sand batch tests: Topics by Science.gov

Sample records for sand batch tests

Batch Tests To Determine Activity Distribution and Kinetic Parameters for Acetate Utilization in Expanded-Bed Anaerobic Reactors

PubMed Central

Fox, Peter; Suidan, Makram T.

1990-01-01

Batch tests to measure maximum acetate utilization rates were used to determine the distribution of acetate utilizers in expanded-bed sand and expanded-bed granular activated carbon (GAC) reactors. The reactors were fed a mixture of acetate and 3-ethylphenol, and they contained the same predominant aceticlastic methanogen, Methanothrix sp. Batch tests were performed both on the entire reactor contents and with media removed from the reactors. Results indicated that activity was evenly distributed within the GAC reactors, whereas in the sand reactor a sludge blanket on top of the sand bed contained approximately 50% of the activity. The Monod half-velocity constant (Ks) for the acetate-utilizing methanogens in two expanded-bed GAC reactors was searched for by combining steady-state results with batch test data. All parameters necessary to develop a model with Monod kinetics were experimentally determined except for Ks. However, Ks was a function of the effluent 3-ethylphenol concentration, and batch test results demonstrated that maximum acetate utilization rates were not a function of the effluent 3-ethylphenol concentration. Addition of a competitive inhibition term into the Monod expression predicted the dependence of Ks on the effluent 3-ethylphenol concentration. A two-parameter search determined a Ks of 8.99 mg of acetate per liter and a Ki of 2.41 mg of 3-ethylphenol per liter. Model predictions were in agreement with experimental observations for all effluent 3-ethylphenol concentrations. Batch tests measured the activity for a specific substrate and determined the distribution of activity in the reactor. The use of steady-state data in conjunction with batch test results reduced the number of unknown kinetic parameters and thereby reduced the uncertainty in the results and the assumptions made. PMID:16348175
Batch tests to determine activity distribution and kinetic parameters for acetate utilization in expanded-bed anaerobic reactors.

PubMed

Fox, P; Suidan, M T

1990-04-01

Batch tests to measure maximum acetate utilization rates were used to determine the distribution of acetate utilizers in expanded-bed sand and expanded-bed granular activated carbon (GAC) reactors. The reactors were fed a mixture of acetate and 3-ethylphenol, and they contained the same predominant aceticlastic methanogen, Methanothrix sp. Batch tests were performed both on the entire reactor contents and with media removed from the reactors. Results indicated that activity was evenly distributed within the GAC reactors, whereas in the sand reactor a sludge blanket on top of the sand bed contained approximately 50% of the activity. The Monod half-velocity constant (K(s)) for the acetate-utilizing methanogens in two expanded-bed GAC reactors was searched for by combining steady-state results with batch test data. All parameters necessary to develop a model with Monod kinetics were experimentally determined except for K(s). However, K(s) was a function of the effluent 3-ethylphenol concentration, and batch test results demonstrated that maximum acetate utilization rates were not a function of the effluent 3-ethylphenol concentration. Addition of a competitive inhibition term into the Monod expression predicted the dependence of K(s) on the effluent 3-ethylphenol concentration. A two-parameter search determined a K(s) of 8.99 mg of acetate per liter and a K(i) of 2.41 mg of 3-ethylphenol per liter. Model predictions were in agreement with experimental observations for all effluent 3-ethylphenol concentrations. Batch tests measured the activity for a specific substrate and determined the distribution of activity in the reactor. The use of steady-state data in conjunction with batch test results reduced the number of unknown kinetic parameters and thereby reduced the uncertainty in the results and the assumptions made.
Techniques employed by the NASA White Sands Test Facility to ensure oxygen system component safety

NASA Technical Reports Server (NTRS)

Stradling, J. S.; Pippen, D. L.; Frye, G. W.

1983-01-01

Methods of ascertaining the safety and suitability of a variety of oxygen system components are discussed. Additionally, qualification and batch control requirements for soft goods in oxygen systems are presented. Current oxygen system component qualification test activities in progress at White Sands Test Facility are described.
Axisymmetric Strain Path Tests on Nellis Baseline Sand

DTIC Science & Technology

1986-09-01

tested to determine their grain-size distributions, specific gravities , and Atterberg limits. The results of these tests are su-Arized in Table 2.1...plastic limits, plasticity index, and specific gravity . All four batches of NB sand were classified by the Unified Soil Classi- fication System...those contaminated by oil due to membrane leakage. Based on these data and a specific gravity of 2.62, values of dry density, void ratio, degree of
Bacterial, viral and turbidity removal by intermittent slow sand filtration for household use in developing countries: experimental investigation and modeling.

PubMed

Jenkins, Marion W; Tiwari, Sangam K; Darby, Jeannie

2011-11-15

A two-factor three-block experimental design was developed to permit rigorous evaluation and modeling of the main effects and interactions of sand size (d(10) of 0.17 and 0.52 mm) and hydraulic head (10, 20, and 30 cm) on removal of fecal coliform (FC) bacteria, MS2 bacteriophage virus, and turbidity, under two batch operating modes ('long' and 'short') in intermittent slow sand filters (ISSFs). Long operation involved an overnight pause time between feeding of two successive 20 L batches (16 h average batch residence time (RT)). Short operation involved no pause between two 20 L batch feeds (5h average batch RT). Conditions tested were representative of those encountered in developing country field settings. Over a ten week period, the 18 experimental filters were fed river water augmented with wastewater (influent turbidity of 5.4-58.6 NTU) and maintained with the wet harrowing method. Linear mixed modeling allowed systematic estimates of the independent marginal effects of each independent variable on each performance outcome of interest while controlling for the effects of variations in a batch's actual residence time, days since maintenance, and influent turbidity. This is the first study in which simultaneous measurement of bacteria, viruses and turbidity removal at the batch level over an extended duration has been undertaken with a large number of replicate units to permit rigorous modeling of ISSF performance variability within and across a range of likely filter design configurations and operating conditions. On average, the experimental filters removed 1.40 log fecal coliform CFU (SD 0.40 log, N=249), 0.54 log MS2 PFU (SD 0.42 log, N=245) and 89.0 percent turbidity (SD 6.9 percent, N=263). Effluent turbidity averaged 1.24 NTU (SD 0.53 NTU, N=263) and always remained below 3 NTU. Under the best performing design configuration and operating mode (fine sand, 10 cm head, long operation, initial HLR of 0.01-0.03 m/h), mean 1.82 log removal of bacteria (98.5%) and mean 0.94 log removal of MS2 viruses (88.5%) were achieved. Results point to new recommendations regarding filter design, manufacture, and operation for implementing ISSFs in local settings in developing countries. Sand size emerged as a critical design factor on performance. A single layer of river sand used in this investigation demonstrated removals comparable to those reported for 2 layers of crushed sand. Pause time and increased residence time each emerged as highly beneficial for improving removal performance on all four outcomes. A relatively large and significant negative effect of influent turbidity on MS2 viral removal in the ISSF was measured in parallel with a much smaller weaker positive effect of influent turbidity on FC bacterial removal. Disturbance of the schmutzdecke by wet harrowing showed no effect on virus removal and a modest reductive effect on the bacterial and turbidity removal as measured 7 days or more after the disturbance. For existing coarse sand ISSFs, this research indicates that a reduction in batch feed volume, effectively reducing the operating head and increasing the pore:batch volume ratio, could improve their removal performance by increasing batch residence time. Copyright © 2011 Elsevier Ltd. All rights reserved.
Bacteriophage PRD1 batch experiments to study attachment, detachment and inactivation processes

NASA Astrophysics Data System (ADS)

Sadeghi, Gholamreza; Schijven, Jack F.; Behrends, Thilo; Hassanizadeh, S. Majid; van Genuchten, Martinus Th.

2013-09-01

Knowledge of virus removal in subsurface environments is pivotal for assessing the risk of viral contamination of water resources and developing appropriate protection measures. Columns packed with sand are frequently used to quantify attachment, detachment and inactivation rates of viruses. Since column transport experiments are very laborious, a common alternative is to perform batch experiments where usually one or two measurements are done assuming equilibrium is reached. It is also possible to perform kinetic batch experiments. In that case, however, it is necessary to monitor changes in the concentration with time. This means that kinetic batch experiments will be almost as laborious as column experiments. Moreover, attachment and detachment rate coefficients derived from batch experiments may differ from those determined using column experiments. The aim of this study was to determine the utility of kinetic batch experiments and investigate the effects of different designs of the batch experiments on estimated attachment, detachment and inactivation rate coefficients. The experiments involved various combinations of container size, sand-water ratio, and mixing method (i.e., rolling or tumbling by pivoting the tubes around their horizontal or vertical axes, respectively). Batch experiments were conducted with clean quartz sand, water at pH 7 and ionic strength of 20 mM, and using the bacteriophage PRD1 as a model virus. Values of attachment, detachment and inactivation rate coefficients were found by fitting an analytical solution of the kinetic model equations to the data. Attachment rate coefficients were found to be systematically higher under tumbling than under rolling conditions because of better mixing and more efficient contact of phages with the surfaces of the sand grains. In both mixing methods, more sand in the container yielded higher attachment rate coefficients. A linear increase in the detachment rate coefficient was observed with increased solid-water ratio using tumbling method. Given the differences in the attachment rate coefficients, and assuming the same sticking efficiencies since chemical conditions of the batch and column experiments were the same, our results show that collision efficiencies of batch experiments are not the same as those of column experiments. Upscaling of the attachment rate from batch to column experiments hence requires proper understanding of the mixing conditions. Because batch experiments, in which the kinetics are monitored, are as laborious as column experiments, there seems to be no major advantage in performing batch instead of column experiments.
Formation of Manganese Oxide Coatings onto Sand for Adsorption of Trace Metals from Groundwater.

PubMed

Tilak, A S; Ojewole, S; Williford, C W; Fox, G A; Sobecki, T M; Larson, S L

2013-11-01

Manganese oxide (MnO) occurs naturally in soil and has a high affinity for trace metals adsorption. In this work, we quantified the factors (pH; flow rate; use of oxidants such as bleach, HO, and O; initial Mn(II) concentrations; and two types of geologic media) affecting MnO coatings onto Ottawa and aquifer sand using batch and column experiments. The batch experiments consisted of manual and automated titration, and the column experiments mimicked natural MnO adsorption and oxidation cycles as a strategy for in situ adsorption. A Pb solution of 50 mg L was passed through MnO-coated sand at a flow rate of 4 mL min to determine its adsorption capacity. Batch experimental results showed that MnO coatings increased from pH 6 to 8, with maximum MnO coating occurring at pH 8. Regarding MnO coatings, bleach and O were highly effective compared with HO. The Ottawa sand had approximately twice the MnO coating of aquifer sand. The sequential increase in initial Mn(II) concentrations on both sands resulted in incremental buildup of MnO. The automated procedure enhanced MnO coatings by 3.5 times compared with manual batch experiments. Column results showed that MnO coatings were highly dependent on initial Mn(II) and oxidant concentrations, pH, flow rate, number of cycles (h), and the type of geologic media used. Manganese oxide coating exceeded 1700 mg kg for Ottawa sand and 130 mg kg for aquifer sand. The Pb adsorption exceeded 2200 mg kg for the Ottawa sand and 300 mg kg for the aquifer sand. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.
Transport and retention of bacteria and viruses in biochar-amended sand.

PubMed

Sasidharan, Salini; Torkzaban, Saeed; Bradford, Scott A; Kookana, Rai; Page, Declan; Cook, Peter G

2016-04-01

The transport and retention of Escherichia coli and bacteriophages (PRD1, MS2 and ФX174), as surrogates for human pathogenic bacteria and viruses, respectively, were studied in the sand that was amended with several types of biochar produced from various feedstocks. Batch and column studies were conducted to distinguish between the role of attachment and straining in microbe retention during transport. Batch experiments conducted at various solution chemistries showed negligible attachment of viruses and bacteria to biochar before or after chemical activation. At any given solution ionic strength, the attachment of viruses to sand was significantly higher than that of biochar, whereas bacteria showed no attachment to either sand or biochar. Consistent with batch results, biochar addition (10% w/w) to sand reduced virus retention in the column experiments, suggesting a potential negative impact of biochar application to soil on virus removal. In contrast, the retention of bacteria was enhanced in biochar-amended sand columns. However, elimination of the fine fraction (<60μm) of biochar particles in biochar-amended sand columns significantly reduced bacteria retention. Results from batch and column experiments suggest that land application of biochar may only play a role in microbe retention via straining, by alteration of pore size distribution, and not via attachment. Consequently, the particle size distribution of biochar and sediments is a more important factor than type of biochar in determining whether land application of biochar enhances or diminishes microbial retention. Copyright © 2016 Elsevier B.V. All rights reserved.
Bacteriophage PRD1 batch experiments to study attachment, detachment and inactivation processes.

PubMed

Sadeghi, Gholamreza; Schijven, Jack F; Behrends, Thilo; Hassanizadeh, S Majid; van Genuchten, Martinus Th

2013-09-01

Knowledge of virus removal in subsurface environments is pivotal for assessing the risk of viral contamination of water resources and developing appropriate protection measures. Columns packed with sand are frequently used to quantify attachment, detachment and inactivation rates of viruses. Since column transport experiments are very laborious, a common alternative is to perform batch experiments where usually one or two measurements are done assuming equilibrium is reached. It is also possible to perform kinetic batch experiments. In that case, however, it is necessary to monitor changes in the concentration with time. This means that kinetic batch experiments will be almost as laborious as column experiments. Moreover, attachment and detachment rate coefficients derived from batch experiments may differ from those determined using column experiments. The aim of this study was to determine the utility of kinetic batch experiments and investigate the effects of different designs of the batch experiments on estimated attachment, detachment and inactivation rate coefficients. The experiments involved various combinations of container size, sand-water ratio, and mixing method (i.e., rolling or tumbling by pivoting the tubes around their horizontal or vertical axes, respectively). Batch experiments were conducted with clean quartz sand, water at pH 7 and ionic strength of 20 mM, and using the bacteriophage PRD1 as a model virus. Values of attachment, detachment and inactivation rate coefficients were found by fitting an analytical solution of the kinetic model equations to the data. Attachment rate coefficients were found to be systematically higher under tumbling than under rolling conditions because of better mixing and more efficient contact of phages with the surfaces of the sand grains. In both mixing methods, more sand in the container yielded higher attachment rate coefficients. A linear increase in the detachment rate coefficient was observed with increased solid-water ratio using tumbling method. Given the differences in the attachment rate coefficients, and assuming the same sticking efficiencies since chemical conditions of the batch and column experiments were the same, our results show that collision efficiencies of batch experiments are not the same as those of column experiments. Upscaling of the attachment rate from batch to column experiments hence requires proper understanding of the mixing conditions. Because batch experiments, in which the kinetics are monitored, are as laborious as column experiments, there seems to be no major advantage in performing batch instead of column experiments. Copyright © 2013 Elsevier B.V. All rights reserved.
Sulfate Fining Chemistry in Oxidized and Reduced Soda-Lime-Silica Glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matyas, Josef; Hrma, Pavel R.

2005-05-13

Various reducing agents were used and their additions were varied to (1) increase glass quality through eliminating defects from silica scum, (2) decrease SOx emissions through changing the kind and quantity of reducing agents, and (3) improve production efficiency through increased flexibility of glass redox control during continuous processing. The work included measuring silica sand dissolution and sulfate decomposition in melts from glass batches. Glass batches were heated at a temperature-increase rate deemed similar to that experienced in the melting furnace. The sulfate decomposition kinetics was investigated with thermogravimetric analysis-differential thermal analysis and evolved gas analysis. Sulfur concentrations in glassesmore » quenched at different temperatures were determined using X-ray fluorescence spectroscopy. The distribution of residual sand (that which was not dissolved during the initial batch reactions) in the glass was obtained as a function of temperature with optical microscopy in thin-sections of melts. The fraction of undissolved sand was measured with X-ray diffraction. The results of the present study helped Visteon Inc. reduce the energy consumption and establish the batch containing 0.118 mass% of graphite as the best candidate for Visteon glass production. The improved glass batch has a lower potential for silica scum formation and for brown fault occurrence in the final glass product. It was established that bubbles trapped in the melt even at 1450 C have a high probability to be refined when reaching the hot zone in the glass furnace. Furthermore, silica sand does not accumulate at the glass surface and dissolves faster in the batch with graphite than in the batch with carbocite.« less
Arsenic(V) Removal in Wetland Filters Treating Drinking Water with Different Substrates and Plants.

PubMed

Wu, Min; Li, Qingyun; Tang, Xianqiang; Huang, Zhuo; Lin, Li; Scholz, Miklas

2014-05-01

Constructed wetlands are an attractive choice for removing arsenic (As) within water resources used for drinking water production. The role of substrate and vegetation in As removal processes is still poorly understood. In this study, gravel, zeolite (microporous aluminosilicate mineral), ceramsite (lightweight expanded clay aggregate) and manganese sand were tested as prospective substrates while aquatic Juncus effuses (Soft Rush or Common Rush) and terrestrial Pteris vittata L. (Chinese Ladder Brake; known as As hyperaccumulator) were tested as potential wetland plants. Indoor batch adsorption experiments combined with outdoor column experiments were conducted to assess the As removal performances and process mechanisms. Batch adsorption results indicated that manganese sand had the maximum As(V) adsorption rate of 4.55 h -1 and an adsorption capacity of 42.37 μg/g compared to the other three aggregates. The adsorption process followed the pseudo-first-order kinetic model and Freundlich isotherm equations better than other kinetic and isotherm models. Film-diffusion was the rate-limiting step. Mean adsorption energy calculation results indicated that chemical forces, particle diffusion and physical processes dominated As adsorption to manganese sand, zeolite and gravel, respectively. During the whole running period, manganese sand-packed wetland filters were associated with constantly 90% higher As(V) reduction of approximate 500 μg/L influent loads regardless if planted or not. The presence of P. vittata contributed to no more than 13.5% of the total As removal. In contrast, J. effuses was associated with a 24% As removal efficiency.
Comparison of physical and mechanical properties of river sand concrete with quarry dust concrete

NASA Astrophysics Data System (ADS)

Opara, Hyginus E.; Eziefula, Uchechi G.; Eziefula, Bennett I.

2018-03-01

This study compared the physical and mechanical properties of river sand concrete with quarry dust concrete. The constituent materials were batched by weight. The water-cement ratio and mix ratio selected for the experimental investigation were 0.55 and 1:2:4, respectively. The specimens were cured for 7, 14, 21 and 28 days. Slump, density and compressive strength tests were carried out. The results showed that river sand concrete had greater density and compressive strength than quarry dust concrete for all curing ages. At 28 days of curing, river sand concrete exceeded the target compressive strength by 36%, whereas quarry dust concrete was less than the target compressive strength by 12%. Both river sand concrete and quarry dust concrete for the selected water/cement ratio and mix ratio are suitable for non-structural applications and lightly-loaded members where high strength is not a prerequisite.
INTERIOR VIEW SHOWING BATCH SCALES. SERIES OF FIVE SCALES WITH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

INTERIOR VIEW SHOWING BATCH SCALES. SERIES OF FIVE SCALES WITH SIX DIFFERENT MATERIALS. MIX SIFTED DOWN FROM SILOS ABOVE. INGREDIENTS: SAND, SODA ASH, DOLOMITE LIMESTONE, NEPHELINE SYENITE, SALT CAKE. - Chambers-McKee Window Glass Company, Batch Plant, Clay Avenue Extension, Jeannette, Westmoreland County, PA
Arsenic(V) Removal in Wetland Filters Treating Drinking Water with Different Substrates and Plants

PubMed Central

Li, Qingyun; Tang, Xianqiang; Huang, Zhuo; Lin, Li; Scholz, Miklas

2014-01-01

Constructed wetlands are an attractive choice for removing arsenic (As) within water resources used for drinking water production. The role of substrate and vegetation in As removal processes is still poorly understood. In this study, gravel, zeolite (microporous aluminosilicate mineral), ceramsite (lightweight expanded clay aggregate) and manganese sand were tested as prospective substrates while aquatic Juncus effuses (Soft Rush or Common Rush) and terrestrial Pteris vittata L. (Chinese Ladder Brake; known as As hyperaccumulator) were tested as potential wetland plants. Indoor batch adsorption experiments combined with outdoor column experiments were conducted to assess the As removal performances and process mechanisms. Batch adsorption results indicated that manganese sand had the maximum As(V) adsorption rate of 4.55 h–1 and an adsorption capacity of 42.37 μg/g compared to the other three aggregates. The adsorption process followed the pseudo-first-order kinetic model and Freundlich isotherm equations better than other kinetic and isotherm models. Film-diffusion was the rate-limiting step. Mean adsorption energy calculation results indicated that chemical forces, particle diffusion and physical processes dominated As adsorption to manganese sand, zeolite and gravel, respectively. During the whole running period, manganese sand-packed wetland filters were associated with constantly 90% higher As(V) reduction of approximate 500 μg/L influent loads regardless if planted or not. The presence of P. vittata contributed to no more than 13.5% of the total As removal. In contrast, J. effuses was associated with a 24% As removal efficiency. PMID:24771958
Cesium migration in saturated silica sand and Hanford sediments as impacted by ionic strength.

PubMed

Flury, Markus; Czigány, Szabolcs; Chen, Gang; Harsh, James B

2004-07-01

Large amounts of 137Cs have been accidentally released to the subsurface from the Hanford nuclear site in the state of Washington, USA. The cesium-containing liquids varied in ionic strengths, and often had high electrolyte contents, mainly in the form of NaNO3 and NaOH, reaching concentrations up to several moles per liter. In this study, we investigated the effect of ionic strengths on Cs migration through two types of porous media: silica sand and Hanford sediments. Cesium sorption and transport was studied in 1, 10, 100, and 1000 mM NaCl electrolyte solutions at pH 10. Sorption isotherms were constructed from batch equilibrium experiments and the batch-derived sorption parameters were compared with column breakthrough curves. Column transport experiments were analyzed with a two-site equilibrium-nonequilibrium model. Cesium sorption to the silica sand in batch experiments showed a linear sorption isotherm for all ionic strengths, which matched well with the results from the column experiments at 100 and 1000 mM ionic strength; however, the column experiments at 1 and 10 mM ionic strength indicated a nonlinear sorption behavior of Cs to the silica sand. Transport through silica sand occurred under one-site sorption and equilibrium conditions. Cesium sorption to Hanford sediments in both batch and column experiments was best described with a nonlinear Freundlich isotherm. The column experiments indicated that Cs transport in Hanford sediments occurred under two-site equilibrium and nonequilibrium sorption. The effect of ionic strength on Cs transport was much more pronounced in Hanford sediments than in silica sands. Effective retardation factors of Cs during transport through Hanford sediments were reduced by a factor of 10 when the ionic strength increased from 100 to 1000 mM; for silica sand, the effective retardation was reduced by a factor of 10 when ionic strength increased from 1 to 1000 mM. A two order of magnitude change in ionic strength was needed in the silica sand to observe the same change in Cs retardation as in Hanford sediments. Copyright 2003 Elsevier B.V.
Batch experiments characterizing the reduction of chromium(VI) using suboxic material from a mildly reducing sand and gravel aquifer

USGS Publications Warehouse

Anderson, Linda Davis; Kent, Douglas B.; Davis, James A.

1994-01-01

Batch experiments were conducted with sand collected from a shallow sand and gravel aquifer to identify the principal chemical reactions influencing the reduction of Cr(VI), so that field-observed Cr(V1) reduction could be described. The reduction appeared to be heterogeneous and occurred primarily on Fe(I1)-bearing minerals. At only 1 wt % , the fine fraction (<64 μm diameter) of the sediments dominated the amount of aqueous Cr(V1) reduction because of its greater reactivity and surface area. Although reduction of Cr(V1) increased with decreasing pH, small variations in the abundance of fine fraction among the replicate samples obscured pH trends in the batch experiments. Consistent results could only be obtained by separating the fine material from the sand and running parallel experiments on each fraction. As pH decreased (6.4 to 4.5), Cr(V1) reduction increased from 30 to 50 nmol/m2 for the sand fraction (64-1000 μm) and from 130 to 200 nmol/m2 for the fine fraction. The amount of Cr(V1) reduced in both the sand-sized and fine material increased from 35 to 80 and from 130 to 1000 nmol/m2, respectively, for a 10-fold increase in Cr(VI)initial. A consistent description of the rate data was achieved by assuming that intraparticle diffusion limited the observed rate of reduction.
Sorption of Cesium on smectite-rich clays from the Bohemian Massif (Czech Republic) and their mixtures with sand.

PubMed

Vejsada, J; Jelínek, E; Randa, Z; Hradil, D; Prikryl, R

2005-01-01

Sorption is an important process for the transport of radionuclides through backfill materials in a radioactive waste underground repository. Within this study, sorption of Cs on selected Czech clay materials and their mixtures with sand was investigated by batch tests. The experiments were performed under oxic conditions at 25 degrees C. Synthetic groundwater as a liquid phase and unconditioned clays (as they were provided by their producer) were used to reach the natural conditions as close as possible. Distribution ratios (Rds) of Cs for all selected clays rise with increase of the clay fraction in clay/sand mixtures in agreement with previous works studying sorption behaviour of such mixtures. The rise of Rds is from 10(2) cm3 g(-1) for mixtures with 80% of sand to 10(3) cm3 g(-1) for pure clays. There are significant differences between natural and technologically modified clays.
Monochloramine Cometabolism by Mixed-Culture Nitrifiers under Drinking Water Conditions

EPA Science Inventory

The current research investigated monochloramine cometabolism by nitrifying mixed cultures grown under drinking water relevant conditions and harvested from sand-packed reactors before conducting suspended growth batch kinetic experiments. Three batch reactors were used in each ...
Transport of sulfacetamide and levofloxacin in granular porous media under various conditions: Experimental observations and model simulations.

PubMed

Dong, Shunan; Gao, Bin; Sun, Yuanyuan; Shi, Xiaoqing; Xu, Hongxia; Wu, Jianfeng; Wu, Jichun

2016-12-15

Understanding the fate and transport of antibiotics in porous media can help reduce their contamination risks to soil and groundwater systems. In this work, batch and column experiments were conducted to determine the interactions between two representative antibiotics, sulfacetamide (SA) and levofloxacin (LEV), and sand porous media under various solution pH, humic acid (HA) concentration, grain size, and moisture content conditions. Batch sorption experimental results indicated that the sand had relatively strong bonding affinity to LEV, but little sorption of SA under different pH, HA concentration, grain size conditions. Results from the packed sand column experiments showed that SA had extremely high mobility in the porous media for all combinations of pH, HA concentration, grain size, and moisture content. The mass recovery of SA was higher than 98.5% in all the columns with the exception of the one packed with fine sand (97.2%). The retention of LEV in the columns was much higher and the recovery rates ranged from 0% to 71.1%. Decreases in solution pH, HA concentration, grain size, or moisture content reduced the mobility of LEV in the columns under the tested conditions. These results indicated that type of antibiotics and environmental conditions also played an important role in controlling their fate and transport in porous media. Mathematical models were applied to simulate and interpret experimental data, and model simulations described the interactions between the two antibiotics and sand porous media very well. Findings from this study elucidated the key factors and processes controlling the fate of SA and LEV in porous media, which can inform the prediction and assessment of the environmental risks of antibiotics. Copyright Â© 2016 Elsevier B.V. All rights reserved.
Simultaneous attenuation of pharmaceuticals, organic matter, and nutrients in wastewater effluent through managed aquifer recharge: Batch and column studies.

PubMed

Im, Huncheol; Yeo, Inseol; Maeng, Sung Kyu; Park, Chul Hwi; Choi, Heechul

2016-01-01

Batch and column experiments were conducted to evaluate the removal of organic matter, nutrients, and pharmaceuticals and to identify the removal mechanisms of the target contaminants. The sands used in the experiments were obtained from the Youngsan River located in South Korea. Neutral and cationic pharmaceuticals (iopromide, estrone, and trimethoprim) were removed with efficiencies greater than 80% from different sand media during experiments, due to the effect of sorption between sand and pharmaceuticals. However, the anionic pharmaceuticals (sulfamethoxazole, ketoprofen, ibuprofen, and diclofenac) were more effectively removed by natural sand, compared to baked sand. These observations were mainly attributed to biodegradation under natural conditions of surface organic matter and ATP concentrations. The removal of organic matter and nitrogen was also found to increase under biotic conditions. Therefore, it is indicated that biodegradation plays an important role and act as major mechanisms for the removal of organic matter, nutrients, and selected pharmaceuticals during sand passage and the managed aquifer recharge, which is an effective treatment method for removing target contaminants. However, the low removal efficiencies of pharmaceuticals (e.g., carbamazepine and sulfamethoxazole) require additional processes (e.g., AOPs, NF and RO membrane), a long residence time, and long travel distance for increasing the removal efficiencies. Copyright © 2015 Elsevier Ltd. All rights reserved.

Application of Biosurfactants Produced by Pseudomonas putida using Crude Palm Oil (CPO) as Substrate for Crude Oil Recovery using Batch Method

NASA Astrophysics Data System (ADS)

Suryanti, V.; Handayani, D. S.; Masykur, A.; Septyaningsih, I.

2018-03-01

The application of biosurfactants which have been produced by Pseudomonas putida in nutrient broth medium supplemented with NaCl and crude palm oil (CPO) for oil recovery has been evaluated. The crude and purified biosurfactants have been examined for oil recovery from a laboratory oil-contaminated sand in agitated flask (batch method). Two synthetic surfactants and water as control was also performed for oil recovery as comparisons. Using batch method, the results showed that removing ability of crude oil from the oil-contaminated sand by purified and crude biosurfactants were 79.40±3.10 and 46.84±2.23 %, respectively. On other hand, the recoveries obtained with the SDS, Triton X-100 and water were 94.33±0.47, 74.84±7.39 and 34.42±1.21%respectively.
Variation in toxicity response of Ceriodaphnia dubia to Athabasca oil sands coke leachates.

PubMed

Puttaswamy, Naveen; Turcotte, Dominique; Liber, Karsten

2010-07-01

Coke from the Athabasca (Alberta, Canada) oil sands operations may someday be integrated into reclamation landscapes. It is hypothesized that the metals associated with the solid coke may leach into the surrounding environment. Therefore, the main objectives of this study were to characterize the toxicity and chemistry of coke leachates collected from two field lysimeters (i.e. shallow lysimeter and deep lysimeter) over a period of 20months, as well as from other oil sands coke storage sites. In addition, a batch renewal leaching of coke was conducted to examine the rate of metals release. Chronic toxicity of key metals (e.g. Al, Mn, Ni and V) found in lysimeter coke leachate was evaluated separately. Toxicity test results revealed that whole coke leachates (100% v/v) were acutely toxic to Ceriodaphnia dubia; the 7-day LC50 values were always <25% v/v coke leachate. The deep lysimeter leachate was generally more toxic than the shallow lysimeter leachate, likely because of significantly higher concentrations of vanadium (V) found in the deep lysimeter leachate at all sampling times. Vanadium concentrations were higher than all other metals found in the leachate from both lysimeters, and in the batch renewal leaching study. Furthermore, V found in leachates collected from other oil sands field sites showed a concentration-response relationship with C. dubia survival. Mass balance calculations indicated that 94-98% of potentially leachable V fraction was still present in the coke from two field lysimeters. Evidence gathered from these assessments, including toxic unit (TU) calculations for the elements of concern, suggests that V was the likely cause of toxicity of the deep lysimeter leachate, whereas in the shallow lysimeter leachate both Ni and V could be responsible for the observed toxicity. 2010 Elsevier Ltd. All rights reserved.
Leaching assessment of road materials containing primary lead and zinc slags.

PubMed

Barna, R; Moszkowicz, P; Gervais, C

2004-01-01

Characterisation of the leaching behaviour of waste-containing materials is a crucial step in the environmental assessment for reuse scenarios. In our research we applied the multi-step European methodology ENV 12-920 to the leaching assessment of road materials containing metallurgical slag. A Zn slag from an imperial smelting furnace (ISF) and a Pb slag from a lead blast furnace (LBF) are investigated. The two slags contain up to 11.2 wt% of lead and 3.5 wt% of zinc and were introduced as a partial substitute for sand in two road materials, namely sand-cement and sand-bitumen. At the laboratory scale, a leaching assessment was performed first through batch equilibrium leaching tests. Second, the release rate of the contaminants was evaluated using saturated leaching tests on monolithic material. Third, laboratory tests were conducted on monolithic samples under intermittent wetting conditions. Pilot-scale tests were conducted for field testing of intermittent wetting conditions. The results show that the release of Pb and Zn from the materials in a saturated scenario was controlled by the pH of the leachates. For the intermittent wetting conditions, an additional factor, blocking of the pores by precipitation during the drying phase is proposed. Pilot-scale leaching behaviour only partially matched with the laboratory-scale test results: new mass transfer mechanisms and adapted laboratory leaching tests are discussed.
Testosterone sorption and desorption: effects of soil particle size.

PubMed

Qi, Yong; Zhang, Tian C; Ren, Yongzheng

2014-08-30

Soils contain a wide range of particles of different diameters with different mobility during rainfall events. Effects of soil particles on sorption and desorption behaviors of steroid hormones have not been investigated. In this study, wet sieve washing and repeated sedimentation methods were used to fractionate the soils into five ranges. The sorption and desorption properties and related mechanisms of testosterone in batch reactors filled with fractionated soil particles were evaluated. Results of sorption and desorption kinetics indicate that small soil particles have higher sorption and lower desorption rates than that of big ones. Thermodynamic results show the sorption processes are spontaneous and exothermal. The sorption capacity ranks as clay>silt>sand, depending mainly on specific surface area and surface functional groups. The urea control test shows that hydrogen bonding contributes to testosterone sorption onto clay and silt but not on sand. Desorption tests indicate sorption is 36-65% irreversible from clay to sand. Clays have highest desorption hysteresis among these five soil fractions, indicating small particles like clays have less potential for desorption. The results provide indirect evidence on the colloid (clay)-facilitated transport of hormones (micro-pollutants) in soil environments. Copyright © 2014 Elsevier B.V. All rights reserved.
Mobile bacteria and transport of polynuclear aromatic hydrocarbons in porous media.

PubMed Central

Jenkins, M B; Lion, L W

1993-01-01

Sorption of hydrophobic pollutants such as polynuclear aromatic hydrocarbons (PAHs) to soil and aquifer materials can severely retard their mobility and the time course of their removal. Because mobile colloids may enhance the mobility of hydrophobic pollutants in porous media and indigenous bacteria are generally colloidal in size, bacterial isolates from soil and subsurface environments were tested for their ability to enhance the transport of phenanthrene, a model PAH, in aquifer sand. Batch isotherm experiments were performed to measure the ability of selected bacteria, including 14 isolates from a manufactured gas plant waste site, to sorb 14C-phenanthrene and to determine whether the presence of the suspended cells would reduce the distribution coefficient (Kd) for phenanthrene with the sand. Column experiments were then used to test the mobility of isolates that reduced the Kd for phenanthrene and to test the most mobile isolate for its ability to enhance the transport of phenanthrene. All of the isolates tested passively sorbed phenanthrene, and most but not all of the isolates reduced the Kd for phenanthrene. Some, but not all, of those isolates were mobile in column experiments. The most mobile isolate significantly enhanced the transport of phenanthrene in aquifer sand, reducing its retardation coefficient by 25% at a cell concentration of approximately 5 x 10(7) ml-1. The experimental results demonstrated that mobile bacteria may enhance the transport of PAHs in the subsurface. PMID:8250555
Aqueous Cleaning and Validation for Space Shuttle Propulsion Hardware at the White Sands Test Facility

NASA Technical Reports Server (NTRS)

Hornung, Steven D.; Biesinger, Paul; Kirsch, Mike; Beeson, Harold; Leuders, Kathy

1999-01-01

The NASA White Sands Test Facility (WSTF) has developed an entirely aqueous final cleaning and verification process to replace the current chlorofluorocarbon (CFC) 113 based process. This process has been accepted for final cleaning and cleanliness verification of WSTF ground support equipment. The aqueous process relies on ultrapure water at 50 C (323 K) and ultrasonic agitation for removal of organic compounds and particulate. The cleanliness is verified bv determining the total organic carbon (TOC) content and filtration with particulate counting. The effectiveness of the aqueous methods for detecting hydrocarbon contamination and particulate was compared to the accepted CFC 113 sampling procedures. Testing with known contaminants, such as hydraulic fluid and cutting and lubricating oils, to establish a correlation between aqueous TOC and CFC 113 nonvolatile residue (NVR) was performed. Particulate sampling on cleaned batches of hardware that were randomly separated and sampled by the two methods was performed. This paper presents the approach and results, and discusses the issues in establishing the equivalence of aqueous sampling to CFC 113 sampling, while describing the approach for implementing aqueous techniques on Space Shuttle Propulsion hardware.
Retardation of ammonium and potassium transport through a contaminated sand and gravel aquifer: The Role of cation exchange

USGS Publications Warehouse

Ceazan, M.L.; Thurman, E.M.; Smith, R.L.

1989-01-01

The role of cation exchange in the retardation of ammonium (NH4+) and potassium (K+) transport in a shallow sand and gravel aquifer was evaluated by use of observed distributions of NH4+ and K+ within a plume of sewage-contaminated groundwater, small-scale tracer injection tests, and batch sorption experiments on aquifer material. Both NH4+ and K+ were transported ???2 km in the 4-km-long contaminant plume (retardation factor, Rf = 2.0). Sediments from the NH4+-containing zone of the plume contained significant quantities of KCl-extractable NH4+ (extraction distribution coefficient, Kd,extr = 0.59-0.87 mL/g of dry sediment), and when added to uncontaminated sediments, NH4+ sorption followed a linear isotherm. Small-scale tracer tests demonstrated that NH4+ and K+ were retarded (Rf =3.5) relative to a nonreactive tracer (Br-). Sorption of dissolved NH4+ was accompanied by concomitant release of calcium (Ca2+), magnesium (Mg2+), and sodium (Na+) from aquifer sediments, suggesting involvement of cation exchange. In contrast, nitrate (NO3-) was not retarded and cleanly separated from NH4+ and K+ in the small-scale tracer tests. This study demonstrates that transport of NH4+ and K+ through a sand and gravel aquifer can be markedly affected by cation-exchange processes even at a clay content less than 0.1%.
Laboratory studies to characterize the efficacy of sand capping a coal tar-contaminated sediment.

PubMed

Hyun, Seunghun; Jafvert, Chad T; Lee, Linda S; Rao, P Suresh C

2006-06-01

Placement of a microbial active sand cap on a coal tar-contaminated river sediment has been suggested as a cost effective remediation strategy. This approach assumes that the flux of contaminants from the sediment is sufficiently balanced by oxygen and nutrient fluxes into the sand layer such that microbial activity will reduce contaminant concentrations within the new benthic zone and reduce the contaminant flux to the water column. The dynamics of such a system were evaluated using batch and column studies with microbial communities from tar-contaminated sediment under different aeration and nutrient inputs. In a 30-d batch degradation study on aqueous extracts of coal tar sediment, oxygen and nutrient concentrations were found to be key parameters controlling the degradation rates of polycyclic aromatic hydrocarbons (PAHs). For the five PAHs monitored (naphthalene, fluorene, phenanthrene, anthracene, and pyrene), degradation rates were inversely proportional to molecular size. For the column studies, where three columns were packed with a 20-cm sand layer on the top of a 5 cm of sediment layer, flow was established to sand layers with (1) aerated water, (2) N(2) sparged water, or (3) HgCl(2)-sterilized N(2) sparged water. After steady-state conditions, PAH concentrations in effluents were the lowest in the aerated column, except for pyrene, whose concentration was invariant with all effluents. These laboratory scale studies support that if sufficient aeration can be achieved in the field through either active and passive means, the resulting microbially active sand layer can improve the water quality of the benthic zone and reduce the flux of many, but not all, PAHs to the water column.
Sand moulds milling for one-of-a-kind pieces

NASA Astrophysics Data System (ADS)

Rodríguez, A.; Calleja, A.; Olvera, D.; Peñafiel, F. J.; López de Lacalle, L. N.

2012-04-01

Time to market is a critical measurement for today's foundry market. Combining 3D digitizing and sand blocks milling is possible to reduce this time. Avoiding the use of a wood pattern, this technique is useful for art pieces or unique parts, when only one component is necessary. The key of the proposed methodology is to achieve enough tool life with conventional tool qualities, avoiding the risk of sand destruction or damage. A special study of tool wear is presented in this work, studying different tool materials and different sand types. Two examples of unique parts are also presented in this work following the proposed methodology in order to reduce time and cost for the rapid reproduction of very short batches.
Effective control of modified palygorskite to NH4+-N release from sediment.

PubMed

Chen, Lei; Zheng, Tianyuan; Zhang, Junjie; Liu, Jie; Zheng, Xilai

2014-01-01

Sediment capping is an in situ treatment technology that can effectively restrain nutrient and pollutant release from the sediment in lakes and reservoirs. Research on sediment capping has focused on the search for effective, non-polluting and affordable capping materials. The efficiency and mechanism of sediment capping with modified palygorskite in preventing sediment ammonia nitrogen (NH4+-N) release to surface water were investigated through a series of batch and sediment capping experiments. Purified palygorskite and different types of modified palygorskite (i.e. heated, acid-modified and NaCI-modified palygorskite) were used in this investigation. Factors affecting control efficiency, including the temperature, thickness and grain size of the capping layer, were also analysed. The batch tests showed that the adsorption of NH4+-N on modified palygorskite achieved an equilibration in the initial 45 min, and the adsorption isotherm followed the Freundlich equation. Sediment capping experiments showed that compared with non-capped condition, covering the sediment with modified palygorskite and sand both inhibited NH4+-N release to the overlying water. Given its excellent chemical stability and strong adsorption, heated palygorskite, which has a NH4+-N release inhibition ratio of 41.3%, is a more effective sediment capping material compared with sand. The controlling effectiveness of the modified palygorskite increases with thicker capping layer, lower temperature and smaller grain size of the capping material.
Comparisons of the film peeling from the composite oxides of quartz sand filters using ozone, hydrogen peroxide and chlorine dioxide.

PubMed

Guo, Yingming; Huang, Tinglin; Wen, Gang; Cao, Xin

2015-08-01

To solve the problem of shortened backwashing intervals in groundwater plants, several disinfectants including ozone (O3), hydrogen peroxide (H2O2) and chlorine dioxide (ClO2) were examined to peel off the film from the quartz sand surface in four pilot-scale columns. An optimized oxidant dosage and oxidation time were determined by batch tests. Subsequently, the optimized conditions were tested in the four pilot-scale columns. The results demonstrated that the backwashing intervals increased from 35.17 to 54.33 (H2O2) and to 53.67 hr (ClO2) after the oxidation treatments, and the increase of backwashing interval after treatment by O3 was much less than for the other two treatments. Interestingly, the treatment efficiency of filters was not affected by O3 or H2O2 oxidation; but after oxidation by ClO2, the treatment efficiency was deteriorated, especially the ammonia removal (from 96.96% to 24.95%). The filter sands before and after the oxidation were characterized by scanning electron microscopy and X-ray photoelectron spectroscopy. Compared with the oxidation by O3 and H2O2, the structures on the surface of filter sands were seriously damaged after oxidation by ClO2. The chemical states of manganese on the surfaces of those treated sands were only changed by ClO2. The damage of the structures and the change of the chemical states of manganese might have a negative effect on the ammonia removal. In summary, H2O2 is a suitable agent for film peeling. Copyright © 2015. Published by Elsevier B.V.
Biodegradation of the artificial sweetener acesulfame in biological wastewater treatment and sandfilters.

PubMed

Castronovo, Sandro; Wick, Arne; Scheurer, Marco; Nödler, Karsten; Schulz, Manoj; Ternes, Thomas A

2017-03-01

A considerable removal of the artificial sweetener acesulfame (ACE) was observed during activated sludge processes at 13 wastewater treatment plants (WWTPs) as well as in a full-scale sand filter of a water works. A long-term sampling campaign over a period of almost two years revealed that ACE removal in WWTPs can be highly variable over time. Nitrifying/denitrifying sequencing batch reactors (SBR) as well as aerobic batch experiments with activated sludge and filter sand from a water works confirmed that both activated sludge as well as filter sand can efficiently remove ACE and that the removal can be attributed to biologically mediated degradation processes. The lab results strongly indicated that varying ACE removal in WWTPs is not associated with nitrification processes. Neither an enhancement of the nitrification rate nor the availability of ammonium or the inhibition of ammonium monooxygenase by N-allylthiourea (ATU) affected the degradation. Moreover, ACE was found to be also degradable by activated sludge under denitrifying conditions, while being persistent in the absence of both dissolved oxygen and nitrate. Using ion chromatography coupled with high resolution mass spectrometry, sulfamic acid (SA) was identified as the predominant transformation product (TP). Quantitative analysis of ACE and SA revealed a closed mass balance during the entire test period and confirmed that ACE was quantitatively transformed to SA. Measurements of dissolved organic carbon (DOC) revealed an almost complete removal of the carbon originating from ACE, thereby further confirming that SA is the only relevant final TP in the assumed degradation pathway of ACE. A first analysis of SA in three municipal WWTP revealed similar concentrations in influents and effluents with maximum concentrations of up to 2.3 mg/L. The high concentrations of SA in wastewater are in accordance with the extensive use of SA in acid cleaners, while the degradation of ACE in WWTPs adds only a very small portion of the total load of SA discharged into surface waters. No removal of SA was observed by the biological treatment applied at these WWTPs. Moreover, SA was also stable in the aerobic batch experiments conducted with the filter sand from a water works. Hence, SA might be a more appropriate wastewater tracer than ACE due to its chemical and microbiological persistence, the negligible sorbing affinity (high negative charge density) and its elevated concentrations in WWTP effluents. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.
Decolorization of black liquor from bioethanol G2 production using iron oxide coating sands

NASA Astrophysics Data System (ADS)

Barlianti, Vera; Triwahyuni, Eka; Waluyo, Joko; Sari, Ajeng Arum

2017-01-01

Bioethanol G2 production using oil palm empty fruit bunch as raw material consists of four steps, namely pretreatment, hydrolysis, fermentation, and purification process. Pretreatment process generates black liquor that causes serious environmental pollution if it is released to the environment. The objective of this research is studying the ability of iron oxide coating sands to adsorb the color of black liquor. The iron oxide coating sands were synthesized from FeCl3.6H2O with quartz sands as support material. This research was conducted on batch mode using black liquor in various pH values. Result obtained that kind of iron oxide on quartz sands's surface was goethite. The result also indicated decreasing of color intensity of black liquor after adsorption process. This research supports local material utilization in environmental technology development to solve some environmental problems.
Experimental investigation of cephapirin adsorption to quartz filter sands and dune sands

NASA Astrophysics Data System (ADS)

Peterson, Jonathan W.; O'Meara, Theresa A.; Seymour, Michael D.

2008-08-01

Batch experiments were performed to investigate cephapirin (a widely used veterinary antibiotic) adsorption on various size sands of low total organic carbon content (0.08-0.36 wt%). In the aqueous concentration range investigated (11-112 μmol/L cephapirin), adsorption to nearly pure quartz filter sands (0.50-3.35 mm diameter) is low. Isotherms are S-shaped and most display a region of minimum adsorption, where decreased adsorption occurs with increasing solution concentration, followed by increased adsorption at higher concentrations. Cephapirin adsorption to quartz-rich, feldspar-bearing dune sands (0.06-0.35 mm diameter), and the smallest quartz filter sand investigated (0.43-0.50 mm), can be described by linear sorption isotherms over the range of concentrations investigated. Distribution coefficients ( K d) range from 0.94 to 3.45 L/kg. No systematic relationship exists between grain size and amount of adsorption for any of the sands investigated. Cephapirin adsorption is positively correlated to the feldspar ratio (K-feldspar/(albite + Ca-plagioclase). Feldspar-ratio normalization of distribution coefficients was more effective than organic carbon normalization at reducing variability of K d values in the dune sands investigated.
Deposition and transport of Pseudomonas aeruginosa in porous media: lab-scale experiments and model analysis.

PubMed

Kwon, Kyu-Sang; Kim, Song-Bae; Choi, Nag-Choul; Kim, Dong-Ju; Lee, Soonjae; Lee, Sang-Hyup; Choi, Jae-Woo

2013-01-01

In this study, the deposition and transport of Pseudomonas aeruginosa on sandy porous materials have been investigated under static and dynamic flow conditions. For the static experiments, both equilibrium and kinetic batch tests were performed at a 1:3 and 3:1 soil:solution ratio. The batch data were analysed to quantify the deposition parameters under static conditions. Column tests were performed for dynamic flow experiments with KCl solution and bacteria suspended in (1) deionized water, (2) mineral salt medium (MSM) and (3) surfactant + MSM. The equilibrium distribution coefficient (K(d)) was larger at a 1:3 (2.43 mL g(-1)) than that at a 3:1 (0.28 mL g(-1)) soil:solution ratio. Kinetic batch experiments showed that the reversible deposition rate coefficient (k(att)) and the release rate coefficient (k(det)) at a soil:solution ratio of 3:1 were larger than those at a 1:3 ratio. Column experiments showed that an increase in ionic strength resulted in a decrease in peak concentration of bacteria, mass recovery and tailing of the bacterial breakthrough curve (BTC) and that the presence of surfactant enhanced the movement of bacteria through quartz sand, giving increased mass recovery and tailing. Deposition parameters under dynamic condition were determined by fitting BTCs to four different transport models, (1) kinetic reversible, (2) two-site, (3) kinetic irreversible and (4) kinetic reversible and irreversible models. Among these models, Model 4 was more suitable than the others since it includes the irreversible sorption term directly related to the mass loss of bacteria observed in the column experiment. Applicability of the parameters obtained from the batch experiments to simulate the column breakthrough data is evaluated.
Experimental Design for One Dimensional Electrolytic Reactive Barrier for Remediation of Munition Constituent in Groundwater

PubMed Central

Gent, David B.; Wani, Altaf; Alshawabkeh, Akram N.

2012-01-01

A combination of direct electrochemical reduction and in-situ alkaline hydrolysis has been proposed to decompose energetic contaminants such as 1,3,5-Trinitroperhydro- 1,3,5-triazine and 2,4,6-Trinitrotoluene (RDX) in deep aquifers. This process utilizes natural groundwater convection to carry hydroxide produced by an upstream cathode to remove the contaminant at the cathode as well as in the pore water downstream as it migrates toward the anode. Laboratory evaluation incorporated fundamental principles of column design coupled with reactive contaminant modeling including electrokinetics transport. Batch and horizontal sand-packed column experiments included both alkaline hydrolysis and electrochemical treatment to determine RDX decomposition reaction rate coefficients. The sand packed columns simulated flow through a contaminated aquifer with a seepage velocity of 30.5 cm/day. Techniques to monitor and record the transient electric potential, hydroxide transport and contaminant concentration within the column were developed. The average reaction rate coefficients for both the alkaline batch (0.0487 hr−1) and sand column (0.0466 hr−1) experiments estimated the distance between the cathode and anode required to decompose 0.5 mg/L RDX to the USEPA drinking water lifetime Health Advisory level of 0.002 mg/L to be 145 and 152 cm. PMID:23472044
Bioprocessing-Based Approach for Bitumen/Water/Fines Separation and Hydrocarbon Recovery from Oil Sands Tailings

DOE PAGES

Brigmon, Robin L.; Berry, Christopher J.; Wade, Arielle; ...

2016-05-04

Oil sands are a major source of oil, but their industrial processing generates tailings ponds that are an environmental hazard. The main concerns are mature fine tailings (MFT) composed of residual hydrocarbons, water, and fine clay. Tailings ponds include toxic contaminants such as heavy metals, and toxic organics including naphthenics. Naphthenic acids and polyaromatic hydrocarbons (PAHs) degrade very slowly and pose a long-term threat to surface and groundwater, as they can be transported in the MFT. Research into improved technologies that would enable densification and settling of the suspended particles is ongoing. In batch tests, BioTiger™, a microbial consortium thatmore » can metabolize PAHs, demonstrated improved oil sands tailings settling from a Canadian tailings pond. Results also showed, depending on the timing of the measurements, lower suspended solids and turbidity. Elevated total organic carbon was observed in the first 48 hours in the BioTiger™-treated columns and then decreased in overlying water. Oil sands tailings mixed with BioTiger™ showed a two-fold reduction in suspended solids within 24 hours as compared to abiotic controls. The tailings treated with BioTiger™ increased in microbial densities three orders of magnitude from 8.5 × 105 CFU/mL to 1.2 × 108 CFU/mL without any other carbon or energy source added, indicating metabolism of hydrocarbons and other available nutrients. Results demonstrated that bioaugmentation of BioTiger™ increased separation of organic carbon from particles in oil sands and enhanced settling with tailings with improved water quality.« less
INFLUENCE OF PEAT ON FENTON OXIDATION

EPA Science Inventory

A diagnostic probe was used to estimate the activity of Fenton-derived hydroxyl radicals (@OH), reaction kinetics, and oxidation efficiency in batch suspensions comprised of silica sand, crushed goethite ("-FeOOH) ore, peat, and H2O2 (0.13 mM). A simple method of kinetic analysi...
Dependence of particle concentration effect on pH and redox for arsenic removal by FeS-coated sand under anoxic conditions.

PubMed

Han, Young-Soo; Demond, Avery H; Gallegos, Tanya J; Hayes, Kim F

2015-09-01

FeS has been recognized as a good scavenger for arsenic under anoxic conditions. To create a suitable adsorbent for flow-through reactors such as permeable reactive barriers, it has been suggested that this material may be coated onto sand. However, previous work on FeS-coated sand has focused on batch reactors, while flow-through reactors usually have higher solid-solution ratios. To ascertain whether differences in the solid-solution ratio (SSR) are important in this system, batch sorption experiments were conducted as a function of pH using As(III) and FeS-coated sands at various solid-solution ratios. The results showed little variation in the distribution coefficient with SSR at pH 7 and 9. However, at pH 5, the results showed lower values of the distribution coefficient at lower SSRs, the reverse of typically reported SSR effects. Measured pe values showed a dependence on SSR, which, when coupled with chemical modeling of the Fe-As-S-H2O system, suggested a change in the removal mechanism with SSR, from adsorption to a reduced Fe(II) oxyhydroxide phase (represented by Fe2(OH)5) to precipitation as As2S3 or AsS. On the other hand, at pH 7 and 9, arsenite adsorption is the most probable removal mechanism regardless of the pe. Thus, this study identified variations in pH and redox conditions, and the removal mechanisms that these parameters govern, as the reason for the apparent SSR effect. Copyright © 2014 Elsevier Ltd. All rights reserved.
Bioaugmentation potential of free and formulated 2,6-dichlorobenzamide (BAM) degrading Aminobacter sp. MSH1 in soil, sand and water.

PubMed

Schultz-Jensen, Nadja; Aamand, Jens; Sørensen, Sebastian R

2016-12-01

Pesticides are used extensively worldwide, which has led to the unwanted contamination of soil and water resources. Former use of the herbicide 2,6-dichlorobenzonitrile (dichlobenil) has caused pollution of ground and surface water resources by the stable degradation product 2,6-dichlorobenzamide (BAM) in several parts of Europe, which has resulted in the costly closure of several drinking water wells. One strategy for preventing this in future is bioaugmentation using bacterial degraders. BAM-degrading Aminobacter sp. MSH1 was therefore formulated into dried beads and tests undertaken to establish their potential for use in the remediation of polluted soil, sand and water. The formulation procedure included freeze drying, combined with trehalose addition for cell wall protection, thus ensuring a high amount of viable cells following prolonged storage at room temperature. The beads were round-shaped pellets with a diameter of about 1.25 mm, a dry matter content of approximately 95 % and an average viable cell content of 4.4 × 10(9) cells/g bead. Formulated MSH1 cells led to a similar, and frequently even faster, BAM mineralisation (20-65 % (14)CO2 produced from (14)C-labelled BAM) in batch tests conducted with sand, water and different soil moisture contents compared to adding free cells. Furthermore, the beads were easy to handle and had a shelf life of several months.

TRANSPORT OF INORGANIC COLLOIDS THROUGH NATURAL AQUIFER MATERIAL: IMPLICATIONS FOR CONTAMINANT TRANSPORT

EPA Science Inventory

The stability and transport of radiolabeled Fe₂O₃ particles were studied using laboratory batch and column techniques. Core material collected from a shallow sand and gravel aquifer was used as the immobile column matrix material. Variables in the study incl...
Investigation of formaldehyde interaction with carbon nanotubes and quartz sand

NASA Astrophysics Data System (ADS)

Georgopoulou, Maria P.; Chrysikopoulos, Constantinos V.

2017-04-01

Assessment of the potential impact of synthetic carbon nanotubes on the fate and transport of common chemical contaminants (pesticides, pharmaceuticals, etc.) in groundwater systems is considered to be an increasingly important aspect of environmental research. This study investigates the interaction of formaldehyde with multi-walled carbon nanotubes (MWCNTs) and quartz sand under static and dynamic conditions. Due to polarity, formaldehyde, is expected to develop strong adsorptive interactions with carbon nanotubes. Several batch adsorption experiments were conducted in test tubes, under controlled conditions. Various initial formaldehyde solution concentration (2, 5, 8 ppm), contact times, and temperatures (8, 18, 25 °C) were considered. Supernatant liquid samples were collected at regular intervals, and centrifuged. Subsequently, the formaldehyde concentration in the supernatant was quantified indirectly, by derivatization with Nash reagent and subsequent measurement of the resulting complex using spectrophotometry in the visible spectral range. Experimental results suggested that formaldehyde has a low affinity for quartz sand, but an enhanced potential for adsorption onto carbon nanotubes. Formaldehyde adsorption onto both absorbents (quartz sand and MWCNTs) was more pronounced under dynamic than static conditions, probably, because agitation improves the mixing of the absorbent within the solution. Also, it was shown that the adsorption data were adequately described by the pseudo-second order kinetic model, suggesting that the primary adsorption mechanism was chemisorption, where two or more (sequential or parallel) processes (e.g. surface chemisorption, intraparticle diffusion) were taking place. Therefore, MWCNTs could be promising adsorbent materials for groundwater remediation.
Sorption and transport of acetaminophen, 17alpha-ethynyl estradiol, nalidixic acid with low organic content aquifer sand.

PubMed

Lorphensri, Oranuj; Sabatini, David A; Kibbey, Tohren C G; Osathaphan, Khemarath; Saiwan, Chintana

2007-05-01

The sorption and transport of three pharmaceutical compounds (acetaminophen, an analgesic; nalidixic acid, an antibiotic; and 17alpha-ethynyl estradiol, a synthetic hormone) were examined by batch sorption experiments and solute displacement in columns of silica, alumina, and low organic carbon aquifer sand at neutral pH. Silica and alumina were used to represent negatively-charged and positively-charged fractions of subsurface media. Column transport experiments were also conducted at pH values of 4.3, 6.2, and 8.2 for the ionizable nalidixic acid. The computer program UFBTC was used to fit the breakthrough data under equilibrium and nonequilibrium conditions with linear/nonlinear sorption. Good agreement was observed between the retardation factors derived from column model studies and estimated from equilibrium batch sorption studies. The sorption and transport of nalidixic acid was observed to be highly pH dependent, especially when the pH was near the pK(a) of nalidixic acid (5.95). Thus, near a compound's pK(a) it is especially important that the batch studies be performed at the same pH as the column experiment. While for ionic pharmaceuticals, ion exchange to oppositely-charged surfaces, appears to be the dominant adsorption mechanism, for neutral pharmaceuticals (i.e., acetaminophen, 17alpha-ethynyl estradiol) the sorption correlated well with the K(ow) of the pharmaceuticals, suggesting hydrophobically motivated sorption as the dominant mechanism.
Surfactant-enhanced remediation of a trichloroethene-contaminated aquifer. 1. Transport of triton X-100

USGS Publications Warehouse

Smith, J.A.; Sahoo, D.; Mclellan, H.M.; Imbrigiotta, T.E.

1997-01-01

Transport of a nonionic surfactant (Triton X-100) at aqueous concentrations less than 400 mg/L through a trichloroethene-contaminated sand-and-gravel aquifer at Picatinny Arsenal, NJ, has been studied through a series of laboratory and field experiments. In the laboratory, batch and column experiments were conducted to quantify the rate and amount of Triton X-100 sorption to the aquifer sediments. In the field, a 400 mg/L aqueous Triton X-100 solution was injected into the aquifer at a rate of 26.5 L/min for a 35-d period. The transport of Triton X-100 was monitored by sampling and analysis of groundwater at six locations surrounding the injection well. Equilibrium batch sorption experiments showed that Triton X-100 sorbs strongly and nonlinearly to the field soil with the sharpest inflection point of the isotherm occurring at an equilibrium aqueous Triton X-100 concentration close to critical micelle concentration. Batch, soil column, and field experimental data were analyzed with zero-, one-, and two- dimensional (respectively) transient solute transport models with either equilibrium or rate-limited sorption. These analyses reveal that Triton X- 100 sorption to the aquifer solids is slow relative to advective and dispersive transport and that an equilibrium sorption model cannot simulate accurately the observed soil column and field data. Comparison of kinetic sorption parameters from batch, column, and field transport data indicate that both physical heterogeneities and Triton X-100 mass transfer between water and soil contribute to the kinetic transport effects.Transport of a nonionic surfactant (Triton X-100) at aqueous concentrations less than 400 mg/L through a trichloroethene-contaminated sand-and-gravel aquifer was studied. Equilibrium batch sorption experiments showed that Triton X-100 sorbs strongly and nonlinearly to the field soil with the sharpest inflection point of the isotherm occurring at an equilibrium aqueous Triton X-100 concentration close to critical micelle concentration. Batch, soil column, and field experimental data were analyzed with zero-, one-, and two-dimensional transient solute transport models with either equilibrium or rate-limited sorption. These analyses revealed that Triton X-100 sorption to the aquifer solids was slow relative to advective and dispersive transport.
Hybrid Sargassum-sand sorbent: a novel adsorbent in packed column to treat metal-bearing wastewaters from inductively coupled plasma-optical emission spectrometry.

PubMed

Vijayaraghavan, K; Joshi, U M

2013-01-01

Laboratory batch and column experiments were carried out to examine the efficiency of algal-based treatment technique to clean-up wastewaters emanating from inductively coupled plasma-optical emission spectrometry (ICP-OES). Chemical characterization revealed the extreme complexity of the wastewater, with the presence of 14 different metals under very low pH (pH = 1.1), high conductivity (6.98 mS/cm), total dissolved solid (4.46 g/L) and salinity (3.77). Batch experiments using Sargassum biomass indicated that it was possible to attain high removal efficiencies at optimum pH of 4.0. Efforts were also made to continuously treat ICP-OES wastewater using up-flow packed column. However, swelling of Sargassum biomass leads to stoppage of column. To address the problem, Sargassum was mixed with sand at a ratio of 40: 60 on volume basis. Remarkably, the hybrid Sargassum-sand sorbent showed very high removal efficiency towards multiple metal ions with the column able to operate for 11 h at a flow rate of 10 mL/min. Metal ions such as Cu, Cd, and Pb were only under trace levels in the treated water until 11 h. The results of the treatment process were compared with trade effluent discharge standards. Further the process evaluation and cost analysis were presented.
Non-pumping reactive wells filled with mixing nano and micro zero-valent iron for nitrate removal from groundwater: Vertical, horizontal, and slanted wells

NASA Astrophysics Data System (ADS)

Hosseini, Seiyed Mossa; Tosco, Tiziana; Ataie-Ashtiani, Behzad; Simmons, Craig T.

2018-03-01

Non-pumping reactive wells (NPRWs) filled by zero-valent iron (ZVI) can be utilized for the remediation of groundwater contamination of deep aquifers. The efficiency of NPRWs mainly depends on the hydraulic contact time (HCT) of the pollutant with the reactive materials, the extent of the well capture zone (Wcz), and the relative hydraulic conductivity of aquifer and reactive material (Kr). We investigated nitrate removal from groundwater using NPRWs filled by ZVI (in nano and micro scales) and examined the effect of NPRWs orientations (i.e. vertical, slanted, and horizontal) on HCT and Wcz. The dependence of HCT on Wcz for different Kr values was derived theoretically for a homogeneous and isotropic aquifer, and verified using particle tracking simulations performed using the semi-analytical particle tracking and pathlines model (PMPATH). Nine batch experiments were then performed to investigate the impact of mixed nano-ZVI, NZVI (0 to 2 g l-1) and micro-ZVI, MZVI (0 to 4 g l-1) on the nitrate removal rate (with initial NO3-=132 mg l-1). The NPRWs system was tested in a bench-scale sand medium (60 cm length × 40 cm width × 25 cm height) for three orientations of NPRWs (vertical, horizontal, and slanted with inclination angle of 45°). A mixture of nano/micro ZVI, was used, applying constant conditions of pore water velocity (0.024 mm s-1) and initial nitrate concentration (128 mg l-1) for five pore volumes. The results of the batch tests showed that mixing nano and micro Fe0 outperforms these individual materials in nitrate removal rates. The final products of nitrate degradation in both batch and bench-scale experiments were NO2-, NH4+, and N2(gas). The results of sand-box experiments indicated that the slanted NPRWs have a higher nitrate reduction rate (57%) in comparison with vertical (38%) and horizontal (41%) configurations. The results also demonstrated that three factors have pivotal roles in expected HCT and Wcz, namely the contrast between the hydraulic conductivity of aquifer and reactive materials within the wells, the mass of Fe0 in the NPRWs, and the orientation of NPRWs adopted. A trade-off between these factors should be considered to increase the efficiency of remediation using the NPRWs system.
Performance evaluation of a dual-flow recharge filter for improving groundwater quality.

PubMed

Samuel, Manoj P; Senthilvel, S; Mathew, Abraham C

2014-07-01

A dual-flow multimedia stormwater filter integrated with a groundwater recharge system was developed and tested for hydraulic efficiency and pollutant removal efficiency. The influent stormwater first flows horizontally through the circular layers of planted grass and biofibers. Subsequently, the flow direction changes to a vertical direction so that water moves through layers of pebbles and sand and finally gets recharged to the deep aquifers. The media in the sequence of vegetative medium:biofiber to pebble:sand were filled in nine proportions and tested for the best performing combination. Three grass species, viz., Typha (Typha angustifolia), Vetiver (Chrysopogon zizanioides), and St. Augustine grass (Stenotaphrum secundatum), were tested as the best performing vegetative medium. The adsorption behavior of Coconut (Cocos nucifera) fiber, which was filled in the middle layer, was determined by a series of column and batch studies.The dual-flow filter showed an increasing trend in hydraulic efficiency with an increase in flowrate. The chemical removal efficiency of the recharge dual-flow filter was found to be very high in case of K+ (81.6%) and Na+ (77.55%). The pH normalizing efficiency and electrical conductivity reduction efficiency were also recorded as high. The average removal percentage of Ca2+ was moderate, while that of Mg2+ was very low. The filter proportions of 1:1 to 1:2 (plant:fiber to pebble:sand) showed a superior performance compared to all other proportions. Based on the estimated annual costs and returns, all the financial viability criteria (internal rate of return, net present value, and benefit-cost ratio) were found to be favorable and affordable to farmers in terms of investing in the developed filtration system.
LABORATORY STUDIES ON THE STABILITY AND TRANSPORT OF INORGANIC COLLOIDS THROUGH NATURAL AQUIFER MATERIAL

EPA Science Inventory

The stability and transport of radio-labeled Fe2O3 particles were studied using laboratory batch and column techniques. Core material collected from shallow sand and gravel aquifer was used as the immobile column matrix material. Variables in the study included flow rate, pH, i...
Modeling hexavalent chromium reduction in groundwater in field-scale transport and laboratory batch experiments

USGS Publications Warehouse

Friedly, J.C.; Davis, J.A.; Kent, D.B.

1995-01-01

A plausible and consistent model is developed to obtain a quantitative description of the gradual disappearance of hexavalent chromium (Cr(VI)) from groundwater in a small-scale field tracer test and in batch kinetic experiments using aquifer sediments under similar chemical conditions. The data exhibit three distinct timescales. Fast reduction occurs in well-stirred batch reactors in times much less than 1 hour and is followed by slow reduction over a timescale of the order of 2 days. In the field, reduction occurs on a timescale of the order of 8 days. The model is based on the following hypotheses. The chemical reduction reaction occurs very fast, and the longer timescales are caused by diffusion resistance. Diffusion into the secondary porosity of grains causes the apparent slow reduction rate in batch experiments. In the model of the field experiments, the reducing agent, heavy Fe(II)-bearing minerals, is heterogeneously distributed in thin strata located between larger nonreducing sand lenses that comprise the bulk of the aquifer solids. It is found that reducing strata of the order of centimeters thick are sufficient to contribute enough diffusion resistance to cause the observed longest timescale in the field. A one-dimensional advection/dispersion model is formulated that describes the major experimental trends. Diffusion rates are estimated in terms of an elementary physical picture of flow through a stratified medium containing identically sized spherical grains. Both reduction and sorption reactions are included. Batch simulation results are sensitive to the fraction of reductant located at or near the surface of grains, which controls the amount of rapid reduction, and the secondary porosity, which controls the rate of slow reduction observed in batch experiments. Results of Cr(VI) transport simulations are sensitive to the thickness and relative size of the reducing stratum. Transport simulation results suggest that nearly all of the reductant must be located in the reducing stratum. Within this context and as long as there is adequate reductive capacity present, the transport simulation results are insensitive to the parameters important for the batch simulations. The results illustrate how a combination of field measurements and batch laboratory studies can be used to improve predictive modeling of contaminant transport.
Granular activated carbon for simultaneous adsorption and biodegradation of toxic oil sands process-affected water organic compounds.

PubMed

Islam, Md Shahinoor; Zhang, Yanyan; McPhedran, Kerry N; Liu, Yang; Gamal El-Din, Mohamed

2015-04-01

Naphthenic acids (NAs) released into oil sands process-affected water (OSPW) during bitumen processing in Northern Alberta are problematic for oil sands industries due to their toxicity in the environment and resistance to degradation during conventional wastewater treatment processes. Granular activated carbon (GAC) has shown to be an effective media in removing biopersistent organics from wastewater using a combination of adsorption and biodegradation removal mechanisms. A simultaneous GAC (0.4 g GAC/L) adsorption and biodegradation (combined treatment) study was used for the treatment of raw and ozonated OSPW. After 28 days of batch treatment, classical and oxidized NAs removals for raw OSPW were 93.3% and 73.7%, and for ozonated OSPW were 96.2% and 77.1%, respectively. Synergetic effects of the combined treatment process were observed in removals of COD, the acid extractable fraction, and oxidized NAs, which indicated enhanced biodegradation and bioregeneration in GAC biofilms. A bacteria copy number >10(8) copies/g GAC on GAC surfaces was found using quantitative real time polymerase chain reaction after treatment for both raw and ozonated OSPW. A Microtox(®) acute toxicity test (Vibrio fischeri) showed effective toxicity removal (>95.3%) for the combined treatments. Therefore, the simultaneous GAC adsorption and biodegradation treatment process is a promising technology for the elimination of toxic OSPW NAs. Copyright © 2015 Elsevier Ltd. All rights reserved.
The fate of H2O2 during managed aquifer recharge: A residual from advanced oxidation processes for drinking water production.

PubMed

Wang, F; van Halem, D; van der Hoek, J P

2016-04-01

The fate of H2O2 residual from advanced oxidation process (AOP) preceding managed aquifer recharge (MAR) is of concern because H2O2 could lead to undesired effects on organisms in the MAR aquatic and soil ecosystem. The objective of this study was to distinguish between factors affecting H2O2 decomposition in MAR systems, simulated in batch reactors with synthetic MAR water and slow sand filter sand. The results showed that pure sand and soil organic matter had no considerable effect on H2O2 decomposition, whereas naturally occurring inorganic substances on the surface of sand grains and microbial biomass are the two main factors accelerating H2O2 decomposition in MAR systems. Additionally, the results showed that the H2O2 decompositions with different initial concentrations fitted first-order kinetics in 2-6 h in a mixture of slow sand filter sand (as a substitute for sand from a MAR system) and synthetic MAR water with high bacterial population. An estimation indicated that low concentrations of H2O2 (<3 mg/L) could decompose to the provisional standard of 0.25 mg/L in the first centimeters of MAR systems with the influent water containing high microbial biomass 38 ng ATP/mL. Copyright © 2016 Elsevier Ltd. All rights reserved.
Effect of bovine manure on fecal coliform attachment to soil and soil particles of different sizes.

PubMed

Guber, Andrey K; Pachepsky, Yakov A; Shelton, Daniel R; Yu, Olivia

2007-05-01

Manure-borne bacteria can be transported in runoff as free cells, cells attached to soil particles, and cells attached to manure particles. The objectives of this work were to compare the attachment of fecal coliforms (FC) to different soils and soil fractions and to assess the effect of bovine manure on FC attachment to soil and soil fractions. Three sand fractions of different sizes, the silt fraction, and the clay fraction of loam and sandy clay loam soils were separated and used along with soil samples in batch attachment experiments with water-FC suspensions and water-manure-FC suspensions. In the absence of manure colloids, bacterial attachment to soil, silt, and clay particles was much higher than the attachment to sand particles having no organic coating. The attachment to the coated sand particles was similar to the attachment to silt and clay. Manure colloids in suspensions decreased bacterial attachment to soils, clay and silt fractions, and coated sand fractions, but did not decrease the attachment to sand fractions without the coating. The low attachment of bacteria to silt and clay particles in the presence of manure colloids may cause predominantly free-cell transport of manure-borne FC in runoff.
Comparison of the release of constituents from granular materials under batch and column testing.

PubMed

Lopez Meza, Sarynna; Garrabrants, Andrew C; van der Sloot, Hans; Kosson, David S

2008-01-01

Column leaching testing can be considered a better basis for assessing field impact data than any other available batch test method and thus provides a fundamental basis from which to estimate constituent release under a variety of field conditions. However, column testing is time-intensive compared to the more simplified batch testing, and may not always be a viable option when making decisions for material reuse. Batch tests are used most frequently as a simple tool for compliance or quality control reasons. Therefore, it is important to compare the release that occurs under batch and column testing, and establish conservative interpretation protocols for extrapolation from batch data when column data are not available. Five different materials (concrete, construction debris, aluminum recycling residue, coal fly ash and bottom ash) were evaluated via batch and column testing, including different column flow regimes (continuously saturated and intermittent unsaturated flow). Constituent release data from batch and column tests were compared. Results showed no significant difference between the column flow regimes when constituent release data from batch and column tests were compared. In most cases batch and column testing agreed when presented in the form of cumulative release. For arsenic in carbonated materials, however, batch testing underestimates the column constituent release for most LS ratios and also on a cumulative basis. For cases when As is a constituent of concern, column testing may be required.
MEASUREMENT OF HYDROXYL RADICAL ACTIVITY IN A SOIL SLURRY USING THE SPIN TRAP A-(4-PYRIDYL-1-OXIDE)-N-TERT-BUTYLNITRONE

EPA Science Inventory

The spin trap compound a-(4-pyridyl-1-oxide)N-tert-butylnitrone (4-POBN) served as a probe to estimate the activity of Fenton-derived hydroxyl radicals (.OH) in a batch suspension comprised of silica sand and crushes goethite ore. The rate of probe disappearance was used to anal...
Effect of feeding strategies on pharmaceutical removal by subsurface flow constructed wetlands.

PubMed

Zhang, Dong Qing; Gersberg, Richard M; Hua, Tao; Zhu, Junfei; Nguyen, Anh Tuan; Law, Wing-Keung; Ng, Wun Jern; Tan, Soon Keat

2012-01-01

This study presents findings on an assessment of the effect of continuous and batch feeding strategies on the removal of selected pharmaceuticals from synthetic wastewater. Six mesocosm-scale constructed wetlands, including three horizontal subsurface flow constructed wetlands and three sand filters, were set up at the campus of Nanyang Technological University, Singapore. The findings showed that ibuprofen and diclofenac removal in the wetlands was significantly ( < 0.05) enhanced in the batch versus continuous mode. In contrast, naproxen and carbamazepine showed no significant differences ( > 0.05) in elimination under either feeding strategy. Our results also clearly showed that the presence of plants exerts a stimulatory effect on pharmaceutical removal for ibuprofen, diclofenac, and naproxen in batch and continuous mode. Estimation of the quantitative role of this stimulatory effect on pharmaceutical elimination of batch operation as compared with the effect of the presence of the higher plant alone showed that batch operation may account for 40 to 87% of the contribution conferred by the aquatic plant. The findings of this study imply that where maximal removal of pharmaceutical compounds is desired, periodic draining and filling might be the preferred operational strategy for full-scale, subsurface flow constructed wetlands. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.
Fertilizers mobilization in alluvial aquifer: laboratory experiments

NASA Astrophysics Data System (ADS)

Mastrocicco, M.; Colombani, N.; Palpacelli, S.

