Characterization of sediment trapped by macroalgae on a Hawaiian reef flat

USGS Publications Warehouse

Stamski, R.E.; Field, M.E.

2006-01-01

Reef researchers studying community shifts in the balance between corals and fleshy macroalgae have noted that algae are often covered with sediment. This study characterizes sediment trapping by macroalgae within a Hawaiian reef habitat and constrains the controls on this process. Sediment-laden macroalgae were sampled and macroalgal cover was assessed on a wide (???1 km) reef flat off south-central Molokai. Macroalgae trapped a mean of 1.26 (??0.91 SD) grams of sediment per gram of dry weight biomass and that sediment was dominantly terrigenous mud (59% by weight). It was determined that biomass, as a proxy for algal size, and morphology were not strict controls on the sediment trapping process. Over 300 metric tons of sediment were estimated to be retained by macroalgae across 5.75 km2 of reef flat (54 g m-2), suggesting that this process is an important component of sediment budgets. In addition, understanding the character of sediment trapped by macroalgae may help constrain suspended sediment flux and has implications for nutrient dynamics in reef flat environments. ?? 2005 Elsevier Ltd. All rights reserved.

Characterization of sediment trapped by macroalgae on a Hawaiian reef flat

NASA Astrophysics Data System (ADS)

Stamski, Rebecca E.; Field, Michael E.

2006-01-01

Reef researchers studying community shifts in the balance between corals and fleshy macroalgae have noted that algae are often covered with sediment. This study characterizes sediment trapping by macroalgae within a Hawaiian reef habitat and constrains the controls on this process. Sediment-laden macroalgae were sampled and macroalgal cover was assessed on a wide (˜1 km) reef flat off south-central Molokai. Macroalgae trapped a mean of 1.26 (±0.91 SD) grams of sediment per gram of dry weight biomass and that sediment was dominantly terrigenous mud (59% by weight). It was determined that biomass, as a proxy for algal size, and morphology were not strict controls on the sediment trapping process. Over 300 metric tons of sediment were estimated to be retained by macroalgae across 5.75 km 2 of reef flat (54 g m -2), suggesting that this process is an important component of sediment budgets. In addition, understanding the character of sediment trapped by macroalgae may help constrain suspended sediment flux and has implications for nutrient dynamics in reef flat environments.

Aquatic Sediments.

ERIC Educational Resources Information Center

Sanville, W. D.; And Others

1978-01-01

Presents a literature review of aquatic sediments and its effect upon water quality, covering publications of 1976-77. This review includes: (1) sediment water interchange; (2) chemical and physical characterization; and (3) heavy water in sediments. A list of 129 references is also presented. (HM)

Sediment Evaluation Framework for the Pacific Northwest

EPA Pesticide Factsheets

The Sediment Evaluation Framework provides a regional framework for assessment, characterization and management of sediments in the Pacific Northwest to determine suitability for unconfined in-water disposal.

Quantitative generalizations for catchment sediment yield following forest logging

Treesearch

James C. Bathurst; Andrés Iroumé

2014-01-01

Published data for temperate forests across the world are analyzed to investigate the potential for generalized quantitative expressions of catchment sediment yield impact in the years immediately following logging. Such generalizations would be useful in a variety of forestry and engineering tasks and would aid the spread of knowledge amongst both relevant...

Results of sampling and analysis : preliminary sediment quality assessment Martha Lake Snohomish County Washington

DOT National Transportation Integrated Search

1995-10-18

This report presents the results of sediment sampling and analysis conducted in support of proposed dredging activities of Martha Lake Sediments. The characterization of the sediments will be used in support of permitting applications and exploring v...

Advanced thermally stable jet fuels: Technical progress report, October 1994--December 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schobert, H.H.; Eser, S.; Song, C.

There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation inmore » a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Characterization of solid gums, sediments, and carbonaceous deposits, is subtask, Studies of surface chemistry of PX-21 activated carbon during thermal degradation of jet A-1 fuel and n-dodecane; under Task 4, Coal-based fuel stabilization studies, is subtask, Exploratory screening and development potential of jet fuel thermal stabilizers over 400 C; and under Task 5, Exploratory studies on the direct conversion of coal to high quality jet fuels, are 4 subtasks: Novel approaches to low-severity coal liquefaction and coal/resid co-processing using water and dispersed catalysts; Shape-selective naphthalene hydrogenation for production of thermally stable jet fuels; Design of a batch mode and a continuous mode three-phase reactor system for the liquefaction of coal and upgrading of coal liquids; and Exploratory studies on coal liquids upgrading using mesopores molecular sieve catalysts. 136 refs., 69 figs., 24 tabs.« less

Characterizing toxicity of metal-contaminated sediments from mining areas

USGS Publications Warehouse

Besser, John M.; Brumbaugh, William G.; Ingersoll, Christopher G.

2015-01-01

This paper reviews methods for testing the toxicity of metals associated with freshwater sediments, linking toxic effects with metal exposure and bioavailability, and developing sediment quality guidelines. The most broadly applicable approach for characterizing metal toxicity is whole-sediment toxicity testing, which attempts to simulate natural exposure conditions in the laboratory. Standard methods for whole-sediment testing can be adapted to test a wide variety of taxa. Chronic sediment tests that characterize effects on multiple endpoints (e.g., survival, growth, and reproduction) can be highly sensitive indicators of adverse effects on resident invertebrate taxa. Methods for testing of aqueous phases (pore water, overlying water, or elutriates) are used less frequently. Analysis of sediment toxicity data focuses on statistical comparisons between responses in sediments from the study area and responses in one or more uncontaminated reference sediments. For large or complex study areas, a greater number of reference sediments is recommended to reliably define the normal range of responses in uncontaminated sediments – the ‘reference envelope’. Data on metal concentrations and effects on test organisms across a gradient of contamination may allow development of concentration-response models, which estimate metal concentrations associated with specified levels of toxic effects (e.g. 20% effect concentration or EC20). Comparisons of toxic effects in laboratory tests with measures of impacts on resident benthic invertebrate communities can help document causal relationships between metal contamination and biological effects. Total or total-recoverable metal concentrations in sediments are the most common measure of metal contamination in sediments, but metal concentrations in labile sediment fractions (e.g., determined as part of selective sediment extraction protocols) may better represent metal bioavailability. Metals released by the weak-acid extraction of acid-volatile sulfide (AVS), termed simultaneously-extracted metals (SEM), are widely used to estimate the ‘potentially-bioavailable’ fraction of metals that is not bound to sulfides (i.e., SEM-AVS). Metal concentrations in pore water are widely considered to be direct measures of metal bioavailability, and predictions of toxicity based on pore-water metal concentrations may be further improved by modeling interactions of metals with other pore-water constituents using Biotic Ligand Models. Data from sediment toxicity tests and metal analyses has provided the basis for development of sediment quality guidelines, which estimate thresholds for toxicity of metals in sediments. Empirical guidelines such as Probable Effects Concentrations or (PECs) are based on associations between sediment metal concentrations and occurrence of toxic effects in large datasets. PECs do not model bioavailable metals, but they can be used to estimate the toxicity of metal mixtures using by calculation of probable effect quotients (PEQ = sediment metal concentration/PEC). In contrast, mechanistic guidelines, such as Equilibrium Partitioning Sediment Benchmarks (ESBs) attempt to predict both bioavailability and mixture toxicity. Application of these simple bioavailability models requires more extensive chemical characterization of sediments or pore water, compared to empirical guidelines, but may provide more reliable estimates of metal toxicity across a wide range of sediment types.

Sediment Toxicity Identification Evaluation

EPA Science Inventory

Approach combining chemical manipulations and aquatic toxicity testing, generally with whole organisms, to systematically characterize, identify and confirm toxic substances causing toxicity in whole sediments and sediment interstitial waters. The approach is divided into thre...

Evaluation of field methods for vertical high resolution aquifer characterization

NASA Astrophysics Data System (ADS)

Vienken, T.; Tinter, M.; Rogiers, B.; Leven, C.; Dietrich, P.

2012-12-01

The delineation and characterization of subsurface (hydro)-stratigraphic structures is one of the challenging tasks of hydrogeological site investigations. The knowledge about the spatial distribution of soil specific properties and hydraulic conductivity (K) is the prerequisite for understanding flow and fluid transport processes. This is especially true for heterogeneous unconsolidated sedimentary deposits with a complex sedimentary architecture. One commonly used approach to investigate and characterize sediment heterogeneity is soil sampling and lab analyses, e.g. grain size distribution. Tests conducted on 108 samples show that calculation of K based on grain size distribution is not suitable for high resolution aquifer characterization of highly heterogeneous sediments due to sampling effects and large differences of calculated K values between applied formulas (Vienken & Dietrich 2011). Therefore, extensive tests were conducted at two test sites under different geological conditions to evaluate the performance of innovative Direct Push (DP) based approaches for the vertical high resolution determination of K. Different DP based sensor probes for the in-situ subsurface characterization based on electrical, hydraulic, and textural soil properties were used to obtain high resolution vertical profiles. The applied DP based tools proved to be a suitable and efficient alternative to traditional approaches. Despite resolution differences, all of the applied methods captured the main aquifer structure. Correlation of the DP based K estimates and proxies with DP based slug tests show that it is possible to describe the aquifer hydraulic structure on less than a meter scale by combining DP slug test data and continuous DP measurements. Even though correlations are site specific and appropriate DP tools must be chosen, DP is reliable and efficient alternative for characterizing even strongly heterogeneous sites with complex structured sedimentary aquifers (Vienken et al. 2012). References: Vienken, T., Leven, C., and Dietrich, P. 2012. Use of CPT and other direct push methods for (hydro-) stratigraphic aquifer characterization — a field study. Canadian Geotechnical Journal, 49(2): 197-206. Vienken, T., and Dietrich, P. 2011. Field evaluation of methods for determining hydraulic conductivity from grain size data. Journal of Hydrology, 400(1-2): 58-71.

The role of probabilistic formulations of sediment transport aimed at describing the behavior of soil-mantled hillslopes over geomorphic timescales (Invited)

NASA Astrophysics Data System (ADS)

Furbish, D. J.; Roering, J. J.

2013-12-01

Recent discussions of local versus nonlocal sediment transport on hillslopes offer a lens for considering uncertainty in formulations of transport rates that are aimed at characterizing patchy, intermittent sediment motions in steeplands. Here we describe a general formulation for transport that is based on a convolution integral of the factors controlling the entrainment and disentrainment of sediment particles on a hillslope. In essence, such a formulation represents a ';flux' version of the Master equation, a general probabilistic (kinematic) formulation of mass conservation. As such, with the relevant physics invoked to represent entrainment and disentrainment, a nonlocal formulation quite happily accommodates local transport (and looks/behaves like a local formulation), as well as nonlocal transport, depending on the characteristic length scale of particle motions relative to the length scale at which the factors controlling particle transport are defined or measured. Nonetheless, nonlocal formulations of the sediment flux have mostly (but not entirely) outpaced experimental and field-based observations needed to inform the theory. At risk is bringing to bear a sophisticated mathematics that is not supported by our uncertain understanding of the processes involved. Experimental and field-based measurements of entrainment rates and particle travel distances are difficult to obtain, notably given the intermittency of many hillslope transport processes and the slow rates of change in hillslope morphology. A ';test' of a specific nonlocal formulation applied to hillslope evolution must therefore in part rest on consistency between measured hillslope configurations and predicted (i.e., modeled) hillslope configurations predicated on the proposed nonlocal formulation, assuming sufficient knowledge of initial and boundary conditions. On the other hand, because of its probabilistic basis, the formulation is in principle well suited to the task of describing transport relevant to geomorphic timescales -- in view of the stochastic nature of the transport processes occurring over these timescales and the uncertainty of our understanding of the physics involved. Moreover, in its basic form, the nonlocal formulation of the sediment flux is such that appropriate physics can be readily embedded within it as we learn more. And, the formulation is space-time averaged in a way that accommodates discontinuous (patchy, intermittent) sediment motions.

PROJECTING THE RESPONSE OF FISH POPULATION GROWTH RATE TO SEDIMENT EXPOSURE

EPA Science Inventory

Sediment is one of the main stressors on stream fish populations in Georgia. Here, a quantitative approach relating sediment exposure to stream fish population dynamics is presented, where equations characterize sediment exposure to vital rates, then vital rates are used in a mat...

A TOXICITY IDENTIFICATION EVALUATION OF SILTY MARINE HARBOR SEDIMENTS TO CHARACTERIZE PERSISTENT AND NON-PERSISTENT CONSTITUENTS

EPA Science Inventory

Sediment toxicity in silty marine harbor sediments is frequently dominated by ammonia or sulfide, leaving the adverse effects of persistent toxic substances unnoticed. To investigate the latter, we subjected interstitial water from three contaminated silty sediments to toxicity i...

Improvement of a free software tool for the assessment of sediment connectivity

NASA Astrophysics Data System (ADS)

Crema, Stefano; Lanni, Cristiano; Goldin, Beatrice; Marchi, Lorenzo; Cavalli, Marco

2015-04-01

Sediment connectivity expresses the degree of linkage that controls sediment fluxes throughout landscape, in particular between sediment sources and downstream areas. The assessment of sediment connectivity becomes a key issue when dealing with risk mitigation and priorities of intervention in the territory. In this work, the authors report the improvements made to an open source and stand-alone application (SedInConnect, http://www.sedalp.eu/download/tools.shtml), along with extensive applications to alpine catchments. SedInConnect calculates a sediment connectivity index as expressed in Cavalli et al. (2013); the software improvements consisted primarily in the introduction of the sink feature, i.e. areas that act as traps for sediment produced upstream (e.g., lakes, sediment traps). Based on user-defined sinks, the software decouples those parts of the catchment that do not deliver sediment to a selected target of interest (e.g., fan apex, main drainage network). In this way the assessment of sediment connectivity is achieved by taking in consideration effective sediment contributing areas. Sediment connectivity analysis has been carried out on several catchments in the South Tyrol alpine area (Northern Italy) with the goal of achieving a fast and objective characterization of the topographic control on sediment transfer. In addition to depicting the variability of sediment connectivity inside each basin, the index of connectivity has proved to be a valuable indicator of the dominant process characterizing the basin sediment dynamics (debris flow, bedload, mixed behavior). The characterization of the dominant process is of great importance for the hazard and risk assessment in mountain areas, and for choice and design of structural and non-structural intervention measures. The recognition of the dominant sediment transport process by the index of connectivity is in agreement with evidences arising from post-event field surveys and with the application of morphometric indexes, such as the Melton ruggedness number, commonly used for discriminating debris-flow catchments from bedload catchments. References: Cavalli, M., Trevisani, S., Comiti, F., Marchi, L., 2013. Geomorphometric assessment of spatial sediment connectivity in small Alpine catchments. Geomorphology 188,31-41. doi:10.1016/j.geomorph.2012.05.007

USGS environmental characterization of flood sediments left in the New Orleans area after Hurricanes Katrina and Rita, 2005--Progress Report

USGS Publications Warehouse

Plumlee, Geoffrey S.; Meeker, Gregory P.; Lovelace, John K.; Rosenbauer, Robert J.; Lamothe, Paul J.; Furlong, Edward T.; Demas, Charles R.

2006-01-01

Introduction: The flooding in the greater New Orleans area that resulted from Hurricanes Katrina and Rita in September, 2005, left behind accumulations of sediments up to many centimeters thick on streets, lawns, parking lots, and other flat surfaces. These flood sediment deposits have been the focus of extensive study by the US Environmental Protection Agency (EPA) and Louisiana Department of Environmental Quality (LDEQ) due to concerns that the sediments may contain elevated levels of heavy metals, organic contaminants, and microbes. The U.S. Geological Survey (USGS) is characterizing a limited number of flood sediment samples that were collected on September 15-16 and October 6-7, 2005, from the greater New Orleans area by personnel from the USGS Louisiana Water Science Center in Baton Rouge. Small samples (< 3 pints each) of wet to dry flood sediment were collected from 11 localities around downtown New Orleans on September 15, 2005, and two large samples (40 pints each) of wet flood sediment were collected from the Chalmette area on September 16. Twelve additional samples (8-10 pints each) were collected from New Orleans, Slidell, Rigolets, and Violet on October 6 and 7. The USGS characterization studies of these flood sediments are designed to produce data and interpretations regarding how the sediments and any contained contaminants may respond to environmental processes. This information will be of use to cleanup managers and DoI/USGS scientists assessing environmental impacts of the hurricanes and subsequent cleanup activities.

Review on physical and chemical characterizations of contaminated sediments from urban stormwater infiltration basins within the framework of the French observatory for urban hydrology (SOERE URBIS).

PubMed

El-Mufleh, Amelène; Béchet, Béatrice; Ruban, Véronique; Legret, Michel; Clozel, Blandine; Barraud, Sylvie; Gonzalez-Merchan, Carolina; Bedell, Jean-Philippe; Delolme, Cécile

2014-04-01

Urban stormwater infiltration basins are designed to hold runoff from impervious surfaces and allow the settling of sediments and associated pollutants. However concerns have been expressed about the environmental impacts that may be exerted by the trapped pollutants on groundwater, soils and ecosystems. In this context, sediment characterization represents a key issue for local authorities in terms of management strategies. During the last two decades, several studies were launched including either physical or chemical characterization of stormwater sediments but without real synthesis of data and methods used. Consequently, there is an important need for reviewing the current experimental techniques devoted to the physico-chemical characterization of sediment. The review is based on the outcomes of two experimental sites for which long term monitoring and data collection have been done: the Cheviré basin (near Nantes) and the Django Reinhardt basin (near Lyon). The authors summarize the studies dealing with bulk properties, pollutant contents, their potential mobility and speciation. This paper aims at promoting the significant progresses that were made through a multidisciplinary approach involving multi-scaled and combined experimental techniques.

Flow Control and Design Assessment for Drainage System at McMurdo Station, Antarctica

DTIC Science & Technology

2014-11-24

Council BMP Best Management Practice CASQUA California Storm Water Quality Task Force CRREL Cold Regions Research and Engineering Laboratory DS...ponds The California Storm Water Quality Task Force (CASQUA 1993) defines a sediment basin as “a pond created by excavation or constructing an em...British Standards Institution. California Storm Water Quality Task Force (CASQUA). 1993. ESC41: Check Dams. In Stormwater Best Management Practices

TOXICITY CHARACTERIZATION PROCEDURES FOR ORGANIC TOXICANTS IN BULK SEDIMENTS

EPA Science Inventory

We have been pursuing development of toxicant characterization, isolation, and identification procedures for organic toxicants that can be applied in the context of 10-d solid-phase sediment tests measuring survival and growth of freshwater in the context of 10-d solid-phase sedi...

REDUCTIVE DEHALOGENATION OF HALOMETHANES IN IRON- AND SULFATE-REDUCING SEDIMENTS. 1. REACTIVITY PATTERN ANALYSIS

EPA Science Inventory

The incorporation of reductive transformations into environmental fate models requires the characterization of natural reductants in well-characterized sediments and aquifer materials. For this purpose, reactivity patterns (i.e., the range and relative order of reactivity) for a...

Characterization of Archaeological Sediments Using Fourier Transform Infrared (FT-IR) and Portable X-ray Fluorescence (pXRF): An Application to Formative Period Pyro-Industrial Sites in Pacific Coastal Southern Chiapas, Mexico.

PubMed

Neff, Hector; Bigney, Scott J; Sakai, Sachiko; Burger, Paul R; Garfin, Timothy; George, Richard G; Culleton, Brendan J; Kennett, Douglas J

2016-01-01

Archaeological sediments from mounds within the mangrove zone of far-southern Pacific coastal Chiapas, Mexico, are characterized in order to test the hypothesis that specialized pyro-technological activities of the region's prehistoric inhabitants (salt and ceramic production) created the accumulations visible today. Fourier transform infrared spectroscopy (FT-IR) is used to characterize sediment mineralogy, while portable X-ray fluorescence (pXRF) is used to determine elemental concentrations. Elemental characterization of natural sediments by both instrumental neutron activation analysis (INAA) and pXRF also contribute to understanding of processes that created the archaeological deposits. Radiocarbon dates combined with typological analysis of ceramics indicate that pyro-industrial activity in the mangrove zone peaked during the Late Formative and Terminal Formative periods, when population and monumental activity on the coastal plain and piedmont were also at their peaks. © The Author(s) 2015.

Borehole Tool for the Comprehensive Characterization of Hydrate-bearing Sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, Sheng; Santamarina, J. Carlos

Reservoir characterization and simulation require reliable parameters to anticipate hydrate deposits responses and production rates. The acquisition of the required fundamental properties currently relies on wireline logging, pressure core testing, and/or laboratory observations of synthesized specimens, which are challenged by testing capabilities and innate sampling disturbances. The project reviews hydrate-bearing sediments, properties, and inherent sampling effects, albeit lessen with the developments in pressure core technology, in order to develop robust correlations with index parameters. The resulting information is incorporated into a tool for optimal field characterization and parameter selection with uncertainty analyses. Ultimately, the project develops a borehole tool formore » the comprehensive characterization of hydrate-bearing sediments at in situ, with the design recognizing past developments and characterization experience and benefited from the inspiration of nature and sensor miniaturization.« less

Predicting lake responses to phosphorus loading with measurement-based characterization of P recycling in sediments

NASA Astrophysics Data System (ADS)

Katsev, S.; Li, J.

2017-12-01

Predicting the time scales on which lake ecosystems respond to changes in anthropogenic phosphorus loadings is critical for devising efficient management strategies and setting regulatory limits on loading. Internal loading of phosphorus from sediments, however, can significantly contribute to the lake P budget and may delay recovery from eutrophication. The efficiency of mineralization and recycling of settled P in bottom sediments, which is ultimately responsible for this loading, is often poorly known and is surprisingly poorly characterized in the societally important systems such as the Great Lakes. We show that a simple mass-balance model that uses only a minimum number of parameters, all of which are measurable, can successfully predict the time scales over which the total phosphorus (TP) content of lakes responds to changes in external loadings, in a range of situations. The model also predicts the eventual TP levels attained under stable loading conditions. We characterize the efficiency of P recycling in Lake Superior based on a detailed characterization of sediments at 13 locations that includes chemical extractions for P and Fe fractions and characterization of sediment-water exchange fluxes of P. Despite the low efficiency of P remobilization in these deeply oxygenated sediments (only 12% of deposited P is recycled), effluxes of dissolved phosphorus (2.5-7.0 μmol m-2 d-1) still contribute 37% to total P inputs into the water column. In this oligotrophic large lake, phosphate effluxes are regulated by organic sedimentation rather than sediment redox conditions. By adjusting the recycling efficiency to conditions in other Laurentian Great Lakes, we show that the model reproduces the historical data for total phosphorus levels. Analysis further suggests that, in the Lower Lakes, the rate of P sequestration from water column into sediments has undergone a significant change in recent decades, possibly in response to their invasion by quagga mussels. Importantly, even for lakes where P budgets are dominated by internal loading, mass balance arguments show that, over multi-year time scales, lakes should respond to changes in external P inputs faster than their hydrological residence times.

Ecological evaluation of proposed dredged material from St. Andrew Bay, Florida

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mayhew, H.L.; Word, J.Q.; Kohn, N.P.

1993-10-01

The US Army Corps of Engineers (USACE), Mobile District, requested that the Battelle/Marine Sciences Laboratory (MSL) conduct field sampling and chemical and biological testing to determine the suitability of potential dredged material for open ocean disposal. Sediment from St. Andrew Bay was chemically characterized and evaluated for biological toxicity and bioaccumulation of contaminants. The Tier III guidance for ocean disposal testing requires tests of water column effects (following dredged material disposal), deposited sediment toxicity, and bioaccumulation of contaminants from deposited sediment (dredged material). To meet these requirements, the MSL conducted suspended-particulate-phase (SPP) toxicity tests, solid-phase toxicity tests, and bioaccumulation testingmore » on sediment representing potential dredged material from Panama City Harbor. Physical and chemical characterization of sediment to support toxicity and bioaccumulation results was also conducted on both the test and reference sediments. The MSL collected sediment samples from five sites in St. Andrew Bay and one reference site near Lands End Peninsula. The five test sediments and the reference sediment were analyzed for physical and chemical sediment characteristics, SPP chemical contaminants, solid-phase toxicity, SPP toxicity, and bioaccumulation of contaminants.« less

Isolation and Physiological Characterization of Psychrophilic Denitrifying Bacteria from Permanently Cold Arctic Fjord Sediments (Svalbard, Norway)

NASA Technical Reports Server (NTRS)

Canion, Andy; Prakash, Om; Green, Stefan J.; Jahnke, Linda; Kuypers, Marcel M. M.; Kostka, Joel E.

2013-01-01

A large proportion of reactive nitrogen loss from polar sediments is mediated by denitrification, but microorganisms mediating denitrification in polar environments remain poorly characterized. A combined approach of most-probable-number (MPN) enumeration, cultivation and physiological characterization was used to describe psychrophilic denitrifying bacterial communities in sediments of three Arctic fjords in Svalbard (Norway). A MPN assay showed the presence of 10(sup 3)-10(sup 6) cells of psychrophilic nitrate-respiring bacteria g(sup -1) of sediment. Fifteen strains within the Proteobacteria were isolated using a systematic enrichment approach with organic acids as electron donors and nitrate as an electron acceptor. Isolates belonged to five genera, including Shewanella, Pseudomonas, Psychromonas (Gammaproteobacteria), Arcobacter (Epsilonproteobacteria) and Herminiimonas (Betaproteobacteria). All isolates were denitrifiers, except Shewanella, which exhibited the capacity for dissimilatory nitrate reduction to ammonium (DNRA). Growth from 0 to 40 degC demonstrated that all genera except Shewanella were psychrophiles with optimal growth below 15 degC, and adaptation to low temperature was demonstrated as a shift from primarily C16:0 saturated fatty acids to C16:1 monounsaturated fatty acids at lower temperatures. This study provides the first targeted enrichment and characterization of psychrophilic denitrifying bacteria from polar sediments, and two genera, Arcobacter and Herminiimonas, are isolated for the first time from permanently cold marine sediments.

Characterization of hydrodynamic and sediment conditions in the lower Yampa River at Deerlodge Park, east entrance to Dinosaur National Monument, northwest Colorado, 2011

USGS Publications Warehouse

Williams, Cory A.

2013-01-01

The Yampa River in northwestern Colorado is the largest, relatively unregulated river system in the upper Colorado River Basin. Water from the Yampa River Basin continues to be sought for a number of municipal, industrial, and energy uses. It is anticipated that future water development within the Yampa River Basin above the amount of water development identified under the Upper Colorado River Endangered Fish Recovery Implementation Program and the Programmatic Biological Opinion may require additional analysis in order to understand the effects on habitat and river function. Water development in the Yampa River Basin could alter the streamflow regime and, consequently, could lead to changes in the transport and storage of sediment in the Yampa River at Deerlodge Park. These changes could affect the physical form of the reach and may impact aquatic and riparian habitat in and downstream from Deerlodge Park. The U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board, began a study in 2011 to characterize the current hydrodynamic and sediment-transport conditions for a 2-kilometer reach of the Yampa River in Deerlodge Park. Characterization of channel conditions in the Deerlodge Park reach was completed through topographic surveying, grain-size analysis of streambed sediment, and characterization of streamflow properties. This characterization provides (1) a basis for comparisons of current stream functions (channel geometry, sediment transport, and stream hydraulics) to future conditions and (2) a dataset that can be used to assess channel response to streamflow alteration scenarios indicated from computer modeling of streamflow and sediment-transport conditions.

Characterization of flood sediments from Hurricanes Katrina and Rita and potential implications for human health and the environment: Chapter 7I in Science and the storms-the USGS response to the hurricanes of 2005

USGS Publications Warehouse

Plumlee, Geoffrey S.; Foreman, William T.; Griffin, Dale W.; Lovelace, John K.; Meeker, Gregory P.; Demas, Charles R.

2007-01-01

The flooding in the greater New Orleans, La., area that resulted from Hurricanes Katrina and Rita in August and September 2005 left behind accumulations of sediments up to many centimeters thick on streets, lawns, parking lots, and other flat surfaces (fig. 1). During the flood dewatering and subsequent cleanup, there were concerns that these sediments might contain pathogens and chemical contaminants that would pose a health risk to emergency responders, cleanup workers, and local residents who came into contact with the wet sediments or inhaled dusts generated from dried sediments. In response to these concerns, U.S. Geological Survey (USGS) scientists and colleagues characterized the potential environmental and health hazards of hurricane flood sediments from the greater New Orleans and Slidell, La., area.

Benthic habitat map of the U.S. Coral Reef Task Force Watershed Partnership Initiative Kā'anapali priority study area and the State of Hawai'i Kahekili Herbivore Fisheries Management Area, west-central Maui, Hawai'i

USGS Publications Warehouse

Cochran, Susan A.; Gibbs, Ann E.; White, Darla J.

2014-01-01

Nearshore areas off of west-central Maui, Hawai‘i, once dominated by abundant coral coverage, now are characterized by an increased abundance of turf algae and macroalgae. In an effort to improve the health and resilience of the coral reef system, the Kahekili Herbivore Fisheries Management Area was established by the State of Hawai‘i, and the U.S. Coral Reef Task Force selected the Kā‘anapali region as a priority study area. To support these efforts, the U.S. Geological survey mapped nearly 5 km2 of sea floor from the shoreline to water depths of about 30 m. Unconsolidated sediment (predominantly sand) constitutes 65 percent of the sea floor in the mapped area. Reef and other hardbottom potentially available for coral recruitments constitutes 35 percent of the mapped area. Of this potentially available hardbottom, only 51 percent is covered with a minimum of 10 percent coral, and most is found between 5 and 10 m water depth.

Erosion, sedimentation, and cumulative effects in the Northern Rocky Mountains

Treesearch

Walter F. Megahan; John G. King

2004-01-01

Erosion and sedimentation are natural geomorphic processes characterized by large temporal and spatial variability. Recent radionuclide studies suggest that rare episodic events, such as large wildfires, produce massive sediment yields over time scales of thousands of years, thereby causing long-term average sediment production to exceed present-day average erosion...

Metal concentrations in urban riparian sediments along an urbanization gradient

Treesearch

Daniel J. Bain; Ian D. Yesilonis; Richard V. Pouyat

2012-01-01

Urbanization impacts fluvial systems via a combination of changes in sediment chemistry and basin hydrology. While chemical changes in urban soils have been well characterized, similar surveys of riparian sediments in urbanized areas are rare. Metal concentrations were measured in sediments collected from riparian areas across the urbanization gradient in Baltimore, MD...

Characterizing and simulating sediment loads and transport in the lower part of the San Antonio River Basin

USGS Publications Warehouse

Banta, J. Ryan; Ockerman, Darwin J.; Crow, Cassi; Opsahl, Stephen P.

2015-01-01

This extended abstract is based on the U.S. Geological Survey Scientific Investigations Reports by Crow et al. (2013) and Banta and Ockerman (2014). Suspended sediment in rivers and streams can play an important role in ecological health of rivers and estuaries and consequently is an important issue for water-resource managers. The quantity and type of suspended sediment can affect the biological communities (Wood and Armitage, 1997), the concentration and movement of natural constituents and anthropogenic contaminants (Moran and others, 2012), and the amount of sediment deposition in coastal environments (Milliman and Meade, 1983). To better understand suspended-sediment characteristics in the San Antonio River Basin, the U.S. Geological Survey (USGS), in cooperation with the San Antonio River Authority and Texas Water Development Board, conducted a two-phase study to (1) collect and analyze sediment data to characterize sediment conditions in the San Antonio River downstream of San Antonio, Texas, and (2) develop and calibrate a watershed model to simulate hydrologic conditions and suspended-sediment loads for four watersheds in the San Antonio River Basin, downstream from San Antonio, Texas.

EFFECT OF REDOX ZONATION ON THE REDUCTIVE TRANSFORMATION OF P-CYANONITROBENZENE IN A LABORATORY SEDIMENT COLUMN

EPA Science Inventory

The reductive transformation of a model compound, p-cyanonitrobenzene (pCNB), was investigated in a laboratory sediment column that had been characterized with respect to redox zonation. Characterization of the redox zones was assessed by measurement of the solution phase concent...

Field Characterization of Potential Reference Sediments in the Gulf of Mexico: Chemical and Biological Quality

EPA Science Inventory

Lewis, Michael A., Jed G. Campbell, Peggy S. Harris, Darrin D. Dantin, Steve S. Foss, Robert L. Quarles, James C. Moore and Cynthia A. Chancy. Submitted. Characterization of Potential Reference Areas in the Gulf of Mexico: Near-Coastal Sediment Chemical and Biological Quality. En...

A geologic approach to field methods in fluvial geomorphology

USGS Publications Warehouse

Fitzpatrick, Faith A.; Thornbush, Mary J; Allen, Casey D; Fitzpatrick, Faith A.

2014-01-01

A geologic approach to field methods in fluvial geomorphology is useful for understanding causes and consequences of past, present, and possible future perturbations in river behavior and floodplain dynamics. Field methods include characterizing river planform and morphology changes and floodplain sedimentary sequences over long periods of time along a longitudinal river continuum. Techniques include topographic and bathymetric surveying of fluvial landforms in valley bottoms and describing floodplain sedimentary sequences through coring, trenching, and examining pits and exposures. Historical sediment budgets that include floodplain sedimentary records can characterize past and present sources and sinks of sediment along a longitudinal river continuum. Describing paleochannels and floodplain vertical accretion deposits, estimating long-term sedimentation rates, and constructing historical sediment budgets can assist in management of aquatic resources, habitat, sedimentation, and flooding issues.

Development of a toxicity identification evaluation procedure for characterizing metal toxicity in marine sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burgess, R.M.; Cantwell, M.G.; Pelletier, M.C.

2000-04-01

A multiagency effort is underway to develop whole sediment toxicity identification evaluation (TIE) methods. Whole sediment TIE methods will be critical tools for characterizing toxicity at hazardous waste sites and in the conduct of environmental risk assessments. The research approach is based on the predominance of three classes of toxicants in sediments: ammonia, nonpolar organic chemicals, and metals. Here the authors describe a procedure for characterizing acute toxicity caused by metals in whole marine sediments. The procedure involves adding a chelating resin to sediments, resulting in the sequestration of bioavailable metal while not stressing testing organisms. Within the testing chambers,more » the presence of resin resulted in statistically significant reductions in the overlying and interstitial water concentrations of five metals (cadmium, copper, nickel, lead, and zinc) generally by factors of 40 and 200. Toxicity to both the amphipod Ampelisca abdita and mysid Americamysis bahia (formerly Mysidopsis bahia) of sediments spiked with the five metals was decreased by approximately a factor of four when resin was present. While very effective at reducing the concentrations and toxicity of metals, the resin has only minor ameliorative effects on the toxicity of ammonia and a representative nonpolar toxicant (Endosulfan). Resin and accumulated metal were easily isolated from the testing system following exposures allowing for the initiation of phase II TIE (identification) procedures. This procedure using the addition of a chelating resin provides an approach for determining the importance of metals to the toxicity of marine sediments. Work is continuing to validate the method with environmentally contaminated sediments.« less

User's manual for the generalized computer program system. Open-channel flow and sedimentation, TABS-2. Main text

NASA Astrophysics Data System (ADS)

Thomas, W. A.; McAnally, W. H., Jr.

1985-07-01

TABS-2 is a generalized numerical modeling system for open-channel flows, sedimentation, and constituent transport. It consists of more than 40 computer programs to perform modeling and related tasks. The major modeling components--RMA-2V, STUDH, and RMA-4--calculate two-dimensional, depth-averaged flows, sedimentation, and dispersive transport, respectively. The other programs in the system perform digitizing, mesh generation, data management, graphical display, output analysis, and model interfacing tasks. Utilities include file management and automatic generation of computer job control instructions. TABS-2 has been applied to a variety of waterways, including rivers, estuaries, bays, and marshes. It is designed for use by engineers and scientists who may not have a rigorous computer background. Use of the various components is described in Appendices A-O. The bound version of the report does not include the appendices. A looseleaf form with Appendices A-O is distributed to system users.

MEASURING THE ACUTE TOXICITY OF ESTUARINE SEDIMENTS

EPA Science Inventory

Estuarine sediments frequently are repositories and sources of anthropogenic contaminants. Toxicity is one method of assessing the environmental quality of sediments, yet because of the extreme range of salinities that characterize estuaries few infaunal organisms have both the p...

DEVELOPMENT OF ECOLOGICAL TOOLS FOR CONTAMINATED SEDIMENTS

EPA Science Inventory

Contaminated sediments are of interest to a broad group of programs in the agency. OERR and the Regions are interested in monitoring contaminated sediments to characterize/assess existing conditions, determine remediation alternatives, track spatial and temporal changes, and dete...

Assessment of sediment quality in dredged and undredged areas of the Trenton Channel of the Detroit River, Michigan USA, using the sediment quality triad

USGS Publications Warehouse

Besser, John M.; Giesy, John P.; Kubitz, Jody A.; Verbrugge, David A.; Coon, Thomas G.; Braselton, W. Emmett

1996-01-01

The “sediment quality triad” approach was used to assess the effects of dredging on the sediment quality of a new marina in the Trenton Channel of the Detroit River, and to evaluate spatial and temporal variation in sediment quality in the Trenton Channel. Samples were collected in November of 1993 (10 months after dredging) and characterized by chemical analysis, sediment bioassays, and assessment of benthic invertebrate communities. The three study components indicated little difference in sediment quality at dredged sites in the marina relative to nearby areas in the Trenton Channel, and little change in sediment quality of Trenton Channel sites relative to conditions reported in the mid-1980s. These results suggest that improvement in sediment quality in the Trenton Channel, due to dredging or natural processes, will depend on elimination of sediment “hot spots” and other upstream contaminant sources. Concentrations of chemical contaminants, especially metals and polycyclic aromatic hydrocarbons, exceeded concentrations associated with effects on biota and were significantly correlated with results of sediment bioassays and characteristics of benthic communities. Laboratory sediment bioassays with Hyalella azteca andChironomus tentans produced better discrimination among sites with differing degrees of contamination than did characterization of benthic communities, which were dominated by oligochaetes at all sites in the marina and the Trenton Channel.

Broadband Scattering from Sand and Sand/Mud Sediments with Extensive Environmental Characterization

DTIC Science & Technology

2017-01-30

experiment , extensive envi- ronmental characterization was also performed to support data/model comparisons for both experimental efforts. The site...mechanisms, potentially addressing questions left unresolved from the previous sediment acoustics experiments , SAX99 and SAX04. This work was also to provide...environmental characterization to support the analysis of data collected during the Target and Reverberation Experiment in 2013 (TREX13) as well as

STRUCTURE AND FUNCTION OF SUBSURFACE MICROBIAL COMMUNITIES AFFECTING RADIONUCLIDE TRANSPORT AND BIOIMMOBILIZATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Joel E. Kostka; Lee Kerkhof; Kuk-Jeong Chin

2011-06-15

The objectives of this project were to: (1) isolate and characterize novel anaerobic prokaryotes from subsurface environments exposed to high levels of mixed contaminants (U(VI), nitrate, sulfate), (2) elucidate the diversity and distribution of metabolically active metal- and nitrate-reducing prokaryotes in subsurface sediments, and (3) determine the biotic and abiotic mechanisms linking electron transport processes (nitrate, Fe(III), and sulfate reduction) to radionuclide reduction and immobilization. Mechanisms of electron transport and U(VI) transformation were examined under near in situ conditions in sediment microcosms and in field investigations at the Oak Ridge Field Research Center (ORFRC), in Oak Ridge, Tennessee, where themore » subsurface is exposed to mixed contamination predominated by uranium and nitrate. A total of 20 publications (16 published or 'in press' and 4 in review), 10 invited talks, and 43 contributed seminars/ meeting presentations were completed during the past four years of the project. PI Kostka served on one proposal review panel each year for the U.S. DOE Office of Science during the four year project period. The PI leveraged funds from the state of Florida to purchase new instrumentation that aided the project. Support was also leveraged by the PI from the Joint Genome Institute in the form of two successful proposals for genome sequencing. Draft genomes are now available for two novel species isolated during our studies and 5 more genomes are in the pipeline. We effectively addressed each of the three project objectives and research highlights are provided. Task I - Isolation and characterization of novel anaerobes: (1) A wide range of pure cultures of metal-reducing bacteria, sulfate-reducing bacteria, and denitrifying bacteria (32 strains) were isolated from subsurface sediments of the Oak Ridge Field Research Center (ORFRC), where the subsurface is exposed to mixed contamination of uranium and nitrate. These isolates which are new to science all show high sequence identity to sequences retrieved from ORFRC subsurface. (2) Based on physiological and phylogenetic characterization, two new species of subsurface bacteria were described: the metal-reducer Geobacter daltonii, and the denitrifier Rhodanobacter denitrificans. (3) Strains isolated from the ORFRC show that Rhodanobacter species are well adapted to the contaminated subsurface. Strains 2APBS1 and 116-2 grow at high salt (3% NaCl), low pH (3.5) and tolerate high concentrations of nitrate (400mM) and nitrite (100mM). Strain 2APBS1 was demonstrated to grow at in situ acidic pHs down to 2.5. (4) R. denitrificans strain 2APBS1 is the first described Rhodanobacter species shown to denitrify. Nitrate is almost entirely converted to N2O, which may account for the large accumulation of N2O in the ORFRC subsurface. (5) G. daltonii, isolated from uranium- and hydrocarbon-contaminated subsurface sediments of the ORFRC, is the first organism from the subsurface clade of the genus Geobacter that is capable of growth on aromatic hydrocarbons. (6) High quality draft genome sequences and a complete eco-physiological description are completed for R. denitrificans strain 2APBS1 and G. daltonii strain FRC-32. (7) Given their demonstrated relevance to DOE remediation efforts and the availability of detailed genotypic/phenotypic characterization, Rhodanobacter denitrificans strain 2APBS1 and Geobacter daltonii strain FRC-32 represent ideal model organisms to provide a predictive understanding of subsurface microbial activity through metabolic modeling. Tasks II and III-Diversity and distribution of active anaerobes and Mechanisms linking electron transport and the fate of radionuclides: (1) Our study showed that members of genus Rhodanobacter and Geobacter are abundant and active in the uranium and nitrate contaminated subsurface. In the contaminant source zone of the Oak Ridge site, Rhodanobacter spp. are the predominant, active organisms detected (comprising 50% to 100% of rRNA detected). (2) We demonstrated for the first time that the function of microbial communities can be quantified in subsurface sediments using messenger RNA assays (molecular proxies) under in situ conditions. (3) Active Geobacteraceae were identified and phylogenetically characterized from the cDNA of messenger RNA extracted from ORFRC subsurface sediment cores. Multiple clone sequences were retrieved from G. uraniireducens, G. daltonii, and G. metallireducens. (4) Results show that Geobacter strain FRC-32 is capable of growth on benzoate, toluene and benzene as the electron donor, thereby providing evidence that this strain is physiologically distinct from other described members of the subsurface Geobacter clade. (5) Fe(III)-reducing bacteria transform structural Fe in clay minerals from their layer edges rather than from their basal surfaces.« less

Microscale geochemical gradients in Hanford 300 Area sediment biofilms and influence of uranium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nguyen, Hung D.; Cao, Bin; Mishra, Bhoopesh

2012-01-01

The presence and importance of microenvironments in the subsurface at contaminated sites were suggested by previous geochemical studies. However, no direct quantitative characterization of the geochemical microenvironments had been reported. We quantitatively characterized microscale geochemical gradients (dissolved oxygen (DO), H(2), pH, and redox potential) in Hanford 300A subsurface sediment biofilms. Our results revealed significant differences in geochemical parameters across the sediment biofilm/water interface in the presence and absence of U(VI) under oxic and anoxic conditions. While the pH was relatively constant within the sediment biofilm, the redox potential and the DO and H(2) concentrations were heterogeneous at the microscale (<500-1000more » μm). We found microenvironments with high DO levels (DO hotspots) when the sediment biofilm was exposed to U(VI). On the other hand, we found hotspots (high concentrations) of H(2) under anoxic conditions both in the presence and in the absence of U(VI). The presence of anoxic microenvironments inside the sediment biofilms suggests that U(VI) reduction proceeds under bulk oxic conditions. To test this, we operated our biofilm reactor under air-saturated conditions in the presence of U(VI) and characterized U speciation in the sediment biofilm. U L(III)-edge X-ray absorption spectroscopy (XANES and EXAFS) showed that 80-85% of the U was in the U(IV) valence state.« less

Microscale geochemical gradients in Hanford 300 Area sediment biofilms and influence of uranium.

PubMed

Nguyen, Hung Duc; Cao, Bin; Mishra, Bhoopesh; Boyanov, Maxim I; Kemner, Kenneth M; Fredrickson, Jim K; Beyenal, Haluk

2012-01-01

The presence and importance of microenvironments in the subsurface at contaminated sites were suggested by previous geochemical studies. However, no direct quantitative characterization of the geochemical microenvironments had been reported. We quantitatively characterized microscale geochemical gradients (dissolved oxygen (DO), H(2), pH, and redox potential) in Hanford 300A subsurface sediment biofilms. Our results revealed significant differences in geochemical parameters across the sediment biofilm/water interface in the presence and absence of U(VI) under oxic and anoxic conditions. While the pH was relatively constant within the sediment biofilm, the redox potential and the DO and H(2) concentrations were heterogeneous at the microscale (<500-1000 μm). We found microenvironments with high DO levels (DO hotspots) when the sediment biofilm was exposed to U(VI). On the other hand, we found hotspots (high concentrations) of H(2) under anoxic conditions both in the presence and in the absence of U(VI). The presence of anoxic microenvironments inside the sediment biofilms suggests that U(VI) reduction proceeds under bulk oxic conditions. To test this, we operated our biofilm reactor under air-saturated conditions in the presence of U(VI) and characterized U speciation in the sediment biofilm. U L(III)-edge X-ray absorption spectroscopy (XANES and EXAFS) showed that 80-85% of the U was in the U(IV) valence state. Copyright © 2011 Elsevier Ltd. All rights reserved.

Coupled geophysical characterization of shallow fluvio-clastic sediments in Agwagune, southeastern Nigeria

NASA Astrophysics Data System (ADS)

Akpan, Anthony E.; Ekwok, Stephen E.; Ebong, Ebong D.; George, Anthony M.; Okwueze, Emeka E.

2018-07-01

Geophysical investigation performed using electrical resistivity tomography (ERT), vertical electrical sounding (VES), seismic refraction (SRF) and ground penetrating radar (GPR) techniques were used to constrain and characterize shallow lithologic units in the Cross River bank (CRB) in southeastern Nigeria. Results show that the upper layer sediments comprise a 3-5-layered lithostratigraphic sequence with high clayey content. Around the Cross River bank (CRB), the top sediments consist of loose, silty and clayey sands with low resistivities (<150 Ωm) and low P-wave velocities (300-1000 m/s). These attenuating sediments have no reasonable continuity beyond the vicinity of the CRB. The low attenuating indurated silts/sands characterized by low resistivities (<25 Ωm) and high P-wave velocities (1000-2400 m/s) underlie the first layer around in the CRB. Localized microstructures (e.g., fractures) trending east-west, and saturated sand-filled channels truncate their lateral continuities. The lacustrine clays characterized by low resistivities (<15 Ωm) and high P-wave velocities (>2400 m/s) make up the third layer. The clayey sediments impede vertical percolation of groundwater forcing it to accumulate at the bottom of the second layer resulting in high static water levels of <3 m within the CRB and >5 m elsewhere. Hydraulic gradient in the Cross River bed (CRBD) and in the coastal groundwater drives groundwater flow into the CRBD through macropores. The sediments become unstable when these macropores become enlarged as more materials are continuously transmitted through them.

ENANTIOSELECTIVE MICROBIAL TRANSFORMATION OF THE PHENYLPYRAZOLE INSECTICIDE FIPRONIL IN ANOXIC SEDIMENTS

EPA Science Inventory

Fipronil, a chiral insecticide, was biotransformed initially to fipronil sulfide in anoxic sediment slurries following a short lag period. Sediment slurries characterized as either sulfidogenic or methanogenic transformed fipronil with half-lives of approximately 35 and 40 days, ...

Toxic Hazards Research Unit. Annual Technical Report. 1978

DTIC Science & Technology

1978-08-01

determinations made for the following battery of clinical tests: HCT Bilirubin RBC Glucose WBC Triglycerides HGB Iron Alkaline Sedimentation Phosphatase Rate ...Count WBC Hematocrit HCT Hemoglobin HGB Sedimentation Rate SEDI Reticulocytes RETIC MCORP Mean Corpuscular Volume MCV Mean Corpuscular Hemoglobin MCH...Contract F33615-76-C-5005 9. PERFORMING ORGANIZATION NAME AND ADDRESS 10. PPOGPAM ELEMENT, PROJECT , TASK University of California, Irvine APEA A WORK UNIT

NUTS and BOLTS: Applications of Fluorescence Detected Sedimentation

PubMed Central

Kroe, Rachel R.; Laue, Thomas M.

2008-01-01

Analytical ultracentrifugation is a widely used method for characterizing the solution behavior of macromolecules. However, the two commonly used detectors (absorbance and interference) impose some fundamental restrictions on the concentrations and complexity of the solutions that can be analyzed. The recent addition of a fluorescence detector for the XL-I analytical ultracentrifuge (AU-FDS) enables two different types of sedimentation experiments. First, the AU-FDS can detect picomolar concentrations of labeled solutes allowing the characterization of very dilute solutions of macromolecules, applications we call Normal Use Tracer Sedimentation (NUTS). The great sensitivity of NUTS analysis allows the characterization of small quantities of materials and high affinity interactions. Second, AU-FDS allows characterization of trace quantities of labeled molecules in solutions containing high concentrations and complex mixtures of unlabeled molecules, applications we call Biological On Line Tracer Sedimentation (BOLTS). The discrimination of BOLTS enables the size distribution of a labeled macromolecule to be determined in biological milieu such as cell lysates and serum. Examples are presented that embody features of both NUTS and BOLTS applications, along with our observations on these applications. PMID:19103145

CHARACTERIZATION AND ISOLATION OF ORGANIC TOXICANTS IN WHOLE SEDIMENT TOXICITY INDENTIFICATION EVALUATIONS (TIES)

EPA Science Inventory

Development of whole sediment toxicity identification and evaluation (TIEs) methods has been under way for approximately four years. These methods are necessary to define cause and effect relationships in toxic sediments during ecological risk assessments, remediation and disposa...

Nearshore sediment thickness, Fire Island, New York

USGS Publications Warehouse

Locker, Stanley D.; Miselis, Jennifer L.; Buster, Noreen A.; Hapke, Cheryl J.; Wadman, Heidi M.; McNinch, Jesse E.; Forde, Arnell S.; Stalk, Chelsea A.

2017-04-03

Investigations of coastal change at Fire Island, New York (N.Y.), sought to characterize sediment budgets and determine geologic framework controls on coastal processes. Nearshore sediment thickness is critical for assessing coastal system sediment availability, but it is largely unquantified due to the difficulty of conducting geological or geophysical surveys across the nearshore. This study used an amphibious vessel to acquire chirp subbottom profiles. These profiles were used to characterize nearshore geology and provide an assessment of nearshore sediment volume. Two resulting sediment-thickness maps are provided: total Holocene sediment thickness and the thickness of the active shoreface. The Holocene sediment section represents deposition above the maximum flooding surface that is related to the most recent marine transgression. The active shoreface section is the uppermost Holocene sediment, which is interpreted to represent the portion of the shoreface thought to contribute to present and future coastal behavior. The sediment distribution patterns correspond to previously defined zones of erosion, accretion, and stability along the island, demonstrating the importance of sediment availability in the coastal response to storms and seasonal variability. The eastern zone has a thin nearshore sediment thickness, except for an ebb-tidal deposit at the wilderness breach caused by Hurricane Sandy. Thicker sediment is found along a central zone that includes shoreface-attached sand ridges, which is consistent with a stable or accretional coastline in this area. The thickest overall Holocene section is found in the western zone of the study, where a thicker lower section of Holocene sediment appears related to the westward migration of Fire Island Inlet over several hundred years.

Screening-level risk assessment applied to dredging of polluted sediments from Guanabara Bay, Rio de Janeiro, Brazil.

PubMed

Silveira, Ana Elisa F; Nascimento, Juliana R; Sabadini-Santos, Elisamara; Bidone, Edison D

2017-05-15

Guanabara Bay is characterized by predominant eutrophication and anoxic sediments with a mixture of pollutants. The risk prognosis associated with the dumping of its dredged sediments into the open ocean was addressed by our algorithm. Our algorithm could prioritize areas, characterize major processes related to dredging, measure the potential risk of sediments, and predict the effects of sediment mixing. The estimated risk of dredged sediment was >10-fold than that of ocean sediments. Among metals, mercury represented 50-90% of the total risk. The transfer of dredged material into the ocean or internal dumping in the bay requires a 1:10 dilution to mitigate the risk and bring the risk levels close to that in the EPA criteria, below which there is less likelihood of adverse effects to the biota, and a 1:100 dilution to maintain the original characteristics of the ocean disposal control area. Our algorithm indicator can be used in the design of both aquatic and continental disposal of dredged materials and their management. Copyright © 2017. Published by Elsevier Ltd.

Geotechnical and Geoacoustic Investigation of Seafloor Sediments on Boston Harbor Approaches

DTIC Science & Technology

2017-01-25

Geoacoustic Investigation of Seafloor Sediments on Boston Harbor Approaches Andrei Abelev Marine Physics Branch Marine Geosciences Division Peter...LIMITATION OF ABSTRACT Geotechnical and Geoacoustic Investigation of Seafloor Sediments on Boston Harbor Approaches Andrei Abelev, Peter Herdic...sampling and analysis series for classification and characterization of the surficial seafloor sediment in the Boston Harbor approaches . 25-01-2017

Characterizing riverbed sediment using high-frequency acoustics 1: spectral properties of scattering

USGS Publications Warehouse

Buscombe, Daniel D.; Grams, Paul E.; Kaplinski, Matt A.

2014-01-01

Bed-sediment classification using high-frequency hydro-acoustic instruments is challenging when sediments are spatially heterogeneous, which is often the case in rivers. The use of acoustic backscatter to classify sediments is an attractive alternative to analysis of topography because it is potentially sensitive to grain-scale roughness. Here, a new method is presented which uses high-frequency acoustic backscatter from multibeam sonar to classify heterogeneous riverbed sediments by type (sand, gravel,rock) continuously in space and at small spatial resolution. In this, the first of a pair of papers that examine the scattering signatures from a heterogeneous riverbed, methods are presented to construct spatially explicit maps of spectral properties from geo-referenced point clouds of geometrically and radiometrically corrected echoes. Backscatter power spectra are computed to produce scale and amplitude metrics that collectively characterize the length scales of stochastic measures of riverbed scattering, termed ‘stochastic geometries’. Backscatter aggregated over small spatial scales have spectra that obey a power-law. This apparently self-affine behavior could instead arise from morphological- and grain-scale roughnesses over multiple overlapping scales, or riverbed scattering being transitional between Rayleigh and geometric regimes. Relationships exist between stochastic geometries of backscatter and areas of rough and smooth sediments. However, no one parameter can uniquely characterize a particular substrate, nor definitively separate the relative contributions of roughness and acoustic impedance (hardness). Combinations of spectral quantities do, however, have the potential to delineate riverbed sediment patchiness, in a data-driven approach comparing backscatter with bed-sediment observations (which is the subject of part two of this manuscript).

Morphodynamics and Sediment connectivity in the Kosi River basin in the Himalaya and their implications for river management

NASA Astrophysics Data System (ADS)

Sinha, R.; Mishra, K.; Swrankar, S.; Jain, V.; Nepal, S.; Uddin, K.

2017-12-01

Sediment flux of large tropical rivers is strongly influenced by the degree of linkage between the sediments sources and sink (i.e. sediment connectivity). Sediment connectivity, especially at the catchment scale, depends largely on the morphological characteristics of the catchment such as relief, terrain roughness, slope, elevation, stream network density and catchment shape and the combined effects of land use, particularly vegetation. Understanding the spatial distribution of sediment connectivity and its temporal evolution can be useful for the characterization of sediment source areas. Specifically, these areas represent sites of instability and their connectivity influences the probability of sediment transfer at a local scale that will propagate downstream through a feedback system. This paper evaluates the morphodynamics and sediment connectivity of the Kosi basin in Nepal and India at various spatial and temporal scales. Our results provide the first order assessment of the spatial sediment connectivity in terms of the channel connectivity (IC outlet) and source to channel connectivity (IC channel) of the upstream and midstream Kosi basin. This assessment helped in the characterization of sediment dynamics in the complex morphological settings and in a mixed environment. Further, Revised Universal Soil Loss Equation (RUSLE) was used to quantify soil erosion and sediment transport capacity equation is used to quantify sediment flux at each cell basis. Sediment Delivery Ratio (SDR) was calculated for each sub-basin to identify the sediment production and transport capacity limited sub-basin. We have then integrated all results to assess the sediment flux in the Kosi basin in relation to sediment connectivity and the factors controlling the pathways of sediment delivery. Results of this work have significant implications for sediment management of the Kosi river in terms of identification of hotspots of sediment accumulation that will in turn be manifested in morphodynamics of the river in the alluvial reaches.

Changes in northern Gulf of Mexico sediment bacterial and archaeal communities exposed to hypoxia

EPA Science Inventory

Biogeochemical changes in marine sediments during coastal water hypoxia are well described, but less is known about underlying changes in microbial communities. Bacterial and archaeal communities in Louisiana continental shelf (LCS) hypoxic zone sediments were characterized by py...

Characterization and evolution of the sediments of a Mediterranean coastal lagoon located next to a former mining area.

PubMed

García, Gregorio; Muñoz-Vera, Ana

2015-11-15

Coastal lagoons are ecosystems that are relatively enclosed water bodies under the influence of both the terrestrial and the marine environment, being vulnerable to human impacts. Human activities, such as mining extraction, are significant anthropogenic coastal stressors that can negatively affect ecosystems and communities. In light of the above, the objective of this research is to examine the influence of metal mining activities on the composition of sediments of a Mediterranean coastal lagoon, named Mar Menor. This paper presents a comprehensive characterization for grain size, mineralogy, geochemistry and organic matter of sediments of this coastal lagoon, investigating their variation along space and time. Sedimentation dynamics are ruling clearly the grain size predominant in each area of the Mar Menor coastal lagoon, determining the existence of entrainment, transport and sedimentation areas. For minerals, elements and organic matter, sedimentation dynamics are also determining their distribution. Copyright © 2015 Elsevier Ltd. All rights reserved.

Sedimentation Velocity Analysis of Large Oligomeric Chromatin Complexes Using Interference Detection.

PubMed

Rogge, Ryan A; Hansen, Jeffrey C

2015-01-01

Sedimentation velocity experiments measure the transport of molecules in solution under centrifugal force. Here, we describe a method for monitoring the sedimentation of very large biological molecular assemblies using the interference optical systems of the analytical ultracentrifuge. The mass, partial-specific volume, and shape of macromolecules in solution affect their sedimentation rates as reflected in the sedimentation coefficient. The sedimentation coefficient is obtained by measuring the solute concentration as a function of radial distance during centrifugation. Monitoring the concentration can be accomplished using interference optics, absorbance optics, or the fluorescence detection system, each with inherent advantages. The interference optical system captures data much faster than these other optical systems, allowing for sedimentation velocity analysis of extremely large macromolecular complexes that sediment rapidly at very low rotor speeds. Supramolecular oligomeric complexes produced by self-association of 12-mer chromatin fibers are used to illustrate the advantages of the interference optics. Using interference optics, we show that chromatin fibers self-associate at physiological divalent salt concentrations to form structures that sediment between 10,000 and 350,000S. The method for characterizing chromatin oligomers described in this chapter will be generally useful for characterization of any biological structures that are too large to be studied by the absorbance optical system. © 2015 Elsevier Inc. All rights reserved.

Characterization of water-quality and bed-sediment conditions in Currituck Sound, North Carolina, prior to the Mid-Currituck Bridge construction, 2011–15

USGS Publications Warehouse

Wagner, Chad R.; Fitzgerald, Sharon; Antolino, Dominick J.

2015-12-24

The characterization of water-quality and bed-sediment chemistry in Currituck Sound along the proposed alignment of the Mid-Currituck Bridge summarized herein provides a baseline for determining the effect of bridge construction and bridge deck runoff on environmental conditions in Currituck Sound.

Wave Attenuation on Muddy Bottoms Offshore Cassino Beach

DTIC Science & Technology

2006-10-01

D.Sc Principal Investigator Laboratory for the Dynamics of Cohesive Sediments Federal University of Rio de Janeiro Rio de Janeiro , Brazil...5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Federal University of Rio de Janeiro ,Laboratory for the...Dynamics of Cohesive Sediments, Rio de Janeiro , Brazil, 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES

Chemical characterization of sediment "Legacy P" in watershed streams - implications for P loading under land management

NASA Astrophysics Data System (ADS)

Audette, Yuki; O'Halloran, Ivan; Voroney, Paul

2016-04-01

Transfer of dissolved phosphorus (P) in runoff water via streams is regulated mainly by both stream sediment P adsorption and precipitation processes. The adsorption capacity of stream sediments acting as a P sink was a great benefit to preserving water quality in downstream lakes in the past, as it minimized the effects of surplus P loading from watershed streams. However, with long-term continued P loading the capacity of the sediments to store P has diminished, and eventually converted stream sediments from P sinks to sources of dissolved P. This accumulation of 'legacy P' in stream sediments has become the major source of dissolved P and risk to downstream water quality. Agricultural best management practices (BMP) for P typically attempt to minimize the transfer of P from farmland. However, because of the limitation in sediment P adsorption capacity, adoption of BMPs, such as reduction of external P loading, may not result in an immediate improvement in water quality. The goal of the research is to chemically characterize the P forms contributing to legacy P in stream sediments located in the watershed connecting to Cook's Bay, one of three basins of Lake Simcoe, Ontario, Canada. This watershed receives the largest amount of external P loading and has the highest rate of sediment build-up, both of which are attributed to agriculture. Water samples were collected monthly at six study sites from October 2015 for analysis of pH, temperature, dissolved oxygen, total P, dissolved reactive P, particulate P, total N, NH4-N, NO3-N, TOC and other elements including Al, Fe, Mn, Mg, Ca, S, Na, K and Zn. Sediment core samples were collected in November 2015 and will continue to be collected in March, July and October 2016. Various forms of P in five vertical sections were characterized by sequential fractionation and solution 31P NMR spectroscopy techniques. Pore water, sediment texture and clay identification were performed. The concentration of total P in water samples were ~equal or less than the Ontario Provincial Water Quality Objectives (PWQO) of 0.03 mg P L-1 except at a site located in the stream in the Holland Marsh, which was ~7 times greater. Forms and distribution of P varied with sediment section and sampling site. The range of total sediment-P was from ~0.8 to 2.5 g P kg-1 sediment, and at some sites the mobile P forms accounted for > 75% of the total sediment-P. The study will continue to examine the temporal spatial and vertical distribution of P forms to predict the rates of P release under varying water chemistries. This basic research provides a fundamental approach for characterization of the legacy P in stream sediments, ultimately providing a better understanding of the linkage between changes in agricultural management practices affecting P losses from terrestrial sources and observed changes in surface water quality.

PREDICTION OF CONTAMINATED SEDIMENT TRANSPORT IN THE MAURICE RIVER-UNION LAKE, NEW JERSEY, USA

EPA Science Inventory

This paper describes a sediment and contaminant transport model and its application to the Maurice River-Union Lake system in southern New Jersey, USA for the purpose of characterizing and forecasting sediment and arsenic distributions before and after proposed dredging activitie...

Conceptual Regional Sediment Budget for USACE North Atlantic Division

DTIC Science & Technology

2015-03-01

sediment budget is the first phase in development of the working budget and is intended to provide a general framework based on existing transport ...existing literature and databases were reviewed and analyzed to characterize sediment transport pathways and magnitudes, and morphologic zones of...net sediment transport pathways for Region 1 (includes NACCS planning regions VA1 through VA6 and MD2 through MD5

Characterizing Feedbacks Between Environmental Forcing and Sediment Characteristics in Fluvial and Coastal Systems

NASA Astrophysics Data System (ADS)

Feehan, S.; Ruggiero, P.; Hempel, L. A.; Anderson, D. L.; Cohn, N.

2016-12-01

Characterizing Feedbacks Between Environmental Forcing and Sediment Characteristics in Fluvial and Coastal Systems American Geophysical Union, 2016 Fall Meeting: San Francisco, CA Authors: Scott Feehan, Peter Ruggiero, Laura Hempel, and Dylan Anderson Linking transport processes and sediment characteristics within different environments along the source to sink continuum provides critical insight into the dominant feedbacks between grain size distributions and morphological evolution. This research is focused on evaluating differences in sediment size distributions across both fluvial and coastal environments in the U.S. Pacific Northwest. The Cascades' high relief is characterized by diverse flow regimes with high peak/flashy flows and sub-threshold flows occurring in relative proximity and one of the most energetic wave climates in the world. Combining analyses of both fluvial and coastal environments provides a broader understanding of the dominant forces driving differences between each system's grain size distributions, sediment transport processes, and resultant evolution. We consider sediment samples taken during a large-scale flume experiment that simulated floods representative of both high/flashy peak flows analogous to runoff dominated rivers and sub-threshold flows, analogous to spring-fed rivers. High discharge flows resulted in narrower grain size distributions while low flows where less skewed. Relative sediment size showed clear dependence on distance from source and the environments' dominant fluid motion. Grain size distributions and sediment transport rates were also quantified in both wave dominated nearshore and aeolian dominated backshore portions of Long Beach Peninsula, Washington during SEDEX2, the Sandbar-aEolian-Dune EXchange Experiment of summer 2016. The distributions showed spatial patterns in mean grain size, skewness, and kurtosis dependent on the dominant sediment transport process. The feedback between these grain size distributions and the predominant driver of sediment transport controls the potential for geomorphic change on societally relevant time scales in multiple settings.

Impacts of heterogeneous organic matter on phenanthrene sorption--Different soil and sediment samples

USGS Publications Warehouse

Karapanagioti, Hrissi K.; Childs, Jeffrey; Sabatini, David A.

2001-01-01

Organic petrography has been proposed as a tool for characterizing the heterogeneous organic matter present in soil and sediment samples. A new simplified method is proposed as a quantitative means of interpreting observed sorption behavior for phenanthrene and different soils and sediments based on their organic petrographical characterization. This method is tested under singe solute conditions and at phenanthrene concentration of 1 μg/L. Since the opaque organic matter fraction dominates the sorption process, we propose that by quantifying this fraction one can interpret organic content normalized sorption distribution coefficient (Koc) values for a sample. While this method was developed and tested for various samples within the same aquifer, in the current study the method is validated for soil and sediment samples from different sites that cover a wide range of organic matter origin, age, and organic content. All 10 soil and sediment samples studied had log Koc values for the opaque particles between 5.6 and 6.8. This range of Koc values illustrates the heterogeneity of opaque particles between sites and geological formations and thus the need to characterize the opaque fraction of materials on a site-by-site basis.

Identifying the causes of sediment-associated toxicity in urban waterways in South China: incorporating bioavailabillity-based measurements into whole-sediment toxicity identification evaluation.

PubMed

Yi, Xiaoyi; Li, Huizhen; Ma, Ping; You, Jing

2015-08-01

Sediments in urban waterways of Guangzhou, China, were contaminated by a variety of chemicals and showed prevalent toxicity to benthic organisms. A combination of whole-sediment toxicity identification evaluation (TIE) and bioavailability-based extraction was used to identify the causes of sediment toxicity. Of the 6 sediment samples collected, 4 caused 100% mortality to Chironomus dilutus in 10-d bioassays, and the potential toxicants were assessed using TIE in these sediments after dilution. The results of phase I characterization showed that organic contaminants were the principal contributors to the mortality of the midges in 2 sediments and that metals and organics jointly caused the mortality in the other 2 sediments. Ammonia played no role in the mortality for any samples. Conventional toxic unit analysis in phase II testing identified Cr, Cu, Ni, Pb, and Zn as the toxic metals, with cypermethrin, lambda-cyhalothrin, deltamethrin, and fipronils being the toxic organics. To improve the accuracy of identifying the toxicants, 4-step sequential extraction and Tenax extraction were conducted to analyze the bioavailability of the metals and organics, respectively. Bioavailable toxic unit analysis narrowed the list of toxic contributors, and the putative toxicants included 3 metals (Zn, Ni, and Pb) and 3 pesticides (cypermethrin, lambda-cyhalothrin, and fipronils). Metals contributed to the mortality in all sediments, but sediment dilution reduced the toxicity and confounded the characterization of toxicity contribution from metals in 2 sediments in phase I. Incorporating bioavailability-based measurements into whole-sediment TIE improved the accuracy of identifying the causative toxicants in urban waterways where multiple stressors occurred and contributed to sediment toxicity jointly. © 2015 SETAC.

Capturing Bioavailable Organic Contaminants for Phase II Whole Sediment Toxicity Identification Evaluations

EPA Science Inventory

In Phase I of whole sediment TIEs, causes of toxicity to freshwater and marine organisms are characterized into broad toxicant classes including ammonia, metals and organic chemicals. In the whole sediment Phase I TIEs performed so far, organic chemicals have been shown to be t...

PREDICTION OF CONTAMINATED SEDIMENT TRANSPORT IN THE MAURICE RIVER-UNION LAKE, NEW JERSEY, USA

EPA Science Inventory

A sediment and contaminant transport model and its application to the Maurice River-Union Lake system in southern New Jersey, USA is described. The application is meant to characterize and forecast sediment and arsenic (As) distributions before and after proposed dredging activit...

Integrating Uncertainty Analysis in the Risk Characterization of In-Place Remedial Strategies for Contaminated Sediments

DTIC Science & Technology

2009-03-01

sediment. The plastic limit for the samples tested averaged to 43.4 percent while the liquid limit was 77.7 percent. As discussed above, the sediment...sediment from the drums, clean it of debris such as plastic , clam shells, sticks, etc., mix to a density to be maintained consistently among all... pollutant loading to aquatic ecosystems has decreased in the past decades, contaminated sediments have shifted from a sink to a potential source of

Large shift in source of fine sediment in the upper Mississippi River

USGS Publications Warehouse

Belmont, P.; Gran, K.B.; Schottler, S.P.; Wilcock, P.R.; Day, S.S.; Jennings, C.; Lauer, J.W.; Viparelli, E.; Willenbring, J.K.; Engstrom, D.R.; Parker, G.

2011-01-01

Although sediment is a natural constituent of rivers, excess loading to rivers and streams is a leading cause of impairment and biodiversity loss. Remedial actions require identification of the sources and mechanisms of sediment supply. This task is complicated by the scale and complexity of large watersheds as well as changes in climate and land use that alter the drivers of sediment supply. Previous studies in Lake Pepin, a natural lake on the Mississippi River, indicate that sediment supply to the lake has increased 10-fold over the past 150 years. Herein we combine geochemical fingerprinting and a suite of geomorphic change detection techniques with a sediment mass balance for a tributary watershed to demonstrate that, although the sediment loading remains very large, the dominant source of sediment has shifted from agricultural soil erosion to accelerated erosion of stream banks and bluffs, driven by increased river discharge. Such hydrologic amplification of natural erosion processes calls for a new approach to watershed sediment modeling that explicitly accounts for channel and floodplain dynamics that amplify or dampen landscape processes. Further, this finding illustrates a new challenge in remediating nonpoint sediment pollution and indicates that management efforts must expand from soil erosion to factors contributing to increased water runoff. ?? 2011 American Chemical Society.

Characterizing Task-Based OpenMP Programs

PubMed Central

Muddukrishna, Ananya; Jonsson, Peter A.; Brorsson, Mats

2015-01-01

Programmers struggle to understand performance of task-based OpenMP programs since profiling tools only report thread-based performance. Performance tuning also requires task-based performance in order to balance per-task memory hierarchy utilization against exposed task parallelism. We provide a cost-effective method to extract detailed task-based performance information from OpenMP programs. We demonstrate the utility of our method by quickly diagnosing performance problems and characterizing exposed task parallelism and per-task instruction profiles of benchmarks in the widely-used Barcelona OpenMP Tasks Suite. Programmers can tune performance faster and understand performance tradeoffs more effectively than existing tools by using our method to characterize task-based performance. PMID:25860023

Watershed sediment measurement and sediment transport modeling techniques: Case study to quantify the impact of converting cropland to forested stream buffers on soil loss and water quality at the watershed scale

USDA-ARS?s Scientific Manuscript database

Watershed models such as the Soil and Water Assessment Tool (SWAT) have been widely used to simulate watershed hydrologic processes and the effect of management, such as agroforestry, on soil and water resources. In order to use model outputs for tasks ranging from aiding policy decision making to r...

Characterization, performance modeling, and design of an active capping remediation project in a heavily polluted urban channel.

PubMed

Yin, Ke; Viana, Priscilla; Zhao, Xiuhong; Rockne, Karl

2010-07-15

Collateral Channel is a heavily polluted former navigation slip to the Chicago Sanitary and Ship Canal (Illinois, USA). Characterization of sediment cores taken in the channel show high levels of heavy metals, polycyclic aromatic hydrocarbons (PAHs) and other contaminants in deposited sediment dating back to the 1800's. Of these, PAHs were the contaminants of greatest concern based upon exceedance of sediment contamination criteria (Sigma(16) PAHs up to 1500mg/kg). Benthic animal counts revealed a lack of biodiversity, with relatively low levels of small tubificid oligochaetes (generally <3000/m(2)) in surficial sediments. Comparison of surficial sediment contaminant levels between 1995 and 2005 showed few decreases in contaminant levels, indicating a lack of "natural recovery" processes occurring in the channel. These results led to an analysis of sediment amendments for an active capping demonstration project in the channel using transport models developed in our previous work (Viana et al., 2008). Based on the sediment characterization and modeling results, the active capping design will be focused on organic contaminant sequestration through the use of organoclay. A site-specific difficulty is the substantial rates of gas ebullition from anaerobic organic matter biodegradation in the sediments, particularly in the summer months. These gases can open advective channels that may result in substantial pollution release and compromise cap effectiveness, and thus the capping scenario must control for such releases. The active capping layer will underlay a sloped sand layer and a high permeability gas venting system to allow biogenically-produced gas migration to shoreline collectors through an innovative support grid. The cap will include an overlaying wetland to remove nutrients from the adjoining Chicago River and provide a public recreational space. Copyright 2010 Elsevier B.V. All rights reserved.

A multi-factor approach for process-based seabed characterization: example from the northeastern continental margin of the Korean peninsula (East Sea)

NASA Astrophysics Data System (ADS)

Cukur, Deniz; Um, In-Kwon; Chun, Jong-Hwa; Kim, So-Ra; Lee, Gwang-Soo; Kim, Yuri; Kong, Gee-Soo; Horozal, Senay; Kim, Seong-Pil

2018-04-01

This study investigates sediment transport and depositional processes from a newly collected dataset comprising sub-bottom chirp profiles, multibeam bathymetry, and sediment cores from the northeastern continental margin of Korea in the East Sea (Japan Sea). Twelve echo-types and eleven sedimentary facies have been defined and interpreted as deposits formed by shallow-marine, hemipelagic sedimentation, bottom current, and mass-movement processes. Hemipelagic sedimentation, which is acoustically characterized by undisturbed layered sediments, appears to have been the primary sedimentary process throughout the study area. The inner and outer continental shelf (<150 m water depth) have been influenced by shallow-marine sedimentary processes. Two slope-parallel canyons, 0.2-2 km wide and up to 30 km long, appear to have acted as possible conduits for turbidity currents from the shallower shelf into the deep basins. Bottom current deposits, expressed as erosional moats immediately below topographic highs, are prevalent on the southern lower slope at water depths of 400-450 m. Mass-movements (i.e., slides/slumps, debris flow deposits) consisting of chaotic facies characterize the lower slope and represent one of the most important sedimentary processes in the study area. Piston cores confirm the presence of mass-transport deposits (MTDs) that are characterized by mud clasts of variable size, shape, and color. Multibeam bathymetry shows that large-scale MTDs are chiefly initiated on the lower slope (400-600 m) with gradients up to 3° and where they produce scarps on the order of 100 m in height. Sandy MTDs also occur on the upper continental slope adjacent to the seaward edge of the shelf terrace. Earthquakes associated with tectonic activity and the development of fluid overpressure is considered as the main conditioning factor for destabilizing the slope sediments. Overall, the sedimentary processes show typical characteristics of a fine-grained clastic slope apron and change down-slope and differ within each physiographic province. Furthermore, the influence of geological inheritance (i.e., structural folds and faults) on geomorphology and sediment facies development is an important additional factor on the lower slopes. Together, these factors provide a rational basis for continental margin seabed characterization.

Molecular characterization of lake sediment WEON by Fourier transform ion cyclotron resonance mass spectrometry and its environmental implications.

PubMed

Zhang, Li; Wang, Shengrui; Xu, Yisheng; Shi, Quan; Zhao, Haichao; Jiang, Bin; Yang, Jiachun

2016-12-01

The compositional properties of water-extractable organic nitrogen (WEON) affect its behavior in lake ecosystems. This work is the first comprehensive study using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) for the characterization of the molecular composition of WEON in lake sediment. In sediments of Erhai Lake in China, this study found complex WEON species, with N-containing compounds in the northern, central, and southern regions contributing 34.47%, 42.44%, and 40.6%, respectively, of total compounds. Additionally, a van Krevelen diagram revealed that lignin components were dominant in sediment WEON structures (68% of the total), suggesting terrestrial sources. Furthermore, this study applied ESI-FT-ICR-MS to the examination of the environmental processes of lake sediment WEON on a molecular level. The results indicated that sediment depth impacted WEON composition and geochemical processes. Compared with other ecosystems, the double bond equivalent (DBE) value was apparently lower in Erhai sediment, indicating the presence of relatively fewer and smaller aromatic compounds. In addition, the presence of a large number of N-containing species and abundant oxidized nitrogen functional compounds that were likely to biodegrade may have further increased the potential releasing risk of WEON from Erhai sediment under certain environmental conditions. Copyright © 2016 Elsevier Ltd. All rights reserved.

Characterization of heavy-metal-contaminated sediment by using unsupervised multivariate techniques and health risk assessment.

PubMed

Wang, Yeuh-Bin; Liu, Chen-Wuing; Wang, Sheng-Wei

2015-03-01

This study characterized the sediment quality of the severely contaminated Erjen River in Taiwan by using multivariate analysis methods-including factor analysis (FA), self-organizing maps (SOMs), and positive matrix factorization (PMF)-and health risk assessment. The SOMs classified the dataset with similar heavy-metal-contaminated sediment into five groups. FA extracted three major factors-traditional electroplating and metal-surface processing factor, nontraditional heavy-metal-industry factor, and natural geological factor-which accounted for 80.8% of the variance. The SOMs and FA revealed the heavy-metal-contaminated-sediment hotspots in the middle and upper reaches of the major tributary in the dry season. The hazardous index value for health risk via ingestion was 0.302. PMF further qualified the source apportionment, indicating that traditional electroplating and metal-surface-processing industries comprised 47% of the health risk posed by heavy-metal-contaminated sediment. Contaminants discharged from traditional electroplating and metal-surface-processing industries in the middle and upper reaches of the major tributary must be eliminated first to improve the sediment quality in Erjen River. The proposed assessment framework for heavy-metal-contaminated sediment can be applied to contaminated-sediment river sites in other regions. Copyright © 2014 Elsevier Inc. All rights reserved.

Large-scale risk assessment of polycyclic aromatic hydrocarbons in shoreline sediments from Saudi Arabia: environmental legacy after twelve years of the Gulf war oil spill.

PubMed

Bejarano, Adriana C; Michel, Jacqueline

2010-05-01

A large-scale assessment of polycyclic aromatic hydrocarbons (PAHs) from the 1991 Gulf War oil spill was performed for 2002-2003 sediment samples (n = 1679) collected from habitats along the shoreline of Saudi Arabia. Benthic sediment toxicity was characterized using the Equilibrium Partitioning Sediment Benchmark Toxic Unit approach for 43 PAHs (ESBTU(FCV,43)). Samples were assigned to risk categories according to ESBTU(FCV,43) values: no-risk (< or = 1), low (>1 - < or = 2), low-medium (>2 - < or = 3), medium (>3 - < or = 5) and high-risk (>5). Sixty seven percent of samples had ESBTU(FCV,43) > 1 indicating potential adverse ecological effects. Sediments from the 0-30 cm layer from tidal flats, and the >30 - <60 cm layer from heavily oiled halophytes and mangroves had high frequency of high-risk samples. No-risk samples were characterized by chrysene enrichment and depletion of lighter molecular weight PAHs, while high-risk samples showed little oil weathering and PAH patterns similar to 1993 samples. North of Safaniya sediments were not likely to pose adverse ecological effects contrary to sediments south of Tanaqib. Landscape and geomorphology has played a role on the distribution and persistence in sediments of oil from the Gulf War. Copyright 2009 Elsevier Ltd. All rights reserved.

Sediment conditions in the San Antonio River Basin downstream from San Antonio, Texas, 2000-13

USGS Publications Warehouse

Ockerman, Darwin J.; Banta, J. Ryan; Crow, Cassi L.; Opsahl, Stephen P.

2015-01-01

Sediment plays an important role in the ecological health of rivers and estuaries and consequently is an important issue for water-resource managers. To better understand sediment characteristics in the San Antonio River Basin, the U.S. Geological Survey, in cooperation with the San Antonio River Authority, completed a two-part study in the San Antonio River Basin downstream from San Antonio, Texas, to (1) collect and analyze sediment data to characterize sediment conditions and (2) develop and calibrate a watershed model to simulate hydrologic conditions and suspended-sediment loads during 2000–12.

Spatiotemporal assessment (quarter century) of pulp mill metal(loid) contaminated sediment to inform remediation decisions.

PubMed

Hoffman, Emma; Lyons, James; Boxall, James; Robertson, Cam; Lake, Craig B; Walker, Tony R

2017-06-01

A bleached kraft pulp mill in Nova Scotia has discharged effluent wastewater into Boat Harbour, a former tidal estuary within Pictou Landing First Nation since 1967. Fifty years of effluent discharge into Boat Harbour has created >170,000 m 3 of unconsolidated sediment, impacted by inorganic and organic contaminants, including metal[loid]s, polycyclic aromatic hydrocarbons (PAHs), dioxins, and furans. This study aimed to characterize metal(loid)-impacted sediments to inform decisions for a $89 million CAD sediment remediation program. The remediation goals are to return this impacted aquatic site to pre-mill tidal conditions. To understand historical sediment characteristics, spatiotemporal variation covering ~quarter century, of metal(loid) sediment concentrations across 103 Boat Harbour samples from 81 stations and four reference locations, were assessed by reviewing secondary data from 1992 to 2015. Metal(loid) sediment concentrations were compared to current Canadian freshwater and marine sediment quality guidelines (SQGs). Seven metal(loid)s, As, Cd, Cr, Cu, Pb, Hg, and Zn, exceeded low effect freshwater and marine SQGs; six, As, Cd, Cr, Pb, Hg, and Zn, exceeded severe effect freshwater SQGs; and four, Cd, Cu, Hg, and Zn, exceeded severe effect marine SQGs. Metal(loid) concentrations varied widely across three distinct temporal periods. Significantly higher Cd, Cu, Pb, Hg, and Zn concentrations were measured between 1998 and 2000, compared to earlier, 1992-1996 and more recent 2003-2015 data. Most samples, 69%, were shallow (0-15 cm), leaving deeper horizons under-characterized. Geographic information system (GIS) techniques also revealed inadequate spatial coverage, presenting challenges for remedy decisions regarding vertical and horizontal delineation of contaminants. Review of historical monitoring data revealed that gaps still exist in our understanding of sediment characteristics in Boat Harbour, including spatial, vertical and horizontal, and temporal variation of sediment contamination. To help return Boat Harbour to a tidal estuary, more detailed sampling is required to better characterize these sediments and to establish appropriate reference (background) concentrations to help develop cost-effective remediation approaches for this decades-old problem.

Characterization of Natural Organic Matter in Alluvial Aquifer Sediments: Approaches and Implications for Reactivity

NASA Astrophysics Data System (ADS)

Fox, P. M.; Nico, P. S.; Hao, Z.; Gilbert, B.; Tfaily, M. M.; Devadoss, J.

