Particle-scale measurement of PAH aqueous equilibrium partitioning in impacted sediments.

PubMed

Ghosh, Upal; Hawthorne, Steven B

2010-02-15

This research investigated the particle-scale processes that control aqueous equilibrium partitioning of PAHs in manufactured gas plant (MGP) site sediments. Dominant particle types in impacted sediments (sand, wood, coal/coke, and pitch) were physically separated under a microscope for equilibrium assessments. Solid-phase microextraction (SPME) combined with selected ion monitoring GC/MS and perdeuterated PAH internal standards were used to determine freely dissolved PAH concentrations in small (0.1-1 mL) water samples at concentrations as low as microg/L (for lower molecular weight PAHs) to ng/L (for higher molecular weight PAHs). For every particle class the initial release of PAHs into the aqueous phase was rapid, and an apparent equilibrium was reached in a matter of days. The average ratio of aqueous total PAH concentration for pitch vs coal/coke particles for eight sediment samples was 20. Thus, sediments that had aged in the field for many decades were not at equilibrium and were still going through a slow process of contaminant mass transfer between the different particle types. A possible consequence of this slow aging process is further lowering of the activity of the chemical as mass transfer is achieved to new sorption sites with time. This study also found that the presence of black carbon even at the level of (1)/(3) of sediment organic carbon does not necessarily imply a BC-dominated sorption behavior, rather source pitch particles if present may dominate PAH partitioning. To our knowledge this is the first report of equilibrium partitioning assessment conducted at the sediment particle scale.

How vegetation and sediment transport feedbacks drive landscape change in the Everglades and wetlands worldwide

USGS Publications Warehouse

Larsen, Laurel G.; Harvey, Judson W.

2010-01-01

Mechanisms reported to promote landscape self‐organization cannot explain vegetation patterning oriented parallel to flow. Recent catastrophic shifts in Everglades landscape pattern and ecological function highlight the need to understand the feedbacks governing these ecosystems. We modeled feedback between vegetation, hydrology, and sediment transport on the basis of a decade of experimentation. Results from more than 100 simulations showed that flows just sufficient to redistribute sediment from sparsely vegetated sloughs to dense ridges were needed for an equilibrium patterned landscape oriented parallel to flow. Surprisingly, although vegetation heterogeneity typically conveys resilience, in wetlands governed by flow/sediment feedbacks it indicates metastability, whereby the landscape is prone to catastrophic shifts. Substantial increases or decreases in flow relative to the equilibrium condition caused an expansion of emergent vegetation and loss of open‐water areas that was unlikely to revert upon restoration of the equilibrium hydrology. Understanding these feedbacks is critical in forecasting wetland responses to changing conditions and designing management strategies that optimize ecosystem services, such as carbon sequestration or habitat provision. Our model and new sensitivity analysis techniques address these issues and make it newly apparent that simply returning flow to predrainage conditions in the Everglades may not be sufficient to restore historic landscape patterns and processes.

Degradation of fipronil in anaerobic sediments and the effect on porewater concentrations.

PubMed

Brennan, Amanda A; Harwood, Amanda D; You, Jing; Landrum, Peter F; Lydy, Michael J

2009-09-01

The current study measured the degradation of fipronil in laboratory-spiked silt loam sediment under anaerobic conditions at different aging times. The half-life of fipronil in anaerobic sediments spiked at 5.8+/-0.049 and 21+/-1.4microg/kg dry weight (dw) was 21+/-0.22 and 15+/-0.11d, respectively. Fipronil-sulfide was the primary degradation product with fipronil-sulfone detected at lower concentrations. No degradation occurred to fipronil-sulfide and fipronil-sulfone over 200d in separate systems. A concurrent decline in sediment concentrations resulted in a decline of fipronil in sediment porewater with an increase in fipronil-sulfide and fipronil-sulfone measured by matrix-solid phase microextraction (matrix-SPME). Equilibrium among sediment, porewater, and matrix-SPME fiber occurred within 138d for fipronil and fipronil-sulfone; however, fipronil-sulfide did not reach equilibrium during the test, and modeling predicted upwards of 1083d to reach equilibrium. Regardless of the time to reach equilibrium, the rapid degradation of fipronil has little ecological significance given that fipronil-sulfide and fipronil-sulfone have equal or greater toxicity, and exhibit greater environmental stability in both the sediment and porewater, thereby becoming bioavailable.

Equilibrium Partitioning Sediment Benchmarks (ESBs) for the Protection of Benthic Organisms: Procedures for the Determination of the Freely Dissolved Interstitial Water Concentrations of Nonionic Organics

EPA Science Inventory

This document describes procedures to determine the concentrations of nonionic organic chemicals in sediment interstitial waters. In previous ESB documents, the general equilibrium partitioning (EqP) approach was chosen for the derivation of sediment benchmarks because it account...

Equilibrium Partitioning Sediment Benchmarks (ESBs) for the ...

EPA Pesticide Factsheets

This document describes procedures to determine the concentrations of nonionic organic chemicals in sediment interstitial waters. In previous ESB documents, the general equilibrium partitioning (EqP) approach was chosen for the derivation of sediment benchmarks because it accounts for the varying bioavailability of chemicals in different sediments and allows for the incorporation of the appropriate biological effects concentration. This provides for the derivation of benchmarks that are causally linked to the specific chemical, applicable across sediments, and appropriately protective of benthic organisms.  This equilibrium partitioning sediment benchmark (ESB) document was prepared by scientists from the Atlantic Ecology Division, Mid-Continent Ecology Division, and Western Ecology Division, the Office of Water, and private consultants. The document describes procedures to determine the interstitial water concentrations of nonionic organic chemicals in contaminated sediments. Based on these concentrations, guidance is provided on the derivation of toxic units to assess whether the sediments are likely to cause adverse effects to benthic organisms. The equilibrium partitioning (EqP) approach was chosen because it is based on the concentrations of chemical(s) that are known to be harmful and bioavailable in the environment.  This document, and five others published over the last nine years, will be useful for the Program Offices, including Superfund, a

Understanding the role of sediment waves and channel conditions over time and space

Treesearch

Thomas E. Lisle

1997-01-01

Abstract - Dynamic equilibrium in stream channels has traditionally been applied on the reach scale, where fluxes of water and sediment into a reach result in rapid but minor adjustments of channel dimensions, hydraulics or roughness (equilibrium), or aggradation and degradation (disequilibrium). Such an essentially one-dimensional spatial approach to sediment-channel...

Equilibrium Conditions of Sediment Suspending Flows on Earth, Mars and Titan

NASA Astrophysics Data System (ADS)

Amy, L. A.; Dorrell, R. M.

2016-12-01

Sediment entrainment, erosion and deposition by liquid water on Earth is one of the key processes controlling planetary surface evolution. Similar modification of planetary surfaces by liquids associated with a volatile cycle are also inferred to have occurred on other planets (e.g., water on Mars and methane-ethane on Titan). Here we explore conditions for equilibrium flow - the threshold between net sediment erosion and deposition - on different planets. We use a new theoretical model for particle erosion-suspension-deposition: this model shows a better fit to empirical data than comparative suspension criterions (e.g., Rouse Number) since it takes into account both flow competence and capacity, and particle size distribution effects. Shear stresses required to initially entrain sediment and maintain equilibrium flow vary significantly, being several times lower on Mars and more than ten times lower on Titan resulting principally from lower gravities. On all planets it is harder to maintain equilibrium flow as sediment mixtures become poorer sorted (higher shear stresses are needed as standard deviation increases). In comparison to large differences in critical shear stresses, critical slopes for equilibrium flow are similar for planets. Compared to Earth, equilibrium slopes on Mars should be slightly lower whilst those on Titan will be higher or lower for organic and ice particle systems, respectively. Particle size distribution has a similar, order of magnitude effect, on equilibrium slope on each planet. The results highlight that whilst reduced gravity on Titan and Mars significantly decreases the bed shear stress required for particle transport, it also proportionally effects the bed shear stress of moving fluid, such that similar slope gradients are required for equilibrium flow; minor variations in equilibrium slopes are related to differences in the particle-fluid density contrasts as well as fluid viscosities. These results help explain why planetary surfaces share striking similarities in their present or past landscapes and shows that particle size distribution is critical to sediment transport dynamics. Interestingly, particle distribution may vary between planets depending on the particle compositions and weathering regimes, imposing differences in equilibrium conditions.

Analysis of equivalent widths of alluvial channels and application for instream habitat in the Rio Grande

Treesearch

Claudia A. Leon

2003-01-01

Rivers are natural systems that adjust to variable water and sediment discharges. Channels with spatial variability in width that are managed to maintain constant widths over a period of time are able to transport the same water and sediment discharges by adjusting the bed slope. Methods developed to de ne equilibrium hydraulic geometry characteristics of alluvial...

Contamination of estuarine water, biota, and sediment by halogenated organic compounds: A field study

USGS Publications Warehouse

Pereira, W.E.; Rostad, C.E.; Chiou, C.T.; Brinton, T.I.; Barber, L.B.; Demcheck, D.K.; Demas, C.R.

1988-01-01

Studies conducted in the vicinity of an industrial outfall in the Calcasieu River estuary, Louisiana, have shown that water, bottom and suspended sediment, and four different species of biota are contaminated with halogenated organic compounds (HOC) including haloarenes. A "salting-out" effect in the estuary moderately enhanced the partitioning tendency of the contaminants into biota and sediments. Contaminant concentrations in water, suspended sediments, and biota were found to be far below the values predicted on the basis of the assumption of phase equilibria with respect to concentrations in bottom sediment. Relative concentration factors of HOC between biota (catfish) and bottom sediment increased with increasing octanol/estuarine water partition coefficients (Kow*), maximizing at log Kow* of about 5, although these ratios were considerably less than equilibrium values. In contrast, contaminant concentrations in water, biota, and suspended sediments were much closer to equilibrium values. Bioconcentration factors of HOC determined on the basis of lipid content for four different biotic species correlated reasonably well with equilibrium triolein/water partition coefficients (Ktw).

Quantifying differences in the impact of variable chemistry on equilibrium uranium(VI) adsorption properties of aquifer sediments

USGS Publications Warehouse

Stoliker, Deborah L.; Kent, Douglas B.; Zachara, John M.

2011-01-01

Uranium adsorption-desorption on sediment samples collected from the Hanford 300-Area, Richland, WA varied extensively over a range of field-relevant chemical conditions, complicating assessment of possible differences in equilibrium adsorption properties. Adsorption equilibrium was achieved in 500-1000 h although dissolved uranium concentrations increased over thousands of hours owing to changes in aqueous chemical composition driven by sediment-water reactions. A nonelectrostatic surface complexation reaction, >SOH + UO22+ + 2CO32- = >SOUO2(CO3HCO3)2-, provided the best fit to experimental data for each sediment sample resulting in a range of conditional equilibrium constants (logKc) from 21.49 to 21.76. Potential differences in uranium adsorption properties could be assessed in plots based on the generalized mass-action expressions yielding linear trends displaced vertically by differences in logKc values. Using this approach, logKc values for seven sediment samples were not significantly different. However, a significant difference in adsorption properties between one sediment sample and the fines (Kc uncertainty were improved by capturing all data points within experimental errors. The mass-action expression plots demonstrate that applying models outside the range of conditions used in model calibration greatly increases potential errors.

Variable-Field Analytical Ultracentrifugation: I. Time-Optimized Sedimentation Equilibrium

PubMed Central

Ma, Jia; Metrick, Michael; Ghirlando, Rodolfo; Zhao, Huaying; Schuck, Peter

2015-01-01

Sedimentation equilibrium (SE) analytical ultracentrifugation (AUC) is a gold standard for the rigorous determination of macromolecular buoyant molar masses and the thermodynamic study of reversible interactions in solution. A significant experimental drawback is the long time required to attain SE, which is usually on the order of days. We have developed a method for time-optimized SE (toSE) with defined time-varying centrifugal fields that allow SE to be attained in a significantly (up to 10-fold) shorter time than is usually required. To achieve this, numerical Lamm equation solutions for sedimentation in time-varying fields are computed based on initial estimates of macromolecular transport properties. A parameterized rotor-speed schedule is optimized with the goal of achieving a minimal time to equilibrium while limiting transient sample preconcentration at the base of the solution column. The resulting rotor-speed schedule may include multiple over- and underspeeding phases, balancing the formation of gradients from strong sedimentation fluxes with periods of high diffusional transport. The computation is carried out in a new software program called TOSE, which also facilitates convenient experimental implementation. Further, we extend AUC data analysis to sedimentation processes in such time-varying centrifugal fields. Due to the initially high centrifugal fields in toSE and the resulting strong migration, it is possible to extract sedimentation coefficient distributions from the early data. This can provide better estimates of the size of macromolecular complexes and report on sample homogeneity early on, which may be used to further refine the prediction of the rotor-speed schedule. In this manner, the toSE experiment can be adapted in real time to the system under study, maximizing both the information content and the time efficiency of SE experiments. PMID:26287634

Estuarine Facies Model Revisited: Conceptual Model of Estuarine Sediment Dynamics During Non-Equilibrium Conditions

NASA Astrophysics Data System (ADS)

Elliott, E. A.; Rodriguez, A. B.; McKee, B. A.

2017-12-01

Traditional models of estuarine systems show deposition occurs primarily within the central basin. There, accommodation space is high within the deep central valley, which is below regional wave base and where current energy is presumed to reach a relative minimum, promoting direct deposition of cohesive sediment and minimizing erosion. However, these models often reflect long-term (decadal-millennial) timescales, where accumulation rates are in relative equilibrium with the rate of relative sea-level rise, and lack the resolution to capture shorter term changes in sediment deposition and erosion within the central estuary. This work presents a conceptual model for estuarine sedimentation during non-equilibrium conditions, where high-energy inputs to the system reach a relative maximum in the central basin, resulting in temporary deposition and/or remobilization over sub-annual to annual timescales. As an example, we present a case study of Core Sound, NC, a lagoonal estuarine system where the regional base-level has been reached, and sediment deposition, resuspension and bypassing is largely a result of non-equilibrium, high-energy events. Utilizing a 465 cm-long sediment core from a mini-basin located between Core Sound and the continental shelf, a 40-year sub-annual chronology was developed for the system, with sediment accumulation rates (SAR) interpolated to a monthly basis over the 40-year record. This study links erosional processes in the estuary directly with sediment flux to the continental shelf, taking advantage of the highly efficient sediment trapping capability of the mini-basin. The SAR record indicates high variation in the estuarine sediment supply, with peaks in the SAR record at a recurrence interval of 1 year (+/- 0.25). This record has been compared to historical storm influence for the area. Through this multi-decadal record, sediment flushing events occur at a much more frequent interval than previously thought (i.e. annual rather than decadal timescales). This non-equilibrium estuarine model highlights moderate-energy events that impact the coast at least every year, in addition to high energy less frequent decadal to millennial events for modulating sediment and particulate matter erosion and transport through the estuary and delivery to the continental shelf.

Geochronology of recent sediments from the Cariaco Trench (Venezuela) by Alpha Spectrometry of {sup 210}Pb ({sup 210}Po)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arriojas, A.; Barros, H.; Palacios, D.

2010-08-04

210Pb concentration in marine sediments of the Cariaco Trench (North-East of Venezuela) was measured through the analysis of 210Po alpha emissions, which can be assumed to be in secular equilibrium with 210Pb. The analysed sediment core has a length of 1.9 m. The results allowed to apply the CF:CS dating model (Constant Flux and Constant Supply). The sedimentation rate was estimated to be 0.25 cm/y. As far as we know this is the first {alpha}- dating carried out in the country, performed with an alpha spectrometer recently funded by the IAEA.

Selecting Performance Reference Compounds (PRCS)for Polyethylene Passive Samplers Deployed at Contaminated Sediment Sites

EPA Science Inventory

Use of equilibrium passive samplers for performing aquatic environmental monitoring at contaminated sediment sites, including Superfund sites, is becoming more common. However, a current challenge in passive sampling is determining when equilibrium is achieved between the sampl...

Human alterations, dynamic equilibrium, and riparian ecosystem responses along selected rivers in Tuscany, Italy (Invited)

NASA Astrophysics Data System (ADS)

Hupp, C. R.; Rinaldi, M.

2010-12-01

Many, if not most, streams have been mildly to severely affected by human disturbance, which complicates efforts to understand riparian ecosystems. Mediterranean regions have a long history of human influences including: dams, stream channelization, mining of sediment, and levee /canal construction. Typically these alterations reduce the ecosystem services that functioning floodplains provide and may negatively impact the natural ecology of floodplains through reductions in suitable habitats, biodiversity, and nutrient cycling. Additionally, human alterations typically shift affected streams away from a state of natural dynamic equilibrium, where net sediment deposition is approximately in balance with net erosion. Lack of equilibrium typically affects the degree to which floodplain ecosystems are connected to streamflow regime. Low connectivity, usually from human- or climate-induced incision, may result in reduced flow on floodplains and lowered water tables. High connectivity may result in severe sediment deposition. Connectivity has a direct impact on vegetation communities. Riparian vegetation distribution patterns and diversity relative to various fluvial geomorphic channel patterns, landforms, and processes are described and interpreted for selected rivers of Tuscany, Central Italy; with emphasis on channel evolution following human impacts. Multivariate analysis reveals distinct quantitative vegetation patterns related to six fluvial geomorphic surfaces. Analysis of vegetation data also shows distinct associations of plants with adjustment processes related to the stage of channel evolution. Plant distribution patterns coincide with disturbance/landform/soil moisture gradients. Species richness increases from channel bed to terrace and on heterogeneous riparian areas, while species richness decreases from moderate to intense incision and from low to intense narrowing. As a feedback mechanism, woody vegetation in particular may facilitate geomorphic recovery of floodplains by affecting sedimentation dynamics. Identification and understanding of critical fluvial parameters related to floodplain connectivity (e.g. stream gradient, grain-size, and hydrography) and spatial and temporal sediment deposition/erosion process trajectories should facilitate management efforts to retain and/or regain important ecosystem services.

DEVELOPMENT AND APPLICATION OF EQUILIBRIUM PARTITIONING SEDIMENT GUIDELINES IN THE ASSESSMENT OF SEDIMENT PAH CONTAMINATION

EPA Science Inventory

The U.S. Environmental Protection Agency used insights and methods from its water quality criteria program to develop ESGs. The discovery that freely-dissolved contaminants were the toxic form led to equilibrium partitioning being chosen to model the distribution of contaminants...

Isotherm, kinetic, and thermodynamic study of ciprofloxacin sorption on sediments.

PubMed

Mutavdžić Pavlović, Dragana; Ćurković, Lidija; Grčić, Ivana; Šimić, Iva; Župan, Josip

2017-04-01

In this study, equilibrium isotherms, kinetics and thermodynamics of ciprofloxacin on seven sediments in a batch sorption process were examined. The effects of contact time, initial ciprofloxacin concentration, temperature and ionic strength on the sorption process were studied. The K d parameter from linear sorption model was determined by linear regression analysis, while the Freundlich and Dubinin-Radushkevich (D-R) sorption models were applied to describe the equilibrium isotherms by linear and nonlinear methods. The estimated K d values varied from 171 to 37,347 mL/g. The obtained values of E (free energy estimated from D-R isotherm model) were between 3.51 and 8.64 kJ/mol, which indicated a physical nature of ciprofloxacin sorption on studied sediments. According to obtained n values as measure of intensity of sorption estimate from Freundlich isotherm model (from 0.69 to 1.442), ciprofloxacin sorption on sediments can be categorized from poor to moderately difficult sorption characteristics. Kinetics data were best fitted by the pseudo-second-order model (R 2  > 0.999). Thermodynamic parameters including the Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) were calculated to estimate the nature of ciprofloxacin sorption. Results suggested that sorption on sediments was a spontaneous exothermic process.

Quantifying Differences in the Impact of Variable Chemistry on Equilibrium Uranium(VI) Adsorption Properties of Aquifer Sediments

PubMed Central

2011-01-01

Uranium adsorption–desorption on sediment samples collected from the Hanford 300-Area, Richland, WA varied extensively over a range of field-relevant chemical conditions, complicating assessment of possible differences in equilibrium adsorption properties. Adsorption equilibrium was achieved in 500–1000 h although dissolved uranium concentrations increased over thousands of hours owing to changes in aqueous chemical composition driven by sediment-water reactions. A nonelectrostatic surface complexation reaction, >SOH + UO22+ + 2CO32- = >SOUO2(CO3HCO3)2–, provided the best fit to experimental data for each sediment sample resulting in a range of conditional equilibrium constants (logKc) from 21.49 to 21.76. Potential differences in uranium adsorption properties could be assessed in plots based on the generalized mass-action expressions yielding linear trends displaced vertically by differences in logKc values. Using this approach, logKc values for seven sediment samples were not significantly different. However, a significant difference in adsorption properties between one sediment sample and the fines (<0.063 mm) of another could be demonstrated despite the fines requiring a different reaction stoichiometry. Estimates of logKc uncertainty were improved by capturing all data points within experimental errors. The mass-action expression plots demonstrate that applying models outside the range of conditions used in model calibration greatly increases potential errors. PMID:21923109

Quantifying differences in the impact of variable chemistry on equilibrium Uranium(VI) adsorption properties of aquifer sediments.

PubMed

Stoliker, Deborah L; Kent, Douglas B; Zachara, John M

2011-10-15

Uranium adsorption-desorption on sediment samples collected from the Hanford 300-Area, Richland, WA varied extensively over a range of field-relevant chemical conditions, complicating assessment of possible differences in equilibrium adsorption properties. Adsorption equilibrium was achieved in 500-1000 h although dissolved uranium concentrations increased over thousands of hours owing to changes in aqueous chemical composition driven by sediment-water reactions. A nonelectrostatic surface complexation reaction, >SOH + UO₂²⁺ + 2CO₃²⁻ = >SOUO₂(CO₃HCO₃)²⁻, provided the best fit to experimental data for each sediment sample resulting in a range of conditional equilibrium constants (logK(c)) from 21.49 to 21.76. Potential differences in uranium adsorption properties could be assessed in plots based on the generalized mass-action expressions yielding linear trends displaced vertically by differences in logK(c) values. Using this approach, logK(c) values for seven sediment samples were not significantly different. However, a significant difference in adsorption properties between one sediment sample and the fines (< 0.063 mm) of another could be demonstrated despite the fines requiring a different reaction stoichiometry. Estimates of logK(c) uncertainty were improved by capturing all data points within experimental errors. The mass-action expression plots demonstrate that applying models outside the range of conditions used in model calibration greatly increases potential errors.

DEVELOPMENT AND AVAILABILITY OF EQUILIBRIUM PARTITIONING SEDIMENT GUIDELINES (ESGS) FOR NONIONIC ORGANIC CONTAMINANTS, METALS MIXTURES, AND POLYCYCLIC AROMATIC HYDROCARBON (PAH) MIXTURES

EPA Science Inventory

Collaborative efforts between EPA's Office of Water and Office of Research and Development have resulted in the development of sediment guidelines based on equilibrium partitioning theory (EqP). The guidance available includes a technical support document, describing the derivat...

Sorption kinetics of TNT and RDX in anaerobic freshwater and marine sediments: Batch studies.

PubMed

Ariyarathna, Thivanka; Vlahos, Penny; Tobias, Craig; Smith, Richard

2016-01-01

Examination of the partitioning of explosives onto sediment in marine environments is critical to predict the toxicological impacts of worldwide explosive-contaminated sites adjacent to estuaries, wetlands, and the coastal ocean. Marine sediments have been identified as sites of enhanced munitions removal, yet most studies addressing these interactions focus on soils and freshwater sediments. The present study measured the kinetics of 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) sorption onto 2 marine sediments of varying grain sizes (silt vs sand) and organic carbon (OC) content. Abiotic sediment sorption tests were performed at 23 °C, 15 °C, and 4 °C by spiking TNT and RDX solutions directly into anaerobic sediment slurries. Marine sediments showed significantly higher compound uptake rates (0.30-0.80 h(-1) ) than freshwater silt (0.0046-0.0065 h(-1) ) for both compounds, probably because of lower compound solubilities and a higher pH in marine systems. Equilibrium partition constants are on the same order of magnitude for marine silt (1.1-2.0 L kg(-1) sediment) and freshwater silt (1.4-3.1 L kg(-1) sediment) but lower for marine sand (0.72-0.92 L kg(-1) sediment). Total organic carbon content in marine sediments varied linearly with equilibrium partition constants for TNT and was moderately linear for RDX. Uptake rates and equilibrium constants of explosives are inversely correlated to temperature regardless of sediment type because of kinetic barriers associated with low temperatures. © 2015 SETAC.

Non-equilibrium flow and sediment transport distribution over mobile river dunes

NASA Astrophysics Data System (ADS)

Hoitink, T.; Naqshband, S.; McElroy, B. J.

2017-12-01

Flow and sediment transport are key processes in the morphodynamics of river dunes. During floods in several rivers (e.g., the Elkhorn, Missouri, Niobrara, and Rio Grande), dunes are observed to grow rapidly as flow strength increases, undergoing an unstable transition regime, after which they are washed out in what is called upper stage plane bed. This morphological evolution of dunes to upper stage plane bed is the strongest bed-form adjustment during non-equilibrium flows and is associated with a significant change in hydraulic roughness and water levels. Detailed experimental investigations, however, have mostly focused on fixed dunes limited to equilibrium flow and bed conditions that are rare in natural channels. Our understanding of the underlying sedimentary processes that result into the washing out of dunes is therefore very limited. In the present study, using the Acoustic Concentration and Velocity Profiler (ACVP), we were able to quantify flow structure and sediment transport distribution over mobile non-equilibrium dunes. Under these non-equilibrium flow conditions average dune heights were decreasing while dune lengths were increasing. Preliminary results suggest that this morphological behaviour is due to a positive phase lag between sediment transport maximum and topographic maximum leading to a larger erosion on the dune stoss side compared to deposition on dune lee side.

Flow, Sediment Supply, and Channel Width Controls on Gravel Bedform Dynamics

NASA Astrophysics Data System (ADS)

Nelson, P. A.; Morgan, J. A.

2017-12-01

Heterogeneous, coarse-grained riverbeds often self-organize into migrating bedforms such as gravel dunes or bedload sheets. It has recently been suggested that sediment supply and the relative mobility of the bed surface sediment affects the type of bedforms that may be present in gravel-bed rivers; however, our understanding of gravel bedform dynamics remains well behind that of bedforms in sandy channels. Here, we present results from flume experiments in which we investigate how the formation and dynamics of gravel bedforms is affected by changes in discharge, sediment supply, and channel geometry. Experiments were conducted in a 1.1-m wide, 18-m long, sediment-feed flume. The initial bed material and the sediment feed mixture was composed of a sediment mixture ranging in size from 0.5-4 mm, with a median value of 3.6 mm. We used two channel geometries (a straight channel and a channel with sinusoidal width variations) and conducted three experimental runs for each geometry: 1) equilibrium sediment supply and steady flow, 2) equilibrium sediment supply and repeated hydrographs, and 3) doubled sediment supply and repeated hydrographs. During the experiments, low-amplitude, migrating bedforms developed and their dynamics were tracked both visually and via collection of repeated structure-from-motion topographic datasets. In the constant-width geometry, bedform amplitudes and migration rates were relatively constant under steady flow, but when subjected to repeated hydrographs the average bedform celerity decreased by about 50% and the amplitude of the bedforms increased and decreased with the changing flow rate. At twice the equilibrium sediment supply, the bedforms organized into an alternating pattern. This pattern was most pronounced at the lower flow rates, and became less stable at the higher discharges of the repeat hydrographs. Preliminary results suggest bedform celerity in the variable width geometry under steady flow and equilibrium sediment supply was half the celerity of the bedforms for the same conditions in the straight-walled geometry. These experiments suggest that variations in discharge, sediment supply, and channel geometry play an important role in the formation and dynamics of bedforms in gravel-bed rivers.

Controls on sediment cover in bedrock-alluvial channels of the Henry Mountains, Utah

NASA Astrophysics Data System (ADS)

Hodge, R. A.; Yager, E.; Johnson, J. P.; Tranmer, A.

2017-12-01

The location and extent of sediment cover in bedrock-alluvial channels influences sediment transport rates, channel incision and instream ecology. However, factors affecting sediment cover and how it responds to changes in relative sediment supply have rarely been quantitatively evaluated in field settings. Using field surveys and SFM analysis of channel reach topography, we quantified sediment cover and channel properties including slope, width, grain size distributions, and bedrock and alluvial roughness in North Wash and Chelada Creek in the Henry Mountains, Utah. Along reaches where upstream sediment supply does not appear to be restricted, we find that the fraction of local bedrock exposure increases as a function of local relative transport capacity . In a downstream section of Chelada Creek, decadal-scale sediment supply has been restricted by an upstream culvert that has caused a backwater effect and corresponding upstream deposition. In this section, alluvial cover is uncorrelated with local stream power. To test the impact of relative sediment supply on sediment cover, a 1D sediment transport model was used to predict the equilibrium sediment cover in Chelada Creek under varying flow and sediment supply conditions. Sediment transport in each model section was predicted using the partial cover model of Johnson (2015), which accounts for differences in bedrock and alluvial roughness on critical shear stress and flow resistance. Model runs in which sediment supply was approximately equal to mean transport capacity produced a pattern of sediment cover which best matched the field observations upstream of the culvert. However, runs where sediment supply was under-capacity produced the pattern most similar to field observations downstream of the culvert, consistent with our field-based interpretations. Model results were insensitive to initial sediment cover, and equilibrium was relatively quickly reached, suggesting that the channel is responsive to changes in imposed conditions. Overall, our results suggest that alluvial cover fractions may be predictable at spatial scales relevant for landscape evolution modelling, but that local bed roughness and thresholds in relative sediment supply may need to be accounted for.

Mechanical analysis of statolith action in roots and rhizoids

NASA Astrophysics Data System (ADS)

Todd, Paul

1994-08-01

Published observations on the response times following gravistimulation (horizontal positioning) of Chara rhizoids and developing roots of vascular plants with normal and ``starchless'' amyloplasts were reviewed and compared. Statolith motion was found to be consistent with gravitational sedimentation opposed by elastic deformation of an intracellular material. The time required for a statolith to sediment to equilibrium was calculated on the basis of its buoyant density and compared with observed sedimentation times. In the examples chosen, the response time following gravistimulation (from horizontal positioning to the return of downward growth) could be related to the statolith sedimentation time. Such a relationship implies that the transduction step is rapid in comparison with the perception steo following gravistimulation of rhizoids and developing roots.

Mechanical analysis of statolith action in roots and rhizoids.

PubMed

Todd, P

1994-01-01

Published observations on the response times following gravistimulation (horizontal positioning) of Chara rhizoids and developing roots of vascular plants with normal and "starchless" amyloplasts were reviewed and compared. Statolith motion was found to be consistent with gravitational sedimentation opposed by elastic deformation of an intracellular material. The time required for a statolith to sediment to equilibrium was calculated on the basis of its buoyant density and compared with observed sedimentation times. In the examples chosen, the response time following gravistimulation (from horizontal positioning to the return of downward growth) could be related to the statolith sedimentation time. Such a relationship implies that the transduction step is rapid in comparison with the perception step following gravistimulation of rhizoids and developing roots.

SEDFIT-MSTAR: Molecular weight and molecular weight distribution analysis of polymers by sedimentation equilibrium in the ultracentrifuge

PubMed Central

Schuck, Peter; Gillis, Richard B.; Besong, Tabot M.D.; Almutairi, Fahad; Adams, Gary G.; Rowe, Arthur J.; Harding, Stephen E.

2014-01-01

Sedimentation equilibrium (analytical ultracentrifugation) is one of the most inherently suitable methods for the determination of average molecular weights and molecular weight distributions of polymers, because of its absolute basis (no conformation assumptions) and inherent fractionation ability (without the need for columns or membranes and associated assumptions over inertness). With modern instrumentation it is also possible to run up to 21 samples simultaneously in a single run. Its application has been severely hampered because of difficulties in terms of baseline determination (incorporating estimation of the concentration at the air/solution meniscus) and complexity of the analysis procedures. We describe a new method for baseline determination based on a smart-smoothing principle and built into the highly popular platform SEDFIT for the analysis of the sedimentation behavior of natural and synthetic polymer materials. The SEDFIT-MSTAR procedure – which takes only a few minutes to perform - is tested with four synthetic data sets (including a significantly non-ideal system) a naturally occurring protein (human IgG1) and two naturally occurring carbohydrate polymers (pullulan and λ–carrageenan) in terms of (i) weight average molecular weight for the whole distribution of species in the sample (ii) the variation in “point” average molecular weight with local concentration in the ultracentrifuge cell and (iii) molecular weight distribution. PMID:24244936

Primary sources and toxicity of PAHs in Milwaukee-area streambed sediment

USGS Publications Warehouse

Baldwin, Austin K.; Corsi, Steven R.; Lutz, Michelle A.; Ingersoll, Christopher G.; Dorman, Rebecca A.; Magruder, Christopher; Magruder, Matthew

2017-01-01

High concentrations of polycyclic aromatic hydrocarbons (PAHs) in streams can be a significant stressor to aquatic organisms. To understand the likely sources and toxicity of PAHs in Milwaukee-area streams, streambed sediment samples from 40 sites and parking lot dust samples from 6 sites were analyzed for 38 parent PAHs and 25 alkylated PAHs. Diagnostic ratios, profile correlations, principal components analysis, source-receptor modeling, and mass fractions analysis were used to identify potential PAH sources to streambed sediment samples, and land-use analysis was used to relate streambed sediment PAH concentrations to different urban-related land uses. On the basis of this multiple lines-of-evidence approach, coal-tar pavement sealant was indicated as the primary source of PAHs in a majority of streambed sediment samples, contributing an estimated 77% of total PAHs to samples, on average. Comparison to the Probable Effect Concentrations and (or) the Equilibrium Partitioning Sediment Benchmark indicates that 78% of stream sediment samples are likely to cause adverse effects to benthic organisms. Laboratory toxicity tests on a 16-sample subset of the streambed sites using the amphipod Hyalella azteca (28-day) and the midge Chironomus dilutus (10-day) measured significant reductions in one or more biological endpoints, including survival, in 75% of samples, with H. azteca more responsive than C. dilutus.

Understanding bioavailability and toxicity of sediment-associated contaminants by combining passive sampling with in vitro bioassays in an urban river catchment.

PubMed

Li, Juan-Ying; Tang, Janet Yat Man; Jin, Ling; Escher, Beate I

2013-12-01

Bioavailable and bioaccessible fractions of sediment-associated contaminants are considered as better dose metrics for sediment-quality assessment than total concentrations. The authors applied exhaustive solvent extraction and nondepletive equilibrium sampling techniques to sediment samples collected along the Brisbane River in South East Queensland, Australia, which range from pristine environments to urban and industry-impacted areas. The wide range of chemicals expected prevents comprehensive chemical analysis, but a battery of cell-based bioassays sheds light on mixture effects of chemicals in relation to various modes of toxic action. Toxic effects were expressed as bioanalytical equivalent concentrations (BEQs) normalized to the organic carbon content of each sediment sample. Bioanalytical equivalent concentrations from exhaustive extraction agreed fairly well with values estimated from polydimethylsiloxane passive sampling extracts via the constant organic carbon to polydimethylsiloxane partition coefficient. Agreement was best for bioassays indicative of photosynthesis inhibition and oxidative stress response and discrepancy within a factor of 3 for the induction of the aryl hydrocarbon receptor. For nonspecific cytotoxicity, BEQ from exhaustive extraction were 1 order of magnitude higher than values from equilibrium sampling, possibly because of coextraction of bioactive natural organic matter that led to an overestimation of toxicity in the exhaustive extracts, which suggests that passive sampling is better suited in combination with bioanalytical assessment than exhaustive extraction. © 2013 SETAC.

Protein associations and analytical ultracentrifugation

NASA Astrophysics Data System (ADS)

Laue, Tom

2010-03-01

Analytical ultracentrifugation (AUC) is a first principle method for characterizing the thermodynamics of macromolecules in solution. Since AUC directly assesses mass, it is particularly useful for characterizing both reversible and irreversible binding interactions between macromolecules. The principle measurement in AUC is the concentration as a function of radial position, which may be provided by either absorbance, interference or fluorescence detection. Each of these three different detectors may be used to characterize protein associations using either sedimentation equilibrium or sedimentation velocity analysis. Examples will be shown for characterizing irreversible (aggregate) formation, high-accuracy reversible association analysis, and the detection of protein interactions in complex and concentrated fluids (e.g. serum, cell cytosol).

Chemical and physical properties affecting strontium distribution coefficients of surficial-sediment samples at the Idaho National Engineering and Environmental Laboratory, Idaho

USGS Publications Warehouse

Liszewski, M.J.; Rosentreter, J.J.; Miller, Karl E.; Bartholomay, R.C.

2000-01-01

The U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy, conducted a study to determine strontium distribution coefficients (K(d)s) of surficial sediments at the Idaho National Engineering and Environmental Laboratory (INEEL). Batch experiments using synthesized aqueous solutions were used to determine K(d)s, which describe the distribution of a solute between the solution and solid phase, of 20 surficial-sediment samples from the INEEL. The K(d)s for the 20 surficial-sediment samples ranged from 36 to 275 ml/g. Many properties of both the synthesized aqueous solutions and sediments used in the experiments also were determined. Solution properties determined were initial and equilibrium concentrations of calcium, magnesium, and strontium, pH and specific conductance, and initial concentrations of potassium and sodium. Sediment properties determined were grain-size distribution, bulk mineralogy, whole-rock major-oxide and strontium and barium concentrations, and Brunauer-Emmett-Teller (BET) surface area. Solution and sediment properties were correlated with strontium K(d)s of the 20 surficial sediments using Pearson correlation coefficients. Solution properties with the strongest correlations with strontium K(d)s were equilibrium pH and equilibrium calcium concentration correlation coefficients, 0.6598 and -0.6518, respectively. Sediment properties with the strongest correlations with strontium K(d)s were manganese oxide (MnO), BET surface area, and the >4.75-mm-grain-size fraction correlation coefficients, 0.7054, 0.7022, and -0.6660, respectively. Effects of solution properties on strontium K(d)s were interpreted as being due to competition among similarly charged and sized cations in solution for strontium-sorption sites; effects of sediment properties on strontium K(d)s were interpreted as being surface-area related. Multivariate analyses of these solution and sediment properties resulted in r2 values of 0.8071 when all five properties were used and 0.8043 when three properties, equilibrium pH, MnO, and BET surface area, were used.

Mechanistic Sediment Quality Guidelines Based on Contaminant Bioavailability: Equilibrium Partitioning Sediment Benchmarks

EPA Science Inventory

Globally, billions of metric tons of contaminated sediments are present in aquatic systems representing a potentially significant ecological risk. Estimated costs to manage (i.e., remediate and monitor) these sediments are in the billions of U.S. dollars. Biologically-based app...

Bioavailability Assessment of a Contaminated Field Sediemtn from Patrick Bayou, Texas: TIE and Equilibrium Partitioning

EPA Science Inventory

Contaminated sediments are commonly found in urbanized harbors. Remediation is often necessary and diagnosing the cause of sediment toxicity becomes imperative. In the present study, sediments from Patrick Bayou, Texas were subjected to initial toxicity testing. All sediments ...

Molecular weight of Escherichia coli β-galactosidase in concentrated solutions of guanidine hydrochloride

PubMed Central

Erickson, Robert P.

1970-01-01

The molecular weight of Escherichia coli β-galactosidase was determined in 6m- and 8m-guanidine hydrochloride by meniscus-depletion sedimentation equilibrium, sedimentation velocity and viscosity. Sedimentation equilibrium revealed heterogeneity with the smallest component having a molecular weight of about 50000. At lower speeds, the apparent weight-average molecular weight is about 80000. By use of a calculation based on an empirical correlation for proteins that are random coils in 6m-guanidine hydrochloride, sedimentation velocity gave a molecular weight of 91000, and the intrinsic viscosity indicated a viscosity-average molecular weight of 84000. Heating in 6m-guanidine hydrochloride lowered the viscosity of β-galactosidase in a variable manner. PMID:4924171

Is Equilibrium Floc Size a Function of Concentration?

NASA Astrophysics Data System (ADS)

Tran, D. A.; Strom, K.

2014-12-01

Flocculation is the process in which cohesive sediments amalgamate to form larger aggregates or flocs. The two factors that strongly influence the flocculation of mud are the turbulent shear rate and the suspended sediment concentration. Increases in turbulent shear rate are known to decrease the time to equilibrium and limit floc size. Increases in concentration are typically thought to decrease the time to equilibrium and increase the final equilibrium floc size. In this laboratory study, the effect of concentration on the growth rate and equilibrium size of flocs is systematically investigated. A camera system and image processing program were used to observe and analyze the evolution of flocs created by of a mixture of 80% kaolinite and 20% montmorillonite clay at six different concentrations (25, 50, 100, 200, 300 and 400 mg/L). Each mixture was first sonicated for 15 minutes before being introduced to a tank of tap water being mixed at an turbulent shear rate of G = 58 s-1. Flocs were then allowed to grow for two hours. During the following hour, a much higher shear rate of G = 1200 s-1 was applied to break the flocs. The shear rate was then reduced back to and maintained at G = 58 s-1 for another six hours. Running the experiments in this way allowed for the observation of floc growth from two different initial particle states at each concentration, resulting in a total of 12 floc growth experiments. The primary conclusions from this set of experiments are: (1) higher suspended sediment concentration is correlated with a higher rate of floc growth, and (2) at equilibrium, the average floc size stabilizes at ≈ 100 µm independent of the initial particle state or the suspended sediment concentration. Therefor, for the sediment mixture tested, the results imply that the effect of concentration on flocculation was restricted to the floc growth rate. This is contrary to what would be predicted using typical mud settling velocity equations.

An Arabidopsis E3 Ligase, SHOOT GRAVITROPISM9, Modulates the Interaction between Statoliths and F-Actin in Gravity Sensing[W][OA

PubMed Central

Nakamura, Moritaka; Toyota, Masatsugu; Tasaka, Masao; Morita, Miyo Terao

2011-01-01

Higher plants use the sedimentation of amyloplasts in statocytes as statolith to sense the direction of gravity during gravitropism. In Arabidopsis thaliana inflorescence stem statocyte, amyloplasts are in complex movement; some show jumping-like saltatory movement and some tend to sediment toward the gravity direction. Here, we report that a RING-type E3 ligase SHOOT GRAVITROPISM9 (SGR9) localized to amyloplasts modulates amyloplast dynamics. In the sgr9 mutant, which exhibits reduced gravitropism, amyloplasts did not sediment but exhibited increased saltatory movement. Amyloplasts sometimes formed a cluster that is abnormally entangled with actin filaments (AFs) in sgr9. By contrast, in the fiz1 mutant, an ACT8 semidominant mutant that induces fragmentation of AFs, amyloplasts, lost saltatory movement and sedimented with nearly statically. Both treatment with Latrunculin B, an inhibitor of AF polymerization, and the fiz1 mutation rescued the gravitropic defect of sgr9. In addition, fiz1 decreased saltatory movement and induced amyloplast sedimentation even in sgr9. Our results suggest that amyloplasts are in equilibrium between sedimentation and saltatory movement in wild-type endodermal cells. Furthermore, this equilibrium is the result of the interaction between amyloplasts and AFs modulated by the SGR9. SGR9 may promote detachment of amyloplasts from AFs, allowing the amyloplasts to sediment in the AFs-dependent equilibrium of amyloplast dynamics. PMID:21602290

Comparison of Methods for Characterizing Nonideal Solute Self-Association by Sedimentation Equilibrium

PubMed Central

Scott, David J.; Winzor, Donald J.

2009-01-01

Abstract We have examined in detail analytical solutions of expressions for sedimentation equilibrium in the analytical ultracentrifuge to describe self-association under nonideal conditions. We find that those containing the radial dependence of total solute concentration that incorporate the Adams-Fujita assumption for composition-dependence of activity coefficients reveal potential shortcomings for characterizing such systems. Similar deficiencies are shown in the use of the NONLIN software incorporating the same assumption about the interrelationship between activity coefficients for monomer and polymer species. These difficulties can be overcome by iterative analyses incorporating expressions for the composition-dependence of activity coefficients predicted by excluded volume considerations. A recommendation is therefore made for the replacement of current software packages by programs that incorporate rigorous statistical-mechanical allowance for thermodynamic nonideality in sedimentation equilibrium distributions reflecting solute self-association. PMID:19651047

Bioavailability Assessment of a Contaminated Field Sediment from Patrick Bayou, Texas, USA: Toxicity Identification Evaluation and Equilibrium Partitioning

EPA Science Inventory

Contaminated sediments are commonly found in urbanized harbors. At sufficiently high contaminant levels, sediments can cause toxicity to aquatic organisms and impair benthic communities. As a result, remediation is necessary and diagnosing the cause of sediment toxicity become...

Effect of sediment transport boundary conditions on the numerical modeling of bed morphodynamics

USDA-ARS?s Scientific Manuscript database

Experimental sediment transport studies in laboratory flumes can use two sediment-supply methods: an imposed feed at the upstream end or recirculation of sediment from the downstream end to the upstream end. These methods generally produce similar equilibrium bed morphology, but temporal evolution c...

Morphodynamic Modeling of the Lower Yellow River, China: Flux (Equilibrium) Form or Entrainment (Nonequilibrium) Form of Sediment Mass Conservation?

NASA Astrophysics Data System (ADS)

An, C.; Parker, G.; Ma, H.; Naito, K.; Moodie, A. J.; Fu, X.

2017-12-01

Models of river morphodynamics consist of three elements: (1) a treatment of flow hydraulics, (2) a formulation relating some aspect of sediment transport to flow hydraulics, and (3) a description of sediment conservation. In the case of unidirectional river flow, the Exner equation of sediment conservation is commonly described in terms of a flux-based formulation, in which bed elevation variation is related to the streamwise gradient of sediment transport rate. An alternate formulation of the Exner equation, however, is the entrainment-based formulation in which bed elevation variation is related to the difference between the entrainment rate of bed sediment into suspension and the deposition rate of suspended sediment onto the bed. In the flux-based formulation, sediment transport is regarded to be in a local equilibrium state (i.e., sediment transport rate locally equals sediment transport capacity). However, the entrainment-based formulation does not require this constraint; the sediment transport rate may lag in space and time behind the changing flow conditions. In modeling the fine-grained Lower Yellow River, it is usual to treat sediment conservation in terms of an entrainment-based (nonequilibrium) rather than a flux-based (equilibrium) formulation with the consideration that fine-grained sediment may be entrained at one place but deposited only at some distant location downstream. However, the differences in prediction between the two formulations are still not well known, and the entrainment formulation may not always be necessary for the Lower Yellow River. Here we study this problem by comparing the results of flux-based and entrainment-based morphodynamics under conditions typical of the Yellow River, using sediment transport equations specifically designed for the Lower Yellow River. We find, somewhat unexpectedly, that in a treatment of a 200-km reach using uniform sediment, there is little difference between the two formulations unless the sediment fall velocity is arbitrarily greatly reduced. A consideration of sediment mixtures, however, shows that the two formulations give very different patterns of grain sorting. We explain this in terms of the structures of the two Exner equations for sediment mixtures, and define conditions for applicability of each formulation.

DNA from lake sediments reveals long-term ecosystem changes after a biological invasion.

PubMed

Ficetola, Gentile Francesco; Poulenard, Jérôme; Sabatier, Pierre; Messager, Erwan; Gielly, Ludovic; Leloup, Anouk; Etienne, David; Bakke, Jostein; Malet, Emmanuel; Fanget, Bernard; Støren, Eivind; Reyss, Jean-Louis; Taberlet, Pierre; Arnaud, Fabien

2018-05-01

What are the long-term consequences of invasive species? After invasion, how long do ecosystems require to reach a new equilibrium? Answering these questions requires long-term, high-resolution data that are vanishingly rare. We combined the analysis of environmental DNA extracted from a lake sediment core, coprophilous fungi, and sedimentological analyses to reconstruct 600 years of ecosystem dynamics on a sub-Antarctic island and to identify the impact of invasive rabbits. Plant communities remained stable from AD 1400 until the 1940s, when the DNA of invasive rabbits was detected in sediments. Rabbit detection corresponded to abrupt changes of plant communities, with a continuous decline of a dominant plant species. Furthermore, erosion rate abruptly increased with rabbit abundance. Rabbit impacts were very fast and were stronger than the effects of climate change during the 20th century. Lake sediments can allow an integrated temporal analysis of ecosystems, revealing the impact of invasive species over time and improving our understanding of underlying mechanisms.

Development and evaluation of consensus-based sediment effect concentrations for polychlorinated biphenyls

USGS Publications Warehouse

MacDonald, Donald D.; Dipinto, Lisa M.; Field, Jay; Ingersoll, Christopher G.; Long, Edward R.; Swartz, Richard C.

2000-01-01

Sediment-quality guidelines (SQGs) have been published for polychlorinated biphenyls (PCBs) using both empirical and theoretical approaches. Empirically based guidelines have been developed using the screening-level concentration, effects range, effects level, and apparent effects threshold approaches. Theoretically based guidelines have been developed using the equilibrium-partitioning approach. Empirically-based guidelines were classified into three general categories, in accordance with their original narrative intents, and used to develop three consensus-based sediment effect concentrations (SECs) for total PCBs (tPCBs), including a threshold effect concentration, a midrange effect concentration, and an extreme effect concentration. Consensus-based SECs were derived because they estimate the central tendency of the published SQGs and, thus, reconcile the guidance values that have been derived using various approaches. Initially, consensus-based SECs for tPCBs were developed separately for freshwater sediments and for marine and estuarine sediments. Because the respective SECs were statistically similar, the underlying SQGs were subsequently merged and used to formulate more generally applicable SECs. The three consensus-based SECs were then evaluated for reliability using matching sediment chemistry and toxicity data from field studies, dose-response data from spiked-sediment toxicity tests, and SQGs derived from the equilibrium-partitioning approach. The results of this evaluation demonstrated that the consensus-based SECs can accurately predict both the presence and absence of toxicity in field-collected sediments. Importantly, the incidence of toxicity increases incrementally with increasing concentrations of tPCBs. Moreover, the consensus-based SECs are comparable to the chronic toxicity thresholds that have been estimated from dose-response data and equilibrium-partitioning models. Therefore, consensus-based SECs provide a unifying synthesis of existing SQGs, reflect causal rather than correlative effects, and accurately predict sediment toxicity in PCB-contaminated sediments.

Experimental and theoretical investigation of the role of clay in subaqueous sediment flows and its effect on run-out distance

NASA Astrophysics Data System (ADS)

Hermidas, Navid; Luthi, Stefan; Eggenhuisen, Joris; Silva Jacinto, Ricardo; Toth, Ferenc; Pohl, Florian; de Leeuw, Jan

2016-04-01

Debris flows are driven by gravity, which in the tail region is overcome by the yield strength of the flow, forcing it to freeze. These flows are capable of achieving staggeringly large run-out distances on low gradients. The case in point, described in previous publications, is the flow which resulted in the deposit of Bed 5 of the Agadir megaslide on the north-west African margin. Debrites of this flow have been recorded several hundred kilometres away from the original landslide. Previous studies have attributed such long run-out distances to hydroplaning, low yield strength, and flow transformation. It is known that the net force acting on a volume of fluid in equilibrium is zero. In this work we show that clay-laden flows are capable of approaching equilibrium. The flows which can achieve the maximum run-out distance are cohesive enough to resist some of the surrounding disturbances, that can upset the equilibrium, and reach close to equilibrium conditions, yet are dilute enough to have low viscous stress, and relatively low yield strength and lose little sediment due to deposition. A flow that is not in equilibrium will always seek to approach equilibrium conditions by speeding up or slowing down, depositing sediment, eroding the substrate, contracting in the form of the tail approaching the head, stretching, entraining water and growing in height, or dewatering and collapsing. Here we present a theory that shows that two dimensional (2D) flows in equilibrium do not grow in height. 2D flume experiments were conducted on different mixtures of kaolinite, sand, silt, and water, on varying slopes and a transitionally rough bed (sand glued), and using various discharge rates, in order to map out different stages in the evolution of a density flow from a cohesive plug flow into a turbidity current. The following flow types were observed: high density turbidity currents, plug flows, and no flow. From the velocity profiles, certain runs demonstrated close to equilibrium behaviour. For these flows, very little flow height growth and velocity variation was observed over the length of the flume. In all cases the flow appeared to be laminar within the boundary layer with Kelvin-Helmholtz instabilities at the top which were suppressed to a large extent for higher sediment concentrations. A deposit consisting of thick muddy sand, with approximately uniform thickness, was observed for higher sediment concentrations, indicating relatively higher yield strength values, while a thinner more sandy deposit was observed for more dilute flows. It was concluded that high sediment concentrations on more moderate slopes result in slower moving plug flows which are capable of suppressing turbulence at the top, while lower sediment concentrations on steeper slopes result in faster moving, more turbulent currents. The flows which can achieve the largest run-out distance are located between these two extremes.

Passive sampling methods for contaminated sediments: Scientific rationale supporting use of freely dissolved concentrations

PubMed Central

Mayer, Philipp; Parkerton, Thomas F; Adams, Rachel G; Cargill, John G; Gan, Jay; Gouin, Todd; Gschwend, Philip M; Hawthorne, Steven B; Helm, Paul; Witt, Gesine; You, Jing; Escher, Beate I

2014-01-01

Passive sampling methods (PSMs) allow the quantification of the freely dissolved concentration (Cfree) of an organic contaminant even in complex matrices such as sediments. Cfree is directly related to a contaminant's chemical activity, which drives spontaneous processes including diffusive uptake into benthic organisms and exchange with the overlying water column. Consequently, Cfree provides a more relevant dose metric than total sediment concentration. Recent developments in PSMs have significantly improved our ability to reliably measure even very low levels of Cfree. Application of PSMs in sediments is preferably conducted in the equilibrium regime, where freely dissolved concentrations in the sediment are well-linked to the measured concentration in the sampler via analyte-specific partition ratios. The equilibrium condition can then be assured by measuring a time series or a single time point using passive samplers with different surface to volume ratios. Sampling in the kinetic regime is also possible and generally involves the application of performance reference compounds for the calibration. Based on previous research on hydrophobic organic contaminants, it is concluded that Cfree allows a direct assessment of 1) contaminant exchange and equilibrium status between sediment and overlying water, 2) benthic bioaccumulation, and 3) potential toxicity to benthic organisms. Thus, the use of PSMs to measure Cfree provides an improved basis for the mechanistic understanding of fate and transport processes in sediments and has the potential to significantly improve risk assessment and management of contaminated sediments. Integr Environ Assess Manag 2014;10:197–209. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. PMID:24288295

Heavy metals relationship with water and size-fractionated sediments in rivers using canonical correlation analysis (CCA) case study, rivers of south western Caspian Sea.

PubMed

Vosoogh, Ali; Saeedi, Mohsen; Lak, Raziyeh

2016-11-01

Some pollutants can qualitatively affect aquatic freshwater such as rivers, and heavy metals are one of the most important pollutants in aquatic fresh waters. Heavy metals can be found in the form of components dissolved in these waters or in compounds with suspended particles and surface sediments. It can be said that heavy metals are in equilibrium between water and sediment. In this study, the amount of heavy metals is determined in water and different sizes of sediment. To obtain the relationship between heavy metals in water and size-fractionated sediments, a canonical correlation analysis (CCA) was utilized in rivers of the southwestern Caspian Sea. In this research, a case study was carried out on 18 sampling stations in nine rivers. In the first step, the concentrations of heavy metals (Cu, Zn, Cr, Fe, Mn, Pb, Ni, and Cd) were determined in water and size-fractionated sediment samples. Water sampling sites were classified by hierarchical cluster analysis (HCA) utilizing squared Euclidean distance with Ward's method. In addition, for interpreting the obtained results and the relationships between the concentration of heavy metals in the tested river water and sample sediments, canonical correlation analysis (CCA) was utilized. The rivers were grouped into two classes (those having no pollution and those having low pollution) based on the HCA results obtained for river water samples. CCA results found numerous relationships between rivers in Iran's Guilan province and their size-fractionated sediments samples. The heavy metals of sediments with 0.038 to 0.125 mm size in diameter are slightly correlated with those of water samples.

Equilibrium Partitioning: What's it Good for and How do you Know if it Works?

EPA Science Inventory

Much has been written about the use of equilibrium partitioning (EqP) as an approach for deriving sediment quality guidelines, and about whether guidelines so derived “work.” The purpose of this presentation is to discuss issues relevant to judging whether equilibrium partitioni...

Mechanisms linking sediment supply and bar morphology: Results from a straight flume with alternate bars

NASA Astrophysics Data System (ADS)

Braudrick, C. A.; Minear, J. T.; Dietrich, W. E.; Dehart, M.; Sklar, L. S.

2008-12-01

One of the largest uncertainties in routing sediment through drainage networks is predicting the degree to which changes in sediment supply are mitigated by changes in sediment storage in bars. We hypothesize that changes in topographic steering link sediment supply and bar morphology. This hypothesis posits that increased sediment supply would enhance topographic steering over the bar, causing the bar to advance laterally into the pool. Contrarily, decreased supply would diminish topographic steering, causing bars to shrink laterally and pools to expand. We examined this hypothesis in a 28-m long, 0.86-m wide flume with a constant discharge of 5.4 l/s and sand with a median grain size of 0.8 mm. The conditions were sufficient to support alternate bars downstream of the upper 8-10 m, and the flume was run for approximately 65 hours at a constant discharge and sediment feed. The equilibrium slope was 0.0033. Once the channel reached equilibrium, the sediment feed was turned off while the discharge was held constant. During the first 25 hours after the feed was stopped, the sediment transport rate at the downstream end of the flume increased from 9.8 to 10.5 kg/hr as sediment was provided by incision at the upstream end of the flume. Because the bed was the only sediment source, sediment supply increased with distance down the flume. Once the feed was shut off, bar response differed between the upstream and downstream portions of the flume. Bars at the downstream end of the flume, where sediment supply increased relative to equilibrium conditions, swelled into the pool. These changes in bar morphology were accompanied by a decrease in surface grain size. Further upstream, where sediment supply was lower, the bars shrunk. These results suggest that there may be a linkage between topographic steering, bar morphology, and sediment supply, but further numerical tests and experimental manipulations are necessary to verify this linkage and to account for the effect of the decreased surface grain size of the bars.

Trimeric transmembrane domain interactions in paramyxovirus fusion proteins: roles in protein folding, stability, and function.

PubMed

Smith, Everett Clinton; Smith, Stacy E; Carter, James R; Webb, Stacy R; Gibson, Kathleen M; Hellman, Lance M; Fried, Michael G; Dutch, Rebecca Ellis

2013-12-13

Paramyxovirus fusion (F) proteins promote membrane fusion between the viral envelope and host cell membranes, a critical early step in viral infection. Although mutational analyses have indicated that transmembrane (TM) domain residues can affect folding or function of viral fusion proteins, direct analysis of TM-TM interactions has proved challenging. To directly assess TM interactions, the oligomeric state of purified chimeric proteins containing the Staphylococcal nuclease (SN) protein linked to the TM segments from three paramyxovirus F proteins was analyzed by sedimentation equilibrium analysis in detergent and buffer conditions that allowed density matching. A monomer-trimer equilibrium best fit was found for all three SN-TM constructs tested, and similar fits were obtained with peptides corresponding to just the TM region of two different paramyxovirus F proteins. These findings demonstrate for the first time that class I viral fusion protein TM domains can self-associate as trimeric complexes in the absence of the rest of the protein. Glycine residues have been implicated in TM helix interactions, so the effect of mutations at Hendra F Gly-508 was assessed in the context of the whole F protein. Mutations G508I or G508L resulted in decreased cell surface expression of the fusogenic form, consistent with decreased stability of the prefusion form of the protein. Sedimentation equilibrium analysis of TM domains containing these mutations gave higher relative association constants, suggesting altered TM-TM interactions. Overall, these results suggest that trimeric TM interactions are important driving forces for protein folding, stability and membrane fusion promotion.

Trimeric Transmembrane Domain Interactions in Paramyxovirus Fusion Proteins

PubMed Central

Smith, Everett Clinton; Smith, Stacy E.; Carter, James R.; Webb, Stacy R.; Gibson, Kathleen M.; Hellman, Lance M.; Fried, Michael G.; Dutch, Rebecca Ellis

2013-01-01

Paramyxovirus fusion (F) proteins promote membrane fusion between the viral envelope and host cell membranes, a critical early step in viral infection. Although mutational analyses have indicated that transmembrane (TM) domain residues can affect folding or function of viral fusion proteins, direct analysis of TM-TM interactions has proved challenging. To directly assess TM interactions, the oligomeric state of purified chimeric proteins containing the Staphylococcal nuclease (SN) protein linked to the TM segments from three paramyxovirus F proteins was analyzed by sedimentation equilibrium analysis in detergent and buffer conditions that allowed density matching. A monomer-trimer equilibrium best fit was found for all three SN-TM constructs tested, and similar fits were obtained with peptides corresponding to just the TM region of two different paramyxovirus F proteins. These findings demonstrate for the first time that class I viral fusion protein TM domains can self-associate as trimeric complexes in the absence of the rest of the protein. Glycine residues have been implicated in TM helix interactions, so the effect of mutations at Hendra F Gly-508 was assessed in the context of the whole F protein. Mutations G508I or G508L resulted in decreased cell surface expression of the fusogenic form, consistent with decreased stability of the prefusion form of the protein. Sedimentation equilibrium analysis of TM domains containing these mutations gave higher relative association constants, suggesting altered TM-TM interactions. Overall, these results suggest that trimeric TM interactions are important driving forces for protein folding, stability and membrane fusion promotion. PMID:24178297

Control of Sediment Availability on the Path of Channel Recovery in Bedload-Dominated Rivers

NASA Astrophysics Data System (ADS)

Doyle, H.; Renshaw, C. E.; Magilligan, F. J.

2015-12-01

Following a disturbance, a channel can recover to an equilibrium form by adjusting its slope, width, depth, grain size, or some combination of these dimensions that define the recovery path. In this study we relate the channel recovery path to the quantity and caliber of sediment introduced due to dam construction/removal or erosion caused by flooding. We suggest that the recovery path of a channel depends on the availability of sediment of a size that is transported as bedload during bankfull flows (the "mobile fraction"). We define a ratio, S*, of the sediment volume added to the channel because of the disturbance to the average annual sediment flux. We compare S* values to the recovery path of New England gravel-bedded streams following two dam emplacements and removals and flooding related to Tropical Storm Irene. Pelham Dam in Pelham, MA (removed 2012) and Kendrick Dam in Pittsford, VT (removed 2014) were on similar streams: drainage areas ~25 km2, slopes 1-2%, and bankfull widths ~10 m. Sediment was excavated from both impoundments prior to removal, resulting in lower S* values. Irene-affected study sites are on ~10 gravel-bedded streams in VT, NH, and MA. Sediment input at these sites is due to bank failures and landslides, many of which continue to supply sediment to the channel four years after flooding. To track recovery we collected annual topographic and sediment size data and calculated Shields numbers to determine if channels had reached an equilibrium form. We define equilibrium for bedload rivers as Shields numbers at bankfull discharge equal to that required to initiate bedload transport. Following dam emplacements the channels failed to recover because mobile sediment was unavailable. Fining dominated the recovery at Irene-affected sites (~10% reduction in sediment size) and dam removal sites (up to 30-60% reduction) with little post-disturbance change in channel geometry, possibly due to the limited mobile fraction.

Disturbances to metal partitioning during toxicity testing of iron(II)-rich estuarine pore waters and whole sediments.

PubMed

Simpson, Stuart L; Batley, Graeme E

2003-02-01

Metal partitioning is altered when suboxic estuarine sediments containing Fe(II)-rich pore waters are disturbed during collection, preparation, and toxicity testing. Experiments with model Fe(II)-rich pore waters demonstrated the rates at which adsorptive losses of Cd, Cu, Ni, Mn, Pb, and Zn occur upon exposure to air. Experiments with Zn-contaminated estuarine sediments demonstrated large and often unpredictable changes to metal partitioning during sediment storage, removal of organisms, and homogenization before testing. Small modifications to conditions, such as aeration of overlying waters, caused large changes to the metal partitioning. Disturbances caused by sediment collection required many weeks for reestablishment of equilibrium. Bioturbation by benthic organisms led to oxidation of pore-water Fe(II) and lower Zn fluxes because of the formation of Fe hydroxide precipitates that adsorb pore-water Zn. For five weeks after the addition of organisms to sediments, Zn fluxes increased slowly as the organisms established themselves in the sediments, indicating that the establishment of equilibrium was not rapid. The results are discussed in terms of the dynamic nature of suboxic, Fe(II)-rich estuarine sediments, how organisms perturb their environment, and the importance of understanding chemistry in toxicity testing with whole sediments or pore water. Recommendations are provided for the handling of sediments for toxicity testing.

Distribution of atrazine and its phytoremediation by submerged macrophytes in lake sediments.

PubMed

Qu, Mengjie; Li, Huidong; Li, Na; Liu, Guanglong; Zhao, Jianwei; Hua, Yumei; Zhu, Duanwei

2017-02-01

We investigated sediments with high atrazine accumulation capability from 6 eutrophic lakes in Hubei Province of central China. Almost all lakes have atrazine in their sediments because of human activities. Honghu Lake and Liangzihu Lake were found to have higher levels of atrazine in sediment: 0.171 and 0.114 mg kg -1 , respectively. The results showed that lake sediments could adsorb atrazine six times faster than soils. The equilibrium partition coefficient of atrazine desorption (K Pd ) is much larger than the adsorption equilibrium partition coefficient (K Pa ) of atrazine, indicating that the residue of atrazine in water is easily immobilized by the sediments. Meanwhile, the incubation experiment showed that the removal rateof atrazine in Potamogeton crispus-planted and Myriophyllum spicatum-planted sediments reached >90%, while the rate in unplanted sediments was 77.2 ± 2.12% over 45 d. In unplanted sediment, the half-life of atrazine dissipation was 14.30 d, which was strongly enhanced by P. crispus and M. spicatum, greatly reducing the half-life to 8.60 and 9.72 d, respectively. These two submerged macrophytes are considered to be potential tools in the remediation of atrazine-contaminated sediments. Copyright © 2016 Elsevier Ltd. All rights reserved.

Assessing bioavailability of DDT and metabolites in marine sediments using solid-phase microextraction with performance reference compounds.

PubMed

Bao, Lian-Jun; Jia, Fang; Crago, J; Zeng, Eddy Y; Schlenk, D; Gan, Jay

2013-09-01

Solid-phase microextraction (SPME) has often been used to estimate the freely dissolved concentration (Cfree ) of organic contaminants in sediments. A significant limitation in the application of SPME for Cfree measurement is the requirement for attaining equilibrium partition, which is often difficult for strongly hydrophobic compounds such as DDT. A method was developed using SPME with stable isotope-labeled analogues as performance reference compounds (PRCs) to measure Cfree of DDT and metabolites (DDTs) in marine sediments. Six (13) C-labeled or deuterated PRCs were impregnated into polydimethylsiloxane (PDMS) fiber before use. Desorption of PRCs from PDMS fibers and absorption of DDTs from sediment were isotropic in a range of sediments evaluated ex situ under well-mixed conditions. When applied to a historically contaminated marine sediment from a Superfund site, the PRC-SPME method yielded Cfree values identical to those found by using a conventional equilibrium SPME approach (Eq-SPME), whereas the time for mixing was reduced from 9 d to only 9 h. The PRC-SPME method was further evaluated against bioaccumulation of DDTs by Neanthes arenaceodentata in the contaminated sediment with or without amendment of activated carbon or sand. Strong correlations were consistently found between the derived equilibrium concentrations on the fiber and lipid-normalized tissue residues for DDTs in the worms. Results from the present study clearly demonstrated the feasibility of coupling PRCs with SPME sampling to greatly shorten sampling time, thus affording much improved flexibility in the use of SPME for bioavailability evaluation. Copyright © 2013 SETAC.

Assessing Bioavailability of DDT and Metabolites in Marine Sediments using Solid-Phase Microextraction with Performance Reference Compounds

PubMed Central

Bao, Lian-Jun; Jia, Fang; Crago, J.; Zeng, Eddy Y.; Schlenk, D.; Gan, Jay

2014-01-01

Solid-phase microextraction (SPME) has often been used to estimate the freely dissolved concentration (Cfree) of organic contaminants in sediments. A significant limitation in the application of SPME for Cfree measurement is the requirement for attaining equilibrium partition, which is often difficult for strongly hydrophobic compounds such as DDT. A method was developed using SPME with stable isotope-labeled analogues as performance reference compounds (PRCs) to measure Cfree of DDT and metabolites (DDTs) in marine sediments. Six 13C-labeled or deuterated PRCs were impregnated into polydimethylsiloxane (PDMS) fiber before use. Desorption of PRCs from PDMS fibers and absorption of DDTs from sediment were isotropic in a range of sediments evaluated ex situ under well-mixed conditions. When applied to a historically contaminated marine sediment from a Superfund site, the PRC-SPME method yielded Cfree values identical to those found by using a conventional equilibrium SPME approach (Eq-SPME), wherease the time for mixing was reduced from 9 d to only 9 h. The PRC-SPME method was further evaluated against bioaccumulation of DDTs by Neanthes arenaceodentata in the contaminated sediment with or without amendment of activated carbon or sand. Strong correlations were consistently found between the derived equilibrium concentrations on the fiber and lipid-normalized tissue residues for DDTs in the worms. Results from the present study clearly demonstrated the feasibility of coupling PRCs with SPME sampling to greatly shorten sampling time, thus affording much improved flexibility in the use of SPME for bioavailability evaluation. Environ Toxicol Chem 2013;32:1946–1953. PMID:23661411

dSED: A database tool for modeling sediment early diagenesis

NASA Astrophysics Data System (ADS)

Katsev, S.; Rancourt, D. G.; L'Heureux, I.

2003-04-01

Sediment early diagenesis reaction transport models (RTMs) are becoming powerful tools in providing kinetic descriptions of the metal and nutrient diagenetic cycling in marine, lacustrine, estuarine, and other aquatic sediments, as well as of exchanges with the water column. Whereas there exist several good database/program combinations for thermodynamic equilibrium calculations in aqueous systems, at present there exist no database tools for classification and analysis of the kinetic data essential to RTM development. We present a database tool that is intended to serve as an online resource for information about chemical reactions, solid phase and solute reactants, sorption reactions, transport mechanisms, and kinetic and equilibrium parameters that are relevant to sediment diagenesis processes. The list of reactive substances includes but is not limited to organic matter, Fe and Mn oxides and oxyhydroxides, sulfides and sulfates, calcium, iron, and manganese carbonates, phosphorus-bearing minerals, and silicates. Aqueous phases include dissolved carbon dioxide, oxygen, methane, hydrogen sulfide, sulfate, nitrate, phosphate, some organic compounds, and dissolved metal species. A number of filters allow extracting information according to user-specified criteria, e.g., about a class of substances contributing to the cycling of iron. The database also includes bibliographic information about published diagenetic models and the reactions and processes that they consider. At the time of preparing this abstract, dSED contained 128 reactions and 12 pre-defined filters. dSED is maintained by the Lake Sediment Structure and Evolution (LSSE) group at the University of Ottawa (www.science.uottawa.ca/LSSE/dSED) and we invite input from the geochemical community.

Exchangeable Phosphorus Pools and Equilibrium Characteristics for River Sediment as a Function of Particle Size

DTIC Science & Technology

2010-10-01

Zea mays L .). Can J Soil Sci 75:361-367. Zhang, T. Q., A. F. MacKenzie, B. C. Liang, and C. F. Drury. 2004. Soil test phosphorus and phosphorus...particulate exchangeable P fractions (as a fractional percentage), respectively, Cs is the suspended sediment concentration (M L -3), and Kd is the...groundwater) amended with P to a concentration of 0.120 mg L -1 to maintain in situ P equilibrium conditions (reported in James and Larson 2008

Sediment transport through self-adjusting, bedrock-walled waterfall plunge pools

NASA Astrophysics Data System (ADS)

Scheingross, Joel S.; Lamb, Michael P.

2016-05-01

Many waterfalls have deep plunge pools that are often partially or fully filled with sediment. Sediment fill may control plunge-pool bedrock erosion rates, partially determine habitat availability for aquatic organisms, and affect sediment routing and debris flow initiation. Currently, there exists no mechanistic model to describe sediment transport through waterfall plunge pools. Here we develop an analytical model to predict steady-state plunge-pool depth and sediment-transport capacity by combining existing jet theory with sediment transport mechanics. Our model predicts plunge-pool sediment-transport capacity increases with increasing river discharge, flow velocity, and waterfall drop height and decreases with increasing plunge-pool depth, radius, and grain size. We tested the model using flume experiments under varying waterfall and plunge-pool geometries, flow hydraulics, and sediment size. The model and experiments show that through morphodynamic feedbacks, plunge pools aggrade to reach shallower equilibrium pool depths in response to increases in imposed sediment supply. Our theory for steady-state pool depth matches the experiments with an R2 value of 0.8, with discrepancies likely due to model simplifications of the hydraulics and sediment transport. Analysis of 75 waterfalls suggests that the water depths in natural plunge pools are strongly influenced by upstream sediment supply, and our model provides a mass-conserving framework to predict sediment and water storage in waterfall plunge pools for sediment routing, habitat assessment, and bedrock erosion modeling.

Sensitivity and spin-up times of cohesive sediment transport models used to simulate bathymetric change: Chapter 31

USGS Publications Warehouse

Schoellhamer, D.H.; Ganju, N.K.; Mineart, P.R.; Lionberger, M.A.; Kusuda, T.; Yamanishi, H.; Spearman, J.; Gailani, J. Z.

2008-01-01

Bathymetric change in tidal environments is modulated by watershed sediment yield, hydrodynamic processes, benthic composition, and anthropogenic activities. These multiple forcings combine to complicate simple prediction of bathymetric change; therefore, numerical models are necessary to simulate sediment transport. Errors arise from these simulations, due to inaccurate initial conditions and model parameters. We investigated the response of bathymetric change to initial conditions and model parameters with a simplified zero-dimensional cohesive sediment transport model, a two-dimensional hydrodynamic/sediment transport model, and a tidally averaged box model. The zero-dimensional model consists of a well-mixed control volume subjected to a semidiurnal tide, with a cohesive sediment bed. Typical cohesive sediment parameters were utilized for both the bed and suspended sediment. The model was run until equilibrium in terms of bathymetric change was reached, where equilibrium is defined as less than the rate of sea level rise in San Francisco Bay (2.17 mm/year). Using this state as the initial condition, model parameters were perturbed 10% to favor deposition, and the model was resumed. Perturbed parameters included, but were not limited to, maximum tidal current, erosion rate constant, and critical shear stress for erosion. Bathymetric change was most sensitive to maximum tidal current, with a 10% perturbation resulting in an additional 1.4 m of deposition over 10 years. Re-establishing equilibrium in this model required 14 years. The next most sensitive parameter was the critical shear stress for erosion; when increased 10%, an additional 0.56 m of sediment was deposited and 13 years were required to re-establish equilibrium. The two-dimensional hydrodynamic/sediment transport model was calibrated to suspended-sediment concentration, and despite robust solution of hydrodynamic conditions it was unable to accurately hindcast bathymetric change. The tidally averaged box model was calibrated to bathymetric change data and shows rapidly evolving bathymetry in the first 10-20 years, though sediment supply and hydrodynamic forcing did not vary greatly. This initial burst of bathymetric change is believed to be model adjustment to initial conditions, and suggests a spin-up time of greater than 10 years. These three diverse modeling approaches reinforce the sensitivity of cohesive sediment transport models to initial conditions and model parameters, and highlight the importance of appropriate calibration data. Adequate spin-up time of the order of years is required to initialize models, otherwise the solution will contain bathymetric change that is not due to environmental forcings, but rather improper specification of initial conditions and model parameters. Temporally intensive bathymetric change data can assist in determining initial conditions and parameters, provided they are available. Computational effort may be reduced by selectively updating hydrodynamics and bathymetry, thereby allowing time for spin-up periods. reserved.

Relationship of geological and geothermal field properties: Midcontinent area, USA, an example

USGS Publications Warehouse

Forster, A.; Merriam, D.F.; Brower, J.C.

1993-01-01

Quantitative approaches to data analysis in the last decade have become important in basin modeling and mineral-resource estimation. The interrelation of geological, geophysical, geochemical, and geohydrological variables is important in adjusting a model to a real-world situation. Revealing the interdependences of variables can contribute in understanding the processes interacting in sedimentary basins. It is reasonably simple to compare spatial data of the same type but more difficult if different properties are involved. Statistical techniques, such as cluster analysis or principal components analysis, or some algebraic approaches can be used to ascertain the relations of standardized spatial data. In this example, structural configuration on five different stratigraphic horizons, one total sediment thickness map, and four maps of geothermal data were copared. As expected, the structural maps are highly related because all had undergone about the same deformation with differing degrees of intensity. The temperature gradients derived (1) from shallow borehole logging measurements under equilibrium conditions with the surrounding rock, and (2) from non-equilibrium bottom-hole temperatures (BHT) from deeper depths are mainly independent of each other. This was expected and confirmed also for the two temperature maps at 1000 ft which were constructed using both types of gradient values. Thus, it is evident that the use of a 2-point (BHT and surface temperature) straightline calculation of a mean temperature gradient gives different information about the geothermal regime than using gradients from temperatures logged under equilibrium conditions. Nevertheless, it is useful to determine to what a degree the larger dataset of nonequilibrium temperatures could reflect quantitative relationships to geologic conditions. Comparing all maps of geothermal information vs. the structural and the sediment thickness maps, it was determined that all correlations are moderately negative or slightly positive. These results are clearly shown by the cluster analysis and the principal components. Considering a close relationship between temperature and thermal conductivity of the sediments as observed for most of the Midcontinent area and relatively homogeneous heat-flow density conditions for the study area these results support the following assumptions: (1) undifferentiated geothermal gradients, computed from temperatures of different depth intervals and differing sediment properties, cannot contribute to an improved understanding of the temperature structure and its controls within the sedimentary cover, and (2) the quantitative approach of revealing such relations needs refined datasets of temperature information valid for the different depth levels or stratigraphic units. ?? 1993 International Association for Mathematical Geology.

Solid-phase Microextraction (SPME) with Stable Isotope Calibration for Measuring Bioavailability of Hydrophobic Organic Contaminants

PubMed Central

Cui, Xinyi; Bao, Lianjun; Gan, Jay

2014-01-01

Solid-phase microextraction (SPME) is a biomimetic tool ideally suited for measuring bioavailability of hydrophobic organic compounds (HOCs) in sediment and soil matrices. However, conventional SPME sampling requires the attainment of equilibrium between the fiber and sample matrix, which may take weeks or months, greatly limiting its applicability. In this study, we explored the preloading of polydimethylsiloxane fiber with stable isotope labeled analogs (SI-SPME) to circumvent the need for long sampling time, and evaluated the performance of SI-SPME against the conventional equilibrium SPME (Eq-SPME) using a range of sediments and conditions. Desorption of stable isotope-labeled analogs and absorption of PCB-52, PCB-153, bifenthrin and cis-permethrin were isotropic, validating the assumption for SI-SPME. Highly reproducible preloading was achieved using acetone-water (1:4, v/v) as the carrier. Compared to Eq-SPME that required weeks or even months, the fiber concentrations (Cf) under equilibrium could be reliably estimated by SI-SPME in 1 d under agitated conditions or 20 d under static conditions in spiked sediments. The Cf values predicted by SI-SPME were statistically identical to those determined by Eq-SPME. The SI-SPME method was further applied successfully to field sediments contaminated with PCB 52, PCB 153, and bifenthrin. The increasing availability of stable isotope labeled standards and mass spectrometry nowadays makes SI-SPME highly feasible, allowing the use of SPME under non-equilibrium conditions with much shorter or flexible sampling time. PMID:23930601

Equilibrium Partitioning Approach for Assessing Toxicity of Contaminants in Sediments: Linking Measured Concentrations to Effects

EPA Science Inventory

A variety of approaches exist for assessing the degree, extent and/or risk of metals contamination in sediments. Selection of the “correct” approach depends on the nature of the question being asked (e.g., the degree of metals contamination in marine sediments may be estimated by...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wei Chen; Kan, A.T.; Tomson, M.B.

Both the adsorption and the desorption processes play important roles in the transport and fate of organic contaminants in water-sediments and groundwater systems. The adsorption-desorption processes are shown to be influenced by a number of factors, including sediments organic carbon content, contaminant aqueous solubility, aqueous-phase concentration as well as some natural environmental factors such as pH, pE, ionic strength and temperature. External mechanical forces, such as sediment perturbation, and repeated dredging will also have finite effect on the microscopic interparticle forces that control bonds between large and small grain particles. The objective of this research is to study the influencesmore » of various environmental effects on the equilibrium or non-equilibrium desorption behavior of nonpolar organic pollutants in historically contaminated natural sediments of Lake Charles, LA. Differences of desorption behavior between freshly and historically contaminated sediments will be compared in order to evaluated the desorption mechanism. The influences of particle size, mineral composition, organic matter concentration, and aqueous phase matrix composition on desorption behaviour will also be evaluated.« less

Cross Validation of Two Partitioning-Based Sampling Approaches in Mesocosms Containing PCB Contaminated Field Sediment, Biota, and Activated Carbon Amendment.

PubMed

Schmidt, Stine N; Wang, Alice P; Gidley, Philip T; Wooley, Allyson H; Lotufo, Guilherme R; Burgess, Robert M; Ghosh, Upal; Fernandez, Loretta A; Mayer, Philipp

2017-09-05

The Gold Standard for determining freely dissolved concentrations (C free ) of hydrophobic organic compounds in sediment interstitial water would be in situ deployment combined with equilibrium sampling, which is generally difficult to achieve. In the present study, ex situ equilibrium sampling with multiple thicknesses of silicone and in situ pre-equilibrium sampling with low density polyethylene (LDPE) loaded with performance reference compounds were applied independently to measure polychlorinated biphenyls (PCBs) in mesocosms with (1) New Bedford Harbor sediment (MA, U.S.A.), (2) sediment and biota, and (3) activated carbon amended sediment and biota. The aim was to cross validate the two different sampling approaches. Around 100 PCB congeners were quantified in the two sampling polymers, and the results confirmed the good precision of both methods and were in overall good agreement with recently published LDPE to silicone partition ratios. Further, the methods yielded C free in good agreement for all three experiments. The average ratio between C free determined by the two methods was factor 1.4 ± 0.3 (range: 0.6-2.0), and the results thus cross-validated the two sampling approaches. For future investigations, specific aims and requirements in terms of application, data treatment, and data quality requirements should dictate the selection of the most appropriate partitioning-based sampling approach.

Cesium migration in saturated silica sand and Hanford sediments as impacted by ionic strength.

PubMed

Flury, Markus; Czigány, Szabolcs; Chen, Gang; Harsh, James B

2004-07-01

Large amounts of 137Cs have been accidentally released to the subsurface from the Hanford nuclear site in the state of Washington, USA. The cesium-containing liquids varied in ionic strengths, and often had high electrolyte contents, mainly in the form of NaNO3 and NaOH, reaching concentrations up to several moles per liter. In this study, we investigated the effect of ionic strengths on Cs migration through two types of porous media: silica sand and Hanford sediments. Cesium sorption and transport was studied in 1, 10, 100, and 1000 mM NaCl electrolyte solutions at pH 10. Sorption isotherms were constructed from batch equilibrium experiments and the batch-derived sorption parameters were compared with column breakthrough curves. Column transport experiments were analyzed with a two-site equilibrium-nonequilibrium model. Cesium sorption to the silica sand in batch experiments showed a linear sorption isotherm for all ionic strengths, which matched well with the results from the column experiments at 100 and 1000 mM ionic strength; however, the column experiments at 1 and 10 mM ionic strength indicated a nonlinear sorption behavior of Cs to the silica sand. Transport through silica sand occurred under one-site sorption and equilibrium conditions. Cesium sorption to Hanford sediments in both batch and column experiments was best described with a nonlinear Freundlich isotherm. The column experiments indicated that Cs transport in Hanford sediments occurred under two-site equilibrium and nonequilibrium sorption. The effect of ionic strength on Cs transport was much more pronounced in Hanford sediments than in silica sands. Effective retardation factors of Cs during transport through Hanford sediments were reduced by a factor of 10 when the ionic strength increased from 100 to 1000 mM; for silica sand, the effective retardation was reduced by a factor of 10 when ionic strength increased from 1 to 1000 mM. A two order of magnitude change in ionic strength was needed in the silica sand to observe the same change in Cs retardation as in Hanford sediments. Copyright 2003 Elsevier B.V.

Erosion of an ancient mountain range, the Great Smoky Mountains, North Carolina and Tennessee

USGS Publications Warehouse

Matmon, A.; Bierman, P.R.; Larsen, J.; Southworth, S.; Pavich, M.; Finkel, R.; Caffee, M.

2003-01-01

Analysis of 10Be and 26Al in bedrock (n=10), colluvium (n=5 including grain size splits), and alluvial sediments (n=59 including grain size splits), coupled with field observations and GIS analysis, suggest that erosion rates in the Great Smoky Mountains are controlled by subsurface bedrock erosion and diffusive slope processes. The results indicate rapid alluvial transport, minimal alluvial storage, and suggest that most of the cosmogenic nuclide inventory in sediments is accumulated while they are eroding from bedrock and traveling down hill slopes. Spatially homogeneous erosion rates of 25 - 30 mm Ky-1 are calculated throughout the Great Smoky Mountains using measured concentrations of cosmogenic 10Be and 26Al in quartz separated from alluvial sediment. 10Be and 26Al concentrations in sediments collected from headwater tributaries that have no upstream samples (n=18) are consistent with an average erosion rate of 28 ?? 8 mm Ky-1, similar to that of the outlet rivers (n=16, 24 ?? 6 mm Ky-1), which carry most of the sediment out of the mountain range. Grain-size-specific analysis of 6 alluvial sediment samples shows higher nuclide concentrations in smaller grain sizes than in larger ones. The difference in concentrations arises from the large elevation distribution of the source of the smaller grains compared with the narrow and relatively low source elevation of the large grains. Large sandstone clasts disaggregate into sand-size grains rapidly during weathering and downslope transport; thus, only clasts from the lower parts of slopes reach the streams. 26Al/10Be ratios do not suggest significant burial periods for our samples. However, alluvial samples have lower 26Al/10Be ratios than bedrock and colluvial samples, a trend consistent with a longer integrated cosmic ray exposure history that includes periods of burial during down-slope transport. The results confirm some of the basic ideas embedded in Davis' geographic cycle model, such as the reduction of relief through slope processes, and of Hack's dynamic equilibrium model such as the similarity of erosion rates across different lithologies. Comparing cosmogenic nuclide data with other measured and calculated erosion rates for the Appalachians, we conclude that rates of erosion, integrated over varying time periods from decades to a hundred million years are similar, the result of equilibrium between erosion and isostatic uplift in the southern Appalachian Mountains.

Sediment Equilibrium and Diffusive Fluxes in Relation to Phosphorus Dynamics in the Turbid Minnesota River

DTIC Science & Technology

2009-01-01

extractable P and K in a sandy clay loam soil under continuous corn ( Zea mays L .). Can J Soil Sci 75:361-367. Zhang, T. Q., A. F. MacKenzie, B. C...diffusive P flux from deposited sediment stored in river channels may also play a role in soluble P control. Ranges in equilibrium partitioning between...largest plants in the State of Minnesota, discharge (average discharge = 1.8 m3 s-1) at effluent P concentrations of 1.5 mg L -1 or less. A 538-megawatt

Probing receptor-ligand interactions by sedimentation equilibrium

NASA Astrophysics Data System (ADS)

Philo, John S.

1997-05-01

While sedimentation equilibrium is most commonly used to characterize the molecular weight and state of association of single proteins, this technique is also a very powerful tool for probing the interactions between two or more different proteins, and can characterize both the binding stoichiometry and the equilibrium constants. To resolve the complex binding interactions that can occur in such systems, it is crucial to globally fit data from many experiments to a common binding model, including samples made with different mixing ratios and a wide range of total concentration. It is often also essential to constrain the parameters during fitting so that the fits correctly reproduce the molar ratio of proteins used in making each sample. We have applied this methodology to probe mechanisms of receptor activation for a number of hematopoietic receptors and their cognate ligands, using receptor extracellular domains expressed as soluble proteins. Such data can potentially help in the design of improved or new protein therapeutics, as well as in efforts to create small- molecular mimetics of protein hormones through structure- based drug design. Sedimentation equilibrium has shown that stem cell factor, erythropoietin, and granulocyte-colony stimulating factor can each dimerize their respective receptors in solution, but the mechanism of ligand-induced receptor dimerization for these three systems are strikingly different.

Radioactive equilibrium in ancient marine sediments

USGS Publications Warehouse

Breger, I.A.

1955-01-01

Radioactive equilibrium in eight marine sedimentary formations has been studied by means of direct determinations of uranium, radium and thorium. Alpha-particle counting has also been carried out in order to cross-calibrate thick-source counting techniques. The maximum deviation from radioactive equilibrium that has been noted is 11 per cent-indicating that there is probably equilibrium in all the formations analyzed. Thick-source alpha-particle counting by means of a proportional counter or an ionization chamber leads to high results when the samples contain less than about 10 p.p.m. of uranium. For samples having a higher content of uranium the results are in excellent agreement with each other and with those obtained by direct analytical techniques. The thorium contents that have been obtained correspond well to the average values reported in the literature. The uranium content of marine sediments may be appreciably higher than the average values that have been reported for sedimentary rocks. Data show that there is up to fourteen times the percentage of uranium as of thorium in the formations studied and that the percentage of thorium never exceeds that of uranium. While the proximity of a depositional environment to a land mass may influence the concentration of uranium in a marine sediment, this is not true with thorium. ?? 1955.

PROCEDURES FOR THE DERIVATION OF EQUILIBRIUM ...

EPA Pesticide Factsheets

This equilibrium partitioning sediment benchmark (ESB) document describes procedures to derive concentrations for 32 nonionic organic chemicals in sediment which are protective of the presence of freshwater and marine benthic organisms. The equilibrium partitioning (EqP) approach was chosen because it accounts for the varying biological availability of chemicals in different sediments and allows for the incorporation of the appropriate biological effects concentration. This provides for the derivation of benchmarks that are causally linked to the specific chemical, applicable across sediments, and appropriately protective of benthic organisms. EqP can be used to calculate ESBs for any toxicity endpoint for which there are water-only toxicity data; it is not limited to any single effect endpoint. For the purposes of this document, ESBs for 32 nonionic organic chemicals, including several low molecular weight aliphatic and aromatic compounds, pesticides, and phthalates, were derived using Final Chronic Values (FCV) from Water Quality Criteria (WQC) or Secondary Chronic Values (SCV) derived from existing toxicological data using the Great Lakes Water Quality Initiative (GLI) or narcosis theory approaches. These values are intended to be the concentration of each chemical in water that is protective of the presence of aquatic life. For nonionic organic chemicals demonstrating a narcotic mode of action, ESBs derived using the GLI approach specifically for fres

Entropy production in a fluid-solid system far from thermodynamic equilibrium.

