Measurement of Fluorescence in a Rhodamine-123 Doped Self-Assembled “Giant” Mesostructured Silica Sphere Using a Smartphone as Optical Hardware

PubMed Central

Canning, John; Lau, Angelica; Naqshbandi, Masood; Petermann, Ingemar; Crossley, Maxwell J.

2011-01-01

The blue OLED emission from a mobile phone was characterised, revealing a sharp emission band centred at λ = 445 nm with a 3dB bandwidth Δλ ∼ 20 nm. It was used to excite Rhodamine 123 doped within a “giant” mesostructured silica sphere during fabrication through evaporative self-assembly of silica nanoparticles. Fluorescence was able to be detected using a standard optical microscope fitted with a green transmission pass filter and cooled CCD and with 1 ms exposure time demonstrating the potential of mobile platforms as the basis for portable diagnostics in the field. PMID:22164002

Synthesis and spectroscopic study of CdS nanoparticles using hydrothermal method

NASA Astrophysics Data System (ADS)

AL-Mamoori, Mohammed H. K.; Mahdi, Dunia K.; Al-Shrefi, Saif M.

2018-05-01

In this work, cadmium sulfide nanoparticles (powder) with diameter 50.8 nm was prepared using hydrothermal method. The structural and optical properties of CdS nanoparticles was studied by X-ray diffraction, FESEM, EDS, FTIR, UV-Diffuse Reflectance spectroscopy and Photoluminance spectrum. X-ray diffraction reveal the formation the purity of prepared phase of CdS particles with hexagonal wurtzite structure with particle size 31.8nm by using sheerer equation. The energy dispersion scattering (EDS) examination explains that the sample is composed of a large amount of Cd and S which are exactly CdS nanoparticles and there is a very small trace of (Zn) and (O) element observed because of there is a small pollutions in the measurement place of samples. FESEM shows the spherical shape of nanoparticles with around 50.8 nm diameter. The optical absorption spectral study identified the red shift of the sample in comparison to bulk ZnO in three dimensions. Photoluminance spectrum (PL) at room temperature showed that there are two luminescence peaks at 433.14 nm and 518.21nm. Samples demonstrate a sharp emission band at around 433.18 nm, which is attributed to the typical exciton luminescence. The broad band at 518.21nm which were attributed to the trapped luminescence. The green emission band at 518.21 nm was associated with the emission due to electronic transition from the conduction band to an accepter level due to interstitial sulphur ion.

High-angular-resolution NIR astronomy with large arrays (SHARP I and SHARP II)

NASA Astrophysics Data System (ADS)

Hofmann, Reiner; Brandl, Bernhard; Eckart, Andreas; Eisenhauer, Frank; Tacconi-Garman, Lowell E.

1995-06-01

SHARP I and SHARP II are near infrared cameras for high-angular-resolution imaging. Both cameras are built around a 256 X 256 pixel NICMOS 3 HgCdTe array from Rockwell which is sensitive in the 1 - 2.5 micrometers range. With a 0.05'/pixel scale, they can produce diffraction limited K-band images at 4-m-class telescopes. For a 256 X 256 array, this pixel scale results in a field of view of 12.8' X 12.8' which is well suited for the observation of galactic and extragalactic near-infrared sources. Photometric and low resolution spectroscopic capabilities are added by photometric band filters (J, H, K), narrow band filters ((lambda) /(Delta) (lambda) approximately equals 100) for selected spectral lines, and a CVF ((lambda) /(Delta) (lambda) approximately equals 70). A cold shutter permits short exposure times down to about 10 ms. The data acquisition electronics permanently accepts the maximum frame rate of 8 Hz which is defined by the detector time constants (data rate 1 Mbyte/s). SHARP I has been especially designed for speckle observations at ESO's 3.5 m New Technology Telescope and is in operation since 1991. SHARP II is used at ESO's 3.6 m telescope together with the adaptive optics system COME-ON + since 1993. A new version of SHARP II is presently under test, which incorporates exchangeable camera optics for observations with scales of 0.035, 0.05, and 0.1'/pixel. The first scale extends diffraction limited observations down to the J-band, while the last one provides a larger field of view. To demonstrate the power of the cameras, images of the galactic center obtained with SHARP I, and images of the R136 region in 30 Doradus observed with SHARP II are presented.

The influence of reaction times on structural, optical and luminescence properties of cadmium telluride nanoparticles prepared by wet-chemical process

NASA Astrophysics Data System (ADS)

Kiprotich, Sharon; Dejene, Francis B.; Ungula, Jatani; Onani, Martin O.

2016-01-01

This paper explains one pot synthesis of type II water soluble L-cysteine capped cadmium telluride (CdTe) core shell quantum dots using cadmium acetate, potassium tellurite and L-cysteine as the starting materials. The reaction was carried out in a single three necked flask without nitrogen under reflux at 100 °C. Results from PL show a sharp absorption excitonic band edge of the CdTe core with respect to the core shell which loses its shoulder during the growth of the shell on the core. The PL spectra indicate a drastic shift in emission window of the core which is simultaneously accompanied by an increase in emission intensity. X-ray diffraction pattern confirms the formation of hexagonal phase for all samples. Some difference in absorption edges were observed due to varying synthesis time of CdTe NPs. The position of the absorption band is observed to shift towards the lower wavelength side for shorter durations of synthesis.

Investigation and characterization of ZnO single crystal microtubes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al-Naser, Qusay A.H.; Zhou, Jian, E-mail: jianzhou@whut.edu.cn; Liu, Guizhen

2016-04-15

Morphological, structural, and optical characterization of microwave synthesized ZnO single crystal microtubes were investigated in this work. The structure and morphology of the ZnO microtubes are characterized using X-ray diffraction (XRD), single crystal diffraction (SCD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM). The results reveal that the as-synthesized ZnO microtube has a highly regular hexagonal cross section and smooth surfaces with an average length of 650–700 μm, an average outer diameter of 50 μm and wall thickness of 1–3 μm, possessing a single crystal wurtzite hexagonal structure. Optical properties of ZnOmore » single crystal microtubes were investigated by photoluminescence (PL) and ultraviolet-visible (UV-vis) absorption techniques. Room-temperature PL spectrum of the microtube reveal a strong UV emission peak at around 375.89 nm and broad and a weak visible emission with a main peak identified at 577 nm, which was assigned to the nearest band-edge emission and the deep-level emission, respectively. The band gap energy of ZnO microtube was found to be 3.27 eV. - Highlights: • ZnO microtube length of 650–700 μm, diameter of 50 μm, wall thickness of 1–3 μm • ZnO microtube possesses a single crystal wurtzite hexagonal structure. • The crystal system is hexahedral oriented along a-axis with indices of (100). • A strong and sharp UV emission at 375.89 nm (3.29 eV) • One prominent absorption band around 378.88 nm (3.27 eV)« less

Photoexcitation Cascade and Quantum-Relativistic Jets in Graphene

NASA Astrophysics Data System (ADS)

Lewandowski, Cyprian; Levitov, L. S.

2018-02-01

In Dirac materials linear band dispersion blocks momentum-conserving interband transitions, creating a bottleneck for electron-hole pair production and carrier multiplication in the photoexcitation cascade. Here we show that the decays are unblocked and the bottleneck is relieved by subtle many-body effects involving multiple off-shell e -h pairs. The decays result from a collective behavior due to simultaneous emission of many soft pairs. We discuss characteristic signatures of the off-shell pathways, in particular the sharp angular distribution of secondary carriers, resembling relativistic jets in high-energy physics. The jets can be directly probed using solid-state equivalent of particle detectors. Collinear scattering enhances carrier multiplication, allowing for emission of as many as ˜10 secondary carriers per single absorbed photon.

Optical study of the band structure of wurtzite GaP nanowires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Assali, S., E-mail: simone.assali@polymtl.ca; Greil, J.; Zardo, I.

2016-07-28

We investigated the optical properties of wurtzite (WZ) GaP nanowires by performing photoluminescence (PL) and time-resolved PL measurements in the temperature range from 4 K to 300 K, together with atom probe tomography to identify residual impurities in the nanowires. At low temperature, the WZ GaP luminescence shows donor-acceptor pair emission at 2.115 eV and 2.088 eV, and Burstein-Moss band-filling continuum between 2.180 and 2.253 eV, resulting in a direct band gap above 2.170 eV. Sharp exciton α-β-γ lines are observed at 2.140–2.164–2.252 eV, respectively, showing clear differences in lifetime, presence of phonon replicas, and temperature-dependence. The excitonic nature of those peaks is critically discussed, leading tomore » a direct band gap of ∼2.190 eV and to a resonant state associated with the γ-line ∼80 meV above the Γ{sub 8C} conduction band edge.« less

Optimized mid-infrared thermal emitters for applications in aircraft countermeasures

NASA Astrophysics Data System (ADS)

Lorenzo, Simón G.; You, Chenglong; Granier, Christopher H.; Veronis, Georgios; Dowling, Jonathan P.

2017-12-01

We introduce an optimized aperiodic multilayer structure capable of broad angle and high temperature thermal emission over the 3 μm to 5 μm atmospheric transmission band. This aperiodic multilayer structure composed of alternating layers of silicon carbide and graphite on top of a tungsten substrate exhibits near maximal emittance in a 2 μm wavelength range centered in the mid-wavelength infrared band traditionally utilized for atmospheric transmission. We optimize the layer thicknesses using a hybrid optimization algorithm coupled to a transfer matrix code to maximize the power emitted in this mid-infrared range normal to the structure's surface. We investigate possible applications for these structures in mimicking 800-1000 K aircraft engine thermal emission signatures and in improving countermeasure effectiveness against hyperspectral imagers. We find these structures capable of matching the Planck blackbody curve in the selected infrared range with relatively sharp cutoffs on either side, leading to increased overall efficiency of the structures. Appropriately optimized multilayer structures with this design could lead to matching a variety of mid-infrared thermal emissions. For aircraft countermeasure applications, this method could yield a flare design capable of mimicking engine spectra and breaking the lock of hyperspectral imaging systems.

Tunable Narrow Band Emissions from Dye-Sensitized Core/Shell/Shell Nanocrystals in the Second Near-Infrared Biological Window

PubMed Central

Shao, Wei; Chen, Guanying; Kuzmin, Andrey; Kutscher, Hilliard L.; Pliss, Artem; Ohulchanskyy, Tymish Y.; Prasad, Paras N.

2017-01-01

We introduce a hybrid organic–inorganic system consisting of epitaxial NaYF4:Yb3+/X3+@NaYbF4@NaYF4:Nd3+ (X = null, Er, Ho, Tm, or Pr) core/shell/shell (CSS) nanocrystal with organic dye, indocyanine green (ICG) on the nanocrystal surface. This system is able to produce a set of narrow band emissions with a large Stokes-shift (>200 nm) in the second biological window of optical transparency (NIR-II, 1000–1700 nm), by directional energy transfer from light-harvesting surface ICG, via lanthanide ions in the shells, to the emitter X3+ in the core. Surface ICG not only increases the NIR-II emission intensity of inorganic CSS nanocrystals by ~4-fold but also provides a broadly excitable spectral range (700–860 nm) that facilitates their use in bioapplications. We show that the NIR-II emission from ICG-sensitized Er3+-doped CSS nanocrystals allows clear observation of a sharp image through 9 mm thick chicken breast tissue, and emission signal detection through 22 mm thick tissue yielding a better imaging profile than from typically used Yb/Tm-codoped upconverting nanocrystals imaged in the NIR-I region (700–950 nm). Our result on in vivo imaging suggests that these ICG-sensitized CSS nanocrystals are suitable for deep optical imaging in the NIR-II region. PMID:27935695

Excited state intramolecular charge transfer reaction in binary mixtures of water and tertiary butanol (TBA): alcohol mole fraction dependence.

PubMed

Pradhan, Tuhin; Ghoshal, Piue; Biswas, Ranjit

2008-02-07

The excited state intramolecular charge transfer reaction of 4-(1-azetidinyl)benzonitrile (P4C) has been studied in water-tertiary butanol (TBA) mixtures at different alcohol mole fractions by using steady state and time-resolved fluorescence spectroscopy. The ratio between the areas under the locally excited (LE) and charge transferred (CT) emission bands is found to exhibit a sharp rise at alcohol mole fraction approximately 0.04, a value at which several thermodynamic properties of this mixture is known to show anomalous change due to the enhancement of H-bonding network. The radiative rate associated with the LE emission also shows a maximum at this TBA mole fraction. Although the structural transition from the water-like tetrahedral network to the alcohol-like chain is reflected in the red shift of the absorption spectrum up to TBA mole fraction approximately 0.10, the emission bands (both LE and CT) show the typical nonideal alcohol mole fraction dependence at all TBA mole fractions. Quantum yield, CT radiative rate as well as transition moments also exhibit a nonideal alcohol mole fraction dependence. The time-resolved emission decay of P4C has been found to be biexponential at all TBA mole fractions, regardless of emission collection around either the LE or the CT bands. The time constant associated with the slow component (tau(slow)) shows a minimum at TBA mole fraction approximately 0.04, whereas such a minimum for the fast time constant, tau(fast) (representing the rate of LE --> CT conversion reaction) is not observed. The nonobservation of the minimum in tau(fast) might be due to the limited time resolution employed in our experiments.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gibbs, Zachary M.; Kim, Hyun-Sik; Materials Research Center, Samsung Advanced Institute of Technology, Samsung Electronics, Suwon 443-803

In characterizing thermoelectric materials, electrical and thermal transport measurements are often used to estimate electronic band structure properties such as the effective mass and band gap. The Goldsmid-Sharp band gap, E{sub g} = 2e|S|{sub max}T{sub max}, is a tool widely employed to estimate the band gap from temperature dependent Seebeck coefficient measurements. However, significant deviations of more than a factor of two are now known to occur. We find that this is when either the majority-to-minority weighted mobility ratio (A) becomes very different from 1.0 or as the band gap (E{sub g}) becomes significantly smaller than 10 k{sub B}T. For narrow gapsmore » (E{sub g} ≲ 6 k{sub B}T), the Maxwell-Boltzmann statistics applied by Goldsmid-Sharp break down and Fermi-Dirac statistics are required. We generate a chart that can be used to quickly estimate the expected correction to the Goldsmid-Sharp band gap depending on A and S{sub max}; however, additional errors can occur for S < 150 μV/K due to degenerate behavior.« less

Development of graphene oxide materials with controllably modified optical properties

NASA Astrophysics Data System (ADS)

Naumov, Anton; Galande, Charudatta; Mohite, Aditya; Ajayan, Pulickel; Weisman, R. Bruce

2015-03-01

One of the major current goals in graphene research is modifying its optical and electronic properties through controllable generation of band gaps. To achieve this, we have studied the changes in optical properties of reduced graphene oxide (RGO) in water suspension upon the exposure to ozone. Ozonation for the periods of 5 to 35 minutes has caused a dramatic bleaching of its absorption and the concurrent appearance of strong visible fluorescence in previously nonemissive samples. These observed spectral changes suggest a functionalization-induced band gap opening. The sample fluorescence induced by ozonation was found to be highly pH-dependent: sharp and structured emission features resembling the spectra of molecular fluorophores were present at basic pH values, but this emission reversibly broadened and red-shifted in acidic conditions. These findings are consistent with excited state protonation of the emitting species in acidic media. Oxygen-containing addends resulting from the ozonation were detected by XPS and FTIR spectroscopy and related to optical transitions in localized graphene oxide fluorophores by computational modeling. Further research will be directed toward producing graphene-based optoelectronic devices with tailored and controllable optical properties.

Photoluminescence of Porous Silicon-Zinc Oxide Hybrid structures

NASA Astrophysics Data System (ADS)

Olenych, I. B.; Monastyrskii, L. S.; Luchechko, A. P.

2017-03-01

Arrays of ZnO nanostructures, which are optically transparent in the visible range, were grown on the surface of porous silicon by electrochemical deposition. Photoluminescence excitation and emission spectra of the obtained hybrid structures were investigated in 220-450 and 400-800 nm regions, respectively. It is established that multicolor emission is formed by combining the luminescence bands of porous silicon and zinc oxide. The possibility of controlling the photoluminescence spectra by changing the excitation energy is demonstrated. It is revealed that thermal annealing has an effect on the luminescent properties of porous silicon/zinc oxide hybrid structures. Thermal processing at 500°C leads to a sharp decrease of long-wavelength luminescence associated with porous silicon and to an increase of short-wavelength luminescence intensity related to zinc oxide.

Observation of pulsed hard X-rays/gamma-rays from PSR 1509-58

NASA Astrophysics Data System (ADS)

Gunji, S.; Hirayama, M.; Kamae, T.; Miyazaki, S.; Sekimoto, Y.; Takahashi, T.; Tamura, T.; Tanaka, M.; Yamasaki, N.; Yamagami, T.; Nomachi, M.; Murakami, H.; Braga, J.; Neri, J. A.

1994-06-01

We observed a young rotation-powered pulsar, PSR 1509-58, in the hard X-ray/gamma-ray or the soft gamma-ray band with a balloon-borne detector in Brazil on 1991 November 19 (UT). With a timing analysis we detected pulsations in the energy band 94-240 keV at the 150.687 ms period determined from radio observations. The pulsating flux is (7.1 +/- 1.7) x 10-4 per sq cm per sec in this band, and the energy spectrum follows a power law with photon index alpha = 1.64 +/- 0.4. The averaged pulse profile shows a broad single peak with a sharp rise and has a duty cycle around 50% or higher: these features are similar to what have been observed in the X-ray band by the Ginga satellite. Based on the data available now, the fraction of energy transformed from rotational energy loss to pulsed/nonpulsed soft gamma-ray radiation is estimated. If the solid angle swept by the pulsed beam is about the same as for the Crab pulsar (PSR 0531+21) and the Vela pulsar (PSR 0833-45), PSR 1509-58 turn out to be an extremely efficient pulsar, converting a large fraction of its rotational energy loss to radiation, as the outer gap model predicts. The observed pulsed spectrum, however, is strong in the soft gamma-ray band, in a sharp contrast to what has been observed in the Vela pulsar, a pulsar expected to be similar PSR 1509-58 in the outer gap model. The fact that the pulse profile remains broad and single-peaked in the soft gamma-ray band is also new for Crab-like pulsars. In these regards, PSR 1509-58 may require some alteration to the standard outer gap model or even a new model for gamma-ray emission in pulsars.

Oxygen adsorption on a Si(1 0 0) substrate: effects on secondary emission properties

NASA Astrophysics Data System (ADS)

Vogan, W. S.; Champion, R. L.

2001-10-01

Secondary anion and electron yields resulting from low-energy (50-500 eV) Na + bombardment of an oxygen-adsorbed Si(1 0 0) substrate have been measured as a function of oxygen exposure and of Na + impact energy. Adsorbate coverage ranges from none to over half a monolayer. The dominant sputtered anion was found to be O - with SiO 2- being a minor constituent. Kinetic energy distributions of the secondary anions and electrons were also measured. The presence of an adsorbate was observed to enhance secondary anion emission to a significant degree whereas secondary electron emission was minor, in sharp contrast to what has been observed for metallic substrates. The mechanism for secondary emission appears to involve electronic excitation of Si xO -; it is suggested that electron emission is governed by a process similar to Penning ionization, in which a vacancy created by the excitation of Si xO - may be filled by an electron from the valence band. The variation in the work function as oxygen accumulated on the surface was observed to be small.

Near-infrared fluorescence amplified organic nanoparticles with aggregation-induced emission characteristics for in vivo imaging

NASA Astrophysics Data System (ADS)

Geng, Junlong; Zhu, Zhenshu; Qin, Wei; Ma, Lin; Hu, Yong; Gurzadyan, Gagik G.; Tang, Ben Zhong; Liu, Bin

2013-12-01

Near-infrared (NIR) fluorescence signals are highly desirable to achieve high resolution in biological imaging. To obtain NIR emission with high brightness, fluorescent nanoparticles (NPs) are synthesized by co-encapsulation of 2,3-bis(4-(phenyl(4-(1,2,2-triphenylvinyl)phenylamino)phenyl)fumaronitrile (TPETPAFN), a luminogen with aggregation-induced emission (AIE) characteristics, and a NIR fluorogen of silicon 2,3-naphthalocyanine bis(trihexylsilyloxide) (NIR775) using 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000] as the encapsulation matrix. The good spectral overlap between the emission of TPETPAFN and the absorption of NIR775 leads to efficient energy transfer, resulting in a 47-fold enhancement of the NIR775 emission intensity upon excitation of TPETPAFN at 510 nm as compared to that upon direct excitation of NIR775 at 760 nm. The obtained fluorescent NPs show sharp NIR emission with a band width of 20 nm, a large Stokes shift of 275 nm, good photostability and low cytotoxicity. In vivo imaging study reveals that the synthesized NPs are able to provide high fluorescence contrast in live animals. The Förster resonance energy transfer strategy overcomes the intrinsic limitation of broad emission spectra for AIE NPs, which opens new opportunities to synthesize organic NPs with high brightness and narrow emission for potential applications in multiplex sensing and imaging.Near-infrared (NIR) fluorescence signals are highly desirable to achieve high resolution in biological imaging. To obtain NIR emission with high brightness, fluorescent nanoparticles (NPs) are synthesized by co-encapsulation of 2,3-bis(4-(phenyl(4-(1,2,2-triphenylvinyl)phenylamino)phenyl)fumaronitrile (TPETPAFN), a luminogen with aggregation-induced emission (AIE) characteristics, and a NIR fluorogen of silicon 2,3-naphthalocyanine bis(trihexylsilyloxide) (NIR775) using 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000] as the encapsulation matrix. The good spectral overlap between the emission of TPETPAFN and the absorption of NIR775 leads to efficient energy transfer, resulting in a 47-fold enhancement of the NIR775 emission intensity upon excitation of TPETPAFN at 510 nm as compared to that upon direct excitation of NIR775 at 760 nm. The obtained fluorescent NPs show sharp NIR emission with a band width of 20 nm, a large Stokes shift of 275 nm, good photostability and low cytotoxicity. In vivo imaging study reveals that the synthesized NPs are able to provide high fluorescence contrast in live animals. The Förster resonance energy transfer strategy overcomes the intrinsic limitation of broad emission spectra for AIE NPs, which opens new opportunities to synthesize organic NPs with high brightness and narrow emission for potential applications in multiplex sensing and imaging. Electronic supplementary information (ESI) available: Characterization of AIE properties of TPETPAFN, UV-vis spectra of NPs, PL spectra comparison upon excitation at the donor and receptor absorbance maxima, ex vivo fluorescence imaging of mice organs. See DOI: 10.1039/c3nr04243j

The structure and emission model of the relativistic jet in the quasar 3C 279 inferred from radio to high-energy γ-ray observations in 2008-2010

DOE PAGES

Hayashida, M.; Madejski, G. M.; Nalewajko, K.; ...

2012-07-16

Here, we present time-resolved broadband observations of the quasar 3C 279 obtained from multi-wavelength campaigns conducted during the first two years of the Fermi Gamma-ray Space Telescope mission. And, while investigating the previously reported γ-ray/optical flare accompanied by a change in optical polarization, we found that the optical emission appears to be delayed with respect to the γ-ray emission by about 10 days. X-ray observations reveal a pair of "isolated" flares separated by ~90 days, with only weak γ-ray/optical counterparts. The spectral structure measured by Spitzer reveals a synchrotron component peaking in the mid-infrared band with a sharp break atmore » the far-infrared band during the γ-ray flare, while the peak appears in the millimeter (mm)/submillimeter (sub-mm) band in the low state. Selected spectral energy distributions are fitted with leptonic models including Comptonization of external radiation produced in a dusty torus or the broad-line region. Furthermore, by adopting the interpretation of the polarization swing involving propagation of the emitting region along a curved trajectory, we can explain the evolution of the broadband spectra during the γ-ray flaring event by a shift of its location from ~1 pc to ~4 pc from the central black hole. On the other hand, if the γ-ray flare is generated instead at sub-pc distance from the central black hole, the far-infrared break can be explained by synchrotron self-absorption. We also model the low spectral state, dominated by the mm/sub-mm peaking synchrotron component, and suggest that the corresponding inverse-Compton component explains the steady X-ray emission.« less

NEAR-INFRARED THERMAL EMISSION FROM TrES-3b: A Ks-BAND DETECTION AND AN H-BAND UPPER LIMIT ON THE DEPTH OF THE SECONDARY ECLIPSE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Croll, Bryce; Jayawardhana, Ray; Fortney, Jonathan J.

2010-08-01

We present H- and Ks-band photometry bracketing the secondary eclipse of the hot Jupiter TrES-3b using the Wide-field Infrared Camera on the Canada-France-Hawaii Telescope. We detect the secondary eclipse of TrES-3b with a depth of 0.133{sup +0.018}{sub -0.016}% in the Ks band (8{sigma})-a result that is in sharp contrast to the eclipse depth reported by de Mooij and Snellen. We do not detect its thermal emission in the H band, but place a 3{sigma} limit of 0.051% on the depth of the secondary eclipse in this band. A secondary eclipse of this depth in Ks requires very efficient day-to-nightside redistributionmore » of heat and nearly isotropic reradiation, a conclusion that is in agreement with longer wavelength, mid-infrared Spitzer observations. Our 3{sigma} upper limit on the depth of our H-band secondary eclipse also argues for very efficient redistribution of heat and suggests that the atmospheric layer probed by these observations may be well homogenized. However, our H-band upper limit is so constraining that it suggests the possibility of a temperature inversion at depth, or an absorbing molecule, such as methane, that further depresses the emitted flux at this wavelength. The combination of our near-infrared measurements and those obtained with Spitzer suggests that TrES-3b displays a near-isothermal dayside atmospheric temperature structure, whose spectrum is well approximated by a blackbody. We emphasize that our strict H-band limit is in stark disagreement with the best-fit atmospheric model that results from longer wavelength observations only, thus highlighting the importance of near-infrared observations at multiple wavelengths, in addition to those returned by Spitzer in the mid-infrared, to facilitate a comprehensive understanding of the energy budgets of transiting exoplanets.« less

Synthesis and Photoluminescence Properties of BaWO4:RE3+ (RE = Eu or Sm) Phosphors

NASA Astrophysics Data System (ADS)

Cho, Shinho

2018-04-01

BaWO4:RE3+ (RE = Eu or Sm) phosphor powders were prepared with different doping concentrations of the activator ion by using the conventional solid-state reaction method. The dependences in the crystal structure, luminescence intensity, and morphology on the Eu3+ and the Sm3+ concentrations in BaWO4 were investigated using X-ray diffraction (XRD), photoluminescence spectrophotometry, and scanning electron microscopy (SEM), respectively. XRD analysis showed tetragonal BaWO4 structures for all the phosphors synthesized, regardless of the type and the doping concentration of the activator ion. SEM images indicated that as the concentration of activator ions was increased, the crystalline particles showed an increasing tendency to agglomerate irregularly. The room temperature excitation spectra of Eu3+- or Sm3+-doped BaWO4 phosphors consisted of a broad charge transfer band in the ultraviolet region and several sharp 4 f-4 f transitions. When Eu3+-doped BaWO4 phosphors were excited at 274 nm, the emission spectra exhibited sharp bands due to inner shell transitions occurring from the excited energy state 5 D 0 to the lower energy levels 7 F J ( J = 1, 2, 3, and 4). For Sm3+-doped BaWO4 phosphors, three intense emission peaks at 568, 603, and 649 nm and a very weak line at 712 nm were observed. The highest asymmetry ratio-the intensity ratio of the 4 G 5/2 → 6 H 9/2 electric dipole to the 4 G 5/2 → 6 H 5/2 magnetic dipole transitions-was obtained for 1 mol% doping of Sm3+, indicating that the Sm3+ ions occupied the non-inversion symmetry sites.

Heterogeneous sharpness for cross-spectral face recognition

NASA Astrophysics Data System (ADS)

Cao, Zhicheng; Schmid, Natalia A.

2017-05-01

Matching images acquired in different electromagnetic bands remains a challenging problem. An example of this type of comparison is matching active or passive infrared (IR) against a gallery of visible face images, known as cross-spectral face recognition. Among many unsolved issues is the one of quality disparity of the heterogeneous images. Images acquired in different spectral bands are of unequal image quality due to distinct imaging mechanism, standoff distances, or imaging environment, etc. To reduce the effect of quality disparity on the recognition performance, one can manipulate images to either improve the quality of poor-quality images or to degrade the high-quality images to the level of the quality of their heterogeneous counterparts. To estimate the level of discrepancy in quality of two heterogeneous images a quality metric such as image sharpness is needed. It provides a guidance in how much quality improvement or degradation is appropriate. In this work we consider sharpness as a relative measure of heterogeneous image quality. We propose a generalized definition of sharpness by first achieving image quality parity and then finding and building a relationship between the image quality of two heterogeneous images. Therefore, the new sharpness metric is named heterogeneous sharpness. Image quality parity is achieved by experimentally finding the optimal cross-spectral face recognition performance where quality of the heterogeneous images is varied using a Gaussian smoothing function with different standard deviation. This relationship is established using two models; one of them involves a regression model and the other involves a neural network. To train, test and validate the model, we use composite operators developed in our lab to extract features from heterogeneous face images and use the sharpness metric to evaluate the face image quality within each band. Images from three different spectral bands visible light, near infrared, and short-wave infrared are considered in this work. Both error of a regression model and validation error of a neural network are analyzed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mohammad, Sabah M., E-mail: Sabahaskari14@gmail.com; Ahmed, Naser M.; Abd-Alghafour, Nabeel M.

Vertically, well-aligned and high density ZnO nanorods were successfully hydrothermally grown on glass and silicon substrates using a simple and low cost system. The mechanism of synthesis of ZnO nanorods, generated with our system under hydrothermal conditions, is investigated in this report. Field-emission scanning electron microscopy indicated that the fabricated ZnO nanorods on both substrates have hexagonal shape with diameters ranging from 20 nm to 70 nm which grew vertically from the substrate. XRD analysis confirms the formation of wurtzite ZnO phase with a preferred orientation along (002) direction perpendicular on the substrate and enhanced crystallinity. The low value ofmore » the tensile strain (0.126 %) revealed that ZnO nanorods preferred to grow along the c-axis for both substrates. Photoluminescence spectra exhibited a strong, sharp UV near band edge emission peak with narrow FWHM values for both samples.« less

The addition of a second lanthanide ion to increase the luminescence of europium(III) macrocyclic complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bromm, A.J. Jr.; Vallarino, L.M.; Leif, R.C.

At present, the microscopic visualization of luminescent labels containing lanthanide(III) ions, primarily europium(III), as light-emitting centers is best performed with time-gated instrumentation, which by virtually eliminating the background fluorescence results in an improved signal to noise ratio. However, the use of the europium(III) macrocycle, Quantum Dye{trademark}, in conjunction with the strong luminescence enhancing effect (cofluorescence) of yttrium(III) or gadolinium(III), can eliminate the need for such specialized instrumentation. In the presence of Gd(III), the luminescence of the Eu(III)-macrocycles can be conveniently observed with conventional fluorescence instrumentation at previously unattainable low levels. The Eu(III) {sup 5}D{sub 0} {r_arrow} {sup 7}F{sub 2} emissionmore » of the Eu(III)-macrocycles was observed as an extremely sharp band with a maximum at 619 nm and a clearly resolved characteristic pattern. At very low Eu(III)-macrocycle concentrations, another sharp emission was detected at 614 nm, arising from traces of Eu(III) present in even the purest commercially available gadolinium products. Discrimination of the resolved emissions of the Eu(III)-macrocycle and Eu(III) contaminant should provide a means to further lower the limit of detection of the Eu(III)-macrocycle.« less

MODELING THE MULTI-BAND AFTERGLOW OF GRB 130831A: EVIDENCE FOR A SPINNING-DOWN MAGNETAR DOMINATED BY GRAVITATIONAL WAVE LOSSES?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Q.; Zong, H. S.; Huang, Y. F., E-mail: zonghs@nju.edu.cn, E-mail: hyf@nju.edu.cn

2016-06-01

The X-ray afterglow of GRB 130831A shows an “internal plateau” with a decay slope of ∼0.8, followed by a steep drop at around 10{sup 5} s with a slope of ∼6. After the drop, the X-ray afterglow continues with a much shallower decay. The optical afterglow exhibits two segments of plateaus separated by a luminous optical flare, followed by a normal decay with a slope basically consistent with that of the late-time X-ray afterglow. The decay of the internal X-ray plateau is much steeper than what we expect in the simplest magnetar model. We propose a scenario in which themore » magnetar undergoes gravitational-wave-driven r-mode instability, and the spin-down is dominated by gravitational wave losses up to the end of the steep plateau, so that such a relatively steep plateau can be interpreted as the internal emission of the magnetar wind and the sharp drop can be produced when the magnetar collapses into a black hole. This scenario also predicts an initial X-ray plateau lasting for hundreds of seconds with an approximately constant flux which is compatible with observation. Assuming that the magnetar wind has a negligible contribution in the optical band, we interpret the optical afterglow as the forward shock emission by invoking the energy injection from a continuously refreshed shock following the prompt emission phase. It is shown that our model can basically describe the temporal evolution of the multi-band afterglow of GRB 130831A.« less

Modeling the Multi-band Afterglow of GRB 130831A: Evidence for a Spinning-down Magnetar Dominated by Gravitational Wave Losses?

NASA Astrophysics Data System (ADS)

Zhang, Q.; Huang, Y. F.; Zong, H. S.

2016-06-01

The X-ray afterglow of GRB 130831A shows an “internal plateau” with a decay slope of ˜0.8, followed by a steep drop at around 105 s with a slope of ˜6. After the drop, the X-ray afterglow continues with a much shallower decay. The optical afterglow exhibits two segments of plateaus separated by a luminous optical flare, followed by a normal decay with a slope basically consistent with that of the late-time X-ray afterglow. The decay of the internal X-ray plateau is much steeper than what we expect in the simplest magnetar model. We propose a scenario in which the magnetar undergoes gravitational-wave-driven r-mode instability, and the spin-down is dominated by gravitational wave losses up to the end of the steep plateau, so that such a relatively steep plateau can be interpreted as the internal emission of the magnetar wind and the sharp drop can be produced when the magnetar collapses into a black hole. This scenario also predicts an initial X-ray plateau lasting for hundreds of seconds with an approximately constant flux which is compatible with observation. Assuming that the magnetar wind has a negligible contribution in the optical band, we interpret the optical afterglow as the forward shock emission by invoking the energy injection from a continuously refreshed shock following the prompt emission phase. It is shown that our model can basically describe the temporal evolution of the multi-band afterglow of GRB 130831A.

Radiative efficiency of lead iodide based perovskite solar cells

PubMed Central

Tvingstedt, Kristofer; Malinkiewicz, Olga; Baumann, Andreas; Deibel, Carsten; Snaith, Henry J.; Dyakonov, Vladimir; Bolink, Henk J.

2014-01-01

The maximum efficiency of any solar cell can be evaluated in terms of its corresponding ability to emit light. We herein determine the important figure of merit of radiative efficiency for Methylammonium Lead Iodide perovskite solar cells and, to put in context, relate it to an organic photovoltaic (OPV) model device. We evaluate the reciprocity relation between electroluminescence and photovoltaic quantum efficiency and conclude that the emission from the perovskite devices is dominated by a sharp band-to-band transition that has a radiative efficiency much higher than that of an average OPV device. As a consequence, the perovskite have the benefit of retaining an open circuit voltage ~0.14 V closer to its radiative limit than the OPV cell. Additionally, and in contrast to OPVs, we show that the photoluminescence of the perovskite solar cell is substantially quenched under short circuit conditions in accordance with how an ideal photovoltaic cell should operate. PMID:25317958

Two-Dimensional Raman Correlation Analysis of Diseased Esophagus in a Rat

NASA Astrophysics Data System (ADS)

Takanezawa, Sota; Morita, Shin-ichi; Maruyama, Atsushi; Murakami, Takurou N.; Kawashima, Norimichi; Endo, Hiroyuki; Iijima, Katsunori; Asakura, Tohru; Shimosegawa, Tooru; Sato, Hidetoshi

2010-07-01

Generalized two-dimensional (2D) Raman correlation analysis effectively distinguished a benign tumor from normal tissue. Line profiling Raman spectra of a rat esophagus, including a benign tumor, were measured and the generalized 2D synchronous and asynchronous spectra were calculated. In the autocorrelation area of the amide I band of proteins in the asynchronous map, a cross-like pattern was observed. A simulation study indicated that the pattern was caused by a sharp band component in the amide I band region. We considered that the benign tumor corresponded to the sharp component.

Implementation of serial amplifying fluorescent polymer arrays for enhanced chemical vapor sensing of landmines

NASA Astrophysics Data System (ADS)

Fisher, Mark E.; la Grone, Marcus; Sikes, John

2003-09-01

A sensor (known as Fido) that utilizes amplification of fluorescence quenching as the transduction mechanism for ultra-trace detection of nitroaromatic compounds associated with landmines has been described previously. Previous sensor prototypes utilized a single band of amplifying polymer deployed inside a capillary waveguide to form the sensing element of the detector. A new prototype has been developed that incorporates multiple, discrete bands of different amplifying polymers deployed in a linear array inside the capillary. Vapor-phase samples are introduced into the sensor as a sharp pulse via a gated inlet. As the vapor pulse is swept through the capillary by flow of a carrier gas, the pulse of analyte encounters the bands of polymer sequentially. If the sample contains nitroaromatic explosives, the bands of polymer will respond with a reduction in emission intensity proportional to the mass of analyte in the sample. Because the polymer bands are deployed serially, the analyte pulse does not reach the bands of polymer simultaneously. Hence, a temporal response pattern will be observed as the analyte pulse traverses the length of the capillary. In addition, the intensity of response for each band will vary, producing a ratiometric response. The temporal and ratiometric responses are characteristic of a given analyte, enhancing discrimination of target analytes from potential interferents. This should translate into a reduction in sensor false alarm rates.

Behold Mount Sharp!

NASA Image and Video Library

2012-08-06

This image taken by NASA Curiosity shows what lies ahead for the rover -- its main science target, informally called Mount Sharp. The rover shadow can be seen in the foreground, and the dark bands beyond are dunes.

Intrinsic defect oriented visible region absorption in zinc oxide films

NASA Astrophysics Data System (ADS)

Rakhesh, V.; Shankar, Balakrishnan

2018-05-01

Zinc Oxide films were deposited on the glass substrate using vacuum arc sputtering technology. Films were prepared in oxygen ambience for 10mA and 15 mA deposition current separately. The UV-Visible spectroscopy of the samples showed that both samples possess sharp absorption near 3.5eV which is the characteristic band gap absorption energy of ZnO films. The absorption coefficient were calculated for the samples and the (αℎϑ)2 vs energy plot is drawn. The plot suggested that in addition to the sharp band edge absorption, the sample prepared at 10mA deposition current showed sharp absorption edge near 1.51eV and that at 15 mA showed absorption edge near 1.47eV. This refers to the presence of an intrinsic defect level which is likely to be deep in the band gap.

The Study of Al0.29Ga0.71N-BASED Schottky Photodiodes Grown on Silicon by Plasma-Assisted Molecular Beam Epitaxy

NASA Astrophysics Data System (ADS)

Mohd Yusoff, M. Z.; Hassan, Z.; Chin, C. W.; Hassan, H. Abu; Abdullah, M. J.; Mohammad, N. N.; Ahmad, M. A.; Yusof, Y.

2013-05-01

In this paper, the growth and characterization of epitaxial Al0.29Ga0.71N grown on Si(111) by RF-plasma assisted molecular beam epitaxy (MBE) are described. The Al mole fraction was derived from the HR-XRD symmetric rocking curve (RC) ω/2θ scans of (0002) plane as x = 0.29. PL spectrum of sample has shown sharp and intense band edge emission of GaN without the existence of yellow emission band, showing that it is comparable in crystal quality of the sample when compared with previous reports. From the Raman measurement of as-grown Al0.29Ga0.71N layer on GaN/AlN/Si sample. We found that the dominant E2 (high) phonon mode of GaN appears at 572.7 cm-1. The E2 (high) mode of AlN appears at 656.7 cm-1 and deviates from the standard value of 655 cm-1 for unstrained AlN. Finally, AlGaN Schottky photodiode have been fabricated and analyzed by mean of electrical characterization, using current-voltage (I-V) measurement to evaluate the performance of this device.

Black carbon emission reduction strategies in healthcare industry for effective global climate change management.

PubMed

Raila, Emilia Mmbando; Anderson, David O

2017-04-01

Climate change remains one of the biggest threats to life on earth to date with black carbon (BC) emissions or smoke being the strongest cause after carbon dioxide (CO 2 ). Surprisingly, scientific evidence about black carbon emissions reduction in healthcare settings is sparse. This paper presents new research findings on the reduction of black carbon emissions from an observational study conducted at the UN Peacekeeping Operations (MINUSTAH) in Haiti in 2014. Researchers observed 20 incineration cycles, 30 minutes for each cycle of plastic and cardboard sharps healthcare waste (HCW) containers ranged from 3 to 14.6 kg. The primary aim was to determine if black carbon emissions from healthcare waste incineration can be lowered by mainstreaming the use of cardboard sharps healthcare waste containers instead of plastic sharps healthcare waste containers. Similarly, the study looks into whether burning temperature was associated with the smoke levels for each case or not. Independent samples t-tests demonstrated significantly lower black carbon emissions during the incineration of cardboard sharps containers (6.81 ± 4.79% smoke) than in plastic containers (17.77 ± 8.38% smoke); a statistically significant increase of 10.96% smoke (95% Confidence Interval ( CI) [4.4 to 17.5% smoke], p = 0.003). Correspondingly, lower bottom burner temperatures occurred during the incineration of cardboard sharps containers than in plastic (95% Cl [16 to 126°C], p = 0.014). Finally, we expect the application of the new quantitative evidence to form the basis for policy formulation, mainstream the use of cardboard sharps containers and opt for non-incineration disposal technologies as urgent steps for going green in healthcare waste management.

Insight into carrier lifetime impact on band-modulation devices

NASA Astrophysics Data System (ADS)

Parihar, Mukta Singh; Lee, Kyung Hwa; Park, Hyung Jin; Lacord, Joris; Martinie, Sébastien; Barbé, Jean-Charles; Xu, Yue; El Dirani, Hassan; Taur, Yuan; Cristoloveanu, Sorin; Bawedin, Maryline

2018-05-01

A systematic study to model and characterize the band-modulation Z2-FET device is developed bringing light to the relevance of the carrier lifetime influence. This work provides guidelines to optimize the Z2-FETs for sharp switching, ESD protection, and 1T-DRAM applications. Lower carrier lifetime in the Z2-FET helps in attaining the sharp switch. We provide new insights into the correlation between generation/recombination, diffusion, electrostatic barriers and carrier lifetime.

Observation and discussion of avalanche electroluminescence in GaN p-n diodes offering a breakdown electric field of 3 MV cm‑1

NASA Astrophysics Data System (ADS)

Mandal, S.; Kanathila, M. B.; Pynn, C. D.; Li, W.; Gao, J.; Margalith, T.; Laurent, M. A.; Chowdhury, S.

2018-06-01

We report on the first observation of avalanche electroluminescence resulting from band-to-band recombination (BTBR) of electron hole pairs at the breakdown limit of Gallium Nitride p-n diodes grown homo-epitaxially on single crystalline GaN substrates. The diodes demonstrated a near ideal breakdown electric field of 3 MV cm‑1 with electroluminescence (EL) demonstrating sharp peaks of emission energies near and at the band gap of GaN. The high critical electric field, near the material limit of GaN, was achieved by generating a smooth curved mesa edge with low plasma damage, using etch engineering without any use of field termination. The superior material quality was critical for such a near-ideal performance. An electric field of 3 MV cm‑1 recorded at the breakdown resulted in impact ionization, confirmed by a positive temperature dependence of the breakdown voltage. The spectral data provided evidence of BTBR of electron hole pairs that were generated by avalanche carrier multiplication in the depletion region.

Study of Sb2S3 thin films deposited by SILAR method

NASA Astrophysics Data System (ADS)

Deshpande, M. P.; Chauhan, Krishna; Patel, Kiran N.; Rajput, Piyush; Bhoi, Hiteshkumar R.; Chaki, S. H.

2018-05-01

In the present work, we deposited Sb2S3 thin films on glass slide by successive ionic layer adsorption and reaction (SILAR) technique with different time cycles. From EDAX, we could observe that the films were non-stoichiometric and contained few elements from glass slide. X-ray diffraction has shown that these films are orthorhombic in structure from where we have calculated the lattice parameter and crystallize size. SEM images shows that SILAR synthesized Sb2S3 thin films are homogenous and well distributed indicating the formation of uniform thin films at lower concentration. The room temperature Raman spectra of Sb2S3 thin films showed sharp peaks at 250 cm‑1 and 300 cm‑1 for all cases. Room temperature photoluminescence emission spectrum shows broad bands over 430–480 nm range with strong blue emission peak centered at same wavelength of 460 nm (2.70 eV) for all cases.

Microstructure-Sensitive Investigation of Fracture Using Acoustic Emission Coupled With Electron Microscopy

NASA Technical Reports Server (NTRS)

Wisner, Brian; Cabal, Mike; Vanniamparambiland, Prashanth A.; Leser, William; Hochhalter, Jacob; Kontsos, Antonios

2015-01-01

A novel technique using Scanning Electron Microscopy (SEM) in conjunction with Acoustic Emission (AE) monitoring is proposed to investigate microstructure-sensitive fatigue and fracture of metals. The coupling between quasi in situ microscopy with actual in situ nondestructive evaluation falls into the ICME framework and the idea of quantitative data-driven characterization of material behavior. To validate the use of AE monitoring inside the SEM chamber, Aluminum 2024-B sharp notch specimen were tested both inside and outside the microscope using a small scale mechanical testing device. Subsequently, the same type of specimen was tested inside the SEM chamber. Load data were correlated with both AE information and observations of microcracks around grain boundaries as well as secondary cracks, voids, and slip bands. The preliminary results are in excellent agreement with similar findings at the mesoscale. Extensions of the application of this novel technique are discussed.

Electroluminescence and Photocurrent Generation from Atomically Sharp WSe2/MoS2 Heterojunction p–n Diodes

PubMed Central

2015-01-01

The p–n diodes represent the most fundamental device building blocks for diverse optoelectronic functions, but are difficult to achieve in atomically thin transition metal dichalcogenides (TMDs) due to the challenges in selectively doping them into p- or n-type semiconductors. Here, we demonstrate that an atomically thin and sharp heterojunction p–n diode can be created by vertically stacking p-type monolayer tungsten diselenide (WSe2) and n-type few-layer molybdenum disulfide (MoS2). Electrical measurements of the vertically staked WSe2/MoS2 heterojunctions reveal excellent current rectification behavior with an ideality factor of 1.2. Photocurrent mapping shows rapid photoresponse over the entire overlapping region with a highest external quantum efficiency up to 12%. Electroluminescence studies show prominent band edge excitonic emission and strikingly enhanced hot-electron luminescence. A systematic investigation shows distinct layer-number dependent emission characteristics and reveals important insight about the origin of hot-electron luminescence and the nature of electron–orbital interaction in TMDs. We believe that these atomically thin heterojunction p–n diodes represent an interesting system for probing the fundamental electro-optical properties in TMDs and can open up a new pathway to novel optoelectronic devices such as atomically thin photodetectors, photovoltaics, as well as spin- and valley-polarized light emitting diodes, on-chip lasers. PMID:25157588

Time-resolved tomography using acoustic emissions in the laboratory, and application to sandstone compaction

NASA Astrophysics Data System (ADS)

Brantut, Nicolas

2018-06-01

Acoustic emission (AE) and active ultrasonic wave velocity monitoring are often performed during laboratory rock deformation experiments, but are typically processed separately to yield homogenized wave velocity measurements and approximate source locations. Here, I present a numerical method and its implementation in a free software to perform a joint inversion of AE locations together with the 3-D, anisotropic P-wave structure of laboratory samples. The data used are the P-wave first arrivals obtained from AEs and active ultrasonic measurements. The model parameters are the source locations and the P-wave velocity and anisotropy parameter (assuming transverse isotropy) at discrete points in the material. The forward problem is solved using the fast marching method, and the inverse problem is solved by the quasi-Newton method. The algorithms are implemented within an integrated free software package called FaATSO (Fast Marching Acoustic Emission Tomography using Standard Optimisation). The code is employed to study the formation of compaction bands in a porous sandstone. During deformation, a front of AEs progresses from one end of the sample, associated with the formation of a sequence of horizontal compaction bands. Behind the active front, only sparse AEs are observed, but the tomography reveals that the P-wave velocity has dropped by up to 15 per cent, with an increase in anisotropy of up to 20 per cent. Compaction bands in sandstones are therefore shown to produce sharp changes in seismic properties. This result highlights the potential of the methodology to image temporal variations of elastic properties in complex geomaterials, including the dramatic, localized changes associated with microcracking and damage generation.

Grain Temperature and Infrared Emission from Carbon Dust of Mixed Composition

NASA Astrophysics Data System (ADS)

Bartlett, S.; Duley, W. W.

1996-06-01

The equilibrium temperature of carbonaceous dust grains whose composition is consistent with IR spectra of diffuse cloud and dense cloud dust has been calculated using random covalent network (RCN) solutions for amorphous dust having a mixed graphite, diamond, and polymeric hydrocarbon composition. An effective medium approximation has been adopted to describe optical and thermal constants for dust compositions consistent with IR absorption spectra. A small amount of sp2 hybridized carbon in the form of aromatic rings is found to have a significant effect in reducing equilibrium temperature in dust with high diamond/polymer content. This formalism has also been used to calculate nonequilibrium emission spectra of very small grains (VSGs) subjected to stochastic heating in the interstellar radiation field. Such grains are found to emit strongly in sharp IR bands associated with C-H bonds at 3.4 μm and longer wavelengths. The effect of varying graphite/diamond/hydrocarbon composition on nonequilibrium emission by VSGs can also be described using this formalism. The ratio of emission at 12 and 25 μm is found to be high for VSGs with a large fraction of diamond or polymeric hydrocarbon but decreases dramatically for dust with a large sp2 aromatic component.

Thermoluminescent properties of nanocrystalline ZnTe thin films: Structural and morphological studies

NASA Astrophysics Data System (ADS)

Rajpal, Shashikant; Kumar, S. R.

2018-04-01

Zinc Telluride (ZnTe) is a binary II-VI direct band gap semiconducting material with cubic structure and having potential applications in different opto-electronic devices. Here we investigated the effects of annealing on the thermoluminescence (TL) of ZnTe thin films. A nanocrystalline ZnTe thin film was successfully electrodeposited on nickel substrate and the effect of annealing on structural, morphological, and optical properties were studied. The TL emission spectrum of as deposited sample is weakly emissive in UV region at ∼328 nm. The variation in the annealing temperature results into sharp increase in emission intensity at ∼328 nm along with appearance of a new peak at ∼437 nm in visible region. Thus, the deposited nanocrystalline ZnTe thin films exhibited excellent thermoluminescent properties upon annealing. Furthermore, the influence of annealing (annealed at 400 °C) on the solid state of ZnTe were also studied by XRD, SEM, EDS, AFM. It is observed that ZnTe thin film annealed at 400 °C after deposition provide a smooth and flat texture suited for optoelectronic applications.

A 38-year Summary of Raptor Banding at Hawk Ridge, Duluth, Minnesota, USA

EPA Science Inventory

Consistent banding of raptors at Hawk Ridge was initiated in 1972 and has continued for 38 years to the present. A total of 99,505 raptors or 2,619 per year have been banded at Hawk Ridge including 23 different species. The majority of birds banded were Sharp-shinned Hawks (Acci...

Multiwavelength Polarization of Rotation-Powered Pulsars

NASA Technical Reports Server (NTRS)

Harding, Alice K.; Kalapotharakos, Constantinos

2017-01-01

Polarization measurements provide strong constraints on models for emission from rotation-powered pulsars. We present multiwavelength polarization predictions showing that measurements over a range of frequencies can be particularly important for constraining the emission location, radiation mechanisms, and system geometry. The results assume a generic model for emission from the outer magnetosphere and current sheet in which optical to hard X-ray emission is produced by synchrotron radiation (SR) from electron-positron pairs and gamma-ray emission is produced by curvature radiation (CR) or SR from accelerating primary electrons. The magnetic field structure of a force-free magnetosphere is assumed and the phase-resolved and phase-averaged polarization is calculated in the frame of an inertial observer. We find that large position angle (PA) swings and deep depolarization dips occur during the light-curve peaks in all energy bands. For synchrotron emission, the polarization characteristics are strongly dependent on photon emission radius with larger, nearly 180deg, PA swings for emission outside the light cylinder (LC)‚ as the line of sight crosses the current sheet. The phase-averaged polarization degree for SR is less that 10% and around 20% for emission starting inside and outside the LC, respectively, while the polarization degree for CR is much larger, up to 40%-60%. Observing a sharp increase in polarization degree and a change in PA at the transition between X-ray and gamma-ray spectral components would indicate that CR is the gamma-ray emission mechanism.

Multiwavelength Polarization of Rotation-powered Pulsars

NASA Astrophysics Data System (ADS)

Harding, Alice K.; Kalapotharakos, Constantinos

2017-05-01

Polarization measurements provide strong constraints on models for emission from rotation-powered pulsars. We present multiwavelength polarization predictions showing that measurements over a range of frequencies can be particularly important for constraining the emission location, radiation mechanisms, and system geometry. The results assume a generic model for emission from the outer magnetosphere and current sheet in which optical to hard X-ray emission is produced by synchrotron radiation (SR) from electron-positron pairs and γ-ray emission is produced by curvature radiation (CR) or SR from accelerating primary electrons. The magnetic field structure of a force-free magnetosphere is assumed and the phase-resolved and phase-averaged polarization is calculated in the frame of an inertial observer. We find that large position angle (PA) swings and deep depolarization dips occur during the light-curve peaks in all energy bands. For synchrotron emission, the polarization characteristics are strongly dependent on photon emission radius with larger, nearly 180°, PA swings for emission outside the light cylinder (LC) as the line of sight crosses the current sheet. The phase-averaged polarization degree for SR is less that 10% and around 20% for emission starting inside and outside the LC, respectively, while the polarization degree for CR is much larger, up to 40%-60%. Observing a sharp increase in polarization degree and a change in PA at the transition between X-ray and γ-ray spectral components would indicate that CR is the γ-ray emission mechanism.

Multiwavelength Polarization of Rotation-powered Pulsars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harding, Alice K.; Kalapotharakos, Constantinos

Polarization measurements provide strong constraints on models for emission from rotation-powered pulsars. We present multiwavelength polarization predictions showing that measurements over a range of frequencies can be particularly important for constraining the emission location, radiation mechanisms, and system geometry. The results assume a generic model for emission from the outer magnetosphere and current sheet in which optical to hard X-ray emission is produced by synchrotron radiation (SR) from electron–positron pairs and γ -ray emission is produced by curvature radiation (CR) or SR from accelerating primary electrons. The magnetic field structure of a force-free magnetosphere is assumed and the phase-resolved andmore » phase-averaged polarization is calculated in the frame of an inertial observer. We find that large position angle (PA) swings and deep depolarization dips occur during the light-curve peaks in all energy bands. For synchrotron emission, the polarization characteristics are strongly dependent on photon emission radius with larger, nearly 180°, PA swings for emission outside the light cylinder (LC) as the line of sight crosses the current sheet. The phase-averaged polarization degree for SR is less that 10% and around 20% for emission starting inside and outside the LC, respectively, while the polarization degree for CR is much larger, up to 40%–60%. Observing a sharp increase in polarization degree and a change in PA at the transition between X-ray and γ -ray spectral components would indicate that CR is the γ -ray emission mechanism.« less

The Bone Black Pigment Identification by Noninvasive, In Situ Infrared Reflection Spectroscopy

PubMed Central

Malagodi, Marco; Vagnini, Manuela

2018-01-01

Two real case studies, an oil painting on woven paper and a cycle of mural paintings, have been presented to validate the use of infrared reflection spectroscopy as suitable technique for the identification of bone black pigment. By the use of the sharp weak band at 2013 cm−1, it has been possible to distinguish animal carbon-based blacks by a noninvasive method. Finally, an attempt for an eventual assignment for the widely used sharp band at 2013 cm−1 is discussed. PMID:29736290

Magnetic, superconducting and electron-boson properties of GdO(F)FeAs oxypnictides

NASA Astrophysics Data System (ADS)

Kuzmicheva, Tatiana; Sadakov, Andrey; Muratov, Andrei; Kuzmichev, Svetoslav; Khlybov, Yevgeny; Kulikova, Lyudmila; Eltsev, Yuri

2018-05-01

We performed comprehensive studies of nearly optimal fluorine-substituted GdO1-xFx FeAs oxypnictide superconductors with TC = 48 - 53 K . Specific heat measurements revealed a sharp peak at T = 3.5 K that shifts to lower temperatures with magnetic field increase. This peak corresponds to an antiferromagnetic ordering in Gd3+ ion sublattice and may indicate coexistence between superconducting and magnetic orderings. Andreev transport through artificially made constriction demonstrated two channels for the carriers from the band(s) with the large superconducting gap as well as from those with the small gap. As expected, the presence of a transport channel with the bands mixing (ΔL +ΔS) was not detected. Using intrinsic multiple Andreev reflections effect (IMARE) spectroscopy, we determined two superconducting gaps, ΔS ≈ 2.7 meV , and ΔL ≈ 11.6 meV . The reproducible fine structure in the dI(V)/dV spectra of the Andreev contacts (satellites of the main subharmonic gap structure for ΔL) was interpreted as caused by a resonant emission of bosons with the energy ε0 = 12 - 15 meV ≈ΔL +ΔS during the process of multiple Andreev reflections (MAR) for normal carriers in ΔL-band(s) transport channel.

Detection of carbon-fluorine bonds in organofluorine compounds by Raman spectroscopy using a copper-vapor laser

NASA Astrophysics Data System (ADS)

Sharts, Clay M.; Gorelik, Vladimir S.; Agoltsov, A. M.; Zlobina, Ludmila I.; Sharts, Olga N.

1999-02-01

The Raman spectra of fluoro-organic compounds show specific emission bands for carbon-fluorine bonds in the range 500- 800 wave numbers (cm-1)). With very limited exceptions, biological materials do not contain carbon- fluorine bonds. Fluoro-organic compounds introduced into biological samples can be detected by a Raman emission signal. Normal mode C-F bond bands are observed: (1) at 710- 785 cm -1 for trifluoromethyl groups; (2) at 530-610 cm -1 for aromatic organofluorine bonds; (3) a range centered at 690 cm -1 for difluoromethylene groups. Specific examples of normal mode C-F bond emissions for organofluorine compounds containing trifluoromethyl groups are: 1-bromoperfluorooctane, 726 cm -1; perfluorodecanoic acid, 730 cm -1; triperfluoropropylamine, 750 cm -1; 1,3,5-tris- (trifluoromethyl)-benzene, 730 cm -1; Fluoxetine (Prozac) commercial powdered pill at 782 cm -1. Compounds containing aromatic C-F bonds are: hexafluorobenzene, 569 cm MIN1; pentafluoropyridine, 589 cm -1. Difluoromethylene groups: perfluorodecalin, 692 cm-1; perfluorocyclohexane, 691 cm -1. Raman spectra were observed with a standard single monochromator. The 510.8 nm light source was a copper-vapor laser operated at 3-10 watts with 10-12 nanosecond pulses at 10 kHz repetition rate. Detection was made with a time-gated photomultiplier tube. Resonance Raman spectra were also observed at 255.4 nm, using a frequency doubling crystal. Observed spectra were free of fluorescence with very sharp strong C-F lines.

`Orphan' afterglows in the Universal structured jet model for γ-ray bursts

NASA Astrophysics Data System (ADS)

Rossi, Elena M.; Perna, Rosalba; Daigne, Frédéric

2008-10-01

The paucity of reliable achromatic breaks in γ-ray burst afterglow light curves motivates independent measurements of the jet aperture. Serendipitous searches of afterglows, especially at radio wavelengths, have long been the classic alternative. These survey data have been interpreted assuming a uniformly emitting jet with sharp edges (`top-hat' jet), in that case the ratio of weakly relativistically beamed afterglows to GRBs scales with the jet solid angle. In this paper, we consider, instead, a very wide outflow with a luminosity that decreases across the emitting surface. In particular, we adopt the universal structured jet (USJ) model, which is an alternative to the top-hat model for the structure of the jet. However, the interpretation of the survey data is very different: in the USJ model, we only observe the emission within the jet aperture and the observed ratio of prompt emission rate to afterglow rate should solely depend on selection effects. We compute the number and rate of afterglows expected in all-sky snapshot observations as a function of the survey sensitivity. We find that the current (negative) results for OA searches are in agreement with our expectations. In radio and X-ray bands, this was mainly due to the low sensitivity of the surveys, while in the optical band the sky coverage was not sufficient. In general, we find that X-ray surveys are poor tools for OA searches, if the jet is structured. On the other hand, the Faint Images of the Radio Sky at Twenty-cm radio survey and future instruments like the Allen Telescope Array (in the radio band) and especially GAIA, Panoramic Survey Telescope and Rapid Response System and Large Synoptic Survey Telescope (in the optical band) will have chances to detect afterglows.

A Small Fullerene (C{sub 24}) may be the Carrier of the 11.2 μ m Unidentified Infrared Band

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bernstein, L. S.; Shroll, R. M.; Lynch, D. K.

2017-02-20

We analyze the spectrum of the 11.2 μ m unidentified infrared band (UIR) from NGC 7027 and identify a small fullerene (C{sub 24}) as a plausible carrier. The blurring effects of lifetime and vibrational anharmonicity broadening obscure the narrower, intrinsic spectral profiles of the UIR band carriers. We use a spectral deconvolution algorithm to remove the blurring, in order to retrieve the intrinsic profile of the UIR band. The shape of the intrinsic profile—a sharp blue peak and an extended red tail—suggests that the UIR band originates from a molecular vibration–rotation band with a blue band head. The fractional areamore » of the band-head feature indicates a spheroidal molecule, implying a nonpolar molecule and precluding rotational emission. Its rotational temperature should be well approximated by that measured for nonpolar molecular hydrogen, ∼825 K for NGC 7027. Using this temperature, and the inferred spherical symmetry, we perform a spectral fit to the intrinsic profile, which results in a rotational constant implying C{sub 24} as the carrier. We show that the spectroscopic parameters derived for NGC 7027 are consistent with the 11.2 μ m UIR bands observed for other objects. We present density functional theory (DFT) calculations for the frequencies and infrared intensities of C{sub 24}. The DFT results are used to predict a spectral energy distribution (SED) originating from absorption of a 5 eV photon, and characterized by an effective vibrational temperature of 930 K. The C{sub 24} SED is consistent with the entire UIR spectrum and is the dominant contributor to the 11.2 and 12.7 μ m bands.« less

Photoluminescence properties of a new orange–red emitting Sm{sup 3+}-doped Y{sub 2}Mo{sub 4}O{sub 15} phosphor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deng, Huajuan; Zhao, Ze; Wang, Jing

2015-08-15

A series of novel Y{sub 2}Mo{sub 4}O{sub 15}:xSm{sup 3+} ( (0.01 ≤ x ≤ 0.20) phosphors for white light-emitting (W-LEDs) were successfully prepared by the solid state reaction technology at 973 K for 12 h. X-ray diffraction and photoluminescence spectra were utilized to characterize the structure and luminescence properties of the as-synthesized phosphors. The emission spectra of the Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} phosphors consisted of some sharp emission peaks of Sm{sup 3+} ions centered at 565 nm, 605 nm, 650 nm, and 712 nm. The strongest one is located at 605 nm due to {sup 4}G{sub 5/2}–{sup 6}H{sub 7/2}more » transition of Sm{sup 3+}, generating bright orange–red light. The optimum dopant concentration of Sm{sup 3+} ions in Y{sub 2}Mo{sub 4}O{sub 15}:xSm{sup 3+} is around 5 mol% and the critical transfer distance of Sm{sup 3+} is calculated as 23.32 Å. The CIE chromaticity coordinates of the Y{sub 2}Mo{sub 4}O{sub 15}:0.05Sm{sup 3+} phosphors were located in the orange reddish region. The Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} phosphors may be potentially used as red phosphors for white light-emitting diodes. - Graphical abstract: The excitation spectrum of Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} is composed of a broad band and some sharp f–f transitions. Under 407 nm excitation, the phosphor presents some sharp emission peaks of Sm{sup 3+} ions. - Highlights: • An orange–red emitting Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} phosphor has been firstly synthesized. • Their structures, luminescent properties have also been investigated. • The optical absorption edge for the molybdate lies around 325 nm. • The CIE chromaticity coordinates were located in the orange reddish region.« less

[Perceptual sharpness metric for visible and infrared color fusion images].

PubMed

Gao, Shao-Shu; Jin, Wei-Qi; Wang, Xia; Wang, Ling-Xue; Luo, Yuan

2012-12-01

For visible and infrared color fusion images, objective sharpness assessment model is proposed to measure the clarity of detail and edge definition of the fusion image. Firstly, the contrast sensitivity functions (CSF) of the human visual system is used to reduce insensitive frequency components under certain viewing conditions. Secondly, perceptual contrast model, which takes human luminance masking effect into account, is proposed based on local band-limited contrast model. Finally, the perceptual contrast is calculated in the region of interest (contains image details and edges) in the fusion image to evaluate image perceptual sharpness. Experimental results show that the proposed perceptual sharpness metrics provides better predictions, which are more closely matched to human perceptual evaluations, than five existing sharpness (blur) metrics for color images. The proposed perceptual sharpness metrics can evaluate the perceptual sharpness for color fusion images effectively.

Discovery of a Color-selected Quasar at z = 5.50.

PubMed

Stern; Spinrad; Eisenhardt; Bunker; Dawson; Stanford; Elston

2000-04-20

We present observations of RD J030117+002025, a quasar at z=5.50 discovered from deep, multicolor, ground-based observations covering 74 arcmin2. This is the most distant quasar or active galaxy currently known. The object was targeted as an R-band dropout, with RAB>26.3 (3 sigma limit in a 3&arcsec; diameter region), IAB=23.8, and zAB=23.4. The Keck/Low-Resolution Imaging Spectrometer spectrum shows broad Lyalpha/N v lambda1240 emission and sharp absorption decrements from the highly redshifted hydrogen forests. The fractional continuum depression due to the Lyalpha forest is DA=0.90. RD J030117+002025 is the least luminous high-redshift quasar known (MB approximately -22.7).

Potential Interference from Wireless Water Tank Transmitters at Goldstone

NASA Astrophysics Data System (ADS)

Ho, C.

2008-02-01

The Deep Space Network (DSN) facility in the Goldstone, California, area is considering installation of a new type of wireless transmitter (M2400S) within the facility. The transmitters will be used to monitor the water levels in several water tanks. Then these water-level signals will be transmitted to the nearby DSN facilities using transmitters operating in the UHF band (900-MHz) or S-band (2.4-GHz). This study is to evaluate the interference effects from the transmitters in adjacent DSN receiving stations. First we perform a terrain profile analysis to identify if there is a line of sight between each transmitter and the nearby DSN stations. After taking into account terrain shielding using high-resolution data, total propagation losses are calculated along each path. Then we perform the link analysis for each site to identify if the interference power exceeds the protection threshold of DSN receiving stations. As a result, we find that, because there is no bandpass filter installed in the transmitter system, interference power from the new transmitter at S-band will greatly exceed the protection criteria of broadband radio astronomy services (RAS) at S-band, such as Deep Space Station (DSS) 12 and DSS 28, by about 50 dB. The interference may also cause problems on all deep-space research stations at S-band, such as the Mars, Apollo, Venus, and Gemini sites. Without a sharp bandpass filter to suppress the out-of-band emissions in the frequency bands that the DSN station and RAS use, the author recommends not installing this type of transmitter within the Goldstone DSN facility area.

Near-infrared exciton-polaritons in strongly coupled single-walled carbon nanotube microcavities

NASA Astrophysics Data System (ADS)

Graf, Arko; Tropf, Laura; Zakharko, Yuriy; Zaumseil, Jana; Gather, Malte C.

2016-10-01

Exciton-polaritons form upon strong coupling between electronic excitations of a material and photonic states of a surrounding microcavity. In organic semiconductors the special nature of excited states leads to particularly strong coupling and facilitates condensation of exciton-polaritons at room temperature, which may lead to electrically pumped organic polariton lasers. However, charge carrier mobility and photo-stability in currently used materials is limited and exciton-polariton emission so far has been restricted to visible wavelengths. Here, we demonstrate strong light-matter coupling in the near infrared using single-walled carbon nanotubes (SWCNTs) in a polymer matrix and a planar metal-clad cavity. By exploiting the exceptional oscillator strength and sharp excitonic transition of (6,5) SWCNTs, we achieve large Rabi splitting (>110 meV), efficient polariton relaxation and narrow band emission (<15 meV). Given their high charge carrier mobility and excellent photostability, SWCNTs represent a promising new avenue towards practical exciton-polariton devices operating at telecommunication wavelengths.

Growth mechanism and optical properties of aligned hexagonal ZnO nanoprisms synthesized by noncatalytic thermal evaporation.

PubMed

Umar, Ahmad; Karunagaran, B; Kim, S H; Suh, E-K; Hahn, Y B

2008-05-19

Vertically aligned perfectly hexagonal-shaped ZnO nanoprisms have been grown on a Si(100) substrate via a noncatalytic thermal evaporation process by using metallic zinc powder in the presence of oxygen gas. The as-grown nanoprisms consist of ultra smooth Zn-terminated (0001) facets bounded with the {0110} surfaces. The as-synthesized products are single-crystalline with the wurtzite hexagonal phase and grown along the [0001] direction, as confirmed from the detailed structural investigations. The presence of a sharp and strong nonpolar optical phonon high-E2 mode at 437 cm(-1) in the Raman scattering spectrum further confirms good crystallinity and wurtzite hexagonal phase for the as-grown products. The as-grown nanoprisms exhibit a strong near-band-edge emission with a very weak deep-level emission in the room-temperature and low-temperature photoluminescence measurements, confirming good optical properties for the deposited products. Moreover, systematic time-dependent experiments were also performed to determine the growth process of the grown vertically aligned nanoprisms.

Toward a Better Understanding of the GRB Phenomenon: a New Model for GRB Prompt Emission and its Effects on the New LiNT- Epeak,irest,NT Relation

NASA Astrophysics Data System (ADS)

Guiriec, S.; Kouveliotou, C.; Daigne, F.; Zhang, B.; Hascoët, R.; Nemmen, R. S.; Thompson, D. J.; Bhat, P. N.; Gehrels, N.; Gonzalez, M. M.; Kaneko, Y.; McEnery, J.; Mochkovitch, R.; Racusin, J. L.; Ryde, F.; Sacahui, J. R.; Ünsal, A. M.

2015-07-01

Gamma-ray burst (GRB) prompt emission spectra in the keV-MeV energy range are usually considered to be adequately fitted with the empirical Band function. Recent observations with the Fermi Gamma-ray Space Telescope (Fermi) revealed deviations from the Band function, sometimes in the form of an additional blackbody (BB) component, while on other occasions in the form of an additional power law (PL) component extending to high energies. In this article we investigate the possibility that the three components may be present simultaneously in the prompt emission spectra of two very bright GRBs (080916C and 090926A) observed with Fermi, and how the three components may affect the overall shape of the spectra. While the two GRBs are very different when fitted to a single Band function, they look like “twins” in the three-component scenario. Through fine-time spectroscopy down to the 100 ms timescale, we follow the evolution of the various components. We succeed in reducing the number of free parameters in the three-component model, which results in a new semi-empirical model—but with physical motivations—to be competitive with the Band function in terms of number of degrees of freedom. From this analysis using multiple components, the Band function is globally the most intense component, although the additional PL can overpower the others in sharp time structures. The Band function and the BB component are the most intense at early times and globally fade across the burst duration. The additional PL is the most intense component at late time and may be correlated with the extended high-energy emission observed thousands of seconds after the burst with Fermi/Large Area Telescope. Unexpectedly, this analysis also shows that the additional PL may be present from the very beginning of the burst, where it may even overpower the other components at low energy. We investigate the effect of the three components on the new time-resolved luminosity-hardness relation in both the observer and rest frames and show that a strong correlation exists between the flux of the non-thermal Band function and its Epeak only when the three components are fitted simultaneously to the data (i.e., {F}i{NT}-{E}{peak,i}{NT} relation). In addition, this result points toward a universal relation between those two quantities when transposed to the central engine rest frame for all GRBs (i.e., {L}i{NT}-{E}{peak,i}{rest,{NT}} relation). We discuss a possible theoretical interpretation of the three spectral components within this new empirical model. We suggest that (i) the BB component may be interpreted as the photosphere emission of a magnetized relativistic outflow, (ii) the Band component has synchrotron radiation in an optically thin region above the photosphere, either from internal shocks or magnetic field dissipation, and (iii) the extra PL component extending to high energies likely has an inverse Compton origin of some sort, even though its extension to a much lower energy remains a mystery.

