co-produced waters, and stream habitat restoration. In contrast, surface disturbance of naturally salt-rich soil by oil and gas development activities, such as pipeline, road, and well pad construction, is a reasonable candidate for explaining the salinity increase. As development continues to expand in semiarid lands worldwide, the potential for soil disturbance to increase stream salinity should be considered, particularly where soils host substantial quantities of native salts.

Investigation of Submarine Groundwater Discharge along the Tidal Reach of the Caloosahatchee River, Southwest Florida

USGS Publications Warehouse

Reich, Christopher D.

2010-01-01

The tidal reach of the Caloosahatchee River is an estuarine habitat that supports a diverse assemblage of biota including aquatic vegetation, shellfish, and finfish. The system has been highly modified by anthropogenic activity over the last 150 years (South Florida Water Management District (SFWMD), 2009). For example, the river was channelized and connected to Lake Okeechobee in 1881 (via canal C-43). Subsequently, three control structures (spillway and locks) were installed for flood protection (S-77 and S-78 in the 1930s) and for saltwater-intrusion prevention (S-79, W.P. Franklin Lock and Dam in 1966). The emplacement of these structures and their impact to natural water flow have been blamed for water-quality problems downstream within the estuary (Flaig and Capece, 1998; SFWMD, 2009). Doering and Chamberlain (1999) found that the operation of these control structures caused large and often rapid variations in salinity during various times of the year. Variable salinities could have deleterious impacts on the health of organisms in the Caloosahatchee River estuary. Flow restriction along the Caloosahatchee has also been linked to surface-water eutrophication problems (Doering and Chamberlain, 1999; SFWMD, 2009) and bottom-sediment contamination (Fernandez and others, 1999). Sources of nutrients (nitrogen and phosphorous) that cause eutrophication are primarily from residential sources and agriculture, though wastewater-treatment-plant discharges can also play a major role (SFWMD, 2009). The pathway for many of these nutrients is by land runoff and direct discharge from stormwater drains. An often overlooked source of nutrients and other chemical constituents is from submarine groundwater discharge (SGD). SGD can be either a diffuse or point source (for example, submarine springs) of nutrients and other chemical constituents to coastal waters (Valiela and others, 1990; Swarzenski and others, 2001; 2006; 2007; 2008). SGD can be composed of either fresh or

Estimates of Nutrient Loading by Ground-Water Discharge into the Lynch Cove Area of Hood Canal, Washington

USGS Publications Warehouse

Simonds, F. William; Swarzenski, Peter W.; Rosenberry, Donald O.; Reich, Christopher D.; Paulson, Anthony J.

2008-01-01

Low dissolved oxygen concentrations in the waters of Hood Canal threaten marine life in late summer and early autumn. Oxygen depletion in the deep layers and landward reaches of the canal is caused by decomposition of excess phytoplankton biomass, which feeds on nutrients (primarily nitrogen compounds) that enter the canal from various sources, along with stratification of the water column that prevents mixing and replenishment of oxygen. Although seawater entering the canal is the largest source of nitrogen, ground-water discharge to the canal also contributes significant quantities, particularly during summer months when phytoplankton growth is most sensitive to nutrient availability. Quantifying ground-water derived nutrient loads entering an ecologically sensitive system such as Hood Canal is a critical component of constraining the total nutrient budget and ultimately implementing effective management strategies to reduce impacts of eutrophication. The amount of nutrients entering Hood Canal from ground water was estimated using traditional and indirect measurements of ground-water discharge, and analysis of nutrient concentrations. Ground-water discharge to Hood Canal is variable in space and time because of local geology, variable hydraulic gradients in the ground-water system adjacent to the shoreline, and a large tidal range of 3 to 5 meters. Intensive studies of ground-water seepage and hydraulic-head gradients in the shallow, nearshore areas were used to quantify the freshwater component of submarine ground-water discharge (SGD), whereas indirect methods using radon and radium geochemical tracers helped quantify total SGD and recirculated seawater. In areas with confirmed ground-water discharge, shore-perpendicular electrical resistivity profiles, continuous electromagnetic seepage-meter measurements, and continuous radon measurements were used to visualize temporal variations in ground-water discharge over several tidal cycles. The results of these

Estimation of groundwater discharge and associated chemical fluxes into Poyang Lake, China: approaches using stable isotopes (δD and δ18O) and radon

NASA Astrophysics Data System (ADS)

Liao, Fu; Wang, Guangcai; Shi, Zheming; Cheng, Guoqiang; Kong, Qingmin; Mu, Wenqing; Guo, Liang

2018-05-01

Poyang Lake is the largest freshwater lake in China and is well known for its ecological and economic importance. Understanding the contribution of groundwater to Poyang Lake is important for the lake's protection and management. In this study, stable isotopes (δD and δ18O), 222Rn measurements, and corresponding models (222Rn and 18O mass balance models) were employed to evaluate the groundwater discharge and associated chemical inputs to Poyang Lake. The results showed that the distribution of δ18O in the lake water reflects the groundwater discharge into the lake. The groundwater discharge estimated using the 222Rn mass balance model was in reasonable agreement with the groundwater discharge derived from the 18O mass balance model. The 222Rn mass balance model showed that the groundwater discharge rate was 24.18 ± 6.85 mm/d with a groundwater discharge flux of (2.24 ± 0.63) × 107 m3/d, which accounts for 6.52-11.14% of river-water input in the Poyang Lake area. The groundwater discharge flux estimated using the 18O mass balance model was 3.17 × 107 m3/d, and the average groundwater discharge rate was 26.62 mm/d. The estimated groundwater discharge was used to estimate the associated chemical fluxes. It was found that groundwater-derived heavy metals such as iron and manganese are potential threats to the lake ecological system because of their large inputs from groundwater discharge.

Chemical and isotopic constrains on the origin of brine and saline groundwater in Hetao plain, Inner Mongolia.

PubMed

Liu, Jun; Chen, Zongyu; Wang, Lijuan; Zhang, Yilong; Li, Zhenghong; Xu, Jiaming; Peng, Yurong

2016-08-01

The origin and evolution of brine and saline groundwater have always been a challenged work for geochemists and hydrogeologists. Chemical and isotopic data of brine and saline waters were used to trace the sources of salinity and therefore to understand the transport mechanisms of groundwater in Xishanzui, Inner Mongolia. Both Cl/Br (molar) versus Na/Br (molar) and Cl (meq/L) versus Na (meq/L) indicated that salinity was from halite dissolution or at least a significant impact by halite dissolution. The logarithmic plot of the concentration trends of Cl (mg/L) versus Br (mg/L) for the evaporation of seawater and the Qinghai Salt Lake showed that the terrestrial halite dissolution was the dominated contribution for the salinity of this brine. The stable isotope ratios of hydrogen and oxygen suggested that the origin of brine was from paleorecharge water which experienced mixing of modern water in shallow aquifer. δ(37)Cl values ranged from -0.02 to 3.43 ‰ (SMOC), and reflecting mixing of different sources. The Cl isotopic compositions suggest that the dissolution of halite by paleometeoric water had a great contribution to the salinity of brine, and the contributions of the residual seawater and the dissolution of halite by the Yellow River water could be excluded.

Influence of the paleogeographic evolution on the groundwater salinity in a coastal aquifer. Cabo de Gata aquifer, SE Spain

NASA Astrophysics Data System (ADS)

Vallejos, A.; Sola, F.; Yechieli, Y.; Pulido-Bosch, A.

2018-02-01

The groundwater of the Cabo de Gata detritic aquifer, in southeastern Spain, exhibit salinities of between 70-726 mmol/L of Cl- (brackish-salt to hypersaline waters). We have investigated the causes of the high salinity anomaly, which at certain points exceeds that of present-day seawater (600 mmol/L). Two hypotheses are considered as possible sources for the saline water: (1) The deeper, more saline groundwater date back to an old marine intrusion that occurred at the end of the last Ice Age (14-17 ka), when seawater salinity was higher than in the present day. This hypothesis is supported by the values of 14C measured in this water (∼6-10 pmc), which indicate old water of up to 17 ka. However, the values of 18O and 2H are lower than would be expected. (2) The water is the result of mixing between fresh groundwater and seawater. The latter explanation agrees well with the low values of 18O and 2H. This mixture is later subject to evaporation, explaining its high salinity. Hydrogeochemical modelling was carried out for the most saline samples, assuming such mixing between freshwater and seawater followed by evaporation, and the results show a very good agreement between the measured and simulated values. According to the model calculation, the original mixture contained approximately 60% seawater and its volume subsequently was reduced through evaporation by around 30%. This mixing and evaporation could occur during the Flandrian Transgression (6000-8000 y), when this area accommodated a coastal lagoon.

Temporal variability of submarine groundwater discharge: Assessments via radon and seep meters, the southern carmel coast, Israel

USGS Publications Warehouse

Weinstein, Y.; Shalem, Y.; Burnett, W.C.; Swarzenski, P.W.; Herut, B.

2007-01-01

Seep meter data from Dor Bay, Israel, showed a steady decrease in submarine groundwater discharge (SGD) rates between March and July 2006 (averages of 34, 10.4 and 1.5 cm d-1 in March, May and July, respectively), while estimates based on radon time series showed remarkably uniform averages (8 cm d-1). The May seep meter data show a rough positive correlation with sea level, unlike the negative correlation shown by the Rn-calculated rates. Smaller-size meters, deployed in July adjacent to the regular-size ones, showed significantly higher rates (10 cm d-1), which negatively correlated with salinity. It is suggested that the decreased rates documented by the seep meters are the result of an increased shallow seawater recharge in the bay (due to decreasing hydraulic gradients). This is not captured by the radon, since recharging water is radon-poor. The positive correlation of discharge with sea level is due to increased seawater recycling in times of high sea stand. Copyright ?? 2007 IAHS Press.

Estimation of methane concentrations and loads in groundwater discharge to Sugar Run, Lycoming County, Pennsylvania

USGS Publications Warehouse

Heilweil, Victor M.; Risser, Dennis W.; Conger, Randall W.; Grieve, Paul L.; Hynek, Scott A.

2014-01-01

A stream-sampling study was conducted to estimate methane concentrations and loads in groundwater discharge to a small stream in an active shale-gas development area of northeastern Pennsylvania. Grab samples collected from 15 streams in Bradford, Lycoming, Susquehanna, and Tioga Counties, Pa., during a reconnaissance survey in May and June 2013 contained dissolved methane concentrations ranging from less than the minimum reporting limit (1.0) to 68.5 micrograms per liter (µg/L). The stream-reach mass-balance method of estimating concentrations and loads of methane in groundwater discharge was applied to a 4-kilometer (km) reach of Sugar Run in Lycoming County, one of the four streams with methane concentrations greater than or equal to 5 µg/L. Three synoptic surveys of stream discharge and methane concentrations were conducted during base-flow periods in May, June, and November 2013. Stream discharge at the lower end of the reach was about 0.10, 0.04, and 0.02 cubic meters per second, respectively, and peak stream methane concentrations were about 20, 67, and 29 µg/L. In order to refine estimated amounts of groundwater discharge and locations where groundwater with methane discharges to the stream, the lower part of the study reach was targeted more precisely during the successive studies, with approximate spacing between stream sampling sites of 800 meters (m), 400 m, and 200 m, in May, June, and November, respectively. Samples collected from shallow piezometers and a seep near the location of the peak methane concentration measured in streamwater had groundwater methane concentrations of 2,300 to 4,600 µg/L. These field data, combined with one-dimensional stream-methane transport modeling, indicate groundwater methane loads of 1.8 ±0.8, 0.7 ±0.3, and 0.7 ±0.2 kilograms per day, respectively, discharging to Sugar Run. Estimated groundwater methane concentrations, based on the transport modeling, ranged from 100 to 3,200 µg/L. Although total methane load

Using natural distributions of short-lived radium isotopes to quantify groundwater discharge and recharge

USGS Publications Warehouse

Krest, J.M.; Harvey, J.W.

2003-01-01

Radium activity in pore water of wetland sediments often differs from the amount expected from local production, decay, and exchange with solid phases. This disequilibrium results from vertical transport of radium with groundwater that flows between the underlying aquifer and surface water. In situations where groundwater recharge or discharge is significant, the rate of vertical water flow through wetland sediment can be determined from the radium disequilibrium by a combined model of transport, production, decay, and exchange with solid phases. We have developed and tested this technique at three sites in the freshwater portion of the Everglades by quantifying vertical advective velocities in areas with persistent groundwater recharge or discharge and estimating a coefficient of dispersion at a site that is subject to reversals between recharge and discharge. Groundwater velocities (v) were determined to be between 0 and -0.5 cm d-1 for a recharge site and 1.5 ?? 0.4 cm d-1 for a discharge site near Levee 39 in the Everglades. Strong gradients in 223Ra and 224Ra usually occurred at the base of the peat layer, which avoided the problems of other tracers (e.g., chloride) for which greatest sensitivity occurs near the peat surface - a zone readily disturbed by processes unrelated to groundwater flow. This technique should be easily applicable to any wetland system with different production rates of these isotopes in distinct sedimentary layers or surface water. The approach is most straightforward in systems where constant pore-water ionic strength can be assumed, simplifying the modeling of radium exchange.

14C age reassessment of groundwater from the discharge zone due to cross-flow mixing in the deep confined aquifer

NASA Astrophysics Data System (ADS)

Mao, Xumei; Wang, Hua; Feng, Liang

2018-05-01

In a groundwater flow system, the age of groundwater should gradually increase from the recharge zone to the discharge zone within the same streamline. However, it is occasionally observed that the groundwater age becomes younger in the discharge zone in the piedmont alluvial plain, and the oldest age often appears in the middle of the plain. A new set of groundwater chemistry and isotopes was employed to reassess the groundwater 14C ages from the discharge zone in the North China Plain (NCP). Carbonate precipitation, organic matter oxidation and cross-flow mixing in the groundwater from the recharge zone to the discharge zone are recognized according to the corresponding changes of HCO3- (or DIC) and δ13C in the same streamline of the third aquifer of the NCP. The effects of carbonate precipitation and organic matter oxidation are calibrated with a 13C mixing model and DIC correction, but these corrected 14C ages seem unreasonable because they grow younger from the middle plain to the discharge zone in the NCP. The relationship of Cl- content and the recharge distance is used to estimate the expected Cl- content in the discharge zone, and ln(a14C)/Cl is proposed to correct the a14C in groundwater for the effect of cross-flow mixing. The 14C ages were reassessed with the corrected a14C due to the cross-flow mixing varying from 1.25 to 30.58 ka, and the groundwater becomes older gradually from the recharge zone to the discharge zone. The results suggest that the reassessed 14C ages are more reasonable for the groundwater from the discharge zone due to cross-flow mixing.

Groundwater discharge to lakes (GDL) - the disregarded component of lake nutrient budgets

NASA Astrophysics Data System (ADS)

Lewandowski, J.; Meinikmann, K.; Pöschke, F.; Nützmann, G.

2012-04-01

Eutrophication is a major threat to lakes in temperate climatic zones. It is necessary to determine the relevance of different nutrient sources to conduct effective management measures, to understand in-lake processes and to model future scenarios. A prerequisite for such nutrient budgets are water budgets. While most components of the water budget can be determined quite accurate the quantification of groundwater discharge to lakes (GDL) and surface water infiltration into the aquifer are much more difficult. For example, it is quite common to determine the groundwater component as residual in the water and nutrient budget which is extremely problematic since in that case all errors of the budget terms are summed up in the groundwater term. In total, we identified 10 different reasons for disregarding the groundwater path in nutrient budgets. We investigated the fate of the nutrients nitrogen and phosphorus on their pathway from the catchment through the reactive aquifer-lake interface into the lake. We reviewed the international literature and summarized numbers reported for GDL of nutrients. Since literature is quite sparse we also had a look at numbers reported for submarine groundwater discharge (SGD) of nutrients for which much more literature exists and which is despite some fundamental differences in principal comparable to GDL.

The role of groundwater discharge fluxes on Si:P ratios in a major tributary to Lake Erie.

PubMed

Maavara, Taylor; Slowinski, Stephanie; Rezanezhad, Fereidoun; Van Meter, Kimberly; Van Cappellen, Philippe

2018-05-01

Groundwater discharge can be a major source of nutrients to river systems. Although quantification of groundwater nitrate loading to streams is common, the dependence of surface water silicon (Si) and phosphorus (P) concentrations on groundwater sources has rarely been determined. Additionally, the ability of groundwater discharge to drive surface water Si:P ratios has not been contextualized relative to riverine inputs or in-stream transformations. In this study, we quantify the seasonal dynamics of Si and P cycles in the Grand River (GR) watershed, the largest Canadian watershed draining into Lake Erie, to test our hypothesis that regions of Si-rich groundwater discharge increase surface water Si:P ratios. Historically, both the GR and Lake Erie have been considered stoichiometrically P-limited, where the molar Si:P ratio is greater than the ~16:1 phytoplankton uptake ratio. However, recent trends suggest that eastern Lake Erie may be approaching Si-limitation. We sampled groundwater and surface water for dissolved and reactive particulate Si as well as total dissolved P for 12months within and downstream of a 50-km reach of high groundwater discharge. Our results indicate that groundwater Si:P ratios are lower than the corresponding surface water and that groundwater is a significant source of bioavailable P to surface water. Despite these observations, the watershed remains P-limited for the majority of the year, with localized periods of Si-limitation. We further find that groundwater Si:P ratios are a relatively minor driver of surface water Si:P, but that the magnitude of Si and P loads from groundwater represent a large proportion of the overall fluxes to Lake Erie. Copyright © 2017 Elsevier B.V. All rights reserved.

Probing the mechanism for Deep Submarine Groundwater Discharge using a Case Study in the Levant Basin (Achziv Canyon)

NASA Astrophysics Data System (ADS)

Paldor, A.; Aharonov, E.; Katz, O.

2017-12-01

Deep Submarine Groundwater Discharge (DSGD) is a ubiquitous and highly significant phenomenon, yet it remains poorly understood. Here we use numerical modeling (FEFLOW) to investigate a case study of DSGD offshore northern Israel, aiming to unravel the main features and mechanics of steady-state DSGD: the hydrology that enables its formation, the controls on rates and salinity of seepage, and the residence time of fluid underground. In addition, we investigate the geometry of the fresh-salt water interface within the seeping offshore aquifer. The first part of this work constructs a large scale (70 km) geologic cross-section of our case-study region. The mapping suggests outcropping of confined aquifer strata (Upper Cenomanian Judea Group) on the continental shelf break, 5-15 km offshore. The second part consists of hydrological simulations of DSGD from a confined aquifer similar to the case-study aquifer. The main findings are thus: steady-state DSGD from a confined aquifer occurs far offshore even under moderate heads. It is accompanied by a circulation cell that forms around an intrinsic freshwater-seawater interface. Circulation consists of seawater entering the confined aquifer at the exposed section offshore, mixing with terrestrial groundwater within the aquifer, and seeping saline water out the upper part of the exposed section. In addition, the simulated confined aquifer displays a very flat fresh-salt water interface extending far offshore, as observed in natural offshore aquifers. Preliminary results of a hydrographic survey in the area of study suggest a low-salinity anomaly close to the seafloor, implying seepage of brines in that area, as expected from the model. These new insights have potentially important implications for coastal hydrology, seawater chemistry, biogeochemistry, and submarine slope instability.

Concentrating solar power plants versus groundwater resources in Mediterranean areas of Spain: The environmental dilemma.

PubMed

Moreno Merino, Luis; Imbern Fernández, Núria; Durán Valsero, Juan José; Aguilera, Héctor

2018-01-15

Concentrating solar power plants (CSPPs) are considered to be particularly respectful of the environment but under Mediterranean climate where surface water scarcity is a key issue, these types of electrical plants usually require groundwater for their cooling towers and use the same aquifers to discharge their salinized effluents. This study analyses de Spanish case, where fifteen out of the fifty active CSPPs use groundwater directly, four discharge their effluents to infiltration ponds and forty-three to surface watercourses most of which recharge underlying aquifers. The volume of water withdrawn and discharged varies greatly among similar plants. The salinity of the effluent exceeds 2.5 times that of the withdrawn water in half of the plants and it may alter the current or potential use of the water turning it unsuitable for drinking or even for irrigation. There is a risk that the impact on groundwater can be extended to related ecosystems such as wetlands. This can become a serious environmental problem, but specific impacts on groundwater are often overlooked in environmental impact assessments of CSPPs and no research on the matter has been reported so far. Other legal and political implications of CSPPs are further discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Climate change impacts on the temperature and magnitude of groundwater discharge from shallow, unconfined aquifers

USGS Publications Warehouse

Kurylyk, Barret L.; MacQuarrie, Kerry T.B; Voss, Clifford I.

2014-01-01

Cold groundwater discharge to streams and rivers can provide critical thermal refuge for threatened salmonids and other aquatic species during warm summer periods. Climate change may influence groundwater temperature and flow rates, which may in turn impact riverine ecosystems. This study evaluates the potential impact of climate change on the timing, magnitude, and temperature of groundwater discharge from small, unconfined aquifers that undergo seasonal freezing and thawing. Seven downscaled climate scenarios for 2046–2065 were utilized to drive surficial water and energy balance models (HELP3 and ForHyM2) to obtain future projections for daily ground surface temperature and groundwater recharge. These future surface conditions were then applied as boundary conditions to drive subsurface simulations of variably saturated groundwater flow and energy transport. The subsurface simulations were performed with the U.S. Geological Survey finite element model SUTRA that was recently modified to include the dynamic freeze-thaw process. The SUTRA simulations indicate a potential rise in the magnitude (up to 34%) and temperature (up to 3.6°C) of groundwater discharge to the adjacent river during the summer months due to projected increases in air temperature and precipitation. The thermal response of groundwater to climate change is shown to be strongly dependent on the aquifer dimensions. Thus, the simulations demonstrate that the thermal sensitivity of aquifers and baseflow-dominated streams to decadal climate change may be more complex than previously thought. Furthermore, the results indicate that the probability of exceeding critical temperature thresholds within groundwater-sourced thermal refugia may significantly increase under the most extreme climate scenarios.

A multi-frequency investigation of the influences of groundwater discharge on hydrocarbon emission and transport in the Baltic Sea

NASA Astrophysics Data System (ADS)

Weidner, E. F.; Jakobsson, M.; Nycander, J.; Mayer, L. A.

2017-12-01

In nearshore coastal regions submarine groundwater discharge is a major component of the hydro-geological cycle: transporting nutrients and pollutants to the ocean, producing up-welling currents through buoyancy effects, and acting as an erosional force at discharge sites. In nearshore regions where biogenic gas production is high, groundwater discharge could potentially act as a control on hydrocarbon emission and transport from the seafloor though the water-column. In the southern Stockholm Archipelago of the Baltic Sea, terraces and semi-circular depressions on shallow (<20 meters) seafloor have been linked to the discharge of ground water, traveling along the permeable layers in glacial clay deposits (Söderberg and Flodén 1995; Jakobsson et al., 2016). Sub-bottom profiles over the same region have identified widespread areas of subsurface blanking, commonly attributed to gas, as well as water-column seep features, both in spatial proximity to the groundwater discharge sites. High-resolution multibeam bathymetry and chirp sub-bottom profiles were combined with water-column data sets collected at multiple frequencies (300 kHz, 45-90 kHz, 160-260 kHz) to map the spatial distribution of seeps and investigate their relationship to localized groundwater discharge as determined by seafloor and subsurface morphology. The spatial extent of seep sites appears closely tied to regions of suspected groundwater discharge, suggesting direct or indirect controls on gas emission pathways. Additionally, seep morphology in the broadband data hints at the possibility of groundwater and gas flow mixing.

Geochemical evolution of groundwater salinity at basin scale: a case study from Datong basin, Northern China.

PubMed

Wu, Ya; Wang, Yanxin

2014-05-01

A hydrogeochemical investigation using integrated methods of stable isotopes ((18)O, (2)H), (87)Sr/(86)Sr ratios, Cl/Br ratios, chloride-mass balance, mass balance and hydrogeochemical modeling was conducted to interpret the geochemical evolution of groundwater salinity in Datong basin, northern China. The δ(2)H, δ(18)O ratios in precipitation exhibited a local meteoric water line of δ(2)H = 6.4 δ(18)O -5 (R(2) = 0.94), while those in groundwater suggested their meteoric origin in a historically colder climatic regime with a speculated recharge rate of less than 20.5 mm overall per year, in addition to recharge from a component of deep residual ancient lake water enriched with Br. According to the Sr isotope binary mixing model, the mixing of recharges from the Shentou karst springs (24%), the western margins (11%) and the eastern margins (65%) accounts for the groundwater from the deep aquifers of the down-gradient parts in the central basin is a possible mixing mechanism. In Datong, hydrolysis of silicate minerals is the most important hydrogeochemical process responsible for groundwater chemistry, in addition to dissolution of carbonate and evaporites. In the recharge areas, silicate chemical weathering is typically at the bisiallitization stage, while that in the central basin is mostly at the monosiallitization stage with limited evidence of being in equilibrium with gibbsite. Na exchange with bound Ca, Mg prevails at basin scale, and intensifies with groundwater salinity, while Ca, Mg exchange with bound Na locally occurs in the east pluvial and alluvial plains. Although groundwater salinity increases with the progress of water-rock/sediment interactions along the flow path, as a result of carbonate solubility control and continuous evapotranspiration, Na-HCO3 and Na-Cl-SO4 types of water are usually characterized respectively in the deep and the shallow aquifers of an inland basin with a silicate terrain in an arid climatic regime.

Redox Trapping of Arsenic During Groundwater Discharge in Sediments from the Meghna Riverbank in Bangladesh

DOE Office of Scientific and Technical Information (OSTI.GOV)

Datta, S.; Mailloux, B; Jung, H

2009-01-01

Groundwater arsenic (As) is elevated in the shallow Holocene aquifers of Bangladesh. In the dry season, the shallow groundwater discharges to major rivers. This process may influence the chemistry of the river and the hyporheic zone sediment. To assess the fate of As during discharge, surface (0-5 cm) and subsurface (1-3 m) sediment samples were collected at 9 sites from the bank of the Meghna River along a transect from its northern source (25 degrees N) to the Bay of Bengal (22.5 degrees N). Bulk As concentrations of surface sediment averaged 16 {+-} 7 mg/kg (n = 9). Subsurface sedimentmore » contained higher mean concentrations of As of 4,000 mg/kg (n = 14), ranging from 1 to 23,000 mg/kg As, with >100 mg/kg As measured at 8 sites. X-ray absorption near-edge structure spectroscopy indicated that As was mainly arsenate and arsenite, not As-bearing sulfides. We hypothesize that the elevated sediment As concentrations form as As-rich groundwater discharges to the river, and enters a more oxidizing environment. A significant portion of dissolved As sorbs to iron-bearing minerals, which form a natural reactive barrier. Recycling of this sediment-bound As to the Ganges-Brahmaputra-Meghna Delta aquifer provides a potential source of As to further contaminate groundwater. Furthermore, chemical fluxes from groundwater discharge from the Ganges-Brahmaputra-Meghna Delta may be less than previous estimates because this barrier can immobilize many elements.« less

Tidal variability of nutrients in a coastal coral reef system influenced by groundwater

NASA Astrophysics Data System (ADS)

Wang, Guizhi; Wang, Shuling; Wang, Zhangyong; Jing, Wenping; Xu, Yi; Zhang, Zhouling; Tan, Ehui; Dai, Minhan

2018-02-01

To investigate variation in nitrite, nitrate, phosphate, and silicate in a spring-neap tide in a coral reef system influenced by groundwater discharge, we carried out a time-series observation of these nutrients and 228Ra, a tracer of groundwater discharge, in the Luhuitou fringing reef at Sanya Bay in the South China Sea. The maximum 228Ra, 45.3 dpm 100 L-1, appeared at low tide and the minimum, 14.0 dpm 100 L-1, appeared during a flood tide in the spring tide. The activity of 228Ra was significantly correlated with water depth and salinity in the spring-neap tide, reflecting the tidal-pumping feature of groundwater discharge. Concentrations of all nutrients exhibited strong diurnal variation, with a maximum in the amplitude of the diel change for nitrite, nitrate, phosphate, and silicate in the spring tide of 0.46, 1.54, 0.12, and 2.68 µM, respectively. Nitrate and phosphate were negatively correlated with water depth during the spring tide but showed no correlation during the neap tide. Nitrite was positively correlated with water depth in the spring and neap tide due to mixing of nitrite-depleted groundwater and nitrite-rich offshore seawater. They were also significantly correlated with salinity (R2 ≥ 0.9 and P < 0.05) at the ebb flow of the spring tide, negative for nitrate and phosphate and positive for nitrite, indicating the mixing of nitrite-depleted, nitrate- and phosphate-rich less saline groundwater and nitrite-rich, nitrate- and phosphate-depleted saline offshore seawater. We quantified variation in oxidized nitrogen (NOx) and phosphate contributed by biological processes based on deviations from mixing lines of these nutrients. During both the spring and neap tide biologically contributed NOx and phosphate were significantly correlated with regression slopes of 4.60 (R2 = 0.16) in the spring tide and 13.4 (R2 = 0.75) in the neap tide, similar to the composition of these nutrients in the water column, 5.43 (R2 = 0.27) and 14.2 (R2 = 0

Salinity Impacts on Agriculture and Groundwater in Delta Regions

NASA Astrophysics Data System (ADS)

Clarke, D.; Salehin, M.; Jairuddin, M.; Saleh, A. F. M.; Rahman, M. M.; Parks, K. E.; Haque, M. A.; Lázár, A. N.; Payo, A.