PubMed

Chung, Bong Jae; Ortega, Blas; Vaidya, Ashwin

2017-11-24

The terminal orientation of a rigid body in a moving fluid is an example of a dissipative system, out of thermodynamic equilibrium and therefore a perfect testing ground for the validity of the maximum entropy production principle (MaxEP). Thus far, dynamical equations alone have been employed in studying the equilibrium states in fluid-solid interactions, but these are far too complex and become analytically intractable when inertial effects come into play. At that stage, our only recourse is to rely on numerical techniques which can be computationally expensive. In our past work, we have shown that the MaxEP is a reliable tool to help predict orientational equilibrium states of highly symmetric bodies such as cylinders, spheroids and toroidal bodies. The MaxEP correctly helps choose the stable equilibrium in these cases when the system is slightly out of thermodynamic equilibrium. In the current paper, we expand our analysis to examine i) bodies with fewer symmetries than previously reported, for instance, a half-ellipse and ii) when the system is far from thermodynamic equilibrium. Using two-dimensional numerical studies at Reynolds numbers ranging between 0 and 14, we examine the validity of the MaxEP. Our analysis of flow past a half-ellipse shows that overall the MaxEP is a good predictor of the equilibrium states but, in the special case of the half-ellipse with aspect ratio much greater than unity, the MaxEP is replaced by the Min-MaxEP, at higher Reynolds numbers when inertial effects come into play. Experiments in sedimentation tanks and with hinged bodies in a flow tank confirm these calculations.

Equilibrium sampling informs tissue residue and sediment remediation for pyrethroid insecticides in mariculture: A laboratory demonstration.

PubMed

Li, Juan-Ying; Shi, Wenxuan; Li, Zhenhua; Chen, Yiqin; Shao, Liu; Jin, Ling

2018-03-01

Mariculture product safety in relation to sediment quality has attracted increasing attention because of the accumulation of potentially hazardous chemicals, including pyrethroid insecticides, in sediment. Passive sampling has been widely used to assess the bioavailability of sediment-associated hydrophobic organic contaminants and predict their body residue in benthic organisms. Therefore, in this study, we introduced polydimethylsiloxane (PDMS) polymer as a biomimetic "chemometer" for freely-dissolved concentrations (C free ) to assess the efficacy of different carbon sorbents in reducing the bioavailability of pyrethroids in the process of sediment remediation. Black carbon (BC)-based materials (e.g., charcoal, biochar, and activated carbon) showed the advantageous sorption capacity over humic substance-based peat soil based on both C free and tissue residue in exposed clams. Of the tested BC-type materials, biochar appeared to be an ideal one in the remediation of pyrethroid-contaminated sediment. The predictive value of the PDMS chemometer approach to informing tissue residue was confirmed by a good agreement between the measured lipid-normalized concentrations of pyrethroids in clams and the lipid-based equilibrium concentrations calculated from C free via lipid-water partition coefficients. The quantitative inter-compartmental relationship underlying the laboratory system of sediment-pore water-PDMS-biota was also cross-validated by a mechanistically-based bioaccumulation model, thus confirming the validity of C free as a predictive intermediate to alert for tissue residue and guide sediment remediation. The present study revealed a great promise of sensing C free by polymer-based equilibrium sampling in predicting tissue residue of chemicals applied in mariculture against regulatory guidelines, and, in turn, informing remediation measures when needs arise. In situ demonstration is warranted in the future to ascertain the field applicability of this approach in real mariculture systems. Copyright © 2017 Elsevier B.V. All rights reserved.

Deposition and simulation of sediment transport in the Lower Susquehanna River reservoir system

USGS Publications Warehouse

Hainly, R.A.; Reed, L.A.; Flippo, H.N.; Barton, G.J.

1995-01-01

The Susquehanna River drains 27,510 square miles in New York, Pennsylvania, and Maryland and is the largest tributary to the Chesapeake Bay. Three large hydroelectric dams are located on the river, Safe Harbor (Lake Clarke) and Holtwood (Lake Aldred) in southern Pennsylvania, and Conowingo (Conowingo Reservoir) in northern Maryland. About 259 million tons of sediment have been deposited in the three reservoirs. Lake Clarke contains about 90.7 million tons of sediment, Lake Aldred contains about 13.6 million tons, and Conowingo Reservoir contains about 155 million tons. An estimated 64.8 million tons of sand, 19.7 million tons of coal, 112 million tons of silt, and 63.3 million tons of clay are deposited in the three reservoirs. Deposition in the reservoirs is variable and ranges from 0 to 30 feet. Chemical analyses of sediment core samples indicate that the three reservoirs combined contain about 814,000 tons of organic nitrogen, 98,900 tons of ammonia as nitrogen, 226,000 tons of phosphorus, 5,610,000 1tons of iron, 2,250,000 tons of aluminum, and about 409,000 tons of manganese. Historical data indicate that Lake Clarke and Lake Aldred have reached equilibrium, and that they no longer store sediment. A comparison of cross-sectional data from Lake Clarke and Lake Aldred with data from Conowingo Reservoir indicates that Conowingo Reservoir will reach equilibrium within the next 20 to 30 years. As the Conowingo Reservoir fills with sediment and approaches equilibrium, the amount of sediment transported to the Chesapeake Bay will increase. The most notable increases will take place when very high flows scour the deposited sediment. Sediment transport through the reservoir system was simulated with the U.S. Army Corps of Engineers' HEC-6 computer model. The model was calibrated with monthly sediment loads for calendar year 1987. Calibration runs with options set for maximum trap efficiency and a "natural" particle-size distribution resulted in an overall computed trap efficiency of 34 percent for 1987, much less than the measured efficiency of 71 percent.

Role of naturally occurring gas hydrates in sediment transport

DOE Office of Scientific and Technical Information (OSTI.GOV)

McIver, R.D.

1982-06-01

Naturally occurring gas hydrates have the potential to store enormous volumes of both gas and water in semi-solid form in ocean-bottom sediments and then to release that gas and water when the hydrate's equilibrium condition are disturbed. Therefore, hydrates provide a potential mechanism for transporting large volumes of sediments. Under the combined low bottom-water temperatures and moderate hydrostatic pressures that exist over most of the continental slopes and all of the continental rises and abyssal plains, hydrocarbon gases at or near saturation in the interstitial waters of the near-bottom sediments will form hydrates. The gas can either be autochthonous, microbiallymore » produced gas, or allochthonous, catagenic gas from deeper sediments. Equilibrium conditions that stabilize hydrated sediments may be disturbed, for example, by continued sedimentation or by lowering of sea level. In either case, some of the solid gas-water matrix decomposes. Released gas and water volume exceeds the volume occupied by the hydrate, so the internal pressure rises - drastically if large volumes of hydrate are decomposed. Part of the once rigid sediment is converted to a gas- and water-rich, relatively low density mud. When the internal pressure, due to the presence of the compressed gas or to buoyancy, is sufficiently high, the overlying sediment may be lifted and/or breached, and the less dense, gas-cut mud may break through. Such hydrate-related phenomena can cause mud diapirs, mud volcanos, mud slides, or turbidite flows, depending on sediment configuration and bottom topography. 4 figures.« less

Effects of sediment supply on surface textures of gravel-bed rivers

Treesearch

John M. Buffington; David R. Montgomery

1999-01-01

Using previously published data from flume studies, we test a new approach for quantifying the effects of sediment supply (i.e., bed material supply) on surface grain size of equilibrium gravel channels. Textural response to sediment supply is evaluated relative to a theoretical prediction of competent median grain size (D’50). We find that surface median grain size (...

Network-scale dynamics of sediment mixtures: how do tectonics affect surface bed texture and channel slope?

NASA Astrophysics Data System (ADS)

Gasparini, N. M.; Bras, R. L.; Tucker, G. E.

2003-04-01

An alluvial channel's slope and bed texture are intimately linked. Along with fluvial discharge, these variables are the key players in setting alluvial transport rates. We know that both channel slope and mean grain size usually decrease downstream, but how sensitive are these variables to tectonic changes? Are basin concavity and downstream fining drastically disrupted during transitions from one tectonic regime to another? We explore these questions using the CHILD numerical landscape evolution model to generate alluvial networks composed of a sand and gravel mixture. The steady-state and transient patterns of both channel slope and sediment texture are investigated. The steady-state patterns in slope and sediment texture are verified independently by solving the erosion equations under equilibrium conditions, i.e. the case when the erosion rate is equal to the uplift rate across the entire landscape. The inclusion of surface texture as a free parameter (as opposed to just channel slope) leads to some surprising results. In all cases, an increase in uplift rate results in channel beds which are finer at equilibrium (for a given drainage area). Higher uplift rates imply larger equilibrium transport rates; this leads to finer channels that have a smaller critical shear stress to entrain material, and therefore more material can be transported for a given discharge (and channel slope). Changes in equilibrium slopes are less intuitive. An increase in uplift rates can cause channel slopes to increase, remain the same, or decrease, depending on model parameter values. In the surprising case in which equilibrium channel slopes decrease with increasing uplift rates, we suggest that surface texture changes more than compensate for the required increase in transport rates, causing channel slopes to decrease. These results highlight the important role of sediment grain size in determining transport rates and caution us against ignoring this important variable in fluvial networks.

Sorption of albendazole in sediments and soils: Isotherms and kinetics.

PubMed

Mutavdžić Pavlović, Dragana; Glavač, Antonija; Gluhak, Mihaela; Runje, Mislav

2018-02-01

Albendazole is a broad-spectrum anthelmintic drug effective against gastrointestinal parasites in humans and animals. Despite the fact that it has been detected in environment (water, sediment and soil), there is no information on its fate in the environment. So, in order to understand the sorption process of albendazole in environment, the sorption mechanism and kinetic properties were investigated through sorption equilibrium and sorption rate experiments. For that purpose, batch sorption of albendazole on five sediment samples and five soil samples from Croatia's region with different physico-chemical properties was investigated. Except physico-chemical properties of used environmental solid samples, the effects of various parameters such as contact time, initial concentration, ionic strength and pH on the albendazole sorption were studied. The K d parameter from linear sorption model was determined by linear regression analysis, while the Freundlich and Langmuir sorption models were applied to describe the equilibrium isotherms. The estimated K d values varied from 29.438 to 104.43 mLg -1 at 0.01 M CaCl 2 and for natural pH value of albendazole solution (pH 6.6). Experimental data showed that the best agreement was obtained with the linear model (R 2  > 0.99), while the rate of albendazole sorption is the best described with the kinetic model of pseudo-second-order. Obtained results point to a medium or even strong sorption of albendazole for soil or sediment particles, which is particularly dependent on the proportion of organic matter, pH, copper and zinc in them. Copyright © 2017 Elsevier Ltd. All rights reserved.

Mineral paragenesis on Mars: The roles of reactive surface area and diffusion

PubMed Central

Gil‐Lozano, Carolina; Uceda, Esther R.; Losa‐Adams, Elisabeth; Davila, Alfonso F.; Gago‐Duport, Luis

2017-01-01

Abstract Geochemical models of secondary mineral precipitation on Mars generally assume semiopen systems (open to the atmosphere but closed at the water‐sediment interface) and equilibrium conditions. However, in natural multicomponent systems, the reactive surface area of primary minerals controls the dissolution rate and affects the precipitation sequences of secondary phases, and simultaneously, the transport of dissolved species may occur through the atmosphere‐water and water‐sediment interfaces. Here we present a suite of geochemical models designed to analyze the formation of secondary minerals in basaltic sediments on Mars, evaluating the role of (i) reactive surface areas and (ii) the transport of ions through a basalt sediment column. We consider fully open conditions, both to the atmosphere and to the sediment, and a kinetic approach for mineral dissolution and precipitation. Our models consider a geochemical scenario constituted by a basin (i.e., a shallow lake) where supersaturation is generated by evaporation/cooling and the starting point is a solution in equilibrium with basaltic sediments. Our results show that cation removal by diffusion, along with the input of atmospheric volatiles and the influence of the reactive surface area of primary minerals, plays a central role in the evolution of the secondary mineral sequences formed. We conclude that precipitation of evaporites finds more restrictions in basaltic sediments of small grain size than in basaltic sediments of greater grain size. PMID:29104844

Mineral paragenesis on Mars: The roles of reactive surface area and diffusion.

PubMed

Fairén, Alberto G; Gil-Lozano, Carolina; Uceda, Esther R; Losa-Adams, Elisabeth; Davila, Alfonso F; Gago-Duport, Luis

2017-09-01

Geochemical models of secondary mineral precipitation on Mars generally assume semiopen systems (open to the atmosphere but closed at the water-sediment interface) and equilibrium conditions. However, in natural multicomponent systems, the reactive surface area of primary minerals controls the dissolution rate and affects the precipitation sequences of secondary phases, and simultaneously, the transport of dissolved species may occur through the atmosphere-water and water-sediment interfaces. Here we present a suite of geochemical models designed to analyze the formation of secondary minerals in basaltic sediments on Mars, evaluating the role of (i) reactive surface areas and (ii) the transport of ions through a basalt sediment column. We consider fully open conditions, both to the atmosphere and to the sediment, and a kinetic approach for mineral dissolution and precipitation. Our models consider a geochemical scenario constituted by a basin (i.e., a shallow lake) where supersaturation is generated by evaporation/cooling and the starting point is a solution in equilibrium with basaltic sediments. Our results show that cation removal by diffusion, along with the input of atmospheric volatiles and the influence of the reactive surface area of primary minerals, plays a central role in the evolution of the secondary mineral sequences formed. We conclude that precipitation of evaporites finds more restrictions in basaltic sediments of small grain size than in basaltic sediments of greater grain size.

Field-scale reduction of PCB bioavailability with activated carbon amendment to river sediments.

PubMed

Beckingham, Barbara; Ghosh, Upal

2011-12-15

Remediation of contaminated sediments remains a technological challenge because traditional approaches do not always achieve risk reduction goals for human health and ecosystem protection and can even be destructive for natural resources. Recent work has shown that uptake of persistent organic pollutants such as polychlorinated biphenyls (PCBs) in the food web is strongly influenced by the nature of contaminant binding, especially to black carbon surfaces in sediments. We demonstrate for the first time in a contaminated river that application of activated carbon to sediments in the field reduces biouptake of PCBs in benthic organisms. After treatment with activated carbon applied at a dose similar to the native organic carbon of sediment, bioaccumulation in freshwater oligochaete worms was reduced compared to preamendment conditions by 69 to 99%, and concentrations of PCBs in water at equilibrium with the sediment were reduced by greater than 93% at all treatment sites for up to three years of monitoring. By comparing measured reductions in bioaccumulation of tetra- and penta-chlorinated PCB congeners resulting from field application of activated carbon to a laboratory study where PCBs were preloaded onto activated carbon, it is evident that equilibrium sorption had not been achieved in the field. Although other remedies may be appropriate for some highly contaminated sites, we show through this pilot study that PCB exposure from moderately contaminated river sediments may be managed effectively through activated carbon amendment in sediments.

Study on the stability control strategy of Triphala solution based on the balance of physical stability and chemical stabilities.

PubMed

Huang, Hao-Zhou; Zhao, Sheng-Yu; Ke, Xiu-Mei; Lin, Jun-Zhi; Huang, Shu-Sen; Xu, Run-Chun; Ma, Hong-Yan; Zhang, Yi; Han, Li; Zhang, Ding-Kun

2018-06-04

Triphala is a well-known prescription in Indian Ayurveda and TCM medicine for its great effect on gingivitis and hyperlipidemia. However, its solution is unstable for the containing of excessive polyphenol, leading to the production of sediment in the short term and the decrease of efficacy. Based on the analysis of sediment formation, a novel control strategy is proposed. To conduct the analysis, the sediment formation was recorded for a consecutive five days. The changes in the composition of the supernatant and the sediment were studied by the HPLC profile analysis. The main components of the sediment were identified as corilagin, ellagic acid and gallic acid, and the amount of ellagic acid sediment increased with the storage time. Then, with a series of pH status adjustments of the Triphala solution, the physical and chemical stabilities were acquired by Turbiscan and HPLC respectively. The results showed that as the pH value increased, so did the physical stability, but the particle size and TSI of the association decreased. While the fingerprint of chemical profile similarity decreased, so did the chemical stability. Combining physical and chemical stability parameters, an equilibrium point was found out. When the pH value was adjusted to 5.0, both the physical and chemical stabilities were better: the verification test showed that the sedimentation inhibition rates on the 3rd, 5th,10th and15th days were 41%, 55%, 41%, and 23%, respectively. This manuscript provided a new control strategy that will pique pharmaceutical and food development engineers' interest and trigger research ideas controlling the quality of decoction. Copyright © 2018 Elsevier B.V. All rights reserved.

Sensitivity analysis of non-cohesive sediment transport formulae

NASA Astrophysics Data System (ADS)

Pinto, Lígia; Fortunato, André B.; Freire, Paula

2006-10-01

Sand transport models are often based on semi-empirical equilibrium transport formulae that relate sediment fluxes to physical properties such as velocity, depth and characteristic sediment grain sizes. In engineering applications, errors in these physical properties affect the accuracy of the sediment fluxes. The present analysis quantifies error propagation from the input physical properties to the sediment fluxes, determines which ones control the final errors, and provides insight into the relative strengths, weaknesses and limitations of four total load formulae (Ackers and White, Engelund and Hansen, van Rijn, and Karim and Kennedy) and one bed load formulation (van Rijn). The various sources of uncertainty are first investigated individually, in order to pinpoint the key physical properties that control the errors. Since the strong non-linearity of most sand transport formulae precludes analytical approaches, a Monte Carlo method is validated and used in the analysis. Results show that the accuracy in total sediment transport evaluations is mainly determined by errors in the current velocity and in the sediment median grain size. For the bed load transport using the van Rijn formula, errors in the current velocity alone control the final accuracy. In a final set of tests, all physical properties are allowed to vary simultaneously in order to analyze the combined effect of errors. The combined effect of errors in all the physical properties is then compared to an estimate of the errors due to the intrinsic limitations of the formulae. Results show that errors in the physical properties can be dominant for typical uncertainties associated with these properties, particularly for small depths. A comparison between the various formulae reveals that the van Rijn formula is more sensitive to basic physical properties. Hence, it should only be used when physical properties are known with precision.

Polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs in the coastal seawater, surface sediment and oyster from Dalian, Northeast China.

PubMed

Hong, Wen-Jun; Jia, Hongliang; Li, Yi-Fan; Sun, Yeqing; Liu, Xianjie; Wang, Luo

2016-06-01

A total of 46 polycyclic aromatic hydrocarbons (PAHs, 21 parent and 25 alkylated) were determined in seawater, surface sediment and oyster from coastal area of Dalian, North China. The concentration of Σ46PAHs in seawater, sediment, and oyster were 136-621 ng/L, 172-4700 ng/g dry weight (dw) and 60.0-129 ng/g wet weight (ww) in winter, and 65.0-1130 ng/L, 71.1-1090 ng/g dw and 72.8-216 ng/g ww in summer, respectively. High PAH levels were found in industrial area both in winter and summer. Selected PAH levels in sediments were compared with Sediments Quality Guidelines (ERM-ERL, TEL-PEL indexes) for evaluation probable toxic effects on marine organism and the results indicate that surface sediment from all sampling sites have a low to medium ecotoxicological risk. Daily intake of PAHs via oyster as seafood by humans were estimated and the results indicated that oyster intake would not pose a health risk to humans even 30 days after a oil spill accident near by. Water-sediment exchange analysis showed that, both in winter and summer, the fluxes for most high molecular weight PAHs were from seawater to sediment, while for low molecular weight PAHs, an equilibrium was reached between seawater and sediment. Copyright © 2016 Elsevier Inc. All rights reserved.

Variability of in situ sediment strength and pore pressure behavior of tidal estuary surface sediments

NASA Astrophysics Data System (ADS)

Lucking, Greg; Stark, Nina; Lippmann, Thomas; Smyth, Stephen

2017-10-01

Tidal estuaries feature spatially and temporally varying sediment dynamics and characteristics. Particularly, the variability of geotechnical sediment parameters is still poorly understood, limiting the prediction of long-term sediment stability and dynamics. This paper presents results from an in situ investigation of surficial sediments (≤50 cm) in a tidal estuary in New Hampshire (USA), using a portable free fall penetrometer. The aim is to investigate variations in sediment strength and pore pressure behavior with regard to sediment type and seabed morphology. The study also provides a detailed analysis of high velocity impact pore pressure data to derive information about sediment type and permeability. The penetrometer was deployed 227 times, and the findings are correlated to 78 sediment samples. Differences in sediment strength and type were found when transitioning from tidal flats to the deeper channels. Finer-grained sediments located predominantly on the tidal flats appeared well consolidated with noticeable and spatially consistent sediment strength (reflected in an estimate of quasi-static bearing capacity qsbcmax 10 kPa). Sediments with higher sand content (>75%) showed more variations in strength relating to differences in gradation, and likely represent loose and poorly consolidated sands (qsbcmax 10-55 kPa). The rate at which the recorded excess pore pressures approached equilibrium after penetration was classified and related to sediment type. The data indicate that the development of excess pore pressures upon impact and during penetration may provide additional insight into the nature and layering of bed material, such as identifying a desiccated or over-consolidated dilative surficial layer. In summary, with varying sediment grain size distributions, bulk densities and morphology, sediment strength and pore pressure behavior can vary significantly within a tidal estuary.

An examination of the rheology of flocculated clay suspensions

NASA Astrophysics Data System (ADS)

Spearman, Jeremy

2017-04-01

A dense cohesive sediment suspension, sometimes referred to as fluid mud, is a thixotropic fluid with a true yield stress. Current rheological formulations struggle to reconcile the structural dynamics of cohesive sediment suspensions with the equilibrium behaviour of these suspensions across the range of concentrations and shear. This paper is concerned with establishing a rheological framework for the range of sediment concentrations from the yield point to Newtonian flow. The shear stress equation is based on floc fractal theory, put forward by Mills and Snabre (1988). This results in a Casson-like rheology equation. Additional structural dynamics is then added, using a theory on the self-similarity of clay suspensions proposed by Coussot (1995), giving an equation which has the ability to match the equilibrium and time-dependent viscous rheology of a wide range of suspensions of different concentration and mineralogy.

The Graded Alluvial River: Variable Flow and the Dominant Discharge

NASA Astrophysics Data System (ADS)

Blom, A.; Arkesteijn, L.; Viparelli, E.

2016-12-01

We derive analytical formulations for the graded or equilibrium longitudinal profile of a mixed-sediment alluvial river under variable flow. The formulations are applicable to reaches upstream from the backwater zone. The model is based on the conservation equations for the mass of two distinct sediment modes, sand and gravel, at the bed surface to account for the effects of grain size selective transport and abrasion of gravel particles. The effects of a variable flow rate are included by (a) treating the flow as a continuously changing yet steady water discharge (i.e. here termed an alternating steady discharge) and (b) assuming the time scale of changes in channel slope and bed surface texture to be much larger than the one of changes in flow rate. The equations are simplified realizing that at equilibrium the river profile finds itself in a dynamic steady state with oscillations around constant mean values of channel slope and bed surface texture. A generalized sediment transport relation representing the stochastic nature of sediment transport allows for explicit or analytical solutions to the streamwise decrease of both the channel slope and the bed surface mean grain size under variable flow for reaches unaffected by backwater effects. This modelling approach also provides a definition of a channel-forming or dominant water discharge, i.e., that steady water discharge that is equivalent in its effect on the equilibrium channel slope to the full hydrograph.

Solution conformation and flexibility of capsular polysaccharides from Neisseria meningitidis and glycoconjugates with the tetanus toxoid protein

NASA Astrophysics Data System (ADS)

Abdelhameed, Ali Saber; Morris, Gordon A.; Almutairi, Fahad; Adams, Gary G.; Duvivier, Pierre; Conrath, Karel; Harding, Stephen E.

2016-10-01

The structural integrity of meningococcal native, micro-fluidized and activated capsular polysaccharides and their glycoconjugates - in the form most relevant to their potential use as vaccines (dilute solution) - have been investigated with respect to their homogeneity, conformation and flexibility. Sedimentation velocity analysis showed that the polysaccharide size distributions were generally bimodal with some evidence for higher molar mass forms at higher concentration. Weight average molar masses Mw where lower for activated polysaccharides. Conjugation with tetanus toxoid protein however greatly increased the molar mass and polydispersity of the final conjugates. Glycoconjugates had an approximately unimodal log-normal but broad and large molar mass profiles, confirmed by sedimentation equilibrium “SEDFIT MSTAR” analysis. Conformation analysis using HYDFIT (which globally combines sedimentation and viscosity data), “Conformation Zoning” and Wales-van Holde approaches showed a high degree of flexibility - at least as great as the unconjugated polysaccharides, and very different from the tetanus toxoid (TT) protein used for the conjugation. As with the recently published finding for Hib-TT complexes, it is the carbohydrate component that dictates the solution behaviour of these glycoconjugates, although the lower intrinsic viscosities suggest some degree of compaction of the carbohydrate chains around the protein.

Solution conformation and flexibility of capsular polysaccharides from Neisseria meningitidis and glycoconjugates with the tetanus toxoid protein.

PubMed

Abdelhameed, Ali Saber; Morris, Gordon A; Almutairi, Fahad; Adams, Gary G; Duvivier, Pierre; Conrath, Karel; Harding, Stephen E

2016-10-26

The structural integrity of meningococcal native, micro-fluidized and activated capsular polysaccharides and their glycoconjugates - in the form most relevant to their potential use as vaccines (dilute solution) - have been investigated with respect to their homogeneity, conformation and flexibility. Sedimentation velocity analysis showed that the polysaccharide size distributions were generally bimodal with some evidence for higher molar mass forms at higher concentration. Weight average molar masses M w where lower for activated polysaccharides. Conjugation with tetanus toxoid protein however greatly increased the molar mass and polydispersity of the final conjugates. Glycoconjugates had an approximately unimodal log-normal but broad and large molar mass profiles, confirmed by sedimentation equilibrium "SEDFIT MSTAR" analysis. Conformation analysis using HYDFIT (which globally combines sedimentation and viscosity data), "Conformation Zoning" and Wales-van Holde approaches showed a high degree of flexibility - at least as great as the unconjugated polysaccharides, and very different from the tetanus toxoid (TT) protein used for the conjugation. As with the recently published finding for Hib-TT complexes, it is the carbohydrate component that dictates the solution behaviour of these glycoconjugates, although the lower intrinsic viscosities suggest some degree of compaction of the carbohydrate chains around the protein.

Cross Validation of Two Partitioning-Based Sampling Approaches in Mesocosms Containing PCB Contaminated Field Sediment, Biota, and Activated Carbon Amendment

EPA Science Inventory

The Gold Standard for determining freely dissolved concentrations (Cfree) of hydrophobic organic compounds in sediment interstitial water would be in situ deployment combined with equilibrium sampling, which is generally difficult to achieve. In the present study, ex situ equilib...

Evaluation of simulated dredging to control internal phosphorus release from sediments: Focused on phosphorus transfer and resupply across the sediment-water interface.

PubMed

Yu, Juhua; Ding, Shiming; Zhong, Jicheng; Fan, Chengxin; Chen, Qiuwen; Yin, Hongbin; Zhang, Lei; Zhang, Yinlong

2017-08-15

Sediment dredging is an effective restoration method to control the internal phosphorus (P) loading of eutrophic lakes. However, the core question is that the real mechanism of dredging responsible for sediment internal P release still remains unclear. In this study, we investigated the P exchange across the sediment-water interface (SWI) and the internal P resupply ability from the sediments after dredging. The study is based on a one-year field simulation study in Lake Taihu, China, using a Rhizon soil moisture sampler, high-resolution dialysis (HR-Peeper), ZrO-Chelex diffusive gradients in thin film (ZrO-Chelex DGT), and P fractionation and adsorption isotherm techniques. The results showed low concentration of labile P in the pore water with a low diffusion potential and a low resupply ability from the sediments after dredging. The calculated flux of P from the post-dredged sediments decreased by 58% compared with that of non-dredged sediments. Furthermore, the resupply in the upper 20mm of the post-dredged sediments was reduced significantly after dredging (P<0.001). Phosphorus fractionation analysis showed a reduction of 25% in the mobile P fractions in the post-dredged sediments. Further analysis demonstrated that the zero equilibrium P concentration (EPC 0 ), partitioning coefficient (K p ), and adsorption capacity (Q max ) on the surface sediments increased after dredging. Therefore, dredging could effectively reduce the internal P resupply ability of the sediments. The reasons for this reduction are probably the lower contributions of mobile P fractions, higher retention ability, and the adsorption capacity of P for post-dredged sediments. Overall, this investigation indicated that dredging was capable of effectively controlling sediment internal P release, which could be ascribed to the removal of the surface sediments enriched with total phosphorus (TP) and/or organic matter (OM), coupled with the inactivation of P to iron (Fe) (hydr)oxides in the upper 20mm active layer. Copyright © 2017 Elsevier B.V. All rights reserved.

Adsorption Processes of Lead Ions on the Mixture Surface of Bentonite and Bottom Sediments.

PubMed

Hegedűsová, Alžbeta; Hegedűs, Ondrej; Tóth, Tomáš; Vollmannová, Alena; Andrejiová, Alena; Šlosár, Miroslav; Mezeyová, Ivana; Pernyeszi, Tímea

2016-12-01

The adsorption of contaminants plays an important role in the process of their elimination from a polluted environment. This work describes the issue of loading environment with lead Pb(II) and the resulting negative impact it has on plants and living organisms. It also focuses on bentonite as a natural adsorbent and on the adsorption process of Pb(II) ions on the mixture of bentonite and bottom sediment from the water reservoir in Kolíňany (SR). The equilibrium and kinetic experimental data were evaluated using Langmuir isotherm kinetic pseudo-first and pseudo-second-order rate equations the intraparticle and surface diffusion models. Langmuir isotherm model was successfully used to characterize the lead ions adsorption equilibrium on the mixture of bentonite and bottom sediment. The pseudo second-order model, the intraparticle and surface (film) diffusion models could be simultaneously fitted the experimental kinetic data.

Bottom-sediment chemistry in Devil's Lake, northeast North Dakota

USGS Publications Warehouse

Komor, S.C.

1994-01-01

High magnesium calcite 8 mole percent MgCO3 is the most abundant carbonate at the sediment surface. With increasing depth abundances of high magnesium carbonate decrease and abundances of low magnesium calcite aragonite and dolomite increase. Carbon isotope compositions of bulk carbonates range from δ13C = -0.7 to +0.5%. These values are close to equilibrium with dissolved inorganic carbon in lake water (δ13C = -2%) but far from equilibrium with dissolved inorganic carbon in pore water (δ13C = -16.3- -10/0%). Disequilibrium between pore water and carbonates suggests that the carbonates did not recrystallize substantially in the presence of pore water. Therefore the change of carbonate mineral proportions with depth in the sediments is due mainly to temporal changes in the proportions of endogenic, detrital, and biologic carbonates that were deposited on the lake bottom rather than postdepositional carbonate diagenesis.

The use of analytical sedimentation velocity to extract thermodynamic linkage.

PubMed

Cole, James L; Correia, John J; Stafford, Walter F

2011-11-01

For 25 years, the Gibbs Conference on Biothermodynamics has focused on the use of thermodynamics to extract information about the mechanism and regulation of biological processes. This includes the determination of equilibrium constants for macromolecular interactions by high precision physical measurements. These approaches further reveal thermodynamic linkages to ligand binding events. Analytical ultracentrifugation has been a fundamental technique in the determination of macromolecular reaction stoichiometry and energetics for 85 years. This approach is highly amenable to the extraction of thermodynamic couplings to small molecule binding in the overall reaction pathway. In the 1980s this approach was extended to the use of sedimentation velocity techniques, primarily by the analysis of tubulin-drug interactions by Na and Timasheff. This transport method necessarily incorporates the complexity of both hydrodynamic and thermodynamic nonideality. The advent of modern computational methods in the last 20 years has subsequently made the analysis of sedimentation velocity data for interacting systems more robust and rigorous. Here we review three examples where sedimentation velocity has been useful at extracting thermodynamic information about reaction stoichiometry and energetics. Approaches to extract linkage to small molecule binding and the influence of hydrodynamic nonideality are emphasized. These methods are shown to also apply to the collection of fluorescence data with the new Aviv FDS. Copyright © 2011 Elsevier B.V. All rights reserved.

The use of analytical sedimentation velocity to extract thermodynamic linkage

PubMed Central

Cole, James L.; Correia, John J.; Stafford, Walter F.

2011-01-01

For 25 years, the Gibbs Conference on Biothermodynamics has focused on the use of thermodynamics to extract information about the mechanism and regulation of biological processes. This includes the determination of equilibrium constants for macromolecular interactions by high precision physical measurements. These approaches further reveal thermodynamic linkages to ligand binding events. Analytical ultracentrifugation has been a fundamental technique in the determination of macromolecular reaction stoichiometry and energetics for 85 years. This approach is highly amenable to the extraction of thermodynamic couplings to small molecule binding in the overall reaction pathway. In the 1980’s this approach was extended to the use of sedimentation velocity techniques, primarily by the analysis of tubulin-drug interactions by Na and Timasheff. This transport method necessarily incorporates the complexity of both hydrodynamic and thermodynamic nonideality. The advent of modern computational methods in the last 20 years has subsequently made the analysis of sedimentation velocity data for interacting systems more robust and rigorous. Here we review three examples where sedimentation velocity has been useful at extracting thermodynamic information about reaction stoichiometry and energetics. Approaches to extract linkage to small molecule binding and the influence of hydrodynamic nonideality are emphasized. These methods are shown to also apply to the collection of fluorescence data with the new Aviv FDS. PMID:21703752

PREFERENTIAL PARTITIONING OF A PAH AND PCB TO A MARINE SEDIMENT AMENDED WITH SEVERAL SOURCES OF SOOT CARBON

EPA Science Inventory

Over the last decade, several studies reported that the partitioning of PAHs to sediments, in some cases, did not follow predictions based on equilibrium partitioning theory. One explanation for these differences is the presence of a second sedimentary phase with partitioning cha...

Mud Flow Characteristics Occurred in Izuoshima Island, 2013

NASA Astrophysics Data System (ADS)

Takebayashi, H.; Egashira, S.; Fujita, M.

2015-12-01

Landslides and mud flows were occurred in the west part of the Izuoshima Island, Japan on 16 October 2013. The Izuoshima Island is a volcanic island and the land surface is covered by the volcanic ash sediment in 1m depth. Hence, the mud flow with high sediment concentration was formed. The laminar layer is formed in the debris flow from the bed to the fluid surface. On the other hand, the laminar flow is restricted near the bed in the mud flow and the turbulence flow is formed on the laminar flow layer. As a result, the equilibrium slope of the mud flow becomes smaller comparing to the debris flow. In this study, the numerical analysis mud flow model considering the effect of turbulence flow on the equilibrium slope of the mud flow is developed. Subsequently, the model is applied to the mud flow occurred in the Izuoshima Island and discussed the applicability of the model and the flow characteristics of the mud flow. The differences of the horizontal flow areas between the simulated results and the field data are compared and it was found that the outline of the horizontal shape of the flow areas is reproduced well. Furthermore, the horizontal distribution of the erosion and deposition area is reproduced by the numerical analysis well except for the residential area (Kandachi area). Kandachi area is judged as the erosion area by the field observation, but the sediment was deposited in the numerical analysis. It is considered that the 1.5hour heavy rain over 100mm/h after the mud flow makes the discrepancy. The difference of the horizontal distribution of the maximum flow surface elevation between the simulated results and the field data are compared and it was found that the simulated flow depth is overestimated slightly, because of the wider erosion area due to the coarse resolution elevation data. The averaged velocity and the depth of the mud flow was enough large to collapse the houses.

An experimental and modeling study of grain-scale uranium desorption from field-contaminated sediments and the potential influence of microporosity on mass-transfer

NASA Astrophysics Data System (ADS)

Stoliker, D.; Liu, C.; Kent, D. B.; Zachara, J. M.

2012-12-01

The aquifer below the 300-Area of the Hanford site (Richland, WA, USA) is plagued by a persistent plume of dissolved uranium (U(VI)) in excess of the Environmental Protection Agency drinking water maximum contamination level even after the removal of highly contaminated sediments. The aquifer sediments in the seasonally saturated lower vadose zone act as both a source and sink for uranium during stage changes in the nearby Columbia River. Diffusion limitation of uranium mass-transfer within these sediments has been cited as a potential cause of the plume's persistence. Equilibrium U(VI) sorption is a strong function of variable chemical conditions, especially carbonate, hydrogen, and uranyl ion activities. Field-contaminated sediments from the site require up to 1,000 hours to reach equilibrium in static batch reactors. Increases in U(VI) concentrations over longer time-scales result from changes in chemical conditions, which drive reactions with sediments that favor U(VI) desorption. Grain-scale U(VI) sorption/desorption rates are slow, likely owing to diffusion of U(VI) and other solutes through intra-granular pore domains. In order to improve understanding of the impact of intra-granular diffusion and chemical reactions controlling grain-scale U(VI) release, experiments were conducted on individual particle size fractions of a <8 mm composite of field-contaminated, lower vadose zone sediments. For each size fraction, equilibrium U(VI) sorption/desorption in static batch reactors was well-described by surface complexation models over a range of chemical conditions applicable to the field site. Desorption rates from individual size fractions in flow-through batch reactors, examined under a single set of constant chemical conditions with multiple stop-flow events, were similar for all size fractions <2 mm. Kinetic U(VI) desorption in flow-through batch reactors was modeled using a multi-rate surface complexation approach, where sorption/desorption rates were assumed to be proportional to the displacement from equilibrium and multiple diffusion domains were described with a two-parameter lognormal distribution of mass-transfer rate coefficients. Parameters describing mass transfer were the same for all size fractions <2 mm but differed for the largest (2-8 mm) size fraction. The evolution of pH, along with dissolved cation and carbonate concentrations, was modeled using equilibrium cation exchange, rate-limited calcite dissolution, aerobic respiration, and silica dissolution. Desorption and chemical reaction models calibrated with individual size fractions predicted U(VI) and chemical composition as a function of time for the bulk sediment sample. Volumes of pores less than 2.4 nm, quantified using nitrogen adsorption-desorption isotherms, were the same for all size fractions < 2 mm, nearly double that of the 2-8 mm size fraction. Similarity in the observed pore volumes and multi-rate mass-transfer parameters across all size fractions <2 mm suggest the importance of pores in this size class in controlling slow grain-scale U(VI) desorption rates. Models like these provide a means for testing the influence of grain-scale mass-transfer on the persistence of U(VI) plume at the site.

Retention and Migration of Chlorpyrifos in Aquatic Sediments and Soils

NASA Astrophysics Data System (ADS)

Gebremariam, S. Y.; Beutel, M.; Yonge, D.; Flury, M.; Harsh, J. B.

2010-12-01

The accurate description of the fate and transport of potentially toxic agricultural pesticides in sediments and soils is of great interest to environmental scientists and regulators. Of particular concern is the widely documented detection of agricultural pesticides and their byproducts in drinking water wells. This presentation discusses results of a study of the fate and transport of chlorpyrifos, a strongly hydrophobic organophosphate-pesticide, in sediments and soils collected from a range of aquatic environments. Using radio-labeled chlorpyrifos, this study is unique in its comprehensive nature and focus on aquatic sediments, for which studies involving pesticide fate and transport are limited. Study components include: (1) batch equilibrium experiments to evaluate sorption/desorption parameters; (2) kinetic and non-equilibrium sorption experiments using miniaturized flow-cells; (3) column experiments to understand patterns of pesticide break through; and (4) numerical modeling of chlorpyrifos transport through aquatic sediments and soils. Initial results show that chlorpyrifos sorption, when corrected for reversible sorption to container walls, exhibited two component sorption, a large irreversible fraction and a smaller reversible fraction that can act as a secondary source. In addition, of a wide range of soil parameters measured, organic carbon content exhibited the highest correlation with chlorpyrifos retention in cranberry field soils. Simulation models developed in this study, which account for hysteretic and nonlinear sorption, will help to better predict the fate of chlorpyrifos and other hydrophobic chemicals in sediments and soils.

Equilibrium and kinetic modeling of contaminant immobilization by activated carbon amended to sediments in the field.

PubMed

Rakowska, Magdalena I; Kupryianchyk, Darya; Koelmans, Albert A; Grotenhuis, Tim; Rijnaarts, Huub H M

2014-12-15

Addition of activated carbons (AC) to polluted sediments and soils is an attractive remediation technique aiming at reducing pore water concentrations of hydrophobic organic contaminants (HOCs). In this study, we present (pseudo-)equilibrium as well as kinetic parameters for sorption of a series of PAHs and PCBs to powdered and granular activated carbons (AC) after three different sediment treatments: sediment mixed with powdered AC (PAC), sediment mixed with granular AC (GAC), and addition of GAC followed by 2 d mixing and subsequent removal ('sediment stripping'). Remediation efficiency was assessed by quantifying fluxes of PAHs towards SPME passive samplers inserted in the sediment top layer, which showed that the efficiency decreased in the order of PAC > GAC stripping > GAC addition. Sorption was very strong to PAC, with Log KAC (L/kg) values up to 10.5. Log KAC values for GAC ranged from 6.3-7.1 and 4.8-6.2 for PAHs and PCBs, respectively. Log KAC values for GAC in the stripped sediment were 7.4-8.6 and 5.8-7.7 for PAH and PCB. Apparent first order adsorption rate constants for GAC (kGAC) in the stripping scenario were calculated with a first-order kinetic model and ranged from 1.6 × 10(-2) (PHE) to 1.7 × 10(-5) d(-1) (InP). Sorption affinity parameters did not change within 9 months post treatment, confirming the longer term effectiveness of AC in field applications for PAC and GAC. Copyright © 2014. Published by Elsevier Ltd.

Analysis of the interaction between membrane proteins and soluble binding partners by surface plasmon resonance.

PubMed

Wu, Zht Cheng; de Keyzer, Jeanine; Kusters, Ilja; Driessen, Arnold J M

2013-01-01

The interaction between membrane proteins and their (protein) ligands is conventionally investigated by nonequilibrium methods such as co-sedimentation or pull-down assays. Surface Plasmon Resonance can be used to monitor such binding events in real-time using isolated membranes immobilized to a surface providing insights in the kinetics of binding under equilibrium conditions. This application provides a fast, automated way to detect interacting species and to determine the kinetics and affinity (Kd) of the interaction.

Molecular weights and subunit structure of LamB proteins.

PubMed

Nakae, T; Ishii, J N

1982-01-01

Phage lambda-receptor proteins of Escherichia coli, LamB proteins, form oligomeric aggregates to build transmembrane diffusion pores selective for maltose and maltodextrins. The molecular weights (MW) of functional oligomers as well as dissociated monomers were determined by sedimentation equilibrium analysis in homogeneous non-ionic surfactant and deuterium oxide and in 6 M guanidine-HCl, respectively. The MW of oligomers and monomers appeared as 135 600 and 45 900, respectively. Thus, functional Lamb proteins consisted of three identical subunits.

A simple shear limited, single size, time dependent flocculation model

NASA Astrophysics Data System (ADS)

Kuprenas, R.; Tran, D. A.; Strom, K.

2017-12-01

This research focuses on the modeling of flocculation of cohesive sediment due to turbulent shear, specifically, investigating the dependency of flocculation on the concentration of cohesive sediment. Flocculation is important in larger sediment transport models as cohesive particles can create aggregates which are orders of magnitude larger than their unflocculated state. As the settling velocity of each particle is determined by the sediment size, density, and shape, accounting for this aggregation is important in determining where the sediment is deposited. This study provides a new formulation for flocculation of cohesive sediment by modifying the Winterwerp (1998) flocculation model (W98) so that it limits floc size to that of the Kolmogorov micro length scale. The W98 model is a simple approach that calculates the average floc size as a function of time. Because of its simplicity, the W98 model is ideal for implementing into larger sediment transport models; however, the model tends to over predict the dependency of the floc size on concentration. It was found that the modification of the coefficients within the original model did not allow for the model to capture the dependency on concentration. Therefore, a new term within the breakup kernel of the W98 formulation was added. The new formulation results is a single size, shear limited, and time dependent flocculation model that is able to effectively capture the dependency of the equilibrium size of flocs on both suspended sediment concentration and the time to equilibrium. The overall behavior of the new model is explored and showed align well with other studies on flocculation. Winterwerp, J. C. (1998). A simple model for turbulence induced flocculation of cohesive sediment. .Journal of Hydraulic Research, 36(3):309-326.

Formation Mechanisms for Spur and Groove Features on Fringing Reefs

NASA Astrophysics Data System (ADS)

Bramante, J. F.; Ashton, A. D.; Perron, J. T.

2016-12-01

Spur and groove systems (SAGs) are ubiquitous morphological features found on fore-reef slopes globally. SAGs consist of parallel, roughly shore-normal ridges of actively growing coral and coralline algae (spurs) separated by offshore-sloping depressions typically carpeted by a veneer of sediment (grooves). Although anecdotal observations and recent statistical analyses have reported correlations between wave exposure and the distribution of SAGs on fore-reef slopes, the physical mechanisms driving SAG formation remain poorly understood. For example, there remains significant debate regarding the importance of coral growth versus bed erosion for SAG formation. Here we investigate a hypothesis that SAG formation is controlled by feedbacks between sediment production and diffusion and coral growth. Using linear stability analysis, we find that sediment production, coral growth, and the feedbacks between them are unable to produce stable periodic structures without a sediment sink. However, if incipient grooves act as conduits for sediment transport offshore, a positive feedback can develop as the groove bed erodes through wave-driven abrasion during offshore transport. Eventually a negative feedback slows groove deepening when the groove bed is armored by sediment, and the groove bed relaxes to a sediment-veneered equilibrium profile analogous to sediment-rich shorefaces. To test this hypothesis, we apply a numerical model that incorporates coral growth and sediment production, sediment diffusion, non-linear wave-driven abrasion, and sediment advection offshore. This model produces the periodic, linear features characteristic of SAG morphology. The relative magnitude of growth, production, diffusion, abrasion, and advection rates affect periodic spacing or wavelength of the modeled SAGs. Finally, we evaluate the ability of the model to replicate geographical variability in SAG characteristics using previously published datasets and reanalysis wave data.

Laboratory Experiments of Sand Ripples with Bimodal Size Distributions Under Asymmetric Oscillatory Flows

NASA Astrophysics Data System (ADS)

Calantoni, J.; Landry, B. J.

2010-12-01

The dynamics of sand ripples are vital to understanding numerous coastal processes such as sediment transport, wave attenuation, boundary layer development, and seafloor acoustic properties. Though significant laboratory research has been conducted to elucidate oscillatory flow morphodynamics under various constant and transient forcing conditions, the majority of the previous experiments were conducted only for beds with unimodal size distributions of sediment. Recent oscillatory flow experiments as well as past laboratory observations in uniform flows suggest that the presence of heterogeneous size sand compositions may significantly impact ripple morphology, resulting in a variety of observable effects (e.g., sediment sorting, bed armoring, and altered transport rates). Experimental work was conducted in a small oscillatory flow tunnel at the Sediment Dynamics Laboratory at the Naval Research Laboratory, Stennis Space Center. Three different monochromatic oscillatory forcings having velocity asymmetry were used to study sand ripple dynamics over five bimodal and two unimodal sediment beds. The seven different mixtures were composed using two unimodal sands of different colors (blue/white) and median grain diameters (d=0.31 mm / d=0.65 mm) combined into various mixtures by mass (i.e., 0/100; 10/90; 25/75; 50/50; 75/25; 90/10; and 100/0 which denotes mass percentage of blue/white sand, respectively, within each mixture). High-definition video of the sediment bed profile was acquired in conjunction with sediment trap measurements to resolve differences in ripple geometries, migration and evolution rates due to the different sediment mixtures and flow conditions. Observational findings clearly illustrate sediment stratification within ripple crests and the depth of the active mixing layer in addition to supporting sediment sorting in previous research on symmetric oscillatory flows in which the larger grains collect on top of ripple crests and smaller grains in the troughs. Preliminary quantitative results illuminate variations in equilibrium ripple geometry, ripple migration rates, and transition time scales between equilibrium states, all as functions of the sediment size mixture and flow forcing.

Sedimentation of a two-dimensional colloidal mixture exhibiting liquid-liquid and gas-liquid phase separation: a dynamical density functional theory study.

PubMed

Malijevský, Alexandr; Archer, Andrew J

2013-10-14

We present dynamical density functional theory results for the time evolution of the density distribution of a sedimenting model two-dimensional binary mixture of colloids. The interplay between the bulk phase behaviour of the mixture, its interfacial properties at the confining walls, and the gravitational field gives rise to a rich variety of equilibrium and non-equilibrium morphologies. In the fluid state, the system exhibits both liquid-liquid and gas-liquid phase separation. As the system sediments, the phase separation significantly affects the dynamics and we explore situations where the final state is a coexistence of up to three different phases. Solving the dynamical equations in two-dimensions, we find that in certain situations the final density profiles of the two species have a symmetry that is different from that of the external potentials, which is perhaps surprising, given the statistical mechanics origin of the theory. The paper concludes with a discussion on this.

Laboratory Alluvial Rivers

NASA Astrophysics Data System (ADS)

Devauchelle, O.; Abramian, A.; Seizilles, G.; Lajeunesse, E.

2015-12-01

By which physical mechanisms does a river select its shape and size? We investigate this question using small laboratory rivers formed by laminar flows.In its simplest form, this experiment consists in a flow of glycerol over a uniform layer of plastic sediments. After a few hours, a channel forms spontaneously, and eventually reaches a stable geometry. This equilibrium state corresponds accurately to the force balance proposed by Henderson (1961).If we impose a sediment discharge at the inlet of the experiment, the river adjusts to this boundary condition by widening its channel. Observation suggests that this new equilibrium results from the balance between gravity, which pulls the entrained grains towards the center of the channel, and bedload diffusion, which returns them towards the banks. This balance explains why experimental rivers get wider and shallower as their sediment load increases.However, to test quantitatively this theory against observation, we need to evaluate independently the effect of transverse slope on bedload transport. We propose to use an instability generated by bedload diffusion to do so.

Modelling the fate of micropollutants in the marine environment using passive sampling.

PubMed

Claessens, Michiel; De Laender, Frederik; Monteyne, Els; Roose, Patrick; Janssen, Colin R

2015-07-15

Polydimethylsiloxane sheets were used to determine freely dissolved concentrations (C(diss)) of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in the Belgian coastal zone. Equilibrium models were used to predict the whole water concentrations (C(ww)) of these compounds as well as their concentrations in sediment, suspended particulate matter (SPM) and biota. In general, contaminant concentrations were predicted well for whole water and biota. C(ww) was increasingly underpredicted as K(oc) increased, possibly because of the presence of black carbon. Concentrations in biota were overestimated by the equilibrium approach when logK(ow) exceeded 6.5, suggesting an increasing role of transformation processes. Concentrations of PAHs and PCBs in sediment and SPM were consistently underpredicted although a good correlation between measured and predicted values was observed. This was potentially due to the use of experimental K(oc) values which have been found to underestimate partitioning of hydrophobic substances to sediment in field studies. Copyright © 2015 Elsevier Ltd. All rights reserved.

Remediation of organochlorine pesticides contaminated lake sediment using activated carbon and carbon nanotubes.

PubMed

Hua, Shan; Gong, Ji-Lai; Zeng, Guang-Ming; Yao, Fu-Bing; Guo, Min; Ou, Xiao-Ming

2017-06-01

Organochlorine pesticides (OCPs) in sediment were a potential damage for humans and ecosystems. The aim of this work was to determine the effectiveness of carbon materials remedy hexachlorocyclohexane (HCH) and dichlorodiphenyltrichloroethanes (DDTs) in sediment. Two different carbon materials including activated carbon (AC) and multi-walled carbon nanotubes (MWCNTs) were used in the present research. Sediment treated with 2 wt% AC and MWCNTs after 150 d contact showed 97%, and 75% reduction for HCH, and 93% and 59% decrease for DDTs in aqueous equilibrium concentration, respectively. Similarly, the reduction efficiencies of DDT and HCH uptake by semipermeable membrane devices (SPMDs) treated with AC (MWCNTs) were 97% (75%) and 92% (63%), respectively under the identical conditions. Furthermore, for 2 wt% AC (MWCNTs) system, a reduction of XAD beads uptake up to 87% (52%) and 73% (67%) was obtained in HCH and DDT flux to overlying water in quiescent system. Adding MWCNTs to contaminated sediment did not significantly decrease aqueous equilibrium concentration and DDTs and HCH availability in SPMDs compared to AC treatment. A series of results indicated that AC had significantly higher remediation efficiency towards HCH and DDTs in sediment than MWCNTs. Additionally, the removal efficiencies of two organic pollutants improved with increasing material doses and contact times. The greater effectiveness of AC was attributed to its greater specific surface area, which was favorable for binding contaminants. These results highlighted the potential for using AC as in-situ sorbent amendments for sediment remediation. Copyright © 2017 Elsevier Ltd. All rights reserved.

Riparian vegetation controls on the hydraulic geometry of streams

NASA Astrophysics Data System (ADS)

McBride, M.

2010-12-01

A synthesis of field measurements, remote observations, and numerical modeling techniques highlights the significance of riparian vegetation in determining the geometry of streams and impacting sediment transport dynamics in temperate, Piedmont regions. Specifically, forested and grassy riparian vegetation establish streams with significantly different widths and with different timescales for attaining a state of dynamic equilibrium. The interactions between riparian vegetation, channel form, and channel dynamics are scale dependent. Scale dependency arises because of variations in ratios of vegetation length scales and geomorphic scales (e.g., channel width and depth). Stream reaches with grassy vegetation experience more frequent overbank discharges, migrate more quickly, and exhibit a more classic dynamic equilibrium than forested reaches. These phenomena are relevant to current watershed management efforts that aim to reduce sediment and nutrient loads to receiving water bodies, such as the Chesapeake Bay. The reforestation of riparian buffers is a common restoration technique that intends to improve water quality, temperature regimes, and in-stream physical habitat. Passive reforestation of riparian areas along a tributary to Sleepers River in Danville, VT, USA caused an increase in channel width and cross-sectional area over a 40-year period. From a comparison of historical records and current cross-sectional dimensions, the channel widening resulted in the mobilization of approximately 85 kg/ha/yr of floodplain sediments. Long-term monitoring of suspended sediments in an adjacent watershed indicates that this sediment source may account for roughly 40 percent of the total suspended sediment load. In some instances, increased sediment loads associated with channel widening may be an unforeseen consequence that compromises riparian restoration efforts.

A gel probe equilibrium sampler for measuring arsenic porewater profiles and sorption gradients in sediments: II. Field application to Haiwee reservoir sediment

USGS Publications Warehouse

Campbell, K.M.; Root, R.; O'Day, P. A.; Hering, J.G.

2008-01-01

Arsenic (As) geochemistry and sorption behavior were measured in As- and iron (Fe)-rich sediments of Haiwee Reservoir by deploying undoped (clear) polyacrylamide gels and hydrous ferric oxide (HFO)-doped gels in a gel probe equilibrium sampler, which is a novel technique for directly measuring the effects of porewater composition on As adsorption to Fe oxides phases in situ. Arsenic is deposited at the sediment surface as As(V) and is reduced to As(III) in the upper layers of the sediment (0-8 cm), but the reduction of As(V) does not cause mobilization into the porewater. Dissolved As and Fe concentrations increased at depth in the sediment column driven by the reductive dissolution of amorphous Fe(III) oxyhydroxides and conversion to a mixed Fe(II, III) green rust-type phase. Adsorption of As and phosphorous (P) onto HFO-doped gels was inhibited at intermediate depths (10-20 cm), possibly due to dissolved organic or inorganic carbon, indicating that dissolved As concentrations were at least partially controlled by porewater composition rather than surface site availability. In sediments that had been recently exposed to air, the region of sorption inhibition was not observed, suggesting that prior exposure to air affected the extent of reductive dissolution, porewater chemistry, and As adsorption behavior. Arsenic adsorption onto the HFO-doped gels increased at depths >20 cm, and the extent of adsorption was most likely controlled by the competitive effects of dissolved phosphate. Sediment As adsorption capacity appeared to be controlled by changes in porewater composition and competitive effects at shallower depths, and by reductive dissolution and availability of sorption sites at greater burial depths. ?? 2008 American Chemical Society.

Observations of Near-Bed Deposition and Resuspension Processes at the Fluvial-Tidal Transition Using High Resolution Adcp, Adv, and Lisst

NASA Astrophysics Data System (ADS)

Haught, D. R.; Stumpner, P.

2012-12-01

Processes that determine deposition and resuspension of sediment in fluvial and tidal systems are complicated and difficult to predict because of turbulence-sediment interaction. In fluvial systems net sediment deposition rates near the bed are determined by shear stresses that occur when turbulence interacts with the bed and the entrained sediment above. In tidal systems, processes are driven primarily by the confounding factors of slack water and reversing flow. In this study we investigate near-bed sediment fluxes, settling velocities and sediment size distributions during a change from a fluvial signal to a tidal signal. In order to examine these processes a high resolution, high frequency ADCP, ADV, water quality sonde and LISST data were collocated at the fluvial-tidal transition in the Sacramento River at Freeport, CA. Data were collected at 15-30 minute increments for a month`. Data were dissevered into fluvial and tidal components. Acoustic backscatterence was used as a surrogate to sediment concentration and sediment flux () was calculated from the turbulence properties. Settling velocities were computed from the diffusion-advection equation assuming equilibrium of settling and re-suspension fluxes. Particle density was back-calculated from median particle diameter and calculated settling velocities (Reynolds number<0.5) using Stokes' law. Preliminary results suggest that during peak fluvial discharge that the diffusion-advection gives poor estimates of settling velocities as inferred from particle densities above 3500 kg/m3. During the transition from fluvial to tidal signal and throughout the tidal signal particle densities range from 2650 kg/m3 to 1000 kg/m3, suggesting that settling velocities were accurately estimated. Thus the equilibrium assumption appears poor during high fluvial discharge and reasonable during low fluvial discharge when tidal signal is dominant.

Turbidity Current Head Mixing

NASA Astrophysics Data System (ADS)

Hernandez, David; Sanchez, Miguel Angel; Medina, Pablo

2010-05-01

A laboratory experimental set - up for studying the behaviour of sediment in presence of a turbulent field with zero mean flow is compared with the behaviour of turbidity currents [1] . Particular interest is shown on the initiation of sediment motion and in the sediment lift - off. The behaviour of the turbidity current in a flat ground is compared with the zero mean flow oscilating grid generated turbulence as when wave flow lifts off suspended sediments [2,3]. Some examples of the results obtained with this set-up relating the height of the head of the turbidity current to the equilibrium level of stirred lutoclines are shown. A turbulent velocity u' lower than that estimated by the Shield diagram is required to start sediment motion. The minimum u' required to start sediment lift - off, is a function of sediment size, cohesivity and resting time. The lutocline height depends on u', and the vorticity at the lutocline seems constant for a fixed sediment size [1,3]. Combining grid stirring and turbidty current head shapes analyzed by means of advanced image analysis, sediment vertical fluxes and settling speeds can be measured [4,5]. [1] D. Hernandez Turbulent structure of turbidity currents and sediment transport Ms Thesis ETSECCPB, UPC. Barcelona 2009. [2] A. Sánchez-Arcilla; A. Rodríguez; J.C. Santás; J.M. Redondo; V. Gracia; R. K'Osyan; S. Kuznetsov; C. Mösso. Delta'96 Surf-zone and nearshore measurements at the Ebro Delta. A: International Conference on Coastal Research through large Scale Experiments (Coastal Dynamics '97). University of Plymouth, 1997, p. 186-187. [3] P. Medina, M. A. Sánchez and J. M. Redondo. Grid stirred turbulence: applications to the initiation of sediment motion and lift-off studies Physics and Chemistry of the Earth, Part B: Hydrology, Oceans and Atmosphere. 26, Issue 4, 2001, Pages 299-304 [4] M.O. Bezerra, M. Diez, C. Medeiros, A. Rodriguez, E. Bahia., A. Sanchez-Arcilla and J.M. Redondo. Study on the influence of waves on coastal diffusion using image analysis. Applied Scientific Research 59,.191-204. 1998. [5] J.M. Redondo. Turbulent mixing in the Atmosphere and Ocean. Fluid Physics. 584-597. World Scientific. New York. 1994

Hypolyminetic Oxygen Depletion And Dynamics of P Binding Forms: Insights From Modeling Sediment Early Diagenesis Coupled With Automatic Parameter Estimation

NASA Astrophysics Data System (ADS)

Shafei, Babak; Schmid, Martin; Müller, Beat; Chwalek, Thomas

2014-05-01

Sediment diagenesis can significantly impact on lake water quality through depleting hypolimnion oxygen and acting as a sink or source of nutrients and contaminants. In this study, we apply MATsedLAB, a sediment diagenesis module developed in MATLAB [1, 2] to quantify benthic oxygen consumption and biogeochemical cycling of phosphate (P) in lacustrine sediments of Lake Baldegg, located in central Switzerland. MATsedLAB provides an access to the advanced computational and visualization capabilities of the interactive programming environment of MATLAB. It allows for a flexible definition of non steady-state boundary conditions at the sediment-water interface (SWI), the model parameters as well as transport and biogeochemical reactions. The model has been extended to facilitate the model-independent parameter estimation and uncertainty analysis using the software package, PEST. Lake Baldegg represents an interesting case where sediment-water interactions control P loading in an eutrophic lake. It is of 5.2 km2 surface area and has been artificially aerated since 1982. Between 1960 and 1980, low oxygen concentrations and meromictic condition were established as a result of high productivity. Here, we use the cores for the measurements of anions and cations which were collected in April and June 2012 respectively from the deepest location (66 m), by Torres et al. (2013) to calibrate the developed model [3]. Depth profiles of thirty three species were simulated by including thirty mixed kinetic-equilibrium biogeochemical processes as well as imposing the fluxes of organic and inorganic matters along with solute concentrations at the SWI as dynamic boundary conditions. The diffusive transport in the boundary layer (DBL) above the SWI was included as the supply of O2 to the sediment surface can be diffusion-limited, and applying a constant O2 concentration at the sediment surface may overestimate O2 consumption. Benthic oxygen consumption was calculated as a function of the present and past deposited OM. The results revealed the transient nature of sediment oxygen uptake and existence of temporal lag associated with benthic oxygen consumption for the aerated versus non-aerated scenarios. The model closely reproduced phosphate partitioning among OM and various redox-sensitive inorganic minerals. The results showed that P associated with OM is the dominant pool as inorganic binding P such as apatite, vivinite and adsorbed P contain a minor fraction of solid phase P. The calculated flux of dissolved P through the SWI under seasonal and decadal variations suggest that oxygen concentration at the SWI and the flux of settling OM along with its composition expressed as the ratio of degradable to inert OM are the major factors that control P release to the overlying water under dynamic forcing. References [1] Couture, R., et al. (2009). "Non steady-stae modeling of arsenic diagenesis in lake sediments." Environmental Science and Technology 44 (1): 197-203. [2] Shafei, B., et al. (2010). "Arsenic sorption in aquatic sediments: equilibrium, kinetic and mixed modeling approaches." Geochimica et cosmochimica acta 74 (12): A938-A938. [3] Torres, N. T., et al. (2013). "Sediment porewater extraction and analysis combining filter tube samplers and capillary electrophoresis." Environmental Science-Processes & Impacts 15(4): 715-720.

How do changes in suspended sediment concentration alone influence the size of mud flocs under steady turbulent shearing?

NASA Astrophysics Data System (ADS)

Tran, Duc; Kuprenas, Rachel; Strom, Kyle

2018-04-01

Modeling the size and settling velocity of sediment under the influence of flocculation is crucial for the accurate prediction of mud movement and deposition in sediment transport modeling of environments such as agricultural streams, large coastal rivers, estuaries, river plumes, and turbidity currents. Yet, collecting accurate and high resolution data on mud flocs is difficult. As a result, models that account for the influence of flocculation on mud settling velocity are based on sparse data that often present non-congruent relationship in floc properties with basic influencers of flocculations such as suspended sediment concentration. This study examines the influence of suspended sediment concentration on floc size populations within a turbulent suspension. Specifically, the work investigates: (1) the relationship between the equilibrium floc size and suspended sediment concentration under conditions of steady concentration and turbulent shearing; and (2) the speed at which mature flocs adapt to an unsteady drop in the concentration when turbulent shear is constant. Two sets of experiments were used to investigate the target processes. All work was conducted in laboratory mixing tanks using a floc camera and a newly developed image acquisition method. The new method allows for direct imaging and sizing of flocs within turbulent suspensions of clay in concentrations ranging from 15 to 400 mg/L, so that no transfer of the sample to another settling column or imaging tank is needed. The primary conclusions from the two sets of experiments are: (1) that the equilibrium floc size in an energetic turbulent suspension is linearly and positively related to concentration over the range of C = 50 to 400 mg/L, yet with a smaller-than-expected slope based on previous data and models from low-energy environments; and (2) that floc sizes decrease quickly (with a time lag on the order of 1-15 min) to time-varying decreases in concentration at turbulent shearing of G = 50s-1 . Overall the data illustrate that equilibrium floc size is a positive function of concentration, but that the rate of increase is weaker than expected. The data also suggest that approximating the size or settling velocity of some muds with a simple equilibrium model might be appropriate if the time steps of interest are on the order of 10 min or larger. The data also shows the importance of calibrating historic mud settling velocity equations for accurate predictions.

Modeling Paragenesis: Erosion Opposite to Gravity in Cave Channels

NASA Astrophysics Data System (ADS)

Cooper, M. P.; Covington, M. D.

2017-12-01

Sediment plays an important role in bedrock channels, providing both tools and cover that influence patterns of bed erosion. It has also been shown that sediment load influences bedrock channel width, with increased sediment leading to wider channels. A variety of models have been developed to explore these effects. In caves, it is hypothesized that sediments covering the floors of fully flooded channels that are forming beneath the water table (phreatic zone) can force dissolution upwards towards the water table, leading to upward erosion balanced by gradual deposition of sediment within the channel bottom. This strange process is termed paragenesis, and while there are conceptual and experimental models of the process, no prior mathematical models of cave passage evolution has captured these effects. Consequently, there is little quantitative understanding of the processes that drive paragenesis and how they link to the morphology of the cave channels that develop. We adapt a previously developed algorithm for estimating boundary shear stress within channels with free-surface flows to enable calculation of boundary shear stress in pipe-full conditions. This model successfully duplicates scaling relationships in surface channels, and geometries of caves formed in the phreatic zone such as phreatic tubes. Once sediment flux is incorporated the model successfully duplicates the hypothesized processes of paragenetic gallery formation: the cover effect prevents dissolution in the direction of gravity; passages are enlarged upwards reducing the sediment transport capacity; sediment is deposited and the process drives a continuing feedback loop. Simulations reveal that equilibrium paragenetic channel widths scale with both sediment flux and discharge. Unlike in open channel settings, increased sediment load actually narrows paragenetic channels. The cross section evolution model also reveals that the existence of equilibrium widths in such galleries requires erosion to scale with shear stress, suggesting a role of either mechanical erosion or transport limited dissolution. These types of erosion contrast with current numerical models of speleogenesis, where chemically limited dissolution, a process independent of shear stress, is predicted to occur in most turbulent flow settings.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kayzar, Theresa M.; Villa, Adam C.; Lobaugh, Megan L.

The uranium concentrations and isotopic compositions of waters, sediment leachates and sediments from Red Rock Creek in the Stanislaus National Forest of California were measured to investigate the transport of uranium from a point source (the Juniper Uranium Mine) to a natural surface stream environment. Furthermore, we alter the (234U)/(238U) composition of Red Rock Creek downstream of the Juniper Mine. As a result of mine-derived contamination, water (234U)/(238U) ratios are 67% lower than in water upstream of the mine (1.114–1.127 ± 0.009 in the contaminated waters versus 1.676 in the clean branch of the stream), and sediment samples have activitymore » ratios in equilibrium in the clean creek and out of equilibrium in the contaminated creek (1.041–1.102 ± 0.007). Uranium concentrations in water, sediment and sediment leachates are highest downstream of the mine, but decrease rapidly after mixing with the clean branch of the stream. Uranium content and compositions of the contaminated creek headwaters relative to the mine tailings of the Juniper Mine suggest that uranium has been weathered from the mine and deposited in the creek. The distribution of uranium between sediment surfaces (leachable fraction) and bulk sediment suggests that adsorption is a key element of transfer along the creek. In clean creek samples, uranium is concentrated in the sediment residues, whereas in the contaminated creek, uranium is concentrated on the sediment surfaces (~70–80% of uranium in leachable fraction). Furthermore, contamination only exceeds the EPA maximum contaminant level (MCL) for drinking water in the sample with the closest proximity to the mine. Isotopic characterization of the uranium in this system coupled with concentration measurements suggest that the current state of contamination in Red Rock Creek is best described by mixing between the clean creek and contaminated upper branch of Red Rock Creek rather than mixing directly with mine sediment.« less

Transport phenomena of graded sediments in tidal environments

NASA Astrophysics Data System (ADS)

Bonaldo, Davide; Dall'Angelo, Chiara; di Silvio, Giampaolo

2010-05-01

A long-term morphodynamic model simulating the ontogenesis and evolution of a tidal lagoon has been undergoing a continuous improvement in order to enrich its predictive ability and assess the relative importance of different factors, of both natural and anthropogenic origin, in defining the equilibrium configuration of such systems. A significant step forward in this direction is achieved by introducing the possibility to extend the analysis from uniform to graded sediments. In the latter case the representation of long-term phenomena is conceptually the same as for a sediment characterized by a single granulometric class, as far as it concerns the temporal averaging and the splitting of the transport in a dispersive component (mainly given by tidal action) and an eulerian residual convective component (resulting from rivers, long-shore currents, and asymmetry between flood and ebb flow fields). The horizontal sediment budget, however, is now coupled with a sediment budget among the different granulometric classes in the bottom, and precisely in a "mixing layer" whose thickness has to be properly defined. This new enhancement of the model allows, beside a more precise description of the morphodynamic processes, a certain number of further investigations. As a first point, it makes it possible to study the effect of the initial stratigraphic conditions on the genesis and evolution of the tidal basin, thus obtaining some informations about the persistence of "geological memory" in the system. Another matter, of environmental interest rather than strictly morphodynamic, concerns the possibility of creating "auxiliary classes" among the grainsize classes in order to label and track contaminated sediments, providing a prediction tool and a decisional support in case of environmental accidents. Such a sediment tracking could also be used to distinguish the sediments according to their fluvial or maritime origin, defining in this way a criterion for the classification of the various morphological features which can be found within the system. A sensitivity analysis of the main parameters is under way.

Dynamic equilibrium behaviour observed on two contrasting tidal flats from daily monitoring of bed-level changes

NASA Astrophysics Data System (ADS)

Hu, Zhan; van der Wal, Daphne; Cai, Huayang; van Belzen, Jim; Bouma, Tjeerd J.

2018-06-01

Dynamic equilibrium theory (DET) has been applied to tidal flats to systematically explain intertidal morphological responses to various distributions of bed shear stress (BSS). However, it is difficult to verify this theory with field observations because of the discrepancy between the idealized conceptions of theory and the complex reality of intertidal dynamics. The core relation between intertidal morphodynamics and BSS distribution can be easily masked by noise in complex datasets, leading to conclusions of insufficient field evidence to support DET. In the current study, hydrodynamic and morphodynamic data were monitored daily for one year on two tidal flats with contrasting wave exposures. BSS distribution was obtained by validated numerical models. Tidal flat dynamic equilibrium behaviour and BSS were linked via Empirical Orthogonal Function (EOF) analysis. We show that the principal morphodynamic modes corresponded well with the respective modes of BSS found at both sites. Tide-induced BSS was the dominant force at both sites, regardless of the level of wave exposure. The overall erosional and steepening trend found at the two flats can be attributed to the prevailing action of tidal forcing and reduced sediment supply. Hence, EOF analysis confirmed that tidal flat morphodynamics are consistent with DET, providing both field and model evidence to support this theory.

Transport of U(VI) through sediments amended with phosphate to induce in situ uranium immobilization.

PubMed

Mehta, Vrajesh S; Maillot, Fabien; Wang, Zheming; Catalano, Jeffrey G; Giammar, Daniel E

2015-02-01

Phosphate amendments can be added to U(VI)-contaminated subsurface environments to promote in situ remediation. The primary objective of this study was to evaluate the impacts of phosphate addition on the transport of U(VI) through contaminated sediments. In batch experiments using sediments (<2 mm size fraction) from a site in Rifle, Colorado, U(VI) only weakly adsorbed due to the dominance of the aqueous speciation by Ca-U(VI)-carbonate complexes. Column experiments with these sediments were performed with flow rates that correspond to a groundwater velocity of 1.1 m/day. In the absence of phosphate, the sediments took up 1.68-1.98 μg U/g of sediments when the synthetic groundwater influent contained 4 μM U(VI). When U(VI)-free influents were then introduced with and without phosphate, substantially more uranium was retained within the column when phosphate was present in the influent. Sequential extractions of sediments from the columns revealed that uranium was uniformly distributed along the length of the columns and was primarily in forms that could be extracted by ion exchange and contact with a weak acid. Laser induced fluorescence spectroscopy (LIFS) analysis along with sequential extraction results suggest adsorption as the dominant uranium uptake mechanism. The response of dissolved uranium concentrations to stopped-flow events and the comparison of experimental data with simulations from a simple reactive transport model indicated that uranium adsorption to and desorption from the sediments was not always at local equilibrium. Copyright © 2014 Elsevier Ltd. All rights reserved.

The distribution dynamics and desorption behaviour of mobile pharmaceuticals and caffeine to combined sewer sediments.

PubMed

Hajj-Mohamad, M; Darwano, H; Duy, S Vo; Sauvé, S; Prévost, M; Arp, H P H; Dorner, S

2017-01-01

Pharmaceuticals are discharged to the environment from wastewater resource recovery facilities, sewer overflows, and illicit sewer connections. To understand the fate of pharmaceuticals, there is a need to better understand their sorption dynamics to suspended sediments (SS) and settled sediments (StS) in sewer systems. In this study, such sorption dynamics to both SS and StS were assessed using a batch equilibrium method under both static and dynamic conditions. Experiments were performed with natively occurring and artificially modified concentrations of sewer pharmaceuticals (acetaminophen, theophylline, carbamazepine, and a metabolite of carbamazepine) and caffeine. Differences in apparent distribution coefficients, K d,app , between SS and StS were related to differences in their organic carbon (OC) content, and the practice of artificially modifying the concentration. K d,app values of modified contaminant concentrations and high OC sediments were substantially higher. Pseudo-second order desorption rates for these mobile compounds were also quantified. Successive flushing events to simulate the addition of stormwater to sewer networks revealed that aqueous concentrations would not necessarily decrease, because the added water will rapidly return to equilibrium concentrations with the sediments. Sorption and desorption kinetics must be considered in addition to dilution, to avoid underestimating the influence of dilution on concentrations of pharmaceuticals discharged to the environment. Copyright © 2016 Elsevier Ltd. All rights reserved.

Evolution of Holocene tidal systems along the Dutch coast: effects of rivers, coastal boundary conditions, eco-engineering species, inherited relief and human interference

NASA Astrophysics Data System (ADS)

Haas, T. D.; Pierik, H. J.; van der Spek, A.; Cohen, K.; van Maanen, B.; Kleinhans, M. G.

2016-12-01

Estuaries and tidal basins are partly enclosed coastal bodies of water with a free connection to the open sea at their tidal inlet and with no to marginal riverine input (tidal basins) or substantial riverine input (estuaries). Their tidal inlets can only remain open over Holocene timescales when (1) the formation of accommodation space exceeds infilling or (2) the inlet system is in dynamic equilibrium (sediment input equals output). Physical and numerical modelling suggest that estuaries and tidal basins develop toward a dynamic equilibrium under constant boundary conditions and remain open over long timescales, whereas many natural estuaries and tidal basins have filled up and were closed off or became deltas during the Holocene. This raises the question if and how tidal inlets can remain open over long timescales? And what is the effect of river inflow and sediment supply thereon? Here we compare the Holocene evolution of tidal systems along the Dutch coast to empirically identify the most important factors that control their long-term evolution. Along the coast of the Netherlands estuaries and tidal basins were formed during the middle Holocene driven by rapid relative sea-level rise and during the late Holocene driven by natural and human-induced subsidence in coastal plain peatlands. During the Holocene tidal inlets connected to rivers (estuaries) were able to persist and attain dynamic equilibrium while tidal basins without or with a very marginal riverine inflow were unstable and closed off under abundant sediment supply. There are many examples of long-lived tidal inlets that rapidly closed off after upstream river avulsion leading to a decrease and finally loss of riverine input. Long-term net import of sediment from the sea into Dutch tidal basins is favoured by strong, flood-dominated, tidal asymmetry along the Dutch coast, the shallow sand-rich floor of the North Sea and the abundance of mud in the coastal area supplied by the Rhine and Meuse rivers. While sandy tidal basins may obtain dynamic equilibrium and remain open over long timescales, we hypothesize that an abundance of mud and eco-engineering species often culminates in continuous basin filling with fine sediment and the growth of intertidal and supratidal areas, eventually resulting in closure of the basin.

Run-of-River Impoundments Can Remain Unfilled While Transporting Gravel Bedload: Numerical Modeling Results

NASA Astrophysics Data System (ADS)

Pearson, A.; Pizzuto, J. E.

2015-12-01

Previous work at run-of-river (ROR) dams in northern Delaware has shown that bedload supplied to ROR impoundments can be transported over the dam when impoundments remain unfilled. Transport is facilitated by high levels of sand in the impoundment that lowers the critical shear stresses for particle entrainment, and an inversely sloping sediment ramp connecting the impoundment bed (where the water depth is typically equal to the dam height) with the top of the dam (Pearson and Pizzuto, in press). We demonstrate with one-dimensional bed material transport modeling that bed material can move through impoundments and that equilibrium transport (i.e., a balance between supply to and export from the impoundment, with a constant bed elevation) is possible even when the bed elevation is below the top of the dam. Based on our field work and previous HEC-RAS modeling, we assess bed material transport capacity at the base of the sediment ramp (and ignore detailed processes carrying sediment up and ramp and over the dam). The hydraulics at the base of the ramp are computed using a weir equation, providing estimates of water depth, velocity, and friction, based on the discharge and sediment grain size distribution of the impoundment. Bedload transport rates are computed using the Wilcock-Crowe equation, and changes in the impoundment's bed elevation are determined by sediment continuity. Our results indicate that impoundments pass the gravel supplied from upstream with deep pools when gravel supply rate is low, gravel grain sizes are relatively small, sand supply is high, and discharge is high. Conversely, impoundments will tend to fill their pools when gravel supply rate is high, gravel grain sizes are relatively large, sand supply is low, and discharge is low. The rate of bedload supplied to an impoundment is the primary control on how fast equilibrium transport is reached, with discharge having almost no influence on the timing of equilibrium.

Sorption kinetics of Hg and HgCl[sub 2] on Kirkwood-Cohansey aquifer sediments from the New Jersey Coastal Plain

DOE Office of Scientific and Technical Information (OSTI.GOV)

MacLeod, C.; Peterson, J.

1992-01-01

Anomalously high Hg concentrations have been detected from domestic wells in the Kirkwood-Cohansey Aquifer System, New Jersey Coastal Plain. Mercury concentrations ranging from 0.2--83.0 [mu]g/l in relatively shallow wells ([lt] 100 feet) have been detected. Concentrations in excess of 2.0 [mu]g/l, (the USEPA Drinking Water Standard) have been detected in wells where the Cohansey Sand is overlain by the Bridgeton Formation; a fluvial iron-rich sand with some gravelly channel deposits containing goethite and gibbsite nodules. In this study, Bridgeton Fm. sediments were used to determine the sorption kinetics for solutions containing HgCl[sub 2] and for solutions containing dissolved elemental Hgmore » in order to assess the potential for the Bridgeton sediments to act as a conduit for Hg mobilized from the surface. Results of batch equilibrium experiments suggest that dissolved elemental Hg sorbs to Bridgeton sediments by a risk-order kinetic process. Sorption of the Hg proceeded exponentially and equilibrium was reached within 14 hours. The sorption kinetics for the HgCl[sub 2] solutions, however, appear to be of a second or higher order. For this compound sorption to the sediments begins exponentially, but after 6 hours desorption into the water begins to predominate followed by a slower exponential sorption step that requires nearly 36 hours to reach equilibrium. These experiments illustrate the necessity of determining the distribution coefficients of possible source compounds when attempting to evaluate mobilization potential of a contaminant in the unsaturated zone. Moreover, these data also suggest that HgCl[sub 2], a seed dressing for corn, medial bacteriacide, and embalming fluid ingredient, is more mobile in the environment than dissolved elemental Hg. Consequently, the ground water contamination potential appears to be greater for HgCl[sub 2] than for elemental Hg.« less

Analysis of Protein Interactions with Picomolar Binding Affinity by Fluorescence-Detected Sedimentation Velocity

PubMed Central

2014-01-01

The study of high-affinity protein interactions with equilibrium dissociation constants (KD) in the picomolar range is of significant interest in many fields, but the characterization of stoichiometry and free energy of such high-affinity binding can be far from trivial. Analytical ultracentrifugation has long been considered a gold standard in the study of protein interactions but is typically applied to systems with micromolar KD. Here we present a new approach for the study of high-affinity interactions using fluorescence detected sedimentation velocity analytical ultracentrifugation (FDS-SV). Taking full advantage of the large data sets in FDS-SV by direct boundary modeling with sedimentation coefficient distributions c(s), we demonstrate detection and hydrodynamic resolution of protein complexes at low picomolar concentrations. We show how this permits the characterization of the antibody–antigen interactions with low picomolar binding constants, 2 orders of magnitude lower than previously achieved. The strongly size-dependent separation and quantitation by concentration, size, and shape of free and complex species in free solution by FDS-SV has significant potential for studying high-affinity multistep and multicomponent protein assemblies. PMID:24552356

Method to determine 226Ra in small sediment samples by ultralow background liquid scintillation.

PubMed

Sanchez-Cabeza, Joan-Albert; Kwong, Laval Liong Wee; Betti, Maria

2010-08-15

(210)Pb dating of sediment cores is a widely used tool to reconstruct ecosystem evolution and historical pollution during the last century. Although (226)Ra can be determined by gamma spectrometry, this method shows severe limitations which are, among others, sample size requirements and counting times. In this work, we propose a new strategy based on the analysis of (210)Pb through (210)Po in equilibrium by alpha spectrometry, followed by the determination of (226)Ra (base or supported (210)Pb) without any further chemical purification by liquid scintillation and with a higher sample throughput. Although gamma spectrometry might still be required to determine (137)Cs as an independent tracer, the effort can then be focused only on those sections dated around 1963, when maximum activities are expected. In this work, we optimized the counting conditions, calibrated the system for changing quenching, and described the new method to determine (226)Ra in small sediment samples, after (210)Po determination, allowing a more precise determination of excess (210)Pb ((210)Pb(ex)). The method was validated with reference materials IAEA-384, IAEA-385, and IAEA-313.

Passive PE Sampling in Support of In Situ Remediation of Contaminated Sediments

DTIC Science & Technology

2015-08-01

control RPD relative percent difference RSD relative standard deviation SERDP Strategic Environmental Research and Development Program SOPs...sediments from 2 stations, each at 4 PCB spike levels, for four individual congeners was 22 ± 6 % relative standard deviation ( RSD ). Also, comparison of... RSD (Table 3). However, larger congeners (e.g., congeners #153 and 180) whose approach to equilibrium is less certain, based on small fractions of

Supercoiled circular DNA of an insect granulosis virus

PubMed Central

Tweeten, Kathleen A.; Bulla, Lee A.; Consigli, Richard A.

1977-01-01

The DNA of the granulosis virus of the Indian meal moth, Plodia interpunctella, was characterized by physical chemical and electron microscopic techniques. Twenty-five percent of the DNA extracted from purified virus was isolated as supercoiled circular molecules. The remaining 75% consisted of relaxed circular molecules. These molecular forms were indicated by the production of two radioactive bands during sedimentation of 3H-labeled granulosis virus DNA in alkaline sucrose gradients or in equilibrium density gradients of neutral cesium chloride/propidium iodide. Electron microscopic visualization of the DNA that banded at the higher density in the latter gradients revealed supercoiled structures whereas that of DNA that banded at the lower density demonstrated relaxed circular molecules. The superhelical molecules were converted to relaxed circles by treatment with pancreatic DNase. The molecular weight of the viral DNA was calculated to be 81 × 106 by sedimentation in neutral sucrose and 78 × 106 by sedimentation in alkaline sucrose. The molecular weight estimated from length measurements in electron micrographs was 76 × 106. The buoyant density of the granulosis virus DNA was 1.703 g/cm3 and that of its insect host DNA was 1.697 g/cm3. Equilibrium sedimentation in cesium chloride and thermal denaturation indicated G + C contents of 44% and 39% for the viral and host DNA, respectively. Images PMID:198791

Fibulin 5 Forms a Compact Dimer in Physiological Solutions*

PubMed Central

Jones, Richard P. O.; Wang, Ming-Chuan; Jowitt, Thomas A.; Ridley, Caroline; Mellody, Kieran T.; Howard, Marjorie; Wang, Tao; Bishop, Paul N.; Lotery, Andrew J.; Kielty, Cay M.; Baldock, Clair; Trump, Dorothy

2009-01-01

Fibulin 5 is a 52-kDa calcium-binding epidermal growth factor (cbEGF)-rich extracellular matrix protein that is essential for the formation of elastic tissues. Missense mutations in fibulin 5 cause the elastin disorder cutis laxa and have been associated with age-related macular degeneration, a leading cause of blindness. We investigated the structure, hydrodynamics, and oligomerization of fibulin 5 using small angle x-ray scattering, EM, light scattering, circular dichroism, and sedimentation. Compact structures for the monomer were determined by small angle x-ray scattering and EM, and are supported by close agreement between the theoretical sedimentation of the structures and the experimental sedimentation of the monomer in solution. EM showed that monomers associate around a central cavity to form a dimer. Light scattering and equilibrium sedimentation demonstrated that the equilibrium between the monomer and the dimer is dependent upon NaCl and Ca2+ concentrations and that the dimer is dominant under physiological conditions. The dimerization of fragments containing just the cbEGF domains suggests that intermolecular interactions between cbEGFs cause dimerization of fibulin 5. It is possible that fibulin 5 functions as a dimer during elastinogenesis or that dimerization may provide a method for limiting interactions with binding partners such as tropoelastin. PMID:19617354

Supercoiled circular DNA of an insect granulosis virus.

PubMed

Tweeten, K A; Bulla, L A; Consigli, R A

1977-08-01

The DNA of the granulosis virus of the Indian meal moth, Plodia interpunctella, was characterized by physical chemical and electron microscopic techniques. Twenty-five percent of the DNA extracted from purified virus was isolated as supercoiled circular molecules. The remaining 75% consisted of relaxed circular molecules. These molecular forms were indicated by the production of two radioactive bands during sedimentation of (3)H-labeled granulosis virus DNA in alkaline sucrose gradients or in equilibrium density gradients of neutral cesium chloride/propidium iodide. Electron microscopic visualization of the DNA that banded at the higher density in the latter gradients revealed supercoiled structures whereas that of DNA that banded at the lower density demonstrated relaxed circular molecules. The superhelical molecules were converted to relaxed circles by treatment with pancreatic DNase. The molecular weight of the viral DNA was calculated to be 81 x 10(6) by sedimentation in neutral sucrose and 78 x 10(6) by sedimentation in alkaline sucrose. The molecular weight estimated from length measurements in electron micrographs was 76 x 10(6). The buoyant density of the granulosis virus DNA was 1.703 g/cm(3) and that of its insect host DNA was 1.697 g/cm(3). Equilibrium sedimentation in cesium chloride and thermal denaturation indicated G + C contents of 44% and 39% for the viral and host DNA, respectively.

Polyoxymethylene passive samplers to assess the effectiveness of biochar by reducing the content of freely dissolved fipronil and ethiprole.

PubMed

Li, Shasha; Wang, Pingping; Liu, Xingang; Wu, Xiaohu; Dong, Fengshou; Xu, Jun; Zheng, Yongquan

2018-07-15

An equilibrium passive sampler based on polyoxymethylene (POM) was used to determine the freely dissolved concentrations (C free ) of fipronil and ethiprole. The sorption equilibrium times of fipronil and ethiprole in POM were 14.2d and 24.0d, respectively. The POM-water partitioning coefficients (logK POM-water ) were 2.6 for fipronil and 1.4 for ethiprole. The method was further used to evaluate the sorption behavior of biochars which produced by pyrolysis of Magnolia wood (Magnolia denudata) at 300°C, 500°C and 700°C. The amounts of target compounds adsorbed increased with increasing pyrolysis temperature of the biochars. Biochars characterized by a low polarity index had better sorption capacity for the target compounds. The additions of biochars to sediment were effective in reducing C free , and the enhancement was found to be more pronounced with high biochar content. C free in sediment with more organic matter was significantly higher after biochar addition. Increasing the sediment-biochar contact time from 7 to 30d resulted in an increase in sorption of the compounds. We conclude that Magnolia wood biochar effectively reduces the content of freely dissolved fipronil and ethiprole content in sediment. Copyright © 2018. Published by Elsevier B.V.

Investigating uranium distribution in surface sediments and waters: a case study of contamination from the Juniper Uranium Mine, Stanislaus National Forest, CA.

PubMed

Kayzar, Theresa M; Villa, Adam C; Lobaugh, Megan L; Gaffney, Amy M; Williams, Ross W

2014-10-01

The uranium concentrations and isotopic compositions of waters, sediment leachates and sediments from Red Rock Creek in the Stanislaus National Forest of California were measured to investigate the transport of uranium from a point source (the Juniper Uranium Mine) to a natural surface stream environment. The ((234)U)/((238)U) composition of Red Rock Creek is altered downstream of the Juniper Mine. As a result of mine-derived contamination, water ((234)U)/((238)U) ratios are 67% lower than in water upstream of the mine (1.114-1.127 ± 0.009 in the contaminated waters versus 1.676 in the clean branch of the stream), and sediment samples have activity ratios in equilibrium in the clean creek and out of equilibrium in the contaminated creek (1.041-1.102 ± 0.007). Uranium concentrations in water, sediment and sediment leachates are highest downstream of the mine, but decrease rapidly after mixing with the clean branch of the stream. Uranium content and compositions of the contaminated creek headwaters relative to the mine tailings of the Juniper Mine suggest that uranium has been weathered from the mine and deposited in the creek. The distribution of uranium between sediment surfaces (leachable fraction) and bulk sediment suggests that adsorption is a key element of transfer along the creek. In clean creek samples, uranium is concentrated in the sediment residues, whereas in the contaminated creek, uranium is concentrated on the sediment surfaces (∼70-80% of uranium in leachable fraction). Contamination only exceeds the EPA maximum contaminant level (MCL) for drinking water in the sample with the closest proximity to the mine. Isotopic characterization of the uranium in this system coupled with concentration measurements suggest that the current state of contamination in Red Rock Creek is best described by mixing between the clean creek and contaminated upper branch of Red Rock Creek rather than mixing directly with mine sediment. Published by Elsevier Ltd.

Investigating uranium distribution in surface sediments and waters: a case study of contamination from the Juniper Uranium Mine, Stanislaus National Forest, CA

DOE PAGES

Kayzar, Theresa M.; Villa, Adam C.; Lobaugh, Megan L.; ...

