Increases in plasma sheet temperature with solar wind driving during substorm growth phases

PubMed Central

Forsyth, C; Watt, C E J; Rae, I J; Fazakerley, A N; Kalmoni, N M E; Freeman, M P; Boakes, P D; Nakamura, R; Dandouras, I; Kistler, L M; Jackman, C M; Coxon, J C; Carr, C M

2014-01-01

During substorm growth phases, magnetic reconnection at the magnetopause extracts ∼1015 J from the solar wind which is then stored in the magnetotail lobes. Plasma sheet pressure increases to balance magnetic flux density increases in the lobes. Here we examine plasma sheet pressure, density, and temperature during substorm growth phases using 9 years of Cluster data (>316,000 data points). We show that plasma sheet pressure and temperature are higher during growth phases with higher solar wind driving, whereas the density is approximately constant. We also show a weak correlation between plasma sheet temperature before onset and the minimum SuperMAG AL (SML) auroral index in the subsequent substorm. We discuss how energization of the plasma sheet before onset may result from thermodynamically adiabatic processes; how hotter plasma sheets may result in magnetotail instabilities, and how this relates to the onset and size of the subsequent substorm expansion phase. PMID:26074645

Increases in plasma sheet temperature with solar wind driving during substorm growth phases.

PubMed

Forsyth, C; Watt, C E J; Rae, I J; Fazakerley, A N; Kalmoni, N M E; Freeman, M P; Boakes, P D; Nakamura, R; Dandouras, I; Kistler, L M; Jackman, C M; Coxon, J C; Carr, C M

2014-12-28

During substorm growth phases, magnetic reconnection at the magnetopause extracts ∼10 15  J from the solar wind which is then stored in the magnetotail lobes. Plasma sheet pressure increases to balance magnetic flux density increases in the lobes. Here we examine plasma sheet pressure, density, and temperature during substorm growth phases using 9 years of Cluster data (>316,000 data points). We show that plasma sheet pressure and temperature are higher during growth phases with higher solar wind driving, whereas the density is approximately constant. We also show a weak correlation between plasma sheet temperature before onset and the minimum SuperMAG AL (SML) auroral index in the subsequent substorm. We discuss how energization of the plasma sheet before onset may result from thermodynamically adiabatic processes; how hotter plasma sheets may result in magnetotail instabilities, and how this relates to the onset and size of the subsequent substorm expansion phase.

Constraining the Antarctic contribution to global sea-level change: ANDRILL and beyond

NASA Astrophysics Data System (ADS)

Naish, Timothy

2016-04-01

Observations, models and paleoclimate reconstructions suggest that Antarctica's marine-based ice sheets behave in an unstable manner with episodes of rapid retreat in response to warming climate. Understanding the processes involved in this "marine ice sheet instability" is key for improving estimates of Antarctic ice sheet contribution to future sea-level rise. Another motivating factor is that far-field sea-level reconstructions and ice sheet models imply global mean sea level (GMSL) was up to 20m and 10m higher, respectively, compared with present day, during the interglacials of the warm Pliocene (~4-3Ma) and Late Pleistocene (at ~400ka and 125ka). This was when atmospheric CO2 was between 280 and 400ppm and global average surface temperatures were 1 to 3°C warmer, suggesting polar ice sheets are highly sensitive to relatively modest increases in climate forcing. Such magnitudes of GMSL rise not only require near complete melt of the Greenland Ice Sheet and the West Antarctic Ice Sheet, but a substantial retreat of marine-based sectors of East Antarctic Ice Sheet. Recent geological drilling initiatives on the continental margin of Antarctica from both ship- (e.g. IODP; International Ocean Discovery Program) and ice-based (e.g. ANDRILL/Antarctic Geological Drilling) platforms have provided evidence supporting retreat of marine-based ice. However, without direct access through the ice sheet to archives preserved within sub-glacial sedimentary basins, the volume and extent of ice sheet retreat during past interglacials cannot be directly constrained. Sediment cores have been successfully recovered from beneath ice shelves by the ANDRILL Program and ice streams by the WISSARD (Whillans Ice Stream Sub-glacial Access Research Drilling) Project. Together with the potential of the new RAID (Rapid Access Ice Drill) initiative, these demonstrate the technological feasibility of accessing the subglacial bed and deeper sedimentary archives. In this talk I will outline the scientific challenges, some potential sub-glacial sedimentary targets, and a strategy for future drilling of sub-glacial sedimentary basins.

Constraining the Antarctic contribution to interglacial sea-level rise

NASA Astrophysics Data System (ADS)

Naish, T.; Mckay, R. M.; Barrett, P. J.; Levy, R. H.; Golledge, N. R.; Deconto, R. M.; Horgan, H. J.; Dunbar, G. B.

2015-12-01

Observations, models and paleoclimate reconstructions suggest that Antarctica's marine-based ice sheets behave in an unstable manner with episodes of rapid retreat in response to warming climate. Understanding the processes involved in this "marine ice sheet instability" is key for improving estimates of Antarctic ice sheet contribution to future sea-level rise. Another motivating factor is that far-field sea-level reconstructions and ice sheet models imply global mean sea level (GMSL) was up to 20m and 10m higher, respectively, compared with present day, during the interglacials of the warm Pliocene (~4-3Ma) and Late Pleistocene (at ~400ka and 125ka). This was when atmospheric CO2 was between 280 and 400ppm and global average surface temperatures were 1- 3°C warmer, suggesting polar ice sheets are highly sensitive to relatively modest increases in climate forcing. Such magnitudes of GMSL rise not only require near complete melt of the Greenland Ice Sheet and the West Antarctic Ice Sheet, but a substantial retreat of marine-based sectors of East Antarctic Ice Sheet. Recent geological drilling initiatives on the continental margin of Antarctica from both ship- (e.g. IODP; International Ocean Discovery Program) and ice-based (e.g. ANDRILL/Antarctic Geological Drilling) platforms have provided evidence supporting retreat of marine-based ice. However, without direct access through the ice sheet to archives preserved within sub-glacial sedimentary basins, the volume and extent of ice sheet retreat during past interglacials cannot be directly constrained. Sediment cores have been successfully recovered from beneath ice shelves by the ANDRILL Program and ice streams by the WISSARD (Whillans Ice Stream Sub-glacial Access Research Drilling) Project. Together with the potential of the new RAID (Rapid Access Ice Drill) initiative, these demonstrate the technological feasibility of accessing the subglacial bed and deeper sedimentary archives. In this talk I will outline the scientific challenges, some potential sub-glacial sedimentary targets, and a strategy for future drilling of sub-glacial sedimentary basins.

Subglacial sedimentary basin characterization of Wilkes Land, East Antarctica via applied aerogeophysical inverse methods

NASA Astrophysics Data System (ADS)

Frederick, B. C.; Gooch, B. T.; Richter, T.; Young, D. A.; Blankenship, D. D.; Aitken, A.; Siegert, M. J.

2013-12-01

Topography, sediment distribution and heat flux are all key boundary conditions governing the stability of the East Antarctic ice sheet (EAIS). Recent scientific scrutiny has been focused on several large, deep, interior EAIS basins including the submarine basal topography characterizing the Aurora Subglacial Basin (ASB). Numerical ice sheet models require accurate deformable sediment distribution and lithologic character constraints to estimate overall flow velocities and potential instability. To date, such estimates across the ASB have been derived from low-resolution satellite data or historic aerogeophysical surveys conducted prior to the advent of GPS. These rough basal condition estimates have led to poorly-constrained ice sheet stability models for this remote 200,000 sq km expanse of the ASB. Here we present a significantly improved quantitative model characterizing the subglacial lithology and sediment in the ASB region. The product of comprehensive ICECAP (2008-2013) aerogeophysical data processing, this sedimentary basin model details the expanse and thickness of probable Wilkes Land subglacial sedimentary deposits and density contrast boundaries indicative of distinct subglacial lithologic units. As part of the process, BEDMAP2 subglacial topographic results were improved through the additional incorporation of ice-penetrating radar data collected during ICECAP field seasons 2010-2013. Detailed potential field data pre-processing was completed as well as a comprehensive evaluation of crustal density contrasts based on the gravity power spectrum, a subsequent high pass data filter was also applied to remove longer crustal wavelengths from the gravity dataset prior to inversion. Gridded BEDMAP2+ ice and bed radar surfaces were then utilized to establish bounding density models for the 3D gravity inversion process to yield probable sedimentary basin anomalies. Gravity inversion results were iteratively evaluated against radar along-track RMS deviation and gravity and magnetic depth to basement results. This geophysical data processing methodology provides a substantial improvement over prior Wilkes Land sedimentary basin estimates yielding a higher resolution model based upon iteration of several aerogeophysical datasets concurrently. This more detailed subglacial sedimentary basin model for Wilkes Land, East Antarctica will not only contribute to vast improvements on EAIS ice sheet model constraints, but will also provide significant quantifiable controls for subglacial hydrologic and geothermal flux estimates that are also sizable contributors to the cold-based, deep interior basal ice dynamics dominant in the Wilkes Land region.

Surface and Basal Roughness in Radar Sounding Data: Obstacle and Opportunity

NASA Astrophysics Data System (ADS)

Schroeder, D. M.; Grima, C.; Haynes, M.

2015-12-01

The surface and basal roughness of glaciers, ice sheets, and ice shelves can pose a significant obstacle to the visual interpretation and quantitative analysis of radar sounding data. Areas of high surface roughness - including grounding zones, shear margins, and crevasse fields - can produce clutter and side-lobe signals that obscure the interpretation of englacial and subglacial features. These areas can also introduce significant variation in bed echo strength profiles as a result of losses from two-way propagation through rough ice surfaces. Similarly, reflections from rough basal interfaces beneath ice sheets and ice shelves can also result in large, spatially variable losses in bed echo power. If unmitigated and uncorrected, these effects can degrade or prevent the definitive interpretation of material and geometric properties at the base of ice sheets and ice shelves using radar reflectivity and bed echo character. However, these effects also provide geophysical signatures of surface and basal interface character - including surface roughness, firn density, subglacial bedform geometry, ice shelf basal roughness, marine-ice/brine detection, and crevasse geometry - that can be observed and constrained by exploiting roughness effects in radar sounding data. We present a series of applications and approaches for characterizing and correcting surface and basal roughness effects for airborne radar sounding data collected in Antarctica. We also present challenges, insights, and opportunities for extending these techniques to the orbital radar sounding of Europa's ice shell.

Rapid model building of beta-sheets in electron-density maps.

PubMed

Terwilliger, Thomas C

2010-03-01

A method for rapidly building beta-sheets into electron-density maps is presented. beta-Strands are identified as tubes of high density adjacent to and nearly parallel to other tubes of density. The alignment and direction of each strand are identified from the pattern of high density corresponding to carbonyl and C(beta) atoms along the strand averaged over all repeats present in the strand. The beta-strands obtained are then assembled into a single atomic model of the beta-sheet regions. The method was tested on a set of 42 experimental electron-density maps at resolutions ranging from 1.5 to 3.8 A. The beta-sheet regions were nearly completely built in all but two cases, the exceptions being one structure at 2.5 A resolution in which a third of the residues in beta-sheets were built and a structure at 3.8 A in which under 10% were built. The overall average r.m.s.d. of main-chain atoms in the residues built using this method compared with refined models of the structures was 1.5 A.

Simulating the impact of glaciations on continental groundwater flow systems: 1. Relevant processes and model formulation

NASA Astrophysics Data System (ADS)

Lemieux, J.-M.; Sudicky, E. A.; Peltier, W. R.; Tarasov, L.

2008-09-01

In the recent literature, it has been shown that Pleistocene glaciations had a large impact on North American regional groundwater flow systems. Because of the myriad of complex processes and large spatial scales involved during periods of glaciation, numerical models have become powerful tools to examine how ice sheets control subsurface flow systems. In this paper, the key processes that must be represented in a continental-scale 3-D numerical model of groundwater flow during a glaciation are reviewed, including subglacial infiltration, density-dependent (i.e., high-salinity) groundwater flow, permafrost evolution, isostasy, sea level changes, and ice sheet loading. One-dimensional hydromechanical coupling associated with ice loading and brine generation were included in the numerical model HydroGeoSphere and tested against newly developed exact analytical solutions to verify their implementation. Other processes such as subglacial infiltration, permafrost evolution, and isostasy were explicitly added to HydroGeoSphere. A specified flux constrained by the ice sheet thickness was found to be the most appropriate boundary condition in the subglacial environment. For the permafrost, frozen and unfrozen elements can be selected at every time step with specified hydraulic conductivities. For the isostatic adjustment, the elevations of all the grid nodes in each vertical grid column below the ice sheet are adjusted uniformly to account for the Earth's crust depression and rebound. In a companion paper, the model is applied to the Wisconsinian glaciation over the Canadian landscape in order to illustrate the concepts developed in this paper and to better understand the impact of glaciation on 3-D continental groundwater flow systems.

Late Wisconsin and early holocene glacial history, inner Ross Embayment, Antarctica

NASA Technical Reports Server (NTRS)

Denton, George H.; Bockheim, James G.; Wilson, Scott C.; Stuiver, Minze

1991-01-01

Lateral drift sheets of outlet glaciers that pass through the Transantarctic Mountains constrain past changes of the huge Ross ice drainage system of the Antarctic Ice Sheet. Drift stratigraphy suggests correlation of Reedy III (Reedy Glacier), Beardmore, Britannia (Hatherton/Darwin Glaciers), Ross Sea (McMurdo Sound), and younger (Terra Nova Bay) drifts; radiocarbon dates place the outer limits of Ross Sea drift in late Wisconsin time at 24,000 to 13,000 yr B.P. Outlet glacier profiles from these drifts constrain late Wisconsin ice sheet surface elevations. Within these constraint, two extreme late Wisconsin reconstructions are given of the Ross ice drainage system. Both show little elevation change of the polar plateau coincident with extensive ice shelf grounding along the inner Ross Embayment. However, in the central Ross Embayment, one reconstruction shows floating shelf ice, where as the other shows a grounded ice sheet. Massive late Wisconsin/Holocene recession of grounded ice from the western Ross Embayment, which was underway at 13,040 yr B.P. and completed by 6600 to 6020 yr B.P., was accompanied by little change in plateau ice levels inland of the Transantarctic Mountains.

Improvements in processing characteristics and engineering properties of wood flour-filled high density polyethylene composite sheeting in the presence of hollow glass microspheres

Treesearch

Baris Yalcin; Steve E Amos; Andrew S D Souza; Craig M Clemons; I Sedat Gunes; Troy K Ista

2012-01-01

Hollow glass microspheres were introduced into wood flour/high density polyethylene composites by melt compounding in a twin-screw extruder. The prepared composites were subsequently converted to extruded profiles in order to obtain composite sheeting. The presence of hollow glass microspheres highly reduced the density of the extruded sheets down to 0.9 g/cc, while...

Explicit Simulation of Networks of Outlet Glaciers to Constrain Greenland's Sea Level Contribution

NASA Astrophysics Data System (ADS)

Ultee, E.; Bassis, J. N.

2017-12-01

Ice from the Greenland Ice Sheet drains to the ocean through hundreds of outlet glaciers, many of which are too small to be accurately resolved in continental-scale ice sheet models. Moreover, despite the fact that dynamic changes in Greenland outlet glaciers are currently responsible for about half of the ice sheet's contribution to global sea level, all but the largest are often excluded from major sea level assessments. We have previously developed and validated a simple model that simulates advance and retreat of networks of marine-terminating glaciers based on the perfect plastic approximation. Here we apply this model to a selection of forcing scenarios, representing both climate persistence and extreme scenarios, to constrain changes in calving flux from the most significant Greenland outlet glaciers. Our model can be implemented in standalone mode or as the calving module in a more sophisticated large-scale model, providing constraints on Greenland's future contribution to global sea level rise under a range of scenarios.

Scanning micro-Hall probe mapping of magnetic flux distributions and current densities in YBa{sub 2}Cu{sub 3}O{sub 7}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xing, W.; Heinrich, B.; Zhou, H.

1994-12-31

Mapping of the magnetic flux density B{sub z} (perpendicular to the film plane) for a YBa{sub 2}Cu{sub 3}O{sub 7} thin-film sample was carried out using a scanning micro-Hall probe. The sheet magnetization and sheet current densities were calculated from the B{sub z} distributions. From the known sheet magnetization, the tangential (B{sub x,y}) and normal components of the flux density B were calculated in the vicinity of the film. It was found that the sheet current density was mostly determined by 2B{sub x,y}/d, where d is the film thickness. The evolution of flux penetration as a function of applied field willmore » be shown.« less

Surface Passivation by Quantum Exclusion Using Multiple Layers

NASA Technical Reports Server (NTRS)

Hoenk, Michael E. (Inventor)

2015-01-01

A semiconductor device has a multilayer doping to provide improved passivation by quantum exclusion. The multilayer doping includes at least two doped layers fabricated using MBE methods. The dopant sheet densities in the doped layers need not be the same, but in principle can be selected to be the same sheet densities or to be different sheet densities. The electrically active dopant sheet densities are quite high, reaching more than 1.times.10.sup.14 cm.sup.-2, and locally exceeding 10.sup.22 per cubic centimeter. It has been found that silicon detector devices that have two or more such dopant layers exhibit improved resistance to degradation by UV radiation, at least at wavelengths of 193 nm, as compared to conventional silicon p-on-n devices.

The phase-space structure of nearby dark matter as constrained by the SDSS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leclercq, Florent; Percival, Will; Jasche, Jens

Previous studies using numerical simulations have demonstrated that the shape of the cosmic web can be described by studying the Lagrangian displacement field. We extend these analyses, showing that it is now possible to perform a Lagrangian description of cosmic structure in the nearby Universe based on large-scale structure observations. Building upon recent Bayesian large-scale inference of initial conditions, we present a cosmographic analysis of the dark matter distribution and its evolution, referred to as the dark matter phase-space sheet, in the nearby universe as probed by the Sloan Digital Sky Survey main galaxy sample. We consider its stretchings andmore » foldings using a tetrahedral tessellation of the Lagrangian lattice. The method provides extremely accurate estimates of nearby density and velocity fields, even in regions of low galaxy density. It also measures the number of matter streams, and the deformation and parity reversals of fluid elements, which were previously thought inaccessible using observations. We illustrate the approach by showing the phase-space structure of known objects of the nearby Universe such as the Sloan Great Wall, the Coma cluster and the Boötes void. We dissect cosmic structures into four distinct components (voids, sheets, filaments, and clusters), using the Lagrangian classifiers DIVA, ORIGAMI, and a new scheme which we introduce and call LICH. Because these classifiers use information other than the sheer local density, identified structures explicitly carry physical information about their formation history. Accessing the phase-space structure of dark matter in galaxy surveys opens the way for new confrontations of observational data and theoretical models. We have made our data products publicly available.« less

The phase-space structure of nearby dark matter as constrained by the SDSS

NASA Astrophysics Data System (ADS)

Leclercq, Florent; Jasche, Jens; Lavaux, Guilhem; Wandelt, Benjamin; Percival, Will

2017-06-01

Previous studies using numerical simulations have demonstrated that the shape of the cosmic web can be described by studying the Lagrangian displacement field. We extend these analyses, showing that it is now possible to perform a Lagrangian description of cosmic structure in the nearby Universe based on large-scale structure observations. Building upon recent Bayesian large-scale inference of initial conditions, we present a cosmographic analysis of the dark matter distribution and its evolution, referred to as the dark matter phase-space sheet, in the nearby universe as probed by the Sloan Digital Sky Survey main galaxy sample. We consider its stretchings and foldings using a tetrahedral tessellation of the Lagrangian lattice. The method provides extremely accurate estimates of nearby density and velocity fields, even in regions of low galaxy density. It also measures the number of matter streams, and the deformation and parity reversals of fluid elements, which were previously thought inaccessible using observations. We illustrate the approach by showing the phase-space structure of known objects of the nearby Universe such as the Sloan Great Wall, the Coma cluster and the Boötes void. We dissect cosmic structures into four distinct components (voids, sheets, filaments, and clusters), using the Lagrangian classifiers DIVA, ORIGAMI, and a new scheme which we introduce and call LICH. Because these classifiers use information other than the sheer local density, identified structures explicitly carry physical information about their formation history. Accessing the phase-space structure of dark matter in galaxy surveys opens the way for new confrontations of observational data and theoretical models. We have made our data products publicly available.

Theoretical modeling of the plasma-assisted catalytic growth and field emission properties of graphene sheet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, Suresh C.; Gupta, Neha

2015-12-15

A theoretical modeling for the catalyst-assisted growth of graphene sheet in the presence of plasma has been investigated. It is observed that the plasma parameters can strongly affect the growth and field emission properties of graphene sheet. The model developed accounts for the charging rate of the graphene sheet; number density of electrons, ions, and neutral atoms; various elementary processes on the surface of the catalyst nanoparticle; surface diffusion and accretion of ions; and formation of carbon-clusters and large graphene islands. In our investigation, it is found that the thickness of the graphene sheet decreases with the plasma parameters, numbermore » density of hydrogen ions and RF power, and consequently, the field emission of electrons from the graphene sheet surface increases. The time evolution of the height of graphene sheet with ion density and sticking coefficient of carbon species has also been examined. Some of our theoretical results are in compliance with the experimental observations.« less

Modeling the evolution of the Laurentide Ice Sheet from MIS 3 to the Last Glacial Maximum: an approach using sea level modeling and ice flow dynamics

NASA Astrophysics Data System (ADS)

Weisenberg, J.; Pico, T.; Birch, L.; Mitrovica, J. X.

2017-12-01

The history of the Laurentide Ice Sheet since the Last Glacial Maximum ( 26 ka; LGM) is constrained by geological evidence of ice margin retreat in addition to relative sea-level (RSL) records in both the near and far field. Nonetheless, few observations exist constraining the ice sheet's extent across the glacial build-up phase preceding the LGM. Recent work correcting RSL records along the U.S. mid-Atlantic dated to mid-MIS 3 (50-35 ka) for glacial-isostatic adjustment (GIA) infer that the Laurentide Ice Sheet grew by more than three-fold in the 15 ky leading into the LGM. Here we test the plausibility of a late and extremely rapid glaciation by driving a high-resolution ice sheet model, based on a nonlinear diffusion equation for the ice thickness. We initialize this model at 44 ka with the mid-MIS 3 ice sheet configuration proposed by Pico et al. (2017), GIA-corrected basal topography, and mass balance representative of mid-MIS 3 conditions. These simulations predict rapid growth of the eastern Laurentide Ice Sheet, with rates consistent with achieving LGM ice volumes within 15 ky. We use these simulations to refine the initial ice configuration and present an improved and higher resolution model for North American ice cover during mid-MIS 3. In addition we show that assumptions of ice loads during the glacial phase, and the associated reconstructions of GIA-corrected basal topography, produce a bias that can underpredict ice growth rates in the late stages of the glaciation, which has important consequences for our understanding of the speed limit for ice growth on glacial timescales.

Self-propulsion of a planar electric or magnetic microbot immersed in a polar viscous fluid

NASA Astrophysics Data System (ADS)

Felderhof, B. U.

2011-05-01

A planar sheet immersed in an electrically polar liquid like water can propel itself by means of a plane wave charge density propagating in the sheet. The corresponding running electric wave polarizes the fluid and causes an electrical torque density to act on the fluid. The sheet is convected by the fluid motion resulting from the conversion of rotational particle motion, generated by the torque density, into translational fluid motion by the mechanism of friction and spin diffusion. Similarly, a planar sheet immersed in a magnetic ferrofluid can propel itself by means of a plane wave current density in the sheet and the torque density acting on the fluid corresponding to the running wave magnetic field and magnetization. The effect is studied on the basis of the micropolar fluid equations of motion and Maxwell’s equations of electrostatics or magnetostatics, respectively. An analytic expression is derived for the velocity of the sheet by perturbation theory to second order in powers of the amplitude of the driving charge or current density. Under the assumption that the equilibrium magnetic equation of state may be used in linearized form and that higher harmonics than the first may be neglected, a set of self-consistent integral equations is derived which can be solved numerically by iteration. In typical situations the second-order perturbation theory turns out to be quite accurate.

Magnetic configurations of the tilted current sheets in magnetotail

NASA Astrophysics Data System (ADS)

Shen, C.; Rong, Z. J.; Li, X.; Dunlop, M.; Liu, Z. X.; Malova, H. V.; Lucek, E.; Carr, C.

2008-11-01

In this research, the geometrical structures of tilted current sheet and tail flapping waves have been analysed based on multiple spacecraft measurements and some features of the tilted current sheets have been made clear for the first time. The geometrical features of the tilted current sheet revealed in this investigation are as follows: (1) The magnetic field lines (MFLs) in the tilted current sheet are generally plane curves and the osculating planes in which the MFLs lie are about vertical to the equatorial plane, while the normal of the tilted current sheet leans severely to the dawn or dusk side. (2) The tilted current sheet may become very thin, the half thickness of its neutral sheet is generally much less than the minimum radius of the curvature of the MFLs. (3) In the neutral sheet, the field-aligned current density becomes very large and has a maximum value at the center of the current sheet. (4) In some cases, the current density is a bifurcated one, and the two humps of the current density often superpose two peaks in the gradient of magnetic strength, indicating that the magnetic gradient drift current is possibly responsible for the formation of the two humps of the current density in some tilted current sheets. Tilted current sheets often appear along with tail current sheet flapping waves. It is found that, in the tail flapping current sheets, the minimum curvature radius of the MFLs in the current sheet is rather large with values around 1 RE, while the neutral sheet may be very thin, with its half thickness being several tenths of RE. During the flapping waves, the current sheet is tilted substantially, and the maximum tilt angle is generally larger than 45°. The phase velocities of these flapping waves are several tens km/s, while their periods and wavelengths are several tens of minutes, and several earth radii, respectively. These tail flapping events generally last several hours and occur during quiet periods or periods of weak magnetospheric activity.

Development of a Prediction Model Based on RBF Neural Network for Sheet Metal Fixture Locating Layout Design and Optimization.

PubMed

Wang, Zhongqi; Yang, Bo; Kang, Yonggang; Yang, Yuan

2016-01-01

Fixture plays an important part in constraining excessive sheet metal part deformation at machining, assembly, and measuring stages during the whole manufacturing process. However, it is still a difficult and nontrivial task to design and optimize sheet metal fixture locating layout at present because there is always no direct and explicit expression describing sheet metal fixture locating layout and responding deformation. To that end, an RBF neural network prediction model is proposed in this paper to assist design and optimization of sheet metal fixture locating layout. The RBF neural network model is constructed by training data set selected by uniform sampling and finite element simulation analysis. Finally, a case study is conducted to verify the proposed method.

Development of a Prediction Model Based on RBF Neural Network for Sheet Metal Fixture Locating Layout Design and Optimization

PubMed Central

Wang, Zhongqi; Yang, Bo; Kang, Yonggang; Yang, Yuan

2016-01-01

Fixture plays an important part in constraining excessive sheet metal part deformation at machining, assembly, and measuring stages during the whole manufacturing process. However, it is still a difficult and nontrivial task to design and optimize sheet metal fixture locating layout at present because there is always no direct and explicit expression describing sheet metal fixture locating layout and responding deformation. To that end, an RBF neural network prediction model is proposed in this paper to assist design and optimization of sheet metal fixture locating layout. The RBF neural network model is constructed by training data set selected by uniform sampling and finite element simulation analysis. Finally, a case study is conducted to verify the proposed method. PMID:27127499

Method of high-density foil fabrication

DOEpatents

Blue, Craig A.; Sikka, Vinod K.; Ohriner, Evan K.

2003-12-16

A method for preparing flat foils having a high density includes the steps of mixing a powdered material with a binder to form a green sheet. The green sheet is exposed to a high intensity radiative source adapted to emit radiation of wavelengths corresponding to an absorption spectrum of the powdered material. The surface of the green sheet is heated while a lower sub-surface temperature is maintained. An apparatus for preparing a foil from a green sheet using a radiation source is also disclosed.

On the Reconstruction of Palaeo-Ice Sheets: Recent Advances and Future Challenges

NASA Technical Reports Server (NTRS)

Stokes, Chris R.; Tarasov, Lev; Blomdin, Robin; Cronin, Thomas M.; Fisher, Timothy G.; Gyllencreutz, Richard; Hattestrand, Clas; Heyman, Jacob; Hindmarsh, Richard C. A.; Hughes, Anna L. C.;

On the reconstruction of palaeo-ice sheets: Recent advances and future challenges

USGS Publications Warehouse

Stokes, Chris R.; Tarasov, Lev; Blomdin, Robin; Cronin, Thomas M.; Fisher, Timothy G.; Gyllencreutz, Richard; Hattestrand, Clas; Heyman, Jakob; Hindmarsh, Richard C. A.; Hughes, Anna L. C.; Jakobsson, Martin; Kirchner, Nina; Livingstone, Stephen J.; Margold, Martin; Murton, Julian B.; Noormets, Riko; Peltier, W. Richard; Peteet, Dorothy M.; Piper, David J. W.; Preusser, Frank; Renssen, Hans; Roberts, David H.; Roche, Didier M.; Saint-Ange, Francky; Stroeven, Arjen P.; Teller, James T.

2015-01-01

Reconstructing the growth and decay of palaeo-ice sheets is critical to understanding mechanisms of global climate change and associated sea-level fluctuations in the past, present and future. The significance of palaeo-ice sheets is further underlined by the broad range of disciplines concerned with reconstructing their behaviour, many of which have undergone a rapid expansion since the 1980s. In particular, there has been a major increase in the size and qualitative diversity of empirical data used to reconstruct and date ice sheets, and major improvements in our ability to simulate their dynamics in numerical ice sheet models. These developments have made it increasingly necessary to forge interdisciplinary links between sub-disciplines and to link numerical modelling with observations and dating of proxy records. The aim of this paper is to evaluate recent developments in the methods used to reconstruct ice sheets and outline some key challenges that remain, with an emphasis on how future work might integrate terrestrial and marine evidence together with numerical modelling. Our focus is on pan-ice sheet reconstructions of the last deglaciation, but regional case studies are used to illustrate methodological achievements, challenges and opportunities. Whilst various disciplines have made important progress in our understanding of ice-sheet dynamics, it is clear that data-model integration remains under-used, and that uncertainties remain poorly quantified in both empirically-based and numerical ice-sheet reconstructions. The representation of past climate will continue to be the largest source of uncertainty for numerical modelling. As such, palaeo-observations are critical to constrain and validate modelling. State-of-the-art numerical models will continue to improve both in model resolution and in the breadth of inclusion of relevant processes, thereby enabling more accurate and more direct comparison with the increasing range of palaeo-observations. Thus, the capability is developing to use all relevant palaeo-records to more strongly constrain deglacial (and to a lesser extent pre-LGM) ice sheet evolution. In working towards that goal, the accurate representation of uncertainties is required for both constraint data and model outputs. Close cooperation between modelling and data-gathering communities is essential to ensure this capability is realised and continues to progress.

Using ATM laser altimetry to constrain surface mass balance estimates and supraglacial hydrology of the Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Studinger, M.; Medley, B.; Manizade, S.; Linkswiler, M. A.

2016-12-01

Repeat airborne laser altimetry measurements can provide large-scale field observations to better quantify spatial and temporal variability of surface processes contributing to seasonal elevation change and therefore surface mass balance. As part of NASA's Operation IceBridge the Airborne Topographic Mapper (ATM) laser altimeter measured the surface elevation of the Greenland Ice Sheet during spring (March - May) and fall (September - October) of 2015. Comparison of the two surveys reveals a general trend of thinning for outlet glaciers and for the ice sheet in a manner related to elevation and latitude. In contrast, some thickening is observed on the west (but not on the east) side of the ice divide above 2200 m elevation in the southern half, below latitude 69°N.The observed magnitude and spatial patterns of the summer melt signal can be utilized as input into ice sheet models and for validating reanalysis of regional climate models such as RACMO and MAR. We use seasonal anomalies in MERRA-2 climate fields (temperature, precipitation) to understand the observed spatial signal in seasonal change. Aside from surface elevation change, runoff from meltwater pooling in supraglacial lakes and meltwater channels accounts for at least half of the total mass loss. The ability of the ATM laser altimeters to image glacial hydrological features in 3-D and determine the depth of supraglacial lakes could be used for process studies and for quantifying melt processes over large scales. The 1-meter footprint diameter of ATM laser on the surface, together with a high shot density, allows for the production of large-scale, high-resolution, geodetic quality DEMs (50 x 50 cm) suitable for fine-scale glacial hydrology research and as input to hydrological models quantifying runoff.

ColDICE: A parallel Vlasov–Poisson solver using moving adaptive simplicial tessellation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sousbie, Thierry, E-mail: tsousbie@gmail.com; Department of Physics, The University of Tokyo, Tokyo 113-0033; Research Center for the Early Universe, School of Science, The University of Tokyo, Tokyo 113-0033

2016-09-15

Resolving numerically Vlasov–Poisson equations for initially cold systems can be reduced to following the evolution of a three-dimensional sheet evolving in six-dimensional phase-space. We describe a public parallel numerical algorithm consisting in representing the phase-space sheet with a conforming, self-adaptive simplicial tessellation of which the vertices follow the Lagrangian equations of motion. The algorithm is implemented both in six- and four-dimensional phase-space. Refinement of the tessellation mesh is performed using the bisection method and a local representation of the phase-space sheet at second order relying on additional tracers created when needed at runtime. In order to preserve in the bestmore » way the Hamiltonian nature of the system, refinement is anisotropic and constrained by measurements of local Poincaré invariants. Resolution of Poisson equation is performed using the fast Fourier method on a regular rectangular grid, similarly to particle in cells codes. To compute the density projected onto this grid, the intersection of the tessellation and the grid is calculated using the method of Franklin and Kankanhalli [65–67] generalised to linear order. As preliminary tests of the code, we study in four dimensional phase-space the evolution of an initially small patch in a chaotic potential and the cosmological collapse of a fluctuation composed of two sinusoidal waves. We also perform a “warm” dark matter simulation in six-dimensional phase-space that we use to check the parallel scaling of the code.« less

Holocene deceleration of the Greenland Ice Sheet.

PubMed

MacGregor, Joseph A; Colgan, William T; Fahnestock, Mark A; Morlighem, Mathieu; Catania, Ginny A; Paden, John D; Gogineni, S Prasad

2016-02-05

Recent peripheral thinning of the Greenland Ice Sheet is partly offset by interior thickening and is overprinted on its poorly constrained Holocene evolution. On the basis of the ice sheet's radiostratigraphy, ice flow in its interior is slower now than the average speed over the past nine millennia. Generally higher Holocene accumulation rates relative to modern estimates can only partially explain this millennial-scale deceleration. The ice sheet's dynamic response to the decreasing proportion of softer ice from the last glacial period and the deglacial collapse of the ice bridge across Nares Strait also contributed to this pattern. Thus, recent interior thickening of the Greenland Ice Sheet is partly an ongoing dynamic response to the last deglaciation that is large enough to affect interpretation of its mass balance from altimetry. Copyright © 2016, American Association for the Advancement of Science.

Geothermal Heat Flux and Upper Mantle Viscosity across West Antarctica: Insights from the UKANET and POLENET Seismic Networks

NASA Astrophysics Data System (ADS)

O'Donnell, J. P.; Dunham, C.; Stuart, G. W.; Brisbourne, A.; Nield, G. A.; Whitehouse, P. L.; Hooper, A. J.; Nyblade, A.; Wiens, D.; Aster, R. C.; Anandakrishnan, S.; Huerta, A. D.; Wilson, T. J.; Winberry, J. P.