2015-12-01

Sediment-associated natural organic matter (NOM) is an extremely complex assemblage of organic molecules with a wide range of sizes, functional groups, and structures, which is intricately associated with mineral particles. The chemical nature of NOM may control its' reactivity towards metals, minerals, enzymes, and bacteria. Organic carbon concentrations in subsurface sediments are typically much lower than in surface soils, posing a distinct challenge for characterization. In this study, we investigated NOM associated with shallow alluvial aquifer sediments in a floodplain of the Colorado River. Total organic carbon (TOC) contents in these subsurface sediments are typically around 0.1%, but can range from 0.03% up to approximately 1.5%. Even at the typical TOC values of 0.1%, the mass of sediment-associated OC is approximately 5000 times higher than the mass of dissolved OC, representing a large pool of carbon that may potentially be mobilized or degraded under changing environmental conditions. Sediment-associated OC is much older than both the depositional age of the alluvial sediments and dissolved OC in the groundwater, indicating that the vast majority of NOM was sequestered by the sediment long before it was deposited in the floodplain. We have characterized the sediment-bound NOM from two locations within the floodplain with differing physical and geochemical properties. One location has relatively low organic carbon (<0.2%) and is considered suboxic [dissolved oxygen is low or absent, but no dissolved Fe(II) observed], while the other is a naturally reducing zone with higher organic carbon (0.2-1.5%) and Fe(II)-reducing conditions. An extraction scheme was developed using a combination of sequential extraction [water and sodium pyrophosphate (pH 10)] and purification in order to isolate different fractions of sediment-associated NOM. Analysis of these different NOM fractions was then carried out by FTIR and ESI-FTICR-MS to allow for comparison of NOM structure and composition both across sites and across fractions for a single location. Using this combination of analytical techniques we can probe the variation in NOM chemical composition and mineral association across different biogeochemical regimes and assess the potential reactivity of various NOM pools.

Biological and chemical characterization of metal bioavailability in sediments from Lake Roosevelt, Columbia River, Washington, USA

USGS Publications Warehouse

Besser, J.M.; Brumbaugh, W.G.; Ivey, C.D.; Ingersoll, C.G.; Moran, P.W.

2008-01-01

We studied the bioavailability and toxicity of copper, zinc, arsenic, cadmium, and lead in sediments from Lake Roosevelt (LR), a reservoir on the Columbia River in Washington, USA that receives inputs of metals from an upstream smelter facility. We characterized chronic sediment toxicity, metal bioaccumulation, and metal concentrations in sediment and pore water from eight study sites: one site upstream in the Columbia River, six sites in the reservoir, and a reference site in an uncontaminated tributary. Total recoverable metal concentrations in LR sediments generally decreased from upstream to downstream in the study area, but sediments from two sites in the reservoir had metal concentrations much lower than adjacent reservoir sites and similar to the reference site, apparently due to erosion of uncontaminated bank soils. Concentrations of acid-volatile sulfide in LR sediments were too low to provide strong controls on metal bioavailability, and selective sediment extractions indicated that metals in most LR sediments were primarily associated with iron and manganese oxides. Oligochaetes (Lumbriculus variegatus) accumulated greatest concentrations of copper from the river sediment, and greatest concentrations of arsenic, cadmium, and lead from reservoir sediments. Chronic toxic effects on amphipods (Hyalella azteca; reduced survival) and midge larvae (Chironomus dilutus; reduced growth) in whole-sediment exposures were generally consistent with predictions of metal toxicity based on empirical and equilibrium partitioning-based sediment quality guidelines. Elevated metal concentrations in pore waters of some LR sediments suggested that metals released from iron and manganese oxides under anoxic conditions contributed to metal bioaccumulation and toxicity. Results of both chemical and biological assays indicate that metals in sediments from both riverine and reservoir habitats of Lake Roosevelt are available to benthic invertebrates. These findings will be used as part of an ongoing ecological risk assessment to determine remedial actions for contaminated sediments in Lake Roosevelt. ?? 2007 Springer Science+Business Media, LLC.

Sedimentation in mountain streams: A review of methods of measurement

USGS Publications Warehouse

Hedrick, Lara B.; Anderson, James T.; Welsh, Stuart A.; Lin, Lian-Shin

2013-01-01

The goal of this review paper is to provide a list of methods and devices used to measure sediment accumulation in wadeable streams dominated by cobble and gravel substrate. Quantitative measures of stream sedimentation are useful to monitor and study anthropogenic impacts on stream biota, and stream sedimentation is measurable with multiple sampling methods. Evaluation of sedimentation can be made by measuring the concentration of suspended sediment, or turbidity, and by determining the amount of deposited sediment, or sedimentation on the streambed. Measurements of deposited sediments are more time consuming and labor intensive than measurements of suspended sediments. Traditional techniques for characterizing sediment composition in streams include core sampling, the shovel method, visual estimation along transects, and sediment traps. This paper provides a comprehensive review of methodology, devices that can be used, and techniques for processing and analyzing samples collected to aid researchers in choosing study design and equipment.

BIOGEOCHEMICAL CONTROLS ON REACTION OF SEDIMENTARY ORGANIC MATTER AND AQUEOUS SULFIDES IN HOLOCENE SEDIMENTS OF MUD LAKE FLORIDA

EPA Science Inventory

The distribution and quantity of organic sulfur and iron sulfur species were determined in the
Holocene sediments from Mud Lake, Florida. The sediments of this shallow, sinkhole lake are characterized by high sulfur and organic carbon contents as well as active sulfate reducti...

Collection, processing, and interpretation of ground-penetrating radar data to determine sediment thickness at selected locations in Deep Creek Lake, Garrett County, Maryland, 2007

USGS Publications Warehouse

Banks, William S.L.; Johnson, Carole D.

2011-01-01

This investigation focused on selected regions of the study area, particularly in the coves where sediment accumulations were presumed to be thickest. GPR was the most useful tool for interpreting sediment thickness, especially in these shallow coves. The radar profiles were interpreted for two surfaces of interest-the water bottom, which was defined as the "2007 horizon," and the interface between Lake sediments and the original Lake bottom, which was defined as the "1925 horizon"-corresponding to the year the Lake was impounded. The ground-penetrating radar data were interpreted on the basis of characteristics of the reflectors. The sediments that had accumulated in the impounded Lake were characterized by laminated, parallel reflections, whereas the subsurface below the original Lake bottom was characterized by more discontinuous and chaotic reflections, often with diffractions indicating cobbles or boulders. The reflectors were picked manually along the water bottom and along the interface between the Lake sediments and the pre-Lake sediments. A simple graphic approach was used to convert traveltimes to depth through water and depth through saturated sediments using velocities of the soundwaves through the water and the saturated sediments. Nineteen cross sections were processed and interpreted in 9 coves around Deep Creek Lake, and the difference between the 2007 horizon and the 1925 horizon was examined. In most areas, GPR data indicate a layer of sediment between 1 and 7 feet thick. When multiple cross sections from a single cove were compared, the cross sections indicated that sediment thickness decreased toward the center of the Lake.

Multi-property characterization chamber for geophysical-hydrological investigations of hydrate bearing sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seol, Yongkoo, E-mail: Yongkoo.Seol@netl.doe.gov; Choi, Jeong-Hoon; Dai, Sheng

With the increase in the interest of producing natural gas from methane hydrates as well as potential risks of massive hydrate dissociation in the context of global warming, studies have recently shifted from pure hydrate crystals to hydrates in sediments. Such a research focus shift requires a series of innovative laboratory devices that are capable of investigating various properties of hydrate-bearing sediments (HBS). This study introduces a newly developed high pressure testing chamber, i.e., multi-property characterization chamber (MPCC), that allows simultaneous investigation of a series of fundamental properties of HBS, including small-strain stiffness (i.e., P- and S-waves), shear strength, large-strainmore » deformation, stress-volume responses, and permeability. The peripheral coolant circulation system of the MPCC permits stable and accurate temperature control, while the core holder body, made of aluminum, enables X-ray computer tomography scanning to be easily employed for structural and morphological characterization of specimens. Samples of hydrate-bearing sediments are held within a rubber sleeve inside the chamber. The thick sleeve is more durable and versatile than thin membranes while also being much softer than oedometer-type chambers that are incapable of enabling flow tests. Bias introduced by the rubber sleeve during large deformation tests are also calibrated both theoretically and experimentally. This system provides insight into full characterization of hydrate-bearing sediments in the laboratory, as well as pressure core technology in the field.« less

The effects of sediment and mercury mobilization in the South Yuba River and Humbug Creek Confluence Area, Nevada County, California: Concentrations, speciation, and environmental fate-Part 1: Field characterization

USGS Publications Warehouse

Fleck, Jacob A.; Alpers, Charles N.; Marvin-DiPasquale, Mark; Hothem, Roger L.; Wright, Scott A.; Ellett, Kevin; Beaulieu, Elizabeth; Agee, Jennifer L.; Kakouros, Evangelos; Kieu, Le H.; Eberl, Dennis D.; Blum, Alex E.; May, Jason T.

2011-01-01

Millions of pounds of mercury (Hg) were deposited in the river and stream channels of the Sierra Nevada from placer and hard-rock mining operations in the late 1800s and early 1900s. The resulting contaminated sediments are relatively harmless when buried and isolated from the overlying aquatic environment. The entrained Hg in the sediment constitutes a potential risk to human and ecosystem health should it be reintroduced to the actively cycling portion of the aquatic system, where it can become methylated and subsequently bioaccumulated in the food web. Each year, sediment is mobilized within these fluvial systems during high stormflows, transporting hundreds of tons of Hg-laden sediment downstream. The State of California and resource-management agencies, including the Bureau of Land Management (BLM) and the U.S. Forest Service, are concerned about additional disturbances, such as from suction gold dredging activities, which have the potential to mobilize Hg associated with buried sediment layers elevated in Hg that are otherwise likely to remain buried under normal storm conditions. The BLM initiated a study looking at the feasibility of removing Hg-contaminated sediment at the confluence of the South Yuba River and Humbug Creek in the northern Sierra Nevada of California by using standard suction-dredge technology. Additionally, the California State Water Resources Control Board (SWRCB) supported a comprehensive characterization of the intended dredge site. Together, the BLM and SWRCB supported a comprehensive characterization of Hg contamination at the site and the potential effects of sediment disturbance at locations with historical hydraulic mining debris on downstream environments. The comprehensive study consisted of two primary components: field studies and laboratory experiments. The field component, described in this report, had several study elements: 1) a preliminary, small-scale, in-stream dredge test; 2) comprehensive characterization of grain size distribution, Hg speciation, and mineralogy of bed and suspended sediment; 3) a determination of the past and current sources of sediment in the study area; 4) an assessment of Hg bioaccumulation in the local invertebrate population; and 5) a comparison of potential Hg transport caused 2 by natural storm disturbances with potential Hg mobilization caused by suction dredging as a method of Hg removal at the study site. The laboratory component of the study assessed the potential influenc of the disturbance of Hg-contaminated sediment through experiments designed to simulate in-stream transport, deposition, and potential methylation of Hg, described in a companion report (see Marvin-DiPasquale and others, 2010). Results of the field studies indicate that the fine-grained fraction (silt-clay, less than 0.063 millimeters) contains the greatest concentration of Hg in contaminated sediment. Because the fine-grained fraction is the most susceptible to long-range fluvial transport, disturbance of Hg-contaminated sediment is likely to increase the concentration and load of Hg in downstream waters. The preliminary, small-scale dredge test showed an increase in the concentration of fine particles and Hg in the water column caused by the dredge activity, despite relatively low concentrations of fine particles and Hg (about 300 nanograms per gram) at the dredge site. Characterization of sediment from two test pits and other sites in the vicinity of the confluence of the South Yuba River and Humbug Creek revealed a highly variable distribution of fine- and coarse-grained sediment. The highest levels of Hg contamination (up to 14,000 ng/g) were associated with the fine-grained fraction of sediment from the bedrock contact zone of Pit 2, a horizon which also yielded grains of gold and gold-Hg amalgam. A closed-circuit tank experiment with a venturi dredge at the base of Pit 1, in a gravel bar within the South Yuba River, resulted in fine-grained suspended sediment remaining in sus

Munitions and Explosives of Concern Survey Methodology and In-field Testing for Wind Energy Areas on the Atlantic Outer Continental Shelf

NASA Astrophysics Data System (ADS)

DuVal, C.; Carton, G.; Trembanis, A. C.; Edwards, M.; Miller, J. K.

2017-12-01

Munitions and explosives of concern (MEC) are present in U.S. waters as a result of past and ongoing live-fire testing and training, combat operations, and sea disposal. To identify MEC that may pose a risk to human safety during development of offshore wind facilities on the Atlantic Outer Continental Shelf (OCS), the Bureau of Ocean Energy Management (BOEM) is preparing to develop guidance on risk analysis and selection processes for methods and technologies to identify MEC in Wind Energy Areas (WEA). This study developed a process for selecting appropriate technologies and methodologies for MEC detection using a synthesis of historical research, physical site characterization, remote sensing technology review, and in-field trials. Personnel were tasked with seeding a portion of the Delaware WEA with munitions surrogates, while a second group of researchers not privy to the surrogate locations tested and optimized the selected methodology to find and identify the placed targets. This in-field trial, conducted in July 2016, emphasized the use of multiple sensors for MEC detection, and led to further guidance for future MEC detection efforts on the Atlantic OCS. An April 2017 follow on study determined the fate of the munitions surrogates after the Atlantic storm season had passed. Using regional hydrodynamic models and incorporating the recommendations from the 2016 field trial, the follow on study examined the fate of the MEC and compared the findings to existing research on munitions mobility, as well as models developed as part of the Office of Naval Research Mine-Burial Program. Focus was given to characterizing the influence of sediment type on surrogate munitions behavior and the influence of mophodynamics and object burial on MEC detection. Supporting Mine-Burial models, ripple bedforms were observed to impede surrogate scour and burial in coarse sediments, while surrogate burial was both predicted and observed in finer sediments. Further, incorporation of recommendations from the previous trial in the 2017 study led to fourfold improvement of MEC detection rates over the 2016 approach. The use of modeling to characterize local morphodynamics, MEC burial or mobility, and the impact of seasonal or episodic storm events are discussed in light of technology selection and timing for future MEC detection surveys.

Where on Earth can we find Mars? Characterization of an Aeolian Analogue in Northwestern Argentina

NASA Astrophysics Data System (ADS)

Favaro, E. A.; Hugenholtz, C.; Barchyn, T.

2017-12-01

The Puna Plateau of northwestern Argentina is as a promising analogue for Martian aeolian processes owing to its altitude, low atmospheric pressure, aridity, and widespread granular and bedrock aeolian features. The study was conducted in and surrounding the area known as the Campo de Piedra Pómez - a prominent expanse of wind-carved ignimbrite in Argentina's Catamarca Province. To interpret the evolution of this unique laboratory, which is limited by its isolated location and dearth of in situ measurements, we investigated contemporary aeolian sediment transport through a combination of modeled meteorological data, satellite imagery, field measurements, and sediment traps. Our objective is to utilize modeled meteorological data, satellite imagery, and field measurements and samples to characterize the aeolian environment here to base analogue studies. Satellite imagery from Terra MODIS, GeoEye, and Ikonos indicate recent large-scale aeolian sediment transport events and migration of gravel in the region. A prominent, region-wide sediment transport event on 14 August 2015 coincided with synoptic-scale pressure patterns indicating a strong Zonda (Foehn) winds. Sediment traps and marbles provide additional evidence of wind-driven transport of sand and gravel. Yet, despite the body of evidence for sediment transport on the Puna Plateau, modeled wind data from the European Center for Midrange Weather Forecasting suggest wind rarely attains the speeds necessary to initiate sediment transport. This disconnect is reminiscent of the Martian Saltation Paradox which suggested winds on Mars were incapable of mobilizing sediment, despite widespread evidence from rover, lander, and satellite observations. This raises questions about: (i) the suitability of modeled wind data for characterizing aeolian processes on both planets, and (ii) the possibility that most geomorphic work is conducted in extreme, but infrequent events in this region (possibly analogous to Mars). We suggest future research should attempt to reconcile disparities between sediment transport observations and modeled wind data.

Broadband Scattering from Sand and Sand/Mud Sediments with Extensive Environmental Characterization

DTIC Science & Technology

2015-09-30

1 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Broadband Scattering from Sand and Sand/ Mud Sediments...TERM GOALS To model the effects of volume heterogeneities, both discrete and continuous, in scattering from sand and mud sediments. A better...IMP2 has been used extensively during TREX13 and BayEx14 to measure the porosity in both sand and mud sediments. Analysis of this recent data inspired a

The Effects of Sediment Properties on Low Frequency Acoustic Propagation

DTIC Science & Technology

2014-09-30

identified in task (a). c. Understanding the effect of ocean acidification on acoustic propagation. The PIs (Miller and Potty) are trying to get funding...the half-space. The properties of the sediment used in the model calculation are shown in the top panel. b. Effect of Ocean Acidification on...Acoustic Propagation: One of the consequences of increasing atmospheric CO2 is ocean acidification . The reduction in pH is a direct result of increased

Infection-Associated Clinical Outcomes in Hospitalized Medical Evacuees After Traumatic Injury: Trauma Infectious Disease Outcome Study

DTIC Science & Technology

2011-07-01

tissue) or systemic inflammation (fever, leukocytes 12,000/L, elevated C-reactive protein, or elevated erythrocyte sedimentation rate ) or all...elevated erythrocyte sedimentation rate ). Joint/bursa infection Definite: organisms cultured from joint fluid/synovial biopsy or evidence of joint/bursa...McDonald J., Murray C. K., 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) United

Factors Effecting the Fate and Transport of CL-20 in the Vadose Zone and Groundwater

DTIC Science & Technology

2005-06-01

recently been investigated (Gamerdinger and Kaplan , 2000; Gamerdinger et al., 2001a, 2001b). This research has shown that changes in the water flow...expected to vary with sediment texture ( Kaplan et al. 1996; Gamerdinger et al. 1998). Research in this task will use sediments that are being used...steady-state unsaturated flow at water contents was selected for conducting transport experiments (Gamerdinger et al. 1998; Gamerdinger and Kaplan

State-shifting at the edge of resilience: River suspended sediment responses to land use change and extreme storms

NASA Astrophysics Data System (ADS)

Abbott, Samantha; Julian, Jason P.; Kamarinas, Ioannis; Meitzen, Kimberly M.; Fuller, Ian C.; McColl, Samuel T.; Dymond, John R.

2018-03-01

The interaction of climate, geomorphology, and land use dictates catchment sediment production and associated river sediment loads. Accordingly, the resilience of catchments to disturbances can be assessed with suspended sediment regimes. This case study in the hill country of the lower North Island of New Zealand was a decade-long examination of the short- and long-term effects of an extreme storm event on sediment supply and exhaustion in the Oroua and Pohangina catchments, two catchments that have experienced intense land use changes and frequent broad-scale landslides. Indicators of Hydrologic Alteration, a program developed to characterize hydrologic regimes, was used to analyze daily suspended sediment records over a period of a decade in order to characterize sediment regimes of the Oroua and Pohangina. An aggregated data set of sediment-bearing events for the period of record was analyzed to examine the suspended sediment response of individual storms relative to runoff magnitudes. The findings of this study demonstrate that large storms that generate extreme landsliding and flooding have the ability to produce enough sediment to temporarily convert catchments from a supply-limited state to a transport-limited state. Landsliding and thus sediment supply was disproportionately high in locations where livestock grazing occurred on steep hillslopes. The timing and intensity of previous storms, or the antecedent catchment condition, was also shown to influence the response of the catchments. In both catchments, suspended sediment loads were elevated for a period of 4 years following the landslide-generating February 2004 storm. The methods and findings we present are useful for assessing the resilience of catchments exposed to frequent disturbances such as land use changes and landslides.

Impact of bottom trawling on deep-sea sediment properties along the flanks of a submarine canyon.

PubMed

Martín, Jacobo; Puig, Pere; Masqué, Pere; Palanques, Albert; Sánchez-Gómez, Anabel

2014-01-01

The offshore displacement of commercial bottom trawling has raised concerns about the impact of this destructive fishing practice on the deep seafloor, which is in general characterized by lower resilience than shallow water regions. This study focuses on the flanks of La Fonera (or Palamós) submarine canyon in the Northwestern Mediterranean, where an intensive bottom trawl fishery has been active during several decades in the 400-800 m depth range. To explore the degree of alteration of surface sediments (0-50 cm depth) caused by this industrial activity, fishing grounds and control (untrawled) sites were sampled along the canyon flanks with an interface multicorer. Sediment cores were analyzed to obtain vertical profiles of sediment grain-size, dry bulk density, organic carbon content and concentration of the radionuclide 210Pb. At control sites, surface sediments presented sedimentological characteristics typical of slope depositional systems, including a topmost unit of unconsolidated and bioturbated material overlying sediments progressively compacted with depth, with consistently high 210Pb inventories and exponential decaying profiles of 210Pb concentrations. Sediment accumulation rates at these untrawled sites ranged from 0.3 to 1.0 cm y-1. Sediment properties at most trawled sites departed from control sites and the sampled cores were characterized by denser sediments with lower 210Pb surface concentrations and inventories that indicate widespread erosion of recent sediments caused by trawling gears. Other alterations of the physical sediment properties, including thorough mixing or grain-size sorting, as well as organic carbon impoverishment, were also visible at trawled sites. This work contributes to the growing realization of the capacity of bottom trawling to alter the physical properties of surface sediments and affect the seafloor integrity over large spatial scales of the deep-sea.

Impact of Bottom Trawling on Deep-Sea Sediment Properties along the Flanks of a Submarine Canyon

PubMed Central

Martín, Jacobo; Puig, Pere; Masqué, Pere; Palanques, Albert; Sánchez-Gómez, Anabel

2014-01-01

The offshore displacement of commercial bottom trawling has raised concerns about the impact of this destructive fishing practice on the deep seafloor, which is in general characterized by lower resilience than shallow water regions. This study focuses on the flanks of La Fonera (or Palamós) submarine canyon in the Northwestern Mediterranean, where an intensive bottom trawl fishery has been active during several decades in the 400–800 m depth range. To explore the degree of alteration of surface sediments (0–50 cm depth) caused by this industrial activity, fishing grounds and control (untrawled) sites were sampled along the canyon flanks with an interface multicorer. Sediment cores were analyzed to obtain vertical profiles of sediment grain-size, dry bulk density, organic carbon content and concentration of the radionuclide 210Pb. At control sites, surface sediments presented sedimentological characteristics typical of slope depositional systems, including a topmost unit of unconsolidated and bioturbated material overlying sediments progressively compacted with depth, with consistently high 210Pb inventories and exponential decaying profiles of 210Pb concentrations. Sediment accumulation rates at these untrawled sites ranged from 0.3 to 1.0 cm y−1. Sediment properties at most trawled sites departed from control sites and the sampled cores were characterized by denser sediments with lower 210Pb surface concentrations and inventories that indicate widespread erosion of recent sediments caused by trawling gears. Other alterations of the physical sediment properties, including thorough mixing or grain-size sorting, as well as organic carbon impoverishment, were also visible at trawled sites. This work contributes to the growing realization of the capacity of bottom trawling to alter the physical properties of surface sediments and affect the seafloor integrity over large spatial scales of the deep-sea. PMID:25111298

Deposition, Alteration, and Resuspension of Colorado River Delta Sediments, Lake Powell, Utah

NASA Astrophysics Data System (ADS)

Kramer, N. M.; Parnell, R.

2002-12-01

Current drought conditions in the southwest United States have resulted in lowering water levels in Lake Powell, Utah. Delta sediments forming at the Colorado River inflow for the past 39 years are becoming exposed and reworked as lake levels continue to fall to over 22 meters below full pool level. Fine sediments act as a sink for pollutants by adsorbing contaminants to their surfaces. Reworking these sediments may pose a risk to water quality in the lake. We examine whether burial and time have sufficiently altered fine sediments in the delta and affected materials adsorbed on their surfaces. Fifteen lake cores and six sediment traps were collected from the sediment delta forming at the Colorado River inflow in Lake Powell. This research characterizes fine sediment mineralogy, the composition of exchangeable materials, and organic matter content within delta sediments to determine the type and amount of alteration of these sediments with cycles of burial and resuspension. We hypothesize that as sediments are reworked, organic carbon is degraded and organic nitrogen is released forming ammonium in these reducing conditions. Sediment trap samples will be used to test this hypothesis. Trap samples will be compared to subsamples from sediment cores to determine the amount of alteration of fine sediments. All samples are analyzed for organic carbon, organic nitrogen, ammonium, cation exchange capacity, exchangeable cation composition, and clay mineralogy. Organic carbon and nitrogen are analyzed using a Leco CN analyzer. Ammonium is analyzed using a Lachet ion chromatograph. Clay mineralogy is characterized using a Siemens D500 powder X-ray diffractometer. Cation exchange capacity and exchangeable cations are measured using standard soil chemical techniques. Clay mineral analyses indicate significant spatial and temporal differences in fine sediment entering the Lake Powell delta which complicates the use of a simple deposition/alteration/resuspension model using a single starting material.

Protein associations and analytical ultracentrifugation

NASA Astrophysics Data System (ADS)

Laue, Tom

2010-03-01

Analytical ultracentrifugation (AUC) is a first principle method for characterizing the thermodynamics of macromolecules in solution. Since AUC directly assesses mass, it is particularly useful for characterizing both reversible and irreversible binding interactions between macromolecules. The principle measurement in AUC is the concentration as a function of radial position, which may be provided by either absorbance, interference or fluorescence detection. Each of these three different detectors may be used to characterize protein associations using either sedimentation equilibrium or sedimentation velocity analysis. Examples will be shown for characterizing irreversible (aggregate) formation, high-accuracy reversible association analysis, and the detection of protein interactions in complex and concentrated fluids (e.g. serum, cell cytosol).

Models, Tools, and Databases for Land and Waste Management Research

EPA Pesticide Factsheets

These publicly available resources can be used for such tasks as simulating biodegradation or remediation of contaminants such as hydrocarbons, measuring sediment accumulation at superfund sites, or assessing toxicity and risk.

Implication of seismic attenuation for gas hydrate resource characterization, Mallik, Mackenzie Delta, Canada

NASA Astrophysics Data System (ADS)

Bellefleur, G.; Riedel, M.; Brent, T.; Wright, F.; Dallimore, S. R.

2007-10-01

Wave attenuation is an important physical property of hydrate-bearing sediments that is rarely taken into account in site characterization with seismic data. We present a field example showing improved images of hydrate-bearing sediments on seismic data after compensation of attenuation effects. Compressional quality factors estimated from zero-offset Vertical Seismic Profiling data acquired at Mallik, Northwest Territories, Canada, demonstrate significant wave attenuation for hydrate-bearing sediments. These results are in agreement with previous attenuation estimates obtained from sonic logs and crosshole data at different frequency intervals. The application of an inverse Q-filter to compensate attenuation effects of permafrost and hydrate-bearing sediments improved the resolution of surface 3D seismic data and its correlation with log data, particularly for the shallowest gas hydrate interval. Compensation of the attenuation effects of the permafrost likely explains most of the improvements for the shallow gas hydrate zone. Our results show that characterization of the Mallik gas hydrates with seismic data not corrected for attenuation would tend to overestimate thicknesses and lateral extent of hydrate-bearing strata and hence, the volume of hydrates in place.

TMDL RUSLE MODEL

EPA Science Inventory

We developed a simplified spreadsheet modeling approach for characterizing and prioritizing sources of sediment loadings from watersheds in the United States. A simplified modeling approach was developed to evaluate sediment loadings from watersheds and selected land segments. ...

Declining sediment loads from Redwood Creek and the Klamath River, north coastal California

Treesearch

Randy D. Klein; Jeffrey K. Anderson

2012-01-01

River basin sediment loads are affected by several factors, with flood magnitude and watershed erosional stability playing dominant and dynamic roles. Long-term average sediment loads for northern California river basins have been computed by several researchers by several methods. However, characterizing the dynamic nature of climate and watershed stability requires...

Documentation of the U.S. Geological Survey Stress and Sediment Mobility Database

USGS Publications Warehouse

Dalyander, P. Soupy; Butman, Bradford; Sherwood, Christopher R.; Signell, Richard P.

2012-01-01

The U.S. Geological Survey Sea Floor Stress and Sediment Mobility Database contains estimates of bottom stress and sediment mobility for the U.S. continental shelf. This U.S. Geological Survey database provides information that is needed to characterize sea floor ecosystems and evaluate areas for human use. The estimates contained in the database are designed to spatially and seasonally resolve the general characteristics of bottom stress over the U.S. continental shelf and to estimate sea floor mobility by comparing critical stress thresholds based on observed sediment texture data to the modeled stress. This report describes the methods used to make the bottom stress and mobility estimates, statistics used to characterize stress and mobility, data validation procedures, and the metadata for each dataset and provides information on how to access the database online.

Present-day sedimentation rates and evolution since the last maximum flooding surface event in the Bay of Brest (W-N France)

NASA Astrophysics Data System (ADS)

Ehrhold, A.; Gregoire, G., Jr.; Sabine, S.; Jouet, G.; Le Roy, P., Sr.

2016-12-01

Despite its importance in term of human activities (military and commercial harbor, aquaculture farm, scallop dredging on maerl beds), there are only few studies of the sedimentation in the Bay of Brest. This coastal region, located at the western-most part of Brittany, is an original estuary system connected with the Atlantic Ocean by a narrow strait (the Goulet). Two rivers, Aulne in the South and Elorn in the North, discharge into the system by an undersea valley. 40 % of the bay concerns the shallow areas (depth < 10m) corresponding to a succession of small bights and were characterized by a superficial cover of muddy sediments colonized by maerl beds. These sediment deposits correspond to the late Holocene HST that constitutes the last sedimentary unit of 1 to 2 meter thick. With the support of the Brittany region and the LabexMer, this work aims to present the first large-scale investigation of the present-day sedimentation framework in the Bay of Brest and his evolution since few thousand years (3000-3500 B.P.). Interface and gravity cores were collected during SERABEQ cruises in 2014 and 2015. Sedimentation intensity was characterized on a century timescale using a multi-tracer approach (210Pb, 137Cs, 232Th) and AMS 14C measurements. Surface 210Pbxs activities are comprised between 30 and 64 mBq g-1, and excesses are detected at depth ranging between 5 and 25 cm, depending on the sites, testifying to large differences in sedimentation rates. The highest sedimentation intensities, up to 0.5 cm yr-1, are observed in the Elorn and Daoulas estuaries but are very low compared of other French atlantic coast estuaries. In the South-West sector of the Bay of Brest, in the Fret and Poulmic inlets, 210Pbxs-derived sediment rates are much lower, < 0.15 cm yr-1. Differences are mainly due to relative position of the studied cores regarding the sediment input, the local hydrodynamics factors (tidal currents and hydrology), but also the sedimentary cover characterization.

Fluid inclusion petrography and microthermometry of the Cocos Ridge hydrothermal system, IODP Expedition 344 (CRISP 2), Site U1414

NASA Astrophysics Data System (ADS)

Brandstätter, J.; Kurz, W.; Krenn, K.; Micheuz, P.

2015-12-01

We present new data from microthermometric analyses of fluid inclusions entrapped in hydrothermal veins within lithified sediments and Cocos Ridge (CCR) basalt from IODP Expedition 344 site U1414 (Costa Rica) and concern on a primary task of Expedition 344, i.e. to evaluate fluid/rock interaction, the hydrologic system, and the geochemical processes (indicated by composition and volume of fluids) active within the incoming Cocos Plate. Mineralization of the veins and crosscutting relationships gives constraints for the different generation of veins. Calcium carbonate, commonly aragonite in the upper part and calcite in the lower part of the igneous basement, is usually present in veins as a late phase following the quartz precipitation and the clay minerals formation. The sequence of vein generations in the lithified sediments close to the contact within the CCR basalt is characterized by smaller veins filled by quartz, followed by massive intersecting calcite veins. A high fluid pressure can be concluded, due to wall rock fragments embedded within the filling and fractured mineral grains in the ground mass, which are close to the veins. This requires that the magmatic basement and the lithified sediments were covered by sequences of low permeability sediments forming a barrier that enabled build up elevated fluid pressure. The investigation of fluid inclusions in the lowest units of borehole 344-U1414, give clues about the source of the fluids and about the vein evolution within the incoming Cocos Plate close to Middle American Trench. The microthermometric analyses of the primary, almost aqueous, inclusions indicate a temperature range during entrapment between 200 and 420°C. The data indicate that seawater within the Cocos Ridge aquifer communicated with high-temperature fluids and/or were modified by heat advection. We consider the Galapagos hotspot and/ or the Cocos-Nazca spreading center as heat source. Fluids originated from mobilized sediment pore water and invaded seawater. Isotope and heat flow data indicate a deep fluid source within the Cocos Plate oceanic crust too.

Characterization of methane hydrate host sediments using synchrotron-computed microtomography (CMT)

USGS Publications Warehouse

Jones, K.W.; Feng, H.; Tomov, S.; Winters, W.J.; Prodanovic, M.; Mahajan, D.

2007-01-01

The hydrate-sediment interaction is an important aspect of gas hydrate studies that needs further examination. We describe here the applicability of the computed microtomography (CMT) technique that utilizes an intense X-ray synchrotron source to characterize sediment samples, two at various depths from the Blake Ridge area (a well-known hydrate-prone region) and one from Georges Bank, that once contained methane trapped as hydrates. Detailed results of the tomographic analysis performed on the deepest sample (667??m) from Blake Ridge are presented as 2-D and 3-D images which show several mineral constituents, the internal grain/pore microstructure, and, following segmentation into pore and grain space, a visualization of the connecting pathways through the pore-space of the sediment. Various parameters obtained from the analysis of the CMT data are presented for all three sediment samples. The micro-scale porosity values showed decreasing trend with increasing depth for all three samples that is consistent with the previously reported bulk porosity data. The 3-D morphology, pore-space pathways, porosity, and permeability values are also reported for all three samples. The application of CMT is now being expanded to the laboratory-formed samples of hydrate in sediments as well as field samples of methane hydrate bearing sediments.

Time-integrated sampling of fluvial suspended sediment: a simple methodology for small catchments

NASA Astrophysics Data System (ADS)

Phillips, J. M.; Russell, M. A.; Walling, D. E.

2000-10-01

Fine-grained (<62·5 µm) suspended sediment transport is a key component of the geochemical flux in most fluvial systems. The highly episodic nature of suspended sediment transport imposes a significant constraint on the design of sampling strategies aimed at characterizing the biogeochemical properties of such sediment. A simple sediment sampler, utilizing ambient flow to induce sedimentation by settling, is described. The sampler can be deployed unattended in small streams to collect time-integrated suspended sediment samples. In laboratory tests involving chemically dispersed sediment, the sampler collected a maximum of 71% of the input sample mass. However, under natural conditions, the existence of composite particles or flocs can be expected to increase significantly the trapping efficiency. Field trials confirmed that the particle size composition and total carbon content of the sediment collected by the sampler were representative statistically of the ambient suspended sediment.

Application of sediment characteristics and transport conditions to resource management in selected main-stem reaches of the Upper Colorado River, Colorado and Utah, 1965-2007

USGS Publications Warehouse

Williams, Cory A.; Schaffrath, Keelin R.; Elliott, John G.; Richards, Rodney J.

2013-01-01

The Colorado River Basin provides habitat for 14 native fish, including 4 endangered species protected under the Federal Endangered Species Act of 1973. These endangered fish species once thrived in the Colorado River system, but water-resource development, including the building of numerous diversion dams and several large reservoirs, and the introduction of non-native fish, resulted in large reductions in the numbers and range of the four species through loss of habitat and stream function. Understanding how stream conditions and habitat change in response to alterations in streamflow is important for water administrators and wildlife managers and can be determined from an understanding of sediment transport. Characterization of the processes that are controlling sediment transport is an important first step in identifying flow regimes needed for restored channel morphology and the sustained recovery of endangered fishes within these river systems. The U.S. Geological Survey, in cooperation with the Upper Colorado River Endangered Fish Recovery Program, Bureau of Reclamation, U.S. Fish and Wildlife Service, Argonne National Laboratory, Western Area Power Administration, and Wyoming State Engineer’s Office, began a study in 2004 to characterize sediment transport at selected locations on the Colorado, Gunnison, and Green Rivers to begin addressing gaps in existing datasets and conceptual models of the river systems. This report identifies and characterizes the relation between streamflow (magnitude and timing) and sediment transport and presents the findings through discussions of (1) suspended-sediment transport, (2) incipient motion of streambed material, and (3) a case study of sediment-transport conditions for a reach of the Green River identified as a razorback sucker spawning habitat (See report for full abstract).

Bacterial community dynamic associated with autochthonous bioaugmentation for enhanced Cu phytoremediation of salt-marsh sediments.

PubMed

Almeida, C Marisa R; Oliveira, Tânia; Reis, Izabela; Gomes, Carlos R; Mucha, Ana P

2017-12-01

Autochthonous bioaugmentation for metal phytoremediation is still little explored, particularly its application to estuarine salt marshes, but results obtained so far are promising. Nevertheless, understanding the behaviour of the microbial communities in the process of bioaugmentation and their role in improving metal phytoremediation is very important to fully validate the application of this biological technology. This study aimed to characterize the bacterial community dynamic associated with the application of autochthonous bioaugmentation in an experimentation which showed that Phragmites australis rhizosphere microorganisms could increase this salt marsh plant potential to phytoremediate Cu contaminated sediments. Bacterial communities present in the autochthonous microbial consortium resistant to Cu added to the medium and in the sediment at the beginning and at the end of the experiment were characterized by ARISA. Complementarily, the consortium and the sediment used for its production were characterized by next generation sequencing using the pyrosequencing platform 454. The microbial consortium resistant to Cu obtained from non-vegetated sediment was dominated by the genus Lactococcus (46%), Raoultella (25%), Bacillus (12%) and Acinetobacter (11%), whereas the one obtained form rhizosediment was dominated by the genus Gluconacetobacter (77%), Bacillus (17%) and Dyella (3%). Results clearly showed that, after two months of experiment, Cu caused a shift in the bacterial community structure of sediments, an effect that was observed either with or without addition of the metal resistant microbial consortium. Therefore, bioaugmentation application improved the process of phytoremediation (metal translocation by the plant was increased) without inducing long term changes in the bacterial community structure of the sediments. So, phytoremediation combined with autochthonous bioaugmentation can be a suitable technology for the recovery of estuarine areas, contributing for an efficient risk management strategy of these coastal zones. Copyright © 2017. Published by Elsevier Ltd.

Distribution of surficial sediment in Long Island Sound and adjacent waters: Texture and total organic carbon

USGS Publications Warehouse

Poppe, L.J.; Knebel, H.J.; Mlodzinska, Z.J.; Hastings, M.E.; Seekins, B.A.

2000-01-01

The surficial sediment distribution within Long Island Sound has been mapped and described using bottom samples, photography, and sidescan sonar, combined with information from the geologic literature. The distributions of sediment type and total organic carbon (TOC) reveal several broad trends that are largely related to the sea-floor geology, the bathymetry, and the effects of modern tidal- and wind-driven currents. Sediment types are most heterogeneous in bathymetrically complex and shallow nearshore areas; the heterogeneity diminishes and the texture fines with decreasing bottom-current energy. Lag deposits of gravel and gravelly sand dominate the surficial sediment texture in areas where bottom currents are the strongest (such as where tidal flow is constricted) and where glacial till crops out at the sea floor. Sand is the dominant sediment type in areas characterized by active sediment transport and in shallow areas affected by fine-grained winnowing. Silty sand and sand-silt-clay mark transitions within the basin from higher- to lower-energy environments, suggesting a diminished hydraulic ability to sort and transport sediment. Clayey silt and silty clay are the dominant sediment types accumulating in the central and western basins and in other areas characterized by long-term depositional environments. The amount of TOC in the sediments of Long Island Sound varies inversely with sediment grain size. Concentrations average more than 1.9% (dry weight) in clayey silt, but are less than 0.4% in sand. Generally, values for TOC increase both toward the west in the Sound and from the shallow margins to the deeper parts of the basin floor. Our data also suggest that TOC concentrations can vary seasonally.

Characterization of the efficiency of sedimentation basins downstream of harvested peat bogs

NASA Astrophysics Data System (ADS)

Samson-Do, Myriam; St-Hilaire, André

2015-04-01

Peat harvesting is a very lucrative industry in the provinces of Quebec and New-Brunswick (Canada). Peat enters in many potting mix used for horticulture. However, harvesting this resource has some impacts on the environment. First, industries need to drain the peat bog to dry the superficial layer. Then, it is harvested with industrial vacuums and the underlying layer is allowed to dry. The drained water is laden with suspended sediments (mostly organic peat fibers) that may affect biota of the stream where it is discharged. To counter the problem, this water does not go directly on the stream but first flows through a sedimentation basin, built to reduce suspended sediment loads. This work focuses on characterizing and eventually modeling the efficiency of those sedimentation basins. Seven basins were studied in Rivière-du-Loup, St-Valère and Escoumins (Quebec, Canada). They each have a different ratio basin area/drained area (4.7 10-4 to 20.3 10-4). To continuously monitor the sediment loads (calculated from sediment concentrations and discharge) entering and leaving basins, a nephelometer and a level logger were installed in the water column upstream and downstream of sedimentation basins. Their trapping efficiency was measured during the ice-free period (May to October) and for each significant rain event, since it is known that the rain and subsequent runoff induce most of the peat transport in and out of the basin. Results show that the event efficiency decreases as the basin is filled up with trapped sediments. For one basin, the efficiency was 85August. Trapping efficiency can be used as a tool to estimate basin dimensions. This has been done for municipal sedimentation ponds that trap minerals and will be adapted to the current context, where the dominant sediment is organic.

Modeling Sediment Bypassing around Rocky Headlands

NASA Astrophysics Data System (ADS)

George, D. A.; Largier, J. L.; Pasternack, G. B.; Erikson, L. H.; Storlazzi, C. D.; Barnard, P.

2016-12-01

Sediment bypassing rocky headlands remains understudied despite the importance of characterizing littoral processes and sediment budgets for erosion abatement, climate change adaptation, and beach management. This study was developed to identify controlling factors on and the mechanisms supporting sediment bypassing. Sediment flux around four idealized rocky headlands was investigated using the hydrodynamic model Delft3D and spectral wave model SWAN. The experimental design involved 120 simulations to explore the influence of headland morphology, substrate composition, sediment grain size, and oceanographic forcing. Headlands represented sizes and shapes found in natural settings, grain sizes ranged from fine to medium sand, and substrates from sandy beds to offshore bedrock reefs. The oceanography included a constructed representative tide, an alongshore background current, and four wave conditions derived from observational records in the eastern Pacific Ocean. A bypassing ratio was developed for alongshore flux between upstream and downstream cross-shore transects to determine the degree of blockage by a headland. Results showed that northwesterly oblique large waves (Hs = 7 m, Tp = 16 s) generated the most flux around headlands, whereas directly incident waves blocked flux across a headland apex. The headland shape heavily influenced the sediment fate by changing the relative angle between the shoreline and the incident waves. The bypassing ratio characterized each headland's capacity to allow alongshore flux under different wave conditions. All headlands may allow flux, although larger ones block sediment more effectively, promoting their ability to be littoral cell boundaries compared to smaller headlands. The controlling factors on sediment bypassing were determined to be wave angle, shape and size of the headland, and sediment grain size. This novel numerical modeling study advances headland modeling from the generic realm to broadly applicable classes of headlands and encourages further investigation into the mechanics of sediment bypassing.

Sediment fingerprinting with long- and short-lived radionuclide tracers in the Root River watershed, southeastern Minnesota

NASA Astrophysics Data System (ADS)

Belmont, P.; Stout, J. C.

2015-12-01

The field of sediment fingerprinting has evolved rapidly over the past decade and is poised to improve our understanding not only of sediment sources, but also the routing of sediment through watersheds. Such information is essential for understanding and modeling human impacts on erosion and sediment routing at the watershed scale. In this study we use long- (Beryllium-10, 10Be) and short-lived (Lead-210 and Cesium-137, 210Pb and 137Cs, respectively) radionuclide tracers associated with suspended sediment to quantify sediment sources and channel-floodplain exchange across a range of watershed scales from 10 km2 to 4500 km2 in in the Root River, southeastern Minnesota, USA. The uppermost quarter of the Root River watershed was glaciated repeatedly during the late Pleistocene and is characterized by low relief agricultural fields and fine textured soils. The remainder of the watershed lies within the driftless area of the upper Midwestern US, which has not been glaciated in at least the past 500,000 years, and is characterized by karst topography, relatively steep hillslopes and bedrock channels that debouch into a wide, aggrading alluvial valley. The structure of the landscape exerts strong control on sediment generation and transport. Geochemical results indicate a highly variable erosion history, with significant variability of 10Be concentrations in source areas (agricultural fields, forested hillslopes, and alluvial floodplains and terraces) and inverted 10Be depth profiles (higher concentrations at depth) in floodplains, suggesting unsteady erosion and significant storage of legacy sediment. Concentrations of 10Be and 210Pb associated with suspended sediment show a systematic disparity in normalized concentrations, indicating that significant storage and re-suspension occurs in both systems as the sediment is routed through the channel-floodplain complex.

Energy Gradients Structure Microbial Communities Across Sediment Horizons in Deep Marine Sediments of the South China Sea

PubMed Central

Graw, Michael F.; D'Angelo, Grace; Borchers, Matthew; Thurber, Andrew R.; Johnson, Joel E.; Zhang, Chuanlun; Liu, Haodong; Colwell, Frederick S.

2018-01-01

The deep marine subsurface is a heterogeneous environment in which the assembly of microbial communities is thought to be controlled by a combination of organic matter deposition, electron acceptor availability, and sedimentology. However, the relative importance of these factors in structuring microbial communities in marine sediments remains unclear. The South China Sea (SCS) experiences significant variability in sedimentation across the basin and features discrete changes in sedimentology as a result of episodic deposition of turbidites and volcanic ashes within lithogenic clays and siliceous or calcareous ooze deposits throughout the basin's history. Deep subsurface microbial communities were recently sampled by the International Ocean Discovery Program (IODP) at three locations in the SCS with sedimentation rates of 5, 12, and 20 cm per thousand years. Here, we used Illumina sequencing of the 16S ribosomal RNA gene to characterize deep subsurface microbial communities from distinct sediment types at these sites. Communities across all sites were dominated by several poorly characterized taxa implicated in organic matter degradation, including Atribacteria, Dehalococcoidia, and Aerophobetes. Sulfate-reducing bacteria comprised only 4% of the community across sulfate-bearing sediments from multiple cores and did not change in abundance in sediments from the methanogenic zone at the site with the lowest sedimentation rate. Microbial communities were significantly structured by sediment age and the availability of sulfate as an electron acceptor in pore waters. However, microbial communities demonstrated no partitioning based on the sediment type they inhabited. These results indicate that microbial communities in the SCS are structured by the availability of electron donors and acceptors rather than sedimentological characteristics. PMID:29696012

T Cell Lipid Rafts and Complement Ligands for Diagnosis and Monitoring of SLE

DTIC Science & Technology

2011-05-01

including complete blood count, erythrocyte sedimentation rate , serum levels of C3 and C4, antinuclear autoantibodies (ANA), and anti-dsDNA level. Tests... sedimentation rate , serum levels of C3 and C4, antinuclear autoantibody (ANA) and anti-dsDNA antibody levels. In addition, each patient underwent history...6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER E-Mail: 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES

Quantifying Enhanced Microbial Dehalogenation Impacting the Fate and Transport of Organohalide Mixtures in Contaminated Sediments

DTIC Science & Technology

2012-02-01

supplying Anacostia River sediment, Dr. Matti Verta, Finnish Environment Institute, for providing Kymijoki River sediment, and the Meadowlands...dehalogenating activity; 2) Characterize the effect of sedimentary conditions on the ( bio )transformation rates of organohalide mixtures and their...the fate and transport of organohalide contaminants, co-amendments and ( bio )transformation products under various bioremediation scenarios. The

Characterization of quality of sediments from Paranaguá Bay (Brazil) by combined in vitro bioassays and chemical analyses.

PubMed

Rizzi, Juliane; Pérez-Albaladejo, Elisabet; Fernandes, Denise; Contreras, Javier; Froehner, Sandro; Porte, Cinta

2017-07-01

The present study characterizes the quality of sediments from the Paranaguá Estuarine Complex (South Brazil). Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs) were determined in sediment samples together with a series of different in vitro bioassays. The fish hepatoma cell line (PLHC-1) was used to determine the presence of cytotoxic compounds and CYP1A- and oxidative stress-inducing agents in sediment extracts. Ovarian microsomal fractions from sea bass (Dicentrarchus labrax) were used to detect the presence of endocrine disrupters that interfered with the synthesis of estrogens (ovarian CYP19). Despite the relatively low levels of pollutants and no evidence of negative effects based on guideline levels, sediments collected close to harbors were enriched with CYP1A-inducing agents and they showed higher cytotoxicity. In contrast, sediments from internal areas inhibited CYP19 activity, which suggests the presence of endocrine disrupters at these sites. Overall, the selected bioassays and the chemistry data led to the identification of potentially impacted areas along the Paranaguá Estuarine Complex that would require further action to improve their environmental quality. Environ Toxicol Chem 2017;36:1811-1819. © 2016 SETAC. © 2016 SETAC.

Freshwater Sediment Characterization Factors of Copper Oxide Nanoparticles

NASA Astrophysics Data System (ADS)

Pu, Yubing; Laratte, Bertrand; Ionescu, Rodica Elena

2017-01-01

Wide use of engineered nanoparticles (ENPs) is likely to result in the eventually accumulation of ENPs in sediment. The benthic organisms living in sediments may suffer relatively high toxic effects of ENPs. This study has selected copper oxide nanoparticles (nano-CuO) as a research object. To consider the impacts of spatial heterogeneity on ENPs toxicity, the characterization factor (CF) derived from life cycle assessment (LCA) methodology is used as an indicator in this study. A nano-specific fate model has been used to calculate the freshwater sediment fate factor (FF) of nano-CuO. A literature survey of the nano-CuO toxicology values has been performed to calculate the effect factor (EF). Seventeen freshwater sediment CFs of nano-CuO are proposed as recommended values for subcontinental regions. The region most likely to be affected by nano-CuO is northern Australia (CF of 21.01·103 CTUe, comparative toxic units) and the least likely is northern Europe and northern Canada (CF of 8.55·103 CTUe). These sediment CFs for nano-CuO could be used in the future when evaluating the ecosystem impacts of products containing nano-CuO by LCA method.

Develop Accurate Methods for Characterizing and Quantifying Cohesive Sediment Erosion Under Combined Current-Wave Conditions

DTIC Science & Technology

2017-09-01

ER D C/ CH L TR -1 7- 15 Strategic Environmental Research and Development Program Develop Accurate Methods for Characterizing and...current environments. This research will provide more accurate methods for assessing contaminated sediment stability for many DoD and Environmental...47.88026 pascals yards 0.9144 meters ERDC/CHL TR-17-15 xi Executive Summary Objective The proposed research goal is to develop laboratory methods

Characterization of Contaminant Migration Potential Through In-Place Sediment Caps

DTIC Science & Technology

2011-06-01

Miracle-Gro Lawn Products , Inc. (Marysville, OH). The peat moss was ground and sieved to 63-1000 µm before being used as an organic carbon...in the sediment. In the absence of a sorbent organic matter phase, the PAH mixture may be present as a separate oil phase that coats the sediment...for PAHs entrapped in the organic carbon of soil and sediment pores (Pignatello, J.J, 1990 and 1995; Schuth, Ch. and Grothwahl, P. et al. 1994; Ran

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gustavson, T.C.; Holliday, V.T.

Eolian sediments have accumulated as non-glacigenic loess and thin sand sheets on the Central and Southern High Plains grasslands of Texas and new mexico since the late Miocene. Locally as much as 110 m of eolian sediments with numerous paleosols are preserved in the Quaternary Blackwater Draw formation and the upper part of the Miocene-Pleiocene Ogallala formation. These sediments and paleosols, which cover more than 130,000 km{sup 2}, are similar to recent surface sediments and soils and record a long period of episodic eolian transport and sedimentation, and pedogenesis on a stable low-relief grass-covered landscape. Eolian sections, which comprise themore » fine sand to coarse silt lithofacies of the Ogallala formation, and the very fine to fine sand and sandy mud lithofacies of the Blackwater Draw formation, generally lack primary sedimentary structures. Grain size of Ogallala sediments decreases from west to east and grain size of Blackwater Draw sediments decreases from southwest to northeast. Soil horizonation is well developed in most sections, and buried calcic and argillic horizons are common. Calcic horizons are characterized by sharply increased CaCO{sub 3} content in the form of filaments, nodules, and petrocalcic horizons (calcretes). Argillic horizons are characterized by increased illuvial clay, pedogenic structure, and darker reddish hues. Rhizocretions are common locally. Open root tubules, which are typically less than 1 mm in diameter and characteristic of small plants like grasses, are present in all Ogallala and Blackwater Draw eolian sediments. Paleosols preserved in eolian sediments of the High Plains reflect periods of sedimentation followed by episodes of landscape stability and pedogenesis, and negligible sedimentation. Episodes of sedimentation and soil development likely resulted from cyclic decreases and increases in available moisture and vegetative cover. Eolian sediments were eroded and transported eastward during dry periods when vegetation was sparse in source areas, such as the western High Plains and the Pecos Valley. During humid periods more abundant vegetation probably protected source areas from deflation, and resulted in landscape stability across the High Plains.« less

The Effect of Low Energy Turbulence in Estuary Margins on Fine Sediment Settling

NASA Astrophysics Data System (ADS)

Allen, R. M.; MacVean, L. J.; Tse, I.; Mazzaro, L. J.; Stacey, M. T.; Variano, E. A.

2014-12-01

Sediment dynamics in estuaries and near shore regions control the growth or erosion of the bed and fringing wetlands, determine the spread of sediment-associated contaminants, and limit the light availability for primary productivity through turbidity. In estuaries such as San Francisco Bay, this sediment is often cohesive, and can flocculate. Changes to the composition of the sediment and waters, the suspended sediment concentration, and the turbulence can all affect the flocculation of suspended sediment. In turn, flocculation controls the particle diameter, settling velocity, density, and particle inertia. These sediment properties drive the turbulent diffusivity, which balances with the settling velocity to impact the vertical distribution of sediment in the water column. The vertical profile strongly affects how sediment is transported through the estuary by lateral flow. Turbulence may also impact settling velocity in non-cohesive particles. In turbulence, dense particles may get trapped in convergent flow regions, thus particles are more likely to get swept along the downward side of a turbulent eddy than the upward side, resulting in enhanced settling velocities. We isolated the impacts of turbulence level, particle size and type, and suspended sediment concentration on particle settling velocities using uniform grain size particles in homogeneous isotropic turbulence. Controlling the turbulence in a well-defined turbulence tank, we used Two Acoustic Doppler Velocimeters, separated vertically, to measure turbulent velocities (w') and suspended sediment concentrations (C), which yield condition dependent settling velocities (ws), via equation 1. Lab characterization of particle settling velocities help to validate the method for measuring settling velocities in the field, and will serve as a foundation for an extensive field experiment in San Francisco Bay. Characterizing the velocity enhancement relative to the Stokes number, the Rouse number, and the turbulent Reynolds number will enable more mechanistic predictions of sediment transport in low energy environments like protected estuary margins.

Organic matter in sediments of an acidic mining lake as assessed by lipid analysis. Part I: fatty acids.

PubMed

Poerschmann, Juergen; Koschorreck, Matthias; Górecki, Tadeusz

2012-01-01

Fatty acid (FA) patterns of sediments collected from the bottom of an acidic mine pit lake (AML) at different depths (surface sediment: 0 to 1cm; deep sediment: 4 to 5 cm) were studied to characterize microbial communities and the sources of sedimentary organic matter (SOM). Studies were performed on the molecular level utilizing source-specific, diagnostic FA biomarkers. The biomarker-based approach has been used widely in marine sediment studies, but has not been applied for sediments from AMLs so far. Combined FA concentrations in the surface sediment were higher compared to those in the deep sediment (497 vs. 127 μg g(-1)d.w., respectively). This was related to deposition of autochthonous biomass and higher terrestrial plants onto the surface sediment, as well as--to lesser extent--with higher bacterial activity on the sediment-water interface. The FA distribution in both sediments was characterized by a strong even-over-odd preference and was bimodal in nature: there was a cluster at nC(14)-nC(18) characteristic of chiefly autochthonous (algal and bacterial) SOM production, and another cluster at nC(22-28) related to input from higher plants. The FA distribution in the surface sediment pointed to higher terrestrial input compared to autochthonous contribution to SOM (67%:33%) as an estimate. Fingerprinting of viable bacteria was accomplished through signature FA markers including branched C(15) and C(17) surrogates, cyclopropanoic acids, 3-hydroxy (OH) acids and monounsaturated surrogates with unusual double bond localization. The abundance of Gram-negative bacteria was higher in the surface sediment as evidenced by total diagnostic 3-OH-fatty acids (37 μg g(-1) versus 25 μg g(-1)). Potential source taxa in both sediment layers included acidophilic iron- and sulfur-oxidizing bacteria including Acidithiobacillus ferrooxidans. High abundances of terminally branched C(15) and C(17) surrogates in both sediments pointed to sulfate- and iron-reducing bacteria. Signature FAs characteristic of methanotrophs were virtually lacking in both sediments. Copyright © 2011 Elsevier B.V. All rights reserved.

Spatial characterization of riparian buffer effects on sediment loads from watershed systems.

PubMed

Momm, Henrique G; Bingner, Ronald L; Yuan, Yongping; Locke, Martin A; Wells, Robert R

2014-09-01

Understanding all watershed systems and their interactions is a complex, but critical, undertaking when developing practices designed to reduce topsoil loss and chemical/nutrient transport from agricultural fields. The presence of riparian buffer vegetation in agricultural landscapes can modify the characteristics of overland flow, promoting sediment deposition and nutrient filtering. Watershed simulation tools, such as the USDA-Annualized Agricultural Non-Point Source (AnnAGNPS) pollution model, typically require detailed information for each riparian buffer zone throughout the watershed describing the location, width, vegetation type, topography, and possible presence of concentrated flow paths through the riparian buffer zone. Research was conducted to develop GIS-based technology designed to spatially characterize riparian buffers and to estimate buffer efficiency in reducing sediment loads in a semiautomated fashion at watershed scale. The methodology combines modeling technology at different scales, at individual concentrated flow paths passing through the riparian zone, and at watershed scales. At the concentrated flow path scale, vegetative filter strip models are applied to estimate the sediment-trapping efficiency for each individual flow path, which are aggregated based on the watershed subdivision and used in the determination of the overall impact of the riparian vegetation at the watershed scale. This GIS-based technology is combined with AnnAGNPS to demonstrate the effect of riparian vegetation on sediment loadings from sheet and rill and ephemeral gully sources. The effects of variability in basic input parameters used to characterize riparian buffers, onto generated outputs at field scale (sediment trapping efficiency) and at watershed scale (sediment loadings from different sources) were evaluated and quantified. The AnnAGNPS riparian buffer component represents an important step in understanding and accounting for the effect of riparian vegetation, existing and/or managed, in reducing sediment loads at the watershed scale. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Characterization and origin of spongillite-hosting sediment from João Pinheiro, Minas Gerais, Brazil

NASA Astrophysics Data System (ADS)

Almeida, A. C. S.; Varajão, A. F. D. C.; Gomes, N. S.; Varajão, C. A. C.; Volkmer-Ribeiro, C.

2010-03-01

Spongillite from João Pinheiro, Minas Gerais, Brazil is mainly known for its use in brick production and in the refractory industry. Very few studies have focused on its geological context. Spongillite-rich deposits occur in shallow ponds on a karstic planation surface developed on rocks of the Neoproterozoic São Francisco Supergroup. Cenozoic siliciclastic sediments are related to this surface. A field study of these deposits and analysis of multispectral images showed a SE-NW preferential drainage system at SE, suggesting that Mesozoic Areado Group sandstones were the source area of the spongillite-hosting sediments. Mineralogical and textural characterization by optical microscopic analysis, X-ray diffraction (XRD), differential and gravimetric thermal analysis (DTA-GTA), infrared spectroscopy (IR) and scanning electron microscopy (SEM) of seven open-pit spongillite-rich deposits (Avião, Carvoeiro, Vânio, Preguiça, Divisa, Severino, Feijão) showed a sedimentological similarity between the deposits. They are lens-shaped and are characterized at the bottom by sand facies, in the middle by spicules-rich muddy-sand facies and at the top by organic matter-rich muddy-sand facies. Petrographically, the spongillite-hosting sediments and the siliclastic sediments of the Areado Group show detrital phases with similar mineralogical and textural features, such as the presence of well-sorted quartz grains and surface features of abrasion typical of aeolian reworking that occurred in the depositional environment in which the sandstones of the Areado Group were formed. Detrital heavy minerals, such as staurolite, zircon, tourmaline, and clay minerals, such as kaolinite, low amounts of illite, scarce chlorite and mixed-layer chlorite/smectite and illite/smectite occur in the spongillite-hosting sediments and in sandstones from the Areado Group. In both formations, staurolite has similar chemical composition. These mineralogical and textural features show that the sediments of the Areado Group constitute the main source of the pond sediments that host spongillite.

Methods To Characterize Contaminant Residuals After Environmental Dredging

EPA Science Inventory

Environmental dredging is a common remedial action for managing contaminated sediments. However, post dredging contaminant concentrations in surface sediment are difficult to predict prior to initiating dredging actions. In some cases, post surface concentrations have been high...

Paleogeography of the upper Paleozoic basins of southern South America: An overview

NASA Astrophysics Data System (ADS)

Limarino, Carlos O.; Spalletti, Luis A.

2006-12-01

The paleogeographic evolution of Late Paleozoic basins located in southern South America is addressed. Three major types of basins are recognized: infracratonic or intraplate, arc-related, and retroarc. Intraplate basins (i.e., Paraná, Chaco-Paraná, Sauce Grande-Colorado, and La Golondrina) are floored by continental or quasi-continental crust, with low or moderate subsidence rates and limited magmatic and tectonic activity. Arc-related basins (northern and central Chile, Navidad-Arizaro, Río Blanco, and Calingasta-Uspallata basins and depocenters along Chilean Patagonia) show a very complex tectonic history, widespread magmatic activity, high subsidence rates, and in some cases metamorphism of Late Paleozoic sediments. An intermediate situation corresponds to the retroarc basins (eastern Madre de Dios, Tarija, Paganzo, and Tepuel-Genoa), which lack extensive magmatism and metamorphism but in which coeval tectonism and sedimentation rates were likely more important than those in the intraplate region. According to the stratigraphic distribution of Late Paleozoic sediments, regional-scale discontinuities, and sedimentation pattern changes, five major paleogeographic stages are proposed. The lowermost is restricted to the proto-Pacific and retroarc basins, corresponds to the Mississippian (stage 1), and is characterized by shallow marine and transitional siliciclastic sediments. During stage 2 (Early Pennsylvanian), glacial-postglacial sequences dominated the infracratonic (or intraplate) and retroarc basins, and terrigenous shallow marine sediments prevailed in arc-related basins. Stage 3 (Late Pennsylvanian-Early Cisuralian) shows the maximum extension of glacial-postglacial sediments in the Paraná and Sauce Grande-Colorado basins (intraplate region), whereas fluvial deposits interfingering with thin intervals of shallow marine sediments prevailed in the retroarc basins. To the west, arc-related basins were dominated by coastal to deep marine conditions (including turbiditic successions). In the Late Cisuralian (stage 4), important differences in sedimentation patterns are registered for the western arc-related basins and eastern intraplate basins. The former were locally dominated by volcaniclastic sediments or marine deposits, and the intraplate basins are characterized by shallow marine conditions punctuated by several episodes of deltaic progradation. Finally, in the Late Permian (stage 5), volcanism and volcaniclastic sedimentation dominated in basins located along the western South American margin. The intraplate basins in turn were characterized by T-R cycles composed of shallow marine, deltaic, and fluvial siliciclastic deposits.

Long term effect of a modified hydrodynamic at a lagoon inlet on the salt marsh ability to keep pace with sea level rise.

NASA Astrophysics Data System (ADS)

Carniello, L.; Nordio, G.; D'Alpaos, A.; Silvestri, S.

2016-12-01

In a context of global increase of mean sea level, the fate of salt marshes relates to their ability of keeping pace with relative sea level rise (SLR) and depends on the external sediment supply and organic soil production. Detecting the vertical sinking of salt marshes is a difficult task being the process characterized by time scales of tens to hundreds of years. Thanks to the availability of historical maps of the Venice lagoon, we reconstructed the reduction of salt mash areas that occurred in the northern part of the lagoon in the last two centuries. In this period, anthropic interventions played a crucial role in promoting the disappearance of vast marsh surfaces in the inner lagoon, while the marshes closer to the inlet remained fairly stable. Using a 2D numerical model we investigated the hydrodynamic behavior of different ancient lagoon configurations analyzing the effect of i) the construction of the jetties at the Lido inlet in 1882-1892 and ii) the removal of reed barriers that protected a fish farm area in the same period. Our results show that the deepening of the inlet induced by the construction of the jetties had a positive feedback on the vertical accretion of the salt marshes close to the inlet by lowering the local mean sea level and increasing the tidal amplitude. This effect contrasted the eustatic SLR for more than 30 years, allowing these marshes to increase their height with respect to the local mean sea level. On the contrary, the salt marshes far from the inlet could not take the same rapid advantage of this effect due to tidal wave dissipation characterizing tide propagation in shallow basins. Elevation of inner marshes is low due to the small tidal excursion, making these marshes extremely vulnerable to changes in sediment supply and SLR. We show that the removal of reed barriers used by ancient Venetians to create fish farms in the inner lagoon may have reduced the sediments available to the marshes thus contributing to their drowning.

Task 1: Correlation of satellite and ground data in air pollution studies. Task 2: Investigation to relate the chlorophyll and suspended sediment content in the waters of the lower Chesapeake Bay to ERTS-1 imagery. Task 3: The use of ERTS-1 to more fully utilize and apply marine station data to the study of productivity along the Eastern Shelf expanded waters of the United States

NASA Technical Reports Server (NTRS)

Copeland, G. E. (Principal Investigator); Bandy, A. R.; Fleischer, P.; Ludwick, J. C. (Principal Investigator); Hanna, W. J.; Gosink, T. A.; Bowker, D. W.; Marshall, H. G. (Principal Investigator)

1972-01-01

The author has identified the following significant results. Analysis of U-2 imagery of CARETS site indicates smoke plumes can be easily detected. First look at selected ERTS-1 color composites demonstrates plumes from forest fires can be detected.

Sediment geochemistry of Corte Madera Marsh, San Francisco Bay, California: have local inputs changed, 1830-2010?

USGS Publications Warehouse

Takesue, Renee K.; Jaffe, Bruce E.

2013-01-01

Large perturbations since the mid-1800s to the supply and source of sediment entering San Francisco Bay have disturbed natural processes for more than 150 years. Only recently have sediment inputs through the Sacramento-San Joaquin Delta (the Delta) decreased to what might be considered pre-disturbance levels. Declining sediment inputs to San Francisco Bay raise concern about continued tidal marsh accretion, particularly if sea level rise accelerates in the future. The aim of this study is to explore whether the relative amount of local-watershed sediment accumulating in a tidal marsh has changed as sediment supply from the Sacramento-San Joaquin Rivers has decreased. To address this question, sediment geochemical indicators, or signatures, in the fine fraction (silt and clay) of Sacramento River, San Joaquin River, San Francisco Bay, and Corte Madera Creek sediment were identified and applied in sediment recovered from Corte Madera Marsh, one of the few remaining natural marshes in San Francisco Bay. Total major, minor, trace, and rare earth element (REE) contents of fine sediment were determined by inductively coupled plasma mass and atomic emission spectroscopy. Fine sediment from potential source areas had the following geochemical signatures: Sacramento River sediment downstream of the confluence of the American River was characterized by enrichments in chromium, zirconium, and heavy REE; San Joaquin River sediment at Vernalis and Lathrop was characterized by enrichments in thorium and total REE content; Corte Madera Creek sediment had elevated nickel contents; and the composition of San Francisco Bay mud proximal to Corte Madera Marsh was intermediate between these sources. Most sediment geochemical signatures were relatively invariant for more than 150 years, suggesting that the composition of fine sediment in Corte Madera Marsh is not very sensitive to changes in the magnitude, timing, or source of sediment entering San Francisco Bay through the Delta. Nor does there appear to be a ubiquitous increase in the proportion of fine sediment from Corte Madera watershed accumulating in the marsh during the last 20 years when sediment inflows through the Delta have decreased to pre-disturbance levels. We conclude that a large, well-mixed reservoir, such as the transportable fine sediment pool in San Francisco Bay, is the primary source of sediment to Corte Madera Marsh, and this source buffers the marsh against changes in sediment supply from the Delta and local watersheds. This study also found that Corte Madera Marsh sediment between about 10-30 centimeters depth is highly contaminated with lead, likely a legacy of lead smelter operations near Carquinez Strait and leaded gasoline use.

SMARTE'S SITE CHARACTERIZATION TOOL

EPA Science Inventory

Site Characterization involves collecting environmental data to evaluate the nature and extent of contamination. Environmental data could consist of chemical analyses of soil, sediment, water or air samples. Typically site characterization data are statistically evaluated for thr...

Coastal circulation and sediment dynamics in Maunalua Bay, Oahu, Hawaii, measurements of waves, currents, temperature, salinity, and turbidity; November 2008-February 2009

USGS Publications Warehouse

Storlazzi, Curt D.; Presto, M. Katherine; Logan, Joshua B.; Field, Michael E.

2010-01-01

High-resolution measurements of waves, currents, water levels, temperature, salinity and turbidity were made in Maunalua Bay, southern Oahu, Hawaii, during the 2008-2009 winter to better understand coastal circulation, water-column properties, and sediment dynamics during a range of conditions (trade winds, kona storms, relaxation of trade winds, and south swells). A series of bottom-mounted instrument packages were deployed in water depths of 20 m or less to collect long-term, high-resolution measurements of waves, currents, water levels, temperature, salinity, and turbidity. These data were supplemented with a series of profiles through the water column to characterize the vertical and spatial variability in water-column properties within the bay. These measurements support the ongoing process studies being done as part of the U.S. Geological Survey (USGS) Coastal and Marine Geology Program's Pacific Coral Reef Project; the ultimate goal of these studies is to better understand the transport mechanisms of sediment, larvae, pollutants, and other particles in coral reef settings. Project Objectives The objective of this study was to understand the temporal variations in currents, waves, tides, temperature, salinity and turbidity within a coral-lined embayment that receives periodic discharges of freshwater and sediment from multiple terrestrial sources in the Maunalua Bay. Instrument packages were deployed for a three-month period during the 2008-2009 winter and a series of vertical profiles were collected in November 2008, and again in February 2009, to characterize water-column properties within the bay. Measurements of flow and water-column properties in Maunalua Bay provided insight into the potential fate of terrestrial sediment, nutrient, or contaminant delivered to the marine environment and coral larval transport within the embayment. Such data are useful for providing baseline information for future watershed decisions and for establishing guidelines for the U.S. Coral Reef Task Force's (USCRTF) Hawaiian Local Action Strategy to address Land-Based Pollution (LAS-LBP) threats to coral reefs adjacent to the urbanized watersheds of Manualua Bay. Study Area Maunalua Bay is on the south side of Oahu, Hawaii, and is approximately 10 km long and 3 km wide. The bay is flanked by two large, dormant craters: Koko Head to the east and Diamond Head to the west. Rainfall in the watersheds that drain into Maunalua Bay ranges from more than 200 cm/year at the top of the Ko'olau Range that borders the northwestern part of the bay to less than 70 cm/year to the east at Koko Head. Seven major channels flow into the bay, and all but one have been altered by engineering structures.

Characterization of sediment and measurement of groundwater levels and temperatures, Camas National Wildlife Refuge, eastern Idaho

USGS Publications Warehouse

Twining, Brian V.; Rattray, Gordon W.

2016-11-02

The Camas National Wildlife Refuge (Refuge) in eastern Idaho, established in 1937, contains wetlands, ponds, and wet meadows that are essential resting and feeding habitat for migratory birds and nesting habitat for waterfowl. Initially, natural sources of water supported these habitats. However, during the past few decades, climate change and changes in surrounding land use have altered and reduced natural groundwater and surface water inflows such that the wetlands, ponds, and wet meadows are now maintained through water management and groundwater pumping. These water management activities have proven to be inefficient and costly, prompting the Refuge to develop alternative water management options that are more efficient and less expensive. The U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, is studying the hydrogeology at the Refuge to provide information for developing alternative water management options.The hydrogeologic studies at the Refuge included characterizing the type, distribution, and hydraulic conductivity of surficial sediments and measuring water levels and temperatures in monitoring wells. Four monitoring wells and seven soil probe coreholes were drilled at the Refuge. Seven water level and temperature data loggers were installed in the wells and water levels and temperatures were continuously recorded from November 2014 to June 2016. Sediment cores were collected from the coreholes and sediment type and distribution were characterized from drillers’ notes, geophysical logs, corehole samples, and particle grain-size analysis. The hydraulic conductivities of sediments were estimated using the measured average grain size and the assumed textural maturity of the sediment, and ranged from about 20 to 290 feet per day.

Characterizing spatial structure of sediment E. coli populations to inform sampling design.

PubMed

Piorkowski, Gregory S; Jamieson, Rob C; Hansen, Lisbeth Truelstrup; Bezanson, Greg S; Yost, Chris K

2014-01-01

Escherichia coli can persist in streambed sediments and influence water quality monitoring programs through their resuspension into overlying waters. This study examined the spatial patterns in E. coli concentration and population structure within streambed morphological features during baseflow and following stormflow to inform sampling strategies for representative characterization of E. coli populations within a stream reach. E. coli concentrations in bed sediments were significantly different (p = 0.002) among monitoring sites during baseflow, and significant interactive effects (p = 0.002) occurred among monitoring sites and morphological features following stormflow. Least absolute shrinkage and selection operator (LASSO) regression revealed that water velocity and effective particle size (D 10) explained E. coli concentration during baseflow, whereas sediment organic carbon, water velocity and median particle diameter (D 50) were important explanatory variables following stormflow. Principle Coordinate Analysis illustrated the site-scale differences in sediment E. coli populations between disconnected stream segments. Also, E. coli populations were similar among depositional features within a reach, but differed in relation to high velocity features (e.g., riffles). Canonical correspondence analysis resolved that E. coli population structure was primarily explained by spatial (26.9–31.7 %) over environmental variables (9.2–13.1 %). Spatial autocorrelation existed among monitoring sites and morphological features for both sampling events, and gradients in mean particle diameter and water velocity influenced E. coli population structure for the baseflow and stormflow sampling events, respectively. Representative characterization of streambed E. coli requires sampling of depositional and high velocity environments to accommodate strain selectivity among these features owing to sediment and water velocity heterogeneity.

Relationship between macrobenthos and physical habitat characters in tidal flat in eastern Seto Inland Sea, Japan.

PubMed

Otani, Sosuke; Kozuki, Yasunori; Kurata, Kengo; Ueda, Kaori; Nakai, Shigefumi; Murakami, Hitoshi

2008-01-01

The investigations were carried out at 6 tidal flats located on the eastern part of the Seto Inland Sea, Japan. This study was focused on physical characteristics of sediments, namely as particle size of sediment and difference in elevation, and generalizes the relationship between sediments and macrobenthos. A total of 192 species were collected at 187 stations at 6 tidal flats. Physical characteristics of sediment were classified into 9 groups by cluster analysis in relation to sediment particle size and difference in elevation. Those groups had also significant difference in physical characteristics of sediments, and were characterized by some specific macrobenthos species. Distribution of macrobenthos can be explained by the classification of physical characteristics of sediment. These findings show the possibility to predict the variety of macrobenthos community using the physical characteristics of sediment.

Reverse weathering in marine sediments and the geochemical cycle of potassium in seawater: Insights from the K isotopic composition (41K/39K) of deep-sea pore-fluids

USGS Publications Warehouse

Santiago Ramos, Danielle P.; Morgan, Leah; Lloyd, Nicholas S.; Higgins, John A.

2018-01-01

In situ Al-silicate formation, also known as “reverse weathering,” is an important sink of many of the major and minor cations in seawater (e.g. Mg, K, and Li). However, the importance of this sink in global geochemical cycles and isotopic budgets of these elements remains poorly constrained. Here, we report on the potassium isotopic composition (41">41K/39">39K) of deep-sea sediment pore-fluids from four (Integrated) Ocean Drilling Program sites (1052, U1378, U1395 and U1403) to characterize potassium isotopic fractionation associated with the formation of authigenic Al-silicate minerals in marine sediments and its role in elevating the 41">41K/39">39K of seawater relative to bulk silicate Earth. Isotopic ratios are obtained by high-resolution multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) in cold plasma conditions with a long-term external reproducibility of ca. 0.17‰. We find that, although all sites are characterized by pore-fluid K concentrations that decline with increasing depth, their K isotopic profiles vary systematically from site-to-site; at sites characterized by rapid sedimentation rates, pore-fluid profiles of 41">41K/39">39K are relatively invariant whereas at sites characterized by slow sedimentation rates, 41">41K/39">39K declines with depth by up to 1.8‰. Results from 1-D diffusion-advection-reaction models suggest that these differences may result from a complex interplay between sedimentation rate and fractionation of K isotopes during diffusion, Al-silicate authigenesis, and ion exchange. Model simulations suggest fractionation factors between 0.9980 and 1.0000 for reverse weathering reactions in deep-sea sediments. Although deep-sea sites do not constitute major sinks of K in seawater, some of the processes responsible for K isotopic fractionation at these sites (diffusion and Al-silicate authigenesis) likely play a role in determining the 41">41K/39">39K of seawater.

Formation of fine sediment deposit from a flash flood river in the Mediterranean Sea

USGS Publications Warehouse

Grifoll, Manel; Gracia, Vicenç; Aretxabaleta, Alfredo L.; Guillén, Jorge; Espino, Manuel; Warner, John C.

2014-01-01

We identify the mechanisms controlling fine deposits on the inner-shelf in front of the Besòs River, in the northwestern Mediterranean Sea. This river is characterized by a flash flood regime discharging large amounts of water (more than 20 times the mean water discharge) and sediment in very short periods lasting from hours to few days. Numerical model output was compared with bottom sediment observations and used to characterize the multiple spatial and temporal scales involved in offshore sediment deposit formation. A high-resolution (50 m grid size) coupled hydrodynamic-wave-sediment transport model was applied to the initial stages of the sediment dispersal after a storm-related flood event. After the flood, sediment accumulation was predominantly confined to an area near the coastline as a result of preferential deposition during the final stage of the storm. Subsequent reworking occurred due to wave-induced bottom shear stress that resuspended fine materials, with seaward flow exporting them toward the midshelf. Wave characteristics, sediment availability, and shelf circulation determined the transport after the reworking and the final sediment deposition location. One year simulations of the regional area revealed a prevalent southwestward average flow with increased intensity downstream. The circulation pattern was consistent with the observed fine deposit depocenter being shifted southward from the river mouth. At the southern edge, bathymetry controlled the fine deposition by inducing near-bottom flow convergence enhancing bottom shear stress. According to the short-term and long-term analyses, a seasonal pattern in the fine deposit formation is expected.

Scaling hyporheic exchange and its influence on biogeochemical reactions in aquatic ecosystems

USGS Publications Warehouse

O'Connor, Ben L.; Harvey, Judson W.

2008-01-01

Hyporheic exchange and biogeochemical reactions are difficult to quantify because of the range in fluid‐flow and sediment conditions inherent to streams, wetlands, and nearshore marine ecosystems. Field measurements of biogeochemical reactions in aquatic systems are impeded by the difficulty of measuring hyporheic flow simultaneously with chemical gradients in sediments. Simplified models of hyporheic exchange have been developed using Darcy's law generated by flow and bed topography at the sediment‐water interface. However, many modes of transport are potentially involved (molecular diffusion, bioturbation, advection, shear, bed mobility, and turbulence) with even simple models being difficult to apply in complex natural systems characterized by variable sediment sizes and irregular bed geometries. In this study, we synthesize information from published hyporheic exchange investigations to develop a scaling relationship for estimating mass transfer in near‐surface sediments across a range in fluid‐flow and sediment conditions. Net hyporheic exchange was quantified using an effective diffusion coefficient (De) that integrates all of the various transport processes that occur simultaneously in sediments, and dimensional analysis was used to scale De to shear stress velocity, roughness height, and permeability that describe fluid‐flow and sediment characteristics. We demonstrated the value of the derived scaling relationship by using it to quantify dissolved oxygen (DO) uptake rates on the basis of DO profiles in sediments and compared them to independent flux measurements. The results support a broad application of the De scaling relationship for quantifying coupled hyporheic exchange and biogeochemical reaction rates in streams and other aquatic ecosystems characterized by complex fluid‐flow and sediment conditions.

Trend analyses with river sediment rating curves

USGS Publications Warehouse

Warrick, Jonathan A.

2015-01-01

Sediment rating curves, which are fitted relationships between river discharge (Q) and suspended-sediment concentration (C), are commonly used to assess patterns and trends in river water quality. In many of these studies it is assumed that rating curves have a power-law form (i.e., C = aQb, where a and b are fitted parameters). Two fundamental questions about the utility of these techniques are assessed in this paper: (i) How well to the parameters, a and b, characterize trends in the data? (ii) Are trends in rating curves diagnostic of changes to river water or sediment discharge? As noted in previous research, the offset parameter, a, is not an independent variable for most rivers, but rather strongly dependent on b and Q. Here it is shown that a is a poor metric for trends in the vertical offset of a rating curve, and a new parameter, â, as determined by the discharge-normalized power function [C = â (Q/QGM)b], where QGM is the geometric mean of the Q values sampled, provides a better characterization of trends. However, these techniques must be applied carefully, because curvature in the relationship between log(Q) and log(C), which exists for many rivers, can produce false trends in â and b. Also, it is shown that trends in â and b are not uniquely diagnostic of river water or sediment supply conditions. For example, an increase in â can be caused by an increase in sediment supply, a decrease in water supply, or a combination of these conditions. Large changes in water and sediment supplies can occur without any change in the parameters, â and b. Thus, trend analyses using sediment rating curves must include additional assessments of the time-dependent rates and trends of river water, sediment concentrations, and sediment discharge.

Organic matter degradation in surface sediments of the Changjiang estuary: Evidence from amino acids.

PubMed

Wang, Kui; Chen, Jianfang; Jin, Haiyan; Li, Hongliang; Zhang, Weiyan

2018-05-12

Organic matter degradation is a key component of the processes of carbon preservation and burial in seafloor sediments. The aim of this study was to explore organic matter degradation state within the open-shelf Changjiang Estuary of the East China Sea, using an amino acids-based degradation index (DI) in conjunction with information about organic matter source (marine versus terrestrial), bottom water oxygenation state, and sediment grain size. The relative molar percentages of 17 individual amino acids (characterized using principal component analysis) in surface sediments indicate that organic matter is degraded to varying extents across the estuary seabed. Sediments with DI >0 (relatively labile) were found mostly within a coastal hypoxic area. Sediments of DI less than -1 (relatively refractory) were found near the Changjiang River mouth and the northern and southern parts of the central shelf. We consider DI to be a more reliable indicator of degradation than simple ratios of AAs. DI was inversely correlated with the proportion of terrestrial organic material (F t ) in the sediments, indicating that relatively fresh/labile organic matter was generally associated with marine sources. DI was significantly correlated with F t and bottom water apparent oxygen utilization (AOU bot ) together. The parameter DI and the (labile) amino acid tyrosine were highest in hypoxic areas, suggesting the presence of relatively fresh organic matter, probably due to a combination of marine-source inputs and better preservation of organic matter in the silt and clay sediments of these areas (as compared to sandy sediments). Less degraded organic matter with high amino acids was also favorable to benthic animals. Overall, sedimentary estuarine organic matter was least degraded in areas characterized by marine sources of organic matter, low-oxygen conditions, and fine-grained sediments. Copyright © 2018 Elsevier B.V. All rights reserved.

Deep Subsurface Life from North Pond: Enrichment, Isolation, Characterization and Genomes of Heterotrophic Bacteria

PubMed Central

Russell, Joseph A.; León-Zayas, Rosa; Wrighton, Kelly; Biddle, Jennifer F.