2014-06-07

The uranium concentrations and isotopic compositions of waters, sediment leachates and sediments from Red Rock Creek in the Stanislaus National Forest of California were measured to investigate the transport of uranium from a point source (the Juniper Uranium Mine) to a natural surface stream environment. Furthermore, we alter the (234U)/(238U) composition of Red Rock Creek downstream of the Juniper Mine. As a result of mine-derived contamination, water (234U)/(238U) ratios are 67% lower than in water upstream of the mine (1.114–1.127 ± 0.009 in the contaminated waters versus 1.676 in the clean branch of the stream), and sediment samples have activitymore » ratios in equilibrium in the clean creek and out of equilibrium in the contaminated creek (1.041–1.102 ± 0.007). Uranium concentrations in water, sediment and sediment leachates are highest downstream of the mine, but decrease rapidly after mixing with the clean branch of the stream. Uranium content and compositions of the contaminated creek headwaters relative to the mine tailings of the Juniper Mine suggest that uranium has been weathered from the mine and deposited in the creek. The distribution of uranium between sediment surfaces (leachable fraction) and bulk sediment suggests that adsorption is a key element of transfer along the creek. In clean creek samples, uranium is concentrated in the sediment residues, whereas in the contaminated creek, uranium is concentrated on the sediment surfaces (~70–80% of uranium in leachable fraction). Furthermore, contamination only exceeds the EPA maximum contaminant level (MCL) for drinking water in the sample with the closest proximity to the mine. Isotopic characterization of the uranium in this system coupled with concentration measurements suggest that the current state of contamination in Red Rock Creek is best described by mixing between the clean creek and contaminated upper branch of Red Rock Creek rather than mixing directly with mine sediment.« less

Post-tsunami beach recovery in Thailand: A case for punctuated equilibrium in coastal dynamics

NASA Astrophysics Data System (ADS)

Switzer, Adam D.; Gouramanis, Chris; Bristow, Charles; Yeo, Jeffrey; Kruawun, Jankaew; Rubin, Charles; Sin Lee, Ying; Tien Dat, Pham

2017-04-01

A morpho-geophysical investigation of two beaches in Thailand over the last decade shows that they have completely recovered from the 2004 Indian Ocean tsunami (IOT) without any human intervention. Although the beach systems show contrasting styles of recovery in both cases natural processes have reconstructed the beaches to comparable pre-tsunami morphologies in under a decade, demonstrating the existence of punctuated equilibrium in coastal systems and the resilience of natural systems to catastrophic events. Through a combination of remote sensing, field surveys and shallow geophysics we reconstruct the post-event recovery of beaches at Phra Thong Island, a remote, near pristine site that was severely impacted by the IOT. We identify periods of aggradation, progradation and washover sedimentation that match with local events including a storm in November 2007. The rapid recovery of these systems implies that majority of sediment scoured by the tsunami was not transported far offshore but remained in the littoral zone within reach of fair-weather waves that returned it (the sediment) to the beach naturally.

Tubulin Dimer Reversible Dissociation

PubMed Central

Schuck, Peter; Sackett, Dan L.

2016-01-01

Tubulins are evolutionarily conserved proteins that reversibly polymerize and direct intracellular traffic. Of the tubulin family only αβ-tubulin forms stable dimers. We investigated the monomer-dimer equilibrium of rat brain αβ-tubulin using analytical ultracentrifugation and fluorescence anisotropy, observing tubulin in virtually fully monomeric and dimeric states. Monomeric tubulin was stable for a few hours and exchanged into preformed dimers, demonstrating reversibility of dimer dissociation. Global analysis combining sedimentation velocity and fluorescence anisotropy yielded Kd = 84 (54–123) nm. Dimer dissociation kinetics were measured by analyzing the shape of the sedimentation boundary and by the relaxation of fluorescence anisotropy following rapid dilution of labeled tubulin, yielding koff in the range 10−3–10−2 s−1. Thus, tubulin dimers reversibly dissociate with moderately fast kinetics. Monomer-monomer association is much less sensitive than dimer-dimer association to solution changes (GTP/GDP, urea, and trimethylamine oxide). PMID:26934918

U-Th and 10Be constraints on sediment recycling in proglacial settings, Lago Buenos Aires, Patagonia

NASA Astrophysics Data System (ADS)

Cogez, Antoine; Herman, Frédéric; Pelt, Éric; Reuschlé, Thierry; Morvan, Gilles; Darvill, Christopher M.; Norton, Kevin P.; Christl, Marcus; Märki, Lena; Chabaux, François

2018-03-01

The estimation of sediment transfer times remains a challenge to our understanding of sediment budgets and the relationships between erosion and climate. Uranium (U) and thorium (Th) isotope disequilibria offer a means of more robustly constraining sediment transfer times. Here, we present new uranium and thorium disequilibrium data for a series of nested moraines around Lago Buenos Aires in Argentine Patagonia. The glacial chronology for the area is constrained using in situ cosmogenic 10Be analysis of glacial outwash. Sediment transfer times within the periglacial domain were estimated by comparing the deposition ages of moraines to the theoretical age of sediment production, i.e., the comminution age inferred from U disequilibrium data and recoil loss factor estimates. Our data show first that the classical comminution age approach must include weathering processes accounted for by measuring Th disequilibrium. Second, our combined data suggest that the pre-deposition history of the moraine sediments is not negligible, as evidenced by the large disequilibrium of the youngest moraines despite the equilibrium of the corresponding glacial flour. Monte Carlo simulations suggest that weathering was more intense before the deposition of the moraines and that the transfer time of the fine sediments to the moraines was on the order of 100-200 kyr. Long transfer times could result from a combination of long sediment residence times in the proglacial lake (recurrence time of a glacial cycle) and the remobilization of sediments from moraines deposited during previous glacial cycles. 10Be data suggest that some glacial cycles are absent from the preserved moraine record (seemingly every second cycle), supporting a model of reworking moraines and/or fluctuations in the extent of glacial advances. The chronological pattern is consistent with the U-Th disequilibrium data and the 100-200 kyr transfer time. This long transfer time raises the question of the proportion of freshly eroded sediments that escape (or not) the proglacial environments during glacial periods.

Molecular weight and oligomerization of rabbit thrombomodulin as assessed by sedimentation equilibrium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Winnard, P.T.; Esmon, C.T.; Laue, T.M.

1989-02-15

Lubrol-solubilized rabbit thrombomodulin has been examined by equilibrium sedimentation in buffers that include sufficient D/sub 2/O to make the detergent neutrally buoyant. Data were acquired at rotor speeds from 12,000 to 28,000 rpm from two thrombomodulin preparations, at protein concentrations from 0.01 to 0.07%, and in buffer containing 0.01 to 0.23% Lubrol. Examination of the data from different rotor speeds shows that the thrombomodulin exists as a heterogeneous mixture containing monomer (Mr 65,000), trimer, and higher oligomers. The oligomers do not equilibrate over the time scale of the experiment. The weight fraction as monomer varies from preparation to preparation, andmore » appears to be independent of detergent concentration. Thus, experimenters should be cautious when interpreting binding or kinetic results obtained under similar buffer conditions.« less

Pyrethroid sorption to Sacramento River suspended solids and bed sediments

PubMed Central

Fojut, Tessa L.; Young, Thomas M.

2011-01-01

Sorption of pyrethroid insecticides to solid materials will typically dominate the fate and transport of these hydrophobic compounds in aquatic environments. Batch reactor isotherm experiments were performed with bifenthrin and λ-cyhalothrin with suspended material and bed sediment collected from the Sacramento River, CA. These batch reactor experiments were performed with low spiking concentrations and a long equilibration time (28 d) to be more relevant to environmental conditions. Sorption to suspended material and bed sediment was compared to examine the role of differential sorption between these phases in the environmental transport of pyrethroids. The equilibrium sorption data were fit to the Freundlich isotherm model and fit with r2 > 0.87 for all experiments. Freundlich exponents ranged from 0.72 ± 0.19 to 1.07 ± 0.050, indicating sorption nonlinearity for some of the experimental conditions and linearity for others over the concentration range tested. The Freundlich capacity factors were larger for the suspended solids than for the bed sediments and the suspended material had a higher specific surface area and higher organic carbon content compared to the bed sediment. Calculated organic carbon-normalized distribution coefficients were larger than those previously reported in the literature by approximately an order of magnitude and ranged from 106.16 to 106.68 at an equilibrium aqueous concentration of 0.1 µg/L. Higher than expected sorption of pyrethroids to the tested materials may be explained by sorption to black carbon and/or mineral surfaces. PMID:21191877

Copper isotope signatures in modern marine sediments

NASA Astrophysics Data System (ADS)

Little, Susan H.; Vance, Derek; McManus, James; Severmann, Silke; Lyons, Timothy W.

2017-09-01

The development of metal stable isotopes as tools in paleoceanography requires a thorough understanding of their modern marine cycling. To date, no Cu isotope data has been published for modern sediments deposited under low oxygen conditions. We present data encompassing a broad spectrum of hydrographic and redox regimes, including continental margin and euxinic (sulphide-containing) settings. Taken together with previously published data from oxic settings, these data indicate that the modern oceanic sink for Cu has a surprisingly homogeneous isotopic composition of about +0.3‰ (δ65Cu, relative to NIST SRM976). We suggest that this signature reflects one of two specific water-column processes: (1) an equilibrium isotope fractionation between soluble, isotopically heavy, Cu complexed to strong organic ligands and an isotopically light pool sorbed to particles that deliver Cu to the sediment, or (2) an equilibrium isotope fractionation between the same isotopically heavy ligand-bound pool and the particle reactive free Cu2+ species, with the latter being scavenged by particulates and thereby delivered to the sediment. An output flux of about +0.3‰ into sediments is isotopically light relative to the known inputs to the ocean (at around +0.6‰) and the seawater value of +0.6 to +0.9‰, suggesting the presence of an as yet unidentified isotopically light source of Cu to the oceans. We hypothesize that this source may be hydrothermal, or may result from the partial dissolution of continentally derived particles.

Modelling potential impacts of bottom trawl fisheries on soft sediment biogeochemistry in the North Sea†

PubMed Central

Duplisea, Daniel E; Jennings, Simon; Malcolm, Stephen J; Parker, Ruth; Sivyer, David B

2001-01-01

Bottom trawling causes physical disturbance to sediments particularly in shelf areas. The disturbance due to trawling is most significant in deeper areas with softer sediments where levels of natural disturbance due to wave and tidal action are low. In heavily fished areas, trawls may impact the same area of seabed more than four times per year. A single pass of a beam trawl, the heaviest gear routinely used in shelf sea fisheries, can kill 5–65% of the resident fauna and mix the top few cm of sediment. We expect that sediment community function, carbon mineralisation and biogeochemical fluxes will be strongly affected by trawling activity because the physical effects of trawling are equivalent to those of an extreme bioturbator, and yet, unlike bioturbating macrofauna, trawling does not directly contribute to community metabolism. We used an existing box-model of a generalised soft sediment system to examine the effects of trawling disturbance on carbon mineralisation and chemical concentrations. We contrasted the effects of a natural scenario, where bioturbation is a function of macrobenthos biomass, with an anthropogenic impact scenario where physical disturbance results from trawling rather than the action of bioturbating macrofauna. Simulation results suggest that the effects of low levels of trawling disturbance will be similar to those of natural bioturbators but that high levels of trawling disturbance prevent the modelled system from reaching equilibrium due to large carbon fluxes between oxic and anoxic carbon compartments. The presence of macrobenthos in the natural disturbance scenario allowed sediment chemical storage and fluxes to reach equilibrium. This is because the macrobenthos are important carbon consumers in the system whose presence reduces the magnitude of available carbon fluxes. In soft sediment systems, where the level physical disturbance due to waves and tides is low, model results suggest that intensive trawling disturbance could cause large fluctuations in benthic chemical fluxes and storage. PMID:16759420

Modelling potential impacts of bottom trawl fisheries on soft sediment biogeochemistry in the North Sea.

PubMed

Duplisea, D E; Jennings, S; Malcolm, S J; Parker, R; Sivyer, D B

2001-12-19

Bottom trawling causes physical disturbance to sediments particularly in shelf areas. The disturbance due to trawling is most significant in deeper areas with softer sediments where levels of natural disturbance due to wave and tidal action are low. In heavily fished areas, trawls may impact the same area of seabed more than four times per year. A single pass of a beam trawl, the heaviest gear routinely used in shelf sea fisheries, can kill 5-65% of the resident fauna and mix the top few cm of sediment. We expect that sediment community function, carbon mineralisation and biogeochemical fluxes will be strongly affected by trawling activity because the physical effects of trawling are equivalent to those of an extreme bioturbator, and yet, unlike bioturbating macrofauna, trawling does not directly contribute to community metabolism. We used an existing box-model of a generalised soft sediment system to examine the effects of trawling disturbance on carbon mineralisation and chemical concentrations. We contrasted the effects of a natural scenario, where bioturbation is a function of macrobenthos biomass, with an anthropogenic impact scenario where physical disturbance results from trawling rather than the action of bioturbating macrofauna. Simulation results suggest that the effects of low levels of trawling disturbance will be similar to those of natural bioturbators but that high levels of trawling disturbance prevent the modelled system from reaching equilibrium due to large carbon fluxes between oxic and anoxic carbon compartments. The presence of macrobenthos in the natural disturbance scenario allowed sediment chemical storage and fluxes to reach equilibrium. This is because the macrobenthos are important carbon consumers in the system whose presence reduces the magnitude of available carbon fluxes. In soft sediment systems, where the level physical disturbance due to waves and tides is low, model results suggest that intensive trawling disturbance could cause large fluctuations in benthic chemical fluxes and storage.

Polycyclic aromatic hydrocarbon (PAH)-phase associations in Washington coastal sediment

NASA Astrophysics Data System (ADS)

Prahl, Fredrick G.; Carpenter, Roy

1983-06-01

Polycyclic aromatic (PAH) and aliphatic hydrocarbon compositions, organic carbon, nitrogen and lignin contents were determined in whole, unfractionated sediment from the Washington continental shelf and in discrete sediment fractions separated by particle size and density. At least 20 to 25% of perylene and PAH derived from pyrolytic processes and 50% of the retene measured in whole sediment are contained within organic C- and lignin-rich panicles of density ≤ 1.9 g/cc. These particles, which include primarily vascular plant remains and bits of charcoal, comprise less than 1% of the total sediment weight. In contrast, a series of methylated phenanthrene homologs, possibly of fossil origin, are concentrated in some component of the more dense, lithic matrix of the sediment. Equilibrium models of PAH sorption/desorption from aqueous phase onto small particles of high surface area do not appear applicable to the behavior of the major PAH types identified in this aquatic environment.

A Non-Equilibrium Sediment Transport Model for Coastal Inlets and Navigation Channels

DTIC Science & Technology

2011-01-01

exchange of water , sediment, and nutrients between estuaries and the ocean. Because of the multiple interacting forces (waves, wind, tide, river...in parallel using OpenMP. The CMS takes advantage of the Surface- water Modeling System (SMS) interface for grid generation and model setup, as well...as for plotting and post- processing (Zundel, 2000). The circulation model in the CMS (called CMS-Flow) computes the unsteady water level and

Response of a channel with alternate bars to a decrease in supple of mixed-size bedload: A flume experiment

Treesearch

Thomas E. Lisle; Fujiko Iseya; Hiroshi Ikeda

1993-01-01

The response of a channel with a topography and modeled bed material size typical of gravel bed rivers to reductions in sediment supply was investigated in a laboratory flume filled and fed with a sand-gravel mixture. After a series of quasi-stationary alternate bars were formed under equilibrium sediment transport, feed rate was reduced in two steps to one third and...

Headwater peatland channels in south-eastern Australia; the attainment of equilibrium

NASA Astrophysics Data System (ADS)

Nanson, R. A.; Cohen, T. J.

2014-05-01

Many small headwater catchments (< 50 km2) in temperate south-eastern Australia store sediment in valley fills. While accumulation in some of these systems commenced up to 30,000 years ago, most did not commence filling with peat or clastic material until at least the mid Holocene. In such headwater settings, many clastic valley fills develop cut-and-fill channels, which contrast to some peatland settings where sinuous equilibrium channels have evolved. Four peatland systems within this dataset demonstrate stable channel systems which span nearly the full spectrum of observed valley-floor slopes. We assess new and published longitudinal data from these four channels and demonstrate that each of these channels has achieved equilibrium profiles. New and published flow and survey data are synthesised to demonstrate how these peatland systems have attained equilibrium. Low rates of sediment supply and exceptionally high bank strengths have resulted in low width to depth ratios which accommodate rapid changes in flow velocity and depth with changes in discharge. In small peatland channels, planform adjustments have been sufficient to counter the energy provided by these hydraulically efficient cross-sections and have enabled the achievement of regime energy-slopes. In larger and higher energy peatland channels, large, armoured, stable, bedforms have developed. These bedforms integrate with planform adjustments to maintain a condition of minimum variance in energy losses as represented by the slope profiles and, therefore, a uniform increase in downstream entropy.

Simulation of the mobility of metal - EDTA complexes in groundwater: The influence of contaminant metals

USGS Publications Warehouse

Friedly, J.C.; Kent, D.B.; Davis, J.A.

2002-01-01

Reactive transport simulations were conducted to model chemical reactions between metal - EDTA (ethylenediaminetetraacetic acid) complexes during transport in a mildly acidic quartz - sand aquifer. Simulations were compared with the results of small-scale tracer tests wherein nickel-, zinc-, and calcium - EDTA complexes and free EDTA were injected into three distinct chemical zones of a plume of sewage-contaminated groundwater. One zone had a large mass of adsorbed, sewage-derived zinc; one zone had a large mass of adsorbed manganese resulting from mildly reducing conditions created bythe sewage plume; and one zone had significantly less adsorbed manganese and negligible zinc background. The chemical model assumed that the dissolution of iron(III) from metal - hydroxypolymer coatings on the aquifer sediments by the metal - EDTA complexes was kinetically restricted. All other reactions, including metal - EDTA complexation, zinc and manganese adsorption, and aluminum hydroxide dissolution were assumed to reach equilibrium on the time scale of transport; equilibrium constants were either taken from the literature or determined independently in the laboratory. A single iron(III) dissolution rate constant was used to fit the breakthrough curves observed in the zone with negligible zinc background. Simulation results agreed well with the experimental data in all three zones, which included temporal moments derived from breakthrough curves at different distances downgradient from the injections and spatial moments calculated from synoptic samplings conducted at different times. Results show that the tracer cloud was near equilibrium with respect to Fe in the sediment after 11 m of transport in the Zn-contaminated region but remained far from equilibrium in the other two zones. Sensitivity studies showed that the relative rate of iron(III) dissolution by the different metal - EDTA complexes was less important than the fact that these reactions are rate controlled. Results suggest that the published solubility for ferrihydrite reasonably approximates the Fe solubility of the hydroxypolymer coatings on the sediments. Aluminum may be somewhat more soluble than represented by the equilibrium constant for gibbsite, and its dissolution may be rate controlled when reacting with Ca - EDTA complexes.

Reanalysis of in situ permeability measurements in the Barbados décollement

USGS Publications Warehouse

Bekins, B.A.; Matmon, D.; Screaton, E.J.; Brown, K.M.

2011-01-01

A cased and sealed borehole in the Northern Barbados accretionary complex was the site of the first attempts to measure permeability in situ along a plate boundary décollement. Three separate efforts at Hole 949C yielded permeability estimates for the décollement spanning four orders of magnitude. An analysis of problems encountered during installation of the casing and seals provides insights into how the borehole conditions may have led to the wide range of results. During the installation, sediments from the surrounding formation repeatedly intruded into the borehole and casing. Stress analysis shows that the weak sediments were deforming plastically and the radial and tangential stresses around the borehole were significantly lower than lithostatic. This perturbed stress state may explain why the test pressure records showed indications of hydrofracture at pressures below lithostatic, and permeabilities rose rapidly as the estimated effective stress dropped below 0.8 MPa. Even after the borehole was sealed, the plastic deformation of the formation and relatively large gap of the wire wrapped screen allowed sediment to flow into the casing. Force equilibrium calculations predict sediment would have filled the borehole to 10 cm above the top of the screen by the time slug tests were conducted 1.5 years after the borehole was sealed. Reanalysis of the slug test results with these conditions yields several orders of magnitude higher permeability estimates than the original analysis which assumed an open casing. Overall the results based on only the tests with no sign of hydrofracture yield a permeability range of 10−14–10−15 m2 and a rate of increase in permeability with decreasing effective stress consistent with laboratory tests on samples from the décollement zone.

Ultraviolet light-resistant primary transfectants of xeroderma pigmentosum cells are also DNA repair-proficient

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stark, M.; Naiman, T.; Canaani, D.

1989-08-15

In a previous work, an immortal xeroderma pigmentosum cell line belonging to complementation group C was complemented to a UV-resistant phenotype by transfection with a human cDNA clone library. We now report that the primary transformants selected for UV-resistance also acquired normal levels of DNA repair. This was assessed both by measurement of UV-induced ({sup 3}H)thymidine incorporation and by equilibrium sedimentation analysis of repair-DNA synthesis. Therefore, the transduced DNA element which confers normal UV-resistance also corrects the excision repair defect of the xeroderma pigmentosum group C cell line.

Passive sampling methods for contaminated sediments: State of the science for organic contaminants

PubMed Central

Lydy, Michael J; Landrum, Peter F; Oen, Amy MP; Allinson, Mayumi; Smedes, Foppe; Harwood, Amanda D; Li, Huizhen; Maruya, Keith A; Liu, Jingfu

2014-01-01

This manuscript surveys the literature on passive sampler methods (PSMs) used in contaminated sediments to assess the chemical activity of organic contaminants. The chemical activity in turn dictates the reactivity and bioavailability of contaminants in sediment. Approaches to measure specific binding of compounds to sediment components, for example, amorphous carbon or specific types of reduced carbon, and the associated partition coefficients are difficult to determine, particularly for native sediment. Thus, the development of PSMs that represent the chemical activity of complex compound–sediment interactions, expressed as the freely dissolved contaminant concentration in porewater (Cfree), offer a better proxy for endpoints of concern, such as reactivity, bioaccumulation, and toxicity. Passive sampling methods have estimated Cfree using both kinetic and equilibrium operating modes and used various polymers as the sorbing phase, for example, polydimethylsiloxane, polyethylene, and polyoxymethylene in various configurations, such as sheets, coated fibers, or vials containing thin films. These PSMs have been applied in laboratory exposures and field deployments covering a variety of spatial and temporal scales. A wide range of calibration conditions exist in the literature to estimate Cfree, but consensus values have not been established. The most critical criteria are the partition coefficient between water and the polymer phase and the equilibrium status of the sampler. In addition, the PSM must not appreciably deplete Cfree in the porewater. Some of the future challenges include establishing a standard approach for PSM measurements, correcting for nonequilibrium conditions, establishing guidance for selection and implementation of PSMs, and translating and applying data collected by PSMs. Integr Environ Assess Manag 2014;10:167–178. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. PMID:24307344

Degradation of rizazole in water-sediment systems.

PubMed

Zhang, Changpeng; Zhao, Hua; Ping, Lifeng; Cai, Xiaoming; Wu, Min; He, Hongmei; Zhang, Chunrong; Zhu, Yahong; Li, Zhen

2013-01-01

This study investigated the degradation of rizazole in water-sediment systems (West Lake system, WL; Beijing-Hangzhou Grand Canal system, BG) with two different types of sediments under aerobic and anaerobic conditions. The half-lives of rizazole in the WL water phase (14.59-15.13 d) were similar to those in the BG water phase (15.90-16.46 d). Within 3-7 d, the rizazole concentration in the sediments reached the maximum values, i.e., equilibrium. Rizazole dissipation was faster in the WL sediment phase with higher organic matter content (T(1/2) = 18.99-19.09 d) compared with the BG sediment phase (T(1/2) = 31.08-33.32 d). Rizazole degradation was slightly faster in the West Lake water-sediment system (WL system) (T(1/2) = 17.11-18.05 d) than in the Beijing-Hangzhou Grand Canal water-sediment system (BG system) (T(1/2) = 20.51-25.02 d). The aerobic degradation of rizazole was similar to its anaerobic degradation in the water-sediment system. The findings are useful to understand the behavior of pesticide in environment.

Study on the sorption behaviour of estrone on marine sediments.

PubMed

Zhang, Jing; Yang, Gui-Peng; Li, Quan; Cao, Xiaoyan; Liu, Guangxing

2013-11-15

The sorption behaviour of estrone (E1) on marine sediments treated by different methods was systematically investigated. About 22 h was required for sorption equilibrium of E1. Sorption isotherms of E1 were well fitted with Freundlich model. The sorption behaviour of E1 on HCl-treatment and H2O-treatment sediments related significantly with the sediment organic carbon contents. Additionally, clay minerals and surface areas of sediments played dominant roles in the sorption of E1 on H2O2-treatment sediments. Some external factors which could affect sorption behaviour of E1 were also investigated. Our results showed that the sorption capacity of E1 on the sediments increased with the increasing concentrations of cationic surfactant cetyltrimethylammonium bromide (CTAB), nonionic surfactant polyoxyethylene (80) sorbitan esters (Tween 80) and salinity of seawater. In contrast, the sorption capacity of E1 decreased with the increasing concentration of anionic surfactant sodium dodecylbenzene sulfonate (SDBS), pH value and temperature of seawater. Copyright © 2013 Elsevier Ltd. All rights reserved.

Simulated oil release from oil-contaminated marine sediment in the Bohai Sea, China.

PubMed

Yuan, Lingling; Han, Longxi; Bo, Wenjie; Chen, Hua; Gao, Wenshen; Chen, Bo

2017-05-15

There is a high degree of heavy oil partitioning into marine sediments when an oil spill occurs. Contaminated sediment, as an endogenous pollution source, can re-pollute overlying water slowly. In this study, a static oil release process and its effects in marine sediment was investigated through a series of experiments with reproductive heavy oil-contaminated marine sediment. The oil release process was accurately simulated with a Lagergren first-order equation and reached equilibration after 48h. The fitted curve for equilibrium concentration (C 0 ) and first-order rate constant (k 1 ) for sediment pollution levels exhibited a first-order log relationship. The instantaneous release rate (dC t dt) was also calculated. The C 0 increased with increases in temperature and dissolved organic matter (DOM), and decreasing salinity. The k 1 increased with temperature, but was not affected by DOM and salinity. These results can be used to better understand the fate of heavy oil in contaminated sediments of the Bohai Sea. Copyright © 2017. Published by Elsevier Ltd.

Processes of nickel and cobalt uptake by a manganese oxide forming sediment in Pinal Creek, Globe mining district, Arizona

USGS Publications Warehouse

Kay, J.T.; Conklin, M.H.; Fuller, C.C.; O'Day, P. A.

2001-01-01

A series of column experiments was conducted using manganese oxide coated sediments collected from the hyporheic zone in Pinal Creek (AZ), a metal-contaminated stream, to study the uptake and retention of Mn, Ni, and Co. Experimental variables included the absence (abiotic) and presence (biotic) of active Mn-oxidizing bacteria, the absence and presence of dissolved Mn, and sediment manganese oxide content. Uptake of Mn under biotic conditions was between 8 and 39% higher than under abiotic conditions. Continuous uptake of Mn due to biotic oxidation was evident from extraction of column sediments. Manganese uptake is hypothesized to initially occur as adsorption, which led to subsequent surface and/or microbial oxidation. Complete breakthrough of Ni within 100 pore volumes indicated no process of continuous uptake and was modeled as an equilibrium adsorption process. Nickel uptake in the presence of dissolved Mn was 67-100% reversible. Sediment extractions suggest that Ni uptake occurred through weak and strong adsorption. Continuous uptake of cobalt increased with sediment manganese oxide content, and Co uptake was up to 75% greater under biotic than abiotic conditions. Cobalt uptake was controlled by both existing and newly formed manganese oxides. Only a small amount of Co uptake was reversible (10-25%). XANES spectral analysis indicated that most Co(II) was oxidized to Co(III) and probably incorporated structurally into manganese oxides. Although manganese oxides were the primary phase controlling uptake and retention of Mn, Ni, and Co, the mechanisms varied among the metals.

Sediment supply controls equilibrium channel geometry in gravel rivers

PubMed Central

Finnegan, Noah J.; Willenbring, Jane K.

2017-01-01

In many gravel-bedded rivers, floods that fill the channel banks create just enough shear stress to move the median-sized gravel particles on the bed surface (D50). Because this observation is common and is supported by theory, the coincidence of bankfull flow and the incipient motion of D50 has become a commonly used assumption. However, not all natural gravel channels actually conform to this simple relationship; some channels maintain bankfull stresses far in excess of the critical stress required to initiate sediment transport. We use a database of >300 gravel-bedded rivers and >600 10Be-derived erosion rates from across North America to explore the hypothesis that sediment supply drives the magnitude of bankfull shear stress relative to the critical stress required to mobilize the median bed surface grain size (τbf*/τc*). We find that τbf*/τc* is significantly higher in West Coast river reaches (2.35, n = 96) than in river reaches elsewhere on the continent (1.03, n = 245). This pattern parallels patterns in erosion rates (and hence sediment supplies). Supporting our hypothesis, we find a significant correlation between upstream erosion rate and local τbf*/τc* at sites where this comparison is possible. Our analysis reveals a decrease in bed surface armoring with increasing τbf*/τc*, suggesting channels accommodate changes in sediment supply through adjustments in bed surface grain size, as also shown through numerical modeling. Our findings demonstrate that sediment supply is encoded in the bankfull hydraulic geometry of gravel bedded channels through its control on bed surface grain size. PMID:28289212

3D-Printing for Analytical Ultracentrifugation

PubMed Central

Desai, Abhiksha; Krynitsky, Jonathan; Pohida, Thomas J.; Zhao, Huaying

2016-01-01

Analytical ultracentrifugation (AUC) is a classical technique of physical biochemistry providing information on size, shape, and interactions of macromolecules from the analysis of their migration in centrifugal fields while free in solution. A key mechanical element in AUC is the centerpiece, a component of the sample cell assembly that is mounted between the optical windows to allow imaging and to seal the sample solution column against high vacuum while exposed to gravitational forces in excess of 300,000 g. For sedimentation velocity it needs to be precisely sector-shaped to allow unimpeded radial macromolecular migration. During the history of AUC a great variety of centerpiece designs have been developed for different types of experiments. Here, we report that centerpieces can now be readily fabricated by 3D printing at low cost, from a variety of materials, and with customized designs. The new centerpieces can exhibit sufficient mechanical stability to withstand the gravitational forces at the highest rotor speeds and be sufficiently precise for sedimentation equilibrium and sedimentation velocity experiments. Sedimentation velocity experiments with bovine serum albumin as a reference molecule in 3D printed centerpieces with standard double-sector design result in sedimentation boundaries virtually indistinguishable from those in commercial double-sector epoxy centerpieces, with sedimentation coefficients well within the range of published values. The statistical error of the measurement is slightly above that obtained with commercial epoxy, but still below 1%. Facilitated by modern open-source design and fabrication paradigms, we believe 3D printed centerpieces and AUC accessories can spawn a variety of improvements in AUC experimental design, efficiency and resource allocation. PMID:27525659

Equilibrium Partitioning Sediment Guidelines (ESGs) for the ...

EPA Pesticide Factsheets

... PLC = partial life-cycle ... 5 ii mini iiiiiiiii iiiiiii mi 1 1 iii mini ii i B : - Benthic vs WQC i— w ~_ ~ _ o° _ -0 ° - - - ii mini iiiiiiiii iiiiiii iiiiiiiii mini ii 0.1 ... PhD thesis. ...

The equilibrium sedimentation of hyaluronic acid and of two synthetic polymers

PubMed Central

Nichol, L. W.; Ogston, A. G.; Preston, B. N.

1967-01-01

1. The method of equilibrium sedimentation has been investigated as an alternative to osmotic-pressure measurement for determining thermodynamic properties of polymer solutions at relatively high concentrations. 2. The simplifications that must be made in the theoretical treatment are discussed. 3. Measurements have been made on samples of polyethylene glycol, neutralized polymethacrylic acid and hyaluronic acid. With the first and third, values of the `non-ideality coefficients' have been obtained that agree with those obtained from osmotic measurements on the same materials. 4. Evidence has been obtained of the presence in hyaluronic acid preparations of a fraction that has either a lower degree of thermodynamic non-ideality or a higher density increment than the bulk of the sample. This fraction is not protein. ImagesFig. 3.Fig. 4.Fig. 5.Fig. 7.Fig. 8.Fig. 9.Fig. 11.Fig. 12.Fig. 13.Fig. 14. PMID:6029600

Analytical Model of Inlet Growth and Equilibrium Cross-Sectional Area

DTIC Science & Technology

2016-04-01

performance in a real-world setting. BACKGROUND: Long-term inlet stability in bar-built systems is determined by the tidal and wave forces that...across the node was limited due to convergence of the two incoming tidal waves . As such, the equivalent bay area was calculated using the midpoint as a...sediment transport is driven by tides and does not incorporate other forcing and associated sediment pathways. The ratio of wave to tidal energy is an

Seasonal variations of natural radionuclides, minor and trace elements in lake sediments and water in a lignite mining area of North-Western Greece.

PubMed

Noli, Fotini; Tsamos, Panagiotis

2018-05-01

The radiological and chemical pollution of a cluster of four lakes in a lignite mining area of North-Western Greece was investigated using a variety of analytical techniques. Alpha spectrometry was applied to measure the activity concentrations of the uranium radioisotopes (U-234, U-235, and U-238) in waters. The mass activities of U-238, Th-232, and K-40 in sediments were measured by high-resolution gamma spectrometry. Furthermore, the determination of the minor and trace elements was carried out by instrumental neutron activation analysis (INAA) in both water and sediments samples, respectively. Pollution levels were also evaluated by calculating enrichment factors (EFs), contamination factors (CFs) and pollution load index (PLI). The data were discussed taking into account several parameters such as the distance from the pollution source, temperature, and location and showed that the environmental impact in this region could not be considered as negligible. The deviation of the isotopic ratio of U-234/U-238 from the equilibrium value indicated waters with intensive dissolution of uranium. The activity values in both waters and sediments found to be low in cool periods and increased in warm periods. Moreover, the concentrations of the elements U, Zn, and Fe were raised in water samples indicating possible pollution as well as the CFs and PLI denoted accumulation in the sediments and moderate to severe contamination for Zn and Cr in some cases.

Pyrethroid sorption to Sacramento River suspended solids and bed sediments.

PubMed

Fojut, Tessa L; Young, Thomas M

2011-04-01

Sorption of pyrethroid insecticides to solid materials will typically dominate the fate and transport of these hydrophobic compounds in aquatic environments. Batch reactor isotherm experiments were performed with bifenthrin and λ-cyhalothrin with suspended material and bed sediment collected from the Sacramento River, California, USA. These batch reactor experiments were performed with low spiking concentrations and a long equilibration time (28 d) to be more relevant to environmental conditions. Sorption to suspended material and bed sediment was compared to examine the role of differential sorption between these phases in the environmental transport of pyrethroids. The equilibrium sorption data were fit to the Freundlich isotherm model and fit with r(2)  > 0.87 for all experiments. Freundlich exponents ranged from 0.72 ± 0.19 to 1.07 ± 0.050, indicating sorption nonlinearity for some of the experimental conditions and linearity for others over the concentration range tested. The Freundlich capacity factors were larger for the suspended solids than for the bed sediments, and the suspended material had a higher specific surface area and higher organic carbon content compared to the bed sediment. Calculated organic carbon-normalized distribution coefficients were larger than those previously reported in the literature, by approximately an order of magnitude, and ranged from 10(6.16) to 10(6.68) at an equilibrium aqueous concentration of 0.1 µg/L. Higher than expected sorption of pyrethroids to the tested materials may be explained by sorption to black carbon and/or mineral surfaces. Copyright © 2011 SETAC.

The Piedmont landscape of Maryland: a new look at an old problem.

USGS Publications Warehouse

Costa, J.E.; Cleaves, E.T.

1984-01-01

Both equilibrium and episodic erosion features can be recognized in the modern landscape. An equilibrium condition is suggested by adjustment of first and second order streams to rock structure and lithology, entrenchment of some streams against gneiss domes, altitudinal zonation of rock types around gneiss domes, correlation of lithology with overburden thickness on uplands, etc. The long-term episodic character of erosion is suggested by clastic wedges on the adjacent Coastal Plain, an upland of low relief that truncates non-carbonate rocks of different lithologies, isovolumetric chemical weathering of alumino-silicate rocks, clastic deposition in marble valleys, and weathering profile truncation by modern drainage. The upland surface preserved in the eastern Piedmont developed by the Late Cretaceous. In the interval from the Late Cretaceous to the Late Miocene, low input of terrigenous sediments to the Coastal Plain, dominance of marine sedimentation, and spotty evidence of saprolite formation on crystalline rocks, suggest that the Maryland Piedmont was an area of low relief undergoing intense weathering. Incised valleys were formed during a cycle of erosion probably initiated in the Late Miocene and extensive colluvial sediments were deposited on hillslopes by periglacial processes during the Pleistocene.-after Authors

A centennial tribute to G.K. Gilbert's Hydraulic Mining Débris in the Sierra Nevada

NASA Astrophysics Data System (ADS)

James, L. A.; Phillips, J. D.; Lecce, S. A.

2017-10-01

G.K. Gilbert's (1917) classic monograph, Hydraulic-Mining Débris in the Sierra Nevada, is described and put into the context of modern geomorphic knowledge. The emphasis here is on large-scale applied fluvial geomorphology, but other key elements-e.g., coastal geomorphology-are also briefly covered. A brief synopsis outlines key elements of the monograph, followed by discussions of highly influential aspects including the integrated watershed perspective, the extreme example of anthropogenic sedimentation, computation of a quantitative, semidistributed sediment budget, and advent of sediment-wave theory. Although Gilbert did not address concepts of equilibrium and grade in much detail, the rivers of the northwestern Sierra Nevada were highly disrupted and thrown into a condition of nonequilibrium. Therefore, concepts of equilibrium and grade-for which Gilbert's early work is often cited-are discussed. Gilbert's work is put into the context of complex nonlinear dynamics in geomorphic systems and how these concepts can be used to interpret the nonequilibrium systems described by Gilbert. Broad, basin-scale studies were common in the period, but few were as quantitative and empirically rigorous or employed such a range of methodologies as PP105. None demonstrated such an extreme case of anthropogeomorphic change.

River discharge controlling a tidal delta: the interplay between monsoon input and tidal reworking in SW Bangladesh

NASA Astrophysics Data System (ADS)

Hale, R. P.; Goodbred, S. L., Jr.; Bain, R. L.; Wilson, C.; Best, J.; Reed, M. J.

2015-12-01

The Ganges-Brahmaputra-Meghna River system (GBM) is among the world's largest in terms of both annual water and sediment discharge. The subaerial delta (110,000 km2) is home to ~160 million people, in addition to the ecologically and economically critical Sundarbans National Forest (SNF). Recent sediment budgets suggest that ~15% of the 1 x 109 t yr-1 sediment load carried by the GBM is subsequently advected along shore and inland via tidal activity, to the otherwise-abandoned SW portion of the delta. A unit-scale estimate based on observed offshore suspended sediment concentrations (SSC) >1.0 g L-1 suggests that sufficient sediment is available in the system to maintain the elevation of the subaerial delta plain, even under current relative sea-level-rise rates. Recent work measuring sedimentation within SNF corroborates this finding, and understanding these sediment delivery dynamics will be critical for protecting the future of nearby regions that are heavily populated, but drastically altered by human activities. Cross-channel hydrodynamic surveys were conducted to estimate what fraction of the water (and sediment) is diverted from the major tidal channels toward the SNF interior. Measurements including profiles of velocity and SSC were collected on spring and neap tides during the dry and monsoon seasons, along transects bracketing major conduit channels into the SNF. During the dry season, we observe water flux at the southern end of the study area to be in approximate equilibrium regardless of tidal range, with SSC <0.3 g L-1 during neap tides, and <1.0 g L-1 during spring tides. North of the SNF conduit channels, we observe equilibrium water discharge and similarly low SSC during neap tides, but a modest ebb dominance and surface SSC >1.0 g L-1 during spring tides. This suggests the possibility of additional inputs of water and sediment from an adjacent tidal channel, as well as a potential source for the deposition observed on the Sundarbans platform during spring-tide flooding. Within channels in SNF, near-bed SSC increase by >5x from neap to spring tides, to a peak of ~1.0 g L-1. Sediment grab samples collected in a distributary channel show a moderate fining trend with distance from the major conduit, which has implications for the sedimentation rates observed on the tidal delta plain.

Changes in Bedform Shape at the Transition Between Upper Plane-Bed and Sheet-Flow Bedload Transport Regimes

NASA Astrophysics Data System (ADS)

Hernandez Moreira, R. R.; Huffman, B.; Vautin, D.; Viparelli, E.

2015-12-01

The interactions between flow hydrodynamics and bedform characteristics at the transition between upper plane-bed bedload transport regime and sheet-flow have not yet been thoroughly described and still remain poorly understood. The present study focuses on the experimental study of this transition in open channel mode. The experiments were performed in the hydraulic laboratory of the Department of Civil and Environmental Engineering of the University of South Carolina in a sediment-feed flume, 9-m long by 19-cm wide with uniform material sediment of geometric mean grain size diameter of 1.11 mm. Sediment feed rates ranged between 0.5 kg/min and 20 kg/min with two different flow rates of 20 l/s and 30 l/s. We recorded periodic measurements of water surface and bed elevation to estimate the global flow parameters, e.g. mean flow velocity and bed shear stress, and to determine when the flow and the sediment transport reached conditions of mobile bed equilibrium. We define mobile bed equilibrium as a condition in which the mean bed elevation does not change in time. At equilibrium, measurements of bed elevation fluctuations were taken with an ultrasonic transducer system at six discrete locations. In the runs with low and medium feed rates, i.e. smaller than ~12 kg/min, the long wavelength and small amplitude bedforms typical of the upper plane bed regime, which were observed in previous experimental work, formed and migrated downstream. In particular, with increasing feed rates, the amplitude of the bedforms decreases and their geometry changes, from well-defined triangular shapes, to rounded shapes to flat bed with very small amplitude, long wavelength undulations. The decrease in amplitude corresponds to a decrease in form drag and an increase in the thickness of the bedload layer. The ultrasonic measurements are analyzed to statistically describe the observed transition in terms of probability distribution functions of the bed elevation fluctuations.

Modelling of sediment transport pattern in the mouth of the Rhone delta: Role of storm and flood events

NASA Astrophysics Data System (ADS)

Boudet, L.; Sabatier, F.; Radakovitch, O.

2017-11-01

The delta of the Rhone River is one of the most important in the Mediterranean Sea. Beach erosion problems along its coasts have developed in recent decades, raising the need for a better understanding of the sediment transport processes at the Rhone mouth and the adjacent beaches. Because field data are very difficult to obtain in such an energetic environment, a high-resolution numerical model (Delft3D) is applied to this area. This model is calibrated by taking into account hydrodynamical and morphological observations. Special attention is given to storm and flood events, which are the major morphological drivers. Therefore, scenarios with different wave and flow conditions are run to estimate the influence of these events on the sediment transport. The analysis of historical hydrological data shows that storms from the southeast represent 70% of the events between 1979 to 2010 and that 20% of them were followed by a flood within a few days. Consequently, specific simulations for such conditions are performed using Delft3D. The model simulates trends in the bedload sediment transport that are consistent with the bedforms observed in the bathymetry data. The total sediment transport at the outlet is only influenced by the river flow, but sediment transport at the mouth-bar depends on an equilibrium between the influence of floods and storms and the succession of these events. A period of 2 or 3 days separating the storm and flood peaks is sufficient to differentiate wave and river flow-induced sediment transport. The waves constrain the total transport on the mouth-bar and shallow mouth-lobe and induce a longshore transfer towards the adjacent beaches. The riverine sediments can be exported seaward only if a flood is energetic enough compared to the storm intensity. Regardless, when a flood is greater than the decadal return period (7800 m3 s-1), the sediment is transported from the outlet across the mouth-bar and is directed offshore.

Interaction of Strontium-90 in Sediment and Porewater in a Stream Near Chernobyl

NASA Astrophysics Data System (ADS)

Freed, R.; Smith, L.; Bugai, D.

2002-12-01

We investigated the interaction of 90Sr in sediments and pore waters of wetlands and stream hyporheic zones at a stream near Chernobyl. A non-dimensional activity ratio was formulated, the ratio of 90Sr in the pore waters compared with exchangeable 90Sr in the sediment on a volume basis. The average activity ratio for the wetland and channel sediments was 0.028 +/- 0.005. The activity ratio decreased when the sediment and porewaters were not in equilibrium. The change in the activity ratio was documented during two observational periods in a wetland: initially during a time when groundwater was discharging to the wetland (snowmelt, 2000) and subsequently at a time of near-stagnant groundwater flow (late fall in 2001 after a dry three month period). In both the discharge and stagnant periods, the exchangeable 90Sr concentration in sediment increased with depth by a factor of five to a peak concentration at 10 cm. In contrast, the 90Sr concentration in porewater differed significantly in the two observational periods. During the groundwater discharge period, the porewater concentration was relatively constant over the 30 cm depth of observation (120 +/-12 Bq/L) and surface water concentrations were similar. During the near-stagnant period, the porewater concentration increased with depth from 20+/-2 Bq/L in surface waters to 400 +/-40 Bq/L at a depth of 10 cm. We hypothesize that during discharge periods, the porewaters in the wetland represent the 90Sr concentration of advecting groundwater while during stagnant periods, the porewaters represent the concentration of 90Sr in equilibrium with the sediment. This proposed explanation is supported using PHREEQC in a dual porosity mode. Using independent estimates of the model parameters, the concentration profiles could be successfully matched with the assumption of advective transport during the discharge period and diffusive transport of 90Sr during near-stagnant conditions.

Peroxiredoxin 6 homodimerization and heterodimerization with glutathione S-transferase pi are required for its peroxidase but not phospholipase A2 activity.

PubMed

Zhou, Suiping; Sorokina, Elena M; Harper, Sandra; Li, Haitao; Ralat, Luis; Dodia, Chandra; Speicher, David W; Feinstein, Sheldon I; Fisher, Aron B

2016-05-01

Peroxiredoxin 6 (Prdx6) is a unique 1-Cys member of the peroxiredoxin family with both GSH peroxidase and phospholipase A2 (PLA2) activities. It is highly expressed in the lung where it plays an important role in antioxidant defense and lung surfactant metabolism. Glutathionylation of Prdx6 mediated by its heterodimerization with GSH S-transferase π (πGST) is required for its peroxidatic catalytic cycle. Recombinant human Prdx6 crystallizes as a homodimer and sedimentation equilibrium analysis confirmed that this protein exists as a high affinity dimer in solution. Based on measurement of molecular mass, dimeric Prdx6 that was oxidized to the sulfenic acid formed a sulfenylamide during storage. After examination of the dimer interface in the crystal structure, we postulated that the hydrophobic amino acids L145 and L148 play an important role in homodimerization of Prdx6 as well as in its heterodimerization with πGST. Oxidation of Prdx6 also was required for its heterodimerization. Sedimentation equilibrium analysis and the Duolink proximity ligation assay following mutation of the L145 and L148 residues of Prdx6 to Glu indicated greatly decreased dimerization propensity reflecting the loss of hydrophobic interactions between the protein monomers. Peroxidase activity was markedly reduced by mutation at either of the Leu sites and was essentially abolished by the double mutation, while PLA2 activity was unaffected. Decreased peroxidase activity following mutation of the interfacial leucines presumably is mediated via impaired heterodimerization of Prdx6 with πGST that is required for reduction and re-activation of the oxidized enzyme. Copyright © 2016 Elsevier Inc. All rights reserved.

Modeling Engineered Nanomaterials (ENMs) Fate and ...

EPA Pesticide Factsheets

Under the Toxic Substances Control Act (TSCA), the Environmental Protection Agency (EPA) is required to perform new chemical reviews of engineered nanomaterials (ENMs) identified in pre-manufacture notices. However, environmental fate models developed for traditional contaminants are limited in their ability to simulate the environmental behavior of nanomaterials due to incomplete understanding and representation of the processes governing nanomaterial distribution in the environment and by scarce empirical data quantifying the interaction of nanomaterials with environmental surfaces. We have updated the Water Quality Analysis Simulation Program (WASP), version S, to incorporate nanomaterials as an explicitly simulated state variable. WASPS now has the capability to simulate nanomaterial fate and transport in surface waters and sediments using heteroaggregation, the kinetic process governing the attachment of nanomaterials to particles and subsequently ENM distribution in the aqueous and sediment phases. Unlike dissolved chemicals which use equilibrium partition coefficients, heteroaggregation consists of a particle collision rate and an attachment efficiency ( lXhet) that generally acts as a one direction process. To demonstrate, we used a derived a het value from sediment attachment studies to parameterize WASP for simulation of multi walled carbon nanotube (MWCNT) transport in Brier Creek, a coastal plain river located in central eastern Georgia, USA and a tr

PAHs in the Great Barrier Reef Lagoon reach potentially toxic levels from coal port activities

NASA Astrophysics Data System (ADS)

Burns, Kathryn A.

2014-05-01

In view of the controversy over expanding the coastal coal ports bordering the Great Barrier Reef (GBR) Lagoon and the World Heritage Area, I re-evaluated the data published in Burns and Brinkman (2011). I used the US EPA procedures for the determination of Equilibrium Partitioning Sediment Benchmarks (ESBs) for the protection of benthic organisms (Hansen et al., 2003), and the new proposed ANZECC/ARMCANZ (2013) sediment quality guidelines (Simpson et al., 2013) and determined that the coastal sediments offshore from the Hay Point coal terminal and suspended sediments caught in sediment traps inshore and at the offshore coral reefs contained levels of PAHs that approach the estimates for toxicity to benthic and water column organisms. This result is discussed in relation to risks posed to the GBR ecosystem by the port practices and the imminent expansion of the Abbott Point, Hay Point and other coal terminals.

Laminar laboratory rivers

NASA Astrophysics Data System (ADS)

Seizilles, Grégoire; Devauchelle, Olivier; Lajeunesse, Éric; Métivier, François

2014-05-01

A viscous fluid flowing over fine plastic grains spontaneously channelizes into a few centimeters-wide river. After reaching its equilibrium shape, this stable laboratory flume is able to carry a steady load of sediments, like many alluvial rivers. When the sediment discharge vanishes, the river size, shape and slope fit the threshold theory proposed by Glover and Florey (1951), which assumes that the Shields parameter is critical on the channel bed. As the sediment discharge is increased, the river widens and flattens. Surprisingly, the aspect ratio of its cross section depends on the sediment discharge only, regardless of the water discharge. We propose a theoretical interpretation of these findings based on the balance between gravity, which pulls particles towards the center of the channel, and the diffusion of bedload particles, which pushes them away from areas of intense bedload.

Hydrologic data on channel adjustments, 1970 to 1975, on the Rio Grande downstream from Cochiti Dam, New Mexico before and after closure

USGS Publications Warehouse

Dewey, Jack D.; Roybal, F.E.; Funderburg, D.E.

1979-01-01

Cross-section channel profiles, sediment transport and hydrologic data have been observed and computed for a series of pre-dam and post-dam investigations from 1970 to 1975 at 37 cross sections established along a 59-mile study reach from Cochiti Dam to Isleta Diversion Dam, New Mexico. Cochiti Dam began impounding water in November 1973. Because the dam will trap virtually all of the sediment load originating upstream and water discharge will be controlled, it is expected that equilibrium values of channel width, depth, slope and sediment-transport capability in the existing main stem of the Rio Grande will change. Changes in cross sections with time and space and changes in size distribution of sediments are documented. (Woodard-USGS).

Evaluating the Relationship between Equilibrium Passive Sampler Uptake and Aquatic Organism Bioaccumulation.

EPA Science Inventory

For decades, biomonitoring organisms have been used to assess the bioavailability of hydrophobic organic contaminants (HOCs) at contaminated sediment Superfund sites across the country. Specific applications include evaluating remedy effectiveness and pre- and post-remediation l...

Hydrodynamics of the VanA-type VanS histidine kinase: an extended solution conformation and first evidence for interactions with vancomycin

PubMed Central

Phillips-Jones, Mary K.; Channell, Guy; Kelsall, Claire J.; Hughes, Charlotte S.; Ashcroft, Alison E.; Patching, Simon G.; Dinu, Vlad; Gillis, Richard B.; Adams, Gary G.; Harding, Stephen E.

2017-01-01

VanA-type resistance to glycopeptide antibiotics in clinical enterococci is regulated by the VanSARA two-component signal transduction system. The nature of the molecular ligand that is recognised by the VanSA sensory component has not hitherto been identified. Here we employ purified, intact and active VanSA membrane protein (henceforth referred to as VanS) in analytical ultracentrifugation experiments to study VanS oligomeric state and conformation in the absence and presence of vancomycin. A combination of sedimentation velocity and sedimentation equilibrium in the analytical ultracentrifuge (SEDFIT, SEDFIT-MSTAR and MULTISIG analysis) showed that VanS in the absence of the ligand is almost entirely monomeric (molar mass M = 45.7 kDa) in dilute aqueous solution with a trace amount of high molar mass material (M ~ 200 kDa). The sedimentation coefficient s suggests the monomer adopts an extended conformation in aqueous solution with an equivalent aspect ratio of ~(12 ± 2). In the presence of vancomycin over a 33% increase in the sedimentation coefficient is observed with the appearance of additional higher s components, demonstrating an interaction, an observation consistent with our circular dichroism measurements. The two possible causes of this increase in s – either a ligand induced dimerization and/or compaction of the monomer are considered. PMID:28397853

Cirque glacier on South Georgia shows centennial variability over the last 7000 years

NASA Astrophysics Data System (ADS)

Oppedal, Lea T.; Bakke, Jostein; Paasche, Øyvind; Werner, Johannes P.; van der Bilt, Willem G. M.

2018-02-01

A 7000 year-long cirque glacier reconstruction from South Georgia, based on detailed analysis of fine-grained sediments deposited downstream in a bog and a lake, suggests continued presence during most of the Holocene. Glacier activity is inferred from various sedimentary properties including magnetic susceptibility (MS), dry bulk density (DBD), loss-on-ignition (LOI) and geochemical elements (XRF), and tallied to a set of terminal moraines. The two independently dated sediment records document concurring events of enhanced glacigenic sediment influx to the bog and lake, whereas the upstream moraines afford the opportunity to calculate past Equilibrium Line Altitudes (ELA) which has varied in the order of 70 m altitude. Combined, the records provide new evidence of cirque glacier fluctuations on South Georgia. Based on the onset of peat formation, the study site was deglaciated prior to 9900±250 years ago when Neumayer tidewater glacier retreated up-fjord. Changes in the lake and bog sediment properties indicate that the cirque glacier was close to its maximum Holocene extent between 7200±400 and 4800±200 cal BP, 2700±150 and 2000±200 cal BP, 500±150-300±100 cal BP, and in the 20th century (likely 1930s). The glacier fluctuations are largely in-phase with reconstructed Patagonian glaciers, implying that they respond to centennial climate variability possibly connected to corresponding modulations of the Southern Westerly Winds.

Emerging investigator series: development and application of polymeric electrospun nanofiber mats as equilibrium-passive sampler media for organic compounds.

PubMed

Qian, Jiajie; Jennings, Brandon; Cwiertny, David M; Martinez, Andres

2017-11-15

We fabricated a suite of polymeric electrospun nanofiber mats (ENMs) and investigated their performance as next-generation passive sampler media for environmental monitoring of organic compounds. Electrospinning of common polymers [e.g., polyacrylonitrile (PAN), polymethyl methacrylate (PMMA), and polystyrene (PS), among others] yielded ENMs with reproducible control of nanofiber diameters (from 50 to 340 nm). The ENM performance was investigated initially with model hydrophilic (aniline and nitrobenzene) and hydrophobic (selected PCB congeners and dioxin) compounds, generally revealing fast chemical uptake into all of these ENMs, which was well described by a one compartment, first-order kinetic model. Typical times to reach 90% equilibrium (t 90% ) were ≤7 days under mixing conditions for all the ENMs and <0.5 days for the best performing materials under static (i.e., no mixing) conditions. Collectively, these short equilibrium timescales suggest that ENMs may be used in the field as an equilibrium-passive sampler, at least for our model compounds. Equilibrium partitioning coefficients (K ENM-W , L kg -1 ) averaged 2 and 4.7 log units for the hydrophilic and hydrophobic analytes, respectively. PAN, PMMA and PS were prioritized for additional studies because they exhibited not only the greatest capacity for simultaneous uptake of the entire model suite (log K ENM-W ∼1.5-6.2), but also fast uptake. For these optimized ENMs, the rates of uptake into PAN and PMMA were limited by aqueous phase diffusion to the nanofiber surface, and the rate-determining step for PS was analyte specific. Sorption isotherms also revealed that the environmental application of these optimized ENMs would occur within the linear uptake regime. We examined the ENM performance for the measurement of pore water concentrations from spiked soil and freshwater sediments. Soil and sediment studies not only yielded reproducible pore water concentrations and comparable values to other passive sampler materials, but also provided practical insights into ENM stability and fouling in such systems. Furthermore, fast uptake for a suite of structurally diverse hydrophilic and moderately hydrophobic compounds was obtained for PAN and PS, with t 90% ranging from 0.01 to 4 days with mixing and K ENM-W values ranging from 1.3 to 3.2 log units. Our findings show promise for the development and use of ENMs as equilibrium-passive samplers for a range of organic pollutants across soil/sediment and water systems.

Landscape self organisation: Modelling Sediment trains

NASA Astrophysics Data System (ADS)

Schoorl, J. M.; Temme, A. J. A. M.; Veldkamp, A.

2012-04-01

Rivers tend to develop towards an equilibrium length profile, independently of exogenous factors. In general, although still under debate, this so-called self-organisation is assumed to be caused by simple feedbacks between sedimentation and erosion. Erosion correlates positively with gradient and discharge and sedimentation negatively. With the LAPSUS model, which was run for the catchment of the Sabinal, a small river in the South of Spain, this interplay of erosion and sedimentation results in sediment pulses (sequences of incision and sedimentation through time). These pulses are visualised in a short movie ( see http://www.youtube.com/watch?v=V5LDUMvYZxU). In this case the LAPSUS model run did not take climate, base level nor tectonics into account. Therefore, these pulses can be considered independent of them. Furthermore, different scenarios show that the existence of the pulses is independent of precipitation, erodibility and sedimentation rate, although they control the number and shape of the pulses. A fieldwork check showed the plausibility of the occurrence of these sediment pulses. We conclude that the pulses as modelled with LAPSUS are indeed the consequence of the feedbacks between erosion and sedimentation and are not depending on exogenous factors. Keywords: Landscape self-organisation, Erosion, Deposition, LAPSUS, Modelling

Estuarine Sediment Deposition during Wetland Restoration: A GIS and Remote Sensing Modeling Approach

NASA Technical Reports Server (NTRS)

Newcomer, Michelle; Kuss, Amber; Kentron, Tyler; Remar, Alex; Choksi, Vivek; Skiles, J. W.

2011-01-01

Restoration of the industrial salt flats in the San Francisco Bay, California is an ongoing wetland rehabilitation project. Remote sensing maps of suspended sediment concentration, and other GIS predictor variables were used to model sediment deposition within these recently restored ponds. Suspended sediment concentrations were calibrated to reflectance values from Landsat TM 5 and ASTER using three statistical techniques -- linear regression, multivariate regression, and an Artificial Neural Network (ANN), to map suspended sediment concentrations. Multivariate and ANN regressions using ASTER proved to be the most accurate methods, yielding r2 values of 0.88 and 0.87, respectively. Predictor variables such as sediment grain size and tidal frequency were used in the Marsh Sedimentation (MARSED) model for predicting deposition rates for three years. MARSED results for a fully restored pond show a root mean square deviation (RMSD) of 66.8 mm (<1) between modeled and field observations. This model was further applied to a pond breached in November 2010 and indicated that the recently breached pond will reach equilibrium levels after 60 months of tidal inundation.

Effect of organic matter on CO(2) hydrate phase equilibrium in phyllosilicate suspensions.

PubMed

Park, Taehyung; Kyung, Daeseung; Lee, Woojin

2014-06-17

In this study, we examined various CO2 hydrate phase equilibria under diverse, heterogeneous conditions, to provide basic knowledge for successful ocean CO2 sequestration in offshore marine sediments. We investigated the effect of geochemical factors on CO2 hydrate phase equilibrium. The three-phase (liquid-hydrate-vapor) equilibrium of CO2 hydrate in the presence of (i) organic matter (glycine, glucose, and urea), (ii) phyllosilicates [illite, kaolinite, and Na-montmorillonite (Na-MMT)], and (iii) mixtures of them was measured in the ranges of 274.5-277.0 K and 14-22 bar. Organic matter inhibited the phase equilibrium of CO2 hydrate by association with water molecules. The inhibition effect decreased in the order: urea < glycine < glucose. Illite and kaolinite (unexpandable clays) barely affected the CO2 hydrate phase equilibrium, while Na-MMT (expandable clay) affected the phase equilibrium because of its interlayer cations. The CO2 hydrate equilibrium conditions, in the illite and kaolinite suspensions with organic matter, were very similar to those in the aqueous organic matter solutions. However, the equilibrium condition in the Na-MMT suspension with organic matter changed because of reduction of its inhibition effect by intercalated organic matter associated with cations in the Na-MMT interlayer.

Morphodynamics: Rivers beyond steady state

NASA Astrophysics Data System (ADS)

Church, M.; Ferguson, R. I.

2015-04-01

The morphology of an alluvial river channel affects the movement of water and sediment along it, but in the longer run is shaped by those processes. This interplay has mostly been investigated empirically within the paradigm of Newtonian mechanics. In rivers, this has created an emphasis on equilibrium configurations with simple morphology and uniform steady flow. But transient adjustment, whether between equilibrium states or indefinitely, is to be expected in a world in which hydrology, sediment supply, and base level are not fixed. More fundamentally, water flows and all the phenomena that accompany them are inherently unsteady, and flows in natural channels are characteristically nonuniform. The morphodynamics of alluvial river channels is the striking consequence. In this paper, we develop the essential connection between the episodic nature of bed material transport and the production of river morphology, emphasizing the fundamental problems of sediment transport, the role of bar evolution in determining channel form, the role of riparian vegetation, and the wide range of time scales for change. As the key integrative exercise, we emphasize the importance of physics-based modeling of morphodynamics. We note consequences that can be of benefit to society if properly understood. These include the possibility to better be able to model how varying flows drive morphodynamic change, to understand the influence of the sediments themselves on morphodynamics, and to recognize the inherent necessity for rivers that transport bed material to deform laterally. We acknowledge pioneering contributions in WRR and elsewhere that have introduced some of these themes.

Estimation of Channel-Forming Discharge and Large-Event Geomorphic Response Using HEC-RAS

NASA Astrophysics Data System (ADS)

Hamilton, P.; Strom, K.; Hosseiny, S. M. H.

2015-12-01

The goal of the present work was to consider the functionality and applicability of HEC-RAS sediment transport simulations in two situations. The first was as a mode for obtaining quick estimates of the effective discharge, one measure of channel-forming discharge, and the second was as a mode to quickly estimate sediment transport and the commensurate potential erosion and deposition during large flood events. Though there are many other sediment transport and morphodynamic models available, e.g., CCHE1D, Nays2DH, we were interested in using HEC-RAS since this is the model of choice for many regulatory bodies, e.g., FEMA, cities, and counties. This makes using the sediment transport capability of HEC-RAS a natural extension of models that already otherwise exist and are well calibrated. In first looking at the utility of these models, we wanted to estimate the effective discharge of streams. Effective discharge is one way of defining the channel-forming discharge for a stream and is therefore an important parameter in natural channel design and restoration efforts. By running this range of floods, one can easily obtain an estimate for recurrence interval most responsible for moving the majority of sediment over a long time period. Results were compared to data collected within our research group on the Brazos River (TX). Effective discharge is an important estimate, particularly in understanding the equilibrium channel condition. Nevertheless, large floods are contemporaneously catastrophic and understanding their potential effects is desirable. Finally, we performed some sensitivity analysis to better understand the underlying assumptions of the various sediment transport model options and how they might affect the outcome of the aforementioned computations.

Mid-Pleistocene climate transition drives net mass loss from rapidly uplifting St. Elias Mountains, Alaska.

PubMed

Gulick, Sean P S; Jaeger, John M; Mix, Alan C; Asahi, Hirofumi; Bahlburg, Heinrich; Belanger, Christina L; Berbel, Glaucia B B; Childress, Laurel; Cowan, Ellen; Drab, Laureen; Forwick, Matthias; Fukumura, Akemi; Ge, Shulan; Gupta, Shyam; Kioka, Arata; Konno, Susumu; LeVay, Leah J; März, Christian; Matsuzaki, Kenji M; McClymont, Erin L; Moy, Chris; Müller, Juliane; Nakamura, Atsunori; Ojima, Takanori; Ribeiro, Fabiana R; Ridgway, Kenneth D; Romero, Oscar E; Slagle, Angela L; Stoner, Joseph S; St-Onge, Guillaume; Suto, Itsuki; Walczak, Maureen D; Worthington, Lindsay L; Bailey, Ian; Enkelmann, Eva; Reece, Robert; Swartz, John M

2015-12-08

Erosion, sediment production, and routing on a tectonically active continental margin reflect both tectonic and climatic processes; partitioning the relative importance of these processes remains controversial. Gulf of Alaska contains a preserved sedimentary record of the Yakutat Terrane collision with North America. Because tectonic convergence in the coastal St. Elias orogen has been roughly constant for 6 My, variations in its eroded sediments preserved in the offshore Surveyor Fan constrain a budget of tectonic material influx, erosion, and sediment output. Seismically imaged sediment volumes calibrated with chronologies derived from Integrated Ocean Drilling Program boreholes show that erosion accelerated in response to Northern Hemisphere glacial intensification (∼ 2.7 Ma) and that the 900-km-long Surveyor Channel inception appears to correlate with this event. However, tectonic influx exceeded integrated sediment efflux over the interval 2.8-1.2 Ma. Volumetric erosion accelerated following the onset of quasi-periodic (∼ 100-ky) glacial cycles in the mid-Pleistocene climate transition (1.2-0.7 Ma). Since then, erosion and transport of material out of the orogen has outpaced tectonic influx by 50-80%. Such a rapid net mass loss explains apparent increases in exhumation rates inferred onshore from exposure dates and mapped out-of-sequence fault patterns. The 1.2-My mass budget imbalance must relax back toward equilibrium in balance with tectonic influx over the timescale of orogenic wedge response (millions of years). The St. Elias Range provides a key example of how active orogenic systems respond to transient mass fluxes, and of the possible influence of climate-driven erosive processes that diverge from equilibrium on the million-year scale.

Mid-Pleistocene climate transition drives net mass loss from rapidly uplifting St. Elias Mountains, Alaska

PubMed Central

Jaeger, John M.; Mix, Alan C.; Asahi, Hirofumi; Bahlburg, Heinrich; Belanger, Christina L.; Berbel, Glaucia B. B.; Childress, Laurel; Cowan, Ellen; Drab, Laureen; Forwick, Matthias; Fukumura, Akemi; Ge, Shulan; Gupta, Shyam; Konno, Susumu; LeVay, Leah J.; März, Christian; McClymont, Erin L.; Moy, Chris; Müller, Juliane; Nakamura, Atsunori; Ojima, Takanori; Ribeiro, Fabiana R.; Ridgway, Kenneth D.; Romero, Oscar E.; Slagle, Angela L.; Stoner, Joseph S.; St-Onge, Guillaume; Suto, Itsuki; Walczak, Maureen D.; Worthington, Lindsay L.; Bailey, Ian; Enkelmann, Eva; Reece, Robert; Swartz, John M.

2015-01-01

Erosion, sediment production, and routing on a tectonically active continental margin reflect both tectonic and climatic processes; partitioning the relative importance of these processes remains controversial. Gulf of Alaska contains a preserved sedimentary record of the Yakutat Terrane collision with North America. Because tectonic convergence in the coastal St. Elias orogen has been roughly constant for 6 My, variations in its eroded sediments preserved in the offshore Surveyor Fan constrain a budget of tectonic material influx, erosion, and sediment output. Seismically imaged sediment volumes calibrated with chronologies derived from Integrated Ocean Drilling Program boreholes show that erosion accelerated in response to Northern Hemisphere glacial intensification (∼2.7 Ma) and that the 900-km-long Surveyor Channel inception appears to correlate with this event. However, tectonic influx exceeded integrated sediment efflux over the interval 2.8–1.2 Ma. Volumetric erosion accelerated following the onset of quasi-periodic (∼100-ky) glacial cycles in the mid-Pleistocene climate transition (1.2–0.7 Ma). Since then, erosion and transport of material out of the orogen has outpaced tectonic influx by 50–80%. Such a rapid net mass loss explains apparent increases in exhumation rates inferred onshore from exposure dates and mapped out-of-sequence fault patterns. The 1.2-My mass budget imbalance must relax back toward equilibrium in balance with tectonic influx over the timescale of orogenic wedge response (millions of years). The St. Elias Range provides a key example of how active orogenic systems respond to transient mass fluxes, and of the possible influence of climate-driven erosive processes that diverge from equilibrium on the million-year scale. PMID:26598689

Decadal to Millennial Sedimentation Patterns of the Hudson River Estuary

NASA Astrophysics Data System (ADS)

Jones, M.; McHugh, C. M.; Burckle, L.; Pekar, S.; Pereira, G.; Ryan, W. B.; Bell, R.; Carbotte, S.

2002-12-01

The Hudson River Estuary (HRE) is adjacent to large metropolitan areas including New York City. Understanding the variable energy conditions for transporting sediments is key to deal with environmental pollution such as the controversial burial and dredging of PCB's in the HRE. We studied sediment transport in the HRE by examining more than 150 cores and grab samples interpreted within the framework of acoustic images. The HRE sedimentary environments were defined based on quantitative estimates of grain size, sedimentary structures, bioturbation, and sedimentation rates and were divided into: channel, channel banks, subtidal flats, tributaries, and islands. Diatom assemblages were used to determine the extent of salt-water intrusion and sediment reworking in the estuary. Along a longitudinal profile, the estuary can be subdivided into: (1) sandy inner fluvial (furthest upstream), (2) muddy central portions, and (3) sandy outer marine. We classified sedimentary facies for the central and fluvial parts of the system (1 and 2). The HRE basin is nearly filled with sediment and tidal energy is focused within the channel and its banks. In the central basin where the estuary is wide (up to 4 km), flood currents are more energetic along the eastern channel bank and the ebb currents lead to minor sediment deposition on the western bank, but only where the system is out of equilibrium with its sediment load. The energy of the tides is accentuated along narrow segments of the estuary that are locally constrained by gorges of the Hudson Valley Highlands leading to erosion and the trapping of sediments. Beyond the banks of the channel, the subtidal flats that were filled with sediment by 0.5 to 3ka, are tranquil environments where the sediment is homogenized by bioturbation and reworked by waves as the estuary shallowed. Occasional high-energy events, (possibly flood-related) eroded the subtidal flats sediment as shown by rare rip-up clasts found in the cores. The inner fluvial part of the estuary is filling with sediments above sea-level forming islands. Here, the energy of tidal currents is strong as evidenced by the sand-mud rhythmic alternations of the sediments. Tributaries contribute a generally low sediment budget, but only on a seasonal basis and the fluvial energy is not strong enough to transport the gravel-size components that remain near the mouths of the tributaries forming localized deltas. The fluvial sands, form waves that migrate along the channel floor, but this coarser-grained bedload is rarely transported south of Kingston, New York, resulting in a muddy estuarine bottom further downstream. Results show that tidal energy is a dominant force in the transport and deposition of HRE sediments and that only fine-grained sediments are transported throughout most of the studied areas. Because the HRE basin is nearly filled, most sediment bypasses the system with only localized areas of sediment trapping where the estuary is out of equilibrium with its sediment load, and in the estuarine turbidity maxima, an area previously shown to contain high sediment concentrations.

Hydrodynamics and morphodynamics of a mobile bed confluence under equilibrium conditions for different values of the flow discharge ratio

NASA Astrophysics Data System (ADS)

Birjukova Canelas, Olga; Lage Ferreira, Rui Miguel; Heleno Cardoso, António

2017-04-01

Under steady water and sediment feeding in laboratory conditions, sediment fluxes tend to reach a steady state and bed morphology tends to equilibrium. This laboratory study states two objectives: i) to provide a detailed three-dimensional characterization of the flow field at a movable bed confluence and ii) to contribute to the characterization of the effect of the flow discharge ratio (Qr = Qt/Qm, Qt - tributary flow discharge and Qm - main channel flow discharge) on the flow field. While the junction angle between the main channel and the tributary as well as the sediment discharge ratio were kept constant, two scenarios corresponding to two different flow discharge ratios with dominant main channel flow discharge (Qm > Qt) were analyzed. Prior to the flow velocity measurements, both channels were fed with water and sand mixtures and tests were run until the equilibrium condition was reached, i.e. until the moment where the difference between the total supplied sand discharge and the total outgoing sand discharge was smaller than ± 5%. During the experiments, bed topography was systematically recorded. Then, the flow was stopped, the water was slowly drained and the bed was carefully fixed with a cement and vernix coat and allowed to dry to guarantee that it remained stable from there on, while the clear water (free of sand) discharges were fed again to the fixed bed converging channels. A 3D side looking Acoustic Doppler Velocimeter (ADV), installed on a remotely controlled and precisely positioned (± 0.1 mm) robotic arm, was used to measure the instantaneous velocities at a very dense mesh. Once the velocities measured and recorded, the water surface levels were surveyed. For the case with more dominant tributary flow (Qr = 0.17), as expected, the scour hole formed at the tributary mouth is much deeper and larger and extends towards the outer bank of the post-confluence channel, as well as upstream the junction corner. The avalanche slopes are, consequently, steeper. On the other hand, for the case with a weaker tributary flow (Qr = 0.08), no erosion is observed immediately upstream the junction. Moreover, the bank-attached sediment bar downstream the junction is considerably more developed in longitudinal and vertical directions. In both scenarios, a strong horizontal vortical structure was observed immediately downstream the junction. More detailed analysis of the origin and the characteristics of these and other flow patterns is still under investigation. Acknowledgements This research as partially supported by Portuguese and European funds, within programs COMPETE2020 and PORL-FEDER, through project PTDC/ECM-HID/6387/2014 granted by the National Foundation for Science and Technology (FCT).

Electrostatic and hydrodynamics effects in a sedimented magnetorheological suspension.

PubMed

Domínguez-García, P; Pastor, J M; Melle, Sonia; Rubio, Miguel A

2009-08-01

We present experimental results on the equilibrium microstructure of a sedimented magnetorheological suspension, namely, an aqueous suspension of micron-sized superparamagnetic particles. We develop a study of the electrical interactions on the suspension by processing video-microscopy images of the sedimented particles. We calculate the pair distribution function, g(r), which yields the electrostatic pair potential u(r), showing an anomalous attractive interaction for distances on the order of twice the particle diameter, with characteristic parameters whose values show a dependence with the two-dimensional concentration of particles. The repulsive body of the potential is adjusted to a DLVO expression in order to calculate the Debye screening length and the effective surface charge density. Influence of confinement and variations on the Boltzmann sedimentation profile because of the electrostatic interactions appear to be essential for the interpretation of experimental results.

Effects of nutrient loading on the carbon balance of coastal wetland sediments

USGS Publications Warehouse

Morris, J.T.; Bradley, P.M.

1999-01-01

Results of a 12-yr study in an oligotrophic South Carolina salt marsh demonstrate that soil respiration increased by 795 g C m-2 yr-1 and that carbon inventories decreased in sediments fertilized with nitrogen and phosphorus. Fertilized plots became net sources of carbon to the atmosphere, and sediment respiration continues in these plots at an accelerated pace. After 12 yr of treatment, soil macroorganic matter in the top 5 cm of sediment was 475 g C m-2 lower in fertilized plots than in controls, which is equivalent to a constant loss rate of 40 g C m-2 yr-1. It is not known whether soil carbon in fertilized plots has reached a new equilibrium or continues to decline. The increase in soil respiration in the fertilized plots was far greater than the loss of sediment organic matter, which indicates that the increase in soil respiration was largely due to an increase in primary production. Sediment respiration in laboratory incubations also demonstrated positive effects of nutrients. Thus, the results indicate that increased nutrient loading of oligotrophic wetlands can lead to an increased rate of sediment carbon turnover and a net loss of carbon from sediments.

Evaluation of toxicity to the amphipod, Hyalella azteca, and to the midge, Chironomus dilutus; and bioaccumulation by the oligochaete, Lumbriculus variegatus, with exposure to PCB-contaminated sediments from Anniston, Alabama

USGS Publications Warehouse

Ingersoll, Christopher G.; Steevens, Jeffery A.; MacDonald, Donald D.; Brumbaugh, William G.; Coady, Matthew R.; Farrar, J. Daniel; Lotufo, Guilherme R.; Kemble, Nile E.; Kunz, James L.; Stanley, Jacob K.; Sinclair, Jesse A.; Ingersoll, Christopher G.; Steevens, Jeffery A.; MacDonald, Donald D.

2014-01-01

The U.S. Environmental Protection Agency (USEPA) requested that as part of the remedial investigation for the Anniston, Alabama Polychlorinated Biphenyl (PCB) Site (Anniston PCB Site), that Pharmacia Corporation and Solutia Inc. (P/S) perform long-term reproduction toxicity tests with the amphipod, Hyalella azteca, and the midge, Chironomus dilutus, and bioaccumulation tests with the oligochaete, Lumbriculus variegatus, using sediment samples collected from reference locations and from Operable Unit 4 of the Anniston PCB Site. The sediment toxicity testing and sediment bioaccumulation results will be used by ARCADIS U.S., Inc. (ARCADIS) as part of a weight-of-evidence assessment to evaluate risks and establish sediment remediation goals for contaminants to sediment-dwelling organisms inhabiting the Anniston PCB Site. The goal of this study was to characterize relations between sediment chemistry and sediment toxicity and relations between sediment chemistry and sediment bioaccumulation in samples of sediments collected from the Anniston PCB Site. A total of 32 samples were evaluated from six test sites and one reference site to provide a wide range in concentrations of chemicals of potential concern (COPCs) including PCBs in samples of whole sediment. The goal of this study was not to determine the extent of sediment contamination across the Anniston PCB Site. Hence, the test sites or samples collected from within a test site were not selected to represent the spatial extent of sediment contamination across the Anniston PCB Site. Sediment chemistry, pore-water chemistry, and sediment toxicity data were generated for 26 sediment samples from the Anniston PCB Site. All of the samples were evaluated to determine if they qualified as reference sediment samples. Those samples that met the chemical selection criteria and biological selection criteria were identified as reference samples and used to develop the reference envelope for each toxicity test endpoint. Physical characterization of samples of whole sediment included analyses of grain size, TOC, and nutrients. Organic chemical characterization of samples of whole sediment included PCB homologs and select (13) PCB congeners, parent and alkylated polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides, and polychlorinated dibenzo-p-dioxins; and dibenzofurans. The PCB aroclors analyzed included 1016, 1221, 1232, 1242, 1248, 1254, 1260, 1262 and 1268. Analyses of whole sediment also included total metals, simultaneously extracted metals, and acid volatile sulfide. Chemical characterization of samples of pore water isolated from samples of whole sediment at the start of the sediment toxicity exposures or at the start of the sediment bioaccumulation exposures included metals, major cations, major anions, dissolved organic carbon, and additional water-quality characteristics. Concentrations of metals or PCBs in pore water during the sediment toxicity exposures or during sediment bioaccumulation exposures also were determined using peeper samples (for metals) or solid-phase microextraction (SPME) samplers (for PCBs). The bioavailability and bioaccumulation of PCBs in 14 sediment samples were investigated using SPME passive samplers and the 28-d L. variegatus whole-sediment bioaccumulation exposures In general the accumulation of PCBs consistently was predicted through the use of organic carbon normalization and equilibrium partitioning. In these sediments, PCB homologs were accumulated differently based on bioavailability and potential to accumulate in oligochaetes. As part of this assessment homolog specific biota sediment accumulation factor values were developed that could be applied across the larger site to predict tissue levels of PCBs. The whole-sediment toxicity tests done with H. azteca and C. dilutus met the established ASTM and USEPA test acceptability criteria. The most responsive H. azteca endpoints were day 42 survival normalized young per female and day 28 biomass and that the most responsive C. dilutus endpoints were adult biomass and percent adult emergence. Overall, between the two species, the most responsive endpoint assessed for these two species was H. azteca survival-normalized young per female (67 percent of the samples classified as toxic). Concentration-response models (CRMs) and site-specific sediment toxicity thresholds (TTs) were generated with matching sediment chemistry and sediment toxicity data. Sediment chemistry, pore-water chemistry, and sediment toxicity data were evaluated for as many as 26 sediment samples from the Anniston PCB Site. The reference-envelope approach was used to identify the sediment samples that were toxic to benthic invertebrates. This procedure involved identification of reference sediment samples, normalizing the toxicity data to reflect control responses, developing a reference envelope for each toxicity test endpoint, and designating each sediment sample as toxic or not toxic for each toxicity test endpoint, for each species, and for all species combined. These results demonstrated percent emergence of adult C. dilutus, biomass of adult C. dilutus, and reproduction of H. azteca normalized to percent survival were among the most responsive endpoints that were evaluated. Therefore, these endpoints were selected for CRM development. The site-specific TTs for whole sediment provide a reliable basis for identifying toxic and not toxic sediment samples in the Anniston PCB Site (that is, for correctly classifying the sediment samples used to derive the TTs as toxic or not toxic, for the endpoint used to derive the TTs). Among the 69 TTs for sediment, the TTLRs for total PCB homologs [499 to 1,870 micrograms per kilogram dry weight (μg/kg DW)] and for lead [(9.48 to 10.3 milligrams per kilogram (mg/kg) DW] based on reproduction of H. azteca or based on emergence or biomass of adult C. dilutus, were the most reliable. Such TTs had low rates of false negative errors (that is, only 0 to 11 percent of the samples below the TT were toxic to benthic invertebrates), low rates of false positive errors (only 0 to 6 percent of the samples greater than the TT were not toxic to benthic invertebrates), and high rates of correct classification (that is, 92 to 96 percent). The site-specific TTs for PCBs and other COPCs derived in this study also were compared to empirically based sediment quality guidelines (SQGs), to equilibrium-partitioning based SQGs, and to the results of spiked-sediment toxicity tests. The results of this evaluation indicated that the site-specific sediment TTs for PCBs were comparable to the consensus-based SQGs that were derived for PCBs. In addition, the site-specific sediment TTs for PCBs are well within the range of SQGs derived using the equilibrium partitioning approach. The site-specific sediment TTs for PCBs also are consistent with the results of chronic TTs that have been estimated for benthic invertebrates using the results of spiked-sediment toxicity tests. As the site-specific sediment TTs for PCBs are consistent with empirically based SQGs, equilibrium-partitioning based SQGs, and results of sediment-spiking studies, these site- specific sediment TTs likely represent the concentrations of PCBs that are sufficient to cause toxicity to benthic invertebrates (as opposed to simply being correlated with adverse effects on the survival, weight, or reproduction of benthic invertebrates). Importantly, such site-specific sediment TTs have been demonstrated to accurately classify sediment samples as toxic or not toxic to benthic invertebrates at the Anniston PCB Site. In contrast, the TTs for metals, PAHs, and organochlorine pesticides were generally lower than consensus-based SQGs (that is, probable effect concentrations), and LC50s (median lethal effect concentrations) generated in spiked-sediment toxicity tests, indicating that these COPCs are likely not the main contributors to the observed toxicity of the site sediments evaluated in this study. The reproduction endpoint for H. azteca provided lower TTs compared to the day 28 biomass endpoint for H. azteca and the emergence or biomass endpoints for adult C. dilutus provided lower TTs compared to the day 13 biomass endpoint for C. dilutus.

A gel probe equilibrium sampler for measuring arsenic porewater profiles and sorption gradients in sediments: I. Laboratory development

USGS Publications Warehouse

Campbell, K.M.; Root, R.; O'Day, P. A.; Hering, J.G.

2008-01-01

A gel probe equilibrium sampler has been developed to study arsenic (As) geochemistry and sorption behavior in sediment porewater. The gels consist of a hydrated polyacrylamide polymer, which has a 92% water content. Two types of gels were used in this study. Undoped (clear) gels were used to measure concentrations of As and other elements in sediment porewater. The polyacrylamide gel was also doped with hydrous ferric oxide (HFO), an amorphous iron (Fe) oxyhydroxide. When deployed in the field, HFO-doped gels introduce a fresh sorbent into the subsurface thus allowing assessment of in situ sorption. In this study, clear and HFO-doped gels were tested under laboratory conditions to constrain the gel behavior prior to field deployment. Both types of gels were allowed to equilibrate with solutions of varying composition and re-equilibrated in acid for analysis. Clear gels accurately measured solution concentrations (??1%), and As was completely recovered from HFO-doped gels (??4%). Arsenic speciation was determined in clear gels through chromatographic separation of the re-equilibrated solution. For comparison to speciation in solution, mixtures of As(III) and As(V) adsorbed on HFO embedded in gel were measured in situ using X-ray absorption spectroscopy (XAS). Sorption densities for As(III) and As(V) on HFO embedded in gel were obtained from sorption isotherms at pH 7.1. When As and phosphate were simultaneously equilibrated (in up to 50-fold excess of As) with HFO-doped gels, phosphate inhibited As sorption by up to 85% and had a stronger inhibitory effect on As(V) than As(III). Natural organic matter (>200 ppm) decreased As adsorption by up to 50%, and had similar effects on As(V) and As(III). The laboratory results provide a basis for interpreting results obtained by deploying the gel probe in the field and elucidating the mechanisms controlling As partitioning between solid and dissolved phases in the environment. ?? 2008 American Chemical Society.

Watershed safety and quality control by safety threshold method

NASA Astrophysics Data System (ADS)

Da-Wei Tsai, David; Mengjung Chou, Caroline; Ramaraj, Rameshprabu; Liu, Wen-Cheng; Honglay Chen, Paris

2014-05-01

Taiwan was warned as one of the most dangerous countries by IPCC and the World Bank. In such an exceptional and perilous island, we would like to launch the strategic research of land-use management on the catastrophe prevention and environmental protection. This study used the watershed management by "Safety Threshold Method" to restore and to prevent the disasters and pollution on island. For the deluge prevention, this study applied the restoration strategy to reduce total runoff which was equilibrium to 59.4% of the infiltration each year. For the sediment management, safety threshold management could reduce the sediment below the equilibrium of the natural sediment cycle. In the water quality issues, the best strategies exhibited the significant total load reductions of 10% in carbon (BOD5), 15% in nitrogen (nitrate) and 9% in phosphorus (TP). We found out the water quality could meet the BOD target by the 50% peak reduction with management. All the simulations demonstrated the safety threshold method was helpful to control the loadings within the safe range of disasters and environmental quality. Moreover, from the historical data of whole island, the past deforestation policy and the mistake economic projects were the prime culprits. Consequently, this study showed a practical method to manage both the disasters and pollution in a watershed scale by the land-use management.

Modeling tidal marsh distribution with sea-level rise: evaluating the role of vegetation, sediment, and upland habitat in marsh resiliency.

PubMed

Schile, Lisa M; Callaway, John C; Morris, James T; Stralberg, Diana; Parker, V Thomas; Kelly, Maggi

2014-01-01

Tidal marshes maintain elevation relative to sea level through accumulation of mineral and organic matter, yet this dynamic accumulation feedback mechanism has not been modeled widely in the context of accelerated sea-level rise. Uncertainties exist about tidal marsh resiliency to accelerated sea-level rise, reduced sediment supply, reduced plant productivity under increased inundation, and limited upland habitat for marsh migration. We examined marsh resiliency under these uncertainties using the Marsh Equilibrium Model, a mechanistic, elevation-based soil cohort model, using a rich data set of plant productivity and physical properties from sites across the estuarine salinity gradient. Four tidal marshes were chosen along this gradient: two islands and two with adjacent uplands. Varying century sea-level rise (52, 100, 165, 180 cm) and suspended sediment concentrations (100%, 50%, and 25% of current concentrations), we simulated marsh accretion across vegetated elevations for 100 years, applying the results to high spatial resolution digital elevation models to quantify potential changes in marsh distributions. At low rates of sea-level rise and mid-high sediment concentrations, all marshes maintained vegetated elevations indicative of mid/high marsh habitat. With century sea-level rise at 100 and 165 cm, marshes shifted to low marsh elevations; mid/high marsh elevations were found only in former uplands. At the highest century sea-level rise and lowest sediment concentrations, the island marshes became dominated by mudflat elevations. Under the same sediment concentrations, low salinity brackish marshes containing highly productive vegetation had slower elevation loss compared to more saline sites with lower productivity. A similar trend was documented when comparing against a marsh accretion model that did not model vegetation feedbacks. Elevation predictions using the Marsh Equilibrium Model highlight the importance of including vegetation responses to sea-level rise. These results also emphasize the importance of adjacent uplands for long-term marsh survival and incorporating such areas in conservation planning efforts.

Evaluation and use of a diffusion-controlled sampler for determining chemical and dissolved oxygen gradients at the sediment-water interface

USGS Publications Warehouse

Simon, N.S.; Kennedy, M.M.; Massoni, C.S.

1985-01-01

Field and laboratory evaluations were made of a simple, inexpensive diffusion-controlled sampler with ports on two sides at each interval which incorporates 0.2-??m polycarbonate membrane to filter samples in situ. Monovalent and divalent ions reached 90% of equilibrium between sampler contents and the external solution within 3 and 6 hours, respectively. Sediment interstitial water chemical gradients to depths of tens of centimeters were obtained within several days after placement. Gradients were consistent with those determined from interstitial water obtained by centrifugation of adjacent sediment. Ten milliliter sample volumes were collected at 1-cm intervals to determine chemical gradients and dissolved oxygen profiles at depth and at the interface between the sediment and water column. The flux of dissolved species, including oxygen, across the sediment-water interface can be assessed more accurately using this sampler than by using data collected from benthic cores. ?? 1985 Dr W. Junk Publishers.

Modeling sediment transport with an integrated view of the biofilm effects

NASA Astrophysics Data System (ADS)

Fang, H. W.; Lai, H. J.; Cheng, W.; Huang, L.; He, G. J.

2017-09-01

Most natural sediment is invariably covered by biofilms in reservoirs and lakes, which have significant influence on bed form dynamics and sediment transport, and also play a crucial role in natural river evolution, pollutant transport, and habitat changes. However, most models for sediment transport are based on experiments using clean sediments without biological materials. In this study, a three-dimensional mathematical model of hydrodynamics and sediment transport is presented with a comprehensive consideration of the biofilm effects. The changes of the bed resistance mainly due to the different bed form dynamics of the biofilm-coated sediment (biosediment), which affect the hydrodynamic characteristics, are considered. Moreover, the variations of parameters related to sediment transport after the biofilm growth are integrated, including the significant changes of the incipient velocity, settling velocity, reference concentration, and equilibrium bed load transport rate. The proposed model is applied to evaluate the effects of biofilms on the hydrodynamic characteristics and sediment transport in laboratory experiments. Results indicate that the mean velocity increases after the biofilm growth, and the turbulence intensity near the river bed decreases under the same flow condition. Meanwhile, biofilm inhibits sediment from moving independently. Thus, the moderate erosion is observed for biosediment resulting in smaller suspended sediment concentrations. The proposed model can reasonably reflect these sediment transport characteristics with biofilms, and the approach to integration of the biological impact could also be used in other modeling of sediment transport, which can be further applied to provide references for the integrated management of natural aqueous systems.