Near-infrared Thermal Emission from TrES-3b: A Ks-band Detection and an H-band Upper Limit on the Depth of the Secondary Eclipse

NASA Astrophysics Data System (ADS)

Croll, Bryce; Jayawardhana, Ray; Fortney, Jonathan J.; Lafrenière, David; Albert, Loic

2010-08-01

We present H- and Ks-band photometry bracketing the secondary eclipse of the hot Jupiter TrES-3b using the Wide-field Infrared Camera on the Canada-France-Hawaii Telescope. We detect the secondary eclipse of TrES-3b with a depth of 0.133+0.018 -0.016% in the Ks band (8σ)—a result that is in sharp contrast to the eclipse depth reported by de Mooij & Snellen. We do not detect its thermal emission in the H band, but place a 3σ limit of 0.051% on the depth of the secondary eclipse in this band. A secondary eclipse of this depth in Ks requires very efficient day-to-nightside redistribution of heat and nearly isotropic reradiation, a conclusion that is in agreement with longer wavelength, mid-infrared Spitzer observations. Our 3σ upper limit on the depth of our H-band secondary eclipse also argues for very efficient redistribution of heat and suggests that the atmospheric layer probed by these observations may be well homogenized. However, our H-band upper limit is so constraining that it suggests the possibility of a temperature inversion at depth, or an absorbing molecule, such as methane, that further depresses the emitted flux at this wavelength. The combination of our near-infrared measurements and those obtained with Spitzer suggests that TrES-3b displays a near-isothermal dayside atmospheric temperature structure, whose spectrum is well approximated by a blackbody. We emphasize that our strict H-band limit is in stark disagreement with the best-fit atmospheric model that results from longer wavelength observations only, thus highlighting the importance of near-infrared observations at multiple wavelengths, in addition to those returned by Spitzer in the mid-infrared, to facilitate a comprehensive understanding of the energy budgets of transiting exoplanets. Based on observations obtained with WIRCam, a joint project of CFHT, Taiwan, Korea, Canada, France, at the Canada-France-Hawaii Telescope (CFHT) which is operated by the National Research Council (NRC) of Canada, the Institute National des Sciences de l'Univers of the Centre National de la Recherche Scientifique of France, and the University of Hawaii.

Annealing effects on the optical and morphological properties of ZnO nanorods on AZO substrate by using aqueous solution method at low temperature.

PubMed

Hang, Da-Ren; Islam, Sk Emdadul; Sharma, Krishna Hari; Kuo, Shiao-Wei; Zhang, Cheng-Zu; Wang, Jun-Jie

2014-01-01

Vertically aligned ZnO nanorods (NRs) on aluminum-doped zinc oxide (AZO) substrates were fabricated by a single-step aqueous solution method at low temperature. In order to optimize optical quality, the effects of annealing on optical and structural properties were investigated by scanning electron microscopy, X-ray diffraction, photoluminescence (PL), and Raman spectroscopy. We found that the annealing temperature strongly affects both the near-band-edge (NBE) and visible (defect-related) emissions. The best characteristics have been obtained by employing annealing at 400°C in air for 2 h, bringing about a sharp and intense NBE emission. The defect-related recombinations were also suppressed effectively. However, the enhancement decreases with higher annealing temperature and prolonged annealing. PL study indicates that the NBE emission is dominated by radiative recombination associated with hydrogen donors. Thus, the enhancement of NBE is due to the activation of radiative recombinations associated with hydrogen donors. On the other hand, the reduction of visible emission is mainly attributed to the annihilation of OH groups. Our results provide insight to comprehend annealing effects and an effective way to improve optical properties of low-temperature-grown ZnO NRs for future facile device applications.

Annealing effects on the optical and morphological properties of ZnO nanorods on AZO substrate by using aqueous solution method at low temperature

PubMed Central

2014-01-01

Vertically aligned ZnO nanorods (NRs) on aluminum-doped zinc oxide (AZO) substrates were fabricated by a single-step aqueous solution method at low temperature. In order to optimize optical quality, the effects of annealing on optical and structural properties were investigated by scanning electron microscopy, X-ray diffraction, photoluminescence (PL), and Raman spectroscopy. We found that the annealing temperature strongly affects both the near-band-edge (NBE) and visible (defect-related) emissions. The best characteristics have been obtained by employing annealing at 400°C in air for 2 h, bringing about a sharp and intense NBE emission. The defect-related recombinations were also suppressed effectively. However, the enhancement decreases with higher annealing temperature and prolonged annealing. PL study indicates that the NBE emission is dominated by radiative recombination associated with hydrogen donors. Thus, the enhancement of NBE is due to the activation of radiative recombinations associated with hydrogen donors. On the other hand, the reduction of visible emission is mainly attributed to the annihilation of OH groups. Our results provide insight to comprehend annealing effects and an effective way to improve optical properties of low-temperature-grown ZnO NRs for future facile device applications. PMID:25520589

The investigation of Al0.29Ga0.71N/GaN/AlN and AlN/GaN/AlN thin films grown on Si (111) by RF plasma-assisted MBE

NASA Astrophysics Data System (ADS)

Yusoff, Mohd Zaki Mohd; Mahyuddin, Azzafeerah; Hassan, Zainuriah; Hassan, Haslan Abu; Abdullah, Mat Johar

2012-06-01

Recently, gallium nitride (GaN) and its related compounds involving Al and In have attracted much attention because of their potential to be used as high-efficiency UV light emitting devices, and as high frequency and high power electronic devices. Consequently, the growth and physics of GaN-based materials have attracted remarkable scientific attention. In this work, the growth and characterization of epitaxial Al0.29Ga0.71N and AlN layers grown on Si (111) by RF-plasma assisted molecular beam epitaxy (MBE) are described. The Al mole fraction was derived from the HR-XRD symmetric rocking curve (RC) ω/2θ scans of (0002) plane as x = 0.29. For AlN/GaN/AlN sample, the maximum Raman intensity at 521.53 cm-1 is attributed to crystalline silicon. It was found that the allowed Raman optical phonon mode of GaN, the E1 (high) is clearly visible, which is located at 570.74 cm-1. Photoluminscence (PL) spectrums of both samples have shown sharp and intense band edge emission of GaN without the existence of yellow emission band, showing good crystal quality of the samples have been successfully grown on Si substrate.

Nanoporous structures on ZnO thin films

NASA Astrophysics Data System (ADS)

Gür, Emre; Kılıç, Bayram; Coşkun, C.; Tüzemen, S.; Bayrakçeken, Fatma

2010-01-01

Porous structures were formed on ZnO thin films which were grown by an electrochemical deposition (ECD) method. The growth processes were carried out in a solution of dimethylsulfoxide (DMSO) zinc perchlorate, Zn(ClO 4) 2, at 120 ∘C on indium tin oxide (ITO) substrates. Optical and structural characterizations of electrochemically grown ZnO thin films have shown that the films possess high (0002) c-axis orientation, high nucleation, high intensity and low FWHM of UV emission at the band edge region and a sharp UV absorption edge. Nanoporous structures were formed via self-assembled monolayers (SAMs) of hexanethiol (C 6SH) and dodecanethiol (C 12SH). Scanning electron microscope (SEM) measurements showed that while a nanoporous structure (pore radius 20 nm) is formed on the ZnO thin films by hexanathiol solution, a macroporous structure (pore radius 360 nm) is formed by dodecanethiol solution. No significant variation is observed in X-ray diffraction (XRD) measurements on the ZnO thin films after pore formation. However, photoluminescence (PL) measurements showed that green emission is observed as the dominant emission for the macroporous structures, while no variation is observed for the thin film nanoporous ZnO sample.

Contemporaneous Ultraviolet and Optical Observations of Direct and Raman-scattered O VI Lines in Symbiotic Stars

NASA Astrophysics Data System (ADS)

Birriel, Jennifer J.; Espey, Brian R.; Schulte-Ladbeck, Regina E.

2000-12-01

Symbiotic stars are binary systems consisting of a hot star, typically a white dwarf, and a cool giant companion. The wind from the cool star is ionized by the radiation from the hot star, resulting in the characteristic combination of sharp nebular emission lines and stellar molecular absorption bands in the optical spectrum. Most of the emission lines are readily identifiable with common ions. However, two strong, broad emission lines at 6825 and 7082 Å defied identification with known atoms and ions. In 1989 Schmid made the case that these long unidentified emission lines resulted from the Raman scattering of the O VI resonance photons at 1032, 1038 Å by neutral hydrogen. We present contemporaneous far-UV and optical observations of direct and Raman-scattered O VI lines for nine symbiotic stars obtained with the Hopkins Ultraviolet Telescope (Astro-2) and various ground-based optical telescopes. The O VI emission lines are present in every instance in which the λλ6825, 7082 lines are present, in support of the Schmid Raman-scattering model. We calculate the scattering efficiencies and discuss the results in terms of the Raman-scattering model. Additionally, we measure the flux of the Fe II fluorescence line at 1776 Å, which is excited by the O VI line at 1032 Å, and calculate the first estimates of the conversion efficiencies for this process.

Matrix isolation of fullerene-derived CO 2 at ambient temperature

NASA Astrophysics Data System (ADS)

Taylor, Roger; Pénicaud, Alain; Tower, Nicole J.

1998-10-01

Heating fullerene oxides, e.g. C 120O, C 70O, C 60O and C 60O 2, in a KBr matrix at 225°C under 0.2 mbar vacuum, produces a sharp IR band at 2330 cm -1 due to matrix-isolated CO 2. The band is also obtained by heating a KBr matrix of the insoluble deposits that fullerenes form on standing in air. The matrices are extremely stable and are unchanged even by prolonged heating at 225°C under vacuum. Heating a KBr matrix of the deposit from C 84 produces also a sharp stable band at 2035 cm -1 consistent with matrix-isolated C 3. Similar treatment of C 70F 38O produces matrices containing both CO 2 and CO, the latter being of lower stability.

Heterocrystal and bicrystal structures of ZnS nanowires synthesized by plasma enhanced chemical vapour deposition

NASA Astrophysics Data System (ADS)

Jie, J. S.; Zhang, W. J.; Jiang, Y.; Meng, X. M.; Zapien, J. A.; Shao, M. W.; Lee, S. T.

2006-06-01

ZnS nanowires with heterocrystal and bicrystal structures were successfully synthesized using the DC-plasma chemical vapour deposition (CVD) method. The heterocrystalline ZnS nanowires have the zinc blende (ZB) and wurtzite (WZ) zones aligned alternately in the transverse direction but without an obvious period. The bicrystal ZnS nanowires are composed of two ZB fractions separated by a clear grain boundary along the length. Significantly, the grain boundaries in both the heterocrystal and bicrystal structures are atomically sharp without any visible lattice distortion. The effects of plasma species, ion bombardment, and silicon impurities in the formation of these distinctive structures are discussed. A defect-induced red-shift and broadening of the band-gap emission are revealed in photoluminescence (PL) and cathodoluminescence (CL) measurements.

Structural and spectral properties of undoped and tungsten doped Zn3(PO4)2ZnO nanopowders

NASA Astrophysics Data System (ADS)

Satyavathi, K.; Subba Rao, M.; Nagabhaskararao, Y.; Cole, Sandhya

2018-01-01

Pure and tungsten doped Zn3(PO4)2ZnO nanopowders (NPs) are prepared using sol-gel method. It has the longest track record of used in dentistry. It is used for cementation of inlays, crowns and orthodontic appliances. The systematic investigations like X-ray Diffraction (XRD), Scanning electron microscope (SEM) with energy dispersive X-ray (EDX) spectroscope, Transmission electron microscope (TEM), Fourier transform infrared (FT-IR) spectroscopy, Optical absorption, Photoluminescence (PL) and Electron Paramagnetic Resonance (EPR) spectroscopic techniques are carried out for the prepared NPs. XRD pattern reveals that the prepared samples are in crystalline nature in which Zn3(PO4)2 corresponding to monoclinic phase and ZnO corresponding to hexagonal wurtzite phase, the average crystallite size of prepared nanopowders is in the range of 20-30 nm. The lattice strain, lattice cell parameters, unit cell volume and dislocation density of the prepared NPs are also calculated. The morphology of the prepared NPs is analyzed with SEM and TEM images. The distribution of Zn, P, O and W species in the prepared samples are identified by the chemical composition mapping through EDX. IR spectra of prepared samples exhibit the characteristic sharp absorption band peaks. The sharp absorption bands observed in the region 1200-900 cm-1 are due to complex stretching of characteristic PO43- groups. The absorption spectra exhibit a broad band around 696 nm is recognized due to 2B2g → 2B1g (dxy → dx2- y2) transition of tungsten ions. The PL spectra exhibit four emission peaks in the visible region indicating the quantum-confinement-induced photoluminescence. The CIE chromaticity diagram suggests that the prepared NPs have good color purity. The EPR spectra indicate that the W5+ ions occupy octahedral site symmetry in the host lattice.

A Compact Multiple Notched Ultra-Wide Band Antenna with an Analysis of the CSRR-TO-CSRR Coupling for Portable UWB Applications.

PubMed

Rahman, MuhibUr; Ko, Dong-Sik; Park, Jung-Dong

2017-09-25

We present a compact ultra-wideband (UWB) antenna integrated with sharp notches with a detailed analysis of the mutual coupling of the multiple notch resonators. By utilizing complementary split ring resonators (CSRR) on the radiating semi-circular patch, we achieve the sharp notch-filtering of various bands within the UWB band without increasing the antenna size. The notched frequency bands include WiMAX, INSAT, and lower and upper WLAN. In order to estimate the frequency shifts of the notch due to the coupling of the nearby CSRRs, an analysis of the coupling among the multiple notch resonators is carried out and we construct the lumped-circuit equivalent model. The time domain analysis of the proposed antenna is performed to show its validity on the UWB application. The measured frequency response of the input port corresponds quite well with the calculations and simulations. The radiation pattern of the implemented quad-notched UWB antenna is nearly omnidirectional in the passband.

A Compact Multiple Notched Ultra-Wide Band Antenna with an Analysis of the CSRR-TO-CSRR Coupling for Portable UWB Applications

PubMed Central

Ko, Dong-Sik

2017-01-01

We present a compact ultra-wideband (UWB) antenna integrated with sharp notches with a detailed analysis of the mutual coupling of the multiple notch resonators. By utilizing complementary split ring resonators (CSRR) on the radiating semi-circular patch, we achieve the sharp notch-filtering of various bands within the UWB band without increasing the antenna size. The notched frequency bands include WiMAX, INSAT, and lower and upper WLAN. In order to estimate the frequency shifts of the notch due to the coupling of the nearby CSRRs, an analysis of the coupling among the multiple notch resonators is carried out and we construct the lumped-circuit equivalent model. The time domain analysis of the proposed antenna is performed to show its validity on the UWB application. The measured frequency response of the input port corresponds quite well with the calculations and simulations. The radiation pattern of the implemented quad-notched UWB antenna is nearly omnidirectional in the passband. PMID:28946658

Using spectral information in forensic imaging.

PubMed

Miskelly, Gordon M; Wagner, John H

2005-12-20

Improved detection of forensic evidence by combining narrow band photographic images taken at a range of wavelengths is dependent on the substance of interest having a significantly different spectrum from the underlying substrate. While some natural substances such as blood have distinctive spectral features which are readily distinguished from common colorants, this is not true for visualization agents commonly used in forensic science. We now show that it is possible to select reagents with narrow spectral features that lead to increased visibility using digital cameras and computer image enhancement programs even if their coloration is much less intense to the unaided eye than traditional reagents. The concept is illustrated by visualising latent fingermarks on paper with the zinc complex of Ruhemann's Purple, cyanoacrylate-fumed fingerprints with Eu(tta)(3)(phen), and soil prints with 2,6-bis(benzimidazol-2-yl)-4-[4'-(dimethylamino)phenyl]pyridine [BBIDMAPP]. In each case background correction is performed at one or two wavelengths bracketing the narrow absorption or emission band of these compounds. However, compounds with sharp spectral features would also lead to improved detection using more advanced algorithms such as principal component analysis.

Nanocomposite synthesis and photoluminescence properties of MeV Au-ion beam modified Ni thin films

NASA Astrophysics Data System (ADS)

Siva, Vantari; Datta, Debi P.; Singh, Avanendra; Som, T.; Sahoo, Pratap K.

2016-01-01

We report on the synthesis and properties of nano-composites from thin Ni films on Silica matrix using Au-ion beam. When 2.2 MeV Au-ions are irradiated on 5 nm Ni film on Silica, the surface morphology changes drastically with ion fluence. In fact, within a fluence range of 5 × 1014-1 × 1016 ions/cm2, a sharp increase in surface roughness follows after an initial surface smoothening. The depth profiles extracted from Rutherford backscattering spectra demonstrates the diffusion of Ni and Au into the silica matrix. The photoluminescence spectra of the irradiated samples reveal the development of two bands centered at 3.3 eV and 2.66 eV, respectively. Deconvolution of those bands shows five different emission peaks, corresponding to different luminescence centers, which confirms the existence of Ni-Au nanocomposites in silica matrix. The optical and structural modifications are understood in terms of ion induced local heating and mass transport due to thermal spikes, which leads to nanocomposite formation in silica.

Rings of Molecular Line Emission in the Disk Orbiting the Young, Close Binary V4046 Sgr

NASA Astrophysics Data System (ADS)

Dickson-Vandervelde, Dorothy; Kastner, Joel H.; Qi, C.; Forveille, Thierry; Hily-Blant, Pierre; Oberg, Karin; Wilner, David; Andrews, Sean; Gorti, Uma; Rapson, Valerie; Sacco, Germano; Principe, David

2018-01-01

We present analysis of a suite of subarcsecond ALMA Band 6 (1.1 - 1.4 mm) molecular line images of the circumbinary, protoplanetary disk orbiting V4046 Sgr. The ~20 Myr-old V4046 Sgr system, which lies a mere ~73 pc from Earth, consists of a close (separation ~10 Rsun) pair of roughly solar-mass stars that are orbited by a gas-rich crcumbinary disk extending to ~350 AU in radius. The ALMA images reveal that the molecules CO and HCN and their isotopologues display centrally peaked surface brightness morphologies, whereas the cyanide group molecules (HC3N, CH3CN), deuterated molecules (DCN, DCO+), hydrocarbons (as traced by C2H), and potential CO ice line tracers (N2H+, and H2CO) appear as a sequence of sharp and diffuse rings of increasing radii. The characteristic sizes of these molecular emission rings, which range from ~25 to >100 AU in radius, are evident in radial emission-line surface brightness profiles extracted from the deprojected disk images. We find that emission from 13CO emission transitions from optically thin to thick within ~50 AU, whereas C18O emission remains optically thin within this radius. We summarize the insight into the physical and chemical processes within this evolved protoplanetary disk that can be obtained from comparisons of the various emission-line morphologies with each other and with that of the continuum (large-grain) emission on size scales of tens of AU.This research is supported by NASA Exoplanets program grant NNX16AB43G to RIT

Toward a better understanding of the GRB phenomenon: a new model for GRB prompt emission and its effects on the new L i NT$-$E peak,i rest,NT relation

DOE PAGES

Guiriec, S.; Kouveliotou, C.; Daigne, F.; ...

2015-07-09

Gamma-ray burst (GRB) prompt emission spectra in the keV–MeV energy range are usually considered to be adequately fitted with the empirical Band function. Recent observations with the Fermi Gamma-ray Space Telescope (Fermi) revealed deviations from the Band function, sometimes in the form of an additional blackbody (BB) component, while on other occasions in the form of an additional power law (PL) component extending to high energies. Here in this article we investigate the possibility that the three components may be present simultaneously in the prompt emission spectra of two very bright GRBs (080916C and 090926A) observed with Fermi, and how the three components may affect the overall shape of the spectra. While the two GRBs are very different when fitted to a single Band function, they look like "twins" in the three-component scenario. Through fine-time spectroscopy down to the 100 ms timescale, we follow the evolution of the various components. We succeed in reducing the number of free parameters in the three-component model, which results in a new semi-empirical model—but with physical motivations—to be competitive with the Band function in terms of number of degrees of freedom. From this analysis using multiple components, the Band function is globally the most intense component, although the additional PL can overpower the others in sharp time structures. The Band function and the BB component are the most intense at early times and globally fade across the burst duration. The additional PL is the most intense component at late time and may be correlated with the extended high-energy emission observed thousands of seconds after the burst with Fermi/Large Area Telescope. Unexpectedly, this analysis also shows that the additional PL may be present from the very beginning of the burst, where it may even overpower the other components at low energy. We investigate the effect of the three components on the new time-resolved luminosity–hardness relation in both the observer and rest frames and show that a strong correlation exists between the flux of the non-thermal Band function and its E peak only when the three components are fitted simultaneously to the data (i.e.,more » $${F}_{i}^{\\mathrm{NT}}$$–$${E}_{\\mathrm{peak},i}^{\\mathrm{NT}}$$ relation). In addition, this result points toward a universal relation between those two quantities when transposed to the central engine rest frame for all GRBs (i.e., $${L}_{i}^{\\mathrm{NT}}$$–$${E}_{\\mathrm{peak},i}^{\\mathrm{rest},\\mathrm{NT}}$$ relation). We discuss a possible theoretical interpretation of the three spectral components within this new empirical model. Lastly, we suggest that (i) the BB component may be interpreted as the photosphere emission of a magnetized relativistic outflow, (ii) the Band component has synchrotron radiation in an optically thin region above the photosphere, either from internal shocks or magnetic field dissipation, and (iii) the extra PL component extending to high energies likely has an inverse Compton origin of some sort, even though its extension to a much lower energy remains a mystery.« less

Spectral properties of Ca-sulfates: Gypsum, bassanite, and anhydrite

USGS Publications Warehouse

Bishop, Janice L.; Lane, Melissa D.; Dyar, M. Darby; King, Sara J.; Brown, Adrian J.; Swayze, Gregg A.

2014-01-01

This study of the spectral properties of Ca-sulfates was initiated to support remote detection of these minerals on Mars. Gypsum, bassanite, and anhydrite are the currently known forms of Ca-sulfates. They are typically found in sedimentary evaporites on Earth, but can also form via reaction of acidic fluids associated with volcanic activity. Reflectance, emission, transmittance, and Raman spectra are discussed here for various sample forms. Gypsum and bassanite spectra exhibit characteristic and distinct triplet bands near 1.4–1.5 μm, a strong band near 1.93–1.94 μm, and multiple features near 2.1–2.3 μm attributed to H2O. Anhydrite, bassanite, and gypsum all have SO4 combination and overtone features from 4.2–5 μm that are present in reflectance spectra. The mid-IR region spectra exhibit strong SO4 ν3 and ν4 vibrational bands near 1150–1200 and 600–680 cm−1 (~8.5 and 16 μm), respectively. Additional weaker features are observed near 1005–1015 cm−1 (~10 μm) for ν1 and near 470–510 cm−1 (~20 μm) for ν2. The mid-IR H2O bending vibration occurs near 1623–1630 cm−1 (~6.2 μm). The visible/near-infrared region spectra are brighter for the finer-grained samples. In reflectance and emission spectra of the mid-IR region the ν4 bands begin to invert for the finer-grained samples, and the ν1 vibration occurs as a band instead of a peak and has the strongest intensity for the finer-grained samples. The ν2 vibration is a sharp band for anhydrite and a broad peak for gypsum. The band center of the ν1 vibration follows a trend of decreasing frequency (increasing wavelength) with increasing hydration of the sample in the transmittance, Raman, and reflectance spectra. Anhydrite forms at elevated temperatures compared to gypsum, and at lower temperature, salt concentration, and pH than bassanite. The relative humidity controls whether bassanite or gypsum is stable. Thus, distinguishing among gypsum, bassanite, and anhydrite via remote sensing can provide constraints on the geochemical environment.

Overview of the SHARP campaign: Motivation, design, and major outcomes

NASA Astrophysics Data System (ADS)

Olaguer, Eduardo P.; Kolb, Charles E.; Lefer, Barry; Rappenglück, Bernhard; Zhang, Renyi; Pinto, Joseph P.

2014-03-01

The Study of Houston Atmospheric Radical Precursors (SHARP) was a field campaign developed by the Houston Advanced Research Center on behalf of the Texas Environmental Research Consortium. SHARP capitalized on previous research associated with the Second Texas Air Quality Study and the development of the State Implementation Plan (SIP) for the Houston-Galveston-Brazoria (HGB) ozone nonattainment area. These earlier studies pointed to an apparent deficit in ozone production in the SIP attainment demonstration model despite the enhancement of simulated emissions of highly reactive volatile organic compounds in accordance with the findings of the original Texas Air Quality Study in 2000. The scientific hypothesis underlying the SHARP campaign was that there are significant undercounted primary and secondary sources of the radical precursors, formaldehyde, and nitrous acid, in both heavily industrialized and more typical urban areas of Houston. These sources, if properly taken into account, could increase the production of ozone in the SIP model and the simulated efficacy of control strategies designed to bring the HGB area into ozone attainment. This overview summarizes the precursor studies and motivations behind SHARP, as well as the overall experimental design and major findings of the 2009 field campaign. These findings include significant combustion sources of formaldehyde at levels greater than accounted for in current point source emission inventories; the underestimation of formaldehyde and nitrous acid emissions, as well as CO/NOx and NO2/NOx ratios, by mobile source models; and the enhancement of nitrous acid by atmospheric organic aerosol.

Characterization of external potential for field emission resonances and its applications on nanometer-scale measurements

NASA Astrophysics Data System (ADS)

Lu, Shin-Ming; Chan, Wen-Yuan; Su, Wei-Bin; Pai, Woei Wu; Liu, Hsiang-Lin; Chang, Chia-Seng

2018-04-01

The form of the external potential (FEP) for generating field emission resonance (FER) in a scanning tunneling microscopy (STM) junction is usually assumed to be triangular. We demonstrate that this assumption can be examined using a plot that can characterize FEP. The plot is FER energies versus the corresponding distances between the tip and sample. Through this energy–distance relationship, we discover that the FEP is nearly triangular for a blunt STM tip. However, the assumption of a triangular potential form is invalid for a sharp tip. The disparity becomes more severe as the tip is sharper. We demonstrate that the energy–distance plot can be exploited to determine the barrier width in field emission and estimate the effective sharpness of an STM tip. Because FERs were observed on Pb islands grown on the Cu(111) surface in this study, determination of the tip sharpness enabled the derivation of the subtle expansion deformation of Pb islands due to electrostatic force in the STM junction.

Mid-infrared interferometry towards the massive young stellar object CRL 2136: inside the dust rim

NASA Astrophysics Data System (ADS)

de Wit, W. J.; Hoare, M. G.; Oudmaijer, R. D.; Nürnberger, D. E. A.; Wheelwright, H. E.; Lumsden, S. L.

2011-02-01

Context. Establishing the importance of circumstellar disks and their properties is crucial to fully understand massive star formation. Aims: We aim to spatially resolve the various components that make-up the accretion environment of a massive young stellar object (⪉100 AU), and reproduce the emission from near-infrared to millimeter wavelengths using radiative transfer codes. Methods: We apply mid-infrared spectro-interferometry to the massive young stellar object CRL 2136. The observations were performed with the Very Large Telescope Interferometer and the MIDI instrument at a 42 m baseline probing angular scales of 50 milli-arcseconds. We model the observed visibilities in parallel with diffraction-limited images at both 24.5 μm and in the N-band (with resolutions of 0.6´´and 0.3´´, respectively), as well as the spectral energy distribution. Results: The arcsec-scale spatial information reveals the well-resolved emission from the dusty envelope. By simultaneously modelling the spatial and spectral data, we find that the bulk of the dust emission occurs at several dust sublimation radii (approximately 170 AU). This reproduces the high mid-infrared fluxes and at the same time the low visibilities observed in the MIDI data for wavelengths longward of 8.5 μm. However, shortward of this wavelength the visibility data show a sharp up-turn indicative of compact emission. We discuss various potential sources of this emission. We exclude a dust disk being responsible for the observed spectral imprint on the visibilities. A cool supergiant star and an accretion disk are considered and both shown to be viable origins of the compact mid-infrared emission. Conclusions: We propose that CRL 2136 is embedded in a dusty envelope, which truncates at several times the dust sublimation radius. A dust torus is manifest in the equatorial region. We find that the spectro-interferometric N-band signal can be reproduced by either a gaseous disk or a bloated central star. If the disk extends to the stellar surface, it accretes at a rate of 3.0 × 10-3 M⊙ yr-1. Based on observations with the VLTI, proposal 381.C-0607.

Sub-bandgap Voltage Electroluminescence and Magneto-oscillations in a WSe2 Light-Emitting van der Waals Heterostructure.

PubMed

Binder, Johannes; Withers, Freddie; Molas, Maciej R; Faugeras, Clement; Nogajewski, Karol; Watanabe, Kenji; Taniguchi, Takashi; Kozikov, Aleksey; Geim, Andre K; Novoselov, Kostya S; Potemski, Marek

2017-03-08

We report on experimental investigations of an electrically driven WSe 2 based light-emitting van der Waals heterostructure. We observe a threshold voltage for electroluminescence significantly lower than the corresponding single particle band gap of monolayer WSe 2 . This observation can be interpreted by considering the Coulomb interaction and a tunneling process involving excitons, well beyond the picture of independent charge carriers. An applied magnetic field reveals pronounced magneto-oscillations in the electroluminescence of the free exciton emission intensity with a 1/B periodicity. This effect is ascribed to a modulation of the tunneling probability resulting from the Landau quantization in the graphene electrodes. A sharp feature in the differential conductance indicates that the Fermi level is pinned and allows for an estimation of the acceptor binding energy.

X-ray absorption spectroscopy and photoluminescence study of rare earth ions doped strontium sulphide phosphors

NASA Astrophysics Data System (ADS)

Vij, Ankush; Gautam, Sanjeev; Kumar, Vinay; Brajpuriya, R.; Kumar, Ravi; Singh, Nafa; Chae, Keun Hwa

2013-01-01

We present here the electronic structure and photoluminescence properties of Sm (0.1-1.0 mol%) doped SrS phosphors. The doping in SrS was probed by near-edge X-ray absorption fine structure (NEXAFS) at M5,4-edges of Sm in total electron yield mode. The simulated absorption edges using atomic multiplet calculations were correlated with experimental results, which clearly reveal the presence of trivalent state of Sm in SrS matrix. However, for Sm (1 mol%), very minor traces of Sm2+ were also observed, which have been explained by comparing the NEXAFS spectra in total electron and florescence yield mode. The PL emission of SrS:Sm comprises of three sharp bands at 567, 602 and 650 nm owing to the well-known intra 4f transitions from 4G5/2 to 6HJ (J = 5/2, 7/2, 9/2) levels of Sm3+ ions in SrS host. The effect of Ce co-doping on SrS:Sm phosphors was also investigated, which exhibits characteristic PL emission of independent ions at their respective excitation wavelengths. However, at an excitation wavelength of 393 nm, SrS:Ce,Sm exhibits the simultaneous characteristic PL emission of both ions spanning into blue-green-red region. The CIE chromaticity coordinates also clearly show the influence of excitation wavelengths on the emission colour of SrS:Ce,Sm.

Vibrational spectroscopy of the silicate mineral plumbotsumite Pb5(OH)10Si4O8 - An assessment of the molecular structure

NASA Astrophysics Data System (ADS)

López, Andrés; Frost, Ray L.; Scholz, Ricardo; Gobac, Željka Žigovečki; Xi, Yunfei

2013-12-01

We have used scanning electron microscopy with energy dispersive X-ray analysis to determine the precise formula of plumbotsumite, a rare lead silicate mineral of formula Pb5(OH)10Si4O8. This study forms the first systematic study of plumbotsumite from the Bigadic deposits, Turkey. Vibrational spectroscopy was used to assess the molecular structure of plumbotsumite as the structure is not known. The mineral is characterized by sharp Raman bands at 1047, 1055 and 1060 cm-1 assigned to SiO stretching vibrational modes and sharp Raman bands at 673, 683 and 697 cm-1 assigned to OSiO bending modes. The observation of multiple bands offers support for a layered structure with variable SiO3 structural units. Little information may be obtained from the infrared spectra because of broad spectral profiles. Intense Raman bands at 3510, 3546 and 3620 cm-1 are ascribed to OH stretching modes. Evidence for the presence of water in the plumbotsumite structure was inferred from the infrared spectra.

ON THE PUZZLING HIGH-ENERGY PULSATIONS OF THE ENERGETIC RADIO-QUIET γ-RAY PULSAR J1813–1246

DOE PAGES

Marelli, M.; Harding, A.; Pizzocaro, D.; ...

2014-10-28

In this study, we have analyzed the new deep XMM-Newton and Chandra observations of the energetic, radio-quiet pulsar J1813–1246. The X-ray spectrum is nonthermal, very hard, and absorbed. Based on spectral considerations, we propose that J1813 is located at a distance further than 2.5 kpc. J1813 is highly pulsed in the X-ray domain, with a light curve characterized by two sharp, asymmetrical peaks, separated by 0.5 in phase. We detected no significant X-ray spectral changes during the pulsar phase. We extended the available Fermi ephemeris to five years. We found two glitches. The γ-ray light curve is characterized by twomore » peaks, separated by 0.5 in phase, with a bridge in between and no off-pulse emission. The spectrum shows clear evolution in phase, being softer at the peaks and hardening toward the bridge. Surprisingly, both X-ray peaks lag behind the γ-ray ones by a quarter of phase. We found a hint of detection in the 30-500 keV band with INTEGRAL, which is consistent with the extrapolation of both the soft X-ray and γ-ray emission of J1813. The unique X-ray and γ-ray phasing suggests a singular emission geometry. We discuss some possibilities within the current pulsar emission models. Finally, we develop an alternative geometrical model where the X-ray emission comes from polar cap pair cascades.« less

On the Puzzling High-Energy Pulsations of the Energetic Radio-Quiet -Ray Pulsar J1813-1246

NASA Technical Reports Server (NTRS)

Marelli, M.; Harding, Alice K.; Pizzocaro, D.; De Luca, A.; Wood, K. S.; Caraveo, P.; Salvetti, D.; Parkinson, P. M.; Acero, F.

2014-01-01

We have analyzed the new deep XMM-Newton and Chandra observations of the energetic, radio-quiet pulsar J1813-1246. The X-ray spectrum is nonthermal, very hard, and absorbed. Based on spectral considerations, we propose that J1813 is located at a distance further than 2.5 kpc. J1813 is highly pulsed in the X-ray domain, with a light curve characterized by two sharp, asymmetrical peaks, separated by 0.5 in phase. We detected no significant X-ray spectral changes during the pulsar phase.We extended the available Fermi ephemeris to five years.We found two glitches. The gamma-ray light curve is characterized by two peaks, separated by 0.5 in phase, with a bridge in between and no off-pulse emission. The spectrum shows clear evolution in phase, being softer at the peaks and hardening toward the bridge. Surprisingly, both X-ray peaks lag behind the gamma-ray ones by a quarter of phase. We found a hint of detection in the 30-500 keV band with INTEGRAL, which is consistent with the extrapolation of both the soft X-ray and gamma-ray emission of J1813. The unique X-ray and gamma-ray phasing suggests a singular emission geometry. We discuss some possibilities within the current pulsar emission models. Finally, we develop an alternative geometrical model where the X-ray emission comes from polar cap pair cascades.

Space charge limited current emission for a sharp tip

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Y. B., E-mail: zhuyingbin@gmail.com; Ang, L. K., E-mail: ricky-ang@sutd.edu.sg

In this paper, we formulate a self-consistent model to study the space charge limited current emission from a sharp tip in a dc gap. The tip is assumed to have a radius in the order of 10s nanometer. The electrons are emitted from the tip due to field emission process. It is found that the localized current density J at the apex of the tip can be much higher than the classical Child Langmuir law (flat surface). A scaling of J ∝ V{sub g}{sup 3/2}/D{sup m}, where V{sub g} is the gap bias, D is the gap size, and m = 1.1–1.2more » (depending on the emission area or radius) is proposed. The effects of non-uniform emission and the spatial dependence of work function are presented.« less

Controlling Blue and Red Light Emissions from Europium (Eu2+)/Manganese (Mn2+)-Codoped Beta-Tricalcium Phosphate [β-Ca3(PO4)2 (TCP)] Phosphors

NASA Astrophysics Data System (ADS)

Van, Hoang Nhu; Hoan, Bui Thi; Nguyen, Khoi Thi; Tam, Phuong Dinh; Huy, Pham Thanh; Pham, Vuong-Hung

2018-03-01

Tunable light emission from europium (Eu2+)/manganese (Mn2+)-codoped beta-tricalcium phosphate [β-Ca3(PO4)2 (TCP)] has been investigated as a function of the Mn2+ and Eu2+ concentrations and annealing temperature. Eu2+/Mn2+-doped TCP phosphor (Eu/Mn-TCP) was synthesized by coprecipitation method followed by thermal annealing at temperature up to 1100°C. The Eu2+/Mn2+-doped TCP particles have diameter of about 1 μm. The light emission from TCP is enhanced in the sample with 7.5 mol.% Mn2+ and 0.3 mol.% Eu2+ annealed in Ar + 5% H2 atmosphere at 1100°C. The blue band at 430 nm is attributed to the 4f 6 5d 1-4f 7 transition of Eu2+. The sharp peak at 660 nm is ascribed to the 4T1-6A1 transition of Mn2+ in TCP. These results suggest codoping of Eu2+/Mn2+ to TCP phosphor to obtain β-Ca3(PO4)2:Eu2+,Mn2+ phosphors with tunable luminescence, having potential applications in agricultural lighting.

The design and synthesis of heterostructured quantum dots with dual emission in the visible and infrared

DOE PAGES

Lin, Qianglu; Makarov, Nikolay S.; Koh, Weon-kyu; ...

2014-11-26

The unique optical properties exhibited by visible emitting core/shell quantum dots with especially thick shells are the focus of widespread study, but have yet to be realized in infrared (IR) -active nanostructures. We apply an effective-mass model to identify PbSe/CdSe core/shell quantum dots as a promising system for achieving this goal. We then synthesize colloidal PbSe/CdSe quantum dots with shell thicknesses of up to 4 nm that exhibit unusually slow hole intra-band relaxation from shell to core states, as evidenced by the emergence of dual emission, i.e., IR photoluminescence from the PbSe core observed simultaneously with visible emission from themore » CdSe shell. In addition to the large shell thickness, the development of slowed intraband relaxation is facilitated by the existence of a sharp core-shell interface without discernible alloying. Growth of thick shells without interfacial alloying or incidental formation of homogenous CdSe nanocrystals was accomplished using insights attained via a systematic study of the dynamics of the cation-exchange synthesis of both PbSe/CdSe as well as the related system PbS/CdS. Finally, we show that the efficiency of the visible photoluminescence can be greatly enhanced by inorganic passivation.« less

The Intersection of CMOS Microsystems and Upconversion Nanoparticles for Luminescence Bioimaging and Bioassays

PubMed Central

Wei, Liping.; Doughan, Samer.; Han, Yi.; DaCosta, Matthew V.; Krull, Ulrich J.; Ho, Derek.

2014-01-01

Organic fluorophores and quantum dots are ubiquitous as contrast agents for bio-imaging and as labels in bioassays to enable the detection of biological targets and processes. Upconversion nanoparticles (UCNPs) offer a different set of opportunities as labels in bioassays and for bioimaging. UCNPs are excited at near-infrared (NIR) wavelengths where biological molecules are optically transparent, and their luminesce in the visible and ultraviolet (UV) wavelength range is suitable for detection using complementary metal-oxide-semiconductor (CMOS) technology. These nanoparticles provide multiple sharp emission bands, long lifetimes, tunable emission, high photostability, and low cytotoxicity, which render them particularly useful for bio-imaging applications and multiplexed bioassays. This paper surveys several key concepts surrounding upconversion nanoparticles and the systems that detect and process the corresponding luminescence signals. The principle of photon upconversion, tuning of emission wavelengths, UCNP bioassays, and UCNP time-resolved techniques are described. Electronic readout systems for signal detection and processing suitable for UCNP luminescence using CMOS technology are discussed. This includes recent progress in miniaturized detectors, integrated spectral sensing, and high-precision time-domain circuits. Emphasis is placed on the physical attributes of UCNPs that map strongly to the technical features that CMOS devices excel in delivering, exploring the interoperability between the two technologies. PMID:25211198

CHARACTERIZATION AND REDUCTION OF FORMALDEHYDE EMISSIONS FROM A LOW-VOC LATEX PAINT

EPA Science Inventory

The paper discusses the measurment and analysis of the patterns of formaldehyde emission from a low volatile organic compound (VOC) latex paint applied to gypsum board, using small environmental chamber tests. The formaldehyde emissions resulted in sharp increase of chamber air...

Temperature Dependence of Wavelength Selectable Zero-Phonon Emission from Single Defects in Hexagonal Boron Nitride.

PubMed

Jungwirth, Nicholas R; Calderon, Brian; Ji, Yanxin; Spencer, Michael G; Flatté, Michael E; Fuchs, Gregory D

2016-10-12

We investigate the distribution and temperature-dependent optical properties of sharp, zero-phonon emission from defect-based single photon sources in multilayer hexagonal boron nitride (h-BN) flakes. We observe sharp emission lines from optically active defects distributed across an energy range that exceeds 500 meV. Spectrally resolved photon-correlation measurements verify single photon emission, even when multiple emission lines are simultaneously excited within the same h-BN flake. We also present a detailed study of the temperature-dependent line width, spectral energy shift, and intensity for two different zero-phonon lines centered at 575 and 682 nm, which reveals a nearly identical temperature dependence despite a large difference in transition energy. Our temperature-dependent results are well described by a lattice vibration model that considers piezoelectric coupling to in-plane phonons. Finally, polarization spectroscopy measurements suggest that whereas the 575 nm emission line is directly excited by 532 nm excitation, the 682 nm line is excited indirectly.

Curiosity Rover on Mount Sharp, Seen from Mars Orbit

NASA Image and Video Library

2017-06-20

The feature that appears bright blue at the center of this scene is NASA's Curiosity Mars rover on the northwestern flank of Mount Sharp, viewed by NASA's Mars Reconnaissance Orbiter. Curiosity is approximately 10 feet long and 9 feet wide (3.0 meters by 2.8 meters). The view is a cutout from observation ESP_050897_1750 taken by the High Resolution Imaging Science Experiment (HiRISE) camera on the orbiter on June 5, 2017. HiRISE has been imaging Curiosity about every three months, to monitor the surrounding features for changes such as dune migration or erosion. When the image was taken, Curiosity was partway between its investigation of active sand dunes lower on Mount Sharp, and "Vera Rubin Ridge," a destination uphill where the rover team intends to examine outcrops where hematite has been identified from Mars orbit. The rover's surroundings include tan rocks and patches of dark sand. As in previous HiRISE color images of Curiosity since the rover was at its landing site, the rover appears bluer than it really is. HiRISE color observations are recorded in a red band, a blue-green band and an infrared band, and displayed in red, green and blue. This helps make differences in Mars surface materials apparent, but does not show natural color as seen by the human eye. Lower Mount Sharp was chosen as a destination for the Curiosity mission because the layers of the mountain offer exposures of rocks that record environmental conditions from different times in the early history of the Red Planet. Curiosity has found evidence for ancient wet environments that offered conditions favorable for microbial life, if Mars has ever hosted life. https://photojournal.jpl.nasa.gov/catalog/PIA21710

Uncertainty relations and topological-band insulator transitions in 2D gapped Dirac materials

NASA Astrophysics Data System (ADS)

Romera, E.; Calixto, M.

2015-05-01

Uncertainty relations are studied for a characterization of topological-band insulator transitions in 2D gapped Dirac materials isostructural with graphene. We show that the relative or Kullback-Leibler entropy in position and momentum spaces, and the standard variance-based uncertainty relation give sharp signatures of topological phase transitions in these systems.

CHARACTERIZATION AND REDUCTION OF FORMALDEHYDE EMISSIONS FROM A LOW-VOC LATEX PAINT

EPA Science Inventory

The patterns of formaldehyde emission from a low volatile organic compound (VOC) latex paint applied to gypsum board were measured and analyzed by small environmental chamber tests. It was found that the formaldehyde emissions resulted in sharp increase of chamber air formaldehy...

Ultrafast Carrier dynamics of InxGa1-xN nanostructures grown directly on Si(111)

NASA Astrophysics Data System (ADS)

Kumar, Praveen; Devi, Pooja; Rodriguez⁠, P. E. D. S.; Kumar, Manish; Shivling, V. D.; Noetzel, Richard; Sharma, Chhavi; Sinha, R. K.; Kumar, Mahesh

2018-05-01

We show a flux dependence changes in structural, optical and electronic properties of InxGa1-xN nanostructures (NSs) namely nanocolumns (NCs), nanoflakes (NFs) and nanowall network (NWN) grown directly on Si(111) surface. Field emission scanning electron microscopy (FESEM) images were recorded to see morphological changes from NFs to NCs and NWNc etc, while high-resolution X-ray diffraction (HRXRD) ω-2θ scans were used to determine In incorporation. The maximum In incorporation was observed to be 20, 33 and 38% for the sharp transition from NFs to NCs and NWNs, respectively. The charge carrier dynamics of these grown NSs were probed using Ultrafast Femtosecond Transient Absorption Spectroscopy (UFTAS) with excitation at 350 nm pump wavelength. The UFTAS studies show the comparative charge carriers dynamics of the NWS, NCs and NFs. The charge carrier studies show a higher lifetime in NWNs as compare to NCs and NFs. Further, to examine electronic structure and level of degeneracy of these NSs, core-level and valence band spectra were analyzed by X-ray photoelectron spectroscopy (XPS), which manifest the upward band bending ranging from 0.2 eV to 0.4 eV.

Low Temperature Photoluminescence of PVT Grown ZnSe and ZnSeTe

NASA Technical Reports Server (NTRS)

Wang, Ling Jun; Su, Ching-Hua; Lehoczky, S. L.

1999-01-01

ZnSe and ZnSeTe single crystals were grown by physical vapor transport (PVT) technique horizontally and vertically. The grown ZnSe and ZnSeTe single crystals were characterized by low temperature photoluminescence at 5 to 10 K using the 3.4 eV emission of an argon laser. The intensity of the sharp near band edge defect lines at 2.799, 2.783 eV and the intrinsic free exciton line at 2.802 eV were mapped on various crystal surfaces with different orientations to the gravitational field. The results show the effects of gravity vector orientation on the defect segregation. Comparison of the photoluminescence spectra of the ZeSe crystal before and after annealing in the Zn vapor shows that the 2.783 eV line of ZnSe crystal is related to the zinc vacancy. The photoluminescence spectra of the ternary ZnSeTe crystal were characterized by a single broad band from 2.2 to 2.4 eV, with a Full Width at Half Maximum (FWHM) of about 100 meV. The temperature dependence of the peak position and intensity were determined from 7 to 150 K.

Occurrence features of simultaneous H+- and He+-band EMIC emissions in the outer radiation belt

NASA Astrophysics Data System (ADS)

Fu, Song; He, Fengming; Gu, Xudong; Ni, Binbin; Xiang, Zheng; Liu, Jiang

2018-04-01

As an important loss mechanism of radiation belt electrons, electromagnetic ion cyclotron (EMIC) waves show up as three distinct frequency bands below the hydrogen (H+), helium (He+), and oxygen (O+) ion gyrofrequencies. Compared to O+-band EMIC waves, H+- and He+-band emissions generally occur more frequently and result in more efficient scattering removal of <∼5 MeV relativistic electrons. Therefore, knowledge about the occurrence of these two bands is important for understanding the evolution of the relativistic electron population. To evaluate the occurrence pattern and wave properties of H+- and He+-band EMIC waves when they occur concurrently, we investigate 64 events of multi-band EMIC emissions identified from high quality Van Allen Probes wave data. Our quantitative results demonstrate a strong occurrence dependence of the multi-band EMIC emissions on magnetic local time (MLT) and L-shell to mainly concentrate on the dayside region of L = ∼4-6. We also find that the average magnetic field amplitude of H+-band waves is larger than that of He+-band waves only when L < 4.5 and AE∗ < 300 nT, and He+-band emissions are more intense under all other conditions. In contrast to 5 events that have average H+-band amplitude over 2 nT, 19 events exhibit >2 nT He+-band amplitude, indicating that the He+-band waves can be more easily amplified than the H+-band waves under the same circumstances. For simultaneous occurrences of the two EMIC wave bands, their frequencies vary with L-shell and geomagnetic activity: the peak wave frequency of H+-band emissions varies between 0.25 and 0.8 fcp with the average between 0.25 and 0.6 fcp, while that of He+-band emissions varies between 0.03 and 0.23 fcp with the average between 0.05 and 0.15 fcp. These newly observed occurrence features of simultaneous H+- and He+-band EMIC emissions provide improved information to quantify the overall contribution of multi-band EMIC waves to the loss processes of radiation belt electrons.

Highly Luminescent Zn(x)Cd(1-x)Se/C Core/Shell Nanocrystals: Large Scale Synthesis, Structural and Cathodoluminescence Studies.

PubMed

Bhattacharyya, Sayan; Estrin, Yevgeni; Moshe, Ofer; Rich, Daniel H; Solovyov, Leonid A; Gedanken, A

2009-07-28

Zn(x)Cd(1-x)Se/C core/shell nanocrystals with 31-39 nm semiconducting core and 11-25 nm carbon shell were synthesized from solid state precursors in large scale amounts. A mixture of spherical and tripod nanostructures were obtained only in the one-step reaction (ZC3), where the Zn- and Cd-precursors were reacted simultaneously, rather than in the two step reactions (ZC1 and ZC2), where largely spherical nanostructures were observed. Rietveld analysis of the X-ray diffraction patterns of the samples prepared in three different ways, all under their autogenic pressure, reveal varying compositions of the Zn(x)Cd(1-x)Se nanocrystal core, where the cubic phases with higher Zn content were dominant compared to the hexagonal phases. Carbon encapsulation offers excellent protection to the nanocrystal core and is an added advantage for biological applications. Cathodoluminescence (CL) measurements with spatially integrated and highly localized excitations show distinct peaks and sharp lines at various wavelengths, representing emissions from single nanostructures possessing different compositions, phases, and sizes. Transmission electron microscopy (TEM) showed striations in the nanocrystals that are indicative of a composition modulation, and possibly reveal a phase separation and spinodal decomposition within the nanocrystals. Thermal quenching of the luminescence for both the near band-edge and defect related emissions were observed in the range 60-300 K. The measured activation energies of ∼50-70 meV were related to the presence of shallow donors or acceptors, deep level emissions, and thermal activation and quenching of the luminescence due to the thermal release of electrons from shallow donors to the conduction band or a thermal release of holes from shallow acceptors to the valence band. Spatially integrated CL spectra revealed the existence of broadening and additional components that are consistent with the presence of a composition modulation in the nanocrystals. Spatial localization of the emission in isolated single nanocrystals was studied using monochromatic CL imaging and local CL spectroscopy. CL spectra acquired by a highly localized excitation of individual nanocrystals showed energy shifts in the excitonic luminescence that are consistent with a phase separation into Zn- and Cd-rich regions. The simultaneous appearance of both structural and compositional phase separation for the synthesis of Zn(x)Cd(1-x)Se nanocrystals reveals the complexity and uniqueness of these results.

On the Mechanism of Boron Ignition

NASA Technical Reports Server (NTRS)

Keil, D. G.; Dreizin, E. L.; Felder, W.; Vicenzi, E. P.

1997-01-01

Boron filaments were electrically heated in air and argon/oxygen mixtures while their resistance, temperature, and radiation at the wavelengths of BO and BO2 bands were monitored. The filaments 'burned' in two distinct stages. Samples of the filaments were quenched at different times before and during the burning and analyzed using electron microscopy. The beginning of the first stage combustion characterized by a local resistance minimum, a sharp spike in boron oxide radiation emission, and a rapid rise in temperature, occurred at 1500 +/- 70 deg. C, independent of pre-heating history and oxygen content (540%) in the gas environment. The data suggest that a phase transition occurs in the filaments at this temperature that triggers stage one combustion. Significant amounts of oxygen were found inside quenched filaments. Large spherical voids formed in the boron filaments during their second stage combustion which is interpreted to indicate a crucial role for the gas dissolution processes in the combustion scenario.

New fluorescent symmetrically substituted perylene-3,4,9,10-dianhydride-azohybrid dyes: Synthesis and spectroscopic studies

NASA Astrophysics Data System (ADS)

Saeed, Aamer; Shabir, Ghulam

2014-12-01

Five phenolic azo-dyes (3a-e) were synthesized by diazo coupling of the suitably substituted anilines (1a-e) with phenol at low temperature in alkaline medium. The resulting dyes have low solubility in aqueous medium due to lack of carboxylic or sulfonic solubilizing functionalities. The hybridization of perylene dianhydride with phenolic azo-dyes was achieved by the nucleophilic aromatic substitution (SNAr) reaction of perylene-3,4,9,10-dianhydride 4 with phenolic azo-dyes 3a-e in basic medium. The hybrid dyes exhibit absorption maxima λmax in the range 440-460 nm in aqueous medium due to presence of azo linkage and highly conjugated system of π bonds. Fluorescence spectra of these dyes in water show sharp emission peaks with small band widths. The structures of perylene-azo dyes were confirmed by FTIR and NMR spectroscopy.

47 CFR 90.1323 - Emission limits.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 47 Telecommunication 5 2010-10-01 2010-10-01 false Emission limits. 90.1323 Section 90.1323... MOBILE RADIO SERVICES Wireless Broadband Services in the 3650-3700 MHz Band § 90.1323 Emission limits. (a) The power of any emission outside a licensee's frequency band(s) of operation shall be attenuated...

Observations of copolar correlation coefficient through a bright band at vertical incidence

NASA Technical Reports Server (NTRS)

Zrnic, D. S.; Raghavan, R.; Chandrasekar, V.

1994-01-01

This paper discusses an application of polarimetric measurements at vertical incidence. In particular, the correlation coefficients between linear copolar components are examined, and measurements obtained with the National Severe Storms Laboratory (NSSL)'s and National Center for Atmospheric Research (NCAR)'s polarimetric radars are presented. The data are from two well-defined bright bands. A sharp decrease of the correlation coefficient, confined to a height interval of a few hundred meters, marks the bottom of the bright band.

Field emission and photoluminescence characteristics of ZnS nanowires via vapor phase growth

NASA Astrophysics Data System (ADS)

Chang, Yongqin; Wang, Mingwei; Chen, Xihong; Ni, Saili; Qiang, Weijing

2007-05-01

Large-area ZnS nanowires were synthesized through a vapor phase deposition method. X-ray diffraction and electron microscopy results show that the products are composed of single crystalline ZnS nanowires with a cubic structure. The nanowires have sharp tips and are distributed uniformly on silicon substrates. The diameter of the bases is in the range of 320-530 nm and that of the tips is around 20-30 nm. The strong ultraviolet emission in the photoluminescence spectra also demonstrates that the ZnS nanowires are of high crystalline perfection. Field emission measurements reveal that the ZnS nanowires have a fairly low threshold field, which may be ascribed to their very sharp tips, rough surfaces and high crystal quality. The perfect field emission ability of the ZnS nanowires makes them a promising candidate for the fabrication of flexible cold cathodes.

Using a sharp metal tip to control the polarization and direction of emission from a quantum dot.

PubMed

Ghimire, Anil; Shafran, Eyal; Gerton, Jordan M

2014-09-24

Optical antennas can be used to manipulate the direction and polarization of radiation from an emitter. Usually, these metallic nanostructures utilize localized plasmon resonances to generate highly directional and strongly polarized emission, which is determined predominantly by the antenna geometry alone, and is thus not easily tuned. Here we show experimentally that the emission polarization can be manipulated using a simple, nonresonant scanning probe consisting of the sharp metallic tip of an atomic force microscope; finite element simulations reveal that the emission simultaneously becomes highly directional. Together, the measurements and simulations demonstrate that interference between light emitted directly into the far field with that elastically scattered from the tip apex in the near field is responsible for this control over polarization and directionality. Due to the relatively weak emitter-tip coupling, the tip must be positioned very precisely near the emitter, but this weak coupling also leads to highly tunable emission properties with a similar degree of polarization and directionality compared to resonant antennas.

Surface-Wave Pulse Routing around Sharp Right Angles

NASA Astrophysics Data System (ADS)

Gao, Z.; Xu, H.; Gao, F.; Zhang, Y.; Luo, Y.; Zhang, B.

2018-04-01

Surface-plasmon polaritons (SPPs), or localized electromagnetic surface waves propagating on a metal-dielectric interface, are deemed promising information carriers for future subwavelength terahertz and optical photonic circuitry. However, surface waves fundamentally suffer from scattering loss when encountering sharp corners in routing and interconnection of photonic signals. Previous approaches enabling scattering-free surface-wave guidance around sharp corners are limited to either volumetric waveguide environments or extremely narrow bandwidth, being unable to guide a surface-wave pulse (SPP wave packet) on an on-chip platform. Here, in a surface-wave band-gap crystal implemented on a single metal surface, we demonstrate in time-domain routing a surface-wave pulse around multiple sharp right angles without perceptible scattering. Our work not only offers a solution to on-chip surface-wave pulse routing along an arbitrary path, but it also provides spatiotemporal information on the interplay between surface-wave pulses and sharp corners, both of which are desirable in developing high-performance large-scale integrated photonic circuits.

Room temperature synthesis of ultra-small, near-unity single-sized lead halide perovskite quantum dots with wide color emission tunability, high color purity and high brightness.

PubMed

Peng, Lucheng; Geng, Jing; Ai, Lisha; Zhang, Ying; Xie, Renguo; Yang, Wensheng

2016-08-19

Phosphor with extremely narrow emission line widths, high brightness, and wide color emission tunability in visible regions is required for display and lighting applications, yet none has been reported in the literature so far. In the present study, single-sized lead halide perovskite (APbX 3; A = CH3NH3 and Cs; X = Cl, Br, and I) nanocrystalline (NC) phosphors were achieved for the first time in a one-pot reaction at room temperature (25 °C). The size-dependent samples, which included four families of CsPbBr3 NCs and exhibited sharp excitonic absorption peaks and pure band gap emission, were directly obtained by simply varying the concentration of ligands. The continuity of the optical spectrum can be successively tuned over the entire UV-visible spectral region (360-610 nm) by preparing CsPbCl3, CsPbI3, and CsPb(Y/Br)3 (Y = Cl and I) NCs with the use of CsPbBr3 NCs as templates by anion exchange while maintaining the size of NCs and high quantum yields of up to 80%. Notably, an emission line width of 10-24 nm, which is completely consistent with that of their single particles, indicates the formation of single-sized NCs. The versatility of the synthetic strategy was validated by extending it to the synthesis of single-sized CH3NH3PbX 3 NCs by simply replacing the cesium precursor by the CH3NH3 X precursor.

Characterization and luminescence properties of Sr3Gd): Sm3+ orange-red phosphor

NASA Astrophysics Data System (ADS)

Yang, Zaifa; Xu, Denghui; Sun, Jiayue; Sun, Yumei; Du, Haiyan

2015-10-01

Reddish-orange emitting phosphors, Sr3Gd): Sm3+, were successfully synthesized by a conventional solid-state reaction. The crystal structure of the phosphors was characterized by x-ray diffraction. The excitation spectra and emission spectra were utilized to characterize the luminescence properties of the as-prepared phosphors. The results show that the phosphor consisted of some sharp emission peaks of Sm3+ ions centered at 564, 600, 647, and 707 nm, respectively. The critical distance of Sr3Gd0.93): 0.07Sm3+ was calculated to be 19.18 Å and the lifetime value of the sample was 1.63 ms. The band gap of Sr3Gd) was estimated to be about 2.74 eV from the diffuse reflection spectrum. The optimum doping concentration is 7 mol. % and the quenching occurs via dipole-dipole interaction according to Dexter's theory. The Commission Internationale de L'Eclairage value of Sr3Gd): Sm3+ phosphors presented that it has high color purity. These results indicated that the Sr3Gd): Sm3+ may be a promising reddish-orange emitting phosphor for cost-effective near ultraviolet white light-emitting diodes.

Nitric oxide gamma and delta band emission at twilight

NASA Technical Reports Server (NTRS)

Feldman, P. D.; Takacs, P. Z.

1974-01-01

Nitric oxide twilight emission above 140 km in the gamma- and delta-bands was observed with a rocket-borne spectrophotometer. The relative intensity of the two band systems indicates that the emission is produced predominantly by the chemiluminescent preassociation of oxygen and nitrogen atoms.

EMI survey for maritime satellite, L-band, shipboard terminal

NASA Technical Reports Server (NTRS)

Taylor, R. E.; Brandel, D. L.; Hill, J. S.

1975-01-01

The paper presents results of an onboard EMI survey of an L-band shipboard terminal for operation with two geostationary maritime satellites. Significant EMC results include: (1) antenna noise temperature measurements indicate a maximum of 70 K steady background component at 1.6 GHz at sea for elevation angles of 5 degrees and higher; (2) field intensity measurements from 1-10 GHz show that a L-band terminal can operate simultaneously with onboard S-band and X-band navigation radar; (3) radar transmitter case emissions, below deck, in-band from 1535-1660 MHz, at 1 m distance from the cabinet, are equivalent, or greater than above-deck emissions in the same frequency range; and (4) conducted-emission tests of a ship's power lines to both radars show both narrow band and broad band emissions are 15 dB to 50 dB higher than equivalent U.S. commercial power lines from 150 kHz to 32 MHz.

Techniques to minimize adjacent band emissions from Earth Exploration Satellites to protect the Space Research (Category B) Earth Stations in the 8400-8450 MHz band

NASA Technical Reports Server (NTRS)

Wang, Charles C.; Sue, Miles K.; Manshadi, Farzin

2004-01-01

The Earth Exploration Satellites operating in the 8025-8400 MHz band can have strong adjacent band emissions on the8400-8450 MHz band which is allocated for Space Research (Category-B). The unwanted emission may exceed the protection criterion establish by the ITU-R for the protection of the Space Research (Category B) earth stations, i.e., deep-space earth stations. An SFCG Action Item (SF 23/14) was created during the 23rd SFCG meeting to explore technical and operational techniques to reduce the adjacent band emissions. In response to this action item, a study was conducted and results are presented in this document.

Single photon infrared emission spectroscopy: a study of IR emission from UV laser excited PAHs between 3 and 15 micrometers

NASA Technical Reports Server (NTRS)

Cook, D. J.; Schlemmer, S.; Balucani, N.; Wagner, D. R.; Harrison, J. A.; Steiner, B.; Saykally, R. J.

1998-01-01

Single-photon infrared emission spectroscopy (SPIRES) has been used to measure emission spectra from polycyclic aromatic hydrocarbons (PAHs). A supersonic free-jet expansion has been used to provide emission spectra of rotationally cold and vibrationally excited naphthalene and benzene. Under these conditions, the observed width of the 3.3-micrometers (C-H stretch) band resembles the bandwidths observed in experiments in which emission is observed from naphthalene with higher rotational energy. To obtain complete coverage of IR wavelengths relevant to the unidentified infrared bands (UIRs), UV laser-induced desorption was used to generate gas-phase highly excited PAHs. Lorentzian band shapes were convoluted with the monochromator-slit function in order to determine the widths of PAH emission bands under astrophysically relevant conditions. Bandwidths were also extracted from bands consisting of multiple normal modes blended together. These parameters are grouped according to the functional groups mostly involved in the vibration, and mean bandwidths are obtained. These bandwidths are larger than the widths of the corresponding UIR bands. However, when the comparison is limited to the largest PAHs studied, the bandwidths are slightly smaller than the corresponding UIR bands. These parameters can be used to model emission spectra from PAH cations and cations of larger PAHs, which are better candidate carriers of the UIRs.

Lateral epitaxy of atomically sharp WSe 2/WS 2 heterojunctions on silicon dioxide substrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Jianyi; Zhou, Wu; Tang, Wei

Here, in recent years, 2-D transition-metal dichalcogenides (TMDCs) have received great interests because of the broader possibilities offered by their tunable band gaps, as opposed to gapless graphene which precludes application in digital electronics. TMDCs exhibit an indirect-to-direct band gap transition at the single atomic sheet state as well as optically accessible spin degree of freedom in valleytronics.

Lateral epitaxy of atomically sharp WSe 2/WS 2 heterojunctions on silicon dioxide substrates

DOE PAGES

Chen, Jianyi; Zhou, Wu; Tang, Wei; ...

2016-09-30

Here, in recent years, 2-D transition-metal dichalcogenides (TMDCs) have received great interests because of the broader possibilities offered by their tunable band gaps, as opposed to gapless graphene which precludes application in digital electronics. TMDCs exhibit an indirect-to-direct band gap transition at the single atomic sheet state as well as optically accessible spin degree of freedom in valleytronics.

Spectroscopy Study on the Location and Distribution of Eu3+ Ions in TiO2 Nanoparticles

NASA Astrophysics Data System (ADS)

Tsuboi, Taiju; Setiawati, Elly; Kawano, Katsuyasu

2008-09-01

Eu3+- and non-doped TiO2 nanoparticles were synthesized by the sol-gel method at sintering temperatures of 500 or 900 °C. The photoluminescence spectra of these nanoparticles have been investigated at various temperatures between 290 and 12 K. Two kinds of Eu3+ photoluminescence spectra were observed. One spectrum consists of sharp lines; the other consists of broad bands. The former was obtained by indirect excitation into Eu3+ with light of wavelengths shorter than 330 nm, while the latter was obtained by direct excitation into Eu3+ with light of wavelengths longer than 380 nm which correspond to the Eu3+ absorption bands. In the latter case, different spectra were obtained depending on the excitation wavelength even in the same absorption band. It is suggested that the sharp line spectrum is caused by Eu3+ ions substituted for Ti4+ but with some distortion around the Eu3+ ions in the matrix of TiO2 due to the large difference in ionic radius between the Ti4+ and Eu3+ ions, which are mainly present in the interior region of the nanoparticle. The broad band spectrum is caused by the disordered Eu3+ ions with Eu-O-Ti bonds which are predominantly present in the near surface region.

Highly Efficient Defect Emission from ZnO:Zn and ZnO:S Powders

NASA Astrophysics Data System (ADS)

Everitt, Henry

2013-03-01

Bulk Zinc Oxide (ZnO) is a wide band gap semiconductor with an ultraviolet direct band gap energy of 3.4 eV and a broad, defect-related visible wavelength emission band centered near 2 eV. We have shown that the external quantum efficiency can exceed 50% for this nearly white emission band that closely matches the human dark-adapted visual response. To explore the potential of ZnO as a rare earth-free white light phosphor, we investigated the mechanism of efficient defect emission in three types of ZnO powders: unannealed, annealed, and sulfur-doped. Annealing and sulfur-doping of ZnO greatly increase the strength of defect emission while suppressing the UV band edge emission. Continuous wave and ultrafast one- and two-photon excitation spectroscopy are used to examine the defect emission mechanism. Low temperature photoluminescence (PL) and PL excitation (PLE) spectra were measured for all three compounds, and it was found that bound excitons mediate the defect emission. Temperature-dependent PLE spectra for the defect and band edge emission were measured to estimate trapping and activation energies of the bound excitons and clarify the role they play in the defect emission. Time-resolved techniques were used to ascertain the role of exciton diffusion, the effects of reabsorption, and the spatial distributions of radiative and non-radiative traps. In unannealed ZnO we find that defect emission is suppressed and UV band edge emission is inefficient (< 2%) because of reabsorption and non-radiative recombination due to a high density of non-radiative bulk traps. By annealing ZnO, bulk trap densities are reduced, and a high density of defects responsible for the broad visible emission are created near the surface. Interestingly, nearly identical PLE spectra are found for both the band edge and the defect emission, one of many indications that the defect emission is deeply connected to bound excitons. Quantum efficiency, also measured as a function of excitation wavelength, closely mirrors the PLE spectra for both emission bands. Sulfur-doped ZnO exhibits additional PLE and X-ray features indicative of a ZnS-rich surface shell that correlates with even more efficient defect emission. The results presented here offer hope that engineering defects in ZnO materials may significantly improve the quantum efficiency for white light phosphor applications. This work was supported by the Army's in-house laboratory innovative research program.

47 CFR 15.239 - Operation in the band 88-108 MHz.

Code of Federal Regulations, 2010 CFR

2010-10-01

... Intentional Radiators Radiated Emission Limits, Additional Provisions § 15.239 Operation in the band 88-108 MHz. (a) Emissions from the intentional radiator shall be confined within a band 200 kHz wide centered... the general radiated emission limits in § 15.209. (d) A custom built telemetry intentional radiator...

Topographical characteristics and principal component structure of the hypnagogic EEG.

PubMed

Tanaka, H; Hayashi, M; Hori, T

1997-07-01

The purpose of the present study was to identify the dominant topographic components of electroencephalographs (EEG) and their behavior during the waking-sleeping transition period. Somnography of nocturnal sleep was recorded on 10 male subjects. Each recording, from "lights-off" to 5 minutes after the appearance of the first sleep spindle, was analyzed. The typical EEG patterns during hypnagogic period were classified into nine EEG stages. Topographic maps demonstrated that the dominant areas of alpha-band activity moved from the posterior areas to anterior areas along the midline of the scalp. In delta-, theta-, and sigma-band activities, the differences of EEG amplitude between the focus areas (the dominant areas) and the surrounding areas increased as a function of EEG stage. To identify the dominant topographic components, a principal component analysis was carried out on a 12-channel EEG data set for each of six frequency bands. The dominant areas of alpha 2- (9.6-11.4 Hz) and alpha 3- (11.6-13.4 Hz) band activities moved from the posterior to anterior areas, respectively. The distribution of alpha 2-band activity on the scalp clearly changed just after EEG stage 3 (alpha intermittent, < 50%). On the other hand, alpha 3-band activity became dominant in anterior areas after the appearance of vertex sharp-wave bursts (EEG stage 7). For the sigma band, the amplitude of extensive areas from the frontal pole to the parietal showed a rapid rise after the onset of stage 7 (the appearance of vertex sharp-wave bursts). Based on the results, sleep onset process probably started before the onset of sleep stage 1 in standard criteria. On the other hand, the basic sleep process may start before the onset of sleep stage 2 or the manually scored spindles.

Electronic structure descriptor for the discovery of narrow-band red-emitting phosphors

DOE PAGES

Wang, Zhenbin; Chu, Iek -Heng; Zhou, Fei; ...

2016-05-09

Narrow-band red-emitting phosphors are a critical component of phosphor-converted light-emitting diodes for highly efficient illumination-grade lighting. In this work, we report the discovery of a quantitative descriptor for narrow-band Eu 2+-activated emission identified through a comparison of the electronic structures of known narrow-band and broad-band phosphors. We find that a narrow emission bandwidth is characterized by a large splitting of more than 0.1 eV between the two highest Eu 2+ 4 f 7 bands. By incorporating this descriptor in a high-throughput first-principles screening of 2259 nitride compounds, we identify five promising new nitride hosts for Eu 2+-activated red-emitting phosphors thatmore » are predicted to exhibit good chemical stability, thermal quenching resistance, and quantum efficiency, as well as narrow-band emission. Lastly, our findings provide important insights into the emission characteristics of rare-earth activators in phosphor hosts and a general strategy to the discovery of phosphors with a desired emission peak and bandwidth.« less

Near-midnight observations of nitric oxide delta- and gamma-band chemiluminescence

NASA Technical Reports Server (NTRS)

Tennyson, P. D.; Feldman, P. D.; Hartig, G. F.; Henry, R. C.

1986-01-01

Chemiluminescent nightglow emission of the nitric oxide delta and gamma bands was measured from a sounding rocket launched on April 27, 1981, near local midnight. The integrated band emission rates for this near zenith observation above 205 km were less than 10 Rayleighs. The solar zenith angle was 127 deg. The branching ratio from the C2Pi state to the A2Sigma(+) state of NO was determined from comparison of the total emission rate of the delta band system to that of the gamma band system and found to be 0.30 + or - 0.06. The branching ratios within each of the band systems were found to be consistent with previous theoretical and experimental determinations. The vertical atomic nitrogen distribution, derived with the use of a model atmosphere, was found to have a peak density of 2.0 x 10 to the 7th atoms/cu cm at an altitude of 205 km. The analysis of these data indicate the presence of residual NO emission above 270 km at local midnight on the order of 1 Rayleigh of total band emission.