2009-02-01

In alluvial plains, intensive farming with conspicuous use of agrochemicals, can cause land pollution and groundwater contamination. In central Po River plain, paleo-channels are important links between arable lands and the underlaying aquifer, since the latter is often confined by clay sediments that act as a barrier against contaminants migration. Therefore, paleo-channels are recharge zones of particular interest that have to be protected from pollution as they are commonly used for water supply. This paper focuses on fertilizer mobilization next to a sand pit excavated in a paleo-channel near Ferrara (Italy). The problem is approached via batch test leaking and columns elution of alluvial sediments. Results from batch experiments showed fast increase in all major cations and anions, suggesting equilibrium control of dissolution reactions, limited availability of solid phases and geochemical homogeneity of samples. In column experiments, early elution and tailing of all ions breakthrough was recorded due to preferential flow paths. For sediments investigated in this study, dispersion, dilution and chemical reactions can reduce fertilizers at concentration below drinking standards in a reasonable time frame, provided fertilizer loading is halted or, at least, reduced. Thus, the definition of a corridor along paleo-channels is recommended to preserve groundwater quality.
Genome-wide transposon insertion scanning of environmental survival functions in the polycyclic aromatic hydrocarbon degrading bacterium Sphingomonas wittichii RW1.

PubMed

Roggo, Clémence; Coronado, Edith; Moreno-Forero, Silvia K; Harshman, Keith; Weber, Johann; van der Meer, Jan Roelof

2013-10-01

Sphingomonas wittichii RW1 is a dibenzofuran and dibenzodioxin-degrading bacterium with potentially interesting properties for bioaugmentation of contaminated sites. In order to understand the capacity of the microorganism to survive in the environment we used a genome-wide transposon scanning approach. RW1 transposon libraries were generated with around 22,000 independent insertions. Libraries were grown for an average of 50 generations (five successive passages in batch liquid medium) with salicylate as sole carbon and energy source in presence or absence of salt stress at -1.5 MPa. Alternatively, libraries were grown in sand with salicylate, at 50% water holding capacity, for 4 and 10 days (equivalent to 7 generations). Library DNA was recovered from the different growth conditions and scanned by ultrahigh throughput sequencing for the positions and numbers of inserted transposed kanamycin resistance gene. No transposon reads were recovered in 579 genes (10% of all annotated genes in the RW1 genome) in any of the libraries, suggesting those to be essential for survival under the used conditions. Libraries recovered from sand differed strongly from those incubated in liquid batch medium. In particular, important functions for survival of cells in sand at the short term concerned nutrient scavenging, energy metabolism and motility. In contrast to this, fatty acid metabolism and oxidative stress response were essential for longer term survival of cells in sand. Comparison to transcriptome data suggested important functions in sand for flagellar movement, pili synthesis, trehalose and polysaccharide synthesis and putative cell surface antigen proteins. Interestingly, a variety of genes were also identified, interruption of which cause significant increase in fitness during growth on salicylate. One of these was an Lrp family transcription regulator and mutants in this gene covered more than 90% of the total library after 50 generations of growth on salicylate. Our results demonstrate the power of genome-wide transposon scanning approaches for analysis of complex traits. © 2013 John Wiley & Sons Ltd and Society for Applied Microbiology.
Pattern of elemental release during the granite dissolution can be changed by aerobic heterotrophic bacterial strains isolated from Damma Glacier (central Alps) deglaciated granite sand.

PubMed

Lapanje, Aleš; Wimmersberger, Celine; Furrer, Gerhard; Brunner, Ivano; Frey, Beat

2012-05-01

Colonisation and weathering of freshly deglaciated granite are key processes in initial soil formation and development. We have obtained 438 isolates from granite sand covering glacial toe, 284 isolates at 22°C and 154 at 4°C incubation temperatures, respectively, to obtain cultures for the investigation of their weathering capabilities under laboratory conditions. The isolation of bacteria from granite sand was performed on rich-, intermediate- and low-nutrient-content solid media. Isolates were identified by 16S rRNA gene sequencing. According to the genera-associated weathering capabilities described in the literature and according to their abundance in our culture collection, we selected eight strains to analyse their effects on the weathering dynamics of granite sand during the batch culture experiment. Analysis of culturable bacteria showed higher species richness among isolates from 22°C than from 4°C incubations. In the R2A and 1/100 Ravan media, we observed the highest species richness of isolates obtained at 22°C and 4°C incubation temperatures, respectively. The obtained 16S rRNA sequences revealed the presence of alpha-, beta- and gamma-proteobacteria, Firmicutes, Actinobacteria and Bacteroidetes. The most numerous group of isolates was distantly related to Collimonas representatives, and according to the sequences of the 16S rRNA genes, they can form a new genus. Isolates from this group had the capability of causing increased dissolution rates for Fe, W, Ni and Rb. In general, at each sampling during the 30-day experiment, every strain showed a unique weathering profile resulting from differential rates of the dissolution and the precipitation of different minerals in the batch culture. Consequently, the presence of different strains, their growth stage and changes in proportions of strains in the bacterial community can affect further soil development and the successive colonisation by plants.
Reducing the chlorine dioxide demand in final disinfection of drinking water treatment plants using activated carbon.

PubMed

Sorlini, Sabrina; Biasibetti, Michela; Collivignarelli, Maria Cristina; Crotti, Barbara Marianna

2015-01-01

Chlorine dioxide is one of the most widely employed chemicals in the disinfection process of a drinking water treatment plant (DWTP). The aim of this work was to evaluate the influence of the adsorption process with granular activated carbon (GAC) on the chlorine dioxide consumption in final oxidation/disinfection. A first series of tests was performed at the laboratory scale employing water samples collected at the outlet of the DWTP sand filter of Cremona (Italy). The adsorption process in batch conditions with seven different types of GAC was studied. A second series of tests was performed on water samples collected at the outlet of four GAC columns installed at the outlet of the DWTP sand filter. The results showed that the best chlorine dioxide demand (ClO2-D) reduction yields are equal to 60-80% and are achieved in the first 30 min after ClO2 addition, during the first 16 days of the column operation using a mineral, coal-based, mesoporous GAC. Therefore, this carbon removes organic compounds that are more rapidly reactive with ClO2. Moreover, a good correlation was found between the ClO2-D and UV absorbance at wavelength 254 nm using mineral carbons; therefore, the use of a mineral mesoporous GAC is an effective solution to control the high ClO2-D in the disinfection stage of a DWTP.
Evaluation of Durability Parameters of Concrete with Manufacture Sand and River Sand

NASA Astrophysics Data System (ADS)

Sangoju, Bhaskar; Ramesh, G.; Bharatkumar, B. H.; Ramanjaneyulu, K.

2017-09-01

Most of the states in our country have banned sand quarrying from the river beds, causing a scarcity of natural river sand for the construction sector. Manufacture sand (M-sand) is one of the alternate solutions to replace the river sand (R-sand) in concrete. The main aim of the present study is to evaluate the durability parameters of concrete with M-sand when compared to that of concrete with R-sand. Corrosion of reinforcement is one of the main deteriorating mechanisms of reinforced concrete due to the ingress of chloride ions or carbon-di-oxide. For comparative evaluation of durability parameters, accelerated tests such as Rapid Chloride Permeability Test, Rapid Chloride Migration Test and accelerated carbonation test were carried out on specimens of R-sand and M-sand. All tests were carried out after 90 days of casting. Test results reveal that the durability parameters of the concrete with M-sand in chloride induced environment is relatively better than that of concrete with R-sand and hence is recommended to use M-sand as a replacement to R-sand.

Removing adsorbed heavy metal ions from sand surfaces via applying interfacial properties of rhamnolipid.

PubMed

Haryanto, Bode; Chang, Chien-Hsiang

2015-01-01

In this study, the interfacial properties of biosurfactant rhamnolipid were investigated and were applied to remove adsorbed heavy metal ions from sand surfaces with flushing operations. The surface tension-lowering activity, micelle charge characteristic, and foaming ability of rhamnolipid were identified first. For rhamnolipid in water, the negatively charged characteristic of micelles or aggregates was confirmed and the foaming ability at concentrations higher than 40 mg/L was evaluated. By using the rhamnolipid solutions in a batch washing approach, the potential of applying the interfacial properties of rhamnolipid to remove adsorbed copper ions from sand surfaces was then demonstrated. In rhamnolipid solution flushing operations for sand-packed medium, higher efficiency was found for the removal of adsorbed copper ions with residual type than with inner-sphere interaction type, implying the important role of interaction type between the copper ion and the sand surface in the removal efficiency. In addition, the channeling effect of rhamnolipid solution flow in the sand-packed medium was clearly observed in the solution flushing operations and was responsible for the low removal efficiency with low contact areas between solution and sand. By using rhamnolipid solution with foam to flush the sand-packed medium, one could find that the channeling effect of the solution flow was reduced and became less pronounced with the increase in the rhamnolipid concentration, or with the enhanced foaming ability. With the reduced channeling effect in the flushing operations, the removal efficiency for adsorbed copper ions was significantly improved. The results suggested that the foam-enhanced rhamnolipid solution flushing operation was efficient in terms of surfactant usage and operation time.
Performance comparison of sand and fine sawdust vermifilters in treating concentrated grey water for urban poor.

PubMed

Adugna, Amare T; Andrianisa, Harinaivo A; Konate, Yacouba; Ndiaye, Awa; Maiga, Amadou H

2015-01-01

A comparative investigation was conducted for 10 months with sand and fine sawdust vermifilters and a control unit to treat concentrated grey water generated from a poor urban household in Ouagadougou, Burkina Faso. Each of the filters was made up of cylindrical DN200-PVC pipes and filled with 10 cm of gravel at the bottom. On top of the gravel layer, filter 1 (fully sand, F1) was completed with 40 cm of sand and 10 cm of fine sawdust, filter 2 (partially sand, F2) with 20 cm of sand and 30 cm of fine sawdust, respectively, and filter 3 (fully sawdust, F3) and 4 (control, F4) with 50 cm of fine sawdust only. Two hundred Eudrilus eugeniae earthworms were inoculated in each of the vermifilters. The vermifiltration system was supplied with grey water four times per day at a hydraulic loading rate of 64 L/m(2)/day on a batch basis. The removal efficiencies of biological oxygen demand, total chemical oxygen demand, and dissolved chemical oxygen demand (dCOD) by the vermifilters were 25-30% higher than the control, but little differences were observed in terms of total suspended solids and coliform removal efficiencies. Though there was no significant difference in the performance of the three vermifilters (p > 0.05), except for dCOD removal efficiency, the lifespan of F2 and F3 was longer than that of F1. Therefore, fine sawdust can substitute sand as a filter medium in vermifilters.
MS2 inactivation by TiO2 nanoparticles in the presence of quartz sand

NASA Astrophysics Data System (ADS)

Syngouna, Vasiliki I.; Chrysikopoulos, Constantinos V.

2017-04-01

Virus inactivation by nanoparticles (NPs) is hypothesized to affect virus fate and transport in the subsurface. This study examines the interactions of viruses with titanium dioxide (TiO2) anatase NPs, which is a good disinfectant with unique physiochemical properties, using three different virus concentrations. The bacteriophage MS2 was used as a model virus. A series of batch experiments of MS2 inactivation by TiO2 NPs were conducted at room temperature (25 °C), in the presence of quartz sand, with and without ambient light. The virus inactivation experimental data were satisfactorily fitted with a pseudo-first order expression with a time dependent rate coefficient. Quartz sand was shown to affect MS2 inactivation by TiO2 NPs both in the presence and absence of ambient light, because, under the experimental conditions of this study, the quartz sand offers a protection to the attached MS2 against inactivation. Moreover, in most cases similar inactivation rates were observed in reactor and control tubes (absence of TiO2 NPs) suggesting that low TiO2 concentration (10 mg/L) affects only slightly MS2 inactivation with and without ambient light.
Tolerance of freshwater test organisms to formulated sediments for use as control materials in whole-sediment toxicity tests

USGS Publications Warehouse

Kemble, N.E.; Dwyer, F.J.; Ingersoll, C.G.; Dawson, T.D.; Norberg-King, T. J.

1999-01-01

A method is described for preparing formulated sediments for use intoxicity testing. Ingredients used to prepare formulated sediments included commercially available silt, clay, sand, humic acid, dolomite, and α-cellulose (as a source of organic carbon). α-Cellulose was selected as the source of organic carbon because it is commercially available, consistent from batch to batch, and low in contaminant concentrations. The tolerance of freshwater test organisms to formulated sediments for use as control materials in whole-sediment toxicity testing was evaluated. Sediment exposures were conducted for 10 d with the amphipod Hyalella azteca, the midges Chironomus riparius and C. tentans, and the oligochaete Lumbriculus variegatus and for 28 d with H. azteca. Responses of organisms in formulated sediments was compared with a field-collected control sediment that has routinely been used to determine test acceptability. Tolerance of organisms to formulated sediments was evaluated by determining responses to varying levels of α-cellulose, to varying levels of grain size, to evaluation of different food types, or to evaluation of different sources of overlying water. In the 10-d exposures, survival of organisms exposed to the formulated sediments routinely met or exceeded the responses of test organisms exposed to the control sediment and routinely met test acceptability criteria required in standard methods. Growth of amphipods and oligochaetes in 10-d exposures with formulated sediment was often less than growth of organisms in the field-collected control sediment. Additional research is needed, using the method employed to prepare formulated sediment, to determine if conditioning formulated sediments before starting 10-d tests would improve the growth of amphipods. In the 28-d exposures, survival of H. azteca was low when reconstituted water was used as the source of overlying water. However, when well water was used as the source of overlying water in 28-d exposures, consistent responses of amphipods were observed in both formulated and control sediments.
Transport characteristics of nanoscale zero-valent iron carried by three different "vehicles" in porous media.

PubMed

Su, Yan; Zhao, Yong S; Li, Lu L; Qin, Chuan Y; Wu, Fan; Geng, Nan N; Lei, Jian S

2014-01-01

This study investigated the transport properties of nanoscale zero-valent iron (Fe(0)) (nZVI) carried by three vehicles: water, sodium dodecyl sulfate (SDS) solution, and SDS foam. Batch experiments were conducted to assess the sedimentation capability of nZVI particles in these three vehicles. Column experiments were conducted to investigate the transport properties of nZVI in porous media formed with different sizes of sand (0.25 mm to 0.5 mm, 0.5 mm to 0.9 mm, and 0.9 mm to 1.4 mm). Three main results were obtained. First, the batch experiments revealed that the stabilities of nZVI particles in SDS solution and SDS foam were improved, compared with that of nZVI particles in water. Moreover, the sedimentation of nZVI in foam was closely associated with the foam drainage volume. The nZVI content in foam was similar to that in the original foaming suspension, and the nZVI particle distribution in foam became significantly more uniform at a stirring speed of 3000 r/min. Second, the transport of nZVI was enhanced by foam compared with water and SDS solution for 0.25 mm to 0.5 mm diameter sand. For sand with diameters of 0.5 mm to 0.9 mm and 0.9 mm to 1.4 mm, the mobility of nZVI carried by SDS solution was optimal, followed by that of nZVI carried by foam and water. Thus, the mobility of nZVI in finer sand was significantly enhanced by foam, compared with that in coarse sand. In contrast, compared with the bare nZVI suspension and nZVI-laden foam, the spatial distribution of nZVI particles carried by SDS solution was significantly uniform along the column length. Third, the SDS concentration significantly influenced the migration of nZVI in porous media. The enhancement in the migration of nZVI carried by SDS solution was greater at an SDS dose of 0.25% compared with that at the other three doses (0.2%, 0.5%, and 1%) for sand with a 0.25 mm to 0.5 mm diameter. Increased SDS concentrations positively affected the transport of nZVI by foam for sand with a 0.25 mm to 0.5 mm diameter, and the SDS concentrations for enhancing the mobility of nZVI carried by SDS foam satisfied the following order: 1% > 0.5% > 0.25% > 0.2%. Thus, SDS solution and SDS foam were better vehicles than water for delivering nZVI particles to porous media for contamination remediation.
Nutrient release and ammonium sorption by poultry litter and wood biochars in stormwater treatment.

PubMed

Tian, Jing; Miller, Valentina; Chiu, Pei C; Maresca, Julia A; Guo, Mingxin; Imhoff, Paul T

2016-05-15

The feasibility of using biochar as a filter medium in stormwater treatment facilities was evaluated with a focus on ammonium retention. Successive batch extractions and batch ammonium sorption experiments were conducted in both deionized (DI) water and artificial stormwater using poultry litter (PL) and hardwood (HW) biochars pyrolyzed at 400°C and 500°C. No measureable nitrogen leached from HW biochars except 0.07 μmol/g of org-N from 400°C HW biochar. PL biochar pyrolyzed at 400°C leached 120-127 μmol/g of nitrogen but only 7.1-8.6 μmol/g of nitrogen when pyrolyzed at 500°C. Ammonium sorption was significant for all biochars. At a typical ammonium concentration of 2mg/L in stormwater, the maximum sorption was 150 mg/kg for PL biochar pryolyzed at 400°C. In stormwater, ion competition (e.g. Ca(2+)) suppressed ammonium sorption compared to DI water. Surprisingly, ammonium sorption was negatively correlated to the BET surface area of the tested biochars, but increased linearly with cation exchange capacity. Cation exchange capacity was the primary mechanism controlling ammonium sorption and was enhanced by pyrolysis at 400°C, while BET surface area was enhanced by pyrolysis at 500°C. The optimal properties (BET surface area, CEC, etc.) of biochar as a sorbent are not fixed but depend on the target pollutant. Stormwater infiltration column experiments in sand with 10% biochar removed over 90% of ammonium with influent ammonium concentration of 2mg/L, compared to only 1.7% removal in a sand-only column, indicating that kinetic limitations on sorption were minor for the storm conditions studied. Hardwood and poultry litter biochar pyrolyzed at 500°C and presumably higher temperature may be viable filter media for stormwater treatment facilities, as they showed limited release of organic and inorganic nutrients and acceptable ammonium sorption. Copyright © 2016 Elsevier B.V. All rights reserved.
10 CFR 430.70 - Enforcement.

Code of Federal Regulations, 2010 CFR

2010-01-01

...), the Secretary may conduct testing of that covered product under this subpart by means of a test notice... be selected for testing, the method of selecting the test sample, the time at which testing shall be... shall select a batch, a batch sample, and test units from the batch sample in accordance with the...
Removal of Cr(VI) from Aqueous Environments Using Micelle-Clay Adsorption

PubMed Central

Qurie, Mohannad; Khamis, Mustafa; Manassra, Adnan; Ayyad, Ibrahim; Nir, Shlomo; Scrano, Laura; Bufo, Sabino A.; Karaman, Rafik

2013-01-01

Removal of Cr(VI) from aqueous solutions under different conditions was investigated using either clay (montmorillonite) or micelle-clay complex, the last obtained by adsorbing critical micelle concentration of octadecyltrimethylammonium ions onto montmorillonite. Batch experiments showed the effects of contact time, adsorbent dosage, and pH on the removal efficiency of Cr(VI) from aqueous solutions. Langmuir adsorption isotherm fitted the experimental data giving significant results. Filtration experiments using columns filled with micelle-clay complex mixed with sand were performed to assess Cr(VI) removal efficiency under continuous flow at different pH values. The micelle-clay complex used in this study was capable of removing Cr(VI) from aqueous solutions without any prior acidification of the sample. Results demonstrated that the removal effectiveness reached nearly 100% when using optimal conditions for both batch and continuous flow techniques. PMID:24222757
Influence of inorganic anions on metals release from oil sands coke and on toxicity of nickel and vanadium to Ceriodaphnia dubia.

PubMed

Puttaswamy, Naveen; Liber, Karsten

2012-02-01

In a previous study it was shown that pH significantly influences the release of metals from oil sands coke, particularly Ni and V which were identified as the cause of coke leachate toxicity. Coke comes in contact with oil sands process water (OSPW) during its transport to and long term storage in reclamation landscapes. However, the influence of dominant inorganic anions present in OSPW (i.e. HCO(3)(-), Cl(-) and SO(4)(2-)) on metals release from coke and on speciation and toxicity of Ni and V, has not been characterized before. Coke was subjected to a 15-d batch leaching process at four levels of HCO(3)(-), Cl(-) and SO(4)(2-) to determine the influence on metals release and speciation. Further, the effects of each of the three anions on Ni and V toxicity, as well as the mixture toxicity of Ni and V, were assessed using the three-brood Ceriodaphnia dubia test. Inorganic anions had a significant influence on the type and amount of metals released from coke. Specifically, sulfate increased the mobilization of cationic metals (e.g. Ni, Fe, Mn and Zn), whereas bicarbonate enhanced the release of oxyanion forming metals (e.g. Al, As, Mo and V) from coke. Chloride had no particular effect on the type and amount of metals released. With respect to toxicity, elevated bicarbonate levels decreased the 7-d Ni IC50 from 6.3 to 2.3 μg L(-1), whereas sulfate showed an ameliorative effect against V toxicity to C. dubia. In combination, Ni and V acted additively at their highest sub-lethal concentrations. Aqueous chemistry and toxicity of Ni and V are discussed with the goal of informing reclamation efforts at the Athabasca oil sands. Copyright © 2011 Elsevier Ltd. All rights reserved.
Are allergen batch differences and the use of double skin prick test important?

PubMed

Thomsen, Gert F; Schlünssen, Vivi; Skadhauge, Lars R; Malling, Tine Halsen; Sherson, David L; Omland, Øyvind; Sigsgaard, Torben

2015-04-09

Skin prick tests (SPT) are widely used both in clinical diagnostics and in research. The standardization of allergen extracts is well documented to be crucial for the validity of SPT, whereas less emphasis has been placed on reproducibility and the SPT procedure itself. The objectives of this study are to clarify how the double skin prick test procedure influence the sensitivity and specificity of the test and to analyse the differences in weal size in skin prick tests between two batches of allergen extracts from the same vendor. The association between rhinitis and SPT was assessed among 1135 persons from a general population sample. SPT was performed twice with 10 common aeroallergens. In a subsample of 90 persons SPT was performed simultaneously with five of the allergens using different batches. Thirty percent had at least one positive SPT. Among asthmatics this number was 62%. Only minor differences were seen between the sizes of two weals from the same batch. A second SPT with the same batch did not change the association between rhinitis and sensitization. When performing SPT with two different batches disagreement was observed in 2% (Birch) to 11% (Cat) of the subjects. Performing SPT twice with the same allergen batch does not enhance the validity of the test, and value of double testing can be questioned. Considerable differences in SPT response with different batches from the same manufacturer were observed. Thus inter batch differences in allergen extracts might be a source of variability.
40 CFR 204.51 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... tests. (m) Test sample means the collection of compressors from the same category or configuration which is randomly drawn from the batch sample and which will receive emissions tests. (n) Batch size means... category or configuration in a batch. (o) Test sample size means the number of compressors of the same...
Electrokinetic transport of aerobic microorganisms under low-strength electric fields.

PubMed

Maillacheruvu, Krishnanand Y; Chinchoud, Preethi R

2011-01-01

To investigate the feasibility of utilizing low strength electric fields to transport commonly available mixed cultures such as those from an activated sludge process, bench scale batch reactor studies were conducted in sand and sandy loam soils. A readily biodegradable substrate, dextrose, was used to test the activity of the transported microorganisms. Electric field strengths of 7V, 10.5V, and 14V were used. Results from this investigation showed that an electric field strength of 0.46 Volts per cm was sufficient to transport activated sludge microorganisms across a sandy loam soil across a distance of about 8 cm in 72 h. More importantly, the electrokinetically transported microbial culture remained active and viable after the transport process and was biodegrade 44% of the dextrose in the soil medium. Electrokinetic treatment without microorganisms resulted in removal of 37% and the absence of any treatment yielded a removal of about 15%.
Sand Impact Tests of a Half-Scale Crew Module Boilerplate Test Article

NASA Technical Reports Server (NTRS)

Vassilakos, Gregory J.; Hardy, Robin C.

2012-01-01

Although the Orion Multi-Purpose Crew Vehicle (MPCV) is being designed primarily for water landings, a further investigation of launch abort scenarios reveals the possibility of an onshore landing at Kennedy Space Center (KSC). To gather data for correlation against simulations of beach landing impacts, a series of sand impact tests were conducted at NASA Langley Research Center (LaRC). Both vertical drop tests and swing tests with combined vertical and horizontal velocity were performed onto beds of common construction-grade sand using a geometrically scaled crew module boilerplate test article. The tests were simulated using the explicit, nonlinear, transient dynamic finite element code LS-DYNA. The material models for the sand utilized in the simulations were based on tests of sand specimens. Although the LSDYNA models provided reasonable predictions for peak accelerations, they were not always able to track the response through the duration of the impact. Further improvements to the material model used for the sand were identified based on results from the sand specimen tests.
Constitutive Soil Properties for Unwashed Sand and Kennedy Space Center

NASA Technical Reports Server (NTRS)

Thomas, Michael A.; Chitty, Daniel E.; Gildea, Martin L.; T'Kindt, Casey M.

2008-01-01

Accurate soil models are required for numerical simulations of land landings for the Orion Crew Exploration Vehicle. This report provides constitutive material models for one soil, unwashed sand, from NASA Langley's gantry drop test facility and three soils from Kennedy Space Center (KSC). The four soil models are based on mechanical and compressive behavior observed during geotechnical laboratory testing of remolded soil samples. The test specimens were reconstituted to measured in situ density and moisture content. Tests included: triaxial compression, hydrostatic compression, and uniaxial strain. A fit to the triaxial test results defines the strength envelope. Hydrostatic and uniaxial tests define the compressibility. The constitutive properties are presented in the format of LS-DYNA Material Model 5: Soil and Foam. However, the laboratory test data provided can be used to construct other material models. The four soil models are intended to be specific to the soil conditions discussed in the report. The unwashed sand model represents clayey sand at high density. The KSC models represent three distinct coastal sand conditions: low density dry sand, high density in-situ moisture sand, and high density flooded sand. It is possible to approximate other sands with these models, but the results would be unverified without geotechnical tests to confirm similar soil behavior.
21 CFR 320.35 - Requirements for in vitro testing of each batch.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 5 2011-04-01 2011-04-01 false Requirements for in vitro testing of each batch... Determining the Bioavailability or Bioequivalence of Drug Products § 320.35 Requirements for in vitro testing of each batch. If a bioequivalence requirement specifies a currently available in vitro test or an in...
21 CFR 320.35 - Requirements for in vitro testing of each batch.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 5 2010-04-01 2010-04-01 false Requirements for in vitro testing of each batch... Determining the Bioavailability or Bioequivalence of Drug Products § 320.35 Requirements for in vitro testing of each batch. If a bioequivalence requirement specifies a currently available in vitro test or an in...
Constitutive Soil Properties for Mason Sand and Kennedy Space Center

NASA Technical Reports Server (NTRS)

Thomas, Michael A.; Chitty, Daniel E.

2011-01-01

Accurate soil models are required for numerical simulations of land landings for the Orion Crew Exploration Vehicle (CEV). This report provides constitutive material models for two soil conditions at Kennedy Space Center (KSC) and four conditions of Mason Sand. The Mason Sand is the test sand for LaRC s drop tests and swing tests of the Orion. The soil models are based on mechanical and compressive behavior observed during geotechnical laboratory testing of remolded soil samples. The test specimens were reconstituted to measured in situ density and moisture content. Tests included: triaxial compression, hydrostatic compression, and uniaxial strain. A fit to the triaxial test results defines the strength envelope. Hydrostatic and uniaxial tests define the compressibility. The constitutive properties are presented in the format of LSDYNA Material Model 5: Soil and Foam. However, the laboratory test data provided can be used to construct other material models. The soil models are intended to be specific to the soil conditions they were tested at. The two KSC models represent two conditions at KSC: low density dry sand and high density in-situ moisture sand. The Mason Sand model was tested at four conditions which encompass measured conditions at LaRC s drop test site.
Effect of residual H2O2 from advanced oxidation processes on subsequent biological water treatment: A laboratory batch study.

PubMed

Wang, Feifei; van Halem, Doris; Liu, Gang; Lekkerkerker-Teunissen, Karin; van der Hoek, Jan Peter

2017-10-01

H 2 O 2 residuals from advanced oxidation processes (AOPs) may have critical impacts on the microbial ecology and performance of subsequent biological treatment processes, but little is known. The objective of this study was to evaluate how H 2 O 2 residuals influence sand systems with an emphasis on dissolved organic carbon (DOC) removal, microbial activity change and bacterial community evolution. The results from laboratory batch studies showed that 0.25 mg/L H 2 O 2 lowered DOC removal by 10% while higher H 2 O 2 concentrations at 3 and 5 mg/L promoted DOC removal by 8% and 28%. A H 2 O 2 dosage of 0.25 mg/L did not impact microbial activity (as measured by ATP) while high H 2 O 2 dosages, 1, 3 and 5 mg/L, resulted in reduced microbial activity of 23%, 37% and 37% respectively. Therefore, DOC removal was promoted by the increase of H 2 O 2 dosage while microbial activity was reduced. The pyrosequencing results illustrated that bacterial communities were dominated by Proteobacteria. The presence of H 2 O 2 showed clear influence on the diversity and composition of bacterial communities, which became more diverse under 0.25 mg/L H 2 O 2 but conversely less diverse when the dosage increased to 5 mg/L H 2 O 2 . Anaerobic bacteria were found to be most sensitive to H 2 O 2 as their growth in batch reactors was limited by both 0.25 and 5 mg/L H 2 O 2 (17-88% reduction). In conclusion, special attention should be given to effects of AOPs residuals on microbial ecology before introducing AOPs as a pre-treatment to biological (sand) processes. Additionally, the guideline on the maximum allowable H 2 O 2 concentration should be properly evaluated. Copyright © 2017 The Author(s). Published by Elsevier Ltd.. All rights reserved.
Comparison of batch and column tests for the elution of artificial turf system components.

PubMed

Krüger, O; Kalbe, U; Berger, W; Nordhauβ, K; Christoph, G; Walzel, H-P

2012-12-18

Synthetic athletic tracks and turf areas for outdoor sporting grounds may release contaminants due to the chemical composition of some components. A primary example is that of zinc from reused scrap tires (main constituent, styrene butadiene rubber, SBR), which might be harmful to the environment. Thus, methods for the risk assessment of those materials are required. Laboratory leaching methods like batch and column tests are widely used to examine the soil-groundwater pathway. We tested several components for artificial sporting grounds with batch tests at a liquid to solid (LS) ratio of 2 L/kg and column tests with an LS up to 26.5 L/kg. We found a higher zinc release in the batch test eluates for all granules, ranging from 15% higher to 687% higher versus data from column tests for SBR granules. Accompanying parameters, especially the very high turbidity of one ethylene propylene diene monomer rubber (EPDM) or thermoplastic elastomer (TPE) eluates, reflect the stronger mechanical stress of batch testing. This indicates that batch test procedures might not be suitable for the risk assessment of synthetic sporting ground components. Column tests, on the other hand, represent field conditions more closely and allow for determination of time-dependent contaminants release.
A remediation performance model for enhanced metabolic reductive dechlorination of chloroethenes in fractured clay till

NASA Astrophysics Data System (ADS)

Manoli, Gabriele; Chambon, Julie C.; Bjerg, Poul L.; Scheutz, Charlotte; Binning, Philip J.; Broholm, Mette M.

2012-04-01

A numerical model of metabolic reductive dechlorination is used to describe the performance of enhanced bioremediation in fractured clay till. The model is developed to simulate field observations of a full scale bioremediation scheme in a fractured clay till and thereby to assess remediation efficiency and timeframe. A relatively simple approach is used to link the fermentation of the electron donor soybean oil to the sequential dechlorination of trichloroethene (TCE) while considering redox conditions and the heterogeneous clay till system (clay till matrix, fractures and sand stringers). The model is tested on lab batch experiments and applied to describe sediment core samples from a TCE-contaminated site. Model simulations compare favorably to field observations and demonstrate that dechlorination may be limited to narrow bioactive zones in the clay matrix around fractures and sand stringers. Field scale simulations show that the injected donor is expected to be depleted after 5 years, and that without donor re-injection contaminant rebound will occur in the high permeability zones and the mass removal will stall at 18%. Long remediation timeframes, if dechlorination is limited to narrow bioactive zones, and the need for additional donor injections to maintain dechlorination activity may limit the efficiency of ERD in low-permeability media. Future work should address the dynamics of the bioactive zones, which is essential to understand for predictions of long term mass removal.

21 CFR 320.34 - Requirements for batch testing and certification by the Food and Drug Administration.

Code of Federal Regulations, 2010 CFR

2010-04-01

... necessary to assure that all batches of the same drug product meet an appropriate in vitro test, he shall include in the bioequivalence requirement a requirement for manufacturers to submit samples of each batch...
21 CFR 320.34 - Requirements for batch testing and certification by the Food and Drug Administration.

Code of Federal Regulations, 2011 CFR

2011-04-01

... necessary to assure that all batches of the same drug product meet an appropriate in vitro test, he shall include in the bioequivalence requirement a requirement for manufacturers to submit samples of each batch...
Preliminary study of tin slag concrete mixture

NASA Astrophysics Data System (ADS)

Hashim, Mohd Jamil; Mansor, Ishak; Pauzi Ismail, Mohamad; Sani, Suhairy; Azmi, Azhar; Sayuti, Shaharudin; Zaidi Ibrahim, Mohd; Adli Anuar, Abul; Rahim, Abdul Adha Abdul

2018-01-01

The study focuses on practices to facilitate tin smelting industry to reduce radioactive waste product (Tin Slag) by diluting its radioactivity to a safe level and turning it to a safer infrastructural building product. In the process the concrete mix which include Portland cement, sand, tin slag, water and plasticizer are used to produce interlocking brick pavements, piles and other infrastructural products. The mixing method follows DOE (UK) standard method of mixing targeted at in selected compressive strength suitable for its function and durability. A batching machine is used in the mixing and six test cubes are produced for the test. The testing equipment used are a compressional machine, ultrasonic measurement and a Geiger Muller counter to evaluate of the concrete mix to find the lowest emission of radiation surface dose without compromising the strength of concrete mix. The result obtained indicated the radioactivity of tin slag in the mixing process has reduced to background level that is 0.5μSv/h while the strength and workability of the concrete has not been severely affected. In conclusion, the concrete mix with tin slag has shown the potential it can be turned into a safe beneficial infrastructural product with good strength.
Examination of Technetium Transport Through Soils Under Contrasting Redox Conditions: Batch and Column Work

NASA Astrophysics Data System (ADS)

Dozier, R.; Montgomery, D.; Wylie, E. M.; Dogan, M.; Moysey, S. M.; Powell, B. A.; Martinez, N. E.

2015-12-01

Experiments were performed under various reducing conditions to evaluate the transport behavior of technetium-99 (99Tc) in the presence of sandy clay loam soil from the Savannah River Site (SRS) and goethite, magnetite, and iron sulfide, which were selected for their increasing reducing potential. The experiments were conducted to investigate how redox reaction equilibria and rates affect the overall mobility of 99Tc as it transitions between the mobile Tc(VII) and immobile Tc(IV). Under oxygen-rich conditions, batch sorption isotherms measured for TcO4- across the concentration range 0.5 to 50 μg/L were linear with distribution coefficients (Kd) of 0.78 mL/g or lower, with decreasing sorption for goethite, magnetite, and iron sulfide, respectively. Addition of Na2S resulted in a marked increase in apparent 99Tc sorption to the solid phase, with Kd of 43 mL/g, 35 mL/g, and 29 mL/g, following the same mineral trend as previously. The increased Kd values are possibly due to reduction of Tc(VII) to Tc(IV), resulting in the formation of TcO2(s). SRS soil batch sorption isotherms measured for TcO4- across the same concentration range were also linear, with Kd of 0.7 mL/g for unadjusted pH, 5.1 mL/g for pH of around 6, and 6.7 mL/g for pH of around 4. Kinetic batch sorption tests showed less than 10% 99Tc sorption in an oxidizing environment and greater than 95% sorption in a reducing environment, with both reactions occurring on the order of minutes. In contrast, desorption experiments initiated by transferring the samples from a reducing environment (0.1% H2(g)/99.9% N2(g)) to atmospheric conditions resulted in a slow desorption step on the order of days. Column experiments conducted with the SRS sands indicate a retardation factor of 1.17 for 99Tc under oxygen rich conditions. Additional column experiments are being conducted to evaluate 99Tc transport dependencies on transitions between oxygen rich and poor conditions.
Oxygen profile and clogging in vertical flow sand filters for on-site wastewater treatment.

PubMed

Petitjean, A; Forquet, N; Boutin, C

2016-04-01

13 million people (about 20% of the population) use on-site wastewater treatment in France. Buried vertical sand filters are often built, especially when the soil permeability is not sufficient for septic tank effluent infiltration in undisturbed soil. Clogging is one of the main problems deteriorating the operation of vertical flow filters for wastewater treatment. The extent of clogging is not easily assessed, especially in buried vertical flow sand filters. We suggest examining two possible ways of detecting early clogging: (1) NH4-N/NO3-N outlet concentration ratio, and (2) oxygen measurement within the porous media. Two pilot-scale filters were equipped with probes for oxygen concentration measurements and samples were taken at different depths for pollutant characterization. Influent and effluent grab-samples were taken three times a week. The systems were operated using batch-feeding of septic tank effluent. Qualitative description of oxygen transfer processes under unclogged and clogged conditions is presented. NH4-N outlet concentration appears to be useless for early clogging detection. However, NO3-N outlet concentration and oxygen content allows us to diagnose the early clogging of the system. Copyright © 2016 Elsevier Ltd. All rights reserved.
[Testing of medicinal products produced from pooled plasma].

PubMed

Unkelbach, U; Hunfeld, A; Breitner-Ruddock, S

2014-10-01

Medicinal products produced from human plasma fall under the administrative batch release procedure of the competent authority. In Germany, this has been carried out since 1995 by the Paul Ehrlich Institute (PEI), the responsible state control agency for blood products. Medicinal products released for the European and national market are tested for quality, efficacy and safety. Experimental testing of the final product and the starting materials, the plasma pools, as well as control of the production documentation guarantee a constantly high product safety. In the 28,000 batches tested since the beginning of the state controlled batch release testing of these blood products at the PEI, there has been no transmission of infectious viruses (HIV, HBV and HCV) to any patient. The batch release has made a contribution to the improvement of product quality. This procedure is still an important tool to ensure safety of blood products. The PEI is integrated in the batch release network of the European Directorate for the Quality of Medicines & Health Care (EDQM) in Strasbourg. Regulations and guidelines for official control authority batch release (OCABR) ensure harmonized procedures for mutual recognition of batch release on the European level. The EU certificates and German national certificates are requested and accepted in over 70 countries worldwide. Experimental testing in the EU and the requisite certificates have developed into a seal of quality for the world market.
40 CFR 1065.545 - Verification of proportional flow control for batch sampling.

Code of Federal Regulations, 2014 CFR

2014-07-01

... control for batch sampling. 1065.545 Section 1065.545 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Performing an Emission Test Over Specified Duty Cycles § 1065.545 Verification of proportional flow control for batch sampling. For any...
Application Of Bacterial Iron Reduction For The Removal Of Iron Impurities From Industrial Silica Sand And Kaolin

NASA Astrophysics Data System (ADS)

Zegeye, A.; Yahaya, S.; Fialips, C. I.; White, M.; Manning, D. A.; Gray, N.

2008-12-01

Biogeochemical evidence exists to support the potential importance of crystalline or amorphous Fe minerals as electron acceptor for Fe reducing bacteria in soils and subsurface sediments. This microbial metabolic activity can be exploited as alternative method in different industrial applications. For instance, the removal of ferric iron impurities from minerals for the glass and paper industries currently rely on physical and chemical treatments having substantial economical and environmental disadvantages. The ability to remove iron by other means, such as bacterial iron reduction, may reduce costs, allow lower grade material to be mined, and improve the efficiency of mineral processing. Kaolin clay and silica sand are used in a wide range of industrial applications, particularly in paper, ceramics and glass manufacturing. Depending on the geological conditions of deposition, they are often associated with iron (hydr)oxides that are either adsorbed to the mineral surfaces or admixed as separate iron bearing minerals. In this study, we have examined the Fe(III) removal efficiency from kaolin and silica sand by a series of iron- reducing bacteria from the Shewanella species (S. alga BrY, S. oneidensis MR-1, S. putrefaciens CN32 and S. putrefaciens ATCC 8071) in the presence of anthraquinone 2,6 disulfonate (AQDS). We have also investigated the effectiveness of a natural organic matter, extracted with the silica sand, as a substitute to AQDS for enhancing Fe(III) reduction kinetics. The microbial reduction of Fe(III) was achieved using batch cultures under non-growth conditions. The rate and the extent of Fe(III) reduction was monitored as a function of the initial Fe(III) content, Shewanella species and temperature. The bacterially- treated minerals were analyzed by transmission electron microscopy (TEM) and X-ray diffraction (XRD) to observe any textural and mineralogical transformation. The whiteness and ISO brightness of the kaolin was also measured by spectrophotometry for quality testing. All Shewanella species were able to couple the oxidation of lactate to the reduction of Fe(III) associated with the kaolins and silica sands. However, there are differences among species with respect to the rate and extent of iron leaching. S. putrefaciens ATCC 8071 is the most effective, with a 10% increase in kaolin whiteness and 4% increase in ISO brightness in less than 5 days.
Acceptance Test Data for BWXT Coated Particle Batches 93172B and 93173B—Defective IPyC and Pyrocarbon Anisotropy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hunn, John D.; Helmreich, Grant W.; Dyer, John A.

Coated particle batches J52O-16-93172B and J52O-16-93173B were produced by Babcock and Wilcox Technologies (BWXT) as part of the production campaign for the Advanced Gas Reactor Fuel Development and Qualification (AGR) Program’s AGR-5/6/7 irradiation test in the Idaho National Laboratory (INL) Advanced Test Reactor (ATR), but were not used in the final fuel composite. However, these batches may be used as demonstration production-scale coated particle fuel for other experiments. Each batch was coated in a 150-mm-diameter production-scale fluidized-bed chemical vapor deposition (CVD) furnace. Tristructural isotropic (TRISO) coatings were deposited on 425-μm-nominal-diameter spherical kernels from BWXT lot J52R-16-69317 containing a mixture ofmore » 15.5%-enriched uranium carbide and uranium oxide (UCO). The TRISO coatings consisted of four consecutive CVD layers: a ~50% dense carbon buffer layer with 100-μm-nominal thickness, a dense inner pyrolytic carbon (IPyC) layer with 40-μm-nominal thickness, a silicon carbide (SiC) layer with 35-μm-nominal thickness, and a dense outer pyrolytic carbon (OPyC) layer with 40-μm-nominal thickness. The TRISO-coated particle batches were sieved to upgrade the particles by removing over-sized and under-sized material, and the upgraded batches were designated by appending the letter A to the end of the batch number (e.g., 93172A). Secondary upgrading by sieving was performed on the A-designated batches to remove particles with missing or very-thin buffer layers that were identified during previous analysis of the individual batches for defective IPyC, as reported in the acceptance test data report for the AGR-5/6/7 production batches [Hunn et al. 2017b]. The additionally-upgraded batches were designated by appending the letter B to the end of the batch number (e.g., 93172B).« less
Evaluation of pharmaceuticals removal by sewage sludge-derived adsorbents with rapid small-scale column tests

NASA Astrophysics Data System (ADS)

Zhang, P.; Ding, R.; Wallace, R.; Bandosz, T.

2015-12-01

New composite adsorbents were developed by pyrolyzing sewage sludge and fish waste (75:25 or 90:10 dry mass ratio) at 650 oC and 950 oC. Batch adsorption experiments demonstrated that the composite adsorbents were able to adsorb a wide range of organic contaminants (volatile organic compounds, pharmaceuticals and endocrine disrupting compounds (EDCs), and nitrosamine disinfection byproducts) with high capacities. Here we further examine the performance of the adsorbents for the simultaneous removal of 8 pharmaceuticals and EDCs with rapid small-scale column tests (RSSCT). Results show that the order of breakthrough in RSSCT is in general consistent with the affinity determined via batch tests. As expected, the maximum amount of adsorption for each compound obtained from RSSCT is identical to or less than that obtained from batch tests (with only one exception), due to adsorption kinetics. However, despite the very different input concentration (1 mg/L vs. 100 mg/L) and contact time (2 min empty bed contact time vs. 16 hour equilibrium time) used in RSSCT and batch tests, the maximum amount of pharmaceuticals and EDCs adsorbed under RSSCT is still about one half of that under equilibrium batch tests, validating the approach of using batch tests with much higher input concentrations to determine adsorption capacities. Results of a pilot-scale column test in a drinking water treatment plant for pharmaceuticals removal will also be presented.
Characterization and Evaluation of Incorporation the Casting Sand in Mortar

NASA Astrophysics Data System (ADS)

Zanelato, E. B.; Azevedo, A. R. G.; Alexandre, J.; Xavier, C. G.; Monteiro, S. N.; Mendonça, T. A. O.

The process of casting metals and alloys occurs through the fusion of this metal and its subsequent casting into a mold with the dimensions and geometry close to the final piece. Most foundries use sand casting molds for making you. This work aims to characterize and evaluate the foundry sand to allow its use in segments of Civil Engineering, creating a viable destination for a residue is that discarded. The following characterization tests were performer: particle size, chemical analysis, X-ray Diffraction and Density Real grain. For the execution of the test specimens was used to 1:3 cement and sand, and the incorporation of 10% and 20% of the total mass replacing the sand, and the trace reference. The results show that best results in compression and bending tests were obtained by replacing 10 % of common sand for sand casting.
U(VI) adsorption on aquifer sediments at the Hanford Site.

PubMed

Um, Wooyong; Serne, R Jeffrey; Brown, Christopher F; Last, George V

2007-08-15

Aquifer sediments collected via split-spoon sampling in two new groundwater wells in the 200-UP-1 operable unit at the Hanford Site were characterized and showed typical Ringold Unit E Formation properties dominated by gravel and sand. High iron-oxide content in Fe oxide/clay coatings caused the highest U(VI) adsorption as quantified by batch K(d) values, indicating iron oxides are the key solid adsorbent in the 200-UP-1 sediments that affect U(VI) fate and mobility. Even though U(VI) adsorption on the gravel-sized fraction of the sediments is considered to be negligible, careful characterization should be conducted to determine U(VI) adsorption on gravel, because of presence of Fe oxides coatings and diffusion-controlled adsorption into the gravel particles' interior surfaces. A linear adsorption isotherm was observed up to 10(-6) M (238 microg/L) of total U(VI) concentration in batch U(VI) adsorption tests with varying total U(VI) concentrations in spiked groundwater. U(VI) adsorption decreased with increasing concentrations of dissolved carbonate, because strong anionic aqueous uranium-carbonate complexes formed at high pH and high alkalinity conditions. Noticeable uranium desorption hysteresis was observed in a flow-through column experiment, suggesting that desorption K(d) values for aged uranium-contaminated sediments at the Hanford Site can be larger than adsorption K(d) values determined in short-term laboratory experiments and slow uranium release from contaminated sediments into the groundwater is expected.
A need for a standardization in anaerobic digestion experiments? Let's get some insight from meta-analysis and multivariate analysis.

PubMed

Lavergne, Céline; Jeison, David; Ortega, Valentina; Chamy, Rolando; Donoso-Bravo, Andrés

2018-09-15

An important variability in the experimental results in anaerobic digestion lab test has been reported. This study presents a meta-analysis coupled with multivariate analysis aiming to assess the impact of this experimental variability in batch and continuous operation at mesophilic and thermophilic anaerobic digestion of waste activated sludge. An analysis of variance showed that there was no significant difference between mesophilic and thermophilic conditions in both continuous and batch conditions. Concerning the operation mode, the values of methane yield were significantly higher in batch experiment than in continuous reactors. According to the PCA, for both cases, the methane yield is positive correlated to the temperature rises. Interestingly, in the batch experiments, the higher the volatile solids in the substrate was, the lowest was the methane production, which is correlated to experimental flaws when setting up those tests. In continuous mode, unlike the batch test, the methane yield is strongly (positively) correlated to the organic content of the substrate. Experimental standardization, above all, in batch conditions are urgently necessary or move to continuous experiments for reporting results. The modeling can also be a source of disturbance in batch test. Copyright © 2018 Elsevier Ltd. All rights reserved.
Acceptance Test Data for the AGR-5/6/7 Irradiation Test Fuel Composite Defective IPyC Fraction and Pyrocarbon Anisotropy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Helmreich, Grant W.; Hunn, John D.; Skitt, Darren J.

Coated particle composite J52R-16-98005 was produced by Babcock and Wilcox Technologies (BWXT) as fuel for the Advanced Gas Reactor Fuel Development and Qualification (AGR) Program’s AGR-5/6/7 irradiation test in the Idaho National Laboratory (INL) Advanced Test Reactor (ATR). This composite was comprised of four coated particle fuel batches J52O-16-93165B (26%), 93168B (26%), 93169B (24%), and 93170B (24%), chosen based on the Quality Control (QC) data acquired for each individual candidate AGR-5/6/7 batch. Each batch was coated in a 150-mm-diameter production-scale fluidized-bed chemical vapor deposition (CVD) furnace. Tristructural isotropic (TRISO) coatings were deposited on 425-μm-nominal-diameter spherical kernels from BWXT Lot J52R-16-69317more » containing a mixture of 15.5%-enriched uranium carbide and uranium oxide (UCO). The TRISO coatings consisted of four consecutive CVD layers: a ~50% dense carbon buffer layer with 100-μm-nominal thickness, a dense inner pyrolytic carbon (IPyC) layer with 40-μm-nominal thickness, a silicon carbide (SiC) layer with 35-μm-nominal thickness, and a dense outer pyrolytic carbon (OPyC) layer with 40-μm-nominal thickness. The TRISO-coated particle batches were sieved to upgrade the particles by removing over-sized and under-sized material, and the upgraded batches were designated by appending the letter A to the end of the batch number (e.g., 93165A). Secondary upgrading by sieving was performed on the A-designated batches to remove particles with missing or very-thin buffer layers that were identified during previous analysis of the individual batches for defective IPyC, as reported in the acceptance test data report for the AGR-5/6/7 production batches [Hunn et al. 2017]. The additionally-upgraded batches were designated by appending the letter B to the end of the batch number (e.g., 93165B).« less
Sorption characteristics of cadmium in a clay soil of Mae Ku creek, Tak Province, Thailand

NASA Astrophysics Data System (ADS)

Thunyawatcharakul, P.; Chotpantarat, S.

2018-05-01

Mae Sot is a district in Tak province, the northern part of Thailand where has encountered with cadmium (Cd) contaminated in soils. Exposure of Cd can lead to severe health effect, for examples, bone softening, osteoporosis, renal dysfunction, and Itai-Itai disease. This study aims at elucidating sorption behavior of Cd in the contaminated soil collected from Mae Ku creek, Mae Sot district, Thailand. Batch sorption experiment was conducted in order to investigate sorption characteristics of Cd onto the contaminated soil. The soil sample taken from the study area consists of 26% sand, 16% silt 58% clay, which categorized as a clay soil, based on USDA classification. Soil pH is slightly alkaline (pH∼7.7) and organic matter in the soil is 2.93%. The initial concentration in the batch sorption experiment was in the range from 0- 200 ppm. The result from the batch sorption experiment showed that soil sample can adsorb Cd up to 173.5 ppm and the sorption behavior of the soil sample can be well described by Freundlich isotherm, indicating the multilayer sorption (R2 = 0.9964), with Freundlich constants of 0.312 and 1.760 L g-1 for 1/n and Kf, respectively.
The Influence of Hydrophilic Interactions on the Sorption and Mobility of Naproxen at Environmentally-Relevant Concentrations

NASA Astrophysics Data System (ADS)

Muller, K.; Ramsburg, C. A.

2011-12-01

Managed underground storage of reclaimed wastewater is currently one viable option for meeting increasing demands on water resources, yet the attenuation of many emerging contaminants within the subsurface environment is not well understood. Pharmaceuticals are of particular concern due to the rapid increase in development and use of these compounds, observations of incomplete removal during wastewater treatment, and emerging concerns over ecosystem effects. Assessment of the subsurface attenuation of pharmaceuticals is difficult because the compounds are polar, pH-active, and present at low-concentration (ng/L). Predictions of sorption that only consider hydrophobic interactions with soil organic matter may not fully describe the extent to which reversible sequestration influences pharmaceutical attenuation. In fact, hydrophilic interactions (i.e. ion exchange, cation-induced sorption, hydrogen bonding, etc) may represent important contributions to total sorption, especially when aqueous solutes are present at low concentration. Here we assess the sorption of naproxen - an acidic pharmaceutical - to three subsurface materials using equilibrium batch experiments and 1-d column experiments. Subsurface materials evaluated include Ottawa sand (quartz with negligible organic carbon and negligible iron oxide), Aplite sand (quartz and feldspar with negligible organic carbon, 0.2% wt iron oxide), and a Hinckley series silty-sand (quartz and feldspar with 0.95% wt organic carbon, and 0.4% wt iron oxides). Sorption of naproxen to the Ottawa sand was negligible and did not result in measurable retardation when naproxen was introduced to the porous medium at a concentration of 275 ng/L. Batch experiments suggest that Aplite sand offers quantifiable interaction (52% of the mass introduced is associated with the solid phase when the aqueous concentration is 1000 ng/L and the solid to liquid ratio is 1.4:1 v/v); however, column data are indicative of markedly less interaction and retardation. Naproxen sorption to the Hinckley series material was considerable (99% of the mass introduced is associated with the solid phase when the aqueous concentration is 1000 ng/L and the solid to liquid ratio is 1:1 v/v). Predictions of naproxen sorption based upon the fraction of organic carbon and the organic-carbon partitioning coefficient (Koc) greatly underestimated the sorption observed in all experiments conducted with the Hinckley series material. Assessment of sorption under 1 mM NaH2PO4 (a sorbant with a strong affinity for hydrophilic sites) suggests that hydrophobic interactions account for approximately 45% of the total interaction. Breakthrough of naproxen (C0 ~ 20 ug/L) was substantially retarded in experiments conducted with the Hinckley material and a thermally-treated Hinckley material (negligible organic carbon). These results highlight the potential role of hydrophilic interactions during the transport and attenuation of acidic pharmaceuticals at solute concentrations typical of water reuse applications.
Vitrification of copper flotation waste.

PubMed

Karamanov, Alexander; Aloisi, Mirko; Pelino, Mario

2007-02-09

The vitrification of an hazardous iron-rich waste (W), arising from slag flotation of copper production, was studied. Two glasses, containing 30wt% W were melted for 30min at 1400 degrees C. The first batch, labeled WSZ, was obtained by mixing W, blast furnace slag (S) and zeolite tuff (Z), whereas the second, labeled WG, was prepared by mixing W, glass cullet (G), sand and limestone. The glass frits showed high chemical durability, measured by the TCLP test. The crystallization of the glasses was evaluated by DTA. The crystal phases formed were identified by XRD resulting to be pyroxene and wollastonite solid solutions, magnetite and hematite. The morphology of the glass-ceramics was observed by optical and scanning electron microscopy. WSZ composition showed a high rate of bulk crystallization and resulted to be suitable for producing glass-ceramics by a short crystallization heat-treatment. WG composition showed a low crystallization rate and good sinterability; glass-ceramics were obtained by sinter-crystallization of the glass frit.
22. INTERIOR VIEW WITH INTERIOR VIEW OF MOLDING SANDS CONTROL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. INTERIOR VIEW WITH INTERIOR VIEW OF MOLDING SANDS CONTROL AND TEST LAB FOR UNIT NO. 2 GREY IRON DISAMATIC. SAND CASTING TECHNICIAN, ROY BATES, TESTS THE WEIGHT OF THE SAND, DRYS IT, AND WEIGHT IT AGAINST STANDARDS TO CALCULATE THE CORRECT MOISTURE NEEDED FOR DIFFERENT MOLDS. THE SAND MIX VARY WITH THE SIZE AND COMPOSITION OF THE CASTING. - Stockham Pipe & Fittings Company, Grey Iron Foundry, 4000 Tenth Avenue North, Birmingham, Jefferson County, AL
Dissolved organic matter effects on the performance of a barrier to polycyclic aromatic hydrocarbon transport by groundwater

NASA Astrophysics Data System (ADS)

Moon, Jung-Won; Goltz, Mark N.; Ahn, Kyu-Hong; Park, Jae-Woo

2003-02-01

In order to contain the movement of organic contaminants in groundwater, a subsurface sorption barrier consisting of sand or clay minerals coated with a cationic surfactant has been proposed. The effectiveness of such a sorption barrier might be affected by the presence of dissolved organic matter (DOM) in the groundwater. To study the impact of DOM on barrier performance, a series of batch experiments were performed by measuring naphthalene and phenanthrene sorption onto sand coated with cetylpyridinium chloride (CPC) and bentonite coated with hexadecyltrimethylammonium bromide (HDTMA) in the presence of various concentrations of DOM. The overall soil-water distribution coefficient ( K*) of naphthalene and phenanthrene onto CPC-coated sand decreased with increasing DOM concentration, whereas the K* of the compounds onto HDTMA-coated bentonite slightly increased with increasing DOM concentration. To describe the overall distribution of polycyclic aromatic hydrocarbons (PAHs) in the systems, a competitive multiphase sorption (CMS) model was developed and compared with an overall mechanistic sorption (OMS) model. The modeling studies showed that while the OMS model did not explain the CPC-coated sand experimental results, a model that included competitive sorption between DOM and PAH did. The experimental results and the modeling study indicated that there was no apparent competition between DOM and PAH in the HDTMA-coated bentonite system, and indicated that in groundwater systems with high DOM, a barrier using HDTMA-coated bentonite might be more effective.
Graphene Oxide Affects Mobility and Antibacterial Ability of Levofloxacin and Ciprofloxacin in Saturated and Unsaturated Porous Media

NASA Astrophysics Data System (ADS)

Kaixuan, S.

2017-12-01

Understand the fate and impact of fluoroquinolone antibiotics (FQs) in soil and groundwater systems is critical to the safety of ecosystem and public health. In this work, laboratory batch sorption, column transport, and bacterial growth experiments were conducted to improve current understanding of the interactions between two typical FQs (levofloxacin (LEV) and ciprofloxacin (CIP)) and graphene oxide (GO) in quartz sand media under various conditions. Studies showed that both GO and quartz sand adsorbed LEV and CIP in aqueous solutions and sand was capable to compete with GO for the antibiotics. While GO showed much larger sorption capacity, the sand had stronger sorption affinity to the two antibiotics. As a result, neither LEV nor CIP showed any signs of breakthrough in saturated or unsaturated porous media. When the two antibiotics were premixed with GO, their mobility in porous media increased for both saturate and unsaturated conditions and the amount of LEV or CIP in the effluents increased with the increasing of initial GO concentration. During their transport in saturated porous media, some of the GO-bound antibiotics, especially those sorbed via relatively weak interactions, transferred from GO to the quartz sand. Under unsaturated conditions, GO-bound LEV might also transfer from GO to the air-water interface due to the strong affiliation between LEV and air-water interface. Sorption onto GO reduced the antibacterial ability of LEV and CIP, however, the GO-bound antibiotics still effectively inhibited the growth of E coli. Findings from this work indicated that mobile GO affected not only the mobility but also the ecotoxicity of LEV and CIP in porous media.

The Influence of SAND’s Gradation and Clay Content of Direct Sheart Test on Clayey Sand

NASA Astrophysics Data System (ADS)

Wibisono, Gunawan; Agus Nugroho, Soewignjo; Umam, Khairul

2018-03-01

The shear strength of clayey-sand can be affected by several factors, e.g. gradation, density, moisture content, and the percentage of clay and sand fraction. The same percentage of clay and sand fraction in clayey-sand mixtures may have different shear strengths due to those factors. This research aims to study the effect of clay content on sand that cause the change of its shear strength. Samples consisted of different clay and sand fractions were reconstituted at a certain moisture content. Sand fractions varied from well-graded to poorly-graded sand. Shear strength was measured in terms of the direct shear test. Prior to the test, surcharge loads were applied to represent overburden pressures. Shear strength results and their components (i.e. Cohesion and internal angle of friction) were correlated with physical properties of samples (i.e. grading coefficient of curvature, coefficient of uniformity, and density). Results showed that samples classified as well-graded and dense sand had higher shear strength. In the other hand, the shear strengths decreased when the mixtures became poorly-graded and less dense. The inclusion of the clay fraction increased cohesion component and decreased internal angle of friction.
Scale-Up Method for the Shock Compaction of Powders

NASA Astrophysics Data System (ADS)

Carton, E. P.; Stuivinga, M.

2004-07-01

Shock wave compaction in the cylindrical configuration lends itself to be scaled-up for small-scale industrial applications. While scaling up in the axial direction is easy, scaling up in the lateral direction is less straightforward and may lead to cracks in the center. A different scale up method is presented here; aluminum tubes are filled with the powder to be compacted and placed in a circle inside a large metal tube, with a metal shock wave reflector in the center. The space in between is filled with an inert powder medium: alumina, salt or sand. It is found that salt is the best medium for the integrity of the aluminum tube and for the ease of removal of the aluminum tube out of the (densified) powder medium. Experimental results of (slightly ellipsoidal) shock compacted tubes that are produced this way are shown as an example. In the case of B4C, after infiltration with the aluminum of the tube, fully dense cermet compacts without any cracks are thus produced, batch by batch.
Silicon isotope amount ratios and molar masses for two silicon isotope reference materials: IRMM-018a and NBS28

NASA Astrophysics Data System (ADS)

Valkiers, S.; Ding, T.; Inkret, M.; Ruße, K.; Taylor, P.

2005-04-01

A new 2 kg batch of SiO2 crystals, IRMM-018a as well as the existing NBS28 silica sand (or RM 8546, obtained by I. Friedman from U.S. Geological Survey) have been characterised for their "absolute" silicon isotope composition and molar mass. The amount-of-substance measurements needed for that purpose were performed on the IRMM amount comparator (Avogadro II) on samples from these batches, which were converted to gaseous silicon tetra-fluoride (SiF4). The isotope amount ratio measurements were calibrated by means of synthesized isotope amount ratios realized in the form of synthetic Si isotope mixtures, the measurement procedure of which makes them SI-traceable. IRMM-018a is intended to be used as Isotope Reference Material for isotope amount measurements in geochemical and other isotope abundance studies of silicon. It is distributed in samples of about 0.1 mol and will replace IRMM-018 (exhausted).
Performance evaluation and modelling studies of gravel--coir fibre--sand multimedia stormwater filter.

PubMed

Samuel, Manoj P; Senthilvel, S; Tamilmani, D; Mathew, A C

2012-09-01

A horizontal flow multimedia stormwater filter was developed and tested for hydraulic efficiency and pollutant removal efficiency. Gravel, coconut (Cocos nucifera) fibre and sand were selected as the media and filled in 1:1:1 proportion. A fabric screen made up of woven sisal hemp was used to separate the media. The adsorption behaviour of coir fibre was determined in a series of column and batch studies and the corresponding isotherms were developed. The hydraulic efficiency of the filter showed a diminishing trend as the sediment level in inflow increased. The filter exhibited 100% sediment removal at lower sediment concentrations in inflow water (>6 g L(-1)). The filter could remove NO3(-), SO4(2-) and total solids (TS) effectively. Removal percentages of Mg(2+) and Na(+) were also found to be good. Similar results were obtained from a field evaluation study. Studies were also conducted to determine the pattern of silt and sediment deposition inside the filter body. The effects of residence time and rate of flow on removal percentages of NO3(-) and TS were also investigated out. In addition, a multiple regression equation that mathematically represents the filtration process was developed. Based on estimated annual costs and returns, all financial viability criteria (internal rate of return, net present value and benefit-cost ratio) were found favourable and affordable to farmers for investment in the developed filtration system. The model MUSIC was calibrated and validated for field conditions with respect to the developed stormwater filter.
Mass Transfer Behavior of Perfluorinated Chemicals in Saturated Clay-rich Sands: A Laboratory-based Study on Fate and Transport in Groundwater and Sediments

NASA Astrophysics Data System (ADS)

Greenberg, R. R.; Tick, G. R.; Abbott, J. B., III; Carroll, K. C.

2017-12-01

Perfluoroalkyl substances (PFAS) are a class of emerging contaminants that pose a threat to the human health and the quality of groundwater, surface water, and drinking water supplies. This study aims to elucidate the primary physicochemical factors controlling the fate and transport of the PFAS contaminants, perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), in groundwater. Physicochemical processes of intercalation, adsorption, and desorption were investigated for the retention of PFAS at different initial aqueous-phase concentrations in modified-natural sediments composed of sand (40/50 accusand; foc = 0.04% unmodified) with low, medium, and high organic carbon contents (foc = 10, 20, and 50%) and various pre-conditioned clay-fractions. Diffusional mass-transfer limitations were evaluated based on initial PFAS concentration, specific clay structure, and resulting contaminant intercalation (d-spacing changes). A series of short- (48 hr), medium- (7 day) and long-term (30 day) batch and column experiments were conducted to determine physicochemical processes as a function of compound chemistry, sediment geochemistry, sorbent crystalline structure, and contaminant/sediment contact-time. Physicochemical parameters, PFAS concentrations, and sediment characterization were conducted using high performance liquid chromatography (HPLC), X-ray diffraction (XRD), and furnace combustion analytical techniques. The results of PFAS contaminant transport, under the different conditions tested, provide a scientific contribution with application to the development of improved risk assessments, predictions of fate and transport, and more effective remediation strategies for emerging perfluorinated contaminants in soil and groundwater.
Study Gradation and Moisture Content of Sand Embankment on Peat Subjected Vibration Potential Liquefaction

NASA Astrophysics Data System (ADS)

Agus Nugroho, Soewignjo; Ika Putra, Agus; Yusa, Muhamad

2018-03-01

In recent years large earthquakes often occur on the island of Sumatra. There is a phenomenon of the damage occurred during the earthquake, one of the effects is a phenomenon of loss of soil strength due to vibration called liquefaction. Some cases of liquefaction occur in some areas in Aceh, Nias Island, Padang and Pariaman. Pekanbaru is located close to the fault area that causes the occurrence of earthquake wave propagation. Pekanbaru are also at risk for geotechnical problems because of earthquake such as liquefaction. Evaluation of liquefaction potential could using by in-situ test and by laboratory test. The laboratory test to evaluation liquefaction potential among which method of experiment shaking table. In this study, liquefaction phenomenon was conducted by creating a physical model of a laboratory scale using a one-way vibration machine, with a review of how big the influence of sand gradation, sand shaped and grain-size, and surface water level in the sand against liquefaction potential. Evaluate of liquefaction potential based on the surface reading of the soil movement, elapsed time for final settlement and an excess pore water dissipation (EPD) during testing. Based on the results of performed test, indicated that fine sand on fully saturated conditions have the potential of maximum settlement for 20.67% and maximum ascend of pore water for 46.67%. This result mean that poorly graded fine sand on fully saturated conditions has more liquefaction potential than medium sand, coarse sand, and well graded sand
40 CFR 205.57-2 - Test vehicle sample selection.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Test vehicle sample selection. 205.57... vehicle sample selection. (a) Vehicles comprising the batch sample which are required to be tested... test request from a batch of vehicles of the category or configuration specified in the test request...
Technetium, Iodine, and Chromium Adsorption/Desorption Kd Values for Vadose Zone Pore Water, ILAW Glass, and Cast Stone Leachates Contacting an IDF Sand Sequence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Last, George V.; Snyder, Michelle M.V.; Um, Wooyong

Performance and risk assessments of immobilized low-activity waste (ILAW) at the Integrated Disposal Facility (IDF) have shown that risks to groundwater are quite sensitive to adsorption-desorption interactions occurring in the near- and far-field environment. These interactions between the underlying sediments and the contaminants present in the leachates that descend from the buried glass, secondary waste grouts, and potentially Cast Stone low-activity waste packages have been represented in these assessments using the contaminant distribution coefficient (Kd) construct. Some contaminants (99Tc, 129I, and Cr) present in significant quantities in these wastes have low Kd values and tend to drive risk to publicmore » health and the environment. Relatively small changes in the Kd value can cause relatively large changes in the retardation factor. Thus, even relatively small uncertainty in the Kd value can result in a relatively large uncertainty in the risk determined through performance assessment modeling. The purpose of this study is to further reduce the uncertainty in Kd values for 99Tc, iodine (iodide and iodate), and Cr (chromate; CrO42-) by conducting systematic adsorption-desorption experiments using actual sand-dominated Hanford formation sediments from beneath the IDF and solutions that closely mimic Hanford vadose zone pore water and leachates from Cast Stone and ILAW glass waste forms. Twenty-four batch and 21 flow-through column experiments were conducted, yielding 261 Kd measurements for these key contaminants, and contributing to our understanding for predicting transport from wastes disposed to the IDF. While the batch Kd methodology is not well-suited for measuring Kd values for non-sorbing species (as noted by the U.S. Environmental Protection Agency), the batch Kd results presented here are not wholly inconsistent with the column Kd results, and could be used for sensitivity purposes. Results from the column experiments are consistent with the best estimate and lower range of Kd values reported by Krupka et al. and Cantrell et al.« less
Model development for naphthenic acids ozonation process.

PubMed

Al Jibouri, Ali Kamel H; Wu, Jiangning

2015-02-01

Naphthenic acids (NAs) are toxic constituents of oil sands process-affected water (OSPW) which is generated during the extraction of bitumen from oil sands. NAs consist mainly of carboxylic acids which are generally biorefractory. For the treatment of OSPW, ozonation is a very beneficial method. It can significantly reduce the concentration of NAs and it can also convert NAs from biorefractory to biodegradable. In this study, a factorial design (2(4)) was used for the ozonation of OSPW to study the influences of the operating parameters (ozone concentration, oxygen/ozone flow rate, pH, and mixing) on the removal of a model NAs in a semi-batch reactor. It was found that ozone concentration had the most significant effect on the NAs concentration compared to other parameters. An empirical model was developed to correlate the concentration of NAs with ozone concentration, oxygen/ozone flow rate, and pH. In addition, a theoretical analysis was conducted to gain the insight into the relationship between the removal of NAs and the operating parameters.
Surfactant enhanced recovery of tetrachloroethylene from a porous medium containing low permeability lenses. 2. Numerical simulation.

PubMed

Rathfelder, K M; Abriola, L M; Taylor, T P; Pennell, K D

2001-04-01

A numerical model of surfactant enhanced solubilization was developed and applied to the simulation of nonaqueous phase liquid recovery in two-dimensional heterogeneous laboratory sand tank systems. Model parameters were derived from independent, small-scale, batch and column experiments. These parameters included viscosity, density, solubilization capacity, surfactant sorption, interfacial tension, permeability, capillary retention functions, and interphase mass transfer correlations. Model predictive capability was assessed for the evaluation of the micellar solubilization of tetrachloroethylene (PCE) in the two-dimensional systems. Predicted effluent concentrations and mass recovery agreed reasonably well with measured values. Accurate prediction of enhanced solubilization behavior in the sand tanks was found to require the incorporation of pore-scale, system-dependent, interphase mass transfer limitations, including an explicit representation of specific interfacial contact area. Predicted effluent concentrations and mass recovery were also found to depend strongly upon the initial NAPL entrapment configuration. Numerical results collectively indicate that enhanced solubilization processes in heterogeneous, laboratory sand tank systems can be successfully simulated using independently measured soil parameters and column-measured mass transfer coefficients, provided that permeability and NAPL distributions are accurately known. This implies that the accuracy of model predictions at the field scale will be constrained by our ability to quantify soil heterogeneity and NAPL distribution.
Sorption and mobility of metronidazole, olaquindox, oxytetracycline and tylosin in soil.

PubMed

Rabølle, M; Spliid, N H

2000-04-01

Laboratory studies were conducted to characterise four different antibiotic compounds with regard to sorption and mobility in various soil types. Distribution coefficients (Kd values) determined by a batch equilibrium method varied between 0.5 and 0.7 for metronidazole, 0.7 and 1.7 for olaquindox and 8 and 128 for tylosin. Tylosin sorption seems to correlate positively with the soil clay content. No other significant interactions between soil characteristics and sorption were observed. Oxytetracycline was particularly strongly sorbed in all soils investigated, with Kd values between 417 in sand soil and 1026 in sandy loam, and no significant desorption was observed. Soil column leaching experiments indicated large differences in the mobility of the four antibiotic substances, corresponding to their respective sorption capabilities. For the weakly adsorbed substances metronidazole and olaquindox the total amounts added were recovered in the leachate of both sandy loam and sand soils. For the strongly adsorbed oxytetracyline and tylosin nothing was detected in the leachate of any of the soil types, indicating a much lower mobility. Results from defractionation and extraction of the columns (30 cm length) showed that 60-80% of the tylosin added had been leached to a depth of 5 cm in the sandy loam soil and 25 cm in the sand soil.
Experimental study of optimal self compacting concrete with spent foundry sand as partial replacement for M-sand using Taguchi approach

NASA Astrophysics Data System (ADS)

Nirmala, D. B.; Raviraj, S.

2016-06-01

This paper presents the application of Taguchi approach to obtain optimal mix proportion for Self Compacting Concrete (SCC) containing spent foundry sand and M-sand. Spent foundry sand is used as a partial replacement for M-sand. The SCC mix has seven control factors namely, Coarse aggregate, M-sand with Spent Foundry sand, Cement, Fly ash, Water, Super plasticizer and Viscosity modifying agent. Modified Nan Su method is used to proportion the initial SCC mix. L18 (21×37) Orthogonal Arrays (OA) with the seven control factors having 3 levels is used in Taguchi approach which resulted in 18 SCC mix proportions. All mixtures are extensively tested both in fresh and hardened states to verify whether they meet the practical and technical requirements of SCC. The quality characteristics considering "Nominal the better" situation is applied to the test results to arrive at the optimal SCC mix proportion. Test results indicate that the optimal mix satisfies the requirements of fresh and hardened properties of SCC. The study reveals the feasibility of using spent foundry sand as a partial replacement of M-sand in SCC and also that Taguchi method is a reliable tool to arrive at optimal mix proportion of SCC.
Geopressured-geothermal test of the EDNA Delcambre No. 1 well, Vermilion Parish, Louisiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wieland, D.R.; Meriwether, J.

1977-11-16

Two sand intervals, Sand No. 3 and Sand No. 1, were independently tested during our program. Sand No. 3 was the deepeer zone and was tested first. A gamma ray--neutron log of these zones, and the intervals perforated, are shown. The gamma ray log run in 1968 showed Sand No. 1 to be a fairly uniform section with few shale breaks and our original plans were to perforate the entire interval. After obtaining the more recent GR log big shale breaks were shown to exist throughout the zone, so a smaller interval was selected. A net sand thickness of 48more » ft. was used for Sand No. 3 and 30 ft. for Sand No. 1. There was no data available to indicate whether these zones became thicker or thinner away from the wellbore; therefore, these values were used as net thickness in the reservoir calculations. The procedure used to perforate the two sands were different. Both were perforated with 0.33 inch jets at a density of 4 shots per foot; however, Sand No. 3 was perforated in two runs using a stand-off gun, whereas Sand No. 1 was perforated in one run using a centralized gun with the jet density being 4 shots per foot but oriented alternately at 180 degrees.« less
Geochemical heterogeneity in a sand and gravel aquifer: Effect of sediment mineralogy and particle size on the sorption of chlorobenzenes

USGS Publications Warehouse

Barber, L.B.; Thurman, E.M.; Runnells, D.R.; ,

1992-01-01

The effect of particle size, mineralogy and sediment organic carbon (SOC) on solution of tetrachlorobenzene and pentachlorobenzene was evaluated using batch-isotherm experiments on sediment particle-size and mineralogical fractions from a sand and gravel aquifer, Cape Cod, Massachusetts. Concentration of SOC and sorption of chlorobenzenes increase with decreasing particle size. For a given particle size, the magnetic fraction has a higher SOC content and sorption capacity than the bulk or non-magnetic fractions. Sorption appears to be controlled by the magnetic minerals, which comprise only 5-25% of the bulk sediment. Although SOC content of the bulk sediment is < 0.1%, the observed sorption of chlorobenzenes is consistent with a partition mechanism and is adequately predicted by models relating sorption to the octanol/water partition coefficient of the solute and SOC content. A conceptual model based on preferential association of dissolved organic matter with positively-charged mineral surfaces is proposed to describe micro-scale, intergranular variability in sorption properties of the aquifer sediments.The effect of particle size, mineralogy and sediment organic carbon (SOC) on sorption of tetrachlorobenzene and pentachlorobenzene was evaluated using batch-isotherm experiments on sediment particle-size and mineralogical fractions from a sand and gravel aquifer, Cape Cod, Massachusetts. Concentration of SOC and sorption of chlorobenzenes increase with decreasing particle size. For a given particle size, the magnetic fraction has a higher SOC content and sorption capacity than the bulk or non-magnetic fractions. Sorption appears to be controlled by the magnetic minerals, which comprise only 5-25% of the bulk sediment. Although SOC content of the bulk sediment is <0.1%, the observed sorption of chlorobenzenes is consistent with a partition mechanism and is adequately predicted by models relating sorption to the octanol/water partition coefficient of the solute and SOC content. A conceptual model based on preferential association of dissolved organic matter with positively-charged mineral surfaces is proposed to describe micro-scale, intergranular variability in sorption properties of the aquifer sediments.
Heritable variation in seed sex ratio of the stinging nettle (Urtica dioica).