2016-01-01

Studies of subsurface microorganisms have yielded few environmentally relevant isolates for laboratory studies. In order to address this lack of cultivated microorganisms, we initiated several enrichments on sediment and underlying basalt samples from North Pond, a sediment basin ringed by basalt outcrops underlying an oligotrophic water-column west of the Mid-Atlantic Ridge at 22°N. In contrast to anoxic enrichments, growth was observed in aerobic, heterotrophic enrichments from sediment of IODP Hole U1382B at 4 and 68 m below seafloor (mbsf). These sediment depths, respectively, correspond to the fringes of oxygen penetration from overlying seawater in the top of the sediment column and upward migration of oxygen from oxic seawater from the basalt aquifer below the sediment. Here we report the enrichment, isolation, initial characterization and genomes of three isolated aerobic heterotrophs from North Pond sediments; an Arthrobacter species from 4 mbsf, and Paracoccus and Pseudomonas species from 68 mbsf. These cultivated bacteria are represented in the amplicon 16S rRNA gene libraries created from whole sediments, albeit at low (up to 2%) relative abundance. We provide genomic evidence from our isolates demonstrating that the Arthrobacter and Pseudomonas isolates have the potential to respire nitrate and oxygen, though dissimilatory nitrate reduction could not be confirmed in laboratory cultures. The cultures from this study represent members of abundant phyla, as determined by amplicon sequencing of environmental DNA extracts, and allow for further studies into geochemical factors impacting life in the deep subsurface. PMID:27242705

Deep Subsurface Life from North Pond: Enrichment, Isolation, Characterization and Genomes of Heterotrophic Bacteria.

PubMed

Russell, Joseph A; León-Zayas, Rosa; Wrighton, Kelly; Biddle, Jennifer F

2016-01-01

Studies of subsurface microorganisms have yielded few environmentally relevant isolates for laboratory studies. In order to address this lack of cultivated microorganisms, we initiated several enrichments on sediment and underlying basalt samples from North Pond, a sediment basin ringed by basalt outcrops underlying an oligotrophic water-column west of the Mid-Atlantic Ridge at 22°N. In contrast to anoxic enrichments, growth was observed in aerobic, heterotrophic enrichments from sediment of IODP Hole U1382B at 4 and 68 m below seafloor (mbsf). These sediment depths, respectively, correspond to the fringes of oxygen penetration from overlying seawater in the top of the sediment column and upward migration of oxygen from oxic seawater from the basalt aquifer below the sediment. Here we report the enrichment, isolation, initial characterization and genomes of three isolated aerobic heterotrophs from North Pond sediments; an Arthrobacter species from 4 mbsf, and Paracoccus and Pseudomonas species from 68 mbsf. These cultivated bacteria are represented in the amplicon 16S rRNA gene libraries created from whole sediments, albeit at low (up to 2%) relative abundance. We provide genomic evidence from our isolates demonstrating that the Arthrobacter and Pseudomonas isolates have the potential to respire nitrate and oxygen, though dissimilatory nitrate reduction could not be confirmed in laboratory cultures. The cultures from this study represent members of abundant phyla, as determined by amplicon sequencing of environmental DNA extracts, and allow for further studies into geochemical factors impacting life in the deep subsurface.

Data on natural organic substances in dissolved, colloidal, suspended-silt and -clay, and bed-sediment phases in the Mississippi River and some of its tributaries, 1987-90

USGS Publications Warehouse

Leenheer, J.A.; Noyes, T.I.; Brown, P.A.

1994-01-01

The Mississippi River and some of its tributaries were sampled for natural organic substances dissolved in water and in suspended and bed sediments during seven sampling cruises from 1987-90. The sampling cruises were made during different seasons, in the free-flowing reaches of the river from St. Louis, Missouri, to New Orleans, Louisiana. The first three cruises were made during low-water conditions, and the last four cruises during high-water conditions. The purpose for sampling and characterizing natural organic substances in the various phases in the river was to provide an understanding of how these substances facilitate contaminant transport and transformations in the Mississippi River. Significant conclusions of this study were: (1) Natural organic substances appear to stabilize ' certain colloids against aggregation; therefore, these colloids remain in suspension and can act as transport agents that are not affected by sedimentation. Bacteria were found to be a significant fraction of organic colloids. (2) A new class of organic contaminants (polyethylene glycols) derived from nonionic surfactant residues was discovered dissolved with natural organic substances in water. These polyethylene glycols have the potential to affect both organic and inorganic contaminant transport in water. (3) The entire dissolved organic-matter component under varying hydrologic and seasonal conditions was characterized. (4) A method was developed to characterize organic matter in sediment by solid-state, 13C-nuclear magnetic resonance spectrometry. (5) The organic matter in suspended sediments was characterized by a variety of spectral and nonspectral methods. The protein component (significant in trace-metal binding) and lipid component (significant in organic-contaminant binding) were found to be major constituents in natural organic matter in suspended sediment. (6) Pools are reservoirs acting as traps of sedimentary organic matter of allochthonous origin and export material of autochthonous nitrogen. (7) A major portion of the mass of organic colloids in transport consisted of bacterial cells.

Modern configuration of the southwest Florida carbonate slope: Development by shelf margin progradation

USGS Publications Warehouse

Brooks, G.R.; Holmes, C.W.

1990-01-01

Depositional patterns and sedimentary processes influencing modern southwest Florida carbonate slope development have been identified based upon slope morphology, seismic facies and surface sediment characteristics. Three slope-parallel zones have been identified: (1) an upper slope progradational zone (100-500 m) characterized by seaward-trending progradational clinoforms and sediments rich in shelf-derived carbonate material, (2) a lower gullied slope zone (500-800 m) characterized by numerous gullies formed by the downslope transport of gravity flows, and (3) a base-of-slope zone (> 800 m) characterized by thin, lens-shaped gravity flow deposits and irregular topography interpreted to be the result of bottom currents and slope failure along the basal extensions of gullies. Modern slope development is interpreted to have been controlled by the offshelf transport of shallow-water material from the adjacent west Florida shelf, deposition of this material along a seaward advancing sediment front, and intermittent bypassing of the lower slope by sediments transported in the form of gravity flows via gullies. Sediments are transported offshelf by a combination of tides and the Loop Current, augmented by the passage of storm frontal systems. Winter storm fronts produce cold, dense, sediment-laden water that cascades offshelf beneath the strong, eastward flowing Florida Current. Sediments are eventually deposited in a relatively low energy transition zone between the Florida Current on the surface and a deep westward flowing counter current. The influence of the Florida Current is evident in the easternmost part of the study area as eastward prograding sediments form a sediment drift that is progressively burying the Pourtales Terrace. The modern southwest Florida slope has seismic reflection and sedimentological characteristics in common with slopes bordering both the non-rimmed west Florida margin and the rimmed platform of the northern Bahamas, and shows many similarities to the progradational Miocene section along the west Florida slope. As with rimmed platform slopes, development of non-rimmed platform slopes can be complex and controlled by a combination of processes that result in a variety of configurations. Consequently, the distinction between the two slope types based solely upon seismic and sedimentological characteristics may not be readily discernible. ?? 1990.

Develop Accurate Methods for Characterizing And Quantifying Cohesive Sediment Erosion Under Combined Current Wave Conditions: Project ER 1497

DTIC Science & Technology

2017-09-01

ER D C/ CH L TR -1 7- 15 Strategic Environmental Research and Development Program Develop Accurate Methods for Characterizing and...current environments. This research will provide more accurate methods for assessing contaminated sediment stability for many DoD and Environmental...47.88026 pascals yards 0.9144 meters ERDC/CHL TR-17-15 xi Executive Summary Objective The proposed research goal is to develop laboratory methods

Characterization of a Louisiana Bay Bottom

NASA Astrophysics Data System (ADS)

Freeman, A. M.; Roberts, H. H.

2016-02-01

This study correlates side-scan sonar and CHIRP water bottom-subbottom acoustic amplitudes with cone penetrometer data to expand the limited understanding of the geotechnical properties of sediments in coastal Louisiana's bays. Standardized analysis procedures were developed to characterize the bay bottom and shallow subsurface of the Sister Lake bay bottom. The CHIRP subbottom acoustic data provide relative amplitude information regarding reflection horizons of the bay bottom and shallow subsurface. An amplitude analysis technique was designed to identify different reflectance regions within the lake from the CHIRP subbottom profile data. This amplitude reflectivity analysis technique provides insight into the relative hardness of the bay bottom and shallow subsurface, useful in identifying areas of erosion versus deposition from storms, as well as areas suitable for cultch plants for state oyster seed grounds, or perhaps other restoration projects. Side-scan and CHIRP amplitude reflectivity results are compared to penetrometer data that quantifies geotechnical properties of surface and near-surface sediments. Initial results indicate distinct penetrometer signatures that characterize different substrate areas including soft bottom, storm-deposited silt-rich sediments, oyster cultch, and natural oyster reef areas. Although amplitude analysis of high resolution acoustic data does not directly quantify the geotechnical properties of bottom sediments, our analysis indicates a close relationship. The analysis procedures developed in this study can be applied in other dynamic coastal environments, "calibrating" the use of synoptic acoustic methods for large-scale water bottom characterization.

Acoustic Seabed Characterization of the Porcupine Bank, Irish Margin

NASA Astrophysics Data System (ADS)

O'Toole, Ronan; Monteys, Xavier

2010-05-01

The Porcupine Bank represents a large section of continental shelf situated west of the Irish landmass, located in water depths ranging between 150 and 500m. Under the Irish National Seabed Survey (INSS 1999-2006) this area was comprehensively mapped, generating multiple acoustic datasets including high resolution multibeam echosounder data. The unique nature of the area's datasets in terms of data density, consistency and geographic extent has allowed the development of a large-scale integrated physical characterization of the Porcupine Bank for multidisciplinary applications. Integrated analysis of backscatter and bathymetry data has resulted in a baseline delineation of sediment distribution, seabed geology and geomorphological features on the bank, along with an inclusive set of related database information. The methodology used incorporates a variety of statistical techniques which are necessary in isolating sonar system artefacts and addressing sonar geometry related issues. A number of acoustic backscatter parameters at several angles of incidence have been analysed in order to complement the characterization for both surface and subsurface sediments. Acoustic sub bottom records have also been incorporated in order to investigate the physical characteristics of certain features on the Porcupine Bank. Where available, groundtruthing information in terms of sediment samples, video footage and cores has been applied to add physical descriptors and validation to the characterization. Extensive mapping of different rock outcrops, sediment drifts, seabed features and other geological classes has been achieved using this methodology.

Transport and Sources of Suspended Sediment in the Mill Creek Watershed, Johnson County, Northeast Kansas, 2006-07

USGS Publications Warehouse

Lee, Casey J.; Rasmussen, Patrick P.; Ziegler, Andrew C.; Fuller, Christopher C.

2009-01-01

The U.S. Geological Survey, in cooperation with the Johnson County Stormwater Management Program, evaluated suspended-sediment transport and sources in the urbanizing, 57.4 mi2 Mill Creek watershed from February 2006 through June 2007. Sediment transport and sources were assessed spatially by continuous monitoring of streamflow and turbidity as well as sampling of suspended sediment at nine sites in the watershed. Within Mill Creek subwatersheds (2.8-16.9 mi2), sediment loads at sites downstream from increased construction activity were substantially larger (per unit area) than those at sites downstream from mature urban areas or less-developed watersheds. Sediment transport downstream from construction sites primarily was limited by transport capacity (streamflow), whereas availability of sediment supplies primarily influenced transport downstream from mature urban areas. Downstream sampling sites typically had smaller sediment loads (per unit area) than headwater sites, likely because of sediment deposition in larger, less sloping stream channels. Among similarly sized storms, those with increased precipitation intensity transported more sediment at eight of the nine monitoring sites. Storms following periods of increased sediment loading transported less sediment at two of the nine monitoring sites. In addition to monitoring performed in the Mill Creek watershed, sediment loads were computed for the four other largest watersheds (48.6-65.7 mi2) in Johnson County (Blue River, Cedar, Indian, and Kill Creeks) during the study period. In contrast with results from smaller watersheds in Mill Creek, sediment load (per unit area) from the most urbanized watershed in Johnson County (Indian Creek) was more than double that of other large watersheds. Potential sources of this sediment include legacy sediment from earlier urban construction, accelerated stream-channel erosion, or erosion from specific construction sites, such as stream-channel disturbance during bridge renovation. The implication of this finding is that sediment yields from larger watersheds may remain elevated after the majority of urban development is complete. Surface soil, channel-bank, suspended-sediment, and streambed-sediment samples were analyzed for grain size, nutrients, trace elements, and radionuclides in the Mill Creek watershed to characterize suspended sediment between surface or channel-bank sources. Although concentrations and activities of cobalt, nitrogen, selenium, total organic carbon, cesium-137, and excess lead-210 had significant differences between surface and channel-bank samples, biases resulting from urban construction, additional sorption of constituents during sediment transport, and inability to accurately represent erosion from rills and gullies precluded accurate characterization of suspended-sediment source.

Quadrant III RFI draft report: Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-12-01

The purpose of the RCRA Facility Investigation (RFI) at The Portsmouth Gaseous Diffusion Plant (PORTS) is to acquire, analyze and interpret data that will: characterize the environmental setting, including ground water, surface water and sediment, soil and air; define and characterize sources of contamination; characterize the vertical and horizontal extent and degree of contamination of the environment; assess the risk to human health and the environment resulting from possible exposure to contaminants; and support the Corrective Measures Study (CMS), which will follow the RFI, if required. A total of 18 Solid Waste Management Units (SWMU's) were investigated. All surficial soilmore » samples (0--2 ft), sediment samples and surface-water samples proposed in the approved Quadrant III RFI Work Plan were collected as specified in the approved work plan and RFI Sampling Plan. All soil, sediment and surface-water samples were analyzed for parameters specified from the Target Compound List and Target Analyte List (TCL/TAL) as listed in the US EPA Statement of Work for Inorganic (7/88a) and Organic (2/88b) analyses for Soil and Sediment, and analyses for fluoride, Freon-113 and radiological parameters (total uranium, gross alpha, gross beta and technetium).« less

Quadrant III RFI draft report: Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-12-01

The purpose of the RCRA Facility Investigation (RFI) at The Portsmouth Gaseous Diffusion Plant (PORTS) is to acquire, analyze and interpret data that will: characterize the environmental setting, including ground water, surface water and sediment, soil and air; define and characterize sources of contamination; characterize the vertical and horizontal extent and degree of contamination of the environment; assess the risk to human health and the environment resulting from possible exposure to contaminants; and support the Corrective Measures Study (CMS), which will follow the RFI, if required. A total of 18 Solid Waste Management Units (SWMU`s) were investigated. All surficial soilmore » samples (0--2 ft), sediment samples and surface-water samples proposed in the approved Quadrant III RFI Work Plan were collected as specified in the approved work plan and RFI Sampling Plan. All soil, sediment and surface-water samples were analyzed for parameters specified from the Target Compound List and Target Analyte List (TCL/TAL) as listed in the US EPA Statement of Work for Inorganic (7/88a) and Organic (2/88b) analyses for Soil and Sediment, and analyses for fluoride, Freon-113 and radiological parameters (total uranium, gross alpha, gross beta and technetium).« less

Characteristics of depositional environments in the Nakdong River Estuary, South Korea

NASA Astrophysics Data System (ADS)

Woo, Han Jun; Lee, Jun-Ho; Kang, Jeongwon; Choi, Jae Ung

2017-04-01

Most of the major Korean estuaries, under high pressure from development, have dams with environmental problems, including restricted water circulation, low water quality, decreased biodiversity and wetland destruction. The Nakdong estuary on the southeastern coast of Korean Peninsula is an enclosed type with two large estuarine dams that were constructed in 1934 and between 1983 and 1987. The construction of dams has led to geomorphologic evolution of the barrier islands within Nakdong estuary. The estuary has been characterized as barrier-lagoon system with various subenvironments and microtidal with a 1.5 m tidal range. The sedimentary analyses and monitoring short-term sedimentation rates were investigated to understand characteristics of depositional environments in barrier-lagoon system of the Nakdong River Estuary. The surface sediments in the system were classified into three sedimentary facies in summer 2015. Generally, sand sediment was dominated in the seaward side of barrier islands and muddy sand sediment was dominated on the lagoon. Sandy mud and mud sediments were distributed in the tidal flat near Noksan industrial district and channels near dams. Fourteen a priori subenvironments were distinguished based on differences in landscape characterization (sediment texture, salinity, total organic carbon, pH and C/N ratios). The dendrogram resulting from cluster analysis of environmental variables from 14 a priori subenvironments could be clustered into 4 groups that were characterized by different sediment texture and hydrodynamic energy. The short-term sedimentation rates were obtained seasonally from three lines by burying a plate at sub-bottom depth from May 2015 to May 2016. The deposition was dominated on the tidal flat between mainland and Jinudo (JW- Line) and Sinjado (SJ-Line) with the net deposition rate of 10.09 mm/year and 12.38 mm/year, respectively. The erosion was dominated on the tidal flats at Eulsukdo (ES-Line) on the east side of the system with an annual erosion rate of -13.15 mm/year. Two 12.5-hours anchoring surveys at inlets were revealed that net suspended sediments were transported to the open sea during a tidal cycle in summer 2015 and 2016. The sedimentary processes of the anthropogenically altered barrier-lagoon system in Nakdong estuary showed that sediments transported into the lagoon through inlets during flood condition and moved to westward and deposited sediments on the tidal flat and channels near dams in low energy environments. In the east side of the system, sediments flowed out the sea with discharge from Nakdong Dam during ebb condition. These data will provide an important baseline for future assessments of environmental quality on dam open.

Sediment dynamics in a large shallow lake characterized by seasonal flood pulse in Southeast Asia.

PubMed

Siev, Sokly; Yang, Heejun; Sok, Ty; Uk, Sovannara; Song, Layheang; Kodikara, Dilini; Oeurng, Chantha; Hul, Seingheng; Yoshimura, Chihiro

2018-08-01

Most of studies on sediment dynamics in stable shallow lakes focused on the resuspension process as it is the dominant process. However, understanding of sediment dynamics in a shallow lake influenced by flood pulse is unclear. We tested a hypothesis that floodplain vegetation plays as a significant role in lessening the intensity of resuspension process in a shallow lake characterized by the flood pulse system. Therefore, this study aimed to investigate sediment dynamics in this type of shallow lake. The target was Tonle Sap Lake (TSL), which is a large shallow lake influenced by a flood pulse system of Mekong River located in Southeast Asia. An extensive and seasonal sampling survey was conducted to measure total suspended solid (TSS) concentrations, sedimentation and resuspension rates in TSL and its 4 floodplain areas. The study revealed that sedimentation process was dominant (TSS ranged: 3-126mgL -1 ) in the high water period (September-December) while resuspension process was dominant (TSS ranged: 4-652mgL -1 ) only in the low water period (March-June). In addition, floodplain vegetation reduced the resuspension of sediment (up to 26.3%) in water. The implication of the study showed that resuspension is a seasonally dominant process in shallow lake influenced by the flood pulse system at least for the case of TSL. Copyright © 2018 Elsevier B.V. All rights reserved.

78 FR 46931 - Intent To Hold North Dakota Task Force Meeting as Established by the Missouri River Protection...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-02

... a long-term strategy to improve conservation, protect recreation from sedimentation, improve water quality, improve erosion control, and protect historic and cultural sites along the Missouri River in...

Influence Of Groundwater Discharge On Arsenic Contamination In Sediments

EPA Science Inventory

A field investigation was conducted to evaluate the impact of a discharging arsenic plume on sediment contaminant characteristics at a site adjacent to a landfill in northeastern Massachusetts. Site characterization included assessment of the hydrologic and chemical samples coll...

NEW GIS WATERSHED ANALYSIS TOOLS FOR SOIL CHARACTERIZATION AND EROSION AND SEDIMENTATION MODELING

EPA Science Inventory

A comprehensive procedure for computing soil erosion and sediment delivery metrics has been developed which utilizes a suite of automated scripts and a pair of processing-intensive executable programs operating on a personal computer platform.

Evaluation of critical shear stresses for consolidated cohesive sediment depositions by using PIV compared with field measurements

NASA Astrophysics Data System (ADS)

Harb, Gabriele; Haun, Stefan

2013-04-01

Reservoir sedimentation is a common problem today. Due to the reduced flow velocities, turbulences and bed shear stresses the transported sediment load start to settle. These depositions reduce the worldwide average storage capacity in the range of about 1% per year. However, depending on the climate conditions and the geology in the catchment area this value may vary strongly. Therefore sediment management tasks, especially the removal of already accumulated sediments, have to be developed for each reservoir separately. The critical bed shear stress is a key parameter used to evaluate the different management tasks and depend strongly on the grain size distribution of the inflowing sediments. However, depositions which contain fine particles like clay and silt increase the critical bed shear stress due to occurring cohesive forces and the use of the Shield curve for evaluating the critical shear stress is no longer valid. Additional data is required for estimating the valid critical shear stress at the reservoir bed. In this study the critical shear stress was evaluated for cohesive sediment samples, taken from two different reservoirs, in a flume in the laboratory. The sediment samples were placed in an installed double bottom in the research flume and the discharge was increased stepwise until mass erosion took place (determined by visual inspection). A 2D PIV device was used to measure the flow conditions (velocities and turbulences) over the sediment sample. The obtained values were used to calculate the bed shear stress for the specific discharge rate by the gravity method and the Reynolds stress method. The results of both methods showed good agreement in the comparison of the values, what indicates that nearly uniform flow conditions occurred in the flume. The results from this study showed that the behaviour of natural cohesive sediments depend strongly on the natural conditions as a result of physical, chemical and biological processes. In this case especially the effect of the layer structure in the sediment samples was controlling the erosion mechanism. The results of the experiments showed also that the obtained average shear stress was above most of the values found in previous conducted studies, which may be explained by consolidation effects in the reservoirs. Additional conducted vane strength measurements have been carried out in situ. The in the field obtained vane strength values were set in relation to the critical shear stresses derived by the experimental tests from the laboratory and to data from a previous conducted study to develop a new relation function. This function may be used in future studies for a rough estimation of the critical shear stress, based on in situ measured vane strength values.

Recovery and validation of historical sediment quality data from coastal and estuarine areas: An integrated approach

USGS Publications Warehouse

Manheim, F.T.; Buchholtz ten Brink, Marilyn R.; Mecray, E.L.

1998-01-01

A comprehensive database of sediment chemistry and environmental parameters has been compiled for Boston Harbor and Massachusetts Bay. This work illustrates methodologies for rescuing and validating sediment data from heterogeneous historical sources. It greatly expands spatial and temporal data coverage of estuarine and coastal sediments. The database contains about 3500 samples containing inorganic chemical, organic, texture and other environmental data dating from 1955 to 1994. Cooperation with local and federal agencies as well as universities was essential in locating and screening documents for the database. More than 80% of references utilized came from sources with limited distribution (gray literature). Task sharing was facilitated by a comprehensive and clearly defined data dictionary for sediments. It also served as a data entry template and flat file format for data processing and as a basis for interpretation and graphical illustration. Standard QA/QC protocols are usually inapplicable to historical sediment data. In this work outliers and data quality problems were identified by batch screening techniques that also provide visualizations of data relationships and geochemical affinities. No data were excluded, but qualifying comments warn users of problem data. For Boston Harbor, the proportion of irreparable or seriously questioned data was remarkably small (<5%), although concentration values for metals and organic contaminants spanned 3 orders of magnitude for many elements or compounds. Data from the historical database provide alternatives to dated cores for measuring changes in surficial sediment contamination level with time. The data indicate that spatial inhomogeneity in harbor environments can be large with respect to sediment-hosted contaminants. Boston Inner Harbor surficial sediments showed decreases in concentrations of Cu, Hg, and Zn of 40 to 60% over a 17-year period.A comprehensive database of sediment chemistry and environmental parameters has been compiled for Boston Harbor and Massachusetts Bay. This work illustrates methodologies for rescuing and validating sediment data from heterogeneous historical sources. It greatly expands spatial and temporal data coverage of estuarine and coastal sediments. The database contains about 3500 samples containing inorganic chemical, organic, texture and other environmental data dating from 1995 to 1994. Cooperation with local and federal agencies as well as universities was essential in locating and screening documents for the database. More than 80% of references utilized came from sources with limited distribution (gray Task sharing was facilitated by a comprehensive and clearly defined data dictionary for sediments. It also served as a data entry template and flat file format for data processing and as a basis for interpretation and graphical illustration. Standard QA/QC protocols are usually inapplicable to historical sediment data. In this work outliers and data quality problems were identified by batch screening techniques that also provide visualizations of data relationships and geochemical affinities. No data were excluded, but qualifying comments warn users of problem data. For Boston Harbor, the proportion of irreparable or seriously questioned data was remarkably small (<5%), although concentration values for metals and organic contaminants spanned 3 orders of magnitude for many elements or compounds. Data from the historical database provide alternatives to dated cores for measuring changes in surficial sediment contamination level with time. The data indicate that spatial inhomogeneity in harbor environments can be large with respect to sediment-hosted contaminants. Boston Inner Harbor surficial sediments showed decreases in concentrations Cu, Hg, and Zn of 40 to 60% over a 17-year period.

Characterization of sediments from the Gulf of Mexico and Atlantic shorelines, Texas to Florida

USGS Publications Warehouse

Lisle, John T.; Comer, Norris N.

2011-01-01

In response to the Deepwater Horizon oil spill, sediment samples that were projected to have a high probability of being impacted by the oil were collected from shoreline zones of Texas, Louisiana, Mississippi, Alabama, and Florida. Sixty-one sites were sampled and analyzed for hydraulic conductivity, porosity, and grain-size distribution. The objective of this effort was to provide a set of baseline data on sediment characteristics known to directly influence (1) the penetration of oil into coastal sediments and (2) the efficacy of chemical and (or) bioremediation.

[Physicochemical properties of Guanting Reservoir sediment and its land application].

PubMed

Su, De-Chun; Hu, Yu-Feng; Song, Chong-Wei; Wu, Fei-Long; Liu, Pei-Bin

2007-06-01

Surface sediment of Guanting Reservoir was dredged up and dewatered in field, and pollutant and physicochemical characterizations were mensurated. The stabilization and agricultural land use of the sediment was also studied in the field. Results showed that the sediments have a higher clay content, bulk density (1.89 g x cm(-3)) and lower porosity (23.8%), higher deoxidize material and available nitrogen, phosphorus concentration. Heavy metal and organochlorinated pesticides concentration was lower than the class II of national standard for soil. Stabilized the sediment with sand soil and straw could improve the physical property and decrease the concentration of deoxidize material and available nitrogen, phosphorus. Stabilized sediment could be a suitable medium for alfalfa, tree and corn growth and used for agricultural land.

Sediment Transport from Urban, Urbanizing, and Rural Areas in Johnson County, Kansas, 2006-08

USGS Publications Warehouse

Lee, Casey J.

2013-01-01

1. Studies have commonly illustrated that erosion and sediment transport from construction sites is extensive, typically 10-100X that of background levels. 2. However, to our knowledge, the affects of construction and urbanization have rarely been assessed (1) since erosion and sediment controls have been required at construction sites, and (2) at watershed (5-65 mi2) scales. This is primarily because of difficulty characterizing sediment loads in small basins. Studies (such as that illustrated from Timble, 1999) illustrated how large changes in surface erosion may not result in substantive changes in downstream sediment loads (b/c of sediment deposition on land-surfaces, floodplains, and in stream channels). 3. Improved technology (in-situ turbidity) sensors provide a good application b/c they provide an independent surrogate of sediment concentration that is more accurate at estimating sediment concentrations and loads that instantaneous streamflow.

Mercury concentrations in estuarine sediments, Lavaca and Matagorda bays, Texas, 1992

USGS Publications Warehouse

Brown, David S.; Snyder, Grant L.; Taylor, R. Lynn

1998-01-01

U.S. Environmental Protection Agency Method 7471 (Cold Vapor Atomic Absorption) was an acceptable analytical method for determining the total mercury concentrations in the Lavaca-Matagorda Bays estuarine sediment samples. Measurement of additional trace metals would aid in the characterization of total mercury concentrations and in the identification of concentrator/collector relations that are principally responsible for the adsorption of mercurous compounds to particulates in the bottom sediments.

Mössbauer study of sediment alteration produced by heat treatment

NASA Astrophysics Data System (ADS)

Labenski de Kanter, F.; Duhalde, S.; Saragovi, C.; March, R. J.

1994-12-01

Pincenvent (France) cooking-place silt-like sediments have been studied by using Mössbauer spectroscopy and characterized by using X-ray diffraction (XRD). The sediments were treated at 400, 600, 800 and 1000°C under oxidizing conditions. We discuss the results and we suggest a “Mössbauer thermometer” to be used to recognize the temperatures and atmosphere ancient people used in their cooking-places.

Detection gas presence in lakes bottom sediments based on seismic investigations.

NASA Astrophysics Data System (ADS)

Krylov, Pavel; Nurgaliev, Danis; Yasonov, Pavel

2017-04-01

Seismic investigations are used for various tasks, such as the study of the bottom sediments properties, finding sunken objects, reconstruction the reservoir history, etc. Detailed seismic investigation has been carried out in the southern part of Lake Bol'shoe Yarovoe (Altai Krai), Lake Sunukul (Chelyabinsk region), Lake Kisegach to map the bottom sediments and features associated with the presence of gas. The obtained results demonstrate that various types of gas can be recognized in lakes sediments, such as pockmarks, acoustic turbidity, gas flares, seeps. These features, on the one hand, prevent the reconstruction of sequence stratigraphic patterns and, on the other hand, contribute to understanding of the processes of gas formation and migration in the sediments, possible impacts of these processes on the formation of sediments enriched in the organic matter. Also, it helps to recognize these processes in the ancient sediments. The paper points out the importance of studying the formation of methane in lake sediments, because it plays an important role in the climate change. The work was carried out according to the Russia Government's Program of Competitive Growth of Kazan Federal University, supported by the grant provided to the Kazan State University for performing the state program in the field of scientific research, and partially supported by the Russian Foundation for Basic research (grant nos. 16-35-00452).

Installation-restoration program environmental technology development. Task Order 12. Field demonstration - composting of propellant-contaminated sediments at the Badger Army Ammunition Plant (BAAP). Final report, Jul 87-Mar 89

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, R.T.; Ziegenfuss, P.S.; Marks, P.J.

1989-03-01

A field-scale demonstration of composting propellants-contaminated sediment was conducted at the Badger Army Ammunition Plant (BAAP). Composting, as used at BAAP, is a treatment process in which organic-chemical contaminated soils or sediments are mixed with organic materials such as manure to enhance the role of microbial metabolism in degrading and stabilizing soil/sediment contaminants. Sediments contaminated with the propellant nitrocellulose (NC) were mixed with manure, alfalfa, livestock feed, and wood chips and composted in four static piles. Negative pressure aeration was used to maintain aerobiosis and remove excess heat. Experimental variables investigated during the study were temperature (mesophilic, 35 C vs.more » thermophilic, 55 C), sediment loading (19 to 32 weight percent), and NC loading. Small aliquots of compost (approximately 400 cu cm) were spiked with pure NC, placed in porous nylon bags and buried in compost piles. These bagged compost samples were used to determine if high levels of NC could be successfully composted. Thermophilic temperatures resulted in the highest percent reduction in NC concentration.« less

Detrital fingerprints of fossil continental-subduction zones (Axial Belt Provenance, European Alps)

NASA Astrophysics Data System (ADS)

Resentini, Alberto; Garzanti, Eduardo; Vezzoli, Giovanni; Andò, Sergio; Malusà, Marco G.; Padoan, Marta; Paparella, Paolo

2010-05-01

Alpine-type collision orogens are generated by attempted subduction of thinned continental margins. Because of complex tectonic structure, orogenic detritus is characterized by a range of detrital signatures, making its recognition an arduous task (Dickinson and Suczek, 1979). Among the various orogenic sub-provenances, Axial Belt Provenance, derived from the erosion of the neometamorphic axial pile, can be regarded as the most typifying signature of collision orogens (Garzanti et al., 2007). In the Austroalpine Cretaceous and Penninic Eocene axial belts of the Alps, we ideally distinguish three structural levels, each characterized by diagnostic detrital fingerprints. The shallow level chiefly consists of offscraped remnant-ocean turbidites and unmetamorphosed continental-margin sediments, and mostly produces lithic to lithoquartzose sedimentaclastic sands yielding very-poor heavy-mineral suites including ultrastable minerals. The intermediate level includes low-grade metasediments and polymetamorphic basements, and sheds lithoquartzose to quartzolithofeldspathic metamorphiclastic sands yielding moderately-rich epidote- amphibole suites with chloritoid or garnet. The deep level contains eclogitic remnants of continent- ocean transitions, and supplies quartzofeldspathic to quartzolithic high-rank metamorphiclastic to lithic ultramaficlastic sands yielding rich to extremely-rich suites dominated by garnet, hornblende, or epidote depending on protoliths (continental vs. oceanic) and pressure/temperature paths followed during exhumation. Although widely overprinted under greenschist-facies or amphibolite-facies conditions, occurrence of ultradense eclogite in source areas is readily revealed by the Heavy Mineral Concentration (HMC) index, which mirrors the average density of source rocks in the absence of hydraulic-sorting effects (Garzanti and Andò 2007). The Metamorphic Index (MI, Garzanti and Vezzoli, 2003) and Hornblende Colour Index (HCI) reflect peak temperatures reached at later stages, when subduction is throttled by arrival of thicker continental crust and geothermal gradients increase. Experience gained from modern sediments provides fundamental help to decrypt the innumerable pieces of information stored in the sedimentary record, and thus to identify and reconstruct subduction events of the past. Dickinson, W., R., Suczek, C.A., 1979.Plate tectonics and sandstone compositions. AAPG Bull. 63, 2164-2182. Garzanti, E. and Andò, S. 2007. Heavy-mineral concentration in modern sands: implications for provenance interpretation. In Mange, M., and Wright, D., eds. Heavy Minerals in Use. Developments in Sedimentology Series 58. Amsterdam, Elsevier, p. 517-545. Garzanti, E., and Vezzoli, G. 2003. A classification of metamorphic grains in sands based on their composition and grade. J. Sediment. Res. 73:830-837. Garzanti, E., Doglioni, C., Vezzoli, G., Andò, S., 2007. Orogenic belts and orogenic sediment provenante. J. Geology, 115:315-334.

Sediment compaction and pore pressure prediction in deepwater basin of the South China Sea: Estimation from ODP and IODP drilling well data

NASA Astrophysics Data System (ADS)

Xie, Yangbing; Wu, Tuoyu; Sun, Jin; Zhang, Hanyu; Wang, Jiliang; Gao, Jinwei; Chen, Chuanxu

2018-02-01

Overpressure in deepwater basins not only causes serious soft sediment deformation, but also significantly affects the safety of drilling operations. Therefore, prediction of overpressure in sediments has become an important task in deepwater oil exploration and development. In this study, we analyze the drilling data from ODP Leg 184 Sites 1144, 1146, and 1148, and IODP Leg 349 Sites U1431, U1432, U1433, and U1435 to study the sediment compaction and controls in the northern South China Sea. Sedimentation rate, sediment content, distribution area, and buried depth are the factors that influence sediment compaction in the deepwater basin of the South China Sea. Among these factors, the sediment content is the most important. The fitted normal compacted coefficients and mudline porosity for an interval of 50 m shows disciplinary variation versus depth. The pore pressure predicted from different fitted results shows varying overpressure situations. The normal compaction trend from Site 1144 reflects the porosity variation trend in stable deposition basins in the northern South China Sea. The predicted pore pressure shows overpressure at Site 1144, which is attributed to compaction disequilibrium. Nevertheless, the mixed lithology column may influence the predicted over-pressure at Site 1148, which is responsible for the confusing result. Above all, we find that sediment compaction should serve as a proxy for pore pressure in the deepwater basin of the South China Sea.

Mapping the geogenic radon potential: methodology and spatial analysis for central Hungary.

PubMed

Szabó, Katalin Zsuzsanna; Jordan, Gyozo; Horváth, Ákos; Szabó, Csaba

2014-03-01

A detailed geogenic radon potential (GRP) mapping based on field soil gas radon and soil gas permeability measurements was carried out in this study. A conventional continuous variable approach was used in this study for GRP determination and to test its applicability to the selected area of Hungary. Spatial pattern of soil gas radon concentration, soil permeability and GRP and the relationship between geological formations and these parameters were studied by performing detailed spatial analysis. Exploratory data analysis revealed that higher soil gas radon activity concentration and GRP characterizes the mountains and hills than the plains. The highest values were found in the proluvial-deluvial sediments, rock debris on the downhill slopes eroded from hills. Among the Quaternary sediments, which characterize the study area, the fluvial sediment has the highest values, which are also located in the hilly areas. The lowest values were found in the plain areas covered by drift sand, fluvioeolic sand, fluvial sand and loess. As a conclusion, radon is related to the sediment cycle in the study area. A geogenic radon risk map was created, which assists human health risk assessment and risk reduction since it indicates the potential of the source of indoor radon. The map shows that low and medium geogenic radon potential characterizes the study area in central Hungary. High risk occurs only locally. The results reveal that Quaternary sediments are inhomogeneous from a radon point of view, fluvial sediment has medium GRP, whereas the other rock formations such as drift sand, fluioeolic sand, fluvial sand and loess, found in the study area, have low GRP. Copyright © 2013 Elsevier Ltd. All rights reserved.

Insight into metabolic potential of carbon-poor pelagic sediments derived from the abundance and composition of organic carbon

NASA Astrophysics Data System (ADS)

Estes, E. R.; Hansel, C. M.; Orsi, W. D.; Anderson, C. H.; Murray, R. W.; Wankel, S. D.; Johnson, D.; Nordlund, D.; Spivack, A. J.; Sauvage, J.; McKinley, C. C.; Homola, K.; Present, T. M.; Pockalny, R. A.; D'Hondt, S.

2016-02-01

Pelagic marine sediments are often carbon-limited, with oxic sediments bearing exceedingly small concentrations of metabolizable organic carbon (OC) and anoxic sediments lacking electron acceptors to drive heterotrophy. This OC is typically considered recalcitrant and presumed to be of limited bioavailability as much of it is difficult to characterize molecularly. Here, we utilize a combination of spectrometry, spectroscopy, and fluorescent assays to characterize the OC content and composition of sediment cores from the western subtropical North Atlantic collected during R/V Knorr expedition 223 in November 2014. We find that OC concentrations decrease linearly over 15m burial depth from 0.15 to 0.075 mol OC/kg sediment, beyond which this lower OC level persists to depths approaching 30m. The ratio of organic carbon to nitrogen (C/N) varies but is consistently close to Redfield values of 6. Further, protein concentrations within the suboxic sediments are 1.75 to 4.90 μg protein/mg sediment, values in excess of predicted cell abundance in subsurface sediments. After an initial decrease in concentration between 0-3 meters below core top, protein content increases and stabilizes at 4 μg protein/mg sediment. RNA is detectable throughout the core and profiles (as μg cDNA amplified/g sediment) generally correlate with the shape of protein profiles. Combined, these results imply a small but active microbial community and the potential for these proteins to fuel heterotrophy at depth. Near-edge X-ray absorption fine structure (NEXAFS) spectroscopy finds that amide and carboxyl C functionalities comprise 25% of total spectral area, with the remainder dominated by aromatic C and O-alkyl-C groups. These findings suggest that sedimentary OC contain identifiable components, including a substantial concentration of intact proteins that may fuel heterotrophic microbial communities.

Sediment connectivity at source-bordering aeolian dunefields along the Colorado River in the Grand Canyon, USA

NASA Astrophysics Data System (ADS)

Sankey, Joel; Kasprak, Alan; Caster, Joshua; East, Amy; Fairley, Helen

2017-04-01

Aeolian dunefields that are primarily built and maintained with river-derived sediment are found in many river valleys throughout the world and are impacted by changes in climate, land use, and river regulation. Quantifying the dynamic response of these aeolian dunefields to alterations in river flow is especially difficult given the highly correlated nature of the interacting geomorphic and sediment transport processes that drive their formation and maintenance. We characterize the effects of controlled river floods on changes in sediment connectivity at source-bordering aeolian dunefields in the Grand Canyon, USA. Controlled floods from the Glen Canyon Dam are used to build sandbars along the Colorado River in Grand Canyon which provide the main sediment source for aeolian dunefields. Aeolian dunefields are a primary resource of concern for land managers in the Grand Canyon because they often contain buried archaeological features. To characterize dunefield response to controlled floods, we use a novel, automated approach for the mechanistic segregation of geomorphic change to discern the geomorphic processes responsible for driving topographic change in very high resolution digital elevation models-of-difference (DODs) that span multiple, consecutive controlled river floods at source-bordering dunefields. We subsequently compare the results of mechanistic segregation with modelled estimates of aeolian dunefield evolution in order to understand how dunefields respond to contemporary, anthropogenically-driven variability in sediment supply and connectivity. These methods provide a rapid technique for sediment budgeting and enable the inference of spatial and temporal patterns in sediment flux between the fluvial and aeolian domains. We anticipate that this approach will be adaptable to other river valleys where the interactions of aeolian, fluvial, and hillslope processes drive sediment connectivity for the maintenance of source-bordering aeolian dunefields.

Climate-scale modelling of suspended sediment load in an Alpine catchment debris flow (Rio Cordon-northeastern Italy)

NASA Astrophysics Data System (ADS)

Diodato, Nazzareno; Mao, Luca; Borrelli, Pasquale; Panagos, Panos; Fiorillo, Francesco; Bellocchi, Gianni

2018-05-01

Pulsing storms and prolonged rainfall can drive hydrological damaging events in mountain regions with soil erosion and debris flow in river catchments. The paper presents a parsimonious model for estimating climate forcing on sediment loads in an Alpine catchment (Rio Cordon, northeastern Italian Alps). Hydroclimatic forcing was interpreted by the novel CliSMSSL (Climate-Scale Modelling of Suspended Sediment Load) model to estimate annual sediment loads. We used annual data on suspended-solid loads monitored at an experimental station from 1987 to 2001 and on monthly precipitation data. The quality of sediment load data was critically examined, and one outlying year was identified and removed from further analyses. This outlier revealed that our model underestimates exceptionally high sediment loads in years characterized by a severe flood event. For all other years, the CliSMSSL performed well, with a determination coefficient (R2) equal to 0.67 and a mean absolute error (MAE) of 129 Mg y-1. The calibrated model for the period 1986-2010 was used to reconstruct sediment loads in the river catchment for historical times when detailed precipitation records are not available. For the period 1810-2010, the model results indicate that the past centuries have been characterized by large interannual to interdecadal fluctuations in the conditions affecting sediment loads. This paper argues that climate-induced erosion processes in Alpine areas and their impact on environment should be given more attention in discussions about climate-driven strategies. Future work should focus on delineating the extents of these findings (e.g., at other catchments of the European Alpine belt) as well as investigating the dynamics for the formation of sediment loads.

In Situ, High-Resolution Profiles of Labile Metals in Sediments of Lake Taihu

PubMed Central

Wang, Dan; Gong, Mengdan; Li, Yangyang; Xu, Lv; Wang, Yan; Jing, Rui; Ding, Shiming; Zhang, Chaosheng

2016-01-01

Characterizing labile metal distribution and biogeochemical behavior in sediments is crucial for understanding their contamination characteristics in lakes, for which in situ, high-resolution data is scare. The diffusive gradient in thin films (DGT) technique was used in-situ at five sites across Lake Taihu in the Yangtze River delta in China to characterize the distribution and mobility of eight labile metals (Fe, Mn, Zn, Ni, Cu, Pb, Co and Cd) in sediments at a 3 mm spatial resolution. The results showed a great spatial heterogeneity in the distributions of redox-sensitive labile Fe, Mn and Co in sediments, while other metals had much less marked structure, except for downward decreases of labile Pb, Ni, Zn and Cu in the surface sediment layers. Similar distributions were found between labile Mn and Co and among labile Ni, Cu and Zn, reflecting a close link between their geochemical behaviors. The relative mobility, defined as the ratio of metals accumulated by DGT to the total contents in a volume of sediments with a thickness of 10 mm close to the surface of DGT probe, was the greatest for Mn and Cd, followed by Zn, Ni, Cu and Co, while Pb and Fe had the lowest mobility; this order generally agreed with that defined by the modified BCR approach. Further analyses showed that the downward increases of pH values in surface sediment layer may decrease the lability of Pb, Ni, Zn and Cu as detected by DGT, while the remobilization of redox-insensitive metals in deep sediment layer may relate to Mn cycling through sulphide coprecipitation, reflected by several corresponding minima between these metals and Mn. These in situ data provided the possibility for a deep insight into the mechanisms involved in the remobilization of metals in freshwater sediments. PMID:27608033

Colloid formation in Hanford sediments reacted with simulated tank waste.

PubMed

Mashal, Kholoud; Harsh, James B; Flury, Markus; Felmy, Andrew R; Zhao, Hongting

2004-11-01

Solutions of high pH, ionic strength, and aluminum concentration have leaked into the subsurface from underground waste storage tanks atthe Hanford Reservation in Washington State. Here, we test the hypothesis that these waste solutions alter and dissolve the native minerals present in the sediments and that colloidal (diameter < 2 microm) feldspathoids form. We reacted Hanford sediments with simulated solutions representative of Hanford waste tanks. The solutions consisted of 1.4 or 2.8 mol/kg NaOH, 0.125 or 0.25 mol/kg NaAlO4, and 3.7 mol/kg NaNO3 and were contacted with the sediments for a period of 25 or 40 days at 50 degrees C. The colloidal size fraction was separated from the sediments and characterized in terms of mineralogy, morphology, chemical composition, and electrophoretic mobility. Upon reaction with tank waste solutions, native minerals released Si and other elements into the solution phase. This Si precipitated with the Al present in the waste solutions to form secondary minerals, identified as the feldspathoids cancrinite and sodalite. The solution phase was modeled with the chemical equilibrium model GMIN for solution speciation and saturation indices with respect to sodalite and cancrinite. The amount of colloidal material in the sediments increased upon reaction with waste solutions. At the natural pH found in Hanford sediments (pH 8) the newly formed minerals are negatively charged, similar to the unreacted colloidal material present in the sediments. The formation of colloidal material in Hanford sediments upon reaction with tank waste solutions is an important aspect to consider in the characterization of Hanford tank leaks and may affect the fate of hazardous radionuclides present in the tank waste.

Sediment unmixing using detrital geochronology

USGS Publications Warehouse

Sharman, Glenn R.; Johnstone, Samuel

2017-01-01

Sediment mixing within sediment routing systems can exert a strong influence on the preservation of provenance signals that yield insight into the influence of environmental forcings (e.g., tectonism, climate) on the earth’s surface. Here we discuss two approaches to unmixing detrital geochronologic data in an effort to characterize complex changes in the sedimentary record. First we summarize ‘top-down’ mixing, which has been successfully employed in the past to characterize the different fractions of prescribed source distributions (‘parents’) that characterize a derived sample or set of samples (‘daughters’). Second we propose the use of ‘bottom-up’ methods, previously used primarily for grain size distributions, to model parent distributions and the abundances of these parents within a set of daughters. We demonstrate the utility of both top-down and bottom-up approaches to unmixing detrital geochronologic data within a well-constrained sediment routing system in central California. Use of a variety of goodness-of-fit metrics in top-down modeling reveals the importance of considering the range of allowable mixtures over any single best-fit mixture calculation. Bottom-up modeling of 12 daughter samples from beaches and submarine canyons yields modeled parent distributions that are remarkably similar to those expected from the geologic context of the sediment-routing system. In general, mixture modeling has potential to supplement more widely applied approaches in comparing detrital geochronologic data by casting differences between samples as differing proportions of geologically meaningful end-member provenance categories.

Sediment unmixing using detrital geochronology

NASA Astrophysics Data System (ADS)

Sharman, Glenn R.; Johnstone, Samuel A.

2017-11-01

Sediment mixing within sediment routing systems can exert a strong influence on the preservation of provenance signals that yield insight into the effect of environmental forcing (e.g., tectonism, climate) on the Earth's surface. Here, we discuss two approaches to unmixing detrital geochronologic data in an effort to characterize complex changes in the sedimentary record. First, we summarize 'top-down' mixing, which has been successfully employed in the past to characterize the different fractions of prescribed source distributions ('parents') that characterize a derived sample or set of samples ('daughters'). Second, we propose the use of 'bottom-up' methods, previously used primarily for grain size distributions, to model parent distributions and the abundances of these parents within a set of daughters. We demonstrate the utility of both top-down and bottom-up approaches to unmixing detrital geochronologic data within a well-constrained sediment routing system in central California. Use of a variety of goodness-of-fit metrics in top-down modeling reveals the importance of considering the range of allowable that is well mixed over any single best-fit mixture calculation. Bottom-up modeling of 12 daughter samples from beaches and submarine canyons yields modeled parent distributions that are remarkably similar to those expected from the geologic context of the sediment-routing system. In general, mixture modeling has the potential to supplement more widely applied approaches in comparing detrital geochronologic data by casting differences between samples as differing proportions of geologically meaningful end-member provenance categories.

Estimating floodplain sedimentation in the Laguna de Santa Rosa, Sonoma County, CA

USGS Publications Warehouse

Curtis, Jennifer A.; Flint, Lorraine E.; Hupp, Cliff R.

2013-01-01

We present a conceptual and analytical framework for predicting the spatial distribution of floodplain sedimentation for the Laguna de Santa Rosa, Sonoma County, CA. We assess the role of the floodplain as a sink for fine-grained sediment and investigate concerns regarding the potential loss of flood storage capacity due to historic sedimentation. We characterized the spatial distribution of sedimentation during a post-flood survey and developed a spatially distributed sediment deposition potential map that highlights zones of floodplain sedimentation. The sediment deposition potential map, built using raster files that describe the spatial distribution of relevant hydrologic and landscape variables, was calibrated using 2 years of measured overbank sedimentation data and verified using longer-term rates determined using dendrochronology. The calibrated floodplain deposition potential relation was used to estimate an average annual floodplain sedimentation rate (3.6 mm/year) for the ~11 km2 floodplain. This study documents the development of a conceptual model of overbank sedimentation, describes a methodology to estimate the potential for various parts of a floodplain complex to accumulate sediment over time, and provides estimates of short and long-term overbank sedimentation rates that can be used for ecosystem management and prioritization of restoration activities.

Quantifying the main sediment sources in agricultural landscapes of Southern Brazil cultivated with conventional and conservation practices

NASA Astrophysics Data System (ADS)

Evrard, Olivier; Le Gall, Marion; Tiecher, Tales; Gomes Minella, Jean Paolo; Laceby, J. Patrick; Ayrault, Sophie

2017-04-01

Agricultural expansion that occurred in the 1960s in Southern Brazil significantly increased soil erosion and sediment supply to the river networks. To limit the deleterious impacts of soil erosion, conservation practices were progressively implemented in the 1990s, including the direct sowing of crops on a soil densely covered with plant residues, contour farming, the installation of ponds to trap sediment in the landscape and the use of crop rotations. However, there remains a lack of observational data to investigate the impact of these conservation practices on soil erosion and sediment supply. This data is crucial to protect soil resources and maintain the sustainability of food production systems in this region of the world characterized by a rapidly increasing population. Accordingly, sediment sources were investigated in the Guaporé catchment (2,032 km2) representative of the cultivated environments found in this part of the world. In the upper catchment, the landscape is characterized by gentle slopes and deep soils (Ferralsols, Nitisols) corresponding to the edge of the basaltic plateau. Soybean, corn and wheat under direct sowing are the main crops in this area. In contrast, steep and shallow soils (Luvisols, Acrisols, Leptosols) highly connected to the rivers are found in the lower catchment, where tobacco and corn fields are cultivated with conventional ploughing. These soil types were characterized by elemental geochemistry and 87Sr/86Sr ratios. Sediment sources were then modelled using the optimal suite of properties (87Sr/86Sr ratios, K, Ti, Co, As, Ba, and Pb). The results demonstrate that sediment collected at the catchment outlet during two hydrological years (2012-2014) mainly originated from downstream soils (Luvisols, Acrisols, Leptosols; 92±3%), with this proportion remaining stable throughout the monitoring period. This research indicates that conservation practices implemented in the upper catchment are effective and that similar methods should be applied to downstream soils in order to conserve soil resources and limit the degradation of freshwater environments.

Use of borehole geophysical logs for improved site characterization at Naval Weapons Industrial Reserve Plant, Dallas, Texas

USGS Publications Warehouse

Anaya, Roberto; Braun, Christopher L.; Kuniansky, Eve L.

2000-01-01

A shallow alluvial aquifer at the Naval Weapons Industrial Reserve Plant near Dallas, Texas, has been contaminated by organic solvents used in the fabrication and assembly of aircraft and aircraft parts. Natural gamma-ray and electromagnetic-induction log data collected during 1997 from 162 wells were integrated with existing lithologic and cone-penetrometer test log data to improve characterization of the subsurface alluvium at the site. The alluvium, consisting of mostly fine-grained, low-permeability sediments, was classified into low, intermediate, and high clay-content sediments on the basis of the gamma-ray logs. Low clay-content sediments were interpreted as being relatively permeable, whereas high clay-content sediments were interpreted as being relatively impermeable. Gamma-ray logs, cone-penetrometer test logs, and electromagnetic-induction logs were used to develop a series of intersecting sections to delineate the spatial distribution of low, intermediate, and high clay-content sediments and to delineate zones of potentially contaminated sediments. The sections indicate three major sedimentary units in the shallow alluvial aquifer at NWIRP. The lower unit consists of relatively permeable, low clay-content sediments and is absent over the southeastern and northwestern part of the site. Permeable zones in the complex, discontinuous middle unit are present mostly in the western part of the site. In the eastern and southeastern part of the site, the upper unit has been eroded away and replaced by fill material. Zones of potentially contaminated sediments are generally within the uppermost clay layer or fill material. In addition, the zones tend to be local occurrences.

Fish debris record the hydrothermal activity in the Atlantis II deep sediments (Red Sea)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oudin, E.; Cocherie, A.

1988-01-01

The REE and U, Th, Zr, Hf, Sc have been analyzed in samples from Atlantis II and Shaban/Jean Charcot Deeps in the Red Sea. The high Zr/Hf ratio in some sediments indicates the presence of fish debris or of finely crystallized apatite. The positive ..sigma..REE vs P/sub 2/O/sub 5/ and ..sigma..REE vs Zr/Hf correlations show that fish debris and finely crystallized apatite are the main REE sink in Atlantis II Deep sediments as in other marine environments. The hydrothermal sediments and the fish debris concentrates have similar REE patterns, characterized by a LREE enrichment and a large positive Eu anomaly.more » This REE pattern is also observed in E.P.R. hydrothermal solutions. Fish debris from marine environments acquire their REE content and signature mostly from sea water during early diagenesis. The hydrothermal REE signature of Atlantis II Deep fish debris indicate that they probably record the REE signature of their hydrothermal sedimentation and diagenetic environment. The different REE signatures of the Shaban/Jean Charcot and Atlantis II Deep hydrothermal sediments suggest a sea water-dominated brine in the Shaban/Jean Charcot Deep as opposed to the predominantly hydrothermal brine in Atlantis II Deep. Atlantis II Deep fish debris are also characterized by their high U but low Th contents. Their low Th contents probably reflect the low Th content of the various possible sources (sea water, brine, sediments). Their U contents are probably controlled by the redox conditions of sedimentation.« less

Holocene oceanographic and climatic variability of the Vega Drift deduced through foraminiferal interpretation

USGS Publications Warehouse

Szymcek, Phillip; Ishman, Scott E.; Domack, Eugene W.; Leventer, Amy

2007-01-01

fusiformis assemblages. Most agglutinated forms tend to decrease downcore, and comparisons to modern analogues imply post-depositional disintegration, while calcareous taxa indicate non-corrosive bottom waters. The lower to middle Holocene Vega Drift sediments are characterized by the calcareous S. fusiformis assemblage and glacial plume sediments. This assemblage is characterized by calcareous forms including Globocassidulina biora, G. subglobosa, and Nonionella iridea. The planktic species Neogloboquadrina pachyderma is associated with the S. fusiformis assemblage. The S. fusiformis assemblage is faunally similar to assemblages described in fjords of the western Antarctic Peninsula and indicates non-corrosive bottom water. Sediments of the mid to upper Holocene interval are characterized by the T. wiesneri and M. arenacea assemblages and indicate the presence of Hyper Saline Shelf Water. These assemblages are similar to modern assemblages directly to the south in the Prince Gustav Channel. The upper Holocene is marked by several small intervals with taxonomic characteristics similar to the S. fusiformis assemblage, indicating periodic introduction of non-corrosive bottom water to the Vega Drift

Water and sediment temperature dynamics in shallow tidal environments: The role of the heat flux at the sediment-water interface

NASA Astrophysics Data System (ADS)

Pivato, M.; Carniello, L.; Gardner, J.; Silvestri, S.; Marani, M.

2018-03-01

In the present study, we investigate the energy flux at the sediment-water interface and the relevance of the heat exchanged between water and sediment for the water temperature dynamics in shallow coastal environments. Water and sediment temperature data collected in the Venice lagoon show that, in shallow, temperate lagoons, temperature is uniform within the water column, and enabled us to estimate the net heat flux at the sediment-water interface. We modeled this flux as the sum of a conductive component and of the solar radiation reaching the bottom, finding the latter being negligible. We developed a "point" model to describe the temperature dynamics of the sediment-water continuum driven by vertical energy transfer. We applied the model considering conditions characterized by negligible advection, obtaining satisfactory results. We found that the heat exchange between water and sediment is crucial for describing sediment temperature but plays a minor role on the water temperature.

Characterization of Suspended-Sediment Loading to and from John Redmond Reservoir, East-Central Kansas, 2007-2008

USGS Publications Warehouse

Lee, Casey J.; Rasmussen, Patrick P.; Ziegler, Andrew C.

2008-01-01

Storage capacity in John Redmond Reservoir is being lost to sedimentation more rapidly than in other federal impoundments in Kansas. The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, initiated a study to characterize suspended-sediment loading to and from John Redmond Reservoir from February 21, 2007, through February 21, 2008. Turbidity sensors were installed at two U.S. Geological Survey stream gages upstream (Neosho River near Americus and the Cottonwood River near Plymouth) and one stream gage downstream (Neosho River at Burlington) from the reservoir to compute continuous, real-time (15-minute) measurements of suspended-sediment concentration and loading. About 1,120,000 tons of suspended-sediment were transported to, and 100,700 tons were transported from John Redmond Reservoir during the study period. Dependent on the bulk density of sediment stored in the reservoir, 5.0 to 1.4 percent of the storage in the John Redmond conservation pool was lost during the study period, with an average deposition of 3.4 to 1.0 inches. Nearly all (98-99 percent) of the incoming sediment load was transported during 9 storms which occurred 25 to 27 percent of the time. The largest storm during the study period (peak-flow recurrence interval of about 4.6-4.9 years) transported about 37 percent of the sediment load to the reservoir. Suspended-sediment yield from the unregulated drainage area upstream from the Neosho River near Americus was 530 tons per square mile, compared to 400 tons per square mile upstream from the Cottonwood River near Plymouth. Comparison of historical (1964-78) to current (2007) sediment loading estimates indicate statistically insignificant (99 percent) decrease in sediment loading at the Neosho River at Burlington. Ninety-percent confidence intervals of streamflow-derived estimates of total sediment load were 7 to 21 times larger than turbidity-derived estimates. Results from this study can be used by natural resource managers to calibrate sediment models and estimate the ability of John Redmond Reservoir to support designated uses into the future.

Estuarine intertidal sediment temperature variability in Zoster marina and Z. japonica habitats in Yaquina Bay, Oregon

EPA Science Inventory

Physical characterization of intertidal estuarine plant habitats over time may reveal distribution-limiting thresholds. Temperature data from loggers embedded in sediment in transects crossing Zostera marina and Z. japonica habitats in lower Yaquina Bay, Oregon display signific...

PCB Congener Sorption To Carbonaceous Sediment Components: Macroscopic Comparison And Characterization Of Sorption Kinetics And Mechanism

EPA Science Inventory

Sorption of polychlorinated biphenyls (PCBs) to sediment is a key process in determining their mobility, bioavailability, and chemical decomposition in aquatic environments. In order to examine the validity of currently used interpretation approaches for PCBs sorption, comparati...

ASSESSMENT OF MERCURY IN HYPOLIMNETIC LAKE SEDIMENTS OF VERMONT AND NEW HAMPSHIRE

EPA Science Inventory

The research is to characterize concentrations of total methylmercury in waters and surficial sediments of Vermont and New Hampshire lakes, and to relate these data to commonly measured water column chemical parameters and watershed-level physical attributes. The primary goal of...

Stability of fenbendazole suspensions for veterinary use. Correlation between zeta potential and sedimentation.

PubMed

Arias, José L; López-Viota, Margarita; Clares, Beatriz; Ruiz, Ma Adolfina

2008-08-07

In this paper we have carried out a detailed investigation of the stability and redispersibility characteristics of fenbendazole aqueous suspensions, through a thermodynamic and electrokinetic characterization, considering the effect of both pH and ionic strength. The hydrophobic character of the drug, and the surface charge and electrical double-layer thickness play an essential role in the stability of the system, hence the need for a full characterization of fenbendazole. It was found that the drug suspensions displays "delayed" or "hindered" sedimentation, determined by their hydrophobic character and their low zeta potential (indicating a small electrokinetic charge on the particles). The electrostatic repulsion between the particles is responsible for the low sedimentation volume and poor redispersibility of the drug. However, only low concentrations of AlCl(3) induced a significant effect on both the zeta potential and stability of the drug, leading to a "free-layered" sedimentation and a very easy redispersion which could be of great interest in the design of an oral pharmaceutical dosage form for veterinary.

The Road to TMDL is Paved with Good Intentions--Total Maximum Daily Loads for a Wild and Scenic River in the Southern Appalachians

Treesearch

M.S. Riedel; J.M. Vose; D.S. Leigh

2003-01-01

We monitored water quality in the Chattooga River Watershed (NE Georgia, NW South Carolina, and SW North Carolina) to compare sediment TMDLs with observed water quality. A judicial consent decree required the EPA to establish TMDLs in one year. The EPA was unable to fully characterize the sediment budgets of these streams and consequently issued phased sediment TMDLs...

High-throughput characterization of sediment organic matter by pyrolysis-gas chromatography/mass spectrometry and multivariate curve resolution: A promising analytical tool in (paleo)limnology.

PubMed

Tolu, Julie; Gerber, Lorenz; Boily, Jean-François; Bindler, Richard

2015-06-23

Molecular-level chemical information about organic matter (OM) in sediments helps to establish the sources of OM and the prevalent degradation/diagenetic processes, both essential for understanding the cycling of carbon (C) and of the elements associated with OM (toxic trace metals and nutrients) in lake ecosystems. Ideally, analytical methods for characterizing OM should allow high sample throughput, consume small amounts of sample and yield relevant chemical information, which are essential for multidisciplinary, high-temporal resolution and/or large spatial scale investigations. We have developed a high-throughput analytical method based on pyrolysis-gas chromatography/mass spectrometry and automated data processing to characterize sedimentary OM in sediments. Our method consumes 200 μg of freeze-dried and ground sediment sample. Pyrolysis was performed at 450°C, which was found to avoid degradation of specific biomarkers (e.g., lignin compounds, fresh carbohydrates/cellulose) compared to 650°C, which is in the range of temperatures commonly applied for environmental samples. The optimization was conducted using the top ten sediment samples of an annually resolved sediment record (containing 16-18% and 1.3-1.9% of total carbon and nitrogen, respectively). Several hundred pyrolytic compound peaks were detected of which over 200 were identified, which represent different classes of organic compounds (i.e., n-alkanes, n-alkenes, 2-ketones, carboxylic acids, carbohydrates, proteins, other N compounds, (methoxy)phenols, (poly)aromatics, chlorophyll and steroids/hopanoids). Technical reproducibility measured as relative standard deviation of the identified peaks in triplicate analyses was 5.5±4.3%, with 90% of the RSD values within 10% and 98% within 15%. Finally, a multivariate calibration model was calculated between the pyrolytic degradation compounds and the sediment depth (i.e., sediment age), which is a function of degradation processes and changes in OM source type. This allowed validation of the Py-GC/MS dataset against fundamental processes involved in OM cycling in aquatic ecosystems. Copyright © 2015 Elsevier B.V. All rights reserved.

Multivariate Statistical Approach Applied to Sediment Source Tracking Through Quantification and Mineral Identification, Cheyenne River, South Dakota

NASA Astrophysics Data System (ADS)

Valder, J.; Kenner, S.; Long, A.

2008-12-01

Portions of the Cheyenne River are characterized as impaired by the U.S. Environmental Protection Agency because of water-quality exceedences. The Cheyenne River watershed includes the Black Hills National Forest and part of the Badlands National Park. Preliminary analysis indicates that the Badlands National Park is a major contributor to the exceedances of the water-quality constituents for total dissolved solids and total suspended solids. Water-quality data have been collected continuously since 2007, and in the second year of collection (2008), monthly grab and passive sediment samplers are being used to collect total suspended sediment and total dissolved solids in both base-flow and runoff-event conditions. In addition, sediment samples from the river channel, including bed, bank, and floodplain, have been collected. These samples are being analyzed at the South Dakota School of Mines and Technology's X-Ray Diffraction Lab to quantify the mineralogy of the sediments. A multivariate statistical approach (including principal components, least squares, and maximum likelihood techniques) is applied to the mineral percentages that were characterized for each site to identify the contributing source areas that are causing exceedances of sediment transport in the Cheyenne River watershed. Results of the multivariate analysis demonstrate the likely sources of solids found in the Cheyenne River samples. A further refinement of the methods is in progress that utilizes a conceptual model which, when applied with the multivariate statistical approach, provides a better estimate for sediment sources.

Characteristics of sediment transport at selected sites along the Missouri River, 2011–12

USGS Publications Warehouse

Rus, David L.; Galloway, Joel M.; Alexander, Jason S.

2015-10-22

The Modified-Einstein Procedure tended to predict greater total-sediment loads when compared to measured values. These differences may be the result of sediment deficits in the Missouri River that lead to an overprediction by the Modified-Einstein Procedure, the unsampled zone above the streambed that leads to an underprediction by the suspended sampler, or general uncertainty in the sampling approach. The differences between total-sediment load obtained through measurements and that estimated from applied theoretical procedures such as the Modified-Einstein Procedure pose a challenge for reliably characterizing total-sediment transport. Though it is not clear which of the two techniques is more accurate, the general tendency of the two to be within an order of magnitude of one another may be adequate for many sediment studies.

Relation between Enterococcus concentrations and turbidity in fresh and saline recreational waters, coastal Horry County, South Carolina, 2003–04

USGS Publications Warehouse

Landmeyer, James E.; Garigen, Thomas J.

2016-06-24

The positive relation observed between turbidity and Enterococcus concentrations in surface water at the water-quality data collection station located in the channel that drains a freshwater swamp may be attributed to bacterial survival in the abundant channel bed sediments that characterized this more naturalized area. Surface-water bed sediments collected near each water-quality data collection station and the surf zone were incubated in static microcosms in the laboratory and analyzed for Enterococcus concentrations over time. Enterococcus concentrations continued to persist in bed sediments collected in the channel that drains the swamp even after almost 4 months of incubation. Conversely, enterococci were not observed to persist in bed sediments characterized by high specific conductance. Although it is currently (2016) unknown whether this persistence of enterococci demonstrates growth or viability, the data indicate that enterococci can exist in channel bed-sediment environments outside of a host for a long time. This observation confirms previous reports that challenge the use of Enterococcus concentrations as an indicator of the recent introduction of fecal-related material and the associated acute risk to other pathogens.

Characterizing suspended sediments from the Piracicaba River Basin by means of k0-INAA

NASA Astrophysics Data System (ADS)

França, E. J.; Fernandes, E. A. N.; Cavalca, I. P. O.; Fonseca, F. Y.; Camilli, L.; Rodrigues, V. S.; Bardini Junior, C.; Ferreira, J. R.; Bacchi, M. A.

2010-10-01

The inorganic chemical characterization of suspended sediments is of utmost relevance for the knowledge of the dynamics and movement of chemical elements in the aquatic and wet ecosystems. Despite the complexity of the effective design for studying this ecological compartment, this work has tested a procedure for analyzing suspended sediments by instrumental neutron activation analysis, k0 method ( k0-INAA). The chemical elements As, Ba, Br, Ca, Ce, Co, Cr, Cs, Eu, Fe, Hf, Hg, K, La, Mo, Na, Ni, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, Yb and Zn were quantified in the suspended sediment compartment by means of k0-INAA. When compared with World Average for rivers, high mass fractions of Fe (222,900 mg/kg), Ba (4990 mg/kg), Zn (1350 mg/kg), Cr (646 mg/kg), Co (74.5 mg/kg), Br (113 mg/kg) and Mo (31.9 mg/kg) were quantified in suspended sediments from the Piracicaba River, the Piracicamirim Stream and the Marins Stream. Results of the principal component analysis for standardized chemical element mass fractions indicated an intricate correlation among chemical elements evaluated, as a response of the contribution of natural and anthropogenic sources of chemical elements for ecosystems.

Sediment compaction in deepwater basin of the South China Sea: estimation from ODP 184 and IODP 349 drilling well data.

NASA Astrophysics Data System (ADS)

Tuoyu, W.; Xie, Y.

2017-12-01

Abnormal compaction in deepwater basins not only cause serious soft sediment deformation, but also significantly affect the safety of the drilling campaign. Therefore, study the compaction condition in the sediments would be an important task in the deepwater basin and associate with the environment variation. We analyze the drilling data from the ODP Leg 184 Site 1144, 1146, 1148 and the IODP Leg 349 Site U1431, U1432, U1433, U1435 to study the sediment compaction and controls in the northern South China Sea. We have found the sedimentation rate, sediment content, distribution area and buried depth control the sediment compaction in deepwater basin of the South China Sea. Among all the factors, the sediment content is the most important factor. The fitted normal compacted coefficients and the mudline porosity for interval 50 m shows disciplinary variation versus depth. The pore pressure predicted from different fitted results shows different overpressure situation. The normal compaction trend from Site 1144 reflects the porosity variation trend in stable deposition basins in the northern South China Sea. The predicted pore pressure shows overpressure at Site 1144, which is attributed to compaction disequilibrium. Nevertheless, the mixed lithology column may influence the predicted overpressure at Site 1148, which is responsible for the confusing result. Above all. we find that sediment compaction should be act as a proxy for pore pressure in the deepwater basin of the South China Sea. The study will help us to nature of sedimentation in the deepwater basin set up and can be used as analog for older sediments deposited in the similar kind of depositional environment in deepwater basin of the South China Sea.

PC-BASED SUPERCOMPUTING FOR UNCERTAINTY AND SENSITIVITY ANALYSIS OF MODELS

EPA Science Inventory

Evaluating uncertainty and sensitivity of multimedia environmental models that integrate assessments of air, soil, sediments, groundwater, and surface water is a difficult task. It can be an enormous undertaking even for simple, single-medium models (i.e. groundwater only) descr...

Characterization and physical properties of hydrate bearing sediments

NASA Astrophysics Data System (ADS)

Terzariol, M.; Santamarina, C.

2016-12-01

The amount of carbon trapped in hydrates is estimated to be larger than in conventional oil and gas reservoirs, thus methane hydrate is a promising energy resource. The high water pressure and the relatively low temperature needed for hydrate stability restrict the distribution of methane hydrates to continental shelves and permafrost regions. Stability conditions add inherent complexity to coring, sampling, handling, testing and data interpretation, have profound implications on potential production strategies. Thus a novel technology is developed for handling, transferring, and testing of natural hydrate bearing sediments without depressurization in order to preserve the sediment structure. Results from the first deployment of these tools on natural samples from Nankai Trough, Japan will also be summarized. Finally, to avoid consequences of poor sampling, a new multi-sensor in-situ characterization tool will be introduced.

Microbial Breakdown of Organic Carbon in the Diverse Sediments of Guaymas Basin

NASA Astrophysics Data System (ADS)

Hoarfrost, A.; Snider, R.; Arnosti, C.

2015-12-01

Guaymas Basin is characterized by sediments under conditions ranging from hemipelagic to hydrothermal. This wide range in geochemical contexts results in diverse microbial communities that may have varying abilities to access organic matter. We can address these functional differences by comparing enzyme activities initializing the breakdown of organic matter across these sediment types; however, previous direct measurements of the extracellular hydrolysis of complex organic carbon in sediments are sparse. We measured this first step of heterotrophic processing of organic matter in sediments at 5-10cm and 55-60cm depth from a wide range of environmental settings in Guaymas Basin. Sediment sources included sulfidic seeps on the Sonora Margin, hemipelagic ridge flank sediments, and hydrothermically altered Sonora Margin sediments bordering a methane seep site. Hydrolysis of organic substrates varied by depth and by sediment source, but despite high energy potential and organic carbon load in sulfidic sediments, activity was not highest where hydrothermal influence was highest. These results suggest that heterotrophic breakdown of organic carbon in Guaymas Basin sediments may be sensitive to factors including varying composition of organic carbon available in different sediment types, or differences in microbial community capacities to access specific organic substrates.

Recent Developments in Whole Sediment Toxicity Identification Evaluations: Innovations in Manipulations and Endpoints

EPA Science Inventory

Whole sediment Toxicity Identification Evaluation (TIE) methods were developed primarily in the late 1990s and early 2000s in research programs dedicated to developing manipulations and endpoints to characterize and identify causes of toxicity to benthic freshwater and marine org...

Developing Rapid and Cost-Effective Tools for Assessing Groundwater Impacts on Contaminated Sediments

EPA Science Inventory

This research developed quick and inexpensive methods that can be useful in characterizing the interaction of water and solids within the GW/SW transition zone to explain processes that occur during physical contact between groundwater and sediments. The research used self-conta...

Inorganic and organic characterization of dredged sediments from the proposed Quonset Point Channel in Narragansett Bay

DOT National Transportation Integrated Search

2003-01-01

The purpose of this study is to provide a preliminary analysis of organic and inorganic contaminants in sediments from the Quonset Point and Davisville areas in Narragansett Bay, Rhode Island. Of particular interest is whether the level of contaminat...

Evolving Role of Passive Samplers in Whole Sediment Toxicity Identification Evaluations

EPA Science Inventory

In Phase I of whole sediment TIEs, causes of toxicity to freshwater and marine organisms are characterized into broad toxicant classes including ammonia, metals and organic chemicals. In Phase II of the TIE, the specific toxicants causing observed toxicity are identified. For a...

Decision scenario analysis for addressing sediment accumulation in Lago Lucchetti, Puerto Rico

EPA Science Inventory

A Bayesian belief network (BBN) was used to characterize the effects of sediment accumulation on water storage capacity of a reservoir (Lago Lucchetti) in southwest Puerto Rico and the potential of different management options to increase reservoir life expectancy. Water and sedi...

Plutonium isotopes offer an alternative approach to establishing chronological profiles in coarse sediments

NASA Astrophysics Data System (ADS)

Pondell, C.; Kuehl, S. A.; Canuel, E. A.

2016-12-01

There are several methodologies used to determine chronologies for sediments deposited within the past 100 years, including 210Pb and 137Cs radioisotopes and organic and inorganic contaminants. These techniques are quite effective in fine sediments, which generally have a high affinity for metals and organic compounds. However, the application of these chronological tools becomes limited in systems where coarse sediments accumulate. Englebright Lake is an impoundment in northern California where sediment accumulation is characterized by a combination of fine and coarse sediments. This combination of sediment grain size complicated chronological analysis using the more traditional 137Cs chronological approach. This study established a chronology of these sediments using 239+240Pu isotopes. While most of the 249+240Pu activity was measured in the fine grain size fraction (<63 microns), up to 25% of the plutonium activity was detected in the coarse size fractions of sediments from Englebright Lake. Profiles of 239+240Pu were similar to available 137Cs profiles, verifying the application of plutonium isotopes for determining sediment chronologies and expanding the established geochronology for Englebright Lake sediments. This study of sediment accumulation in Englebright Lake demonstrates the application of plutonium isotopes in establishing chronologies in coarse sediments and highlights the potential for plutonium to offer new insights into patterns of coarse sediment accumulation.

Lanthanide-labeled clay: A new method for tracing sediment transport in Karst

USGS Publications Warehouse

Mahler, B.J.; Bennett, P.C.; Zimmerman, M.

1998-01-01

Mobile sediment is a fundamental yet poorly characterized aspect of mass transport through karst aquifers. Here the development and field testing of an extremely sensitive particle tracer that may be used to characterize sediment transport in karst aquifers is described. The tracer consists of micron-size montmorillonite particles homoionized to the lanthanide form; after injection and retrieval from a ground water system, the lanthanide ions are chemically stripped from the clay and quantified by high performance liquid chromatography. The tracer meets the following desired criteria: low detection limit; a number of differentiable signatures; inexpensive production and quantification using standard methods; no environmental risks; and hydrodynamic properties similar to the in situ sediment it is designed to trace. The tracer was tested in laboratory batch experiments and field tested in both surface water and ground water systems. In surface water, arrival times of the tracer were similar to those of a conservative water tracer, although a significant amount of material was lost due to settling. Two tracer tests were undertaken in a karst aquifer under different flow conditions. Under normal flow conditions, the time of arrival and peak concentration of the tracer were similar to or preceded that of a conservative water tracer. Under low flow conditions, the particle tracer was not detected, suggesting that in low flow the sediment settles out of suspension and goes into storage.Mobile sediment is a fundamental yet poorly characterized aspect of mass transport through karst aquifers. Here the development and field testing of an extremely sensitive particle tracer that may be used to characterize sediment transport in karst aquifers is described. The tracer consists of micron-size montmorillonite particles homoionized to the lanthanide form; after injection and retrieval from a ground water system, the lanthanide ions are chemically stripped from the clay and quantified by high performance liquid chromatography. The tracer meets the following desired criteria: low detection limit; a number of differentiable signatures; inexpensive production and quantification using standard methods; no environmental risks; and hydrodynamic properties similar to the in situ sediment it is designed to trace. The tracer was tested in laboratory batch experiments and field tested in both surface water and ground water systems. In surface water, arrival times of the tracer were similar to those of a conservative water tracer, although a significant amount of material was lost due to settling. Two tracer tests were undertaken in a karst aquifer under different flow conditions. Under normal flow conditions, the time of arrival and peak concentration of the tracer were similar to or preceded that of a conservative water tracer. Under low flow conditions, the particle tracer was not detected, suggesting that in low flow the sediment settles out of suspension and goes into storage.

Study of gamma spectrometry laboratory measurement in various sediment and vulcanic rocks

NASA Astrophysics Data System (ADS)

Nurhandoko, Bagus Endar B.; Kurniadi, Rizal; Rizka Asmara Hadi, Muhammad; Rizal Komara, Insan

2017-01-01

Gamma-ray spectroscopy is the quantitative study of the energy spectra of gamma-ray sources. This method is powerful to characterize some minerals, especially to differentiate rocks which contains among Potassium, Uranium, dan Thorium. Rock contains radioactive material which produce gamma rays in various energies and intensities. When these emissions are detected and analyzed with a spectroscopy system, a gamma-ray energy spectrum can be used as indicator for mineral content of rock. Some sediment and vulcanic rock have been collected from East Java Basin. Samples are ranging from Andesite vulcanics, Tuff, Shale, various vulcanic clay and Alluvial clay. We present some unique characteristics of gamma spectrometry in various sedimentar and vulcanic rocks of East Java Basins. Details contents of gamma ray spectra give enrichments to characterize sample of sediment and vulcanic in East Java. Weathered vulcanic clay has lower counting rate of gamma ray than alluvial deltaic clay counting rate. Therefore, gamma spectrometrometry can be used as tool for characterizing the enviroment of clay whether vulcanic or alluvial-deltaic. This phenomena indicates that gamma ray spectrometry can be as tool for characterizing the clay whether it tends to Smectite or Illite

Water permeability in hydrate-bearing sediments: A pore-scale study

NASA Astrophysics Data System (ADS)

Dai, Sheng; Seol, Yongkoo

2014-06-01

Permeability is a critical parameter governing methane flux and fluid flow in hydrate-bearing sediments; however, limited valid data are available due to experimental challenges. Here we investigate the relationship between apparent water permeability (k') and hydrate saturation (Sh), accounting for hydrate pore-scale growth habit and meso-scale heterogeneity. Results from capillary tube models rely on cross-sectional tube shapes and hydrate pore habits, thus are appropriate only for sediments with uniform hydrate distribution and known hydrate pore character. Given our pore network modeling results showing that accumulating hydrate in sediments decreases sediment porosity and increases hydraulic tortuosity, we propose a modified Kozeny-Carman model to characterize water permeability in hydrate-bearing sediments. This model agrees well with experimental results and can be easily implemented in reservoir simulators with no empirical variables other than Sh. Results are also relevant to flow through other natural sediments that undergo diagenesis, salt precipitation, or bio-clogging.

Overview of selected surrogate technologies for high-temporal resolution suspended-sediment monitoring

USGS Publications Warehouse

Gray, John R.; Gartner, Jeffrey W.

2010-01-01

Traditional methods for characterizing selected properties of suspended sediments in rivers are being augmented and in some cases replaced by cost-effective surrogate instruments and methods that produce a temporally dense time series of quantifiably accurate data for use primarily in sediment-flux computations. Turbidity is the most common such surrogate technology, and the first to be sanctioned by the U.S. Geological Survey for use in producing data used in concert with water-discharge data to compute sediment concentrations and fluxes for storage in the National Water Information System. Other technologies, including laser-diffraction, digital photo-optic, acoustic-attenuation and backscatter, and pressure-difference techniques are being evaluated for producing reliable sediment concentration and, in some cases, particle-size distribution data. Each technology addresses a niche for sediment monitoring. Their performances range from compelling to disappointing. Some of these technologies have the potential to revolutionize fluvial-sediment data collection, analysis, and availability.

Removal of organic matter and electricity generation of sediments from Progreso, Yucatan, Mexico, in a sediment microbial fuel cell.

PubMed

González-Gamboa, Nancy Karina; Valdés-Lozano, David Sergio; Barahona-Pérez, Luis Felipe; Alzate-Gaviria, Liliana; Domínguez-Maldonado, Jorge Arturo

2017-02-01

Sediment microbial fuel cells (SMFCs) are devices that generate electrical energy through sediments rich in organic matter (OM). The present study assessed the potential of sediments collected at two sites in Yucatan, Mexico, (the swamp of Progreso port and Yucalpetén dock) to be used in these electrochemical devices. Sediments were collected during the rainy and winter seasons and were monitored in the SMFC for 120 days through electrochemical and physicochemical characterization. OM removal in the SMFC ranged from 8.1-18.01%, generating a maximum current density of 232.46 mA/cm 2 and power density of 95.85 mW/cm 2 . SUVA analysis indicated that with a young soil, the ratio E4/E6 presented evidence directly related to the degradation of aromatic and aliphatic compound formation, implying humification and, therefore, sediment enrichment.

Seismic Site Effects from the Seafloor Motion Recorded by the Short-period Ocean Bottom Seismometers

NASA Astrophysics Data System (ADS)

Lin, J. Y.; Cheng, W. B.; Chin, S. J.; Hsu, S. K.; Dong, J. J.

2014-12-01

For decades, it has been mentioned that submarine slope failures are spatially linked to the presence of gas hydrates/gas-charged sediments. When triggered by earthquakes, oversteepen and instable sediments may prompt breakouts of the slopes containing gas hydrates and cause submarine landslides and tsunamis. Widely distributed BSRs have been observed in the area offshore of southwestern Taiwan where the active accretionary complex meets with the passive China continental margin. In the region, large or small scale landslides were also reported based on seismic interpretations. In order to clarify the link between earthquake, landslide and the presence of gas hydrate, we evaluate the response of seafloor sediments in regard to passive dynamic loads. Horizontal-to-vertical (H/V) spectral ratios are used to characterize the local sediment response. Ambient noise as well as distant earthquakes are used as generators of the passive dynamic loads. Based on this study, we aim to characterize the site in terms of its physical properties and the local site effect produced by shallow marine sediments. The results show that the maximum H/V ratios appeared in the range of 5-10 Hz, where the horizontal amplitudes increased by an order of magnitude relative to the vertical amplitude. The stations located in the northwestern part of study area were characterized by another relatively small peak at proximately 2 Hz, which may indicates the presence of a discontinuity of sediments. For most stations, the H/V ratios estimated based on the earthquake (i.e. strong input signal) and noise (background, micro-seismic noise) records were characterized by different pattern. No distinct peak is observed for the H/V pattern calculated during earthquakes. This phenomenon may suggest that no clear sedimentary boundary exist when a stronger motion applies. Estimating H/V spectral ratios of data recorded by the seven short period OBSs (Ocean Bottom Seismometer) deployed in the southwest Taiwan offshore area in April 2014 offers a general understanding of the preferential vibration modes of soft sediment systems. By comparing the resonance characteristics of each sites and the gas hydrate distribution, we hope to provide precious information for the designing of marine structures such as oil drilling and production platforms.