Electronic structure descriptor for the discovery of narrow-band red-emitting phosphors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Zhenbin; Chu, Iek -Heng; Zhou, Fei

Narrow-band red-emitting phosphors are a critical component of phosphor-converted light-emitting diodes for highly efficient illumination-grade lighting. In this work, we report the discovery of a quantitative descriptor for narrow-band Eu 2+-activated emission identified through a comparison of the electronic structures of known narrow-band and broad-band phosphors. We find that a narrow emission bandwidth is characterized by a large splitting of more than 0.1 eV between the two highest Eu 2+ 4 f 7 bands. By incorporating this descriptor in a high-throughput first-principles screening of 2259 nitride compounds, we identify five promising new nitride hosts for Eu 2+-activated red-emitting phosphors thatmore » are predicted to exhibit good chemical stability, thermal quenching resistance, and quantum efficiency, as well as narrow-band emission. Lastly, our findings provide important insights into the emission characteristics of rare-earth activators in phosphor hosts and a general strategy to the discovery of phosphors with a desired emission peak and bandwidth.« less

3.3 and 11.3 micron images of HD 44179 - Evidence for an optically thick polycyclic aromatic hydrocarbon disk

NASA Technical Reports Server (NTRS)

Bregman, Jesse D.; Rank, David; Temi, Pasquale; Hudgins, Doug; Kay, Laura

1993-01-01

Images of HD 44179 (the Red Rectangle) obtained in the 3.3 and 11.3 micron emission bands show two different spatial distributions. The 3.3 micron band image is centrally peaked and slightly extended N-S while the 11.3 micron image shows a N-S bipolar shape with no central peak. If the 3.3 micron band image shows the intrinsic emission of the 11.3 micron band, then the data suggest absorption of the 11.3 micron emission near the center of HD 44179 by a disk with an optical depth of about one, making HD 44179 the first object in which the IR emission bands have been observed to be optically thick. Since there is no evidence of absorption of the 3.3 micron emission band by the disk, the absorption cross section of the 3.3 micron band must be substantially less than for the 11.3 micron band. Since the 3.3 and 11.3 micron bands are thought to arise from different size PAHs, the similar N-S extents of the two images implies that the ratio of small to large PAHs does not change substantially with distance from the center.

{Delta}I = 2 energy staggering in normal deformed dysprosium nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riley, M.A.; Brown, T.B.; Archer, D.E.

1996-12-31

Very high spin states (I{ge}50{Dirac_h}) have been observed in {sup 155,156,157}Dy. The long regular band sequences, free from sharp backbending effects, observed in these dysprosium nuclei offer the possibility of investigating the occurence of any {Delta}I = 2 staggering in normal deformed nuclei. Employing the same analysis techniques as used in superdeformed nuclei, certain bands do indeed demonstrate an apparent staggering and this is discussed.

Photoluminescence characteristics of ZnTe bulk crystal and ZnTe epilayer grown on GaAs substrate by MOVPE

NASA Astrophysics Data System (ADS)

Lü, Hai-Yan; Mu, Qi; Zhang, Lei; Lü, Yuan-Jie; Ji, Zi-Wu; Feng, Zhi-Hong; Xu, Xian-Gang; Guo, Qi-Xin

2015-12-01

Excitation power and temperature-dependent photoluminescence (PL) spectra of the ZnTe epilayer grown on (100) GaAs substrate and ZnTe bulk crystal are investigated. The measurement results show that both the structures are of good structural quality due to their sharp bound excitonic emissions and absence of the deep level structural defect-related emissions. Furthermore, in contrast to the ZnTe bulk crystal, although excitonic emissions for the ZnTe epilayer are somewhat weak, perhaps due to As atoms diffusing from the GaAs substrate into the ZnTe epilayer and/or because of the strain-induced degradation of the crystalline quality of the ZnTe epilayer, neither the donor-acceptor pair (DAP) nor conduction band-acceptor (e-A) emissions are observed in the ZnTe epilayer. This indicates that by further optimizing the growth process it is possible to obtain a high-crystalline quality ZnTe heteroepitaxial layer that is comparable to the ZnTe bulk crystal. Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20120131110006), the Key Science and Technology Program of Shandong Province, China (Grant No. 2013GGX10221), the Key Laboratory of Functional Crystal Materials and Device (Shandong University, Ministry of Education), China (Grant No. JG1401), the National Natural Science Foundation of China (Grant No. 61306113), the Major Research Plan of the National Natural Science Foundation of China (Grant No. 91433112), and the Partnership Project for Fundamental Technology Researches of the Ministry of Education, Culture, Sports, Science and Technology, Japan.

[Study on the fine structure of K-feldspar of Qichun granite].

PubMed

Du, Deng-Wen; Hong, Han-Lie; Fan, Kan; Wang, Chao-Wen; Yin, Ke

2013-03-01

Fine structure of K-feldspar from the Qichun granite was investigated using X-ray diffraction (XRD), Fourier infrared absorption spectroscopy (FTIR), and inductively coupled plasma mass spectrometry methods to understand the evolution of the granitic magmatism and its correlation to molybdenite mineralization. The XRD results showed that K-feldspar of the potassic alteration veins has higher ordering index and triclinicity and is namely microcline with triclinic symmetry. K-feldspar of the early cretaceous granite has relatively lower ordering index and has widening [131] peak and is locally triclinic ordering. K-feldspar of the late cretaceous granite has lowest ordering index and sharp [131] peak and is honiogeneously monoclinic. The FTIR results showed that the IR spectra of the Qichun K-feldspar are similar to that of orthoclase reported by Farmer (1974). The 640 cm-1 absorption band increases while the 540 cm-' absorption band decreases with increase in K-feldspar ordering index, also, the 1,010 cm-1 absorption band separates into 1,010 and 1,046 cm-1 absorption bands, with a change in the band shape from widening to sharp outline. The ICP-MS results suggested that K-feldspar of the early cretaceous granite has relatively higher metal elements and rare earth elements, and the granite exhibits better mineralization background, K-feldspar of the potassic alteration veins has markedly lower Sr and Ba, indicating that the alteration fluid originated from the granitic magmatism, and hence, potassic alteration is a good indicator for molybdenite exploration.

Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering

NASA Astrophysics Data System (ADS)

Yan, Danhua; Zhang, Wenrui; Cen, Jiajie; Stavitski, Eli; Sadowski, Jerzy T.; Vescovo, Elio; Walter, Andrew; Attenkofer, Klaus; Stacchiola, Darío J.; Liu, Mingzhao

2017-12-01

Zinc oxide (ZnO) nanowire arrays have potential applications for various devices such as ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of the reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.

Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Danhua; Zhang, Wenrui; Cen, Jiajie

Zinc oxide (ZnO) nanowire arrays have potential applications for various devices including ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O 2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of themore » reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.« less

Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering

DOE PAGES

Yan, Danhua; Zhang, Wenrui; Cen, Jiajie; ...

2017-12-04

Zinc oxide (ZnO) nanowire arrays have potential applications for various devices including ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O 2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of themore » reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.« less

C-H Hot Bands in the Near-IR Emission Spectra of Leonids

NASA Technical Reports Server (NTRS)

Freund, F. T.; Scoville, J.; Holm, R.; Seelemann, R.; Freund, M. M.

2002-01-01

The reported infrared (IR) emission spectra from 1999 Leonid fireballs show a 3.4 micron C-H emission band and unidentified bands at longer wavelengths. Upon atmospheric entry, the Leonid meteorites were flash-heated to temperatures around 2400K, which would destroy any organics on the surface of the meteorite grains. We propose that the nu(sub )CH emission band in the Leonid emission spectra arises from matrix-embedded C(sub n)-H-O entities that are protected from instant pyrolysis. Our model is based on IR absorption nu(sub )CH bands, which we observed in laboratory-grown MgO and natural olivine single crystals, where they arise from C(sub n)-H-O units imbedded in the mineral matrix, indicative of aliphatic -CH2- and -CH3 organics. Instead of being pyrolyzed, the C(sub n)-H-O entities in the Leonid trails become vibrationally excited to higher levels n = 1, 2, 3 etc. During de-excitation they emit at 3.4 microns, due to the (0 => 1) transition, and at longer wavelengths, due to hot bands. As a first step toward verifying this hypothesis we measured the C-H vibrational manifold of hexane (C6H14). The calculated positions of the (2 => l ) , (3 => 2), and possibly (4 => 3) hot bands agree with the Leonid emission bands at 3.5, 3.8 and 4.l microns.

Detection of boron nitride radicals by emission spectroscopy in a laser-induced plasma

NASA Astrophysics Data System (ADS)

Dutouquet, C.; Acquaviva, S.; Hermann, J.

2001-06-01

Several vibrational bands of boron nitride radicals have been observed in a plasma produced by pulsed-laser ablation of a boron nitride target in low-pressure nitrogen or argon atmospheres. Using time- and space-resolved emission spectroscopic measurements with a high dynamic range, the most abundant isotopic species B 11N have been detected. The emission bands in the spectral range from 340 to 380 nm belong to the Δυ =-1, 0, +1 sequences of the triplet system (transition A 3Π-X 3Π). For positive identification, the molecular emission bands have been compared with synthetic spectra obtained by computer simulations. Furthermore, B 10N emission bands have been reproduced by computer simulation using molecular constants which have been deduced from the B 11N constants. Nevertheless, the presence of the lower abundant isotopic radical B 10N was not proved due the noise level which masked the low emission intensity of the B 10N band heads.

Modeling the complexity of acoustic emission during intermittent plastic deformation: Power laws and multifractal spectra

NASA Astrophysics Data System (ADS)

Kumar, Jagadish; Ananthakrishna, G.

2018-01-01

Scale-invariant power-law distributions for acoustic emission signals are ubiquitous in several plastically deforming materials. However, power-law distributions for acoustic emission energies are reported in distinctly different plastically deforming situations such as hcp and fcc single and polycrystalline samples exhibiting smooth stress-strain curves and in dilute metallic alloys exhibiting discontinuous flow. This is surprising since the underlying dislocation mechanisms in these two types of deformations are very different. So far, there have been no models that predict the power-law statistics for discontinuous flow. Furthermore, the statistics of the acoustic emission signals in jerky flow is even more complex, requiring multifractal measures for a proper characterization. There has been no model that explains the complex statistics either. Here we address the problem of statistical characterization of the acoustic emission signals associated with the three types of the Portevin-Le Chatelier bands. Following our recently proposed general framework for calculating acoustic emission, we set up a wave equation for the elastic degrees of freedom with a plastic strain rate as a source term. The energy dissipated during acoustic emission is represented by the Rayleigh-dissipation function. Using the plastic strain rate obtained from the Ananthakrishna model for the Portevin-Le Chatelier effect, we compute the acoustic emission signals associated with the three Portevin-Le Chatelier bands and the Lüders-like band. The so-calculated acoustic emission signals are used for further statistical characterization. Our results show that the model predicts power-law statistics for all the acoustic emission signals associated with the three types of Portevin-Le Chatelier bands with the exponent values increasing with increasing strain rate. The calculated multifractal spectra corresponding to the acoustic emission signals associated with the three band types have a maximum spread for the type C bands and decreasing with types B and A. We further show that the acoustic emission signals associated with Lüders-like band also exhibit a power-law distribution and multifractality.

Modeling the complexity of acoustic emission during intermittent plastic deformation: Power laws and multifractal spectra.

PubMed

Kumar, Jagadish; Ananthakrishna, G

2018-01-01

Scale-invariant power-law distributions for acoustic emission signals are ubiquitous in several plastically deforming materials. However, power-law distributions for acoustic emission energies are reported in distinctly different plastically deforming situations such as hcp and fcc single and polycrystalline samples exhibiting smooth stress-strain curves and in dilute metallic alloys exhibiting discontinuous flow. This is surprising since the underlying dislocation mechanisms in these two types of deformations are very different. So far, there have been no models that predict the power-law statistics for discontinuous flow. Furthermore, the statistics of the acoustic emission signals in jerky flow is even more complex, requiring multifractal measures for a proper characterization. There has been no model that explains the complex statistics either. Here we address the problem of statistical characterization of the acoustic emission signals associated with the three types of the Portevin-Le Chatelier bands. Following our recently proposed general framework for calculating acoustic emission, we set up a wave equation for the elastic degrees of freedom with a plastic strain rate as a source term. The energy dissipated during acoustic emission is represented by the Rayleigh-dissipation function. Using the plastic strain rate obtained from the Ananthakrishna model for the Portevin-Le Chatelier effect, we compute the acoustic emission signals associated with the three Portevin-Le Chatelier bands and the Lüders-like band. The so-calculated acoustic emission signals are used for further statistical characterization. Our results show that the model predicts power-law statistics for all the acoustic emission signals associated with the three types of Portevin-Le Chatelier bands with the exponent values increasing with increasing strain rate. The calculated multifractal spectra corresponding to the acoustic emission signals associated with the three band types have a maximum spread for the type C bands and decreasing with types B and A. We further show that the acoustic emission signals associated with Lüders-like band also exhibit a power-law distribution and multifractality.

DIRECT IMAGING OF THE WATER SNOW LINE AT THE TIME OF PLANET FORMATION USING TWO ALMA CONTINUUM BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Banzatti, A.; Pontoppidan, K. M.; Pinilla, P.

2015-12-10

Molecular snow lines in protoplanetary disks have been studied theoretically for decades because of their importance in shaping planetary architectures and compositions. The water snow line lies in the planet formation region at ≲10 AU, and so far its location has been estimated only indirectly from spatially unresolved spectroscopy. This work presents a proof-of-concept method to directly image the water snow line in protoplanetary disks through its physical and chemical imprint on the local dust properties. We adopt a physical disk model that includes dust coagulation, fragmentation, drift, and a change in fragmentation velocities of a factor of 10 betweenmore » dry silicates and icy grains as found by laboratory work. We find that the presence of a water snow line leads to a sharp discontinuity in the radial profile of the dust emission spectral index α{sub mm} due to replenishment of small grains through fragmentation. We use the ALMA simulator to demonstrate that this effect can be observed in protoplanetary disks using spatially resolved ALMA images in two continuum bands. We explore the model dependence on the disk viscosity and find that the spectral index reveals the water snow line for a wide range of conditions, with opposite trends when the emission is optically thin rather than thick. If the disk viscosity is low (α{sub visc} < 10{sup −3}), the snow line produces a ringlike structure with a minimum at α{sub mm} ∼ 2 in the optically thick regime, possibly similar to what has been measured with ALMA in the innermost region of the HL Tau disk.« less

Raman spectroscopy of the organic and mineral structure of bone grafts

NASA Astrophysics Data System (ADS)

Timchenko, E. V.; Timchenko, P. E.; Volova, L. T.; Ponomareva, Yu V.; Taskina, L. A.

2014-07-01

We report the results of experimental Raman spectroscopy of donor bone samples (rat, rabbit and human) with varying degrees of mineralisation. Raman spectra are obtained for the Raman bands of 950 - 962 cm-1 (PO4)3-, 1065 - 1070 cm-1 (CO3)2- and 1665 cm-1 (amide I). In demineralised bone, a sharp (98%) decrease in the intensities of 950 - 962 and 1065 - 1070 cm-1 bands is observed, which is accompanied by the emergence of the 1079 - 1090 cm-1 band corresponding to the hydrated amorphous state CO3-3.

Glimpse of Bagnold Dunes Edging Mount Sharp

NASA Image and Video Library

2015-11-16

The dark band in the lower portion of this Martian scene is part of the "Bagnold Dunes" dune field lining the northwestern edge of Mount Sharp, inside Gale Crater. The view combines multiple images taken with the Mast Camera (Mastcam) on NASA's Curiosity Mars rover on Sept. 25, 2015, during the 1,115th Martian day, or sol, of Curiosity's work on Mars. The images are from Mastcam's right-eye camera, which has a telephoto lens. The view is toward south-southeast. Curiosity will visit examples of the Bagnold Dunes on the rover's route to higher layers of Mount Sharp. The informal name for the dune field is a tribute to British military engineer Ralph Bagnold (1896-1990), a pioneer in the study of how winds move sand particles of dunes on Earth. The dune field is evident as a dark band in orbital images of the area inside Gale Crater where Curiosity has been active since landing in 2012, such as a traverse map at PIA20162. Dunes are larger than wind-blown ripples of sand or dust that Curiosity and other rovers have visited previously. The scene is presented with a color adjustment that approximates white balancing, to resemble how the rocks and sand would appear under daytime lighting conditions on Earth. http://photojournal.jpl.nasa.gov/catalog/PIA19929

Optogenetic activation of septal cholinergic neurons suppresses sharp wave ripples and enhances theta oscillations in the hippocampus.

PubMed

Vandecasteele, Marie; Varga, Viktor; Berényi, Antal; Papp, Edit; Barthó, Péter; Venance, Laurent; Freund, Tamás F; Buzsáki, György

2014-09-16

Theta oscillations in the limbic system depend on the integrity of the medial septum. The different populations of medial septal neurons (cholinergic and GABAergic) are assumed to affect different aspects of theta oscillations. Using optogenetic stimulation of cholinergic neurons in ChAT-Cre mice, we investigated their effects on hippocampal local field potentials in both anesthetized and behaving mice. Cholinergic stimulation completely blocked sharp wave ripples and strongly suppressed the power of both slow oscillations (0.5-2 Hz in anesthetized, 0.5-4 Hz in behaving animals) and supratheta (6-10 Hz in anesthetized, 10-25 Hz in behaving animals) bands. The same stimulation robustly increased both the power and coherence of theta oscillations (2-6 Hz) in urethane-anesthetized mice. In behaving mice, cholinergic stimulation was less effective in the theta (4-10 Hz) band yet it also increased the ratio of theta/slow oscillation and theta coherence. The effects on gamma oscillations largely mirrored those of theta. These findings show that medial septal cholinergic activation can both enhance theta rhythm and suppress peri-theta frequency bands, allowing theta oscillations to dominate.

Digging in the coronal graveyard - A Rosat observation of the red giant Arcturus

NASA Technical Reports Server (NTRS)

Ayres, Thomas R.; Fleming, Thomas A.; Schmitt, Juergen H. M. M.

1991-01-01

A deep exposure of the bright star Arcturus (Alpha Bootis: K1 III) with the Roentgensatellit (Rosat) failed to detect soft X-ray emission from the archetype 'noncoronal' red giant. The 3-sigma upper limit in the energy band 0.1-2.4 keV corresponds to an X-ray luminosity of less than 3 x 10 to the 25th erg/s, equivalent to a coronal surface flux density of less than 0.0001 solar. The nondetection safely eliminates coronal irradiation as a possible mechanism to produce the highly variable He I 10830 feature and emphasizes the sharp decline in solarlike coronal activity that accompanies the evolution of low-mass single stars away from the main sequence. While the most conspicuous object in the Rosat field of view was not visible in X-rays, at least one fainter star is among the about 60 sources recorded: the Sigma Sct variable CN Boo, an A8 giant in the UMa Stream.

New CVD-based method for the growth of high-quality crystalline zinc oxide layers

NASA Astrophysics Data System (ADS)

Huber, Florian; Madel, Manfred; Reiser, Anton; Bauer, Sebastian; Thonke, Klaus

2016-07-01

High-quality zinc oxide (ZnO) layers were grown using a new chemical vapour deposition (CVD)-based low-cost growth method. The process is characterized by total simplicity, high growth rates, and cheap, less hazardous precursors. To produce elementary zinc vapour, methane (CH4) is used to reduce a ZnO powder. By re-oxidizing the zinc with pure oxygen, highly crystalline ZnO layers were grown on gallium nitride (GaN) layers and on sapphire substrates with an aluminum nitride (AlN) nucleation layer. Using simple CH4 as precursor has the big advantage of good controllability and the avoidance of highly toxic gases like nitrogen oxides. In photoluminescence (PL) measurements the samples show a strong near-band-edge emission and a sharp line width at 5 K. The good crystal quality has been confirmed in high resolution X-ray diffraction (HRXRD) measurements. This new growth method has great potential for industrial large-scale production of high-quality single crystal ZnO layers.

A New Method for Atmospheric Correction of MRO/CRISM Data.

NASA Astrophysics Data System (ADS)

Noe Dobrea, Eldar Z.; Dressing, C.; Wolff, M. J.

2009-09-01

The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) aboard the Mars Reconnaissance Orbiter (MRO) collects hyperspectral images from 0.362 to 3.92 μm at 6.55 nanometers/channel, and at a spatial resolution of 20 m/pixel. The 1-2.6 μm spectral range is often used to identify and map the distribution of hydrous minerals using mineralogically diagnostic bands at 1.4 μm, 1.9 μm, and 2 - 2.5 micron region. Atmospheric correction of the 2-μm CO2 band typically employs the same methodology applied to OMEGA data (Mustard et al., Nature 454, 2008): an atmospheric opacity spectrum, obtained from the ratio of spectra from the base to spectra from the peak of Olympus Mons, is rescaled for each spectrum in the observation to fit the 2-μm CO2 band, and is subsequently used to correct the data. Three important aspects are not considered in this correction: 1) absorptions due to water vapor are improperly accounted for, 2) the band-center of each channel shifts slightly with time, and 3) multiple scattering due to atmospheric aerosols is not considered. The second issue results in miss-registration of the sharp CO2 features in the 2-μm triplet, and hence poor atmospheric correction. This leads to the necessity to ratio all spectra using the spectrum of a spectrally "bland” region in each observation in order to distinguish features 1.9 μm. Here, we present an improved atmospheric correction method, which uses emission phase function (EPF) observations to correct for molecular opacity, and a discrete ordinate radiative transfer algorithm (DISORT - Stamnes et al., Appl. Opt. 27, 1988) to correct for the effects of multiple scattering. This method results in a significant improvement in the correction of the 2-μm CO2 band, allowing us to forgo the use of spectral ratios that affect the spectral shape and preclude the derivation of reflectance values in the data.

Local adaptive tone mapping for video enhancement

NASA Astrophysics Data System (ADS)

Lachine, Vladimir; Dai, Min (.

2015-03-01

As new technologies like High Dynamic Range cameras, AMOLED and high resolution displays emerge on consumer electronics market, it becomes very important to deliver the best picture quality for mobile devices. Tone Mapping (TM) is a popular technique to enhance visual quality. However, the traditional implementation of Tone Mapping procedure is limited by pixel's value to value mapping, and the performance is restricted in terms of local sharpness and colorfulness. To overcome the drawbacks of traditional TM, we propose a spatial-frequency based framework in this paper. In the proposed solution, intensity component of an input video/image signal is split on low pass filtered (LPF) and high pass filtered (HPF) bands. Tone Mapping (TM) function is applied to LPF band to improve the global contrast/brightness, and HPF band is added back afterwards to keep the local contrast. The HPF band may be adjusted by a coring function to avoid noise boosting and signal overshooting. Colorfulness of an original image may be preserved or enhanced by chroma components correction by means of saturation function. Localized content adaptation is further improved by dividing an image to a set of non-overlapped regions and modifying each region individually. The suggested framework allows users to implement a wide range of tone mapping applications with perceptional local sharpness and colorfulness preserved or enhanced. Corresponding hardware circuit may be integrated in camera, video or display pipeline with minimal hardware budget

Fabrication of 3-D Photonic Band Gap Crystals Via Colloidal Self-Assembly

NASA Technical Reports Server (NTRS)

Subramaniam, Girija; Blank, Shannon

2005-01-01

The behavior of photons in a Photonic Crystals, PCs, is like that of electrons in a semiconductor in that, it prohibits light propagation over a band of frequencies, called Photonic Band Gap, PBG. Photons cannot exist in these band gaps like the forbidden bands of electrons. Thus, PCs lend themselves as potential candidates for devices based on the gap phenomenon. The popular research on PCs stem from their ability to confine light with minimal losses. Large scale 3-D PCs with a PBG in the visible or near infra red region will make optical transistors and sharp bent optical fibers. Efforts are directed to use PCs for information processing and it is not long before we can have optical integrated circuits in the place of electronic ones.

Investigating model deficiencies in the global budget of ethane

NASA Astrophysics Data System (ADS)

Tzompa Sosa, Z. A.; Keller, C. A.; Turner, A. J.; Mahieu, E.; Franco, B.; Fischer, E. V.

2015-12-01

Many locations in the Northern Hemisphere show a statistically-significant sharp increase in measurements of ethane (C2H6) since 2009. It is hypothesized that the recent massive growth of shale gas exploitation in North America could be the source of this change. However, state-of-the-science chemical transport models are currently unable to reproduce the hemispheric burden of C2H6 or the recent sharp increase, pointing to a potential problem with current emission inventories. To resolve this, we used space-borne CH4 observations from the Greenhouse Gases Observing SATellite (GOSAT) to derive C2H6 emissions. By using known emission ratios to CH4, we estimated emissions of C2H6 from oil and gas activities, biofuels, and biomass burning over North America. The GEOS-Chem global chemical transport model was used to simulate atmospheric abundances of C2H6 with the new emissions estimates. The model is able to reproduce Northern Hemisphere surface concentrations. However, the model significantly under-predicts the amount of C2H6 throughout the column and the observed Northern Hemispheric gradient as diagnosed by comparisons to aircraft observations from the Hiaper Pole-to-Pole (HIPPO) Campaign.

Auroral nitric oxide concentration and infrared emission

NASA Astrophysics Data System (ADS)

Reidy, W. P.; Degges, T. C.; Hurd, A. G.; Stair, A. T., Jr.; Ulwick, J. C.

1982-05-01

Rocket-borne measurements of infrared auroral emission by nitric oxide are analyzed. Four rocket flights provided opportunities to measure 5.3- and 2.7-micron NO emission by means of infrared fixed band radiometers and CVF spectrometers, narrow band photometers, and incident energy spectra on various occasions. Analysis of infrared emission profiles and electron flux data indicates the NO density to be significantly enhanced with respect to midlatitude values. NO emission in the fundamental 5.3-micron band is attributed to resonance excitation by warm earth radiation, collisional excitation primarily by O atoms and chemiluminescence from the reaction of N with O2; with an energy efficiency of 0.015. The overtone band emission at 2.7 microns is accounted for by chemiluminescence produced with an energy efficiency of 0.0054. Total photon yield for the chemiluminescence reaction is estimated to range from 1.2 to 2.4 vibrational quanta per NO molecule.

Field emission electron source

DOEpatents

Zettl, Alexander Karlwalter; Cohen, Marvin Lou

2000-01-01

A novel field emitter material, field emission electron source, and commercially feasible fabrication method is described. The inventive field emission electron source produces reliable electron currents of up to 400 mA/cm.sup.2 at 200 volts. The emitter is robust and the current it produces is not sensitive to variability of vacuum or the distance between the emitter tip and the cathode. The novel emitter has a sharp turn-on near 100 volts.

The study of optical property of sapphire irradiated with 73 MeV Ca ions

NASA Astrophysics Data System (ADS)

Yang, Yitao; Zhang, Chonghong; Song, Yin; Gou, Jie; Liu, Juan; Xian, Yongqiang

2015-12-01

Single crystals of sapphire were irradiated with 73 MeV Ca ions at room temperature to the fluences of 0.1, 0.5 and 1.0 × 1014 ions/cm2. Optical properties of these samples were characterized by ultraviolet-visible spectrometry (UV-VIS) and fluorescence spectrometer (PL). In UV-VIS spectra, it is observed the absorbance bands from oxygen single vacancy (F and F+ color centers) and vacancy pair (F2+ and F22+ color centers). The oxygen single vacancy initially increases rapidly and then does not increase in the fluence range from 0.1 to 0.5 × 1014 ions/cm2. When the fluence is higher than 0.5 × 1014 ions/cm2, oxygen single vacancy starts to increase again. Oxygen vacancy pair increases monotonically with fluence for all irradiated samples. The variation of oxygen single vacancy with fluence is probably associated with the recombination of oxygen vacancies with Al interstitials and complex defect formation (such as vacancy clusters). From PL spectra, two emission bands around 3.1 and 2.34 eV are observed. The PL intensity of the emission band around 3.1 eV decreases for all the irradiated samples. For the emission band around 2.34 eV, the PL intensity initially decreases, and then increases with fluence. Meanwhile, the peak position of the emission band around 2.34 eV gradually shifts to high energy direction with increase of fluence. The decrease of the intensity of the emission bands around 3.1 and 2.34 eV could be induced by stress from the damage layer in the irradiated samples. The shift of peak position for the emission band around 2.34 eV is induced by the appearance of emission band from Al interstitials.

Effect of narrow band nonuniformity on unsteady heat up of water vapor under radiation-conduction combined heat transfer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Okamoto, Tatsuyuki; Tanaka, Tomohiro; Morimune, Atsushi

Effect of narrow band nonuniformity on unsteady heat up process of water vapor under radiation-conduction combined heat transfer is examined by comparing the result of numerical simulations with and without incorporation of narrow band nonuniformity. The authors propose a rational and comprehensive computational approach for incorporating the narrow band nonuniformity into numerical simulations of radiative heat transfer when the considered field is nonisothermal. Results of examination exhibited that the contribution of radiative heat transfer to the heat up rate of water vapor may be almost twice overestimated, if the narrow band nonuniformity effect is neglected. Separate analyses of radiative energymore » attributed to wall emission and gas emission clarified that the absorption of wall emission is overestimated and, on the contrary, the absorption of radiation energy emitted by water vapor itself is underestimated if the narrow band nonuniformity is neglected. The reason why such over- or under-estimation is induced is understood by examining the influence of line overlap parameter on the transmittance averaged within a narrow band. Smaller value of line overlap parameter {gamma}/d means more violent narrow band nonuniformity. The broken lines show the narrow band transmittance for flat incident power spectrum, and the solid lines show that for the radiative emission from the absorbing gas itself. It is also clarified that the disregard of the narrow band nonuniformity give rise to serious error in the estimation of absorption rate of wall and gas emission even in the case where the disregard of narrow band nonuniformity bring little change to the temperature distribution. The results illustrated in this paper suggest that the narrow band nonuniformity should not be neglected.« less

Pressure-induced emission band separation of the hybridized local and charge transfer excited state in a TPE-based crystal.

PubMed

Liu, Xuedan; Li, Aisen; Xu, Weiqing; Ma, Zhiyong; Jia, Xinru

2018-05-08

We herein report a newly synthesized simple molecule, named TPE[double bond, length as m-dash]C4, with twisted D-A structure. TPE[double bond, length as m-dash]C4 showed two intrinsic emission bands ascribed to the locally excited (LE) state and the intramolecular charge transfer (ICT) state, respectively. In the crystal state, the LE emission band is usually observed. However, by applying hydrostatic pressure to the powder sample and the single crystal sample of TPE[double bond, length as m-dash]C4, dual-fluorescence (445 nm and 532 nm) was emerged under high pressure, owing to the pressure-induced emission band separation of the hybridized local and charge transfer excited state (HLCT). It is found that the emission of TPE[double bond, length as m-dash]C4 is generally determined by the ratio of the LE state to the ICT state. The ICT emission band is much more sensitive to the external pressure than the LE emission band. The HLCT state leads to a sample with different responsiveness to grinding and hydrostatic pressure. This study is of significance in the molecular design of such D-A type molecules and in the control of photoluminescence features by molecular structure. Such results are expected to pave a new way to further understand the relationship between the D-A molecular structure and stimuli-responsive properties.

Sharp increase of radio flux in flaring blazar PKS 1424-41

NASA Astrophysics Data System (ADS)

Nemenashi, Pfesesani; Gaylard, Michael; Ojha, Roopesh

2013-02-01

The Hartebeesthoek Radio Astronomy Observatory (HartRAO) 26m telescope has detected a sharp increase in the flux density of PKS 1424-41 (also known as 2FGL J1428.0-4206, Nolan et al. 2012, ApJS, 199, 31) coinciding with the flaring activity reported at gamma-ray and optical (ATel#4714), X-ray (ATel#4717, ATel#4770) and OIR (ATel#4775) bands. At 8.4 GHz, its flux has risen from 6.1 Jy on 2013 Jan 08 to 7.0 Jy on 2013 Jan 28 and it remains at that level.

Electron Density Dropout Near Enceladus in the Context of Water-Vapor and Water-Ice

NASA Technical Reports Server (NTRS)

Farrell, W. M.; Kurth, W. S.; Gurnett, D. A.; Johnson, R. E.; Kaiser, M. L.; Wahlund, J.-E.; Waite, J. H., Jr.

2009-01-01

On 12 March 2008, the Cassini spacecraft made a close encounter with the Saturnian moon Enceladus, passing within 52 km of the moon. The spacecraft trajectory was intentionally-oriented in a southerly direction to create a close alignment with the intense water-dominated plumes emitted from the south polar region. During the passage, the Cassini Radio and Plasma Wave System (RPWS) detected two distinct radio signatures: 1) Impulses associated with small water-ice dust grain impacts and 2) an upper hybrid (UH) resonance emission that both intensified and displayed a sharp frequency decrease in the near-vicinity of the moon. The frequency decrease of the UH emission is associated with an unexpectedly sharp decrease in electron density from approximately 90 el/cubic cm to below 20 el/cubic cm that occurs on a time scale of a minute near the closest encounter with the moon. In this work, we consider a number of scenarios to explain this sharp electron dropout, but surmise that electron absorption by ice grains is the most likely process.

Multi-photon excited coherent random laser emission in ZnO powders

NASA Astrophysics Data System (ADS)

Tolentino Dominguez, Christian; Gomes, Maria De A.; Macedo, Zélia S.; de Araújo, Cid B.; Gomes, Anderson S. L.

2014-11-01

We report the observation and analysis of anti-Stokes coherent random laser (RL) emission from zinc oxide (ZnO) powders excited by one-, two- or three-photon femtosecond laser radiation. The ZnO powders were produced via a novel proteic sol-gel, low-cost and environmentally friendly route using coconut water in the polymerization step of the metal precursor. One- and two-photon excitation at 354 nm and 710 nm, respectively, generated single-band emissions centred at about 387 nm. For three-photon excitation, the emission spectra showed a strong ultraviolet (UV) band (380-396 nm) attributed to direct three-photon absorption from the valence band to the conduction band. The presence of an intensity threshold and a bandwidth narrowing of the UV band from about 20 to 4 nm are clear evidence of RL action. The observation of multiple sub-nanometre narrow peaks in the emission spectra for excitation above the RL threshold is consistent with random lasing by coherent feedback.

POST-OUTBURST RADIO OBSERVATIONS OF THE HIGH MAGNETIC FIELD PULSAR PSR J1119-6127

DOE Office of Scientific and Technical Information (OSTI.GOV)

Majid, Walid A.; Pearlman, Aaron B.; Dobreva, Tatyana

We have carried out high-frequency radio observations of the high magnetic field pulsar PSR J1119-6127 following its recent X-ray outburst. While initial observations showed no evidence of significant radio emission, subsequent observations detected pulsed emission across a large frequency band. In this Letter, we report on the initial disappearance of the pulsed emission and its prompt reactivation and dramatic evolution over several months of observation. The periodic pulse profile at S -band (2.3 GHz) after reactivation exhibits a multi-component emission structure, while the simultaneous X -band (8.4 GHz) profile shows a single emission peak. Single pulses were also detected atmore » S -band near the main emission peaks. We present measurements of the spectral index across a wide frequency bandwidth, which captures the underlying changes in the radio emission profile of the neutron star. The high-frequency radio detection, unusual emission profile, and observed variability suggest similarities with magnetars, which may independently link the high-energy outbursts to magnetar-like behavior.« less

The Mars diffuse aurora: A model of ultraviolet and visible emissions

NASA Astrophysics Data System (ADS)

Gérard, J.-C.; Soret, L.; Shematovich, V. I.; Bisikalo, D. V.; Bougher, S. W.

2017-05-01

A new type of Martian aurora, characterized by an extended spatial distribution, an altitude lower than the discrete aurora and electron precipitation up to 200 keV has been observed following solar activity on several occasions from the MAVEN spacecraft. We describe the results of Monte Carlo simulations of the production of several ultraviolet and violet auroral emissions for initial electron energies extending from 0.25 to 200 keV. These include the CO2+ ultraviolet doublet (UVD) at 288.3 and 289.6 nm and the Fox-Duffendack-Barker (FDB) bands, CO Cameron and Fourth Positive bands, OI 130.4 and 297.2 nm and CI 156.1 nm and 165.7 nm multiplets. We calculate the nadir and limb production rates of several of these emissions for a unit precipitated energy flux. Our results indicate that electrons in the range 50-200 keV produce maximum CO2+ UVD emission below 75 km, in agreement with the MAVEN observations. We calculate the efficiency of photon production per unit precipitated electron power. The strongest emissions are the CO2+ FDB, UVD and CO Cameron bands and the oxygen emission at 297.2 nm. The metastable a 3Π state which radiates the Cameron bands is deactivated by collisions below about 110 km. As a consequence, we show that the Cameron band emission is expected to peak at a higher altitude than the CO2+ UVD and FDB bands. Collisional quenching also causes the intensity ratio of the CO2+ UVD to CO Cameron bands to increase below ∼100 km in the energetic diffuse aurora.

A vibrational spectroscopic study of tengerite-(Y) Y2(CO3)3 2-3H2O

NASA Astrophysics Data System (ADS)

Frost, Ray L.; López, Andrés; Wang, Lina; Scholz, Ricardo; Sampaio, Ney Pinheiro; de Oliveira, Fernando A. N.

2015-02-01

The mineral tengerite-(Y) has been studied by vibrational spectroscopy. Multiple carbonate stretching modes are observed and support the concept of non-equivalent carbonate units in the tengerite-(Y) structure. Intense sharp bands at 464, 479 and 508 cm-1 are assigned to YO stretching modes. Raman bands at 765 and 775 cm-1 are assigned to the CO32- ν4 bending modes and Raman bands at 589, 611, 674 and 689 cm-1 are assigned to the CO32- ν2 bending modes. Multiple Raman and infrared bands in the OH stretching region are observed, proving the existence of water in different molecular environments in the structure of tengerite-(Y).

Spatial Variation of the 3.29 and 3.40 Micron Emission Bands Within Reflection Nebulae and The Photochemical Evolution of Methylated Polycyclic Aromatic Hydrocarbons

NASA Technical Reports Server (NTRS)

Joblin, C.; Tielens, A. G. G. M.; Allamandola, L. J.; Geballe, T. R.

1996-01-01

Spectra of 3 microns emission features have been obtained at several positions within the reflection nebulae NGC 1333 SVS3 and NGC 2023. Strong variations of the relative intensities of the 3.29 microns feature and its most prominent satellite band at 3.40 microns are found. It is shown that: (1) the 3.40 microns band is too intense with respect to the 3.29 microns band at certain positions to arise from hot band emission alone, (2) the 3.40 microns band can be reasonably well matched by new laboratory spectra of gas-phase polycyclic aromatic hydrocarbons (PAHs) with alkyl (-CH3) side groups, and (3) the variations in the 3.40 microns to 3.29 microns band intensity ratios are consistent with the photochemical erosion of alkylated PAHs. We conclude that the 3.40 microns emission feature is attributable to -CH3 side groups on PAH molecules. We predict a value of 0.5 for the peak intensity ratio of the 3.40 and 3.29 microns emission bands from free PAHs in the diffuse interstellar medium, which would correspond to a proportion of one methyl group for four peripheral hydrogens. We also compare the 3 microns spectrum of the proto-planetary nebula IRAS 05341 + 0852 with the spectrum of the planetary nebula IRAS 21282 + 5050. We suggest that a photochemical evolution of the initial aliphatic and aromatic hydrocarbon mixture formed in the outflow is responsible for the changes observed in the 3 microns emission spectra of these objects.

Spatial variation of the 3.29 and 3.40 micron emission bands within reflection nebulae and the photochemical evolution of methylated polycyclic aromatic hydrocarbons

NASA Technical Reports Server (NTRS)

Joblin, C.; Tielens, A. G.; Allamandola, L. J.; Geballe, T. R.

1996-01-01

Spectra of 3 micrometers emission features have been obtained at several positions within the reflection nebulae NGC 1333 SVS3 and NGC 2023. Strong variations of the relative intensities of the 3.29 micrometers feature and its most prominent satellite band at 3.40 micrometers are found. It is shown that (i) the 3.40 micrometers band is too intense with respect to the 3.29 micrometers band at certain positions to arise from hot band emission alone, (ii) the 3.40 micrometers band can be reasonably well matched by new laboratory spectra of gas-phase polycyclic aromatic hydrocarbons (PAHs) with alkyl (-CH3) side groups, and (iii) the variations in the 3.40 micrometers to 3.29 micrometers band intensity ratios are consistent with the photochemical erosion of alkylated PAHs. We conclude that the 3.40 micrometers emission feature is attributable to -CH3 side groups on PAH molecules. We predict a value of 0.5 for the peak intensity ratio of the 3.40 and 3.29 micrometers emission bands from free PAHs in the diffuse interstellar medium, which would correspond to a proportion of one methyl group for four peripheral hydrogens. We also compare the 3 micrometers spectrum of the proto-planetary nebula IRAS 05341+0852 with the spectrum of the planetary nebula IRAS 21282+5050. We suggest that a photochemical evolution of the initial aliphatic and aromatic hydrocarbon mixture formed in the outflow is responsible for the changes observed in the 3 micrometers emission spectra of these objects.

Theory of extrinsic and intrinsic heterojunctions in thermal equilibrium

NASA Technical Reports Server (NTRS)

Von Ross, O.

1980-01-01

A careful analysis of an abrupt heterojunction consisting of two distinct semiconductors either intrinsic or extrinsic is presented. The calculations apply to a one-dimensional, nondegenerate structure. Taking into account all appropriate boundary conditions, it is shown that the intrinsic Fermi level shows a discontinuity at the interface between the two materials which leads to a discontinuity of the valence band edge equal to the difference in the band gap energies of the two materials. The conduction band edge stays continuous however. This result is independent of possible charged interface states and in sharp contrast to the Anderson model. The reasons for this discrepancy are discussed.

Nonlinear waves in subwavelength waveguide arrays: evanescent bands and the "phoenix soliton".

PubMed

Peleg, Or; Segev, Mordechai; Bartal, Guy; Christodoulides, Demetrios N; Moiseyev, Nimrod

2009-04-24

We formulate wave propagation in arrays of subwavelength waveguides with sharp index contrasts and demonstrate the collapse of bands into evanescent modes and lattice solitons with superluminal phase velocity. We find a self-reviving soliton ("phoenix soliton") comprised of coupled forward- and backward-propagating light, originating solely from evanescent bands. In the linear regime, all Bloch waves comprising this beam decay, whereas a proper nonlinearity assembles them into a propagating self-trapped beam. Finally, we simulate the dynamics of such a beam and observe breakup into temporal pulses, indicating a new kind of slow-light gap solitons, trapped in time and in one transverse dimension.

Si/SiGe heterointerfaces in one-, two-, and three-dimensional nanostructures: their impact on SiGe light emission

NASA Astrophysics Data System (ADS)

Lockwood, David; Wu, Xiaohua; Baribeau, Jean-Marc; Mala, Selina; Wang, Xialou; Tsybeskov, Leonid

2016-03-01

Fast optical interconnects together with an associated light emitter that are both compatible with conventional Si-based complementary metal-oxide- semiconductor (CMOS) integrated circuit technology is an unavoidable requirement for the next-generation microprocessors and computers. Self-assembled Si/Si1-xGex nanostructures, which can emit light at wavelengths within the important optical communication wavelength range of 1.3 - 1.55 μm, are already compatible with standard CMOS practices. However, the expected long carrier radiative lifetimes observed to date in Si and Si/Si1-xGex nanostructures have prevented the attainment of efficient light-emitting devices including the desired lasers. Thus, the engineering of Si/Si1-xGex heterostructures having a controlled composition and sharp interfaces is crucial for producing the requisite fast and efficient photoluminescence (PL) at energies in the range 0.8-0.9 eV. In this paper we assess how the nature of the interfaces between SiGe nanostructures and Si in heterostructures strongly affects carrier mobility and recombination for physical confinement in three dimensions (corresponding to the case of quantum dots), two dimensions (corresponding to quantum wires), and one dimension (corresponding to quantum wells). The interface sharpness is influenced by many factors such as growth conditions, strain, and thermal processing, which in practice can make it difficult to attain the ideal structures required. This is certainly the case for nanostructure confinement in one dimension. However, we demonstrate that axial Si/Ge nanowire (NW) heterojunctions (HJs) with a Si/Ge NW diameter in the range 50 - 120 nm produce a clear PL signal associated with band-to-band electron-hole recombination at the NW HJ that is attributed to a specific interfacial SiGe alloy composition. For three-dimensional confinement, the experiments outlined here show that two quite different Si1-xGex nanostructures incorporated into a Si0.6Ge0.4 wavy superlattice structure display PL of high intensity while exhibiting a characteristic decay time that is up to 1000 times shorter than that found in conventional Si/SiGe nanostructures. The non-exponential PL decay found experimentally in Si/SiGe nanostructures can be interpreted as resulting from variations in the separation distance between electrons and holes at the Si/SiGe heterointerface. The results demonstrate that a sharp Si/SiGe heterointerface acts to reduce the carrier radiative recombination lifetime and increase the PL quantum

Microscopic Distributions of Defect Luminescence From Subgrain Boundaries in Multicrystalline Silicon Wafers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nguyen, Hieu T.; Jensen, Mallory A.; Li, Li

We investigate the microscopic distributions of sub-band-gap luminescence emission (the so-called D-lines D1/D2/D3/D4) and the band-to-band luminescence intensity, near recombination-active sub-grain boundaries in multicrystalline silicon wafers for solar cells. We find that the sub-band-gap luminescence from decorating defects/impurities (D1/D2) and from intrinsic dislocations (D3/D4) have distinctly different spatial distributions, and are asymmetric across the sub-grain boundaries. The presence of D1/D2 is correlated with a strong reduction in the band-to-band luminescence, indicating a higher recombination activity. In contrast, D3/D4 emissions are not strongly correlated with the band-to-band intensity. Based on spatially-resolved, synchrotron-based micro-X-ray fluorescence measurements of metal impurities, we confirm thatmore » high densities of metal impurities are present at locations with strong D1/D2 emission but low D3/D4 emission. Finally, we show that the observed asymmetry of the sub-band-gap luminescence across the sub-grain boundaries is due to their inclination below the wafer surface. Based on the luminescence asymmetries, the sub-grain boundaries are shown to share a common inclination locally, rather than be orientated randomly.« less

Subsurface banding poultry litter impacts greenhouse gas emissions

USDA-ARS?s Scientific Manuscript database

The impact subsurface banding poultry litter (PL) has on greenhouse gas emissions is limited. Thus, a study was conducted in established bermudagrass pastures located in Coastal Plain and Piedmont regions to determine the effects subsurface applying PL has on soil flux using two different band spaci...

The 11.2 μm emission of PAHs in astrophysical objects

NASA Astrophysics Data System (ADS)

Candian, A.; Sarre, P. J.

2015-04-01

The 11.2-μm emission band belongs to the family of the `unidentified' infrared emission bands seen in many astronomical environments. In this work, we present a theoretical interpretation of the band characteristics and profile variation for a number of astrophysical sources in which the carriers are subject to a range of physical conditions. The results of Density Functional Theory calculations for the solo out-of-plane vibrational bending modes of large polycyclic aromatic hydrocarbon (PAH) molecules are used as input for a detailed emission model which includes the temperature and mass dependence of PAH band wavelength, and a PAH mass distribution that varies with object. Comparison of the model with astronomical spectra indicates that the 11.2-μm band asymmetry and profile variation can be explained principally in terms of the mass distribution of neutral PAHs with a small contribution from anharmonic effects.

Cathodoluminescence emission of REE (Dy, Pr and Eu) doped LaAlO3 phosphors

NASA Astrophysics Data System (ADS)

Boronat, C.; Rivera, T.; Garcia-Guinea, J.; Correcher, V.

2017-01-01

Luminescence emission from rare earth (REE) ions doped materials are being of interest since can be employed as scintillators, catalysts, battery and magnetic materials, etc. We herein report on the preliminary results obtained from the cathodoluminescence (CL) properties of undoped LaAlO3 (LAO) and LaAlO3: REE3+ (REE=Dy3+, Pr3+ and Eu3+) samples synthesized by a sol-gel process based on the Pechini's method with a spray-drying technique. The samples, previously characterized by means of Environmental Scanning Electron Microscopy and Energy Dispersive X-Ray Analysis Spectrometry, display CL spectra with well-defined peaks that could specifically be associated with the LAO structure (in the range of 300-450 nm) and point defects (from 450 to 800 nm) spectral regions. The observed wavebands are as follows: (i) 480 and 570 from the Dy-doped LAO correspond respectively to 4F9/2→6H15/2 and 4F9/2→6H13/2 transitions, (ii) 490-638 from the Pr-doped LAO is linked to 3P0→3H4, 1D2→3H4 transitions and (iii) 590 and 620 where the dopant Eu3+ gives rise to 5D0→7F1 and 5D0→7F2 transitions and (iv) a UV-blue broad band is associated with NBHOC in undoped LAO. Such emissions are due to the presence of the 4f electrons of rare earth ions that are shielded by the outer 5s and 5p electrons, the intra-4f emission spectra of REE that induce sharp and narrow wavebands.

Growth and Brilliant Photo-Emission of Crystalline Hexagonal Column of Alq3 Microwires

PubMed Central

Kim, Seokho; Kim, Do Hyoung; Choi, Jinho; Lee, Hojin; Kim, Sun-Young; Park, Jung Woon; Park, Dong Hyuk

2018-01-01

We report the growth and nanoscale luminescence characteristics of 8-hydroxyquinolinato aluminum (Alq3) with a crystalline hexagonal column morphology. Pristine Alq3 nanoparticles (NPs) were prepared using a conventional reprecipitation method. Crystal hexagonal columns of Alq3 were grown by using a surfactant-assisted self-assembly technique as an adjunct to the aforementioned reprecipitation method. The formation and structural properties of the crystalline and non-crystalline Alq3 NPs were analyzed with scanning electron microscopy and X-ray diffraction. The nanoscale photoluminescence (PL) characteristics and the luminescence color of the Alq3 single NPs and their crystal microwires (MWs) were evaluated from color charge-coupled device images acquired using a high-resolution laser confocal microscope. In comparison with the Alq3 NPs, the crystalline MWs exhibited a very bright and sharp emission. This enhanced and sharp emission from the crystalline Alq3 single MWs originated from effective π-π stacking of the Alq3 molecules due to strong interactions in the crystalline structure. PMID:29565306

Pulsar observations with the MAGIC Telescope

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lopez, M.; Contreras, J. L.; Otte, N.

2007-07-12

Pulsars were detected by EGRET up to energies below 20 GeV. Observations at higher energies with ground-based experiments, including MAGIC, so far failed to detect pulsars, indicating a sharp cutoff of the pulsed emission. Here we present, in particular, the results of the search for very high {gamma}-ray emission from the pulsar PSR B1951+32.

Effect of silver nanoparticles on the 1.53 μm fluorescence in Er3+/Yb3+ codoped tellurite glasses

NASA Astrophysics Data System (ADS)

Wu, Libo; Zhou, Yaxun; Zhou, Zizhong; Cheng, Pan; Huang, Bo; Yang, Fengjing; Li, Jun

2016-07-01

Improving the spectroscopic properties of rare earth (RE) doped glass materials is a challenging task. In the present work the metallic silver nanoparticles (Ag NPs) were embedded into Er3+/Yb3+ codoped tellurite glasses with composition TeO2-Bi2O3-TiO2, prepared using melt-quenching and subsequent heat-treated techniques, and the improved effect of Ag NPs on the 1.53 μm band fluorescence of Er3+ ions was investigated. About 24 h heat-treatment of Er3+/Yb3+ codoped tellurite glass containing 1 mol % amount of AgNO3 at the temperature 370 °C yielded the well-dispersed and near-spherical Ag NPs with ∼11.4 nm average diameter as evidenced by transmission electron microscopy (TEM) image. The intense 1.53 μm band fluorescence was observed in the prepared Er3+/Yb3+ codoped tellurite glasses under the excitation of 980 nm and was further improved with the presence of Ag NPs in the glass matrix, which is attributed to the enhanced local electric field around doped RE ions induced by Ag NPs and the possible energy transfer from Ag NPs to Er3+ ions. The enhanced local electric field was well demonstrated by comparing the variation of emission spectra of hypersensitive probe Eu3+ ions in tellurite glasses with and without Ag NPs. From the Judd-Ofelt analysis, it was also found that the value of Ω6 intensity parameter increased slightly with the increase of Ag NPs concentration in a certain range, also confirming the possibility of realizing strong fluorescence emission. In addition, the amorphous structural nature was demonstrated by the measured X-ray diffraction (XRD) patterns with no sharp diffraction peak. The enhanced 1.53 μm band fluorescence indicates that the Er3+/Yb3+ codoped tellurite glass with an appropriate amount of Ag NPs is a promising candidate for the development of Er3+-doped fiber amplifiers (EDFAs) applied in the WDM systems.

Chemical trends of the luminescence in wide band gap II 1-xMn xVI semimagnetic semiconductors

NASA Astrophysics Data System (ADS)

Benecke, C.; Busse, W.; Gumlich, H.-E.

1990-04-01

Time resolved emission and excitation spectroscopy is used to investigate the Mn correlated luminescence in wide band gap II-VI compounds, i.e. Zn 1-xMn xS, Cd 1-xMn xSe, Zn 1-xMn xTe and Cd 1-xMn xTe. Additional Information has been obtained with CdxZnyMnzTe( x+ y+ z=1) in checking the luminescence by variation of the ratio of the cations Cd and Zn. Generally speaking, at least two distinct emissions bands can be observed for each II 1- xMn xVI compound. One emissions band is attributed to the internal transition 4T 1(G)→ 6A 1(S) of the 3d 5 electron of the Mn 2+ on regular metal sites with energies of about ≈2 eV. The other emission band is found to occur in the near infrared range of about ≈1.3 eV. This emission band is tentatively interpreted as a transition of Mn 2+ ions on interstitial sites or in small Mn chalcogenide clusters, both interpretations assuming cubic symmetry. This model is supported by the existence of low energy excitation bands and by the great similarity of the shape of the two emission bands which lead to comparable Huang-Rhys factors and effective phonon energies. Also the established trend in the experimental data of the II-VI compounds under consideration confirm this interpretation. For both the IR and the yellow Mn 2+ center, the Racah parameters B and C and the crystal field parameter Dq are determined on the basis of experimental data. As a result, the energy of both the emission and the excitation bands is predominantly determined by the sorrounding anions. These bands shift to higher energies when the anions are changed in the fixed order: Te→Se→S. Regularly, there is also a spectral shift when Zn is replaced by Cd, which is smaller than the shift due to the variation of onions.

Do joints initiate as sharp mode I fractures or finite thickness dilatancy bands? Insights from laboratory experiments and field data

NASA Astrophysics Data System (ADS)

Petit, J.; Chemenda, A. I.; Jorand, C.

2011-12-01

Terminology on fracture and discontinuities in geological objects mainly relies on distinguishing between tabular and sharp forms of deformation localization/failure structures (Aydin et al, JSG 2006; Shultz and Fossen, AAPG, 2009). On this basis joints (considered as mode I fractures) and dilation bands (very rarely observed) are distinguished among extension discontinuities. The former propagate with the separation of the fracture walls due to strong stress concentration at the fracture tips. The plumose features or hackles typical of joints (these terms cover a wide variety of diverging fractographic features) are believed to result from the fracture front breakdown due to the loading mode change (the origin of this change remains unclear). This view is called into question by recent experimental results of extension tests conducted on a synthetic physical rock analogue (granular, frictional, cohesive and dilatant) material (GRAM1) and by field observations of embryonic (not yet open) joints in highly jointed dolomicrite Chemenda et al., JGR, 2011). The initial porosity and grain size of both materials are very different, but at SEM scale, both experimental and natural unopened discontinuities reveal a comparable dilatancy (dilation) band structure with a porosity increase over a width of several grains. This suggests that the distinction between tabular and sharp is a matter of observation scale. Both axisymetric and poly-axial extension tests show that dilatancy bands form at elevated mean stress and have plumose morphology. Mode I cracking occurs only at very low mean stres and the forming fractures do not bear plumose features. Thus the absence of plumose structures can be considered as the signature of mode I fracturing. Consequently, we propose that non- plumose bearing natural joints (provided their fractography is not eroded) could originate as mode I fractures and call them "mode I joints". We call the joints formed as closed dilatancy bands propagating at relatively high pressure (depth) conditions and generating the plumose fractography "dilatancy joints". These joints obtained in poly-axial experiments can be very tight as is also often observed in nature. Joint spacing was shown to depend on the loading conditions but not on the sample thickness, which is another argument against the mode I mechanism. There are two main reasons for which the dilatancy joints were not detected previously: (1) the dilatancy band tends to open during exhumation (it is a weakness zone) leading to the separation of the two walls with destruction of the dilatancy band texture and mineral infilling; (2) if no opening occurs, as soon as the band of increased permeability is formed, diagenetic/epigenetic processes can rapidly cancel the initial structure, the trace of the band appearing at great magnification as a tiny mineralized vein. Such transformation must be very frequent in sedimentary rocks, but it can be absent when the mineral solubility is limited, as for the dolomicrite example presented.

Chemical physics of molecules and continuous channel electron multipliers

NASA Technical Reports Server (NTRS)

Judge, D. L.

1971-01-01

The A approaches X, B approaches X and B approaches A bands of CO(+) have been excited using monochromatic photons and the band intensities measured. Using such data the variations of the electronic transition moments for these above emission bands as well as for the absorption bands have been determined. Further, the specific cross sections for the absorption processes have been determined by measuring the total emission intensity in the band system through which the upper state decays. The band intensity measurements and the derived results are presented.

Use of IRI to Model the Effect of Ionosphere Emission on Earth Remote Sensing at L-Band

NASA Technical Reports Server (NTRS)

Abraham, Saji; LeVine, David M.

2004-01-01

Microwave remote sensing in the window at 1.413 GHz (L-band) set aside for passive use only is important for monitoring sea surface salinity and soil moisture. These parameters are important for understanding ocean dynamics and energy exchange between the surface and atmosphere, and both NASA and ESA plan to launch satellite sensors to monitor these parameters at L-band (Aquarius, Hydros and SMOS). The ionosphere is an important source of error for passive remote sensing at this frequency. In addition to Faraday rotation, emission from the ionosphere is also a potential source of error at L-band. As an aid for correcting for emission, a regression model is presented that relates ionosphere emission to the integrated electron density (TEC). The goal is to use TEC from sources such as TOPEX, JASON or GPS to obtain estimates of emission over the oceans where the electron density profiles needed to compute emission are not available. In addition, data will also be presented to evaluate the use of the IRI for computing emission over the ocean.

Peripherally hydrogenated neutral polycyclic aromatic hydrocarbons as carriers of the 3 micron interstellar infrared emission complex: results from single-photon infrared emission spectroscopy

NASA Technical Reports Server (NTRS)

Wagner, D. R.; Kim, H. S.; Saykally, R. J.

2000-01-01

Infrared emission spectra of five gas-phase UV laser-excited polycyclic aromatic hydrocarbons (PAHs) containing aliphatic hydrogens are compared with the main 3.3 microns and associated interstellar unidentified infrared emission bands (UIRs). We show that neutral PAHs can account for the majority of the 3 microns emission complex while making little contribution to the other UIR bands; peripherally hydrogenated PAHs produce a better match to astrophysical data than do those containing methyl side groups; 3.4 microns plateau emission is shown to be a general spectral feature of vibrationally excited PAHs containing aliphatic hydrogens, especially those containing methyl groups; and finally, hot-band and overtone emissions arising from aromatic C-H vibrations are not observed in laboratory emission spectra, and therefore, in contrast to current assignments, are not expected to be observed in the UIRs.

Laser-induced optical breakdown spectroscopy of polymer materials based on evaluation of molecular emission bands

NASA Astrophysics Data System (ADS)

Trautner, Stefan; Jasik, Juraj; Parigger, Christian G.; Pedarnig, Johannes D.; Spendelhofer, Wolfgang; Lackner, Johannes; Veis, Pavel; Heitz, Johannes

2017-03-01

Laser-induced breakdown spectroscopy (LIBS) for composition analysis of polymer materials results in optical spectra containing atomic and ionic emission lines as well as molecular emission bands. In the present work, the molecular bands are analyzed to obtain spectroscopic information about the plasma state in an effort to quantify the content of different elements in the polymers. Polyethylene (PE) and a rubber material from tire production are investigated employing 157 nm F2 laser and 532 nm Nd:YAG laser ablation in nitrogen and argon gas background or in air. The optical detection reaches from ultraviolet (UV) over the visible (VIS) to the near infrared (NIR) spectral range. In the UV/VIS range, intense molecular emissions, C2 Swan and CN violet bands, are measured with an Echelle spectrometer equipped with an intensified CCD camera. The measured molecular emission spectra can be fitted by vibrational-rotational transitions by open access programs and data sets with good agreement between measured and fitted spectra. The fits allow determining vibrational-rotational temperatures. A comparison to electronic temperatures Te derived earlier from atomic carbon vacuum-UV (VUV) emission lines show differences, which can be related to different locations of the atomic and molecular species in the expanding plasma plume. In the NIR spectral region, we also observe the CN red bands with a conventional CDD Czerny Turner spectrometer. The emission of the three strong atomic sulfur lines between 920 and 925 nm is overlapped by these bands. Fitting of the CN red bands allows a separation of both spectral contributions. This makes a quantitative evaluation of sulfur contents in the start material in the order of 1 wt% feasible.

Structural evolution of the [(CO2)n(H2O)]- cluster anions: quantifying the effect of hydration on the excess charge accommodation motif.

PubMed

Muraoka, Azusa; Inokuchi, Yoshiya; Hammer, Nathan I; Shin, Joong-Won; Johnson, Mark A; Nagata, Takashi

2009-08-06

The [(CO2)n(H2O)]- cluster anions are studied using infrared photodissociation (IPD) spectroscopy in the 2800-3800 cm(-1) range. The observed IPD spectra display a drastic change in the vibrational band features at n = 4, indicating a sharp discontinuity in the structural evolution of the monohydrated cluster anions. The n = 2 and 3 spectra are composed of a series of sharp bands around 3600 cm(-1), which are assignable to the stretching vibrations of H2O bound to C2O4- in a double ionic hydrogen-bonding (DIHB) configuration, as was previously discussed (J. Chem. Phys. 2005, 122, 094303). In the n > or = 4 spectrum, a pair of intense bands additionally appears at approximately 3300 cm(-1). With the aid of ab initio calculations at the MP2/6-31+G* level, the 3300 cm(-1) bands are assigned to the bending overtone and the hydrogen-bonded OH vibration of H2O bound to CO2- via a single O-H...O linkage. Thus, the structures of [(CO2)n(H2O)]- evolve with cluster size such that DIHB to C2O4- is favored in the smaller clusters with n = 2 and 3 whereas CO2- is preferentially stabilized via the formation of a single ionic hydrogen-bonding (SIHB) configuration in the larger clusters with n > or = 4.

Thermal emission and absorption of radiation in finite inverted-opal photonic crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Florescu, Marian; Stimpson, Andrew J.; Lee, Hwang

We study theoretically the optical properties of a finite inverted-opal photonic crystal. The light-matter interaction is strongly affected by the presence of the three-dimensional photonic crystal and the alterations of the light emission and absorption processes can be used to suppress or enhance the thermal emissivity and absorptivity of the dielectric structure. We investigate the influence of the absorption present in the system on the relevant band edge frequencies that control the optical response of the photonic crystal. Our study reveals that the absorption processes cause spectral broadening and shifting of the band edge optical resonances, and determine a strongmore » reduction of the photonic band gap spectral range. Using the angular and spectral dependence of the band edge frequencies for stop bands along different directions, we argue that by matching the blackbody emission spectrum peak with a prescribed maximum of the absorption coefficient, it is possible to achieve an angle-sensitive enhancement of the thermal emission/absorption of radiation. This result opens a way to realize a frequency-sensitive and angle-sensitive photonic crystal absorbers/emitters.« less

Thermal emission from a metamaterial wire medium slab.

PubMed

D'Aguanno, G; Mattiucci, N; Alù, A; Argyropoulos, C; Foreman, J V; Bloemer, M J

2012-04-23

We investigate thermal emission from a metamaterial wire medium embedded in a dielectric host and highlight two different regimes for efficient emission, respectively characterized by broadband emission near the effective plasma frequency of the metamaterial, and by narrow-band resonant emission at the band-edge in the Bragg scattering regime. We discuss how to control the spectral position and relative strength of these two emission mechanisms by varying the geometrical parameters of the proposed metamaterial and its temperature. © 2012 Optical Society of America

Dynamics of a Sonoluminescing Bubble in Sulfuric Acid

NASA Astrophysics Data System (ADS)

Hopkins, Stephen D.; Putterman, Seth J.; Kappus, Brian A.; Suslick, Kenneth S.; Camara, Carlos G.

2005-12-01

The spectral shape and observed sonoluminescence emission from Xe bubbles in concentrated sulfuric acid is consistent only with blackbody emission from a spherical surface that fills the bubble. The interior of the observed 7000 K blackbody must be at least 4 times hotter than the emitting surface in order that the equilibrium light-matter interaction length be smaller than the radius. Bright emission is correlated with long emission times (˜10ns), sharp thresholds, unstable translational motion, and implosions that are sufficiently weak that contributions from the van der Waals hard core are small.

Dynamics of a sonoluminescing bubble in sulfuric acid.

PubMed

Hopkins, Stephen D; Putterman, Seth J; Kappus, Brian A; Suslick, Kenneth S; Camara, Carlos G

2005-12-16

The spectral shape and observed sonoluminescence emission from Xe bubbles in concentrated sulfuric acid is consistent only with blackbody emission from a spherical surface that fills the bubble. The interior of the observed 7000 K blackbody must be at least 4 times hotter than the emitting surface in order that the equilibrium light-matter interaction length be smaller than the radius. Bright emission is correlated with long emission times (approximately 10 ns), sharp thresholds, unstable translational motion, and implosions that are sufficiently weak that contributions from the van der Waals hard core are small.

A parametric study of the linear growth of magnetospheric EMIC waves in a hot plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Qi; Cao, Xing; Gu, Xudong, E-mail: guxudong@whu.edu.cn, E-mail: bbni@whu.edu.cn

2016-06-15

Since electromagnetic ion cyclotron (EMIC) waves in the terrestrial magnetosphere play a crucial role in the dynamic losses of relativistic electrons and energetic protons and in the ion heating, it is important to pursue a comprehensive understanding of the EMIC wave dispersion relation under realistic circumstances, which can shed significant light on the generation, amplification, and propagation of magnetospheric EMIC waves. The full kinetic linear dispersion relation is implemented in the present study to evaluate the linear growth of EMIC waves in a multi-ion (H{sup +}, He{sup +}, and O{sup +}) magnetospheric plasma that also consists of hot ring currentmore » protons. Introduction of anisotropic hot protons strongly modifies the EMIC wave dispersion surface and can result in the simultaneous growth of H{sup +}-, He{sup +}-, and O{sup +}-band EMIC emissions. Our parametric analysis demonstrates that an increase in the hot proton concentration can produce the generation of H{sup +}- and He{sup +}-band EMIC waves with higher possibility. While the excitation of H{sup +}-band emissions requires relatively larger temperature anisotropy of hot protons, He{sup +}-band emissions are more likely to be triggered in the plasmasphere or plasmaspheric plume where the background plasma is denser. In addition, the generation of He{sup +}-band waves is more sensitive to the variation of proton temperature than H{sup +}-band waves. Increase of cold heavy ion (He{sup +} and O{sup +}) density increases the H{sup +} cutoff frequency and therefore widens the frequency coverage of the stop band above the He{sup +} gyrofrequency, leading to a significant damping of H{sup +}-band EMIC waves. In contrast, O{sup +}-band EMIC waves characteristically exhibit the temporal growth much weaker than the other two bands, regardless of all considered variables, suggesting that O{sup +}-band emissions occur at a rate much lower than H{sup +}- and He{sup +}-band emissions, which is consistent with the observations.« less

[Preparation and photoluminescence study of Er3+ : Y2O3 transparent ceramics].

PubMed

Luo, Jun-ming; Li, Yong-xiu; Deng, Li-ping

2008-10-01

Y2O3 acted as the matrix material, which was doped with different concentrations of Er3+, Er3+ : Y2O3 nanocrystalline powder was prepared by co-precipitation method, and Er3+ : Y2O3 transparent ceramics was fabricated by vacuum sintering at 1700 degrees C, 1 x 10(-3) Pa for 8 h. By using the X-ray diffraction (D/MAX-RB), transmission electron microscopy(Philips EM420), automatic logging spectrophotometer(DMR-22), fluorescence analyzer (F-4500) and 980 nm diode laser, the structural, morphological and luminescence properties of the sample were investigated. The results show that Er3+ dissolved completely in the Y2O3 cubic phase, the precursor was amorphous, weak diffraction peaks appeared after calcination at 400 degrees C, and if calcined at 700 degrees C, the precursor turned to pure cubic phase. With increasing the calcining temperature, the diffraction peaks became sharp quickly, and when the calcining temperature reached 1100 degrees C, the diffraction peaks became very sharp, indicating that the grains were very large. The particles of Er+ : Y2O3 is homogeneous and nearly spherical, the average diameter of the particles is in the range of 40-60 nm after being calcined at 1000 degrees C for 2 h. The relative density of Er3+ : Y2O3 transparent ceramics is 99.8%, the transmittance of the Er2+ : Y2O3 transparent ceramics is markedly lower than the single crystal at the short wavelength, but the transmittance is improved noticeably with increasing the wavelength, and the transmittance exceeds 60% at the wavelength of 1200 nm. Excited under the 980 nm diode laser, there are two main up-conversion emission bands, green emission centers at 562 nm and red emission centers at 660 nm, which correspond to (4)S(3/2) / (2)H(11/2) - (4)I(15/2) and (4)F(9/2) - (4)I(15/2) radiative transitions respectively. By changing the doping concentrations of Er3+, the color of up-conversion luminescence can be tuned from green to red gradually. The luminescence intensity is not reinforce with the increase in the concentration, so the doping concentration of Er3+ should not exceed 2%. If the doping concentration of Er3+ exceeds the range, the concentration has very small effect on the improvement of luminescence intensity.

High-frequency tone-pip-evoked otoacoustic emissions in chinchillas

NASA Astrophysics Data System (ADS)

Siegel, Jonathan H.; Charaziak, Karolina K.

2015-12-01

We measured otoacoustic emissions in anesthetized chinchillas evoked by short (1 ms) high-frequency (4 kHz) tone-pips (TEOAE) using either a compression or suppression method to separate the stimulus from the emission. Both methods revealed consistent features of the TEOAEs. The main spectral band of the emission generally corresponded to the spectrum of the stimulus, exhibiting a group delay similar to that of SFOAEs [9]. However, a second spectral band below 1.5 kHz, clearly separated from the low-frequency cut-off frequency of the stimulus spectrum, corresponded to an amplitude modulation of the waveform of the TEOAE. The group delay of this low-frequency band was similar to that of the main band near the probe frequency. The average level and group delay of the main band declined monotonically when revealed as the suppressor frequency was raised above the probe. The low-frequency band was more sensitive than the main band to shifts in compound action potential thresholds near the probe frequency induced by acute exposure to intense tones. Taken together, the experiments indicate that both the main and low-frequency bands of the TEOAE are generated primarily near the cochlear region maximally stimulated by the probe, but that significant contributions arise over a large region even more basal.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mezdrogina, M. M., E-mail: Margaret.m@mail.ioffe.ru; Vinogradov, A. Ya.; Kuzmin, R. V.

For ZnO films, nanorods, and bulk single crystals doped with Er{sup +} ions, it is shown that the effect of codopants introduced into the cation and ion sublattices and the observation of a high-intensity emission band at the wavelength λ{sub max} = 1535 nm are defined by the local environment of the Er{sup +} ion. Doping of the films and single crystals with Er{sup +} ions by diffusion brings about an infrared (IR) emission band with a low intensity because of an inadequate concentration of impurity ions. The emission intensity of this band can be raised by introducing additional Ag,more » Au, or N{sup +} impurities into the ZnO films. The UV-emission intensity of the Er-doped films and single crystals at λ{sub max} = 368–372 nm is identical to that of the undoped films. ZnO nanorods doped with Er only or together with Al or Ga codopants exhibit only one IR band (at λ{sub max} = 1535 nm), whose intensity decreases upon the introduction of codopants. Doping of the nanorods with the N{sup +} gaseous impurity during growth (930 < T < 960°C) and then with the Er{sup +} impurity by diffusion does not yield a substantial increase in the IR-emission intensity compared to the that of the corresponding band for nanorods not doped with the N{sup +} impurity. In the Er-doped nanorods, whose photoluminescence spectra exhibit a high-intensity band at λ{sub max} = 1535 nm, the UV emission band at λ{sub max} = 372 nm is practically lacking.« less

GW Orionis: Inner disk readjustments in a triple system

NASA Astrophysics Data System (ADS)

Fang, M.; Sicilia-Aguilar, A.; Roccatagliata, V.; Fedele, D.; Henning, Th.; Eiroa, C.; Müller, A.