2017-12-01

Quantifying the geothermal heat flux at the base of ice sheets is necessary to understand their dynamics and evolution. The heat flux is a composite function of concentration of upper crustal radiogenic elements and flow of heat from the mantle into the crust. Radiogenic element concentration varies with tectonothermal age, while heat flow across the crust-mantle boundary depends on crustal and lithospheric thicknesses. Meanwhile, accurately monitoring current ice mass loss via satellite gravimetry or altimetry hinges on knowing the upper mantle viscosity structure needed to account for the superimposed glacial isostatic adjustment (GIA) signal in the satellite data. In early 2016 the UK Antarctic Network (UKANET) of 10 broadband seismometers was deployed for two years across the southern Antarctic Peninsula and Ellsworth Land. Using UKANET data in conjunction with seismic records from our partner US Polar Earth Observing Network (POLENET) and the Antarctic Seismographic Argentinian Italian Network (ASAIN), we have developed a 3D shear wave velocity model of the West Antarctic crust and uppermost mantle based on Rayleigh and Love wave phase velocity dispersion curves extracted from ambient noise cross-correlograms. We combine seismic receiver functions with the shear wave model to help constrain the depth to the crust-mantle boundary across West Antarctica and delineate tectonic domains. The shear wave model is subsequently converted to temperature using a database of densities and elastic properties of minerals common in crustal and mantle rocks, while the various tectonic domains are assigned upper crustal radiogenic element concentrations based on their inferred tectonothermal ages. We combine this information to map the basal geothermal heat flux variation across West Antarctica. Mantle viscosity depends on factors including temperature, grain size, the hydrogen content of olivine and the presence of melt. Using published mantle xenolith and magnetotelluric data to constrain grain size and hydrogen content, respectively, we use the temperature model to estimate the regional upper mantle viscosity structure. The viscosity information will be incorporated in a 3D GIA model that will better constrain estimates of current ice loss from the West Antarctic Ice Sheet.

Predicting pulsar scintillation from refractive plasma sheets

NASA Astrophysics Data System (ADS)

Simard, Dana; Pen, Ue-Li

2018-07-01

The dynamic and secondary spectra of many pulsars show evidence for long-lived, aligned images of the pulsar that are stationary on a thin scattering sheet. One explanation for this phenomenon considers the effects of wave crests along sheets in the ionized interstellar medium, such as those due to Alfvén waves propagating along current sheets. If these sheets are closely aligned to our line of sight to the pulsar, high bending angles arise at the wave crests and a selection effect causes alignment of images produced at different crests, similar to grazing reflection off of a lake. Using geometric optics, we develop a simple parametrized model of these corrugated sheets that can be constrained with a single observation and that makes observable predictions for variations in the scintillation of the pulsar over time and frequency. This model reveals qualitative differences between lensing from overdense and underdense corrugated sheets: only if the sheet is overdense compared to the surrounding interstellar medium can the lensed images be brighter than the line-of-sight image to the pulsar, and the faint lensed images are closer to the pulsar at higher frequencies if the sheet is underdense, but at lower frequencies if the sheet is overdense.

Predicting Pulsar Scintillation from Refractive Plasma Sheets

NASA Astrophysics Data System (ADS)

Simard, Dana; Pen, Ue-Li

2018-05-01

The dynamic and secondary spectra of many pulsars show evidence for long-lived, aligned images of the pulsar that are stationary on a thin scattering sheet. One explanation for this phenomenon considers the effects of wave crests along sheets in the ionized interstellar medium, such as those due to Alfvén waves propagating along current sheets. If these sheets are closely aligned to our line-of-sight to the pulsar, high bending angles arise at the wave crests and a selection effect causes alignment of images produced at different crests, similar to grazing reflection off of a lake. Using geometric optics, we develop a simple parameterized model of these corrugated sheets that can be constrained with a single observation and that makes observable predictions for variations in the scintillation of the pulsar over time and frequency. This model reveals qualitative differences between lensing from overdense and underdense corrugated sheets: Only if the sheet is overdense compared to the surrounding interstellar medium can the lensed images be brighter than the line-of-sight image to the pulsar, and the faint lensed images are closer to the pulsar at higher frequencies if the sheet is underdense, but at lower frequencies if the sheet is overdense.

Uncertainty quantification of Antarctic contribution to sea-level rise using the fast Elementary Thermomechanical Ice Sheet (f.ETISh) model

NASA Astrophysics Data System (ADS)

Bulthuis, Kevin; Arnst, Maarten; Pattyn, Frank; Favier, Lionel

2017-04-01

Uncertainties in sea-level rise projections are mostly due to uncertainties in Antarctic ice-sheet predictions (IPCC AR5 report, 2013), because key parameters related to the current state of the Antarctic ice sheet (e.g. sub-ice-shelf melting) and future climate forcing are poorly constrained. Here, we propose to improve the predictions of Antarctic ice-sheet behaviour using new uncertainty quantification methods. As opposed to ensemble modelling (Bindschadler et al., 2013) which provides a rather limited view on input and output dispersion, new stochastic methods (Le Maître and Knio, 2010) can provide deeper insight into the impact of uncertainties on complex system behaviour. Such stochastic methods usually begin with deducing a probabilistic description of input parameter uncertainties from the available data. Then, the impact of these input parameter uncertainties on output quantities is assessed by estimating the probability distribution of the outputs by means of uncertainty propagation methods such as Monte Carlo methods or stochastic expansion methods. The use of such uncertainty propagation methods in glaciology may be computationally costly because of the high computational complexity of ice-sheet models. This challenge emphasises the importance of developing reliable and computationally efficient ice-sheet models such as the f.ETISh ice-sheet model (Pattyn, 2015), a new fast thermomechanical coupled ice sheet/ice shelf model capable of handling complex and critical processes such as the marine ice-sheet instability mechanism. Here, we apply these methods to investigate the role of uncertainties in sub-ice-shelf melting, calving rates and climate projections in assessing Antarctic contribution to sea-level rise for the next centuries using the f.ETISh model. We detail the methods and show results that provide nominal values and uncertainty bounds for future sea-level rise as a reflection of the impact of the input parameter uncertainties under consideration, as well as a ranking of the input parameter uncertainties in the order of the significance of their contribution to uncertainty in future sea-level rise. In addition, we discuss how limitations posed by the available information (poorly constrained data) pose challenges that motivate our current research.

Inter-annual Variations in Snow/Firn Density over the Greenland Ice Sheet by Combining GRACE gravimetry and Envisat Altimetry

NASA Astrophysics Data System (ADS)

Su, X.; Shum, C. K.; Guo, J.; Howat, I.; Jezek, K. C.; Luo, Z.; Zhou, Z.

2017-12-01

Satellite altimetry has been used to monitor elevation and volume change of polar ice sheets since the 1990s. In order to derive mass change from the measured volume change, different density assumptions are commonly used in the research community, which may cause discrepancies on accurately estimating ice sheets mass balance. In this study, we investigate the inter-annual anomalies of mass change from GRACE gravimetry and elevation change from Envisat altimetry during years 2003-2009, with the objective of determining inter-annual variations of snow/firn density over the Greenland ice sheet (GrIS). High positive correlations (0.6 or higher) between these two inter-annual anomalies at are found over 93% of the GrIS, which suggests that both techniques detect the same geophysical process at the inter-annual timescale. Interpreting the two anomalies in terms of near surface density variations, over 80% of the GrIS, the inter-annual variation in average density is between the densities of snow and pure ice. In particular, at the Summit of Central Greenland, we validate the satellite data estimated density with the in situ data available from 75 snow pits and 9 ice cores. This study provides constraints on the currently applied density assumptions for the GrIS.

Surface Passivation by Quantum Exclusion Using Multiple Layers

NASA Technical Reports Server (NTRS)

Hoenk, Michael E. (Inventor)

2013-01-01

A semiconductor device has a multilayer doping to provide improved passivation by quantum exclusion. The multilayer doping includes a plurality M of doped layers, where M is an integer greater than 1. The dopant sheet densities in the M doped layers need not be the same, but in principle can be selected to be the same sheet densities or to be different sheet densities. M-1 interleaved layers provided between the M doped layers are not deliberately doped (also referred to as "undoped layers"). Structures with M=2, M=3 and M=4 have been demonstrated and exhibit improved passivation.

Use of a spread sheet to calculate the current-density distribution produced in human and rat models by low-frequency electric fields.

PubMed

Hart, F X

1990-01-01

The current-density distribution produced inside irregularly shaped, homogeneous human and rat models by low-frequency electric fields is obtained by a two-stage finite-difference procedure. In the first stage the model is assumed to be equipotential. Laplace's equation is solved by iteration in the external region to obtain the capacitive-current densities at the model's surface elements. These values then provide the boundary conditions for the second-stage relaxation solution, which yields the internal current-density distribution. Calculations were performed with the Excel spread-sheet program on a Macintosh-II microcomputer. A spread sheet is a two-dimensional array of cells. Each cell of the sheet can represent a square element of space. Equations relating the values of the cells can represent the relationships between the potentials in the corresponding spatial elements. Extension to three dimensions is readily made. Good agreement was obtained with current densities measured on human models with both, one, or no legs grounded and on rat models in four different grounding configurations. The results also compared well with predictions of more sophisticated numerical analyses. Spread sheets can provide an inexpensive and relatively simple means to perform good, approximate dosimetric calculations on irregularly shaped objects.

The extent and timing of the last British-Irish Ice Sheet offshore of west Ireland-preliminary findings

NASA Astrophysics Data System (ADS)

Peters, Jared; Benetti, Sara; Dunlop, Paul; Cofaigh, Colm Ó.

2014-05-01

Recently interpreted marine geophysical data from the western Irish shelf has provided the first direct evidence that the last British-Irish Ice Sheet (BIIS) extended westwards onto the Irish continental shelf as a grounded ice mass composed of several lobes with marine-terminating margins. Marine terminating ice margins are known to be sensitive to external forcing mechanisms and currently there is concern regarding the future stability of marine based ice sheets, such as the West Antarctic Ice Sheet, in a warming world. Given its position, the glaciated western Irish continental shelf is a prime location to investigate the processes of how marine-based ice sheets responded to past climatic and oceanic events, which may in turn help us better predict the future trajectory of the marine sectors of modern Ice Sheets. However, despite the potential importance of the former Irish ice margin to our understanding of ice sheet behaviour, the timing and nature of its advance and retreat is currently poorly understood. This study aims to describe the depositional history of the last BIIS on the continental shelf west of Ireland and age-constrain the rate of retreat of two ice lobes that extended from Galway Bay and Clew Bay. This is being accomplished through a multifaceted analysis of at least 29 sediment cores gathered across the continental shelf offshore of counties Galway and Mayo, Ireland. This poster shows results from initial sedimentological descriptions of cores from the mid to outer shelf, which support previous geomorphic interpretations of BIIS history. Preliminary palaeoenvironmental results from ongoing micropaleontological analyses are also discussed and provide new data that verifies sedimentary interpretations on ice proximity. Finally, results from several radiocarbon dates are discussed, which limit these deposits to the last glacial maximum and constrain the timings of ice advance and retreat on the continental shelf west of Ireland.

Stretched hydrogen molecule from a constrained-search density-functional perspective

DOE Office of Scientific and Technical Information (OSTI.GOV)

Valone, Steven M; Levy, Mel

2009-01-01

Constrained-search density functional theory gives valuable insights into the fundamentals of density functional theory. It provides exact results and bounds on the ground- and excited-state density functionals. An important advantage of the theory is that it gives guidance in the construction of functionals. Here they engage constrained search theory to explore issues associated with the functional behavior of 'stretched bonds' in molecular hydrogen. A constrained search is performed with familiar valence bond wavefunctions ordinarily used to describe molecular hydrogen. The effective, one-electron hamiltonian is computed and compared to the corresponding uncorrelated, Hartree-Fock effective hamiltonian. Analysis of the functional suggests themore » need to construct different functionals for the same density and to allow a competition among these functions. As a result the correlation energy functional is composed explicitly of energy gaps from the different functionals.« less

Exploring Explanations of Subglacial Bedform Sizes Using Statistical Models.

PubMed

Hillier, John K; Kougioumtzoglou, Ioannis A; Stokes, Chris R; Smith, Michael J; Clark, Chris D; Spagnolo, Matteo S

2016-01-01

Sediments beneath modern ice sheets exert a key control on their flow, but are largely inaccessible except through geophysics or boreholes. In contrast, palaeo-ice sheet beds are accessible, and typically characterised by numerous bedforms. However, the interaction between bedforms and ice flow is poorly constrained and it is not clear how bedform sizes might reflect ice flow conditions. To better understand this link we present a first exploration of a variety of statistical models to explain the size distribution of some common subglacial bedforms (i.e., drumlins, ribbed moraine, MSGL). By considering a range of models, constructed to reflect key aspects of the physical processes, it is possible to infer that the size distributions are most effectively explained when the dynamics of ice-water-sediment interaction associated with bedform growth is fundamentally random. A 'stochastic instability' (SI) model, which integrates random bedform growth and shrinking through time with exponential growth, is preferred and is consistent with other observations of palaeo-bedforms and geophysical surveys of active ice sheets. Furthermore, we give a proof-of-concept demonstration that our statistical approach can bridge the gap between geomorphological observations and physical models, directly linking measurable size-frequency parameters to properties of ice sheet flow (e.g., ice velocity). Moreover, statistically developing existing models as proposed allows quantitative predictions to be made about sizes, making the models testable; a first illustration of this is given for a hypothesised repeat geophysical survey of bedforms under active ice. Thus, we further demonstrate the potential of size-frequency distributions of subglacial bedforms to assist the elucidation of subglacial processes and better constrain ice sheet models.

Capturing total chronological and spatial uncertainties in palaeo-ice sheet reconstructions: the DATED example

NASA Astrophysics Data System (ADS)

Hughes, Anna; Gyllencreutz, Richard; Mangerud, Jan; Svendsen, John Inge

2017-04-01

Glacial geologists generate empirical reconstructions of former ice-sheet dynamics by combining evidence from the preserved record of glacial landforms (e.g. end moraines, lineations) and sediments with chronological evidence (mainly numerical dates derived predominantly from radiocarbon, exposure and luminescence techniques). However the geomorphological and sedimentological footprints and chronological data are both incomplete records in both space and time, and all have multiple types of uncertainty associated with them. To understand ice sheets' response to climate we need numerical models of ice-sheet dynamics based on physical principles. To test and/or constrain such models, empirical reconstructions of past ice sheets that capture and acknowledge all uncertainties are required. In 2005 we started a project (Database of the Eurasian Deglaciation, DATED) to produce an empirical reconstruction of the evolution of the last Eurasian ice sheets, (including the British-Irish, Scandinavian and Svalbard-Barents-Kara Seas ice sheets) that is fully documented, specified in time, and includes uncertainty estimates. Over 5000 dates relevant to constraining ice build-up and retreat were assessed for reliability and used together with published ice-sheet margin positions based on glacial geomorphology to reconstruct time-slice maps of the ice sheets' extent. The DATED maps show synchronous ice margins with maximum-minimum uncertainty bounds for every 1000 years between 25-10 kyr ago. In the first version of results (DATED-1; Hughes et al. 2016) all uncertainties (both quantitative and qualitative, e.g. precision and accuracy of numerical dates, correlation of moraines, stratigraphic interpretations) were combined based on our best glaciological-geological assessment and expressed in terms of distance as a 'fuzzy' margin. Large uncertainties (>100 km) exist; predominantly across marine sectors and other locations where there are spatial gaps in the dating record (e.g. the timing of coalescence and separation of the Scandinavian and Svalbard-Barents-Kara ice sheets) but also in well-studied areas due to conflicting yet apparently equally robust data. In the four years since the DATED-1 census (1 January 2013), the volume of new information (from both dates and mapped glacial geomorphology) has grown significantly ( 1000 new dates). Here, we present work towards the updated version of results, DATED-2, that attempts to further reduce and explicitly report all uncertainties inherent in ice sheet reconstructions. Hughes, A. L. C., Gyllencreutz, R., Lohne, Ø. S., Mangerud, J., Svendsen, J. I. 2016: The last Eurasian ice sheets - a chronological database and time-slice reconstruction, DATED-1. Boreas, 45, 1-45. 10.1111/bor.12142

Meltwater storage in low-density near-surface bare ice in the Greenland ice sheet ablation zone

NASA Astrophysics Data System (ADS)

Cooper, Matthew G.; Smith, Laurence C.; Rennermalm, Asa K.; Miège, Clément; Pitcher, Lincoln H.; Ryan, Jonathan C.; Yang, Kang; Cooley, Sarah W.

2018-03-01

We document the density and hydrologic properties of bare, ablating ice in a mid-elevation (1215 m a.s.l.) supraglacial internally drained catchment in the Kangerlussuaq sector of the western Greenland ice sheet. We find low-density (0.43-0.91 g cm-3, μ = 0.69 g cm-3) ice to at least 1.1 m depth below the ice sheet surface. This near-surface, low-density ice consists of alternating layers of water-saturated, porous ice and clear solid ice lenses, overlain by a thin (< 0.5 m), even lower density (0.33-0.56 g cm-3, μ = 0.45 g cm-3) unsaturated weathering crust. Ice density data from 10 shallow (0.9-1.1 m) ice cores along an 800 m transect suggest an average 14-18 cm of specific meltwater storage within this low-density ice. Water saturation of this ice is confirmed through measurable water levels (1-29 cm above hole bottoms, μ = 10 cm) in 84 % of cryoconite holes and rapid refilling of 83 % of 1 m drilled holes sampled along the transect. These findings are consistent with descriptions of shallow, depth-limited aquifers on the weathered surface of glaciers worldwide and confirm the potential for substantial transient meltwater storage within porous low-density ice on the Greenland ice sheet ablation zone surface. A conservative estimate for the ˜ 63 km2 supraglacial catchment yields 0.009-0.012 km3 of liquid meltwater storage in near-surface, porous ice. Further work is required to determine if these findings are representative of broader areas of the Greenland ice sheet ablation zone, and to assess the implications for sub-seasonal mass balance processes, surface lowering observations from airborne and satellite altimetry, and supraglacial runoff processes.

Evaluation of gravitational gradients generated by Earth's crustal structures

NASA Astrophysics Data System (ADS)

Novák, Pavel; Tenzer, Robert; Eshagh, Mehdi; Bagherbandi, Mohammad

2013-02-01

Spectral formulas for the evaluation of gravitational gradients generated by upper Earth's mass components are presented in the manuscript. The spectral approach allows for numerical evaluation of global gravitational gradient fields that can be used to constrain gravitational gradients either synthesised from global gravitational models or directly measured by the spaceborne gradiometer on board of the GOCE satellite mission. Gravitational gradients generated by static atmospheric, topographic and continental ice masses are evaluated numerically based on available global models of Earth's topography, bathymetry and continental ice sheets. CRUST2.0 data are then applied for the numerical evaluation of gravitational gradients generated by mass density contrasts within soft and hard sediments, upper, middle and lower crust layers. Combined gravitational gradients are compared to disturbing gravitational gradients derived from a global gravitational model and an idealised Earth's model represented by the geocentric homogeneous biaxial ellipsoid GRS80. The methodology could be used for improved modelling of the Earth's inner structure.

Engineering tubular bone using mesenchymal stem cell sheets and coral particles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Geng, Wenxin; Ma, Dongyang; Yan, Xingrong

Highlights: • We developed a novel engineering strategy to solve the limitations of bone grafts. • We fabricated tubular constructs using cell sheets and coral particles. • The composite constructs showed high radiological density and compressive strength. • These characteristics were similar to those of native bone. -- Abstract: The development of bone tissue engineering has provided new solutions for bone defects. However, the cell-scaffold-based approaches currently in use have several limitations, including low cell seeding rates and poor bone formation capacity. In the present study, we developed a novel strategy to engineer bone grafts using mesenchymal stem cell sheetsmore » and coral particles. Rabbit bone marrow mesenchymal stem cells were continuously cultured to form a cell sheet with osteogenic potential and coral particles were integrated into the sheet. The composite sheet was then wrapped around a cylindrical mandrel to fabricate a tubular construct. The resultant tubular construct was cultured in a spinner-flask bioreactor and subsequently implanted into a subcutaneous pocket in a nude mouse for assessment of its histological characteristics, radiological density and mechanical property. A similar construct assembled from a cell sheet alone acted as a control. In vitro observations demonstrated that the composite construct maintained its tubular shape, and exhibited higher radiological density, compressive strength and greater extracellular matrix deposition than did the control construct. In vivo experiments further revealed that new bone formed ectopically on the composite constructs, so that the 8-week explants of the composite sheets displayed radiological density similar to that of native bone. These results indicate that the strategy of using a combination of a cell sheet and coral particles has great potential for bone tissue engineering and repairing bone defects.« less

Plasma sheet density dependence on Interplanetary Magnetic Field and Solar Wind properties: statistical study using 9+ year of THEMIS data

NASA Astrophysics Data System (ADS)

Nykyri, K.; Chu, C.; Dimmock, A. P.

2017-12-01

Previous studies have shown that plasma sheet in tenuous and hot during southward IMF, whereas northward IMF conditions are associated with cold, dense plasma. The cold, dense plasma sheet (CDPS) has strong influence on magnetospheric dynamics. Closer to Earth, the CDPS could be formed via double high-latitude reconnection, while at increasing tailward distance reconnection, diffusion and kinetic Alfven waves in association with Kelvin-Helmholtz Instability are suggested as dominant source for cold-dense plasma sheet formation. In this paper we present statistical correlation study between Solar Wind, Magnetosheath and Plasma sheet properties using 9+ years of THEMIS data in aberrated GSM frame, and in a normalized coordinate system that takes into account the changes of the magnetopause and bow shock location with respect to changing solar wind conditions. We present statistical results of the plasma sheet density dependence on IMF orientation and other solar wind properties.

Structural and Electronic Properties of α2-Graphyne Nanotubes: A Density Functional Theory Study

NASA Astrophysics Data System (ADS)

Majidi, Roya

2018-02-01

Another form of carbon-based two-dimensional material in the graphene family, named the α2-graphyne sheet, was predicted very recently. The α2-graphyne sheet was created by doubling each acetylenic linker in an α-graphyne sheet. It exhibited semimetallic Dirac point features similar to graphene and α-graphyne sheets. In the present work, single -walled carbon nanotubes based on an α2-graphyne sheet was introduced. The structural and electronic properties of these nanotubes were studied using density functional theory. It was found that armchair α2-graphyne nanotubes showed metallic behavior, while zigzag α2-graphyne nanotubes were found to have semiconducting or metallic properties depending on tube size. The energy band gap of zigzag α2-graphyne nanotubes decreased with increasing tube diameter. The results indicated that the α2-graphyne sheet and its nanotubes can be proper materials for future nanoelectronics.

Exploring Explanations of Subglacial Bedform Sizes Using Statistical Models

PubMed Central

Kougioumtzoglou, Ioannis A.; Stokes, Chris R.; Smith, Michael J.; Clark, Chris D.; Spagnolo, Matteo S.

2016-01-01

Sediments beneath modern ice sheets exert a key control on their flow, but are largely inaccessible except through geophysics or boreholes. In contrast, palaeo-ice sheet beds are accessible, and typically characterised by numerous bedforms. However, the interaction between bedforms and ice flow is poorly constrained and it is not clear how bedform sizes might reflect ice flow conditions. To better understand this link we present a first exploration of a variety of statistical models to explain the size distribution of some common subglacial bedforms (i.e., drumlins, ribbed moraine, MSGL). By considering a range of models, constructed to reflect key aspects of the physical processes, it is possible to infer that the size distributions are most effectively explained when the dynamics of ice-water-sediment interaction associated with bedform growth is fundamentally random. A ‘stochastic instability’ (SI) model, which integrates random bedform growth and shrinking through time with exponential growth, is preferred and is consistent with other observations of palaeo-bedforms and geophysical surveys of active ice sheets. Furthermore, we give a proof-of-concept demonstration that our statistical approach can bridge the gap between geomorphological observations and physical models, directly linking measurable size-frequency parameters to properties of ice sheet flow (e.g., ice velocity). Moreover, statistically developing existing models as proposed allows quantitative predictions to be made about sizes, making the models testable; a first illustration of this is given for a hypothesised repeat geophysical survey of bedforms under active ice. Thus, we further demonstrate the potential of size-frequency distributions of subglacial bedforms to assist the elucidation of subglacial processes and better constrain ice sheet models. PMID:27458921

Application of sintered titanium alloys to metal denture bases: a study of titanium powder sheets for complete denture base.

PubMed

Doi, H; Harrori, M; Hasegawa, K; Yoshinari, M; Kawada, E; Oda, Y

2001-02-01

The purpose of this study was the fabrication of titanium powder sheets to enable the application of sintered titanium alloys as metal denture bases. The effects of titanium particle shape and size, binder content, and plasticizer content on the surface smoothness, tensile strength and elongation of titanium powder sheets was investigated. To select a suitable ratio of powdered metal contents for application as a metal denture base, the effects of aluminum content in Ti sheets and various other powder metal contents in Ti-Al sheets on the density, sintering shrinkage, and bending strength were evaluated. Based on the results of the above experiments, we developed a mixed powder sheet composed of 83Ti-7Al-10Cr with TA45 titanium powder (atomized, -45 microm), and 8 mass% binder content. This titanium alloy sheet had good formability and ductility. Its sintered titanium alloy had a density of 3.2 g/cm3, sintering shrinkage of 3.8%, and bending strength of 403 MPa. The titanium alloy sheet is clinically acceptable for fabricating denture bases.

Linear Tidal Vestige Found in the WM Sheet

NASA Astrophysics Data System (ADS)

Lee, Jounghun; Kim, Suk; Rey, Soo-Chang

2018-06-01

We present a vestige of the linear tidal influence on the spin orientations of the constituent galaxies of the WM sheet discovered in the vicinity of the Virgo Cluster and the Local Void. The WM sheet is chosen as an optimal target since it has a rectangular parallelepiped-like shape whose three sides are in parallel with the supergalactic Cartesian axes. Determining three probability density functions of the absolute values of the supergalactic Cartesian components of the spin vectors of the WM sheet galaxies, we investigate their alignments with the principal directions of the surrounding large-scale tidal field. When the WM sheet galaxies located in the central region within the distance of 2 h ‑1 Mpc are excluded, the spin vectors of the remaining WM sheet galaxies are found to be weakly aligned, strongly aligned, and strongly anti-aligned with the minor, intermediate, and major principal directions of the surrounding large-scale tidal field, respectively. To examine whether or not the origin of the observed alignment tendency from the WM sheet is the linear tidal effect, we infer the eigenvalues of the linear tidal tensor from the axial ratios of the WM sheet with the help of the Zeldovich approximation and conduct a full analytic evaluation of the prediction of the linear tidal torque model for the three probability density functions. A detailed comparison between the analytical and the observational results reveals a good quantitative agreement not only in the behaviors but also in the amplitudes of the three probability density functions.

Spin-density wave state in simple hexagonal graphite

NASA Astrophysics Data System (ADS)

Mosoyan, K. S.; Rozhkov, A. V.; Sboychakov, A. O.; Rakhmanov, A. L.

2018-02-01

Simple hexagonal graphite, also known as AA graphite, is a metastable configuration of graphite. Using tight-binding approximation, it is easy to show that AA graphite is a metal with well-defined Fermi surface. The Fermi surface consists of two sheets, each shaped like a rugby ball. One sheet corresponds to electron states, another corresponds to hole states. The Fermi surface demonstrates good nesting: a suitable translation in the reciprocal space superposes one sheet onto another. In the presence of the electron-electron repulsion, a nested Fermi surface is unstable with respect to spin-density-wave ordering. This instability is studied using the mean-field theory at zero temperature, and the spin-density-wave order parameter is evaluated.

Modeling of Firn Compaction for Estimating Ice-Sheet Mass Change from Observed Ice-Sheet Elevation Change

NASA Technical Reports Server (NTRS)

Li, Jun; Zwally, H. Jay

2011-01-01

Changes in ice-sheet surface elevation are caused by a combination of ice-dynamic imbalance, ablation, temporal variations in accumulation rate, firn compaction and underlying bedrock motion. Thus, deriving the rate of ice-sheet mass change from measured surface elevation change requires information on the rate of firn compaction and bedrock motion, which do not involve changes in mass, and requires an appropriate firn density to associate with elevation changes induced by recent accumulation rate variability. We use a 25 year record of surface temperature and a parameterization for accumulation change as a function of temperature to drive a firn compaction model. We apply this formulation to ICESat measurements of surface elevation change at three locations on the Greenland ice sheet in order to separate the accumulation-driven changes from the ice-dynamic/ablation-driven changes, and thus to derive the corresponding mass change. Our calculated densities for the accumulation-driven changes range from 410 to 610 kg/cu m, which along with 900 kg/cu m for the dynamic/ablation-driven changes gives average densities ranging from 680 to 790 kg/cu m. We show that using an average (or "effective") density to convert elevation change to mass change is not valid where the accumulation and the dynamic elevation changes are of opposite sign.

Sediment movement and dispersal patterns on the Grand Banks continental shelf and slope were tied to the dynamics of the Laurentide ice-sheet margin

NASA Astrophysics Data System (ADS)

Rashid, H.; MacKillop, K.; Piper, D.; Vermooten, M.; Higgins, J.; Marche, B.; Langer, K.; Brockway, B.; Spicer, H. E.; Webb, M. D.; Fournier, E.

2015-12-01

The expansion and contraction of the late Pleistocene Laurentide ice-sheet (LIS) was the crucial determining factor for the geomorphic features and shelf and slope sediment mobility on the eastern Canadian continental margin, with abundant mass-transport deposits (MTDs) seaward of ice margins on the upper slope. Here, we report for the first time sediment failure and mass-transport deposits from the central Grand Banks slope in the Salar and Carson petroleum basins. High-resolution seismic profiles and multibeam bathymetry show numerous sediment failure scarps in 500-1600 m water depth. There is no evidence for an ice margin on the upper slope younger than MIS 6. Centimeter-scale X-ray fluorescence analysis (XRF), grain size, and oxygen isotope data from piston cores constrain sediment processes over the past 46 ka. Geotechnical measurements including Atterberg limit tests, vane shear measurements and triaxial and multi-stage isotropic consolidation tests allowed us to assess the instability on the continental margin. Cores with continuous undisturbed stratigraphy in contourite silty muds show normal downcore increase in bulk density and undrained peak shear strength. Heinrich (H) layers are identifiable by a marked increase in the bulk density, high Ca (ppm), increase in iceberg-rafted debris and lighter δ18O in the polar planktonic foram Neogloboquadrina pachyderma (sinistral): with a few C-14 dates they provide a robust chronology. There is no evidence for significant supply of sediment from the Grand Banks at the last-glacial maximum. Mass-transport deposits (MTD) are marked by variability in the bulk density, undrained shear strength and little variation in bulk density or Ca (ppm) values. The MTD are older than 46 ka on the central Grand Banks slope, whereas younger MTDs are present in southern Flemish Pass. Factor of safety calculations suggest the slope is statically stable up to gradients of 10°, but more intervals of silty mud may fail during earthquake-induced cyclic loading based on Atterberg tests. By analogy with the Holocene, contourites deposited in MIS 5e may be particularly silty and form a "weak layer" susceptible to failure.

MIS-11 duration key to disappearance of the Greenland ice sheet

NASA Astrophysics Data System (ADS)

Robinson, Alexander; Alvarez-Solas, Jorge; Calov, Reinhard; Ganopolski, Andrey; Montoya, Marisa

2017-07-01

Palaeo data suggest that Greenland must have been largely ice free during Marine Isotope Stage 11 (MIS-11). However, regional summer insolation anomalies were modest during this time compared to MIS-5e, when the Greenland ice sheet likely lost less volume. Thus it remains unclear how such conditions led to an almost complete disappearance of the ice sheet. Here we use transient climate-ice sheet simulations to simultaneously constrain estimates of regional temperature anomalies and Greenland's contribution to the MIS-11 sea-level highstand. We find that Greenland contributed 6.1 m (3.9-7.0 m, 95% credible interval) to sea level, ~7 kyr after the peak in regional summer temperature anomalies of 2.8 °C (2.1-3.4 °C). The moderate warming produced a mean rate of mass loss in sea-level equivalent of only around 0.4 m per kyr, which means the long duration of MIS-11 interglacial conditions around Greenland was a necessary condition for the ice sheet to disappear almost completely.

Hypsometric amplification and routing moderation of Greenland ice sheet meltwater release

NASA Astrophysics Data System (ADS)

van As, Dirk; Mikkelsen, Andreas Bech; Holtegaard Nielsen, Morten; Box, Jason E.; Claesson Liljedahl, Lillemor; Lindbäck, Katrin; Pitcher, Lincoln; Hasholt, Bent

2017-06-01

Concurrent ice sheet surface runoff and proglacial discharge monitoring are essential for understanding Greenland ice sheet meltwater release. We use an updated, well-constrained river discharge time series from the Watson River in southwest Greenland, with an accurate, observation-based ice sheet surface mass balance model of the ˜ 12 000 km2 ice sheet area feeding the river. For the 2006-2015 decade, we find a large range of a factor of 3 in interannual variability in discharge. The amount of discharge is amplified ˜ 56 % by the ice sheet's hypsometry, i.e., area increase with elevation. A good match between river discharge and ice sheet surface meltwater production is found after introducing elevation-dependent transit delays that moderate diurnal variability in meltwater release by a factor of 10-20. The routing lag time increases with ice sheet elevation and attains values in excess of 1 week for the upper reaches of the runoff area at ˜ 1800 m above sea level. These multi-day routing delays ensure that the highest proglacial discharge levels and thus overbank flooding events are more likely to occur after multi-day melt episodes. Finally, for the Watson River ice sheet catchment, we find no evidence of meltwater storage in or release from the en- and subglacial environments in quantities exceeding our methodological uncertainty, based on the good match between ice sheet runoff and proglacial discharge.

A Bayesian Retrieval of Greenland Ice Sheet Internal Temperature from Ultra-wideband Software-defined Microwave Radiometer (UWBRAD) Measurements

NASA Astrophysics Data System (ADS)

Duan, Y.; Durand, M. T.; Jezek, K. C.; Yardim, C.; Bringer, A.; Aksoy, M.; Johnson, J. T.

2017-12-01

The ultra-wideband software-defined microwave radiometer (UWBRAD) is designed to provide ice sheet internal temperature product via measuring low frequency microwave emission. Twelve channels ranging from 0.5 to 2.0 GHz are covered by the instrument. A Greenland air-borne demonstration was demonstrated in September 2016, provided first demonstration of Ultra-wideband radiometer observations of geophysical scenes, including ice sheets. Another flight is planned for September 2017 for acquiring measurements in central ice sheet. A Bayesian framework is designed to retrieve the ice sheet internal temperature from simulated UWBRAD brightness temperature (Tb) measurements over Greenland flight path with limited prior information of the ground. A 1-D heat-flow model, the Robin Model, was used to model the ice sheet internal temperature profile with ground information. Synthetic UWBRAD Tb observations was generated via the partially coherent radiation transfer model, which utilizes the Robin model temperature profile and an exponential fit of ice density from Borehole measurement as input, and corrupted with noise. The effective surface temperature, geothermal heat flux, the variance of upper layer ice density, and the variance of fine scale density variation at deeper ice sheet were treated as unknown variables within the retrieval framework. Each parameter is defined with its possible range and set to be uniformly distributed. The Markov Chain Monte Carlo (MCMC) approach is applied to make the unknown parameters randomly walk in the parameter space. We investigate whether the variables can be improved over priors using the MCMC approach and contribute to the temperature retrieval theoretically. UWBRAD measurements near camp century from 2016 was also treated with the MCMC to examine the framework with scattering effect. The fine scale density fluctuation is an important parameter. It is the most sensitive yet highly unknown parameter in the estimation framework. Including the fine scale density fluctuation greatly improved the retrieval results. The ice sheet vertical temperature profile, especially the 10m temperature, can be well retrieved via the MCMC process. Future retrieval work will apply the Bayesian approach to UWBRAD airborne measurements.