Characterizing the capacity of hyporheic sediments to attenuate groundwater nitrate loads by adsorption.

PubMed

Meghdadi, Aminreza

2018-05-02

Nitrate has been recognized as a global threat to environmental health. In this regard, the hyporheic zone (saturated media beneath and adjacent to the stream bed) plays a crucial role in attenuating groundwater nitrate, prior to discharge into surface water. While different nitrate removal pathways have been investigated over recent decades, the adsorption capacity of hyporheic sediments under natural conditions has not yet been identified. In this study, the natural attenuation capacity of the hyporheic-sediments of the Ghezel-Ozan River, located in the north-west of Iran, was determined. The sampled sediments (from 1 m below the stream bed) were characterized via XRD, FT-IR, BET, SEM, BJH, and Zeta potential. Nitrate adsorption was evaluated using a batch experiment with hyporheic pore-water from each study site. The study was performed in the hyporheic sediments of two morphologically different zones, including Z 1 located in the parafluvial zone having the clay sediment texture (57.8% clay) with smectite/Illite mixed layer clay type and Z 2 located in the river confluence area containing silty clay sediment texture (47.6% clay) with smectite/kaolinite mixed layer clay type. Data obtained from the batch experiment were subjected to pseudo-first order, pseudo-second order, intra-particle diffusion, and Elovich mass transfer kinetic models to characterize the nitrate adsorption mechanism. Furthermore, to replicate nitrate removal efficiencies of the hyporheic sediments under natural conditions, the sampled hyporheic pore-waters were applied as initial solutions to run the batch experiment. The results of the artificial nitrate solution correlated well with pseudo-second order (R 2 >95%; in both Z 1 and Z 2 ) and maximum removal efficiencies of 85.3% and 71.2% (adsorbent dosage 90 g/L, pH = 5.5, initial adsorbate concentration of 90 mg/L) were achieved in Z 1 and Z 2 , respectively. The results of the nitrate adsorption analysis revealed that the nitrate removal efficiencies varied from 17.24 ± 1.86% in Z 1 during the wet season to 28.13 ± 0.89% in Z 2 during the dry season. The results obtained by this study yielded strong evidence of the potential of hyporheic sediments to remove nitrate from an aqueous environment with great efficiency. Crown Copyright © 2018. Published by Elsevier Ltd. All rights reserved.

Separation, Characterization and Initial Reaction Studies of Magnetite Particles from Hanford Sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baer, Donald R.; Grosz, Andrew E.; Ilton, Eugene S.

2010-04-24

Magnetic and density separation methods have been applied to composite sediment sample from the Hanford formation from sediment recovered during drilling of an uncontaminated borehole located near the 200 West Area of the Hanford Site in southeastern Washington State. This paper describes the results of using those separation methods and from the characterization and initial reactivity measurements on a highly magnetic fraction isolated from that sediment. X-ray diffraction (XRD) analysis of the highly magnetic sediment fraction indicates that this material contains predominantly magnetite (Fe3O4). Particle morphology observed by scanning electron microscopy (SEM) and compositions determined energy dispersive spectroscopy (EDS) aremore » consistent with this identification. Analyses by X-ray photoelectron spectroscopy (XPS) indicates that there is a thin coating on the particles that are likely a type of aluminosilicate. This highly magnetic fraction of material is not reactive with indigo carmine, an organic redox probe molecule that was shown to readily react with synthetic magnetite. Because of the limited amounts of material readily available, initial tests have been conducted that demonstrate the ability to complete U(VI) sorption on individual particles (nominally ~100 µm in size) of the isolated sediment and to remove and mount these individual particles for analysis of the concentration and chemical state of the sorbed U species using small area XPS.« less

Separation, Characterization and Initial Reaction Studies of Magnetite Particles from Hanford Sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baer, Donald R.; Grosz, Andrew E.; Ilton, Eugene S.

2010-08-01

Magnetic and density separation methods have been applied to composite sediment sample from the Hanford formation from sediment recovered during drilling of an uncontaminated borehole located near the 200 West Area of the Hanford Site in southeastern Washington State. This paper describes the results of using those separation methods and from the characterization and initial reactivity measurements on a highly magnetic fraction isolated from that sediment. X-ray diffraction (XRD) analysis of the highly magnetic sediment fraction indicates that this material contains predominantly magnetite (Fe3O4). Particle morphology observed by scanning electron microscopy (SEM) and compositions determined energy dispersive spectroscopy (EDS) aremore » consistent with this identification. Analyses by X-ray photoelectron spectroscopy (XPS) indicates that there is a thin coating on the particles that are likely a type of aluminosilicate. This highly magnetic fraction of material is not reactive with indigo carmine, an organic redox probe molecule that was shown to readily react with synthetic magnetite. Because of the limited amounts of material readily available, initial tests have been conducted that demonstrate the ability to complete U(VI) sorption on individual particles (nominally ~100 µm in size) of the isolated sediment and to remove and mount these individual particles for analysis of the concentration and chemical state of the sorbed U species using small area XPS.« less

Microbial Community Structure in Lake and Wetland Sediments from a High Arctic Polar Desert Revealed by Targeted Transcriptomics

PubMed Central

Stoeva, Magdalena K.; Aris-Brosou, Stéphane; Chételat, John; Hintelmann, Holger; Pelletier, Philip; Poulain, Alexandre J.

2014-01-01

While microbial communities play a key role in the geochemical cycling of nutrients and contaminants in anaerobic freshwater sediments, their structure and activity in polar desert ecosystems are still poorly understood, both across heterogeneous freshwater environments such as lakes and wetlands, and across sediment depths. To address this question, we performed targeted environmental transcriptomics analyses and characterized microbial diversity across three depths from sediment cores collected in a lake and a wetland, located on Cornwallis Island, NU, Canada. Microbial communities were characterized based on 16S rRNA and two functional gene transcripts: mcrA, involved in archaeal methane cycling and glnA, a bacterial housekeeping gene implicated in nitrogen metabolism. We show that methane cycling and overall bacterial metabolic activity are the highest at the surface of lake sediments but deeper within wetland sediments. Bacterial communities are highly diverse and structured as a function of both environment and depth, being more diverse in the wetland and near the surface. Archaea are mostly methanogens, structured by environment and more diverse in the wetland. McrA transcript analyses show that active methane cycling in the lake and wetland corresponds to distinct communities with a higher potential for methane cycling in the wetland. Methanosarcina spp., Methanosaeta spp. and a group of uncultured Archaea are the dominant methanogens in the wetland while Methanoregula spp. predominate in the lake. PMID:24594936

Exchange across the sediment-water interface quantified from porewater radon profiles

NASA Astrophysics Data System (ADS)

Cook, Peter G.; Rodellas, Valentí; Andrisoa, Aladin; Stieglitz, Thomas C.

2018-04-01

Water recirculation through permeable sediments induced by wave action, tidal pumping and currents enhances the exchange of solutes and fine particles between sediments and overlying waters, and can be an important hydro-biogeochemical process. In shallow water, most of the recirculation is likely to be driven by the interaction of wave-driven oscillatory flows with bottom topography which can induce pressure fluctuations at the sediment-water interface on very short timescales. Tracer-based methods provide the most reliable means for characterizing this short-timescale exchange. However, the commonly applied approaches only provide a direct measure of the tracer flux. Estimating water fluxes requires characterizing the tracer concentration in discharging porewater; this implies collecting porewater samples at shallow depths (usually a few mm, depending on the hydrodynamic dispersivity), which is very difficult with commonly used techniques. In this study, we simulate observed vertical profiles of radon concentration beneath shallow coastal lagoons using a simple water recirculation model that allows us to estimate water exchange fluxes as a function of depth below the sediment-water interface. Estimated water fluxes at the sediment water interface at our site were 0.18-0.25 m/day, with fluxes decreasing exponentially with depth. Uncertainty in dispersivity is the greatest source of error in exchange flux, and results in an uncertainty of approximately a factor-of-five.

LONG-TERM RECOVERY OF PCB-CONTAMINATED SEDIMENTS AT THE LAKE HARTWELL SUPERFUND SITE: PCB DECHLORINATION. 1. END-MEMBER CHARACTERIZATION

EPA Science Inventory

Under anaerobic conditions, such as those typically found in buried sediments, the primary metabolic pathway for polychlorinated biphenyls (PCBs) is reductive dechlorination in which chlorine removal and substitution with hydrogen by bacteria result in a reduced organic compound ...

MERCURY CONCENTRATIONS IN SEDIMENT, WATER AND BIOTA COLLECTED FROM NEAR-COASTAL AREAS IMPACTED BY COMMON ESTUARINE STRESSORS

EPA Science Inventory

Mercury concentrations in non-commercial organisms indigenous to the Gulf of Mexico are not well characterized particularly when compared to potential sources. In response to this need, mercury levels were determined in sediment, water and various biota in reference and non-refer...

Effects of Stormwater Pipe Size and Rainfall on Sediment and Nutrients Delivered to a Coastal Bayou

EPA Science Inventory

Pollutants discharged from stormwater pipes can cause water quality and ecosystem problems in coastal bayous. A study was conducted to characterize sediment and nutrients discharged by small and large (, 20 cm and .20 cm in internal diameters, respectively) pipes under different ...

Oil characterization and distribution in shoreline sediments of Pensacola Bay, Florida following the Deepwater Horizon spill

EPA Science Inventory

Barrier islands of Northwest Florida were heavily oiled during the Deepwater Horizon spill, but less is known about the impacts to the shorelines of the associated estuaries. Shoreline sediment oiling was investigated at 18 sites within the Pensacola Bay, Florida system prior to...

IN-SITU REDUCTION OF CHROMIUM-CONTAMINATED GROUNDWATER, SOILS, AND SEDIMENTS BY SODIUM DITHIONITE

EPA Science Inventory

Laboratory studies were conducted to characterize the extent of chromium contamination in the groundwater and underlying soils and sediments of a chrome-plating shop at the USCG Support Center near Elizabeth City, NC. Most of the mobile Cr(VI) is present in the capillary zone ...

IN-SITU REMEDIATION OF CHROMIUM-CONTAMINATED SOILS AND SEDIMENTS

EPA Science Inventory

The objectives of this study were to characterize the extent of total chromium and Cr(VI)contamination in the underlying soils and sediments of a chrome-plating shop at the USCG Support Center near Elizabeth City, NC and to evaluate the use of liquid reductants for in situ treatm...

AN EVALUATION OF ELECTRODE INSERTION TECHNIQUES FOR MEASUREMENT OF REDOX POTENTIAL IN ESTUARINE SEDIMENTS

EPA Science Inventory

Eh measurements by electrodes are commonly used to characterize redox status of sediments in freshwater, marine and estuarine studies, due to the relative ease and rapidity of data collection. In our studies of fine-grained estuarine seabeds, we observed that Eh values measured i...

Non-halide sediments from the Loule diapir salt mine: characterization and environmental significance

NASA Astrophysics Data System (ADS)

Ribeiro, Carlos; Terrinha, Pedro; Andrade, Alexandre; Fonseca, Bruno; Caetano, Miguel; Neres, Marta; Font, Eric; Mirão, José; Dias, Cristina; Rosado, Lúcia; Maurer, Anne-France; Manhita, Ana

2017-04-01

The sedimentary record of the Mesozoic Algarve Basin (south Portugal) spans from the Triassic to the Lower Cretaceous. Following the initial phase of Pangaea breakup and the related continental sedimentation during the Triassic, the sedimentation evolved through transitional (Triassic-Jurassic transition) to marine (Jurassic) environments. During the Hettangian a thick sequence of evaporites deposited in the basin. Most of the occurrences of these deposits have undetermined volumes, due to the post depositional diapiric movements. At the central Algarve, under the town of Loulé, a salt wall of up to > 1 km across, > 3 km in length and > 2 km in height has been exploited for the chemical industry (Loulé Diapir - LD). Most of the sediments that constitute LD are halides (> 99% halite), the exception being a package of non-halide sediments, constituted by carbonates (dolomite and magnesite) and sulphates (anhydrite) in various proportions with a maximum thickness of 3 meters. This package has a distinctive mesoscopic aspect of three layers of approximately the same thickness, different colours and primary sedimentary structures: black-brow-grey, from bottom to top. The sediments of this package were studied with a multidisciplinary approach aiming their mineralogical and chemical characterization, the determination of the organic matter content and origin, as well as the characterization and understanding of the chemical processes that occurred during the emplacement and compression of the LD: (i) X-ray diffraction for the determination of the mineral phases present and semi-quantification using the RIR-Reference Intensity Ratio method; (ii) micro analysis of the mineralogical samples by Scanning Electron Microscopy coupled to Energy Dispersive Spectroscopy; (iii) REE content determination by ICP-MS; (iv) determination of the carbon content by CHN Elemental analysis; (v) determination of the organic matter content by elemental analysis and their composition by pyrolysis-GC-MS; (vi) determination of the carbon and nitrogen stable isotopic ratios of the organic matter; (vii) anisotropy of the magnetic susceptibility to study it emplacement mode. The LD is deformed by a set of shear-zones and thrusts formed during the Cenozoic Alpine compression that are underlined by the presence of a fine grained, non-halide material, whose nature and characterization was also done, using the same analytical methods. The preliminary mineralogical and geochemical results show a clear pattern in the evolution of the environmental conditions of the sedimentation with influence on the availability of the dissolved cations. The three of the sediment package showed distinct organic carbon content reaching 4.42% in the black horizon, five times the values found in the adjacent layers. By using the rare earth elements as geochemical tracers of sediment provenance, shale normalised profiles suggest that sediment particles from the three layers have the same origin. However, the non-halide sediments retained in the shear zones showed a different profile with an increase of MREE and a positive Eu anomaly. This work was done in the scope of the MEDSALT - Uncovering the Mediterranean salt giant, COST action CA15103.

Sediment sources in an urbanizing, mixed land-use watershed

NASA Astrophysics Data System (ADS)

Nelson, Erin J.; Booth, Derek B.

2002-07-01

The Issaquah Creek watershed is a rapidly urbanizing watershed of 144 km 2 in western Washington, where sediment aggradation of the main channel and delivery of fine sediment into a large downstream lake have raised increasingly frequent concerns over flooding, loss of fish habitat, and degraded water quality. A watershed-scale sediment budget was evaluated to determine the relative effects of land-use practices, including urbanization, on sediment supply and delivery, and to guide management responses towards the most effective source-reduction strategies. Human activity in the watershed, particularly urban development, has caused an increase of nearly 50% in the annual sediment yield, now estimated to be 44 tonnes km -2 yr -1. The main sources of sediment in the watershed are landslides (50%), channel-bank erosion (20%), and road-surface erosion (15%). This assessment characterizes the role of human activity in mixed-use watersheds such as this, and it demonstrates some of the key processes, particularly enhanced stream-channel erosion, by which urban development alters sediment loads.

Sharing the rivers: Balancing the needs of people and fish against the backdrop of heavy sediment loads downstream from Mount Rainier, Washington

NASA Astrophysics Data System (ADS)

Magirl, C. S.; Czuba, J. A.; Czuba, C. R.; Curran, C. A.

2012-12-01

Despite heavy sediment loads, large winter floods, and floodplain development, the rivers draining Mount Rainier, a 4,392-m glaciated stratovolcano within 85 km of sea level at Puget Sound, Washington, support important populations of anadromous salmonids, including Chinook salmon and steelhead trout, both listed as threatened under the Endangered Species Act. Aggressive river-management approaches of the early 20th century, such as bank armoring and gravel dredging, are being replaced by more ecologically sensitive approaches including setback levees. However, ongoing aggradation rates of up to 8 cm/yr in lowland reaches present acute challenges for resource managers tasked with ensuring flood protection without deleterious impacts to aquatic ecology. Using historical sediment-load data and a recent reservoir survey of sediment accumulation, rivers draining Mount Rainer were found to carry total sediment yields of 350 to 2,000 tonnes/km2/yr, notably larger than sediment yields of 50 to 200 tonnes/km2/yr typical for other Cascade Range rivers. An estimated 70 to 94% of the total sediment load in lowland reaches originates from the volcano. Looking toward the future, transport-capacity analyses and sediment-transport modeling suggest that large increases in bedload and associated aggradation will result from modest increases in rainfall and runoff that are predicted under future climate conditions. If large sediment loads and associated aggradation continue, creative solutions and long-term management strategies are required to protect people and structures in the floodplain downstream of Mount Rainier while preserving aquatic ecosystems.

Sea-Floor Character and Sedimentary Processes in the Vicinity of Woods Hole, Massachusetts

USGS Publications Warehouse

Poppe, Lawrence J.; McMullen, Katherine Y.; Foster, David S.; Blackwood, Dann S.; Williams, S. Jeffress; Ackerman, Seth D.; Barnum, Steven R.; Brennan, Rick T.

2008-01-01

Continuous-coverage multibeam bathymetric models and sidescan-sonar imagery have been verified with high-resolution seismic-reflection profiles, sediment sampling, and bottom photography. Together these data layers provide detailed base maps that yield topographic, compositional, and environmental perspectives of the sea floor in the vicinity of Woods Hole, an important harbor and major passage between the Elizabeth Islands and Cape Cod, Massachusetts. Tidally dominated high-energy environments within Woods Hole have prevented deposition of Holocene marine sediments, exposed underlying glacial drift of the Buzzards Bay moraine, and winnowed finer grained sediments, leaving lag deposits of boulders and gravel. These conditions have also enlarged and preserved depressions in the moraine surface that were originally kettle holes and formed ebb-tidal deltas at the entrances to passages. Fields of transverse and barchanoid sand waves dominate across the southern part of the study area in Vineyard Sound, where benthic environments are characterized by processes associated with coarse-bedload transport. Transverse sand waves dominate near shoals where sediment supply is greater and have asymmetries that indicate that the shoals are shaped and maintained by clockwise gyres of net sediment transport. Barchanoid sand waves, which are most common where Holocene sediments are thinner, commonly align into elongate fields that have smaller isolated waves concentrated at the eastern ends and that progressively widen and have waveforms that increase in amplitude, wavelength, and complexity westward. The northern, protected parts of the Little and Inner Harbors are characterized by muddy sediment and processes associated with deposition. A pockmark field in Little Harbor and the muddy, organic-rich sediments that form a scarp along the edge of Parker Flat are evidence for the presence of submerged marsh deposits formed during the Holocene rise in sea level.

Impact of early diagenesis and bulk particle grain size distribution on estimates of relative geomagnetic palaeointensity variations in sediments from Lama Lake, northern Central Siberia

NASA Astrophysics Data System (ADS)

Nowaczyk, Norbert R.; Harwart, Stefanie; Melles, Martin

2001-04-01

High-resolution analyses of rock magnetic and sedimentological parameters were conducted on an 11m long sediment core from Lama Lake, Northern Siberia, which encompasses the late Pleistocene and the Holocene epochs. The results reveal a strong link between the median grain size of the magnetic particles, identified as magnetite, and the oxidation state of the sediment. Reducing conditions associated with a relative high total organic carbon (TOC) content of the sediment characterize the upper 7m of the core (~Holocene), and these have led to a partial dissolution of detrital magnetite grains, and a homogenization of grain-size-related rock magnetic parameters. The anoxic sediments are characterized by significantly larger median magnetic grain sizes, as indicated, for example, by lower median destructive fields of the natural remanent magnetization (MDFNRM) and lower ratios of saturation remanence to saturation magnetization (MSR/MS). Consequently, estimates of relative geomagnetic palaeointensity variations yielded large amplitude shifts associated with anoxic/oxic boundaries. Despite the partial reductive dissolution of magnetic particles within the anoxic section, and consequent minimal variations in magnetic concentration and grain size, palaeointensity estimates for this part of the core were still lithologically distorted by the effects of particle size (and subsidiary TOC) variations. Anomalously high values coincide with an interval of significantly more fine-grained sediment, which is also associated with a decrease in TOC content, which may thus imply a decreased level of magnetite dissolution in this interval. Calculation of relative palaeointensity estimates therefore seems to be compromised by a combined effect of shifts in the particle size distribution of the bulk sediment and by partial magnetite dissolution varying in association with the TOC content of the sediment.

Organic matter in sediment layers of an acidic mining lake as assessed by lipid analysis. Part II: Neutral lipids.

PubMed

Poerschmann, Juergen; Koschorreck, Matthias; Górecki, Tadeusz

2017-02-01

Natural neutralization of acidic mining lakes is often limited by organic matter. The knowledge of the sources and degradability of organic matter is crucial for understanding alkalinity generation in these lakes. Sediments collected at different depths (surface sediment layer from 0 to 1 cm and deep sediment layer from 4 to 5cm) from an acidic mining lake were studied in order to characterize sedimentary organic matter based on neutral signature markers. Samples were exhaustively extracted, subjected to pre-chromatographic derivatizations and analyzed by GC/MS. Herein, molecular distributions of diagnostic alkanes/alkenes, terpenes/terpenoids, polycyclic aromatic hydrocarbons, aliphatic alcohols and ketones, sterols, and hopanes/hopanoids were addressed. Characterization of the contribution of natural vs. anthropogenic sources to the sedimentary organic matter in these extreme environments was then possible based on these distributions. With the exception of polycyclic aromatic hydrocarbons, combined concentrations across all marker classes proved higher in the surface sediment layer as compared to those in the deep sediment layer. Alkane and aliphatic alcohol distributions pointed to predominantly allochthonous over autochthonous contribution to sedimentary organic matter. Sterol patterns were dominated by phytosterols of terrestrial plants including stigmasterol and β-sitosterol. Hopanoid markers with the ββ-biohopanoid "biological" configuration were more abundant in the surface sediment layer, which pointed to higher bacterial activity. The pattern of polycyclic aromatic hydrocarbons pointed to prevailing anthropogenic input. Pyrolytic makers were likely to due to atmospheric deposition from a nearby former coal combustion facility. The combined analysis of the array of biomarkers provided new insights into the sources and transformations of organic matter in lake sediments. Copyright © 2016 Elsevier B.V. All rights reserved.

[Cloning, expression and characterization of a novel esterase from marine sediment microbial metagenomic library].

PubMed

Xu, Shiqing; Hu, Yongfei; Yuan, Aihua; Zhu, Baoli

2010-07-01

To clone, express and characterize a novel esterase from marine sediment microbial metagenomic library. Using esterase segregation agar containing tributyrin, we obtained esterase positive fosmid clone FL10 from marine sediment microbial metagenomic library. This fosmid was partially digested with Sau3A I to construct the sublibrary, from which the esterase positive subclone pFLS10 was obtained. The full length of the esterase gene was amplified and cloned into the expressing vector pET28a, and the recombinant plasmid was transformed into E. coli BL21 cells. We analyse the enzyme activity and study the characterization of the esterase after its expression and purification. An ORF (Open Reading Frame) of 924 bp was identified from the subclone pFLS10. Sequence analysis indicated that it showed 71% amino acid identity to esterase (ADA70030) from a marine sediment metagenomic library. The esterase is a novel low-temperature-active esterase and had highest lipolytic activity to the substrate of 4-nitrophenyl butyrate (C4). The optimum temperature of the esterase was 20 degrees C, the optimum pH was 7.5. The esterase in this study had good thermostability at 20 degrees C and good pH stability at pH8 -10. Significant increase in lipolytic activity was observed with addition of K+ and Mg2+, while decrease with Mn2+ etc. We obtained the novel esterase gene fls10 from the marine sediment microbial metagenomic library. The esterase had good thermostability and high lipolytic activity at low temperature and under basic conditions, which laid a basis for industrial application.

The deeper structure of the southern Dead Sea basin derived from neural network analysis of velocity and attenuation tomography

NASA Astrophysics Data System (ADS)

Braeuer, Benjamin; Haberland, Christian; Bauer, Klaus; Weber, Michael

2014-05-01

The Dead Sea basin is a pull-apart basin at the Dead Sea transform fault, the boundary between the African and the Arabian plates. Though the DSB has been studied for a long time, the available knowledge - based mainly on surface geology, drilling and seismic reflection surveys - gives only a partial picture of its shallow structure. Therefore, within the framework of the international DESIRE (DEad Sea Integrated REsearch) project, a dense temporary local seismological network was operated in the southern Dead Sea area. Within 18 month of recording 650 events were detected. In addition to an already published tomography study revealing the distribution of P velocities and the Vp/Vs ratios a 2D P-wave attenuation tomography (parameter Qp) was performed. The neural network technique of Self-organizing maps (SOM) is used for the joint interpretation of these three parameters (Vp, Vp/Vs, Qp). The resulting clusters in the petrophysical parameter space are assigned to the main lithological units below the southern part of the Dead Sea basin: (1) The basin sediments characterized by strong attenuation, high vp/vs ratios and low P velocities. (2) The pre-basin sediments characterized by medium to strong attenuation, low Vp/Vs ratios and medium P velocities. (3) The basement characterized by low to moderate attenuation, medium vp/vs ratios and high P velocities. Thus, the asymmetric southern Dead Sea basin is filled with basin sediments down to depth of 7 to 12 km. Below the basin sediments, the pre-basin sediments are extending to a depth between 13 and 18 km.

Conservation of the plastid sedimentation zone in all moss genera with known gravitropic protonemata

NASA Technical Reports Server (NTRS)

Schwuchow, J. M.; Kern, V. D.; White, N. J.; Sack, F. D.

2002-01-01

Moss protonemata from several species are known to be gravitropic. The characterization of additional gravitropic species would be valuable to identify conserved traits that may relate to the mechanism of gravitropism. In this study, four new species were found to have gravitropic protonemata, Fissidens adianthoides, Fissidens cristatus, Physcomitrium pyriforme, and Barbula unguiculata. Comparison of upright and inverted apical cells of P. pyriforme and Fissidens species showed clear axial sedimentation. This sedimentation is highly regulated and not solely dependent on amyloplast size. Additionally, the protonemal tip cells of these species contained broad subapical zones that displayed lateral amyloplast sedimentation. The conservation of a zone of lateral sedimentation in a total of nine gravitropic moss species from five different orders supports the idea that this sedimentation serves a specialized and conserved function in gravitropism, probably in gravity sensing.

Tracing the recently increasing anthropogenic Pb inputs into the East China Sea shelf sediments using Pb isotopic analysis.

PubMed

Wang, Deli; Zhao, Zhiqi; Dai, Minhan

2014-02-15

This study examined the Pb content and Pb isotopic composition in a sediment core taken from the East China Sea (ECS) shelf, and it was observed that since 2003 the increasing anthropogenic Pb inputs have impacted as far as the ECS shelf sediments. The ECS shelf sediments were generally characterized with low bulk Pb contents (12.5-15.0 μg/g) and relatively lithogenic Pb isotopic signatures (both HCl-leached and residual fractions). However, elevated Pb records along with lighter Pb isotopic signals have occurred in the post-2003 sediments, as a result of a small but increasing anthropogenic Pb contribution from the heavily human perturbed coastal sediments due to the sharply increasing coal consumption in mainland China since 2003. Copyright © 2013 Elsevier Ltd. All rights reserved.

Relationship between the parent material and the soil, in plain and mountainous areas

NASA Astrophysics Data System (ADS)

Kerek, Barbara; Kuti, Laszlo; Dobos, Timea; Vatai, Jozsef; Szentpetery, Ildiko

2013-04-01

One of the most important tasks of the soil is the nutrition of plants. This function is determinated by those parts of the geological media on what is the soil situated and from what the soil was formed (those two can be different). Soil can be formed definitely just from sediment, so it is more proper to speak about parent material than parent rock. Soil forming sediment is defined as the loose sediment on the surface, which is the upper layer of near-surface rocks in flat and hilly regions, and it is the upper layer of the sediment-ensemble situated on the undisturbed bedrock in mountainous areas. Considering its origin, these sediments could be autochthon or allochton. Soil forming is determinated, besides other factors (climate, elevation, vegetation, etc.), by the parent material, which has a crucial influence on the type, quality and fertility of soils through its mineral composition, physical and chemical characteristics. Agrogeological processes happen in the superficial loose sediments in mountainous areas, but the underlying solid rock (where on the surface or close to it, there is solid rock), has an effect on them. The plain and hilly regions covered by thick loose sediment and the areas build up by solid rock and covered with thinner loose sediment in mountainous areas should be searched separately. In plain areas the near-surface formations have to be studied as a whole down to the saturated zone, but at least to 10 m. In regions of mountain and mountain fronts, the thickness, the composition and genetics of the young unconsolidated sediments situated above the older solid rocks have a vital importance, and also the relations among the soils, soil forming sediments and the base rocks have to be understood.

A record of recent change in terrestrial sedimentation in a coral-reef environment, La Parguera, Puerto Rico: a response to coastal development?

PubMed

Ryan, K E; Walsh, J P; Corbett, D R; Winter, A

2008-06-01

Increased sediment flux to the coastal ocean due to coastal development is considered a major threat to the viability of coral reefs. A change in the nature of sediment supply and storage has been identified in a variety of coastal settings, particularly in response to European colonization, but sedimentation around reefs has received less attention. This research examines the sedimentary record adjacent to a coastal village that has experienced considerable land-use change over the last few decades. Sediment cores were analyzed to characterize composition and sediment accumulation rates. Sedimentation rates decreased seaward across the shelf from 0.85 cm y(-1) in a nearshore bay to 0.19 cm y(-1) in a fore-reef setting. Data reflected a significant (up to 2x) increase over the last approximately 80 years in terrestrial sediment accumulating in the back-reef setting, suggesting greater terrestrial sediment flux to the area. Reef health has declined, and increased turbidity is believed to be an important impact, particularly when combined with additional stressors.

Lithofacies and seismic-reflection interpretation of temperate glacimarine sedimentation in Tarr Inlet, Glacier Bay, Alaska

USGS Publications Warehouse

Cai, J.; Powell, R.D.; Cowan, E.A.; Carlson, P.R.

1997-01-01

High-resolution seismic-reflection profiles of sediment fill within Tart Inlet of Glacier Bay, Alaska, show seismic facies changes with increasing distance from the glacial termini. Five types of seismic facies are recognized from analysis of Huntec and minisparker records, and seven lithofacies are determined from detailed sedimentologic study of gravity-, vibro- and box-cores, and bottom grab samples. Lithofacies and seismic facies associations, and fjord-floor morphology allow us to divide the fjord into three sedimentary environments: ice-proximal, iceberg-zone and ice-distal. The ice-proximal environment, characterized by a morainal-bank depositional system, can be subdivided into bank-back, bank-core and bank-front subenvironments, each of which is characterized by a different depositional subsystem. A bank-back subsystem shows chaotic seismic facies with a mounded surface, which we infer consists mainly of unsorted diamicton and poorly sorted coarse-grained sediments. A bank-core depositional subsystem is a mixture of diamicton, rubble, gravel, sand and mud. Seismic-reflection records of this subsystem are characterized by chaotic seismic facies with abundant hyperbolic diffractions and a hummocky surface. A bank-front depositional subsystem consists of mainly stratified and massive sand, and is characterized by internal hummocky facies on seismic-reflection records with significant surface relief and sediment gravity flow channels. The depositional system formed in the iceberg-zone environment consists of rhythmically laminated mud interbedded with thin beds of weakly stratified diamicton and stratified or massive sand and silt. On seismic-reflection profiles, this depositional system is characterized by discontinuously stratified facies with multiple channels on the surface in the proximal zone and a single channel on the largely flat sediment surface in the distal zone. The depositional system formed in the ice-distal environment consists of interbedded homogeneous or laminated mud and massive or stratified sand and coarse silt. This depositional system shows continuously stratified seismic facies with smooth and flat surfaces on minisparker records, and continuously stratified seismic facies which are interlayered with thin weakly stratified facies on Huntec records.

Comparison of Methods for Characterizing Nonideal Solute Self-Association by Sedimentation Equilibrium

PubMed Central

Scott, David J.; Winzor, Donald J.

2009-01-01

Abstract We have examined in detail analytical solutions of expressions for sedimentation equilibrium in the analytical ultracentrifuge to describe self-association under nonideal conditions. We find that those containing the radial dependence of total solute concentration that incorporate the Adams-Fujita assumption for composition-dependence of activity coefficients reveal potential shortcomings for characterizing such systems. Similar deficiencies are shown in the use of the NONLIN software incorporating the same assumption about the interrelationship between activity coefficients for monomer and polymer species. These difficulties can be overcome by iterative analyses incorporating expressions for the composition-dependence of activity coefficients predicted by excluded volume considerations. A recommendation is therefore made for the replacement of current software packages by programs that incorporate rigorous statistical-mechanical allowance for thermodynamic nonideality in sedimentation equilibrium distributions reflecting solute self-association. PMID:19651047

Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation.

PubMed

Juracek, K E; Drake, K D

2016-10-01

Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

Evidence for gassy sediments on the inner shelf of SE Korea from geoacoustic properties

NASA Astrophysics Data System (ADS)

Gorgas, Thomas J.; Kim, Gil Y.; Park, Soo C.; Wilkens, Roy H.; Kim, Dae C.; Lee, Gwang H.; Seo, Young K.

2003-05-01

The inner shelf of SE Korea is characterized by an up to 40 m thick blanket of soft sediments often characterized by acoustic turbidity (AT). This AT is caused by a layer of sub-surface gas, which prohibits the identification of geological structures below that gas layer. Sound speeds were measured directly in these sediments using the Acoustic Lance (AL) in both mid- and late-September 1999. In situ sound speeds obtained in mid-September varied between 1400 and 1550 m/s, and thus did not confirm the presence of gas within the top 3.5 m of the seafloor. However, signal waveforms suggested that a gassy layer might have been just below the depth penetrated by the Lance. In late-September, on the other hand, two sites showed an abrupt decrease in signal amplitudes and in sound speed (less than 800 m/s) at depths as shallow as 2 m below seafloor, indicating the presence of free gas bubbles. Piston-cored sediments were retrieved at the same sites in February 1999. X-radiographs of some of the cores revealed numerous microcracks caused by the expansion of gas bubbles during core retrieval. In contrast to in situ acoustic data, ultrasonic sound speeds acquired in the laboratory in May 1999 on those cores did not differentiate convincingly between gas-bearing and gas-free sediments. Our measurements on the SE Korean shelf with the AL provide new data on the in situ acoustic behavior of gassy sediments and the sediments that overlie them in zones of AT.

Sediment matrix characterization as a tool for evaluating the environmental impact of heavy metals in metal mining, smelting, and ore processing areas.

PubMed

Ružičková, Silvia; Remeteiová, Dagmar; Mičková, Vladislava; Dirner, Vojtech

2018-02-21

In this work, the matrix characterization (mineralogy, total and local chemical composition, and total organic (TOC) and inorganic carbon (TIC) contents) of different types of sediments from mining- and metallurgy-influenced areas and the assessment of the impact of the matrix on the association of potentially hazardous metals with the mineral phases of these samples, which affect their mobility in the environment, are presented. For these purposes, sediment samples with different origins and from different locations in the environment were analyzed. Anthropogenic sediments from metal-rich post-flotation tailings (Lintich, Slovakia) represent waste from ore processing, natural river sediments from the Hornád River (Košice, Slovakia) represent areas influenced predominantly by the metallurgical industry, and lake sediments from a water reservoir Ružín (inflow from the Hornád and Hnilec Rivers, Slovakia) represent the impact of the metallurgical and/or mining industries. The total metal contents were determined by X-ray fluorescence (XRF) analysis, the local chemical and morphological microanalysis by scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and the TOC and TIC contents by infrared (IR) spectrometry. The mobility/bioavailability of Cu, Pb, and Zn in/from sediments at the studied areas was assessed by ethylenediaminetetraacetic acid (EDTA) and acetic acid (AA) extraction and is discussed in the context of the matrix composition. The contents of selected potentially hazardous elements in the extracts were determined by the high-resolution continuum source flame atomic absorption spectrometry (HR-CS FAAS).

Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation

NASA Astrophysics Data System (ADS)

Juracek, K. E.; Drake, K. D.

2016-10-01

Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

Deep subsurface life from North Pond: Enrichment, isolation, characterization and genomes of heterotrophic bacteria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Joseph A.; Leon-Zayas, Rosa; Wrighton, Kelly

Studies of subsurface microorganisms have yielded few environmentally relevant isolates for laboratory studies. In order to address this lack of cultivated microorganisms, we initiated several enrichments on sediment and underlying basalt samples from North Pond, a sediment basin ringed by basalt outcrops underlying an oligotrophic watercolumn west of the Mid-Atlantic Ridge at 22° N. In contrast to anoxic enrichments, growth was observed in aerobic, heterotrophic enrichments from sediment of IODP Hole U1382B at 4 and 68 m below seafloor (mbsf). These sediment depths, respectively, correspond to the fringes of oxygen penetration from overlying seawater in the top of the sedimentmore » column and upward migration of oxygen from oxic seawater from the basalt aquifer below the sediment. Here we report the enrichment, isolation, initial characterization and genomes of three isolated aerobic heterotrophs from North Pond sediments; an Arthrobacter species from 4 mbsf, and Paracoccus and Pseudomonas species from 68 mbsf. These cultivated bacteria are represented in the amplicon 16S rRNA gene libraries created from whole sediments, albeit at low (up to 2%) relative abundance. We provide genomic evidence from our isolates demonstrating that the Arthrobacter and Pseudomonas isolates have the potential to respire nitrate and oxygen, though dissimilatory nitrate reduction could not be confirmed in laboratory cultures. Furthermore, the cultures from this study represent members of abundant phyla, as determined by amplicon sequencing of environmental DNA extracts, and allow for further studies into geochemical factors impacting life in the deep subsurface.« less

Late Holocene distal mud deposits off the Nakdong delta, SE Korea: evidence for shore-parallel sediment transport in a current-dominated setting

NASA Astrophysics Data System (ADS)

Chun, Jong-Hwa; Kim, Yuri; Bahk, Jang-Jun; Kim, Young Jun; Kang, Dong-Hyo; Kim, Yong Hoon; Kim, Gil Young; Ryu, Byong-Jae

2015-12-01

The distal mud deposits (DMDs) off the Nakdong delta represent a subaqueous delta on the inner continental shelf aligned parallel to the southeast coast of Korea and displaying a clinoform geometry. Hydrographically, the coast is characterized by a micro-tidal regime, the strong Korean Coastal Current (KCC) and the East Korean Warm Current (EKWC). Age models and sedimentary facies related to the clinoform geometries are based on high-resolution chirp subbottom profile data and have provided information on shore-parallel sediment transport and accumulation during the late Holocene sea-level highstand. The highest sedimentation rates (6.19-9.17 cm/year) produced steep foresets in the central DMDs at water depths of 35-50 m. Here, vertical burrows are repeatedly truncated by laminated mud packages displaying erosional surfaces. This region represents the main depocenter of the Nakdong subaqueous delta. The topset sediments of the southern DMD at ~40 m water depth closer to the river mouth show relatively low sedimentation rates (0.01-0.12 cm/year). Here, the muds have a predominantly mottled character. Similarly, the foreset sediments of the northern DMD at ~71-80 m water depth with sedimentation rates of 0.10-2.03 cm/year are also predominantly characterized by mottled muds. The spatial dispersal pattern of the DMDs is consistent with the coast-parallel front between the KCC and EKWC along the southeast Korean coast. In addition, the depocenter of the Nakdong subaqueous delta clinoform is affected by the near-bed turbulence generated by episodic storm events.

Deep subsurface life from North Pond: Enrichment, isolation, characterization and genomes of heterotrophic bacteria

DOE PAGES

Russell, Joseph A.; Leon-Zayas, Rosa; Wrighton, Kelly; ...

2016-05-10

Studies of subsurface microorganisms have yielded few environmentally relevant isolates for laboratory studies. In order to address this lack of cultivated microorganisms, we initiated several enrichments on sediment and underlying basalt samples from North Pond, a sediment basin ringed by basalt outcrops underlying an oligotrophic watercolumn west of the Mid-Atlantic Ridge at 22° N. In contrast to anoxic enrichments, growth was observed in aerobic, heterotrophic enrichments from sediment of IODP Hole U1382B at 4 and 68 m below seafloor (mbsf). These sediment depths, respectively, correspond to the fringes of oxygen penetration from overlying seawater in the top of the sedimentmore » column and upward migration of oxygen from oxic seawater from the basalt aquifer below the sediment. Here we report the enrichment, isolation, initial characterization and genomes of three isolated aerobic heterotrophs from North Pond sediments; an Arthrobacter species from 4 mbsf, and Paracoccus and Pseudomonas species from 68 mbsf. These cultivated bacteria are represented in the amplicon 16S rRNA gene libraries created from whole sediments, albeit at low (up to 2%) relative abundance. We provide genomic evidence from our isolates demonstrating that the Arthrobacter and Pseudomonas isolates have the potential to respire nitrate and oxygen, though dissimilatory nitrate reduction could not be confirmed in laboratory cultures. Furthermore, the cultures from this study represent members of abundant phyla, as determined by amplicon sequencing of environmental DNA extracts, and allow for further studies into geochemical factors impacting life in the deep subsurface.« less

Mining-related sediment and soil contamination in a large Superfund site: Characterization, habitat implications, and remediation

USGS Publications Warehouse

Juracek, Kyle E.; Drake, K. D.

2016-01-01

Historical mining activity (1850–1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

Effects of Attenuation of Gas Hydrate-bearing Sediments on Seismic Data: Example from Mallik, Northwest Territories, Canada

NASA Astrophysics Data System (ADS)

Bellefleur, G.; Riedel, M.; Brent, T.

2007-05-01

Wave attenuation is an important physical property of hydrate-bearing sediments that is rarely taken into account in site characterization with seismic data. We present a field example showing improved images of hydrate- bearing sediments on seismic data after compensation of attenuation effects. Compressional quality factors (Q) are estimated from zero-offset Vertical Seismic Profiling data acquired at Mallik, Northwest Territories, Canada. During the last 10 years, two internationally-partnered research drilling programs have intersected three major intervals of sub-permafrost gas hydrates at Mallik, and have successfully extracted core samples containing significant amount of gas hydrates. Individual gas hydrate intervals are up to 40m in thickness and are characterized by high in situ gas hydrate saturation, sometimes exceeding 80% of pore volume of unconsolidated clastic sediments having average porosities ranging from 25% to 40%. The Q-factors obtained from the VSP data demonstrate significant wave attenuation for permafrost and hydrate- bearing sediments. These results are in agreement with previous attenuation estimates from sonic logs and crosshole data at different frequency intervals. The Q-factors obtained from VSP data were used to compensate attenuation effects on surface 3D seismic data acquired over the Mallik gas hydrate research wells. Intervals of gas hydrate on surface seismic data are characterized by strong reflectivity and effects from attenuation are not perceptible from a simple visual inspection of the data. However, the application of an inverse Q-filter increases the resolution of the data and improves correlation with log data, particularly for the shallowest gas hydrate interval. Compensation of the attenuation effects of the permafrost likely explains most of the improvements for the shallow gas hydrate zone. Our results show that characterization of the Mallik gas hydrates with seismic data not corrected for attenuation would tend to overestimate thicknesses and lateral extent of hydrate-bearing strata and hence, the volume of hydrates in place.

Using R to unravel animal-sediment interactions.

NASA Astrophysics Data System (ADS)

Soetaert, Karline

2017-04-01

Marine sediments are often characterized by seabed features ranging from small sand ripples to large sandbanks. These sediments also form the living space of many marine organisms, impacting the sediment dynamics and the geochemical cycles. In a number of projects in the Northsea, we have started to investigate these interactions, combining field sampling with laboratory experiments and modelling. R is used to interpret the various data sets and to model the effects of biology and geomorphology on the geochemistry. I will discuss these new developments in R, based on my previous R-work (packages FME, ReacTran, deSolve, rootSolve, plot3D, marelac).

Suspended sediment load, climate and relief in the central Pamirs

NASA Astrophysics Data System (ADS)

Pohl, Eric; Gloaguen, Richard; Andermann, Christoff; Schön, Ariane

2013-04-01

Relief and climate affect the generation of sediment transport. While relief and climate also affect each other, their influence on sediment transport can be investigated separately to determine their direct impact on this matter. Taking into account the complex topography of the central Pamirs and the fact that this region marks the transition zone of the Westerlies and the northward Indian Summer Monsoon, this region provides an excellent basis to investigate the interrelationship between sediment transport, climate and relief. The Panj River and its tributaries are representative for the hydrological setting of the central Pamirs as they drain most of the region. We first present suspended sediment characteristics from historical archive data for the whole river catchment and for the sub-catchments. We show the dynamics of the relationship between suspended sediment concentration and discharge on an annual basis for the different catchment sizes. The uppermost catchments are characterized by a transport-limited situation, showing a simple power-law relationship between discharge and sediment concentration for the entire year. The lowermost catchments show a strong hysteresis effect, especially in spring, which is related to the onset of snowmelt. The result is a differentiated power-law relationship within a year. As snow and glacier melt control the discharge in the central Pamirs, we investigate the climatological conditions derived from remote sensing data. We do this with respect to the different sub-catchments and with a special focus on the temporal variability. Results from the previous steps are finally interrelated with calculated geomorphological features at different catchment scales to characterize the suspended sediment load in the context of both relief and climatic conditions. Our results suggest climate to play the first-order determinant for the generation of suspended sediment load. This is in particular due to the Westerlies that provide the bulk of precipitation as snow in winter. Eventually temperature triggers snowmelt and causes high sediment loads. Still, relief causes the sediment load indirectly by forcing the climatic setting and providing the potential energy for stream flow.

Evaluation of erosion and sedimentation associated with tracked vehicle training

Treesearch

Jackie F. Crim; Jon E. Schoonover; Karl W.J. Williard; John W. Groninger; James J. Zaczek; Charles M. Ruffner

2011-01-01

A project was designed to assess erosion and sedimentation associated with tracked vehicle training in the Ft. Knox Military Reservation in Kentucky. The project provided an extensive physical and biotic characterization of the training area, including hydrology, water quality, soils, and vegetation. To determine any changes in channel morphology, cross sections were...

A Bayesian Belief Network Approach to Explore Alternative Decisions for Sediment Control and water Storage Capacity at Lago Lucchetti, Puerto Rico

EPA Science Inventory

A Bayesian belief network (BBN) was developed to characterize the effects of sediment accumulation on the water storage capacity of Lago Lucchetti (located in southwest Puerto Rico) and to forecast the life expectancy (usefulness) of the reservoir under different management scena...

Linking the historic 2011 Mississippi River flood to coastal wetland sedimentation

USGS Publications Warehouse

Falcini, Federico; Khan, Nicole S.; Macelloni, Leonardo; Horton, Benjamin P.; Lutken, Carol B.; McKee, Karen L.; Santoleri, Rosalia; Colella, Simone; Li, Chunyan; Volpe, Gianluca; D’Emidio, Marco; Salusti, Alessandro; Jerolmack, Douglas J.

2012-01-01

Wetlands in the Mississippi River deltaic plain are deteriorating in part because levees and control structures starve them of sediment. In Spring of 2011 a record-breaking flood brought discharge on the lower Mississippi River to dangerous levels, forcing managers to divert up to 3500 m3/s-1 of water to the Atchafalaya River Basin. Here we quantify differences between the Mississippi and Atchafalaya River inundation and sediment-plume patterns using field-calibrated satellite data, and assess the impact these outflows had on wetland sedimentation. We characterize hydrodynamics and suspended sediment patterns of the Mississippi River plume using in-situ data collected during the historic flood. We show that the focused, high-momentum jet from the leveed Mississippi delivered sediment far offshore. In contrast, the plume from the Atchafalaya was more diffuse; diverted water inundated a large area; and sediment was trapped within the coastal current. Maximum sedimentation (up to several centimetres) occurred in the Atchafalaya Basin despite the larger sediment load carried by the Mississippi. Minimum accumulation occurred along the shoreline between these river sources. Our findings provide a mechanistic link between river-mouth dynamics and wetland sedimentation patterns that is relevant for plans to restore deltaic wetlands using artificial diversions.

Variation of nonylphenol-degrading gene abundance and bacterial community structure in bioaugmented sediment microcosm.

PubMed

Wang, Zhao; Yang, Yuyin; Sun, Weimin; Dai, Yu; Xie, Shuguang

2015-02-01

Nonylphenol (NP) can accumulate in river sediment. Bioaugmentation is an attractive option to dissipate heavy NP pollution in river sediment. In this study, two NP degraders were isolated from crude oil-polluted soil and river sediment. Microcosms were constructed to test their ability to degrade NP in river sediment. The shift in the proportion of NP-degrading genes and bacterial community structure in sediment microcosms were characterized using quantitative PCR assay and terminal restriction fragment length polymorphism analysis, respectively. Phylogenetic analysis indicated that the soil isolate belonged to genus Stenotrophomonas, while the sediment isolate was a Sphingobium species. Both of them could almost completely clean up a high level of NP in river sediment (150 mg/kg NP) in 10 or 14 days after inoculation. An increase in the proportion of alkB and sMO genes was observed in sediment microcosms inoculated with Stenotrophomonas strain Y1 and Sphingobium strain Y2, respectively. Moreover, bioaugmentation using Sphingobium strain Y2 could have a strong impact on sediment bacterial community structure, while inoculation of Stenotrophomonas strain Y1 illustrated a weak impact. This study can provide some new insights towards NP biodegradation and bioremediation.

A sediment-dispersal model for the South Texas continental shelf, northwest Gulf of Mexico

USGS Publications Warehouse

Shideler, G.L.

1978-01-01

Textural-distribution patterns of sea-floor sediments on the South Texas continental shelf between Matagorda Bay and the U.S.-Mexico international boundary were evaluated as part of a regional environmental-studies program. Sediment textural gradients support a conceptual model for the regional sediment-dispersal system, which is characterized by both net offshore transport and net south-trending coastwise transport components on a wind-dominated shelf. Coastwise transport results in the net southward migration of both palimpsest sandy mud composing the ancestral Brazos-Colorado delta flank in the northern sector, and modern mud composing the central sector; these migrating sediments are encroaching southward onto immobile relict muddy sands composing the ancestral Rio Grande delta in the southern sector. In the proposed model, the suspension transport of modern silt-enriched mud derived mainly from coastal sources is the dominant dispersal mechanism. Net offshore transport is attributed both to diffusion, and to the advective ebb-tide discharge of turbid lagoonal-estuarine waters from coastal inlets. Net southward transport is attributed mainly to advection by seasonally residual coastwise drift currents reflecting a winter-dominated hydraulic regime. Frequent winter storms characterized by relatively high-speed northerly winds that accompany the passage of cold fronts appear to be dominant regional dispersal agents. ?? 1978.

Chemical composition of sediments from White Sea, Russian Arctic

NASA Astrophysics Data System (ADS)

Gamza, Olga; Shevchenko, Vladimir; Novigatsky, Aleksandr

2010-05-01

The White Sea, the only Russian inland sea, is located on the north of outlying districts of the European part of Russia, belongs to Arctic Ocean. Area of water of sea occupies about 90 tousend square kilometers. The sea can be divided into some general parts: neck, funnel, basin and 4 Bays: Dvina Bay, Kandalaksha Bay, Mezen Bay and Onega Bay. The purpose of this work was geochemical mapping of the surface sediments of this area. The main tasks were: compilation data base of element composition of the surface sediments, geochemical mapping of each element, research of the anormal concentration of elements on the surface. To detect the content of chemical elements several methods were used: atomic absorption spectrometry (P.P. Shirshov Institute of Oceanology); neutron activation analysis (Vernadsky Institute of Geochemistry and Analytical Chemistry), total and organic carbon analysis, photometric method to detection Si, Al, P (P.P. Shirshov Institute of Oceanology). Bulk composition is one of the fundamental characteristics of sediments and bottom deposites of modern basins. Coarse-grained sediments with portion of pelitic component <50% is spread on the shallow area (Kandalaksha Bay), in areas with high hydrodynamic activity of near-bottom water. Under the conditions of their low activity, fine-grained facies are common(>80%). Character of elements distribution correlates with facial distribution of sediments from White Sea. According to litologic description, bottom surface of Dvina Bay is practically everywhere covered by layer of fine-grained sand. In the border area between Dvina Bay and White Sea basin on terraced subwater slope aleurite politic silts are abundant. They tend to exhange down the slope to clay silts. In Onega Bay fractions of non-deposition are observed. They are characterized by wide spread of thin blanket poorgraded sediments, which are likely to be relic. Relief of Kandalakscha Bay bottom is presented as alternation of abyssal fosses (near 300 m) with silles and elevations (<20 m), and also numerous islands. Thus variety of sediment composition is observed here - from rules and gravels to fine-grained clay silts [1]. The map of distribution of chemical elements was created by using bulk composition data with the help of program ArcView. Mn distribution in sedimentation mass is largely determed by influence of redox diagenesis. Reactive form of Mn dominates over less moving, litogenic form in sedimation mass of White Sea. Litogenic form remains in sediment, reactive form moves into silt near-bottom water, resulting Mn migration both in sediment and near-bottom layer of marine water. Mn oxidizes on the contact with oxygen of marine water and alters into insoluble form MnO2, causing Mn enrichment of surface layer of sediments. Highly movable silt deposit MnO2 and enriched by Mn suspension are moved by underflow and accumulate in bottom depressions and in central part of the sea, which is quite wide from both places of original sedimentation and run off sources [2]. Thus, the interrelation between granulometric composition of sediment and materials concentration can be shown by the example of Mn. Local conditions, leading to accumulation of clastic components, are: 1. Rise of content in sand owning to separation of heavy minerals 2. Rise of content in surface, mainly sandy clay sediments owning to presence of concretions 3. Rise of content in lower bunches roof owning to diagenetic contraction. Authors thank academic Lisitsyn for encourage, Andrey Apletalin for valuable help, and everybody, who helped in field and laboratory research of the White sea sediments. Work was being done under the auspices of Russian foundation of basic research (grants 09-05-10081, 09-05-00658 and 08-05-00860), RSA presidiums program of 17 fundamental researches (project 17.1). References: 1.Kuzmina T., Lein A., Lutchsheva L., Murdmaa I., Novigatsky A., Shevchenko V. Chemical composition of White Sea's sediments // Litology and mineral deposits . 2009. - № 2. - P 115-132. 2.Nevessky E., Medvedev V. , Kalinenko V. White sea, sedimentation and holocoen developmental history. - Moscow.: Nauka, 1977. - 236 p. 3.White Sea and it water collection affected by climatic and antropogenic factors. / under the editorship of Terzhevik A., Filatov N. - Petrozavodsk.: Karelsky nauchny centr RAN, 2007. - 335p

Sequential Leaching of Chromium Contaminated Sediments - A Study Characterizing Natural Attenuation

NASA Astrophysics Data System (ADS)

Musa, D.; Ding, M.; Beroff, S.; Rearick, M.; Perkins, G.; WoldeGabriel, G. W.; Ware, D.; Harris, R.; Kluk, E.; Katzman, D.; Reimus, P. W.; Heikoop, J. M.

2015-12-01

Natural attenuation is an important process in slowing down the transport of hexavalent chromium, Cr(VI), an anthropogenic environmental contaminant, either by adsorption of Cr(VI) to sediments, or by reduction to nontoxic trivalent chromium, Cr(III). The capacity and mechanism of attenuation is explored in this sequential leaching study of different particle size fractions of chromium contaminated sediments and similar uncontaminated sediments from the regional aquifer near Los Alamos, New Mexico. Using this leaching protocol each sediment sample is split in two: one half is leached three times using a 0.1 M sodium bicarbonate/carbonate solution, while the second half is leached three times using a 0.01 M nitric acid, followed by two consecutively increasing magnitudes of nitric acid concentrations. Based on the amphoteric nature of chromium, alkaline leaching is used to establish the amount of Cr(VI) sorbed on the sediment, whereas acid leaching is used to establish the amount of Cr(III). The weak acid is predicted to release the attenuated anthropogenic Cr(III), without affecting Cr-bearing minerals. The sequential, stronger, acid is anticipated to leach Cr(III)-incorporated in the minerals. The efficiency and validation of the sequential leaching method is assessed by comparing the leaching behavior of bentonite and biotite samples, with and without loaded Cr(VI). A 97% chromium mass balance of leached Cr(VI)-loaded bentonite and biotite proves the viability of this method for further use on leaching contaminated sediments. By comparing contaminated and uncontaminated sediment leachate results, of chromium and other major and trace elements, the signature of anthropogenic chromium is determined. Further mineralogical characterization of the sediments provides a quantitative measure of the natural attenuation capacity for chromium. Understanding these results is pertinent in delineating the optimal procedure for the remediation of Cr(VI) in the regional aquifer near Los Alamos.

A conceptual review of regional-scale controls on the composition of clastic sediment and the co-evolution of continental blocks and their sedimentary cover.

PubMed

Cox, R; Lowe, D R

1995-01-02

Both sediment recycling and first-cycle input influence the composition of clastic material in sedimentary systems. This paper examines conceptually the roles played by these processes in governing the composition of clastic sediment on a regional scale by outlining the expected effects on sediment composition of protracted sediment recycling and of continuous first-cycle input on a maturing continental block. Generally speaking, long-term recycling tends to enrich sediments in the most chemically and mechanically stable components: quartz in the sand and silt size fractions, and illite among the clay minerals. Sandstones trend towards pure quartz arenites, and mudrocks become more potassic and aluminous. The average grain size of clastic sediment decreases by a combination of progressive attrition of sand grains and ongoing breakdown of primary silicate minerals to finer-grained clay minerals and oxides. Sandstones derived by continuous first-cycle input from an evolving continental crustal source also become increasingly rich in quartz, but in addition become more feldspathic as the proportion of granitic material in the upper continental crust increases during crustal stabilization. Associated mudrocks also become richer in potassium and aluminum, but will have higher K2O/Al2O3 ratios than recycled muds. The average grain size of the sediment may increase with time as the proportion of sand-prone granitic source rocks increases at the expense of more mud-prone volcanic sources. In general, except in instances where chemical weathering is extreme, first-cycle sediments lack the compositional maturity of recycled detritus, and are characterized by the presence of a variety of primary silicate minerals. Sedimentary systems are not usually completely dominated by either recycling or first-cycle detritus. Generally, however, sedimentary systems associated with the earliest phases of formation and accretion of continental crust are characterized by first-cycle input from igneous and metamorphic rocks, whereas those associated with more mature cratons tend to be dominated by recycled sedimentary material.

JV Task 92 - Alcoa/Retec SFE and SPME

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steven Hawthorne

2009-02-15

This report summarizes the work performed by the Energy & Environmental Research Center (EERC) under the U.S. Department of Energy Jointly Sponsored Research Program JV Task 92, which is a continuation of JV9. Successful studies performed in 1999 through the end of 2008 demonstrated the potential for using selective supercritical fluid extraction (SFE) and a solid-phase microextraction (SPME) method for measuring sediment pore water polycyclic aromatic hydrocarbons (PAHs) to mimic the bioavailability of PAHs from manufactured gas plant and aluminum smelter soils and sediments both in freshwater and saltwater locations. The studies that the EERC has performed with the commercialmore » partners have continued to generate increased interest in both the regulatory communities and in the industries that have historically produced or utilized coal tar products. Both ASTM International and the U.S. Environmental Protection Agency (EPA) have accepted the pore water method developed at the EERC as standard methods. The studies have demonstrated the effectiveness of our techniques in predicting bioavailability of PAHs from ca. 250 impacted and background field sediments and soils. The field demonstrations from the final years of the project continued to build the foundation data for acceptance of our methods by the regulatory communities. The JV92 studies provide the single largest database in the world that includes measures of PAH bioavailability along with biological end points. These studies clearly demonstrated that present regulatory paradigms based on equilibrium partitioning greatly overpredict bioavailability. These investigations also laid the foundation for present (non-JV) studies being applied to PAHs and polychlorinated biphenyls (PCBs) at EPA Superfund sites, investigations into PAH and PCB bioavailability at U.S Department of Defense sites, and the application of the techniques to investigating the bioavailability of chlorinated dioxins and furans from impacted sediments.« less

Shoreline changes at the mouths of the Mekong River delta over the last 50 years: fluctuating sediment supply and shoreline cells

NASA Astrophysics Data System (ADS)

Anthony, E.; Besset, M.; Brunier, G.; Dussouillez, P.; Dolique, F.; Nguyen, V. L.; Goichot, M.

2014-12-01

River delta shorelines may be characterized by complex patterns of sediment transport and sequestering at various timescales in response to changes in sediment supply, hydrodynamic conditions, and deltaic self-organization. While being good indicators of delta stability, these changes also have important coastal management and defence implications. These aspects are examined with reference to the mouths of the Mekong River delta, the world's third largest delta, backbone of the Vietnamese economy and home to nearly 20 million people. We conducted an analysis of shoreline fluctuations over the last five decades using low-resolution Landsat (1973-2014), very high-resolution SPOT 5 (2003-2011) satellite imagery, topographic maps (1950, 1965), and field hydrodynamic and shoreline topographic measurements. The results show that the 250 km-long river-mouth sector of the delta shoreline has been characterized by overall accretion but with marked temporal and spatial variations. The temporal pattern is attributed to fluctuations in sediment supply due to both human activities and natural variations in catchment sediment loads (e.g., 2000-2003), and natural adjustments in delta-plain sediment storage and delivery to the coast. The spatial pattern is indicative of discrete sediment cells that may be a response to an overall decreasing sand supply, especially since 2003, following increasingly massive riverbed mining with concomitant losses in channel-bed sand. Field measurements show the prevalence of mesotidal bar-trough beaches characterized by sand migration to the southwest in response to energetic dry-season monsoon waves. Beaches underfed as a result of both wave-energy gradients and possible diminishing sand supply from the adjacent river mouths are eroded to feed accreting beaches. Understanding this cell pattern has important implications in terms of: (1) interpreting past patterns of shoreline translation involved in the construction of successive beach ridges that characterise the prograding mouths sector of the Mekong; (2) linking shoreline stability/instability with coastal sand supply by the Mekong River and the impacts of human activities on this supply; (3) shoreline management and defence planning in the critical sandy river-mouth sector of this densely populated delta.

Spectral and Geological Characterization of Beach Components in Northern Puerto Rico

NASA Astrophysics Data System (ADS)

Caraballo Álvarez, I. O.; Torres-Perez, J. L.; Barreto, M.

2015-12-01

Understanding how changes in beach components may reflect beach processes is essential since variations along beach profiles can shed light on river and ocean processes influencing beach sedimentation and beachrock formation. It is likely these influences are related to beach proximity within the Río Grande de Manatí river mouth. Therefore, this study focuses on characterizing beach components at two sites in Manatí, Puerto Rico. Playa Machuca and Playa Tombolo, which are separated by eolianites, differ greatly in sediment size, mineralogy, and beachrock morphology. Several approaches were taken to geologically and spectrally characterize main beach components at each site. These approaches included field and microscopic laboratory identification, granulometry, and a comparison between remote sensing reflectance (Rrs) obtained with a field spectroradiometer and pre-existing spectral library signatures. Preliminary results indicate a positive correlation between each method. This study may help explore the possibility of using only Rrs to characterize beach and shallow submarine components for detailed image analysis and management of coastal features.This study focuses on characterizing beach components at two sites in Manatí, Puerto Rico. Playa Machuca and Playa Tombolo, two beaches that are separated by eolianites, differ greatly in sediment size and mineralogy, as well as in beachrock morphology. Understanding how changes in beach components may reflect beach processes is essential, since it is likely that differences are mostly related to each beaches' proximity to the Río Grande de Manatí river mouth. Hence, changes in components along beach profiles can shed light on the river's and the ocean's influence on beach sedimentation and beachrock formation. Several approaches were taken to properly geologically and spectrally characterize the main beach components at each site. These approaches included field and microscopic laboratory identification, granulometry, and a comparison between remote sensing reflectance (Rrs) obtained with a field spectroradiometer and the ENVI spectral library. Preliminary results show a positive correlation between each method. This study may help explore the possibility of using only Rrs to characterize beach and shallow submarine components for detailed image analysis and management of coastal features.

Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering/Geological Implications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, Sheng; Santamarina, J. Carlos

Fine-grained sediments host more than 90 percent of global gas hydrate accumulation. However, hydrate formation in clay-dominated sediments is less understood and characterized than other types of hydrate occurrence. There is an inadequate understanding of hydrate formation mechanisms, segregation structures, hydrate lens topology, system connectivity, and physical macro-scale properties of clay-dominated hydrate-bearing sediments. This situation hinders further analyses of the global carbon budget as well as engineering challenges/solutions related to hydrate instability and production. This project studies hydrate-bearing clay-dominated sediments with emphasis on the enhanced fundamental understanding of hydrate formation and resulting morphology, the development laboratory techniques to emulate naturalmore » hydrate formations, the assessment of analytical tools to predict physical properties, the evaluation of engineering and geological implications, and the advanced understanding of gas production potential from finegrained sediments.« less

Mixed sediment beach processes: Kachemak Bay, Alaska

USGS Publications Warehouse

Ruggiero, P.; Adams, P.N.; Warrick, J.A.

2007-01-01

Mixed sediment beaches are morphologically distinct from and more complex than either sand or gravel only beaches. Three digital imaging techniques are employed to quantify surficial grain size and bedload sediment transport rates along the mixed sediment beaches of Kachemak Bay, Alaska. Applying digital imaging procedures originally developed for quickly and efficiently quantifying grain sizes of sand to coarse sediment classes gives promising results. Hundreds of grain size estimates lead to a quantitative characterization of the region's sediment at a significant reduction in cost and time as compared to traditional techniques. Both the sand and coarse fractions on this megatidal beach mobilize into self-organized bedforms that migrate alongshore with a seasonally reflecting the temporal pattern of the alongshore component of wave power. In contrast, the gravel bedforms also migrate in the cross-shore without significant seasonally suggesting that swash asymmetry is sufficient to mobilize the gravel even during low energy summer conditions. ?? 2007 ASCE.

Multiscale Sediment-Laden Flow Theory and Its Application in Flood Risk Management

NASA Astrophysics Data System (ADS)

Cao, Z. X.; Pender, G.; Hu, P.

2011-09-01

Sediment-laden flows over erodible bed normally feature multiple time scales. The time scales of sediment transport and bed deformation relative to the flow essentially measure how fast sediment transport adapts to capacity regime in line with local flow scenario and the bed deforms as compared to the flow, which literally dictate if a capacity based and/or decoupled model is justified. This paper synthesizes the recently developed multiscale theory for sediment-laden flows over erodible bed, with bed load and suspended load transport respectively. It is unravelled that bed load transport can adapt to capacity sufficiently rapidly even under highly unsteady flows and thus a capacity model is mostly applicable, whereas a non-capacity model is critical for suspended sediment because of the lower rate of adaptation to capacity. Physically coupled modeling is critical for cases characterized by rapid bed variation. Applications are outlined on flash floods and landslide dam break floods.

Combined mineralogical and EXAFS characterization of polluted sediments for the definition of technological variables and constraints

NASA Astrophysics Data System (ADS)

Brigatti, M. F.; Elmi, C.; Laurora, A.; Malferrari, D.; Medici, L.

2009-04-01

An extremely severe aspect, both from environmental and economic viewpoint, is the management of polluted sediments removed from drainage and irrigation canals. Canals, in order to retain their functionality over the time, need to have their beds, periodically cleaned from sediments there accumulating. The management of removed sediments is extremely demanding, also from an economical perspective, if these latter needs to be treated as dangerous waste materials, as stated in numerous international standards. Furthermore the disposal of such a large amount of material may introduce a significant environmental impact as well. An appealing alternative is the recovery or reuse of these materials, for example in brick and tile industry, after obviously the application of appropriate techniques and protocols that could render these latter no longer a threat for human health. The assessment of the effective potential danger for human health and ecosystem of sediments before and after treatment obviously requires both a careful chemical and mineralogical characterization and, even if not always considered in the international standards, the definition of the coordination shell of heavy metals dangerous for human health, as a function of their oxidation state and coordination (e.g. Cr and Pb), and introducing technological constraints or affecting the features of the end products. Fe is a good representative for this second category, as the features of the end product, such as color, strongly depend not only from Fe concentration but also from its oxidation state, speciation and coordination. This work will first of all provide mineralogical characterization of sediments from various sampling points of irrigation and drainage canals of Po river region in the north-eastern of Italy. Samples were investigated with various approaches including X-ray powder diffraction under non-ambient conditions, thermal analysis and EXAFS spectroscopy. Obtained results, and in particular EXAFS spectra were used to define and optimize the technological variables of the recovery process.

Sediment data collected in 2014 and 2015 from around Breton and Gosier Islands, Breton National Wildlife Refuge, Louisiana

USGS Publications Warehouse

Bernier, Julie C.; Kelso, Kyle W.; Tuten, Thomas M.; Stalk, Chelsea A.; Flocks, James G.

2017-03-08

Breton Island, located at the southern end of the Chandeleur Islands, supports one of Louisiana’s largest historical brown pelican (Pelecanus occidentalis) nesting colonies. Although the brown pelican was delisted as an endangered species in 2009, nesting areas are threatened by continued land loss and are extremely vulnerable to storm impacts. The U.S. Fish and Wildlife Service proposed to restore Breton Island to pre-Hurricane Katrina conditions through rebuilding the shoreface, dune, and back-barrier marsh environments. Prior to restoration, scientists from the U.S. Geological Survey’s (USGS) St. Petersburg Coastal and Marine Science Center Geologic and Morphologic Evolution of Coastal Margins project collected high-resolution geophysical (topography, bathymetry, and sub-bottom profiles) and sedimentologic data from around Breton Island to characterize the geologic framework of the island platform, nearshore, and shelf environments. These data will be used to characterize the geologic framework around Breton Island, identify potential borrow areas for restoration efforts, quantify seafloor change, and provide information for sediment transport and morphologic change models to assess island response to restoration and natural processes.This report, along with the accompanying USGS data release, serves as an archive of sediment data from vibracores, push cores, and submerged grab samples collected from around Breton and Gosier Islands, Louisiana, during two surveys conducted in July 2014 and January 2015 (USGS Field Activity Numbers 2014–314–FA and 2014–336–FA, respectively). Sedimentologic and stratigraphic metrics (for example, sediment texture or unit thicknesses) derived from these data can be used to ground-truth the geophysical data and characterize potential sand resources or can be incorporated into sediment transport or morphologic change models. Data products, including sample location tables, descriptive core logs, core photographs and x-radiographs, results of sediment grain-size analyses, and geographic information system data files with accompanying formal Federal Geographic Data Committee metadata can be downloaded from the accompanying data release.

Farm-system modeling to evaluate environmental losses, profitability, and best management practice cost-effectiveness

USDA-ARS?s Scientific Manuscript database

To meet Chesapeake Bay Total Maximum Daily Load requirements for agricultural pollution, conservation districts and farmers are tasked with implementing best management practices (BMPs) that reduce farm losses of nutrients and sediment. The importance of the agricultural industry to the regional eco...

Screening of novel actinobacteria and characterization of the potential isolates from mangrove sediment of south coastal India.

PubMed

Arumugam, T; Senthil Kumar, P; Kameshwar, R; Prapanchana, K

2017-06-01

The importance of the current research is to investigate the different types of samples from the various mangrove sediments; as source of actinobacteria from the mangrove wet soil. Potential isolate screening by antimicrobial activity and identified actinobacteria was characterized based on cultural morphology, physiological and biochemical characteristics. Three different types of media were used to isolate actinobacteria from various geographical region of mangrove soil sediment and the genotype locus was recognized by 16S rDNA. Totally 144 actinobacteria isolates were recovered from 10 samples using three media. The most active culture media in the isolation of actinobacteria were ISP2 and Glycerol Yeast Extract Agar. Among 144 isolates, 38 isolates (26.38%) exhibited antimicrobial activity. Out of 38 isolates, potentially active 2 cultures were further supported for morphological and biochemical characterization analysis. Most of the isolates were produced pharmaceutically important enzymes such as protease, amylase, lipase, cellulose and also revealed antimicrobial activity against tested microorganism. The enriched salt, pH and temperature tolerance of the actinobacteria isolates to discharge commercially valuable primary and secondary bioactive metabolites. The present results functionally characterize novel mangrove actinobacteria and their metabolites for commercial interest in pharmaceutical industry. Copyright © 2017 Elsevier Ltd. All rights reserved.

Shallow geology, sea-floor texture, and physiographic zones of Buzzards Bay, Massachusetts

USGS Publications Warehouse

Foster, David S.; Baldwin, Wayne E.; Barnhardt, Walter A.; Schwab, William C.; Ackerman, Seth D.; Andrews, Brian D.; Pendleton, Elizabeth A.

2015-01-07

Geologic, sediment texture, and physiographic zone maps characterize the sea floor of Buzzards Bay, Massachusetts. These maps were derived from interpretations of seismic-reflection profiles, high-resolution bathymetry, acoustic-backscatter intensity, bottom photographs, and surficial sediment samples. The interpretation of the seismic stratigraphy and mapping of glacial and Holocene marine units provided a foundation on which the surficial maps were created. This mapping is a result of a collaborative effort between the U.S. Geological Survey and the Massachusetts Office of Coastal Zone Management to characterize the surface and subsurface geologic framework offshore of Massachusetts.

Sediment erosion and transport at the Rio Grande mouth : report for the National Border Technology Program and International Boundary and Water Commission.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chapin, D. Michael, Jr.; Langford, Richard; Neu, Roene

2003-11-01

The mouth of the Rio Grande has become silted up, obstructing its flow into the Gulf of Mexico. This is problematic in that it has created extensive flooding. The purpose of this study was to determine the erosion and transport potential of the sediments obstructing the flow of the Rio Grande by employing a unique Mobile High Shear Stress flume developed by Sandia's Carlsbad Programs Group for the US Army Corps of Engineers. The flume measures in-situ sediment erosion properties at shear stresses ranging from normal flow to flood conditions for a variable depth sediment core. The flume is inmore » a self-contained trailer that can be placed on site in the field. Erosion rates and sediment grain size distributions were determined from sediment samples collected in and around the obstruction and were subsequently used to characterize the erosion potential of the sediments under investigation.« less

Seismic profile analysis of sediment deposits in Brownlee and Hells Canyon Reservoirs near Cambridge, Idaho

USGS Publications Warehouse

Flocks, James; Kelso, Kyle; Fosness, Ryan; Welcker, Chris

2014-01-01

The U.S. Geological Survey (USGS) St. Petersburg Coastal and Marine Science Center, in cooperation with the USGS Idaho Water Science Center and the Idaho Power Company, collected high-resolution seismic reflection data in the Brownlee and Hells Canyon Reservoirs, in March of 2013.These reservoirs are located along the Snake River, and were constructed in 1958 (Brownlee) and 1967 (Hells Canyon). The purpose of the survey was to gain a better understanding of sediment accumulation within the reservoirs since their construction. The chirp system used in the survey was an EdgeTech Geo-Star Full Spectrum Sub-Bottom (FSSB) system coupled with an SB-424 towfish with a frequency range of 4 to 24 kHz. Approximately 325 kilometers of chirp data were collected, with water depths ranging from 0-90 meters. These reservoirs are characterized by very steep rock valley walls, very low flow rates, and minimal sediment input into the system. Sediments deposited in the reservoirs are characterized as highly fluid clays. Since the acoustic signal was not able to penetrate the rock substrate, only the thin veneer of these recent deposits were imaged. Results from the seismic survey indicate that throughout both of the Brownlee and Hells Canyon reservoirs the accumulation of sediments ranged from 0 to 2.5 m, with an average of 0.5 m. Areas of above average sediment accumulation may be related to lower slope, longer flooding history, and proximity to fluvial sources.

U(VI) adsorption on aquifer sediments at the Hanford Site.

PubMed

Um, Wooyong; Serne, R Jeffrey; Brown, Christopher F; Last, George V

2007-08-15

Aquifer sediments collected via split-spoon sampling in two new groundwater wells in the 200-UP-1 operable unit at the Hanford Site were characterized and showed typical Ringold Unit E Formation properties dominated by gravel and sand. High iron-oxide content in Fe oxide/clay coatings caused the highest U(VI) adsorption as quantified by batch K(d) values, indicating iron oxides are the key solid adsorbent in the 200-UP-1 sediments that affect U(VI) fate and mobility. Even though U(VI) adsorption on the gravel-sized fraction of the sediments is considered to be negligible, careful characterization should be conducted to determine U(VI) adsorption on gravel, because of presence of Fe oxides coatings and diffusion-controlled adsorption into the gravel particles' interior surfaces. A linear adsorption isotherm was observed up to 10(-6) M (238 microg/L) of total U(VI) concentration in batch U(VI) adsorption tests with varying total U(VI) concentrations in spiked groundwater. U(VI) adsorption decreased with increasing concentrations of dissolved carbonate, because strong anionic aqueous uranium-carbonate complexes formed at high pH and high alkalinity conditions. Noticeable uranium desorption hysteresis was observed in a flow-through column experiment, suggesting that desorption K(d) values for aged uranium-contaminated sediments at the Hanford Site can be larger than adsorption K(d) values determined in short-term laboratory experiments and slow uranium release from contaminated sediments into the groundwater is expected.

A scheme to scientifically and accurately assess cadmium pollution of river sediments, through consideration of bioavailability when assessing ecological risk.

PubMed

Song, Zhixin; Tang, Wenzhong; Shan, Baoqing

2017-10-01

Evaluating heavy metal pollution status and ecological risk in river sediments is a complex task, requiring consideration of contaminant pollution levels, as well as effects of biological processes within the river system. There are currently no simple or low-cost approaches to heavy metal assessment in river sediments. Here, we introduce a system of assessment for pollution status of heavy metals in river sediments, using measurements of Cd in the Shaocun River sediments as a case study. This system can be used to identify high-risk zones of the river that should be given more attention. First, we evaluated the pollution status of Cd in the river sediments based on their total Cd content, and calculated a risk assessment, using local geochemical background values at various sites along the river. Using both acetic acid and ethylenediaminetetraacetic acid to extracted the fractions of Cd in sediments, and used DGT to evaluate the bioavailability of Cd. Thus, DGT provided a measure of potentially bioavailable concentrations of Cd concentrations in the sediments. Last, we measured Cd contents in plant tissue collected at the same site to compare with our other measures. A Pearson's correlation analysis showed that Cd-Plant correlated significantly with Cd-HAc, (r = 0.788, P < 0.01), Cd-EDTA (r = 0.925, P < 0.01), Cd-DGT (r = 0.976, P < 0.01), and Cd-Total (r = 0.635, P < 0.05). We demonstrate that this system of assessment is a useful means of assessing heavy metal pollution status and ecological risk in river sediments. Copyright © 2017 Elsevier Ltd. All rights reserved.

Evaluation of toxicity to the amphipod, Hyalella azteca, and to the midge, Chironomus dilutus; and bioaccumulation by the oligochaete, Lumbriculus variegatus, with exposure to PCB-contaminated sediments from Anniston, Alabama

USGS Publications Warehouse

Ingersoll, Christopher G.; Steevens, Jeffery A.; MacDonald, Donald D.; Brumbaugh, William G.; Coady, Matthew R.; Farrar, J. Daniel; Lotufo, Guilherme R.; Kemble, Nile E.; Kunz, James L.; Stanley, Jacob K.; Sinclair, Jesse A.; Ingersoll, Christopher G.; Steevens, Jeffery A.; MacDonald, Donald D.

2014-01-01

The U.S. Environmental Protection Agency (USEPA) requested that as part of the remedial investigation for the Anniston, Alabama Polychlorinated Biphenyl (PCB) Site (Anniston PCB Site), that Pharmacia Corporation and Solutia Inc. (P/S) perform long-term reproduction toxicity tests with the amphipod, Hyalella azteca, and the midge, Chironomus dilutus, and bioaccumulation tests with the oligochaete, Lumbriculus variegatus, using sediment samples collected from reference locations and from Operable Unit 4 of the Anniston PCB Site. The sediment toxicity testing and sediment bioaccumulation results will be used by ARCADIS U.S., Inc. (ARCADIS) as part of a weight-of-evidence assessment to evaluate risks and establish sediment remediation goals for contaminants to sediment-dwelling organisms inhabiting the Anniston PCB Site. The goal of this study was to characterize relations between sediment chemistry and sediment toxicity and relations between sediment chemistry and sediment bioaccumulation in samples of sediments collected from the Anniston PCB Site. A total of 32 samples were evaluated from six test sites and one reference site to provide a wide range in concentrations of chemicals of potential concern (COPCs) including PCBs in samples of whole sediment. The goal of this study was not to determine the extent of sediment contamination across the Anniston PCB Site. Hence, the test sites or samples collected from within a test site were not selected to represent the spatial extent of sediment contamination across the Anniston PCB Site. Sediment chemistry, pore-water chemistry, and sediment toxicity data were generated for 26 sediment samples from the Anniston PCB Site. All of the samples were evaluated to determine if they qualified as reference sediment samples. Those samples that met the chemical selection criteria and biological selection criteria were identified as reference samples and used to develop the reference envelope for each toxicity test endpoint. Physical characterization of samples of whole sediment included analyses of grain size, TOC, and nutrients. Organic chemical characterization of samples of whole sediment included PCB homologs and select (13) PCB congeners, parent and alkylated polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides, and polychlorinated dibenzo-p-dioxins; and dibenzofurans. The PCB aroclors analyzed included 1016, 1221, 1232, 1242, 1248, 1254, 1260, 1262 and 1268. Analyses of whole sediment also included total metals, simultaneously extracted metals, and acid volatile sulfide. Chemical characterization of samples of pore water isolated from samples of whole sediment at the start of the sediment toxicity exposures or at the start of the sediment bioaccumulation exposures included metals, major cations, major anions, dissolved organic carbon, and additional water-quality characteristics. Concentrations of metals or PCBs in pore water during the sediment toxicity exposures or during sediment bioaccumulation exposures also were determined using peeper samples (for metals) or solid-phase microextraction (SPME) samplers (for PCBs). The bioavailability and bioaccumulation of PCBs in 14 sediment samples were investigated using SPME passive samplers and the 28-d L. variegatus whole-sediment bioaccumulation exposures In general the accumulation of PCBs consistently was predicted through the use of organic carbon normalization and equilibrium partitioning. In these sediments, PCB homologs were accumulated differently based on bioavailability and potential to accumulate in oligochaetes. As part of this assessment homolog specific biota sediment accumulation factor values were developed that could be applied across the larger site to predict tissue levels of PCBs. The whole-sediment toxicity tests done with H. azteca and C. dilutus met the established ASTM and USEPA test acceptability criteria. The most responsive H. azteca endpoints were day 42 survival normalized young per female and day 28 biomass and that the most responsive C. dilutus endpoints were adult biomass and percent adult emergence. Overall, between the two species, the most responsive endpoint assessed for these two species was H. azteca survival-normalized young per female (67 percent of the samples classified as toxic). Concentration-response models (CRMs) and site-specific sediment toxicity thresholds (TTs) were generated with matching sediment chemistry and sediment toxicity data. Sediment chemistry, pore-water chemistry, and sediment toxicity data were evaluated for as many as 26 sediment samples from the Anniston PCB Site. The reference-envelope approach was used to identify the sediment samples that were toxic to benthic invertebrates. This procedure involved identification of reference sediment samples, normalizing the toxicity data to reflect control responses, developing a reference envelope for each toxicity test endpoint, and designating each sediment sample as toxic or not toxic for each toxicity test endpoint, for each species, and for all species combined. These results demonstrated percent emergence of adult C. dilutus, biomass of adult C. dilutus, and reproduction of H. azteca normalized to percent survival were among the most responsive endpoints that were evaluated. Therefore, these endpoints were selected for CRM development. The site-specific TTs for whole sediment provide a reliable basis for identifying toxic and not toxic sediment samples in the Anniston PCB Site (that is, for correctly classifying the sediment samples used to derive the TTs as toxic or not toxic, for the endpoint used to derive the TTs). Among the 69 TTs for sediment, the TTLRs for total PCB homologs [499 to 1,870 micrograms per kilogram dry weight (μg/kg DW)] and for lead [(9.48 to 10.3 milligrams per kilogram (mg/kg) DW] based on reproduction of H. azteca or based on emergence or biomass of adult C. dilutus, were the most reliable. Such TTs had low rates of false negative errors (that is, only 0 to 11 percent of the samples below the TT were toxic to benthic invertebrates), low rates of false positive errors (only 0 to 6 percent of the samples greater than the TT were not toxic to benthic invertebrates), and high rates of correct classification (that is, 92 to 96 percent). The site-specific TTs for PCBs and other COPCs derived in this study also were compared to empirically based sediment quality guidelines (SQGs), to equilibrium-partitioning based SQGs, and to the results of spiked-sediment toxicity tests. The results of this evaluation indicated that the site-specific sediment TTs for PCBs were comparable to the consensus-based SQGs that were derived for PCBs. In addition, the site-specific sediment TTs for PCBs are well within the range of SQGs derived using the equilibrium partitioning approach. The site-specific sediment TTs for PCBs also are consistent with the results of chronic TTs that have been estimated for benthic invertebrates using the results of spiked-sediment toxicity tests. As the site-specific sediment TTs for PCBs are consistent with empirically based SQGs, equilibrium-partitioning based SQGs, and results of sediment-spiking studies, these site- specific sediment TTs likely represent the concentrations of PCBs that are sufficient to cause toxicity to benthic invertebrates (as opposed to simply being correlated with adverse effects on the survival, weight, or reproduction of benthic invertebrates). Importantly, such site-specific sediment TTs have been demonstrated to accurately classify sediment samples as toxic or not toxic to benthic invertebrates at the Anniston PCB Site. In contrast, the TTs for metals, PAHs, and organochlorine pesticides were generally lower than consensus-based SQGs (that is, probable effect concentrations), and LC50s (median lethal effect concentrations) generated in spiked-sediment toxicity tests, indicating that these COPCs are likely not the main contributors to the observed toxicity of the site sediments evaluated in this study. The reproduction endpoint for H. azteca provided lower TTs compared to the day 28 biomass endpoint for H. azteca and the emergence or biomass endpoints for adult C. dilutus provided lower TTs compared to the day 13 biomass endpoint for C. dilutus.