2015-12-01

Delta regions are attractive for high intensity agriculture due to the availability of rich sedimentary soils and of fresh water. Many of the world's tropical deltas support high population densities which are reliant on irrigated agriculture. However environmental changes such as sea level rise, tidal inundation and reduced river flows have reduced the quantity and quality of water available for successful agriculture. Additionally, anthropogenic influences such as the over abstraction of ground water and the increased use of low quality water from river inlets has resulted in the accumulation of salts in the soils which diminishes crop productivity. Communities based in these regions are usually reliant on the same water for drinking and cooking because surface water is frequently contaminated by commercial and urban pollution. The expansion of shallow tube well systems for drinking water and agricultural use over the last few decades has resulted in mobilisation of salinity in the coastal and estuarine fringes. Sustainable development in delta regions is becoming constrained by water salinity. However salinity is often studied as an independent issue by specialists working in the fields of agriculture, community water supply and groundwater. The lack of interaction between these disciplines often results in corrective actions being applied to one sector without fully assessing the effects of these actions on other sectors. This paper describes a framework for indentifying the causes and impacts of salinity in delta regions based on the source-pathway-receptor framework. It uses examples and scenarios from the Ganges-Brahmaputra-Meghna delta in Bangladesh together with field measurements and observations made in vulnerable coastal communities. The paper demonstrates the importance of creating an holistic understanding of the development and management of water resources to reduce the impact of salinity in fresh water in delta regions.

Freshwater recharge into a shallow saline groundwater system, Cooper Creek floodplain, Queensland, Australia

NASA Astrophysics Data System (ADS)

Cendón, Dioni I.; Larsen, Joshua R.; Jones, Brian G.; Nanson, Gerald C.; Rickleman, Daniel; Hankin, Stuart I.; Pueyo, Juan J.; Maroulis, Jerry

2010-10-01

SummaryFreshwater lenses have been identified as having penetrated the shallow regional saline groundwater beneath the Cooper Creek floodplain near Ballera (south-west Queensland). Piezometers were installed to evaluate the major-element chemistry along a floodplain transect from a major waterhole (Goonbabinna) to a smaller waterhole (Chookoo) associated with a sand dune complex. The floodplain consists of 2-7 m of impermeable mud underlain by unconsolidated fluvial sands with a saline watertable. Waterholes have in places scoured into the floodplain. The transect reveals that groundwater recharge takes place through the base of the waterholes at times of flood scour, but not through the floodplain mud. Total dissolved solids rise with distance from the waterhole and independently of the presence of sand dunes. Stable water isotopes (δ 2H and δ 18O) confirm that recharge is consistent with, and dependant on, monsoonal flooding events. Following floods, the waterholes self-seal and retain water for extended periods, with sulfate-δ 34S and δ 18O isotopes suggesting bacterial reduction processes within the hyporheic zone, and limited interaction between the surface water and groundwater during no-flow conditions. The area occupied by the freshwater lenses (TDS < 5000 mg/L) is locally asymmetrical with respect to the channel flow direction, extending down gradient along distances of ˜300 m.

Mapping saline groundwater beneath the Sea Galilee and its vicinity using time domain electromagnetic (TDEM) geophysical technique

USGS Publications Warehouse

Goldman, M.; Gvirtzman, H.; Hurwitz, S.

2004-01-01

An extensive time domain electromagnetic (TDEM) survey covering the Sea of Galilee with a dense grid of points has been recently carried out. A total of 269 offshore and 33 supplementary onshore TDEM soundings were performed along six N-S and ten W-E profiles and at selected points both offshore and onshore along the whole coastal line. The interpreted resistivities were calibrated with the direct salinity measurements in the Haon-2 borehole and relatively deep (5 m) cores taken from the lake bottom. It was found that resistivities below 1 ohm-m are solely indicative of groundwater salinity exceeding 10,000 mg Cl/l. Such low resistivities (high salinities) were detected at depths greater than 15 m below almost the entire bottom of the lake. At some parts of the lake, particularly in the south, the saline water was detected at shallower depths, sometimes at a few meters below the bottom. Relatively high resistivity (fresh groundwater) was found along the margins of the lake down to roughly 100 m, the maximum exploration depth of the system. The detected sharp lateral contrasts at the lake margin between high and low resistivities coincide with the faults separating the carbonate and clastic units, respectively. The geometry of the fresh/saline groundwater interface below the central part of the lake is very similar to the shape of the lake bottom, probably due to the diffusive salt transport from the bottom sediments to the lake water. The above geophysical observations suggest differentsalt transport mechanisms from the sediments to the central part of the lake (diffusion) and from regional aquifers to the margins of the lake (advection). ?? 2004 Science From Israel/LPPLtd.

Groundwater sustainability and groundwater/surface-water interaction in arid Dunhuang Basin, northwest China

NASA Astrophysics Data System (ADS)

Lin, Jingjing; Ma, Rui; Hu, Yalu; Sun, Ziyong; Wang, Yanxin; McCarter, Colin P. R.

2018-03-01

The Dunhuang Basin, a typical inland basin in northwestern China, suffers a net loss of groundwater and the occasional disappearance of the Crescent Lake. Within this region, the groundwater/surface-water interactions are important for the sustainability of the groundwater resources. A three-dimensional transient groundwater flow model was established and calibrated using MODFLOW 2000, which was used to predict changes to these interactions once a water diversion project is completed. The simulated results indicate that introducing water from outside of the basin into the Shule and Danghe rivers could reverse the negative groundwater balance in the Basin. River-water/groundwater interactions control the groundwater hydrology, where river leakage to the groundwater in the Basin will increase from 3,114 × 104 m3/year in 2017 to 11,875 × 104 m3/year in 2021, and to 17,039 × 104 m3/year in 2036. In comparison, groundwater discharge to the rivers will decrease from 3277 × 104 m3/year in 2017 to 1857 × 104 m3/year in 2021, and to 510 × 104 m3/year by 2036; thus, the hydrology will switch from groundwater discharge to groundwater recharge after implementing the water diversion project. The simulation indicates that the increased net river infiltration due to the water diversion project will raise the water table and then effectively increasing the water level of the Crescent Lake, as the lake level is contiguous with the water table. However, the regional phreatic evaporation will be enhanced, which may intensify soil salinization in the Dunhuang Basin. These results can guide the water allocation scheme for the water diversion project to alleviate groundwater depletion and mitigate geo-environmental problem.

Cation exchange in a temporally fluctuating thin freshwater lens on top of saline groundwater

NASA Astrophysics Data System (ADS)

Eeman, S.; De Louw, P. G. B.; Van der Zee, S. E. A. T. M.

2017-01-01

In coastal-zone fields with a high groundwater level and sufficient rainfall, freshwater lenses are formed on top of saline or brackish groundwater. The fresh and the saline water meet at shallow depth, where a transition zone is found. This study investigates the mixing zone that is characterized by this salinity change, as well as by cation exchange processes, and which is forced by seepage and by rainfall which varies as a function of time. The processes are first investigated for a one-dimensional (1D) stream tube perpendicular to the interface concerning salt and major cation composition changes. The complex sequence of changes is explained with basic cation exchange theory. It is also possible to show that the sequence of changes is maintained when a two-dimensional field is considered where the upward saline seepage flows to drains. This illustrates that for cation exchange, the horizontal component (dominant for flow of water) has a small impact on the chemical changes in the vertical direction. The flow's horizontal orientation, parallel to the interface, leads to changes in concentration that are insignificant compared with those that are found perpendicular to the interface, and are accounted for in the 1D flow tube. Near the drains, differences with the 1D considerations are visible, especially in the longer term, exceeding 100 years. The simulations are compared with field data from the Netherlands which reveal similar patterns.

ASSESSMENT OF GROUNDWATER DISCHARGE AND SEWAGE IMPACT INTO SARASOTA BAY AND SUWANNEE RIVER ESTUARY

EPA Science Inventory

The ongoing objectives in Sarasota Bay are to 1) determine if the reduced water clarity and enriched 15N seagrass values are due to groundwater N inputs, 2) determine the effectiveness of geophysical reconnaissance methods in identifying zones of groundwater discharge under a var...

Rainfall and irrigation controls on groundwater rise and salinity risk in the Ord River Irrigation Area, northern Australia

NASA Astrophysics Data System (ADS)

Smith, Anthony J.

2008-09-01

Groundwater beneath the Ord River Irrigation Area (ORIA) in northern Australia has risen in elevation by 10-20 m during the past 40 years with attendant concerns about water logging and soil salinization. Persistent groundwater accession has been attributed to excessive irrigation and surface water leakage; however, analysis of daily water-table records from the past 10 years yielded a contrary result. On a seasonal basis, water-table elevation typically fell during irrigation (dry) seasons and rose during fallow (wet) seasons, conflicting with the conventional view that irrigation and not rainfall must be the dominant control on groundwater accession. Previous investigations of unexpectedly large infiltration losses through the cracking clay soils provide a plausible explanation for the apparent conundrum. Because rainfall is uncontrolled and occurs independently of the soil moisture condition, there is greater opportunity for incipient ponding and rapid infiltration through preferred flow pathways. In contrast, irrigation is scheduled when needed and applications are stopped after soil wetting is achieved. Contemporary groundwater management in the ORIA is focused on improving irrigation efficiency during dry seasons but additional opportunities may exist to improve groundwater conditions and salinity risk through giving equal attention to the wet-season water balance.

Identifying spatial variability of groundwater discharge in a wetland stream using a distributed temperature sensor

USGS Publications Warehouse

Lowry, Christopher S.; Walker, John F.; Hunt, Randall J.; Anderson, Mary P.

2007-01-01

Discrete zones of groundwater discharge in a stream within a peat‐dominated wetland were identified on the basis of variations in streambed temperature using a distributed temperature sensor (DTS). The DTS gives measurements of the spatial (±1 m) and temporal (15 min) variation of streambed temperature over a much larger reach of stream (>800 m) than previous methods. Isolated temperature anomalies observed along the stream correspond to focused groundwater discharge zones likely caused by soil pipes within the peat. The DTS also recorded variations in the number of temperature anomalies, where higher numbers correlated well with a gaining reach identified by stream gauging. Focused zones of groundwater discharge showed essentially no change in position over successive measurement periods. Results suggest DTS measurements will complement other techniques (e.g., seepage meters and stream gauging) and help further improve our understanding of groundwater–surface water dynamics in wetland streams.

Ra and Rn isotopes as natural tracers of submarine groundwater discharge in Tampa Bay, Florida

USGS Publications Warehouse

Swarzenski, P.W.; Reich, C.; Kroeger, K.D.; Baskaran, M.

2007-01-01

A suite of naturally occurring radionuclides in the U/Th decay series (222Rn, 223,224,226,228Ra) were studied during wet and dry conditions in Tampa Bay, Florida, to evaluate their utility as groundwater discharge tracers, both within the bay proper and within the Alafia River/estuary — a prominent free-flowing river that empties into the bay. In Tampa Bay, almost 30% of the combined riverine inputs still remain ungauged. Consequently, groundwater/surface water (hyporheic) exchange in the discharging coastal rivers, as well as submarine groundwater discharge (SGD) within the bay, are still unresolved components of this system's water and material budgets. Based on known inputs and sinks, there exists an excess of 226Ra in the water column of Tampa Bay, which can be evaluated in terms of a submarine groundwater contribution to the bay proper. Submarine groundwater discharge rates calculated using a mass balance of excess 226Ra ranged from 2.2 to 14.5 L m− 2 day− 1, depending on whether the estuarine residence time was calculated using 224Ra/xs228Ra isotope ratios, or whether a long term, averaged model-derived estuarine residence time was used. When extrapolated to the total shoreline length of the bay, such SGD rates ranged from 1.6 to 10.3 m3 m− 1 day− 1. Activities of 222Rn were also elevated in surface water and shallow groundwater of the bay, as well as in the Alafia River estuary, where upstream activities as high as 250 dpm L− 1 indicate enhanced groundwater/surface water exchange, facilitated by an active spring vent. From average nutrient concentrations of 39 shallow, brackish, groundwater samples, rates of nutrient loading into Tampa Bay by SGD rates were estimated, and these ranged from 0.2 to 1.4 × 105 mol day− 1 (PO43−), 0.9–6.2 × 105 mol day− 1 (SiO4−), 0.7–5.0 × 105 mol day− 1 (dissolved organic nitrogen, DON), and 0.2–1.4 × 106 mol day− 1 (total dissolved nitrogen, TDN). Such nutrient loading estimates, when compared

The integrated impacts of natural processes and human activities on the origin and processes of groundwater salinization in the coastal aquifers of Beihai, Southern China

NASA Astrophysics Data System (ADS)

Li, Q.; Zhan, Y., , Dr; Chen, W. Ms; Yu, S., , Dr

2017-12-01

Salinization in coastal aquifers usually is the results of contamination related to both seawater intrusion and water-rock interaction. The chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai. The concentrations of the major ions that dominate in sea water (Cl-, Na+, Ca2+, Mg2+ and SO2- 4), as well as the isotopic ratios (2H, 18O, 87Sr/86Sr and 13C) suggest that the salinization occurring in the aquifer water of the coastal plain is related to seawater and the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization occurred in parts of the area, which is significantly influenced by the land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds is identified in the confined aquifer I at site BBW2. In consequence, the leakage from this polluted aquifer causes the salinization of groundwater in the confined aquifer II. At site BBW3, the confined aquifer I and lower confined aquifer II are remarkably contaminated by seawater intrusion. The weak connectivity with upper aquifers and seaward movement of freshwater prevents saltwater from encroaching the confined aquifer III. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for sustainable planning and management of groundwater resources in this region.

Assessing tsunami-induced groundwater salinization and its temporal change: a numerical modelling study on the Niijima Island, Japan

NASA Astrophysics Data System (ADS)

Liu, Jiaqi; Tokunaga, Tomochika

2016-04-01

Groundwater is vulnerable to many natural hazards, including tsunami. As reported after the 2004 Indian Ocean earthquake and the 2011 Great East Japan earthquake, the generated massive tsunami inundations resulted in unexpected groundwater salinization in coastal areas. Water supply was strongly disturbed due to the significantly elevated salinity in groundwater. Supplying fresh water is one of the prioritized concerns in the immediate aftermath of disaster, and during long-term post-disaster reconstruction as well. The aim of this study is to assess the impact of tsunami on coastal groundwater system and provide guidelines on managing water resources in post-tsunami period. We selected the study area as the Niijima Island, a tsunami-prone area in Japan, which is under the risk of being attacked by a devastated tsunami with its wave height up to 30 m. A three-dimension (3-D) numerical model of the groundwater system on the Niijima Island was developed by using the simulation code FEFLOW which can handle both density- dependent groundwater flow and saturated-unsaturated flow processes. The model was justified by the measured water table data obtained from the field work in July, 2015. By using this model, we investigated saltwater intrusion and aquifer recovery process under different tsunami scenarios. Modelling results showed that saltwater could fully saturate the vadose zone and come into contact with groundwater table in just 10 mins. The 0.6 km2 of inundation area introduced salt mass equivalent to approximately 9×104 t of NaCl into the vadose zone. After the retreat of tsunami waves, the remained saltwater in vadose zone continuously intruded into the groundwater and dramatically salinized the aquifer up to about 10,000 mg/L. In the worst tsunami scenario, it took more than 10 years for the polluted aquifer to be entirely recovered by natural rainfall. Given that the groundwater is the only freshwater source on the Niijima Island, we can provide suggestions

Groundwater

USGS Publications Warehouse

Stonestrom, David A.; Wohl, Ellen E.

2016-01-01

Groundwater represents the terrestrial subsurface component of the hydrologic cycle. As such, groundwater is generally in motion, moving from elevated areas of recharge to lower areas of discharge. Groundwater usually moves in accordance with Darcy’s law (Dalmont, Paris: Les Fontaines Publiques de la Ville de Dijon, 1856). Groundwater residence times can be under a day in small upland catchments to over a million years in subcontinental-sized desert basins. The broadest definition of groundwater includes water in the unsaturated zone, considered briefly here. Water chemically bound to minerals, as in gypsum (CaSO4 • 2H2O) or hydrated clays, cannot flow in response to gradients in total hydraulic head (pressure head plus elevation head); such water is thus usually excluded from consideration as groundwater. In 1940, M. King Hubbert showed Darcy’s law to be a special case of thermodynamically based potential field equations governing fluid motion, thereby establishing groundwater hydraulics as a rigorous engineering science (Journal of Geology 48, pp. 785–944). The development of computer-enabled numerical methods for solving the field equations with real-world approximating geometries and boundary conditions in the mid-1960s ushered in the era of digital groundwater modeling. An estimated 30 percent of global fresh water is groundwater, compared to 0.3 percent that is surface water, 0.04 percent atmospheric water, and 70 percent that exists as ice, including permafrost (Shiklomanov and Rodda 2004, cited under Groundwater Occurrence). Groundwater thus constitutes the vast majority—over 98 percent—of the unfrozen fresh-water resources of the planet, excluding surface-water reservoirs. Environmental dimensions of groundwater are equally large, receiving attention on multiple disciplinary fronts. Riparian, streambed, and spring-pool habitats can be sensitively dependent on the amount and quality of groundwater inputs that modulate temperature and solutes

Assessment of human activities impact on groundwater quality discharging into a reef lagoon

NASA Astrophysics Data System (ADS)

Rebolledo-Vieyra, M.; Hernandez, L.; Paytan, A.; Merino-Ibarra, M.; Lecossec, A.; Soto, M.

2010-03-01

The Eastern coast of the Yucatan Peninsula has the fastest growth rate in Mexico and groundwater is the only source of drinking water in the region. The consequences of the lack of proper infrastructure to collect and treat wastewater and the impact of human activities on the quality of groundwater are addressed. The groundwater in the coastal aquifer of Quintana Roo (SE Mexico) discharges directly into the ocean (Submarine Groundwater Discharges). In addition, the coral reef of the Eastern Yucatan Peninsula is part of the Mesoamerican Coral Reef System, one of the largest in the world. The interaction of the reef-lagoon hydraulics with the coastal aquifer of Puerto Morelos (NE Yucatan Peninsula), and a major input of NH4, SO4, SiO2, as a consequence of the use of septic tanks and the lack of modern wastewater treatment plants are presented. A conceptual model of the coastal aquifer was developed, in order to explain how the human activities are impacting directly on the groundwater quality that, potentially, will have a direct impact on the coral reef. The protection and conservation of coral reefs must be directly related with a policy of sound management of coastal aquifers and wastewater treatment.

Physical hydrogeology and environmental isotopes to constrain the age, origins, and stability of a low-salinity groundwater lens formed by periodic river recharge: Murray Basin, Australia

NASA Astrophysics Data System (ADS)

Cartwright, Ian; Weaver, Tamie R.; Simmons, Craig T.; Fifield, L. Keith; Lawrence, Charles R.; Chisari, Robert; Varley, Simon

2010-01-01

SummaryA low-salinity (total dissolved solids, TDS, <5000 mg/L) groundwater lens underlies the Murray River in the Colignan-Nyah region of northern Victoria, Australia. Hydraulic heads, surface water elevations, δ 18O values, major ion geochemistry, 14C activities, and 3H concentrations show that the lens is recharged from the Murray River largely through the riverbank with limited recharge through the floodplain. Recharge of the lens occurs mainly at high river levels and the low-salinity groundwater forms baseflow to some river reaches during times of low river levels. Within the lens, flow through the shallow Channel Sands and deeper Parilla Sands aquifers is sub-horizontal. While the Blanchetown Clay locally separates the Channel Sands and the Parilla Sands, the occurrence of recently recharged low-salinity groundwater below the Blanchetown Clay suggests that there is considerable leakage through this unit, implying that it is not an efficient aquitard. The lateral margin of the lens with the regional groundwater (TDS >25,000 mg/L) is marked by a hectometer to kilometer scale transition in TDS concentrations that is not stratigraphically controlled. Rather this boundary represents a mixing zone with the regional groundwater, the position of which is controlled by the rate of recharge from the river. The lens is part of an active and dynamic hydrogeological system that responds over years to decades to changes in river levels. The lens has shrunk during the drought of the late 1990s to the mid 2000s, and it will continue to shrink unless regular high flows in the Murray River are re-established. Over longer timescales, the rise of the regional water table due to land clearing will increase the hydraulic gradient between the regional groundwater and the groundwater in the lens, which will also cause it to degrade. Replacement of low-salinity groundwater in the lens with saline groundwater will ultimately increase the salinity of the Murray River reducing its

Character of Submarine Groundwater Discharge (SGD) at the Coast of Mallorca Island

NASA Astrophysics Data System (ADS)

Coffey, R.; Bokuniewicz, H. J.; Basterretxea, G.; Tovar Sánchez, A.

2007-12-01

Preliminary results of geochemical tracers indicated that submarine groundwater discharge (SGD) is prevalent around the Mallorca coast, Spain; SGD would be an important source of trace metals and phosphorus to the coastal ocean. During September 2006, vented benthic chambers (a.k.a. seepage meters) were used at four diverse sites along the coast (Es Caragol, Porto Colom, Santa Ponça and Sóller) to directly measure SGD in order to investigate the characteristics of SGD. Mallorca is an example of a (Miocene) carbonate platform. The site at Sóller on the northeast coast is located on a wide stretch of beach in an embayment surrounded by part of the high relief of the Tramuntana Range; the other three sites were in areas of relatively low relief. The average rate of groundwater seepage at the four sites ranged from 3 to 19 cm d-1, being highest at Es Caragol, a wide embayment on the southern coast of Mallorca. All sites were characterized by an irregular, spatial distribution of seepage which was dominated by low values, less than 15 cm d-1 in most locations, but punctuated by high values (up to 65 cm d-1) in discrete locations. This characteristic was best represented by the observations at Sóller, where one device documented a consistently higher SGD, averaging 52 cm d-1, while the rest of the study area had an average SGD of 6 cm d-1. Such an irregular distribution would be expected to characterize fractured rock or karstic aquifers. There was little or no tidal modulation of the SGD which suggested to us that the driving forces adjusted, for the most part, to the tidal elevations in open water. In addition, the water seeping across the sediment-water interface showed little or no dilution from the ambient, open-water salinity, in fact, in one case, the salinity of the SGD was greater than ambient sea water. SGD at these locations appeared to be dominated by the recirculation of sea water through the aquifer, driven by oceanic processes. This work was supported

Determining sources of elevated salinity in pre-hydraulic fracturing water quality data using a multivariate discriminant analysis model

NASA Astrophysics Data System (ADS)

Lautz, L. K.; Hoke, G. D.; Lu, Z.; Siegel, D. I.

2013-12-01

Hydraulic fracturing has the potential to introduce saline water into the environment due to migration of deep formation water to shallow aquifers and/or discharge of flowback water to the environment during transport and disposal. It is challenging to definitively identify whether elevated salinity is associated with hydraulic fracturing, in part, due to the real possibility of other anthropogenic sources of salinity in the human-impacted watersheds in which drilling is taking place and some formation water present naturally in shallow groundwater aquifers. We combined new and published chemistry data for private drinking water wells sampled across five southern New York (NY) counties overlying the Marcellus Shale (Broome, Chemung, Chenango, Steuben, and Tioga). Measurements include Cl, Na, Br, I, Ca, Mg, Ba, SO4, and Sr. We compared this baseline groundwater quality data in NY, now under a moratorium on hydraulic fracturing, with published chemistry data for 6 different potential sources of elevated salinity in shallow groundwater, including Appalachian Basin formation water, road salt runoff, septic effluent, landfill leachate, animal waste, and water softeners. A multivariate random number generator was used to create a synthetic, low salinity (< 20 mg/L Cl) groundwater data set (n=1000) based on the statistical properties of the observed low salinity groundwater. The synthetic, low salinity groundwater was then artificially mixed with variable proportions of different potential sources of salinity to explore chemical differences between groundwater impacted by formation water, road salt runoff, septic effluent, landfill leachate, animal waste, and water softeners. We then trained a multivariate, discriminant analysis model on the resulting data set to classify observed high salinity groundwater (> 20 mg/L Cl) as being affected by formation water, road salt, septic effluent, landfill leachate, animal waste, or water softeners. Single elements or pairs of

Quantifying Groundwater Nutrient Discharge to a Large Glacial Lake using a Watershed Loading Model

NASA Astrophysics Data System (ADS)

Schilling, K. E.

2015-12-01

Groundwater discharge to a lake is an important, if often neglected, component to water and nutrient budgets. Point measurements of groundwater discharge into a lake are prone to error, so in this study of 15.57 km2 West Lake Okoboji, Iowa, a watershed-based groundwater loading model was developed. Located in northwest Iowa, West Lake Okoboji is considered one of Iowa's premier tourist destinations but is threatened by eutrophication. A network of 21 observation wells was installed in the watershed to evaluate groundwater recharge and quality under representative land cover types in a range of landscape positions. Our objective was to develop typical groundwater responses from various land cover-landscape associations for scaling up to unmonitored areas in the watershed. Results indicated substantial variation in groundwater recharge and quality in the 3847 ha watershed. Recharge was similar among land covers under vegetation but was much lower under urban pavement. Nitrate-nitrogen concentrations were highest under cropped fields and lowest under perennial grassland and golf courses, whereas dissolved phosphorus was highest under residential and urban areas, including an engineered bioswale. A groundwater load allocation model indicated 91% of the nitrate load was from cropped areas and 7% from residential areas. In contrast, P loads were more equally divided among cropped fields (43%), perennial grass (36%) and residential (19%) areas. Based on the mass of nitrate and P in the lake, groundwater accounts for 71% and 18% of the nutrient inputs, respectively.

Estimating groundwater discharge into the ocean in the Yucatán Peninsula

NASA Astrophysics Data System (ADS)

Alvarez Rodriguez, G.; Gutierrez-Jurado, H. A.; Uuh-Sonda, J.

2017-12-01

The Yucatán peninsula is an emerged flat carbonate block abundant in soluble rocks. High permeability and dissolution of the rock, facilitates the development of channels, sinkholes and caves where underground rivers discharge into the ocean. There are no rivers or streams acting as a surface drainage system, all rainfall water entering the peninsula is discharged either as evapotranspiration (ET) or as underground runoff into the ocean. To date there are no estimates of the total groundwater discharge from the peninsula into the sea, and of the spatial distribution of recharge and discharge areas thereby hindering efforts to understand the dynamics of a complex hydrologic system. In this study, we estimate the discharge (Q) by solving the water balance equation (ΔS=PPT-ET-Q) using remote sensing products over a period of 12 years; the change in storage (ΔS) was retrieved from the satellite GRACE; precipitation (PPT) from the Tropical Rainfall Measuring Mission; and evapotranspiration (ET) from the Moderate Resolution Imaging Spectroradiometer. Results show that freshwater discharge via evapotranspiration can be a significant portion of the water budget depending on the climatic conditions throughout the year. We observe high recharge-discharge inter-annual variability in the center of the peninsula and some clearly defined recharge and discharge zones around the perimeter. On average the dryer north-east and wetter north-western parts of the peninsula act as recharge zones (where the influx of water is higher than the outflow), while the central-northern part of the peninsula corresponding to agricultural lands, acts as a discharge zone (outflow is higher than influx). The most southern region of the peninsula and the western mangroves are always discharge zones. Finally, our analyses reveal a number of highly subsidized zones, where precipitation levels are consistently lower than evapotranspiration, hence indicating the presence of groundwater dependent

Estimating changes to groundwater discharge temperature under altered climate conditions

NASA Astrophysics Data System (ADS)

Manga, M.; Burns, E. R.; Zhu, Y.; Zhan, H.; Williams, C. F.; Ingebritsen, S.; Dunham, J.