2014-10-01

Context. Disks are expected to dissipate quickly in binary or multiple systems. Investigating such systems can improve our knowledge of the disk dispersal. The triple system GW Ori, still harboring a massive disk, is an excellent target. Aims: We study the young stellar system GW Ori, concentrating on its accretion, wind activity and disk properties. Methods: We use high-resolution optical spectra of GW Ori to do spectral classification and derive the radial velocities (RV). We analyze the wind and accretion activity using the emission lines in the spectra. We also use U-band photometry, which has been collected from the literature, to study the accretion variability of GW Ori. We characterize the disk properties of GW Ori by modeling its spectral energy distribution (SED). Results.By comparing our data to the synthetical spectra, we classify GW Ori as a G8 star. Based on the RVs derived from the optical spectra, we confirm the previous result as a close companion in GW Ori with a period of ~242 days and an orbital semi-major axis of ~1 AU. The RV residuals after the subtraction of the orbital solution with the equivalent widths (EW) of accretion-related emission lines vary with periods of 5-6.7 days during short-time intervals, which are caused by the rotational modulation. The Hα and Hβ line profiles of GW Ori can be decomposed in two central-peaked emission components and one blue-shifted absorption component. The blue-shifted absorption components are due to a disk wind modulated by the orbital motion of the close companion. Therefore, the systems like GW Ori can be used to study the extent of disk winds. We find that the accretion rates of GW Ori are rather constant but can occasionally be enhanced by a factor of 2-3. We reproduce the SED of GW Ori by using disk models with gaps ~25-55 AU in size. A small population of tiny dust particles within the gap produces the excess emission at near-infrared bands and the strong and sharp silicate feature at 10 μm. The SED of GW Ori exhibits dramatic changes on timescales of ~20 yr in the near-infrared bands, which can be explained as the change in the amount and distribution of small dust grains in the gap. We collect a sample of binary/multiple systems with disks in the literature and find a strong positive correlation between their gap sizes and separations from the primaries to companions, which is generally consistent with the prediction from the theory. Table 4 is available in electronic form at http://www.aanda.org

PROBING THE IONIZATION STATES OF POLYCYCLIC AROMATIC HYDROCARBONS VIA THE 15–20 μm EMISSION BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shannon, M. J.; Stock, D. J.; Peeters, E., E-mail: mshann3@uwo.ca

2015-10-01

We report new correlations between ratios of band intensities of the 15–20 μm emission bands of polycyclic aromatic hydrocarbons (PAHs) in a sample of 57 sources observed with the Spitzer/Infrared Spectrograph. This sample includes Large Magellanic Cloud point sources from the SAGE-Spec survey, nearby galaxies from the Spitzer Infrared Nearby Galaxies Survey survey, two Galactic interstellar medium cirrus sources, and the spectral maps of the Galactic reflection nebulae NGC 2023 and NGC 7023. We find that the 16.4, 17.4, and 17.8 μm band intensities are inter-correlated in all environments. In NGC 2023 and NGC 7023 these bands also correlate withmore » the 11.0 and 12.7 μm band intensities. The 15.8 μm band correlates only with the 15–18 μm plateau and the 11.2 μm emission. We examine the spatial morphology of these bands and introduce radial cuts. We find that these bands can be spatially organized into three sets: the 12.7, 16.4, and 17.8 μm bands; the 11.2, 15.8 μm bands and the 15–18 μm plateau; and the 11.0 and 17.4 μm bands. We also find that the spatial distribution of the 12.7, 16.4, and 17.8 μm bands can be reconstructed by averaging the spatial distributions of the cationic 11.0 μm and neutral 11.2 μm bands. We conclude that the 17.4 μm band is dominated by cations, the 15.8 μm band by neutral species, and the 12.7, 16.4, and 17.8 μm bands by a combination of the two. These results highlight the importance of PAH ionization for spatially differentiating sub-populations by their 15–20 μm emission variability.« less

Calibration of VIIRS F1 Sensor Fire Detection Band Using lunar Observations

NASA Technical Reports Server (NTRS)

McIntire, Jeff; Efremova, Boryana; Xiong, Xiaoxiong

2012-01-01

Visible Infrared Imager Radiometer Suite (VIIRS) Fight 1 (Fl) sensor includes a fire detection band at roughly 4 microns. This spectral band has two gain states; fire detection occurs in the low gain state above approximately 345 K. The thermal bands normally utilize an on-board blackbody to provide on-orbit calibration. However, as the maximum temperature of this blackbody is 315 K, the low gain state of the 4 micron band cannot be calibrated in the same manner as the rest of the thermal bands. Regular observations of the moon provide an alternative calibration source. The lunar surface temperature has been recently mapped by the DIVINER sensor on the LRO platform. The periodic on-board high gain calibration along with the DIVINER surface temperatures was used to determine the emissivity and solar reflectance of the lunar surface at 4 microns; these factors and the lunar data are then used to fit the low gain calibration coefficients of the 4 micron band. Furthermore, the emissivity of the lunar surface is well known near 8.5 microns due to the Christiansen feature (an emissivity maximum associated with Si-O stretching vibrations) and the solar reflectance is negligible. Thus, the 8.5 micron band is used for relative calibration with the 4 micron band to de-trend any temporal variations. In addition, the remaining thermal bands are analyzed in a similar fashion, with both calculated emissivities and solar reflectances produced.

Sub-band gap photo-enhanced secondary electron emission from high-purity single-crystal chemical-vapor-deposited diamond

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yater, J. E., E-mail: joan.yater@nrl.navy.mil; Shaw, J. L.; Pate, B. B.

2016-02-07

Secondary-electron-emission (SEE) current measured from high-purity, single-crystal (100) chemical-vapor-deposited diamond is found to increase when sub-band gap (3.06 eV) photons are incident on the hydrogenated surface. Although the light does not produce photoemission directly, the SEE current increases by more than a factor of 2 before saturating with increasing laser power. In energy distribution curves (EDCs), the emission peak shows a corresponding increase in intensity with increasing laser power. However, the emission-onset energy in the EDCs remains constant, indicating that the bands are pinned at the surface. On the other hand, changes are observed on the high-energy side of the distributionmore » as the laser power increases, with a well-defined shoulder becoming more pronounced. From an analysis of this feature in the EDCs, it is deduced that upward band bending is present in the near-surface region during the SEE measurements and this band bending suppresses the SEE yield. However, sub-band gap photon illumination reduces the band bending and thereby increases the SEE current. Because the bands are pinned at the surface, we conclude that the changes in the band levels occur below the surface in the electron transport region. Sample heating produces similar effects as observed with sub-band gap photon illumination, namely, an increase in SEE current and a reduction in band bending. However, the upward band bending is not fully removed by either increasing laser power or temperature, and a minimum band bending of ∼0.8 eV is established in both cases. The sub-band gap photo-excitation mechanism is under further investigation, although it appears likely at present that defect or gap states play a role in the photo-enhanced SEE process. In the meantime, the study demonstrates the ability of visible light to modify the electronic properties of diamond and enhance the emission capabilities, which may have potential impact for diamond-based vacuum electron sources, particle detectors, and other electronic devices.« less

Spectrally resolved localized states in GaAs 1– xBi x

DOE PAGES

Christian, Theresa M.; Alberi, Kirstin; Beaton, Daniel A.; ...

2017-02-01

In this study, the role of localized states and their influence on the broader band structure remains a crucial question in understanding the band structure evolution in GaAs 1-xBi x. Here in this work, we present clear spectroscopic observations of recombination at several localized states in GaAs 1-xBi x. Sharp and recognizable photoluminescence features appear in multiple samples and redshift as a function of GaBi fraction between x = 0.16% and 0.4% at a linearized rate of 34 meV per % Bi, weaker than the redshift associated with band-to-band recombination. Interpreting these results in terms of radiative recombination between localizedmore » holes and free electrons sheds light on the relative movement of the conduction band minimum and the characteristics of localized bismuth-related trap states in GaAs 1-xBi x alloys.« less

SEM, EDX, Infrared and Raman spectroscopic characterization of the silicate mineral yuksporite

NASA Astrophysics Data System (ADS)

Frost, Ray L.; López, Andrés; Scholz, Ricardo; Theiss, Frederick L.; Romano, Antônio Wilson

2015-02-01

The mineral yuksporite (K,Ba)NaCa2(Si,Ti)4O11(F,OH)ṡH2O has been studied using the combination of SEM with EDX and vibrational spectroscopic techniques of Raman and infrared spectroscopy. Scanning electron microscopy shows a single pure phase with cleavage fragment up to 1.0 mm. Chemical analysis gave Si, Al, K, Na and Ti as the as major elements with small amounts of Mn, Ca, Fe and REE. Raman bands are observed at 808, 871, 930, 954, 980 and 1087 cm-1 and are typical bands for a natural zeolite. Intense Raman bands are observed at 514, 643 and 668 cm-1. A very sharp band is observed at 3668 cm-1 and is attributed to the OH stretching vibration of OH units associated with Si and Ti. Raman bands resolved at 3298, 3460, 3562 and 3628 cm-1 are assigned to water stretching vibrations.

Polaron physics and crossover transition in magnetite probed by pressure-dependent infrared spectroscopy.

PubMed

Ebad-Allah, J; Baldassarre, L; Sing, M; Claessen, R; Brabers, V A M; Kuntscher, C A

2013-01-23

The optical properties of magnetite at room temperature were studied by infrared reflectivity measurements as a function of pressure up to 8 GPa. The optical conductivity spectrum consists of a Drude term, two sharp phonon modes, a far-infrared band at around 600 cm(-1) and a pronounced mid-infrared absorption band. With increasing pressure both absorption bands shift to lower frequencies and the phonon modes harden in a linear fashion. Based on the shape of the MIR band, the temperature dependence of the dc transport data, and the occurrence of the far-infrared band in the optical conductivity spectrum, the polaronic coupling strength in magnetite at room temperature should be classified as intermediate. For the lower energy phonon mode an abrupt increase of the linear pressure coefficient occurs at around 6 GPa, which could be attributed to minor alterations of the charge distribution among the different Fe sites.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zheng, Zhang; Wanjun, Tang, E-mail: tangmailbox@126.com

Highlights: • Iso-structural garnet-type Na{sub 2}(Y,Eu)Mg{sub 2}V{sub 3}O{sub 12} solid solution were synthesized. • Efficient energy transfer from [VO{sub 4}]{sup 3−} to Eu{sup 3+} ions in this phosphor is observed obviously. • Tuning the Y/Eu ratio generates the varied hues from yellowish-green to reddish-orange. • This kind of phosphor can be potentially used in UV pumped LEDs. - Abstract: A series of solid-solution phosphors Na{sub 2}(Y,Eu)Mg{sub 2}V{sub 3}O{sub 12} were prepared using solution combustion reaction. X-ray diffraction studies verified the formation of single phase Na{sub 2}(Y,Eu)Mg{sub 2}V{sub 3}O{sub 12} with garnet structure. Na{sub 2}(Y,Eu)Mg{sub 2}V{sub 3}O{sub 12} phosphors show notmore » only a broad emission band with a maximum at 510 nm due to the [VO{sub 4}]{sup 3−} group but also several sharp emission lines due to the Eu{sup 3+} ions. The energy transfer from [VO{sub 4}]{sup 3−} to Eu{sup 3+} was discussed on the base of the spectral analysis. The color-tunable emissions of the Na{sub 2}(Y,Eu)Mg{sub 2}V{sub 3}O{sub 12} phosphor as a function of Y/Eu ratio are realized by continuously generating the varied hues from yellowish-green to reddish-orange. This indicates that the obtained phosphor may have potential applications in the field of UV-based white LEDs.« less

GRB 091127: The Cooling Break Race on Magnetic Fuel

NASA Technical Reports Server (NTRS)

Filgas, R.; Greiner, J.; Schady, P.; Kruhler, T.; Updike, A. C.; Klose, S.; Nardini, M.; Kann, D. A.; Rossi, A.; Sudilovsky, V.;

Spectral modification of the laser emission of a terahertz quantum cascade laser induced by broad-band double pulse injection seeding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Markmann, Sergej, E-mail: sergej.markmann@ruhr-uni-bochum.de; Nong, Hanond, E-mail: nong.hanond@ruhr-uni-bochum.de; Hekmat, Negar

2015-09-14

We demonstrate by injection seeding that the spectral emission of a terahertz (THz) quantum cascade laser (QCL) can be modified with broad-band THz pulses whose bandwidths are greater than the QCL bandwidth. Two broad-band THz pulses delayed in time imprint a modulation on the single THz pulse spectrum. The resulting spectrum is used to injection seed the THz QCL. By varying the time delay between the THz pulses, the amplitude distribution of the QCL longitudinal modes is modified. By applying this approach, the QCL emission is reversibly switched from multi-mode to single mode emission.

A new metamaterial-based wideband rectangular invisibility cloak

NASA Astrophysics Data System (ADS)

Islam, S. S.; Hasan, M. M.; Faruque, M. R. I.

2018-02-01

A new metamaterial-based wideband electromagnetic rectangular cloak is being introduced in this study. The metamaterial unit cell shows sharp transmittances in the C- and X-bands and displays wideband negative effective permittivity region there. The metamaterial unit cell was then applied in designing a rectangular-shaped electromagnetic cloak. The scattering reduction technique was adopted for the cloaking operation. The cloak operates in the certain portion of C-and X-bands that covers more than 4 GHz bandwidth region. The experimental results were provided as well for the metamaterial and the cloak.

Structural and Optical Behaviour of Ar+ Implanted Polycarbonate

NASA Astrophysics Data System (ADS)

Shekhawat, Nidhi; Aggarwal, Sanjeev; Sharma, Annu; Deshpande, S. K.; Nair, K. G. M.

2011-07-01

Effects of 130 keV Ar+ ion implantation on the structural and optical properties of polycarbonate specimens have been studied using Raman, UV-Visible spectroscopy and glancing angle X-ray diffraction techniques. Formation of disordered carbonaceous network in the implanted layers has been observed using Raman and UV-Visible spectroscopy. A sharp decline in band gap values (4.1 eV to 0.63 eV) with increase in implantation dose has been observed. This decrease in optical band gap has been correlated with the formation of disordered structures in the implanted layers of polycarbonate.

Highly selective and sensitive detection of metal ions and nitroaromatic compounds by an anionic europium(iii) coordination polymer.

PubMed

Feyisa Bogale, Raji; Ye, Junwei; Sun, Yuan; Sun, Tongxin; Zhang, Siqi; Rauf, Abdul; Hang, Cheng; Tian, Peng; Ning, Guiling

2016-07-05

A luminescent Eu(iii)-based coordination polymer, {[Eu(H2O)5(BTEC)][H(C5H6N2)]·3H2O} () has been synthesized under hydrothermal conditions using 1,2,4,5-benzenetetracarboxylic acid (H4BTEC) as a linker. Compound possesses an anionic zig-zag chain constructed from the BTEC ligands and [EuO4(H2O)5] nodes. The protonated 4-aminopyridine groups as guests are located between chains. exhibits the characteristic sharp emission bands of Eu(3+) at 578, 593, 615, 652 and 693 nm upon excitation at 290 nm. The strong emission of could be quenched effectively by trace amounts of Fe(3+) ions even in the presence of other metal ions including Al(3+), Ca(2+), Cd(2+), Co(2+), Cr(3+), Cu(2+), Fe(2+), K(+), Mg(2+), Mn(2+), Pd(2+) and Zn(2+). Similarly, also exhibits superior selectivity and sensitivity towards 4-nitrophenol (4-NP) compared with other competing interfering analytes, such as 2,4,6-trinitrophenol, 2,6-dinitrotolune, 4-nitrotoluene, nitrobenzene, 1,3-dinitrobenzene, o-xylene, nitromethane, nitropropane, phenol, 4-bromophenol and bromobenzene, through a fluorescence quenching mechanism. The possible fluorescence quenching mechanisms are discussed. Moreover, could be used as a visual fluorescent test paper for selectively detecting trace amounts of Fe(3+) and 4-NP.

Heat-induced reorganization of the structure of photosystem II membranes: role of oxygen evolving complex.

PubMed

Busheva, Mira; Tzonova, Iren; Stoitchkova, Katerina; Andreeva, Atanaska

2012-12-05

The sensitivity of the green plants' photosystem II (PSII) to high temperatures is investigated in PSII enriched membranes and in membranes, from which the oxygen evolving complex is removed. Using steady-state 77 K fluorescence and resonance Raman spectroscopy we analyze the interdependency between the temperature-driven changes in structure and energy distribution in the PSII supercomplex. The results show that the heat treatment induces different reduction of the 77 K fluorescence emission in both types of investigated membranes: (i) an additional considerable decrease of the overall fluorescence emission in Tris-washed membranes as compared to the native membranes; (ii) a transition point at 42°C(,) observed only in native membranes; (iii) a sharp reduction of the PSII core fluorescence in Tris-washed membranes at temperatures higher than 50°C; (iv) a 3 nm red-shift of F700 band's maximum in Tris-washed membranes already at 20°C and its further shift by 1 nm at temperature increase. Both treatments intensified their action by increasing the aggregation and dissociation of the peripheral light harvesting complexes. The oxygen-evolving complex, in addition to its main function to produce O(2), increases the thermal stability of PSII core by strengthening the connection between the core and the peripheral antenna proteins and by keeping their structural integrity. Copyright © 2012 Elsevier B.V. All rights reserved.

Unique light-induced degradation in yellow-emitting K₂SiF₆:Mn²⁺ phosphor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oyama, Takuya; Adachi, Sadao, E-mail: adachi@el.gunma-u.ac.jp

2014-10-07

Photo-induced luminescence intensity degradation in yellow-emitting K₂SiF₆:Mn²⁺ phosphor is studied using x-ray diffraction measurement, photoluminescence (PL) analysis, PL excitation (PLE) spectroscopy, PL decay analysis, and electron spin resonance (ESR) measurement. The yellow-emitting K₂SiF₆:Mn²⁺ phosphor exhibits remarkable degradation in the PL intensity under Xe lamp exposure. Coherent laser irradiation also induces degradation and its degree is in the order of He–Cd (λ = 325 nm) > Ar⁺ (488 nm) > He–Ne laser (632.8 nm). The degradation mechanism is proposed to be due to change in the valence state of manganese ions from Mn²⁺ to Mn³⁺ by the photooxidation (Mn²⁺ → Mn³⁺)more » or disproportionation reaction (2Mn²⁺ → Mn⁺ + Mn³⁺). The ESR measurement confirms the decreased Mn²⁺ spin density in the sample exposed with Xe lamp. The PLE spectrum suggests that the excitation of Mn³⁺ ions occurs through energy transfer upon absorption of exciting radiation by the Mn²⁺ ions. Thermal annealing of the degraded samples at ≥200 °C causes a blueshift in the PL emission band with an appearance of the Mn⁴⁺-related sharp red emission lines.« less

Large-scale uniform ZnO tetrapods on catalyst free glass substrate by thermal evaporation method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alsultany, Forat H., E-mail: foratusm@gmail.com; Hassan, Z.; Ahmed, Naser M.

2016-07-15

Highlights: • Investigate the growth of ZnO-Ts on glass substrate by thermal evaporation method. • Glass substrate without any catalyst or a seed layer. • The morphology was controlled by adjusting the temperature of the material and the substrate. • Glass substrate was placed vertically in the quartz tube. - Abstract: Here, we report for the first time the catalyst-free growth of large-scale uniform shape and size ZnO tetrapods on a glass substrate via thermal evaporation method. Three-dimensional networks of ZnO tetrapods have needle–wire junctions, an average leg length of 2.1–2.6 μm, and a diameter of 35–240 nm. The morphologymore » and structure of ZnO tetrapods were investigated by controlling the preparation temperature of each of the Zn powder and the glass substrate under O{sub 2} and Ar gases. Studies were carried out on ZnO tetrapods using X-ray diffraction, field emission scanning electron microscopy, UV–vis spectrophotometer, and a photoluminescence. The results showed that the sample grow in the hexagonal wurtzite structure with preferentially oriented along (002) direction, good crystallinity and high transmittance. The band gap value is about 3.27 eV. Photoluminescence spectrum exhibits a very sharp peak at 378 nm and a weak broad green emission.« less

Polarization Characteristics of Zebra Patterns in Type IV Solar Radio Bursts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaneda, K.; Misawa, H.; Tsuchiya, F.

The polarization characteristics of zebra patterns (ZPs) in type IV solar bursts were studied. We analyzed 21 ZP events observed by the Assembly of Metric-band Aperture Telescope and Real-time Analysis System between 2010 and 2015 and identified the following characteristics: a degree of circular polarization (DCP) in the range of 0%–70%, a temporal delay of 0–70 ms between the two circularly polarized components (i.e., the right- and left-handed components), and dominant ordinary-mode emission in about 81% of the events. For most events, the relation between the dominant and delayed components could be interpreted in the framework of fundamental plasma emissionmore » and depolarization during propagation, though the values of DCP and delay were distributed across wide ranges. Furthermore, it was found that the DCP and delay were positively correlated (rank correlation coefficient R = 0.62). As a possible interpretation of this relationship, we considered a model based on depolarization due to reflections at sharp density boundaries assuming fundamental plasma emission. The model calculations of depolarization including multiple reflections and group delay during propagation in the inhomogeneous corona showed that the DCP and delay decreased as the number of reflections increased, which is consistent with the observational results. The dispersive polarization characteristics could be explained by the different numbers of reflections causing depolarization.« less

Band-to-Band Tunneling-Dominated Thermo-Enhanced Field Electron Emission from p-Si/ZnO Nanoemitters.

PubMed

Huang, Zhizhen; Huang, Yifeng; Xu, Ningsheng; Chen, Jun; She, Juncong; Deng, Shaozhi

2018-06-13

Thermo-enhancement is an effective way to achieve high performance field electron emitters, and enables the individually tuning on the emission current by temperature and the electron energy by voltage. The field emission current from metal or n-doped semiconductor emitter at a relatively lower temperature (i.e., < 1000 K) is less temperature sensitive due to the weak dependence of free electron density on temperature, while that from p-doped semiconductor emitter is restricted by its limited free electron density. Here, we developed full array of uniform individual p-Si/ZnO nanoemitters and demonstrated the strong thermo-enhanced field emission. The mechanism of forming uniform nanoemitters with well Si/ZnO mechanical joint in the nanotemplates was elucidated. No current saturation was observed in the thermo-enhanced field emission measurements. The emission current density showed about ten-time enhancement (from 1.31 to 12.11 mA/cm 2 at 60.6 MV/m) by increasing the temperature from 323 to 623 K. The distinctive performance did not agree with the interband excitation mechanism but well-fit to the band-to-band tunneling model. The strong thermo-enhancement was proposed to be benefit from the increase of band-to-band tunneling probability at the surface portion of the p-Si/ZnO nanojunction. This work provides promising cathode for portable X-ray tubes/panel, ionization vacuum gauges and low energy electron beam lithography, in where electron-dose control at a fixed energy is needed.

Extended infrared emission around IRAS 21282 + 5050

NASA Technical Reports Server (NTRS)

Bregman, Jesse D.; Booth, John; Gilmore, D. K.; Kay, Laura; Rank, David

1992-01-01

Multiaperture 3-4-micron spectra along with K- and L-band images of the compact planetary nebula IRAS 21282 + 5050 show a 5 arcsec - 20 arcsec diameter nebula with structure similar to many other planetary nebulae. The spectral observations and the L-band image show evidence for extended PAH emission out to a radius of 20 arcsec, while the K-band image shows a 5 arcsec diameter nebula. An observed linear increase of integrated brightness with aperture size at L band implies a 1/r exp 2 volume emissivity for a spherically symmetric model. The spectral similarity of the emission in the small and large apertures suggests fluorescent emission by the PAHs. If the observed emission is from PAHs which formed during the planetary nebulae stage of IRAs 21282 + 5050, then PAHs have been forming for not less than 3000 yr. If the PAH emission is from material produced during the earlier red giant phase, then the formation time frame was much longer. The morphological and spectral similarity of IRAS 21282 + 5050 to many other planetary nebulae suggests that this phenomenon may be widespread, and that planetary nebulae may be a significant source of interstellar PAHs.

A Ratio-Analysis Method to the Dynamics of Excited State Proton Transfer: Pyranine in Water and Micelles.

PubMed

Sahu, Kalyanasis; Nandi, Nilanjana; Dolai, Suman; Bera, Avisek

2018-06-05

Emission spectrum of a fluorophore undergoing excited state proton transfer (ESPT) often exhibits two distinct bands each representing emissions from protonated and deprotonated forms. The relative contribution of the two bands, best represented by an emission intensity ratio (R) (intensity maximum of the protonated band / intensity maximum of the deprotonated band), is an important parameter which usually denotes feasibility or promptness of the ESPT process. However, the use of ratio is only limited to the interpretation of steady-state fluorescence spectra. Here, for the first time, we exploit the time-dependence of the ratio (R(t)), calculated from time-resolved emission spectra (TRES) at different times, to analyze ESPT dynamics. TRES at different times were fitted with a sum of two lognormal-functions representing each peaks and then, the peak intensity ratio, R(t) was calculated and further fitted with an analytical function. Recently, a time-resolved area-normalized emission spectra (TRANES)-based analysis was presented where the decay of protonated emission or the rise of deprotonated emission intensity conveniently accounts for the ESPT dynamics. We show that these two methods are equivalent but the new method provides more insights on the nature of the ESPT process.

Secular trends in Cherokee cranial morphology: Eastern vs Western bands.

PubMed

Sutphin, Rebecca; Ross, Ann H; Jantz, Richard L

2014-01-01

The research objective was to examine if secular trends can be identified for cranial data commissioned by Boas in 1892, specifically for cranial breadth and cranial length of the Eastern and Western band Cherokee who experienced environmental hardships. Multiple regression analysis was used to test the degree of relationship between each of the cranial measures: cranial length, cranial breadth and cephalic index, along with predictor variables (year-of-birth, location, sex, admixture); the model revealed a significant difference for all craniometric variables. Additional regression analysis was performed with smoothing Loess plots to observe cranial length and cranial breadth change over time (year-of-birth) separately for Eastern and Western Cherokee band females and males born between 1783-1874. This revealed the Western and Eastern bands show a decrease in cranial length over time. Eastern band individuals maintain a relatively constant head breadth, while Western Band individuals show a sharp decline beginning around 1860. These findings support negative secular trend occurring for both Cherokee bands where the environment made a detrimental impact; this is especially marked with the Western Cherokee band.

Infrared emission spectra of candidate interstellar aromatic molecules

NASA Technical Reports Server (NTRS)

Schlemmer, S.; Balucani, N.; Wagner, D. R.; Steiner, B.; Saykally, R. J.

1996-01-01

Interstellar dust is responsible, through surface reactions, for the creation of molecular hydrogen, the main component of the interstellar clouds in which new stars form. Intermediate between small, gas-phase molecules and dust are the polycyclic aromatic hydrocarbons (PAHs). Such molecules could account for 2-30% of the carbon in the Galaxy, and may provide nucleation sites for the formation of carbonaceous dust. Although PAHs have been proposed as the sources of the unidentified infrared emission bands that are observed in the spectra of a variety of interstellar sources, the emission characteristics of such molecules are still poorly understood. Here we report laboratory emission spectra of several representative PAHs, obtained in conditions approximating those of the interstellar medium, and measured over the entire spectral region spanned by the unidentified infrared bands. We find that neutral PAHs of small and moderate size can at best make only a minor contribution to these emission bands. Cations of these molecules, as well as much larger PAHs and their cations, remain viable candidates for the sources of these bands.

RFID Transponders' RF Emissions in Aircraft Communication and Navigation Radio Bands

NASA Technical Reports Server (NTRS)

Nguyen, Truong X.; Ely, Jay J.; Koppen Sandra V.; Fersch, Mariatheresa S.

2008-01-01

Radiated emission data in aircraft communication and navigation bands are presented for several active radio frequency identification (RFID) tags. The individual tags are different in design, operation and transmitting frequencies. The process for measuring the tags emissions in a reverberation chamber is discussed. Measurement issues dealing with tag interrogation, low level measurement in the presence of strong transmissions, and tags low duty factors are discussed. The results show strong emissions, far exceeding aircraft emission limits and can be of potential interference risks.

2D XANES-XEOL mapping: observation of enhanced band gap emission from ZnO nanowire arrays

NASA Astrophysics Data System (ADS)

Wang, Zhiqiang; Guo, Xiaoxuan; Sham, Tsun-Kong

2014-05-01

Using 2D XANES-XEOL spectroscopy, it is found that the band gap emission of ZnO nanowire arrays is substantially enhanced i.e. that the intensity ratio between the band gap and defect emissions increases by more than an order of magnitude when the excitation energy is scanned across the O K-edge. Possible mechanisms are discussed.Using 2D XANES-XEOL spectroscopy, it is found that the band gap emission of ZnO nanowire arrays is substantially enhanced i.e. that the intensity ratio between the band gap and defect emissions increases by more than an order of magnitude when the excitation energy is scanned across the O K-edge. Possible mechanisms are discussed. Electronic supplementary information (ESI) available: XEOL spectra with different excitation energies. X-ray attenuation length vs. photon energy. Details of surface defects in ZnO NWs. The second O K-edge and Zn L-edge 2D XANES-XEOL maps. Comparison of the first and second TEY at O K-edge and Zn L-edge scans, respectively. Raman spectra of the ZnO NWs with different IBGE/IDE ratios. See DOI: 10.1039/c4nr01049c

Interpreting the Subtle Spectral Variations of the 11.2 and 12.7 μm Polycyclic Aromatic Hydrocarbon Bands

NASA Astrophysics Data System (ADS)

Shannon, M. J.; Stock, D. J.; Peeters, E.

2016-06-01

We report new properties of the 11 and 12.7 μm emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution Spitzer Space Telescope data, we study in detail the spectral and spatial characteristics of the 11 and 12.7 μm emission bands in maps of reflection nebulae NGC 7023 and NGC 2023 (north and south) and the star-forming region M17. Profile variations are observed in both the 11 and 12.7 μm emission bands. We identify a neutral contribution to the traditional 11.0 μm PAH band and a cationic contribution to the traditional 11.2 μm band, the latter of which affects the PAH class of the 11.2 μm emission in our sample. The peak variations of the 12.7 μm complex are explained by the competition between two underlying blended components. The spatial distributions of these components link them to cations and neutrals. We conclude that the 12.7 μm emission originates in both neutral and cationic PAHs, lending support to the use of the 12.7/11.2 intensity ratio as a charge proxy.

Optofluidic chlorophyll lasers.

PubMed

Chen, Yu-Cheng; Chen, Qiushu; Fan, Xudong

2016-06-21

Chlorophylls are essential for photosynthesis and also one of the most abundant pigments on earth. Using an optofluidic ring resonator of extremely high Q-factors (>10(7)), we investigated the unique characteristics and underlying mechanism of chlorophyll lasers. Chlorophyll lasers with dual lasing bands at 680 nm and 730 nm were observed for the first time in isolated chlorophyll a (Chla). Particularly, a laser at the 730 nm band was realized in 0.1 mM Chla with a lasing threshold of only 8 μJ mm(-2). Additionally, we observed lasing competition between the two lasing bands. The presence of laser emission at the 680 nm band can lead to quenching or significant reduction of laser emission at the 730 nm band, effectively increasing the lasing threshold for the 730 nm band. Further concentration-dependent studies, along with theoretical analysis, elucidated the mechanism that determines when and why the laser emission band appears at one of the two bands, or concomitantly at both bands. Finally, Chla was exploited as the donor in fluorescence resonance energy transfer to extend the laser emission to the near infrared regime with an unprecedented wavelength shift as large as 380 nm. Our work will open a door to the development of novel biocompatible and biodegradable chlorophyll-based lasers for various applications such as miniaturized tunable coherent light sources and in vitro/in vivo biosensing. It will also provide important insight into the chlorophyll fluorescence and photosynthesis processes inside plants.

The Rovibrational Intensities of the (40 deg 1) and (00 deg 0) Pentad Absorption Bands of 12C16O2 Between 7284 and 7921 cm(exp-1)

NASA Technical Reports Server (NTRS)

Giver, L. P.; Chackerian, C., Jr.; Spencer, N.; Brown, L. R.; Wattson, R. B.; Gore, Warren J. (Technical Monitor)

1995-01-01

Carbon dioxide is the major constituent of the atmospheres of both Mars and Venus. Correct interpretations of spectra of these atmospheres require accurate knowledge of a substantial number of absorption bands of this gas. This is especially true for Venus; many weak CO2 bands that are insignificant in the earth's atmosphere are prominent absorbers in Venus' hot, dense lower atmosphere. Yet, recent near-infrared spectra of Venus' nightside have discovered emission windows, which occur between CO2 absorption bands, at 4040-4550 cm(exp-1), 5700-5900 cm(exp-1), and several smaller ones between 7500 and 9400 cm(exp-1). This radiation is due to thermal emission from Venus' lower atmosphere, diminished by scattering and absorption within the sulfuric acid clouds on its way to space. Simulations of these data with radiative transfer models can provide improved information on the abundances of a number of constituents of the lower atmosphere (e.g. H2O, CO, HDO, HCl, HF, and OCS) and the optical properties of the clouds, whose spatial variation modulates the brightness of the emissions. However, the accuracy of these retrievals has been limited by insufficient knowledge of the opacity of some of the gas species, including CO2, at the large pathlengths and high temperatures and pressures that exist on Venus. In particular, modeling the emission spectrum did not produce a good fit for the emission window centered at 7830 cm(exp-1). In an ongoing effort to assist analyses of these Venus spectra, we have been making laboratory intensity measurements of several weak bands of CO2 which are significant absorbers in these Venus emission windows. The CO2 bands that are prominent in the 7830 cm(exp-1) region belong to the vibrational sequence 4v1+v3 and associated hot bands. Only 2 of the 5 bands of this sequence have been previously measured. Modeling Venus' emission spectrum in the 7830 cm(exp-1) region had to rely on calculated intensity values for the weak ground state band at 7921 cm-1 and the associated hot bands. Since the calculated intensities of ground state bands are known to have significant uncertainties, we decided to measure this (40 deg 1)I (left arrow) (00 deg 0) band with the Ames 25 meter multiple reflection absorption cell and Fourier transform spectrometer. We also measured the (40 deg 1) (sub IV) (left arrow) (00 deg 0) band at 7460 cm(exp-1), which also had not been previously measured. These measurements are reported in this article, and we also give our reanalysis of the prior measurements of the (40 deg 1) (sub III) (left arrow) (00 deg 0) bands. These measurements provide the basis for improving calculated intensities for related hot bands as well as simulations of Venus' spectrum.

The TES Hematite-Rich Region in Sinus Meridiani: A Proposed Landing Site for the 2003 Rover

NASA Technical Reports Server (NTRS)

Christensen, Philip R.; Bandfield, Joshua; Hamilton, Victoria; Ruff, Steven; Morris, Richard; Lane, Melissa; Malin, Michael

2001-01-01

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has identified an accumulation of crystalline hematite (alpha-Fe2O3) that covers an area with very sharp boundaries approximately 350 by 750 km in size centered near 2 S latitude between 0 and 8 W longitude (Sinus Meridiani). The depth and shape of the hematite fundamental bands in the TES spectra show that the hematite is relatively coarse grained (greater than 5-10 micrometers). The spectrally-derived areal abundance of hematite varies with particle size from approximately 10% for particles greater than 30 micrometers in diameter to 40-60% for unpacked 10 micrometer powders. The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter less than 5-10 micrometers), red, crystalline hematite considered, on the basis of visible and near-IR data, to be a minor spectral component in Martian bright regions. A global map of the hematite abundance has been constructed using TES data from the MGS mapping mission.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, Bing; Shen, Chao; Zhang, Mengya

Green synthesis of CdSe quantum dots for application in the quantum-dots-sensitized solar cells (QDSCs) is investigated in this work. The CdSe QDs were prepared with glycerol as the solvent, with sharp emission peak, full width at half maximum around 30 nm, and absorption peak from 475 nm to 510 nm. The reaction is environmental friendly and energy saving. What's more, the green synthesized CdSe QDs are coherence to the maximum remittance region of the solar spectrum and suitable as sensitizers to assemble onto TiO{sub 2} electrodes for cell devices application. What's more, the dynamic procedure of the carriers' excitation, transportation, and recombination inmore » the QDSCs are discussed. Because the recombination of the electrons from the conduction band of TiO{sub 2}'s to the electrolyte affects the efficiency of the solar cells greatly, 3-Mercaptopropionic acid capped water-dispersible QDs were used to cover the surface of TiO{sub 2}. The resulting green synthesized CdSe QDSCs with Cu{sub 2}S as the electrode show a photovoltaic performance with a conversion efficiency of 3.39%.« less

In-Flight Measurement of the Absolute Energy Scale of the Fermi Large Area Telescope

NASA Technical Reports Server (NTRS)

Ackermann, M.; Ajello, M.; Allafort, A.; Atwood, W. B.; Axelsson, M.; Baldini, L.; Barbielini, G; Bastieri, D.; Bechtol, K.; Bellazzini, R.;

In-Flight Measurement of the Absolute Energy Scale of the Fermi Large Area Telescope

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ackermann, M.; /Stanford U., HEPL /SLAC /KIPAC, Menlo Park; Ajello, M.

The Large Area Telescope (LAT) on-board the Fermi Gamma-ray Space Telescope is a pair-conversion telescope designed to survey the gamma-ray sky from 20 MeV to several hundreds of GeV. In this energy band there are no astronomical sources with sufficiently well known and sharp spectral features to allow an absolute calibration of the LAT energy scale. However, the geomagnetic cutoff in the cosmic ray electron-plus-positron (CRE) spectrum in low Earth orbit does provide such a spectral feature. The energy and spectral shape of this cutoff can be calculated with the aid of a numerical code tracing charged particles in themore » Earth's magnetic field. By comparing the cutoff value with that measured by the LAT in different geomagnetic positions, we have obtained several calibration points between {approx}6 and {approx}13 GeV with an estimated uncertainty of {approx}2%. An energy calibration with such high accuracy reduces the systematic uncertainty in LAT measurements of, for example, the spectral cutoff in the emission from gamma ray pulsars.« less

Lessons from the Short GRB 170817A: The First Gravitational-wave Detection of a Binary Neutron Star Merger

NASA Astrophysics Data System (ADS)

Granot, Jonathan; Guetta, Dafne; Gill, Ramandeep

2017-12-01

The first, long-awaited, detection of a gravitational-wave (GW) signal from the merger of a binary neutron star (NS-NS) system was finally achieved (GW170817) and was also accompanied by an electromagnetic counterpart—the short-duration gamma-ray burst (GRB) 170817A. It occurred in the nearby (D≈ 40 Mpc) elliptical galaxy NGC 4993 and showed optical, IR, and UV emission from half a day up to weeks after the event, as well as late-time X-ray (at ≥slant 8.9 days) and radio (at ≥slant 16.4 days) emission. There was a delay of {{Δ }}t≈ 1.74 {{s}} between the GW merger chirp signal and the prompt GRB emission onset, and an upper limit of {θ }{obs}< 28^\\circ was set on the viewing angle w.r.t the jet’s symmetry axis from the GW signal. In this letter we examine some of the implications of these groundbreaking observations. The delay {{Δ }}t sets an upper limit on the prompt GRB emission radius, {R}γ ≲ 2c{{Δ }}t/{({θ }{obs}-{θ }0)}2, for a jet with sharp edges at an angle {θ }0< {θ }{obs}. GRB 170817A’s relatively low isotropic equivalent γ-ray energy output may suggest a viewing angle slightly outside the jet’s sharp edge, {θ }{obs}-{θ }0˜ {(0.05-0.1)({{Γ }}/100)}-1, but its peak ν {F}ν photon energy and afterglow emission suggest instead that the jet does not have sharp edges and the prompt emission was dominated by less energetic material along our line of sight, at {θ }{obs}≳ 2{θ }0. Finally, we consider the type of remnant that is produced by the NS-NS merger and find that a relatively long-lived (> 2 s) massive NS is strongly disfavored, while a hyper-massive NS of lifetime ˜ 1 {{s}} appears to be somewhat favored over the direct formation of a black hole.

Variability of OH(3-1) and OH(6-2) emission altitude and volume emission rate from 2003 to 2011

NASA Astrophysics Data System (ADS)

Teiser, Georg; von Savigny, Christian

2017-08-01

In this study we report on variability in emission rate and centroid emission altitude of the OH(3-1) and OH(6-2) Meinel bands in the terrestrial nightglow based on spaceborne nightglow measurements with the SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY) instrument on the Envisat satellite. The SCIAMACHY observations cover the time period from August 2002 to April 2012 and the nighttime observations used in this study are performed at 10:00 p.m. local solar time. Characterizing variability in OH emission altitude - particularly potential long-term variations - is important for an appropriate interpretation of ground-based OH rotational temperature measurements, because simultaneous observations of the vertical OH volume emission rate profile are usually not available for these measurements. OH emission altitude and vertically integrated emission rate time series with daily resolution for the OH(3-1) band and monthly resolution for the OH(6-2) band were analyzed using a standard multilinear regression approach allowing for seasonal variations, QBO-effects (Quasi-Biennial Oscillation), solar cycle (SC) variability and a linear long-term trend. The analysis focuses on low latitudes, where SCIAMACHY nighttime observations are available all year. The dominant sources of variability for both OH emission rate and altitude are the semi-annual and annual variations, with emission rate and altitude being highly anti-correlated. There is some evidence for a 11-year solar cycle signature in the vertically integrated emission rate and in the centroid emission altitude of both the OH(3-1) and OH(6-2) bands.

47 CFR 15.217 - Operation in the band 160-190 kHz.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 47 Telecommunication 1 2012-10-01 2012-10-01 false Operation in the band 160-190 kHz. 15.217... Intentional Radiators Radiated Emission Limits, Additional Provisions § 15.217 Operation in the band 160-190 k... lead (if used) shall not exceed 15 meters. (c) All emissions below 160 kHz or above 190 kHz shall be...

47 CFR 15.217 - Operation in the band 160-190 kHz.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 47 Telecommunication 1 2011-10-01 2011-10-01 false Operation in the band 160-190 kHz. 15.217... Intentional Radiators Radiated Emission Limits, Additional Provisions § 15.217 Operation in the band 160-190 k... lead (if used) shall not exceed 15 meters. (c) All emissions below 160 kHz or above 190 kHz shall be...

47 CFR 15.217 - Operation in the band 160-190 kHz.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 47 Telecommunication 1 2013-10-01 2013-10-01 false Operation in the band 160-190 kHz. 15.217... Intentional Radiators Radiated Emission Limits, Additional Provisions § 15.217 Operation in the band 160-190 k... lead (if used) shall not exceed 15 meters. (c) All emissions below 160 kHz or above 190 kHz shall be...

47 CFR 15.217 - Operation in the band 160-190 kHz.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 47 Telecommunication 1 2014-10-01 2014-10-01 false Operation in the band 160-190 kHz. 15.217... Intentional Radiators Radiated Emission Limits, Additional Provisions § 15.217 Operation in the band 160-190 k... lead (if used) shall not exceed 15 meters. (c) All emissions below 160 kHz or above 190 kHz shall be...

47 CFR 15.217 - Operation in the band 160-190 kHz.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 47 Telecommunication 1 2010-10-01 2010-10-01 false Operation in the band 160-190 kHz. 15.217... Intentional Radiators Radiated Emission Limits, Additional Provisions § 15.217 Operation in the band 160-190 k... lead (if used) shall not exceed 15 meters. (c) All emissions below 160 kHz or above 190 kHz shall be...

PAH Emission in the Orion Bar

NASA Technical Reports Server (NTRS)

Bregman, Jesse; Sloan, G. C.

1996-01-01

The emission from polycyclic aromatic hydrocarbons (PAH's) in the Orion Bar region is investigated using a combination of narrow-band imaging and long-slit spectroscopy. The goal was to study how the strength of the PAH bands vary with spatial position in this edge-on photo-dissociation region. The specific focus here is how these variations constrain the carrier of the 3.4 micron band.

47 CFR 15.253 - Operation within the bands 46.7-46.9 GHz and 76.0-77.0 GHz.

Code of Federal Regulations, 2010 CFR

2010-10-01

...-77.0 GHz is restricted to vehicle-mounted field disturbance sensors used as vehicle radar systems... the radiating structure. (c) The power density of any emissions outside the operating band shall... GHz shall not exceed the general limits in § 15.209. (2) Radiated emissions outside the operating band...

Effect of stacking faults on the photoluminescence spectrum of zincblende GaN

NASA Astrophysics Data System (ADS)

Church, S. A.; Hammersley, S.; Mitchell, P. W.; Kappers, M. J.; Lee, L. Y.; Massabuau, F.; Sahonta, S. L.; Frentrup, M.; Shaw, L. J.; Wallis, D. J.; Humphreys, C. J.; Oliver, R. A.; Binks, D. J.; Dawson, P.

2018-05-01

The photoluminescence spectra of a zincblende GaN epilayer grown via metal-organic chemical vapour deposition upon 3C-SiC/Si (001) substrates were investigated. Of particular interest was a broad emission band centered at 3.4 eV, with a FWHM of 200 meV, which extends above the bandgap of both zincblende and wurtzite GaN. Photoluminescence excitation measurements show that this band is associated with an absorption edge centered at 3.6 eV. Photoluminescence time decays for the band are monoexponential, with lifetimes that reduce from 0.67 ns to 0.15 ns as the recombination energy increases. TEM measurements show no evidence of wurtzite GaN inclusions which are typically used to explain emission in this energy range. However, dense stacking fault bunches are present in the epilayers. A model for the band alignment at the stacking faults was developed to explain this emission band, showing how both electrons and holes can be confined adjacent to stacking faults. Different stacking fault separations can change the carrier confinement energies sufficiently to explain the width of the emission band, and change the carrier wavefunction overlap to account for the variation in decay time.

RFID Transponders' Radio Frequency Emissions in Aircraft Communication and Navigation Radio Bands

NASA Technical Reports Server (NTRS)

Nguyen, Truong X.; Ely, Jay J.; Williams, Reuben A.; Koppen, Sandra V.; Salud, Maria Theresa P.

2006-01-01

Radiated emissions in aircraft communication and navigation bands are measured from several active radio frequency identification (RFID) tags. The individual tags are different in design and operations. They may also operate in different frequency bands. The process for measuring the emissions is discussed, and includes tag interrogation, reverberation chamber testing, and instrument settings selection. The measurement results are described and compared against aircraft emission limits. In addition, interference path loss for the cargo bays of passenger aircraft is measured. Cargo bay path loss is more appropriate for RFID tags than passenger cabin path loss. The path loss data are reported for several aircraft radio systems on a Boeing 747 and an Airbus A320.

Carbon stars with alpha-C:H emission

NASA Technical Reports Server (NTRS)

Gerbault, Florence; Goebel, John H.

1989-01-01

Many carbon stars in the IRS low resolution spectra (LRS) catalog were found which display emission spectra that compare favorable with the absorption spectrum of alpha-C:H. These stars have largely been classified as 4X in the LRS which has led to their interpretation by others in terms of displaying a mixture of the UIRF's 8.6 micron band and SiC at 11.5 microns. It was also found that many of these stars have a spectral upturn at 20+ microns which resembles the MgS band seen in carbon stars and planetary nebulae. It was concluded that this group of carbon stars will evolve into planetary nebulae like NGC 7027 and IC 418. In the presence of hard ultraviolet radiation the UIRF's will light up and be displayed as narrow emission bands on top of the broad alpha-C:H emission bands.

Spectrally selective solar absorber with sharp and temperature dependent cut-off based on semiconductor nanowire arrays

NASA Astrophysics Data System (ADS)

Wang, Yang; Zhou, Lin; Zheng, Qinghui; Lu, Hong; Gan, Qiaoqiang; Yu, Zongfu; Zhu, Jia

2017-05-01

Spectrally selective absorbers (SSA) with high selectivity of absorption and sharp cut-off between high absorptivity and low emissivity are critical for efficient solar energy conversion. Here, we report the semiconductor nanowire enabled SSA with not only high absorption selectivity but also temperature dependent sharp absorption cut-off. By taking advantage of the temperature dependent bandgap of semiconductors, we systematically demonstrate that the absorption cut-off profile of the semiconductor-nanowire-based SSA can be flexibly tuned, which is quite different from most of the other SSA reported so far. As an example, silicon nanowire based selective absorbers are fabricated, with the measured absorption efficiency above (below) bandgap ˜97% (15%) combined with an extremely sharp absorption cut-off (transition region ˜200 nm), the sharpest SSA demonstrated so far. The demonstrated semiconductor-nanowire-based SSA can enable a high solar thermal efficiency of ≳86% under a wide range of operating conditions, which would be competitive candidates for the concentrated solar energy utilizations.

High Pressure Noble Gas Alkali Vapor Mixtures and Their Visible and Infrared Excimer Bands.

DTIC Science & Technology

1980-02-01

Curry, and W. Bapper, "Visible emission bands of KXen polyatomic exciplexes ," Phys. Rev. Letters 41, 543 (1978). A. C. Tam, T. Yabuzaki, S. M. Curry...I178 Visible Emission Bands of KXe. Polyatomic Exciplexes ’. Yauviki.’ ) A. C. Tam, 0’ S. M. Curry, ( ) and W. liapper COdumble Ru’Iiati.op labor,, ,wy...giound electronic states. These temperature. " exciplex " molectle, are often gool laser species (2) The polyxetide band broadens substantially since the

Investigations of the Nonlinear Optical Response of Composite and Photonic Band Gap Materials

DTIC Science & Technology

1998-11-01

M. J. Bloemer, M. Scalora , J. P. Dowling, and C. M. Bowden, "Measurement of spontaneous-emission enhancement near the one-dimensional photonic band...with applications to photonic band structures," Phys. Rev. A 46, 612 (1992). 5. M. Scalora , J. P. Dowling, M. Tocci, M. J. Bloemer, C. M. Bowden, and...J. W. Haus, "Dipole emission rates in one-dimensional photonic band-gap materials," Appl. Phys. B 60, S57 (1995). 6. J. P. Dowling, M. Scalora , M. J

Modeling of Electron Transpiration Cooling for Leading Edges of Hypersonic Vehicles

NASA Astrophysics Data System (ADS)

Hanquist, Kyle Matthew

The development of aeronautics has been largely driven by the passion to fly faster. From the flight of the Wright Flyer that flew 48 km/hr to the recent advances in hypersonic flight, most notably NASA's X-43A that flew at over 3 km/s, the velocity of flight has steadily increased. However, as these hypersonic speeds are reached and increased, contradicting aerothermodynamic design requirements present themselves. For example, a hypersonic cruise vehicle requires sharp leading edges to decrease the drag in order to maximize the range. However, the aerodynamic performance gains obtained by having a sharp leading edge come at the cost of very high, localized heating rates. There is currently no ideal way to manage these heating loads for sustained hypersonic flight, especially as flight velocities continue to increase. An approach that has been recently proposed involves using thermo-electric materials on these sharp leading edges to manage the heating loads. When exposed to high convective heating rates, these materials emit a current of electrons that leads to a cooling effect of the surface of the vehicle called electron transpiration cooling (ETC). This dissertation focuses on developing a modeling approach to investigate this phenomenon. The research includes developing and implementing an approach for ETC into a computational fluid dynamics code for simulation of hypersonic flow that accounts for electron emission from the surface. Models for space-charge-limited emission are also developed and implemented in order to accurately determine the level of emission from the surface. This work involves developing analytic models and assessing them using a direct-kinetic plasma sheath solver. Electric field effects are also implemented in the modeling approach, which accounts for forced diffusion and Joule heating. Finally, the modeling approach is coupled to a material response code in order to model the heat transfer into the material surface. Using this modeling approach, ETC is investigated as a viable technology for a wide range of hypersonic operating conditions. This includes altitudes between 30 and 60 km, freestream velocities between 4 and 8 km/s, and leading edge radii between 1 mm and 10 cm. The results presented in this study show that ETC can reduce the leading edge temperature significantly for certain conditions, most notably from 3120 to 1660 K for Mach 26 flight for a sharp leading edge (1 cm). However, at lower velocities, the cooling effect can be diminished by space-charge limits in the plasma sheath. ETC is shown to be most effective at cooling hotter surfaces (e.g. high freestream velocities and sharp leading edges) and the level of ionization in the flowfield can help the emission overcome space-charge limits. The modeling approach is assessed using experiments from the 1960s where thermionic emission was investigated as a mode of power generation for reentry vehicles. The computational results produce a wide range of emitted current due to the uncertainty in the freestream conditions and material properties, but they still agree well with the experiments. Overall, this work indicates that ETC is a viable method of managing the immense heat loads on sharp leading edges during hypersonic flight for certain conditions and motivates future work in the area both computationally and experimentally.

Shear banding, discontinuous shear thickening, and rheological phase transitions in athermally sheared frictionless disks

NASA Astrophysics Data System (ADS)

Vâgberg, Daniel; Olsson, Peter; Teitel, S.

2017-05-01

We report on numerical simulations of simple models of athermal, bidisperse, soft-core, massive disks in two dimensions, as a function of packing fraction ϕ , inelasticity of collisions as measured by a parameter Q , and applied uniform shear strain rate γ ˙. Our particles have contact interactions consisting of normally directed elastic repulsion and viscous dissipation, as well as tangentially directed viscous dissipation, but no interparticle Coulombic friction. Mapping the phase diagram in the (ϕ ,Q ) plane for small γ ˙, we find a sharp first-order rheological phase transition from a region with Bagnoldian rheology to a region with Newtonian rheology, and show that the system is always Newtonian at jamming. We consider the rotational motion of particles and demonstrate the crucial importance that the coupling between rotational and translational degrees of freedom has on the phase structure at small Q (strongly inelastic collisions). At small Q , we show that, upon increasing γ ˙, the sharp Bagnoldian-to-Newtonian transition becomes a coexistence region of finite width in the (ϕ ,γ ˙) plane, with coexisting Bagnoldian and Newtonian shear bands. Crossing this coexistence region by increasing γ ˙ at fixed ϕ , we find that discontinuous shear thickening can result if γ ˙ is varied too rapidly for the system to relax to the shear-banded steady state corresponding to the instantaneous value of γ ˙.

Backbending in the {}_{90}^{223}{Th} nucleus: presentation of the consistency of two different experiments

NASA Astrophysics Data System (ADS)

Maquart, G.; Astier, A.; Ducoin, C.; Guinet, D.; Stézowski, O.; Augey, L.; Chaix, L.; Companis, I.; Dudouet, J.; Lehaut, G.; Mancuso, C.; Redon, N.; Vancraeyenest, A.

2017-06-01

The detailed level structure of {}223{Th} has been investigated in measurements of γ radiations following the fusion-evaporation channel of the {}208{Pb}{(}18{{O}},3n{)}223{Th} reaction at 85 MeV beam energy. The present data are extracted from two different experiments performed with the EUROBALL IV and JUROGAM II γ-ray detector array, respectively. The level structure has been extended up to spin 49/2 and 33 new γ-rays have been added using triple-γ coincidence data. The spins and parities of the newly observed states have been confirmed by angular distribution ratios. In addition to the two known yrast bands based on a K=5/2 configuration, a non-yrast band has been established up to spin 35/2. This observation has brought to light a sharp backbending occuring at the highest spins promoting the {}223{Th} as the heavier thorium isotope having an accident observed in its moment of inertia at high spin. We interpret this new structure as based on the same configuration as the yrast band in {}221{Th} having dominant K=1/2 contribution. At the highest spin a backbending occurs around a rotational frequency of {\\hslash }ω =0.23 {MeV}, very close to the one predicted in the {}222{Th} where a sharp transition to a reflection-symmetric shape is expected.

Optical Properties of ZnCdS:I Orange and ZnSTe:I White Thin Film Phosphor for High Ra White LED

NASA Astrophysics Data System (ADS)

Fujii, Satoshi; Tasaki, Norio; Shinomura, Naohiko; Kurai, Satoshi; Yamada, Yoichi; Taguchi, Tsunemasa

In order to develop visible thin film phosphors, we have for the first time prepared ZnCdS and ZnSTe doped with Iodine (I) using low-pressure MOCVD method. ZnCdS:I, of which Cd composition was calibrated to match the lattice constant to that of substrate and the band gap to absorption peak, showed a orange broad emission consist of yellow near band edge emission and red SA emission. Isoelectronic Te in ZnS indicates strong blue-green emissions, whilst I donor impurity in ZnS shows strong red SA emissions. A typical ZnSTe:I thin film shows two broad emission bands locating at around 500 and 680 nm, respectively, indicating Ra˜90. It was shown that high Ra thin film phosphor can be realized by single material (ZnSTe:I), and that MOCVD method is capable for controlling the thickness and doping profile to obtain uniform white emission pattern.

Stimulated emission in quantum well laser diodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blood, P.

1989-07-03

We observe that stimulated emission from inhomogeneously pumped quantum well laser diodes is shifted down in energy compared with the subband transition energy. Measured spontaneous emission spectra show that this stimulated emission is due to band-to-band transitions shifted by renormalization at high injected carrier densities, and we suggest that this same mechanism explains reported observations of stimulated emission from inhomogeneously photopumped structures which previously have been interpreted as evidence for longitudinal optic (LO) phonon participation. We show that LO phonon participation cannot account for the photon energy of stimulated emission from conventional homogeneously pumped quantum well laser diodes.

Local microstructure evolution at shear bands in metallic glasses with nanoscale phase separation

PubMed Central

He, Jie; Kaban, Ivan; Mattern, Norbert; Song, Kaikai; Sun, Baoan; Zhao, Jiuzhou; Kim, Do Hyang; Eckert, Jürgen; Greer, A. Lindsay

2016-01-01

At room temperature, plastic flow of metallic glasses (MGs) is sharply localized in shear bands, which are a key feature of the plastic deformation in MGs. Despite their clear importance and decades of study, the conditions for formation of shear bands, their structural evolution and multiplication mechanism are still under debate. In this work, we investigate the local conditions at shear bands in new phase-separated bulk MGs containing glassy nanospheres and exhibiting exceptional plasticity under compression. It is found that the glassy nanospheres within the shear band dissolve through mechanical mixing driven by the sharp strain localization there, while those nearby in the matrix coarsen by Ostwald ripening due to the increased atomic mobility. The experimental evidence demonstrates that there exists an affected zone around the shear band. This zone may arise from low-strain plastic deformation in the matrix between the bands. These results suggest that measured property changes originate not only from the shear bands themselves, but also from the affected zones in the adjacent matrix. This work sheds light on direct visualization of deformation-related effects, in particular increased atomic mobility, in the region around shear bands. PMID:27181922

47 CFR 74.637 - Emissions and emission limitations.

Code of Federal Regulations, 2012 CFR

2012-10-01

... vestigial sideband AM video: On any frequency removed from the center frequency of the authorized band by... communications. Frequency Band (MHz) Maximum authorized bandwidth (MHz) 1,990 to 2,110 18 6,425 to 6,525 25 6,875...

47 CFR 74.637 - Emissions and emission limitations.

Code of Federal Regulations, 2013 CFR

2013-10-01

... vestigial sideband AM video: On any frequency removed from the center frequency of the authorized band by... communications. Frequency Band (MHz) Maximum authorized bandwidth (MHz) 1,990 to 2,110 18 6,425 to 6,525 25 6,875...

47 CFR 74.637 - Emissions and emission limitations.

Code of Federal Regulations, 2010 CFR

2010-10-01

... vestigial sideband AM video: On any frequency removed from the center frequency of the authorized band by... communications. Frequency Band (MHz) Maximum authorized bandwidth (MHz) 1,990 to 2,110 18 6,425 to 6,525 25 6,875...

47 CFR 74.637 - Emissions and emission limitations.

Code of Federal Regulations, 2011 CFR

2011-10-01

... vestigial sideband AM video: On any frequency removed from the center frequency of the authorized band by... communications. Frequency Band (MHz) Maximum authorized bandwidth (MHz) 1,990 to 2,110 18 6,425 to 6,525 25 6,875...

47 CFR 74.637 - Emissions and emission limitations.

Code of Federal Regulations, 2014 CFR

2014-10-01

... vestigial sideband AM video: On any frequency removed from the center frequency of the authorized band by... communications. Frequency Band (MHz) Maximum authorized bandwidth (MHz) 1,990 to 2,110 18 6,425 to 6,525 25 6,875...

Data Quality Evaluation and Application Potential Analysis of TIANGONG-2 Wide-Band Imaging Spectrometer

NASA Astrophysics Data System (ADS)

Qin, B.; Li, L.; Li, S.

2018-04-01

Tiangong-2 is the first space laboratory in China, which launched in September 15, 2016. Wide-band Imaging Spectrometer is a medium resolution multispectral imager on Tiangong-2. In this paper, the authors introduced the indexes and parameters of Wideband Imaging Spectrometer, and made an objective evaluation about the data quality of Wide-band Imaging Spectrometer in radiation quality, image sharpness and information content, and compared the data quality evaluation results with that of Landsat-8. Although the data quality of Wide-band Imager Spectrometer has a certain disparity with Landsat-8 OLI data in terms of signal to noise ratio, clarity and entropy. Compared with OLI, Wide-band Imager Spectrometer has more bands, narrower bandwidth and wider swath, which make it a useful remote sensing data source in classification and identification of large and medium scale ground objects. In the future, Wide-band Imaging Spectrometer data will be widely applied in land cover classification, ecological environment assessment, marine and coastal zone monitoring, crop identification and classification, and other related areas.

Field emission and explosive electron emission process in focused ion beam fabricated platinum and tungsten three-dimensional overhanging nanostructure

NASA Astrophysics Data System (ADS)

Singh, Abhishek Kumar

2018-06-01

Three-dimensional platinum and tungsten overhanging nanogap (∼70 nm) electrodes are fabricated on a glass substrate using focused ion beam milling and chemical vapour deposition processes. Current-voltage (I-V) characteristics of the devices measured at a pressure of ∼10-6 mbar shows space-charge emission followed by the Fowler-Nordheim (F-N) field emission. After the F-N emission, the system enters into an explosive emission process, at a higher voltage generating a huge current. We observe a sharp and abrupt rise in the emission current which marks the transition from the F-N emission to the explosive emission state. The explosive emission process is destructive in nature and yields micro-/nano-size spherical metal particles. The chemical compositions and the size-distribution of such particles are performed.

Modelling of N2 Vegard-Kaplan and LBH emissions in the planetary atmospheres

NASA Astrophysics Data System (ADS)

Jain, Sonal Kumar; Bhardwaj, Anil

The N_{2} triplet band emissions are common features in the dayglow of Earth. Recent discoveries of N _{2} Vegard-Kaplan (VK) band emissions on Mars by SPICAM/Mars-Express and N _{2} VK and LBH band emissions on Titan by Cassini's UVIS have led planetary scientists to look for the processes governing the N _{2} triplet and singlet band emissions in different planetary atmospheres. We have developed a model to calculate N _{2} triplet and Lyman-Birge-Hopefield (LBH) band emissions in the dayglow of Venus, Mars, Titan, and Pluto. The Steady state photoelectron fluxes and volume excitation rates have been calculated using the Analytical Yield Spectra (AYS) technique. Since interstate cascading is important for triplet and singlet states of N _{2}, the population of any given level of N _{2} triplet and singlet states is calculated under statistical equilibrium considering direct excitation, cascading, and quenching effects. Relative population of all vibrational levels of each triplet and singlet states is calculated in the model. Line of sight intensities and height-integrated overhead intensities have been calculated for VK ( A(3Sigma_u^+) - X(1Sigma^+_g) ), first positive ( B(3Pi_g) - A(3Sigma^+_u) ), second positive ( C(3Pi_u) - B(3Pi_g) ), Wu-Benesch (W(3Delta_u) - B(3Pi_g) ), B '-> B, E -> B, E-> C, E-> A, and LBH (a(1Pi_g) - X(1Sigma^+_g) ) bands of N _{2}. The N _{2} VK band span wavelength range from far ultraviolet to visible, and some transitions even originate at wavelength more than 1000 nm. Our calculations show that the overhead intensity of VK bands in the wavelength range 400-800, 300-190, 200-300, and 150-200 nm are 22%, 39%, 35%, and 4% of the total VK band emission. On Titan, the calculated intensities of N _{2} VK and LBH bands in 150-190 and 120-190 nm wavelength range, respectively, are in good agreement with the Cassini-UVIS observation. On Mars, calculated intensities of N _{2} VK bands are in agreement with the SPICAM observed limb profile of N _{2} VK (0-6) when the N _{2} density in Martian upper atmosphere is reduced by a factor of 3. Calculations are also carried out on Venus using this model. Calculated intensities on Venus are about factor of 10 higher than that on Mars. On Pluto, the predicted limb intensities of N _{2} VK and LBH bands for New Horizons flyby condition peak at radial distance of 2000 km with a value of about 5 and 9.5 R, respectively for solar zenith angle 60(°) . The results will presented and discussed.

Synthesis and Characterization of Luminol Persulphate Chemiluminescence in Aqueous Amines

NASA Astrophysics Data System (ADS)

Raut, V. M.; More, P. S.; Khollam, Y. B.; Sonone, R. S.; Kondawar, S. B.; Koinkar, Pankaj

The chemiluminescence (CL) emission spectra of luminol were recorded using Fuss spectrograph in different aqueous aliphatic amines using sodium persulphate alone and mixture with hydrogen peroxide as an oxidant. The CL emission spectra after resolution showed two emission bands at 425 and 455 nm. The CL mechanism was explained on the basis of two exited state species formed during oxidation of luminol. The CL of luminol is found to be very weak as persulphate slowly produced oxygen. The glow become intense with time as more and more oxygen is made available for oxidation of luminol. The mixture of hydrogen peroxide and sodium persulphate is found to be more effective in producing intense and long lived CL glow for luminol. The CL emission band of luminol by using sodium persulphate and mixture with hydrogen peroxide is explained on the basis of formation of exited singlet and triplet state of 3-aminophthalate ion (3-APA). The shorter wavelength emission band of 425 nm is found to be very weak in intensity as compared to longer wavelength emission band of 455 nm. Thus phosphoresce is favored in case of persulphate CL of luminol.

Calculation of the X-Ray emission K and L 2,3 bands of metallic magnesium and aluminum with allowance for multielectron effects

NASA Astrophysics Data System (ADS)

Ovcharenko, R. E.; Tupitsyn, I. I.; Savinov, E. P.; Voloshina, E. N.; Dedkov, Yu. S.; Shulakov, A. S.

2014-01-01

A procedure is proposed to calculate the shape of the characteristic X-ray emission bands of metals with allowance for multielectron effects. The effects of the dynamic screening of a core vacancy by conduction electrons and the Auger effect in the valence band are taken into account. The dynamic screening of a core vacancy, which is known to be called the MND (Mahan-Nozeieres-De Dominics) effect, is taken into account by an ab initio band calculation of crystals using the PAW (projected augmented waves) method. The Auger effect is taken into account by a semiempirical method using the approximation of a quadratic dependence of the level width in the valence band on the difference between the level energy and the Fermi energy. The proposed calculation procedure is used to describe the X-ray emission K and L 2,3 bands of metallic magnesium and aluminum crystals. The calculated spectra agree well with the experimental bands both near the Fermi level and in the low-energy part of the spectra in all cases.

Radiative recombination in GaN/InGaN heterojunction bipolar transistors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kao, Tsung-Ting; Lee, Yi-Che; Kim, Hee-Jin

2015-12-14

We report an electroluminescence (EL) study on npn GaN/InGaN heterojunction bipolar transistors (HBTs). Three radiative recombination paths are resolved in the HBTs, corresponding to the band-to-band transition (3.3 eV), conduction-band-to-acceptor-level transition (3.15 eV), and yellow luminescence (YL) with the emission peak at 2.2 eV. We further study possible light emission paths by operating the HBTs under different biasing conditions. The band-to-band and the conduction-band-to-acceptor-level transitions mostly arise from the intrinsic base region, while a defect-related YL band could likely originate from the quasi-neutral base region of a GaN/InGaN HBT. The I{sub B}-dependent EL intensities for these three recombination paths are discussed. The resultsmore » also show the radiative emission under the forward-active transistor mode operation is more effective than that using a diode-based emitter due to the enhanced excess electron concentration in the base region as increasing the collector current increases.« less

Luminescence of mesoporous silicon powders treated by high-pressure water vapor annealing

NASA Astrophysics Data System (ADS)

Gelloz, Bernard; Loni, Armando; Canham, Leigh; Koshida, Nobuyoshi

2012-07-01

We have studied the photoluminescence of nanocrystalline silicon microparticle powders fabricated by fragmentation of PSi membranes. Several porosities were studied. Some powders have been subjected to further chemical etching in HF in order to reduce the size of the silicon skeleton and reach quantum sizes. High-pressure water vapor annealing was then used to enhance both the luminescence efficiency and stability. Two visible emission bands were observed. A red band characteristic of the emission of Si nanocrystals and a blue band related to localized centers in oxidized powders. The blue band included a long-lived component, with a lifetime exceeding 1 sec. Both emission bands depended strongly on the PSi initial porosity. The colors of the processed powders were tunable from brown to off-white, depending on the level of oxidation. The surface area and pore volume of some powders were also measured and discussed. The targeted applications are in cosmetics and medicine.

Obtaining reliable phase-gradient delays from otoacoustic emission data.

PubMed

Shera, Christopher A; Bergevin, Christopher

2012-08-01

Reflection-source otoacoustic emission phase-gradient delays are widely used to obtain noninvasive estimates of cochlear function and properties, such as the sharpness of mechanical tuning and its variation along the length of the cochlear partition. Although different data-processing strategies are known to yield different delay estimates and trends, their relative reliability has not been established. This paper uses in silico experiments to evaluate six methods for extracting delay trends from reflection-source otoacoustic emissions (OAEs). The six methods include both previously published procedures (e.g., phase smoothing, energy-weighting, data exclusion based on signal-to-noise ratio) and novel strategies (e.g., peak-picking, all-pass factorization). Although some of the methods perform well (e.g., peak-picking), others introduce substantial bias (e.g., phase smoothing) and are not recommended. In addition, since standing waves caused by multiple internal reflection can complicate the interpretation and compromise the application of OAE delays, this paper develops and evaluates two promising signal-processing strategies, the first based on time-frequency filtering using the continuous wavelet transform and the second on cepstral analysis, for separating the direct emission from its subsequent reflections. Altogether, the results help to resolve previous disagreements about the frequency dependence of human OAE delays and the sharpness of cochlear tuning while providing useful analysis methods for future studies.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ishimoto, M.; Meng, C.; Romick, G.J.

The UV spectra over the southern hemisphere nightside auroral oval have been obtained from an AFGL spectral/photometric experiment on board the low-altitude polar-orbiting S3-4 satellite. A detailed analysis of nightside auroral spectra from seven orbits between mid-May and June 1978 was performed to estimate the average energy and total energy flux of incident electrons. This study was based on observations of the N{sub 2} LBH (3-10) (1928-A) band and the N{sub 2} VK (0-5) (2604 A) band emission intensities and the application of model calculations. Comparison of the estimated quantities with the statistical satellite measurement of incident particles indicates thatmore » the LBH (3-10) band emission intensity can be used to estimate the total energy flux of incident electrons, similar to the N{sub 2}(+) 1N (0-0) (3914 A) band emission intensity in the visible region. In addition, the ratio of the LBH (3-10) to the VK (0-5) bande mission intensities indicates the average energy of incident auroral electrons in much the same way that the N{sub 2}(+)1N (0-0) and O I (6300 A) emission ratio does in the visible region. This study shows the use of different constituent emissions, model calculations, and synthetic spectra to infer the inherent possibilities in these types of studies.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ishimoto, M.; Meng, C.; Romick, G.J.

The UV spectra over the southern hemisphere nightside auroral oval have been obtained from an AFGL spectral/photometric experiment on board the low-altitude polar-orbiting S3--4 satellite. A detailed analysis of nightside auroral spectra from seven orbits between mid-May and June 1978 was performed to estimate the average energy and total energy flux of incident electrons. This study was based on observations of the N/sub 2/ LBH (3--10) (1928 A) band and the N/sub 2/ VK (0--5) (2604 A) band emission intensities and the application of model calculations by Strickland et al. (1983) and Daniell and Strickland (1986). Comparison of the estimatedmore » quantities with the statistical satellite measurement of incident particles by Hardy et al. (1985) indicates that the LBH (3--10) band emission intensity can be used to estimate the total energy flux of incident electrons, similar to the N/sub 2//sup +/ 1N (0--0) (3914 A) band emission intensity in the visible region. In addition, the ratio of the BLH (3--10) to the VK (0--5) band emission intensities indicates the average energy of incident auroral electrons in much the same way that the N/sub 2//sup +/ IN (0--0) and O I (6300 A) emission ratio does in the visible region.« less

INTERPRETING THE SUBTLE SPECTRAL VARIATIONS OF THE 11.2 AND 12.7 μ m POLYCYCLIC AROMATIC HYDROCARBON BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shannon, M. J.; Stock, D. J.; Peeters, E., E-mail: mshann3@uwo.ca

2016-06-20

We report new properties of the 11 and 12.7 μ m emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution Spitzer Space Telescope data, we study in detail the spectral and spatial characteristics of the 11 and 12.7 μ m emission bands in maps of reflection nebulae NGC 7023 and NGC 2023 (north and south) and the star-forming region M17. Profile variations are observed in both the 11 and 12.7 μ m emission bands. We identify a neutral contribution to the traditional 11.0 μ m PAH band and a cationic contribution to the traditionalmore » 11.2 μ m band, the latter of which affects the PAH class of the 11.2 μ m emission in our sample. The peak variations of the 12.7 μ m complex are explained by the competition between two underlying blended components. The spatial distributions of these components link them to cations and neutrals. We conclude that the 12.7 μ m emission originates in both neutral and cationic PAHs, lending support to the use of the 12.7/11.2 intensity ratio as a charge proxy.« less

[The mechanism and function of hippocampal neural oscillation].