The nature and function of microbial enzymes in subsurface marine sediments

NASA Astrophysics Data System (ADS)

Steen, A. D.; Schmidt, J.

2016-02-01

Isotopic and genomic evidence indicates that marine sediments contain populations of active heterotrophic microorganisms which appear to metabolize old, detrital, apparently recalcitrant organic matter. In surface communities, heterotrophs use extracellular enzymes to access complex organic matter. In subsurface sediments, in which microbial doubling times can be on the order of hundreds or thousands of years, it is not clear whether extracellular enzymes could remain stable and active long enough to constitute a 'profitable' stragtegy for accessing complex organic carbon. Here we present evidence that a wide range of extracellular enzyme are active in subsurface sediments from two different environments: the White Oak River, NC, and deep (up to 80 m) sediments of the Baltic Sea Basin recovered from IODP Expedition 347. In the White Oak River, enzymes from deeper sediments appear to be better-adapted to highly-degraded organic matter than enzymes from surface sediments. In the Baltic Sea, preliminary data suggest that enzymes related to nitrogen acquisition are preferentially expressed. By characterizing the extracellular enzymes present in marine sediments, we hope to achieve a better understanding of the mechanisms that control sedimentary organic matter remineralization and preservation.

Regression modeling of particle size distributions in urban storm water: advancements through improved sample collection methods

USGS Publications Warehouse

Fienen, Michael N.; Selbig, William R.

2012-01-01

A new sample collection system was developed to improve the representation of sediment entrained in urban storm water by integrating water quality samples from the entire water column. The depth-integrated sampler arm (DISA) was able to mitigate sediment stratification bias in storm water, thereby improving the characterization of suspended-sediment concentration and particle size distribution at three independent study locations. Use of the DISA decreased variability, which improved statistical regression to predict particle size distribution using surrogate environmental parameters, such as precipitation depth and intensity. The performance of this statistical modeling technique was compared to results using traditional fixed-point sampling methods and was found to perform better. When environmental parameters can be used to predict particle size distributions, environmental managers have more options when characterizing concentrations, loads, and particle size distributions in urban runoff.

Determining Sediment Sources in the Anacostia River Watershed

NASA Astrophysics Data System (ADS)

Devereux, O. H.; Needelman, B. A.; Prestegaard, K. L.; Gellis, A. C.; Ritchie, J. C.

2005-12-01

Suspended sediment is a water-quality problem in the Chesapeake Bay. This project is designed to identify sediment sources in an urban watershed, the Northeast Branch of the Anacostia River (in Washington, D.C. and Maryland - drainage area = 188.5 km2), which delivers sediment directly to the Bay. This watershed spans two physiographic regions - the Piedmont and Coastal Plain. Bank sediment and suspended-sediment deposits were characterized using the following techniques: radionuclide (Cs-137) analysis by gamma ray spectrometry, trace-element analysis by ICP-MS, clay mineralogy by XRD, and particle-size analysis by use of a laser particle-size analyzer. Sampling of bank and suspended sediment was designed to: a) characterize tributary inputs from both Piedmont and Coastal Plain sources, and b) differentiate tributary inputs from bank erosion along the main stem of the Northeast Branch. Thirteen sample sites were chosen that represent tributary source areas of each physiographic region and the main stem where mixing occurs. Surface samples of the banks were compared to overbank deposits from a ten year storm (a proxy for the suspended sediments). Fingerprint components are selected from these data. Cesium-137 concentrations were analyzed for bank and overbank deposits for each physiographic region. No clear differences were seen between the two physiographic regions. Significant differences were observed between upland tributaries and the main stem of the Anacostia River. The average activity of Cs-137 for the tributaries was 5.4 bq/kg and the average for the main stem was 1.1 bq/kg. This suggests that there is significant erosion and storage of sediment in the tributaries. The low activity from Cs-137 in the main stem suggests a lack of storage of sediment along the main stem of the river. For the trace-element data, we focused on elements that showed significant variation among the sites. For the bank sediment, these elements include: Sr, V, Y, Ce, and Nd. For the overbank deposits, Zr, V, Ba, Ce, and Cu showed significant variability. In both physiographic regions, Pb is primarily found in bank deposits, while Cu is found in higher concentrations in overbank deposits. The Cs-137 data clearly showed the erosion and storage of sediment patterns in the watershed. The trace-element data indicate that stream banks may be differentiated from overbank deposits.

Rare earth element compositions of core sediments from the shelf of the South Sea, Korea: Their controls and origins

NASA Astrophysics Data System (ADS)

Jung, Hoi-Soo; Lim, Dhongil; Choi, Jin-Yong; Yoo, Hae-Soo; Rho, Kyung-Chan; Lee, Hyun-Bok

2012-10-01

Rare earth elements (REEs) of bulk sediments and heavy mineral samples of core sediments from the South Sea shelf, Korea, were analyzed to determine the constraints on REE concentrations and distribution patterns as well as to investigate their potential applicability for discriminating sediment provenance. Bulk sediment REEs showed large variation in concentrations and distribution patterns primarily due to grain size and carbonate dilution effects, as well as due to an abundance of heavy minerals. In the fine sandy sediments (cores EZ02-15 and 19), in particular, heavy minerals (primarily monazite and titanite/sphene) largely influenced REE compositions. Upper continental crust-normalized REE patterns of these sand-dominated sediments are characterized by enriched light REEs (LREEs), because of inclusion of heavy minerals with very high concentrations in LREEs. Notably, such a strong LREE enrichment is also observed in Korean river sediments. So, a great care must be taken when using the REE concentrations and distribution patterns of sandy and coarse silty shelf sediments as a proxy for discriminating sediment provenance. In the fine-grained muddy sediments with low heavy mineral abundance, in contrast, REE fractionation ratios and their UCC-normalized patterns seem to be reliable proxies for assessing sediment provenance. The resultant sediment origin suggested a long lateral transportation of some fine-grained Chinese river sediments (probably the Changjiang River) to the South Sea of Korea across the shelf of the northern East China Sea.

Suspended-sediment sources in an urban watershed, Northeast Branch Anacostia River, Maryland

USGS Publications Warehouse

Devereux, Olivia H.; Prestegaard, Karen L.; Needelman, Brian A.; Gellis, Allen C.

2010-01-01

Fine sediment sources were characterized by chemical composition in an urban watershed, the Northeast Branch Anacostia River, which drains to the Chesapeake Bay. Concentrations of 63 elements and two radionuclides were measured in possible land-based sediment sources and suspended sediment collected from the water column at the watershed outlet during storm events. These tracer concentrations were used to determine the relative quantity of suspended sediment contributed by each source. Although this is an urbanized watershed, there was not a distinct urban signature that can be evaluated except for the contributions from road surfaces. We identified the sources of fine sediment by both physiographic province (Piedmont and Coastal Plain) and source locale (streambanks, upland and street residue) by using different sets of elemental tracers. The Piedmont contributed the majority of the fine sediment for seven of the eight measured storms. The streambanks contributed the greatest quantity of fine sediment when evaluated by source locale. Street residue contributed 13% of the total suspended sediment on average and was the source most concentrated in anthropogenically enriched elements. Combining results from the source locale and physiographic province analyses, most fine sediment in the Northeast Branch watershed is derived from streambanks that contain sediment eroded from the Piedmont physiographic province of the watershed. Sediment fingerprinting analyses are most useful when longer term evaluations of sediment erosion and storage are also available from streambank-erosion measurements, sediment budget and other methods.

Characterizing relationships among fecal indicator bacteria, microbial source tracking markers, and associated waterborne pathogen occurrence in stream water and sediments in a mixed land use watershed

EPA Science Inventory

Bed sediments of streams and rivers may store high concentrations of fecal indicator bacteria (FIB) and pathogens. Due to resuspension events, these contaminants can be mobilized into the water column and affect overall water quality. Other bacterial indicators such as microbial ...

Benthic bacterial diversity in submerged sinkhole ecosystems.

PubMed

Nold, Stephen C; Pangborn, Joseph B; Zajack, Heidi A; Kendall, Scott T; Rediske, Richard R; Biddanda, Bopaiah A

2010-01-01

Physicochemical characterization, automated ribosomal intergenic spacer analysis (ARISA) community profiling, and 16S rRNA gene sequencing approaches were used to study bacterial communities inhabiting submerged Lake Huron sinkholes inundated with hypoxic, sulfate-rich groundwater. Photosynthetic cyanobacterial mats on the sediment surface were dominated by Phormidium autumnale, while deeper, organically rich sediments contained diverse and active bacterial communities.

The use (and misuse) of sediment traps in coral reef environments: theory, observations, and suggested protocols

NASA Astrophysics Data System (ADS)

Storlazzi, C. D.; Field, M. E.; Bothner, M. H.

2011-03-01

Sediment traps are commonly used as standard tools for monitoring "sedimentation" in coral reef environments. In much of the literature where sediment traps were used to measure the effects of "sedimentation" on corals, it is clear from deployment descriptions and interpretations of the resulting data that information derived from sediment traps has frequently been misinterpreted or misapplied. Despite their widespread use in this setting, sediment traps do not provide quantitative information about "sedimentation" on coral surfaces. Traps can provide useful information about the relative magnitude of sediment dynamics if trap deployment standards are used. This conclusion is based first on a brief review of the state of knowledge of sediment trap dynamics, which has primarily focused on traps deployed high above the seabed in relatively deep water, followed by our understanding of near-bed sediment dynamics in shallow-water environments that characterize coral reefs. This overview is followed by the first synthesis of near-bed sediment trap data collected with concurrent hydrodynamic information in coral reef environments. This collective information is utilized to develop nine protocols for using sediment traps in coral reef environments, which focus on trap parameters that researchers can control such as trap height ( H), trap mouth diameter ( D), the height of the trap mouth above the substrate ( z o ), and the spacing between traps. The hydrodynamic behavior of sediment traps and the limitations of data derived from these traps should be forefront when interpreting sediment trap data to infer sediment transport processes in coral reef environments.

Sediment and organic carbon transport in Cap de Creus canyon, Gulf of Lions (France)

NASA Astrophysics Data System (ADS)

Tesi, T.; Puig, P.; Palanques, A.; Goni, M. A.; Miserocchi, S.; Langone, L.

2009-04-01

The off-shelf transport of particles in continental margins is responsible for much of the flux of organic matter (OM)and nutrients towards deep-sea ecosystems, playing a key role in the global oceanic biogeochemical cycles. Off-shelf sediment transport mechanism have been well described for many continental margins being triggered by a series of physical forcings such as tides, storms, internal waves, floods, earthquakes, as well as the combination of some of these processes, while topographic structures such as submarine canyons act as preferential sedimentary conduits toward deep ocean. However, the composition of the material supplied to the deep ocean during these events is still poorly understood since most studies have only investigated the magnitude of the down-slope fluxes or limited their analysis to the major bulk components. A special opportunity to characterize the biogeochemical composition of the off-shelf export in the Gulf of Lions (GoL) margin was provided during the winter 2004-2005, when an exceptional dense water cascading event occurred. Dense water overflowing off the shelf in the GoL has been recently recognized as one of the main process affecting particulate shelf-to-slope exchange in northwestern Mediterranean Sea. During the 2004-2005 cascading event, moored instruments were deployed at the Cap de Creus (CdC) canyon head to monitor the physical parameters and to characterize the temporal variability of the exported material. Post-cascading sediment cores were collected along the sediment dispersal system to trace the sediment transport pathway. In this study we developed a source tracing method using elemental compositions, alkaline CuO reaction products (lignin, cutin, lipids, hydroxy benzenes, proteins, lipids, and polysaccharides products), biogenic silica, carbon stable isotope composition, radiocarbon measurements, and grain size as a fingerprint for each sample. The aforementioned analyses were carried out on both sediment trap and sediment samples to obtain a homogeneous data matrix. The dynamic mixture of OM sources and shelf sediments was then analyzed using multivariate statistics. A quantitative mixing model was used to assess the relative contribution of allochthonous and autochthonous OM and to identify the relationship between sediment export from the shelf and down-slope particulate fluxes (sediment provenance).

Effects of Bioadvection by Arenicola marina on Microphytobenthos in Permeable Sediments.

PubMed

Chennu, Arjun; Volkenborn, Nils; de Beer, Dirk; Wethey, David S; Woodin, Sarah A; Polerecky, Lubos

2015-01-01

We used hyperspectral imaging to study short-term effects of bioturbation by lugworms (Arenicola marina) on the surficial biomass of microphytobenthos (MPB) in permeable marine sediments. Within days to weeks after the addition of a lugworm to a homogenized and recomposed sediment, the average surficial MPB biomass and its spatial heterogeneity were, respectively, 150-250% and 280% higher than in sediments without lugworms. The surficial sediment area impacted by a single medium-sized lugworm (~4 g wet weight) over this time-scale was at least 340 cm2. While sediment reworking was the primary cause of the increased spatial heterogeneity, experiments with lugworm-mimics together with modeling showed that bioadvective porewater transport from depth to the sediment surface, as induced by the lugworm ventilating its burrow, was the main cause of the increased surficial MPB biomass. Although direct measurements of nutrient fluxes are lacking, our present data show that enhanced advective supply of nutrients from deeper sediment layers induced by faunal ventilation is an important mechanism that fuels high primary productivity at the surface of permeable sediments even though these systems are generally characterized by low standing stocks of nutrients and organic material.

Effects of Bioadvection by Arenicola marina on Microphytobenthos in Permeable Sediments

PubMed Central

Chennu, Arjun; Volkenborn, Nils; de Beer, Dirk; Wethey, David S.; Woodin, Sarah A.; Polerecky, Lubos

2015-01-01

We used hyperspectral imaging to study short-term effects of bioturbation by lugworms (Arenicola marina) on the surficial biomass of microphytobenthos (MPB) in permeable marine sediments. Within days to weeks after the addition of a lugworm to a homogenized and recomposed sediment, the average surficial MPB biomass and its spatial heterogeneity were, respectively, 150-250% and 280% higher than in sediments without lugworms. The surficial sediment area impacted by a single medium-sized lugworm (~4 g wet weight) over this time-scale was at least 340 cm2. While sediment reworking was the primary cause of the increased spatial heterogeneity, experiments with lugworm-mimics together with modeling showed that bioadvective porewater transport from depth to the sediment surface, as induced by the lugworm ventilating its burrow, was the main cause of the increased surficial MPB biomass. Although direct measurements of nutrient fluxes are lacking, our present data show that enhanced advective supply of nutrients from deeper sediment layers induced by faunal ventilation is an important mechanism that fuels high primary productivity at the surface of permeable sediments even though these systems are generally characterized by low standing stocks of nutrients and organic material. PMID:26230398

Contribution of Sediment Compaction/Loading to the Ganges-Bangladesh Delta Subsidence

NASA Astrophysics Data System (ADS)

Karpytchev, Mikhail; Krien, Yann; Ballu, Valerie; Becker, Melanie; Calmant, Stephane; Spada, Giorgio; Guo, Junyi; Khan, Zahirul; Shum, Ck

2016-04-01

A pronounced spatial variability characterizes the subsidence/uplift rates in the Ganges-Bangladesh delta estimated from both sediment cores and modern geodetic techniques. The large variability of the subsidence rates suggests an interplay of different natural and anthropogenic processes including tectonics, sediment loading and sediment compaction, groundwater extaction among many others drivers of the delta vertical land movements.In this study, we focus on estimating the subsidence rates due to the sediments transported by the Ganges-Brahmaputra since the last 18 000 years. The delta subsidence induced by the sediment loading and the resulting sea level changes are modelled by the TABOO and SELEN software (Spada, 2003; Stocchi and Spada, 2007) in the framework of a gravitationally self-consistent Earth model. The loading history was obtained from available sediment cores and from the isopach map of Goodbread and Kuehl (2000). The results demonstrate that the delta loading enhanced by the Holocene sedimention can be responsable for a regular subsidence across the Ganges-Brahmaputra delta with an amplitude of 1-5 mm/yr along the Bengal coast. These estimates demonstrate that the contribution of the Holocene as well as modern sediment loading should be taken into account in climate change mitigation politicy for Bangladesh.

Biodynamics of copper oxide nanoparticles and copper ions in an oligochaete: Part I: relative importance of water and sediment as exposure routes

USGS Publications Warehouse

Ramskov, Tina; Thit, Amalie; Croteau, Marie-Noele; Selck, Henriette

2015-01-01

Copper oxide (CuO) nanoparticles (NPs) are widely used, and likely released into the aquatic environment. Both aqueous (i.e., dissolved Cu) and particulate Cu can be taken up by organisms. However, how exposure routes influence the bioavailability and subsequent toxicity of Cu remains largely unknown. Here, we assess the importance of exposure routes (water and sediment) and Cu forms (aqueous and nanoparticulate) on Cu bioavailability and toxicity to the freshwater oligochaete, Lumbriculus variegatus, a head-down deposit-feeder. We characterize the bioaccumulation dynamics of Cu in L. variegatus across a range of exposure concentrations, covering both realistic and worst-case levels of Cu contamination in the environment. Both aqueous Cu (Cu-Aq; administered as Cu(NO3)2) and nanoparticulate Cu (CuO NPs), whether dispersed in artificial moderately hard freshwater or mixed into sediment, were weakly accumulated by L. variegatus. Once incorporated into tissues, Cu elimination was negligible, i.e., elimination rate constants were in general not different from zero for either exposure route or either Cu form. Toxicity was only observed after waterborne exposure to Cu-Aq at very high concentration (305 µgL-1), where all worms died. There was no relationship between exposure route, Cu form or Cu exposure concentration on either worm survival or growth. Slow feeding rates and low Cu assimilation efficiency (approximately 30%) characterized the uptake of Cu from the sediment for both Cu forms. In nature, L. variegatus is potentially exposed to Cu via both water and sediment. However, sediment progressively becomes the predominant exposure route for Cu in L. variegatus as Cu partitioning to sediment increases.

Instrumental and bioanalytical measures of dioxin-like compounds and activities in sediments of the Pohang Area, Korea.

PubMed

Hong, Seongjin; Khim, Jong Seong; Park, Jinsoon; Kim, Sunmi; Lee, Sangwoo; Choi, Kyungho; Kim, Chul-Su; Choi, Sung-Deuk; Park, Jeongim; Ryu, Jongseong; Jones, Paul D; Giesy, John P

2014-02-01

Pohang is a mid-sized city in which Korea's largest manufacturer of steel is located. The Hyeongsan River, which runs through Pohang and empties into Yeongil Bay, is therefore expected to be affected by various municipal and industrial inputs. In order to characterize aryl hydrocarbon receptor (AhR)-mediated activities in sediments from the Pohang area, a total of eight locations along the Hyeongsan River were chosen and 16 sediment samples were collected during two sampling campaigns in 2010. Organic extracts of sediments were characterized by both quantitative chemical analyses of dioxin-like chemicals and the in vitro H4IIE-luc bioassay. Significant dioxin-like activities were observed in sediments from industrial and municipal areas, which indicates that most of the dioxin-like chemicals were associated with surrounding anthropogenic sources. In general, responses of the H4IIE-luc assay were significantly correlated with concentrations of target compounds including dioxins, furans, co-planar PCBs, and dioxin-like PAHs. A potency balance analysis indicated that instrumentally derived TCDD equivalents (TEQs) explained about 77% of the bioassay-derived TCDD equivalents (TCDD-EQs). Among the target chemicals measured, certain penta-chlorinated dioxin and furan compounds accounted for the majority of dioxin-like activities associated with sediments. Compositional analysis of target chemicals the sources of such dioxin-like activities were mainly derived from the local activities such as the iron and steel industries. Concentrations and activities of AhR agonists were similar to what was measured approximately 10 years ago. Thus, while AhR agonists seem to be persistent in sediments there seem to have been no large increases in these chemicals in the Pohang area. © 2013. Published by Elsevier B.V. All rights reserved.

Towards Biogeochemical Modeling of Anaerobic Oxidation of Methane: Characterization of Microbial Communities in Methane-bearing North American Continental Margin Sediments

NASA Astrophysics Data System (ADS)

Graw, M. F.; Solomon, E. A.; Chrisler, W.; Krause, S.; Treude, T.; Ruppel, C. D.; Pohlman, J.; Colwell, F. S.

2015-12-01

Methane advecting through continental margin sediments may enter the water column and potentially contribute to ocean acidification and increase atmospheric methane concentrations. Anaerobic oxidation of methane (AOM), mediated by syntrophic consortia of anaerobic methanotrophic archaea and sulfate-reducing bacteria (ANME-SRB), consumes nearly all dissolved methane in methane-bearing sediments before it reaches the sediment-water interface. Despite the significant role ANME-SRB play in carbon cycling, our knowledge of these organisms and their surrounding microbial communities is limited. Our objective is to develop a metabolic model of ANME-SRB within methane-bearing sediments and to couple this to a geochemical reaction-transport model for these margins. As a first step towards this goal, we undertook fluorescent microscopic imaging, 16S rRNA gene deep-sequencing, and shotgun metagenomic sequencing of sediments from the US Pacific (Washington) and northern Atlantic margins where ANME-SRB are present. A successful Illumina MiSeq sequencing run yielded 106,257 bacterial and 857,834 archaeal 16S rRNA gene sequences from 12 communities from the Washington Margin using both universal prokaryotic and archaeal-specific primer sets. Fluorescent microscopy confirmed the presence of cells of the ANME-2c lineage in the sequenced communities. Microbial community characterization was coupled with measurements of sediment physical and geochemical properties and, for samples from the US Atlantic margin, 14C-based measurements of AOM rates and 35S-based measurements of sulfate reduction rates. These findings have the potential to increase understanding of ANME-SRB, their surrounding microbial communities, and their role in carbon cycling within continental margins. In addition, they pave the way for future efforts at developing a metabolic model of ANME-SRB and coupling it to geochemical models of the US Washington and Atlantic margins.

Simultaneous Recovery of Extracellular and Intracellular DNA Suitable for Molecular Studies from Marine Sediments

PubMed Central

Corinaldesi, Cinzia; Danovaro, Roberto; Dell'Anno, Antonio

2005-01-01

The occurrence of high extracellular DNA concentrations in aquatic sediments (concentrations that are 3 to 4 orders of magnitude greater than those in the water column) might play an important role in biogeochemical cycling, as well as in horizontal gene transfer through natural transformation. Since isolation of extracellular DNA from sediments is a difficult and unsolved task, in this study we developed an efficient procedure to recover simultaneously DNA associated with microbial cells and extracellular DNA from the same sediment sample. This procedure is specifically suitable for studying extracellular DNA because it avoids any contamination with DNA released by cell lysis during handling and extraction. Applying this procedure to different sediment types, we obtained extracellular DNA concentrations that were about 10 to 70 times higher than the intracellular DNA concentrations. Using specific targeted prokaryotic primers, we obtained evidence that extracellular DNA recovered from different sediments did not contain amplifiable 16S rRNA genes. By contrast, using DNA extracted from microbial cells as the template, we always amplified 16S rRNA genes. Although 16S rRNA genes were not detected in extracellular DNA, analyses of the sizes of extracellular DNA indicated the presence of high-molecular-weight fragments that might have contained other gene sequences. This protocol allows investigation of extracellular DNA and its possible participation in natural transformation processes. PMID:15640168

Water-quality, bed-sediment, and biological data (October 1993 through September 1994) and statistical summaries of data for streams in the Upper Clark Fork basin, Montana

USGS Publications Warehouse

Lambing, J.H.; Hornberger, Michelle I.; Axtmann, E.V.; Dodge, K.A.

1995-01-01

Water, bed sediment, and biota were sampled in streams from Butte to below Missoula as part of a program to characterize aquatic resources in the upper Clark Fork basin of western Montana. Water- quality data were obtained periodically at 16 stations during October 1993 through September 1994 (water year 1994); daily suspended-sediment data were obtained at six of these stations. Bed-sediment and biological data were obtained at 11 stations in August 1994. Sampling stations were located on the Clark Fork and major tributaries. The primary constituents analyzed were trace elements associated with mine tailings from historical mining and smelting activities. Water-quality data include concentrations of major ions, trace elements, and suspended sediment in samples collected periodically during water year 1994. Daily values of streamflow, suspended-sediment concentration, and suspended- sediment discharge are given for six stations. Bed- sediment data include trace-element concentrations in the fine and bulk fractions. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Quality-assurance data are reported for analytical results of water, bed sediment, and biota. Statistical summaries of bed sediment, and biological data are provided for the period of record at each station since 1985.

Stochastic model for the long-term transport of stored sediment in a river channel

USGS Publications Warehouse

Kelsey, Harvey M.; Lamberson, Roland; Madej, Mary Ann

1987-01-01

We develop a stochastic model for the transport of stored sediment down a river channel. The model is based on probabilities of transition of particles among four different sediment storage reservoirs, called active (often mobilized), semiactive, inactive, and stable (hardly ever mobilized). The probabilities are derived from computed sediment residence times. Two aspects of sediment storage are investigated: flushing times of sediment out of a storage reservoir and changes in the quantity of sediment stored in different reservoirs due to seasonal sediment transport into, and out of, a reach. We apply the model to Redwood Creek, a gravel bed river in northern California. Although the Redwood Creek data set is incomplete, the application serves as an example of the sorts of analyses that can be done with the method. The application also provides insights into the sediment storage process. Sediment flushing times are highly dependent on the degree of interaction of the stable reservoir with the more mobile sediment reservoirs. The most infrequent and highest intensity storm events, which mobilize the stable reservoir, are responsible for the long-term shifts in sediment storage. Turnover times of channel sediment in all but the stable reservoir are on the order of 750 years, suggesting this is all the time needed for thorough interchange between these sediment compartments and cycling of most sediment particles from the initial reservoir to the ocean. Finally, the Markov model has adequately characterized sediment storage changes in Redwood Creek for 1947–1982, especially for the active reservoir. The model replicates field observation of the passage of a slug of sediment through the active reservoir of the middle reach of Redwood Creek in the 18 years following a major storm in 1964 that introduced large quantities of landslide debris to the channel.

Estimation of historic flows and sediment loads to San Francisco Bay,1849–2011

USGS Publications Warehouse

Moftakhari, H.R.; Jay, D.A.; Talke, S.A.; Schoellhamer, David H.

2015-01-01

River flow and sediment transport in estuaries influence morphological development over decadal and century time scales, but hydrological and sedimentological records are typically too short to adequately characterize long-term trends. In this study, we recover archival records and apply a rating curve approach to develop the first instrumental estimates of daily delta inflow and sediment loads to San Francisco Bay (1849–1929). The total sediment load is constrained using sedimentation/erosion estimated from bathymetric survey data to produce continuous daily sediment transport estimates from 1849 to 1955, the time period prior to sediment load measurements. We estimate that ∼55% (45–75%) of the ∼1500 ± 400 million tons (Mt) of sediment delivered to the estuary between 1849 and 2011 was the result of anthropogenic alteration in the watershed that increased sediment supply. Also, the seasonal timing of sediment flux events has shifted because significant spring-melt floods have decreased, causing estimated springtime transport (April 1st to June 30th) to decrease from ∼25% to ∼15% of the annual total. By contrast, wintertime sediment loads (December 1st to March 31st) have increased from ∼70% to ∼80%. A ∼35% reduction of annual flow since the 19th century along with decreased sediment supply has resulted in a ∼50% reduction in annual sediment delivery. The methods developed in this study can be applied to other systems for which unanalyzed historic data exist.

4. What do we need to know about roads?

Treesearch

Leslie M. Reid; Robert R. Ziemer; Michael J. Furniss

1994-01-01

Abstract - Roads facilitate forest management activities, recreational access, and fire suppression. At the same time, they damage wildlife habitat, destroy the remoteness many seek in wildland recreation, produce sediment, alter aquatic ecosystems, and abet the dispersal of noxious weeds. Design of appropriate road networks is thus a controversial task for land...

Forest road erosion control using multiobjective optimization

Treesearch

Matthew Thompson; John Sessions; Kevin Boston; Arne Skaugset; David Tomberlin

2010-01-01

Forest roads are associated with accelerated erosion and can be a major source of sediment delivery to streams, which can degrade aquatic habitat. Controlling road-related erosion therefore remains an important issue for forest stewardship. Managers are faced with the task to develop efficient road management strategies to achieve conflicting environmental and economic...

Characterization of natural organic matter in low-carbon sediments: Extraction and analytical approaches

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fox, Patricia M.; Nico, Peter S.; Tfaily, Malak M.

Sediment-associated natural organic matter (NOM) is a complex assemblage of organic molecules with a wide range of sizes, functional groups, and structures, which is intricately associated with mineral particles. Organic carbon (OC) concentrations in subsurface sediments are typically 10 to 200 times lower than in surface soils, posing a distinct challenge for characterization. A range of chemical extractions were evaluated for extraction of NOM, and a NOM extraction scheme was developed using a combination of sequential extraction with water (MQ) and sodium pyrophosphate at pH 10 (PP), and purification by dialysis and solid phase extraction in order to isolate differentmore » fractions of sediment-associated NOM. Analysis of these different NOM fractions was then carried out by Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible (UV-Vis) spectroscopy, and electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS). The OC extraction efficiency of the tested extractions followed the order PP>NaOH>HCl=hydroxylamine hydrochloride>dithionite. Greater concentrations of OC in PP vs NaOH extracts suggest that metal complexation and/or ligand exchange plays an important role in OC stabilization. Characterization of different pools of extraction NOM by FITR shows that the water soluble fraction has a higher fraction of aliphatic and carboxylic groups, while the PP fractions have higher C=C groups. This trend from aliphatic to more aromatic is also supported by the UV-Vis and ESI-FTICR-MS data.« less

Bathymetry, substrate and circulation in Westcott Bay, San Juan Islands, Washington

USGS Publications Warehouse

Grossman, Eric E.; Stevens, Andrew W.; Curran, Chris; Smith, Collin; Schwartz, Andrew

2007-01-01

Nearshore bathymetry, substrate type, and circulation patterns in Westcott Bay, San Juan Islands, Washington, were mapped using two acoustic sonar systems, video and direct sampling of seafloor sediments. The goal of the project was to characterize nearshore habitat and conditions influencing eelgrass (Z. marina) where extensive loss has occurred since 1995. A principal hypothesis for the loss of eelgrass is a recent decrease in light availability for eelgrass growth due to increase in turbidity associated with either an increase in fine sedimentation or biological productivity within the bay. To explore sources for this fine sediment and turbidity, a dual-frequency Biosonics sonar operating at 200 and 430 kHz was used to map seafloor depth, morphology and vegetation along 69 linear kilometers of the bay. The higher frequency 430 kHz system also provided information on particulate concentrations in the water column. A boat-mounted 600 kHz RDI Acoustic Doppler Current Profiler (ADCP) was used to map current velocity and direction and water column backscatter intensity along another 29 km, with select measurements made to characterize variations in circulation with tides. An underwater video camera was deployed to ground-truth acoustic data. Seventy one sediment samples were collected to quantify sediment grain size distributions across Westcott Bay. Sediment samples were analyzed for grain size at the Western Coastal and Marine Geology Team sediment laboratory in Menlo Park, Calif. These data reveal that the seafloor near the entrance to Westcott Bay is rocky with a complex morphology and covered with dense and diverse benthic vegetation. Current velocities were also measured to be highest at the entrance and along a deep channel extending 1 km into the bay. The substrate is increasingly comprised of finer sediments with distance into Westcott Bay where current velocities are lower. This report describes the data collected and preliminary findings of USGS Cruise B-6-07-PS conducted between May 31, 2007 and June 5, 2007.

Passive sampling methods for contaminated sediments: State of the science for metals

PubMed Central

Peijnenburg, Willie JGM; Teasdale, Peter R; Reible, Danny; Mondon, Julie; Bennett, William W; Campbell, Peter GC

2014-01-01

“Dissolved” concentrations of contaminants in sediment porewater (Cfree) provide a more relevant exposure metric for risk assessment than do total concentrations. Passive sampling methods (PSMs) for estimating Cfree offer the potential for cost-efficient and accurate in situ characterization of Cfree for inorganic sediment contaminants. In contrast to the PSMs validated and applied for organic contaminants, the various passive sampling devices developed for metals, metalloids, and some nonmetals (collectively termed “metals”) have been exploited to a limited extent, despite recognized advantages that include low detection limits, detection of time-averaged trends, high spatial resolution, information about dissolved metal speciation, and the ability to capture episodic events and cyclic changes that may be missed by occasional grab sampling. We summarize the PSM approaches for assessing metal toxicity to, and bioaccumulation by, sediment-dwelling biota, including the recognized advantages and limitations of each approach, the need for standardization, and further work needed to facilitate broader acceptance and application of PSM-derived information by decision makers. Integr Environ Assess Manag 2014;10:179–196. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. Key Points Passive sampling methods (PSMs) offer the potential for cost-efficient and accurate in situ characterization of the dissolved concentrations for inorganic sediment contaminants. PSMs are useful for evaluating the geochemical behavior of metals in surficial sediments, including determination of fluxes across the sediment-water interface, and post-depositional changes in metal speciation. Few studies have tried to link PSM responses in sediments to metal uptake and toxicity responses in benthic organisms. There is a clear need for further studies. Future PSMs could be designed to mimic saturable kinetics, which would fill the gap between the kinetic and the equilibrium regime samplers currently used, and may improve prediction of metals accumulation by benthic organisms. PMID:24470168

Oxygen, carbon, and nutrient exchanges at the sediment-water interface in the Mar Piccolo of Taranto (Ionian Sea, southern Italy).

PubMed

De Vittor, Cinzia; Relitti, Federica; Kralj, Martina; Covelli, Stefano; Emili, Andrea

2016-07-01

In the shallow environment, the nutrient and carbon exchanges at the sediment-water interface contribute significantly to determine the trophic status of the whole water column. The intensity of the allochthonous input in a coastal environment subjected to strong anthropogenic pressures determines an increase in the benthic oxygen demand leading to depressed oxygen levels in the bottom waters. Anoxic conditions resulting from organic enrichment can enhance the exchange of nutrients between sediments and the overlying water. In the present study, carbon and nutrient fluxes at the sediment-water interface were measured at two experimental sites, one highly and one moderately contaminated, as reference point. In situ benthic flux measurements of dissolved species (O2, DIC, DOC, N-NO3 (-), N-NO2 (-), N-NH4 (+), P-PO4 (3-), Si-Si(OH)4, H2S) were conducted using benthic chambers. Furthermore, undisturbed sediment cores were collected for analyses of total and organic C, total N, and biopolymeric carbon (carbohydrates, proteins, and lipids) as well as of dissolved species in porewaters and supernatant in order to calculate the diffusive fluxes. The sediments were characterized by suboxic to anoxic conditions with redox values more negative in the highly contaminated site, which was also characterized by higher biopolymeric carbon content (most of all lipids), lower C/N ratios and generally higher diffusive fluxes, which could result in a higher release of contaminants. A great difference was observed between diffusive and in situ benthic fluxes suggesting the enhancing of fluxes by bioturbation and the occurrence of biogeochemically important processes at the sediment-water interface. The multi-contamination of both inorganic and organic pollutants, in the sediments of the Mar Piccolo of Taranto (declared SIN in 1998), potentially transferable to the water column and to the aquatic trophic chain, is of serious concern for its ecological relevance, also considering the widespread fishing and mussel farming activities in the area.

A fingerprinting mixing model approach to generate uniformly representative solutions for distributed contributions of sediment sources in a Pyrenean drainage basin

NASA Astrophysics Data System (ADS)

Palazón, Leticia; Gaspar, Leticia; Latorre, Borja; Blake, Will; Navas, Ana

2014-05-01

Spanish Pyrenean reservoirs are under pressure from high sediment yields in contributing catchments. Sediment fingerprinting approaches offer potential to quantify the contribution of different sediment sources, evaluate catchment erosion dynamics and develop management plans to tackle the reservoir siltation problems. The drainage basin of the Barasona reservoir (1509 km2), located in the Central Spanish Pyrenees, is an alpine-prealpine agroforest basin supplying sediments to the reservoir at an annual rate of around 350 t km-2 with implications for reservoir longevity. The climate is mountain type, wet and cold, with both Atlantic and Mediterranean influences. Steep slopes and the presence of deep and narrow gorges favour rapid runoff and large floods. The ability of geochemical fingerprint properties to discriminate between the sediment sources was investigated by conducting the nonparametric Kruskal-Wallis H-test and a stepwise discriminant function analysis (minimization of Wilk's lambda). This standard procedure selects potential fingerprinting properties as optimum composite fingerprint to characterize and discriminate between sediment sources to the reservoir. Then the contribution of each potential sediment source was assessed by applying a Monte Carlo mixing model to obtain source proportions for the Barasona reservoir sediment samples. The Monte Carlo mixing model was written in C programming language and designed to deliver a user-defined number possible solutions. A Combinatorial Principals method was used to identify the most probable solution with associated uncertainty based on source variability. The unique solution for each sample was characterized by the mean value and the standard deviation of the generated solutions and the lower goodness of fit value applied. This method is argued to guarantee a similar set of representative solutions in all unmixing cases based on likelihood of occurrence. Soil samples for the different potential sediment sources of the drainage basin were compared with samples from the reservoir using a range of different fingerprinting properties (i.e. mass activities of environmental radionuclides, elemental composition and magnetic susceptibility) analyzed in the < 63 μm sediment fraction. In this case, the 100 best results from 106 generated iterations were selected obtaining a goodness of fit higher than 0.76. The preliminary results using this new data processing methodology for samples collected in the reservoir allowed us to identify cultivated fields and badlands as main potential sources of sediments to the reservoir. These findings support the appropriate use of the fingerprinting methodology in a Spanish Pyrenees basin, which will enable us to better understand the basin sediment production of the Barasona reservoir.

Quantifying hyporheic exchange in a karst stream using 222Rn

NASA Astrophysics Data System (ADS)

Khadka, M. B.; Martin, J. B.; Kurz, M. J.

2013-12-01

The hyporheic zone is a critical interface between groundwater and river water environments and is characterized by steep biogeochemical gradients. Understanding how this interface affects solute transport, nutrient cycling and contaminant attenuation is essential for better water resource management of streams. However, this understanding is constrained due to difficulty associated with quantification of exchange of water through the hyporheic zone. We tested a radon (222Rn) method to estimate the hyporheic water residence time and exchange rate in the bottom sediment of the spring-fed Ichetucknee River, north-central Florida. The river, which flows over the top of the unconfined karstic Floridan Aquifer, is characterized by a broad bedrock channel partially in-filled with unconsolidated sediments. Radon (222Rn) activity in the pore waters of the channel sediments differs from the amount expected from sediment production and decay. Although most radon in streams originates from sources in bottom sediments, the Ichetucknee River water has 222Rn activities (251×5 PCi/L) that are nearly twice that of the pore water (128×15 PCi/L). The river water 222Rn activity is consistent with that of the source springs, suggesting the source of Rn in the river is from deep within the aquifer rather than bottom sediments and that the excess 222Rn in the pore water results from hyporheic exchange. Profiles of radon concentrations with depth through the sediments show that the mixing of stream water and pore water extends 35-45 cm below the sediment and water interface. Based on a model that integrates the excess radon with depth, we estimate the water exchange rate to be between 1.1 and 1.6 cm/day with an average value of 1.3×0.2 cm/day. Water that exchanges across the sediment-water interface pumps oxygen into the sediments, thereby enhancing organic carbon remineralization, as well as the production of NH4+ and PO43- and their fluxes from sediments to the stream. As opposed to conventional in-stream tracer injection method which estimates exchange between the stream and both the hyporheic zone and the surface transient storage zone, the 222Rn approach measures the water exchange between stream and hyporheic sediments only. Although the present method is tested on a spring-fed karst stream, it has potential for any freshwater system (e.g. wetland, lake) where distinct radon activity and production between surface water and underlying sediments occur.

Sediment connectivity evolution on an alpine catchment undergoing glacier retreat

NASA Astrophysics Data System (ADS)

Goldin, Beatrice; Rudaz, Benjamin; Bardou, Eric

2014-05-01

Climate changes can result in a wide range of variations of natural environment including retreating glaciers. Melting from glaciers will have a significant impact on the sediment transport characteristics of glacierized alpine catchments that can affect downstream channel network. Sediment connectivity assessment, i.e. the degree of connections that controls sediment fluxes between different segments of a landscape, can be useful in order to address management activity on sediment fluxes changes of alpine streams. Through the spatial characterization of the connectivity patterns of a catchment and its potential evolution it is possible to both define sediment transport pathways and estimate different contributions of the sub-catchment as sediment sources. In this study, a topography based index (Cavalli et al., 2013) has been applied to assess spatial sediment connectivity in the Navisence catchment (35 km2), an alpine basin located in the southern Walliser Alps (Switzerland) characterized by a complex glacier system with well-developed lateral moraines on glacier margins already crossed by several lateral channels. Glacier retreat of the main glacial edifice will provide a new connectivity pattern. At present the glacier disconnects lateral slopes from the main talweg: it is expected that its retreat will experience an increased connectivity. In order to study this evolution, two high resolution (2 m) digital terrain models (DTMs) describing respectively the terrain before and after glacier retreat have been analyzed. The current DTM was obtained from high resolution photogrammetry (2 m resolution). The future DTM was derived from application of the sloping local base level (SLBL) routine (Jaboyedoff et al., 2004) on the current glacier system, allowing to remove the ice body by reconstituting a U-shaped polynomial bedrock surface. From this new surface a coherent river network was drawn and slight random noise was added. Finally the river network was burned into the rough surface of the SLBL results. The impact of sediment dynamic changes on the study catchment due to glacier retreat has been assessed by comparing predictions deriving from model application on different scenarios. Simulations allowed the analysis of sediment connectivity evolution over decade scales suggesting an increase of potential sediment transfer and connections in areas close to the main channel network. References: Cavalli, M., Trevisani, S., Comiti, F., Marchi, L., 2013. Geomorphometric assessment of spatial sediment connectivity in small Alpine catchments. Geomorphology 188, 31-41. Jaboyedoff M., Bardou E., Derron M.-H. 2004. Sloping local base level: a tool to estimate potential erodible volume and infilling alluvial sediment of glacial valleys. Swiss Geo-Scientists meeting, November 2004, Lausanne.

In situ redox manipulation of subsurface sediments from Fort Lewis, Washington: Iron reduction and TCE dechlorination mechanisms

DOE Office of Scientific and Technical Information (OSTI.GOV)

JE Szecsody; JS Fruchter; DS Sklarew

2000-03-21

Pacific Northwest National Laboratory (PNNL) conducted a bench-scale study to determine how effective chemically treated Ft. Lewis sediments can degrade trichloroethylene (TCE). The objectives of this experimental study were to quantify: (1) sediment reduction and oxidation reactions, (2) TCE degradation reactions, and (3) other significant geochemical changes that occurred. Sediment reduction and oxidation were investigated to determine the mass of reducible iron in the Ft. Lewis sediments and the rate of this reduction and subsequent oxidation at different temperatures. The temperature dependence was needed to be able to predict field-scale reduction in the relatively cold ({approximately}11 C) Ft. Lewis aquifer.more » Results of these experiments were used in conjunction with other geochemical and hydraulic characterization to design the field-scale injection experiment and predict barrier longevity. For example, the sediment reduction rate controls the amount of time required for the dithionite solution to fully react with sediments. Sediment oxidation experiments were additionally conducted to determine the oxidation rate and provide a separate measure of the mass of reduced iron. Laboratory experiments that were used to meet these objectives included: (1) sediment reduction in batch (static) systems, (2) sediment reduction in 1-D columns, and (3) sediment oxidation in 1-D columns. Multiple reaction modeling was conducted to quantify the reactant masses and reaction rates.« less

The SED-TOX: Toxicity-directed management tool to assess and rank sediments based on their hazard -- concept and application

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bombardier, M.; Bermingham, N.

1999-04-01

This article introduces the sediment Toxicity (SED-TOX) Index for the assessment and ranking of toxic hazards in sediment. Major features include expression of toxicity responses on a single scale of measurement (dry weight-based toxic units), consideration of multiple routes of exposure (pore water, organic extract, wet sediment, and whole sediment), application of differential treatments to toxicity data depending on the level of response, and use of weighting factors to discriminate sediment exposure phases and effect endpoints on the basis of sensitivity. A battery of seven bioassays with four test species (Vibrio fischeri, Escherichia coli, Lytechinus pictus, and Amphiporeia virginiana) wasmore » conducted on 49 marine sediment samples collected from six sites at Anse-a-Beaufils and Cap-aux-Meules, which are in the Gulf of St. Lawrence. The SED-TOX scores were calculated for each sampling station and compared with sediment contaminant concentrations. Results indicate that physico-chemical characterization is not sufficient to assess contaminated-sediment hazard for organisms; furthermore, using several exposure phases and test species belonging to various trophic levels increases the possibility of correctly identifying toxic sediments. The results of this study indicate that the SED-TOX approach is valuable as a toxicity assessment and ranking tool for sediments. It could easily be combined with other measures of ecosystem disturbance to discriminate between polluted and unpolluted sites.« less

Sea-floor morphology and sedimentary environments in southern Narragansett Bay, Rhode Island

USGS Publications Warehouse

McMullen, Katherine Y.; Poppe, Lawrence J.; Blackwood, Dann S.; Nardi, Matthew J.; Andring, Matthew A.

2015-09-09

Multibeam echosounder data collected by the National Oceanic and Atmospheric Administration along with sediment samples and still and video photography of the sea floor collected by the U.S. Geological Survey were used to interpret sea-floor features and sedimentary environments in southern Narragansett Bay, Rhode Island, as part of a long-term effort to map the sea floor along the northeastern coast of the United States. Sea-floor features include rocky areas and scour depressions in high-energy environments characterized by erosion or nondeposition, and sand waves and megaripples in environments characterized by coarse-grained bedload transport. Two shipwrecks are also located in the study area. Much of the sea floor is relatively featureless within the resolution of the multibeam data; sedimentary environments in these areas are characterized by processes associated with sorting and reworking. This report releases bathymetric data from the multibeam echosounder, grain-size analyses of sediment samples, and photographs of the sea floor and interpretations of the sea-floor features and sedimentary environments. It provides base maps that can be used for resource management and studies of topics such as benthic ecology, contaminant inventories, and sediment transport.

Benthic Bacterial Diversity in Submerged Sinkhole Ecosystems▿ †

PubMed Central

Nold, Stephen C.; Pangborn, Joseph B.; Zajack, Heidi A.; Kendall, Scott T.; Rediske, Richard R.; Biddanda, Bopaiah A.

2010-01-01

Physicochemical characterization, automated ribosomal intergenic spacer analysis (ARISA) community profiling, and 16S rRNA gene sequencing approaches were used to study bacterial communities inhabiting submerged Lake Huron sinkholes inundated with hypoxic, sulfate-rich groundwater. Photosynthetic cyanobacterial mats on the sediment surface were dominated by Phormidium autumnale, while deeper, organically rich sediments contained diverse and active bacterial communities. PMID:19880643

Characterizing relationships among fecal indicator bacteria, microbial source tracking markers, and associated waterborne pathogen occurrence in stream water and sediments in a mixed land use watershed

USDA-ARS?s Scientific Manuscript database

Bed sediments of streams and rivers may store high concentrations of fecal indicator bacteria (FIB) and pathogens. These contaminants can be mobilized into the water column due to resuspension events, thus affecting overall water quality. Along with the contaminants, other markers such as microbia...

Chemical and Biological Characterization of Black Rock Harbor Dredged Material.

DTIC Science & Technology

1985-09-01

452. .... Stegeman, J.J. and Teal, J.M. 1973. "Accumulation, Release and Reten- ’’’’’ tion of Petroleum Hydrocarbons by the Oyster, Crassostrea...sediment (6800 ng/g), while tissue concentrations of parent poly- nuclear hydrocarbons were 28% of sediment concentrations that ranged up to " 9800 ng/g...36 ,- "-. Annelids ................................................... 40 Molluscs .................................................. 43

Sulfide production kinetics and model of stormwater retention ponds.

PubMed

D'Aoust, P M; Pick, F R; Wang, R; Poulain, A; Rennie, C; Chen, L; Kinsley, C; Delatolla, R

2018-06-01

Stormwater retention ponds can play a critical role in mitigating the detrimental effects of urbanization on receiving waters that result from increases in polluted runoff. However, the benthic oxygen demand of stormwater facilities may cause significant hypoxia and trigger the production of hydrogen sulfide (H 2 S). This process is not well-documented and further research is needed to characterize benthic processes in stormwater retention ponds in order to improve their design and operation. In this study, sediment oxygen demand (SOD), sediment ammonia release (SAR) and sediment sulfide production (SSP) kinetics were characterized in situ and in the laboratory. In situ SOD and SSP data were utilized to develop a stormwater retention pond water sulfide concentration model which demonstrates strong correlation with sulfide concentrations observed in situ (r = 0.724, N = 91, p < 0.001) and in laboratory experiments (r = 0.691, N = 38, p < 0.001). At 4 °C, in situ rates of SOD, SAR and SSP were higher than those measured in laboratory. Sulfate-reducing bacteria (SRB) represented 4.99% of the bacteria present in the top 30 cm of the pond sediment, with Desulfobulbaceae spp., Desulfobacteraceae spp. and Desulfococcus spp. being the dominant SRB taxa identified.

Estuarine bed-sediment-quality data collected in New Jersey and New York after Hurricane Sandy, 2013

USGS Publications Warehouse

Fischer, Jeffrey M.; Phillips, Patrick J.; Reilly, Timothy J.; Focazio, Michael J.; Loftin, Keith A.; Benzel, William M.; Jones, Daniel K.; Smalling, Kelly L.; Fisher, Shawn C.; Fisher, Irene J.; Iwanowicz, Luke R.; Romanok, Kristin M.; Jenkins, Darkus E.; Bowers, Luke; Boehlke, Adam; Foreman, William T.; Deetz, Anna C.; Carper, Lisa G.; Imbrigiotta, Thomas E.; Birdwell, Justin E.

2015-01-01

Bed-sediment samples were collected from June to October 2013 from 167 estuarine sites extending from Cape May, New Jersey, to the New York Harbor and the eastern end of Long Island. Each sampling location and study region was characterized by using geographic information to identify potential contaminant sources. Characterizations included land cover, locations and types of businesses (industrial, financial, and others), spills (sewage, chemical, and others), bulk storage facilities, effluent discharges within 2 kilometers of the sampling point, and discharges within inundated and non-inundated regions near the sampling location. Samples were analyzed for particle size, total organic carbon, metals and trace elements, semivolatile organic compounds, wastewater compounds, hormones, and sediment toxicity. Samples were also screened using x-ray fluorescence, Fourier transform infrared spectroscopy, and x-ray diffraction. In addition, bioassays for endocrine disruptors and protein phosphatase 2A inhibition were conducted. The study was designed to provide the data needed to understand the extent and sources of contamination resulting from Hurricane Sandy, to compare the chemistry and toxicity of estuarine bed sediments before and after the storm, and to evaluate the usefulness of rapid screening and bioassay approaches in disaster settings.

Metal complexation capacity of Antarctic lacustrine sediments.

PubMed

Alberti, Giancarla; Mussi, Matteo; Quattrini, Federico; Pesavento, Maria; Biesuz, Raffaela

2018-04-01

The purpose of this study is to implement a work that is a part of a project funded by the Italian National Antarctic Research Program (PNRA, Piano Nazionale di Ricerche in Antartide) within the main thematic focus "Chemical Contamination-Global Change". This research was devoted to detect and characterize micro and nano components with strong complexing capability towards metal ions at trace level in sea water, lakes and lacustrine sediments, sampled during the XXII expedition of PNRA. In particular, in the present work, the sorption complexation capacity of an Antarctic lacustrine sediments toward Cu(II) and Pb(II) is described. The characterization of the sorption was undertaken, studying kinetics and isotherm profiles. The lake here considered is Tarn Flat in the area of Terra Nova Bay. The sorption equilibria of Cu(II) and Pb(II) on the lacustrine sediments were reached in about 10 h, and they were best modelled by the Langmuir equation. Preliminary, to establish if the data here obtained were consistent with those reported for the same area in other expeditions, a common multivariate techniques, namely the principal component analysis (PCA), was applied and finally the consistency of the data has been confirmed. Copyright © 2018 Elsevier Ltd. All rights reserved.

The effect of Hurricane Lili on the distribution of organic matter along the inner Louisiana shelf (Gulf of Mexico, USA)

NASA Astrophysics Data System (ADS)

Goñi, Miguel A.; Gordon, Elizabeth S.; Monacci, Natalie M.; Clinton, Rebecca; Gisewhite, Rachel; Allison, Mead A.; Kineke, Gail

2006-11-01

On October 3, 2002 Hurricane Lili made landfall on a previously studied region of the inner Louisiana shelf as a Category 2 storm with winds over 160 km/h. A week after the hurricane, major impacts of the storm were not evident in the water column except for the lower than expected inshore salinities (˜12 psu) for this time of year, which was characterized by low river discharge. Turbidity profiles were typical of those measured during previous investigations with suspended sediment concentrations >75 mg/L at inshore stations and <50 mg/L in surface waters and offshore. The implication is that the sediments resuspended during the hurricane settled soon after the storm passage. Water column particulate organic carbon (POC) concentrations ranged from 0.1 to over 2.0 mg/L, with the highest concentrations measured near the seabed and in the inshore portions of the study area. Suspended particles were characterized by low organic matter content (%POC of 0.5-2 wt%), low chlorophyll:POC ratios (Chl:POC<4 mg/g) and moderately elevated POC:particulate nitrogen ratios (POC:PN of 10-14 mol/mol), all suggesting their source was locally resuspended seabed sediment rather than from algal biomass or land-derived vascular plant detritus. Post hurricane sediment deposition throughout the study area resulted in a storm layer that ranged from <0.5 to 20 cm in thickness. In most locations sediment accumulation ranged from 3 to 10 cm. The storm deposits were generally composed of silty clays with a coarser, somewhat sandy 1-2 cm basal layer. Surface sediments from the storm layer were characterized by relatively high mineral surface areas (SA of 30-50 m 2/g) and elevated OC contents (%OC of 1.0-2.0%). The dispersal of fine sediments following the hurricane resulted in marked changes in the SA and %OC values of surface sediments from offshore locations, which prior to the storm contained coarser, organic-poor particles (SA of 5-15 m 2/g and %OC of 0.2-0.6%). The OC:SA and OC:N ratios of storm layer sediments ranged from 0.4 to 0.6 mg OC/m 2 and from 10 to 12 mol/mol, respectively, and were comparable to those measured in surface sediments prior to the hurricane. Such similarities in the composition of the organic matter reinforce the idea that the source of the storm deposits was the finer fraction of resuspended seabed sediments, with little evidence for inputs from local land-derived sources or autochthonous algal production. Overall, the magnitude of sediment and organic matter deposition on the seabed after the storm greatly exceeded the annual inputs from the Atchafalaya River and coastal primary production. The combined effects of hurricane-driven erosion and post-storm deposition represent a major perturbation to the benthic community of the region, which is already subject to these types of disturbances due to the combined effects of peaks in river discharge and the passage of storm fronts.

Metatranscriptomic analysis of a high-sulfide aquatic spring reveals insights into sulfur cycling and unexpected aerobic metabolism

PubMed Central

Elshahed, Mostafa S.; Najar, Fares Z.; Krumholz, Lee R.

2015-01-01

Zodletone spring is a sulfide-rich spring in southwestern Oklahoma characterized by shallow, microoxic, light-exposed spring water overlaying anoxic sediments. Previously, culture-independent 16S rRNA gene based diversity surveys have revealed that Zodletone spring source sediments harbor a highly diverse microbial community, with multiple lineages putatively involved in various sulfur-cycling processes. Here, we conducted a metatranscriptomic survey of microbial populations in Zodletone spring source sediments to characterize the relative prevalence and importance of putative phototrophic, chemolithotrophic, and heterotrophic microorganisms in the sulfur cycle, the identity of lineages actively involved in various sulfur cycling processes, and the interaction between sulfur cycling and other geochemical processes at the spring source. Sediment samples at the spring’s source were taken at three different times within a 24-h period for geochemical analyses and RNA sequencing. In depth mining of datasets for sulfur cycling transcripts revealed major sulfur cycling pathways and taxa involved, including an unexpected potential role of Actinobacteria in sulfide oxidation and thiosulfate transformation. Surprisingly, transcripts coding for the cyanobacterial Photosystem II D1 protein, methane monooxygenase, and terminal cytochrome oxidases were encountered, indicating that genes for oxygen production and aerobic modes of metabolism are actively being transcribed, despite below-detectable levels (<1 µM) of oxygen in source sediment. Results highlight transcripts involved in sulfur, methane, and oxygen cycles, propose that oxygenic photosynthesis could support aerobic methane and sulfide oxidation in anoxic sediments exposed to sunlight, and provide a viewpoint of microbial metabolic lifestyles under conditions similar to those seen during late Archaean and Proterozoic eons. PMID:26417542

Magnetic signature of river sediments drained into the southern and eastern part of the South China Sea (Malay Peninsula, Sumatra, Borneo, Luzon and Taiwan)

NASA Astrophysics Data System (ADS)

Kissel, Catherine; Liu, Zhifei; Li, Jinhua; Wandres, Camille

2017-01-01

Magnetic properties of 22 river samples collected in the Malay Peninsula, Sumatra, Borneo, Luzon and Taiwan have been investigated in order to magnetically characterize the sediments drained and deposited into the South China Sea. The geological formations as well as the present climatic conditions are different from one region to another. Laboratory analyses include low-field magnetic susceptibility, anhysteretic (ARM) and isothermal (IRM) remanent magnetizations acquisition and decay, back-field acquisition, thermal demagnetization of three-axes IRM, hysteresis cycles and low-temperature magnetic measurements. The magnetic properties indicate that the sediments are a mixture of hematite, magnetite and pyrrhotite in different proportions depending on the region. Combined with results previously reported for the three main Asian rivers (Pearl, Red and Mekong rivers), the new data indicate that, in general, hematite-rich sediments are delivered to the southern basin of the South China Sea while the northern basin is fed with magnetite and pyrrhotite-rich sediments. In addition to this general picture, some variability is observed at smaller geographic scales. Indeed, the magnetic assemblages are closely related to the geology of the various catchments while clay minerals, previously reported for the same samples, are more representative of the climatic conditions under which the parent rocks have evolved within each catchment. The magnetic fraction, now well characterized in the main river sediments drained into the South China Sea, can be used as a tracer for changes in precipitation on land and in oceanic water mass transport and exchange.

Microbial Communities and Organic Matter Composition in Surface and Subsurface Sediments of the Helgoland Mud Area, North Sea

PubMed Central

Oni, Oluwatobi E.; Schmidt, Frauke; Miyatake, Tetsuro; Kasten, Sabine; Witt, Matthias; Hinrichs, Kai-Uwe; Friedrich, Michael W.

2015-01-01

The role of microorganisms in the cycling of sedimentary organic carbon is a crucial one. To better understand relationships between molecular composition of a potentially bioavailable fraction of organic matter and microbial populations, bacterial and archaeal communities were characterized using pyrosequencing-based 16S rRNA gene analysis in surface (top 30 cm) and subsurface/deeper sediments (30–530 cm) of the Helgoland mud area, North Sea. Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) was used to characterize a potentially bioavailable organic matter fraction (hot-water extractable organic matter, WE-OM). Algal polymer-associated microbial populations such as members of the Gammaproteobacteria, Bacteroidetes, and Verrucomicrobia were dominant in surface sediments while members of the Chloroflexi (Dehalococcoidales and candidate order GIF9) and Miscellaneous Crenarchaeota Groups (MCG), both of which are linked to degradation of more recalcitrant, aromatic compounds and detrital proteins, were dominant in subsurface sediments. Microbial populations dominant in subsurface sediments (Chloroflexi, members of MCG, and Thermoplasmata) showed strong correlations to total organic carbon (TOC) content. Changes of WE-OM with sediment depth reveal molecular transformations from oxygen-rich [high oxygen to carbon (O/C), low hydrogen to carbon (H/C) ratios] aromatic compounds and highly unsaturated compounds toward compounds with lower O/C and higher H/C ratios. The observed molecular changes were most pronounced in organic compounds containing only CHO atoms. Our data thus, highlights classes of sedimentary organic compounds that may serve as microbial energy sources in methanic marine subsurface environments. PMID:26635758

Distribution and sources of organic matter in surface marine sediments across the North American Arctic margin

NASA Astrophysics Data System (ADS)

Goñi, Miguel A.; O'Connor, Alison E.; Kuzyk, Zou Zou; Yunker, Mark B.; Gobeil, Charles; Macdonald, Robie W.

2013-09-01

As part of the International Polar Year research program, we conducted a survey of surface marine sediments from box cores along a section extending from the Bering Sea to Davis Strait via the Canadian Archipelago. We used bulk elemental and isotopic compositions, together with biomarkers and principal components analysis, to elucidate the distribution of marine and terrestrial organic matter in different regions of the North American Arctic margin. Marked regional contrasts were observed in organic carbon loadings, with the highest values (≥1 mg C m-2 sediment) found in sites along Barrow Canyon and the Chukchi and Bering shelves, all of which were characterized by sediments with low oxygen exposure, as inferred from thin layers (<2 cm) of Mn oxihydroxides. We found strong regional differences in inorganic carbon concentrations, with sites from the Canadian Archipelago and Lancaster Sound displaying elevated values (2-7 wt %) and highly depleted 14C compositions consistent with inputs from bedrock carbonates. Organic carbon:nitrogen ratios, stable carbon isotopes, and terrigenous organic biomarkers (lignin phenols and cutin acids) all indicate marked regional differences in the proportions of marine and terrigenous organic matter present in surface sediments. Regions such as Barrow Canyon and the Mackenzie River shelf were characterized by the highest contributions of land-derived organic matter, with compositional characteristics that suggested distinct sources and provenance. In contrast, sediments from the Canadian Archipelago and Davis Strait had the smallest contributions of terrigenous organic matter and the lowest organic carbon loadings indicative of a high degree of post-depositional oxidation.

Metatranscriptomic analysis of a high-sulfide aquatic spring reveals insights into sulfur cycling and unexpected aerobic metabolism.

PubMed

Spain, Anne M; Elshahed, Mostafa S; Najar, Fares Z; Krumholz, Lee R

2015-01-01

Zodletone spring is a sulfide-rich spring in southwestern Oklahoma characterized by shallow, microoxic, light-exposed spring water overlaying anoxic sediments. Previously, culture-independent 16S rRNA gene based diversity surveys have revealed that Zodletone spring source sediments harbor a highly diverse microbial community, with multiple lineages putatively involved in various sulfur-cycling processes. Here, we conducted a metatranscriptomic survey of microbial populations in Zodletone spring source sediments to characterize the relative prevalence and importance of putative phototrophic, chemolithotrophic, and heterotrophic microorganisms in the sulfur cycle, the identity of lineages actively involved in various sulfur cycling processes, and the interaction between sulfur cycling and other geochemical processes at the spring source. Sediment samples at the spring's source were taken at three different times within a 24-h period for geochemical analyses and RNA sequencing. In depth mining of datasets for sulfur cycling transcripts revealed major sulfur cycling pathways and taxa involved, including an unexpected potential role of Actinobacteria in sulfide oxidation and thiosulfate transformation. Surprisingly, transcripts coding for the cyanobacterial Photosystem II D1 protein, methane monooxygenase, and terminal cytochrome oxidases were encountered, indicating that genes for oxygen production and aerobic modes of metabolism are actively being transcribed, despite below-detectable levels (<1 µM) of oxygen in source sediment. Results highlight transcripts involved in sulfur, methane, and oxygen cycles, propose that oxygenic photosynthesis could support aerobic methane and sulfide oxidation in anoxic sediments exposed to sunlight, and provide a viewpoint of microbial metabolic lifestyles under conditions similar to those seen during late Archaean and Proterozoic eons.

Seismo-acoustic imaging of marine hard substrate habitats: a case study from the German Bight (SE North Sea)

NASA Astrophysics Data System (ADS)

Papenmeier, Svenja; Hass, H. Christian

2016-04-01

The detection of hard substrate habitats in sublittoral environments is a considerable challenge in spite of modern high resolution hydroacoustic techniques. In offshore areas those habitats are mainly represented by either cobbles and boulders (stones) often located in wide areas of soft sediments or by glacial relict sediments (heterogeneous mixture of medium sand to gravel size with cobbles and boulders). Sediment classification and object detection is commonly done on the basis of hydroacoustic backscatter intensities recorded with e.g. sidescan sonar (SSS) and multibeam echo sounder (MBES). Single objects lying on the sediment such as stones can generally be recognized by the acoustic shadow behind the object. However, objects close to the sonar's nadir may remain undetected because their shadows are below the data resolution. Further limitation in the detection of objects is caused by sessile communities that thrive on the objects. The bio-cover tends to absorb most of the acoustic signal. Automated identification based on the backscatter signal is often not satisfactory, especially when stones are present in a setting with glacial deposits. Areas characterized by glacial relict sediments are hardly differentiable in their backscatter characteristics from rippled coarse sand and fine gravel (rippled coarse sediments) without an intensive ground-truthing program. From the ecological point of view the relict and rippled coarse sediments are completely different habitats and need to be distinguished. The case study represents a seismo-acoustic approach in which SSS and nonlinear sediment echo sounder (SES) data are combined to enable a reliable and reproducible differentiation between relict sediments (with stones and coarse gravels) and rippled coarse sediments. Elevated objects produce hyperbola signatures at the sediment surface in the echo data which can be used to complement the SSS data. The nonlinear acoustic propagation of the SES sound pulses produces a comparably small foot print which results in high spatial resolution (decimeter in the xyz directions) and hence allows a more precise demarcation of hard substrate areas. Data for this study were recorded in the "Sylt Outer Reef" (German Bight, North Sea) in May 2013 and March 2015. The investigated area is characterized by heterogeneously distributed moraine deposits and rippled coarse sediments partly draped with Holocene fine sands. The relict sediments and the rippled coarse sediments indicate both high backscatter intensities but can be distinguished by means of the hyperbola locations. The northeast of the study area is dominated by rippled coarse sediments (without hyperbolas) and the southwestern part by relict sediments with a high amount of stones represented by hyperbolas which is also proven by extensive ground-truthing (grab sampling and high quality underwater videos). An automated procedure to identify and export the hyperbola positions makes the demarcation of hard substrate grounds (here: relict sediments) reproducible, faster and less complex in comparison to the visual-manual identification on the basis of sidescan sonar data.

Integrated approach to monitor water dynamics with drones

NASA Astrophysics Data System (ADS)

Raymaekers, Dries; De Keukelaere, Liesbeth; Knaeps, Els; Strackx, Gert; Decrop, Boudewijn; Bollen, Mark

2017-04-01

Remote sensing has been used for more than 20 years to estimate water quality in the open ocean and study the evolution of vegetation on land. More recently big improvements have been made to extend these practices to coastal and inland waters, opening new monitoring opportunities, eg. monitoring the impact of dredging activities on the aquatic environment. While satellite sensors can provide complete coverage and historical information of the study area, they are limited in their temporal revisit time and spatial resolution. Therefore, deployment of drones can create an added value and in combination with satellite information increase insights in the dynamics and actors of coastal and aquatic systems. Drones have the advantages of monitoring at high spatial detail (cm scale), with high frequency and are flexible. One of the important water quality parameters is the suspended sediment concentration. However, retrieving sediment concentrations from unmanned systems is a challenging task. The sediment dynamics in the port of Breskens, the Netherlands, were investigated by combining information retrieved from different data sources: satellite, drone and in-situ data were collected, analysed and inserted in sediment models. As such, historical (satellite), near-real time (drone) and predictive (sediment models) information, integrated in a spatial data infrastructure, allow to perform data analysis and can support decision makers.

Biomonitoring for deposited sediment using benthic invertebrates: A test on 4 Missouri streams

USGS Publications Warehouse

Zweig, L.D.; Rabeni, Charles F.

2001-01-01

The response of stream benthic invertebrates to surficially deposited fine sediment was investigated in 4 Missouri streams. Twenty to 24 sampling sites in each stream were selected based on similarities of substrate particle-size distributions, depths, and current velocities but for differences in amounts of deposited sediment, which ranged from 0 to 100% surface cover. Deposited sediment was quantified 2 ways: a visual estimate of % surface cover, and a measurement of substrate embeddedness, which were highly correlated with each other and with the amount of sand. Invertebrates were collected using a kicknet for a specified time in a 1-m2 area. Five commonly used biomonitoring metrics (taxa richness, density, Ephemeroptera, Plecoptera, and Trichoptera [EPT] richness, EPT density, and EPT/Chironomidae richness) were consistently significantly correlated across streams to deposited sediment. Shannon diversity index, Chironomidae richness, Chironomidae density, a biotic index, and % dominant taxon did not relate to increasing levels of deposited sediment. Tolerance values representing taxa responses to deposited sediment were developed for 30 taxa. Deposited-sediment tolerance values were not correlated with biotic index tolerance values, indicating a different response by taxa to deposited sediment than to organic enrichment. Deposited-sediment tolerance values were used to develop the Deposited Sediment Biotic Index (DSBI). The DSBI was calculated for all samples (n = 85) to characterize sediment impairment of the sampled streams. DSBI values for each site were highly correlated with measures of deposited sediment. Model validation by a resampling procedure confirmed that the DSBI is a potentially useful tool for assessing ecological effects of deposited sediment.

Pre-treatments, characteristics, and biogeochemical dynamics of dissolved organic matter in sediments: A review.

PubMed

Chen, Meilian; Hur, Jin

2015-08-01

Dissolved organic matter (DOM) in sediments, termed here sediment DOM, plays a variety of important roles in global biogeochemical cycling of carbon and nutrients as well as in the fate and transport of xenobiotics. Here we reviewed sediment DOM, including pore waters and water extractable organic matter from inland and coastal sediments, based on recent literature (from 1996 to 2014). Sampling, pre-treatment, and characterization methods for sediment DOM were summarized. The characteristics of sediment DOM have been compared along an inland to coastal ecosystems gradient and also with the overlying DOM in water column to distinguish the unique nature of it. Dissolved organic carbon (DOC) from inland sediment DOM was generally higher than coastal areas, while no notable differences were found for their aromaticity and apparent molecular weight. Fluorescence index (FI) revealed that mixed sources are dominant for inland sediment DOM, but marine end-member prevails for coastal sediment DOM. Many reports showed that sediments operate as a net source of DOC and chromophoric DOM (CDOM) to the water column. Sediment DOM has shown more enrichment of nitrogen- and sulfur-containing compounds in the elemental signature than the overlying DOM. Fluorescent fingerprint investigated by excitation-emission matrix coupled with parallel factor analysis (EEM-PARAFAC) further demonstrated the characteristics of sediment DOM lacking in the photo-oxidized and the intermediate components, which are typically present in the overlying surface water. In addition, the biogeochemical changes in sediment DOM and the subsequent environmental implications were discussed with the focus on the binding and the complexation properties with pollutants. Copyright © 2015 Elsevier Ltd. All rights reserved.

In-situ Geotechnical Investigation of Arctic Nearshore Zone Sediments, Herschel Island, Yukon

NASA Astrophysics Data System (ADS)

Stark, N.; Quinn, B.; Radosavljevic, B.; Lantuit, H.

2016-02-01

The Arctic is currently undergoing rapid changes with regard to ice coverage, permafrost retreat and coastal erosion. In addition to hydrodynamic processes, the sediments in the Arctic nearshore zone are affected by potential variations in freeze-thaw cycles, as well as an increase of abundant suspended sediment introduced by active retrogressive thaw slumps and increased river discharge. During the YUKON14 expedition to Herschel Island, Yukon, in-situ geotechnical testing of nearshore zone sediments was conducted using a portable free fall penetrometer. The research goals were mapping of sediment types, identification of surficial sediment stratification related to recent sediment remobilization or deposition processes, and the investigation of the soil mechanical characteristics of the uppermost seabed surface in the nearshore zone. Approximately 200 sites were tested using the portable free fall penetrometer, and five different geotechnical signatures identified and grouped. Most locations were characterized by a soft sediment top layer that exhibited a noticeably lower sediment strength than the underlying sediment. The results were correlated to existing sediment grain size records and a sediment type interpretation based on side scan sonar backscatter information. Strong spatial variations in sediment type and stiffness were observed, as well as in abundance and thickness of a top layer of very soft and loose sediment. It was attempted to relate the geotechnical signature to site-specific hydrodynamic energy, morphology, and vicinity to thaw slumps. The results will contribute to a detailed investigation of Arctic coastal erosion in the region, and the investigation of the role of geotechnical parameters for Arctic coastal erosion.

Assessment of the ecotoxicity of urban estuarine sediment using benthic and pelagic copepod bioassays.

PubMed

Charry, Maria P; Keesing, Vaughan; Costello, Mark; Tremblay, Louis A

2018-01-01

Urban estuarine sediments are sinks to a range of contaminants of anthropogenic origin, and a key challenge is to characterize the risk of these compounds to receiving environments. In this study, the toxicity of urban estuarine sediments was tested using acute and chronic bioassays in the benthic harpacticoid Quinquelaophonte sp., and in the planktonic calanoid Gladioferens pectinatus , two New Zealand copepod species. The sediment samples from the estuary tributary sites significantly impacted reproduction in Quinquelaophonte sp. However, results from one of the estuary sites were not significantly different to those from the tributaries sites, suggesting that chemicals other than trace metals, polycyclic aromatic hydrocarbons and ammonia may be the causative stressors. Sediment elutriate samples had significant effects on reproductive endpoints in G. pectinatus , and on the induction of DNA damage in cells, as shown by the comet assay. The results indicate that sediment contamination at the Ahuriri Estuary has the potential to impact biological processes of benthic and pelagic organisms. The approach used provides a standardized methodology to assess the toxicity of estuarine sediments.

Chemical and ecotoxicological analyses of sediments and elutriates of contaminated rivers due to e-waste recycling activities using a diverse battery of bioassays.

PubMed

Wang, F; Leung, A O W; Wu, S C; Yang, M S; Wong, M H

2009-07-01

A multi-trophic, multi-exposure phase assessment approach was applied to characterize the toxicity of sediments collected from two rivers in Guiyu, China, an e-waste recycling centre. Elutriate toxicity tests (bacterium Vibrio fischeri and microalga Selenastrum capricornutum) and whole sediment toxicity test (crustacean Heterocypris incongruens) showed that most sediments exhibited acute toxicity, due to elevated heavy metals and PAHs levels, and low pH caused by uncontrolled acid discharge. The survival rates of crustaceans were negatively (p < 0.05) correlated with total PAHs in sediments (411-1755 mg kg(-1)); EC50s of V. fischeri on the elutriates were significantly correlated with elutriate pH (p < 0.01). Significant (p < 0.05) correlations between the induction of hepatic metallothionein in tilapia (Oreochromis mossambicus) and metal concentrations (Cu, Zn, Pb) in sediments were also observed, when fish were fed with diets containing sediment. The results showed that uncontrolled e-waste recycling activities may bring adverse effects to local aquatic ecosystem.

The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river sediments

NASA Astrophysics Data System (ADS)

Yang, Shou Ye; Jung, Hoi Soo; Choi, Man Sik; Li, Cong Xian

2002-07-01

Thirty-four samples from the Changjiang and Huanghe were analyzed to characterize their rare earth element (REE) compositions. Although REE concentrations in the Changjiang sediments are higher than those of the Huanghe sediments, the former are less variable. Bulk samples and acid-leachable fractions have convex REE patterns and middle REE enrichments relative to upper continental crust, whereas flat patterns are present in the residual fractions. Source rock composition is the primary control on REE composition, and weathering processes play a minor role. Grain size exerts some influence on REE composition, as demonstrated by the higher REE contents of clay minerals in sediments from both rivers. Heavy minerals contribute about 10-20% of the total REE in the sediments. Apatite is rare in the river sediments, and contributes less than 2% of the REE content, but other heavy minerals such as sphene, allanite and zircon are important reservoirs of residual REE fractions. The Fe-Mn oxides phase accounts for about 14% of bulk REE content in the Changjiang sediments, which could be one of the more important factors controlling REE fractionation in the leachable fraction.

Salinity shifts in marine sediment: Importance of number of fluctuation rather than their intensities on bacterial denitrifying community.

PubMed

Zaghmouri, Imen; Michotey, Valerie D; Armougom, Fabrice; Guasco, Sophie; Bonin, Patricia C

2018-05-01

The sensitivity of denitrifying community to salinity fluctuations was studied in microcosms filled with marine coastal sediments subjected to different salinity disturbances over time (sediment under frequent salinity changes vs sediment with "stable" salinity pattern). Upon short-term salinity shift, denitrification rate and denitrifiers abundance showed high resistance whatever the sediment origin is. Denitrifying community adapted to frequent salinity changes showed high resistance when salinity increases, with a dynamic nosZ relative expression level. Marine sediment denitrifying community, characterized by more stable pattern, was less resistant when salinity decreases. However, after two successive variations of salinity, it shifted toward the characteristic community of fluctuating conditions, with larger proportion of Pseudomonas-nosZ, exhibiting an increase of nosZ relative expression level. The impact of long-term salinity variation upon bacterial community was confirmed at ribosomal level with a higher percentage of Pseudomonas and lower proportion of nosZII clade genera. Copyright © 2018 Elsevier Ltd. All rights reserved.

Monitoring suspended sediment and associated trace element and nutrient fluxes in large river basins in the USA

USGS Publications Warehouse

Horowitz, A.J.

2004-01-01

In 1996, the US Geological Survey converted its occurrence and distribution-based National Stream Quality Accounting Network (NASQAN) to a national, flux-based water-quality monitoring programme. The main objective of the revised programme is to characterize large USA river basins by measuring the fluxes of selected constituents at critical nodes in various basins. Each NASQAN site was instrumented to determine daily discharge, but water and suspended sediment samples are collected no more than 12-15 times per year. Due to the limited sampling programme, annual suspended sediment fluxes were determined from site-specific sediment rating (transport) curves. As no significant relationship could be found between either discharge or suspended sediment concentration (SSC) and suspended sediment chemistry, trace element and nutrient fluxes are estimated using site-specific mean or median chemical levels determined from a number of samples collected over a period of years, and under a variety of flow conditions.

Recolonization of macrozoobenthos on defaunated sediments in a hypertrophic brackish lagoon: effects of sulfide removal and sediment grain size.

PubMed

Kanaya, Gen

2014-04-01

Influences of sediment types on recolonization of estuarine macrozoobenthos were tested using enclosures in a hypertrophic lagoon. Three types of azoic sediment, sand (S), sulfide-rich mud (M), and mud removed of sulfide through iron addition (MFe), were set in field for 35 days during a hypoxic period. A total of 14 taxa including opportunistic polychaetes and amphipods occurred. Infaunal community in S treatment was characterized by highest diversity, total density and biomass, and population density of five dominant taxa, while those parameters were lowest in M treatment. Sulfide removal in MFe treatment achieved much higher density, biomass, and population densities of several taxa in the sediment. Multivariate analyses demonstrated that the established community structure was unique to each treatment. These imply that dissolved sulfide level as well as sediment grain size is a key determinant for the community composition and recolonization speed of early colonists in estuarine soft-bottom habitats. Copyright © 2014 Elsevier Ltd. All rights reserved.

A review of oil, dispersed oil and sediment interactions in the aquatic environment: influence on the fate, transport and remediation of oil spills.

PubMed

Gong, Yanyan; Zhao, Xiao; Cai, Zhengqing; O'Reilly, S E; Hao, Xiaodi; Zhao, Dongye

2014-02-15

The 2010 Deepwater Horizon oil spill has spurred significant amounts of researches on fate, transport, and environmental impacts of oil and oil dispersants. This review critically summarizes what is understood to date about the interactions between oil, oil dispersants and sediments, their roles in developing oil spill countermeasures, and how these interactions may change in deepwater environments. Effects of controlling parameters, such as sediment particle size and concentration, organic matter content, oil properties, and salinity on oil-sediment interactions are described in detail. Special attention is placed to the application and effects of oil dispersants on the rate and extent of the interactions between oil and sediment or suspended particulate materials. Various analytical methods are discussed for characterization of oil-sediment interactions. Current knowledge gaps are identified and further research needs are proposed to facilitate sounder assessment of fate and impacts of oil spills in the marine environment. Copyright © 2013 Elsevier Ltd. All rights reserved.

The influence of network structure upon sediment routing in two disturbed catchments, East Cape, New Zealand

NASA Astrophysics Data System (ADS)

Walley, Yasmin; Tunnicliffe, Jon; Brierley, Gary

2018-04-01

Lateral inputs from hillslopes and tributaries exert a variable impact upon the longitudinal connectivity of sediment transfer in river systems with differing drainage network configurations. Network topology influences channel slope and confinement at confluence zones, thereby affecting patterns of sediment storage and the conveyance of sediments through catchments. Rates of disturbance response, patterns of sediment propagation, and the implications for connectivity and recovery were assessed in two neighbouring catchments with differing network configurations on the East Cape of New Zealand. Both catchments were subject to forest clearing in the late 1940s and a major cyclonic storm in 1988. However, reconstruction of landslide runout pathways, and characterization of connectivity using a Tokunaga framework, demonstrates different patterns and rates of sediment transfer and storage in a dendritic network relative to a more elongate, herringbone drainage network. The dendritic network has a higher rate of sediment transfer between storage sites in successive Strahler orders, whereas longitudinal connectivity along the fourth-order mainstem is disrupted by lateral sediment inputs from multiple low-order tributaries in the more elongate, herringbone network. In both cases the most dynamic ('hotspot') reaches are associated with a high degree of network side-branching.

Permeability-Porosity Relationships of Subduction Zone Sediments

NASA Astrophysics Data System (ADS)

Gamage, K.; Screaton, E.; Bekins, B.; Aiello, I.

2008-12-01

Permeability-porosity relationships for sediments from Northern Barbados, Costa Rica, Nankai, and Peru subduction zones were examined based on their sediment type and grain size distribution. Greater correlation was observed between permeability and porosity for siliciclastic sediments, diatom oozes, and nannofossil chalk than for nannofossil oozes. For siliciclastic sediments, grouping of sediments by clay content yields relationships that are generally consistent with results from other marine settings and suggest decreasing permeability for a given porosity as clay content increases. Correction of measured porosities for smectite content generally improves the quality of permeability-porosity relationships. The relationship between permeability and porosity for diatom oozes may be controlled by the amount of clay present in the ooze, causing diatom oozes to behave similarly to siliciclastic sediments. For a given porosity the nannofossil oozes have higher permeability values by 1.5 orders of magnitude than the siliciclastic sediments. However, the use of a permeability-porosity relation may not be appropriate for unconsolidated carbonates such as nannofossil oozes. This study provided insight to the effects of porosity correction for smectite, variations in lithology and grain size in permeability-porosity relationships. However, further progress in delineating controls on permeability will require more careful and better documented permeability tests on characterized samples.

Emergence of burrowing urchins from California continental shelf sediments-A response to alongshore current reversals?

USGS Publications Warehouse

Nichols, F.H.; Cacchione, D.A.; Drake, D.E.; Thompson, J.K.

1989-01-01

Two sequences of bottom photographs taken every two or four hours for two months during the Coastal Ocean Dynamics Experiment (CODE) off the Russian River, California, reveal the dynamic nature of interations between the water column, the sediments, and benthic organisms in the mid-shelf silt deposit. Time-lapse photographs taken between late spring and early summer in 1981 and 1982 show that the subsurface-dwelling urchin Brisaster latifrons (one of the largest invertebrates found in shelf-depth fine sediment off the U.S. Pacific coast) occasionally emerged from the sediment, plowed the sediment surface during the course of a few hours to several days, then buried themselves again. Frame-by-frame study of the film sequences shows that the urchins typically emerged following relaxation of coastal upwelling, periods characterized by current direction reversals and increases in bottom water turbidity. Among the possible causes of the emergence of urchins and the consequent bioturbation of the upper few cm of sediment, a response to an enhanced food supply seems most plausible. Circumstantial evidence suggests the possibility that phytoplankton sedimentation during periods of upwelling relaxation could provide a new source of food at the sediment surface. ?? 1989.