A general mixture model and its application to coastal sandbar migration simulation

NASA Astrophysics Data System (ADS)

Liang, Lixin; Yu, Xiping

2017-04-01

A mixture model for general description of sediment laden flows is developed and then applied to coastal sandbar migration simulation. Firstly the mixture model is derived based on the Eulerian-Eulerian approach of the complete two-phase flow theory. The basic equations of the model include the mass and momentum conservation equations for the water-sediment mixture and the continuity equation for sediment concentration. The turbulent motion of the mixture is formulated for the fluid and the particles respectively. A modified k-ɛ model is used to describe the fluid turbulence while an algebraic model is adopted for the particles. A general formulation for the relative velocity between the two phases in sediment laden flows, which is derived by manipulating the momentum equations of the enhanced two-phase flow model, is incorporated into the mixture model. A finite difference method based on SMAC scheme is utilized for numerical solutions. The model is validated by suspended sediment motion in steady open channel flows, both in equilibrium and non-equilibrium state, and in oscillatory flows as well. The computed sediment concentrations, horizontal velocity and turbulence kinetic energy of the mixture are all shown to be in good agreement with experimental data. The mixture model is then applied to the study of sediment suspension and sandbar migration in surf zones under a vertical 2D framework. The VOF method for the description of water-air free surface and topography reaction model is coupled. The bed load transport rate and suspended load entrainment rate are all decided by the sea bed shear stress, which is obtained from the boundary layer resolved mixture model. The simulation results indicated that, under small amplitude regular waves, erosion occurred on the sandbar slope against the wave propagation direction, while deposition dominated on the slope towards wave propagation, indicating an onshore migration tendency. The computation results also shows that the suspended load will also make great contributions to the topography change in the surf zone, which is usually neglected in some previous researches.

PEaCH4 v.2.0: A modelling platform to predict early diagenetic processes in marine sediments with a focus on biogenic methane - Case study: Offshore Namibia

NASA Astrophysics Data System (ADS)

Arning, Esther T.; Häußler, Steffen; van Berk, Wolfgang; Schulz, Hans-Martin

2016-07-01

The modelling of early diagenetic processes in marine sediments is of interest in marine science, and in the oil and gas industry, here, especially with respect to methane occurrence and gas hydrate formation as resources. Early diagenesis in marine sediments evolves from a complex web of intertwining (bio)geochemical reactions. It comprises microbially catalysed reactions and inorganic mineral-water-gas interactions. A model that will describe and consider all of these reactions has to be complex. However, it should be user-friendly, as well as to be applicable for a broad community and not only for experts in the field of marine chemistry. The presented modelling platform PeaCH4 v.2.0 combines both aspects, and is Microsoft Excel©-based. The modelling tool is PHREEQC (version 2), a computer programme for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. The conceptual PEaCH4 model is based on the conversion of sediment-bound degradable organic matter. PEaCH4 v.2.0 was developed to quantify and predict early diagenetic processes in marine sediments with the focus on biogenic methane formation and its phase behaviour, and allows carbon mass balancing. In regard to the irreversible degradation of organic matter, it comprises a "reaction model" and a "kinetic model" to predict methane formation. Both approaches differ in their calculations and outputs as the "kinetic model" considers the modelling time to integrate temperature dependent biogenic methane formation in its calculations, whereas the "reaction model" simply relies on default organic matter degradation. With regard to the inorganic mineral-water-gas interactions, which are triggered by irreversible degradation of organic matter, PEaCH4 v.2.0 is based on chemical equilibrium thermodynamics, appropriate mass-action laws, and their temperature dependent equilibrium constants. The programme is exemplarily presented with the example of upwelling sediments off Namibia, ODP Leg 175, Site 1082. The application demonstrates that the modelling platform PEaCH4 v.2.0 provides a user-friendly, but complex scientific tool that delivers retraceable information about early diagenetic processes and products in marine sediments.

Effect of adsorbed metals ions on the transport of Zn- and Ni-EDTA complexes in a sand and gravel aquifer

USGS Publications Warehouse

Kent, D.B.; Davis, J.A.; Anderson, L.C.D.; Rea, B.A.; Coston, J.A.

2002-01-01

Adsorption, complexation, and dissolution reactions strongly influenced the transport of metal ions complexed with ethylenediaminetetraacetic acid (EDTA) in a predominantly quartz-sand aquifer during two tracer tests conducted under mildly reducing conditions at pH 5.8 to 6.1. In tracer test M89, EDTA complexes of zinc (Zn) and nickel (Ni), along with excess free EDTA, were injected such that the lower portion of the tracer cloud traveled through a region with adsorbed manganese (Mn) and the upper portion of the tracer cloud traveled through a region with adsorbed Zn. In tracer test S89, Ni- and Zn-EDTA complexes, along with excess EDTA complexed with calcium (Ca), were injected into a region with adsorbed Mn. The only discernable chemical reaction between Ni-EDTA and the sediments was a small degree of reversible adsorption leading to minor retardation. In the absence of adsorbed Zn, the injected Zn was displaced from EDTA complexes by iron(III) [Fe(III)] dissolved from the sediments. Displacement of Zn by Fe(III) on EDTA became increasingly thermodynamically favorable with decreasing total EDTA concentration. The reaction was slow compared to the time-scale of transport. Free EDTA rapidly dissolved aluminum (Al) from the sediments, which was subsequently displaced slowly by Fe. In the portion of tracer cloud M89 that traveled through the region contaminated with adsorbed Zn, little displacement of Zn complexed with EDTA was observed, and Al was rapidly displaced from EDTA by Zn desorbed from the sediments, in agreement with equilibrium calculations. In tracer test S89, desorption of Mn dominated over the more thermodynamically favorable dissolution of Al oxyhydroxides. Comparison with results from M89 suggests that dissolution of Al oxyhydroxides in coatings on these sediment grains by Ca-EDTA was rate-limited whereas that by free EDTA reached equilibrium on the time-scale of transport. Rates of desorption are much faster than rates of dissolution of Fe oxyhydroxides from sediment-grain surfaces and, therefore, adsorbed metal ions can strongly influence the speciation of ligands like EDTA in soils and sediments, especially over small temporal and spatial scales. Copyright ?? 2002 Elsevier Science Ltd.

Vegetation ecogeomorphology, dynamic equilibrium, and disturbance: chapter 7

USGS Publications Warehouse

Hupp, Cliff R.

2013-01-01

Early ecologists understood the need to document geomorphic form and process to explain plant species distributions. Although this relationship has been acknowledged for over a century, with the exception of a few landmark papers, only the past few decades have experienced intensive research on this interdisciplinary topic. Here the authors provide a summary of the intimate relations between vegetation and geomorphic/process on hillslopes and fluvial systems. These relations are separated into systems (primarily fluvial) in dynamic equilibrium and those that are in nonequilibrium conditions including the impacts of various human disturbances affecting landforms, geomorphic processes, and interrelated, attendant vegetation patterns and processes. The authors conclude with a conceptual model of stream regime focusing on sediment deposition, erosion, and equilibrium that can be expanded to organize and predict vegetation patterns and life history strategies.

Radiological and multi-element analysis of sediments from the Proserpina reservoir (Spain) dating from Roman times.

PubMed

Baeza, A; Guillén, J; Ontalba Salamanca, M A; Rodríguez, A; Ager, F J

2009-10-01

The Proserpina dam was built in Roman times to provide drinking water to Emerita Augusta (today's Mérida in SW Spain). During maintenance work, a sediment core was extracted, offering an excellent opportunity to analyze the historical environmental impacts of the dam and its reservoir over the 2000 years since Roman times. In order to establish an accurate chronology, (14)C ages were determined by accelerator mass spectrometry (AMS). Core samples were assayed for their content in uranium and thorium series isotopes, (40)K, and the anthropogenic radionuclides (137)Cs, (90)Sr, and (239+240)Pu. Potassium-40 presented the highest activity level and was not constant with depth. The uranium and thorium series were generally in equilibrium, suggesting there had been no additional input of natural radionuclides. The presence of (137)Cs was only found in relation with the global fallout in the early 1960s. Multi-element assays were performed using the PIXE and PIGE techniques. Some variations in the multi-element concentrations were observed with depth, but the sediment core could be considered as clean, and no presumptive anthropogenic pollutants were found. Nevertheless, an unusually high Zn content was detected at depths corresponding to pre-Roman times, due to geological anomalies in the area.

Turbidity Currents With Equilibrium Basal Driving Layers: A Mechanism for Long Runout

NASA Astrophysics Data System (ADS)

Luchi, R.; Balachandar, S.; Seminara, G.; Parker, G.

2018-02-01

Turbidity currents run out over 100 km in lakes and reservoirs, and over 1,000 km in the ocean. They do so without dissipating themselves via excess entrainment of ambient water. Existing layer-averaged formulations cannot capture this. We use a numerical model to describe the temporal evolution of a turbidity current toward steady state under condition of zero net sediment flux at the bed. The flow self-partitions itself into two layers. The lower "driving layer" approaches an invariant flow thickness, velocity profile, and suspended sediment concentration profile that sequesters nearly all of the suspended sediment. This layer can continue indefinitely at steady state over a constant bed slope. The upper "driven layer" contains a small fraction of the suspended sediment. The devolution of the flow into these two layers likely allows the driving layer to run out long distances.

The unbearable heaviness of colloids: facts, surprises, and puzzles in sedimentation

NASA Astrophysics Data System (ADS)

Piazza, Roberto; Buzzaccaro, Stefano; Secchi, Eleonora

2012-07-01

Sedimentation has played a key role in the development of colloid science. In fact, it is because of the celebrated experiments by Perrin, yielding a concrete demonstration of molecular reality and giving strong support to Einstein’s theory of Brownian motion, that colloids enter the realm of basic physics. Subsequent investigations have shown that a lot more can be learnt both from sedimentation equilibrium and from particle settling dynamics. These advances, together with new experimental approaches, will be reviewed in this paper. Yet, we shall also show that inquiring about gravity settling is far from being a closed matter: for instance, the concept of buoyancy for a settling colloidal mixture is far from being obvious. Moreover, sedimentation holds novel surprises, such as colloidal inflations and settling disasters, showing that a simple external field like gravity may induce mind-boggling, and theoretically challenging effects.

Microbially assisted recording of the Earth's magnetic field in sediment.

PubMed

Zhao, Xiangyu; Egli, Ramon; Gilder, Stuart A; Müller, Sebastian

2016-02-11

Sediments continuously record variations of the Earth's magnetic field and thus provide an important archive for studying the geodynamo. The recording process occurs as magnetic grains partially align with the geomagnetic field during and after sediment deposition, generating a depositional remanent magnetization (DRM) or post-DRM (PDRM). (P)DRM acquisition mechanisms have been investigated for over 50 years, yet many aspects remain unclear. A key issue concerns the controversial role of bioturbation, that is, the mechanical disturbance of sediment by benthic organisms, during PDRM acquisition. A recent theory on bioturbation-driven PDRM appears to solve many inconsistencies between laboratory experiments and palaeomagnetic records, yet it lacks experimental proof. Here we fill this gap by documenting the important role of bioturbation-induced rotational diffusion for (P)DRM acquisition, including the control exerted on the recorded inclination and intensity, as determined by the equilibrium between aligning and perturbing torques acting on magnetic particles.

Study of sediment movement in an irrigated maize-cotton system combining rainfall simulations, sediment tracers and soil erosion models

NASA Astrophysics Data System (ADS)

Guzmán, Gema; Laguna, Ana; Cañasveras, Juan Carlos; Boulal, Hakim; Barrón, Vidal; Gómez-Macpherson, Helena; Giráldez, Juan Vicente; Gómez, José Alfonso

2015-05-01

Although soil erosion is one of the main threats to agriculture sustainability in many areas of the world, its processes are difficult to measure and still need a better characterization. The use of iron oxides as sediment tracers, combined with erosion and mixing models opens up a pathway for improving the knowledge of the erosion and redistribution of soil, determining sediment sources and sinks. In this study, magnetite and a multivariate mixing model were used in rainfall simulations at the micro-plot scale to determine the source of the sediment at different stages of a furrow-ridge system both with (+T) and without (-T) wheel tracks. At a plot scale, magnetite, hematite and goethite combined with two soil erosion models based on the kinematic wave approach were used in a sprinkler irrigation test to study trends in sediment transport and tracer dynamics along furrow lengths under a wide range of scenarios. In the absence of any stubble cover, sediment contribution from the ridges was larger than the furrow bed one, almost 90%, while an opposite trend was observed with stubble, with a smaller contribution from the ridge (32%) than that of the bed, at the micro-plot trials. Furthermore, at a plot scale, the tracer concentration analysis showed an exponentially decreasing trend with the downstream distance both for sediment detachment along furrows and soil source contribution from tagged segments. The parameters of the distributed model KINEROS2 have been estimated using the PEST Model to obtain a more accurate evaluation. Afterwards, this model was used to simulate a broad range of common scenarios of topography and rainfall from commercial farms in southern Spain. Higher slopes had a significant influence on sediment yields while long furrow distances allowed a more efficient water use. For the control of runoff, and therefore soil loss, an equilibrium between irrigation design (intensity, duration, water pattern) and hydric needs of the crops should be defined in order to establish a sustainable management strategy.

Rapid Dissolution of Soluble Uranyl Phases in Arid, Mine-Impacted Catchments Near Church Rock, NM

DOE Office of Scientific and Technical Information (OSTI.GOV)

deLemos, J.L.; Bostick, B.C.; Quicksall, A.N.

2009-05-14

We tested the hypothesis that runoff of uranium-bearing particles from mining waste disposal areas was a significant mechanism for redistribution of uranium in the northeastern part of the Upper Puerco River watershed (New Mexico). However, our results were not consistent with this hypothesis. Analysis of >100 sediment and suspended sediment samples collected adjacent to and downstream from uranium source areas indicated that uranium levels in the majority of the samples were not elevated above background. Samples collected within 50 m of a known waste disposal site were subjected to detailed geochemical characterization. Uranium in these samples was found to bemore » highly soluble; treatment with synthetic pore water for 24 h caused dissolution of 10-50% of total uranium in the samples. Equilibrium uranium concentrations in pore water were >4.0 mg/L and were sustained in repeated wetting events, effectively depleting soluble uranium from the solid phase. The dissolution rate of uranium appeared to be controlled by solid-phase diffusion of uranium from within uranium-bearing mineral particles. X-ray adsorption spectroscopy indicated the presence of a soluble uranyl silicate, and possibly a uranyl phosphate. These phases were exhausted in transported sediment suggesting that uranium was readily mobilized from sediments in the Upper Puerco watershed and transported in the dissolved load. These results could have significance for uranium risk assessment as well as mining waste management and cleanup efforts.« less

Rapid Dissolution of Soluble Uranyl Phases in Arid, Mine-Impacted Catchments near Church Rock, NM

PubMed Central

DELEMOS, JAMIE L.; BOSTICK, BENJAMIN C.; QUICKSALL, ANDREW N.; LANDIS, JOSHUA D.; GEORGE, CHRISTINE C.; SLAGOWSKI, NAOMI L.; ROCK, TOMMY; BRUGGE, DOUG; LEWIS, JOHNNYE; DURANT, JOHN L.

2008-01-01

We tested the hypothesis that runoff of uranium-bearing particles from mining waste disposal areas was a significant mechanism for redistribution of uranium in the northeastern part of the Upper Puerco River watershed (New Mexico). However, our results were not consistent with this hypothesis. Analysis of >100 sediment and suspended sediment samples collected adjacent to and downstream from uranium source areas indicated that uranium levels in the majority of the samples were not elevated above background. Samples collected within 50 m of a known waste disposal site were subjected to detailed geochemical characterization. Uranium in these samples was found to be highly soluble; treatment with synthetic pore water for 24 h caused dissolution of 10–50% of total uranium in the samples. Equilibrium uranium concentrations in pore water were >4.0 mg/L and were sustained in repeated wetting events, effectively depleting soluble uranium from the solid phase. The dissolution rate of uranium appeared to be controlled by solid-phase diffusion of uranium from within uranium-bearing mineral particles. X-ray adsorption spectroscopy indicated the presence of a soluble uranyl silicate, and possibly a uranyl phosphate. These phases were exhausted in transported sediment suggesting that uranium was readily mobilized from sediments in the Upper Puerco watershed and transported in the dissolved load. These results could have significance for uranium risk assessment as well as mining waste management and cleanup efforts. PMID:18589950

Trends in the sediment yield of the Sacramento River, California, 1957-2001

USGS Publications Warehouse

Wright, Scott A.; Schoellhamer, David H.

2004-01-01

Human activities within a watershed, such as agriculture, urbanization, and dam building, may affect the sediment yield from the watershed. Because the equilibrium geomorphic form of an estuary is dependent in part on the sediment supply from the watershed, anthropogenic activities within the watershed have the potential to affect estuary geomorphology. The Sacramento River drains the northern half of California’s Central Valley and is the primary source of sediment to San Francisco Bay. In this paper, it is shown that the delivery of suspended-sediment from the Sacramento River to San Francisco Bay has decreased by about one-half during the period 1957 to 2001. Many factors may be contributing to the trend in sediment yield, including the depletion of erodible sediment from hydraulic mining in the late 1800s, trapping of sediment in reservoirs, riverbank protection, altered land-uses (such as agriculture, grazing, urbanization, and logging), and levees. This finding has implications for planned tidal wetland restoration activities around San Francisco Bay, where an adequate sediment supply will be needed to build subsided areas to elevations typical of tidal wetlands as well as to keep pace with projected sea-level rise. In a broader context, the study underscores the need to address anthropogenic impacts on watershed sediment yield when considering actions such as restoration within downstream depositional areas.

POLANYI-BASED MODELS FOR THE COMPETITIVE SORPTION OF LOW-POLARITY ORGANIC CONTAMINANTS ON A NATURAL SORBENT. (R825406)

EPA Science Inventory

The development of appropriate equilibrium sorption relationships for anthropogenic organic contaminants with soils and sediments is essential to predicting the extents and rates of solid-water interactions in the environment. In this context, we previously reported results that ...

Supporting Documentation Used in the Derivation of Selected Freshwater Tier 2 ESBs

EPA Science Inventory

Compilation of toxicity data used to derive secondary chronic values (SCVs) and tier 2 equilibrium partitioning sediment benchmarks (ESBs) for a selection of nonionic organic chemicals. The values are used in the following U.S. EPA document: U.S. EPA. 2008. Procedures for th...

Mechanism for pH-dependent gene regulation by amino-terminus-mediated homooligomerization of Bacillus subtilis anti-trp RNA-binding attenuation protein

PubMed Central

Sachleben, Joseph R.; McElroy, Craig A.; Gollnick, Paul; Foster, Mark P.

2010-01-01

Anti-TRAP (AT) is a small zinc-binding protein that regulates tryptophan biosynthesis in Bacillus subtilis by binding to tryptophan-bound trp RNA-binding attenuation protein (TRAP), thereby preventing it from binding RNA, and allowing transcription and translation of the trpEDCFBA operon. Crystallographic and sedimentation studies have shown that AT can homooligomerize to form a dodecamer, AT12, composed of a tetramer of trimers, AT3. Structural and biochemical studies suggest that only trimeric AT is active for binding to TRAP. Our chromatographic and spectroscopic data revealed that a large fraction of recombinantly overexpressed AT retains the N-formyl group (fAT), presumably due to incomplete N-formyl-methionine processing by peptide deformylase. Hydrodynamic parameters from NMR relaxation and diffusion measurements showed that fAT is exclusively trimeric (AT3), while (deformylated) AT exhibits slow exchange between both trimeric and dodecameric forms. We examined this equilibrium using NMR spectroscopy and found that oligomerization of active AT3 to form inactive AT12 is linked to protonation of the amino terminus. Global analysis of the pH dependence of the trimer-dodecamer equilibrium revealed a near physiological pKa for the N-terminal amine of AT and yielded a pH-dependent oligomerization equilibrium constant. Estimates of excluded volume effects due to molecular crowding suggest the oligomerization equilibrium may be physiologically important. Because deprotonation favors “active” trimeric AT and protonation favors “inactive” dodecameric AT, our findings illuminate a possible mechanism for sensing and responding to changes in cellular pH. PMID:20713740

Seven years of geomorphic change in the head of Monterey Canyon, CA: Steady state equilibrium or monotonic change?

NASA Astrophysics Data System (ADS)

Smith, D. P.; Kvitek, R. G.; Ross, E.; Iampietro, P.; Paull, C. K.; Sandersfeld, M.

2010-12-01

The head of Monterey submarine canyon has been surveyed with high-precision multibeam sonar at least once each year since September 2002. This poster provides a summary of changes between September 2002 and September 2008. Data were collected with a variety of Reson mulitbeam sonar heads, and logged with an ISIS data acquisition system. Vessel attitude was corrected using an Applanix POS MV equipped with an auxillary C-Nav 2050 GPS receiver. Data were processed and filtered and cleaned in Caris HIPS. Depth changes for various time spans were determined through raster subtraction of pairs of 3-m resolution bathymetric grids in ArcMap. The depth change analyses focused on the canyon floor, except where a landslide occurred on a wall, and where obvious gullying near the headwall had occurred during the time of our study. Canyon walls were generally excluded from analysis. The analysis area was 1,414,240 sq meters. The gross changes between 2002 and 2008 include net erosion of 2,300,000 m^3 +/- 800,000 m^3 of material from the canyon. The annualized rate of net sediment loss from this time frame agrees within an order of magnitude with our previously published estimates from earlier (shorter) time frames, so the erosion events seem to be moderate magnitude and frequent, rather than infrequent and catastrophic. The greatest sediment loss appears to be from lateral erosion of channel-bounding terraces rather than deepening or scouring of the existing channel axis. A single landslide event that occurred in summer 2003 had an initial slide scar (void) volume of 71,000 m^3. The scar was observed to increase annually, and had grown to approximately 96,000 m^3 by 2008. The initial slide was too small to be tsunamigenic. In contrast to the monotonic canyon axis widening, the shoreward terminus of the canyon (canyon lip) appears to be in steady state equilibrium with sediment supply entering the canyon from the littoral zone. The lip position, indicated by the clearly defined shelf/slope break, typically oscillates offshore and onshore about 20 m to 30 m annually, but a 50 m change was measured. This oscillation likely represents cycles of sediment wedge progradation followed by slope failure and shoreward lip retreat. At this time, it appears that buildings along Moss Landing strand are not at risk from net shoreward canyon growth. The canyon appears to be excavating material that was previously stored in the canyon during an era when sediment supply outcompeted submarine transport processes. Published ages and pollen analyses from the canyon walls indicate that an enormous volume of sediment entered the canyon in post-European settlement time, with up to 1.6 m of sediment drape occurring after 1945 (presence of trace DDT). Likewise, 1930’s-era bathymetric charts indicate that major depositional features now located in the canyon were not present in the 1930’s, again suggesting a very young age for the deposits now being excavated from the canyon. One possible source of the young deposits is the construction of nearby Moss Landing Harbor in 1946, which has led to very high erosion rates in adjacent Elkhorn Slough.

Combining remote sensing with an inverse Bruun Rule for the analysis and management of almost equilibrium beaches

NASA Astrophysics Data System (ADS)

Eelsalu, Maris; Soomere, Tarmo; Männikus, Rain

2016-04-01

The management of beaches that suffer from sediment deficit and construction of nearshore infrastructure in locations with intense sediment transit require adequate predictions of the future of the relevant sedimentary systems. To a large extent, this task can be accomplished by using jointly the information about sediment texture and long-term changes in the dry beach volume and the location of the waterline. It is straightforward to evaluate relative changes in the dry beach volume from a succession of airborne laser scanning (ALS) surveys. We use in addition terrestrial laser scanning (TLS) technique to reduce ALS surveys performed with different devices and from different height to the same absolute height. This is accomplished using a TLS survey of a large horizontal surface of constant elevation within ALS snapshots. The most complicated, time-consuming and expensive task in beach management and planning of nearshore infrastructure is to get an adequate picture of the intensity and direction of underwater sediment transport processes. We demonstrate how a simple application of so-called inverse Bruun Rule makes it possible to evaluate the underwater volumetric changes for almost equilibrium beaches. The approach requires three data sets: wave statistics, sediment texture and changes in the average position of the waterline. The main properties of the wave climate, closure depths, magnitude and direction of wave-driven alongshore transport near the test areas are established using a triple nested high-resolution version of the wave model WAM that is forced for 34 years by high-quality marine winds. The relocation of the waterline is extracted from the ALS scanning of elevation isolines of 0.4-0.7 m on the subaerial beach. The technique has been applied to two basically different sections of Tallinn Bay, the Baltic Sea. Pirita Beach is gradually losing sand and requires beach refill while a moderate reclamation action is planned in the vicinity of gradually widening beach in the bayhead of this bay (Russalka beach). Sand volume in the latter area exhibits extensive interannual variations. The changes in the subaerial and underwater part are synchronised whereas the magnitude of changes in the underwater part is by a factor of 2-2.5 larger than similar changes in the subaerial part (that gains about 2000 m3/yr sand in 2008-2014). The discussed technique combined with classic estimates of the wave-driven sediment transport direction demonstrates that the Russalka beach is a convergence area of littoral flow. The existing pattern of sediment motions is such that even a minor shift in the coastline may lead to considerable increase in the transport of sand to neighbouring coastal sections. This conjecture is consistent with the general perception in coastal science that even seemingly small activities may have unexpectedly large potential for remote impacts. Such impacts are well known on high-energy open sea coasts but often considered as minor in relatively sheltered locations.

Pocomoke Sound Sedimentary and Ecosystem History

USGS Publications Warehouse

Cronin, Thomas M.

2004-01-01

Summary of Results: Pocomoke Sound Sediment and Sediment Processes Transport of sediment from coastal marshes. Analyses of pollen and foraminifera from surface sediments in Pocomoke Sound suggest that neither the upstream forested wetlands nor coastal marshes bordering the sound have contributed appreciably to particulate matter in the 10- to 1000-micron size range that is currently being deposited in the sound. Sediment processes derived from short-lived isotope. Analyses of beryllium-7, cesium-137 and lead-210 and redox sensitive elements from Pocomoke sediments showed that there has been a significant increase in anthropogenic elements since the late 1940's when the Delmarva Peninsula became more accessible from the Baltimore-Washington region. Cesium-137 was found to be a useful tool to determine changes in sedimentation within the system. Three major stages of sedimentation occurred. Before 1950, the system was equilibrium with the agriculture activity in the watershed, whereas urbanization and agricultural activity changes during and immediately preceding World War II resulted in increased sediment flux. Around 1970, the sediment flux diminished and there was an apparent increase in bank erosion sediment to the deeper parts of the system. Rates of sediment deposition. Radiocarbon, lead-210, and pollen dating of sediment cores from Pocomoke Sound indicate relatively continuous deposition of fine-grained sediments in the main Pocomoke channel at > ~7 m water depths. Mean sediment accumulation rates during the past few centuries were relatively high (>1 cm yr -1 ). The ages of coarser-grained sediments (sands) blanketing the shallow (4.0 cm yr -1 ) at most sites throughout the Sound in post-Colonial time. These results confirm those from other regions of the bay that land-clearance increased the flux of river-borne sediment to certain r

Determination of adsorption and desorption of DNA molecules on freshwater and marine sediments.

PubMed

Xue, J; Feng, Y

2018-06-01

Free DNA and its adsorption by sediment in the aquatic environment lead to ambiguity in the identification of recent faecal pollution sources. The goal of this study was to understand the mechanisms of DNA adsorption and desorption on aquatic sediment under various conditions using quantitative polymerase chain reaction (qPCR). Both raw sewage (RS) DNA and purified PCR product (PPP) were used in adsorption and desorption experiments; autoclaved freshwater and marine sediments served as sorbents. Thirty-six hours were needed for adsorption to reach equilibrium. More DNA was adsorbed on both sediments in stream water than in 5 mmol l -1 NaCl and DNA adsorption increased in the presence of Ca 2+ and Mg 2+ . Successive desorption experiments showed that between 5% and 22% of adsorbed DNA was desorbed. Organic matter and clay played a significant role in determining the DNA adsorption capacity on sediment. The data suggest the presence of multilayer adsorption. DNA molecules on sediments were mostly adsorbed through ligand binding rather than electrostatic binding. Quantitative polymerase chain reaction assays provide a better way to investigate the DNA adsorption and desorption mechanisms by sediment. DNA desorption can potentially complicate the outcomes of microbial source tracking studies. © 2018 The Society for Applied Microbiology.

In situ passive sampling of sediments in the Lower Duwamish Waterway Superfund site: Replicability, comparison with ex situ measurements, and use of data.

PubMed

Apell, Jennifer N; Gschwend, Philip M

2016-11-01

Superfund sites with sediments contaminated by hydrophobic organic compounds (HOCs) can be difficult to characterize because of the complex nature of sorption to sediments. Porewater concentrations, which are often used to model transport of HOCs from the sediment bed into overlying water, benthic organisms, and the larger food web, are traditionally estimated using sediment concentrations and sorption coefficients estimated using equilibrium partitioning (EqP) theory. However, researchers have begun using polymeric samplers to determine porewater concentrations since this method does not require knowledge of the sediment's sorption properties. In this work, polyethylene passive samplers were deployed into sediments in the field (in situ passive sampling) and mixed with sediments in the laboratory (ex situ active sampling) that were contaminated with polychlorinated biphenyls (PCBs). The results show that porewater concentrations based on in situ and ex situ sampling generally agreed within a factor of two, but in situ concentrations were consistently lower than ex situ porewater concentrations. Imprecision arising from in situ passive sampling procedures does not explain this bias suggesting that field processes like bioirrigation may cause the differences observed between in situ and ex situ polymeric samplers. Copyright © 2016 Elsevier Ltd. All rights reserved.

Large-scale risk assessment of polycyclic aromatic hydrocarbons in shoreline sediments from Saudi Arabia: environmental legacy after twelve years of the Gulf war oil spill.

PubMed

Bejarano, Adriana C; Michel, Jacqueline

2010-05-01

A large-scale assessment of polycyclic aromatic hydrocarbons (PAHs) from the 1991 Gulf War oil spill was performed for 2002-2003 sediment samples (n = 1679) collected from habitats along the shoreline of Saudi Arabia. Benthic sediment toxicity was characterized using the Equilibrium Partitioning Sediment Benchmark Toxic Unit approach for 43 PAHs (ESBTU(FCV,43)). Samples were assigned to risk categories according to ESBTU(FCV,43) values: no-risk (< or = 1), low (>1 - < or = 2), low-medium (>2 - < or = 3), medium (>3 - < or = 5) and high-risk (>5). Sixty seven percent of samples had ESBTU(FCV,43) > 1 indicating potential adverse ecological effects. Sediments from the 0-30 cm layer from tidal flats, and the >30 - <60 cm layer from heavily oiled halophytes and mangroves had high frequency of high-risk samples. No-risk samples were characterized by chrysene enrichment and depletion of lighter molecular weight PAHs, while high-risk samples showed little oil weathering and PAH patterns similar to 1993 samples. North of Safaniya sediments were not likely to pose adverse ecological effects contrary to sediments south of Tanaqib. Landscape and geomorphology has played a role on the distribution and persistence in sediments of oil from the Gulf War. Copyright 2009 Elsevier Ltd. All rights reserved.

Surfactant-enhanced remediation of a trichloroethene-contaminated aquifer. 1. Transport of triton X-100

USGS Publications Warehouse

Smith, J.A.; Sahoo, D.; Mclellan, H.M.; Imbrigiotta, T.E.

1997-01-01

Transport of a nonionic surfactant (Triton X-100) at aqueous concentrations less than 400 mg/L through a trichloroethene-contaminated sand-and-gravel aquifer at Picatinny Arsenal, NJ, has been studied through a series of laboratory and field experiments. In the laboratory, batch and column experiments were conducted to quantify the rate and amount of Triton X-100 sorption to the aquifer sediments. In the field, a 400 mg/L aqueous Triton X-100 solution was injected into the aquifer at a rate of 26.5 L/min for a 35-d period. The transport of Triton X-100 was monitored by sampling and analysis of groundwater at six locations surrounding the injection well. Equilibrium batch sorption experiments showed that Triton X-100 sorbs strongly and nonlinearly to the field soil with the sharpest inflection point of the isotherm occurring at an equilibrium aqueous Triton X-100 concentration close to critical micelle concentration. Batch, soil column, and field experimental data were analyzed with zero-, one-, and two- dimensional (respectively) transient solute transport models with either equilibrium or rate-limited sorption. These analyses reveal that Triton X- 100 sorption to the aquifer solids is slow relative to advective and dispersive transport and that an equilibrium sorption model cannot simulate accurately the observed soil column and field data. Comparison of kinetic sorption parameters from batch, column, and field transport data indicate that both physical heterogeneities and Triton X-100 mass transfer between water and soil contribute to the kinetic transport effects.Transport of a nonionic surfactant (Triton X-100) at aqueous concentrations less than 400 mg/L through a trichloroethene-contaminated sand-and-gravel aquifer was studied. Equilibrium batch sorption experiments showed that Triton X-100 sorbs strongly and nonlinearly to the field soil with the sharpest inflection point of the isotherm occurring at an equilibrium aqueous Triton X-100 concentration close to critical micelle concentration. Batch, soil column, and field experimental data were analyzed with zero-, one-, and two-dimensional transient solute transport models with either equilibrium or rate-limited sorption. These analyses revealed that Triton X-100 sorption to the aquifer solids was slow relative to advective and dispersive transport.

Assembly of hard spheres in a cylinder: a computational and experimental study.

PubMed

Fu, Lin; Bian, Ce; Shields, C Wyatt; Cruz, Daniela F; López, Gabriel P; Charbonneau, Patrick

2017-05-14

Hard spheres are an important benchmark of our understanding of natural and synthetic systems. In this work, colloidal experiments and Monte Carlo simulations examine the equilibrium and out-of-equilibrium assembly of hard spheres of diameter σ within cylinders of diameter σ≤D≤ 2.82σ. Although phase transitions formally do not exist in such systems, marked structural crossovers can nonetheless be observed. Over this range of D, we find in simulations that structural crossovers echo the structural changes in the sequence of densest packings. We also observe that the out-of-equilibrium self-assembly depends on the compression rate. Slow compression approximates equilibrium results, while fast compression can skip intermediate structures. Crossovers for which no continuous line-slip exists are found to be dynamically unfavorable, which is the main source of this difference. Results from colloidal sedimentation experiments at low diffusion rate are found to be consistent with the results of fast compressions, as long as appropriate boundary conditions are used.

Characterizing toxicity of metal-contaminated sediments from mining areas

USGS Publications Warehouse

Besser, John M.; Brumbaugh, William G.; Ingersoll, Christopher G.

2015-01-01

This paper reviews methods for testing the toxicity of metals associated with freshwater sediments, linking toxic effects with metal exposure and bioavailability, and developing sediment quality guidelines. The most broadly applicable approach for characterizing metal toxicity is whole-sediment toxicity testing, which attempts to simulate natural exposure conditions in the laboratory. Standard methods for whole-sediment testing can be adapted to test a wide variety of taxa. Chronic sediment tests that characterize effects on multiple endpoints (e.g., survival, growth, and reproduction) can be highly sensitive indicators of adverse effects on resident invertebrate taxa. Methods for testing of aqueous phases (pore water, overlying water, or elutriates) are used less frequently. Analysis of sediment toxicity data focuses on statistical comparisons between responses in sediments from the study area and responses in one or more uncontaminated reference sediments. For large or complex study areas, a greater number of reference sediments is recommended to reliably define the normal range of responses in uncontaminated sediments – the ‘reference envelope’. Data on metal concentrations and effects on test organisms across a gradient of contamination may allow development of concentration-response models, which estimate metal concentrations associated with specified levels of toxic effects (e.g. 20% effect concentration or EC20). Comparisons of toxic effects in laboratory tests with measures of impacts on resident benthic invertebrate communities can help document causal relationships between metal contamination and biological effects. Total or total-recoverable metal concentrations in sediments are the most common measure of metal contamination in sediments, but metal concentrations in labile sediment fractions (e.g., determined as part of selective sediment extraction protocols) may better represent metal bioavailability. Metals released by the weak-acid extraction of acid-volatile sulfide (AVS), termed simultaneously-extracted metals (SEM), are widely used to estimate the ‘potentially-bioavailable’ fraction of metals that is not bound to sulfides (i.e., SEM-AVS). Metal concentrations in pore water are widely considered to be direct measures of metal bioavailability, and predictions of toxicity based on pore-water metal concentrations may be further improved by modeling interactions of metals with other pore-water constituents using Biotic Ligand Models. Data from sediment toxicity tests and metal analyses has provided the basis for development of sediment quality guidelines, which estimate thresholds for toxicity of metals in sediments. Empirical guidelines such as Probable Effects Concentrations or (PECs) are based on associations between sediment metal concentrations and occurrence of toxic effects in large datasets. PECs do not model bioavailable metals, but they can be used to estimate the toxicity of metal mixtures using by calculation of probable effect quotients (PEQ = sediment metal concentration/PEC). In contrast, mechanistic guidelines, such as Equilibrium Partitioning Sediment Benchmarks (ESBs) attempt to predict both bioavailability and mixture toxicity. Application of these simple bioavailability models requires more extensive chemical characterization of sediments or pore water, compared to empirical guidelines, but may provide more reliable estimates of metal toxicity across a wide range of sediment types.

Hydrogeochemical and mineralogical effects of sustained CO2 contamination in a shallow sandy aquifer: A field-scale controlled release experiment

NASA Astrophysics Data System (ADS)

Cahill, Aaron G.; Marker, Pernille; Jakobsen, Rasmus

2014-02-01

A shallow aquifer CO2 contamination experiment was performed to investigate evolution of water chemistry and sediment alteration following leakage from geological storage by physically simulating a leak from a hypothetical storage site. In a carbonate-free aquifer, in western Denmark, a total of 1600 kg of gas phase CO2 was injected at 5 and 10 m depth over 72 days through four inclined injection wells into aeolian and glacial sands. Water chemistry was monitored for pH, EC, and dissolved element evolution through an extensive network of multilevel sampling points over 305 days. Sediment cores were taken pre and postinjection and analyzed to search for effects on mineralogy and sediment properties. Results showed the simulated leak to evolve in two distinct phases; an advective elevated ion pulse followed by increasing persistent acidification. Spatial and temporal differences in evolution of phases suggest separate chemical mechanisms and geochemical signatures. Dissolved element concentrations developed exhibiting four behaviors: (1) advective pulse (Ca, Mg, Na, Si, Ba, and Sr), (2) pH sensitive abundance dependent (Al and Zn), (3) decreasing (Mn and Fe), and (4) unaffected (K). Concentration behaviors were characterized by: (1) a maximal front moving with advective flow, (2) continual increase in close proximity to the injection plane, (3) removal from solution, and (4) no significant change. Only Al was observed to exceed WHO guidelines, however significantly so (10-fold excess). The data indicate that pH is controlled by equilibrium with gibbsite which is again coupled to cation exchange processes. Pre and postinjection sediment analysis indicated alteration of sediment composition and properties including depletion of reactive mineral species.

Temperature-dependent sorption of naphthalene, phenanthrene, and pyrene to low organic carbon aquifer sediments

USGS Publications Warehouse

Piatt, Joseph J.; Backhus, Debera A.; Capel, Paul D.; Eisenreich, Steven J.

1996-01-01

Sorption experiments were conducted with naphthalene, phenanthrene, and pyrene on low organic carbon sediments at 4 and 26 °C using batch and column techniques. Experimental controls ensured the absence of biologic and photolytic activity and colloid-free solution supernatants. Equilibrium distribution coefficients (Kd) increased 1.1−1.6 times with a decrease in temperature of 22 °C. Fraction instantaneous sorption (F) values did not change significantly with a decrease in temperature of 22 °C. Desorption rate constants (k2) decreased 1.2−2.6 times with a decrease in temperature of 22 °C. Times to equilibrium were at least 40 h. The magnitude of observed Kd and k2 values and the effect of temperature on Kd (e.g., low enthalpy of sorption) are consistent with sorbate partitioning between the aqueous phase and small amounts of organic matter (foc = 0.02%) on the sediments. The temperature dependence of Kd and k2 may be small as compared to the effects of heterogeneities in field-scale aquifer systems. Thus, thermal gradients may not be of major importance in most saturated subsurface regimes when predicting solute transport. However, aquifer remediation pump-and-treat times could be decreased because increased temperature decreases both retardation and tailing.

Deriving sediment Interstitial Water Remediation Goals ...

EPA Pesticide Factsheets

Background/Objectives. Passive sampling is becoming a frequently used measurement technique at Superfund sites with contaminated sediments. Passive sampling measures the concentrations of freely dissolved chemicals (Cfrees) in the sediment interstitial water. The freely dissolved chemical is a good surrogate for and a very practical means for estimating the concentrations of bioavailable chemical in the sediments. Building from this approach, a methodology is proposed to derive sediment Interstitial Water Remediation Goals (IWRGs) for the protection of benthic organisms from direct toxicity using Cfrees measured with passive sampling.Approach/Activities. In the early 2000s, EPA developed and released Equilibrium Partitioning Sediment Benchmarks (ESBs) for a series of chemicals. ESBs are intended to be chemical concentrations below which unacceptable toxicity to benthic organisms does not occur. The ESBs (expressed with the units of ug/g OC) were derived using the equations:ESB= K_OC×FCV where K_OC=0.00028+0.983K_OWThe KOC is the organic carbon normalized sediment-water chemical partition coefficient, FCV is the Final Chronic Value from EPA’s ambient water quality criteria for the protection of aquatic life, and KOW is the n-octanol/water partition coefficient for the chemical. At a specific site, the remedial goal (CS:ESB µg/kg-dw) in sediment are then derived using the site-specific fraction of organic carbon in the sediment (fOC:SS) at the site:C_

Equilibrium concentration profiles and sedimentation kinetics of colloidal gels under gravitational stress

NASA Astrophysics Data System (ADS)

Buzzaccaro, S.; Secchi, E.; Brambilla, G.; Piazza, R.; Cipelletti, L.

2012-07-01

We study the sedimentation of colloidal gels by using a combination of light scattering, polarimetry and video imaging. The asymptotic concentration profiles φ(z,t → ∞) exhibit remarkable scaling properties: profiles for gels prepared at different initial volume fractions and particle interactions can be superimposed onto a single master curve by using suitable reduced variables. We show theoretically that this behavior stems from a power law dependence of the compressive elastic modulus versus φ, which we directly test experimentally. The sedimentation kinetics comprises an initial latency stage, followed by a rapid collapse where the gel height h decreases at constant velocity and a final compaction stage characterized by a stretched exponential relaxation of h toward a plateau. Analogies and differences with previous works are briefly discussed.

Direct atmospheric deposition of 210Pb to rivers determined through 210Pb (210Po) disequilibrium and implications to sediment source apportionment

NASA Astrophysics Data System (ADS)

Blumentritt, D. J.; Shottler, S.; Engstrom, D. R.

2011-12-01

Atmospheric radioisotopes such as 210Pb can be an effective tool for determining sediment source types in rivers and streams. Pb-210 is ubiquitous in deposition from atmospheric washout and is highly particle reactive, so sediments derived from a surface with prolonged exposure to rainfall, such as farm fields, are enriched in atmospheric 210Pb. Conversely, sediment sources that are not readily exposed to rainfall (i.e. streambanks) are absent of any appreciable 210Pb. Many sediment source apportionment studies have used 210Pb to quantify the proportion of sediment loads from the two source types, field and non-field. These studies, however, primarily take place in smaller watersheds where 210Pb that falls directly onto the surface of the water is assumed negligible. Lake Pepin is a riverine lake located in southeastern Minnesota with a 122,000 km2 watershed composed of three major rivers, the Minnesota, headwaters Mississippi, and St. Croix. The sediment load in Lake Pepin has increased by an order of magnitude since Euro-American settlement in the region. Most of the sediment (>80%) is transported to Lake Pepin from the highly agricultural Minnesota River basin. Extensive sediment fingerprinting work has been done on Lake Pepin sediments, but a source of significant uncertainty still exists: How much of the 210Pb measured in Lake Pepin is directly deposited to the surface of the contributing water bodies and did not enter on eroded particles? To answer this important question, we have developed a method to quantify the amount of directly deposited 210Pb. Alpha spectrometry is used to measure 210Po, a daughter product of 210Pb decay. Because 210Po has a short half-life (138 days), it takes approximately one year to reach equilibrium with 210Pb on sediment particles. If deposition of 210Pb directly from the atmosphere to the water surface is significant, there will be disequilibrium between the two radioisotopes and the activity of 210Po will increase as an inverse exponential function, with respect to time, following sample collection. The magnitude of this increase is the amount of directly deposited 210Pb. Samples were collected at four locations, corresponding to gauging stations, on the Minnesota/Mississippi River system above Lake Pepin. Three measurements were made on each sample over the course of a year after collection. Based on those three measurements, the activity of 210Po was modeled for time zero and for the equilibrium concentration, revealing the amount of 210Pb from direct atmospheric deposition. These estimates were flow-weighted over the course of the year, providing a critical correction to the source apportionment model.

Tracing the sources and cycling of phosphorus in river sediments using oxygen isotopes: Methodological adaptations and first results from a case study in France.

PubMed

Pistocchi, Chiara; Tamburini, Federica; Gruau, Gerard; Ferhi, André; Trevisan, Dominique; Dorioz, Jean-Marcel

2017-03-15

An essential aspect of eutrophication studies is to trace the ultimate origin of phosphate ions (P-PO 4 ) associated with the solid phase of river sediments, as certain processes can make these ions available for algae. However, this is not a straightforward task because of the diversity of allochthonous and autochthonous sources that can supply P-PO 4 to river sediments as well as the existence of in-stream processes that can change the speciation of these inputs and obscure the original sources. Here, we present the results of a study designed to explore the potentials, limitations and conditions for the use of the oxygen isotope composition of phosphate (δ 18 Op) extracted from river sediments for this type of tracing. We first tested if the method commonly applied to soils to purify P-PO 4 and to measure their δ 18 Op concentrations could be adapted to sediments. We then applied this method to a set of sediments collected in a river along a gradient of anthropogenic pressure and compared their isotopic signatures with those from samples that are representative of the potential P-PO 4 inputs to the river system (soils and riverbank material). The results showed that following some adaptations, the purification method could be successfully transposed to river sediments with a high level of P-PO 4 purification (>97%) and high δ 18 Op measurement repeatability and accuracy (<0.4‰). The values for the potential allochthonous sources varied from 11.8 to 18.3‰, while the δ 18 Op value for the river sediments ranged from 12.2 to 15.8‰. Moreover, a sharp increase (>3‰) in the sediment δ 18 Op value immediately downstream from the discharge point revealed the strong impact of municipal wastewater. The calculation of the theoretical equilibrium δ 18 O p values using the river water temperature and δ 18 O w showed that the downstream sediments were in equilibrium, which was not the case for the upstream sediments. This difference could be related to the contrast between the short residence time of the transfer system in the catchment head, which can preserve the isotopic variability of the source materials, and the longer residence times and higher P bioavailability in the lower catchment, possibly fostering the recycling of P-PO 4 by the biota and the equilibration of the oxygen isotope signature in P-PO 4 . These results demonstrate the potential of the isotopic approach to assess the sources and in-stream turnover of sedimentary P in river systems. Copyright © 2016 Elsevier Ltd. All rights reserved.

Three-Dimensional Sediment Dynamics in Well-Mixed Estuaries: Importance of the Internally Generated Overtide, Spatial Settling Lag, and Gravitational Circulation

NASA Astrophysics Data System (ADS)

Wei, Xiaoyan; Kumar, Mohit; Schuttelaars, Henk M.

2018-02-01

To investigate the dominant sediment transport and trapping mechanisms, a semi-analytical three-dimensional model is developed resolving the dynamic effects of salt intrusion on sediment in well-mixed estuaries in morphodynamic equilibrium. As a study case, a schematized estuary with a converging width and a channel-shoal structure representative for the Delaware estuary is considered. When neglecting Coriolis effects, sediment downstream of the estuarine turbidity maximum (ETM) is imported into the estuary through the deeper channel and exported over the shoals. Within the ETM region, sediment is transported seaward through the deeper channel and transported landward over the shoals. The largest contribution to the cross-sectionally integrated seaward residual sediment transport is attributed to the advection of tidally averaged sediment concentrations by river-induced flow and tidal return flow. This contribution is mainly balanced by the residual landward sediment transport due to temporal correlations between the suspended sediment concentrations and velocities at the M2 tidal frequency. The M2 sediment concentration mainly results from spatial settling lag effects and asymmetric bed shear stresses due to interactions of M2 bottom velocities and the internally generated M4 tidal velocities, as well as the salinity-induced residual currents. Residual advection of tidally averaged sediment concentrations also plays an important role in the landward sediment transport. Including Coriolis effects hardly changes the cross-sectionally integrated sediment balance, but results in a landward (seaward) sediment transport on the right (left) side of the estuary looking seaward, consistent with observations from literature. The sediment transport/trapping mechanisms change significantly when varying the settling velocity and river discharge.

Is “morphodynamic equilibrium” an oxymoron?

USGS Publications Warehouse

Zhou, Zeng; Coco, Giovanni; Townend, Ian; Olabarrieta, Maitane; van der Wegen, Mick; Gong, Zheng; D'Alpaos, Andrea; Gao, Shu; Jaffe, Bruce E.; Gelfenbaum, Guy R.; He, Qing; Wang, Yaping; Lanzoni, Stefano; Wang, Zhengbing; Winterwerp, Han; Zhang, Changkuan

2017-01-01

Morphodynamic equilibrium is a widely adopted yet elusive concept in the field of geomorphology of coasts, rivers and estuaries. Based on the Exner equation, an expression of mass conservation of sediment, we distinguish three types of equilibrium defined as static and dynamic, of which two different types exist. Other expressions such as statistical and quasi-equilibrium which do not strictly satisfy the Exner conditions are also acknowledged for their practical use. The choice of a temporal scale is imperative to analyse the type of equilibrium. We discuss the difference between morphodynamic equilibrium in the “real world” (nature) and the “virtual world” (model). Modelling studies rely on simplifications of the real world and lead to understanding of process interactions. A variety of factors affect the use of virtual-world predictions in the real world (e.g., variability in environmental drivers and variability in the setting) so that the concept of morphodynamic equilibrium should be mathematically unequivocal in the virtual world and interpreted over the appropriate spatial and temporal scale in the real world. We draw examples from estuarine settings which are subject to various governing factors which broadly include hydrodynamics, sedimentology and landscape setting. Following the traditional “tide-wave-river” ternary diagram, we summarize studies to date that explore the “virtual world”, discuss the type of equilibrium reached and how it relates to the real world.

Do weirs affect the physical and geochemical mobility of toxic metals in mining-impacted floodplain sediments?

NASA Astrophysics Data System (ADS)

Bulcock, Amelia; Coleman, Alexandra; Whitfield, Elizabeth; Andres Lopez-Tarazon, Jose; Byrne, Patrick; Whitfield, Greg

2015-04-01

Weirs are common river structures designed to modify river channel hydraulics and hydrology for purposes of navigation, flood defence, irrigation and hydrometry. By design, weirs constrain natural flow processes and affect sediment flux and river channel forms leading to homogenous river habitats and reduced biodiversity. The recent movement towards catchment-wide river restoration, driven by the EU Water Framework Directive, has recognised weirs as a barrier to good ecological status. However, the removal of weirs to achieve more 'natural' river channels and flow processes is inevitably followed by a period of adjustment to the new flow regime and sediment flux. This period of adjustment can have knock-on effects that may increase flood risk, sedimentation and erosion until the river reaches a state of geomorphological equilibrium. Many catchments in the UK contain a legacy of toxic metals in floodplain sediments due to historic metal mining activities. The consequences of weir removal in these catchments may be to introduce 'stored' mine wastes into the river system with severe implications for water quality and biodiversity. The purpose of this study is to investigate the potential impact of a weir on the physical and geochemical mobilisation of mine wastes in the formerly mined River Twymyn catchment, Wales. Our initial investigations have shown floodplain and riverbed sediments to be grossly contaminated (up to 15,500 mg/kg Pb) compared to soil from a pre-mining Holocene terrace (180 mg/kg Pb). Geomorphological investigations also suggest that weir removal will re-establish more dynamic river channel processes resulting in lateral migration of the channel and erosion of contaminated floodplain sediments. These data will be used as a baseline for more detailed investigations of the potential impact of weirs on the physical and geochemical mobilisation of contaminated sediments. We have two specific objectives. (1) Geomorphological assessments will use unmanned aerial vehicle (UAV) photographic surveys, historical aerial photographs, ground-based topographic surveys, surface and subsurface particle size determination, bed stability and sediment entrainment assessment, together with discharge and sediment (both suspended and bedload) monitoring to establish the effect of the weir on patterns of sediment flux and the physical transport of metal contaminants. 2D and 1D models (IBER, HEC-RAS) of the weir-affected reach will investigate sediment and metal flux following weir removal. (2) The physicochemical speciation and geochemical stability of contaminated floodplain sediments will be characterised using bulk chemistry, mineralogical (XRD, SEM) and speciation methods (sequential extractions, electron microprobe analysis).

SEDIMENT-AIR EQUILIBRIUM PARTITIONING OF SEMI-VOLATILE HYDROPHOBIC ORGANIC COMPOUNDS. PART 1. METHOD DEVELOPMENT AND WATER VAPOR SORPTION ISOTHERM. (R825513C017)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

Bed topography and sand transport responses to a step change in discharge and water depth

USDA-ARS?s Scientific Manuscript database

Ephemeral streams with sand and gravel beds may inherit bed topography caused by previous flow events, resulting in bed topography that is not in equilibrium with flow conditions, complicating the modeling of flow and sediment transport. Major flow events, resulting from rainfall with high intensity...

Gas hydrate property measurements in porous sediments with resonant ultrasound spectroscopy

NASA Astrophysics Data System (ADS)

McGrail, B. P.; Ahmed, S.; Schaef, H. T.; Owen, A. T.; Martin, P. F.; Zhu, T.

2007-05-01

Resonant ultrasound spectroscopy was used to characterize a natural geological core sample obtained from the Mallik 5L-38 gas hydrate research well at high pressure and subambient temperatures. Using deuterated methane gas to form gas hydrate in the core sample, it was discovered that resonance amplitudes are correlated with the fraction of the pore space occupied by the gas hydrate crystals. A pore water freezing model was developed that utilizes the known pore size distribution and pore water chemistry to predict gas hydrate saturation as a function of pressure and temperature. The model showed good agreement with the experimental measurements and demonstrated that pore water chemistry is the most important factor controlling equilibrium gas hydrate saturations in these sediments when gas hydrates are formed artificially in laboratory pressure vessels. With further development, the resonant ultrasound technique can provide a rapid, nondestructive, field portable means of measuring the equilibrium P-T properties and dissociation kinetics of gas hydrates in porous media, determining gas hydrate saturations, and may provide new insights into the nature of gas hydrate formation mechanisms in geologic materials.

A pre-dam-removal assessment of sediment transport for four dams on the Kalamazoo River between Plainwell and Allegan, Michigan

USGS Publications Warehouse

Syed, Atiq U.; Bennett, James P.; Rachol, Cynthia M.

2005-01-01

Four dams on the Kalamazoo River between the cities of Plainwell and Allegan, Mich., are in varying states of disrepair. The Michigan Department of Environmental Quality (MDEQ) and U.S. Environmental Protection Agency (USEPA) are considering removing these dams to restore the river channels to pre-dam conditions. This study was initiated to identify sediment characteristics, monitor sediment transport, and predict sediment resuspension and deposition under varying hydraulic conditions. The mathematical model SEDMOD was used to simulate streamflow and sediment transport using three modeling scenarios: (1) sediment transport simulations for 730 days (Jan. 2001 to Dec. 2002), with existing dam structures, (2) sediment transport simulations based on flows from the 1947 flood at the Kalamazoo River with existing dam structures, and (3) sediment transport simulations based on flows from the 1947 flood at the Kalamazoo River with dams removed. Sediment transport simulations based on the 1947 flood hydrograph provide an estimate of sediment transport rates under maximum flow conditions. These scenarios can be used as an assessment of the sediment load that may erode from the study reach at this flow magnitude during a dam failure. The model was calibrated using suspended sediment as a calibration parameter and root mean squared error (RMSE) as an objective function. Analyses of the calibrated model show a slight bias in the model results at flows higher than 75 m3/s; this means that the model-simulated suspended-sediment transport rates are higher than the observed rates; however, the overall calibrated model results show close agreement between simulated and measured values of suspended sediment. Simulation results show that the Kalamazoo River sediment transport mechanism is in a dynamic equilibrium state. Model results during the 730-day simulations indicate significant sediment erosion from the study reach at flow rates higher than 55 m3/s. Similarly, significant sediment deposition occurs during low to average flows (monthly mean flows between 25.49 m3/s and 50.97 m3/s) after a high-flow event. If the flow continues to stay in the low to average range the system shifts towards equilibrium, resulting in a balancing effect between sediment deposition and erosion rates. The 1947 flood-flow simulations show approximately 30,000 m3 more instream sediments erosion for the first 21 days of the dams removed scenario than for the existing-dams scenario, with the same initial conditions for both scenarios. Application of a locally weighted regression smoothing (LOWESS) function to simulation results of the dams removed scenario indicates a steep downtrend with high sediment transport rates during the first 21 days. In comparison, the LOWESS curve for the existing-dams scenario shows a smooth transition of sediment transport rates in response to the change in streamflow. The high erosion rates during the dams-removed scenario are due to the absence of the dams; in contrast, the presence of dams in the existing-dams scenario helps reduce sediment erosion to some extent. The overall results of 60-day simulations for the 1947 flood show no significant difference in total volume of eroded sediment between the two scenarios, because the dams in the study reach have low heads and no control gates. It is important to note that the existing-dams and dams-removed scenarios simulations are run for only 60 days; therefore, the simulations take into account the changes in sediment erosion and deposition rates only during that time period. Over an extended period, more erosion of instream sediments would be expected to occur if the dams are not properly removed than under the existing conditions. On the basis of model simulations, removal of dams would further lower the head in all the channels. This lowering of head could produce higher flow velocities in the study reach, which ultimately would result in accelerated erosion rates.

Cycling of mercury across the sediment-water interface in seepage lakes: Chapter 13, Advances in Chemistry

USGS Publications Warehouse

Hurley, James P.; Krabbenhoft, David P.; Babiarz, Christopher L.; Andren, Anders

1994-01-01

The magnitude and direction of Hg fluxes across the sediment—water interface were estimated by groundwater, dry bulk sediment, sediment pore water, sediment trap, and water-column analyses in two northern Wisconsin seepage lakes. Little Rock Lake (Treatment Basin) received no groundwater discharge during the study period (1988—1990), and Follette Lake received continuous groundwater discharge. In Little Rock Lake, settling of particulate matter accounted for the major Hg delivery mechanism to the sediment—water interface. Upward diffusion of Hg from sediment pore waters below 2—4-cm sediment depth was apparently a minor source during summer stratification. Time-series comparisons suggested that the observed buildup of Hg in the hypolimnion of Little Rock Lake was attributable to dissolution and diffusion of Hg from recently fallen particulate matter close to the sediment—water interface. Groundwater inflow represented an important source of new Hg, and groundwater outflow accounted for significant removal of Hg from Pallette Lake. Equilibrium speciation calculations revealed that association of Hg with organic matter may control solubility in well-oxygenated waters, whereas in anoxic environments sulfur (polysulfide and bisulfide) complexation governs dissolved total Hg levels.

Formation of natural gas hydrates in marine sediments. Gas hydrate growth and stability conditioned by host sediment properties

USGS Publications Warehouse

Clennell, M.B.; Henry, P.; Hovland, M.; Booth, J.S.; Winters, W.J.; Thomas, M.

2000-01-01

The stability conditions of submarine gas hydrates (methane clathrates) are largely dictated by pressure, temperature, gas composition, and pore water salinity. However, the physical properties and surface chemistry of the host sediments also affect the thermodynamic state, growth kinetics, spatial distributions, and growth forms of clathrates. Our model presumes that gas hydrate behaves in a way analogous to ice in the pores of a freezing soil, where capillary forces influence the energy balance. Hydrate growth is inhibited within fine-grained sediments because of the excess internal phase pressure of small crystals with high surface curvature that coexist with liquid water in small pores. Therefore, the base of gas hydrate stability in a sequence of fine sediments is predicted by our model to occur at a lower temperature, and so nearer to the seabed than would be calculated from bulk thermodynamic equilibrium. The growth forms commonly observed in hydrate samples recovered from marine sediments (nodules, sheets, and lenses in muds; cements in sand and ash layers) can be explained by a requirement to minimize the excess of mechanical and surface energy in the system.

Comparative phosphorus sorption by marine sediments and agricultural soils in a tropical environment.

PubMed

Fox, Robert L; Fares, Ali; Wan, Y; Evensen, Carl I

2006-01-01

The influence of soil phosphorus (P) sources on P sorption characteristics of marine sediments was investigated for Pearl Harbor and off shore Molokai in Hawaii. Estuary sediments were sampled in seven locations; these represented different soils and on-shore activities. The soil samples included nine major soils that contributed sediment to the Harbor and coastal sediments near the island of Molokai. Sediment and soil samples were equilibrated for 6 days in 0.01 M CaCl(2) solution and synthetic seawater containing differing amounts of P. Phosphorus sorption curves were constructed. The equilibrated solution P, with no P added, ranged from 0.01 to 0.2 mg L(-1); P sorption by sediments at standard solution concentration 0.2 mg L(-1), ranged from 0 to 230 mg kg(-1). Sediment P sorption corresponded closely with soil sorption characteristics. Soils contributing sediments to the west reach of Pearl Harbor are highly weathered Oxisols with high standard P sorption values while those in the southeast of the Harbor were Vertisols and Mollisols which sorb little P. The influence of source materials on sediment P sorption was also observed for off-shore sediments near Molokai. Sediments serve as both source and sink for P in Pearl Harbor and in this role can be a stabilizing influence on P concentration in the water column. Phosphorus sorption curves in conjunction with water quality data can help to understand P dynamics between sediments and the water column and help evaluate concerns about P loading to a water body. For Pearl Harbor, solution P in equilibrium with sediments from the Lochs was 0.021 mg L(-1); a value unlikely to produce an algal bloom. (Measured total P in the water columns (mean) was 0.060.).

A screening level probabilistic ecological risk assessment of PAHs in sediments of San Francisco Bay

DOE Office of Scientific and Technical Information (OSTI.GOV)

Febbo, E.J.; Arnold, W.R.; Biddinger, G.R.

1995-12-31

As part of the Regional Monitoring Program administered by the San Francisco Estuary Institute (SFEI), sediment samples were collected at 20 stations in San Francisco Bay and analyzed to determine concentrations of 43 PAHs. These data were obtained from SFEI and used to calculate the potential risk to aquatic organisms using probabilistic modeling and Monte Carlo statistical procedures. Sediment chemistry data were used in conjunction with a sediment equilibrium model, a bioconcentration model, biota-sediment accumulation factors, and critical body burden effects concentrations to assess potential risk to bivalves. Bivalves were the chosen receptors because they lack a well-developed enzymatic systemmore » for metabolizing PAHs. Thus, they more readily accumulate PAHs and represent a species at greater risk than other taxa, such as fish and crustaceans. PAHs considered in this study span a broad range of octanol-water partition coefficients. Results indicate that risk of non-polar narcotic effects from PAHs was low in the Northern Bay Area, but higher in the South Bay near the more urbanized sections of the drainage basin.« less

Tetracyclic diterpenoid hydrocarbons in some Australian coals, sediments and crude oils

NASA Astrophysics Data System (ADS)

Noble, Rohinton A.; Alexander, Robert; Kagi, Robert Ian; Knox, John

1985-10-01

Tetracyclic diterpenoid hydrocarbons (diterpanes) based on the ent-beyerane, phyllocladane and ent-kaurane skeletons have been identified in the hydrocarbon extracts of some Australian coals, sediments and crude oils. Structures were assigned to the geological diterpanes by comparison with synthetically prepared reference compounds. Studies of a sample suite consisting of low-rank coals and sediments indicate that the ratios of C-16 epimers of phyllocladane and ent-kaurane are maturity dependent, and that the relative proportion of the thermodynamically preferred 16β (H)-compounds increases with increasing thermal maturity. Thermodynamic equilibrium for the interconversion reactions is attained in sediments before the onset of crude oil generation. The most likely natural product precursors for the tetracyclic diterpanes are considered to be the tetracyclic diterpene hydrocarbons which occur widely in the leaf resins of conifers. Tetracyclic diterpanes have been identified in sediments and coals of Permian age or younger, suggesting that these compounds are markers for both modern and extinct families of conifers. In particular, phyllocladane is proposed as a marker for the Podocarpaceae family of conifers.

Conductivity dependence of seismoelectric wave phenomena in fluid-saturated sediments

NASA Astrophysics Data System (ADS)

Block, Gareth I.; Harris, John G.

2006-01-01

Seismoelectric phenomena in sediments arise from acoustic wave-induced fluid motion in the pore space, which perturbs the electrostatic equilibrium of the electric double layer on the grain surfaces. Experimental techniques and the apparatus built to study the conductivity dependence of the electrokinetic (EK) effect are described, and outcomes for studies in loose glass microspheres and medium-grain sand are presented. By varying the NaCl concentration in the pore fluid, we measured the conductivity dependence of two kinds of EK behavior: (1) the electric fields generated within the samples by the passage of transmitted acoustic waves and (2) the electromagnetic waves produced at the fluid-sediment interface by the incident acoustic wave. Both phenomena are caused by relative fluid motion in the sediment pores; this feature is characteristic of poroelastic (Biot) media but is not predicted by either viscoelastic fluid or solid models. A model of plane wave reflection from a fluid-sediment interface using EK-Biot theory leads to theoretical predictions that compare well to the experimental data for both loose glass microspheres and medium-grain sand.

Geochemical controls on lead concentrations in stream water and sediments

USGS Publications Warehouse

Hem, J.D.

1976-01-01

The equilibrium distribution of lead in solution and adsorbed on cation exchange sites in sediment theoretically may be calculated from equations representing selectivities of substrate for lead over H+, Ca2+ and Na+, and the stabilities of lead solute species. Such calculations include consideration of total concentrations of major ions, cation exchange capacity (CEC) of substrate, and pH, at values expected in various natural systems. Measurements of CEC and selectivity coefficients were made for synthetic halloysite, a finely divided amorphous 1:1 clay prepared by precipitation from a mixture of solutions of aluminum and silica. Where suspended sediment having the same properties is present in concentrations of 10-1,000 mg/1 at pH 6-8, more than 90% of the lead present can be adsorbed on sediment surfaces. The cation exchange behavior of lead and other minor cationic species in natural systems could be predicted by this type of model if enough other supporting information were available. Information of the type needed describing natural stream sediments, however, is presently inadequate for accurate predictions. ?? 1976.

Influence of the sediment transport threshold on a river network (Invited)

NASA Astrophysics Data System (ADS)

Devauchelle, O.; Petroff, A.; Seybold, H. F.; Rothman, D.

2010-12-01

In order to transport sediment as bedload, a river must impose a sufficient shear stress on its bed. Conversely, a river far above the threshold for bedload would quickly erode its bed and decrease its slope, thus returning towards the threshold. In 1961, F. M. Henderson first used this hypothesis to derive theoretically Lacey's law (which states that the width of a river scales with the square root of its discharge). His reasoning can be extended to demonstrate that, under similar conditions, the product of the water discharge with the square of its slope is constant (Q S2 = const.), the value of this constant depending on the sediment properties. The steephead ravines of the Florida panhandle, formed by seepage erosion in a homogeneous sand plateau, fall remarkably close to Henderson's equilibrium. Thanks to the uniformity of the sediment and to the steady input of groundwater, the hundreds of streams which drain this landscape are ideal field cases to understand how the quasi-equilibrium hypothesis constrains the network structure. Indeed, both Lacey's equation and the above discharge-slope relation are satisfied in the field. The slope-discharge relation Q S2 = const. is a boundary condition for both the aquifer and the landscape itself, as it relates the flux of water drained by the streams to their longitudinal profile. A direct illustration of this coupling is the shape of the longitudinal profile of rivers in the neighborhood of their springs, which we predict theoretically. The boundary condition Q S2 = const. also holds further downstream, and raises delicate theoretical questions concerning the architecture of the entire network. In particular, we address the limitation of the distance between a spring and the first confluence of a stream.

Invasion of drilling mud into gas-hydrate-bearing sediments. Part I: effect of drilling mud properties

NASA Astrophysics Data System (ADS)

Ning, Fulong; Zhang, Keni; Wu, Nengyou; Zhang, Ling; Li, Gang; Jiang, Guosheng; Yu, Yibing; Liu, Li; Qin, Yinghong

2013-06-01

To our knowledge, this study is the first to perform a numerical simulation and analysis of the dynamic behaviour of drilling mud invasion into oceanic gas-hydrate-bearing sediment (GHBS) and to consider the effects of such an invasion on borehole stability and the reliability of well logging. As a case study, the simulation background sets up the conditions of mud temperature over hydrate equilibrium temperature and overbalanced drilling, considering the first Chinese expedition to drill gas hydrate (GMGS-1). The results show that dissociating gas may form secondary hydrates in the sediment around borehole by the combined effects of increased pore pressure (caused by mud invasion and flow resistance), endothermic cooling that accompanies hydrate dissociation compounded by the Joule-Thompson effect and the lagged effect of heat transfer in sediments. The secondary hydrate ring around the borehole may be more highly saturated than the in situ sediment. Mud invasion in GHBS is a dynamic process of thermal, fluid (mud invasion), chemical (hydrate dissociation and reformation) and mechanical couplings. All of these factors interact and influence the pore pressure, flow ability, saturation of fluid and hydrates, mechanical parameters and electrical properties of sediments around the borehole, thereby having a strong effect on borehole stability and the results of well logging. The effect is particularly clear in the borehole SH7 of GMGS-1 project. The borehole collapse and resistivity distortion were observed during practical drilling and wireline logging operations in borehole SH7 of the GMGS-1.mud density (i.e. the corresponding borehole pressure), temperature and salinity have a marked influence on the dynamics of mud invasion and on hydrate stability. Therefore, perhaps well-logging distortion caused by mud invasion, hydrate dissociation and reformation should be considered for identifying and evaluating gas hydrate reservoirs. And some suitable drilling measurements need to be adopted to reduce the risk of well-logging distortion and borehole instability.

Assessment of the bioavailability and phytotoxicity of sediment spiked with polycyclic aromatic hydrocarbons.

PubMed

Rončević, Srđan; Spasojević, Jelena; Maletić, Snežana; Jazić, Jelena Molnar; Isakovski, Marijana Kragulj; Agbaba, Jasmina; Grgić, Marko; Dalmacija, Božo

2016-02-01

Large amounts of sediment are dredged globally every year. This sediment is often contaminated with low concentrations of metals, polycyclic aromatic hydrocarbons, pesticides and other organic pollutants. Some of this sediment is disposed of on land, creating a need for risk assessment of the sediment disposal method, to minimize the degradation of environmental quality and prevent risks to human health. Evaluating the available fractions of certain polycyclic aromatic hydrocarbons is very important, as in the presence of various organisms, they are believed to be easily subject to the processes of bioaccumulation, biosorption and transformation. In order to determine the applicability of applying these methods for the evaluation of pollutant bioavailability in sediments, the desorption kinetics from the sediment of various polycyclic aromatic hydrocarbons in the presence of Tenax and XAD4 were examined over the course of 216 h. Changes in the PAH concentrations in dredged sediments using five different seed plants during a short time of period (10 days) were also followed. Using chemical extraction techniques with Tenax and XAD4, a time of around 24 h is enough to achieve equilibrium for all four PAHs. Results showed good agreement between the seed accumulation and PAH extraction methods with both agents. If we compare the two extraction techniques, XAD4 gave better results for phenanthrene, pyrene and benzo(a)pyrene, and Tenax gave better results for chrysene.

Basin scale controls on CO2 and CH4 emissions from the Upper Mississippi River

USGS Publications Warehouse

Crawford, John T.; Loken, Luke C.; Stanley, Emily H.; Stets, Edward G.; Dornblaser, Mark M.; Striegl, Robert G.

2016-01-01

The Upper Mississippi River, engineered for river navigation in the 1930s, includes a series of low-head dams and navigation pools receiving elevated sediment and nutrient loads from the mostly agricultural basin. Using high-resolution, spatially resolved water quality sensor measurements along 1385 river kilometers, we show that primary productivity and organic matter accumulation affect river carbon dioxide and methane emissions to the atmosphere. Phytoplankton drive CO2to near or below atmospheric equilibrium during the growing season, while anaerobic carbon oxidation supports a large proportion of the CO2 and CH4 production. Reductions of suspended sediment load, absent of dramatic reductions in nutrients, will likely further reduce net CO2emissions from the river. Large river pools, like Lake Pepin, which removes the majority of upstream sediments, and large agricultural tributaries downstream that deliver significant quantities of sediments and nutrients, are likely to persist as major geographical drivers of greenhouse gas emissions.

Influence of variable chemical conditions on EDTA-enhanced transport of metal ions in mildly acidic groundwater

USGS Publications Warehouse

Kent, D.B.; Davis, J.A.; Joye, J.L.; Curtis, G.P.

2008-01-01

Adsorption of Ni and Pb on aquifer sediments from Cape Cod, Massachusetts, USA increased with increasing pH and metal-ion concentration. Adsorption could be described quantitatively using a semi-mechanistic surface complexation model (SCM), in which adsorption is described using chemical reactions between metal ions and adsorption sites. Equilibrium reactive transport simulations incorporating the SCMs, formation of metal-ion-EDTA complexes, and either Fe(III)-oxyhydroxide solubility or Zn desorption from sediments identified important factors responsible for trends observed during transport experiments conducted with EDTA complexes of Ni, Zn, and Pb in the Cape Cod aquifer. Dissociation of Pb-EDTA by Fe(III) is more favorable than Ni-EDTA because of differences in Ni- and Pb-adsorption to the sediments. Dissociation of Ni-EDTA becomes more favorable with decreasing Ni-EDTA concentration and decreasing pH. In contrast to Ni, Pb-EDTA can be dissociated by Zn desorbed from the aquifer sediments. Variability in adsorbed Zn concentrations has a large impact on Pb-EDTA dissociation.

Large scale clear-water local pier scour experiments

USGS Publications Warehouse

Sheppard, D.M.; Odeh, M.; Glasser, T.

2004-01-01

Local clear-water scour tests were performed with three different diameter circular piles (0. 114, 0.305, and 0.914 m), three different uniform cohesionless sediment diameters (0.22, 0.80, and 2.90 mm) and a range of water depths and flow velocities. The tests were performed in the 6.1 m wide, 6.4 m deep, and 38.4 m long flume at the United States Geological Survey Conte Research Center in Turners Falls, Mass. These tests extend local scour data obtained in controlled experiments to prototype size piles and ratios of pile diameter to sediment diameter to 4,155. Supply water for this flow through flume was supplied by a hydroelectric power plant reservoir and the concentration of suspended fine sediment (wash load) could not be controlled. Equilibrium scour depths were found to depend on the wash load concentration. ?? ASCE.

Development and application of a three dimensional numerical model for predicting pollutant and sediment transport using an Eulerian-Lagrangian marker particle technique

NASA Technical Reports Server (NTRS)

Pavish, D. L.; Spaulding, M. L.

1977-01-01

A computer coded Lagrangian marker particle in Eulerian finite difference cell solution to the three dimensional incompressible mass transport equation, Water Advective Particle in Cell Technique, WAPIC, was developed, verified against analytic solutions, and subsequently applied in the prediction of long term transport of a suspended sediment cloud resulting from an instantaneous dredge spoil release. Numerical results from WAPIC were verified against analytic solutions to the three dimensional incompressible mass transport equation for turbulent diffusion and advection of Gaussian dye releases in unbounded uniform and uniformly sheared uni-directional flow, and for steady-uniform plug channel flow. WAPIC was utilized to simulate an analytic solution for non-equilibrium sediment dropout from an initially vertically uniform particle distribution in one dimensional turbulent channel flow.

Spatial variation in sediment-water exchange of phosphorus in Florida Bay: AMP as a model organic compound.

PubMed

Huang, Xiao-Lan; Zhang, Jia-Zhong

2010-10-15

Dissolved organic phosphorus (DOP) has been recognized as dominant components in total dissolved phosphorus (TDP) pools in many coastal waters, and its exchange between sediment and water is an important process in biogeochemical cycle of phosphorus. Adenosine monophosphate (AMP) was employed as a model DOP compound to simulate phosphorus exchange across sediment-water interface in Florida Bay. The sorption data from 40 stations were fitted to a modified Freundlich equation and provided a detailed spatial distribution both of the sediment's zero equilibrium phosphorus concentration (EPC(0-T)) and of the distribution coefficient (K(d-T)) with respect to TDP. The K(d-T) was found to be a function of the index of phosphorus saturation (IPS), a molar ratio of the surface reactive phosphorus to the surface reactive iron oxide content in the sediment, across the entire bay. However, the EPC(0-T) was found to correlate to the contents of phosphorus in the eastern bay only. Sediment in the western bay might act as a source of the phosphorus in the exchange process due to their high EPC(0-T) and low K(d-T), whereas sediments in the eastern bay might act as a sink because of their low EPC(0-T) and high K(d-T). These results strongly support the hypothesis that both phosphorus and iron species in calcareous marine sediments play a critical role in governing the sediment-water exchange of both phosphate and DOP in the coastal and estuarine ecosystems.

The effect of activated carbon on partitioning, desorption, and biouptake of native polychlorinated biphenyls in four freshwater sediments.

PubMed

Sun, Xueli; Ghosh, Upal

2008-11-01

The present study evaluated the effect of activated carbon amendment in four freshwater sediments from the Great Lakes (North America) areas of concern with a wide range of sediment geochemical characteristics (0.83-5.1% total organic carbon) and polychlorinated biphenyl (PCB) concentrations (0.33-84.7 microg/g). The work focused on understanding the impact of activated carbon amendment on PCB aqueous partitioning, PCB desorption characteristics, and PCB biouptake in a freshwater oligochaete (Lumbriculus variegatus). The results showed that PCB aqueous equilibrium concentrations, rapid desorption fractions, and biouptake by the oligochaete were reduced after activated carbon amendment. Addition of activated carbon at a dose of 0.5-fold native organic carbon reduced PCB bioaccumulation by 42% for Niagara River sediment, 85% for Grasse River sediment, 74% for Milwaukee River sediment 1, and 70% for Milwaukee River sediment 2. A linear relationship was observed between log biota-sediment accumulation factor and the first 6-h desorption fractions for each PCB homologue for treated and untreated sediments. Water-lipid bioconcentration factors for PCB congeners were largely conserved after amendment with activated carbon. Our present results suggest that at steady state, changes in the aqueous PCB concentrations can be used to predict changes in PCB bioaccumulation in deposit-feeding organisms. Thus, use of advanced pore-water measurement techniques, such as solid-phase extraction passive samplers, may be suitable for long-term monitoring of treatment performance.

Variation laws and release characteristics of phosphorus on surface sediment of Dongting Lake.

PubMed

Zhu, Guangrui; Yang, Ying

2018-05-01

The variation trend and growth rate of P were analyzed by the concentration of the phosphorus fraction on surface sediment of Dongting Lake from 2012 to 2016, to reveal the cumulative effect of P in the actual environment. Meanwhile, the adsorption kinetics and adsorption isotherm were employed to examine the P-release possibility of sediment, which predicts the yearly released sediment phosphorus in Dongting Lake. The actual growth rate of TP (Total Phosphorus) is 53 mg·(kg·year) -1 in East Dongting Lake, 39 mg·(kg·year) -1 in South Dongting Lake, and 29 mg·(kg·year) -1 in West Dongting Lake, while the sum of the phosphorus fraction growth rates has little difference from the rate of TP in sediments of the three areas of Dongting Lake. Furthermore, the Elovich model and the Langmuir crossover-type equations are established to present the adsorption characteristic of sediment in Dongting Lake; the result shows that the sediments play a source role for phosphorus in East and South Dongting Lake from zero equilibrium phosphorus concentration (EPC 0 ) in the present situation, but an adsorption effect on TP is shown in West Dongting Lake. When the conditions of environment change are ignored, the maximum P-sorption level in sediments of East Dongting Lake will reach in 2040 according to the actual growth rate of sediments, while that in West Dongting Lake and South Dongting Lake will be in 2046 and 2061, respectively.

Water geochemistry of shallow lakes from the southeastern Pampa plain, Argentina and their implications on mollusk shells preservation.

PubMed

Cristini, Paula A; Tietze, Eleonor; De Francesco, Claudio G; Martínez, Daniel E

2017-12-15

A seasonal sampling of sediments, column and interstitial water for physico-chemical analysis were performed in littoral and open water areas in three freshwater shallow lakes (Nahuel Rucá, Las Mostazas and Los Carpinchos) from Southeastern Pampa plain, Argentina. The main objective of the present study is to evaluate how the characteristics of the depositional environments could be affecting mollusk shell preservation. These lakes are very shallow (2m) and are characterized by an extensive littoral area, dominated by the emergent macrophyte Schoenoplectus californicus, which forms a complete ring around the lake, and an open water area, in general free of vegetation. Five samples of sediments in each compartment were extracted for analysis of pH, moisture, organic matter and carbonates content using a gravity corer, while five samples from column and interstitial water were extracted for chemical analysis (pH, conductivity, major ions, minor ions and hardness). Besides, calcite and aragonite saturation indices and the redox potential were calculated for each lake. The results show the significant impact of water chemistry and redox conditions on the preservation potential of freshwater mollusk and consequently in the quality of paleonvironmental reconstruction based on the biological record from the study region. The higher concentration of organic matter and lower pH registered in the littoral area, mainly during warm months (autumn and summer), suggest worst environments for mollusk preservation, compared to open waters. Moreover, water geochemistry analysis showed aragonite and calcite indices near equilibrium or slightly subsaturated in interstitial water associated with more acid pHs, while column water is strongly oversaturated related to alkaline pHs. These results suggest that carbonate remains within sediments will be subject to dissolution affecting negatively their preservation potential. However, mollusk shells in contact with the column water are not expected to be dissolved. Copyright © 2017 Elsevier B.V. All rights reserved.

Minero-chemical composition as environmental quality assessment tool of an artificial water reservoir: the case of the "Pietra del Pertusillo" lake (Basilicata, Italia)

NASA Astrophysics Data System (ADS)

fortunato, elisabetta; mongelli, giovanni; paternoster, michele; sinisi, rosa

2016-04-01

The Pietra del Pertusillo fresh-water reservoir is an artificial lake located in the High Agri River Valley (Basilicata); its dam was completed in 1963 for producing hydroelectric energy and providing water for human use to Puglia and Basilicata southern Italian regions (approximately 2 million people). Pertusillo lake lies within a national park because of the presence of many special protected areas. This reservoir is a natural laboratory for assessing the sediment pollution from human activities, including: waste-water treatment plants, landfills, farms, treatment oil plant, plastics and other industrial activities. In addition, the Pertusillo reservoir is located in the area of the largest oil field of continental Europe. This anthropogenic pressure may thus represent an impact factor on the environmental equilibrium and consequently the knowledge and control on their quality represents a relevant environmental challenge. This study reports the preliminary results of a multidisciplinary (sedimentological, mineralogical, geochemical) PhD research focused on the analysis of the lacustrine sediments filling the Pietra del Pertusillo fresh-water reservoir. The lakes and its sediments represent the natural sink for nutrients and possible pollutants which tend to accumulate in relation to the nature and composition of the solid matrix but also the concentration and characteristics of the substances themselves. Moreover the deeper sediments, deposited under undisturbed condition, represent the "historical memory" of the ecosystem. Sub-aqueous lake sediments were investigated in May 2014, sampled using a small platform and a gravity corer (UWITEC, Austria) of 90 mm diameter which allowed to drill 19 cores up to 2 m long from the sediment/water interface. Successively cores were studied and described by using facies analysis techniques; a large number of core samples (147) were collected from the working half of each core, stored in HPDE containers, and frozen at -20°C for subsequent chemical and mineralogical analysis. Further, in order to assess the provenance effects on the composition of lake sediments, the bedrock (Meso-Cenozoic rocks and Quaternary fluvial-lacustrine deposits) and the stream sediments of the main "Pietra del Pertusillo" tributaries, close to the detrital supply entry points of Pietra del Pertusillo lake were also sampled. The mineralogical composition was obtained from randomly oriented powders by XRPD. Chemistry (major, minor, and trace elements) was performed on powdered samples by ICP-MS technique after a four acids digestion and lithium metaborate/tetraborate fusion to facilitate the destruction of possible resistate minerals. Preliminary data related to the stream sediments show that both major and minor elements (including heavy metals, barium and arsenic) have a minor variability and are close to the median values of the bedrock. The mineralogical composition of the analysed samples can explain the elemental relationships,thus excluding any anthropogenic input. The mineralogical composition of the lacustrine samples is made of quartz, carbonates, feldspars, muscovite/illite, chlorite, and interstratified clay minerals, and it is constant throughout the cores. Finally, as further step ot he research plan, we are processing 20 of all lake samples with the highest peaks of interstratified clay minerals, which likely represent the most reactive phases in our sediment-water system.

Experimental Investigation and Analysis of HEC-6 River Morphological Model

NASA Astrophysics Data System (ADS)

Tingsanchali, Tawatchai; Supharatid, Seree

1996-05-01

Only comparatively few experimental studies have been carried out to investigate the performance of the HEC-6 river morphological model. The model was developed by the Hydrologic Engineering Center of the US Army Corps of Engineers. In this study, experiments were carried out in a 20 m long concrete flume 0.6 m wide with varying rectangular cross-sections. The channel bed is paved with uniform sand of D50 = 0.9 mm and D90 = 1.2 mm within the test reach of 12 m. Two types of experiments were carried out with sediment transport, one under steady uniform flow and another under steady non-uniform flow conditions. Nine steady uniform flow experiments were carried out to compare the measured equilibrium relationship of flow and sediment transport rate with two bedload formulae, namely, Du Boys and Meyer-Peter and Muller, and with three total load formulae, namely, Toffaleti, Laursen and Yang. It was found that even though the sediment transport consists of a certain portion of bedload, the total load formulae give satisfactory results and better agreement than the two bedload formulae. Five steady non-uniform flow experiments were carried out under various conditions of varying bed profile and channel width and also with sediment addition and withdrawal. The measured transient water surface and bed profiles are compared with the computed results from the HEC-6 model. It was found that the Toffaleti and Yang total load formulae used in the HEC-6 model give the most satisfactory prediction of actual bed profiles under various conditions of non-uniform flow and sediment transport. The effects of Manning's n, variations of sediment inflow, various sediment transport formulae, sediment grain size and the model numerical parameters, i.e. distance interval x and numerical weighting factor, on the computed water surface and bed profiles were determined. It was found that the selection of the sediment transport formulae has the most significant effect on the computed results. It can be concluded that the HEC-6 model can predict satisfactorily a long-term average pattern of local scour and deposition along a channel with either a small abrupt change in geometry or gradually varying cross-sections. However, the accuracy of the model prediction is reduced in the regions where highly non-uniform flow occurs.

Morphological Modeling of a Low-Dune Barrier Headland System's Response to Hurricane Forcing Before and After a Large Scale Restoration

NASA Astrophysics Data System (ADS)

Johnson, C.; Chen, Q. J.

2017-12-01

Coastal barrier landforms serve as the first line of defense against oceanic and meteorological forcing. Widespread recognition of this function has prompted coastal managers to adopt systematic restoration programs. The state of Louisiana has, in response to its critically eroding shorelines (Byrnes et al., 2017), implemented 30 barrier island and headland restoration projects over the past three decades. The Caminada Headlands Beach and Dune Restoration Project, completed in 2016, restored 22.5 kilometers of Louisiana's coastline by elevating the cross-shore profile and placing approximately 250,000 m3 of sediment within the back- and foreshore. Interventions of this magnitude are significant perturbations to the local sediment budget and geomorphodynamic equilibrium. In Louisiana, an important question is the immediate fate of placed sediment transported during the passage of a hurricane, as the potential to ultimately retain this sediment is influenced by the location of its deposition. The direction of net sediment transport (on- or offshore) depends mainly on the elevation of the storm surge relative to the dune crest, but also on the evolution of the cross-shore water surface gradient and the spatial configuration of biogeophysical properties and hard-structures (Sherwood et al., 2014; Smallegan et al., 2016) . Prior to its restoration, the Caminada headlands were generally of low elevation with the majority of dune crest extending less than 50 cm above MHW and several active breaches. Hurricanes Gustav (2008) and Isaac (2012) made landfall directly on the headlands with inundating storm surges that resulted in observed overwash deposition (Doran et al, 2009; Guy et al, 2013), i.e. landward directed sediment transport and deposition. An open-source process-based morphological model (XBeach) is used to study hurricane induced sediment transport for both pre- and post-restoration of the Caminada headlands. Hindcast pre-restoration simulations of Gustav's and Isaac's impact are compared with forecast post-restoration simulations implemented with similar hydrodynamic forcing. Analysis of post-storm erosion/deposition highlights the importance of restoration design components such as back-barrier marsh creation and the dune crest elevation.

Biological and chemical characterization of metal bioavailability in sediments from Lake Roosevelt, Columbia River, Washington, USA

USGS Publications Warehouse

Besser, J.M.; Brumbaugh, W.G.; Ivey, C.D.; Ingersoll, C.G.; Moran, P.W.

2008-01-01

We studied the bioavailability and toxicity of copper, zinc, arsenic, cadmium, and lead in sediments from Lake Roosevelt (LR), a reservoir on the Columbia River in Washington, USA that receives inputs of metals from an upstream smelter facility. We characterized chronic sediment toxicity, metal bioaccumulation, and metal concentrations in sediment and pore water from eight study sites: one site upstream in the Columbia River, six sites in the reservoir, and a reference site in an uncontaminated tributary. Total recoverable metal concentrations in LR sediments generally decreased from upstream to downstream in the study area, but sediments from two sites in the reservoir had metal concentrations much lower than adjacent reservoir sites and similar to the reference site, apparently due to erosion of uncontaminated bank soils. Concentrations of acid-volatile sulfide in LR sediments were too low to provide strong controls on metal bioavailability, and selective sediment extractions indicated that metals in most LR sediments were primarily associated with iron and manganese oxides. Oligochaetes (Lumbriculus variegatus) accumulated greatest concentrations of copper from the river sediment, and greatest concentrations of arsenic, cadmium, and lead from reservoir sediments. Chronic toxic effects on amphipods (Hyalella azteca; reduced survival) and midge larvae (Chironomus dilutus; reduced growth) in whole-sediment exposures were generally consistent with predictions of metal toxicity based on empirical and equilibrium partitioning-based sediment quality guidelines. Elevated metal concentrations in pore waters of some LR sediments suggested that metals released from iron and manganese oxides under anoxic conditions contributed to metal bioaccumulation and toxicity. Results of both chemical and biological assays indicate that metals in sediments from both riverine and reservoir habitats of Lake Roosevelt are available to benthic invertebrates. These findings will be used as part of an ongoing ecological risk assessment to determine remedial actions for contaminated sediments in Lake Roosevelt. ?? 2007 Springer Science+Business Media, LLC.