PubMed

Lu, Ning; Xing, Dan-Qin; Sheng, Tao; Lu, Wei

2017-10-25

Neural oscillation is rhythmic or repetitive neural activity in the central nervous system that is usually generated by oscillatory activity of neuronal ensembles, reflecting regular and synchronized activities within these cell populations. According to several oscillatory bands covering frequencies from approximately 0.5 Hz to >100 Hz, neural oscillations are usually classified as delta oscillation (0.5-3 Hz), theta oscillation (4-12 Hz), beta oscillation (12-30 Hz), gamma oscillation (30-100 Hz) and sharp-wave ripples (>100 Hz ripples superimposed on 0.01-3 Hz sharp waves). Neural oscillation in different frequencies can be detected in different brain regions of human and animal during perception, motion and sleep, and plays an essential role in cognition, learning and memory process. In this review, we summarize recent findings on neural oscillations in hippocampus, as well as the mechanism and function of hippocampal theta oscillation, gamma oscillation and sharp-wave ripples. This review may yield new insights into the functions of neural oscillation in general.

Photoluminescence due to early stage of oxygen precipitation in multicrystalline Si for solar cells

NASA Astrophysics Data System (ADS)

Higuchi, Fumito; Tajima, Michio; Ogura, Atsushi

2017-07-01

To analyze the early stage of oxygen precipitation in n-type multicrytalline Si, the spectral change of photoluminescence (PL) induced by thermal treatment at 450-650 °C was investigated in relation to the changes in excess donor and interstitial oxygen concentrations. We observed the characteristic PL bands in the near-band-edge region and sharp lines in the deep-level region in correspondence with the generation of thermal donors and new donors. The observed PL spectral variation is essentially the same as that in Czochralski-grown Si annealed at 450-650 °C.

Helical quantum states in HgTe quantum dots with inverted band structures.

PubMed

Chang, Kai; Lou, Wen-Kai

2011-05-20

We investigate theoretically the electron states in HgTe quantum dots (QDs) with inverted band structures. In sharp contrast to conventional semiconductor quantum dots, the quantum states in the gap of the HgTe QD are fully spin-polarized and show ringlike density distributions near the boundary of the QD and spin-angular momentum locking. The persistent charge currents and magnetic moments, i.e., the Aharonov-Bohm effect, can be observed in such a QD structure. This feature offers us a practical way to detect these exotic ringlike edge states by using the SQUID technique.

Wide band cryogenic ultra-high vacuum microwave absorber

DOEpatents

Campisi, I.E.

1992-05-12

An absorber waveguide assembly for absorbing higher order modes of microwave energy under cryogenic ultra-high vacuum conditions, that absorbs wide-band multi-mode energy. The absorber is of a special triangular shape, made from flat tiles of silicon carbide and aluminum nitride. The leading sharp end of the absorber is located in a corner of the waveguide and tapers to a larger cross-sectional area whose center is located approximately in the center of the wave guide. The absorber is relatively short, being of less height than the maximum width of the waveguide. 11 figs.

Wide band cryogenic ultra-high vacuum microwave absorber

DOEpatents

Campisi, Isidoro E.

1992-01-01

An absorber wave guide assembly for absorbing higher order modes of microwave energy under cryogenic ultra-high vacuum conditions, that absorbs wide-band multi-mode energy. The absorber is of a special triangular shape, made from flat tiles of silicon carbide and aluminum nitride. The leading sharp end of the absorber is located in a corner of the wave guide and tapers to a larger cross-sectional area whose center is located approximately in the center of the wave guide. The absorber is relatively short, being of less height than the maximum width of the wave guide.

Raman spectroscopy for monitoring of organic and mineral structure of bone grafts

NASA Astrophysics Data System (ADS)

Timchenko, Elena V.; Timchenko, Pavel E.; Volova, Larisa T.; Ponomareva, Julia V.; Taskina, Larisa A.; Pershutkina, Svetlana V.

2014-09-01

The results of experimental studies of donor bone samples (rat, rabbit and human) with varying degrees of mineralisation by Raman spectroscopy were presented. Raman spectra were obtained for the Raman bands 950-962 (РО4)3-, 1065-1070 (СО3)2- and 1665 cm-1 (Amide I). In demineralized bone a sharp decline (to 98 %) in the range of 950-962 cm-1 (РО4)3- and 1065 - 1070 cm-1 was observed. This decrease was accompanied by the emergence of the 1079-1090 cm-1 band corresponding to the hydrated state СО3 2-.

Controlling upconversion nanocrystals for emerging applications

NASA Astrophysics Data System (ADS)

Zhou, Bo; Shi, Bingyang; Jin, Dayong; Liu, Xiaogang

2015-11-01

Lanthanide-doped upconversion nanocrystals enable anti-Stokes emission with pump intensities several orders of magnitude lower than required by conventional nonlinear optical techniques. Their exceptional properties, namely large anti-Stokes shifts, sharp emission spectra and long excited-state lifetimes, have led to a diversity of applications. Here, we review upconversion nanocrystals from the perspective of fundamental concepts and examine the technical challenges in relation to emission colour tuning and luminescence enhancement. In particular, we highlight the advances in functionalization strategies that enable the broad utility of upconversion nanocrystals for multimodal imaging, cancer therapy, volumetric displays and photonics.

47 CFR 73.757 - System specifications for single-sideband (SSB) modulated emissions in the HF broadcasting service.

Code of Federal Regulations, 2013 CFR

2013-10-01

... emission is one giving the same audio-frequency signal-to-noise ratio at the receiver output as the... is equally valid for both DSB and SSB emissions. (3) Audio-frequency band. The upper limit of the audio-frequency band (at—3 dB) of the transmitter shall not exceed 4.5 kHz with a further slope of...

47 CFR 73.757 - System specifications for single-sideband (SSB) modulated emissions in the HF broadcasting service.

Code of Federal Regulations, 2014 CFR

2014-10-01

... emission is one giving the same audio-frequency signal-to-noise ratio at the receiver output as the... is equally valid for both DSB and SSB emissions. (3) Audio-frequency band. The upper limit of the audio-frequency band (at—3 dB) of the transmitter shall not exceed 4.5 kHz with a further slope of...

47 CFR 73.757 - System specifications for single-sideband (SSB) modulated emissions in the HF broadcasting service.

Code of Federal Regulations, 2012 CFR

2012-10-01

... emission is one giving the same audio-frequency signal-to-noise ratio at the receiver output as the... is equally valid for both DSB and SSB emissions. (3) Audio-frequency band. The upper limit of the audio-frequency band (at—3 dB) of the transmitter shall not exceed 4.5 kHz with a further slope of...

Electromagnetic radiation trapped in the magnetosphere above the plasma frequency

NASA Technical Reports Server (NTRS)

Gurnett, D. A.; Shaw, R. R.

1973-01-01

An electromagnetic noise band is frequently observed in the outer magnetosphere by the Imp 6 spacecraft at frequencies from about 5 to 20 kHz. This noise band generally extends throughout the region from near the plasmapause boundary to near the magnetopause boundary. The noise typically has a broadband field strength of about 5 microvolts/meter. The noise band often has a sharp lower cutoff frequency at about 5 to 10 kHz, and this cutoff has been identified as the local electron plasma frequency. Since the plasma frequency in the plasmasphere and solar wind is usually above 20 kHz, it is concluded that this noise must be trapped in the low-density region between the plasmapause and magnetopause boundaries. The noise bands often contain a harmonic frequency structure which suggests that the radiation is associated with harmonics of the electron cyclotron frequency.

Vibrational spectroscopy of the borate mineral tunellite SrB6O9(OH)2·3(H2O) - Implications for the molecular structure

NASA Astrophysics Data System (ADS)

Frost, Ray L.; López, Andrés; Scholz, Ricardo; Xi, Yunfei

2014-02-01

Tunellite is a strontium borate mineral with formula: SrB6O9(OH)2·3(H2O) and occurs as colorless crystals in the monoclinic pyramidal crystal system. An intense Raman band at 994 cm-1 was assigned to the BO stretching vibration of the B2O3 units. Raman bands at 1043, 1063, 1082 and 1113 cm-1 are attributed to the in-plane bending vibrations of trigonal boron. Sharp Raman bands observed at 464, 480, 523, 568 and 639 cm-1 are simply defined as trigonal and tetrahedral borate bending modes. The Raman spectrum clearly shows intense Raman bands at 3567 and 3614 cm-1, attributed to OH units. The molecular structure of a natural tunellite has been assessed by using vibrational spectroscopy.

Superconductivity in an electron band just above the Fermi level: possible route to BCS-BEC superconductivity.

PubMed

Okazaki, K; Ito, Y; Ota, Y; Kotani, Y; Shimojima, T; Kiss, T; Watanabe, S; Chen, C-T; Niitaka, S; Hanaguri, T; Takagi, H; Chainani, A; Shin, S

2014-02-28

Conventional superconductivity follows Bardeen-Cooper-Schrieffer(BCS) theory of electrons-pairing in momentum-space, while superfluidity is the Bose-Einstein condensation(BEC) of atoms paired in real-space. These properties of solid metals and ultra-cold gases, respectively, are connected by the BCS-BEC crossover. Here we investigate the band dispersions in FeTe(0.6)Se(0.4)(Tc = 14.5 K ~ 1.2 meV) in an accessible range below and above the Fermi level(EF) using ultra-high resolution laser angle-resolved photoemission spectroscopy. We uncover an electron band lying just 0.7 meV (~8 K) above EF at the Γ-point, which shows a sharp superconducting coherence peak with gap formation below Tc. The estimated superconducting gap Δ and Fermi energy [Symbol: see text]F indicate composite superconductivity in an iron-based superconductor, consisting of strong-coupling BEC in the electron band and weak-coupling BCS-like superconductivity in the hole band. The study identifies the possible route to BCS-BEC superconductivity.

On the Relationship Between Schottky Barrier Capacitance and Mixer Performance at Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Romanofsky, Robert R.

1996-01-01

The flat-band voltage is the Schottky junction voltage required to shrink the depletion width to zero. At cryogenic temperatures, mixer diodes are generally biased and/or pumped beyond the flat-band condition to minimize conversion loss and noise figure. This occurs despite the presumed sharp increase in junction capacitance near flat-band, which should instead limit mixer performance. Past moderate forward bias, the diode C-V relationship is difficult to measure. A simple analytic expression for C(V) is usually used to model and predict mixer performance. This letter provides experimental data on C(V) at 77 K based on a microwave measurement and modeling technique. Data is also provided on the conversion loss of a singly balanced mixer optimized for 77 K operation. The connection between junction capacitance, flat-band potential, and conversion loss is examined. It is shown that the analytic expression greatly overestimates the junction capacitance that occurs as flat-band is approached.

The Martian diffuse aurora: Monte Carlo simulations and comparison with IUVS-MAVEN observations

NASA Astrophysics Data System (ADS)

Gerard, J. C. M. C.; Soret, L.; Schneider, N. M.; Shematovich, V.; Bisikalo, D.; Bougher, S. W.; Jain, S.; Lillis, R. J.; Mitchell, D. L.; Jakosky, B. M.; Deighan, J.; Larson, D. E.

2016-12-01

A new type of Martian aurora, characterized by an extended spatial distribution, an altitude lower than the discrete aurora and electron precipitation up to 200 keV has been observed following solar activity on several occasions with the IUVS on board the MAVEN spacecraft. We describe the results of Monte Carlo simulations of the production of several ultraviolet and visible auroral emissions for initial electron energies from 0.1 to 200 keV. These include the CO2+ ultraviolet doublet (UVD) at 288.3 and 289.6 nm and the Fox-Duffendack-Barker (FDB) bands, CO Cameron and Fourth Positive bands, OI 130.4 and 297.2 nm and CI 156.1 nm and 165.7 nm multiplets. We calculate the nadir and limb intensities of several of these emissions for a unit precipitated energy flux. Our results indicate that electrons in the range 100-200 keV produce maximum CO2+ UVD emission near 75 km. We combine SWEA and SEP electron energy spectra measured during diffuse aurora to calculate the volume emission rates and compare with IUVS observations of the emission limb profiles. The strongest predicted emissions are the CO2+ FDB, UVD and the CO Cameron bands. The metastable a 3Π state which radiates the Cameron bands is deactivated by collisions below 110 km. As a consequence, we show that the CO2+ UVD to the Cameron bands ratio increases at low altitude in the energetic diffuse aurora.

New-type planar field emission display with superaligned carbon nanotube yarn emitter.

PubMed

Liu, Peng; Wei, Yang; Liu, Kai; Liu, Liang; Jiang, Kaili; Fan, Shoushan

2012-05-09

With the superaligned carbon nanotube yarn as emitter, we have fabricated a 16 × 16 pixel field emission display prototype by adopting screen printing and laser cutting technologies. A planar diode field emission structure has been adopted. A very sharp carbon nanotube yarn tip emitter can be formed by laser cutting. Low voltage phosphor was coated on the anode electrodes also by screen printing. With a specially designed circuit, we have demonstrated the dynamic character display with the field emission display prototype. The emitter material and fabrication technologies in this paper are both easy to scale up to large areas.

Observations of Ultraviolet Emission from Mg+ in the Lower and Middle Thermosphere

NASA Astrophysics Data System (ADS)

Minschwaner, K.; Shukla, N.; Fortna, C.; Budzien, S.; Dymond, K.; McCoy, R.

2004-12-01

New observations of ionized magnesium dayglow are reported from the Ionospheric Spectroscopy and Atmospheric Chemistry (ISAAC) instrument on the ARGOS satellite. We focused on two periods, October 14-28 1999 and November 15-30 1999, when ISAAC obtained high quality limb spectra between 2600 and 3000 Å and from 85 to 350 km tangent altitude. In addition to the resonant scattering by Mg+ near 2800 Å, these limb spectra also contain signatures of fluorescent scattering by nitric oxide in the gamma bands, emission by molecular nitrogen in the Vergard-Kaplan bands, and atomic emission by oxygen in the 2972 Å line. A retrieval algorithm has been developed to measure the abundance of nitric oxide using the intensity of fluorescent scattering in the γ (1,5) band at 2670 Å. This technique then allows for separating the overlapping emission by nitric oxide in the γ (1,6) band from the Mg+ doublet at 2800 Å. Retrieved Mg+ column densities have been mapped as a function of altitude and geomagnetic latitude.

Manipulation of spontaneous emission in a tapered photonic crystal fibre

NASA Astrophysics Data System (ADS)

Myers, S. J.; Fussell, D. P.; Dawes, J. M.; Mägi, E.; McPhedran, R. C.; Eggleton, B. J.; de Sterke, C. Martijn

2006-12-01

We characterize the spontaneous emission of dye that is introduced into the central core of a tapered photonic crystal fiber. Since the photonic crystal period in the fibre cladding varies along the taper, the transmission and spontaneous emission spectra over a wide range of relative frequencies can be observed. The spontaneous emission spectra of the fibre transverse to the fiber axis show suppression due to partial band-gaps of the structure, and also enhancement of spontaneous emission near the band edges. We associate these with van Hove features, as well as finite cluster size effects.

Field emission from isolated individual vertically aligned carbon nanocones

NASA Astrophysics Data System (ADS)

Baylor, L. R.; Merkulov, V. I.; Ellis, E. D.; Guillorn, M. A.; Lowndes, D. H.; Melechko, A. V.; Simpson, M. L.; Whealton, J. H.

2002-04-01

Field emission from isolated individual vertically aligned carbon nanocones (VACNCs) has been measured using a small-diameter moveable probe. The probe was scanned parallel to the sample plane to locate the VACNCs, and perpendicular to the sample plane to measure the emission turn-on electric field of each VACNC. Individual VACNCs can be good field emitters. The emission threshold field depends on the geometric aspect ratio (height/tip radius) of the VACNC and is lowest when a sharp tip is present. VACNCs exposed to a reactive ion etch process demonstrate a lowered emission threshold field while maintaining a similar aspect ratio. Individual VACNCs can have low emission thresholds, carry high current densities, and have long emission lifetime. This makes them very promising for various field emission applications for which deterministic placement of the emitter with submicron accuracy is needed.

Note: Automated electrochemical etching and polishing of silver scanning tunneling microscope tips.

PubMed

Sasaki, Stephen S; Perdue, Shawn M; Rodriguez Perez, Alejandro; Tallarida, Nicholas; Majors, Julia H; Apkarian, V Ara; Lee, Joonhee

2013-09-01

Fabrication of sharp and smooth Ag tips is crucial in optical scanning probe microscope experiments. To ensure reproducible tip profiles, the polishing process is fully automated using a closed-loop laminar flow system to deliver the electrolytic solution to moving electrodes mounted on a motorized translational stage. The repetitive translational motion is controlled precisely on the μm scale with a stepper motor and screw-thread mechanism. The automated setup allows reproducible control over the tip profile and improves smoothness and sharpness of tips (radius 27 ± 18 nm), as measured by ultrafast field emission.

Refined tip preparation by electrochemical etching and ultrahigh vacuum treatment to obtain atomically sharp tips for scanning tunneling microscope and atomic force microscope.

PubMed

Hagedorn, Till; El Ouali, Mehdi; Paul, William; Oliver, David; Miyahara, Yoichi; Grütter, Peter

2011-11-01

A modification of the common electrochemical etching setup is presented. The described method reproducibly yields sharp tungsten tips for usage in the scanning tunneling microscope and tuning fork atomic force microscope. In situ treatment under ultrahigh vacuum (p ≤10(-10) mbar) conditions for cleaning and fine sharpening with minimal blunting is described. The structure of the microscopic apex of these tips is atomically resolved with field ion microscopy and cross checked with field emission. © 2011 American Institute of Physics

An X-ray image of the Seyfert galaxy NGC 1068

NASA Technical Reports Server (NTRS)

Wilson, A. S.; Elvis, M.; Lawrence, A.; Bland-Hawthorn, J.

1992-01-01

An image of NGC 1068 with 4-5 arcsec obtained with the High Resolution Imager on the Rosat X-ray Observatory in the energy band 0.1-2.4 keV is presented and discussed. The map reveals an unresolved nuclear source, extended (about 1.5 kpc) emission around the nucleus, and extended (about 13 kpc) emission from the starburst disk. The extended circumnuclear emission aligns toward the NE, the same direction as found for the resolved emission of the active nucleus in several other wavebands. Thermal emission from a hot wind is argued to be the source of the steep-spectrum, nuclear, and circumnuclear emission. The disk of NGC 1068 has ratios of soft X-ray to B band and soft X-ray to 60-micron luminosities which are similar to those found for other starburst systems. The X-ray spectrum of the starburst disk is harder than that of the nuclear emission. By adopting a plausible spectrum and extrapolating the present measured flux, it is concluded that the starburst disk contributes most of the hard component seen in the 2-10 keV band.

A Fluorescent Indicator for Imaging Lysosomal Zinc(II) with Förster Resonance Energy Transfer (FRET)-Enhanced Photostability and a Narrow Band of Emission

PubMed Central

Sreenath, Kesavapillai; Yuan, Zhao; Allen, John R.

2015-01-01

We demonstrate a strategy to transfer the zinc(II) sensitivity of a fluoroionophore with low photostability and a broad emission band to a bright and photostable fluorophore with a narrow emission band. The two fluorophores are covalently connected to afford an intramolecular Förster resonance energy transfer (FRET) conjugate. The FRET donor in the conjugate is a zinc(II)-sensitive arylvinylbipyridyl fluoroionophore, the absorption and emission of which undergo bathochromic shifts upon zinc(II) coordination. When the FRET donor is excited, efficient intramolecular energy transfer occurs to result in the emission of the acceptor boron dipyrromethene (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene or BODIPY) as a function of zinc(II) concentration. The broad emission band of the donor/zinc(II) complex is transformed into the strong, narrow emission band of the BODIPY acceptor in the FRET conjugates, which can be captured within the narrow emission window that is preferred for multicolor imaging experiments. In addition to competing with other nonradiative decay processes of the FRET donor, the rapid intramolecular FRET of the excited FRET-conjugate molecule protects the donor fluorophore from photobleaching, thus enhancing the photostability of the indicator. FRET conjugates 3 and 4 contain aliphatic amino groups, which selectively target lysosomes in mammalian cells. This subcellular localization preference was verified by using confocal fluorescence microscopy, which also shows the zinc(II)-enhanced emission of 3 and 4 in lysosomes. It was further shown using two-color structured illumination microscopy (SIM), which is capable of extending the lateral resolution over the Abbe diffraction limit by a factor of two, that the morpholino-functionalized compound 4 localizes in the interior of lysosomes, rather than anchoring on the lysosomal membranes, of live HeLa cells. PMID:25382395

Numerical simulation of systems of shear bands in ductile metal with inclusions

NASA Astrophysics Data System (ADS)

Plohr, Jeeyeon

2017-06-01

We develop a method for numerical simulations of high strain-rate loading of mesoscale samples of ductile metal with inclusions. Because of its small-scale inhomogeneity, the composite material is prone to localized shear deformation. This method employs the Generalized Method of Cells to ensure that the micro mechanical behavior of the metal and inclusions is reflected properly in the behavior of the composite at the mesoscale. To find the effective plastic strain rate when shear bands are present, we extend and apply the analytic and numerical analysis of shear bands of Glimm, Plohr, and Sharp. Our tests of the method focus on the stress/strain response in uniaxial-strain flow, both compressive and tensile, of depleted uranium metal containing silicon carbide inclusions. In results, we verify the elevated temperature and thermal softening at shear bands in our simulations of pure DU and DU/SiC composites. We also note that in composites, due the asymmetry caused by the inclusions, shear band form at different times in different subcells. In particular, in the subcells near inclusions, shear band form much earlier than they do in pure DU.

Low-Temperature Single Carbon Nanotube Spectroscopy of sp 3 Quantum Defects

DOE PAGES

He, Xiaowei; Gifford, Brendan J.; Hartmann, Nicolai F.; ...

2017-09-28

Aiming to unravel the relationship between chemical configuration and electronic structure of sp3 defects of aryl-functionalized (6,5) single-walled carbon nanotubes (SWCNTs), we perform low-temperature single nanotube photoluminescence (PL) spectroscopy studies and correlate our observations with quantum chemistry simulations. Here, we observe sharp emission peaks from individual defect sites that are spread over an extremely broad, 1000-1350 nm, spectral range. Our simulations allow us to attribute this spectral diversity to the occurrence of six chemically and energetically distinct defect states resulting from topological variation in the chemical binding configuration of the monovalent aryl groups. Both PL emission efficiency and spectral linemore » width of the defect states are strongly influenced by the local dielectric environment. Wrapping the SWCNT with a polyfluorene polymer provides the best isolation from the environment and yields the brightest emission with near-resolution limited spectral line width of 270 ueV, as well as spectrally resolved emission wings associated with localized acoustic phonons. Pump-dependent studies further revealed that the defect states are capable of emitting single, sharp, isolated PL peaks over 3 orders of magnitude increase in pump power, a key characteristic of two-level systems and an important prerequisite for single-photon emission with high purity. Our findings point to the tremendous potential of sp3 defects in development of room temperature quantum light sources capable of operating at telecommunication wavelengths as the emission of the defect states can readily be extended to this range via use of larger diameter SWCNTs.« less

Low-Temperature Single Carbon Nanotube Spectroscopy of sp 3 Quantum Defects

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Xiaowei; Gifford, Brendan J.; Hartmann, Nicolai F.

Aiming to unravel the relationship between chemical configuration and electronic structure of sp3 defects of aryl-functionalized (6,5) single-walled carbon nanotubes (SWCNTs), we perform low-temperature single nanotube photoluminescence (PL) spectroscopy studies and correlate our observations with quantum chemistry simulations. Here, we observe sharp emission peaks from individual defect sites that are spread over an extremely broad, 1000-1350 nm, spectral range. Our simulations allow us to attribute this spectral diversity to the occurrence of six chemically and energetically distinct defect states resulting from topological variation in the chemical binding configuration of the monovalent aryl groups. Both PL emission efficiency and spectral linemore » width of the defect states are strongly influenced by the local dielectric environment. Wrapping the SWCNT with a polyfluorene polymer provides the best isolation from the environment and yields the brightest emission with near-resolution limited spectral line width of 270 ueV, as well as spectrally resolved emission wings associated with localized acoustic phonons. Pump-dependent studies further revealed that the defect states are capable of emitting single, sharp, isolated PL peaks over 3 orders of magnitude increase in pump power, a key characteristic of two-level systems and an important prerequisite for single-photon emission with high purity. Our findings point to the tremendous potential of sp3 defects in development of room temperature quantum light sources capable of operating at telecommunication wavelengths as the emission of the defect states can readily be extended to this range via use of larger diameter SWCNTs.« less

Polycyclic aromatic hydrocarbons and the unidentified infrared emission bands - Auto exhaust along the Milky Way

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Tielens, A. G. G. M.; Barker, J. R.

1985-01-01

The unidentified infrared emission features (UIR bands) are attributed to a collection of partially hydrogenated, positively charged polycyclic aromatic hydrocarbons (PAHs). This assignment is based on a spectroscopic analysis of the UIR bands. Comparison of the observed interstellar 6.2 and 7.7-micron bands with the laboratory measured Raman spectrum of a collection of carbon-based particulates (auto exhaust) shows a very good agreement, supporting this identification. The infrared emission is due to relaxation from highly vibrationally and electronically excited states. The excitation is probably caused by UV photon absorption. The infrared fluorescence of one particular, highly vibrationally excited PAH (chrysene) is modeled. In this analysis the species is treated as a molecule rather than bulk material and the non-thermodynamic equilibrium nature of the emission is fully taken into account. From a comparison of the observed ratio of the 3.3 to 11.3-micron UIR bands with the model calculations, the average number of carbon atoms per molecule is estimated to be about 20. The abundance of interstellar PAHs is calculated to be about 2 x 10 to the -7th with respect to hydrogen.

PREDICTION OF FORBIDDEN ULTRAVIOLET AND VISIBLE EMISSIONS IN COMET 67P/CHURYUMOV–GERASIMENKO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raghuram, Susarla; Galand, Marina; Bhardwaj, Anil, E-mail: raghuramsusarla@gmail.com

Remote observation of spectroscopic emissions is a potential tool for the identification and quantification of various species in comets. The CO Cameron band (to trace CO{sub 2}) and atomic oxygen emissions (to trace H{sub 2}O and/or CO{sub 2}, CO) have been used to probe neutral composition in the cometary coma. Using a coupled-chemistry-emission model, various excitation processes controlling the CO Cameron band and different atomic oxygen and atomic carbon emissions have been modeled in comet 67P/Churyumov–Gerasimenko at 1.29 AU (perihelion) and at 3 AU heliocentric distances, which is being explored by ESA's Rosetta mission. The intensities of the CO Cameronmore » band, atomic oxygen, and atomic carbon emission lines as a function of projected distance are calculated for different CO and CO{sub 2} volume mixing ratios relative to water. Contributions of different excitation processes controlling these emissions are quantified. We assess how CO{sub 2} and/or CO volume mixing ratios with respect to H{sub 2}O can be derived based on the observed intensities of the CO Cameron band, atomic oxygen, and atomic carbon emission lines. The results presented in this work serve as baseline calculations to understand the behavior of low out-gassing cometary coma and compare them with the higher gas production rate cases (e.g., comet Halley). Quantitative analysis of different excitation processes governing the spectroscopic emissions is essential to study the chemistry of inner coma and to derive neutral gas composition.« less

Multicolor emission from intermediate band semiconductor ZnO 1-xSe x

DOE Office of Scientific and Technical Information (OSTI.GOV)

Welna, M.; Baranowski, M.; Linhart, W. M.

Photoluminescence and photomodulated reflectivity measurements of ZnOSe alloys are used to demonstrate a splitting of the valence band due to the band anticrossing interaction between localized Se states and the extended valence band states of the host ZnO matrix. A strong multiband emission associated with optical transitions from the conduction band to lower E - and upper E + valence subbands has been observed at room temperature. The composition dependence of the optical transition energies is well explained by the electronic band structure calculated using the kp method combined with the band anticrossing model. The observation of the multiband emissionmore » is possible because of relatively long recombination lifetimes. Longer than 1 ns lifetimes for holes photoexcited to the lower valence subband offer a potential of using the alloy as an intermediate band semiconductor for solar power conversion applications.« less

Multicolor emission from intermediate band semiconductor ZnO 1-xSe x

DOE PAGES

Welna, M.; Baranowski, M.; Linhart, W. M.; ...

2017-03-13

Photoluminescence and photomodulated reflectivity measurements of ZnOSe alloys are used to demonstrate a splitting of the valence band due to the band anticrossing interaction between localized Se states and the extended valence band states of the host ZnO matrix. A strong multiband emission associated with optical transitions from the conduction band to lower E - and upper E + valence subbands has been observed at room temperature. The composition dependence of the optical transition energies is well explained by the electronic band structure calculated using the kp method combined with the band anticrossing model. The observation of the multiband emissionmore » is possible because of relatively long recombination lifetimes. Longer than 1 ns lifetimes for holes photoexcited to the lower valence subband offer a potential of using the alloy as an intermediate band semiconductor for solar power conversion applications.« less

Major crustal fractures in the Baltic Shield

NASA Technical Reports Server (NTRS)

Tuominen, H. V. (Principal Investigator)

1972-01-01

The author has identified the following significant results. Initial analysis of the bands for images 1039-09322, 1039-09315, and 1040-09371 provide a detailed picture of a zone extending 500 km north-northeast from the northern coast of the Gulf of Bothnia. Highways (on bands 0.5-0.6 and 0.6-0.7), rivers (bands 0.7-0.8, 0.8-1.1) and bare fell tops are visible. Schist belts, as known from ground surveys, can be discerned from areas occupied by their basement rocks or major plutons. A number of sharp lineaments, apparently faults, are visible. Some major fracture zones, up to 50 km wide, that form distinct lineaments in weather satellite pictures and belong to the main objects of this study, are rather indistinct in the images but can be traced.

Comparison of Photoluminescence Imaging on Starting Multi-Crystalline Silicon Wafers to Finished Cell Performance: Preprint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnston, S.; Yan, F.; Dorn, D.

2012-06-01

Photoluminescence (PL) imaging techniques can be applied to multicrystalline silicon wafers throughout the manufacturing process. Both band-to-band PL and defect-band emissions, which are longer-wavelength emissions from sub-bandgap transitions, are used to characterize wafer quality and defect content on starting multicrystalline silicon wafers and neighboring wafers processed at each step through completion of finished cells. Both PL imaging techniques spatially highlight defect regions that represent dislocations and defect clusters. The relative intensities of these imaged defect regions change with processing. Band-to-band PL on wafers in the later steps of processing shows good correlation to cell quality and performance. The defect bandmore » images show regions that change relative intensity through processing, and better correlation to cell efficiency and reverse-bias breakdown is more evident at the starting wafer stage as opposed to later process steps. We show that thermal processing in the 200 degrees - 400 degrees C range causes impurities to diffuse to different defect regions, changing their relative defect band emissions.« less

Atmospheric dayglow diagnostics involving the O2(b-X) Atmospheric band emission: Global Oxygen and Temperature (GOAT) mapping

NASA Astrophysics Data System (ADS)

Slanger, T. G.; Pejaković, D. A.; Kostko, O.; Matsiev, D.; Kalogerakis, K. S.

2017-03-01

The terrestrial dayglow displays prominent emission features from the 0-0 and 1-1 bands of the O2 Atmospheric band system in the 760-780 nm region. We present an analysis of observations in this wavelength region recorded by the Space Shuttle during the Arizona Airglow Experiment. A major conclusion is that the dominant product of O(1D) + O2 energy transfer is O2(b, v = 1), a result that corroborates our previous laboratory studies. Moreover, critical to the interpretation of dayglow is the possible interference by N2 and N2+ bands in the 760-780 nm region, where the single-most important component is the N2 1PG 3-1 band that overlaps with the O2(b-X) 0-0 band. When present, this background must be accounted for to reveal the O2(b-X) 0-0 and 1-1 bands for altitudes at which the O2 and N2/N2+ emissions coincide. Finally, we exploit the very different collisional behavior of the two lowest O2(b) vibrational levels to outline a remote sensing technique that provides information on Atmospheric composition and temperature from space-based observations of the 0-0 and 1-1 O2 atmospheric bands.

GTC/CanariCam Mid-IR Imaging of the Fullerene-rich Planetary Nebula IC 418: Searching for the Spatial Distribution of Fullerene-like Molecules

NASA Astrophysics Data System (ADS)

Díaz-Luis, J. J.; García-Hernández, D. A.; Manchado, A.; García-Lario, P.; Villaver, E.; García-Segura, G.

2018-03-01

We present seeing-limited narrow-band mid-IR GTC/CanariCam images of the spatially extended fullerene-containing planetary nebula (PN) IC 418. The narrow-band images cover the C60 fullerene band at 17.4 μm, the polycyclic aromatic hydrocarbon like (PAH-like) feature at 11.3 μm, the broad 9–13 μm feature, and their adjacent continua at 9.8 and 20.5 μm. We study the relative spatial distribution of these complex species, all detected in the Spitzer and Infrared Space Observatory spectra of IC 418, with the aim of getting observational constraints to the formation process of fullerenes in H-rich circumstellar environments. A similar ring-like extended structure is seen in all narrow-band filters, except in the dust continuum emission at 9.8 μm, which peaks closer to the central star. The continuum-subtracted images display a clear ring-like extended structure for the carrier of the broad 9–13 μm emission, while the spatial distribution of the (PAH-like) 11.3 μm emission is not so well defined. Interestingly, a residual C60 17.4 μm emission (at about 4σ from the sky background) is seen when subtracting the dust continuum emission at 20.5 μm. This residual C60 emission, if real, might have several interpretations, the most exciting being perhaps that other fullerene-based species like hydrogenated fullerenes with very low H-content may contribute to the observed 17.4 μm emission. We conclude that higher sensitivity mid-IR images and spatially resolved spectroscopic observations (especially in the Q-band) are necessary to get some clues about fullerene formation in PNe.

Sonochemical driven ultrafast synthesis of Praseodymium doped Y2O3 nanostructures for display applications

NASA Astrophysics Data System (ADS)

Venkatachalaiah, K. N.; Nagabhushana, H.; Basavaraj, R. B.; Venkataravanappa, M.

2018-02-01

For the first time Pr3+ (1-11 mol %) doped Y2O3nanophosphors were synthesized by ultrasound supported sonochemical method using mimosa pudica (MP) leaves extract as bio-surfactant. The obtained product was heat treated at 700°C for 3 h and used for characterization. The powder X-ray diffraction (PXRD) profiles of nanophosphors showed cubic phase structure. The sonication time and concentration of bio-surfactant play a vital role in tuning the morphologies of Y2O3. The particle size was further confirmed by transmission electron microscope (TEM) and it was found to be in the range of 20-30 nm. The band gap energy of the phosphors were estimated by making use of diffuse reflectance spectrum (DRS) and the values were found to be in the range of 5.67 - 5.80 eV. Under 447 nm excitation wavelength, the photoluminescence (PL) emission spectrum was recorded. The PL emission spectra consist of sharp peaks centred at 554, 612 and 738 nm and were attributed to 3P0→3H5, 3P0→3H6, and 3P0→3F4 transitions respectively. The 5 mol% Pr3+ doped Y2O3nanophosphors showed maximum intensity. Further CIE and CCT were estimated and found that the color coordinates lies in between (0.593, 0.412) and (0.358, 0.544) respectively. Results obtained evident that the phosphor was highly useful in display device applications.

Temperature effects on luminescence properties of Cr3+ ions in alkali gallium silicate nanostructured media

NASA Astrophysics Data System (ADS)

Lipinska-Kalita, Kristina E.; Krol, Denise M.; Hemley, Russell J.; Kalita, Patricia E.; Gobin, Cedric L.; Ohki, Yoshimichi

2005-09-01

We have investigated the optical properties of Cr3+ ions in an alkali gallium silicate glass system and in two glass-based nanocomposites with nucleated β-Ga2O3 nanocrystals. The nucleation and growth of the nanocrystalline phase in the host glass matrix were monitored by Raman scattering spectroscopy and angle-dispersive x-ray diffraction. A broadband luminescence, associated with the 4T2-4A2 transition from the weak crystal field of octahedral Cr3+ sites, dominated the emission of the precursor as-quenched glass. The luminescence spectra of the synthesized glass-ceramic nanocomposites revealed a crystal-like 2E-4A2 strong emission and indicated that the major fraction of Cr3+ ions was located within the nanocrystalline environment. The variable-temperature studies of the nanocomposites demonstrated that the fluorescence of Cr3+ ions can be transformed from sharp R lines of the 2E-4A2 transition to a combination of R lines and of the broad band of the 4T2-4A2 transition. We propose a simple distribution model where the major part of Cr3+ ions is located in the nanocrystalline phase of the glass-ceramic composites in the octahedral environment, substituting the gallium atoms in the β-Ga2O3 crystal structure. The developed nanocrystalline glass-ceramics are a promising class of Cr3+-doped oxide glass-based optically active composite materials.

Red-emitting phosphor Rb2TiF6:Mn4+ with high thermal-quenching resistance for wide color-gamut white light-emitting diodes

NASA Astrophysics Data System (ADS)

Wang, Zhengliang; Yang, Zhiyu; Tan, Huiying; Brik, Mikhail G.; Zhou, Qiang; Chen, Guo; Liang, Hongbin

2017-10-01

Red-emitting phosphor plays a critical role in improving performance of the phosphor-converted white light-emitting diodes (pc-WLEDs). Herein, a red-emitting phosphor, Rb2TiF6:Mn4+, was synthesized via the ion exchange method under mild condition. The crystal structure and morphology were characterized by the powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The Rietveld refinements of Rb2TiF6:Mn4+ indicate that this sample is of single phase with hexagonal crystal structure. The as-prepared Rb2TiF6:Mn4+ has sharp red emissions with broad excitation band at ∼460 nm. The luminescent behavior of Mn4+ was discussed in detail. The temperature-dependent emission spectra of Rb2TiF6:Mn4+ indicate that this phosphor shares high thermal quenching resistance and excellent color stability. A series of WLEDs with tunable color rendering index and color temperature were fabricated by combining commercial Y3Al5O12:Ce3+ and Rb2TiF6:Mn4+ on blue GaN-LED chips. With the addition of Rb2TiF6:Mn4+, WLED with wide gamut was obtained with low color temperature (3123 K), high color rendering index (91.5) and high luminous efficacy (187.9 lm/W). These findings show this phosphor could be a promising commercial red phosphor in wide color-gamut WLEDs.

A curious case of the accretion-powered X-ray pulsar GX 1+4

NASA Astrophysics Data System (ADS)

Jaisawal, Gaurava K.; Naik, Sachindra; Gupta, Shivangi; Chenevez, Jérôme; Epili, Prahlad

2018-07-01

We present detailed spectral and timing studies using a NuSTAR observation of GX 1+4 in 2015 October during an intermediate-intensity state. The measured spin period of 176.778 s is found to be one of the highest values since its discovery. In contrast to a broad sinusoidal-like pulse profile, a peculiar sharp peak is observed in profiles below ˜25 keV. The profiles at higher energies are found to be significantly phase shifted compared to the soft X-ray profiles. Broad-band energy spectra of GX 1+4, obtained from NuSTAR and Swift observations, are described with various continuum models. Among these, a two-component model consisting of a bremsstrahlung and a blackbody component is found to best fit the phase-averaged and phase-resolved spectra. Physical models are also used to investigate the emission mechanism in the pulsar, which allows us to estimate the magnetic field strength to be in ˜(5-10) × 1012 G range. Phase-resolved spectroscopy of NuSTAR observation shows a strong blackbody emission component in a narrow pulse phase range. This component is interpreted as the origin of the peculiar peak in the pulse profiles below ≤25 keV. The size of emitting region is calculated to be ˜400 m. The bremsstrahlung component is found to dominate in hard X-rays and explains the nature of simple profiles at high energies.

Radio Emission from the Exoplanetary System ɛ Eridani

NASA Astrophysics Data System (ADS)

Bastian, T. S.; Villadsen, J.; Maps, A.; Hallinan, G.; Beasley, A. J.

2018-04-01

As part of a wider search for radio emission from nearby systems known or suspected to contain extrasolar planets, ɛ Eridani was observed by the Jansky Very Large Array (VLA) in the 2–4 GHz and 4–8 GHz frequency bands. In addition, as part of a separate survey of thermal emission from solar-like stars, ɛ Eri was observed in the 8–12 GHz and the 12–18 GHz bands of the VLA. Quasi-steady continuum radio emission from ɛ Eri was detected in the three high-frequency bands at levels ranging from 67 to 83 μJy. No significant variability is seen in the quasi-steady emission. The emission in the 2–4 GHz emission, however, is shown to be the result of a circularly polarized (up to 50%) radio pulse or flare of a few minutes in duration that occurred at the beginning of the observation. We consider the astrometric position of the radio source in each frequency band relative to the expected position of the K2V star and the purported planet. The quasi-steady radio emission at frequencies ≥8 GHz is consistent with a stellar origin. The quality of the 4–8 GHz astrometry provides no meaningful constraint on the origin of the emission. The location of the 2–4 GHz radio pulse is >2.5σ from the star; however, based on the ephemeris of Benedict et al., it is not consistent with the expected location of the planet either. If the radio pulse has a planetary origin, then either the planetary ephemeris is incorrect or the emission originates from another planet.

Comparison of band model calculations of upper atmospheric cooling rates for the 15-micrometer carbon dioxide band

NASA Technical Reports Server (NTRS)

Boughner, R. E.

1985-01-01

Within the atmosphere of the earth, absorption and emission of thermal radiation by the 15-micron CO2 bands are the largest contributors to infrared cooling rates in the stratosphere. Various techniques for calculating cooling rates due to these bands have been described. These techniques can be classified into one of two categories, including 'exact' or line-by-line calculations and other methods. The latter methods are based on broad band emissivity and band absorptance formulations. The present paper has the objective to present comparisons of the considered computational approaches. It was found that the best agreement with the exact line-by-line calculations of Fels and Schwarzkopf (1981) could be obtained by making use of a new Doppler band model which is described in the appendix of the paper.

Surface Emissivity Maps for Use in Satellite Retrievals of Longwave Radiation

NASA Technical Reports Server (NTRS)

Wilber, Anne C.; Kratz, David P.; Gupta, Shashi K.

1999-01-01

Accurate accounting of surface emissivity is essential for the retrievals of surface temperature from remote sensing measurements, and for the computations of longwave (LW) radiation budget of the Earth?s surface. Past studies of the above topics assumed that emissivity for all surface types, and across the entire LW spectrum is equal to unity. There is strong evidence, however, that emissivity of many surface materials is significantly lower than unity, and varies considerably across the LW spectrum. We have developed global maps of surface emissivity for the broadband LW region, the thermal infrared window region (8-12 micron), and 12 narrow LW spectral bands. The 17 surface types defined by the International Geosphere Biosphere Programme (IGBP) were adopted as such, and an additional (18th) surface type was introduced to represent tundra-like surfaces. Laboratory measurements of spectral reflectances of 10 different surface materials were converted to corresponding emissivities. The 10 surface materials were then associated with 18 surface types. Emissivities for the 18 surface types were first computed for each of the 12 narrow spectral bands. Emissivities for the broadband and the window region were then constituted from the spectral band values by weighting them with Planck function energy distribution.

Dayglow emissions of the O2 Herzberg bands and the Rayleigh backscattered spectrum of the earth

NASA Technical Reports Server (NTRS)

Frederick, J. E.; Abrams, R. B.

1982-01-01

It is pointed out that numerous fluorescent emissions from the Herzberg bands of molecular oxygen lie in the spectral region 242-300 nm. This coincides with the wavelength range used by orbiting spectrometers that observe the Rayleigh backscattered spectrum of the earth for the purpose of monitoring the vertical distribution of stratospheric ozone. Model calculations suggest that Herzberg band emissions in the dayglow could provide significant contamination of the ozone measurements if the quenching rate of O2(A3Sigma) is sufficiently small. It is noted that this is especially true near 255 nm, where the most intense fluorescent emissions relative to the Rayleigh scattered signal are located and where past satellite measurements have shown a persistent excess radiance above that expected for a pure ozone absorbing and molecular scattering atmosphere. Very small quenching rates, however, are adequate to reduce the dayglow emission to negligible levels. Noting that available laboratory data have not definitely established the quenching on the rate of O2(A3Sigma) as a function of vibration level, it is emphasized that such information is required before the Herzberg band contributions can be evaluated with confidence.

Spectral Selectivity of Plasmonic Interactions between Individual Up-Converting Nanocrystals and Spherical Gold Nanoparticles.

PubMed

Piątkowski, Dawid; Schmidt, Mikołaj K; Twardowska, Magdalena; Nyk, Marcin; Aizpurua, Javier; Maćkowski, Sebastian

2017-08-04

We experimentally demonstrate strong spectral selectivity of plasmonic interaction that occurs between α-NaYF₄:Er 3+ /Yb 3+ nanocrystals, which feature two emission bands, and spherical gold nanoparticles, with plasmon frequency resonant with one of the emission bands. Spatially-resolved luminescence intensity maps acquired for individual nanocrystals, together with microsecond luminescence lifetime images, show two qualitatively different effects that result from the coupling between plasmon excitations in metallic nanoparticles and emitting states of the nanocrystals. On the one hand, we observe nanocrystals, whose emission intensity is strongly enhanced for both resonant and non-resonant bands with respect to the plasmon resonance. Importantly, this increase is accompanied with shortening of luminescence decays times. In contrast, a significant number of nanocrystals exhibits almost complete quenching of the emission resonant with the plasmon resonance of gold nanoparticles. Theoretical analysis indicates that such an effect can occur for emitters placed at distances of about 5 nm from gold nanoparticles. While under these conditions, both transitions experience significant increases of the radiative emission rates due to the Purcell effect, the non-radiative energy transfer between resonant bands results in strong quenching, which in that situation nullifies the enhancement.

Modification of electronic properties of graphene by using low-energy K{sup +} ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Jingul; Lee, Paengro; Ryu, Mintae

2016-05-02

Despite its superb electronic properties, the semi-metallic nature of graphene with no band gap (E{sub g}) at the Dirac point has been a stumbling block for its industrial application. We report an improved means of producing a tunable band gap over other schemes by doping low energy (10 eV) potassium ions (K{sup +}) on single layer graphene formed on 6H-SiC(0001) surface, where the noble Dirac nature of the π-band remains almost unaltered. The changes in the π-band induced by K{sup +} ions reveal that the band gap increases gradually with increasing dose (θ) of the ions up to E{sub g} = 0.65 eV atmore » θ = 1.10 monolayers, demonstrating the tunable character of the band gap. Our core level data for C 1s, Si 2p, and K 2p suggest that the K{sup +}-induced asymmetry in charge distribution among carbon atoms drives the opening of band gap, which is in sharp contrast with no band gap when neutral K atoms are adsorbed on graphene. This tunable K{sup +}-induced band gap in graphene illustrates its potential application in graphene-based nano-electronics.« less

Excitation of O+ Band EMIC Waves Through H+ Ring Velocity Distributions: Van Allen Probe Observations

NASA Astrophysics Data System (ADS)

Yu, Xiongdong; Yuan, Zhigang; Huang, Shiyong; Yao, Fei; Wang, Dedong; Funsten, Herbert O.; Wygant, John R.

2018-02-01

A typical case of electromagnetic ion cyclotron (EMIC) emissions with both He+ band and O+ band waves was observed by Van Allen Probe A on 14 July 2014. These emissions occurred in the morning sector on the equator inside the plasmasphere, in which region O+ band EMIC waves prefer to appear. Through property analysis of these emissions, it is found that the He+ band EMIC waves are linearly polarized and propagating quasi-parallelly along the background magnetic field, while the O+ band ones are of linear and left-hand polarization and propagating obliquely with respect to the background magnetic field. Using the in situ observations of plasma environment and particle data, excitation of these O+ band EMIC waves has been investigated with the linear growth theory. The calculated linear growth rate shows that these O+ band EMIC waves can be locally excited by ring current protons with ring velocity distributions. The comparison of the observed wave spectral intensity and the calculated growth rate suggests that the density of H+ rings providing the free energy for the instability has decreased after the wave grows. Therefore, this paper provides a direct observational evidence to the excitation mechanism of O+ band EMIC waves: ring current protons with ring distributions provide the free energy supporting the instability in the presence of rich O+ in the plasmasphere.

Emission coefficients for the OH Meinel band system; calculations and nightglow comparisons

NASA Astrophysics Data System (ADS)

Slanger, T. G.

2016-12-01

The OH Meinel band system is an extensive series of bands that are transitions between the vibrational levels of the X2Π ground-state of the molecule. The exothermicity of the source reaction is sufficient to populate up to OH(v = 9), and in fact the nascent reaction puts most of the product into that level. Subsequently, relaxation of the population to lower levels takes place via collisions with the ambient atmosphere and radiation within the OH(v) manifold. Considerable effort has been spent in determining the emission coefficients of the OH Meinel band system. This emission is a prominent feature of the terrestrial nightglow, and because it is relatively intense, there have been numerous investigations, generally based on ground-based instrumentation. The very exothermic source reaction, H + O3 → OH(v) + O2, results in the production of vibrationally and rotationally hot OH(v), and leads to a great number of OH emission lines, covering a wide spectral range, 500-2000 nm. The full range of energy-accessible OH vibrational levels, up to v = 9, is produced in the reaction, and in this presentation we make the case that it is essential to simultaneously measure as many OH bands as possible, to retrieve the maximum amount of spectroscopic and dynamic information. In order to do so, we must agree on the emission coefficients (A-factors) associated with the individual OH bands, and this determination has presented problems in the past. A major advance in the study of atmospheric OH Meinel band emission took place when astronomical sky spectra were utilized to record all accessible OH bands simultaneously, from Mauna Kea [Cosby and Slanger, 2007]. Subsequently, similar studies were undertaken at the VLT [Noll et al. 2015 a,b], and at the GIANO-TNG [Oliva et al., 2015]. With these intensity-calibrated spectra, it becomes possible to compare the OH optical data with sets of A-factor calculations that have been presented over the years [Mies, 1974; Turnbull and Lowe, 1989; Langhoff et al., 1986; Goldman et al., 1998; Pendleton and Taylor, 2002; van der Loo and Groenenboom, 2007; Brooke et al., 2016] and others. We conclude that the most recent determinations provide the best representation of the Meinel band A-factors. AcknowledgementsThis work has been supported by NSF Aeronomy grants, with the participation of Dr. Philip Cosby.

Experimental and first-principles study of photoluminescent and optical properties of Na-doped CuAlO2: the role of the NaAl-2Na i complex

NASA Astrophysics Data System (ADS)

Liu, Ruijian; Li, Yongfeng; Yao, Bin; Ding, Zhanhui; Deng, Rui; Zhang, Ligong; Zhao, Haifeng; Liu, Lei

2015-08-01

We report that a band-tail emission at 3.08 eV, lower than near-band-edge energy, is observed in photoluminescence measurements of bulk Na-doped CuAlO2. The band-tail emission is attributed to Na-related defects. Electronic structure calculations based on the first-principles method demonstrate that the donor-acceptor compensated complex of NaAl-2Na i in Na-doped CuAlO2 plays a key role in leading to the band-tail emission and bandgap narrowing. Furthermore, Hall effect measurements indicates that the hole concentration in CuAlO2 is independent on Na doping, which is well understood by the donor-acceptor compensation effect of NaAl-2Na i complex.

Density Measurements in Air by Optically Exciting the Cordes Bands of I2

NASA Technical Reports Server (NTRS)

Balla, R. Jeffrey; Exton, Reginald J.

2000-01-01

We describe an optical method based on laser-induced fluorescence for obtaining instantaneous measurements of density along a line in low-density air seeded with I2. The Cordes bands of I2 (D(sup 1)sigma(sup +, sub u)) left arrow X(sup 1)sigma(sup +, sub g)) are excited with a tunable ArF excimer laser. air densities in the range (0.1-6.5) x 10(exp 17) cm(exp -3) are measured over 295-583 K using the density-dependent emission ratio of two emission bands of I2; the 340 nm bands and the diffuse-structured McLennan bands near 320 nm.

Evolution of near UV Halley's spectrum in the inner coma

NASA Technical Reports Server (NTRS)

Rousselot, Phillippe; Clairemidi, Jacques; Vernotte, F.; Moreels, Guy

1992-01-01

A direct way to observe the photodissociation of water vapor in a cometary coma is to detect the OH prompt emission. This emission is shifted of delta lambda = 4 nm with respect to the OH 309 nm fluorescence band. The extended data set obtained with the three-channel spectrometer on-board Vega 2 reveals at short distance of the nucleus (i.e., less than 600 km) an excess of emission on the right wing of the OH band which may be interpreted as being mainly due to prompt emission.

Electrostatic Graphene Loudspeaker

DTIC Science & Technology

2013-06-01

millennia, with classic examples being drum- heads and whistles for long-range communications and entertainment .4 In modern society, efficient small...harmonic oscilla- tor. Unlike most insect or musical instrument resonators which exhibit lightly damped sharp frequency response, a wide-band audio...sound signal is introduced from a signal generator or from a commercial laptop or digital music player. The maximum amplitude of the input signal Vin

Near-infrared emission bands of TeH and TeD

NASA Astrophysics Data System (ADS)

Fink, E. H.; Setzer, K. D.; Ramsay, D. A.; Vervloet, M.

1989-11-01

High-resolution emission spectra of TeH and TeD have been obtained in the region 4200 to 3600 cm -1 using a Bomem DA3.002 Fourier transform spectrometer. Analyses are given for the 0-0 and 1-1 bands of the X 22Π{1}/{2}-X 12Π{3}/{2} system of TeH and for the 0-0 band of TeD. In addition the 2-0 vibrational overtone bands of 130TeH, 128TeH, and 126TeH are observed and analyzed. Accurate molecular constants are given for the first time.

Histopathological Muscle Findings May Be Essential for a Definitive Diagnosis of Suspected Sharp Trauma Associated with Ship Strikes in Stranded Cetaceans

PubMed Central

Sierra, Eva; Fernández, Antonio; Espinosa de los Monteros, Antonio; Arbelo, Manuel; Díaz-Delgado, Josué; Andrada, Marisa; Herráez, Pedro

2014-01-01

Ship strikes are a major issue for the conservation of may cetacean species. Certain gross and microscopic criteria have been previously reported for establishing a diagnosis of death due to ship strikes in these animals. However, some ship-strike injuries may be masked by advanced carcass decomposition and may be undetectable due to restricted access to the animals. In this report we describe histopathological muscular findings in 13 cetaceans with sharp trauma from ship strikes as the cause of death. Skeletal muscle samples were taken from the incision site and from the main locomotor muscle, the longissimus dorsi, in areas not directly affected by the sharp injury. The microscopic findings in tissues from both sites mainly consisted of haemorrhages; oedema; flocculent, granular or/and hyalinised segmentary degeneration; contraction band necrosis; and discoid degeneration or fragmentation of myofibres. We propose that skeletal muscle histopathology provides evidence of ante-mortem injuries even if the sample was taken elsewhere in the carcass and not only within or adjacent to the sharp trauma site and despite the advanced decomposition of some of the carcasses. This method helps to establish the diagnosis of ship strike as the cause of death. PMID:24551162

Impact on carbon footprint: a life cycle assessment of disposable versus reusable sharps containers in a large US hospital.

PubMed

Grimmond, Terry; Reiner, Sandra

2012-06-01

Hospitals are striving to reduce their greenhouse gas (GHG) emissions. Targeting supply chain points and replacing disposable with reusable items are among recommendations to achieve this. Annually, US hospitals use 35 million disposable (DSC) or reusable sharps containers (RSC) generating GHG in their manufacture, use, and disposal. Using a life cycle assessment we assessed the global warming potential (GWP) of both systems at a large US hospital which replaced DSC with RSC. GHG emissions (CO(2), CH(4), N(2)O) were calculated in metric tons of CO(2) equivalents (MTCO(2)eq). Primary energy input data was used wherever possible and region-specific conversions used to calculate the GWP of each activity. Unit process GHGs were collated into manufacture, transport, washing, and treatment and disposal. The DSC were not recycled nor had recycled content. Chemotherapy DSC were used in both systems. Emission totals were workload-normalized per 100 occupied beds-yr and rate ratio analyzed using Fisher's test with P ≤0.05 and 95% confidence level. With RSC, the hospital reduced its annual GWP by 127 MTCO(2)eq (-83.5%) and diverted 30.9 tons of plastic and 5.0 tons of cardboard from landfill. Using RSC reduced the number of containers manufactured from 34,396 DSC annually to 1844 RSC in year one only. The study indicates sharps containment GWP in US hospitals totals 100,000 MTCO(2)eq and if RSC were used nationally the figure could fall by 64,000 MTCO(2)eq which, whilst only a fraction of total hospital GWP, is a positive, sustainable step.

Investigation of narrow-band thermal emission from intersubband transitions in quantum wells

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Zoysa, M.; Hakubi Center, Kyoto University, Yoshida, Kyoto 606-8501; Asano, T.

2015-09-14

We investigate thermal emission from n-doped GaAs/AlGaAs quantum wells (QWs). Emission peaks with Lorentzian shapes (linewidth 11∼19 meV) that reflect transitions between the first and second conduction subbands are observed in the mid-infrared range. It is demonstrated that the emission characteristics can be tuned by modifying the QW parameters. The peak emissivity is increased from 0.3 to 0.9 by modifying the doping density, and the peak wavelength is tuned from 6 to 10 μm by changing the well width. The obtained results are useful for the design of narrow-band thermal emitters.

Windrow composting mitigated CH4 emissions: characterization of methanogenic and methanotrophic communities in manure management.

PubMed

Chen, Ruirui; Wang, Yiming; Wei, Shiping; Wang, Wei; Lin, Xiangui

2014-12-01

With increasing livestock breeding, methane (CH4 ) emissions from manure management will increasingly contribute more to atmospheric CH4 concentration. The dynamics of methanogens and methanotrophs have not yet been studied in the manure environment. The current study combines surface CH4 emissions with methanogenic and methanotrophic community analyses from two management practices, windrow composting (WCOM) and solid storage (SSTO). Our results showed that there was an c. 50% reduction of CH4 emissions with WCOM compared with SSTO over a 50-day period. A sharp decrease in the quantities of both methanogens and methanotrophs in WCOM suggested that CH4 mitigation was mainly due to decreased CH4 production rather than increased CH4 oxidation. Pyrosequencing analysis demonstrated that aeration caused a clear shift of dominant methanogens in the manure, with specifically a significant decrease in Methanosarcina and increase in Methanobrevibacter. The composition of methanogenic community was influenced by manure management and regulated CH4 production. A sharp increase in the quantity of methanotrophs in SSTO suggested that microbial CH4 oxidation is an important sink for the CH4 produced. The increased abundance of Methylococcaceae in SSTO suggested that Type I methanotrophs have an advantage in CH4 oxidation in occupying niches under low CH4 and high O2 conditions. © 2014 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

A Comparative Cathodoluminescence Emission Study of Feldspathic Glasses in SNC Meteorites and Quenched Melts of These Glasses

NASA Astrophysics Data System (ADS)

Kubny, A.; Jagoutz, E.

2001-12-01

In this study the cathodoluminescence (electron-excited luminescence) emission spectra were measured in the range 200 to 900 nm of individual feldspathic glass grains in the SNC meteorites Shergotty 101, Shergotty 232, ALHA 84001, EETA 79001-47, EETA 79001-276, and Dar al Gani 476 and those of quenched melts of the feldspathic glass grains. The quenching experiments of the original feldspathic glasses were conducted at 1500° C and atmospheric pressure. The aim of this CL emission study was the characterization of feldspathic glasses of SNC meteorites by comparison of the diagnostic spectral features of the feldspathic glasses of SNC meteorites with those of their quenched melts. In the CL emission spectra of the studied feldspathic glasses generally broad bands in the blue (ca. 460 nm), green (ca. 560 nm), and red (ca. 700 nm) can appear. These emission bands are assigned to structural defects (Al-O--Al centers), and the structural incorporation of Mn2+ and Fe3+ , respectively. The blue emission band at about 460 nm attributed to Al-O--Al centers is observed in the spectra of the original feldspathic glasses whereas it is not present (or only in low relative intensity) in the spectra of the quenched melts. The green emission band at 550 to 575 nm assigned to electronic transitions of Mn2+ in M sites is observed in the spectra of the original feldspathic glasses. It is shifted to longer wavelengths of 590 to 605 nm in the spectra of the quenched melts. The occurrence of the red emission band at about 700 nm attributed to electronic transition of Fe3+ in the spectra of the quenched melts of the feldspathic glasses indicates the presence of structural units which allow the occupancy of Fe3+ on tetrahedral sites. The results obtained by CL emission spectroscopy confirm results of Raman spectroscopic studies that the stuctures of feldspathic glasses of the studied SNC meteorites are modified by melting and quenching at atmospheric pressure. Additionally, comparison with published work on CL emission of shocked oligoclases shows that the feldspathic glasses of the studied SNC meteorites are not diaplectic but melt glasses.

A study of the spectrum of HD 108, an unusual Of star

NASA Astrophysics Data System (ADS)

Underhill, Anne B.

1994-01-01

Spectra of the peculiar O star HD 108 obtained at a scale of 30 A/mm in the years 1986-1991 have been studied for line displacements and line profiles. The wavelength regions covered are 4180-5050 A, 5100-5980 A, and 6180-7070 A. The spectra were recorded with a Reticon, and most have a signal-to-noise ratio per pixel in the continuum greater than 200. It is argued that the spectral type is best described as O7fpe III. The spectrum at the time of observation was similar to te description given by Plaskett (1924), but the radial velocity has changed. In 1922 and 1923 the absorption lines and the emission lines showed a displacement of -62 km/s. In the ensuing years the radial velocity shown by the absorption lines, mostly He II, N III, and O III, has changed to about -84 km/s in 1991. The emission-line velocity remained near -62 km/s until about 1991, when this radial velocity became (apparently) about -66 km/s. There is some reason to suspect that the last few spectra obtained in 1991 suffer from a small random negative shift. The meaning of the radial velocity results is discussed, and it is argued that by 1973 the photosphere may have begun to undergo an outward surge. The change of motion shown by the emission lines is less than that shown by the photospheric absorption lines. It is argued that the emission lines, both the strong sharp emission lines due to H and He I and the weaker lines due to C II, C III, N II, O II, and Si III, are formed in a polar jet which is moving almost perpendicular to the line of sight. The star HD 108 appears to be related to the luminous blues variables (LBVs) and to the B(e) stars. No forbidden emission lines, as from a nebula, were detected in the visible spectral range. Strong distinctive P Cygni type displaced absorption components for the H and He I lines are not seen. Rather, one sees a sharp emission line superposed on a photospehric absorption line. The absence of a strong P Cygni type absorption component indicates that the optical depth along the line of sight to the jet is small in the H and He I lines. The profiles of the H and He I emission components are somewhat asymmetric. This suggests that weak P Cygni type absorption takes place in the plasma forming the emission lines.

No evidence for Lyman α emission in spectroscopy of z > 7 candidate galaxies

NASA Astrophysics Data System (ADS)

Caruana, Joseph; Bunker, Andrew J.; Wilkins, Stephen M.; Stanway, Elizabeth R.; Lacy, Mark; Jarvis, Matt J.; Lorenzoni, Silvio; Hickey, Samantha

2012-12-01

We present Gemini/Gemini Near Infrared Spectrograph (GNIRS) spectroscopic observations of four z-band (z ≈ 7) dropout galaxies and Very Large Telescope (VLT)/XSHOOTER observations of one z-band dropout and three Y-band (z ≈ 8-9) dropout galaxies in the Hubble Ultra Deep Field, which were selected with Wide Field Camera 3 imaging on the Hubble Space Telescope. We find no evidence of Lyman α emission with a typical 5σ sensitivity of 5 × 10-18 erg cm-2 s-1, and use the upper limits on Lyman α flux and the broad-band magnitudes to constrain the rest-frame equivalent widths for this line emission. Accounting for incomplete spectral coverage, we survey 3.0 z-band dropouts and 2.9 Y-band dropouts to a Lyman α rest-frame equivalent width limit >120 Å (for an unresolved emission line); for an equivalent width limit of 50 Å the effective numbers of drop-outs surveyed fall to 1.2 z-band drop-outs and 1.5 Y-band drop-outs. A simple model where the fraction of high rest-frame equivalent width emitters follows the trend seen at z = 3-6.5 is inconsistent with our non-detections at z = 7-9 at the ≈1σ level for spectrally unresolved lines, which may indicate that a significant neutral H I fraction in the intergalactic medium suppresses the Lyman α line in z-drop and Y-drop galaxies at z > 7. Based on observations collected at the European Organization for Astronomical Research in the Southern Hemisphere, Chile, as part of programme 086.A-0968(B).

Single Molecule Detection in Living Biological Cells using Carbon Nanotube Optical Probes

NASA Astrophysics Data System (ADS)

Strano, Michael

2009-03-01

Nanoscale sensing elements offer promise for single molecule analyte detection in physically or biologically constrained environments. Molecular adsorption can be amplified via modulation of sharp singularities in the electronic density of states that arise from 1D quantum confinement [1]. Single-walled carbon nanotubes (SWNT), as single molecule optical sensors [2-3], offer unique advantages such as photostable near-infrared (n-IR) emission for prolonged detection through biological media, single-molecule sensitivity and, nearly orthogonal optical modes for signal transduction that can be used to identify distinct classes of analytes. Selective binding to the SWNT surface is difficult to engineer [4]. In this lecture, we will briefly review the immerging field of fluorescent diagnostics using band gap emission from SWNT. In recent work, we demonstrate that even a single pair of SWNT provides at least four optical modes that can be modulated to uniquely fingerprint chemical agents by the degree to which they alter either the emission band intensity or wavelength. We validate this identification method in vitro by demonstrating detection and identification of six genotoxic analytes, including chemotherapeutic drugs and reactive oxygen species (ROS), which are spectroscopically differentiated into four distinct classes. We also demonstrate single-molecule sensitivity in detecting hydrogen peroxide, one of the most common genotoxins and an important cellular signal. Finally, we employ our sensing and fingerprinting method of these analytes in real time within live 3T3 cells, demonstrating the first multiplexed optical detection from a nanoscale biosensor and the first label-free tool to optically discriminate between genotoxins. We will also discuss our recent efforts to fabricate biomedical sensors for real time detection of glucose and other important physiologically relevant analytes in-vivo. The response of embedded SWNT in a swellable hydrogel construct to osmotic pressure gradients will be discussed, as well as its potential as a unique transduction mechanism for a new class of implantable sensors. [4pt] [1] Saito, R., Dresselhaus, G. & Dresselhaus, M. S. Physical Properties of Carbon Nanotubes (Imperial College Press, London, 1998). [0pt] [2] Barone, P. W., Baik, S., Heller, D. A. & Strano, M. S. Near-Infrared Optical Sensors Based on Single-Walled Carbon Nanotubes. Nature Materials 4, 86-92 (2005). [0pt] [3] Jeng, E. S., Moll, A. E., Roy, A. C., Gastala, J. B. & Strano, M. S. Detection of DNA hybridization using the near infrared band-gap fluorescence of single-walled carbon nanotubes. Nano Letters 6, 371-375 (2006). [0pt] [4] Heller, D. A. et al. Optical detection of DNA conformational polymorphism on single-walled carbon nanotubes. Science 311, 508-511 (2006).

Moderate Resolution Imaging Spectroradiometer (MODIS) MOD21 Land Surface Temperature and Emissivity Algorithm Theoretical Basis Document

NASA Technical Reports Server (NTRS)

Hulley, G.; Malakar, N.; Hughes, T.; Islam, T.; Hook, S.

2016-01-01

This document outlines the theory and methodology for generating the Moderate Resolution Imaging Spectroradiometer (MODIS) Level-2 daily daytime and nighttime 1-km land surface temperature (LST) and emissivity product using the Temperature Emissivity Separation (TES) algorithm. The MODIS-TES (MOD21_L2) product, will include the LST and emissivity for three MODIS thermal infrared (TIR) bands 29, 31, and 32, and will be generated for data from the NASA-EOS AM and PM platforms. This is version 1.0 of the ATBD and the goal is maintain a 'living' version of this document with changes made when necessary. The current standard baseline MODIS LST products (MOD11*) are derived from the generalized split-window (SW) algorithm (Wan and Dozier 1996), which produces a 1-km LST product and two classification-based emissivities for bands 31 and 32; and a physics-based day/night algorithm (Wan and Li 1997), which produces a 5-km (C4) and 6-km (C5) LST product and emissivity for seven MODIS bands: 20, 22, 23, 29, 31-33.

The far-ultraviolet spectra and geometric albedos of Jupiter and Saturn

NASA Technical Reports Server (NTRS)

Clarke, J. T.; Moos, H. W.; Feldman, P. D.

1982-01-01

Spectra and geometric albedoes in the range 1200 to 1940 A are compiled for Jupiter and Saturn on the basis of IUE observations. The spectra of both planets are dominated by H Lyman-alpha emission line at 1216 A, although absorption bands of C2H2 are apparent at longer wavelengths, particularly in the spectrum of Saturn, and the C I line at 1657 A is also observed. Geometric albedoes show emission features corresponding to the weak H2 Lyman and Werner bands around 1230-1280 A, auroral Lyman band emission, C I emission, and C2H2 absorption from 1600 to 1900 A. A model of atmospheric absorption in homogeneously mixed atmospheres of H2 and trace molecular absorbers is then presented and fit to the Jupiter albedo, resulting in a predicted atmosphere containing C2H2 and an unidentified molecular or particulate absorber. Finally, north-south maps of Jupiter continuum emission show limb darkening, and a comparison of equatorial and polar spectra indicates a polar increase in C2H2 absorption and weaker polar H2 emissions than previously reported.

Resolution improvement in positron emission tomography using anatomical Magnetic Resonance Imaging.

PubMed

Chu, Yong; Su, Min-Ying; Mandelkern, Mark; Nalcioglu, Orhan

2006-08-01

An ideal imaging system should provide information with high-sensitivity, high spatial, and temporal resolution. Unfortunately, it is not possible to satisfy all of these desired features in a single modality. In this paper, we discuss methods to improve the spatial resolution in positron emission imaging (PET) using a priori information from Magnetic Resonance Imaging (MRI). Our approach uses an image restoration algorithm based on the maximization of mutual information (MMI), which has found significant success for optimizing multimodal image registration. The MMI criterion is used to estimate the parameters in the Sharpness-Constrained Wiener filter. The generated filter is then applied to restore PET images of a realistic digital brain phantom. The resulting restored images show improved resolution and better signal-to-noise ratio compared to the interpolated PET images. We conclude that a Sharpness-Constrained Wiener filter having parameters optimized from a MMI criterion may be useful for restoring spatial resolution in PET based on a priori information from correlated MRI.

Enhanced Spontaneous Emission of Bloch Oscillation Radiation from a Single Energy Band

DTIC Science & Technology

2006-06-30

ignore interband tunneling , spon- taneous photon emission occurs as the Bloch electron inter- acts with the quantum radiation field; the emission occurs... interband coupling 17 and electron intraband scattering are ignored. Therefore, the quantum dynamics is described by the time-dependent Schrödinger...single band “n0” of a periodic crystal with energy n0K; the ef- fects of interband coupling15 and electron intraband scatter- ing are ignored

Satellite Moisture Retrieval Techniques. Volume 2. Atmospheric Sounding Bibliography

DTIC Science & Technology

1983-01-01

Jerusalem, Israel 14. THE SPECTRAL EMISSION OF THE ATMOSPHERE IN THE SUBMILLIMETRE BAND Igoshin, F. F.; Kir’Yanov, A. P.; Kuzenkov, A. F.; Mozhaev ...THE SPECTRAL EMISSION OF THE ATMOSPHERE IN THE SUBMILLIMETRE BAND Igoshin, F. F.; Kir’Yanov, A. P.; Kuzenkov, A. F.; Mozhaev , V. V.; Rudakov, V. V

Auroral excitation of the N2 2P(0,0) and VK(0,9) bands

NASA Technical Reports Server (NTRS)

Solomon, Stanley C.

1989-01-01

The low-energy secondary electron flux caused by auroral electron precipitation is examined using data from the Atmosphere Explorer C satellite. An energetic electron transport algorithm is used to compute the differential electron flux produced by measured primaries. Emissions of N2 in the 2P(0,0) band at 337 nm and the VK(0,9) band at 335 nm predicted by the model are compared with photometric observation of their combined volume emission rate altitude profile made by the visible airglow experiment. Reasonable correspondence between model and measurement is obtained. Ratios of emissions at 337 nm and 630 nm to the N2(+) 1N(0,0) band at 428 nm are also studied. It is concluded that the 337/428 nm ratio responds to changes in the characteristic energy of primary auroral electrons only insofar as part of the 337 nm brightness is due to N2 VK(0,9) emission. The 630/428 nm ratio, which is strongly dependent on characteristic energy, also varies significantly with changes in atomic oxygen density.