2017-12-01

Changes in groundwater temperature resulting from climate-driven boundary conditions (recharge and land surface temperature) can be evaluated using new analytical solutions of the groundwater heat transport equation. These steady-state solutions account for land-surface boundary conditions, hydrology, and geothermal and viscous heating, and can be used to identify the key physical processes that control thermal responses of groundwater-fed ecosystems to climate change, in particular (1) groundwater recharge rate and temperature and (2) land-surface temperature transmitted through the vadose zone. Also, existing transient solutions of conduction are compared with a new solution for advective transport of heat to estimate the timing of groundwater-discharge response to changes in recharge and land surface temperature. As an example, the new solutions are applied to the volcanic Medicine Lake highlands, California, USA, and associated Fall River Springs complexes that host groundwater-dependent ecosystems. In this system, high-elevation groundwater temperatures are strongly affected only by recharge conditions, but as the vadose zone thins away from the highlands, changes to the average annual land surface temperature will also influence groundwater temperatures. Transient response to temperature change depends on both the conductive timescale and the rate at which recharge delivers heat. Most of the thermal response of groundwater at high elevations will occur within 20 years of a shift in recharge temperatures, but the lower-elevation Fall River Springs will respond more slowly, with about half of the conductive response occurring within the first 20 years and about half of the advective response to higher recharge temperatures occurring in approximately 60 years.

Stream measurements locate thermogenic methane fluxes in groundwater discharge in an area of shale-gas development.

PubMed

Heilweil, Victor M; Grieve, Paul L; Hynek, Scott A; Brantley, Susan L; Solomon, D Kip; Risser, Dennis W

2015-04-07

The environmental impacts of shale-gas development on water resources, including methane migration to shallow groundwater, have been difficult to assess. Monitoring around gas wells is generally limited to domestic water-supply wells, which often are not situated along predominant groundwater flow paths. A new concept is tested here: combining stream hydrocarbon and noble-gas measurements with reach mass-balance modeling to estimate thermogenic methane concentrations and fluxes in groundwater discharging to streams and to constrain methane sources. In the Marcellus Formation shale-gas play of northern Pennsylvania (U.S.A.), we sampled methane in 15 streams as a reconnaissance tool to locate methane-laden groundwater discharge: concentrations up to 69 μg L(-1) were observed, with four streams ≥ 5 μg L(-1). Geochemical analyses of water from one stream with high methane (Sugar Run, Lycoming County) were consistent with Middle Devonian gases. After sampling was completed, we learned of a state regulator investigation of stray-gas migration from a nearby Marcellus Formation gas well. Modeling indicates a groundwater thermogenic methane flux of about 0.5 kg d(-1) discharging into Sugar Run, possibly from this fugitive gas source. Since flow paths often coalesce into gaining streams, stream methane monitoring provides the first watershed-scale method to assess groundwater contamination from shale-gas development.

Sources of salinity and boron in the Gaza strip: Natural contaminant flow in the southern Mediterranean coastal aquifer

NASA Astrophysics Data System (ADS)

Vengosh, Avner; Kloppmann, Wolfram; Marei, Amer; Livshitz, Yakov; Gutierrez, Alexis; Banna, Mazen; Guerrot, Catherine; Pankratov, Irena; Raanan, Hadas

2005-01-01

Salinization in coastal aquifers is a global phenomenon resulting from the overexploitation of scarce water resources. The Gaza Strip is one of the most severe cases of salinization, as accelerated degradation of the water quality endangers the present and future water supply for over 1 million people. We investigate the chemical and isotopic (87Sr/86Sr, δ11B, δ18O, δ2H, and δ34SSO4) compositions of groundwater from the southern Mediterranean coastal aquifer (Israel) and the Gaza Strip in order to elucidate the origin of salinity and boron contamination. The original salinity in the eastern part of the aquifer is derived from discharge of saline groundwater from the adjacent Avedat aquitard (Na/Cl < 1, 87Sr/86Sr ˜ 0.7079, and δ11B ˜ 40‰). As the groundwater flows to the central part of the aquifer, a dramatic change in its composition occurs (Na/Cl > 1, high B/Cl, SO4/Cl, and HCO3, 87Sr/86Sr ˜ 0.7083; δ11B ˜ 48‰), although the δ18O-δ2H slope is identical to that of the Avedat aquitard. The geochemical data suggest that dissolution of pedogenic carbonate and gypsum minerals in the overlying loessial sequence generated the Ca-rich solution that triggered base exchange reactions and produced Na- and B-rich groundwater. The geochemical data show that most of the salinization process in the Gaza Strip is derived from the lateral flow of the Na-rich saline groundwater, superimposed with seawater intrusion and anthropogenic nitrate pollution. The methodology of identification of multiple salinity sources can be used to establish a long-term management plan for the Gaza Strip and can also be implemented to understand complex salinization processes in other similarly stressed coastal aquifers.

Sources of salinity and boron in the Gaza strip: Natural contaminant flow in the southern Mediterranean coastal aquifer

NASA Astrophysics Data System (ADS)

Vengosh, Avner; Kloppmann, Wolfram; Marei, Amer; Livshitz, Yakov; Gutierrez, Alexis; Banna, Mazen; Guerrot, Catherine; Pankratov, Irena; Raanan, Hadas

2005-01-01

Salinization in coastal aquifers is a global phenomenon resulting from the overexploitation of scarce water resources. The Gaza Strip is one of the most severe cases of salinization, as accelerated degradation of the water quality endangers the present and future water supply for over 1 million people. We investigate the chemical and isotopic (87Sr/86Sr, δ11B, δ18O, δ2H, and δ34SSO4) compositions of groundwater from the southern Mediterranean coastal aquifer (Israel) and the Gaza Strip in order to elucidate the origin of salinity and boron contamination. The original salinity in the eastern part of the aquifer is derived from discharge of saline groundwater from the adjacent Avedat aquitard (Na/Cl < 1, 87Sr/86Sr ~ 0.7079, and δ11B ~ 40‰). As the groundwater flows to the central part of the aquifer, a dramatic change in its composition occurs (Na/Cl > 1, high B/Cl, SO4/Cl, and HCO3, 87Sr/86Sr ~ 0.7083; δ11B ~ 48‰), although the δ18O-δ2H slope is identical to that of the Avedat aquitard. The geochemical data suggest that dissolution of pedogenic carbonate and gypsum minerals in the overlying loessial sequence generated the Ca-rich solution that triggered base exchange reactions and produced Na- and B-rich groundwater. The geochemical data show that most of the salinization process in the Gaza Strip is derived from the lateral flow of the Na-rich saline groundwater, superimposed with seawater intrusion and anthropogenic nitrate pollution. The methodology of identification of multiple salinity sources can be used to establish a long-term management plan for the Gaza Strip and can also be implemented to understand complex salinization processes in other similarly stressed coastal aquifers.

Assessing potential toxicity of chloride-affected groundwater discharging to an urban stream using juvenile freshwater mussels (Lampsilis siliquoidea).

PubMed

Roy, James W; McInnis, Rodney; Bickerton, Greg; Gillis, Patricia L

2015-11-01

Groundwater contaminants, such as chloride from road salt, pose a threat to aquatic ecosystems when and where they discharge to surface waters. Here we study the application of a laboratory toxicity bioassay to field-collected samples from contaminated groundwater discharging to an urban stream. The objectives were to assess the potential toxicity of the discharging groundwater, while also exploring the suitability of such standard tests to site groundwater. Juvenile freshwater mussels were chosen as a groundwater-appropriate (endobenthic) test organism. Groundwater was sampled from 6 sites at approximate depths of 0, 10, and 50 cm below the sediment. Concentrations of chloride and several metals were above aquatic life guidelines in some samples. Exposure (96-h) to site groundwater resulted in survival of 90-100% and 80-100% for the 0-cm and deeper samples, respectively, indicating that groundwater may pose a toxicological threat to freshwater mussels. Several samples with high chloride had a survival rate of 80%, but generally there was poor correlation between survival and individual contaminants. Parallel juvenile mussel exposures using reconstituted water and NaCl predicted survival in the natural groundwater below 50% based on chloride concentrations. This indicates some protective ability of groundwater, possibly associated with water hardness. Finally, some technical issues with performing bioassays with groundwater were noted. First, aeration of previously anoxic groundwater samples caused marked changes in water quality (especially metal concentrations). Second, calcite crystals formed on the mussel shells in samples with elevated chloride and water hardness, though with no apparent negative effects. Crown Copyright © 2015. Published by Elsevier B.V. All rights reserved.

Hydrogeologic Framework of Bedrock Units and Initial Salinity Distribution for a Simulation of Groundwater Flow for the Lake Michigan Basin

USGS Publications Warehouse

Lampe, David C.

2009-01-01

The U.S. Geological Survey is assessing groundwater availability in the Lake Michigan Basin. As part of the assessment, a variable-density groundwater-flow model is being developed to simulate the effects of groundwater use on water availability throughout the basin. The hydrogeologic framework for the Lake Michigan Basin model was developed by grouping the bedrock geology of the study area into hydrogeologic units on the basis of the functioning of each unit as an aquifer or confining layer within the basin. Available data were evaluated based on the areal extent of coverage within the study area, and procedures were established to characterize areas with sparse data coverage. Top and bottom altitudes for each hydrogeologic unit were interpolated in a geographic information system for input to the model and compared with existing maps of subsurface formations. Fourteen bedrock hydrogeologic units, making up 17 bedrock model layers, were defined, and they range in age from the Jurassic Period red beds of central Michigan to the Cambrian Period Mount Simon Sandstone. Information on groundwater salinity in the Lake Michigan Basin was compiled to create an input dataset for the variable-density groundwater-flow simulation. Data presented in this report are referred to as 'salinity data' and are reported in terms of total dissolved solids. Salinity data were not available for each hydrogeologic unit. Available datasets were assigned to a hydrogeologic unit, entered into a spatial database, and data quality was visually evaluated. A geographic information system was used to interpolate salinity distributions for each hydrogeologic unit with available data. Hydrogeologic units with no available data either were set equal to neighboring units or were vertically interpolated by use of values from units above and below.

Evaporation from groundwater discharge playas, Estancia Basin, central New Mexico

USGS Publications Warehouse

Menking, Kirsten M.; Anderson, Roger Y.; Brunsell, Nathaniel A.; Allen, Bruce D.; Ellwein, Amy L.; Loveland, Thomas A.; Hostetler, Steven W.

2000-01-01

Bowen ratio meteorological stations have been deployed to measure rates of evaporation from groundwater discharge playas and from an adjacent vegetated bench in the Estancia Basin, in central New Mexico. The playas are remnants of late Pleistocene pluvial Lake Estancia and are discharge areas for groundwater originating as precipitation in the adjacent Manzano Mts. They also accumulate water during local precipitation events. Evaporation is calculated from measured values of net radiation, soil heat flux, atmospheric temperature, and relative humidity. Evaporation rates are strongly dependent on the presence or absence of standing water in the playas, with rates increasing more than 600% after individual rainstorms. Evaporation at site E-12, in the southeastern part of the playa Complex, measured 74 cm over a yearlong period from mid-1997 through mid-1998. This value compares favorably to earlier estimates from northern Estancia playas, but is nearly three times greater than evaporation at a similar playa in western Utah. Differences in geographical position, salt crust composition, and physical properties may explain some of the difference in evaporation rates in these two geographic regions.

Calculating discharge of phosphorus and nitrogen with groundwater base flow to a small urban stream reach

NASA Astrophysics Data System (ADS)

Fitzgerald, Alex; Roy, James W.; Smith, James E.

2015-09-01

Elevated levels of nutrients, especially phosphorus, in urban streams can lead to eutrophication and general degradation of stream water quality. Contributions of phosphorus from groundwater have typically been assumed minor, though elevated concentrations have been associated with riparian areas and urban settings. The objective of this study was to investigate the importance of groundwater as a pathway for phosphorus and nitrogen input to a gaining urban stream. The stream at the 28-m study reach was 3-5 m wide and straight, flowing generally eastward, with a relatively smooth bottom of predominantly sand, with some areas of finer sediments and a few boulders. Temperature-based methods were used to estimate the groundwater flux distribution. Detailed concentration distributions in discharging groundwater were mapped using in-stream piezometers and diffusion-based peepers, and showed elevated levels of soluble reactive phosphorus (SRP) and ammonium compared to the stream (while nitrate levels were lower), especially along the south bank, where groundwater fluxes were lower and geochemically reducing conditions dominated. Field evidence suggests the ammonium may originate from nearby landfills, but that local sediments likely contribute the SRP. Ammonium and SRP mass discharges with groundwater were then estimated as the product of the respective concentration distributions and the groundwater flux distribution. These were determined as approximately 9 and 200 g d-1 for SRP and ammonium, respectively, which compares to stream mass discharges over the observed range of base flows of 20-1100 and 270-7600 g d-1, respectively. This suggests that groundwater from this small reach, and any similar areas along Dyment's Creek, has the potential to contribute substantially to the stream nutrient concentrations.

A GIS COST MODEL TO ASSESS THE AVAILABILITY OF FRESHWATER, SEAWATER, AND SALINE GROUNDWATER FOR ALGAL BIOFUEL PRODUCTION IN THE UNITED STATES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Venteris, Erik R.; Skaggs, Richard; Coleman, Andre M.

2013-03-15

A key advantage of using microalgae for biofuel production is the ability of some algal strains to thrive in waters unsuitable for conventional crop irrigation such as saline groundwater or seawater. Nonetheless, the availability of sustainable water supplies will provide significant challenges for scale-up and development of algal biofuels. We conduct a limited techno-economic assessment based on the availability of freshwater, saline groundwater, and seawater for use in open pond algae cultivation systems. We explore water issues through GIS-based models of algae biofuel production, freshwater supply, and cost models for supplying seawater and saline groundwater. We estimate that combined, withinmore » the coterminous US these resources can support production on the order of 9.46E+7 m3 yr-1 (25 billion gallons yr-1) of renewable biodiesel. Achievement of larger targets requires the utilization of less water efficient sites and relatively expensive saline waters. Geographically, water availability is most favorable for the coast of the Gulf of Mexico and Florida peninsula, where evaporation relative to precipitation is moderate and various saline waters are economically available. As a whole, barren and scrub lands of the southwestern US have limited freshwater supplies so accurate assessment of alternative waters is critical.« less

Significance of groundwater flux on contaminant concentration and mass discharge in the nonaqueous phase liquid (NAPL) contaminated zone.

PubMed

Zhu, Jianting; Sun, Dongmin

2016-09-01

Groundwater flowing through residual nonaqueous phase liquid (NAPL) source zone will cause NAPL dissolution and generate large contaminant plume. The use of contaminant mass discharge (CMD) measurements in addition to NAPL aqueous phase concentration to characterize site conditions and assess remediation performance is becoming popular. In this study, we developed new and generic numerical models to investigate the significance of groundwater flux temporal variations on the NAPL source dynamics. The developed models can accommodate any temporal variations of groundwater flux in the source zone. We examined the various features of groundwater flux using a few selected functional forms of linear increase/decrease, gradual smooth increase/decrease, and periodic fluctuations with a general trend. Groundwater flux temporal variations have more pronounced effects on the contaminant mass discharge dynamics than the aqueous concentration. If the groundwater flux initially increases, then the reduction in contaminant mass discharge (CMDR) vs. NAPL mass reduction (MR) relationship is mainly downward concave. If the groundwater flux initially decreases, then CMDR vs. MR relationship is mainly upward convex. If the groundwater flux variations are periodic, the CMDR vs. MR relationship tends to also have periodic variations ranging from upward convex to downward concave. Eventually, however, the CMDR vs. MR relationship approaches 1:1 when majority of the NAPL mass becomes depleted. Copyright © 2016 Elsevier B.V. All rights reserved.

Estimates of ground-water discharge as determined from measurements of evapotranspiration, Ash Meadows area, Nye County, Nevada

USGS Publications Warehouse

Laczniak, R.J.; DeMeo, G.A.; Reiner, S.R.; Smith, J. LaRue; Nylund, W.E.

1999-01-01

Ash Meadows is one of the major discharge areas within the regional Death Valley ground-water flow system of southern Nevada and adjacent California. Ground water discharging at Ash Meadows is replenished from inflow derived from an extensive recharge area that includes the eastern part of the Nevada Test Site (NTS). Currently, contaminants introduced into the subsurface by past nuclear testing at NTS are the subject of study by the U.S. Department of Energy's Environmental Restoration Program. The transport of any contaminant in contact with ground water is controlled in part by the rate and direction of ground-water flow, which itself depends on the location and quantity of ground water discharging from the flow system. To best evaluate any potential risk associated with these test-generated contaminants, studies were undertaken to accurately quantify discharge from areas downgradient from the NTS. This report presents results of a study to refine the estimate of ground-water discharge at Ash Meadows. The study estimates ground-water discharge from the Ash Meadows area through a rigorous quantification of evapotranspiration (ET). To accomplish this objective, the study identifies areas of ongoing ground-water ET, delineates unique areas of ET defined on the basis of similarities in vegetation and soil-moisture conditions, and computes ET rates for each of the delineated areas. A classification technique using spectral-reflectance characteristics determined from satellite images recorded in 1992 identified seven unique units representing areas of ground-water ET. The total area classified encompasses about 10,350 acres dominated primarily by lush desert vegetation. Each unique area, referred to as an ET unit, generally consists of one or more assemblages of local phreatophytes. The ET units identified range from sparse grasslands to open water. Annual ET rates are computed by energy-budget methods from micrometeorological measurements made at 10 sites within six

Revisiting analytical solutions for steady interface flow in subsea aquifers: Aquitard salinity effects

NASA Astrophysics Data System (ADS)

Werner, Adrian D.; Robinson, Neville I.

2018-06-01

Existing analytical solutions for the distribution of fresh groundwater in subsea aquifers presume that the overlying offshore aquitard, represented implicitly, contains seawater. Here, we consider the case where offshore fresh groundwater is the result of freshwater discharge from onshore aquifers, and neglect paleo-freshwater sources. A recent numerical modeling investigation, involving explicit simulation of the offshore aquitard, demonstrates that offshore aquitards more likely contain freshwater in areas of upward freshwater leakage to the sea. We integrate this finding into the existing analytical solutions by providing an alternative formulation for steady interface flow in subsea aquifers, whereby the salinity in the offshore aquitard can be chosen. The new solution, taking the aquitard salinity as that of freshwater, provides a closer match to numerical modeling results in which the aquitard is represented explicitly.

A GIS cost model to assess the availability of freshwater, seawater, and saline groundwater for algal biofuel production in the United States.

PubMed

Venteris, Erik R; Skaggs, Richard L; Coleman, Andre M; Wigmosta, Mark S

2013-05-07

A key advantage of using microalgae for biofuel production is the ability of some algal strains to thrive in waters unsuitable for conventional crop irrigation such as saline groundwater or seawater. Nonetheless, the availability of sustainable water supplies will provide significant challenges for scale-up and development of algal biofuels. We conduct a partial techno-economic assessment based on the availability of freshwater, saline groundwater, and seawater for use in open pond algae cultivation systems. We explore water issues through GIS-based models of algae biofuel production, freshwater supply (constrained to less than 5% of mean annual flow per watershed) and costs, and cost-distance models for supplying seawater and saline groundwater. We estimate that, combined, these resources can support 9.46 × 10(7) m(3) yr(-1) (25 billion gallons yr(-1)) of renewable biodiesel production in the coterminous United States. Achievement of larger targets requires the utilization of less water efficient sites and relatively expensive saline waters. Despite the addition of freshwater supply constraints and saline water resources, the geographic conclusions are similar to our previous results. Freshwater availability and saline water delivery costs are most favorable for the coast of the Gulf of Mexico and Florida peninsula, where evaporation relative to precipitation is moderate. As a whole, the barren and scrub lands of the southwestern U.S. have limited freshwater supplies, and large net evaporation rates greatly increase the cost of saline alternatives due to the added makeup water required to maintain pond salinity. However, this and similar analyses are particularly sensitive to knowledge gaps in algae growth/lipid production performance and the proportion of freshwater resources available, key topics for future investigation.

Temporal variation in stable isotopes ( 18O and 2H) and major ion concentrations within the Darling River between Bourke and Wilcannia due to variable flows, saline groundwater influx and evaporation

NASA Astrophysics Data System (ADS)

Meredith, K. T.; Hollins, S. E.; Hughes, C. E.; Cendón, D. I.; Hankin, S.; Stone, D. J. M.

2009-11-01

detrimental impacts on the surface water system by providing a pathway for saline groundwaters to discharge into the river system. Persistent drought and continued over-abstraction of surface waters will lead to further saline groundwater intrusion along this reach of the river. This work shows that a suite of hydrochemical and isotopic tracers are needed on spatially and temporally significant scales to unravel the hydrological complexities of dryland river systems such as the Darling River.

Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah

USGS Publications Warehouse

Naftz, D.L.; Bullen, T.D.; Stolp, B.J.; Wilkowske, C.D.

2008-01-01

Stream discharge and geochemical data were collected at two sites along lower Ashley Creek, Utah, from 1999 to 2003, to assess the success of a site specific salinity and Se remediation project. The remediation project involved the replacement of a leaking sewage lagoon system that was interacting with Mancos Shale and increasing the dissolved salinity and Se load in Ashley Creek. Regression modeling successfully simulated the mean daily dissolved salinity and Se loads (R2 values ranging from 0.82 to 0.97) at both the upstream (AC1) and downstream (AC2/AC2A) sites during the study period. Prior to lagoon closure, net gain in dissolved-salinity load exceeded 2177??metric tons/month and decreased after remediation to less than 590??metric tons/month. The net gain in dissolved Se load during the same pre-closure period exceeded 120??kg/month and decreased to less than 18??kg/month. Sen's slope estimator verified the statistical significance of the modeled reduction in monthly salinity and Se loads. Measured gain in dissolved constituent loads during seepage tests conducted during September and November 2003 ranged from 0.334 to 0.362??kg/day for dissolved Se and 16.9 to 26.1??metric tons/day for dissolved salinity. Stream discharge and changes in the isotopic values of delta boron-11 (??11B) were used in a mixing model to differentiate between constituent loadings contributed by residual sewage effluent and naturally occurring ground-water seepage entering Ashley Creek. The majority of the modeled ??11B values of ground-water seepage were positive, indicative of minimal seepage contributions from sewage effluent. The stream reach between sites S3 and AC2A contained a modeled ground-water seepage ??11B value of - 2.4???, indicative of ground-water seepage composed of remnant water still draining from the abandoned sewage lagoons.

Evaluation of groundwater discharge into small lakes based on the temporal distribution of radon-222

USGS Publications Warehouse

Dimova, N.T.; Burnett, W.C.

2011-01-01

In order to evaluate groundwater discharge into small lakes we constructed a model that is based on the budget of 222Rn (radon t1/2 5 3.8 d) as a tracer. The main assumptions in our model are that the lake's waters are wellmixed horizontally and vertically; the only significant 222Rn source is via groundwater discharge; and the only losses are due to decay and atmospheric evasion. In order to evaluate the groundwater-derived 222Rn flux, we monitored the 222Rn concentration in lake water over periods long enough (usually 1-3 d) to observe changes likely caused by variations in atmospheric exchange (primarily a function of wind speed and temperature). We then attempt to reproduce the observed record by accounting for decay and atmospheric losses and by estimating the total 222Rn input flux using an iterative approach. Our methodology was tested in two lakes in central Florida: one of which is thought to have significant groundwater inputs (Lake Haines) and another that is known not to have any groundwater inflows but requires daily groundwater augmentation from a deep aquifer (Round Lake). Model results were consistent with independent seepage meter data at both Lake Haines (positive seepage of ??? 1.6 ?? 104 m3 d-1 in Mar 2008) and at Round Lake (no net groundwater seepage). ?? 2011, by the American Society of Limnology and Oceanography, Inc.

Impact of hydrological alterations on river-groundwater exchange and water quality in a semi-arid area: Nueces River, Texas.

PubMed

Murgulet, Dorina; Murgulet, Valeriu; Spalt, Nicholas; Douglas, Audrey; Hay, Richard G

2016-12-01

There is a lack of understanding and methods for assessing the effects of anthropogenic disruptions, (i.e. river fragmentation due to dam construction) on the extent and degree of groundwater-surface water interaction and geochemical processes affecting the quality of water in semi-arid, coastal catchments. This study applied a novel combination of electrical resistivity tomography (ERT) and elemental and isotope geochemistry in a coastal river disturbed by extended drought and periodic flooding due to the operation of multiple dams. Geochemical analyses show that the saltwater barrier causes an increase in salinity in surface water in the downstream river as a result of limited freshwater inflows, strong evaporation effects on shallow groundwater and mostly stagnant river water, and is not due to saltwater intrusion by tidal flooding. Discharge from bank storage is dominant (~84%) in the downstream fragment and its contribution could increase salinity levels within the hyporheic zone and surface water. When surface water levels go up due to upstream freshwater releases the river temporarily displaces high salinity water trapped in the hyporheic zone to the underlying aquifer. Geochemical modeling shows a higher contribution of distant and deeper groundwater (~40%) in the upstream river and lower discharge from bank storage (~13%) through the hyporheic zone. Recharge from bank storage is a source of high salt to both upstream and downstream portions of the river but its contribution is higher below the dam. Continuous ERT imaging of the river bed complements geochemistry findings and indicate that while lithologically similar, downstream of the dam, the shallow aquifer is affected by salinization while fresher water saturates the aquifer in the upstream fragment. The relative contribution of flows (i.e. surface water releases or groundwater discharge) as related to the river fragmentation control changes of streamwater chemistry and likely impact the interpretation

Water quality impacts from on-site waste disposal systems to coastal areas through groundwater discharge

NASA Astrophysics Data System (ADS)

Harris, P. J.

1995-12-01

This report summarizes research studies linking on-site waste disposal systems (OSDS) to pathogen and nutrient concentrations in groundwater with the potential to impact coastal embayments. Few studies connect OSDS to coastal water quality. Most studies examined pathogen and nutrient impacts to groundwater and omitted estimations of contaminants discharged to surface water. The majority of studies focused on nitrogen, with little information on pathogens and even less on phosphorus. Nitrogen discharged from OSDS poses the greatest threat to water quality. Vertical distance of septic tank infiltration system from the water table, septic system design, and siting remain the key components in minimizing potential impacts from OSDS for control of both pathogens and nutrients. The most comprehensive information connecting nutrient contributions from OSDS to surface water quality was the study conducted on Buttermilk Bay in Massachusetts where 74% of nitrogen to the bay was attributed to onsite disposal systems. In conclusion, further studies on the viability and transport of pathogens and nutrients through the groundwater aquifer and across the groundwater/surface-water interface are needed. Additional research on the importance of septic system design on the availability of contaminants to groundwater as well as the minimum distance between the septic system and water table necessary to protect groundwater are also indicated.

Understanding the hydrologic impacts of wastewater treatment plant discharge to shallow groundwater: Before and after plant shutdown

USGS Publications Warehouse

Hubbard, Laura E.; Keefe, Steffanie H.; Kolpin, Dana W.; Barber, Larry B.; Duris, Joseph W.; Hutchinson, Kasey J.; Bradley, Paul M.

2016-01-01

Effluent-impacted surface water has the potential to transport not only water, but wastewater-derived contaminants to shallow groundwater systems. To better understand the effects of effluent discharge on in-stream and near-stream hydrologic conditions in wastewater-impacted systems, water-level changes were monitored in hyporheic-zone and shallow-groundwater piezometers in a reach of Fourmile Creek adjacent to and downstream of the Ankeny (Iowa, USA) wastewater treatment plant (WWTP). Water-level changes were monitored from approximately 1.5 months before to 0.5 months after WWTP closure. Diurnal patterns in WWTP discharge were closely mirrored in stream and shallow-groundwater levels immediately upstream and up to 3 km downstream of the outfall, indicating that such discharge was the primary control on water levels before shutdown. The hydrologic response to WWTP shutdown was immediately observed throughout the study reach, verifying the far-reaching hydraulic connectivity and associated contaminant transport risk. The movement of WWTP effluent into alluvial aquifers has implications for potential WWTP-derived contamination of shallow groundwater far removed from the WWTP outfall.

Environmental and Groundwater Controls on Evaporation Rates of A Shallow Saline Lake in the Western Sandhills Nebraska, USA

NASA Astrophysics Data System (ADS)

Peake, C.; Riveros-Iregui, D.; Lenters, J. D.; Zlotnik, V. A.; Ong, J.