PubMed

de Jong, T J; Nell, H W; Glawe, G A

2005-03-01

Male and female flowering plants of the dioecious Urtica dioica occur in approximately equal numbers in our study area on the coastal sand dunes of Meijendel. The seed sex ratio (SSR, fraction of males) collected from female plants in the field varied between 0.05 and 0.76, and differed significantly between maternal parents. After one generation of selection for either high or low SSR, female plants produced seed batches with sex ratios as extreme as 0.08 and 0.73. Natural populations of U. dioica harbour considerable genetic variation in SSR.
System Vaccinology for the Evaluation of Influenza Vaccine Safety by Multiplex Gene Detection of Novel Biomarkers in a Preclinical Study and Batch Release Test

PubMed Central

Mizukami, Takuo; Momose, Haruka; Kuramitsu, Madoka; Takizawa, Kazuya; Araki, Kumiko; Furuhata, Keiko; Ishii, Ken J.; Hamaguchi, Isao; Yamaguchi, Kazunari

2014-01-01

Vaccines are beneficial and universal tools to prevent infectious disease. Thus, safety of vaccines is strictly evaluated in the preclinical phase of trials and every vaccine batch must be tested by the National Control Laboratories according to the guidelines published by each country. Despite many vaccine production platforms and methods, animal testing for safety evaluation is unchanged thus far. We recently developed a systems biological approach to vaccine safety evaluation where identification of specific biomarkers in a rat pre-clinical study evaluated the safety of vaccines for pandemic H5N1 influenza including Irf7, Lgals9, Lgalsbp3, Cxcl11, Timp1, Tap2, Psmb9, Psme1, Tapbp, C2, Csf1, Mx2, Zbp1, Ifrd1, Trafd1, Cxcl9, β2m, Npc1, Ngfr and Ifi47. The current study evaluated whether these 20 biomarkers could evaluate the safety, batch-to-batch and manufacturer-to-manufacturer consistency of seasonal trivalent influenza vaccine using a multiplex gene detection system. When we evaluated the influenza HA vaccine (HAv) from four different manufactures, the biomarker analysis correlated to findings from conventional animal use tests, such as abnormal toxicity test. In addition, sensitivity of toxicity detection and differences in HAvs were higher and more accurate than with conventional methods. Despite a slight decrease in body weight caused by HAv from manufacturer B that was not statistically significant, our results suggest that HAv from manufacturer B is significantly different than the other HAvs tested with regard to Lgals3bp, Tapbp, Lgals9, Irf7 and C2 gene expression in rat lungs. Using the biomarkers confirmed in this study, we predicted batch-to-batch consistency and safety of influenza vaccines within 2 days compared with the conventional safety test, which takes longer. These biomarkers will facilitate the future development of new influenza vaccines and provide an opportunity to develop in vitro methods of evaluating batch-to-batch consistency and vaccine safety as an alternative to animal testing. PMID:25010690
Identifying the causes of oil sands coke leachate toxicity to aquatic invertebrates.

PubMed

Puttaswamy, Naveen; Liber, Karsten

2011-11-01

A previous study found that coke leachates (CL) collected from oil sands field sites were acutely toxic to Ceriodaphnia dubia; however, the cause of toxicity was not known. Therefore, the purpose of this study was to generate CL in the laboratory to evaluate the toxicity response of C. dubia and perform chronic toxicity identification evaluation (TIE) tests to identify the causes of CL toxicity. Coke was subjected to a 15-d batch leaching process at pH 5.5 and 9.5. Leachates were filtered on day 15 and used for chemical and toxicological characterization. The 7-d median lethal concentration (LC50) was 6.3 and 28.7% (v/v) for pH 5.5 and 9.5 CLs, respectively. Trace element characterization of the CLs showed Ni and V levels to be well above their respective 7-d LC50s for C. dubia. Addition of ethylenediaminetetraacetic acid significantly (p ≤ 0.05) improved survival and reproduction in pH 5.5 CL, but not in pH 9.5 CL. Cationic and anionic resins removed toxicity of pH 5.5 CL only. Conversely, the toxicity of pH 9.5 CL was completely removed with an anion resin alone, suggesting that the pH 9.5 CL contained metals that formed oxyanions. Toxicity reappeared when Ni and V were added back to anion resin-treated CLs. The TIE results combined with the trace element chemistry suggest that both Ni and V are the cause of toxicity in pH 5.5 CL, whereas V appears to be the primary cause of toxicity in pH 9.5 CL. Environmental monitoring and risk assessments should therefore focus on the fate and toxicity of metals, especially Ni and V, in coke-amended oil sands reclamation landscapes. Copyright © 2011 SETAC.
White Sands Missile Range Overview & Introduction: Test Capabilities Briefing

DTIC Science & Technology

2011-11-07

PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Army Test and Evaluation Command (ATEC),White Sands Missile Range,White Sands Missile Range,NM,88002...5000 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR’S ACRONYM(S) 11. SPONSOR...solar radiation, icing, salt fog, etc. • Instrumented for system performance / diagnostics  Climatics testing capabilities • Fixed and mobile test
Risk factors for faecal sand excretion in Icelandic horses.

PubMed

Husted, L; Andersen, M S; Borggaard, O K; Houe, H; Olsen, S N

2005-07-01

Sandy soil is often mentioned as a risk factor in the development of sand-related gastrointestinal disease (SGID) in the horse. There are other variables, but few studies confirm any of these. To investigate soil type, pasture quality, feeding practice in the paddock, age, sex and body condition score as risk factors for sand intake in the horse. Faeces were collected from 211 Icelandic horses on 19 different studs in Denmark together with soil samples and other potential risk factors. Sand content in faeces determined by a sand sedimentation test was interpreted as evidence of sand intake. Soil types were identified by soil analysis and significance of the data was tested using logistic analysis. Of horses included in the study, 56.4% showed sand in the faeces and 5.7% had more than 5 mm sand as quantified by the rectal sleeve sedimentation test. Soil type had no significant effect when tested as main effect, but there was interaction between soil type and pasture quality. Significant interactions were also found between paddock feeding practice and pasture quality. To evaluate the risk of sand intake it is important to consider 3 variables: soil type, pasture quality and feeding practice. Pasture quality was identified as a risk factor of both short and long grass in combination with sandy soil, while clay soil had the lowest risk in these combinations. Feeding practice in the paddock revealed feeding directly on the ground to be a risk factor when there was short (1-5 cm) or no grass. Also, no feeding outdoors increased the risk on pastures with short grass, while this had no effect in paddocks with no grass. More than 50% of all horses investigated in this study had sand in the faeces. The identification of risk factors is an important step towards prevention of SGID. Further research is necessary to determine why some horses exhibit more than 5 mm sand in the sedimentation test and whether this is correlated with geophagic behaviour.
Overview of NASA White Sands Test Facility Composite Overwrapped Pressure Vessel Testing

NASA Technical Reports Server (NTRS)

Greene, Nathanael; Saulsberry, Regor; Thesken, John; Phoenix, Leigh

2006-01-01

This viewgraph presentation examines the White Sands Test Facility testing of Composite overwrapped pressure vessel (COPV). A COPV is typically a metallic liner overwrapped with a fiber epoxy matrix. There is a weight advantage over the traditional all metal design. The presentation shows pictures of the facilities at White Sands, and then examines some of the testing performed. The tests include fluids compatibility, and Kevlar COPV. Data for the Kevlar tests are given, and an analysis is reviewed. There is also a comparison between Carbon COPVs and the Kevlar COPVs.

The relationship between pH and concentrations of antioxidants and vasoconstrictors in local anesthetic solutions.

PubMed

Hondrum, S O; Ezell, J H

1996-01-01

pH affects the efficacy of local anesthetics by determining the percentage of the lipid-soluble base form of the anesthetic available for diffusion and penetration of the nerve sheath. The purpose of this study was to determine the relationship between pH and the concentrations of antioxidant and vasoconstrictor in dental local anesthetic solutions over real-time and after accelerated aging. Several batches of lidocaine and mepivacaine with vasoconstrictors were tested. Results showed that, immediately upon receipt from the manufacturers, three batches were below the USP pH limit (pH 3.3), and two batches contained less than the minimum limit of vasoconstrictors (90%). Real-time tests on batches that were within normal limits revealed that solutions were stable past 4 yr. Accelerated aging tests revealed a strong correlation between a decrease in pH and loss of antioxidants and vasoconstrictors. In conclusion, a quality batch of local anesthetic should remain efficacious long past the manufacturer's stated shelf life; a batch that is less than optimal, or one that is exposed to environmental stresses, will degrade rapidly, and efficacy may be affected by decreases in pH and loss of vasoconstrictor. pH may be an inexpensive, readily available screening test for efficacy of local anesthetics.
The relationship between pH and concentrations of antioxidants and vasoconstrictors in local anesthetic solutions.

PubMed Central

Hondrum, S. O.; Ezell, J. H.

1996-01-01

pH affects the efficacy of local anesthetics by determining the percentage of the lipid-soluble base form of the anesthetic available for diffusion and penetration of the nerve sheath. The purpose of this study was to determine the relationship between pH and the concentrations of antioxidant and vasoconstrictor in dental local anesthetic solutions over real-time and after accelerated aging. Several batches of lidocaine and mepivacaine with vasoconstrictors were tested. Results showed that, immediately upon receipt from the manufacturers, three batches were below the USP pH limit (pH 3.3), and two batches contained less than the minimum limit of vasoconstrictors (90%). Real-time tests on batches that were within normal limits revealed that solutions were stable past 4 yr. Accelerated aging tests revealed a strong correlation between a decrease in pH and loss of antioxidants and vasoconstrictors. In conclusion, a quality batch of local anesthetic should remain efficacious long past the manufacturer's stated shelf life; a batch that is less than optimal, or one that is exposed to environmental stresses, will degrade rapidly, and efficacy may be affected by decreases in pH and loss of vasoconstrictor. pH may be an inexpensive, readily available screening test for efficacy of local anesthetics. PMID:10323112
Disturbance of the inclined inserting-type sand fence to wind-sand flow fields and its sand control characteristics

NASA Astrophysics Data System (ADS)

Cheng, Jian-jun; Lei, Jia-qiang; Li, Sheng-yu; Wang, Hai-feng

2016-06-01

The inclined inserting-type sand fence is a novel sand retaining wall adopted along the Lanxin High-Speed Railway II in Xinjiang for controlling and blocking sand movement. To verify the effectiveness of the new fence structure for sand prevention, a wind tunnel test was used for flow field test simulation of the sand fence. The results indicate that the inclined inserting-type sand fence was able to deflect the flow of the sand and was able to easily form an upward slant acceleration zone on the leeward side of the sand fence. As shown by the percentage change in sand collection rates on the windward side and the leeward side of the sand fence, the sand flux per unit area at 4 m height in the slant upward direction increased on the leeward side of the inclined inserting-type sand fence. By comparing the flow fields, this site is an acceleration zone, which also reaffirms the correspondence of wind-sand flow fields with the spatial distribution characteristic of the wind-carried sand motion. The field sand collection data indicates that under the effects of the inclined inserting-type sand fence, the sandy air currents passing in front and behind the sand fence not only changed in quality, but the grain composition and particle size also significantly changed, suggesting that the inclined inserting-type sand fence has a sorting and filtering effect on the sandy air currents that passed through. The fence retained coarse particulates on the windward side and fine particulates within the shade of the wind on the leeward side.
[Batch release of immunoglobulin and monoclonal antibody products].

PubMed

Gross, S

2014-10-01

The Paul-Ehrlich Institute (PEI) is an independent institution of the Federal Republic of Germany responsible for performing official experimental batch testing of sera. The institute decides about the release of each batch and performs experimental research in the field. The experimental quality control ensures the potency of the product and also the absence of harmful impurities. For release of an immunoglobulin batch the marketing authorization holder has to submit the documentation of the manufacture and the results of quality control measures together with samples of the batch to the PEI. Experimental testing is performed according to the approved specifications regarding the efficacy and safety. Since implementation of the 15th German drug law amendment, the source of antibody is not defined anymore. According to § 32 German drug law, all batches of sera need to be released by an official control laboratory. Sera are medicinal products, which contain antibodies, antibody fragments or fusion proteins with a functional antibody portion. Therefore, all batches of monoclonal antibodies and derivatives must also be released by the PEI and the marketing authorization holder has to submit a batch release application. Under certain circumstances a waiver for certain products can be issued with regard to batch release. The conditions for such a waiver apply to the majority of monoclonal antibodies.
Between-Batch Pharmacokinetic Variability Inflates Type I Error Rate in Conventional Bioequivalence Trials: A Randomized Advair Diskus Clinical Trial.

PubMed

Burmeister Getz, E; Carroll, K J; Mielke, J; Benet, L Z; Jones, B

2017-03-01

We previously demonstrated pharmacokinetic differences among manufacturing batches of a US Food and Drug Administration (FDA)-approved dry powder inhalation product (Advair Diskus 100/50) large enough to establish between-batch bio-inequivalence. Here, we provide independent confirmation of pharmacokinetic bio-inequivalence among Advair Diskus 100/50 batches, and quantify residual and between-batch variance component magnitudes. These variance estimates are used to consider the type I error rate of the FDA's current two-way crossover design recommendation. When between-batch pharmacokinetic variability is substantial, the conventional two-way crossover design cannot accomplish the objectives of FDA's statistical bioequivalence test (i.e., cannot accurately estimate the test/reference ratio and associated confidence interval). The two-way crossover, which ignores between-batch pharmacokinetic variability, yields an artificially narrow confidence interval on the product comparison. The unavoidable consequence is type I error rate inflation, to ∼25%, when between-batch pharmacokinetic variability is nonzero. This risk of a false bioequivalence conclusion is substantially higher than asserted by regulators as acceptable consumer risk (5%). © 2016 The Authors Clinical Pharmacology & Therapeutics published by Wiley Periodicals, Inc. on behalf of The American Society for Clinical Pharmacology and Therapeutics.
Batch statistical process control of a fluid bed granulation process using in-line spatial filter velocimetry and product temperature measurements.

PubMed

Burggraeve, A; Van den Kerkhof, T; Hellings, M; Remon, J P; Vervaet, C; De Beer, T

2011-04-18

Fluid bed granulation is a batch process, which is characterized by the processing of raw materials for a predefined period of time, consisting of a fixed spraying phase and a subsequent drying period. The present study shows the multivariate statistical modeling and control of a fluid bed granulation process based on in-line particle size distribution (PSD) measurements (using spatial filter velocimetry) combined with continuous product temperature registration using a partial least squares (PLS) approach. Via the continuous in-line monitoring of the PSD and product temperature during granulation of various reference batches, a statistical batch model was developed allowing the real-time evaluation and acceptance or rejection of future batches. Continuously monitored PSD and product temperature process data of 10 reference batches (X-data) were used to develop a reference batch PLS model, regressing the X-data versus the batch process time (Y-data). Two PLS components captured 98.8% of the variation in the X-data block. Score control charts in which the average batch trajectory and upper and lower control limits are displayed were developed. Next, these control charts were used to monitor 4 new test batches in real-time and to immediately detect any deviations from the expected batch trajectory. By real-time evaluation of new batches using the developed control charts and by computation of contribution plots of deviating process behavior at a certain time point, batch losses or reprocessing can be prevented. Immediately after batch completion, all PSD and product temperature information (i.e., a batch progress fingerprint) was used to estimate some granule properties (density and flowability) at an early stage, which can improve batch release time. Individual PLS models relating the computed scores (X) of the reference PLS model (based on the 10 reference batches) and the density, respectively, flowabililty as Y-matrix, were developed. The scores of the 4 test batches were used to examine the predictive ability of the model. Copyright © 2011 Elsevier B.V. All rights reserved.
Laboratory test on maximum and minimum void ratio of tropical sand matrix soils

NASA Astrophysics Data System (ADS)

Othman, B. A.; Marto, A.

2018-04-01

Sand is generally known as loose granular material which has a grain size finer than gravel and coarser than silt and can be very angular to well-rounded in shape. The present of various amount of fines which also influence the loosest and densest state of sand in natural condition have been well known to contribute to the deformation and loss of shear strength of soil. This paper presents the effect of various range of fines content on minimum void ratio e min and maximum void ratio e max of sand matrix soils. Laboratory tests to determine e min and e max of sand matrix soil were conducted using non-standard method introduced by previous researcher. Clean sand was obtained from natural mining site at Johor, Malaysia. A set of 3 different sizes of sand (fine sand, medium sand, and coarse sand) were mixed with 0% to 40% by weight of low plasticity fine (kaolin). Results showed that generally e min and e max decreased with the increase of fines content up to a minimal value of 0% to 30%, and then increased back thereafter.
Acceptance Test Data for Candidate AGR-5/6/7 TRISO Particle Batches BWXT Coater Batches 93165 93172 Defective IPyC Fraction and Pyrocarbon Anisotropy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Helmreich, Grant W.; Hunn, John D.; Skitt, Darren J.

2017-03-01

Coated particle fuel batches J52O-16-93165, 93166, 93168, 93169, 93170, and 93172 were produced by Babcock and Wilcox Technologies (BWXT) for possible selection as fuel for the Advanced Gas Reactor Fuel Development and Qualification (AGR) Program’s AGR-5/6/7 irradiation test in the Idaho National Laboratory (INL) Advanced Test Reactor (ATR). Some of these batches may alternately be used as demonstration coated particle fuel for other experiments. Each batch was coated in a 150-mm-diameter production-scale fluidized-bed chemical vapor deposition (CVD) furnace. Tristructural isotropic (TRISO) coatings were deposited on 425-μm-nominal-diameter spherical kernels from BWXT lot J52R-16-69317 containing a mixture of 15.5%-enriched uranium carbide andmore » uranium oxide (UCO). The TRISO coatings consisted of four consecutive CVD layers: a ~50% dense carbon buffer layer with 100-μm-nominal thickness, a dense inner pyrolytic carbon (IPyC) layer with 40-μm-nominal thickness, a silicon carbide (SiC) layer with 35-μm-nominal thickness, and a dense outer pyrolytic carbon (OPyC) layer with 40-μmnominal thickness. The TRISO-coated particle batches were sieved to upgrade the particles by removing over-sized and under-sized material, and the upgraded batches were designated by appending the letter A to the end of the batch number (e.g., 93165A).« less
Coupled Geochemical Impacts of Leaking CO2 and Contaminants from Subsurface Storage Reservoirs on Groundwater Quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shao, Hongbo; Qafoku, Nikolla; Lawter, Amanda R.

2015-07-07

The leakage of CO2 and the concomitant saline solutions from deep storage reservoirs to overlying groundwater aquifers is considered one of the major potential risks associated with geologic CO2 sequestration (GCS). Batch and column experiments were conducted to determine the fate of trace metals in groundwater in the scenarios of CO2 and metal contaminated brine leakage. The sediments used in this work were collected from an unconsolidated sand and gravel aquifer in Kansas, and contained 0-4 wt% carbonates. Cd and As were spiked into the reaction system to represent potential contaminants from the reservoir brine that could intrude into groundwatermore » aquifers with leaking CO2 at initial concentrations of 114 and 40 ppb, respectively. Through this research we demonstrated that Cd and As were adsorbed on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. Cd concentrations were well below its MCL in both batch and column studies, even for sediment samples without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent were also significantly lower than influent concentration, suggesting that the sediments tested have the capacity to mitigate the coupled adverse effects of CO2 leakage and brine intrusion. However, the mitigation capacity of sediment is a function of its geochemical properties [e.g., the calcite content; the presence of adsorbed As(III); and the presence of P in the natural sediment]. The competitive adsorption between phosphate and arsenate may result in higher concentrations of As in the aqueous phase.« less
Faecal indicator bacteria enumeration in beach sand: a comparison study of extraction methods in medium to coarse sands.

PubMed

Boehm, A B; Griffith, J; McGee, C; Edge, T A; Solo-Gabriele, H M; Whitman, R; Cao, Y; Getrich, M; Jay, J A; Ferguson, D; Goodwin, K D; Lee, C M; Madison, M; Weisberg, S B

2009-11-01

The absence of standardized methods for quantifying faecal indicator bacteria (FIB) in sand hinders comparison of results across studies. The purpose of the study was to compare methods for extraction of faecal bacteria from sands and recommend a standardized extraction technique. Twenty-two methods of extracting enterococci and Escherichia coli from sand were evaluated, including multiple permutations of hand shaking, mechanical shaking, blending, sonication, number of rinses, settling time, eluant-to-sand ratio, eluant composition, prefiltration and type of decantation. Tests were performed on sands from California, Florida and Lake Michigan. Most extraction parameters did not significantly affect bacterial enumeration. anova revealed significant effects of eluant composition and blending; with both sodium metaphosphate buffer and blending producing reduced counts. The simplest extraction method that produced the highest FIB recoveries consisted of 2 min of hand shaking in phosphate-buffered saline or deionized water, a 30-s settling time, one-rinse step and a 10 : 1 eluant volume to sand weight ratio. This result was consistent across the sand compositions tested in this study but could vary for other sand types. Method standardization will improve the understanding of how sands affect surface water quality.
38. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF TEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

38. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF TEST BAY AND EXHAUST PIT, LOOKING WEST - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
37. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF TEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

37. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF TEST BAY AND EXHAUST PIT, LOOKING SOUTHWEST - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Effects of sand and straw bedding on the lying behavior, cleanliness, and hoof and hock injuries of dairy cows.

PubMed

Norring, M; Manninen, E; de Passillé, A M; Rushen, J; Munksgaard, L; Saloniemi, H

2008-02-01

This experiment compared the effects of sand and straw bedding in free stalls on resting time, cleanliness, hock injuries, and hoof health of dairy cows and tested whether cow preferences for a bedding material depended on the familiarity with the material. A total of 52 dairy cows were kept either on straw bedded concrete stalls or sand stalls for at least 21 wk. The lying behavior was observed, and hock lesions, hoof health, and cleanliness of the cows and stalls were measured. A 5-d preference test between sand and straw stalls was conducted at the end of the experiment. The total daily duration of lying was longer for cows on straw bedding than on sand bedding (straw 749 +/- 16 vs. sand 678 +/- 19 min). During the preference test, cows that had been kept on straw bedding preferred lying in straw stalls [straw 218.7 (133.4 to 239.7) vs. sand 9.0 min (2.8 to 44.8)]; however, cows that had been kept on sand showed no preference [straw 101.3 (51.7 to 205.9) vs. sand 94.3 min (54.1 to 156.1, median and interquartile range)]. Although there were no differences in the dirtiness of stalls, the cows using straw stalls were dirtier than cows using sand stalls [straw 6.04 (5.39 to 6.28) vs. sand 4.19 (3.62 to 5.16)]. At the end of experiment the severity of hock lesions was lower for cows on sand than for cows on straw [sand 0.5 (0.0 to 1.0) vs. straw 1.0 (1.0 to 2.0)]. The improvement in overall hoof health over the observation period was greater for cows kept on sand compared with cows kept on straw [sand -2.00 (-3.75 to -0.25) vs. straw 0.00 (-2.00 to 2.00)]. Straw bedding increased the time that cows spend lying, and cows preferred straw stalls to sand stalls. However, previous experience with sand reduces avoidance of sand stalls. Sand stalls were advantageous for cow cleanliness and health; hock lesions and claw diseases healed more quickly for cows using sand stalls compared with straw.
White Sands, Carrizozo Lava Beds, NM

NASA Technical Reports Server (NTRS)

1973-01-01

A truly remarkable view of White Sands and the nearby Carrizozo Lava Beds in southeast NM (33.5N, 106.5W). White Sands, site of the WW II atomic bomb development and testing facility and later post war nuclear weapons testing that can still be seen in the cleared circular patterns on the ground.
Load capacity, failure mode and design criteria investigation of sand jacks : full scale load testing of sand jacks.

DOT National Transportation Integrated Search

2008-12-01

A sand-jack is a sand filled container used as a component of cast-in-place bridge false-work. The sand filler facilitates the removal of the false-work by allowing slow and controlled lowering of the bracing that has become wedged beneath the new br...
A new statistic for identifying batch effects in high-throughput genomic data that uses guided principal component analysis.

PubMed

Reese, Sarah E; Archer, Kellie J; Therneau, Terry M; Atkinson, Elizabeth J; Vachon, Celine M; de Andrade, Mariza; Kocher, Jean-Pierre A; Eckel-Passow, Jeanette E

2013-11-15

Batch effects are due to probe-specific systematic variation between groups of samples (batches) resulting from experimental features that are not of biological interest. Principal component analysis (PCA) is commonly used as a visual tool to determine whether batch effects exist after applying a global normalization method. However, PCA yields linear combinations of the variables that contribute maximum variance and thus will not necessarily detect batch effects if they are not the largest source of variability in the data. We present an extension of PCA to quantify the existence of batch effects, called guided PCA (gPCA). We describe a test statistic that uses gPCA to test whether a batch effect exists. We apply our proposed test statistic derived using gPCA to simulated data and to two copy number variation case studies: the first study consisted of 614 samples from a breast cancer family study using Illumina Human 660 bead-chip arrays, whereas the second case study consisted of 703 samples from a family blood pressure study that used Affymetrix SNP Array 6.0. We demonstrate that our statistic has good statistical properties and is able to identify significant batch effects in two copy number variation case studies. We developed a new statistic that uses gPCA to identify whether batch effects exist in high-throughput genomic data. Although our examples pertain to copy number data, gPCA is general and can be used on other data types as well. The gPCA R package (Available via CRAN) provides functionality and data to perform the methods in this article. reesese@vcu.edu
White Sands, Carrizozo Lava Beds, NM

NASA Image and Video Library

1982-03-30

STS003-10-613 (22-30 March 1982) --- A truly remarkable view of White Sands and the nearby Carrizozo Lava Beds in southeast NM (33.5N, 106.5W). White Sands, site of the WW II atomic bomb development and testing facility and later post war nuclear weapons testing that can still be seen in the cleared circular patterns on the ground. Space shuttle Columbia (STS-3), this mission, landed at the White Sands alternate landing site because of bad weather at Edwards AFB, CA. Photo credit: NASA
A Preliminary Design of a Calibration Chamber for Evaluating the Stability of Unsaturated Soil Slope

NASA Astrophysics Data System (ADS)

Hsu, H.-H.

2012-04-01

The unsaturated soil slopes, which have ground water tables and are easily failure caused by heavy rainfalls, are widely distributed in the arid and semi-arid areas. For analyzing the stability of slope, in situ tests are the direct methods to obtain the test site characteristics. The cone penetration test (CPT) is a popular in situ test method. Some of the CPT empirical equations established from calibration chamber tests. The CPT performed in calibration chamber was commonly used clean quartz sand as testing material in the past. The silty sand is observed in many actual slopes. Because silty sand is relatively compressible than quartz sand, it is not suitable to apply the correlations between soil properties and CPT results built from quartz sand to silty sand. The experience on CPT calibration in silty sand has been limited. CPT calibration tests were mostly performed in dry or saturated soils. The condition around cone tip during penetration is assumed to be fully drained or fully undrained, yet it was observed to be partially drained for unsaturated soils. Because of the suction matrix has a great effect on the characteristics of unsaturated soils, they are much sensitive to the water content than saturated soils. The design of an unsaturated calibration chamber is in progress. The air pressure is supplied from the top plate and the pore water pressure is provided through the high air entry value ceramic disks located at the bottom plate of chamber cell. To boost and uniform distribute the unsaturated effect, four perforated burettes are installed onto the ceramic disks and stretch upwards to the midheight of specimen. This paper describes design concepts, illustrates this unsaturated calibration chamber, and presents the preliminary test results.
Sorption kinetics of TNT and RDX in anaerobic freshwater and marine sediments: Batch studies.

PubMed

Ariyarathna, Thivanka; Vlahos, Penny; Tobias, Craig; Smith, Richard

2016-01-01

Examination of the partitioning of explosives onto sediment in marine environments is critical to predict the toxicological impacts of worldwide explosive-contaminated sites adjacent to estuaries, wetlands, and the coastal ocean. Marine sediments have been identified as sites of enhanced munitions removal, yet most studies addressing these interactions focus on soils and freshwater sediments. The present study measured the kinetics of 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) sorption onto 2 marine sediments of varying grain sizes (silt vs sand) and organic carbon (OC) content. Abiotic sediment sorption tests were performed at 23 °C, 15 °C, and 4 °C by spiking TNT and RDX solutions directly into anaerobic sediment slurries. Marine sediments showed significantly higher compound uptake rates (0.30-0.80 h(-1) ) than freshwater silt (0.0046-0.0065 h(-1) ) for both compounds, probably because of lower compound solubilities and a higher pH in marine systems. Equilibrium partition constants are on the same order of magnitude for marine silt (1.1-2.0 L kg(-1) sediment) and freshwater silt (1.4-3.1 L kg(-1) sediment) but lower for marine sand (0.72-0.92 L kg(-1) sediment). Total organic carbon content in marine sediments varied linearly with equilibrium partition constants for TNT and was moderately linear for RDX. Uptake rates and equilibrium constants of explosives are inversely correlated to temperature regardless of sediment type because of kinetic barriers associated with low temperatures. © 2015 SETAC.
Full scale load testing of sand-jacks.

DOT National Transportation Integrated Search

2006-06-01

A sand-jack is a sand filled container used as a component of cast-in-place bridge false-work. The sand filler facilitates the removal of the false-work by allowing slow and controlled lowering of the bracing that has become wedged beneath the new br...

Monochloramine Cometabolism by Mixed-Culture Nitrifiers ...

EPA Pesticide Factsheets

The current research investigated monochloramine cometabolism by nitrifying mixed cultures grown under drinking water relevant conditions and harvested from sand-packed reactors before conducting suspended growth batch kinetic experiments. Three batch reactors were used in each experiment: (1) a positive control to estimate ammonia kinetic parameters, (2) a negative control to account for abiotic reactions, and (3) a cometabolism reactor to estimate cometabolism kinetic constants. Kinetic parameters were estimated in AQUASIM with a simultaneous fit to all experimental data. Cometabolism kinetics were best described by a first order model. Monochloramine cometabolism kinetics were similar to those of ammonia metabolism, and monochloramine cometabolism was a significant loss mechanism (30% of the observed monochloramine loss). These results demonstrated that monochloramine cometabolism occurred in mixed cultures similar to those found in drinking water distribution systems; thus, cometabolism may be a significant contribution to monochloramine loss during nitrification episodes in drinking water distribution systems. The results demonstrated that monochloramine cometabolism occurred in mixed cultures similar to those found in drinking water distribution systems; thus, cometabolism may be a significant contribution to monochloramine loss during nitrification episodes in drinking water distribution systems.
"RCL-Pooling Assay": A Simplified Method for the Detection of Replication-Competent Lentiviruses in Vector Batches Using Sequential Pooling.

PubMed

Corre, Guillaume; Dessainte, Michel; Marteau, Jean-Brice; Dalle, Bruno; Fenard, David; Galy, Anne

2016-02-01

Nonreplicative recombinant HIV-1-derived lentiviral vectors (LV) are increasingly used in gene therapy of various genetic diseases, infectious diseases, and cancer. Before they are used in humans, preparations of LV must undergo extensive quality control testing. In particular, testing of LV must demonstrate the absence of replication-competent lentiviruses (RCL) with suitable methods, on representative fractions of vector batches. Current methods based on cell culture are challenging because high titers of vector batches translate into high volumes of cell culture to be tested in RCL assays. As vector batch size and titers are continuously increasing because of the improvement of production and purification methods, it became necessary for us to modify the current RCL assay based on the detection of p24 in cultures of indicator cells. Here, we propose a practical optimization of this method using a pairwise pooling strategy enabling easier testing of higher vector inoculum volumes. These modifications significantly decrease material handling and operator time, leading to a cost-effective method, while maintaining optimal sensibility of the RCL testing. This optimized "RCL-pooling assay" ameliorates the feasibility of the quality control of large-scale batches of clinical-grade LV while maintaining the same sensitivity.
Leaching Behavior Of Mineral Processing Waste: Comparison Of Batch And Column Investigations

EPA Science Inventory

In this study, a comparison of laboratory batch and column experiments on metal release profile from a mineral processing waste (MPW) is presented. Batch (equilibrium) and column (dynamic) leaching tests were conducted on ground MPW at different liquid–solid ratios (LS) to determ...
Transport and retention of nanoscale C60 aggregates in water-saturated porous media.

PubMed

Wang, Yonggang; Li, Yusong; Fortner, John D; Hughes, Joseph B; Abriola, Linda M; Pennell, Kurt D

2008-05-15

Experimental and mathematical modeling studies were performed to investigate the transport and retention of nanoscale fullerene aggregates (nC60) in water-saturated porous media. Aqueous suspensions of nC60 aggregates (95 nm diameter, 1 to 3 mg/L) were introduced into columns packed with either glass beads or Ottawa sand at a Darcy velocity of 2.8 m/d. In the presence of 1.0 mM CaCl2, nC60 effluent breakthrough curves (BTCs) gradually increased to a maximum value and then declined sharply upon reintroduction of nC60-free solution. Retention of nC60 in glass bead columns ranged from 8 to 49% of the introduced mass, while up to 77% of the mass was retained in Ottawa sand columns. When nC60 suspensions were prepared in deionized water alone, effluent nC60 BTCs coincided with those of a nonreactive tracer (Br-), with minimal nC60 retention. Observed differences in nC60 transport and retention behavior in glass beads and Ottawa sand were consistent with independent batch retention data and theoretical calculations of electrostatic interactions between nC60 and the solid surfaces. Effluent concentration and retention profile data were accurately simulated using a numerical model that accounted for nC60 attachment kinetics and a limiting retention capacity.
Determination of thermodynamic and transport parameters of naphthenic acids and organic process chemicals in oil sand tailings pond water.

PubMed

Wang, Xiaomeng; Robinson, Lisa; Wen, Qing; Kasperski, Kim L

2013-07-01

Oil sand tailings pond water contains naphthenic acids and process chemicals (e.g., alkyl sulphates, quaternary ammonium compounds, and alkylphenol ethoxylates). These chemicals are toxic and can seep through the foundation of the tailings pond to the subsurface, potentially affecting the quality of groundwater. As a result, it is important to measure the thermodynamic and transport parameters of these chemicals in order to study the transport behavior of contaminants through the foundation as well as underground. In this study, batch adsorption studies and column experiments were performed. It was found that the transport parameters of these chemicals are related to their molecular structures and other properties. The computer program (CXTFIT) was used to further evaluate the transport process in the column experiments. The results from this study show that the transport of naphthenic acids in a glass column is an equilibrium process while the transport of process chemicals seems to be a non-equilibrium process. At the end of this paper we present a real-world case study in which the transport of the contaminants through the foundation of an external tailings pond is calculated using the lab-measured data. The results show that long-term groundwater monitoring of contaminant transport at the oil sand mining site may be necessary to avoid chemicals from reaching any nearby receptors.
A Thermal Stability Test for Primary Explosive Stab Sensitizers: Study of the Thermal and Hydrolytic Stability of 2-Picryl-5-Nitrotetrazole,

DTIC Science & Technology

1984-02-01

have been described previously (2]. The actual batch used was designated Batch D and was identical to that referred to as Batch C in Reference [2...Tetrazene was type RD1357 prepared at Materials Research Laboratories. The batch used was designated Batch 10/83(A). Lead Azide was type RD1343 and was...Preparation of Experimental Detonators Eperimental detonators were prepared in mild steel tubes, 6 mm o.d., 3.2 mm i.d., length 6 mm, prepared from
Faecal indicator bacteria enumeration in beach sand: A comparison study of extraction methods in medium to coarse sands

USGS Publications Warehouse

Boehm, A.B.; Griffith, J.; McGee, C.; Edge, T.A.; Solo-Gabriele, H. M.; Whitman, R.; Cao, Y.; Getrich, M.; Jay, J.A.; Ferguson, D.; Goodwin, K.D.; Lee, C.M.; Madison, M.; Weisberg, S.B.

2009-01-01

Aims: The absence of standardized methods for quantifying faecal indicator bacteria (FIB) in sand hinders comparison of results across studies. The purpose of the study was to compare methods for extraction of faecal bacteria from sands and recommend a standardized extraction technique. Methods and Results: Twenty-two methods of extracting enterococci and Escherichia coli from sand were evaluated, including multiple permutations of hand shaking, mechanical shaking, blending, sonication, number of rinses, settling time, eluant-to-sand ratio, eluant composition, prefiltration and type of decantation. Tests were performed on sands from California, Florida and Lake Michigan. Most extraction parameters did not significantly affect bacterial enumeration. anova revealed significant effects of eluant composition and blending; with both sodium metaphosphate buffer and blending producing reduced counts. Conclusions: The simplest extraction method that produced the highest FIB recoveries consisted of 2 min of hand shaking in phosphate-buffered saline or deionized water, a 30-s settling time, one-rinse step and a 10 : 1 eluant volume to sand weight ratio. This result was consistent across the sand compositions tested in this study but could vary for other sand types. Significance and Impact of the Study: Method standardization will improve the understanding of how sands affect surface water quality. ?? 2009 The Society for Applied Microbiology.
Comparative Emissions of Random Orbital Sanding between Conventional and Self-Generated Vacuum Systems

PubMed Central

Liverseed, David R.

2013-01-01

Conventional abrasive sanding generates high concentrations of particles. Depending on the substrate being abraded and exposure duration, overexposure to the particles can cause negative health effects ranging from respiratory irritation to cancer. The goal of this study was to understand the differences in particle emissions between a conventional random orbital sanding system and a self-generated vacuum random orbital sanding system with attached particle filtration bag. Particle concentrations were sampled for each system in a controlled test chamber for oak wood, chromate painted (hexavalent chromium) steel panels, and gel-coated (titanium dioxide) fiberglass panels using a Gesamtstaub-Probenahmesystem (GSP) sampler at three different locations adjacent to the sanding. Elevated concentrations were reported for all particles in the samples collected during conventional sanding. The geometric mean concentration ratios for the three substrates ranged from 320 to 4640 times greater for the conventional sanding system than the self-generated vacuum sanding system. The differences in the particle concentration generated by the two sanding systems were statistically significant with the two sample t-test (P < 0.0001) for all three substances. The data suggest that workers using conventional sanding systems could utilize the self-generated vacuum sanding system technology to potentially reduce exposure to particles and mitigate negative health effects. PMID:23065674
[Environmental toxicity of waste foundry sand].

PubMed

Zhang, Hai-Feng; Wang, Yu-Jue; Wang, Jin-Lin; Huang, Tian-You; Xiong, Ying

2013-03-01

The metal leaching characteristics and volatile organic compounds (VOCs) of five different types of waste foundry sands were analyzed with the toxicity characteristic leaching procedure (TCLP) and head space-gas chromatography (HS-GC). Microtox and soil dehydrogenase activity (DHA) tests were then used to evaluate the bio-effects of these waste sands. The results showed that due to the different metals poured and casting materials used to make the sand molds, there was significant difference among the five waste foundry sands in the compositions and concentrations of metal and organic pollutants. The concentrations of Fe in the leachates of iron and steel casting waste foundry sand exceeded the maximal allowable concentrations specified in the National Standard of Drinking Water Quality, whereas the As concentration in the leachate of aluminum casting waste foundry sand exceeded the standard. The five waste foundry sands had quite different compositions and levels of VOCs, which resulted in different levels of inhibition effects on the luminescent bacteria (30% and 95%). Additionally, the soil DHA tests suggested that metal pollutants in waste foundry sands may inhibit the soil microbial activity, whereas organics in the sands may slightly promote the microbial activity. The results of this study indicated that the waste foundry sands may pose considerable threat to the environment when improperly disposed.
Comparative emissions of random orbital sanding between conventional and self-generated vacuum systems.

PubMed

Liverseed, David R; Logan, Perry W; Johnson, Carl E; Morey, Sandy Z; Raynor, Peter C

2013-03-01

Conventional abrasive sanding generates high concentrations of particles. Depending on the substrate being abraded and exposure duration, overexposure to the particles can cause negative health effects ranging from respiratory irritation to cancer. The goal of this study was to understand the differences in particle emissions between a conventional random orbital sanding system and a self-generated vacuum random orbital sanding system with attached particle filtration bag. Particle concentrations were sampled for each system in a controlled test chamber for oak wood, chromate painted (hexavalent chromium) steel panels, and gel-coated (titanium dioxide) fiberglass panels using a Gesamtstaub-Probenahmesystem (GSP) sampler at three different locations adjacent to the sanding. Elevated concentrations were reported for all particles in the samples collected during conventional sanding. The geometric mean concentration ratios for the three substrates ranged from 320 to 4640 times greater for the conventional sanding system than the self-generated vacuum sanding system. The differences in the particle concentration generated by the two sanding systems were statistically significant with the two sample t-test (P < 0.0001) for all three substances. The data suggest that workers using conventional sanding systems could utilize the self-generated vacuum sanding system technology to potentially reduce exposure to particles and mitigate negative health effects.
Study on shear properties of coral sand under cyclic simple shear condition

NASA Astrophysics Data System (ADS)

Ji, Wendong; Zhang, Yuting; Jin, Yafei

2018-05-01

In recent years, the ocean development in our country urgently needs to be accelerated. The construction of artificial coral reefs has become an important development direction. In this paper, experimental studies of simple shear and cyclic simple shear of coral sand are carried out, and the shear properties and particle breakage of coral sand are analyzed. The results show that the coral sand samples show an overall shear failure in the simple shear test, which is more accurate and effective for studying the particle breakage. The shear displacement corresponding to the peak shear stress of the simple shear test is significantly larger than that corresponding to the peak shear stress of the direct shear test. The degree of particle breakage caused by the simple shear test is significantly related to the normal stress level. The particle breakage of coral sand after the cyclic simple shear test obviously increases compared with that of the simple shear test, and universal particle breakage occurs within the whole particle size range. The increasing of the cycle-index under cyclic simple shear test results in continuous compacting of the sample, so that the envelope curve of peak shearing force increases with the accumulated shear displacement.
Critical state of sand matrix soils.

PubMed

Marto, Aminaton; Tan, Choy Soon; Makhtar, Ahmad Mahir; Kung Leong, Tiong

2014-01-01

The Critical State Soil Mechanic (CSSM) is a globally recognised framework while the critical states for sand and clay are both well established. Nevertheless, the development of the critical state of sand matrix soils is lacking. This paper discusses the development of critical state lines and corresponding critical state parameters for the investigated material, sand matrix soils using sand-kaolin mixtures. The output of this paper can be used as an interpretation framework for the research on liquefaction susceptibility of sand matrix soils in the future. The strain controlled triaxial test apparatus was used to provide the monotonic loading onto the reconstituted soil specimens. All tested soils were subjected to isotropic consolidation and sheared under undrained condition until critical state was ascertain. Based on the results of 32 test specimens, the critical state lines for eight different sand matrix soils were developed together with the corresponding values of critical state parameters, M, λ, and Γ. The range of the value of M, λ, and Γ is 0.803-0.998, 0.144-0.248, and 1.727-2.279, respectively. These values are comparable to the critical state parameters of river sand and kaolin clay. However, the relationship between fines percentages and these critical state parameters is too scattered to be correlated.
Critical State of Sand Matrix Soils

PubMed Central

Marto, Aminaton; Tan, Choy Soon; Makhtar, Ahmad Mahir; Kung Leong, Tiong

2014-01-01

The Critical State Soil Mechanic (CSSM) is a globally recognised framework while the critical states for sand and clay are both well established. Nevertheless, the development of the critical state of sand matrix soils is lacking. This paper discusses the development of critical state lines and corresponding critical state parameters for the investigated material, sand matrix soils using sand-kaolin mixtures. The output of this paper can be used as an interpretation framework for the research on liquefaction susceptibility of sand matrix soils in the future. The strain controlled triaxial test apparatus was used to provide the monotonic loading onto the reconstituted soil specimens. All tested soils were subjected to isotropic consolidation and sheared under undrained condition until critical state was ascertain. Based on the results of 32 test specimens, the critical state lines for eight different sand matrix soils were developed together with the corresponding values of critical state parameters, M, λ, and Γ. The range of the value of M, λ, and Γ is 0.803–0.998, 0.144–0.248, and 1.727–2.279, respectively. These values are comparable to the critical state parameters of river sand and kaolin clay. However, the relationship between fines percentages and these critical state parameters is too scattered to be correlated. PMID:24757417
Experimental Observations of Localization Phenomena in Sands: Plane Strain Versus Triaxial Compression Conditions

NASA Technical Reports Server (NTRS)

Alshibli, Khalid A.; Batiste, Susan N.; Sture, Stein; Curreri, Peter A. (Technical Monitor)

2002-01-01

A comprehensive experimental investigation was conducted to investigate the effects of loading condition and confining pressure on strength properties and instability phenomena in sands. A uniform sub-rounded to rounded natural silica sand known as F-75 Ottawa sand was used in the investigation. The results of a series on Conventional Triaxial Compression (CTC) experiments tested under very low confining pressures (0.05 - 1.30) kPa tested in a Microgravity environment abroad the NASA Space Shuttle are presented in addition to the results similar specimens tested in terrestrial laboratory to investigate the effect of confining pressure on the constitutive behavior of sands. The behavior of the CTC experiments is compared with the results of Plane Strain (PS) experiments. Computed tomography and other digital imaging techniques were used to study the development and evolution of shear bands.
Groundwater arsenic remediation using zerovalent iron: Batch and column tests

EPA Science Inventory

Recently, increasing efforts have been made to explore the applicability and limitations of zerovalent iron (Fe0) for the treatment of arsenicbearing groundwater and wastewater. The experimental batch and column tests have demonstrated that arsenate and arsenite are removed effec...
Mechanical and Physical Properties of ASTM C33 Sand

DTIC Science & Technology

2008-02-01

ERDC/GSL TR-08-2 7 Grain-size Distribution (1) (ASTM D 422) 1 test run on total sand sample Proctor Density Curves (2) (ASTM D 698 and D... Proctor (Figure 4). Because of the noncohesive nature of the SP material, a series of relative density tests measuring both minimum and maximum... density tests were conducted with moisture added to the sand. A summary of the minimum and maximum densities is given in Table 2. During Proctor
Good Laboratory Practices of Materials Testing at NASA White Sands Test Facility

NASA Technical Reports Server (NTRS)

Hirsch, David; Williams, James H.

2005-01-01

An approach to good laboratory practices of materials testing at NASA White Sands Test Facility is presented. The contents include: 1) Current approach; 2) Data analysis; and 3) Improvements sought by WSTF to enhance the diagnostic capability of existing methods.
Evaluation of the factors controlling the time-dependent inactivation rate coefficients of bacteriophage MS2 and PRD1

USGS Publications Warehouse

Anders, R.; Chrysikopoulos, C.V.

2006-01-01

Static and dynamic batch experiments were conducted to study the effects of temperature and the presence of sand on the inactivation of bacteriophage MS2 and PRD1. The experimental data suggested that the inactivation process can be satisfactorily represented by a pseudo-first-order expression with time-dependent rate coefficients. The time-dependent rate coefficients were used to determine pertinent thermodynamic properties required for the analysis of the molecular processes involved in the inactivation of each bacteriophage. A combination of high temperature and the presence of sand appears to produce the greatest disruption to the surrounding protein coat of MS2. However, the lower activation energies for PRD1 indicate a weaker dependence of the inactivation rate on temperature. Instead, the presence of air-liquid and air-solid interfaces appears to produce the greatest damage to specific viral components that are related to infection. These results indicate the importance of using thermodynamic parameters based on the time-dependent inactivation model to better predict the inactivation of viruses in groundwater. ?? 2006 American Chemical Society.
Pb2+ and Zn2+ adsorption by a natural aluminum- and iron-bearing surface coating on an aquifer sand

USGS Publications Warehouse

Coston, J.A.; Fuller, C.C.; Davis, J.A.

1995-01-01

Pb2+ and Zn2+ adsorption was studied in batch experiments with material collected from a shallow, unconfined aquifer of glacial outwash sand and gravel in Falmouth, Massachusetts, USA. The aquifer solids contain primarily quartz with minor amounts of alkali feldspars and ferromagnetic minerals. Pb2+ and Zn2+ adsorption experiments with various grain size and mineral fractions of the aquifer solids showed that: 1) Zn2+ adsorption was independent of grain size, but Pb2+ was preferentially adsorbed by the <64 ??m size fraction and 2) Pb2+ adsorption decreased after removal of the paramagnetic, Fe-bearing mineral fraction, but Zn2+ adsorption was unaffected. Pb2+ and Zn2+ adsorption on mineral separates from the aquifer material compared with metal adsorption on a purified quartz powder indicated that adsorption of both metal ions was dominated by coatings on the quartz fraction of the sediment. Characterization of the coatings by AES, SEM-EDS, and TOF-SIMS demonstrated that the natural quartz grains were extensively coated with Al- and Fe-bearing minerals of variable composition. -from Authors
Geochemical heterogeneity in a sand and gravel aquifer: Effect of sediment mineralogy and particle size on the sorption of chlorobenzenes

USGS Publications Warehouse

Barber, Larry B.; Thurman, E. Michael; Runnells, Donald D.

1992-01-01

The effect of particle size, mineralogy and sediment organic carbon (SOC) on sorption of tetrachlorobenzene and pentachlorobenzene was evaluated using batch-isotherm experiments on sediment particle-size and mineralogical fractions from a sand and gravel aquifer, Cape Cod, Massachusetts. Concentration of SOC and sorption of chlorobenzenes increase with decreasing particle size. For a given particle size, the magnetic fraction has a higher SOC content and sorption capacity than the bulk or non-magnetic fractions. Sorption appears to be controlled by the magnetic minerals, which comprise only 5–25% of the bulk sediment. Although SOC content of the bulk sediment is <0.1%, the observed sorption of chlorobenzenes is consistent with a partition mechanism and is adequately predicted by models relating sorption to the octanol/water partition coefficient of the solute and SOC content. A conceptual model based on preferential association of dissolved organic matter with positively-charged mineral surfaces is proposed to describe micro-scale, intergranular variability in sorption properties of the aquifer sediments.

Design and initial testing of a piezoelectric sensor to quantify aeolian sand transport

NASA Astrophysics Data System (ADS)

Raygosa-Barahona, Ruben; Ruiz-Martinez, Gabriel; Mariño-Tapia, Ismael; Heyser-Ojeda, Emilio

2016-09-01

This paper describes a sensor for measuring the mass flux of aeolian sand transport based on a low-cost piezo-electric transducer. The device is able to measure time series of aeolian sand transport. Maximum fluxes of 27 mg per second can be achieved. The design includes a sand trap, an electronic amplifier circuit and an embedded system for data collection. A field test was performed, where the basis for signal interpretation and the corresponding measurements of aeolian sand transport are presented. The sensor successfully measures fluxes driven by sea breezes of 10 ms-1, showing the importance of this process for dune-building in the region.
34. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF BLOCKHOUSE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

34. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF BLOCKHOUSE AND TOP OF TEST BAY, LOOKING NORTHEAST - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
33. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF BLOCKHOUSE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

33. 100,000 POUND STATIC TEST FACILITY: GENERAL VIEW OF BLOCKHOUSE AND UPPER LEVEL OF TEST BAY, LOOKING NORTH - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Combination of surfactant solubilization with permanganate oxidation for DNAPL remediation.

PubMed

Li, Zhaohui; Hanlie, Hong

2008-02-01

A combination of surfactant solubilization with permanganate oxidation of trichloroethylene (TCE) was studied in batch, flow-through column, and three-dimensional (3-D) tank tests. Batch results showed that chloride production, an indication of TCE degradation, followed a pseudo-first-order reaction kinetics with respect to KMnO4 in the presence of free-phase TCE. A higher chloride production rate was achieved when anionic surfactants were present. The observed pseudo-first-order reaction rate constant increased as the concentrations of anionic surfactants Ninate 411 and Calfax increased from 0% to 0.1%, 0.3%, and 1.0%. Column experiments on TCE reduction by permanganate in the presence and absence of surfactants were carried out using well-sorted coarse Ottawa sand. The peak effluent TCE concentration reached 1700 mg/L due to enhanced solubilization when both sodium dodecyl sulfate (SDS) and permanganate were used, in contrast to less than 300 mg/L when only permanganate solution was used. In addition, the effluent TCE concentration decreased much faster when SDS was present in the permanganate solution, compared with the case when SDS was absent. With an initial 1 mL of TCE emplaced in the columns, the effluent TCE concentration dropped to <5mg/L after 29-31h of flushing with 1% SDS and 0.1% KMnO4 solution in contrast to 37-73 h when only 0.1% KMnO4 was used. Furthermore, KMnO4 breakthrough occurred after 21-25 h of injection when SDS was present compared with 45-70 h later when SDS was absent. A slightly higher chloride concentration was observed in the earlier stage of the column experiment and the chloride concentration decreased quickly once KMnO4 was seen in the effluent. The 3-D tank test showed that the MnO2 precipitation front formed more quickly when 1% SDS was present, which further confirmed the observation from the column study.
RELATIVE LEACHING AND AQUATIC TOXICITY OF PRESSURE-TREATED WOOD PRODUCTS USING BATCH LEACHING TESTS

EPA Science Inventory

Samples of southern yellow pine dimensional lumber, each treated with one of five different waterborne chemical preservatives, were leached using 18-hour batch leaching tests. The wood preservatives included chromated copper arsenate (CCA), alkaline copper quaternary (ACQ), coppe...
X-ray Analysis of Defects and Anomalies in AGR-5/6/7 TRISO Particles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Helmreich, Grant W.; Hunn, John D.; Skitt, Darren J.

2017-06-01

Coated particle fuel batches J52O-16-93164, 93165, 93166, 93168, 93169, 93170, and 93172 were produced by Babcock and Wilcox Technologies (BWXT) for possible selection as fuel for the Advanced Gas Reactor Fuel Development and Qualification (AGR) Program’s AGR-5/6/7 irradiation test in the Idaho National Laboratory (INL) Advanced Test Reactor (ATR), or may be used for other tests. Each batch was coated in a 150-mm-diameter production-scale fluidized-bed chemical vapor deposition (CVD) furnace. Tristructural isotropic (TRISO) coatings were deposited on 425-μm-nominal-diameter spherical kernels from BWXT lot J52R-16-69317 containing a mixture of 15.4%-enriched uranium carbide and uranium oxide (UCO), with the exception of Batchmore » 93164, which used similar kernels from BWXT lot J52L-16-69316. The TRISO-coatings consisted of a ~50% dense carbon buffer layer with 100-μmnominal thickness, a dense inner pyrolytic carbon (IPyC) layer with 40-μm-nominal thickness, a silicon carbide (SiC) layer with 35-μm-nominal thickness, and a dense outer pyrolytic carbon (OPyC) layer with 40-μm-nominal thickness. Each coated particle batch was sieved to upgrade the particles by removing over-sized and under-sized material, and the upgraded batch was designated by appending the letter A to the end of the batch number (e.g., 93164A). Secondary upgrading by sieving was performed on the upgraded batches to remove specific anomalies identified during analysis for Defective IPyC, and the upgraded batches were designated by appending the letter B to the end of the batch number (e.g., 93165B). Following this secondary upgrading, coated particle composite J52R-16-98005 was produced by BWXT as fuel for the AGR Program’s AGR-5/6/7 irradiation test in the INL ATR. This composite was comprised of coated particle fuel batches J52O-16-93165B, 93168B, 93169B, and 93170B.« less
A morphometric comparison of the Namib and southwest Kalahari dunefields using ASTER GDEM data

NASA Astrophysics Data System (ADS)

White, Kevin; Bullard, Joanna; Livingstone, Ian; Moran, Lisa

2015-12-01

The increased availability of digital elevation models and satellite image data enable testing of morphometric relationships between sand dune variables (dune height, spacing and equivalent sand thickness), which were originally established using limited field survey data. These long-established geomorphological hypotheses can now be tested against very much larger samples than were possible when available data were limited to what could be collected by field surveys alone. This project uses ASTER global digital elevation model (GDEM) data to compare morphometric relationships between sand dune variables in the southwest Kalahari dunefield to those of the Namib sand sea, to test whether the relationships found in an active sand sea (Namib) also hold for the fixed dune system of the nearby southwest Kalahari. The data show significant morphometric differences between the simple linear dunes of the Namib sand sea and the southwest Kalahari; the latter do not show the expected positive relationship between dune height and spacing. The southwest Kalahari dunes show a similar range of dune spacings, but they are less tall, on average, than the Namib sand sea dunes. There is a clear spatial pattern to these morphometric data; the tallest and most closely spaced dunes are towards the southeast of the Kalahari dunefield; and this is where the highest values of equivalent sand thickness result. We consider the possible reasons for the observed differences and highlight the need for more studies comparing sand seas and dunefields from different environmental settings.
Penetration tests to study the mechanical tribological properties of chisel type knife

NASA Astrophysics Data System (ADS)

Vlăduţoiu, L.; Chişiu, G.; Andrei, T.; Predescu, A.; Muraru, C.; Vlăduţ, V.

2017-02-01

The goal of this study was to analyze the behaviour of chisel knife type penetration in a certain type of sand. A series of penetration tests were carried out with chisel knife type, the answer to penetration depending mainly on nature, shape, size of knife and operating parameters such as speed, depth and working conditions. Tests were conducted in work conditions with wet sand and dry sand and determined force of resistance to penetration of the chisel knife type to a certain depth.
Supercritical-Fluid Extraction of Oil From Tar Sands

NASA Technical Reports Server (NTRS)

Compton, L. E.

1982-01-01

New supercritical solvent mixtures have been laboratory-tested for extraction of oil from tar sands. Mixture is circulated through sand at high pressure and at a temperature above critical point, dissolving organic matter into the compressed gas. Extract is recovered from sand residues. Low-temperature super-critical solvents reduce energy consumption and waste-disposal problems.
40 CFR 1066.425 - Performing emission tests.

Code of Federal Regulations, 2014 CFR

2014-07-01

... as described in paragraph (g)(5) of this section and zero and span all batch gas analyzers as soon as practical before any batch sample analysis. You may perform this batch analyzer zero and span before the end... value after stabilizing a zero gas to the analyzer. Stabilization may include time to purge the analyzer...
Study on HDPE Mixed with Sand as Backfilled Material on Retaining Structure

NASA Astrophysics Data System (ADS)

Talib, Z. A.

2018-04-01

The failure of the retaining wall is closely related to backfill material. Granular soils such as sand and gravel are most suitable backfill material because of its drainage properties. However two basic materials are quite heavy and contribute high amount of lateral loads. This study was to determine the effectiveness High Density Polyethylene (HDPE) as a backfill material. HDPE has a lighter weight compare to the sand. It makes HDPE has potential to be used as backfill material. The objective of this study is to identify the most effective percentage of HDPE to replace sand as a backfill material. The percentage of HDPE used in this study was 20%, 30%, 50%, 75% and also 100%. Testing involved in this study were sieve analysis test, constant head permeability test, direct shear test and relative density test. The result shows that the HDPE can be used as backfilled material and save the cost of backfill material
White Sands, Carrizozo Lava Beds, NM

NASA Image and Video Library

1973-06-22

SL2-04-288 (22 June 1973) --- A truly remarkable view of White Sands and the nearby Carrizozo Lava Beds in southeast New Mexico (33.5N, 106.5W). White Sands, site of the WW II atomic bomb development and testing facility and later post war nuclear weapons testing that can still be seen in the cleared circular patterns on the ground. Photo credit: NASA
Slow-release Permanganate Gel (SRP-G) for Groundwater Remediation: Spreading, Gelation, and Release in Porous and Low-Permeability Media

NASA Astrophysics Data System (ADS)

Lee, E. S.; Hastings, J.; Kim, Y.

2015-12-01

Dense nonaqueous phase liquids (DNAPLs) like trichloroethylene (TCE) serve as the most common form of groundwater pollution in the world. Pore-plugging by the solid oxidation product MnO2 and limited lateral dispersion of the oxidant are two common problems with existing in-situ chemical oxidation (ISCO) schemes that could be alleviated through the development of a delayed gelation method for oxidant delivery. The objective of the current study was to further develop and optimize slow-release permanganate gel (SRP-G), a solution comprising colloidal silica and KMnO4, as a novel low-cost treatment option for large and dilute TCE plumes in groundwater. Batch tests showed that gelation could be delayed through manipulation of KMnO4 concentration, pH, and silica particle size of the SRP-G solution. In flow-through columns and flow-tanks filled with saturated sands, silica concentration had little effect on the gelation lag stage and release rate, but increasing silica concentration was associated with increasing release duration. When compared to a pure KMnO4 solution, visual observations and [MnO4-] measurements from flow tank tests demonstrated that the SRP-G prolonged the release duration and enhanced lateral spreading of the oxidant.
Behavior of plastic sand confinement grids

DOT National Transportation Integrated Search

1986-01-01

The concept of improving the load carrying ability of unbound aggregates, particularly sand, by lateral confinement has been investigated for some time. Extensive full-scale testing of the trafficability of confined beach sand pavement layers has bee...
Pilot- and bench-scale testing of faecal indicator bacteria survival in marine beach sand near point sources.

PubMed

Mika, K B; Imamura, G; Chang, C; Conway, V; Fernandez, G; Griffith, J F; Kampalath, R A; Lee, C M; Lin, C-C; Moreno, R; Thompson, S; Whitman, R L; Jay, J A

2009-07-01

Factors affecting faecal indicator bacteria (FIB) and pathogen survival/persistence in sand remain largely unstudied. This work elucidates how biological and physical factors affect die-off in beach sand following sewage spills. Solar disinfection with mechanical mixing was pilot-tested as a disinfection procedure after a large sewage spill in Los Angeles. Effects of solar exposure, mechanical mixing, predation and/or competition, season, and moisture were tested at bench scale. First-order decay constants for Escherichia coli ranged between -0.23 and -1.02 per day, and for enterococci between -0.5 and -1.0 per day. Desiccation was a dominant factor for E. coli but not enterococci inactivation. Effects of season were investigated through a comparison of experimental results from winter, spring, and fall. Moisture was the dominant factor controlling E. coli inactivation kinetics. Initial microbial community and sand temperature were also important factors. Mechanical mixing, common in beach grooming, did not consistently reduce bacterial levels. Inactivation rates are mainly dependent on moisture and high sand temperature. Chlorination was an effective disinfection treatment in sand microcosms inoculated with raw influent.
Comparison of biomass from integrated fixed-film activated sludge (IFAS), moving bed biofilm reactor (MBBR) and membrane bioreactor (MBR) treating recalcitrant organics: Importance of attached biomass.

PubMed

Huang, Chunkai; Shi, Yijing; Xue, Jinkai; Zhang, Yanyan; Gamal El-Din, Mohamed; Liu, Yang

2017-03-15

This study compared microbial characteristics and oil sands process-affected water (OSPW) treatment performance of five types of microbial biomass (MBBR-biofilm, IFAS-biofilm, IFAS-floc, MBR-aerobic-floc, and MBR-anoxic-floc) cultivated from three types of bioreactors (MBBR, IFAS, and MBR) in batch experiments. Chemical oxygen demand (COD), ammonium, acid extractable fraction (AEF), and naphthenic acids (NAs) removals efficiencies were distinctly different between suspended and attached bacterial aggregates and between aerobic and anoxic suspended flocs. MBR-aerobic-floc and MBR-anoxic-floc demonstrated COD removal efficiencies higher than microbial aggregates obtained from MBBR and IFAS, MBBR and IFAS biofilm had higher AEF removal efficiencies than those obtained using flocs. MBBR-biofilm demonstrated the most efficient NAs removal from OSPW. NAs degradation efficiency was highly dependent on the carbon number and NA cyclization number according to UPLC/HRMS analysis. Mono- and di-oxidized NAs were the dominant oxy-NA species in OSPW samples. Microbial analysis with quantitative polymerase chain reaction (q-PCR) indicated that the bacterial 16S rRNA gene abundance was significantly higher in the batch bioreactors with suspended flocs than in those with biofilm, the NSR gene abundance in the MBR-anoxic bioreactor was significantly lower than that in aerobic batch bioreactors, and denitrifiers were more abundant in the suspended phase of the activated sludge flocs. Copyright © 2016 Elsevier B.V. All rights reserved.
Batch test screening of industrial product/byproduct filter materials for agricultural drainage water treatment

USDA-ARS?s Scientific Manuscript database

Filter treatment may be a viable means for removing the nitrate, phosphate, and pesticides discharged with agricultural drainage waters that cause adverse environmental impacts within the U.S. on local, regional, and national scales. Laboratory batch test screening for agricultural drainage water ...
NASA Johnson Space Center: White Sands Test Facility

NASA Technical Reports Server (NTRS)

Aggarwal, Pravin; Kowalski, Robert R.

2011-01-01

This slide presentation reviews the testing facilities and laboratories available at the White Sands Test Facility (WSTF). The mission of WSTF is to provide the expertise and infrastructure to test and evaluate spacecraft materials, components and propulsion systems that enable the safe exploration and use of space. There are nine rocket test stands in two major test areas, six altitude test stands, three ambient test stands,
A Statistics-Based Cracking Criterion of Resin-Bonded Silica Sand for Casting Process Simulation

NASA Astrophysics Data System (ADS)

Wang, Huimin; Lu, Yan; Ripplinger, Keith; Detwiler, Duane; Luo, Alan A.

2017-02-01

Cracking of sand molds/cores can result in many casting defects such as veining. A robust cracking criterion is needed in casting process simulation for predicting/controlling such defects. A cracking probability map, relating to fracture stress and effective volume, was proposed for resin-bonded silica sand based on Weibull statistics. Three-point bending test results of sand samples were used to generate the cracking map and set up a safety line for cracking criterion. Tensile test results confirmed the accuracy of the safety line for cracking prediction. A laboratory casting experiment was designed and carried out to predict cracking of a cup mold during aluminum casting. The stress-strain behavior and the effective volume of the cup molds were calculated using a finite element analysis code ProCAST®. Furthermore, an energy dispersive spectroscopy fractographic examination of the sand samples confirmed the binder cracking in resin-bonded silica sand.
An experimental study on dynamic response for MICP strengthening liquefiable sands

NASA Astrophysics Data System (ADS)

Han, Zhiguang; Cheng, Xiaohui; Ma, Qiang

2016-12-01

The technology of bio-grouting is a new technique for soft ground improvement. Many researchers have carried out a large number of experiments and study on this topic. However, few studies have been carried out on the dynamic response of solidified sand samples, such reducing liquefaction in sand. To study this characteristic of microbial-strengthened liquefiable sandy foundation, a microorganism formula and grouting scheme is applied. After grouting, the solidified samples are tested via dynamic triaxial testing to examine the cyclic performance of solidified sand samples. The results indicate that the solidified sand samples with various strengths can be obtained to meet different engineering requirements, the use of bacteria solution and nutritive salt is reduced, and solidified time is shortened to 1-2 days. Most importantly, in the study of the dynamic response, it is found that the MICP grouting scheme is effective in improving liquefiable sand characteristic, such as liquefaction resistance.

Cadmium removal using Cladophora in batch, semi-batch and flow reactors.

PubMed

Sternberg, Steven P K; Dorn, Ryan W

2002-02-01

This study presents the results of using viable algae to remove cadmium from a synthetic wastewater. In batch and semi-batch tests, a local strain of Cladophora algae removed 80-94% of the cadmium introduced. The flow experiments that followed were conducted using non-local Cladophora parriaudii. Results showed that the alga removed only 12.7(+/-6.4)% of the cadmium introduced into the reactor. Limited removal was the result of insufficient algal quantities and poor contact between the algae and cadmium solution.
Optimization and evaluation of a bottom substrate denitrification tank for nitrate removal from a recirculating aquaculture system.

PubMed

Pungrasmi, Wiboonluk; Playchoom, Cholticha; Powtongsook, Sorawit

2013-08-01

A bottom substrate denitrification tank for a recirculating aquaculture system was developed. The laboratory scale denitrification tank was an 8 L tank (0.04 m2 tank surface area), packed to a depth of 5 cm with a bottom substrate for natural denitrifying bacteria. An aquarium pump was used for gentle water mixing in the tank; the dissolved oxygen in the water was maintained in aerobic conditions (e.g. > 2 mg/L) while anoxic conditions predominated only at the bottom substrate layer. The results showed that, among the four substrates tested (soil, sand, pumice stone and vermiculite), pumice was the most preferable material. Comparing carbon supplementation using methanol and molasses, methanol was chosen as the carbon source because it provided a higher denitrification rate than molasses. When methanol was applied at the optimal COD:N ratio of 5:1, a nitrate removal rate of 4591 +/- 133 mg-N/m2 tank bottom area/day was achieved. Finally, nitrate removal using an 80 L denitrification tank was evaluated with a 610 L recirculating tilapia culture system. Nitrate treatment was performed by batch transferring high nitrate water from the nitrification tank into the denitrification tank and mixing with methanol at a COD:N ratio of 5:1. The results from five batches of nitrate treatment revealed that nitrate was successfully removed from water without the accumulation of nitrite and ammonia. The average nitrate removal efficiency was 85.17% and the average denitrification rate of the denitrification tank was 6311 +/- 945 mg-N/m2 tank bottom area/day or 126 +/- 18 mg-N/L of pumice packing volume/day.
40 CFR 63.1325 - Batch process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2010 CFR

2010-07-01

... either total organic HAP or TOC. For purposes of this paragraph (c), the term “batch emission episode... ensure the measurement of total organic HAP or TOC (minus methane and ethane) concentrations in all batch... organic HAP or TOC, as appropriate. Alternatively, any other method or data that has been validated...
40. 500,000 POUND STATIC TEST FACILITY: DISTANT VIEW WITH BLOCKHOUSE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

40. 500,000 POUND STATIC TEST FACILITY: DISTANT VIEW WITH BLOCKHOUSE IN FOREGROUND, LOOKING SOUTHEAST - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Testing and evaluation of recovered traction sanding material.

DOT National Transportation Integrated Search

2013-04-01

The Montana Department of Transportation (MDT) is searching for a solution to the accumulation of traction sand that is applied to Montana highways every winter. An analysis of reuse and recycle options for salvaged traction sand was conducted using ...
A short term quality control tool for biodegradable microspheres.

PubMed

D'Souza, Susan; Faraj, Jabar A; Dorati, Rossella; DeLuca, Patrick P

2014-06-01

Accelerated in vitro release testing methodology has been developed as an indicator of product performance to be used as a discriminatory quality control (QC) technique for the release of clinical and commercial batches of biodegradable microspheres. While product performance of biodegradable microspheres can be verified by in vivo and/or in vitro experiments, such evaluation can be particularly challenging because of slow polymer degradation, resulting in extended study times, labor, and expense. Three batches of Leuprolide poly(lactic-co-glycolic acid) (PLGA) microspheres having varying morphology (process variants having different particle size and specific surface area) were manufactured by the solvent extraction/evaporation technique. Tests involving in vitro release, polymer degradation and hydration of the microspheres were performed on the three batches at 55°C. In vitro peptide release at 55°C was analyzed using a previously derived modification of the Weibull function termed the modified Weibull equation (MWE). Experimental observations and data analysis confirm excellent reproducibility studies within and between batches of the microsphere formulations demonstrating the predictability of the accelerated experiments at 55°C. The accelerated test method was also successfully able to distinguish the in vitro product performance between the three batches having varying morphology (process variants), indicating that it is a suitable QC tool to discriminate product or process variants in clinical or commercial batches of microspheres. Additionally, data analysis utilized the MWE to further quantify the differences obtained from the accelerated in vitro product performance test between process variants, thereby enhancing the discriminatory power of the accelerated methodology at 55°C.
Prediction of Liquefaction Potential of Dredge Fill Sand by DCP and Dynamic Probing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alam, Md. Jahangir; Azad, Abul Kalam; Rahman, Ziaur

2008-07-08

From many research it is proved that liquefaction potential of sand is function of mainly relative density and confining pressure. During routine site investigations, high-quality sampling and laboratory testing of sands are not feasible because of inevitable sample disturbance effects and budgetary constraints. On the other hand quality control of sand fill can be done by determining in situ density of sand in layer by layer which is expensive and time consuming. In this paper TRL DCP (Transportation Research Laboratory Dynamic Cone Penetration) and DPL (Dynamic Probing Light) are calibrated to predict the relative density of sand deposit. For thismore » purpose sand of known relative density is prepared in a calibration chamber which is a mild steel cylinder with diameter 0.5 m and height 1.0 m. Relative density of sand is varied by controlling height of fall and diameter of hole of sand discharge bowl. After filling, every time DPL and DCP tests are performed and for every blow the penetration of cone is recorded. N10 is then calculated from penetration records. Thus a database is compiled where N10 and relative densities are known. A correlation is made between N{sub 10} and relative density for two types of sand. A good correlation of N{sub 10} and relative density is found.« less
A practical method for estimating maximum shear modulus of cemented sands using unconfined compressive strength

NASA Astrophysics Data System (ADS)

Choo, Hyunwook; Nam, Hongyeop; Lee, Woojin

2017-12-01

The composition of naturally cemented deposits is very complicated; thus, estimating the maximum shear modulus (Gmax, or shear modulus at very small strains) of cemented sands using the previous empirical formulas is very difficult. The purpose of this experimental investigation is to evaluate the effects of particle size and cement type on the Gmax and unconfined compressive strength (qucs) of cemented sands, with the ultimate goal of estimating Gmax of cemented sands using qucs. Two sands were artificially cemented using Portland cement or gypsum under varying cement contents (2%-9%) and relative densities (30%-80%). Unconfined compression tests and bender element tests were performed, and the results from previous studies of two cemented sands were incorporated in this study. The results of this study demonstrate that the effect of particle size on the qucs and Gmax of four cemented sands is insignificant, and the variation of qucs and Gmax can be captured by the ratio between volume of void and volume of cement. qucs and Gmax of sand cemented with Portland cement are greater than those of sand cemented with gypsum. However, the relationship between qucs and Gmax of the cemented sand is not affected by the void ratio, cement type and cement content, revealing that Gmax of the complex naturally cemented soils with unknown in-situ void ratio, cement type and cement content can be estimated using qucs.
A Laboratory Investigation on Shear Strength Behavior of Sandy Soil: Effect of Glass Fiber and Clinker Residue Content

NASA Astrophysics Data System (ADS)

Bouaricha, Leyla; Henni, Ahmed Djafar; Lancelot, Laurent

2017-12-01

A study was undertaken to investigate the shear strength parameters of treated sands reinforced with randomly distributed glass fibers by carrying out direct shear test after seven days curing periods. Firstly, we studied the fiber content and fiber length effect on the peak shear strength on samples. The second part gives a parametric analysis on the effect of glass fiber and clinker residue content on the shear strength parameters for two types of uniform Algerian sands having different particle sizes (Chlef sand and Rass sand) with an average relative density Dr = 50%. Finally, the test results show that the combination of glass fiber and clinker residue content can effectively improve the shear strength parameters of soil in comparison with unreinforced soil. For instance, there is a significant gain for the cohesion and friction angle of reinforced sand of Chlef. Compared to unreinforced sand, the cohesion for sand reinforced with different ratios of clinker residue increased by 4.36 to 43.08 kPa for Chlef sand and by 3.1 to 28.64 kPa for Rass sand. The feature friction angles increased from 38.73° to 43.01° (+4.28°), and after the treatment, clinker residue content of soil evaluated to 5% (WRC = 5%).
Complete Non-Radioactive Operability Tests for Cladding Hull Chlorination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Collins, Emory D; Johnson, Jared A.; Hylton, Tom D.

2016-04-01

Non-radioactive operability tests were made to test the metal chlorination reactor and condenser and their accessories using batch chlorinations of non-radioactive cladding samples and to identify optimum operating practices and components that need further modifications prior to installation of the equipment into the hot cell for tests on actual used nuclear fuel (UNF) cladding. The operability tests included (1) modifications to provide the desired heating and reactor temperature profile; and (2) three batch chlorination tests using, respectively, 100, 250, and 500 g of cladding. During the batch chlorinations, metal corrosion of the equipment was assessed, pressurization of the gas inletmore » was examined and the best method for maintaining solid salt product transfer through the condenser was determined. Also, additional accessing equipment for collection of residual ash and positioning of the unit within the hot cell were identified, designed, and are being fabricated.« less
A Modified Edge Crack Torsion Test for Measurement of Mode III Fracture Toughness of Laminated Tape Composites

NASA Technical Reports Server (NTRS)

Czabaj, Michael W.; Davidson, Barry D.; Ratcliffe, James G.

2016-01-01

Modifications to the edge crack torsion (ECT) test are studied to improve the reliability of this test for measuring the mode-III fracture toughness, G (sub IIIc), of laminated tape fiber-reinforced polymeric (FRP) composites. First, the data reduction methods currently used in the ECT test are evaluated and deficiencies in their accuracy are discussed. An alternative data reduction technique, which uses a polynomial form to represent ECT specimen compliance solution, is evaluated and compared to FEA (finite element analysis) results. Second, seven batches of ECT specimens are tested, each batch containing specimens with a preimplanted midplane edge delamination and midplane plies with orientations of plus theta divided by minus theta, with theta ranging from 0 degrees to 90 degrees in 15-degree increments. Tests on these specimens show that intralaminar cracking occurs in specimens from all batches except for which theta = 15 degrees and 30 degrees. Tests on specimens of these two batches are shown to result in mode-III delamination growth at the intended ply interface. The findings from this study are encouraging steps towards the use of the ECT test as a standardized method for measuring G (sub IIIc), although further modification to the data reduction method is required to make it suitable for use as part of a standardized test method.
40 CFR 80.1644 - Sampling and testing requirements for producers and importers of certified ethanol denaturant.