Holocene delta evolution and sediment discharge of the Mekong River, southern Vietnam

NASA Astrophysics Data System (ADS)

Ta, Thi Kim Oanh; Nguyen, Van Lap; Tateishi, Masaaki; Kobayashi, Iwao; Tanabe, Susumu; Saito, Yoshiki

2002-09-01

Evolutionary changes, delta progradation, and sediment discharge of the Mekong River Delta, southern Vietnam, during the late Holocene are presented based on detailed analyses of samples from six boreholes on the lower delta plain. Sedimentological and chronostratigraphic analyses indicate clearly that the last 3 kyr were characterized by delta progradation under increasing wave influence, southeastward sediment dispersal, decreasing progradation rates, beach-ridge formation, and steepening of the face of the delta front. Estimated sediment discharge of the Mekong River for the last 3 kyr, based on sediment-volume analysis, was 144±36 million t yr -1 on average, or almost the same as the present level. The constant rate of delta front migration and stable sediment discharge during the last 3 kyr indicate that a dramatic increase in sediment discharge owing to human activities, as has been suggested for the Yellow River watershed, did not occur. Although Southeast Asian rivers have been considered candidates for such dramatic increases in discharge during the last 2 kyr, the Mekong River example, although it is a typical, large river of this region, does not support this hypothesis. Therefore, estimates of the millennial-scale global pristine sediment flux to the oceans must be revised.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mouser, Paula J.; N'Guessan, A. Lucie; Qafoku, Nikolla

The capacity for subsurface sediments to sequester metal contaminants, such as uranium (U), and retain them after bioremediation efforts are completed is critical to site stewardship. Sediments enriched in natural organic matter are capable of sequestering significant quantities of U, but may also serve as sources to the aquifer, contributing to plume persistence. Two types of sediments were compared to better understand the mechanisms contributing to the sequestration and release of U in the presence of organic matter. Artificially bioreduced sediments were retrieved from a field experimental plot previously stimulated with acetate while naturally bioreduced sediments were collected from amore » location enriched in organic matter but never subject to acetate amendment. Batch incubations demonstrated that the artificially bioreduced sediments were primed to rapidly remove uranium from the groundwater whereas naturally bioreduced sediments initially released a sizeable portion of sediment U before U(VI)-removal commenced. Column experiments confirmed that U release persisted for 65 pore volumes in naturally bioreduced sediments, demonstrating the sink-source behavior of this sediment. Acetate addition to artificially bioreduced sediments shifted the microbial community from one dominated by sulfate-reducing bacteria within Desulfobacteraceae to the iron-reducing family Geobacteraceae and Firmicutes during U(VI) reduction. In contrast, initial Geobacteraceae communities innaturally reduced sediments were replaced by clone sequences with similarity to opportunistic Pseudomonas spp. during U release, while U(VI) removal occurred concurrent with enrichment of Firmicutes. These investigations stress the importance of characterizing zones with heterogeneous carbon pools at U contaminated sites prior to the determination of a remedial strategy.« less

Metagenomic analyses of the late Pleistocene permafrost - additional tools for reconstruction of environmental conditions

NASA Astrophysics Data System (ADS)

Rivkina, Elizaveta; Petrovskaya, Lada; Vishnivetskaya, Tatiana; Krivushin, Kirill; Shmakova, Lyubov; Tutukina, Maria; Meyers, Arthur; Kondrashov, Fyodor

2016-04-01

A comparative analysis of the metagenomes from two 30 000-year-old permafrost samples, one of lake-alluvial origin and the other from late Pleistocene Ice Complex sediments, revealed significant differences within microbial communities. The late Pleistocene Ice Complex sediments (which have been characterized by the absence of methane with lower values of redox potential and Fe2+ content) showed a low abundance of methanogenic archaea and enzymes from both the carbon and nitrogen cycles, but a higher abundance of enzymes associated with the sulfur cycle. The metagenomic and geochemical analyses described in the paper provide evidence that the formation of the sampled late Pleistocene Ice Complex sediments likely took place under much more aerobic conditions than lake-alluvial sediments.

Geophysical bed sediment characterization of the Androscoggin River from the former Chlor-Alkali Facility Superfund Site, Berlin, New Hampshire, to the state border with Maine, August 2009

USGS Publications Warehouse

Degnan, James R.; Teeple, Andrew; Johnston, Craig M.; Marvin-DiPasquale, Mark C.; Luce, Darryl

2011-01-01

The former Chlor-Alkali Facility in Berlin, New Hampshire, was listed on the U.S. Environmental Protection Agency National Priorities List in 2005 as a Superfund site. The Chlor-Alkali Facility lies on the east bank of the Androscoggin River. Elemental mercury currently discharges from that bank into the Androscoggin River. The nature, extent, and the speciation of mercury and the production of methyl mercury contamination in the adjacent Androscoggin River is the subject of continuing investigations. The U.S. Geological Survey, in cooperation with Region I of the U.S. Environmental Protection Agency, used geophysical methods to determine the distribution, thickness, and physical properties of sediments in the Androscoggin River channel at a small area of an upstream reference reach and downstream from the site to the New Hampshire–Maine State border. Separate reaches of the Androscoggin River in the study area were surveyed with surface geophysical methods including ground-penetrating radar and step-frequency electromagnetics. Results were processed to assess sediment characteristics including grain size, electrical conductivity, and pore-water specific conductance. Specific conductance measured during surface- and pore-water sampling was used to help interpret the results of the geophysical surveys. The electrical resistivity of sediment samples was measured in the laboratory with intact pore water for comparison with survey results. In some instances, anthropogenic features and land uses, such as roads and power lines affected the detection of riverbed properties using geophysical methods; when this occurred, the data were removed. Through combining results, detailed riverbed sediment characterizations were made. Results from ground-penetrating radar surveys were used to image and measure the depth to the riverbed, depth to buried riverbeds, riverbed thickness and to interpret material-type variations in terms of relative grain size. Fifty two percent of the riverbed in the study area was covered with gravel and finer sediments. The electrically resistive river water and sediment in this study area were conducive to the penetration of the ground-penetrating radar and step-frequency electromagnetic signals and allowed for effective sediment characterization by geophysical methods. The reach between the former Chlor-Alkali Facility and the Riverside Dam, had small areas of fine sediment (estimated 11 percent of riverbed area), found on the upstream left bank and the downstream right bank, with an electromagnetic conductivity (31.4 millisiemens per meter (mS/m) maximum) that was higher than the upstream reference reach. The greatest electromagnetic conductivity (195 mS/m), pore-water specific conductance (324 mS/m) and lab measured sediment conductivity of (76.8 mS/m, measured with a direct-current resistivity test box) in the study were measured approximately 1 mile (mi) downstream of the site from a sandbar on the left bank. Reaches adjacent to and within 2 mi downstream from the site had elevated electromagnetic conductivity despite having lower estimated percentages of riverbed area covered in sediment (11, 25, and 61 percent, respectively) than the reference reach (97). Typically finer grained sediment with similar mineralogy will be more conductive. The Shelburne Reservoir is approximately 8 mi downstream from the site had the second greatest pore-water specific conductance measured, 45.8 mS/m. Many of the locations with the largest step-frequency electromagnetic values have not been sampled for pore water and sediment.

Contrasting sedimentation patterns in two semi-enclosed mesotidal bays along the west and south coasts of Korea controlled by their orientation to the regional monsoon climate

NASA Astrophysics Data System (ADS)

Hong, Seok Hwi; Chun, Seung Soo; Chang, Tae Soo; Jang, Dae Geon

2017-08-01

Sedimentation patterns of tidal flats along the Korean west coast have long been known to be largely controlled by the monsoon climate. On the other hand, much less is known about the effect of the monsoon on sedimentation in coastal embayments with mouths of different geographic orientations. Good examples are Hampyeong and Yeoja bays along the west and south coasts, respectively. Both have narrow entrances, but their mouths open toward the northwest and the south, respectively. With mean tidal ranges of 3.46 and 3.2 m, respectively, the two bays experience similar tidal regimes and are hence excellent candidates to compare the effect of different exposure to the same regional monsoon climate on their respective sediment distribution patterns. The winter monsoon, in particular, is characterized by strong northwesterly winds that directly impact the west coast, but blow offshore along the south coast. For the purpose of this study, surficial sediment samples were collected from intertidal and subtidal flats of the two bays, both in summer and winter. Grain-size analyses were carried out by sieving (sand fraction) and Sedigraph (mud fraction). In the case of Yeoja Bay, the sediments consist mostly of mud (mean grain sizes of 5.4 to 8.8 phi). Seasonal changes are very subtle, the sediments being slightly coarser in summer when silt-dominated sediments are supplied by two streams to the northern parts of the bay in response to heavy rainfall. With the exception of the deeper tidal channels, Yeoja Bay is characterized by a thick mud blanket the year round, which is modulated by processes associated with the summer monsoon that predominantly blows from the east. Textural parameters suggest severely restricted sediment mixing on the subtidal and intertidal flats, the overall low energy situation preventing sands from reaching the tidal flats. The sediments of Hampyeong Bay, by contrast, are characterized by a distinct shoreward fining trend. Mean grain sizes average around -2.2 phi at the mouth and 8.2 phi near the shore of the inner bay. The textural relationships suggest progressive mixing between two hydraulic populations, the overall higher energy situation allowing sands to be transported onto the tidal flats in winter. In addition, a clear seasonal signal indicating deposition in summer and erosion in winter is observed, the latter probably being controlled by waves generated by strong northwesterly winds of the winter monsoon. The contrasting energy regimes controlling sediment distribution in the two bays are particularly well reflected in ternary diagrams of sand/silt/clay ratios and bivariate plots of textural parameters. The results clearly demonstrate that tidal sedimentation along the west coast of Korea is controlled by the more energetic winter monsoon, whereas along the south coast it is modulated by the less energetic summer monsoon. As a consequence, distinct seasonal changes are particularly pronounced along the west coast, whereas these are more subtle along the south coast. The orientation of bay mouths relative to the direction of wind associated with the summer and winter monsoon is thus identified as the main reason for the completely different sedimentation patterns observed on the subtidal and intertidal flats of the two bays.

Antecedent topography and morphological controls on sediment accumulation and slope stability of the U.S. Atlantic margin

NASA Astrophysics Data System (ADS)

Hill, J. C.; Brothers, D. S.; Ten Brink, U. S.; Andrews, B. D.

2017-12-01

The U.S. Atlantic margin encompasses a wide variety of slope failure processes, ranging from small canyon-confined failures on the upper slope to large, open slope landslides originating in deeper water. Here we used a suite of high-resolution multibeam bathymetry and detailed multichannel seismic data coverage to investigate the relationship between modern seafloor morphology, pre-existing stratigraphy and sediment accumulation patterns. We suggest that a combination of sediment supply and antecedent margin physiography, whereby variations in margin evolution during the Miocene have influenced the modern seafloor morphology, controls both the location of slope sediment accumulation and the style of slope failure. Oversteepened margins with angular shelf breaks and steep upper slopes, referred to as oblique margins, are characterized by downslope mass transport and densely-spaced canyon formation. These margins are most likely the locus of canyon-confined failures and smaller lower slope fan-apron failures (e.g., much of the Mid-Atlantic). Sigmoidal margins with prograded slopes, a rounded shelf edge, and a low gradient slope morphology can support significant sediment accumulation across a broad area, with limited canyon development. These margins are often associated with high sediment supply and are prone to large, upper slope slab-style failures (e.g., the Hudson Apron, southwestern New England, the Currituck and Cape Fear Slide complexes). Areas with morphologies in between these two end members are characterized by limited shelf-edge accommodation space and large-scale lower slope accumulation and onlap, representing transitional stages of equilibrium slope adjustment. Large failures along these intermediate-type margins tend to develop lower on the slope where thick wedges of onlapping sediment are found (e.g., around Washington Canyon, Cape Lookout and southeastern New England). As antecedent topography and sediment loading appear to play an important role in determining the spatial distribution of submarine slope failures, other key processes that contribute to the development of overpressure (e.g., sediment compaction and fluid migration) should be examined with this in mind to improve our understanding of the geologic factors that precondition slopes for failure.

Characterizing Flow and Suspended Sediment Trends in the Sacramento River Basin, CA Using Hydrologic Simulation Program - FORTRAN (HSPF)

NASA Astrophysics Data System (ADS)

Stern, M. A.; Flint, L. E.; Flint, A. L.; Wright, S. A.; Minear, J. T.

2014-12-01

A watershed model of the Sacramento River Basin, CA was developed to simulate streamflow and suspended sediment transport to the San Francisco Bay Delta (SFBD) for fifty years (1958-2008) using the Hydrological Simulation Program - FORTRAN (HSPF). To compensate for the large model domain and sparse data, rigorous meteorological development and characterization of hydraulic geometry were employed to spatially distribute climate and hydrologic processes in unmeasured locations. Parameterization techniques sought to include known spatial information for tributaries such as soil information and slope, and then parameters were scaled up or down during calibration to retain the spatial characteristics of the land surface in un-gaged areas. Accuracy was assessed by comparing model calibration to measured streamflow. Calibration and validation of the Sacramento River ranged from "good" to "very good" performance based upon a "goodness-of-fit" statistical guideline. Model calibration to measured sediment loads were underestimated on average by 39% for the Sacramento River, and model calibration to suspended sediment concentrations were underestimated on average by 22% for the Sacramento River. Sediment loads showed a slight decreasing trend from 1958-2008 and was significant (p < 0.0025) in the lower 50% of stream flows. Hypothetical climate change scenarios were developed using the Climate Assessment Tool (CAT). Several wet and dry scenarios coupled with temperature increases were imposed on the historical base conditions to evaluate sensitivity of streamflow and sediment on potential changes in climate. Wet scenarios showed an increase of 9.7 - 17.5% in streamflow, a 7.6 - 17.5% increase in runoff, and a 30 - 93% increase in sediment loads. The dry scenarios showed a roughly 5% decrease in flow and runoff, and a 16 - 18% decrease in sediment loads. The base hydrology was most sensitive to a temperature increase of 1.5 degrees Celsius and an increase in storm intensity and frequency. The complete calibrated HSPF model will use future climate scenarios to make projections of potential hydrologic and sediment trends to the SFBD from 2000-2100.

Trace metals adhered to urban sediments. Results from fieldwork in Poços de Caldas, Brazil

NASA Astrophysics Data System (ADS)

Isidoro, Jorge; Silveira, Alexandre; Júnior, José; Poleto, Cristiano; de Lima, João; Gonçalves, Flávio; Alvarenga, Lívia

2016-04-01

The urbanization process has consequences such as the introduction of new sources of pollution and changes in the natural environment, like increase of impervious areas that accumulate pollutants between rainfall events. The pollution caused by the washing of accumulated sediment on the gutters, ultimately carried to water bodies through the stormwater drainage system, stands out in this process. This study aimed to quantify and characterize the sediments accumulated in the gutters of roads in an urban area of Poços de Caldas (MG), Brazil. Fieldwork took place during the period of 21.05.2013 to 27.08.2013. Main goal was to investigate the process of accumulation of dry sediments on impervious surfaces and find how this process relates with the urban occupation. More specific goals were to quantify the average mass and characterize the granulometric distribution of accumulated sediments, and identify the occurrence of trace metals Zn, Cu, Ni, Cd, Cu and Pb in the fraction of sediments with diameter smaller or equal to 63μm. The samples were weighed to find the aggregate mass and then sieved through meshes of 63μm, 125μm, 250μm, 600μm, 1180μm, and 2000μm for the granulometric analysis. Samples of the sediment fraction smaller than 63μm of diameter were subjected to analysis by Energy Dispersive X-Ray Fluorescence (EDXRF) and Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) for the identification of trace metals. We found that the aggregate mass of accumulated sediments varies in time and space and is particularly influenced by the land use of the sampling areas. Areas under construction produced more sediments than built areas or areas without construction. This study may serve as an input for creating diffuse pollution control and mitigation strategies towards the reduction of accumulated pollutants in the urban environment of Poços de Caldas. Pb and Zn shown the highest concentrations. The heavy metal concentration decreases after wet periods, showing that runoff carries these elements.

A multivariate analytical method to characterize sediment attributes from high-frequency acoustic backscatter and ground-truthing data (Jade Bay, German North Sea coast)

NASA Astrophysics Data System (ADS)

Biondo, Manuela; Bartholomä, Alexander

2017-04-01

One of the burning issues on the topic of acoustic seabed classification is the lack of solid, repeatable, statistical procedures that can support the verification of acoustic variability in relation to seabed properties. Acoustic sediment classification schemes often lead to biased and subjective interpretation, as they ultimately aim at an oversimplified categorization of the seabed based on conventionally defined sediment types. However, grain size variability alone cannot be accounted for acoustic diversity, which will be ultimately affected by multiple physical processes, scale of heterogeneity, instrument settings, data quality, image processing and segmentation performances. Understanding and assessing the weight of all of these factors on backscatter is a difficult task, due to the spatially limited and fragmentary knowledge of the seabed from of direct observations (e.g. grab samples, cores, videos). In particular, large-scale mapping requires an enormous availability of ground-truthing data that is often obtained from heterogeneous and multidisciplinary sources, resulting into a further chance of misclassification. Independently from all of these limitations, acoustic segments still contain signals for seabed changes that, if appropriate procedures are established, can be translated into meaningful knowledge. In this study we design a simple, repeatable method, based on multivariate procedures, with the scope to classify a 100 km2, high-frequency (450 kHz) sidescan sonar mosaic acquired in the year 2012 in the shallow upper-mesotidal inlet of the Jade Bay (German North Sea coast). The tool used for the automated classification of the backscatter mosaic is the QTC SWATHVIEWTMsoftware. The ground-truthing database included grab sample data from multiple sources (2009-2011). The method was designed to extrapolate quantitative descriptors for acoustic backscatter and model their spatial changes in relation to grain size distribution and morphology. The modelled relationships were used to: 1) asses the automated segmentation performance, 2) obtain a ranking of most discriminant seabed attributes responsible for acoustic diversity, 3) select the best-fit ground-truthing information to characterize each acoustic class. Using a supervised Linear Discriminant Analysis (LDA), relationships between seabed parameters and acoustic classes discrimination were modelled, and acoustic classes for each data point were predicted. The model predicted a success rate of 63.5%. An unsupervised LDA was used to model relationships between acoustic variables and clustered seabed categories with the scope of identifying misrepresentative ground-truthing data points. The model prediction scored a success rate of 50.8%. Misclassified data points were disregarded for final classification. Analyses led to clearer, more accurate appreciation of relationship patterns and improved understanding of site-specific processes affecting the acoustic signal. Value to the qualitative classification output was added by comparing the latter with a more recent set of acoustic and ground-truthing information (2014). Classification resulted in the first acoustic sediment map ever produced in the area and offered valuable knowledge for detailed sediment variability. The method proved to be a simple, repeatable strategy that may be applied to similar work and environments.

Metagenomic Insights into Effects of Chemical Pollutants on Microbial Community Composition and Function in Estuarine Sediments Receiving Polluted River Water.

PubMed

Lu, Xiao-Ming; Chen, Chang; Zheng, Tian-Ling

2017-05-01

Pyrosequencing and metagenomic profiling were used to assess the phylogenetic and functional characteristics of microbial communities residing in sediments collected from the estuaries of Rivers Oujiang (OS) and Jiaojiang (JS) in the western region of the East China Sea. Another sediment sample was obtained from near the shore far from estuaries, used for contrast (CS). Characterization of estuary sediment bacterial communities showed that toxic chemicals potentially reduced the natural variability in microbial communities, while they increased the microbial metabolic enzymes and pathways. Polycyclic aromatic hydrocarbons (PAHs) and nitrobenzene were negatively correlated with the bacterial community variation. The dominant class in the sediments was Gammaproteobacteria. According to Kyoto Encyclopedia of Genes and Genomes (KEGG) enzyme profiles, dominant enzymes were found in estuarine sediments, which increased greatly, such as 2-oxoglutarate synthase, acetolactate synthase, inorganic diphosphatase, and aconitate hydratase. In KEGG pathway profiles, most of the pathways were also dominated by specific metabolism in these sediments and showed a marked increase, for instance alanine, aspartate, and glutamate metabolism, carbon fixation pathways in prokaryotes, and aminoacyl-tRNA biosynthesis. The estuarine sediment bacterial diversity varied with the polluted river water inputs. In the estuary receiving river water from the more seriously polluted River Oujiang, the sediment bacterial community function was more severely affected.

Trace Metal Content of Sediments Close to Mine Sites in the Andean Region

PubMed Central

Yacoub, Cristina; Pérez-Foguet, Agustí; Miralles, Nuria

2012-01-01

This study is a preliminary examination of heavy metal pollution in sediments close to two mine sites in the upper part of the Jequetepeque River Basin, Peru. Sediment concentrations of Al, As, Cd, Cu, Cr, Fe, Hg, Ni, Pb, Sb, Sn, and Zn were analyzed. A comparative study of the trace metal content of sediments shows that the highest concentrations are found at the closest points to the mine sites in both cases. The sediment quality analysis was performed using the threshold effect level of the Canadian guidelines (TEL). The sediment samples analyzed show that potential ecological risk is caused frequently at both sites by As, Cd, Cu, Hg, Pb, and Zn. The long-term influence of sediment metals in the environment is also assessed by sequential extraction scheme analysis (SES). The availability of metals in sediments is assessed, and it is considered a significant threat to the environment for As, Cd, and Sb close to one mine site and Cr and Hg close to the other mine site. Statistical analysis of sediment samples provides a characterization of both subbasins, showing low concentrations of a specific set of metals and identifies the main characteristics of the different pollution sources. A tentative relationship between pollution sources and possible ecological risk is established. PMID:22606058

Effects of salinity and particle concentration on sediment hydrodynamics and critical bed-shear-stress for erosion of fine grained sediments used in wetland restoration projects

NASA Astrophysics Data System (ADS)

Ghose-Hajra, M.; McCorquodale, A.; Mattson, G.; Jerolleman, D.; Filostrat, J.

2015-03-01

Sea-level rise, the increasing number and intensity of storms, oil and groundwater extraction, and coastal land subsidence are putting people and property at risk along Louisiana's coast, with major implications for human safety and economic health of coastal areas. A major goal towards re-establishing a healthy and sustainable coastal ecosystem has been to rebuild Louisiana's disappearing wetlands with fine grained sediments that are dredged or diverted from nearby rivers, channels and lakes to build land in open water areas. A thorough geo-hydrodynamic characterization of the deposited sediments is important in the correct design and a more realistic outcome assessment of the long-term performance measures for ongoing coastal restoration projects. This paper evaluates the effects of salinity and solid particle concentration on the re-suspension characteristics of fine-grained dredged sediments obtained from multiple geographic locations along the Gulf coast. The critical bed-shear-stress for erosion has been evaluated as a function of sedimentation time. The sediment hydrodynamic properties obtained from the laboratory testing were used in a numerical coastal sediment distribution model to aid in evaluating sediment diversions from the Mississippi River into Breton Sound and Barataria Bay.

Distribution of Cr and Pb in artificial sea water and their sorption in marine sediments: an example from experimental mesocosms.

PubMed

Maccotta, A; Cosentino, Claudia; Coccioni, R; Frontalini, F; Scopelliti, G; Caruso, A

2016-12-01

The uptake of two heavy metals (chromium and lead) in sediments in experimental mesocosms under exposure to different metal concentrations was evaluated by monitoring their concentrations over time both in seawater and in sediment. Two separate experiments under laboratory-controlled conditions were carried out for the two metals. Sediments were collected from a protected natural area characterized by low anthropic influence and were placed in mesocosms that were housed in aquaria each with seawater at a different metal concentration. At pre-established time intervals, seawater and sediment samples were collected from each mesocosm for chemical analyses. Quantification of chromium and lead concentration in seawater and sediment samples was carried out by atomic absorption spectrometer with graphite furnace. Low doses of chromium and lead (<1 mg L -1 ) do not entail an uptake in sediments and waters. At doses ≥1 mg L -1 , evolution of concentrations over time shows significant differences between these two metals: (i) chromium absorption from seawater is twice faster than lead; (ii) lead accumulates in considerable amount in sediments. The different behaviour of the two investigated heavy metals could be ascribed to different interactions existing between metal ions and different components of sediment.

Community and functional shifts in ammonia oxidizers across terrestrial and marine (soil/sediment) boundaries in two coastal Bay ecosystems.

PubMed

Zhang, Li-Mei; Duff, Aoife M; Smith, Cindy J

2018-04-24

Terrestrial-marine boundaries are significant sites of biogeochemical activity with delineated gradients from land to sea. While niche differentiation of ammonia-oxidizing archaea (AOA) and bacteria (AOB) driven by pH and nitrogen is well known, the patterns and environmental drivers of AOA and AOB community structure and activity across soil-sediment boundaries have not yet been determined. In this study, nitrification potential rate, community composition and transcriptional activity of AOA and AOB in soil, soil/sediment interface and sediments of two coastal Bays were characterized using a combination of field investigations and microcosm incubations. At DNA level, amoA gene abundances of AOA were significantly greater than AOB in soil, while in sediments AOB were significantly more abundant than AOA, but at the soil/sediment interface there were equal numbers of AOA and AOB amoA genes. Microcosm incubations provided further evidence, through qPCR and DGGE-sequencing analysis of amoA transcripts, that AOA were active in soil, AOB in sediment and both AOA and AOB were active at the soil/sediment interface. The AOA and AOB community composition shifted across the coastal soil-interface-sediment gradient with salinity and pH identified as major environmental drivers. © 2018 Society for Applied Microbiology and John Wiley & Sons Ltd.

The Miocene Extraterrestrial Dust Deposition Event Tracked by Helium, Neon, Chromium and Extraterrestrial Insoluble Organic Matter at the Monte Dei Corvi Beach Section

NASA Astrophysics Data System (ADS)

Meier, M. M. M.; Steele, R. C. J.; Schmitz, B.; Piani, L.; Maden, C.; Plant, A. A.; Schönbächler, M.; Busemann, H.

2017-12-01

A temporarily increased flux of extraterrestrial dust to Earth can lead to tell-tale clues in sediments of the same age. A common example is peaks of 3He in sediments, which occur because extraterrestrial material is rich in implanted solar wind that has a high 3He/4He ratio compared to the atmosphere. One of two known 3He-peaks in Cenozoic sediments is found within the Miocene, at an age of about 8 Ma (Tortonian stage). This peak has been tied to the asteroid break-up event which formed the Veritas family (Farley et al., Nature, 2006). The Global Boundary Stratotype Section and Point for the Tortonian is located near Monte Dei Corvi, in Ancona, Italy. It has previously been well characterized using both magneto- and cyclostratigraphy (Hüsing et al., EPSL, 2009), and can thus provide excellent time-constraints on the age of the event, now dated to have started at 8.47±0.05 Ma (Montanari et al., GSA Bulletin, 2017). In this project, we study these sediments with the primary goal of determining the meteoritic type of the extraterrestrial dust. We have been following three different avenues towards that goal: (1) light noble gas (He, Ne) analyses of bulk sediments (Meier et al., Annual Meeting of the Meteoritical Society, 2016), which are used as tracers of dust flux. The measured He vs. Ne allows us to characterize the preservation state of the extraterrestrial noble gases in the sediments (see Chavrit et al., EPSL, 2016); (2) Cr abundance and isotope analysis of bulk sediments and residues, which should allow us to determine the meteoritic type of the deposited dust (e.g., Rotaru et al., Nature, 1992); (3) an attempt to isolate and characterize potentially surviving meteoritic organic matter in the bulk sediments from Monte Dei Corvi. Insoluble organic matter, which contributes 1-2% of the mass in some carbonaceous chondrites (tied to C- and D-type asteroids, like the ones found abundantly in the Veritas family; Ziffer et al., Icarus, 2011) is strongly acid- and temperature-resistant, and shows D/H and 14N/15N isotopic anomalies (e.g., Piani et al., EPSL, 2015). It thus has potential as a new tracer for dust deposition events from carbonaceous chondrite parent asteroids. We will provide an update for all three projects at the conference.

Mycodiversity in marine sediments contaminated by heavy metals: preliminary results

NASA Astrophysics Data System (ADS)

Zotti, Mirca; Carbone, Cristina; Cecchi, Grazia; Consani, Sirio; Cutroneo, Laura; Di Piazza, Simone; Gabutto, Giacomo; Greco, Giuseppe; Vagge, Greta; Capello, Marco

2016-04-01

Fungi represent the main decomposers of woody and herbaceous substrates in the marine ecosystems. To date there is a gap in the knowledge about the global diversity and distribution of fungi in marine habitats. On the basis of their biological diversity and their role in ecosystem processes, marine fungi may be considered one of the most attractive groups of organisms in modern biotechnology, e.g. ecotoxic metal bioaccumulation. Here we report the data about the first mycological survey in the metal contaminated coastal sediments of the Gromolo Bay. The latter is located in Ligurian Sea (Eastern Liguria, Italy) and is characterized by an enrichment of heavy metals due to pollution of Gromolo Torrent by acidic processes that interest Fe-Cu sulphide mine. 24 samples of marine sediments were collected along a linear plot in front of the shoreline in July 2015. Each sample was separated into three aliquot for mineralogical, chemical analyses and fungal characterization. The sediment samples are characterised by clay fractions (illite and chlorite), minerals of ophiolitic rocks (mainly serpentine, pyroxene and plagioclase) and quartz and are enriched some chemical elements of environmental importance (such as Cu, Zn, Pb, Cd, As). For fungal characterisation the sediment samples were inoculated in Petri dishes on different culture media (Malt Extract Agar and Rose Bengal) prepared with sea water and added with antibiotics. The inoculated dishes were incubated at 20°C in the dark for 28 days. Every week fungal growth was monitored counting the number of colonies. Later, the colonies were isolated in axenic culture for further molecular analysis. The mycodiversity evaluate on the basis of Colony Forming Units (CFU) and microfungal-morphotype characterised by macro-and micro-morphology. Until now on the 72 Petri dishes inoculated 112 CFU of filamentous fungi were counted, among these about 50 morphotypes were characterized. The quantitative results show a mean value of 4.6 CFU per gram of sediments. The maximum value of 11 CFU g-1 has been recorded in two stations (off the Sestri Levante Tombolo), while the minimum value has been recorded closer to the coast. As concern qualitative results, the most recurrent genera are Aspergillus and Penicillium. These data confirm the occurrence of a mycobiota in these heavy metal contaminated sediments. Our preliminary results are a first contribution to the knowledge of presence of microfungi in marine sediments, and propel us to increase our research in order to find out new organisms for bioremediation purpose.

Toward an understanding of "Legacy P" - phosphorus sorption mechanisms in stream sediments as influenced by organic matter

NASA Astrophysics Data System (ADS)

Audette, Yuki; O'Halloran, Ivan P.; Nowell, Peter M.; Congreves, Katelyn; Voroney, R. Paul

2017-04-01

Water chemistry and phosphorus (P) forms were analyzed to determine the nature of legacy P in sediments of the West Holland River and the adjacent drainage canals of the Holland Marsh drainage system, located in southern Ontario, Canada. The river and canals route water from the intensively cropped muck polders of the Holland Marsh and drain Lake Simcoe. Sediment samples were characterized for mineralogy using X-ray diffraction techniques (XRD); total P (TP); and Ca, Fe, Mn, and Mg contents, as well as cation exchange capacity and organic matter (OM) content. Forms of sediment P in five depth sections (ranging from 0-15 cm depth) were characterized and quantified by sequential P fractionation chemistry. At all study sites, mobile P forms including organic P forms were found to be higher in surface sediments than in deeper sediments. The major P form within the sediments of the two canal sites, where the concentration of TP in the surface water was within the Ontario Provincial Water Quality Objectives (PWQO) of 0.03 mg P L-1, was Ca-bound P, indicating a low risk of soluble reactive P (SRP) release. A trace of apatite (a stable Ca-P mineral) was also detected in these sediments. Conversely, sediments collected from the West Holland River at sites located within the Holland Marsh exhibited a high risk of SRP release, and redox-sensitive P was the dominant P form in the sediment despite the surface water exhibiting higher concentration of Ca and alkaline pH. In addition, the concentrations of TP as measured in surface water samples taken from the site were 8 times greater than PWQO. In the sediments where the risk of SRP release was high, OM contents were also relatively high and traces of brushite (a labile Ca-P mineral) were detected. The formation of OM and cation complexes, such as OM-Fe complexes, may play an important role in regulating the fate of sediment-P forms through the adsorption of SRP. These OM-Fe complexes may inhibit the formation of more stable Ca-P minerals, even under neutral to alkaline conditions. Thus, where OM-Fe-P forms predominate, we predict a high risk of SRP release from sediments when water chemistry changes. In addition, OM may inhibit the transformation of labile Ca-P forms to more stable Ca-P minerals. Loading of OM affects the development of hypoxia in aquatic systems, and the accumulation of OM can promote the release of both SRP and dissolved organic C to downstream environments. This study provides evidence that the presence of OM in stream sediments influences P sorption mechanisms and is critical in understanding P biogeochemistry in freshwater environments.

Archaea in Organic-Lean and Organic-Rich Marine Subsurface Sediments: An Environmental Gradient Reflected in Distinct Phylogenetic Lineages

PubMed Central

Durbin, Alan M.; Teske, Andreas

2012-01-01

Examining the patterns of archaeal diversity in little-explored organic-lean marine subsurface sediments presents an opportunity to study the association of phylogenetic affiliation and habitat preference in uncultured marine Archaea. Here we have compiled and re-analyzed published archaeal 16S rRNA clone library datasets across a spectrum of sediment trophic states characterized by a wide range of terminal electron-accepting processes. Our results show that organic-lean marine sediments in deep marine basins and oligotrophic open ocean locations are inhabited by distinct lineages of archaea that are not found in the more frequently studied, organic-rich continental margin sediments. We hypothesize that different combinations of electron donor and acceptor concentrations along the organic-rich/organic-lean spectrum result in distinct archaeal communities, and propose an integrated classification of habitat characteristics and archaeal community structure. PMID:22666218

The Influence of Chitosan Substrate and Its Nanometric Form Toward the Green Power Generation in Sediment Microbial Fuel Cell.

PubMed

Karthikeyan, C; Sathishkumar, Y; Lee, Yang Soo; Kim, Ae Rhan; Yoo, Dong Jin; Kumar, G Gnana

2017-01-01

A simple, environmental friendly and biologically important sediment interfaced fuel cell was developed for the green energy generation. The soil sediment used for the study is enriched of rich anthropogenic free organic carbon, sufficient manganese and high level potassium contents as evidenced from the geochemical characterizations. The saccharides produced by the catalytic reaction of substrate chitosan were utilized for the growth of microorganisms and electron shuttling processes. Chitosan substrate influenced sediment microbial fuel cells exhibited the nearly two fold power increment over the substrate free fuel cells. The fuel cell efficiencies were further increased by bringing the substrate chitosan at nanometric level, which is nearly three and two fold higher than that of substrate free and chitosan influenced sediment microbial fuel cells, respectively, and the influential parameters involved in the power and longevity issues were addressed with different perspectives.

Long-term observations of bottom conditions and sediment movement on the Atlantic continental shelf; time-lapse photography from instrumented tripod

USGS Publications Warehouse

Butman, Bradford; Bryden, Cynthia G.; Pfirman, Stephanie L.; Strahle, William J.; Noble, Marlene A.

1984-01-01

An instrument system that measures bottom current, temperature, light transmission, and pressure, and that photographs the bottom at 2- to 6-hour intervals has been developed to study sediment transport on the Atlantic Continental Shelf. Instruments have been deployed extensively along the United States East Coast Continental Shelf for periods of from 2 to 6 months to study the frequency, direction, and rate of bottom sediment movement, and the processes causing movement. The time-lapse photographs are used to (1) characterize the bottom benthic community and surface microtopography; (2) monitor changes in the bottom topography and near-bottom water column caused by currents and storms (for example, ripple generation and migration, sediment resuspension); and (3) monitor seasonal changes in the bottom benthic community and qualitative effects of this community on the bottom sediments.

Final Project Report: Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jon Chorover, University of Arizona; Peggy O'€™Day, University of California, Merced; Karl Mueller, Penn State University

2012-10-01

Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided detailed characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, PCO2, and reaction time; (ii) improved molecular-scale understanding of howmore » sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions.« less

Chemical fractionation of Cu and Zn in stormwater, roadway dust and stormwater pond sediments

USGS Publications Warehouse

Camponelli, Kimberly M.; Lev, Steven M.; Snodgrass, Joel W.; Landa, Edward R.; Casey, Ryan E.

2010-01-01

This study evaluated the chemical fractionation of Cu and Zn from source to deposition in a stormwater system. Cu and Zn concentrations and chemical fractionation were determined for roadway dust, roadway runoff and pond sediments. Stormwater Cu and Zn concentrations were used to generate cumulative frequency distributions to characterize potential exposure to pond-dwelling organisms. Dissolved stormwater Zn exceeded USEPA acute and chronic water quality criteria in approximately 20% of storm samples and 20% of the storm duration sampled. Dissolved Cu exceeded the previously published chronic criterion in 75% of storm samples and duration and exceeded the acute criterion in 45% of samples and duration. The majority of sediment Cu (92–98%) occurred in the most recalcitrant phase, suggesting low bioavailability; Zn was substantially more available (39–62% recalcitrant). Most sediment concentrations for Cu and Zn exceeded published threshold effect concentrations and Zn often exceeded probable effect concentrations in surface sediments.

Polycyclic aromatic hydrocarbons in sediments from the Old Yellow River Estuary, China: occurrence, sources, characterization and correlation with the relocation history of the Yellow River.

PubMed

Yuan, Zijiao; Liu, Guijian; Wang, Ruwei; Da, Chunnian

2014-11-01

The levels of 16 USEPA priority PAHs were determined in surface sediments and one dated sediment core from the abandoned Old Yellow River Estuary, China. Total PAH concentrations in the surface sediments ranged from 100.4 to 197.3 ng g(-1) dry weight and the total toxic equivalent quantity (TEQ(carc)) values of the carcinogenic PAHs were very low. An evaluation of PAH sources based on diagnostic ratios and principal component analysis suggested that PAHs in the surface sediments mainly derived from combustion sources. The total PAH concentrations altered significantly with year of deposition and showed quite different patterns of change compared with other studies: it is hypothesized that the principal cause of these changes is the relocation of the course of the Yellow River to the sea in 1976 and 1996. Copyright © 2014 Elsevier Inc. All rights reserved.

Tracing suspended sediment sources in the Upper Sangamon River Basin using conservative and non-conservative tracers

NASA Astrophysics Data System (ADS)

Yu, M.; Rhoads, B. L.; Stumpf, A.

2015-12-01

As the awareness of water pollution, eutrophication and other water related environmental concerns grows, the significance of sediment in the transport of nutrients and contaminants from agricultural areas to streams has received increasing attention. Both the physical and geochemical properties of suspended sediment are strongly controlled by sediment sources. Thus, tracing sources of suspended sediment in watersheds is important for the design of management practices to reduce sediment loads and contributions of sediment-adsorbed nutrients from agricultural areas to streams. However, the contributions of different sediment sources to suspended sediment loads within intensively managed watersheds in the Midwest still remain insufficiently explored. This study aims to assess the provenance of suspended sediment and the relation between channel morphology and production of suspended sediment in the Upper Sangamon River Basin, Illinois, USA. The 3,690-km2 Upper Sangamon River Basin is characterized by low-relief, agricultural lands dominated by row-crop agriculture. Sediment source samples were collected in the Saybrook from five potential sources: farmland, forests, floodplains, river banks, and grasslands. Event-based and accumulated suspended sediment samples were collected by ISCO automatic pump samplers and in situ suspended sediment samplers and from the stream at watershed outlet. A quantitative geochemical fingerprinting technique, combining statistically verified multicomponent signatures and an un-mixing model, was employed to estimate the relative contributions of sediment from five potential sources to the suspended sediment loads. Organic matter content, trace elements, and radionuclides from soil samples were used as potential tracers. Our preliminary results indicate that the majority of suspended sediment is derived from floodplains in the downstream portions of the watersheds, while only minor amounts of suspended sediment are derived from upland areas and banks. These results suggest that floodplain erosion during high flow events contributes to the suspended sediment.

Defining Hepatocellular Carcinoma Subtypes and Treatment Responses in Patient-Derived Tumorgrafts

DTIC Science & Technology

2017-10-01

models to uncover novel biology and establish a platform to study experimental therapeutics. 1. KEYWORDS: HCC, patient derived xenografts, siRNA...have distinct cell-intrinsic biology in PDX engraftment assays Major Task 1: Expand and characterize PDX models derived from surgical and biopsy HCC...intrinsic biology in PDX engraftment assays Major Task 1: Expand and characterize PDX models derived from surgical and biopsy HCC specimens Pre-task

Geologic framework of the long bay inner shelf: implications for coastal evolution in South Carolina

USGS Publications Warehouse

Barnhardt, W.; Denny, J.; Baldwin, W.; Schwab, W.; Morton, R.; Gayes, P.; Driscoll, N.

2007-01-01

The inner continental shelf off northern South Carolina is a sediment-limited environment characterized by extensive hardground areas, where coastal plain strata and ancient channel-fill deposits are exposed at the sea floor. Holocene sand is concentrated in large shoals associated with active tidal inlets, an isolated shore-detached sand body, and a widespread series of low-relief sand ridges. The regional geologic framework is a strong control on the production, movement and deposition of sediment. High-resolution geologic mapping of the sea floor supports conceptual models indicative of net southwestward sediment transport along the coast.

Summary of oceanographic measurements for characterizing light attenuation and sediment resuspension in the Barnegat Bay-Little Egg Harbor Estuary, New Jersey, 2013

USGS Publications Warehouse

Dickhudt, Patrick J.; Ganju, Neil K.; Montgomery, Ellyn T.

2015-08-28

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, measured suspended-sediment concentrations, currents, waves, light attenuation, and a variety of other water-quality parameters in the summer of 2013 in Barnegat Bay-Little Egg Harbor, New Jersey. These measurements quantified light attenuation and sediment resuspension in three seagrass meadows. Data were acquired sequentially at three paired channel-shoal sites, as the equipment was moved from south to north in the estuary. Data were collected for approximately 3 weeks at each site.

Reactive iron in marine sediments

NASA Technical Reports Server (NTRS)

Canfield, Donald E.

1989-01-01

The influence of reactive iron oxides on sediment pore-water chemistry is considered in detail. A carefully calibrated extraction scheme is used to determine the depth distributions of reactive iron phases at two very different localities: the relatively iron-rich Mississippi Delta and the relatively iron-poor FOAM site in Long Island Sound. Closed system incubations are used to characterize the rates of reaction between sulfide and both naturally occurring and pure iron mineral phases. Rates of iron liberation to pore solution are measured in the presence and absence of sulfate reduction, and the origin of dissolved iron in organic-rich sediments is speculated upon.

Modern sedimentation patterns in Potter Cove, King George Island, Antarctica

NASA Astrophysics Data System (ADS)

Hass, H. Christian; Kuhn, Gerhard; Wölfl, Anne-Cathrin; Wittenberg, Nina; Betzler, Christian

2013-04-01

IMCOAST among a number of other initiatives investigates the modern and the late Holocene environmental development of south King George Island with a strong emphasis on Maxwell Bay and its tributary fjord Potter Cove (maximum water depth: about 200 m). In this part of the project we aim at reconstructing the modern sediment distribution in the inner part of Potter Cove using an acoustic ground discrimination system (RoxAnn) and more than136 ground-truth samples. Over the past 20 years the air temperatures in the immediate working area increased by more than 0.6 K (Schloss et al. 2012) which is less than in other parts of the West Antarctic Peninsula (WAP) but it is still in the range of the recovery of temperatures from the Little Ice Age maximum to the beginning of the 20th century. Potter Cove is a small fjord characterized by a series of moraine ridges produced by a tidewater glacier (Fourcade Glacier). Presumably, the farthest moraine is not much older than about 500 years (LIA maximum), hence the sediment cover is rather thin as evidenced by high resolution seismic data. Since a few years at least the better part of the tidewater glacier retreated onto the island's mainland. It is suggested that such a fundamental change in the fjord's physiography has also changed sedimentation patterns in the area. Potter Cove is characterized by silty-clayey sediments in the deeper inner parts of the cove. Sediments are coarser (fine to coarse sands and boulders) in the shallower areas; they also coarsen from the innermost basin to the mouth of the fjord. Textural structures follow the seabed morphology, i.e. small v-shaped passages through the moraine ridges. The glacier still produces large amounts of turbid melt waters that enter the cove at various places. We presume that very fine-grained sediments fall out from the meltwater plumes and are distributed by mid-depth or even bottom currents, thus suggesting an anti-estuarine circulation pattern. Older sediments that are more distal to the glacier front and sediments in shallower places (e.g. on top of the moraine ridges) become increasingly overprinted by coarser sediments from the shallow areas of the fjord. These areas are prone to wave induced winnowing effects as well as disturbances by ploughing icebergs. It can be concluded that coarsening of the fjord sediments will continue while the supply of fine-grained meltwater sediments might cease due to exhaustion of the reservoirs.

Effects of fluvial processes in different order river valleys on redistribution and storage of particle-bound radioactive caesium-137 in area of significant Chernobyl fallout and impact on linked rivers with lower contamination levels

NASA Astrophysics Data System (ADS)

Belyaev, Vladimir; Golosov, Valentin; Shamshurina, Evgeniya; Ivanov, Maxim; Ivanova, Nadezhda; Bezukhov, Dmitry; Onda, Yuichi; Wakiyama, Yoshifumi; Evrard, Olivier

2015-04-01

Detailed investigations of the post-fallout fate of radionuclide contamination represent an important task in terms of environmental quality assessment. In addition, particle-bound radionuclides such as the most widespread anthropogenic isotope caesium-137 can be used as tracers for quantitative assessment of different sediment redistribution processes. In landscapes of humid plains with agriculture-dominated land use the post-fallout redistribution of caesium-137 is primarily associated with fluvial activity of various scales in cascade systems starting from soil erosion on cultivated hillslopes through gully and small dry valley network into different order perennial streams and rivers. Our investigations in the so-called Plavsk hotspot (area of very high Chernobyl caesium-137 contamination within the Plava River basin, Tula Region, Central European Russia) has been continuing for more than 15 years by now, while the time passed since the Chernobyl disaster and associated radioactive fallout (1986) is almost 29 years. Detailed information on the fluvial sediment and associated caesium-137 redistribution has been obtained for case study sites of different size from individual cultivated slopes and small catchments of different size (2-180 km2) to the entire Plava River basin scale (1856 km2). It has been shown that most of the contaminated sediment over the time passed since the fallout has remained stored within the small dry valleys of the 1-4 Hortonian order and local reservoirs (>70%), while only about 5% reached the 5-6 order valleys (main tributaries of the Plava River) and storage of the Plava floodplain itself represents as low as 0.3% of the basin-scale total sediment production from eroded cultivated hillslopes. Nevertheless, it has been shown that contaminated sediment yield from the Plava River basin exerts significant influence on less polluted downstream-linked river system. Recent progress of the investigations involved sampling of 7 detailed depth-incremental floodplain sediment sections along the Upa River valley, which is the receiving river for the Plava and is characterized by generally much lower caesium-137 contamination within other parts of its basin. One of the sampled sections was located several kilometers upstream from the Plava River mouth and the other 6 - at different distances downstream starting from about 2 km to about 40 km. In this case we can assume the Plava River mouth to be the point-source of sediment-associated radioactive contamination additional to the initial fallout. It has been found that while at the nearest point downstream the floodplain sediment contamination by caesium-137 is about 2 order of magnitude higher, than upstream, it decreases quickly along the Upa River valley two about 3 times higher than upstream at the most remote downstream point. Importantly, the decrease is not represented by gradual and uniform curve. In contrast, it is interrupted by local increase caused by smaller tributary from relatively high contamination area. It is believed that the obtained information on decadal-scale sediment and associated post-fallout caesium-137 redistribution through the fluvial network, patterns of sinks and rate of contamination propagation into the less polluted downstream-linked river basin can be used for testing and improving the predictive models being developed for applications in other contaminated areas such as river basins around the Fukushima Daiichi nuclear power plant, providing that differences in landscape settings, hydrological regime and land use patterns are taken into account.

The use (and misuse) of sediment traps in coral reef environments: Theory, observations, and suggested protocols

USGS Publications Warehouse

Storlazzi, C.D.; Field, M.E.; Bothner, Michael H.

2011-01-01

Sediment traps are commonly used as standard tools for monitoring “sedimentation” in coral reef environments. In much of the literature where sediment traps were used to measure the effects of “sedimentation” on corals, it is clear from deployment descriptions and interpretations of the resulting data that information derived from sediment traps has frequently been misinterpreted or misapplied. Despite their widespread use in this setting, sediment traps do not provide quantitative information about “sedimentation” on coral surfaces. Traps can provide useful information about the relative magnitude of sediment dynamics if trap deployment standards are used. This conclusion is based first on a brief review of the state of knowledge of sediment trap dynamics, which has primarily focused on traps deployed high above the seabed in relatively deep water, followed by our understanding of near-bed sediment dynamics in shallow-water environments that characterize coral reefs. This overview is followed by the first synthesis of near-bed sediment trap data collected with concurrent hydrodynamic information in coral reef environments. This collective information is utilized to develop nine protocols for using sediment traps in coral reef environments, which focus on trap parameters that researchers can control such as trap height (H), trap mouth diameter (D), the height of the trap mouth above the substrate (z o ), and the spacing between traps. The hydrodynamic behavior of sediment traps and the limitations of data derived from these traps should be forefront when interpreting sediment trap data to infer sediment transport processes in coral reef environments.

Mineralogical analyses of surface sediments in the Antarctic Dry Valleys: coordinated analyses of Raman spectra, reflectance spectra and elemental abundances.

PubMed

Bishop, Janice L; Englert, Peter A J; Patel, Shital; Tirsch, Daniela; Roy, Alex J; Koeberl, Christian; Böttger, Ute; Hanke, Franziska; Jaumann, Ralf

2014-12-13

Surface sediments at Lakes Fryxell, Vanda and Brownworth in the Antarctic Dry Valleys (ADV) were investigated as analogues for the cold, dry environment on Mars. Sediments were sampled from regions surrounding the lakes and from the ice cover on top of the lakes. The ADV sediments were studied using Raman spectra of individual grains and reflectance spectra of bulk particulate samples and compared with previous analyses of subsurface and lakebottom sediments. Elemental abundances were coordinated with the spectral data in order to assess trends in sediment alteration. The surface sediments in this study were compared with lakebottom sediments (Bishop JL et al. 2003 Int. J. Astrobiol. 2, 273-287 (doi:10.1017/S1473550403001654)) and samples from soil pits (Englert P et al. 2013 In European Planetary Science Congress, abstract no. 96; Englert P et al. 2014 In 45th Lunar and Planetary Science Conf., abstract no. 1707). Feldspar, quartz and pyroxene are common minerals found in all the sediments. Minor abundances of carbonate, chlorite, actinolite and allophane are also found in the surface sediments, and are similar to minerals found in greater abundance in the lakebottom sediments. Surface sediment formation is dominated by physical processes; a few centimetres below the surface chemical alteration sets in, whereas lakebottom sediments experience biomineralization. Characterizing the mineralogical variations in these samples provides insights into the alteration processes occurring in the ADV and supports understanding alteration in the cold and dry environment on Mars. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

Numerical simulation of two-phase flow for sediment transport in the inner-surf and swash zones

NASA Astrophysics Data System (ADS)

Bakhtyar, R.; Barry, D. A.; Yeganeh-Bakhtiary, A.; Li, L.; Parlange, J.-Y.; Sander, G. C.

2010-03-01

A two-dimensional two-phase flow framework for fluid-sediment flow simulation in the surf and swash zones was described. Propagation, breaking, uprush and backwash of waves on sloping beaches were studied numerically with an emphasis on fluid hydrodynamics and sediment transport characteristics. The model includes interactive fluid-solid forces and intergranular stresses in the moving sediment layer. In the Euler-Euler approach adopted, two phases were defined using the Navier-Stokes equations with interphase coupling for momentum conservation. The k-ɛ closure model and volume of fluid approach were used to describe the turbulence and tracking of the free surface, respectively. Numerical simulations explored incident wave conditions, specifically spilling and plunging breakers, on both dissipative and intermediate beaches. It was found that the spatial variation of sediment concentration in the swash zone is asymmetric, while the temporal behavior is characterized by maximum sediment concentrations at the start and end of the swash cycle. The numerical results also indicated that the maximum turbulent kinetic energy and sediment flux occurs near the wave-breaking point. These predictions are in general agreement with previous observations, while the model describes the fluid and sediment phase characteristics in much more detail than existing measurements. With direct quantifications of velocity, turbulent kinetic energy, sediment concentration and flux, the model provides a useful approach to improve mechanistic understanding of hydrodynamic and sediment transport in the nearshore zone.

Seabed-Structure Interaction: Workshop Report and Recommendations for Future Research Held in Metairie, Louisiana on 5-6 November 1991.

DTIC Science & Technology

1992-02-01

14 Measurements of Sediment Properties and Data Analysis ............................................. 15 object...Object Sensing Methods (Detect/Classification) and (B) Sediment Properties Measurements and Data Analysis . Although important to the understanding of S...characterized by a variety of geological materials, seabed properties, and hydrodynamic processes, the problems of I modeling, analysis , and prediction of S-SI

Characterization of microbial populations across geochemical and lithological boundaries in urban lake sediments under environmental change in Minneapolis-St. Paul

NASA Astrophysics Data System (ADS)

Gilbertson, M.; Harrison, B. K.; Flood, B. E.; Myrbo, A.; Bailey, J. V.

2013-12-01

The characterization of microbial communities within urban lake sediments may offer a promising method to observe changes in lake geochemistry due to human impact. By mapping the abundances and diversity of microorganisms through the uppermost meter of sediment in three distinctive Minneapolis-St. Paul lakes (Brownie Lake and Twin Lake, both meromictic, and oligomictic Lake McCarrons) using 16S rRNA characterization, our aim was to observe changes in microbial populations across steep geochemical and lithological gradients. Lake McCarrons underwent a process of eutrophication and a shift to bottom water anoxia beginning around 1910 due mostly to agricultural run-off. This shift greatly increased the preservation potential of seasonal sedimentation and finely laminated varve accumulation. The onset of meromixis in Brownie Lake in ~1915 is abrupt and has been attributed to a sudden drop in water level. Twin Lake is perennially meromictic due to the topography of the watershed. The three lakes were sampled by collecting freeze cores in July, 2012 (McCarrons, Brownie) and February, 2013 (Twin) at the deepest locations beneath anoxic to hypoxic bottom waters. The cores were then subsampled with high resolution techniques at places of interest: within individual lamina, across mass flow deposits, and near the onset of laminae preservation (beginning of oxygen-depleted bottom waters). Terminal Restriction Fragment Length Polymorphism (T-RFLP) allows for comparison of the microbial assemblages throughout the sediment columns of each lake and from lake to lake, with a focus on the horizons mentioned previously. The microbial assemblages present in specific horizons are often introduced via sedimentation and are partially derived from community composition at the time of sedimentation. T-RFLP analyses are complemented by mineralogical and lithological descriptions. The lakes have each been subject to their own set of variables and inputs. Brownie Lake contains high levels of Fe and Mn (measured up to 78 and 6 mg/l in bottom waters, respectively, US EPA STORET). The ecology of McCarrons has been greatly disturbed most recently when the lake was targeted by a 2004 aluminum sulfate treatment to counteract high phosphorous levels. Twin Lake has mass flow deposits nearly 5 cm thick, similar to turbidites, likely caused by increased sedimentation from large housing developments on the lake shores. The microbial community in each of the lakes is impacted by these distinct parameters. This study examines variability in microbial community assemblages through time and space within these lake sediments. Changes seen in the ecology of the communities are related to changes in chemical and physical parameters, namely, shifts in lithology and sediment accumulation via the onset of meromixis. Freeze coring exceptionally allows super-high resolution subsampling techniques to identify differences across geochemical gradients and between individual seasonal laminae within each lake and from lake to lake.

Integrated Pore-Water and Geophysical Investigations StreamlineCharacterization of Ground-Water Discharges to Surface Water

EPA Science Inventory

This issue of Technology News and Trends highlights strategies and tools for characterizing or monitoring remediation of sites with contaminated sediment. Addressing these sites often relies upon dynamic workplans that involve more efficient, cost-effective, and practical methods...

Heavy metal accumulation in surface sediments at the port of Cagliari (Sardinia, western Mediterranean): Environmental assessment using sequential extractions and benthic foraminifera.

PubMed

Schintu, Marco; Marrucci, Alessandro; Marras, Barbara; Galgani, Francois; Buosi, Carla; Ibba, Angelo; Cherchi, Antonietta

2016-10-15

Superficial sediments were taken at the port of Cagliari (Sardinia, Italy), which includes the oil terminal of one of the largest oil refineries in the Mediterranean. Significant trace metal concentrations were found in the whole port area. Sequential extraction of metals from the different sediment fractions (BCR method) showed a higher risk of remobilisation for Cd, which is mostly bound to the exchangeable fraction. Foraminiferal density and richness of species were variable across the study area. The living assemblages were characterized by low diversity in samples collected close to the port areas. Ammonia tepida and bolivinids, which were positively correlated with concentrations of heavy metals and organic matter content, appeared to show tolerance to the environmental disturbance. The sampling sites characterized by the highest values of biotic indices were located far from the port areas and present an epiphytic and epifaunal biocoenosis. Copyright © 2016 Elsevier Ltd. All rights reserved.

Characterization of land-based sources of pollution in Jobos Bay, Puerto Rico: status of heavy metal concentration in bed sediment.

PubMed

Apeti, Dennis A; Whitall, David R; Pait, Anthony S; Dieppa, Angel; Zitello, Adam G; Lauenstein, Gunnar G

2012-01-01

As part of an assessment of land-based sources of pollution in Jobos Bay, Puerto Rico, sediment samples were collected at 43 sites to characterize concentrations of a suite of pollutants, including metals. Fifteen major and trace metals (Ag, Al, As, Cd, Cr, Cu, Fe, Hg, Mn Ni, Pb, Sb, Se, Sn, and Zn) were measured along with total organic carbon and grain size in surficial sediments. For most metals, maximum concentrations were seen in the eastern bay; however, values were still within concentration ranges found in other estuarine systems. In contrast, silver was higher in the western region. In general, metal distribution in the bay was positively correlated with grain size. Additionally, correlations between Al and other metals suggest natural sources for metals. The data presented here suggest that, although the Jobos Bay watershed contains both urban centers along with industrial and agricultural developments, anthropogenic inputs of metals may be negligible.

Chemical and ecotoxicological characterization of Columbia River sediments below the Hanford site (USA).

PubMed

Delistraty, Damon; Yokel, Jerry

2007-01-01

Columbia River sediments were characterized (metals, organics, porewater toxicity) with samples (n=12) from four dams below the Hanford site. Analyses were supplemented with colocated radionuclide data, along with comparable data from the Priest Rapids dam, immediately upriver from Hanford. Although not statistically significant (Bonferroni P>0.05), metals were generally highest at Priest Rapids, relative to downriver dams. Semivolatiles, Aroclors, and organochlorine pesticides were below method reporting limits. Radionuclide differences across locations were minor (Bonferroni P>0.05). Whereas Microtox showed little toxicity, Daphnia IQ tests exhibited measurable toxicity at all locations (EC50 = 22 - 78% porewater). Ecotoxicological benchmarks for metals were exceeded at several locations, most notably at Priest Rapids. Except for K-40, radionuclides were below benchmarks. Overall, chemistry and ecotoxicity results suggested that sediments may pose a risk to benthic biota, likely due to metals (derived largely from upriver mining) or factors associated with a reducing environment (e.g., low oxygen, high ammonia).

Ultrastable Natural Ester-Based Nanofluids for High Voltage Insulation Applications.

PubMed

Peppas, Georgios D; Bakandritsos, Aristides; Charalampakos, Vasilis P; Pyrgioti, Eleftheria C; Tucek, Jiri; Zboril, Radek; Gonos, Ioannis F

2016-09-28

Nanofluids for high voltage insulation systems have emerged as a potential substitute for liquid dielectrics in industrial applications. Nevertheless, the sedimentation of nanoparticles has been so far a serious barrier for their wide and effective exploitation. The present work reports on the development and in-depth characterization of colloidally ultrastable natural ester oil insulation systems containing iron oxide nanocrystals which lift the problem of sedimentation and phase separation. Compared to state-of-the-art systems, the final product is endowed with increased dielectric strength, faster thermal response, lower dielectric losses (decreased dissipation factor: tan δ), and very high endurance during discharge stressing. The developed nanofluid was studied and compared with a similar system containing commercial iron oxide nanoparticles, the latter demonstrating extensive sedimentation. Herein, the dielectric properties of the nanofluids are analyzed at various concentrations by means of breakdown voltage and dissipation factor measurements. The characterization techniques unequivocally demonstrate the high performance reliability of the reported nanofluid, which constitutes a significant breakthrough in the field of high voltage insulation technologies.

Quasi-planer-laminated sandstone beds of the Lower Cretaceous Bootlegger Member, north-central Montana: Evidence of combined-flow sedimentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnott, R.W.C.

1993-05-01

Lower-shoreface to shallow-shelf strata of the Bootlegger Member of the Lower Cretaceous Blackleaf Formation are characterized by interbedded sandstone and mudstone. Sandstone beds are characterized by a peculiar planar lamination showing a subtle although perceptible undulation; spacing-to-height ratios of the undulation are generally 100 or more. Typically the undulation shows no evidence of lateral accretion but only vertical aggradation, and as a result most beds consist of a single laminaset. Aspects of quasi-planar-laminated beds indicate single-event storm sedimentation, and paleocurrent data indicate offshore sediment transport. By its sedimentary characteristics and its similarity with a bed configuration generated in an experimentalmore » wave duct, quasi-planar lamination is produced by high-energy combined flows. This style of stratification should be common in the shallow-marine stratigraphic record, and its recognition should aid in interpreting high-energy, combined-flow depositional events.« less

Allowance for effects of thermodynamic nonideality in sedimentation equilibrium distributions reflecting protein dimerization.

PubMed

Wills, Peter R; Scott, David J; Winzor, Donald J

2012-03-01

This reexamination of a high-speed sedimentation equilibrium distribution for α-chymotrypsin under slightly acidic conditions (pH 4.1, I(M) 0.05) has provided experimental support for the adequacy of nearest-neighbor considerations in the allowance for effects of thermodynamic nonideality in the characterization of protein self-association over a moderate concentration range (up to 8 mg/mL). A widely held but previously untested notion about allowance for thermodynamic nonideality effects is thereby verified experimentally. However, it has also been shown that a greater obstacle to better characterization of protein self-association is likely to be the lack of a reliable estimate of monomer net charge, a parameter that has a far more profound effect on the magnitude of the measured equilibrium constant than any deficiency in current procedures for incorporating the effects of thermodynamic nonideality into the analysis of sedimentation equilibrium distributions reflecting reversible protein self-association. Copyright © 2011 Elsevier Inc. All rights reserved.

Geologic implications of gas hydrates in the offshore of India: Krishna-Godavari Basin, Mahanadi Basin, Andaman Sea, Kerala-Konkan Basin

USGS Publications Warehouse

Kumar, Pushpendra; Collett, Timothy S.; Boswell, Ray; Cochran, James R.; Lall, Malcolm; Mazumdar, Aninda; Ramana, Mangipudi Venkata; Ramprasad, Tammisetti; Riedel, Michael; Sain, Kalachand; Sathe, Arun Vasant; Vishwanath, Krishna; Yadav, U.S.

2014-01-01

NGHP-01 yielded evidence of gas hydrate from downhole log and core data obtained from all the sites in the Krishna–Godavari Basin, the Mahanadi Basin, and in the Andaman Sea. The site drilled in the Kerala–Konkan Basin during NGHP-01 did not yield any evidence of gas hydrate. Most of the downhole log-inferred gas hydrate and core-recovered gas hydrate were characterized as either fracture-filling in clay-dominated sediments or as pore-filling or grain-displacement particles disseminated in both fine- and coarse-grained sediments. Geochemical analyses of gases obtained from sediment cores recovered during NGHP-01 indicated that the gas in most all of the hydrates in the offshore of India is derived from microbial sources; only one site in the Andaman Sea exhibited limited evidence of a thermogenic gas source. The gas hydrate petroleum system concept has been used to effectively characterize the geologic controls on the occurrence of gas hydrates in the offshore of India.

Determination of selected heavy metal concentrations and distribution in a southwestern stream using macrophytes.

PubMed

Martinez, Edward A; Shu-Nyamboli, Chemanji

2011-09-01

Since the reduction of the arsenic standard from 50 to 10 μg L(-1) by the US Environmental Protection Agency in 2006 many small town and rural water municipalities were left with the task of preventing or mitigating arsenic contamination of drinking water supplies. In this study macrophytes and sediments were used to determine the concentration and distribution of heavy metals (As, Cd, Cu, Pb, and Zn) within the primary source of drinking water (Gallinas River watershed) to the residents of Las Vegas, New Mexico. Sampling was done in the spring and fall at four sites, two above the city and two below, and samples were analyzed using ICP-MS. Results showed significantly higher (p<.05) metal concentrations in plant roots than shoots for most metals. Spearman's correlation showed positive correlations (r>.3) between plant and sediment concentrations of Cd, Pb, Zn, As, and a negative correlation for Cu. The site above waste water treatment plant (AWWTP) had the highest plant tissue concentrations of Cd, Pb, Zn, and As. All of these concentrations attained critical toxicity levels exceeding sediment quality guidelines. High concentration factor values and levels of metals detected in macrophyte tissues indicate that heavy metals within sediments in the Gallinas River occur in bioavailable forms. Correlations between plant and sediment metal concentrations indicate that metal concentrations in macrophyte tissues are a good reflection of metal concentrations within the sediment in the Gallinas River. Copyright © 2011 Elsevier Inc. All rights reserved.

Phospholipids fatty acids of drinking water reservoir sedimentary microbial community: Structure and function responses to hydrostatic pressure and other physico-chemical properties.

PubMed

Chai, Bei-Bei; Huang, Ting-Lin; Zhao, Xiao-Guang; Li, Ya-Jiao

2015-07-01

Microbial communities in three drinking water reservoirs, with different depth in Xi'an city, were quantified by phospholipids fatty acids analysis and multivariate statistical analysis was employed to interpret their response to different hydrostatic pressure and other physico-chemical properties of sediment and overlying water. Principle component analyses of sediment characteristics parameters showed that hydrostatic pressure was the most important effect factor to differentiate the overlying water quality from three drinking water reservoirs from each other. NH4+ content in overlying water was positive by related to hydrostatic pressure, while DO in water-sediment interface and sediment OC in sediment were negative by related with it. Three drinking water reservoir sediments were characterized by microbial communities dominated by common and facultative anaerobic Gram-positive bacteria, as well as, by sulfur oxidizing bacteria. Hydrostatic pressure and physico-chemical properties of sediments (such as sediment OC, sediment TN and sediment TP) were important effect factors to microbial community structure, especially hydrostatic pressure. It is also suggested that high hydrostatic pressure and low dissolved oxygen concentration stimulated Gram-positive and sulfate-reducing bacteria (SRB) bacterial population in drinking water reservoir sediment. This research supplied a successful application of phospholipids fatty acids and multivariate analysis to investigate microbial community composition response to different environmental factors. Thus, few physico-chemical factors can be used to estimate composition microbial of community as reflected by phospholipids fatty acids, which is difficult to detect.

Physical abrasion of mafic minerals and basalt grains: application to Martian aeolian deposits

USGS Publications Warehouse

Cornwall, Carin; Bandfield, Joshua L.; Titus, Timothy N.; Schreiber, B. C.; Montgomery, D.R.

2015-01-01

Sediment maturity, or the mineralogical and physical characterization of sediment deposits, has been used to locate sediment source, transport medium and distance, weathering processes, and paleoenvironments on Earth. Mature terrestrial sands are dominated by quartz, which is abundant in source lithologies on Earth and is physically and chemically stable under a wide range of conditions. Immature sands, such as those rich in feldspars or mafic minerals, are composed of grains that are easily physically weathered and highly susceptible to chemical weathering. On Mars, which is predominately mafic in composition, terrestrial standards of sediment maturity are not applicable. In addition, the martian climate today is cold, dry and sediments are likely to be heavily influenced by physical weathering rather than chemical weathering. Due to these large differences in weathering processes and composition, martian sediments require an alternate maturity index. Abrason tests have been conducted on a variety of mafic materials and results suggest that mature martian sediments may be composed of well sorted, well rounded, spherical basalt grains. In addition, any volcanic glass present is likely to persist in a mechanical weathering environment while chemically altered products are likely to be winnowed away. A modified sediment maturity index is proposed that can be used in future studies to constrain sediment source, paleoclimate, mechanisms for sediment production, and surface evolution. This maturity index may also provide details about erosional and sediment transport systems and preservation processes of layered deposits.

Magnetic Signature of Glacial Flour in Sediments From Bear Lake, Utah/Idaho

NASA Astrophysics Data System (ADS)

Rosenbaum, J. G.; Dean, W. E.; Colman, S. M.; Reynolds, R. L.

2002-12-01

Variations in magnetic properties within an interval of Bear Lake sediments correlative with oxygen isotope stage 2 (OIS 2) and OIS 3 provide a record of glacial flour production for the Uinta Mountains. Like sediments of the same age from Upper Klamath Lake (OR), these Bear Lake sediments have high magnetic susceptibilities (MS) relative to non-glacial-age sediments and contain well-defined millennial-scale variations in magnetic properties. In contrast to glacial flour derived from volcanic rocks surrounding Upper Klamath Lake, glacial flour derived from the Uinta Mountains and deposited in Bear Lake by the Bear River has low magnetite content but high hematite content. The relatively low MS values of younger and older non-glacial-age sediments are due entirely to dilution by non-magnetic endogenic carbonate and to the effects of sulfidic alteration of detrital Fe-oxides. Analysis of samples from streams entering Bear Lake and from along the course of the Bear River demonstrates that, in comparison to other areas of the catchment, sediment derived from the Uinta Mountains is rich in hematite (high HIRM) and aluminum, and poor in magnetite (low MS) and titanium. Within the glacial-age lake sediments, there are strong positive correlations among HIRM, Al/Ti, and fine sediment grain size. MS varies inversely with theses three variables. These relations indicate that the observed millennial-scale variations in magnetic and chemical properties arise from varying proportions of two detrital components: (1) very fine-grained glacial flour derived from Proterozoic metasedimentary rocks in the Uinta Mountains and characterized by high HIRM and low MS, and (2) somewhat coarser material, characterized by higher MS and lower HIRM, derived from widespread sedimentary rocks along the course of the Bear River and around Bear Lake. Measurement of glacial flour incorporated in lake sediments can provide a continuous history of alpine glaciation, because the rate of accumulation of glacial flour probably varies closely with the areal extent of glaciation. In the absence of post-depositional alteration of magnetic minerals, magnetic measurements can provide a highly sensitive tool for assessing variations in glacial flour content if glacial and non-glacial materials have contrasting magnetic properties. For Bear Lake, the required contrast is produced by differences in bedrock underlying glaciated and unglaciated areas.

Changes in Depositional Setting Reflect Rising Sealevel in Latest Holocene Sediments of the Hudson River

NASA Astrophysics Data System (ADS)

Slagle, A.; Carbotte, S. M.; Ryan, W. B.; Bell, R.; Nitsche, F. O.; McHugh, C. M.

2002-12-01

An extensive database of geophysical and sampling data in the Hudson River has been obtained in ten study areas between the New York Harbor and the Troy Dam. These data include bathymetry, bank-to-bank coverage of side-looking sonar imagery, subbottom reflection profiles, sediment cores and grabs. Geophysical properties, including gamma density, magnetic susceptibility and P-wave velocity, have been measured in a 9.3 m Vibracore (SD-30) from the near-channel tidal flats of the Tappan Zee area. Three distinct sedimentary facies have been identified, based on changes in physical properties, lithology and seismic reflections. Facies 1 is an oyster-rich unit with unstratified sediments and high sound velocities, and is found in the upper 1.5 m of core SD-30. Chirp subbottom data, which provide reflectors down to approximately 4 m depth, show a distinct horizon at 1.5 m, supporting the change seen in physical property data and lithology at this depth. A unit characterized by laminated sediments, interbedded with homogeneous layers and coquina layers, is identified as Facies 2 and is found between 1.5 and 6.1 m. This facies has high magnetic susceptibility and the appearance of discrete density cycles. The oldest unit, Facies 3, extends from 6.1 m to the base of the core at 9.3 m. It is made up of oyster-rich, unbedded sediments and thick coquina layers, and is characterized by low magnetic susceptibility. Radiocarbon dating of oysters and bivalves indicates that the different facies in SD-30 correspond to different sedimentation rates, with highest values occurring during deposition of Facies 2. The facies changes and variations in sedimentation rates are attributed to an evolving depositional environment in the tidal flats of the Tappan Zee area due to rising sealevel. Extrapolating from nearby cores that penetrate deeper into the sedimentary record, Facies 3 sits above post-glacial fluvial sands and represents the transition from a fresh to more brackish environment, suitable for development of oyster beds. The laminated sediments of Facies 2 are attributed to infilling of the tidal flats during a rapid rise in sealevel. The lack of laminated sediments and low sedimentation rates of Facies 1 are attributed to the modern wave-base dominated depositional setting in the Tappan Zee area.

Linking high-resolution geomorphic mapping, sediment sources, and channel types in a formerly glaciated basin of northeastern Alto-Adige/Sudtirol, Italy

NASA Astrophysics Data System (ADS)

Brardinoni, F.; Perina, E.; Bonfanti, G.; Falsitta, G.; Agliardi, F.

2012-04-01

To characterize channel-network morphodynamics and response potential in the Gadria-Strimm basin (14.8 km^2) we conduct a concerted effort entailing: (i) high-resolution mapping of landforms, channel reaches, and sediment sources; and (ii) historical evolution of colluvial channel disturbance through sequential aerial photosets (1945-59-69-82-90-00-06-11). The mapping was carried out via stereographic inspection of aerial photographs, examination of 2.5-m gridded DTM and DSM, and extensive field work. The study area is a formerly glaciated basin characterized by peculiar landform assemblages imposed by a combination of tectonic and glacial first-order structures. The most striking feature in Strimm Creek is a structurally-controlled valley step separating an upper hanging valley, dominated by periglacial and fluvial processes, and a V-notched lower part in which lateral colluvial channels are directly connected to Strimm's main stem. In Gadria Creek, massive kame terraces located in proximity of the headwaters provide virtually unlimited sediment supply to frequent debris-flow activity, making this sub-catchment an ideal site for monitoring, hence studying the mechanics of these processes. Preliminary results point to a high spatial variability of the colluvial channel network, in which sub-sectors have remained consistently active during the study period while others have become progressively dormant with notable forest re-growth. In an attempt to link sediment flux to topography and substrate type, future work will involve photogrammetric analysis across the sequential aerial photosets as well as a morphometric/geomechanical characterization of the surficial materials.

Shallow geology, sea-floor texture, and physiographic zones of Vineyard and western Nantucket Sounds, Massachusetts

USGS Publications Warehouse

Baldwin, Wayne E.; Foster, David S.; Pendleton, Elizabeth A.; Barnhardt, Walter A.; Schwab, William C.; Andrews, Brian D.; Ackerman, Seth D.

2016-09-02

Geologic, sediment texture, and physiographic zone maps characterize the sea floor of Vineyard and western Nantucket Sounds, Massachusetts. These maps were derived from interpretations of seismic-reflection profiles, high-resolution bathymetry, acoustic-backscatter intensity, bottom photographs/video, and surficial sediment samples collected within the 494-square-kilometer study area. Interpretations of seismic stratigraphy and mapping of glacial and Holocene marine units provided a foundation on which the surficial maps were created. This mapping is a result of a collaborative effort between the U.S. Geological Survey and the Massachusetts Office of Coastal Zone Management to characterize the surface and subsurface geologic framework offshore of Massachusetts.

A rock-magnetic record from Lake Baikal, Siberia: Evidence for Late Quaternary climate change

USGS Publications Warehouse

Peck, J.A.; King, J.W.; Colman, Steven M.; Kravchinsky, V.A.

1994-01-01

Rock-magnetic measurements of sediment cores from the Academician Ridge region of Lake Baikal, Siberia show variations related to Late Quaternary climate change. Based upon the well-dated last glacial-interglacial transition, variations in magnetic concentration and mineralogy are related to glacial-interglacial cycles using a conceptual model. Interglacial intervals are characterized by low magnetic concentrations and a composition that is dominated by low coercivity minerals. Glacial intervals are characterized by high magnetic concentrations and increased amounts of high coercivity minerals. The variation in magnetic concentration is consistent with dilution by diatom opal during the more productive interglacial periods. We also infer an increased contribution of eolian sediment during the colder, windier, and more arid glacial conditions when extensive loess deposits were formed throughout Europe and Asia. Eolian transport is inferred to deliver increased amounts of high coercivity minerals as staining on eolian grains during the glacial intervals. Variations in magnetic concentration and mineralogy of Lake Baikal sediment correlate to the SPECMAP marine oxygen-isotope record. The high degree of correlation between Baikal magnetic concentration/mineralogy and the SPECMAP oxygen-isotope record indicates that Lake Baikal sediment preserves a history of climate change in central Asia for the last 250 ka. This correlation provides a method of estimating the age of sediment beyond the range of the radiocarbon method. Future work must include providing better age control and additional climate proxy data, thereby strengthening the correlation of continental and marine climate records. ?? 1994.

Impact of natural oil and higher hydrocarbons on microbial diversity, distribution, and activity in Gulf of Mexico cold-seep sediments

NASA Astrophysics Data System (ADS)

Orcutt, Beth N.; Joye, Samantha B.; Kleindienst, Sara; Knittel, Katrin; Ramette, Alban; Reitz, Anja; Samarkin, Vladimir; Treude, Tina; Boetius, Antje

2010-11-01

Gulf of Mexico cold seeps characterized by variable compositions and magnitudes of hydrocarbon seepage were sampled in order to investigate the effects of natural oils, methane, and non-methane hydrocarbons on microbial activity, diversity, and distribution in seafloor sediments. Though some sediments were characterized by relatively high quantities of oil, which may be toxic to some microorganisms, high rates of sulfate reduction (SR, 27.9±14.7 mmol m-2 d-1), anaerobic oxidation of methane (AOM, 16.2±6.7 mmol m-2 d-1), and acetate oxidation (2.74±0.76 mmol m-2 d-1) were observed in radiotracer measurements. In many instances, the SR rate was higher than the AOM rate, indicating that non-methane hydrocarbons fueled SR. Analysis of 16S rRNA gene clone libraries revealed phylogenetically diverse communities that were dominated by phylotypes of sulfate-reducing bacteria (SRB) and anaerobic methanotrophs of the ANME-1 and ANME-2 varieties. Another group of archaea form a Gulf of Mexico-specific clade (GOM ARC2) that may be important in brine-influenced, oil-impacted sediments from deeper water. Additionally, species grouping within the uncultivated Deltaproteobacteria clades SEEP-SRB3 and -SRB4, as well as relatives of Desulfobacterium anilini, were observed in relatively higher abundance in the oil-impacted sediments, suggesting that these groups of SRB may be involved in or influenced by degradation of higher hydrocarbons or petroleum byproducts.

Effects of fluidization of the host sediment on peperite textures: A field example from the Cretaceous Buan Volcanics, SW Korea

NASA Astrophysics Data System (ADS)

Gihm, Yong Sik; Kwon, Chang Woo

2017-04-01

In the Cretaceous Buan Volcanics (SW Korea), blocky and fluidal peperites are hosted in a massive pumiceous lapilli tuff intruded by intermediate dikes. Blocky peperites, the most abundant species, are characterized by polyhedral or platy juvenile clasts and a jigsaw-crack texture. Fluidal peperites occur only along dike margins, where the host sediments are composed of well sorted, fine to very fine ash (fine-grained zone), and are characterized by fluidal or globular juvenile clasts with irregular or ragged margins. The fine-grained zone is interpreted to form by grain size segregation caused by upward moving pore water (fluidization) that has resulted from heat transfer from intruding magma toward waterlogged host sediments during intrusion. With the release of pore water and the selective entrainment of fine-grained ash, fine-grained zones formed within the host sediments. Subsequent interactions between the fine-grained zone and the intruding magma resulted in ductile deformation of the magma before fragmentation, which generated fluidal peperites. Outside the fine-grained zone, intruding magma fragmented in a brittle manner because of the relative deficiency of both pore water and fine-grained ash, resulting in the formation of blocky peperites. The results of this study suggest that redistribution of constituent particles (ash) and interstitial fluids during fluidization resulted in heterogeneous physical conditions of the host sediments, which influenced peperite-forming processes, as reflected by the different peperite textures.

Methane hydrate formation in turbidite sediments of northern Cascadia, IODP Expedition 311

USGS Publications Warehouse

Torres, M.E.; Trehu, A.M.; Cespedes, N.; Kastner, M.; Wortmann, U.G.; Kim, J.-H.; Long, P.; Malinverno, A.; Pohlman, J.W.; Riedel, M.; Collett, T.

2008-01-01

Expedition 311 of the Integrated Ocean Drilling Program (IODP) to northern Cascadia recovered gas-hydrate bearing sediments along a SW-NE transect from the first ridge of the accretionary margin to the eastward limit of gas-hydrate stability. In this study we contrast the gas gas-hydrate distribution from two sites drilled ~ 8??km apart in different tectonic settings. At Site U1325, drilled on a depositional basin with nearly horizontal sedimentary sequences, the gas-hydrate distribution shows a trend of increasing saturation toward the base of gas-hydrate stability, consistent with several model simulations in the literature. Site U1326 was drilled on an uplifted ridge characterized by faulting, which has likely experienced some mass wasting events. Here the gas hydrate does not show a clear depth-distribution trend, the highest gas-hydrate saturation occurs well within the gas-hydrate stability zone at the shallow depth of ~ 49??mbsf. Sediments at both sites are characterized by abundant coarse-grained (sand) layers up to 23??cm in thickness, and are interspaced within fine-grained (clay and silty clay) detrital sediments. The gas-hydrate distribution is punctuated by localized depth intervals of high gas-hydrate saturation, which preferentially occur in the coarse-grained horizons and occupy up to 60% of the pore space at Site U1325 and > 80% at Site U1326. Detailed analyses of contiguous samples of different lithologies show that when enough methane is present, about 90% of the variance in gas-hydrate saturation can be explained by the sand (> 63????m) content of the sediments. The variability in gas-hydrate occupancy of sandy horizons at Site U1326 reflects an insufficient methane supply to the sediment section between 190 and 245??mbsf. ?? 2008 Elsevier B.V.

A Risk-Based Characterization of Sediment Contamination by Legacy and Emergent Contaminants of Concern in Coastal British Columbia, Canada.

PubMed

Morales-Caselles, Carmen; Desforges, Jean-Pierre W; Dangerfield, Neil; Ross, Peter S

2017-08-01

Sediments have long been used to help describe pollution sources, contaminated sites, trends over time, and habitat quality for marine life. We collected surficial sediments from 12 sites at an average seawater depth of 25 m in three near-urban areas of the Salish Sea (British Columbia, Canada) to investigate habitat quality for marine life, including heavily contaminated killer whales. Samples were analyzed using high-resolution instrumentation for a wide variety of congeners of polychlorinated biphenyls (PCBs), polybrominated diphenylethers (PBDEs), hexabromocyclododecane (HBCDD), polybrominated biphenyls, polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans, organochlorine pesticides, and polychlorinated naphthalenes (PCNs). The top six contaminant classes detected in sediments were ∑PCB > ∑PBDE > ∑PCDD/F > DDT > ∑HBCDD > ∑PCN. Near-urban harbor sediments had up to three orders of magnitude higher concentrations of contaminants than more remote sites. With limited tools available to characterize biological risks associated with complex mixtures in the real world, we applied several available approaches to prioritize the pollutant found in our study: (1) sediment quality guidelines from the Canadian Council of Ministers of the Environment where available; (2) US NOAA effects range low and other international guidelines; (3) total TEQ for dioxin-like PCBs for the protection of mammals; and (4) the calculation of risk quotients. Our findings provide an indication of the state of contamination of coastal environments in British Columbia and guidance for chemical regulations and priority setting, as well as management actions including best-practices, dredging, disposal at sea, and source control. In this regard, the legacy PCB and the emergent PBDEs should command continued priority monitoring.