2013-12-01

The western Sand Hills of Nebraska exhibit many shallow saline lakes that actively mediate groundwater-lake-atmospheric exchanges. The region is home to the largest stabilized dune field in the western hemisphere. Most of the lakes in the western Sand Hills region are saline and support a wide range of ecosystems. However, they are also highly sensitive to variability in evaporative and groundwater fluxes, which makes them a good laboratory to examine the effects of climate on the water balance of interdunal lakes. Despite being semiarid, little is known about the importance of groundwater-surface water interactions on evaporative rates, or the effects of changes in meteorological and energy forcings on the diel, and seasonal dynamics of evaporative fluxes. Our study is the first to estimate evaporation rates from one of the hundreds of shallow saline lakes that occur in the western Sand Hills region. We applied the energy balance Bowen ratio method at Alkali Lake, a typical saline western Sand Hills lake, over a three-year period (2007-2009) to quantify summer evaporation rates. Daily evaporation rates averaged 5.5 mm/day from July through September and were largely controlled by solar radiation on a seasonal and diel scales. Furthermore, the range of annual variability of evaporation rates was low. Although less pronounced, groundwater level effects on evaporation rates were also observed, especially from August through October when solar radiation was lower. The lake exhibits significant fluctuation in lake levels and combined with a shallow lake bed, large changes in lake surface area are observed. Our findings also show that with the onset of summer conditions, lake surface area can change very rapidly (e.g. 24% of its surface area or ~16.6 hectares were lost in less than ~2 months). In every year summer evaporation exceeded annual rainfall by an average of 28.2% suggesting that groundwater is a significant component of the lake water balance, it is important

Salinization of groundwater in arid and semi-arid zones: an example from Tajarak, western Iran

NASA Astrophysics Data System (ADS)

Jalali, Mohsen

2007-06-01

Study of the groundwater samples from Tajarak area, western Iran, was carried out in order to assess their chemical compositions and suitability for agricultural purposes. All of the groundwaters are grouped into two categories: relatively low mineralized of Ca-HCO3 and Na-HCO3 types and high mineralized waters of Na-SO4 and Na-Cl types. The chemical evolution of groundwater is primarily controlled by water-rock interactions mainly weathering of aluminosilicates, dissolution of carbonate minerals and cation exchange reactions. Calculated values of pCO2 for the groundwater samples range from 2.34 × 10-4 to 1.07 × 10-1 with a mean value of 1.41 × 10-2 (atm), which is above the pCO2 of the earth’s atmosphere (10-3.5). The groundwater is oversaturated with respect to calcite, aragonite and dolomite and undersaturated with respect to gypsum, anhydrite and halite. According to the EC and SAR the most dominant classes (C3-S1, C4-S1 and C4-S2) were found. With respect to adjusted SAR (adj SAR), the sodium (Na+) content in 90% of water samples in group A is regarded as low and can be used for irrigation in almost all soils with little danger of the development of harmful levels of exchangeable Na+, while in 40 and 37% of water samples in group B the intensity of problem is moderate and high, respectively. Such water, when used for irrigation will lead to cation exchange and Na+ is adsorbed on clay minerals while calcium (Ca2+) and magnesium (Mg2+) are released to the liquid phase. The salinity hazard is regarded as medium to high and special management for salinity control is required. Thus, the water quality for irrigation is low, providing the necessary drainage to avoid the build-up of toxic salt concentrations.

Factors controlling groundwater salinization and hydrogeochemical processes in coastal aquifers from southern Spain.

PubMed

Argamasilla, M; Barberá, J A; Andreo, B

2017-02-15

In detrital coastal aquifers, seawater and surface water may interact with groundwater in multiple ways. Understanding the interference of water fluxes in this type of environment is essential to effectively manage the groundwater resources in water-stressed regions, such as the Mediterranean coastal fringe. In this research, the characterization of the main hydrogeochemical processes and the interaction between surface water and groundwater in the Marbella-Estepona coastal aquifers (southern Spain) have been carried out by means of the combined use of different hydrogeochemical indicators along with isotope data. The results show that the diversity of source lithologies (peridotite, carbonate and/or metapelitic) substantially conditions the groundwater geochemistry. The analysis of ionic deltas made it possible a preliminary screening of the geochemical reactions that occur in the Marbella-Estepona aquifers, while the Discriminant Analysis allowed for a consistent classification of sampled groundwater types. The dissolution of calcite and dolomite determines the chemical composition of the groundwater from the eastern sector that are more conditioned by the rainwater infiltration. The dissolution of magnesium-bearing minerals (predominantly forming peridotite rocks) is observed in groundwater samples from the western and central sectors, whose chemical composition showed a greater influence of surface water. The spatial analysis of rCl - /Br - in groundwater has permitted to corroborate that saline intrusion is negligible, hardly affecting to its original water quality. The irregularly distributed recharge by precipitation (seasonal effect) and the atmospheric circulation of cloud fronts (coastal/continental effect) explains why most of groundwater sampled is isotopically impoverished with respect to the rainfall signature. The isotope approach also suggests the hydraulic relationship between surface water and groundwater in the study site. A deeper knowledge of

Continental patterns of submarine groundwater discharge reveal coastal vulnerabilities.

PubMed

Sawyer, Audrey H; David, Cédric H; Famiglietti, James S

2016-08-12

Submarine groundwater discharge (SGD) delivers water and dissolved chemicals from continents to oceans, and its spatial distribution affects coastal water quality. Unlike rivers, SGD is broadly distributed and relatively difficult to measure, especially at continental scales. We present spatially resolved estimates of fresh (land-derived) SGD for the contiguous United States based on historical climate records and high-resolution hydrographic data. Climate controls regional patterns in fresh SGD, while coastal drainage geometry imparts strong local variability. Because the recharge zones that contribute fresh SGD are densely populated, the quality and quantity of fresh SGD are both vulnerable to anthropogenic disturbance. Our analysis unveils hot spots for contaminant discharge to marine waters and saltwater intrusion into coastal aquifers. Copyright © 2016, American Association for the Advancement of Science.

Origin and characteristics of discharge at San Marcos Springs, south-central Texas

USGS Publications Warehouse

Musgrove, MaryLynn; Crow, Cassi L.

2013-01-01

Weissmuller Spring. Also, San Marcos Springs discharge is influenced by mixing with a component of saline groundwater.

Effects of Submarine Groundwater Discharge (SGD) on the Growth of the Lobe Coral Porites lobata in Maunalua Bay, Hawaii.

NASA Astrophysics Data System (ADS)

Lubarsky, K.

2016-02-01

Submarine groundwater discharge (SGD) constitutes a large percentage of the freshwater inputs onto coastal coral reefs on high islands such as the Hawaiian Islands, although the impact of SGD on coral reef health is currently understudied. In Maunalua Bay, on Oahu, Hawaii, SGD is discharged onto shallow reef flats from discrete seeps, creating natural gradients of water chemistry across the reef flat. We used this system to investigate rates of growth of the lobe coral Porites lobata across a gradient of SGD influence at two study sites within the bay, and to characterize the variation in water chemistry gradient over space and time due to SGD. SGD input at these sites is tidally modulated, and the groundwater itself is brackish and extremely nutrient-rich (mean=190 μM NO3- at the Black Point study site, mean=40 μM NO3- at Wailupe Beach Park), with distinct carbonate signatures at both study sites. Coral nubbins were placed across the gradient for 6 months, and growth was measured using three metrics: surface area (photo analysis), buoyant weight, and linear extension. Various chemical parameters, including pH, salinity, total alkalinity, nutrients, and chlorphyll were sampled at the same locations across the gradient over 24 hour periods in the spring and fall in order to capture spatial and temporal variation in water chemistry due to the SGD plume. Spatial patterns and temporal variation in water chemistry were correlated with the observed spatial patterns in coral growth across the SGD gradient.

Using an autonomous Wave Glider to detect seawater anomalies related to submarine groundwater discharge - engineering challenge

NASA Astrophysics Data System (ADS)

Leibold, P.; Brueckmann, W.; Schmidt, M.; Balushi, H. A.; Abri, O. A.

2017-12-01

Coastal aquifer systems are amongst the most precious and vulnerable water resources worldwide. While differing in lateral and vertical extent they commonly show a complex interaction with the marine realm. Excessive groundwater extraction can cause saltwater intrusion from the sea into the aquifers, having a strongly negative impact on the groundwater quality. While the reverse pathway, the discharge of groundwater into the sea is well understood in principle, it's mechanisms and quantities not well constrained. We will present a project that combines onshore monitoring and modeling of groundwater in the coastal plain of Salalah, Oman with an offshore autonomous robotic monitoring system, the Liquid Robotics Wave Glider. Eventually, fluxes detected by the Wave Glider system and the onshore monitoring of groundwater will be combined into a 3-D flow model of the coastal and deeper aquifers. The main tool for offshore SGD investigation project is a Wave Glider, an autonomous vehicle based on a new propulsion technology. The Wave Glider is a low-cost satellite-connected marine craft, consisting of a combination of a sea-surface and an underwater component which is propelled by the conversion of ocean wave energy into forward thrust. While the wave energy propulsion system is purely mechanical, electrical energy for onboard computers, communication and sensors is provided by photovoltaic cells. For the project the SGD Wave Glider is being equipped with dedicated sensors to measure temperature, conductivity, Radon isotope (222Rn, 220Rn) activity concentration as well as other tracers of groundwater discharge. Dedicated software using this data input will eventually allow the Wave Glider to autonomously collect information and actively adapt its search pattern to hunt for spatial and temporal anomalies. Our presentation will focus on the engineering and operational challenges ofdetecting submarine groundwater discharges with the Wave Glider system in the Bay of Salalah

Temporal 222Rn distributions to reveal groundwater discharge into desert lakes: Implication of water balance in the Badain Jaran Desert, China

NASA Astrophysics Data System (ADS)

Luo, Xin; Jiao, Jiu Jimmy; Wang, Xu-sheng; Liu, Kun

2016-03-01

How lake systems are maintained and water is balanced in the lake areas in the Badain Jaran Desert (BJD), northeast of China have been debated for about a decade. In this study, continuous 222Rn measurement is used to quantify groundwater discharge into two representative fresh and brine water lakes in the desert using a steady-state mass-balance model. Two empirical equations are used to calculate atmospheric evasion loss crossing the water-air interface of the lakes. Groundwater discharge rates yielded from the radon mass balance model based on the two empirical equations are well correlated and of almost the same values, confirming the validity of the model. The fresh water and brine lakes have a daily averaged groundwater discharge rate of 7.6 ± 1.7 mm d-1 and 6.4 ± 1.8 mm d-1, respectively. The temporal fluctuations of groundwater discharge show similar patterns to those of the lake water level, suggesting that the lakes are recharged from nearby groundwater. Assuming that all the lakes have the same discharge rate as the two studied lakes, total groundwater discharge into all the lakes in the desert is estimated to be 1.59 × 105 m3 d-1. A conceptual model of water balance within a desert lake catchment is proposed to characterize water behaviors within the catchment. This study sheds lights on the water balance in the BJD and is of significance in sustainable regional water resource utilization in such an ecologically fragile area.

The typological approach to submarine groundwater discharge (SGD)

USGS Publications Warehouse

Bokuniewicz, H.; Buddemeier, R.; Maxwell, B.; Smith, C.

2003-01-01

Coastal zone managers need to factor submarine groundwater discharge (SGD) in their integration. SGD provides a pathway for the transfer of freshwater, and its dissolved chemical burden, from the land to the coastal ocean. SGD reduces salinities and provides nutrients to specialized coastal habitats. It also can be a pollutant source, often undetected, causing eutrophication and triggering nuisance algal blooms. Despite its importance, SGD remains somewhat of a mystery in most places because it is usually unseen and difficult to measure. SGD has been directly measured at only about a hundred sites worldwide. A typology generated by the Land-Ocean Interaction in the Coastal Zone (LOICZ) Project is one of the few tools globally available to coastal resource managers for identifying areas in their jurisdiction where SGD may be a confounding process. (LOICZ is a core project of the International Geosphere/Biosphere Programme.) Of the hundreds of globally distributed parameters in the LOICZ typology, a SGD subset of potentially relevant parameters may be culled. A quantitative combination of the relevant hydrological parameters can serve as a proxy for the SGD conditions not directly measured. Web-LOICZ View, geospatial software then provides an automated approach to clustering these data into groups of locations that have similar characteristics. It permits selection of variables, of the number of clusters desired, and of the clustering criteria, and provides means of testing predictive results against independent variables. Information on the occurrence of a variety of SGD indicators can then be incorporated into regional clustering analysis. With such tools, coastal managers can focus attention on the most likely sites of SGD in their jurisdiction and design the necessary measurement and modeling programs needed for integrated management.

Numerical study of groundwater flow cycling controlled by seawater/freshwater interaction in a coastal karst aquifer through conduit network using CFPv2

NASA Astrophysics Data System (ADS)

Xu, Zexuan; Hu, Bill X.; Davis, Hal; Kish, Stephen

2015-11-01

In this study, a groundwater flow cycling in a karst springshed and an interaction between two springs, Spring Creek Springs and Wakulla Springs, through a subground conduit network are numerically simulated using CFPv2, the latest research version of MODFLOW-CFP (Conduit Flow Process). The Spring Creek Springs and Wakulla Springs, located in a marine estuary and 11 miles inland, respectively, are two major groundwater discharge spots in the Woodville Karst Plain (WKP), North Florida, USA. A three-phase conceptual model of groundwater flow cycling between the two springs and surface water recharge from a major surface creek (Lost Creek) was proposed in various rainfall conditions. A high permeable subground karst conduit network connecting the two springs was found by tracer tests and cave diving. Flow rate of discharge, salinity, sea level and tide height at Spring Creek Springs could significantly affect groundwater discharge and water stage at Wakulla Springs simultaneously. Based on the conceptual model, a numerical hybrid discrete-continuum groundwater flow model is developed using CFPv2 and calibrated by field measurements. Non-laminar flows in conduits and flow exchange between conduits and porous medium are implemented in the hybrid coupling numerical model. Time-variable salinity and equivalent freshwater head boundary conditions at the submarine spring as well as changing recharges have significant impacts on seawater/freshwater interaction and springs' discharges. The developed numerical model is used to simulate the dynamic hydrological process and quantitatively represent the three-phase conceptual model from June 2007 to June 2010. Simulated results of two springs' discharges match reasonably well to measurements with correlation coefficients 0.891 and 0.866 at Spring Creeks Springs and Wakulla Springs, respectively. The impacts of sea level rise on regional groundwater flow field and relationship between the inland springs and submarine springs are

Long-term changes in pond permanence, size, and salinity in Prairie Pothole Region wetlands: The role of groundwater-pond interaction

USGS Publications Warehouse

LaBaugh, James W.; Rosenberry, Donald O.; Mushet, David M.; Neff, Brian; Nelson, Richard D.; Euliss, Ned H.

2018-01-01

Study RegionCottonwood Lake area wetlands, North Dakota, U.S.A.Study FocusFluctuations in pond permanence, size, and salinity are key features of prairie-pothole wetlands that provide a variety of wetland habitats for waterfowl in the northern prairie of North America. Observation of water-level and salinity fluctuations in a semi-permanent wetland pond over a 20-year period, included periods when the wetland occasionally was dry, as well as wetter years when the pond depth and surface extent doubled while volume increased 10 times.New hydrological insights for the study regionCompared to all other measured budget components, groundwater flow into the pond often contributed the least water (8–28 percent) but the largest amount (>90 percent) of specific solutes to the water and solute budgets of the pond. In drier years flow from the pond into groundwater represented > 10 percent of water loss, and in 1992 was approximately equal to evapotranspiration loss. Also during the drier years, export of calcium, magnesium, sodium, potassium, chloride, and sulfate by flow from the pond to groundwater was substantial compared with previous or subsequent years, a process that would have been undetected if groundwater flux had been calculated as a net value. Independent quantification of water and solute gains and losses were essential to understand controls on water-level and salinity fluctuations in the pond in response to variable climate conditions.

Origin and mechanisms of high salinity in Hombolo Dam and groundwater in Dodoma municipality Tanzania, revealed

NASA Astrophysics Data System (ADS)

Shemsanga, Ceven; Muzuka, Alfred Nzibavuga Nyarubakula; Martz, Lawrance; Komakech, Hans Charles; Elisante, Eliapenda; Kisaka, Marry; Ntuza, Cosmas

2017-10-01

The Hombolo dam (HD), in central Tanzania, is a shallow reservoir characterized by high salinity that limits its use for human activities. The origin of the salinity, mechanisms of reaching and concentrating in the dam remain unclear. These were assessed using hydrogeochemical facies, water type evolutions and mapping. The source of HD salinity was identified to be shallow groundwater (SG) and runoff from a seasonal floodplain with NaCl-rich lithological materails, along Little Kinyasungwe River that feeds the dam. The NaCl-rich lithological units, about 5-7 km upstream of the dam, were highly concentrated with NaCl to the extent that the local community was commercially separating table salt from them. The physicochemical parameters from these NaCl-rich lithological materials were well represented in HD and nearby groundwater sources, which suggests active water interactions. Water type evolution and surface hydrology assessments clearly showed that SG in the salty-floodplain was influenced by evaporation (ET) and was periodically carried to the HD. Clearly; HD water had high chemical similarity with the nearby SG. This agrees with previous studies that HD is partly fed by the local aquifer. However, this is the first attempt at mapping its physical origin. The origin of HD salinity was further supported by the spatial distribution of electrical conductivity (EC), where very high EC (up to 21,230 μScm-1) was recorded in SG within the NaCl-rich lithological unit while water sources far away from the NaCl-rich materials had much lower EC values. Thus, the study disagrees with previous conclusions that HD salinity was sorely due to high dam surface ET but is primarily due to geological reasons. Comparisons of HD with a nearby Matumbulu dam (MD), another earthen dam in climatologically similar settings, reveals that MD water was less saline/mineralised. This further shows that HD high salinity is most likely a geologic phenomenon, but local climatic factors, namely

Catchment tracers reveal discharge, recharge and sources of groundwater-borne pollutants in a novel lake modelling approach

NASA Astrophysics Data System (ADS)

Kristensen, Emil; Madsen-Østerbye, Mikkel; Massicotte, Philippe; Pedersen, Ole; Markager, Stiig; Kragh, Theis

2018-02-01

Groundwater-borne contaminants such as nutrients, dissolved organic carbon (DOC), coloured dissolved organic matter (CDOM) and pesticides can have an impact the biological quality of lakes. The sources of pollutants can, however, be difficult to identify due to high heterogeneity in groundwater flow patterns. This study presents a novel approach for fast hydrological surveys of small groundwater-fed lakes using multiple groundwater-borne tracers. Water samples were collected from the lake and temporary groundwater wells, installed every 50 m within a distance of 5-45 m to the shore, were analysed for tracer concentrations of CDOM, DOC, total dissolved nitrogen (TDN, groundwater only), total nitrogen (TN, lake only), total dissolved phosphorus (TDP, groundwater only), total phosphorus (TP, lake only), δ18O / δ16O isotope ratios and fluorescent dissolved organic matter (FDOM) components derived from parallel factor analysis (PARAFAC). The isolation of groundwater recharge areas was based on δ18O measurements and areas with a high groundwater recharge rate were identified using a microbially influenced FDOM component. Groundwater discharge sites and the fractions of water delivered from the individual sites were isolated with the Community Assembly via Trait Selection model (CATS). The CATS model utilized tracer measurements of TDP, TDN, DOC and CDOM from the groundwater samples and related these to the tracer measurements of TN, TP, DOC and CDOM in the lake. A direct comparison between the lake and the inflowing groundwater was possible as degradation rates of the tracers in the lake were taken into account and related to a range of water retention times (WRTs) of the lake (0.25-3.5 years in 0.25-year increments). These estimations showed that WRTs above 2 years required a higher tracer concentration of inflowing water than found in any of the groundwater wells around the lake. From the estimations of inflowing tracer concentration, the CATS model isolated

Tracking groundwater discharge to a large river using tracers and geophysics.

PubMed

Harrington, Glenn A; Gardner, W Payton; Munday, Tim J

2014-01-01

Few studies have investigated large reaches of rivers in which multiple sources of groundwater are responsible for maintaining baseflow. This paper builds upon previous work undertaken along the Fitzroy River, one of the largest perennial river systems in north-western Australia. Synoptic regional-scale sampling of both river water and groundwater for a suite of environmental tracers ((4) He, (87) Sr/(86) Sr, (222) Rn and major ions), and subsequent modeling of tracer behavior in the river, has enabled definition and quantification of groundwater input from at least three different sources. We show unambiguous evidence of both shallow "local" groundwater, possibly recharged to alluvial aquifers beneath the adjacent floodplain during recent high-flow events, and old "regional" groundwater introduced via artesian flow from deep confined aquifers. We also invoke hyporheic exchange and either bank return flow or parafluvial flow to account for background (222) Rn activities and anomalous chloride trends along river reaches where there is no evidence of the local or regional groundwater inputs. Vertical conductivity sections acquired through an airborne electromagnetic (AEM) survey provide insights to the architecture of the aquifers associated with these sources and general groundwater quality characteristics. These data indicate fresh groundwater from about 300 m below ground preferentially discharging to the river, at locations consistent with those inferred from tracer data. The results demonstrate how sampling rivers for multiple environmental tracers of different types-including stable and radioactive isotopes, dissolved gases and major ions-can significantly improve conceptualization of groundwater-surface water interaction processes, particularly when coupled with geophysical techniques in complex hydrogeological settings. © 2013, National Ground Water Association.

Hydrochemical evolution of regional groundwaters to playa brines in central Australia

NASA Astrophysics Data System (ADS)

Jankowski, J.; Jacobson, G.

A large-scale groundwater system in central Australia discharges to a chain of playas. Recharge in calcrete and fractured rock aquifers gives rise to relatively low-salinity HCO 3 Cl SO 4 groundwaters, which evolve through regional saline groundwaters, to highly saline playa brines. The hydrochemical evolution of the groundwaters follows the anionic sequence HCO 3 Cl SO 4 → ClbHCO 3SO 4 → ClSO 4HCO 3 → ClSO 4 → Cl. With increasing salinity, there is a relative increase in Na, K, Mg, Cl and SO 4; however, there is a relative decrease in HCO 3, Ca, and SiO 2 owing to the precipitation of carbonate, sulphate and silicate minerals, and the resultant brines are depleted in these ions. Significant chemical variation in the composition of playa brines is a result of complex processes of solution, evaporative concentration, precipitation and mineralogical change, including dolomitisation. Thermodynamic calculations based on the Pitzer equations have enabled a general model to be developed for these evolutionary processes in saline groundwaters up to the stage of halite saturation. At an early stage the regional groundwaters are saturated with respect to the carbonate minerals, dolomite first, then calcite. With increasing salinity, sulphate minerals begin to precipitate: saturation with respect to gypsum is attained at a chlorinity of 19‰, and saturation with respect to anhydrite is attained at 122‰. The playa brines attain saturation with respect to halite at a chlorinity of 144‰. Solute budgets based on a chloride concentration factor show that final playa brines are 178 times more concentrated than recharge groundwaters, and confirm the virtually complete loss of HCO 3, Ca and SiO 2 through precipitation. There are subtle differences in the hydrochemistry of different central Australian playa brines and also vis-à-vis playa brines described from other parts of the world. Most Australian playas have brines of the ClNa type with SO 4 and

Dissolved organic matter composition of winter flow in the Yukon River basin: Implications of permafrost thaw and increased groundwater discharge

USGS Publications Warehouse

O'Donnell, Jonathan A.; Aiken, George R.; Walvoord, Michelle Ann; Butler, Kenna D.

2012-01-01

Groundwater discharge to rivers has increased in recent decades across the circumpolar region and has been attributed to thawing permafrost in arctic and subarctic watersheds. Permafrost-driven changes in groundwater discharge will alter the flux of dissolved organic carbon (DOC) in rivers, yet little is known about the chemical composition and reactivity of dissolved organic matter (DOM) of groundwater in permafrost settings. Here, we characterize DOM composition of winter flow in 60 rivers and streams of the Yukon River basin to evaluate the biogeochemical consequences of enhanced groundwater discharge associated with permafrost thaw. DOC concentration of winter flow averaged 3.9 ± 0.5 mg C L−1, yet was highly variable across basins (ranging from 20 mg C L−1). In comparison to the summer-autumn period, DOM composition of winter flow had lower aromaticity (as indicated by specific ultraviolet absorbance at 254 nm, or SUVA254), lower hydrophobic acid content, and a higher proportion of hydrophilic compounds (HPI). Fluorescence spectroscopy and parallel factor analysis indicated enrichment of protein-like fluorophores in some, but not all, winter flow samples. The ratio of DOC to dissolved organic nitrogen, an indicator of DOM biodegradability, was positively correlated with SUVA254 and negatively correlated with the percentage of protein-like compounds. Using a simple two-pool mixing model, we evaluate possible changes in DOM during the summer-autumn period across a range of conditions reflecting possible increases in groundwater discharge. Across three watersheds, we consistently observed decreases in DOC concentration and SUVA254 and increases in HPI with increasing groundwater discharge. Spatial patterns in DOM composition of winter flow appear to reflect differences in the relative contributions of groundwater from suprapermafrost and subpermafrost aquifers across watersheds. Our findings call for more explicit consideration of DOC loss and stabilization

Utilizing multichannel electrical resistivity methods to examine the dynamics of the fresh water–seawater interface in two Hawaiian groundwater systems

USGS Publications Warehouse

Dimova, Natasha T.; Swarzenski, Peter W.; Dulaiova, Henrieta; Glenn, Craig R.

2012-01-01

Multichannel electrical resistivity (ER) measurements were conducted at two contrasting coastal sites in Hawaii to obtain new information on the spatial scales and dynamics of the fresh water–seawater interface and rates of coastal groundwater exchange. At Kiholo Bay (located on the dry, Kona side of the Big Island) and at a site in Maunalua Bay (Oahu), there is an evidence for abundant submarine groundwater discharge (SGD). However, the hydrologic and geologic controls on coastal groundwater discharge are likely to be different at these two sites. While at Kiholo Bay SGD is predominantly through lava tubes, at the Maunalua Bay site exchange occurs mostly through nearshore submarine springs. In order to calculate SGD fluxes, it is important to understand the spatial and temporal scales of coastal groundwater exchange. From ER time series data, subsurface salinity distributions were calculated using site-specific formation factors. A salinity mass balance box model was then used to calculate rates of point source (i.e., spatially discreet) and total fresh water discharge. From these data, mean SGD rates were calculated for Kiholo Bay (∼9,200 m3/d) and for the Maunalua Bay site (∼5,900 m3/d). While such results are on the same order of magnitude to geochemical tracer-derived SGD rates, the ER SGD rates provide enhanced details of coastal groundwater exchange that can enable a more cohesive whole watershed perspective.

Use of a time-domain electromagnetic method with geochemical tracers to explore the salinity anomalies in a small coastal aquifer in north-eastern Tunisia

NASA Astrophysics Data System (ADS)

Chekirbane, Anis; Tsujimura, Maki; Kawachi, Atsushi; Lachaal, Fethi; Isoda, Hiroko; Tarhouni, Jamila

2014-12-01

The study area is a small coastal plain in north-eastern Tunisia. It is drained by an ephemeral stream network and is subject to several pollutant discharges such as oilfield brine coming from a neighboring oil company and wastewater from Somâa city, located in the upstream of the plain. Furthermore, a hydraulic head near the coastal part of the aquifer is below sea level, suggesting that seawater intrusion may occur. A time-domain electromagnetic (TDEM) survey, based on 28 soundings, was conducted in Wadi Al Ayn and Daroufa plains to delineate the saline groundwater. Based on longitudinal and transversal resistivity two-dimensional pseudosections calibrated with boring data, the extent of saline water was identified. Geochemical tracers were combined with the resistivity dataset to differentiate the origin of groundwater salinization. In the upstream part of the plain, the infiltration of oilfield brine through the sandy bed of Wadi Al Ayn seems to have a considerable effect on groundwater salinization. However, in the coastal part of the aquifer, groundwater salinization is due to seawater intrusion and the saltwater is reaching an inland extent around 1.3 km from the shoreline. The contribution ratios of saline water bodies derived from the inverted chloride data vary for the oilfield brine from 1 to 13 % and for the seawater from 2 to 21 %.

Characterization of mean transit time at large springs in the Upper Colorado River Basin, USA: A tool for assessing groundwater discharge vulnerability

USGS Publications Warehouse

Solder, John; Stolp, Bernard J.; Heilweil, Victor M.; Susong, David D.