Determination of 1-chloro-4-[2,2,2-trichloro-1-(4-chlorophenyl)ethyl]benzene and related compounds in marine pore water by automated thermal desorption-gas chromatography/mass spectrometry using disposable optical fiber

USGS Publications Warehouse

Eganhouse, Robert P.; DiFilippo, Erica L

2015-01-01

A method is described for determination of ten DDT-related compounds in marine pore water based on equilibrium solid-phase microextraction (SPME) using commercial polydimethylsiloxane-coated optical fiber with analysis by automated thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS). Thermally cleaned fiber was directly exposed to sediments and allowed to reach equilibrium under static conditions at the in situ field temperature. Following removal, fibers were rinsed, dried and cut into appropriate lengths for storage in leak-tight containers at -20°C. Analysis by TD-GC/MS under full scan (FS) and selected ion monitoring (SIM) modes was then performed. Pore-water method detection limits in FS and SIM modes were estimated at 0.05-2.4ng/L and 0.7-16pg/L, respectively. Precision of the method, including contributions from fiber handling, was less than 10%. Analysis of independently prepared solutions containing eight DDT compounds yielded concentrations that were within 6.9±5.5% and 0.1±14% of the actual concentrations in FS and SIM modes, respectively. The use of optical fiber with automated analysis allows for studies at high temporal and/or spatial resolution as well as for monitoring programs over large spatial and/or long temporal scales with adequate sample replication. This greatly enhances the flexibility of the technique and improves the ability to meet quality control objectives at significantly lower cost.

Geochemical behavior and dissolved species control in acid sand pit lakes, Sepetiba sedimentary basin, Rio de Janeiro, SE - Brazil

NASA Astrophysics Data System (ADS)

Marques, Eduardo D.; Sella, Sílvia M.; Bidone, Edison D.; Silva-Filho, Emmanoel V.

2010-12-01

This work shows the influence of pluvial waters on dissolved components and mineral equilibrium of four sand pit lakes, located in the Sepetiba sedimentary basin, SE Brazil. The sand mining activities promote sediment oxidation, lowering pH and increasing SO 4 contents. The relatively high acidity of these waters, similar to ore pit lakes environment and associated acid mine drainage, increases weathering rate, especially of silicate minerals, which produces high Al concentrations, the limiting factor for fish aquaculture. During the dry season, basic cations (Ca, Mg, K and Na), SiO 2 and Al show their higher values due to evapoconcentration and pH are buffered. In the beginning of the wet season, the dilution factor by rainwater increases SO 4 and decreases pH values. The aluminum monomeric forms (Al(OH) 2+ and Al(OH) 2+), the most toxic species for aquatic organisms, occur during the dry season, while AlSO 4+ species predominate during the wet season. Gibbsite, allophane, alunite and jurbanite are the reactive mineral phases indicated by PHREEQC modeling. During the dry season, hydroxialuminosilicate allophane is the main phase in equilibrium with the solution, while the sulphate salts alunite and jurbanite predominate in the rainy season due to the increasing of SO 4 values. Gibbsite is also in equilibrium with sand pit lakes waters, pointing out that hydrolysis reaction is a constant process in the system. Comparing to SiO 2, sulphate is the main Al retriever in the pit waters because the most samples (alunite and jurbanite) are in equilibrium with the solution in both seasons. This Al hydrochemical control allied to some precaution, like pH correction and fertilization of these waters, allows the conditions for fishpond culture. Equilibrium of the majority samples with kaolinite (Ca, Mg, Na diagrams) and primary minerals (K diagram) points to moderate weathering rate in sand pit sediments, which cannot be considered for the whole basin due to the anomalous acidification of the studied waters.

Numerical Modeling of River Fluxes Under Changing Environmental Conditions (Invited)

NASA Astrophysics Data System (ADS)

Simpson, G.

2013-12-01

High frequency climate cycles have a major impact on landscapes, but it remains uncertain if alluvial rivers can transfer the resulting sediment pulses downstream to sedimentary basins. Stratigraphic records located near the mouth of rivers exhibit cyclicity consistent with orbital forcing. However, in some cases, the sediment supply from rivers appears to have remained remarkably constant despite changes in climate, which has been interpreted to indicate that rivers dampen rapid variability. Here, we employ a physically-based numerical model to resolve this outstanding problem. Our simulations show that rivers forced with water flux cycles exhibit highly pulsed sediment outflux records, even when the period of forcing is several orders of magnitude shorter than river response times. This non-linear amplified system response characterised by positive feedback is related to the strong negative correlation between water flux and the equilibrium slope of a river. We also show that the apparent stability of sediment fluxes based on time-averaged data is an artifact of integrating highly episodic records over multiple cycles rather than a signature of diffusive floodplain processes. We conclude that marine sedimentary basins may record sediment-flux cycles resulting from discharge (and ultimately climate) variability, whereas they may be relatively insensitive to pure sediment-flux perturbations (such as for example those induced by tectonics).

Different partition of polycyclic aromatic hydrocarbon on environmental particulates in freshwater: Microplastics in comparison to natural sediment.

PubMed

Wang, Wenfeng; Wang, Jun

2018-01-01

Microplastics pollution in the aquatic ecosystems has aroused increasing concerns in recent years. Though microplastics are known to sorb organic contaminants from water, the interaction mechanisms between microplastics and organic chemicals are not yet well understood. Here we investigated the partition characteristics of phenanthrene (Phe) in three mass-produced plastic particles, including polyethylene (PE), polystyrene (PS) and polyvinylchloride (PVC)， and one natural sediment, as a comparison. The sorption kinetics of Phe onto microplastics and natural sediment were successfully described by the pseudo-second-order model (R 2 > 0.992), while the equilibrium data were best-fitted to the Langmuir isotherm (R 2 > 0.995). Compared with natural sediment, microplastics exhibited higher capacities for Phe which followed an order of PE > PS > PVC. As the aqueous concentration of pyrene (Pyr) increased, both uptakes and distribution coefficients (K d ) of Phe within the solids decreased, with natural sediment giving the largest decline. Although proportions of Phe desorbed from the contaminated microplastics were low, due to the high Phe uptake, microplastics released larger amounts of the sorbed Phe to water than the natural sediment during the desorption process. Given their minimal abundance relative to natural sediment, microplastics may play a less important role in the transport of organic pollutants in a natural aquatic environment. Copyright © 2017 Elsevier Inc. All rights reserved.

Deformation pattern during normal faulting: A sequential limit analysis

NASA Astrophysics Data System (ADS)

Yuan, X. P.; Maillot, B.; Leroy, Y. M.

2017-02-01

We model in 2-D the formation and development of half-graben faults above a low-angle normal detachment fault. The model, based on a "sequential limit analysis" accounting for mechanical equilibrium and energy dissipation, simulates the incremental deformation of a frictional, cohesive, and fluid-saturated rock wedge above the detachment. Two modes of deformation, gravitational collapse and tectonic collapse, are revealed which compare well with the results of the critical Coulomb wedge theory. We additionally show that the fault and the axial surface of the half-graben rotate as topographic subsidence increases. This progressive rotation makes some of the footwall material being sheared and entering into the hanging wall, creating a specific region called foot-to-hanging wall (FHW). The model allows introducing additional effects, such as weakening of the faults once they have slipped and sedimentation in their hanging wall. These processes are shown to control the size of the FHW region and the number of fault-bounded blocks it eventually contains. Fault weakening tends to make fault rotation more discontinuous and this results in the FHW zone containing multiple blocks of intact material separated by faults. By compensating the topographic subsidence of the half-graben, sedimentation tends to slow the fault rotation and this results in the reduction of the size of the FHW zone and of its number of fault-bounded blocks. We apply the new approach to reproduce the faults observed along a seismic line in the Southern Jeanne d'Arc Basin, Grand Banks, offshore Newfoundland. There, a single block exists in the hanging wall of the principal fault. The model explains well this situation provided that a slow sedimentation rate in the Lower Jurassic is proposed followed by an increasing rate over time as the main detachment fault was growing.

The subunit structure of horse spleen apoferritin: the molecular weight of the oligomer and its stability to dissociation by dilution (Short Communication)

PubMed Central

Crichton, Robert R.; Eason, Robert; Barclay, Allan; Bryce, Charles F. A.

1973-01-01

The oligomer molecular weight of horse spleen apoferritin was determined by sedimentation-equilibrium techniques and a value of 443000 found. It is concluded that the apoferritin molecule consists of 24 subunits. At concentrations as low as 0.01μm there is no evidence of subunit dissociation. PMID:4737327

Depth and temperature of permafrost on the Alaskan Arctic Slope; preliminary results

USGS Publications Warehouse

Lachenbruch, Arthur H.; Sass, J.H.; Lawver, L.A.; Brewer, M.C.; Moses, T.H.

1982-01-01

As permafrost is defined by its temperature, the only way to determine its depth is to monitor the return to equilibrium of temperatures in boreholes that penetrate permafrost. Such measurements are under way in 25 wells on the Alaskan Arctic Slope; 21 are in Naval Petroleum Reserve Alaska (NPRA), and 4 are in the foothills to the east. Near-equilibrium results indicate that permafrost thickness in NPRA generally ranges between 200 and 400 m (compared to 600+ m at Prudhoe Bay); there are large local variations and no conspicuous regional trends. By contrast the long-term mean temperature of the ground surface (one factor determining permafrost depth) varies systematically from north to south in a pattern modified by the regional topography. The observed variation in permafrost temperature and depth cannot result primarily from effects of surface bodies of water or regional variations in heat flow; they are consistent, however, with expectable variations in the thermal conductivity of the sediments. It remains to be determined (with conductivity measurements) whether certain sites with anomalously high local gradients have anomalously high heat flow; if they do, they might indicate upwelling of interstitial fluids in the underlying basin sediments.

Effect of gas hydrates melting on seafloor slope stability

NASA Astrophysics Data System (ADS)

Sultan, N.; Cochonat, P.; Foucher, J. P.; Mienert, J.; Haflidason, H.; Sejrup, H. P.

2003-04-01

Quantitative studies of kinetics of gas hydrate formation and dissociation is of a particular concern to the petroleum industry for an evaluation of environmental hazards in deep offshore areas. Gas hydrate dissociation can generate excess pore pressure that considerably decreases the strength of the soil. In this paper, we present a theoretical study of the thermodynamic chemical equilibrium of gas hydrate in soil, which is based on models previously reported by Handa (1989), Sloan (1998) and Henry (1999). Our study takes into account the influence of temperature, pressure, pore water chemistry, and the pore size distribution of the sediment. This model fully accounts for the latent heat effects, as done by Chaouch and Briaud (1997) and Delisle et al. (1998). It uses a new formulation based on the enthalpy form of the law of conservation of energy. The model allows for the evaluation of the excess pore pressure generated during gas hydrate dissociation using the Soave’s (1972) equation of state. Fluid flow in response to the excess pore pressure is simulated using the finite element method. In the second part of the paper, we present and discuss an application of the model through a back-analysis of the case of the giant Storegga slide on the Norwegian margin. Two of the most important changes during and since the last deglaciation (hydrostatic pressure due to the change of the sea level and the increase of the sea water temperature) were considered in the calculation. Simulation results are presented and discussed. Chaouch, A., &Briaud, J.-L., 1997. Post melting behavior of gas hydrates in soft ocean sediments, OTC-8298, in 29th offshore technology conference proceedings, v. 1, Geology, earth sciences and environmental factors: Society of Petroleum Engineers, p. 217-224. Delisle, G.; Beiersdorf, H.; Neben, S.; Steinmann, D., 1998. The geothermal field of the North Sulawesi accretionary wedge and a model on BSR migration in unstable depositional environments. in Henriet, J.-P.; Mienert, J. (Ed.): Gas hydrates: relevance to world margin stability and climate change. Geological Society Special Publication, 137. The Geological Society: London, UK, p. 267-274. Handa,Y.P., 1989. Effect of Hydrostatic Pressure and Salinity on the Stability of Gas Hydrates. J.Phys.Chem., Vol.94, p.2652-2657. Henry, P., Thomas, M.; Clennell, M.B., 1999. Formation of Natural Gas Hydrates in Marine Sediments 2. Thermodynamic Calculations of Stability Conditions in Porous Sediments,” J. Geophys. Res., 104, p. 23005. Sloan, E.D. Jr., 1998. Clathrate hydrates of natural gases. Marcel Dekker Inc., 2nd edition, New York, pp. 705. Soave G, 1972. Equilibrium

Prospective Environmental Risk Assessment for Sediment-Bound Organic Chemicals: A Proposal for Tiered Effect Assessment.

PubMed

Diepens, Noël J; Koelmans, Albert A; Baveco, Hans; van den Brink, Paul J; van den Heuvel-Greve, Martine J; Brock, Theo C M

A broadly accepted framework for prospective environmental risk assessment (ERA) of sediment-bound organic chemicals is currently lacking. Such a framework requires clear protection goals, evidence-based concepts that link exposure to effects and a transparent tiered-effect assessment. In this paper, we provide a tiered prospective sediment ERA procedure for organic chemicals in sediment, with a focus on the applicable European regulations and the underlying data requirements. Using the ecosystem services concept, we derived specific protection goals for ecosystem service providing units: microorganisms, benthic algae, sediment-rooted macrophytes, benthic invertebrates and benthic vertebrates. Triggers for sediment toxicity testing are discussed.We recommend a tiered approach (Tier 0 through Tier 3). Tier-0 is a cost-effective screening based on chronic water-exposure toxicity data for pelagic species and equilibrium partitioning. Tier-1 is based on spiked sediment laboratory toxicity tests with standard benthic test species and standardised test methods. If comparable chronic toxicity data for both standard and additional benthic test species are available, the Species Sensitivity Distribution (SSD) approach is a more viable Tier-2 option than the geometric mean approach. This paper includes criteria for accepting results of sediment-spiked single species toxicity tests in prospective ERA, and for the application of the SSD approach. We propose micro/mesocosm experiments with spiked sediment, to study colonisation success by benthic organisms, as a Tier-3 option. Ecological effect models can be used to supplement the experimental tiers. A strategy for unifying information from various tiers by experimental work and exposure-and effect modelling is provided.

[Mechanism of phosphorus adsorption and immobility by sediments in innercity heavily polluted canal].

PubMed

Li, Da-Peng; Huang, Yong; Yuan, Yan; Fan, Cheng-Xin

2011-01-01

The mechanisms of phosphorus (P) adsorption and immobility were investigated in laboratory experiments. The sediments and waters used were taken from an inner-city heavily polluted canal. Addition of KH2PO4 into the operated experimental units, with and without (i.e., static) intermittent sediment resuspension, were made similar to the external P input and carried out periodically. The results show that the amount of the accumulative P adsorption onto the sediments was up to 363.4 mg x kg(-1) under the conditions of sediment disturbance over a 39-day period, and it was evidently higher than that (213.2 mg x kg(-1)) under static conditions. Sequential fractionation indicated that most of the incorporated P was accounted for in the Fe/Al-P. There were over 61% in the case of intermittent sediment disturbance and up to 83% in the case of static conditions. Based on the bioavailability of Fe/Al-P, 40.6% of the incorporated P was accounted for in non-occluded Fe/Al-P of the sediments under intermittent sediment disturbance conditions. This value increased to 59.5% under static conditions. In addition, more than 23% of the incorporated P was accounted for in HCl-P of the sediments under intermittent sediment disturbance conditions, on the other hand, the concentration of HCl-P kept relatively constant under static conditions. After 39 d of P adsorption by the both sediments, the values of the maximum sorption capacity (S(max)) decreased,while zero equilibrium P concentration (EPC0) and P saturation P(%) increased. However, the extent of EPC0 and P% under intermittent sediment disturbance conditions was obviously lower than that under static conditions. It was hopefully suggested that intermittent sediment disturbance can not only accelerate the P adsorption but also enhance the P retention by sediments.

Flow regulation manipulates contemporary seasonal sedimentary dynamics in the reservoir fluctuation zone of the Three Gorges Reservoir, China.

PubMed

Tang, Qiang; Bao, Yuhai; He, Xiubin; Fu, Bojie; Collins, Adrian L; Zhang, Xinbao

2016-04-01

Since the launch of the Three Gorges Dam on the Yangtze River, a distinctive reservoir fluctuation zone has been created and significantly modified by regular dam operations. Sediment redistribution within this artificial landscape differs substantially from that in natural fluvial riparian zones, due to a specific hydrological regime comprising steps of water impoundment with increasing magnitudes and seasonal water level fluctuation holding a range of sediment fluxes. This study reinterpreted post-dam sedimentary dynamics in the reservoir fluctuation zone by stratigraphy determination of a 345-cm long sediment core, and related it to impact of the hydrological regime. Seasonality in absolute grain-size composition of suspended sediment was applied as a methodological basis for stratigraphic differentiation. Sedimentary laminations with relatively higher proportions of sandy fractions were ascribed to sedimentation during the dry season when proximal subsurface bank erosion dominates source contributions, while stratigraphy with a lower proportion of sandy fractions is possibly contributed by sedimentation during the wet season when distal upstream surface erosion prevails. Chronology determination revealed non-linear and high annual sedimentation rates ranging from 21.7 to 152.1cm/yr. Although channel geomorphology may primarily determine the spatial extent of sedimentation, seasonal sedimentary dynamics was predominantly governed by the frequency, magnitude, and duration of flooding. Summer inundation by natural floods with enhanced sediment loads produced from upstream basins induced higher sedimentation rates than water impoundment during the dry season when distal sediment supply was limited. We thus conclude that flow regulation manipulates contemporary seasonal sedimentary dynamics in the reservoir fluctuation zone, though little impact on total sediment retention rate was detected. Ongoing reductions in flow and sediment supply under human disturbance may have profound implications in affecting sedimentary equilibrium in the reservoir fluctuation zone. The results herein provide insights of how big dams have disrupted the sediment conveyance processes of large scale fluvial systems. Copyright © 2016 Elsevier B.V. All rights reserved.

Transferring mixtures of chemicals from sediment to a bioassay using silicone-based passive sampling and dosing.

PubMed

Mustajärvi, Lukas; Eriksson-Wiklund, Ann-Kristin; Gorokhova, Elena; Jahnke, Annika; Sobek, Anna

2017-11-15

Environmental mixtures of chemicals consist of a countless number of compounds with unknown identity and quantity. Yet, chemical regulation is mainly built around the assessment of single chemicals. Existing frameworks for assessing the toxicity of mixtures require that both the chemical composition and quantity are known. Quantitative analyses of the chemical composition of environmental mixtures are however extremely challenging and resource-demanding. Bioassays may therefore serve as a useful approach for investigating the combined toxicity of environmental mixtures of chemicals in a cost-efficient and holistic manner. In this study, an unknown environmental mixture of bioavailable semi-hydrophobic to hydrophobic chemicals was sampled from a contaminated sediment in a coastal Baltic Sea area using silicone polydimethylsiloxane (PDMS) as an equilibrium passive sampler. The chemical mixture was transferred to a PDMS-based passive dosing system, and its applicability was demonstrated using green algae Tetraselmis suecica in a cell viability assay. The proportion of dead cells increased significantly with increasing exposure level and in a dose-response manner. At an ambient concentration, the proportion of dead cells in the population was nearly doubled compared to the control; however, the difference was non-significant due to high inter-replicate variability and a low number of replicates. The validation of the test system regarding equilibrium sampling, loading efficiency into the passive dosing polymer, stability of the mixture composition, and low algal mortality in control treatments demonstrates that combining equilibrium passive sampling and passive dosing is a promising tool for investigating the toxicity of bioavailable semi-hydrophobic and hydrophobic chemicals in complex environmental mixtures.

Scaling laws for perturbations in the ocean-atmosphere system following large CO2 emissions

NASA Astrophysics Data System (ADS)

Towles, N.; Olson, P.; Gnanadesikan, A.

2015-01-01

Scaling relationships are derived for the perturbations to atmosphere and ocean variables from large transient CO2 emissions. Using the carbon cycle model LOSCAR (Zeebe et al., 2009; Zeebe, 2012b) we calculate perturbations to atmosphere temperature and total carbon, ocean temperature, total ocean carbon, pH, and alkalinity, marine sediment carbon, plus carbon-13 isotope anomalies in the ocean and atmosphere resulting from idealized CO2 emission events. The peak perturbations in the atmosphere and ocean variables are then fit to power law functions of the form γDαEbeta, where D is the event duration, E is its total carbon emission, and γ is a coefficient. Good power law fits are obtained for most system variables for E up to 50 000 PgC and D up to 100 kyr. However, these power laws deviate substantially from predictions based on simplified equilibrium considerations. For example, although all of the peak perturbations increase with emission rate E/D, we find no evidence of emission rate-only scaling α + β =0, a prediction of the long-term equilibrium between CO2 input by volcanism and CO2 removal by silicate weathering. Instead, our scaling yields α + β ≃ 1 for total ocean and atmosphere carbon and 0< α + β < 1 for most of the other system variables. The deviations in these scaling laws from equilibrium predictions are mainly due to the multitude and diversity of time scales that govern the exchange of carbon between marine sediments, the ocean, and the atmosphere.

Morphological resilience to flow fluctuations of fine sediment deposits in bank lateral cavities

NASA Astrophysics Data System (ADS)

Juez, C.; Thalmann, M.; Schleiss, A. J.; Franca, M. J.

2018-05-01

Lateral cavities are built in the banks of rivers for several purposes: to create harbors, to capture sediment, to keep a central navigable channel (i.e., Casiers de Girardon in the Rhone river) or to promote the formation of aquatic habitats if a limited amount of sediment is captured, providing hydraulic and morphologic diversity (i.e., the case of Japanese Wandos). This work is focused on this latter purpose: promotion of hydraulic and morphologic diversity. In these scenarios, an increase in the flow discharge in the main channel may, however, re-mobilize the deposit of sediment inside these lateral embayments and cause a sudden increase of the sediment concentration and turbidity in the main channel. It is thus of interest to characterize the resistance and resilience of these sedimentary deposits when the main channel is subjected to high flow or flushing events. Laboratory tests were carried out for five different normalized geometries of the cavities installed in the banks of an open channel and for five hydrographs with different levels of unsteadiness. Water depth, sediment deposit mass, sediment concentration and area covered by the settled sediments were recorded throughout each experiment. Although sediment deposits established at equilibrium before the flushing events are different depending on the geometry of the cavities, generally, they are recovered after being flushed by the high flow events. It is shown that the resistance and resilience of the sediment deposits are strongly dependent on the flow field and the mass exchange between the main channel and the cavities. This mass exchange is governed by the geometry of the cavities and the magnitude of the hydrographs applied.

Slip slidin' away: A post-glacial environmental history of the Waipaoa River basin

NASA Astrophysics Data System (ADS)

Gomez, Basil; Rosser, Brenda J.

2018-04-01

The dramatic changes that occurred to the post-glacial landscape in the headwaters of the Waipaoa River basin are a consequence of perturbations about the equilibrium that exists between the rate of tectonic uplift and fluvial incision. At times when the amount of coarse sediment delivered to channels exceeds the capacity of streams to remove it, the channel bed rises at the rate of tectonic uplift. Once bedload overcapacity is replaced by undercapacity and the alluvial cover is depleted, streams reestablish contact with bedrock and recuperate the time lost to fluvial incision. The first major perturbation occurred during the final phase of the last glaciation (ca. 33-17.5 cal. ka), when aggradation was driven by a climate-forced variation in the relative supplies of sediment and water. We suggest that the subsequent transformation of channels in the headwaters of the Waipaoa River basin, from alluvial to bedrock, occurred as the atmospheric and oceanic circulation converged on their contemporary patterns ca. 12 cal. ka. A second major perturbation that continues to the present began ca. 1910-1912 CE, when a massive increase in sediment load was accompanied by a modest increase in water discharge after the native vegetation cover in the headwaters was replaced by pasture. The processes of terrace creation and incision are inherently unsteady, and in five interim cases incision was arrested by a transient increase in the thickness of the alluvial cover that was a response to climatic forcing. Events that disrupted the native vegetation cover in the headwaters also modulated patterns of sediment dispersal and accumulation in other parts of the fluvial system and caused rapid, storm-driven infilling of the Poverty Bay Flats. Tectonic subsidence dictates the course of the Waipaoa River across Poverty Bay Flats which, because the modern rate of floodplain construction by vertical accretion is rapid relative to the amount of destruction by lateral channel migration, has remained virtually unchanged for the past 100 years. During this time the channel assumed a narrower, deeper form that is in equilibrium with the contemporary supply of sediment and hydraulic regime.

Ecological risk assessment of boreal sediments affected by metal mining: Metal geochemistry, seasonality, and comparison of several risk assessment methods.

PubMed

Väänänen, Kristiina; Kauppila, Tommi; Mäkinen, Jari; Leppänen, Matti T; Lyytikäinen, Merja; Akkanen, Jarkko

2016-10-01

The mining industry is a common source of environmental metal emissions, which cause long-lasting effects in aquatic ecosystems. Metal risk assessment is challenging due to variations in metal distribution, speciation, and bioavailability. Therefore, seasonal effects must be better understood, especially in boreal regions in which seasonal changes are large. We sampled 4 Finnish lakes and sediments affected by mining for metals and geochemical characteristics in autumn and late winter, to evaluate seasonal changes in metal behavior, the importance of seasonality in risk assessment, and the sensitivity and suitability of different risk assessment methods. We compared metal concentrations in sediment, overlying water, and porewater against environmental quality guidelines (EQGs). We also evaluated the toxicity of metal mixtures using simultaneously extracted metals and an acid volatile sulfides (SEM-AVS) approach together with water quality criteria (US Environmental Protection Agency equilibrium partitioning benchmarks). Finally, site-specific risks for 3 metals (Cu, Ni, Zn) were assessed using 2 biotic ligand models (BLMs). The metal concentrations in the impacted lakes were elevated. During winter stratification, the hypolimnetic O2 saturation levels were low (<6%) and the pH was acidic (3.5-6.5); however, abundant O2 (>89%) and neutral pH (6.1-7.5) were found after the autumnal water overturn. Guidelines were the most conservative benchmark for showing an increased risk of toxicity in the all of the lakes. The situation remained stable between seasons. On the other hand, SEM-AVS, equilibrium partition sediment benchmarks (ESBs), and BLMs provided a clearer distinction between lakes and revealed a seasonal variation in risk among some of the lakes, which evidenced a higher risk during late winter. If a sediment risk assessment is based on the situation in the autumn, the overall risk may be underestimated. It is advisable to carry out sampling and risk assessment during periods in which metals are assumed to be the most environmentally harmful. Integr Environ Assess Manag 2016;12:759-771. © 2015 SETAC. © 2015 SETAC.

Morrowan sedimentation in the Orogrande basin, west Texas and south-central New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Connolly, W.M.; Stanton, R.J. Jr.

1986-03-01

Morrowan strata in the Hueco and Franklin Mountains reflect deposition within a shallow, gradually subsiding, carbonate shelf lagoon. Postulated environments fluctuated between open shelf lagoon with localized shoaling, restricted inner shelf lagoon, and peritidal settings. Variations in depth were slight, probably not exceeding several tens of meters within the photic zone. The La Tuna Formation (Franklin Mountains) was deposited near the axis (center) of the Orogrande basin; the lower division of the Magdalena limestone (Hueco Mountains), 30 mi east, was deposited 20-30 mi west of the paleoshoreline. Physiographically, the Orogrande sea was a small gulf, offering a certain degree ofmore » protection from the Morrowan seaway to the south. Sedimentologically, it was a wide expanse of predominantly quiet-water carbonate sedimentation with subordinate argillaceous influex and coarser peripheral clastics. The Orogrande basin, a stratigraphic feature, corresponds to a blanket deposit of shallow epeiric carbonates. Climatic and orographic effects are invoked to explain the contrasting style of clastic sedimentation in the Delaware and orogrande basins, east and west of the Pedernal uplift. Analysis of Morrowan carbonates reveals no evidence of cyclicity, major transgressions or regressions, or local tectonic activity. Deposition was stable and in equilibrium with a gradually subsiding shallow basin. Based on lithologic, faunal, biostratigraphic, and paleogeographic criteria, the lower division is both laterally and temporally equivalent with the La Tuna Formation. Accordingly, the latter term is advocated in favor of the former, which lacks both priority and formal status.« less

Development and application of freshwater sediment-toxicity benchmarks for currently used pesticides

USGS Publications Warehouse

Nowell, Lisa H.; Norman, Julia E.; Ingersoll, Christopher G.; Moran, Patrick W.

2016-01-01

Sediment-toxicity benchmarks are needed to interpret the biological significance of currently used pesticides detected in whole sediments. Two types of freshwater sediment benchmarks for pesticides were developed using spiked-sediment bioassay (SSB) data from the literature. These benchmarks can be used to interpret sediment-toxicity data or to assess the potential toxicity of pesticides in whole sediment. The Likely Effect Benchmark (LEB) defines a pesticide concentration in whole sediment above which there is a high probability of adverse effects on benthic invertebrates, and the Threshold Effect Benchmark (TEB) defines a concentration below which adverse effects are unlikely. For compounds without available SSBs, benchmarks were estimated using equilibrium partitioning (EqP). When a sediment sample contains a pesticide mixture, benchmark quotients can be summed for all detected pesticides to produce an indicator of potential toxicity for that mixture. Benchmarks were developed for 48 pesticide compounds using SSB data and 81 compounds using the EqP approach. In an example application, data for pesticides measured in sediment from 197 streams across the United States were evaluated using these benchmarks, and compared to measured toxicity from whole-sediment toxicity tests conducted with the amphipod Hyalella azteca (28-d exposures) and the midge Chironomus dilutus (10-d exposures). Amphipod survival, weight, and biomass were significantly and inversely related to summed benchmark quotients, whereas midge survival, weight, and biomass showed no relationship to benchmarks. Samples with LEB exceedances were rare (n = 3), but all were toxic to amphipods (i.e., significantly different from control). Significant toxicity to amphipods was observed for 72% of samples exceeding one or more TEBs, compared to 18% of samples below all TEBs. Factors affecting toxicity below TEBs may include the presence of contaminants other than pesticides, physical/chemical characteristics of sediment, and uncertainty in TEB values. Additional evaluations of benchmarks in relation to sediment chemistry and toxicity are ongoing.

Field application of activated carbon amendment for in-situ stabilization of polychlorinated biphenyls in marine sediment.

PubMed

Cho, Yeo-Myoung; Ghosh, Upal; Kennedy, Alan J; Grossman, Adam; Ray, Gary; Tomaszewski, Jeanne E; Smithenry, Dennis W; Bridges, Todd S; Luthy, Richard G

2009-05-15

We report results on the first field-scale application of activated carbon (AC) amendment to contaminated sediment for in-situ stabilization of polychlorinated biphenyls (PCBs). The test was performed on a tidal mud flat at South Basin, adjacent to the former Hunters Point Naval Shipyard, San Francisco Bay, CA. The major goals of the field study were to (1) assess scale up of the AC mixing technology using two available, large-scale devices, (2) validate the effectiveness of the AC amendment at the field scale, and (3) identify possible adverse effects of the remediation technology. Also, the test allowed comparison among monitoring tools, evaluation of longer-term effectiveness of AC amendment, and identification of field-related factors that confound the performance of in-situ biological assessments. Following background pretreatment measurements, we successfully incorporated AC into sediment to a nominal 30 cm depth during a single mixing event, as confirmed by total organic carbon and black carbon contents in the designated test plots. The measured AC dose averaged 2.0-3.2 wt% and varied depending on sampling locations and mixing equipment. AC amendment did not impact sediment resuspension or PCB release into the water column over the treatment plots, nor adversely impactthe existing macro benthic community composition, richness, or diversity. The PCB bioaccumulation in marine clams was reduced when exposed to sediment treated with 2% AC in comparison to the control plot Field-deployed semi permeable membrane devices and polyethylene devices showed about 50% reduction in PCB uptake in AC-treated sediment and similar reduction in estimated pore-water PCB concentration. This reduction was evident even after 13-month post-treatment with then 7 months of continuous exposure, indicating AC treatment efficacy was retained for an extended period. Aqueous equilibrium PCB concentrations and PCB desorption showed an AC-dose response. Field-exposed AC after 18 months retained a strong stabilization capability to reduce aqueous equilibrium PCB concentrations by about 90%, which also supports the long-term effectiveness of AC in the field. Additional mixing during or after AC deployment, increasing AC dose, reducing AC-particle size, and sequential deployment of AC dose will likely improve AC-sediment contact and overall effectiveness. The reductions in PCB availability observed with slow mass transfer under field conditions calls for predictive models to assess the long-term trends in pore-water PCB concentrations and the benefits of alternative in-situ AC application and mixing strategies.

Phenomenological Partial Specific Volumes for G-Quadruplex DNAs

PubMed Central

Hellman, Lance M.; Rodgers, David W.; Fried, Michael G.

2009-01-01

Accurate partial specific volume (ν̄) values are required for sedimentation velocity and sedimentation equilibrium analyses. For nucleic acids, the estimation of these values is complicated by the fact that ν̄ depends on base composition, secondary structure, solvation and the concentrations and identities of ions in the surrounding buffer. Here we describe sedimentation equilibrium measurements of the apparent isopotential partial specific volume φ′ for two G-quadruplex DNAs and a single-stranded DNA of similar molecular weight and base composition. The G-quadruplex DNAs are a 22 nucleotide fragment of the human telomere consensus sequence and a 27 nucleotide fragment from the human c-myc promoter. The single-stranded DNA is 26 nucleotides long and is designed to have low propensity to form secondary structures. Parallel measurements were made in buffers containing NaCl and in buffers containing KCl, spanning the range 0.09M ≤ [salt] ≤ 2.3M. Limiting values of φ′, extrapolated to [salt] = 0M, were: 22-mer (NaCl-form), 0.525 ± 0.004 mL/g; 22-mer (KCl-form), 0.531 ± 0.006 mL/g; 27-mer (NaCl-form), 0.548 ± 0.005 mL/g; 27-mer (KCl-form), 0.557 ± 0.006 mL/g; 26-mer (NaCl-form), 0.555 ± 0.004 mL/g; 26-mer (KCl-form), 0.564 ± 0.006 mL/g. Small changes in φ′ with [salt] suggest that large changes in counterion association or hydration are unlikely to take place over these concentration ranges. PMID:19238377

Estimating aquatic toxicity as determined through laboratory tests of great lakes sediments containing complex mixtures of environmental contaminants

USGS Publications Warehouse

1996-01-01

We developed and evaluated a total toxic units modeling approach for predicting mean toxicity as measured in laboratory tests for Great Lakes sediments containing complex mixtures of environmental contaminants (e.g., polychlorinated biphenyls, polycyclic aromatic hydrocarbons, pesticides, chlorinated dioxins, and metals). The approach incorporates equilibrium partitioning and organic carbon control of bioavailability for organic contaminants and acid volatile sulfide (AVS) control for metals, and includes toxic equivalency for planar organic chemicals. A toxic unit is defined as the ratio of the estimated pore-water concentration of a contaminant to the chronic toxicity of that contaminant, as estimated by U.S. Environmental Protection Agency Ambient Water Quality Criteria (AWQC). The toxic unit models we developed assume complete additivity of contaminant effects, are completely mechanistic in form, and were evaluated without any a posteriori modification of either the models or the data from which the models were developed and against which they were tested. A linear relationship between total toxic units, which included toxicity attributable to both iron and un-ionized ammonia, accounted for about 88% of observed variability in mean toxicity; a quadratic relationship accounted for almost 94%. Exclusion of either bioavailability components (i.e., equilibrium partitioning control of organic contaminants and AVS control of metals) or iron from the model substantially decreased its ability to predict mean toxicity. A model based solely on un-ionized ammonia accounted for about 47% of the variability in mean toxicity. We found the toxic unit approach to be a viable method for assessing and ranking the relative potential toxicity of contaminated sediments.

UXO Burial Prediction Fidelity: A Summary

DTIC Science & Technology

2017-07-01

should not be construed as representing the official position of either the Department of Defense or the sponsoring organization. For More Information ...equilibrium. Any complete picture of munition evolution in sediment would need to account for these effects. More relevant to the present topic: these...of adds uncertainty to predictions of munition fate, and assessments of risk probabilities would need to account for the statistical distribution of

Flow characteristics and longitudinal sorting patterns associated with stable alluvial-bedrock and bedrock-alluvial transitions

NASA Astrophysics Data System (ADS)

Jafarinik, S.; Viparelli, E.

2017-12-01

Recent research recognized the existence of bedrock channels in low-slope rivers, but little is known about the morphodynamics of bedrock-alluvial and alluvial-bedrock transitions in these systems. Bedrock-alluvial and alluvial-bedrock transitions are fluvial features separating bedrock and alluvial reaches. In the bedrock reach the river bed is partially covered with alluvium. An increase in sediment supply to an alluvial reach results in channel bed aggradation. An increase in sediment supply to a bedrock reach, on the other hand, results in a reduction of the exposed bedrock. Mathematical modeling of the alluvial morphodynamics of bedrock reaches reveals that these transitions can characterize transient or equilibrium conditions. Model results show that the magnitude of the alluvial equilibrium slope and the depth of the bedrock surface relative to the downstream water surface base level have a primary control on the equilibrium conditions. Further, numerical results show that when a stable bedrock-alluvial transition forms, the bed material transport capacity in bedrock reach decreases in the flow direction. On the contrary, when a stable alluvial-bedrock transition forms the bed material transport capacity in the bedrock reach increases in the flow direction. These spatial changes in bed material transport capacity are associated with spatial changes in alluvial cover and flow hydrodynamics. Here we present a one-dimensional formulation of alluvial morphodynamics that accounts for the non-uniformity of the bed material and for the spatial change in flow resistances associated with the spatial and temporal changes in flow hydrodynamics of the bedrock reaches. This change in flow resistances can be associated with 1) changes in skin friction due to longitudinal changes in the grain size distribution of the bed surface, and/or 2) changes in bedform geometry associated with the interaction between the alluvial cover and the underlying bedrock. The model has been validated against laboratory experiments with stable alluvial-bedrock transitions and is applied to describe the spatial changes in flow characteristics and sediment sorting patterns upstream of a stable bedrock-alluvial transition.

Numerical modelling of bedload sediment transport

NASA Astrophysics Data System (ADS)

Langlois, Vincent J.

2010-05-01

We present a numerical study of sediment transport in the bedload regime. Classical bedload transport laws only describe the variation of the vertically integrated flux of grains as a function of the Shields number. However, these relations are only valid if the moving layer of the bed is at equilibrium with the external flow. Besides, they do not contain enough information for many geomorphological applications. For instance, understanding inertial effects in the moving bed requires models that are able to account for the variability of hydrodynamical conditions, and the discrete nature of the sediment material. We developped a numerical modelling of the behaviour of a three-dimensional bed of grains sheared by a unidirectional fluid flow. These simulations are based on a combination of discrete and continuum approaches: sediment particles are modelled by hard spheres interacting through simple contact forces, whereas the fluid flow is described by a 'mean field' model. Both the drag exerted on grains by the fluid and the retroactive effect of the presence of grains on the flow are accounted for, allowing the system to converge to its equilibrium state (no assumption is made on the fluid velocity profile inside the layer of moving grains). Above the motion threshold, the variation of the flux of grains in the steady state is found to vary like the cube of the Shields number (as predicted by Bagnold). Besides, our simulations allow us to obtain new insights into the detailed mechanisms of bedload transport, by giving access to non-integral quantities, such as the trajectories of each individual grains, the detailed velocity and packing fraction profiles inside the granular bed, etc. It is therefore possible to investigate some effects that are not accounted for in usual continuum models, such as the polydispersity of grains, the ageing of the bed, the response to a variation of the flowrate, etc.

Landscape disequilibrium on 1000-10,000 year scales Marsyandi River, Nepal, central Himalaya

NASA Astrophysics Data System (ADS)

Pratt-Sitaula, Beth; Burbank, Douglas W.; Heimsath, Arjun; Ojha, Tank

2004-03-01

In an actively deforming orogen, maintenance of a topographic steady state requires that hillslope erosion, river incision, and rock uplift rates are balanced over timescales of 10 5-10 7 years. Over shorter times, <10 5 years, hillslope erosion and bedrock river incision rates fluctuate with changes in climate. On 10 4-year timescales, the Marsyandi River in the central Nepal Himalaya has oscillated between bedrock incision and valley alluviation in response to changes in monsoon intensity and sediment flux. Stratigraphy and 14C ages of fill terrace deposits reveal a major alluviation, coincident with a monsoonal maximum, ca. 50-35 ky BP. Cosmogenic 10Be and 26Al exposure ages define an alluviation and reincision event ca. 9-6 ky BP, also at a time of strong South Asian monsoons. The terrace deposits that line the Lesser Himalayan channel are largely composed of debris flows which originate in the Greater Himalayan rocks up to 40 km away. The terrace sequences contain many cubic kilometers of sediment, but probably represent only 2-8% of the sediments which flushed through the Marsyandi during the accumulation period. At ˜10 4-year timescales, maximum bedrock incision rates are ˜7 mm/year in the Greater Himalaya and ˜1.5 mm/year in the Lesser Himalayan Mahabarat Range. We propose a model in which river channel erosion is temporally out-of-phase with hillslope erosion. Increased monsoonal precipitation causes an increase in hillslope-derived sediment that overwhelms the transport capacity of the river. The resulting aggradation protects the bedrock channel from erosion, allowing the river gradient to steepen as rock uplift continues. When the alluvium is later removed and the bedrock channel re-exposed, bedrock incision rates probably accelerate beyond the long-term mean as the river gradient adjusts downward toward a more "equilibrium" profile. Efforts to document dynamic equilibrium in active orogens require quantification of rates over time intervals significantly exceeding the scale of these millennial fluctuations in rate.

Modeling Elevation Equilibrium and Human Adaptation in the Ganges-Brahmaputra Delta

NASA Astrophysics Data System (ADS)

Tasich, C. M.; Gilligan, J. M.; Goodbred, S. L., Jr.; Hale, R. P.; Wilson, C.

2017-12-01

The communities living in the low-lying tidal reaches of the Ganges-Brahmaputra delta rely on a system of polders (earthen-embanked landscapes) to prevent against tidal inundation and storm surge. These communities initially thrived as a result of poldering due to the increase in the total arable land, which presently helps sustain a population of 20 million people. However, poldering led to the unintended consequence of reducing water and sediment exchange between the polders and the tidal network, which has resulted in a significant elevation offset of 1-1.5 m relative to that of the natural landscape. This offset causes significant waterlogging which is problematic for rice cultivation. Engineering solutions, such as Tidal River Management (TRM), have been proposed to help alleviate this offset. Previous work suggests with proper implementation of TRM, polder elevations can successfully be reequilibrated to that of the natural elevation on timescales of 5-20 years. However, TRM implementation requires community commitment to allowing controlled tidal inundation. Here, we expand previous numerical simulations of sediment accumulation through field-based constraints of grain size, compaction, and sea level rise. We then model human decision-making for implementation of TRM practices using an agent-based model. Our sediment model employs a mass balance of sediment accumulation as a function of tidal height, suspended sediment concentration, settling velocity, and dry bulk density. We couple this sediment model to an agent-based model of human decision making. We model a hypothetical 500 x 300 m polder community with the lowest elevations in the middle and the highest elevations adjacent to the tidal channels. Landowners assess their risk and profit for future scenarios with and without TRM. All landowner decisions are aggregated and then a community decision is made on whether to implement TRM. Initial findings suggest that basic voting (majority rule) results in significant inequality within a polder community. Landowners closest to the tidal channel vote to close the embankment breach before the interior landowners have fully realized the benefit of TRM. Further analysis will elucidate better strategies for implementing TRM successfully at a community level.

Large sized non-uniform sediment transport at high capacity on steep slopes

NASA Astrophysics Data System (ADS)

Fu, X.; Zhang, L.; Duan, J. G.

2015-12-01

Transport of large-sized particles such as cobbles in steep streams still remains poorly understood in spite of its importance in mountain stream morphdynamics. Here we explored the law of cobble transport and the effect of cobble existence on gravel bed material transport, using flume experiments with a steep slope (4.9%) and water and sediment constantly supplying. The experiments were conducted in an 8 m long and 0.6 m wide circulating flume with the maximal size up to 90 mm and cobble concentrations in the sediment bed ranging from 22 percent to 6 percent. The sediment transport rate is on the order of 1000 g/m/s, which could be taken as high rate transport compared with existing researches. Bed load transport rate and flow variables were measured after the flume reached an equilibrium state. Bed surface topography was also measured by applying Kinect range camera before and after each run in order to analyze the fractal characteristics of the bed surface under different flow conditions. Critical shear stress of each size friction was estimated from the reference transport method (RTM) and a new hiding function was recommended. Preliminary results show that the bed was nearly in an equal mobility transport regime. We then plot dimensionless fractional transport rate versus dimensionless shear stress and assess the existing bed load transport formulas of non-uniform sediments for their applicability at high sediment transport capacity. This study contributes to the comprehension of high rate sediment transport on steep slopes.

Sediment Transport of Fine Sand to Fine Gravel on Transverse Bed Slopes in Rotating Annular Flume Experiments

NASA Astrophysics Data System (ADS)

Baar, Anne W.; de Smit, Jaco; Uijttewaal, Wim S. J.; Kleinhans, Maarten G.

2018-01-01

Large-scale morphology, in particular meander bend depth, bar dimensions, and bifurcation dynamics, are greatly affected by the deflection of sediment transport on transverse bed slopes due to gravity and by secondary flows. Overestimating the transverse bed slope effect in morphodynamic models leads to flattening of the morphology, while underestimating leads to unrealistically steep bars and banks and a higher braiding index downstream. However, existing transverse bed slope predictors are based on a small set of experiments with a minor range of flow conditions and sediment sizes, and in practice models are calibrated on measured morphology. The objective of this research is to experimentally quantify the transverse bed slope effect for a large range of near-bed flow conditions with varying secondary flow intensity, sediment sizes (0.17-4 mm), sediment transport mode, and bed state to test existing predictors. We conducted over 200 experiments in a rotating annular flume with counterrotating floor, which allows control of the secondary flow intensity separate from the streamwise flow velocity. Flow velocity vectors were determined with a calibrated analytical model accounting for rough bed conditions. We isolated separate effects of all important parameters on the transverse slope. Resulting equilibrium transverse slopes show a clear trend with varying sediment mobilities and secondary flow intensities that deviate from known predictors depending on Shields number, and strongly depend on bed state and sediment transport mode. Fitted functions are provided for application in morphodynamic modeling.

Longitudinal variation in lateral trapping of fine sediment in tidal estuaries: observations and a 3D exploratory model

NASA Astrophysics Data System (ADS)

Chen, Wei; de Swart, Huib E.

2018-03-01

This study investigates the longitudinal variation of lateral entrapment of suspended sediment, as is observed in some tidal estuaries. In particular, field data from the Yangtze Estuary are analysed, which reveal that in one cross-section, two maxima of suspended sediment concentration (SSC) occur close to the south and north sides, while in a cross-section 2 km down-estuary, only one SSC maximum on the south side is present. This pattern is found during both spring tide and neap tide, which are characterised by different intensities of turbulence. To understand longitudinal variation in lateral trapping of sediment, results of a new three-dimensional exploratory model are analysed. The hydrodynamic part contains residual flow due to fresh water input, density gradients and Coriolis force and due to channel curvature-induced leakage. Moreover, the model includes a spatially varying eddy viscosity that accounts for variation of intensity of turbulence over the spring-neap cycle. By imposing morphodynamic equilibrium, the two-dimensional distribution of sediment in the domain is obtained analytically by a novel procedure. Results reveal that the occurrence of the SSC maxima near the south side of both cross-sections is due to sediment entrapment by lateral density gradients, while the second SSC maximum near the north side of the first cross-section is by sediment transport due to curvature-induced leakage. Coriolis deflection of longitudinal flow also contributes the trapping of sediment near the north side. This mechanism is important in the upper estuary, where the flow due to lateral density gradients is weak.

Toxicity of smelter slag-contaminated sediments from Upper Lake Roosevelt and associated metals to early life stage White Sturgeon (Acipenser transmontanus Richardson, 1836)

USGS Publications Warehouse

Little, E.E.; Calfee, R.D.; Linder, G.

2014-01-01

The toxicity of five smelter slag-contaminated sediments from the upper Columbia River and metals associated with those slags (cadmium, copper, zinc) was evaluated in 96-h exposures of White Sturgeon (Acipenser transmontanus Richardson, 1836) at 8 and 30 days post-hatch. Leachates prepared from slag-contaminated sediments were evaluated for toxicity. Leachates yielded a maximum aqueous copper concentration of 11.8 μg L−1 observed in sediment collected at Dead Man's Eddy (DME), the sampling site nearest the smelter. All leachates were nonlethal to sturgeon that were 8 day post-hatch (dph), but leachates from three of the five sediments were toxic to fish that were 30 dph, suggesting that the latter life stage is highly vulnerable to metals exposure. Fish maintained consistent and prolonged contact with sediments and did not avoid contaminated sediments when provided a choice between contaminated and uncontaminated sediments. White Sturgeon also failed to avoid aqueous copper (1.5–20 μg L−1). In water-only 96-h exposures of 35 dph sturgeon with the three metals, similar toxicity was observed during exposure to water spiked with copper alone and in combination with cadmium and zinc. Cadmium ranging from 3.2 to 41 μg L−1 or zinc ranging from 21 to 275 μg L−1 was not lethal, but induced adverse behavioral changes including a loss of equilibrium. These results suggest that metals associated with smelter slags may pose an increased exposure risk to early life stage sturgeon if fish occupy areas contaminated by slags.

Phosphorus sorption and buffering mechanisms in suspended sediments from the Yangtze Estuary and Hangzhou Bay, China

NASA Astrophysics Data System (ADS)

Li, M.; Whelan, M. J.; Wang, G.; White, S. M.

2012-12-01

The adsorption isotherm and the mechanism of the buffering effect are important controls on phosphorus behaviors in estuaries and are important for estimating phosphate concentrations in aquatic environments. In this paper, we derive phosphate adsorption isotherms in order to investigate sediment adsorption and buffering capacity for phosphorus discharged from sewage outfalls in the Yangtze Estuary and Hangzhou Bay near Shanghai, China. Experiments were also carried out at different temperatures in order to explore the buffering effects for phosphate. The results show that P sorption in sediments with low fine particle fractions was best described using exponential equations. Some P interactions between water and sediment may be caused by the precipitation of CaHPO4 from Ca2+ and HPO42- when the phosphate concentration in the liquid phase is high. Results from the buffering experiments suggest that the Zero Equilibrium Phosphate Concentrations (EPC0) vary from 0.014 mg l-1 to 0.061 mg l-1, which are consistent with measured phosphate concentrations in water samples collected at the same time as sediment sampling. Values of EPC0 and linear sorption coefficients (K) in sediments with high fine particle and organic matter contents are relatively high, which implies that they have high buffering capacity. Both EPC0 and K increase with increasing temperature, indicating a higher P buffering capacity at high temperatures.

Phosphorus sorption and buffering mechanisms in suspended sediments from the Yangtze Estuary and Hangzhou Bay, China

NASA Astrophysics Data System (ADS)

Li, M.; Whelan, M. J.; Wang, G. Q.; White, S. M.

2013-05-01

The adsorption isotherm and the mechanism of the buffering effect are important controls on phosphorus (P) behaviors in estuaries and are important for estimating phosphate concentrations in aquatic environments. In this paper, we derive phosphate adsorption isotherms in order to investigate sediment adsorption and buffering capacity for phosphorus discharged from sewage outfalls in the Yangtze Estuary and Hangzhou Bay near Shanghai, China. Experiments were also carried out at different temperatures in order to explore the buffering effects for phosphate. The results show that P sorption in sediments with low fine particle fractions was best described using exponential equations. Some P interactions between water and sediment may be caused by the precipitation of CaHPO4 from Ca2+ and HPO42- when the phosphate concentration in the liquid phase is high. Results from the buffering experiments suggest that the Zero Equilibrium Phosphate Concentrations (EPC0) vary from 0.014 mg L-1 to 0.061 mg L-1, which are consistent with measured phosphate concentrations in water samples collected at the same time as sediment sampling. Values of EPC0 and linear sorption coefficients (K) in sediments with high fine particle and organic matter contents are relatively high, which implies that they have high buffering capacity. Both EPC0 and K increase with increasing temperature, indicating a higher P buffering capacity at high temperatures.

Effect of temperature and salinity on phosphate sorption on marine sediments.

PubMed

Zhang, Jia-Zhong; Huang, Xiao-Lan

2011-08-15

Our previous studies on the phosphate sorption on sediments in Florida Bay at 25 °C in salinity 36 seawater revealed that the sorption capacity varies considerably within the bay but can be attributed to the content of sedimentary P and Fe. It is known that both temperature and salinity influence the sorption process and their natural variations are the greatest in estuaries. To provide useful sorption parameters for modeling phosphate cycle in Florida Bay, a systematic study was carried out to quantify the effects of salinity and temperature on phosphate sorption on sediments. For a given sample, the zero equilibrium phosphate concentration and the distribution coefficient were measured over a range of salinity (2-72) and temperature (15-35 °C) conditions. Such a suite of experiments with combinations of different temperature and salinity were performed for 14 selected stations that cover a range of sediment characteristics and geographic locations of the bay. Phosphate sorption was found to increase with increasing temperature or decreasing salinity and their effects depended upon sediment's exchangeable P content. This study provided the first estimate of the phosphate sorption parameters as a function of salinity and temperature in marine sediments. Incorporation of these parameters in water quality models will enable them to predict the effect of increasing freshwater input, as proposed by the Comprehensive Everglades Restoration Plan, on the seasonal cycle of phosphate in Florida Bay.

Sorption of selected pharmaceuticals and pesticides on different river sediments.

PubMed

Radović, Tanja T; Grujić, Svetlana D; Kovačević, Srđan R; Laušević, Mila D; Dimkić, Milan A

2016-12-01

In the present work, the sorption ability of 17 pharmaceutical compounds, two metabolites, and 15 pesticides (34 target compounds in total) onto four different river sediments was investigated separately. Selected compounds present the most frequently prescribed pharmaceuticals in human and animal medicine and the most frequently used pesticides in agriculture. Their presence into the surface, ground, and waste waters was confirmed into the numerous papers in literature, as well as their presence into the river sediments (for some of them). However, investigations of their sorption onto the river sediments, as major natural protection from potential pollution of ground water by them is missing. Sorption in this study was investigated onto river sediments taken from rivers in the Republic of Serbia, where only less than 10 % of total generated waste water passes through mainly basic treatment processes. Experiments were based on batch equilibrium procedures and obtained solutions were analyzed by previously developed and validated sensitive high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) analytical methods. All results were modeled by Freundlich isotherms. Obtained results have shown that Kf coefficient values are in correlation with organic carbon content. Kd sorption coefficient values were relatively low and ranged in wide ranges for almost all compounds and sediments. That implicates on the conclusion that capacities of the investigated sorbents are not large for those compounds.

Latest Holocene evolution and human disturbance of a channel segment in the Hudson River Estuary

USGS Publications Warehouse

Klingbeil, A.D.; Sommerfield, C.K.

2005-01-01

The latest Holocene sedimentary record of a cohesive channel and subtidal shoal in the lower Hudson River Estuary was examined to elucidate natural (sea-level rise, sediment transport) and anthropogenic (bulkheading, dredging) influences on the recent morphodynamic evolution of the system. To characterize the seafloor and shallow subbottom, ??? 100 km of high-resolution seismic reflection profiles (chirp) were collected within a 20-km reach of the estuary and correlated with sediment lithologies provided by eight vibracores recovered along seismic lines. Sediment geochronology with 137Cs and 14C was used to estimate intermediate and long-term sedimentation rates, respectively, and historical bathymetric data were analyzed to identify regional patterns of accretion and erosion, and to quantify changes in channel geometry and sediment volume. The shoal lithosome originated around 4 ka presumably with decelerating eustatic sea level rise during the latest Holocene. Long-term sedimentation rates on the shoal (2.3-2.6 mm/yr) are higher than in the channel (2 mm/yr) owing to hydrodynamic conditions that preferentially sequester suspended sediment on the western side of the estuary. As a result, the shoal accretes oblique to the principal axis of tidal transport, and more rapidly than the channel to produce an asymmetric cross-section. Shoal deposits consist of tidally bedded muds and are stratified by minor erosion surfaces that seismic profiles reveal to extend for 10s of meters to kilometers. The frequency and continuity of these surfaces suggest that the surficial shoal is catastrophically stripped on decadal-centennial time scales by elevated tidal flows; tidal erosion maintains the shoal at a uniform depth below sea level and prevents it from transitioning to an intertidal environment. Consequently, the long-term sedimentation rate approximates the rate of sea-level rise in the lower estuary (1-3 mm/yr). After the mid 1800s, the natural geometry of the lower Hudson River Estuary changed rapidly in response to engineering works that forced the channel to self-deepen. Analysis of historical bathymetric data indicates that the channel lost an estimated 3 ?? 106 tons of sediment between ca. 1939 and 2002 (50,000 tons/yr average) by subaqueous erosion, increasing in depth by as much as 4 m in places. Erosion appears to have been concurrent with systematic bulkheading of the shoreline after ca. 1865, which decreased the estuary surface area by ??? 19% overall. Evidently, self-deepening of the channel is a morphodynamic adjustment to reestablish equilibrium cross-sectional area, yet the state of this change locally and elsewhere in the estuary is unknown. Subaqueous erosion documented in this study is a significant source of sediment with implications to the sediment budget and environmental quality of the Hudson River Estuary. ?? 2005 Elsevier B.V. All rights reserved.

Considerations of erosion and storage of carbon, focusing on tropical landscapes in Puerto Rico and Panama (Invited)

NASA Astrophysics Data System (ADS)

Stallard, R. F.

2013-12-01

Humid tropical regions are particularly good settings to examine the terrestrial carbon and nutrient cycles because the high average temperatures combined with abundant water and frequent intense storms promote rapid biological activity, weathering, and physical erosion. In studying the human-modified carbon or nutrient cycles on particular landscapes, assessments of the impact of human activities must be compared to prior states of those landscapes with regard to (1) biogeochemical reservoir sizes on the landscape, (2) rates of transport through and out of the landscape, and (3) ultimate fate of the material exported. Ongoing studies in small catchments and larger adjacent watersheds in Puerto Rico (PR) and Panama (PTY) assess which biological, hydrologic, and geomorphic mechanisms have been affected by human activities. The catchments are on older volcanic rocks (6, 2 in PR), granitic rocks (3, all in PR), and one in PTY on limey sediments. Three of the volcanic catchments and one granitic catchment are agricultural. In all these landscapes, landslides, rather than surficial erosion, appear to be the largest regional sediment source, and the biggest landslide-producing storms occur once every few decades. Both landslide-related and surficial erosion are greater in agricultural catchments compared to forested catchments on the same lithology, and granitic landscapes are eroding far more rapidly than volcanic landscapes. Physical erosion on the granitic landscapes appears to be greatly in excess of reasonable equilibrium rates based on mass balances and estimates based on Be-10. The particulate-organic-carbon (POC) yields exceed combined dissolved organic (DOC) and inorganic (DIC) carbon yields in the granitic watersheds, but they are considerably less than the DOC+DIC yields in the volcanic watersheds. Annual yields of DIC and DOC relate linearly to annual runoff, whereas POC has a steep exponential-style increase with increasing runoff, indicating a strong sensitivity to climate change, compared to a linear response. POC yields are tied to sediment yields that are, in turn, far in excess of equilibrium yields. This excess implies that much of the present carbon transport in eastern PR is the result of erosion in excess of equilibrium. In essence, soils that have developed for thousands of years are eroding more rapidly than they are now forming. Carbon accumulation in soil is rapid, and in a landslide scar, which can endure thousands of years, half of the carbon is regenerated in 80 years and all of it in about 200 years. Thus, eroding carbon is being replaced with carbon from the atmosphere. In PR, sediments are delivered to reservoirs or the ocean; in PTY deposition is in reservoirs. These reservoirs are strongly coupled sinks for carbon and nutrients. After landslides, huge quantities of sediment are deposited along with considerable wood and other organic debris. Sediment that deposits in the crenulated arms of the reservoirs is quite rich in organic matter derived from lake productivity that has been greatly augmented by nutrients derived from agricultural lands and domestic wastes. Carbon storage in reservoirs exceeds forest storage, and unlike forests, increases with time.

Nitrogen-assisted Three-phase Equilibrium in Hydrate Systems Composed of Water, Methane, Carbon Dioxide, and Nitrogen

NASA Astrophysics Data System (ADS)

Darnell, K.; Flemings, P. B.; DiCarlo, D. A.

2016-12-01

In June 2016, seawater samples at sediment-seawater interface and sediment samples were collected by the he Jiaolong, China's manned submersible, at four sampling sites located in the Yap Trench. Seawater samples from different depths of the trench were also collected by CTD. Chemical parameters, including pH, alkanility, concentrations of dissolved inorganic carbon, dissolved and total organic carbon, methane, dimethylsulfoniopropionate, nutrients, carbohydrates, and amino acids were analyzed in the seawater samples. Concentrations of total organic carbon, six constant elements and nine trace elements were determined in the sediment samples. All the vertical profiles of the chemical parameters in the seawater have unique characteristics. Our resluts also showed that the carbonate compensation depth (CCD) was between 4500 m and 5000 m in the trench. The hadal sediment at 6500 m depth under the CCD line was siliceous ooze favored for the burial of orgaic carbon, attributed to accumulation of surface sediment by gravity flow. The abyssal sediment at the 4500 m depth was calcareous ooze. Various microfossils, such as discoasters and diatoms, were identified in different sediment layers of the sediment samples.Based on the ratios of Fe/Al and Ti/Al, and the correlation between different elements, the sediment in the Yap Trench were derived from biogenic, terrestrial, volcanic and autogenic sources. The ratios of Ni/Co and V/Cr showed that the deposition environment of the trench should be oxidative, arributed to inflow of the Antractic bottom oxygen-rich seawater.The high concentraiont of Ca in the sediment from the station 371-Yap-S02 below 4 cm depth indicated that there was no large-scale volcanic eruption in the research area and the volcanic materials in the sediment might orginated from the Mariana Volcanic Arc, and the Carolyn Ridge has been slowly sinking on the east side of the trench due to plate subduction. This study is the first systematic study of chemical characteristics in the seawater and sediment of the Yap Trench.

An approach to standardization of urine sediment analysis via suggestion of a common manual protocol.

PubMed

Ko, Dae-Hyun; Ji, Misuk; Kim, Sollip; Cho, Eun-Jung; Lee, Woochang; Yun, Yeo-Min; Chun, Sail; Min, Won-Ki

2016-01-01

The results of urine sediment analysis have been reported semiquantitatively. However, as recent guidelines recommend quantitative reporting of urine sediment, and with the development of automated urine sediment analyzers, there is an increasing need for quantitative analysis of urine sediment. Here, we developed a protocol for urine sediment analysis and quantified the results. Based on questionnaires, various reports, guidelines, and experimental results, we developed a protocol for urine sediment analysis. The results of this new protocol were compared with those obtained with a standardized chamber and an automated sediment analyzer. Reference intervals were also estimated using new protocol. We developed a protocol with centrifugation at 400 g for 5 min, with the average concentration factor of 30. The correlation between quantitative results of urine sediment analysis, the standardized chamber, and the automated sediment analyzer were generally good. The conversion factor derived from the new protocol showed a better fit with the results of manual count than the default conversion factor in the automated sediment analyzer. We developed a protocol for manual urine sediment analysis to quantitatively report the results. This protocol may provide a mean for standardization of urine sediment analysis.

Bathymetry and Sediment-Storage Capacity Change in Three Reservoirs on the Lower Susquehanna River, 1996-2008

USGS Publications Warehouse

Langland, Michael J.

2009-01-01

The Susquehanna River transports a substantial amount of the sediment and nutrient load to the Chesapeake Bay. Upstream of the bay, three large dams and their associated reservoirs trap a large amount of the transported sediment and associated nutrients. During the fall of 2008, the U.S. Geological Survey in cooperation with the Pennsylvania Department of Environmental Protection completed bathymetric surveys of three reservoirs on the lower Susquehanna River to provide an estimate of the remaining sediment-storage capacity. Previous studies indicated the upper two reservoirs were in equilibrium with long-term sediment storage; only the most downstream reservoir retained capacity to trap sediments. A differential global positioning system (DGPS) instrument was used to provide the corresponding coordinate position. Bathymetry data were collected using a single beam 210 kHz (kilohertz) echo sounder at pre-defined transects that matched previous surveys. Final horizontal (X and Y) and vertical (Z) coordinates of the geographic positions and depth to bottom were used to create bathymetric maps of the reservoirs. Results indicated that from 1996 to 2008 about 14,700,000 tons of sediment were deposited in the three reservoirs with the majority (12,000,000 tons) being deposited in Conowingo Reservoir. Approximately 20,000 acre-feet or 30,000,000 tons of remaining storage capacity is available in Conowingo Reservoir. At current transport (3,000,000 tons per year) and deposition (2,000,000 tons per year) rates and with no occurrence of major scour events due to floods, the remaining capacity may be filled in 15 to 20 years. Once the remaining sediment-storage capacity in the reservoirs is filled, sediment and associated phosphorus loads entering the Chesapeake Bay are expected to increase.

Colloid formation in Hanford sediments reacted with simulated tank waste.

PubMed

Mashal, Kholoud; Harsh, James B; Flury, Markus; Felmy, Andrew R; Zhao, Hongting

2004-11-01

Solutions of high pH, ionic strength, and aluminum concentration have leaked into the subsurface from underground waste storage tanks atthe Hanford Reservation in Washington State. Here, we test the hypothesis that these waste solutions alter and dissolve the native minerals present in the sediments and that colloidal (diameter < 2 microm) feldspathoids form. We reacted Hanford sediments with simulated solutions representative of Hanford waste tanks. The solutions consisted of 1.4 or 2.8 mol/kg NaOH, 0.125 or 0.25 mol/kg NaAlO4, and 3.7 mol/kg NaNO3 and were contacted with the sediments for a period of 25 or 40 days at 50 degrees C. The colloidal size fraction was separated from the sediments and characterized in terms of mineralogy, morphology, chemical composition, and electrophoretic mobility. Upon reaction with tank waste solutions, native minerals released Si and other elements into the solution phase. This Si precipitated with the Al present in the waste solutions to form secondary minerals, identified as the feldspathoids cancrinite and sodalite. The solution phase was modeled with the chemical equilibrium model GMIN for solution speciation and saturation indices with respect to sodalite and cancrinite. The amount of colloidal material in the sediments increased upon reaction with waste solutions. At the natural pH found in Hanford sediments (pH 8) the newly formed minerals are negatively charged, similar to the unreacted colloidal material present in the sediments. The formation of colloidal material in Hanford sediments upon reaction with tank waste solutions is an important aspect to consider in the characterization of Hanford tank leaks and may affect the fate of hazardous radionuclides present in the tank waste.

Geomorphology and sediment transport on a submerged back-reef sand apron: One Tree Reef, Great Barrier Reef

NASA Astrophysics Data System (ADS)

Harris, Daniel L.; Vila-Concejo, Ana; Webster, Jody M.

2014-10-01

Back-reef sand aprons are conspicuous and dynamic sedimentary features in coral reef systems. The development of these features influences the evolution and defines the maturity of coral reefs. However, the hydrodynamic processes that drive changes on sand aprons are poorly understood with only a few studies directly assessing sediment entrainment and transport. Current and wave conditions on a back-reef sand apron were measured during this study and a digital elevation model was developed through topographic and bathymetric surveying of the sand apron, reef flats and lagoon. The current and wave processes that may entrain and transport sediment were assessed using second order small amplitude (Stokes) wave theory and Shields equations. The morphodynamic interactions between current flow and geomorphology were also examined. The results showed that sediment transport occurs under modal hydrodynamic conditions with waves the main force entraining sediment rather than average currents. A morphodynamic relationship between current flow and geomorphology was also observed with current flow primarily towards the lagoon in shallow areas of the sand apron and deeper channel-like areas directing current off the sand apron towards the lagoon or the reef crest. These results show that the short-term mutual interaction of hydrodynamics and geomorphology in coral reefs can result in morphodynamic equilibrium.

Linking morphology to ecosystem structure using satellite for monitoring Wetlands

NASA Astrophysics Data System (ADS)

Filipponi, F.; Valentini, E.; Taramelli, A.; Giulio, S.; Persichillo, M.; D'Alpaos, A.

2013-12-01

Modern views on the behavior of complex systems, like the low lying coastal areas, allow the interpretation of phenomenological coastal landscape as a steady state that corresponds to a dynamic equilibrium, and to a self-organized exogenic order of the edge of the chaos. Space-borne data, coupled with field spectral measurements and observations, are quantitative tools for the research on feedbacks between the biological influences and physical forming processes steering landscape changes, allowing the identification of critical thresholds beyond which the ecosystem reach a new steady state. This research deals with a multi-temporal change analysis of halophytic vegetation and morphology of two analogous accumulation sites along the northern Adriatic adjoining coast: the 'Bacan island' (Venice Lagoon) and the Spit of Goro Lagoon (Po Delta). These two sites represent delicate ecosystems and are susceptible to different drivers being located close to the lagoon's inlet. The two tests sites support a great biodiversity and supply important resources, so the conservation of their habitats is necessary to maintain the ecosystem services provision. Evidence from previous studies highlights the role of climate, mostly winds and hydrology acting on sediment transport, but only few accounts for the role of vegetation in landform shaping and sediment stabilizing. In this study spatial trends of both vegetation cover/typology and sediment/soil distribution are implemented to obtain detailed classification from EO. By means of sub-pixel processing techniques (Spectral Mixing Analysis), classifications are analyzed in terms of spatial (Power law) and temporal (Empirical Orthogonal Functions) patterns, in order to find the fingerprint of spatial patterns of vegetation, sediments and very shallow waters and their variation over time. The application of a double step analysis from coarse to finer spatial resolution lead first to a biophysical cover map in term of vegetation typologies and cover percent, sediment typology and length of the different branches highlighting the mosaic of spatial pattern of vegetation, sediments and morphology. Then our results support the fact that the most frequent patch sizes, corresponding to the smallest vegetation patches as consistent with a power law relationship, are associated with the highest length values and specific sediments values; as the patch sizes become larger, and thus less frequent, the length next to patches decreases and reaches much lower values in relations to sediments classes. This indicates that at first, the formation of small vegetation patches increases flow resistance and facilitates the formation of new morphology; at the same time, when a threshold size is reached (due to patch growth or merging between adjacent patches), vegetation controls length of the different branches. In the framework of spatial self-organization, this method gives rise to a new approach to the study of landscape-forming processes, taking into account the prominent role of living organisms in shaping Earth's surface, in order to develop new instruments and tools that allow modular variation of spatial and temporal scales of observation (i.e. from local to regional; from seasonal to inter annual) that is mandatory for a valuable implementation of current management and conservation strategies (Integrated Coastal Zone Management).

Evaluation of Bajo Blanco Sandbar as a Potential Beach Nourishment Borrow Site for Eroding Beaches in Rincon, Puerto Rico

NASA Astrophysics Data System (ADS)

Rojas, C. A.; Canals, M.

2016-02-01

The municipality of Rincón, Puerto Rico is recognized for its world-class surfing beaches. Unfortunately, the coast from Punta Higüero to Punta Cadena in Rincón is experiencing long-term erosion (Thieler 2007), which has caused the destruction of many beachfront homes and hotels and had negative impacts on the local tourism-driven economy. The purpose of this project is to evaluate whether the nearby Bajo Blanco sandbar, located just offshore of these eroded beaches, could be used as a possible beach nourishment borrow site. A high-resolution bathymetric survey of Bajo Blanco sandbar was conducted along with a grain size analysis to compare the grain size distribution of the Bajo Blanco sandbar with the sediment properties of the eroded beaches. It was found that the sediment from Bajo Blanco is finer yet may be suitable as beach fill material for these beaches according to Dean's overfill ratio. Compatibility analysis suggests a total volume of sandbar sediment of approximately 685,555 cubic meters to allow successful beach equilibrium. To evaluate the potential effects of the sand extraction on the nearshore wave climate, numerical simulations were performed using the spectral wave model of the USACE Coastal Modeling System (CMS-Wave). Wave model results for several dredging scenarios suggest that wave energy flux concentrates around the shoal causing an increase in wave height at the northern and southern edges of the shoal. Therefore, conservation of energy leads to a reduction of wave energy flux shoreward of the shoal, causing a shadow of reduced wave height. In addition, the Tres Palmas Marine reserve is located just north of Bajo Blanco sandbar and features some of the healthiest Elkorn Corals in the Caribbean. To avoid excessive sedimentation of these reefs during dredging activities, the Particle Tracking Module (PTM), integrated in the Surface-water Modeling System (SMS), was used to evaluate the Lagrangian particle transport processes along Bajo Blanco under various wave conditions. Results suggest that dredging operations be conducted during small to moderate wave events, since the wave-induced currents related to these events force sediment particles to advect south and thus away from the Tres Palmas Marine Reserve.

Interactions between globular proteins and F-actin in isotonic saline solution.

PubMed

Lakatos, S; Minton, A P

1991-10-05

Solutions of each of three different globular proteins (cytochrome c, chromophorically labeled serum albumin, and chromophorically labeled aldolase), mixed with another unlabeled globular protein or with fibrous actin, were prepared in pH 8.0 Tris-HCl buffer containing 0.15 M NaCl. Each solution was centrifuged at low speed, at 5 degrees C, until unassociated globular protein in solution achieved sedimentation equilibrium. Individual absorbance gradients of both macrosolutes in the mixtures subsequent to centrifugation were obtained via optical scans of the centrifuge tubes at two wavelengths. The gradients of each macrosolute in mixtures of two globular proteins revealed no association of globular proteins under the conditions of these experiments, but perturbation of the gradients of serum albumin, aldolase, and cytochrome c in the presence of F-actin indicated association of all three globular proteins with F-actin. Perturbation of actin gradients in the presence of serum albumin and aldolase suggested partial depolymerization of the F-actin by the globular protein. Analysis of the data with a simple phenomenological model relating free globular protein, bound globular protein, and total actin concentration provided estimates of the respective equilibrium constants for association of serum albumin and aldolase with F-actin, under the conditions of these experiments, of the order of 0.1 microM-1.

Methodology for predicting maximum velocity and shear stress in a sinuous channel with bendway weirs using 1-D HEC-RAS modeling results

Treesearch

Paul Sclafani; Christopher I. Thornton; Amanda L. Cox; Steven R. Abt

2012-01-01

As with every natural process, river morphology incorporates a complex and nuanced set of processes that combine to produce an infinite set of possible outcomes. Natural laws that govern natural systems cause rivers to react to changes in the environment in order to maintain equilibrium. Changes in hydraulics, sediment transport, and habitat help keep natural systems...

Research and Development of Methods for Estimating Physicochemical Properties of Organic Compounds of Environmental Concern

DTIC Science & Technology

1979-02-01

coefficient (at equilibrium) when hysteresis is apparent. 6. Coefficient n in Freundlich equation for 1/n soil or sediment adsorption isotherms ýX - KC . 7...Biodegradation Chemical structures cal clasaes (e.g., Diffusion Correlations phenols). General Diffusion coefficients Equations terms for organic...OF THE FATE AND TRANSPORT OF ORGANIC CHEMICALS Adsorption coefficients: K, n* from Freundlich equation + Desorption coefficients: K’*, n’* from

Availability of polycyclic aromatic hydrocarbons to earthworms (Eisenia andrei, Oligochaeta) in field-polluted soils and soil-sediment mixtures.

PubMed

Jager, Tjalling; Baerselman, Rob; Dijkman, Ellen; de Groot, Arthur C; Hogendoorn, Elbert A; de Jong, Ad; Kruitbosch, Jantien A W; Peijnenburg, Willie J G M

2003-04-01

The bioavailability of polycyclic aromatic hydrocarbons (PAHs) for earthworms (Eisenia andrei) was experimentally determined in seven field-polluted soils and 15 soil-sediment mixtures. The pore-water concentration of most PAHs was higher than predicted. However, most of the compound was associated with dissolved organic carbon (DOC) and not directly available for uptake by earthworms. The apparent sorption could be reasonably predicted on the basis of interactions with DOC; however, the biota-soil accumulation factors (BSAFs) for earthworms were up to two orders of magnitude lower than predicted by equilibrium partitioning. The large variability between sites was not fully explained by differences in sorption. Experimental results indicate that the pool of freely dissolved PAHs in the pore water became partially depleted because of uptake by the earthworms and that bioaccumulation is thus also influenced by the kinetics of PAH desorption and mass transport. A pilot study with Lumbricus rubellus showed that steady-state body residues were well correlated to E. andrei. Current results show that depositing dredge spoil on land may lead to increased bioavailability of the lower-molecular-weight PAHs. However, risk assessment can conservatively rely on equilibrium partitioning, but accurate prediction requires quantification of the kinetics of bioavailability.

A 20,000-year record of environmental change from Laguna Kollpa Kkota, Bolivia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seltzer, G.O.; Abbott, M.B.

Most records of paleoclimate in the Bolivian Andes date from the last glacial-to-interglacial transition. However, Laguna Kollpa Kkota and other lakes like it, formed more than 20,000 yr BP when glaciers retreated and moraines dammed the drainage of the valleys they are located in. These lakes were protected from subsequent periods of glaciation because the headwalls of these valleys are below the level of the late-Pleistocene glacial equilibrium-line altitude. The chemical, mineral, and microfossil stratigraphies of these glacial lakes provide continuous records of environmental change for the last 20,000 years that can be used to address several problems in paleoclimatemore » specific to tropical-subtropical latitudes. Preliminary results from Laguna Kollpa Kkota indicate that glacial equilibrium-line altitudes were never depressed more than 600 m during the last 20,000 years, suggesting that temperatures were reduced only a few-degrees celsius over this time period. Sedimentation rates and the organic carbon stratigraphy of cores reflect an increase in moisture in the late Pleistocene just prior to the transition to a warmer and drier Holocene. The pollen and diatom concentrations in the sediments are sufficient to permit the high resolution analyses needed to address whether or not there were climatic reversals during the glacial-to-interglacial transition.« less

Factors controlling dimethylsulfide emission from salt marshes

NASA Technical Reports Server (NTRS)

Dacey, John W. H.; Wakeham, S. G.; Howes, B. L.

1985-01-01

The factors that control the emission of methylated gases from salt marshes are being studied. Research focusses on dimethylsulfide (DMS) formation and the mechanism of DMS and CH4 emission to the atmosphere. The approach is to consider the plants as valves regulating the emission of methylated gases to the atmosphere with the goal of developing appropriate methods for emission measurement. In the case of CH4, the sediment is the source and transport to the atmosphere occurs primarily through the internal gas spaces in the plants. The source of DMS appears to be dimethyl sulfoniopropionate (DMSP) which may play a role in osmoregulation in plant tissues. Concentrations of DMSP in leaves are typically several-fold higher than in roots and rhizomes. Even so, the large below ground biomass of this plant means that 2/3 of the DMSP in the ecosystem is below ground on the aerial basis. Upon introduction to sediment water, DMSP rapidly decomposes to DMS and acrylic acid. The solubility of a gas (its equilibrium vapor pressure) is a fundamental aspect of gas exchange kinetics. The first comprehensive study was conducted of DMS solubility in freshwater and seawater. Data suggest that the Setchenow relation holds for H at intermediate salinities collected. These data support the concept that the concentration of DMS in the atmosphere is far from equilibrium with seawater.

Sediment transport dynamics in response to large-scale human intervention

NASA Astrophysics Data System (ADS)

Eelkema, Menno; Wang, Zheng Bing

2010-05-01

SEDIMENT TRANSPORT DYNAMICS IN RESPONSE TO LARGE-SCALE HUMAN INTERVENTION M. Eelkema and Z.B. Wang The Eastern Scheldt basin in the southwestern part of the Netherlands is an elongated tidal basin of approximately 50 km in length with an average tidal range of roughly 3 meters at the inlet. Before 1969 A.D., this basin was also connected to two more tidal basins to the north through several narrow, yet deep channels. These connections were closed off with dams in the nineteen sixties in response to the catastrophic flooding in 1953. In the inlet of the Eastern Scheldt a storm-surge barrier was built in order to safeguard against flooding during storms while retaining a part of the tidal influence inside the basin during normal conditions. This barrier was finalized in 1986. The construction of the back-barrier dams in 1965 and 1969 had a significant impact on the tidal hydrodynamics and sediment transport (Van den Berg, 1986). The effects of these interventions were still ongoing when the hydrodynamic regime was altered again by the construction of the storm-surge barrier between 1983 and 1986. This research aims to describe the hydrodynamic and morphodynamic evolution of the Eastern Scheldt between 1953 and 1983, before construction of the storm-surge barrier had started. An analysis is made of the manner in which the back-barrier dams changed the tidal flow through the basin, and how these altered hydrodynamics influenced the sediment transport and morphology. This analysis consists first of all of a description of the observed hydrodynamical and bathymetrical changes. Second, these observations are used as input for a process-based hydrodynamic model (Delft3D), which is applied in order to gain more insight into the changes in sediment transport patterns. The model is used to simulate the situations before and after the closures of the connections between the Eastern Scheldt and the basins north of it In the decades before 1965, the Eastern Scheldt exported large quantities of sediment towards sea through its inlet. This export was estimated to be roughly 2 to 3 million m3 per year, and was observable as deepening channels inside the basin, and a growing ebb-tidal delta. The implementation of the dams caused a significant increase in tidal prism, while at the same time they stopped the residual flow of water from the Eastern Scheldt towards the northern basins. The increase in tidal prism was observable in the response of bathymetry; the rates of channel deepening and ebb-tidal delta growth both increased. Analysis of tidal flow measurements and model output show a persistent trend for sediment transport towards and out of the Eastern Scheldt's inlet. This export is caused by both the strong ebb-directed asymmetry in the tidal flow as well as higher sediment concentrations during ebb. The construction of the back-barrier dams only amplified this export by cutting off the residual import of flow and by causing the basin to be out of equilibrium even more than it apparently already was. References Van den Berg, J.H., 1986. Aspects of Sediment- and Morphodynamics of Subtidal Deposits of the Oosterschelde (the Netherlands). Rijkswaterstaat Communications, no. 43/1986, The Hague.

Modelling of hyperconcentrated flood and channel evolution in a braided reach using a dynamically coupled one-dimensional approach

NASA Astrophysics Data System (ADS)

Xia, Junqiang; Zhang, Xiaolei; Wang, Zenghui; Li, Jie; Zhou, Meirong

2018-06-01

Hyperconcentrated sediment-laden floods often occur in a braided reach of the Lower Yellow River, usually leading to significant channel evolution. A one-dimensional (1D) morphodynamic model using a dynamically coupled solution approach is developed to simulate hyperconcentrated flood and channel evolution in the braided reach with an extremely irregular cross-sectional geometry. In the model, the improved equations for hydrodynamics account for the effects of sediment concentration and bed evolution, which are coupled with the equations of non-equilibrium sediment transport and bed evolution. The model was validated using measurements from the 1977 and 2004 hyperconcentrated floods. Furthermore, the effects were investigated of different cross-sectional spacings and allocation modes of channel deformation area on the model results. It was found that a suitable cross-sectional distance of less than 3 km should be adopted when simulating hyperconcentrated floods, and the results using the uniform allocation mode can agree better with measurements than other two allocation modes.

Amending soils with sediment material from constructed wetlands increases phosphorus sorption

NASA Astrophysics Data System (ADS)

Laakso, Johanna; Uusitalo, Risto; Leppänen, Janette; Yli-Halla, Markku

2017-04-01

Sediment of agricultural constructed wetlands (CWs) is comprised of matter eroded from surrounding fields. This material is rich in aluminium (Al) and iron (Fe) (hydr)oxides that have a high affinity for phosphorus (P). Sediment material returned to fields could therefore affect soil P retention characteristics. We incubated a clay soil with a high soil test P (STP, 24 mg PAc l-1; extracted with pH 4.65 ammonium acetate buffer) and a sandy loam with excessive STP (210 mg PAc l-1) for three weeks with increasing amounts of CW sediment: 0, 2, 5, 10 and 50% of the sample volume. After incubation, the soil-sediment mixtures were studied with the quantity/intensity (Q/I) technique, using chemical extractions and by exposing the mixtures to simulated rainfall. Sorption affinity for P regularly increased with increasing the sediment share of the mixtures, the 0% sediment content having the lowest and 50% sediment content the highest P sorption. With 0% sediment application, the value of equilibrium P concentration (EPC0) determined by Q/I technique, was 0.69 and 44.3 mg l-1 for clay soil and sandy loam, respectively. With 2-5% sediment amendment, the EPC0 decreased 13-36% for clay soil and 13-54% for sandy loam. The 50% sediment mixtures had EPC0 of 0.05 mg l-1 for both soils. At a practically feasible sediment addition rate of 5%, dissolved reactive P (DRP) in percolating water from simulated rainfall decreased by 55% in the clay soil and 54% in sandy loam (p<0.001 in both cases). Particulate-P (PP) also showed a decreasing trend with increasing sediment addition rate. Upon prolonged simulated rainfall, the decreasing effect of sediment on DRP and PP declined somewhat. The effects of sediment addition can be attributed partly to increased salt concentrations in the sediment, which have a short-term effect on P mobilisation, but mostly to increased concentrations of Al and Fe (hydr)oxides, increasing long-term P sorption capacity. Amending the soils with sediment material would decrease P solubility and might at large application rates hamper P uptake by plants or, on the other hand, the sediment amendment in the soil might reduce P losses by runoff.

Sedimentation equilibrium of a small oligomer-forming membrane protein: effect of histidine protonation on pentameric stability.

PubMed

Surya, Wahyu; Torres, Jaume

2015-04-02

Analytical ultracentrifugation (AUC) can be used to study reversible interactions between macromolecules over a wide range of interaction strengths and under physiological conditions. This makes AUC a method of choice to quantitatively assess stoichiometry and thermodynamics of homo- and hetero-association that are transient and reversible in biochemical processes. In the modality of sedimentation equilibrium (SE), a balance between diffusion and sedimentation provides a profile as a function of radial distance that depends on a specific association model. Herein, a detailed SE protocol is described to determine the size and monomer-monomer association energy of a small membrane protein oligomer using an analytical ultracentrifuge. AUC-ES is label-free, only based on physical principles, and can be used on both water soluble and membrane proteins. An example is shown of the latter, the small hydrophobic (SH) protein in the human respiratory syncytial virus (hRSV), a 65-amino acid polypeptide with a single α-helical transmembrane (TM) domain that forms pentameric ion channels. NMR-based structural data shows that SH protein has two protonatable His residues in its transmembrane domain that are oriented facing the lumen of the channel. SE experiments have been designed to determine how pH affects association constant and the oligomeric size of SH protein. While the pentameric form was preserved in all cases, its association constant was reduced at low pH. These data are in agreement with a similar pH dependency observed for SH channel activity, consistent with a lumenal orientation of the two His residues in SH protein. The latter may experience electrostatic repulsion and reduced oligomer stability at low pH. In summary, this method is applicable whenever quantitative information on subtle protein-protein association changes in physiological conditions have to be measured.

The Role of Grain Dynamics in the Onset of Sediment Transport

NASA Astrophysics Data System (ADS)

Clark, A., IV; Shattuck, M. D.; Ouellette, N. T.; O'Hern, C.

2016-12-01

Despite decades of research, the grain-scale mechanisms that control the onset of sediment transport are still not well understood. A large collection of data, known as the Shields curve, shows that Θ c, which is the minimum dimensionless shear stress at the bed for grains to move, is primarily a function of the shear Reynolds number Re*. To understand this collapse, it is typically assumed that the onset of grain motion is determined by the conditions at which fluid forces violate static equilibrium for surface grains. Re* compares the grain size to the size of the viscous sublayer in the fluid flow, so the relevant fluid lift and drag forces vary with Re*. A complimentary approach, which remains relatively unexplored, is to ask instead when mobilized grains can stop. In this case, Re* is the ratio of two important time scales related to grain motion: (1) the time for a grain to equilibrate to the fluid flow and (2) the time for the shear stress to accelerate a grain over the characteristic bed roughness. Thus, Re* controls whether grains are accelerated significantly between collisions with the bed. To test how this effect relates to the Shields curve, we perform simulations of granular beds sheared by a model fluid flow, where Re* is varied only through the fluid-grain coupling, which alters the grain dynamics. We find good qualitative agreement with the Shields curve, and the quantitative discrepancies are consistent with lift forces calculations at varying Re*. Our results suggest that the onset of sediment transport may be better described as when mobile grains are able to stop, which varies significantly with Re*, and theoretical descriptions that account for this effect may be more successful than those that consider only static equilibrium.

Hydromorphodynamic effects of the width ratio and local tributary widening on discordant confluences

NASA Astrophysics Data System (ADS)

Guillén-Ludeña, S.; Franca, M. J.; Alegria, F.; Schleiss, A. J.; Cardoso, A. H.

2017-09-01

River training works performed in the last couple of centuries constrained the natural dynamics of channel networks in locations that include the confluences between tributaries and main channels. As a result, the dynamics of these confluences are currently characterized by homogeneous flow depths, flow velocities, and morphologic conditions, which are associated with impoverished ecosystems. The widening of river reaches is seen as a useful measure for river restoration, as it enhances the heterogeneity in flow depths, flow velocities, sediment transport, and bed substrates. The purpose of this study is to analyze the effects of local widening of the tributary mouth as well as the effects of the ratio between the width of the tributary and that of the main channel on the flow dynamics and bed morphology of river confluences. For that purpose, 12 experiments were conducted in a 70° laboratory confluence. In these experiments, three unit-discharge ratios were tested (qr = 0.37, 0.50, and 0.77) with two width ratios and two tributary configurations. The unit-discharge ratio is defined as the unit discharge in the tributary divided by that of the main channel, measured upstream of the confluence. The width ratio, which is defined as the width of the tributary divided by that of the main channel, was modified by changing the width of the main channel from 0.50 to 1.00 m (corresponding to Br = 0.30 and 0.15 respectively). The tributary configurations consisted of (i) a straight reach with a constant width (the so-called reference configuration) and (ii) a straight reach with a local widening at the downstream end (the so-called widened configuration). During the experiments, a uniform sediment mixture was continuously supplied to both channels. This experimental setup is novel among existing experimental studies on confluence dynamics, as it addresses new confluence configurations and includes a continuous sediment supply to both channels. The experiments were run until the outgoing sediment rate was nearly the same as the incoming; i.e., equilibrium had been achieved. The bed topography and water surface were then recorded in both channels. The results reveal that the width ratio and the locally widened tributary reach influence the dynamics of the confluence. The different width ratios influenced the size of the bank-attached bar at equilibrium, which was wider and longer for Br = 0.15 than for Br = 0.30. Other morphological differences were observed at equilibrium for the different width ratios, such as deeper scour holes and increased penetration of the tributary into the main channel. These differences were attributed to the different values of the ratio between the unit momentum-flux of the tributary and that of the main channel that were noted at equilibrium for the different width ratios. The local widening of the downstream reach of the tributary significantly enhanced the heterogeneity in flow depth, flow velocity, and bed morphology within the widened reach. This heterogeneity contrasts with the homogeneity observed in the tributary without widening (reference configuration). Additionally, the effects of the local tributary widening were limited to the tributary, with minor or negligible effects on the main channel.

Hydrated calcareous oil-shale ash as potential filter media for phosphorus removal in constructed wetlands.