Code of Federal Regulations, 2014 CFR

2014-07-01

... producers and importers of certified ethanol denaturant. 80.1644 Section 80.1644 Protection of Environment... ethanol denaturant. (a) Sample and test each batch of certified ethanol denaturant. (1) Producers and importers of certified ethanol denaturant shall collect a representative sample from each batch of certified...
Sludge batch 9 follow-on actual-waste testing for the nitric-glycolic flowsheet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martino, C. J.; Newell, J. D.; Crawford, C. L.

An actual-waste Sludge Batch 9 qualification run with the nitric-glycolic flowsheet (SC-18) was performed in FY16. In order to supplement the knowledge base for the nitric-glycolic flowsheet, additional testing was performed on the product slurries, condensates, and intermediate samples from run SC-18.
40 CFR 1065.245 - Sample flow meter for batch sampling.

Code of Federal Regulations, 2010 CFR

2010-07-01

... rates or total flow sampled into a batch sampling system over a test interval. You may use the... rates or total raw exhaust flow over a test interval. (b) Component requirements. We recommend that you... averaging Pitot tube, or a hot-wire anemometer. Note that your overall system for measuring sample flow must...
Update on EPA Stove Testing, Focus on Batch-Fueled Stoves

EPA Science Inventory

A webinar, entitled Update on EPA Stove Testing, Focus on Batch-Fueled Stoves, will be presented by Jim Jetter, EPA, and will be hosted by the Global Alliance for Clean Cookstoves on August 20, 2013. The purpose of this webinar is to (1) provide an update on the EPA cookstove te...
Study of twenty preparations of human albumin solution which failed in quality control testing due to elevated sodium content, a poor internal quality control at manufacturing unit.

PubMed

Prasad, J P; Madhu, Y; Singh, Surinder; Soni, G R; Agnihotri, N; Singh, Varsha; Kumar, Pradeep; Jain, Nidhi; Prakash, Anu; Singh, Varun

2016-11-01

Current study is conducted in our laboratory due to failure in quality control testing of twenty batches of Human Albumin solution in which sodium content is higher than the prescribed limit. These batches are received in short duration from indigenous manufacturer and is the first incident of failure of Human albumin preparation in sodium content of manufacturer. On request of manufacturer, study is conducted to rule out the cause. Repeat testing of each out of specification batch is conducted and a trend analysis is drawn between our findings and manufacturer's results, also study of trend analysis of manufacturer for the last one year. Trend analysis data indicated towards poor consistency of batches with major shift at various time intervals in sodium content of human albumin preparation. Further analysis rule out that non-traceable quality of standard used in the internal quality control testing by manufacturer is the root cause of the problem. Copyright © 2016 International Alliance for Biological Standardization. Published by Elsevier Ltd. All rights reserved.
Occurrence of Partial Nuclei in Eggs of the Sand Dollar, Clypeaster japonicus.

PubMed

Yoneda, M; Nemoto, S I

1990-10-01

Females of Clypeaster japonicus bearing eggs with multiple nuclei were occasionally found. DAPI (4'-6-diamidino-2-phenylindole) stained all these nuclei. The summed volume of the two nuclei in binucleate eggs was similar to the nuclear volume in mononucleate eggs from the same batch. On fertilization, two partial nuclei migrated to the center of the egg with a time-course similar to that taken by a single nucleus; they then participated in forming the zygote nucleus, which subsequently formed a single mitotic spindle. These multiple nuclei thus appear to function as genuine nuclei. Possibly they result from the failure of a single nucleus to form during oogenesis.
Cation-Inhibited Transport of Graphene Oxide Nanomaterials in Saturated Porous Media: The Hofmeister Effects.

PubMed

Xia, Tianjiao; Qi, Yu; Liu, Jing; Qi, Zhichong; Chen, Wei; Wiesner, Mark R

2017-01-17

Transport of negatively charged nanoparticles in porous media is largely affected by cations. To date, little is known about how cations of the same valence may affect nanoparticle transport differently. We observed that the effects of cations on the transport of graphene oxide (GO) and sulfide-reduced GO (RGO) in saturated quartz sand obeyed the Hofmeister series; that is, transport-inhibition effects of alkali metal ions followed the order of Na + < K + < Cs + , and those of alkaline earth metal ions followed the order of Mg 2+ < Ca 2+ < Ba 2+ . With batch adsorption experiments and microscopic data, we verified that cations having large ionic radii (and thus being weakly hydrated) interacted with quartz sand and GO and RGO more strongly than did cations of small ionic radii. In particular, the monovalent Cs + and divalent Ca 2+ and Ba 2+ , which can form inner-sphere complexes, resulted in very significant deposition of GO and RGO via cation bridging between quartz sand and GO and RGO, and possibly via enhanced straining, due to the enhanced aggregation of GO and RGO from cation bridging. The existence of the Hofmeister effects was further corroborated with the interesting observation that cation bridging was more significant for RGO, which contained greater amounts of carboxyl and phenolic groups (i.e., metal-complexing moieties) than did GO. The findings further demonstrate that transport of nanoparticles is controlled by the complex interplay between nanoparticle surface functionalities and solution chemistry constituents.
Medication Waste Reduction in Pediatric Pharmacy Batch Processes

PubMed Central

Veltri, Michael A.; Hamrock, Eric; Mollenkopf, Nicole L.; Holt, Kristen; Levin, Scott

2014-01-01

OBJECTIVES: To inform pediatric cart-fill batch scheduling for reductions in pharmaceutical waste using a case study and simulation analysis. METHODS: A pre and post intervention and simulation analysis was conducted during 3 months at a 205-bed children's center. An algorithm was developed to detect wasted medication based on time-stamped computerized provider order entry information. The algorithm was used to quantify pharmaceutical waste and associated costs for both preintervention (1 batch per day) and postintervention (3 batches per day) schedules. Further, simulation was used to systematically test 108 batch schedules outlining general characteristics that have an impact on the likelihood for waste. RESULTS: Switching from a 1-batch-per-day to a 3-batch-per-day schedule resulted in a 31.3% decrease in pharmaceutical waste (28.7% to 19.7%) and annual cost savings of $183,380. Simulation results demonstrate how increasing batch frequency facilitates a more just-in-time process that reduces waste. The most substantial gains are realized by shifting from a schedule of 1 batch per day to at least 2 batches per day. The simulation exhibits how waste reduction is also achievable by avoiding batch preparation during daily time periods where medication administration or medication discontinuations are frequent. Last, the simulation was used to show how reducing batch preparation time per batch provides some, albeit minimal, opportunity to decrease waste. CONCLUSIONS: The case study and simulation analysis demonstrate characteristics of batch scheduling that may support pediatric pharmacy managers in redesign toward minimizing pharmaceutical waste. PMID:25024671
Medication waste reduction in pediatric pharmacy batch processes.

PubMed

Toerper, Matthew F; Veltri, Michael A; Hamrock, Eric; Mollenkopf, Nicole L; Holt, Kristen; Levin, Scott

2014-04-01

To inform pediatric cart-fill batch scheduling for reductions in pharmaceutical waste using a case study and simulation analysis. A pre and post intervention and simulation analysis was conducted during 3 months at a 205-bed children's center. An algorithm was developed to detect wasted medication based on time-stamped computerized provider order entry information. The algorithm was used to quantify pharmaceutical waste and associated costs for both preintervention (1 batch per day) and postintervention (3 batches per day) schedules. Further, simulation was used to systematically test 108 batch schedules outlining general characteristics that have an impact on the likelihood for waste. Switching from a 1-batch-per-day to a 3-batch-per-day schedule resulted in a 31.3% decrease in pharmaceutical waste (28.7% to 19.7%) and annual cost savings of $183,380. Simulation results demonstrate how increasing batch frequency facilitates a more just-in-time process that reduces waste. The most substantial gains are realized by shifting from a schedule of 1 batch per day to at least 2 batches per day. The simulation exhibits how waste reduction is also achievable by avoiding batch preparation during daily time periods where medication administration or medication discontinuations are frequent. Last, the simulation was used to show how reducing batch preparation time per batch provides some, albeit minimal, opportunity to decrease waste. The case study and simulation analysis demonstrate characteristics of batch scheduling that may support pediatric pharmacy managers in redesign toward minimizing pharmaceutical waste.

Inhibition of iron (III) minerals and acidification on the reductive dechlorination of trichloroethylene.

PubMed

Paul, Laiby; Smolders, Erik

2014-09-01

Reductive dechlorination of chlorinated ethenes is inhibited by acidification and by the presence of Fe (III) as a competitive electron acceptor. Synergism between both factors on dechlorination is predicted as reductive dissolution of Fe (III) minerals is facilitated by acidification. This study was set-up to assess this synergism for two common aquifer Fe (III) minerals, goethite and ferrihydrite. Anaerobic microbial dechlorination of trichloroethylene (TCE) by KB-1 culture and formate as electron donor was investigated in anaerobic batch containers at different solution pH values (6.2-7.2) in sand coated with these Fe minerals and a sand only as control. In the absence of Fe, lowering substrate pH from 7.2 to 6.2 increased the time for 90% TCE degradation from 14±1d to 42±4d. At pH 7.2, goethite did not affect TCE degradation time while ferrihydrite increased the degradation time to 19±1d compared to the no Fe control. At pH 6.2, 90% degradation was at 78±1 (ferrihydrite) or 131±1d (goethite). Ferrous iron production in ferrihydrite treatment increased between pH 7.2 and 6.5 but decreased by further lowering pH to 6.2, likely due to reduced microbial activity. This study confirms that TCE is increasingly inhibited by the combined effect of acidification and bioavailable Fe (III), however no evidence was found for synergistic inhibition since Fe reduction did not increase as pH decreases. To the best of our knowledge, this is the first study where effect of pH and Fe (III) reduction on TCE was simultaneously tested. Acid Fe-rich aquifers need sufficient buffering and alkalinity to ensure swift degradation of chlorinated ethenes. Copyright © 2014. Published by Elsevier Ltd.
Materials Test Laboratory activities at the NASA-Johnson Space Center White Sands Test Facility (WSTF)

NASA Technical Reports Server (NTRS)

Stradling, J.; Pippen, D. L.

1985-01-01

The NASA Johnson Space Center White Sands Test Facility (WSTF) performs aerospace materials testing and evaluation. Established in 1963, the facility grew from a NASA site dedicated to the development of space engines for the Apollo project to a major test facility. In addition to propulsion tests, it tests materials and components, aerospace fluids, and metals and alloys in simulated space environments.
Microbial strengthening of loose sand.

PubMed

Banagan, B L; Wertheim, B M; Roth, M J S; Caslake, L F

2010-08-01

To test whether the addition of Flavobacterium johnsoniae could increase the strength of saturated Ottawa 30 sand. A box model was built that simulates groundwater-like flow through a main sand compartment. Strength tests were performed at seven locations and at two depths, 10.8 and 20.3 cm below the top of the tank, using a vane shear device before and after the addition of bacteria. After the addition of Fl. johnsoniae, sand samples were obtained from multiple sampling ports on the vertical sides of the box model. The presence of a bacterial biofilm was confirmed by staining these sand samples with SYTO-9 and Alexa Fluor 633 and viewing with a confocal microscope. The average shear strength increases after the addition of Fl. johnsoniae were 15.2-87.5%, depending on the experimental conditions. Flavobacterium johnsoniae caused a statistically significant increase in the strength of saturated Ottawa 30 sand. Biofilm-forming bacteria can increase the shear strength of saturated sand. The addition of biofilm-forming bacteria to a building site may be an alternate method to mitigate the effects of liquefaction.
Liquefaction sites, Imperial Valley, California.

USGS Publications Warehouse

Youd, T.L.; Bennett, M.J.

1983-01-01

Sands that did and did not liquefy at two sites during the 1979 Imperial Valley, Calif., earthquake (ML = 6.6) are identified and their properties evaluated. SPT tests were used to evaluate liquefaction susceptibility. Loose fine sands in an abandoned channel liquefied and produced sand boils, ground fissures, and a lateral spread at the Heber Road sites. Evidence of liquefaction was not observed over moderately dense over-bank sand east of the channel nor over dense point-bar sand to the west. -from ASCE Publications Information
Pilot- and bench-scale testing of faecal indicator bacteria survival in marine beach sand near point sources

USGS Publications Warehouse

Mika, K.B.; Imamura, G.; Chang, C.; Conway, V.; Fernandez, G.; Griffith, J.F.; Kampalath, R.A.; Lee, C.M.; Lin, C.-C.; Moreno, R.; Thompson, S.; Whitman, R.L.; Jay, J.A.

2009-01-01

Aim: Factors affecting faecal indicator bacteria (FIB) and pathogen survival/persistence in sand remain largely unstudied. This work elucidates how biological and physical factors affect die-off in beach sand following sewage spills. Methods and Results: Solar disinfection with mechanical mixing was pilot-tested as a disinfection procedure after a large sewage spill in Los Angeles. Effects of solar exposure, mechanical mixing, predation and/or competition, season, and moisture were tested at bench scale. First-order decay constants for Escherichia coli ranged between -0??23 and -1??02 per day, and for enterococci between -0??5 and -1??0 per day. Desiccation was a dominant factor for E. coli but not enterococci inactivation. Effects of season were investigated through a comparison of experimental results from winter, spring, and fall. Conclusions: Moisture was the dominant factor controlling E. coli inactivation kinetics. Initial microbial community and sand temperature were also important factors. Mechanical mixing, common in beach grooming, did not consistently reduce bacterial levels. Significance and Impact of the Study: Inactivation rates are mainly dependent on moisture and high sand temperature. Chlorination was an effective disinfection treatment in sand microcosms inoculated with raw influent. ?? 2009 The Society for Applied Microbiology.
Sand effects on thermal barrier coatings for gas turbine engines

NASA Astrophysics Data System (ADS)

Walock, Michael; Barnett, Blake; Ghoshal, Anindya; Murugan, Muthuvel; Swab, Jeffrey; Pepi, Marc; Hopkins, David; Gazonas, George; Kerner, Kevin

Accumulation and infiltration of molten/ semi-molten sand and subsequent formation of calcia-magnesia-alumina-silicate (CMAS) deposits in gas turbine engines continues to be a significant problem for aviation assets. This complex problem is compounded by the large variations in the composition, size, and topology of natural sands, gas generator turbine temperatures, thermal barrier coating properties, and the incoming particulate's momentum. In order to simplify the materials testing process, significant time and resources have been spent in the development of synthetic sand mixtures. However, there is debate whether these mixtures accurately mimic the damage observed in field-returned engines. With this study, we provide a direct comparison of CMAS deposits from both natural and synthetic sands. Using spray deposition techniques, 7% yttria-stabilized zirconia coatings are deposited onto bond-coated, Ni-superalloy discs. Each sample is coated with a sand slurry, either natural or synthetic, and exposed to a high temperature flame for 1 hour. Test samples are characterized before and after flame exposure. In addition, the test samples will be compared to field-returned equipment. This research was sponsored by the US Army Research Laboratory, and was accomplished under Cooperative Agreement # W911NF-12-2-0019.
Comparison of heavy metal toxicity in continuous flow and batch reactors

NASA Astrophysics Data System (ADS)

Sengor, S. S.; Gikas, P.; Moberly, J. G.; Peyton, B. M.; Ginn, T. R.

2009-12-01

The presence of heavy metals may significantly affect microbial growth. In many cases, small amounts of particular heavy metals may stimulate microbial growth; however, larger quantities may result in microbial growth reduction. Environmental parameters, such as growth pattern may alter the critical heavy metal concentration, above which microbial growth stimulation turns to growth inhibition. Thus, it is important to quantify the effects of heavy metals on microbial activity for understanding natural or manmade biological reactors, either in situ or ex situ. Here we compare the toxicity of Zn and Cu on Arthrobacter sp., a heavy metal tolerant microorganism, under continuous flow versus batch reactor operations. Batch and continuous growth tests of Arthrobacter sp. were carried out at various individual and combined concentrations of Zn and Cu. Biomass concentration (OD) was measured for both the batch and continuous reactors, whereas ATP, oxygen uptake rates and substrate concentrations were additionally measured for the continuous system. Results indicated that Cu was more toxic than Zn under all conditions for both systems. In batch reactors, all tested Zn concentrations up to 150 uM showed a stimulatory effect on microbial growth. However, in the case of mixed Zn and Cu exposures, the presence of Zn either eliminated (at the 50 uM level both Zn and Cu) or reduced by ~25% (at the 100 and 150 uM levels both Zn and Cu) the Cu-induced inhibition. In the continuous system, only one test involved combined Cu (40uM) and Zn (125uM) and this test showed similar results to the 40uM Cu continuous test, i.e., no reduction in inhibition. The specific ATP concentration, i.e., ATP/OD, results for the continuous reactor showed an apparent recovery for both Cu-treated populations, although neither the OD nor glucose data showed any recovery. This may reflect that the individual microorganisms that survived after the addition of heavy metals, kept maintaining the usual ATP levels, as before metal addition. The last may imply a short of adaptation by some microorganisms to the presence of heavy metals. Overall, the batch reactor tests underestimated significantly the heavy metal inhibition, as compared to the continuous flow reactors. Therefore, the results of batch reactor tests should be used with some caution when heavy metal inhibition is to be interpreted for continuous flow natural environmental systems, such as rivers or wetlands.
Investigation of vinegar production using a novel shaken repeated batch culture system.

PubMed

Schlepütz, Tino; Büchs, Jochen

2013-01-01

Nowadays, bioprocesses are developed or optimized on small scale. Also, vinegar industry is motivated to reinvestigate the established repeated batch fermentation process. As yet, there is no small-scale culture system for optimizing fermentation conditions for repeated batch bioprocesses. Thus, the aim of this study is to propose a new shaken culture system for parallel repeated batch vinegar fermentation. A new operation mode - the flushing repeated batch - was developed. Parallel repeated batch vinegar production could be established in shaken overflow vessels in a completely automated operation with only one pump per vessel. This flushing repeated batch was first theoretically investigated and then empirically tested. The ethanol concentration was online monitored during repeated batch fermentation by semiconductor gas sensors. It was shown that the switch from one ethanol substrate quality to different ethanol substrate qualities resulted in prolonged lag phases and durations of the first batches. In the subsequent batches the length of the fermentations decreased considerably. This decrease in the respective lag phases indicates an adaptation of the acetic acid bacteria mixed culture to the specific ethanol substrate quality. Consequently, flushing repeated batch fermentations on small scale are valuable for screening fermentation conditions and, thereby, improving industrial-scale bioprocesses such as vinegar production in terms of process robustness, stability, and productivity. Copyright © 2013 American Institute of Chemical Engineers.
51. 500,000 POUND STATIC TEST FACILITY: CLOSEUP VIEW FROM EAST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

51. 500,000 POUND STATIC TEST FACILITY: CLOSE-UP VIEW FROM EAST SHOWING MOVABLE OBSERVATION MIRRORS WITH TRACKS - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Microtox(TM) characterization of foundry sand residuals

USGS Publications Warehouse

Bastian, K.C.; Alleman, J.E.

1998-01-01

Although foundry residuals, consisting mostly of waste Sands, represent a potentially attractive, high-volume resource for beneficial reuse applications (e.g. highway embankment construction), prospective end users are understandably concerned about unforeseen liabilities stemming from the use of these residuals. This paper, therefore, focuses on the innovative use of a microbial bioassay as a means of developing a characterization of environmental suitability extending beyond the analytical coverage already provided by mandated chemical-specific tests (i.e., TCLP, etc.). Microtox(TM) bioassays were conducted on leachates derived from residuals obtained at a wide range of facilities, including: 11 gray and ductile iron foundries plus one each steel and aluminum foundries. In addition, virgin sand samples were used to establish a relative 'natural' benchmark against which the waste foundry sands could then be compared in terms of their apparent quality. These bioassay tests were able to effectively 'fingerprint' those residuals whose bioassay behavior was comparable to that of virgin materials. In fact, the majority of gray and ductile iron foundry residuals tested during this reported study elicited Microtox(TM) response levels which fell within or below the virgin sand response range, consequently providing another quantifiable layer of Support for this industry's claim that their sands are 'cleaner than dirt.' However, negative Microtox(TM) responses beyond that of the virgin sands were observed with a number of foundry samples (i.e. four of the 11 gray or ductile iron sands plus both non-iron sands). Therefore, the latter results would suggest that these latter residuals be excluded from beneficial reuse for the immediate future, at least until the cause and nature of this negative response has been further identified.
Adsorption of mixtures of nutrients and heavy metals in simulated urban stormwater by different filter materials.

PubMed

Reddy, Krishna R; Xie, Tao; Dastgheibi, Sara

2014-01-01

In recent years, several best management practices have been developed for the removal of different types of pollutants from stormwater runoff that lead to effective stormwater management. Filter materials that remove a wide range of contaminants have great potential for extensive use in filtration systems. In this study, four filter materials (calcite, zeolite, sand, and iron filings) were investigated for their adsorption and efficiency in the removal of nutrients and heavy metals when they exist individually versus when they co-exist. Laboratory batch experiments were conducted separately under individual and mixed contaminants conditions at different initial concentrations. Adsorption capacities varied under the individual and mixed contaminant conditions due to different removal mechanisms. Most filter materials showed lower removal efficiency under mixed contaminant conditions. In general, iron filings were found effective in the removal of nutrients and heavy metals simultaneously to the maximum levels. Freundlich and Langmuir isotherms were used to model the batch adsorption results and the former better fitted the experimental results. Overall, the results indicate that the filter materials used in this study have the potential to be effective media for the treatment of nutrients and heavy metals commonly found in urban stormwater runoff.
Laboratory studies of dune sand for the use of construction industry in Sri Lanka

NASA Astrophysics Data System (ADS)

de Silva Jayawardena, Upali; Wijesuriya, Roshan; Abayaweera, Gayan; Viduranga, Tharaka

2015-04-01

With the increase of the annual sand demand for the construction industry the excessive excavation of river sand is becoming a serious environmental problem in Sri Lanka. Therefore, it is necessary to explore the possibility for an alternative to stop or at least to minimize river sand mining activities. Dune sand is one of the available alternative materials to be considered instead of river sand in the country. Large quantities of sand dunes occur mainly along the NW and SE coastal belt which belong to very low rainfall Dry Zone coasts. The height of dune deposits, vary from 1m to about 30 meters above sea level. The objective of this paper is to indicate some studies and facts on the dune sand deposits of Sri Lanka. Laboratory studies were carried out for visual observations and physical properties at the initial stage and then a number of tests were carried out according to ASTM standards to obtain the compressive strength of concrete cylinders and mortar cubes mixing dune sand and river sand in different percentages keeping a constant water cement ratio. Next the water cement ratio was changed for constant dune sand and river sand proportion. Microscopic analysis shows that the dune sand consist of 95 % of quartz and 5 % of garnet, feldspar, illmenite and other heavy minerals with clay, fine dust, fine shell fragments and organic matters. Grains are sub-rounded to angular and tabular shapes. The grain sizes vary from fine to medium size of sand with silt. The degree of sorting and particle size observed with dune sands are more suited with the requirement of fine aggregates in the construction industry. The test result indicates that dune sand could be effectively used in construction work without sieving and it is ideal for wall plastering due to its'-uniformity. It could also be effectively used in concrete and in mortars mixing with river sand. The best mixing ratio is 75% dune sand and 25% river sand as the fine aggregate of concrete. For mortar the mixing percentage is 50%. The best water cement ratio for mix proportion is 0.45. It was observed that the available amount of dune sand can be extracted to meet the demand for sand in construction industry. However, the extraction of dune sand from the areas close to the sea will cause several social, environmental and legal problems. Therefore sand mining from dunes must be commenced after making a detailed Environmental Impact Assessment.
Observations of transport of bacterial-like microspheres through beach sand

NASA Astrophysics Data System (ADS)

Gast, Rebecca J.; Elgar, Steve; Raubenheimer, Britt

2015-04-01

Often, there is an order of magnitude more fecal indicator bacteria (enterococci) in beach sand than in nearby water. Consequently, sand is considered a reservoir for these bacteria, potentially contributing to poor water quality, and raising questions regarding the human health risks associated with sand exposure. An integral aspect of the distribution and persistence of sand-associated enterococci is the transport of bacteria introduced into the beach environment. Here, plastic microspheres are used as a proxy to examine the wave-induced movement of bacterial-like particles through sand on an ocean beach. Laboratory tests suggest microspheres and bacteria move similarly through sand columns, and have qualitatively similar short-term adsorption-to-sand behavior. Microspheres buried ~0.05 m below the sand surface on an ocean beach moved rapidly [O(10-3) m/s] away from their initial location, both vertically into the ground water below the sand and horizontally seaward within the sediment matrix in response to waves running up the beach face and percolating through the sand.
Prenatal exposure to sand and dust storms and children's cognitive function in China: a quasi-experimental study.

PubMed

Li, Zhihui; Chen, Lincoln; Li, Mingqiang; Cohen, Jessica

2018-05-01

While there is evidence that sand and dust storms can have adverse health effects, the effects of such storms on children's cognitive function has not been explored. We examined whether prenatal exposure to sand and dust storms affects children's cognitive function and, if so, whether harmful effects of sand and dust storms vary by the trimester of exposure. This study used nationally representative data from the China Family Panel Studies between 2010 and 2014 and data on sand and dust storms from the national Sand and Dust Weather Almanac. We selected four indicators of children's cognitive function: mathematics test scores, word-recognition test scores, the age the child began speaking in whole sentences, and the age the child began counting from one to ten. Since the annual incidence of sand and dust storms is highly variable and is largely unpredictable, we used a region-and-year fixed-effect model to compare the cognitive function of children born in the same region and year but with varying amounts of prenatal exposure to sand and dust storms. We also investigated whether the effect of sand and dust storms varied by the specific month of prenatal exposure. We included 1236 observations for the analysis of mathematics and word-recognition test scores, 2693 observations in the analysis of the age the child began speaking in whole sentences, and 1951 observations for the analysis of the age the child began counting from one to ten. Every 10 additional days of prenatal exposure to sand and dust storms was associated with a 0·20 SD (95% CI 0·06 to 0·35, p=0·009) reduction in word test scores, 0·04 (-0·00 to 0·09, p=0·089) additional months to begin speaking in sentences, and 0·14 (0·03 to 0·25, p=0·021) additional months to begin counting, but was not significantly associated with mathematics test scores (reduction of 0·02 SD, -0·19 to 0·15). 10 additional days of prenatal exposure to sand and dust storms in the seventh gestational month was associated with a 0·18 SD (0·10 to 0·25) reduction in mathematics test scores, a 0·34 SD (0·18 to 0·50) reduction in word test scores, an additional 0·33 months (0·07 to 0·59) to begin speaking in sentences, and an additional 0·20 months (0·04 to 0·35) to begin counting. Our results suggest that protecting pregnant women from the effects of sand and dust storms in the critical periods of fetal brain development could generate benefits for the cognitive function of the next generation. None. Copyright © 2018 The Author(s). Published by Elsevier Ltd. This is an Open Access article under the CC BY 4.0 license. Published by Elsevier Ltd.. All rights reserved.
A combined CFD-experimental method for developing an erosion equation for both gas-sand and liquid-sand flows

NASA Astrophysics Data System (ADS)

Mansouri, Amir

The surface degradation of equipment due to consecutive impacts of abrasive particles carried by fluid flow is called solid particle erosion. Solid particle erosion occurs in many industries including oil and gas. In order to prevent abrupt failures and costly repairs, it is essential to predict the erosion rate and identify the locations of the equipment that are mostly at risk. Computational Fluid Dynamics (CFD) is a powerful tool for predicting the erosion rate. Erosion prediction using CFD analysis includes three steps: (1) obtaining flow solution, (2) particle tracking and calculating the particle impact speed and angle, and (3) relating the particle impact information to mass loss of material through an erosion equation. Erosion equations are commonly generated using dry impingement jet tests (sand-air), since the particle impact speed and angle are assumed not to deviate from conditions in the jet. However, in slurry flows, a wide range of particle impact speeds and angles are produced in a single slurry jet test with liquid and sand particles. In this study, a novel and combined CFD/experimental method for developing an erosion equation in slurry flows is presented. In this method, a CFD analysis is used to characterize the particle impact speed, angle, and impact rate at specific locations on the test sample. Then, the particle impact data are related to the measured erosion depth to achieve an erosion equation from submerged testing. Traditionally, it was assumed that the erosion equation developed based on gas testing can be used for both gas-sand and liquid-sand flows. The erosion equations developed in this work were implemented in a CFD code, and CFD predictions were validated for various test conditions. It was shown that the erosion equation developed based on slurry tests can significantly improve the local thickness loss prediction in slurry flows. Finally, a generalized erosion equation is proposed which can be used to predict the erosion rate in gas-sand, water-sand and viscous liquid-sand flows with high accuracy. Furthermore, in order to gain a better understanding of the erosion mechanism, a comprehensive experimental study was conducted to investigate the important factors influencing the erosion rate in gas-sand and slurry flows. The wear pattern and total erosion ratio were measured in a direct impingement jet geometry (for both dry impact and submerged impingement jets). The effects of fluid viscosity, abrasive particle size, particle impact speed, jet inclination angle, standoff distance, sand concentration, and exposure time were investigated. Also, the eroded samples were studied with Scanning Electron Microscopy (SEM) to understand the erosion micro-structure. Also, the sand particle impact speed and angle were measured using a Particle Image Velocimetry (PIV) system. The measurements were conducted in two types of erosion testers (gas-solid and liquid-solid impinging jets). The Particle Tracking Velocimetry (PTV) technique was utilized which is capable of tracking individual small particles. Moreover, CFD modeling was performed to predict the particle impact data. Very good agreement between the CFD results and PTV measurements was observed.
Experimental investigation on high performance RC column with manufactured sand and silica fume

NASA Astrophysics Data System (ADS)

Shanmuga Priya, T.

2017-11-01

In recent years, the use High Performance Concrete (HPC) has increased in construction industry. The ingredients of HPC depend on the availability and characteristics of suitable alternative materials. Those alternative materials are silica fume and manufactured sand, a by products from ferro silicon and quarry industries respectively. HPC made with silica fume as partial replacement of cement and manufactured sand as replacement of natural sand is considered as sustainable high performance concrete. In this present study the concrete was designed to get target strength of 60 MPa as per guide lines given by ACI 211- 4R (2008). The laboratory study was carried out experimentally to analyse the axial behavior of reinforced cement HPC column of size 100×100×1000mm and square in cross section. 10% of silica fume was preferred over ordinary portland cement. The natural sand was replaced by 0, 20, 40, 60, 80 and 100% with Manufactured Sand (M-Sand). In this investigation, totally 6 column specimens were cast for mixes M1 to M6 and were tested in 1000kN loading frame at 28 days. From this, Load-Mid height deflection curves were drawn and compared. Maximum ultimate load carrying capacity and the least deflection is obtained for the mix prepared by partial replacement of cement with 10% silica fume & natural sand by 100% M-Sand. The fine, amorphous and pozzalonic nature of silica fume and fine mineral particles in M- Sand increased the stiffness of HPC column. The test results revealed that HPC can be produced by using M-Sand with silica fume.
Electric conductivity for laboratory and field monitoring of induced partial saturation (IPS) in sands

NASA Astrophysics Data System (ADS)

Kazemiroodsari, Hadi

Liquefaction is loss of shear strength in fully saturated loose sands caused by build-up of excess pore water pressure, during moderate to large earthquakes, leading to catastrophic failures of structures. Currently used liquefaction mitigation measures are often costly and cannot be applied at sites with existing structures. An innovative, practical, and cost effective liquefaction mitigation technique titled "Induced Partial Saturation" (IPS) was developed by researchers at Northeastern University. The IPS technique is based on injection of sodium percarbonate solution into fully saturated liquefaction susceptible sand. Sodium percarbonate dissolves in water and breaks down into sodium and carbonate ions and hydrogen peroxide which generates oxygen gas bubbles. Oxygen gas bubbles become trapped in sand pores and therefore decrease the degree of saturation of the sand, increase the compressibility of the soil, thus reduce its potential for liquefaction. The implementation of IPS required the development and validation of a monitoring and evaluation technique that would help ensure that the sands are indeed partially saturated. This dissertation focuses on this aspect of the IPS research. The monitoring system developed was based on using electric conductivity fundamentals and probes to detect the transport of chemical solution, calculate degree of saturation of sand, and determine the final zone of partial saturation created by IPS. To understand the fundamentals of electric conductivity, laboratory bench-top tests were conducted using electric conductivity probes and small specimens of Ottawa sand. Bench-top tests were used to study rate of generation of gas bubbles due to reaction of sodium percarbonate solution in sand, and to confirm a theory based on which degree of saturation were calculated. In addition to bench-top tests, electric conductivity probes were used in a relatively large sand specimen prepared in a specially manufactured glass tank. IPS was implemented in the prepared specimen to validate the numerical simulation model and explore the use of conductivity probes to detect the transport of chemical solution, estimate degree of saturation achieved due to injection of chemical solution, and evaluate final zone of partial saturation. The conductivity probe and the simulation results agreed well. To study the effect of IPS on liquefaction response of the sand specimen, IPS was implemented in a large (2-story high) sand specimen prepared in the laminar box of NEES Buffalo and then the specimen was subjected to harmonic shaking. Electric conductivity probes were used in the specimen treatment by controlling the duration and spacing of injection of the chemical solution, in monitoring the transport of chemical solution, in the estimation of zone of partial saturation achieved, and in the estimation of degree of saturation achieved due to implementation of IPS. The conductivity probes indicated partial saturation of the specimen. The shaking tests results confirmed the partial saturation state of the sand specimen. In addition, to the laboratory works, electric conductivity probes were used in field implementation of IPS in a pilot test at the Wildlife Liquefaction Array (WLA) of NEES UCSB site. The conductivity probes in the field test helped decide the optimum injection pressure, the injection tube spacing, and the degree of saturation that could be achieved in the field. The various laboratory and field tests confirmed that electric conductivity and the probes devised and used can be invaluable in the implementation of IPS, by providing information regarding transport of the chemical solution, the spacing of injection tubes, duration of injection, and the zone and degree of partial saturation caused by IPS.
Vehicle Test Facilities at Aberdeen Test Center and Yuma Test Center

DTIC Science & Technology

2012-02-27

boulders, concrete, steel 30.5 m 100 ft Corrosion Facility 27 Various corrosive environments NA NA Abrasive Mud Course 28 Sand loam 73 x 290 m 240 x...950 ft Fording Basin 30 Concrete 82 m 270 ft Underwater Fording Facility 31 Concrete 96 m 315 ft Amphibian Ramp 31 Bituminous concrete 6 x 15 m...Courses Fording Basin 97 Concrete (L x W) 67 x 25 m 220 x 82 ft Kofa Dust Course 98 Sand, Dust 3.2 km 2.0 mi Cibola Dust Course 99 Sand, Dust 6.3 km 3.9
Comprehensive clone screening and evaluation of fed-batch strategies in a microbioreactor and lab scale stirred tank bioreactor system: application on Pichia pastoris producing Rhizopus oryzae lipase

PubMed Central

2014-01-01

Background In Pichia pastoris bioprocess engineering, classic approaches for clone selection and bioprocess optimization at small/micro scale using the promoter of the alcohol oxidase 1 gene (PAOX1), induced by methanol, present low reproducibility leading to high time and resource consumption. Results An automated microfermentation platform (RoboLector) was successfully tested to overcome the chronic problems of clone selection and optimization of fed-batch strategies. Different clones from Mut+P. pastoris phenotype strains expressing heterologous Rhizopus oryzae lipase (ROL), including a subset also overexpressing the transcription factor HAC1, were tested to select the most promising clones. The RoboLector showed high performance for the selection and optimization of cultivation media with minimal cost and time. Syn6 medium was better than conventional YNB medium in terms of production of heterologous protein. The RoboLector microbioreactor was also tested for different fed-batch strategies with three clones producing different lipase levels. Two mixed substrates fed-batch strategies were evaluated. The first strategy was the enzymatic release of glucose from a soluble glucose polymer by a glucosidase, and methanol addition every 24 hours. The second strategy used glycerol as co-substrate jointly with methanol at two different feeding rates. The implementation of these simple fed-batch strategies increased the levels of lipolytic activity 80-fold compared to classical batch strategies used in clone selection. Thus, these strategies minimize the risk of errors in the clone selection and increase the detection level of the desired product. Finally, the performance of two fed-batch strategies was compared for lipase production between the RoboLector microbioreactor and 5 liter stirred tank bioreactor for three selected clones. In both scales, the same clone ranking was achieved. Conclusion The RoboLector showed excellent performance in clone selection of P. pastoris Mut+ phenotype. The use of fed-batch strategies using mixed substrate feeds resulted in increased biomass and lipolytic activity. The automated processing of fed-batch strategies by the RoboLector considerably facilitates the operation of fermentation processes, while reducing error-prone clone selection by increasing product titers. The scale-up from microbioreactor to lab scale stirred tank bioreactor showed an excellent correlation, validating the use of microbioreactor as a powerful tool for evaluating fed-batch operational strategies. PMID:24606982
Removal of Cesium From Acidic Radioactive Tank Waste Using IONSIV IE-911 (CST)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mann, Nicholas Robert; Todd, Terry Allen

2004-10-01

IONSIV IE-911, or the engineered form of crystalline silicotitanate (CST), manufactured by UOP Molecular Sieves, has been evaluated for the removal of cesium from Idaho National Engineering and Environmental Laboratory (INEEL) acidic radioactive tank waste. A series of batch contacts and column tests were performed by using three separate batches of CST. Batch contacts were performed to evaluate the concentration effects of nitric acid, sodium, and potassium ions on cesium sorption. Additional batch tests were performed to determine if americium, mercury, and plutonium would sorb onto IONSIV IE-911. An equilibrium isotherm was generated by using a concentrated tank waste simulant.more » Column tests using a 1.5 cm 3 column and flow rates of 3, 5, 10, 20, and 30 bed volumes (BV)/hr were performed to elucidate dynamic cesium sorption capacities and sorption kinetics. Additional experiments investigated the effect of CST batch and pretreatment on cesium sorption. The thermal stability of IONSIV IE-911 was evaluated by performing thermal gravimetric analysis/differential thermal analysis. Overall, IONSIV IE-911 was shown to be effective for cesium sorption from complex, highly acidic solutions; however, sorbent stability in these solutions may have a deleterious effect on cesium sorption.« less

Influence of solid-liquid separation method parameters employed in soil leaching tests on apparent metal concentration.

PubMed

Imoto, Yukari; Yasutaka, Tetsuo; Someya, Masayuki; Higashino, Kazuo

2018-05-15

Soil leaching tests are commonly used to evaluate the leachability of hazardous materials, such as heavy metals, from the soil. Batch leaching tests often enhance soil colloidal mobility and may require solid-liquid separation procedures to remove excess soil particles. However, batch leaching test results depend on particles that can pass through a 0.45μm membrane filter and are influenced by test parameters such as centrifugal intensity and filtration volume per filter. To evaluate these parameters, we conducted batch leaching experiments using metal-contaminated soils and focused on the centrifugal intensity and filtration volume per filter used in solid-liquid separation methods currently employed in standard leaching tests. Our experiments showed that both centrifugal intensity and filtration volume per filter affected the reproducibility of batch leaching tests for some soil types. The results demonstrated that metal concentrations in the filtrates significantly differed according to the centrifugal intensity when it was 3000 g for 2h or less. Increased filtration volume per filter led to significant decreases in filtrate metal concentrations when filter cakes formed during filtration. Comparison of the filtration tests using 0.10 and 0.45μm membrane filters showed statistically significant differences in turbidity and metal concentration. These findings suggest that colloidal particles were not adequately removed from the extract and contributed substantially to the apparent metal concentrations in the leaching test of soil containing colloidal metals. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.
sts003-010-613

NASA Image and Video Library

2009-06-24

STS003-010-613 (22-30 March 1982) --- A truly remarkable view of White Sands and the nearby Carrizozo Lava Beds in southeast NM (33.5N, 106.5W). White Sands, site of the WW II atomic bomb development and testing facility and later post war nuclear weapons testing that can still be seen in the cleared circular patterns on the ground. Space shuttle Columbia (STS-3), this mission, landed at the White Sands alternate landing site because of bad weather at Edwards AFB, CA. Photo credit: NASA
Techno-economic evaluation of a tandem dry batch, garage-style digestion-compost process for remote work camp environments.

PubMed

Hayes, Alexander C; Enongene Ekwe, S; Mervin, Steve; Jenson, Earl

2016-12-01

The extraction of natural resources often involves housing workers in remote work camps far from population centres. These camps are prevalent in northern Alberta where they house approximately 40,000 workers involved in oil sands processing. The central, full-service cafeterias at these camps produce a significant quantity of food and cardboard waste. Due to their remote nature, these camps face high waste disposal costs associated with trucking waste long distances to the landfill. In this study, we investigated the techno-economic feasibility of on-site treatment of food and cardboard waste in a tandem dry batch, garage-style anaerobic digestion-compost process in which the waste material is converted into renewable energy used to heat the camp water supply and a nutrient-rich soil amendment for local land reclamation projects. Dry batch digestion and windrow composting pilot trials were performed on a simulated work camp waste in order to assess technical performance. The quality of the final compost was found to meet regulatory standards. A complete mass balance was then developed for a facility treating 3000 tonnes food waste and 435 tonnes waste cardboard annually. An economic assessment of such a facility was performed and, depending on the level of capital support and recognition of carbon credits for landfill methane mitigation, would require waste disposal costs to be between $115 and $195 CAD per tonne to meet financial criteria for project selection in Alberta's oil and gas industry. Copyright © 2016 Elsevier Ltd. All rights reserved.
Identification of TCE and PCE sorption and biodegradation parameters in a sandy aquifer for fate and transport modelling: batch and column studies.

PubMed

Kret, E; Kiecak, A; Malina, G; Nijenhuis, I; Postawa, A

2015-07-01

The main aim of this study was to determine the sorption and biodegradation parameters of trichloroethene (TCE) and tetrachloroethene (PCE) as input data required for their fate and transport modelling in a Quaternary sandy aquifer. Sorption was determined based on batch and column experiments, while biodegradation was investigated using the compound-specific isotope analysis (CSIA). The aquifer materials medium (soil 1) to fine (soil 2) sands and groundwater samples came from the representative profile of the contaminated site (south-east Poland). The sorption isotherms were approximately linear (TCE, soil 1, K d = 0.0016; PCE, soil 1, K d = 0.0051; PCE, soil 2, K d = 0.0069) except for one case in which the best fitting was for the Langmuir isotherm (TCE, soil 2, K f = 0.6493 and S max = 0.0145). The results indicate low retardation coefficients (R) of TCE and PCE; however, somewhat lower values were obtained in batch compared to column experiments. In the column experiments with the presence of both contaminants, TCE influenced sorption of PCE, so that the R values for both compounds were almost two times higher. Non-significant differences in isotope compositions of TCE and PCE measured in the observation points (δ(13)C values within the range of -23.6 ÷ -24.3‰ and -26.3 ÷-27.7‰, respectively) indicate that biodegradation apparently is not an important process contributing to the natural attenuation of these contaminants in the studied sandy aquifer.
Addressing case specific biogas plant tasks: industry oriented methane yields derived from 5L Automatic Methane Potential Test Systems in batch or semi-continuous tests using realistic inocula, substrate particle sizes and organic loading.

PubMed

Kolbl, Sabina; Paloczi, Attila; Panjan, Jože; Stres, Blaž

2014-02-01

The primary aim of the study was to develop and validate an in-house upscale of Automatic Methane Potential Test System II for studying real-time inocula and real-scale substrates in batch, codigestion and enzyme enhanced hydrolysis experiments, in addition to semi-continuous operation of the developed equipment and experiments testing inoculum functional quality. The successful upscale to 5L enabled comparison of different process configurations in shorter preparation times with acceptable accuracy and high-through put intended for industrial decision making. The adoption of the same scales, equipment and methodologies in batch and semi-continuous tests mirroring those at full scale biogas plants resulted in matching methane yields between the two laboratory tests and full-scale, confirming thus the increased decision making value of the approach for industrial operations. Copyright © 2013 Elsevier Ltd. All rights reserved.
Utilization of fly ash as partial sand replacement in oil palm shell lightweight aggregate concrete

NASA Astrophysics Data System (ADS)

Nazrin Akmal, A. Z. Muhammad; Muthusamy, K.; Mat Yahaya, F.; Hanafi, H. Mohd; Nur Azzimah, Z.

2017-11-01

Realization on the increasing demand for river sand supply in construction sector has inspired the current research to find alternative material to reduce the use of natural sand in oil palm shell lightweight aggregate concrete (OPS LWAC) production. The existence of fly ash, a by-product generated from coal power plant, which pose negative impact to the environment when it is disposed as waste, were used in this research. The effect of fly ash content as partial sand replacement towards workability and compressive strength of OPS lightweight aggregate concrete were investigated. Four concrete mixes containing various percentage of fly ash that are 0%, 10%, 20% and 30% by weight of sand were used in the experimental work. All mixes were cast in form of cubes before subjected to water curing until the testing age. Compressive strength test were conducted at 1, 3, 7 and 28 days. The finding shows that the workability of the OPS LWAC decreases when more fly ash are used as sand replacement. It was found that adding of 10% fly ash as sand replacement content resulted in better compressive strength of OPS LWAC, which is higher than the control mix.
Geology and hydrogeology of Naval Air Station Chase Field and Naval Auxiliary Landing Field Goliad, Bee and Goliad counties, Texas

USGS Publications Warehouse

Snyder, G.L.

1995-01-01

Large vertical hydraulic-head gradients are present between the unconfined Evangeline aquifer and confined Fleming aquifers at Naval Air Station Chase Field and Naval Auxiliary Landing Field Goliad. These gradients, together with the results of the aquifer test at Naval Air Station Chase Field and assumed characteristics of the confining units, indicate that downward flow of ground water probably occurs from the water-table aquifer to the underlying aquifers. The rate of downward flow between the two confined Fleming aquifers (from A-sand to B-sand) can be approximated using an estimate of vertical hydraulic conductivity of the intervening confining unit obtained from assumed storage characteristics and data from the aquifer test. Under the relatively high vertical hydraulic-head gradient induced by the aquifer test, ground-water movement from the A-sand aquifer to the B-sand aquifer could require about 490 years; and about 730 years under the natural gradient. Future increases in ground-water withdrawals from the B-sand aquifer might increase downward flow in the aquifer system of the study area.
Undrained behavior and shear strength of clean sand containing low-plastic fines

NASA Astrophysics Data System (ADS)

To-Anh Phan, Vu; Hsiao, Darn-Horng

2018-04-01

This study presents experimental tests to understand the undrained behavior of sand containing various fines contents. The specimens were prepared by the wet tamping method. The consolidated undrained triaxial shear tests were carried out by sands mixed with amounts of fines in ranging from 0 to 60%. The results showed that the deviator stress quickly reaches the peak value with an axial strain in a range of 0.5 to 2%, and then, the value drops significantly with further increases in the axial strain, the pore water pressure of all the sand-fines mixtures rapidly increases as the axial strain reaches a value in a range from 1 to 2% and then slowly increases and reaches a stable state when strain is greater than 8%. Peak deviator stress gradually decreases with an increasing fines content from 0 to 40%, thereafter, the peak deviator significantly increases with further increases in the fines content up to 60%, irrespective of confining pressure values using in these tests. Finally, the effective internal friction angles are remarkably greater than the total friction angles for various sand-fines mixtures.
Suitability of river delta sediment as proppant, Missouri and Niobrara Rivers, Nebraska and South Dakota, 2015

USGS Publications Warehouse

Zelt, Ronald B.; Hobza, Christopher M.; Burton, Bethany L.; Schaepe, Nathaniel J.; Piatak, Nadine

2017-11-16

Sediment management is a challenge faced by reservoir managers who have several potential options, including dredging, for mitigation of storage capacity lost to sedimentation. As sediment is removed from reservoir storage, potential use of the sediment for socioeconomic or ecological benefit could potentially defray some costs of its removal. Rivers that transport a sandy sediment load will deposit the sand load along a reservoir-headwaters reach where the current of the river slackens progressively as its bed approaches and then descends below the reservoir water level. Given a rare combination of factors, a reservoir deposit of alluvial sand has potential to be suitable for use as proppant for hydraulic fracturing in unconventional oil and gas development. In 2015, the U.S. Geological Survey began a program of researching potential sources of proppant sand from reservoirs, with an initial focus on the Missouri River subbasins that receive sand loads from the Nebraska Sand Hills. This report documents the methods and results of assessments of the suitability of river delta sediment as proppant for a pilot study area in the delta headwaters of Lewis and Clark Lake, Nebraska and South Dakota. Results from surface-geophysical surveys of electrical resistivity guided borings to collect 3.7-meter long cores at 25 sites on delta sandbars using the direct-push method to recover duplicate, 3.8-centimeter-diameter cores in April 2015. In addition, the U.S. Geological Survey collected samples of upstream sand sources in the lower Niobrara River valley.At the laboratory, samples were dried, weighed, washed, dried, and weighed again. Exploratory analysis of natural sand for determining its suitability as a proppant involved application of a modified subset of the standard protocols known as American Petroleum Institute (API) Recommended Practice (RP) 19C. The RP19C methods were not intended for exploration-stage evaluation of raw materials. Results for the washed samples are not directly applicable to evaluations of suitability for use as fracture sand because, except for particle-size distribution, the API-recommended practices for assessing proppant properties (sphericity, roundness, bulk density, and crush resistance) require testing of specific proppant size classes. An optical imaging particle-size analyzer was used to make measurements of particle-size distribution and particle shape. Measured samples were sieved to separate the dominant-size fraction, and the separated subsample was further tested for roundness, sphericity, bulk density, and crush resistance.For the bulk washed samples collected from the Missouri River delta, the geometric mean size averaged 0.27 millimeters (mm), 80 percent of the samples were predominantly sand in the API 40/70 size class, and 17 percent were predominantly sand in the API 70/140 size class. Distributions of geometric mean size among the four sandbar complexes were similar, but samples collected from sandbar complex B were slightly coarser sand than those from the other three complexes. The average geometric mean sizes among the four sandbar complexes ranged only from 0.26 to 0.30 mm. For 22 main-stem sampling locations along the lower Niobrara River, geometric mean size averaged 0.26 mm, an average of 61 percent was sand in the API 40/70 size class, and 28 percent was sand in the API 70/140 size class. Average composition for lower Niobrara River samples was 48 percent medium sand, 37 percent fine sand, and about 7 percent each very fine sand and coarse sand fractions. On average, samples were moderately well sorted.Particle shape and strength were assessed for the dominant-size class of each sample. For proppant strength, crush resistance was tested at a predetermined level of stress (34.5 megapascals [MPa], or 5,000 pounds-force per square inch). To meet the API minimum requirement for proppant, after the crush test not more than 10 percent of the tested sample should be finer than the precrush dominant-size class. For particle shape, all samples surpassed the recommended minimum criteria for sphericity and roundness, with most samples being well-rounded. For proppant strength, of 57 crush-resistance tested Missouri River delta samples of 40/70-sized sand, 23 (40 percent) were interpreted as meeting the minimum criterion at 34.5 MPa, or 5,000 pounds-force per square inch. Of 12 tested samples of 70/140-sized sand, 9 (75 percent) of the Missouri River delta samples had less than 10 percent fines by volume following crush testing, achieving the minimum criterion at 34.5 MPa. Crush resistance for delta samples was strongest at sandbar complex A, where 67 percent of tested samples met the 10-percent fines criterion at the 34.5-MPa threshold. This frequency was higher than was indicated by samples from sandbar complexes B, C, and D that had rates of 50, 46, and 42 percent, respectively. The group of sandbar complex A samples also contained the largest percentages of samples dominated by the API 70/140 size class, which overall had a higher percentage of samples meeting the minimum criterion compared to samples dominated by coarser size classes; however, samples from sandbar complex A that had the API 40/70 size class tested also had a higher rate for meeting the minimum criterion (57 percent) than did samples from sandbar complexes B, C, and D (50, 43, and 40 percent, respectively). For samples collected along the lower Niobrara River, of the 25 tested samples of 40/70-sized sand, 9 samples passed the API minimum criterion at 34.5 MPa, but only 3 samples passed the more-stringent criterion of 8 percent postcrush fines. All four tested samples of 70/140 sand passed the minimum criterion at 34.5 MPa, with postcrush fines percentage of at most 4.1 percent.For two reaches of the lower Niobrara River, where hydraulic sorting was energized artificially by the hydraulic head drop at and immediately downstream from Spencer Dam, suitability of channel deposits for potential use as fracture sand was confirmed by test results. All reach A washed samples were well-rounded and had sphericity scores above 0.65, and samples for 80 percent of sampled locations met the crush-resistance criterion at the 34.5-MPa stress level. A conservative lower-bound estimate of sand volume in the reach A deposits was about 86,000 cubic meters. All reach B samples were well-rounded but sphericity averaged 0.63, a little less than the average for upstream reaches A and SP. All four samples tested passed the crush-resistance test at 34.5 MPa. Of three reach B sandbars, two had no more than 3 percent fines after the crush test, surpassing more stringent criteria for crush resistance that accept a maximum of 6 percent fines following the crush test for the API 70/140 size class.Relative to the crush-resistance test results for the API 40/70 size fraction of two samples of mine output from Loup River settling-basin dredge spoils near Genoa, Nebr., four of five reach A sample locations compared favorably. The four samples had increases in fines composition of 1.6–5.9 percentage points, whereas fines in the two mine-output samples increased by an average 6.8 percentage points.
Heater Validation for the NEXT-C Hollow Cathodes

NASA Technical Reports Server (NTRS)

Verhey, Timothy R.; Soulas, George C.; Mackey, Jonathan A.

2018-01-01

Swaged cathode heaters whose design was successfully demonstrated under a prior flight project are to be provided by the NASA Glenn Research Center for the NEXT-C ion thruster being fabricated by Aerojet Rocketdyne. Extensive requalification activities were performed to validate process controls that had to be re-established or revised because systemic changes prevented reuse of the past approaches. A development batch of heaters was successfully fabricated based on the new process controls. Acceptance and cyclic life testing of multiple discharge and neutralizer sized heaters extracted from the development batch was initiated in August, 2016, with the last heater completing testing in April, 2017. Cyclic life testing results substantially exceeded the NEXT-C thruster requirement as well as all past experience for GRC-fabricated units. The heaters demonstrated ultimate cyclic life capability of 19050 to 33500 cycles. A qualification batch of heaters is now being fabricated using the finalized process controls. A set of six heaters will be acceptance and cyclic tested to verify conformance to the behavior observed with the development heaters. The heaters for flight use will be then be provided to the contractor from the remainder of the qualification batch. This paper summarizes the fabrication process control activities and the acceptance and life testing of the development heater units.
Hydrogeology of glacial deposits in a preglacial bedrock valley, Waukesha County, Wisconsin

USGS Publications Warehouse

Batten, W.G.; Conlon, T.D.

1993-01-01

Results of a 6.5-hour aquifer test indicate that the silty sand and gravel deposits have an average transmissivity of about 140 feet squared per day and an average storage coefficient of about 1.2x10"3 at one location. The horizontal hydraulic conductivity of these deposits averages about 4 feet per day. Analysis of drawdown indicates that these deposits are part of a leaky confined-aquifer system and that some water is derived from storage in an overlying clay layer. The transmissivity value determined from this aquifer test and a lack of clean sand and gravel encountered in other test holes indicate that glacial deposits at these sites may not yield enough water for a large municipal water supply. Sand and gravel deposits, capable of development as a municipal supply, may be present in the southern part of the study area. However, additional test holes are needed to determine whether adequate sand and gravel deposits underlie this area.
Biodegradation of propylene glycol and associated hydrodynamic effects in sand.

PubMed

Bielefeldt, Angela R; Illangasekare, Tissa; Uttecht, Megan; LaPlante, Rosanna

2002-04-01

At airports around the world, propylene glycol (PG) based fluids are used to de-ice aircraft for safe operation. PG removal was investigated in 15-cm deep saturated sand columns. Greater than 99% PG biodegradation was achieved for all flow rates and loading conditions tested, which decreased the hydraulic conductivity of the sand by 1-3 orders of magnitude until a steady-state minimum was reached. Under constant loading at 120 mg PG/d for 15-30 d, the hydraulic conductivity (K) decreased by 2-2.5 orders of magnitude when the average linear velocity of the water was 4.9-1.4 cm/h. Variable PG loading in recirculation tests resulted in slower conductivity declines and lower final steady-state conductivity than constant PG feeding. After significant sand plugging, endogenous periods of time without PG resulted in significant but partial recovery of the original conductivity. Biomass growth also increased the dispersivity of the sand.
Ecology of sand flies in a low-density residential rural area, with mixed forest/agricultural exploitation, in north-eastern Brazil.

PubMed

Miranda, Débora Elienai de Oliveira; Sales, Kamila Gaudêncio da Silva; Faustino, Maria Aparecida da Gloria; Alves, Leucio Câmara; Brandão-Filho, Sinval Pinto; Dantas-Torres, Filipe; de Carvalho, Gílcia Aparecida

2015-06-01

Cutaneous leishmaniasis caused by Leishmania braziliensis is endemic in Brazil, where Lutzomyia whitmani is the most important vector involved in the transmission to humans, particularly in the peridomestic environment. Herein, we assessed the ecology of sand flies, including Lu. whitmani, in a low-density residential rural area with mixed forest/agricultural exploitation in north-eastern Brazil, where cutaneous leishmaniasis is endemic. Particularly, we hypothesized that sand fly abundance was correlated with climatic variables. Sand fly collections were carried out monthly from August 2013 to August 2014, using seven CDC light traps, for three consecutive nights, in three kinds of environments: indoor, peridomicile and forest. Collected sand flies were identified based on morphology and females of Lu. whitmani (n=169), Lu. amazonensis (n=134) and Lu. complexa (n=21) were selected and tested by PCR for Leishmania (Viannia) spp. In total, 5167 sand flies belonging to 19 species were identified, being that Lu. choti (43.2%) was the most frequent species, followed by Lu. amazonensis (16.6%), Lu. whitmani (15.8%), Lu. sordellii (10.7%) and Lu. quinquefer (5.8%), which together represented over 90% of the collected sand flies. All females tested by PCR were negative. The number of sand flies collected daily was positively correlated with temperature and negatively correlated with rainfall and relative humidity. Furthermore, there was a positive correlation between daily number of sand flies and daily average saturation deficit. This study points out that the number of sand flies captured daily is correlated to climatic variables, including saturation deficit, which may represent a useful parameter for monitoring sand fly populations in leishmaniasis-endemic areas. Copyright © 2015 Elsevier B.V. All rights reserved.
Surface coating with Ca(OH)2 for improvement of the transport of nanoscale zero-valent iron (nZVI) in porous media.

PubMed

Wei, Cai-jie; Li, Xiao-yan

2013-01-01

A novel thermal deposition method was developed to coat Ca(OH)2 on the surface of nanoscale zero-valent iron (nZVI). The nZVI particles with the Ca(OH)2 coating layer, nZVI/Ca(OH)2, had a clear core-shell structure based on the transmission electron microscopy observations, and the Ca(OH)2 shell was identified as an amorphous phase. The Ca(OH)2 coating shell would not only function as an effective protection layer for nZVI but also improve the mobility of nZVI in porous media for its use in environmental decontamination. A 10% Ca/Fe mass ratio was found to result in a proper thickness of the Ca(OH)2 shell on the nZVI surface. Based on the filtration tests in sand columns, the Ca(OH)2-based surface coating could greatly improve the mobility and transport of nZVI particles in porous media. In addition, batch experiments were conducted to evaluate the reactivity of Ca(OH)2-coated nZVI particles for the reduction of Cr(VI) and its removal from water.
Removal of pharmaceuticals during drinking water treatment.

PubMed

Ternes, Thomas A; Meisenheimer, Martin; McDowell, Derek; Sacher, Frank; Brauch, Heinz-Jürgen; Haist-Gulde, Brigitte; Preuss, Gudrun; Wilme, Uwe; Zulei-Seibert, Ninette

2002-09-01

The elimination of selected pharmaceuticals (bezafibrate, clofibric acid, carbamazepine, diclofenac) during drinking water treatment processes was investigated at lab and pilot scale and in real waterworks. No significant removal of pharmaceuticals was observed in batch experiments with sand under natural aerobic and anoxic conditions, thus indicating low sorption properties and high persistence with nonadapted microorganisms. These results were underscored by the presence of carbamazepine in bank-filtrated water with anaerobic conditions in a waterworks area. Flocculation using iron(III) chloride in lab-scale experiments (Jar test) and investigations in waterworks exhibited no significant elimination of the selected target pharmaceuticals. However, ozonation was in some cases very effective in eliminating these polar compounds. In lab-scale experiments, 0.5 mg/L ozone was shown to reduce the concentrations of diclofenac and carbamazepine by more than 90%, while bezafibrate was eliminated by 50% with a 1.5 mg/L ozone dose. Clofibric acid was stable even at 3 mg/L ozone. Under waterworks conditions, similar removal efficiencies were observed. In addition to ozonation, filtration with granular activated carbon (GAC) was very effective in removing pharmaceuticals. Except for clofibric acid, GAC in pilot-scale experiments and waterworks provided a major elimination of the pharmaceuticals under investigation.
Geotechnical properties of cemented sands in steep slopes

USGS Publications Warehouse

Collins, B.D.; Sitar, N.

2009-01-01

An investigation into the geotechnical properties specific to assessing the stability of weakly and moderately cemented sand cliffs is presented. A case study from eroding coastal cliffs located in central California provides both the data and impetus for this study. Herein, weakly cemented sand is defined as having an unconfined compressive strength (UCS) of less than 100 kPa, and moderately cemented sand is defined as having UCS between 100 and 400 kPa. Testing shows that both materials fail in a brittle fashion and can be modeled effectively using linear Mohr-Coulomb strength parameters, although for weakly cemented sands, curvature of the failure envelope is more evident with decreasing friction and increasing cohesion at higher confinement. Triaxial tests performed to simulate the evolving stress state of an eroding cliff, using a reduction in confinement-type stress path, result in an order of magnitude decrease in strain at failure and a more brittle response. Tests aimed at examining the influence of wetting on steep slopes show that a 60% decrease in UCS, a 50% drop in cohesion, and 80% decrease in the tensile strength occurs in moderately cemented sand upon introduction to water. In weakly cemented sands, all compressive, cohesive, and tensile strength is lost upon wetting and saturation. The results indicate that particular attention must be given to the relative level of cementation, the effects of groundwater or surficial seepage, and the small-scale strain response when performing geotechnical slope stability analyses on these materials. ?? 2009 ASCE.
Virus elimination in activated sludge systems: from batch tests to mathematical modeling.

PubMed

Haun, Emma; Ulbricht, Katharina; Nogueira, Regina; Rosenwinkel, Karl-Heinz

2014-01-01

A virus tool based on Activated Sludge Model No. 3 for modeling virus elimination in activated sludge systems was developed and calibrated with the results from laboratory-scale batch tests and from measurements in a municipal wastewater treatment plant (WWTP). The somatic coliphages were used as an indicator for human pathogenic enteric viruses. The extended model was used to simulate the virus concentration in batch tests and in a municipal full-scale WWTP under steady-state and dynamic conditions. The experimental and modeling results suggest that both adsorption and inactivation processes, modeled as reversible first-order reactions, contribute to virus elimination in activated sludge systems. The model should be a useful tool to estimate the number of viruses entering water bodies from the discharge of treated effluents.
Study on strength characteristics of concrete using M-Sand and coconut fibers

NASA Astrophysics Data System (ADS)

Neeraja, D.; Wani, Amir Iqbal; Kamili, Zainulabideen; Agarwal, Krishnakant

2017-11-01

In the current world, concrete has become a very important part of the construction industry and the materials which are used in making concrete have evolved due to better quality of cement and better grade of coarse aggregates. The sand is an important part of concrete. It is mainly procured from natural sources. Thus the grade of sand is not under our control. The methods of removing sand from river beds are causing various environmental issues and river sand is depleting at a faster rate than it is replaced by natural methods. Hence, various replacements for the river sand are being done, one of which is manufactured-sand. It is obtained from various granite quarries. Manufactured-sand or M-sand is slowly replacing the fine aggregate in the concrete as the sand is well graded and gives higher strength of concrete. There are various fibers used for reinforcing concrete which consist mainly of artificial or steel fibers. Some of these fibers are quite costly and sometimes difficult to obtain. So there are many natural fibers which can be used in place of these fibers, one of which is coconut fiber, extracted from the shell of a coconut. Coconut fibers are used in various industries like rope making, coir mattresses etc. Since these fibers are one of the strongest fibers among naturally occuring fibers, they can be used in the concrete mix to increase the resistance in concrete. They are also light weight and easily available and thus can be used in reinforcement of concrete. The studies up till now have tested the use of coconut fibers in normal concrete involving river sand but in this study a particular ratio of M-sand and river sand is used to get the maximum possible strength. Hence, in this project an attempt was made to use M-sand and coconut fiber in concrete. Based on the test results, it can be concluded that combination of M-sand and coconut fibers gave favorable results in strength criteria.
National Metal Casting Research Institute final report. Volume 1, Sand reclamation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vondra, L.F.; Burningham, J.S.

1995-08-01

A mobile thermal foundry sand reclamation unit was designed and constructed. This unit consisted of thermal and mechanical sand reclamation equipment installed on the bed of a 50 foot low-boy trailer. It was transported to a number of Midwest foundries for on-site demonstration of the sand reclamation process. This allowed participating foundries to have their own refuse sand (10-100 tons) processed and then reused in production for evaluation. The purpose for building the unit was to demonstrate to foundries through ``hands on`` experience that refuse sands can be reclaimed and successfully reused particularly in regard to product quality. Most ofmore » the participating foundries indicated a high level of satisfaction with the reclaimed sand. Laboratory testing of samples of the used sand, before and after processing by the demonstration unit, verified the usability of the reclaimed sand. One of the foundries participating was a brass foundry, the sand from this foundry contained lead and is classified as a hazardous material. After reclamation the sand was no longer hazardous and could also be reused in the foundry.« less
Test wells TW1 and TW2, and TW3, White Sands Missile Range, Otero County, New Mexico

USGS Publications Warehouse

Myers, R.G.; Pinckley, K.M.

1987-01-01

Three test wells, TW1, TW2, and TW3, were drilled at White Sands Missile Range in south-central New Mexico in July, August, and October 1983 as part of a joint military training program sponsored by the U.S. Navy and U.S. Army in July, August, and October 1983. The test wells were drilled as exploratory and monitoring wells for the toxic waste storage facility at White Sands Missile Range. Information obtained from these wells includes lithologic logs for all wells and borehole-geophysical logs for the cased wells. (Author 's abstract)

Fumaric Acid Production from Alkali-Pretreated Corncob by Fed-Batch Simultaneous Saccharification and Fermentation Combined with Separated Hydrolysis and Fermentation at High Solids Loading.

PubMed

Li, Xin; Zhou, Jin; Ouyang, Shuiping; Ouyang, Jia; Yong, Qiang

2017-02-01

Production of fumaric acid from alkali-pretreated corncob (APC) at high solids loading was investigated using a combination of separated hydrolysis and fermentation (SHF) and fed-batch simultaneous saccharification and fermentation (SSF) by Rhizopus oryzae. Four different fermentation modes were tested to maximize fumaric acid concentration at high solids loading. The highest concentration of 41.32 g/L fumaric acid was obtained from 20 % (w/v) APC at 38 °C in the combined SHF and fed-batch SSF process, compared with 19.13 g/L fumaric acid in batch SSF alone. The results indicated that a combination of SHF and fed-batch SSF significantly improved production of fumaric acid from lignocellulose by R. oryzae than that achieved with batch SSF at high solids loading.
Testing SLURM open source batch system for a Tierl/Tier2 HEP computing facility

NASA Astrophysics Data System (ADS)

Donvito, Giacinto; Salomoni, Davide; Italiano, Alessandro

2014-06-01

In this work the testing activities that were carried on to verify if the SLURM batch system could be used as the production batch system of a typical Tier1/Tier2 HEP computing center are shown. SLURM (Simple Linux Utility for Resource Management) is an Open Source batch system developed mainly by the Lawrence Livermore National Laboratory, SchedMD, Linux NetworX, Hewlett-Packard, and Groupe Bull. Testing was focused both on verifying the functionalities of the batch system and the performance that SLURM is able to offer. We first describe our initial set of requirements. Functionally, we started configuring SLURM so that it replicates all the scheduling policies already used in production in the computing centers involved in the test, i.e. INFN-Bari and the INFN-Tier1 at CNAF, Bologna. Currently, the INFN-Tier1 is using IBM LSF (Load Sharing Facility), while INFN-Bari, an LHC Tier2 for both CMS and Alice, is using Torque as resource manager and MAUI as scheduler. We show how we configured SLURM in order to enable several scheduling functionalities such as Hierarchical FairShare, Quality of Service, user-based and group-based priority, limits on the number of jobs per user/group/queue, job age scheduling, job size scheduling, and scheduling of consumable resources. We then show how different job typologies, like serial, MPI, multi-thread, whole-node and interactive jobs can be managed. Tests on the use of ACLs on queues or in general other resources are then described. A peculiar SLURM feature we also verified is triggers on event, useful to configure specific actions on each possible event in the batch system. We also tested highly available configurations for the master node. This feature is of paramount importance since a mandatory requirement in our scenarios is to have a working farm cluster even in case of hardware failure of the server(s) hosting the batch system. Among our requirements there is also the possibility to deal with pre-execution and post-execution scripts, and controlled handling of the failure of such scripts. This feature is heavily used, for example, at the INFN-Tier1 in order to check the health status of a worker node before execution of each job. Pre- and post-execution scripts are also important to let WNoDeS, the IaaS Cloud solution developed at INFN, use SLURM as its resource manager. WNoDeS has already been supporting the LSF and Torque batch systems for some time; in this work we show the work done so that WNoDeS supports SLURM as well. Finally, we show several performance tests that we carried on to verify SLURM scalability and reliability, detailing scalability tests both in terms of managed nodes and of queued jobs.
Toward Higher QA: From Parametric Release of Sterile Parenteral Products to PAT for Other Pharmaceutical Dosage Forms.

PubMed

Hock, Sia Chong; Constance, Neo Xue Rui; Wah, Chan Lai

2012-01-01

Pharmaceutical products are generally subjected to end-product batch testing as a means of quality control. Due to the inherent limitations of conventional batch testing, this is not the most ideal approach for determining the pharmaceutical quality of the finished dosage form. In the case of terminally sterilized parenteral products, the limitations of conventional batch testing have been successfully addressed with the application of parametric release (the release of a product based on control of process parameters instead of batch sterility testing at the end of the manufacturing process). Consequently, there has been an increasing interest in applying parametric release to other pharmaceutical dosage forms, beyond terminally sterilized parenteral products. For parametric release to be possible, manufacturers must be capable of designing quality into the product, monitoring the manufacturing processes, and controlling the quality of intermediates and finished products in real-time. Process analytical technology (PAT) has been thought to be capable of contributing to these prerequisites. It is believed that the appropriate use of PAT tools can eventually lead to the possibility of real-time release of other pharmaceutical dosage forms, by-passing the need for end-product batch testing. Hence, this literature review attempts to present the basic principles of PAT, introduce the various PAT tools that are currently available, present their recent applications to pharmaceutical processing, and explain the potential benefits that PAT can bring to conventional ways of processing and quality assurance of pharmaceutical products. Last but not least, current regulations governing the use of PAT and the manufacturing challenges associated with PAT implementation are also discussed. Pharmaceutical products are generally subjected to end-product batch testing as a means of quality control. Due to the inherent limitations of conventional batch testing, this is not the most ideal approach. In the case of terminally sterilized parenteral products, these limitations have been successfully addressed with the application of parametric release (the release of a product based on control of process parameters instead of batch sterility testing at the end of the manufacturing process). Consequently, there has been an increasing interest in applying parametric release to other pharmaceutical dosage forms. With the advancement of process analytical technology (PAT), it is possible to monitor the manufacturing processes closely. This will eventually enable quality control of the intermediates and finished products, and thus their release in real-time. Hence, this literature review attempts to present the basic principles of PAT, introduce the various PAT tools that are currently available, present their recent applications to pharmaceutical processing, and explain the potential benefits that PAT can bring to conventional ways of processing and quality assurance of pharmaceutical products. It will also discuss the current regulations governing the use of PAT and the manufacturing challenges associated with the implementation of PAT.
Aerobic biodegradability of methyldiethanolamine (MDEA) used in natural gas sweetening plants in batch tests and continuous flow experiments.

PubMed

Fürhacker, M; Pressl, A; Allabashi, R

2003-09-01

Mixtures of different amines including tertiary amines (methyldiethanolamine, MDEA) are commonly used for the removal of CO2 from gas mixtures or in gas sweetening processes for the extraction of CO2 and H2S. The absorber solutions used can be released into the industrial waste water due to continuous substitution of degraded MDEA, periodically cleaning processes or an accidental spill. In this study, the aerobic biodegradability of MDEA was investigated in a standardised batch test and a continuous flow experiment (40 l/d). The results of the batch test indicated that the MDEA-solution was non-biodegradable during the test period of 28 days, whereas the continuous flow experiments showed biodegradation of more than 96% based on TOC-measurements. This was probably due to the adaptation of the microorganisms to this particular waste water contamination during continuous flow experiment.
Characterize Behaviour of Emerging Pollutants in Artificial Recharge: Column Experiments - Experiment Design and Results of Preliminary Tests

NASA Astrophysics Data System (ADS)

Wang, H.; Carrera, J.; Ayora, C.; Licha, T.

2012-04-01

Emerging pollutants (EPs) have been detected in water resources as a result of human activities in recent years. They include pharmaceuticals, personal care products, dioxins, flame retardants, etc. They are a source of concern because many of them are resistant to conventional water treatment, and they are harmful to human health, even in low concentrations. Generally, this study aims to characterize the behaviour of emerging pollutants in reclaimed water in column experiments which simulates artificial recharge. One column set includes three parts: influent, reactive layer column (RLC) and aquifer column (AC). The main influent is decided to be Secondary Effluent (SE) of El Prat Wastewater Treatment Plant, Barcelona. The flow rate of the column experiment is 0.9-1.5 mL/min. the residence time of RLC is designed to be about 1 day and 30-40 days for AC. Both columns are made of stainless steel. Reactive layer column (DI 10cm * L55cm) is named after the filling material which is a mixture of organic substrate, clay and goethite. One purpose of the application of the mixture is to increase dissolve organic carbon (DOC). Leaching test in batchs and columns has been done to select proper organic substrate. As a result, compost was selected due to its long lasting of releasing organic matter (OM). The other purpose of the application of the mixture is to enhance adsorption of EPs. Partition coefficients (Kow) of EPs indicate the ability of adsorption to OM. EPs with logKow>2 could be adsorbed to OM, like Ibuprofen, Bezafibrate and Diclofenac. Moreover, some of EPs are charged in the solution with pH=7, according to its acid dissociation constant (Ka). Positively charged EPs, for example Atenolol, could adsorb to clay. In the opposite, negatively charged EPs, for example Gemfibrozil, could adsorb to goethite. Aquifer column (DI 35cm * L1.5m) is to simulate the processes taking place in aquifer in artificial recharge. The filling of AC has two parts: silica sand and compost. The grain size of the sand is about 0.5mm. Aquifer deposits usually contain some natural organic matter. Therefore, compost (<1mm) was selected to be mixed with sand with the ratio of 1:99. Long residence time of AC and high concentration of DOC are favourable to generate variable redox states, which favour EPs degradation.
Mobility of as, Cu, Cr, and Zn from tailings covered with sealing materials using alkaline industrial residues: a comparison between two leaching methods.