SEA-LEVEL RISE. Sea-level rise due to polar ice-sheet mass loss during past warm periods.

PubMed

Dutton, A; Carlson, A E; Long, A J; Milne, G A; Clark, P U; DeConto, R; Horton, B P; Rahmstorf, S; Raymo, M E

2015-07-10

Interdisciplinary studies of geologic archives have ushered in a new era of deciphering magnitudes, rates, and sources of sea-level rise from polar ice-sheet loss during past warm periods. Accounting for glacial isostatic processes helps to reconcile spatial variability in peak sea level during marine isotope stages 5e and 11, when the global mean reached 6 to 9 meters and 6 to 13 meters higher than present, respectively. Dynamic topography introduces large uncertainties on longer time scales, precluding robust sea-level estimates for intervals such as the Pliocene. Present climate is warming to a level associated with significant polar ice-sheet loss in the past. Here, we outline advances and challenges involved in constraining ice-sheet sensitivity to climate change with use of paleo-sea level records. Copyright © 2015, American Association for the Advancement of Science.

A model of the Greenland ice sheet deglaciation

NASA Astrophysics Data System (ADS)

Lecavalier, Benoit

The goal of this thesis is to improve our understanding of the Greenland ice sheet (GrIS) and how it responds to climate change. This was achieved using ice core records to infer elevation changes of the GrIS during the Holocene (11.7 ka BP to Present). The inferred elevation changes show the response of the ice sheet interior to the Holocene Thermal Maximum (HTM; 9-5 ka BP) when temperatures across Greenland were warmer than present. These ice-core derived thinning curves act as a new set of key constraints on the deglacial history of the GrIS. Furthermore, a calibration was conducted on a three-dimensional thermomechanical ice sheet, glacial isostatic adjustment, and relative sea-level model of GrIS evolution during the most recent deglaciation (21 ka BP to present). The model was data-constrained to a variety of proxy records from paleoclimate archives and present-day observations of ice thickness and extent.

Evidence for the stability of the West Antarctic Ice Sheet divide for 1.4 million years

NASA Astrophysics Data System (ADS)

Hein, Andrew S.; Woodward, John; Marrero, Shasta M.; Dunning, Stuart A.; Steig, Eric J.; Freeman, Stewart P. H. T.; Stuart, Finlay M.; Winter, Kate; Westoby, Matthew J.; Sugden, David E.

2016-02-01

Past fluctuations of the West Antarctic Ice Sheet (WAIS) are of fundamental interest because of the possibility of WAIS collapse in the future and a consequent rise in global sea level. However, the configuration and stability of the ice sheet during past interglacial periods remains uncertain. Here we present geomorphological evidence and multiple cosmogenic nuclide data from the southern Ellsworth Mountains to suggest that the divide of the WAIS has fluctuated only modestly in location and thickness for at least the last 1.4 million years. Fluctuations during glacial-interglacial cycles appear superimposed on a long-term trajectory of ice-surface lowering relative to the mountains. This implies that as a minimum, a regional ice sheet centred on the Ellsworth-Whitmore uplands may have survived Pleistocene warm periods. If so, it constrains the WAIS contribution to global sea level rise during interglacials to about 3.3 m above present.

Greenland-Wide Seasonal Temperatures During the Last Deglaciation

NASA Astrophysics Data System (ADS)

Buizert, C.; Keisling, B. A.; Box, J. E.; He, F.; Carlson, A. E.; Sinclair, G.; DeConto, R. M.

2018-02-01

The sensitivity of the Greenland ice sheet to climate forcing is of key importance in assessing its contribution to past and future sea level rise. Surface mass loss occurs during summer, and accounting for temperature seasonality is critical in simulating ice sheet evolution and in interpreting glacial landforms and chronologies. Ice core records constrain the timing and magnitude of climate change but are largely limited to annual mean estimates from the ice sheet interior. Here we merge ice core reconstructions with transient climate model simulations to generate Greenland-wide and seasonally resolved surface air temperature fields during the last deglaciation. Greenland summer temperatures peak in the early Holocene, consistent with records of ice core melt layers. We perform deglacial Greenland ice sheet model simulations to demonstrate that accounting for realistic temperature seasonality decreases simulated glacial ice volume, expedites the deglacial margin retreat, mutes the impact of abrupt climate warming, and gives rise to a clear Holocene ice volume minimum.

An overview of a highly versatile forward and stable inverse algorithm for airborne, ground-based and borehole electromagnetic and electric data

NASA Astrophysics Data System (ADS)

Auken, Esben; Christiansen, Anders Vest; Kirkegaard, Casper; Fiandaca, Gianluca; Schamper, Cyril; Behroozmand, Ahmad Ali; Binley, Andrew; Nielsen, Emil; Effersø, Flemming; Christensen, Niels Bøie; Sørensen, Kurt; Foged, Nikolaj; Vignoli, Giulio

2015-07-01

We present an overview of a mature, robust and general algorithm providing a single framework for the inversion of most electromagnetic and electrical data types and instrument geometries. The implementation mainly uses a 1D earth formulation for electromagnetics and magnetic resonance sounding (MRS) responses, while the geoelectric responses are both 1D and 2D and the sheet's response models a 3D conductive sheet in a conductive host with an overburden of varying thickness and resistivity. In all cases, the focus is placed on delivering full system forward modelling across all supported types of data. Our implementation is modular, meaning that the bulk of the algorithm is independent of data type, making it easy to add support for new types. Having implemented forward response routines and file I/O for a given data type provides access to a robust and general inversion engine. This engine includes support for mixed data types, arbitrary model parameter constraints, integration of prior information and calculation of both model parameter sensitivity analysis and depth of investigation. We present a review of our implementation and methodology and show four different examples illustrating the versatility of the algorithm. The first example is a laterally constrained joint inversion (LCI) of surface time domain induced polarisation (TDIP) data and borehole TDIP data. The second example shows a spatially constrained inversion (SCI) of airborne transient electromagnetic (AEM) data. The third example is an inversion and sensitivity analysis of MRS data, where the electrical structure is constrained with AEM data. The fourth example is an inversion of AEM data, where the model is described by a 3D sheet in a layered conductive host.

History of the Greenland Ice Sheet: paleoclimatic insights

USGS Publications Warehouse

Alley, Richard B.; Andrews, John T.; Brigham-Grette, J.; Clarke, G.K.C.; Cuffey, Kurt M.; Fitzpatrick, J.J.; Funder, S.; Marshall, S.J.; Miller, G.H.; Mitrovica, J.X.; Muhs, D.R.; Otto-Bliesner, B. L.; Polyak, L.; White, J.W.C.

2010-01-01

Paleoclimatic records show that the GreenlandIce Sheet consistently has lost mass in response to warming, and grown in response to cooling. Such changes have occurred even at times of slow or zero sea-level change, so changing sea level cannot have been the cause of at least some of the ice-sheet changes. In contrast, there are no documented major ice-sheet changes that occurred independent of temperature changes. Moreover, snowfall has increased when the climate warmed, but the ice sheet lost mass nonetheless; increased accumulation in the ice sheet's center has not been sufficient to counteract increased melting and flow near the edges. Most documented forcings and ice-sheet responses spanned periods of several thousand years, but limited data also show rapid response to rapid forcings. In particular, regions near the ice margin have responded within decades. However, major changes of central regions of the ice sheet are thought to require centuries to millennia. The paleoclimatic record does not yet strongly constrain how rapidly a major shrinkage or nearly complete loss of the ice sheet could occur. The evidence suggests nearly total ice-sheet loss may result from warming of more than a few degrees above mean 20th century values, but this threshold is poorly defined (perhaps as little as 2 °C or more than 7 °C). Paleoclimatic records are sufficiently sketchy that the ice sheet may have grown temporarily in response to warming, or changes may have been induced by factors other than temperature, without having been recorded.

Quantitative analysis of defects in silicon. Silicon sheet growth development for the large are silicon sheet task of the low-cost solar array project

NASA Technical Reports Server (NTRS)

Natesh, R.; Smith, J. M.; Bruce, T.; Oidwai, H. A.

1980-01-01

One hundred and seventy four silicon sheet samples were analyzed for twin boundary density, dislocation pit density, and grain boundary length. Procedures were developed for the quantitative analysis of the twin boundary and dislocation pit densities using a QTM-720 Quantitative Image Analyzing system. The QTM-720 system was upgraded with the addition of a PDP 11/03 mini-computer with dual floppy disc drive, a digital equipment writer high speed printer, and a field-image feature interface module. Three versions of a computer program that controls the data acquisition and analysis on the QTM-720 were written. Procedures for the chemical polishing and etching were also developed.

Understanding ice sheet evolution to avoid massive sea level rise instead of experiencing it (Louis Agassiz Medal Lecture)

NASA Astrophysics Data System (ADS)

Rignot, Eric

2017-04-01

With unabated climate warming, massive sea level rise from the melting of ice sheets in Greenland and Antarctica looms at the horizon. This is unfortunately an experiment that we can afford to run only once. Satellite and airborne sensors have significantly helped reveal the magnitude of the mass balance of the ice sheets, where the changes take place, when they started, how they change with time and the nature of the physical processes controlling them. These observations have constrained the maturation of numerical modeling techniques for projecting changes in these ice sheets, including the coupling of ocean and ice sheet models, yet significant uncertainties remain to make these projections directly policy relevant and many challenges remain. I will review the state of balance of the ice sheets as we know it today and the fundamental processes that will drive fast ice sheet retreat and sea level change: ice-ocean interaction and iceberg calving. Ice-ocean interaction are dominated by the wind-forced intrusion of warm, salty, subsurface waters toward the ice sheet periphery to melt ice from below at rates orders of magnitude greater than at the surface. In Greenland, these rates are difficult to observe, but model simulations indicate rates of ice melt along vertical calving faces of meters per day, along with undercutting of the ice faces. Constraining the temperature of the ocean waters from high resolution models and observations, however, remains a significant challenge. I will describe the progress we have made in addressing one major issue which is the mapping of fjord bathymetry around Greenland to define the pathways for warm waters. In Antarctica, the rates of melt are measured from remote sensing data but averaged over long periods, so that we are dependent on in-situ observations to understand the interaction of ocean waters with ice within the sub-ice-shelf cavities. I will describe progress made in mapping the bathymetry of the ice shelves and how the results have impacted our understanding of these interactions. In terms of calving, there is a range of processes acting upon the glacier and ice shelf faces, proceeding from the surface and mostly from below, that are still not sufficiently well explored. I will discuss processes elucidated in Greenland (undercutting and rotation of ice blocks near floatation) and those that are not well known in Antarctica.

A first-principles study on adsorption behaviors of pristine and Li-decorated graphene sheets toward hydrazine molecules

NASA Astrophysics Data System (ADS)

Zeng, Huadong; Cheng, Xinlu; Wang, Wei

2018-03-01

The adsorption behaviors and properties of hydrazine (N2H4) molecules on pristine and Li-decorated graphene sheets were investigated by means of first-principles based on density functional theory. We systematically analyzed the optimal geometry, average binding energy, charge transfer, charge density difference and density of states of N2H4 molecules adsorbed on pristine and Li-decorated graphene sheets. It is found that the interaction between single N2H4 molecule and pristine graphene is weak physisorption with the low binding energy of -0.026 eV, suggesting that the pristine graphene sheet is insensitive to the presence of N2H4 molecule. However, it is markedly enhanced after lithium decoration with the high binding energy of -1.004 eV, verifying that the Li-decorated graphene sheet is significantly sensitive to detect N2H4 molecule. Meanwhile, the effects of the concentrations of N2H4 molecules on two different substrates were studied detailedly. For pristine graphene substrate, the average binding energy augments apparently with increasing the number of N2H4 molecules, which is mainly attributed to the van der Waals interactions and hydrogen bonds among N2H4 clusters. Li-decorated graphene sheet has still a strong affinity to N2H4 molecules despite the corresponding average binding energy emerges a contrary tendency. Overall, Li-decorated graphene sheet could be considered as a potential gas sensor in field of hydrazine molecules.

Observations of ionospheric electron beams in the plasma sheet.

PubMed

Zheng, H; Fu, S Y; Zong, Q G; Pu, Z Y; Wang, Y F; Parks, G K

2012-11-16

Electrons streaming along the magnetic field direction are frequently observed in the plasma sheet of Earth's geomagnetic tail. The impact of these field-aligned electrons on the dynamics of the geomagnetic tail is however not well understood. Here we report the first detection of field-aligned electrons with fluxes increasing at ~1 keV forming a "cool" beam just prior to the dissipation of energy in the current sheet. These field-aligned beams at ~15 R(E) in the plasma sheet are nearly identical to those commonly observed at auroral altitudes, suggesting the beams are auroral electrons accelerated upward by electric fields parallel (E([parallel])) to the geomagnetic field. The density of the beams relative to the ambient electron density is δn(b)/n(e)~5-13% and the current carried by the beams is ~10(-8)-10(-7) A m(-2). These beams in high β plasmas with large density and temperature gradients appear to satisfy the Bohm criteria to initiate current driven instabilities.

Dose equivalent neutron dosimeter

DOEpatents

Griffith, Richard V.; Hankins, Dale E.; Tomasino, Luigi; Gomaa, Mohamed A. M.

1983-01-01

A neutron dosimeter is disclosed which provides a single measurements indicating the amount of potential biological damage resulting from the neutron exposure of the wearer, for a wide range of neutron energies. The dosimeter includes a detecting sheet of track etch detecting material such as a carbonate plastic, for detecting higher energy neutrons, and a radiator layer containing conversion material such as .sup.6 Li and .sup.10 B lying adjacent to the detecting sheet for converting moderate energy neutrons to alpha particles that produce tracks in the adjacent detecting sheet. The density of conversion material in the radiator layer is of an amount which is chosen so that the density of tracks produced in the detecting sheet is proportional to the biological damage done by neutrons, regardless of whether the tracks are produced as the result of moderate energy neutrons striking the radiator layer or as the result of higher energy neutrons striking the sheet of track etch material.

Thermal and energetic constraints on ectotherm abundance: A global test using lizards

USGS Publications Warehouse

Buckley, L.B.; Rodda, G.H.; Jetz, W.

2008-01-01

Population densities of birds and mammals have been shown to decrease with body mass at approximately the same rate as metabolic rates increase, indicating that energetic needs constrain endotherm population densities. In ectotherms, the exponential increase of metabolic rate with body temperature suggests that environmental temperature may additionally constrain population densities. Here we test simple bioenergetic models for an ecologically important group of ectothermic vertebrates by examining 483 lizard populations. We find that lizard population densities decrease as a power law of body mass with a slope approximately inverse to the slope of the relationship between metabolic rates and body mass. Energy availability should limit population densities. As predicted, environmental productivity has a positive effect on lizard density, strengthening the relationship between lizard density and body mass. In contrast, the effect of environmental temperature is at most weak due to behavioral thermoregulation, thermal evolution, or the temperature dependence of ectotherm performance. Our results provide initial insights into how energy needs and availability differentially constrain ectotherm and endotherm density across broad spatial scales. ?? 2008 by the Ecological Society of America.

Thermal and energetic constraints on ectotherm abundance: a global test using lizards.

PubMed

Buckley, Lauren B; Rodda, Gordon H; Jetz, Walter

2008-01-01

Population densities of birds and mammals have been shown to decrease with body mass at approximately the same rate as metabolic rates increase, indicating that energetic needs constrain endotherm population densities. In ectotherms, the exponential increase of metabolic rate with body temperature suggests that environmental temperature may additionally constrain population densities. Here we test simple bioenergetic models for an ecologically important group of ectothermic vertebrates by examining 483 lizard populations. We find that lizard population densities decrease as a power law of body mass with a slope approximately inverse to the slope of the relationship between metabolic rates and body mass. Energy availability should limit population densities. As predicted, environmental productivity has a positive effect on lizard density, strengthening the relationship between lizard density and body mass. In contrast, the effect of environmental temperature is at most weak due to behavioral thermoregulation, thermal evolution, or the temperature dependence of ectotherm performance. Our results provide initial insights into how energy needs and availability differentially constrain ectotherm and endotherm density across broad spatial scales.

Influence of the initial parameters of the magnetic field and plasma on the spatial structure of the electric current and electron density in current sheets formed in helium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ostrovskaya, G. V., E-mail: galya-ostr@mail.ru; Markov, V. S.; Frank, A. G., E-mail: annfrank@fpl.gpi.ru

The influence of the initial parameters of the magnetic field and plasma on the spatial structure of the electric current and electron density in current sheets formed in helium plasma in 2D and 3D magnetic configurations with X-type singular lines is studied by the methods of holographic interferometry and magnetic measurements. Significant differences in the structures of plasma and current sheets formed at close parameters of the initial plasma and similar configurations of the initial magnetic fields are revealed.

Electronic properties of T graphene-like C-BN sheets: A density functional theory study

NASA Astrophysics Data System (ADS)

Majidi, R.

2015-11-01

We have used density functional theory to study the electronic properties of T graphene-like C, C-BN and BN sheets. The planar T graphene with metallic property has been considered. The results show that the presence of BN has a considerable effect on the electronic properties of T graphene. The T graphene-like C-BN and BN sheets show semiconducting properties. The energy band gap is increased by enhancing the number of BN units. The possibility of opening and controlling band gap opens the door for T graphene in switchable electronic devices.

Constraining Earth's Rheology of the Barents Sea Using Grace Gravity Change Observations

NASA Astrophysics Data System (ADS)

van der Wal, W.; Root, B. C.; Tarasov, L.

2014-12-01

The Barents Sea region was ice covered during last glacial maximum and experiences Glacial Isostatic Adjustment (GIA). Because of the limited amount of relevant geological and geodetic observations, it is difficult to constrain GIA models for this region. With improved ice sheet models and gravity observations from GRACE, it is possible to better constrain Earth rheology. This study aims to constrain the upper mantle viscosity and elastic lithosphere thickness from GRACE data in the Barents Sea region. The GRACE observations are corrected for current ice melting on Svalbard, Novaya Zemlya and Frans Joseph Land. A secular trend in gravity rate trend is estimated from the CSR release 5 GRACE data for the period of February 2003 to July 2013. Furthermore, long wavelength effects from distant large mass balance signals such as Greenland ice melting are filtered out. A new high-variance set of ice loading histories from calibrated glaciological modeling are used in the GIA modeling as it is found that ICE-5G over-estimates the observed GIA gravity change in the region. It is found that the rheology structure represented by VM5a results in over-estimation of the observed gravity change in the region for all ice sheet chronologies investigated. Therefore, other rheological Earth models were investigated. The best fitting upper mantle viscosity and elastic lithosphere thickness in the Barents Sea region are 4 (±0.5)*10^20 Pas and 110 (±20) km, respectively. The GRACE satellite mission proves to be a useful constraint in the Barents Sea Region for improving our knowledge on the upper mantle rheology.

Radiocarbon chronology of the last deglaciation in the Baffin Bay reveals asynchronous melting of Arctic and Laurentide ice sheets

NASA Astrophysics Data System (ADS)

Jackson, Rebecca; Kucera, Michal; Vogt, Christoph; Wacker, Lukas

2016-04-01

The transition from the last ice age into the Holocene interglacial was characterised by rapid retreat of North American ice sheets, discharging large quantities of meltwater into the Labrador Sea. Whereas the meltwater chronology of the Laurentide Ice Sheet is well documented, the deglacial history of the American Arctic ice sheets (Inuit Ice sheet and northern Greenland Ice Sheet) draining into the Labrador Sea via the Baffin Bay is less well constrained. Here we present the first high-resolution radiocarbon-dated deglacial records from the Canadian and Greenland margins of the central Baffin Bay. Sedimentological and geochemical data confirm the presence during Termination I of two events of enhanced delivery of detrital carbonate (Baffin Bay Detrital Carbonate Events) dated to 14.2-13.7 ka BP and 12.7-11 ka BP. The events are synchronous across the Baffin Bay and their mineralogical signature indicates a common source of detrital carbonate from the Canadian Arctic, with a synchronous clastic source proximal to Greenland. The events postdate Heinrich layers and their onset is not linked to Greenland temperature change. This indicates that the deglaciation of American Arctic ice sheets and associated meltwater discharge were decoupled from the dominant North Atlantic climate mode.

Size of graphene sheets determines the structural and mechanical properties of 3D graphene foams

NASA Astrophysics Data System (ADS)

Shen, Zhiqiang; Ye, Huilin; Zhou, Chi; Kröger, Martin; Li, Ying

2018-03-01

Graphene is recognized as an emerging 2D nanomaterial for many applications. Assembly of graphene sheets into 3D structures is an attractive way to enable their macroscopic applications and to preserve the exceptional mechanical and physical properties of their constituents. In this study, we develop a coarse-grained (CG) model for 3D graphene foams (GFs) based on the CG model for a 2D graphene sheet by Ruiz et al (2015 Carbon 82 103-15). We find that the size of graphene sheets plays an important role in both the structural and mechanical properties of 3D GFs. When their size is smaller than 10 nm, the graphene sheets can easily stack together under the influence of van der Waals interactions (vdW). These stacks behave like building blocks and are tightly packed together within 3D GFs, leading to high density, small pore radii, and a large Young’s modulus. However, if the sheet sizes exceed 10 nm, they are staggered together with a significant amount of deformation (bending). Therefore, the density of 3D GFs has been dramatically reduced due to the loosely packed graphene sheets, accompanied by large pore radii and a small Young’s modulus. Under uniaxial compression, rubber-like stress-strain curves are observed for all 3D GFs. This material characteristic is dominated by the vdW interactions between different graphene layers and slightly affected by the out-of-plane deformation of the graphene sheets. We find a simple scaling law E˜ {ρ }4.2 between the density ρ and Young’s modulus E for a model of 3D GFs. The simulation results reveal structure-property relations of 3D GFs, which can be applied to guide the design of 3D graphene assemblies with exceptional properties.

Phenomenological Model of Current Sheet Canting in Pulsed Electromagnetic Accelerators

NASA Technical Reports Server (NTRS)

Markusic, Thomas; Choueiri, E. Y.

2003-01-01

The phenomenon of current sheet canting in pulsed electromagnetic accelerators is the departure of the plasma sheet (that carries the current) from a plane that is perpendicular to the electrodes to one that is skewed, or tipped. Review of pulsed electromagnetic accelerator literature reveals that current sheet canting is a ubiquitous phenomenon - occurring in all of the standard accelerator geometries. Developing an understanding of current sheet canting is important because it can detract from the propellant sweeping capabilities of current sheets and, hence, negatively impact the overall efficiency of pulsed electromagnetic accelerators. In the present study, it is postulated that depletion of plasma near the anode, which results from axial density gradient induced diamagnetic drift, occurs during the early stages of the discharge, creating a density gradient normal to the anode, with a characteristic length on the order of the ion skin depth. Rapid penetration of the magnetic field through this region ensues, due to the Hall effect, leading to a canted current front ahead of the initial current conduction channel. In this model, once the current sheet reaches appreciable speeds, entrainment of stationary propellant replenishes plasma in the anode region, inhibiting further Hall-convective transport of the magnetic field; however, the previously established tilted current sheet remains at a fairly constant canting angle for the remainder of the discharge cycle, exerting a transverse J x B force which drives plasma toward the cathode and accumulates it there. This proposed sequence of events has been incorporated into a phenomenological model. The model predicts that canting can be reduced by using low atomic mass propellants with high propellant loading number density; the model results are shown to give qualitative agreement with experimentally measured canting angle mass dependence trends.

Glaciological constraints on current ice mass changes from modelling the ice sheets over the glacial cycles

NASA Astrophysics Data System (ADS)

Huybrechts, P.

2003-04-01

The evolution of continental ice sheets introduces a long time scale in the climate system. Large ice sheets have a memory of millenia, hence the present-day ice sheets of Greenland and Antarctica are still adjusting to climatic variations extending back to the last glacial period. This trend is separate from the direct response to mass-balance changes on decadal time scales and needs to be correctly accounted for when assessing current and future contributions to sea level. One way to obtain estimates of current ice mass changes is to model the past history of the ice sheets and their underlying beds over the glacial cycles. Such calculations assist to distinguish between the longer-term ice-dynamic evolution and short-term mass-balance changes when interpreting altimetry data, and are helpful to isolate the effects of postglacial rebound from gravity and altimetry trends. The presentation will discuss results obtained from 3-D thermomechanical ice-sheet/lithosphere/bedrock models applied to the Antarctic and Greenland ice sheets. The simulations are forced by time-dependent boundary conditions derived from sediment and ice core records and are constrained by geomorphological and glacial-geological data of past ice sheet and sea-level stands. Current simulations suggest that the Greenland ice sheet is close to balance, while the Antarctic ice sheet is still losing mass, mainly due to incomplete grounding-line retreat of the West Antarctic ice sheet since the LGM. The results indicate that altimetry trends are likely dominated by ice thickness changes but that the gravitational signal mainly reflects postglacial rebound.

Abrupt Bølling warming and ice saddle collapse contributions to the Meltwater Pulse 1a rapid sea level rise: North American MWP1a Contribution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gregoire, Lauren J.; Otto-Bliesner, Bette; Valdes, Paul J.

Elucidating the source(s) of Meltwater Pulse 1a, the largest rapid sea level rise caused by ice melt (14-18 m in less than 340 years, 14,600 years ago), is important for understanding mechanisms of rapid ice melt and the links with abrupt climate change. Here we quantify how much and by what mechanisms the North American ice sheet could have contributed to Meltwater Pulse 1a, by driving an ice sheet model with two transient climate simulations of the last 21,000 years. Ice sheet perturbed physics ensembles were run to account for model uncertainties, constraining ice extent and volume with reconstructions ofmore » 21,000 years ago to present. We determine that the North American ice sheet produced 3-4 m global mean sea level rise in 340 years due to the abrupt Bølling warming, but this response is amplified to 5-6 m when it triggers the ice sheet saddle collapse.« less

MIS-11 duration key to disappearance of the Greenland ice sheet

PubMed Central

Robinson, Alexander; Alvarez-Solas, Jorge; Calov, Reinhard; Ganopolski, Andrey; Montoya, Marisa

2017-01-01

Palaeo data suggest that Greenland must have been largely ice free during Marine Isotope Stage 11 (MIS-11). However, regional summer insolation anomalies were modest during this time compared to MIS-5e, when the Greenland ice sheet likely lost less volume. Thus it remains unclear how such conditions led to an almost complete disappearance of the ice sheet. Here we use transient climate–ice sheet simulations to simultaneously constrain estimates of regional temperature anomalies and Greenland’s contribution to the MIS-11 sea-level highstand. We find that Greenland contributed 6.1 m (3.9–7.0 m, 95% credible interval) to sea level, ∼7 kyr after the peak in regional summer temperature anomalies of 2.8 °C (2.1–3.4 °C). The moderate warming produced a mean rate of mass loss in sea-level equivalent of only around 0.4 m per kyr, which means the long duration of MIS-11 interglacial conditions around Greenland was a necessary condition for the ice sheet to disappear almost completely. PMID:28681860

Abrupt Bølling warming and ice saddle collapse contributions to the Meltwater Pulse 1a rapid sea level rise: North American MWP1a Contribution

DOE PAGES

Gregoire, Lauren J.; Otto-Bliesner, Bette; Valdes, Paul J.; ...

2016-08-23

Elucidating the source(s) of Meltwater Pulse 1a, the largest rapid sea level rise caused by ice melt (14-18 m in less than 340 years, 14,600 years ago), is important for understanding mechanisms of rapid ice melt and the links with abrupt climate change. Here we quantify how much and by what mechanisms the North American ice sheet could have contributed to Meltwater Pulse 1a, by driving an ice sheet model with two transient climate simulations of the last 21,000 years. Ice sheet perturbed physics ensembles were run to account for model uncertainties, constraining ice extent and volume with reconstructions ofmore » 21,000 years ago to present. We determine that the North American ice sheet produced 3-4 m global mean sea level rise in 340 years due to the abrupt Bølling warming, but this response is amplified to 5-6 m when it triggers the ice sheet saddle collapse.« less

MIS-11 duration key to disappearance of the Greenland ice sheet.

PubMed

Robinson, Alexander; Alvarez-Solas, Jorge; Calov, Reinhard; Ganopolski, Andrey; Montoya, Marisa

2017-07-06

Palaeo data suggest that Greenland must have been largely ice free during Marine Isotope Stage 11 (MIS-11). However, regional summer insolation anomalies were modest during this time compared to MIS-5e, when the Greenland ice sheet likely lost less volume. Thus it remains unclear how such conditions led to an almost complete disappearance of the ice sheet. Here we use transient climate-ice sheet simulations to simultaneously constrain estimates of regional temperature anomalies and Greenland's contribution to the MIS-11 sea-level highstand. We find that Greenland contributed 6.1 m (3.9-7.0 m, 95% credible interval) to sea level, ∼7 kyr after the peak in regional summer temperature anomalies of 2.8 °C (2.1-3.4 °C). The moderate warming produced a mean rate of mass loss in sea-level equivalent of only around 0.4 m per kyr, which means the long duration of MIS-11 interglacial conditions around Greenland was a necessary condition for the ice sheet to disappear almost completely.

Nitrotyrosine adsorption on defective graphene: A density functional theory study

NASA Astrophysics Data System (ADS)

Majidi, R.; Karami, A. R.

2015-06-01

We have applied density functional theory to study adsorption of nitrotyrosine on perfect and defective graphene sheets. The graphene sheets with Stone-Wales (SW) defect, pentagon-nonagon (5-9) single vacancy, and pentagon-octagon-pentagon (5-8-5) double vacancy were considered. The calculations of adsorption energy showed that nitrotyrosine presents a more strong interaction with defective graphene rather than with perfect graphene sheet. The order of interaction strength is: SW>5-9>5-8-5>perfect graphene. It is found that the electronic properties of perfect and defective graphene are sensitive to the presence of nitrotyrosine. Hence, graphene sheets can be considered as a good sensor for detection of nitrotyrosine molecule which is observed in connection with several human disorders, such as Parkinson's and Alzheimer's disease.

Theoretical investigation of calcium-decorated β12 boron sheet for hydrogen storage

NASA Astrophysics Data System (ADS)

Tang, Xiao; Gu, Yuantong; Kou, Liangzhi

2018-03-01

From first-principles calculations based on density functional theory, we find that the recently synthesized β12 boron sheet is a perfect candidate for calcium-decoration and hydrogen storage application. In contrast to graphene where defects are required to capture Ca, the naturally formed hexagonal hollow ring in β12 boron sheet provides the ideal site for Ca adsorption, and up to 6H2 molecules for each Ca atom can be captured with a desirable binding energy of ∼0.2 eV/H2. The gravimetric hydrogen density for Ca decorated boron sheet can reach up to 8.92 wt%. From the electronic analysis, it is found that both the orbital hybridizations and polarization mechanism play significant roles in H2 adsorption and storage.

Impact of the storm-time plasma sheet ion composition on the ring current energy density

NASA Astrophysics Data System (ADS)

Mouikis, C.; Kistler, L. M.; Petrinec, S. M.; Fuselier, S. A.; Cohen, I.

2017-12-01

The adiabatic inward transport of the night-side near-earth ( 6 Re) hot plasma sheet is the dominant contributor to the ring current pressure during storm times. During storm times, the plasma sheet composition in the 6 - 12 Re tail region changes due to O+ entry from the lobes (from the cusp) and the direct feeding from the night side auroral region. In addition, at substorm onset the plasma sheet O+ ions can be preferentially accelerated. We use MMS and observations during two magnetic storms, 5/8/2016 and 7/16/2017, to monitor the composition changes and energization in the 6 - 12 Re plasma sheet region. For both storms the MMS apogee was in the tail. In addition, we use subsequent Van Allen Probe observations (with apogee in the dawn and dusk respectively) to test if the 6-12 Re plasma sheet, observed by MMS, is a sufficient source of the O+ in the ring current. For this we will compare the phase space density (PSD) of the plasma sheet source population and the PSD of the inner magnetosphere at constant magnetic moment values as used in Kistler et al., [2016].

Vibration responses of h-BN sheet to charge doping and external strain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Wei; Yang, Yu; Zheng, Fawei

2013-12-07

Based on density functional theory and density functional perturbation theory calculations, we systematically investigate the vibration responses of h-BN sheet to charge doping and external strains. It is found that under hole doping, the phonon frequencies of the ZO and TO branches at different wave vector q shift linearly with different slopes. Under electron doping, although the phonon frequencies shift irregularly, the shifting values are different at different phonon wave vectors. Interestingly, we find that external strain can restrain the irregular vibration responses of h-BN sheet to electron doping. The critical factor is revealed to be the relative position ofmore » the nearly free electron and boron p{sub z} states of h-BN sheet. Under external strains, the vibration responses of h-BN sheet are also found to be highly dependent on the phonon branches. Different vibration modes at different q points are revealed to be responsible for the vibration responses of h-BN sheet to charge doping and external strain. Our results point out a new way to detect the doping or strain status of h-BN sheet by measuring the vibration frequencies at different wave vector.« less

Thin Sheet Modeling for the Seismogenic Crust of Western North America: How Strong is the top Slice of "Sandwich Bread" Above the "Jelly"?

NASA Astrophysics Data System (ADS)

Klein, E. C.; Holt, W. E.; Flesch, L. M.; Haines, A. J.

2006-12-01

The "jelly sandwich" and "crème brûlée" models divides continental lithosphere into distinct rheological layers. Dynamic models from thin sheet approximations provide estimates of the total strength of the lithosphere, but only to a thickness governed by the degree of mechanical coupling between rheological layers. If either the "jelly sandwich" or the "crème brûlée" model of the lithosphere is appropriate for the diffuse plate boundary zone setting of western North America, we expect a sharp contrast or decoupling between the strong upper crust ("bread") layer overlying the weak lower crustal ("jelly") layer. We examine the strength of the upper crust with and without strength contribution from the lower crust using thin sheet modeling methodologies. We use seismically defined densities to constrain vertical integrals of vertical stress (GPE) within the crust. Neglecting stresses due to flexure as well as shear stresses at the base of the crustal layer, lateral differences in GPE within the layer, are balanced solely by gradients in horizontal deviatoric stress [Flesch et al., 2001, 2006]. We solve the force-balance equations for the minimum deviatoric stress field associated with gradients of GPE. This deviatoric stress field calibrates the magnitude of deviatoric stresses within the seismogenic layer. We then solve for stress field boundary conditions associated with the stress field contributions from sources outside the modeled region that together with the minimum solution from GPE differences provide a best match with stress field indicators within western North America. In order to infer appropriate stress field indicators we develop a long-term kinematic strain rate and velocity field model. Where we use this strain rate field we assume that the relationship between deviatoric stress directions and kinematic strain rate directions is isotropic. In our calculations the seismogenic layer extends from the surface to either a uniform depth below sea level or to a variable depth below sea level constrained by heat flow. For the case of a long-term seismogenic layer with a uniform base 20 km below sea level, the long-term vertically integrated deviatoric stress magnitudes range between 0.05-0.75x10^{12} N/m, while the long-term vertically integrated strength magnitudes of the layer are of the order of 0.05-1.5x10^{12} N/m. These strength values constrain low long-term friction coefficients of 0.02-0.30 under hydrostatic to wet conditions in the Basin and Range region. We test the sensitivity of our solutions to different assumed brittle-ductile transition depths and find that coefficients of friction on faults, along with magnitudes of vertically integrated strength, are relatively insensitive to these assumed layer thicknesses. Moreover, through this sensitivity modeling we find evidence that our assumption of decoupling is valid for most of the Basin and Range region in that we find evidence for diminishing contributions to crustal strength with depth. We model the interface between the upper and lower crust by parameterization of a variable seismogenic thickness in the thin sheet equations. This allows us to estimate the strength of the top slice of "bread" without the incorporation of any "jelly". We find that most of the long-term strength of the crust within the diffuse plate boundary zone of western North America resides in the seismogenic layer of the upper crust.