PubMed

Kaasik, Ago; Vohla, Christina; Mõtlep, Riho; Mander, Ulo; Kirsimäe, Kalle

2008-02-01

The P-retention in hydrated calcareous ash sediment from oil-shale burning thermal power plants in Estonia was studied. Batch experiments indicate good (up to 65 mg P g(-1)) P-binding capacity of the hydrated oil-shale ash sediment, with a removal effectiveness of 67-85%. The high phosphorus sorption potential of hydrated oil-shale ash is considered to be due to the high content of reactive Ca-minerals, of which ettringite Ca6Al2(SO4)3(OH)12.26H2O and portlandite Ca(OH)2 are the most important. The equilibrium dissolution of ettringite provides free calcium ions that act as stable nuclei for phosphate precipitation. The precipitation mechanism of phosphorus removal in hydrated ash plateau sediment is suggested by Ca-phosphate formation in batch experiments at different P-loadings. Treatment with a P-containing solution causes partial-to-complete dissolution of ettringite and portlandite, and precipitation of Ca-carbonate and Ca-phosphate phases, which was confirmed by X-ray diffraction (XRD) and scanning electron microscope (SEM)-EDS studies. Thus, the hydrated oil-shale ash sediment can be considered as a potential filtration material for P removal in constructed wetlands for wastewater treatment.

Tidal controls on river delta morphology

NASA Astrophysics Data System (ADS)

Hoitink, A. J. F.; Wang, Z. B.; Vermeulen, B.; Huismans, Y.; Kästner, K.

2017-09-01

River delta degradation has been caused by extraction of natural resources, sediment retention by reservoirs, and sea-level rise. Despite global concerns about these issues, human activity in the world’s largest deltas intensifies. Harbour development, construction of flood defences, sand mining and land reclamation emerge as key contemporary factors that exert an impact on delta morphology. Tides interacting with river discharge can play a crucial role in the morphodynamic development of deltas under pressure. Emerging insights into tidal controls on river delta morphology suggest that--despite the active morphodynamics in tidal channels and mouth bar regions--tidal motion acts to stabilize delta morphology at the landscape scale under the condition that sediment import during low flows largely balances sediment export during high flows. Distributary channels subject to tides show lower migration rates and are less easily flooded by the river because of opposing non-linear interactions between river discharge and the tide. These interactions lead to flow changes within channels, and a more uniform distribution of discharge across channels. Sediment depletion and rigorous human interventions in deltas, including storm surge defence works, disrupt the dynamic morphological equilibrium and can lead to erosion and severe scour at the channel bed, even decades after an intervention.

Passive sampling methods for contaminated sediments: Practical guidance for selection, calibration, and implementation

PubMed Central

Ghosh, Upal; Driscoll, Susan Kane; Burgess, Robert M; Jonker, Michiel To; Reible, Danny; Gobas, Frank; Choi, Yongju; Apitz, Sabine E; Maruya, Keith A; Gala, William R; Mortimer, Munro; Beegan, Chris

2014-01-01

This article provides practical guidance on the use of passive sampling methods (PSMs) that target the freely dissolved concentration (Cfree) for improved exposure assessment of hydrophobic organic chemicals in sediments. Primary considerations for selecting a PSM for a specific application include clear delineation of measurement goals for Cfree, whether laboratory-based “ex situ” and/or field-based “in situ” application is desired, and ultimately which PSM is best-suited to fulfill the measurement objectives. Guidelines for proper calibration and validation of PSMs, including use of provisional values for polymer–water partition coefficients, determination of equilibrium status, and confirmation of nondepletive measurement conditions are defined. A hypothetical example is described to illustrate how the measurement of Cfree afforded by PSMs reduces uncertainty in assessing narcotic toxicity for sediments contaminated with polycyclic aromatic hydrocarbons. The article concludes with a discussion of future research that will improve the quality and robustness of Cfree measurements using PSMs, providing a sound scientific basis to support risk assessment and contaminated sediment management decisions. Integr Environ Assess Manag 2014;10:210–223. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. PMID:24288273

Consensus sediment quality guidelines for polycyclic aromatic hydrocarbon mixtures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swartz, R.C.

1999-04-01

Sediment quality guidelines (SQGs) for polycyclic aromatic hydrocarbons (PAHs) have been derived from a variety of laboratory, field, and theoretical foundations. They include the screening level concentration, effects ranges-low and -median, equilibrium partitioning concentrations, apparent effects threshold, {Sigma}PAH model, and threshold and probable effects levels. The resolution of controversial differences among the PAH SQGs lies in an understanding of the effects of mixtures. Polycyclic aromatic hydrocarbons virtually always occur in field-collected sediment as a complex mixture of covarying compounds. When expressed as a mixture concentration, that is, total PAH (TPAH), the guidelines form three clusters that were intended in theirmore » original derivations to represent threshold (TEC = 290 {micro}g/g organic carbon [OC]), median (MEC = 1,800 {micro}g/g OC), and extreme (EEC = 10,000 {micro}g/g OC) effects concentrations. The TEC/MEC/EEC consensus guidelines provide a unifying synthesis of other SQGs, reflect causal rather than correlative effects, account for mixtures, and predict sediment toxicity and benthic community perturbations at sites of PAH contamination. The TEC offers the most useful SQG because PAH mixtures are unlikely to cause adverse effects on benthic ecosystems below the TEC.« less

Effects of triclosan on marine benthic and epibenthic organisms.

PubMed

Perron, Monique M; Ho, Kay T; Cantwell, Mark G; Burgess, Robert M; Pelletier, Marguerite C

2012-08-01

Triclosan is an antimicrobial compound that has been widely used in consumer products such as toothpaste, deodorant, and shampoo. Because of its widespread use, triclosan has been detected in various environmental media, including wastewater, sewage sludge, surface waters, and sediments. Triclosan is acutely toxic to numerous aquatic organisms, but very few studies have been performed on estuarine and marine benthic organisms. For whole sediment toxicity tests, the sediment-dwelling estuarine amphipod, Ampelisca abdita, and the epibenthic mysid shrimp, Americamysis bahia, are commonly used organisms. In the present study, median lethal concentration values (LC50) were obtained for both of these organisms using water-only and whole sediment exposures. Acute 96-h water-only toxicity tests resulted in LC50 values of 73.4 and 74.3 µg/L for the amphipod and mysid, respectively. For the 7-d whole sediment toxicity test, LC50 values were 303 and 257 mg/kg (dry wt) for the amphipod and mysid, respectively. Using equilibrium partitioning theory, these whole sediment values are equivalent to interstitial water LC50 values of 230 and 190 µg/L for the amphipod and mysid, respectively, which are within a threefold difference of the observed 96-h LC50 water-only values. Triclosan was found to accumulate in polychaete tissue in a 28-d bioaccumulation study with a biota-sediment accumulation factor of 0.23 kg organic carbon/kg lipid. These data provide some of the first toxicity data for triclosan with marine benthic and epibenthic species while also indicating a need to better understand the effects of other forms of sediment carbon, triclosan ionization, and organism metabolism of triclosan on the chemical's behavior and toxicity in the aquatic environment. Copyright © 2012 SETAC.

Ammonia Gas Transport and Reactions in Unsaturated Sediments: Implications for Use as an Amendment to Immobilize Inorganic Contaminants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhong, Lirong; Szecsody, James E.; Truex, Michael J.

Use of gas-phase amendments for in situ remediation of inorganic contaminants in unsaturated sediments of the vadose zone may be advantageous, but there has been limited development and testing of gas remediation technologies. Treatment with ammonia gas has been studied and has a potential for use in treating inorganic contaminants such as uranium because it induces a high pore-water pH causing mineral dissolution and subsequent formation of stable precipitates that decrease the mobility of some contaminants. For field application, knowledge of ammonia transport and the geochemical reactions induced by ammonia is needed. Laboratory studies were conducted to support calculations neededmore » for field treatment design, to quantify advective and diffusive ammonia transport in unsaturated sediments, to evaluate reactions among gas, sediment, and water, and to study reaction-induced pore-water chemistry changes as a function of ammonia delivery conditions. Ammonia gas quickly partitions into sediment pore water and increases pH up to 13.2. Injected ammonia gas front movement can be reasonably predicted by gas flow rate and equilibrium partitioning. The ammonia gas diffusion rate is a function of the water content in the sediment. Measured diffusion front movement was 0.05, 0.03, and 0.02 cm/hr. in sediments with 2.0%, 8.7%, and 13.0% water content, respectively. Sodium, aluminum, and silica pore-water concentrations increase on exposure to ammonia and then decline as aluminosilicates precipitate with declining pH. When uranium is present in the sediment and pore water, up to 85% of the water-leachable uranium was immobilized by ammonia treatment.« less

Drivers of Microbial Metabolic Activity, Biogeochemical Cycling and Associated Greenhouse Gas Production in Streambed Sediments

NASA Astrophysics Data System (ADS)

Comer-Warner, S.; Krause, S.; Gooddy, D.; Blaen, P.; Brekenfeld, N.; Wexler, S.; Kaiser, J.

2017-12-01

Hotspots of enhanced biogeochemical reactivity are produced where groundwater and surface water mixes in streambed sediments. This enhanced reactivity is due to elevated residence times and nutrient concentrations found in these areas, leading to increased rates of microbial metabolic activity. Streambed sediments, therefore, may be important in reducing catchment-wide nutrient concentrations through increased cycling. However, they also have the potential to produce high concentrations of greenhouse gases (CO2, CH4 and N2O), as end-products of respiration and intermediate products of denitrification. The hydrological and biogeochemical drivers of streambed C and N cycling, are still insufficiently understood. Here we present results from biogeochemical sampling and tracer experiments in an agricultural sandstone stream in the UK. Nutrient, DOC and greenhouse gas concentrations, as well as d13CCO2, were measured in the streambed sediment in multilevel piezometers, and nutrient concentrations, as well as d15NNO3 and d18ONO3, were measured in Diffusive Equilibrium in Thin-film Gels. Tracer experiments using both conservative (Fluorescein and NaCl) and smart (Resazurin-Resorufin) tracers were performed to determine in-stream metabolism, transient storage and solute transport times in sub-reaches of the stream. Our results show large differences in nutrient and greenhouse gas concentrations between sub-reaches dominated by gravel sediments and those dominated by sandy sediments, as well as seasonally. This suggests temperature, sediment type and residence time are key controls on streambed nutrient cycling and greenhouse gas production. The results of this study have important implications for future greenhouse gas estimates from streams and rivers, particularly as the contribution of sediment greenhouse gas production is recognised as increasingly significant.

Fine sediment trapping in river lateral cavities

NASA Astrophysics Data System (ADS)

Juez, C.; Maechler, G.; Schleiss, A. J.; Franca, M. J.

2016-12-01

River restoration is nowadays a major issue in the field of hydraulics. The natural course and geometry of the rivers have been artificially changed by human activities for different purposes (land gaining, flood protection, agriculture). From a morphologic point of view, channelized rivers often display a straight path and monotonous river banks. This is in contradiction with natural morphology, where a high diversity can be found across the channel path (meanders) and the banks (pools, riffles). One way to restore rivers consist of transforming the artificial banks by adding macro-roughness elements in the lateral river banks (also called cavities and lateral embayments). The creation of irregularities on the banks causes new flow patterns that diversify the river habitat. However, these lateral cavities may be also responsible of the change of the river morphology, since they may trap the fine sediments travelling within the water. This is particularly important in glacier-fed streams such as the upper Rhone River in Switzerland. These are charged with fine sediments resulting from the erosion of the underlying glaciers bottom. The creation of lateral cavities may affect the sediment and morphological equilibrium of the river since these may trap sediments. This work aims to study the influence of the lateral cavities on the transport of fine sediments in the main channel. A set of laboratory experiments were done which covered a wide range of rectangular cavity configurations. Key parameters such as the flow discharge, the aspect ratio of the cavities and the initial sediment concentration were tested. Surface PIV, sediment samples and turbidity temporal records were collected during the experiments. The trapping efficiency of the cavities and the associated flow patterns were analyzed. The resulting conclusions provide a useful information for the future design of river restoration projects.

Sediment quality criteria: A review with recommendations for developing criteria for the Hanford Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Driver, C.J.

1994-05-01

Criteria for determining the quality of liver sediment are necessary to ensure that concentrations of contaminants in aquatic systems are within acceptable limits for the protection of aquatic and human life. Such criteria should facilitate decision-making about remediation, handling, and disposal of contaminants. Several approaches to the development of sediment quality criteria (SQC) have been described and include both descriptive and numerical methods. However, no single method measures all impacts at all times to all organisms (U.S. EPA 1992b). The U.S. EPA`s interest is primarily in establishing chemically based, numerical SQC that are applicable nation-wide (Shea 1988). Of the approachesmore » proposed for SQC development, only three are being considered for numerical SQC on a national level. These approaches include an Equilibrium Partitioning Approach, a site-specific method using bioassays (the Apparent Effects Threshold Approach), and an approach similar to EPA`s water quality criteria (Pavlou and Weston 1984). Although national (or even regional) criteria address a number of political, litigative, and engineering needs, some researchers feel that protection of benthic communities require site-specific, biologically based criteria (Baudo et al. 1990). This is particularly true for areas where complex mixtures of contaminants are present in sediments. Other scientifically valid and accepted procedures for freshwater SQC include a background concentration approach, methods using field or spiked bioassays, a screening level concentration approach, the Apparent Effects Threshold Approach, the Sediment Quality Triad, the International Joint Commission Sediment Assessment Strategy, and the National Status and Trends Program Approach. The various sediment assessment approaches are evaluated for application to the Hanford Reach and recommendations for Hanford Site sediment quality criteria are discussed.« less

Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

NASA Astrophysics Data System (ADS)

Méndez-García, C.; Renteria-Villalobos, M.; García-Tenorio, R.; Montero-Cabrera, M. E.

2014-07-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. 232Th-series, 238U-series, 40K and 137Cs activity concentrations (AC, Bq kg-1) were determined by gamma spectrometry with a high purity Ge detector. 238U and 234U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to 210Pb activities. Results were verified by 137Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High 238U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento - Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) 234U/overflow="scroll">238U and 238U/overflow="scroll">226Ra in sediments have values between 0.9-1.2, showing a behavior close to radioactive equilibrium in the entire basin. 232Th/overflow="scroll">238U, 228Ra/overflow="scroll">226Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.

Biodynamic modeling of PCB uptake by Macoma balthica and Corbicula fluminea from sediment amended with activated carbon

USGS Publications Warehouse

McLeod, Pamela B.; Luoma, S.N.; Luthy, R.G.

2008-01-01

Activated carbon amendment was assessed in the laboratory as a remediation strategy for freshwater sediment contaminated with polychlorinated biphenyls (PCBs) from the Grasse River (near Massena, NY). Three end points were evaluated: aqueous equilibrium PCB concentration, uptake into semipermeable membrane devices (SPMDs), and 28-day bioaccumulation in the clam Corbicula fluminea. PCB uptake by water, SPMDs, and clams followed similar trends, with reductions increasing as a function of carbon dose. Average percent reductions in clam tissue PCBs were 67, 86, and 95% for activated carbon doses of 0.7, 1.3, and 2.5% dry wt, respectively. A biodynamic model that incorporates sediment geochemistry and dietary and aqueous uptake routes was found to agree well with observed uptake by C. fluminea in our laboratory test systems. Results from this study were compared to 28-day bioaccumulation experiments involving PCB-contaminated sediment from Hunters Point Naval Shipyard (San Francisco Bay, CA) and the clam Macoma balthica. Due to differences in feeding strategy, M. balthica deposit-feeds whereas C. fluminea filter-feeds, the relative importance of the aqueous uptake route is predicted to be much higher for C. fluminea than for M. balthica. Whereas M. balthica takes up approximately 90% of its body burden through sediment ingestion, C. fluminea only accumulates approximately 45% via this route. In both cases, results strongly suggest that it is the mass transfer of PCBs from native sediment to added carbon particles, not merely reductions in aqueous PCB concentrations, that effectively reduces PCB bioavailability and uptake by sediment-dwelling organisms. ?? 2008 American Chemical Society.

Organic Matter Polymerization by Disulfide Bonding Near the Chemocline in Cariaco Basin

NASA Astrophysics Data System (ADS)

Raven, M. R.; Adkins, J. F.; Sessions, A. L.

2013-12-01

The preservation of organic carbon in sediments as kerogen is an essential pathway in the global carbon cycle, but the chemical reactions involved in kerogen formation remain poorly understood. Previous researchers have found that many sediments deposited under euxinic conditions contain sulfur-bearing non-polar lipids as well as disulfide bonds among lipid and carbohydrate monomers. It remains unclear, however, when during organic matter decomposition and diagenesis these different sulfur-bearing structures form, and how different environmental conditions affect the extent of organic matter sulfurization. We investigate organic sulfurization processes armed with a technique for measuring the sulfur-isotopic compositions of individual organosulfur compounds by coupled gas chromatography - inductively coupled plasma mass spectrometry. Organic compounds were extracted from sediments and water column sediment traps from Cariaco Basin, a euxinic basin in the Caribbean Sea. We measured the sulfur-isotopic compositions of both non-polar lipids and of derivatized disulfide-bound compounds from eight sediment trap profiles and a six-meter-long sediment core. In Cariaco Basin, lipid sulfurization processes appear to begin near the chemocline and continue in sediments on timescales of thousands of years. Slow diagenetic sulfurization in sediments produces lipid monomers with sulfur atoms in ring structures that are 34S-depleted relative to coexisting dissolved sulfide. Lipid monomers become progressively enriched in 34S over time, indicating ongoing formation coinciding with an increase in the amount of total sulfur in bulk kerogen. One of the most abundant monomers observed in Cariaco sediments, a phytol-related thiophene, is also produced intermittently near the chemocline. Phytol thiophene δ34S values in sediment traps are similar to those observed in shallow Cariaco sediments except during occasional ';enrichment events,' when phytol thiophene δ34S values increase to as high as -2‰. In contrast, disulfide bonding appears to affect both lipids and carbohydrates and occur exclusively at the chemocline on very short timescales of days to weeks. In both the water column and the sediments, the sulfur isotope ratios of disulfide-bound monosaccharides are dramatically 34S-enriched relative to dissolved sulfide at the chemocline (~-30‰), ranging from -11‰ to +9‰. Disulfide-bound phytenes, which likely derive from the same precursor compounds as phytol thiophenes, were observed in only a few of the sediment trap extracts and have sulfur-isotopic compositions near +4.5‰. These 34S-enriched compositions indicate that the source of sulfur for rapid disulfide bonding may be an intermediate sulfur species that is not in isotopic equilibrium with dissolved sulfide. Significantly, δ34S values for disulfide-bound compounds in Cariaco Basin appear to be set at the chemocline and stable during subsequent diagenesis, opening the possibility that organic sulfur isotopes may archive information about environmental conditions at the chemocline in low-maturity sediments. Disulfide bonding does not, however, appear to be the major process driving slower diagenetic sulfur incorporation into kerogen. Compound-specific organic sulfur isotope analysis makes it possible to distinguish the products of different lipid and carbohydrate sulfurization processes for the first time.

Estimates of Sediment Load Prior to Dam Removal in the Elwha River, Clallam County, Washington

USGS Publications Warehouse

Curran, Christopher A.; Konrad, Christopher P.; Higgins, Johnna L.; Bryant, Mark K.

2009-01-01

Years after the removal of the two dams on the Elwha River, the geomorphology and habitat of the lower river will be substantially influenced by the sediment load of the free-flowing river. To estimate the suspended-sediment load prior to removal of the dams, the U.S. Geological Survey collected suspended-sediment samples during water years 2006 and 2007 at streamflow-gaging stations on the Elwha River upstream of Lake Mills and downstream of Glines Canyon Dam at McDonald Bridge. At the gaging station upstream of Lake Mills, discrete samples of suspended sediment were collected over a range of streamflows including a large peak in November 2006 when suspended-sediment concentrations exceeded 7,000 milligrams per liter, the highest concentrations recorded on the river. Based on field measurements in this study and from previous years, regression equations were developed for estimating suspended-sediment and bedload discharge as a function of streamflow. Using a flow duration approach, the average total annual sediment load at the gaging station upstream of Lake Mills was estimated at 327,000 megagrams with a range of uncertainty of +57 to -34 percent (217,000-513,000 megagrams) at the 95 percent confidence level; 77 percent of the total was suspended-sediment load and 23 percent was bedload. At the McDonald Bridge gaging station, daily suspended-sediment samples were obtained using an automated pump sampler, and concentrations were combined with the record of streamflow to calculate daily, monthly, and annual suspended-sediment loads. In water year 2006, an annual suspended-sediment load of 49,300 megagrams was determined at the gaging station at McDonald Bridge, and a load of 186,000 megagrams was determined upstream at the gaging station upstream of Lake Mills. In water year 2007, the suspended-sediment load was 75,200 megagrams at McDonald Bridge and 233,000 megagrams upstream of Lake Mills. The large difference between suspended-sediment loads at both gaging stations shows the extent of sediment trapping by Lake Mills, and a trap efficiency of 0.86 was determined for the reservoir. Pre-dam-removal estimates of suspended-sediment load and sediment-discharge relations will help planners monitor geomorphic and habitat changes in the river as it reaches a dynamic equilibrium following the removal of dams.

Vertical suspsended sediment fluxes observed from ocean gliders

NASA Astrophysics Data System (ADS)

Merckelbach, Lucas; Carpenter, Jeffrey

2016-04-01

Many studies trying to understand a coastal system in terms of sediment transport paths resort to numerical modelling - combining circulation models with sediment transport models. Two aspects herein are crucial: sediment fluxes across the sea bed-water column interface, and the subsequent vertical mixing by turbulence. Both aspects are highly complex and have relatively short time scales, so that the processes involved are implemented in numerical models as parameterisations. Due to the effort required to obtain field observations of suspended sediment concentrations (and other parameters), measurements are scarce, which makes the development and tuning of parameterisations a difficult task. Ocean gliders (autonomous underwater vehicles propelled by a buoyancy engine) provide a platform complementing more traditional methods of sampling. In this work we present observations of suspended sediment concentration (SSC) and dissipation rate taken by two gliders, each equipped with optical sensors and a microstructure sensor, along with current observations from a bottom mounted ADCP, all operated in the German Bight sector of the North Sea in Summer 2014. For about two weeks of a four-week experiment, the gliders were programmed to fly in a novel way as Lagrangian profilers to water depths of about 40 m. The benefit of this approach is that the rate of change of SSC - and other parameters - is local to the water column, as opposed to an unknown composition of temporal and spatial variability when gliders are operated in the usual way. Therefore, vertical sediment fluxes can be calculated without the need of the - often dubious - assumption that spatial variability can be neglected. During the experiment the water column was initially thermally stratified, with a cross-pycnocline diffusion coefficient estimated at 7\\cdot10-5 m2 s-1. Halfway through the experiment the remnants of tropical storm Bertha arrived at the study site and caused a complete mixing of the water column. An analysis of the data showed that resuspension and deposition were solely tidally-driven and in equilibrium prior to the arrival of the storm, with an averaged resuspension rate of 3-4 g m-2 s-1. During the storm the effect of surface waves increased the resuspension rate by an order of magnitude. The data suggest that after the passing of the storm, when the tide was the main driver again, resuspension rates are generally higher than before the storm. This provides a further indication that although a (Summer) storm might be a short-term event, its effects on sediment transport may be felt on much longer time scales.

Bottom currents and sediment waves on a shallow carbonate shelf, Northern Carnarvon Basin, Australia

NASA Astrophysics Data System (ADS)

Belde, Johannes; Reuning, Lars; Back, Stefan

2017-04-01

The modern seafloor of the Australian Northwest Shelf between Exmouth and Dampier was analyzed for large scale sedimentary bedforms on 3D seismic reflection data. The Carnarvon MegaSurvey of Petroleum Geo-Services (PGS), a merged dataset of multiple industrial 3D seismic reflection surveys with a total size of 49,717 km2, offers an extensive view of the continental shelf, slope and rise of the Northern Carnarvon Basin. Over the shelf two fields of large scale sediment waves were observed in water depths between 55-130 m, where the seafloor may be influenced by different processes including internal waves, tides and storms. Based on the dimensions and orientations of the sediment waves the dominant direction and approximate strength of local bottom currents could be estimated. Information on local sediment grain-size distribution was provided by the auSEABED database allowing a classification of the observed sediment waves into sand- or mudwaves. The first sediment wave field is positioned northwest of the Montebello Islands where the shelf is comparatively narrow and local sediment is mainly sand-sized. It most likely formed by increased bottom currents induced by the diversion of tidal flows around the islands. The second sediment wave field is located north of the Serrurier and Bessieres Islands within a local seafloor depression. Local sediments are poorly sorted, containing significant amounts of mud and gravel in addition to the mainly sand-sized grains. The coarser sediment fraction could have been reworked to sandwaves by cyclone-induced bottom currents. Alternatively, the finer sediment fraction could form mudwaves shaped by less energetic along-slope oriented currents in the topographic depression. The sediment waves consist partially of carbonate grains such as ooids and peloids that formed in shallow water during initial stages of the post glacial sea-level rise. These stranded carbonate grains thus formed in a different environment than the sediment waves in which they were redeposited. In fossil examples of similar high-energy ramp systems this possible out-of-equilibrium relationship between grains and bedforms has to be taken into account for the interpretation of the depositional environment.

A modified experimental setup for sedimentation equilibrium experiments with gels. Part 2: Technical developments.

PubMed

Cölfen, H; Borchard, W

1994-06-01

This part of the paper trilogy describes technical developments for an efficient experimental setup to investigate gels with equilibrium analytical ultracentrifugation. New 10-channel centerpieces for the Schlieren optics, a new programmable multiplexer, a modified Schlieren optical system, and a photo pickup with impulse transformer are introduced as major developments. Also, some new centerpieces suitable for equilibrium experiments with solutions using the Rayleigh interference and the uv-absorption optics are presented. These centerpieces allow the investigation of 10, 12, or even 26 samples per centerpiece. The problem to find suitable materials for cell centerpieces and windows in the case of adhering samples is discussed for the system gelatin/water. A phase volume calculation for circular sample channels as a correction for the case of broadened menisci is presented. The method described allows an accurate measurement of up to 70 samples simultaneously in an equilibrium experiment if the 8-hole rotor presented in part 1 of the trilogy is used. The number of samples is sufficient to characterize a gel/solvent system in the experimentally accessible range under identical conditions, which is not possible by means of any of the methods known before. All parts described are also applicable for the investigation of solutions.

Effects of organic carbon supply rates on uranium mobility in a previously bioreduced contaminated sediment.

PubMed

Wan, Jiamin; Tokunaga, Tetsu K; Kim, Yongman; Brodie, Eoin; Daly, Rebecca; Hazen, Terry C; Firestone, Mary K

2008-10-15

Bioreduction-based strategies for remediating uranium (U)-contaminated sediments face the challenge of maintaining the reduced status of U for long times. Because groundwater influxes continuously bring in oxidizing terminal electron acceptors (O2, NO3(-)), it is necessary to continue supplying organic carbon (OC) to maintain the reducing environment after U bioreduction is achieved. We tested the influence of OC supply rates on mobility of previously microbial reduced uranium U(IV) in contaminated sediments. We found that high degrees of U mobilization occurred when OC supply rates were high, and when the sediment still contained abundant Fe(III). Although 900 days with low levels of OC supply minimized U mobilization, the sediment redox potential increased with time as did extractable U(VI) fractions. Molecular analyses of total microbial activity demonstrated a positive correlation with OC supply and analyses of Geobacteraceae activity (RT-qPCR of 16S rRNA) indicated continued activity even when the effluent Fe(II) became undetectable. These data support our hypothesis on the mechanisms responsible for remobilization of U under reducing conditions; that microbial respiration caused increased (bi)carbonate concentration and formation of stable uranyl carbonate complexes, thereby shifted U(IV)/U(VI) equilibrium to more reducing potentials. The data also suggested that low OC concentrations could not sustain the reducing condition of the sediment for much longer time. Bioreduced U(IV) is not sustainable in an oxidizing environment for a very long time.

Influence of competing inorganic cations on the ion exchange equilibrium of the monovalent organic cation metoprolol on natural sediment.

PubMed

Niedbala, Anne; Schaffer, Mario; Licha, Tobias; Nödler, Karsten; Börnick, Hilmar; Ruppert, Hans; Worch, Eckhard

2013-02-01

The aim of this study was to systematically investigate the influence of the mono- and divalent inorganic ions Na(+) and Ca(2+) on the sorption behavior of the monovalent organic cation metoprolol on a natural sandy sediment at pH=7. Isotherms for the beta-blocker metoprolol were obtained by sediment-water batch tests over a wide concentration range (1-100000 μg L(-1)). Concentrations of the competing inorganic ions were varied within freshwater relevant ranges. Data fitted well with the Freundlich sorption model and resulted in very similar Freundlich exponents (n=0.9), indicating slightly non-linear behavior. Results show that the influence of Ca(2+) compared to Na(+) is more pronounced. A logarithmic correlation between the Freundlich coefficient K(Fr) and the concentration or activity of the competing inorganic ions was found allowing the prediction of metoprolol sorption on the investigated sediment at different electrolyte concentrations. Additionally, the organic carbon of the sediment was completely removed for investigating the influence of organic matter on the sorption of metoprolol. The comparison between the experiments with and without organic carbon removal revealed no significant contribution of the organic carbon fraction (0.1%) to the sorption of metoprolol on the in this study investigated sediment. Results of this study will contribute to the development of predictive models for the transport of organic cations in the subsurface. Copyright © 2012 Elsevier Ltd. All rights reserved.

Benthic phosphorus regeneration in the Potomac River Estuary

USGS Publications Warehouse

Callender, E.

1982-01-01

The flux of dissolved reactive phosphate from Potomac riverine and estuarine sediments is controlled by processes occurring at the water-sediment interface and within surficial sediment. In situ benthic fluxes (0.1 to 2.0 mmoles m-2 day-1) are generally five to ten times higher than calculated diffusive fluxes (0.020 to 0.30 mmoles m-2 day-1). The discrepancy between the two flux estimates is greatest in the transition zone (river mile 50 to 70) and is attributd to macrofaunal irrigation. Both in situ and diffusive fluxes of dissolved reactive phosphate from Potomac tidal river sediments are low while those from anoxic lower estuarine sediments are high. The net accumulation rate of phosphorus in benthic sediment exhibits an inverse pattern. Thus a large fraction of phosphorus is retained by Potomac tidal river sediments, which contain a surficial oxidized layer and oligochaete worms tolerant of low oxygen conditions, and a large fraction of phosphorus is released from anoxic lower estuary sediments. Tidal river sediment pore waters are in equilibrium with amorphous Fe (OH)3 while lower estuary pore waters are significantly undersaturated with respect to this phase. Benthic regeneration of dissolved reactive phosphorus is sufficient to supply all the phosphorus requirements for net primary production in the lower tidal river and transition-zone waters of the Potomac River Estuary. Benthic regeneration supplies approximately 25% as much phosphorus as inputs from sewage treatment plants and 10% of all phosphorus inputs to the tidal Potomac River. When all available point source phosphorus data are put into a steady-state conservation of mass model and reasonable coefficients for uptake of dissolved phosphorus, remineralization of particulate phosphorus, and sedimentation of particulate phosphorus are used in the model, a reasonably accurate simulation of dissolved and particulate phosphorus in the water column is obtained for the summer of 1980. ?? 1982 Dr W. Junk Publishers.

Simulation of acid water movement in canals

NASA Astrophysics Data System (ADS)

Van Truong, To; Tat Dac, Nguyen; Ngoc Phienc, Huynh

1996-05-01

An attempt to tackle the problem of the propagation of acid water in canals is described, and a mathematical model to simulate the acid water movement is developed, in which the jurbanite equilibrium is found to prevail. The processes of settling owing to sedimentation, precipitation and redissolution have been considered in the modelling. Data available from Tan Thanh, in the Plain of Reeds of the Mekong Delta in Viet Nam, are used as a case study.

Model-based analysis of coupled equilibrium-kinetic processes: indirect kinetic studies of thermodynamic parameters using the dynamic data.

PubMed

Emami, Fereshteh; Maeder, Marcel; Abdollahi, Hamid

2015-05-07

Thermodynamic studies of equilibrium chemical reactions linked with kinetic procedures are mostly impossible by traditional approaches. In this work, the new concept of generalized kinetic study of thermodynamic parameters is introduced for dynamic data. The examples of equilibria intertwined with kinetic chemical mechanisms include molecular charge transfer complex formation reactions, pH-dependent degradation of chemical compounds and tautomerization kinetics in micellar solutions. Model-based global analysis with the possibility of calculating and embedding the equilibrium and kinetic parameters into the fitting algorithm has allowed the complete analysis of the complex reaction mechanisms. After the fitting process, the optimal equilibrium and kinetic parameters together with an estimate of their standard deviations have been obtained. This work opens up a promising new avenue for obtaining equilibrium constants through the kinetic data analysis for the kinetic reactions that involve equilibrium processes.

Accelerated relative sea-level rise and rapid coastal erosion: Testing a causal relationship for the Louisiana barrier islands

USGS Publications Warehouse

List, J.H.; Sallenger, A.H.; Hansen, M.E.; Jaffe, B.E.

1997-01-01

The role of relative sea-level rise as a cause for the rapid erosion of Louisiana's barrier island coast is investigated through a numerical implementation of a modified Bruun rule that accounts for the low percentage of sand-sized sediment in the eroding Louisiana shoreface. Shore-normal profiles from 150 km of coastline west of the Mississippi delta are derived from bathymetric surveys conducted during the 1880s. 1930s and 1980s. An RMS difference criterion is employed to test whether an equilibrium profile form is maintained between survey years. Only about half the studied profiles meet the equilibrium Criterion this represents a significant limitation on the potential applicability of the Bruun rule. The profiles meeting the equilibrium criterion, along with measured rates of relative sea-level rise, are used to hindcast shoreline retreat rates at 37 locations within the study area. Modeled and observed shoreline retreat rates show no significant correlation. Thus in terms of the Bruun approach relative sea-level rise has no power for hindcasting (and presumably forecasting) rates of coastal erosion for the Louisiana barrier islands.

Floating liquid phase in sedimenting colloid-polymer mixtures.

PubMed

Schmidt, Matthias; Dijkstra, Marjolein; Hansen, Jean-Pierre

2004-08-20

Density functional theory and computer simulation are used to investigate sedimentation equilibria of colloid-polymer mixtures within the Asakura-Oosawa-Vrij model of hard sphere colloids and ideal polymers. When the ratio of buoyant masses of the two species is comparable to the ratio of differences in density of the coexisting bulk (colloid) gas and liquid phases, a stable "floating liquid" phase is found, i.e., a thin layer of liquid sandwiched between upper and lower gas phases. The full phase diagram of the mixture under gravity shows coexistence of this floating liquid phase with a single gas phase or a phase involving liquid-gas equilibrium; the phase coexistence lines meet at a triple point. This scenario remains valid for general asymmetric binary mixtures undergoing bulk phase separation.

Numerical modeling of sorption kinetics of organic compounds to soil and sediment particles

NASA Astrophysics Data System (ADS)

Wu, Shian-chee; Gschwend, Phillip M.

1988-08-01

A numerical model is developed to simulate hydrophobic organic compound sorption kinetics, based on a retarded intraaggregate diffusion conceptualization of this solid-water exchange process. This model was used to ascertain the sensitivity of the sorption process for various sorbates to nonsteady solution concentrations and to polydisperse soil or sediment aggregate particle size distributions. Common approaches to modeling sorption kinetics amount to simplifications of our model and appear justified only when (1) the concentration fluctuations occur on a time scale which matches the sorption timescale of interest and (2) the particle size distribution is relatively narrow. Finally, a means is provided to estimate the extent of approach of a sorbing system to equilibrium as a function of aggregate size, chemical diffusivity and hydrophobicity, and system solids concentration.

Occurrence, distribution, and transport of pesticides, trace elements, and selected inorganic constituents into the Salton Sea Basin, California, 2001-2002

USGS Publications Warehouse

LeBlanc, Lawrence A.; Schroeder, Roy A.; Orlando, James L.; Kuivila, Kathyrn M.

2004-01-01

A study of pesticide distribution and transport within the Salton Sea Basin, California, was conducted from September 2001 to October 2002. Sampling for the study was done along transects for the three major rivers that flow into the Salton Sea Basin: the New and Alamo Rivers at the southern end of the basin and the Whitewater River at the northern end. Three stations were established on each river: an outlet station approximately 1 mile upstream of the river discharge, a near-shore station in the river delta, and off-shore station in the Salton Sea. Water and suspended and bed sediments were collected at each station in October 2001, March-April 2002, and September 2002, coinciding with peak pesticide applications in the fall and spring. Fourteen current-use pesticides were detected in the water column. Concentrations of dissolved pesticides typically decreased from the outlets to the sea in all three rivers, consistent with the off-shore transport of pesticides from the rivers to the sea. Dissolved concentrations ranged from the limits of detection to 151 nanograms per liter (ng/L); however, diazinon, eptam (EPTC), and malathion were detected at much higher concentrations (940?3,830 ng/L) at the New and Alamo River outlet and near-shore stations. Concentrations of carbaryl, dacthal, diazinon, and eptam were higher during the two fall sampling periods, whereas concentrations of atrazine, carbofuran, and trifluralin were higher during the spring. Current-use pesticides also were detected on suspended and bed sediments in concentrations ranging from method detection limits to 106 ng/g (nanograms per gram). Chlorpyrifos, dacthal, eptam, trifluralin, and DDE were the most frequently detected pesticides on sediments from all three rivers. The number and concentrations of pesticides associated with suspended sediments frequently were similar for the river outlet and near-shore sites, consistent with the downstream transport of sediment-associated pesticides out of the rivers. Seasonal trends in pesticide concentration were similar to those for dissolved concentrations in fall 2001 and spring 2002, but not in fall 2002. Generally, the pesticides detected in the suspended sediments were the same pesticides detected in the bed sediments, and concentrations were similar, especially at the Alamo River outlet site in spring 2002 and fall 2002. Pesticides generally were not detected in sediments from the off-shore sites; however, the samples from these sites also had greater incidences of matrix interference during analysis. Sediment-associated pesticide concentrations were above equilibrium in water, suggesting a bound fraction of sediment-associated pesticides that are resistant to desorption. Concentrations of trace elements and other inorganic constituents in suspended sediments collected during the fall 2001 followed expected trends with dilution of river-derived minerals owing to highly organic autochthonous production within the Salton Sea Basin. However, calculation of enrichment ratios provided evidence for the bioconcentration of several trace elements, notably selenium in the off-shore biota.

Implications of water supply for indigenous Americans during Holocene ardity phases on the Southern High Plains, USA

USGS Publications Warehouse

Wood, W.W.; Stokes, S.; Rich, J.

2002-01-01

Springs in the 40 to 50 large lake basins (>15 km2) on the southern portion of the Southern High Plains (SHP) were active during periods of aridity in the Holocene when there may have been human habitation of the area. Eolian erosion of the lake floors and lunette accretion occurred as groundwater levels declined in response to decreased groundwater recharge. The declining lake floor associated with eolian erosion allowed groundwater evaporative discharge to continue, thus maintaining a groundwater gradient toward the lake. This hydrologic condition was favorable for a relatively continuous spring discharge to the lake, independent of the elevation of the lake floor. To evaluate the postulated dynamic equilibrium critical to this conclusion, 17 optically stimulated ages were determined from a 17.7-m deep core of a lunette adjacent to Double Lakes, Texas (33??13???15???N, 101??54???08???W). The core yielded sediment accumulation dates of 11,500 ?? 1100, 6500 ?? 700, and 4900 ?? 500 yr B.P., corresponding broadly with periods of aridity known from other evidence. Based on analysis of this lunette, it is concluded that springs in Double Lakes basin probably existed throughout the Holocene with discharges similar to those observed historically. We assumed that similar dynamic equilibrium existed in the other large lake basins in the SHP and that these springs could have provided a continuous source of water for indigenous peoples during periods of prolonged aridity. The dynamic equilibrium that is proposed in this study is applicable not only to other arid and semiarid geographic areas with wind-erodible material but also over different geologic times. ?? 2002 University of Washington.

METHODS FOR THE DETERMINATION OF TOTAL ORGANIC ...

EPA Pesticide Factsheets

Organic matter in soils and sediments is widely distributed over the earth's surface occurring in almost all terrestrial and aquatic environments (Schnitzer, 1978). Soils and sediments contain a large variety of organic materials ranging from simple sugars and carbohydrates to the more complex proteins, fats, waxes, and organic acids. Important characteristics of the organic matter include their ability to: form water-soluble and water- insoluble complexes with metal ions and hydrous oxides; interact with clay minerals and bind particles together; sorb and desorb both naturally-occurring and anthropogenically-introduced organic compounds; absorb and release plant nutrients; and hold water in the soil environment. As a result of these characteristics, the determination of total organic carbon (a measure of one of the chemical components of organic matter that is often used as an indicator of its presence in a soil or sediment) is an essential part of any site characterization since its presence or absence can markedly influence how chemicals will react in the soil or sediment. Soil and sediment total organic carbon (TOC) determinations are typically requested with contaminant analyses as part of an ecological risk assessment data package. TOC contents may be used qualitatively to assess the nature of the sampling location (e.g., was it a depositional area) or may be used to normalize portions of the analytical chemistry data set (e.g., equilibrium partitioning).

The oceanic budgets of nickel and zinc isotopes: the importance of sulfidic environments as illustrated by the Black Sea

PubMed Central

Little, Susan H.; Archer, Corey; Cameron, Vyllinniskii; Andersen, Morten B.; Rijkenberg, Micha J. A.; Lyons, Timothy W.

2016-01-01

Isotopic data collected to date as part of the GEOTRACES and other programmes show that the oceanic dissolved pool is isotopically heavy relative to the inputs for zinc (Zn) and nickel (Ni). All Zn sinks measured until recently, and the only output yet measured for Ni, are isotopically heavier than the dissolved pool. This would require either a non-steady-state ocean or other unidentified sinks. Recently, isotopically light Zn has been measured in organic carbon-rich sediments from productive upwelling margins, providing a potential resolution of this issue, at least for Zn. However, the origin of the isotopically light sedimentary Zn signal is uncertain. Cellular uptake of isotopically light Zn followed by transfer to sediment does not appear to be a quantitatively important process. Here, we present Zn and Ni isotope data for the water column and sediments of the Black Sea. These data demonstrate that isotopically light Zn and Ni are extracted from the water column, probably through an equilibrium fractionation between different dissolved species followed by sequestration of light Zn and Ni in sulfide species to particulates and the sediment. We suggest that a similar, non-quantitative, process, operating in porewaters, explains the Zn data from organic carbon-rich sediments. This article is part of the themed issue ‘Biological and climatic impacts of ocean trace element chemistry’. PMID:29035259

Dispersal of river sediment in the Southern California Bight

USGS Publications Warehouse

Warrick, J.A.; Farnsworth, K.L.

2009-01-01

The rivers of Southern California deliver episodic pulses of water, sediment, nutrients, and pollutants to the region's coastal waters. Although river-sediment dispersal is observed in positively buoyant (hypopycnal) turbid plumes extending tens of kilometers from river mouths, very little of the river sediment is found in these plumes. Rather, river sediment settles quickly from hypopycnal plumes to the seabed, where transport is controlled by bottom-boundary layer processes, presumably including fluid-mud (hyperpycnal) gravity currents. Here we investigate the geographical patterns of river-sediment dispersal processes by examining suspended-sediment concentrations and loads and the continental shelf morphology offshore river mouths. Throughout Southern California, river sediment is discharged at concentrations adequately high to induce enhanced sediment settling, including negative buoyancy. The rivers draining the Western Transverse Range produce suspended-sediment concentrations that are orders of magnitude greater than those in the urbanized region and Peninsular Range to the south, largely due to differences in sediment yield. The majority of sediment discharge from the Santa Clara River and Calleguas Creek occurs above the theoretical negative buoyancy concentration (>40 g/l). These rivers also produce event sediment loading as great as the Eel River, where fluid-mud gravity currents are observed. The continental shelf of Southern California has variable morphology, which influences the ability to transport via gravity currents. Over half of the rivers examined are adjacent to shelf slopes greater than 0.01, which are adequately steep to sustain auto-suspending gravity currents across the shelf, and have little (<10 m) Holocene sediment accumulation. Shelf settings of the Ventura, Santa Clara, and Tijuana Rivers are very broad and low sloped (less than 0.004), which suggests that fluid-mud gravity currents could transport across these shelves, albeit slowly (??10 cm/s) and only with adequate wave-generated shear stress and sediment loading. Calleguas Creek is unique in that it discharges directly into a steepsloped canyon (greater than 0.1) that should allow for violent auto-suspending gravity currents. In light of this, only one shelf setting-the Santa Clara and Ventura-has considerable Holocene sediment accumulation (exceeding 60 m), and here we show that the morphology of this shelf is very similar to an equilibrium shape predicted by gravity-current sediment transport. Thus, we conclude that a wide distribution of river-shelf settings occur in the Southern California Bight, which will directly influence sediment dispersal processes-both dilute suspended and gravity-current transport-and sediment-accumulation patterns. ?? 2009 The Geological Society of America.

Reciprocal interactions between fluvial processes and riparian plants at multiple scales: ecogeomorphic feedbacks drive coevolution of floodplain morphology and vegetation communities

NASA Astrophysics Data System (ADS)

Stella, J. C.; Kui, L.; Diehl, R. M.; Bywater-Reyes, S.; Wilcox, A. C.; Shafroth, P. B.; Lightbody, A.

2017-12-01

Fluvial forces interact with woody riparian plants in complex ways to influence the coevolution of river morphology and floodplain plant communities. Here, we report on an integrated suite of multi-disciplinary studies that contrast the responses of plants with different morphologies, tamarisk (Tamarix spp.) and cottonwood (Populus fremontii) in terms of (1) differences in vulnerability to scour and burial during floods; (2) interactions and feedbacks between plants and river morphodynamics; and (3) long-term coevolution of river floodplains and riparian communities following flow regulation from dams. The focus of these studies is sand-bed rivers in arid-land regions where invasion by tamarisk has strongly influenced riverine plant communities and geomorphic processes. We complemented a suite of field-scale flume experiments using live seedlings to quantify the initial stages of plant-river interactions with an analysis of long-term vegetation and geomorphic changes along the dammed Bill Williams River (AZ, USA) using time-series air photographs. Vegetation-fluvial interactions varied with plant characteristics, river hydraulics and sediment conditions, across the wide range of scales we investigated. In the flume studies, tamarisk's denser crowns and stiffer stems induced greater sedimentation compared to cottonwood. This resulted in tamarisk's greater mortality from burial as small seedlings under sediment equilibrium conditions but higher relative survival in larger floods under sediment deficit scenarios, in which more cottonwoods were lost to root scour. Sediment deficit conditions, as occurs downstream of dams, induced both greater scour and greater plant loss. With larger size and at higher densities, plants' vulnerability diminished due to greater root anchoring and canopy effects on hydraulics. At the corridor scale, we observed a pattern of plant encroachment during five decades of flow regulation, in which channel narrowing and simplification was more associated with tamarisk-dominated reaches compared with native woodlands. Together, these multi-scale plant-river dynamics help explain the persistence of tamarisk along regulated rivers where catastrophic floods have been reduced and also highlight limitations of using flow releases for invasive species management.

Unravelling earth flow dynamics with 3-D time series derived from UAV-SfM models

NASA Astrophysics Data System (ADS)

Clapuyt, François; Vanacker, Veerle; Schlunegger, Fritz; Van Oost, Kristof

2017-12-01

Accurately assessing geo-hazards and quantifying landslide risks in mountainous environments are gaining importance in the context of the ongoing global warming. For an in-depth understanding of slope failure mechanisms, accurate monitoring of the mass movement topography at high spatial and temporal resolutions remains essential. The choice of the acquisition framework for high-resolution topographic reconstructions will mainly result from the trade-off between the spatial resolution needed and the extent of the study area. Recent advances in the development of unmanned aerial vehicle (UAV)-based image acquisition combined with the structure-from-motion (SfM) algorithm for three-dimensional (3-D) reconstruction make the UAV-SfM framework a competitive alternative to other high-resolution topographic techniques. In this study, we aim at gaining in-depth knowledge of the Schimbrig earthflow located in the foothills of the Central Swiss Alps by monitoring ground surface displacements at very high spatial and temporal resolution using the efficiency of the UAV-SfM framework. We produced distinct topographic datasets for three acquisition dates between 2013 and 2015 in order to conduct a comprehensive 3-D analysis of the landslide. Therefore, we computed (1) the sediment budget of the hillslope, and (2) the horizontal and (3) the three-dimensional surface displacements. The multitemporal UAV-SfM based topographic reconstructions allowed us to quantify rates of sediment redistribution and surface movements. Our data show that the Schimbrig earthflow is very active, with mean annual horizontal displacement ranging between 6 and 9 m. Combination and careful interpretation of high-resolution topographic analyses reveal the internal mechanisms of the earthflow and its complex rotational structure. In addition to variation in horizontal surface movements through time, we interestingly showed that the configuration of nested rotational units changes through time. Although there are major changes in the internal structure of the earthflow in the 2013-2015 period, the sediment budget of the drainage basin is nearly in equilibrium. As a consequence, our data show that the time lag between sediment mobilization by landslides and enhanced sediment fluxes in the river network can be considerable.

Mountain glaciation and paleoclimate reconstruction in the Picos de Europa (Iberian Peninsula, SW Europe)

NASA Astrophysics Data System (ADS)

Serrano, Enrique; González-Trueba, Juan José; González-García, María

2012-09-01

Geomorphic mapping and stratigraphic analysis of a lake core document the late Quaternary glacial history of the Central and Eastern Massifs of the Picos de Europa, northwestern Spain. The distribution of glacial deposits indicates that at their most advanced positions glaciers occupied 9.1 km2, extended as far as 7 km down-valley and had an estimated equilibrium-line altitude (ELA) ranging between 1666 and 1722 m. Radiocarbon dating of sediment deposited in a lake dammed by moraines of this advance show that the maximum glacial extent was prior to 35,280 ± 440 cal yr BP. This advance was followed by two subsequent but less extensive late Pleistocene advances, recorded by multiple moraines flanking both massifs and sedimentary characteristics in the lake deposits. The last recognized glacial episode is the 19th-century maximum extent of small Little Ice Age glaciers in the highest cirques above 2200 m.

Diverse origins of Arctic and Subarctic methane point source emissions identified with multiply-substituted isotopologues

NASA Astrophysics Data System (ADS)

Douglas, P. M. J.; Stolper, D. A.; Smith, D. A.; Walter Anthony, K. M.; Paull, C. K.; Dallimore, S.; Wik, M.; Crill, P. M.; Winterdahl, M.; Eiler, J. M.; Sessions, A. L.

2016-09-01

Methane is a potent greenhouse gas, and there are concerns that its natural emissions from the Arctic could act as a substantial positive feedback to anthropogenic global warming. Determining the sources of methane emissions and the biogeochemical processes controlling them is important for understanding present and future Arctic contributions to atmospheric methane budgets. Here we apply measurements of multiply-substituted isotopologues, or clumped isotopes, of methane as a new tool to identify the origins of ebullitive fluxes in Alaska, Sweden and the Arctic Ocean. When methane forms in isotopic equilibrium, clumped isotope measurements indicate the formation temperature. In some microbial methane, however, non-equilibrium isotope effects, probably related to the kinetics of methanogenesis, lead to low clumped isotope values. We identify four categories of emissions in the studied samples: thermogenic methane, deep subsurface or marine microbial methane formed in isotopic equilibrium, freshwater microbial methane with non-equilibrium clumped isotope values, and mixtures of deep and shallow methane (i.e., combinations of the first three end members). Mixing between deep and shallow methane sources produces a non-linear variation in clumped isotope values with mixing proportion that provides new constraints for the formation environment of the mixing end-members. Analyses of microbial methane emitted from lakes, as well as a methanol-consuming methanogen pure culture, support the hypothesis that non-equilibrium clumped isotope values are controlled, in part, by kinetic isotope effects induced during enzymatic reactions involved in methanogenesis. Our results indicate that these kinetic isotope effects vary widely in microbial methane produced in Arctic lake sediments, with non-equilibrium Δ18 values spanning a range of more than 5‰.

Nonequilibrium Thermodynamics of Hydrate Growth on a Gas-Liquid Interface

NASA Astrophysics Data System (ADS)

Fu, Xiaojing; Cueto-Felgueroso, Luis; Juanes, Ruben

2018-04-01

We develop a continuum-scale phase-field model to study gas-liquid-hydrate systems far from thermodynamic equilibrium. We design a Gibbs free energy functional for methane-water mixtures that recovers the isobaric temperature-composition phase diagram under thermodynamic equilibrium conditions. The proposed free energy is incorporated into a phase-field model to study the dynamics of hydrate formation on a gas-liquid interface. We elucidate the role of initial aqueous concentration in determining the direction of hydrate growth at the interface, in agreement with experimental observations. Our model also reveals two stages of hydrate growth at an interface—controlled by a crossover in how methane is supplied from the gas and liquid phases—which could explain the persistence of gas conduits in hydrate-bearing sediments and other nonequilibrium phenomena commonly observed in natural methane hydrate systems.

Experimental study on local scouring at pile-supported piers

NASA Astrophysics Data System (ADS)

Moreno, Mario; Birjukova, Olga; Grimaldi, Carmelo; Gaudio, Roberto; Cardoso, António H.

2017-06-01

In spite of the increasing importance of complex piers for bridges, the number of studies on these piers is comparatively small and the predictors of scour depth at complex piers are only a few, derived from limited experimental evidence. The main purpose of this paper is to share with the hydraulics community the results of 67 tests on scouring at pile-supported piers (including complex piers) aligned with the flow, under clear-water conditions close to the threshold of beginning of sediment motion, while contributing to shade some more light on the influence of the pile-cap thickness on the equilibrium scour depth, the reliability of the superposition approach, the contribution of each one of the complex pier components to the equilibrium scour depth of the ensemble, and the performance of existing predictors of local scour at complex piers.

Nonequilibrium Thermodynamics of Hydrate Growth on a Gas-Liquid Interface.

PubMed

Fu, Xiaojing; Cueto-Felgueroso, Luis; Juanes, Ruben

2018-04-06

We develop a continuum-scale phase-field model to study gas-liquid-hydrate systems far from thermodynamic equilibrium. We design a Gibbs free energy functional for methane-water mixtures that recovers the isobaric temperature-composition phase diagram under thermodynamic equilibrium conditions. The proposed free energy is incorporated into a phase-field model to study the dynamics of hydrate formation on a gas-liquid interface. We elucidate the role of initial aqueous concentration in determining the direction of hydrate growth at the interface, in agreement with experimental observations. Our model also reveals two stages of hydrate growth at an interface-controlled by a crossover in how methane is supplied from the gas and liquid phases-which could explain the persistence of gas conduits in hydrate-bearing sediments and other nonequilibrium phenomena commonly observed in natural methane hydrate systems.

Extended Fujita Approach to the Molecular Weight Distribution of Polysaccharides and other Polymeric Systems

PubMed Central

Harding, Stephen E.; Schuck, Peter; Abdelhameed, Ali Saber; Adams, Gary; Kök, M. Samil; Morris, Gordon A.

2011-01-01

In 1962 H. Fujita (Mathematical Theory of Sedimentation Analysis, Academic Press, New York, pp. 182–192) examined the possibility of transforming a quasi-continuous distribution g(s) of sedimentation coefficient s into a distribution f(M) of molecular weight M for linear polymers using the relation f(M) = g(s).(ds/dM) and showed that this could be done if information about the relation between s and M is available from other sources. Fujita provided the transformation based on the scaling relation s = κM0.5, where κ is taken as a constant for that particular polymer and the exponent 0.5 essentially corresponds to a randomly coiled polymer under ideal conditions. This method was successfully applied to mucus glycoproteins (S.E. Harding, Adv. Carbohyd. Chem. Biochem. 47 (1989), 345–381). We now describe an extension of the method to general conformation types via the scaling relation s = κMb, where b = 0.4–0.5 for a coil, ~0.15–0.2 for a rod and ~0.67 for a sphere. We give examples of distributions f(M) vs M obtained for polysaccharides from SEDFIT derived least squares g(s) vs s profiles (P. Schuck, Biophys. J. 78 (2000) 1606–1619) and the analytical derivative for ds/dM performed with Microcal ORIGIN. We also describe a more direct route from a direct numerical solution of the integral equation describing the molecular weight distribution problem. Both routes give identical distributions although the latter offers the advantage of being incorporated completely within SEDFIT. The method currently assumes that solutions behave ideally: sedimentation velocity has the major advantage over sedimentation equilibrium in that concentrations less than 0.2 mg/ml can be employed, and for many systems non-ideality effects can be reasonably ignored. For large, non-globular polymer systems, diffusive contributions are also likely to be small. PMID:21276851

Extended Fujita approach to the molecular weight distribution of polysaccharides and other polymeric systems.

PubMed

Harding, Stephen E; Schuck, Peter; Abdelhameed, Ali Saber; Adams, Gary; Kök, M Samil; Morris, Gordon A

2011-05-01

In 1962 H. Fujita (H. Fujita, Mathematical Theory of Sedimentation Analysis, Academic Press, New York, 1962) examined the possibility of transforming a quasi-continuous distribution g(s) of sedimentation coefficient s into a distribution f(M) of molecular weight M for linear polymers using the relation f(M)=g(s)·(ds/dM) and showed that this could be done if information about the relation between s and M is available from other sources. Fujita provided the transformation based on the scaling relation s=κ(s)M(0.5), where κ(s) is taken as a constant for that particular polymer and the exponent 0.5 essentially corresponds to a randomly coiled polymer under ideal conditions. This method has been successfully applied to mucus glycoproteins (S.E. Harding, Adv. Carbohyd. Chem. Biochem. 47 (1989) 345-381). We now describe an extension of the method to general conformation types via the scaling relation s=κM(b), where b=0.4-0.5 for a coil, ∼0.15-0.2 for a rod and ∼0.67 for a sphere. We give examples of distributions f(M) versus M obtained for polysaccharides from SEDFIT derived least squares g(s) versus s profiles (P. Schuck, Biophys. J. 78 (2000) 1606-1619) and the analytical derivative for ds/dM performed with Microcal ORIGIN. We also describe a more direct route from a direct numerical solution of the integral equation describing the molecular weight distribution problem. Both routes give identical distributions although the latter offers the advantage of being incorporated completely within SEDFIT. The method currently assumes that solutions behave ideally: sedimentation velocity has the major advantage over sedimentation equilibrium in that concentrations less than 0.2mg/ml can be employed, and for many systems non-ideality effects can be reasonably ignored. For large, non-globular polymer systems, diffusive contributions are also likely to be small. Copyright © 2011 Elsevier Inc. All rights reserved.

Quality-assurance plan for the analysis of fluvial sediment by the U.S. Geological Survey Kentucky Water Science Center Sediment Laboratory

USGS Publications Warehouse

Shreve, Elizabeth A.; Downs, Aimee C.

2005-01-01

This report describes laboratory procedures used by the U.S. Geological Survey Kentucky Water Science Center Sediment Laboratory for the processing and analysis of fluvial-sediment samples for concentration of sand and finer material. The report details the processing of a sediment sample through the laboratory from receiving the sediment sample, through the analytical process, to compiling results of the requested analysis. Procedures for preserving sample integrity, calibrating and maintaining of laboratory and field instruments and equipment, analyzing samples, internal quality assurance and quality control, and validity of the sediment-analysis results also are described. The report includes a list of references cited and a glossary of sediment and quality-assurance terms.

Analysis of the transport of sediment by the Suncook River in Epsom, Pembroke, and Allenstown, New Hampshire, after the May 2006 flood

USGS Publications Warehouse

Flynn, Robert H.

2011-01-01

During May 13-16, 2006, rainfall in excess of 8.8 inches flooded central and southern New Hampshire. On May 15, 2006, a breach in a bank of the Suncook River in Epsom, New Hampshire, caused the river to follow a new path. In order to assess and predict the effect of the sediment in, and the subsequent flooding on, the river and flood plain, a study by the U.S. Geological Survey (USGS) characterizing sediment transport in the Suncook River was undertaken in cooperation with the Federal Emergency Management Agency (FEMA) and the New Hampshire Department of Environmental Services (NHDES). The U.S. Army Corps of Engineers (USACE) Hydrologic Engineering Center-River Analysis System (HEC-RAS) model was used to simulate flow and the transport of noncohesive sediments in the Suncook River from the upstream corporate limit of Epsom to the river's confluence with the Merrimack River in the Village of Suncook (Allenstown and Pembroke, N.H.), a distance of approximately 16 miles. In addition to determining total sediment loads, analyses in this study reflect flooding potentials for selected recurrence intervals that are based on the Suncook River streamgage flow data (streamgage 01089500) and on streambed elevations predicted by HEC-RAS for the end of water year 2010 (September 30, 2010) in the communities of Epsom, Pembroke, and Allenstown. This report presents changes in streambed and water-surface elevations predicted by the HEC-RAS model using data through the end of water year 2010 for the 50-, 10-, 2-, 1-, 0.2-percent annual exceedence probabilities (2-, 10-, 50-, 100-, and 500-year recurrence-interval floods, respectively), calculated daily and annual total sediment loads, and a determination of aggrading and degrading stream reaches. The model was calibrated and evaluated for a 400-day span from May 8, 2008 through June 11, 2009; these two dates coincided with field collection of stream cross-sectional elevation data. Seven sediment-transport functions were evaluated in the model with the Laursen (Copeland) sediment-transport function best describing the sediment load, transport behavior, and changes in streambed elevation for the specified spatial and temporal conditions of the 400-day calibration period. Simulation results from the model and field-collected sediment data indicate that, downstream of the avulsion channel, for the average daily mean flow during the study period, approximately 100 to 400 tons per day of sediment (varying with daily mean flow) was moving past the Short Falls Road Bridge over the Suncook River in Epsom, while approximately 0.05 to 0.5 tons per day of sediment was moving past the Route 28 bridge in Pembroke and Allenstown, and approximately 1 to 10 tons per day was moving past the Route 3 bridge in Pembroke and Allenstown. Changes in water-surface elevation that the model predicted for the end of water year 2010 to be a result of changes in streambed elevation ranged from a mean increase of 0.20 feet (ft) for the 50-percent annual exceedence-probability flood (2-year recurrence-interval flood) due to an average thalweg increase of 0.88 ft between the Short Falls Road Bridge and the Buck Street Dams in Pembroke and Allenstown to a mean decrease of 0.41 ft for the 50-percent annual exceedence-probability flood due to an average thalweg decrease of 0.49 ft above the avulsion in Epsom. An analysis of shear stress (force created by a fluid acting on sediment particles) was undertaken to determine potential areas of erosion and deposition. Based on the median grain size (d50) and shear stress analysis, the study found that in general, for floods greater than the 50-percent annual exceedence probability flood, the shear stress in the streambed is greater than the critical shear stress in much of the river study reach. The result is an expectation of streambed-sediment movement and erosion even at high exceedence-probability events, pending although the stream ultimately attains equilibrium through stream-stabilization measures or the adjustment of the river over time. The potential for aggradation in the Suncook River is greatest in the reach downstream of the avulsion. Specifically, these reaches are (1) downstream of the former sand pit from adjacent to Round Pond to downstream of the flood chute at the large meander bends, and (2) downstream of the Short Falls Road Bridge to approximately 3,800 ft upstream of the Route 28 bridge. The potential for degradation-net lowering of the streambed-is greatest for the reach upstream of the avulsion to the Route 4 bridge.

Recent and historic sediment dynamics along Difficult Run, a suburban Virginia Piedmont stream

NASA Astrophysics Data System (ADS)

Hupp, Cliff R.; Noe, Gregory B.; Schenk, Edward R.; Benthem, Adam J.

2013-01-01

Suspended sediment is one of the major concerns regarding the quality of water entering the Chesapeake Bay. Some of the highest suspended-sediment concentrations occur on Piedmont streams, including Difficult Run, a tributary of the Potomac River draining urban and suburban parts of northern Virginia. Accurate information on catchment level sediment budgets is rare and difficult to determine. Further, the sediment trapping portion of sediment budget represents an important ecosystem service that profoundly affects downstream water quality. Our objectives, with special reference to human alterations to the landscape, include the documentation and estimation of floodplain sediment trapping (present and historic) and bank erosion along an urbanized Piedmont stream, the construction of a preliminary sediment balance, and the estimation of legacy sediment and recent development impacts. We used white feldspar markers to measure floodplain sedimentation rates and steel pins to measure erosion rates on floodplains and banks, respectively. Additional data were collected for/from legacy sediment thickness and characteristics, mill pond impacts, stream gaging station records, topographic surveying, and sediment density, texture, and organic content. Data were analyzed using GIS and various statistical programs. Results are interpreted relative to stream equilibrium affected by both post-colonial bottomland sedimentation (legacy) and modern watershed hardening associated with urbanization. Six floodplain/channel sites, from high to low in the watershed, were selected for intensive study. Bank erosion ranges from 0 to 470 kg/m/y and floodplain sedimentation ranges from 18 to 1369 kg/m/y (m refers to meters of stream reach). Upstream reaches are net erosional, while downstream reaches have a distinctly net depositional flux providing a watershed sediment balance of 2184 kg/m/y trapped within the system. The amounts of both deposition and erosion are large and suggest nonequilibrium channel conditions. Both peak discharge and number of peaks above base have substantially increased since the mid-1960s when urbanization of the watershed began. Deposition patterns are most closely correlated with channel gradient, sinuosity, and channel width/floodplain width for recent and historic periods. The substantial amounts of fine grained sediment deposited on the floodplain over the past two centuries or so do not appear to be closely related to historic mill pond presence or location. The floodplain continues to provide the critical ecosystem service of sediment trapping in the face of multiple human alterations. Trends in sediment deposition/erosion may react rapidly to land use practices within the watershed and offer a valuable barometer of the effects of management actions.

Recent and historic sediment dynamics along Difficult Run, a suburban Virginia Piedmont stream

USGS Publications Warehouse

Hupp, Cliff R.; Noe, Gregory B.; Schenk, Edward R.; Bentham, Adam J.

2012-01-01

Suspended sediment is one of the major concerns regarding the quality of water entering the Chesapeake Bay. Some of the highest suspended-sediment concentrations occur on Piedmont streams, including Difficult Run, a tributary of the Potomac River draining urban and suburban parts of northern Virginia. Accurate information on catchment level sediment budgets is rare and difficult to determine. Further, the sediment trapping portion of sediment budget represents an important ecosystem service that profoundly affects downstream water quality. Our objectives, with special reference to human alterations to the landscape, include the documentation and estimation of floodplain sediment trapping (present and historic) and bank erosion along an urbanized Piedmont stream, the construction of a preliminary sediment balance, and the estimation of legacy sediment and recent development impacts. We used white feldspar markers to measure floodplain sedimentation rates and steel pins to measure erosion rates on floodplains and banks, respectively. Additional data were collected for/from legacy sediment thickness and characteristics, mill pond impacts, stream gaging station records, topographic surveying, and sediment density, texture, and organic content. Data were analyzed using GIS and various statistical programs. Results are interpreted relative to stream equilibrium affected by both post-colonial bottomland sedimentation (legacy) and modern watershed hardening associated with urbanization. Six floodplain/channel sites, from high to low in the watershed, were selected for intensive study. Bank erosion ranges from 0 to 470 kg/m/y and floodplain sedimentation ranges from 18 to 1369 kg/m/y (m refers to meters of stream reach). Upstream reaches are net erosional, while downstream reaches have a distinctly net depositional flux providing a watershed sediment balance of 2184 kg/m/y trapped within the system. The amounts of both deposition and erosion are large and suggest nonequilibrium channel conditions. Both peak discharge and number of peaks above base have substantially increased since the mid-1960s when urbanization of the watershed began. Deposition patterns are most closely correlated with channel gradient, sinuosity, and channel width/floodplain width for recent and historic periods. The substantial amounts of fine grained sediment deposited on the floodplain over the past two centuries or so do not appear to be closely related to historic mill pond presence or location. The floodplain continues to provide the critical ecosystem service of sediment trapping in the face of multiple human alterations. Trends in sediment deposition/erosion may react rapidly to land use practices within the watershed and offer a valuable barometer of the effects of management actions.

Hydro-bio-geomechanical properties of hydrate-bearing sediments from Nankai Trough

USGS Publications Warehouse

Santamarina, J.C.; Dai, Shifeng; Terzariol, M.; Jang, Jeonghwan; Waite, William F.; Winters, William J.; Nagao, J.; Yoneda, J.; Konno, Y.; Fujii, T.; Suzuki, K.

2015-01-01

Natural hydrate-bearing sediments from the Nankai Trough, offshore Japan, were studied using the Pressure Core Characterization Tools (PCCTs) to obtain geomechanical, hydrological, electrical, and biological properties under in situ pressure, temperature, and restored effective stress conditions. Measurement results, combined with index-property data and analytical physics-based models, provide unique insight into hydrate-bearing sediments in situ. Tested cores contain some silty-sands, but are predominantly sandy- and clayey-silts. Hydrate saturations Sh range from 0.15 to 0.74, with significant concentrations in the silty-sands. Wave velocity and flexible-wall permeameter measurements on never-depressurized pressure-core sediments suggest hydrates in the coarser-grained zones, the silty-sands where Sh exceeds 0.4, contribute to soil-skeletal stability and are load-bearing. In the sandy- and clayey-silts, where Sh < 0.4, the state of effective stress and stress history are significant factors determining sediment stiffness. Controlled depressurization tests show that hydrate dissociation occurs too quickly to maintain thermodynamic equilibrium, and pressure–temperature conditions track the hydrate stability boundary in pure-water, rather than that in seawater, in spite of both the in situ pore water and the water used to maintain specimen pore pressure prior to dissociation being saline. Hydrate dissociation accompanied with fines migration caused up to 2.4% vertical strain contraction. The first-ever direct shear measurements on never-depressurized pressure-core specimens show hydrate-bearing sediments have higher sediment strength and peak friction angle than post-dissociation sediments, but the residual friction angle remains the same in both cases. Permeability measurements made before and after hydrate dissociation demonstrate that water permeability increases after dissociation, but the gain is limited by the transition from hydrate saturation before dissociation to gas saturation after dissociation. In a proof-of-concept study, sediment microbial communities were successfully extracted and stored under high-pressure, anoxic conditions. Depressurized samples of these extractions were incubated in air, where microbes exhibited temperature-dependent growth rates.

Formation of natural gas hydrates in marine sediments 1. Conceptual model of gas hydrate growth conditioned by host sediment properties

USGS Publications Warehouse

Clennell, M.B.; Hovland, M.; Booth, J.S.; Henry, P.; Winters, W.J.

1999-01-01

The stability of submarine gas hydrates is largely dictated by pressure and temperature, gas composition, and pore water salinity. However, the physical properties and surface chemistry of deep marine sediments may also affect the thermodynamic state, growth kinetics, spatial distributions, and growth forms of clathrates. Our conceptual model presumes that gas hydrate behaves in a way analogous to ice in a freezing soil. Hydrate growth is inhibited within fine-grained sediments by a combination of reduced pore water activity in the vicinity of hydrophilic mineral surfaces, and the excess internal energy of small crystals confined in pores. The excess energy can be thought of as a "capillary pressure" in the hydrate crystal, related to the pore size distribution and the state of stress in the sediment framework. The base of gas hydrate stability in a sequence of fine sediments is predicted by our model to occur at a lower temperature (nearer to the seabed) than would be calculated from bulk thermodynamic equilibrium. Capillary effects or a build up of salt in the system can expand the phase boundary between hydrate and free gas into a divariant field extending over a finite depth range dictated by total methane content and pore-size distribution. Hysteresis between the temperatures of crystallization and dissociation of the clathrate is also predicted. Growth forms commonly observed in hydrate samples recovered from marine sediments (nodules, and lenses in muds; cements in sands) can largely be explained by capillary effects, but kinetics of nucleation and growth are also important. The formation of concentrated gas hydrates in a partially closed system with respect to material transport, or where gas can flush through the system, may lead to water depletion in the host sediment. This "freeze-drying" may be detectable through physical changes to the sediment (low water content and overconsolidation) and/or chemical anomalies in the pore waters and metastable presence of free gas within the normal zone of hydrate stability. 

Mars Sample Return: The Next Step Required to Revolutionize Knowledge of Martian Geological and Climatological History

NASA Technical Reports Server (NTRS)

Mittlefehldt, D. W.

2012-01-01

The capability of scientific instrumentation flown on planetary orbiters and landers has made great advances since the signature Viking mission of the seventies. At some point, however, the science return from orbital remote sensing, and even in situ measurements, becomes incremental, rather than revolutionary. This is primarily caused by the low spatial resolution of such measurements, even for landed instrumentation, the incomplete mineralogical record derived from such measurements, the inability to do the detailed textural, mineralogical and compositional characterization needed to demonstrate equilibrium or reaction paths, and the lack of chronological characterization. For the foreseeable future, flight instruments will suffer from this limitation. In order to make the next revolutionary breakthrough in understanding the early geological and climatological history of Mars, samples must be available for interrogation using the full panoply of laboratory-housed analytical instrumentation. Laboratory studies of samples allow for determination of parageneses of rocks through microscopic identification of mineral assemblages, evaluation of equilibrium through electron microbeam analyses of mineral compositions and structures, determination of formation temperatures through secondary ion or thermal ionization mass spectrometry (SIMS or TIMS) analyses of stable isotope compositions. Such details are poorly constrained by orbital data (e.g. phyllosilicate formation at Mawrth Vallis), and incompletely described by in situ measurements (e.g. genesis of Burns formation sediments at Meridiani Planum). Laboratory studies can determine formation, metamorphism and/or alteration ages of samples through SIMS or TIMS of radiogenic isotope systems; a capability well-beyond flight instrumentation. Ideally, sample return should be from a location first scouted by landers such that fairly mature hypotheses have been formulated that can be tested. However, samples from clastic sediments derived from an extensive region of Mars can provide important, detailed understanding of early martian geological and climatological history. Interrogating clastic "sediments" from the Earth, Moon and asteroids has allowed discovery of new crustal units, identification of now-vanished crust, and determination of the geological history of extensive, remote regions. Returned sample of martian fluvial and/or aeolian sediments, for example from Gale crater, could be "read like a book" in terrestrial laboratories to provide truly revolutionary new insights into early martian geological and climatological evolution.

Verifying Food Web Bioaccumulation Models by Tracking Fish Exposure and Contaminant Uptake

DTIC Science & Technology

2012-03-01

Arnot, J. A. and F. A. P. C. Gobas (2004). "A Food Web Bioaccumulation Model for Organic Chemicals in Aquatic Ecosystems." Environmental Toxicology...site in Eagle Harbor, Washington." Aquatic Toxicology 88: 277-288. Myers, M. S., L. L. Johnson, et al. (2003). "Establishing the Causal Relationship...P. Connolly, et al. (1992). "An Equilibrium Model of Organic Chemical Accumulation in Aquatic Food Webs with Sediment Interaction." Environmental

Lack of Evidence for Onshore Sediment Transport from Deep Water at Decadal Time Scales: Fire Island, New York

DTIC Science & Technology

2011-01-01

the net volume change within the cell.  Qsource includes net longshore transport, net onshore transport, and contributions from bluff or dune erosion...in restoration of the downcoast beach at Westhampton Dunes (Daley et al., 2000; Terchunian and Merkert, 1994) and after the Westhampton groin...nourishment, backshore dune erosion added to the control volume, and overwash losses out of the control volume or losses due to equilibrium profile

Problem-based test: replication of mitochondrial DNA during the cell cycle.

PubMed

Sétáló, György

2013-01-01

Terms to be familiar with before you start to solve the test: cell cycle, generation time, S-phase, cell culture synchronization, isotopic pulse-chase labeling, density labeling, equilibrium density-gradient centrifugation, buoyant density, rate-zonal centrifugation, nucleoside, nucleotide, kinase enzymes, polymerization of nucleic acids, re-replication block, cell fractionation, Svedberg (sedimentation constant = [ S]), nuclear DNA, mitochondrial DNA, heavy and light mitochondrial DNA chains, heteroplasmy, mitochondrial diseases Copyright © 2013 Wiley Periodicals, Inc.

Non-Equilibrium Sediment Transport Modeling - Extensions and Applications

DTIC Science & Technology

2013-01-01

which considers the bed slope effect but can be lumped in the Manning’s n coefficient.      2 2 2 1/3 1 2 s b t t Uh U h UVh t x y z n m UUU U...n m UUU U h h gh gh g x x y y x x h C C C UhC m q U h h x x y y p L

Advective removal of intraparticle uranium from contaminated vadose zone sediments, Hanford, U.S.

PubMed

Ilton, Eugene S; Qafoku, Nikolla P; Liu, Chongxuan; Moore, Dean A; Zachara, John M

2008-03-01

A column study on U(VI)-contaminated vadose zone sediments from the Hanford Site, WA, was performed to investigate U(VI) release kinetics with water advection and variable geochemical conditions. The sediments were collected from an area adjacent to and below tank BX-102 that was contaminated as a result of a radioactive tank waste overfill event. The primary reservoir for U(VI) in the sediments are micrometer-size precipitates composed of nanocrystallite aggregates of a Na-U-Silicate phase, most likely Na-boltwoodite, that nucleated and grew within microfractures of the plagioclase component of sand-sized granitic clasts. Two sediment samples, with different U(VI) concentrations and intraparticle mass transfer properties, were leached with advective flows of three different solutions. The influent solutions were all calcite-saturated and in equilibrium with atmospheric CO2. One solution was prepared from DI water, the second was a synthetic groundwater (SGW) with elevated Na that mimicked groundwater at the Hanford site, and the third was the same SGW but with both elevated Na and Si. The latter two solutions were employed, in part, to test the effect of saturation state on U(VI) release. For both sediments, and all three electrolytes, there was an initial rapid release of U(VI) to the advecting solution followed by slower near steady-state release. U(VI)aq concentrations increased during subsequent stop-flow events. The electrolytes with elevated Na and Si depressed U(VL)aq concentrations in effluent solutions. Effluent U(VI)aq concentrations for both sediments and all three electrolytes were simulated reasonably well by a three domain model (the advecting fluid, fractures, and matrix) that coupled U(VI) dissolution, intraparticle U(VI)aq diffusion, and interparticle advection, where diffusion and dissolution properties were parameterized in a previous batch study.

Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Méndez-García, C.; Montero-Cabrera, M. E., E-mail: elena.montero@cimav.edu.mx; Renteria-Villalobos, M.

2008-01-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. ²³²Th-series, ²³⁸U-series, ⁴⁰K and ¹³⁷Cs activity concentrations (AC, Bq kg⁻¹) were determined by gamma spectrometry with a high purity Ge detector. ²³⁸U and ²³⁴U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating ofmore » core sediments was performed applying CRS method to ²¹⁰Pb activities. Results were verified by ¹³⁷Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High ²³⁸U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento – Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) ²³⁴U/²³⁸U and ²³⁸U/²²⁶Ra in sediments have values between 0.9–1.2, showing a behavior close to radioactive equilibrium in the entire basin. ²³²Th/²³⁸U, ²²⁸Ra/²²⁶Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.« less

Evaluation of lead concentration by one-box type multimedia model in Lake Biwa-Yodo River basin of Japan.

PubMed

Kondo, Akira; Yamamoto, Megumi; Inoue, Yoshio; Ariyadasa, B H A K T

2013-07-01

A one box type multimedia model was developed and applied for Lake Biwa-Yodo River basin in Japan to assess the distribution of lead in the environment. This model is based on mass balance and includes four environmental media; the atmosphere, the soil, the water body, and the sediment. The mass balance of lead is represented by the summation of mass transfer flux at equilibrium, emission flux, advection flux, and deposition flux or sedimentation flux. In the case of metallic compounds, dissolution rate and exchange equilibrium have also been taken into consideration. Pollutant Release and Transfer Registry (PRTR) in Japan was used as one of the major data source for this study. The emission of lead in Lake Biwa-Yodo River basin is calculated based on five sources of registered emission in PRTR, unregistered emission in PRTR, incinerators, leaded gasoline, and landfills. In this study, we estimated lead emission from 1957 to 2007 to observe the temporal accumulation of lead. Calculated lead concentrations were compared with the measured/observed concentrations. It was found out that the model could closely predict lead concentration in the soil and the water body. The concentration in the atmosphere was underestimated by the calculated concentrations. The reason was attributed to the underestimation of the amount of lead emission from incinerators. Copyright © 2013 Elsevier Ltd. All rights reserved.

Structural instability, multiple stable states, and hysteresis in periphyton driven by phosphorus enrichment in the Everglades

USGS Publications Warehouse

Dong, Quan; McCormick, Paul V.; Sklar, Fred H.; DeAngelis, Donald L.

2002-01-01

Periphyton is a key component of the Everglades ecosystems. It is a major primary producer, providing food and habitat for a variety of organisms, contributing material to the surface soil, and regulating water chemistry. Periphyton is sensitive to the phosphorus (P) supply and P enrichment has caused dramatic changes in the native Everglades periphyton assemblages. Periphyton also affects P availability by removing P from the water column and depositing a refractory portion into sediment. A quantitative understanding of the response of periphyton assemblages to P supply and its effects on P cycling could provide critical supports to decision making in the conservation and restoration of the Everglades. We constructed a model to examine the interaction between periphyton and P dynamics. The model contains two differential equations: P uptake and periphyton growth are assumed to follow the Monod equation and are limited by a modified logistic equation. Equilibrium and stability analyses suggest that P loading is the driving force and determines the system behavior. The position and number of steady states and the stability also depend upon the rate of sloughing, through which periphyton deposits refractory P into sediment. Multiple equilibria may exist, with two stable equilibria separated by an unstable equilibrium. Due to nonlinear interplay of periphyton and P in this model, catastrophe and hysteresis are likely to occur.

Analysis of factors controlling sediment phosphorus flux potential of wetlands in Hulun Buir grassland by principal component and path analysis method.

PubMed

He, Jing; Su, Derong; Lv, Shihai; Diao, Zhaoyan; Ye, Shengxing; Zheng, Zhirong

2017-11-08

Phosphorus (P) flux potential can predict the trend of phosphorus release from wetland sediments to water and provide scientific parameters for further monitoring and management for phosphorus flux from wetland sediments to overlying water. Many studies have focused on factors affecting sediment P flux potential in sediment-water interface, but rarely on the relationship among these factors. In the present study, experiment on sediment P flux potential in sediment-water interface was conducted in six wetlands in Hulun Buir grassland, China and the relationships among sediment P flux potential in sediment-water interface, sediment physical properties, and sediment chemical characteristics were examined. Principal component analysis and path analysis were used to discuss these data in correlation coefficient, direct, and indirect effects on sediment P flux potential in sediment-water interface. Results indicated that the major factors affecting sediment P flux potential in sediment-water interface were amount of organophosphate-degradation bacterium in sediment, Ca-P content, and total phosphorus concentrations. The factors of direct influence sediment P flux potential were sediment Ca-P content, Olsen-P content, SOC content, and sediment Al-P content. The indirect influence sediment P flux potential in sediment-water interface was sediment Olsen-P content, sediment SOC content, sediment Ca-P content, and sediment Al-P content. And the standard multiple regression describing the relationship between sediment P flux potential in sediment-water interface and its major effect factors was Y = 5.849 - 1.025X 1  - 1.995X 2  + 0.188X 3  - 0.282X 4 (r = 0.9298, p < 0.01, n = 96), where Y is sediment P flux potential in sediment-water interface, X 1 is sediment Ca-P content, X 2 is sediment Olsen-P content, X 3 is sediment SOC content, and X 4 is sediment Al-P content. Therefore, future research will focus on these sediment properties to analyze the interrelation among sediment properties factors, main vegetable factors, and environment factors which influence the sediment P flux potential in sediment-water interface.

The distribution of triclosan and methyl-triclosan in marine sediments of Barker Inlet, South Australia.

PubMed

Fernandes, Milena; Shareef, Ali; Kookana, Rai; Gaylard, Sam; Hoare, Sonja; Kildea, Tim

2011-04-01

In this work, we investigated the transport and burial of triclosan and its methylated derivative, in surface sediments near the mouth of Barker Inlet in South Australia. The most likely source of this commonly used bactericide to the area is a wastewater outfall discharging at the confluence of the inlet with marine waters. Triclosan was detected in all samples, at concentrations (5-27 μg kg(-1)) comparable to values found in other surface sediments under the influence of marine wastewater outfalls. Its dispersal was closely associated with fine and organic-rich fractions of the sediments. Methyl-triclosan was detected in approximately half of the samples at concentrations <11 μg kg(-1). The occurrence of this compound was linked to both wastewater discharges and biological methylation of the parent compound. Wastewater-borne methyl-triclosan had a smaller spatial footprint than triclosan and was mostly deposited in close proximity to the outfall. In situ methylation of triclosan likely occurs at deeper depositional sites, whereas the absence of methyl-triclosan from shallower sediments was potentially explained by photodegradation of the parent compound. Based on partition equilibrium, a concentration of triclosan in the order of 1 μg L(-1) was estimated in sediment porewaters, a value lower than the threshold reported for harmful effects to occur in the couple of species of marine phytoplankton investigated to date. Methyl-triclosan presents a greater potential for bioaccumulation than triclosan, but the implications of its occurrence to aquatic ecosystem health are difficult to predict given the lack of ecotoxicological data in the current literature.

Methods for Estimating Adsorbed Uranium(VI) and Distribution Coefficients of Contaminated Sediments

USGS Publications Warehouse

Kohler, M.; Curtis, G.P.; Meece, D.E.; Davis, J.A.

2004-01-01

Assessing the quantity of U(VI) that participates in sorption/desorption processes in a contaminated aquifer is an important task when investigating U migration behavior. U-contaminated aquifer sediments were obtained from 16 different locations at a former U mill tailings site at Naturita, CO (U.S.A.) and were extracted with an artificial groundwater, a high pH sodium bicarbonate solution, hydroxylamine hydrochloride solution, and concentrated nitric acid. With an isotopic exchange method, both a KD value for the specific experimental conditions as well as the total exchangeable mass of U(VI) was determined. Except for one sample, KD values determined by isotopic exchange with U-contaminated sediments that were in equilibrium with atmospheric CO2 agreed within a factor of 2 with KD values predicted from a nonelectrostatic surface complexation model (NEM) developed from U(VI) adsorption experiments with uncontaminated sediments. The labile fraction of U(VI) and U extracted by the bicarbonate solution were highly correlated (r2 = 0.997), with a slope of 0.96 ?? 0.01. The proximity of the slope to one suggests that both methods likely access the same reservoir of U(VI) associated with the sediments. The results indicate that the bicarbonate extraction method is useful for estimating the mass of labile U(VI) in sediments that do not contain U(IV). In-situ KD values calculated from the measured labile U(VI) and the dissolved U(VI) in the Naturita alluvial aquifer agreed within a factor of 3 with in-situ K D values predicted with the NEM and groundwater chemistry at each well.

Sediment data for computations of deposition rates in the tidal Potomac system, Maryland and Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Glenn, J.L.; Martin, E.A.; Rice, C.A.

1986-01-01

Sixty-two cores ranging in length from 33 to 1,002 cm were collected from the tidal Potomac system and from selected tributaries downstream from the local head-of-tides between June 1978 and July 1981. Segments from selected depths below the sediment surface have been analyzed for a variety of constituents, including lead-210, trace metals, nutrients, and particle size. The core sites were positioned throughout the hydrologic divisions and geomorphic units of the tidal Potomac system and in water depths ranging from 1 to 30 cm. Alpha counting methods were used to determine the polonium-210 radioactivity and secular equilibrium was assumed between lead-210more » and polonium-210. The alpha decay of polonium-210 provides a measure of the lead-210 radioactivity of the lead-210 produced by in-situ decay of radium-226 in the sediment column and the lead-210 from external sources. Only the unsupported lead-210 was used in computations of the deposition rate. The background level of lead-210 in tidal Potomac system sediment cores usually is based on in-situ measurements of total lead-210 at depths below which no unsupported lead-210 is believed to be present, and the lead-210 concentrations are relatively constant. 6 refs., 3 figs., 1 tab.« less

Heat storage in the Hettangian aquifer in Berlin - results from a column experiment

NASA Astrophysics Data System (ADS)

Milkus, Chri(Sch)augott

2015-04-01

Aquifer Thermal Energy Storage (ATES) is a sustainable alternative for storage and seasonal availability of thermal energy. However, its impact on the subsurface flow regime is not well known. In Berlin (Germany), the Jurassic (Hettangian) sandstone aquifer with highly mineralized groundwater (TDS 27 g/L) is currently used for heat storage. The aim of this study was to examine the hydrogeochemical changes that are caused by the induced temperature shift and its effects on the hydraulic permeability of the aquifer. Column experiments were conducted, in which stainless steel columns were filled with sediment from the aquifer and flushed with native groundwater for several weeks. The initial temperature of the experiment was 20°C, comparable to the in-situ conditions within the aquifer. After reaching equilibrium between sediment and water, the temperature was increased to simulate heating of the aquifer. During the experiment, physical and chemical parameters (pH, ORP, dissolved oxygen and dissolved carbon dioxide) were measured at the outflow of the column and the effluent water was sampled. Using a Scanning Electron Microscope, the deposition of precipitated minerals and biofilm on sediment grains was analyzed. Changes in hydraulic properties of the sediment were studied by the use of tracer tests with Uranin.

Assessment of the environmental fate and effects of azilsartan, a selective antagonist of angiotensin II type 1.

PubMed

Weltman, R; Brands, C M J; Corral, E; Desmares-Koopmans, M J E; Migchielsen, M H J; Oudhoff, K A; de Roode, D F

2012-06-01

In this paper the results of a thorough evaluation of the environmental fate and effects of azilsartan are presented. Azilsartan medoxomil is administered as a pro-drug for the treatment of patients with essential hypertension. The pro-drug is converted by hydrolysis to the active pharmaceutical ingredient azilsartan. Laboratory tests to evaluate the environmental fate and effects of azilsartan medoxomil were conducted with azilsartan and performed in accordance with OECD test guidelines. The predicted environmental concentration (PEC) in surface water was estimated at 0.32 μg L(-1) (above the action limit of 0.01 μg L(-1)), triggering a Phase II assessment. Azilsartan is not readily biodegradable. Results of the water sediment study demonstrated significant shifting of azilsartan metabolites to sediment. Based on the equilibrium partitioning method, metabolites are unlikely to pose a risk to sediment-dwelling organisms. Ratios of the predicted environmental concentrations (PECs) to the predicted-no-effect concentrations (PNECs) did not exceed the relevant triggers, and the risk to aquatic, sewage treatment plant (STP), groundwater and sediment compartments was concluded acceptable. A terrestrial assessment was not triggered. Azilsartan poses an acceptable risk to the environment. Copyright © 2012 Elsevier Ltd. All rights reserved.

In-stream biogeochemical processes of a temporary river.

PubMed

Tzoraki, Ourania; Nikolaidis, Nikolaos P; Amaxidis, Yorgos; Skoulikidis, Nikolaos Th

2007-02-15

A reach at the estuary of Krathis River in Greece was used to assess how in-stream processes alter its hydrologic and biogeochemical regime. Krathis River exhibited high annual flow variability and its transmission losses become significant, especially during the dry months. These transmission losses are enhanced in chemistry due to release of nutrients from river sediments. These fluxes are significant because they correspond to 11% of the dissolved inorganic nitrogen flux of the river. Release of nitrogen species was influenced by temperature, while release of phosphate was not because phosphate levels were below the equilibrium concentration. There is a significant amount of sediments with fine composition that create "hot spot" areas in the river reach. These sediments are mobilized during the first flush events in the fall carrying with them a significant load of nutrient and suspended matter to the coastal zone. The nutrient organic content of sediments was also significant and it was studied in terms of its mineralization capacity. The capacity for mineralization was influenced by soil moisture, exhibiting significant capacity even at moisture levels of 40%. Temporary rivers are sensitive ecosystems, vulnerable to climate changes. In-stream processes play a significant role in altering the hydrology and biogeochemistry of the water and its impacts to the coastal zone.