Marine coastal sediments microbial hydrocarbon degradation processes: contribution of experimental ecology in the omics’era

PubMed Central

Cravo-Laureau, Cristiana; Duran, Robert

2014-01-01

Coastal marine sediments, where important biological processes take place, supply essential ecosystem services. By their location, such ecosystems are particularly exposed to human activities as evidenced by the recent Deepwater Horizon disaster. This catastrophe revealed the importance to better understand the microbial processes involved on hydrocarbon degradation in marine sediments raising strong interests of the scientific community. During the last decade, several studies have shown the key role played by microorganisms in determining the fate of hydrocarbons in oil-polluted sediments but only few have taken into consideration the whole sediment’s complexity. Marine coastal sediment ecosystems are characterized by remarkable heterogeneity, owning high biodiversity and are subjected to fluctuations in environmental conditions, especially to important oxygen oscillations due to tides. Thus, for understanding the fate of hydrocarbons in such environments, it is crucial to study microbial activities, taking into account sediment characteristics, physical-chemical factors (electron acceptors, temperature), nutrients, co-metabolites availability as well as sediment’s reworking due to bioturbation activities. Key information could be collected from in situ studies, which provide an overview of microbial processes, but it is difficult to integrate all parameters involved. Microcosm experiments allow to dissect in-depth some mechanisms involved in hydrocarbon degradation but exclude environmental complexity. To overcome these lacks, strategies have been developed, by creating experiments as close as possible to environmental conditions, for studying natural microbial communities subjected to oil pollution. We present here a review of these approaches, their results and limitation, as well as the promising future of applying “omics” approaches to characterize in-depth microbial communities and metabolic networks involved in hydrocarbon degradation. In addition, we present the main conclusions of our studies in this field. PMID:24575083

Sediment delivery and lake dynamics in a Mediterranean mountain watershed: Human-climate interactions during the last millennium (El Tobar Lake record, Iberian Range, Spain).

PubMed

Barreiro-Lostres, Fernando; Brown, Erik; Moreno, Ana; Morellón, Mario; Abbott, Mark; Hillman, Aubrey; Giralt, Santiago; Valero-Garcés, Blas

2015-11-15

Land degradation and soil erosion are key environmental problems in Mediterranean mountains characterized by a long history of human occupation and a strong variability of hydrological regimes. To assess recent trends and evaluate climatic and anthropogenic impacts in these highly human modified watersheds we apply an historical approach combining lake sediment core multi-proxy analyses and reconstructions of past land uses to El Tobar Lake watershed, located in the Iberian Range (Central Spain). Four main periods of increased sediment delivery have been identified in the 8m long sediment sequence by their depositional and geochemical signatures. They took place around 16th, late 18th, mid 19th and early 20th centuries as a result of large land uses changes such as forest clearing, farming and grazing during periods of increasing population. In this highly human-modified watershed, positive synergies between human impact and humid periods led to increased sediment delivery periods. During the last millennium, the lake depositional and geochemical cycles recovered quickly after each sediment delivery event, showing strong resilience of the lacustrine system to watershed disturbance. Recent changes are characterized by large hydrological affections since 1967 with the construction of a canal from a nearby reservoir and a decreased in anthropic pressure in the watershed as rural areas were abandoned. The increased fresh water influx to the lake has caused large biological changes, leading to stronger meromictic conditions and higher organic matter accumulation while terrigenous inputs have decreased. Degradation processes in Iberian Range watersheds are strongly controlled by anthropic activities (land use changes, soil erosion) but modulated by climate-related hydrological changes (water availability, flood and runoff frequency). Copyright © 2015 Elsevier B.V. All rights reserved.

Asian dust input in the western Philippine Sea: Evidence from radiogenic Sr and Nd isotopes

NASA Astrophysics Data System (ADS)

Jiang, Fuqing; Frank, Martin; Li, Tiegang; Chen, Tian-Yu; Xu, Zhaokai; Li, Anchun

2013-05-01

The radiogenic strontium (Sr) and neodymium (Nd) isotope compositions of the detrital fraction of surface and subsurface sediments have been determined to trace sediment provenance and contributions from Asian dust off the east coast of Luzon Islands in the western Philippine Sea. The Sr and Nd isotope compositions have been very homogenous near the east coast of the Luzon Islands during the latest Quaternary yielding relatively least radiogenic Sr (87Sr/86Sr = 0.70453 to 0.70491) and more radiogenic Nd isotope compositions (ɛNd(0) = +5.3 to +5.5). These isotope compositions are similar to Luzon rocks and show that these sediments were mainly derived from the Luzon Islands. In contrast, the Sr and Nd isotope compositions of sediments on the Benham Rise and in the Philippine Basin are markedly different in that they are characterized by overall more variable and more radiogenic Sr isotope compositions (87Sr/86Sr = 0.70452 to 0.70723) and less radiogenic Nd isotope compositions (ɛNd(0) = -5.3 to +2.4). The Sr isotope composition in the Huatung Basin is intermediate between those of the east coast of Luzon and Benham Rise, but shows the least radiogenic Nd isotope compositions. The data are consistent with a two end-member mixing relationship between Luzon volcanic rocks and eolian dust from the Asian continent, which is characterized by highly radiogenic Sr and unradiogenic Nd isotope compositions. The results show that Asian continental dust contributes about 10-50% of the detrital fraction of the sediments on Benham Rise in the western Philippine Sea, which offers the potentials to reconstruct the climatic evolution of eastern Asia from these sediments and compare this information to the records from the central and northern Pacific.

Distribution and contamination status of chromium in surface sediments of northern Kaohsiung Harbor, Taiwan.

PubMed

Dong, Cheng-Di; Chen, Chiu-Wen; Chen, Chih-Feng

2013-07-01

The distribution, enrichment, accumulation, and potential ecological risk of chromium (Cr) in the surface sediments of northern Kaohsiung Harbor, Taiwan, China were investigated. Sediment samples from ten locations located between the river mouths and harbor entrance of northern Kaohsiung Harbor were collected quarterly in 2011 and characterized for Cr, aluminum, water content, organic matter, total nitrogen, total phosphorous, total grease, and grain size. Results showed that the Cr concentrations varied from 27.0 to 361.9 mg/kg with an average of (113.5 +/- 87.0) mg/kg. High Cr concentration was observed near the Jen-Gen River mouth. The mean Cr concentration was high at 255.5 mg/kg, which was at least 2 to 7 times than that of other sites. This might imply significant Cr contribution from upstream receiving tanneries wastewater into the Jen-Gen River. The spatial distribution of Cr reveals relatively high in the river mouth region, especially in Jen-Gen River, and gradually diminishes toward the harbor entrance region. This indicates that the major sources of Cr pollution from upstream industrial and municipal wastewaters discharged along the river bank; and Cr may drift with sea current and be dispersed into open sea. Moreover, Cr concentrations correlated closely to the physical-chemical properties of the sediments, which suggested the influence of industrial and municipal wastewaters discharged from the neighboring industrial parks and river basins. Results from the enrichment factor and geo-accumulation index analyses imply that the Jen-Gen River sediments can be characterized as moderate enrichment and none to medium accumulation of Cr, respectively. However, results of potential ecological risk index indicate that the sediment has low ecological potential risk. The results can provide valuable information to developing future strategies for the management of river mouth and harbor.

Water erosion and climate change in a small alpine catchment

NASA Astrophysics Data System (ADS)

Berteni, Francesca; Grossi, Giovanna

2017-04-01

WATER EROSION AND CLIMATE CHANGE IN A SMALL ALPINE CATCHMENT Francesca Berteni, Giovanna Grossi A change in the mean and variability of some variables of the climate system is expected to affect the sediment yield of mountainous areas in several ways: for example through soil temperature and precipitation peak intensity change, permafrost thawing, snow- and ice-melt time shifting. Water erosion, sediment transport and yield and the effects of climate change on these physical phenomena are the focus of this work. The study area is a small mountainous basin, the Guerna creek watershed, located in the Central Southern Alps. The sensitivity of sediment yield estimates to a change of condition of the climate system may be investigated through the application of different models, each characterized by its own features and limits. In this preliminary analysis two different empirical mathematical models are considered: RUSLE (Revised Universal Soil Loss Equation; Renard et al., 1991) and EPM (Erosion Potential Method; Gavrilovic, 1988). These models are implemented in a Geographical Information System (GIS) supporting the management of the territorial database used to estimate relevant geomorphological parameters and to create different thematic maps. From one side the geographical and geomorphological information is required (land use, slope and hydrogeological instability, resistance to erosion, lithological characterization and granulometric composition). On the other side the knowledge of the weather-climate parameters (precipitation and temperature data) is fundamental as well to evaluate the intensity and variability of the erosive processes and estimate the sediment yield at the basin outlet. Therefore different climate change scenarios were considered in order to tentatively assess the impact on the water erosion and sediment yield at the small basin scale. Keywords: water erosion, sediment yield, climate change, empirical mathematical models, EPM, RUSLE, GIS, Guerna

Sea-floor morphology and sedimentary environments of western Block Island Sound, northeast of Gardiners Island, New York

USGS Publications Warehouse

McMullen, Katherine Y.; Poppe, Lawrence J.; Danforth, William W.; Blackwood, Dann S.; Clos, Andrew R.; Parker, Castle E.

2014-01-01

Multibeam-echosounder data, collected during survey H12299 by the National Oceanic and Atmospheric Administration in a 162-square-kilometer area of Block Island Sound, northeast of Gardiners Island, New York, are used along with sediment samples and bottom photography, collected at 37 stations in this area by the U.S. Geological Survey during cruise 2013-005-FA, to interpret sea-floor features and sedimentary environments. These data and interpretations provide important base maps for future studies of the sea floor, focused, for example, on benthic ecology and resource management. The features and sedimentary environments on the sea floor are products of the glacial history and modern tidal regime. Features include bedforms such as sand waves and megaripples, boulders, a large current-scoured depression, exposed glaciolacustrine sediments, and areas of modern marine sediment. Sand covers much of the study area and is often in the form of sand waves and megaripples, which indicate environments characterized by coarse-grained bedload transport. Boulders and gravelly lag deposits, which indicate environments of erosion or nondeposition, are found off the coast of Gardiners Island and on bathymetric highs, probably marking areas where deposits associated with recessional ice-front positions, the northern flank of the terminal moraine, or coastal-plain sediments covered with basal till are exposed. Bottom photographs and video of boulders show that they are commonly covered with sessile fauna. Strong tidal currents have produced the deep scour depression along the northwestern edge of the study area. The eastern side of this depression is armored with a gravel lag. Sea-floor areas characterized by modern marine sediments appear featureless at the 2-meter resolution of the bathymetry and flat to current rippled in the photography. These modern environments are indicative of sediment sorting and reworking.

Geoacoustic Characterization of the Mud Drape at the New England Mud Patch

NASA Astrophysics Data System (ADS)

Reed, A. H.

2016-02-01

The New England Mud Patch is an extensive deposit of fine-grained sediments that extends from an area south of Cape Cod, MA to south of Montauk Point Long Island, NY out on the continental shelf in water depths of 60 to 90 meters. The mud patch has a remarkable accumulation of up to a 13 meter thick sequence of mud that overlays a transgressive surface of Pleistocene Age and then thins out on the periphery where surficial sediments convert from mud to sand and sand/gravel. The deposit likely accumulated in this region due to the coalescing of shelf currents that had oppositional flow. This work focuses on a section of the mud patch that is centered over the thickest portion of mud and extends east-west for 30 km and north south for 10 km. Gravity cores were collected throughout this region and the cores penetrated the upper 2-4 m of mud at 28 different sites with multiple cores collected in several locations. The mud thickness in these regions exceeded the core barrel length, therefore the cores did not penetrate into the basal sand sediment layer, a relict transgressional horizon, which displays prominently in the acoustic data for this selected region. These cores were evaluated for compressional sound speed (averaging 1480 m/s) and density (1580 kg/m3) and found to be largely homogeneous and similar throughout the study area. The largest source of inhomogeneity was due to dispersed shell hash and disarticulated bivalves, but these inclusions represent minor components in the total sediment volume. The overlying sediment that characterizes the New England Mud Patch can be readily classified as mud, silty mud, or sandy-silty mud. This fine-grained sediment deposit reflects upon the low-energy nature of the hydrodynamics within this region.

Predicting watershed post-fire sediment yield with the InVEST sediment retention model: Accuracy and uncertainties

USGS Publications Warehouse

Sankey, Joel B.; McVay, Jason C.; Kreitler, Jason R.; Hawbaker, Todd J.; Vaillant, Nicole; Lowe, Scott

2015-01-01

Increased sedimentation following wildland fire can negatively impact water supply and water quality. Understanding how changing fire frequency, extent, and location will affect watersheds and the ecosystem services they supply to communities is of great societal importance in the western USA and throughout the world. In this work we assess the utility of the InVEST (Integrated Valuation of Ecosystem Services and Tradeoffs) Sediment Retention Model to accurately characterize erosion and sedimentation of burned watersheds. InVEST was developed by the Natural Capital Project at Stanford University (Tallis et al., 2014) and is a suite of GIS-based implementations of common process models, engineered for high-end computing to allow the faster simulation of larger landscapes and incorporation into decision-making. The InVEST Sediment Retention Model is based on common soil erosion models (e.g., USLE – Universal Soil Loss Equation) and determines which areas of the landscape contribute the greatest sediment loads to a hydrological network and conversely evaluate the ecosystem service of sediment retention on a watershed basis. In this study, we evaluate the accuracy and uncertainties for InVEST predictions of increased sedimentation after fire, using measured postfire sediment yields available for many watersheds throughout the western USA from an existing, published large database. We show that the model can be parameterized in a relatively simple fashion to predict post-fire sediment yield with accuracy. Our ultimate goal is to use the model to accurately predict variability in post-fire sediment yield at a watershed scale as a function of future wildfire conditions.

Towards a better understanding on how large wood is controlling longitudinal sediment (dis)connectivity in mountain streams - concepts and first results

NASA Astrophysics Data System (ADS)

Schuchardt, Anne; Pöppl, Ronald; Morche, David

2016-04-01

Large wood (LW) provides various ecological and morphological functions. Recent research has focused on habitat diversity and abundance, effects on channel planforms, pool formation, flow regimes and increased storage of organic matter as well as storage of fine sediment. While LW studies and sediment transport rates are the focus of numerous research questions, the influence of large channel blocking barriers (e.g. LW) and their impact on sediment trapping and decoupling transportation pathways is less studied. This project tries to diminish the obvious gap and deals with the modifications of the sediment connectivity by LW. To investigate the influence of large wood on sediment transporting processes and sediment connectivity, the spatial distribution and characterization of LW (>1 m in length and >10 cm in diameter) in channels is examined by field mapping and dGPS measurements. Channel hydraulic parameters are determined by field measurements of channel long profiles and cross sections. To quantify the direct effects of LW on discharge and bed load transport the flow velocity and bed load up- and downstream of LW is measured using an Ott-Nautilus and a portable Helley-Smith bed load sampler during different water stages. Sediment storages behind LWD accumulations will be monitored with dGPS. While accumulation of sediment indicates in-channel sediment storage and thus disconnection from downstream bed load transport, erosion of sediment evidences downstream sediment connectivity. First results will be presented from two study areas in mountain ranges in Germany (Wetterstein Mountain Range) and Austria (Bohemian Massif).

Occurrence, distribution, and volume of metals-contaminated sediment of selected streams draining the Tri-State Mining District, Missouri, Oklahoma, and Kansas, 2011–12

USGS Publications Warehouse

Smith, D. Charlie

2016-12-14

Lead and zinc were mined in the Tri-State Mining District (TSMD) of southwest Missouri, northeast Oklahoma, and southeast Kansas for more than 100 years. The effects of mining on the landscape are still evident, nearly 50 years after the last mine ceased operation. The legacies of mining are the mine waste and discharge of groundwater from underground mines. The mine-waste piles and underground mines are continuous sources of trace metals (primarily lead, zinc, and cadmium) to the streams that drain the TSMD. Many previous studies characterized the horizontal extent of mine-waste contamination in streams but little information exists on the depth of mine-waste contamination in these streams. Characterizing the vertical extent of contamination is difficult because of the large amount of coarse-grained material, ranging from coarse gravel to boulders, within channel sediment. The U.S. Geological Survey, in cooperation with U.S. Fish and Wildlife service, collected channel-sediment samples at depth for subsequent analyses that would allow attainment of the following goals: (1) determination of the relation between concentration and depth for lead, zinc and cadmium in channel sediments and flood-plain sediments, and (2) determination of the volume of gravel-bar sediment from the surface to the maximum depth with concentrations of these metals that exceeded sediment-quality guidelines. For the purpose of this report, volume of gravel-bar sediment is considered to be distributed in two forms, gravel bars and the wetted channel, and this study focused on gravel bars. Concentrations of lead, zinc, and cadmium in samples were compared to the consensus probable effects concentration (CPEC) and Tri-State Mining District specific probable effects concentration (TPEC) sediment-quality guidelines.During the study, more than 700 sediment samples were collected from borings at multiple sites, including gravel bars and flood plains, along Center Creek, Turkey Creek, Shoal Creek, Tar Creek, and Spring River in order to characterize the vertical extent of mine waste in select streams in the TSMD. The largest concentrations of lead, zinc, and cadmium in gravel bar-sediment samples generally were detected in Turkey Creek and Tar Creek and the smallest concentrations were detected in Shoal Creek followed by the Spring River. Gravel bar-sediment samples from Turkey Creek exceeded the CPEC for cadmium (minimum of 70 percent of samples), lead (94 percent), and zinc (99 percent) at a slightly higher frequency than similar samples from Tar Creek (69 percent, 88 percent, and 96 percent, respectively). Gravel bar-sediment samples from Turkey Creek also contained the largest concentrations of cadmium (174 milligrams per kilogram [mg/kg]) and lead (7,520 mg/kg) detected; however, the largest zinc concentration (46,600 mg/kg) was detected in a gravel bar-sediment sample from Tar Creek. In contrast, none of the 65 gravel bar-sediment samples from Shoal Creek contained cadmium above the x-ray fluorescence reporting level of 12 mg/kg, and lead and zinc exceeded the CPEC in only 12 percent and 74 percent of samples, respectively. In most cases, concentrations of lead and zinc above the CPEC or TPEC were present at the maximum depth of boring, which indicated that nearly the entire thickness of sediment in the stream has been contaminated by mine wastes. Approximately 284,000 cubic yards of channel sediment from land surface to the maximum depth that exceeded the CPEC and approximately 236,000 cubic yards of channel sediment from land surface to the maximum depth that exceeded the TPEC were estimated along 37.6 of the 55.1 miles of Center Creek, Turkey Creek, Shoal Creek, and Tar Creek examined in this study. Mine-waste contamination reported along additional reaches of these streams is beyond the scope of this study. Flood-plain cores collected in the TSMD generally only had exceedances of the CPEC and TPEC for lead and zinc in the top 1 or 2 feet of soil with a few exceptions, such as cores in low areas near the stream or cores in areas disturbed by past mining.

Quantification of the Bioturbation Activity of Lumbriculus Variegatus Worms Using Fluorescent Particulate Tracers

NASA Astrophysics Data System (ADS)

Hernandez-Gonzalez, L. M.; Roche, K. R.; Xie, M.; Packman, A. I.

2014-12-01

Important biological, physical and chemical processes, such as fluxes of oxygen, nutrients and contaminants, occur across sediment-water interfaces. These processes are influenced by bioturbation activities of benthic animals. Bioturbation is thought to be significant in releasing metals to the water column from contaminated sediments, but metals contamination also affects organism activity. Consequently, the aim of this study was to consider the interactions of biological activity, sediment chemistry, pore water transport, and chemical reactions in sediment mixing and the flux and toxicity of metals in sediments. Prior studies have modeled bioturbation as a diffusive process. However, diffusion models often do not describe accurately sediment mixing due to bioturbation. To this end, we used the continuous time random walk (CTRW) model to assess sediment mixing caused by bioturbation activity of Lumbriculus variegatus worms. We performed experiments using fine-grained sediments with different levels of zinc contamination from Lake DePue, which is a Superfund Site in Illinois. The tests were conducted in an aerated fresh water chamber. Fluorescent particulate tracers were added to the sediment surface to quantify mixing processes and the influence of metals contaminants on L. variegatus bioturbation activity. We observed sediment mixing and organism activity by time-lapse photography over 14 days. Then, we analyzed the images to characterize the fluorescent particle concentration as a function of sediment depth and time. Results reveal that sediment mixing caused by L. variegatus is subdiffusive in time and superdiffusive in space. These results suggest that anomalous sediment mixing is probably a ubiquitous process, as this behavior has only been observed previously in marine sediments. Also, the experiments indicate that bioturbation and sediment mixing decreased in the presence of higher metals concentrations in sediments. This process is expected to decrease efflux of metals from highly contaminated sediments by reducing biological activity.

Contemporary suspended sediment yield of a partly glaciated catchment, Riffler Bach (Tyrol, Austria)

NASA Astrophysics Data System (ADS)

Weber, Martin; Baewert, Henning; Morche, David

2015-04-01

Due to glacier retreat since the LIA (Little Ice Age) proglacial areas in high mountain landscapes are growing. These systems are characterized by a high geomorphological activity, especially in the fluvial subsystem. Despite the long tradition of geomorphological research in the European Alps there is a still a lack of understanding in the interactions between hydrology, sediment sources, sediments sinks and suspended sediment transport. As emphasized by ORWIN ET AL. (2010) those problems can be solved by gathering data in a higher frequency and/or in a higher spatial resolution or density - both leading to a big amount of data. In 2012 a gauging station was installed at the outlet of the partly glaciated catchment of the Riffler Bach (Kaunertal valley, Tyrol). During the ablation seasons in 2012 and 2013 water stage was logged automatically every 15 minutes. In both seasons discharge was measured at different water levels to calculate a stage-discharge relation. Additionally, water samples were taken by an automatic water sampler. Within 16 sampling cycles with sampling frequencies ranging from 1 to 24 hours 389 water samples have been collected. The samples were filtered to calculate the suspended sediment concentration (SSC) of each sample. Furthermore, the climate station Weißsee provided meteorological data at a 15 minute interval. Due to the high variability in suspended sediment transport in proglacial rivers it is impossible to compute a robust annual Q-SSC-relation. Hence, two other approaches were used to calculate the suspended sediment load (SSL) and the suspended sediment yield (SSY): A) Q-SSC-relations for every single sampling cycle (e.g. GEILHAUSEN ET AL. 2013) B) Q-SSC-relations based on classification of dominant runoff-generating processes (e.g. ORWIN AND SMART 2004). The first approach uses commonly operated analysis methods that are well understood. While the hydro-climatic approach is more feasible to explain discharge generation and to locate sediment sources both approaches underline the fact that SSC does not always depends on discharge but also on sediment availability. The comparison of both approaches shows that in well investigated areas the results are strongly determined by the choice of the analysis method. References Geilhausen, M., Morche, D., Otto, J.-C. and Schrott, L. (2013): Sediment discharge from the proglacial zone of a retreating Alpine glacier. Z Geomorphol Supplementary Issue 57 (2), 29-53. DOI: 10.1127/0372-8854/2012/S-00122 Orwin, J., Lamoureux, S.F., Warburton, J. and Beylich, A., (2010): A framework for characterizing fluvial sediment fluxes from source to sink in cold environments. Geogr. Ann. 92 A (2): 155-176. Orwin, J.F. and Smart, C.C. (2004): Short-term spatial and temporal patterns of suspended sediment transfer in proglacial channels, Small River Glacier, Canada. Hydrol. Process. 18, 1521-1542.

Magma-sediment interactions in the Limagne trench (Massif Central, France): distinction between phreatomagmatic and stricto-sensu peperitic processes

NASA Astrophysics Data System (ADS)

Leibrandt, Sebastien; Bénard, Antoine; Brigaud, Benjamin

2013-04-01

Magma-sediment interactions provide important information to reconstruct paleo-eruption dynamics in hydromagmatic environments. The lithofacies resulting from these interactions are usually named "peperite" as first described on rocks from the Limagne area (Massif Central, France). Nevertheless, it is nowadays admitted that both fluidal and blocky peperite formation refers to mostly non-explosive, hydrodynamic disintegration of magma intruding and mingling with unconsolidated wet sediments (e.g. Skilling et al., 2002). Here we observe magma-limestones interactions (i.e. explosive and non-explosive) in phreatomagmatic vent-filling deposits, from outcrop scale to thin-section observations, with polarized, electronic and cathodoluminescence microscopy. Our field study is based on the comparison of selected localities from the Limagne trench that are mapped as peperites but which apparently only record phreatomagmatic processes leading to the deposit of sediment-rich maar diatreme material. Microscopic characterization mainly focuses on juvenile clasts and host carbonate sediment textural relationships, when mixed together and dispersed in the maar diatreme material. We deduce the mechanisms and timing of interaction of several generations of magmatic clasts with host pristine carbonate sediments or pre-existing volcaniclastic breccia. The extent of mixing and dispersion of the magmatic clasts is assessed in relation with the emplacement dynamics, magmatic cooling rates and host sediment properties. In this regard, cathodoluminescence microscopy allows us to deduce the properties of sediment before, during and after interaction, which also helps to reconstruct the paleo-environmental frame. As a first outcome of this study, we distinguish (1) early syn-eruptive fragmented material during phreatomagmatic magma-sediment interaction from (2) secondary, non-explosive, magmatic intrusions in poorly consolidated and water-saturated vent-filling deposits. This second process can solely give birth to the stricto-sensu fluidal to blocky peperite microtexture, which we clearly distinguish for the first time in the Limagne area. A second outcome emerges thanks to the several approaches we use for microscopic characterization, which possibly reveal high-grade, non-explosive mingling of liquefied sediment with magma at the sub-millimetre scale. These observations provide new insights into peperite formation processes in carbonate sediments, when both considering experiments (e.g. Zimanowski and Büttner, 2002) and worldwide field observations in contrasting environments (e.g. McClintock & White, 2002). McClintock, M.K., White, J.D.L., 2002. Granulation of weak rock as a precursor to peperite formation: coal peperite, Coombs Hill, Antartica. Journal of Volcanology and Geothermal Research, 114, 205-217. Skilling, I.P., White, J.D.L., McPhie, J., 2002. Peperite: a review of magma-sediment mingling. Journal of Volcanology and Geothermal Research, 114, 1-17. Zimanowski, B., Büttner, R., 2002. Dynamic mingling of magma and liquefied sediments. Journal of Volcanology and Geothermal Research, 114, 37-44.

Stress history and geotechnical properties of sediment from the Cape Fear Diapir, Blake Ridge Diapir, and Blake Ridge

USGS Publications Warehouse

Winters, W.J.

2000-01-01

Geotechnical properties of sediment from Ocean Drilling Program Leg 164 are presented as: (1) normalized shipboard strength ratios from the Cape Fear Diapir, the Blake Ridge Diapir, and the Blake Ridge; and (2) Atterberg limit, vane shear strength, pocket-penetrometer strength, and constant-rate-of-strain consolidation results from Hole 995A, located on the Blake Ridge. This study was conducted to understand the stress history in a region characterized by high sedimentation rates and the presence of gas hydrates. Collectively, the results indicate that sediment from the Blake Ridge exhibits significant underconsolidated behavior, except near the seafloor. At least 10 m of additional overburden was removed by erosion or mass wasting at Hole 993A on the Cape Fear Diapir, compared to nearby sites.

Reductive reactivity of iron(III) oxides in the east china sea sediments: characterization by selective extraction and kinetic dissolution.

PubMed

Chen, Liang-Jin; Zhu, Mao-Xu; Yang, Gui-Peng; Huang, Xiang-Li

2013-01-01

Reactive Fe(III) oxides in gravity-core sediments collected from the East China Sea inner shelf were quantified by using three selective extractions (acidic hydroxylamine, acidic oxalate, bicarbonate-citrate buffered sodium dithionite). Also the reactivity of Fe(III) oxides in the sediments was characterized by kinetic dissolution using ascorbic acid as reductant at pH 3.0 and 7.5 in combination with the reactive continuum model. Three parameters derived from the kinetic method: m 0 (theoretical initial amount of ascorbate-reducible Fe(III) oxides), k' (rate constant) and γ (heterogeneity of reactivity), enable a quantitative characterization of Fe(III) oxide reactivity in a standardized way. Amorphous Fe(III) oxides quantified by acidic hydroxylamine extraction were quickly consumed in the uppermost layer during early diagenesis but were not depleted over the upper 100 cm depth. The total amounts of amorphous and poorly crystalline Fe(III) oxides are highly available for efficient buffering of dissolved sulfide. As indicated by the m 0, k' and γ, the surface sediments always have the maximum content, reactivity and heterogeneity of reactive Fe(III) oxides, while the three parameters simultaneously downcore decrease, much more quickly in the upper layer than at depth. Albeit being within a small range (within one order of magnitude) of the initial rates among sediments at different depths, incongruent dissolution could result in huge discrepancies of the later dissolution rates due to differentiating heterogeneity, which cannot be revealed by selective extraction. A strong linear correlation of the m 0 at pH 3.0 with the dithionite-extractable Fe(III) suggests that the m 0 may represent Fe(III) oxide assemblages spanning amorphous and crystalline Fe(III) oxides. Maximum microbially available Fe(III) predicted by the m 0 at pH 7.5 may include both amorphous and a fraction of other less reactive Fe(III) phases.

Reductive Reactivity of Iron(III) Oxides in the East China Sea Sediments: Characterization by Selective Extraction and Kinetic Dissolution

PubMed Central

Chen, Liang-Jin; Zhu, Mao-Xu; Yang, Gui-Peng; Huang, Xiang-Li

2013-01-01

Reactive Fe(III) oxides in gravity-core sediments collected from the East China Sea inner shelf were quantified by using three selective extractions (acidic hydroxylamine, acidic oxalate, bicarbonate-citrate buffered sodium dithionite). Also the reactivity of Fe(III) oxides in the sediments was characterized by kinetic dissolution using ascorbic acid as reductant at pH 3.0 and 7.5 in combination with the reactive continuum model. Three parameters derived from the kinetic method: m 0 (theoretical initial amount of ascorbate-reducible Fe(III) oxides), k′ (rate constant) and γ (heterogeneity of reactivity), enable a quantitative characterization of Fe(III) oxide reactivity in a standardized way. Amorphous Fe(III) oxides quantified by acidic hydroxylamine extraction were quickly consumed in the uppermost layer during early diagenesis but were not depleted over the upper 100 cm depth. The total amounts of amorphous and poorly crystalline Fe(III) oxides are highly available for efficient buffering of dissolved sulfide. As indicated by the m 0, k′ and γ, the surface sediments always have the maximum content, reactivity and heterogeneity of reactive Fe(III) oxides, while the three parameters simultaneously downcore decrease, much more quickly in the upper layer than at depth. Albeit being within a small range (within one order of magnitude) of the initial rates among sediments at different depths, incongruent dissolution could result in huge discrepancies of the later dissolution rates due to differentiating heterogeneity, which cannot be revealed by selective extraction. A strong linear correlation of the m 0 at pH 3.0 with the dithionite-extractable Fe(III) suggests that the m 0 may represent Fe(III) oxide assemblages spanning amorphous and crystalline Fe(III) oxides. Maximum microbially available Fe(III) predicted by the m 0 at pH 7.5 may include both amorphous and a fraction of other less reactive Fe(III) phases. PMID:24260377

Particulate export and lateral advection in the Antarctic Polar Front (Southern Pacific Ocean): One-year mooring deployment

NASA Astrophysics Data System (ADS)

Tesi, T.; Langone, L.; Ravaioli., M.; Giglio, F.; Capotondi, L.

2012-12-01

An instrumented mooring line with sediment traps, current meters and recorders of temperature and conductivity was deployed just south of the Antarctic Polar Front (63° 26‧ S, 178° 03‧E; water depth 4400 m) from January 9th 1999 to January 10th 2000. Sediment traps at 900 and 3700 m had a single large cup to collect particulate material throughout the 1-year study whereas time-series sediment traps were used to characterize the temporal variability at 1300 and 2400 m. Samples were characterized via several parameters including total mass flux, elemental composition (organic carbon, total nitrogen, biogenic silica, and calcium carbonate), concentration of metals (aluminum, iron, barium, and manganese), 210Pb activity, and foraminifera identification. High vertical fluxes of biogenic particles were observed in both summer 1999 and 2000 as a result of seasonal algal blooms associated with sea ice retreat and water column stratification. During autumn and winter, several high energy events occurred and resulted in advecting resuspended biogenic particles from flat-topped summits of the Pacific Antarctic Ridge. Whereas the distance between seabed and uppermost sediment traps was sufficient to avoid lateral advection processes, resuspension was significant in the lowermost sediment traps accounting for ~ 60 and ~ 90% of the material caught at 2400 and 3700 m, respectively. Although resuspended material showed an elemental composition relatively similar to vertical summer fluxes, samples collected during high energy events contained benthic foraminifera and exhibited significantly higher 210Pb activity indicating a longer residence time in the water column. In addition, during quiescent periods characterized by low mass fluxes, the content of lithogenic particles increased at the expense of phytodetritus indicating the influence of material advected through the benthic nepheloid layer. Organic matter content was particularly high during these periods and showed statistically significant linear correlations with metals suggesting adsorption of organic coatings onto the mineral surface of lithogenic particles.

Transitional Benthic Boundary Layers and their Influence on Nutrient Flux in Tidal Estuaries

NASA Astrophysics Data System (ADS)

Koetje, K. M.; Foster, D. L.; Lippmann, T. C.; Kalnejais, L. H.

2016-12-01

Quantifying the coupled physical and geochemical processes in the fluid-sediment interface is critical to managing coastal resources. This is of particular importance during times of enhanced hydrodynamic forcing where extreme tide or wind events can have a significant impact on water quality. A combination of field and laboratory experiments were used to examine the relationship between large-scale fluid shear stresses and geochemical fluxes at the fluid-sediment interface in the Great Bay Estuary, New Hampshire. Sediment geochemical measurements paired with flow field observations along estuary-wide transects over several tidal cycles provide nutrient load estimates that can be scaled to represent the whole Bay. Three-dimensional flow field measurements collected using a maneuverable personal watercraft were used to determine the spatial and temporal variability of the shear stress throughout the Bay. High-resolution bottom boundary layer dynamics were observed using a suite of acoustic Doppler current profilers (ADCP) in order to improve the accuracy of diffusive flux estimates by directly measuring the thickness of the benthic boundary layer. Over the 2.5 m tidal range and at water depths ranging from 0.3 m to 1.5 m at mean lower low water, peak mean flows ranged from 0.2 m/s to 1 m/s at the sampling sites. The dominant contribution of hydrodynamic forcing to the Bay is due to tidal flows, which are largely unidirectional during flood tide. Sediment grain size analysis characterized the bed at sampling sites as fine-grained sandy mud (d50 = 47 μm). Sampling during typical tidal flow conditions, a smooth turbulent flow field was observed and the threshold of motion was not exceeded. Along with sediment characterization, porosity profiles and erosion chamber experiments were used to characterize nutrient release. This host of data provides shear stress estimates that can constrain nutrient loads under variable hydrodynamic conditions.

High-resolution seismic characterization of the gas and gas hydrate system at Green Canyon 955, Gulf of Mexico, USA

USGS Publications Warehouse

Haines, Seth S.; Hart, Patrick E.; Collett, Timothy S.; Shedd, William; Frye, Matthew; Weimer, Paul; Boswell, Ray

2017-01-01

The Pliocene and Pleistocene sediments at lease block Green Canyon 955 (GC955) in the Gulf of Mexico include sand-rich strata with high saturations of gas hydrate; these gas hydrate accumulations and the associated geology have been characterized over the past decade using conventional industry three-dimensional (3D) seismic data and dedicated logging-while-drilling (LWD) borehole data. To improve structural and stratigraphic characterization and to address questions of gas flow and reservoir properties, in 2013 the U.S. Geological Survey acquired high-resolution two-dimensional (2D) seismic data at GC955. Combined analysis of all available data improves our understanding of the geological evolution of the study area, which includes basin-scale migration of the Mississippi River sediment influx as well as local-scale shifting of sedimentary channels at GC955 in response to salt-driven uplift, structural deformation associated with the salt uplift, and upward gas migration from deeper sediments that charges the main gas hydrate reservoir and shallower strata. The 2D data confirm that the sand-rich reservoir is composed principally of sediments deposited in a proximal levee setting and that episodes of channel scour, interspersed with levee deposition, have resulted in an assemblage of many individual proximal levee deposit “pods” each with horizontal extent up to several hundred meters. Joint analysis of the 2D and 3D data reveals new detail of a complex fault network that controls the fluid-flow system; large east-west trending normal faults allow fluid flow through the reservoir-sealing fine-grained unit, and smaller north-south oriented faults provide focused fluid-flow pathways (chimneys) through the shallower sediments. This system has enabled the flow of gas from the main reservoir to the seafloor throughout the recent history at GC955, and its intricacies help explain the distributed occurrences of gas hydrate in the intervening strata.

Using structural equation modeling to investigate relationships among ecological variables

USGS Publications Warehouse

Malaeb, Z.A.; Kevin, Summers J.; Pugesek, B.H.

2000-01-01

Structural equation modeling is an advanced multivariate statistical process with which a researcher can construct theoretical concepts, test their measurement reliability, hypothesize and test a theory about their relationships, take into account measurement errors, and consider both direct and indirect effects of variables on one another. Latent variables are theoretical concepts that unite phenomena under a single term, e.g., ecosystem health, environmental condition, and pollution (Bollen, 1989). Latent variables are not measured directly but can be expressed in terms of one or more directly measurable variables called indicators. For some researchers, defining, constructing, and examining the validity of latent variables may be the end task of itself. For others, testing hypothesized relationships of latent variables may be of interest. We analyzed the correlation matrix of eleven environmental variables from the U.S. Environmental Protection Agency's (USEPA) Environmental Monitoring and Assessment Program for Estuaries (EMAP-E) using methods of structural equation modeling. We hypothesized and tested a conceptual model to characterize the interdependencies between four latent variables-sediment contamination, natural variability, biodiversity, and growth potential. In particular, we were interested in measuring the direct, indirect, and total effects of sediment contamination and natural variability on biodiversity and growth potential. The model fit the data well and accounted for 81% of the variability in biodiversity and 69% of the variability in growth potential. It revealed a positive total effect of natural variability on growth potential that otherwise would have been judged negative had we not considered indirect effects. That is, natural variability had a negative direct effect on growth potential of magnitude -0.3251 and a positive indirect effect mediated through biodiversity of magnitude 0.4509, yielding a net positive total effect of 0.1258. Natural variability had a positive direct effect on biodiversity of magnitude 0.5347 and a negative indirect effect mediated through growth potential of magnitude -0.1105 yielding a positive total effects of magnitude 0.4242. Sediment contamination had a negative direct effect on biodiversity of magnitude -0.1956 and a negative indirect effect on growth potential via biodiversity of magnitude -0.067. Biodiversity had a positive effect on growth potential of magnitude 0.8432, and growth potential had a positive effect on biodiversity of magnitude 0.3398. The correlation between biodiversity and growth potential was estimated at 0.7658 and that between sediment contamination and natural variability at -0.3769.

Designing and Testing of Self-Cleaning Recirculating Zebrafish Tanks.

PubMed

Nema, Shubham; Bhargava, Yogesh

2016-08-01

Maintenance of large number of zebrafish in captive conditions is a daunting task. This can be eased by the use of recirculating racks with self-cleaning zebrafish tanks. Commercially available systems are costly, and compatibility of intercompany products has never been investigated. Although various cost-effective designs and methods of construction of custom-made recirculating zebrafish racks are available in literature, the design of self-cleaning zebrafish tanks is still not available. In this study, we report the design and method of construction of the self-cleaning unit, which can be fitted in any zebrafish tank. We validated the design by investigating sediment cleaning process in rectangular and cylindrical tank geometries using time lapse imaging. Our results suggest that for both tank geometries, the tanks fitted with self-cleaning unit provided superior sediment cleaning than the tanks fitted with overflow-drain unit. Although the self-cleaning unit could clean the sediment completely from both geometries over prolonged period, the cleaning of sediments was faster in the cylindrical tank than the rectangular tank. In conclusion, cost and efforts of zebrafish maintenance could be significantly reduced through the installation of our self-cleaning unit in any custom-made zebrafish tank.

Recent carbonate sedimentation on Balearic platform: model for temperate-climate carbonate shelves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fornos, J.; Rodriguez-Perea, A.; Massuti, C.

Existing models for carbonate sedimentation on continental platforms are derived from the study of modern carbonate platforms in tropical climates. The Balearic platform in the western Mediterranean provides a new model for carbonate sedimentation in a temperature, semiarid climate. On most of the continental shelf around the Balearic Islands, modern sediments are exclusively bioclastic carbonates. Shoreline carbonate sediments are bioclastic sands and muds accumulating in beach-dune systems without significant tidal influence (there are no astronomical tides in the western Mediterranean ). From the upper shoreface to 35 m deep, the sandy bottom is extensively colonized by sea grass (Posidonia oceanica),more » the rhizomes and roots of which form a rigid entrapment that retains the sediment derived from calcareous organisms living within the sea grass and from calcareous epiphytes living on the stems and leaves. Archeological dating establishes a rate of vertical accretion in this zone of 10/sup 3/ Bubnoff units (1 Bubnoff unit = 1 mm/1000 years). Between depths of 40 and 60 m, carbonate sands are composed predominantly or red-algal fragments. Intensely bioturbated wave ripples occur in environments dominated by laminar red algae (Lithothamnium and Phymatolithon). Below depths of 60 m, coarse sediment produced by rhodolitic and ramose red algae is deposited in areas of tens to hundreds of meters in size. Biogenic buildups up to 2 m high occur in sandy areas as well as in deeper muddy areas. At the same depth in open-platform zones, the bottom topography is characterized by large hummocks several hundred meters across. From the horizontal distribution of facies, it is possible to construct the probable vertical sequence of lithofacies which would characterize carbonates accumulating on a temperate-climate carbonate shelf. Many of these lithofacies are recognized in upper Miocene limestones on the Balearic Islands.« less

Characterization of bottom sediments in the Río de la Plata estuary

NASA Astrophysics Data System (ADS)

Simionato, Claudia G.; Moreira, Diego

2016-04-01

Bottom sediments and surface water samples were collected in the intermediate and outer Río de la Plata Estuary during 2009-2010, in six repeated cruises, with 26 stations each. Samples were processed for grain size using a laser particle size analyzer, and water and organic matter contents. The aim of this work is to analyze this data set to provide a comprehensive and objective characterization of the bottom sediments distribution, to study their composition and to progress in the construction of a conceptual model of the involved physical mechanisms. Principal Components Analysis is applied to the bottom sediments size histograms to investigate the spatial patterns. Variations in grain-size parameters contain information on possible sediment transport patterns, which were analyzed by means of trend vectors. Sediments show a gradational arrangement of textures, sand dominant at the head, silt in the intermediate estuary and clayey silt and clay at its mouth; textures become progressively more poorly sorted offshore, and the water and organic matter contents increase. And seem to be strongly related to the geometry and the hydrodynamics. Along the Northern coast of the intermediate estuary, well sorted medium and fine silt predominates, whereas in the Southern coast, coarser and less sorted silt prevails, due to differences in tidal currents and/or in water pathways. Around Barra del Indio, clay prevails over silt and sand, and the water and organic matter contents reach a maximum, probably due flocculation, and the reduction of the currents. Immediately seawards the salt wedge, net transport reverses its direction and well sorted coarser sand from the adjacent shelf dominates. Relict sediment is observed around the Santa Lucía River, consisting of poorly sorted fine silt and clay. The inferred net transport suggests convergence at the Barra del Indio shoal, which is consistent with the constant growing of the banks.

Integrated Forensics Approach to Fingerprint PCB Sources in Sediments using Rapid Sediment Characterization (RSC) and Advanced Chemical Fingerprinting (ACF). (Environmental Security Technology Certification Program)

DTIC Science & Technology

2012-06-01

23 5 TEST DESIGN ... research project, ORD will continue to focus on only the PCB inventory in the test zone and selected areas of the river as further defined in subsequent...1,000 500 50 25 5 TEST DESIGN This section of the report provides the detailed description of the experimental design and testing

Dust emission from wet and dry playas in the Mojave Desert, USA

USGS Publications Warehouse

Reynolds, R.L.; Yount, J.C.; Reheis, M.; Goldstein, H.; Chavez, P.; Fulton, R.; Whitney, J.; Fuller, C.; Forester, R.M.

2007-01-01

The interactions between playa hydrology and playa-surface sediments are important factors that control the type and amount of dust emitted from playas as a result of wind erosion. The production of evaporite minerals during evaporative loss of near-surface ground water results in both the creation and maintenance of several centimeters or more of loose sediment on and near the surfaces of wet playas. Observations that characterize the texture, mineralogic composition and hardness of playa surfaces at Franklin Lake, Soda Lake and West Cronese Lake playas in the Mojave Desert (California), along with imaging of dust emission using automated digital photography, indicate that these kinds of surface sediment are highly susceptible to dust emission. The surfaces of wet playas are dynamic - surface texture and sediment availability to wind erosion change rapidly, primarily in response to fluctuations in water-table depth, rainfall and rates of evaporation. In contrast, dry playas are characterized by ground water at depth. Consequently, dry playas commonly have hard surfaces that produce little or no dust if undisturbed except for transient silt and clay deposited on surfaces by wind and water. Although not the dominant type of global dust, salt-rich dusts from wet playas may be important with respect to radiative properties of dust plumes, atmospheric chemistry, windborne nutrients and human health.

[Characterization of microbial activities in marine mudflat sediment using FDA hydrolase analysis].

PubMed

Liu, Ye; Zou, Li; Liu, Lu; Gao, Dong-Mei

2013-10-01

A method based on fluorescence spectrometry was developed to detect the microbial activities in marine mudflat sediment, where is characterized by high salinity, complex organic compounds and low microbial biomass. This paper optimized the sample extracts, the detection equipment for reaction products, the pretreatment methods, and the experimental conditions. The optimal procedure is described as following. Fresh sediment was first extracted with sterilized and aged seawater, followed by the addition of Tween-80 solution, then uniformly dispersed by thorough oscillating, and kept steady for precipitation. After filtration through a sterilized membrane (1. 2 microm, sterilized in boiling water repeatedly) , the supernatant was supplemented with an appropriate amount of FDA solution and allowed to react in dark for 180 min at temperature ranged 25-30 degrees C . The reaction was terminated by the addition of acetone, and the fluorescence intensity of the reaction mixture was measured within 25 min using a molecular fluorescence photometer at an excitation wavelength of 488 nm and an emission wavelength of 530 nm, and the detection range of this method (dry weight) was 3.0 x10(3)-1. 1 x 10(5) ind.g-1. The microbial activity was reported as fluorescence content in per unit sediment mass (microg.g-1, dry weight).

Mechanical properties of simulated Mars materials: gypsum-rich sandstones and lapilli tuff

USGS Publications Warehouse

Morrow, Carolyn; Lockner, David; Okubo, Chris

2013-01-01

Observations by the Mars Exploration Rover (MER) Opportunity, and other recent studies on diagenesis in the extensive equatorial layered deposits on Mars, suggest that the likely lithologies of these deposits are gypsum-rich sandstones and tuffaceous sediments (for example, Murchie and others, 2009; Squyres and others, 2012; Zimbelman and Scheidt, 2012). Of particular interest is how the diagenesis history of these sediments (degree of cementation and composition) influences the strength and brittle behavior of the material. For instance, fractures are more common in lower porosity materials under strain, whereas deformation bands, characterized by distributed strain throughout a broader discontinuity in a material, are common in higher porosity sedimentary materials. Such discontinuities can either enhance or restrict fluid flow; hence, failure mode plays an important role in determining the mechanics of fluid migration through sediments (Antonellini and Aydin, 1994; 1995; Taylor and Pollard, 2000; Ogilvie and Glover, 2001). As part of a larger study to characterize processes of fault-controlled fluid flow in volcaniclastic and gypsum-rich sediments on Mars, we have completed a series of laboratory experiments to focus on how gypsum clast content and degree of authigenic cementation affects the strength behavior of simulated Mars rocks. Both axial deformation and hydrostatic pressure tests were done at room temperature under dry conditions.

Neutral monosaccharides from a hypersaline tropical environment: Applications to the characterization of modern and ancient ecosystems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moers, M.E.C.; Larter, S.R.

1993-07-01

Surficial and buried sediment samples from a hypersaline lagoon-sabkha system (Abu Dhabi, United Arab Emirates) were analyzed for carbohydrates (as neutral monosaccharides) to distinguish and characterize various types of recent and ancient tropical ecosystems on a molecular level. The samples consisted of surficial and buried microbial mats, lagoonal sediments containing seagrass (Halodule uninervis), and mangrove (Avicennia marine) paleosoils and handpicked mangrove leaves, ranging in age from contemporary to ca. 6000 yr BP. Analysis of quantitative neutral monosaccharide data by multivariate techniques shows that various groups can be distinguished: intact vascular plant material (mangrove leaf) contains high amounts of arabinose andmore » glucose and hardly any partially methylated monosaccharides, whereas microbial mats in general and lagoonal seagrass sediments show high contributions of fucose, ribose, mannose, galactose, and partially methylated monosaccharides. Moreover, surficial microbial mats consisting of filamentous cyanobacteria (Microcoleus chtonoplastes, Lyngbya aestuarii) can be distinguished from other mats and sediments containing coccoid cyanobacteria (Entophysalis major) and/or fermenting, sulphate reducing, and methanogenic bacteria on the basis of high contributions of specific groups of partially methylated monosaccharides and other [open quotes]minor[close quotes] saccharides. The neutral monosaccharides present in mangrove paleosoils are for a substantial part derived from microorganisms. 22 refs., 4 figs., 4 tabs.« less

Geochemistry of loess-paleosol sediments of Kashmir Valley, India: Provenance and weathering

NASA Astrophysics Data System (ADS)

Ahmad, Ishtiaq; Chandra, Rakesh

2013-04-01

Middle to Late Pleistocene loess-paleosol sediments of Kashmir Valley, India, were analyzed for major, trace and REE elements in order to determine their chemical composition, provenance and intensity of palaeo-weathering of the source rocks. These sediments are generally enriched with Fe2O3, MgO, MnO, TiO2, Y, Ni, Cu, Zn, Th, U, Sc, V and Co while contents of SiO2, K2O, Na2O, P2O5, Sr, Nb and Hf are lower than the UCC. Chondrite normalized REE patterns are characterized by moderate enrichment of LREEs, relatively flat HREE pattern (GdCN/YbCN = 1.93-2.31) and lack of prominent negative Eu anomaly (Eu/Eu* = 0.73-1.01, average = 0.81). PAAS normalized REE are characterized by slightly higher LREE, depleted HREE and positive Eu anomaly. Various provenance discrimination diagrams reveal that the Kashmir Loess-Paleosol sediments are derived from the mixed source rocks suggesting large provenance with variable geological settings, which apparently have undergone weak to moderate recycling processes. Weathering indices such as CIA, CIW and PIA values (71.87, 83.83 and 80.57 respectively) and A-CN-K diagram imply weak to moderate weathering of the source material.

Sequence stratigraphy and hydrocarbon potential of the Phu Khanh Basin offshore central Vietnam, South China Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, G.H.; Watkins, J.S.

1996-12-31

The Phu Khanh Basin offshore central Vietnam is one of the few untested basins on the Vietnam margin of the South China Sea. Analysis of over 1,600 km of multi-channel seismic reflection data indicates that the Phu Khanh Basin follows a typical rift-margin order: faulted basement, synrift sedimentation, a breakup unconformity, and postrift sedimentation. Postrift sedimentation consists of a transgressive phase characterized by ramp-like depositional geometries followed by a regressive phase characterized by prograding sequences. An early middle Miocene unconformity separates these two phases. During the transgressive phase rising sea level provided favorable conditions for carbonate buildup development. The regressivemore » interval contains a number of third-order depositional sequences composed of seismically resolvable lowstand, highstand, and rarely, transgressive systems tracts. Lacustrine sediments deposited in graben and half-graben lakes during the rifting stage are probably the principal source rocks. Fractured and/or weathered basement, carbonate complexes, basinfloor fans, and shallows water sands may have good reservoir quality. Potential traps include basement hills, carbonate complexes, fault taps, and stratigraphic traps within lowstand systems tracts. Hydrocarbon indicators such as flat spots, bright spots, gas chimneys with gas mounds on the seafloor occur at a number of locations.« less

Sequence stratigraphy and hydrocarbon potential of the Phu Khanh Basin offshore central Vietnam, South China Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, G.H.; Watkins, J.S.

1996-01-01

The Phu Khanh Basin offshore central Vietnam is one of the few untested basins on the Vietnam margin of the South China Sea. Analysis of over 1,600 km of multi-channel seismic reflection data indicates that the Phu Khanh Basin follows a typical rift-margin order: faulted basement, synrift sedimentation, a breakup unconformity, and postrift sedimentation. Postrift sedimentation consists of a transgressive phase characterized by ramp-like depositional geometries followed by a regressive phase characterized by prograding sequences. An early middle Miocene unconformity separates these two phases. During the transgressive phase rising sea level provided favorable conditions for carbonate buildup development. The regressivemore » interval contains a number of third-order depositional sequences composed of seismically resolvable lowstand, highstand, and rarely, transgressive systems tracts. Lacustrine sediments deposited in graben and half-graben lakes during the rifting stage are probably the principal source rocks. Fractured and/or weathered basement, carbonate complexes, basinfloor fans, and shallows water sands may have good reservoir quality. Potential traps include basement hills, carbonate complexes, fault taps, and stratigraphic traps within lowstand systems tracts. Hydrocarbon indicators such as flat spots, bright spots, gas chimneys with gas mounds on the seafloor occur at a number of locations.« less

Comparative Evaluation of U.S. Brand and Generic Intravenous Sodium Ferric Gluconate Complex in Sucrose Injection: Physicochemical Characterization

PubMed Central

Sun, Dajun; Rouse, Rodney; Patel, Vikram; Wu, Yong; Zheng, Jiwen; Karmakar, Alokita; Patri, Anil K.; Keire, David; Ma, Jia; Jiang, Wenlei

2018-01-01

The objective of this study was to evaluate physicochemical equivalence between brand (i.e., Ferrlecit) and generic sodium ferric gluconate (SFG) in sucrose injection by conducting a series of comparative in vitro characterizations using advanced analytical techniques. The elemental iron and carbon content, thermal properties, viscosity, particle size, zeta potential, sedimentation coefficient, and molecular weight were determined. There was no noticeable difference between brand and generic SFG in sucrose injection for the above physical parameters evaluated, except for the sedimentation coefficient determined by sedimentation velocity analytical ultracentrifugation (SV-AUC) and molecular weight by asymmetric field flow fractionation-multi-angle light scattering (AFFF-MALS). In addition, brand and generic SFG complex products showed comparable molecular weight distributions when determined by gel permeation chromatography (GPC). The observed minor differences between brand and generic SFG, such as sedimentation coefficient, do not impact their biological activities in separate studies of in vitro cellular uptake and rat biodistribution. Coupled with the ongoing clinical study comparing the labile iron level in healthy volunteers, the FDA-funded post-market studies intended to illustrate comprehensive surveillance efforts ensuring safety and efficacy profiles of generic SFG complex in sucrose injection, and also to shed new light on the approval standards on generic parenteral iron colloidal products. PMID:29303999

Characterization of organic chemical contaminants in sediments from Jobos Bay, Puerto Rico.

PubMed

Pait, Anthony S; Whitall, David R; Dieppa, Angel; Newton, Sarah E; Brune, Lia; Caldow, Chris; Mason, Andrew L; Apeti, Dennis A; Christensen, John D

2012-08-01

Jobos Bay, located on the southeastern coast of Puerto Rico, contains a variety of habitats including mangroves, seagrass meadows, and coral reefs. The watershed surrounding the bay includes a number of towns, agricultural areas, and the Jobos Bay National Estuarine Research Reserve (NERR). Jobos Bay and the surrounding watershed are part of a Conservation Effects Assessment Project (CEAP), involving the Jobos Bay NERR, the US Department of Agriculture, and the National Oceanic and Atmospheric Administration (NOAA) to assess the benefits of agricultural best management practices (BMPs) on the terrestrial and marine environments. As part of the Jobos Bay CEAP, NOAA collected sediment samples in May 2008 to characterize over 130 organic chemical contaminants. This paper presents the results of the organic contaminant analysis. The organic contaminants detected in the sediments included polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls, and the pesticide DDT. PAHs at one site in the inner bay near a boat yard were significantly elevated; however, all organic contaminant classes measured were below NOAA sediment quality guidelines that would have indicated that impacts were likely. The results of this work provide an important baseline assessment of the marine environment that will assist in understanding the benefits of implementing BMPs on water quality in Jobos Bay.

Alkylphenols, polycyclic aromatic hydrocarbons, and organochlorines in sediment from Lake Shihwa, Korea: Instrumental and bioanalytical characterization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khim, J.S.; Villeneuve, D.L.; Kannan, K.

1999-11-01

Lake Shihwa is an artificial lake, located on the west coast of Korea, that has experienced environmental deterioration since 1994, when it was formed by construction of a sea dike. This study used instrumental analysis and in vitro bioassays to characterize organic contaminants in sediment collected from 11 stations on Lake Shihwa. Alkylphenol (AP) concentrations in Lake Shihwa sediment ranged from 20.2 to 1,820 ng/g nonylphenol and from 4.69 to 50.5 ng/g octylphenol, on a dry weight basis. Maximum concentrations of polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides, and polychlorinated biphenyls (PCBs) were 30.8, 2.26, and 12.3 ng/g (dry weight), respectively.more » Significant estrogenic activity was associated with fractions containing APs. Mass-balance analysis suggested that reported concentrations of APs account for less than 20% of the estrogenic activity observed. No significant dioxin like activity was associated with fractions containing classic aryl hydrocarbon receptor agonists, such as PCBs, but the mid-polarity fractions containing PAHs and most polar fractions yielded significant dioxin like activity. Overall, most of the in vitro bioassay responses appear to have been caused by unidentified and/or undetectable compounds associated with Lake Shihwa sediment.« less

Optical properties of fly ash. Volume 1, Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Self, S.A.

1994-12-01

Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executivemore » summary of the whole program followed by the dissertation of Ghosal. Volume 1 contains the dissertation of Ghosal which covers the characterization of fly ash and the measurements of the radiant properties of fly ash dispersions. A list of publications and conference presentations resulting from the work is also included.« less

Delineation, Characterization and Assessment of Gas-hydrates: Examples from Indian Offshore

NASA Astrophysics Data System (ADS)

Sain, K.

2017-12-01

Successful test productions in McKenzie delta, Alaska, Nankai Trough and more recently in South China Sea have provided great hopes for production of gas-hydrates in near future, and boosted national programs of many countries including India. It has been imperative to map the prospective zones of gas-hydrates and evaluate their resource potential. Hence, we have adopted a systematic strategy for the delineation, characterization and quantification of gas-hydrates based on seismic traveltime tomography, full-waveform inversion, impedance inversion, attributes computation and rock-physical modeling. The bathymetry, seafloor temperature, total organic carbon content, sediment-thickness, rate of sedimentation, geothermal gradient imply that shallow sediments of Indian deep water are good hosts for occurrences of gas-hydrates. From the analysis of multi-channel seismic (MCS) data, we have identified the Krishna-Godavari (KG), Mahanadi and Andaman basins as prospective for gas-hydrates, and their presence has been validated by drilling and coring of Indian Expeditions-01 and -02. The MCS data also shows BSR-like features in the Cauvery, Kerala-Konkan and Saurashtra basins indicating that gas-hydrates cannot be ruled out from these basins also. We shall present several approaches that have been applied to field seismic and well-log data for the detection, characterization and quantification of gas-hydrates along the Indian margin.

Sequestration of priority pollutant PAHs from sediment pore water employing semipermeable membrane devices.

PubMed

Williamson, Kelly S; Petty, Jimmie D; Huckins, James N; Lebo, Jon A; Kaiser, Edwin M

2002-11-01

Semipermeable membrane devices (SPMDs) were employed to sample sediment pore water in static exposure studies under controlled laboratory conditions using (control pond and formulated) sediments fortified with 15 priority pollutant polycyclic aromatic hydrocarbons (PPPAHs). The sediment fortification level of 750 ng/g was selected on the basis of what might be detected in a sediment sample from a contaminated area. The sampling interval consisted of 0, 4, 7, 14, and 28 days for each study. The analytical methodologies, as well as the extraction and sample cleanup procedures used in the isolation, characterization, and quantitation of 15 PPPAHs at different fortification levels in SPMDs, water, and sediment were reported previously (Williamson, M.S. Thesis, University of Missouri-Columbia, USA; Williamson et al., Chemosphere (This issue--PII: S0045-6535(02)00394-6)) and used for this project. Average (mean) extraction recoveries for each PPPAH congener in each matrix are reported and discussed. No procedural blank extracts (controls) were found to contain any PPPAH residues above the method quantitation limit, therefore, no matrix interferences were detected. The focus of this publication is to demonstrate the ability to sequester environmental contaminants, specifically PPPAHs, from sediment pore water using SPMDs and two different types of fortified sediment.

Temporal-spatial variation of bacterial diversity in estuary sediments in the south of Zhejiang Province, China.

PubMed

Lu, Xiao-Ming; Chen, Chang; Zheng, Tian-Ling; Chen, Jian-Jun

2016-03-01

The winter and summer microbial community structure in sediment samples obtained from the estuaries of the wastewater-polluted River Ou (DO and XO), River Feiyun (DF and XF), and River Ao (DA and XA) in the south of Zhejiang Province in China was determined using 454 pyrosequencing. Sediment samples (DD and XD) were also correspondingly collected near the shore far from the estuaries for comparison. For the above sediments, 294,870 effective sequences were obtained to do the bacterial diversity and abundance determination. In total, 1924, 1517, 2071, 1956, 1995, 1800, 2261, and 2097 operational taxonomic units were obtained at 3 % distance cutoff in the DO, XO, DF, XF, DA, XA, DD, and XD sediments, respectively. Bacterial phylotype richness in DD was higher than the other sediments, and XO had the least richness. The most dominant class in the DA, DD, DF, DO, and XA sediments is Gammaproteobacteria. Deltaproteobacteria is the most dominant one in XD, XO, and XF. Circa 14.4 % sequences in XD were found to be affiliated with the Flavobacteriales order. Characterization of the estuarine sediment bacterial communities indicated that chemical pollution has the potential to decrease the natural variability that exists among estuary ecosystems. However, chemical pollutants did not cause clear bio-homogenization in these estuaries.

Sequestration of priority pollutant PAHs from sediment pore water employing semipermeable membrane devices

USGS Publications Warehouse

Williamson, K.S.; Petty, J.D.; Huckins, J.N.; Lebo, J.A.; Kaiser, E.M.

2002-01-01

Semipermeable membrane devices (SPMDs) were employed to sample sediment pore water in static exposure studies under controlled laboratory conditions using (control pond and formulated) sediments fortified with 15 priority pollutant polycyclic aromatic hydrocarbons (PPPAHs). The sediment fortification level of 750 ng/g was selected on the basis of what might be detected in a sediment sample from a contaminated area. The sampling interval consisted of 0, 4, 7, 14, and 28 days for each study. The analytical methodologies, as well as the extraction and sample cleanup procedures used in the isolation, characterization, and quantitation of 15 PPPAHs at different fortification levels in SPMDs, water, and sediment were reported previously (Williamson, M.S. Thesis, University of Missouri - Columbia, USA; Williamson et al., Chemosphere (This issue - PII: S0045-6535(02)00394-6)) and used for this project. Average (mean) extraction recoveries for each PPPAH congener in each matrix are reported and discussed. No procedural blank extracts (controls) were found to contain any PPPAH residues above the method quantitation limit, therefore, no matrix interferences were detected. The focus of this publication is to demonstrate the ability to sequester environmental contaminants, specifically PPPAHs, from sediment pore water using SPMDs and two different types of fortified sediment.

In situ passive sampling of sediments in the Lower Duwamish Waterway Superfund site: Replicability, comparison with ex situ measurements, and use of data.

PubMed

Apell, Jennifer N; Gschwend, Philip M

2016-11-01

Superfund sites with sediments contaminated by hydrophobic organic compounds (HOCs) can be difficult to characterize because of the complex nature of sorption to sediments. Porewater concentrations, which are often used to model transport of HOCs from the sediment bed into overlying water, benthic organisms, and the larger food web, are traditionally estimated using sediment concentrations and sorption coefficients estimated using equilibrium partitioning (EqP) theory. However, researchers have begun using polymeric samplers to determine porewater concentrations since this method does not require knowledge of the sediment's sorption properties. In this work, polyethylene passive samplers were deployed into sediments in the field (in situ passive sampling) and mixed with sediments in the laboratory (ex situ active sampling) that were contaminated with polychlorinated biphenyls (PCBs). The results show that porewater concentrations based on in situ and ex situ sampling generally agreed within a factor of two, but in situ concentrations were consistently lower than ex situ porewater concentrations. Imprecision arising from in situ passive sampling procedures does not explain this bias suggesting that field processes like bioirrigation may cause the differences observed between in situ and ex situ polymeric samplers. Copyright © 2016 Elsevier Ltd. All rights reserved.

WAG 2 remedial investigation and site investigation site-specific work plan/health and safety checklist for the sediment transport modeling task

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holt, V.L.; Baron, L.A.

1994-05-01

This site-specific Work Plan/Health and Safety Checklist (WP/HSC) is a supplement to the general health and safety plan (HASP) for Waste Area Grouping (WAG) 2 remedial investigation and site investigation (WAG 2 RI&SI) activities [Health and Safety Plan for the Remedial Investigation and Site Investigation of Waste Area Grouping 2 at the Oak Ridge National Laboratory, Oak Ridge, Tennessee (ORNL/ER-169)] and provides specific details and requirements for the WAG 2 RI&SI Sediment Transport Modeling Task. This WP/HSC identifies specific site operations, site hazards, and any recommendations by Oak Ridge National Laboratory (ORNL) health and safety organizations [i.e., Industrial Hygiene (IH),more » Health Physics (HP), and/or Industrial Safety] that would contribute to the safe completion of the WAG 2 RI&SI. Together, the general HASP for the WAG 2 RI&SI (ORNL/ER-169) and the completed site-specific WP/HSC meet the health and safety planning requirements specified by 29 CFR 1910.120 and the ORNL Hazardous Waste Operations and Emergency Response (HAZWOPER) Program Manual. In addition to the health and safety information provided in the general HASP for the WAG 2 RI&SI, details concerning the site-specific task are elaborated in this site-specific WP/HSC, and both documents, as well as all pertinent procedures referenced therein, will be reviewed by all field personnel prior to beginning operations.« less

Effects of Emergent Vegetation on Sediment Dynamics within a Retreating Coastal Marshland

NASA Astrophysics Data System (ADS)

Stellern, C.; Grossman, E.; Fuller, R.; Wallin, D.; Linneman, S. R.

2015-12-01

Coastal emergent vegetation in estuaries physically interrupts flow within the water column, reduces wave energy and increases sediment deposition. Previous workers conclude that wave attenuation rates decrease exponentially with distance from the marsh edge and are dependent on site and species-specific plant characteristics (Yang et al., 2011). Sediment deposition may exhibit similar patterns; however, sediment, geomorphic and habitat models seldom integrate site-specific biophysical plant parameters into change analyses. We paired vegetation and sediment dynamic studies to: (1) characterize vegetation structure, (2) estimate sediment available for deposition, (3) estimate rate, distribution and composition of sediment deposits, (4) determine sediment accumulation on vegetation, (5) compare sediment deposition within dense tidal wetland relative to non-vegetated tidal flat. These studies integrate a variety of monitoring methods, including the use of sediment traps, turbidity sensors, side-on photographs of vegetation and remote sensing image analysis. We compared sedimentation data with vegetation characteristics and spatial distribution data to examine the relative role of vegetation morphologic traits (species, stem density, biomass, distribution, tidal channels, etc.) on sediment dynamics. Our study is focused on Port Susan Bay of Washington State; a protected delta that has experienced up to 1 kilometer of marsh retreat (loss) over the past fifty years. Preliminary results show that the highest winter deposition occurred in the high marsh/mid-marsh boundary, up to 300m inland of the marsh edge, where bulrush species are most dense. These results will inform restoration efforts aimed at reestablishing sediment supply to the retreating marshland. This research is necessary to understand the vulnerability and adaptability of coastal marshlands to climate change related stressors such as, increased water levels (sea-level rise) and wave energy.

Microbiome succession during ammonification in eelgrass bed sediments.

PubMed

Ettinger, Cassandra L; Williams, Susan L; Abbott, Jessica M; Stachowicz, John J; Eisen, Jonathan A

2017-01-01

Eelgrass ( Zostera marina ) is a marine angiosperm and foundation species that plays an important ecological role in primary production, food web support, and elemental cycling in coastal ecosystems. As with other plants, the microbial communities living in, on, and near eelgrass are thought to be intimately connected to the ecology and biology of eelgrass. Here we characterized the microbial communities in eelgrass sediments throughout an experiment to quantify the rate of ammonification, the first step in early remineralization of organic matter, also known as diagenesis, from plots at a field site in Bodega Bay, CA. Sediment was collected from 72 plots from a 15 month long field experiment in which eelgrass genotypic richness and relatedness were manipulated. In the laboratory, we placed sediment samples ( n  = 4 per plot) under a N 2 atmosphere, incubated them at in situ temperatures (15 °C) and sampled them initially and after 4, 7, 13, and 19 days to determine the ammonification rate. Comparative microbiome analysis using high throughput sequencing of 16S rRNA genes was performed on sediment samples taken initially and at seven, 13 and 19 days to characterize changes in the relative abundances of microbial taxa throughout ammonification. Within-sample diversity of the sediment microbial communities across all plots decreased after the initial timepoint using both richness based (observed number of OTUs, Chao1) and richness and evenness based diversity metrics (Shannon, Inverse Simpson). Additionally, microbial community composition changed across the different timepoints. Many of the observed changes in relative abundance of taxonomic groups between timepoints appeared driven by sulfur cycling with observed decreases in predicted sulfur reducers ( Desulfobacterales ) and corresponding increases in predicted sulfide oxidizers ( Thiotrichales ). None of these changes in composition or richness were associated with variation in ammonification rates. Our results showed that the microbiome of sediment from different plots followed similar successional patterns, which we infer to be due to changes related to sulfur metabolism. These large changes likely overwhelmed any potential changes in sediment microbiome related to ammonification rate. We found no relationship between eelgrass presence or genetic composition and the microbiome. This was likely due to our sampling of bulk sediments to measure ammonification rates rather than sampling microbes in sediment directly in contact with the plants and suggests that eelgrass influence on the sediment microbiome may be limited in spatial extent. More in-depth functional studies associated with eelgrass microbiome will be required in order to fully understand the implications of these microbial communities in broader host-plant and ecosystem functions (e.g., elemental cycling and eelgrass-microbe interactions).

Role of the bottom sediments immediately beneath the lake water-groundwater interface in the transport and removal of cyanobacteria, cyanophage, and dissolved organic carbon during natural lake-bank filtration at a kettle pond subject to harmful algal blooms

NASA Astrophysics Data System (ADS)

Harvey, R. W.; Metge, D. W.; LeBlanc, D. R.; Underwood, J. C.; Aiken, G.; McCobb, T. D.; Jasperse, J.

2015-12-01

Bank filtration has proven to be a sustainable, cost-effective method of removing cyanobacteria and their harmful toxins from surface water during filtration through bottom and aquifer sediments. The biologically active layer of sediments immediately beneath the sediment-water interface (colmation layer) is believed to be particularly important in this process. An in situ experiment was conducted that involved assessing the transport behaviors of bromide (conservative tracer), Synechococcus sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophages, 110 nm long), MS2 (coliphages, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The constituents were monitored as they advected through the colmation layer and underlying aquifer sediments at Ashumet Pond in Cape Cod, MA, a mesotrophic kettle pond that recharges a portion of a sole-source, drinking water aquifer. Because the pond DOC includes the various cyanotoxins produced during harmful algal bloom senescence, the DOC and aforementioned colloids were tracked concomitantly. The tracer test constituents were monitored as they advected across the pond water-groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-points samplers placed at ~30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ~42% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d-1). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by 3 orders of magnitude) at removing microspheres than was the underlying 30-cm-long segment of sediment. A follow-up study conducted the following year at the same location demonstrated that removal of the top 5 cm of sediment resulted in a six-fold decrease in the efficiency of the near-surface bottom sediments for filtering out Synechococcus, cyanophage, and well-characterized microspheres.

Bathymetric and sediment facies maps for China Bend and Marcus Flats, Franklin D. Roosevelt Lake, Washington, 2008 and 2009

USGS Publications Warehouse

Weakland, Rhonda J.; Fosness, Ryan L.; Williams, Marshall L.; Barton, Gary J.

2011-01-01

The U.S. Geological Survey (USGS) created bathymetric and sediment facies maps for portions of two reaches of Lake Roosevelt in support of an interdisciplinary study of white sturgeon (Acipenser transmontanus) and their habitat areas within Franklin D. Roosevelt Lake, Washington. In October 2008, scientists from the USGS used a boat-mounted multibeam echo sounder (MBES) to describe bathymetric data to characterize surface relief at China Bend and Marcus Flats, between Northport and Kettle Falls, Washington. In March 2009, an underwater video camera was used to view and record sediment facies that were then characterized by sediment type, grain size, and areas of sand deposition. Smelter slag has been identified as having the characteristics of sand-sized black particles; the two non-invasive surveys attempted to identify areas containing black-colored particulate matter that may be elements and minerals, organic material, or slag. The white sturgeon population in Lake Roosevelt is threatened by the failure of natural recruitment, resulting in a native population that consists primarily of aging fish and that is gradually declining as fish die and are not replaced by nonhatchery reared juvenile fish. These fish spawn and rear in the riverine and upper reservoir reaches where smelter slag is present in the sediment of the river lake bed. Effects of slag on the white sturgeon population in Lake Roosevelt are largely unknown. Two recent studies demonstrated that copper and other metals are mobilized from slag in aqueous environments with concentrations of copper and zinc in bed sediments reaching levels of 10,000 and 30,000 mg/kg due to the presence of smelter slag. Copper was found to be highly toxic to 30-day-old white sturgeon with 96-h LC50 concentrations ranging from 3 to 5 (u or mu)g copper per liter. Older juvenile and adult sturgeons commonly ingest substantial amounts of sediment while foraging. Future study efforts in Lake Roosevelt should include sampling of bottom material to confirm the presence or absence of slag material indicated on the map. In addition, follow-up acoustic work to determine stream velocities at varying discharges, in conjunction with sediment mapping, would be helpful to more accurately identify areas of scour and areas of sediment deposition where slag deposits may accumulate within the Marcus Flats and China Bend reaches. MBES mapping could also be used to determine changes in bed elevation and sedimentation in the study reaches and could help evaluate annual deposition and provide estimates on fine-sediment thickness.

Effects of farmhouse hotel and paper mill effluents on bacterial community structures in sediment and surface water of Nanxi River, China.

PubMed

Lu, Xiao-Ming; Lu, Peng-Zhen

2014-11-01

The pyrosequencing technique was used to evaluate bacterial community structures in sediment and surface water samples taken from Nanxi River receiving effluents from a paper mill and a farmhouse hotel, respectively. For each sample, 4,610 effective bacterial sequences were selected and used to do the analysis of diversity and abundance, respectively. Bacterial phylotype richness in the sediment sample without effluent input was higher than the other samples, and the surface water sample with addition of effluent from the paper mill contained the least richness. Effluents from both the paper mill and farmhouse hotel have a potential to reduce the bacterial diversity and abundance in the sediment and surface water, especially it is more significant in the sediment. The effect of the paper mill effluent on the sediment and surface water bacterial communities was more serious than that of the farmhouse hotel effluent. Characterization of microbial community structures in the sediment and surface water from two tributaries of the downstream river indicated that various effluents from the paper mill and farmhouse hotel have the similar potential to decrease the natural variability in riverine microbial ecosystems.

Dissolved oxygen transfer to sediments by sweep and eject motions in aquatic environments

USGS Publications Warehouse

O'Connor, B.L.; Hondzo, Miki

2008-01-01

Dissolved oxygen (DO) concentrations were quantified near the sediment-water interface to evaluate DO transfer to sediments in a laboratory recirculating flume and open channel under varying fluid-flow conditions. DO concentration fluctuations were observed within the diffusive sublayer, as defined by the time-averaged DO concentration gradient near the sediment-water interface. Evaluation of the DO concentration fluctuations along with detailed fluid-flow characterizations were used to quantify quasi-periodic sweep and eject motions (bursting events) near the sediments. Bursting events dominated the Reynolds shear stresses responsible for momentum and mass fluctuations near the sediment bed. Two independent methods for detecting bursting events using DO concentration and velocity data produced consistent results. The average time between bursting events was scaled with wall variables and was incorporated into a similarity model to describe the dimensionless mass transfer coefficient (Sherwood number, Sh) in terms of the Reynolds number, Re, and Schmidt number, Sc, which described transport in the flow. The scaling of bursting events was employed with the similarity model to quantify DO transfer to sediments and results showed a high degree of agreement with experimental data. ?? 2008, by the American Society of Limnology and Oceanography, Inc.

Suspended-sediment flux and retention in a backwater tidal slough complex near the landward boundary of an estuary

USGS Publications Warehouse

Morgan-King, Tara L.; Schoellhamer, David H.

2013-01-01

Backwater tidal sloughs are commonly found at the landward boundary of estuaries. The Cache Slough complex is a backwater tidal region within the Upper Sacramento–San Joaquin Delta that includes two features that are relevant for resource managers: (1) relatively high abundance of the endangered fish, delta smelt (Hypomesus transpacificus), which prefers turbid water and (2) a recently flooded shallow island, Liberty Island, that is a prototype for habitat restoration. We characterized the turbidity around Liberty Island by measuring suspended-sediment flux at four locations from July 2008 through December 2010. An estuarine turbidity maximum in the backwater Cache Slough complex is created by tidal asymmetry, a limited tidal excursion, and wind-wave resuspension. During the study, there was a net export of sediment, though sediment accumulates within the region from landward tidal transport during the dry season. Sediment is continually resuspended by both wind waves and flood tide currents. The suspended-sediment mass oscillates within the region until winter freshwater flow pulses flush it seaward. The hydrodynamic characteristics within the backwater region such as low freshwater flow during the dry season, flood tide dominance, and a limited tidal excursion favor sediment retention.

Functional evaluation of pollutant transformation in sediment from combined sewer system.

PubMed

Shi, Xuan; Ngo, Huu Hao; Sang, Langtao; Jin, Pengkang; Wang, Xiaochang C; Wang, Guanghua

2018-07-01

In this study, a pilot combined sewer system was constructed to characterize the pollutant transformation in sewer sediment. The results showed that particulate contaminants deposited from sewage could be transformed into dissolved matter by distinct pollutant transformation pathways. Although the oxidation-reduction potential (ORP) was varied from -80 mV to -340 mV in different region of the sediment, the fermentation was the dominant process in all regions of the sediment, which induced hydrolysis and decomposition of particulate contaminants. As a result, the accumulation of dissolved organic matter and the variation of ORP values along the sediment depth led to the depth-dependent reproduction characteristics of methanogens and sulfate-reducing bacteria, which were existed in the middle and deep layer of the sediment respectively. However, the diversity of nitrifying and polyphosphate-accumulating bacteria was low in sewer sediment and those microbial communities showed a non-significant correlation with nitrogen and phosphorus contaminants, which indicated that the enrichment of nitrogen and phosphorus contaminants was mainly caused by physical deposition process. Thus, this study proposed a promising pathway to evaluate pollutant transformation and can help provide theoretical foundation for urban sewer improvement. Copyright © 2018 Elsevier Ltd. All rights reserved.

Bed-sediment grain-size and morphologic data from Suisun, Grizzly, and Honker Bays, CA, 1998-2002

USGS Publications Warehouse

Hampton, Margaret A.; Snyder, Noah P.; Chin, John L.; Allison, Dan W.; Rubin, David M.

2003-01-01

The USGS Place Based Studies Program for San Francisco Bay investigates this sensitive estuarine system to aid in resource management. As part of the inter-disciplinary research program, the USGS collected side-scan sonar data and bed-sediment samples from north San Francisco Bay to characterize bed-sediment texture and investigate temporal trends in sedimentation. The study area is located in central California and consists of Suisun Bay, and Grizzly and Honker Bays, sub-embayments of Suisun Bay. During the study (1998-2002), the USGS collected three side-scan sonar data sets and approximately 300 sediment samples. The side-scan data revealed predominantly fine-grained material on the bayfloor. We also mapped five different bottom types from the data set, categorized as featureless, furrows, sand waves, machine-made, and miscellaneous. We performed detailed grain-size and statistical analyses on the sediment samples. Overall, we found that grain size ranged from clay to fine sand, with the coarsest material in the channels and finer material located in the shallow bays. Grain-size analyses revealed high spatial variability in size distributions in the channel areas. In contrast, the shallow regions exhibited low spatial variability and consistent sediment size over time.

Identification of water soluble and particle bound compounds causing sublethal toxic effects. A field study on sediments affected by a chlor-alkali industry.

PubMed

Bosch, Carme; Olivares, Alba; Faria, Melissa; Navas, Jose M; del Olmo, Iván; Grimalt, Joan O; Piña, Benjamín; Barata, Carlos

2009-08-13

A combination of cost effective sublethal Daphnia magna feeding tests, yeast- and cell culture-based bioassays and Toxicity Identification Evaluation (TIE) procedures was used to characterize toxic compounds within sediments collected in a river area under the influence of the effluents from a chlor-alkali industry (Ebro River, NE Spain). Tests were designed to measure and identify toxic compounds in the particulate and filtered water fractions of sediment elutriates. The combined use of bioassays responding to elutriates and dioxin-like compounds evidenced the existence of three major groups of hazardous contaminants in the most contaminated site: (A) metals such as cadmium and mercury bound to sediment fine particles that could be easily resuspended and moved downstream, (B) soluble compounds (presumably, lye) able to alkalinize water to toxic levels, and (C) organochlorine compounds with high dioxin-like activity. These results provided evidence that elutriate D. magna feeding responses can be used as surrogate assays for more tedious chronic whole sediment tests, and that the incorporation of such tests in sediment TIE procedures may improve the ability to identify the toxicity of particle-bound and water-soluble contaminants in sediments.

Radiological characterization of skyshine from a retired, low-level, radioactive liquid effluent disposal facility at Hanford

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, R.C.; Perkins, C.J.

1991-02-01

The 1301-N Liquid Waste Disposal Facility, located on the Hanford Site received N Reactor low-level radioactive liquid process effluent from 1962 to 1985. Radiation emanating from the top of the trench sections was not significant because of the sediments were normally under several meters of water, which provided the necessary shielding. Following retirement of the facility, the liquid in the trench sections percolated into the ground leaving the residual radioactively contaminated sediments unshielded along the bottom and sides of the trench sections. The radioactive constituents of the contaminated sediments include the gamma-emitting isotopes Co-60 and Cs-137. Because of the lackmore » of water covering, some of the gamma photons that were emitted upward were scattered downward due to Compton interaction with atmospheric constituents. This phenomenon is known as skyshine.'' A radiological characterization was required to provide guidance for determining the effectiveness of interim stabilization alternatives that would not adversely affect future Resource Conservation and Recovery Act site closure activities, (e.g., filling in trench sections with spoils from excavation activities). A noninvasive radiological characterization of this disposal facility and the affected area of the Columbia River shoreline was conducted. This characterization confirmed that skyshine is the cause of the elevated shoreline exposure rates and provided a model that could be used to rate the effectiveness of alternative interim stabilization measures. 4 refs., 5 figs.« less

Evaluating chemical extraction techniques for the determination of uranium oxidation state in reduced aquifer sediments.