Molding cork sheets to complex shapes

NASA Technical Reports Server (NTRS)

Sharpe, M. H.; Simpson, W. G.; Walker, H. M.

1977-01-01

Partially cured cork sheet is easily formed to complex shapes and then final-cured. Temperature and pressure levels required for process depend upon resin system used and final density and strength desired. Sheet can be bonded to surface during final cure, or can be first-formed in mold and bonded to surface in separate step.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bajaj, Sanyam, E-mail: bajaj.10@osu.edu; Shoron, Omor F.; Park, Pil Sung

We report on the direct measurement of two-dimensional sheet charge density dependence of electron transport in AlGaN/GaN high electron mobility transistors (HEMTs). Pulsed IV measurements established increasing electron velocities with decreasing sheet charge densities, resulting in saturation velocity of 1.9 × 10{sup 7 }cm/s at a low sheet charge density of 7.8 × 10{sup 11 }cm{sup −2}. An optical phonon emission-based electron velocity model for GaN is also presented. It accommodates stimulated longitudinal optical (LO) phonon emission which clamps the electron velocity with strong electron-phonon interaction and long LO phonon lifetime in GaN. A comparison with the measured density-dependent saturation velocity showsmore » that it captures the dependence rather well. Finally, the experimental result is applied in TCAD-based device simulator to predict DC and small signal characteristics of a reported GaN HEMT. Good agreement between the simulated and reported experimental results validated the measurement presented in this report and established accurate modeling of GaN HEMTs.« less

Evidence for the stability of the West Antarctic Ice Sheet divide for 1.4 million years

PubMed Central

Hein, Andrew S.; Woodward, John; Marrero, Shasta M.; Dunning, Stuart A.; Steig, Eric J.; Freeman, Stewart P. H. T.; Stuart, Finlay M.; Winter, Kate; Westoby, Matthew J.; Sugden, David E.

2016-01-01

Past fluctuations of the West Antarctic Ice Sheet (WAIS) are of fundamental interest because of the possibility of WAIS collapse in the future and a consequent rise in global sea level. However, the configuration and stability of the ice sheet during past interglacial periods remains uncertain. Here we present geomorphological evidence and multiple cosmogenic nuclide data from the southern Ellsworth Mountains to suggest that the divide of the WAIS has fluctuated only modestly in location and thickness for at least the last 1.4 million years. Fluctuations during glacial–interglacial cycles appear superimposed on a long-term trajectory of ice-surface lowering relative to the mountains. This implies that as a minimum, a regional ice sheet centred on the Ellsworth-Whitmore uplands may have survived Pleistocene warm periods. If so, it constrains the WAIS contribution to global sea level rise during interglacials to about 3.3 m above present. PMID:26838462

Aligned carbon nanotube-silicon sheets: a novel nano-architecture for flexible lithium ion battery electrodes.

PubMed

Fu, Kun; Yildiz, Ozkan; Bhanushali, Hardik; Wang, Yongxin; Stano, Kelly; Xue, Leigang; Zhang, Xiangwu; Bradford, Philip D

2013-09-25

Aligned carbon nanotube sheets provide an engineered scaffold for the deposition of a silicon active material for lithium ion battery anodes. The sheets are low-density, allowing uniform deposition of silicon thin films while the alignment allows unconstrained volumetric expansion of the silicon, facilitating stable cycling performance. The flat sheet morphology is desirable for battery construction. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Efficient Adsorption Characteristics of Pristine and Silver-Doped Graphene Oxide Towards Contaminants: A Potential Membrane Material for Water Purification?

PubMed

Panigrahi, Puspamitra; Dhinakaran, Ashok Kumar; Sekar, Yuvaraj; Ahuja, Rajeev; Hussain, Tanveer

2018-05-16

In this work, we have investigated the potential of pristine and silver (Ag)-functionalized graphene oxide monolayers GO (GO-Ag) as efficient membranes for water filtration. Our first principles calculations based on density functional theory (DFT) reveal the hydrophilic nature of GO surfaces. The phonon frequency calculations within density functional perturbation theory (DFPT) confirmed the stability of GO sheets in aqueous media. Van der Waals-corrected binding energies of GO sheet towards heavy metals suggest that even pristine GO sheets are completely impermeable to various heavy metals like arsenic (As) and lead (Pb). However, compared to GO, the GO-Ag sheets have a much higher affinity towards the three amino acids histidine, phenyl-alanine and tyrosine, which are the main component of a bacteria cell wall. The GO-Ag sheet is found to be extremely efficient for bacteria inactivation. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Simultaneous Measurements of Substorm-Related Electron Energization in the Ionosphere and the Plasma Sheet

NASA Astrophysics Data System (ADS)

Sivadas, N.; Semeter, J.; Nishimura, Y.; Kero, A.

2017-10-01

On 26 March 2008, simultaneous measurements of a large substorm were made using the Poker Flat Incoherent Scatter Radar, Time History of Events and Macroscale Interactions during Substorm (THEMIS) spacecraft, and all sky cameras. After the onset, electron precipitation reached energies ≳100 keV leading to intense D region ionization. Identifying the source of energetic precipitation has been a challenge because of lack of quantitative and magnetically conjugate measurements of loss cone electrons. In this study, we use the maximum entropy inversion technique to invert altitude profiles of ionization measured by the radar to estimate the loss cone energy spectra of primary electrons. By comparing them with magnetically conjugate measurements from THEMIS-D spacecraft in the nightside plasma sheet, we constrain the source location and acceleration mechanism of precipitating electrons of different energy ranges. Our analysis suggests that the observed electrons ≳100 keV are a result of pitch angle scattering of electrons originating from or tailward of the inner plasma sheet at 9RE, possibly through interaction with electromagnetic ion cyclotron waves. The electrons of energy 10-100 keV are produced by pitch angle scattering due to a potential drop of ≲10 kV in the auroral acceleration region (AAR) as well as wave-particle interactions in and tailward of the AAR. This work demonstrates the utility of magnetically conjugate ground- and space-based measurements in constraining the source of energetic electron precipitation. Unlike in situ spacecraft measurements, ground-based incoherent scatter radars combined with an appropriate inversion technique can be used to provide remote and continuous-time estimates of loss cone electrons in the plasma sheet.

Committed sea-level rise for the next century from Greenland ice sheet dynamics during the past decade

PubMed Central

Price, Stephen F.; Payne, Antony J.; Howat, Ian M.; Smith, Benjamin E.

2011-01-01

We use a three-dimensional, higher-order ice flow model and a realistic initial condition to simulate dynamic perturbations to the Greenland ice sheet during the last decade and to assess their contribution to sea level by 2100. Starting from our initial condition, we apply a time series of observationally constrained dynamic perturbations at the marine termini of Greenland’s three largest outlet glaciers, Jakobshavn Isbræ, Helheim Glacier, and Kangerdlugssuaq Glacier. The initial and long-term diffusive thinning within each glacier catchment is then integrated spatially and temporally to calculate a minimum sea-level contribution of approximately 1 ± 0.4 mm from these three glaciers by 2100. Based on scaling arguments, we extend our modeling to all of Greenland and estimate a minimum dynamic sea-level contribution of approximately 6 ± 2 mm by 2100. This estimate of committed sea-level rise is a minimum because it ignores mass loss due to future changes in ice sheet dynamics or surface mass balance. Importantly, > 75% of this value is from the long-term, diffusive response of the ice sheet, suggesting that the majority of sea-level rise from Greenland dynamics during the past decade is yet to come. Assuming similar and recurring forcing in future decades and a self-similar ice dynamical response, we estimate an upper bound of 45 mm of sea-level rise from Greenland dynamics by 2100. These estimates are constrained by recent observations of dynamic mass loss in Greenland and by realistic model behavior that accounts for both the long-term cumulative mass loss and its decay following episodic boundary forcing. PMID:21576500

Rapid advance and retreat over centennial/millennial timescales at Kangiata Nunaata Sermia, SW Greenland - implications for modelling, and behaviour of tidewater glaciers

NASA Astrophysics Data System (ADS)

Lea, J.; Mair, D. W.; Rea, B. R.; Schofield, J.; Kamenos, N.; Pearce, D.; Schoenrock, K. M.

2017-12-01

While the Greenland Ice Sheet has undergone significant retreat over the last 80 years, our understanding of the ice sheet's response to climate forcing over centennial to millennial timescales is poorly constrained. Knowledge of marine glacier outlets over these timescales would provide crucial information regarding longer term ice sheet dynamics, beyond instrumental and historical records. It is notably difficult to constrain such histories for these glaciers due to: (i) a highly dynamic ice front environment in combination with the Little Ice Age advance(s) destroying much of the preceding evidence for glacier change; (ii) often poor landform/sediment preservation due to steep sided fjords; (iii) the areas with greatest preservation potential, the fjords bottoms, being submarine and often ice choked, and therefore non-trivial to survey, and sample. The tidewater glacier Kangiata Nunaata Sermia (KNS), SW Greenland provides an exception to this. Here we present a record of >22km of terminus advance and retreat spanning the last 1000 years using a combination of geomorphological, sedimentological and archaeological evidence. This timescale includes periods of substantial warming and cooling of air temperatures that appear to correspond to periods of advance and retreat. Results also suggest that the average advance rates in the early part of the millennium (110 m a-1) are of a similar magnitude to contemporary retreat rates observed around Greenland. The results generated here provide an ideal opportunity to validate the performance of numerical models (notably those that include calving) over centennial timescales. Evaluating model performance against the past behaviour of KNS could therefore lead to significant improvements in the confidence of ice sheet change projections up to 2100 and beyond.

Committed sea-level rise for the next century from Greenland ice sheet dynamics during the past decade.

PubMed

Price, Stephen F; Payne, Antony J; Howat, Ian M; Smith, Benjamin E

2011-05-31

We use a three-dimensional, higher-order ice flow model and a realistic initial condition to simulate dynamic perturbations to the Greenland ice sheet during the last decade and to assess their contribution to sea level by 2100. Starting from our initial condition, we apply a time series of observationally constrained dynamic perturbations at the marine termini of Greenland's three largest outlet glaciers, Jakobshavn Isbræ, Helheim Glacier, and Kangerdlugssuaq Glacier. The initial and long-term diffusive thinning within each glacier catchment is then integrated spatially and temporally to calculate a minimum sea-level contribution of approximately 1 ± 0.4 mm from these three glaciers by 2100. Based on scaling arguments, we extend our modeling to all of Greenland and estimate a minimum dynamic sea-level contribution of approximately 6 ± 2 mm by 2100. This estimate of committed sea-level rise is a minimum because it ignores mass loss due to future changes in ice sheet dynamics or surface mass balance. Importantly, > 75% of this value is from the long-term, diffusive response of the ice sheet, suggesting that the majority of sea-level rise from Greenland dynamics during the past decade is yet to come. Assuming similar and recurring forcing in future decades and a self-similar ice dynamical response, we estimate an upper bound of 45 mm of sea-level rise from Greenland dynamics by 2100. These estimates are constrained by recent observations of dynamic mass loss in Greenland and by realistic model behavior that accounts for both the long-term cumulative mass loss and its decay following episodic boundary forcing.

Moldable cork ablation material

NASA Technical Reports Server (NTRS)

1977-01-01

A successful thermal ablative material was manufactured. Moldable cork sheets were tested for density, tensile strength, tensile elongation, thermal conductivity, compression set, and specific heat. A moldable cork sheet, therefore, was established as a realistic product.

Analysis of Lithospheric Stresses Using Satellite Gravimetry: Hypotheses and Applications to North Atlantic

NASA Astrophysics Data System (ADS)

Minakov, A.; Medvedev, S.

2017-12-01

Analysis of lithospheric stresses is necessary to gain understanding of the forces that drive plate tectonics and intraplate deformations and the structure and strength of the lithosphere. A major source of lithospheric stresses is believed to be in variations of surface topography and lithospheric density. The traditional approach to stress estimation is based on direct calculations of the Gravitational Potential Energy (GPE), the depth integrated density moment of the lithosphere column. GPE is highly sensitive to density structure which, however, is often poorly constrained. Density structure of the lithosphere may be refined using methods of gravity modeling. However, the resulted density models suffer from non-uniqueness of the inverse problem. An alternative approach is to directly estimate lithospheric stresses (depth integrated) from satellite gravimetry data. Satellite gravity gradient measurements by the ESA GOCE mission ensures a wealth of data for mapping lithospheric stresses if a link between data and stresses or GPE can be established theoretically. The non-uniqueness of interpretation of sources of the gravity signal holds in this case as well. Therefore, the data analysis was tested for the North Atlantic region where reliable additional constraints are supplied by both controlled-source and earthquake seismology. The study involves comparison of three methods of stress modeling: (1) the traditional modeling approach using a thin sheet approximation; (2) the filtered geoid approach; and (3) the direct utilization of the gravity gradient tensor. Whereas the first two approaches (1)-(2) calculate GPE and utilize a computationally expensive finite element mechanical modeling to calculate stresses, the approach (3) uses a much simpler numerical treatment but requires simplifying assumptions that yet to be tested. The modeled orientation of principal stresses and stress magnitudes by each of the three methods are compared with the World Stress Map.

Experimental investigation of a 1 kA/cm² sheet beam plasma cathode electron gun.

PubMed

Kumar, Niraj; Pal, Udit Narayan; Pal, Dharmendra Kumar; Prajesh, Rahul; Prakash, Ram

2015-01-01

In this paper, a cold cathode based sheet-beam plasma cathode electron gun is reported with achieved sheet-beam current density ∼1 kA/cm(2) from pseudospark based argon plasma for pulse length of ∼200 ns in a single shot experiment. For the qualitative assessment of the sheet-beam, an arrangement of three isolated metallic-sheets is proposed. The actual shape and size of the sheet-electron-beam are obtained through a non-conventional method by proposing a dielectric charging technique and scanning electron microscope based imaging. As distinct from the earlier developed sheet beam sources, the generated sheet-beam has been propagated more than 190 mm distance in a drift space region maintaining sheet structure without assistance of any external magnetic field.

Long-Term Variability of Jupiter's Magnetodisk and Implications for the Aurora

NASA Astrophysics Data System (ADS)

Vogt, Marissa F.; Bunce, Emma J.; Nichols, Jonathan D.; Clarke, John T.; Kurth, William S.

2017-12-01

Observations of Jupiter's UV auroral emissions collected over several years show that the ionospheric positions of the main emission and the Ganymede footprint can vary by as much as 3° in latitude. One explanation for this shift is a change of Jupiter's current sheet current density, which would alter the amount of field line stretching and displace the ionospheric mapping of field lines from a given radial distance in the magnetosphere. In this study we measure the long-term variability of Jupiter's magnetodisk using Galileo magnetometer data collected from 1996 to 2003. Using the Connerney et al. (1981) current sheet model, we calculate the current sheet density parameter that gives the best fit to the data from each orbit and find that the current density parameter varies by about 15% of its average value during the Galileo era. We investigate possible relationships between the observed current sheet variability and quantities such as Io's plasma torus production rate inferred from volcanic activity and external solar wind conditions extrapolated from data at 1 AU but find only a weak correlation. Finally, we trace Khurana (1997) model field lines to show that the observed changes in Jupiter's current sheet are sufficient to shift the ionospheric footprint of Ganymede and main auroral emission by a few degrees of latitude, consistent with the magnitude of auroral variability observed by Hubble Space Telescope (HST). However, we find that the measured auroral shifts in HST images are not consistent with concurrent changes in the current density parameter measured by Galileo.

A high density two-dimensional electron gas in an oxide heterostructure on Si (001)

NASA Astrophysics Data System (ADS)

Jin, E. N.; Kornblum, L.; Kumah, D. P.; Zou, K.; Broadbridge, C. C.; Ngai, J. H.; Ahn, C. H.; Walker, F. J.

2014-11-01

We present the growth and characterization of layered heterostructures comprised of LaTiO3 and SrTiO3 epitaxially grown on Si (001). Magnetotransport measurements show that the sheet carrier densities of the heterostructures scale with the number of LaTiO3/SrTiO3 interfaces, consistent with the presence of an interfacial 2-dimensional electron gas (2DEG) at each interface. Sheet carrier densities of 8.9 × 1014 cm-2 per interface are observed. Integration of such high density oxide 2DEGs on silicon provides a bridge between the exceptional properties and functionalities of oxide 2DEGs and microelectronic technologies.

Refreezing on the Greenland ice sheet: a model comparison

NASA Astrophysics Data System (ADS)

Steger, Christian; Reijmer, Carleen; van den Broeke, Michiel; Ligtenberg, Stefan; Kuipers Munneke, Peter; Noël, Brice

2016-04-01

Mass loss of the Greenland ice sheet (GrIS) is an important contributor to global sea level rise. Besides calving, surface melt is the dominant source of mass loss. However, only part of the surface melt leaves the ice sheet as runoff whereas the other part percolates into the snow cover and refreezes. Due to this process, part of the meltwater is (intermediately) stored. Refreezing thus impacts the surface mass balance of the ice sheet but it also affects the vertical structure of the snow cover due to transport of mass and energy. Due to the sparse availability of in situ data and the demand of future projections, it is inevitable to use numerical models to simulate refreezing and related processes. Currently, the magnitude of refrozen mass is neither well constrained nor well validated. In this study, we model the snow and firn layer, and compare refreezing on the GrIS as modelled with two different numerical models. Both models are forced with meteorological data from the regional climate model RACMO 2 that has been shown to simulate realistic conditions for Greenland. One model is the UU/IMAU firn densification model (FDM) that can be used both in an on- and offline mode with RACMO 2. The other model is SNOWPACK; a model originally designed to simulate seasonal snow cover in alpine conditions. In contrast to FDM, SNOWPACK accounts for snow metamorphism and microstructure and contains a more physically based snow densification scheme. A first comparison of the models indicates that both seem to be able to capture the general spatial and temporal pattern of refreezing. Spatially, refreezing occurs mostly in the ablation zone and decreases in the accumulation zone towards the interior of the ice sheet. Below the equilibrium line altitude (ELA) where refreezing occurs in seasonal snow cover on bare ice, the storage effect is only intermediate. Temporal patterns on a seasonal range indicate two peaks in refreezing; one at the beginning of the melt season where water infiltrates the cold snow pack and one in early winter where the penetration of the cold surface temperature refreezes the retained liquid water. However, the model comparison reveals differences especially close to the equilibrium line where refreezing and runoff seem to be highly sensitive to the exact model formulation and fresh snow density initialization. Furthermore, SNOWPACK's densification scheme generally underestimates densification rates in case of high overburden pressure.

Toward more accurate basal boundary conditions: a new 2-D model of distributed and channelised subglacial drainage

NASA Astrophysics Data System (ADS)

Werder, M. A.; Hewitt, I. J.; Schoof, C.; Flowers, G. E.

2012-04-01

Basal boundary conditions are one of the least constrained components of today's ice sheet models. To get at these one needs to know the distributed basal water pressure. We present a new glacier drainage system model to contribute to this missing piece of the puzzle. This two dimensional mathematical/numerical model combines distributed and channelised drainage at the ice-bed interface coupled to a water storage component. Notably the model determines the location of the channels as part of the solution. This is achieved by allowing channels (modelled as R-channels) to form on any of the edges of the unstructured triangular grid used to discretise the model. The distributed system is represented by a water sheet which is a continuum description of a linked-cavity system and exchanges water with the channels along their length. Water storage is parameterised as a function of the subglacial water pressure, which can be interpreted as storage in an englacial aquifer or due to elastic processes. The parabolic equation that determines the water pressure is solved using finite elements, the time evolution of the water sheet thickness and channel diameter are governed by local differential equations that are integrated using explicit methods. To explore the model's properties, we apply it to synthetic ice sheet catchments with areas up to 3000km2. We present steady state drainage system configurations and evaluate their channel-network properties (fractal dimensions, channel spacing). We find that an arborescent channel network forms whose density depends on the water sheet conductivity relative to water input. As a further experiment, we force the model with a seasonally and diurnally varying melt water input to investigate how the modelled drainage system evolves on these time scales: a channelised system grows up glacier as meltwater is delivered to the bed in spring and collapses in autumn. Water pressure is highest just before the formation of channels and then drops. Conversely, the diurnal variations in discharge affect the drainage system morphology only slightly. Instead they lead to large water pressure variations which lag meltwater input and coincide with changes in the volume of stored water. By incorporating an evolving R-channel network within a continuum model of distributed water drainage and storage, this 2-D model succeeds in qualitatively reproducing many of the observed and postulated features of the glacier drainage system.

Constrained subsystem density functional theory.

PubMed

Ramos, Pablo; Pavanello, Michele

2016-08-03

Constrained Subsystem Density Functional Theory (CSDFT) allows to compute diabatic states for charge transfer reactions using the machinery of the constrained DFT method, and at the same time is able to embed such diabatic states in a molecular environment via a subsystem DFT scheme. The CSDFT acronym is chosen to reflect the fact that on top of the subsystem DFT approach, a constraining potential is applied to each subsystem. We show that CSDFT can successfully tackle systems as complex as single stranded DNA complete of its backbone, and generate diabatic states as exotic as a hole localized on a phosphate group as well as on the nucleobases. CSDFT will be useful to investigators needing to evaluate the environmental effect on charge transfer couplings for systems in condensed phase environments.

Experimental investigation of a 1 kA/cm{sup 2} sheet beam plasma cathode electron gun

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Niraj, E-mail: niraj.ceeri@gmail.com; Narayan Pal, Udit; Prajesh, Rahul

In this paper, a cold cathode based sheet-beam plasma cathode electron gun is reported with achieved sheet-beam current density ∼1 kA/cm{sup 2} from pseudospark based argon plasma for pulse length of ∼200 ns in a single shot experiment. For the qualitative assessment of the sheet-beam, an arrangement of three isolated metallic-sheets is proposed. The actual shape and size of the sheet-electron-beam are obtained through a non-conventional method by proposing a dielectric charging technique and scanning electron microscope based imaging. As distinct from the earlier developed sheet beam sources, the generated sheet-beam has been propagated more than 190 mm distance inmore » a drift space region maintaining sheet structure without assistance of any external magnetic field.« less

Multiscale field-aligned current analyzer

NASA Astrophysics Data System (ADS)

Bunescu, C.; Marghitu, O.; Constantinescu, D.; Narita, Y.; Vogt, J.; Blǎgǎu, A.

2015-11-01

The magnetosphere-ionosphere coupling is achieved, essentially, by a superposition of quasi-stationary and time-dependent field-aligned currents (FACs), over a broad range of spatial and temporal scales. The planarity of the FAC structures observed by satellite data and the orientation of the planar FAC sheets can be investigated by the well-established minimum variance analysis (MVA) of the magnetic perturbation. However, such investigations are often constrained to a predefined time window, i.e., to a specific scale of the FAC. The multiscale field-aligned current analyzer, introduced here, relies on performing MVA continuously and over a range of scales by varying the width of the analyzing window, appropriate for the complexity of the magnetic field signatures above the auroral oval. The proposed technique provides multiscale information on the planarity and orientation of the observed FACs. A new approach, based on the derivative of the largest eigenvalue of the magnetic variance matrix with respect to the length of the analysis window, makes possible the inference of the current structures' location (center) and scale (thickness). The capabilities of the FAC analyzer are explored analytically for the magnetic field profile of the Harris sheet and tested on synthetic FAC structures with uniform current density and infinite or finite geometry in the cross-section plane of the FAC. The method is illustrated with data observed by the Cluster spacecraft on crossing the nightside auroral region, and the results are cross checked with the optical observations from the Time History of Events and Macroscale Interactions during Substorms ground network.

Phonological Codes Constrain Output of Orthographic Codes via Sublexical and Lexical Routes in Chinese Written Production

PubMed Central

Wang, Cheng; Zhang, Qingfang

2015-01-01

To what extent do phonological codes constrain orthographic output in handwritten production? We investigated how phonological codes constrain the selection of orthographic codes via sublexical and lexical routes in Chinese written production. Participants wrote down picture names in a picture-naming task in Experiment 1or response words in a symbol—word associative writing task in Experiment 2. A sublexical phonological property of picture names (phonetic regularity: regular vs. irregular) in Experiment 1and a lexical phonological property of response words (homophone density: dense vs. sparse) in Experiment 2, as well as word frequency of the targets in both experiments, were manipulated. A facilitatory effect of word frequency was found in both experiments, in which words with high frequency were produced faster than those with low frequency. More importantly, we observed an inhibitory phonetic regularity effect, in which low-frequency picture names with regular first characters were slower to write than those with irregular ones, and an inhibitory homophone density effect, in which characters with dense homophone density were produced more slowly than those with sparse homophone density. Results suggested that phonological codes constrained handwritten production via lexical and sublexical routes. PMID:25879662

Substorm Electric And Magnetic Fields In The Earth's Magnetotail: Observations Compared To The WINDMI Model

NASA Astrophysics Data System (ADS)

Srinivas, P. G.; Spencer, E. A.; Vadepu, S. K.; Horton, W., Jr.

2017-12-01

We compare satellite observations of substorm electric fields and magnetic fields to the output of a low dimensional nonlinear physics model of the nightside magnetosphere called WINDMI. The electric and magnetic field satellite data are used to calculate the E X B drift, which is one of the intermediate variables of the WINDMI model. The model uses solar wind and IMF measurements from the ACE spacecraft as input into a system of 8 nonlinear ordinary differential equations. The state variables of the differential equations represent the energy stored in the geomagnetic tail, central plasma sheet, ring current and field aligned currents. The output from the model is the ground based geomagnetic westward auroral electrojet (AL) index, and the Dst index.Using ACE solar wind data, IMF data and SuperMAG identification of substorm onset times up to December 2015, we constrain the WINDMI model to trigger substorm events, and compare the model intermediate variables to THEMIS and GEOTAIL satellite data in the magnetotail. By forcing the model to be consistent with satellite electric and magnetic field observations, we are able to track the magnetotail energy dynamics, the field aligned current contributions, energy injections into the ring current, and ensure that they are within allowable limts. In addition we are able to constrain the physical parameters of the model, in particular the lobe inductance, the plasma sheet capacitance, and the resistive and conductive parameters in the plasma sheet and ionosphere.

Lacustrine Records of Holocene Mountain Glacier Fluctuations from Western Greenland

NASA Astrophysics Data System (ADS)

Schweinsberg, A.; Briner, J. P.; Bennike, O.

2014-12-01

Recent studies have focused on documenting fluctuations of the Greenland Ice Sheet margin throughout the Holocene but few data exist that constrain past changes of local glaciers independent of the ice sheet. Our research combines proglacial lake sediment analysis with cosmogenic 10Be dating of Holocene moraines and radiocarbon dating of ice-cap-killed vegetation with an overall objective to use this multi-proxy approach to generate a detailed record of the coupled climate-glacier system through the Holocene. Here, we present lacustrine records of mountain glacier variability from continuous pro-glacial lake sediment sequences recovered from two glaciated catchments in northeastern Nuussuaq, western Greenland. We use radiocarbon-dated sediments from Sikuiui and Pauiaivik lakes to reconstruct the timing of advance and retreat of local glaciers. Sediments were characterized with magnetic susceptibility (MS), gamma density, Itrax XRF and visible reflectance spectroscopy at 0.2 cm intervals and sediment organic matter at 0.5 cm intervals. Basal radiocarbon ages provide minimum-age constraints on deglaciation from Sikuiui and Pauiaivik lakes of ~9.6 and 8.7 ka, respectively. Organic-rich gyttja from deglaciation until ~5.0 ka in Pauiaivik Lake suggests minimal glacial extent there while slightly elevated MS values from ~9.0 - 7.0 ka in Sikuiui Lake may reflect early Holocene glacial advances. Minerogenic sediment input gradually increases starting at ~5.0 ka in Pauiaivik Lake, which we interpret as the onset of Neoglaciation in the catchment. Furthermore, a distinct episode of enhanced glacial activity from ~4.0 - 2.2 ka in Sikuiui Lake may be correlative to a period of persistent snowline lowering evidenced by radiocarbon dates of ice-killed vegetation from nearby ice cap margins. Results from these lacustrine records and our ice-killed vegetation dataset suggest a middle Holocene onset of Neoglaciation ~5.0 - 4.0 ka in this region. We are supplementing these records with cosmogenic 10Be exposure dating to further constrain the timing of deglaciation. In addition, these sedimentary archives will continue to be compared to radiocarbon dates of ice-killed vegetation along adjacent ice cap margins to determine if times of persistent snowline lowering are correlative to periods of glacier advance.

Bedrock Erosion Surfaces Record Former East Antarctic Ice Sheet Extent

NASA Astrophysics Data System (ADS)

Paxman, Guy J. G.; Jamieson, Stewart S. R.; Ferraccioli, Fausto; Bentley, Michael J.; Ross, Neil; Armadillo, Egidio; Gasson, Edward G. W.; Leitchenkov, German; DeConto, Robert M.

2018-05-01

East Antarctica hosts large subglacial basins into which the East Antarctic Ice Sheet (EAIS) likely retreated during past warmer climates. However, the extent of retreat remains poorly constrained, making quantifying past and predicted future contributions to global sea level rise from these marine basins challenging. Geomorphological analysis and flexural modeling within the Wilkes Subglacial Basin are used to reconstruct the ice margin during warm intervals of the Oligocene-Miocene. Flat-lying bedrock plateaus are indicative of an ice sheet margin positioned >400-500 km inland of the modern grounding zone for extended periods of the Oligocene-Miocene, equivalent to a 2-m rise in global sea level. Our findings imply that if major EAIS retreat occurs in the future, isostatic rebound will enable the plateau surfaces to act as seeding points for extensive ice rises, thus limiting extensive ice margin retreat of the scale seen during the early EAIS.

Supraglacial Lakes in the Percolation Zone of the Western Greenland Ice Sheet: Formation and Development using Operation IceBridge Snow Radar and ATM (2009-2014)

NASA Astrophysics Data System (ADS)

Chen, C.; Howat, I. M.; de la Peña, S.

2015-12-01

Surface meltwater lakes on the Greenland Ice Sheet have appeared at higher elevations, extending well into the percolation zone, under recent warming, with the largest expansion occurring in the western Greenland Ice Sheet. The conditions that allow lakes to form atop firn are poorly constrained, but the formation of new lakes imply changes in the permeability of the firn at high elevations, promoting meltwater runoff. We explore the formation and evolution of new surface lakes in this region above 1500 meters, using a combination of satellite imagery and repeat Snow (2-6.5 GHz) radar echograms and LIDAR measurements from NASA's Operation IceBridge of 2009-2014. We identify conditions for surface lake formation at their farthest inland extent and suggest behaviors of persistence and lake drainage are due to differences in regional ice dynamics.

Postglacial Rebound From Space Geodesy

NASA Astrophysics Data System (ADS)

Argus, D. F.; Peltier, W. R.

2005-12-01

To study the viscous response of the earth to the unloading of the late Pleistocene ice sheets and, to a lesser extent, the elastic response of the earth to current changes in ice sheet mass, we integrate geodetic observations from VLBI over 24 years, from SLR over 23 years, from DORIS over 12 years, and from GPS over 11 years. The excellent geodetic velocity solutions upon which this study are based are from Chopo Ma and Dan MacMillan (Goddard Space Flight Center), Michael Heflin (Jet Propulsion Laboratory), John Ries and Richard Eanes (Center for Space Research, University of Texas at Austin), and Pascal Willis (Institut Geogpraphique National and Jet Propulsion Laboratory). The rates of uplift and subsidence we determine, which in places differ significantly from published studies, are constraining postglacial rebound models like that of Peltier [1994], Peltier [1996], Milne [2001], and Peltier [2004]. We find the following: Yellowknife is rising at 5.7 ±1.8 mm/yr (95% confidence limits), showing [Peltier 2002, 2004], with complimentary ground observations of gravity [Lambert et al. 2001], that the western part of the Laurentide ice sheet was thicker during the Last Glacial Maximum than previously [Peltier 1994, 1996] believed. Onsala (Sweden) is rising at 2.4 ±1.3 mm/yr and Algonquin Park (Ontario) is rising at 2.3 ±1.4 mm/yr, constraining the positions of the margins of the Fennoscandian and Laurentide ice sheets during the Last Glacial Maximum. The eastern United States is falling at ~1 mm/yr, suggesting that the area around the ancient Laurentide ice sheet is subsiding more slowly than predicted by the model of Peltier [2004]. Western and central Europe are falling at ~0.5 mm/yr, suggesting that the area around the ancient Fennoscandian ice sheet is hardly subsiding at all, consistent with the model of Peltier [2004]. Kellyville (Greenland) is falling insignificantly at 1.1 ±4.3 mm/yr, not requiring current loading of the ice sheet [Wahr et al. 2002, Tarasov and Peltier 2002]. Ny Alesund (Spitsbergen) is rising at 6.3 ±1.7 mm/yr, in elastic response to current unloading of a glacier [Hagedoorn and Wolf 2003]. Sites along the margins of the ancient ice sheets are moving horizontally away from the former ice centers at ~1 mm/yr, more slowly than predicted by the model of Peltier [2004]. Sites far from the ancient ice sheets are moving horizontally hardly at all, at insignificant speeds again slower than predicted by the model of Peltier [2004]. Much of the Antarctic, Eurasian, and North American plates are deforming horizontally hardly at all, allowing the angular velocities of the plates to be estimated meaningfully. Satisfying the geodetic observations is going to require revising the ice sheet thickness and the viscosity of the upper mantle (or the elastic lithosphere thickness) in the model of Peltier [2004].

Energization of the Ring Current through Convection of Substorm Enhancements of the Plasma Sheet Source.

NASA Astrophysics Data System (ADS)

Menz, A.; Kistler, L. M.; Mouikis, C.; Spence, H. E.; Henderson, M. G.; Matsui, H.

2017-12-01

It has been shown that electric field strength and night-side plasma sheet density are the two best predictors of the adiabatic energy gain of the ring current during geomagnetic storms (Liemohn and Khazanov, 2005). While H+ dominates the ring current during quiet times, O+ can contribute substantially during geomagnetic storms. Substorm activity provides a mechanism to enhance the energy density of O+ in the plasma sheet during geomagnetic storms, which is then convected adiabatically into the inner-magnetosphere. Using the Van Allen Probes data in the the plasma sheet source region (defined as L>5.5 during storms) and the inner magnetosphere, along with LANL-GEO data to identify substorm injection times, we show that adiabatic convection of O+ enhancements in the source region can explain the observed enhancements in the inner magnetosphere. We use the UNH-IMEF electric field model to calculate drift times from the source region to the inner magnetosphere to test whether enhancements in the inner-magnetosphere can be explained by dipolarization driven enhancements in the plasma sheet source hours before.