Simulated wave-driven sediment transport along the eastern coast of the Baltic Sea

NASA Astrophysics Data System (ADS)

Soomere, Tarmo; Viška, Maija

2014-01-01

Alongshore variations in sediment transport along the eastern Baltic Sea coast from the Sambian (Samland) Peninsula up to Pärnu Bay in the Gulf of Riga are analysed using long-term (1970-2007) simulations of the nearshore wave climate and the Coastal Engineering Research Centre (CERC) wave energy flux model applied to about 5.5 km long beach sectors. The local rate of bulk transport is the largest along a short section of the Sambian Peninsula and along the north-western part of the Latvian coast. The net transport has an overall counter-clockwise nature but contains a number of local temporary reversals. The alongshore sediment flux has several divergence and convergence points. One of the divergence points at the Akmenrags Cape divides the sedimentary system of the eastern coast of the Baltic Proper into two almost completely separated compartments in the simulated wave climate. Cyclic relocation of a highly persistent convergence point over the entire Curonian Spit suggests that this landform is in almost perfect dynamical equilibrium in the simulated approximation of the contemporary wave climate.

Risk assessment of nonylphenol and its ethoxylates in U.S. river water and sediment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weeks, J.A.; Adams, W.J.; Guiney, P.D.

1994-12-31

A comprehensive program addressing the risks of nonylphenol (NP) and its ethoxylates (NPE) in aquatic environments of the United States has been undertaken by the Alkyl Phenol Ethoxylates Panel of the Chemical Manufacturers Association cooperating with EPA. Several hundred million pounds of NPE surfactants are used in the US each year. Nonylphenol can be an intermediate product of degradation of nonylphenol ethoxylates. A survey of those river reaches most likely to contain NPE and NP residues was conducted based on a random sample of a subset of the EPA River Reach File defined by certain selection criteria. Applying enhanced analyticalmore » techniques, little or no NP and NPE were found in river water at most locations, while low levels were usually detected in sediment. Acute and chronic toxicity tests using a variety of organisms have also been completed. New results are presented for shrimp, fish, tadpoles, midges, and algae. The risk of NP to the aquatic environment is examined by comparison of observed levels with toxicity benchmarks, and by application of equilibrium partitioning theory to calculate sediment interstitial chemical concentrations.« less

A coupled geomorphic and ecological model of tidal marsh evolution.

PubMed

Kirwan, Matthew L; Murray, A Brad

2007-04-10

The evolution of tidal marsh platforms and interwoven channel networks cannot be addressed without treating the two-way interactions that link biological and physical processes. We have developed a 3D model of tidal marsh accretion and channel network development that couples physical sediment transport processes with vegetation biomass productivity. Tidal flow tends to cause erosion, whereas vegetation biomass, a function of bed surface depth below high tide, influences the rate of sediment deposition and slope-driven transport processes such as creek bank slumping. With a steady, moderate rise in sea level, the model builds a marsh platform and channel network with accretion rates everywhere equal to the rate of sea-level rise, meaning water depths and biological productivity remain temporally constant. An increase in the rate of sea-level rise, or a reduction in sediment supply, causes marsh-surface depths, biomass productivity, and deposition rates to increase while simultaneously causing the channel network to expand. Vegetation on the marsh platform can promote a metastable equilibrium where the platform maintains elevation relative to a rapidly rising sea level, although disturbance to vegetation could cause irreversible loss of marsh habitat.

Bifurcation and Stability Analysis of the Equilibrium States in Thermodynamic Systems in a Small Vicinity of the Equilibrium Values of Parameters

NASA Astrophysics Data System (ADS)

Barsuk, Alexandr A.; Paladi, Florentin

2018-04-01

The dynamic behavior of thermodynamic system, described by one order parameter and one control parameter, in a small neighborhood of ordinary and bifurcation equilibrium values of the system parameters is studied. Using the general methods of investigating the branching (bifurcations) of solutions for nonlinear equations, we performed an exhaustive analysis of the order parameter dependences on the control parameter in a small vicinity of the equilibrium values of parameters, including the stability analysis of the equilibrium states, and the asymptotic behavior of the order parameter dependences on the control parameter (bifurcation diagrams). The peculiarities of the transition to an unstable state of the system are discussed, and the estimates of the transition time to the unstable state in the neighborhood of ordinary and bifurcation equilibrium values of parameters are given. The influence of an external field on the dynamic behavior of thermodynamic system is analyzed, and the peculiarities of the system dynamic behavior are discussed near the ordinary and bifurcation equilibrium values of parameters in the presence of external field. The dynamic process of magnetization of a ferromagnet is discussed by using the general methods of bifurcation and stability analysis presented in the paper.

Modeling sediment transport as a spatio-temporal Markov process.

NASA Astrophysics Data System (ADS)

Heyman, Joris; Ancey, Christophe

2014-05-01

Despite a century of research about sediment transport by bedload occuring in rivers, its constitutive laws remain largely unknown. The proof being that our ability to predict mid-to-long term transported volumes within reasonable confidence interval is almost null. The intrinsic fluctuating nature of bedload transport may be one of the most important reasons why classical approaches fail. Microscopic probabilistic framework has the advantage of taking into account these fluctuations at the particle scale, to understand their effect on the macroscopic variables such as sediment flux. In this framework, bedload transport is seen as the random motion of particles (sand, gravel, pebbles...) over a two-dimensional surface (the river bed). The number of particles in motion, as well as their velocities, are random variables. In this talk, we show how a simple birth-death Markov model governing particle motion on a regular lattice accurately reproduces the spatio-temporal correlations observed at the macroscopic level. Entrainment, deposition and transport of particles by the turbulent fluid (air or water) are supposed to be independent and memoryless processes that modify the number of particles in motion. By means of the Poisson representation, we obtained a Fokker-Planck equation that is exactly equivalent to the master equation and thus valid for all cell sizes. The analysis shows that the number of moving particles evolves locally far from thermodynamic equilibrium. Several analytical results are presented and compared to experimental data. The index of dispersion (or variance over mean ratio) is proved to grow from unity at small scales to larger values at larger scales confirming the non Poisonnian behavior of bedload transport. Also, we study the one and two dimensional K-function, which gives the average number of moving particles located in a ball centered at a particle centroid function of the ball's radius.

Stiparin: a glycoprotein from sea cucumber dermis that aggregates collagen fibrils.

PubMed

Trotter, J A; Lyons-Levy, G; Luna, D; Koob, T J; Keene, D R; Atkinson, M A

1996-07-01

The interactions between collagen fibrils in many echinoderm connective tissues are rapidly altered by the secretions of resident neurosecretory cells. Recent evidence has suggested that a secreted protein is responsible for the interactions that lead to an increase in tissue stiffness (Trotter and Koob, 1995). Structurally intact collagen fibrils have been isolated from such a connective tissue- the dermis of the sea cucumber Cucumaria frondosa- and used in an assay in vitro to identify a protein that binds to them and causes them to aggregate. This protein has been purified by anion-exchange and molecular sieve chromatography. It is eluted from a MonoQ column at approximately 0.55 M NaCl. Its isoelectric point is 5.2. It elutes from a Superose-6 column in a position corresponding to a molecule with a Stokes radius of 11.5 nm. Its native molecular weight estimated from sedimentation equilibrium analysis under non-denaturing conditions is 375,000, and its monomer molecular weight, estimated by polyacrylamide gel electrophoresis in the presence of sodium dodecyl sulfate, is approximately 350,000. Sedimentation velocity measurements indicated for the native molecule a sedimentation coefficient of 11 x 10(-13)s, a diffusion coefficient of 3.274 x 10(-7) cm2s-1, and a frictional ratio of 1.95, which corresponds to a prolate ellipsoid of revolution with an axial ratio of 19. The highly asymmetric structure suggested by the above correlated well with the images obtained by transmission electron microscopy following rotary shadowing, which revealed a flexible structure approximately 125 nm long. Based on its ability to aggregate collagen fibrils, this protein has been named "stiparin," from the Latin stipare, "to pack together."

A new conceptual framework for water and sediment connectivity

NASA Astrophysics Data System (ADS)

Keesstra, Saskia; Cerdà, Artemi; Parsons, Tony; Nunes, Joao Pedro; Saco, Patricia

2016-04-01

For many years scientists have tried to understand, describe and quantify sediment transport on multiple scales; from the geomorphological work triggered by a single thunderstorm to the geological time scale land scape evolution, and from particles and soil aggregates up to the continental scale. In the last two decades, a new concept called connectivity (Baartman et al., 2013; Bracken et al., 2013, 2015; Parsons et al., 2015) has been used by the scientific community to describe the connection between the different scales at which the sediment redistribution research along the watershed are being studied: pedon, slope tram, slope, watersheds, and basins. This concept is seen as a means to describe and quantify the results of processes influencing the transport of sediment on all these scales. Therefore the concept of connectivity and the way scales are used in the design of a measurement and monitoring scheme are interconnected (Cerdà et al., 2012), which shows that connectivity is not only a tool for process understanding, but also a tool to measure processes on multiple scales. This research aims to describe catchment system dynamics from a connectivity point of view. This conceptual framework can be helpful to look at catchment systems and synthesize which data are necessary to take into account when measuring or modelling water and sediment transfer in catchment systems, Identifying common patterns and generalities will help discover physical reasons for differences in responses and interaction between these processes. We describe a conceptual framework which is meant to bring a better understanding of the system dynamics of a catchment in terms of water and sediment transfer by breaking apart the system dynamics in stocks (the system state at a given moment) and flows (the system fluxes). Breaking apart the internal system dynamics that determine the behaviour of the catchment system is in our opinion a way to bring a better insight into the concepts of hydrological and sediment connectivity as described in previous research by Bracken et al (2013, 2015). By looking at the individual parts of the system, it becomes more manageable and less conceptual, which is important because we have to indicate where the research on connectivity should focus on. With this approach, processes and feedbacks in the catchment system can be pulled apart to study separately, making the system understandable and measureable, which will enable parameterization of models with actual measured data. The approach we took in describing water and sediment transfer is to first assess how they work in a system in dynamic equilibrium. After describing this, an assessment is made of how such dynamic equilibriums can be taken out of balance by an external push. Baartman, J.E.M., Masselink, R.H., Keesstra, S.D., Temme, A.J.A.M., 2013. Linking landscape morphological complexity and sediment connectivity. Earth Surface Processes and Landforms 38: 1457-1471. Bracken, L.J., Wainwright, J., Ali, G.A., Tetzlaff, D., Smith, M.W., Reaney, S.M., and Roy, A.G. 2013. Concepts of hydrological connectivity: research approaches, pathways and future agendas. Earth Science Reviews, 119, 17-34. Bracken, L.J., Turnbull, L, Wainwright, J. and Boogart, P. Submitted. Sediment Connectivity: A Framework for Understanding Sediment Transfer at Multiple Scales. Earth Surface Processes and Landforms. Cerdà, A., Brazier, R., Nearing, M., and de Vente, J. 2012. scales and erosion. Catena, 102, 1-2. doi:10.1016/j.catena.2011.09.006 Parsons A.J., Bracken L., Peoppl , R., Wainwright J., Keesstra, S.D., 2015. Editorial: Introduction to special issue on connectivity in water and sediment dynamics. In press in Earth Surface Processes and Landforms. DOI: 10.1002/esp.3714

Today's sediment budget of the Rhine River channel, focusing on the Upper Rhine Graben and Rhenish Massif

NASA Astrophysics Data System (ADS)

Frings, Roy M.; Gehres, Nicole; Promny, Markus; Middelkoop, Hans; Schüttrumpf, Holger; Vollmer, Stefan

2014-01-01

The river bed of the Rhine River is subject to severe erosion and sedimentation. Such high geomorphological process rates are unwanted for economical, ecological, and safety reasons. The objectives of this study were (1) to quantify the geomorphological development of the Rhine River between 1985 and 2006; (2) to investigate the bed erosion process; and (3) to distinguish between tectonic, hydrological, and human controls. We used a unique data set with thousands of bedload and suspended-load measurements and quantified the fluxes of gravel, sand, silt, and clay through the northern Upper Rhine Graben and the Rhenish Massif. Furthermore, we calculated bed level changes and evaluated the sediment budget of the channel. Sediment transport rates were found to change in the downstream direction: silt and clay loads increase because of tributary supply; sand loads increase because of erosion of sand from the bed; and gravel loads decrease because of reduced sediment mobility caused by the base-level control exerted by the uplifting Rhenish Massif. This base-level control shows tectonic setting, in addition to hydrology and human interventions, to represent a major control on morphodynamics in the Rhine. The Rhine bed appears to be in a state of disequilibrium, with an average net bed degradation of 3 mm/a. Sand being eroded from the bed is primarily washed away in suspension, indicating a rapid supply of sand to the Rhine delta. The degradation is the result of an increased sediment transport capacity caused by nineteenth and twentieth century's river training works. In order to reduce degradation, huge amounts of sediment are fed into the river by river managers. Bed degradation and artificial sediment feeding represent the major sources of sand and gravel to the study area; only small amounts of sediment are supplied naturally from upstream or by tributaries. Sediment sinks include dredging, abrasion, and the sediment output to the downstream area. Large uncertainties exist about the amounts of sediment deposited on floodplains and in groyne fields. Compared to the natural situation during the middle Holocene, the present-day gravel and sand loads seem to be lower, whereas the silt and clay loads seem to be higher. This is probably caused by the present-day absence of meander migration, the deforestation, and the reduced sediment trapping efficiency of the floodplains. Even under natural conditions no equilibrium bed level existed.

Rate of strontium sorption and the effects of variable aqueous concentrations of sodium and potassium on strontium distribution coefficients of a surficial sediment at the Idaho National Engineering Laboratory, Idaho

USGS Publications Warehouse

Bunde, R.L.; Rosentreter, J.J.; Liszewski, M.J.

1998-01-01

The rate of strontium sorption and the effects of variable aqueous concentrations of sodium and potassium on strontium sorption were measured as part of an investigation to determine strontium chemical transport properties of a surficial sediment at the Idaho National Engineering Laboratory (INEL), Idaho. Batch experimental techniques were used to determine the rate of strontium sorption and strontium distribution coefficients (K(d)s) between aqueous and solid phases. Rate experiments indicate that strontium in solution reached an apparent equilibrium with the sediment in 26 h. K(d)s were derived using the linear isotherm model at initial sodium concentrations from 100 to 5,000 mg/l and initial potassium concentrations from 2 to 150 mg/l. K(d)s ranged from 56 ?? 2 to 62 ?? 3 ml/g at initial aqueous concentrations of sodium and potassium equal to or less than 300 and 150 mg/l, respectively. K(d)s hinged from 4.7 ?? 0.2 to 19 ?? 1 ml/g with initial aqueous concentrations of sodium between 1,000 and 5,000 mg/l. These data indicate that sodium concentrations greater than 300 mg/l in wastewater increase the availability of strontium for transport beneath waste disposal ponds at the INEL by decreasing strontium sorption on the surficial sediment. Wastewater concentrations of sodium and potassium less than 300 and 150 mg/l, respectively, have little effect on the availability of strontium for transport.The rate of strontium sorption and the effects of variable aqueous concentrations of sodium and potassium on strontium sorption were measured as part of an investigation to determine strontium chemical transport properties of a surficial sediment at the Idaho National Engineering Laboratory (INEL), Idaho. Batch experimental techniques were used to determine the rate of strontium sorption and strontium distribution coefficients (Kds) between aqueous and solid phases. Rate experiments indicate that strontium in solution reached an apparent equilibrium with the sediment in 26 h. Kds were derived using the linear isotherm model at initial sodium concentrations from 100 to 5,000 mg/l and initial potassium concentrations from 2 to 150 mg/l. Kds ranged from 56??2 to 62??3 ml/g at initial aqueous concentrations of sodium and potassium equal to or less than 300 and 150 mg/l, respectively. Kds ranged from 4.7??0.2 to 19??1 ml/g with initial aqueous concentrations of sodium between 1,000 and 5,000 mg/l. These data indicate that sodium concentrations greater than 300 mg/l in wastewater increase the availability of strontium for transport beneath waste disposal ponds at the INEL by decreasing strontium sorption on the surficial sediment. Wastewater concentrations of sodium and potassium less than 300 and 150 mg/l, respectively, have little effect on the availability of strontium for transport.

Impact of Slow-Rate Land Treatment on Groundwater Quality, Toxic Organics

DTIC Science & Technology

1984-12-01

environmentally significant or mobile in tween the soil or sediment partition coefficient the soil solution . and the partitiop coafficien: for the same sub... soil solution in equi- ment particles and have found a strong correlation librium with an eqaal mass of soil material: between the extent of sorption...then the equilibrium soil solution concen- Pentachlorophenol 2 tration is 0.021 ppm (mg/L). Of a total mass of z m-Nitrotoluene 3 "added to an equal

Comments on some novel approaches for the determination of micellar aggregation numbers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kratohvil, J.P.

1980-05-01

Micellar aggregation numbers of sodium dodecyl sulfates in water and at several concentrations of soidum chloride from several recent papers and from earlier literature have been critically evaluated. The data of D.A. Doughty (J. Phys. Chem. 83, 2621, 1979) based on sedimentation equilibrium and H.F. Huisman (Proc. Kon. Ned. Akad. Wetensch. B 67, 367, 376, 388, 407, 1964) from intensity light scattering are recommended as standared reference data for sodium dodecyl sulfate. 37 references.

Impact of sedimentation on wetland carbon sequestration in an agricultural watershed.

PubMed

McCarty, Gregory; Pachepsky, Yakov; Ritchie, Jerry

2009-01-01

Landscape redistribution of soil C is common within agricultural ecosystems. Little is known about the effects of upland sediment deposition on C dynamics within riparian wetlands. To assess sedimentation impact, we obtained profile samples of wetland soil and used the combination of (137)Cs, (210)Pb, and (14)C chronological markers to determine rates of C sequestration and mineral deposition over the history of a wetland within a first-order catchment under agricultural management in the coastal plains of the United States. Substantial post settlement deposition in the wetland soil was evidenced in places by a 20- to 40-cm layer of mineral soil that buried the original histosol. Soil profiles contained a minimum in C content within the top 35 cm of the profile which originated from a rapid deposition from low C upland soils. Radiocarbon and radioisotope dating showed that increases in C above this minimum were the result of C sequestered in the past approximately 50 yr. Modeling the kinetics of modern C dynamics using the (137)Cs and (210)Pb markers within these surface profiles provides strong evidence for accelerated C sequestration associated with mineral sediment deposition in the ecosystem. These findings indicate that at the landscape scale, dilution of ecosystem C by import of low C upland sediment into wetlands stimulates C sequestration by pulling soil C content below some pedogenic equilibrium value for the ecosystem. They also indicate that over the history of the wetland, rates of C accretion may be linked to mineral soil deposition.

Mudflat morphodynamics and the impact of sea level rise in South San Francisco Bay

USGS Publications Warehouse

Van der Wegen, Mick; Jaffe, Bruce E.; Foxgrover, Amy C.; Roelvink, Dano

2017-01-01

Estuarine tidal mudflats form unique habitats and maintain valuable ecosystems. Historic measurements of a mudflat in San Fancsico Bay over the past 150 years suggest the development of a rather stable mudflat profile. This raises questions on its origin and governing processes as well as on the mudflats’ fate under scenarios of sea level rise and decreasing sediment supply. We developed a 1D morphodynamic profile model (Delft3D) that is able to reproduce the 2011 measured mudflat profile. The main, schematised, forcings of the model are a constant tidal cycle and constant wave action. The model shows that wave action suspends sediment that is transported landward during flood. A depositional front moves landward until landward bed levels are high enough to carry an equal amount of sediment back during ebb. This implies that, similar to observations, the critical shear stress for erosion is regularly exceeded during the tidal cycle and that modelled equilibrium conditions include high suspended sediment concentrations at the mudflat. Shear stresses are highest during low water, while shear stresses are lower than critical (and highest at the landward end) along the mudflat during high water. Scenarios of sea level rise and decreasing sediment supply drown the mudflat. In addition, the mudflat becomes more prone to channel incision because landward accumulation is hampered. This research suggests that sea level rise is a serious threat to the presence of many estuarine intertidal mudflats, adjacent salt marshes and their associated ecological values.

Modelling the diffusive transport and remobilisation of 137Cs in sediments: The effects of sorption kinetics and reversibility

NASA Astrophysics Data System (ADS)

Smith, J. T.; Comans, R. N. J.

1996-03-01

In determining the mobility of ions in sediments it is important to take account of the solid phase sorption and speciation. Measurements were made of activity depth profiles of 137Cs from fallout from Nuclear Weapons Testing and from the Chernobyl accident in two lake sediments. The fraction of 137Cs in the aqueous, exchangeably sorbed and "fixed" phases was determined at each depth interval. A model was developed to simulate the transport of 137Cs in these sediments, taking account of changes in sorption properties as the concentration of the competing ammonium ion changes with depth, as well as transfers of activity to less-exchangeable sites on the solids. The model simulations give reasonable agreement with experimental data, and the fitted rate constant for slow transfers to less-exchangeable sites ( T1/2 = 50-125 d) is in agreement with independent measurements. The modelling gave evidence for a reverse reaction from less-exchangeable to exchangeable sites with a half-life of order 10 y. Model results were compared with those generated by a physical mixing model and the standard molecular diffusion model assuming equilibrium sorption to the solid phase. Estimates were made of the remobilisation of Chernobyl 137Cs from these sediments to the water column: predicted rates vary from around 3% of the inventory per year 2 years after the fallout event to 0.04% per year 30 years after the fallout.

Fluvial drainage networks: the fractal approach as an improvement of quantitative geomorphic analyses

NASA Astrophysics Data System (ADS)

Melelli, Laura; Liucci, Luisa; Vergari, Francesca; Ciccacci, Sirio; Del Monte, Maurizio

2014-05-01

Drainage basins are primary landscape units for geomorphological investigations. Both hillslopes and river drainage system are fundamental components in drainage basins analysis. As other geomorphological systems, also the drainage basins aim to an equilibrium condition where the sequence of erosion, transport and sedimentation approach to a condition of minimum energy effort. This state is revealed by a typical geometry of landforms and of drainage net. Several morphometric indexes can measure how much a drainage basin is far from the theoretical equilibrium configuration, revealing possible external disarray. In active tectonic areas, the drainage basins have a primary importance in order to highlight style, amount and rate of tectonic impulses, and morphometric indexes allow to estimate the tectonic activity classes of different sectors in a study area. Moreover, drainage rivers are characterized by a self-similarity structure; this promotes the use of fractals theory to investigate the system. In this study, fractals techniques are employed together with quantitative geomorphological analysis to study the Upper Tiber Valley (UTV), a tectonic intermontane basin located in northern Apennines (Umbria, central Italy). The area is the result of different tectonic phases. From Late Pliocene until present time the UTV is strongly controlled by a regional uplift and by an extensional phase with different sets of normal faults playing a fundamental role in basin morphology. Thirty-four basins are taken into account for the quantitative analysis, twenty on the left side of the basin, the others on the right side. Using fractals dimension of drainage networks, Horton's laws results, concavity and steepness indexes, and hypsometric curves, this study aims to obtain an evolutionary model of the UTV, where the uplift is compared to local subsidence induced by normal fault activity. The results highlight a well defined difference between western and eastern tributary basins, suggesting a greater disequilibrium in the last ones. The quantitative analysis points out the segments of the basin boundaries where the fault activity is more efficient and the resulting geomorphological implications.

Determinants of Shallow Groundwater As Variability in Bangladesh

NASA Astrophysics Data System (ADS)

Radloff, K. A.; Zheng, Y.; Stute, M.; Rahman, M.; Mihajlov, I.; Siu, H.; Huq, M.; Choudhury, I.; Ahmed, K.; van Geen, A.

2010-12-01

Manually operated tube wells that tap into shallow aquifers remain a critical source of untreated drinking water in south Asia and an estimated 37 million people are still exposed to elevated levels of As in Bangladesh(1). This field effort sought to address two questions. What mechanisms control the partitioning of As between groundwater and sediment? How does groundwater transport affect the spatial variability of dissolved As? Understanding the source of groundwater variability is essential for understanding how [As] will change with time, especially as Bangladesh and its water demands develop. Arsenic mobility and transport within the shallow aquifer was investigated at a 0.5 km2 site where [As] increases from <5 to 600 μg/L over 300 m as the aquifer becomes increasingly reducing. Aquifer recharge occurs in the raised, sandy village, where low [As] and elevated [SO4] are found. Until a few years ago, the net groundwater flow extended from the village, beneath a thickening silty layer covered by agricultural fields, towards a small stream. The sediments, however, were a homogenous, highly reduced sand throughout the site. Arsenic adsorption along this transect was investigated by two different approaches. Despite the geochemical gradients along the transect, adsorption of As under anaerobic conditions measured by spiking freshly collected sediment was remarkably uniform: Kd = 1.5 ± 0.5 L/kg, at 14 of 15 locations. Push- pull tests were used to alter groundwater [As] surrounding a well, without disturbing the sediment. The aquifer responded to the imposed dis-equilibrium by either adsorbing or desorbing As within a few days. These results provide further evidence that groundwater [As] is controlled by As sorption reactions with the sediment that reach equilibrium rapidly compared to the time scale of groundwater flow. A simple reactive-transport model for the site based on the measured partitioning coefficient, Kd, however, supports the notion that the [As] gradient observed reflects the gradual removal of As by groundwater flow over hundreds to thousands of years. The onset of irrigation and industrial pumping at this site has induced a reversal in flow, consequently groundwater now moves from high [As] into low [As] areas. This change could result in rising [As] to levels >50 μg/L in the village within the next few decades. The rapid economic development of Bangladesh could induce similar changes in groundwater flow, and thus As concentrations, elsewhere. This suggests that periodic monitoring of shallow wells low in As within regions of where the As content of groundwater is variable is particularly important. The size of the pool of As adsorbed on the sediment also indicates that current attempts to flush Bangladeshi aquifers “clean” through increased pumping will likely be ineffective. 1. BBS/UNICEF. Bangladesh: Multiple Indicator Cluster Survey, 2009. (Dhaka, Bangladesh, 2009).

Solute profiles in soils, weathering gradients and exchange equilibrium/disequilibrium

USGS Publications Warehouse

White, A.F.; Schulz, M.S.; Stonestrom, David A.; Vivit, D.V.; Fitzpatrick, J.; Bullen, T.

2008-01-01

The spatial and temporal changes in hydrology and pore water elemental and 87/86Sr compositions were used to determine contemporary weathering rates in a 65 to 226 ky old soil chronosequence formed from granitic sediments deposited on marine terraces along coastal California. Cl-corrected Na, K and Si increased with depth denoting inputs from the weathering of plagioclase and K-feldspar. Solute 87/86Sr exhibited progressive mixing of sea water-dominated precipitation with inputs from less radiogenic plagioclase. Linear approximations to these weathering gradients were used to determine plagioclase weathering rates of between 0.38 and 8.9×10−15 moles m−2 s−1. The lack of corresponding weathering gradients for Ca and Sr indicated short-term equilibrium with the clay ion exchange pool which requires periodic resetting by natural perturbations to maintain continuity, in spite of soil composition changes reflecting the effects of long-term weathering.

Decoupling of mass flux and turbulent wind fluctuations in drifting snow

NASA Astrophysics Data System (ADS)

Paterna, E.; Crivelli, P.; Lehning, M.

2016-05-01

The wind-driven redistribution of snow has a significant impact on the climate and mass balance of polar and mountainous regions. Locally, it shapes the snow surface, producing dunes and sastrugi. Sediment transport has been mainly represented as a function of the wind strength, and the two processes assumed to be stationary and in equilibrium. The wind flow in the atmospheric boundary layer is unsteady and turbulent, and drifting snow may never reach equilibrium. Our question is therefore: what role do turbulent eddies play in initiating and maintaining drifting snow? To investigate the interaction between drifting snow and turbulence experimentally, we conducted several wind tunnel measurements of drifting snow over naturally deposited snow covers. We observed a coupling between snow transport and turbulent flow only in a weak saltation regime. In stronger regimes it self-organizes developing its own length scales and efficiently decoupling from the wind forcing.

Sediment budgets for glacier forefields (Pasterze & Obersulzbachkees, Upper Tauern, Austria) - quantification and temporal variability

NASA Astrophysics Data System (ADS)

Geilhausen, M.; Otto, J.-C.; Schrott, L.

2009-04-01

In the context of Global Climate Change, magnitudes and frequencies of geomorphic processes are subject to climatic controlled variations leading to significant modifications in land surface topography. A sediment budget approach identifies and quantifies sediment transfer processes and sediment storages and clarifies to what extent these system components are coupled to each other. The relationship between sediment storage volumes and present-day sediment transfer rates can contribute to both, an understanding of previous (postglacial) landscape development and the prediction of future topographic evolution. As retreating Alpine glaciers expose landscapes with partly unconsolidated, loose and potentially unstable landforms (e.g. moraine slopes), which are not in equilibrium with changing environmental conditions, glacier forefields react very sensible to climate change and therefore are susceptible to rapid topographic modification. Due to this accelerated, paraglacial geomorphodynamic, sediment budget studies on relative short time scales within glacier forefield landsystems are of specific scientific interest. Within the collaborative research project SedyMONT (Timescales of Sediment Dynamics, Climate and Topographic Change in Mountain Environments, ESF Top Europe programme), these issues are concerned by an individual project of the University of Salzburg. This paper points out the conceptual approach, aims and objectives of this ongoing research project and presents first results within the glacier forefield of the Pasterze. The methodical approach includes orthophoto-interpretation, geomorphological mapping, GIS analyses and a combination of field geophysics (ERT, GPR, RST) in order to identify sediment storages, sediment transfer processes as well as thickness, volumes and internal structures of sediment bodies. Present sediment fluxes will be monitored by a number of different measurements, including hydrological methods (valley bottom) and repeated terrestrial laser scanning (valley bottom and slope processes). The outcomes of the project are i) a high temporarily resoluted data in a proglacial area with rapidly changing sediment budget conditions, ii) the integration of present day fluxes and temporarily stored sediments, and iii) the validation of existing models of landscape development (paraglacial sedimentation). The study site Pasterze is a former lake that has been completely filled up by continuous glacifluvial sedimentation. The glacial melt water stream is the dominant path of sediment transfer through the sandur system. The mean sediment thickness is approx. 6.15 m leading to a calculated volume and mass of 785.700 m³ respectively 1.571.400 t stored in the forefield. More than 50.000 t of suspended load produced by glacial erosion were passed the system in 2006.Compared to channel processes, slope processes play a minor role and sediment input through avalanches, rock falls and debris flows seems to be negligible. Furthermore it is remarkable, that no significant clastic output (bed load) has occurred in 2006 at the outlet of the sandur. The system therefore appears to be partially closed.

Interactions between landslides and landscape evolution using a sediment flux-dependent bedrock incision model incorporating bed macro-roughness

NASA Astrophysics Data System (ADS)

Kwang, J. S.; Parker, G.

2017-12-01

Many landscape evolution models incorporate sediment removal as a quasi-equilibrium process via the Stream Power Incision Model, or otherwise incorporate sediment supply to mixed bedrock-alluvial channels according to a quasi-steady relation between channel incision and hillslope production. Yet in actively uplifting landscapes, hillslope production is often a highly punctuated phenomenon governed by landslides. We investigate the following key question: how does a landscape subject to punctuated sediment supply differ from one with a steady supply at the same rate? To do this, we incorporate punctuated supply into the Macro Roughness Saltation Abrasion Alluviation model [Zhang et al., 2015], a descendant of the Capacity Saltation Abrasion model [Sklar and Dietrich, 2004, 2006], that is specifically designed to capture unsteady alluvial morphodynamics. Our model has three modules: a) a bedrock-alluvial channel module, b) a hillslope diffusion module, and c) a stochastically-driven landslide supply module. Sediment in bedrock channels plays two roles in incision: 1) as an abrasive agent that incises the bed via collisions and 2) as a protector that inhibits collisions of sediment on the bed. The abrasion rate is proportional to a bedload transport rate times the areal fraction of bedrock surface that is exposed. The transport rate is equal to the capacity transport rate times the areal fraction of bedrock surface that is covered with alluvium, i.e. cover factor. Here, the incision rate vanishes with either vanishing cover (no tools) or complete cover (no bedrock exposed for abrasion). The properties of and amount of sediment delivered to the channel heavily depend on hillslope dynamics. Therefore, hillslope dynamics are important in determining the rate of incision of bedrock channels. Conversely, bedrock incision drives the production of sediment by lowering the base of hillslopes, creating a feedback. We explore this feedback in our landscape evolution model by adjusting our landslide model so that it supplies sediment at a steady rate or according to a stochastic algorithm chosen to characterize landslide size and frequency in such settings as Taiwan or Sichuan near the 2008 Wenchuan Earthquake epicenter. We use our model to study the signature of punctuated sediment delivery on the landscape.

Response and recovery of streams to an intense regional flooding event

NASA Astrophysics Data System (ADS)

Dethier, E.; Magilligan, F. J.; Renshaw, C. E.; Kantack, K. M.

2015-12-01

Determining the relative roles of frequent and infrequent events on landscape form and material transport has implications for understanding landscape development, and informs planning and infrastructure decisions. Flooding due to Tropical Storm Irene in 2011 provides a unique opportunity to examine the effects of a rare, major disturbance across a broad area (14,000 km2). Intense flooding caused variable but widespread channel and riparian reconfiguration, including 995 channel-adjacent mass-wasting events, collectively referred to here as landslides, that mostly occurred in glacial deposits. Of these, about half involved reactivation of existing scars. Landslides were generally small, ranging from 60 - 26,000 m2 in planform, and covered less than 0.01 % of land in the region, yet sediment input from landslides alone (131 mm/kyr when integrated over the study area) exceeded inferred local background erosion rates by 60 times. If Irene inputs are included in a thirty-year erosion record, the estimated erosion rate, 7.2 mm/kyr, aligns closely with long-term regional rates of 5-10 mm/kyr. Landslides also input trees to streams, increasing large wood influence on those reaches. Combined wood and sediment inputs contributed to channel changes downstream of landslides. In four years since Irene, terrestrial lidar and suspended sediment sampling has documented continued large wood and sediment input. Erosion occurred on each of seventeen monitored landslides during snowmelt, but is otherwise limited except during intense precipitation and/or flood events. Repeat lidar models have recorded erosion of up to 5,000 m3 on a single slide in one year, including as much as 4000 m3 during a single event. Tree fall on scarps during erosion events creates sediment traps at the base of landslides, contributing to an observed return to equilibrium slopes. Despite trapping, substantial sediment continues to enter streams. Ninety-five suspended sediment samples from forty sites show that landslides remain important sediment sources. Across a range of flows, 2014 - 2015 sediment flux for a given discharge is an order of magnitude higher than pre-Irene flux. Though landslide slope relaxation suggests incipient recovery from Irene, persistent rapid erosion of large wood and sediment indicates that recovery is still on-going.

Simulation Studies to Explore Biodegradation in Water-Sediment Systems: From OECD 308 to OECD 309.

PubMed

Shrestha, Prasit; Junker, Thomas; Fenner, Kathrin; Hahn, Stefan; Honti, Mark; Bakkour, Rani; Diaz, Cecilia; Hennecke, Dieter

2016-07-05

Studies according to OECD 308 and OECD 309 are performed to simulate the biodegradation of chemicals in water-sediment systems in support of persistence assessment and exposure modeling. However, several shortcomings of OECD 308 have been identified that hamper data evaluation and interpretation, and its relation to OECD 309 is still unclear. The present study systematically compares OECD 308 and OECD 309 and two variants thereof to derive recommendations on how to experimentally address any shortcomings and improve data for persistence and risk assessment. To this end, four (14)C-labeled compounds with different biodegradation and sorption behavior were tested across standard OECD 308 and 309 test systems and two modified versions thereof. The well-degradable compounds showed slow equilibration and the least mineralization in OECD 308, whereas the modified systems provided the highest degree of mineralization. Different lines of evidence suggest that this was due to increased oxygenation of the sediment in the modified systems. Particularly for rapidly degrading compounds, non-extractable residue formation was in line with degradation and did not follow the sediment-water ratio. For the two more slowly degrading compounds, sorption in OECD 309 (standard and modified) increased with time beyond levels proposed by equilibrium partitioning, which could be attributed to the grinding of the sediment through the stirring of the sediment suspension. Overall, the large differences in degradation observed across the four test systems suggest that refined specifications in test guidelines are required to reduce variability in test outcomes. At the same time, the amount of sediment and its degree of oxygenation emerged as drivers across all test systems. This suggests that a unified description of the systems was possible and would pave the way toward a more consistent consideration of degradation in the water-sediment systems across different exposure situations and regulatory frameworks.

Passive sampling methods for contaminated sediments: State of the science for metals

PubMed Central

Peijnenburg, Willie JGM; Teasdale, Peter R; Reible, Danny; Mondon, Julie; Bennett, William W; Campbell, Peter GC

2014-01-01

“Dissolved” concentrations of contaminants in sediment porewater (Cfree) provide a more relevant exposure metric for risk assessment than do total concentrations. Passive sampling methods (PSMs) for estimating Cfree offer the potential for cost-efficient and accurate in situ characterization of Cfree for inorganic sediment contaminants. In contrast to the PSMs validated and applied for organic contaminants, the various passive sampling devices developed for metals, metalloids, and some nonmetals (collectively termed “metals”) have been exploited to a limited extent, despite recognized advantages that include low detection limits, detection of time-averaged trends, high spatial resolution, information about dissolved metal speciation, and the ability to capture episodic events and cyclic changes that may be missed by occasional grab sampling. We summarize the PSM approaches for assessing metal toxicity to, and bioaccumulation by, sediment-dwelling biota, including the recognized advantages and limitations of each approach, the need for standardization, and further work needed to facilitate broader acceptance and application of PSM-derived information by decision makers. Integr Environ Assess Manag 2014;10:179–196. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. Key Points Passive sampling methods (PSMs) offer the potential for cost-efficient and accurate in situ characterization of the dissolved concentrations for inorganic sediment contaminants. PSMs are useful for evaluating the geochemical behavior of metals in surficial sediments, including determination of fluxes across the sediment-water interface, and post-depositional changes in metal speciation. Few studies have tried to link PSM responses in sediments to metal uptake and toxicity responses in benthic organisms. There is a clear need for further studies. Future PSMs could be designed to mimic saturable kinetics, which would fill the gap between the kinetic and the equilibrium regime samplers currently used, and may improve prediction of metals accumulation by benthic organisms. PMID:24470168

Sediment-phosphorus dynamics can shift aquatic ecology and cause downstream legacy effects after wildfire in large river systems.

PubMed

Emelko, Monica B; Stone, Micheal; Silins, Uldis; Allin, Don; Collins, Adrian L; Williams, Chris H S; Martens, Amanda M; Bladon, Kevin D

2016-03-01

Global increases in the occurrence of large, severe wildfires in forested watersheds threaten drinking water supplies and aquatic ecology. Wildfire effects on water quality, particularly nutrient levels and forms, can be significant. The longevity and downstream propagation of these effects as well as the geochemical mechanisms regulating them remain largely undocumented at larger river basin scales. Here, phosphorus (P) speciation and sorption behavior of suspended sediment were examined in two river basins impacted by a severe wildfire in southern Alberta, Canada. Fine-grained suspended sediments (<125 μm) were sampled continuously during ice-free conditions over a two-year period (2009-2010), 6 and 7 years after the wildfire. Suspended sediment samples were collected from upstream reference (unburned) river reaches, multiple tributaries within the burned areas, and from reaches downstream of the burned areas, in the Crowsnest and Castle River basins. Total particulate phosphorus (TPP) and particulate phosphorus forms (nonapatite inorganic P, apatite P, organic P), and the equilibrium phosphorus concentration (EPC0 ) of suspended sediment were assessed. Concentrations of TPP and the EPC0 were significantly higher downstream of wildfire-impacted areas compared to reference (unburned) upstream river reaches. Sediments from the burned tributary inputs contained higher levels of bioavailable particulate P (NAIP) - these effects were also observed downstream at larger river basin scales. The release of bioavailable P from postfire, P-enriched fine sediment is a key mechanism causing these effects in gravel-bed rivers at larger basin scales. Wildfire-associated increases in NAIP and the EPC0 persisted 6 and 7 years after wildfire. Accordingly, this work demonstrated that fine sediment in gravel-bed rivers is a significant, long-term source of in-stream bioavailable P that contributes to a legacy of wildfire impacts on downstream water quality, aquatic ecology, and drinking water treatability. © 2015 John Wiley & Sons Ltd.

Simulating the evolution of coastal morphology and stratigraphy with a new morphological-behaviour model (GEOMBEST)

USGS Publications Warehouse

Stolper, D.; List, J.H.; Thieler, E.R.

2005-01-01

A new morphological-behaviour model is used to simulate evolution of coastal morphology associated with cross-shore translations of the shoreface, barrier, and estuary. The model encapsulates qualitative principles drawn from established geological concepts that are parameterized to provide quantitative predictions of morphological change on geological time scales (order 10 3 years), as well as shorter time scales applicable for long-term coastal management (order 101 to 102 years). Changes in sea level, and sediment volume within the shoreface, barrier, and estuary, drive the model behaviour. Further parameters, defining substrate erodibility, sediment composition, and time-dependent shoreface response, constrain the evolution of the shoreface towards an equilibrium profile. Results from numerical experiments are presented for the low-gradient autochthonous setting of North Carolina and the steep allochthonous setting of the Washington shelf. Simulations in the Currituck region of North Carolina examined the influence of sediment supply, substrate composition, and substrate erodibility on barrier transgression. Results demonstrate that the presence of a lithified substrate reduces the rate of barrier transgression compared to scenarios where an erodible, sand-rich substrate exists. Simulations of the Washington coast, 20 km north of the Columbia River, confirmed that the model can reproduce complex stratigraphy involving regressive and transgressive phases of coastal evolution. Results suggest that the first major addition of sediment to the shelf occurred around 12 900 years ago and resulted from the rapid addition of sediment volume from the Columbia River attributed to the Missoula floods. This was followed by a period where little or no sediment was added (12 400-9100 BP) and a third period when most sediment was added to the shelf (9100 BP to present) from the Columbia River. Comparing results from each setting demonstrates an indirect control that substrate slope has on shoreface transgression rates. Shoreface transgression is shown to be sensitive to the rate of estuarine sedimentation, with the sensitivity increasing as substrate slope decreases. 

A sandpile model of grain blocking and consequences for sediment dynamics in step-pool streams

NASA Astrophysics Data System (ADS)

Molnar, P.

2012-04-01

Coarse grains (cobbles to boulders) are set in motion in steep mountain streams by floods with sufficient energy to erode the particles locally and transport them downstream. During transport, grains are often blocked and form width-spannings structures called steps, separated by pools. The step-pool system is a transient, self-organizing and self-sustaining structure. The temporary storage of sediment in steps and the release of that sediment in avalanche-like pulses when steps collapse, leads to a complex nonlinear threshold-driven dynamics in sediment transport which has been observed in laboratory experiments (e.g., Zimmermann et al., 2010) and in the field (e.g., Turowski et al., 2011). The basic question in this paper is if the emergent statistical properties of sediment transport in step-pool systems may be linked to the transient state of the bed, i.e. sediment storage and morphology, and to the dynamics in sediment input. The hypothesis is that this state, in which sediment transporting events due to the collapse and rebuilding of steps of all sizes occur, is analogous to a critical state in self-organized open dissipative dynamical systems (Bak et al., 1988). To exlore the process of self-organization, a cellular automaton sandpile model is used to simulate the processes of grain blocking and hydraulically-driven step collapse in a 1-d channel. Particles are injected at the top of the channel and are allowed to travel downstream based on various local threshold rules, with the travel distance drawn from a chosen probability distribution. In sandpile modelling this is a simple 1-d limited non-local model, however it has been shown to have nontrivial dynamical behaviour (Kadanoff et al., 1989), and it captures the essence of stochastic sediment transport in step-pool systems. The numerical simulations are used to illustrate the differences between input and output sediment transport rates, mainly focussing on the magnification of intermittency and variability in the system response by the processes of grain blocking and step collapse. The temporal correlation in input and output rates and the number of grains stored in the system at any given time are quantified by spectral analysis and statistics of long-range dependence. Although the model is only conceptually conceived to represent the real processes of step formation and collapse, connections will be made between the modelling results and some field and laboratory data on step-pool systems. The main focus in the discussion will be to demonstrate how even in such a simple model the processes of grain blocking and step collapse may impact the sediment transport rates to the point that certain changes in input are not visible anymore, along the lines of "shredding the signals" proposed by Jerolmack and Paola (2010). The consequences are that the notions of stability and equilibrium, the attribution of cause and effect, and the timescales of process and form in step-pool systems, and perhaps in many other fluvial systems, may have very limited applicability.

An Organochronology and Deep History of a North Carolina Tidal Marsh

NASA Astrophysics Data System (ADS)

Morris, J. T.; Kemp, A.; Horton, B.

2016-12-01

Tidal marshes have survived for millennia in a dynamic equilibrium with sea level. A record of their history can be found in the sediments underlying modern marshes. Since the industrial revolution the rate of relative sea-level rise has been increasing and the equilibrium is changing. To reconstruct the history of these marshes we analyzed a 1000 year record of soil organic matter content (SOM) from Tump Point, Cedar Island, North Carolina. SOM concentration is a function of the standing biomass at the time of its creation, its subsequent preservation, and annual input of inorganic matter. SOM and inorganic concentration determine the soil bulk density and volume. The standing biomass, sediment organic matter input, and consequent carbon sequestration are functions of hydroperiod or, by proxy, the paleo-marsh elevation (PME) below mean high water. The annual input of inorganic matter is determined by the depth, duration, and frequency of flooding, concentration of total suspended solids (TSS), and settling velocity. Using an inverse modeling technique we were able to solve the Marsh Equilibrium Model (MEM) for PME and relative sea level that would have resulted in the observed SOM chronologies. The TSS was inferred from the accretion rates derived from dated core sections. Consistent with foraminifera-derived relative sea-level reconstructions, the MEM-derived rate of SLR doubled after 1700 CE compared with the previous 900 years, and the PME has declined and is approaching the lower limit of the vegetation. We estimate that C-sequestration prior to 1260 varied between 15 and 40 (average 30) g C m-2 y-1, but has since declined to a range of 5 to 33 (average 16) g C m-2 y-1. The decline in carbon sequestration can be attributed to the acceleration in rate of sea-level rise and is a trend that probably will characterize most tidal wetlands in the future.

Characterizing particle-scale equilibrium adsorption and kinetics of uranium(VI) desorption from U-contaminated sediments

USGS Publications Warehouse

Stoliker, Deborah L.; Liu, Chongxuan; Kent, Douglas B.; Zachara, John M.

2013-01-01

Rates of U(VI) release from individual dry-sieved size fractions of a field-aggregated, field-contaminated composite sediment from the seasonally saturated lower vadose zone of the Hanford 300-Area were examined in flow-through reactors to maintain quasi-constant chemical conditions. The principal source of variability in equilibrium U(VI) adsorption properties of the various size fractions was the impact of variable chemistry on adsorption. This source of variability was represented using surface complexation models (SCMs) with different stoichiometric coefficients with respect to hydrogen ion and carbonate concentrations for the different size fractions. A reactive transport model incorporating equilibrium expressions for cation exchange and calcite dissolution, along with rate expressions for aerobic respiration and silica dissolution, described the temporal evolution of solute concentrations observed during the flow-through reactor experiments. Kinetic U(VI) desorption was well described using a multirate SCM with an assumed lognormal distribution for the mass-transfer rate coefficients. The estimated mean and standard deviation of the rate coefficients were the same for all <2 mm size fractions but differed for the 2–8 mm size fraction. Micropore volumes, assessed using t-plots to analyze N2 desorption data, were also the same for all dry-sieved <2 mm size fractions, indicating a link between micropore volumes and mass-transfer rate properties. Pore volumes for dry-sieved size fractions exceeded values for the corresponding wet-sieved fractions. We hypothesize that repeated field wetting and drying cycles lead to the formation of aggregates and/or coatings containing (micro)pore networks which provided an additional mass-transfer resistance over that associated with individual particles. The 2–8 mm fraction exhibited a larger average and standard deviation in the distribution of mass-transfer rate coefficients, possibly caused by the abundance of microporous basaltic rock fragments.

CFD analysis of laboratory scale phase equilibrium cell operation

NASA Astrophysics Data System (ADS)

Jama, Mohamed Ali; Nikiforow, Kaj; Qureshi, Muhammad Saad; Alopaeus, Ville

2017-10-01

For the modeling of multiphase chemical reactors or separation processes, it is essential to predict accurately chemical equilibrium data, such as vapor-liquid or liquid-liquid equilibria [M. Šoóš et al., Chem. Eng. Process.: Process Intensif. 42(4), 273-284 (2003)]. The instruments used in these experiments are typically designed based on previous experiences, and their operation verified based on known equilibria of standard components. However, mass transfer limitations with different chemical systems may be very different, potentially falsifying the measured equilibrium compositions. In this work, computational fluid dynamics is utilized to design and analyze laboratory scale experimental gas-liquid equilibrium cell for the first time to augment the traditional analysis based on plug flow assumption. Two-phase dilutor cell, used for measuring limiting activity coefficients at infinite dilution, is used as a test case for the analysis. The Lagrangian discrete model is used to track each bubble and to study the residence time distribution of the carrier gas bubbles in the dilutor cell. This analysis is necessary to assess whether the gas leaving the cell is in equilibrium with the liquid, as required in traditional analysis of such apparatus. Mass transfer for six different bio-oil compounds is calculated to determine the approach equilibrium concentration. Also, residence times assuming plug flow and ideal mixing are used as reference cases to evaluate the influence of mixing on the approach to equilibrium in the dilutor. Results show that the model can be used to predict the dilutor operating conditions for which each of the studied gas-liquid systems reaches equilibrium.

CFD analysis of laboratory scale phase equilibrium cell operation.

PubMed

Jama, Mohamed Ali; Nikiforow, Kaj; Qureshi, Muhammad Saad; Alopaeus, Ville

2017-10-01

For the modeling of multiphase chemical reactors or separation processes, it is essential to predict accurately chemical equilibrium data, such as vapor-liquid or liquid-liquid equilibria [M. Šoóš et al., Chem. Eng. Process Intensif. 42(4), 273-284 (2003)]. The instruments used in these experiments are typically designed based on previous experiences, and their operation verified based on known equilibria of standard components. However, mass transfer limitations with different chemical systems may be very different, potentially falsifying the measured equilibrium compositions. In this work, computational fluid dynamics is utilized to design and analyze laboratory scale experimental gas-liquid equilibrium cell for the first time to augment the traditional analysis based on plug flow assumption. Two-phase dilutor cell, used for measuring limiting activity coefficients at infinite dilution, is used as a test case for the analysis. The Lagrangian discrete model is used to track each bubble and to study the residence time distribution of the carrier gas bubbles in the dilutor cell. This analysis is necessary to assess whether the gas leaving the cell is in equilibrium with the liquid, as required in traditional analysis of such apparatus. Mass transfer for six different bio-oil compounds is calculated to determine the approach equilibrium concentration. Also, residence times assuming plug flow and ideal mixing are used as reference cases to evaluate the influence of mixing on the approach to equilibrium in the dilutor. Results show that the model can be used to predict the dilutor operating conditions for which each of the studied gas-liquid systems reaches equilibrium.

Comparative analysis of several sediment transport formulations applied to dam-break flows over erodible beds

NASA Astrophysics Data System (ADS)

Cea, Luis; Bladé, Ernest; Corestein, Georgina; Fraga, Ignacio; Espinal, Marc; Puertas, Jerónimo

2014-05-01

Transitory flows generated by dam failures have a great sediment transport capacity, which induces important morphological changes on the river topography. Several studies have been published regarding the coupling between the sediment transport and hydrodynamic equations in dam-break applications, in order to correctly model their mutual interaction. Most of these models solve the depth-averaged shallow water equations to compute the water depth and velocity. On the other hand, a wide variety of sediment transport formulations have been arbitrarily used to compute the topography evolution. These are based on semi-empirical equations which have been calibrated under stationary and uniform conditions very different from those achieved in dam-break flows. Soares-Frazao et al. (2012) proposed a Benchmark test consisting of a dam-break over a mobile bed, in which several teams of modellers participated using different numerical models, and concluded that the key issue which still needs to be investigated in morphological modelling of dam-break flows is the link between the solid transport and the hydrodynamic variables. This paper presents a comparative analysis of different sediment transport formulations applied to dam-break flows over mobile beds. All the formulations analysed are commonly used in morphological studies in rivers, and include the formulas of Meyer-Peter & Müller (1948), Wong-Parker (2003), Einstein-Brown (1950), van Rijn (1984), Engelund-Hansen (1967), Ackers-White (1973), Yang (1973), and a Meyer-Peter & Müller type formula but with ad-hoc coefficients. The relevance of corrections on the sediment flux direction and magnitude due to the bed slope and the non-equilibrium hypothesis is also analysed. All the formulations have been implemented in the numerical model Iber (Bladé et al. (2014)), which solves the depth-averaged shallow water equations coupled to the Exner equation to evaluate the bed evolution. Two different test cases have been studied. The first one is the benchmark case presented in Soares-Frazao et al. (2012), and consists in an instanteneous dam-break flow over a sand bed. The second one corresponds to the experimental studies performed at the Engineering Faculty of the UNAM (Fuentes-Mariles et al. (2010)) and consists in the erosion of a volcanic sand dike by an overtopping flow. In both cases experimental measurements of water depth and bed evolution are available to evaluate the performance of different sediment transport formulations. A sensitivity analysis to the physical properties of the bed material (grain density and size) is also presented for each formulation, in order to analyse to which degree the properties of the bed material need to be defined in the numerical model. References Bladé, E., Cea, L., Corestein, G., Escolano, E., Puertas, J., Vázquez-Cendón, M.E., Dolz, J., Coll, A. (2014). Iber: herramienta de simulación numérica del flujo en ríos. Revista Internacional de Métodos Numéricos para Cálculo y Diseño en Ingeniería, Vol.30(1), pp.1-10 Fuentes-Mariles, Ó. A., Cruz-Gerón, J. A., Rivera-Díaz, C., Luna-Cruz, F., and González-Prado, J. (2010). "Caracterización Experimental de Ruptura de Diques." XXIV Congreso Latinoamericano de Hidráulica Soares-Frazão et al. (2012). Dambreak flows over mobile beds: experiments and benchmark tests for numerical models. Journal of Hydraulic Research, Vol.50(4), pp.364-375

U.S. Geological Survey ArcMap Sediment Classification tool

USGS Publications Warehouse

O'Malley, John

2007-01-01

The U.S. Geological Survey (USGS) ArcMap Sediment Classification tool is a custom toolbar that extends the Environmental Systems Research Institute, Inc. (ESRI) ArcGIS 9.2 Desktop application to aid in the analysis of seabed sediment classification. The tool uses as input either a point data layer with field attributes containing percentage of gravel, sand, silt, and clay or four raster data layers representing a percentage of sediment (0-100%) for the various sediment grain size analysis: sand, gravel, silt and clay. This tool is designed to analyze the percent of sediment at a given location and classify the sediments according to either the Folk (1954, 1974) or Shepard (1954) as modified by Schlee(1973) classification schemes. The sediment analysis tool is based upon the USGS SEDCLASS program (Poppe, et al. 2004).

Polymer scaling and dynamics in steady-state sedimentation at infinite Péclet number.

PubMed

Lehtola, V; Punkkinen, O; Ala-Nissila, T

2007-11-01

We consider the static and dynamical behavior of a flexible polymer chain under steady-state sedimentation using analytic arguments and computer simulations. The model system comprises a single coarse-grained polymer chain of N segments, which resides in a Newtonian fluid as described by the Navier-Stokes equations. The chain is driven into nonequilibrium steady state by gravity acting on each segment. The equations of motion for the segments and the Navier-Stokes equations are solved simultaneously using an immersed boundary method, where thermal fluctuations are neglected. To characterize the chain conformation, we consider its radius of gyration RG(N). We find that the presence of gravity explicitly breaks the spatial symmetry leading to anisotropic scaling of the components of RG with N along the direction of gravity RG, parallel and perpendicular to it RG, perpendicular, respectively. We numerically estimate the corresponding anisotropic scaling exponents nu parallel approximately 0.79 and nu perpendicular approximately 0.45, which differ significantly from the equilibrium scaling exponent nue=0.588 in three dimensions. This indicates that on the average, the chain becomes elongated along the sedimentation direction for large enough N. We present a generalization of the Flory scaling argument, which is in good agreement with the numerical results. It also reveals an explicit dependence of the scaling exponents on the Reynolds number. To study the dynamics of the chain, we compute its effective diffusion coefficient D(N), which does not contain Brownian motion. For the range of values of N used here, we find that both the parallel and perpendicular components of D increase with the chain length N, in contrast to the case of thermal diffusion in equilibrium. This is caused by the fluid-driven fluctuations in the internal configuration of the polymer that are magnified as polymer size becomes larger.

Sedimentation Equilibrium of a Small Oligomer-forming Membrane Protein: Effect of Histidine Protonation on Pentameric Stability

PubMed Central

Surya, Wahyu; Torres, Jaume

2015-01-01

Analytical ultracentrifugation (AUC) can be used to study reversible interactions between macromolecules over a wide range of interaction strengths and under physiological conditions. This makes AUC a method of choice to quantitatively assess stoichiometry and thermodynamics of homo- and hetero-association that are transient and reversible in biochemical processes. In the modality of sedimentation equilibrium (SE), a balance between diffusion and sedimentation provides a profile as a function of radial distance that depends on a specific association model. Herein, a detailed SE protocol is described to determine the size and monomer-monomer association energy of a small membrane protein oligomer using an analytical ultracentrifuge. AUC-ES is label-free, only based on physical principles, and can be used on both water soluble and membrane proteins. An example is shown of the latter, the small hydrophobic (SH) protein in the human respiratory syncytial virus (hRSV), a 65-amino acid polypeptide with a single α-helical transmembrane (TM) domain that forms pentameric ion channels. NMR-based structural data shows that SH protein has two protonatable His residues in its transmembrane domain that are oriented facing the lumen of the channel. SE experiments have been designed to determine how pH affects association constant and the oligomeric size of SH protein. While the pentameric form was preserved in all cases, its association constant was reduced at low pH. These data are in agreement with a similar pH dependency observed for SH channel activity, consistent with a lumenal orientation of the two His residues in SH protein. The latter may experience electrostatic repulsion and reduced oligomer stability at low pH. In summary, this method is applicable whenever quantitative information on subtle protein-protein association changes in physiological conditions have to be measured.   PMID:25867485

Massive units deposited by bedload transport in sheet flow mode

NASA Astrophysics Data System (ADS)

Viparelli, E.; Hernandez Moreira, R. R.; Jafarinik, S.; Sanders, S.; Huffman, B.; Parker, G.; Kendall, C.

2017-12-01

A sandy massive (structureless) unit overlying a basal erosional surface and underlying a parallel or cross-laminated unit often characterizes turbidity current and coastal storm deposits. The basal massive units are thought to be the result of relatively rapid deposition of suspended sediment. However, suspension-based models fail to explain how basal massive units can be emplaced for long distances, far away from the source and can contain gravel particles as floating clasts. Here we present experimental results that can significantly change the understanding of the processes forming turbidity current and coastal storm deposits. The experiments were performed in open channel flow mode in the Hydraulics Laboratory at the University of South Carolina. The sediment was a mixture of sand size particles with a geometric mean diameter of 0.95 mm and a geometric standard deviation of 1.65. Five experiments were performed with a flow rate of 30 l/s and sediment feed rates varying between 1.5 kg/min and 20 kg/min. Each experiment was characterized by two phases, 1) the equilibration phase, in which we waited for the system to reach equilibrium condition, and 2) the aggradation phase, in which we slowly raised the water surface base level to induce channel bed aggradation under the same transport conditions observed over the equilibrium bed. Our experiments show that sandy massive units can be the result of deposition from a thick bedload layer of colliding grains, the sheet flow layer. The presence of this sheet flow layer explains how a strong, sustained current can emplace extensive massive units containing gravel clasts. Although our experiments were conducted in open-channel mode, observations of bedload driven by density underflows suggest that our results are directly applicable to sheet flows driven by deep-sea turbidity currents. More specifically, we believe that this mechanism offers an explanation for massive turbidites that heretofore have been identified as the deposits of "high density" turbidity currents.

Biotic and abiotic pathways of phosphorus cycling in minerals and sediments: insights from oxygen isotopes in phosphate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jaisi, Deb P.; Kukkadapu, Ravi K.; Stout, Lisa M.

2011-07-06

A key question to address in the development of oxygen isotope ratios in phosphate (18Op) as a tracer of biogeochemical cycling of phosphorus in ancient and modern environments is the nature of isotopic signatures associated with uptake and cycling of mineral-bound phosphate by microorganisms. Here we present experimental results aimed at understanding the biotic and abiotic pathway of P cycling during biological uptake of phosphate sorbed to ferrihydrite and the selective uptake of specific sedimentary phosphate phases by Escherichia coli, Vibrio fischeri and Marinobacter aquaeolei. Results indicate that a significant fraction of ferrihydrite-bound phosphate is biologically available. The fraction ofmore » phosphate taken up by E. coli attained an equilibrium isotopic composition in a short time (<50 hrs) due to efficient O-isotope exchange between phosphate and water (biotic pathway). The difference in isotopic composition between newly equilibrated aqueous and residual sorbed phosphate promoted the exchange of intact phosphate radicals (abiotic pathway) so that this difference gradually became negligible. In sediment containing different P phases, E. coli and V. fischeri ‘extracted’ loosely sorbed phosphate first while M. aquaeolei preferred iron-oxide bound phosphate. Each bacterium imprinted a biotic isotopic signature on each P phase that it took up and cycled. For example, the 18Op value of the sorbed phosphate phase shifted gradually towards equilibrium isotopic composition and the value of Fe oxide-bound phosphate showed slight changes at first, but when new iron oxides were formed, co-precipitated/occluded phosphate retained 18O values of aqueous phosphate at that time. Concentrations and isotopic compositions of authigenic and detrital phosphates did not change, suggesting that these phosphate phases were not utilized by bacteria. These findings support burgeoning applications of 18Op as a tracer of phosphorus cycling in sediments, soils and aquatic environments and as an indicator of paleo- environmental conditions.« less

Attenuation of landfill leachate by UK Triassic sandstone aquifer materials. 1. Fate of inorganic pollutants in laboratory columns

NASA Astrophysics Data System (ADS)

Thornton, Steven F.; Tellam, John H.; Lerner, David N.

2000-05-01

The attenuation of inorganic contaminants in acetogenic and methanogenic landfill leachate by calcareous and carbonate-deficient, oxide-rich Triassic sandstone aquifer materials from the English Midlands was examined in laboratory columns. Aqueous equilibrium speciation modelling, simple transport modelling and chemical mass balance approaches are used to evaluate the key processes and aquifer geochemical properties controlling contaminant fate. The results indicate that leachate-rock interactions are dominated by ion-exchange processes, acid-base and redox reactions and sorption/precipitation of metal species. Leachate NH 4 is attenuated by cation exchange with the aquifer sediments; however, NH 4 migration could be described with a simple model using retardation factors. Organic acids in the acetogenic leachate buffered the system pH at low levels during flushing of the calcareous aquifer material. In contrast, equilibrium with Al oxyhydroxide phases initially buffered pH (˜4.5) during flushing of the carbonate-deficient sandstone with methanogenic leachate. This led to the mobilisation of sorbed and oxide-bound heavy metals from the aquifer sediment which migrated as a concentrated pulse at the leachate front. Abiotic reductive dissolution of Mn oxyhydroxides on each aquifer material by leachate Fe 2+ maintains high concentrations of dissolved Mn and buffers the leachate inorganic redox system. This feature is analogous to the Mn-reducing zones found in leachate plumes and in the experiments provides a sink for the leachate Fe load and other heavy metals. The availability of reactive solid phase Mn oxyhydroxides limits the duration of redox buffering and Fe attenuation by these aquifer sediments. Aquifer pH and redox buffering capacity exert a fundamental influence on leachate inorganic contaminant fate in these systems. The implications for the assessment of aquifer vulnerability at landfills are discussed and simple measurements of aquifer properties which may improve the prediction of contaminant attenuation are outlined.

Laboratory theory and methods for sediment analysis

USGS Publications Warehouse

Guy, Harold P.

1969-01-01

The diverse character of fluvial sediments makes the choice of laboratory analysis somewhat arbitrary and the pressing of sediment samples difficult. This report presents some theories and methods used by the Water Resources Division for analysis of fluvial sediments to determine the concentration of suspended-sediment samples and the particle-size distribution of both suspended-sediment and bed-material samples. Other analyses related to these determinations may include particle shape, mineral content, and specific gravity, the organic matter and dissolved solids of samples, and the specific weight of soils. The merits and techniques of both the evaporation and filtration methods for concentration analysis are discussed. Methods used for particle-size analysis of suspended-sediment samples may include the sieve pipet, the VA tube-pipet, or the BW tube-VA tube depending on the equipment available, the concentration and approximate size of sediment in the sample, and the settling medium used. The choice of method for most bed-material samples is usually limited to procedures suitable for sand or to some type of visual analysis for large sizes. Several tested forms are presented to help insure a well-ordered system in the laboratory to handle the samples, to help determine the kind of analysis required for each, to conduct the required processes, and to assist in the required computations. Use of the manual should further 'standardize' methods of fluvial sediment analysis among the many laboratories and thereby help to achieve uniformity and precision of the data.

Freshwater mussel response to bedform movement: experimental stream studies

NASA Astrophysics Data System (ADS)

Kozarek, J. L.; MacGregor, K. R.; Hornbach, D.; Hove, M.

2017-12-01

Freshwater mussels are intrinsically linked to near-bed sediment dynamics, but it remains unclear how mussels respond to changing sediment loads across spatial and temporal scales. The interactions between mussels and sediment transport are complex and often involve feedback loops. Mussels are filter feeders removing suspended particles from the water column and the physical presence of mussels can have significant impacts on the structure of riverbed habitat. We investigated the feedbacks between mussels, flow, and migrating bedforms during flood experiments in the St. Anthony Falls Laboratory Outdoor StreamLab (OSL) at the University of Minnesota. The OSL is a field-scale sand-bed meandering stream channel with independent control over sediment feed (recirculated) and water flow (diverted from the Mississippi River). Mussel location, orientation to flow, and protrusion from sediment was surveyed immediately before, after, and one and two days after each flood event. Flow fields, bed shear stress, bedform migration, and bar topography were measured during each flooding event with and without mussels present (density = 4/m2 and 8/m2) to quantify the influence of mussels on channel morphology and bedform migration. Mobile bedforms (up to 14 cm high) were present for all flood events with quasi-equilibrium, aggrading, and degrading bed conditions. Mussels moved little horizontally during all flood events, but were shown to move quickly to deeper water after the flood receded. However, mussels moved vertically, burrowing or being buried under mobile bedforms, during each flood event. The research presented here will focus on feedbacks between three mussel species with different shell sculptures, flow conditions, and migrating bedforms during flooding events. These results reveal how freshwater mussels respond to and affect flow and sediment transport during flood events that are difficult to observe in the field.

Natural remananent magnetization acquisition through sediment mixing: theory and implications for relative paleointensity

NASA Astrophysics Data System (ADS)

Egli, Ramon; Zhao, Xiangyu

2015-04-01

We present a general theory on the acquisition of natural remanent magnetizations (NRM) in sediment under the influence of (a) magnetic torques, (b) randomizing torques (e.g. from bioturbation), and (c) torques resulting from interaction forces between remanence carriers and other particles. Dynamic equilibrium between (a) and (b) in the water column and sediment-water interface produce a detrital remanent magnetization (DRM), while much stronger randomizing forces occur in the mixed layer of sediment due to bioturbation forces. These generate a so-called mixing remanent magnetization (MRM), which is stabilized by interaction forces. During the time required to cross the mixed layer, DRM is lost and MRM is acquired at a rate that depends on bioturbation intensity. Both processes are governed by the same MRM lock-in function. The final NRM intensity is controlled mainly by a single parameter defined as the product of rotational diffusion constant and mixed layer thickness, divided by the sedimentation rate. This parameter defines three regimes: (1) slow mixing, leading to DRM preservation and insignificant MRM acquisition, (2) fast mixing with MRM acquisition and full randomization of the original DRM, and (3) intermediate mixing. Because the acquisition efficiency of DRM is expectedly larger than that of a MRM, MRM is particularly sensitive to the mixing rate in case of intermediate regimes, and generates variable NRM acquisition efficiencies. Our model explains (1) lock-in delays that can be matched with empirical reconstructions from paleomagnetic records, (2) the existence of small lock-in depths leading to DRM preservation, (3) NRM acquisition efficiencies of magnetofossil-rich sediments, and (4) relative paleointensity artifacts reported in some recent studies.

Fluid flow and sediment transport in evolving sedimentary basins

NASA Astrophysics Data System (ADS)

Swenson, John Bradley

This thesis consists of three studies that focus on groundwater flow and sediment transport in evolving sedimentary basins. The first study considers the subsurface hydrodynamic response to basin-scale transgression and regression and its implications for stratiform ore genesis. I demonstrate that the transgressive sequence focuses marginward-directed, compaction-driven discharge within a basal aquifer during progradation and deposition of the overlying regressive sequence, isolates the basal aquifer from overlying flow systems, and serves as a chemical sink for metal-bearing brines. In the second study, I develop a new theory for the shoreline response to subsidence, sediment supply, and sea level. In this theory, sediment transport in a fluvio-deltaic basin is formally equivalent to heat transfer in a two-phase (liquid and isothermal solid) system: the fluvial system is analogous to a conduction-dominated liquid phase, the shoreline is the melting front, and the water depth at the delta toe is equivalent to the latent heat of fusion. A natural consequence of this theory is that sediment-starved basins do not possess an equilibrium state. In contrast to existing theories, I do not observe either strong phase shifting or attenuation of the shoreline response to low-frequency eustatic forcing; rather, shoreline tracks sea level over a spectrum of forcing frequencies, and its response to low-frequency forcing is amplified relative to the high-frequency response. For the third study, I use a set of dimensionless numbers from the previous study as a mathematical framework for providing a unified treatment of existing stratigraphic theories. In the limit of low-amplitude eustatic forcing, my study suggests that strong phase shifting between shoreline and sea level is a consequence of specifying the sedimentation rate at the shoreline; basins free of this constraint do not develop strong phase shifts.

Sediment discharge and channel change in the North Fork Teton River, 1977-78, Fremont and Madison counties, Idaho

USGS Publications Warehouse

Williams, Rhea P.

1979-01-01

The Teton Dam failure flood of June 5, 1976, severely disrupted the geomorphic character of North Fork Teton River in Idaho. Extensive channel restoration was required to contain expected normal spring flows. Six principal sites were established on the 17-mile reach of the river to study sediment transport and channel change during 1977-78. During April 1 to September 30, 1977, total water discharge at Teton Island bridge was 97,530 acre-feet; 4,360 tons of total sediment were transported. Total water discharge, April 1 to September 30, 1978, was 191,940 acre-feet; 10,680 tons of total sediment were transported. Analyses of data indicated several trends of erosion and deposition. Minimal channel change in the upper 7 miles of the river indicated equilibrium may temporarily exist between hydraulic-flow properties and channel shape. Streambed profiles indicated little change in streambed elevations. Erosional tonnage at mid-study reaches was 4,260 tons. One-half mile downstream, an increase of 4,150 tons of suspended and 1,050 tons of bedload sediment probably was partly derived from upstream bank erosion. An estimated 5,870 tons was deposited within the next subreach downstream. Virtually the entire bedload was redeposited before the last subreach, 4.4 miles downstream measured bedload was 91 tons. Suspended-sediment discharge transported past the last site was 16,470 tons. Lateral erosion and deposition in the lower 10 miles of the river indicate that subreaches now shortened by manmade channel alinements may begin to meander. Future deposition of coarse material at upstream gravel and concrete impoundments may trigger instability in the entire river. (Kosco-USGS)

Geochemical characterisation of shallow aquifer sediments of Matlab Upazila, Southeastern Bangladesh — Implications for targeting low-As aquifers

NASA Astrophysics Data System (ADS)

von Brömssen, Mattias; Häller Larsson, Sara; Bhattacharya, Prosun; Hasan, M. Aziz; Ahmed, Kazi Matin; Jakariya, M.; Sikder, Mohiuddin A.; Sracek, Ondra; Bivén, Annelie; Doušová, Barbora; Patriarca, Claudio; Thunvik, Roger; Jacks, Gunnar

2008-07-01

High arsenic (As) concentrations in groundwater pose a serious threat to the health of millions of people in Bangladesh. Reductive dissolution of Fe(III)-oxyhydroxides and release of its adsorbed As is considered to be the principal mechanism responsible for mobilisation of As. The distribution of As is extremely heterogeneous both laterally and vertically. Groundwater abstracted from oxidised reddish sediments, in contrast to greyish reducing sediments, contains significantly lower amount of dissolved arsenic and can be a source of safe water. In order to study the sustainability of that mitigation option, this study describes the lithofacies and genesis of the sediments within 60 m depth and establishes a relationship between aqueous and solid phase geochemistry. Oxalate extractable Fe and Mn contents are higher in the reduced unit than in the oxidised unit, where Fe and Mn are present in more crystalline mineral phases. Equilibrium modelling of saturation indices suggest that the concentrations of dissolved Fe, Mn and PO43--tot in groundwater is influenced by secondary mineral phases in addition to redox processes. Simulating AsIII adsorption on hydroferric oxides using the Diffuse Layer Model and analytical data gave realistic concentrations of dissolved and adsorbed AsIII for the reducing aquifer and we speculate that the presence of high PO43--tot in combination with reductive dissolution results in the high-As groundwater. The study confirms high mobility of As in reducing aquifers with typically dark colour of sediments found in previous studies and thus validates the approach for location of wells used by local drillers based on sediment colour. A more systematic and standardised colour description and similar studies at more locations are necessary for wider application of the approach.

Results of sampling and analysis : preliminary sediment quality assessment Martha Lake Snohomish County Washington

DOT National Transportation Integrated Search

1995-10-18

This report presents the results of sediment sampling and analysis conducted in support of proposed dredging activities of Martha Lake Sediments. The characterization of the sediments will be used in support of permitting applications and exploring v...

Planview Geometry and morphological characteristics of pocket beaches on the Catalan coast (Spain)

NASA Astrophysics Data System (ADS)

Bowman, D.; Guillén, J.; López, L.; Pellegrino, V.

2009-07-01

Coastal planform studies are a relevant initial stage before launching detailed dynamic field experiments. The aim of this study is to define the planform characteristics of 72 Catalan pocket beaches, natural and man-made, and to determine their sheltering effect, embaymentization and their status of equilibrium. Planform measurements were performed on SIGPAC, 1:5000 orthophoto sets and wave climate was provided by Puertos del Estado (Wana model). Planform parameters were applied and coastal planview indexes were determined. The study shows that the Catalan pocket beaches display a wide range of indentation, suggesting that no single structural, tectonic or morphological control dominates their planform. The man-made pocket beaches typically display indentations which are smaller than those shown by natural pocket beaches. Headland spacing and beach area are positively correlated. The more indented bays are, the shorter their beaches become. Low-indented pocket beaches are the widest and the longest ones. Deep indentation contributes towards beach protection and energy dissipation which counteracts rip efficiency and inhibits the formation of mega-rips. Pocket beaches often show gradual and moderate alongshore changes in texture and beach morphology. One third of the Catalan pocket beaches are "sediment starved", i.e., 60% and more of their embayed shorelines are deprived of beach sediments. Examination of the status of equilibrium demonstrates that most of the Catalan pocket beaches are in an unstable mode, with indentation ratios that are unrelated to the wave obliquity.

Ferric iron in sediments as a novel CO2 mineral trap: CO 2-SO2 reaction with hematite

USGS Publications Warehouse

Palandri, J.L.; Rosenbauer, R.J.; Kharaka, Y.K.

2005-01-01

Thermodynamic simulations of reactions among SO2-bearing CO 2-dominated gas, water and mineral phases predict that Fe III in sediments should be converted almost entirely to dissolved FeII and siderite (FeCO3), and that SO2 should simultaneously be oxidized to dissolved sulfate. The reactions are however, subject to kinetic constraints which may result in deviation from equilibrium and the precipitation of other metastable mineral phases. To test the prediction, a laboratory experiment was carried out in a well stirred hydrothermal reactor at 150??C and 300 bar with hematite, 1.0 m NaCl, 0.5 m NaOH, SO2 in quantity sufficient to reduce much of the iron, and excess CO2. The experiment produced stable siderite and metastable pyrite and elemental S. Changes in total dissolved Fe are consistent with nucleation of pyrite at ???17 h, and nucleation of siderite at ???600 h. Dissolution features present on elemental S at the conclusion of the experiment suggest nucleation early in the experiment. The experiment did not reach equilibrium after ???1400 h, as indicated by coexistence of hematite with metastable pyrite and elemental sulfur. However, the results confirm that FeIII can be used to trap CO2 in siderite if partly oxidized S, as SO2, is present to reduce the Fe with CO2 in the gas phase. ?? 2005 Elsevier Ltd. All rights reserved.

Biofilm-induced bioclogging produces sharp interfaces in hyporheic flow, redox conditions, and microbial community structure

NASA Astrophysics Data System (ADS)

Caruso, Alice; Boano, Fulvio; Ridolfi, Luca; Chopp, David L.; Packman, Aaron

2017-05-01

Riverbed sediments host important biogeochemical processes that play a key role in nutrient dynamics. Sedimentary nutrient transformations are mediated by bacteria in the form of attached biofilms. The influence of microbial metabolic activity on the hydrochemical conditions within the hyporheic zone is poorly understood. We present a hydrobiogeochemical model to assess how the growth of heterotrophic and autotrophic biomass affects the transport and transformation of dissolved nitrogen compounds in bed form-induced hyporheic zones. Coupling between hyporheic exchange, nitrogen metabolism, and biomass growth leads to an equilibrium between permeability reduction and microbial metabolism that yields shallow hyporheic flows in a region with low permeability and high rates of microbial metabolism near the stream-sediment interface. The results show that the bioclogging caused by microbial growth can constrain rates and patterns of hyporheic fluxes and microbial transformation rate in many streams.

Internal loading of phosphorus in a sedimentation pond of a treatment wetland: effect of a phytoplankton crash.

PubMed

Palmer-Felgate, Elizabeth J; Mortimer, Robert J G; Krom, Michael D; Jarvie, Helen P; Williams, Richard J; Spraggs, Rachael E; Stratford, Charlie J

2011-05-01

Sedimentation ponds are widely believed to act as a primary removal process for phosphorus (P) in nutrient treatment wetlands. High frequency in-situ P, ammonium (NH(4)(+)) and dissolved oxygen measurements, alongside occasional water quality measurements, assessed changes in nutrient concentrations and productivity in the sedimentation pond of a treatment wetland between March and June. Diffusive equilibrium in thin films (DET) probes were used to measure in-situ nutrient and chemistry pore-water profiles. Diffusive fluxes across the sediment-water interface were calculated from the pore-water profiles, and dissolved oxygen was used to calculate rates of primary productivity and respiration. The sedimentation pond was a net sink for total P (TP), soluble reactive P (SRP) and NH(4)(+) in March, but became subject to a net internal loading of TP, SRP and NH(4)(+) in May, with SRP concentrations increasing by up to 41μM (1300μl(-1)). Reductions in chlorophyll a and dissolved oxygen concentrations also occurred at this time. The sediment changed from a small net sink of SRP in March (average diffusive flux: -8.2μmolm(-2)day(-1)) to a net source of SRP in June (average diffusive flux: +1324μmolm(-2)day(-1)). A diurnal pattern in water column P concentrations, with maxima in the early hours of the morning, and minima in the afternoon, occurred during May. The diurnal pattern and release of SRP from the sediment were attributed to microbial degradation of diatom biomass, causing reduction of the dissolved oxygen concentration and leading to redox-dependent release of P from the sediment. In June, 2.7mol-Pday(-1) were removed by photosynthesis and 23mol-Pday(-1) were supplied by respiration in the lake volume. SRP was also released through microbial respiration within the water column, including the decomposition of algal matter. It is imperative that consideration to internal recycling is given when maintaining sedimentation ponds, and before the installation of new ponds designed to treat nutrient waste. Copyright © 2011 Elsevier B.V. All rights reserved.

Nutrient recycling and the stoichiometric relationship among C, N, and P in Paleozoic anoxic sediments

NASA Astrophysics Data System (ADS)

Tuite, M. L., Jr.

2016-12-01

Remineralized organic N and P diffused into the water column from underlying anoxic sediments were important sources of macronutrients for primary production in shallow Paleozoic epicontinental seas. Ratios of total organic C to total N or P in ancient sediments that are greater than Redfield-like values are often cited as evidence for macronutrient recycling. We propose that the stoichiometric relationship among C, N, and P in anoxic Paleozoic sediments was mediated primarily by heterotrophic bacterial alkaline phosphatases. Bacterial heterotrophy in organic-rich anaerobic sediments is frequently limited by the availability of labile (low C/N) organic matter. In response, bacterial heterotrophs invest scarce C and N to produce alkaline phosphatases in order to alleviate labile organic matter limitation by hydrolysis of organophosphates. This suggests that sediment organic C/N may represent a threshold beyond which the investment of intracellular C and N in the production of alkaline phosphatase no longer results in a stoichiometrically favorable return on the investment. If this is the case, then C/P likely represents the point in the diagenesis of organic matter at which the effectiveness of alkaline phosphatase in procuring labile organic matter by remineralization of P is constrained by the lability of the organic matter itself. Because alkaline phosphatase activity is expressed in inverse proportion to the porewater concentration of phosphate, at a given distance from the terrestrial source of weathered P, an equilibrium determined by total phosphate influx results in consistent total P burial rates and consistent organic C/N values independent of the total organic content of the sediment. To account for consistent C/N in spite of variable total organic carbon at a given location, we propose that variations in the absolute abundance of organic C in organic-rich Devonian sediments were largely a function of the lipid content of algal primary producers. The significance of this research is two-fold: First, it puts forth a novel mechanistic explanation for observed relationships among C, N, and P in ancient sediments based upon observations of modern microbial ecosystems. Second, it links the preservation of organic matter in the geological record to the nutritional status of primary producers.

Antecedent topography and morphological controls on sediment accumulation and slope stability of the U.S. Atlantic margin

NASA Astrophysics Data System (ADS)

Hill, J. C.; Brothers, D. S.; Ten Brink, U. S.; Andrews, B. D.

2017-12-01

The U.S. Atlantic margin encompasses a wide variety of slope failure processes, ranging from small canyon-confined failures on the upper slope to large, open slope landslides originating in deeper water. Here we used a suite of high-resolution multibeam bathymetry and detailed multichannel seismic data coverage to investigate the relationship between modern seafloor morphology, pre-existing stratigraphy and sediment accumulation patterns. We suggest that a combination of sediment supply and antecedent margin physiography, whereby variations in margin evolution during the Miocene have influenced the modern seafloor morphology, controls both the location of slope sediment accumulation and the style of slope failure. Oversteepened margins with angular shelf breaks and steep upper slopes, referred to as oblique margins, are characterized by downslope mass transport and densely-spaced canyon formation. These margins are most likely the locus of canyon-confined failures and smaller lower slope fan-apron failures (e.g., much of the Mid-Atlantic). Sigmoidal margins with prograded slopes, a rounded shelf edge, and a low gradient slope morphology can support significant sediment accumulation across a broad area, with limited canyon development. These margins are often associated with high sediment supply and are prone to large, upper slope slab-style failures (e.g., the Hudson Apron, southwestern New England, the Currituck and Cape Fear Slide complexes). Areas with morphologies in between these two end members are characterized by limited shelf-edge accommodation space and large-scale lower slope accumulation and onlap, representing transitional stages of equilibrium slope adjustment. Large failures along these intermediate-type margins tend to develop lower on the slope where thick wedges of onlapping sediment are found (e.g., around Washington Canyon, Cape Lookout and southeastern New England). As antecedent topography and sediment loading appear to play an important role in determining the spatial distribution of submarine slope failures, other key processes that contribute to the development of overpressure (e.g., sediment compaction and fluid migration) should be examined with this in mind to improve our understanding of the geologic factors that precondition slopes for failure.

Strong Deformation of the Thick Electric Double Layer around a Charged Particle during Sedimentation or Electrophoresis.

PubMed

Khair, Aditya S

2018-01-23

The deformation of the electric double layer around a charged colloidal particle during sedimentation or electrophoresis in a binary, symmetric electrolyte is studied. The surface potential of the particle is assumed to be small compared to the thermal voltage scale. Additionally, the Debye length is assumed to be large compared to the particle size. These assumptions enable a linearization of the electrokinetic equations. The particle appears as a point charge in this thick-double-layer limit; the distribution of charge in the diffuse cloud surrounding it is determined by a balance of advection due to the particle motion, Brownian diffusion of ions, and electrostatic screening of the particle by the cloud. The ability of advection to deform the charge cloud from its equilibrium state is parametrized by a Péclet number, Pe. For weak advection (Pe ≪ 1), the cloud is only slightly deformed. In contrast, the cloud can be completely stripped from the particle at Pe ≫ 1; consequently, electrokinetic effects on the particle motion vanish in this regime. Therefore, in sedimentation the drag limits to Stokes' law for an uncharged particle as Pe → ∞. Likewise, the particle velocity for electrophoresis approaches Huckel's result. The strongly deformed cloud at large Pe is predicted to generate a concomitant increase in the sedimentation field in a dilute settling suspension.

Transport of chromium and selenium in the suboxic zone of a shallow aquifer: Influence of redox and adsorption reactions

USGS Publications Warehouse

Kent, D.B.; Davis, J.A.; Anderson, L.C.D.; Rea, B.A.; Waite, T.D.

1994-01-01

Breakthrough of Cr(VI) (chromate), Se(VI) (selenate), and O2 (dissolved oxygen) was observed in tracer tests conducted in a shallow, sand and gravel aquifer with mildly reducing conditions. Loss of Cr, probably due to reduction of Cr(VI) to Cr(III) and irreversible sorption of Cr(III), occurred along with slight retardation of Cr(VI), owing to reversible sorption. Reduction of Se(VI) and O2 was thermodynamically feasible but did not occur, indicating conditions, were unfavorable to microbial reduction. Cr(VI) reduction by constituents of aquifer sediments did not achieve local equilibrium during transport. The reduction rate was probably limited by incomplete contact between Cr(VI) transported along predominant flow paths and reductants located in regions within aquifer sediments of comparatively low permeability. Scatter in the amount of Cr reduction calculated from individual breakthrough curves at identical distances downgradient probably resulted from heterogeneities in the distribution of reductants in the sediments. Predictive modeling of the transport and fate of redox-sensitive solutes cannot be based strictly on thermodynamic considerations; knowledge of reaction rates is critical. Potentially important mass transfer rate limitations between solutes and reactants in sediments as well as heterogeneities in the distribution of redox properties in aquifers complicate determination of limiting rates for use in predictive simulations of the transport of redox-sensitive contaminants in groundwater.

Multivariate analysis of heavy metal contamination using river sediment cores of Nankan River, northern Taiwan

NASA Astrophysics Data System (ADS)

Lee, An-Sheng; Lu, Wei-Li; Huang, Jyh-Jaan; Chang, Queenie; Wei, Kuo-Yen; Lin, Chin-Jung; Liou, Sofia Ya Hsuan

2016-04-01

Through the geology and climate characteristic in Taiwan, generally rivers carry a lot of suspended particles. After these particles settled, they become sediments which are good sorbent for heavy metals in river system. Consequently, sediments can be found recording contamination footprint at low flow energy region, such as estuary. Seven sediment cores were collected along Nankan River, northern Taiwan, which is seriously contaminated by factory, household and agriculture input. Physico-chemical properties of these cores were derived from Itrax-XRF Core Scanner and grain size analysis. In order to interpret these complex data matrices, the multivariate statistical techniques (cluster analysis, factor analysis and discriminant analysis) were introduced to this study. Through the statistical determination, the result indicates four types of sediment. One of them represents contamination event which shows high concentration of Cu, Zn, Pb, Ni and Fe, and low concentration of Si and Zr. Furthermore, three possible contamination sources of this type of sediment were revealed by Factor Analysis. The combination of sediment analysis and multivariate statistical techniques used provides new insights into the contamination depositional history of Nankan River and could be similarly applied to other river systems to determine the scale of anthropogenic contamination.

Isotopic exchange on solid-phase micro extraction fiber in sediment under stagnant conditions: Implications for field application of performance reference compound calibration.

PubMed

Bao, Lian-Jun; Wu, Xiaoqin; Jia, Fang; Zeng, Eddy Y; Gan, Jay

2016-08-01

An overlooked issue for field application of in situ performance reference compound (PRC) calibration methods is the validity of the assumption that both the sorption of a target compound and desorption of its corresponding PRC follow the first-order kinetics with the same rate constants under stagnant conditions. In the present study, disposable polydimethylsiloxane fibers of 2 sizes (7 and 35 µm) impregnated with 8 (13) C-labeled or deuterated PRCs were statically deployed into different marine sediments, from which the kinetics for sorption of the target compounds and desorption of the PRCs were characterized. Nonsymmetrical profiles were observed for exchange of the target analytes and their corresponding PRCs in sediment under stagnant conditions. The hysteretic desorption of PRCs in the kinetic regime may be ascribed to the low chemical potential between the fiber and sediment porewater, which reflects the inability of water molecules to rapidly diffuse through sediment to solvate the PRCs in the aqueous layer around the fiber surface. A moderate correlation (r = 0.77 and r = 0.57, p < 0.05 for both regressions) between the PRC-calibrated equilibrium concentrations of 1,1-dichloro-2,2-bis-(chlorophenyl) ethylene (p,p'-DDE) and polychlorinated biphenyl (PCB)-153 and the lipid normalized levels in worms (Neanthes arenaceodentata) was obtained in co-exposure tests under simulating field conditions, probably resulting from slightly overestimated bioavailability because of the hysteretic desorption of PRCs and toxic effects. Environ Toxicol Chem 2016;35:1978-1985. © 2015 SETAC. © 2015 SETAC.

Natural remanent magnetization acquisition in bioturbated sediment: General theory and implications for relative paleointensity reconstructions

NASA Astrophysics Data System (ADS)

Egli, R.; Zhao, X.

2015-04-01

We present a general theory for the acquisition of natural remanent magnetizations (NRM) in sediment under the influence of (a) magnetic torques, (b) randomizing torques, and (c) torques resulting from interaction forces. Dynamic equilibrium between (a) and (b) in the water column and at the sediment-water interface generates a detrital remanent magnetization (DRM), while much stronger randomizing torques may be provided by bioturbation inside the mixed layer. These generate a so-called mixed remanent magnetization (MRM), which is stabilized by mechanical interaction forces. During the time required to cross the surface mixed layer, DRM is lost and MRM is acquired at a rate that depends on bioturbation intensity. Both processes are governed by a MRM lock-in function. The final NRM intensity is controlled mainly by a single parameter γ that is defined as the product of rotational diffusion and mixed-layer thickness, divided by sedimentation rate. This parameter defines three regimes: (1) slow mixing (γ < 0.2) leading to DRM preservation and insignificant MRM acquisition, (2) fast mixing (γ > 10) with MRM acquisition and full DRM randomization, and (3) intermediate mixing. Because the acquisition efficiency of DRM is larger than that of MRM, NRM intensity is particularly sensitive to γ in case of mixed regimes, generating variable NRM acquisition efficiencies. This model explains (1) lock-in delays that can be matched with empirical reconstructions from paleomagnetic records, (2) the existence of small lock-in depths that lead to DRM preservation, (3) specific NRM acquisition efficiencies of magnetofossil-rich sediments, and (4) some relative paleointensity artifacts.