2016-01-01

Environmental tracers (noble gases, tritium, industrial gases, stable isotopes, and radio-carbon) and hydrogeology were interpreted to determine groundwater transit-time distribution and calculate mean transit time (MTT) with lumped parameter modeling at 19 large springs distributed throughout the Upper Colorado River Basin (UCRB), USA. The predictive value of the MTT to evaluate the pattern and timing of groundwater response to hydraulic stress (i.e., vulnerability) is examined by a statistical analysis of MTT, historical spring discharge records, and the Palmer Hydrological Drought Index. MTTs of the springs range from 10 to 15,000 years and 90 % of the cumulative discharge-weighted travel-time distribution falls within the range of 2−10,000 years. Historical variability in discharge was assessed as the ratio of 10–90 % flow-exceedance (R 10/90%) and ranged from 2.8 to 1.1 for select springs with available discharge data. The lag-time (i.e., delay in discharge response to drought conditions) was determined by cross-correlation analysis and ranged from 0.5 to 6 years for the same select springs. Springs with shorter MTTs (<80 years) statistically correlate with larger discharge variations and faster responses to drought, indicating MTT can be used for estimating the relative magnitude and timing of groundwater response. Results indicate that groundwater discharge to streams in the UCRB will likely respond on the order of years to climate variation and increasing groundwater withdrawals.

An integrated hydrogeochemical and isotopic approach to study groundwater Salinization in the overexploited aquifers of Indo-Gangetic Plain, a part of NCR Delhi

NASA Astrophysics Data System (ADS)

Kumari, R.

2017-12-01

roundwater resources in arid and semi-arid areas are highly vulnerable to salinity problems. Inadequate availability of surface water supply, vagaries of mansoonal rainfall and overexploitation due to population pressure and rapid landuse change induced decline in groundwater levels and salinization has been observed in many Asian cities. After green revolution, large part of Indo-Gangetic plain groundwater salinization has been reported. One such region is National Capital Region, Delhi- India's largest and the world's second largest agglomeration of people and economic hub of Northern India. The present study includes National capital territory, Delhi, Gurgaon and Faridabad. In the present study, different graphical plots, Piper plot, saturation index values (using PHREEQC), stable isotopes (δ18O and δD) and GIS is used to create the database for analysis of spatial variation in respective water quality parameters as well as to decipher the hydrogeochemical process occurring in the area. Major ions are analysed to describe the composition and distribution of salinization and dissolution/precipitation dynamics. It was observed that groundwater weathering is governed by carbonate and silicate weathering and reverse ion-exchange, however due to semi-arid climate evaporation is also playing a major role in groundwater chemistry and salinity of the area. δ18O and δD regression line of groundwater samples of the study area is below the LMWL also suggest from non-equilibrium fractionation during evaporation. Large lateral variation in chloride concentration indicates impact of evapotranspiration rate during recharge. Most of water facies are of Na-Cl. Stable isotope (δ18O and δD) analysis helps to identify evaporation and to better understand recharge processes and mixing dynamics in the study region. Limited availability of surface water supply, no pricing exists for groundwater extraction has resulted in a widespread decline in the water table and intermixing of

Challenging the distributed temperature sensing technique for estimating groundwater discharge to streams through controlled artificial point source experiment

NASA Astrophysics Data System (ADS)

Lauer, F.; Frede, H.-G.; Breuer, L.

2012-04-01

Spatially confined groundwater discharge can contribute significantly to stream discharge. Distributed fibre optic temperature sensing (DTS) of stream water has been successfully used to localize- and quantify groundwater discharge from this type "point sources" (PS) in small first-order streams. During periods when stream and groundwater temperatures differ PS appear as abrupt step in longitudinal stream water temperature distribution. Based on stream temperature observation up- and downstream of a point source and estimated or measured groundwater temperature the proportion of groundwater inflow to stream discharge can be quantified using simple mixing models. However so far this method has not been quantitatively verified, nor has a detailed uncertainty analysis of the method been conducted. The relative accuracy of this method is expected to decrease nonlinear with decreasing proportions of lateral inflow. Furthermore it depends on the temperature differences (ΔT) between groundwater and surface water and on the accuracy of temperature measurement itself. The latter could be affected by different sources of errors. For example it has been shown that a direct impact of solar radiation on fibre optic cables can lead to errors in temperature measurements in small streams due to low water depth. Considerable uncertainty might also be related to the determination of groundwater temperature through direct measurements or derived from the DTS signal. In order to directly validate the method and asses it's uncertainty we performed a set of artificial point source experiments with controlled lateral inflow rates to a natural stream. The experiments were carried out at the Vollnkirchener Bach, a small head water stream in Hessen, Germany in November and December 2011 during a low flow period. A DTS system was installed along a 1.2 km sub reach of the stream. Stream discharge was measured using a gauging flume installed directly upstream of the artificial PS. Lateral

Fresh Versus Marine Submarine Groundwater Discharge: How 222Rn Might Help Distinguish These Two Sources

NASA Astrophysics Data System (ADS)

Smith, C. G.; Cable, J. E.; Martin, J. B.; Roy, M.

2008-05-01

Pore water distributions of 222Rn (t1/2 = 3.83 d), obtained during two sampling trips 9-12 May 2005 and 6-8 May 2006, are used to determine spatial and temporal variations of fluid discharge from a seepage face located along the mainland shoreline of Indian River Lagoon, Florida. Porewater samples were collected from a 30 m transect of multi-level piezometers and analyzed for 222Rn via liquid scintillation counting; the mean of triplicate measurements was used to represent the porewater 222Rn activities. Sediment samples were collected from five vibracores (0, 10, 17.5, 20, and 30 m offshore) and emanation rates of 222Rn (sediment supported) were determined using a standard cryogenic extraction technique. A conceptual 222Rn transport model and subsequent numerical model were developed based on the vertical distribution of dissolved and sediment-supported 222Rn and applicable processes occurring along the seepage face (e.g. advection, diffusion, and nonlocal exchange). The model was solved inversely with the addition of two Monte Carlo (MC) simulations to increase the statistical reliability of three parameters: fresh groundwater seepage velocity (v), irrigation intensity (α0), and irrigation attenuation (α1). The first MC simulation ensures that the Nelder-Mead minimization algorithm converges on a global minimum of the merit function and that the parameters estimates are consistent within this global minimum. The second MC simulation provides 90% confidence intervals on the parameter estimates using the measured 222Rn activity variance. Fresh groundwater seepage velocities obtained from the model decrease linearly with distance from the shoreline; seepage velocities range between 0.6 and 42.2 cm d-1. Based on this linear relationship, the terminus of the fresh groundwater seepage is approximately 25 m offshore and total fresh groundwater discharge for the May-2005 and May-2006 sampling trips are 1.16 and 1.45 m3 d-1 m-1 of shoreline, respectively. We hypothesize

Effect of an offshore sinkhole perforation in a coastal confined aquifer on submarine groundwater discharge

USGS Publications Warehouse

Fratesi, S.E.; Leonard, V.; Sanford, W.E.

2007-01-01

In order to explore submarine groundwater discharge in the vicinity of karst features that penetrate the confining layer of an offshore, partially confined aquifer, we constructed a three-dimensional groundwater model using the SUTRA (Saturated-Unsaturated TRAnsport) variable-density groundwater flow model. We ran a parameter sensitivity analysis, testing the effects of recharge rates, permeabilities of the aquifer and confining layer, and thickness of the confining layer. In all simulations, less than 20% of the freshwater recharge for the entire model exits through the sinkhole. Recirculated seawater usually accounts for 10-30% of the total outflow from the model. Often, the sinkhole lies seaward of the transition zone and acts as a recharge feature for recirculating seawater. The permeability ratio between aquifer and confining layer influences the configuration of the freshwater wedge the most; as confining layer permeability decreases, the wedge lengthens and the fraction of total discharge exiting through the sinkhole increases. Copyright ?? 2007 IAHS Press.

Investigating the salinization and freshening processes of coastal groundwater resources in Urmia aquifer, NW Iran.

PubMed

Amiri, Vahab; Nakhaei, Mohammad; Lak, Razyeh; Kholghi, Majid

2016-04-01

This paper presents the results of an assessment about interaction between Urmia Lake (UL) and coastal groundwater in the Urmia aquifer (UA). This aquifer is the most significant contributor to the freshwater supply of the coastal areas. The use of hydrochemical facies can be very useful to identify the saltwater encroachment or freshening phases in the coastal aquifers. In this study, the analysis of salinization/freshening processes was carried out through the saturation index (SI), ionic deltas (Δ), binary diagrams, and hydrochemical facies evolution (HFE) diagram. Based on the Gibbs plot, the behavior of the major ions showed that the changes in the chemical composition of the groundwater are mainly controlled by the water-soil/rock interaction zone and few samples are relatively controlled by evaporation. A possible explanation for this phenomenon is that the deposited chloride and sulfate particles can form the minor salinity source in some coastal areas when washed down by precipitation. The SI calculations showed that all groundwater samples, collected in these periods, show negative saturation indices, which indicate undersaturation with respect to anhydrite, gypsum, and halite. In addition, except in a few cases, all other samples showed the undersaturation with respect to the carbonate minerals such as aragonite, calcite, and dolomite. Therefore, these minerals are susceptible to dissolution. In the dry season, the SI calculations showed more positive values with respect to dolomite, especially in the northern part of UA, which indicated a higher potential for precipitation and deposition of dolomite. The percentage of saltwater in the groundwater samples of Urmia plain was very low, ranging between 0.001 and 0.79 % in the wet season and 0.0004 and 0.81 % in the dry season. The results of HFE diagram, which was taken to find whether the aquifer was in the saltwater encroachment phase or in the freshening phase, indicated that except for a few wells

Identifying, characterizing and predicting spatial patterns of lacustrine groundwater discharge

NASA Astrophysics Data System (ADS)

Tecklenburg, Christina; Blume, Theresa

2017-10-01

Lacustrine groundwater discharge (LGD) can significantly affect lake water balances and lake water quality. However, quantifying LGD and its spatial patterns is challenging because of the large spatial extent of the aquifer-lake interface and pronounced spatial variability. This is the first experimental study to specifically study these larger-scale patterns with sufficient spatial resolution to systematically investigate how landscape and local characteristics affect the spatial variability in LGD. We measured vertical temperature profiles around a 0.49 km2 lake in northeastern Germany with a needle thermistor, which has the advantage of allowing for rapid (manual) measurements and thus, when used in a survey, high spatial coverage and resolution. Groundwater inflow rates were then estimated using the heat transport equation. These near-shore temperature profiles were complemented with sediment temperature measurements with a fibre-optic cable along six transects from shoreline to shoreline and radon measurements of lake water samples to qualitatively identify LGD patterns in the offshore part of the lake. As the hydrogeology of the catchment is sufficiently homogeneous (sandy sediments of a glacial outwash plain; no bedrock control) to avoid patterns being dominated by geological discontinuities, we were able to test the common assumptions that spatial patterns of LGD are mainly controlled by sediment characteristics and the groundwater flow field. We also tested the assumption that topographic gradients can be used as a proxy for gradients of the groundwater flow field. Thanks to the extensive data set, these tests could be carried out in a nested design, considering both small- and large-scale variability in LGD. We found that LGD was concentrated in the near-shore area, but alongshore variability was high, with specific regions of higher rates and higher spatial variability. Median inflow rates were 44 L m-2 d-1 with maximum rates in certain locations going

A simple method for estimating basin-scale groundwater discharge by vegetation in the basin and range province of Arizona using remote sensing information and geographic information systems

USGS Publications Warehouse

Tillman, F.D.; Callegary, J.B.; Nagler, P.L.; Glenn, E.P.

2012-01-01

Groundwater is a vital water resource in the arid to semi-arid southwestern United States. Accurate accounting of inflows to and outflows from the groundwater system is necessary to effectively manage this shared resource, including the important outflow component of groundwater discharge by vegetation. A simple method for estimating basin-scale groundwater discharge by vegetation is presented that uses remote sensing data from satellites, geographic information systems (GIS) land cover and stream location information, and a regression equation developed within the Southern Arizona study area relating the Enhanced Vegetation Index from the MODIS sensors on the Terra satellite to measured evapotranspiration. Results computed for 16-day composited satellite passes over the study area during the 2000 through 2007 time period demonstrate a sinusoidal pattern of annual groundwater discharge by vegetation with median values ranging from around 0.3 mm per day in the cooler winter months to around 1.5 mm per day during summer. Maximum estimated annual volume of groundwater discharge by vegetation was between 1.4 and 1.9 billion m3 per year with an annual average of 1.6 billion m3. A simplified accounting of the contribution of precipitation to vegetation greenness was developed whereby monthly precipitation data were subtracted from computed vegetation discharge values, resulting in estimates of minimum groundwater discharge by vegetation. Basin-scale estimates of minimum and maximum groundwater discharge by vegetation produced by this simple method are useful bounding values for groundwater budgets and groundwater flow models, and the method may be applicable to other areas with similar vegetation types.

A practical assessment of aquifer discharge for regional groundwater demand by characterizing leaky confined aquifer overlain on a Mesozoic granitic gneiss basement

NASA Astrophysics Data System (ADS)

Shih, David Ching-Fang

2018-04-01

Due to increasing population worldwide, there is an urgent need to manage these important but diminishing groundwater resources efficiently to ensure their continued availability. The major innovative design of this study is to provide a practical assessment process for groundwater discharge under a regional demand by characterizing the nature of leaky confined aquifers overlain on a Mesozoic granitic gneiss basement which involves the important groundwater system in the Kinmen region (Taiwan, ROC) and the assessment of adoptable groundwater discharge in aquifer is needed. The storage coefficient presents an order of one in a thousand and hydraulic conductivity is approximately at the order of 1-8 m/d and 0.4-0.9 m/d for aquifer and aquitard respectively. Groundwater discharge and admissible number of pumping well is suggested considering scheduled maximum groundwater volume and head decline change for eastern and western studied area respectively. The safety subjected to the conservative issue is then addressed by the use of scheduled maximum groundwater volume. It reveals that the safety can be ensured using the indicator as scheduled maximum groundwater volume with predefined scenarios. The result can be utilized practically for developing management strategy of groundwater resources due to the applicability and novel of method.

Resistivity-Chemistry Integrated Approaches for Investigating Groundwater Salinity of Water Supply and Agricultural Activity at Island Coastal Area

NASA Astrophysics Data System (ADS)

Baharuddin, M. F. T.; Masirin, M. I. M.; Hazreek, Z. A. M.; Azman, M. A. A.; Madun, A.

2018-04-01

Groundwater suitability for water supply and agriculture in an island coastal area may easily be influenced by seawater intrusion. The aim of this study was to investigate seawater intrusion to the suitability of the groundwater for water supply and oil palm cultivation on Carey Island in Malaysia. This is the first study that used integrated method of geo-electrical resistivity and hydrogeochemical methods to investigate seawater intrusion to the suitability of groundwater for water supply and oil palm cultivation at two different surface elevation and land cover. The relationship between earth resistivity, total dissolved solids and earth conductivity was derived with water type classifications and crop suitability classification according to salinity, used to identify water types and also oil palm tolerance to salinity. Results from the contour resistivity and conductivity maps showed that the area facing severe coastal erosion (east area) exhibited unsuitable groundwater condition for water supply and oil palm at the unconfined aquifer thickness of 7.8 m and 14.1 m, respectively. Comparing to the area that are still intact with mangrove (west area), at the same depth, groundwater condition exhibits suitable usage for both socioeconomic activities. Different characteristics of surface elevation and land cover are paramount factors influencing saltwater distribution at the west and east area. By the end of the twenty-first century there will no longer be suitable water for supply and oil palm plantation based on the local sea-level rise prediction and Ghyben–Herzberg assumption (sharp interface), focusing on the severe erosion area of the study site.

Multi-scale Analysis of the Fluxes Between Terrestrial Water Storage, Groundwater, and Stream Discharge in the Columbia River Basin

NASA Astrophysics Data System (ADS)

Sproles, E.; Leibowitz, S. G.; Wigington, P. J.; Patil, S.; Reager, J. T.; Famiglietti, J. S.

2013-12-01

The temporal relationships between the measurements of terrestrial water storage (TWS), groundwater, and stream discharge were analyzed at three different scales in the Columbia River Basin (CRB) for water years 2004 - 2012. Our nested watershed approach examined the Snake River (182,000 sq km), Upper Columbia (155,000 sq km), and the greater CRB (614,000 sq km). These three watersheds represent distinct climatic and geologic provinces found in the region. TWS (the vertically-integrated sum of snow, soil moisture, surface water, and groundwater) was measured remotely by NASA's Gravity Recovery and Climate Experiment (GRACE). Results show that over the course of a water year, TWS and discharge exhibit a characteristic counter clockwise hysteresis pattern for each of the three regional watersheds. Similarly, in each of the three watersheds groundwater and discharge also exhibit a characteristic hysteresis pattern over the course of a water year--only in a clockwise direction. Our findings provide regional characteristics that quantify and describe the fluxes between snow, groundwater, and discharge, and also identify the out-of-phase relationship between the region's wet winters and groundwater recharge from during the spring. The methods and results presented in this study provide an analytic framework to incorporate remotely-sensed measurements of TWS to better understand how regional watersheds function as an integrated system, and also to identify potential water surplus and scarcity in the CRB and other regional watersheds.

Coastal groundwater/surface-water interactions: a Great Lakes case study

USGS Publications Warehouse

Neff, Brian P.; Haack, Sheridan K.; Rosenberry, Donald O.; Savino, Jacqueline F.; Lundstrom, Scott C.

2006-01-01

Key similarities exist between marine and Great Lakes coastal environments. Water and nutrient fluxes across lakebeds in the Great Lakes are influenced by seiche and wind set-up and set-down, analogous to tidal influence in marine settings. Groundwater/surface-water interactions also commonly involve a saline-fresh water interface, although in the Great-Lakes cases, it is groundwater that is commonly saline and surface water that is fresh. Evapotranspiration also affects nearshore hydrology in both settings. Interactions between groundwater and surface water have recently been identified as an important component of ecological processes in the Great Lakes. Water withdrawals and the reversal of the groundwater/surface water seepage gradient are also common to many coastal areas around the Great Lakes. As compared to surface water, regional groundwater that discharges to western Lake Erie from Michigan is highly mineralized. Studies conducted by the U.S. Geological Survey at Erie State Game Area in southeastern Michigan, describe groundwater flow dynamics and chemistry, shallow lake-water chemistry, and fish and invertebrate communities. Results presented here provide an overview of recent progress of ongoing interdisciplinary studies of Great Lakes nearshore systems and describe a conceptual model that identifies relations among geologic, hydrologic, chemical, and biological processes in the coastal habitats of Lake Erie. This conceptual model is based on analysis of hydraulic head in piezometers at the study site and chemical analysis of deep and shallow coastal groundwater.

Combining geochemical tracers with geophysical tools to study groundwater quality in Mesilla Bolson of the semi-arid Rio Grande watershed

NASA Astrophysics Data System (ADS)

Ma, L.; Hiebing, M.; Garcia, S.; Szynkiewicz, A.; Doser, D. I.

2017-12-01

Mesilla Bolson is an important alluvial aquifer system of the semi-arid Rio Grande watershed in southern New Mexico and West Texas. It is one of the two major groundwater sources for the City of El Paso in Texas and provides about 30% of the region's domestic groundwater needs. Groundwater from Mesilla Bolson is also extensively used for agriculture irrigation in this region. However, high concentrations of total dissolved solids in some areas of this region significantly impact groundwater quality for the Rio Grande alluvial aquifer. For example, an increase in groundwater salinity is generally observed from north to south within the aquifer. Some previous researchers have suggested this salinity change is due to 1) runoff and recharge from agricultural activity; 2) natural upwelling of deeper brackish groundwater; and 3) water-rock interactions in the aquifer. To better study how agricultural and municipal practices contribute to increasing salinity, we sampled 50 wells of the Mesilla Bolson in 2015-2016 for uranium (234U/238U), strontium (87Sr/86Sr), boron (d11B), and sulfur (d34S) isotope compositions to characterize major salinity sources of groundwater. In addition, we applied a geophysical gravity survey to determine the possible influences of faults and other subsurface structures on groundwater quality in this region. Our multi-isotope results suggest that the groundwater resources of this alluvial aquifer have been already impacted by human activities and groundwater recharge to the alluvial aquifer is affected by surface processes such as i) the return flows from the Rio Grande surface water used for irrigation, ii) municipal discharges, and iii) irrigation with the reclaimed city water. However, natural upwelling is also probably responsible for the salinity increase near some fault areas, primarily due to water-rock interactions such as dissolution of evaporites within the deeper basin. In some areas of the Mesilla Bolson, fault systems act as conduits

Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah.

PubMed

Naftz, David L; Bullen, Thomas D; Stolp, Bert J; Wilkowske, Christopher D

2008-03-15

Stream discharge and geochemical data were collected at two sites along lower Ashley Creek, Utah, from 1999 to 2003, to assess the success of a site specific salinity and Se remediation project. The remediation project involved the replacement of a leaking sewage lagoon system that was interacting with Mancos Shale and increasing the dissolved salinity and Se load in Ashley Creek. Regression modeling successfully simulated the mean daily dissolved salinity and Se loads (R(2) values ranging from 0.82 to 0.97) at both the upstream (AC1) and downstream (AC2/AC2A) sites during the study period. Prior to lagoon closure, net gain in dissolved-salinity load exceeded 2177 metric tons/month and decreased after remediation to less than 590 metric tons/month. The net gain in dissolved Se load during the same pre-closure period exceeded 120 kg/month and decreased to less than 18 kg/month. Sen's slope estimator verified the statistical significance of the modeled reduction in monthly salinity and Se loads. Measured gain in dissolved constituent loads during seepage tests conducted during September and November 2003 ranged from 0.334 to 0.362 kg/day for dissolved Se and 16.9 to 26.1 metric tons/day for dissolved salinity. Stream discharge and changes in the isotopic values of delta boron-11 (delta(11)B) were used in a mixing model to differentiate between constituent loadings contributed by residual sewage effluent and naturally occurring ground-water seepage entering Ashley Creek. The majority of the modeled delta(11)B values of ground-water seepage were positive, indicative of minimal seepage contributions from sewage effluent. The stream reach between sites S3 and AC2A contained a modeled ground-water seepage delta(11)B value of -2.4 per thousand, indicative of ground-water seepage composed of remnant water still draining from the abandoned sewage lagoons.

Dynamics of submarine groundwater discharge and associated fluxes of dissolved nutrients, carbon, and trace gases to the coastal zone (Okatee River estuary, South Carolina)

USGS Publications Warehouse

Porubsky, W.P.; Weston, N.B.; Moore, W.S.; Ruppel, C.; Joye, S.B.

2014-01-01

Multiple techniques, including thermal infrared aerial remote sensing, geophysical and geological data, geochemical characterization and radium isotopes, were used to evaluate the role of groundwater as a source of dissolved nutrients, carbon, and trace gases to the Okatee River estuary, South Carolina. Thermal infrared aerial remote sensing surveys illustrated the presence of multiple submarine groundwater discharge sites in Okatee headwaters. Significant relationships were observed between groundwater geochemical constituents and 226Ra activity in groundwater with higher 226Ra activity correlated to higher concentrations of organics, dissolved inorganic carbon, nutrients, and trace gases to the Okatee system. A system-level radium mass balance confirmed a substantial submarine groundwater discharge contribution of these constituents to the Okatee River. Diffusive benthic flux measurements and potential denitrification rate assays tracked the fate of constituents in creek bank sediments. Diffusive benthic fluxes were substantially lower than calculated radium-based submarine groundwater discharge inputs, showing that advection of groundwater-derived nutrients dominated fluxes in the system. While a considerable potential for denitrification in tidal creek bank sediments was noted, in situ denitrification rates were nitrate-limited, making intertidal sediments an inefficient nitrogen sink in this system. Groundwater geochemical data indicated significant differences in groundwater chemical composition and radium activity ratios between the eastern and western sides of the river; these likely arose from the distinct hydrological regimes observed in each area. Groundwater from the western side of the Okatee headwaters was characterized by higher concentrations of dissolved organic and inorganic carbon, dissolved organic nitrogen, inorganic nutrients and reduced metabolites and trace gases, i.e. methane and nitrous oxide, than groundwater from the eastern side

Chronology, sedimentology, and microfauna of groundwater discharge deposits in the central Mojave Desert, Valley Wells, California

USGS Publications Warehouse

Pigati, J.S.; Miller, D.M.; Bright, J.E.; Mahan, S.A.; Nekola, J.C.; Paces, J.B.

2011-01-01

groundwater supported persistent and long-lived desert wetlands in many broad valleys and basins in the American Southwest. When active, these systems provided important food and water sources for local fauna, supported hydrophilic and phreatophytic vegetation, and acted as catchments for eolian and alluvial sediments. Desert wetlands are represented in the geologic record by groundwater discharge deposits, which are also called spring or wetland deposits. Groundwater discharge deposits contain information on the timing and magnitude of past changes in water-table levels and, thus, are a source of paleohydrologic and paleoclimatic information. Here, we present the results of an investigation of extensive groundwater discharge deposits in the central Mojave Desert at Valley Wells, California. We used geologic mapping and stratigraphic relations to identify two distinct wetland sequences at Valley Wells, which we dated using radiocarbon, luminescence, and uranium-series techniques. We also analyzed the sediments and microfauna (ostracodes and gastropods) to reconstruct the specific environments in which they formed. Our results suggest that the earliest episode of high water-table conditions at Valley Wells began ca. 60 ka (thousands of calendar yr B.P.), and culminated in peak discharge between ca. 40 and 35 ka. During this time, cold (4-12 ??C) emergent groundwater supported extensive wetlands that likely were composed of a wet, sedge-rush-tussock meadow mixed with mesic riparian forest. After ca. 35 ka, the water table dropped below the ground surface but was still shallow enough to support dense stands of phreatophytes through the Last Glacial Maximum (LGM). The water table dropped further after the LGM, and xeric conditions prevailed until modest wetlands returned briefly during the Younger Dryas cold event (13.0-11.6 ka). We did not observe any evidence of wet conditions during the Holocene at Valley Wells. The timing of these fluctuations is consistent with

Chronology, sedimentology, and microfauna of groundwater discharge deposits in the central Mojave Desert, Valley Wells, California

USGS Publications Warehouse

Pigati, Jeffrey S.; Miller, David M.; Bright, Jordon E.; Mahan, Shannon; Nekola, Jeffrey C.; Paces, James B.

2011-01-01

During the late Pleistocene, emergent groundwater supported persistent and long-lived desert wetlands in many broad valleys and basins in the American Southwest. When active, these systems provided important food and water sources for local fauna, supported hydrophilic and phreatophytic vegetation, and acted as catchments for eolian and alluvial sediments. Desert wetlands are represented in the geologic record by groundwater discharge deposits, which are also called spring or wetland deposits. Groundwater discharge deposits contain information on the timing and magnitude of past changes in water-table levels and, thus, are a source of paleohydrologic and paleoclimatic information. Here, we present the results of an investigation of extensive groundwater discharge deposits in the central Mojave Desert at Valley Wells, California. We used geologic mapping and stratigraphic relations to identify two distinct wetland sequences at Valley Wells, which we dated using radiocarbon, luminescence, and uranium-series techniques. We also analyzed the sediments and microfauna (ostracodes and gastropods) to reconstruct the specific environments in which they formed. Our results suggest that the earliest episode of high water-table conditions at Valley Wells began ca. 60 ka (thousands of calendar yr B.P.), and culminated in peak discharge between ca. 40 and 35 ka. During this time, cold (4–12 °C) emergent groundwater supported extensive wetlands that likely were composed of a wet, sedge-rush-tussock meadow mixed with mesic riparian forest. After ca. 35 ka, the water table dropped below the ground surface but was still shallow enough to support dense stands of phreatophytes through the Last Glacial Maximum (LGM). The water table dropped further after the LGM, and xeric conditions prevailed until modest wetlands returned briefly during the Younger Dryas cold event (13.0–11.6 ka). We did not observe any evidence of wet conditions during the Holocene at Valley Wells. The timing

Flow and geochemistry of groundwater beneath a back-barrier lagoon: The subterranean estuary at Chincoteague Bay, Maryland, USA

USGS Publications Warehouse

Bratton, J.F.; Böhlke, J.K.; Krantz, D.E.; Tobias, C.R.