Critical transition in the constrained traveling salesman problem.

PubMed

Andrecut, M; Ali, M K

2001-04-01

We investigate the finite size scaling of the mean optimal tour length as a function of density of obstacles in a constrained variant of the traveling salesman problem (TSP). The computational experience pointed out a critical transition (at rho(c) approximately 85%) in the dependence between the excess of the mean optimal tour length over the Held-Karp lower bound and the density of obstacles.

Structural charge site influence on the interlayer hydration of expandable three-sheet clay minerals

USGS Publications Warehouse

Kerns, Raymond L.; Mankin, Charles J.

1968-01-01

Previous investigations have demonstrated the influences of interlayer cation composition, relative humidity, temperature, and magnitude of interlayer surface charge on the interlayer hydration of montmorillonites and vermiculites. It has been suggested that the sites of layer charge deficiencies may also have an influence upon the amount of hydration that can take place in the interlayers of expandable clay minerals. If the interlayer cation-to-layer bonds are considered as ideally electrostatic, the magnitude of the forces resisting expansion may be expressed as a form of Coulomb's law. If this effect is significant, expandable structures in which the charge-deficiency sites are predominantly in the tetrahedral sheet should have less pronounced swelling properties than should structures possessing charge deficiencies located primarily in the octahedral sheet.Three samples that differed in location of layer charge sites were selected for study. An important selection criterion was a non-correlation between tetrahedral charge sites and high surface-charge density, and between octahedral charge sites and low surface-charge density.The effects of differences in interlayer cation composition were eliminated by saturating portions of each sample with the same cations. Equilibrium (001) d values at controlled constant humidities were used as a measure of the relative degree of interlayer hydration.Although no correlation could be made between the degree of interlayer hydration and total surface-charge density, the investigation does not eliminate total surface-charge density as being significant to the swelling properties of three-sheet clay-mineral structures. The results do indicate a correlation between more intense expandability and predominance of charge deficiencies in the octahedral sheet. Conversely, less intense swelling behavior is associated with predominantly tetrahedral charge deficiencies.

Phased occupation and retreat of the last British-Irish Ice Sheet in the southern North Sea; geomorphic and seismostratigraphic evidence of a dynamic ice lobe

NASA Astrophysics Data System (ADS)

Dove, Dayton; Evans, David J. A.; Lee, Jonathan R.; Roberts, David H.; Tappin, David R.; Mellett, Claire L.; Long, David; Callard, S. Louise

2017-05-01

Along the terrestrial margin of the southern North Sea, previous studies of the MIS 2 glaciation impacting eastern Britain have played a significant role in the development of principles relating to ice sheet dynamics (e.g. deformable beds), and the practice of reconstructing the style, timing, and spatial configuration of palaeo-ice sheets. These detailed terrestrially-based findings have however relied on observations made from only the outer edges of the former ice mass, as the North Sea Lobe (NSL) of the British-Irish Ice Sheet (BIIS) occupied an area that is now almost entirely submarine (c.21-15 ka). Compounded by the fact that marine-acquired data have been primarily of insufficient quality and density, the configuration and behaviour of the last BIIS in the southern North Sea remains surprisingly poorly constrained. This paper presents analysis of a new, integrated set of extensive seabed geomorphological and seismo-stratigraphic observations that both advances the principles developed previously onshore (e.g. multiple advance and retreat cycles), and provides a more detailed and accurate reconstruction of the BIIS at its southern-most extent in the North Sea. A new bathymetry compilation of the region reveals a series of broad sedimentary wedges and associated moraines that represent several terminal positions of the NSL. These former still-stand ice margins (1-4) are also found to relate to newly-identified architectural patterns (shallow stacked sedimentary wedges) in the region's seismic stratigraphy (previously mapped singularly as the Bolders Bank Formation). With ground-truthing constraint provided by sediment cores, these wedges are interpreted as sub-marginal till wedges, formed by complex subglacial accretionary processes that resulted in till thickening towards the former ice-sheet margins. The newly sub-divided shallow seismic stratigraphy (at least five units) also provides an indication of the relative event chronology of the NSL. While there is a general record of south-to-north retreat, seismic data also indicate episodes of ice-sheet re-advance suggestive of an oscillating margin (e.g. MIS 2 maximum not related to first incursion of ice into region). Demonstrating further landform interdependence, geographically-grouped sets of tunnel valleys are shown to be genetically related to these individual ice margins, providing clear insight into how meltwater drainage was organised at the evolving termini of this dynamic ice lobe. The newly reconstructed offshore ice margins are found to be well correlated with previously observed terrestrial limits in Lincolnshire and E. Yorkshire (Holderness) (e.g. MIS 2 maximum and Withernsea Till). This reconstruction will hopefully provide a useful framework for studies targeting the climatic, mass-balance, and external glaciological factors (i.e. Fennoscandian Ice Sheet) that influenced late-stage advance and deglaciation, important for accurately characterising both modern and palaeo-ice sheets.

Ice-coupled wave propagation across an abrupt change in ice rigidity, density, or thickness

NASA Astrophysics Data System (ADS)

Barrett, Murray D.; Squire, Vernon A.

1996-09-01

The model of Fox and Squire [1990, 1991, 1994], which discusses the oblique propagation of surface gravity waves from the open sea into an ice sheet of constant thickness and properties, is augmented to include propagation across an abrupt transition of properties within a continuous ice sheet or across two dissimilar ice sheets that abut one another but are free to move independently. Rigidity, thickness, and/or density may change across the transition, allowing, for example, the modeling of ice-coupled waves into, across, and out of refrozen leads and polynyas, across cracks, and through coherent pressure ridges. Reflection and transmission behavior is reported for various changes in properties under both types of transition conditions.

Kinetic Simulations of Current-Sheet Formation and Reconnection at a Magnetic X Line

NASA Technical Reports Server (NTRS)

Black, C.; Antiochos, S. K.; Hesse, M.; Karpen, J. T.; DeVore, C. R.; Kuznetsova, M. M.; Zenitani, S.

2011-01-01

The integration of kinetic effects into macroscopic numerical models is currently of great interest to the plasma physics community, particularly in the context of magnetic reconnection. We are examining the formation and reconnection of current sheets in a simple, two-dimensional X-line configuration using high resolution particle-in-cell (PIC) simulations. The initial potential magnetic field is perturbed by thermal pressure introduced into the particle distribution far from the X line. The relaxation of this added stress leads to the development of a current sheet, which reconnects for imposed stress of sufficient strength. We compare the evolution and final state of our PIC simulations with magnetohydrodynamic simulations assuming both uniform and localized resistivities, and with force-free magnetic-field equilibria in which the amount of reconnect ion across the X line can be constrained to be zero (ideal evolution) or optimal (minimum final magnetic energy). We will discuss implications of our results for reconnection onset and cessation at kinetic scales in dynamically formed current sheets, such as those occurring in the terrestrial magnetotail and solar corona.

Postglacial Rebound and Current Ice Loss Estimates from Space Geodesy: The New ICE-6G (VM5a) Global Model

NASA Astrophysics Data System (ADS)

Peltier, W. R.; Argus, D.; Drummond, R.; Moore, A. W.

2012-12-01

We compare, on a global basis, estimates of site velocity against predictions of the newly constructed postglacial rebound model ICE-6G (VM5a). This model is fit to observations of North American postglacial rebound thereby demonstrating that the ice sheet at last glacial maximum must have been, relative to ICE-5G,thinner in southern Manitoba, thinner near Yellowknife (northwest Territories), thicker in eastern and southern Quebec, and thicker along the British Columbia-Alberta border. The GPS based estimates of site velocity that we employ are more accurate than were previously available because they are based on GPS estimates of position as a function of time determined by incorporating satellite phase center variations [Desai et al. 2011]. These GPS estimates are constraining postglacial rebound in North America and Europe more tightly than ever before. In particular, given the high density of GPS sites in North America, and the fact that the velocity of the mass center (CM) of Earth is also more tightly constrained, the new model much more strongly constrains both the lateral extent of the proglacial forebulge and the rate at which this peripheral bulge (that was emplaced peripheral to the late Pleistocence Laurentia ice sheet) is presently collapsing. This fact proves to be important to the more accurate inference of the current rate of ice loss from both Greenland and Alaska based upon the time dependent gravity observations being provided by the GRACE satellite system. In West Antarctica we have also been able to significantly revise the previously prevalent ICE-5G deglaciation history so as to enable its predictions to be optimally consistent with GPS site velocities determined by connecting campaign WAGN measurements to those provided by observations from the permanent ANET sites. Ellsworth Land (south of the Antarctic peninsula), is observed to be rising at 6 ±3 mm/yr according to our latest analyses; the Ellsworth mountains themselves are observed to be rising at 5 ±4 mm/yr; Palmer Land is observed to be rising at 3 ±3 mm/yr. The predictions of the ICE-5G (VM2) model and those of the postglacial rebound component of the model of Simons, Ivins, and James [2010] had predicted uplift to be significantly faster than observed in this region, as previously documented in Argus et al [2011]. From a global perspective the new ICE-6G (VM5a) model is also a further significant improvement on the previous ICE-5G (VM2) model in that the degree two and order one components of its predicted time dependence of geoid height are tightly constrained by the recent inferences of Roy and Peltier [2011] of the post-GRACE-launch values of the speed and direction of true polar wander and the non-tidal acceleration of the lod. .

Adjoint-Based Sensitivity and Uncertainty Analysis for Density and Composition: A User’s Guide

DOE PAGES

Favorite, Jeffrey A.; Perko, Zoltan; Kiedrowski, Brian C.; ...

2017-03-01

The ability to perform sensitivity analyses using adjoint-based first-order sensitivity theory has existed for decades. This paper provides guidance on how adjoint sensitivity methods can be used to predict the effect of material density and composition uncertainties in critical experiments, including when these uncertain parameters are correlated or constrained. Two widely used Monte Carlo codes, MCNP6 (Ref. 2) and SCALE 6.2 (Ref. 3), are both capable of computing isotopic density sensitivities in continuous energy and angle. Additionally, Perkó et al. have shown how individual isotope density sensitivities, easily computed using adjoint methods, can be combined to compute constrained first-order sensitivitiesmore » that may be used in the uncertainty analysis. This paper provides details on how the codes are used to compute first-order sensitivities and how the sensitivities are used in an uncertainty analysis. Constrained first-order sensitivities are computed in a simple example problem.« less

Magnetic exchange couplings from constrained density functional theory: an efficient approach utilizing analytic derivatives.

PubMed

Phillips, Jordan J; Peralta, Juan E

2011-11-14

We introduce a method for evaluating magnetic exchange couplings based on the constrained density functional theory (C-DFT) approach of Rudra, Wu, and Van Voorhis [J. Chem. Phys. 124, 024103 (2006)]. Our method shares the same physical principles as C-DFT but makes use of the fact that the electronic energy changes quadratically and bilinearly with respect to the constraints in the range of interest. This allows us to use coupled perturbed Kohn-Sham spin density functional theory to determine approximately the corrections to the energy of the different spin configurations and construct a priori the relevant energy-landscapes obtained by constrained spin density functional theory. We assess this methodology in a set of binuclear transition-metal complexes and show that it reproduces very closely the results of C-DFT. This demonstrates a proof-of-concept for this method as a potential tool for studying a number of other molecular phenomena. Additionally, routes to improving upon the limitations of this method are discussed. © 2011 American Institute of Physics

Friis Hills Drilling Project - Coring an Early to mid-Miocene terrestrial sequence in the Transantarctic Mountains to examine climate gradients and ice sheet variability along an inland-to-offshore transect

NASA Astrophysics Data System (ADS)

Lewis, A. R.; Levy, R. H.; Naish, T.; Gorman, A. R.; Golledge, N.; Dickinson, W. W.; Kraus, C.; Florindo, F.; Ashworth, A. C.; Pyne, A.; Kingan, T.

2015-12-01

The Early to mid-Miocene is a compelling interval to study Antarctic ice sheet (AIS) sensitivity. Circulation patterns in the southern hemisphere were broadly similar to present and reconstructed atmospheric CO2 concentrations were analogous to those projected for the next several decades. Geologic records from locations proximal to the AIS are required to examine ice sheet response to climate variability during this time. Coastal and offshore drill core records recovered by ANDRILL and IODP provide information regarding ice sheet variability along and beyond the coastal margin but they cannot constrain the extent of inland retreat. Additional environmental data from the continental interior is required to constrain the magnitude of ice sheet variability and inform numerical ice sheet models. The only well-dated terrestrial deposits that register early to mid-Miocene interior ice extent and climate are in the Friis Hills, 80 km inland. The deposits record multiple glacial-interglacial cycles and fossiliferous non-glacial beds show that interglacial climate was warm enough for a diverse biota. Drifts are preserved in a shallow valley with the oldest beds exposed along the edges where they terminate at sharp erosional margins. These margins reveal drifts in short stratigraphic sections but none is more than 13 m thick. A 34 m-thick composite stratigraphic sequence has been produced from exposed drift sequences but correlating beds in scattered exposures is problematic. Moreover, much of the sequence is buried and inaccessible in the basin center. New seismic data collected during 2014 reveal a sequence of sediments at least 50 m thick. This stratigraphic package likely preserves a detailed and more complete sedimentary sequence for the Friis Hills that can be used to refine and augment the outcrop-based composite stratigraphy. We aim to drill through this sequence using a helicopter-transportable diamond coring system. These new cores will allow us to obtain continuous measurements on unweathered material through the terrestrial sequence. Beds of tephra are exposed in outcrop and we expect to encounter these key age markers in the cored sequence. These new high quality, well-dated terrestrial data will be directly compared to marine cores to provide environmental data across a broad onshore-offshore transect.

The Distribution of Basal Water Beneath the Greenland Ice Sheet from Radio-Echo Sounding

NASA Astrophysics Data System (ADS)

Jordan, T.; Williams, C.; Schroeder, D. M.; Martos, Y. M.; Cooper, M.; Siegert, M. J.; Paden, J. D.; Huybrechts, P.; Bamber, J. L.

2017-12-01

There is widespread, but often indirect, evidence that a significant fraction of the Greenland Ice Sheet is thawed at the bed. This includes major outlet glaciers and around the NorthGRIP ice-core in the interior. However, the ice-sheet-wide distribution of basal water is poorly constrained by existing observations, and the spatial relationship between basal water and other ice-sheet and subglacial properties is therefore largely unexplored. In principle, airborne radio-echo sounding (RES) surveys provide the necessary information and spatial coverage to infer the presence of basal water at the ice-sheet scale. However, due to uncertainty and spatial variation in radar signal attenuation, the commonly used water diagnostic, bed-echo reflectivity, is highly ambiguous and prone to spatial bias. Here we introduce a new RES diagnostic for the presence of basal water which incorporates both sharp step-transitions and rapid fluctuations in bed-echo reflectivity. This has the advantage of being (near) independent of attenuation model, and enables a decade of recent Operation Ice Bride RES survey data to be combined in a single map for basal water. The ice-sheet-wide water predictions are compared with: bed topography and drainage network structure, existing knowledge of the thermal state and geothermal heat flux, and ice velocity. In addition to the fast flowing ice-sheet margins, we also demonstrate widespread water routing and storage in parts of the slow-flowing northern interior. Notably, this includes a quasi-linear `corridor' of basal water, extending from NorthGRIP to Petermann glacier, which spatially correlates with a region of locally high (magnetic-derived) geothermal heat flux. The predicted water distribution places a new constraint upon the basal thermal state of the Greenland Ice Sheet, and could be used as an input for ice-sheet model simulations.

Repeated large-scale retreat and advance of Totten Glacier indicated by inland bed erosion.

PubMed

Aitken, A R A; Roberts, J L; van Ommen, T D; Young, D A; Golledge, N R; Greenbaum, J S; Blankenship, D D; Siegert, M J

2016-05-19

Climate variations cause ice sheets to retreat and advance, raising or lowering sea level by metres to decametres. The basic relationship is unambiguous, but the timing, magnitude and sources of sea-level change remain unclear; in particular, the contribution of the East Antarctic Ice Sheet (EAIS) is ill defined, restricting our appreciation of potential future change. Several lines of evidence suggest possible collapse of the Totten Glacier into interior basins during past warm periods, most notably the Pliocene epoch, causing several metres of sea-level rise. However, the structure and long-term evolution of the ice sheet in this region have been understood insufficiently to constrain past ice-sheet extents. Here we show that deep ice-sheet erosion-enough to expose basement rocks-has occurred in two regions: the head of the Totten Glacier, within 150 kilometres of today's grounding line; and deep within the Sabrina Subglacial Basin, 350-550 kilometres from this grounding line. Our results, based on ICECAP aerogeophysical data, demarcate the marginal zones of two distinct quasi-stable EAIS configurations, corresponding to the 'modern-scale' ice sheet (with a marginal zone near the present ice-sheet margin) and the retreated ice sheet (with the marginal zone located far inland). The transitional region of 200-250 kilometres in width is less eroded, suggesting shorter-lived exposure to eroding conditions during repeated retreat-advance events, which are probably driven by ocean-forced instabilities. Representative ice-sheet models indicate that the global sea-level increase resulting from retreat in this sector can be up to 0.9 metres in the modern-scale configuration, and exceeds 2 metres in the retreated configuration.

Past ice-sheet behaviour: retreat scenarios and changing controls in the Ross Sea, Antarctica

NASA Astrophysics Data System (ADS)

Halberstadt, Anna Ruth W.; Simkins, Lauren M.; Greenwood, Sarah L.; Anderson, John B.

2016-05-01

Studying the history of ice-sheet behaviour in the Ross Sea, Antarctica's largest drainage basin can improve our understanding of patterns and controls on marine-based ice-sheet dynamics and provide constraints for numerical ice-sheet models. Newly collected high-resolution multibeam bathymetry data, combined with two decades of legacy multibeam and seismic data, are used to map glacial landforms and reconstruct palaeo ice-sheet drainage. During the Last Glacial Maximum, grounded ice reached the continental shelf edge in the eastern but not western Ross Sea. Recessional geomorphic features in the western Ross Sea indicate virtually continuous back-stepping of the ice-sheet grounding line. In the eastern Ross Sea, well-preserved linear features and a lack of small-scale recessional landforms signify rapid lift-off of grounded ice from the bed. Physiography exerted a first-order control on regional ice behaviour, while sea floor geology played an important subsidiary role. Previously published deglacial scenarios for Ross Sea are based on low-spatial-resolution marine data or terrestrial observations; however, this study uses high-resolution basin-wide geomorphology to constrain grounding-line retreat on the continental shelf. Our analysis of retreat patterns suggests that (1) retreat from the western Ross Sea was complex due to strong physiographic controls on ice-sheet drainage; (2) retreat was asynchronous across the Ross Sea and between troughs; (3) the eastern Ross Sea largely deglaciated prior to the western Ross Sea following the formation of a large grounding-line embayment over Whales Deep; and (4) our glacial geomorphic reconstruction converges with recent numerical models that call for significant and complex East Antarctic ice sheet and West Antarctic ice sheet contributions to the ice flow in the Ross Sea.

Interlayer interaction and mechanical properties in multi-layer graphene, Boron-Nitride, Aluminum-Nitride and Gallium-Nitride graphene-like structure: A quantum-mechanical DFT study

NASA Astrophysics Data System (ADS)

Ghorbanzadeh Ahangari, Morteza; Fereidoon, A.; Hamed Mashhadzadeh, Amin

2017-12-01

In present study, we investigated mechanical, electronic and interlayer properties of mono, bi and 3layer of Boron-Nitride (B-N), Aluminum-Nitride (Al-N) and Gallium-Nitride (Ga-N) graphene sheets and compared these results with results obtained from carbonic graphenes (C-graphenes). For reaching this purpose, first we optimized the geometrical parameters of these graphenes by using density functional theory (DFT) method. Then we calculated Young's modulus of graphene sheet by compressing and then elongating these sheets in small increment. Our results indicates that Young's modulus of graphenes didn't changed obviously by increasing the number of layer sheet. We also found that carbonic graphene has greatest Young's modulus among another mentioned sheets because of smallest equilibrium distance between its elements. Next we modeled the van der Waals interfacial interaction exist between two sheets with classical spring model by using general form of Lennard-Jones (L-J) potential for all of mentioned graphenes. For calculating L-J parameters (ε and σ), the potential energy between layers of mentioned graphene as a function of the separation distance was plotted. Moreover, the density of states (DOS) are calculated to understand the electronic properties of these systems better.

Joule heating and runaway electron acceleration in a solar flare

NASA Technical Reports Server (NTRS)

Holman, Gordon D.; Kundu, Mukul R.; Kane, Sharad R.

1989-01-01

The hard and soft x ray and microwave emissions from a solar flare (May 14, 1980) were analyzed and interpreted in terms of Joule heating and runaway electron acceleration in one or more current sheets. It is found that all three emissions can be generated with sub-Dreicer electric fields. The soft x ray emitting plasma can only be heated by a single current sheet if the resistivity in the sheet is well above the classical, collisional resistivity of 10(exp 7) K, 10(exp 11)/cu cm plasma. If the hard x ray emission is from thermal electrons, anomalous resistivity or densities exceeding 3 x 10(exp 12)/cu cm are required. If the hard x ray emission is from nonthermal electrons, the emissions can be produced with classical resistivity in the current sheets if the heating rate is approximately 4 times greater than that deduced from the soft x ray data (with a density of 10(exp 10)/cu cm in the soft x ray emitting region), if there are at least 10(exp 4) current sheets, and if the plasma properties in the sheets are characteristic of the superhot plasma observed in some flares by Lin et al., and with Hinotori. Most of the released energy goes directly into bulk heating, rather than accelerated particles.

A view from the terrace; ice-sheet dynamics during the Eocene Oligocene Transition climate tipping point

NASA Astrophysics Data System (ADS)

Scher, Howie; Bohaty, Steven; Huck, Claire

2017-04-01

Glaciation of Antarctica was the pièce de résistance of the shift in global climate that took place during the Eocene Oligocene Transition (EOT; ca. 34 Ma). The timing and progression of ice-sheet development is constrained by benthic foraminiferal d18O records and geochemical proxies for continental weathering from deep-sea sediment cores. The terrace interval is the roughly 500 kyr interval after the precursor glaciation at 34.2 Ma, when ice-sheet expansion reached a short-lived plateau prior to the coalescence of a continent-scale ice sheet at 33.7 Ma. The terrace interval appears to be the tipping point between greenhouse and icehouse climate states, however ice-sheet dynamics are poorly understood during this crucial time. We present evidence for rapid changes in the Nd isotopic composition of bottom waters bathing a sediment core on Maud Rise (ODP Site 689) during the terrace interval of the EOT. Three distinct excursions toward less radiogenic eNd values suggest either 1) changes in the flux of Antarctic weathering products into the Weddell Sea and/or 2) pulses of deep water production that brought shelf waters with the Antarctic Nd isotope fingerprint into contact with Maud Rise. Both interpretations support a scenario of expansion and contraction of the Antarctic ice sheet during the terrace interval.

Predicting uncertainty in future marine ice sheet volume using Bayesian statistical methods

NASA Astrophysics Data System (ADS)

Davis, A. D.

2015-12-01

The marine ice instability can trigger rapid retreat of marine ice streams. Recent observations suggest that marine ice systems in West Antarctica have begun retreating. However, unknown ice dynamics, computationally intensive mathematical models, and uncertain parameters in these models make predicting retreat rate and ice volume difficult. In this work, we fuse current observational data with ice stream/shelf models to develop probabilistic predictions of future grounded ice sheet volume. Given observational data (e.g., thickness, surface elevation, and velocity) and a forward model that relates uncertain parameters (e.g., basal friction and basal topography) to these observations, we use a Bayesian framework to define a posterior distribution over the parameters. A stochastic predictive model then propagates uncertainties in these parameters to uncertainty in a particular quantity of interest (QoI)---here, the volume of grounded ice at a specified future time. While the Bayesian approach can in principle characterize the posterior predictive distribution of the QoI, the computational cost of both the forward and predictive models makes this effort prohibitively expensive. To tackle this challenge, we introduce a new Markov chain Monte Carlo method that constructs convergent approximations of the QoI target density in an online fashion, yielding accurate characterizations of future ice sheet volume at significantly reduced computational cost.Our second goal is to attribute uncertainty in these Bayesian predictions to uncertainties in particular parameters. Doing so can help target data collection, for the purpose of constraining the parameters that contribute most strongly to uncertainty in the future volume of grounded ice. For instance, smaller uncertainties in parameters to which the QoI is highly sensitive may account for more variability in the prediction than larger uncertainties in parameters to which the QoI is less sensitive. We use global sensitivity analysis to help answer this question, and make the computation of sensitivity indices computationally tractable using a combination of polynomial chaos and Monte Carlo techniques.

Continuous development of current sheets near and away from magnetic nulls

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Sanjay; Bhattacharyya, R.

2016-04-15

The presented computations compare the strength of current sheets which develop near and away from the magnetic nulls. To ensure the spontaneous generation of current sheets, the computations are performed congruently with Parker's magnetostatic theorem. The simulations evince current sheets near two dimensional and three dimensional magnetic nulls as well as away from them. An important finding of this work is in the demonstration of comparative scaling of peak current density with numerical resolution, for these different types of current sheets. The results document current sheets near two dimensional magnetic nulls to have larger strength while exhibiting a stronger scalingmore » than the current sheets close to three dimensional magnetic nulls or away from any magnetic null. The comparative scaling points to a scenario where the magnetic topology near a developing current sheet is important for energetics of the subsequent reconnection.« less

High volumetric supercapacitor with a long life span based on polymer dots and graphene sheets

NASA Astrophysics Data System (ADS)

Wei, Ji-Shi; Chen, Jie; Ding, Hui; Zhang, Peng; Wang, Yong-Gang; Xiong, Huan-Ming

2017-10-01

A series of polymer dots/graphene sheets composites with high densities are prepared and tested for supercapacitors. Polymer dots (PDs) are synthesized by one-step method at room temperature. They can effectively increase surface areas of the composites (almost 10 times), and the functional groups from PDs produce high pseudocapacitance, so that the samples exhibit high specific capacitances (e. g., 364.2 F cm-3 at 1 A g-1) and high cycling stability (e. g., more than 95% of the initial capacity retention over 10 000 cycles at different current densities). The optimal sample is employed to fabricate a symmetric supercapacitor, which exhibits an energy density up to 8 Wh L-1 and a power density up to 11 800 W L-1, respectively.

A Tailward Moving Current Sheet Normal Magnetic Field Front Followed by an Earthward Moving Dipolarization Front

NASA Technical Reports Server (NTRS)

Hwang, K.-J.; Goldstein, M. L.; Moore, T. E.; Walsh, B. M.; Baishev, D. G.; Moiseyev, A. V.; Shevtsov, B. M.; Yumoto, K.

2014-01-01

A case study is presented using measurements from the Cluster spacecraft and ground-based magnetometers that show a substorm onset propagating from the inner to outer plasma sheet. On 3 October 2005, Cluster, traversing an ion-scale current sheet at the near-Earth plasma sheet, detected a sudden enhancement of Bz, which was immediately followed by a series of flux rope structures. Both the local Bz enhancement and flux ropes propagated tailward. Approximately 5 min later, another Bz enhancement, followed by a large density decrease, was observed to rapidly propagate earthward. Between the two Bz enhancements, a significant removal of magnetic flux occurred, possibly resulting from the tailward moving Bz enhancement and flux ropes. In our scenario, this flux removal caused the magnetotail to be globally stretched so that the thinnest sheet formed tailward of Cluster. The thinned current sheet facilitated magnetic reconnection that quickly evolved from plasma sheet to lobe and generated the later earthward moving dipolarization front (DF) followed by a reduction in density and entropy. Ground magnetograms located near the meridian of Cluster's magnetic foot points show two-step bay enhancements. The positive bay associated with the first Bz enhancement indicates that the substorm onset signatures propagated from the inner to the outer plasma sheet, consistent with the Cluster observation. The more intense bay features associated with the later DF are consistent with the earthward motion of the front. The event suggests that current disruption signatures that originated in the near-Earth current sheet propagated tailward, triggering or facilitating midtail reconnection, thereby preconditioning the magnetosphere for a later strong substorm enhancement.

Evidence for elevated and spatially variable geothermal flux beneath the West Antarctic Ice Sheet

PubMed Central

Schroeder, Dustin M.; Blankenship, Donald D.; Young, Duncan A.; Quartini, Enrica

2014-01-01

Heterogeneous hydrologic, lithologic, and geologic basal boundary conditions can exert strong control on the evolution, stability, and sea level contribution of marine ice sheets. Geothermal flux is one of the most dynamically critical ice sheet boundary conditions but is extremely difficult to constrain at the scale required to understand and predict the behavior of rapidly changing glaciers. This lack of observational constraint on geothermal flux is particularly problematic for the glacier catchments of the West Antarctic Ice Sheet within the low topography of the West Antarctic Rift System where geothermal fluxes are expected to be high, heterogeneous, and possibly transient. We use airborne radar sounding data with a subglacial water routing model to estimate the distribution of basal melting and geothermal flux beneath Thwaites Glacier, West Antarctica. We show that the Thwaites Glacier catchment has a minimum average geothermal flux of ∼114 ± 10 mW/m2 with areas of high flux exceeding 200 mW/m2 consistent with hypothesized rift-associated magmatic migration and volcanism. These areas of highest geothermal flux include the westernmost tributary of Thwaites Glacier adjacent to the subaerial Mount Takahe volcano and the upper reaches of the central tributary near the West Antarctic Ice Sheet Divide ice core drilling site. PMID:24927578

Covalent addition of chitosan to graphene sheets: Density functional theory explorations of quadrupole coupling constants

NASA Astrophysics Data System (ADS)

Mokhtari, Ali; Harismah, Kun; Mirzaei, Mahmoud

2015-12-01

Density functional theory (DFT) calculations have been performed to detect the stabilities and properties of chitosan-functionalized graphene and graphene-oxide structures (G-Chit and GO-Chit). The model systems with two different sizes of sheets have been optimized and the molecular and atomic properties have been evaluated for them. The results indicated that investigated G-Chit and GO-Chit structures could be considered as stable structures but with different properties. The properties for GO and GO-Chit structures are almost similar; however, they are different from the original G and G-Chit structures. The results also indicated that the properties could be also size-dependent, in which different molecular and atomic properties have been observed for the investigate G sheets.

Development of Rolling Schedules for AZ31 Magnesium Alloy Sheets

DTIC Science & Technology

2015-06-01

Materials 2 2.2 Hot Rolling 3 2.2 Sample Characterization: Microstructure and Tensile Properties 3 3. Rolling Experiments 5 3.1 High-Temperature...material systems for protective and structural applications, especially in ground vehicles. Magnesium (Mg), due to its low density (~25% that of steel ...applications, wrought Mg is difficult to produce in thin sheets because of its inherently low ductility . As a result, Mg sheet is often produced at

Prestack density inversion using the Fatti equation constrained by the P- and S-wave impedance and density

NASA Astrophysics Data System (ADS)

Liang, Li-Feng; Zhang, Hong-Bing; Dan, Zhi-Wei; Xu, Zi-Qiang; Liu, Xiu-Juan; Cao, Cheng-Hao

2017-03-01

Simultaneous prestack inversion is based on the modified Fatti equation and uses the ratio of the P- and S-wave velocity as constraints. We use the relation of P-wave impedance and density (PID) and S-wave impedance and density (SID) to replace the constant Vp/Vs constraint, and we propose the improved constrained Fatti equation to overcome the effect of P-wave impedance on density. We compare the sensitivity of both methods using numerical simulations and conclude that the density inversion sensitivity improves when using the proposed method. In addition, the random conjugate-gradient method is used in the inversion because it is fast and produces global solutions. The use of synthetic and field data suggests that the proposed inversion method is effective in conventional and nonconventional lithologies.

Cosmogenic exposure age constraints on deglaciation and flow behaviour of a marine-based ice stream in western Scotland, 21-16 ka

NASA Astrophysics Data System (ADS)

Small, David; Benetti, Sara; Dove, Dayton; Ballantyne, Colin K.; Fabel, Derek; Clark, Chris D.; Gheorghiu, Delia M.; Newall, Jennifer; Xu, Sheng

2017-07-01

Understanding how marine-based ice streams operated during episodes of deglaciation requires geochronological data that constrain both timing of deglaciation and changes in their flow behaviour, such as that from unconstrained ice streaming to topographically restricted flow. We present seventeen new 10Be exposure ages from glacial boulders and bedrock at sites in western Scotland within the area drained by the Hebrides Ice Stream, a marine-based ice stream that drained a large proportion of the former British-Irish Ice Sheet. Exposure ages from Tiree constrain deglaciation of a topographic high within the central zone of the ice stream, from which convergent flowsets were produced during ice streaming. These ages thus constrain thinning of the Hebrides Ice Stream, which, on the basis of supporting information, we infer to represent cessation of ice streaming at 20.6 ± 1.2 ka, 3-4 ka earlier than previously inferred. A period of more topographically restricted flow produced flow indicators superimposed on those relating to full ice stream conditions, and exposure ages from up-stream of these constrain deglaciation to 17.5 ± 1.0 ka. Complete deglaciation of the marine sector of the Hebrides Ice Stream occurred by 17-16 ka at which time the ice margin was located near the present coastline. Exposure ages from the southernmost Outer Hebrides (Mingulay and Barra) indicate deglaciation at 18.9 ± 1.0 and 17.1 ± 1.0 ka respectively, demonstrating that an independent ice cap persisted on the southern Outer Hebrides for 3-4 ka after initial ice stream deglaciation. This suggests that deglaciation of the Hebrides Ice Stream was focused along major submarine troughs. Collectively, our data constrain initial deglaciation and changes in flow regime of the Hebrides Ice Stream, final deglaciation of its marine sector, and deglaciation of the southern portion of the independent Outer Hebrides Ice Cap, providing chronological constraints on future numerical reconstructions of this key sector of the former British-Irish Ice Sheet.

Quantification of Sheet Resistance in Boron-Diffused Silicon Using Micro-Photoluminescence Spectroscopy at Room Temperature

DOE PAGES

Nguyen, Hieu T.; Johnston, Steve; Paduthol, Appu; ...