PubMed

Jia, Yu; Maurice, Christian; Öhlander, Björn

2016-01-01

Different alkaline residue materials (fly ash, green liquor dregs, and lime mud) generated from the pulp and paper industry as sealing materials were evaluated to cover aged mine waste tailings (<1% sulfur content, primarily pyrite). The mobility of four selected trace elements (Cr, Cu, Zn, and As) was compared based on batch and column leaching studies to assess the effectiveness of these alkaline materials as sealing agents. Based on the leaching results, Cr, Cu, and Zn were immobilized by the alkaline amendments. In the amended tailings in the batch system only As dramatically exceeded the limit values at L/S 10 L/kg. The leaching results showed similar patterns to the batch results, though leached Cr, Cu, and Zn showed higher levels in the column tests than in the batch tests. However, when the columns were compared with the batches, the trend for Cu was opposite for the unamended tailings. By contrast, both batch and column results showed that the amendment caused mobilization of As compared with the unamended tailings in the ash-amended tailings. The amount of As released was greatest in the ash column and decreased from the dregs to the lime columns. The leaching of As at high levels can be a potential problem whenever alkaline materials (especially for fly ash) are used as sealing materials over tailings. The column test was considered by the authors to be a more informative method in remediation of the aged tailings with low sulfur content, since it mimics better actual situation in a field.
FIELD TEST OF NONFUEL HYDROCARBON BIOVENTING IN CLAYEY-SAND SOIL

EPA Science Inventory

A pilot-scale bioventing test was conducted at the Greenwood Chemical Superfund Site in Virginia. The characteristics of the site included clayey-sand soils and nonfuel organic contamination such as acetone, toluene, and naphthalene in the vadose zone. Based on the results of an...
Solid sand particle addition can enhance the production of resting cysts in dinoflagellates

NASA Astrophysics Data System (ADS)

Yang, Aoao; Hu, Zhangxi; Tang, Yingzhong

2018-03-01

Resting cysts are an important part of the life cycle for many harmful algal bloom-forming dinoflagellates, and play vital roles in the recurrence and geographical spread of harmful algal blooms. Numerous factors have been suggested to regulate the formation of resting cysts, although only a few have been proven to be significant. Cyst formation can be induced by adverse environmental conditions such as drastic changes in temperature, light, salinity, and nutrient levels, and by biological interactions. In this study, we evaluated the ability of an artificial factor (fine sand particles) to enhance the formation of resting cysts. Fine sand particles were added to cultures of dinoflagellates that are known to produce cysts. The addition of fine sand particles significantly increased both the production rate and final yield of cysts in cultures of Scrippsiella trochoidea, Biecheleria brevisulcata, and Levanderina fissa (= Gymnodinium fissum, Gyrodinium instriatum, Gyrodinium uncatenum). The largest increase in the final yield (107-fold) of cysts as a result of sand addition was in S. trochoidea. However, addition of fine sand particles did not induce cyst formation, or barely affected cyst formation, in Akashiwo sanguinea, Cochlodinium polykrikoides and Pheopolykrikos hartmannii, which are also known to be cyst-producing species. We speculated that addition of sand significantly increased the chances of cell collision, which triggered cyst formation. However, further research is required to test this idea. Importantly, our findings indicate that the addition of fine sand particles is a useful method to obtain a large quantity of cysts in a short time for laboratory studies or tests; for example, if a cyst viability test is being used to assess the effectiveness of ships' ballast water treatment.
Zinc Leaching from Tire Crumb Rubber

NASA Astrophysics Data System (ADS)

Rhodes, E. P.; Ren, J.; Mays, D. C.

2010-12-01

Recent estimates indicate that more than 2 billion scrap tires are currently stockpiled in the United States and approximately 280 million more tires are added annually. Various engineering applications utilize recycled tires in the form of shredded tire crumb rubber. However, the use of tire crumb rubber may have negative environmental impacts, especially when the rubber comes into contact with water. A review of the literature indicates that leaching of zinc from tire crumb rubber is the most significant water quality concern associated with using this material. Zinc is generally used in tire manufacturing, representing approximately 1.3% of the final product by mass. This study will report results from the U.S. Environmental Protection Agency’s (EPA’s) Synthetic Precipitation Leaching Procedure, batch leaching tests, and column leaching tests performed to quantify the process by which zinc leaches from tire crumb rubber into water. Results are interpreted with a first-order kinetic attachment/detachment model, implemented with the U.S. Agricultural Research Service software HYDRUS-1D, in order to determine the circumstances when zinc leaching from tire crumb rubber would be expected to comply with the applicable discharge limits. One potential application for recycled tires is replacing sand with tire crumb rubber in granular media filters used for stormwater pollution control. For this to be a viable application, the total zinc in the stormwater discharge must be below the EPA’s benchmark value of 0.117 mg/L.
Sugarcane Genotype Selection on Muck and Sand Soils in Florida — a Case for Dedicated Environments

USDA-ARS?s Scientific Manuscript database

Traditionally, the cooperative sugarcane (Saccharum spp.) breeding program located at Canal Point has selected genotypes exclusively on muck soils in the early to middle stages of the program. Only about 0.20% of genotypes are ever tested on sand, resulting in the possibility that many sand-adapted ...
Use of bauxite as packing material in steam injection wells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scoglio, J.; Joubert, G.; Gallardo, B.

1995-12-31

Cyclic steam injection, also known as steam soak, has proven to be the most efficient method for producing heavy crude oil and bitumen from unconsolidated sands. The application of steam injection may, however, generate sand production, causing, among other things, a decrease in production. The gravel pack technique is the most efficient way to prevent fines production from cold producing wells. But, once they are steam stimulated, a dissolution of quartz containing gravel material takes place reducing greatly the packing permeability and eventually sand production. Different types of packing material have been used to avoid sand production after cyclic steammore » injection, such as gravel, ceramics, bauxite, coated resin, and American sand. This paper presents the results of field test, using sinterized bauxite as a packing material, carried out in Venezuela`s heavy oil operations as a part of a comprehensive program aimed at increasing the packing durability and reducing sand production. This paper also verify the results of laboratory tests in which Bauxite was found to be less soluble than other packing material when steam injected.« less
Aluminum-fly ash metal matrix composites for automotive parts. [Reports for October 1 to December 1998, and January 31 to March 31, 1999

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weiss, David; Purgert, Robert; Rhudy, Richard

1999-04-21

Some highlights are: (1) Material development, process development, and part validation are occurring simultaneously on a fast track schedule. (2) Prior project activity has resulted in a program emphasis on three components--manifolds, mounting brackets, and motor mounts; and three casting techniques--squeeze casting, pressure die casting, and sand casting. (3) With the project focus, it appears possible to offer manifolds and mounting brackets for automotive qualification testing on a schedule in line with the PNGV Year 2004 goal. (4) Through an iterative process of fly ash treatment, MMC ingot preparation, foundry process refinement, and parts production, both foundries (Eck Industries andmore » Thompson Aluminum Casting Company) are addressing the pre-competitive issues of: (a) Optimum castability with fly ash shapes and sizes; (b) Best mechanical properties derived from fly ash shapes and sizes; (c) Effective fly ash classification processes; (d) Mechanical properties resulting from various casting processes and fly ash formulations. Eck and TAC continued experiments with batch ingot provided by both Eck and the University of Wisconsin at Milwaukee. Castings were run that contained varying amounts of fly ash and different size fractions. Components were cast using cenosphere material to ascertain the effects of squeeze casting and to determine whether the pressure would break the cenospheres. Test parts are currently being machined into substandard test bars for mechanical testing. Also, the affect of heat treatments on ashalloy are being studied through comparison to two lots, one heat treated and one in the ''as cast'' condition.« less
Actual waste demonstration of the nitric-glycolic flowsheet for sludge batch 9 qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newell, D.; Pareizs, J.; Martino, C.

For each sludge batch that is processed in the Defense Waste Processing Facility (DWPF), the Savannah River National Laboratory (SRNL) performs qualification testing to demonstrate that the sludge batch is processable. Based on the results of this actual-waste qualification and previous simulant studies, SRNL recommends implementation of the nitric-glycolic acid flowsheet in DWPF. Other recommendations resulting from this demonstration are reported in section 5.0.
The Reliability and Validity of the Concepts About Print and Record of Oral Language.

ERIC Educational Resources Information Center

Day, H. D.; Day, Kaaren C.

The Concepts about Print (Sand) and Record of Oral Language (ROL) tests were administered three times to 29 male and 27 female kindergarten children as part of a study to determine the reliability and concurrent validity of the tests. The Sand and Metropolitan Readiness Test (MRT) were administered to the returning participants (27 males and 24…
106-17 Telemetry Standards Front Matter

DTIC Science & Technology

2017-07-01

IS UNLIMITED ABERDEEN TEST CENTER DUGWAY PROVING GROUND REAGAN TEST SITE REDSTONE TEST CENTER WHITE SANDS MISSILE RANGE YUMA PROVING GROUND...Council US Army White Sands Missile Range, New Mexico 88002-5110 This page intentionally left blank. Telemetry Standards, IRIG Standard 106-17...TM receiver commands for interoperability. f. Task TG-141: Update IRIG 106 with Standards for Data Quality Metrics (DQM) and Data Quality
Porous media augmented with biochar for the retention of E. coli

NASA Astrophysics Data System (ADS)

Kolotouros, Christos A.; Manariotis, Ioannis D.; Karapanagioti, Hrissi K.

2016-04-01

A significant number of epidemic outbreaks has been attributed to waterborne fecal-borne pathogenic microorganisms from contaminated ground water. The transport of pathogenic microorganisms in groundwater is controlled by physical and chemical soil properties like soil structure, texture, percent water saturation, soil ionic strength, pore-size distribution, soil and solution pH, soil surface charge, and concentration of organic carbon in solution. Biochar can increase soil productivity by improving both chemical and physical soil properties. The mixing of biochar into soils may stimulate microbial population and activate dormant soil microorganisms. Furthermore, the application of biochar into soil affects the mobility of microorganisms by altering the physical and chemical properties of the soil, and by retaining the microorganisms on the biochar surface. The aim of this study was to investigate the effect of biochar mixing into soil on the transport of Escherichia coli in saturated porous media. Initially, batch experiments were conducted at two different ionic strengths (1 and 150 mM KCl) and at varying E. coli concentrations in order to evaluate the retention of E. coli on biochar in aqueous solutions. Kinetic analysis was conducted, and three isotherm models were employed to analyze the experimental data. Column experiments were also conducted in saturated sand columns augmented with different biochar contents, in order to examine the effect of biochar on the retention of E. coli. The Langmuir model fitted better the retention experimental data, compared to Freundlich and Tempkin models. The retention of E. coli was enhanced at lower ionic strength. Finally, biochar-augmented sand columns were more capable in retaining E. coli than pure sand columns.
Naphthenic acids speciation and removal during petroleum-coke adsorption and ozonation of oil sands process-affected water.

PubMed

Gamal El-Din, Mohamed; Fu, Hongjing; Wang, Nan; Chelme-Ayala, Pamela; Pérez-Estrada, Leonidas; Drzewicz, Przemysław; Martin, Jonathan W; Zubot, Warren; Smith, Daniel W

2011-11-01

The Athabasca Oil Sands industry produces large volumes of oil sands process-affected water (OSPW) as a result of bitumen extraction and upgrading processes. Constituents of OSPW include chloride, naphthenic acids (NAs), aromatic hydrocarbons, and trace heavy metals, among other inorganic and organic compounds. To address the environmental issues associated with the recycling and/or safe return of OSPW into the environment, water treatment technologies are required. This study examined, for the first time, the impacts of pretreatment steps, including filtration and petroleum-coke adsorption, on ozonation requirements and performance. The effect of the initial OSPW pH on treatment performance, and the evolution of ozonation and its impact on OSPW toxicity and biodegradability were also examined. The degradation of more than 76% of total acid-extractable organics was achieved using a semi-batch ozonation system at a utilized ozone dose of 150 mg/L. With a utilized ozone dose of 100 mg/L, the treated OSPW became more biodegradable and showed no toxicity towards Vibrio fischeri. Changes in the NA profiles in terms of carbon number and number of rings were observed after ozonation. The filtration of the OSPW did not improve the ozonation performance. Petroleum-coke adsorption was found to be effective in reducing total acid-extractable organics by a 91%, NA content by an 84%, and OSPW toxicity from 4.3 to 1.1 toxicity units. The results of this study indicate that the combination of petroleum-coke adsorption and ozonation is a promising treatment approach to treat OSPW. Copyright © 2011 Elsevier B.V. All rights reserved.
Preparation and characterization of poly(acrylic acid)—corn starch blend for use as chemical sand-fixing materials

NASA Astrophysics Data System (ADS)

Dang, Xugang; Chen, Hui; Shan, Zhihua

2017-07-01

One chemical sand-fixing materials based on poly(acrylic acid)-corn starch (PACS) blend was studied in this work. The PACS blend was prepared by solution mixing method between PA and CS. In order to prepare sand-fixing materials for environmental applications using the well-established method of spraying evenly PACS blend solution on the surfaces of fine sand. Fourier transform infrared spectroscopy (FT-IR) revealed the existence of the intermolecular interactions between the blend components. Scanning electron microscope (SEM) analysis showed a continuous phase of blend, and it also showed the good sand-fixing capacity. The test results of hygroscopicity and water retention experiments indicated that the blends had excellent water-absorbing and water-retention capacity. The results of contact angle measurements between the PACS solutions and fine sand showed that the PACS blend has a satisfactory effect on fine sand wetting. And the PACS, as a sand-fixation material, has excellent sand-fixation rate up to 99.5%.
Biological CO2 conversion to acetate in subsurface coal-sand formation using a high-pressure reactor system.

PubMed

Ohtomo, Yoko; Ijiri, Akira; Ikegawa, Yojiro; Tsutsumi, Masazumi; Imachi, Hiroyuki; Uramoto, Go-Ichiro; Hoshino, Tatsuhiko; Morono, Yuki; Sakai, Sanae; Saito, Yumi; Tanikawa, Wataru; Hirose, Takehiro; Inagaki, Fumio

2013-01-01

Geological CO2 sequestration in unmineable subsurface oil/gas fields and coal formations has been proposed as a means of reducing anthropogenic greenhouse gasses in the atmosphere. However, the feasibility of injecting CO2 into subsurface depends upon a variety of geological and economic conditions, and the ecological consequences are largely unpredictable. In this study, we developed a new flow-through-type reactor system to examine potential geophysical, geochemical and microbiological impacts associated with CO2 injection by simulating in-situ pressure (0-100 MPa) and temperature (0-70°C) conditions. Using the reactor system, anaerobic artificial fluid and CO2 (flow rate: 0.002 and 0.00001 ml/min, respectively) were continuously supplemented into a column comprised of bituminous coal and sand under a pore pressure of 40 MPa (confined pressure: 41 MPa) at 40°C for 56 days. 16S rRNA gene analysis of the bacterial components showed distinct spatial separation of the predominant taxa in the coal and sand over the course of the experiment. Cultivation experiments using sub-sampled fluids revealed that some microbes survived, or were metabolically active, under CO2-rich conditions. However, no methanogens were activated during the experiment, even though hydrogenotrophic and methylotrophic methanogens were obtained from conventional batch-type cultivation at 20°C. During the reactor experiment, the acetate and methanol concentration in the fluids increased while the δ(13)Cacetate, H2 and CO2 concentrations decreased, indicating the occurrence of homo-acetogenesis. 16S rRNA genes of homo-acetogenic spore-forming bacteria related to the genus Sporomusa were consistently detected from the sandstone after the reactor experiment. Our results suggest that the injection of CO2 into a natural coal-sand formation preferentially stimulates homo-acetogenesis rather than methanogenesis, and that this process is accompanied by biogenic CO2 conversion to acetate.
Biological CO2 conversion to acetate in subsurface coal-sand formation using a high-pressure reactor system

PubMed Central

Ohtomo, Yoko; Ijiri, Akira; Ikegawa, Yojiro; Tsutsumi, Masazumi; Imachi, Hiroyuki; Uramoto, Go-Ichiro; Hoshino, Tatsuhiko; Morono, Yuki; Sakai, Sanae; Saito, Yumi; Tanikawa, Wataru; Hirose, Takehiro; Inagaki, Fumio

2013-01-01

Geological CO2 sequestration in unmineable subsurface oil/gas fields and coal formations has been proposed as a means of reducing anthropogenic greenhouse gasses in the atmosphere. However, the feasibility of injecting CO2 into subsurface depends upon a variety of geological and economic conditions, and the ecological consequences are largely unpredictable. In this study, we developed a new flow-through-type reactor system to examine potential geophysical, geochemical and microbiological impacts associated with CO2 injection by simulating in-situ pressure (0–100 MPa) and temperature (0–70°C) conditions. Using the reactor system, anaerobic artificial fluid and CO2 (flow rate: 0.002 and 0.00001 ml/min, respectively) were continuously supplemented into a column comprised of bituminous coal and sand under a pore pressure of 40 MPa (confined pressure: 41 MPa) at 40°C for 56 days. 16S rRNA gene analysis of the bacterial components showed distinct spatial separation of the predominant taxa in the coal and sand over the course of the experiment. Cultivation experiments using sub-sampled fluids revealed that some microbes survived, or were metabolically active, under CO2-rich conditions. However, no methanogens were activated during the experiment, even though hydrogenotrophic and methylotrophic methanogens were obtained from conventional batch-type cultivation at 20°C. During the reactor experiment, the acetate and methanol concentration in the fluids increased while the δ13Cacetate, H2 and CO2 concentrations decreased, indicating the occurrence of homo-acetogenesis. 16S rRNA genes of homo-acetogenic spore-forming bacteria related to the genus Sporomusa were consistently detected from the sandstone after the reactor experiment. Our results suggest that the injection of CO2 into a natural coal-sand formation preferentially stimulates homo-acetogenesis rather than methanogenesis, and that this process is accompanied by biogenic CO2 conversion to acetate. PMID:24348470

Properties of Desert Sand and CMAS Glass

NASA Technical Reports Server (NTRS)

Bansal, Narottam P.; Choi, Sung R.

2014-01-01

As-received desert sand from a Middle East country has been characterized for its phase composition and thermal stability. X-ray diffraction analysis showed the presence of quartz (SiO2), calcite (CaCO3), gypsum (CaSO4.2H2O), and NaAlSi3O8 phases in as-received desert sand and showed weight loss of approx. 35 percent due to decomposition of CaCO3 and CaSO4.2H2O when heated to 1400 C. A batch of as-received desert sand was melted into calcium magnesium aluminosilicate (CMAS) glass at approx. 1500 C. From inductively coupled plasma-atomic emission spectrometry, chemical composition of the CMAS glass was analyzed to be 27.8CaO-4MgO-5Al2O3-61.6SiO2-0.6Fe2O3-1K2O (mole percent). Various physical, thermal and mechanical properties of the glass have been evaluated. Bulk density of CMAS glass was 2.69 g/cc, Young's modulus 92 GPa, Shear modulus 36 GPa, Poisson's ratio 0.28, dilatometric glass transition temperature (T (sub g)) 706 C, softening point (T (sub d)) 764 C, Vickers microhardness 6.3 +/- 0.4 GPa, indentation fracture toughness 0.75 +/- 0.15 MPa.m (sup 1/2), and coefficient of thermal expansion (CTE) 9.8 x 10 (exp -6)/degC in the temperature range 25 to 700 C. Temperature dependence of viscosity has also been estimated from various reference points of the CMAS glass using the Vogel-Fulcher-Tamman (VFT) equation. The glass remained amorphous after heat treating at 850 C for 10 hr but crystallized into CaSiO3 and Ca-Mg-Al silicate phases at 900 C or higher temperatures. Crystallization kinetics of the CMAS glass has also been investigated by differential thermal analysis (DTA). Activation energies for the crystallization of two different phases in the glass were calculated to be 403 and 483 kJ/mol, respectively.
Extraction-Scrub-Strip test results from the interim Salt Disposition Program Macrobatch 9 Tank 21H qualification samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T.

2016-02-23

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 9 for the Interim Salt Disposition Program (ISDP). The Salt Batch 9 characterization results were previously reported. An Extraction-Scrub-Strip (ESS) test was performed to determine cesium distribution ratios (D (Cs)) and cesium concentration in the strip effluent and decontaminated salt solution (DSS) streams; this data will be used by Tank Farm Engineering to project a cesium decontamination factor (DF). This test used actual Tank 21H material, and a blend solvent prepared by SRNL that mimics the solvent composition currently being used atmore » the Modular Caustic-Side Solvent Extraction Unit (MCU). The ESS test showed acceptable performance with an extraction D (Cs) value of 52.4. This value is consistent with results from previous salt batch ESS tests using similar solvent formulations. This compares well against the predicted value of 56.5 from a recently created D (Cs) model« less
Extraction, -scrub, -strip test results from the interim salt disposition program macrobatch 10 tank 21H qualification samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T. B.

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 10 for the Interim Salt Disposition Program (ISDP). The Salt Batch 10 characterization results were previously reported.ii,iii An Extraction, -Scrub, -Strip (ESS) test was performed to determine cesium distribution ratios (D(Cs)) and cesium concentration in the strip effluent (SE) and decontaminated salt solution (DSS) streams; this data will be used by Tank Farm Engineering to project a cesium decontamination factor (DF). This test used actual Tank 21H material, and a sample of the NGS Blend solvent currently being used at the Modularmore » Caustic-Side Solvent Extraction Unit (MCU). The ESS test showed acceptable performance with an extraction D(Cs) value of 110. This value is consistent with results from previous salt batch ESS tests using similar solvent formulations. This is better than the predicted value of 39.8 from a recently created D(Cs) model.« less
The consistency approach for quality control of vaccines - a strategy to improve quality control and implement 3Rs.

PubMed

De Mattia, Fabrizio; Chapsal, Jean-Michel; Descamps, Johan; Halder, Marlies; Jarrett, Nicholas; Kross, Imke; Mortiaux, Frederic; Ponsar, Cecile; Redhead, Keith; McKelvie, Jo; Hendriksen, Coenraad

2011-01-01

Current batch release testing of established vaccines emphasizes quality control of the final product and is often characterized by extensive use of animals. This report summarises the discussions of a joint ECVAM/EPAA workshop on the applicability of the consistency approach for routine release of human and veterinary vaccines and its potential to reduce animal use. The consistency approach is based upon thorough characterization of the vaccine during development and the principle that the quality of subsequent batches is the consequence of the strict application of a quality system and of a consistent production of batches. The concept of consistency of production is state-of-the-art for new-generation vaccines, where batch release is mainly based on non-animal methods. There is now the opportunity to introduce the approach into established vaccine production, where it has the potential to replace in vivo tests with non-animal tests designed to demonstrate batch quality while maintaining the highest quality standards. The report indicates how this approach may be further developed for application to established human and veterinary vaccines and emphasizes the continuing need for co-ordination and harmonization. It also gives recommendations for work to be undertaken in order to encourage acceptance and implementation of the consistency approach. Copyright © 2011. Published by Elsevier Ltd.. All rights reserved.
Acceptance Test Data for BWXT Coated Particle Batch 93164A Defective IPyC Fraction and Pyrocarbon Anisotropy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Helmreich, Grant W.; Hunn, John D.; Skitt, Darren J.

2017-02-01

Coated particle fuel batch J52O-16-93164 was produced by Babcock and Wilcox Technologies (BWXT) for possible selection as fuel for the Advanced Gas Reactor Fuel Development and Qualification (AGR) Program’s AGR-5/6/7 irradiation test in the Idaho National Laboratory (INL) Advanced Test Reactor (ATR), or may be used as demonstration production-scale coated particle fuel for other experiments. The tristructural-isotropic (TRISO) coatings were deposited in a 150-mm-diameter production-scale fluidizedbed chemical vapor deposition (CVD) furnace onto 425-μm-nominal-diameter spherical kernels from BWXT lot J52L-16-69316. Each kernel contained a mixture of 15.5%-enriched uranium carbide and uranium oxide (UCO) and was coated with four consecutive CVD layers:more » a ~50% dense carbon buffer layer with 100-μm-nominal thickness, a dense inner pyrolytic carbon (IPyC) layer with 40-μm-nominal thickness, a silicon carbide (SiC) layer with 35-μm-nominal thickness, and a dense outer pyrolytic carbon (OPyC) layer with 40-μm-nominal thickness. The TRISO-coated particle batch was sieved to upgrade the particles by removing over-sized and under-sized material, and the upgraded batch was designated by appending the letter A to the end of the batch number (i.e., 93164A).« less
Geophysical Assessment of Groundwater Potential: A Case Study from Mian Channu Area, Pakistan.

PubMed

Hasan, Muhammad; Shang, Yanjun; Akhter, Gulraiz; Jin, Weijun

2017-11-17

An integrated study using geophysical method in combination with pumping tests and geochemical method was carried out to delineate groundwater potential zones in Mian Channu area of Pakistan. Vertical electrical soundings (VES) using Schlumberger configuration with maximum current electrode spacing (AB/2 = 200 m) were conducted at 50 stations and 10 pumping tests at borehole sites were performed in close proximity to 10 of the VES stations. The aim of this study is to establish a correlation between the hydraulic parameters obtained from geophysical method and pumping tests so that the aquifer potential can be estimated from the geoelectrical surface measurements where no pumping tests exist. The aquifer parameters, namely, transmissivity and hydraulic conductivity were estimated from Dar Zarrouyk parameters by interpreting the layer parameters such as true resistivities and thicknesses. Geoelectrical succession of five-layer strata (i.e., topsoil, clay, clay sand, sand, and sand gravel) with sand as a dominant lithology was found in the study area. Physicochemical parameters interpreted by World Health Organization and Food and Agriculture Organization were well correlated with the aquifer parameters obtained by geoelectrical method and pumping tests. The aquifer potential zones identified by modeled resistivity, Dar Zarrouk parameters, pumped aquifer parameters, and physicochemical parameters reveal that sand and gravel sand with high values of transmissivity and hydraulic conductivity are highly promising water bearing layers in northwest of the study area. Strong correlation between estimated and pumped aquifer parameters suggest that, in case of sparse well data, geophysical technique is useful to estimate the hydraulic potential of the aquifer with varying lithology. © 2017, National Ground Water Association.
The White Sands Test Facility

NASA Technical Reports Server (NTRS)

1994-01-01

This is an overview of the White Sands Test Facility's role in ensuring the safety and reliability of materials and hardware slated for launch aboard the Space Shuttle. Engine firings, orbital flights debris impact tests, and propulsion tests are featured as well as illustrating how they provide flight safety testing for the Johnson Space Center, other NASA centers, and various government agencies. It also contains a historical perspective and highlights of major programs that have been participated in as part of NASA.
Performance validation of the ANSER control laws for the F-18 HARV

NASA Technical Reports Server (NTRS)

Messina, Michael D.

1995-01-01

The ANSER control laws were implemented in Ada by NASA Dryden for flight test on the High Alpha Research Vehicle (HARV). The Ada implementation was tested in the hardware-in-the-loop (HIL) simulation, and results were compared to those obtained with the NASA Langley batch Fortran implementation of the control laws which are considered the 'truth model.' This report documents the performance validation test results between these implementations. This report contains the ANSER performance validation test plan, HIL versus batch time-history comparisons, simulation scripts used to generate checkcases, and detailed analysis of discrepancies discovered during testing.
Performance validation of the ANSER Control Laws for the F-18 HARV

NASA Technical Reports Server (NTRS)

Messina, Michael D.

1995-01-01

The ANSER control laws were implemented in Ada by NASA Dryden for flight test on the High Alpha Research Vehicle (HARV). The Ada implementation was tested in the hardware-in-the-loop (HIL) simulation, and results were compared to those obtained with the NASA Langley batch Fortran implementation of the control laws which are considered the 'truth model'. This report documents the performance validation test results between these implementations. This report contains the ANSER performance validation test plan, HIL versus batch time-history comparisons, simulation scripts used to generate checkcases, and detailed analysis of discrepancies discovered during testing.
Impact of the New Abbott mPLUS Feature on Clinical Laboratory Efficiencies of Abbott RealTime Assays for Detection of HIV-1, Hepatitis C Virus, Hepatitis B Virus, Chlamydia trachomatis, and Neisseria gonorrhoeae

PubMed Central

Jones, Sara; Wiesneth, Russ; Barry, Cathy; Webb, Erika; Belova, Larissa; Dolan, Peggy; Ho, Shiaolan; Abravaya, Klara; Cloherty, Gavin

2013-01-01

Diagnostic laboratories are under increasing pressure to improve and expand their services. Greater flexibility in sample processing is a critical factor that can improve the time to results while reducing reagent waste, making laboratories more efficient and cost-effective. The introduction of the Abbott mPLUS feature, with the capacity for extended use of amplification reagents, significantly increases the flexibility of the m2000 platform and enables laboratories to customize their workflows based on sample arrival patterns. The flexibility in sample batch size offered by mPLUS enables significant reductions in processing times. For hepatitis B virus tests, a reduction in sample turnaround times of up to 30% (105 min) was observed for batches of 12 samples compared with those for batches of 24 samples; for Chlamydia trachomatis/Neisseria gonorrhoeae tests, the ability to run batches of 24 samples reduced the turnaround time by 83% (54 min) compared with that for batches of 48 samples. Excellent correlations between mPLUS and m2000 standard condition results were observed for all RealTime viral load assays evaluated in this study, with correlation r values of 0.998 for all assays tested. For the qualitative RealTime C. trachomatis/N. gonorrhoeae assay, the overall agreements between the two conditions tested were >98% for C. trachomatis and 100% for N. gonorrhoeae. Comparable precision results were observed for the two conditions tested for all RealTime assays. The enhanced mPLUS capability provides clinical laboratories with increased efficiencies to meet increasingly stringent turnaround time requirements without increased costs associated with discarding partially used amplification reagents. PMID:24088850
Impact of the New Abbott mPLUS feature on clinical laboratory efficiencies of abbott RealTime assays for detection of HIV-1, Hepatitis C Virus, Hepatitis B Virus, Chlamydia trachomatis, and Neisseria gonorrhoeae.

PubMed

Lucic, Danijela; Jones, Sara; Wiesneth, Russ; Barry, Cathy; Webb, Erika; Belova, Larissa; Dolan, Peggy; Ho, Shiaolan; Abravaya, Klara; Cloherty, Gavin

2013-12-01

Diagnostic laboratories are under increasing pressure to improve and expand their services. Greater flexibility in sample processing is a critical factor that can improve the time to results while reducing reagent waste, making laboratories more efficient and cost-effective. The introduction of the Abbott mPLUS feature, with the capacity for extended use of amplification reagents, significantly increases the flexibility of the m2000 platform and enables laboratories to customize their workflows based on sample arrival patterns. The flexibility in sample batch size offered by mPLUS enables significant reductions in processing times. For hepatitis B virus tests, a reduction in sample turnaround times of up to 30% (105 min) was observed for batches of 12 samples compared with those for batches of 24 samples; for Chlamydia trachomatis/Neisseria gonorrhoeae tests, the ability to run batches of 24 samples reduced the turnaround time by 83% (54 min) compared with that for batches of 48 samples. Excellent correlations between mPLUS and m2000 standard condition results were observed for all RealTime viral load assays evaluated in this study, with correlation r values of 0.998 for all assays tested. For the qualitative RealTime C. trachomatis/N. gonorrhoeae assay, the overall agreements between the two conditions tested were >98% for C. trachomatis and 100% for N. gonorrhoeae. Comparable precision results were observed for the two conditions tested for all RealTime assays. The enhanced mPLUS capability provides clinical laboratories with increased efficiencies to meet increasingly stringent turnaround time requirements without increased costs associated with discarding partially used amplification reagents.
Assessing the performance of multiplexed tandem PCR for the diagnosis of pathogenic genotypes of Theileria orientalis using pooled blood samples from cattle.

PubMed

Gebrekidan, Hagos; Gasser, Robin B; Stevenson, Mark A; McGrath, Sean; Jabbar, Abdul

2017-02-01

Oriental theileriosis caused by multiple genotypes of Theileria orientalis is an important tick-borne disease of bovines. Here, we assessed the performance of an established multiplexed tandem PCR (MT-PCR) for the diagnosis of the two recognized, pathogenic genotypes (chitose and ikeda) of T. orientalis in cattle using pooled blood samples. We used a total of 265 cattle blood samples, which were divided into two groups according to previous MT-PCR results for individual samples. Samples in group 1 (n = 155) were from a herd with a relatively high prevalence of T. orientalis infection; and those in group 2 (n = 110) were from four herds with a low prevalence. For group 1, 31 and 15 batches of five- and ten-pooled samples (selected at random), respectively, were formed. For group 2, 22 and 11 batches of five- and ten-pooled samples (selected at random), respectively, were formed. DNAs from individual pooled samples in each batch and group were then tested by MT-PCR. For group 1, the apparent prevalences estimated using the 31 batches of five-pooled samples (97%) and 15 batches of ten-pooled samples (100%) were significantly higher compared with individual samples (75%). For group 2, higher apparent prevalences (9% and 36%) were also recorded for the 22 and 11 batches of pooled samples, respectively, compared with individual samples (7%). Overall, the average infection intensity recorded for the genotypes of chitose and ikeda were considerably lower in pooled compared with individual samples. The diagnostic specificities of MT-PCR were estimated at 95% and 94%, respectively, when batches of five- and ten-pooled samples were tested, and 94% for individual samples. The diagnostic sensitivity of this assay was estimated at 98% same for all individual, five- and ten-pooled samples. This study shows that screening batches of five- and ten-pooled blood samples from cattle herds are similar to those obtained for individual samples, and, importantly, that the reduced cost for the testing of pooled samples represents a considerable saving to herd managers. Copyright © 2016 Elsevier Ltd. All rights reserved.
Engineered Option Treatment of Remediated Nitrate Salts: Surrogate Batch-Blending Testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anast, Kurt Roy

2016-03-11

This report provides results from batch-blending test work for remediated nitrate salt (RNS) treatment. Batch blending was identified as a preferred option for blending RNS and unremediated nitrate salt (UNS) material with zeolite to effectively safe the salt/Swheat material identified as ignitable (U.S. Environmental Protection Agency code D001). Blending with zeolite was the preferred remediation option identified in the Options Assessment Report and was originally proposed as the best option for remediation by Clark and Funk in their report, Chemical Reactivity and Recommended Remediation Strategy for Los Alamos Remediated Nitrate Salt (RNS) Wastes, and also found to be a preferredmore » option in the Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing. This test work evaluated equipment and recipe alternatives to achieve effective blending of surrogate waste with zeolite.« less
Seismotectonic implications of sand blows in the southern Mississippi Embayment

USGS Publications Warehouse

Cox, R.T.; Hill, A.A.; Larsen, D.; Holzer, T.; Forman, S.L.; Noce, T.; Gardner, C.; Morat, J.

2007-01-01

We explore seismically-induced sand blows from the southern Mississippi Embayment and their implications in resolving the question of near or distal epicentral source region. This was accomplished using aerial photography, field excavations, and cone penetration tests. Our analysis shows that three sand blow fields exhibit a distinct chronology of strong ground motion for the southern embayment: (1) The Ashley County, Arkansas sand blow field, near the Arkansas/Louisiana state border, experienced four Holocene sand venting episodes; (2) to the north, the Desha County field experienced at least three episodes of liquefaction; and (3) the Lincoln-Jefferson Counties field experienced at least one episode. Cone penetration tests (CPT) conducted in and between the sand blow fields suggest that the fields may not be distal liquefaction associated with New Madrid seismic zone earthquakes but rather are likely associated with strong earthquakes on local faults. This conclusion is consistent with the differences in timing of the southern embayment sand venting episodes and those in the New Madrid seismic zone. These results suggest that active tectonism and strong seismicity in intraplate North America may not be localized at isolated weak spots, but rather widespread on fault systems that are favorably oriented for slip in the contemporary stress field. ?? 2006 Elsevier B.V. All rights reserved.
A direct comparison of U.S. Environmental Protection Agency's method 304B and batch tests for determining activated-sludge biodegradation rate constants for volatile organic compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cano, M.L.; Wilcox, M.E.; Compernolle, R. van

Biodegradation rate constants for volatile organic compounds (VOCs) in activated-sludge systems are needed to quantify emissions. One current US environmental Protection Agency method for determining a biodegradation rate constant is Method 304B. In this approach, a specific activated-sludge unit is simulated by a continuous biological treatment system with a sealed headspace. Batch experiments, however, can be alternatives to Method 304B. Two of these batch methods are the batch test that uses oxygen addition (BOX) and the serum bottle test (SBT). In this study, Method 304B was directly compared to BOX and SBT experiments. A pilot-scale laboratory reactor was constructed tomore » serve as the Method 304B unit. Biomass from the unit was also used to conduct BOX and modified SBT experiments (modification involved use of a sealed draft-tube reactor with a headspace recirculation pump instead of a serum bottle) for 1,2-dichloroethane, diisopropyl ether, methyl tertiary butyl ether, and toluene. Three experimental runs--each consisting of one Method 304B experiment, one BOX experiment, and one modified SBT experiment--were completed. The BOX and SBT data for each run were analyzed using a Monod model, and best-fit biodegradation kinetic parameters were determined for each experiment, including a first-order biodegradation rate constant (K{sub 1}). Experimental results suggest that for readily biodegradable VOCs the two batch techniques can provide improved means of determining biodegradation rate constants compared with Method 304B. In particular, these batch techniques avoid the Method 304B problem associated with steady-state effluent concentrations below analytical detection limits. However, experimental results also suggest that the two batch techniques should not be used to determine biodegradation rate constants for slowly degraded VOCs (i.e., K{sub 1} {lt} 0.1 L/g VSS-h).« less
NE TARDIS Banner Event

NASA Image and Video Library

2017-12-08

Workers sign the banner marking the successful delivery of a liquid oxygen test tank, called Tardis, in the Prototype Development Laboratory at NASA's Kennedy Space Center in Florida. Engineers and technicians worked together to develop the tank and build it at the lab to support cryogenic testing at Johnson Space Center's White Sands Test Facility in Las Cruces, New Mexico. The 12-foot-tall, 3,810-pound aluminum tank will be shipped to White Sands for testing.
Effect of compost-, sand-, or gypsum-amended waste foundry sands on turfgrass yield and nutrient content

USDA-ARS?s Scientific Manuscript database

To prevent the 7-11 million metric tons of waste foundry sand (WFS) produced annually in the U.S. from entering landfills, current research is focused on the reuse of WFSs as soil amendments. The effects of different WFS-containing amendments on turfgrass growth and nutrient content were tested by ...
The Sand Yacht Challenge...Inspires Lots of Science

ERIC Educational Resources Information Center

James, Robin

2018-01-01

In this article, Robin James describes the Sand Yacht Challenge. The race took place on sand between small, wind-powered land yachts made by groups of children from four local schools. The project provided a term of collaborative opportunities at the designing and testing stage, followed by a competition when the students raced them. It was…
USE OF PRETREATMENT ZONES AND ZERO-VALENT IRON FOR THE REMEDIATION OF CHLOROALKENES IN AN OXIC AQUIFER

EPA Science Inventory

Pre-treatment zones (PTZs) composed of sand, 10% zero-valent iron [Fe(0)]/sand, and 10% pyrite (FeS2)/sand were examined for their ability to prolong Fe(0) reactivity in aboveground column reactors and a subsurface permeable reactive barrier (PRB). The test site had an acidic, o...
Investigation of guided waves propagation in pipe buried in sand

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leinov, Eli; Cawley, Peter; Lowe, Michael J.S.

The inspection of pipelines by guided wave testing is a well-established method for the detection of corrosion defects in pipelines, and is currently used routinely in a variety of industries, e.g. petrochemical and energy. When the method is applied to pipes buried in soil, test ranges tend to be significantly compromised because of attenuation of the waves caused by energy radiating into the soil. Moreover, the variability of soil conditions dictates different attenuation characteristics, which in-turn results in different, unpredictable, test ranges. We investigate experimentally the propagation and attenuation characteristics of guided waves in pipes buried in fine sand usingmore » a well characterized full scale experimental apparatus. The apparatus consists of an 8 inch-diameter, 5.6-meters long steel pipe embedded over 3 meters of its length in a rectangular container filled with fine sand, and an air-bladder for the application of overburden pressure. Longitudinal and torsional guided waves are excited in the pipe and recorded using a transducer ring (Guided Ultrasonics Ltd). Acoustic properties of the sand are measured independently in-situ and used to make model predictions of wave behavior in the buried pipe. We present the methodology and the systematic measurements of the guided waves under a range of conditions, including loose and compacted sand. It is found that the application of overburden pressure modifies the compaction of the sand and increases the attenuation, and that the measurement of the acoustic properties of sand allows model prediction of the attenuation of guided waves in buried pipes with a high level of confidence.« less

Design of a single batch leaching test to assess the environmental impact of volcanic ash

NASA Astrophysics Data System (ADS)

Fernandez-Turiel, J.; Ruggieri, F.; Saavedra, J.; Gimeno, D.; Martinez, L.; Galindo, G.; Garcia-Valles, M.; Polanco, E.; Perez-Torrado, F.; Rodriguez-Gonzalez, A.; Rodriguez-Fernandez, D.

2010-12-01

Most of the environmentally mobile constituents of volcanic ashes may be detected by one stage batch leaching tests, but the lack of a standardized procedure makes difficult the comparison between different studies. A series of batch tests were conducted using rhyolithic Andean ashes of the Chaiten 2008 eruption (Chile) and an ancient (hundreds of thousands of years) eruption in the southern Puna (NW Argentina) in order to propose a batch test susceptible of harmonization for volcanic ash. Tests carried out varying amount of ash (0.1 and 1 g), leachant volume (1, 2, 5, 10, 25 and 50 ml of deionized water) and contact time (1.5, 4 and 16 h). The mixture of ash and leachant was shaken at 20 rpm at room temperature in polypropylene test tubes (14x100 mm) or polyethylene (HDPE) reactors (50 and 100 ml), depending on the leachate volume. Leachate solutions, previous centrifugation (3000 rpm) during 15 minutes, were filtered through PVDF syringe filters with tube tip (25 mm diameter and 0.45 µm pore size) and made up to 100 ml volume in 1% (v/v) HNO3. These solutions were analyzed by ICP-OES, ICP-MS and ISE (fluoride). Leaching tests with 0.1 g of ash have a low reproducibility of results whereas leachant volume has not a great influence on the element contents released when 1 g of sample is employed. Batch leaching tests performed at 1.5 and 16 h are less reproducible that those tested at 4 h. The best batch leaching conditions tested correspond to 1 g of ash and 10 ml of deionized water shaking during 4 h. This methodology has been applied to recent and historical eruptions of the Southern Volcanic Zone of the Andes (Quizapu, 1932; Lonquimay, 1988; Hudson, 1991; Copahue, 2000; Llaima 2008; Chaiten 2008), the Central Volcanic Zone of the Andes (Quaternary ashes of different eruptions in southern Puna and neighboring areas in northwestern Argentina), and the recent eruption of Eyjafjallajokull (april-may 2010) in Iceland. The method developed is reproducible, fast and reliable in laboratory conditions and the results easily applicable to environmental impact models. This study was carried out in the framework of the PEGEFA Working Group (Catalonian Government 2009-SGR-972), and was funded by the Project ASH of the Spanish MICINN (CGL2008-00099) and the FPU Grant of the Spanish Ministry of Education of one of the authors (F. Ruggieri, Ref. AP2006-04592).
Influence of pore structure on compressive strength of cement mortar.

PubMed

Zhao, Haitao; Xiao, Qi; Huang, Donghui; Zhang, Shiping

2014-01-01

This paper describes an experimental investigation into the pore structure of cement mortar using mercury porosimeter. Ordinary Portland cement, manufactured sand, and natural sand were used. The porosity of the manufactured sand mortar is higher than that of natural sand at the same mix proportion; on the contrary, the probable pore size and threshold radius of manufactured sand mortar are finer. Besides, the probable pore size and threshold radius increased with increasing water to cement ratio and sand to cement ratio. In addition, the existing models of pore size distribution of cement-based materials have been reviewed and compared with test results in this paper. Finally, the extended Bhattacharjee model was built to examine the relationship between compressive strength and pore structure.
Influence of Pore Structure on Compressive Strength of Cement Mortar

PubMed Central

Zhao, Haitao; Xiao, Qi; Huang, Donghui

2014-01-01

This paper describes an experimental investigation into the pore structure of cement mortar using mercury porosimeter. Ordinary Portland cement, manufactured sand, and natural sand were used. The porosity of the manufactured sand mortar is higher than that of natural sand at the same mix proportion; on the contrary, the probable pore size and threshold radius of manufactured sand mortar are finer. Besides, the probable pore size and threshold radius increased with increasing water to cement ratio and sand to cement ratio. In addition, the existing models of pore size distribution of cement-based materials have been reviewed and compared with test results in this paper. Finally, the extended Bhattacharjee model was built to examine the relationship between compressive strength and pore structure. PMID:24757414
Results of Hg speciation testing on DWPF SMECT-8, OGCT-1, AND OGCT-2 samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bannochie, C.

2016-02-22

The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The sixteenth shipment of samples was designated to include a Defense Waste Processing Facility (DWPF) Slurry Mix Evaporator Condensate Tank (SMECT) sample from Sludge Receipt and Adjustment Tank (SRAT) Batch 738 processing and two Off-Gas Condensate Tank (OGCT) samples, one following Batch 736 and one following Batch 738. The DWPF sample designations for the three samples analyzed are provided. The Batch 738 ‘End ofmore » SME Cycle’ SMECT sample was taken at the conclusion of Slurry Mix Evaporator (SME) operations for this batch and represents the fourth SMECT sample examined from Batch 738. Batch 738 experienced a sludge slurry carryover event, which introduced sludge solids to the SMECT that were particularly evident in the SMECT-5 sample, but less evident in the ‘End of SME Cycle’ SMECT-8 sample.« less
Development of a mathematical model for the growth associated Polyhydroxybutyrate fermentation by Azohydromonas australica and its use for the design of fed-batch cultivation strategies.

PubMed

Gahlawat, Geeta; Srivastava, Ashok K

2013-06-01

In the present investigation, batch cultivation of Azohydromonas australica DSM 1124 was carried out in a bioreactor for growth associated PHB production. The observed batch PHB production kinetics data was then used for the development of a mathematical model which adequately described the substrate limitation and inhibition during the cultivation. The statistical validity test demonstrated that the proposed mathematical model predictions were significant at 99% confidence level. The model was thereafter extrapolated to fed-batch to identify various nutrients feeding regimes during the bioreactor cultivation to improve the PHB accumulation. The distinct capability of the mathematical model to predict highly dynamic fed-batch cultivation strategies was demonstrated by experimental implementation of two fed-batch cultivation strategies. A significantly high PHB concentration of 22.65 g/L & an overall PHB content of 76% was achieved during constant feed rate fed-batch cultivation which is the highest PHB content reported so far using A. australica. Copyright © 2013 Elsevier Ltd. All rights reserved.
Implementation of a repeated fed-batch process for the production of chitin-glucan complex by Komagataella pastoris.

PubMed

Farinha, Inês; Freitas, Filomena; Reis, Maria A M

2017-07-25

The yeast Komagataella pastoris was cultivated under different fed-batch strategies for the production of chitin-glucan complex (CGC), a co-polymer of chitin and β-glucan. The tested fed-batch strategies included DO-stat mode, predefined feeding profile and repeated fed-batch operation. Although high cell dry mass and high CGC production were obtained under the tested DO-stat strategy in a 94h cultivation (159 and 29g/L, respectively), the overall biomass and CGC productivities were low (41 and 7.4g/Lday, respectively). Cultivation with a predefined profile significantly improved both biomass and CGC volumetric productivity (87 and 10.8g/Lday, respectively). Hence, this strategy was used to implement a repeated fed-batch process comprising 7 consecutive cycles. A daily production of 119-126g/L of biomass with a CGC content of 11-16wt% was obtained, thus proving this cultivation strategy is adequate to reach a high CGC productivity that ranged between 11 and 18g/Lday. The process was stable and reproducible in terms of CGC productivity and polymer composition, making it a promising strategy for further process development. Copyright © 2016 Elsevier B.V. All rights reserved.
A high-throughput media design approach for high performance mammalian fed-batch cultures

PubMed Central

Rouiller, Yolande; Périlleux, Arnaud; Collet, Natacha; Jordan, Martin; Stettler, Matthieu; Broly, Hervé

2013-01-01

An innovative high-throughput medium development method based on media blending was successfully used to improve the performance of a Chinese hamster ovary fed-batch medium in shaking 96-deepwell plates. Starting from a proprietary chemically-defined medium, 16 formulations testing 43 of 47 components at 3 different levels were designed. Media blending was performed following a custom-made mixture design of experiments considering binary blends, resulting in 376 different blends that were tested during both cell expansion and fed-batch production phases in one single experiment. Three approaches were chosen to provide the best output of the large amount of data obtained. A simple ranking of conditions was first used as a quick approach to select new formulations with promising features. Then, prediction of the best mixes was done to maximize both growth and titer using the Design Expert software. Finally, a multivariate analysis enabled identification of individual potential critical components for further optimization. Applying this high-throughput method on a fed-batch, rather than on a simple batch, process opens new perspectives for medium and feed development that enables identification of an optimized process in a short time frame. PMID:23563583
PHYTO-REMOVAL OF TRINITROTOLUENE FROM WATER WITH BATCH KINETIC STUDIES

EPA Science Inventory

A series of batch reactor studies were conducted to obtain kinetic data for optimizing phyto-treatment of water contaminated with trinitrotoluene (TNT). A plant screening study indicated that stonewort and parrotfeather were the most effective among the plants tested; parrotfeath...
Evaluating Impacts of CO2 Gas Intrusion Into a Confined Sandstone aquifer: Experimental Results

DOE PAGES

Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; ...

2014-12-31

Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnershipmore » Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.« less
LARGE-SCALE NATURAL GRADIENT TRACER TEST IN SAND AND GRAVEL, CAPE CODE, MASSACHUSETTS 3. HYDRAULIC CONDUCTI- VITY AND CALCULATED MACRODISPERSIVITIES

EPA Science Inventory

Hydraulic conductivity (K) variability in a sand and gravel aquifer on Cape Cod, Massachusetts, was measured and subsequently used in stochastic transport theories to estimate macrodispersivities. Nearly 1500 K measurements were obtained by borehole flowmeter tests ...
Weather resistance of CaSO4 ṡ 1/2H2O-based sand-fixation material

NASA Astrophysics Data System (ADS)

Liu, Xin; Tie, Shengnian

2017-07-01

Searching for an economical and effective sand-fixing material and technology is of great importance in Northwest China. This paper described the use of a semihydrated gypsum-(CaSO4 ṡ 1/2H2O-)based composite as a sand-fixing material. Its morphology and composition were characterized by SEM, and its water resistance, freezing-thawing resistance and wind erosion resistance were tested in the field. The results indicated that semihydrated gypsum-(CaSO4 ṡ 1/2H2O-)based sand-fixing composite has good water resistance and water-holding capacity. Its strength is maintained at 1.42 MPa after 50 freezing and thawing cycles, and its wind erosion increases with increasing wind speed and slope. Its compressive strength starts to decrease after nine months of field tests with no change in appearance, but it still satisfies the requirements of fixation technology. This sand-fixing material should have wide application owing to its good weather resistance.
Experimental Study on Artificial Cemented Sand Prepared with Ordinary Portland Cement with Different Contents.

PubMed

Li, Dongliang; Liu, Xinrong; Liu, Xianshan

2015-07-02

Artificial cemented sand test samples were prepared by using ordinary Portland cement (OPC) as the cementing agent. Through uniaxial compression tests and consolidated drained triaxial compression tests, the stress-strain curves of the artificial cemented sand with different cementing agent contents (0.01, 0.03, 0.05 and 0.08) under various confining pressures (0.00 MPa, 0.25 MPa, 0.50 MPa and 1.00 MPa) were obtained. Based on the test results, the effect of the cementing agent content ( C v ) on the physical and mechanical properties of the artificial cemented sand were analyzed and the Mohr-Coulomb strength theory was modified by using C v . The research reveals that when C v is high (e.g., C v = 0.03, 0.05 or 0.08), the stress-strain curves of the samples indicate a strain softening behavior; under the same confining pressure, as C v increases, both the peak strength and residual strength of the samples show a significant increase. When C v is low (e.g., C v = 0.01), the stress-strain curves of the samples indicate strain hardening behavior. From the test data, a function of C v (the cementing agent content) with c ' (the cohesion force of the sample) and Δϕ' (the increment of the angle of shearing resistance) is obtained. Furthermore, through modification of the Mohr-Coulomb strength theory, the effect of cementing agent content on the strength of the cemented sand is demonstrated.
Collaborative study for the calibration of the Ph. Eur. prekallikrein activator in albumin BRP batches 4, 5 and 6.

PubMed

Lackner, F; Daas, A; Terao, E

2015-01-01

An international collaborative study was organised by the European Directorate for the Quality of Medicines & HealthCare (EDQM, Council of Europe) to calibrate replacement batches for the current European Pharmacopoeia (Ph. Eur.) prekallikrein activator (PKA) in albumin biological reference preparation (BRP), whose stocks were dwindling. The study was run in the framework of the Biological Standardisation Programme (BSP) of the Council of Europe and the European Union (EU) Commission. Twenty three laboratories from official medicines control authorities and manufacturers in Europe and outside Europe took part in the study. Three candidate replacement batches were produced from the same material as the one used for the World Health Organization (WHO) 2(nd) International Standard (IS) for PKA in albumin (02/168) and the Ph. Eur. PKA in albumin BRP batches 1, 2 and 3. Participants were requested to evaluate the candidate batches against the current WHO IS using their routine assay method. The Ph. Eur. PKA in albumin BRP batch 3 (BRP3) was also included in the test panel to ensure the continuity of the consecutive BRP batches. The study confirmed the stability of the PKA content of the current BRP3. The candidate batches were found to be comparable. Previous data on the starting material support its high stability. Thermal stress study on the candidate batches confirmed the stability of their PKA activity. The Commission of the Ph. Eur. officially adopted in November 2013 the 3 candidate batches as Ph. Eur. PKA in albumin BRP batches 4, 5 and 6 with an assigned content of 38 IU/vial. The activity of the 3 new batches of Ph. Eur. PKA in albumin BRP will be regularly monitored.
Geomagnetic model investigations for 1980 - 1989: A model for strategic defense initiative particle beam experiments and a study in the effects of data types and observatory bias solutions

NASA Technical Reports Server (NTRS)

Langel, Robert A.; Sabaka, T. J.; Baldwin, R. T.

1991-01-01

Two suites of geomagnetic field models were generated at the request of Los Alamos National Lab. concerning Strategic Defense Initiative (SDI) research. The first is a progression of five models incorporating MAGSAT data and data from a sequence of batches as a priori information. The batch sequence is: post 1979.5 observatory data, post 1980 land survey and selected aeromagnetic and marine survey data, a special White Sands (NM) area survey by Project Magnet with some additional post 1980 marine survey data, and finally DE-2 satellite data. These models are of 13th deg and order in their main field terms, and deg and order 10 in their first derivative temporal terms. The second suite consists of four models based solely upon post 1983.5 observatory and survey data. They are of deg and order 10 in main field and 8 in a first deg Taylor series. A comprehensive error analysis was applied to both series, which accounted for error sources such as the truncated core and crustal fields, and the neglected Sq and low deg crustal fields. Comparison of the power spectrum of the MGST (10/81) model with those of this series show good agreement.
Laboratory evidence of MTBE biodegradation in Borden aquifer material

NASA Astrophysics Data System (ADS)

Schirmer, Mario; Butler, Barbara J.; Church, Clinton D.; Barker, James F.; Nadarajah, Nalina

2003-02-01

Mainly due to intrinsic biodegradation, monitored natural attenuation can be an effective and inexpensive remediation strategy at petroleum release sites. However, gasoline additives such as methyl tert-butyl ether (MTBE) can jeopardize this strategy because these compounds often degrade, if at all, at a slower rate than the collectively benzene, toluene, ethylbenzene and the xylene (BTEX) compounds. Investigation of whether a compound degrades under certain conditions, and at what rate, is therefore important to the assessment of the intrinsic remediation potential of aquifers. A natural gradient experiment with dissolved MTBE-containing gasoline in the shallow, aerobic sand aquifer at Canadian Forces Base (CFB) Borden (Ontario, Canada) from 1988 to 1996 suggested that biodegradation was the main cause of attenuation for MTBE within the aquifer. This laboratory study demonstrates biologically catalyzed MTBE degradation in Borden aquifer-like environments, and so supports the idea that attenuation due to biodegradation may have occurred in the natural gradient experiment. In an experiment with batch microcosms of aquifer material, three of the microcosms ultimately degraded MTBE to below detection, although this required more than 189 days (or >300 days in one case). Failure to detect the daughter product tert-butyl alcohol (TBA) in the field and the batch experiments could be because TBA was more readily degradable than MTBE under Borden conditions.
Cyclodextrin-enhanced solubilization and removal of residual-phase chlorinated solvents from porous media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boving, T.B.; Wang, X.; Brusseau, M.L.

1999-03-01

The development of improved methods for remediation of contaminated aquifers has emerged as a significant environmental priority. One technology that appears to have considerable promise involves the use of solubilization agents such as surfactants and cosolvents for enhancing the removal of residual phase immiscible liquids. The authors examined the use of cyclodextrin, a glucose-based molecule, for solubilizing and removing residual-phase immiscible liquid from porous media. Batch experiments were conducted to measure the degree of trichloroethene (TCE) and tetrachloroethene (PCE) solubilization induced by hydroxypropyl-{beta}-cyclodextrin (HPCD) and methyl-{beta}-cyclodextrin (MCD). These studies revealed that the solubilities of TCE and PCE were enhanced bymore » up to 9.5 and 36.0 times, respectively. Column experiments were conducted to compare water and cyclodextrin-enhanced flushing of Borden sand containing residual saturations of TCE and PCE. The results indicate that solubilization and mass removal were enhanced substantially with the use of cyclodextrins. The effluent concentrations during the steady-state phase of the HPCD and MCD flushing experiments were close to the apparent solubilities measured with the batch experiments, indicating equilibrium concentrations were maintained during the initial phase of cyclodextrin flushing. Mobilization was observed for only the TCE-MCD and PCE-5%MCD experiments.« less
BIOLAB experiment development status 2005

NASA Astrophysics Data System (ADS)

Brinckmann, Enno; Manieri, Pierfilippo

2005-08-01

BIOLAB, ESA's major facility for biological Space research on the International Space Station (ISS), will accommodate the first two batches of experiments after its launch with the "Columbus" Laboratory (spring 2007). Seven experiments have been selected for development: three of the first batch have concluded Phase A/B with the testing of the breadboards, in which the main functions of the scientific studies can be simulated and defined for further inputs to the final design of the experiment hardware. The biological specimens of the first batch are scorpions, plant seedlings, bacteria suspensions and cell cultures of mammalian and invertebrate origin. The experiment protocols request demanding resources ranging from life support for the entire mission (90 days) to skilled crew operations and transport/storage in deep freezers. Even more sophisticated experiments are in preparation for the second batch, dealing with various cell culture systems. This presentation gives an overview about the experiment development status, whilst the science background and breadboard test results will be presented by the respective experiment teams.
Sequencing batch-reactor control using Gaussian-process models.

PubMed

Kocijan, Juš; Hvala, Nadja

2013-06-01

This paper presents a Gaussian-process (GP) model for the design of sequencing batch-reactor (SBR) control for wastewater treatment. The GP model is a probabilistic, nonparametric model with uncertainty predictions. In the case of SBR control, it is used for the on-line optimisation of the batch-phases duration. The control algorithm follows the course of the indirect process variables (pH, redox potential and dissolved oxygen concentration) and recognises the characteristic patterns in their time profile. The control algorithm uses GP-based regression to smooth the signals and GP-based classification for the pattern recognition. When tested on the signals from an SBR laboratory pilot plant, the control algorithm provided a satisfactory agreement between the proposed completion times and the actual termination times of the biodegradation processes. In a set of tested batches the final ammonia and nitrate concentrations were below 1 and 0.5 mg L(-1), respectively, while the aeration time was shortened considerably. Copyright © 2013 Elsevier Ltd. All rights reserved.
The influence of sorbitol on the production of cellulases and xylanases in an airlift bioreactor.

PubMed

Ritter, Carla Eliana Todero; Fontana, Roselei Claudete; Camassola, Marli; da Silveira, Maurício Moura; Dillon, Aldo José Pinheiro

2013-11-01

The production of cellulases and xylanases by Penicillium echinulatum in an airlift bioreactor was evaluated. In batch production, we tested media with isolated or associated cellulose and sorbitol. In fed-batch production, we tested cellulose addition at two different times, 30 h and 48 h. Higher liquid circulation velocities in the downcomer were observed in sorbitol 10 g L(-1) medium. In batch production, higher FPA (filter paper activity) and endoglucanase activities were obtained with cellulose (7.5 g L(-1)) and sorbitol (2.5 g L(-1)), 1.0 U mL(-1) (120 h) and 6.4 U m L(-1) (100 h), respectively. For xylanases, the best production condition was cellulose 10 g L(-1), which achieved 5.5 U mL(-1) in 64 h. The fed-batch process was favorable for obtaining xylanases, but not for FPA and endoglucanases, suggesting that in the case of cellulases, the inducer must be added early in the process. Copyright © 2013 Elsevier Ltd. All rights reserved.
Different cultivation methods to acclimatise ammonia-tolerant methanogenic consortia.

PubMed

Tian, Hailin; Fotidis, Ioannis A; Mancini, Enrico; Angelidaki, Irini

2017-05-01

Bioaugmentation with ammonia tolerant-methanogenic consortia was proposed as a solution to overcome ammonia inhibition during anaerobic digestion process recently. However, appropriate technology to generate ammonia tolerant methanogenic consortia is still lacking. In this study, three basic reactors (i.e. batch, fed-batch and continuous stirred-tank reactors (CSTR)) operated at mesophilic (37°C) and thermophilic (55°C) conditions were assessed, based on methane production efficiency, incubation time, TAN/FAN (total ammonium nitrogen/free ammonia nitrogen) levels and maximum methanogenic activity. Overall, fed-batch cultivation was clearly the most efficient method compared to batch and CSTR. Specifically, by saving incubation time up to 150%, fed-batch reactors were acclimatised to nearly 2-fold higher FAN levels with a 37%-153% methanogenic activity improvement, compared to batch method. Meanwhile, CSTR reactors were inhibited at lower ammonia levels. Finally, specific methanogenic activity test showed that hydrogenotrophic methanogens were more active than aceticlastic methanogens in all FAN levels above 540mgNH 3 -NL -1 . Copyright © 2017 Elsevier Ltd. All rights reserved.

NE TARDIS Banner Event

NASA Image and Video Library

2017-12-08

A liquid oxygen test tank was completed in the Prototype Development Laboratory at NASA's Kennedy Space Center in Florida. A banner signing event marked the successful delivery of the tank called Tardis. Engineers and technicians worked together to develop the tank and build it at the lab to support cryogenic testing at Johnson Space Center's White Sands Test Facility in Las Cruces, New Mexico. The 12-foot-tall, 3,810-pound aluminum tank will be shipped to White Sands for testing.
NE TARDIS Banner Event

NASA Image and Video Library

2017-12-08

Inside the Prototype Development Laboratory at NASA's Kennedy Space Center in Florida, workers in the lab hold a banner marking the successful delivery of a liquid oxygen test tank called Tardis. Engineers and technicians worked together to develop the tank to build it at the lab to support cryogenic testing at Johnson Space Center's White Sands Test Facility in Las Cruces, New Mexico. The 12-foot-tall, 3,810-pound aluminum tank will be shipped to White Sands for testing.
Establishment of hepatitis A detection antibodies set BRR batch 3 for antigen content determination by ELISA.

PubMed

Morgeaux, S; Manniam, I; Variot, P; Daas, A; Costanzo, A

2015-01-01

The current batch of the European Pharmacopoeia (Ph. Eur.) Biological Reference Reagents (BRRs) used for the in vitro potency assay of hepatitis A vaccines (HAV) by ELISA (enzymelinked immunosorbent assay) was established in 2012 for use in conjunction with Ph. Eur. general chapter 2.7.14 Assay of hepatitis A vaccine. It is composed of a coating reagent and a set of detection antibodies. As stocks of the latter are running low, the European Directorate for the Quality of Medicines & HealthCare (EDQM) organised a collaborative study to qualify replacement batches. The candidate BRR antibodies (primary monoclonal antibody and labelled secondary antibody) were prepared under appropriate conditions from starting materials similar to those used for the current batches. The new batches of antibodies were tested alongside previous batches of BRRs to ensure continuity, and the results confirmed that they were suitable for use in the potency assay of hepatitis A vaccines by ELISA using the standard method referenced in Ph. Eur. general chapter 2.7.14 at the same final concentrations as the previous batches, i.e. 1:500 for the primary monoclonal antibody and 1:400 for the secondary conjugated antibody. The outcome of the study allowed their establishment by the Ph. Eur. Commission in March 2015 as anti-hepatitis A virus primary detection antibody BRR batch 3 and conjugated secondary detection antibody BRR batch 3 respectively. They are available from the EDQM as hepatitis A vaccine ELISA detection antibodies set BRR batch 3.
Use of Carboxymethyl-beta-cyclodextrin (CMCD) as Flushing Agent for Remediation of Metal Contaminated Soil

NASA Astrophysics Data System (ADS)

Skold, M. E.; Thyne, G. D.; McCray, J. E.; Drexler, J. W.

2005-12-01

One of the major challenges in remediating soil and ground water is the presence of mixed organic and inorganic contaminants. Due to their very different behavior, research has to a large extent focused on remediation of either organic or inorganic contaminants rather than mixed waste. Cyclodextrins (CDs) are a group of non-toxic sugar based molecules that do not sorb to soil particles and do not experience pore size exclusion. Thus, they have good hydraulic properties. CDs enhance the solubility of organic compounds by forming inclusion complexes between organic contaminants and the non-polar cavity at the center of the CD. By substituting functional groups to the cyclodextrin molecule it can form complexes with heavy metals. Previous studies have shown that carboxymethyl-beta-cyclodextrin (CMCD) can simultaneously complex organic and inorganic contaminants. The aim of this study is to compare how strongly CMCD complexes several common heavy metals, radioactive elements and a common divalent cation. Results from batch experiments show that CMCD has the ability to complex a wide array of heavy metals and radioactive elements. The solubility of metal oxalates and metal oxides clearly increased in the presence of CMCD. Logarithmic conditional formation constants ranged from 3.5 to 6 for heavy metals and from 3 to 6 for radioactive elements. Calcium, which may compete for binding sites, has a logarithmic conditional formation constant of 3.1. Batch experiments performed at 10 and 25 degrees C showed little temperature effect on conditional formation constants. Results from batch experiments were compared to results from column experiments where Pb was sorbed onto hydrous ferric oxide coated sand and subsequently removed by a CMCD solution. The results indicate that CMCD is a potential flushing agent for remediation of mixed waste sites.
Shake table test of soil-pile groups-bridge structure interaction in liquefiable ground

NASA Astrophysics Data System (ADS)

Tang, Liang; Ling, Xianzhang; Xu, Pengju; Gao, Xia; Wang, Dongsheng

2010-03-01

This paper describes a shake table test study on the seismic response of low-cap pile groups and a bridge structure in liquefiable ground. The soil profile, contained in a large-scale laminar shear box, consisted of a horizontally saturated sand layer overlaid with a silty clay layer, with the simulated low-cap pile groups embedded. The container was excited in three El Centro earthquake events of different levels. Test results indicate that excessive pore pressure (EPP) during slight shaking only slightly accumulated, and the accumulation mainly occurred during strong shaking. The EPP was gradually enhanced as the amplitude and duration of the input acceleration increased. The acceleration response of the sand was remarkably influenced by soil liquefaction. As soil liquefaction occurred, the peak sand displacement gradually lagged behind the input acceleration; meanwhile, the sand displacement exhibited an increasing effect on the bending moment of the pile, and acceleration responses of the pile and the sand layer gradually changed from decreasing to increasing in the vertical direction from the bottom to the top. A jump variation of the bending moment on the pile was observed near the soil interface in all three input earthquake events. It is thought that the shake table tests could provide the groundwork for further seismic performance studies of low-cap pile groups used in bridges located on liquefiable groun.
Effect of High-Intensity Wildfire and Silvicultural Treatments on Reptile Communities in Sand-Pine Scrub

Treesearch

Cathryn H. Greenberg; Daniel G. Neary; Larry D. Harris

1994-01-01

We tested whether the herpetofuunal response to clearcutting followed by site preparation was similar to high-intensity wildfire foIlowed by salvage logging in sand- pine scrub. Herpetofaunal communities were compared in three replicated 5- to 7-yearpost-disturbance treatments and mature sand-pine forest. The three disturbance treatments were (1) high-intensity...
Combination of bioaugmentation and biostimulation for remediation of paddy soil contaminated with 2,4-dichlorophenoxyacetic acid.

PubMed

Yang, Zhiman; Xu, Xiaohui; Dai, Meng; Wang, Lin; Shi, Xiaoshuang; Guo, Rongbo

2018-04-22

The batch and fed-batch tests were performed to evaluate the efficiency of bioaugmentation in combination with biostimulation for remediation of paddy soil contaminated with 2,4-dichlorophenoxyacetic acid (2,4-D). 2,4-D degrading enrichments were used for bioaugmentation, and effluents prepared through biological hydrogen production process were used as substrate for biostimulation. The batch tests indicated that 2,4-D degradation depended on the enrichment/substrate ratio (E/S), where E/S of 0.03 showed an excellent performance. The fed-batch tests showed that biostimulation only led to an improvement in 2,4-D degradation, while the pattern of repeated augmentation of enrichments (FRA) together with biostimulation obviously improved degradation of 2,4-D, 2-chlorophenol (2-CP) and phenol. DNA-sequencing approach showed that the FRA pattern altered the bacterial community composition, and high removal of 2,4-D, 2-CP and phenol may be attributed to the acclimation and persistence of Thauera. The findings demonstrated the importance of the FRA pattern on remediation of paddy soil contaminated with 2,4-D. Copyright © 2018 Elsevier B.V. All rights reserved.
Mathematical Model Relating Uniaxial Compressive Behavior of Manufactured Sand Mortar to MIP-Derived Pore Structure Parameters

PubMed Central

Tian, Zhenghong; Bu, Jingwu

2014-01-01

The uniaxial compression response of manufactured sand mortars proportioned using different water-cement ratio and sand-cement ratio is examined. Pore structure parameters such as porosity, threshold diameter, mean diameter, and total amounts of macropores, as well as shape and size of micropores are quantified by using mercury intrusion porosimetry (MIP) technique. Test results indicate that strains at peak stress and compressive strength decreased with the increasing sand-cement ratio due to insufficient binders to wrap up entire sand. A compression stress-strain model of normal concrete extending to predict the stress-strain relationships of manufactured sand mortar is verified and agreed well with experimental data. Furthermore, the stress-strain model constant is found to be influenced by threshold diameter, mean diameter, shape, and size of micropores. A mathematical model relating stress-strain model constants to the relevant pore structure parameters of manufactured sand mortar is developed. PMID:25133257
Mathematical model relating uniaxial compressive behavior of manufactured sand mortar to MIP-derived pore structure parameters.

PubMed

Tian, Zhenghong; Bu, Jingwu

2014-01-01

The uniaxial compression response of manufactured sand mortars proportioned using different water-cement ratio and sand-cement ratio is examined. Pore structure parameters such as porosity, threshold diameter, mean diameter, and total amounts of macropores, as well as shape and size of micropores are quantified by using mercury intrusion porosimetry (MIP) technique. Test results indicate that strains at peak stress and compressive strength decreased with the increasing sand-cement ratio due to insufficient binders to wrap up entire sand. A compression stress-strain model of normal concrete extending to predict the stress-strain relationships of manufactured sand mortar is verified and agreed well with experimental data. Furthermore, the stress-strain model constant is found to be influenced by threshold diameter, mean diameter, shape, and size of micropores. A mathematical model relating stress-strain model constants to the relevant pore structure parameters of manufactured sand mortar is developed.
A novel multiple batch extraction test to assess contaminant mobilization from porous waste materials

NASA Astrophysics Data System (ADS)

Iden, S. C.; Durner, W.; Delay, M.; Frimmel, F. H.

2009-04-01

Contaminated porous materials, like soils, dredged sediments or waste materials must be tested before they can be used as filling materials in order to minimize the risk of groundwater pollution. We applied a multiple batch extraction test at varying liquid-to-solid (L/S) ratios to a demolition waste material and a municipal waste incineration product and investigated the release of chloride, sulphate, sodium, copper, chromium and dissolved organic carbon from both waste materials. The liquid phase test concentrations were used to estimate parameters of a relatively simple mass balance model accounting for equilibrium partitioning. The model parameters were estimated within a Bayesian framework by applying an efficient MCMC sampler and the uncertainties of the model parameters and model predictions were quantified. We tested isotherms of the linear, Freundlich and Langmuir type and selected the optimal isotherm model by use of the Deviance Information Criterion (DIC). Both the excellent fit to the experimental data and a comparison between the model-predicted and independently measured concentrations at the L/S ratios of 0.25 and 0.5 L/kg demonstrate the applicability of the model for almost all studied substances and both waste materials. We conclude that batch extraction tests at varying L/S ratios provide, at moderate experimental cost, a powerful complement to established test designs like column leaching or single batch extraction tests. The method constitutes an important tool in risk assessments, because concentrations at soil water contents representative for the field situation can be predicted from easier-to-obtain test concentrations at larger L/S ratios. This helps to circumvent the experimental difficulties of the soil saturation extract and eliminates the need to apply statistical approaches to predict such representative concentrations which have been shown to suffer dramatically from poor correlations.
Corrosion Resistance of a Sand Particle-Modified Enamel Coating Applied to Smooth Steel Bars

PubMed Central

Tang, Fujian; Chen, Genda; Brow, Richard K.; Koenigstein, Michael L.

2014-01-01

The protective performance of a sand particle-modified enamel coating on reinforcing steel bars was evaluated in 3.5 wt% NaCl solution by electrochemical impedance spectroscopy (EIS). Seven percentages of sand particles by weight were investigated: 0%, 5%, 10%, 20%, 30%, 50% and 70%. The phase composition of the enamel coating and sand particles were determined with the X-ray diffraction (XRD) technique. The surface and cross-sectional morphologies of the sand particle-modified enamel coating were characterized using scanning electron microscopy (SEM). XRD tests revealed three phases of sand particles: SiO2, CaCO3 and MgCO3. SEM images demonstrated that the enamel coating wetted well with the sand particles. However, a weak enamel coating zone was formed around the sand particles due to concentrated air bubbles, leading to micro-cracks as hydrogen gas pressure builds up and exceeds the tensile strength of the weak zone. As a result, the addition of sand particles into the enamel coating reduced both the coating and corrosion resistances. PMID:28788203
Two-fold sustainability – Adobe with sawdust as partial sand replacement

NASA Astrophysics Data System (ADS)

Jokhio, Gul A.; Syed Mohsin, Sharifah M.; Gul, Yasmeen

2018-04-01

Adobe is a material that is economic, environment friendly, and provides better indoor air quality. The material required for the preparation of adobe include clay, sand, and sometimes straw or other organic materials. These materials do not require industrial processing or transportation, however, sand mining has been recently posing a threat to the environment. Therefore, to enhance the existing sustainability of adobe, sand can be partially or fully replaced by other waste materials. This approach will not only solve the problem of excessive sand mining, it will also address the issue of waste management. Sawdust is one such waste material that can be used to partially replace sand in Adobe. This paper presents the results of compressive and flexural test carried out on Adobe samples with partial sand replacement by sawdust. The results show that about 4% sand replacement by volume produces higher compressive strength, whereas the flexural strength reduces with the use of sawdust. However, since flexural strength is not a critical property for adobe, it is concluded that replacing sand with sawdust by about 4% of volume will be beneficial.
Non destructive testing of soft body armor

NASA Astrophysics Data System (ADS)

Bhise, Karan

Pristine bullet proof vests are extremely effective at halting pre-determined projectile threats and have saved over 3000 lives. However, the effectiveness of these vests to halt a bullet is seen to decrease over time.Owing to the importance of bullet proof vests over a period of time, tests to determine their effectiveness have been carried out on every batch of vests at the time of inception and at certain time intervals by shooting a bullet through them. A few vests from every batch are picked up and shot at to check for bullet penetration during this process while these results are extrapolated onto the other vests from the batch.One of the main issues with this method is the fact that testing a few jackets among a large set of jackets does not guarantee the safety of every jacket in the entire batch.Further the jackets that are shot-at have the possibility of undergoing substantial damage during the process thus compromising its safety rendering them unsafe for future use.As the vest penetration phenomenon is extremely complex too, there arose a need for a better testing procedure that could not only help ensure more safety, but also save time and money.The new testing procedure proposed a non-destructive evaluation of the jackets that would solve the issues previous faced in testing the vests. This would lead to the building of a portable set up which could be carried to any location to test jackets in a matter of minutes thus saving time and money.
Laboratory-scale integrated ARP filter test

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poirier, M.; Burket, P.

2016-03-01

The Savannah River Site (SRS) is currently treating radioactive liquid waste with the Actinide Removal Process (ARP) and the Modular Caustic Side Solvent Extraction Unit (MCU). Recently, the low filter flux through the ARP of approximately 5 gallons per minute has limited the rate at which radioactive liquid waste can be treated. Salt Batch 6 had a lower processing rate and required frequent filter cleaning. There is a desire to understand the causes of the low filter flux and to increase ARP/MCU throughput. This task attempted to simulate the entire ARP process, including multiple batches (5), washing, chemical cleaning, andmore » blending the feed with heels and recycle streams. The objective of the tests was to determine whether one of these processes is causing excessive fouling of the crossflow or secondary filter. The authors conducted the tests with feed solutions containing 6.6 M sodium Salt Batch 6 simulant supernate with no MST.« less
Direct analysis in real time mass spectrometry, a process analytical technology tool for real-time process monitoring in botanical drug manufacturing.