2009-01-01

To better understand large-scale interactions between fresh and saline groundwater beneath an Atlantic coastal estuary, an offshore drilling and sampling study was performed in a large barrier-bounded lagoon, Chincoteague Bay, Maryland, USA. Groundwater that was significantly fresher than overlying bay water was found in shallow plumes up to 8??m thick extending more than 1700??m offshore. Groundwater saltier than bay surface water was found locally beneath the lagoon and the barrier island, indicating recharge by saline water concentrated by evaporation prior to infiltration. Steep salinity and nutrient gradients occur within a few meters of the sediment surface in most locations studied, with buried peats and estuarine muds acting as confining units. Groundwater ages were generally more than 50??years in both fresh and brackish waters as deep as 23??m below the bay bottom. Water chemistry and isotopic data indicate that freshened plumes beneath the estuary are mixtures of water originally recharged on land and varying amounts of estuarine surface water that circulated through the bay floor, possibly at some distance from the sampling location. Ammonium is the dominant fixed nitrogen species in saline groundwater beneath the estuary at the locations sampled. Isotopic and dissolved-gas data from one location indicate that denitrification within the subsurface flow system removed terrestrial nitrate from fresh groundwater prior to discharge along the western side of the estuary. Similar situations, with one or more shallow semi-confined flow systems where groundwater geochemistry is strongly influenced by circulation of surface estuary water through organic-rich sediments, may be common on the Atlantic margin and elsewhere.

A comparison of thermal infrared to fiber-optic distributed temperature sensing for evaluation of groundwater discharge to surface water

NASA Astrophysics Data System (ADS)

Hare, Danielle K.; Briggs, Martin A.; Rosenberry, Donald O.; Boutt, David F.; Lane, John W.

2015-11-01

Groundwater has a predictable thermal signature that can be used to locate discrete zones of discharge to surface water. As climate warms, surface water with strong groundwater influence will provide habitat stability and refuge for thermally stressed aquatic species, and is therefore critical to locate and protect. Alternatively, these discrete seepage locations may serve as potential point sources of contaminants from polluted aquifers. This study compares two increasingly common heat tracing methods to locate discrete groundwater discharge: direct-contact measurements made with fiber-optic distributed temperature sensing (FO-DTS) and remote sensing measurements collected with thermal infrared (TIR) cameras. FO-DTS is used to make high spatial resolution (typically m) thermal measurements through time within the water column using temperature-sensitive cables. The spatial-temporal data can be analyzed with statistical measures to reveal zones of groundwater influence, however, the personnel requirements, time to install, and time to georeference the cables can be burdensome, and the control units need constant calibration. In contrast, TIR data collection, either from handheld, airborne, or satellite platforms, can quickly capture point-in-time evaluations of groundwater seepage zones across large scales. However the remote nature of TIR measurements means they can be adversely influenced by a number of environmental and physical factors, and the measurements are limited to the surface ;skin; temperature of water features. We present case studies from a range of lentic to lotic aquatic systems to identify capabilities and limitations of both technologies and highlight situations in which one or the other might be a better instrument choice for locating groundwater discharge. FO-DTS performs well in all systems across seasons, but data collection was limited spatially by practical considerations of cable installation. TIR is found to consistently locate

Sustainable use of groundwater in Atoll Islands

NASA Astrophysics Data System (ADS)

Taniguchi, M.; Nakada, S.; Umezawa, Y.; Yamano, H.

2010-12-01

Water resources in small islands, such as atoll islands, are limited and threatened by climate change such as changes in precipitation and sea level rise. Groundwater is the main water resources in many atoll islands, and the freshwater in aquifers in coral atolls, where the average elevations are a few meters above the sea level, exists as lenses f1oating on salt water. Decrease in precipitation and groundwater recharge is caused by the climate change, increases of storm surge, and excessive groundwater extractions due to over population. There is high possibility that the aquifer salinization can damage the important natural ambience for the people living habitat such as crops field and vegetation. In this study, the aquifer salinization is evaluated by using electrical resistivity, hydrological and long-term meteorological data in two low-lying coral atolls, Laura islet, Majuro Atoll, Marshall islands and Fongafale islet, Funafuti atoll, Tuvalu. Hydrological surveys conducted in Laura islet showed that the interface between seawater and freshwater is shallowed in Aug 2009. This may be attributed to the result of recent decrease of the decadal rainfall and/or the sea level rise. The detailed structure of the freshwater lens based on the electrical resistivity surveys showed patches of brackish water due to the intrusion of seawater and over-pumping. The clear intrusion of the saltwater was observed near the lagoon coast which might be inf1uenced by the recirculation of the seawater in the margin of the freshwater lens. The recirculation was confirmed based on the analysis of the submarine groundwater discharge (SGD) observed by seepage meters. On the other hand, in Fongatale islet, the geoelectric and hydrological surveys conducted in March 2009 showed that the soil and groundwater salinization was mainly caused by the tidal forcing during spring tides. The decrease of the resistivity during the f1ood tide indicates the coastal aquifer beneath the islet is

Modelling river discharge and precipitation from estuarine salinity in the northern Chesapeake Bay: Application to Holocene palaeoclimate

USGS Publications Warehouse

Saenger, C.; Cronin, T.; Thunell, R.; Vann, C.

2006-01-01

Long-term chronologies of precipitation can provide a baseline against which twentieth-century trends in rainfall can be evaluated in terms of natural variability and anthropogenic influence. However, there are relatively few methods to quantitatively reconstruct palaeoprecipitation and river discharge compared with proxies of other climatic factors, such as temperature. We developed autoregressive and least squares statistical models relating Chesapeake Bay salinity to river discharge and regional precipitation records. Salinity in northern and central parts of the modern Chesapeake Bay is influenced largely by seasonal, interannual and decadal variations in Susquehanna River discharge, which in turn are controlled by regional precipitation patterns. A power regressive discharge model and linear precipitation model exhibit well-defined decadal variations in peak discharge and precipitation. The utility of the models was tested by estimating Holocene palaeoprecipitation and Susquehanna River palaeodischarge, as indicated by isotopically derived palaeosalinity reconstructions from Chesapeake Bay sediment cores. Model results indicate that the early-mid Holocene (7055-5900 yr BP) was drier than the late Holocene (1500 yr BP - present), the 'Mediaeval Warm Period' (MWP) (1200-600 yr BP) was drier than the 'Little Ice Age' (LIA) (500-100 yr BP), and the twentieth century experienced extremes in precipitation possibly associated with changes in ocean-atmosphere teleconnections. ?? 2006 Edward Arnold (Publishers) Ltd.

Atoll groundwater movement and its response to climatic and sea-level fluctuations

USGS Publications Warehouse

Oberle, Ferdinand; Swarzenski, Peter W.; Storlazzi, Curt

2017-01-01

Groundwater resources of low-lying atoll islands are threatened due to short-term and long-term changes in rainfall, wave climate, and sea level. A better understanding of how these forcings affect the limited groundwater resources was explored on Roi-Namur in the Republic of the Marshall Islands. As part of a 16-month study, a rarely recorded island-overwash event occurred and the island’s aquifer’s response was measured. The findings suggest that small-scale overwash events cause an increase in salinity of the freshwater lens that returns to pre-overwash conditions within one month. The overwash event is addressed in the context of climate-related local sea-level change, which suggests that overwash events and associated degradations in freshwater resources are likely to increase in severity in the future due to projected rises in sea level. Other forcings, such as severe rainfall events, were shown to have caused a sudden freshening of the aquifer, with salinity levels retuning to pre-rainfall levels within three months. Tidal forcing of the freshwater lens was observed in electrical resistivity profiles, high-resolution conductivity, groundwater-level well measurements and through submarine groundwater discharge calculations. Depth-specific geochemical pore water measurements further assessed and confirmed the distinct boundaries between fresh and saline water masses in the aquifer. The identification of the freshwater lens’ saline boundaries is essential for a quantitative evaluation of the aquifers freshwater resources and help understand how these resources may be impacted by climate change and anthropogenic activities.

Baseline Geochemistry of Natural Occurring Methane and Saline Groundwater in an Area of Unconventional Shale Gas Development Through Time

NASA Astrophysics Data System (ADS)

Harkness, J.; Darrah, T.; Warner, N. R.; Whyte, C. J.; Moore, M. T.; Millot, R.; Kloppmann, W.; Jackson, R. B.; Vengosh, A.

2017-12-01

Naturally occurring methane is nearly ubiquitous in most sedimentary basins and delineating the effects of anthropogenic contamination sources from geogenic sources is a major challenge for evaluating the impact of unconventional shale gas development on water quality. This study employs a broadly integrated study of various geochemical techniques to investigate the geochemical variations of groundwater and surface water before, during, and after hydraulic fracturing.This approache combines inorganic geochemistry (major cations and anions), stable isotopes of select inorganic constituents including strontium (87Sr/86Sr), boron (δ11B), lithium (δ7Li), and carbon (δ13C-DIC), select hydrocarbon molecular (methane, ethane, propane, butane, and pentane) and isotopic tracers (δ13C-CH4, δ13C-C2H6), tritium (3H), and noble gas elemental and isotopic composition (He, Ne, Ar) to apportion natural and anthropogenic sources of natural gas and salt contaminants both before and after drilling. Methane above 1 ccSTP/L in groundwater samples awas strongly associated with elevated salinity (chloride >50 mg/L).The geochemical and isotopic analysis indicate saline groundwater originated via naturally occurring processes, presumably from the migration of deeper methane-rich brines that have interacted extensively with coal lithologies. The chemistry and gas compostion of both saline and fresh groundwater wells did not change following the installation of nearby shale-gas wells.The results of this study emphasize the value of baseline characterization of water quality in areas of fossil fuel exploration. Overall this study presents a comprehensive geochemical framework that can be used as a template for assessing the sources of elevated hydrocarbons and salts to water resources in areas potentially impacted by oil and gas development.

Effects of Changes in Irrigation Practices and Aquifer Development on Groundwater Discharge to the Jobos Bay National Estuarine Research Reserve near Salinas, Puerto Rico

USGS Publications Warehouse

Kuniansky, Eve L.; Rodriguez, Jose M.

2010-01-01

Since 1990, about 75 acres of black mangroves have died in the Jobos Bay National Estuarine Research Reserve near Salinas, Puerto Rico. Although many factors can contribute to the mortality of mangroves, changes in irrigation practices, rainfall, and water use resulted in as much as 25 feet of drawdown in the potentiometric surface of the aquifer in the vicinity of the reserve between 1986 and 2002. To clarify the issue, the U.S. Geological Survey, in cooperation with the Puerto Rico Department of Natural and Environmental Resources, conducted a study to ascertain how aquifer development and changes in irrigation practices have affected groundwater levels and groundwater flow to the Mar Negro area of the reserve. Changes in groundwater flow to the mangrove swamp and bay from 1986 to 2004 were estimated in this study by developing and calibrating a numerical groundwater flow model. The transient simulations indicate that prior to 1994, high irrigation return flows more than offset the effect of reduced groundwater withdrawals. In this case, the simulated discharge to the coast in the modeled area was 19 million gallons per day. From 1994 through 2004, furrow irrigation was completely replaced by micro-drip irrigation, thus eliminating return flows and the simulated average coastal discharge was 7 million gallons per day, a reduction of 63 percent. The simulated average groundwater discharge to the coastal mangrove swamps in the reserve from 1986 to 1993 was 2 million gallons per day, compared to an average simulated discharge of 0.2 million gallons per day from 1994 to 2004. The average annual rainfall for each of these periods was 38 inches. The groundwater discharge to the coastal mangrove swamps in the Jobos Bay National Estuarine Research Reserve was estimated at about 0.5 million gallons per day for 2003-2004 because of higher than average annual rainfall during these 2 years. The groundwater flow model was used to test five alternatives for increasing

Measurement of submarine groundwater discharge using diverse methods in Coleroon Estuary, Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Prakash, R.; Srinivasamoorthy, K.; Gopinath, S.; Saravanan, K.

2018-03-01

Submarine groundwater discharge (SGD) is described as submarine inflow of fresh and brackish groundwater from land into the sea. The release of sewages from point and non-point source pollutants from industries, agricultural and domestic activities gets discharged through groundwater to ocean creating natural disparity like decreasing flora fauna and phytoplankton blooms. Hence, to quantify fluxes of SGD in coastal regions is important. Quantification of SGD was attempted in Coleroon estuary, India, using three dissimilar methods like water budget, Darcy law and manual seepage meter. Three seepage meters were installed at two prominent litho units (alluvium and fluvio marine) at a distance of (0-14.7 km) away from Bay of Bengal. The water budget and Darcy law-quantified submarine seepage at a rate of 6.9 × 106 and 3.2 × 103 to 308.3 × 103 m3 year-1, respectively, and the seepage meter quantified seepage rate of 0.7024 m h-1 at an average. Larger seepage variations were isolated from three different techniques and the seepage rates were found to be influenced by hydrogeological characteristics of the litho units and distance from the coast.

Potential effects of groundwater pumping on water levels, phreatophytes, and spring discharges in Spring and Snake Valleys, White Pine County, Nevada, and adjacent areas in Nevada and Utah

USGS Publications Warehouse

Halford, Keith J.; Plume, Russell W.

2011-01-01

Assessing hydrologic effects of developing groundwater supplies in Snake Valley required numerical, groundwater-flow models to estimate the timing and magnitude of capture from streams, springs, wetlands, and phreatophytes. Estimating general water-table decline also required groundwater simulation. The hydraulic conductivity of basin fill and transmissivity of basement-rock distributions in Spring and Snake Valleys were refined by calibrating a steady state, three-dimensional, MODFLOW model of the carbonate-rock province to predevelopment conditions. Hydraulic properties and boundary conditions were defined primarily from the Regional Aquifer-System Analysis (RASA) model except in Spring and Snake Valleys. This locally refined model was referred to as the Great Basin National Park calibration (GBNP-C) model. Groundwater discharges from phreatophyte areas and springs in Spring and Snake Valleys were simulated as specified discharges in the GBNP-C model. These discharges equaled mapped rates and measured discharges, respectively. Recharge, hydraulic conductivity, and transmissivity were distributed throughout Spring and Snake Valleys with pilot points and interpolated to model cells with kriging in geologically similar areas. Transmissivity of the basement rocks was estimated because thickness is correlated poorly with transmissivity. Transmissivity estimates were constrained by aquifer-test results in basin-fill and carbonate-rock aquifers. Recharge, hydraulic conductivity, and transmissivity distributions of the GBNP-C model were estimated by minimizing a weighted composite, sum-of-squares objective function that included measurement and Tikhonov regularization observations. Tikhonov regularization observations were equations that defined preferred relations between the pilot points. Measured water levels, water levels that were simulated with RASA, depth-to-water beneath distributed groundwater and spring discharges, land-surface altitudes, spring discharge at

The geochemistry of naturally occurring methane and saline groundwater in an area of unconventional shale gas development

NASA Astrophysics Data System (ADS)

Harkness, Jennifer S.; Darrah, Thomas H.; Warner, Nathaniel R.; Whyte, Colin J.; Moore, Myles T.; Millot, Romain; Kloppmann, Wolfram; Jackson, Robert B.; Vengosh, Avner

2017-07-01

Since naturally occurring methane and saline groundwater are nearly ubiquitous in many sedimentary basins, delineating the effects of anthropogenic contamination sources is a major challenge for evaluating the impact of unconventional shale gas development on water quality. This study investigates the geochemical variations of groundwater and surface water before, during, and after hydraulic fracturing and in relation to various geospatial parameters in an area of shale gas development in northwestern West Virginia, United States. To our knowledge, we are the first to report a broadly integrated study of various geochemical techniques designed to distinguish natural from anthropogenic sources of natural gas and salt contaminants both before and after drilling. These measurements include inorganic geochemistry (major cations and anions), stable isotopes of select inorganic constituents including strontium (87Sr/86Sr), boron (δ11B), lithium (δ7Li), and carbon (δ13C-DIC), select hydrocarbon molecular (methane, ethane, propane, butane, and pentane) and isotopic tracers (δ13C-CH4, δ13C-C2H6), tritium (3H), and noble gas elemental and isotopic composition (helium, neon, argon) in 105 drinking-water wells, with repeat testing in 33 of the wells (total samples = 145). In a subset of wells (n = 20), we investigated the variations in water quality before and after the installation of nearby (<1 km) shale-gas wells. Methane occurred above 1 ccSTP/L in 37% of the groundwater samples and in 79% of the samples with elevated salinity (chloride > 50 mg/L). The integrated geochemical data indicate that the saline groundwater originated via naturally occurring processes, presumably from the migration of deeper methane-rich brines that have interacted extensively with coal lithologies. These observations were consistent with the lack of changes in water quality observed in drinking-water wells following the installation of nearby shale-gas wells. In contrast to groundwater

Interception of nutrient rich submarine groundwater discharge seepage on European temperate beaches by the acoel flatworm, Symsagittifera roscoffensis.

PubMed

Carvalho, Liliana F; Rocha, Carlos; Fleming, Alexandra; Veiga-Pires, Cristina; Aníbal, Jaime

2013-10-15

Submarine groundwater discharge (SGD) occurs in intertidal areas, representing a largely unquantified source of solute fluxes to adjacent coastal zones, with nitrogen being constantly the keynote chemical of concern. In Olhos de Água SGD is present as groundwater springs or merely sub-aerial runoff. The occurrence of the flatworm Symsagittifera roscoffensis is described for the first time in Olhos de Água in connection to seepage flows. To assess the impact of this symbiotic flatworm on the nitrogen associated to groundwater discharge flow at the beach, nitrate uptake experiments were conducted in laboratory microcosms. Our results show that S. roscoffensis actively uptakes nitrate at different rates depending on light availability, with rates ≈ 10 times higher than that of its symbiotic microalgae alone. This supports the hypothesis that S. roscoffensis could be an important in situ nitrate interceptor, potentially playing a biological role on the transformation of groundwater-borne nitrate loads at the land-ocean boundary. Copyright © 2013 Elsevier Ltd. All rights reserved.

Heterogeneous hyporheic zone dechlorination of a TCE groundwater plume discharging to an urban river reach.

PubMed

Freitas, Juliana G; Rivett, Michael O; Roche, Rachel S; Durrant Neé Cleverly, Megan; Walker, Caroline; Tellam, John H

2015-02-01

The typically elevated natural attenuation capacity of riverbed-hyporheic zones is expected to decrease chlorinated hydrocarbon (CHC) groundwater plume discharges to river receptors through dechlorination reactions. The aim of this study was to assess physico-chemical processes controlling field-scale variation in riverbed-hyporheic zone dechlorination of a TCE groundwater plume discharge to an urban river reach. The 50-m long pool-riffle-glide reach of the River Tame in Birmingham (UK) studied is a heterogeneous high energy river environment. The shallow riverbed was instrumented with a detailed network of multilevel samplers. Freeze coring revealed a geologically heterogeneous and poorly sorted riverbed. A chlorine number reduction approach provided a quantitative indicator of CHC dechlorination. Three sub-reaches of contrasting behaviour were identified. Greatest dechlorination occurred in the riffle sub-reach that was characterised by hyporheic zone flows, moderate sulphate concentrations and pH, anaerobic conditions, low iron, but elevated manganese concentrations with evidence of sulphate reduction. Transient hyporheic zone flows allowing input to varying riverbed depths of organic matter are anticipated to be a key control. The glide sub-reach displayed negligible dechlorination attributed to the predominant groundwater baseflow discharge condition, absence of hyporheic zone, transition to more oxic conditions and elevated sulphate concentrations expected to locally inhibit dechlorination. The tail-of-pool-riffle sub-reach exhibited patchy dechlorination that was attributed to sub-reach complexities including significant flow bypass of a low permeability, high organic matter, silty unit of high dechlorination potential. A process-based conceptual model of reach-scale dechlorination variability was developed. Key findings of practitioner relevance were: riverbed-hyporheic zone CHC dechlorination may provide only a partial, somewhat patchy barrier to CHC

Submarine groundwater discharge into the coast revealed by water chemistry of man-made undersea liquefied petroleum gas cavern

NASA Astrophysics Data System (ADS)

Lee, Jin-Yong; Cho, Byung Wook

2008-10-01

SummaryThe occurrence of submarine groundwater discharge (SGD) as well as its supply of many nutrients and metals to coastal seawaters is now generally known. However, previous studies have focused on the chemical and radiological analysis of groundwater, surface seawater, shallow marine sediments and their pore waters, as well as the measurement of upward flow through the marine sediments, as end members of the discharge process. In this study, chemical and isotopic analysis results of marine subsurface waters are reported. These were obtained from deep boreholes of an undersea liquefied petroleum gas (LPG) storage cavern, located about 8 km off the western coast of Korea. The cavern is about 130-150 m below the sea bottom, which is covered by a 4.8-19.5 m silty clay stratum. An isotopic composition (δ 2H and δ 18O) of the marine subsurface waters falls on a mixing line between terrestrial groundwater and seawater. Vertical EC profiling at the cavern boreholes revealed the existence of a fresh water zone. An increase in the contents of ferrous iron and manganese and a decrease in levels of nitrate, bicarbonate and cavern seepage were recorded in August 2006, indicating a decreased submarine groundwater flux originating from land, mainly caused by an elevated cavern gas pressure. It is suggested in this study that the main source of fresh waters in the man-made undersea cavern is the submarine groundwater discharge mainly originating from the land.

Ground-water discharge determined from measurements of evapotranspiration, other available hydrologic components, and shallow water-level changes, Oasis Valley, Nye County, Nevada

USGS Publications Warehouse

Reiner, S.R.; Laczniak, R.J.; DeMeo, G.A.; Smith, J. LaRue; Elliott, P.E.; Nylund, W.E.; Fridrich, C.J.

2002-01-01

Oasis Valley is an area of natural ground-water discharge within the Death Valley regional ground-water flow system of southern Nevada and adjacent California. Ground water discharging at Oasis Valley is replenished from inflow derived from an extensive recharge area that includes the northwestern part of the Nevada Test Site (NTS). Because nuclear testing has introduced radionuclides into the subsurface of the NTS, the U.S. Department of Energy currently is investigating the potential transport of these radionuclides by ground water flow. To better evaluate any potential risk associated with these test-generated contaminants, a number of studies were undertaken to accurately quantify discharge from areas downgradient in the regional ground-water flow system from the NTS. This report refines the estimate of ground-water discharge from Oasis Valley. Ground-water discharge from Oasis Valley was estimated by quantifying evapotranspiration (ET), estimating subsurface outflow, and compiling ground-water withdrawal data. ET was quantified by identifying areas of ongoing ground-water ET, delineating areas of ET defined on the basis of similarities in vegetation and soil-moisture conditions, and computing ET rates for each of the delineated areas. A classification technique using spectral-reflectance characteristics determined from satellite imagery acquired in 1992 identified eight unique areas of ground-water ET. These areas encompass about 3,426 acres of sparsely to densely vegetated grassland, shrubland, wetland, and open water. Annual ET rates in Oasis Valley were computed with energy-budget methods using micrometeorological data collected at five sites. ET rates range from 0.6 foot per year in a sparse, dry saltgrass environment to 3.1 feet per year in dense meadow vegetation. Mean annual ET from Oasis Valley is estimated to be about 7,800 acre-feet. Mean annual ground-water discharge by ET from Oasis Valley, determined by removing the annual local precipitation

Sorption Behavior of Eu(III) into CSH Gel in Imitated Saline Groundwater - 12145

DOE Office of Scientific and Technical Information (OSTI.GOV)

Funabashi, Taihei; Niibori, Yuichi; Mimura, Hitoshi

2012-07-01

The sorption behavior of Eu(III) (europium (III)) into CSH (Calcium Silicate Hydrate) gel without dried processes was examined in imitated saline groundwater by using the spectro-fluorometer, Raman spectrophotometer and ICP-AES (Inductively Coupled Plasma- Atomic Emission Spectrometry). Ca/Si ratio was set to 0.4, 0.8, 1.2 and 1.6, and NaCl concentration was also set to 0.6, 0.06 and 0.006. The synthesis of each sample was conducted in a glove box saturated with nitrogen gas. The sealed sample tubes were gently shaken with 120 strokes/min. The time-period to contact Eu(III) with the CSH gel was set to 60 days. The fluorescence emission spectramore » suggested the incorporation of Eu{sup 3+} into CSH gel in the high Ca/Si ratio samples. On the other hand, from the decay behavior of fluorescence emission spectra, even in the low Ca/Si ratio samples, sorption behavior of Eu{sup 3+} into CSH gel was confirmed. Besides, the Raman spectra showed that the degree of polymerization of Si-O in CSH gel was raised with increasing Na ions concentration. These results suggest that the CSH gel, formed as secondary mineral, would retard the migration of radionuclides even in saline groundwater. Considering the inflow of saline groundwater into repository, this study examined the interaction between CSH gel (without dry processes) and Eu{sup 3+} by using the fluorescence emission spectra, the decay behavior of fluorescence and the Raman spectra. As a result, the fluorescence emission spectra of the sample of more than 0.8 Ca/Si ratio confirmed the intensity split into two peaks around 618 nm (5D0→7F2 transition). Furthermore, even in relatively low Ca/Si ratio samples, the fluorescence lifetimes both of the surface sorption sample and the co-precipitated samples exceeded that of the filtrate sample. These suggested that Eu{sup 3+} is not only hydrolyzed to form Eu(OH){sub 3} colloid, but is also stably incorporated into CSH gel (in Ca/Si ratio>1.2) or is forming complex on the

Numerical study of groundwater flow cycling controlled by seawater/freshwater interaction in a coastal karst aquifer through conduit network using CFPv2.

PubMed

Xu, Zexuan; Hu, Bill X; Davis, Hal; Kish, Stephen

2015-11-01

In this study, a groundwater flow cycling in a karst springshed and an interaction between two springs, Spring Creek Springs and Wakulla Springs, through a subground conduit network are numerically simulated using CFPv2, the latest research version of MODFLOW-CFP (Conduit Flow Process). The Spring Creek Springs and Wakulla Springs, located in a marine estuary and 11 miles inland, respectively, are two major groundwater discharge spots in the Woodville Karst Plain (WKP), North Florida, USA. A three-phase conceptual model of groundwater flow cycling between the two springs and surface water recharge from a major surface creek (Lost Creek) was proposed in various rainfall conditions. A high permeable subground karst conduit network connecting the two springs was found by tracer tests and cave diving. Flow rate of discharge, salinity, sea level and tide height at Spring Creek Springs could significantly affect groundwater discharge and water stage at Wakulla Springs simultaneously. Based on the conceptual model, a numerical hybrid discrete-continuum groundwater flow model is developed using CFPv2 and calibrated by field measurements. Non-laminar flows in conduits and flow exchange between conduits and porous medium are implemented in the hybrid coupling numerical model. Time-variable salinity and equivalent freshwater head boundary conditions at the submarine spring as well as changing recharges have significant impacts on seawater/freshwater interaction and springs' discharges. The developed numerical model is used to simulate the dynamic hydrological process and quantitatively represent the three-phase conceptual model from June 2007 to June 2010. Simulated results of two springs' discharges match reasonably well to measurements with correlation coefficients 0.891 and 0.866 at Spring Creeks Springs and Wakulla Springs, respectively. The impacts of sea level rise on regional groundwater flow field and relationship between the inland springs and submarine springs are

Contribution of seawater recirculation to submarine groundwater discharge and related nutrient fluxes in two tropical bays

NASA Astrophysics Data System (ADS)

Vautier, Camille; Dulaiova, Henrietta

2017-04-01

Hawaiian coastal waters suffer from excess terrestrial nutrient loading, most of which comes from submarine groundwater discharge (SGD). This study quantifies and distinguishes the role of the fresh terrestrial and tidally pumped salt water components of SGD into the nearshore zone of two reefs on the island of Oahu: Maunalua Bay and Kāneohe Bay. The two components of SGD are characterized using isotopic techniques, and the study mainly focuses on the less understood recirculation component. A two-step approach is implemented: first, a conceptual model of groundwater circulation is established; second, nutrient fluxes associated with seawater recirculation are quantified. Groundwater circulation through the beach berm is quantified and characterized using 222Rn and 224Ra activity measurements. Nutrient fluxes are obtained by coupling nutrient concentration measurements and discharge estimates. The isotopic signatures inform us about the influence of the tidal cycle on groundwater circulation. 222Rn, 224Ra, and δ18O isotopes are used to derive apparent ages of the infiltrated seawater and allow us to quantify recirculation rates. The method is also complemented with the use of silicate concentration as tracers of the recirculation process. The trends in apparent ages observed in pore water in Maunalua match previously published conceptual groundwater circulation models and show a sequentially aging pore water circulation loop. However, the ages obtained in Kāneohe suggest a different tidal pumping dynamic that lacks a circulation loop, perhaps resulting from the absence of freshwater discharge. Derived nutrient fluxes show that the autochthonous production of inorganic nitrogen and phosphorus that occurs during seawater recirculation has a significant impact on nutrient cycles in the nearshore areas of the bays. This result suggests that seawater recirculation should be taken into account in biogeochemical studies of coastal areas.

The influence of heterogeneity on coastal groundwater flow - physical and numerical modeling of fringing reefs, dykes and structured conductivity fields

NASA Astrophysics Data System (ADS)

Houben, Georg J.; Stoeckl, Leonard; Mariner, Katrina E.; Choudhury, Anis S.