Activation of an intense near band edge emission from ZnTe/ZnMgTe core/shell nanowires grown on silicon.

PubMed

Wojnar, P; Szymura, M; Zaleszczyk, W; Kłopotowski, L; Janik, E; Wiater, M; Baczewski, L T; Kret, S; Karczewski, G; Kossut, J; Wojtowicz, T

2013-09-13

The absence of luminescence in the near band edge energy region of Te-anion based semiconductor nanowires grown by gold catalyst assisted molecular beam epitaxy has strongly limited their applications in the field of photonics. In this paper, an enhancement of the near band edge emission intensity from ZnTe/ZnMgTe core/shell nanowires grown on Si substrates is reported. A special role of the use of Si substrates instead of GaAs substrates is emphasized, which results in an increase of the near band edge emission intensity by at least one order of magnitude accompanied by a simultaneous reduction of the defect related luminescence. A possible explanation of this effect relies on the presence of Ga-related deep level defects in structures grown on GaAs substrates, which are absent when Si substrates are used. Monochromatic mapping of the cathodoluminescence clearly confirms that the observed emission originates, indeed, from the ZnTe/ZnMgTe core/shell nanowires, whereas individual objects are studied by means of microphotoluminescence.

IRAS surface brightness maps of reflection nebulae in the Pleiades

NASA Technical Reports Server (NTRS)

Castelaz, Michael W.; Werner, M. W.; Sellgren, K.

1987-01-01

Surface brightness maps at 12, 25, 60, and 100 microns were made of a 2.5 deg x 2.5 deg area of the reflection nebulae in the Pleiades by coadding IRAS scans of this region. Emission is seen surrounding 17 Tau, 20 Tau, 23 Tau, and 25 Tau in all four bands, coextensive with the visible reflection nebulosity, and extending as far as 30 arcminutes from the illuminating stars. The infrared energy distributions of the nebulae peak in the 100 micron band, but up to 40 percent of the total infrared power lies in the 12 and 25 micron bands. The brightness of the 12 and 25 micron emission and the absence of temperature gradients at these wavelengths are inconsistent with the predictions of equilibrium thermal emission models. The emission at these wavelengths appears to be the result of micron nonequilibrium emission from very small grains, or from molecules consisting of 10-100 carbon atoms, which have been excited by ultraviolet radiation from the illuminating stars.

Portable Integrated Wireless Device Threat Assessment to Aircraft Radio Systems

NASA Technical Reports Server (NTRS)

Salud, Maria Theresa P.; Williams, Reuben A. (Technical Monitor)

2004-01-01

An assessment was conducted on multiple wireless local area network (WLAN) devices using the three wireless standards for spurious radiated emissions to determine their threat to aircraft radio navigation systems. The measurement process, data and analysis are provided for devices tested using IEEE 802.11a, IEEE 802.11b, and Bluetooth as well as data from portable laptops/tablet PCs and PDAs (grouping known as PEDs). A comparison was made between wireless LAN devices and portable electronic devices. Spurious radiated emissions were investigated in the radio frequency bands for the following aircraft systems: Instrument Landing System Localizer and Glideslope, Very High Frequency (VHF) Communication, VHF Omnidirectional Range, Traffic Collision Avoidance System, Air Traffic Control Radar Beacon System, Microwave Landing System and Global Positioning System. Since several of the contiguous navigation systems were grouped under one encompassing measurement frequency band, there were five measurement frequency bands where spurious radiated emissions data were collected for the PEDs and WLAN devices. The report also provides a comparison between emissions data and regulatory emission limit.

Hard X-ray Flux from Low-Mass Stars in the Cygnus OB2 Association

NASA Astrophysics Data System (ADS)

Caramazza, M.; Drake, J. J.; Micela, G.; Flaccomio, E.

2009-05-01

We investigate the X-ray emission in the 20-40 keV band expected from the flaring low-mass stellar population in Cygnus OB2 assuming that the observed soft X-ray emission is due to a superposition of flares and that the ratio of hard X-ray to soft X-ray emission is described by a scaling found for solar flares by Isola and co-workers. We estimate a low-mass stellar hard X-ray flux in the 20-40 keV band in the range ~7×1031-7×1033 erg/s and speculate the limit of this values. Hard X-ray emission could lie at a level not much below the current observed flux upper limits for Cygnus OB2. Simbol-X, with its broad energy band (10-100 keV) and its sensitivity should be able to detect this emission and would provide insights into the hard X-ray production of flares on pre-main sequence stars.

L Band Service Compatibility Part I: Optimum OOBE Compatibility

DOT National Transportation Integrated Search

2014-12-04

Discussion: -- Two Parts - Today we focus on optimum L Band ABC Out of Band Emission into GPS L1, OOBE. - Next ABC meeting will examine GPS-side mitigation of Adjacent Band Interference, ABI. -- Greater Compatibility: OOBE and ABI are distinct but pa...

GRB 091127: The cooling break race on magnetic fuel

NASA Astrophysics Data System (ADS)

Filgas, R.; Greiner, J.; Schady, P.; Krühler, T.; Updike, A. C.; Klose, S.; Nardini, M.; Kann, D. A.; Rossi, A.; Sudilovsky, V.; Afonso, P. M. J.; Clemens, C.; Elliott, J.; Nicuesa Guelbenzu, A.; Olivares E., F.; Rau, A.

2011-11-01

Aims: Using high-quality, broad-band afterglow data for GRB 091127, we investigate the validity of the synchrotron fireball model for gamma-ray bursts (GRBs), and infer physical parameters of the ultra-relativistic outflow. Methods: We used multi-wavelength (NIR to X-ray) follow-up observations obtained with GROND simultaneously in the g'r'i'z'JH filters and the XRT onboard the Swift satellite in the 0.3 to 10 keV energy range. The resulting afterglow light curve is of excellent accuracy with relative photometric errors as low as 1%, and the spectral energy distribution (SED) is well-sampled over 5 decades in energy. These data present one of the most comprehensive observing campaigns for a single GRB afterglow and allow us to test several proposed emission models and outflow characteristics in unprecedented detail. Results: Both the multi-color light curve and the broad-band SED of the afterglow of GRB 091127 show evidence of a cooling break moving from high to lower energies. The early light curve is well described by a broken power-law, where the initial decay in the optical/NIR wavelength range is considerably flatter than at X-rays. Detailed fitting of the time-resolved SED shows that the break is very smooth with a sharpness index of 2.2 ± 0.2, and evolves towards lower frequencies as a power-law with index - 1.23 ± 0.06. These are the first accurate and contemporaneous measurements of both the sharpness of the spectral break and its time evolution. Conclusions: The measured evolution of the cooling break (νc ∝ t~-1.2) is not consistent with the predictions of the standard model, wherein νc ∝ t~-0.5 is expected. A possible explanation for the observed behavior is a time dependence of the microphysical parameters, in particular the fraction of the total energy in the magnetic field ɛB. This conclusion provides further evidence that the standard fireball model is too simplistic, and time-dependent micro-physical parameters may be required to model the growing number of well-sampled afterglow light curves. Tables 3 and 4 are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/535/A57

A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3)

NASA Astrophysics Data System (ADS)

Frost, Ray L.; López, Andrés; Scholz, Ricardo; Belotti, Fernanda Maria; Xi, Yunfei

2015-02-01

Sidorenkite is a very rare low-temperature hydrothermal mineral, formed very late in the crystallization of hyperagpaitic pegmatites in a differentiated alkalic massif (Mt. Alluaiv, Kola Peninsula, Russia). Sidorenkite Na3Mn(PO4)(CO3) is a phosphate-carbonate of sodium and manganese. Such a formula with two oxyanions lends itself to vibrational spectroscopy. The sharp Raman band at 959 cm-1 and 1012 cm-1 are assigned to the PO43- stretching modes, whilst the Raman bands at 1044 cm-1 and 1074 cm-1 are attributed to the CO32- stretching modes. It is noted that no Raman bands at around 800 cm-1 for sidorenkite were observed. The infrared spectrum of sidorenkite shows a quite intense band at 868 cm-1 with other resolved component bands at 850 and 862 cm-1. These bands are ascribed to the CO32- out-of-plane bend (ν2) bending mode. The series of Raman bands at 622, 635, 645 and 704 cm-1 are assigned to the ν4 phosphate bending modes. The observation of multiple bands supports the concept of a reduction in symmetry of the carbonate anion from D3h or even C2v.

Vibrational spectroscopy of the phosphate mineral kovdorskite - Mg2PO4(OH)ṡ3H2O

NASA Astrophysics Data System (ADS)

Frost, Ray L.; López, Andrés; Xi, Yunfei; Granja, Amanda; Scholz, Ricardo; Lima, Rosa Malena Fernandes

2013-10-01

The mineral kovdorskite Mg2PO4(OH)ṡ3H2O was studied by electron microscopy, thermal analysis and vibrational spectroscopy. A comparison of the vibrational spectroscopy of kovdorskite is made with other magnesium bearing phosphate minerals and compounds. Electron probe analysis proves the mineral is very pure. The Raman spectrum is characterized by a band at 965 cm-1 attributed to the PO43- ν1 symmetric stretching mode. Raman bands at 1057 and 1089 cm-1 are attributed to the PO43- ν3 antisymmetric stretching modes. Raman bands at 412, 454 and 485 cm-1 are assigned to the PO43- ν2 bending modes. Raman bands at 536, 546 and 574 cm-1 are assigned to the PO43- ν4 bending modes. The Raman spectrum in the OH stretching region is dominated by a very sharp intense band at 3681 cm-1 assigned to the stretching vibration of OH units. Infrared bands observed at 2762, 2977, 3204, 3275 and 3394 cm-1 are attributed to water stretching bands. Vibrational spectroscopy shows that no carbonate bands are observed in the spectra; thus confirming the formula of the mineral as Mg2PO4(OH)ṡ3H2O.

Photonic band edge assisted spontaneous emission enhancement from all Er3+ 1-D photonic band gap structure

NASA Astrophysics Data System (ADS)

Chiasera, A.; Meroni, C.; Varas, S.; Valligatla, S.; Scotognella, F.; Boucher, Y. G.; Lukowiak, A.; Zur, L.; Righini, G. C.; Ferrari, M.

2018-06-01

All Er3+ doped dielectric 1-D Photonic Band Gap Structure was fabricated by rf-sputtering technique. The structure was constituted by of twenty pairs of SiO2/TiO2 alternated layers doped with Er3+ ions. The scanning electron microscopy was used to check the morphology of the structure. Transmission measurements put in evidence the stop band in the range 1500 nm-1950 nm. The photoluminescence measurements were obtained by optically exciting the sample and detecting the emitted light in the 1.5 μm region at different detection angles. Luminescence spectra and luminescence decay curves put in evidence that the presence of the stop band modify the emission features of the Er3+ ions.

Optical Band Gap Alteration of Graphene Oxide via Ozone Treatment.

PubMed

Hasan, Md Tanvir; Senger, Brian J; Ryan, Conor; Culp, Marais; Gonzalez-Rodriguez, Roberto; Coffer, Jeffery L; Naumov, Anton V

2017-07-25

Graphene oxide (GO) is a graphene derivative that emits fluorescence, which makes GO an attractive material for optoelectronics and biotechnology. In this work, we utilize ozone treatment to controllably tune the band gap of GO, which can significantly enhance its applications. Ozone treatment in aqueous GO suspensions yields the addition/rearrangement of oxygen-containing functional groups suggested by the increase in vibrational transitions of C-O and C=O moieties. Concomitantly it leads to an initial increase in GO fluorescence intensity and significant (100 nm) blue shifts in emission maxima. Based on the model of GO fluorescence originating from sp 2 graphitic islands confined by oxygenated addends, we propose that ozone-induced functionalization decreases the size of graphitic islands affecting the GO band gap and emission energies. TEM analyses of GO flakes confirm the size decrease of ordered sp 2 domains with ozone treatment, whereas semi-empirical PM3 calculations on model addend-confined graphitic clusters predict the inverse dependence of the band gap energies on sp 2 cluster size. This model explains ozone-induced increase in emission energies yielding fluorescence blue shifts and helps develop an understanding of the origins of GO fluorescence emission. Furthermore, ozone treatment provides a versatile approach to controllably alter GO band gap for optoelectronics and bio-sensing applications.

Strong Photonic-Band-Gap Effect on the Spontaneous Emission in 3D Lead Halide Perovskite Photonic Crystals.

PubMed

Zhou, Xue; Li, Mingzhu; Wang, Kang; Li, Huizeng; Li, Yanan; Li, Chang; Yan, Yongli; Zhao, Yongsheng; Song, Yanlin

2018-03-25

Stimulated emission in perovskite-embedded polymer opal structures is investigated. A polymer opal structure is filled with a perovskite, and perovskite photonic crystals are prepared. The spontaneous emission of the perovskite embedded in the polymer opal structures exhibits clear signatures of amplified spontaneous emission (ASE) via gain modulation. The difference in refractive-index contrast between the perovskite and the polymer opal is large enough for retaining photonic-crystals properties. The photonic band gap has a strong effect on the fluorescence emission intensity and lifetime. The stimulated emission spectrum exhibits a narrow ASE rather than a wide fluorescence peak in the thin film. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hurricane Season 2005: Katrina

NASA Technical Reports Server (NTRS)

2005-01-01

Seventeen days after Hurricane Katrina flooded New Orleans, much of the city is still under water. In this pair of images from the Advanced Spaceborne Thermal Emission and Reflection Radiometer on NASA's Terra satellite, the affected areas can clearly be seen. The top image mosaic was acquired in April and September 2000, and the bottom image was acquired September 13, 2005. The flooded parts of the city appear dark blue, such as the golf course in the northeast corner, where there is standing water. Areas that have dried out appear light blue gray, such as the city park in the left middle. On the left side of the image, the failed 17th street canal marks a sharp boundary between flooded city to the east, and dry land to the west.

The U.S. science team is located at NASA's Jet Propulsion Laboratory, Pasadena, Calif. The Terra mission is part of NASA's Science Mission Directorate.

Size: 10.4 by 7.1 kilometers Location: 30 degrees North latitude, 90.1 degrees West longitude Orientation: North at top Image Data: ASTER bands 1, 2, and 3 Original Data Resolution: 15 meters (49.2 feet) Dates Acquired: September 13, 2005

Fabrication of a high sensitivity and fast response self-powered photosensor based on a core-shell silicon nanowire homojunction

NASA Astrophysics Data System (ADS)

Abdul-Hameed, Assel A.; Mahdi, M. A.; Ali, Basil; Selman, Abbas M.; Al-Taay, H. F.; Jennings, P.; Lee, Wen-Jen

2018-04-01

Core-shell self-powered SiNWs homojunction photosensors have been fabricated. SiNWs are prepared by a metal assisted chemical etching method using different HF/H2O2 ratios and etching times. The length of the p-SiNWs increased as the H2O2 concentration and etching time increased. All the grown SiNWs show very low (∼0.7%) optical reflectance for the wavelength range of 200-1100 nm. Photoluminescence spectra of all prepared SiNWs show sharp and broad emission bands located in the red region of the light spectrum. Core-shell homojunction photosensors were fabricated by spin coating P2O2 onto the surface of the prepared p-SiNWs and annealed at 900 °C for 1 h. The fabricated devices exhibited photovoltaic behavior and high photosensitivity with fast response speed to the visible light. However, the sample that was fabricated using HF/H2O2 ratio of 1:1 showed the highest photosensitivity value of 3578% while the photosensor prepared using 2:1 ratio of HF/H2O2 gave the faster rise and decay time.

Efficient Tuning of Optical Properties and Morphology of Mesoscopic CdS via a Facile Route

NASA Astrophysics Data System (ADS)

Aslam, Samia; Mustafa, Faiza; Jamil, Ayesha; Abbas, Ghazanfar; Raza, Rizwan; Ahmad, Muhammad Ashfaq

2018-03-01

A facile and simple synthetic route has been employed to synthesize rod-shaped optically efficient cadmium sulfide (CdS) mesoscopic structures using high concentrations of cetyl trimethyl ammonium bromide (CTAB) as the stabilizing agent. The mesoscopic structures were characterized using x-ray diffaractometer (XRD), scanning electron microscopy, UV-visible, photoluminescence (PL), and Fourier transform and infrared (FTIR) spectroscopy. It was found that, if the concentration of CTAB is significantly higher than its critical micelle concentration, the nucleation of CdS mesoscopic structures resulted in rod-like structures. The size of the mesoscopic structures initially increased and then decreased with band gaps 2.5-2.7 eV. XRD analysis showed that the samples had a pure cubic phase confirming the particle size. The values of Urbach energy for the absorption tail states were determined and found to be in agreement with the single crystal. PL spectra showed sharp green emission peaks in the 530-nm to 560-nm wavelength range. FTIR spectra showed the adsorption mode of CTAB onto the CdS mesoscopic structures. A possible mechanism of formation of rod-shaped CdS mesoscopic structures is also elucidated.

Mini Survey of SDSS [OIII] AGN with Swift: Testing the Hypothesis that L(sub [OIII]) Traces AGN Luminosity

NASA Technical Reports Server (NTRS)

2007-01-01

The number of AGN and their luminosity distribution are crucial parameters for our understanding of the AGN phenomenon. Recent work strongly suggests every massive galaxy has a central black hole. However most of these objects either are not radiating or have been very difficult to detect We are now in the era of large surveys, and the luminosity function (LF] of AGN has been estimated in various ways. In the X-ray band. Chandra and XMM surveys have revealed that the LF of hard X-ray selected AGN shows a strong luminosity-dependent evolution with a dramatic break towards low L(sub x) (at all z). This is seen for all types of AGN, but is stronger for the broad-line objects. In sharp contrast, the local LF of optically-selected samples shows no such break and no differences between narrow and broad-line objects. If as been suggested, hard X ray and optical emission line can both can be fair indicators of AGN activity, it is important to first understand how reliable these characteristics are if we hope to understand the apparent discrepancy in the LFs.

Growth of semiconducting GaN hollow spheres and nanotubes with very thin shells via a controllable liquid gallium-gas interface chemical reaction.

PubMed

Yin, Long-Wei; Bando, Yoshio; Li, Mu-Sen; Golberg, Dmitri

2005-11-01

An in situ liquid gallium-gas interface chemical reaction route has been developed to synthesize semiconducting hollow GaN nanospheres with very small shell size by carefully controlling the synthesis temperature and the ammonia reaction gas partial pressure. In this process the gallium droplet does not act as a catalyst but rather as a reactant and a template for the formation of hollow GaN structures. The diameter of the synthesized hollow GaN spheres is typically 20-25 nm and the shell thickness is 3.5-4.5 nm. The GaN nanotubes obtained at higher synthesis temperatures have a length of several hundreds of nanometers and a wall thickness of 3.5-5.0 nm. Both the hollow GaN spheres and nanotubes are polycrystalline and are composed of very fine GaN nanocrystalline particles with a diameter of 3.0-3.5 nm. The room-temperature photoluminescence (PL) spectra for the synthesized hollow GaN spheres and nanotubes, which have a narrow size distribution, display a sharp, blue-shifted band-edge emission peak at 3.52 eV (352 nm) due to quantum size effects.

Variability of OH rotational temperatures on time scales from hours to 15 years by kinetic temperature variations, emission layer changes, and non-LTE effects

NASA Astrophysics Data System (ADS)

Noll, Stefan

2016-07-01

Rotational temperatures derived from hydroxyl (OH) line emission are frequently used to study atmospheric temperatures at altitudes of about 87 km. While the measurement only requires intensities of a few bright lines of an OH band, the interpretation can be complicated. Ground-based temperatures are averages for the entire, typically 8 km wide emission layer. Variations in the rotational temperature are then caused by changes of the kinetic temperature and the OH emission profile. The latter can also be accompanied by differences in the layer-averaged efficiency of the thermalisation of the OH rotational level populations. Since this especially depends on the frequency of collisions with O_2, which is low at high altitudes, the non-local thermodynamic equilibrium (non-LTE) contribution to the measured temperatures can be significant and variable. In order to understand the impact of the different sources of OH rotational temperature variations from time scales of hours to a solar cycle, we have studied spectra from the astronomical echelle spectrographs X-shooter and UVES located at Cerro Paranal in Chile. While the X-shooter data spanning 3.5 years allowed us to measure temperatures for 25 OH and two O_2 bands, the UVES spectra cover no more than 10 OH bands simultaneously but a period of about 15 years. These data have been complemented by kinetic temperature and OH and O_2 emission profiles from the multi-channel radiometer SABER on the TIMED satellite. Taking the O_2 and SABER kinetic temperatures as reference and considering the different band-dependent emission profiles, we could evaluate the contribution of non-LTE effects to the measured OH rotational temperatures depending on line set, band, and time. Non-LTE contributions are significant for most bands and can exceed 10 K. The amplitudes of their average nocturnal and seasonal variation are of the order of 1 to 2 K.

Intensities of the Venusian N2 electron-impact excited dayglow emissions

NASA Astrophysics Data System (ADS)

Fox, Jane L.; F. Hać, Nicholas E.

2013-12-01

Dayglow emissions are signatures of both the energy deposition into an atmosphere and the abundances of the species from which they arise. The first N2 dayglow emissions from Mars, the (0,5) and (0,6) bands of the N2 Vegard-Kaplan band system, were detected by the Spectroscopy for Investigations of the Characteristics of the Atmosphere of Mars (SPICAM) UV spectrometer on board the Mars Express spacecraft. The Vegard-Kaplan band system arises from the transition from the lowest N2 triplet state (A3Σu+;v') to the electronic ground state (X1Σg+;v″). It is populated by direct electron-impact excitation and by cascading from higher triplet states. The Venus UV dayglow is currently being probed by an instrument similar to SPICAM, the Spectroscopy for the Investigations of the Characteristics of the Atmosphere of Venus (SPICAV) UV spectrometer on Venus Express, but no N2 emissions have been detected. Because the N2 mixing ratios in the Venus thermosphere are larger than those in the thermosphere of Mars and the solar flux is greater at the orbit of Venus than that at Mars, we expect the Venus N2 emissions to be significantly more intense than those of Mars. A prediction of the intensities of various N2 emissions from Venus could be used to guide observations by the SPICAV and other instruments that are used to measure the Venus dayglow. Employing updated data, we here construct models of the low and high solar activity thermospheres of Venus, and we compute the integrated overhead intensities of 17 N2 band systems and limb profiles of the Vegard-Kaplan bands. The ratios of the predicted intensities of the various N2 bands at Venus to those at Mars are in the range 5.5-9.5.

Thermally switchable photonic band-edge to random laser emission in dye-doped cholesteric liquid crystals

NASA Astrophysics Data System (ADS)

Ye, Lihua; Wang, Yan; Feng, Yangyang; Liu, Bo; Gu, Bing; Cui, Yiping; Lu, Yanqing

2018-03-01

By changing the doping concentration of the chiral agent to adjust the relative position of the reflection band of cholesteric liquid crystals and the fluorescence emission spectrum of the dye, photonic band-edge and random lasing were observed, respectively. The reflection band of the cholesteric phase liquid crystal can also be controlled by adjusting the temperature: the reflection band is blue-shifted with increasing temperature, and a reversible switch from photonic band-edge to random lasing is obtained. Furthermore, the laser line width can be thermally adjusted from 1.1 nm (at 27 °C) to 4.6 nm (at 32.1 °C). A thermally tunable polarization state of a random laser from dual cells was observed, broadening the field of application liquid crystal random lasers.

Curiosity Destinations for Second Extended Mission

NASA Image and Video Library

2016-10-03

This map shows the route driven by NASA's Curiosity Mars rover from the location where it landed in August 2012 to its location in September 2016 at "Murray Buttes," and the path planned for reaching destinations at "Hematite Unit" and "Clay Unit" on lower Mount Sharp. Blue triangles mark waypoints investigated by Curiosity during the rover's two-year prime mission and first two-year extended mission. The Hematite Unit and Clay Unit are key destinations for the second two-year extension, through September 2018. The base image for the map is from the High Resolution Imaging Science Experiment (HiRISE) camera on NASA's Mars Reconnaissance Orbiter. North is up. Bagnold Dunes form a band of dark, wind-blown material at the foot of Mount Sharp. http://photojournal.jpl.nasa.gov/catalog/PIA20846

Image sharpness assessment based on wavelet energy of edge area

NASA Astrophysics Data System (ADS)

Li, Jin; Zhang, Hong; Zhang, Lei; Yang, Yifan; He, Lei; Sun, Mingui

2018-04-01

Image quality assessment is needed in multiple image processing areas and blur is one of the key reasons of image deterioration. Although great full-reference image quality assessment metrics have been proposed in the past few years, no-reference method is still an area of current research. Facing this problem, this paper proposes a no-reference sharpness assessment method based on wavelet transformation which focuses on the edge area of image. Based on two simple characteristics of human vision system, weights are introduced to calculate weighted log-energy of each wavelet sub band. The final score is given by the ratio of high-frequency energy to the total energy. The algorithm is tested on multiple databases. Comparing with several state-of-the-art metrics, proposed algorithm has better performance and less runtime consumption.

First Year Wilkinson Microwave Anisotropy Probe (WMAP) Observations: Foreground Emission

NASA Technical Reports Server (NTRS)

Bennett, C. L.; Hill, R. S.; Hinshaw, G.; Nolta, M. R.; Odegard, N.; Page, L.; Spergel, D. N.; Weiland, J. L.; Wright, E. L.; Halpern, M.

2003-01-01

The WMAP mission has mapped the full sky to determine the geometry, content, and evolution of the universe. Full sky maps are made in five microwave frequency bands to separate the temperature anisotropy of the cosmic microwave background (CMB) from foreground emission, including diffuse Galactic emission and Galactic and extragalactic point sources. We define masks that excise regions of high foreground emission, so CMB analyses can became out with minimal foreground contamination. We also present maps and spectra of the individual emission components, leading to an improved understanding of Galactic astrophysical processes. The effectiveness of template fits to remove foreground emission from the WMAP data is also examined. These efforts result in a CMB map with minimal contamination and a demonstration that the WMAP CMB power spectrum is insensitive to residual foreground emission. We use a Maximum Entropy Method to construct a model of the Galactic emission components. The observed total Galactic emission matches the model to less than 1% and the individual model components are accurate to a few percent. We find that the Milky Way resembles other normal spiral galaxies between 408 MHz and 23 GHz, with a synchrotron spectral index that is flattest (beta(sub s) approx. -2.5) near star-forming regions, especially in the plane, and steepest (beta(sub s) approx. -3) in the halo. This is consistent with a picture of relativistic cosmic ray electron generation in star-forming regions and diffusion and convection within the plane. The significant synchrotron index steepening out of the plane suggests a diffusion process in which the halo electrons are trapped in the Galactic potential long enough to suffer synchrotron and inverse Compton energy losses and hence a spectral steepening. The synchrotron index is steeper in the WMAP bands than in lower frequency radio surveys, with a spectral break near 20 GHz to beta(sub s) less than -3. The modeled thermal dust spectral index is also steep in the WMAP bands, with beta(sub d) approx. = 2.2. Our model is driven to these conclusions by the low level of total foreground contamination at approx. 60 GHz. Microwave and Ha measurements of the ionized gas agree well with one another at about the expected levels. Spinning dust emission is limited to less than 5% of the Ka-band foreground emission. A catalog of 208 point sources is presented. The reliability of the catalog is 98%, i.e., we expect five of the 208 sources to be statistically spurious. The mean spectral index of the point sources is alpha approx. 0(beta approx. -2). Derived source counts suggest a contribution to the anisotropy power from unresolved sources of (15.0 +/- 1.4) x 10(exp -3)micro sq K sr at Q-band and negligible levels at V-band and W-band. The Sunyaev-Zeldovich effect is shown to be a negligible "contamination" to the maps.

Black bark as an indicator of bird peck defect in sugar maple

Treesearch

John H. Ohman; K.J., Jr. Kessler

1964-01-01

Portions of the lower bole of occasional sugar maples (Acer saccharum Marsh.) in Lake States northern hardwood stands are sooty black in sharp contrast to the normal gray. The blackened areas may encircle the entire stem or be confined to a narrow band; they have been observed as high as 25 feet but generally extend about 15 feet above the ground....

Second Harmonic Hectometric Radio Emission at Jupiter

NASA Technical Reports Server (NTRS)

Menietti, J. D.; Gurnett, D. A.; Groene, J. B.

1998-01-01

Galileo has been in orbit around Jupiter since December 1995. The plasma wave instrument on board the spacecraft has occasionally detected a rotationally modulated attenuation band in the hectometric (HOM) emission that most likely is due to scattering of the radiation from density fluctuations along the Io L-shell, as reported earlier. The occurrence of the attenuation band is likely to be dependent on Io activity and the presence of density scattering centers along the Io-L-shell as well as the location of the source region. Some of the attenuation bands show clear indications of second harmonic emission. Without polarization measurements, it is difficult to place constraints on the local generation conditions based on the cyclotron maser instability, but the results imply that second harmonic emission could be present in the decametric (DAM) radiation as well. A survey of the data has revealed about 30 examples of second harmonic HOM.

Second Harmonic Hectometric Radio Emission at Jupiter

NASA Technical Reports Server (NTRS)

Menietti, J. D.; Gurnett, D. A.; Groene, J. B.

1998-01-01

Galileo has been in orbit around Jupiter since December 1995. The plasma wave instrument on board the spacecraft has occasionally detected a rotationally modulated attenuation band in the hectometric (HOM) emission that most likely is due to scattering of the radiation from density fluctuations along the Io L-shell, as reported earlier. The occurrence of the attenuation band is likely to be dependent on Io activity and the presence of density scattering centers along the Io L-shell as well as the location of the source region. Some of the attenuation bands show clear indications of second harmonic emission. Without polarization measurements, it is difficult to place constraints on the local generation conditions based on the cyclotron maser instability, but the results imply that second harmonic emission could be present in the decametric (DAM) radiation as well. A survey of the data has revealed about 30 examples of second harmonic HOM.

Luminescence of the (O2(a(1)Δ(g)))2 collisional complex in the temperature range of 90-315 K: Experiment and theory.

PubMed

Zagidullin, M V; Pershin, A A; Azyazov, V N; Mebel, A M

2015-12-28

Experimental and theoretical studies of collision induced emission of singlet oxygen molecules O2(a(1)Δg) in the visible range have been performed. The rate constants, half-widths, and position of peaks for the emission bands of the (O2(a(1)Δg))2 collisional complex centered around 634 nm (2) and 703 nm (3) have been measured in the temperature range of 90-315 K using a flow-tube apparatus that utilized a gas-liquid chemical singlet oxygen generator. The absolute values of the spontaneous emission rate constants k2 and k3 are found to be similar, with the k3/k2 ratio monotonically decreasing from 1.1 at 300 K to 0.96 at 90 K. k2 slowly decreases with decreasing temperature but a sharp increase in its values is measured below 100 K. The experimental results were rationalized in terms of ab initio calculations of the ground and excited potential energy and transition dipole moment surfaces of singlet electronic states of the (O2)2 dimole, which were utilized to compute rate constants k2 and k3 within a statistical model. The best theoretical results reproduced experimental rate constants with the accuracy of under 40% and correctly described the observed temperature dependence. The main contribution to emission process (2), which does not involve vibrational excitation of O2 molecules at the ground electronic level, comes from the spin- and symmetry-allowed 1(1)Ag←(1)B3u transition in the rectangular H configuration of the dimole. Alternatively, emission process (3), in which one of the monomers becomes vibrationally excited in the ground electronic state, is found to be predominantly due to the vibronically allowed 1(1)Ag←2(1)Ag transition induced by the asymmetric O-O stretch vibration in the collisional complex. The strong vibronic coupling between nearly degenerate excited singlet states of the dimole makes the intensities of vibronically and symmetry-allowed transitions comparable and hence the rate constants k2 and k3 close to one another.

C{sub 60} AS A PROBE FOR ASTROPHYSICAL ENVIRONMENTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brieva, A. C.; Jäger, C.; Huisken, F.

2016-08-01

The C{sub 60} molecule has been recently detected in a wide range of astrophysical environments through its four active intramolecular vibrational modes ( T {sub 1u}) near 18.9, 17.4, 8.5, and 7.0 μ m. The strengths of the mid-infrared emission bands have been used to infer astrophysical conditions in the fullerene-rich regions. Widely varying values of the relative intrinsic strengths (RIS) of these four bands are reported in laboratory and theoretical papers, which impedes the derivation of the excitation mechanism of C{sub 60} in the astrophysical sources. The spectroscopic analysis of the C{sub 60} samples produced with our method deliversmore » highly reproducible RIS values of 100, 25 ± 1, 26 ± 1 and 40 ± 4. A comparison of the inferred C{sub 60} emission band strengths with the astrophysical data shows that the observed strengths cannot be explained in terms of fluorescent or thermal emission alone. The large range in the observed 17.4 μ m/18.9 μ m emission ratios indicates that either the emission bands contain significant contributions from emitters other than C{sub 60}, or that the population distribution among the C{sub 60} vibrational modes is affected by physical processes other than thermal or UV excitation, such as chemo-luminescence from nascent C{sub 60} or possibly Poincaré fluorescence resulting from an inverse internal energy conversion. We have carefully analyzed the effect of the weakly active fundamental modes and second order modes in the mid-infrared spectrum of C{sub 60}, and propose that neutral C{sub 60} is the carrier of the unidentified emission band at 6.49 μ m which has been observed in fullerene-rich environments.« less

Hydrogenation of polycyclic aromatic hydrocarbons as a factor affecting the cosmic 6.2 micron emission band

NASA Technical Reports Server (NTRS)

Beegle, L. W.; Wdowiak, T. J.; Harrison, J. G.

2001-01-01

While many of the characteristics of the cosmic unidentified infrared (UIR) emission bands observed for interstellar and circumstellar sources within the Milky Way and other galaxies, can be best attributed to vibrational modes of the variants of the molecular family known as polycyclic aromatic hydrocarbons (PAH), there are open questions that need to be resolved. Among them is the observed strength of the 6.2 micron (1600 cm(-1)) band relative to other strong bands, and the generally low strength for measurements in the laboratory of the 1600 cm(-1) skeletal vibration band of many specific neutral PAH molecules. Also, experiments involving laser excitation of some gas phase neutral PAH species while producing long lifetime state emission in the 3.3 micron (3000 cm(-1)) spectral region, do not result in significant 6.2 micron (1600 cm(-1)) emission. A potentially important variant of the neutral PAH species, namely hydrogenated-PAH (H(N)-PAH) which exhibit intriguing spectral correlation with interstellar and circumstellar infrared emission and the 2175 A extinction feature, may be a factor affecting the strength of 6.2 micron emission. These species are hybrids of aromatic and cycloalkane structures. Laboratory infrared absorption spectroscopy augmented by density function theory (DFT) computations of selected partially hydrogenated-PAH molecules, demonstrates enhanced 6.2 micron (1600 cm(-1)) region skeletal vibration mode strength for these molecules relative to the normal PAH form. This along with other factors such as ionization or the incorporation of nitrogen or oxygen atoms could be a reason for the strength of the cosmic 6.2 micron (1600 cm(-1)) feature.

Band limited emission with central frequency around 2 Hz accompanying powerful cyclones

NASA Technical Reports Server (NTRS)

Troitskaia, V. A.; Shepetnov, K. S.; Dvobnia, B. D.

1992-01-01

It has been found that powerful cyclones are proceeded, accompanied and followed by narrow band electromagnetic emission with central frequency around 2 Hz. It is shown that the signal from this emission is unique and clearly distinguishable from known types of magnetic pulsations, spectra of local thunderstorms, and signals from industrial sources. This emission was first observed during an unusually powerful cyclone with tornadoes in the western European part of the Soviet Union, which passed by the observatory of Borok from south to north-east. The emission has been confirmed by analysis of similar events in Antarctica. The phenomenon described presents a new aspect of interactions of processes in the lower atmosphere and the ionosphere.

Narrow-band tunable terahertz emission from ferrimagnetic Mn{sub 3-x}Ga thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Awari, N.; University of Groningen, 9747 AG Groningen; Kovalev, S., E-mail: s.kovalev@hzdr.de, E-mail: c.fowley@hzdr.de, E-mail: rodek@tcd.ie

2016-07-18

Narrow-band terahertz emission from coherently excited spin precession in metallic ferrimagnetic Mn{sub 3-x}Ga Heusler alloy nanofilms has been observed. The efficiency of the emission, per nanometer film thickness, is comparable or higher than that of classical laser-driven terahertz sources based on optical rectification. The center frequency of the emission from the films can be tuned precisely via the film composition in the range of 0.20–0.35 THz, making this type of metallic film a candidate for efficient on-chip terahertz emitters. Terahertz emission spectroscopy is furthermore shown to be a sensitive probe of magnetic properties of ultra-thin films.

Bridgman-Stockbarger growth of SrI2:Eu2+ single crystal

NASA Astrophysics Data System (ADS)

Raja, A.; Daniel, D. Joseph; Ramasamy, P.; Singh, S. G.; Sen, S.; Gadkari, S. C.

2018-05-01

Strontium Iodide (SrI2): Europium Iodide (EuI2) was purified by Zone-refinement process. Europium doped strontium iodide (SrI2:Eu2+) single crystal was grown by modified vertical Bridgman - Stockbarger technique. Photoluminescence (PL) excitation and emission (PLE) spectra were measured for Eu2+ doped SrI2 crystal. The sharp emission was recorded at 432 nm. Scintillation properties of the SrI2:Eu2+ crystal were checked by the gamma ray spectrometer using 137Cs gamma source.

Thermal evaporation and condensation synthesis of metallic Zn layered polyhedral microparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khan, Waheed S.; Cao, Chuanbao, E-mail: cbcao@bit.edu.cn; Usman, Zahid

2011-12-15

Highlights: Black-Right-Pointing-Pointer Zn polyhedral microparticles prepared by thermal evaporation and condensation route. Black-Right-Pointing-Pointer Vapour-solid process based growth model governs the formation of Zn microparticles. Black-Right-Pointing-Pointer A strong PL emission band is observed at 369 nm in UV region. Black-Right-Pointing-Pointer Radiative recombination of electrons in the s, p conduction band and the holes in the d bands causes this emission. -- Abstract: Metallic zinc layered polyhedral microparticles have been fabricated by thermal evaporation and condensation technique using zinc as precursor at 750 Degree-Sign C for 120 min and NH{sub 3} as a carrier gas. The zinc polyhedral microparticles with oblate sphericalmore » shape are observed to be 2-9 {mu}m in diameter along major axes and 1-7 {mu}m in thickness along minor axes. The structural, compositional and morphological characterizations were performed by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED). A vapour-solid (VS) mechanism based growth model has been proposed for the formation of Zn microparticles. Room temperature photoluminescence (PL) emission spectrum of the product exhibited a strong emission band at 369 nm attributed to the radiative recombination of electrons in the s, p conduction band near Fermi surface and the holes in the d bands generated by the optical excitation.« less

First detection of Mars atmospheric hydroxyl: CRISM Near-IR measurement versus LMD GCM simulation of OH Meinel band emission in the Mars polar winter atmosphere

NASA Astrophysics Data System (ADS)

Todd Clancy, R.; Sandor, Brad J.; García-Muñoz, Antonio; Lefèvre, Franck; Smith, Michael D.; Wolff, Michael J.; Montmessin, Franck; Murchie, Scott L.; Nair, Hari

2013-09-01

Visible and near-IR Meinel band emissions originate from excited OH in the terrestrial upper atmosphere (Meinel, I.A.B. [1950]. Astrophys. J. 111, 555. http://dx.doi.org/10.1086/145296), and have recently been detected in the Venus nightside upper mesosphere (Piccioni, G. et al. [2008]. Astron. Astrophys. 483, L29-L33. http://dx.doi.org/10.1051/0004-6361:200809761). Meinel band observations support key studies of transport and photochemistry in both of these atmospheres. In the case of Mars, OH regulates the basic stability of the CO2 atmosphere to photolytic decomposition (to CO and O2, e.g. Parkinson, T.D., Hunten, D.M. [1972]. J. Atmos. Sci. 29, 1380-1390. http://dx.doi.org/10.1175/1520-0469(1972)029<1380:SAAOOO>2.0.CO;2), and yet has never been measured. We present the first detection of Mars atmospheric OH, associated with CRISM near-IR spectral limb observations of polar night Meinel band emissions centered at 1.45 and 2.9 μm. Meinel band (1-0), (2-1), and (2-0) average limb intensities of 990 ± 280, 1060 ± 480, and 200 ± 100 kiloRayleighs (kR), respectively, are determined for 70-90 NS polar winter latitudes over altitudes of 40-56 km. Additional OH bands, such as (3-2), (3-1), and (4-2), present ⩽1σ measurements. Uncertainty in the (4-2) band emission rate contributes to increased uncertainty in the determination of the O2(1Δg) (0-0)/(0-1) band emission ratio A00/A01=47-12+26. An average profile retrieval for Mars OH polar nightglow indicates 45-55 km altitude levels for volume emission rates (VER) of 0.4 (2-0) to 2 (1-0, 2-1) × 104 photons/(cm3 s). Similar to polar night O2(1Δg) emission (e.g. Clancy, R.T. et al. [2012]. J. Geophys. Res. (Planets) 117, E00J10. http://dx.doi.org/10.1029/2011JE004018), Meinel OH band emission is supported by upper level, winter poleward transport of O and H in the deep Hadley solsticial circulations of Mars. The retrieved OH emission rates are compared to polar winter OH nightglow simulated by the LMD (Laboratoire de Météorologie Dynamique) photochemical GCM (global climate model), employing detailed photochemistry (e.g. Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F. [2004]. J. Geophys. Res. (Planets) 109, E07004. http://dx.doi.org/10.1029/2004JE002268) and energy transfer processes (excitation and quenching) developed for Mars Meinel OH band nightglow by García Muñoz et al. (García Muñoz, A., McConnell, J.C., McDade, I.C., Melo, S.M.L. [2005]. Icarus 176, 75-95). Modeled versus observed OH emission behavior agrees within measurement uncertainties with the assumptions of a Bates-Nicolet (H + O3) source for excited OH production, and ‘collisional-cascade’ quenching of the OH vibrational population by CO2. ‘Sudden-death’ quenching of excited OH by CO2 leads to 100× less OH emission than observed. The combined agreement between LMD GCM simulated and CRISM observed O2(1Δg) and Meinel OH polar nightglow behaviors represents a significant demonstration of the LMD model capability to couple odd oxygen and hydrogen photochemistry and transport by the Mars global circulation in a realistic fashion.

Direct and Indirect Electron Emission from the Green Fluorescent Protein Chromophore

NASA Astrophysics Data System (ADS)

Toker, Y.; Rahbek, D. B.; Klærke, B.; Bochenkova, A. V.; Andersen, L. H.

2012-09-01

Photoelectron spectra of the deprotonated green fluorescent protein chromophore have been measured in the gas phase at several wavelengths within and beyond the S0-S1 photoabsorption band of the molecule. The vertical detachment energy (VDE) was determined to be 2.68±0.1eV. The data show that the first electronically excited state is bound in the Franck-Condon region, and that electron emission proceeds through an indirect (resonant) electron-emission channel within the corresponding absorption band.

Ultraviolet electroluminescence from zinc oxide nanorods/deoxyribonucleic acid hybrid bio light-emitting diode

NASA Astrophysics Data System (ADS)

Gupta, Rohini Bhardwaj; Nagpal, Swati; Arora, Swati; Bhatnagar, Pramod Kumar; Mathur, Parmatma Chandra

2011-01-01

Ultraviolet (UV) light-emitting diode using salmon deoxyribonucleic acid (sDNA)-cetyltrimethylammonium complex as an electron blocking layer and zinc oxide (ZnO) nanorods as emissive material was fabricated. UV emission, which was blue shifted up to 335 nm with respect to the band edge emission of 390 nm, was observed. This blue shift was caused due to accumulation of electrons in the conduction band of ZnO because of a high potential barrier existing at the sDNA/ZnO interface.

Raman spectroscopic study of a hydroxy-arsenate mineral containing bismuth-atelestite Bi 2O(OH)(AsO 4)

NASA Astrophysics Data System (ADS)

Frost, Ray L.; Čejka, Jiří; Sejkora, Jiří; Plášil, Jakub; Reddy, B. J.; Keeffe, Eloise C.

2011-01-01

The Raman spectrum of atelestite Bi 2O(OH)(AsO 4), a hydroxy-arsenate mineral containing bismuth, has been studied in terms of spectra-structure relations. The studied spectrum is compared with the Raman spectrum of atelestite downloaded from the RRUFF database. The sharp intense band at 834 cm -1 is assigned to the ν1 AsO 43- ( A1) symmetric stretching mode and the three bands at 767, 782 and 802 cm -1 to the ν3 AsO 43- antisymmetric stretching modes. The bands at 310, 324, 353, 370, 395, 450, 480 and 623 cm -1 are assigned to the corresponding ν4 and ν2 bending modes and Bi sbnd O sbnd Bi (vibration of bridging oxygen) and Bi sbnd O (vibration of non-bridging oxygen) stretching vibrations. Lattice modes are observed at 172, 199 and 218 cm -1. A broad low intensity band at 3095 cm -1 is attributed to the hydrogen bonded OH units in the atelestite structure. A weak band at 1082 cm -1 is assigned to δ(Bi sbnd OH) vibration.

Polarization and angle insensitive dual-band bandpass frequency selective surface using all-dielectric metamaterials

NASA Astrophysics Data System (ADS)

Yu, Fei; Wang, Jun; Wang, Jiafu; Ma, Hua; Du, Hongliang; Xu, Zhuo; Qu, Shaobo

2016-04-01

In this paper, we demonstrate a dual-band bandpass all-dielectric frequency selective surface (FSS), the building elements of which are high-permittivity ceramic particles rather than metallic patterns. With proper structural design and parameter adjustment, the resonant frequency can be tuned at will. Dual-band bandpass response can be realized due to the coupling between electric and magnetic resonances. As an example, a dual-band bandpass FSS is designed in Ku band, which is composed of two-dimensional periodic arrays of complementary quatrefoil structures (CQS) cut from dielectric plates. Moreover, cylindrical dielectric resonators are introduced and placed in the center of each CQS to broaden the bandwidth and to sharpen the cut-off frequency. Theoretical analysis shows that the bandpass response arises from impedance matching caused by electric and magnetic resonances. In addition, effective electromagnetic parameters and dynamic field distributions are presented to explain the mechanism of impedance matching. The proposed FSS has the merits of polarization independence, stable transmission, and sharp roll-off frequency. The method can also be used to design all-dielectric FSSs with continuum structures at other frequencies.

Conduction-band valley spin splitting in single-layer H-T l2O

NASA Astrophysics Data System (ADS)

Ma, Yandong; Kou, Liangzhi; Du, Aijun; Huang, Baibiao; Dai, Ying; Heine, Thomas

2018-02-01

Despite numerous studies, coupled spin and valley physics is currently limited to two-dimensional (2D) transition-metal dichalcogenides (TMDCs). Here, we predict an exceptional 2D valleytronic material associated with the spin-valley coupling phenomena beyond 2D TMDCs—single-layer (SL) H-T l2O . It displays large valley spin splitting (VSS), significantly larger than that of 2D TMDCs, and a finite band gap, which are both critically attractive for the integration of valleytronics and spintronics. More importantly, in sharp contrast to all the experimentally confirmed 2D valleytronic materials, where the strong valence-band VSS (0.15-0.46 eV) supports the spin-valley coupling, the VSS in SL H-T l2O is pronounced in its conduction band (0.61 eV), but negligibly small in its valence band (21 meV), thus opening a way for manipulating the coupled spin and valley physics. Moreover, SL H-T l2O possesses extremely high carrier mobility, as large as 9.8 ×103c m2V-1s-1 .

DOE Office of Scientific and Technical Information (OSTI.GOV)

Emin, David, E-mail: emin@unm.edu

Charge carriers that execute multi-phonon hopping generally interact strongly enough with phonons to form polarons. A polaron's sluggish motion is linked to slowly shifting atomic displacements that severely reduce the intrinsic width of its transport band. Here a means to estimate hopping polarons' bandwidths from Seebeck-coefficient measurements is described. The magnitudes of semiconductors' Seebeck coefficients are usually quite large (>k/|q| = 86 μV/K) near room temperature. However, in accord with the third law of thermodynamics, Seebeck coefficients must vanish at absolute zero. Here, the transition of the Seebeck coefficient of hopping polarons to its low-temperature regime is investigated. The temperature and sharpness ofmore » this transition depend on the concentration of carriers and on the width of their transport band. This feature provides a means of estimating the width of a polaron's transport band. Since the intrinsic broadening of polaron bands is very small, less than the characteristic phonon energy, the net widths of polaron transport bands in disordered semiconductors approach the energetic disorder experienced by their hopping carriers, their disorder energy.« less

Probing topological Fermi-Arcs and bulk boundary correspondence in the Weyl semimetal TaAs

NASA Astrophysics Data System (ADS)

Batabyal, Rajib; Morali, Noam; Avraham, Nurit; Sun, Yan; Schmidt, Marcus; Felser, Claudia; Stern, Ady; Yan, Binghai; Beidenkopf, Haim

The relation between surface Fermi-arcs and bulk Weyl cones in a Weyl semimetal, uniquely allows to study the notion of bulk to surface correspondence. We visualize these topological Fermi arc states on the surface of the Weyl semi-metal tantalum arsenide using scanning tunneling spectroscopy. Its surface hosts 12 Fermi arcs amongst several other surface bands of non-topological origin. We detect the possible scattering processes of surface bands in which Fermi arcs are involved including intra- and inter arc scatterings and arc-trivial scatterings. Each of the measured scattering processes entails additional information on the unique nature of Fermi arcs in tantalum arsenide: their contour, their energy-momentum dispersion and its relation with the bulk Weyl nodes. We further identify a sharp distinction between the wave function's spatial distribution of topological versus trivial bands. The non-topological surface bands, which are derived from the arsenic dangling bonds, are tightly bound to the arsenic termination layer. In contrast, the Fermi-arc bands reside on the deeper tantalum layer, penetrating into the bulk, which is predominantly derived from tantalum orbitals.

Photoexcited emission efficiencies of zinc oxide

NASA Astrophysics Data System (ADS)

Foreman, John Vincent

Optoelectronic properties of the II-VI semiconductor zinc oxide (ZnO) have been studied scientifically for almost 60 years; however, many fundamental questions remain unanswered about its two primary emission bands--the exciton-related luminescence in the ultraviolet and the defect-related emission band centered in the green portion of the visible spectrum. The work in this dissertation was motivated by the surprising optical properties of a ZnO nanowire sample grown by the group of Prof. Jie Liu, Department of Chemistry, Duke University. We found that this nanowire sample exhibited defect-related green/white emission of unprecedented intensity relative to near-band-edge luminescence. The experimental work comprising this dissertation was designed to explain the optical properties of this ZnO nanowire sample. Understanding the physics underlying such exceptional intensity of green emission addresses many of the open questions of ZnO research and assesses the possibility of using ZnO nanostructures as an ultraviolet-excited, broadband visible phosphor. The goal of this dissertation is to provide insight into what factors influence the radiative and nonradiative recombination efficiencies of ZnO by characterizing simultaneously the optical properties of the near-band-edge ultraviolet and the defect-related green emission bands. Specifically, we seek to understand the mechanisms of ultraviolet and green emission, the mechanism of energy transfer between them, and the evolution of their emission efficiencies with parameters such as excitation density and sample temperature. These fundamental but unanswered questions of ZnO emission are addressed here by using a novel combination of ultrafast spectroscopic techniques in conjunction with a systematic set of ZnO samples. Through this systematic investigation, ZnO may be realistically assessed as a potential green/white light phosphor. Photoluminescence techniques are used to characterize the thermal quenching behavior of both emission bands in micrometer-scale ZnO powders. Green luminescence quenching is described by activation energies associated with bound excitons. We find that green luminescence efficiency is maximized when excitons are localized in the vicinity of green-emitting defects. Subsequent photoluminescence excitation measurements performed at multiple temperatures independently verified that green band photoluminescence intensity directly correlates with the photogenerated exciton population. The spatial distributions of green-emitting defects and nonradiative traps are elucidated by an innovative combination of quantum efficiency and time-integrated/resolved photoluminescence measurements. By combining these techniques for the first time, we take advantage of the drastically different absorption coefficients for one- and two-photon excitations to provide details about the types and concentrations of surface and bulk defects and to demonstrate the non-negligible effects of reabsorption. A comparison of results for unannealed and annealed ZnO powders indicates that the annealing process creates a high density of green-emitting defects near the surface of the sample while simultaneously reducing the density of bulk nonradiative traps. These experimental results are discussed in the context of a simple rate equation model that accounts for the quantum efficiencies of both emission bands. For both femtosecond pulsed and continuous-wave excitations, the green band efficiency is found to decrease with increasing excitation density--from 35% to 5% for pulsed excitation spanning 1-1000 muJ/cm--2, and from 60% to 5% for continuous excitation in the range 0.01-10 W/cm --2. On the other hand, near-band-edge emission efficiency increases from 0.4% to 25% for increasing pulsed excitation density and from 0.1% to 0.6% for continuous excitation. It is shown experimentally that these changes in efficiency correspond to a reduction in exciton formation efficiency. The differences in efficiencies for pulsed versus continuous-wave excitation are described by changes in the relative rates of exciton luminescence and exciton capture at green defects based on an extended rate equation model that accounts for the excitation density dependence of both luminescence bands. In using a systematic set of ZnO samples and a novel combination of optical techniques to characterize them, this body of work presents a comprehensive and detailed physical picture of recombination mechanisms in ZnO. The insight provided by these results has immediate implications for material growth/processing techniques and should help material growers control the relative efficiencies of ultraviolet, green/visible, and nonradiative recombination channels in ZnO.

Estimating lithospheric properties at Atla Regio, Venus

NASA Technical Reports Server (NTRS)

Phillips, Roger J.

1994-01-01

Magellan spehrical harmonic gravity and topography models are used to estimate lithospheric properties at Alta Regio, Venus, a proposed hotspot with dynamic support from mantle plume(s). Global spherical harmonic and local representations of the gravity field share common properties in the Atla region interms of their spectral behavior over a wavelength band from approximately 2100 to approximately 700 km. The estimated free-air admittance spectrum displays a rather featureless long-wavelength portion followed by a sharp rise at wavelengths shorter than about 1000 km. This sharp rise requires significant flexural support of short-wavelength structures. The Bouguer coherence also displays a sharp drop in this wavelength band, indicating a finite flexural rigidity of the lithosphere. A simple model for lithospheric loading from above and below is introduced (D. W. Forsyth, 1985) with four parameters: f, the ratio of bottom loading to top loading; z(sub m), crustal thickness; z(sub l) depth to bottom loading source; and T(sub e) elastic lithosphere thickness. A dual-mode compensation model is introduced in which the shorter wavelengths (lambda approximately less than 1000 km) might be explained best by a predominance of top loading by the large shield volcanoes Maat Mons, Ozza Mons, and Sapas Mons, and the longer wavelengths (lambda approximately greater than 1500 km) might be explained best by a deep depth of compensation, possibly representing bottom loading by a dynamic source. A Monte Carlo inversion technique is introduced to thoroughly search out the four-space of the model parameters and to examine parameter correlation in the solutions. Venus either is a considerabe deficient in heat sources relative to Earth, or the thermal lithosphere is overthickened in response to an earlier episode of significant heat loss from the planet.

Integrated Advanced Microwave Sounding Unit-A (AMSU-A). Engineering Test Report: Radiated Emissions and SARR, SARP, DCS Receivers, Link Frequencies EMI Sensitive Band Test Results, AMSU-A1, S/N 109

NASA Technical Reports Server (NTRS)

Valdez, A.

2000-01-01

This is the Engineering Test Report, Radiated Emissions and SARR, SARP, DCS Receivers, Link Frequencies EMI Sensitive Band Test Results, AMSU-A1, S/N 109, for the Integrated Advanced Microwave Sounding Unit-A (AMSU-A).

Acoustic Emission during Intermittent Creep in an Aluminum-Magnesium Alloy

NASA Astrophysics Data System (ADS)

Shibkov, A. A.; Zheltov, M. A.; Gasanov, M. F.; Zolotov, A. E.

2018-01-01

The use of high-speed methods to measure deformation, load, and the dynamics of deformation bands, as well as the correlation between the intermittent creep characteristics of the AlMg6 aluminum-magnesium alloy and the parameters of the acoustic emission signals, has been studied experimentally. It has been established that the emergence and rapid expansion of the primary deformation band, which generates a characteristic acoustic emission signal in the frequency range of 10-1000 Hz, is a trigger for the development of a deformation step in the creep curve. The results confirm the accuracy of the mechanism of generating an acoustic signal associated with the emergence of a dislocation band on the external surface of the specimen.

Bias-polarity-dependent UV/visible transferable electroluminescence from ZnO nanorod array LED with graphene oxide electrode supporting layer

NASA Astrophysics Data System (ADS)

Liu, Weizhen; Wang, Wei; Xu, Haiyang; Li, Xinghua; Yang, Liu; Ma, Jiangang; Liu, Yichun

2015-09-01

A simple top electrode preparation process, employing continuous graphene oxide films as electrode supporting layers, was adopted to fabricate a ZnO nanorod array/p-GaN heterojunction LED. The achieved LED demonstrated different electroluminescence behaviors under forward and reverse biases: a yellow-red emission band was observed under forward bias, whereas a blue-UV emission peak was obtained under reverse bias. Electroluminescence spectra under different currents and temperatures, as well as heterojunction energy-band alignments, reveal that the yellow-red emission under forward bias originates from recombinations related to heterointerface defects, whereas the blue-UV electroluminescence under reverse bias is ascribed to transitions from near-band-edge and Mg-acceptor levels in p-GaN.

Broad emission band of Yb3+ in the nonlinear Nb:RbTiOPO4 crystal: origin and applications.

PubMed

Carvajal, J J; Ciatto, G; Mateos, X; Schmidt, A; Griebner, U; Petrov, V; Boulon, G; Brenier, A; Peña, A; Pujol, M C; Aguiló, M; Díaz, F

2010-03-29

By means of micro-structural and optical characterization of the Yb:Nb:RbTiOPO(4) crystal, we demonstrated that the broad emission band of Yb(3+) in these crystals is due to the large splitting of the ytterbium ground state only, and not to a complex multisite occupation by the ytterbium ions in the crystals. We used this broad emission band to demonstrate wide laser tuning range and generation of femtosecond laser pulses. Passive mode-locked laser operation has been realized by using a semiconductor saturable absorber mirror, generating ultra short laser pulses of 155 fs, which were very stable in time, under Ti:sapphire laser pumping at 1053 nm.

An infrared and Raman spectroscopic study of natural zinc phosphates.

PubMed

Frost, Ray L

2004-06-01

Zinc phosphates are important in the study of the phosphatisation of metals. Raman spectroscopy in combination with infrared spectroscopy has been used to characterise the zinc phosphate minerals. The minerals may be characterised by the patterns of the hydroxyl stretching vibrations in both the Raman and infrared spectra. Spencerite is characterised by a sharp Raman band at 3516 cm(-1) and tarbuttite by a single band at 3446 cm(-1). The patterns of the Raman spectra of the hydroxyl stretching region of hopeite and parahopeite are different in line with their differing crystal structures. The Raman spectrum of the PO4 stretching region shows better band separated peaks than the infrared spectra which consist of a complex set of overlapping bands. The position of the PO4 symmetric stretching mode can be used to identify the zinc phosphate mineral. It is apparent that Raman spectroscopy lends itself to the fundamental study of the evolution of zinc phosphate films.

Fast Purcell-enhanced single photon source in 1,550-nm telecom band from a resonant quantum dot-cavity coupling

PubMed Central

Birowosuto, Muhammad Danang; Sumikura, Hisashi; Matsuo, Shinji; Taniyama, Hideaki; van Veldhoven, Peter J.; Nötzel, Richard; Notomi, Masaya

2012-01-01

High-bit-rate nanocavity-based single photon sources in the 1,550-nm telecom band are challenges facing the development of fibre-based long-haul quantum communication networks. Here we report a very fast single photon source in the 1,550-nm telecom band, which is achieved by a large Purcell enhancement that results from the coupling of a single InAs quantum dot and an InP photonic crystal nanocavity. At a resonance, the spontaneous emission rate was enhanced by a factor of 5 resulting a record fast emission lifetime of 0.2 ns at 1,550 nm. We also demonstrate that this emission exhibits an enhanced anti-bunching dip. This is the first realization of nanocavity-enhanced single photon emitters in the 1,550-nm telecom band. This coupled quantum dot cavity system in the telecom band thus provides a bright high-bit-rate non-classical single photon source that offers appealing novel opportunities for the development of a long-haul quantum telecommunication system via optical fibres. PMID:22432053

Fast Purcell-enhanced single photon source in 1,550-nm telecom band from a resonant quantum dot-cavity coupling.

PubMed

Birowosuto, Muhammad Danang; Sumikura, Hisashi; Matsuo, Shinji; Taniyama, Hideaki; van Veldhoven, Peter J; Nötzel, Richard; Notomi, Masaya

2012-01-01

High-bit-rate nanocavity-based single photon sources in the 1,550-nm telecom band are challenges facing the development of fibre-based long-haul quantum communication networks. Here we report a very fast single photon source in the 1,550-nm telecom band, which is achieved by a large Purcell enhancement that results from the coupling of a single InAs quantum dot and an InP photonic crystal nanocavity. At a resonance, the spontaneous emission rate was enhanced by a factor of 5 resulting a record fast emission lifetime of 0.2 ns at 1,550 nm. We also demonstrate that this emission exhibits an enhanced anti-bunching dip. This is the first realization of nanocavity-enhanced single photon emitters in the 1,550-nm telecom band. This coupled quantum dot cavity system in the telecom band thus provides a bright high-bit-rate non-classical single photon source that offers appealing novel opportunities for the development of a long-haul quantum telecommunication system via optical fibres.

Fabrication of ceramic layer-by-layer infrared wavelength photonic band gap crystals

NASA Astrophysics Data System (ADS)

Kang, Henry Hao-Chuan

Photonic band gap (PBG) crystals, also known as photonic crystals, are periodic dielectric structures which form a photonic band gap that prohibit the propagation of electromagnetic (EM) waves of certain frequencies at any incident angles. Photonic crystals have several potential applications including zero-threshold semiconductor lasers, the inhibiting spontaneous emission, dielectric mirrors, and wavelength filters. If defect states are introduced in the crystals, light can be guided from one location to another or even a sharp bending of light in submicron scale can be achieved. This generates the potential for optical waveguide and optical circuits, which will contribute to the improvement in the fiber-optic communications and the development of high-speed computers. The goal of this dissertation research is to explore techniques for fabricating 3D ceramic layer-by-layer (LBL) photonic crystals operating in the infrared frequency range, and to characterize the infilling materials properties that affect the fabrication process as well as the structural and optical properties of the crystals. While various approaches have been reported in literature for the fabrication of LBL structure, the uniqueness of this work ties with its cost-efficiency and relatively short process span. Besides, very few works have been reported on fabricating ceramic LBL crystals at mid-IR frequency range so far. The fabrication techniques reported here are mainly based on the concepts of microtransfer molding with the use of polydimethyl siloxane (PDMS) as molds/stamps. The infilling materials studied include titanium alkoxide precursors and aqueous suspensions of nanosize titania particles (slurries). Various infilling materials were synthesized to determine viscosities, effects on drying and firing shrinkages, effects on film surface roughness, and their moldability. Crystallization and phase transformation of the materials were also monitored using DTA, TGA and XRD. Mutilayer crystal structures of 2.5 and 1.0 mum periodicity have been successfully built. The structures of the fabricated crystals are inspected with scanning electron microscopy (SEM) and the optical characteristics are examined with optical microscopy and FtIR spectroscopy.

Effects of thermal annealing on the structural and optical properties of carbon-implanted SiO2.

PubMed

Poudel, P R; Paramo, J A; Poudel, P P; Diercks, D R; Strzhemechny, Y M; Rout, B; McDaniel, F D

2012-03-01

Amorphous carbon (a-C) nanoclusters were synthesized by the implantation of carbon ions (C-) into thermally grown silicon dioxide film (-500 nm thick) on a Si (100) wafer and processed by high temperature thermal annealing. The carbon ions were implanted with an energy of 70 keV at a fluence of 5 x 10(17) atoms/cm2. The implanted samples were annealed at 1100 degrees C for different time periods in a gas mixture of 96% Ar+4% H2. Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and High Resolution Transmission Electron Microscopy (HRTEM) were used to study the structural properties of both the as-implanted and annealed samples. HRTEM reveals the formation of nanostructures in the annealed samples. The Raman spectroscopy also confirms the formation of carbon nano-clusters in the samples annealed for 10 min, 30 min, 60 min and 90 min. No Raman features originating from the carbon-clusters are observed for the sample annealed further to 120 min, indicating a complete loss of implanted carbon from the SiO2 layer. The loss of the implanted carbon in the 120 min annealed sample from the SiO2 layer was also observed in the XPS depth profile measurements. Room temperature photoluminescence (PL) spectroscopy revealed visible emissions from the samples pointing to carbon ion induced defects as the origin of a broad 2.0-2.4 eV band, and the intrinsic defects in SiO2 as the possible origin of the -2.9 eV bands. In low temperature photoluminescence spectra, two sharp and intense photoluminescence lines at -3.31 eV and -3.34 eV appear for the samples annealed for 90 min and 120 min, whereas no such bands are observed in the samples annealed for 10 min, 30 min, and 60 min. The Si nano-clusters forming at the Si-SiO2 interface could be the origin of these intense peaks.

Adaptive Optics Near-Infrared Imaging of R136 in 30 Doradus: The Stellar Population of a Nearby Starburst

NASA Astrophysics Data System (ADS)

Brandl, B.; Sams, B. J.; Bertoldi, F.; Eckart, A.; Genzel, R.; Drapatz, S.; Hofmann, R.; Loewe, M.; Quirrenbach, A.

1996-07-01

We report 0".15 resolution near-infrared (NIR) imaging of R136, the central region of 30 Doradus in the large Magellanic Cloud. Our 12".8 x 12".8 images were recorded with the MPE camera SHARP II at the 3.6 m ESO telescope, using the adaptive optics system COME ON+. The high spatial resolution and sensitivity (20th magnitude in K) of our observations allow our H- and K-band images to be compared and combined with recent Hubble Space Telescope (HST) WFPC2 data of R136. We fit theoretical models with variable foreground extinction to the observed magnitudes of ˜1000 stars (roughly half of which were detected in HST and NIR bands) and derive the stellar population in this starburst region. We find no red giants or supergiants; however, we detect ˜110 extremely red sources which are probably young, pre-main-sequence low- or intermediate-mass stars. We obtained narrow-band images to identify known and new Wolf-Rayet stars by their He 11(2.189 μm) and Bry (2.166 μm) emission lines. The presence of W-R stars and absence of red supergiants narrow the cluster age to ˜3-5 Myr, while the derived ratio of W-R to 0 stars of 0.05 in the central region favors an age of 3.5 Myr, with a relatively short starburst duration. For the 0 stars, the core radius is found to be 0.1 pc and appears to decrease with increasing stellar mass. The slope of the mass function function is Γ = -1.6 on average, but it steepens with increasing distance from the cluster center from Γ = -1.3 in the inner 0.4 pc to Γ = -2.2 outside 0.8 pc for stars more massive than 12 Msun. The radial variation of the mass function reveals strong mass segregation that is probably due to the cluster's dynamical evolution.

Characterization of PVT Grown ZnSe by Low Temperature Photoluminescence

NASA Technical Reports Server (NTRS)

Wang, Ling Jun

1998-01-01

ZnSe, a II-VI semiconductor with a large direct band gap of 2.7 eV at room temperature and 2.82 eV at 10 K, is considered a promising material for optoelectric applications in the blue-green region of the spectrum. Photoemitting devices and diode laser action has been demonstrated as a result of decades of research. A key issue in the development of II-VI semiconductors is the control of the concentration of the various impurities. The II-VI semiconductors seem to defy the effort of high level doping due to the well known self compensation of the donors and the acceptors. A good understanding of roles of the impurities and the behavior of the various intrinsic defects such as vacancies, interstitials and their complexes with impurities is necessary in the development and application of these materials. Persistent impurities such as Li and Cu have long played a central role in the photoelectronic properties of many II-VI compounds, particularly ZnSe. The shallow centers which may promote useful electrical conductivity are of particular interest. They contribute the richly structured near gap edge luminescence, containing weak to moderate phonon coupling and therefore very accessible information about the energy states of the different centers. Significance of those residual impurities which may contribute such centers in II-VI semiconductors must be fully appreciated before improved control of their electrical properties may be possible. Low temperature photoluminescence spectroscopy is an important source of information and a useful tool of characterization of II-VI semiconductors such as ZnSe. The low temperature photoluminescence spectrum of a ZnSe single crystal typically consists of a broad band emission peaking at 2.34 eV, known as the Cu-green band, and some very sharp lines near the band gap. These bands and lines are used to identify the impurity ingredients and the defects. The assessment of the quality of the crystal based on the photoluminescence analysis is then possible. In this report we present the characterization of a ZnSe single crystal as grown by the physical vapor transport method, with special intention paid to the possible effects of the gravitational field to the growth of the crystal.

New Kronig-Penney Equation Emphasizing the Band Edge Conditions

ERIC Educational Resources Information Center

Szmulowicz, Frank

2008-01-01

The Kronig-Penney problem is a textbook example for discussing band dispersions and band gap formation in periodic layered media. For example, in photonic crystals, the behaviour of bands next to the band edges is important for further discussions of such effects as inhibited light emission, slow light and negative index of refraction. However,…

Exploring Moho sharpness in Northeastern North China Craton with frequency-dependence analysis of Ps receiver function

NASA Astrophysics Data System (ADS)

Zhang, P.; Yao, H.; Chen, L.; WANG, X.; Fang, L.

2017-12-01

The North China Craton (NCC), one of the oldest cratons in the world, has attracted wide attention in Earth Science for decades because of the unusual Mesozoic destruction of its cratonic lithosphere. Understanding the deep processes and mechanism of this craton destruction demands detailed knowledge about the deep structure of this region. In this study, we calculate P-wave receiver functions (RFs) with two-year teleseismic records from the North China Seismic Array ( 200 stations) deployed in the northeastern NCC. We observe both diffused and concentered PpPs signals from the Moho in RF waveforms, which indicates heterogeneous Moho sharpness variations in the study region. Synthetic Ps phases generated from broad positive velocity gradients at the depth of the Moho (referred as Pms) show a clear frequency dependence nature, which in turn is required to constrain the sharpness of the velocity gradient. Practically, characterizing such a frequency dependence feature in real data is challenging, because of low signal-to-noise ratio, contaminations by multiples generated from shallow structure, distorted signal stacking especially in double-peak Pms signals, etc. We attempt to address these issues by, firstly, utilizing a high-resolution Moho depth model of this region to predict theoretical delay times of Pms that facilitate more accurate Pms identifications. The Moho depth model is derived by wave-equation based poststack depth migration on both Ps phase and surface-reflected multiples in RFs in our previous study (Zhang et al., submitted to JGR). Second, we select data from a major back azimuth range of 100° - 220° that includes 70% teleseismic events due to the uneven data coverage and to avoid azimuthal influence as well. Finally, we apply an adaptive cross-correlation stacking of Pms signals in RFs for each station within different frequency bands. High-quality Pms signals at different frequencies will be selected after careful visual inspection and adaptive cross-correlation stacking. At last, we will model the stacked Pms signals within different frequency bands to obtain the final sharpness of crust-mantle boundary, which may shed new lights on understanding the mechanism of cratonic reactivation and destruction in the NCC.

Shallow Carrier Trap Levels in GaAsN Investigated by Photoluminescence

NASA Astrophysics Data System (ADS)

Inagaki, Makoto; Suzuki, Hidetoshi; Suzuki, Akio; Mutaguchi, Kazumasa; Fukuyama, Atsuhiko; Kojima, Nobuaki; Ohshita, Yoshio; Yamagichi, Masafumi

2011-04-01

Shallow carrier trap levels in GaAs1-xNx (0.0010≤x≤0.0038) were investigated by photoluminescence (PL) and photoreflectance (PR) ranging from 4.2 to 300 K. The band gap energies of the GaAsN were clearly determined in the whole temperature range by the PR fitting analysis. It is clarified by peak decomposing that there were three emission peaks in the near-band-edge PL spectra of GaAsN. One of them was originated from band-to-band transition. The energies of two emission peaks were located at approximately 6 and 17 meV below the band edge. The existence of these peaks is evidence of carrier localization at the near-band-edge. The intensity ratio of the peak at the low energy side to other peaks increases with increasing N composition. This behavior is similar to the degradation of electrical properties.

Assessing the impacts of ethanol and isobutanol on gaseous and particulate emissions from flexible fuel vehicles.