2017-09-01

A micro-photoluminescence-based technique is presented, to quantify and map sheet resistances of boron-diffused layers in silicon solar cell precursors with micron-scale spatial resolution at room temperature. The technique utilizes bandgap narrowing effects in the heavily-doped layers, yielding a broader photoluminescence spectrum at the long-wavelength side compared to the spectrum emitted from lightly doped silicon. By choosing an appropriate spectral range as a metric to assess the doping density, the impacts of photon reabsorption on the analysis can be avoided; thus, an accurate characterization of the sheet resistance can be made. This metric is demonstrated to be better representative of themore » sheet resistance than the surface doping density or the total dopant concentration of the diffused layer. The technique is applied to quantify sheet resistances of 12-um-wide diffused fingers in interdigitated back-contact solar cell precursors and large diffused areas. The results are confirmed by both 4-point probe and time-of-flight secondary-ion mass spectrometry measurements. Lastly, the practical limitations associated with extending the proposed technique into an imaging mode are presented and explained.« less

Quantification of Sheet Resistance in Boron-Diffused Silicon Using Micro-Photoluminescence Spectroscopy at Room Temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nguyen, Hieu T.; Johnston, Steve; Paduthol, Appu

A micro-photoluminescence-based technique is presented, to quantify and map sheet resistances of boron-diffused layers in silicon solar cell precursors with micron-scale spatial resolution at room temperature. The technique utilizes bandgap narrowing effects in the heavily-doped layers, yielding a broader photoluminescence spectrum at the long-wavelength side compared to the spectrum emitted from lightly doped silicon. By choosing an appropriate spectral range as a metric to assess the doping density, the impacts of photon reabsorption on the analysis can be avoided; thus, an accurate characterization of the sheet resistance can be made. This metric is demonstrated to be better representative of themore » sheet resistance than the surface doping density or the total dopant concentration of the diffused layer. The technique is applied to quantify sheet resistances of 12-um-wide diffused fingers in interdigitated back-contact solar cell precursors and large diffused areas. The results are confirmed by both 4-point probe and time-of-flight secondary-ion mass spectrometry measurements. Lastly, the practical limitations associated with extending the proposed technique into an imaging mode are presented and explained.« less

Spectroscopic Diagnostics of Electric Fields in the Plasma of Current Sheets

NASA Astrophysics Data System (ADS)

Gavrilenko, Valeri; Kyrie, Natalya P.; Frank, Anna G.; Oks, Eugene

2004-11-01

Spectroscopic measurements of electric fields (EFs) in current sheet plasmas were performed in the CS-3D device. The device is intended to study the evolution of current sheets and the magnetic reconnection phenomena. We used the broadening of spectral lines (SLs) of HeII ions for diagnostics of EFs in the current sheet middle plane, and the broadening of SLs of HeI atoms for detection of EFs in the current sheet peripheral regions. For detection of EFs in current sheet plasma, we used SLs of HeII ions at 468.6; 320.3 and 656.0 nm, as well as SLs of HeI atoms at 667.8; 587.6; 492.2 and 447.1 nm. The latter two lines are of a special interest since their profiles include the dipole-forbidden components along with the allowed components. The experimental data have been analyzed by using the numerical calculations based on the Model Microfield Method. The maximum plasma density in the middle of the sheet was in the range (2-8) × 10^16 cm-3, the density in the peripheral regions was (1-2)×10^15 cm-3, and the strength of the quasi-one-dimensional anomalous electric fields in the peripheral regions reached the value of 100 kV/cm. Supported by CRDF, grant RU-P1-2594-MO-04; by the RFBR, grant 03-02-17282; and by the ISTC, project 2098.

Retreat of the Coalescent Greenland and Innuitian Ice Sheets from Nares Strait

NASA Astrophysics Data System (ADS)

Jennings, A. E.; Bailey, E.; Oliver, B.; Andrews, J. T.; Prins, M. A.; Troelstra, S.; Stoner, J. S.; Reilly, B. T.; Davies-Walczak, M.; Mix, A. C.

2015-12-01

Nares Strait, which forms one of the main connections between the Arctic Ocean and Baffin Bay was blocked by coalescent Innuitian and Greenland ice sheets during the LGM. Nares Strait opened ca. 9000 cal ka BP when the connection between the two ice sheets was finally severed. Our research focuses on the events and processes leading up to the opening of the strait and the response of the glacier and marine systems to establishment of the throughflow. The study at present involves new analysis of two sediment cores: 2001LSSL-163PC from Smith Sound, at the southern end of Nares Strait, and 2001LSSL-079PC from the mouth of Petermann Fjord at the northern end of the strait. X-radiography and core photographs were studied to establish basic lithofacies and stratigraphy. Foraminiferal faunas provide insight into changes in ice margin proximity, Atlantic Water advection and sea-ice conditions and are used to develop the radiocarbon chronologies. Quantitative X-ray diffraction analysis of bulk sediments aids in determining sediment provenance and the establishment of a north to south connection. Grain size analysis allows sediment processes and sedimentary environments, such as iceberg rafting, current deposition, and sub ice-shelf deposition to be evaluated. A radiocarbon date of >50 kyr was obtained from foraminifera in an overconsolidated, gray diamicton in core 163PC. The diamicton is overlain by a red deglacial sequence of barren laminated sediments followed by gray pebbly mud. Two radiocarbon dates submitted from near the base of the pebbly mud constrain the timing of ice retreat from Smith Sound. The chronology of core 079PC indicates that it captures the opening of Nares Strait, but 4 submitted radiocarbon dates will further constrain its chronology. The goal of the work on these two cores is to lay a framework for extensive marine fieldwork to study ice sheet-ocean interactions in the Petermann Glacier in late summer 2015.

Potential sea-level rise from Antarctic ice-sheet instability constrained by observations.

PubMed

Ritz, Catherine; Edwards, Tamsin L; Durand, Gaël; Payne, Antony J; Peyaud, Vincent; Hindmarsh, Richard C A

2015-12-03

Large parts of the Antarctic ice sheet lying on bedrock below sea level may be vulnerable to marine-ice-sheet instability (MISI), a self-sustaining retreat of the grounding line triggered by oceanic or atmospheric changes. There is growing evidence that MISI may be underway throughout the Amundsen Sea embayment (ASE), which contains ice equivalent to more than a metre of global sea-level rise. If triggered in other regions, the centennial to millennial contribution could be several metres. Physically plausible projections are challenging: numerical models with sufficient spatial resolution to simulate grounding-line processes have been too computationally expensive to generate large ensembles for uncertainty assessment, and lower-resolution model projections rely on parameterizations that are only loosely constrained by present day changes. Here we project that the Antarctic ice sheet will contribute up to 30 cm sea-level equivalent by 2100 and 72 cm by 2200 (95% quantiles) where the ASE dominates. Our process-based, statistical approach gives skewed and complex probability distributions (single mode, 10 cm, at 2100; two modes, 49 cm and 6 cm, at 2200). The dependence of sliding on basal friction is a key unknown: nonlinear relationships favour higher contributions. Results are conditional on assessments of MISI risk on the basis of projected triggers under the climate scenario A1B (ref. 9), although sensitivity to these is limited by theoretical and topographical constraints on the rate and extent of ice loss. We find that contributions are restricted by a combination of these constraints, calibration with success in simulating observed ASE losses, and low assessed risk in some basins. Our assessment suggests that upper-bound estimates from low-resolution models and physical arguments (up to a metre by 2100 and around one and a half by 2200) are implausible under current understanding of physical mechanisms and potential triggers.

Potential sea-level rise from Antarctic ice-sheet instability constrained by observations

NASA Astrophysics Data System (ADS)

Ritz, Catherine; Edwards, Tamsin L.; Durand, Gaël; Payne, Antony J.; Peyaud, Vincent; Hindmarsh, Richard C. A.

2015-12-01

Large parts of the Antarctic ice sheet lying on bedrock below sea level may be vulnerable to marine-ice-sheet instability (MISI), a self-sustaining retreat of the grounding line triggered by oceanic or atmospheric changes. There is growing evidence that MISI may be underway throughout the Amundsen Sea embayment (ASE), which contains ice equivalent to more than a metre of global sea-level rise. If triggered in other regions, the centennial to millennial contribution could be several metres. Physically plausible projections are challenging: numerical models with sufficient spatial resolution to simulate grounding-line processes have been too computationally expensive to generate large ensembles for uncertainty assessment, and lower-resolution model projections rely on parameterizations that are only loosely constrained by present day changes. Here we project that the Antarctic ice sheet will contribute up to 30 cm sea-level equivalent by 2100 and 72 cm by 2200 (95% quantiles) where the ASE dominates. Our process-based, statistical approach gives skewed and complex probability distributions (single mode, 10 cm, at 2100; two modes, 49 cm and 6 cm, at 2200). The dependence of sliding on basal friction is a key unknown: nonlinear relationships favour higher contributions. Results are conditional on assessments of MISI risk on the basis of projected triggers under the climate scenario A1B (ref. 9), although sensitivity to these is limited by theoretical and topographical constraints on the rate and extent of ice loss. We find that contributions are restricted by a combination of these constraints, calibration with success in simulating observed ASE losses, and low assessed risk in some basins. Our assessment suggests that upper-bound estimates from low-resolution models and physical arguments (up to a metre by 2100 and around one and a half by 2200) are implausible under current understanding of physical mechanisms and potential triggers.

Rise in central west Greenland surface melt unprecedented over the last three centuries

NASA Astrophysics Data System (ADS)

Trusel, Luke; Das, Sarah; Osman, Matthew; Evans, Matthew; Smith, Ben; McConnell, Joe; Noël, Brice; van den Broeke, Michiel

2017-04-01

Greenland Ice Sheet surface melting has intensified and expanded over the last several decades and is now a leading component of ice sheet mass loss. Here, we constrain the multi-century temporal evolution of surface melt across central west Greenland by quantifying layers of refrozen melt within well-dated firn and ice cores collected in 2014 and 2015, as well as from a core collected in 2004. We find significant agreement among ice core, satellite, and regional climate model melt datasets over recent decades, confirming the fidelity of the ice core melt stratigraphy as a reliable record of past variability in the magnitude of surface melt. We also find a significant correlation between the melt records derived from our new 100-m GC-2015 core (2436 m.a.s.l.) and the older (2004) 150-m D5 core (2472 m.a.s.l.) located 50 km to the southeast. This agreement demonstrates the robustness of the ice core-derived melt histories and the potential for reconstructing regional melt evolution from a single site, despite local variability in melt percolation and refreeze processes. Our array of upper percolation zone cores reveals that although the overall frequency of melt at these sites has not increased, the intensification of melt over the last three decades is unprecedented within at least the last 365 years. Utilizing the regional climate model RACMO 2.3, we show that this melt intensification is a nonlinear response to warming summer air temperatures, thus underscoring the heightened sensitivity of this sector of Greenland to further climate warming. Finally, we examine spatial correlations between the ice core melt records and modeled melt fields across the ice sheet to assess the broader representation of each ice core record. This analysis reveals wide-ranging significant correlations, including to modeled meltwater runoff. As such, our ice core melt records may furthermore offer unique, observationally-constrained insights into past variability in ice sheet mass loss.

Constraining Future Sea Level Rise Estimates from the Amundsen Sea Embayment, West Antarctica

NASA Astrophysics Data System (ADS)

Nias, I.; Cornford, S. L.; Edwards, T.; Gourmelen, N.; Payne, A. J.

2016-12-01

The Amundsen Sea Embayment (ASE) is the primary source of mass loss from the West Antarctic Ice Sheet. The catchment is particularly susceptible to grounding line retreat, because the ice sheet is grounded on bedrock that is below sea level and deepening towards its interior. Mass loss from the ASE ice streams, which include Pine Island, Thwaites and Smith glaciers, is a major uncertainty on future sea level rise, and understanding the dynamics of these ice streams is essential to constraining this uncertainty. The aim of this study is to construct a distribution of future ASE sea level contributions from an ensemble of ice sheet model simulations and observations of surface elevation change. A 284 member ensemble was performed using BISICLES, a vertically-integrated ice flow model with adaptive mesh refinement. Within the ensemble parameters associated with basal traction, ice rheology and sub-shelf melt rate were perturbed, and the effect of bed topography and sliding law were also investigated. Initially each configuration was run to 50 model years. Satellite observations of surface height change were then used within a Bayesian framework to assign likelihoods to each ensemble member. Simulations that better reproduced the current thinning patterns across the catchment were given a higher score. The resulting posterior distribution of sea level contributions is narrower than the prior distribution, although the central estimates of sea level rise are similar between the prior and posterior. The most extreme simulations were eliminated and the remaining ensemble members were extended to 200 years, using a simple melt rate forcing.

Constraining ice sheet history in the Weddell Sea, West Antarctica, using ice fabric at Korff Ice Rise

NASA Astrophysics Data System (ADS)

Brisbourne, A.; Smith, A.; Kendall, J. M.; Baird, A. F.; Martin, C.; Kingslake, J.

2017-12-01

The grounding history of ice rises (grounded area of independent flow regime within a floating ice shelf) can be used to constrain large scale ice sheet history: ice fabric, resulting from the preferred orientation of ice crystals due to the stress regime, can be used to infer this grounding history. With the aim of measuring the present day ice fabric at Korff Ice Rise, West Antarctica, a multi-azimuth wide-angle seismic experiment was undertaken. Three wide-angle common-midpoint gathers were acquired centred on the apex of the ice rise, at azimuths of 60 degrees to one another, to measure variation in seismic properties with offset and azimuth. Both vertical and horizontal receivers were used to record P and S arrivals including converted phases. Measurements of the variation with offset and azimuth of seismic traveltimes, seismic attenuation and shear wave splitting have been used to quantify seismic anisotropy in the ice column. The observations cannot be reproduced using an isotropic ice column model. Anisotropic ray tracing has been used to test likely models of ice fabric by comparison with the data. A model with a weak girdle fabric overlying a strong cluster fabric provides the best fit to the observations. Fabric of this nature is consistent with Korff Ice Rise having been stable for the order of 10,000 years without any ungrounding or significant change in the ice flow configuration across the ice rise for this period. This observation has significant implications for the ice sheet history of the Weddell Sea sector.

Uniform magnetic fields in density-functional theory

NASA Astrophysics Data System (ADS)

Tellgren, Erik I.; Laestadius, Andre; Helgaker, Trygve; Kvaal, Simen; Teale, Andrew M.

2018-01-01

We construct a density-functional formalism adapted to uniform external magnetic fields that is intermediate between conventional density functional theory and Current-Density Functional Theory (CDFT). In the intermediate theory, which we term linear vector potential-DFT (LDFT), the basic variables are the density, the canonical momentum, and the paramagnetic contribution to the magnetic moment. Both a constrained-search formulation and a convex formulation in terms of Legendre-Fenchel transformations are constructed. Many theoretical issues in CDFT find simplified analogs in LDFT. We prove results concerning N-representability, Hohenberg-Kohn-like mappings, existence of minimizers in the constrained-search expression, and a restricted analog to gauge invariance. The issue of additivity of the energy over non-interacting subsystems, which is qualitatively different in LDFT and CDFT, is also discussed.

Uniform magnetic fields in density-functional theory.

PubMed

Tellgren, Erik I; Laestadius, Andre; Helgaker, Trygve; Kvaal, Simen; Teale, Andrew M

2018-01-14

We construct a density-functional formalism adapted to uniform external magnetic fields that is intermediate between conventional density functional theory and Current-Density Functional Theory (CDFT). In the intermediate theory, which we term linear vector potential-DFT (LDFT), the basic variables are the density, the canonical momentum, and the paramagnetic contribution to the magnetic moment. Both a constrained-search formulation and a convex formulation in terms of Legendre-Fenchel transformations are constructed. Many theoretical issues in CDFT find simplified analogs in LDFT. We prove results concerning N-representability, Hohenberg-Kohn-like mappings, existence of minimizers in the constrained-search expression, and a restricted analog to gauge invariance. The issue of additivity of the energy over non-interacting subsystems, which is qualitatively different in LDFT and CDFT, is also discussed.

Glacial-Geomorphological Evidence for Past Ice Cover in the Western Amundsen Sea Embayment of Antarctica

NASA Astrophysics Data System (ADS)

Roberts, S. J.; Johnson, J.; Ireland, L.; Rood, D. H.; Schaefer, J. M.; Whitehouse, P. L.; Pollard, D.

2016-12-01

Reliable model predictions of the future evolution of the West Antarctic Ice Sheet in the Amundsen Sea Embayment of Antarctica are currently hindered by a lack of data on the regional thinning history, particularly to the west of Thwaites Glacier. Our project will fill this critical gap by acquiring glacial-geological data, in particular, a high density of cosmogenic exposure ages that record ice sheet changes in the western Amundsen Sea Embayment over the past 20,000 years. In 2015/6, during the first of two field seasons in the region, we collected glacial-geomorphological evidence and cosmogenic surface exposure dating samples to constrain past ice cover of nunataks around Mt Murphy, which are adjacent to the Pope Glacier. The presence of abundant rounded granite and gneiss cobbles perched on bedrock ridges and terraces up to 885 m asl, as well as extensive striated bedrock above this height, indicate that ice was much thicker in the past. We also present preliminary results from a novel study on Turtle Rock, a key site for understanding past fluctuations of Pope Glacier. We used an unmanned aerial vehicle (UAV) to map the geomorphology of selected areas in greater detail than is currently possible from high-resolution satellite imagery, and ground-truthed the data by measuring the size, orientation and lithological composition of erratic cobbles and boulders. Combined with surface exposure dating, we will use these datasets to determine whether there were multiple phases of ice overriding, and the timing of thinning of Pope Glacier since the Last Glacial Maximum.

The Antarctic Ice Sheet during the last Interglaciation: Insights from my Thesis

NASA Astrophysics Data System (ADS)

Whipple, Matthew; Lunt, Dan; Singarayer, Joy; Bradley, Sarah; Milne, Glenn; Wolff, Eric; Siddall, Mark

2015-04-01

The last interglaciation represents a period of warmer climates and higher sea levels, and a useful analogue to future climate. While many studies have focussed on the response of the Greenland Ice sheet, far less is known about the response of the Antarctic ice sheet. Here, I present the summarised results of my PhD thesis "Constraints on the minimum extent of the Antarctic ice sheet during the last interglaciation". Firstly, I cover the timings of interglaciation in Antarctica, and their differences with respect to the Northern Hemisphere timings, based on paleo sea level indicators, and oceanic temperature records. I move on to cover climate forcings, and how they influence the ice sheet, relative to present, and early Holocene. Secondly, I present thesis results, from looking at ice core stable water isotopes. These are compared with Isostatic and Climatic modelling results, for various different Ice sheet scenarios, as to the resulting Climate, from changes in Elevation, Temperature, Precipitation, and Sublimation, all contributing to the recorded stable water isotope record. Thirdly, I move on to looking at the mid-field relative sea level records, from Australia and Argentina. Using isostatic modelling, these are used to assess the relative contribution of the Eastern and Western Antarctic Ice sheets. Although data uncertainties result in us being to identify the contribution from West Antarctica. Overall, using model-data comparison, we find a lack of evidence for a substantial retreat of the Wilkes Subglacial basin. No data location is close enough to determine the existence of the marine based West Antarctic Ice sheet. Model uncertainty is unable to constrain evidence of variations in ice thickness in East Antarctica.

Surface-atmosphere decoupling limits accumulation at Summit, Greenland.

PubMed

Berkelhammer, Max; Noone, David C; Steen-Larsen, Hans Christian; Bailey, Adriana; Cox, Christopher J; O'Neill, Michael S; Schneider, David; Steffen, Konrad; White, James W C

2016-04-01

Despite rapid melting in the coastal regions of the Greenland Ice Sheet, a significant area (~40%) of the ice sheet rarely experiences surface melting. In these regions, the controls on annual accumulation are poorly constrained owing to surface conditions (for example, surface clouds, blowing snow, and surface inversions), which render moisture flux estimates from myriad approaches (that is, eddy covariance, remote sensing, and direct observations) highly uncertain. Accumulation is partially determined by the temperature dependence of saturation vapor pressure, which influences the maximum humidity of air parcels reaching the ice sheet interior. However, independent proxies for surface temperature and accumulation from ice cores show that the response of accumulation to temperature is variable and not generally consistent with a purely thermodynamic control. Using three years of stable water vapor isotope profiles from a high altitude site on the Greenland Ice Sheet, we show that as the boundary layer becomes increasingly stable, a decoupling between the ice sheet and atmosphere occurs. The limited interaction between the ice sheet surface and free tropospheric air reduces the capacity for surface condensation to achieve the rate set by the humidity of the air parcels reaching interior Greenland. The isolation of the surface also acts to recycle sublimated moisture by recondensing it onto fog particles, which returns the moisture back to the surface through gravitational settling. The observations highlight a unique mechanism by which ice sheet mass is conserved, which has implications for understanding both past and future changes in accumulation rate and the isotopic signal in ice cores from Greenland.

Surface-atmosphere decoupling limits accumulation at Summit, Greenland

PubMed Central

Berkelhammer, Max; Noone, David C.; Steen-Larsen, Hans Christian; Bailey, Adriana; Cox, Christopher J.; O’Neill, Michael S.; Schneider, David; Steffen, Konrad; White, James W. C.

2016-01-01

Despite rapid melting in the coastal regions of the Greenland Ice Sheet, a significant area (~40%) of the ice sheet rarely experiences surface melting. In these regions, the controls on annual accumulation are poorly constrained owing to surface conditions (for example, surface clouds, blowing snow, and surface inversions), which render moisture flux estimates from myriad approaches (that is, eddy covariance, remote sensing, and direct observations) highly uncertain. Accumulation is partially determined by the temperature dependence of saturation vapor pressure, which influences the maximum humidity of air parcels reaching the ice sheet interior. However, independent proxies for surface temperature and accumulation from ice cores show that the response of accumulation to temperature is variable and not generally consistent with a purely thermodynamic control. Using three years of stable water vapor isotope profiles from a high altitude site on the Greenland Ice Sheet, we show that as the boundary layer becomes increasingly stable, a decoupling between the ice sheet and atmosphere occurs. The limited interaction between the ice sheet surface and free tropospheric air reduces the capacity for surface condensation to achieve the rate set by the humidity of the air parcels reaching interior Greenland. The isolation of the surface also acts to recycle sublimated moisture by recondensing it onto fog particles, which returns the moisture back to the surface through gravitational settling. The observations highlight a unique mechanism by which ice sheet mass is conserved, which has implications for understanding both past and future changes in accumulation rate and the isotopic signal in ice cores from Greenland. PMID:27386509

Infused polymers for cell sheet release

NASA Astrophysics Data System (ADS)

Juthani, Nidhi; Howell, Caitlin; Ledoux, Haylea; Sotiri, Irini; Kelso, Susan; Kovalenko, Yevgen; Tajik, Amanda; Vu, Thy L.; Lin, Jennifer J.; Sutton, Amy; Aizenberg, Joanna

2016-05-01

Tissue engineering using whole, intact cell sheets has shown promise in many cell-based therapies. However, current systems for the growth and release of these sheets can be expensive to purchase or difficult to fabricate, hindering their widespread use. Here, we describe a new approach to cell sheet release surfaces based on silicone oil-infused polydimethylsiloxane. By coating the surfaces with a layer of fibronectin (FN), we were able to grow mesenchymal stem cells to densities comparable to those of tissue culture polystyrene controls (TCPS). Simple introduction of oil underneath an edge of the sheet caused it to separate from the substrate. Characterization of sheets post-transfer showed that they retain their FN layer and morphology, remain highly viable, and are able to grow and proliferate normally after transfer. We expect that this method of cell sheet growth and detachment may be useful for low-cost, flexible, and customizable production of cellular layers for tissue engineering.

Infused polymers for cell sheet release

PubMed Central

Juthani, Nidhi; Howell, Caitlin; Ledoux, Haylea; Sotiri, Irini; Kelso, Susan; Kovalenko, Yevgen; Tajik, Amanda; Vu, Thy L.; Lin, Jennifer J.; Sutton, Amy; Aizenberg, Joanna

2016-01-01

Tissue engineering using whole, intact cell sheets has shown promise in many cell-based therapies. However, current systems for the growth and release of these sheets can be expensive to purchase or difficult to fabricate, hindering their widespread use. Here, we describe a new approach to cell sheet release surfaces based on silicone oil-infused polydimethylsiloxane. By coating the surfaces with a layer of fibronectin (FN), we were able to grow mesenchymal stem cells to densities comparable to those of tissue culture polystyrene controls (TCPS). Simple introduction of oil underneath an edge of the sheet caused it to separate from the substrate. Characterization of sheets post-transfer showed that they retain their FN layer and morphology, remain highly viable, and are able to grow and proliferate normally after transfer. We expect that this method of cell sheet growth and detachment may be useful for low-cost, flexible, and customizable production of cellular layers for tissue engineering. PMID:27189419

Infused polymers for cell sheet release.

PubMed

Juthani, Nidhi; Howell, Caitlin; Ledoux, Haylea; Sotiri, Irini; Kelso, Susan; Kovalenko, Yevgen; Tajik, Amanda; Vu, Thy L; Lin, Jennifer J; Sutton, Amy; Aizenberg, Joanna

2016-05-18

Tissue engineering using whole, intact cell sheets has shown promise in many cell-based therapies. However, current systems for the growth and release of these sheets can be expensive to purchase or difficult to fabricate, hindering their widespread use. Here, we describe a new approach to cell sheet release surfaces based on silicone oil-infused polydimethylsiloxane. By coating the surfaces with a layer of fibronectin (FN), we were able to grow mesenchymal stem cells to densities comparable to those of tissue culture polystyrene controls (TCPS). Simple introduction of oil underneath an edge of the sheet caused it to separate from the substrate. Characterization of sheets post-transfer showed that they retain their FN layer and morphology, remain highly viable, and are able to grow and proliferate normally after transfer. We expect that this method of cell sheet growth and detachment may be useful for low-cost, flexible, and customizable production of cellular layers for tissue engineering.

Synergistic Effect between Ultra-Small Nickel Hydroxide Nanoparticles and Reduced Graphene Oxide sheets for the Application in High-Performance Asymmetric Supercapacitor.

PubMed

Liu, Yonghuan; Wang, Rutao; Yan, Xingbin

2015-06-08

Nanoscale electrode materials including metal oxide nanoparticles and two-dimensional graphene have been employed for designing supercapacitors. However, inevitable agglomeration of nanoparticles and layers stacking of graphene largely hamper their practical applications. Here we demonstrate an efficient co-ordination and synergistic effect between ultra-small Ni(OH)2 nanoparticles and reduced graphene oxide (RGO) sheets for synthesizing ideal electrode materials. On one hand, to make the ultra-small Ni(OH)2 nanoparticles work at full capacity as an ideal pseudocapacitive material, RGO sheets are employed as an suitable substrate to anchor these nanoparticles against agglomeration. As a consequence, an ultrahigh specific capacitance of 1717 F g(-1) at 0.5 A g(-1) is achieved. On the other hand, to further facilitate ion transfer within RGO sheets as an ideal electrical double layer capacitor material, the ultra-small Ni(OH)2 nanoparticles are introduced among RGO sheets as the recyclable sacrificial spacer to prevent the stacking. The resulting RGO sheets exhibit superior rate capability with a high capacitance of 182 F g(-1) at 100 A g(-1). On this basis, an asymmetric supercapacitor is assembled using the two materials, delivering a superior energy density of 75 Wh kg(-1) and an ultrahigh power density of 40 000 W kg(-1).

Synergistic Effect between Ultra-Small Nickel Hydroxide Nanoparticles and Reduced Graphene Oxide sheets for the Application in High-Performance Asymmetric Supercapacitor

PubMed Central

Liu, Yonghuan; Wang, Rutao; Yan, Xingbin

2015-01-01

Nanoscale electrode materials including metal oxide nanoparticles and two-dimensional graphene have been employed for designing supercapacitors. However, inevitable agglomeration of nanoparticles and layers stacking of graphene largely hamper their practical applications. Here we demonstrate an efficient co-ordination and synergistic effect between ultra-small Ni(OH)2 nanoparticles and reduced graphene oxide (RGO) sheets for synthesizing ideal electrode materials. On one hand, to make the ultra-small Ni(OH)2 nanoparticles work at full capacity as an ideal pseudocapacitive material, RGO sheets are employed as an suitable substrate to anchor these nanoparticles against agglomeration. As a consequence, an ultrahigh specific capacitance of 1717 F g−1 at 0.5 A g−1 is achieved. On the other hand, to further facilitate ion transfer within RGO sheets as an ideal electrical double layer capacitor material, the ultra-small Ni(OH)2 nanoparticles are introduced among RGO sheets as the recyclable sacrificial spacer to prevent the stacking. The resulting RGO sheets exhibit superior rate capability with a high capacitance of 182 F g−1 at 100 A g−1. On this basis, an asymmetric supercapacitor is assembled using the two materials, delivering a superior energy density of 75 Wh kg−1 and an ultrahigh power density of 40 000 W kg−1. PMID:26053847

The mechanistic exploration of porous activated graphene sheets-anchored SnO2 nanocrystals for application in high-performance Li-ion battery anodes.

PubMed

Yang, Yingchang; Ji, Xiaobo; Lu, Fang; Chen, Qiyuan; Banks, Craig E

2013-09-28

Porous activated graphene sheets have been for the first time exploited herein as encapsulating substrates for lithium ion battery (LIB) anodes. The as-fabricated SnO2 nanocrystals-porous activated graphene sheet (AGS) composite electrode exhibits improved electrochemical performance as an anode material for LIBs, such as better cycle performance and higher rate capability in comparison with graphene sheets, activated graphene sheets, bare SnO2 and SnO2-graphene sheet composites. The superior electrochemical performances of the designed anode can be ascribed to the porous AGS substrate, which improves the electrical conductivity of the electrode, inhibits agglomeration between particles and effectively buffers the strain from the volume variation during Li(+)-intercalation-de-intercalation and provides more cross-plane diffusion channels for Li(+) ions. As a result, the designed anode exhibits an outstanding capacity of up to 610 mA h g(-1) at a current density of 100 mA g(-1) after 50 cycles and a good rate performance of 889, 747, 607, 482 and 372 mA h g(-1) at a current density of 100, 200, 500, 1000, and 2000 mA g(-1), respectively. This work is of importance for energy storage as it provides a new substrate for the design and implementation of next-generation LIBs exhibiting exceptional electrochemical performances.

The Influence of 5000 year-old and Younger Glacial Mass Variability on Present-day Crustal Rebound in the Antarctic Peninsula

NASA Technical Reports Server (NTRS)

Ivins, E.; Raymond, C.; James, T.

1999-01-01

Much of the late-Quaternary ice sheet history in the northern hemisphere is now relatively well-constrained, with the total contributions to eustatic sea level change from North America and Eurasia estimated at roughly 60 (+-12) and 20 (+-7) m, respectively, and with deglaciation bracketed at 22 to 8.5 kyr BP.

Multi-channel Ice Penetrating Radar Traverse for Estimates of Firn Density in the Percolation Zone, Western Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Meehan, T.; Osterberg, E. C.; Lewis, G.; Overly, T. B.; Hawley, R. L.; Bradford, J.; Marshall, H. P.

2016-12-01

To better predict the response of the Greenland Ice Sheet (GrIS) to future warming, leading edge Regional Climate Models (RCM) must be calibrated with in situ measurements of recent accumulation and melt. Mass balance estimates averaged across the entire Greenland Ice Sheet (GrIS) vary between models by more than 30 percent, and regional comparisons of mass balance reconstructions in Greenland vary by 100 percent or more. Greenland Traverse for Accumulation and Climate Studies (GreenTrACS) is a multi-year and multi-disciplinary 1700 km science traverse from Raven/Dye2 in SW Greenland, to Summit Station. Multi-offset radar measurements can provide high accuracy electromagnetic (EM) velocity estimates of the firn to within (+-) 0.002 to 0.003 m/ns. EM velocity, in turn, can be used to estimate bulk firn density. Using a mixing equation such as the CRIM Equation we use the measured EM velocity, along with the known EM velocity in air and ice, to estimate bulk density. During spring 2016, we used multi-channel 500MHz radar in a multi-offset configuration to survey more than 800 km from Raven towards summit. Preliminary radar-derived snow density estimates agree with density estimates from a firn core measurement ( 50 kg/m3), despite the lateral heterogeneity of the firn across the length of the antenna array (12 m).

Frozen-bed Fennoscandian and Laurentide ice sheets during the Last Glacial Maximum

NASA Astrophysics Data System (ADS)

Kleman, Johan; Hättestrand, Clas

1999-11-01

The areal extents of the Laurentide and Fennoscandian ice sheets during the Last Glacial Maximum (about 20,000 years ago) are well known, but thickness estimates range widely, from high-domed to thin, with large implications for our reconstruction of the climate system regarding, for example, Northern Hemisphere atmospheric circulation and global sea levels. This uncertainty stems from difficulties in determining the basal temperatures of the ice sheets and the shear strength of subglacial materials, a knowledge of which would better constrain reconstructions of ice-sheet thickness. Here we show that, in the absence of direct data, the occurrence of ribbed moraines in modern landscapes can be used to determine the former spatial distribution of frozen- and thawed-bed conditions. We argue that ribbed moraines were formed by brittle fracture of subglacial sediments, induced by the excessive stress at the boundary between frozen- and thawed-bed conditions resulting from the across-boundary difference in basal ice velocity. Maps of glacial landforms from aerial photographs of Canada and Scandinavia reveal a concentration of ribbed moraines around the ice-sheet retreat centres of Quebec, Keewatin, Newfoundland and west-central Fennoscandia. Together with the evidence from relict landscapes that mark glacial areas with frozen-bed conditions, the distribution of ribbed moraines on both continents suggest that a large area of the Laurentide and Fennoscandian ice sheets was frozen-based-and therefore high-domed and stable-during the Last Glacial Maximum.

Hypsometric Amplification of Greenland Ice Sheet Meltwater Release

NASA Astrophysics Data System (ADS)

van As, D.; Hasholt, B.; Mikkelsen, A. B.; Holtegaard Nielsen, M.; Box, J.; Claesson Liljedahl, L.; Lindback, K.; Pitcher, L. H.

2017-12-01

Proglacial discharge monitoring provides valuable insights in Greenland ice sheet meltwater release. We use a 2006-2016 discharge time series from the Watson River draining 12000 km2 of the ice sheet in southwest Greenland to investigate the large variability in catchment-total meltwater production. An observationally-constrained reconstruction of past discharge shows that meltwater release has on average increased by a factor of 1.5 since 2003 compared to the 1949-2002 period, and that interannual variability has disproportionally increased by a factor of 2.1, suggesting that melt amplifiers are at play. We derive a hypsometric amplification factor of 1.6, which is the result of the exponential melt area increase with rising temperature. Peak meltwater discharge events such as during the July 2012 flooding are due to this and other melt amplifiers, but also require intense melting over a period exceeding the multi-day transit time for high-elevation meltwater to pass through the glacial drainage system.

Response of Honeycomb Core Sandwich Panel with Minimum Gage GFRP Face-Sheets to Compression Loading After Impact

NASA Technical Reports Server (NTRS)

McQuigg, Thomas D.; Kapania, Rakesh K.; Scotti, Stephen J.; Walker, Sandra P.

2011-01-01

A compression after impact study has been conducted to determine the residual strength of three sandwich panel constructions with two types of thin glass fiber reinforced polymer face-sheets and two hexagonal honeycomb Nomex core densities. Impact testing is conducted to first determine the characteristics of damage resulting from various impact energy levels. Two modes of failure are found during compression after impact tests with the density of the core precipitating the failure mode present for a given specimen. A finite element analysis is presented for prediction of the residual compressive strength of the impacted specimens. The analysis includes progressive damage modeling in the face-sheets. Preliminary analysis results were similar to the experimental results; however, a higher fidelity core material model is expected to improve the correlation.