PubMed

Wang, Lu; Zeng, Shanshan; Chen, Teng; Qu, Haibin

2014-03-01

A promising process analytical technology (PAT) tool has been introduced for batch processes monitoring. Direct analysis in real time mass spectrometry (DART-MS), a means of rapid fingerprint analysis, was applied to a percolation process with multi-constituent substances for an anti-cancer botanical preparation. Fifteen batches were carried out, including ten normal operations and five abnormal batches with artificial variations. The obtained multivariate data were analyzed by a multi-way partial least squares (MPLS) model. Control trajectories were derived from eight normal batches, and the qualification was tested by R(2) and Q(2). Accuracy and diagnosis capability of the batch model were then validated by the remaining batches. Assisted with high performance liquid chromatography (HPLC) determination, process faults were explained by corresponding variable contributions. Furthermore, a batch level model was developed to compare and assess the model performance. The present study has demonstrated that DART-MS is very promising in process monitoring in botanical manufacturing. Compared with general PAT tools, DART-MS offers a particular account on effective compositions and can be potentially used to improve batch quality and process consistency of samples in complex matrices. Copyright © 2014 Elsevier B.V. All rights reserved.
Optimization of permeability for quality improvement by using factorial design

NASA Astrophysics Data System (ADS)

Said, Rahaini Mohd; Miswan, Nor Hamizah; Juan, Ng Shu; Hussin, Nor Hafizah; Ahmad, Aminah; Kamal, Mohamad Ridzuan Mohamad

2017-05-01

Sand castings are used worldwide by the manufacturing process in Metal Casting Industry, whereby the green sand are the commonly used sand mould type in the industry of sand casting. The defects on the surface of casting product is one of the problems in the industry of sand casting. The problems that relates to the defect composition of green sand are such as blowholes, pinholes shrinkage and porosity. Our objective is to optimize the best composition of green sand in order to minimize the occurrence of defects. Sand specimen of difference parameters (Bentonite, Green Sand, Cold dust and water) were design and prepared to undergo permeability test. The 24 factorial design experiment with four factors at difference composition were runs, and the total of 16 runs experiment were conducted. The developed models based on the experimental design necessary models were obtained. The model with a high coefficient of determination (R2=0.9841) and model for predicted and actual fitted well with the experimental data. Using the Analysis of Design Expert software, we identified that bentonite and water are the main interaction effect in the experiments. The optimal settings for green sand composition are 100g silica sand, 21g bentonite, 6.5 g water and 6g coal dust. This composition gives an effect of permeability number 598.3GP.
Some epidemiological aspects of cutaneous leishmaniasis with emphasis on vectors and reservoirs of disease in the borderline of Iran and Iraq.

PubMed

Moradi, Mohammad; Rassi, Yavar; Abai, Mohammad Reza; Zahraei Ramazani, Alireza; Mohebali, Mehdi; Rafizadeh, Sayena

2018-06-01

Cutaneous leishmaniasis (CL) is endemic and a major health problem in 17 provinces out of 31 in Iran. This study aimed to determine vectors and reservoirs of the disease using molecular techniques in the borderline of Iran and Iraq. Sand flies and rodents were sampled using sticky paper traps and metal wire live traps, respectively, in the selected villages. About 10% of archived confirmed human positive slides was randomly checked for Leishmania by PCR-RFLP assay. The female sand flies were dissected in alcohol 96% in a sterile condition, the head and two segments of the abdomen end permanently mounted for identification and the remaining of body used for DNA extraction. The direct parasitological tests were carried out on the stained slides of rodents for Leishmania as well as PCR-RFLP assay used for molecular detection of parasite. A total of 2050 sand flies were identified comprising of Phlebotomus papatasi , Sergentomyia sintoni , Se . clydei , Se . mervynae , Se . theodori, Se . dentate and Se . iranica . The Ph . papatasi was ranked as a prevailing sand fly species. Molecular tests on female sand flies revealed infection of Ph . papatasi to Leishmania major . Direct parasitology and molecular tests confirmed of 20% infection to L . major among the sole rodents species " Tatera indica ". Due to wide dispersion of rodents colonies in the area and long favorite climate condition for sand flies, the CL foci will be provided the health risk for the religious tourists.
Field Application of a Rapid Spectrophotometric Method for Determination of Persulfate in Soil

PubMed Central

Cunningham, Colin J.; Pitschi, Vanessa; Anderson, Peter; Barry, D. A.; Patterson, Colin; Peshkur, Tanya A.

2013-01-01

Remediation of hydrocarbon contaminated soils can be performed both in situ and ex situ using chemical oxidants such as sodium persulfate. Standard methods for quantifying persulfate require either centrifugation or prolonged settling times. An optimized soil extraction procedure was developed for persulfate involving simple water extraction using a modified disposable syringe. This allows considerable saving of time and removes the need for centrifugation. The extraction time was reduced to only 5 min compared to 15 min for the standard approach. A comparison of the two approaches demonstrated that each provides comparable results. Comparisons were made using high (93 g kg−1 soil) and low (9.3 g kg−1 soil) additions of sodium persulfate to a petroleum hydrocarbon-contaminated soil, as well as sand spiked with diesel. Recoveries of 95±1% and 96±10% were observed with the higher application rate in the contaminated soil and spiked sand, respectively. Corresponding recoveries of 86±5% and 117±19% were measured for the lower application rate. Results were obtained in only 25 min and the method is well suited to batch analyses. In addition, it is suitable for application in a small field laboratory or even a mobile, vehicle-based system, as it requires minimal equipment and reagents. PMID:23776446
Occurrence, fate, and persistence of gemfibrozil in water and soil.

PubMed

Fang, Yu; Karnjanapiboonwong, Adcharee; Chase, Darcy A; Wang, Jiafan; Morse, Audra N; Anderson, Todd A

2012-03-01

Pharmaceuticals and personal care products (PPCPs) have emerged as a group of potential environmental contaminants of concern. The occurrence of gemfibrozil, a lipid-regulating drug, was studied in the influent and effluent at a wastewater treatment plant (WWTP) and groundwater below a land application site receiving treated effluent from the WWTP. In addition, the sorption of gemfibrozil in two loam soils and sand was assessed, and biological degradation rates in two soil types under aerobic conditions were also determined. Results showed that concentrations of gemfibrozil in wastewater influent, effluent, and groundwater were in the range of 3.47 to 63.8 µg/L, 0.08 to 19.4 µg/L, and undetectable to 6.86 µg/L, respectively. Data also indicated that gemfibrozil in the wastewater could reach groundwater following land application of the treated effluent. Soil-water distribution coefficients for gemfibrozil, determined by the batch equilibrium method, varied with organic carbon content in the soils. The sorption capacity was silt loam > sandy loam > sand. Under aerobic conditions, dissipation half-lives for gemfibrozil in sandy loam and silt loam soils were 17.8 and 20.6 days, respectively; 25.4 and 11.3% of gemfibrozil was lost through biodegradation from the two soils over 14 days. Copyright © 2011 SETAC.
Water movement in the unsaturated zone at a low-level radioactive-waste burial site near Barnwell, South Carolina

USGS Publications Warehouse

Dennehy, Kevin F.; McMahon, Peter B.

1989-01-01

Four unsaturated-zone monitoring sites and a meteorologic station were installed at the low-level radioactive-waste burial site near Barnwell, S.C., to investigate the geohydrologic and climatologic factors affecting water movement in the unsaturated zone. The study site is located in the Atlantic Coastal Plain. The unsaturated zone consists of a few centimeters to more than 1 meter of surface sand, underlain by up to 15 meters of clayey sand. Two monitoring sites were installed in experimental trenches, and two were installed in radioactive-waste trenches. Two different trench designs were evaluated at the monitoring sites. A meteorologic station was used to measure precipitation and to calculate actual evapotranspiration using the Bowen ratio method. Soil-moisture tensiometers, soil-moisture conductance probes, and temperature sensors were used to monitor soil-water movement in and adjacent to the trenches. Tracer tests using sodium chloride were conducted at each monitoring site. Hydrologic properties of unsaturated-zone materials were also determined. Data collection at the monitoring sites began in January 1982 and continued until early May 1984. Tensiometer data show that the unsaturated materials had their highest percent saturations in winter and spring. Saturations in the backfill sand varied from 20 to 100 percent, and in the adjacent undisturbed and overlying compacted clayey sand, from about 75 to 100 percent. The same pattern generally was observed at all four monitoring sites. The tracer-test data indicate that water movement occurred mainly during the recharge period, winter and spring. The tracer-test results enabled computation of rates of unsaturated flow in the compacted clayey-sand cap, the compacted clayey-sand barrier, and the backfill sand. A micro-scale hydrologic budget was determined for an undisturbed part of the site from July 1983 through June 1984.Total precipitation was 144 centimeters, and actual evapotranspiration was 101 centimeters. Additionally, because tensiometer data indicate negligible water-storage changes in the unsaturated zone, it is estimated that approximately 43 centimeters of recharge reached the water table. During 1984, the rise and fall of ponded water in an experimental trench was continuously monitored with a digital recorder. This water-level record was used to compute the rate of leakage of ponded water from that trench--1 x 10 -5 centimeter per second. A cross-sectional finite-element model of variably saturated flow was used to test the conceptual model of water movement in the unsaturated zone and to illustrate the effect of trench design on water movement into the experimental trenches. Monitoring and model results show that precipitation on trenches infiltrated the trench cap and moved vertically into the trench backfill material. Precipitation on the undisturbed material adjacent to the trenches moved vertically through the surface sand and continued either downward into undisturbed clayey sand or laterally along the sand/clayey-sand interface into the backfill sand, depending on trench design. The trench construction practice of placing a compacted clayey-sand barrier around the trench greatly inhibits soil water from entering the trench.

Coupled changes in sand grain size and sand transport driven by changes in the upstream supply of sand in the Colorado River: relative importance of changes in bed-sand grain size and bed-sand area

USGS Publications Warehouse

Topping, D.J.; Rubin, D.M.; Melis, T.S.

2007-01-01

Sand transport in the Colorado River in Marble and Grand canyons was naturally limited by the upstream supply of sand. Prior to the 1963 closure of Glen Canyon Dam, the river exhibited the following four effects of sand supply limitation: (1) hysteresis in sediment concentration, (2) hysteresis in sediment grain size coupled to the hysteresis in sediment concentration, (3) production of inversely graded flood deposits, and (4) development or modification of a lag between the time of a flood peak and the time of either maximum or minimum (depending on reach geometry) bed elevation. Construction and operation of the dam has enhanced the degree to which the first two of these four effects are evident, and has not affected the degree to which the last two effects of sand supply limitation are evident in the Colorado River in Marble and Grand canyons. The first three of the effects involve coupled changes in suspended-sand concentration and grain size that are controlled by changes in the upstream supply of sand. During tributary floods, sand on the bed of the Colorado River fines; this causes the suspended sand to fine and the suspended-sand concentration to increase, even when the discharge of water remains constant. Subsequently, the bed is winnowed of finer sand, the suspended sand coarsens, and the suspended-sand concentration decreases independently of discharge. Also associated with these changes in sand supply are changes in the fraction of the bed that is covered by sand. Thus, suspended-sand concentration in the Colorado River is likely regulated by both changes in the bed-sand grain size and changes in the bed-sand area. A physically based flow and suspended-sediment transport model is developed, tested, and applied to data from the Colorado River to evaluate the relative importance of changes in the bed-sand grain size and changes in the bed-sand area in regulating suspended-sand concentration. Although the model was developed using approximations for steady, uniform flow, and other simplifications that are not met in the Colorado River, the results nevertheless support the idea that changes in bed-sand grain size are much more important than changes in bed-sand area in regulating the concentration of suspended sand.
Data report for the geologic and scenic quality evaluation of selected sand and gravel sites on the Wind River Indian Reservation, Wyoming

USGS Publications Warehouse

Langer, William H.; Van Gosen, Bradley S.; Arbogast, Belinda; Lindsey, David A.

2011-01-01

In April 2005, the U.S. Geological Survey (USGS) conducted field studies on the Wind River Indian Reservation, Wyoming, to inventory and evaluate sand and gravel deposits underlying river terraces on tribal lands along the Wind River. This report contains the results for 12 sites of sand and gravel deposits evaluated for their potential use as aggregate in Portland cement concrete, asphalt, and base course. The report provides the results of: * The USGS geologic studies and engineering tests. * A conclusion and recommendation for the best use of sand and gravel materials. * Calculations of available sand and gravel materials. * A scenic quality landscape inventory and evaluation.
Stratified randomization controls better for batch effects in 450K methylation analysis: a cautionary tale.

PubMed

Buhule, Olive D; Minster, Ryan L; Hawley, Nicola L; Medvedovic, Mario; Sun, Guangyun; Viali, Satupaitea; Deka, Ranjan; McGarvey, Stephen T; Weeks, Daniel E

2014-01-01

Batch effects in DNA methylation microarray experiments can lead to spurious results if not properly handled during the plating of samples. Two pilot studies examining the association of DNA methylation patterns across the genome with obesity in Samoan men were investigated for chip- and row-specific batch effects. For each study, the DNA of 46 obese men and 46 lean men were assayed using Illumina's Infinium HumanMethylation450 BeadChip. In the first study (Sample One), samples from obese and lean subjects were examined on separate chips. In the second study (Sample Two), the samples were balanced on the chips by lean/obese status, age group, and census region. We used methylumi, watermelon, and limma R packages, as well as ComBat, to analyze the data. Principal component analysis and linear regression were, respectively, employed to identify the top principal components and to test for their association with the batches and lean/obese status. To identify differentially methylated positions (DMPs) between obese and lean males at each locus, we used a moderated t-test. Chip effects were effectively removed from Sample Two but not Sample One. In addition, dramatic differences were observed between the two sets of DMP results. After "removing" batch effects with ComBat, Sample One had 94,191 probes differentially methylated at a q-value threshold of 0.05 while Sample Two had zero differentially methylated probes. The disparate results from Sample One and Sample Two likely arise due to the confounding of lean/obese status with chip and row batch effects. Even the best possible statistical adjustments for batch effects may not completely remove them. Proper study design is vital for guarding against spurious findings due to such effects.
Stratified randomization controls better for batch effects in 450K methylation analysis: a cautionary tale

PubMed Central

Buhule, Olive D.; Minster, Ryan L.; Hawley, Nicola L.; Medvedovic, Mario; Sun, Guangyun; Viali, Satupaitea; Deka, Ranjan; McGarvey, Stephen T.; Weeks, Daniel E.

2014-01-01

Background: Batch effects in DNA methylation microarray experiments can lead to spurious results if not properly handled during the plating of samples. Methods: Two pilot studies examining the association of DNA methylation patterns across the genome with obesity in Samoan men were investigated for chip- and row-specific batch effects. For each study, the DNA of 46 obese men and 46 lean men were assayed using Illumina's Infinium HumanMethylation450 BeadChip. In the first study (Sample One), samples from obese and lean subjects were examined on separate chips. In the second study (Sample Two), the samples were balanced on the chips by lean/obese status, age group, and census region. We used methylumi, watermelon, and limma R packages, as well as ComBat, to analyze the data. Principal component analysis and linear regression were, respectively, employed to identify the top principal components and to test for their association with the batches and lean/obese status. To identify differentially methylated positions (DMPs) between obese and lean males at each locus, we used a moderated t-test. Results: Chip effects were effectively removed from Sample Two but not Sample One. In addition, dramatic differences were observed between the two sets of DMP results. After “removing” batch effects with ComBat, Sample One had 94,191 probes differentially methylated at a q-value threshold of 0.05 while Sample Two had zero differentially methylated probes. The disparate results from Sample One and Sample Two likely arise due to the confounding of lean/obese status with chip and row batch effects. Conclusion: Even the best possible statistical adjustments for batch effects may not completely remove them. Proper study design is vital for guarding against spurious findings due to such effects. PMID:25352862
Influence of the incubation temperature and the batch components on the sensitivity of an enzyme-linked immunosorbent assay to detect Aujeszky's disease virus glycoprotein E (gE).

PubMed

Cay, A B; Van der Stede, Y

2010-12-01

Although licensed batches of an enzyme-linked immunosorbent assay (ELISA) for Aujeszky's disease virus (ADV) were used, and the assays were performed within an ISO/IEC 17025 accredited quality control system, certain routine runs of the ADV ELISA were not validated using the quality system criteria, even when all technical parameters were controlled. Incubation at different temperatures and batch composition were identified as parameters that could result in non-validated assays/runs. Therefore, the effect of incubation temperature and batch composition on the analytical sensitivity of the ELISA was investigated. The World Organisation for Animal Health (OIE) standard reference serum ADV1 was diluted 1:8 and tested in 94 different glycoprotein E ELISA runs performed with different batches and different incubation temperatures. The incubation temperature and batch components had a significant influence on the qualitative result for the OIE standard reference serum. An incubation temperature of at least 22 degrees C was recommended, based on the results of this analysis. Which of the batch components caused these differences in sensitivity was not investigated further.
Comparison of batch cultivation strategies for cost-effective biomass production of Micractinium inermum NLP-F014 using a blended wastewater medium.

PubMed

Park, Seonghwan; Kim, Jeongmi; Park, Younghyun; Son, Suyoung; Cho, Sunja; Kim, Changwon; Lee, Taeho

2017-06-01

Two competitive strategies, fed-batch and sequencing-batch cultivation, were compared in cost-effective biomass production of a high lipid microalgae, Micractinium inermum NLP-F014 using a blended wastewater medium. For fed-batch cultivations, additional nutrient was supplemented at day 2 (FB1) or consecutively added at day 2 and 4 (FB2). Through inoculum size test, 1.0g-DCWL -1 was selected for the sequencing-batch cultivation (SB) where about 65% of culture was replaced with fresh medium every 2days. Both fed-batch cultivations showed the maximum biomass productivity of 0.95g-DCWL -1 d -1 , while average biomass productivity in SB was slightly higher as 0.96±0.08g-DCWL -1 d -1 . Furthermore, remained concentrations of organics (426mg-CODL -1 ), total nitrogen (15.4mg-NL -1 ) and phosphorus (0.6mg-PL -1 ) in SB were much lower than those of fed-batch conditions. The results suggested that SB could be a promising strategy to cultivate M. inermum NLP-F014 with the blended wastewater medium. Copyright © 2017 Elsevier Ltd. All rights reserved.
MODELING HEXAVALENT CHROMIUM REDUCTION IN GROUND- WATER IN FIELD-SCALE TRANSPORT AND LABORATORY BATCH EXPERIMENTS

EPA Science Inventory

A plausible and consistent model is developed to obtain a quantitative description of the gradual disappearance of hexavalent chromium (Cr(VI)) from groundwater in a small-scale field tracer test and in batch kinetic experiments using aquifer sediments under similar chemical cond...
40 CFR 63.785 - Compliance procedures.

Code of Federal Regulations, 2014 CFR

2014-07-01

... violation. If the owner or operator performs the certification testing, only one of the containers in which... coating by affixing a label to each container of coating in the batch or through another means described... batch of the coating by affixing a label to each container of coating or through another means described...
Properties of concrete containing foamed concrete block waste as fine aggregate replacement

NASA Astrophysics Data System (ADS)

Muthusamy, K.; Budiea, A. M. A.; Zaidan, A. L. F.; Rasid, M. H.; Hazimmah, D. S.

2017-11-01

Environmental degradation due to excessive sand mining dumping at certain places and disposal of foamed concrete block waste from lightweight concrete producing industry are issues that should be resolved for a better and cleaner environment of the community. Thus, the main intention of this study is to investigate the potential of foamed concrete block waste as partial sand replacement in concrete production. The foamed concrete waste (FCW) used in this research that were supplied by a local lightweight concrete producing industry. The workability and compressive strength of concrete containing various percentage of foamed concrete waste as partial sand replacement has been investigated. Prior to the use, the foamed concrete waste were crushed to produce finer particles. Six concrete mixes containing various content of crushed foamed concrete waste that are 0%, 10%, 20%, 30%, 40% and 50% were used in this experimental work. Then the prepared specimens were placed in water curing until the testing age. Compressive strength test and flexural strength tests were conducted at 7, 14 and 28 days. The result shows that integration of crushed foamed concrete waste as partial sand replacement in concrete reduces the mix workability. It is interesting to note that both compressive strength and flexural strength of concrete improves when 30% crushed foamed concrete waste is added as partial sand replacement.
Assessment of the microbial growth potential of slow sand filtrate with the biomass production potential test in comparison with the assimilable organic carbon method.

PubMed

van der Kooij, Dick; Veenendaal, Harm R; van der Mark, Ed J; Dignum, Marco

2017-11-15

Slow sand filtration is the final treatment step at four surface-water supplies in the Netherlands. The microbial growth potential (MGP) of the finished water was measured with the assimilable organic carbon (AOC) method using pure cultures and the biomass production potential (BPP) test. In the BPP test, water samples were incubated untreated at 25 °C and the active-biomass concentration was measured by adenosine tri-phosphate (ATP) analysis. Addition of a river-water inoculum improved the test performance and characteristic growth and maintenance profiles of the water were obtained. The maximum ATP concentration attained within seven days and the cumulative biomass production after 14 days of incubation (BPC 14 , d ng ATP L -1 ) showed highly significant and strong linear relationships with the AOC in the slow sand filtrates. The lowest AOC and BPC 14 levels were observed in the supplies applying dune filtration without ozonation in post treatment, with AOC/TOC = 1.7 ± 0.3 μg acetate-C equivalents mg -1 C and BPC 14 /TOC = 16.3 ± 2.2 d ng ATP mg -1 C, corresponding with 1.2 ± 0.19 ng ATP mg -1 C. These characteristics may represent the lowest specific MGP of natural organic matter achievable by biofiltration at temperatures ≤20 °C. The AOC and BPC 14 concentrations in the slow sand filtrate of the supply treating lake water by ozonation with granular-activated-carbon filtration and slow sand filtration as post treatment increased with decreasing temperature. The BPP test revealed that this slow sand filtrate sampled at 2 °C contained growth-promoting compounds that were not detected with the AOC test. These observations demonstrate the utility of the BPP test for assessing the MGP of drinking water and show the performance limits of biofiltration for MGP reduction. Copyright © 2017 Elsevier Ltd. All rights reserved.
Perchlorate remediation using packed-bed bioreactors and electricity generation in microbial fuel cells (MFCs)

NASA Astrophysics Data System (ADS)

Min, Booki

Two pilot-scale fixed bed bioreactors were operated in continuous mode in order to treat groundwater contaminated by perchlorate. The bioreactors were constructed and operated side-by-side at the Texas Street Well Facility in Redlands, California. Each reactor was packed with either sand or plastic media. A perchlorate-reducing bacterium, Dechlorosoma sp. KJ, was used to inoculate the bioreactors. Perchlorate was successfully removed down to a non-detectable level (<4mug/L) in both bioreactors with acetate as a carbon source and nutrients at loading rates less than 0.063 L/s (1 gpm; 0.34 L/m2s). The sand medium bioreactor could achieve complete-perchlorate removal up to flow rate of 0.126 L/s. A regular backwashing cycle (once a week) was an important factor for completely removing perchlorate in groundwater. Power generation directly from pure or mixed organic matter was examined using microbial fuel cells (MFCs), which were run either in batch or continuous mode. In batch experiments, both a pure culture (Geobactor metallireducens) and a mixed culture (wastewater inoculum) were used as the biocatalyst, and acetate was added as substrate in the anode chamber of the MFC. Power output in a membrane MFC with either inoculum was essentially the same, with 40 +/- 1 mW/m2 for G. metallireducens and 38 +/- 1 mW/m2 for mixed culture. A different type of the MFC containing a salt bridge instead of a membrane system was examined to generate power using the same substrate and pure culture as used in the membrane MFC. Power output in the salt bridge MFC was 2.2 mW/m 2. It was found that the lower power output was directly attributed to the higher internal resistance of the salt bridge system (19920 +/- 50 O) in comparison with that of the membrane system (1286 +/- 1 O). Continuous electricity generation was examined in a flat plate microbial fuel cell (FPMFC) using domestic wastewater and specific organic substrates. The FPMFC, containing a combined electrode/proton exchange membrane (PEM), was initially acclimated for one month to domestic wastewater, and then was operated as a plug flow reactor system. Power density using domestic wastewater as a substrate was 72 +/- 1 mW/m2 at a liquid flow rate of 0.39 mL/min (1.1 hr hydraulic retention time, HRT), and COD removal was 42%. At a longer HRT of 4.0 hr, the COD removal increased to 79%, and power density was 43 mW/m2. Several organic compounds (about 1000 mg-COD/L) also generated high power densities including: glucose (212 +/- 2 mW/m2), acetate (286 +/- 3 mW/m2), butyrate (220 +/- 1 mW/m2), dextran (150 +/- 1 mW/m 2), and starch (242 +/- 3 mW/m2). Therefore, it was shown that power could be successfully generated in a continuous-mode MFC with a variety of organic substrates. Animal wastewater was also tested as substrate to generate power in an air-cathode single chamber MFC operated in batch mode. This preliminary experiment demonstrated that power generation could be sustained with animal wastewater and that wastewater strength and odors were substantially reduced in the reactor after only one day of operation.
Anaerobic digestion of Chinese cabbage waste silage with swine manure for biogas production: batch and continuous study.

PubMed

Kafle, Gopi Krishna; Bhattarai, Sujala; Kim, Sang Hun; Chen, Lide

2014-01-01

The aim of this study was to investigate the potential for anaerobic co-digestion of Chinese cabbage waste silage (CCWS) with swine manure (SM). Batch and continuous experiments were carried out under mesophilic anaerobic conditions (36-38°C). The batch test evaluated the effect of CCWS co-digestion with SM (SM: CCWS=100:0; 25:75; 33:67; 0:100, % volatile solids (VS) basis). The continuous test evaluated the performance of a single stage completely stirred tank reactor with SM alone and with a mixture of SM and CCWS. Batch test results showed no significant difference in biogas yield up to 25-33% of CCWS; however, biogas yield was significantly decreased when CCWS contents in feed increased to 67% and 100%. When testing continuous digestion, the biogas yield at organic loading rate (OLR) of 2.0 g VSL⁻¹ d⁻¹ increased by 17% with a mixture of SM and CCWS (SM:CCWS=75:25) (423 mL g⁻¹ VS) than with SM alone (361 mL g⁻¹ VS). The continuous anaerobic digestion process (biogas production, pH, total volatile fatty acids (TVFA) and TVFA/total alkalinity ratios) was stable when co-digesting SM and CCWS (75:25) at OLR of 2.0 g VSL⁻¹ d⁻¹ and hydraulic retention time of 20 days under mesophilic conditions.
Susceptibility to an inoculum of infectious hypodermal and haematopoietic necrosis virus (IHHNV) in three batches of whiteleg shrimp Litopenaeus vannamei (Boone, 1931)

PubMed Central

Escobedo-Bonilla, César Marcial; Rangel, José Luis Ibarra

2014-01-01

Abstract The present study evaluated the susceptibility of three different batches of whiteleg shrimp Litopenaeus vannamei from Mexico to an inoculum of infectious hypodermal and haematopoietic necrosis virus (IHHNV). Each of the three shrimp batches came from a different hatchery. Because of their origin, it was possible that the genetic makeup of these batches was different among each other. The three batches tested showed differences in IHHNV susceptibility. Here, susceptibility is defined as the capacity of the host to become infected, and it can be measured by the infectivity titer. Susceptibility to IHHNV was observed in decreasing order in shrimp from batch 1 (hatchery from El Rosario, Sinaloa), batch 3 (hatchery from Nayarit) and batch 2 (hatchery from El Walamo, Sinaloa), respectively. The largest susceptibility difference between batches was 5012 times, and that between early and late juveniles from the same batch was 25 times. These results indicate that within a species, susceptibility to a pathogen such as IHHNV can have large differences. Susceptibility to pathogens is an important trait to consider before performing studies on pathogenesis. It may influence virological parameters such as speed of replication, pathogenicity and virus titer. In order to evaluate the potential use of IHHNV as a natural control agent against white spot syndrome virus (WSSV), it is necessary to know host susceptibility and the kinetics of IHHNV infection. These features can help to determine the conditions in which IHHNV could be used as antagonist in a WSSV infection. PMID:25561847
Agar Sediment Test for Assessing the Suitability of Organic Waste Streams for Recovering Nutrients by the Aquatic Worm Lumbriculus variegatus.

PubMed

Laarhoven, Bob; Elissen, H J H; Temmink, H; Buisman, C J N

2016-01-01

An agar sediment test was developed to evaluate the suitability of organic waste streams from the food industry for recovering nutrients by the aquatic worm Lumbriculus variegatus (Lv). The effects of agar gel, sand, and food quantities in the sediment test on worm growth, reproduction, and water quality were studied. Agar gel addition ameliorated growth conditions by reducing food hydrolysis and altering sediment structure. Best results for combined reproduction and growth were obtained with 0.6% agar-gel (20 ml), 10 g. fine sand, 40 g. coarse sand, and 105 mg fish food (Tetramin). With agar gel, ingestion and growth is more the result of addition of food in its original quality. Final tests with secondary potato starch sludge and wheat bran demonstrated that this test is appropriate for the comparison of solid feedstuffs and suspended organic waste streams. This test method is expected to be suitable for organic waste studies using other sediment dwelling invertebrates.
Agar Sediment Test for Assessing the Suitability of Organic Waste Streams for Recovering Nutrients by the Aquatic Worm Lumbriculus variegatus

PubMed Central

Laarhoven, Bob; Elissen, H. J. H.; Temmink, H.; Buisman, C. J. N.

2016-01-01

An agar sediment test was developed to evaluate the suitability of organic waste streams from the food industry for recovering nutrients by the aquatic worm Lumbriculus variegatus (Lv). The effects of agar gel, sand, and food quantities in the sediment test on worm growth, reproduction, and water quality were studied. Agar gel addition ameliorated growth conditions by reducing food hydrolysis and altering sediment structure. Best results for combined reproduction and growth were obtained with 0.6% agar-gel (20 ml), 10 g. fine sand, 40 g. coarse sand, and 105 mg fish food (Tetramin). With agar gel, ingestion and growth is more the result of addition of food in its original quality. Final tests with secondary potato starch sludge and wheat bran demonstrated that this test is appropriate for the comparison of solid feedstuffs and suspended organic waste streams. This test method is expected to be suitable for organic waste studies using other sediment dwelling invertebrates. PMID:26937632
Low temperature-pressure batch experiments and field push-pull tests: Assessing potential effects of an unintended CO2 release from CCUS projects on groundwater chemistry

NASA Astrophysics Data System (ADS)

Mickler, P. J.; Yang, C.; Lu, J.; Reedy, R. C.; Scanlon, B. R.

2012-12-01

Carbon Capture Utilization and Storage projects (CCUS), where CO2 is captured at point sources such as power stations and compressed into a supercritical liquid for underground storage, has been proposed to reduce atmospheric CO2 and mitigate global climate change. Problems may arise from CO2 releases along discreet pathways such as abandoned wells and faults, upwards and into near surface groundwater. Migrating CO2 may inversely impact fresh water resources by increasing mineral solubility and dissolution rates and mobilizing harmful trace elements including As and Pb. This study addresses the impacts on fresh water resources through a combination of laboratory batch experiments, where aquifer sediment are reacted in their corresponding groundwater in 100% CO2 environments, and field push-pull tests where groundwater is equilibrated with 100% CO2, reacted in-situ in the groundwater system, and pulled out for analyses. Batch experiments were performed on aquifer material from carbonate dominated, mixed carbonate/silicalstic, and siliclastic dominated systems. A mixed silicalstic/carbonate system was chosen for the field based push-pull test. Batch experiment results suggest carbonate dissolution increased the concentration of Ca, Mg, Sr, Ba, Mn, U and HCO3- in groundwater. In systems with significant carbonate content, dissolution continued until carbonate saturation was achieved at approximately 1000 hr. Silicate dissolution increased the conc. of Si, K Ni and Co, but at much lower rates than carbonate dissolution. The elements As, Mo, V, Zn, Se and Cd generally show similar behavior where concentrations initially increase but soon drop to levels at or below the background concentrations (~48 hours). A Push-Pull test on one aquifer system produced similar geochemical behavior but observed reaction rates are higher in batch experiments relative to push-pull tests. Release of CO2 from CCUS sites into overlying aquifer systems may adversely impact groundwater quality primarily through carbonate dissolution which releases Ca and elements that substitute for Ca in crystal lattices. Silicate weathering releases primarily Si and K at lower rates. Chemical changes with the addition of CO2 may initially mobilize As, Mo, V, Zn, Se and Cd but these elements become immobile in the lowered pH water and sorb onto aquifer minerals. A combined laboratory batch experiment and field push-pull test in fresh water aquifers overlying CCUS projects will best characterize the response of the aquifer to increased pCO2. The long experimental duration of the batch experiments may allow reactions to reach equilibrium however; reaction rates may be artificially high due to increased mineral surface areas. Field based push-pull tests offer a more realistic water rock ratio and test a much larger volume of aquifer material but the test must be shorter in duration because the high pCO2 water is subject to mixing with low pCO2 background water and migration away from the test well with groundwater flow. A comparison of the two methods best characterizes the potential effects on groundwater chemistry
Reversible adsorption and flushing of arsenic in a shallow, Holocene aquifer of Bangladesh

PubMed Central

Radloff, Kathleen A.; Zheng, Yan; Stute, Martin; Weinman, Beth; Bostick, Benjamin; Mihajlov, Ivan; Bounds, Margaret; Rahman, M. Moshiur; Huq, M. Rezaul; Ahmed, Kazi M.; Schlosser, Peter; van Geen, Alexander

2015-01-01

The spatial heterogeneity of dissolved arsenic (As) concentrations in shallow groundwater of the Bengal Basin has been attributed to transport of As (and reactive carbon) from external sources or to the release of As from within grey sand formations. We explore the latter scenario in this detailed hydrological and geochemical study along a 300 m transect of a shallow aquifer extending from a groundwater recharge area within a sandy channel bar to its discharge into a nearby stream. Within the 10–20 m depth range, groundwater ages along the transect determined by the 3H–3He method increase from <10 yr in the recharge area to a maximum of 40 yr towards the stream. Concentrations of groundwater As within the same grey sands increase from 10 to 100 to ∼500 µg/L along this transect. Evidence of reversible adsorption of As between the groundwater and sediment was obtained from a series of push–pull experiments, traditional batch adsorption experiments, and the accidental flooding of a shallow monitoring well. Assuming reversible adsorption and a distribution coefficient, Kd, of 0.15–1.5 L/kg inferred from these observations, a simple flushing model shows that the increase in As concentrations with depth and groundwater age at this site, and at other sites in the Bengal and Red River Basins, can be attributed to the evolution of the aquifer over 100–1000 years as aquifer sands are gradually flushed of their initial As content. A wide range of As concentrations can thus be maintained in groundwater with increases with depth governed by the history of flushing and local recharge rates, without external inputs of reactive carbon or As from other sources. PMID:28458447
Laboratory Simulated Acid-Sulfate Weathering of Basaltic Materials: Implications for Formation of Sulfates at Meridiani Planum and Gusev Crater, Mars

NASA Technical Reports Server (NTRS)

Golden, D. C.; Ming, Douglas W.; Morris, Richard V.; Mertzman, A.

2006-01-01

Acid-sulfate weathering of basaltic materials is a candidate formation process for the sulfate-rich outcrops and rocks at the MER rover Opportunity and Spirit landing sites. To determine the style of acid-sulfate weathering on Mars, we weathered basaltic materials (olivine-rich glassy basaltic sand and plagioclase feldspar-rich basaltic tephra) in the laboratory under different oxidative, acid-sulfate conditions and characterized the alteration products. We investigated alteration by (1) sulfuric-acid vapor (acid fog), (2) three-step hydrothermal leaching treatment approximating an open system and (3) single-step hydrothermal batch treatment approximating a "closed system." In acid fog experiments, Al, Fe, and Ca sulfates and amorphous silica formed from plagioclase-rich tephra, and Mg and Ca sulfates and amorphous silica formed from the olivine-rich sands. In three-step leaching experiments, only amorphous Si formed from the plagioclase-rich basaltic tephra, and jarosite, Mg and Ca sulfates and amorphous silica formed from olivine-rich basaltic sand. Amorphous silica formed under single-step experiments for both starting materials. Based upon our experiments, jarosite formation in Meridiani outcrop is potential evidence for an open system acid-sulfate weathering regime. Waters rich in sulfuric acid percolated through basaltic sediment, dissolving basaltic phases (e.g., olivine) and forming jarosite, other sulfates, and iron oxides. Aqueous alteration of outcrops and rocks on the West Spur of the Columbia Hills may have occurred when vapors rich in SO2 from volcanic sources reacted with basaltic materials. Soluble ions from the host rock (e.g., olivine) reacted with S to form Ca-, Mg-, and other sulfates along with iron oxides and oxyhydroxides.
Equilibrium sorption and diffusion rate studies with halogenated organic chemical and sandy aquifer material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ball, W.P.

1990-01-01

Concepts for rate limitation of sorptive uptake of hydrophobic organic solutes by aquifer solids are reviewed, emphasizing physical diffusion models and in the context of effects on contaminant transport. Data for the sorption of tetrachloroethene (PCE) and 1,2,4,5-tetrachlorobenzene (TeCB) on Borden sand are presented, showing that equilibrium is attained very slowly, requiring equilibration times on the order of tens of days for PCE and hundreds of days for TeCB. The rate of approach to equilibrium decreased with increasing particle size and sorption distribution coefficient, in accordance with retarded intragranular diffusion models. Pulverization of the samples significantly decreased the required timemore » to equilibrium without changing the sorption capacity of the solids. Batch sorption methodology was refined to allow accurate measurement of long-term distribution coefficients, using purified {sup 14}C-labelled solute spikes and sealed glass ampules. Sorption isotherms for PCE and TeCB were conducted with size fractions of Borden sand over four to five orders of magnitude in aqueous concentration, and were found to be slightly nonlinear (Freundlich exponent = 0.8). A concentrated set of data in the low concentration range (<50 ug/L) revealed that sorption in this range could be equally well described by a linear isotherm. Distribution coefficients of the two solutes with seven size fractions of Borden sand, measured at low concentration and at full equilibrium, were between seven and sixty times the value predicted on the basis of recent correlations with organic carbon content. Rate results for coarse size fractions support a simple pore diffusion model, with pore diffusion coefficients estimated to be approximately 3 {times} 10{sup {minus}8} cm{sup 2}/sec, more than 200{times} lower than the aqueous diffusivities.« less
Guided wave attenuation in coated pipes buried in sand

NASA Astrophysics Data System (ADS)

Leinov, Eli; Cawley, Peter; Lowe, Michael J. S.

2016-02-01

Long-range guided wave testing (GWT) is routinely used for the monitoring and detection of corrosion defects in above ground pipelines in various industries. The GWT test range in buried, coated pipelines is greatly reduced compared to aboveground pipelines due to energy leakage into the embedding soil. In this study, we aim to increase test ranges for buried pipelines. The effect of pipe coatings on the T(0,1) and L(0,2) guided wave attenuation is investigated using a full-scale experimental apparatus and model predictions. Tests are performed on a fusion-bonded epoxy (FBE)-coated 8" pipe, buried in loose and compacted sand over a frequency range of 10-35 kHz. The application of a low impedance coating is shown to effectively decouple the influence of the sand on the ultrasound leakage from the buried pipe. We demonstrate ultrasonic isolation of a buried pipe by coating the pipe with a Polyethylene (PE)-foam layer that has a smaller impedance than both pipe and sand and the ability to withstand the overburden load from the sand. The measured attenuation in the buried PE-foam-FBE-coated pipe is substantially reduced, in the range of 0.3-1.2 dBm-1 for loose and compacted sand conditions, compared to buried FBE-coated pipe without the PE-foam, where the measured attenuation is in the range of 1.7-4.7 dBm-1. The acoustic properties of the PE-foam are measured independently using ultrasonic interferometry technique and used in model predictions of guided wave propagation in a buried coated pipe. Good agreement is found between the attenuation measurements and model predictions. The attenuation exhibits periodic peaks in the frequency domain corresponding to the through-thickness resonance frequencies of the coating layer. The large reduction in guided wave attenuation for PE-coated pipes would lead to greatly increased GWT test ranges, so such coatings would be attractive for new pipeline installations.

Artificial recharge to a freshwater-sensitive brackish-water sand aquifer, Norfolk, Virginia

USGS Publications Warehouse

Brown, Donald L.; Silvey, William Dudley

1977-01-01

Fresh water was injected into a brackish-water sand for storage and retrieval. The initial injection rate of 400 gpm decreased to 70 gpm during test 3. The specific capacity of the well decreased also, from 15.4 to 0.93 gpm. Current-meter surveys indicated uniform reduction in hydraulic conductivity of all contributing zones in the aquifer. Hydraulic and chemical data indicate this was caused by dispersion of the interstitial clay upon introduction of the calcium bicarbonate water into the sodium chloride bearing sand aquifer. The clay dispersion also caused particulate rearrangement and clogging of well screen. A pre-flush of 0.2 N calcium chloride solution injected in front of the fresh water at the start of test 4 stabilized the clay. However, it did not reverse the particulate clogging that permanently reduced permeability and caused sanding during redevelopment. Clogging can be prevented by stabilization of the clay using commercially available trivalent aluminum compounds. Test 1 and test 2 showed that 85 percent of the water injected can be recovered, and the water meets U.S. Public Health Standards. Storage of fresh water in a brackish-water aquifer appears feasible provided proper control measures are used. (Woodard-USGS)
Identification of Algerian Field-Caught Phlebotomine Sand Fly Vectors by MALDI-TOF MS

PubMed Central

Lafri, Ismail; Almeras, Lionel; Bitam, Idir; Caputo, Aurelia; Yssouf, Amina; Forestier, Claire-Lise; Izri, Arezki; Raoult, Didier; Parola, Philippe

2016-01-01

Background Phlebotomine sand flies are known to transmit Leishmania parasites, bacteria and viruses that affect humans and animals in many countries worldwide. Precise sand fly identification is essential to prevent phlebotomine-borne diseases. Over the past two decades, progress in matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) has emerged as an accurate tool for arthropod identification. The objective of the present study was to investigate the usefulness of MALDI-TOF MS as a tool for identifying field-caught phlebotomine. Methodology/Principal Findings Sand flies were captured in four sites in north Algeria. A subset was morphologically and genetically identified. Six species were found in these areas and a total of 28 stored frozen specimens were used for the creation of the reference spectrum database. The relevance of this original method for sand fly identification was validated by two successive blind tests including the morphological identification of 80 new specimens which were stored at -80°C, and 292 unknown specimens, including engorged specimens, which were preserved under different conditions. Intra-species reproducibility and inter-species specificity of the protein profiles were obtained, allowing us to distinguish specimens at the gender level. Querying of the sand fly database using the MS spectra from the blind test groups revealed concordant results between morphological and MALDI-TOF MS identification. However, MS identification results were less efficient for specimens which were engorged or stored in alcohol. Identification of 362 phlebotomine sand flies, captured at four Algerian sites, by MALDI-TOF MS, revealed that the subgenus Larroussius was predominant at all the study sites, except for in M’sila where P. (Phlebotomus) papatasi was the only sand fly species detected. Conclusion The present study highlights the application of MALDI-TOF MS for monitoring sand fly fauna captured in the field. The low cost, reliability and rapidity of MALDI-TOF MS analyses opens up new ways in the management of phlebotomine sand fly-borne diseases. PMID:26771833
Investigation of guided wave propagation and attenuation in pipe buried in sand

NASA Astrophysics Data System (ADS)

Leinov, Eli; Lowe, Michael J. S.; Cawley, Peter

2015-07-01

Long-range guided wave testing is a well-established method for detection of corrosion defects in pipelines. The method is currently used routinely for above ground pipelines in a variety of industries, e.g. petrochemical and energy. When the method is applied to pipes buried in soil, test ranges tend to be significantly compromised and unpredictable due to attenuation of the guided wave resulting from energy leakage into the embedding soil. The attenuation characteristics of guided wave propagation in an 8 in. pipe buried in sand are investigated using a laboratory full-scale experimental rig and model predictions. We report measurements of attenuation of the T(0,1) and L(0,2) guided wave modes over a range of sand conditions, including loose, compacted, mechanically compacted, water saturated and drained. Attenuation values are found to be in the range of 1.65-5.5 dB/m and 0.98-3.2 dB/m for the torsional and longitudinal modes, respectively, over the frequency of 11-34 kHz. The application of overburden pressure modifies the compaction of the sand and increases the attenuation. Mechanical compaction of the sand yields similar attenuation values to those obtained with applied overburden pressure. The attenuation decreases in the fully water-saturated sand, and increases in drained sand to values comparable with those obtained for compacted sand. Attenuation measurements are compared with Disperse software model predictions and confirm that the attenuation phenomenon in buried pipes is essentially governed by the bulk shear velocity in the sand. The attenuation behaviour of the torsional guided wave mode is found not to be captured by a uniform soil model; comparison with predictions obtained with the Disperse software suggest that this is likely to be due to a layer of sand adhering to the surface of the pipe.
Identification of Algerian Field-Caught Phlebotomine Sand Fly Vectors by MALDI-TOF MS.

PubMed

Lafri, Ismail; Almeras, Lionel; Bitam, Idir; Caputo, Aurelia; Yssouf, Amina; Forestier, Claire-Lise; Izri, Arezki; Raoult, Didier; Parola, Philippe

2016-01-01

Phlebotomine sand flies are known to transmit Leishmania parasites, bacteria and viruses that affect humans and animals in many countries worldwide. Precise sand fly identification is essential to prevent phlebotomine-borne diseases. Over the past two decades, progress in matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) has emerged as an accurate tool for arthropod identification. The objective of the present study was to investigate the usefulness of MALDI-TOF MS as a tool for identifying field-caught phlebotomine. Sand flies were captured in four sites in north Algeria. A subset was morphologically and genetically identified. Six species were found in these areas and a total of 28 stored frozen specimens were used for the creation of the reference spectrum database. The relevance of this original method for sand fly identification was validated by two successive blind tests including the morphological identification of 80 new specimens which were stored at -80°C, and 292 unknown specimens, including engorged specimens, which were preserved under different conditions. Intra-species reproducibility and inter-species specificity of the protein profiles were obtained, allowing us to distinguish specimens at the gender level. Querying of the sand fly database using the MS spectra from the blind test groups revealed concordant results between morphological and MALDI-TOF MS identification. However, MS identification results were less efficient for specimens which were engorged or stored in alcohol. Identification of 362 phlebotomine sand flies, captured at four Algerian sites, by MALDI-TOF MS, revealed that the subgenus Larroussius was predominant at all the study sites, except for in M'sila where P. (Phlebotomus) papatasi was the only sand fly species detected. The present study highlights the application of MALDI-TOF MS for monitoring sand fly fauna captured in the field. The low cost, reliability and rapidity of MALDI-TOF MS analyses opens up new ways in the management of phlebotomine sand fly-borne diseases.
Experimental Investigations on the Pull-Out Behavior of Tire Strips Reinforced Sands.

PubMed

Li, Li-Hua; Chen, Yan-Jun; Ferreira, Pedro Miguel Vaz; Liu, Yong; Xiao, Heng-Lin

2017-06-27

Waste tires have excellent mechanical performance and have been used as reinforcing material in geotechnical engineering; however, their interface properties are poorly understood. To further our knowledge, this paper examines the pull-out characteristics of waste tire strips in a compacted sand, together with uniaxial and biaxial geogrids also tested under the same conditions. The analysis of the results shows that the interlocking effect and pull-out resistance between the tire strip and the sand is very strong and significantly higher than that of the geogrids. In the early stages of the pull-out test, the resistance is mainly provided by the front portion of the embedded tire strips, as the pull-out test continues, more and more of the areas towards the end of the tire strips are mobilized, showing a progressive failure mechanism. The deformations are proportional to the frictional resistance between the tire-sand interface, and increase as the normal stresses increase. Tire strips of different wear intensities were tested and presented different pull-out resistances; however, the pull-out resistance mobilization patterns were generally similar. The pull-out resistance values obtained show that rubber reinforcement can provide much higher pull-out forces than the geogrid reinforcements tested here, showing that waste tires are an excellent alternative as a reinforcing system, regardless of the environmental advantages.
Characterizing optical polishing pitch

NASA Astrophysics Data System (ADS)

Varshneya, Rupal; DeGroote, Jessica E.; Gregg, Leslie L.; Jacobs, Stephen D.

2003-05-01

Characterization data for five experimental optical polishing pitch products were compared to those for corresponding standard commercial optical polishing pitches. The experimental pitches were tested for three physical properties: hardness, viscosity at 90°C, and softening point. A Shore A Durometer test was used to measure hardness. Viscosity data were collected using a Stony Brook Scientific falling needle viscometer. Softening point was determined using the ASTM D3104-97 method. Results demonstrate that the softest and the hardest batches of the experimental grades of optical pitch are comparable to the industry-accepted standards, while the other grades of pitch are not. The experimental methodology followed in this research may allow opticians to rapidly compare different brands of pitch to help identify batch-to-batch differences and control pitch quality before use.
Characterizing optical polishing pitch

NASA Astrophysics Data System (ADS)

Varshneya, Rupal

2003-05-01

Characterization data for five experimental optical polishing pitch products were compared to those for corresponding standard commercial optical polishing pitches. The experimental pitches were tested for three physical properties: hardness, viscosity at 90°C, and softening point. A Shore A Durometerl test was used to measure hardness. Viscosity data were collected using a Stony Brook Scientific' falling needle viscometer. Softening point was determined using the ASTM D3104-97 method. Results demonstrate that the softest and the hardest batches of the experimental grades of optical pitch are comparable to the industry-accepted standards, while the other grades of pitch are not. The experimental methodology followed in this research may allow opticians to rapidly compare different brands of pitch to help identify batch- to- batch differences and control pitch quality before use.
In vitro growth of Curcuma longa L. in response to five mineral elements and plant density in fed-batch culture systems.

PubMed

El-Hawaz, Rabia F; Bridges, William C; Adelberg, Jeffrey W

2015-01-01

Plant density was varied with P, Ca, Mg, and KNO3 in a multifactor experiment to improve Curcuma longa L. micropropagation, biomass and microrhizome development in fed-batch liquid culture. The experiment had two paired D-optimal designs, testing sucrose fed-batch and nutrient sucrose fed-batch techniques. When sucrose became depleted, volume was restored to 5% m/v sucrose in 200 ml of modified liquid MS medium by adding sucrose solutions. Similarly, nutrient sucrose fed-batch was restored to set points with double concentration of treatments' macronutrient and MS micronutrient solutions, along with sucrose solutions. Changes in the amounts of water and sucrose supplementations were driven by the interaction of P and KNO3 concentrations. Increasing P from 1.25 to 6.25 mM increased both multiplication and biomass. The multiplication ratio was greatest in the nutrient sucrose fed-batch technique with the highest level of P, 6 buds/vessel, and the lowest level of Ca and KNO3. The highest density (18 buds/vessel) produced the highest fresh biomass at the highest concentrations of KNO3 and P with nutrient sucrose fed-batch, and moderate Ca and Mg concentrations. However, maximal rhizome dry biomass required highest P, sucrose fed-batch, and a moderate plant density. Different media formulations and fed-batch techniques were identified to maximize the propagation and storage organ responses. A single experimental design was used to optimize these dual purposes.
In Vitro Growth of Curcuma longa L. in Response to Five Mineral Elements and Plant Density in Fed-Batch Culture Systems

PubMed Central

El-Hawaz, Rabia F.; Bridges, William C.; Adelberg, Jeffrey W.

2015-01-01

Plant density was varied with P, Ca, Mg, and KNO3 in a multifactor experiment to improve Curcuma longa L. micropropagation, biomass and microrhizome development in fed-batch liquid culture. The experiment had two paired D-optimal designs, testing sucrose fed-batch and nutrient sucrose fed-batch techniques. When sucrose became depleted, volume was restored to 5% m/v sucrose in 200 ml of modified liquid MS medium by adding sucrose solutions. Similarly, nutrient sucrose fed-batch was restored to set points with double concentration of treatments’ macronutrient and MS micronutrient solutions, along with sucrose solutions. Changes in the amounts of water and sucrose supplementations were driven by the interaction of P and KNO3 concentrations. Increasing P from 1.25 to 6.25 mM increased both multiplication and biomass. The multiplication ratio was greatest in the nutrient sucrose fed-batch technique with the highest level of P, 6 buds/vessel, and the lowest level of Ca and KNO3. The highest density (18 buds/vessel) produced the highest fresh biomass at the highest concentrations of KNO3 and P with nutrient sucrose fed-batch, and moderate Ca and Mg concentrations. However, maximal rhizome dry biomass required highest P, sucrose fed-batch, and a moderate plant density. Different media formulations and fed-batch techniques were identified to maximize the propagation and storage organ responses. A single experimental design was used to optimize these dual purposes. PMID:25830292
DOE Office of Scientific and Technical Information (OSTI.GOV)

Earl D Mattson; Ghanashyam Neupane; Mitchell Plummer

Long-term sustainability of fracture conductivity is critical for commercial success of engineered geothermal system (EGS) and hydrogeothermal field sites. The injection of proppants has been suggested as a means to enhance the conductivity in these systems. Several studies have examined the chemical behavior of proppants that are not at chemical equilibrium with the reservoir rock and water. These studies have suggested that in geothermal systems, geochemical reactions can lead to enhance proppant dissolution and deposition alteration minerals. We hypothesize that proppant dissolution will decrease the strength of the proppant and can potentially reduce the conductivity of the fracture. To examinemore » the geomechanical strength of proppants, we have performed modified crushing tests of proppants and reservoir rock material that was subjected to geothermal reservoir temperature conditions. The batch reactor experiments heated crushed quartz monzonite rock material, proppants (either quartz sand, sintered bauxite or kryptospheres) with Raft River geothermal water to 250 ºC for a period of 2 months. Solid and liquid samples were shipped to University of Utah for chemical characterization with ICP-OES, ICP-MS, and SEM. A separate portion of the rock/proppant material was subjected to a modified American Petroleum Institute ISO 13503-2 proppant crushing test. This test is typically used to determine the maximum stress level that can be applied to a proppant pack without the occurrence of unacceptable proppant crushing. We will use the test results to examine potential changes in proppant/reservoir rock geomechanical properties as compared to samples that have not been subjected to geothermal conditions. These preliminary results will be used to screen the proppants for long term use in EGS and hot hydrogeothermal systems.« less
69. Photograph of line drawing. ISOMETRIC VIEW OF 500,000 POUND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

69. Photograph of line drawing. ISOMETRIC VIEW OF 500,000 POUND STATIC TEST FACILITY, NO DATE - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
70. Photograph of line drawing. TOPOGRAPHIC SITE PLAN OF 500,000 ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

70. Photograph of line drawing. TOPOGRAPHIC SITE PLAN OF 500,000 POUND STATIC TEST FACILITY, APRIL 1947 - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
72. Photograph of line drawing. SOUTH ELEVATION OF MOTOR CARRIAGE, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

72. Photograph of line drawing. SOUTH ELEVATION OF MOTOR CARRIAGE, 500,000 POUND STATIC TEST FACILITY, NO DATE - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Enhanced Gravitational Drainage of Crude Oil Through Alabama Beach Sand Caused by the Dispersant Corexit 9500A

NASA Astrophysics Data System (ADS)

Steffy, D. A.; Nichols, A.; Hobbs, K.

2017-12-01

Oil spill material released by the 2010 Deepwater Horizon accident contaminated a majority of the 60 miles of Alabama coastline. In response to the oil spill, BP sprayed a dispersant, Corexit 9500A, as an initial remediation effort. An unforeseen impact of the saltwater-dispersant mixture includes the mobilization of oil-spilled material into the underlying beach sand. This study investigated the effect of the dispersant to promote gravitational drainage by measuring the physical characteristics of the sand, saltwater, crude oil, and the dispersant solution. The saltwater-dispersant mixture promoted the downward movement of oil mass 20 times greater extent than just saltwater. These tests are meant to simulate spill material on the beach being exposed to a low-energy, 1-meter mixed tide occurring along the Alabama coastline. A separate test simulated oilwet sand exposed to saltwater and a saltwater-dispersant mixture. The oil-wet sand impeded the vertical movement of saltwater, but allowed a saltwater-dispersant solution to mobilize the oil to migrate downward. The mobilization of oil in this three phase system of saltwater, oil, and air is controlled by: the pressure-saturation profile of the sand; interfacial tension with saltwater; and its surface tension with air.
Influence of different processing techniques on the mechanical properties of used tires in embankment construction.

PubMed

Edinçliler, Ayşe; Baykal, Gökhan; Saygili, Altug

2010-06-01

Use of the processed used tires in embankment construction is becoming an accepted way of beneficially recycling scrap tires due to shortages of natural mineral resources and increasing waste disposal costs. Using these used tires in construction requires an awareness of the properties and the limitations associated with their use. The main objective of this paper is to assess the different processing techniques on the mechanical properties of used tires-sand mixtures to improve the engineering properties of the available soil. In the first part, a literature study on the mechanical properties of the processed used tires such as tire shreds, tire chips, tire buffings and their mixtures with sand are summarized. In the second part, large-scale direct shear tests are performed to evaluate shear strength of tire crumb-sand mixtures where information is not readily available in the literature. The test results with tire crumb were compared with the other processed used tire-sand mixtures. Sand-used tire mixtures have higher shear strength than that of the sand alone and the shear strength parameters depend on the processing conditions of used tires. Three factors are found to significantly affect the mechanical properties: normal stress, processing techniques, and the used tire content. Copyright 2009. Published by Elsevier Ltd.
Construction of a test embankment using a sand-tire shred mixture as fill material.

PubMed

Yoon, Sungmin; Prezzi, Monica; Siddiki, Nayyar Zia; Kim, Bumjoo

2006-01-01

Use of tire shreds in construction projects, such as highway embankments, is becoming an accepted way of beneficially recycling scrap tires. However, in the last decade there was a decline in the use of pure tire shreds as fill materials in embankment construction, as they are susceptible to fire hazards due to the development of exothermic reactions. Tire shred-sand mixtures, on the other hand, were found to be effective in inhibiting exothermic reactions. When compared with pure tire shreds, tire shred-sand mixtures are less compressible and have higher shear strength. However, the literature contains limited information on the use of tire shred-soil mixtures as a fill material. The objectives of this paper are to discuss and evaluate the feasibility of using tire shred-sand mixtures as a fill material in embankment construction. A test embankment constructed using a 50/50 mixture, by volume, of tire shreds and sand was instrumented and monitored to: (a) determine total and differential settlements; (b) evaluate the environmental impact of the embankment construction on the groundwater quality due to leaching of fill material; and (c) study the temperature variation inside the embankment. The findings in this research indicate that mixtures of tire shreds and sand are viable materials for embankment construction.
A further study on seismic response of a set of parallel rock fractures filled with viscoelastic materials

NASA Astrophysics Data System (ADS)

Wu, W.; Zhu, J. B.; Zhao, J.

2013-02-01

The purpose of this study is to further investigate the seismic response of a set of parallel rock fractures filled with viscoelastic materials, following the work by Zhu et al. Dry quartz sands are used to represent the viscoelastic materials. The split Hopkinson rock bar (SHRB) technique is modified to simulate 1-D P-wave propagation across the sand-filled parallel fractures. At first, the displacement and stress discontinuity model (DSDM) describes the seismic response of a sand-filled single fracture. The modified recursive method (MRM) then predicts the seismic response of the sand-filled parallel fractures. The SHRB tests verify the theoretical predictions by DSDM for the sand-filled single fracture and by MRM for the sand-filled parallel fractures. The filling sands cause stress discontinuity across the fractures and promote displacement discontinuity. The wave transmission coefficient for the sand-filled parallel fractures depends on wave superposition between the fractures, which is similar to the effect of fracture spacing on the wave transmission coefficient for the non-filled parallel fractures.
Performance of sand and shredded rubber tire mixture as a natural base isolator for earthquake protection

NASA Astrophysics Data System (ADS)

Bandyopadhyay, Srijit; Sengupta, Aniruddha; Reddy, G. R.

2015-12-01

The performance of a well-designed layer of sand, and composites like layer of sand mixed with shredded rubber tire (RSM) as low cost base isolators, is studied in shake table tests in the laboratory. The building foundation is modeled by a 200 mm by 200 mm and 40 mm thick rigid plexi-glass block. The block is placed in the middle of a 1m by 1m tank filled with sand. The selected base isolator is placed between the block and the sand foundation. Accelerometers are placed on top of the footing and foundation sand layer. The displacement of the footing is also measured by LVDT. The whole setup is mounted on a shake table and subjected to sinusoidal motions with varying amplitude and frequency. Sand is found to be effective only at very high amplitude (> 0.65 g) of motions. The performance of a composite consisting of sand and 50% shredded rubber tire placed under the footing is found to be most promising as a low-cost effective base isolator.
Recommendation of ruthenium source for sludge batch flowsheet studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woodham, W.

Included herein is a preliminary analysis of previously-generated data from sludge batches 7a, 7b, 8, and 9 sludge simulant and real-waste testing, performed to recommend a form of ruthenium for future sludge batch simulant testing under the nitric-formic flowsheet. Focus is given to reactions present in the Sludge Receipt and Adjustment Tank cycle, given that this cycle historically produces the most changes in chemical composition during Chemical Process Cell processing. Data is presented and analyzed for several runs performed under the nitric-formic flowsheet, with consideration given to effects on the production of hydrogen gas, nitrous oxide gas, consumption of formate,more » conversion of nitrite to nitrate, and the removal and recovery of mercury during processing. Additionally, a brief discussion is given to the effect of ruthenium source selection under the nitric-glycolic flowsheet. An analysis of data generated from scaled demonstration testing, sludge batch 9 qualification testing, and antifoam degradation testing under the nitric-glycolic flowsheet is presented. Experimental parameters of interest under the nitric-glycolic flowsheet include N2O production, glycolate destruction, conversion of glycolate to formate and oxalate, and the conversion of nitrite to nitrate. To date, the number of real-waste experiments that have been performed under the nitric-glycolic flowsheet is insufficient to provide a complete understanding of the effects of ruthenium source selection in simulant experiments with regard to fidelity to real-waste testing. Therefore, a determination of comparability between the two ruthenium sources as employed under the nitric-glycolic flowsheet is made based on available data in order to inform ruthenium source selection for future testing under the nitric-glycolic flowsheet.« less
Modeling of flood-deposited sand distributions in a reach of the Colorado River below the Little Colorado River, Grand Canyon, Arizona

USGS Publications Warehouse

Wiele, S.M.

1998-01-01

A release from Glen Canyon Dam during March-April 1996 was designed to test the effectiveness with which the riparian environment could be renewed with discharges greatly in excess of the normal powerplant-restricted maximum. Of primary concern was the rebuilding of sand deposits along the channel sides that are important to the flora and fauna along the river corridor and that provide the only camp sites for riverside visitors to the Grand Canyon National Park. Analysis of the depositional processes with a model of flow, sand transport, and bed evolution shows that the sand deposits formed along the channel sides early during the high flow were affected only slightly by the decline in suspended-sand concentrations over the course of the controlled flood. Modeling results suggest that the removal of a large sand deposit over several hours was not a response to declining suspended-sand concentrations. Comparisons of the controlled-flood deposits with deposits formed during a flood in January 1993 on the Little Colorado River that contributed sufficient sand to raise the suspended-sand concentrations to predam levels in the main stem show that the depositional pattern as well as the magnitude is strongly influenced by the suspended-sand concentrations.

Enhancement of Micropollutant Degradation at the Outlet of Small Wastewater Treatment Plants

PubMed Central

Rossi, Luca; Queloz, Pierre; Brovelli, Alessandro; Margot, Jonas; Barry, D. A.

2013-01-01

The aim of this work was to evaluate low-cost and easy-to-operate engineering solutions that can be added as a polishing step to small wastewater treatment plants to reduce the micropollutant load to water bodies. The proposed design combines a sand filter/constructed wetland with additional and more advanced treatment technologies (UV degradation, enhanced adsorption to the solid phase, e.g., an engineered substrate) to increase the elimination of recalcitrant compounds. The removal of five micropollutants with different physico-chemical characteristics (three pharmaceuticals: diclofenac, carbamazepine, sulfamethoxazole, one pesticide: mecoprop, and one corrosion inhibitor: benzotriazole) was studied to evaluate the feasibility of the proposed system. Separate batch experiments were conducted to assess the removal efficiency of UV degradation and adsorption. The efficiency of each individual process was substance-specific. No process was effective on all the compounds tested, although elimination rates over 80% using light expanded clay aggregate (an engineered material) were observed. A laboratory-scale flow-through setup was used to evaluate interactions when removal processes were combined. Four of the studied compounds were partially eliminated, with poor removal of the fifth (benzotriazole). The energy requirements for a field-scale installation were estimated to be the same order of magnitude as those of ozonation and powdered activated carbon treatments. PMID:23484055
Orientation of colonized sand flies Phlebotomus papatasi, P. duboscqi, and Lutzomyia longipalpis (Diptera: Psychodidae) to diverse honeys using a 3-chamber in-line olfactometer.

PubMed

Wasserberg, G; Kirsch, P; Rowton, E D

2014-06-01

A 3-chamber in-line olfactometer designed for use with sand flies is described and tested as a high-throughput method to screen honeys for attractiveness to Phlebotomus papatasi (four geographic isolates), P. duboscqi (two geographic isolates), and Lutzomyia longipalpis maintained in colonies at the Walter Reed Army Institute of Research. A diversity of unifloral honey odors were evaluated as a proxy for the natural floral odors that sand flies may use in orientation to floral sugar sources in the field. In the 3-chamber in-line olfactometer, the choice modules come directly off both sides of the release area instead of angling away as in the Y-tube olfactometer. Of the 25 honeys tested, five had a significant attraction for one or more of the sand fly isolates tested. This olfactometer and high-throughput method has utility for evaluating a diversity of natural materials with unknown complex odor blends that can then be down-selected for further evaluation in wind tunnels and/or field scenarios. © 2014 The Society for Vector Ecology.
Calcium, BOBs, QEDs, microdomains and a cellular decision: control of mitotic cell division in sand dollar blastomeres.

PubMed

Silver, R B

1996-08-01

The role of Ca2+ in controlling cell processes (e.g. mitosis) presents an enigma in its ubiquity and selectivity. Intracellular free Ca2+ (Ca2+i) is an essential regulator of specific biochemical and physiological aspects of mitosis (e.g. nuclear envelope breakdown (NEB)). Changes in Ca2+i concentrations during mitosis in second cell-cycle sand dollar (Echinaracnius parma) blastomeres were imaged as Ca(2+)-dependent luminescence of the photoprotein aequorin with multi-spectral analytical video microscopy. Photons of this luminescence were seen as bright observable blobs (BOBs). Spatiotemporal patterns of BOBs were followed through one or more cell cycles to detect directly changes in Ca2+i, and were seen to change in a characteristic fashion prior to NEB, the onset of anaphase chromosome movement, and during cytokinesis. These patterns were observed from one cell cycle to the next in a single cell, from cell to cell, and from egg batch to egg batch. In both mitosis and synaptic transmission increases in Ca2+i concentration occurs in discrete, short-lived, highly localized pulses we name quantum emission domains (QEDs) within regions we named microdomains. Signal and statistical optical analyses of spatiotemporal BOB patterns show that many BOBs are linked by constant displacements in space-time (velocity). Linked BOBs are thus nonrandom and are classified as QEDS. Analyses of QED patterns demonstrated that the calcium signals required for NEB are nonrandom, and are evoked by an agent(s) generated proximal to a Ca2+i-QED; models of waves, diffusible agonists and Ca(2+)-activated Ca2+ release do not fit pre-NEB cell data. Spatial and temporal resolution of this multispectral approach significantly exceeds that reported for other methods, and avoids the perturbations associated with many fluorescent Ca2+ reporters that interfere with cells being studied (Ca(2+)-buffering, UV toxicity, etc.). Spatiotemporal patterns of Ca2+i-QED can control so many different processes, i.e. specific frequencies used to control particular processes. Predictive and structured patterns of calcium signals (e.g. a language expressed in Ca2+) may selectively regulate specific Ca(2+)-dependent cellular processes.
Imidacloprid transport and sorption nonequilibrium in single and multilayered columns of Immokalee fine sand

PubMed Central

Nkedi-Kizza, Peter; Morgan, Kelly T.; Kadyampakeni, Davie M.

2017-01-01

Imidacloprid (IMD) is a neonicotinoid pesticide soil-drenched to many crops to control piercing-sucking insects such as the Asian citrus psyllid (ACP). Neonicotinoids are persistent in the environment and transport analyses are helpful estimate leaching potential from soils that could result in groundwater pollution. The objective of this study was to analyze IMD breakthrough under saturated water flow in soil columns packed with three horizons (A, E, Bh) of Immokalee Fine Sand (IFS). Also, we used the dimensionless form of the convective-dispersive model (CD-Model) to compare the optimized transport parameters from each column experiment (retardation factor, R; fraction of instantaneous-to-total retardation, β; and mass transfer coefficient, ω) with the parameters obtained from sorption batch equilibria and sorption kinetics. The tracer (Cl-) breakthrough curves (BTCs) were symmetrical and properly described by the CD-Model. IMD BTCs from A, Bh, and multilayered [A+E+Bh] soil columns showed steep fronts and tailing that were well described by the one-site nonequilibrium (OSNE) model, which was an evidence of non-ideal transport due to IMD mass transfer into the soil organic matter. In general, IMD was weakly-sorbed in the A and Bh horizons (R values of 3.72 ± 0.04 and 3.08 ± 0.07, respectively), and almost no retardation was observed in the E horizon (R = 1.20 ± 0.02) due to its low organic matter content (0.3%). Using the HYDRUS-1D package, optimized parameters (R, β, ω) from the individual columns successfully simulated IMD transport in a multilayered column mimicking an IFS soil profile. These column studies and corresponding simulations agreed with previous findings from batch sorption equilibria and kinetics experiments, where IMD showed one-site kinetic mass transfer between soil surfaces and soil solution. Ideally, sandy soils should be maintained unsaturated by crop irrigation systems and rainfall monitoring during and after soil-drench application. The unsaturated soil will increase IMD retardation factors and residence time for plant uptake, lowering leaching potential from soil layers with low sorption capacity, such as the E horizon. PMID:28837702
Foaming of E-Glass II (Report for G Plus Project for PPG)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Dong-Sang; Portch, Matthew P.; Matyas, Josef

2005-09-23

In a previous study, the effect of the furnace atmosphere on E glass foaming was investigated with the specific goal to understand the impact of increased water content on foaming in oxy-fired furnaces. The present study extended the previous study and focused on the effect of glass batch chemical composition on E-glass foaming. The present study also included reruns of foam tests performed in a previous study, which resulted in the same trend: the foaming extent increased nearly linearly with the heating rate and no foam was produced when CO2 + 55% H2O atmosphere was introduced at 300°C. It wasmore » shown that the lack of foaming in the test with CO2 + 55% H2O atmosphere introduced at 300°C was caused by a loss of sulfate at T <1250°C because of higher water content at the early stages of melting. The tests with new batches in the present study showed that replacing quicklime with limestone tend to decrease foaming, possibly caused by increased sulfate loss during early stages of melting in the batch with limestone. The batches where Na2SO4 was replaced with NaNO3, NaNO3 + CeO2, or CeO2, produced only very limited foaming regardless of the replacing components. As expected, the foaming extent increased as the sulfate content in the batch increased. The results of the present study suggest that foaming can be reduced by using limestone over quicklime and by decreasing the sulfate addition to a minimum required for refining.« less
Effect of differently pelletized digestate on the plant growth of spring wheat

NASA Astrophysics Data System (ADS)

Dietrich, Nils; Knoop, Christine; Raab, Thomas

2017-04-01

In Germany, biowaste is used in more than 100 biogas plants and has increasing potential as a fermentation substrate. To optimise waste cycle management organic digestates should be redistributed and innovative products for soil amendment of agricultural areas could be developed. The BMBF-funded VeNGA project seeks to find answers on how to improve the properties of soil amendments produced from fermentation residues. Here, we report findings from our study that focuses on plant growth and soil development. Within a three-month rhizotron experiment, the influence of differently prepared fermentation residues on the root development of summer wheat was investigated. The four variants of the prepared digestate (rolled pellet, pressed pellet, shredded, loose) were tested under constant conditions in the greenhouse on two soils with different textures (sandy and loamy-sand). All fermentation residues originated from the same batch and were composted before the preparation to ensure adequate hygienisation. Depending on preparation type and soil substrate significant differences in root growth and root development have been observed. Plant growth was most intense in the rhizotron experiment with the loose digestate, indicating high nutrient availability due to the large surface area of the organic matter. Plant growth in the substrate with the rolled and pressed pellets was less pronounced, indicating a more persistent stability of the pellets. In rhizotrons applied with rolled and pressed pellets root growth into the mineral fabric was significantly lower in sandy substrate than in the loamy-sand. However, in the sandy substrate root growth within the rolled pellets was more intense than in the substrate with the pressed pellets. Obviously, the different production techniques of the pellets seem to have an influence on the rooting of the pellets and facilitate the long term stability of soil organic carbon. Furthermore, the comparison of the two different textures indicate, that sandy substrates benefit more from the positive effects of soil amendments on increased water retention than loamy substrates.
Batch crystallization of rhodopsin for structural dynamics using an X-ray free-electron laser

DOE PAGES

Wu, Wenting; Nogly, Przemyslaw; Rheinberger, Jan; ...

2015-06-27

Rhodopsin is a membrane protein from the G protein-coupled receptor family. Together with its ligand retinal, it forms the visual pigment responsible for night vision. In order to perform ultrafast dynamics studies, a time-resolved serial femtosecond crystallography method is required owing to the nonreversible activation of rhodopsin. In such an approach, microcrystals in suspension are delivered into the X-ray pulses of an X-ray free-electron laser (XFEL) after a precise photoactivation delay. Here in this study, a millilitre batch production of high-density microcrystals was developed by four methodical conversion steps starting from known vapour-diffusion crystallization protocols: (i) screening the low-salt crystallizationmore » conditions preferred for serial crystallography by vapour diffusion, (ii) optimization of batch crystallization, (iii) testing the crystal size and quality using second-harmonic generation (SHG) imaging and X-ray powder diffraction and (iv) production of millilitres of rhodopsin crystal suspension in batches for serial crystallography tests; these crystals diffracted at an XFEL at the Linac Coherent Light Source using a liquid-jet setup.« less
Development of freeze dried vegetables

NASA Technical Reports Server (NTRS)

Larson, R. W.

1970-01-01

The development of freeze dried vegetables to be used in the Apollo food system is discussed. After the initial selection and screening of vegetables, several types of freeze dried vegetables were prepared in small batches. From these small batches, two vegetables were judged satisfactory for further testing and evaluation. These vegetables, mashed potatoes and asparagus, were subjected to storage at 100 deg plus or minus 5 F. for two weeks and then taste tested. The vegetables were also tested to determine if they complied with the microbiological requirements for Apollo food. The space food prototype production guide for the vegetables is submitted.
The potential use of silica sand as nanomaterials for mortar

NASA Astrophysics Data System (ADS)

Setiati, N. Retno

2017-11-01

The development of nanotechnology is currently experiencing rapid growth. The use of the term nanotechnology is widely applied in areas such as healthcare, industrial, pharmaceutical, informatics, or construction. By the nanotechnology in the field of concrete construction, especially the mechanical properties of concrete are expected to be better than conventional concrete. This study aims to determine the effect of the potential of silica sand as a nanomaterial that is added into the concrete mix The methodology used consist of nanomaterial synthesis process of silica sand using Liquid Polishing Milling Technology (PLMT). The XRF and XRD testing were conducted to determine the composition of silica contained in the silica sand and the level of reactivity of the compound when added into the concrete mix. To determine the effect of nano silica on mortar, then made the specimen with size 50 mm x 50 mm x 50 mm. The composition of mortar is made in two variations, ie by the addition of 3% nano silica and without the addition of nanosilica. To know the mechanical properties of mortar, it is done testing of mortar compressive strength at the age of 28 days. Based on the analysis and evaluation, it is shown that compounds of silica sand in Indonesia, especially Papua reached more than 99% SiO2 and so that the amorphous character of silica sand can be used as a nanomaterial for concrete construction. The results of mechanical tests show that there is an increase of 12% compressive strength of mortar that is added with 3% nano silica.
The growth-defense trade-off and habitat specialization by plants in Amazonian forests.