PubMed

Karavalakis, Georgios; Short, Daniel; Russell, Robert L; Jung, Heejung; Johnson, Kent C; Asa-Awuku, Akua; Durbin, Thomas D

2014-12-02

This study investigated the effects of higher ethanol blends and an isobutanol blend on the criteria emissions, fuel economy, gaseous toxic pollutants, and particulate emissions from two flexible-fuel vehicles equipped with spark ignition engines, with one wall-guided direct injection and one port fuel injection configuration. Both vehicles were tested over triplicate Federal Test Procedure (FTP) and Unified Cycles (UC) using a chassis dynamometer. Emissions of nonmethane hydrocarbons (NMHC) and carbon monoxide (CO) showed some statistically significant reductions with higher alcohol fuels, while total hydrocarbons (THC) and nitrogen oxides (NOx) did not show strong fuel effects. Acetaldehyde emissions exhibited sharp increases with higher ethanol blends for both vehicles, whereas butyraldehyde emissions showed higher emissions for the butanol blend relative to the ethanol blends at a statistically significant level. Particulate matter (PM) mass, number, and soot mass emissions showed strong reductions with increasing alcohol content in gasoline. Particulate emissions were found to be clearly influenced by certain fuel parameters including oxygen content, hydrogen content, and aromatics content.

Breakdown voltage reduction by field emission in multi-walled carbon nanotubes based ionization gas sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saheed, M. Shuaib M.; Muti Mohamed, Norani; Arif Burhanudin, Zainal, E-mail: zainabh@petronas.com.my

2014-03-24

Ionization gas sensors using vertically aligned multi-wall carbon nanotubes (MWCNT) are demonstrated. The sharp tips of the nanotubes generate large non-uniform electric fields at relatively low applied voltage. The enhancement of the electric field results in field emission of electrons that dominates the breakdown mechanism in gas sensor with gap spacing below 14 μm. More than 90% reduction in breakdown voltage is observed for sensors with MWCNT and 7 μm gap spacing. Transition of breakdown mechanism, dominated by avalanche electrons to field emission electrons, as decreasing gap spacing is also observed and discussed.

Plasmon-mediated Enhancement of Rhodamine 6G Spontaneous Emission on Laser-spalled Nanotextures

NASA Astrophysics Data System (ADS)

Kuchmizhak, A. A.; Nepomnyashchii, A. V.; Vitrik, O. B.; Kulchin, Yu. N.

Biosensing characteristics of the laser-spalled nanotextures produced under single-pulse irradiation of a 500-nm thick Ag film surface were assessed by measuring spontaneous emission enhancement of overlaying Rhodamine 6G (Rh6G) molecules utilizing polarization-resolved confocal microspectroscopy technique. Our preliminary study shows for the first time that a single spalled micro-sized crater covered with sub-100 nm sharp tips at a certain excitation conditions provides up to 40-fold plasmon-mediated enhancement of the spontaneous emission from the 10-nm thick Rh6G over-layer indicating high potential of these easy-to-do structures for routine biosensing tasks.

UNIDENTIFIED INFRARED EMISSION BANDS: PAHs or MAONs?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun Kwok; Yong Zhang, E-mail: sunkwok@hku.hk

2013-07-01

We suggest that the carrier of the unidentified infrared emission (UIE) bands is an amorphous carbonaceous solid with mixed aromatic/aliphatic structures, rather than free-flying polycyclic aromatic hydrocarbon molecules. Through spectral fittings of the astronomical spectra of the UIE bands, we show that a significant amount of the energy is emitted by the aliphatic component, implying that aliphatic groups are an essential part of the chemical structure. Arguments in favor of an amorphous, solid-state structure rather than a gas-phase molecule as a carrier of the UIE are also presented.

Synthesis and Crystal Structure of Highly Strained [4]Cyclofluorene: Green-Emitting Fluorophore.

PubMed

Liu, Yu-Yu; Lin, Jin-Yi; Bo, Yi-Fan; Xie, Ling-Hai; Yi, Ming-Dong; Zhang, Xin-Wen; Zhang, Hong-Mei; Loh, Teck-Peng; Huang, Wei

2016-01-15

[4]Cyclo-9,9-dipropyl-2,7-fluorene ([4]CF) with the strain energy of 79.8 kcal/mol is synthesized in high quantum yield. Impressively, hoop-shaped [4]CF exhibits a green fluorescence emission around 512 nm offering a new explanation for the green band (g-band) in polyfluorenes. The solution-processed [4]CF-based organic light emitting diode (OLED) has also been fabricated with the a stronger green band emission. Strained semiconductors offer a promising approach to fabricating multifunctional optoelectronic materials in organic electronics and biomedicine.

Image plane detector spectrophotometer - Application to O2 atmospheric band nightglow

NASA Technical Reports Server (NTRS)

Luo, Mingzhao; Yee, Jeng-Hwa; Hays, Paul B.

1988-01-01

A new variety of low resolution spectrometer is described. This device, an image plane detector spectrophotometer, has high sensitivity and modest resolution sufficient to determine the rotational temperature and brightness of molecular band emissions. It uses an interference filter as a dispersive element and a multichannel image plane detector as the photon collecting device. The data analysis technqiue used to recover the temperature of the emitter and the emission brightness is presented. The atmospheric band of molecular oxygen is used to illustrate the use of the device.

Imaging diagnostics of pulsed plasma discharges in saline generated with various sharp pin powered electrodes

NASA Astrophysics Data System (ADS)

Asimakoulas, L.; Karim, M. L.; Dostal, L.; Krcma, F.; Graham, W. G.; Field, T. A.

2016-09-01

Plasmas formed by 1 ms pulses of between 180 and 300 V applied to sharp pin-like electrodes immersed in saline solution have been imaged with a Photron SA-X2 fast framing camera and an Andor iStar 510 ICCD camera. Stainless steel, Tungsten and Gold electrodes were investigated with tip diameters of 30 μm, 1 μm and < 1 μ m respectively. As previously observed, a vapour layer forms around the electrode prior to plasma ignition. For gold and stainless steel lower voltages were required to minimize electrode damage. Preliminary anlaysis indicates at lower voltages for all tips the fast framing results show that light emission is normally centred on a single small volume, which appears to move about, but remains close to the tip. In the case of Tungsten with higher voltages or longer pulses the tip of the needle can heat up to incandescent temperatures. At higher voltages shock wave fronts appear to be observed as the vapour layer collapses at the end of the voltage pulse. Backlighting and no lighting to observe bubble/vapour layer formation and emission due to plasma formation were employed. Sometimes at higher voltages a thicker vapour layer engulfs the tip and no plasma emission/current is observed.

Bat noseleaf model: echolocation function, design considerations, and experimental verification.

PubMed

Kuc, Roman

2011-05-01

This paper describes a possible bat noseleaf echolocation function that improves target elevation resolution. Bats with a protruding noseleaf can rotate the lancet to act as an acoustic mirror that reflects the nostril emission, modeled as a virtual nostril that produces a delayed emission. The cancellation of the nostril and virtual nostril components at a target produces a sharp spectral notch whose frequency location relates to target elevation. This notch can be observed directly from the swept-frequency emission waveform, suggesting cochlear processing capabilities. Physical acoustic principles indicate the design considerations and trade-offs that a bat can accomplish through noseleaf shape and emission characteristics. An experimental model verifies the analysis and exhibits an elevation versus notch frequency sensitivity of approximately 1°/kHz.

Anticrack inclusion model for compaction bands in sandstone

NASA Astrophysics Data System (ADS)

Sternlof, Kurt R.; Rudnicki, John W.; Pollard, David D.

2005-11-01

Detailed observations of compaction bands exposed in the Aztec Sandstone of southeastern Nevada indicate that these thin, tabular, bounded features of localized porosity loss initiated at pervasive grain-scale flaws, which collapsed in response to compressive tectonic loading. From many of these Griffith-type flaws, an apparently self-sustaining progression of collapse propagated outward to form bands of compacted grains a few centimeters thick and tens of meters in planar extent. These compaction bands can be idealized as highly eccentric ellipsoidal bodies that have accommodated uniform uniaxial plastic strain parallel to their short dimension within a surrounding elastic material. They thus can be represented mechanically as contractile Eshelby inclusions, which generate near-tip compressive stress concentrations consistent with self-sustaining, in-plane propagation. The combination of extreme aspect ratio (˜10-4) and significant uniaxial plastic strain (˜10%) also justifies an approximation of the bands as anticracks: sharp boundaries across which a continuous distribution of closing mode displacement discontinuity has been accommodated. This anticrack interpretation of compaction bands is analogous to that of pressure solution surfaces, except that porosity loss takes the place of material dissolution. We find that displacement discontinuity boundary element modeling of compaction bands as anticracks within a two-dimensional linear elastic continuum can accurately represent the perturbed external stress fields they induce.

Design of broadband multilayer dichroic coating for a high-efficiency solar energy harvesting system.

PubMed

Jiachen, Wang; Lee, Sang Bae; Lee, Kwanil

2015-05-20

We report on the design and performance of a broadband dichroic coating for a solar energy conversion system. As a spectral beam splitter, the coating facilitates a hybrid system that combines a photovoltaic cell with a thermal collector. When positioned at a 45° angle with respect to incident light, the coating provides high reflectance in the 40-1100 nm and high transmission in the 1200-2000 nm ranges for a photovoltaic cell and a thermal collector, respectively. Numerical simulations show that our design leads to a sharp transition between the reflection and transmission bands, low ripples in both bands, and slight polarization dependence.

Compact ultra wide band microstrip bandpass filter based on multiple-mode resonator and modified complementary split ring resonator.

PubMed

Marcotegui, J Antonio; Illescas, Jesús Miguel; Estevez, Aritz; Falcone, Francisco

2013-01-01

A new class of broadband microstrip filters for Ultra Wide Band (UWB) applications is proposed. In the design, different stages of parallel-coupled microstrip line and other stages with a Modified Complementary Split Ring Resonator (MCSRR)-a concept proposed here for the first time-are adjusted to obtain the desired response with broadband, sharp rejection, low insertion loss, and low return loss. Full wave simulation results as well as measurement results from fabricated prototypes are presented, showing good agreement. The proposed technique offers a new alternative to implement low-cost high-performance filter devices, applicable to a wide range of communication systems.

Compact Ultra Wide Band Microstrip Bandpass Filter Based on Multiple-Mode Resonator and Modified Complementary Split Ring Resonator

PubMed Central

Marcotegui, J. Antonio; Illescas, Jesús Miguel; Estevez, Aritz

2013-01-01

A new class of broadband microstrip filters for Ultra Wide Band (UWB) applications is proposed. In the design, different stages of parallel-coupled microstrip line and other stages with a Modified Complementary Split Ring Resonator (MCSRR)—a concept proposed here for the first time—are adjusted to obtain the desired response with broadband, sharp rejection, low insertion loss, and low return loss. Full wave simulation results as well as measurement results from fabricated prototypes are presented, showing good agreement. The proposed technique offers a new alternative to implement low-cost high-performance filter devices, applicable to a wide range of communication systems. PMID:24319366

Defect induced structural inhomogeneity, ultraviolet light emission and near-band-edge photoluminescence broadening in degenerate In2O3 nanowires

NASA Astrophysics Data System (ADS)

Mukherjee, Souvik; Sarkar, Ketaki; Wiederrecht, Gary P.; Schaller, Richard D.; Gosztola, David J.; Stroscio, Michael A.; Dutta, Mitra

2018-04-01

We demonstrate here defect induced changes on the morphology and surface properties of indium oxide (In2O3) nanowires and further study their effects on the near-band-edge (NBE) emission, thereby showing the significant influence of surface states on In2O3 nanostructure based device characteristics for potential optoelectronic applications. In2O3 nanowires with cubic crystal structure (c-In2O3) were synthesized via carbothermal reduction technique using a gold-catalyst-assisted vapor-liquid-solid method. Onset of strong optical absorption could be observed at energies greater than 3.5 eV consistent with highly n-type characteristics due to unintentional doping from oxygen vacancy ({V}{{O}}) defects as confirmed using Raman spectroscopy. A combination of high resolution transmission electron microscopy, x-ray photoelectron spectroscopy and valence band analysis on the nanowire morphology and stoichiometry reveals presence of high-density of {V}{{O}} defects on the surface of the nanowires. As a result, chemisorbed oxygen species can be observed leading to upward band bending at the surface which corresponds to a smaller valence band offset of 2.15 eV. Temperature dependent photoluminescence (PL) spectroscopy was used to study the nature of the defect states and the influence of the surface states on the electronic band structure and NBE emission has been discussed. Our data reveals significant broadening of the NBE PL peak consistent with impurity band broadening leading to band-tailing effect from heavy doping.

Electronic band structure and optical gain of GaN{sub x}Bi{sub y}As{sub 1−x−y}/GaAs pyramidal quantum dots

DOE Office of Scientific and Technical Information (OSTI.GOV)

Song, Zhi-Gang; State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083; Bose, Sumanta

The electronic band structure and optical gain of GaN{sub x}Bi{sub y}As{sub 1−x−y}/GaAs pyramidal quantum dots (QDs) are investigated using the 16-band k ⋅ p model with constant strain. The optical gain is calculated taking both homogeneous and inhomogeneous broadenings into consideration. The effective band gap falls as we increase the composition of nitrogen (N) and bismuth (Bi) and with an appropriate choice of composition we can tune the emission wavelength to span within 1.3 μm–1.55 μm, for device application in fiber technology. The extent of this red shift is more profound in QDs compared with bulk material due to quantum confinement. Othermore » factors affecting the emission characteristics include virtual crystal, strain profile, band anticrossing (BAC), and valence band anticrossing (VBAC). The strain profile has a profound impact on the electronic structure, specially the valence band of QDs, which can be determined using the composition distribution of wave functions. All these factors eventually affect the optical gain spectrum. With an increase in QD size, we observe a red shift in the emission energy and emergence of secondary peaks owing to transitions or greater energy compared with the fundamental transition.« less

Complex optical/UV and X-ray variability of the Seyfert 1 galaxy 1H 0419-577

NASA Astrophysics Data System (ADS)

Pal, Main; Dewangan, Gulab C.; Kembhavi, Ajit K.; Misra, Ranjeev; Naik, Sachindra

2018-01-01

We present detailed broad-band UV/optical to X-ray spectral variability of the Seyfert 1 galaxy 1H 0419-577 using six XMM-Newton observations performed during 2002-2003. These observations covered a large amplitude variability event in which the soft X-ray (0.3-2 keV) count rate increased by a factor of ∼4 in six months. The X-ray spectra during the variability are well described by a model consisting of a primary power law, blurred and distant reflection. The 2-10 keV power-law flux varied by a factor of ∼7 while the 0.3-2 keV soft X-ray excess flux derived from the blurred reflection component varied only by a factor of ∼2. The variability event was also observed in the optical and UV bands but the variability amplitudes were only at the 6-10 per cent level. The variations in the optical and UV bands appear to follow the variations in the X-ray band. During the rising phase, the optical bands appear to lag behind the UV band but during the declining phase, the optical bands appear to lead the UV band. Such behaviour is not expected in the reprocessing models where the optical/UV emission is the result of reprocessing of X-ray emission in the accretion disc. The delayed contribution of the broad emission lines in the UV band or the changes in the accretion disc/corona geometry combined with X-ray reprocessing may give rise to the observed behaviour of the variations.

Freeze-Drying Process Development and Scale-Up: Scale-Up of Edge Vial Versus Center Vial Heat Transfer Coefficients, Kv.

PubMed

Pikal, Michael J; Bogner, Robin; Mudhivarthi, Vamsi; Sharma, Puneet; Sane, Pooja

2016-11-01

This report presents calculations of the difference between the vial heat transfer coefficient of the "edge vial" and the "center vial" at all scales. The only scale-up adjustment for center vials is for the contribution of radiation from the shelf upon which the vial sits by replacing the emissivity of the laboratory dryer shelf with the emissivity of the production dryer shelf. With edge vials, scales-up adjustments are more complex. While convection is not important, heat transfer from the wall to the bands (surrounding the vial array) by radiation and directly from the band to the vials by both radiation and conduction is important; this radiation heat transfer depends on the emissivity of the vial and the bands and is nearly independent of the emissivity of the dryer walls. Differences in wall temperatures do impact the edge vial effect and scale-up, and estimates for wall temperatures are needed for both laboratory and manufacturing dryers. Auto-loading systems (no bands) may give different edge vial heat transfer coefficients than when operating with bands. Satisfactory agreement between theoretical predictions and experimental values of the edge vial effect indicate that results calculated from the theory are of useful accuracy. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Green Color Purification in Tb(3+) Ions through Silica Inverse Opal Heterostructure.

PubMed

Shrivastava, Vishnu Prasad; Sivakumar, Sri; Kumar, Jitendra

2015-06-10

The ordered SiO2:Tb(3+) inverse opal heterostructure films are fabricated through polystyrene spheres hetero-opal template using the convective self-assembly method to examine their potential for color purification. Their optical properties and photoluminescence have been investigated and compared with individual single inverse opals and reference (SiO2:Tb(3+) powder). The heterostructures are shown to possess two broad photonic stop bands separated by an effective pass band, causing suppression of blue, orange, and red emission bands corresponding to (5)D4 → (7)F(j); j = 6, 4, 3 transitions, respectively and an enhancement of green emission (i.e., (5)D4 → (7)F5). Although the suppression of various emission occurs because of its overlap with the photonic band gaps (PSBs), the enhancement of green radiation is observed because of its location matching with the pass band region. The Commission International de l'Eclairage (CIE) chromaticity coordinates of the emission spectrum of the heterostructure based on polystyrene sphere of 390 and 500 nm diameter are x = 0.2936, y = 0.6512 and lie closest to those of standard green color (wavelength 545 nm). In addition, a significant increase observed in luminescence lifetime for (5)D4 level of terbium in inverse opal heterostructures vis-à-vis reference (SiO2:Tb(3+) powder) is attributed to the change in the effective refractive index.

A 1.1-1.9 GHz SETI Survey of the Kepler Field. I. A Search for Narrow-band Emission from Select Targets

NASA Astrophysics Data System (ADS)

Siemion, Andrew P. V.; Demorest, Paul; Korpela, Eric; Maddalena, Ron J.; Werthimer, Dan; Cobb, Jeff; Howard, Andrew W.; Langston, Glen; Lebofsky, Matt; Marcy, Geoffrey W.; Tarter, Jill

2013-04-01

We present a targeted search for narrow-band (<5 Hz) drifting sinusoidal radio emission from 86 stars in the Kepler field hosting confirmed or candidate exoplanets. Radio emission less than 5 Hz in spectral extent is currently known to only arise from artificial sources. The stars searched were chosen based on the properties of their putative exoplanets, including stars hosting candidates with 380 K > T eq > 230 K, stars with five or more detected candidates or stars with a super-Earth (R p < 3 R ⊕) in a >50 day orbit. Baseband voltage data across the entire band between 1.1 and 1.9 GHz were recorded at the Robert C. Byrd Green Bank Telescope between 2011 February and April and subsequently searched offline. No signals of extraterrestrial origin were found. We estimate that fewer than ~1% of transiting exoplanet systems host technological civilizations that are radio loud in narrow-band emission between 1 and 2 GHz at an equivalent isotropically radiated power (EIRP) of ~1.5 × 1021 erg s-1, approximately eight times the peak EIRP of the Arecibo Planetary Radar, and we limit the number of 1-2 GHz narrow-band-radio-loud Kardashev type II civilizations in the Milky Way to be {<}10^{-6}\\ M^{-1}_\\odot. Here we describe our observations, data reduction procedures and results.

Storm-Time VLF Emissions Caused by The Solar Wind Disturbances: A Case Study on 8 December 2013

NASA Astrophysics Data System (ADS)

Manninen, J.; Kleimenova, N. G.; Turunen, T.; Gromova, L. I.

2017-08-01

This study is made of temporal variations of the daytime VLF emissions (1-6 kHz) occurred during the moderate magnetic storm (Kp = 6) on 8 December 2013. The storm was associated with the Coronal Mass Ejection (CME). VLF emissions were recorded in the frequency band of 0.2-39 kHz during the dark winter at Kannuslehto (KAN, L 5.5) in Northern Finland. The results were compared with simultaneous variations in the solar wind and Interplanetary Magnetic Field (IMF). It was found that intense VLF chorus started after the pressure jump in solar wind (from 7 to 12 nPa) under the positive IMF Bz. The VLF emissions occurred in two separate frequency bands. The lower frequency (below 2 kHz) band represents the intense long lasting hiss with right-hand polarization, and in the upper frequency band (above 2 kHz) the left-hand polarized hiss bursts occurred during about 1 hour. The plasmasphere was strongly compressed, and due to that KAN was mapped outside of the plasmapause. We suppose that VLF chorus exited in the magnetosphere by the cyclotron instability of the radiation belt electrons. The low frequency chorus was generated outside of the plasmapause and arrived to KAN along the direction of N-S meridian. The high-frequency band was generated inside of the plasmasphere arrived to KAN almost along the meridian.

Integrated Advanced Microwave Sounding Unit-A (AMSU-A). Engineering Test Report: Radiated Emissions and SARR, SARP, DCS Receivers, Link Frequencies EMI Sensitive Band Test Results, AMSU-A2, S/N 108, 08

NASA Technical Reports Server (NTRS)

Valdez, A.

2000-01-01

This is the Engineering Test Report, Radiated Emissions and SARR, SARP, DCS Receivers, Link Frequencies EMI Sensitive Band Test Results, AMSU-A2, S/N 108, for the Integrated Advanced Microwave Sounding Unit-A (AMSU-A).

47 CFR 25.252 - Special requirements for ancillary terrestrial components operating in the 2000-2020 MHz/2180...

Code of Federal Regulations, 2011 CFR

2011-10-01

... MHz. (3) Exceed an EIRP toward the physical horizon (not to include man-made structures) of 25.5 dBW... active transmission interval, of discrete out-of-band emissions of less than 700 Hz bandwidth from such... EIRP, measured over any two-millisecond active transmission interval, of discrete out-of-band emissions...

47 CFR 25.252 - Special requirements for ancillary terrestrial components operating in the 2000-2020 MHz/2180...

Code of Federal Regulations, 2010 CFR

2010-10-01

... MHz. (3) Exceed an EIRP toward the physical horizon (not to include man-made structures) of 25.5 dBW... active transmission interval, of discrete out-of-band emissions of less than 700 Hz bandwidth from such... EIRP, measured over any two-millisecond active transmission interval, of discrete out-of-band emissions...

47 CFR 25.252 - Special requirements for ancillary terrestrial components operating in the 2000-2020 MHz/2180...

Code of Federal Regulations, 2012 CFR

2012-10-01

... MHz. (3) Exceed an EIRP toward the physical horizon (not to include man-made structures) of 25.5 dBW... active transmission interval, of discrete out-of-band emissions of less than 700 Hz bandwidth from such... EIRP, measured over any two-millisecond active transmission interval, of discrete out-of-band emissions...

Photovoltaic Performance Enhancement of Silicon Solar Cells Based on Combined Ratios of Three Species of Europium-Doped Phosphors.

PubMed

Ho, Wen-Jeng; You, Bang-Jin; Liu, Jheng-Jie; Bai, Wen-Bin; Syu, Hong-Jhang; Lin, Ching-Fuh

2018-05-18

This paper presents a scheme for the enhancement of silicon solar cells in terms of luminescent emission band and photovoltaic performance. The proposed devices are coated with an luminescent down-shifting (LDS) layer comprising three species of europium (Eu)-doped phosphors mixed within a silicate film (SiO₂) using a spin-on film deposition. The three species of phosphor were mixed at ratios of 0.5:1:1.5, 1:1:1, or 1.5:1:0.5 in weight percentage (wt %). The total quantity of Eu-doped phosphors in the silicate solution was fixed at 3 wt %. The emission wavelengths of the Eu-doped phosphors were as follows: 518 nm (specie-A), 551 nm (specie-B), and 609 nm (specie-C). We examined the extended luminescent emission bands via photoluminescence measurements at room temperature. Closely matching the luminescent emission band to the high responsivity band of the silicon semiconductor resulted in good photovoltaic performance. Impressive improvements in efficiency were observed in all three samples: 0.5:1:1.5 (20.43%), 1:1:1 (19.67%), 1.5:1:0.5 (16.81%), compared to the control with a layer of pure SiO₂ (13.80%).

Molecular emission in laser-induced breakdown spectroscopy: An investigation of its suitability for chlorine quantification on Mars

NASA Astrophysics Data System (ADS)

Vogt, D. S.; Rammelkamp, K.; Schröder, S.; Hübers, H. W.

2018-03-01

The intensity of the molecular CaCl emission in LIBS spectra is examined in order to evaluate its suitability for the detection of chlorine in a Martian environment. Various mixtures resembling Martian targets with varying Cl content are investigated under simulated Martian conditions. The reactions leading to the formation of CaCl are modeled based on reaction kinetics and are used to fit the measured CaCl band intensities. MgCl bands are also investigated as potential alternatives to CaCl, but no MgCl bands can be identified in samples containing both Mg and Cl. The study confirms that CaCl is well suited for the indirect detection of chlorine, but finds a strong dependence on the concentrations of Ca and Cl in the sample. Spectra from samples with a high chlorine concentration can have low-intensity CaCl emission due to a deficiency of Ca. A qualitative estimate of the sample composition is possible based on the ratio of the band intensity of CaCl to the intensity of Ca emission lines. Time-resolved measurements show that the CaCl concentration in the plasma is highest after about 1 μs.

Method and apparatus for chemical and topographical microanalysis

NASA Technical Reports Server (NTRS)

Kossakovski, Dmitri A. (Inventor); Baldeschwieler, John D. (Inventor); Beauchamp, Jesse L. (Inventor)

2002-01-01

A scanning probe microscope is combined with a laser induced breakdown spectrometer to provide spatially resolved chemical analysis of the surface correlated with the surface topography. Topographical analysis is achieved by scanning a sharp probe across the sample at constant distance from the surface. Chemical analysis is achieved by the means of laser induced breakdown spectroscopy by delivering pulsed laser radiation to the sample surface through the same sharp probe, and consequent collection and analysis of emission spectra from plasma generated on the sample by the laser radiation. The method comprises performing microtopographical analysis of the sample with a scanning probe, selecting a scanned topological site on the sample, generating a plasma plume at the selected scanned topological site, and measuring a spectrum of optical emission from the plasma at the selected scanned topological site. The apparatus comprises a scanning probe, a pulsed laser optically coupled to the probe, an optical spectrometer, and a controller coupled to the scanner, laser and spectrometer for controlling the operation of the scanner, laser and spectrometer. The probe and scanner are used for topographical profiling the sample. The probe is also used for laser radiation delivery to the sample for generating a plasma plume from the sample. Optical emission from the plasma plume is collected and delivered to the optical spectrometer so that analysis of emission spectrum by the optical spectrometer allows for identification of chemical composition of the sample at user selected sites.

Strong visible and near infrared photoluminescence from ZnO nanorods/nanowires grown on single layer graphene studied using sub-band gap excitation

NASA Astrophysics Data System (ADS)

Biroju, Ravi K.; Giri, P. K.

2017-07-01

Fabrication and optoelectronic applications of graphene based hybrid 2D-1D semiconductor nanostructures have gained tremendous research interest in recent times. Herein, we present a systematic study on the origin and evolution of strong broad band visible and near infrared (NIR) photoluminescence (PL) from vertical ZnO nanorods (NRs) and nanowires (NWs) grown on single layer graphene using both above band gap and sub-band gap optical excitations. High resolution field emission scanning electron microscopy and X-ray diffraction studies are carried out to reveal the morphology and crystalline quality of as-grown and annealed ZnO NRs/NWs on graphene. Room temperature PL studies reveal that besides the UV and visible PL bands, a new near-infrared (NIR) PL emission band appears in the range between 815 nm and 886 nm (1.40-1.52 eV). X-ray photoelectron spectroscopy studies revealed excess oxygen content and unreacted metallic Zn in the as-grown ZnO nanostructures, owing to the low temperature growth by a physical vapor deposition method. Post-growth annealing at 700 °C in the Ar gas ambient results in the enhanced intensity of both visible and NIR PL bands. On the other hand, subsequent high vacuum annealing at 700 °C results in a drastic reduction in the visible PL band and complete suppression of the NIR PL band. PL decay dynamics of green emission in Ar annealed samples show tri-exponential decay on the nanosecond timescale including a very slow decay component (time constant ˜604.5 ns). Based on these results, the NIR PL band comprising two peaks centered at ˜820 nm and ˜860 nm is tentatively assigned to neutral and negatively charged oxygen interstitial (Oi) defects in ZnO, detected experimentally for the first time. The evidence for oxygen induced trap states on the ZnO NW surface is further substantiated by the slow photocurrent response of graphene-ZnO NRs/NWs. These results are important for tunable light emission, photodetection, and other cutting edge applications of graphene-ZnO based 2D-1D hybrid nanostructures.

Liquid Crystal Cells for Blazed Grating Steering Devices.

DTIC Science & Technology

1999-12-08

gratings2, and micromirror devices3, among other technologies. Liquid crystalline materials are also under investigation for their potential use in beam...discrete wavelengths over a range encompassing the reflection band. These FDTD-generated data points were superimposed on the curve of the analytic...field intensity pattern is shown in Figure 3.19. The sharp spike in the near field intensity curve is the product of the disclination appearing in

Linear Phase Sharp Transition BPF to Detect Noninvasive Maternal and Fetal Heart Rate.

PubMed

Marchon, Niyan; Naik, Gourish; Pai, K R

2018-01-01

Fetal heart rate (FHR) detection can be monitored using either direct fetal scalp electrode recording (invasive) or by indirect noninvasive technique. Weeks before delivery, the invasive method poses a risk factor to the fetus, while the latter provides accurate fetal ECG (FECG) information which can help diagnose fetal's well-being. Our technique employs variable order linear phase sharp transition (LPST) FIR band-pass filter which shows improved stopband attenuation at higher filter orders. The fetal frequency fiduciary edges form the band edges of the filter characterized by varying amounts of overlap of maternal ECG (MECG) spectrum. The one with the minimum maternal spectrum overlap was found to be optimum with no power line interference and maximum fetal heart beats being detected. The improved filtering is reflected in the enhancement of the performance of the fetal QRS detector (FQRS). The improvement has also occurred in fetal heart rate obtained using our algorithm which is in close agreement with the true reference (i.e., invasive fetal scalp ECG). The performance parameters of the FQRS detector such as sensitivity (Se), positive predictive value (PPV), and accuracy (F 1 ) were found to improve even for lower filter order. The same technique was extended to evaluate maternal QRS detector (MQRS) and found to yield satisfactory maternal heart rate (MHR) results.

Field-induced coexistence of s++ and s± superconducting states in dirty multiband superconductors

NASA Astrophysics Data System (ADS)

Garaud, Julien; Corticelli, Alberto; Silaev, Mihail; Babaev, Egor

2018-02-01

In multiband systems, such as iron-based superconductors, the superconducting states with locking and antilocking of the interband phase differences are usually considered as mutually exclusive. For example, a dirty two-band system with interband impurity scattering undergoes a sharp crossover between the s± state (which favors phase antilocking) and the s++ state (which favors phase locking). We discuss here that the situation can be much more complex in the presence of an external field or superconducting currents. In an external applied magnetic field, dirty two-band superconductors do not feature a sharp s±→s++ crossover but rather a washed-out crossover to a finite region in the parameter space where both s± and s++ states can coexist for example as a lattice or a microemulsion of inclusions of different states. The current-carrying regions such as the regions near vortex cores can exhibit an s± state while it is the s++ state that is favored in the bulk. This coexistence of both states can even be realized in the Meissner state at the domain's boundaries featuring Meissner currents. We demonstrate that there is a magnetic-field-driven crossover between the pure s± and the s++ states.

Thermal characteristics of multi-wavelength emission during a B8.3 flare occurred on July 04, 2009

NASA Astrophysics Data System (ADS)

Awasthi, Arun Kumar; Sylwester, Barbara; Sylwester, Janusz; Jain, Rajmal

2015-08-01

We explore the temporal evolution of flare plasma parameters including temperature (T) - differential emission measure (DEM) relationship by analyzing high spectral and temporal cadence X-ray emission in 1.2-20 keV energy band, recorded by SphinX (Polish) and Solar X-ray Spectrometer (SOXS; Indian) instruments, during a B8.3 flare which occurred on July 04, 2009. SphinX records X-ray emission in 1.2-15 keV energy band with the temporal and spectral cadence as good as 6µs and 0.4 keV, respectively. On the other hand, SOXS provides X-ray observations in 4-25 keV energy band with the temporal and spectral resolution of 3s and 0.7 keV, respectively. In addition, we integrate co-temporal EUV line emission in 171, 194 and 284 angstrom obtained from STEREO mission in order to explore low-temperature response to the flare emission. In order to fit observed evolution of multi-wavelength emission during the flare, we incorporate multi-Gaussian and well-established Withbroe - Sylwester maximum likelihood DEM inversion algorithms. Thermal energetics are also estimated using geometrically corrected flaring loop structure obtained through EUV images of the active region from STEREO twin satellites. In addition, we also study the trigger and energy release scenario of this low-intensity class flare in terms of magnetic field as well as multi-wavelength emission.

Modeling electron emission and surface effects from diamond cathodes

NASA Astrophysics Data System (ADS)

Dimitrov, D. A.; Smithe, D.; Cary, J. R.; Ben-Zvi, I.; Rao, T.; Smedley, J.; Wang, E.

2015-02-01

We developed modeling capabilities, within the Vorpal particle-in-cell code, for three-dimensional simulations of surface effects and electron emission from semiconductor photocathodes. They include calculation of emission probabilities using general, piece-wise continuous, space-time dependent surface potentials, effective mass, and band bending field effects. We applied these models, in combination with previously implemented capabilities for modeling charge generation and transport in diamond, to investigate the emission dependence on applied electric field in the range from approximately 2 MV/m to 17 MV/m along the [100] direction. The simulation results were compared to experimental data. For the considered parameter regime, conservation of transverse electron momentum (in the plane of the emission surface) allows direct emission from only two (parallel to [100]) of the six equivalent lowest conduction band valleys. When the electron affinity χ is the only parameter varied in the simulations, the value χ = 0.31 eV leads to overall qualitative agreement with the probability of emission deduced from experiments. Including band bending in the simulations improves the agreement with the experimental data, particularly at low applied fields, but not significantly. Using surface potentials with different profiles further allows us to investigate the emission as a function of potential barrier height, width, and vacuum level position. However, adding surface patches with different levels of hydrogenation, modeled with position-dependent electron affinity, leads to the closest agreement with the experimental data.

Annealing effect on the photoluminescence properties of ZnO nanorod array prepared by a PLD-assistant wet chemical method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wei Sufeng; Lian Jianshe; Wu Hua, E-mail: weisufeng@gmail.com

2010-11-15

Well-aligned ZnO nanorod arrays were synthesized by a wet chemical method on the glass substrate with ZnO thin film as seed layer prepared by pulsed laser deposition. The effect of annealing temperature on the luminescence characteristics was investigated. As the annealing temperature increased, the photoluminescence properties show a general enhancing tendency. The nanorod array with high ultraviolet emission and negligible visible light emission (designated by the photoluminescence intensity ratio of ultraviolet to visible emission of 66.4) is obtained by annealing the sample at 700 deg. C for 1 h. Based on the results of X-ray photoelectron spectroscopy and photoluminescence spectra,more » the mechanisms of visible emission were discussed. - Research Highlights: {yields} ZnO nanorod array with good crystallography, low defects concentration and good optical property was obtained after annealed at 700 deg. C for 1 h. {yields} The transition from the conduction band to the O{sub i} level may be responsible for the yellow-green emission. {yields} The yellow emission may originate from the presence of Zn(OH){sub 2} on the surface or the band transition from conduction band to V{sub o}Zn{sub i} level. {yields} The transition from the Zn{sub i} level to the level should produce an orange emission or an orange-red emission.« less

Blue light emission from ZnO-graphene hybrid quantum dot (Conference Presentation)

NASA Astrophysics Data System (ADS)

Choi, Won Kook; Kim, Hong Hee; Park, Cheolmin; Hwang, Do Kyung; Lee, Yeonju

2017-03-01

One of a wide-bandgap semiconductor, Zinc oxide (ZnO) has a near ultraviolet bandgap (3.37 eV) and an exciton binding energy of 60 meV at room temperature (RT), and has several favorable properties, such as high electron mobility, high oscillator strength, and good transparency. In the photoluminescence (PL) spectra of ZnO nanoparticles, the near band edge ultraviolet (UV) emission at 378 nm relevant to direct bandgap of ZnO, and blue light emissions centered at 410, 435, and 465 nm corresponding to Zn interstitial (Zni) to valence band maximum (VBM), and to Zn vacancies (VZn) and green light emission at 540 nm corresponding to conduction band maximum (CBM) to oxygen vacancy (Vo). Ultra-small size quasi consolidated ZnO-graphene nanoparticles was synthesized in which graphene outer layer was chemically attached with ZnO inner core. After attaching graphene to ZnO, green emission completely disappeared whereas the intensity of blue emission was greatly increased. Enhanced blue emission could be well described by both fast electron transfer from CBM of ZnO to graphene having similar molecular energy level with Zni and transition to VBM and Vzn. Glass/ITO/PEDOT:PSS/poly-TPD/ZnO-graphene/Cs2CO3/Al were fabricated and showed the blue emission centered at 435 nm with FWHM of about 90 nm.

First-Year Wilkinson Microwave Anisotropy Probe (WMAP) Observations: Foreground Emission

NASA Astrophysics Data System (ADS)

Bennett, C. L.; Hill, R. S.; Hinshaw, G.; Nolta, M. R.; Odegard, N.; Page, L.; Spergel, D. N.; Weiland, J. L.; Wright, E. L.; Halpern, M.; Jarosik, N.; Kogut, A.; Limon, M.; Meyer, S. S.; Tucker, G. S.; Wollack, E.

2003-09-01

The WMAP mission has mapped the full sky to determine the geometry, content, and evolution of the universe. Full-sky maps are made in five microwave frequency bands to separate the temperature anisotropy of the cosmic microwave background (CMB) from foreground emission, including diffuse Galactic emission and Galactic and extragalactic point sources. We define masks that excise regions of high foreground emission, so CMB analyses can be carried out with minimal foreground contamination. We also present maps and spectra of the individual emission components, leading to an improved understanding of Galactic astrophysical processes. The effectiveness of template fits to remove foreground emission from the WMAP data is also examined. These efforts result in a CMB map with minimal contamination and a demonstration that the WMAP CMB power spectrum is insensitive to residual foreground emission. We use a maximum entropy method to construct a model of the Galactic emission components. The observed total Galactic emission matches the model to less than 1%, and the individual model components are accurate to a few percent. We find that the Milky Way resembles other normal spiral galaxies between 408 MHz and 23 GHz, with a synchrotron spectral index that is flattest (βs~-2.5) near star-forming regions, especially in the plane, and steepest (βs~-3) in the halo. This is consistent with a picture of relativistic cosmic-ray electron generation in star-forming regions and diffusion and convection within the plane. The significant synchrotron index steepening out of the plane suggests a diffusion process in which the halo electrons are trapped in the Galactic potential long enough to suffer synchrotron and inverse Compton energy losses and hence a spectral steepening. The synchrotron index is steeper in the WMAP bands than in lower frequency radio surveys, with a spectral break near 20 GHz to βs<-3. The modeled thermal dust spectral index is also steep in the WMAP bands, with βd~2.2. Our model is driven to these conclusions by the low level of total foreground contamination at ~60 GHz. Microwave and Hα measurements of the ionized gas agree well with one another at about the expected levels. Spinning dust emission is limited to <~5% of the Ka-band foreground emission, assuming a thermal dust distribution with a cold neutral medium spectrum and a monotonically decreasing synchrotron spectrum. A catalog of 208 point sources is presented. The reliability of the catalog is 98%; i.e., we expect five of the 208 sources to be statistically spurious. The mean spectral index of the point sources is α~0 (β~-2). Derived source counts suggest a contribution to the anisotropy power from unresolved sources of (15.0+/-1.4)×10-3 μK2 sr at Q band and negligible levels at V band and W band. The Sunyaev-Zeldovich effect is shown to be a negligible ``contamination'' to the maps. WMAP is the result of a partnership between Princeton University and the NASA Goddard Space Flight Center. Scientific guidance is provided by the WMAP Science Team.

EUV studies of N2 and O2 produced by low energy electron impact

NASA Technical Reports Server (NTRS)

Morgan, H. D.; Mentall, J. E.

1983-01-01

The emission spectra resulting from electron impact excitation on molecular nitrogen and oxygen in the 500-1200 A spectral region are investigated. Electron energies are from 0 to 300 eV. Numerous bands of N2 are found between 800 and 1000 A. Excitation functions are measured for the NII 916 A, the OI 879 A, and the OII 834 multiplets, and nitrogen band emission. Cross sections were measured at 200 eV for several of the band emissions plus the NI 1135 A, NI 1164 A, NI 1177 A, NII 776 A, NII 1084 A, OI 1152 A, OI 1041 A, OI 999 A, OI 989 A, OI 879 A, OII 834 A, OII 616 A, OII 555 A, OII 539 A, and OII 718 A multiplets.

Spark discharge trace element detection system

DOEpatents

Adler-Golden, Steven; Bernstein, Lawrence S.; Bien, Fritz

1988-01-01

A spark discharge trace element detection system is provided which includes a spark chamber including a pair of electrodes for receiving a sample of gas to be analyzed at no greater than atmospheric pressure. A voltage is provided across the electrodes for generating a spark in the sample. The intensity of the emitted radiation in at least one primary selected narrow band of the radiation is detected. Each primary band corresponds to an element to be detected in the gas. The intensity of the emission in each detected primary band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in each selected primary bond is utilized to determine the concentration of the corresponding element in the gas.

Spark discharge trace element detection system

DOEpatents

Adler-Golden, S.; Bernstein, L.S.; Bien, F.

1988-08-23

A spark discharge trace element detection system is provided which includes a spark chamber including a pair of electrodes for receiving a sample of gas to be analyzed at no greater than atmospheric pressure. A voltage is provided across the electrodes for generating a spark in the sample. The intensity of the emitted radiation in at least one primary selected narrow band of the radiation is detected. Each primary band corresponds to an element to be detected in the gas. The intensity of the emission in each detected primary band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in each selected primary bond is utilized to determine the concentration of the corresponding element in the gas. 12 figs.

Structural and optical characterization of self-assembled Ge nanocrystal layers grown by plasma-enhanced chemical vapor deposition.

PubMed

Saeed, Saba; Buters, Frank; Dohnalova, Katerina; Wosinski, Lech; Gregorkiewicz, Tom

2014-10-10

We present a structural and optical study of solid-state dispersions of Ge nanocrystals prepared by plasma-enhanced chemical vapor deposition. Structural analysis shows the presence of nanocrystalline germanium inclusions embedded in an amorphous matrix of Si-rich SiO(2).Optical characterization reveals two prominent emission bands centered around 2.6 eV and 3.4 eV, and tunable by excitation energy. In addition, the lower energy band shows an excitation power-dependent blue shift of up to 0.3 eV. Decay dynamics of the observed emission contains fast (nanosecond) and slow (microseconds) components, indicating contributions of several relaxation channels. Based on these material characteristics, a possible microscopic origin of the individual emission bands is discussed.

Two Surface Temperature Retrieval Methods Compared Over Agricultural Lands

NASA Technical Reports Server (NTRS)

French, Andrew N.; Schmugge, Thomas J.; Jacob, Frederic; Ogawa, Kenta; Houser, Paul R. (Technical Monitor)

2002-01-01

Accurate, spatially distributed surface temperatures are required for modeling evapotranspiration (ET) over agricultural fields under wide ranging conditions, including stressed and unstressed vegetation. Modeling approaches that use surface temperature observations, however, have the burden of estimating surface emissivities. Emissivity estimation, the subject of much recent research, is facilitated by observations in multiple thermal infrared bands. But it is nevertheless a difficult task. Using observations from a multiband thermal sensor, the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), estimated surface emissivities and temperatures are retrieved in two different ways: the temperature emissivity separation approach (TES) and the normalized emissivity approach (NEM). Both rely upon empirical relationships, but the assumed relationships are different. TES relies upon a relationship between the minimum spectral emissivity and the range of observed emissivities. NEM relies upon an assumption that at least one thermal band has a pre-determined emissivity (close to 1.0). The benefits and consequences of each approach will be demonstrated for two different landscapes: one in central Oklahoma, USA and another in southern New Mexico.

Detection of Buckminsterfullerene emission in the diffuse interstellar medium.

PubMed

Berné, O; Cox, N L J; Mulas, G; Joblin, C

2017-09-01

Emission of fullerenes in their infrared vibrational bands has been detected in space near hot stars. The proposed attribution of the diffuse interstellar bands at 9577 and 9632 Å to electronic transitions of the buckminsterfullerene cation (i.e. [Formula: see text]) was recently supported by new laboratory data, confirming the presence of this species in the diffuse interstellar medium (ISM). In this letter, we present the detection, also in the diffuse ISM, of the 17.4 and 18.9 μ m emission bands commonly attributed to vibrational bands of neutral C 60 . According to classical models that compute the charge state of large molecules in space, C 60 is expected to be mostly neutral in the diffuse ISM. This is in agreement with the abundances of diffuse C 60 we derive here from observations. We also find that C 60 is less abundant in the diffuse ISM than in star-forming regions, supporting the theory that C 60 can be formed in these regions.

Properties of polycyclic aromatic hydrocarbons in the northwest photon dominated region of NGC 7023. II. Traditional PAH analysis using k-means as a visualization tool

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boersma, C.; Bregman, J.; Allamandola, L. J., E-mail: Christiaan.Boersma@nasa.gov

2014-11-10

Polycyclic aromatic hydrocarbon (PAH) emission in the Spitzer-IRS spectral map of the northwest photon dominated region (PDR) in NGC 7023 is analyzed using the 'traditional' approach in which the PAH bands and plateaus between 5.2-19.5 μm are isolated by subtracting the underlying continuum and removing H{sub 2} emission lines. The spectra are organized into seven spectroscopic bins by using k-means clustering. Each cluster corresponds to, and reveals, a morphological zone within NGC 7023. The zones self-organize parallel to the well-defined PDR front that coincides with an increase in intensity of the H{sub 2} emission lines. PAH band profiles and integratedmore » strengths are measured, classified, and mapped. The morphological zones revealed by the k-means clustering provides deeper insight into the conditions that drive variations in band strength ratios and evolution of the PAH population that otherwise would be lost. For example, certain band-band relations are bifurcated, revealing two limiting cases; one associated with the PDR, the other with the diffuse medium. Traditionally, PAH band strength ratios are used to gain insight into the properties of the emitting PAH population, i.e., charge, size, structure, and composition. Insights inferred from this work are compared and contrasted to those from Boersma et al. (first paper in this series), where the PAH emission in NGC 7023 is decomposed exclusively using the PAH spectra and tools made available through the NASA Ames PAH IR Spectroscopic Database.« less

Valence-band and core-level photoemission study of single-crystal Bi2CaSr2Cu2O8 superconductors

NASA Astrophysics Data System (ADS)

Shen, Z.-X.; Lindberg, P. A. P.; Wells, B. O.; Mitzi, D. B.; Lindau, I.; Spicer, W. E.; Kapitulnik, A.

1988-12-01

High-quality single crystals of Bi2CaSr2Cu2O8 superconductors have been prepared and cleaved in ultrahigh vacuum. Low-energy electron diffraction measurements show that the surface structure is consistent with the bulk crystal structure. Ultraviolet photoemission and x-ray photoemission experiments were performed on these well-characterized sample surfaces. The valence-band and the core-level spectra obtained from the single-crystal surfaces are in agreement with spectra recorded from polycrystalline samples, justifying earlier results from polycrystalline samples. Cu satellites are observed both in the valence band and Cu 2p core level, signaling the strong correlation among the Cu 3d electrons. The O 1s core-level data exhibit a sharp, single peak at 529-eV binding energy without any clear satellite structures.

Silicon nanoparticle-ZnS nanophosphors for ultraviolet-based white light emitting diode

NASA Astrophysics Data System (ADS)

Stupca, Matthew; Nayfeh, Osama M.; Hoang, Tuan; Nayfeh, Munir H.; Alhreish, Bahjat; Boparai, Jack; AlDwayyan, Abdullah; AlSalhi, Mohamad

2012-10-01

Present red phosphor converters provide spectra dominated by sharp lines and suffer from availability and stability issues which are not ideal for color mixing in display or solid state lighting applications. We examine the use of mono dispersed 3 nm silicon nanoparticles, with inhomogeneously broadened red luminescence as an effective substitute for red phosphors. We tested a 3-phase hybrid nanophosphor consisting of ZnS:Ag, ZnS:Cu,Au,Al, and nanoparticles. Correlated color temperature is examined under UV and LED pumping in the range 254, 365-400 nm. The temperature is found reasonably flat for the longer wavelengths and drops for the shorter wavelengths while the color rendering index increases. The photo stability of the phosphors relative to the silicon nanoparticles is recorded. The variation in the temperature is analyzed in terms of the strength of inter-band-gap transition and continuum band to band transitions.

LANDSAT-4 MSS and Thematic Mapper data quality and information content analysis

NASA Technical Reports Server (NTRS)

Anuta, P.; Bartolucci, L.; Dean, E.; Lozano, F.; Malaret, E.; Mcgillem, C. D.; Valdes, J.; Valenzuela, C.

1984-01-01

LANDSAT-4 thematic mapper (TM) and multispectral scanner (MSS) data were analyzed to obtain information on data quality and information content. Geometric evaluations were performed to test band-to-band registration accuracy. Thematic mapper overall system resolution was evaluated using scene objects which demonstrated sharp high contrast edge responses. Radiometric evaluation included detector relative calibration, effects of resampling, and coherent noise effects. Information content evaluation was carried out using clustering, principal components, transformed divergence separability measure, and supervised classifiers on test data. A detailed spectral class analysis (multispectral classification) was carried out to compare the information content of the MSS and TM for a large number of scene classes. A temperature-mapping experiment was carried out for a cooling pond to test the quality of thermal-band calibration. Overall TM data quality is very good. The MSS data are noisier than previous LANDSAT results.

Estimating net rainfall, evaporation and water storage of a bare soil from sequential L-band emissivities

NASA Technical Reports Server (NTRS)

Stroosnijder, L.; Lascano, R. J.; Newton, R. W.; Vanbavel, C. H. M.

1984-01-01

A general method to use a time series of L-band emissivities as an input to a hydrological model for continuously monitoring the net rainfall and evaporation as well as the water content over the entire soil profile is proposed. The model requires a sufficiently accurate and general relation between soil emissivity and surface moisture content. A model which requires the soil hydraulic properties as an additional input, but does not need any weather data was developed. The method is shown to be numerically consistent.

Target-specific nanoparticles containing a broad band emissive NIR dye for the sensitive detection and characterization of tumor development.

PubMed

Behnke, Thomas; Mathejczyk, Julia E; Brehm, Robert; Würth, Christian; Gomes, Fernanda Ramos; Dullin, Christian; Napp, Joanna; Alves, Frauke; Resch-Genger, Ute

2013-01-01

Current optical probes including engineered nanoparticles (NPs) are constructed from near infrared (NIR)-emissive organic dyes with narrow absorption and emission bands and small Stokes shifts prone to aggregation-induced self-quenching. Here, we present the new asymmetric cyanine Itrybe with broad, almost environment-insensitive absorption and emission bands in the diagnostic window, offering a unique flexibility of the choice of excitation and detection wavelengths compared to common NIR dyes. This strongly emissive dye was spectroscopically studied in different solvents and encapsulated into differently sized (15, 25, 100 nm) amino-modified polystyrene NPs (PSNPs) via a one-step staining procedure. As proof-of-concept for its potential for pre-/clinical imaging applications, Itrybe-loaded NPs were surface-functionalized with polyethylene glycol (PEG) and the tumor-targeting antibody Herceptin and their binding specificity to the tumor-specific biomarker HER2 was systematically assessed. Itrybe-loaded NPs display strong fluorescence signals in vitro and in vivo and Herceptin-conjugated NPs bind specifically to HER2 as demonstrated in immunoassays as well as on tumor cells and sections from mouse tumor xenografts in vitro. This demonstrates that our design strategy exploiting broad band-absorbing and -emitting dyes yields versatile and bright NIR probes with a high potential for e.g. the sensitive detection and characterization of tumor development and progression. Copyright © 2012 Elsevier Ltd. All rights reserved.

Photoluminescence studies of a perceived white light emission from a monolithic InGaN/GaN quantum well structure

PubMed Central

Ben Sedrine, N.; Esteves, T. C.; Rodrigues, J.; Rino, L.; Correia, M. R.; Sequeira, M. C.; Neves, A. J.; Alves, E.; Bockowski, M.; Edwards, P. R.; O’Donnell, K. P.; Lorenz, K.; Monteiro, T.

2015-01-01

In this work we demonstrate by photoluminescence studies white light emission from a monolithic InGaN/GaN single quantum well structure grown by metal organic chemical vapour deposition. As-grown and thermally annealed samples at high temperature (1000 °C, 1100 °C and 1200 °C) and high pressure (1.1 GPa) were analysed by spectroscopic techniques, and the annealing effect on the photoluminescence is deeply explored. Under laser excitation of 3.8 eV at room temperature, the as-grown structure exhibits two main emission bands: a yellow band peaked at 2.14 eV and a blue band peaked at 2.8 eV resulting in white light perception. Interestingly, the stability of the white light is preserved after annealing at the lowest temperature (1000 °C), but suppressed for higher temperatures due to a deterioration of the blue quantum well emission. Moreover, the control of the yellow/blue bands intensity ratio, responsible for the white colour coordinate temperatures, could be achieved after annealing at 1000 °C. The room temperature white emission is studied as a function of incident power density, and the correlated colour temperature values are found to be in the warm white range: 3260–4000 K. PMID:26336921

Probing the End of the IMF in NGC 2024 with NIRCam on JWST: Assessing the Impact of Nebular Emission in Galactic Star Forming Regions

NASA Astrophysics Data System (ADS)

Suri, Veenu; Meyer, Michael; Greenbaum, Alexandra Z.; Bell, Cameron; Beichman, Charles; Gordon, Karl D.; Greene, Thomas P.; Hodapp, K.; Horner, Scott; Johnstone, Doug; Leisenring, Jarron; Manara, Carlos; Mann, Rita; Misselt, K.; Raileanu, Roberta; Rieke, Marcia; Roellig, Thomas

2018-01-01

We describe observations of the embedded young cluster associated with the HII region NGC 2024 planned as part of the guaranteed time observing program for the James Webb Space Telescope with the NIRCam (Near Infrared Camera) instrument. Our goal is to obtain a census of the cluster down to 2 Jupiter masses, viewed through 10-20 magnitudes of extinction, using multi-band filter photometry, both broadband filters and intermediate band filters that are expected to be sensitive to temperature and surface gravity. The cluster contains several bright point sources as well as extended emission due to reflected light, thermal emission from warm dust, as well as nebular line emission. We first developed techniques to better understand which point sources would saturate in our target fields when viewed through several JWST NIRCam filters. Using images of the field with the WISE satellite in filters W1 and W2, as well as 2MASS (J and H) bands, we devised an algorithm that takes the K-band magnitudes of point sources in the field, and the known saturation limits of several NIRCam filters to estimate the impact of the extended emission on survey sensitivity. We provide an overview of our anticipated results, detecting the low mass end of the IMF as well as planetary mass objects likely liberated through dynamical interactions.

Atmospheric verification of anthropogenic CO2 emission trends

NASA Astrophysics Data System (ADS)

Francey, Roger J.; Trudinger, Cathy M.; van der Schoot, Marcel; Law, Rachel M.; Krummel, Paul B.; Langenfelds, Ray L.; Paul Steele, L.; Allison, Colin E.; Stavert, Ann R.; Andres, Robert J.; Rödenbeck, Christian

2013-05-01

International efforts to limit global warming and ocean acidification aim to slow the growth of atmospheric CO2, guided primarily by national and industry estimates of production and consumption of fossil fuels. Atmospheric verification of emissions is vital but present global inversion methods are inadequate for this purpose. We demonstrate a clear response in atmospheric CO2 coinciding with a sharp 2010 increase in Asian emissions but show persisting slowing mean CO2 growth from 2002/03. Growth and inter-hemispheric concentration difference during the onset and recovery of the Global Financial Crisis support a previous speculation that the reported 2000-2008 emissions surge is an artefact, most simply explained by a cumulative underestimation (~ 9PgC) of 1994-2007 emissions; in this case, post-2000 emissions would track mid-range of Intergovernmental Panel on Climate Change emission scenarios. An alternative explanation requires changes in the northern terrestrial land sink that offset anthropogenic emission changes. We suggest atmospheric methods to help resolve this ambiguity.

Flow Shears at the Poleward Boundary of Omega Bands Observed During Conjunctions of Swarm and THEMIS ASI

NASA Astrophysics Data System (ADS)

Liu, Jiang; Lyons, L. R.; Archer, W. E.; Gallardo-Lacourt, B.; Nishimura, Y.; Zou, Ying; Gabrielse, C.; Weygand, J. M.

2018-02-01

Omega bands are curved aurora forms that evolve from a quiet arc located along the poleward edge of a diffuse auroral band within the midnight to morningside auroral oval. They usually propagate eastward. Because omega bands are a significant contributor to an active magnetotail, knowledge about their generation is important for understanding tail dynamics. Previous studies have shown that auroral streamers, footprints of fast flows in the tail, can propagate into omega bands. Such events, however, are limited, and it is still unclear whether and how the flows trigger the bands. The ionospheric flows associated with omega bands may provide valuable information on the driving mechanisms of the bands. We examine these flows taking advantage of the conjunctions between the Swarm spacecraft and Time History of Events and Macroscale Interactions during Substorms all-sky imagers, which allow us to demonstrate the relative location of the flows to the omega bands' bright arcs for the first time. We find that a strong eastward ionospheric flow is consistently present immediately poleward of the omega band's bright arc, resulting in a sharp flow shear near the poleward boundary of the band. This ionospheric flow shear should correspond to a flow shear near the inner edge of the plasma sheet. This plasma sheet shear may drive a Kelvin-Helmholz instability which then distorts the quiet arc to form omega bands. It seems plausible that the strong eastward flows are driven by streamer-related fast flows or enhanced convection in the magnetotail.

Rare Earth Garnet Selective Emitter

NASA Technical Reports Server (NTRS)

Lowe, Roland A.; Chubb, Donald L.; Farmer, Serene C.; Good, Brian S.

1994-01-01

Thin film Ho-YAG and Er-YAG emitters with a platinum substrate exhibit high spectral emittance in the emission band (epsilon(sub lambda) approx. = 0.75, sup 4)|(sub 15/2) - (sup 4)|(sub 13/2),for Er-YAG and epsilon(sub lambda) approx. = 0.65, (sup 5)|(sub 7) - (sup 5)|(sub 8) for Ho-YAG) at 1500 K. In addition, low out-of-band spectral emittance, epsilon(sub lambda) less than 0.2, suggest these materials would be excellent candidates for high efficiency selective emitters in thermophotovoltaic (TPV) systems operating at moderate temperatures (1200-1500 K). Spectral emittance measurements of the thin films were made (1.2 less than lambda less than 3.0 microns) and compared to the theoretical emittances calculated using measured values of the spectral extinction coefficient. In this paper we present the results for a new class of rare earth ion selective emitters. These emitters are thin sections (less than 1 mm) of yttrium aluminum garnet (YAG) single crystal with a rare earth substitutional impurity. Selective emitters in the near IR are of special interest for thermophotovoltaic (TPV) energy conversion. The most promising solid selective emitters for use in a TPV system are rare earth oxides. Early spectral emittance work on rare earth oxides showed strong emission bands in the infrared (0.9 - 3 microns). However, the emittance outside the emission band was also significant and the efficiency of these emitters was low. Recent improvements in efficiency have been made with emitters fabricated from fine (5 - 10 microns) rare earth oxide fibers similar to the Welsbach mantle used in gas lanterns. However, the rare earth garnet emitters are more rugged than the mantle type emitters. A thin film selective emitter on a low emissivity substrate such as gold, platinum etc., is rugged and easily adapted to a wide variety of thermal sources. The garnet structure and its many subgroups have been successfully used as hosts for rare earth ions, introduced as substitutional impurities, in the development of solid state laser crystals. Doping, dependent on the particular ion and crystal structure, may be as high as 100 at. % (complete substitution of yttrium ion with the rare earth ion). These materials have high melting points, 1940 C for YAG (Yttrium Aluminum Garnet), and low emissivity in the near infrared making them excellent candidates for a thin film selective emitter. As previously stated, the spectral emittance of a rare earth emitter is characterized by one or more well defined emission bands. Outside the emission band the emittance(absorptance) is much lower. Therefore, it is expected that emission outside the band for a thin film selective emitter will be dominated by the emitter substrate. For an efficient emitter (power in the emission band/total emitted power) the substrate must have low emittance, epsilon(sub S). This paper presents normal spectral emittance, epsilon(sub lambda), measurements of holmium(Ho) and erbium (Er) doped YAG thin film selective emitters at (1500 K), and compares those results with the theoretical spectral emittance.

Martian atmospheric radiation budget

NASA Technical Reports Server (NTRS)

Lindner, Bernhard Lee

1994-01-01

A computer model is used to study the radiative transfer of the martian winter-polar atmosphere. Solar heating at winter-polar latitudes is provided predominately by dust. For normal, low-dust conditions, CO2 provides almost as much heating as dust. Most heating by CO2 in the winter polar atmosphere is provided by the 2.7 micron band between 10 km and 30 km altitude, and by the 2.0 micron band below 10 km. The weak 1.3 micron band provides some significant heating near the surface. The minor CO2 bands at 1.4, 1.6, 4.8 and 5.2 micron are all optically thin, and produce negligible heating. O3 provides less than 10 percent of the total heating. Atmospheric cooling is predominantly thermal emission by dust, although CO2 15 micron band emission is important above 20 km altitude.

Identification of the UV nightglow from Venus

NASA Technical Reports Server (NTRS)

Feldman, P. D.; Moos, H. W.; Clarke, J. T.; Lane, A. L.

1979-01-01

Observations of atmospheric ultraviolet emission between 1350 and 2200 A from the night side of Venus, made by the International Ultraviolet Explorer (IUE), are reported. Low dispersion spectra taken by the short and long wavelength IUE spectrographs clearly show the (0,0) band of the NO delta system at 1909 A; the delta (0,1) band at 1980 A and the delta (0,2) band are indicated, while the (2,0) Cameron band of CO at 1928 A does not seem to be present. The relative band intensities appear to be the same as in earth airglow, where the excitation mechanism has been identified as radiative association of O and N atoms. The column emission rate of 0.5 kR implies a larger N to O ratio in the atmosphere of Venus than in that of the earth.

Localized-Surface-Plasmon Enhanced the 357 nm Forward Emission from ZnMgO Films Capped by Pt Nanoparticles

PubMed Central

2009-01-01

The Pt nanoparticles (NPs), which posses the wider tunable localized-surface-plasmon (LSP) energy varying from deep ultraviolet to visible region depending on their morphology, were prepared by annealing Pt thin films with different initial mass-thicknesses. A sixfold enhancement of the 357 nm forward emission of ZnMgO was observed after capping with Pt NPs, which is due to the resonance coupling between the LSP of Pt NPs and the band-gap emission of ZnMgO. The other factors affecting the ultraviolet emission of ZnMgO, such as emission from Pt itself and light multi-scattering at the interface, were also discussed. These results indicate that Pt NPs can be used to enhance the ultraviolet emission through the LSP coupling for various wide band-gap semiconductors. PMID:20596433

Polarized Gamma-Ray Emission from the Galactic Black Hole Cygnus X-1

NASA Technical Reports Server (NTRS)

Laurent, P.; Rodriquez, J.; Wilms, J.; Bel, M. Cadolle; Pottschmidt, K.; Grinberg, V.

2011-01-01

Because of their inherently high flux allowing the detection of clear signals, black hole X-ray binaries are interesting candidates for polarization studies, even if no polarization signals have been observed from them before. Such measurements would provide further detailed insight into these sources' emission mechanisms. We measured the polarization of the gamma-ray emission from the black hole binary system Cygnus X-I with the INTEGRAL/IBIS telescope. Spectral modeling ofthe data reveals two emission mechanisms: The 250-400 keY data are consistent with emission dominated by Compton scattering on thermal electrons and are weakly polarized. The second spectral component seen in the 400keV-2MeV band is by contrast strongly polarized, revealing that the MeV emission is probably related to the jet first detected in the radio band.

Mars, Venus, Earth and Titan UV Laboratory Aeronomy by Electron Impact

NASA Astrophysics Data System (ADS)

Malone, C. P.; Ajello, J. M.; McClintock, W. E.; Eastes, R.; Evans, J. S.; Holsclaw, G.; Schneider, N. M.; Jain, S.; Gerard, J. C. M. C.; Hoskins, A.

2017-12-01

The UV response of the Mars, Earth, Titan and Venus upper atmospheres to the solar radiation fields [solar wind and solar EUV] is the focus of the present generation of Mars, Earth, Titan and Venus missions. These missions are Mars Express (MEX), the Mars Atmosphere and Volatile Evolution Mission (MAVEN), Cassini at Titan, Global-scale Observations of the Limb and Disk (GOLD) mission for Earth and Venus Express (VEX). Each spacecraft is equipped with a UV spectrometer that senses far ultraviolet (FUV) emissions from 110-190 nm, whose dayglow intensities are proportional to three quantities:1) particle (electron, ion) fluxes, 2) the altitude distribution of species in the ionosphere: CO, CO2, O, N2 at Venus and Mars and N2, O and O2 at Titan and Earth and 3) the emission cross section for the interaction process. UV spectroscopy provides a benchmark to the present space environment and indicates pathways for removing upper atmosphere gas (e.g., water escape from Mars and Earth) or N2 escape at Titan over eons. We present a UV laboratory program that utilizes an instrument, unique in the world, at the University of Colorado that can measure excitation mechanisms by particle (electron, ion) impact and the resulting emission cross sections that include processes occurring in a planetary atmosphere, particularly the optically forbidden emissions presented by the Cameron bands, the Lyman Birge Hopfield bands and the OI 135.6 nm multiplet. There are presently uncertainties by a factor of two in the existing measurements of the emission cross section, affecting modeling of electron transport. We have utilized the MAVEN Imaging Ultraviolet Spectrograph (IUVS) engineering model which operates at moderate spectral resolution ( 0.5-1.0nm FWHM) to obtain the full vibrational spectra of the Cameron band system CO(a 3Π → X 1Σ+) from both CO direct excitation and CO2 dissociative excitation, and for the dipole-allowed Fourth Positive band system of CO, while for N2 we have studied molecular nitrogen (N2 LBH bands, a 1Πg → X 1Σg+). We have performed laboratory measurements using mono-energetic electrons in a large chamber to excite band systems by the same processes as occur at low densities in planetary atmospheres. We have ascertained vibrational structure and emission cross sections for the strongest band systems on solar system objects.

Aluminum speciation in aqueous fluids at deep crustal pressure and temperature

NASA Astrophysics Data System (ADS)

Mookherjee, Mainak; Keppler, Hans; Manning, Craig E.

2014-05-01

We investigated aluminum speciation in aqueous fluids in equilibrium with corundum using in situ Raman spectroscopy in hydrothermal diamond anvil cells to 20 kbar and 1000 °C. We have studied aluminum species in (a) pure H2O, (b) 5.3 m KOH solution, and (c) 1 m KOH solution. In order to better understand the spectral features of the aqueous fluids, we used ab initio simulations based on density functional theory to calculate and predict the energetics and vibrational spectra for various aluminum species that are likely to be present in aqueous solutions. The Raman spectra of pure water in equilibrium with Al2O3 are devoid of any characteristic spectral features. In contrast, aqueous fluids with 5.3 m and 1 m KOH solution in equilibrium with Al2O3 show a sharp band at ˜620 cm-1 which could be attributed to the [ species. The band grows in intensity with temperature along an isochore. A shoulder on the high-frequency side of this band may be due to a hydrated, charge neutral Al(OH)3·H2O species. In the limited pressure, temperature and density explored in the present study, we do not find any evidence for the polymerization of the [ species to dimers [(OH)2-Al-(OH)2-Al(OH)2] or [(OH)3-Al-O-Al(OH)3]2-. This is likely due to the relatively low concentration of Al in the solutions and does not rule out significant polymerization at higher pressures and temperatures. Upon cooling of Al-bearing solutions to room temperatures, Raman bands indicating the precipitation of diaspore (AlOOH) were observed in some experiments. The Raman spectra of the KOH solutions (with or without dissolved alumina) showed a sharp OH stretching band at ˜3614 cm-1 and an in-plane OH bending vibration at ˜1068 cm-1, likely related to an OH- ion with the oxygen atom attached to a water molecule by hydrogen bonding. A weak feature at ˜935 cm-1 may be related to the out-of-plane bending vibration of the same species or to an OH species with a different environment.

Influence of Tl+ activator ions on the luminescence characteristics of KCl0.5Br0.5:Eu2+ powder phosphors.

PubMed

Nagarajan, S; Sudarkodi, R

2009-01-01

Photoluminescence (PL) of thallium co-doped with KCl0.5Br0.5:Eu2+ powder phosphors display emission bands at 320 and 370 nm attributable to centres involving Tl+ ions in addition to characteristic Eu2+ emission around 420 nm. Additional PL excitation and emission bandS observed around 260 and 380 nm, respectively, were observed in the double-doped KCl0.5Br0.5:Eu2+, Tl+ powder phosphors and are attributed to complex centres involving Tl+ and Eu2+ ions. The enhancement observed in the intensity of Eu2+ emission around 420 nm with the addition of TlBr in KCl0.5Br0.5:Eu2+ powder phosphors is attributed to the energy transfer from Tl+ --> Eu2+ ions. Photostimulated luminescence (PSL) studies of gamma-irradiated KCl0.5Br0.5:Eu2+, Tl+ mixed phosphors are reported and a tentative PSL mechanism in the phosphors has been suggested.

Evaluation of Mobile Phone Interference With Aircraft GPS Navigation Systems

NASA Technical Reports Server (NTRS)

Pace, Scott; Oria, A. J.; Guckian, Paul; Nguyen, Truong X.

2004-01-01

This report compiles and analyzes tests that were conducted to measure cell phone spurious emissions in the Global Positioning System (GPS) radio frequency band that could affect the navigation system of an aircraft. The cell phone in question had, as reported to the FAA (Federal Aviation Administration), caused interference to several GPS receivers on-board a small single engine aircraft despite being compliant with data filed at the time with the FCC by the manufacturer. NASA (National Aeronautics and Space Administration) and industry tests show that while there is an emission in the 1575 MHz GPS band due to a specific combination of amplifier output impedance and load impedance that induces instability in the power amplifier, these spurious emissions (i.e., not the intentional transmit signal) are similar to those measured on non-intentionally transmitting devices such as, for example, laptop computers. Additional testing on a wide sample of different commercial cell phones did not result in any emission in the 1575 MHz GPS Band above the noise floor of the measurement receiver.

Sensible Ozone on Mars based on 2-D Maps of O 2(a 1△ g) Emission for L s=102° Comparison of (0,0) and (1,1) Bands

NASA Astrophysics Data System (ADS)

Novak, Robert E.; Mumma, Michael J.; Villanueva, Geronimo Luis

2016-10-01

We report 2-D maps of the O2(a1△g) emission rate (a tracer for high-altitude ozone) taken during early northern summer (Ls=102° on 30 January 2016) using CSHELL at NASA's IRTF. The entrance slit of the spectrometer was positioned N-S on Mars and stepped E-W at 0.5 arc-sec increments. Spectral extracts were taken at 0.6 arc-sec intervals along the slit. We also took data to compare the emission rates of the O2(a1△g) (1-1) band (1.28 μm) to the (0-0) band (1.27 μm) with the entrance slit centered at the sub-Earth point. A model consisting of the solar continuum with Fraunhofer lines, two-way transmission through Mars' atmosphere, and a one-way transmission through the Earth's atmosphere was used to isolate and analyze individual spectral emission lines from Mars. Boltzmann analysis of these lines yielded a rotational temperature (~165 K) that was used to determine the total emission rates for the a-X system from the measured line intensities. The line-of-sight emission rates were converted to vertical emission rates and O2(a1△g) column densities after geometric correction. The sensible O3 column implied by these data is compared with maps of total O3 in Mars standard atmosphere models.The 2-D map shows increased emission in the southern hemisphere when compared to previously reported results taken at earlier seasonal points (Ls=72° on 3 April 2010 and Ls=88° on 10 February 2014). Emission results of the O2(a1△g) (0-0) band (Local Time ~ 14:30) will be compared with MARCI results (LT ~ 15:00, Clancy et al., Icarus 266 (2016) 112-113). We searched for the (1-1) band in two adjacent wavelength ranges; (0-0) emissions were detected at these settings, but no (1-1) emissions were noticed above the noise level. An upper limit will be presented, and implications discussed.This work was partially funded by grants from NASA's Mars Fundamental Research Program (11-MFRP11-0066) and the NSF-RUI Program (AST-805540). The NASA Astrobiology Institute supported this work through funding awarded to the Goddard Center for Astrobiology under proposal 13-13NAI7-0032. We thank the administration and staff of the NASA-IRTF for awarding observing times and coordinating our observations.