PubMed

Stoliker, Deborah L; Campbell, Kate M; Fox, Patricia M; Singer, David M; Kaviani, Nazila; Carey, Minna; Peck, Nicole E; Bargar, John R; Kent, Douglas B; Davis, James A

2013-08-20

Extraction techniques utilizing high pH and (bi)carbonate concentrations were evaluated for their efficacy in determining the oxidation state of uranium (U) in reduced sediments collected from Rifle, CO. Differences in dissolved concentrations between oxic and anoxic extractions have been proposed as a means to quantify the U(VI) and U(IV) content of sediments. An additional step was added to anoxic extractions using a strong anion exchange resin to separate dissolved U(IV) and U(VI). X-ray spectroscopy showed that U(IV) in the sediments was present as polymerized precipitates similar to uraninite and/or less ordered U(IV), referred to as non-uraninite U(IV) species associated with biomass (NUSAB). Extractions of sediment containing both uraninite and NUSAB displayed higher dissolved uranium concentrations under oxic than anoxic conditions while extractions of sediment dominated by NUSAB resulted in identical dissolved U concentrations. Dissolved U(IV) was rapidly oxidized under anoxic conditions in all experiments. Uraninite reacted minimally under anoxic conditions but thermodynamic calculations show that its propensity to oxidize is sensitive to solution chemistry and sediment mineralogy. A universal method for quantification of U(IV) and U(VI) in sediments has not yet been developed but the chemical extractions, when combined with solid-phase characterization, have a narrow range of applicability for sediments without U(VI).

Suspended-sediment transport and storage: A demonstration of acoustic methods in the evaluation of reservoir management strategies for a small water-supply reservoir in western Colorado

USGS Publications Warehouse

Williams, Cory A.; Richards, Rodney J.; Collins, Kent L.

2015-01-01

The U.S. Bureau of Reclamation (USBR) and local stakeholder groups are evaluating reservoir-management strategies within Paonia Reservoir. This small reservoir fills to capacity each spring and requires approximately half of the snowmelt-runoff volume from its sediment-laden source waters, Muddy Creek. The U.S. Geological Survey is currently conducting high-resolution (15-minute data-recording interval) sediment monitoring to characterize incoming and outgoing sediment flux during reservoir operations at two sites on Muddy Creek. The high-resolution monitoring is being used to establish current rates of reservoir sedimentation, support USBR sediment transport and storage models, and assess the viability of water-storage recovery in Paonia Reservoir. These sites are equipped with in situ, single-frequency, side-looking acoustic Doppler current meters in conjunction with turbidity sensors to monitor sediment flux. This project serves as a demonstration of the capability of using surrogate techniques to predict suspended-sediment concentrations in small streams (less than 20 meters in width and 2 meters in depth). These two sites provide the ability to report near real-time suspended-sediment concentrations through the U.S. Geological Survey National Water Information System (NWIS) web interface and National Real-Time Water Quality websites (NRTWQ) to aid in reservoir operations and assessments.

Evaluating chemical extraction techniques for the determination of uranium oxidation state in reduced aquifer sediments

USGS Publications Warehouse

Stoliker, Deborah L.; Campbell, Kate M.; Fox, Patricia M.; Singer, David M.; Kaviani, Nazila; Carey, Minna; Peck, Nicole E.; Barger, John R.; Kent, Douglas B.; Davis, James A.

2013-01-01

Extraction techniques utilizing high pH and (bi)carbonate concentrations were evaluated for their efficacy in determining the oxidation state of uranium (U) in reduced sediments collected from Rifle, CO. Differences in dissolved concentrations between oxic and anoxic extractions have been proposed as a means to quantify the U(VI) and U(IV) content of sediments. An additional step was added to anoxic extractions using a strong anion exchange resin to separate dissolved U(IV) and U(VI). X-ray spectroscopy showed that U(IV) in the sediments was present as polymerized precipitates similar to uraninite and/or less ordered U(IV), referred to as non-uraninite U(IV) species associated with biomass (NUSAB). Extractions of sediment containing both uraninite and NUSAB displayed higher dissolved uranium concentrations under oxic than anoxic conditions while extractions of sediment dominated by NUSAB resulted in identical dissolved U concentrations. Dissolved U(IV) was rapidly oxidized under anoxic conditions in all experiments. Uraninite reacted minimally under anoxic conditions but thermodynamic calculations show that its propensity to oxidize is sensitive to solution chemistry and sediment mineralogy. A universal method for quantification of U(IV) and U(VI) in sediments has not yet been developed but the chemical extractions, when combined with solid-phase characterization, have a narrow range of applicability for sediments without U(VI).

Natural Attenuation in Streambed Sediment Receiving Chlorinated Solvents from Underlying Fracture Networks

DOE PAGES

Şimşir, Burcu; Yan, Jun; Im, Jeongdae; ...

2017-03-22

Contaminant discharge from fractured bedrock formations remains a remediation challenge. Here, we applied an integrated approach to assess the natural attenuation potential of sediment that forms the transition zone between upwelling groundwater from a chlorinated solvent-contaminated fractured bedrock aquifer and the receiving surface water. In situ measurements demonstrated that reductive dechlorination in the sediment attenuated chlorinated compounds before reaching the water column. Microcosms established with creek sediment or in situ incubated Bio-Sep beads degraded C 1-C 3 chlorinated solvents to less-chlorinated or innocuous products. Quantitative PCR and 16S rRNA gene amplicon sequencing revealed the abundance and spatial distribution of knownmore » dechlorinator biomarker genes within the creek sediment and demonstrated that multiple dechlorinator populations degrading chlorinatedC 1-C 3 alkanes and alkenes co-inhabit the sediment. Phylogenetic classification of bacterial and archaeal sequences indicated a relatively uniform distribution over spatial (300 m horizontally) scale, but Dehalococcoides and Dehalobacter were more abundant in deeper sediment, where 5.7 ± 0.4 × 10 5 and 5.4 ± 0.9 × 10 6 16S rRNA gene copies per g of sediment, respectively, were measured. The microbiological and hydrogeological characterization demonstrated that microbial processes at the fractured bedrock-sediment interface were crucial for preventing contaminants reaching the water column, emphasizing the relevance of this critical zone environment for contaminant attenuation.« less

Water-quality, bed-sediment, and biological data (October 1992 through September 1993) and statistical summaries of water-quality data (March 1985 through September 1993) for streams in the upper Clark Fork basin, Montana

USGS Publications Warehouse

Lambing, John H.

1994-01-01

Water, bed sediment, and biota were sampled in streams from Butte to below Missoula as part of a program to characterize aquatic resources in the upper Clark Fork basin of western Montana. Water-quality data were obtained periodically at 16 stations during October 1992 through September 1993 (water year 1993); daily suspended-sediment data were obtained at six of these stations. Bed-sediment and biological data were obtained at 11 stations in August 1993. Sampling stations were located on the Clark Fork and major tributaries. The primary constituents analyzed were trace elements associated with mine tailings from historic mining and smelting activities. Water-quality data include concentra- tions of major ions, trace elements, and suspended sediment in samples collected periodically during water year 1993. A statistical summary of water- quality data is provided for the period of record at each station since 1985. Daily values of streamflow, suspended-sediment concentration, and suspended-sediment discharge are given for six stations. Bed-sediment data include trace- element concentrations in the fine and bulk fractions. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Quality-assurance data are reported for analytical results of water, bed sediment, and biota.

Natural Attenuation in Streambed Sediment Receiving Chlorinated Solvents from Underlying Fracture Networks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Şimşir, Burcu; Yan, Jun; Im, Jeongdae

Contaminant discharge from fractured bedrock formations remains a remediation challenge. Here, we applied an integrated approach to assess the natural attenuation potential of sediment that forms the transition zone between upwelling groundwater from a chlorinated solvent-contaminated fractured bedrock aquifer and the receiving surface water. In situ measurements demonstrated that reductive dechlorination in the sediment attenuated chlorinated compounds before reaching the water column. Microcosms established with creek sediment or in situ incubated Bio-Sep beads degraded C 1-C 3 chlorinated solvents to less-chlorinated or innocuous products. Quantitative PCR and 16S rRNA gene amplicon sequencing revealed the abundance and spatial distribution of knownmore » dechlorinator biomarker genes within the creek sediment and demonstrated that multiple dechlorinator populations degrading chlorinatedC 1-C 3 alkanes and alkenes co-inhabit the sediment. Phylogenetic classification of bacterial and archaeal sequences indicated a relatively uniform distribution over spatial (300 m horizontally) scale, but Dehalococcoides and Dehalobacter were more abundant in deeper sediment, where 5.7 ± 0.4 × 10 5 and 5.4 ± 0.9 × 10 6 16S rRNA gene copies per g of sediment, respectively, were measured. The microbiological and hydrogeological characterization demonstrated that microbial processes at the fractured bedrock-sediment interface were crucial for preventing contaminants reaching the water column, emphasizing the relevance of this critical zone environment for contaminant attenuation.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chu, C.I.C.; Gillespie, B.L.

One of the most perplexing problems facing the coal industry is how to properly dispose of the waste and/or even recovery a small fraction of the Btu value of the waste, while minimizing the environmental concerns. UCC Research considers this monumental environmental problems as an opportunity to recovery useable organic materials and reduce the environmental problems created by coal waste. Mild gasification is the method used by UCC Research to realize these objectives. Coal feedstocks are fed into the mild gasification system yielding liquids, char, and gases for commercial application. The program consists of seven tasks: Task 1, Characterize Managementmore » of Coal Preparation Wastes; Task 2, Review Design Specifications and Prepare Preliminary Test Plan; Task 3, Select and Characterize Test Feedstocks; Task 4, Acquire/Construct Process Elements; Task 5, Prepare Final Test Plan; Task 6, Implement Final Test Plan; Task 7, Analyze Test Results and Assess System Economics. A schedule of the program is given. The program was initiated on September 30, 1984. Tasks 1, 2, 3, 4, 5, and 6 have been completed. Work is continuing on Task 7.« less

A Study of the Optimal Planning Model for Reservoir Sustainable Management- A Case Study of Shihmen Reservoir

NASA Astrophysics Data System (ADS)

Chen, Y. Y.; Ho, C. C.; Chang, L. C.

2017-12-01

The reservoir management in Taiwan faces lots of challenge. Massive sediment caused by landslide were flushed into reservoir, which will decrease capacity, rise the turbidity, and increase supply risk. Sediment usually accompanies nutrition that will cause eutrophication problem. Moreover, the unevenly distribution of rainfall cause water supply instability. Hence, how to ensure sustainable use of reservoirs has become an important task in reservoir management. The purpose of the study is developing an optimal planning model for reservoir sustainable management to find out an optimal operation rules of reservoir flood control and sediment sluicing. The model applies Genetic Algorithms to combine with the artificial neural network of hydraulic analysis and reservoir sediment movement. The main objective of operation rules in this study is to prevent reservoir outflow caused downstream overflow, minimum the gap between initial and last water level of reservoir, and maximum sluicing sediment efficiency. A case of Shihmen reservoir was used to explore the different between optimal operating rule and the current operation of the reservoir. The results indicate optimal operating rules tended to open desilting tunnel early and extend open duration during flood discharge period. The results also show the sluicing sediment efficiency of optimal operating rule is 36%, 44%, 54% during Typhoon Jangmi, Typhoon Fung-Wong, and Typhoon Sinlaku respectively. The results demonstrate the optimal operation rules do play a role in extending the service life of Shihmen reservoir and protecting the safety of downstream. The study introduces a low cost strategy, alteration of operation reservoir rules, into reservoir sustainable management instead of pump dredger in order to improve the problem of elimination of reservoir sediment and high cost.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jay, David A.

Long-term changes and fluctuations in river flow, water properties, tides, and sediment transport in the Columbia River and its estuary have had a profound effect on Columbia River salmonids and their habitat. Understanding the river-flow, temperature, tidal, and sediment-supply regimes of the Lower Columbia River (LCR) and how they interact with habitat is, therefore, critical to development of system management and restoration strategies. It is also useful to separate management and climate impacts on hydrologic properties and habitat. This contract, part of a larger project led by the National Oceanic and Atmospheric Administration (NOAA), consists of three work elements, onemore » with five tasks. The first work element relates to reconstruction of historic conditions in a broad sense. The second and third elements consist, respectively, of participation in project-wide integration efforts, and reporting. This report focuses on the five tasks within the historic reconstruction work element. It in part satisfies the reporting requirement, and it forms the basis for our participation in the project integration effort. The first task consists of several topics related to historic changes in river stage and tide. Within this task, the chart datum levels of 14 historic bathymetric surveys completed before definition of Columbia River Datum (CRD) were related to CRD, to enable analysis of these surveys by other project scientists. We have also modeled tidal datums and properties (lower low water or LLW, higher high water or HHW, mean water level or MWL, and greater diurnal tidal range or GDTR) as a function of river flow and tidal range at Astoria. These calculations have been carried for 10 year intervals (1940-date) for 21 stations, though most stations have data for only a few time intervals. Longer-term analyses involve the records at Astoria (1925-date) and Vancouver (1902-date). Water levels for any given river flow have decreased substantially (0.3-1.8 m, depending on river flow and tidal range), and tidal ranges have increased considerably (by a factor of 1.5 to 4 for most river-flow levels) since the 1900-1940 period at most stations, with the largest percentage changes occurring at upriver stations. These changes have been caused by a combination of changes in channel roughness, shape and alignment, changes in coastal tides, and (possibly) bed degradation. Tides are growing throughout the Northeast Pacific, and Astoria (Tongue Pt) has one of the most rapid rates of increase in tidal range in the entire Eastern Pacific, about 0.3m per century. More than half of this change appears to result from changes within the system, the rest from larger scale changes in coastal tides. Regression models of HHW have been used to estimate daily shallow water habitat (SWHA) available in a {approx}25 mile long reach of the system from Eagle Cliff to Kalama for 1925-2004 under four different scenarios (the four possible combinations of diked/undiked and observed flow/ virgin flow). More than 70% of the habitat in this reach has been lost (modern conditions vs. virgin flow with not dikes). In contrast, however, to the reach between Skamokawa and Beaver, selective dike removal (instead of a combination of dike removal and flow restoration) would suffice to increase spring SWHA. The second task consists of reconstruction of the hydrologic cycle before 1878, based on historic documents and inversion of tidal data collected before the onset of the historic flow record in 1878. We have a complete list of freshet times and peak flows for 1858-1877, and scattered freshet information for 1841-1857. Based on tidal data, we have reconstructed the annual flow cycles for 1870 and 1871; other time periods between 1854 and 1867 are under analysis. The three remaining tasks relate to post-1878 hydrologic conditions (flows, sediment supply and water temperature), and separation of the human and climate influences thereon. Estimated ob-served (sometimes routed), adjusted (corrected for reservoir manipulation) and virgin (corrected also for irrigation diversion) flows for 1878-2004 have been compiled for the Columbia River at The Dalles and Beaver, and for the Willamette River at Portland. Sediment transports for the ob-served, adjusted and virgin flows have been calculated for 1878-2004 for the Columbia River at Vancouver and Beaver, for the Willamette River at Portland, and for other west-side tributaries seaward of Vancouver. For Vancouver and Portland, it has been possible to estimate sand trans-port (including gravel), fine sediment transport and total load. Only total load can be estimated at Beaver, and only fine sediment transport can be determined for the west-side tributaries, except for the post-1980 period influenced by the 1980 eruption of Mt St. Helens. Changes in flows and sediment transport due to flow regulation, irrigation diversion, and climate have been estimated.« less

Structural architecture and petrophysical properties of the Rocca di Neto extensional fault zone developed in the shallow marine sediments of the Crotone Basin (Southern Apennines, Italy).

NASA Astrophysics Data System (ADS)

Pizzati, Mattia; Balsamo, Fabrizio; Iacumin, Paola; Swennen, Rudy; Storti, Fabrizio

2017-04-01

In this contribution we describe the architecture and petrophysical properties of the Rocca di Neto extensional fault zone in loose and poorly lithified sediments, located in the Crotone forearc basin (south Italy). To this end, we combined fieldwork with microstructural observations, grain size analysis, and in situ permeability measurements. The studied fault zone has an estimated maximum displacement of 80-90 m and separates early Pleistocene age (Gelasian) sands in the footwall from middle Pleistocene (Calabrian) silty clay in the hangingwall. The analysed outcrop consists of about 70 m section through the fault zone mostly developed in the footwall block. Fault zone consists of four different structural domains characterized by distinctive features: (1) <1 m-thick fault core (where the majority of the displacement is accommodated) in which bedding is transposed into foliation imparted by grain preferential orientation and some black gouges decorate the main slip surfaces; (2) zone of tectonic mixing characterized by a set of closely spaced and anastomosed deformation bands parallel to the main slip surface; (3) about 8 m-thick footwall damage zone characterized by synthetic and antithetic sets of deformation bands; (4) zone of background deformation with a few, widely-spaced conjugate minor faults and deformation bands. The boundary between the relatively undeformed sediments and the damage zone is not sharp and it is characterized by a progressive decrease in deformation intensity. The silty clay in the hangingwall damage zone is characterized by minor faults. Grain size and microstructural data indicate that particulate flow with little amount of cataclasis is the dominant deformation mechanism in both fault core rocks and deformation bands. Permeability of undeformed sediments is about 70000 mD, whereas the permeability in deformation bands ranges from 1000 to 18000 mD; within the fault core rocks permeability is reduced up to 3-4 orders of magnitude respect to the undeformed domains. Structural and petrophysical data suggest that the Rocca di Neto fault zone may compartmentalize the footwall block due to both juxtaposition of clay-rich lithology in the hangingwall and the development of low permeability fault core rocks.

Characterization and Modeling of Settling, Consolidation, and Suspension to Optimize Sediment Retention of Sediment Diversions for Coastal Restoration

NASA Astrophysics Data System (ADS)

Sha, X.; Xu, K.; Bentley, S. J.; Robichaux, P.

2016-02-01

Although many studies of sediment diversions have been conducted on the Mississippi Delta, relatively less attention has been paid to understanding sediment retention and basic cohesive sedimentation processes in receiving basins. Our research evaluates long-term (up to six months) sedimentation processes through various laboratory experiments, especially cohesive sediment settling, consolidation and resuspension and their impacts on sediment retention. Bulk sediment samples were collected from West Bay, near Head of Passes of the Mississippi Delta, and the Big Mar basin that receive water and sediment from the Caernarvon Diversion in the upper Breton Sound region of Louisiana, USA. A-230-cm tall settling column with nine sampling ports at 15 cm intervals was used to measure the consolidation for four initial sediment concentrations (10-120 kg m-3) with two salinities (1 ppt & 5 ppt). Samples of sediment slurry were taken from every port at different time intervals up to 15 days or longer (higher concentration needs longer time to consolidate) to record concentrations gravimetrically. A 200 cm long tube was connected to a 50 cm long core chamber to accumulate at least a 10 cm thick sediment column for erosion tests. A dual-core Gust Erosion Microcosm System was employed to measure time-series (0.5, 1, 2, 3, 4, 5, 6 months) erodibility at seven shear stress regimes (0.01-0.60 Pa). Our preliminary results show a significant decrease of erodibility with time and high concentration (120g/L). Salinity impacted on sediment behavior in consolidation experiments. Our study reveals that more enclosed receiving basins, intermittent openings of diversions, or reduced shear stress due to man-made structure all can potentially reduce cohesive sediment erosion in coastal Louisiana. Further results will be analyzed to determine the model constants. Consolidating rates and corresponding erosional changes will be determined to optimize sediment retention in coastal protection.

Carbon transport in Monterey Submarine Canyon

NASA Astrophysics Data System (ADS)

Barry, J.; Paull, C. K.; Xu, J. P.; Clare, M. A.; Gales, J. A.; Buck, K. R.; Lovera, C.; Gwiazda, R.; Maier, K. L.; McGann, M.; Parsons, D. R.; Simmons, S.; Rosenberger, K. J.; Talling, P. J.

2017-12-01

Submarine canyons are important conduits for sediment transport from continental margins to the abyss, but the rate, volume, and time scales of material transport have been measured only rarely. Using moorings with current meters, sediment traps (10 m above bottom) and optical backscatter sensors, we measured near-bottom currents, suspended sediment concentrations, and sediment properties at 1300 m depth in Monterey Canyon and at a non-canyon location on the continental slope at the same depth. Flow and water column backscatter were used to characterize "ambient" conditions when tidal currents dominated the flow field, and occasional "sediment transport events" when anomalously high down-canyon flow with sediment-laden waters arrived at the canyon mooring. The ambient sediment flux measured in sediment traps in Monterey Canyon was 350 times greater than measured at the non-canyon location. Although the organic carbon content of the canyon sediment flux during ambient periods was low (1.8 %C) compared to the slope location (4.9 %C), the ambient carbon transport in the canyon was 130 times greater than at the non-canyon site. Material fluxes during sediment transport events were difficult to measure owing to clogging of sediment traps, but minimal estimates indicate that mass transport during events exceeds ambient sediment fluxes through the canyon by nearly 3 orders of magnitude, while carbon transport is 380 times greater. Estimates of the instantaneous and cumulative flux of sediment and carbon from currents, backscatter, and sediment properties indicated that: 1) net flux is down-canyon, 2) flux is dominated by sediment transport events, and 3) organic carbon flux through 1300 m in Monterey Canyon was ca. 1500 MT C per year. The injection of 1500 MTCy-1 into the deep-sea represents ca. 260 km2 of the sediment C flux measured at the continental slope station (5.8 gCm-2y-1) and is sufficient to support a benthic community carbon demand of 5 gCm-2y-1 over 300 km2.

Integrative neural networks model for prediction of sediment rating curve parameters for ungauged basins

NASA Astrophysics Data System (ADS)

Atieh, M.; Mehltretter, S. L.; Gharabaghi, B.; Rudra, R.

2015-12-01

One of the most uncertain modeling tasks in hydrology is the prediction of ungauged stream sediment load and concentration statistics. This study presents integrated artificial neural networks (ANN) models for prediction of sediment rating curve parameters (rating curve coefficient α and rating curve exponent β) for ungauged basins. The ANN models integrate a comprehensive list of input parameters to improve the accuracy achieved; the input parameters used include: soil, land use, topographic, climatic, and hydrometric data sets. The ANN models were trained on the randomly selected 2/3 of the dataset of 94 gauged streams in Ontario, Canada and validated on the remaining 1/3. The developed models have high correlation coefficients of 0.92 and 0.86 for α and β, respectively. The ANN model for the rating coefficient α is directly proportional to rainfall erosivity factor, soil erodibility factor, and apportionment entropy disorder index, whereas it is inversely proportional to vegetation cover and mean annual snowfall. The ANN model for the rating exponent β is directly proportional to mean annual precipitation, the apportionment entropy disorder index, main channel slope, standard deviation of daily discharge, and inversely proportional to the fraction of basin area covered by wetlands and swamps. Sediment rating curves are essential tools for the calculation of sediment load, concentration-duration curve (CDC), and concentration-duration-frequency (CDF) analysis for more accurate assessment of water quality for ungauged basins.

A multicriteria-based methodology for site prioritisation in sediment management.

PubMed

Alvarez-Guerra, Manuel; Viguri, Javier R; Voulvoulis, Nikolaos

2009-08-01

Decision-making for sediment management is a complex task that incorporates the selections of areas for remediation and the assessment of options for any mitigation required. The application of Multicriteria Analysis (MCA) to rank different areas, according to their need for sediment management, provides a great opportunity for prioritisation, a first step in an integrated methodology that finally aims to assess and select suitable alternatives for managing the identified priority sites. This paper develops a methodology that starts with the delimitation of management units within areas of study, followed by the application of MCA methods that allows ranking of these management units, according to their need for remediation. This proposed process considers not only scientific evidence on sediment quality, but also other relevant aspects such as social and economic criteria associated with such decisions. This methodology is illustrated with its application to the case study area of the Bay of Santander, in northern Spain, highlighting some of the implications of utilising different MCA methods in the process. It also uses site-specific data to assess the subjectivity in the decision-making process, mainly reflected through the assignment of the criteria weights and uncertainties in the criteria scores. Analysis of the sensitivity of the results to these factors is used as a way to assess the stability and robustness of the ranking as a first step of the sediment management decision-making process.

Metal cycling along the northwestern Seward Peninsula, Alaska: A possible natural cause of metal contamination in the arctic: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1997

USGS Publications Warehouse

Parnow, C.C.; Goldfarb, Richard J.; Kelley, Karen D.; York, Geoffrey S.

1999-01-01

The northwestern Seward Peninsula was targeted for detailed geochemical study after evaluation of data collected during the NURE reconnaissance-level program indicated anomalously high arsenic (60-635 ppm) concentrations in stream sediments. The arsenic is associated with tin skarn, greisen, and replacement deposits in the western Seward Peninsula. Surficial sampling of waters and sediments indicate that arsenic is being transported detritally but that solution transport is insignificant. Our new data indicate that sediments downstream from these tin occurrences are characterized by anomalous values of As (85- 530 ppm) and Sn (14-36 ppm), as well as consistent anomalies of Ag, Be, Cu, Sb, and W. Stream sediments collected from drainages underlain by slate, but distal to the exposed tin occurrences, are characterized by background levels of As ( 10-60 ppm), Li (16-80 ppm), Sn (5-14 ppm), and W (5-10 ppm). These background levels for As and Sn are much higher than concentrations in typical slates and suggest a broad, weak hydrothermal alteration during mineral-deposit formation in much of the study area. A consistent pattern of Ca>>Mg>Na>K and generally alkaline pH (7 .2-8.2) characterize waters throughout the study area. Dissolved sulfate concentrations range from 10 to 40 ppm for waters draining slates and from 3 to 20 ppm for water draining carbonates. The waters collected in areas of known tin occurrences in the Potato Mountain area are characterized by increased dissolved sulfate (43-75 ppm) and are generally acidic (pH 4.7-6.5), but most trace metals are at or below detection limits. Dissolved arsenic concentrations in the areas of known tin occurrences are at or below 2 ppb. Our data suggest that detrital arsenic and tin from mineral occurrences may be naturally entering the nearshore marine environment.

CHARACTERIZING SPATIAL AND TEMPORAL DYNAMICS: DEVELOPMENT OF A GRID-BASED WATERSHED MERCURY LOADING MODEL

EPA Science Inventory

A distributed grid-based watershed mercury loading model has been developed to characterize spatial and temporal dynamics of mercury from both point and non-point sources. The model simulates flow, sediment transport, and mercury dynamics on a daily time step across a diverse lan...

Erosion and Sediment Transport Modelling in Shallow Waters: A Review on Approaches, Models and Applications.

PubMed

Hajigholizadeh, Mohammad; Melesse, Assefa M; Fuentes, Hector R

2018-03-14

The erosion and sediment transport processes in shallow waters, which are discussed in this paper, begin when water droplets hit the soil surface. The transport mechanism caused by the consequent rainfall-runoff process determines the amount of generated sediment that can be transferred downslope. Many significant studies and models are performed to investigate these processes, which differ in terms of their effecting factors, approaches, inputs and outputs, model structure and the manner that these processes represent. This paper attempts to review the related literature concerning sediment transport modelling in shallow waters. A classification based on the representational processes of the soil erosion and sediment transport models (empirical, conceptual, physical and hybrid) is adopted, and the commonly-used models and their characteristics are listed. This review is expected to be of interest to researchers and soil and water conservation managers who are working on erosion and sediment transport phenomena in shallow waters. The paper format should be helpful for practitioners to identify and generally characterize the types of available models, their strengths and their basic scope of applicability.

Presence, concentrations and risk assessment of selected antibiotic residues in sediments and near-bottom waters collected from the Polish coastal zone in the southern Baltic Sea - Summary of 3years of studies.

PubMed

Siedlewicz, Grzegorz; Białk-Bielińska, Anna; Borecka, Marta; Winogradow, Aleksandra; Stepnowski, Piotr; Pazdro, Ksenia

2018-04-01

Concentrations of selected antibiotic compounds from different groups were measured in sediment samples (14 analytes) and in near-bottom water samples (12 analytes) collected in 2011-2013 from the southern Baltic Sea (Polish coastal zone). Antibiotics were determined at concentration levels of a few to hundreds of ng g -1 d.w. in sediments and ng L -1 in near-bottom waters. The most frequently detected compounds were sulfamethoxazole, trimethoprim, oxytetracycline in sediments and sulfamethoxazole and trimethoprim in near-bottom waters. The occurrence of the identified antibiotics was characterized by spatial and temporal variability. A statistically important correlation was observed between sediment organic matter content and the concentrations of sulfachloropyridazine and oxytetracycline. Risk assessment analyses revealed a potential high risk of sulfamethoxazole contamination in near-bottom waters and of contamination by sulfamethoxazole, trimethoprim and tetracyclines in sediments. Both chemical and risk assessment analyses show that the coastal area of the southern Baltic Sea is highly exposed to antibiotic residues. Copyright © 2017 Elsevier Ltd. All rights reserved.

Erosion and Sediment Transport Modelling in Shallow Waters: A Review on Approaches, Models and Applications

PubMed Central

Fuentes, Hector R.

2018-01-01

The erosion and sediment transport processes in shallow waters, which are discussed in this paper, begin when water droplets hit the soil surface. The transport mechanism caused by the consequent rainfall-runoff process determines the amount of generated sediment that can be transferred downslope. Many significant studies and models are performed to investigate these processes, which differ in terms of their effecting factors, approaches, inputs and outputs, model structure and the manner that these processes represent. This paper attempts to review the related literature concerning sediment transport modelling in shallow waters. A classification based on the representational processes of the soil erosion and sediment transport models (empirical, conceptual, physical and hybrid) is adopted, and the commonly-used models and their characteristics are listed. This review is expected to be of interest to researchers and soil and water conservation managers who are working on erosion and sediment transport phenomena in shallow waters. The paper format should be helpful for practitioners to identify and generally characterize the types of available models, their strengths and their basic scope of applicability. PMID:29538335

Fine Sediment Erosion and Transport to the Near Coastal Zone from Watersheds of St. Thomas, USVI

NASA Astrophysics Data System (ADS)

Benoit, G.; Xuan, Z.

2014-12-01

The US Virgin Islands' landscape is characterized by steep slopes and short distances from ridge peaks to fringing reefs. Fine-grained sediments eroded from predominantly thin soils may be transported rapidly by streams (locally called guts) to the sea and cause stress to corals. We have studied erosion and transport processes on St Thomas by three methods: (1) continuous monitoring of suspended matter in one of the island's few perennial streams, Dorothea Gut, (2) measurement of 137Cs inventories in soil cores taken across the landscape, and (3) evaluation of sediment captured in most of the island's coastal ponds, through which a significant portion of runoff must pass. We find that, for areas that have not been recently disturbed, watersheds retain fine sediments surprisingly well. On the other hand, small patches of land, like building lots that have been recently disturbed and poorly managed, can produce disproportionate amounts of fine sediment. These results differ somewhat from nearby St John, USVI, where unpaved roads are the major source of eroded sediments.

Early Mesozoic rift basin architecture and sediment routing system in the Moroccan High Atlas

NASA Astrophysics Data System (ADS)

Perez, N.; Teixell, A.; Gomez, D.

2016-12-01

Late Permian to Triassic extensional systems associated with Pangea breakup governed the structural framework and rift basin architecture that was inherited by Cenozoic High Atlas Mountains in Morocco. U-Pb detrital zircon geochronologic and mapping results from Permo-Triassic deposits now incorporated into the High Atlas Mountains provide new constraints on the geometry and interconnectivity among synextensional depocenters. U-Pb detrital zircon data provide provenance constraints of Permo-Triassic deposits, highlighting temporal changes in sediment sources and revealing the spatial pattern of sediment routing along the rift. We also characterize the U-Pb detrital zircon geochronologic signature of distinctive interfingering fluvial, tidal, and aeolian facies that are preferentially preserved near the controlling normal faults. These results highlight complex local sediment mixing patterns potentially linked to the interplay between fault motion, eustatic, and erosion/transport processes. We compare our U-Pb geochronologic results with existing studies of Gondwanan and Laurentian cratonic blocks to investigate continent scale sediment routing pathways, and with analogous early Mesozoic extensional systems situated in South America (Mitu basin, Peru) and North America (Newark Basin) to assess sediment mixing patterns in rift basins.

Statistical assessment to magnetic susceptibility and heavy metal data for characterizing the coastal sediment of East coast of Tamilnadu, India.

PubMed

Harikrishnan, N; Chandrasekaran, A; Ravisankar, R; Alagarsamy, R

2018-05-01

A rapid urbanization and industrialization enhances the significant heavy metal pollution in the sediments of coastal area and introduced a serious threat to the human health. In the present study, concentration of heavy metals such as Al, Ti, Fe, V, Cr, Mn, Co, Zn, La, Pb, Mg, Ca, Ni, Cd and Ba are determined in sediments along Periyakalapet to Parangaipettai coastal area, Tamilnadu using energy dispersive X-ray fluorescence spectrometer (EDXRF).These metals have more affinity to establish metallic bond with ferrous material leading to enhancement of sediment magnetic susceptibility. Hence, a magnetic susceptibility (χLF, χHF, χFD) measurement was carried for sediments by using MS2B dual frequency susceptibility meter. Multivariate statistical analysis (Pearson correlation, factor and cluster analysis) was carried out between heavy metals and magnetic susceptibility to assess the anthropogenic impact in the sediments. The study revealed that a magnetic susceptibility measurement is an inexpensive, fast, non-destructive and suitable method to identify the heavy metal pollution sources. Copyright © 2018 Elsevier Ltd. All rights reserved.

Characterization and consequences of intermittent sediment oxygenation by macrofauna: interpretation of high-resolution data sets

NASA Astrophysics Data System (ADS)

Meile, C. D.; Dwyer, I.; Zhu, Q.; Polerecky, L.; Volkenborn, N.

2017-12-01

Mineralization of organic matter in marine sediments leads to the depletion of oxygen, while activities of infauna introduce oxygenated seawater to the subsurface. In permeable sediments solutes can be transported from animals and their burrows into the surrounding sediment through advection over several centimeters. The intermittency of pumping leads to a spatially heterogeneous distribution of oxidants, with the temporal dynamics depending on sediment reactivity and activity patterns of the macrofauna. Here, we present results from a series of experiments in which these dynamics are studied at high spatial and temporal resolution using planar optodes. From O2, pH and pCO2 optode data, we quantify rates of O2 consumption and dissolved inorganic carbon production, as well alkalinity dynamics, with millimeter-scale resolution. Simulating intermittent irrigation by imposed pumping patterns in thin aquaria, we derive porewater flow patterns, which together with the production and consumption rates cause the chemical distributions and the establishment of reaction fronts. Our analysis thus establishes a quantitative connection between the locally dynamic redox conditions relevant for biogeochemical transformations and macroscopic observations commonly made with sediment cores.

Measuring Fast-Temporal Sediment Fluxes with an Analogue Acoustic Sensor: A Wind Tunnel Study

PubMed Central

Poortinga, Ate; van Minnen, Jan; Keijsers, Joep; Riksen, Michel; Goossens, Dirk; Seeger, Manuel

2013-01-01

In aeolian research, field measurements are important for studying complex wind-driven processes for land management evaluation and model validation. Consequently, there have been many devices developed, tested, and applied to investigate a range of aeolian-based phenomena. However, determining the most effective application and data analysis techniques is widely debated in the literature. Here we investigate the effectiveness of two different sediment traps (the BEST trap and the MWAC catcher) in measuring vertical sediment flux. The study was performed in a wind tunnel with sediment fluxes characterized using saltiphones. Contrary to most studies, we used the analogue output of five saltiphones mounted on top of each other to determine the total kinetic energy, which was then used to calculate aeolian sediment budgets. Absolute sediment losses during the experiments were determined using a balance located beneath the test tray. Test runs were conducted with different sand sizes and at different wind speeds. The efficiency of the two traps did not vary with the wind speed or sediment size but was affected by both the experimental setup (position of the lowest trap above the surface and number of traps in the saltation layer) and the technique used to calculate the sediment flux. Despite this, good agreement was found between sediment losses calculated from the saltiphone and those measured using the balance. The results of this study provide a framework for measuring sediment fluxes at small time resolution (seconds to milliseconds) in the field. PMID:24058512

Phosphorus retention and internal loading in the Bay of Quinte, Lake Ontario, using diagenetic modelling.

PubMed

Doan, Phuong T K; Watson, Sue B; Markovic, Stefan; Liang, Anqi; Guo, Jay; Mugalingam, Shan; Stokes, Jonathan; Morley, Andrew; Zhang, Weitao; Arhonditsis, George B; Dittrich, Maria

2018-04-24

Internal phosphorus (P) loading significantly contributes to hysteresis in ecosystem response to nutrient remediation, but the dynamics of sediment P transformations are often poorly characterized. Here, we applied a reaction-transport diagenetic model to investigate sediment P dynamics in the Bay of Quinte, a polymictic, spatially complex embayment of Lake Ontario, (Canada). We quantified spatial and temporal variability of sediment P binding forms and estimated P diffusive fluxes and sediment P retention in different parts of the bay. Our model supports the notion that diagenetic recycling of redox sensitive and organic bound P forms drive sediment P release. In the recent years, summer sediment P diffusive fluxes varied in the range of 3.2-3.6 mg P m -2  d -1 in the upper bay compared to 1.5 mg P m -2  d -1 in the middle-lower bay. Meanwhile sediment P retention ranged between 71% and 75% in the upper and middle-lower bay, respectively. The reconstruction of temporal trends of internal P loading in the past century, suggests that against the backdrop of reduced external P inputs, sediment P exerts growing control over the lake nutrient budget. Higher sediment P diffusive fluxes since mid-20th century with particular increase in the past 20 years in the shallower upper basins, emphasize limited sediment P retention potential and suggest prolonged ecosystem recovery, highlighting the importance of ongoing P control measures. Copyright © 2018 Elsevier B.V. All rights reserved.

Preparation and characterization of nickel-spiked freshwater sediments for toxicity tests: toward more environmentally realistic nickel partitioning

USGS Publications Warehouse

Brumbaugh, William G.; Besser, John M.; Ingersoll, Christopher G.; May, Thomas W.; Ivey, Chris D.; Schlekat, Christian E.; Garman, Emily R.

2013-01-01

Two spiking methods were compared and nickel (Ni) partitioning was evaluated during a series of toxicity tests with 8 different freshwater sediments having a range of physicochemical characteristics. A 2-step spiking approach with immediate pH adjustment by addition of NaOH at a 2:1 molar ratio to the spiked Ni was effective in producing consistent pH and other chemical characteristics across a range of Ni spiking levels. When Ni was spiked into sediment having a high acid-volatile sulfide and organic matter content, a total equilibration period of at least 10 wk was needed to stabilize Ni partitioning. However, highest spiking levels evidently exceeded sediment binding capacities; therefore, a 7-d equilibration in toxicity test chambers and 8 volume-additions/d of aerobic overlying water were used to avoid unrealistic Ni partitioning during toxicity testing. The 7-d pretest equilibration allowed excess spiked Ni and other ions from pH adjustment to diffuse from sediment porewater and promoted development of an environmentally relevant, 0.5- to 1-cm oxic/suboxic sediment layer in the test chambers. Among the 8 different spiked sediments, the logarithm of sediment/porewater distribution coefficient values (log Kd) for Ni during the toxicity tests ranged from 3.5 to 4.5. These Kd values closely match the range of values reported for various field Ni-contaminated sediments, indicating that testing conditions with our spiked sediments were environmentally realistic.

Measuring fast-temporal sediment fluxes with an analogue acoustic sensor: a wind tunnel study.

PubMed

Poortinga, Ate; van Minnen, Jan; Keijsers, Joep; Riksen, Michel; Goossens, Dirk; Seeger, Manuel

2013-01-01

In aeolian research, field measurements are important for studying complex wind-driven processes for land management evaluation and model validation. Consequently, there have been many devices developed, tested, and applied to investigate a range of aeolian-based phenomena. However, determining the most effective application and data analysis techniques is widely debated in the literature. Here we investigate the effectiveness of two different sediment traps (the BEST trap and the MWAC catcher) in measuring vertical sediment flux. The study was performed in a wind tunnel with sediment fluxes characterized using saltiphones. Contrary to most studies, we used the analogue output of five saltiphones mounted on top of each other to determine the total kinetic energy, which was then used to calculate aeolian sediment budgets. Absolute sediment losses during the experiments were determined using a balance located beneath the test tray. Test runs were conducted with different sand sizes and at different wind speeds. The efficiency of the two traps did not vary with the wind speed or sediment size but was affected by both the experimental setup (position of the lowest trap above the surface and number of traps in the saltation layer) and the technique used to calculate the sediment flux. Despite this, good agreement was found between sediment losses calculated from the saltiphone and those measured using the balance. The results of this study provide a framework for measuring sediment fluxes at small time resolution (seconds to milliseconds) in the field.

Ecotoxicological bioassays of sediment leachates in a river bed flanked by decommissioned pesticide plants in Nantong City, East China.

PubMed

Zhou, Yan; Wang, Fenghe; Wan, Jinzhong; He, Jian; Li, Qun; Qiang Chen; Gao, Jay; Lin, Yusuo; Zhang, Shengtian

2017-03-01

Traditionally, the toxicity of river contaminants is analyzed chemically or physically through river bed sediments. The biotoxicity of polluted sediment leachates has not caught our attention. This study aims to overcome this deficiency through a battery of biotests which were conducted to monitor comprehensive toxicity of sediment leachates for the Yaogang River in East Jiangsu Province of China, which is in close proximity to former pesticide plants. The general physical and chemical parameters of major pollutants were analyzed from river bed sediments collected at five strategic locations. The ecotoxicity analyses undertaken include overall fish (adult zebrafish) acute toxicity, luminescent bacteria (Vibrio fischeri) bioassay, and zebrafish embryo toxicity assay. Compared with the control group, sediment leachates increased the lethality, inhibited the embryos hatching and induced development abnormalities of zebrafish embryos, and inhibited the luminescence of V. fischeri. The results show that sediment leachates may assume various toxic effects, depending on the test organism. This diverse toxicity to aquatic organisms reflects their different sensitivity to sediment leachates. It is found clearly that V. fischeri was the organism which was characterized by the highest sensitivity to the sediment leachates. The complicated toxicity of leachates was not caused by one single factor but by multiple pollutants together. This indicates the need of estimations of sediment leachate not only taking into account chemical detection but also of applying the biotests to the problem. Thus, multigroup bioassays are necessary to realistically evaluate river ecological risks imposed by leachates.

Implications of Tidally Varying Bed Stress and Intermittent Estuarine Stratification on Fine-Sediment Dynamics through the Mekong's Tidal River to Estuarine Reach

NASA Astrophysics Data System (ADS)

McLachlan, R. L.; Ogston, A. S.; Allison, M. A.; Hilmo, R. S.

2016-12-01

Widely varying ratios of marine to freshwater influence within near-mouth distributaries have impacts on sedimentary processes within the lower river that have yet to be thoroughly characterized. These impacts are of particular interest because river gauging stations are often above the river-estuary interface and, therefore, may not accurately characterize sediment flux through the lower river. Flow velocity, salinity, and suspended sediment properties (concentration, particle size, and settling velocity) were measured within the tidal Sông Hu distributary of the lower Mekong River, Vietnam during both high and low river discharge seasons. Seasonal variations in river discharge and estuarine regime resulted in export of fine sediment when discharge was high ( 1.7 t s-1) and import when discharge was low ( 0.25 t s-1). Generally, the estuary moved in and out of 40 km of the lower distributary with discharge and tidal phase, and the estuary exhibited salt wedge to partially-mixed conditions. High river discharge and neap tides increased stratification of salinity and suspended sediment. Suspended sediment was influenced by seasonal and tidal fluctuations in near-bed shear stress and the intermittent presence of a protective salt wedge and associated estuary turbidity maximum. This fluctuating flow and salinity regime induced variations in flocculation, settling, and trapping of sediment within the river channel. Above the estuary, particles were pre-flocculated, and within and near the estuary, increased flocculation promoted particle settling. The degree of aggregation and settling velocity of suspended particles were largest during ebb tides of high river discharge and during flood tides of low river discharge. Sediment deposited on the river bed was protected from resuspension by lowered bed stress within and near the salt wedge. These patterns promote retention of mud in the lower river when estuarine processes exist and mud export when fluvial processes dominate. The spectrum of present conditions analyzed collaboratively with field studies, remotely sensed observations, and modeling has shed light on how this environment, and other large tropical deltas, will react to changing magnitudes of fluvial and marine influences due to sea-level rise and anthropogenic alterations to the delta.

Sediment transport on the Palos Verdes shelf over seasonal to decadal time scales

USGS Publications Warehouse

Wiberg, P.L.; Drake, D.E.; Harris, C.K.; Noble, M.

2002-01-01

We combine direct observations, longer-term wave data, and model calculations to characterize resuspension and transport of fine-grained, effluent-affected sediment on the Palos Verdes shelf. Near-bed waves, currents, and suspended sediment concentrations were monitored during the winter of 1992-93 with a bottom tripod and current-meter mooring at a 63-m-deep site. Wave conditions that winter were moderate (??? 2 year recurrence interval), and mean current was alongshelf to the northwest; currents were not significantly correlated with wave conditions. Seven wave events during the winter (December-March) produced near-bed wave orbital velocities at the study site in excess of 14 cm s-1, the observed threshold for significant resuspension. Three of these events occurred during the bottom tripod deployment and are characterized by the highest persistent suspended sediment concentrations in the tripod record. Suspended sediment flux was alongshelf to the northwest for 5 of the 6 wave events for which current data were available; one event occurred during low southeast currents. Measured suspended sediment concentration and grain size generally agree with values that were calculated using a shelf sediment transport model with no adjustment of parameters from values determined for two muddy sites on the northern California shelf. We extend our seasonal observations to a period of almost 2 decades by applying the observed thresholds for wave-driven resuspension to near-bed wave conditions calculated from NDBC Buoy 46025 surface wave data. An average of 10 resuspension events per year, with an average duration of 1.6 days, were identified at a water depth of 60 m; the number of events dropped to 3 per year at 90 m, beyond the shelf break. For the majority of these events, calculated net suspended sediment flux is toward the northwest (alongshelf) at an average rate of 140 kg m-1 h-1; about a third of the events have net southeastward flux at an average rate of 30 kg m-1 h-1. The calculated thickness of the resuspended surface layer of the bed was less than 1 cm for all events at 60 m. ?? 2002 Elsevier Science Ltd. All rights reserved.

Clinch River remedial investigation task 9 -- benthic macroinvertebrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scott, E.M. Jr.

1994-08-01

This report summarizes the results of Task 9 of the TVA/Department of Energy (DOE) Interagency Agreement supporting DOE`s Clinch River Remedial Investigation. Species lists and densities (numbers/m{sup 2}) of benthic macroinvertebrates sampled at 16 sites in the Clinch River and Poplar Creek embayments of upper Watts Bar Reservoir near Oak Ridge, Tennessee, in March, 1994, are presented and briefly discussed. Data are also analyzed to assess and compare quality of benthic communities at each site, according to methods developed for TVA`s Reservoir Vital Signs Monitoring Program. Results of this study will be incorporated with other program tasks in a comprehensivemore » report prepared by Oak Ridge National Laboratory in 1995, which will, in part, assess the effect of sediment contaminants on benthic macroinvertebrate communities in Watts Bar Reservoir.« less

In-situ geotechnical investigation of sediment dynamics over `The Bar', Raglan, New Zealand

NASA Astrophysics Data System (ADS)

Stark, N.; Greer, D.; Phillips, D. J.; Borrero, J. C.; Harrison, S.; Kopf, A.

2010-12-01

The geotechnical characteristics of surficial sediments on a highly mobile, N-S-oriented ebb tidal shoal (‘The Bar’) near the entrance to Whaingaroa Harbour, in Raglan, NZ, were investigated using the dynamic penetrometer Nimrod, which is suitable for deployments in areas characterized by strong currents and active wave climate common to this site. Vertical sediment strength, based upon penetrometer deceleration and a quasi-static bearing capacity equivalent, was profiled at 23 positions along as well as in the vicinity of ‘The Bar’ during slack water. Recently deposited or loose sediment was detected as a top layer of lower sediment strength (quasi-static bearing capacity equivalent [qs. bc.] < 10 kPa) over a stiff substratum (mean maximum qs. bs. ~ 105 kPa), and quantified (thickness: 0 - 7 cm) indicating areas of sediment accumulation and areas of sediment erosion. These results were correlated to mean current velocities and directions predicted by ASR Ltd.’s Whaingaroa Harbour Model. In relation to sediment dynamics, ‘The Bar’ area can be divided into different zones: (i) the channel connecting ‘The Bar’ to the harbor, (ii) the southern arm, (iii) the mid-section, (iv) the northern arm, and (v, vi) the northern and southern wings covering the area between ‘The Bar’ and the shore. The channel is characterized by high current velocities (up to 1.7 m/s) along the W-E-axis, suggesting strong sediment erosion and no (re-)deposition. However, despite the high mean current velocities, the penetrometer results hint at sediment deposition. This is most likely explained by the deep trench in the channel that could trap sediment. Comparing the northern and the southern wing, the currents follow the bathymetry and coastline alignment and are mirrored at the W-E-axis, but the mean current velocities are higher at the southern wing (northern wing: up to 0.4 m/s; southern wing: up to 0.6 m/s). The penetrometer results suggest strong sediment erosion on the southern wing (qs. bc. up to 155 kPa, top layer thickness ~ 2 cm), and show no evidence of sediment remobilization on the northern wing (no layering). On the northern and southern arms, low currents (~ 0.3 m/s) with very mixed directions were predicted. In front (west) of the most southern corner an area of strong sediment accumulation was localized following the penetrometer results (top layer thickness: 7 cm). This leads to the hypothesis that in the ebb-shoal system at Whaingaroa Harbour, mobile sediment is mainly transported via the southern wing of the ‘The Bar’ potentially leading to an increase of sediment erosion in this area due to effects like sanding. Sediment deposition might occur in the trench of the channel as well as in the vicinity of the southernmost portion of the sandbar. This matches observations according to which the southern arm shifted about 220 m whereas the northern arm only moved 20 m within one year. The in-situ penetrometer as well as the numerical results compare favorably with observations of ‘The Bar’s morphology. Both methods provide valuable insights which enhance our understanding of the sediment dynamics in this area.

Permeability-porosity relationships of subduction zone sediments

USGS Publications Warehouse

Gamage, Kusali; Screaton, Elizabeth; Bekins, B.; Aiello, I.

2011-01-01

Permeability-porosity relationships for sediments from the northern Barbados, Costa Rica, Nankai, and Peru subduction zones were examined based on sediment type, grain size distribution, and general mechanical and chemical compaction history. Greater correlation was observed between permeability and porosity in siliciclastic sediments, diatom oozes, and nannofossil chalks than in nannofossil oozes. For siliciclastic sediments, grouping of sediments by percentage of clay-sized material yields relationships that are generally consistent with results from other marine settings and suggests decreasing permeability as percentage of clay-sized material increases. Correction of measured porosities for smectite content improved the correlation of permeability-porosity relationships for siliciclastic sediments and diatom oozes. The relationship between permeability and porosity for diatom oozes is very similar to the relationship in siliciclastic sediments, and permeabilities of both sediment types are related to the amount of clay-size particles. In contrast, nannofossil oozes have higher permeability values by 1.5 orders of magnitude than siliciclastic sediments of the same porosity and show poor correlation between permeability and porosity. More indurated calcareous sediments, nannofossil chalks, overlap siliciclastic permeabilities at the lower end of their measured permeability range, suggesting similar consolidation patterns at depth. Thus, the lack of correlation between permeability and porosity for nannofossil oozes is likely related to variations in mechanical and chemical compaction at shallow depths. This study provides the foundation for a much-needed global database with fundamental properties that relate to permeability in marine settings. Further progress in delineating controls on permeability requires additional carefully documented permeability measurements on well-characterized samples. ?? 2010 Elsevier B.V.

Rare earth elements in fine-grained sediments of major rivers from the high-standing island of Taiwan

NASA Astrophysics Data System (ADS)

Li, Chuan-Shun; Shi, Xue-Fa; Kao, Shuh-Ji; Liu, Yan-Guang; Lyu, Hua-Hua; Zou, Jian-Jun; Liu, Sheng-Fa; Qiao, Shu-Qing

2013-06-01

Thirty-eight sediment samples from 15 primary rivers on Taiwan were retrieved to characterize the rare earth element (REE) signature of fluvial fine sediment sources. Compared to the three large rivers on the Chinese mainland, distinct differences were observed in the REE contents, upper continental crust normalized patterns and fractionation factors of the sediment samples. The average REE concentrations of the Taiwanese river sediments are higher than those of the Changjiang and Huanghe, but lower than the Zhujiang. Light rare earth elements (LREEs) are enriched relative to heavy rare earth elements (HREEs) with ratios from 7.48 to 13.03. We found that the variations in (La/Lu)UCC-(Gd/Lu)UCC and (La/Yb)UCC-(Gd/Yb)UCC are good proxies for tracing the source sediments of Taiwanese and Chinese rivers due to their distinguishable values. Our analyses indicate that the REE compositions of Taiwanese river sediments were primarily determined by the properties of the bedrock, and the intensity of chemical weathering in the drainage areas. The relatively high relief and heavy rainfall also have caused the REEs in the fluvial sediments from Taiwan to be transported to the estuaries down rivers from the mountains, and in turn delivered nearly coincidently to the adjacent seas by currents and waves. Our studies suggest that the REE patterns of the river sediments from Taiwan are distinguishable from those from the other sources of sediments transported into the adjacent seas, and therefore are useful proxies for tracing the provenances and dispersal patterns of sediments, as well as paleoenvironmental changes in the marginal seas.

Sigh rate and respiratory variability during mental load and sustained attention.

PubMed

Vlemincx, Elke; Taelman, Joachim; De Peuter, Steven; Van Diest, Ilse; Van den Bergh, Omer

2011-01-01

Spontaneous breathing consists of substantial correlated variability: Parameters characterizing a breath are correlated with parameters characterizing previous and future breaths. On the basis of dynamic system theory, negative emotion states are predicted to reduce correlated variability whereas sustained attention is expected to reduce total respiratory variability. Both are predicted to evoke sighing. To test this, respiratory variability and sighing were assessed during a baseline, stressful mental arithmetic task, nonstressful sustained attention task, and recovery in between tasks. For respiration rate (excluding sighs), reduced total variability was found during the attention task, whereas correlated variation was reduced during mental load. Sigh rate increased during mental load and during recovery from the attention task. It is concluded that mental load and task-related attention show specific patterns in respiratory variability and sigh rate. Copyright © 2010 Society for Psychophysiological Research.

Size analysis of polyglutamine protein aggregates using fluorescence detection in an analytical ultracentrifuge.

PubMed

Polling, Saskia; Hatters, Danny M; Mok, Yee-Foong

2013-01-01

Defining the aggregation process of proteins formed by poly-amino acid repeats in cells remains a challenging task due to a lack of robust techniques for their isolation and quantitation. Sedimentation velocity methodology using fluorescence detected analytical ultracentrifugation is one approach that can offer significant insight into aggregation formation and kinetics. While this technique has traditionally been used with purified proteins, it is now possible for substantial information to be collected with studies using cell lysates expressing a GFP-tagged protein of interest. In this chapter, we describe protocols for sample preparation and setting up the fluorescence detection system in an analytical ultracentrifuge to perform sedimentation velocity experiments on cell lysates containing aggregates formed by poly-amino acid repeat proteins.

Late Holocene climate dynamics: A high-resolution sediment core from Maxwell Bay, South Shetland Islands, Antarctica

NASA Astrophysics Data System (ADS)

Hass, H. C.; Kuhn, G.; Monien, P.; Brumsack, H.

2009-12-01

Presently, the Antarctic Peninsula belongs to the fastest warming regions on Earth. Meltwater discharge increases, glaciers retreat and as a consequence the coastal ecosystems change at an ever-increasing pace. The goal of our study is to reconstruct the timing and impact of historical climate phases such as the Medieval Warm Period (MWP) and the Little Ice Age (LIA) as analogs for the recent climate development, and to identify the marine sedimentary processes affected by the changing climate. We present results from a 928 cm long gravity core from Maxwell Bay, King George Island, Antarctica. The core spans the past c. 1700 years. Sedimentation at the core site is governed by sediments from the tributary fjords entering Maxwell Bay, namely Potter and Marian coves and Collins Harbor. There are two sediment classes: Class 1 is characterized by two grain-size subpopulations. The coarser one represents the bedload fraction, whereas the finer one is interpreted to represent meltwater-induced suspension load. Since meltwater is restricted to the summer season, it is suggested that Class 1 sediments characterize periods of intense summer-meltwater production and thus, warmer climate phases. Class 2 samples show the same coarse grain-size mode but they lack the fine subpopulation. We suggest that these sediments indicate less intense summer-meltwater production and thus colder climatic conditions. The mean grain size suggests that average bottom current speeds were slightly higher during colder climate phases than during the warmer phases. Bioproduction at the core location and in the sediment source areas as reflected by bio-productivity proxies (TOC, bio-opal) is not always positively related to climate since warm-phase meltwater discharge adversely affects bioproduction through light attenuation by turbid waters. Furthermore, during warmer phases the TOC signal becomes diluted due to increased deposition of terrigenous fine sediment. Comparison with Antarctic, hemispherical, and global temperature reconstructions reveals clear signals of the MWP, the LIA and the post-LIA climate recovery. Class 1 sediments dominate the warmer MWP, Class 2 sediments dominate the colder LIA. The Maxwell Bay record shows climate signals that are partly unique to either one of the hemispheres. Thus, it resembles best the global temperature reconstruction. Apparently, the MWP started earlier in the Southern Hemisphere (SH) than in the Northern Hemisphere suggesting that the source for the warming might also be in the SH. In contrast to the MWP the timing of the LIA appears to be largely synchronous between the hemispheres. Generally finer sediments clearly mark the end of the LIA. however no stronger meltwater influence can be detected; the conditions of the AD 1970s resemble those at the beginning of the MWP. Changing sedimentation processes cannot be detected in the Maxwell Bay record until AD 1975.

Characterization of eco-hydraulic habitats for examining biogeochemical processes in rivers

NASA Astrophysics Data System (ADS)

McPhillips, L. E.; O'Connor, B. L.; Harvey, J. W.

2009-12-01

Spatial variability in biogeochemical reaction rates in streams is often attributed to sediment characteristics such as particle size, organic material content, and biota attached to or embedded within the sediments. Also important in controlling biogeochemical reaction rates are hydraulic conditions, which influence mass transfer of reactants from the stream to the bed, as well as hyporheic exchange within near-surface sediments. This combination of physical and ecological variables has the potential to create habitats that are unique not only in sediment texture but also in their biogeochemical processes and metabolism rates. In this study, we examine the two-dimensional (2D) variability of these habitats in an agricultural river in central Iowa. The streambed substratum was assessed using a grid-based survey identifying dominant particle size classes, as well as aerial coverage of green algae, benthic organic material, and coarse woody debris. Hydraulic conditions were quantified using a calibrated 2D model, and hyporheic exchange was assessed using a scaling relationship based on sediment and hydraulic characteristics. Point-metabolism rates were inferred from measured sediment dissolved oxygen profiles using an effective diffusion model and compared to traditional whole-stream measurements of metabolism. The 185 m study reach had contrasting geomorphologic and hydraulic characteristics in the upstream and downstream portions of an otherwise relatively straight run of a meandering river. The upstream portion contained a large central gravel bar (50 m in length) flanked by riffle-run segments and the downstream portion contained a deeper, fairly uniform channel cross-section. While relatively high flow velocities and gravel sediments were characteristic of the study river, the upstream island bar separated channels that differed with sandy gravels on one side and cobbley gravels on the other. Additionally, green algae was almost exclusively found in riffle portions of the cobbley gravel channel sediments while fine benthic organic material was concentrated at channel margins, regardless of the underlying sediments. A high degree of spatial variability in hyporheic exchange potential was the result of the complex 2D nature of topography and hydraulics. However, sediment texture classifications did a reasonable job in characterizing variability in hyporheic exchange potential because sediment texture mapping incorporates qualitative aspects of bed shear stress and hydraulic conductivity that control hyporheic exchange. Together these variables greatly influenced point-metabolism measurements in different sediment texture habitats separated by only 1 to 2 m. Results from this study suggest that spatial variability and complex interactions between geomorphology, hydraulics, and biological communities generate eco-hydraulic habitats that control variability in biogeochemical processes. The processes controlling variability are highly two-dimensional in nature and are not often accounted for in traditional one-dimensional analysis approaches of biogeochemical processes.

Contaminants in stream sediments from seven United States metropolitan areas: part II—sediment toxicity to the amphipod Hyalella azteca and the midge Chironomus dilutus

USGS Publications Warehouse

Kemble, Nile E.; Hardesty, Douglas K.; Ingersoll, Christopher G.; Kunz, James L.; Sibley, Paul K.; Calhoun, Daniel L.; Gilliom, Robert J.; Kuivila, Kathryn; Nowell, Lisa H.; Moran, Patrick W.

2013-01-01

Pyrethroids are hydrophobic compounds that have been observed to accumulate in sediments (Laskowski 2002). Toxicity of pyrethroids in field-collected sediment from small urban streams (Weston et al. 2005; Holmes et al. 2008; Ding et al. 2010; Domagalski et al. 2010) or with pyrethroids spiked into sediment (Amweg et al. 2006; Hintzen et al. 2009) have been evaluated primarily in 10 day lethality tests conducted with the amphipod Hyalella azteca. However, the sublethal effects in long-term exposures to pyrethroids in sediment have not been evaluated, and the distribution of pyrethroids sediments has not typically been evaluated in wadeable streams (Gilliom et al. 2006). This article is the second in a series that describe the results of a study of the distribution and toxicity of pyrethroids and other co-occurring trace elements and organic contaminants (PCBs, PAHs, OC pesticides) in stream sediments from 7 metropolitan areas across the United States (Moran et al. 2012). The study evaluated 98 sediment samples collected from streams ranging from undeveloped to highly urban and differs from previous studies by sampling larger wadeable streams and avoiding point sources (such as storm drains) and other inflows (Gilliom et al. 2006). Part 1 of the series characterizes sediment contaminants in relation to urbanization and other factors in the 7 metropolitan study areas (Nowell et al. 2012). Part 2 (this article) evaluates relationships between sediment chemistry and sediment toxicity in 28 day whole-sediment exposures conducted with the amphipod H. azteca and in 10 day whole-sediment exposure conducted with the midge Chironomus dilutus (USEPA United States Environmental Protection Agency 2000; ASTM American Society for Testing and Materials International 2012). Toxicity end points evaluated in the amphipod and midge exposures included the effects of these field-collected sediments on survival, weight, or biomass of the test organisms.

Characterizing Three-Dimensional Mixing Process in a River Confluence using Hydro-acoustical Backscatter and Flow Measurement

NASA Astrophysics Data System (ADS)

Son, Geunsoo; Kim, Dongsu; Kim, YoungDo; Lyu, Siwan; Kim, Seojun

2017-04-01

River confluences are zones where two rivers with different geomorphic and hydraulic characteristics amalgamate, resulting in rapid change in terms of flow regime, sediment entrainment and hydraulic geometry. In these confluence zones, the flow structure is basically complicated responded with concurrent mixing of physical and chemical aquatic properties, and continuous channel morphology could be changed due to erosion and sedimentation. In addition, the confluences are regions in which two rivers join and play an important role in river ecology. In order to characterize the mixing process of confluence for understanding the impacts of a river on the other river, therefore, it has been crucial to analyze the spatial mixing patterns for main streams depending on various inflow conditions of tributaries. However, most conventional studies have mostly relied upon hydraulic or water quality numerical models for understanding mixing pattern analysis of confluences, due to the difficulties to acquire a wide spatial range of in-situ data especially for characterizing this kind of mixing process. Even with intensive in-situ measurements, those researches tended to focus mainly on the hydraulic characteristics such as the flow and morphological complexity of confluence, so that very few studies comprehensively included sediment variation with flow at the same time. In this study, subsequently, flow and sediment mixing characteristics were concurrently investigated in the confluence between Nakdong and Nam river in South Korea, where it has been frequently questioned to determine how Nam river affects Nakdong river that recently have suffered various environmental problems such as green algae bloom and erosion/deposition in the confluence. We basically examined the mixing characteristics of confluence by using acoustic Doppler current profilers (ADCPs) which were used to measure hydraulic factors such as flow rate and depth, as well as measuring the suspended sediment concentration by using acoustic backscatter. Cross-sectional ADCP measurements in a confluence were collected with high spatial resolution in order to analyze the details of spatial distribution in the perspective of the three-dimensional mixing patterns of flow and sediment, where backscatters (or SNR) measured from ADCPs were used to track sediment mixing assuming that it could be a surrogate to estimate the suspended sediment concentration. Raw backscatter data were corrected by considering the beam spreading and absorption by water. Also, an optical Laser diffraction instrument (LISST) was used to verify the method of acoustic backscatter and to collect the particle size distribution of main stream and tributary. In addition, image-based spatial distributions of sediment mixture in the confluence were monitored in various flow conditions by using an unmanned aerial vehicle (UAV), which were compared with the spatial distribution of acoustic backscatter. As results, we found that when acoustic backscatter and flow measurements by ADCPs were well processed, they could be proper indicators to identify the spatial patterns of the three-dimensional mixing process between two rivers.

Mathematical Tasks and the Student: Navigating "Tensions of Intentions" between Designers, Teachers, and Students

ERIC Educational Resources Information Center

Johnson, Heather Lynn; Coles, Alf; Clarke, David

2017-01-01

We articulate a student perspective on task design in mathematics education, foregrounding a dynamic relationship between intentions of task designers, teachers, and students. First, we characterize a student perspective on task design. Second, we provide theoretical perspectives that we use as tools to account for different facets of task design…

Effects of Wave Energy Converter (WEC) Arrays on Wave, Current, and Sediment Circulation

NASA Astrophysics Data System (ADS)

Ruehl, K.; Roberts, J. D.; Jones, C.; Magalen, J.; James, S. C.

2012-12-01

The characterization of the physical environment and commensurate alteration of that environment due to Wave Energy Conversion (WEC) devices, or arrays of devices, must be understood to make informed device-performance predictions, specifications of hydrodynamic loads, and environmental evaluations of eco-system responses (e.g., changes to circulation patterns, sediment dynamics, and water quality). Hydrodynamic and sediment issues associated with performance of wave-energy devices will primarily be nearshore where WEC infrastructure (e.g., anchors, piles) are exposed to large forces from the surface-wave action and currents. Wave-energy devices will be subject to additional corrosion, fouling, and wear of moving parts caused by suspended sediments in the water column. The alteration of the circulation and sediment transport patterns may also alter local ecosystems through changes in benthic habitat, circulation patterns, or other environmental parameters. Sandia National Laboratories is developing tools and performing studies to quantitatively characterize the environments where WEC devices may be installed and to assess potential affects to hydrodynamics and local sediment transport. The primary tools are wave, hydrodynamic, and sediment transport models. To ensure confidence in the resulting evaluation of system-wide effects, the models are appropriately constrained and validated with measured data where available. An extension of the US EPA's EFDC code, SNL-EFDC, provides a suitable platform for modeling the necessary hydrodynamics;it has been modified to directly incorporate output from a SWAN wave model of the region. Model development and results are presented. In this work, a model is exercised for Monterey Bay, near Santa Cruz where a WEC array could be deployed. Santa Cruz is located on the northern coast of Monterey Bay, in Central California, USA. This site was selected for preliminary research due to the readily available historical hydrodynamic data (currents and wave heights, periods, and directions), sediment characterization data, and near-shore bathymetric data. In addition, the region has been under evaluation for future ocean energy projects. The modeling framework of SWAN and SNL-EFDC combined with field validation datasets allows for a robust quantitative description of the nearshore environment within which the MHK devices will be evaluated. This quantitative description can be directly incorporated into environmental impact assessments to eliminate guesswork related to the effects of the presence of large-scale arrays. These results can be used to design more efficient arrays while minimizing impacts on the nearshore environments. Further investigations into fine-scale scour near the structures will help determine if these large-scale results show that, in fact, there is deposition adjacent to the arrays, which could have design implications on anchorage and cabling systems.

Tide-Dominated Tract (TDT) as a key sedimentary zone characterizing tide-dominated large-river delta and estuary systems

NASA Astrophysics Data System (ADS)

Saito, Y.

2017-12-01

Large rivers in continents have a characteristic of slow rise and fall in water levels during floods or the wet season due to a wide drainage basin. A gentle river gradient and large water discharge have relatively large tidal ranges at the river mouth, resulting in large backwater effects further upstream. The result of the Mekong River survey (386 riverbed sediments, river topography, CTD, and biofacies) shows that the distributary channels of the Mekong River delta in Vietnam are divided into two parts: the landward river-dominated tract (RDT) and seaward tide-dominated tract (TDT). The RDT is characterized by a highly variable and deepening trend in water depth and coarse-grained sediments with a fining trend downstream. The TDT is characterized by a shallowing trend in water depth with river-widening, smooth riverbeds, a straight shape, and heterolithic f- to vf-sand and mud alternation (tidal thythmite). The boundary of both tracts is sharply identified by sediment facies and river morphology. Sediment facies indicates that the dominant sedimentary process of bottom sediments is "bedload" in the RDT and "suspension" in the TDT. Daily tidal changes are observed through the year, while water-level changes during the flood/wet season are limited in the TDT. Saltwater intrusion is limited within the seaward part of the TDT alone ( 50 km), close to final bifurcation points. However, brackish-water biofacies is observed in the TDT mainly due to diluted brackish water and/or tolerance to the freshwater environment. These characteristics are also found in the Yangtze; the distance of the TDT/RDT boundary from the river mouth is ca. 100 km in the Mekong, and 200 km in the Yangtze. The preservation potential of sediments in a TDT is low in a progradational system, and high in abandoned channels. The early Holocene transgressive estuary system in the incised valley of the Yangtze formed during the Last Glacial Maximum was composed of 20 m-thick fine-grained heterolithic sediments (inclusive of tidal thythmite), distributed over 200 km in the valley, inside of the paleo-shoreline. Similarly, such well-preserved sediments are formed in a TDT of a large-river transgressive estuarine system. An estuarine facies model for large-river systems is the need of the hour. cf. references Gugliotta et al., Process regime, salinity, morphological, and sedimentary trends along the fluvial to marine transition zone of the mixed-energy Mekong River delta, Vietnam. Continental Shelf Research. http://dx.doi.org/10.1016/j.csr.2017.03.001. Hori et al., 2001. Sedimentary facies of the tide-dominated paleo-Changjiang (Yangtze) estuary during the last transgression. Marine Geology, 177, 331-351.

A framework for characterizing eHealth literacy demands and barriers.

PubMed

Chan, Connie V; Kaufman, David R

2011-11-17

Consumer eHealth interventions are of a growing importance in the individual management of health and health behaviors. However, a range of access, resources, and skills barriers prevent health care consumers from fully engaging in and benefiting from the spectrum of eHealth interventions. Consumers may engage in a range of eHealth tasks, such as participating in health discussion forums and entering information into a personal health record. eHealth literacy names a set of skills and knowledge that are essential for productive interactions with technology-based health tools, such as proficiency in information retrieval strategies, and communicating health concepts effectively. We propose a theoretical and methodological framework for characterizing complexity of eHealth tasks, which can be used to diagnose and describe literacy barriers and inform the development of solution strategies. We adapted and integrated two existing theoretical models relevant to the analysis of eHealth literacy into a single framework to systematically categorize and describe task demands and user performance on tasks needed by health care consumers in the information age. The method derived from the framework is applied to (1) code task demands using a cognitive task analysis, and (2) code user performance on tasks. The framework and method are applied to the analysis of a Web-based consumer eHealth task with information-seeking and decision-making demands. We present the results from the in-depth analysis of the task performance of a single user as well as of 20 users on the same task to illustrate both the detailed analysis and the aggregate measures obtained and potential analyses that can be performed using this method. The analysis shows that the framework can be used to classify task demands as well as the barriers encountered in user performance of the tasks. Our approach can be used to (1) characterize the challenges confronted by participants in performing the tasks, (2) determine the extent to which application of the framework to the cognitive task analysis can predict and explain the problems encountered by participants, and (3) inform revisions to the framework to increase accuracy of predictions. The results of this illustrative application suggest that the framework is useful for characterizing task complexity and for diagnosing and explaining barriers encountered in task completion. The framework and analytic approach can be a potentially powerful generative research platform to inform development of rigorous eHealth examination and design instruments, such as to assess eHealth competence, to design and evaluate consumer eHealth tools, and to develop an eHealth curriculum.

A Framework for Characterizing eHealth Literacy Demands and Barriers

PubMed Central

Chan, Connie V

2011-01-01

Background Consumer eHealth interventions are of a growing importance in the individual management of health and health behaviors. However, a range of access, resources, and skills barriers prevent health care consumers from fully engaging in and benefiting from the spectrum of eHealth interventions. Consumers may engage in a range of eHealth tasks, such as participating in health discussion forums and entering information into a personal health record. eHealth literacy names a set of skills and knowledge that are essential for productive interactions with technology-based health tools, such as proficiency in information retrieval strategies, and communicating health concepts effectively. Objective We propose a theoretical and methodological framework for characterizing complexity of eHealth tasks, which can be used to diagnose and describe literacy barriers and inform the development of solution strategies. Methods We adapted and integrated two existing theoretical models relevant to the analysis of eHealth literacy into a single framework to systematically categorize and describe task demands and user performance on tasks needed by health care consumers in the information age. The method derived from the framework is applied to (1) code task demands using a cognitive task analysis, and (2) code user performance on tasks. The framework and method are applied to the analysis of a Web-based consumer eHealth task with information-seeking and decision-making demands. We present the results from the in-depth analysis of the task performance of a single user as well as of 20 users on the same task to illustrate both the detailed analysis and the aggregate measures obtained and potential analyses that can be performed using this method. Results The analysis shows that the framework can be used to classify task demands as well as the barriers encountered in user performance of the tasks. Our approach can be used to (1) characterize the challenges confronted by participants in performing the tasks, (2) determine the extent to which application of the framework to the cognitive task analysis can predict and explain the problems encountered by participants, and (3) inform revisions to the framework to increase accuracy of predictions. Conclusions The results of this illustrative application suggest that the framework is useful for characterizing task complexity and for diagnosing and explaining barriers encountered in task completion. The framework and analytic approach can be a potentially powerful generative research platform to inform development of rigorous eHealth examination and design instruments, such as to assess eHealth competence, to design and evaluate consumer eHealth tools, and to develop an eHealth curriculum. PMID:22094891

Reconstructing Sediment Supply, Transport and Deposition Behind the Elwha River Dams

NASA Astrophysics Data System (ADS)

Beveridge, C.

2017-12-01

The Elwha River watershed in Olympic National Park of Washington State, USA is predominantly a steep, mountainous landscape where dominant geomorphic processes include landslides, debris flows and gullying. The river is characterized by substantial variability of channel morphology and fluvial processes, and alternates between narrow bedrock canyons and wider alluvial reaches for much of its length. Literature suggests that the Elwha watershed is topographically and tectonically in steady state. The removal of the two massive hydropower dams along the river in 2013 marked the largest dam removal in history. Over the century long lifespan of the dams, approximately 21 million cubic meters of sediment was impounded behind them. Long term erosion rates documented in this region and reservoir sedimentation data give unprecedented opportunities to test watershed sediment yield models and examine dominant processes that control sediment yield over human time scales. In this study, we aim to reconstruct sediment supply, transport and deposition behind the Glines Canyon Dam (most upstream dam) over its lifespan using a watershed modeling approach. We developed alternative models of varying complexity for sediment production and transport at the network scale driven by hydrologic forcing. We simulate sediment supply and transport in tributaries upstream of the dam. The modeled sediment supply and transport dynamics are based on calibrated formulae (e.g., bedload transport is simulated using Wilcock-Crowe 2003 with modification based on observed bedload transport in the Elwha River). Observational data that aid in our approach include DEM, channel morphology, meteorology, and streamflow and sediment (bedload and suspended load) discharge. We aim to demonstrate how the observed sediment yield behind the dams was influenced by upstream transport supply and capacity limitations, thereby demonstrating the scale effects of flow and sediment transport processes in the Elwha River watershed.

Fluvial bar dynamics in large meandering rivers with different sediment supply in the Amazon River basin

NASA Astrophysics Data System (ADS)

Monegaglia, Federico; Zolezzi, Guido; Tubino, Marco; Henshaw, Alex

2017-04-01

Sediments in the large meandering rivers of the Amazon basin are known to be supplied by sources providing highly different magnitudes of sediment input and storage, ranging from the sediment-rich Andean region to the sediment-poor Central Trough. Recent observations have highlighted how such differences in sediment supply have an important, net effect on the rates of planform activity of meandering rivers in the basin, in terms of meander migration and frequency of cutoffs. In this work we quantify and discuss the effect of sediment supply on the organization of macroscale sediment bedforms on several large meandering rivers in the Amazon basin, and we link our findings with those regarding the rates of planform activity. Our analysis is conducted through the newly developed software PyRIS, which enables us to perform extensive multitemporal analysis of river morphodynamics from multispectral remotely sensed Landsat imagery in a fully automated fashion. We show that large rivers with low sediment supply tend to develop alternate bars that consistently migrate through long reaches, characterized at the same time by limited planform development. On the contrary, high sediment supply is associated with the development of point bars that are well-attached to the evolving meander bends and that follow temporal oscillations around the bend apexes, which in turn show rapid evlution towards complex meander shapes. Finally, rivers with intermediate rates of sediment supply develop rather steady point bars associated with slowly migrating, regular meanders. We finally discuss the results of the image analysis in the light of the properties of river planform metrics (like channel curvature and width) for the examined classes of river reaches with different sediment supply rates.

Sediment yields from small, steep coastal watersheds of California

USGS Publications Warehouse

Warrick, Jonathan A.; Melack, John M.; Goodridge, Blair M.

2015-01-01

Global inventories of sediment discharge to the ocean highlight the importance of small, steep watersheds (i.e., those having drainage areas less than 100,000 km2 and over 1000 m of relief) that collectively provide a dominant flux of sediment. The smallest of these coastal watersheds (e.g., those that have drainage areas less than 1000 km2) can represent a large portion of the drainage areas of active margin coasts, such as California’s coast, but remain almost universally unmonitored. Here we report on the suspended-sediment discharge of several small coastal watersheds (10-56 km2) of the Santa Ynez Mountains, California, that were found to have ephemeral discharge and suspended-sediment concentrations ranging between 1 and over 200,000 mgL-1. Sediment concentrations were weakly correlated with discharge (r2 = 0.10–0.25), and all types of hysteresis patterns were observed during high flows (clockwise, counterclockwise, no hysteresis, and complex). Sediment discharge varied strongly with time and was measurably elevated in one watershed following a wildfire. Although sediment yields varied by over 100-fold across the watersheds (e.g., 15 – 2100 tkm-2 yr -1during the relatively wet 2005 water year), the majority of sediment discharge (65-80%) occurred during only 1% of the time for all watersheds. Furthermore, sampling of dozens of high flow events provides evidence that sediment yields were generally related to peak discharge yields, although these relationships were not consistent across the watersheds. These results suggest that small watersheds of active margins can provide large fluxes of sediment to the coast, but that the rates and timing of this sediment discharge is more irregular in time – and thus more difficult to characterize – than the better monitored and studied watersheds that are 1000-100,000 km2.

Geochemical signature of provenance, tectonics and chemical weathering in the Quaternary flood plain sediments of the Hindon River, Gangetic plain, India

NASA Astrophysics Data System (ADS)

Mondal, M. E. A.; Wani, H.; Mondal, Bulbul

2012-09-01

The Ganga basin in the Himalayan foreland is a part of the world's largest area of modern alluvial sedimentation. Flood plain sediments of the Hindon River of the Gangetic plain have been analyzed for sediment texture, major and trace elements including rare earth elements (REEs). The results have been used to characterize the source rock composition and to understand the intensity of chemical weathering, tectonics and their interplay in the Hindon flood plain. The sediments of the Hindon flood plain dominantly consist of sand sized particles with little silt and clay. The geochemistry of the Hindon sediments has been compared to the Siwalik mudstone of the Siwalik Group (Siwaliks). The Siwalik sedimentary rocks like sandstones, mudstones and conglomerates are the known source rocks for the Hindon flood plain sediments. Mudstone geochemistry has been considered best to represent the source rock characteristics. The UCC (Upper Continental Crust) normalized major and trace elements of the Hindon flood plain sediments are very similar to the Siwalik mudstone except for Th and Cr. Furthermore, the average chondrite normalized REE pattern of the Hindon flood plain sediments is similar to the Siwalik mudstone. Textural immaturity, K/Rb ratios and the average CIA (Chemical Index of Alteration) and PIA (Plagioclase Index of Alteration) values of the Hindon flood plain sediments indicate that the sediments have not been affected by chemical weathering. Our study suggests that the active tectonics of the Himalayas and monsoon climate enhances only physical erosion of the source rocks (Siwaliks) rather than the chemical alteration. These factors help the Hindon sediments to retain their parental and tectonic signature even after recycling.

Dynamics of sediments along with their core properties in the Monastir-Bekalta coastline (Tunisia, Central Mediterranean)

NASA Astrophysics Data System (ADS)

Khiari, Nouha; Atoui, Abdelfattah; Khalil, Nadia; Charef, Abdelkrim; Aleya, Lotfi

2017-10-01

The authors report on two campaigns of high-resolution samplings along the shores of Monastir Bay in Tunisia: the first being a study of sediment dynamics, grain size and mineral composition in surface sediment, and the second, eight months later, using four sediment cores to study grain-size distribution in bottom sediments. Particle size analysis of superficial sediment shows that the sand in shallow depths is characterized by S-shaped curves, indicating a certain degree of agitation, possible transport by rip currents near the bottom and hyperbolic curves illustrating heterogeneity of sand stock. The sediments settle in a relatively calm environment. Along the bay shore (from 0 to 2 m depth), the bottom is covered by medium sand. Sediment transport is noted along the coast; from north to south and from south to north, caused by longshore drift and a rip current in the middle of the bay. These two currents are generated by wind and swell, especially by north to northeast waves which transport the finest sediment. Particle size analysis of bottom sediment indicates a mean grain size ranging from coarse to very fine sands while vertical distribution of grain size tends to decrease from surface to depth. The increase in particle size of sediment cores may be due to the coexistence of terrigenous inputs along with the sedimentary transit parallel to the coast due to the effect of longshore drift. Mineralogical analysis shows that Monastir's coastal sands and bottom sediment are composed of quartz, calcite, magnesium calcite, aragonite and hematite. The existence of a low energy zone with potential to accumulate pollutants indicates that managerial action is necessary to help preserve Monastir Bay.

K/Ar Dating of Fine Grained Sediments Near Prydz Bay, Antarctica: East Antarctic Ice Sheet Behavior During the Middle-Miocene Climate Transition

NASA Astrophysics Data System (ADS)

Duchesne, A. E.; Pierce, E. L.; Williams, T.; Hemming, S. R.; Johnson, D. L.; May, T.; Gombiner, J.; Torfstein, A.

2012-12-01

¶ The Middle Miocene Climate Transition (MMCT) (~14 Ma) represents a time of major East Antarctic Ice-Sheet (EAIS) expansion, with research suggesting major global sea level fall on the order of ~60 meters (John et al., 2011, EPSL). Ocean Drilling Program (ODP) core data from Site 1165B near Prydz Bay shows an influx of cobbles deposited ~13.8-13.5 Ma, representing a sudden burst of ice-rafted detritus (IRD) during the MMCT. Based on 40Ar/39Ar dating of hornblendes and/or biotite grains, 5 of 6 dated pebbles from a companion study show Wilkes Land origins, indicating transport from over 1500 kilometers away. However, samples throughout this time interval have an anomalously low abundance of sand, thus we seek to understand the sedimentary processes that led to the deposition of these isolated dropstones in a fine matrix through provenance studies of the core's terrigenous fine fraction. Geochemical provenance studies of the terrigenous fraction of marine sediments can aid in identifying past dynamic EAIS behavior; the few outcrops available on the continent provide specific rock characterizations and age constraints from which cored marine sediments can then be matched to using established radiogenic isotope techniques. Here we apply the K/Ar dating method as a provenance tool for identifying the source area(s) of fine-grained terrigenous sediments (<63 μm) deposited during the MMCT. ¶ After source area characterization, we find that the fine-grained sediments from the mid-Miocene show a mixture of both local Prydz Bay sourcing (~400 Ma signature) and Wilkes Land provenance (~900 Ma signature). While locally-derived Prydz Bay sediments are likely to have been delivered via meltwater from ice and deposited as hemipelagic sediments (with some possible bottom current modification, as this is a drift site), sediments sourced from Wilkes Land required transport via large icebergs. Future work will involve further provenance determination on both the fine-grained sediments and the abundant dropstones deposited at ODP Site 1165B during the MMCT. We anticipate that the use of the K/Ar radiometric dating technique as a proxy for the study of glacially transported fine-grained terrigenous materials will enable future Antarctic provenance research and further aid in providing insight into past EAIS behavior.; ODP Core 34X from Site 1165B