2018-03-01

Geological heterogeneity of the subsurface, caused by both discrete features and spatially distributed hydraulic conductivity fields, affects the flow of coastal groundwater. It influences the shape and the position of the interface between saltwater and freshwater, as well as the location and flux rate of freshwater discharge to the ocean. Fringing reefs lead to a bimodal regime of freshwater discharge, with discharge at the beach face and through deeper, submarine springs. Impermeable vertical flow barriers (dykes) lead to an impoundment of fresh groundwater and a compartmentalization of the aquifer but also to a delayed expulsion of saline water. Spatially distributed conductivity fields affect the shape of the interface and the geometry of the saltwater wedge. Higher effective conductivities lead to a further landward intrusion of the wedge toe. These flow characteristics can be important for groundwater extraction, the delineation of protection zones and the assessment of contaminant transport to coastal ecosystems.

Nitrogen enrichment and speciation in a coral reef lagoon driven by groundwater inputs of bird guano

NASA Astrophysics Data System (ADS)

McMahon, Ashly; Santos, Isaac R.

2017-09-01

While the influence of river inputs on coral reef biogeochemistry has been investigated, there is limited information on nutrient fluxes related to submarine groundwater discharge (SGD). Here, we investigate whether significant saline groundwater-derived nutrient inputs from bird guano drive coral reef photosynthesis and calcification off Heron Island (Great Barrier Reef, Australia). We used multiple experimental approaches including groundwater sampling, beach face transects, and detailed time series observations to assess the dynamics and speciation of groundwater nutrients as they travel across the island and discharge into the coral reef lagoon. Nitrogen speciation shifted from nitrate-dominated groundwater (>90% of total dissolved nitrogen) to a coral reef lagoon dominated by dissolved organic nitrogen (DON; ˜86%). There was a minimum input of nitrate of 2.1 mmol m-2 d-1 into the lagoon from tidally driven submarine groundwater discharge estimated from a radon mass balance model. An independent approach based on the enrichment of dissolved nutrients during isolation at low tide implied nitrate fluxes of 5.4 mmol m-2 d-1. A correlation was observed between nitrate and daytime net ecosystem production and calcification. We suggest that groundwater nutrients derived from bird guano may offer a significant addition to oligotrophic coral reef lagoons and fuel ecosystem productivity and the coastal carbon cycle near Heron Island. The large input of groundwater nutrients in Heron Island may serve as a natural ecological analogue to other coral reefs subject to large nutrient inputs from anthropogenic sources.

A modified resistance equation for modeling underwater spark discharge with salinity and high pressure conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Pengfei; Roy, Subrata, E-mail: roy@ufl.edu

2014-05-07

This work investigates the performance of underwater spark discharge relating to bubble growth and decay under high pressure and with salinity conditions by introducing a modified form of the resistance equation. Here, we study salinity influence on circuit parameters by fitting the experimental data for which gap resistance is much larger in conductive water than in dielectric water. Accordingly, the resistance equation is modified by considering the influence of both plasma and its surrounding liquid. Thermal radiation effect of the bubble is also studied by comparing two different radiation models. Numerical results predict a larger bubble pressure for saline watermore » but a reduced size and a smaller bubble cycle at a greater water depth. Such study may be useful in many saltwater applications, including that for deep sea conditions.« less

Quantifying anthropogenic contributions to century-scale groundwater salinity changes, San Joaquin Valley, California, USA

USGS Publications Warehouse

Hansen, Jeffrey; Jurgens, Bryant; Fram, Miranda S.

2018-01-01

Total dissolved solids (TDS) concentrations in groundwater tapped for beneficial uses (drinking water, irrigation, freshwater industrial) have increased on average by about 100 mg/L over the last 100 years in the San Joaquin Valley, California (SJV). During this period land use in the SJV changed from natural vegetation and dryland agriculture to dominantly irrigated agriculture with growing urban areas. Century-scale salinity trends were evaluated by comparing TDS concentrations and major ion compositions of groundwater from wells sampled in 1910 (Historic) to data from wells sampled in 1993-2015 (Modern). TDS concentrations in subregions of the SJV, the southern (SSJV), western (WSJV), northeastern (NESJV), and southeastern (SESJV) were calculated using a cell-declustering method. TDS concentrations increased in all regions, with the greatest increases found in the SSJV and SESJV. Evaluation of the Modern data from the NESJV and SESJV found higher TDS concentrations in recently recharged (post-1950) groundwater from shallow (< 50 m) wells surrounded predominantly by agricultural land uses, while premodern (pre-1950) groundwater from deeper wells, and recently recharged groundwater from wells surrounded by mainly urban, natural, and mixed land uses had lower TDS concentrations, approaching the TDS concentrations in the Historic groundwater. For the NESJV and SESJV, inverse geochemical modeling with PHREEQC indicated that weathering of primary silicate minerals accounted for the majority of the increase in TDS concentrations, contributing more than nitrate from fertilizers and sulfate from soil amendments combined. Bicarbonate showed the greatest increase among major ions, resulting from enhanced silicate weathering due to recharge of irrigation water enriched in CO2 during the growing season. The results of this study demonstrate that large anthropogenic changes to the hydrologic regime, like massive development of irrigated agriculture in semi-arid areas like the

Quantifying anthropogenic contributions to century-scale groundwater salinity changes, San Joaquin Valley, California, USA.

PubMed

Hansen, Jeffrey A; Jurgens, Bryant C; Fram, Miranda S

2018-06-09

Total dissolved solids (TDS) concentrations in groundwater tapped for beneficial uses (drinking water, irrigation, freshwater industrial) have increased on average by about 100 mg/L over the last 100 years in the San Joaquin Valley, California (SJV). During this period land use in the SJV changed from natural vegetation and dryland agriculture to dominantly irrigated agriculture with growing urban areas. Century-scale salinity trends were evaluated by comparing TDS concentrations and major ion compositions of groundwater from wells sampled in 1910 (Historic) to data from wells sampled in 1993-2015 (Modern). TDS concentrations in subregions of the SJV, the southern (SSJV), western (WSJV), northeastern (NESJV), and southeastern (SESJV) were calculated using a cell-declustering method. TDS concentrations increased in all regions, with the greatest increases found in the SSJV and SESJV. Evaluation of the Modern data from the NESJV and SESJV found higher TDS concentrations in recently recharged (post-1950) groundwater from shallow (<50 m) wells surrounded predominantly by agricultural land uses, while premodern (pre-1950) groundwater from deeper wells, and recently recharged groundwater from wells surrounded by mainly urban, natural, and mixed land uses had lower TDS concentrations, approaching the TDS concentrations in the Historic groundwater. For the NESJV and SESJV, inverse geochemical modeling with PHREEQC indicated that weathering of primary silicate minerals accounted for the majority of the increase in TDS concentrations, contributing more than nitrate from fertilizers and sulfate from soil amendments combined. Bicarbonate showed the greatest increase among major ions, resulting from enhanced silicate weathering due to recharge of irrigation water enriched in CO 2 during the growing season. The results of this study demonstrate that large anthropogenic changes to the hydrologic regime, like massive development of irrigated agriculture in semi-arid areas

Groundwater Discharge to Upper Barataria Basin Driven by Mississippi River Stage

NASA Astrophysics Data System (ADS)

Cable, J. E.; Kim, J.; Johannesson, K. H.; Kolker, A.; Telfeyan, K.; Breaux, A.

2017-12-01

Groundwater flow into deltaic wetlands occurs despite the heterogeneous and anisotropic depositional environment of deltas. Along the Mississippi River this groundwater flow is augmented by the vast alluvial aquifer and the levees which confine the river to a zone much more narrow than the historical floodplain. The effect of the levees has been to force the river stage to as much as 10 m above the adjacent back-levee wetlands. Consequently, the head difference created by higher river stages can drive groundwater flow into these wetlands, especially during flood seasons. We measured Rn-222 in the surface waters of a bayou draining a bottomland hardwood swamp in the lower Mississippi River valley over a 14-month period. With a half-life of 3.83 days and its conservative geochemical behavior, Rn-222 is a well-known tracer for groundwater inputs in both fresh and marine environments. Transects from the mouth to the headwaters of the bayou were monitored for Rn-222 in real-time using Rad-7s on a semi-monthly basis. We found that Rn-222 decreased exponentially from the swamp at the headwaters to the mouth of the bayou. Using a mass balance approach, we calculated groundwater inputs to the bayou headwaters and compared these discharge estimates to variations in Mississippi River stage. Groundwater inputs to the Barataria Basin, Louisiana, represent a significant fraction of the freshwater budget of the basin. The flow appears to occur through the sandy Point Bar Aquifer that lies adjacent to the river and underlies many of the freshwater swamps of the Basin. Tracer measurements throughout the Basin in these swamp areas appear to confirm our hypothesis about the outlet for groundwater in this deltaic environment.

Ecosystem-groundwater interactions under changing land uses: Linking water, salts, and carbon across central Argentina

NASA Astrophysics Data System (ADS)

Jobbagy, E. G.; Nosetto, M. D.; Santoni, C. S.; Jackson, R. B.

2007-05-01

Although most ecosystems display a one-way connection with groundwater based on the regulation of deep water drainage (recharge), this link can become reciprocal when the saturated zone is shallow and plants take up groundwater (discharge). In what context is the reciprocal link most likely? How is it affected by land use changes? Has it consequences on salt and carbon cycling? We examine these questions across a precipitation gradient in the Pampas and Espinal of Argentina focusing on three vegetation change situations (mean annual rainfall): afforestation of humid (900-1300 mm) and subhumid grassland (700-900 mm/yr of rainfall), annual cultivation of subhumid grasslands (700-800 mm/yr), and annual cultivation of semiarid forests (500-700 mm). Humid and subhumid grasslands have shallow (< 5 m deep) groundwater tables that are poorly consumed by grasses but highly used by planted trees, as evidenced by satellite canopy temperatures, soil moisture and water table level records, and sapflow measurements. Groundwater contributions enhance carbon uptake in plantations compared to grasslands as suggested by aboveground biomass measurements and satellite vegetation indexes from sites with and without access to groundwater. Where rainfall is <1100 mm, grassland afforestation switches water fluxes to groundwater from positive (net recharge) to negative (net discharge) causing a salt accumulation process in soils and groundwater that is ultimately limited by the tolerance to salinity of tree species. Cultivation with corn and soybean can lead to groundwater consumption in the driest belt of subhumid grassland. Up to five-fold yield increases in lowlands vs. uplands during the driest years indicate a dramatic impact of groundwater use on carbon uptake and groundwater salinization suggests a recharge-to- discharge switch. In dry forests groundwater is not accessible (> 15 m deep) and recharge under natural conditions is null. The establishment of crops, however, triggers the

Estimates of natural ground-water discharge and characterization of water quality in Dry Valley, Washoe County, West-Central Nevada, 2002-2003

USGS Publications Warehouse

Berger, David L.; Maurer, Douglas K.; Lopes, Thomas J.; Halford, Keith J.

2004-01-01

The Dry Valley Hydrographic Area is being considered as a potential source area for additional water supplies for the Reno-Sparks area, which is about 25 miles south of Dry Valley. Current estimates of annual ground-water recharge to Dry Valley have a considerable range. In undeveloped valleys, such as Dry Valley, long-term ground-water discharge can be assumed the same as long-term ground-water recharge. Because estimating ground-water discharge has more certainty than estimating ground-water recharge from precipitation, the U.S. Geological Survey, in cooperation with Washoe County, began a three-year study to re-evaluate the ground-water resources by estimating natural ground-water discharge and characterize ground-water quality in Dry Valley. In Dry Valley, natural ground-water discharge occurs as subsurface outflow and by ground-water evapotranspiration. The amount of subsurface outflow from the upper part of Dry Valley to Winnemucca and Honey Lake Valleys likely is small. Subsurface outflow from Dry Valley westward to Long Valley, California was estimated using Darcy's Law. Analysis of two aquifer tests show the transmissivity of poorly sorted sediments near the western side of Dry Valley is 1,200 to 1,500 square feet per day. The width of unconsolidated sediments is about 4,000 feet between exposures of tuffaceous deposits along the State line, and decreases to about 1,500 feet (0.5 mile) west of the State line. The hydraulic gradient east and west of the State line ranges from 0.003 to 0.005 foot per foot. Using these values, subsurface outflow to Long Valley is estimated to be 50 to 250 acre-feet per year. Areas of ground-water evapotranspiration were field mapped and partitioned into zones of plant cover using relations derived from Landsat imagery acquired July 8, 2002. Evapotranspiration rates for each plant-cover zone were multiplied by the corresponding area and summed to estimate annual ground-water evapotranspiration. About 640 to 790 acre-feet per

Investigating the efficiency of microscale zero valent iron-based in situ reactive zone (mZVI-IRZ) for TCE removal in fresh and saline groundwater.

PubMed

Xin, Jia; Tang, Fenglin; Yan, Jing; La, Chenghong; Zheng, Xilai; Liu, Wei

2018-06-01

In this study, long-term column experiments were conducted in three media (Milli-Q water, fresh groundwater and saline groundwater) to evaluate the trichloroethylene (TCE) removal performance, electron efficiency (EE), and permeability loss of a microscale zero valent iron-based in situ reactive zone (mZVI-IRZ) under different field conditions. A potential scenario of in situ contamination plume remediation was simulated by adding a TCE-containing influent to columns filled with mixed mZVI particles and silica sand at a flow rate of 4 mL h -1 for 6 months. Results showed that, over the course of 100 pore volumes (PV) for 6 months, mZVI displayed the lowest TCE breakthrough rate (0.0026 PV -1 ) and highest TCE removal capacity (43.72 mg) but the poorest EE value (25-40%) in saline groundwater. Mineral characterization (SEM, XRD), ion concentration analysis, and geochemical modeling corroborated that different dominant solid precipitates (magnetite, siderite, dolomite/magnetite) were identified inside the three columns. The column containing saline groundwater experienced the greatest porosity loss, approximately 30.23 mL over the course of 100 PVs. This study illustrates that, to improve designs of mZVI-IRZs, EE as well as hydraulic conductivity should be taken into consideration for predictive evaluations. Copyright © 2018 Elsevier B.V. All rights reserved.

Indicators: Salinity

EPA Pesticide Factsheets

Salinity is the dissolved salt content of a body of water. Excess salinity, due to evaporation, water withdrawal, wastewater discharge, and other sources, is a chemical sterssor that can be toxic for aquatic environments.

Groundwater-derived nutrient inputs to the Upper Gulf of Thailand

NASA Astrophysics Data System (ADS)

Burnett, William C.; Wattayakorn, Gullaya; Taniguchi, Makoto; Dulaiova, Henrieta; Sojisuporn, Pramot; Rungsupa, Sompop; Ishitobi, Tomotoshi

2007-01-01

We report here the first direct measurements of nutrient fluxes via groundwater discharge into the Upper Gulf of Thailand. Nutrient and standard oceanographic surveys were conducted during the wet and dry seasons along the Chao Phraya River, Estuary and out into the Upper Gulf of Thailand. Additional measurements in selected near-shore regions of the Gulf included manual and automatic seepage meter deployments, as well as nutrient evaluations of seepage and coastal waters. The river transects characterized the distribution of biogeochemical parameters in this highly contaminated urban environment. Seepage flux measurements together with nutrient analyses of seepage fluids were used to estimate nutrient fluxes via groundwater pathways for comparison to riverine fluxes. Our findings show that disseminated seepage of nutrient-rich mostly saline groundwater into the Upper Gulf of Thailand is significant. Estimated fluxes of dissolved inorganic nitrogen (DIN) supplied via groundwater discharge were 40-50% of that delivered by the Chao Phraya River, inorganic phosphate was 60-70%, and silica was 15-40%. Dissolved organic nitrogen (DON) and phosphorus (DOP) groundwater fluxes were also high at 30-40% and 30-130% of the river inputs, respectively. These observations are especially impressive since the comparison is being made to the river that is the largest source of fresh water into the Gulf of Thailand and flows directly through the megacity of Bangkok with high nutrient loadings from industrial and domestic sources.

Geochemical behavior of Cs, Sr, Tc, Np, and U in saline groundwaters: Sorption experiments on shales and their clay mineral components: Progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyer, R.E.; Arnold, W.D.; Ho, P.C.

1987-11-01

The Sedimentary Rock Program at the Oak Ridge National Laboratory is investigating shale to determine its potential suitability as a host rock for the disposal of high-level radioactive wastes (HLW). In support of this program, preliminary studies were carried out on sorption of cesium, strontium, technetium, neptunium, and uranium onto Chattanooga (Upper Dowelltown), Pierre, Green River Formation, Nolichucky, and Pumpkin Valley Shales under oxic conditions (air present). Three simulated groundwaters were used. One of the groundwaters was a synthetic brine made up to simulate highly saline groundwaters in the Pumpkin Valley Shale. The second was a 100/1 dilution of thismore » groundwater and the third was 0.03 M NaHCO/sub 3/. Moderate to significant sorption was observed under most conditions for all of the tested radionuclides except technetium. Moderate technetium sorption occurred on Upper Dowelltown Shale, and although technetium sorption was low on the other shales, it was higher than expected for Tc(VII), present as the anion TcO/sub 4//sup -/. Little sorption of strontium onto the shales was observed from the concentrated saline groundwater. These data can be used in a generic fashion to help assess the sorption characteristics of shales in support of a national survey. 10 refs., 4 figs., 23 tabs.« less

Use of radon-222 to evaluate the influence of groundwater discharge on fecal indicator bacteria concentrations in the near-shore ocean, Malibu, California

NASA Astrophysics Data System (ADS)

Izbicki, J. A.; Burton, C.; Swarzenski, P. W.

2011-12-01

To protect beach-goers from waterborne disease, California requires water-quality monitoring for fecal indicator bacteria (FIB) at beaches having more than 50,000 visits annually. The source(s) of FIB in ocean beaches in excess of marine recreational water standards is often not known, or may be incorrectly identified. Onsite wastewater treatment systems (OWTS) used to treat residential and commercial sewage have been implicated by regulatory agencies as a possible source of FIB to recreational ocean beaches, near Malibu, California. For this to occur, treated wastewater must first move through groundwater prior to discharge at the ocean. Groundwater discharge to the ocean near Malibu Lagoon (the estuary of Malibu Creek) is complicated by seasonally changing water levels in the lagoon. The lagoon is isolated from the ocean by a sand berm that develops across the mouth of the lagoon during the dry season. Higher water levels in the lagoon during the dry season, and lower water-levels during the wet season, cause seasonal changes in the direction of groundwater flow and the magnitude of discharge from the adjacent small (3,400 hectare), alluvial aquifer. Radon-222, an indicator of groundwater discharge, was measured in Malibu Lagoon, in the near-shore ocean adjacent to the lagoon, and in the near-shore ocean adjacent to unsewered residential development to determine the timing and magnitude of groundwater discharge. During the dry season, when the berm of the lagoon was closed and the lagoon was isolated from the ocean, radon-222 concentrations in the near-shore ocean during low tide increased as water discharged from the lagoon through the berm. Enterococcus concentrations in the near-shore ocean increased to almost 600 Most Probable Number (MPN) per 100 milliliter at this time. Radon-222 concentrations also increased at low tide as groundwater discharged to the ocean from the adjacent alluvial aquifer underlying the unsewered residential development, but there was

Enrichment of fluoride in groundwater under the impact of saline water intrusion at the salt lake area of Yuncheng basin, northern China

NASA Astrophysics Data System (ADS)

Gao, Xubo; Wang, Yanxin; Li, Yilian; Guo, Qinghai

2007-12-01

Long-term intake of high-fluoride groundwater causes endemic fluorosis. This study, for the first time, discovered that the salt lake water intrusion into neighboring shallow aquifers might result in elevation of fluoride content of the groundwater. Two cross-sections along the groundwater flow paths were selected to study the geochemical processes controlling fluoride concentration in Yuncheng basin, northern China. There are two major reasons for the observed elevation of fluoride content: one is the direct contribution of the saline water; the other is the undersaturation of the groundwater with respect to fluorite due to salt water intrusion, which appears to be more important reason. The processes of the fluorine activity reduction and the change of Na/Ca ratio in groundwater induced by the intrusion of saline water favor further dissolution of fluorine-bearing mineral, and it was modeled using PHREEQC. With the increase in Na concentration (by adding NaCl or Na2SO4 as Na source, calcium content kept invariable), the increase of NaF concentration was rapid at first and then became slower; and the concentrations of HF, HF{2/-}, CaF+, and MgF+ were continuously decreasing. The geochemical conditions in the study area are advantageous to the complexation of F- with Na+ and the decline of saturation index of CaF2, regardless of the water type (Cl-Na or SO4-Na type water).

Using Heat as a Tracer to Estimate Saline Groundwater Fluxes from the Deep Aquifer System to the Shallow Aquifers and the Rio Grande in the Mesilla Basin, New Mexico, USA

NASA Astrophysics Data System (ADS)

Pepin, J. D.; Robertson, A.; Ferguson, C.; Burns, E. R.

2017-12-01

Heat is used as a tracer to estimate vertical groundwater flow and associated saline fluxes from deep (greater than 1 km) parts of the Mesilla Basin regional aquifer to the Rio Grande. Profiles of temperature with depth below ground surface are used to locate groundwater upflow zones and to estimate associated salinity fluxes. The results of this study will inform understanding of the impact of deep saline groundwater on regional water supplies. The Mesilla Basin in southern New Mexico, Texas, and Chihuahua, Mexico was designated by the U.S. as a priority transboundary aquifer in part because of the presence of the Rio Grande within the basin. Declining water levels, deteriorating water quality in both the aquifer and the river, and increasing use of water resources on both sides of the international border raise concerns about the sustainability of regional water supplies. The Rio Grande chloride concentration increases by about 130% (120 ppm to 280 ppm) as the river traverses the Mesilla Basin. Previous research attributed this reduction in water quality to the upwelling of deep sedimentary brines and geothermal waters within the basin. However, the spatial distribution of these upflow zones and their groundwater flow rates are poorly understood. Temperature profiles from 374 existing boreholes within the Mesilla Basin indicate that temperature-profile shape is affected by heat advection in the basin. Three distinct geothermal upflow zones were identified along regional fault zones in the study area based on the temperature profiles. Groundwater in these zones is considered thermal, having temperatures greater than 50°C at depths of less than 200 m. Identification of upflow-zone profiles combines analysis of temperature profiles, lithologic records, well-completion data, and profile derivatives. The Bredehoeft and Papadopulos (1965) one-dimensional heat-transport analytical solution will be applied to upflow-zone profiles to estimate the corresponding vertical

Potential effects of existing and proposed groundwater withdrawals on water levels and natural groundwater discharge in Snake Valley, Juab and Millard Counties, Utah, White Pine County, Nevada, and surrounding areas in Utah and Nevada

USGS Publications Warehouse

Masbruch, Melissa D.; Gardner, Philip M.

2014-01-01

Applications have been filed for several water-right changes and new water rights, with total withdrawals of about 1,800 acre-feet per year, in Snake Valley near Eskdale and Partoun, Utah. The Bureau of Land Management has identified 11 sites where the Bureau of Land Management holds water rights and 7 other springs of interest that could be affected by these proposed groundwater withdrawals. This report presents a hydrogeologic analysis of areas within Snake Valley to assess the potential effects on Bureau of Land Management water rights and other springs of interest resulting from existing and proposed groundwater withdrawals. A previously developed numerical groundwater-flow model was used to quantify potential groundwater drawdown and the capture, or groundwater withdrawals that results in depletion, of natural discharge resulting from existing and proposed groundwater withdrawals within Snake Valley. Existing groundwater withdrawals were simulated for a 50-year period prior to adding the newly proposed withdrawals to bring the model from pre-development conditions to the start of 2014. After this initial 50-year period, existing withdrawals, additional proposed withdrawals, and consequent effects were simulated for periods of 5, 10, 25, 50, and 100 years. Downward trends in water levels measured in wells indicate that the existing groundwater withdrawals in Snake Valley are affecting water levels. The numerical model simulated similar downward trends in water levels. The largest simulated drawdowns caused by existing groundwater withdrawals ranged between 10 and 26 feet and were near the centers of the agricultural areas by Callao, Eskdale, Baker, Garrison, and along the Utah-Nevada state line in southern Snake Valley. The largest simulated water-level declines were at the Bureau of Land Management water-rights sites near Eskdale, Utah, where simulated drawdowns ranged between 2 and 8 feet at the start of 2014. These results were consistent with, but lower

Export of excess Cl by river systems indicates long-term changes to groundwater-surface water interaction

NASA Astrophysics Data System (ADS)

Cartwright, Ian; Hofmann, Harald; Gilfedder, Ben

2013-04-01

Understanding whether catchments are in chemical mass balance is important in understand long-term groundwater-surface water interactions. The mass balance of a conservative solute such as Cl in a catchment is: P*Cl(P) = SW*Cl(SW) + GW*Cl(GW) + dST*Cl(ST) where P, SW, and GW, are net precipitation, surface water outflows, and groundwater outflows and dST accounts for changes to water held in storage, primarily in the groundwater system. Cl() is the concentration of Cl in the various water components. Precipitation and river discharges are commonly well constrained and in many regions there are also rainfall, groundwater, and surface water geochemistry data. Groundwater fluxes and changes to water in storage are less well known meaning that it is difficult to perform accurate solute balances. However, if the flux of a conservative solute out of a catchment via the river system is larger than the input from rainfall (i.e., if SW*Cl(SW) > P*Cl(P)), the catchment is a net exporter of solutes. In turn this implies a change to the amount of water stored in the catchment and/or a change in chemistry of water in storage. We apply this technique to several regional-scale catchments (areas up to 15,000 km2) from Victoria, southeast Australia. Cl/Br ratios indicate that the Cl in groundwater and surface water in this region is derived from evapotranspiration of rainfall. Rivers from several catchments in Victoria are saline (Cl >500 mg/L) due mainly to groundwater inflows. Cl concentrations and EC values are well correlated allowing a long-term (up to 25 years) continual record of Cl fluxes to be estimated from sub-daily river discharge and EC data. Many of the rivers export significantly higher volumes of Cl than is delivered via rainfall (up to 1800%). Two scenarios may explain this chemical imbalance. Firstly, saline marshes and lakes developed on young (<1 Ma) basaltic lava plains have gradually drained as blocked river systems re-established. Evapotranspiration and

Seasonal arsenic accumulation in stream sediments at a groundwater discharge zone.

PubMed

MacKay, Allison A; Gan, Ping; Yu, Ran; Smets, Barth F

2014-01-21

Seasonal changes in arsenic and iron accumulation rates were examined in the sediments of a brook that receives groundwater discharges of arsenic and reduced iron. Clean glass bead columns were deployed in sediments for known periods over the annual hydrologic cycle to monitor changes in arsenic and iron concentrations in bead coatings. The highest accumulation rates occurred during the dry summer period (July-October) when groundwater discharges were likely greatest at the sample locations. The intermediate flow period (October-March), with higher surface water levels, was associated with losses of arsenic and iron from bead column coatings at depths below 2-6 cm. Batch incubations indicated iron releases from solids to be induced by biological reduction of iron (oxy)hydroxide solids. Congruent arsenic releases during incubation were limited by the high arsenic sorption capacity (0.536 mg(As)/mg(Fe)) of unreacted iron oxide solids. The flooded spring (March-June) with high surface water flows showed the lowest arsenic and iron accumulation rates in the sediments. Comparisons of accumulation rates across a shoreline transect were consistent with greater rates at regions exposed above surface water levels for longer times and greater losses at locations submerged below surface water. Iron (oxy)hydroxide solids in the shallowest sediments likely serve as a passive barrier to sorb arsenic released to pore water at depth by biological iron reduction.

Quantity and quality of ground-water discharge to the South Platte River, Denver to Fort Lupton, Colorado, August 1992 through July 1993

USGS Publications Warehouse

McMahon, P.B.; Lull, K.J.; Dennehy, K.F.; Collins, J.A.