PubMed

Fine, Paul V A; Miller, Zachariah J; Mesones, Italo; Irazuzta, Sebastian; Appel, Heidi M; Stevens, M Henry H; Sääksjärvi, Ilari; Schultz, Jack C; Coley, Phyllis D

2006-07-01

Tropical forests include a diversity of habitats, which has led to specialization in plants. Near Iquitos, in the Peruvian Amazon, nutrient-rich clay forests surround nutrient-poor white-sand forests, each harboring a unique composition of habitat specialist trees. We tested the hypothesis that the combination of impoverished soils and herbivory creates strong natural selection for plant defenses in white-sand forest, while rapid growth is favored in clay forests. Recently, we reported evidence from a reciprocal-transplant experiment that manipulated the presence of herbivores and involved 20 species from six genera, including phylogenetically independent pairs of closely related white-sand and clay specialists. When protected from herbivores, clay specialists exhibited faster growth rates than white-sand specialists in both habitats. But, when unprotected, white-sand specialists outperformed clay specialists in white-sand habitat, and clay specialists outperformed white-sand specialists in clay habitat. Here we test further the hypothesis that the growth defense trade-off contributes to habitat specialization by comparing patterns of growth, herbivory, and defensive traits in these same six genera of white-sand and clay specialists. While the probability of herbivore attack did not differ between the two habitats, an artificial defoliation experiment showed that the impact of herbivory on plant mortality was significantly greater in white-sand forests. We quantified the amount of terpenes, phenolics, leaf toughness, and available foliar protein for the plants in the experiment. Different genera invested in different defensive strategies, and we found strong evidence for phylogenetic constraint in defense type. Overall, however, we found significantly higher total defense investment for white-sand specialists, relative to their clay specialist congeners. Furthermore, herbivore resistance consistently exhibited a significant trade-off against growth rate in each of the six phylogenetically independent species-pairs. These results confirm theoretical predictions that a trade-off exists between growth rate and defense investment, causing white-sand and clay specialists to evolve divergent strategies. We propose that the growth-defense trade-off is universal and provides an important mechanism by which herbivores govern plant distribution patterns across resource gradients.
A Testing Service for Industry

NASA Technical Reports Server (NTRS)

1994-01-01

A small isolated NASA facility provides assistance to industry in the design, testing, and operation of oxygen systems. White Sands Test Facility (WSTF) was originally established to test rocket propulsion systems for the Apollo program. The facility's role was later expanded into testing characterization, flammability and toxicity characteristics of materials. Its materials and components test methods were adopted by the American society for Testing and Materials. When research and testing results became known, industry requested assistance, and in 1980, NASA authorized WSTF to open its facility to private firms, a valuable service, as oxygen systems testing is often too expensive and too hazardous for many companies. Today, some of the best known American industries utilize White Sands testing capabilities.
Observations of Kindergarten and First Grade Children's Development of Oral Language, Concepts about Print, and Reading Readiness.

ERIC Educational Resources Information Center

Day, Kaaren C.; Day, H. D.

A study originally involving 56 children from four schools was undertaken to observe the development of children's oral language and concepts of print during the kindergarten year using the Record of Oral Language (ROL) and the Concepts about Print (Sand) tests. In addition, the Sand test was administered early in the first grade to the available…
The Radar Roadmap

DTIC Science & Technology

2013-01-01

local oscillator to measure the phase of both the transmitted and received pulses and then matching them to the correct range ambiguity. 2.5 High...track closely spaced objects. White Sands Missile Range (WSMR) and Patrick Air Force Base (AFB) operate the phased -array AN/MPS-39 MOTRs. The...ABERDEEN TEST CENTER DUGWAY PROVING GROUND REAGAN TEST SITE YUMA PROVING GROUND WHITE SANDS MISSILE RANGE NAVAL AIR WARFARE CENTER AIRCRAFT
MULTISPECIES REACTIVE TRACER TEST IN A SAND AND GRAVEL AQUIFER, CAPE COD, MASSACHUSETTS: PART 1: EXPERIMENTAL DESIGN AND TRANSPORT OF BROMIDE AND NICKEL-EDTA TRACERS

EPA Science Inventory

In this report, we summarize a portion of the results of a large-scale tracer test conducted at the U. S. Geological Survey research site on Cape Cod, Massachusetts. The site is located on a large sand and gravel glacial outwash plain in an unconfined aquifer. In April 1993, ab...
Anti-A and anti-B hemagglutinin depletion during Cohn purification process of 5% immunoglobulin.

PubMed

Salvatore, Alfonso; Esin, Semih; Batoni, Giovanna; Ascione, Ester; Farina, Claudio; Nardini, Claudia

2015-07-01

Polyvalent immunoglobulin G (IgG) products obtained by fractionation of human plasma are widely used to treat a broad range of conditions, including immunodeficiency syndromes and autoimmune, inflammatory, and infectious diseases. For high-quality products and to minimize adverse events related to the use of intravenous IgG (IVIG) it is very important to perform detailed analyses of their components. One of these components, that in rare cases can cause severe hemolytic conditions, is the amount of hemagglutinins, natural antibodies that bind A and/or B (anti-A or -B) antigens present in red blood cells (RBCs). To characterize different IgG batches and to monitor the efficacy of the production procedure in the hemagglutinin reduction, a direct agglutination test (DAT) and a new flow cytometry (FC)-based assay were used for measuring the activity and the content of hemagglutinins in IgG samples obtained at different stages of the purification process. A total of 113 batches of 5% IVIG, produced in 2013 by Kedrion Biopharma, were analyzed for the ability to agglutinate RBCs by DAT. All batches tested were within the limits set by the European Pharmacopoeia. Three batches of 5% IVIG were analyzed for their hemagglutinin levels. The finished products and the production intermediates were evaluated by the DAT and the FC assay. A significant decrease of anti-A and anti-B titer after the Fraction (F)III precipitation was observed in all batches tested and an evaluation of the results obtained by the two methods was performed. This study shows that the hemagglutinin titer, accurately measured in a high number of 5% IVIG batches, is within the allowed limits for the DAT method. The specific production process employed, in particular the FIII precipitation step, successfully removes IgM and significantly reduces IgG class hemagglutinins. © 2015 AABB.
NE TARDIS Banner Event

NASA Image and Video Library

2017-12-08

NASA Kennedy Space Center's Engineering Director Pat Simpkins, at left, talks with Michael E. Johnson, a project engineer; and Emilio Cruz, deputy division chief in the Laboratories, Development and Testing Division, inside the Prototype Development Laboratory. A banner signing event was held to mark the successful delivery of a liquid oxygen test tank, called Tardis. Engineers and technicians worked together to develop the tank and build it at the lab to support cryogenic testing at Johnson Space Center's White Sands Test Facility in Las Cruces, New Mexico. The 12-foot-tall, 3,810-pound aluminum tank will be shipped to White Sands for testing.
Acoustic Scattering from Sand Dollars (Dendraster excentricus): Modeling as High Aspect Ratio Oblate Objects and Comparison to Experiment

DTIC Science & Technology

2008-09-01

2004), forward scattering and backscattering from a sand dollar test, a bivalve shell , and a machined aluminum disk of similar size were measured over a...Abstract Benthic shells can contribute greatly to the scattering variability of the ocean bottom, particularly at low grazing angles. Among the...effects of shell aggregates are increased scattering strength and potential subcritical angle penetration of the seafloor. Sand dollars (Dendraster
Separation and Depleted Uranium Fragments from Gun Test Catchment. Volume 2. Catchment System and Separations Methods

DTIC Science & Technology

1993-12-30

projectile fragments from target materials, principally sand. Phase I activities included (1) literature review of separations technology , (2) site visits, (3...the current operation, evaluation of alternative means for separation of DU from sand, a review of uranium mining technology for v possible...the current operation, evaluation of alternative means for separation of DU from sand, a review of uranium mining technology for possible
Interaction Effects of Simultaneous Torsional and Compressional Cyclic Loading of Sand.

DTIC Science & Technology

1979-12-01

loading 3a AftrRACT (rwo si .v1W f9111 t "Ofslr -d IderufI ST *lack ""iha)ln experimental research program based on laboratory test studies and scaled...experimental research program based on laboratory test studies and scaled slope model tests was conducted with specimens of Monterey No. 0 sand. The principal...objective of the research was to study the effects of interactive coupling during combined compression (normal) and shear loading on the response of
Mechanical Properties of Misers Bluff Sand.

DTIC Science & Technology

1986-09-01

in Chapter 4. 4 .7 Y~ e -~1 % CHAPTER 2 LABORATORY TESTS 2.1 CONVENTIONAL SOIL TESTS Samples of MB sand were split from the available supply of...air Va , and void ratio e (the ratio of void volume to solid volume). These composition data are listed in Table 2.1 for each test. 5 2.3 MECHANICAL...and diameter changes are made. The data can be plotted as principal stress difference versus axial strain, the slope of which is Young’s modulus E

Transport of Lactate-modified Nanoscale Iron Particles in Porous Media

NASA Astrophysics Data System (ADS)

Reddy, K. R.

2012-12-01

Nanoscale iron particles (NIP) have recently shown to be effective for dehalogenation of recalcitrant organic contaminants such as pentachlorphenol (PCP) and dinitrotoluene (DNT) in the environment. However, effective transport of NIP into the contaminated subsurface zones is crucial for the success of in-situ remediation. Previous studies showed that the transport of NIP in soils is very limited and surface-modification of NIP is required to achieve adequate transport. This paper investigates the transport of NIP and lactate-modified NIP (LMNIP) through four different porous media (sands with different particle size and distribution). A series of laboratory column experiments was conducted to quantify the transport of NIP and LMNIP at two different slurry concentrations of 1 g/L and 4 g/L under two different flow velcoities. NIP used in this study possessed magentic properties, thus a magnetic susceptibility sensor system was used to monitor the changes in magnetic susceptibility (MS) along the length of the column at different times during the experiments. At the end of testing, the distribution of total Fe in the sand column was measured. Results showed a linear correlation between the Fe concentration and MS and it was used to assess the transient transport of NIP and LMNIP in the sand columns. Results showed that LMNIP transported better than bare NIP and higher concentration of 4 g/L LMNIP exhibited unform and greater transport compared to other tested conditions. Transport of NIP increased in the order from fine Ottawa sand > medium field sand > coarse field sand > coarse Ottawa sand. Filtration theory and advective-dispersion equation with reaction were applied to capture the transport response of NIP and LMNIP in the sand columns.
Assessment of Mud-Capped Dredge Pit Evolution Offshore Louisiana: Implications to Sand Excavation and Coastal Restoration

NASA Astrophysics Data System (ADS)

Xu, K.; Miner, M. D.; Bentley, S. J.; Li, C.; Obelcz, J.; O'Connor, M. C.

2016-02-01

The shelf offshore Louisiana is characterized by a dominantly muddy seafloor with a paucity of restoration-quality sand proximal to shore. Discrete sand deposits associated with ancient rivers that incised the shelf during lower sea-level positions occur close to shore. These shelf channel sands have been targeted for coastal restoration projects resulting in significant cost savings over more distal deposits. Several recent projects targeted shelf paleo-fluvial deposits comprising relatively deep (10 m) channel sands underlying a muddy overburden. Because of contrasting characteristics of cohesive mud vs. non-cohesive sand and potential modern fluvial mud supply from the Mississippi and Atchafalaya Rivers, long term pit evolution is poorly understood relative to their more common sand-only counterparts. Alterations to seafloor topography from dredging shelf sediment resources can potentially affect oil and gas infrastructure or other resources of concern (i.e. historic shipwrecks) located proximal to dredge pits. Site-specific data required to make accurate predictions and empirical measurements to test and validate predictive models were only available for Peveto Channel offshore Holly Beach, Louisiana. Here we present new geophysical and geological data (bathymetry, sidescan, subbottom, and radionuclide of sediment cores) and physical oceanographic observations (hydrodynamics and sediment dynamics) collected at Raccoon Island (dredged in 2013) dredge pit in Louisiana. These field data collections along with pre-existing data provide a time-series to capture evolution at Raccoon Island post-excavation. Conceptual morphological models will be developed for dredge pit evolution and testing effectiveness of setback buffers protecting pipelines, habitats, and cultural resources. Our results will increase decision making ability regarding safety and protecting environmental and cultural resources, and better management of valuable sand resources.
Do peat amendments to oil sands wet sediments affect Carex aquatilis biomass for reclamation success?

PubMed

Roy, Marie-Claude; Mollard, Federico P O; Foote, A Lee

2014-06-15

The oil sands industries of Alberta (Canada) have reclamation objectives to return the mined landscape to equivalent pre-disturbance land capability. Industrial operators are charged with reclaiming a vast landscape of newly exposed sediments on saline-sodic marine-shales sediments. Incorporated in these sediments are by-products resulting from bitumen extraction (consolidated tailings (CT), tailings-sand (TS), and oil sands processed water (OSPW)). A sedge community dominated by Carex aquatilis was identified as a desirable and representative late-succession community for wet-meadow zones of oil sands-created marshes. However, the physical and chemical conditions, including high salinity and low nutrient content of CT and TS sediments suppress plant growth and performance. We experimentally tested the response of C. aquatilis to amendments with peat-mineral-mix (PM) on oil sand sediments (CT and TS). In a two factorial design experiment, we also tested the effects of OSPW on C. aquatilis. We assessed survival, below- and aboveground biomass, and physiology (chlorophyll a fluorescence). We demonstrated that PM amendments to oil sands sediments significantly increased C. aquatilis survival as well as below and aboveground biomass. The use of OSPW significantly reduced C. aquatilis belowground biomass and affected its physiological performance. Due to its tolerance and performance, we verified that C. aquatilis was a good candidate for use in reclaiming the wet-meadow zones of oil sands-created marshes. Ultimately, amending CT and TS with PM expedited the reclamation of the wetland to a C. aquatilis-community which was similar in gross structure to undisturbed wetlands of the region. Copyright © 2014 Elsevier Ltd. All rights reserved.
Catalytic wet-oxidation of a mixed liquid waste: COD and AOX abatement.

PubMed

Goi, D; de Leitenburg, C; Trovarelli, A; Dolcetti, G

2004-12-01

A series of catalytic wet oxidation (CWO) reactions, at temperatures of 430-500 K and in a batch bench-top pressure vessel were carried out utilizing a strong wastewater composed of landfill leachate and heavily organic halogen polluted industrial wastewater. A CeO2-SiO2 mixed oxide catalyst with large surface area to assure optimal oxidation performance was prepared. The catalytic process was examined during batch reactions controlling Chemical Oxygen Demand (COD) and Adsorbable Organic Halogen (AOX) parameters, resulting AOX abatement to achieve better effect. Color and pH were also controlled during batch tests. A simple first order-two stage reaction behavior was supposed and verified with the considered parameters. Finally an OUR test was carried out to evaluate biodegradability changes of wastewater as a result of the catalytic reaction.
Test sections containing natural and manufactured sands.

DOT National Transportation Integrated Search

1989-01-01

This report describes the materials, mix properties, and early pavement cross sections of two mixes placed on Route 50, Fairfax County, in August 1988. The difference in the two mixes was that one contained a natural and the other a manufactured sand...
About White Sands Missile Range

NASA Technical Reports Server (NTRS)

1991-01-01

Information on the White Sands Missile Range is given in viewgraph form. Navy programs, test sites, rocket programs, research rockets' booster capacity, current boost capabilities, ordnance and payload assembly areas, commercial space launch history and agreements, and lead times are among the topics covered.
67. Photograph of line drawing. PLANS AND SECTIONS OF 20,000 ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

67. Photograph of line drawing. PLANS AND SECTIONS OF 20,000 POUND MOTOR TEST AND LAUNCH FACILITY ('BLAST PIT'), DECEMBER 1945 - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
68. Photograph of line drawing. SECTIONS AND DETAILS OF 20,000 ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

68. Photograph of line drawing. SECTIONS AND DETAILS OF 20,000 POUND MOTOR TEST AND LAUNCH FACILITY ('BLAST PIT'), DECEMBER 1945 - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Soft sensor modeling based on variable partition ensemble method for nonlinear batch processes

NASA Astrophysics Data System (ADS)

Wang, Li; Chen, Xiangguang; Yang, Kai; Jin, Huaiping

2017-01-01

Batch processes are always characterized by nonlinear and system uncertain properties, therefore, the conventional single model may be ill-suited. A local learning strategy soft sensor based on variable partition ensemble method is developed for the quality prediction of nonlinear and non-Gaussian batch processes. A set of input variable sets are obtained by bootstrapping and PMI criterion. Then, multiple local GPR models are developed based on each local input variable set. When a new test data is coming, the posterior probability of each best performance local model is estimated based on Bayesian inference and used to combine these local GPR models to get the final prediction result. The proposed soft sensor is demonstrated by applying to an industrial fed-batch chlortetracycline fermentation process.
Improved model for detection of homogeneous production batches of electronic components

NASA Astrophysics Data System (ADS)

Kazakovtsev, L. A.; Orlov, V. I.; Stashkov, D. V.; Antamoshkin, A. N.; Masich, I. S.

2017-10-01

Supplying the electronic units of the complex technical systems with electronic devices of the proper quality is one of the most important problems for increasing the whole system reliability. Moreover, for reaching the highest reliability of an electronic unit, the electronic devices of the same type must have equal characteristics which assure their coherent operation. The highest homogeneity of the characteristics is reached if the electronic devices are manufactured as a single production batch. Moreover, each production batch must contain homogeneous raw materials. In this paper, we propose an improved model for detecting the homogeneous production batches of shipped lot of electronic components based on implementing the kurtosis criterion for the results of non-destructive testing performed for each lot of electronic devices used in the space industry.
Heater Validation for the NEXT-C Hollow Cathodes

NASA Technical Reports Server (NTRS)

Verhey, Timothy R.; Soulas, George C.; Mackey, Jonathan Ar.

2017-01-01

Swaged cathode heaters whose design was successfully demonstrated under a prior flight project are to be provided by the NASA Glenn Research Center for the NEXT-C ion thruster being fabricated by Aerojet Rocketdyne. Extensive requalification activities were performed to validate process controls that had to be re-established or revised because systemic changes prevented reuse of the past approaches. A development batch of heaters was successfully fabricated based on the new process controls. Acceptance and cyclic life testing of multiple discharge and neutralizer sized heaters extracted from the development batch was initiated in August, 2016, with the last heater completing testing in April, 2017. Cyclic life testing results substantially exceeded the NEXT-C thruster requirement as well as all past experience for GRC fabricated units. The heaters demonstrated ultimate cyclic life capability of 19050 to 33500 cycles. A qualification batch of heaters is now being fabricated using the finalized process controls. A set of six heaters will be acceptance and cyclic tested to verify conformance to the behavior observed with the development heaters. The heaters for flight use will be then be provided to the contractor. This paper summarizes the fabrication process control activities and the acceptance and life testing of the development heater units.
Spacecraft propulsion systems test capability at the NASA White Sands Test Facility

NASA Technical Reports Server (NTRS)

Baker, Pleddie; Gorham, Richard

1993-01-01

The NASA White Sands Facility (WSTF), a component insallation of the Johnson Space Center, is located on a 94-square-mile site in southwestern New Mexico. WSTF maintains many unique capabilities to support its mission to test and evaluate spacecraft materials, components, and propulsion systems to enable the safe human exploration and utilization of space. WSTF has tested over 340 rocket engines with more than 2.5 million firings to date. Included are propulsion system testing for Apollo, Shuttle, and now Space Station as well as unmanned spacecraft such as Viking, Pioneer, and Mars Observer. This paper describes the current WSTF propulsion test facilities and capabilities.
Effects of Uygur sand therapy on the mechanical properties of femurs in osteoarthritic rabbits.

PubMed

Maitirouzi, Julaiti; Yanna, Li; Abulizi, Adinaer; Aihemaitiniyazi, Aizezi; Kuerban, Shataer; Shaojun, Huang

2017-01-01

To investigate the effects of Uygur sand therapy on the mechanical properties of the femur bone of osteoarthritic rabbits. Sixteen rabbits were injected with papain in the right posterior femoral articular cavity on the first, fourth and seventh day to establish the osteoarthritis (OA) rabbit model. Animals were divided into the experimental group and control group (8 rabbits each). The experimental group was treated with sand therapy, and the control group received no sand therapy treatment. Computed tomography (CT) scanning was used to collect the data of the femur before modeling, after modeling and 14 and 28 days after sand treatment. A 3D model of the femur was generated with the MIMIC software the bone layer was divided according to the different gray values and the change of the bone volume was analyzed. The body mesh is divided, and the material properties are given, then the three-point bending simulation is performed in Ansys. Additionally, the three-point bending test was performed on all the rabbits' femur to obtain the deflection and maximum stress values. And the effects of the sand treatment on the volume and mechanical properties of the bone were analyzed. Finally, the simulation results are compared with the experimental results, and the effects of sand treatment on the volume and mechanical properties of the bone are analyzed. (1) there is a tendency in the control group to convert the hard bone into dense bone and soft bone, while in the experimental group, the soft bone is converted into dense bone and hard bone obviously; (2) the morphological parameters of the experimental group are lower than those of the control group, whereas the maximum load, maximum normal stress, maximum shear stress of the experimental group are higher than those of the control group. (3) The mechanical test of three-point bending test was carried out using the three dimensional finite element model of rabbit femur. The sand therapy has positive effects on the volume distribution of bone layer and the mechanical properties of the femur of adult osteoarthritic rabbits.
The Role of Natural Hydrate on the Strength of Sands: Load-bearing or Cementing?

NASA Astrophysics Data System (ADS)

Priest, J. A.; Hayley, J. L.

2017-12-01

The strength of hydrate bearing sands is a key parameter for simulating the long-term performance of hydrate reservoirs during gas production and assessing reservoir and wellbore stability. Historically this parameter has been determined from testing synthesized hydrate sand samples, which has led to significant differences in measured strength that appears to reflect different formation methods adopted. At present, formation methods can be grouped into either those that form hydrate at grain contacts leading to a high strength `cemented' sand, or those where the hydrate forms a `load-bearing' structure in which the hydrate grains reside in the pore space resulting in more subtle changes in strength. Recovered natural hydrate-bearing cores typically exhibit this `load-bearing' behavior, although these cores have generally undergone significant changes in temperature and pressure during recovery, which may have altered the structure of the hydrate and sediment. Recent drilling expeditions using pressure coring, such as NGHP2 offshore India, have enabled intact hydrate bearing sediments to be recovered that have maintained hydrostatic stresses minimizing any changes in the hydrate structure within the core. Triaxial testing on these samples highlight enhanced strength even at zero effective stresses. This suggests that the hydrate forms a connected framework within the pore space apparently `cementing' the sand grains in place: we differentiate here between true cementation where hydrate is sintered onto the sand grains and typical observed behavior for cemented sands (cohesion, peak strength, post-peak strain softening). This inter-connected hydrate, and its ability to increase strength of the sands, appears to occur even at hydrate saturations as low as 30%, where typical `load-bearing' hydrates just start to increase strength. The results from pressure cores suggest that hydrate formation techniques that lead to `load-bearing' behavior may not capture the true interaction between the hydrate and sand and thus further research is needed to form synthesized hydrate bearing samples that more realistically mimic the observed strength behavior of natural hydrate bearing cores.
Site selection for DOE/JIP gas hydrate drilling in the northern Gulf of Mexico

USGS Publications Warehouse

Hutchinson, Deborah; Shelander, Dianna; Dai, J.; McConnell, D.; Shedd, William; Frye, Matthew; Ruppel, Carolyn D.; Boswell, R.; Jones, Emrys; Collett, Timothy S.; Rose, Kelly K.; Dugan, Brandon; Wood, Warren T.

2008-01-01

n the late spring of 2008, the Chevron-led Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) expects to conduct an exploratory drilling and logging campaign to better understand gas hydrate-bearing sands in the deepwater Gulf of Mexico. The JIP Site Selection team selected three areas to test alternative geological models and geophysical interpretations supporting the existence of potential high gas hydrate saturations in reservoir-quality sands. The three sites are near existing drill holes which provide geological and geophysical constraints in Alaminos Canyon (AC) lease block 818, Green Canyon (GC) 955, and Walker Ridge (WR) 313. At the AC818 site, gas hydrate is interpreted to occur within the Oligocene Frio volcaniclastic sand at the crest of a fold that is shallow enough to be in the hydrate stability zone. Drilling at GC955 will sample a faulted, buried Pleistocene channel-levee system in an area characterized by seafloor fluid expulsion features, structural closure associated with uplifted salt, and abundant seismic evidence for upward migration of fluids and gas into the sand-rich parts of the sedimentary section. Drilling at WR313 targets ponded sheet sands and associated channel/levee deposits within a minibasin, making this a non-structural play. The potential for gas hydrate occurrence at WR313 is supported by shingled phase reversals consistent with the transition from gas-charged sand to overlying gas-hydrate saturated sand. Drilling locations have been selected at each site to 1) test geological methods and models used to infer the occurrence of gas hydrate in sand reservoirs in different settings in the northern Gulf of Mexico; 2) calibrate geophysical models used to detect gas hydrate sands, map reservoir thicknesses, and estimate the degree of gas hydrate saturation; and 3) delineate potential locations for subsequent JIP drilling and coring operations that will collect samples for comprehensive physical property, geochemical and other analyses
Experimental Investigation on Dilation Mechanisms of Land-Facies Karamay Oil Sand Reservoirs under Water Injection

NASA Astrophysics Data System (ADS)

Lin, Botao; Jin, Yan; Pang, Huiwen; Cerato, Amy B.

2016-04-01

The success of steam-assisted gravity drainage (SAGD) is strongly dependent on the formation of a homogeneous and highly permeable zone in the land-facies Karamay oil sand reservoirs. To accomplish this, hydraulic fracturing is applied through controlled water injection to a pair of horizontal wells to create a dilation zone between the dual wells. The mechanical response of the reservoirs during this injection process, however, has remained unclear for the land-facies oil sand that has a loosely packed structure. This research conducted triaxial, permeability and scanning electron microscopy (SEM) tests on the field-collected oil sand samples. The tests evaluated the influences of the field temperature, confining stress and injection pressure on the dilation mechanisms as shear dilation and tensile parting during injection. To account for petrophysical heterogeneity, five reservoir rocks including regular oil sand, mud-rich oil sand, bitumen-rich oil sand, mudstone and sandstone were investigated. It was found that the permeability evolution in the oil sand samples subjected to shear dilation closely followed the porosity and microcrack evolutions in the shear bands. In contrast, the mudstone and sandstone samples developed distinct shear planes, which formed preferred permeation paths. Tensile parting expanded the pore space and increased the permeability of all the samples in various degrees. Based on this analysis, it is concluded that the range of injection propagation in the pay zone determines the overall quality of hydraulic fracturing, while the injection pressure must be carefully controlled. A region in a reservoir has little dilation upon injection if it remains unsaturated. Moreover, a cooling of the injected water can strengthen the dilation potential of a reservoir. Finally, it is suggested that the numerical modeling of water injection in the Karamay oil sand reservoirs must take into account the volumetric plastic strain in hydrostatic loading.
40 CFR Table 2 to Subpart Sssss of... - Operating Limits

Code of Federal Regulations, 2010 CFR

2010-07-01

... activity level of the catalyst at least every 12 months. 7. Each affected batch process unit For each batch... activity level of the catalyst at least every 12 months. 10. Each new kiln that is used to process clay... across the DLA at or above the minimum levels established during the most recent performance test; and b...
40 CFR Table 2 to Subpart Sssss of... - Operating Limits

Code of Federal Regulations, 2011 CFR

2011-07-01

... activity level of the catalyst at least every 12 months. 7. Each affected batch process unit For each batch... activity level of the catalyst at least every 12 months. 10. Each new kiln that is used to process clay... across the DLA at or above the minimum levels established during the most recent performance test; and b...
40 CFR 61.164 - Test methods and procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

... glass type (i) produced during the 12-month period, as follows: ER17OC00.483 Where: Ti = The theoretical uncontrolled arsenic emission factor for each glass type (i), g/kg (lb/ton). Abi = Fraction by weight of elemental arsenic in the fresh batch for each glass type (I). Wbi = Weight of fresh batch melted per unit...
Trajectories of saltating sand particles behind a porous fence

NASA Astrophysics Data System (ADS)

Zhang, Ning; Lee, Sang Joon; Chen, Ting-Guo

2015-01-01

Trajectories of aeolian sand particles behind a porous wind fence embedded in a simulated atmospheric boundary layer were visualized experimentally, to investigate the shelter effect of the fence on sand saltation. Two sand samples, one collected from a beach (d = 250 μm) and the other from a desert (d = 100 μm), were tested in comparison with the previous studies of a 'no-fence' case. A wind fence (ε = 38.5%) was installed on a flat sand bed filled with each sand sample. A high-speed photography technique and the particle tracking velocimetry (PTV) method were employed to reconstruct the trajectories of particles saltating behind the fence. The collision processes of these sand particles were analyzed, momentum and kinetic energy transfer between saltating particles and ground surface were also investigated. In the wake region, probability density distributions of the impact velocities agree well with the pattern of no-fence case, and can be explained by a log-normal law. The horizontal component of impact velocity for the beach sand is decreased by about 54%, and about 76% for the desert sand. Vertical restitution coefficients of bouncing particles are smaller than 1.0 due to the presence of the wind fence. The saltating particles lose a large proportion of their energy during the collision process. These results illustrate that the porous wind fence effectively abates the further evolution of saltating sand particles.

Experimental Investigations on the Pull-Out Behavior of Tire Strips Reinforced Sands

PubMed Central

Li, Li-Hua; Chen, Yan-Jun; Ferreira, Pedro Miguel Vaz; Liu, Yong; Xiao, Heng-Lin

2017-01-01

Waste tires have excellent mechanical performance and have been used as reinforcing material in geotechnical engineering; however, their interface properties are poorly understood. To further our knowledge, this paper examines the pull-out characteristics of waste tire strips in a compacted sand, together with uniaxial and biaxial geogrids also tested under the same conditions. The analysis of the results shows that the interlocking effect and pull-out resistance between the tire strip and the sand is very strong and significantly higher than that of the geogrids. In the early stages of the pull-out test, the resistance is mainly provided by the front portion of the embedded tire strips, as the pull-out test continues, more and more of the areas towards the end of the tire strips are mobilized, showing a progressive failure mechanism. The deformations are proportional to the frictional resistance between the tire-sand interface, and increase as the normal stresses increase. Tire strips of different wear intensities were tested and presented different pull-out resistances; however, the pull-out resistance mobilization patterns were generally similar. The pull-out resistance values obtained show that rubber reinforcement can provide much higher pull-out forces than the geogrid reinforcements tested here, showing that waste tires are an excellent alternative as a reinforcing system, regardless of the environmental advantages. PMID:28773069
Butyric acid fermentation of sodium hydroxide pretreated rice straw with undefined mixed culture.

PubMed

Ai, Binling; Li, Jianzheng; Chi, Xue; Meng, Jia; Liu, Chong; Shi, En

2014-05-01

This study describes an alternative mixed culture fermentation technology to anaerobically convert lignocellulosic biomass into butyric acid, a valuable product with wide application, without supplementary cellulolytic enzymes. Rice straw was soaked in 1% NaOH solution to increase digestibility. Among the tested pretreatment conditions, soaking rice straw at 50°C for 72 h removed ~66% of the lignin, but retained ~84% of the cellulose and ~71% of the hemicellulose. By using an undefined cellulose-degrading butyrate-producing microbial community as butyric acid producer in batch fermentation, about 6 g/l of butyric acid was produced from the pretreated rice straw, which accounted for ~76% of the total volatile fatty acids. In the repeated-batch operation, the butyric acid production declined batch by batch, which was most possibly caused by the shift of microbial community structure monitored by denaturing gradient gel electrophoresis. In this study, batch operation was observed to be more suitable for butyric acid production.
Generation rate and particle size distribution of wood dust by handheld sanding operation.

PubMed

Ojima, Jun

2016-11-29

The International Agency for Research on Cancer (IARC) and Japan Society for Occupational Health (JSOH) classified wood dust as a human carcinogen. Former studies have suggested that sanding with a portable sander is one of the processes that are liable to cause highest exposure to wood dust. However, the wood dust by sanding operation has not been investigated sufficiently. In this study, the generation rate and the particle size distribution of the wood dust produced by handheld sanding operation were observed by laboratory experiments. Beech and cypress were taken as typical hard and soft wood specimen respectively, and sanded with a portable sander. Three grades of sand paper (coarse, medium, fine) were attached to the sander in turn to be tested. The quantity of the wood dust produced by the sander was measured by weighing the specimen before and after the sanding and then the generation rate of the dust was calculated. Soft wood generated more dust than hard wood due to the difference in abrasion durability. A coarse sand paper produced more dust than a fine sand paper. The particles of less than 1 μm diameter were scarcely observed in the wood dust. When the specimens were sanded with a fine sand paper, the mass median aerodynamic diameters of beech dust and cypress dust were 9.0 μm and 9.8 μm, respectively. Respirable wood dust is able to be controlled by general ventilation with more than 0.7-4.2 m 3 /min ventilation rate.
Transport of fine sediment over a coarse, immobile riverbed

USGS Publications Warehouse

Grams, Paul E.; Wilcock, Peter R.

2014-01-01

Sediment transport in cobble-boulder rivers consists mostly of fine sediment moving over a coarse, immobile bed. Transport rate depends on several interrelated factors: boundary shear stress, the grain size and volume of fine sediment, and the configuration of fine sediment into interstitial deposits and bed forms. Existing models do not incorporate all of these factors. Approaches that partition stress face a daunting challenge because most of the boundary shear is exerted on immobile grains. We present an alternative approach that divides the bed into sand patches and interstitial deposits and is well constrained by two clear end-member cases: full sand cover and absence of sand. Entrainment from sand patches is a function of their aerial coverage. Entrainment from interstices among immobile grains is a function of sand elevation relative to the size of the immobile grains. The bed-sand coverage function is used to predict the ratio of the rate of entrainment from a partially covered bed to the rate of entrainment from a completely sand-covered bed, which is determined using a standard sand transport model. We implement the bed-sand coverage function in a morphodynamic routing model and test it against observations of sand bed elevation and suspended sand concentration for conditions of nonuniform fine sediment transport in a large flume with steady uniform flow over immobile hemispheres. The results suggest that this approach may provide a simple and robust method for predicting the transport and migration of fine sediment through rivers with coarse, immobile beds.
Feeding preferences of Lutzomyia longipalpis (Diptera: Psychodidae), the sand fly vector, for Leishmania infantum (Kinetoplastida: Trypanosomatidae).

PubMed

Macedo-Silva, Virgínia P; Martins, Daniella R A; De Queiroz, Paula Vivianne Souza; Pinheiro, Marcos Paulo G; Freire, Caio C M; Queiroz, José W; Dupnik, Kathryn M; Pearson, Richard D; Wilson, Mary E; Jeronimo, Selma M B; Ximenes, Maria De Fátima F M

2014-01-01

Leishmania infantum, the causative agent of visceral leishmaniasis (VL) in Brazil, is spread mostly by the bite of the sand fly Lutzomyia longipalpis (Lutz & Neiva). We trapped sand flies in endemic neighborhoods near Natal, Brazil, where cases of human and dog VL were documented. Amplification of species-specific cytochrome b (Cyt b) genes by polymerase chain reaction revealed that sand flies from rural and periurban areas harbored blood from different sources. The most common source ofbloodmeal was human, but blood from dog, chicken, and armadillo was also present. We tested the preference for a source of bloodmeal experimentally by feeding L. longipalpis F1 with blood from different animals. There were significant differences between the proportion of flies engorged and number of eggs laid among flies fed on different sources, varying from 8.4 to 19 (P < 0.0001). Blood from guinea pig or horse was best to support sand fly oviposition, but human blood also supported sand fly oviposition well. No sand flies fed on cats, and sand flies feeding on the opossum Monodelphis domestica Wagner produced no eggs. These data support the hypothesis that L. longipalpis is an eclectic feeder, and humans are an important source of blood for this sand fly species in periurban areas of Brazil.
Feeding Preferences of Lutzomyia longipalpis (Diptera: Psychodidae), the Sand Fly Vector, for Leishmania infantum (Kinetoplastida: Trypanosomatidae)

PubMed Central

Macedo-Silva, Virgínia P.; Martins, Daniella R. A.; De Queiroz, Paula Vivianne Souza; Pinheiro, Marcos Paulo G.; Freire, Caio C. M.; Queiroz, José W.; Dupnik, Kathryn M.; Pearson, Richard D.; Wilson, Mary E.; Jeronimo, Selma M. B.; Ximenes, Maria De Fátima F.M.

2014-01-01

Leishmania infantum, the causative agent of visceral leishmaniasis (VL) in Brazil, is spread mostly by the bite of the sand fly Lutzomyia longipalpis (Lutz & Neiva). We trapped sand flies in endemic neighborhoods near Natal, Brazil, where cases of human and dog VL were documented. Amplification of species-specific cytochrome b (Cyt b) genes by polymerase chain reaction revealed that sand flies from rural and periurban areas harbored blood from different sources. The most common source of bloodmeal was human, but blood from dog, chicken, and armadillo was also present. We tested the preference for a source of bloodmeal experimentally by feeding L. longipalpis F1 with blood from different animals. There were significant differences between the proportion of flies engorged and number of eggs laid among flies fed on different sources, varying from 8.4 to 19 (P < 0.0001). Blood from guinea pig or horse was best to support sand fly oviposition, but human blood also supported sand fly oviposition well. No sand flies fed on cats, and sand flies feeding on the opossum Monodelphis domestica Wagner produced no eggs. These data support the hypothesis that L. longipalpis is an eclectic feeder, and humans are an important source of blood for this sand fly species in periurban areas of Brazil. PMID:24605474
Unloading Characteristics of Sand-drift in Wind-shallow Areas along Railway and the Effect of Sand Removal by Force of Wind

PubMed Central

Cheng, Jian-jun; Xin, Guo-Wei; Zhi, Ling-yan; Jiang, Fu-qiang

2017-01-01

Wind-shield walls decrease the velocity of wind-drift sand flow in transit. This results in sand accumulating in the wind-shadow zone of both windshield wall and track line, causing severe sand sediment hazard. This study reveals the characteristics of sand accumulation and the laws of wind-blown sand removal in the wind-shadow areas of three different types of windshield walls, utilizing three-dimensional numerical simulations and wind tunnel experiments and on-site sand sediment tests. The results revealed the formation of apparent vortex and acceleration zones on the leeward side of solid windshield walls. For uniform openings, the vortex area moved back and narrowed. When bottom-opening windshield walls were adopted, the track-supporting layer at the step became a conflux acceleration zone, forming a low velocity vortex zone near the track line. At high wind speeds, windshield walls with bottom-openings achieved improved sand dredging. Considering hydrodynamic mechanisms, the flow field structure on the leeward side of different types of windshield structures is a result of convergence and diffusion of fluids caused by an obstacle. This convergence and diffusion effect of air fluid is more apparent at high wind velocities, but not obvious at low wind velocities. PMID:28120915
Experimental and modeling of the unsaturated transports of S-metolachlor and its metabolites in glaciofluvial vadose zone solids.

PubMed

Sidoli, Pauline; Lassabatere, Laurent; Angulo-Jaramillo, Rafael; Baran, Nicole

2016-07-01

The transport of pesticides to groundwater is assumed to be impacted by flow processes and geochemical interactions occurring in the vadose zone. In this study, the transport of S-metolachlor (SMOC) and its two metabolites ESA-metolachlor (MESA) and OXA-metolachlor (MOXA) in vadose zone materials of a glaciofluvial aquifer is studied at laboratory scale. Column experiments are used to study the leaching of a conservative tracer (bromide) and SMOC, MESA and MOXA under unsaturated conditions in two lithofacies, a bimodal gravel (Gcm,b) and a sand (S-x). Tracer experiments showed water fractionation into mobile and immobile compartments more pronounced in bimodal gravel columns. In both lithofacies columns, SMOC outflow is delayed (retardation factor>2) and mass balance reveals depletion (mass balance of 0.59 and 0.77 in bimodal gravel and sand, respectively). However, complete mass elution associated with retardation factors close to unity shows that there is no adsorption of MESA and MOXA in either lithofacies. SMOC transport is characterized by non-equilibrium sorption and sink term in both bimodal gravel and sand columns. Batch experiments carried out using agitation times consistent with column water residence times confirmed a time-dependence of SMOC sorption and high adsorption rates (>80%) of applied concentrations. Desorption experiments confirm the irreversibility of a major part of the SMOC adsorption onto particles, corresponding to the sink term in columns. In the bimodal gravel column, SMOC adsorption occurs mainly on reactive particles in contact with mobile water because of flow regionalization whereas in the sand column, there is pesticide diffusion to the immobile water. Such results clearly show that sorption mechanisms in the vadose zone solids below the soil are both solute and contact-time-dependent and are impacted by hydrodynamic conditions. The more rapid transport of MESA and MOXA to the aquifer would be controlled mainly by water flow through the unsaturated zone whereas SMOC transport is retarded by sorption processes within the vadose zone. Copyright © 2016 Elsevier B.V. All rights reserved.
Results Of Initial Analyses Of The Salt (Macro) Batch 9 Tank 21H Qualification Samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T.

2015-10-08

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Interim Salt Disposition Project (ISDP) Salt (Macro) Batch 9 for processing through the Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU). This document reports the initial results of the analyses of samples of Tank 21H. Analysis of the Tank 21H Salt (Macro) Batch 9 composite sample indicates that the material does not display any unusual characteristics. Further results on the chemistry and other tests will be issued in the future.
Effect of unground oil palm ash as mixing ingredient towards properties of concrete

NASA Astrophysics Data System (ADS)

Sulaiman, M. A.; Muthusamy, K.; Mat Aris, S.; Rasid, M. H. Mohd; Paramasivam, R.; Othman, R.

2018-04-01

Malaysia being one of the world largest palm oil producers generates palm oil fuel ash (POFA), a by-product in increasing quantity. This material which usually disposed as solid waste causes pollution to the environment. Success in converting this waste material into benefitting product would reduce amount of waste disposed and contributes towards cleaner environment. This research explores the potential of unground oil palm ash being used as partial sand replacement in normal concrete production. Experimental work has been conducted to determine the workability, compressive strength and flexural strength of concrete when unground oil palm ash is added as partial sand replacement. A total of five mixes containing various percentage of oil palm ash, which are 0%, 5%, 10%, 15% and 20% have been prepared. All specimens were water cured until the testing date. The slump test, compressive strength test and flexural strength test was conducted. The findings show that mix produced using 10% of palm oil fuel ash exhibit higher compressive strength and flexural strength as compared to control specimen. Utilization of unground oil palm ash as partial sand replacement would be able to reduce dependency of construction industry on natural sand supply and also as one of the solution to reuse palm oil industry waste.
Thermodynamic parameters of U (VI) sorption onto soils in aquatic systems.

PubMed

Kumar, Ajay; Rout, Sabyasachi; Ghosh, Malay; Singhal, Rakesh Kumar; Ravi, Pazhayath Mana

2013-01-01

The thermodynamic parameters viz. the standard free energy (∆Gº), Standard enthalpy change (∆Hº) and standard entropy change (∆Sº) were determined using the obtained values of distribution coefficient (kd) of U (VI) in two different types of soils (agricultural and undisturbed) by conducting a batch equilibrium experiment with aqueous media (groundwater and deionised water) at two different temperatures 25°C and 50°C. The obtained distribution coefficients (kd) values of U for undisturbed soil in groundwater showed about 75% higher than in agricultural soil at 25°C while in deionised water, these values were highly insignificant for both soils indicating that groundwater was observed to be more favorable for high surface sorption. At 50°C, the increased kd values in both soils revealed that solubility of U decreased with increasing temperature. Batch adsorption results indicated that U sorption onto soils was promoted at higher temperature and an endothermic and spontaneous interfacial process. The high positive values of ∆Sº for agricultural soil suggested a decrease in sorption capacity of U in that soil due to increased randomness at solid-solution interface. The low sorption onto agricultural soil may be due to presence of high amount of coarse particles in the form of sand (56%). Geochemical modeling predicted that mixed hydroxo-carbonato complexes of uranium were the most stable and abundant complexes in equilibrium solution during experimental.
Advanced stimulation technology deployment program, Chevron USA Production Company, Wolfcamp A2 Sand, Pakenham Field, Val Verde Basin. Topical report, July 1995-March 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wright, C.A.; Weijers, L.; Minner, W.A.

1996-07-01

This report describes the results from Chevron`s Pakenham Field effort at fracture stimulation engineering which incorporated, to the greatest extent possible, the results of actual measured field data. Measurement of the sand-shale closure stress contrast around the Wolfcamp A2 sand and the relatively high net fracturing pressures (compared to the closure stress contrast) that were observed during real-data (net pressure) fracture treatment analysis revealed that fractures obtained in most of the treatments were much shorter and less confined than originally expected: the fracture half-length was about 200 to 300 ft (instead of about 600 ft), which is consistent with estimatesmore » from post-fracture pressure build-up tests. Based on these measurements, Chevron`s fracturing practices in the Pakenham Field could be carefully reviewed to enhance fracture economics. Supported by the real-data fracture treatment analysis, several changes in completion, fracture treatment design and data-collection procedures were made, such as: (1) using cheaper 20/40 Ottawa sand instead of pre-cured 20/40 resin coated sand; (2) reducing the pad fluid size, as fluid leakoff from the fracture into the formation was relatively low; and, (3) utilizing stepdown tests and proppant slugs to minimize near-wellbore screen-out potential (in the Wolfcamp D sand).« less
63. Photograph of line drawing. SITE PLAN OF GANTRY CRANE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

63. Photograph of line drawing. SITE PLAN OF GANTRY CRANE TRACKS AND 20,000 POUND MOTOR TEST AND LAUNCH FACILITY ('BLAST PIT'), OCTOBER 1946 - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Quality-by-Design approach to monitor the operation of a batch bioreactor in an industrial avian vaccine manufacturing process.

PubMed

Largoni, Martina; Facco, Pierantonio; Bernini, Donatella; Bezzo, Fabrizio; Barolo, Massimiliano

2015-10-10

Monitoring batch bioreactors is a complex task, due to the fact that several sources of variability can affect a running batch and impact on the final product quality. Additionally, the product quality itself may not be measurable on line, but requires sampling and lab analysis taking several days to be completed. In this study we show that, by using appropriate process analytical technology tools, the operation of an industrial batch bioreactor used in avian vaccine manufacturing can be effectively monitored as the batch progresses. Multivariate statistical models are built from historical databases of batches already completed, and they are used to enable the real time identification of the variability sources, to reliably predict the final product quality, and to improve process understanding, paving the way to a reduction of final product rejections, as well as to a reduction of the product cycle time. It is also shown that the product quality "builds up" mainly during the first half of a batch, suggesting on the one side that reducing the variability during this period is crucial, and on the other side that the batch length can possibly be shortened. Overall, the study demonstrates that, by using a Quality-by-Design approach centered on the appropriate use of mathematical modeling, quality can indeed be built "by design" into the final product, whereas the role of end-point product testing can progressively reduce its importance in product manufacturing. Copyright © 2015 Elsevier B.V. All rights reserved.
Collaborative study for the calibration of replacement batches for the heparin low-molecular-mass for assay biological reference preparation.

PubMed

Terao, E; Daas, A

2016-01-01

The European Pharmacopoeia (Ph. Eur.) prescribes the control of the activity of low molecular mass heparins by assays for anti-Xa and anti-IIa activities (monograph 0828), using a reference standard calibrated in International Units (IU). An international collaborative study coded BSP133 was launched in the framework of the Biological Standardisation Programme (BSP) run under the aegis of the Council of Europe and the European Commission to calibrate replacement batches for the dwindling stocks of the Heparin low-molecular-mass for assay Biological Reference Preparation (BRP) batch 8. Thirteen official medicines control and manufacturers laboratories from European and non-European countries took part in this study to calibrate two freeze-dried candidate batches against the 3rd International Standard (IS) for heparin, low molecular weight (11/176; 3rd IS). The Heparin low-molecular-mass for assay BRP (batch 8) was also included in the test panel to check the continuity between subsequent BRP batches. Taking into account the stability data, the results of this collaborative study and on the basis of the central statistical analysis performed at the European Directorate for the Quality of Medicines & HealthCare (EDQM), the 2 candidate batches were officially adopted by the Commission of the European Pharmacopoeia as Heparin low-molecular-mass for assay BRP batches 9 and 10 with assigned anti-Xa activities of 102 and 100 IU/vial and anti-IIa activities of 34 and 33 IU/vial respectively.
Can pore-clogging by ash explain post-fire runoff?

USGS Publications Warehouse

Stoof, Cathelijne R.; Gevaert, Anouk I.; Baver, Christine; Hassanpour, Bahareh; Morales, Veronica L.; Zhang, Wei; Martin, Deborah; Giri, Shree K.; Steenhuis, Tammo S.

2016-01-01

Ash plays an important role in controlling runoff and erosion processes after wildfire and has frequently been hypothesised to clog soil pores and reduce infiltration. Yet evidence for clogging is incomplete, as research has focussed on identifying the presence of ash in soil; the actual flow processes remain unknown. We conducted laboratory infiltration experiments coupled with microscope observations in pure sands, saturated hydraulic conductivity analysis, and interaction energy calculations, to test whether ash can clog pores (i.e. block pores such that infiltration is hampered and ponding occurs). Although results confirmed previous observations of ash washing into pores, clogging was not observed in the pure sands tested, nor were conditions found for which this does occur. Clogging by means of strong attachment of ash to sand was deemed unlikely given the negative surface charge of the two materials. Ponding due to washing in of ash was also considered improbable given the high saturated conductivity of pure ash and ash–sand mixtures. This first mechanistic step towards analysing ash transport and attachment processes in field soils therefore suggests that pore clogging by ash is unlikely to occur in sands. Discussion is provided on other mechanisms by which ash can affect post-fire hydrology.
A study of morphology, provenance, and movement of desert sand seas in Africa, Asia, and Australia

NASA Technical Reports Server (NTRS)

Mckee, E. D. (Principal Investigator); Breed, C. S.

1973-01-01

The author has identified the following significant results. Recent acquisition of generally high quality color prints for most of the test sites has enabled the project to make significant advances in preparing mosaics of sand desert areas under study. Computer enhancement of imagery of selected sites, where details of complex dune forms need to be determined, has been achieved with arrival of computer-compatible ERTS-1 tapes. Further, a comparator, recently received, gives precise visual measurements of width, length, and spacing of sand bodies and so improves comparison of patterns in various test sites. Considerable additional meteorological data recently received on sand-moving winds in China, Pakistan, Libya and other areas enabled much progress to be made in developing overlays for the dune mosaics. These data show direction, speed, and frequency of winds. Other new data for use in preparing overlays used with ERTS-1 image mosaics include ground truth on moisture control, geologic settings, and plant distribution. With the addition of visual observation data and prints from hand-held photography now being obtained by the Skylab mission, much progress in interpreting the patterns of sand seas for 17 desert sites is anticipated.
A study of morphology, provenance, and movement of desert sand seas in Africa, Asia, and Australia

NASA Technical Reports Server (NTRS)

Mckee, E. D. (Principal Investigator); Breed, C. S.

1974-01-01

The author has identified the following significant results. Recent acquisition of generally high quality color prints for most of the test sites has enabled this project to make significant advances in preparing mosaics of sand desert areas under study. Computer enhancement of imagery, where details of complex dune forms need to be determined, has been achieved with arrival of computer-compatible ERTS-1 tapes. Further, a comparator, recently received, gives precise visual measurements of width, length, and spacing of sand bodies and so improves comparison of patterns in various test sites. Considerable additional meteorological data recently received on sand-moving winds in China, Pakistan, Libya, and other study areas enabled much progress to be made in developing overlays for the dune mosaics. These data show direction, speed, and frequency of winds. Other new data for use in preparing overlays used with ERTS-1 image mosaics include ground truth on moisture control, geologic settings, and plant distribution. With the addition of visual observation data and prints from hand-held photography now being obtained by the Skylab 4 mission, much progress in interpreting the patterns of sand seas for 17 desert sites is anticipated.
Hydrogeologic characteristics and water quality of a confined sand unit in the surficial aquifer system, Hunter Army Airfield, Chatham County, Georgia

USGS Publications Warehouse

Gonthier, Gerard

2012-01-01

An 80-foot-deep well (36Q397, U.S. Geological Survey site identification 320146081073701) was constructed at Hunter Army Airfield to assess the potential of using the surficial aquifer system as a water source to irrigate a ballfield complex. A 300-foot-deep test hole was drilled beneath the ballfield complex to characterize the lithology and water-bearing characteristics of sediments above the Upper Floridan aquifer. The test hole was then completed as well 36Q397 open to a 19-foot-thick shallow, confined sand unit contained within the surficial aquifer system. A single-well, 24-hour aquifer test was performed by pumping well 36Q397 at a rate of 50 gallons per minute during July 13-14, 2011, to characterize the hydrologic properties of the shallow, confined sand unit. Two pumping events prior to the aquifer test affected water levels. Drawdown during all three pumping events and residual drawdown during recovery periods were simulated using the Theis formula on multiple changes in discharge rate. Simulated drawdown and residual drawdown match well with measured drawdown and residual drawdown using values of horizontal hydraulic conductivity and specific storage, which are typical for a confined sand aquifer. Based on the hydrologic parameters used to match simulated drawdown and residual drawdown to measured drawdown and residual drawdown, the transmissivity of the sand was determined to be about 400 feet squared per day. The horizontal hydraulic conductivity of the sand was determined to be about 20 feet per day. Analysis of a water-quality sample indicated that the water is suitable for irrigation. Sample analysis indicated a calcium-carbonate type water having a total dissolved solids concentration of 39 milligrams per liter. Specific conductance and concentrations of all analyzed constituents were below those that would be a concern for irrigation, and were below primary and secondary water-quality criteria levels.
TESTING OF TMR SAND MANTIS FINAL REPORT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krementz, D; William Daugherty, W

2007-06-12

Screening tests of Sand Mantis candidate materials selected for erosion resistance have been completed. The results of this testing identified that over a relatively short period of operation (<1 hour), measurable erosion will occur in each of the candidate zoom tube materials given equal operating exposure. Additionally, this testing has shown that erosion of the rubber discharge hose directly downstream of the vehicle could be expected to limit the service life of the discharge hose. On the basis of these test results, SRNL recommends the following; {lg_bullet} redesign of critical system components (e.g., zoom tube, discharge hose) should be conductedmore » to improve system characteristics relative to erosion and capitalize on the results of this testing, {lg_bullet} continued efforts to deploy the Sand Mantis should include testing to better define and optimize operating parameters, and gain an understanding of system dynamics, {lg_bullet} discontinue wear testing with the selected materials pending redesign of critical system components (1st recommendation) and inclusion of other candidate materials. The final selection of additional candidate materials should be made following design changes, but might include a Stellite alloy or zirconia.« less

Risk-based Methodology for Validation of Pharmaceutical Batch Processes.

PubMed

Wiles, Frederick

2013-01-01

In January 2011, the U.S. Food and Drug Administration published new process validation guidance for pharmaceutical processes. The new guidance debunks the long-held industry notion that three consecutive validation batches or runs are all that are required to demonstrate that a process is operating in a validated state. Instead, the new guidance now emphasizes that the level of monitoring and testing performed during process performance qualification (PPQ) studies must be sufficient to demonstrate statistical confidence both within and between batches. In some cases, three qualification runs may not be enough. Nearly two years after the guidance was first published, little has been written defining a statistical methodology for determining the number of samples and qualification runs required to satisfy Stage 2 requirements of the new guidance. This article proposes using a combination of risk assessment, control charting, and capability statistics to define the monitoring and testing scheme required to show that a pharmaceutical batch process is operating in a validated state. In this methodology, an assessment of process risk is performed through application of a process failure mode, effects, and criticality analysis (PFMECA). The output of PFMECA is used to select appropriate levels of statistical confidence and coverage which, in turn, are used in capability calculations to determine when significant Stage 2 (PPQ) milestones have been met. The achievement of Stage 2 milestones signals the release of batches for commercial distribution and the reduction of monitoring and testing to commercial production levels. Individuals, moving range, and range/sigma charts are used in conjunction with capability statistics to demonstrate that the commercial process is operating in a state of statistical control. The new process validation guidance published by the U.S. Food and Drug Administration in January of 2011 indicates that the number of process validation batches or runs required to demonstrate that a pharmaceutical process is operating in a validated state should be based on sound statistical principles. The old rule of "three consecutive batches and you're done" is no longer sufficient. The guidance, however, does not provide any specific methodology for determining the number of runs required, and little has been published to augment this shortcoming. The paper titled "Risk-based Methodology for Validation of Pharmaceutical Batch Processes" describes a statistically sound methodology for determining when a statistically valid number of validation runs has been acquired based on risk assessment and calculation of process capability.
Quality control and batch testing of MRPC modules for BESIII ETOF upgrade

NASA Astrophysics Data System (ADS)

Liu, Z.; Li, X.; Sun, Y. J.; Li, C.; Heng, Y. K.; Chen, T. X.; Dai, H. L.; Shao, M.; Sun, S. S.; Tang, Z. B.; Yang, R. X.; Wu, Z.; Wang, X. Z.

2017-12-01

The end-cap time-of-flight (ETOF) system for the Beijing Spectrometer III (BESIII) has been upgraded using the Multi-gap Resistive Plate Chamber (MRPC) technology (Williams et al., 1999; Li et al., 2001; Blanco et al., 2003; Fonte et al., 2013, [1-4]). A set of quality-assurance procedures has been developed to guarantee the performances of the 72 mass-produced MRPC modules installed. The cosmic ray batch testing show that the average detection efficiency of the MRPC modules is about 95%. Two different calibration methods indicate that MRPCs' time resolution can reach 60 ps in the cosmic ray test.
Collaborative study for the establishment of the WHO 3(rd) International Standard for Endotoxin, the Ph. Eur. endotoxin biological reference preparation batch 5 and the USP Reference Standard for Endotoxin Lot H0K354.

PubMed

Findlay, L; Desai, T; Heath, A; Poole, S; Crivellone, M; Hauck, W; Ambrose, M; Morris, T; Daas, A; Rautmann, G; Buchheit, K H; Spieser, J M; Terao, E

2015-01-01

An international collaborative study was organised jointly by the World Health Organization (WHO)/National Institute for Biological Standards and Control (NIBSC), the United States Pharmacopeia (USP) and the European Directorate for the Quality of Medicines & HealthCare (EDQM/Council of Europe) for the establishment of harmonised replacement endotoxin standards for these 3 organisations. Thirty-five laboratories worldwide, including Official Medicines Control Laboratories (OMCLs) and manufacturers enrolled in the study. Three candidate preparations (10/178, 10/190 and 10/196) were produced with the same material and same formulation as the current reference standards with the objective of generating a new (3(rd)) International Standard (IS) with the same potency (10 000 IU/vial) as the current (2(nd)) IS, as well as new European Pharmacopoeia (Ph. Eur.). and USP standards. The suitability of the candidate preparations to act as the reference standard in assays for endotoxin performed according to compendial methods was evaluated. Their potency was calibrated against the WHO 2(nd) IS for Endotoxin (94/580). Gelation and photometric methods produced similar results for each of the candidate preparations. The overall potency estimates for the 3 batches were comparable. Given the intrinsic assay precision, the observed differences between the batches may be considered unimportant for the intended use of these materials. Overall, these results were in line with those generated for the establishment of the current preparations of reference standards. Accelerated degradation testing of vials stored at elevated temperatures supported the long-term stability of the 3 candidate preparations. It was agreed between the 3 organisations that batch 10/178 be shared between WHO and EDQM and that batches 10/190 and 10/196 be allocated to USP, with a common assigned value of 10 000 IU/vial. This value maintains the continuity of the global harmonisation of reference materials and unitage for the testing of endotoxins in parenteral pharmaceutical products. Based on the results of the collaborative study, batch 10/178 was established by the European Pharmacopoeia Commission as the Ph. Eur. Endotoxin Biological Reference Preparation (BRP) batch 5. The same batch was also established by the Expert Committee on Biological Standardisation (ECBS) of WHO as the WHO 3(rd) IS for Endotoxin. Batch 10/190 was adopted as the USP Endotoxin Reference Standard, lot H0K354 and vials from this same batch (10/190) will serve as the United States Food and Drug Administration (USFDA) Endotoxin Standard, EC-7.
Comparison between the 6-minute walk tests performed in patients with chronic obstructive pulmonary disease at different altitudes

PubMed Central

Squassoni, Selma Denis; Machado, Nadine Cristina; Lapa, Mônica Silveira; Cordoni, Priscila Kessar; Bortolassi, Luciene Costa; de Oliveira, Juliana Nascimento; Tavares, Cecilia Melo Rosa; Fiss, Elie

2014-01-01

Objective To evaluate the influence of the altitude on the 6-minute walking test in patients with moderate to severe pulmonary disease. Methods Twenty-nine patients performed the 6-minute walk test at a pulmonary rehabilitation clinic in Santo André (above sea level), in São Paulo State, and at the Enseada Beach, in Guarujá (at sea level), also in São Paulo State. Of these 29 patients, 8 did the test both on hard sand and on asphalt to analyze if there were differences in performance during the tests. Data such as heart rate, oxygen saturation, test distance, and Borg scale were compared. Results We found no statistical difference in relation to oxygen saturation at rest before the beginning of the walking test in Santo André 94.67±2.26% and at sea level 95.56±2% (p=0.71). The minimum saturation measured during the test was 87.27±6.54% in Santo André and 89.10±5.41% in Guarujá (p=0.098). There were no differences in the performed distance between the different kinds of terrains; the distance on sand was 387.75±5.02m and on asphalt it was 375.00±6.54m (p=0.654). Regarding oxygen saturation during walking, the pulse oximetry on sand was 95.12±1.80% and on asphalt it was 96.87±1.64% (p=1.05). Conclusion Altitude did not affect the performance of the walking test in patients with moderate to severe pulmonary disease and the results were similar in both cases, on sand and on asphalt. PMID:25628195
Evaluation of Liquefaction Susceptibility of Clean Sands after Blast Densification

NASA Astrophysics Data System (ADS)

Vega Posada, Carlos Alberto

The effect of earthquakes on infrastructure facilities is an important topic of interest in geotechnical research. A key design issue for such facilities is whether or not liquefaction will occur during an earthquake. The consequences of this type of ground failure are usually severe, resulting in severe damage to a facility and in some cases the loss of human life. One approach to minimize the effect of liquefaction is to improve the ground condition by controlled blasting. The main limitations of the blast densification technique are that the design is mostly empirical and verification studies of densification have resulted in contradictory results in some case studies. In such cases, even though the ground surface settles almost immediately after blasting, common verification tests such as the cone penetration test (CPT), standard penetration test (SPT), and shear wave velocity test (Vs) suggest that the soil mass has not been improved at all. This raises concerns regarding the future performance of the soil and casts doubts on whether or not the improved deposit is still susceptible to liquefaction. In this work, a blast densification program was implemented at the Oakridge Landfill located in Dorchester County, SC, to gain information regarding the condition of a loose sand deposit during and after each blast event. In addition, an extensive laboratory testing program was conducted on reconstituted sand specimens to evaluate the mechanical behavior of saturated and gassy, medium dense sands during monotonic and cyclic loading. The results from the field and laboratory program indicate that gas released during blasting can remain trapped in the soil mass for several years, and this gas greatly affects the mechanical behavior of the sand. Gas greatly increases the liquefaction resistance of the soil. If the gas remains in the sand over the life of a project, then it will maintain this increased resistance to liquefaction, whether or not the penetration resistance increases with time. As part of this work, a methodology based on the critical state concepts was described to quantify the amount of densification needed at a certain project to make the soil more resistant to liquefaction and flow.
Ultrasonic isolation of buried pipes

NASA Astrophysics Data System (ADS)

Leinov, Eli; Lowe, Michael J. S.; Cawley, Peter

2016-02-01

Long-range guided wave testing (GWT) is used routinely for the monitoring and detection of corrosion defects in above ground pipelines. The GWT test range in buried, coated pipelines is greatly reduced compared to above ground configurations due to energy leakage into the embedding soil. In this paper, the effect of pipe coatings on the guided wave attenuation is investigated with the aim of increasing test ranges for buried pipelines. The attenuation of the T(0,1) and L(0,2) guided wave modes is measured using a full-scale experimental apparatus in a fusion-bonded epoxy (FBE)-coated 8 in. pipe, buried in loose and compacted sand. Tests are performed over a frequency range typically used in GWT of 10-35 kHz and compared with model predictions. It is shown that the application of a low impedance coating between the FBE layer and the sand effectively decouples the influence of the sand on the ultrasound leakage from the buried pipe. Ultrasonic isolation of a buried pipe is demonstrated by coating the pipe with a Polyethylene (PE)-foam layer that has a smaller impedance than both the pipe and sand, and has the ability to withstand the overburden load from the sand. The measured attenuation in the buried PE-foam-FBE-coated pipe is found to be substantially reduced, in the range of 0.3-1.2 dB m-1 for loose and compacted sand conditions, compared to measured attenuation of 1.7-4.7 dB m-1 in the buried FBE-coated pipe without the PE-foam. The acoustic properties of the PE-foam are measured independently using ultrasonic interferometry and incorporated into model predictions of guided wave propagation in buried coated pipe. Good agreement is found between the experimental measurements and model predictions. The attenuation exhibits periodic peaks in the frequency domain corresponding to the through-thickness resonance frequencies of the coating layer. The large reduction in guided wave attenuation for PE-coated pipes would lead to greatly increased GWT test ranges; such coatings would be attractive for new pipeline installations.
Impacts of oil sands process water on fen plants: implications for plant selection in required reclamation projects.

PubMed

Pouliot, Rémy; Rochefort, Line; Graf, Martha D

2012-08-01

Fen plant growth in peat contaminated with groundwater discharges of oil sands process water (OSPW) was assessed in a greenhouse over two growing seasons. Three treatments (non-diluted OSPW, diluted OSPW and rainwater) were tested on five vascular plants and four mosses. All vascular plants tested can grow in salinity and naphthenic acids levels currently produced by oil sands activity in northwestern Canada. No stress sign was observed after both seasons. Because of plant characteristics, Carex species (C. atherodes and C. utriculata) and Triglochin maritima would be more useful for rapidly restoring vegetation and creating a new peat-accumulating system. Groundwater discharge of OSPW proved detrimental to mosses under dry conditions and ensuring adequate water levels would be crucial in fen creation following oil sands exploitation. Campylium stellatum would be the best choice to grow in contaminated areas and Bryum pseudotriquetrum might be interesting as it has spontaneously regenerated in all treatments. Copyright © 2012 Elsevier Ltd. All rights reserved.
Flight test of MMW radar for brown-out helicopter landing

NASA Astrophysics Data System (ADS)

Martin, Christopher A.; Kolinko, Vladimir; Otto, Gregory P.; Lovberg, John A.

2012-06-01

Trex Enterprises and US Army RDECOM CERDEC Night Vision Electronic Sensors Directorate developed and tested helicopter radar to aid in brown-out landing situations. A brown-out occurs when sand and dust kicked up by the helicopter rotors impair the pilot's vision. Millimeter-wave (MMW) radiation penetrates sand and dust with little loss or scattering, and radar at this frequency can provide a pilot with an image of the intended landing zone. The Brown-out Situational Awareness System (BSAS) is a frequency-modulated, continuous-wave radar that measures range to the ground across a conical field-of-view and uses that range information to create an image for the pilot. The BSAS collected imagery from a helicopter in a blowing sand environment with obstacles including ditches, hills, posts, poles, wires, buildings and vehicles. The BSAS proved the capability to form images of the ground through heavy blowing sand and resolve images of some obstacles. The BSAS also attempted to differentiate flat ground from bumpy ground with limited success at some viewing angles. The BSAS test imagery includes some artifacts formed by high radar cross-section targets in the field-of-view or sidelobes. The paper discusses future improvements that could limit these artifacts.
Evaluating the Emergency Notification Systems of the NASA White Sands Test

NASA Technical Reports Server (NTRS)

Chavez, Alfred Paul

2004-01-01

The problem was that the NASA Fire and Emergency Services did not know if the current emergency notification systems on the NASA White Sands Test Facility were appropriate for alerting the employees of an emergency. The purpose of this Applied Research Project was to determine if the current emergency notification systems of the White Sands Test Facility are appropriate for alerting the employees of an emergency. This was a descriptive research project. The research questions were: 1) What are similar facilities using to alert the employees of an emergency?; 2) Are the current emergency notification systems suitable for the community hazards on the NASA White Sands Test Facility?; 3) What is the NASA Fire and Emergency Services currently using to measure the effectiveness of the emergency notification systems?; and 4) What are the current training methods used to train personnel to the emergency notification systems at the NASA White Sands Test Facility? The procedures involved were to research other established facilities, research published material from credible sources, survey the facility to determine the facility perception of the emergency notification systems, and evaluate the operating elements of the established emergency notification systems for the facility. The results were that the current systems are suitable for the type of hazards the facility may endure. The emergency notification systems are tested frequently to ensure effectiveness in the event of an emergency. Personnel are trained and participate in a yearly drill to make certain personnel are educated on the established systems. The recommendations based on the results were to operationally improve the existing systems by developing and implementing one system that can overall notify the facility of a hazard. Existing procedures and training should also be improved to ensure that all personnel are educated on what to do when the emergency notification systems are activated.
[Evaluation of pipetting systems. III. Micropipette precision in a routine task].

PubMed

Salas, R; Loría, A; Rocha, C

1995-01-01

To establish a norm of the precision achievable with a micropipette in an IRMA assay under routine conditions. A micropipette (Gilson) adjusted to dispense 100 microL was used by a single analyst with experience in its use. In each assay, ten aliquots of radioactive antiprolactin were pipetted in clean tubes (PRE-batch tubes), followed by pipetting of the tubes being processed in the assay, and at the end, a second pipetting of 10 aliquots in clean tubes (POST-batch tubes). The study includes the data of 15 consecutive batches during a seven month period with an overall mean of 283 tubes per batch. The PRE- and POST-tubes were read in a gamma counter (Crystal plus). The mean, SD and CV for PRE, POST and global (PRE+POST) tubes were calculated for each batch. The global CV of the 15 batches ranged from 1.6 to 6.9%, mean of 3.1%. We found no evidence of increased imprecision due to fatigue of the analyst, but surprisingly, we observed that in nine of the 15 batches there was a significant difference in the means of the PRE-tubes vs the POST-tubes (t test) without differences in precision. Thus, part of the global variability is due to what we have called pseudoimprecision (i.e. an increase in CV due to differences in means). In addition, the POST-tubes had higher values in the first 7 batches but the opposite occurred in the last 8 batches (table 2). This shift in the sign of the PRE-POST differences suggests the presence of opposite factors operating in time, i.e. one or more factors increased the volume of pipetting after using the pipette more than 150 times (batches 1-7) whereas other/others decreased it (batches 8-15). 1. Our first approximation to a norm of micropipetting precision in batches of 200-300 tubes was a CV of 3.1%. 2. This norm was influenced by a problem of pseudoimprecision detected ex-post-facto. 3. Our findings justify continuation studies to detect the pseudoimprecision and evaluate its causes prospectively.
Actual distribution of Cronobacter spp. in industrial batches of powdered infant formula and consequences for performance of sampling strategies.

PubMed

Jongenburger, I; Reij, M W; Boer, E P J; Gorris, L G M; Zwietering, M H

2011-11-15

The actual spatial distribution of microorganisms within a batch of food influences the results of sampling for microbiological testing when this distribution is non-homogeneous. In the case of pathogens being non-homogeneously distributed, it markedly influences public health risk. This study investigated the spatial distribution of Cronobacter spp. in powdered infant formula (PIF) on industrial batch-scale for both a recalled batch as well a reference batch. Additionally, local spatial occurrence of clusters of Cronobacter cells was assessed, as well as the performance of typical sampling strategies to determine the presence of the microorganisms. The concentration of Cronobacter spp. was assessed in the course of the filling time of each batch, by taking samples of 333 g using the most probable number (MPN) enrichment technique. The occurrence of clusters of Cronobacter spp. cells was investigated by plate counting. From the recalled batch, 415 MPN samples were drawn. The expected heterogeneous distribution of Cronobacter spp. could be quantified from these samples, which showed no detectable level (detection limit of -2.52 log CFU/g) in 58% of samples, whilst in the remainder concentrations were found to be between -2.52 and 2.75 log CFU/g. The estimated average concentration in the recalled batch was -2.78 log CFU/g and a standard deviation of 1.10 log CFU/g. The estimated average concentration in the reference batch was -4.41 log CFU/g, with 99% of the 93 samples being below the detection limit. In the recalled batch, clusters of cells occurred sporadically in 8 out of 2290 samples of 1g taken. The two largest clusters contained 123 (2.09 log CFU/g) and 560 (2.75 log CFU/g) cells. Various sampling strategies were evaluated for the recalled batch. Taking more and smaller samples and keeping the total sampling weight constant, considerably improved the performance of the sampling plans to detect such a type of contaminated batch. Compared to random sampling, stratified random sampling improved the probability to detect the heterogeneous contamination. Copyright © 2011 Elsevier B.V. All rights reserved.
Parcperdue Geopressure -- Geothermal Project: Appendix E

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sweezy, L.R.

1981-10-05

The mechanical and transport properties and characteristics of rock samples obtained from DOW-DOE L.R. SWEEZY NO. 1 TEST WELL at the Parcperdue Geopressure/Geothermal Site have been investigated in the laboratory. Elastic moduli, compressibility, uniaxial compaction coefficient, strength, creep parameters, permeability, acoustic velocities (all at reservoir conditions) and changes in these quantities induced by simulated reservoir production have been obtained from tests on several sandstone and shale samples from different depths. Most important results are that the compaction coefficients are approximately an order of magnitude lower than those generally accepted for the reservoir sand in the Gulf Coast area and thatmore » the creep behavior is significant. Geologic characterization includes lithological description, SEM micrographs and mercury intrusion tests to obtain pore distributions. Petrographic analysis shows that approximately half of the total sand interval has excellent reservoir potential and that most of the effective porosity in the Cib Jeff Sand is formed by secondary porosity development.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)

Logan, A.; Devenny, D.; Porcari, G.

The activities carried out and the results obtained from a 15 tons/hour oil sands extraction pilot plant operated in Fort McMurray in Northern Alberta are described. The process is the Rio Tinto TIL Holding S.A. (RTR)/Gulf Canada Lt. Oil Sands Extraction Process. It is a modified hot water extraction process. It is used to extract bitumen from Athabasca oil sands. The test ran from July to December 1981 through ambient conditions ranging from plus 38/sup 0/C to minus 30/sup 0/C (100/sup 0/F to -22/sup 0/F). The process, the on-site facilities, the test program, an analysis of plant performance, an appraisalmore » of the process economics, and an evaluation of its potential application are described.« less
Geochemical Monitoring Of The Gas Hydrate Production By CO2/CH4 Exchange In The Ignik Sikumi Gas Hydrate Production Test Well, Alaska North Slope

NASA Astrophysics Data System (ADS)

Lorenson, T. D.; Collett, T. S.; Ignik Sikumi, S.

2012-12-01

Hydrocarbon gases, nitrogen, carbon dioxide and water were collected from production streams at the Ignik Sikumi gas hydrate production test well (TD, 791.6 m), drilled on the Alaska North Slope. The well was drilled to test the feasibility of producing methane by carbon dioxide injection that replaces methane in the solid gas hydrate. The Ignik Sikumi well penetrated a stratigraphically-bounded prospect within the Eileen gas hydrate accumulation. Regionally, the Eileen gas hydrate accumulation overlies the more deeply buried Prudhoe Bay, Milne Point, and Kuparuk River oil fields and is restricted to the up-dip portion of a series of nearshore deltaic sandstone reservoirs in the Sagavanirktok Formation. Hydrate-bearing sandstones penetrated by Ignik Sikumi well occur in three primary horizons; an upper zone, ("E" sand, 579.7 - 597.4 m) containing 17.7 meters of gas hydrate-bearing sands, a middle zone ("D" sand, 628.2 - 648.6 m) with 20.4 m of gas hydrate-bearing sands and a lower zone ("C" sand, 678.8 - 710.8 m), containing 32 m of gas hydrate-bearing sands with neutron porosity log-interpreted average gas hydrate saturations of 58, 76 and 81% respectively. A known volume mixture of 77% nitrogen and 23% carbon dioxide was injected into an isolated section of the upper part of the "C" sand to start the test. Production flow-back part of the test occurred in three stages each followed by a period of shut-in: (1) unassisted flowback; (2) pumping above native methane gas hydrate stability conditions; and (3) pumping below the native methane gas hydrate stability conditions. Methane production occurred immediately after commencing unassisted flowback. Methane concentration increased from 0 to 40% while nitrogen and carbon dioxide concentrations decreased to 48 and 12% respectively. Pumping above the hydrate stability phase boundary produced gas with a methane concentration climbing above 80% while the carbon dioxide and nitrogen concentrations fell to 2 and 18% respectively. Pumping below the gas hydrate stability phase boundary occurred in two periods with the composition of the produced gases continually increasing in methane reaching an excess of 96%, along with carbon dioxide decreasing to <1% and nitrogen to ~3%. The isotopic composition of all the gases was monitored. Methane carbon and hydrogen isotopic compositions remained stable throughout the test, while the carbon dioxide carbon became isotopically heavier. Nitrogen isotopic composition remained stable or became slightly isotopically depleted at the later phase of the test. These results imply that the produced methane was not isotopically fractionated, whereas carbon dioxide was fractionated becoming isotopically heavier at the end of each production phase. In addition, water samples were analyzed during the production phase documenting an increase in salinity.
A Study of the Optimal Model of the Flotation Kinetics of Copper Slag from Copper Mine BOR

NASA Astrophysics Data System (ADS)

Stanojlović, Rodoljub D.; Sokolović, Jovica M.