Experimental realization of two-dimensional boron sheets

NASA Astrophysics Data System (ADS)

Feng, Baojie; Zhang, Jin; Zhong, Qing; Li, Wenbin; Li, Shuai; Li, Hui; Cheng, Peng; Meng, Sheng; Chen, Lan; Wu, Kehui

2016-06-01

A variety of two-dimensional materials have been reported in recent years, yet single-element systems such as graphene and black phosphorus have remained rare. Boron analogues have been predicted, as boron atoms possess a short covalent radius and the flexibility to adopt sp2 hybridization, features that favour the formation of two-dimensional allotropes, and one example of such a borophene material has been reported recently. Here, we present a parallel experimental work showing that two-dimensional boron sheets can be grown epitaxially on a Ag(111) substrate. Two types of boron sheet, a β12 sheet and a χ3 sheet, both exhibiting a triangular lattice but with different arrangements of periodic holes, are observed by scanning tunnelling microscopy. Density functional theory simulations agree well with experiments, and indicate that both sheets are planar without obvious vertical undulations. The boron sheets are quite inert to oxidization and interact only weakly with their substrate. We envisage that such boron sheets may find applications in electronic devices in the future.

ISEE-1 and 2 observations of field-aligned currents in the distant midnight magnetosphere

NASA Technical Reports Server (NTRS)

Elphic, R. C.; Kelly, T. J.; Russell, C. T.

1985-01-01

Magnetic field measurements obtained in the nightside magnetosphere by the co-orbiting ISEE-1 and 2 spacecraft have been examined for signatures of field-aligned currents (FAC). Such currents are found on the boundary of the plasma sheet both when the plasma sheet is expanding and when it is thinning. Evidence is often found for the existence of waves on the plasma sheet boundary, leading to multiple crossings of the FAC sheet. At times the boundary layer FAC sheet orientation is nearly parallel to the X-Z GSM plane, suggesting 'protrusions' of plasma sheet into the lobes. The boundary layer current polarity is, as expected, into the ionosphere in the midnight to dawn local time sector, and outward near dusk. Current sheet thicknesses and velocities are essentially independent of plasma sheet expansion or thinning, having typical values of 1500 km and 20-40 km/s respectively. Characteristic boundary layer current densities are about 10 nanoamps per square meter.

North Atlantic Oscillation Drives Regional Greenland Glacier Volume During the 20th Century

NASA Astrophysics Data System (ADS)

Bjork, A. A.; Aagaard, S.; Hallander, A. M.; Khan, S. A.; Box, J. E.; Kjeldsen, K. K.; Larsen, N. K.; Korsgaard, N. J.; Cappelen, J.; Colgan, W. T.; Machguth, H.; Andresen, C. S.; Kjaer, K. H.

2016-12-01

While most areas of the Greenland ice sheet have undergone rapid mass loss since c. 1990, the central eastern section of the ice sheet has advanced and gained mass. This contrasting regional trend has been attributed to positive surface mass balance (SMB) in the absence of significant dynamic mass loss. To constrain the atypical behavior in this region, we mapped glacier length fluctuations of nearly 200 peripheral glaciers and ice caps (PGICs) over a 103-year period, and compare the results with c. 150 new glacier length records from central west Greenland. We demonstrate that the regional response in ice volume is closely correlated to changes in precipitation, governed by circulation patterns associated with the North Atlantic Oscillation (NAO) and secondarily influenced by temperature forcing in certain periods. More broadly, we find that the NAO contributes to contrasting precipitation variability in East and West Greenland, where it appears to be responsible for at least 10% and more than 25%, respectively, of the variability in ice sheet accumulation rate. This east-west asymmetry, which influences both LGICs and the ice sheet, illustrates how substantial uncertainty in NAO projections directly contributes to uncertainty in mass balance projections.

Eastern Ross Ice Sheet Deglacial History inferred from the Roosevelt Island Ice Core

NASA Astrophysics Data System (ADS)

Fudge, T. J.; Buizert, C.; Lee, J.; Waddington, E. D.; Bertler, N. A. N.; Conway, H.; Brook, E.; Severinghaus, J. P.

2017-12-01

The Ross Ice Sheet drains large portions of both West and East Antarctica. Understanding the retreat of the Ross Ice Sheet following the Last Glacial Maximum is particularly difficult in the eastern Ross area where there is no exposed rock and the Ross Ice Shelf prevents extensive bathymetric mapping. Coastal domes, by preserving old ice, can be used to infer the establishment of grounded ice and be used to infer past ice thickness. Here we focus on Roosevelt Island, in the eastern Ross Sea, where the Roosevelt Island Climate Evolution project recently completed an ice core to bedrock. Using ice-flow modeling constrained by the depth-age relationship and an independent estimate of accumulation rate from firn-densification measurements and modeling, we infer ice thickness histories for the LGM (20ka) to present. Preliminary results indicate thinning of 300m between 15ka and 12ka is required. This is similar to the amount and timing of thinning inferred at Siple Dome, in the central Ross Sea (Waddington et al., 2005; Price et al., 2007) and supports the presence of active ice streams throughout the Ross Ice Sheet advance during the LGM.

The Self-Association of Graphane Is Driven by London Dispersion and Enhanced Orbital Interactions.

PubMed

Wang, Changwei; Mo, Yirong; Wagner, J Philipp; Schreiner, Peter R; Jemmis, Eluvathingal D; Danovich, David; Shaik, Sason

2015-04-14

We investigated the nature of the cohesive energy between graphane sheets via multiple CH···HC interactions, using density functional theory (DFT) including dispersion correction (Grimme's D3 approach) computations of [n]graphane σ dimers (n = 6-73). For comparison, we also evaluated the binding between graphene sheets that display prototypical π/π interactions. The results were analyzed using the block-localized wave function (BLW) method, which is a variant of ab initio valence bond (VB) theory. BLW interprets the intermolecular interactions in terms of frozen interaction energy (ΔE(F)) composed of electrostatic and Pauli repulsion interactions, polarization (ΔE(pol)), charge-transfer interaction (ΔE(CT)), and dispersion effects (ΔE(disp)). The BLW analysis reveals that the cohesive energy between graphane sheets is dominated by two stabilizing effects, namely intermolecular London dispersion and two-way charge transfer energy due to the σ(CH) → σ*(HC) interactions. The shift of the electron density around the nonpolar covalent C-H bonds involved in the intermolecular interaction decreases the C-H bond lengths uniformly by 0.001 Å. The ΔE(CT) term, which accounts for ∼15% of the total binding energy, results in the accumulation of electron density in the interface area between two layers. This accumulated electron density thus acts as an electronic "glue" for the graphane layers and constitutes an important driving force in the self-association and stability of graphane under ambient conditions. Similarly, the "double faced adhesive tape" style of charge transfer interactions was also observed among graphene sheets in which it accounts for ∼18% of the total binding energy. The binding energy between graphane sheets is additive and can be expressed as a sum of CH···HC interactions, or as a function of the number of C-H bonds.

The folding of acetyl(Ala)28NH2 and acetyl(Ala)40NH2 extended strand peptides into antiparallel β-sheets. A density functional theory study of β-sheets with β-turns.

PubMed

Ali-Torres, Jorge; Dannenberg, J J

2012-12-06

We report ONIOM calculations using B3LYP/D95** and AM1 on β-sheet formation from acetyl(Ala)(N)NH(2) (N = 28 or 40). The sheets contain from one to four β-turns for N = 28 and up to six for N = 40. We have obtained four types of geometrically optimized structures. All contain only β-turns. They differ from each other in the types of β-turns formed. The unsolvated sheets containing two turns are most stable. Aqueous solvation (using the SM5.2 and CPCM methods) reduces the stabilities of the folded structures compared to the extended strands.

Charge Density Wave and Narrow Energy Gap at Room Temperature in 2D Pb 3–xSb 1+xS 4Te 2-δ with Square Te Sheets

DOE PAGES

Chen, Haijie; Malliakas, Christos D.; Narayan, Awadhesh; ...

2017-07-17

We report a new two-dimensional compound Pb 3–xSb 1+xS 4Te 2-δ has a charge density wave (CDW) at room temperature. The CDW is incommensurate with q-vector of 0.248(6)a* + 0.246(8)b* + 0.387(9)c* for x = 0.29(2) and d = 0.37(3) due to positional and occupational long range ordering of Te atoms in the sheets. The modulated structure was refined from the single crystal X-ray diffraction data with a superspace group Pmore » $$\\bar{1}$$(αβγ)0 using (3 + 1)-dimensional crystallography. The resistivity increases with decreasing temperature, suggesting semiconducting behavior. The transition temperature (T CDW) of the CDW is ~ 345 K above which the Te square sheets become disordered with no q-vector. Lastly, first-principles density functional theory calculations on the undistorted structure and an approximate commensurate supercell reveal that the gap is due to the structure modulation.« less

Charge Density Wave and Narrow Energy Gap at Room Temperature in 2D Pb 3–xSb 1+xS 4Te 2-δ with Square Te Sheets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Haijie; Malliakas, Christos D.; Narayan, Awadhesh

We report a new two-dimensional compound Pb 3–xSb 1+xS 4Te 2-δ has a charge density wave (CDW) at room temperature. The CDW is incommensurate with q-vector of 0.248(6)a* + 0.246(8)b* + 0.387(9)c* for x = 0.29(2) and d = 0.37(3) due to positional and occupational long range ordering of Te atoms in the sheets. The modulated structure was refined from the single crystal X-ray diffraction data with a superspace group Pmore » $$\\bar{1}$$(αβγ)0 using (3 + 1)-dimensional crystallography. The resistivity increases with decreasing temperature, suggesting semiconducting behavior. The transition temperature (T CDW) of the CDW is ~ 345 K above which the Te square sheets become disordered with no q-vector. Lastly, first-principles density functional theory calculations on the undistorted structure and an approximate commensurate supercell reveal that the gap is due to the structure modulation.« less

Ultrashort electromagnetic pulse control of intersubband quantum well transitions

PubMed Central

2012-01-01

We study the creation of high-efficiency controlled population transfer in intersubband transitions of semiconductor quantum wells. We give emphasis to the case of interaction of the semiconductor quantum well with electromagnetic pulses with a duration of few cycles and even a single cycle. We numerically solve the effective nonlinear Bloch equations for a specific double GaAs/AlGaAs quantum well structure, taking into account the ultrashort nature of the applied field, and show that high-efficiency population inversion is possible for specific pulse areas. The dependence of the efficiency of population transfer on the electron sheet density and the carrier envelope phase of the pulse is also explored. For electromagnetic pulses with a duration of several cycles, we find that the change in the electron sheet density leads to a very different response of the population in the two subbands to pulse area. However, for pulses with a duration equal to or shorter than 3 cycles, we show that efficient population transfer between the two subbands is possible, independent of the value of electron sheet density, if the pulse area is Π. PMID:22916956

Ultrashort electromagnetic pulse control of intersubband quantum well transitions.

PubMed

Paspalakis, Emmanuel; Boviatsis, John

2012-08-23

: We study the creation of high-efficiency controlled population transfer in intersubband transitions of semiconductor quantum wells. We give emphasis to the case of interaction of the semiconductor quantum well with electromagnetic pulses with a duration of few cycles and even a single cycle. We numerically solve the effective nonlinear Bloch equations for a specific double GaAs/AlGaAs quantum well structure, taking into account the ultrashort nature of the applied field, and show that high-efficiency population inversion is possible for specific pulse areas. The dependence of the efficiency of population transfer on the electron sheet density and the carrier envelope phase of the pulse is also explored. For electromagnetic pulses with a duration of several cycles, we find that the change in the electron sheet density leads to a very different response of the population in the two subbands to pulse area. However, for pulses with a duration equal to or shorter than 3 cycles, we show that efficient population transfer between the two subbands is possible, independent of the value of electron sheet density, if the pulse area is Π.

Charge Density Wave and Narrow Energy Gap at Room Temperature in 2D Pb3-xSb1+xS4Te2-δ with Square Te Sheets.

PubMed

Chen, Haijie; Malliakas, Christos D; Narayan, Awadhesh; Fang, Lei; Chung, Duck Young; Wagner, Lucas K; Kwok, Wai-Kwong; Kanatzidis, Mercouri G

2017-08-16

We report a new two-dimensional compound, Pb 3-x Sb 1+x S 4 Te 2-δ , that has a charge density wave (CDW) at room temperature. The CDW is incommensurate with q-vector of 0.248(6)a* + 0.246(8)b* + 0.387(9)c* for x = 0.29(2) and δ = 0.37(3) due to positional and occupational long-range ordering of Te atoms in the sheets. The modulated structure was refined from the single-crystal X-ray diffraction data with a superspace group P1̅(αβγ)0 using (3 + 1)-dimensional crystallography. The resistivity increases with decreasing temperature, suggesting semiconducting behavior. The transition temperature (T CDW ) of the CDW is ∼345 K, above which the Te square sheets become disordered with no q-vector. First-principles density functional theory calculations on the undistorted structure and an approximate commensurate supercell reveal that the gap is due to the structure modulation.

The divergence characteristics of constrained-sheath optics systems for use with 5-eV atomic oxygen sources

NASA Technical Reports Server (NTRS)

Anderson, John R.; Wilbur, Paul J.

1989-01-01

The potential usefulness of the constrained sheath optics concept as a means of controlling the divergence of low energy, high current density ion beams is examined numerically and experimentally. Numerical results demonstrate that some control of the divergence of typical ion beamlets can be achieved at perveance levels of interest by contouring the surface of the constrained sheath properly. Experimental results demonstrate that a sheath can be constrained by a wire mesh attached to the screen plate of the ion optics system. The numerically predicted beamlet divergence characteristics are shown to depart from those measured experimentally, and additional numerical analysis is used to demonstrate that this departure is probably due to distortions of the sheath caused by the fact that it attempts to conform to the individual wires that make up the sheath constraining mesh. The concept is considered potentially useful in controlling the divergence of ion beamlets in applications where low divergence, low energy, high current density beamlets are being sought, but more work is required to demonstrate this for net beam ion energies as low as 5 eV.

Analysis of polarization in hydrogen bonded complexes: An asymptotic projection approach

NASA Astrophysics Data System (ADS)

Drici, Nedjoua

2018-03-01

The asymptotic projection technique is used to investigate the polarization effect that arises from the interaction between the relaxed, and frozen monomeric charge densities of a set of neutral and charged hydrogen bonded complexes. The AP technique based on the resolution of the original Kohn-Sham equations can give an acceptable qualitative description of the polarization effect in neutral complexes. The significant overlap of the electron densities, in charged and π-conjugated complexes, impose further development of a new functional, describing the coupling between constrained and non-constrained electron densities within the AP technique to provide an accurate representation of the polarization effect.

An internally consistent inverse model to calculate ridge-axis hydrothermal fluxes

NASA Astrophysics Data System (ADS)

Coogan, L. A.; Dosso, S.

2010-12-01

Fluid and chemical fluxes from high-temperature, on-axis, hydrothermal systems at mid-ocean ridges have been estimated in a number of ways. These generally use simple mass balances based on either vent fluid compositions or the compositions of altered sheeted dikes. Here we combine these approaches in an internally consistent model. Seawater is assumed to enter the crust and react with the sheeted dike complex at high temperatures. Major element fluxes for both the rock and fluid are calculated from balanced stoichiometric reactions. These reactions include end-member components of the minerals plagioclase, pyroxene, amphibole, chlorite and epidote along with pure anhydrite, quartz, pyrite, pyrrhotite, titanite, magnetite, ilmenite and ulvospinel and the fluid species H2O, Mg2+, Ca2+, Fe2+, Na+, Si4+, H2S, H+ and H2. Trace element abundances (Li, B, K, Rb, Cs, Sr, Ba, U, Tl, Mn, Cu, Zn, Co, Ni, Pb and Os) and isotopic ratios (Li, B, O, Sr, Tl, Os) are calculated from simple mass balance of a fluid-rock reaction. A fraction of the Cu, Zn, Pb, Co, Ni, Os and Mn in the fluid after fluid-rock reaction is allowed to precipitate during discharge before the fluid reaches the seafloor. S-isotopes are tied to mineralogical reactions involving S-bearing phases. The free parameters in the model are the amounts of each mineralogical reaction that occurs, the amounts of the metals precipitated during discharge, and the water-to-rock ratio. These model parameters, and their uncertainties, are constrained by: (i) mineral abundances and mineral major element compositions in altered dikes from ODP Hole 504B and the Pito and Hess Deep tectonic windows (EPR crust); (ii) changes in dike bulk-rock trace element and isotopic compositions from these locations relative to fresh MORB glass compositions; and (iii) published vent fluid compositions from basalt-hosted high-temperature ridge axis hydrothermal systems. Using a numerical inversion algorithm, the probability density of different model parameter sets has been computed and thus the probability of different fluid and chemical fluxes. Most data can be fit by the model within their uncertainty. The entire dataset is best-fit with a water-to-rock mass ratio between 1.3 and 2.1 (~1 to 1.5 x10**13 kg yr-1) implying a substantial fraction of the magmatic (latent) heat available to drive the axial hydrothermal system is extracted by these systems. Many element fluxes are better constrained than in previous studies (e.g., Sr: 2 to 7 x10**8 moles yr-1; Ca: 2 to 7 x10**11 moles yr-1). Future developments will use experimental data to further constrain the model.

Freestanding two-dimensional Ni(OH)2 thin sheets assembled by 3D nanoflake array as basic building units for supercapacitor electrode materials.

PubMed

Song, Dianmei; Zhu, Jikui; Xuan, Liying; Zhao, Chenglan; Xie, Li; Chen, Lingyun

2018-01-01

Freestanding two dimensional (2D) porous nanostructures have great potential in electrical energy storage. In the present work, we reported the first synthesis of two-dimensional (2D) β-Ni(OH) 2 thin sheets (CQU-Chen-Ni-O-H-1) assembled by 3D nanoflake array as basic building units under acid condition by direct hydrothermal decomposition of the mixed solution of nickel nitrate (Ni(NO 3 ) 2 ) and acetic acid (CH 3 COOH, AA). The unique 3D nanoflake array assembled mesoporous 2D structures endow the thin sheets with a high specific capacitance of 1.78Fcm -2 (1747.5Fg -1 ) at the current density of 1.02mAcm -2 and good rate capability of 67.4% retain from 1.02 to 10.2mAcm -2 . The corresponding assembled asymmetric supercapacitor (ASC) achieves (CQU-Chen-Ni-O-H-1//active carbon (AC)) a high voltage of 1.8V and an energy density of 23.45Whkg -1 with a maximum power density of 9kWkg -1 , as well as cycability with 93.6% capacitance retention after 10,000 cycles. These results show the mesoporous thin sheets have great potential for SCs and other energy storage devices. Copyright © 2017 Elsevier Inc. All rights reserved.

Practical Application of Sheet Lead for Sound Barriers.

ERIC Educational Resources Information Center

Lead Industries Association, New York, NY.

Techniques for improving sound barriers through the use of lead sheeting are described. To achieve an ideal sound barrier a material should consist of the following properties--(1) high density, (2) freedom from stiffness, (3) good damping capacity, and (4) integrity as a non-permeable membrane. Lead combines these desired properties to a greater…

Enhanced sheet carrier densities in polarization controlled AlInN/AlN/GaN/InGaN field-effect transistor on Si (111)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hennig, J., E-mail: jonas.hennig@ovgu.de; Dadgar, A.; Witte, H.

2015-07-15

We report on GaN based field-effect transistor (FET) structures exhibiting sheet carrier densities of n = 2.9 10{sup 13} cm{sup −2} for high-power transistor applications. By grading the indium-content of InGaN layers grown prior to a conventional GaN/AlN/AlInN FET structure control of the channel width at the GaN/AlN interface is obtained. The composition of the InGaN layer was graded from nominally x{sub In} = 30 % to pure GaN just below the AlN/AlInN interface. Simulations reveal the impact of the additional InGaN layer on the potential well width which controls the sheet carrier density within the channel region of the devices.more » Benchmarking the In{sub x}Ga{sub 1−x}N/GaN/AlN/Al{sub 0.87}In{sub 0.13}N based FETs against GaN/AlN/AlInN FET reference structures we found increased maximum current densities of I{sub SD} = 1300 mA/mm (560 mA/mm). In addition, the InGaN layer helps to achieve broader transconductance profiles as well as reduced leakage currents.« less

Tracking millennial-scale Holocene glacial advance and retreat using osmium isotopes: Insights from the Greenland ice sheet

USGS Publications Warehouse

Rooney, Alan D.; Selby, David; Llyod, Jeremy M.; Roberts, David H.; Luckge, Andreas; Sageman, Bradley B.; Prouty, Nancy G.

2016-01-01

High-resolution Os isotope stratigraphy can aid in reconstructing Pleistocene ice sheet fluctuation and elucidating the role of local and regional weathering fluxes on the marine Os residence time. This paper presents new Os isotope data from ocean cores adjacent to the West Greenland ice sheet that have excellent chronological controls. Cores MSM-520 and DA00-06 represent distal to proximal sites adjacent to two West Greenland ice streams. Core MSM-520 has a steadily decreasing Os signal over the last 10 kyr (187Os/188Os = 1.35–0.81). In contrast, Os isotopes from core DA00-06 (proximal to the calving front of Jakobshavn Isbræ) highlight four stages of ice stream retreat and advance over the past 10 kyr (187Os/188Os = 2.31; 1.68; 2.09; 1.47). Our high-resolution chemostratigraphic records provide vital benchmarks for ice-sheet modelers as we attempt to better constrain the future response of major ice sheets to climate change. Variations in Os isotope composition from sediment and macro-algae (seaweed) sourced from regional and global settings serve to emphasize the overwhelming effect weathering sources have on seawater Os isotope composition. Further, these findings demonstrate that the residence time of Os is shorter than previous estimates of ∼104 yr.

Cosmogenic nuclide age estimate for Laurentide Ice Sheet recession from the terminal moraine, New Jersey, USA, and constraints on latest Pleistocene ice sheet history

USGS Publications Warehouse

Corbett, Lee B.; Bierman, Paul R.; Stone, Byron D.; Caffee, Marc W.; Larsen, Patrick L.

2017-01-01

The time at which the Laurentide Ice Sheet reached its maximum extent and subsequently retreated from its terminal moraine in New Jersey has been constrained by bracketing radiocarbon ages on preglacial and postglacial sediments. Here, we present measurements of in situ produced 10Be and 26Al in 16 quartz-bearing samples collected from bedrock outcrops and glacial erratics just north of the terminal moraine in north-central New Jersey; as such, our ages represent a minimum limit on the timing of ice recession from the moraine. The data set includes field and laboratory replicates, as well as replication of the entire data set five years after initial measurement. We find that recession of the Laurentide Ice Sheet from the terminal moraine in New Jersey began before 25.2±2.1 ka (10Be, n=16, average, 1 standard deviation). This cosmogenic nuclide exposure age is consistent with existing limiting radiocarbon ages in the study area and cosmogenic nuclide exposure ages from the terminal moraine on Martha’s Vineyard ~300 km to the northeast. The age we propose for Laurentide Ice Sheet retreat from the New Jersey terminal position is broadly consistent with regional and global climate records of the last glacial maximum termination and records of fluvial incision.

Analysis of defect structure in silicon. Characterization of SEMIX material. Silicon sheet growth development for the large area silicon sheet task of the low-cost solar array project

NASA Technical Reports Server (NTRS)

Natesh, R.; Stringfellow, G. B.; Virkar, A. V.; Dunn, J.; Guyer, T.

1983-01-01

Statistically significant quantitative structural imperfection measurements were made on samples from ubiquitous crystalline process (UCP) Ingot 5848 - 13C. Important correlation was obtained between defect densities, cell efficiency, and diffusion length. Grain boundary substructure displayed a strong influence on the conversion efficiency of solar cells from Semix material. Quantitative microscopy measurements gave statistically significant information compared to other microanalytical techniques. A surface preparation technique to obtain proper contrast of structural defects suitable for quantimet quantitative image analyzer (QTM) analysis was perfected and is used routinely. The relationships between hole mobility and grain boundary density was determined. Mobility was measured using the van der Pauw technique, and grain boundary density was measured using quantitative microscopy technique. Mobility was found to decrease with increasing grain boundary density.

1 μm-thickness ultra-flexible and high electrode-density surface electromyogram measurement sheet with 2 V organic transistors for prosthetic hand control.

PubMed

Fuketa, Hiroshi; Yoshioka, Kazuaki; Shinozuka, Yasuhiro; Ishida, Koichi; Yokota, Tomoyuki; Matsuhisa, Naoji; Inoue, Yusuke; Sekino, Masaki; Sekitani, Tsuyoshi; Takamiya, Makoto; Someya, Takao; Sakurai, Takayasu

2014-12-01

A 64-channel surface electromyogram (EMG) measurement sheet (SEMS) with 2 V organic transistors on a 1 μm-thick ultra-flexible polyethylene naphthalate (PEN) film is developed for prosthetic hand control. The surface EMG electrodes must satisfy the following three requirements; high mechanical flexibility, high electrode density and high signal integrity. To achieve high electrode density and high signal integrity, a distributed and shared amplifier (DSA) architecture is proposed, which enables an in-situ amplification of the myoelectric signal with a fourfold increase in EMG electrode density. In addition, a post-fabrication select-and-connect (SAC) method is proposed to cope with the large mismatch of organic transistors. The proposed SAC method reduces the area and the power overhead by 96% and 98.2%, respectively, compared with the use of conventional parallel transistors to reduce the transistor mismatch by a factor of 10.

Culture-expanded mesenchymal stem cell sheets enhance extraction-site alveolar bone growth: An animal study.

PubMed

Mu, S; Tee, B C; Emam, H; Zhou, Y; Sun, Z

2018-04-06

Impaired bone formation of the buccal alveolar plate after tooth extraction during adolescence increases the difficulty of future implant restoration. This study was undertaken to assess the feasibility and efficacy of transplanting autogenous scaffold-free culture-expanded mesenchymal stem cell (MSC) sheets to the buccal alveolar bone surface to stimulate local bone growth. Mandibular bone marrow was aspirated from 3-month-old pigs (n = 5), from which MSCs were isolated and culture expanded. Triple-layer MSC sheets were then fabricated using temperature-responsive tissue culture plates. One month after bone marrow aspirations, the same pigs underwent bilateral extraction of mandibular primary molars, immediately followed by transplantation of 3 autogenous triple-layer MSC sheets on to the subperiosteal buccal alveolar surface of 1 randomly chosen side. The contralateral side (control) underwent the same periosteal reflection surgery without receiving MSC sheet transplantation. Six weeks later, the animals were killed and specimens from both sides were immediately harvested for radiographic and histological analysis. Buccal alveolar bone thickness, tissue mineral density (TMD), mineral apposition and bone volume fraction (BV/TV) were quantified and compared between the MSC sheet and control sides using paired t-tests. Triple-layer MSC sheets were reliably fabricated and the majority of cells remained vital before transplantation. The thickness of buccal bone tended to increase with MSC sheet transplantation (P = .18), with 4 of 5 animals showing an average of 1.82 ± 0.73 mm thicker bone on the MSC sheet side than the control side. After being normalized by the TMD of intracortical bone, the TMD of surface cortical bone was 0.5-fold higher on the MSC sheet side than the control side (P < .05). Likewise, the BV/TV measurements of the buccal surface region were also 0.4-fold higher on the MSC sheet side than the control side (P < .05) after being normalized by measurements from the intracortical region. Mineral apposition measurements were not different between the 2 sides. Mandibular marrow-derived MSCs can be fabricated into cell sheets and autogenous transplantation of MSC sheets onto the subperiosteal buccal alveolar bone surface at the tooth-extraction site may increase local bone density. © 2018 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Modeling the effect of doping on the catalyst-assisted growth and field emission properties of plasma-grown graphene sheet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gupta, Neha; Sharma, Suresh C.; Sharma, Rinku

A theoretical model describing the effect of doping on the plasma-assisted catalytic growth of graphene sheet has been developed. The model accounts the charging rate of the graphene sheet, kinetics of all the plasma species, including the doping species, and the growth rate of graphene nuclei and graphene sheet due to surface diffusion, and accretion of ions on the catalyst nanoparticle. Using the model, it is observed that nitrogen and boron doping can strongly influence the growth and field emission properties of the graphene sheet. The results of the present investigation indicate that nitrogen doping results in reduced thickness andmore » shortened height of the graphene sheet; however, boron doping increases the thickness and height of the graphene sheet. The time evolutions of the charge on the graphene sheet and hydrocarbon number density for nitrogen and boron doped graphene sheet have also been examined. The field emission properties of the graphene sheet have been proposed on the basis of the results obtained. It is concluded that nitrogen doped graphene sheet exhibits better field emission characteristics as compared to undoped and boron doped graphene sheet. The results of the present investigation are consistent with the existing experimental observations.« less

An Antarctic stratigraphic record of step-wise ice-sheet growth through the Eocene-Oligocene transition

NASA Astrophysics Data System (ADS)

Passchier, S.; Ciarletta, D. J.; Miriagos, T.; Bijl, P.; Bohaty, S. M.

2016-12-01

The Antarctic cryosphere plays a critical role in the ocean-atmosphere system, but its early evolution is still poorly known. With a near-field record from Prydz Bay, Antarctica, we conclude that Antarctic continental ice-sheet growth commenced with the EOT-1 "precursor" glaciation, during a time of Subantarctic surface ocean cooling and a decline in atmospheric pCO2. Prydz Bay lies downstream of a major East Antarctic ice-sheet drainage system and the Gamburtsev Mountains, a likely nucleation point for the first ice sheets. Its sedimentary records uniquely constrain the timing of ice-sheet advance onto the continental shelf. We investigate a detrital record extracted from three Ocean Drilling Program drill holes in Prydz Bay within a new depositional and chronological framework spanning the late Eocene to early Oligocene ( 36-33 Ma). The chemical index of alteration (CIA) and the S-index, calculated from the major element geochemistry of bulk samples, yield estimates of chemical weathering intensities and mean annual temperature (MAT) on the East Antarctic continent. We document evidence for late Eocene mountain glaciation along with transient warm events at 35.8-34.8 Ma. These data and our sedimentological analyses confirm the presence of ephemeral mountain glaciers on East Antarctica during the late Eocene between 35.9 and 34.4 Ma. Furthermore, we document the stepwise climate cooling of the Antarctic hinterland from 34.4 Ma as the ice sheet advanced towards the edges of the continent during EOT-1. The youngest part of our data set correlates to the time interval of the Oi-1 glaciation, when the ice-sheet in Prydz Bay extended to the outer shelf. Cooling and ice growth on Antarctica was spatially variable and ice sheets formed under declining pCO2. These results point to complex ice sheet - atmosphere - ocean - solid-earth feedbacks.

Geological and geomorphological insights into Antarctic ice sheet evolution.

PubMed

Sugden, David E; Bentley, Michael J; O Cofaigh, Colm

2006-07-15

Technical advances in the study of ice-free parts of Antarctica can provide quantitative records that are useful for constraining and refining models of ice sheet evolution and behaviour. Such records improve our understanding of system trajectory, influence the questions we ask about system stability and help to define the ice-sheet processes that are relevant on different time-scales. Here, we illustrate the contribution of cosmogenic isotope analysis of exposed bedrock surfaces and marine geophysical surveying to the understanding of Antarctic ice sheet evolution on a range of time-scales. In the Dry Valleys of East Antarctica, 3He dating of subglacial flood deposits that are now exposed on mountain summits provide evidence of an expanded and thicker Mid-Miocene ice sheet. The survival of surface boulders for approximately 14Myr, the oldest yet measured, demonstrates exceptionally low rates of subsequent erosion and points to the persistence and stability of the dry polar desert climate since that time. Increasingly, there are constraints on West Antarctic ice sheet fluctuations during Quaternary glacial cycles. In the Sarnoff Mountains of Marie Byrd Land in West Antarctica, 10Be and 26Al cosmogenic isotope analysis of glacial erratics and bedrock reveal steady thinning of the ice sheet from 10400 years ago to the present, probably as a result of grounding line retreat. In the Antarctic Peninsula, offshore analysis reveals an extensive ice sheet at the last glacial maximum. Based on radiocarbon dating, deglaciation began by 17000cal yr BP and was complete by 9500cal yr BP. Deglaciation of the west and east sides of the Antarctic Peninsula ice sheet occurred at different times and rates, but was largely complete by the Early Holocene. At that time ice shelves were less extensive on the west side of the Antarctic Peninsula than they are today. The message from the past is that individual glacier drainage basins in Antarctica respond in different and distinctive ways to global climate change, depending on the link between regional topography and climate setting.

EnviroAtlas - New York, NY - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Paterson, NJ - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Fresno, CA - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Green Bay, WI - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Des Moines, IA - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Minneapolis/St. Paul, MN - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Woodbine, IA - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Phoenix, AZ - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Pittsburgh, PA - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - New Bedford, MA - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Milwaukee, WI - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Austin, TX - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Cleveland, OH - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Portland, ME - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Portland, OR - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Durham, NC - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Tampa, FL - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

EnviroAtlas - Memphis, TN - Estimated Intersection Density of Walkable Roads

EPA Pesticide Factsheets

This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections are defined as any point where 3 or more roads meet and density is calculated using kernel density, where closer intersections are weighted higher than further intersections. Intersection density is highly correlated with walking for transportation. This dataset was produced by the US EPA to support research and online mapping activities related to EnviroAtlas. EnviroAtlas (https://www.epa.gov/enviroatlas) allows the user to interact with a web-based, easy-to-use, mapping application to view and analyze multiple ecosystem services for the contiguous United States. The dataset is available as downloadable data (https://edg.epa.gov/data/Public/ORD/EnviroAtlas) or as an EnviroAtlas map service. Additional descriptive information about each attribute in this dataset can be found in its associated EnviroAtlas Fact Sheet (https://www.epa.gov/enviroatlas/enviroatlas-fact-sheets).

Multi-proxy Organic Geochemical Reconstruction of Holocene Hydroclimate Near the Western Greenland Ice Sheet Margin

NASA Astrophysics Data System (ADS)

Cluett, A.; Thomas, E. K.

2017-12-01

Anthropogenic warming is projected to drive profound change to the Arctic hydrological cycle within the century, most notably in the intensification of rainfall, with potential feedbacks to the climate system and cryosphere. However, the relationship between hydroclimate and cryosphere variability is poorly constrained in the long-term due to a scarcity of high-resolution hydroclimate records from the Arctic. We analyze the stable hydrogen isotopes (dD) of leaf wax biomarkers from lacustrine sediments spanning the Holocene to 9000 cal. year B.P. from Lake Gus (67.032ºN, 52.427ºW, 300 m a.s.l.; informal name), a small lake approximately 90 km from the modern western margin of the Greenland Ice Sheet. We interpret the signal of aquatic leaf wax isotopes in the context of a survey of 100 modern lake water samples from western Greenland across an aridity gradient to better understand the combined climatological and hydrological controls on lake water dD in the study area. We compare variability of aquatic and terrestrial leaf wax isotopes to infer changes in relative moisture throughout the Holocene, and complement our leaf wax record with analysis of glycerol dialkyl glycerol tetraethers (GDGTs) and alkenones, to produce records of summer temperature. Pairing temperature and leaf wax isotope records provides a means to constrain the changing dD-temperature relationship throughout the Holocene and infer moisture source variability. In combination, these proxies produce a comprehensive hydroclimate record at approximately centennial scale to evaluate shifts in relative moisture, temperature, and moisture source, and to investigate the interaction between hydroclimate and Greenland Ice Sheet margin fluctuations through the Holocene.

Deglacial history of the Pensacola Mountains, Antarctica from glacial geomorphology and cosmogenic nuclide surface exposure dating

NASA Astrophysics Data System (ADS)

Bentley, M. J.; Hein, A. S.; Sugden, D. E.; Whitehouse, P. L.; Shanks, R.; Xu, S.; Freeman, S. P. H. T.