Internal loading of phosphate in Lake Erie Central Basin.

PubMed

Paytan, Adina; Roberts, Kathryn; Watson, Sue; Peek, Sara; Chuang, Pei-Chuan; Defforey, Delphine; Kendall, Carol

2017-02-01

After significant reductions in external phosphorus (P) loads, and subsequent water quality improvements in the early 1980s, the water quality of Lake Erie has declined considerably over the past decade. The frequency and magnitude of harmful algal blooms (primarily in the western basin) and the extent of hypoxic bottom waters in the central basin have increased. The decline in ecosystem health, despite meeting goals for external P loads, has sparked a renewed effort to understand P cycling in the lake. We use pore-water P concentration profiles and sediment cores incubation experiments to quantify the P flux from Lake Erie central basin sediments. In addition, the oxygen isotopes of phosphate were investigated to assess the isotopic signature of sedimentary phosphate inputs relative to the isotopic signature of phosphate in lake water. Extrapolating the total P sediment flux based on the pore-water profiles to the whole area of the central basin ranged from 300 to 1250metric tons per year and using the flux based on core incubation experiments an annual flux of roughly 2400metric tons of P is calculated. These estimates amount to 8-20% of the total external input of P to Lake Erie. The isotopic signature of phosphate in the extractable fraction of the sediments (~18‰) can explain the non-equilibrium isotope values of dissolved phosphate in the deep water of the central basin of Lake Erie, and this is consistent with sediments as an important internal source of P in the Lake. Copyright © 2016 Elsevier B.V. All rights reserved.

Hazard evaluation of ten organophosphorous insecticides against the midge, Chironomus riparius via QSAR

USGS Publications Warehouse

Landrum, Peter F.; Fisher, Susan W.; Hwang, Haejo; Hickey, James P.

1999-01-01

Toxicities of ten organophosphorus (OP) insecticides were measured against midge larvae (Chironomus riparius) under varying temperature (11, 18, and 25°C) and pH (6, 7, and 8) conditions and with and without sediment. Toxicity usually increased with increasing temperature and was greater in the absence of sediment. No trend was found with varying pH. A series of unidimensional parameters and multidimensional models were used to describe the changes in toxicity. Log Kow was able to explain about 40–60% of the variability in response data for aqueous exposures while molecular volume and aqueous solubility were less predictive. Likewise, the linear solvation energy relationship (LSER) model only explained 40–70% of the response variability, suggesting that factors other than solubility were most important for producing the observed response. Molecular connectivity was the most useful for describing the variability in the response. In the absence of sediment, 1χv and 3κ were best able to describe the variation in response among all compounds at each pH (70–90%). In the presence of sediment, even molecular connectivity could not describe the variability until the partitioning potential to sediment was accounted for by assuming equilibrium partitioning. After correcting for partitioning, the same molecular connectivity terms as in the aqueous exposures described most of the variability, 61–87%, except for the 11°C data where correlations were not significant. Molecular connectivity was a better tool than LSER or the unidimensional variables to explain the steric fitness of OP insecticides which was crucial to the toxicity.

Environmental Effects of Storage Preservation Practices: Controlled Flushing of Fine Sediment from a Small Hydropower Reservoir

NASA Astrophysics Data System (ADS)

Espa, Paolo; Castelli, Elena; Crosa, Giuseppe; Gentili, Gaetano

2013-07-01

Sediment flushing may be effective in mitigating loss of reservoir storage due to siltation, but flushing must be controlled to limit the impact on the downstream environment. A reliable prediction of the environmental effects of sediment flushing is hindered by the limited scientific information currently available. Consequently, there may be some controversy as regards to management decisions, planning the work, and monitoring strategies. This paper summarizes the main results of a monitoring campaign on the stream below a small alpine hydropower reservoir subjected to annual flushing between 2006 and 2009. The removed sediment was essentially silt, and the suspended solid concentration (SSC) of the discharged water was controlled to alleviate downstream impact. Control was achieved through hydraulic regulation and mechanical digging, alternating daytime sediment evacuation, and nocturnal clear water release. The four operations lasted about two weeks each and had an average SSC of about 4 g L-1. Maximum values of SSC were generally kept below 10 g L-1. Downstream impact was quantified through sampling of fish fauna (brown trout) and macroinvertebrate in the final reach of the effluent stream. The benthic community was severely impaired by the flushing operations, but recovered to pre-flushing values in a few months. As expected, the impact on brown trout was heavier on juveniles. While data biasing due to fish removal and re-stocking cannot be ruled out, the fish community seems to have reached a state of equilibrium characterized by a lower density than was measured before the flushing operations.

Environmental effects of storage preservation practices: controlled flushing of fine sediment from a small hydropower reservoir.

PubMed

Espa, Paolo; Castelli, Elena; Crosa, Giuseppe; Gentili, Gaetano

2013-07-01

Sediment flushing may be effective in mitigating loss of reservoir storage due to siltation, but flushing must be controlled to limit the impact on the downstream environment. A reliable prediction of the environmental effects of sediment flushing is hindered by the limited scientific information currently available. Consequently, there may be some controversy as regards to management decisions, planning the work, and monitoring strategies. This paper summarizes the main results of a monitoring campaign on the stream below a small alpine hydropower reservoir subjected to annual flushing between 2006 and 2009. The removed sediment was essentially silt, and the suspended solid concentration (SSC) of the discharged water was controlled to alleviate downstream impact. Control was achieved through hydraulic regulation and mechanical digging, alternating daytime sediment evacuation, and nocturnal clear water release. The four operations lasted about two weeks each and had an average SSC of about 4 g L(-1). Maximum values of SSC were generally kept below 10 g L(-1). Downstream impact was quantified through sampling of fish fauna (brown trout) and macroinvertebrate in the final reach of the effluent stream. The benthic community was severely impaired by the flushing operations, but recovered to pre-flushing values in a few months. As expected, the impact on brown trout was heavier on juveniles. While data biasing due to fish removal and re-stocking cannot be ruled out, the fish community seems to have reached a state of equilibrium characterized by a lower density than was measured before the flushing operations.

The hyperturbid state of the water column in estuaries and rivers: the importance of hindered settling

NASA Astrophysics Data System (ADS)

Dijkstra, Yoeri M.; Schuttelaars, Henk M.; Winterwerp, Johan C.

2018-03-01

Over the last few decades, some estuaries have undergone a transition to a hyperturbid state, characterised by suspended sediment concentrations of several grammes per litre averaged over the water column. To improve our understanding of this transition and of naturally hyperturbid estuaries, we systematically identify the processes allowing for high suspended sediment concentrations using a water column (1DV) model. Under a range of realistic forcing conditions, the state of the water column can be characterised by one of two equilibrium states. The first is an erosion-limited state, in which there still is sediment available for erosion at the bed. We find that this state only occurs with relatively low concentrations. The second is a supply-limited state, in which all erodable sediment is in suspension. The concentration in this state depends entirely on the amount of sediment in the system and can potentially be very high. We identify the conditions under which the state of the water column can jump from a low to a high concentration and identify hysteresis in the transition between the two states. The mechanism responsible for this hysteresis is hindered settling. It thus follows that hyperturbidity is only possible in a supply-limited state. From this observation we derive a necessary condition for an estuarine system to make the transition from low turbidity to hyperturbidity in a 1DV context. This is an important step towards understanding why some estuaries are hyperturbid and assessing the risk that particular estuaries may become hyperturbid in the future.

Equilibrium unfolding studies of the rat liver methionine adenosyltransferase III, a dimeric enzyme with intersubunit active sites.

PubMed Central

Gasset, María; Alfonso, Carlos; Neira, José L; Rivas, Germán; Pajares, María A

2002-01-01

The reversible unfolding of rat liver methionine adenosyltransferase dimer by urea under equilibrium conditions has been monitored by fluorescence spectroscopy, CD, size-exclusion chromatography, analytical ultracentrifugation and enzyme activity measurements. The results obtained indicate that unfolding takes place through a three-state mechanism, involving an inactive monomeric intermediate. This intermediate has a 70% native secondary structure, binds less 8-anilinonaphthalene-1-sulphonic acid than the native dimer and has a sedimentation coefficient of 4.24+/-0.15. The variations of free energy in the absence of denaturant [DeltaG(H(2)O)] and its coefficients of urea dependence (m), calculated by the linear extrapolation model, were 36.15+/-2.3 kJ.mol(-1) and 19.87+/-0.71 kJ.mol(-1).M(-1) for the dissociation of the native dimer and 14.77+/-1.63 kJ.mol(-1) and 5.23+/-0.21 kJ.mol(-1).M(-1) for the unfolding of the monomeric intermediate respectively. Thus the global free energy change in the absence of denaturant and the m coefficient were calculated to be 65.69 kJ.mol(-1) and 30.33 kJ.mol(-1).M(-1) respectively. Analysis of the calculated thermodynamical parameters indicate the instability of the dimer in the presence of denaturant, and that the major exposure to the solvent is due to dimer dissociation. Finally, a minimum-folding mechanism for methionine adenosyltransferase III is established. PMID:11772402

Baryon Distribution in Galaxy Clusters as a Result of Sedimentation of Helium Nuclei.

PubMed

Qin; Wu

2000-01-20

Heavy particles in galaxy clusters tend to be more centrally concentrated than light ones according to the Boltzmann distribution. An estimate of the drift velocity suggests that it is possible that the helium nuclei may have entirely or partially sedimented into the cluster core within the Hubble time. We demonstrate this scenario using the Navarro-Frenk-White profile as the dark matter distribution of clusters and assuming that the intracluster gas is isothermal and in hydrostatic equilibrium. We find that a greater fraction of baryonic matter is distributed at small radii than at large radii, which challenges the prevailing claim that the baryon fraction increases monotonically with cluster radius. It shows that the conventional mass estimate using X-ray measurements of intracluster gas along with a constant mean molecular weight may have underestimated the total cluster mass by approximately 20%, which in turn leads to an overestimate of the total baryon fraction by the same percentage. Additionally, it is pointed out that the sedimentation of helium nuclei toward cluster cores may at least partially account for the sharp peaks in the central X-ray emissions observed in some clusters.

Large sulfur isotope fractionations in Martian sediments at Gale crater

NASA Astrophysics Data System (ADS)

Franz, H. B.; McAdam, A. C.; Ming, D. W.; Freissinet, C.; Mahaffy, P. R.; Eldridge, D. L.; Fischer, W. W.; Grotzinger, J. P.; House, C. H.; Hurowitz, J. A.; McLennan, S. M.; Schwenzer, S. P.; Vaniman, D. T.; Archer, P. D., Jr.; Atreya, S. K.; Conrad, P. G.; Dottin, J. W., III; Eigenbrode, J. L.; Farley, K. A.; Glavin, D. P.; Johnson, S. S.; Knudson, C. A.; Morris, R. V.; Navarro-González, R.; Pavlov, A. A.; Plummer, R.; Rampe, E. B.; Stern, J. C.; Steele, A.; Summons, R. E.; Sutter, B.

2017-09-01

Variability in the sulfur isotopic composition in sediments can reflect atmospheric, geologic and biological processes. Evidence for ancient fluvio-lacustrine environments at Gale crater on Mars and a lack of efficient crustal recycling mechanisms on the planet suggests a surface environment that was once warm enough to allow the presence of liquid water, at least for discrete periods of time, and implies a greenhouse effect that may have been influenced by sulfur-bearing volcanic gases. Here we report in situ analyses of the sulfur isotopic compositions of SO2 volatilized from ten sediment samples acquired by NASA’s Curiosity rover along a 13 km traverse of Gale crater. We find large variations in sulfur isotopic composition that exceed those measured for Martian meteorites and show both depletion and enrichment in 34S. Measured values of δ34S range from -47 +/- 14‰ to 28 +/- 7‰, similar to the range typical of terrestrial environments. Although limited geochronological constraints on the stratigraphy traversed by Curiosity are available, we propose that the observed sulfur isotopic signatures at Gale crater can be explained by equilibrium fractionation between sulfate and sulfide in an impact-driven hydrothermal system and atmospheric processing of sulfur-bearing gases during transient warm periods.

Fertilizers mobilization in alluvial aquifer: laboratory experiments

NASA Astrophysics Data System (ADS)

Mastrocicco, M.; Colombani, N.; Palpacelli, S.

2009-02-01

In alluvial plains, intensive farming with conspicuous use of agrochemicals, can cause land pollution and groundwater contamination. In central Po River plain, paleo-channels are important links between arable lands and the underlaying aquifer, since the latter is often confined by clay sediments that act as a barrier against contaminants migration. Therefore, paleo-channels are recharge zones of particular interest that have to be protected from pollution as they are commonly used for water supply. This paper focuses on fertilizer mobilization next to a sand pit excavated in a paleo-channel near Ferrara (Italy). The problem is approached via batch test leaking and columns elution of alluvial sediments. Results from batch experiments showed fast increase in all major cations and anions, suggesting equilibrium control of dissolution reactions, limited availability of solid phases and geochemical homogeneity of samples. In column experiments, early elution and tailing of all ions breakthrough was recorded due to preferential flow paths. For sediments investigated in this study, dispersion, dilution and chemical reactions can reduce fertilizers at concentration below drinking standards in a reasonable time frame, provided fertilizer loading is halted or, at least, reduced. Thus, the definition of a corridor along paleo-channels is recommended to preserve groundwater quality.

Model behavior and sensitivity in an application of the cohesive bed component of the community sediment transport modeling system for the York River estuary, VA, USA

USGS Publications Warehouse

Fall, Kelsey A.; Harris, Courtney K.; Friedrichs, Carl T.; Rinehimer, J. Paul; Sherwood, Christopher R.

2014-01-01

The Community Sediment Transport Modeling System (CSTMS) cohesive bed sub-model that accounts for erosion, deposition, consolidation, and swelling was implemented in a three-dimensional domain to represent the York River estuary, Virginia. The objectives of this paper are to (1) describe the application of the three-dimensional hydrodynamic York Cohesive Bed Model, (2) compare calculations to observations, and (3) investigate sensitivities of the cohesive bed sub-model to user-defined parameters. Model results for summer 2007 showed good agreement with tidal-phase averaged estimates of sediment concentration, bed stress, and current velocity derived from Acoustic Doppler Velocimeter (ADV) field measurements. An important step in implementing the cohesive bed model was specification of both the initial and equilibrium critical shear stress profiles, in addition to choosing other parameters like the consolidation and swelling timescales. This model promises to be a useful tool for investigating the fundamental controls on bed erodibility and settling velocity in the York River, a classical muddy estuary, provided that appropriate data exists to inform the choice of model parameters.

Increases to Inferred Rates of Planetesimal Accretion due to Thermohaline Mixing in Metal-accreting White Dwarfs

NASA Astrophysics Data System (ADS)

Bauer, Evan B.; Bildsten, Lars

2018-06-01

Many isolated, old white dwarfs (WDs) show surprising evidence of metals in their photospheres. Given that the timescale for gravitational sedimentation is astronomically short, this is taken as evidence for ongoing accretion, likely of tidally disrupted planetesimals. The rate of such accretion, {\\dot{M}}acc}, is important to constrain, and most modeling of this process relies on assuming an equilibrium between diffusive sedimentation and metal accretion supplied to the WD’s surface convective envelope. Building on the earlier work of Deal and collaborators, we show that high {\\dot{M}}acc} models with only diffusive sedimentation are unstable to thermohaline mixing and that models that account for the enhanced mixing from the active thermohaline instability require larger accretion rates, sometimes reaching {\\dot{M}}acc}≈ {10}13 {{g}} {{{s}}}-1 to explain observed calcium abundances. We present results from a grid of MESA models that include both diffusion and thermohaline mixing. These results demonstrate that both mechanisms are essential for understanding metal pollution across the range of polluted WDs with hydrogen atmospheres. Another consequence of active thermohaline mixing is that the observed metal abundance ratios are identical to accreted material.

Floodplain geomorphic processes and environmental impacts of human alteration along coastal plain rivers, USA

USGS Publications Warehouse

Hupp, C.R.; Pierce, Aaron R.; Noe, G.B.

2009-01-01

Human alterations along stream channels and within catchments have affected fluvial geomorphic processes worldwide. Typically these alterations reduce the ecosystem services that functioning floodplains provide; in this paper we are concerned with the sediment and associated material trapping service. Similarly, these alterations may negatively impact the natural ecology of floodplains through reductions in suitable habitats, biodiversity, and nutrient cycling. Dams, stream channelization, and levee/canal construction are common human alterations along Coastal Plain fluvial systems. We use three case studies to illustrate these alterations and their impacts on floodplain geomorphic and ecological processes. They include: 1) dams along the lower Roanoke River, North Carolina, 2) stream channelization in west Tennessee, and 3) multiple impacts including canal and artificial levee construction in the central Atchafalaya Basin, Louisiana. Human alterations typically shift affected streams away from natural dynamic equilibrium where net sediment deposition is, approximately, in balance with net erosion. Identification and understanding of critical fluvial parameters (e.g., stream gradient, grain-size, and hydrography) and spatial and temporal sediment deposition/erosion process trajectories should facilitate management efforts to retain and/or regain important ecosystem services. ?? 2009, The Society of Wetland Scientists.

River basin affected by rare perturbation events: the Chaiten volcanic eruption.

NASA Astrophysics Data System (ADS)

Picco, Lorenzo; Iroumé, Andrés; Oss-Cazzador, Daniele; Ulloa, Hector

2017-04-01

Natural disasters can strongly and rapidly affect a wide array of environments. Among these, volcanic eruptions can exert severe impacts on the dynamic equilibrium of riverine environment. The production and subsequent mobilization of large amounts of sediment all over the river basin, can strongly affect both hydrology and sediment and large wood transport dynamics. The aim of this research is to quantify the impact of a volcanic eruption along the Blanco River basin (Southern Chile), considering the geomorphic settings, the sediment dynamics and wood transport. Moreover, an overview on the possible management strategies to reduce the risks will be proposed. The research was carried out mainly along a 2.2 km-long reach of the fourth-order Blanco stream. Almost the entire river basin was affected by the volcanic eruption, several meters of tephra (up to 8 m) were deposited, affecting the evergreen forest and the fluvial corridor. Field surveys and remote sense analysis were carried out to investigate the effect of such extreme event. A Terrestrial Laser Scanner (TLS) was used to detect the morphological changes by computing Difference of Dems (DoDs), while field surveys were carried out to detect the amount of in-channel wood; moreover aerial photos have been analyzed to detect the extension of the impact of volcanic eruption over the river basin. As expected, the DoDs analysis permitted to detect predominant erosional processes along the channel network. In fact, over 190569 m2 there was erosion that produced about 362999 m3 of sediment mobilized, while the deposition happened just over 58715 m2 for a total amount of 23957 m3. Looking then to the LW recruited and transported downstream, was possible to detect as along the active channel corridor a total amount of 113 m3/ha of wood was present. Moreover, analyzing aerial photographs taken before and after the volcanic eruption was possible to define as a total area of about 2.19 km2 was affected by tephra deposition, 0.87 km2 has already been eroded by floods, while 1.32 km2 is still there. Considering an average depth of 5 m, the potential amount of sediment erodible and potentially transported downstream during the next near future is around 6.5 x 106 m3. Finally, from the same area can be recruited other 7.3 x 104 m3 of LW that can be transported towards the mouth. These results may help to better define management strategies to reduce the potential risks to the sensitive structures and cross section downstream. In fact, the management of sediment and LW transport through the lower Chaiten village appear of fundamental importance to guarantee a safer condition. This research is funded by the Chilean research Project FONDECYT 1141064 "Effects of vegetation on channel morphodynamics: a multiscale investigation in Chilean gravel-bed rivers".

Quantitative geochemical modeling along a transect off Peru: Carbon cycling in time and space, and the triggering factors for carbon loss and storage

NASA Astrophysics Data System (ADS)

Arning, Esther T.; van Berk, Wolfgang; Schulz, Hans-Martin

2012-12-01

Early diagenetic processes in Peruvian shelf and slope sediments are numerically reproduced by applying chemical thermodynamics in a complex, universal approach using the PHREEQC (version 2) computer code. The reaction kinetics of organic carbon remineralization are integrated into a set of equilibrium reactions by defining the type and the amount of converted organic matter in a certain time step. We calculate the most intense remineralization of organic carbon for present-day shelf sites, and the final carbon pool is dominated by secondary carbonates. This serves to highlight the influence of organic matter degradation and anaerobic oxidation of methane (AOM) on diagenetic mineral formation. The enrichment of aqueous methane and the formation of methane hydrate only takes place in slope sediments with high sedimentation rates that prevent diffusive loss of methane (e.g., Sites 682 and 688). Moreover, AOM prevents the diffusion of dissolved methane into overlying seawater. Throughout the Miocene period, these sites were located on a former shelf and the total carbon loss from the sediments was significantly higher in comparison with the present-day. Compared with the present-day shelf site, organic matter remineralization is high, and methane is produced but not stored within the sediments. Our model calculations rule out the possibility of present-day and former shelf site sediments off the coast of Peru as methane reservoirs. Remineralized TOC has to be considered, particularly in older sediments, when interpreting TOC profiles and calculating mass accumulation rates of total organic carbon (MARTOC). The more organic matter has been remineralized during the depositional history, the larger the difference between MARTOC calculated from measured TOC data, and from the sum of modeled and measured TOC data. Consequently, most reliable primary productivity calculations are based on the sum of measured relict TOC and the amount of remineralized organic carbon determined by modeling.

Microbial production of isotopically light iron(II) in a modern chemically precipitated sediment and implications for isotopic variations in ancient rocks

USGS Publications Warehouse

Tangalos, G.E.; Beard, B.L.; Johnson, C.M.; Alpers, Charles N.; Shelobolina, E.S.; Xu, H.; Konishi, H.; Roden, E.E.

2012-01-01

The inventories and Fe isotope composition of aqueous Fe(II) and solid-phase Fe compounds were quantified in neutral-pH, chemically precipitated sediments downstream of the Iron Mountain acid mine drainage site in northern California, USA. The sediments contain high concentrations of amorphous Fe(III) oxyhydroxides [Fe(III)am] that allow dissimilatory iron reduction (DIR) to predominate over Fe–S interactions in Fe redox transformation, as indicated by the very low abundance of Cr(II)-extractable reduced inorganic sulfur compared with dilute HCl-extractable Fe. δ56Fe values for bulk HCl- and HF-extractable Fe were ≈ 0. These near-zero bulk δ56Fe values, together with the very low abundance of dissolved Fe in the overlying water column, suggest that the pyrite Fe source had near-zero δ56Fe values, and that complete oxidation of Fe(II) took place prior to deposition of the Fe(III) oxide-rich sediment. Sediment core analyses and incubation experiments demonstrated the production of millimolar quantities of isotopically light (δ56Fe ≈ -1.5 to -0.5‰) aqueous Fe(II) coupled to partial reduction of Fe(III)am by DIR. Trends in the Fe isotope composition of solid-associated Fe(II) and residual Fe(III)am are consistent with experiments with synthetic Fe(III) oxides, and collectively suggest an equilibrium Fe isotope fractionation between aqueous Fe(II) and Fe(III)am of approximately -2‰. These Fe(III) oxide-rich sediments provide a model for early diagenetic processes that are likely to have taken place in Archean and Paleoproterozoic marine sediments that served as precursors for banded iron formations. Our results suggest pathways whereby DIR could have led to the formation of large quantities of low-δ56Fe minerals during BIF genesis.

Identification of varying time scales in sediment transport using the Hilbert-Huang Transform method

NASA Astrophysics Data System (ADS)

Kuai, Ken Z.; Tsai, Christina W.

2012-02-01

SummarySediment transport processes vary at a variety of time scales - from seconds, hours, days to months and years. Multiple time scales exist in the system of flow, sediment transport and bed elevation change processes. As such, identification and selection of appropriate time scales for flow and sediment processes can assist in formulating a system of flow and sediment governing equations representative of the dynamic interaction of flow and particles at the desired details. Recognizing the importance of different varying time scales in the fluvial processes of sediment transport, we introduce the Hilbert-Huang Transform method (HHT) to the field of sediment transport for the time scale analysis. The HHT uses the Empirical Mode Decomposition (EMD) method to decompose a time series into a collection of the Intrinsic Mode Functions (IMFs), and uses the Hilbert Spectral Analysis (HSA) to obtain instantaneous frequency data. The EMD extracts the variability of data with different time scales, and improves the analysis of data series. The HSA can display the succession of time varying time scales, which cannot be captured by the often-used Fast Fourier Transform (FFT) method. This study is one of the earlier attempts to introduce the state-of-the-art technique for the multiple time sales analysis of sediment transport processes. Three practical applications of the HHT method for data analysis of both suspended sediment and bedload transport time series are presented. The analysis results show the strong impact of flood waves on the variations of flow and sediment time scales at a large sampling time scale, as well as the impact of flow turbulence on those time scales at a smaller sampling time scale. Our analysis reveals that the existence of multiple time scales in sediment transport processes may be attributed to the fractal nature in sediment transport. It can be demonstrated by the HHT analysis that the bedload motion time scale is better represented by the ratio of the water depth to the settling velocity, h/ w. In the final part, HHT results are compared with an available time scale formula in literature.

Factors Controlling Sediment Load in The Central Anatolia Region of Turkey: Ankara River Basin.

PubMed

Duru, Umit; Wohl, Ellen; Ahmadi, Mehdi

2017-05-01

Better understanding of the factors controlling sediment load at a catchment scale can facilitate estimation of soil erosion and sediment transport rates. The research summarized here enhances understanding of correlations between potential control variables on suspended sediment loads. The Soil and Water Assessment Tool was used to simulate flow and sediment at the Ankara River basin. Multivariable regression analysis and principal component analysis were then performed between sediment load and controlling variables. The physical variables were either directly derived from a Digital Elevation Model or from field maps or computed using established equations. Mean observed sediment rate is 6697 ton/year and mean sediment yield is 21 ton/y/km² from the gage. Soil and Water Assessment Tool satisfactorily simulated observed sediment load with Nash-Sutcliffe efficiency, relative error, and coefficient of determination (R²) values of 0.81, -1.55, and 0.93, respectively in the catchment. Therefore, parameter values from the physically based model were applied to the multivariable regression analysis as well as principal component analysis. The results indicate that stream flow, drainage area, and channel width explain most of the variability in sediment load among the catchments. The implications of the results, efficient siltation management practices in the catchment should be performed to stream flow, drainage area, and channel width.

Factors Controlling Sediment Load in The Central Anatolia Region of Turkey: Ankara River Basin

NASA Astrophysics Data System (ADS)

Duru, Umit; Wohl, Ellen; Ahmadi, Mehdi

2017-05-01

Better understanding of the factors controlling sediment load at a catchment scale can facilitate estimation of soil erosion and sediment transport rates. The research summarized here enhances understanding of correlations between potential control variables on suspended sediment loads. The Soil and Water Assessment Tool was used to simulate flow and sediment at the Ankara River basin. Multivariable regression analysis and principal component analysis were then performed between sediment load and controlling variables. The physical variables were either directly derived from a Digital Elevation Model or from field maps or computed using established equations. Mean observed sediment rate is 6697 ton/year and mean sediment yield is 21 ton/y/km² from the gage. Soil and Water Assessment Tool satisfactorily simulated observed sediment load with Nash-Sutcliffe efficiency, relative error, and coefficient of determination ( R²) values of 0.81, -1.55, and 0.93, respectively in the catchment. Therefore, parameter values from the physically based model were applied to the multivariable regression analysis as well as principal component analysis. The results indicate that stream flow, drainage area, and channel width explain most of the variability in sediment load among the catchments. The implications of the results, efficient siltation management practices in the catchment should be performed to stream flow, drainage area, and channel width.

Chronology for fluctuations in late Pleistocene Sierra Nevada glaciers and lakes

USGS Publications Warehouse

Phillips, F.M.; Zreda, M.G.; Benson, L.V.; Plummer, M.A.; Elmore, D.; Sharma, Prakash

1996-01-01

Mountain glaciers, because of their small size, are usually close to equilibrium with the local climate and thus should provide a test of whether temperature oscillations in Greenland late in the last glacial period are part of global-scale climate variability or are restricted to the North Atlantic region. Correlation of cosmogenic chlorine-36 dates on Sierra Nevada moraines with a continuous radiocarbon-dated sediment record from nearby Owens Lake shows that Sierra Nevada glacial advances were associated with Heinrich events 5, 3, 2, and 1.

Hydrogeochemie und geogene Fluorid- und Borproblematik des Emschermergels im Münsterland

NASA Astrophysics Data System (ADS)

Wisotzky, Frank; Droste, Björn; Banning, Andre

2017-03-01

The hydrogeochemistry of the Cretaceous Emscher Fm. in northwest Germany was investigated, including analysis of 160 rock samples for carbon and sulfur content. Beneath a weathered zone, unweathered rocks containing pyrite were found. Groundwater data from the Emscher Fm. (580 analyses of house wells and additional literature data) were collected and evaluated. Some groundwater contains high fluoride and boron concentrations of up to 10 mg/l. Regionally, up to 30% of house wells show fluoride concentrations above 1.5 mg/l, and up to 50% above 1 mg/l boron. The spatial distribution depends on the presence of Quaternary cover sediments. Groundwater with high fluoride concentrations displays low Ca2+, and vice versa, indicating equilibrium with the mineral fluorite (CaF2). Concentrations above drinking water guidelines almost exclusively occur in ion exchange waters of the Na-HCO3 -(Cl) type with pH > 7.5. The main mobilization mechanism of both contaminants appears to be pH-triggered desorption from mineral surfaces.

A new method for fingerprinting sediments source contributions using distances from discriminant function analysis

USDA-ARS?s Scientific Manuscript database

Mixing models have been used to predict sediment source contributions. The inherent problem of the mixing models limited the number of sediment sources. The objective of this study is to develop and evaluate a new method using Discriminant Function Analysis (DFA) to fingerprint sediment source contr...

Relationship between compressional-wave velocity and porosity of sediments along subduction plate interface

NASA Astrophysics Data System (ADS)

Yamaguchi, M.; Hashimoto, Y.

2012-12-01

Evolution of physical properties of sediments along subduction interface has effects on wedge strength, wedge geometry, dewatering and dehydration processes, and seismic behavior. Sediments have initially more than 70% of porosity prior to subduction. Through underthrusting and accretion, porosity of sediments decreases by compaction and cementation to be lithified sediments. The purpose of this study is to understand evolution of physical properties from a state before subduction to a state within a wedge using a relationship between compressional-wave velocity and porosity. In this study, we obtained new data for sediments from a reference site in IODP NanTroSEIZE, Expedition 333. In addition to that, we have complied velocity-porosity relationships for the samples and also for previous studies from NanTroSEIZE (off Kumano) (Hashimoto et al., 2010, 2011), ODP Leg 190 (off Shikoku) (Hoffman and Tobin, 2004) and ODP Leg 170 (off Costa Rica) (Gettemy and Tobin, 2003). Velocity measurement procedure in this study to obtain new data is as following: Two pumps were used to control pore fluid pressure and confining pressure. The pore pressure of 1000kPa was kept under drained conditions. Confining (effective) pressure was increased stepwise in the measurements. Velocity measurements were conducted under isotropic pressure conditions. Confining pressure was pressurized in tens seconds and kept for more than 8 hours for next step to obtain equilibrium conditions between effective pressure and sediments strain. Lead zirconate titanate (PZT) shear wave transducers (500kHz) were used in a source-receiver pair to measure wave speed. Porosity and P-wave velocity ranges about 27 - 75% and 1.4 - 2.2 km/s in this study, respectively. In the comparison in Vp-porosity relationships between sedimetns from reference sites and others, sediments were classified into two, simply compacted sediments (reference site and slope sediments) and wedge sediments. Different trends in Vp-porosity relationships were observed for the classified sediments. For compacted sediments, Vp-porosity relationships are along the global empirical relationships (Erickson and Jarrard 1988) and almost within the area between normal and highly compaction curves. On the other hand, some of Vp-porosity relationships for wedge sediments represent trends with higher velocity at a porosity. Such trend was observed for wedge sediments from Site C0001 and C0004. Those higher Vp trend in Vp-porosity relationship for wedge sediments can be explained by shear strain of sediments and/or cementation. Even though the velocity measurements was conducted under hydrostatic condition, we examined the void ratio-porosity curve as a kind of compaction curve. On the basis of the curves, break points were observed at the pressure which corresponds to the effective pressure assuming the hydrostatic pore fluid pressure. The result suggests that the sediments were under condition of normal compaction. Some of void ratio-porosity curve represent a evidence of weak cement which can correspond with anomaly in porosity-depth curve in the shallow portion of the reference sites.

Use of surrogate technologies to estimate suspended sediment in the Clearwater River, Idaho, and Snake River, Washington, 2008-10

USGS Publications Warehouse

Wood, Molly S.; Teasdale, Gregg N.

2013-01-01

Elevated levels of fluvial sediment can reduce the biological productivity of aquatic systems, impair freshwater quality, decrease reservoir storage capacity, and decrease the capacity of hydraulic structures. The need to measure fluvial sediment has led to the development of sediment surrogate technologies, particularly in locations where streamflow alone is not a good estimator of sediment load because of regulated flow, load hysteresis, episodic sediment sources, and non-equilibrium sediment transport. An effective surrogate technology is low maintenance and sturdy over a range of hydrologic conditions, and measured variables can be modeled to estimate suspended-sediment concentration (SSC), load, and duration of elevated levels on a real-time basis. Among the most promising techniques is the measurement of acoustic backscatter strength using acoustic Doppler velocity meters (ADVMs) deployed in rivers. The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, Walla Walla District, evaluated the use of acoustic backscatter, turbidity, laser diffraction, and streamflow as surrogates for estimating real-time SSC and loads in the Clearwater and Snake Rivers, which adjoin in Lewiston, Idaho, and flow into Lower Granite Reservoir. The study was conducted from May 2008 to September 2010 and is part of the U.S. Army Corps of Engineers Lower Snake River Programmatic Sediment Management Plan to identify and manage sediment sources in basins draining into lower Snake River reservoirs. Commercially available acoustic instruments have shown great promise in sediment surrogate studies because they require little maintenance and measure profiles of the surrogate parameter across a sampling volume rather than at a single point. The strength of acoustic backscatter theoretically increases as more particles are suspended in the water to reflect the acoustic pulse emitted by the ADVM. ADVMs of different frequencies (0.5, 1.5, and 3 Megahertz) were tested to target various sediment grain sizes. Laser diffraction and turbidity also were tested as surrogate technologies. Models between SSC and surrogate variables were developed using ordinary least-squares regression. Acoustic backscatter using the high frequency ADVM at each site was the best predictor of sediment, explaining 93 and 92 percent of the variability in SSC and matching sediment sample data within +8.6 and +10 percent, on average, at the Clearwater River and Snake River study sites, respectively. Additional surrogate models were developed to estimate sand and fines fractions of suspended sediment based on acoustic backscatter. Acoustic backscatter generally appears to be a better estimator of suspended sediment concentration and load over short (storm event and monthly) and long (annual) time scales than transport curves derived solely from the regression of conventional sediment measurements and streamflow. Changing grain sizes, the presence of organic matter, and aggregation of sediments in the river likely introduce some variability in the model between acoustic backscatter and SSC.

TG-FTIR analysis on pyrolysis and combustion of marine sediment

NASA Astrophysics Data System (ADS)

Oudghiri, Fatiha; Allali, Nabil; Quiroga, José María; Rodríguez-Barroso, María Rocío

2016-09-01

In this paper, the pyrolysis and combustion of sediment have been compared using thermogravimetric analysis (TG) coupled with Fourier transform infrared spectrometry (TG-FTIR) analysis. The TG results showed that both the pyrolysis and combustion of sediment presented four weight loss stages, each. The evolving gaseous products during pyrolysis were H2O, CO2 and hydrocarbons, while combustion yielded considerable amounts of CO2, in addition to H2O, CO, Cdbnd C, Cdbnd O and NH3. Comparing the pyrolysis and combustion TG-FTIR curves, it is possible to evaluate the effect of oxygen presence in the temperature range of 200-600 °C, which increases the volatilisation rate of organic matter in sediment. For the better detection of organic and inorganic matter in sediment by TG-FTIR analysis it is recommended to work in combustion mode of sediment.

Southwest Greenland's Alpine Glacier History: Recent Glacier Change in the Context of the Holocene Geologic Record

NASA Astrophysics Data System (ADS)

Larocca, L. J.; Axford, Y.; Lasher, G. E.; Lee, C. W.

2017-12-01

Due to anthropogenic climate change, the Arctic region is currently undergoing major transformation, and is expected to continue warming much faster than the global average. To put recent and future changes into context, a longer-term understanding of this region's past response to natural climate variability is needed. Given their sensitivity to modest climate change, small alpine glaciers and ice caps on Greenland's coastal margin (beyond the Greenland Ice Sheet) represent ideal features to record climate variability through the Holocene. Here we investigate the Holocene history of a small ( 160 square km) ice cap and adjacent alpine glaciers, located in southwest Greenland approximately 50 km south of Nuuk. We employ measurements on sediment cores from a glacier-fed lake in combination with geospatial analysis of satellite images spanning the past several decades. Sedimentary indicators of sediment source and thus glacial activity, including organic matter abundance, inferred chlorophyll-a content, sediment major element abundances, grain size, and magnetic susceptibility are presented from cores collected from a distal glacier-fed lake (informally referred to here as Per's Lake) in the summer of 2015. These parameters reflect changes in the amount and character of inorganic detrital input into the lake, which may be linked to the size of the upstream glaciers and ice cap and allow us to reconstruct their status through the Holocene. Additionally, we present a complementary record of recent changes in Equilibrium Line Altitude (ELA) for the upstream alpine glaciers. Modern ELAs are inferred using the accumulation area ratio (AAR) method in ArcGIS via Landsat and Worldview-2 satellite imagery, along with elevation data obtained from digital elevation models (DEMs). Paleo-ELAs are inferred from the positions of moraines and trim lines marking the glaciers' most recent expanded state, which we attribute to the Little Ice Age (LIA). This approach will allow us to explore the possibility of quantitatively or qualitatively linking changes in ELA (and thus the size of upstream glaciers) to specific sediment parameters. Ultimately, we aim to reconstruct glacier variability through the entire Holocene epoch, and to compare this history with 20th and 21st Century changes.

Erosion characteristics and horizontal variability for small erosion depths in the Sacramento-San Joaquin River Delta, California, USA

NASA Astrophysics Data System (ADS)

Schoellhamer, David H.; Manning, Andrew J.; Work, Paul A.

2017-06-01

Erodibility of cohesive sediment in the Sacramento-San Joaquin River Delta (Delta) was investigated with an erosion microcosm. Erosion depths in the Delta and in the microcosm were estimated to be about one floc diameter over a range of shear stresses and times comparable to half of a typical tidal cycle. Using the conventional assumption of horizontally homogeneous bed sediment, data from 27 of 34 microcosm experiments indicate that the erosion rate coefficient increased as eroded mass increased, contrary to theory. We believe that small erosion depths, erosion rate coefficient deviation from theory, and visual observation of horizontally varying biota and texture at the sediment surface indicate that erosion cannot solely be a function of depth but must also vary horizontally. We test this hypothesis by developing a simple numerical model that includes horizontal heterogeneity, use it to develop an artificial time series of suspended-sediment concentration (SSC) in an erosion microcosm, then analyze that time series assuming horizontal homogeneity. A shear vane was used to estimate that the horizontal standard deviation of critical shear stress was about 30% of the mean value at a site in the Delta. The numerical model of the erosion microcosm included a normal distribution of initial critical shear stress, a linear increase in critical shear stress with eroded mass, an exponential decrease of erosion rate coefficient with eroded mass, and a stepped increase in applied shear stress. The maximum SSC for each step increased gradually, thus confounding identification of a single well-defined critical shear stress as encountered with the empirical data. Analysis of the artificial SSC time series with the assumption of a homogeneous bed reproduced the original profile of critical shear stress, but the erosion rate coefficient increased with eroded mass, similar to the empirical data. Thus, the numerical experiment confirms the small-depth erosion hypothesis. A linear model of critical shear stress and eroded mass is proposed to simulate small-depth erosion, assuming that the applied and critical shear stresses quickly reach equilibrium.

Erosion characteristics and horizontal variability for small erosion depths in the Sacramento-San Joaquin River Delta, California, USA

USGS Publications Warehouse

Schoellhamer, David H.; Manning, Andrew J.; Work, Paul A.

2017-01-01

Erodibility of cohesive sediment in the Sacramento-San Joaquin River Delta (Delta) was investigated with an erosion microcosm. Erosion depths in the Delta and in the microcosm were estimated to be about one floc diameter over a range of shear stresses and times comparable to half of a typical tidal cycle. Using the conventional assumption of horizontally homogeneous bed sediment, data from 27 of 34 microcosm experiments indicate that the erosion rate coefficient increased as eroded mass increased, contrary to theory. We believe that small erosion depths, erosion rate coefficient deviation from theory, and visual observation of horizontally varying biota and texture at the sediment surface indicate that erosion cannot solely be a function of depth but must also vary horizontally. We test this hypothesis by developing a simple numerical model that includes horizontal heterogeneity, use it to develop an artificial time series of suspended-sediment concentration (SSC) in an erosion microcosm, then analyze that time series assuming horizontal homogeneity. A shear vane was used to estimate that the horizontal standard deviation of critical shear stress was about 30% of the mean value at a site in the Delta. The numerical model of the erosion microcosm included a normal distribution of initial critical shear stress, a linear increase in critical shear stress with eroded mass, an exponential decrease of erosion rate coefficient with eroded mass, and a stepped increase in applied shear stress. The maximum SSC for each step increased gradually, thus confounding identification of a single well-defined critical shear stress as encountered with the empirical data. Analysis of the artificial SSC time series with the assumption of a homogeneous bed reproduced the original profile of critical shear stress, but the erosion rate coefficient increased with eroded mass, similar to the empirical data. Thus, the numerical experiment confirms the small-depth erosion hypothesis. A linear model of critical shear stress and eroded mass is proposed to simulate small-depth erosion, assuming that the applied and critical shear stresses quickly reach equilibrium.

Hydro-climatic Changes: Potential Non-linear Responses of Phosphorus Dynamic in Aquatic/Semi-aquatic Systems

NASA Astrophysics Data System (ADS)

Pant, H. K.

2007-12-01

Depending on resilience, threshold and lag times, hydro-climatic changes can cause nonlinear and/or irreversible changes in phosphorus (P) dynamic, and instigate P enrichment in aquatic/semi-aquatic systems. Thus, studying direct/indirect effects of expected global climate change on bioavailability of organic P in aquatic systems are in critical need, to help manage or increase the resilience of the ecosystem. The central hypothesis of this study is that P dynamic in aquatic, especially freshwater, ecosystem is likely to behave nonlinearly due to expected changes in sediment and water acidity, redox status, etc., because of potential hydro-climatic changes in the decades to come, thus, could face irreversible adverse changes. Devising possible biological and chemical treatments for the removal of P from eutrophic lakes, estuaries, etc, as well as helping in predicting the movement and fate of P under changing hydro-climatic conditions would be crucial to manage aquatic ecosystem in the near future. The critical question is not how much P is stored in any given aquatic/semi-aquatic system, but how the resilience and nonlinearity relate to the stability of stored P are affected due to the levels of environmental stressors, which are expected to fluctuate due to global change in the decades to come. Studies related to 31P Nuclear Magnetic Resonance Spectroscopy analysis, and multiple hydraulic retention cycles showed that, in general, frequent drying and reflooding of a semi-aquatic system such as wetland could significantly increase the bioavailability of P due to degradation of relatively less stable organic P, e.g., glycerophosphate and nucleoside monophosphate. Moreover, nutrients flux from sediments to the water column depended on the concentration gradients of the sediment-water interface and redox status. Shift in equilibrium P concentration of the water column as the water level rises, may cause release of adsorbed P from the sediments. Restoration of a eutrophic system may involve stepwise efforts including control of catchment nutrient inputs, internal nutrient loading, and biomanipulation, however, flooding, previously non-flooded areas, could export massive amount of P to nearby aquatic bodies, in turn, may cause collapse of the ecosystem.

Estimation of apparent rate coefficients for radionuclides interacting with marine sediments from Novaya Zemlya.

PubMed

Børretzen, P; Salbu, B

2000-10-30

To assess the impact of radionuclides entering the marine environment from dumped nuclear waste, information on the physico-chemical forms of radionuclides and their mobility in seawater-sediment systems is essential. Due to interactions with sediment components, sediments may act as a sink, reducing the mobility of radionuclides in seawater. Due to remobilisation, however, contaminated sediments may also act as a potential source of radionuclides to the water phase. In the present work, time-dependent interactions of low molecular mass (LMM, i.e. species < 10 kDa) radionuclides with sediments from the Stepovogo Fjord, Novaya Zemlya and their influence on the distribution coefficients (Kd values) have been studied in tracer experiments using 109Cd2+ and 60Co2+ as gamma tracers. Sorption of the LMM tracers occurred rapidly and the estimated equilibrium Kd(eq)-values for 109Cd and 60Co were 500 and 20000 ml/g, respectively. Remobilisation of 109Cd and 60Co from contaminated sediment fractions as a function of contact time was studied using sequential extraction procedures. Due to redistribution, the reversibly bound fraction of the gamma tracers decreased with time, while the irreversibly (or slowly reversibly) associated fraction of the gamma tracers increased. Two different three-compartment models, one consecutive and one parallel, were applied to describe the time-dependent interaction of the LMM tracers with operationally defined reversible and irreversible (or slowly reversible) sediment fractions. The interactions between these fractions were described using first order differential equations. By fitting the models to the experimental data, apparent rate constants were obtained using numerical optimisation software. The model optimisations showed that the interactions of LMM 60Co were well described by the consecutive model, while the parallel model was more suitable to describe the interactions of LMM 109Cd with the sediments, when the squared sum of residuals were compared. The rate of sorption of the irreversibly (or slowly reversibly) associated fraction was greater than the rate of desorption of the reversibly bound fractions (i.e. k3 > k2) for both radionuclides. Thus, the Novaya Zemlya sediment are supposed to act as a sink for the radionuclides under oxic conditions, and transport to the water phase should mainly be attributed to resuspended particles.

Relationship of pyrogenic polycyclic aromatic hydrocarbons contamination among environmental solid media.

PubMed

Kim, Dong Won; Kim, Seung Kyu; Lee, Dong Soo

2009-06-01

This study compared the contamination levels and compositional characteristics of PAHs in soil, SS and sediment to understand the cross media characteristics among the three solid media and ecological risk implications for the purpose to help manage in a more integrated manner the environmental quality objectives or the ecological risk in the media. The study area included urban (metropolis and industrial zone), suburban and rural sites. Seasonal samples were concurrently collected in surface soils, surface waters (dissolved and suspended solid (SS) phases separately) and sediments. The emission estimate and source characterizing PAH indices consistently indicated that PAHs were from pyrogenic sources. The level of total PAHs in soil declined along the wind direction from the urban areas to the rural areas. The sorption power of soil appeared distinctly different between the urban and rural areas. The contamination levels and PAH profiles in soil and sediment were closely related to each other while no such correlation was observed between SS and sediment or SS and soil. Comparisons of the observed partitioning coefficients with three different partitioning equilibrium models strongly suggested that PAHs in water appeared to undergo partitioning among the dissolved phase in water, dissolved organic matter, and organic and soot carbons in SS, which might account for the level and profile of PAHs in SS that were not correlated with those in soil or sediment. The observed results suggested that PAHs of pyrogenic origins entered into soil, sediment, and water by the atmospheric deposition and subsequent other cross-media transfers of PAHs. The results also evidenced that sediments were principally contaminated with PAHs delivered via surface run-off from soil although in the urban areas the run-off influence appeared less immediate than in the rural areas. Environmental quality objectives for PAHs in soil and sediment should be set in a coherent manner and the protection efforts for the sediment quality should be made with the consideration of the soil quality particularly where the river bottom sediment is renewed periodically with eroded soil due to heavy rain and/or large river regime coefficient. In spite of the difference in PAH profiles among the three solid media, BaP commonly appeared to present the greatest TEQ, suggesting that strict regulation of BaP is necessary to efficiently and substantially minimize the total risk of the environmental PAHs.

Toxicity of sediments potentially contaminated by coal mining and natural gas extraction to unionid mussels and commonly tested benthic invertebrates

USGS Publications Warehouse

Wang, Ning; Ingersoll, Christopher G.; Kunz, James L.; Brumbaugh, William G.; Kane, Cindy M.; Evans, R. Brian; Alexander, Steven; Walker, Craig; Bakaletz, Steve

2013-01-01

Sediment toxicity tests were conducted to assess potential effects of contaminants associated with coal mining or natural gas extraction activities in the upper Tennessee River basin and eastern Cumberland River basin in the United States. Test species included two unionid mussels (rainbow mussel, Villosa iris, and wavy-rayed lampmussel, Lampsilis fasciola, 28-d exposures), and the commonly tested amphipod, Hyalella azteca (28-d exposure) and midge, Chironomus dilutus (10-d exposure). Sediments were collected from seven test sites with mussel communities classified as impacted and in proximity to coal mining or gas extraction activities, and from five reference sites with mussel communities classified as not impacted and no or limited coal mining or gas extraction activities. Additional samples were collected from six test sites potentially with high concentrations of polycyclic aromatic hydrocarbons (PAHs) and from a test site contaminated by a coal ash spill. Mean survival, length, or biomass of one or more test species was reduced in 10 of 14 test samples (71%) from impacted areas relative to the response of organisms in the five reference samples. A higher proportion of samples was classified as toxic to mussels (63% for rainbow mussels, 50% for wavy-rayed lampmussels) compared with amphipods (38%) or midge (38%). Concentrations of total recoverable metals and total PAHs in sediments did not exceed effects-based probable effect concentrations (PECs). However, the survival, length, or biomasses of the mussels were reduced significantly with increasing PEC quotients for metals and for total PAHs, or with increasing sum equilibrium-partitioning sediment benchmark toxic units for PAHs. The growth of the rainbow mussel also significantly decreased with increasing concentrations of a major anion (chloride) and major cations (calcium and magnesium) in sediment pore water. Results of the present study indicated that (1) the findings from laboratory tests were generally consistent with the field observations of impacts on mussel populations; (2) total recoverable metals, PAHs, or major ions, or all three in sediments might have contributed to the sediment toxicity; (3) the mussels were more sensitive to the contaminants in sediments than the commonly tested amphipod and midge; and (4) a sediment toxicity benchmark of 1.0 based on PECs may not be protective of mussels.

Prion disease susceptibility is affected by β-structure folding propensity and local side-chain interactions in PrP

PubMed Central

Khan, M. Qasim; Sweeting, Braden; Mulligan, Vikram Khipple; Arslan, Pharhad Eli; Cashman, Neil R.; Pai, Emil F.; Chakrabartty, Avijit

2010-01-01

Prion diseases occur when the normally α-helical prion protein (PrP) converts to a pathological β-structured state with prion infectivity (PrPSc). Exposure to PrPSc from other mammals can catalyze this conversion. Evidence from experimental and accidental transmission of prions suggests that mammals vary in their prion disease susceptibility: Hamsters and mice show relatively high susceptibility, whereas rabbits, horses, and dogs show low susceptibility. Using a novel approach to quantify conformational states of PrP by circular dichroism (CD), we find that prion susceptibility tracks with the intrinsic propensity of mammalian PrP to convert from the native, α-helical state to a cytotoxic β-structured state, which exists in a monomer–octamer equilibrium. It has been controversial whether β-structured monomers exist at acidic pH; sedimentation equilibrium and dual-wavelength CD evidence is presented for an equilibrium between a β-structured monomer and octamer in some acidic pH conditions. Our X-ray crystallographic structure of rabbit PrP has identified a key helix-capping motif implicated in the low prion disease susceptibility of rabbits. Removal of this capping motif increases the β-structure folding propensity of rabbit PrP to match that of PrP from mouse, a species more susceptible to prion disease. PMID:21041683

Prion disease susceptibility is affected by beta-structure folding propensity and local side-chain interactions in PrP.

PubMed

Khan, M Qasim; Sweeting, Braden; Mulligan, Vikram Khipple; Arslan, Pharhad Eli; Cashman, Neil R; Pai, Emil F; Chakrabartty, Avijit

2010-11-16

Prion diseases occur when the normally α-helical prion protein (PrP) converts to a pathological β-structured state with prion infectivity (PrP(Sc)). Exposure to PrP(Sc) from other mammals can catalyze this conversion. Evidence from experimental and accidental transmission of prions suggests that mammals vary in their prion disease susceptibility: Hamsters and mice show relatively high susceptibility, whereas rabbits, horses, and dogs show low susceptibility. Using a novel approach to quantify conformational states of PrP by circular dichroism (CD), we find that prion susceptibility tracks with the intrinsic propensity of mammalian PrP to convert from the native, α-helical state to a cytotoxic β-structured state, which exists in a monomer-octamer equilibrium. It has been controversial whether β-structured monomers exist at acidic pH; sedimentation equilibrium and dual-wavelength CD evidence is presented for an equilibrium between a β-structured monomer and octamer in some acidic pH conditions. Our X-ray crystallographic structure of rabbit PrP has identified a key helix-capping motif implicated in the low prion disease susceptibility of rabbits. Removal of this capping motif increases the β-structure folding propensity of rabbit PrP to match that of PrP from mouse, a species more susceptible to prion disease.

Hydrologic controls on equilibrium soil depths

NASA Astrophysics Data System (ADS)

Nicótina, L.; Tarboton, D. G.; Tesfa, T. K.; Rinaldo, A.

2011-04-01

This paper deals with modeling the mutual feedbacks between runoff production and geomorphological processes and attributes that lead to patterns of equilibrium soil depth. Our primary goal is an attempt to describe spatial patterns of soil depth resulting from long-term interactions between hydrologic forcings and soil production, erosion, and sediment transport processes under the framework of landscape dynamic equilibrium. Another goal is to set the premises for exploiting the role of soil depths in shaping the hydrologic response of a catchment. The relevance of the study stems from the massive improvement in hydrologic predictions for ungauged basins that would be achieved by using directly soil depths derived from geomorphic features remotely measured and objectively manipulated. Hydrological processes are here described by explicitly accounting for local soil depths and detailed catchment topography. Geomorphological processes are described by means of well-studied geomorphic transport laws. The modeling approach is applied to the semiarid Dry Creek Experimental Watershed, located near Boise, Idaho. Modeled soil depths are compared with field data obtained from an extensive survey of the catchment. Our results show the ability of the model to describe properly the mean soil depth and the broad features of the distribution of measured data. However, local comparisons show significant scatter whose origins are discussed.

In situ visualization and data analysis for turbidity currents simulation

NASA Astrophysics Data System (ADS)

Camata, Jose J.; Silva, Vítor; Valduriez, Patrick; Mattoso, Marta; Coutinho, Alvaro L. G. A.

2018-01-01

Turbidity currents are underflows responsible for sediment deposits that generate geological formations of interest for the oil and gas industry. LibMesh-sedimentation is an application built upon the libMesh library to simulate turbidity currents. In this work, we present the integration of libMesh-sedimentation with in situ visualization and in transit data analysis tools. DfAnalyzer is a solution based on provenance data to extract and relate strategic simulation data in transit from multiple data for online queries. We integrate libMesh-sedimentation and ParaView Catalyst to perform in situ data analysis and visualization. We present a parallel performance analysis for two turbidity currents simulations showing that the overhead for both in situ visualization and in transit data analysis is negligible. We show that our tools enable monitoring the sediments appearance at runtime and steer the simulation based on the solver convergence and visual information on the sediment deposits, thus enhancing the analytical power of turbidity currents simulations.

Large wood, sediment, and flow regimes: Their interactions and temporal changes caused by human impacts in Japan

NASA Astrophysics Data System (ADS)

Nakamura, Futoshi; Seo, Jung Il; Akasaka, Takumi; Swanson, Frederick J.

2017-02-01

Water, sediment, and large wood (LW) are the three key components of dynamic river-floodplain ecosystems. We examined variations in sediment and LW discharge with respect to precipitation, the presence of dams, land and river use change, and related channel incision and forest expansion on gravel bars and floodplains across Japan. The results indicated that unit sediment discharge and unit LW discharge were smaller in southern Japan where precipitation intensity is generally much greater. Effective precipitation, an index that takes current and antecedent precipitation into account, was a strong predictor of discharge in small watersheds, but not in larger watersheds. However, precipitation intensities related to unit sediment discharge in intermediate and large watersheds were smaller than those associated with unit LW discharge, which we attribute to differences in particle shape and size and also transport mechanisms. The relationship between river flow and discharge of sediment and LW lead us to posit that discharges of these components are supply limited in southern Japan and transport limited in northern Japan. The cross-sectional mean low-flow bed elevation of gravel-bed and sand-bed rivers in Japan decreased by 0.71 and 0.74 m on average, respectively, over the period 1960-2000. Forest expansion on bars and floodplains has been prominent since the 1990s, and trees apparently began to colonize gravel bars 10 to 20 years after riverbed degradation began. Forest recovery in headwater basins, dam construction, gravel mining, and channelization over the past half century are likely the dominant factors that significantly reduced downstream sediment delivery, thereby promoting channel incision and forest expansion. Changes in rivers and floodplains associated with channel incision and forest expansion alter the assemblages of aquatic and terrestrial organisms in riverine landscapes of Japan, and climate change may contribute to this change by intensified precipitation. Additionally, regime shifts of water, sediment, and LW may continue or they may reach a dynamic state of quasi-equilibrium in the future. Continued monitoring of these three components, taking into account their geographic variation, is critical for anticipating and managing future changes in river-floodplain systems in Japan and around the world.

Sediment sorting at a side channel bifurcation

NASA Astrophysics Data System (ADS)

van Denderen, Pepijn; Schielen, Ralph; Hulscher, Suzanne

2017-04-01

Side channels have been constructed to reduce the flood risk and to increase the ecological value of the river. In various Dutch side channels large aggradation in these channels occurred after construction. Measurements show that the grain size of the deposited sediment in the side channel is smaller than the grain size found on the bed of the main channel. This suggest that sorting occurs at the bifurcation of the side channel. The objective is to reproduce with a 2D morphological model the fining of the bed in the side channel and to study the effect of the sediment sorting on morphodynamic development of the side channel. We use a 2D Delft3D model with two sediment fractions. The first fraction corresponds with the grain size that can be found on the bed of the main channel and the second fraction corresponds with the grain size found in the side channel. With the numerical model we compute several side channel configurations in which we vary the length and the width of the side channel, and the curvature of the upstream channel. From these computations we can derive the equilibrium state and the time scale of the morphodynamic development of the side channel. Preliminary results show that even when a simple sediment transport relation is used, like Engelund & Hansen, more fine sediment enters the side channel than coarse sediment. This is as expected, and is probably related to the bed slope effects which are a function of the Shields parameter. It is expected that by adding a sill at the entrance of the side channel the slope effect increases. This might reduce the amount of coarse sediment which enters the side channel even more. It is unclear whether the model used is able to reproduce the effect of such a sill correctly as modelling a sill and reproducing the correct hydrodynamic and morphodynamic behaviour is not straightforward in a 2D model. Acknowledgements: This research is funded by STW, part of the Dutch Organization for Scientific Research under grant number P12-P14 (RiverCare Perspective Programme) project number 13516.

Using DoD Maps to Examine the Influence of Large Wood on Channel Morphodynamics

NASA Astrophysics Data System (ADS)

MacKenzie, L. C.; Eaton, B. C.

2012-12-01

Since the advent of logging and slash burning, many streams in British Columbia have experienced changes to the amount of large wood added to or removed from these systems, which has, in turn, influenced the storage and movement of sediment within these channels. This set of flume experiments examines and quantifies the impacts of large wood on the reach-scale morphodynamics. Understanding the relation between the wood load and channel morphodynamics is important when assessing the quality of the aquatic habitat of a stream. The experiments were conducted using a fixed-bank, mobile bed Froude-scaled physical model of Fishtrap Creek, British Columbia, built in a shallow flume that is 1.5 m wide and 11 m long. The stream table was run without wood until it reached equilibrium at which point wood pieces of varying sizes were added to the channel. The bed morphology was surveyed using a laser profiling system at five-hour intervals. The laser profiles were then interpolated to create digital elevation models (DEM) from which DEM of difference (DoD) maps were produced. Analysis of the DoD maps focused on quantifying and locating differences in the distribution of sediment storage, erosion, and deposition between the runs as well as those induced by the addition of large wood into the stream channel. We then assessed the typical influence of individual pieces and of jams on pool frequency, size and distribution along the channels.

Late Glacial and Holocene Paleolimnology of two temperate lakes inferred from sediment organic δ13C chronology

NASA Astrophysics Data System (ADS)

Lovan, N. A.; Krishnamurthy, R. V.

2000-03-01

The stable carbon isotope (δ13C) and elemental C/N ratios in Total Organic Carbon (TOC) extracted from radiometrically dated cores from two Midwestern USA lakes were determined to investigate the factors that control these values in temperate lakes. The range of δ13C values (-26 to -32%) and C/N ratios (mean value ˜10.8) are typical of values reported for other temperate lake organic matter in this region. In the core from Lake Winnebago, Wisconsin, a negative correlation was seen between the TOC and δ13C, which can be interpreted in terms of a re-mixing and consumption of sedimented organic carbon along with rapid equilibration throughout the water column. No correlation was seen between the TOC and δ13C in the record from Ladd Lake, Ohio, implying that in this latter lake productivity alone was not a singular process controlling the isotope ratio. Here, it is suggested that equilibrium conditions are maintained such that the DIC of the water is never depleted of aqueous CO2 during high organic production and the resulting δ13C of the organic carbon lacks correlation with the TOC. Further, in this lake a fine resolution analysis was carried out which indicated a possible anthropogenic influence on the isotope ratio around times when human settlement (˜300 yrs ago) and enhanced agricultural practices (˜80 yrs ago) were significant. The study shows that carbon isotope studies are useful in paleolimnologic investigations.

Estimation of sediments in urban drainage areas and relation analysis between sediments and inundation risk using GIS.

PubMed

Moojong, Park; Hwandon, Jun; Minchul, Shin

2008-01-01

Sediments entering the sewer in urban areas reduce the conveyance in sewer pipes, which increases inundation risk. To estimate sediment yields, individual landuse areas in each sub-basin should be obtained. However, because of the complex nature of an urban area, this is almost impossible to obtain manually. Thus, a methodology to obtain individual landuse areas for each sub-basin has been suggested for estimating sediment yields. Using GIS, an urban area is divided into sub-basins with respect to the sewer layout, with the area of individual landuse estimated for each sub-basin. The sediment yield per unit area for each sub-basin is then calculated. The suggested method was applied to the GunJa basin in Seoul. For a relation analysis between sediments and inundation risk, sub-basins were ordered by the sediment yields per unit area and compared with historical inundation areas. From this analysis, sub-basins with higher order were found to match the historical inundation areas. Copyright IWA Publishing 2008.

Suspended sediment in the St. Francis River at St. Francis, Arkansas, 1986-95

USGS Publications Warehouse

Green, W. Reed; Barks, C. Shane; Hall, Alan P.

2000-01-01

Daily suspended-sediment concentrations were analyzed from the St. Francis River at St. Francis, Arkansas during 1986 through 1995. Suspended-sediment particle size distribution was measured in selected samples from 1978 through 1998. These data are used to assess changes in suspended-sediment concentrations and loads through time. Suspended-sediment concentrations were positively related to discharge. At higher flows, percent silt-clay was negatively related to discharge. Nonparametric trend analysis (Mann-Kendall test) of suspended-sediment concentration over the period of record indicated a slight decrease in concentration. Flow-adjusted residuals of suspended-sediment concentration also decreased slightly through the same period. No change was identified in annual suspended-sediment load or annual flow-weighted concentration. Continued monitorig of daily-suspended-sediment concentrations at this site and others, and similar data analysis at other sites where data are available will provide a better understanding of sediment transport withint the St. Francis River.

Variations in Nutrient Cycling and Meltwater Composition Between Ice-Lidded and Open System Cryoconites

NASA Astrophysics Data System (ADS)

Mass, A.

2016-12-01

Cryoconites are small melt pools on the ablation surface of glaciers created by the accumulation of aeolian sediment with a lower albedo than the surrounding ice. While many cryoconites remain open to the surrounding atmosphere, environmental conditions in the McMurdo Dry Valleys of Antarctica often lead to the formation of dense ice lids due to advection from cold winds. These lidded cryoconites are isolated from atmospheric exchange while maintaining subsurface melt in a solid-state greenhouse. The varying conditions for the formation and freeze-thaw cycle of cryoconites lead to a range of biogeochemical processes occurring within the pools. This study analyzed the biochemistry of both open and lidded cryoconite water from six glaciers in the Dry Valleys throughout the initial pulse melt, equilibrium, and refreezing periods in 2013- 2015. Many of the spatial gradients in carbon cycling, solute concentrations, and pH identified for lidded cryoconites exhibited opposite trends for pools in equilibrium with the atmosphere, while temporal gradients were less diverse for open pools.

Quality-assurance plan for the analysis of suspended sediment by the U.S. Geological Survey in Montana

USGS Publications Warehouse

Dodge, Kent A.; Lambing, John H.

2006-01-01

A quality-assurance plan has been developed for use by the sediment laboratory of the U.S. Geological Survey Montana Water Science Center in conducting activities related to the analysis of suspended sediment. The plan documents quality-assurance policies for sediment-laboratory certification, personnel responsibilities and training, documentation requirements, and laboratory safety. The plan also documents quality-assurance procedures related to laboratory equipment and supplies, sample management, sample analysis, analytical quality control, and data management.

Oxygen isotopes in nitrite: Analysis, calibration, and equilibration

USGS Publications Warehouse

Casciotti, K.L.; Böhlke, J.K.; McIlvin, M.R.; Mroczkowski, S.J.; Hannon, J.E.

2007-01-01

Nitrite is a central intermediate in the nitrogen cycle and can persist in significant concentrations in ocean waters, sediment pore waters, and terrestrial groundwaters. To fully interpret the effect of microbial processes on nitrate (NO3-), nitrite (NO2-), and nitrous oxide (N2O) cycling in these systems, the nitrite pool must be accessible to isotopic analysis. Furthermore, because nitrite interferes with most methods of nitrate isotopic analysis, accurate isotopic analysis of nitrite is essential for correct measurement of nitrate isotopes in a sample that contains nitrite. In this study, nitrite salts with varying oxygen isotopic compositions were prepared and calibrated and then used to test the denitrifier method for nitrite oxygen isotopic analysis. The oxygen isotopic fractionation during nitrite reduction to N2O by Pseudomonas aureofaciens was lower than for nitrate conversion to N2O, while oxygen isotopic exchange between nitrite and water during the reaction was similar. These results enable the extension of the denitrifier method to oxygen isotopic analysis of nitrite (in the absence of nitrate) and correction of nitrate isotopes for the presence of nitrite in “mixed” samples. We tested storage conditions for seawater and freshwater samples that contain nitrite and provide recommendations for accurate oxygen isotopic analysis of nitrite by any method. Finally, we report preliminary results on the equilibrium isotope effect between nitrite and water, which can play an important role in determining the oxygen isotopic value of nitrite where equilibration with water is significant.

U.S. Geological Survey Quality-Assurance Project for Sediment Analysis

USGS Publications Warehouse

Gordon, John D.; Newland, Carla

2000-01-01

Introduction Sediment is derived primarily from natural weathering of rock and is an assemblage of individual mineral grains that are then deposited by some physical agent, such as water, wind, ice, or gravity (Fetter, 1988). The U.S. Geological Survey (USGS) samples sediments and collects data on the amount of sediment in selected waterways. The most pressing sediment-related problems are associated with environmental questions, such as the transport and fate of attached pollutants, effects of sediment on aquatic biota and their habitats, and effects on sediment transport from land-use changes. Current (2000) sediment issues require that sediment studies address multiple objectives in water-resources management (Koltun and others, 1997). To support sediment research, the USGS operates laboratories for the analysis of the physical characteristics of sediment. Sediment laboratories producing data for the USGS have two principal functions: (1) the determination of suspended-sediment concentration in samples and (2) the determination of sand/fine separations. The reliability of these determinations and the usefulness of the data are dependent on the accuracy and reliability of the laboratory analyses (Guy, 1969).

Passive sampling to measure baseline dissolved persistent organic pollutant concentrations in the water column of the Palos Verdes Shelf Superfund site.

PubMed

Fernandez, Loretta A; Lao, Wenjian; Maruya, Keith A; White, Carmen; Burgess, Robert M

2012-11-06

Passive sampling was used to deduce water concentrations of persistent organic pollutants (POPs) in the vicinity of a marine Superfund site on the Palos Verdes Shelf, California, USA. Precalibrated solid phase microextraction (SPME) fibers and polyethylene (PE) strips that were preloaded with performance reference compounds (PRCs) were codeployed for 32 d along an 11-station gradient at bottom, surface, and midwater depths. Retrieved samplers were analyzed for DDT congeners and their breakdown products (DDE, DDD, DDMU, and DDNU) and 43 PCB congeners using GC-EI- and NCI-MS. PRCs were used to calculate compound-specific fractional equilibration achieved in situ for the PE samplers, using both an exponential approach to equilibrium (EAE) and numerical integration of Fickian diffusion (NI) models. The highest observed concentrations were for p,p'-DDE, with 2200 and 990 pg/L deduced from PE and SPME, respectively. The difference in these estimates could be largely attributed to uncertainty in equilibrium partition coefficients, unaccounted for disequilibrium between samplers and water, or different time scales over which the samplers average. The concordance between PE and SPME estimated concentrations for DDE was high (R(2) = 0.95). PCBs were only detected in PE samplers, due to their much larger size. Near-bottom waters adjacent to and down current from sediments with the highest bulk concentrations exhibited aqueous concentrations of DDTs and PCBs that exceeded Ambient Water Quality Criteria (AWQC) for human and aquatic health, indicating the need for future monitoring to determine the effectiveness of remedial activities taken to reduce adverse effects of contaminated surface sediments.

Seasonal Changes in the Isotopic Compositions and Sinking Fluxes of Euthecosomatous Pteropod Shells in the Sargasso Sea

NASA Astrophysics Data System (ADS)

Fabry, V. J.; Deuser, W. G.

1992-04-01

Seasonal variations in the oxygen and carbon isotopic compositions and fluxes of five euthecosomatous pteropods were determined from a 14-month series of sediment trap deployments in the Sargasso Sea. Medium and large shell sizes of Styliola subula, Clio pyramidata, Limacina inflata, Creseis acicula, and Cuvierina columnella were collected throughout the sampling period. Comparisons of the δ18O of shell samples with the vertical and temporal variations in the calculated δ18O of aragonite in equilibrium with seawater suggest that these pteropods deposited the bulk of their shell mass at the following depths: S. subula and L. inflata at 50 m, C. pyramidata at 75 m, C. acicula in the upper 25 m, and C. columnella at 50-75 m. Although several of these species undergo diel vertical migration of several hundred meters in this region, the estimated depths of calcification match the upper parts of the species' vertical ranges, where the mean populations occur only at night. In all species, seasonal changes in the δ18O of shells were closely coupled to those of equilibrium δ18O for aragonite, suggesting that most of the shell mass of these individuals was formed within several months. Flux-weighted, mean δ18O values for the species reveal that seasonal variations in the sinking fluxes of shells would not affect the isotopic compositions of shell accumulations in Bermuda Rise sediments. Carbon and oxygen isotopes were positively correlated in all species except C. columnella, which suggests that temperature may influence the δ13C of the shells of these species.

Heterogeneous carbonaceous matter in sedimentary rock lithocomponents causes significant trichloroethylene (TCE) sorption in a low organic carbon content aquifer/aquitard system

NASA Astrophysics Data System (ADS)

Choung, Sungwook; Zimmerman, Lisa R.; Allen-King, Richelle M.; Ligouis, Bertrand; Feenstra, Stanley

2014-10-01

This study evaluated the effects of heterogeneous thermally altered carbonaceous matter (CM) on trichloroethylene (TCE) sorption for a low fraction organic carbon content (foc) alluvial sedimentary aquifer and aquitard system (foc = 0.046-0.105%). The equilibrium TCE sorption isotherms were highly nonlinear with Freundlich exponents of 0.46-0.58. Kerogen + black carbon was the dominant CM fraction extracted from the sediments and accounted for > 60% and 99% of the total in the sands and silt, respectively. Organic petrological examination determined that the kerogen included abundant amorphous organic matter (bituminite), likely of marine origin. The dark calcareous siltstone exhibited the greatest TCE sorption among aquifer lithocomponents and accounted for most sorption in the aquifer. The results suggest that the source of the thermally altered CM, which causes nonlinear sorption, was derived from parent Paleozoic marine carbonate rocks that outcrop throughout much of New York State. A synthetic aquifer-aquitard unit system (10% aquitard) was used to illustrate the effect of the observed nonlinear sorption on mass storage potential at equilibrium. The calculation showed that > 80% of TCE mass contained in the aquifer was sorbed on the aquifer sediment at aqueous concentration < 1000 μg L- 1. These results show that sorption is likely a significant contributor to the persistence of a TCE groundwater plume in the aquifer studied. It is implied that sorption may similarly contribute to TCE persistence in other glacial alluvial aquifers with similar geologic characteristics, i.e., comprised of sedimentary rock lithocomponents that contain thermally altered CM.

Experimental observations of granular debris flows

NASA Astrophysics Data System (ADS)

Ghilardi, P.

2003-04-01

Various tests are run using two different laboratory flumes with rectangular cross section and transparent walls. The grains used in a single experiment have an almost constant grain sizes; mean diameter ranges from 5 mm to 20 mm. In each test various measurements are taken: hydrograms, velocity distribution near the transparent walls and on the free surface, average flow concentration. Concentration values are measured taking samples. Velocity distributions are obtained from movies recorded by high speed video cameras capable of 350 frames per second; flow rates and depth hydrograms are computed from the same velocity distributions. A gate is installed at the beginning of one of the flumes; this gate slides normally to the bed and opens very quickly, reproducing a dam-break. Several tests are run using this device, varying channel slope, sediment concentration, initial mixture thickness before the gate. Velocity distribution in the flume is almost constant from left to right, except for the flow sections near the front. The observed discharges and velocities are less than those given by a classic dam break formula, and depend on sediment concentration. The other flume is fed by a mixture with constant discharge and concentration, and is mainly used for measuring velocity distributions when the flow is uniform, with both rigid and granular bed, and to study erosion/deposition processes near debris flow dams or other mitigation devices. The equilibrium slope of the granular bed is very close to that given by the classical equilibrium formulas for debris flow. Different deposition processes are observed depending on mixture concentration and channel geometry.

MODELING FRAMEWORK FOR EVALUATING SEDIMENTATION IN STREAM NETWORKS: FOR USE IN SEDIMENT TMDL ANALYSIS

EPA Science Inventory

A modeling framework that can be used to evaluate sedimentation in stream networks is described. This methodology can be used to determine sediment Total Maximum Daily Loads (TMDLs) in sediment impaired waters, and provide the necessary hydrodynamic and sediment-related data t...

Shifts in microbial community composition following surface application of dredged river sediments.

PubMed

Baniulyte, Dovile; Favila, Emmanuel; Kelly, John J

2009-01-01

Sediment input to the Illinois River has drastically decreased river depth and reduced habitats for aquatic organisms. Dredging is being used to remove sediment from the Illinois River, and the dredged sediment is being applied to the surface of a brownfield site in Chicago with the goal of revegetating the site. In order to determine the effects of this drastic habitat change on sediment microbial communities, we examined sediment physical, chemical, and microbial characteristics at the time of sediment application to the soil surface as well as 1 and 2 years after application. Microbial community biomass was determined by measurement of lipid phosphate. Microbial community composition was assessed using phospholipid fatty acid (PLFA) analysis, terminal restriction fragment length polymorphism (T-RFLP) analysis of 16S rRNA genes, and clone library sequencing of 16S rRNA genes. Results indicated that the moisture content, organic carbon, and total nitrogen content of the sediment all decreased over time. Total microbial biomass did not change over the course of the study, but there were significant changes in the composition of the microbial communities. PLFA analysis revealed relative increases in fungi, actinomycetes, and Gram positive bacteria. T-RFLP analysis indicated a significant shift in bacterial community composition within 1 year of application, and clone library analysis revealed relative increases in Proteobacteria, Gemmatimonadetes, and Bacteriodetes and relative decreases in Acidobacteria, Spirochaetes, and Planctomycetes. These results provide insight into microbial community shifts following land application of dredged sediment.

Tracking channel-floodplain sediment exchange with conservative and non-conservative geochemical tracers

NASA Astrophysics Data System (ADS)

Belmont, Patrick; Stout, Justin

2013-04-01

Fine sediment is routed through landscapes and channel networks in a highly unsteady and non-uniform manner, potentially experiencing deposition and re-suspension many times during transport from source to sink. Developing a better understanding of sediment routing at the landscape scale is an intriguing challenge from a modeling perspective because it requires consideration of a multitude of processes that interact and vary in space and time. From an applied perspective, an improved understanding of sediment routing is essential for predicting how conservation and restoration practices within a watershed will influence water quality, to support land and water management decisions. Two key uncertainties in predicting sediment routing at the landscape scale are 1) determining the proportion of suspended sediment that is derived from terrestrial (soil) erosion versus channel (bank) erosion, and 2) constraining the proportion of sediment that is temporarily stored and re-suspended within the channel-floodplain complex. Sediment fingerprinting that utilizes a suite of conservative and non-conservative geochemical tracers associated with suspended sediment can provide insight regarding both of these key uncertainties. Here we present a model that tracks suspended sediment with associated conservative and non-conservative geochemical tracers. The model assumes that particle residence times are described by a bimodal distribution wherein some fraction of sediment is transported through the system in a relatively short time (< 1 year) and the remainder experiences temporary storage (of variable duration) within the channel-floodplain complex. We use the model to explore the downstream evolution of non-conservative tracers under equilibrium conditions (i.e., exchange between the channel and floodplain is allowed, but no net change in channel-floodplain storage can occur) to illustrate how the process of channel-floodplain storage and re-suspension can potentially bias interpretation of sediment fingerprinting results. We then apply the model to explain measurements of meteoric Beryllium-10, Lead-210, and Cesium-137 associated with suspended sediment in two very different rivers, one incising (Le Sueur River, south-central Minnesota, USA) and the other aggrading (Root River, southeastern Minnesota, USA) in response to base level fall and rise, respectively. The Le Sueur River exhibits a remarkably narrow range of tracer concentrations in source areas, which include agricultural fields, alluvial banks, and bluffs. Suspended sediment samples collected immediately above and below the 30 km long incising reach show a systematic shift in terrestrial sources in the downstream direction, indicated by changes in Beryllium-10 concentrations. The Root River indicates a more variable erosion history, with significant variability of Beryllium-10 concentrations in source areas (agricultural fields, forested hillslopes, and alluvial floodplains and terraces) and inverted Beryllium-10 depth profiles (higher concentrations at depth, suggesting unsteady erosion and significant storage of legacy sediment). Both rivers show a systematic disparity in normalized concentrations of conservative versus non-conservative tracers, indicating that significant storage and re-suspension occurs in both systems as the sediment is routed through the channel-floodplain complex.

Partitioning of hydrophobic organic contaminants between polymer and lipids for two silicones and low density polyethylene.

PubMed

Smedes, Foppe; Rusina, Tatsiana P; Beeltje, Henry; Mayer, Philipp

2017-11-01

Polymers are increasingly used for passive sampling of neutral hydrophobic organic substances (HOC) in environmental media including water, air, soil, sediment and even biological tissue. The equilibrium concentration of HOC in the polymer can be measured and then converted into equilibrium concentrations in other (defined) media, which however requires appropriate polymer to media partition coefficients. We determined thus polymer-lipid partition coefficients (K PL ) of various PCB, PAH and organochlorine pesticides by equilibration of two silicones and low density polyethylene (LDPE) with fish oil and Triolein at 4 °C and 20 °C. We observed (i) that K PL was largely independent of lipid type and temperature, (ii) that lipid diffusion rates in the polymers were higher compared to predictions based on their molecular volume, (iii) that silicones showed higher lipid diffusion and lower lipid sorption compared to LDPE and (iv) that absorbed lipid behaved like a co-solute and did not affect the partitioning of HOC at least for the smaller molecular size HOC. The obtained K PL can convert measured equilibrium concentrations in passive sampling polymers into equilibrium concentrations in lipid, which then can be used (1) for environmental quality monitoring and assessment, (2) for thermodynamic exposure assessment and (3) for assessing the linkage between passive sampling and the traditionally measured lipid-normalized concentrations in biota. LDPE-lipid partition coefficients may also be of use for a thermodynamically sound risk assessment of HOC contained in microplastics. Copyright © 2017 Elsevier Ltd. All rights reserved.

Equilibrium shoreline response of a high wave energy beach

USGS Publications Warehouse

Yates, M.L.; Guza, R.T.; O'Reilly, W. C.; Hansen, J.E.; Barnard, P.L.

2011-01-01

Four years of beach elevation surveys at Ocean Beach, San Francisco, California, are used to extend an existing equilibrium shoreline change model, previously calibrated with fine sand and moderate energy waves, to medium sand and higher-energy waves. The shoreline, characterized as the cross-shore location of the mean high water contour, varied seasonally by between 30 and 60 m, depending on the alongshore location. The equilibrium shoreline change model relates the rate of horizontal shoreline displacement to the hourly wave energy E and the wave energy disequilibrium, the difference between E and the equilibrium wave energy that would cause no change in the present shoreline location. Values for the model shoreline response coefficients are tuned to fit the observations in 500 m alongshore segments and averaged over segments where the model has good skill and the estimated effects of neglected alongshore sediment transport are relatively small. Using these representative response coefficients for 0.3 mm sand from Ocean Beach and driving the model with much lower-energy winter waves observed at San Onofre Beach (also 0.3 mm sand) in southern California, qualitatively reproduces the small seasonal shoreline fluctuations at San Onofre. This consistency suggests that the shoreline model response coefficients depend on grain size and may be constant, and thus transportable, between sites with similar grain size and different wave climates. The calibrated model response coefficients predict that for equal fluctuations in wave energy, changes in shoreline location on a medium-grained (0.3 mm) beach are much smaller than on a previously studied fine-grained (0.2 mm) beach. Copyright ?? 2011 by the American Geophysical Union.

[Speciation and Risk Characteristics of Heavy Metals in the Sediments of the Yangtze Estuary].

PubMed

Yin, Su; Feng, Cheng-hong; Li, Yang-yang; Yin, Li-feng; Shen, Zhen-yao

2016-03-15

Based on the investigation on the distribution of total contents and speciation of 8 heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, Zn) in the surface sediments at 14 typical sites of the Yangtze Estuary during three hydrological seasons ( wet, normal, and dry seasons) , this study applied equilibrium partitioning approach to build the sediment quality guidelines (SQGs) of the Yangtze Estuary, and assessed ecological risks of the heavy metals. The relationship between ecological risk and speciation of heavy metals was also revealed. The results showed that, except for Cd, the residual fraction was the main speciation of heavy metals, especially for As, Cr and Hg, their residual fraction proportions were all over 90%. The sediment quality guidelines of the Yangtze Estuary for As, Cd, Cr, Cu, Hg, Ni, Pb, Zn were 43.29, 0.672, 79.65, 19.08, 0.569, 339.09, 30.87, 411.36 µg · g⁻¹, respectively. Cu had the highest ecological risk to aquatic organisms. The upstream of Yangtze Estuary was mainly affected by Yangtze River runoff, where the risks were relatively high in wet season and relatively low in normal and dry seasons. However, the downstream of the estuary was mainly affected by municipal sewage of cities like Shanghai, where the risks were relatively high, especially in normal and dry seasons. There were three different relationships between the ecological risks and speciation of the eight heavy metals.

Three-stage stochastic pump: Another type of Onsager-Casimir symmetry and results far from equilibrium

NASA Astrophysics Data System (ADS)

Rosas, Alexandre; Van den Broeck, Christian; Lindenberg, Katja

2018-06-01

The stochastic thermodynamic analysis of a time-periodic single particle pump sequentially exposed to three thermochemical reservoirs is presented. The analysis provides explicit results for flux, thermodynamic force, entropy production, work, and heat. These results apply near equilibrium as well as far from equilibrium. In the linear response regime, a different type of Onsager-Casimir symmetry is uncovered. The Onsager matrix becomes symmetric in the limit of zero dissipation.

Bifurcation analysis in SIR epidemic model with treatment

NASA Astrophysics Data System (ADS)

Balamuralitharan, S.; Radha, M.

2018-04-01

We investigated the bifurcation analysis of nonlinear system of SIR epidemic model with treatment. It is accepted that the treatment is corresponding to the quantity of infective which is below the limit and steady when the quantity of infective achieves the limit. We analyze about the Transcritical bifurcation which occurs at the disease free equilibrium point and Hopf bifurcation which occurs at endemic equilibrium point. Using MATLAB we show the picture of bifurcation at the disease free equilibrium point.

Sensitivity analysis of a sediment dynamics model applied in a Mediterranean river basin: global change and management implications.

PubMed

Sánchez-Canales, M; López-Benito, A; Acuña, V; Ziv, G; Hamel, P; Chaplin-Kramer, R; Elorza, F J

2015-01-01

Climate change and land-use change are major factors influencing sediment dynamics. Models can be used to better understand sediment production and retention by the landscape, although their interpretation is limited by large uncertainties, including model parameter uncertainties. The uncertainties related to parameter selection may be significant and need to be quantified to improve model interpretation for watershed management. In this study, we performed a sensitivity analysis of the InVEST (Integrated Valuation of Environmental Services and Tradeoffs) sediment retention model in order to determine which model parameters had the greatest influence on model outputs, and therefore require special attention during calibration. The estimation of the sediment loads in this model is based on the Universal Soil Loss Equation (USLE). The sensitivity analysis was performed in the Llobregat basin (NE Iberian Peninsula) for exported and retained sediment, which support two different ecosystem service benefits (avoided reservoir sedimentation and improved water quality). Our analysis identified the model parameters related to the natural environment as the most influential for sediment export and retention. Accordingly, small changes in variables such as the magnitude and frequency of extreme rainfall events could cause major changes in sediment dynamics, demonstrating the sensitivity of these dynamics to climate change in Mediterranean basins. Parameters directly related to human activities and decisions (such as cover management factor, C) were also influential, especially for sediment exported. The importance of these human-related parameters in the sediment export process suggests that mitigation measures have the potential to at least partially ameliorate climate-change driven changes in sediment exportation. Copyright © 2014 Elsevier B.V. All rights reserved.

Approaches for derivation of environmental quality criteria for substances applied in risk assessment of discharges from offshore drilling operations.

PubMed

Altin, Dag; Frost, Tone Karin; Nilssen, Ingunn

2008-04-01

In order to achieve the offshore petroleum industries "zero harm" goal to the environment, the environmental impact factor for drilling discharges was developed as a tool to identify and quantify the environmental risks associated with disposal of drilling discharges to the marine environment. As an initial step in this work the main categories of substances associated with drilling discharges and assumed to contribute to toxic or nontoxic stress were identified and evaluated for inclusion in the risk assessment. The selection were based on the known toxicological properties of the substances, or the total amount discharged together with their potential for accumulation in the water column or sediments to levels that could be expected to cause toxic or nontoxic stress to the biota. Based on these criteria 3 categories of chemicals were identified for risk assessment the water column and sediments: Natural organic substances, metals, and drilling fluid chemicals. Several approaches for deriving the environmentally safe threshold concentrations as predicted no effect concentrations were evaluated in the process. For the water column consensus were reached for using the species sensitivity distribution approach for metals and the assessment factor approach for natural organic substances and added drilling chemicals. For the sediments the equilibrium partitioning approach was selected for all three categories of chemicals. The theoretically derived sediment quality criteria were compared to field-derived threshold effect values based on statistical approaches applied on sediment monitoring data from the Norwegian Continental Shelf. The basis for derivation of predicted no effect concentration values for drilling discharges should be consistent with the principles of environmental risk assessment as described in the Technical Guidance Document on Risk Assessment issued by the European Union.

Diatoms as Proxies for a Fluctuating Ice Cap Margin, Hvitarvatn, Iceland

NASA Astrophysics Data System (ADS)

Black, J. L.; Miller, G. H.; Geirsdottir, A.

2005-12-01

There are no complete records of terrestrial environmental change for the Holocene (11,000yrs) in Iceland and the status of Icelandic glaciers in the early Holocene remains unclear. It is not even known whether Iceland's large ice caps disappeared in the early Holocene, and if they did, when they re-grew. Icelandic lakes are particularly well suited to address these uncertainties as: 1) Glacial erosion and soft bedrock result in high lacustrine sedimentation rates, 2) Diagnostic tephras aid the geochronology, 3) Iceland's sensitivity to changes in North Atlantic circulation should produce clear signals in key environmental proxies (diatoms) preserved in lacustrine sequences, and 4) Ice-cap profiles are relatively flat so small changes in the equilibrium line altitude result in large changes in accumulation area. Hence, large changes in ice-sheet margins during the Holocene will impact sedimentation in glacier-dominated lakes and the diatom assemblages at those times. Hvitarvatn is a glacier dominated lake located on the eastern margin of Langjokull Ice Cap in central-western Iceland. The uppermost Hvitarvatn sediments reflect a glacially dominated system with planktonic, silica-demanding diatom taxa that suggest a high dissolved silica and turbid water environment consistent with high fluxes of glacial flour. Below this are Neoglacial sediments deposited when Langjokull was active, but outlet glaciers were not in contact with Hvitarvatn. The diatom assemblage here shows a small increase in abundance, but is still dominated by planktic, silica-demanding taxa. A distinct shift in lake conditions is reflected in the lowermost sediments, composed of predominantly benthic diatoms and deposited in clear water conditions with long growing seasons likely found in an environment with warmer summers than present and with no glacial erosion. Langjokull must have disappeared in the early Holocene for such a diverse, benthic dominated diatom assemblage to flourish.

Residual flow patterns and morphological changes along a macro- and meso-tidal coastline

NASA Astrophysics Data System (ADS)

Leonardi, Nicoletta; Plater, Andrew James

2017-11-01

The hydrodynamic and residual transport patterns arising from oscillating tidal motion have important consequences for the transport of sediments, and for the evolution of the shoreline, especially under macro- and meso-tidal conditions. For many locations there are significant uncertainties about residual currents and sediment transport characteristics, and their possible influence on the morphological evolution of the coastline and on the character of the bed. Herein we use the coastline of SE England as a test case to investigate possible changes in residual currents, and residual transport patterns from neap to spring tide, the reciprocal interaction between residuals and the character of the bed, and the morphological evolution of the coastline at a century timescale. We found that in the long term the morphology of the system evolves toward a dynamic equilibrium configuration characterized by smaller, and spatially constant residual transport patterns. While the spatial distribution of residual currents maintains a similar trend during both neap and spring tide, during spring tide and for large areas residual currents switch between northerly and southerly directions, and their magnitude is doubled. Residual eddies develop in regions characterized by the presence of sand bars due to the interaction of the tide with the varying topography. Residual transport patterns are also computed for various sediment fractions, and based on the hydrodynamics and sediment availability at the bottom. We found that the distribution of sediments on the bed is significantly correlated with the intensity of residuals. Finally, the majority of long-term morphological changes tend to develop or augment sand banks features, with an increase in elevation and steepening of the bank contours.