1995-01-01

Water-quality studies conducted by the Metro Wastewater Reclamation District have indicated that during low flow in segments of the South Platte River between Denver and Fort Lupton, concentrations of dissolved oxygen are less than minimum concen- trations set by the State of Colorado. Low dissolved-oxygen concentrations are observed in two reaches of the river-they are about 3.3 to 6.4 miles and 17 to 25 miles downstream from the Metro Waste- water Reclamation District effluent outfalls. Concentrations of dissolved oxygen recover between these two reaches. Studies conducted by the U.S. Geological Survey have indicated that ground-water discharge to the river may contribute to these low dissolved-oxygen concentrations. As a result, an assessment was made of the quantity and quality of ground-water discharge to the South Platte River from Denver to Fort Lupton. Measurements of surface- water and ground-water discharge and collections of surface water and ground water for water-quality analyses were made from August 1992 through January 1993 and in May and July 1993. The quantity of ground-water discharge to the South Platte River was determined indirectly by mass balance of surface-water inflows and outflows and directly by instantaneous measurements of ground-water discharge across the sediment/water interface in the river channel. The quality of surface water and ground water was determined by sampling and analysis of water from the river and monitoring wells screened in the alluvial aquifer adjacent to the river and by sampling and analysis of water from piezometers screened in sediments underlying the river channel. The ground-water flow system was subdivided into a large-area and a small-area flow system. The precise boundaries of the two flow systems are not known. However, the large-area flow system is considered to incorporate all alluvial sediments in hydrologic connection with the South Platte River. The small- area flow system is considered to incorporate

Modelling the salinization of a coastal lagoon-aquifer system

NASA Astrophysics Data System (ADS)

Colombani, N.; Mastrocicco, M.

2017-08-01

In this study, a coastal area constituted by alternations of saline-brackish lagoons and freshwater bodies was studied and modelled to understand the hydrological processes occurring between the lagoons, the groundwater system of the Po River Delta (Italy) and the Adriatic Sea. The contribution of both evaporation and anthropogenic factors on groundwater salinization was assessed by means of soil, groundwater and surface water monitoring. Highresolution multi-level samplers were used to capture salinity gradients within the aquifer and surface water bodies. Data were employed to calibrate a density-dependent numerical transport model implemented with SEAWAT code along a transect perpendicular to the coast line. The results show that the lagoon is hydraulically well connected with the aquifer, which provides the major source of salinity because of the upcoming of paleo-seawater from the aquitard laying at the base of the unconfined aquifer. On the contrary, the seawater (diluted by the freshwater river outflow) creates only a limited saltwater wedge. The increase in groundwater salinity could be of serious concern, especially for the pinewood located in the dune near the coast, sensitive to salinity increases. This case study represents an interesting paradigm for other similar environmental setting, where the assumption of classical aquifer salinization from a saltwater wedge intruding from the sea is often not representative of the actual aquifer’s salinization mechanisms.

Mapping of road-salt-contaminated groundwater discharge and estimation of chloride load to a small stream in southern New Hampshire, USA

USGS Publications Warehouse

Harte, P.T.; Trowbridge, P.R.

2010-01-01

Concentrations of chloride in excess of State of New Hampshire water-quality standards (230 mg/l) have been measured in watersheds adjacent to an interstate highway (I-93) in southern New Hampshire. A proposed widening plan for I-93 has raised concerns over further increases in chloride. As part of this effort, road-salt-contaminated groundwater discharge was mapped with terrain electrical conductivity (EC) electromagnetic (EM) methods in the fall of 2006 to identify potential sources of chloride during base-flow conditions to a small stream, Policy Brook. Three different EM meters were used to measure different depths below the streambed (ranging from 0 to 3 m). Results from the three meters showed similar patterns and identified several reaches where high EC groundwater may have been discharging. Based on the delineation of high (up to 350 mmhos/m) apparent terrain EC, seven-streambed piezometers were installed to sample shallow groundwater. Locations with high specific conductance in shallow groundwater (up to 2630 mmhos/m) generally matched locations with high streambed (shallow subsurface) terrain EC. A regression equation was used to convert the terrain EC of the streambed to an equivalent chloride concentration in shallow groundwater unique for this site. Utilizing the regression equation and estimates of onedimensional Darcian flow through the streambed, a maximum potential groundwater chloride load was estimated at 188 Mg of chloride per year. Changes in chloride concentration in stream water during streamflow recessions showed a linear response that indicates the dominant process affecting chloride is advective flow of chloride-enriched groundwater discharge. Published in 2010 by John Wiley & Sons, Ltd.

The influence of submarine groundwater discharge on greenhouse gas evasion from coastal waters (Invited)

NASA Astrophysics Data System (ADS)

Santos, I. R.

2013-12-01

Coastal waters are thought to play a major role on global carbon budgets but we still lack a quantitative understanding about some mechanisms driving greenhouse gas cycling in coastal waters. Very little is known about the role of submarine groundwater discharge (SGD) in delivering carbon to rivers, estuaries and coastal waters even though the concentrations of most carbon species in groundwater are often much higher than those in surface waters. I hypothesize that SGD plays a significant role in coastal carbon and greenhouse gas budgets even if the volumetric SGD contribution is small. I will report new, detailed observations of radon (a natural groundwater tracer) and carbon dioxide and methane concentrations and stable isotopes in tidal rivers, estuaries, coastal wetlands, mangroves and coral reef lagoons. Groundwater exchange at these contrasting sites was driven by a wide range of processes, including terrestrial hydraulic gradients, tidal pumping, and convection. In all systems, SGD was an important source of carbon dioxide, DIC, and methane to surface waters. In some cases, groundwater seepage alone could account for 100% of carbon dioxide evasion from surface waters to the atmosphere. Combining high precision in situ radon and greenhouse gas concentration and stable isotope observations allows for an effective, unambiguous assessment of how groundwater seepage drives carbon dynamics in surface waters.

Nitrate retention in a sand plains stream and the importance of groundwater discharge

Treesearch

Robert S. Stelzer; Damion R. Drover; Susan L. Eggert; Maureen A. Muldoon

2011-01-01

We measured net nitrate retention by mass balance in a 700-m upwelling reach of a third-order sand plains stream, Emmons Creek, from January 2007 to November 2008. Surface water and ground-water fluxes of nitrate were determined from continuous records of discharge and from nitrate concentrations based on weekly and biweekly sampling at three surface water stations and...

Brackish groundwater in the United States

USGS Publications Warehouse

Stanton, Jennifer S.; Anning, David W.; Brown, Craig J.; Moore, Richard B.; McGuire, Virginia L.; Qi, Sharon L.; Harris, Alta C.; Dennehy, Kevin F.; McMahon, Peter B.; Degnan, James R.; Böhlke, John Karl

2017-04-05

For some parts of the Nation, large-scale development of groundwater has caused decreases in the amount of groundwater that is present in aquifer storage and that discharges to surface-water bodies. Water supply in some areas, particularly in arid and semiarid regions, is not adequate to meet demand, and severe drought is affecting large parts of the United States. Future water demand is projected to heighten the current stress on groundwater resources. This combination of factors has led to concerns about the availability of freshwater to meet domestic, agricultural, industrial, mining, and environmental needs. To ensure the water security of the Nation, currently [2016] untapped water sources may need to be developed.Brackish groundwater is an unconventional water source that may offer a partial solution to current and future water demands. In support of the national census of water resources, the U.S. Geological Survey completed the national brackish groundwater assessment to better understand the occurrence and characteristics of brackish groundwater in the United States as a potential water resource. Analyses completed as part of this assessment relied on previously collected data from multiple sources; no new data were collected. Compiled data included readily available information about groundwater chemistry, horizontal and vertical extents and hydrogeologic characteristics of principal aquifers (regionally extensive aquifers or aquifer systems that have the potential to be used as a source of potable water), and groundwater use. Although these data were obtained from a wide variety of sources, the compiled data are biased toward shallow and fresh groundwater resources; data representing groundwater that is at great depths and is saline were not as readily available.One of the most important contributions of this assessment is the creation of a database containing chemical characteristics and aquifer information for the known areas with brackish groundwater

Spatial Patterns of Groundwater Biogeochemical Reactivity in an Intertidal Beach Aquifer

NASA Astrophysics Data System (ADS)

Kim, Kyra H.; Heiss, James W.; Michael, Holly A.; Cai, Wei-Jun; Laattoe, Tariq; Post, Vincent E. A.; Ullman, William J.

2017-10-01

Beach aquifers host a dynamic and reactive mixing zone between fresh and saline groundwater of contrasting origin and composition. Seawater, driven up the beachface by waves and tides, infiltrates into the aquifer and meets the seaward-discharging fresh groundwater, creating and maintaining a reactive intertidal circulation cell. Within the cell, land-derived nutrients delivered by fresh groundwater are transformed or attenuated. We investigated this process by collecting pore water samples from multilevel wells along a shore-perpendicular transect on a beach near Cape Henlopen, Delaware, and analyzing solute and particulate concentrations. Pore water incubation experiments were conducted to determine rates of oxygen consumption and nitrogen gas production. A numerical model was employed to support field and laboratory interpretations. Results showed that chemically sensitive parameters such as pH and ORP diverged from salinity distribution patterns, indicating biogeochemical reactivity within the circulation cell. The highest respiration rates were found in the landward freshwater-saltwater mixing zone, supported by high dissolved inorganic carbon. Chlorophyll a, a proxy for phytoplankton, and particulate carbon did not co-occur with the highest respiration rates but were heterogeneously distributed in deeper and hypoxic areas of the cell. The highest rates of N2 production were also found in the mixing zone coinciding with elevated O2 consumption rates but closer to the lower discharge point. Model results were consistent with these observations, showing heightened denitrification in the mixing zone. The results of this work emphasize the relationship between the physical flow processes of the circulation cell and its biogeochemical reactivity and highlight the environmental significance of sandy beaches.

Hydrological and geochemical processes constraining groundwater salinity in wetland areas related to evaporitic (karst) systems. A case study from Southern Spain

NASA Astrophysics Data System (ADS)

Gil-Márquez, J. M.; Barberá, J. A.; Andreo, B.; Mudarra, M.

2017-01-01

Chemical and isotopic evolution of groundwater in an evaporite karst plateau (including wetland areas and saline to hyper-saline springs) located at S Spain was studied. Physicochemical parameters, major ions and stable isotopes were analyzed in rain, brine spring, wetland and leakage water samples, from which the most common mineral saturation indexes were computed and geochemical and isotopic modelling were performed. Results show an apparent relationship between the elevation of brine springs and their water mineralization, indicating that drainage at higher altitude may be associated to gravity-driven flows, since brackish groundwater is isotopically fractionated due to evaporation. On the other hand, the lower altitude springs could drain deeper flows with longer residence time, resulting in highly mineralized and warmer (briny) groundwater. The dissolution of halite and gypsum has proved to be the main geochemical processes, which are favored by the great ionic strength of groundwater. Calcite precipitation occurs in brackish waters draining wetlands, being boosted by common ion effect (when CaSO4 waters are present) and solute concentration caused by evaporation. Modelling results strongly support the hypothesis that most of the selected springs geochemically evolve in a common (S-N) flowpath. The methods used in this research contribute to a better understanding of the hydrogeological processes occurring in the studied evaporitic system, but also in equivalent hydrological environments worldwide.

Joint Inversion of Multi-type and Time-lapse Airborne Electromagnetic Data Sets for Tempo-spatial Variation of Groundwater Salinity

NASA Astrophysics Data System (ADS)

Yang, D.; Oldenburg, D.

2016-12-01

The salinization of the floodplains of Lower Murray River in South Australia has caused negative consequences to the local ecosystem. As part of the Living Murray Initiative, the Clark's Floodplain at Bookpurnong was chosen to examine the effectiveness of different intervention methods from 2005 to 2008. Because of the link between groundwater salinity and electric conductivity, electromagnetic (EM) methods have been an integrated part of the project to test it as a cost-effective tool for monitoring. In this paper, we analyze two airborne EM surveys that assess the salinization at the regional scale: the SkyTEM in 2006 and the RESOLVE in 2008. Conventional interpretation often inverts those data sets separately using the 1D layered earth modeling, which often produces inconsistent images if different surveys are carried out at different times. Here we propose a new approach that considers the coherence in time and across systems. We allow each data set to iteratively construct its own model with guidance from a common reference model that is updated in a democratic voting procedure after every iteration. There are two possible outcomes. If the data sets are intrinsically compatible, the individual models will converge to essentially the same model, like in the regular unimodal joint inversion. If there are survey-specific errors or a change of ground truth, the inversion can still fit the data but leaves discrepancy in the models. By applying this approach to the two data sets at Bookpurnong, we identify an area of increased conductivity at the midstream section of the river that can only be explained by a temporal variation of salinity, a plausible evidence of escalated saline water intrusion due to irrigation on the nearby riverbank. This study illustrates that multi-type time-lapse EM, in conjunction with advanced inversion techniques, can achieve superior temporal resolution for the purpose of groundwater evaluation and management.

A multi-method approach for groundwater resource assessment in coastal carbonate (karst) aquifers: the case study of Sierra Almijara (southern Spain)

NASA Astrophysics Data System (ADS)

Andreo, B.; Barberá, J. A.; Mudarra, M.; Marín, A. I.; García-Orellana, J.; Rodellas, V.; Pérez, I.

2018-02-01

Understanding the transference of water resources within hydrogeological systems, particularly in coastal aquifers, in which groundwater discharge may occur through multiple pathways (through springs, into rivers and streams, towards the sea, etc.), is crucial for sustainable groundwater use. This research aims to demonstrate the usefulness of the application of conventional recharge assessment methods coupled to isotopic techniques for accurately quantifying the hydrogeological balance and submarine groundwater discharge (SGD) from coastal carbonate aquifers. Sierra Almijara (Southern Spain), a carbonate aquifer formed of Triassic marbles, is considered as representative of Mediterranean coastal karst formations. The use of a multi-method approach has permitted the computation of a wide range of groundwater infiltration rates (17-60%) by means of direct application of hydrometeorological methods (Thornthwaite and Kessler) and spatially distributed information (modified APLIS method). A spatially weighted recharge rate of 42% results from the most coherent information on physiographic and hydrogeological characteristics of the studied system. Natural aquifer discharge and groundwater abstraction have been volumetrically quantified, based on flow and water-level data, while the relevance of SGD was estimated from the spatial analysis of salinity, 222Rn and the short-lived radium isotope 224Ra in coastal seawater. The total mean aquifer discharge (44.9-45.9 hm3 year-1) is in agreement with the average recharged groundwater (44.7 hm3 year-1), given that the system is volumetrically equilibrated during the study period. Besides the groundwater resources assessment, the methodological aspects of this research may be interesting for groundwater management and protection strategies in coastal areas, particularly karst environments.

Evaluation of Geophysical and Thermal Methods for Detecting Submarine Groundwater Discharge (SGD) in the Suwannee River Estuary

NASA Astrophysics Data System (ADS)

Weiss, M.; Kruse, S.; Burnett, W. C.; Chanton, J.; Greenwood, W.; Murray, M.; Peterson, R.; Swarzenski, P.

2005-12-01

In an effort to evaluate geophysical and thermal methods for detecting submarine groundwater discharge (SGD) on the Florida Gulf coast, a suite of water-borne surveys were run in conjunction with aerial thermal imagery over the lower Suwannee estuary in March 2005. Marine resistivity streaming data were collected alongside continuous radon and methane sampling from surface waters. Resistivity measurements were collected with dipole-dipole geometries. Readings were inverted for terrain resistivity assuming two-dimensional structure and constraining uppermost layers to conform to measured water depths and surface water conductivities. Thermal images were collected at the end of winter and at night to maximize temperatures between warmer discharging groundwater and colder surface waters. For the preliminary data analysis presented here, we assume high radon and methane concentrations coincide with zones of high SGD, and look at relationships between radon and methane concentrations and terrain resistivity and thermal imagery intensity values. For a limited set of coincident thermal intensity and radon readings, thermal intensities are higher at sites with the highest radon readings. These preliminary results suggest that in this environment, thermal imagery may be effective for identifying the "hottest" spots for SGD, but not for zones of diffuse discharge. The thermal imagery shows high intensity features at the heads of tidal streams, but shallow water depths precluded boat-based resistivity and sampling at these sites. Shallow terrain resistivities generally show a positive correlation with methane concentrations, as would be expected over zones of discharging groundwater that is fresher than Gulf surface water.

Hurricanes, submarine groundwater discharge, and Florida's red tides

NASA Astrophysics Data System (ADS)

Hu, Chuanmin; Muller-Karger, Frank E.; Swarzenski, Peter W.

2006-06-01

A Karenia brevis Harmful Algal Bloom affected coastal waters shallower than 50 m off west-central Florida from January 2005 through January 2006, showing a sustained anomaly of ~1 mg chlorophyll m-3 over an area of up to 67,500 km2. Red tides occur in the same area (approximately 26-29°N, 82-83°W) almost every year, but the intense 2005 bloom led to a widespread hypoxic zone (dissolved oxygen <2 mg L-1) that caused mortalities of benthic communities, fish, turtles, birds, and marine mammals. Runoff alone provided insufficient nitrogen to support this bloom. We pose the hypothesis that submarine groundwater discharge (SGD) provides the missing nutrients, and indeed can trigger and support the recurrent red tides off west-central Florida. SGD inputs of dissolved inorganic nitrogen (DIN) in Tampa Bay alone are ~35% of that discharged by all central Florida rivers draining west combined. We propose that the unusual number of hurricanes in 2004 resulted in high runoff, and in higher than normal SGD emerging along the west Florida coast throughout 2005, initiating and fueling the persistent HAB. This mechanism may also explain recurrent red tides in other coastal regions of the Gulf of Mexico.

Hurricanes, submarine groundwater discharge, and Florida's red tides

USGS Publications Warehouse

Hu, C.; Muller-Karger, F. E.; Swarzenski, P.W.

2006-01-01

A Karenia brevis Harmful Algal Bloom affected coastal waters shallower than 50 m off west-central Florida from January 2005 through January 2006, showing a sustained anomaly of ???1 mg chlorophyll m-3 over an area of up to 67,500 km2. Red tides occur in the same area (approximately 26-29??N, 82-83??W) almost every year, but the intense 2005 bloom led to a widespread hypoxic zone (dissolved oxygen <2 mg L-1) that caused mortalities of benthic communities, fish, turtles, birds, and marine mammals. Runoff alone provided insufficient nitrogen to support this bloom. We pose the hypothesis that submarine groundwater discharge (SGD) provides the missing nutrients, and indeed can trigger and support the recurrent red tides off west-central Florida. SGD inputs of dissolved inorganic nitrogen (DIN) in Tampa Bay alone are ???35% of that discharged by all central Florida rivers draining west combined. We propose that the unusual number of hurricanes in 2004 resulted in high runoff, and in higher than normal SGD emerging along the west Florida coast throughout 2005, initiating and fueling the persistent HAB. This mechanism may also explain recurrent red tides in other coastal regions of the Gulf of Mexico. Copyright 2006 by the American Geophysical Union.

Investigation of Submarine Groundwater Discharge and Preferential Groundwater Flow-paths in a Coastal Karst Area using towed Marine and Terrestrial Electrical Resistivity

NASA Astrophysics Data System (ADS)

O'connell, Y.; Daly, E.; Duffy, G.; Henry, T.

2012-12-01

Large volumes of groundwater, containing nutrients and contaminants enter the coastal waters of southern Galway Bay on the west coast of Ireland through submarine groundwater discharge (SGD). The SGD occurs through karstified Carboniferous limestone in a major karst region comprising the Burren and Gort Lowlands. The Carboniferous limestones have experienced extensive dissolution resulting in the development of an underground network of conduits and fissures that define a trimodal groundwater flow pattern across the region. Groundwater discharge to the sea in this area is exclusively intertidal and submarine. Storage in the karst is limited and typical winter rainfall conditions result in the karst system becoming saturated. Temporary lakes (turloughs) form in lowlying areas and act as large reservoirs which provide storage to enable the transmission of the large volumes of water in the system to the sea. Between 2010 and 2012, terrestrial and shallow marine geophysical surveying has been undertaken to investigate preferential groundwater flow-paths and SGD locations in order to quantify the groundwater-seawater interactions in this coastal karst system. A report into the groundwater system of this karst region following a major flood event proposed a conceptual conduit model defined by extensive water tracing, water level monitoring, hydrochemical sampling, geological mapping and drilling. Limited information about the dimensions of the conduits was known. Electrical resistivity tomography (ERT) profiling to depths of 100m below ground level, with multiple array configurations, has been carried out to investigate the modes of groundwater flow in to and out of both temporary and permanent freshwater lakes in the system. Towed dipole-dipole profiles have been recorded to investigate conduits beneath a permanent lake exhibiting a tidal influence despite its location 5.5 km from the seashore. The ERT data indicates significant variations in subsurface resistivities

Strategies for implementing zero discharge in an industrial smelter : 1. Managing fluroide in groundwater

NASA Astrophysics Data System (ADS)

Stagnitti, F.; Salzman, S.; Thwaites, L.; Allinson, G.; Le Blanc, M.; Hill, J.; Doerr, S.; de Rooij, G.

2003-04-01

The Portland Aluminium smelter produces approximately 75 ML of process wastewater each year. This is combined with storm water runoff from the site to give an annual production of 715 ML. In common with many other smelters, this wastewater stream is currently discharged to the ocean. However, although the quality of the water Portland Aluminium discharges currently meets all Australian Environmental Protection Agency license requirements, this mode of release is unlikely to be acceptable in the near future, and alternative disposal options for the water are required. The Portland smelter has developed strategies which will enable it to achieve zero-discharge within 5 years. These strategies include separating process water from storm water, recycling storm water, construction of evaporation ponds to receive process water, irrigation of process water and storm water on lands within the site and maintenance of important wetland functions. The poster presents a summary of the management strategies currently being trialed and in particular focuses on modeling the spatial and temporal variations of fluoride found in the shallow groundwater and the implications of achieving zero-discharge. The poster also discusses the possible impacts on the distribution of fluoride and other solutes in the vadose zone by the irrigation of treated process water on blue-gum plantations. Computer simulations indicate that irrigation of process water (either treated or untreated) on the land poses no significant long-term threat to regional or surficial groundwater. However the impacts of increased solute transport through the vadose zone on changes in soil structure and nutrition require further investigation.

Remediation of the Highland Drive South Ravine, Port Hope, Ontario: Contaminated Groundwater Discharge Management Using Permeable Reactive Barriers and Contaminated Sediment Removal - 13447

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smyth, David; Roos, Gillian; Ferguson Jones, Andrea

2013-07-01

The Highland Drive South Ravine (HDSR) is the discharge area for groundwater originating from the Highland Drive Landfill, the Pine Street North Extension (PSNE) roadbed parts of the Highland Drive roadbed and the PSNE Consolidation Site that contain historical low-level radioactive waste (LLRW). The contaminant plume from these LLRW sites contains elevated concentrations of uranium and arsenic and discharges with groundwater to shallow soils in a wet discharge area within the ravine, and directly to Hunt's Pond and Highland Drive South Creek, which are immediately to the south of the wet discharge area. Remediation and environmental management plans for HDSRmore » have been developed within the framework of the Port Hope Project and the Port Hope Area Initiative. The LLRW sites will be fully remediated by excavation and relocation to a new Long-Term Waste Management Facility (LTWMF) as part of the Port Hope Project. It is projected, however, that the groundwater contaminant plume between the remediated LLRW sites and HDSR will persist for several hundreds of years. At the HDSR, sediment remediation within Hunt's Ponds and Highland Drive South Creek, excavation of the existing and placement of clean fill will be undertaken to remove current accumulations of solid-phase uranium and arsenic associated with the upper 0.75 m of soil in the wet discharge area, and permeable reactive barriers (PRBs) will be used for in situ treatment of contaminated groundwater to prevent the ongoing discharge of uranium and arsenic to the area in HDSR where shallow soil excavation and replacement has been undertaken. Bench-scale testing using groundwater from HDSR has confirmed excellent treatment characteristics for both uranium and arsenic using permeable reactive mixtures containing granular zero-valent iron (ZVI). A sequence of three PRBs containing ZVI and sand in backfilled trenches has been designed to intercept the groundwater flow system prior to its discharge to the ground

Using remote sensing and GIS techniques to estimate discharge and recharge fluxes for the Death Valley regional groundwater flow system, USA

USGS Publications Warehouse

D'Agnese, F. A.; Faunt, C.C.; Turner, A.K.; ,

1996-01-01

The recharge and discharge components of the Death Valley regional groundwater flow system were defined by techniques that integrated disparate data types to develop a spatially complex representation of near-surface hydrological processes. Image classification methods were applied to multispectral satellite data to produce a vegetation map. The vegetation map was combined with ancillary data in a GIS to delineate different types of wetlands, phreatophytes and wet playa areas. Existing evapotranspiration-rate estimates were used to calculate discharge volumes for these area. An empirical method of groundwater recharge estimation was modified to incorporate data describing soil-moisture conditions, and a recharge potential map was produced. These discharge and recharge maps were readily converted to data arrays for numerical modelling codes. Inverse parameter estimation techniques also used these data to evaluate the reliability and sensitivity of estimated values.The recharge and discharge components of the Death Valley regional groundwater flow system were defined by remote sensing and GIS techniques that integrated disparate data types to develop a spatially complex representation of near-surface hydrological processes. Image classification methods were applied to multispectral satellite data to produce a vegetation map. This map provided a basis for subsequent evapotranspiration and infiltration estimations. The vegetation map was combined with ancillary data in a GIS to delineate different types of wetlands, phreatophytes and wet playa areas. Existing evapotranspiration-rate estimates were then used to calculate discharge volumes for these areas. A previously used empirical method of groundwater recharge estimation was modified by GIS methods to incorporate data describing soil-moisture conditions, and a recharge potential map was produced. These discharge and recharge maps were readily converted to data arrays for numerical modelling codes. Inverse parameter

Evaluating the human impact on groundwater quality discharging into a coastal reef lagoon

NASA Astrophysics Data System (ADS)

Rebolledo-Vieyra, M.; Hernandez-Terrones, L.; Soto, M.; Lecossec, A.; Monroy-Rios, E.

2008-12-01

The Eastern coast of the Yucatan Peninsula has the fastest growth rate in Mexico and groundwater is the only source of drinking water in the region. The consequences of the lack of proper infrastructure to collect and treat wastewater and the impact of human activities on the quality of groundwater are addressed. The groundwater in the coastal aquifer of Quintana Roo (SE Mexico) discharges directly into the ocean. In addition, the coral reef of the Eastern Yucatan Peninsula is part of the Mesoamerican Coral Reef System, one of the largest in the world. The interaction of the reef-lagoon hydraulics with the coastal aquifer of Puerto Morelos (NE Yucatan Peninsula), and a major input of NH4, SO4, SiO2, as a consequence of the use of septic tanks and the lack of modern wastewater treatment plants are presented. No seasonal parameters differences were observed, suggesting that groundwater composition reaching the reef lagoon is not changing seasonally. A conceptual model of the coastal aquifer was developed, in order to explain how the human activities are impacting directly on the groundwater quality that, potentially, will have a direct impact on the coral reef. The protection and conservation of coral reefs must be directly related with a policy of sound management of coastal aquifers and wastewater treatment.

Relations Between Coastal Catchment Attributes and Submarine Groundwater Discharge at Different Scales

NASA Astrophysics Data System (ADS)

Moosdorf, N.; Langlotz, S. T.

2016-02-01

Submarine groundwater discharge (SGD) has been recognized as a relevant field of coastal research in the last years. Its implications on local scale have been documented by an increasing number of studies researching individual locations with SGD. The local studies also often emphasize its large variability. On the other end, global scale studies try to estimate SGD related fluxes of e.g. carbon (Cole et al., 2007) and nitrogen (Beusen et al., 2013). These studies naturally use a coarse resolution, too coarse to represent the aforementioned local variability of SGD (Moosdorf et al., 2015). A way to transfer information of the local variability of SGD to large scale flux estimates is needed. Here we discuss the upscaling of local studies based on the definition and typology of coastal catchments. Coastal catchments are those stretches of coast that do not drain into major rivers but directly into the sea. Their attributes, e.g. climate, topography, land cover, or lithology can be used to extrapolate from the local scale to larger scales. We present first results of a typology, compare coastal catchment attributes to SGD estimates from field studies and discuss upscaling as well as the associated uncertainties. This study aims at bridging the gap between the scales and enabling an improved representation of local scale variability on continental to global scale. With this, it can contribute to a recent initiative to model large scale SGD fluxes (NExT SGD). References: Beusen, A.H.W., Slomp, C.P., Bouwman, A.F., 2013. Global land-ocean linkage: direct inputs of nitrogen to coastal waters via submarine groundwater discharge. Environmental Research Letters, 8(3): 6. Cole, J.J., Prairie, Y.T., Caraco, N.F., McDowell, W.H., Tranvik, L.J., Striegl, R.G., Duarte, C.M., Kortelainen, P., Downing, J.A., Middelburg, J.J., Melack, J., 2007. Plumbing the global carbon cycle: Integrating inland waters into the terrestrial carbon budget. Ecosystems, 10(1): 171-184. Moosdorf, N

Evaluating long-term patterns of decreasing groundwater discharge through a lake-bottom permeable reactive barrier.