2014-10-01

In this study the effect of mixtures of copper slag and flotation tailings from copper mine Bor, Serbia on the flotation results of copper recovery and flotation kinetics parameters in a batch flotation cell has been investigated. By simultaneous adding old flotation tailings in the ball mill at the rate of 9%, it is possible to increase copper recovery for about 20%. These results are compared with obtained copper recovery of pure copper slag. The results of batch flotation test were fitted by MatLab software for modeling the first-order flotation kinetics in order to determine kinetics parameters and define an optimal model of the flotation kinetics. Six kinetic models are tested on the batch flotation copper recovery against flotation time. All models showed good correlation, however the modified Kelsall model provided the best fit.
High-Alpha Research Vehicle (HARV) longitudinal controller: Design, analyses, and simulation resultss

NASA Technical Reports Server (NTRS)

Ostroff, Aaron J.; Hoffler, Keith D.; Proffitt, Melissa S.; Brown, Philip W.; Phillips, Michael R.; Rivers, Robert A.; Messina, Michael D.; Carzoo, Susan W.; Bacon, Barton J.; Foster, John F.

1994-01-01

This paper describes the design, analysis, and nonlinear simulation results (batch and piloted) for a longitudinal controller which is scheduled to be flight-tested on the High-Alpha Research Vehicle (HARV). The HARV is an F-18 airplane modified for and equipped with multi-axis thrust vectoring. The paper includes a description of the facilities, a detailed review of the feedback controller design, linear analysis results of the feedback controller, a description of the feed-forward controller design, nonlinear batch simulation results, and piloted simulation results. Batch simulation results include maximum pitch stick agility responses, angle of attack alpha captures, and alpha regulation for full lateral stick rolls at several alpha's. Piloted simulation results include task descriptions for several types of maneuvers, task guidelines, the corresponding Cooper-Harper ratings from three test pilots, and some pilot comments. The ratings show that desirable criteria are achieved for almost all of the piloted simulation tasks.
Transport of strontium and cesium in simulated hanford tank waste leachate through quartz sand under saturated and unsaturated flow.

PubMed

Rod, Kenton A; Um, Wooyong; Flury, Markus

2010-11-01

We investigated the effects of water saturation and secondary precipitate formation on Sr and Cs transport through quartz sand columns under saturated and unsaturated flow. Column experiments were conducted at effective water saturation ranging from 0.2 to 1.0 under steady-state flow using either 0.1 M NaNO(3) or simulated tank waste leachate (STWL; 1 M NaNO(3) and 1 M NaOH) mimicking Hanford (Washington, USA) tank waste. In 0.1 M NaNO(3) columns, Sr transported like a conservative tracer, whereas Cs was retarded relative to Sr. The transport of Sr and Cs in the 0.1 M NaNO(3) columns under all water saturations could be described with the equilibrium convection-dispersion equation (CDE). In STWL columns, Sr mobility was significantly reduced compared to the 0.1 M NaNO(3) column, because Sr was incorporated into or sorbed to neo-formed secondary precipitates. Strontium sequestration by precipitates was confirmed by additional batch and electron micrograph analyses. In contrast(,) the transport of Cs was less affected by the STWL; retardation of Cs in STWL columns was similar to that found in 0.1 M NaNO(3) columns. Analysis of STWL column data revealed that both Sr and Cs breakthrough curves showed nonideal behavior that suggest nonequilibrium conditions, although nonlinear geochemical behavior cannot be ruled out.
40 CFR 63.2460 - What requirements must I meet for batch process vents?

Code of Federal Regulations, 2010 CFR

2010-07-01

.... (ii) When you conduct a performance test or design evaluation for a non-flare control device used to... paragraphs (c)(9)(ii)(A) through (D) of this section. The design evaluation option for small control devices...) of this section. (b) Group status. If a process has batch process vents, as defined in § 63.2550, you...
40 CFR 63.2460 - What requirements must I meet for batch process vents?

Code of Federal Regulations, 2011 CFR

2011-07-01

.... (ii) When you conduct a performance test or design evaluation for a non-flare control device used to... paragraphs (c)(9)(ii)(A) through (D) of this section. The design evaluation option for small control devices...) of this section. (b) Group status. If a process has batch process vents, as defined in § 63.2550, you...
40 CFR 63.2460 - What requirements must I meet for batch process vents?

Code of Federal Regulations, 2014 CFR

2014-07-01

.... (ii) When you conduct a performance test or design evaluation for a non-flare control device used to... paragraphs (c)(9)(ii)(A) through (D) of this section. The design evaluation option for small control devices... (c) of this section. (b) Group status. If a process has batch process vents, as defined in § 63.2550...

40 CFR 63.2460 - What requirements must I meet for batch process vents?

Code of Federal Regulations, 2012 CFR

2012-07-01

.... (ii) When you conduct a performance test or design evaluation for a non-flare control device used to... paragraphs (c)(9)(ii)(A) through (D) of this section. The design evaluation option for small control devices... (c) of this section. (b) Group status. If a process has batch process vents, as defined in § 63.2550...
40 CFR 63.2460 - What requirements must I meet for batch process vents?

Code of Federal Regulations, 2013 CFR

2013-07-01

.... (ii) When you conduct a performance test or design evaluation for a non-flare control device used to... paragraphs (c)(9)(ii)(A) through (D) of this section. The design evaluation option for small control devices... (c) of this section. (b) Group status. If a process has batch process vents, as defined in § 63.2550...
Using MATLAB Software on the Peregrine System | High-Performance Computing

Science.gov Websites

Learn how to run MATLAB software in batch mode on the Peregrine system. Below is an example MATLAB job in batch (non-interactive) mode. To try the example out, create both matlabTest.sub and /$USER. In this example, it is also the directory into which MATLAB will write the output file x.dat
40 CFR 63.490 - Batch front-end process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2010 CFR

2010-07-01

... may be based on either total organic HAP or TOC. For purposes of this paragraph (c), the term “batch... inlet sampling sites shall ensure the measurement of total organic HAP or TOC (minus methane and ethane... used to determine the concentration of organic HAP or TOC, as appropriate. Alternatively, any other...
Effect of Dissolved NaC1 on Freezing Curves of Kaolinite, Montmorillonite, and Sand Pastes,

DTIC Science & Technology

1999-01-01

test this procedure. Pastes of kaolinite clay, montmorillonite , and quartz sand were prepared by washing repeatedly with aque- ous solutions of 0.1...Cold Regions Research & Engineering Laboratory Effect of Dissolved NaCI on Freezing Curves of Kaolinite , Montmorillonite , and Sand Pastes S.A...of kaolinite pastes warmed from -66.6°C to 0°C 8 4. Unfrozen-water contents, as measured by pulsed NMR, of montmorillonite pastes cooled from 0
Efficacy of Commercial Mosquito Traps in Capturing Phlebotomine Sand Flies (Diptera: Psychodidae) in Egypt

DTIC Science & Technology

2010-01-01

forDiseaseControl andPrevention (CDC) light trap for efÞcacy in collecting phlebotomine sand ßies (Diptera: Psychodidae) in a small farming village in the...Prevention (CDC) light trap for ef?acy in collecting phlebotomine sand ?es (Diptera: Psychodidae) in a small farming village in the Nile River Valley 10 km...Testing was conducted in June, August, and September 2007, in Bahrif village, a farming com- munity of 500 people 10 km north of Aswan on the east
Qualitative and Quantitative Assessment of Four Marketed Formulations of Brahmi

PubMed Central

Saini, Neeti; Mathur, Rajani; Agrawal, S. S.

2012-01-01

This study was conducted with the aim to compare two batches each of four popular commercial formulations of Bacopa monnieri (Brahmi), and report, if any, inter-batch variations. The formulations were procured from local market and analyzed for label specifications, uniformity of weight of capsule, identity, purity and strength parameters (total ash content test, acid insoluble ash content, water soluble extractive, alcohol soluble extractive, loss on drying). Bacoside A, one of the pharmacologically active saponin present in B. monnieri, was quantified in all the formulations using UV-spectrophotometer. In addition each formulation was assessed and compared for variation in biological activity using in vitro test for hemolytic activity using human erythrocytes. The results of the study show that there is a wide variation in the quality and content of herbal drugs marketed by different manufacturers. More importantly this study demonstrates that there exists a bigger challenge of batch-to-batch variation in the quality and content of herbal formulations of the same manufacturer. This challenge of providing standardized formulations is being faced by not any one manufacturing house but by all, and may be attributed firstly to, lack of stringent regulations and secondly to high variability in raw material quality. PMID:23204618
Qualitative and quantitative assessment of four marketed formulations of brahmi.

PubMed

Saini, Neeti; Mathur, Rajani; Agrawal, S S

2012-01-01

This study was conducted with the aim to compare two batches each of four popular commercial formulations of Bacopa monnieri (Brahmi), and report, if any, inter-batch variations. The formulations were procured from local market and analyzed for label specifications, uniformity of weight of capsule, identity, purity and strength parameters (total ash content test, acid insoluble ash content, water soluble extractive, alcohol soluble extractive, loss on drying). Bacoside A, one of the pharmacologically active saponin present in B. monnieri, was quantified in all the formulations using UV-spectrophotometer. In addition each formulation was assessed and compared for variation in biological activity using in vitro test for hemolytic activity using human erythrocytes. The results of the study show that there is a wide variation in the quality and content of herbal drugs marketed by different manufacturers. More importantly this study demonstrates that there exists a bigger challenge of batch-to-batch variation in the quality and content of herbal formulations of the same manufacturer. This challenge of providing standardized formulations is being faced by not any one manufacturing house but by all, and may be attributed firstly to, lack of stringent regulations and secondly to high variability in raw material quality.
T-F and S/DOE Gladys McCall No. 1 well, Cameron Parish, Louisiana. Geopressured-geothermal well report, Volume II. Well workover and production testing, February 1982-October 1985. Final report. Appendices 1-7

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-01-01

These appendices contain the following reports: (1) investigation of coupling failure from the Gladys McCall No. 1 well; (2) failure analysis - oil well casing coupling; (3) technical remedial requirements for 5-inch production tubing string; (4) reservoir limit test data for sand zone No. 9; (5) reservoir fluid study - sand zone No. 9; (6) engineering interpretation of exploration drawdown tests; and (7) reservoir analysis. (ACR)
Test wells T27 and T28, White Sands Missile Range, Dona Ana County, New Mexico

USGS Publications Warehouse

Myers, R.G.; Pinckley, K.M.

1985-01-01

Two test wells, T27 and T28, were drilled at White Sands Missile Range in south-central New Mexico as part of a joint military training program sponsored by the U.S. Army in February and March 1983. Test wells T27 and T28 were drilled as observation wells in the vicinity of the Liquid Propellant Storage Area. Information obtained from these wells includes lithologic logs, driller 's logs, and borehole-geophysical logs from the cased wells. (USGS)
Results of Hg speciation testing on DWPF SMECT-4, SMECT-6, and RCT-2 samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bannochie, C. J.

2016-02-04

The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team.i,ii The fifteenth shipment of samples was designated to include Defense Waste Processing Facility (DWPF) Slurry Mix Evaporator Condensate Tank (SMECT) samples from Sludge Receipt and Adjustment Tank (SRAT) Batch 738 and a Recycle Condensate Tank (RCT) sample from SRAT Batch 736. The DWPF sample designations for the three samples analyzed are provided in Table 1. The Batch 738 ‘Baseline’ SMECT sample was taken priormore » to Precipitate Reactor Feed Tank (PRFT) addition and concentration and therefore, precedes the SMECT-5 sample reported previously. iii The Batch 738 ‘End of SRAT Cycle’ SMECT sample was taken at the conclusion of SRAT operations for this batch (PRFT addition/concentration, acid additions, initial concentration, MCU addition, and steam stripping). Batch 738 experienced a sludge slurry carryover event, which introduced sludge solids to the SMECT that were particularly evident in the SMECT-5 sample, but less evident in the ‘End of SRAT Cycle’ SMECT-6 sample. The Batch 736 ‘After SME’ RCT sample was taken after completion of SMECT transfers at the end of the SME cycle.« less
Estimating the change of porosity in the saturated zone during air sparging.

PubMed

Tsai, Yih-jin; Kuo, Yu-chia; Chen, Tsu-chi; Chou, Feng-chih

2006-01-01

Air sparging is a remedial method for groundwater. The remedial region is similar to the air flow region in the saturated zone. If soil particles are transported during air sparging, the porosity distributions in the saturated zone change, which may alter the flow path of the air. To understand better the particle movement, this study performed a sandbox test to estimate the soil porosity change during air sparging. A clear fracture was formed and the phenomenon of particle movement was observed when the air injection was started. The moved sand filled the porous around the fracture and the reparked sand filled the fracture, reducing the porosity around the fracture. The results obtained from the photographs of the sandbox, the current measurements and the direct sand sample measurements were close to each other and are credible. Therefore, air injection during air sparging causes sand particle movement of sand, altering the characteristic of the sand matrix and the air distribution.
Laboratory colonization and mass rearing of phlebotomine sand flies (Diptera, Psychodidae)

PubMed Central

Lawyer, Phillip; Killick-Kendrick, Mireille; Rowland, Tobin; Rowton, Edgar; Volf, Petr

2017-01-01

Laboratory colonies of phlebotomine sand flies are necessary for experimental study of their biology, behaviour and mutual relations with disease agents and for testing new methods of vector control. They are indispensable in genetic studies and controlled observations on the physiology and behaviour of sand flies, neglected subjects of high priority. Colonies are of particular value for screening insecticides. Colonized sand flies are used as live vector models in a diverse array of research projects, including xenodiagnosis, that are directed toward control of leishmaniasis and other sand fly-associated diseases. Historically, labour-intensive maintenance and low productivity have limited their usefulness for research, especially for species that do not adapt well to laboratory conditions. However, with growing interest in leishmaniasis research, rearing techniques have been developed and refined, and sand fly colonies have become more common, enabling many significant breakthroughs. Today, there are at least 90 colonies representing 21 distinct phlebotomine sand fly species in 35 laboratories in 18 countries worldwide. The materials and methods used by various sand fly workers differ, dictated by the availability of resources, cost or manpower constraints rather than choice. This paper is not intended as a comprehensive review but rather a discussion of methods and techniques most commonly used by researchers to initiate, establish and maintain sand fly colonies, with emphasis on the methods proven to be most effective for the species the authors have colonized. Topics discussed include collecting sand flies for colony stock, colony initiation, maintenance and mass-rearing procedures, and control of sand fly pathogens in colonies. PMID:29139377
Generation rate and particle size distribution of wood dust by handheld sanding operation

PubMed Central

Ojima, Jun

2016-01-01

Objectives: The International Agency for Research on Cancer (IARC) and Japan Society for Occupational Health (JSOH) classified wood dust as a human carcinogen. Former studies have suggested that sanding with a portable sander is one of the processes that are liable to cause highest exposure to wood dust. However, the wood dust by sanding operation has not been investigated sufficiently. In this study, the generation rate and the particle size distribution of the wood dust produced by handheld sanding operation were observed by laboratory experiments. Methods: Beech and cypress were taken as typical hard and soft wood specimen respectively, and sanded with a portable sander. Three grades of sand paper (coarse, medium, fine) were attached to the sander in turn to be tested. The quantity of the wood dust produced by the sander was measured by weighing the specimen before and after the sanding and then the generation rate of the dust was calculated. Results: Soft wood generated more dust than hard wood due to the difference in abrasion durability. A coarse sand paper produced more dust than a fine sand paper. The particles of less than 1 μm diameter were scarcely observed in the wood dust. When the specimens were sanded with a fine sand paper, the mass median aerodynamic diameters of beech dust and cypress dust were 9.0 μm and 9.8 μm, respectively. Conclusions: Respirable wood dust is able to be controlled by general ventilation with more than 0.7-4.2 m3/min ventilation rate. PMID:27725491
Voluntary exercise enhances activity rhythms and ameliorates anxiety- and depression-like behaviors in the sand rat model of circadian rhythm-related mood changes.

PubMed

Tal-Krivisky, Katy; Kronfeld-Schor, Noga; Einat, Haim

2015-11-01

Physical exercise is a non-pharmacological treatment for affective disorders. The mechanisms of its effects are unknown although some suggest a relationship to synchronization of circadian rhythms. One way to explore mechanisms is to utilize animal models. We previously demonstrated that the diurnal fat sand rat is an advantageous model for studying the interactions between photoperiods and mood. The current study was designed to evaluate the effects of voluntary exercise on activity rhythms and anxiety and depression-like behaviors in sand rats as a step towards better understanding of the underlying mechanisms. Male sand rats were housed in short photoperiod (SP; 5h light/19 h dark) or neutral light (NP; 12h light/12h dark) regimens for 3 weeks and divided into subgroups with or without running wheels. Activity was monitored for 3 additional weeks and then animals were tested in the elevated plus-maze, the forced swim test and the social interaction test. Activity rhythms were enhanced by the running wheels. As hypothesized, voluntary exercise had significant effects on SP animals' anxiety- and depression-like behaviors but not on NP animals. Results are discussed in the context of interactions between physical exercise, circadian rhythms and mood. We suggest that the sand rat model can be used to explore the underlying mechanism of the effects of physical exercise for mood disorders. Copyright © 2015 Elsevier Inc. All rights reserved.
Experimental Study on Stress Monitoring of Sand-Filled Steel Tube during Impact Using Piezoceramic Smart Aggregates.

PubMed

Du, Guofeng; Zhang, Juan; Zhang, Jicheng; Song, Gangbing

2017-08-22

The filling of thin-walled steel tubes with quartz sand can help to prevent the premature buckling of the steel tube at a low cost. During an impact, the internal stress of the quartz sand-filled steel tube column is subjected to not only axial force but also lateral confining force, resulting in complicated internal stress. A suitable sensor for monitoring the internal stress of such a structure under an impact is important for structural health monitoring. In this paper, piezoceramic Smart Aggregates (SAs) are embedded into a quartz Sand-Filled Steel Tube Column (SFSTC) to monitor the internal structural stress during impacts. The piezoceramic smart aggregates are first calibrated by an impact hammer. Tests are conducted to study the feasibility of monitoring the internal stress of a structure. The results reflect that the calibration value of the piezoceramic smart aggregate sensitivity test is in good agreement with the theoretical value, and the output voltage value of the piezoceramic smart aggregate has a good linear relationship with external forces. Impact tests are conducted on the sand-filled steel tube with embedded piezoceramic smart aggregates. By analyzing the output signal of the piezoceramic smart aggregates, the internal stress state of the structure can be obtained. Experimental results demonstrated that, under the action of impact loads, the piezoceramic smart aggregates monitor the compressive stress at different locations in the steel tube, which verifies the feasibility of using piezoceramic smart aggregate to monitor the internal stress of a structure.
The use of cone penetration testing to investigate sand fill subsidence at cross-drain locations: final report : Volume I.

DOT National Transportation Integrated Search

1984-03-01

During construction of Interstate I-10 between Baton Rouge and LaPlace, Louisiana, highly organic swamp deposits were excavated and replaced with hydraulically pumped river sand. Recently, excessive settlement was encountered at numerous cross-drain ...
22. V2 GANTRY, LAUNCH COMPLEX 33: GENERAL VIEW, LOOKING WEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. V-2 GANTRY, LAUNCH COMPLEX 33: GENERAL VIEW, LOOKING WEST AND UPWARD FROM APRON OF BLAST PIT, 20,000 POUND MOTOR TEST AND LAUNCH FACILITY - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
21. V2 GANTRY, LAUNCH COMPLEX 33: VIEW OF CRANE WITH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

21. V-2 GANTRY, LAUNCH COMPLEX 33: VIEW OF CRANE WITH BLAST PIT OF 20,000 POUND MOTOR TEST AND LAUNCH FACILITY, IN FOREGROUND, LOOKING WEST - White Sands Missile Range, V-2 Rocket Facilities, Near Headquarters Area, White Sands, Dona Ana County, NM
Numerical simulations of sand production in interbedded hydrate-bearing sediments during depressurization

USGS Publications Warehouse

Uchida, Shun; Lin, Jeen-Shang; Myshakin, Evgeniy; Seol, Yongkoo; Collett, Timothy S.; Boswell, Ray

2017-01-01

Geomechanical behavior of hydrate-bearing sediments during gas production is complex, involving changes in hydrate-dependent mechanical properties. When interbedded clay layers are present, the complexity is more pronounced because hydrate dissociation tends to occur preferentially in the sediments adjacent to the clay layers due to clay layers acting as a heat source. This would potentially lead to shearing deformation along the sand/clay contacts and may contribute to solid migration, which hindered past field-scale gas production tests. This paper presents a near-wellbore simulation of sand/clay interbedded hydrate-bearing sediments that have been subjected to depressurization and discusses the effect of clay layers on sand production.

[Study on the influence of bioclogging on permeability of saturated porous media by experiments and models].

PubMed

Yang, Jing; Ye, Shu-jun; Wu, Ji-chun

2011-05-01

This paper studied on the influence of bioclogging on permeability of saturated porous media. Laboratory hydraulic tests were conducted in a two-dimensional C190 sand-filled cell (55 cm wide x 45 cm high x 1.28 cm thick) to investigate growth of the mixed microorganisms (KB-1) and influence of biofilm on permeability of saturated porous media under condition of rich nutrition. Biomass distributions in the water and on the sand in the cell were measured by protein analysis. The biofilm distribution on the sand was observed by confocal laser scanning microscopy. Permeability was measured by hydraulic tests. The biomass levels measured in water and on the sand increased with time, and were highest at the bottom of the cell. The biofilm on the sand at the bottom of the cell was thicker. The results of the hydraulic tests demonstrated that the permeability due to biofilm growth was estimated to be average 12% of the initial value. To investigate the spatial distribution of permeability in the two dimensional cell, three models (Taylor, Seki, and Clement) were used to calculate permeability of porous media with biofilm growth. The results of Taylor's model showed reduction in permeability of 2-5 orders magnitude. The Clement's model predicted 3%-98% of the initial value. Seki's model could not be applied in this study. Conclusively, biofilm growth could obviously decrease the permeability of two dimensional saturated porous media, however, the reduction was much less than that estimated in one dimensional condition. Additionally, under condition of two dimensional saturated porous media with rich nutrition, Seki's model could not be applied, Taylor's model predicted bigger reductions, and the results of Clement's model were closest to the result of hydraulic test.
Simulating Sand Behavior through Terrain Subdivision and Particle Refinement

NASA Astrophysics Data System (ADS)

Clothier, M.

2013-12-01

Advances in computer graphics, GPUs, and parallel processing hardware have provided researchers with new methods to visualize scientific data. In fact, these advances have spurred new research opportunities between computer graphics and other disciplines, such as Earth sciences. Through collaboration, Earth and planetary scientists have benefited by using these advances in hardware technology to process large amounts of data for visualization and analysis. At Oregon State University, we are collaborating with the Oregon Space Grant and IGERT Ecosystem Informatics programs to investigate techniques for simulating the behavior of sand. In addition, we have also been collaborating with the Jet Propulsion Laboratory's DARTS Lab to exchange ideas on our research. The DARTS Lab specializes in the simulation of planetary vehicles, such as the Mars rovers. One aspect of their work is testing these vehicles in a virtual "sand box" to test their performance in different environments. Our research builds upon this idea to create a sand simulation framework to allow for more complex and diverse environments. As a basis for our framework, we have focused on planetary environments, such as the harsh, sandy regions on Mars. To evaluate our framework, we have used simulated planetary vehicles, such as a rover, to gain insight into the performance and interaction between the surface sand and the vehicle. Unfortunately, simulating the vast number of individual sand particles and their interaction with each other has been a computationally complex problem in the past. However, through the use of high-performance computing, we have developed a technique to subdivide physically active terrain regions across a large landscape. To achieve this, we only subdivide terrain regions where sand particles are actively participating with another object or force, such as a rover wheel. This is similar to a Level of Detail (LOD) technique, except that the density of subdivisions are determined by their proximity to the interacting object or force with the sand. To illustrate an example, as a rover wheel moves forward and approaches a particular sand region, that region will continue to subdivide until individual sand particles are represented. Conversely, if the rover wheel moves away, previously subdivided sand regions will recombine. Thus, individual sand particles are available when an interacting force is present but stored away if there is not. As such, this technique allows for many particles to be represented without the computational complexity. We have also further generalized these subdivision regions in our sand framework into any volumetric area suitable for use in the simulation. This allows for more compact subdivision regions and has fine-tuned our framework so that more emphasis can be placed on regions of actively participating sand. We feel that this increases the framework's usefulness across scientific applications and can provide for other research opportunities within the earth and planetary sciences. Through continued collaboration with our academic partners, we continue to build upon our sand simulation framework and look for other opportunities to utilize this research.
Collaborative study for the establishment of replacement batches of heparin low- molecular-mass for assay biological reference preparations.

PubMed

Terao, E; Daas, A; Rautmann, G; Buchheit, K-H

2010-10-01

A collaborative study was run by the European Directorate for the Quality of Medicines & HealthCare (EDQM) in the context of the Biological Standardisation Programme (BSP), under the aegis of the Council of Europe and the European Commission, to establish replacement batches for the dwindling stocks of the Heparin low-molecular-mass for assay European Pharmacopoeia Biological Reference Preparation (BRP). The replacement batches of BRP are intended to be used in the assays for anti-Xa and anti-IIa activities, as described in the European Pharmacopoeia (Ph. Eur.) monograph Heparins, low-molecular-mass (0828). Three freeze-dried candidate batches were calibrated against the current International Standard (IS) for Heparin, lowmolecular- weight (2nd IS, 01/608). For the purpose of the continuity check between subsequent BRP batches, the current Heparin low-molecular-mass for assay BRP (batch 5) was also included in the test panel. Thirteen official medicines control and manufacturers laboratories from European and non-European countries contributed data. A central statistical analysis of the datasets was performed at the EDQM. On the basis of the results, the 3 candidate materials were assigned a potency of 104 IU/vial for the anti-Xa activity and 31 IU/vial for the anti-IIa activity. Taken into account the preliminary stability data and the results of this collaborative study, the 3 batches of candidate BRP were adopted in June 2010 by the Commission of the Ph. Eur. as Heparin low-molecular-mass for assay BRP batches 6, 7 and 8.
Identifying and mitigating batch effects in whole genome sequencing data.

PubMed

Tom, Jennifer A; Reeder, Jens; Forrest, William F; Graham, Robert R; Hunkapiller, Julie; Behrens, Timothy W; Bhangale, Tushar R

2017-07-24

Large sample sets of whole genome sequencing with deep coverage are being generated, however assembling datasets from different sources inevitably introduces batch effects. These batch effects are not well understood and can be due to changes in the sequencing protocol or bioinformatics tools used to process the data. No systematic algorithms or heuristics exist to detect and filter batch effects or remove associations impacted by batch effects in whole genome sequencing data. We describe key quality metrics, provide a freely available software package to compute them, and demonstrate that identification of batch effects is aided by principal components analysis of these metrics. To mitigate batch effects, we developed new site-specific filters that identified and removed variants that falsely associated with the phenotype due to batch effect. These include filtering based on: a haplotype based genotype correction, a differential genotype quality test, and removing sites with missing genotype rate greater than 30% after setting genotypes with quality scores less than 20 to missing. This method removed 96.1% of unconfirmed genome-wide significant SNP associations and 97.6% of unconfirmed genome-wide significant indel associations. We performed analyses to demonstrate that: 1) These filters impacted variants known to be disease associated as 2 out of 16 confirmed associations in an AMD candidate SNP analysis were filtered, representing a reduction in power of 12.5%, 2) In the absence of batch effects, these filters removed only a small proportion of variants across the genome (type I error rate of 3%), and 3) in an independent dataset, the method removed 90.2% of unconfirmed genome-wide SNP associations and 89.8% of unconfirmed genome-wide indel associations. Researchers currently do not have effective tools to identify and mitigate batch effects in whole genome sequencing data. We developed and validated methods and filters to address this deficiency.
Lateral fluid flow in a compacting sand-shale sequence: South Caspian basin.

USGS Publications Warehouse

Bredehoeft, J.D.; Djevanshir, R.D.; Belitz, K.R.

1988-01-01

The South Caspian basin contains both sands and shales that have pore-fluid pressures substantially in excess of hydrostatic fluid pressure. Pore-pressure data from the South Caspian basin demonstrate that large differences in excess hydraulic head exist between sand and shale. The data indicate that sands are acting as drains for overlying and underlying compacting shales and that fluid flows laterally through the sand on a regional scale from the basin interior northward to points of discharge. The major driving force for the fluid movement is shale compaction. We present a first- order mathematical analysis in an effort to test if the permeability of the sands required to support a regional flow system is reasonable. The results of the analysis suggest regional sand permeabilities ranging from 1 to 30 md; a range that seems reasonable. This result supports the thesis that lateral fluid flow is occurring on a regional scale within the South Caspian basin. If vertical conduits for flow exist within the basin, they are sufficiently impermeable and do not provide a major outlet for the regional flow system. The lateral fluid flow within the sands implies that the stratigraphic sequence is divided into horizontal units that are hydraulically isolated from one another, a conclusion that has important implications for oil and gas migration.-Authors
Geosynthetic Reinforcement of Sand-Mat Layer above Soft Ground

PubMed Central

Park, Jong-Beom; Park, Hyun-Soo; Kim, Daehyeon

2013-01-01

In order to improve the bearing capacity of soft ground for the purpose of getting trafficability of construction vehicles, the reinforcement of geosynthetics for sand-mat layers on soft ground has often been used. As the strength of the geosynthetics increases, and the sand-mat system becomes stronger, the bearing capacity of sand-mat systems will be increased. The depths of geosynthetics, reinforced in sand-mat layers, were varied with respect to the width of footing. The tensile strengths of geosynthetics were also varied to evaluate the effect of reinforcement on the bearing capacity of soft ground. The dispersion angles, with varying sand-mat thicknesses, were also determined in consideration of the tensile strength of geosynthetics and the depths of reinforcement installations. The bearing capacity ratios, with the variation of footing width and reinforced embedment depth, were determined for the geosynthetics-only, reinforced soft ground, 1-layer sand-mat system and 2-layer sand-mat system against the non-reinforced soft ground. From the test results of various models, a principle that better explains the concept of geosynthetic reinforcement has been found. On the basis of this principle, a new bearing capacity equation for practical use in the design of geosynthetically reinforced soft ground has been proposed by modifying Yamanouchi’s equation. PMID:28788392
Groundwater Remediation and Alternate Energy at White Sands Test Facility

NASA Technical Reports Server (NTRS)

Fischer, Holger

2008-01-01

White Sands Test Facility Core Capabilities: a) Remote Hazardous Testing of Reactive, Explosive, and Toxic Materials and Fluids; b) Hypergolic Fluids Materials and Systems Testing; c) Oxygen Materials and System Testing; d) Hypervelocity Impact Testing; e)Flight Hardware Processing; and e) Propulsion Testing. There is no impact to any drinking water well. Includes public wells and the NASA supply well. There is no public exposure. Groundwater is several hundred feet below ground. No air or surface water exposure. Plume is moving very slowly to the west. Plume Front Treatment system will stop this westward movement. NASA performs on-going monitoring. More than 200 wells and zones are routinely sampled. Approx. 850 samples are obtained monthly and analyzed for over 300 different hazardous chemicals.
The influence of different geotechnically relevant amendments on the reductive degradation of TCE by nZVI

NASA Astrophysics Data System (ADS)

Freitag, Peter; Schöftner, Philipp; Waldner, Georg; Reichenauer, Thomas G.; Nickel, Claudia; Spitz, Marcus; Dietzel, Martin

2014-05-01

Trichloroethylene (TCE) was widely used as a cleaning and degreasing agent. Companies needing these agents were often situated in or close to built up areas, so spillage led to contaminated sites which now can only be remediated using in situ techniques. The situation is compounded by the fact that TCE tends to seep through ground water bodies forming pools at the bottom of the aquifer. When reacting with TCE, nanoscale zero valent iron (nZVI) is known to reduce it into non-toxic substances. The difficulty is to bring it in contact with the pollutant. Attempts using passive insertion into the groundwater via wells yielded mixed results. Reasons for this are that ZVI tends to coagulate, to sediment and to adsorb on the matrix of the aquifer. Also, in inhomogeneous aquifers a passive application of nZVI can be difficult and might not bring the desired results, due to existence of preferential flow paths. A possible solution to this problem is the physical in situ mixing of ZVI into the contaminant source. This can, in principle, be done by adapting jet grouting - a method that uses a high pressure slurry jet, consisting of water and geotechnical additives ("binders"), to mix and compact zones ("columns") in soil. These columns are commonly used to solve foundation problems but can also be used to solve the problem of delivering nZVI to TCE source zones. This paper examines the influence binders have on the degradation reaction between TCE and nZVI. The necessity of these binders is explained by the fact that the subsoil structure is rearranged during the jetting process leading to subsidence on the surface. These subsidences could result in damage to neighbouring structures. A series of batch experiments was conducted in this study. Contaminated groundwater was brought into contact with samples of slurries commonly used in geotechnical applications. We tested the effects of concresole, bentonite, zeolithe, fly ash, slag sand and cement on the kinetics of TCE degradation by nZVI. The degradation of TCE was measured using GC Headspace samples. Furthermore, additional experiments were conducted to investigate the interaction between binders and TCE as well as binders and nZVI. The results of these experiments led to the conclusion that jet grouting could be well suited for the delivery of nZVI to TCE contaminated source zones. Currently, soil column experiments and large-scale experiments in test facilities are performed to confirm the batch testing results.
Biological CO2 conversion to acetate in subsurface coal-sand formation using a high-pressure reactor system

NASA Astrophysics Data System (ADS)

Ohtomo, Y.; Ijiri, A.; Ikegawa, Y.; Tsutsumi, M.; Imachi, H.; Uramoto, G.; Hoshino, T.; Morono, Y.; Tanikawa, W.; Hirose, T.; Inagaki, F.

2013-12-01

The geological CO2 sequestration into subsurface unmineable oil/gas fields and coal formations has been considered as one of the possible ways to reduce dispersal of anthropogenic greenhouse gasses into the atmosphere. However, feasibility of CO2 injection largely depends on a variety of geological and economical settings, and its ecological consequences have remained largely unpredictable. To address these issues, we developed a new flow-through-type CO2 injection system designated as the 'geobio-reactor system' to examine possible geophysical, geochemical and microbiological impact caused by CO2 injection under in-situ pressure (0-100 MPa) and temperature (0-70°C) conditions. In this study, we investigated Eocene bituminous coal-sandstones in the northwestern Pacific coast, Hokkaido, Japan, using the geobio-reactor system. Anaerobic artificial fluid and CO2 (flow rate: 0.002 and 0.00001 mL/min, respectively) were continuously supplemented into the coal-sand column under the pore pressure of 40 MPa (confined pressure: 41 MPa) at 40°C for 56 days. Molecular analysis of bacterial 16S rRNA genes showed that predominant bacterial components were physically dispersed from coal to sand as the intact form during experiment. Cultivation experiments from sub-sampling fluids indicated that some terrestrial microbes could preserve their survival in subsurface condition. Molecular analysis of archaeal 16S rRNA genes also showed that no methanogens were activated during experiment. We also anaerobically incubated the coal sample using conventional batch-type cultivation technique with a medium for methanogens. After one year of the batch incubation at 20°C, methane could be detected from the cultures except for the acetate-fed culture. The sequence of archaeal 16S rRNA genes via PCR amplification obtained from the H2 plus formate-fed culture was affiliated with a hydrogenotrophic methanogen within the genus Methanobacterium, whereas the methanol plus trimethylamine culture belonged to a methylotrophic methanogen within the genus Methanosarcina. For the acetate-fed culture, no cell proliferation and methane-production were observed after two-years incubation. During the injection of CO2 and fluid, increase of dissolved CH4 concentration was observed, of which δ13CCH4 were constantly similar to those of the absorbed coal-bed methane (δ13CCBM, ~70‰), suggesting the enhanced gas recovery with fluid flow. The output volume of CO2 (ΣCO2out, 22.1 to 125.6 mM) was smaller than initial concentration (ΣCO2in, 138.38 mM), which can be explained by either adsorption on coal, formation of carbonate minerals, or microbial consumption. Increase of acetate concentration in the fluids was also observed, whereas δ13Cacetate depleted during experiment. Considering with the decrease of additive H2, it is most likely that homo-acetogenesis would occur during experiments, which is consistent with detection of Sporomusa-related 16S rRNA genes, homo-acetogenic bacterium, in cloning analysis of sandstone after experiment. Decrease of formate concentrations and increase of δ13Cformate indicate bacterial consumption of formate and isotopic fractionation. Our results suggest that CO2 injection to natural coal-sand formation stimulates homo-acetogenesis rather than methanogenesis, accompanied by biogenic CO2 conversion to acetate.
Co-digestion of food waste in a municipal wastewater treatment plant: Comparison of batch tests and full-scale experiences.

PubMed

Koch, Konrad; Plabst, Markus; Schmidt, Andreas; Helmreich, Brigitte; Drewes, Jörg E

2016-01-01

The effects of co-digestion of food waste in a municipal wastewater treatment plant (WWTP) were studied in batch tests. The results obtained were compared with the mass balance of a digester at a full-scale WWTP for a one-year period without and with the addition of co-substrate. The specific methane yield calculated from the balance was 18% higher than the one in the batch tests, suggesting a stimulation of methane generation by co-digestion. It was hypothesized that this increase was caused by shifting the C/N ratio of raw sludge (8.8) to a more favourable ratio of the added food waste (17.7). In addition, potential benefits by adding food waste for energy autarky was investigated. While just 25% of the total energy demand of the plant could be recovered by biogas generation when no co-substrate was fed, this percentage has more than doubled when food waste was added at a ratio of 10% (w/w). Copyright © 2015 Elsevier Ltd. All rights reserved.
Results of a test well in the Nanafalia Formation near Melvin, Choctaw County, Alabama

USGS Publications Warehouse

Davis, M.E.; Sparkes, A.K.; Peacock, B.S.

1983-01-01

Test drilling at Melvin, Choctaw County, Alabama, discloses that the Nanafalia Formation (Paleocene) contains freshwater in sand at a distance of 25 miles downdip from the outcrop area. A nearby fault on the north side of Gilberttown-Pickens fault zone does not appear to affect either the head or the water quality in sand of the Nanafalia. This presently undeveloped aquifer could be a source of water supply in this area. (USGS)
40 CFR Appendix 1 to Subpart A of... - Static Sheen Test

Code of Federal Regulations, 2010 CFR

2010-07-01

... drilling fluids, drill cuttings, produced sand, and well treatment, completion and workover fluids. “Free... drill cuttings or produced sand are introduced into ambient seawater in a container having an air-to... specified. 6. Quality Control Procedures None currently specified. 7. Sample Collection and Handling 7...
Centrifuge modeling of cyclic lateral response of pile-cap systems and seat-type abutments in dry sands

DOT National Transportation Integrated Search

1998-10-02

This report presents the results of slow, cyclic, lateral-loading centrifuge tests performed on models of pile-cap foundation systems and seat-type bridge abutements in dry Neveda sand of 75% relative density to study the lateral response of these sy...
Risk of Mycoplasma bovis transmission from contaminated sand bedding to naive dairy calves.

PubMed

Wilson, D J; Justice-Allen, A; Goodell, G; Baldwin, T J; Skirpstunas, R T; Cavender, K B

2011-03-01

The objective of this study was to evaluate the possible transmission of Mycoplasma bovis from positive sand bedding to naïve dairy calves. Twelve preweaned Holstein bull calves were blocked in pairs and randomly assigned as unexposed controls (n=6) bedded with control sand, or exposed calves (n=6) bedded with sand previously positive for M. bovis at a dairy farm. Bedding sand was cultured weekly. Nasal and ear swabs and sera were collected weekly, tracheal swabs were collected monthly, and by the end of the 105-d study, all calves were euthanized (n=10) or died (n=2). Sera were tested for M. bovis-specific antibody. Mycoplasma spp. culture was performed on nasal and ear swabs; culture and a PCR differentiating multiple Mycoplasma spp. were performed on postmortem samples of lung, retropharyngeal lymph node, and trachea from each calf. A complete necropsy also was performed. During 6 wk, mycoplasma concentration in exposed group sand was between 200 and 32,000 cfu/g. All 166 tracheal swabs, nasal and ear swabs, and postmortem tests from all calves were negative for mycoplasma. All 94 sera were negative for M. bovis-specific antibody. No gross pathology suggestive of mycoplasma disease was detected. The probability of mycoplasma detection, if an exposed calf had become infected 4 wk after exposure, ranged between 97 and 99% depending on time of exposure for individual calves. There was no evidence that sand bedding contaminated with M. bovis might serve as a source of transmission to naïve dairy calves. Copyright © 2011 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.
Monthly Distribution of Phlebotomine Sand Flies, and Biotic and Abiotic Factors Related to Their Abundance, in an Urban Area to Which Visceral Leishmaniasis Is Endemic in Corumbá, Brazil.

PubMed

Falcão de Oliveira, Everton; Casaril, Aline Etelvina; Fernandes, Wagner Souza; Ravanelli, Michelle de Saboya; Medeiros, Márcio José de; Gamarra, Roberto Macedo; Paranhos Filho, Antônio Conceição; Oshiro, Elisa Teruya; Oliveira, Alessandra Gutierrez de; Galati, Eunice Aparecida Bianchi

2016-01-01

The monthly distribution and abundance of sand flies are influenced by both biotic and abiotic factors. The present study aimed to evaluate the seasonal distribution of sand flies and the relation between their abundance and environmental parameters, including vegetation and climate. This study was conducted over a 2-year period (April 2012 to March 2014). Monthly distribution was evaluated through the weekly deployment of CDC light traps in the peridomicile area of 5 residences in an urban area of the municipality of Corumbá in the State of Mato Grosso do Sul, Brazil. Meteorological data were obtained from the Mato Grosso do Sul Center for Weather, Climate, and Water Resources. The spectral indices were calculated based on spatial resolution images (GeoEye) and the percentage of vegetal coverage. Differences in the abundance of sand flies among the collection sites were assessed using the Kruskal-Wallis test, and the strength of correlations between environmental variables was determined by calculating Spearman's correlation coefficients. Lutzomyia cruzi, Lu. forattinii, and Evandromyia corumbaensis were the most frequently found species. Although no significant association was found among these sand fly species and the tested environmental variables (vegetation and climate), high population peaks were found during the rainy season, whereas low peaks were observed in the dry season. The monthly distribution of sand flies was primarily determined by Lu. cruzi, which accounted for 93.94% of the specimens collected each month throughout the experimental period. The fact that sand flies were detected year-round indicates a continuous risk of infection to humans, demonstrating the need for targeted management and education programs.
Microstructure Based Material-Sand Particulate Interactions and Assessment of Coatings for High Temperature Turbine Blades

NASA Technical Reports Server (NTRS)

Murugan, Muthuvel; Ghoshal, Anindya; Walock, Michael; Nieto, Andy; Bravo, Luis; Barnett, Blake; Pepi, Marc; Swab, Jeffrey; Pegg, Robert Tyler; Rowe, Chris;

2017-01-01

Gas turbine engines for military/commercial fixed-wing and rotary wing aircraft use thermal barrier coatings in the high-temperature sections of the engine for improved efficiency and power. The desire to further make improvements in gas turbine engine efficiency and high power-density is driving the research and development of thermal barrier coatings and the effort of improving their tolerance to fine foreign particulates that may be contained in the intake air. Both commercial and military aircraft engines often are required to operate over sandy regions such as in the Middle-East nations, as well as over volcanic zones. For rotorcraft gas turbine engines, the sand ingestion is adverse during take-off, hovering near ground, and landing conditions. Although, most of the rotorcraft gas turbine engines are fitted with inlet particle separators, they are not 100 percent efficient in filtering fine sand particles of size 75 microns or below. The presence of these fine solid particles in the working fluid medium has an adverse effect on the durability of turbine blade thermal barrier coatings and overall performance of the engine. Typical turbine blade damages include blade coating wear, sand glazing, Calcia-Magnesia-Alumina-Silicate (CMAS) attack, oxidation, plugged cooling holes, all of which can cause rapid performance deterioration including loss of aircraft. The objective of this research is to understand the fine particle interactions with typical ceramic coatings of turbine blades at the microstructure level. A finite-element based microstructure modeling and analysis has been performed to investigate particle-surface interactions, and restitution characteristics. Experimentally, a set of tailored thermal barrier coatings and surface treatments were down-selected through hot burner rig tests and then applied to first stage nozzle vanes of the Gas Generator Turbine of a typical rotorcraft gas turbine engine. Laser Doppler velocity measurements were performed during hot burner rig testing to determine sand particle incoming velocities and their rebound characteristics upon impact on coated material targets. Further, engine sand ingestion tests were carried out to test the CMAS tolerance of the coated nozzle vanes. The findings from this on-going collaborative research to develop the next-gen sand tolerant coatings for turbine blades are presented in this paper.

Biodegradation of phenol, salicylic acid, benzenesulfonic acid, and iomeprol by Pseudomonas fluorescens in the capillary fringe

NASA Astrophysics Data System (ADS)

Hack, Norman; Reinwand, Christian; Abbt-Braun, Gudrun; Horn, Harald; Frimmel, Fritz H.

2015-12-01

Mass transfer and biological transformation phenomena in the capillary fringe were studied using phenol, salicylic acid, benzenesulfonic acid, and the iodinated X-ray contrast agent iomeprol as model organic compounds and the microorganism strain Pseudomonas fluorescens. Three experimental approaches were used: Batch experiments (uniform water saturation and transport by diffusion), in static columns (with a gradient of water saturation and advective transport in the capillaries) and in a flow-through cell (with a gradient of water saturation and transport by horizontal and vertical flow: 2-dimension flow-through microcosm). The reactors employed for the experiments were filled with quartz sand of defined particle size distribution (dp = 200…600 μm, porosity ε = 0.42). Batch experiments showed that phenol and salicylic acid have a high, whereas benzenesulfonic acid and iomeprol have a quite low potential for biodegradation under aerobic conditions and in a matrix nearly close to water saturation. Batch experiments under anoxic conditions with nitrate as electron acceptor revealed that the biodegradation of the model compounds was lower than under aerobic conditions. Nevertheless, the experiments showed that the moisture content was also responsible for an optimized transport in the liquid phase of a porous medium. Biodegradation in the capillary fringe was found to be influenced by both the moisture content and availability of the dissolved substrate, as seen in static column experiments. The gas-liquid mass transfer of oxygen also played an important role for the biological activity. In static column experiments under aerobic conditions, the highest biodegradation was found in the capillary fringe (e.g. βt/β0 (phenol) = 0 after t = 6 d) relative to the zone below the water table and unsaturated zone. The highest biodegradation occurred in the flow-through cell experiment where the height of the capillary fringe was largest.
Biodegradation of phenol, salicylic acid, benzenesulfonic acid, and iomeprol by Pseudomonas fluorescens in the capillary fringe.

PubMed

Hack, Norman; Reinwand, Christian; Abbt-Braun, Gudrun; Horn, Harald; Frimmel, Fritz H

2015-12-01

Mass transfer and biological transformation phenomena in the capillary fringe were studied using phenol, salicylic acid, benzenesulfonic acid, and the iodinated X-ray contrast agent iomeprol as model organic compounds and the microorganism strain Pseudomonas fluorescens. Three experimental approaches were used: Batch experiments (uniform water saturation and transport by diffusion), in static columns (with a gradient of water saturation and advective transport in the capillaries) and in a flow-through cell (with a gradient of water saturation and transport by horizontal and vertical flow: 2-dimension flow-through microcosm). The reactors employed for the experiments were filled with quartz sand of defined particle size distribution (dp=200...600 μm, porosity ε=0.42). Batch experiments showed that phenol and salicylic acid have a high, whereas benzenesulfonic acid and iomeprol have a quite low potential for biodegradation under aerobic conditions and in a matrix nearly close to water saturation. Batch experiments under anoxic conditions with nitrate as electron acceptor revealed that the biodegradation of the model compounds was lower than under aerobic conditions. Nevertheless, the experiments showed that the moisture content was also responsible for an optimized transport in the liquid phase of a porous medium. Biodegradation in the capillary fringe was found to be influenced by both the moisture content and availability of the dissolved substrate, as seen in static column experiments. The gas-liquid mass transfer of oxygen also played an important role for the biological activity. In static column experiments under aerobic conditions, the highest biodegradation was found in the capillary fringe (e.g. βt/β0 (phenol)=0 after t=6 d) relative to the zone below the water table and unsaturated zone. The highest biodegradation occurred in the flow-through cell experiment where the height of the capillary fringe was largest. Copyright © 2015 Elsevier B.V. All rights reserved.
40 CFR 63.1325 - Batch process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2011 CFR

2011-07-01

... production or activity level. (1) If the expected mix of products serves as the basis for the batch mass... from the high-level calibration gas is at least 20 times the standard deviation of the response from... 25A, 40 CFR part 60, appendix A, is acceptable if the response from the high-level calibration gas is...
Experimental Investigation of the Effect of Manufactured Sand and Lightweight Sand on the Properties of Fresh and Hardened Self-Compacting Lightweight Concretes.

PubMed

Zhu, Yiyun; Cui, Hongzhi; Tang, Waiching

2016-08-29

Self-compacting lightweight concrete (SCLC) is a promising construction material for building applications, but most SCLCs today are made with river sand (RS). There is an increasing demand for environmental protection, as well as materials with a high strength/density ratio. The manufactured sand (MS) and lightweight sand (LS) as fine aggregates in cement-based composite materials have been receiving more attention among researchers. However, there is not much information about the effects of MS and LS on the properties of the fresh and hardened SCLCs. In this paper, the properties of fresh and hardened SCLC made with MS and LS were investigated by a series of experiments. SCLCs made with RS served as the control in this study. The test results show that increasing the sand ratio (from 0.40-0.50) decreased the filling ability and led to an increased T 50 time, which is the time spent for the concrete to reach the 500 mm spread circle, for all of the fresh SCLCs. Although the passing ability of MS-SCLCs and LS-SCLCs is not as good as RS-SCLCs, their results are still within an acceptable range. The ratio of mechanical properties to density was found to increase with an increase of the sand ratio for all of the hardened SCLCs. MS-SCLCs presented the highest compressive strength among all of the SCLCs studied. Although the mean compressive strength of LS-SCLCs is lower than those of the other two SCLCs by 8%, their strength to density ratio is higher than others by 15%, and the ratio increases remarkably with the increase of the sand ratio. Permeability test results showed that the permeability coefficient of MS-SCLC is remarkably lower than that of LS-SCLC, but slightly higher than that of RS-SCLC.

Mapping epibenthic assemblages and their relations to sedimentary features in shallow-water, high-energy environments

NASA Astrophysics Data System (ADS)

Sisson, John D.; Shimeta, Jeff; Zimmer, Cheryl Ann; Traykovski, Peter

2002-03-01

Knowledge of spatial relationships among benthic biota and sedimentary features in shallow-water (<30 m) high-energy environments has been severely limited by sampling technology. We describe and report tests of a SCUBA-diving mapping method specifically for this region. Underwater acoustic location is used to achieve meter-scale resolution over kilometer-scale regions of the sea floor. A triad of acoustic transponders is bottom-mounted at known positions, 300-500 m apart. Transported by underwater personal vehicles, SCUBA-divers map the bed using hand-held acoustic receivers that record ranges to the transponders. The mean error of acoustic fixes was 2.4±1.2 m in a 0.5 km×1.0 km test area. Dense assemblages of epibenthic animals were mapped relative to sediment texture and bedforms off the exposed south coast of Martha's Vineyard Island, Massachusetts, USA. Surveys one month apart within a 0.6 km×0.6 km area (8-12 m depth) revealed 100-m-scale patches of the tube worm Spiophanes bombyx (⩽30,000 m -2) in fine sand and of the sand dollar Echinarachnius parma (⩽55 m -2) in coarse sand. Raised mud patches that, together with fine sand, occurred in two shore-perpendicular belts are likely exposed, ancient marsh deposits. Depth gradients of sand-ripple geometry indicated that ripples in deeper areas were not in equilibrium with wave conditions monitored during surveys; i.e., they were relict ripples. Thus, sand dollars in some areas may have had >1 month to rework surficial sands since their transformation by physical processes. Linear regressions of ripple characteristics against sand dollar or tube worm densities were not significant, although such relationships would be highly dependent on temporal scale. The survey method described here can be used at more frequent intervals to explore such interactions between epibenthic animals and sediment-transport dynamics.
Experimental Investigation of the Effect of Manufactured Sand and Lightweight Sand on the Properties of Fresh and Hardened Self-Compacting Lightweight Concretes

PubMed Central

Zhu, Yiyun; Cui, Hongzhi; Tang, Waiching

2016-01-01

Self-compacting lightweight concrete (SCLC) is a promising construction material for building applications, but most SCLCs today are made with river sand (RS). There is an increasing demand for environmental protection, as well as materials with a high strength/density ratio. The manufactured sand (MS) and lightweight sand (LS) as fine aggregates in cement-based composite materials have been receiving more attention among researchers. However, there is not much information about the effects of MS and LS on the properties of the fresh and hardened SCLCs. In this paper, the properties of fresh and hardened SCLC made with MS and LS were investigated by a series of experiments. SCLCs made with RS served as the control in this study. The test results show that increasing the sand ratio (from 0.40–0.50) decreased the filling ability and led to an increased T50 time, which is the time spent for the concrete to reach the 500 mm spread circle, for all of the fresh SCLCs. Although the passing ability of MS-SCLCs and LS-SCLCs is not as good as RS-SCLCs, their results are still within an acceptable range. The ratio of mechanical properties to density was found to increase with an increase of the sand ratio for all of the hardened SCLCs. MS-SCLCs presented the highest compressive strength among all of the SCLCs studied. Although the mean compressive strength of LS-SCLCs is lower than those of the other two SCLCs by 8%, their strength to density ratio is higher than others by 15%, and the ratio increases remarkably with the increase of the sand ratio. Permeability test results showed that the permeability coefficient of MS-SCLC is remarkably lower than that of LS-SCLC, but slightly higher than that of RS-SCLC. PMID:28773857
Comparison of chemiluminescence methods for analysis of hydrogen peroxide and hydroxyl radicals

NASA Astrophysics Data System (ADS)

Pehrman, R.; Amme, M.; Cachoir, C.

2006-01-01

Assessment of alpha radiolysis influence on the chemistry of geologically disposed spent fuel demands analytical methods for radiolytic product determination at trace levels. Several chemiluminescence methods for the detection of radiolytic oxidants hydrogen peroxide and hydroxyl radicals are tested. Two of hydrogen peroxide methods use luminol, catalyzed by either μ-peroxidase or hemin, one uses 10-methyl-9-(p-formylphenyl)-acridinium carboxylate trifluoromethanesulfonate and one potassium periodate. All recipes are tested as batch systems in basic conditions. For hydroxyl radical detection luminophores selected are 3-hydroxyphthalic hydrazide and rutin. Both methods are tested as batch systems. The results are compared and the applicability of the methods for near-field dissolution studies is discussed.
Test of precoat filtration technology for treatment of swimming pool water.

PubMed

Christensen, Morten Lykkegaard; Klausen, Morten Møller; Christensen, Peter Vittrup

2018-02-01

The technical performance of a precoat filter was compared with that of a traditional sand filter. Particle concentration and size distribution were measured before and after the filtration of swimming pool water. Both the sand and precoat filters could reduce the particle concentration in the effluent. However, higher particle removal efficiency was generally observed for the precoat filter, especially for particles smaller than 10 μm in diameter. Adding flocculant improved the removal efficiency of the sand filter, resulting in removal efficiencies comparable to those of the precoat filter. Three powders, i.e., two types of perlite (Harbolite ® and Aquatec perlite) and cellulose fibers (Arbocel ® ), were tested for the precoat filter, but no significant difference in particle removal efficiency was observed among them. The maximum efficiency was reached within 30-40 min of filtration. The energy required for the pumps increased by approximately 35% over a period of 14 days. The energy consumption could be reduced by replacing the powder on the filter cloth. The sand filter was backwashed once a week, while the powder on the precoat filter was replaced every two weeks. Under these conditions, it was possible to reduce the water used for cleaning by 88% if the precoat filter was used instead of the sand filter.
Testing ecological tradeoffs of a new tool for removing fine sediment in a spring-fed stream

USGS Publications Warehouse

Sepulveda, Adam; Sechrist, Juddson D.; Marczak, Laurie B

2014-01-01

Excessive fine sediment is a focus of stream restoration work because it can impair the structure and function of streams, but few methods exist for removing sediment in spring-fed streams. We tested a novel method of sediment removal with the potential to have minimal adverse effects on the biological community during the restoration process. The Sand Wand system, a dredgeless vacuum developed by Streamside Technologies, was used to experimentally remove fine sediment from Kackley Springs, a spring creek in southeastern Idaho. We assessed the effects of the Sand Wand on stream physical habitat and macroinvertebrate composition for up to 60 days after the treatment. We documented changes in multiple habitat variables, including stream depth, median particle size, and the frequency of embedded substrate in stream reaches that were treated with the Sand Wand. We also found that macroinvertebrate composition was altered even though common macroinvertebrate metrics changed little after the treatment. Our results suggest that the Sand Wand was effective at removing fine sediments in Kackley Springs and did minimal harm to macroinvertebrate function, but the Sand Wand was not ultimately effective in improving substrate composition to desired conditions. Additional restoration techniques are still needed to decrease the amount of fine sediment.
Mineralogy and morphology of sand: Key parameters in the durability for its use in artificial beach nourishment.

PubMed

López, M; Baeza-Brotons, F; López, I; Tenza-Abril, A J; Aragonés, L

2018-05-19

Sand is the third most consumed material in the world, although it is a very scarce material. An exhaustive knowledge of sand and its behaviour against the waves is important for selecting the most suitable material to avoid shoreline erosion. To this end, a pattern of behaviour against accelerated wear test has been sought for 26 sand samples with different characteristics and origins (natural, dredged and quarried), with a focus on their mineralogy as well as a comparison of beach evolution carried out by other authors. Several techniques have been applied for characterization: granulometry, calcimetry, XRD and SEM. The results show that the different degrees of sand grain wear are not only due to their size and mineralogy, but also to the morphology of the particles. Copyright © 2018 Elsevier B.V. All rights reserved.
Fuzzy logic feedback control for fed-batch enzymatic hydrolysis of lignocellulosic biomass.

PubMed

Tai, Chao; Voltan, Diego S; Keshwani, Deepak R; Meyer, George E; Kuhar, Pankaj S

2016-06-01

A fuzzy logic feedback control system was developed for process monitoring and feeding control in fed-batch enzymatic hydrolysis of a lignocellulosic biomass, dilute acid-pretreated corn stover. Digested glucose from hydrolysis reaction was assigned as input while doser feeding time and speed of pretreated biomass were responses from fuzzy logic control system. Membership functions for these three variables and rule-base were created based on batch hydrolysis data. The system response was first tested in LabVIEW environment then the performance was evaluated through real-time hydrolysis reaction. The feeding operations were determined timely by fuzzy logic control system and efficient responses were shown to plateau phases during hydrolysis. Feeding of proper amount of cellulose and maintaining solids content was well balanced. Fuzzy logic proved to be a robust and effective online feeding control tool for fed-batch enzymatic hydrolysis.
Kinetic modelling of anaerobic hydrolysis of solid wastes, including disintegration processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

García-Gen, Santiago; Sousbie, Philippe; Rangaraj, Ganesh

2015-01-15

Highlights: • Fractionation of solid wastes into readily and slowly biodegradable fractions. • Kinetic coefficients estimation from mono-digestion batch assays. • Validation of kinetic coefficients with a co-digestion continuous experiment. • Simulation of batch and continuous experiments with an ADM1-based model. - Abstract: A methodology to estimate disintegration and hydrolysis kinetic parameters of solid wastes and validate an ADM1-based anaerobic co-digestion model is presented. Kinetic parameters of the model were calibrated from batch reactor experiments treating individually fruit and vegetable wastes (among other residues) following a new protocol for batch tests. In addition, decoupled disintegration kinetics for readily and slowlymore » biodegradable fractions of solid wastes was considered. Calibrated parameters from batch assays of individual substrates were used to validate the model for a semi-continuous co-digestion operation treating simultaneously 5 fruit and vegetable wastes. The semi-continuous experiment was carried out in a lab-scale CSTR reactor for 15 weeks at organic loading rate ranging between 2.0 and 4.7 g VS/L d. The model (built in Matlab/Simulink) fit to a large extent the experimental results in both batch and semi-continuous mode and served as a powerful tool to simulate the digestion or co-digestion of solid wastes.« less
Investigation of Media Effects on Removal of Heavy Metals in Bioretention Cells

NASA Astrophysics Data System (ADS)

Gülbaz, Sezar; Melek Kazezyilmaz-Alhan, Cevza; Copty, Nadim K.

2015-04-01

Heavy metals are the most toxic elements at high concentrations, although some of them such as Cu and Zn are essential to plants, humans, and animals within a limited value. However, some heavy metals, such as Pb, have adverse effects even at low concentrations. Therefore, it is known that the toxic metals such as Zn, Cu and Pb in storm water runoff are serious threat for aquatic organisms. It is very important to control and reduce heavy metal concentration in urban storm water runoff. There are several methods to remove the aforementioned toxic metals such as electrolyte extraction, chemical precipitation, ion-exchange, reverse osmosis, membrane filtration, adsorption, cementation, and electrochemical treatment technologies. However, these methods are highly expensive and hard to implement for treatment of big volumes of water such as storm water. For this purpose, Low Impact Development (LID) Best Management Practices (BMPs) have become popular to collect, infiltrate, and treat toxic metals in storm water runoff in recent years. LID-BMP is a land planning method which is used to manage storm water runoff and improve water quality by reducing contaminant in storm water runoff. Bioretention is an example of LID-BMP application of which usage has recently been started in storm water treatment. Researchers have been investigating the advantages of bioretention systems and this study contributes to these research efforts by seeking for the media effects of bioretention on heavy metal removal. For this purpose, batch sorption experiments were performed to determine the distribution coefficients and retardation factor of copper (Cu), lead (Pb), and zinc (Zn) for bioretention media such as mulch, turf, local or vegetative soil, sand and gravel. Furthermore, sorption reaction kinetics of Cu, Pb and Zn are tested in order to assess the sorption equilibrium time of these metals for 5 bioretention media. The results of sorption test show that turf has higher sorption capacity than mulch and local soil for heavy metals used in the experiment. On the other hand, sand and gravel have relatively lower sorption capacities. Linear equilibrium isotherm represents sorption of these metals for all bioretention media. The highest sorption is observed for Pb followed by Cu and Zn for all bioretention media. The time required for reaching equilibrium conditions for bioretention column media is ranged from 1 to 6 hours for each metal investigated.
Colorado River sediment transport: 2. Systematic bed‐elevation and grain‐size effects of sand supply limitation

USGS Publications Warehouse

Topping, David J.; Rubin, David M.; Nelson, Jonathan M.; Kinzel, Paul J.; Corson, Ingrid C.

2000-01-01

The Colorado River in Marble and Grand Canyons displays evidence of annual supply limitation with respect to sand both prior to [Topping et al, this issue] and after the closure of Glen Canyon Dam in 1963. Systematic changes in bed elevation and systematic coupled changes in suspended‐sand concentration and grain size result from this supply limitation. During floods, sand supply limitation either causes or modifies a lag between the time of maximum discharge and the time of either maximum or minimum (depending on reach geometry) bed elevation. If, at a cross section where the bed aggrades with increasing flow, the maximum bed elevation is observed to lead the peak or the receding limb of a flood, then this observed response of the bed is due to sand supply limitation. Sand supply limitation also leads to the systematic evolution of sand grain size (both on the bed and in suspension) in the Colorado River. Sand input during a tributary flood travels down the Colorado River as an elongating sediment wave, with the finest sizes (because of their lower settling velocities) traveling the fastest. As the fine front of a sediment wave arrives at a given location, the bed fines and suspended‐sand concentrations increase in response to the enhanced upstream supply of finer sand. Then, as the front of the sediment wave passes that location, the bed is winnowed and suspended‐sand concentrations decrease in response to the depletion of the upstream supply of finer sand. The grain‐size effects of depletion of the upstream sand supply are most obvious during periods of higher dam releases (e.g., the 1996 flood experiment and the 1997 test flow). Because of substantial changes in the grain‐size distribution of the bed, stable relationships between the discharge of water and sand‐transport rates (i.e., stable sand rating curves) are precluded. Sand budgets in a supply‐limited river like the Colorado River can only be constructed through inclusion of the physical processes that couple changes in bed‐sediment grain size to changes in sand‐transport rates.
A continuously weighing, high frequency sand trap: Wind tunnel and field evaluations

NASA Astrophysics Data System (ADS)

Yang, Fan; Yang, XingHua; Huo, Wen; Ali, Mamtimin; Zheng, XinQian; Zhou, ChengLong; He, Qing

2017-09-01

A new continuously weighing, high frequency sand trap (CWHF) has been designed. Its sampling efficiency is evaluated in a wind tunnel and the potential of the new trap has been demonstrated in field trials. The newly designed sand trap allows fully automated and high frequency measurement of sediment fluxes over extensive periods. We show that it can capture the variations and structures of wind-driven sand transport processes and horizontal sediment flux, and reveal the relationships between sand transport and meteorological parameters. Its maximum sampling frequency can reach 10 Hz. Wind tunnel tests indicated that the sampling efficiency of the CWHF sand trap varies between 39.2 to 64.3%, with an average of 52.5%. It achieved a maximum sampling efficiency of 64.3% at a wind speed of 10 m s- 1. This is largely achieved by the inclusion of a vent hole which leads to a higher sampling efficiency than that of a step-like sand trap at high wind speeds. In field experiments, we show a good agreement between the mass of sediment from the CWHF sand trap, the wind speed at 2 m and the number of saltating particles at 5 cm above the ground surface. According to analysis of the horizontal sediment flux at four heights from the CWHF sand trap (25, 35, 50, and 100 cm), the vertical distribution of the horizontal sediment flux up to a height of 100 cm above the sand surface follows an exponential function. Our field experiments show that the new instrument can capture more detailed information on sediment transport with much reduced labor requirement. Therefore, it has great potential for application in wind-blown sand monitoring and process studies.
Citric Acid-Modified Fenton's Reaction for the Oxidation of Chlorinated Ethylenes in Soil Solution Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seol, Yongkoo; Javandel, Iraj

Fenton's reagent, a solution of hydrogen peroxide and ferrous iron catalyst, is used for an in-situ chemical oxidation of organic contaminants. Sulfuric acid is commonly used to create an acidic condition needed for catalytic oxidation. Fenton's reaction often involves pressure buildup and precipitation of reaction products, which can cause safety hazards and diminish efficiency. We selected citric acid, a food-grade substance, as an acidifying agent to evaluate its efficiencies for organic contaminant removal in Fenton's reaction, and examined the impacts of using citric acid on the unwanted reaction products. A series of batch and column experiments were performed with varyingmore » H{sub 2}O{sub 2} concentrations to decompose selected chlorinated ethylenes. Either dissolved iron from soil or iron sulfate salt was added to provide the iron catalyst in the batch tests. Batch experiments revealed that both citric and sulfuric acid systems achieved over 90% contaminant removal rates, and the presence of iron catalyst was essential for effective decontamination. Batch tests with citric acid showed no signs of pressure accumulation and solid precipitations, however the results suggested that an excessive usage of H{sub 2}O{sub 2} relative to iron catalysts (Fe{sup 2+}/H{sub 2}O{sub 2} < 1/330) would result in lowering the efficiency of contaminant removal by iron chelations in the citric acid system. Column tests confirmed that citric acid could provide suitable acidic conditions to achieve higher than 55% contaminant removal rates.« less
Citric acid-modified Fenton's reaction for the oxidation of chlorinated ethylenes in soil solution systems.

PubMed

Seol, Yongkoo; Javandel, Iraj

2008-06-01

Fenton's reagent, a solution of hydrogen peroxide and ferrous iron catalyst, is used for an in situ chemical oxidation of organic contaminants. Sulfuric acid is commonly used to create an acidic condition needed for catalytic oxidation. Fenton's reaction often involves pressure buildup and precipitation of reaction products, which can cause safety hazards and diminish efficiency. We selected citric acid, a food-grade substance, as an acidifying agent to evaluate its efficiencies for organic contaminant removal in Fenton's reaction, and examined the impacts of using citric acid on the unwanted reaction products. A series of batch and column experiments were performed with varying H2O2 concentrations to decompose selected chlorinated ethylenes. Either dissolved iron from soil or iron sulfate salt was added to provide the iron catalyst in the batch tests. Batch experiments revealed that both citric and sulfuric acid systems achieved over 90% contaminant removal rates, and the presence of iron catalyst was essential for effective decontamination. Batch tests with citric acid showed no signs of pressure accumulation and solid precipitations, however the results suggested that an excessive usage of H2O2 relative to iron catalysts (Fe2+/H2O2<1/330) would result in lowering the efficiency of contaminant removal by iron chelation in the citric acid system. Column tests confirmed that citric acid could provide suitable acidic conditions to achieve higher than 55% contaminant removal rates.
Batch process fault detection and identification based on discriminant global preserving kernel slow feature analysis.

PubMed

Zhang, Hanyuan; Tian, Xuemin; Deng, Xiaogang; Cao, Yuping

2018-05-16

As an attractive nonlinear dynamic data analysis tool, global preserving kernel slow feature analysis (GKSFA) has achieved great success in extracting the high nonlinearity and inherently time-varying dynamics of batch process. However, GKSFA is an unsupervised feature extraction method and lacks the ability to utilize batch process class label information, which may not offer the most effective means for dealing with batch process monitoring. To overcome this problem, we propose a novel batch process monitoring method based on the modified GKSFA, referred to as discriminant global preserving kernel slow feature analysis (DGKSFA), by closely integrating discriminant analysis and GKSFA. The proposed DGKSFA method can extract discriminant feature of batch process as well as preserve global and local geometrical structure information of observed data. For the purpose of fault detection, a monitoring statistic is constructed based on the distance between the optimal kernel feature vectors of test data and normal data. To tackle the challenging issue of nonlinear fault variable identification, a new nonlinear contribution plot method is also developed to help identifying the fault variable after a fault is detected, which is derived from the idea of variable pseudo-sample trajectory projection in DGKSFA nonlinear biplot. Simulation results conducted on a numerical nonlinear dynamic system and the benchmark fed-batch penicillin fermentation process demonstrate that the proposed process monitoring and fault diagnosis approach can effectively detect fault and distinguish fault variables from normal variables. Copyright © 2018 ISA. Published by Elsevier Ltd. All rights reserved.
Fermentation and microflora of plaa-som, a thai fermented fish product prepared with different salt concentrations.

PubMed

Paludan-Müller, Christine; Madsen, Mette; Sophanodora, Pairat; Gram, Lone; Møller, Peter Lange

2002-02-25

Plaa-som is a Thai fermented fish product prepared from snakehead fish, salt, palm syrup and sometimes roasted rice. We studied the effects of different salt concentrations on decrease in pH and on microflora composition during fermentation. Two low-salt batches were prepared, containing 6% and 7% salt (w/w) as well as two high-salt batches, containing 9% and 11% salt. pH decreased rapidly from 6 to 4.5 in low-salt batches, whereas in high-salt batches, a slow or no decrease in pH was found. Lactic acid bacteria (LAB) and yeasts were isolated as the dominant microorganisms during fermentation. LAB counts increased to 10(8)-10(9) cfu g(-1) and yeast counts to 10(7)-5 x 10(7) cfu g(-1) in all batches, except in the 11% salt batch, where counts were 1-2 log lower. Phenotypic tests, ITS-PCR, carbohydrate fermentations and 16S rRNA gene sequencing identified LAB isolates as Pediococcus pentosaceus, Lactobacillus alimentarius/farciminis, Weisella confusa, L. plantarum and Lactococcus garviae. The latter species was only isolated from high-salt batches. Phenotypic characteristics, ITS-PCR and carbohydrate assimilation identified 95% of the yeasts as Zygosaccharomyces rouxii. It is concluded that the fermentation of plaa-som is delayed by a salt-level of 9% due to an inhibition of LAB growth. The growth of Z. rouxii has no influence on the fermentation rate, but may contribute positively to the flavour development of the product.
The effects of time on the capacity of pipe piles in dense marine sand

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chow, F.C.; Jardine, R.J.; Brucy, F.

Investigations into pile behavior in dense marine sand have been performed by IFP and IC at Dunkirk, North France. In the most recent series of tests, strain-gauged, open-ended pipe piles, driven and statically load tested in 1989, were retested in 1994. Surprisingly large increases in shaft capacity were measured. The possible causes are evaluated in relation to previous case histories, laboratory soil tests, pile corrosion and new effective stress analyses developed using smaller, more intensively instrumented piles. The shaft capacities predicted by existing design methods are also assessed. 51 refs., 12 figs., 4 tabs.
Blast Induced Liquefaction of Soils: Laboratory and Field Tests

DTIC Science & Technology

1988-06-25

characteristics are summarized below and given in Table A.23 in Appendix A.S. 1 . Grain Size Distribution and Grain Shape The physical properties of the sand were...in terms of soil type and void ratio for dynamic tests. -74- Table 4.1. Physical Properties of Monterey No. 0/30 Sand, Bonny Silt and a 50-50 Mixture...Results agree with the experimental observations of peak and long- term porewater pressure responses. The results of our study indicate the following. 1
Sweet lake geopressured-geothermal project, Magma Gulf-Technadril/DOE Amoco Fee. Annual report, December 1, 1979-February 27, 1981. Volume I. Drilling and completion test well and disposal well

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodgers, R.W.

The Sweet lake site is located approximately 15 miles southeast of Lake Charles in Cameron Parish, Louisiana. A geological study showed that the major structure in this area is a graben. The dip of the beds is northwesterly into the basin. A well drilled into the deep basin would find the target sand below 18,000', at high pressures and temperatures. However, since there is no well control in the basin, the specific site was chosen on the 15,000' contour of the target sand in the eastern, more narrow part of the garben. Those key control wells are present within onemore » mile of the test well. The information acquired by drilling the test well confirmed the earlier geologic study. The target sand was reached at 15,065', had a porosity of over 20% and a permeability to water of 300 md. The original reservoir pressure was 12,060 psi and the bottom hole temperature 299{sup 0}F. There are approximately 250 net feet of sand available for the perforation. The disposal well was drilled to a total depth of 7440'.« less
TESTING AND PERFORMANCE ANALYSIS OF NASA 5 CM BY 5 CM BI-SUPPORTED SOLID OXIDE ELECTROLYSIS CELLS OPERATED IN BOTH FUEL CELL AND STEAM ELECTROLYSIS MODES

DOE Office of Scientific and Technical Information (OSTI.GOV)

R. C. O'Brien; J. E. O'Brien; C. M. Stoots

A series of 5 cm by 5 cm bi-supported Solid Oxide Electrolysis Cells (SOEC) were produced by NASA for the Idaho National Laboratory (INL) and tested under the INL High Temperature Steam Electrolysis program. The results from the experimental demonstration of cell operation for both hydrogen production and operation as fuel cells is presented. An overview of the cell technology, test apparatus and performance analysis is also provided. The INL High Temperature Steam Electrolysis laboratory has developed significant test infrastructure in support of single cell and stack performance analyses. An overview of the single cell test apparatus is presented. Themore » test data presented in this paper is representative of a first batch of NASA's prototypic 5 cm by 5 cm SOEC single cells. Clearly a significant relationship between the operational current density and cell degradation rate is evident. While the performance of these cells was lower than anticipated, in-house testing at NASA Glenn has yielded significantly higher performance and lower degradation rates with subsequent production batches of cells. Current post-test microstructure analyses of the cells tested at INL will be published in a future paper. Modification to cell compositions and cell reduction techniques will be altered in the next series of cells to be delivered to INL with the aim to decrease the cell degradation rate while allowing for higher operational current densities to be sustained. Results from the testing of new batches of single cells will be presented in a future paper.« less
A homemade sand-volcano in a gassy alluvial plain (Medolla, Italy): when shallow drilling triggers violent degassing

NASA Astrophysics Data System (ADS)

Capaccioni, Bruno; Coltorti, Massimo; Todesco, Micol; Cremoni, Stefano; Di Giuseppe, Dario; Faccini, Barbara; Tessari, Umberto

2017-04-01

Sand volcanoes are remarkable geological features which form when shallow, water-saturated sand deposits are set in motion and reach the surface. This commonly occurs during earthquakes, as a result of liquefaction of waterlogged bodies, but some of these sand emissions are unrelated to seismic events. We present the case of a sand eruption triggered by a Cone Penetration Test (CPT) near Medolla (Italy), on the 10th of October 2014. A large amount of natural gas (CO2 and CH4)was erupted together with a mixture of water and sand, creating a sand volcano. The event was recorded and its evolution and final result were analyzed from several points of view. Our multidisciplinary approach involved morphological and sedimentological studies on the sand-volcano, chemical and isotopic analysis of discharged gases, repeated measurements of gas flux on the drill hole and of diffuse degassing in the surrounding area and numerical modelling of the aquifer feeding the discharge. Our results suggest that a geyser discharging a mixture of gas and water, capable of building a sand volcano, requires the presence of a shallow pressurized reservoir (1.2 MPa) where water coexists with a small amount of exsolved gas (a volume fraction of 0.05). The violent degassing occurred in Medolla confirms the role that a free gas phase may have in favoring the mobilization of liquid water and loose deposits, even in the absence of a seismic event.

Some links on this page may take you to non-federal websites. Their policies may differ from this site.