Excitation-Power Dependence of the Near Band-Edge PL Spectra of CdMnTe with High Mn Concentrations

NASA Astrophysics Data System (ADS)

Hwang, Younghun; Um, Youngho; Park, Hyoyeol

2011-12-01

Temperature and excitation power dependences of photoluminescence (PL) measurements were studied for the CdMnTe crystal grown by the vertical Bridgman method. The near band-edge and intra-Mn2+ emissions were investigated as a function of temperature. The observed band-edge peak of the PL spectrum showed a clear blue-shift with decreasing temperature. However, the peak energy of the intra-Mn2+ transition did not decrease monotonically with changing temperature, as can be seen above 70 K. With increasing the excitation power, the intensity of the emission peak was increased.

Sensitivity of Heterointerfaces on Emission Wavelength in Quantum Cascade Lasers

DTIC Science & Technology

2016-08-18

sharp satellite peaks and highly resolved thickness interference fringes. The full-width at 4 half-maximum of the n=0 peak is nominally similar... Watanabe , M. Sugiyama, and Y. Nakano, "Effect of hetero-interfaces on in situ wafer curvature behavior in InGaAs/GaAsP strain-balanced MQWs

Sensitivity of Heterointerfaces on Emission Wavelength in Quantum Cascade Lasers

DTIC Science & Technology

2016-10-31

as expected, and all scans exhibit sharp satellite peaks and highly resolved thickness interference fringes. The full- width at half-maximum of the n...K. Watanabe , M. Sugiyama, and Y. Nakano, "Effect of hetero-interfaces on in situ wafer curvature behavior in InGaAs/GaAsP strain-balanced MQWs

The PAH Emission Characteristics of the Reflection Nebula NGC 2023

NASA Astrophysics Data System (ADS)

Peeters, Els; Bauschlicher, Charles W., Jr.; Allamandola, Louis J.; Tielens, Alexander G. G. M.; Ricca, Alessandra; Wolfire, Mark G.

2017-02-01

We present 5-20 μm spectral maps of the reflection nebula NGC 2023 obtained with the Infrared Spectrograph SL and SH modes on board the Spitzer Space Telescope, which reveal emission from polycyclic aromatic hydrocarbons (PAHs), C60, and H2 superposed on a dust continuum. We show that several PAH emission bands correlate with each other and exhibit distinct spatial distributions that reveal a spatial sequence with distance from the illuminating star. We explore the distinct morphology of the 6.2, 7.7, and 8.6 μm PAH bands and find that at least two spatially distinct components contribute to the 7-9 μm PAH emission in NGC 2023. We report that the PAH features behave independently of the underlying plateaus. We present spectra of compact, oval PAHs ranging in size from C66 to C210, determined computationally using density functional theory, and we investigate trends in the band positions and relative intensities as a function of PAH size, charge, and geometry. Based on the NASA Ames PAH database, we discuss the 7-9 μm components in terms of band assignments and relative intensities. We assign the plateau emission to very small grains with possible contributions from PAH clusters and identify components in the 7-9 μm emission that likely originate in these structures. Based on the assignments and the observed spatial sequence, we discuss the photochemical evolution of the interstellar PAH family as the PAHs are more and more exposed to the radiation field of the central star in the evaporative flows associated with the Photo-Dissociation Regions in NGC 2023.

Mid infrared emission spectroscopy of carbon plasma.

PubMed

Nemes, Laszlo; Brown, Ei Ei; S-C Yang, Clayton; Hommerich, Uwe

2017-01-05

Mid infrared time-resolved emission spectra were recorded from laser-induced carbon plasma. These spectra constitute the first study of carbon materials LIB spectroscopy in the mid infrared range. The carbon plasma was induced using a Q-switched Nd: YAG laser. The laser beam was focused to high purity graphite pellets mounted on a translation stage. Mid infrared emission from the plasma in an atmospheric pressure background gas was detected by a cooled HgCdTe detector in the range 4.4-11.6μm, using long-pass filters. LIB spectra were taken in argon, helium and also in air. Despite a gate delay of 10μs was used there were strong backgrounds in the spectra. Superimposed on this background broad and noisy emission bands were observed, the form and position of which depended somewhat on the ambient gas. The spectra were digitally smoothed and background corrected. In argon, for instance, strong bands were observed around 4.8, 6.0 and 7.5μm. Using atomic spectral data by NIST it could be concluded that carbon, argon, helium and nitrogen lines from neutral and ionized atoms are very weak in this spectral region. The width of the infrared bands supports molecular origin. The infrared emission bands were thus compared to vibrational features of carbon molecules (excluding C2) of various sizes on the basis of previous carbon cluster infrared absorption and emission spectroscopic analyses in the literature and quantum chemical calculations. Some general considerations are given about the present results. Copyright © 2016 Elsevier B.V. All rights reserved.

GeV Outbursts in Mrk 501

NASA Technical Reports Server (NTRS)

Sreekumar, P.; Bertsch, D. L.; Bloom, S. D.; Hartman, R. C.; Lin, Y. C.; Mukherjee, R.; Thompson, D. J.

1999-01-01

Mrk 501 is the third TeV blazar with a known GeV component. Previous multiwavelength campaigns on Mrk 501 showed well correlated outbursts at x-ray and TeV energies with no significant activity at GeV energies. We present here new evidence suggesting GeV outbursts in Mrk 501 when the spectrum appears to be extremely hard. However, this outburst appears uncorrelated with emission at x-ray energies. The resulting spectral energy distribution suggests a sharp cut off in the high-energy emission beyond a few hundred GeV.

Control of spontaneous emission from a microwave-field-driven four-level atom in an anisotropic photonic crystal

NASA Astrophysics Data System (ADS)

Zhang, Duo; Li, Jiahua; Ding, Chunling; Yang, Xiaoxue

2012-05-01

The spontaneous emission properties of a microwave-field-driven four-level atom embedded in anisotropic double-band photonic crystals (PCs) are investigated. We discuss the influences of the band-edge positions, Rabi frequency and detuning of the microwave field on the emission spectrum. It is found that several interesting features such as spectral-line enhancement, spectral-line suppression, spectral-line overlap, and multi-peak structures can be observed in the spectra. The proposed scheme can be achieved by use of a microwave-coupled field into hyperfine levels in rubidium atom confined in a photonic crystal. These theoretical investigations may provide more degrees of freedom to manipulate the atomic spontaneous emission.

On the origin of blue emission from ZnO quantum dots synthesized by a sol-gel route

NASA Astrophysics Data System (ADS)

Han, Li-Li; Cui, Lan; Wang, Wei-Hua; Wang, Jiang-Long; Du, Xi-Wen

2012-06-01

ZnO quantum dots (QDs) with blue emission were synthesized by a sol-gel method. A series of control experiments were conducted to explore the origin of the blue emission. It is found that the blue emission arises from neither the quantum confinement nor intermediate products, and it can be achieved only in the presence of Li+ cations and excessive OH- anions. Moreover, the long decay time of the blue emission suggests a defect-related de-excitation process. On the basis of the experimental and calculation results, possible de-excitation paths for light emission were discussed, and the origin of the blue emission was determined as the electron transition from the conduction band to interstitial oxygen defects. Excessive OH- anions are responsible for the formation of interstitial oxygen defects, and Li+ ions can stabilize the defects by substituting for Zn atoms. Besides, Li+ ions can block the growth of ZnO QDs, broaden their band gap and cause a blue shift of the blue emission.

Monitoring the Near-infrared Volcanic Flux from Io's Jupiter-facing Hemisphere from Fan Mountain Observatory

NASA Astrophysics Data System (ADS)

Skrutskie, Michael F.; Nelson, Matthew J.; Schmidt, Carl

2016-10-01

Fan Mountain Observatory, near Charlottesville, Virginia, is a dark-sky site that supports a number of telescopes including a 31-inch reflecting telescope equipped with a 1024x1024 HgCdTe 1-2.5 um (YJHK) imager. Reflected sunlight ordinarily overwhelms Io's comparatively weak K-band (2.0-2.4 um) volcanic emission in unresolved observations, however when Io is eclipsed in Jupiter's shadow even a small infrared-equipped telescope can detect Io's volcanic emission. The Fan Mountain Infrared Camera observed Io in eclipse at regular intervals, typically weekly, during the few months before and after Jupiter's March 2016 opposition. When in eclipse Io's Jupiter-facing hemisphere is oriented toward Earth with sub-Earth longitudes at the time of observation ranging from 345 - 360 degrees (pre-opposition) to 0 - 15 degrees (post-opposition). A K-band filter (2.04-2.42 um) provided a bulk measurement of Io's volcanic flux weighted largely toward the 2.4 um end of this filter given the typical 500K color temperature of the volcanic emission. Most epochs also included observation in a narrowband filter centered at 2.12 um that, when combined with the broadband "long" wavelength measurement, provided a proxy for color temperature. The K-band flux of Io varied by more than 2 magnitudes during the 7 month observation interval. The [2.12 um - K-band] color of the emission strongly correlated with the K-band flux in the expected sense that the color temperature of the emission increased when Io's broadband volcanic flux was the greatest. One epoch of TripleSpec near-IR Io eclipse spectroscopy (0.90 - 2.45 um; R~3000) from the Apache Point Observatory 3.5-meter telescope provided ground truth for transforming the filter photometry into quantitative temperatures.

The ALMA Spectroscopic Survey in the Hubble Ultra Deep Field: Implications for Spectral Line Intensity Mapping at Millimeter Wavelengths and CMB Spectral Distortions

NASA Astrophysics Data System (ADS)

Carilli, C. L.; Chluba, J.; Decarli, R.; Walter, F.; Aravena, M.; Wagg, J.; Popping, G.; Cortes, P.; Hodge, J.; Weiss, A.; Bertoldi, F.; Riechers, D.

2016-12-01

We present direct estimates of the mean sky brightness temperature in observing bands around 99 and 242 GHz due to line emission from distant galaxies. These values are calculated from the summed line emission observed in a blind, deep survey for spectral line emission from high redshift galaxies using ALMA (the ALMA spectral deep field observations “ASPECS” survey). In the 99 GHz band, the mean brightness will be dominated by rotational transitions of CO from intermediate and high redshift galaxies. In the 242 GHz band, the emission could be a combination of higher order CO lines, and possibly [C II] 158 μm line emission from very high redshift galaxies (z ˜ 6-7). The mean line surface brightness is a quantity that is relevant to measurements of spectral distortions of the cosmic microwave background, and as a potential tool for studying large-scale structures in the early universe using intensity mapping. While the cosmic volume and the number of detections are admittedly small, this pilot survey provides a direct measure of the mean line surface brightness, independent of conversion factors, excitation, or other galaxy formation model assumptions. The mean surface brightness in the 99 GHZ band is: T B = 0.94 ± 0.09 μK. In the 242 GHz band, the mean brightness is: T B = 0.55 ± 0.033 μK. These should be interpreted as lower limits on the average sky signal, since we only include lines detected individually in the blind survey, while in a low resolution intensity mapping experiment, there will also be the summed contribution from lower luminosity galaxies that cannot be detected individually in the current blind survey.

SPECTRAL LINE SURVEY TOWARD THE YOUNG MASSIVE PROTOSTAR NGC 2264 CMM3 IN THE 4 mm, 3 mm, AND 0.8 mm BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watanabe, Yoshimasa; Sakai, Nami; López-Sepulcre, Ana

2015-08-20

Spectral line survey observations are conducted toward the high-mass protostar candidate NGC 2264 CMM3 in the 4, 3, and 0.8 mm bands with the Nobeyama 45 m telescope and the Atacama Submillimeter Telescope Experiment (ASTE) 10 m telescope. In total, 265 emission lines are detected in the 4 and 3 mm bands, and 74 emission lines in the 0.8 mm band. As a result, 36 molecular species and 30 isotopologues are identified. In addition to the fundamental molecular species, many emission lines of carbon-chain molecules such as HC{sub 5}N, C{sub 4}H, CCS, and C{sub 3}S are detected in the 4more » and 3 mm bands. Deuterated molecular species are also detected with relatively strong intensities. On the other hand, emission lines of complex organic molecules such as HCOOCH{sub 3} and CH{sub 3}OCH{sub 3} are found to be weak. For the molecules for which multiple transitions are detected, rotation temperatures are derived to be 7–33 K except for CH{sub 3}OH. Emission lines with high upper-state energies (E{sub u} > 150 K) are detected for CH{sub 3}OH, indicating the existence of a hot core. In comparison with the chemical composition of the Orion KL, carbon-chain molecules and deuterated molecules are found to be abundant in NGC 2264 CMM3, while sulfur-bearing species and complex organic molecules are deficient. These characteristics indicate the chemical youth of NGC 2264 CMM3 in spite of its location at the center of the cluster forming core, NGC 2264 C.« less

Defect induced structural inhomogeneity, ultraviolet light emission and near-band-edge photoluminescence broadening in degenerate In 2 O 3 nanowires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukherjee, Souvik; Sarkar, Ketaki; Wiederrecht, Gary P.

We demonstrate here defect induced changes on the morphology and surface properties of indium oxide (In2O3) nanowires and further study their effects on the near-band-edge (NBE) emission, thereby showing the significant influence of surface states on In2O3 nanostructure based device characteristics for potential optoelectronic applications. In2O3 nanowires with cubic crystal structure (c-In2O3) were synthesized via carbothermal reduction technique using a gold-catalyst-assisted vapor–liquid–solid method. Onset of strong optical absorption could be observed at energies greater than 3.5 eV consistent with highly n-type characteristics due to unintentional doping from oxygen vacancy (VO) defects as confirmed using Raman spectroscopy. A combination of highmore » resolution transmission electron microscopy, x-ray photoelectron spectroscopy and valence band analysis on the nanowire morphology and stoichiometry reveals presence of high-density of VO defects on the surface of the nanowires. As a result, chemisorbed oxygen species can be observed leading to upward band bending at the surface which corresponds to a smaller valence band offset of 2.15 eV. Temperature dependent photoluminescence (PL) spectroscopy was used to study the nature of the defect states and the influence of the surface states on the electronic band structure and NBE emission has been discussed. Our data reveals significant broadening of the NBE PL peak consistent with impurity band broadening leading to band-tailing effect from heavy doping.« less

Defect induced structural inhomogeneity, ultraviolet light emission and near-band-edge photoluminescence broadening in degenerate In2O3 nanowires.

PubMed

Mukherjee, Souvik; Sarkar, Ketaki; Wiederrecht, Gary P; Schaller, Richard D; Gosztola, David J; Stroscio, Michael A; Dutta, Mitra

2018-04-27

We demonstrate here defect induced changes on the morphology and surface properties of indium oxide (In 2 O 3 ) nanowires and further study their effects on the near-band-edge (NBE) emission, thereby showing the significant influence of surface states on In 2 O 3 nanostructure based device characteristics for potential optoelectronic applications. In 2 O 3 nanowires with cubic crystal structure (c-In 2 O 3 ) were synthesized via carbothermal reduction technique using a gold-catalyst-assisted vapor-liquid-solid method. Onset of strong optical absorption could be observed at energies greater than 3.5 eV consistent with highly n-type characteristics due to unintentional doping from oxygen vacancy [Formula: see text] defects as confirmed using Raman spectroscopy. A combination of high resolution transmission electron microscopy, x-ray photoelectron spectroscopy and valence band analysis on the nanowire morphology and stoichiometry reveals presence of high-density of [Formula: see text] defects on the surface of the nanowires. As a result, chemisorbed oxygen species can be observed leading to upward band bending at the surface which corresponds to a smaller valence band offset of 2.15 eV. Temperature dependent photoluminescence (PL) spectroscopy was used to study the nature of the defect states and the influence of the surface states on the electronic band structure and NBE emission has been discussed. Our data reveals significant broadening of the NBE PL peak consistent with impurity band broadening leading to band-tailing effect from heavy doping.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fares, Hssen, E-mail: fares.hssen@gmail.com; Férid, Mokhtar; Elhouichet, Habib, E-mail: habib.elhouichet@fst.rnu.tn

The melt quenching method is used to prepare tellurite glasses co-activated with erbium ions and silver nanoparticles (Ag NPs). The glass samples are characterized by x-ray diffraction, UV-vis-NIR absorption, transmission electron microscopy (TEM) imaging, and photoluminescence spectroscopy. The XRD pattern shows no sharp peak indicating an amorphous nature of the glasses. The presence of Ag NPs is confirmed from TEM micrograph. The absorption spectra reveal not only the peaks due to Er{sup 3+} ions, but also the surface plasmon resonance band of silver NPs in the 510–535 nm range. The J-O model has been applied to the room temperature absorption intensitiesmore » of Er{sup 3+} (4f{sup 11}) transitions to establish the so-called J-O intensity parameters: Ω{sub 2}, Ω{sub 4}, and Ω{sub 6}. The intensity parameters are used to determine the radiative decay rates (emission probabilities of transitions) and branching ratios of the Er{sup 3+} transitions from the excited state J manifolds to the lower-lying J' manifolds. Intensified of 1.53 μm band is obtained for the sample containing 0.5 mol. % of AgNO{sub 3} (Ag0.5 glass) using for excitation a laser operating at 980 nm. The simultaneous influence of the Ag NPs → Er{sup 3+} energy transfer and the contribution of the intensified local field effect due to the silver NPs give origin to the enhancement of both the Photoluminescence (PL) intensity and the PL lifetime relative to the {sup 4}I{sub 13/2} → {sup 4}I{sub 15/2} transition, whereas the quenching is ascribed to the energy transfer from Er{sup 3+} ions to silver NPs. Based on the analysis of the temperature dependence of the PL intensity and decay time, we identified a weak back transfer process from Er to the glass host that makes the quenching of the PL intensity weak. Large magnitudes of calculated emission cross-section (σ{sub e}), effective bandwidth (Δλ{sub eff}), and bandwidth quality factor (FWHM × σ{sub e}) relatives to {sup 4}I{sub 13/2} → {sup 4}I{sub 15/2} transition in Er doped Ag0.5 glass have been shown. They indicate that this glass sample has good prospect as a gain medium applied for 1.53 μm band broad and high-gain erbium-doped fiber amplifiers.« less

[New technique for safe removal of impacted foreign bodies in the upper gastrointestinal tract using reusable variceal "cap" (cup, cap or cylinder)].

PubMed

Chávez Rossell, Miguel

2012-01-01

The ingestion of a foreign body is one of the most common endoscopic emergencies. Foreign bodies in the upper gastrointestinal tract should be extracted as soon as possible to avoid serious complications such as perforation o bleeding. However, removals of foreign bodies with sharp edges are very difficult and can develop complications during their removal. Various devices have therefore been developed to prevent mucosal injury from the sharp edges during endoscopic extraction. We report a new technique for the successful foreign body extraction of upper digestive tract using the cap from six shooter variceal banding reused. We present 17 cases (9 males and 8 females). The types of foreign bodies removed were: chicken bones (n:7), fish bones (n:3), denture prosthesis (n:2), food bolus (n:2), long pin (n:1), golden thumb tack (n: 1) and press-through package (n:1). There were no complications. This new technique is safe and effective. Highlights its advantages: enhanced sight pharyngo esophageal junction, foreign bodies disimpact at that level, food bolus suck, avoid sharp object damage mucosal or scope and decrease time removal.

Disrupting neural activity related to awake-state sharp wave-ripple complexes prevents hippocampal learning.

PubMed

Nokia, Miriam S; Mikkonen, Jarno E; Penttonen, Markku; Wikgren, Jan

2012-01-01

Oscillations in hippocampal local-field potentials (LFPs) reflect the crucial involvement of the hippocampus in memory trace formation: theta (4-8 Hz) oscillations and ripples (~200 Hz) occurring during sharp waves are thought to mediate encoding and consolidation, respectively. During sharp wave-ripple complexes (SPW-Rs), hippocampal cell firing closely follows the pattern that took place during the initial experience, most likely reflecting replay of that event. Disrupting hippocampal ripples using electrical stimulation either during training in awake animals or during sleep after training retards spatial learning. Here, adult rabbits were trained in trace eyeblink conditioning, a hippocampus-dependent associative learning task. A bright light was presented to the animals during the inter-trial interval (ITI), when awake, either during SPW-Rs or irrespective of their neural state. Learning was particularly poor when the light was presented following SPW-Rs. While the light did not disrupt the ripple itself, it elicited a theta-band oscillation, a state that does not usually coincide with SPW-Rs. Thus, it seems that consolidation depends on neuronal activity within and beyond the hippocampus taking place immediately after, but by no means limited to, hippocampal SPW-Rs.

Structural defects and recombination behavior of excited carriers in Cu(In,Ga)Se2 solar cells

NASA Astrophysics Data System (ADS)

Yang, J.; Du, H. W.; Li, Y.; Gao, M.; Wan, Y. Z.; Xu, F.; Ma, Z. Q.

2016-08-01

The carriers' behavior in neutral region (NTR) and space charged region (SCR) of Cu(In,Ga)Se2 thin film based solar cells has been investigated by temperature dependent photoluminescence (PL-T), electroluminescence (EL-T) and current-voltage (IV-T) from 10 to 300 K. PL-T spectra show that three kinds of defects, namely VSe, InCu and (InCu+VCu), are localized within the band gap of NTR and SCR of CIGS layer, corresponding to the energy levels of EC-0.08, EC-0.20 and EC-0.25 eV, respectively. The InCu and (InCu+VCu) deep level defects are non-radiative recombination centers at room temperature. The IV-T and EL-T analysis reveals that the injection modes of electrons from ZnO conduction band into Cu(In,Ga)Se2 layer are tunneling, thermally-excited tunneling and thermionic emission under 10-40, 60-160, and 180-300 K, respectively. At 10-160 K, the electrons tunnel into (InCu+VCu) and Vse defect levels in band gap of SCR and the drifting is involved in the emission bands at 0.96 and 1.07 eV, which is the direct evidence for a tunneling assisted recombination. At 180-300 K, the electrons are directly injected into the Cu(In,Ga)Se2 conduction band, and the emission of 1.13 eV are ascribed to the transitions from the conduction band to the valence band.

Fabrication of silver tips for scanning tunneling microscope induced luminescence.

PubMed

Zhang, C; Gao, B; Chen, L G; Meng, Q S; Yang, H; Zhang, R; Tao, X; Gao, H Y; Liao, Y; Dong, Z C

2011-08-01

We describe a reliable fabrication procedure of silver tips for scanning tunneling microscope (STM) induced luminescence experiments. The tip was first etched electrochemically to yield a sharp cone shape using selected electrolyte solutions and then sputter cleaned in ultrahigh vacuum to remove surface oxidation. The tip status, in particular the tip induced plasmon mode and its emission intensity, can be further tuned through field emission and voltage pulse. The quality of silver tips thus fabricated not only offers atomically resolved STM imaging, but more importantly, also allows us to perform challenging "color" photon mapping with emission spectra taken at each pixel simultaneously during the STM scan under relatively small tunnel currents and relatively short exposure time.

Current from a nano-gap hyperbolic diode using shape-factors: Theory

NASA Astrophysics Data System (ADS)

Jensen, Kevin L.; Shiffler, Donald A.; Peckerar, Martin; Harris, John R.; Petillo, John J.

2017-08-01

Quantum tunneling by field emission from nanoscale features or sharp field emission structures for which the anode-cathode gap is nanometers in scale ("nano diodes") experience strong deviations from the planar image charge lowered tunneling barrier used in the Murphy and Good formulation of the Fowler-Nordheim equation. These deviations alter the prediction of total current from a curved surface. Modifications to the emission barrier are modeled using a hyperbolic (prolate spheroidal) geometry to determine the trajectories along which the Gamow factor in a WKB-like treatment is undertaken; a quadratic equivalent potential is determined, and a method of shape factors is used to evaluate the corrected total current from a protrusion or wedge geometry.

Modelling of mid-infrared interferometric signature of hot exozodiacal dust emission

NASA Astrophysics Data System (ADS)

Kirchschlager, Florian; Wolf, Sebastian; Brunngräber, Robert; Matter, Alexis; Krivov, Alexander V.; Labdon, Aaron

2018-01-01

Hot exozodiacal dust emission was detected in recent surveys around two dozen main-sequence stars at distances of less than 1 au using the H- and K-band interferometry. Due to the high contrast as well as the small angular distance between the circumstellar dust and the star, direct observation of this dust component is challenging. An alternative way to explore the hot exozodiacal dust is provided by mid-infrared interferometry. We analyse the L, M and N bands interferometric signature of this emission in order to find stronger constraints for the properties and the origin of the hot exozodiacal dust. Considering the parameters of nine debris disc systems derived previously, we model the discs in each of these bands. We find that the M band possesses the best conditions to detect hot dust emission, closely followed by L and N bands. The hot dust in three systems - HD 22484 (10 Tau), HD 102647 (β Leo) and HD 177724 (ζ Aql) - shows a strong signal in the visibility functions, which may even allow one to constrain the dust location. In particular, observations in the mid-infrared could help to determine whether the dust piles up at the sublimation radius or is located at radii up to 1 au. In addition, we explore observations of the hot exozodiacal dust with the upcoming mid-infrared interferometer Multi AperTure mid-Infrared SpectroScopic Experiment (MATISSE) at the Very Large Telescope Interferometer.

Light Emission Mechanisms in CuInS 2 Quantum Dots Evaluated by Spectral Electrochemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuhr, Addis S.; Yun, Hyeong Jin; Makarov, Nikolay S.

Luminescent CuInS 2 (CIS) quantum dots (QDs) exhibit highly efficient intragap emission and long, hundreds-of-nanoseconds radiative lifetimes. These spectral properties, distinct from structurally similar II–VI QDs, can be explained by the involvement of intragap defect states containing a localized hole capable of coupling with a conduction band electron for a radiative transition. However, the absolute energies of the intragap and band-edge states, the structure of the emissive defect(s), and the role and origin of nonemissive decay channels still remain poorly understood. Here, we address these questions by applying methods of spectral electrochemistry. Cyclic voltammetry measurements reveal a well-defined intragap statemore » whose redox potential is close to that of the Cu x defect state (where x = 1+ or 2+). The energy offset of this state from the valence band accounts well for the apparent photoluminescence Stokes shift observed in optical spectra. These results provide direct evidence that Cu-related defects serve as emission centers responsible for strong intragap emission from CIS QDs. We then use in situ spectroelectrochemistry to reveal two distinct emission pathways based on the differing oxidation states of Cu defects, which can be controlled by altering QD stoichiometry (1+ for stoichiometric QDs and 2+ for Cu-deficient QDs).« less

Excitation-scanning hyperspectral imaging microscope

PubMed Central

Favreau, Peter F.; Hernandez, Clarissa; Heaster, Tiffany; Alvarez, Diego F.; Rich, Thomas C.; Prabhat, Prashant; Leavesley, Silas J.

2014-01-01

Abstract. Hyperspectral imaging is a versatile tool that has recently been applied to a variety of biomedical applications, notably live-cell and whole-tissue signaling. Traditional hyperspectral imaging approaches filter the fluorescence emission over a broad wavelength range while exciting at a single band. However, these emission-scanning approaches have shown reduced sensitivity due to light attenuation from spectral filtering. Consequently, emission scanning has limited applicability for time-sensitive studies and photosensitive applications. In this work, we have developed an excitation-scanning hyperspectral imaging microscope that overcomes these limitations by providing high transmission with short acquisition times. This is achieved by filtering the fluorescence excitation rather than the emission. We tested the efficacy of the excitation-scanning microscope in a side-by-side comparison with emission scanning for detection of green fluorescent protein (GFP)-expressing endothelial cells in highly autofluorescent lung tissue. Excitation scanning provided higher signal-to-noise characteristics, as well as shorter acquisition times (300  ms/wavelength band with excitation scanning versus 3  s/wavelength band with emission scanning). Excitation scanning also provided higher delineation of nuclear and cell borders, and increased identification of GFP regions in highly autofluorescent tissue. These results demonstrate excitation scanning has utility in a wide range of time-dependent and photosensitive applications. PMID:24727909

Excitation-scanning hyperspectral imaging microscope.

PubMed

Favreau, Peter F; Hernandez, Clarissa; Heaster, Tiffany; Alvarez, Diego F; Rich, Thomas C; Prabhat, Prashant; Leavesley, Silas J

2014-04-01

Hyperspectral imaging is a versatile tool that has recently been applied to a variety of biomedical applications, notably live-cell and whole-tissue signaling. Traditional hyperspectral imaging approaches filter the fluorescence emission over a broad wavelength range while exciting at a single band. However, these emission-scanning approaches have shown reduced sensitivity due to light attenuation from spectral filtering. Consequently, emission scanning has limited applicability for time-sensitive studies and photosensitive applications. In this work, we have developed an excitation-scanning hyperspectral imaging microscope that overcomes these limitations by providing high transmission with short acquisition times. This is achieved by filtering the fluorescence excitation rather than the emission. We tested the efficacy of the excitation-scanning microscope in a side-by-side comparison with emission scanning for detection of green fluorescent protein (GFP)-expressing endothelial cells in highly autofluorescent lung tissue. Excitation scanning provided higher signal-to-noise characteristics, as well as shorter acquisition times (300  ms/wavelength band with excitation scanning versus 3  s/wavelength band with emission scanning). Excitation scanning also provided higher delineation of nuclear and cell borders, and increased identification of GFP regions in highly autofluorescent tissue. These results demonstrate excitation scanning has utility in a wide range of time-dependent and photosensitive applications.

Light Emission Mechanisms in CuInS 2 Quantum Dots Evaluated by Spectral Electrochemistry

DOE PAGES

Fuhr, Addis S.; Yun, Hyeong Jin; Makarov, Nikolay S.; ...

2017-09-07

Luminescent CuInS 2 (CIS) quantum dots (QDs) exhibit highly efficient intragap emission and long, hundreds-of-nanoseconds radiative lifetimes. These spectral properties, distinct from structurally similar II–VI QDs, can be explained by the involvement of intragap defect states containing a localized hole capable of coupling with a conduction band electron for a radiative transition. However, the absolute energies of the intragap and band-edge states, the structure of the emissive defect(s), and the role and origin of nonemissive decay channels still remain poorly understood. Here, we address these questions by applying methods of spectral electrochemistry. Cyclic voltammetry measurements reveal a well-defined intragap statemore » whose redox potential is close to that of the Cu x defect state (where x = 1+ or 2+). The energy offset of this state from the valence band accounts well for the apparent photoluminescence Stokes shift observed in optical spectra. These results provide direct evidence that Cu-related defects serve as emission centers responsible for strong intragap emission from CIS QDs. We then use in situ spectroelectrochemistry to reveal two distinct emission pathways based on the differing oxidation states of Cu defects, which can be controlled by altering QD stoichiometry (1+ for stoichiometric QDs and 2+ for Cu-deficient QDs).« less

A LIGHT CURVE ANALYSIS OF CLASSICAL NOVAE: FREE-FREE EMISSION VERSUS PHOTOSPHERIC EMISSION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hachisu, Izumi; Kato, Mariko, E-mail: hachisu@ea.c.u-tokyo.ac.jp, E-mail: mariko@educ.cc.keio.ac.jp

2015-01-10

We analyzed light curves of seven relatively slower novae, PW Vul, V705 Cas, GQ Mus, RR Pic, V5558 Sgr, HR Del, and V723 Cas, based on an optically thick wind theory of nova outbursts. For fast novae, free-free emission dominates the spectrum in optical bands rather than photospheric emission, and nova optical light curves follow the universal decline law. Faster novae blow stronger winds with larger mass-loss rates. Because the brightness of free-free emission depends directly on the wind mass-loss rate, faster novae show brighter optical maxima. In slower novae, however, we must take into account photospheric emission because of theirmore » lower wind mass-loss rates. We calculated three model light curves of free-free emission, photospheric emission, and their sum for various white dwarf (WD) masses with various chemical compositions of their envelopes and fitted reasonably with observational data of optical, near-IR (NIR), and UV bands. From light curve fittings of the seven novae, we estimated their absolute magnitudes, distances, and WD masses. In PW Vul and V705 Cas, free-free emission still dominates the spectrum in the optical and NIR bands. In the very slow novae, RR Pic, V5558 Sgr, HR Del, and V723 Cas, photospheric emission dominates the spectrum rather than free-free emission, which makes a deviation from the universal decline law. We have confirmed that the absolute brightnesses of our model light curves are consistent with the distance moduli of four classical novae with known distances (GK Per, V603 Aql, RR Pic, and DQ Her). We also discussed the reason why the very slow novae are about ∼1 mag brighter than the proposed maximum magnitude versus rate of decline relation.« less

Impact of Fe doping on the electronic structure of SrTiO3 thin films determined by resonant photoemission

NASA Astrophysics Data System (ADS)

Kubacki, J.; Kajewski, D.; Goraus, J.; Szot, K.; Koehl, A.; Lenser, Ch.; Dittmann, R.; Szade, J.

2018-04-01

Epitaxial thin films of Fe doped SrTiO3 have been studied by the use of resonant photoemission. This technique allowed us to identify contributions of the Fe and Ti originating electronic states to the valence band. Two valence states of iron Fe2+ and Fe3+, detected on the base of x-ray absorption studies spectra, appeared to form quite different contributions to the valence band of SrTiO3. The electronic states within the in-gap region can be attributed to Fe and Ti ions. The Fe2+ originating states which can be connected to the presence of oxygen vacancies form a broad band reaching binding energies of about 0.5 eV below the conduction band, while Fe3+ states form in the gap a sharp feature localized just above the top of the valence band. These structures were also confirmed by calculations performed with the use of the FP-LAPW/APW+lo method including Coulomb correlations within the d shell. It has been shown that Fe doping induced Ti originating states in the energy gap which can be related to the hybridization of Ti and Fe 3d orbitals.

Temperature-dependent optical band gap of the metastable zinc-blende structure [beta]-GaN

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ramirez-Flores, G.; Navarro-Contreras, H.; Lastras-Martinez, A.

1994-09-15

The temperature-dependent (10--300 K) optical band gap [ital E][sub 0]([ital T]) of the epitaxial metastable zinc-blende-structure [beta]-GaN(001)4[times]1 has been determined by modulated photoreflectance and used to interpret low-temperature photoluminescence spectra. [ital E][sub 0] in [beta]-GaN was found to vary from 3.302[plus minus]0.004 eV at 10 K to 3.231[plus minus]0.008 eV at 300 K with a temperature dependence given by [ital E][sub 0]([ital T]) =3.302--6.697[times]10[sup [minus]4][ital T][sup 2]/([ital T]+600) eV. The spin-orbit splitting [Delta][sub 0] in the valence band was determined to be 17[plus minus]1 meV. The oscillations in the photoreflectance spectra were very sharp with a broadening parameter [Gamma] ofmore » only 10 meV at 10 K. The dominant transition observed in temperature-dependent photoluminescence was attributed to radiative recombination between a shallow donor, at [congruent]11 meV below the conduction-band edge and the valence band.« less

Electromagnetic and electrostatic emissions at the cusp-magnetosphere interface during substorms

NASA Technical Reports Server (NTRS)

Curtis, S. A.; Fairfield, D. H.; Wu, C. S.

1979-01-01

Strongly peaked electrostatic emissions near 10.0 kHz and electromagnetic emissions near 0.56 kHz have been observed by the VLF wave detector on board Imp 6 on crossings from the earth's magnetosphere into the polar cusp during the occurrence of large magnetospheric substorms. The electrostatic emissions were observed to be closely confined to the cusp-magnetosphere interface. The electromagnetic emissions were of somewhat broader spatial extent and were seen on higher-latitude field lines within the cusp. Using these plasma wave observations and additional information provided by plasma, magnetometer and particle measurements made simultaneously on Imp 6, theories are constructed to explain each of the two classes of emission. The electromagnetic waves are modeled as whistlers, and the electrostatic waves as electron-cyclotron harmonics. The resulting growth rates predict power spectra similar to those observed for both emission classes. The electrostatic waves may play a significant role via enhanced diffusion in the relaxation of the sharp substorm time cusp-magnetosphere boundary to a more diffuse quiet time boundary.

A Multiwavelength Study of Cygnus X-3

NASA Technical Reports Server (NTRS)

McCollough, M. L; Robinson, C. R.; Zhang, S. N.; Paciesas, W. S.; Harmon, B. A.; Hjellming, R. M.; Rupen, M.; Waltman, E. B.; Foster, R. S.; Ghigo, F. D.

1997-01-01

We present a global comparison of long term observations of the hard X-ray (20-100 keV), soft X-ray (1.5-12 keV), infrared (1-2 micron) and radio (2.25, 8.3 and 15 GHz) bands for the unusual X-ray binary Cygnus X-3. Data were obtained in the hard X-ray band from CGRO/BATSE, in the soft X-ray band from Rossi Xray Timing Explorer (RXTE)/ASM, in the radio band from the Green Bank Interferometer and Ryle Telescope and in the infrared band from various ground based observatories. Radio flares, quenched radio states and quiescent radio emission can all be associated with changes in the hard and soft X-ray intensity. The injection of plasma into the radio jet is directly related to changes in the hard and soft X-ray emission. The infrared observations are examined in the context of these findings.

Laser spectroscopic study of β-estradiol and its monohydrated clusters in a supersonic jet.

PubMed

Morishima, Fumiya; Inokuchi, Yoshiya; Ebata, Takayuki

2012-08-09

The structures of 17β-estradiol (estradiol) and its 1:1 cluster with water have been investigated in supersonic jets. The S(1)-S(0) electronic spectrum of estradiol monomer shows four strong sharp bands in the 35050-35200 cm(-1) region. Ultraviolet-ultraviolet hole-burning (UV-UV HB) and infrared-ultraviolet double-resonance (IR-UV DR) spectra of these bands indicate that they are due to four different conformers of estradiol originating from the different orientation of the OH groups in the A- and D-rings. The addition of water vapor to the sample gas generates four new bands in the 34700-34800 cm(-1) region, which are assigned to the estradiol-H(2)O 1:1 cluster with the A-ring (phenyl ring) OH acting as a hydrogen(H)-bond donor. In addition, we found very weak bands near the origin bands of bare estradiol upon the addition of water vapor. These bands are assigned to the isomers of estradiol-H(2)O 1:1 cluster having an H-bond at the D-ring OH. We determine the conformation of bare estradiol and the structures of its monohydrated clusters with the aid of density functional theory calculation and discuss the relationship between the stability of hydrated clusters and the conformation of estradiol.

High-spin states in 103,105Mo, 103Nb, and the νh11/2 alignment

NASA Astrophysics Data System (ADS)

Hua, H.; Wu, C. Y.; Cline, D.; Hayes, A. B.; Teng, R.; Clark, R. M.; Fallon, P.; Macchiavelli, A. O.; Vetter, K.

2002-06-01

High-spin states in neutron-rich nuclei 103,105Mo,103Nb have been studied using the 238U(α,f) fusion-fission reaction. The deexcitation γ rays were detected by Gammasphere in coincidence with the detection of both fission fragments by the Rochester 4π heavy-ion detector array, CHICO. The measured fission kinematics were used to deduce the masses and velocity vectors for both fission fragments. This allowed Doppler-shift corrections to be applied to the observed γ rays on an event-by-event basis and the origin of γ rays from either fission fragment to be established. With such advantages, the yrast sequences for these nuclei have been extended to the band crossing region. This band crossing is ascribed to the alignment of a pair of h11/2 neutrons, which is supported by the observed blocking effect for the νh11/2 band in 105Mo while there is no evidence for blocking in the alignment measured for either the νd5/2 band in 103Mo or the πg9/2 band in 103Nb. The observed upbend, rather than the sharp backbend seen in the Ru-Pd region, indicates a strong interaction between the ground-state and the aligned h11/2 bands.

Luminescent rare earth vanadate nanoparticles doped with Eu3+ and Bi3 for sensing and imaging applications

NASA Astrophysics Data System (ADS)

Escudero, Alberto; Carrillo-Carrión, Carolina; Zyuzin, Mikhail; Hartmann, Raimo; Ashraf, Sumaira; Parak, Wolfgang J.

2016-03-01

Nanoparticles (NPs) are attracting interest in nanomedicine due to their potential medical applications, ranging from optical biolabels and contrast agents for magnetic resonance imaging to carriers for drug and gene delivery for disease therapy.[1] Rare earth (RE) based nanophosphors exhibit important advantages compared with other available luminescent materials, such as quantum dots and nanostructures functionalized with organic dyes, due to their lower toxicities, photostabilities, high thermal and chemical stabilities, high luminescence quantum yields, and sharp emission bands.[2] Yttrium orthovanadate NPs doped with Eu3+ and Bi3+, functionalized with poly acryl acid (PAA), and excitable by near-ultraviolet light have been synthesized by homogeneous precipitation at 120 °C from solutions of rare earth precursors (yttrium acetylacetonate and europium nitrate), bismuth nitrate, sodium orthovanadate, and PAA, in an ethylene glycol/water mixture. Quasispheres with sizes from 93 to 51 nm were obtained. The as synthesized NPs were already functionalized with PAA. The NPs showed the typical red luminescence of Eu3+, which can be excited with near-UV light through an energy transfer from the vanadate anion. The presence of Bi3+ shifts the maximum of the broad excitation band from 280 nm to 342 nm. This excitation path is much more efficient than the direct excitation of the Eu3+ electronic levels, and results in a much higher luminescence. The NPs can be uptaken by HeLa cells, and are eventually located in the lysosomes after being internalized. Finally, the functionalization with PAA provides -COOH anchors for adding functional ligands of biomedical interest that can be used for sensing applications.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fares, Hssen; Férid, Mokhtar; Elhouichet, Habib, E-mail: habib.elhouichet@fst.rnu.tn

Tellurite glasses doped Er³⁺ ions and containing Silver nanoparticles (Ag NPs) are prepared using melt quenching technique. The nucleation and growth of Ag NPs were controlled by a thermal annealing process. The X-ray diffraction pattern shows no sharp peak indicating an amorphous nature of the glasses. The presence of Ag NPs is confirmed from transmission electron microscopy micrograph. Absorption spectra show typical surface plasmon resonance (SPR) band of Ag NPs within the 510–550 nm range in addition to the distinctive absorption peaks of Er³⁺ ions. The Judd-Ofelt (J-O) intensity parameters, oscillator strengths, spontaneous transition probabilities, branching ratios, and radiative lifetimesmore » were successfully calculated based on the experimental absorption spectrum and the J-O theory. It was found that the presence of silver NPs nucleated and grown during the heat annealing process improves both of the photoluminescence (PL) intensity and the PL lifetime relative to the ⁴I 13/2 → ⁴I 15/2 transition. Optimum PL enhancement was obtained after 10 h of heat-treatment. Such enhancements are mainly attributed to the strong local electric field induced by SPR of silver NPs and also to energy transfer from the surface of silver NPs to Er³⁺ ions, whereas the quenching is ascribed to the energy transfer from Er³⁺ ions to silver NPs. Using the Mc Cumber method, absorption cross-section, calculated emission cross-section, and gain cross-section for the ⁴I 13/2 → ⁴I 15/2 transition were determined and compared for the doped and co-doped glasses. The present results indicate that the glass heat-treated for 10 h has good prospect as a gain medium applied for 1.53 μm band broad and high-gain erbium-doped fiber amplifiers.« less

Structural, optical and magnetic investigation of Gd implanted CeO2 nanocrystals

NASA Astrophysics Data System (ADS)

Kaviyarasu, K.; Murmu, P. P.; Kennedy, J.; Thema, F. T.; Letsholathebe, Douglas; Kotsedi, L.; Maaza, M.

2017-10-01

Gadolinium implanted cerium oxide (Gd-CeO2) nanocomposites is an important candidate which have unique hexagonal structure and high K- dielectric constant. Gd-CeO2 nanoparticles were synthesized using hydrothermal method. X-ray diffraction (XRD) results showed that the peaks are consistent with pure phase cubic structure the XRD pattern also confirmed crystallinity and phase purity of the sample. Nanocrystals sizes were found to be up to 25 nm as revealed by XRD and SEM. It is suggested that Gd gives an affirmative effect on the ion influence behavior of Gd-CeO2. XRD patterns showed formation of new phases and SEM micrographs revealed hexagonal structure. Photoluminescence measurement (PL) reveals the systematic shift of the emission band towards lower wavelength thereby ascertaining the quantum confinement effect (QCE). The PL spectrum has wider broad peak ranging from 390 nm to 770 nm and a sharp one centered on at 451.30 nm which is in tune with Gd ions. In the Raman spectra showed intense band observed between 460 cm-1 and 470 cm-1 which is attributed to oxygen ions into CeO2. Room temperature ferromagnetism was observed in un-doped and Gd implanted and annealed CeO2 nanocrystals. In the recent studies, ceria based materials have been considered as one of the most promising electrolytes for reduced temperature SOFC (solid oxide fuel cell) system due to their high ionic conductivities allowing its use in stainless steel supported fuel cells. CeO2 having an optical bandgap 3.3 eV and n-type carrier density which make it a promising candidate for various technological application such as buffer layer on silicon on insulator devices.

Modeling electron emission and surface effects from diamond cathodes

DOE PAGES

Dimitrov, D. A.; Smithe, D.; Cary, J. R.; ...

2015-02-05

We developed modeling capabilities, within the Vorpal particle-in-cell code, for three-dimensional (3D) simulations of surface effects and electron emission from semiconductor photocathodes. They include calculation of emission probabilities using general, piece-wise continuous, space-time dependent surface potentials, effective mass and band bending field effects. We applied these models, in combination with previously implemented capabilities for modeling charge generation and transport in diamond, to investigate the emission dependence on applied electric field in the range from approximately 2 MV/m to 17 MV/m along the [100] direction. The simulation results were compared to experimental data. For the considered parameter regime, conservation of transversemore » electron momentum (in the plane of the emission surface) allows direct emission from only two (parallel to [100]) of the six equivalent lowest conduction band valleys. When the electron affinity χ is the only parameter varied in the simulations, the value χ = 0.31 eV leads to overall qualitative agreement with the probability of emission deduced from experiments. Including band bending in the simulations improves the agreement with the experimental data, particularly at low applied fields, but not significantly. In this study, using surface potentials with different profiles further allows us to investigate the emission as a function of potential barrier height, width, and vacuum level position. However, adding surface patches with different levels of hydrogenation, modeled with position-dependent electron affinity, leads to the closest agreement with the experimental data.« less

47 CFR 80.207 - Classes of emission.

Code of Federal Regulations, 2014 CFR

2014-10-01

... carrier: (i) In the 1600-4000 kHz band: (A) For coast station transmitters 18±2 dB below peak envelope... envelope power. (ii) In the 4000-27500 kHz band: (A) For coast station transmitters 18±2 dB below peak... emission Ship Stations 1 Radiotelegraphy: 100-160 kHz A1A. 405-525 kHz A1A, J2A. 1615-27500 kHz: Manual 15...

47 CFR 80.207 - Classes of emission.

Code of Federal Regulations, 2011 CFR

2011-10-01

... carrier: (i) In the 1600-4000 kHz band: (A) For coast station transmitters 18±2 dB below peak envelope... envelope power. (ii) In the 4000-27500 kHz band: (A) For coast station transmitters 18±2 dB below peak... emission Ship Stations 1 Radiotelegraphy: 100-160 kHz A1A. 405-525 kHz A1A, J2A. 1615-27500 kHz: Manual 15...

47 CFR 80.207 - Classes of emission.

Code of Federal Regulations, 2010 CFR

2010-10-01

... carrier: (i) In the 1600-4000 kHz band: (A) For coast station transmitters 18±2 dB below peak envelope... envelope power. (ii) In the 4000-27500 kHz band: (A) For coast station transmitters 18±2 dB below peak... emission Ship Stations 1 Radiotelegraphy: 100-160 kHz A1A. 405-525 kHz A1A, J2A. 1615-27500 kHz: Manual 15...

Photovoltaic Performance Enhancement of Silicon Solar Cells Based on Combined Ratios of Three Species of Europium-Doped Phosphors

PubMed Central

You, Bang-Jin; Liu, Jheng-Jie; Bai, Wen-Bin; Syu, Hong-Jhang; Lin, Ching-Fuh

2018-01-01

This paper presents a scheme for the enhancement of silicon solar cells in terms of luminescent emission band and photovoltaic performance. The proposed devices are coated with an luminescent down-shifting (LDS) layer comprising three species of europium (Eu)-doped phosphors mixed within a silicate film (SiO2) using a spin-on film deposition. The three species of phosphor were mixed at ratios of 0.5:1:1.5, 1:1:1, or 1.5:1:0.5 in weight percentage (wt %). The total quantity of Eu-doped phosphors in the silicate solution was fixed at 3 wt %. The emission wavelengths of the Eu-doped phosphors were as follows: 518 nm (specie-A), 551 nm (specie-B), and 609 nm (specie-C). We examined the extended luminescent emission bands via photoluminescence measurements at room temperature. Closely matching the luminescent emission band to the high responsivity band of the silicon semiconductor resulted in good photovoltaic performance. Impressive improvements in efficiency were observed in all three samples: 0.5:1:1.5 (20.43%), 1:1:1 (19.67%), 1.5:1:0.5 (16.81%), compared to the control with a layer of pure SiO2 (13.80%). PMID:29783716

Variability in Comet P/Swift-Tuttle

NASA Technical Reports Server (NTRS)

Schulz, Rita; Mcfadden, Lucy A.; Chamberlin, Alan B.; A'Hearn, Michael F.; Schleicher, David G.

1994-01-01

Spatial profiles of the coma of Comet P/Swift-Tuttle perpendicular to the projected Sun-comet line were obtained for the emission bands of CN, C2, and C3 as well as for two continuum bands from spectrophotometric observations taken from Oct. 5 to 8, 1992. The intensities were converted into emissivities per sq km in the cases of the continua and into column densities for the emission band profiles. Spatial and temporal variabilities have been found in all five investigated components, which are consistent with the rotational period of the nucleus determined from the observations of the comet during its last perihelion passage in 1862. The emission band profiles were fitted with the vectorial model and the production rates of CN, C2, and C3 were determined. One half of the profiles was fitted adequately under steady state conditions for the production rate in a first approximation, whereas the other half showed prominent bumps, which could only be explained by introducing a time-dependent production rate. Further investigations showed evidence for the presence of gaseous as well as dust jets in the coma, which indicated the presence of at least two active areas on the surface of the nucleus. The projected radial expansion velocities of two different features were determined to be (430 +/- 100) and (460 +/- 100) m/sec, respectively.

High-performance field emission device utilizing vertically aligned carbon nanotubes-based pillar architectures

NASA Astrophysics Data System (ADS)

Gupta, Bipin Kumar; Kedawat, Garima; Gangwar, Amit Kumar; Nagpal, Kanika; Kashyap, Pradeep Kumar; Srivastava, Shubhda; Singh, Satbir; Kumar, Pawan; Suryawanshi, Sachin R.; Seo, Deok Min; Tripathi, Prashant; More, Mahendra A.; Srivastava, O. N.; Hahm, Myung Gwan; Late, Dattatray J.

2018-01-01

The vertical aligned carbon nanotubes (CNTs)-based pillar architectures were created on laminated silicon oxide/silicon (SiO2/Si) wafer substrate at 775 °C by using water-assisted chemical vapor deposition under low pressure process condition. The lamination was carried out by aluminum (Al, 10.0 nm thickness) as a barrier layer and iron (Fe, 1.5 nm thickness) as a catalyst precursor layer sequentially on a silicon wafer substrate. Scanning electron microscope (SEM) images show that synthesized CNTs are vertically aligned and uniformly distributed with a high density. The CNTs have approximately 2-30 walls with an inner diameter of 3-8 nm. Raman spectrum analysis shows G-band at 1580 cm-1 and D-band at 1340 cm-1. The G-band is higher than D-band, which indicates that CNTs are highly graphitized. The field emission analysis of the CNTs revealed high field emission current density (4mA/cm2 at 1.2V/μm), low turn-on field (0.6 V/μm) and field enhancement factor (6917) with better stability and longer lifetime. Emitter morphology resulting in improved promising field emission performances, which is a crucial factor for the fabrication of pillared shaped vertical aligned CNTs bundles as practical electron sources.

Evaluation of the Absolute Regional Temperature Potential

NASA Technical Reports Server (NTRS)

Shindell, D. T.

2012-01-01

The Absolute Regional Temperature Potential (ARTP) is one of the few climate metrics that provides estimates of impacts at a sub-global scale. The ARTP presented here gives the time-dependent temperature response in four latitude bands (90-28degS, 28degS-28degN, 28-60degN and 60-90degN) as a function of emissions based on the forcing in those bands caused by the emissions. It is based on a large set of simulations performed with a single atmosphere-ocean climate model to derive regional forcing/response relationships. Here I evaluate the robustness of those relationships using the forcing/response portion of the ARTP to estimate regional temperature responses to the historic aerosol forcing in three independent climate models. These ARTP results are in good accord with the actual responses in those models. Nearly all ARTP estimates fall within +/-20%of the actual responses, though there are some exceptions for 90-28degS and the Arctic, and in the latter the ARTP may vary with forcing agent. However, for the tropics and the Northern Hemisphere mid-latitudes in particular, the +/-20% range appears to be roughly consistent with the 95% confidence interval. Land areas within these two bands respond 39-45% and 9-39% more than the latitude band as a whole. The ARTP, presented here in a slightly revised form, thus appears to provide a relatively robust estimate for the responses of large-scale latitude bands and land areas within those bands to inhomogeneous radiative forcing and thus potentially to emissions as well. Hence this metric could allow rapid evaluation of the effects of emissions policies at a finer scale than global metrics without requiring use of a full climate model.

The Solar Wind Charge-Transfer X-Ray Emission in the 1/4 keV Energy Range: Inferences on Local Bubble Hot Gas at Low Z

NASA Astrophysics Data System (ADS)

Koutroumpa, D.; Lallement, R.; Raymond, J. C.; Kharchenko, V.

2009-05-01

We present calculations of the heliospheric solar wind charge-exchange (SWCX) emission spectra and the resulting contributions of this diffuse background in the ROSAT 1/4 keV bands. We compare our results with the soft X-ray background (SXRB) emission detected in front of 378 identified shadowing regions during the ROSAT All-Sky Survey. This foreground component is principally attributed to the hot gas of the so-called Local Bubble (LB), an irregularly shaped cavity of ~50-150 pc around the Sun, which is supposed to contain ~106 K plasma. Our results suggest that the SWCX emission from the heliosphere is bright enough to account for most of the foreground emission toward the majority of low galactic latitude directions, where the LB is the least extended. On the other hand, in a large part of directions with galactic latitude above 30°, the heliospheric SWCX intensity is significantly smaller than the measured one. However, the SWCX R2/R1 band ratio differs slightly from the data in the galactic center direction, and more significantly in the galactic anticentre direction where the observed ratio is the smallest. Assuming that both SWCX and hot gas emission are present and their relative contributions vary with direction, we tested a series of thermal plasma spectra for temperatures ranging from 10 5 to 10 6.5 K and searched for a combination of SWCX spectra and thermal emission matching the observed intensities and band ratios, while simultaneously being compatible with O VI emission measurements. In the frame of collisional equilibrium models and for solar abundances, the range we derive for hot gas temperature and emission measure cannot reproduce the Wisconsin C/B band ratio. This implies that accounting for SWCX contamination does not remove these known disagreements between data and classical hot gas models. We emphasize the need for additional atomic data, describing consistently EUV and X-ray photon spectra of the charge-exchange emission of heavier solar wind ions.

X-ray Photoelectron Spectroscopic and Raman microscopic investigation of the variscite group minerals: Variscite, strengite, scorodite and mansfieldite

NASA Astrophysics Data System (ADS)

Kloprogge, J. Theo; Wood, Barry J.

2017-10-01

Several structurally related AsO4 and PO4 minerals, were studied with Raman microscopy and X-ray Photoelectron Spectroscopy (XPS). XPS revealed only Fe, As and O for scorodite. The Fe 2p, As 3d, and O 1s indicated one position for Fe2 +, while 2 different environments for O and As were observed. The O 1s at 530.3 eV and the As 3d 5/2 at 43.7 eV belonged to AsO4, while minor bands for O 1s at 531.3 eV and As 3d 5/2 at 44.8 eV were due to AsO4 groups exposed on the surface possibly forming OH-groups. Mansfieldite showed, besides Al, As and O, a trace of Co. The PO4 equivalent of mansfieldite is variscite. The change in crystal structure replacing As with P resulted in an increase in the binding energy (BE) of the Al 2p by 2.9 eV. The substitution of Fe3 + for Al3 + in the structure of strengite resulted in a Fe 2p at 710.8 eV. An increase in the Fe 2p BE of 4.8 eV was found between mansfieldite and strengite. The scorodite Raman OH-stretching region showed a sharp band at 3513 cm- 1 and a broad band around 3082 cm- 1. The spectrum of mansfieldite was like that of scorodite with a sharp band at 3536 cm- 1 and broader maxima at 3100 cm- 1 and 2888 cm- 1. Substituting Al in the arsenate structure instead of Fe resulted in a shift of the metal-OH-stretching mode by 23 cm- 1 towards higher wavenumbers due to a slightly longer H-bonding in mansfieldite compared to scorodite. The intense band for scorodite at 805 cm- 1 was ascribed to the symmetric stretching mode of the AsO4. The medium intensity bands at 890, 869, and 830 cm- 1 were ascribed to the internal modes. A significant shift towards higher wavenumbers was observed for mansfieldite. The strengite Raman spectrum in the 900-1150 cm- 1 shows a strong band at 981 cm- 1 accompanied by a series of less intense bands. The 981 cm- 1 band was assigned to the PO4 symmetric stretching mode, while the weak band at 1116 cm- 1 was the corresponding antisymmetric stretching mode. The remaining bands at 1009, 1023 and 1035 cm- 1 were assigned to υ1(A1) internal modes in analogy to the interpretation of the AsO4 bands for scorodite and mansfieldite. The variscite spectrum showed a shift towards higher wavenumbers in comparison to the strengite spectrum with the strongest band observed at 1030 cm- 1 and was assigned to the symmetric stretching mode of the PO4, while the corresponding antisymmetric stretching mode was observed at 1080 cm- 1. Due to the band splitting component bands were observed at 1059, 1046, 1013 and 940 cm- 1. The AsO4 symmetric bending modes for scorodite were observed at 381 and 337 cm- 1, while corresponding antisymmetric bending modes occurred at 424, 449 and 484 cm- 1. Comparison with other arsenate and phosphate minerals showed that both XPS and Raman spectroscopy are fast and non-destructive techniques to identify these minerals based on their differences in chemistry and the arsenate/phosphate vibrational modes due to changes in the symmetry and the unique fingerprint region of the lattice modes.

Diffuse X-ray emission from the Dumbbell Nebula?

NASA Technical Reports Server (NTRS)

Chu, You-Hua; Kwitter, Karen B.; Kaler, James B.

1993-01-01

We have analyzed ROSAT Position Sensitive Proportional Counter pointed observations of the Dumbbell Nebula and find that the previously reported 'extended' X-ray emission is an instrumental electronic ghost image at the softest energy band. At slightly higher energy bands, the image of the Dumbbell is not very different from that of the white dwarf HZ43. We conclude that the X-ray emission of the Dumbbell Nebula comes from its central star. A blackbody model is fitted to the spectrum and the best-fit temperature of not greater than 136,000 +/- 10,000 K is in excellent agreement with the Zanstra temperatures.

X ray absorption by dark nebulae (HEAO-2 guest investigator program)

NASA Technical Reports Server (NTRS)

Sanders, W. T.

1991-01-01

A study is described of data obtained from the Imaging Proportional Counter (IPC) x ray detector aboard the HEAO-2 satellite (Einstein Observatory). The research project involved a search for absorption of diffuse low energy x ray background emission by galactic dark nebulae. The commonly accepted picture that the bulk of the C band emission originates locally, closer that a few hundred parsec, and the bulk of the M band emission originates farther away than a few hundred parsec, was tested. The idea was to look for evidence of absorption of the diffuse background radiation by nearby interstellar clouds.

Production of N2 Vegard-Kaplan and Lyman-Birge-Hopfield emissions on Pluto

NASA Astrophysics Data System (ADS)

Jain, Sonal Kumar; Bhardwaj, Anil

2015-01-01

We have developed a model to calculate the emission intensities of various vibrational transitions of N2 triplet band and Lyman-Birge-Hopfield (LBH) band emissions in the dayglow of Pluto for solar minimum, moderate, and maximum conditions. The calculated overhead intensities of Vegard-Kaplan (A3Σu+ -X1 Σg+) , First Positive (B3Πg -A3 Σu+), Second Positive (C3Πu -B3Πg) , Wu-Benesch (W3Δu -B3Πg) , Reverse First Positive, and LBH (a1Πg -X1 Σg+) bands of N2 are 17 (74), 14.8 (64), 2.4 (10.8), 2.9 (12.7), 2.9 (12.5), and 2.3 (10) R, respectively, for solar minimum (maximum) condition. We have predicted the overhead and limb intensities of VK (150-190 nm) and LBH (120-190 nm) bands of N2 on Pluto for the New Horizons (NH) flyby condition that can be observed by ALICE: the ultraviolet imaging spectrograph also know as P-ALICE. The predicted limb intensities of VK and LBH bands peak at radial distance of ∼2000 km with the value of about 5 (13) and 9.5 (22) R for solar zenith angle 60° (0°), respectively. We have also calculated overhead and limb intensities of few prominent transition of CO Fourth Positive bands for NH flyby condition.

NEAR-INFRARED THERMAL EMISSION DETECTIONS OF A NUMBER OF HOT JUPITERS AND THE SYSTEMATICS OF GROUND-BASED NEAR-INFRARED PHOTOMETRY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Croll, Bryce; Albert, Loic; Lafreniere, David

We present detections of the near-infrared thermal emission of three hot Jupiters and one brown dwarf using the Wide-field Infrared Camera (WIRCam) on the Canada-France-Hawaii Telescope (CFHT). These include Ks-band secondary eclipse detections of the hot Jupiters WASP-3b and Qatar-1b and the brown dwarf KELT-1b. We also report Y-band, K {sub CONT}-band, and two new and one reanalyzed Ks-band detections of the thermal emission of the hot Jupiter WASP-12b. We present a new reduction pipeline for CFHT/WIRCam data, which is optimized for high precision photometry. We also describe novel techniques for constraining systematic errors in ground-based near-infrared photometry, so asmore » to return reliable secondary eclipse depths and uncertainties. We discuss the noise properties of our ground-based photometry for wavelengths spanning the near-infrared (the YJHK bands), for faint and bright stars, and for the same object on several occasions. For the hot Jupiters WASP-3b and WASP-12b we demonstrate the repeatability of our eclipse depth measurements in the Ks band; we therefore place stringent limits on the systematics of ground-based, near-infrared photometry, and also rule out violent weather changes in the deep, high pressure atmospheres of these two hot Jupiters at the epochs of our observations.« less

Thermal, optical and structural properties of Dy3+ doped sodium aluminophosphate glasses

NASA Astrophysics Data System (ADS)

Kaur, Manpreet; Singh, Anupinder; Thakur, Vanita; Singh, Lakhwant

2016-03-01

Trivalent Dysprosium doped sodium aluminophosphate glasses with composition 50P2O5-10Al2O3-(20-x)Na2O-20CaO-xDy2O3 (x varying from 0 to 5 mol%) were prepared by melt quench technique. The density of the prepared samples was measured using Archimedes principle and various physical properties like molar volume, rare earth ion concentration, polaron radius, inter nuclear distance and field strength were calculated using different formulae. The differential scanning calorimetry (DSC) was carried out to study the thermal stability of prepared glasses. The UV Visible absorption spectra of the dysprosium doped glasses were found to be comprised of ten absorption bands which correspond to transitions from ground state 6H15/2 to various excited states. The indirect optical band gap energy of the samples was calculated by Tauc's plot and the optical energy was found to be attenuated with Dy3+ ions. The photoluminescence spectrum revealed that Dy3+ doped aluminophosphate glasses have strong emission bands in the visible region. A blue emission band centred at 486 nm, a bright yellow band centred at 575 nm and a weak red band centred at 668 nm were observed in the emission spectrum due to excitation at 352 nm wavelength. Both FTIR and Raman spectra assert slight structural changes induced in the host glass network with Dy3+ ions.

Growth of electron plasma waves above and below f(p) in the electron foreshock

NASA Technical Reports Server (NTRS)

Cairns, Iver H.; Fung, Shing F.

1988-01-01

This paper investigates the conditions required for electron beams to drive wave growth significantly above and below the electron plasma frequency, f(p), by numerically solving the linear dispersion equation. It is shown that kinetic growth well below f(p) may occur over a broad range of frequencies due to the beam instability, when the electron beam is slow, dilute, and relatively cold. Alternatively, a cold or sharp feature at low parallel velocities in the distribution function may drive kinetic growth significantly below f(p). Kinetic broadband growth significantly above f(p) is explained in terms of faster warmer beams. A unified qualitative theory for the narrow-band and broad-band waves is proposed.

Landsat-4 MSS and Thematic Mapper data quality and information content analysis

NASA Technical Reports Server (NTRS)

Anuta, P. E.; Bartolucci, L. A.; Dean, M. E.; Lozano, D. F.; Malaret, E.; Mcgillem, C. D.; Valdes, J. A.; Valenzuela, C. R.

1984-01-01

Landsat-4 Thematic Mapper and Multispectral Scanner data were analyzed to obtain information on data quality and information content. Geometric evaluations were performed to test band-to-band registration accuracy. Thematic Mapper overall system resolution was evaluated using scene objects which demonstrated sharp high contrast edge responses. Radiometric evaluation included detector relative calibration, effects of resampling, and coherent noise effects. Information content evaluation was carried out using clustering, principal components, transformed divergence separability measure, and numerous supervised classifiers on data from Iowa and Illinois. A detailed spectral class analysis (multispectral classification) was carried out on data from the Des Moines, IA area to compare the information content of the MSS and TM for a large number of scene classes.

Direct Observation of Two-Step Photon Absorption in an InAs/GaAs Single Quantum Dot for the Operation of Intermediate-Band Solar Cells.

PubMed

Nozawa, Tomohiro; Takagi, Hiroyuki; Watanabe, Katsuyuki; Arakawa, Yasuhiko

2015-07-08

We present the first direct observation of two-step photon absorption in an InAs/GaAs single quantum dot (QD) using photocurrent spectroscopy with two lasers. The sharp peaks of the photocurrent are shifted due to the quantum confined Stark effect, indicating that the photocurrent from a single QD is obtained. In addition, the intensity of the peaks depends on the power of the secondary laser. These results reveal the direct demonstration of the two-step photon absorption in a single QD. This is an essential result for both the fundamental operation and the realization of ultrahigh solar-electricity energy conversion in quantum dot intermediate-band solar cells.

Investigations on the effects of the Stark splitting on the fluorescence behaviors in Yb3+-doped silicate, tellurite, germanate, and phosphate glasses

NASA Astrophysics Data System (ADS)

Zhang, Liaolin; Xia, Yu; Shen, Xiao; Yang, Runlan; Wei, Wei

2018-01-01

In this work, we systematically studied the spectroscopic characteristics of Yb3+ doped germanate, phosphate, silicate, and tellurite glasses. The emission peak beyond 976 nm showed irregular shift from 1001 nm to 1023 nm when Yb3+ in different glass matrices. It was associated with the Stark splitting of 2F7/2 and the emission intensities ratio between the transition from the lowest Stark splitting energy level of 2F5/2 to the Stark splitting energy levels of 2F7/2, e to b and that of e to d. Larger Stark splitting of 2F7/2 results in the red-shift of the near infrared emission band at room temperature and larger ratio results in the blue-shift of emission band. The fluorescence lifetimes of Yb3+ doped germanate, phosphate, silicate, and tellurite glasses were measured to be 0.94, 0.82, 1.51, and 0.66 ms, respectively. The fluorescence lifetime was associated with the reabsorption of Yb3+, which larger absorption cross section at the emission band results in larger reabsorption, then leads to the shorter near infrared fluorescence lifetime.

Investigation of the normal spectral band emissivity characteristic within 7.5 to 13 μm for Molybdenum between 100 and 500 °C

NASA Astrophysics Data System (ADS)

Zhang, Yan; Zhang, Yuzhong; Lu, Rongsheng; Shu, Shuangbao; Lang, Xianli; Yang, Lei

2018-01-01

Molybdenum (Mo) is an important material to construct the first wall for the Experimental Advanced Superconducting Tokamak (EAST). The real-time monitoring of temperature distribution of the first wall based on radiation thermometry is essential to guarantee the stable operation of EAST. So, it is especially important for the acquisition of emissivity property of Mo. In this work, a self-designed emissivity measurement apparatus is developed, and the relationship between the normal infrared spectral band (7.5-13 μm) emissivity of Mo against the temperature and surface roughness of material samples is experimentally investigated under the vacuum condition over the temperature ranging from 100 °C to 500 °C. Moreover, the dependence of spectral band emissivity of Mo exposed to air on the heating-duration time at a given elevated temperature is also studied. The emissivity measurement apparatus is mainly composed of a high temperature furnace and a radiation thermometer as well as a benchmark blackbody furnace. The radiation thermometer is firstly calibrated against the blackbody furnace by means of the multi-temperature methods. And then the temperature of the sample is simultaneously measured by the two highly accurate S-type thermocouples and the radiation thermometer. Finally the emissivity value of the sample is calculated based on the direct radiometric method. The developed emissivity measurement method and experimental results obtained in this work may be helpful to understand the work state the EAST and to use of Mo as an emissivity reference.

EUV emission spectra in collisions of highly charged tantalum ions with nitrogen and oxygen molecules

NASA Astrophysics Data System (ADS)

Tanuma, Hajime; Numadate, Naoki; Uchikura, Yoshiyuki; Shimada, Kento; Akutsu, Takuto; Long, Elaine; O'Sullivan, Gerry

2017-10-01

We have performed ion beam collision experiments using multiply charged tantalum ions and observed EUV (extreme ultra-violet) emission spectra in collisions of ions with molecular targets, N2 and O2. Broad UTAs (un-resolved transition arrays) from multiply charged Ta ions were observed, and the mean wavelengths of the UTAs shifted and became shorter at higher charge statea of Ta ions. These UTAs may be attributed to the 4f-5d and 4f-5g transitions. Not only the UTA emission from incident ions, but also the sharp emission lines from multiply charged fragment atomic ions were observed. Production of temporary highly charged molecular ions, their kinetic energy and fragmentation processes have been investigated with coincident detection technique. However, the observation of emission from the fragments might be for the first time. The formation mechanisms of the multiply charged fragment atomic ions from target molecules are discussed.

Thermal removal from near-infrared imaging spectroscopy data of the Moon

USGS Publications Warehouse

Clark, R.N.; Pieters, C.M.; Green, R.O.; Boardman, J.W.; Petro, N.E.

2011-01-01

In the near-infrared from about 2 ??m to beyond 3 ??m, the light from the Moon is a combination of reflected sunlight and emitted thermal emission. There are multiple complexities in separating the two signals, including knowledge of the local solar incidence angle due to topography, phase angle dependencies, emissivity, and instrument calibration. Thermal emission adds to apparent reflectance, and because the emission's contribution increases over the reflected sunlight with increasing wavelength, absorption bands in the lunar reflectance spectra can be modified. In particular, the shape of the 2 ??m pyroxene band can be distorted by thermal emission, changing spectrally determined pyroxene composition and abundance. Because of the thermal emission contribution, water and hydroxyl absorptions are reduced in strength, lowering apparent abundances. It is important to quantify and remove the thermal emission for these reasons. We developed a method for deriving the temperature and emissivity from spectra of the lunar surface and removing the thermal emission in the near infrared. The method is fast enough that it can be applied to imaging spectroscopy data on the Moon. Copyright ?? 2011 by the American Geophysical Union.

Thermal removal from near-infrared imaging spectroscopy data of the Moon

USGS Publications Warehouse

Clark, Roger N.; Pieters, Carle M.; Green, Robert O.; Boardman, J.W.; Petro, Noah E.

2011-01-01

In the near-infrared from about 2 μm to beyond 3 μm, the light from the Moon is a combination of reflected sunlight and emitted thermal emission. There are multiple complexities in separating the two signals, including knowledge of the local solar incidence angle due to topography, phase angle dependencies, emissivity, and instrument calibration. Thermal emission adds to apparent reflectance, and because the emission's contribution increases over the reflected sunlight with increasing wavelength, absorption bands in the lunar reflectance spectra can be modified. In particular, the shape of the 2 μm pyroxene band can be distorted by thermal emission, changing spectrally determined pyroxene composition and abundance. Because of the thermal emission contribution, water and hydroxyl absorptions are reduced in strength, lowering apparent abundances. It is important to quantify and remove the thermal emission for these reasons. We developed a method for deriving the temperature and emissivity from spectra of the lunar surface and removing the thermal emission in the near infrared. The method is fast enough that it can be applied to imaging spectroscopy data on the Moon.