2017-02-01

The retreat history of the Antarctic Ice Sheet is important for understanding rapid deglaciation, as well as to constrain numerical ice sheet models and ice loading models required for glacial isostatic adjustment modelling. There is particular debate about the extent of grounded ice in the Weddell Sea embayment at the Last Glacial Maximum, and its subsequent deglacial history. Here we provide a new dataset of geomorphological observations and cosmogenic nuclide surface exposure ages of erratic samples that constrain the deglacial history of the Pensacola Mountains, adjacent to the present day Foundation Ice Stream and Academy Glacier in the southern Weddell Sea embayment. We show there is evidence of at least two glaciations, the first of which was relatively old and warm-based, and a more recent cold-based glaciation. During the most recent glaciation ice thickened by at least 450 m in the Williams Hills and at least 380 m on Mt Bragg. Progressive thinning from these sites was well underway by 10 ka BP and ice reached present levels by 2.5 ka BP, and is broadly similar to the relatively modest thinning histories in the southern Ellsworth Mountains. The thinning history is consistent with, but does not mandate, a Late Holocene retreat of the grounding line to a smaller-than-present configuration, as has been recently hypothesized based on ice sheet and glacial isostatic modelling. The data also show that clasts with complex exposure histories are pervasive and that clast recycling is highly site-dependent. These new data provide constraints on a reconstruction of the retreat history of the formerly-expanded Foundation Ice Stream, derived using a numerical flowband model.

Understanding Subsurface Geoelectrical and Structural Constrains for Low Frequency Radar Sounding of Jovian Satellites

NASA Astrophysics Data System (ADS)

Heggy, Essam; Bruzzone, Lorenzo; Beck, Pierre; Doute, Sylvain; Gim, Youngyu; Herique, Alain; Kofman, Wlodek; Orosei, Roberto; Plaut, Jeffery; Rosen, Paul; Seu, Roberto

2010-05-01

Thermally stable Ice sheets on earth are known to be among the most favorable geophysical contexts for deep subsurface sounding radars. Penetrations ranging from few to several hundreds of meters have been observed at 10 to 60 MHz when sounding homogenous and pure ice sheets in Antarctica and in Alaskan glaciers. Unlike the terrestrial case, ice sheets on Jovian satellites are older formations with a more complex matrix of mineral inclusions with an even three dimensional distribution on the surface and subsurface that is yet to be understood in order to quantify its effect on the dielectric attenuation at the experiment sounding frequencies. Moreover, ridges, tectonic and shock features, may results in a complex and heterogeneous subsurface structure that can induce scattering attenuation with different amplitudes depending on the subsurface heterogeneity levels. Such attenuation phenomena's has to be accounted in the instrument design and future data analysis in order to optimize the science return, reduce mission risk and define proper operation modes. In order to address those challenges in the current performance studies and instrument design of the proposed radar sounding experiments, we present an attempt to quantify both the dielectric and scattering losses on both icy satellites, Ganymede and Europa, based on experimental dielectric characterization of relevant icy-dust mixtures samples, field work from analog environment and radar propagation simulations in parametric subsurface geophysical models representing potential geological scenarios of the two Jovian satellites. Our preliminary results suggest that the use of a dual band radar enable to overcome several of these constrains and reduces ambiguities associated subsurface interface mapping. Acknowledgement. This research is carried out by the Jet Propulsion Laboratory/Caltech, under a grant from the National Aeronautics and Space Administration.

Probing the Milky Way electron density using multi-messenger astronomy

NASA Astrophysics Data System (ADS)

Breivik, Katelyn; Larson, Shane

2015-04-01

Multi-messenger observations of ultra-compact binaries in both gravitational waves and electromagnetic radiation supply highly complementary information, providing new ways of characterizing the internal dynamics of these systems, as well as new probes of the galaxy itself. Electron density models, used in pulsar distance measurements via the electron dispersion measure, are currently not well constrained. Simultaneous radio and gravitational wave observations of pulsars in binaries provide a method of measuring the average electron density along the line of sight to the pulsar, thus giving a new method for constraining current electron density models. We present this method and assess its viability with simulations of the compact binary component of the Milky Way using the public domain binary evolution code, BSE. This work is supported by NASA Award NNX13AM10G.

Analysis of defect structure in silicon. Silicon sheet growth development for the large area silicon sheet task of the Low-Cost Solar array Project

NASA Technical Reports Server (NTRS)

Natesh, R.; Mena, M.; Plichta, M.; Smith, J. M.; Sellani, M. A.

1982-01-01

One hundred ninety-three silicon sheet samples, approximately 880 square centimeters, were analyzed for twin boundary density, dislocation pit density, and grain boundary length. One hundred fifteen of these samples were manufactured by a heat exchanger method, thirty-eight by edge defined film fed growth, twenty-three by the silicon on ceramics process, and ten by the dendritic web process. Seven solar cells were also step-etched to determine the internal defect distribution on these samples. Procedures were developed or the quantitative characterization of structural defects such as dislocation pits, precipitates, twin & grain boundaries using a QTM 720 quantitative image analyzing system interfaced with a PDP 11/03 mini computer. Characterization of the grain boundary length per unit area for polycrystalline samples was done by using the intercept method on an Olympus HBM Microscope.

High Resolution Photogrammetric Digital Elevation Models Across Calving Fronts and Meltwater Channels in Greenland

NASA Astrophysics Data System (ADS)

Le Bel, D. A.; Brown, S.; Zappa, C. J.; Bell, R. E.; Frearson, N.; Tinto, K. J.

2014-12-01

Photogrammetric digital elevation models (DEMs) are a powerful approach for understanding elevation change and dynamics along the margins of the large ice sheets. The IcePod system, mounted on a New York Air National Guard LC-130, can measure high-resolution surface elevations with a Riegl VQ580 scanning laser altimeter and Imperx Bobcat IGV-B6620 color visible-wavelength camera (6600x4400 resolution); the surface temperature with a Sofradir IRE-640L infrared camera (spectral response 7.7-9.5 μm, 640x512 resolution); and the structure of snow and ice with two radar systems. We show the use of IcePod imagery to develop DEMs across calving fronts and meltwater channels in Greenland. Multiple over-flights of the Kangerlussaq Airport ramp have provided a test of the technique at a location with accurate, independently-determined elevation. Here the photogrammetric DEM of the airport, constrained by ground control measurements, is compared with the Lidar results. In July 2014 the IcePod ice-ocean imaging system surveyed the calving fronts of five outlet glaciers north of Jakobshavn Isbrae. We used Agisoft PhotoScan to develop a DEM of each calving front using imagery captured by the IcePod systems. Adjacent to the ice sheet, meltwater plumes foster mixing in the fjord, moving warm ocean water into contact with the front of the ice sheet where it can undercut the ice front and trigger calving. The five glaciers provide an opportunity to examine the calving front structure in relation to ocean temperature, fjord circulation, and spatial scale of the meltwater plumes. The combination of the accurate DEM of the calving front and the thermal imagery used to constrain the temperature and dynamics of the adjacent plume provides new insights into the ice-ocean interactions. Ice sheet margins provide insights into the connections between the surface meltwater and the fate of the water at the ice sheet base. Surface meltwater channels are visualized here for the first time using the combination of Lidar, photogrammetry DEMs and infrared imagery. These techniques leverage electromagnetic surface properties that allow us to identify the presence of water, measure the slope and elevation of the channel, as well as the two-dimensional temperature variability of the water/ice/snow in multiple melt channels within a drainage system.

Translating hydrologically-relevant variables from the ice sheet model SICOPOLIS to the Greenland Analog Project hydrologic modeling domain

NASA Astrophysics Data System (ADS)

Vallot, Dorothée; Applegate, Patrick; Pettersson, Rickard

2013-04-01

Projecting future climate and ice sheet development requires sophisticated models and extensive field observations. Given the present state of our knowledge, it is very difficult to say what will happen with certainty. Despite the ongoing increase in atmospheric greenhouse gas concentrations, the possibility that a new ice sheet might form over Scandinavia in the far distant future cannot be excluded. The growth of a new Scandinavian Ice Sheet would have important consequences for buried nuclear waste repositories. The Greenland Analogue Project, initiated by the Swedish Nuclear Fuel and Waste Management Company (SKB), is working to assess the effects of a possible future ice sheet on groundwater flow by studying a constrained domain in Western Greenland by field measurements (including deep bedrock drilling in front of the ice sheet) combined with numerical modeling. To address the needs of the GAP project, we interpolated results from an ensemble of ice sheet model runs to the smaller and more finely resolved modeling domain used in the GAP project's hydrologic modeling. Three runs have been chosen with three fairly different positive degree-day factors among those that reproduced the modern ice margin at the borehole position. The interpolated results describe changes in hydrologically-relevant variables over two time periods, 115 ka to 80 ka, and 20 ka to 1 ka. In the first of these time periods, the ice margin advances over the model domain; in the second time period, the ice margin retreats over the model domain. The spatially-and temporally dependent variables that we treated include the ice thickness, basal melting rate, surface mass balance, basal temperature, basal thermal regime (frozen or thawed), surface temperature, and basal water pressure. The melt flux is also calculated.

Chronology of paleozoic metamorphism and deformation in the Blue Ridge thrust complex, North Carolina and Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldberg, S.A.; Dallmeyer, R.D.

1997-05-01

The Blue Ridge province in northwestern North Carolina and northeastern Tennessee records a multiphase collisional and accretionary history from the Mesoproterozoic through the Paleozoic. To constrain the tectonothermal evolution in this region, radiometric ages have been determined for 23 regionally metamorphosed amphibolites, granitic gneisses, and pelitic schists and from mylonites along shear zones that bound thrust sheets and within an internal shear zone. The garnet ages from the Pumpkin Patch a thrust sheet (458, 455, and 451 Ma) are similar to those from the structurally overlying Spruce Pine thrust sheet (460, 456, 455, and 450 Ma). Both thrust sheets exhibitmore » similar upper amphibolite-facies conditions. Because of the high closure temperature for garnet, the garnet ages are interpreted to date growth at or near the peak of Taconic metamorphism. Devonian metamorphic ages are recognized in the Spruce Pine thrust sheet, where Sm-Nd and Rb-Sr garnet ages of 386 and 393 Ma and mineral isochron ages of 397 {+-} 14 and 375 {+-} 27 Ma are preserved. Hornblendes record similar {sup 40}Ar/{sup 39}Ar, Sm-Nd, and Rb-Sr ages of 398 to 379 Ma. Devonian {sup 40}Ar/{sup 39}Ar hornblende ages are also recorded in the structurally lower Pumpkin Patch thrust sheet. The Devonian mineral ages are interpreted to date a discrete tectonothermal event, as opposed to uplift and slow cooling from an Ordovician metamorphic event. The Mississippian mylonitization is interpreted to represent thrusting and initial assembly of crystalline sheets associated with the Alleghanian orogeny. The composite thrust stack of the Blue Ridge complex was subsequently thrust northwestward along the Linville Falls fault during middle Alleghanian orogeny (about 300 Ma).« less

Extensive Holocene ice sheet grounding line retreat and uplift-driven readvance in West Antarctica

NASA Astrophysics Data System (ADS)

Kingslake, J.; Scherer, R. P.; Albrecht, T.; Coenen, J. J.; Powell, R. D.; Reese, R.; Stansell, N.; Tulaczyk, S. M.; Whitehouse, P. L.

2017-12-01

The West Antarctic Ice Sheet (WAIS) reached its Last Glacial Maximum (LGM) extent 29-14 kyr before present. Numerical models used to project future ice-sheet contributions to sea-level rise exploit reconstructions of post-LGM ice mass loss to tune model parameterizations. Ice-sheet reconstructions are poorly constrained in areas where floating ice shelves or a lack of exposed geology obstruct conventional glacial-geological techniques. In the Weddell and Ross Sea sectors, ice-sheet reconstructions have traditionally assumed progressive grounding line (GL) retreat throughout the Holocene. Contrasting this view, using three distinct lines of evidence, we show that the GL retreated hundreds of kilometers inland of its present position, before glacial isostatic rebound during the Mid to Late Holocene caused the GL to readvance to its current position. Evidence for retreat and readvance during the last glacial termination includes (1) widespread radiocarbon in sediment cores recovered from beneath ice streams along the Siple and Gould Coasts, indicating marine exposure at least 200 km inland of the current GL, (2) ice-penetrating radar observations of relic crevasses and other englacial structures preserved in slow-moving grounded ice, indicating ice-shelf grounding and (3) an ensemble of new ice-sheet simulations showing widespread post-LGM retreat of the GL inland of its current location and later readvance. The model indicates that GL readvance across low slope ice-stream troughs requires uplift-driven grounding of the ice shelf on topographic highs (ice rises). Our findings highlight ice-shelf pinning points and lithospheric response to unloading as drivers of major ice-sheet fluctuations. Full WAIS collapse likely requires GL retreat well beyond its current position in the Ronne and Ross Sectors and linkage via Amundsen Sea sector glaciers.

Exploring changes in vertical ice extent along the margin of the East Antarctic Ice Sheet in western Dronning Maud Land - initial results of the MAGIC-DML collaboration

NASA Astrophysics Data System (ADS)

Lifton, N. A.; Newall, J. C.; Fredin, O.; Glasser, N. F.; Fabel, D.; Rogozhina, I.; Bernales, J.; Prange, M.; Sams, S.; Eisen, O.; Hättestrand, C.; Harbor, J.; Stroeven, A. P.

2017-12-01

Numerical ice sheet models constrained by theory and refined by comparisons with observational data are a central component of work to address the interactions between the cryosphere and changing climate, at a wide range of scales. Such models are tested and refined by comparing model predictions of past ice geometries with field-based reconstructions from geological, geomorphological, and ice core data. However, on the East Antarctic Ice sheet, there are few empirical data with which to reconstruct changes in ice sheet geometry in the Dronning Maud Land (DML) region. In addition, there is poor control on the regional climate history of the ice sheet margin, because ice core locations, where detailed reconstructions of climate history exist, are located on high inland domes. This leaves numerical models of regional glaciation history in this near-coastal area largely unconstrained. MAGIC-DML is an ongoing Swedish-US-Norwegian-German-UK collaboration with a focus on improving ice sheet models by combining advances in numerical modeling with filling critical data gaps that exist in our knowledge of the timing and pattern of ice surface changes on the western Dronning Maud Land margin. A combination of geomorphological mapping using remote sensing data, field investigations, cosmogenic nuclide surface exposure dating, and numerical ice-sheet modeling are being used in an iterative manner to produce a comprehensive reconstruction of the glacial history of western Dronning Maud Land. We will present an overview of the project, as well as field observations and preliminary in situ cosmogenic nuclide measurements from the 2016/17 expedition.

The Folding of Acetyl(Ala)28NH2 and Acetyl(Ala)40NH2 Extended Strand Peptides into Antiparallel β-Sheets. A Density Functional Theory Study of β-Sheets with β-Turns

PubMed Central

Ali-Torres, Jorge

2012-01-01

We report ONIOM calculations using B3LYP/D95** and AM1 on β-sheet formation from acetyl(Ala)NNH2 (N=28 or 40). The sheets contain from one to four β-turns for N=28 and up to six for N=40. We have obtained four types of geometrically optimized structures. All contain only β-turns. They differ from each other in the types of β-turns formed. The unsolvated sheets containing two turns are most stable. Aqueous solvation (using the SM5.2 and CPCM methods) reduces the stabilities of the folded structures compared to the extended strands. PMID:23157432

One-dimensional Vlasov-Maxwell equilibrium for the force-free Harris sheet.

PubMed

Harrison, Michael G; Neukirch, Thomas

2009-04-03

In this Letter, the first nonlinear force-free Vlasov-Maxwell equilibrium is presented. One component of the equilibrium magnetic field has the same spatial structure as the Harris sheet, but whereas the Harris sheet is kept in force balance by pressure gradients, in the force-free solution presented here force balance is maintained by magnetic shear. Magnetic pressure, plasma pressure and plasma density are constant. The method used to find the equilibrium is based on the analogy of the one-dimensional Vlasov-Maxwell equilibrium problem to the motion of a pseudoparticle in a two-dimensional conservative potential. The force-free solution can be generalized to a complete family of equilibria that describe the transition between the purely pressure-balanced Harris sheet to the force-free Harris sheet.

40 CFR Appendix A to Subpart II of... - VOC Data Sheet 1

Code of Federal Regulations, 2013 CFR

2013-07-01

... supplied” by the manufacturer. Properties of the coating as supplied 1 to the customer: A. Coating Density... (nonvolatiles) 2. __ g/L coating (less water and exempt compounds) G. Thinner Density: Dth __ g/L ASTM...

40 CFR Appendix A to Subpart II of... - VOC Data Sheet 1

Code of Federal Regulations, 2011 CFR

2011-07-01

... supplied” by the manufacturer. Properties of the coating as supplied 1 to the customer: A. Coating Density... (nonvolatiles) 2. __ g/L coating (less water and exempt compounds) G. Thinner Density: Dth __ g/L ASTM...

Fiber length - fiber strength interrelationship for slash pine and its effect on pulp-sheet properties

Treesearch

F.F. Wangaard; George E. Woodson

1972-01-01

Based on a model developed for hardwood fiber strength-pulp property relationships, multiple-regression equations involving fiber strength, fiber length, and sheet density were determined to predict the properties of kraft pulps of slash pine (Pinus elliottii). Regressions for breaking length and burst factor accounted for 88 and 90 percent,...

Fiber length strength interrelationship for slash pine and its effect on pulp-sheet properties

Treesearch

F. G. Wangaard; G. E. Woodson

1973-01-01

Based on a model developed for hardwood fiber strength-pulp property relationships, multiple-regression equations involving fiber strength, fiber length, and sheet density were determined to predict the properties of kraft pulps of slash pine (Pinus elliottii). Regressions for breaking length and burst factor accounted for 88 and 90 percent,...

Macroscopically constrained Wang-Landau method for systems with multiple order parameters and its application to drawing complex phase diagrams

NASA Astrophysics Data System (ADS)

Chan, C. H.; Brown, G.; Rikvold, P. A.

2017-05-01

A generalized approach to Wang-Landau simulations, macroscopically constrained Wang-Landau, is proposed to simulate the density of states of a system with multiple macroscopic order parameters. The method breaks a multidimensional random-walk process in phase space into many separate, one-dimensional random-walk processes in well-defined subspaces. Each of these random walks is constrained to a different set of values of the macroscopic order parameters. When the multivariable density of states is obtained for one set of values of fieldlike model parameters, the density of states for any other values of these parameters can be obtained by a simple transformation of the total system energy. All thermodynamic quantities of the system can then be rapidly calculated at any point in the phase diagram. We demonstrate how to use the multivariable density of states to draw the phase diagram, as well as order-parameter probability distributions at specific phase points, for a model spin-crossover material: an antiferromagnetic Ising model with ferromagnetic long-range interactions. The fieldlike parameters in this model are an effective magnetic field and the strength of the long-range interaction.

Comparisons of human amniotic mesenchymal stem cell viability in FDA-approved collagen-based scaffolds: Implications for engineered diaphragmatic replacement.

PubMed

Shieh, Hester F; Graham, Christopher D; Brazzo, Joseph A; Zurakowski, David; Fauza, Dario O

2017-06-01

We sought to examine amniotic fluid mesenchymal stem cell (afMSC) viability within two FDA-approved collagen-based scaffolds, as a prerequisite to clinical translation of afMSC-based engineered diaphragmatic repair. Human afMSCs were seeded in a human-derived collagen hydrogel and in a bovine-derived collagen sheet at 3 matching densities. Cell viability was analyzed at 1, 3, and 5days using an ATP-based 3D bioluminescence assay. Statistical comparisons were by ANOVA (P<0.05). There was a highly significant 3-way interaction between scaffold type, seeding density, and time in 3D culture as determinants of cell viability, clearly favoring the human hydrogel (P<0.001). In both scaffolds, cell viability was highest at the highest seeding density of 150,000 cells/mL. Time in 3D culture impacted cell viability at the optimal seeding density in the human hydrogel, with the highest levels on days 1 (P<0.001) and 5 (P=0.05) with no significant effect in the bovine sheet (P=0.39-0.96). Among clinically-approved cell delivery vehicles, mesenchymal stem cell viability is significantly enhanced in a collagen hydrogel when compared with a collagen sheet. Cell viability can be further optimized by seeding density and time in 3D culture. These data further support the regulatory viability of clinical trials of engineered diaphragmatic repair. N/A (animal and laboratory study). Copyright © 2017 Elsevier Inc. All rights reserved.

Constraining the Speed of Sound inside Neutron Stars with Chiral Effective Field Theory Interactions and Observations

NASA Astrophysics Data System (ADS)

Tews, I.; Carlson, J.; Gandolfi, S.; Reddy, S.

2018-06-01

The dense matter equation of state (EOS) determines neutron star (NS) structure but can be calculated reliably only up to one to two times the nuclear saturation density, using accurate many-body methods that employ nuclear interactions from chiral effective field theory constrained by scattering data. In this work, we use physically motivated ansatzes for the speed of sound c S at high density to extend microscopic calculations of neutron-rich matter to the highest densities encountered in stable NS cores. We show how existing and expected astrophysical constraints on NS masses and radii from X-ray observations can constrain the speed of sound in the NS core. We confirm earlier expectations that c S is likely to violate the conformal limit of {c}S2≤slant {c}2/3, possibly reaching values closer to the speed of light c at a few times the nuclear saturation density, independent of the nuclear Hamiltonian. If QCD obeys the conformal limit, we conclude that the rapid increase of c S required to accommodate a 2 M ⊙ NS suggests a form of strongly interacting matter where a description in terms of nucleons will be unwieldy, even between one and two times the nuclear saturation density. For typical NSs with masses in the range of 1.2–1.4 M ⊙, we find radii between 10 and 14 km, and the smallest possible radius of a 1.4 M ⊙ NS consistent with constraints from nuclear physics and observations is 8.4 km. We also discuss how future observations could constrain the EOS and guide theoretical developments in nuclear physics.

Constraining Water Vapor Abundance on Mars using a Coupled Heat-Water Transport Model and Seasonal Frost Observations

NASA Astrophysics Data System (ADS)

Bapst, J.; Byrne, S.

2016-12-01

The stability of water ice on Mars' surface is determined by its temperature and the density of water vapor at the bottom of the atmosphere. Multiple orbiting instruments have been used to study column-integrated water abundance in the martian atmosphere, resolving the global annual water cycle. However, poor knowledge of the vertical distribution of water makes constraining its abundance near the surface difficult. One must assume a mixing regime to produce surface vapor density estimates. More indirectly, one can use the appearance and disappearance of seasonal water frost, along with ice stability models, to estimate this value. Here, we use derived temperature and surface reflectance data from MGS TES to constrain a 1-D thermal diffusion model, which is coupled to an atmospheric water transport model. TES temperatures are used to constrain thermal properties of our modeled subsurface, while changes in TES albedo can be used to determine the timing of water frost. We tune the density of water vapor in the atmospheric model to match the observed seasonal water frost timing in the northern hemisphere, poleward of 45°N. Thus, we produce a new estimate for the water abundance in the lower atmosphere of Mars and how it varies seasonally and geographically. The timing of water frost can be ambiguous in TES data, especially at lower latitudes where the albedo contrast between frosted and unfrosted surfaces is lower (presumably due to lesser areal coverage of water frost). The uncertainty in frost timing with our approach is <20° LS ( 40 sols), and will be used to define upper and lower bounds in our estimate of vapor density. The implications of our derived vapor densities on the stability of surface and subsurface water ice will be discussed.

Modelling the Climate - Greenland Ice Sheet Interaction in the Coupled Ice-sheet/Climate Model EC-EARTH - PISM

NASA Astrophysics Data System (ADS)

Yang, S.; Madsen, M. S.; Rodehacke, C. B.; Svendsen, S. H.; Adalgeirsdottir, G.

2014-12-01

Recent observations show that the Greenland ice sheet (GrIS) has been losing mass with an increasing speed during the past decades. Predicting the GrIS changes and their climate consequences relies on the understanding of the interaction of the GrIS with the climate system on both global and local scales, and requires climate model systems with an explicit and physically consistent ice sheet module. A fully coupled global climate model with a dynamical ice sheet model for the GrIS has recently been developed. The model system, EC-EARTH - PISM, consists of the EC-EARTH, an atmosphere, ocean and sea ice model system, and the Parallel Ice Sheet Model (PISM). The coupling of PISM includes a modified surface physical parameterization in EC-EARTH adapted to the land ice surface over glaciated regions in Greenland. The PISM ice sheet model is forced with the surface mass balance (SMB) directly computed inside the EC-EARTH atmospheric module and accounting for the precipitation, the surface evaporation, and the melting of snow and ice over land ice. PISM returns the simulated basal melt, ice discharge and ice cover (extent and thickness) as boundary conditions to EC-EARTH. This coupled system is mass and energy conserving without being constrained by any anomaly correction or flux adjustment, and hence is suitable for investigation of ice sheet - climate feedbacks. Three multi-century experiments for warm climate scenarios under (1) the RCP85 climate forcing, (2) an abrupt 4xCO2 and (3) an idealized 1% per year CO2 increase are performed using the coupled model system. The experiments are compared with their counterparts of the standard CMIP5 simulations (without the interactive ice sheet) to evaluate the performance of the coupled system and to quantify the GrIS feedbacks. In particular, the evolution of the Greenland ice sheet under the warm climate and its impacts on the climate system are investigated. Freshwater fluxes from the Greenland ice sheet melt to the Arctic and North Atlantic basin and their influence on the ocean stratification and ocean circulation are analysed. The changes in the surface climate and the atmospheric circulation associated with the impact of the Greenland ice sheet changes are quantified. The interaction between the Greenland ice sheet and Arctic sea ice is also examined.

Dual modes of motility at the leading edge of migrating epithelial cell sheets

PubMed Central

Klarlund, Jes K.

2012-01-01

Purse-string healing is driven by contraction of actin/myosin cables that span cells at wound edges, and it is the predominant mode of closing small round wounds in embryonic and some adult epithelia. Wounds can also heal by cell crawling, and my colleagues and I have shown previously that the presence of unconstrained, straight edges in sheets of epithelial cells is a sufficient signal to induce healing by crawling. Here, it is reported that the presence of highly concave edges, which are free or physically constrained by an inert material (agarose), is sufficient to induce formation of purse strings. It was determined that neither of the two types of healing required cell damage or other potential stimuli by using the particularly gentle procedure of introducing gaps by digesting agarose blocks imbedded in the cell sheets. Movement by crawling depends on signaling by the EGF receptor (EGFR); however, this was not required for purse-string contraction. A migrating epithelial cell sheet usually produces finger-like projections of crawling cells. The cells between fingers contain continuous actin cables, which were also determined to contain myosin IIA and exhibit additional characteristics of purse strings. When crawling was blocked by inhibition of EGFR signaling, the concave regions continued to move, suggesting that both mechanisms contribute to propel the sheets forward. Wounding epithelial cell sheets causes activation of the EGFR, which triggers movement by crawling. The EGFR was found to be activated only at straight and convex edges, which explains how both types of movement can coexist at leading epithelial edges. PMID:23019364

Scale size and life time of energy conversion regions observed by Cluster in the plasma sheet

NASA Astrophysics Data System (ADS)

Hamrin, M.; Norqvist, P.; Marghitu, O.; Vaivads, A.; Klecker, B.; Kistler, L. M.; Dandouras, I.

2009-11-01

In this article, and in a companion paper by Hamrin et al. (2009) [Occurrence and location of concentrated load and generator regions observed by Cluster in the plasma sheet], we investigate localized energy conversion regions (ECRs) in Earth's plasma sheet. From more than 80 Cluster plasma sheet crossings (660 h data) at the altitude of about 15-20 RE in the summer and fall of 2001, we have identified 116 Concentrated Load Regions (CLRs) and 35 Concentrated Generator Regions (CGRs). By examining variations in the power density, E·J, where E is the electric field and J is the current density obtained by Cluster, we have estimated typical values of the scale size and life time of the CLRs and the CGRs. We find that a majority of the observed ECRs are rather stationary in space, but varying in time. Assuming that the ECRs are cylindrically shaped and equal in size, we conclude that the typical scale size of the ECRs is 2 RE≲ΔSECR≲5 RE. The ECRs hence occupy a significant portion of the mid altitude plasma sheet. Moreover, the CLRs appear to be somewhat larger than the CGRs. The life time of the ECRs are of the order of 1-10 min, consistent with the large scale magnetotail MHD simulations of Birn and Hesse (2005). The life time of the CGRs is somewhat shorter than for the CLRs. On time scales of 1-10 min, we believe that ECRs rise and vanish in significant regions of the plasma sheet, possibly oscillating between load and generator character. It is probable that at least some of the observed ECRs oscillate energy back and forth in the plasma sheet instead of channeling it to the ionosphere.

Boron supercapacitors

DOE PAGES

Zhan, Cheng; Zhang, Pengfei; Dai, Sheng; ...

2016-11-16

Supercapacitors based on the electric double-layer mechanism use porous carbons or graphene as electrodes. To move beyond this paradigm, we propose boron supercapacitors to leverage two-dimensional (2D) boron sheets’ metallicity and low weight. Six 2D boron sheets from both previous theoretical design and experimental growth are chosen as test electrodes. By applying joint density functional theory (JDFT) to the electrode–electrolyte system, we examine how the 2D boron sheets charge up against applied potential. JDFT predicts that these 2D boron sheets exhibit specific capacitance on the order of 400 F/g, about four times that of graphene. As a result, our workmore » suggests that 2D boron sheets are promising electrodes for supercapacitor applications.« less

Boron supercapacitors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhan, Cheng; Zhang, Pengfei; Dai, Sheng

Supercapacitors based on the electric double-layer mechanism use porous carbons or graphene as electrodes. To move beyond this paradigm, we propose boron supercapacitors to leverage two-dimensional (2D) boron sheets’ metallicity and low weight. Six 2D boron sheets from both previous theoretical design and experimental growth are chosen as test electrodes. By applying joint density functional theory (JDFT) to the electrode–electrolyte system, we examine how the 2D boron sheets charge up against applied potential. JDFT predicts that these 2D boron sheets exhibit specific capacitance on the order of 400 F/g, about four times that of graphene. As a result, our workmore » suggests that 2D boron sheets are promising electrodes for supercapacitor applications.« less

Structure and Dynamics of Current Sheets in 3D Magnetic Fields with the X-line

NASA Astrophysics Data System (ADS)

Frank, Anna G.; Bogdanov, S. Yu.; Bugrov, S. G.; Markov, V. S.; Dreiden, G. V.; Ostrovskaya, G. V.

2004-11-01

Experimental results are presented on the structure of current sheets formed in 3D magnetic fields with singular lines of the X-type. Two basic diagnostics were used with the device CS - 3D: two-exposure holographic interferometry and magnetic measurements. Formation of extended current sheets and plasma compression were observed in the presence of the longitudinal magnetic field component aligned with the X-line. Plasma density decreased and the sheet thickness increased with an increase of the longitudinal component. We succeeded to reveal formation of the sheets taking unusual shape, namely tilted and asymmetric sheets, in plasmas with the heavy ions. These current sheets were obviously different from the planar sheets formed in 2D magnetic fields, i.e. without longitudinal component. Analysis of typical plasma parameters made it evident that plasma dynamics and current sheet evolution should be treated on the base of the two-fluid approach. Specifically it is necessary to take into account the Hall currents in the plane perpendicular to the X-line, and the dynamic effects resulting from interaction of the Hall currents and the 3D magnetic field. Supported by RFBR, grant 03-02-17282, and ISTC, project 2098.

The crustal thickness of West Antarctica

NASA Astrophysics Data System (ADS)

Chaput, J.; Aster, R. C.; Huerta, A.; Sun, X.; Lloyd, A.; Wiens, D.; Nyblade, A.; Anandakrishnan, S.; Winberry, J. P.; Wilson, T.

2014-01-01

P-to-S receiver functions (PRFs) from the Polar Earth Observing Network (POLENET) GPS and seismic leg of POLENET spanning West Antarctica and the Transantarctic Mountains deployment of seismographic stations provide new estimates of crustal thickness across West Antarctica, including the West Antarctic Rift System (WARS), Marie Byrd Land (MBL) dome, and the Transantarctic Mountains (TAM) margin. We show that complications arising from ice sheet multiples can be effectively managed and further information concerning low-velocity subglacial sediment thickness may be determined, via top-down utilization of synthetic receiver function models. We combine shallow structure constraints with the response of deeper layers using a regularized Markov chain Monte Carlo methodology to constrain bulk crustal properties. Crustal thickness estimates range from 17.0±4 km at Fishtail Point in the western WARS to 45±5 km at Lonewolf Nunataks in the TAM. Symmetric regions of crustal thinning observed in a transect deployment across the West Antarctic Ice Sheet correlate with deep subice basins, consistent with pure shear crustal necking under past localized extension. Subglacial sediment deposit thicknesses generally correlate with trough/dome expectations, with the thickest inferred subice low-velocity sediment estimated as ˜0.4 km within the Bentley Subglacial Trench. Inverted PRFs from this study and other published crustal estimates are combined with ambient noise surface wave constraints to generate a crustal thickness map for West Antarctica south of 75°S. Observations are consistent with isostatic crustal compensation across the central WARS but indicate significant mantle compensation across the TAM, Ellsworth Block, MBL dome, and eastern and western sectors of thinnest WARS crust, consistent with low density and likely dynamic, low-viscosity high-temperature mantle.

Mathematical modeling of damage in unidirectional composites

NASA Technical Reports Server (NTRS)

Goree, J. G.; Dharani, L. R.; Jones, W. F.

1981-01-01

A review of some approximate analytical models for damaged, fiber reinforced composite materials is presented. Using the classical shear lag stress displacement assumption, solutions are presented for a unidirectional laminate containing a notch, a rectangular cut-out, and a circular hole. The models account for longitudinal matrix yielding and splitting as well as transverse matrix yielding and fiber breakage. The constraining influence of a cover sheet on the unidirectional laminate is also modeled.

Continuous Estimates of Surface Density and Annual Snow Accumulation with Multi-Channel Snow/Firn Penetrating Radar in the Percolation Zone, Western Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Meehan, T.; Marshall, H. P.; Bradford, J.; Hawley, R. L.; Osterberg, E. C.; McCarthy, F.; Lewis, G.; Graeter, K.

2017-12-01

A priority of ice sheet surface mass balance (SMB) prediction is ascertaining the surface density and annual snow accumulation. These forcing data can be supplied into firn compaction models and used to tune Regional Climate Models (RCM). RCMs do not accurately capture subtle changes in the snow accumulation gradient. Additionally, leading RCMs disagree among each other and with accumulation studies in regions of the Greenland Ice Sheet (GrIS) over large distances and temporal scales. RCMs tend to yield inconsistencies over GrIS because of sparse and outdated validation data in the reanalysis pool. Greenland Traverse for Accumulation and Climate Studies (GreenTrACS) implemented multi-channel 500 MHz Radar in multi-offset configuration throughout two traverse campaigns totaling greater than 3500 km along the western percolation zone of GrIS. The multi-channel radar has the capability of continuously estimating snow depth, average density, and annual snow accumulation, expressed at 95% confidence (+-) 0.15 m, (+-) 17 kgm-3, (+-) 0.04 m w.e. respectively, by examination of the primary reflection return from the previous year's summer surface.

Controlling microstructure and texture in magnesium alloy sheet by shear-based deformation processing

NASA Astrophysics Data System (ADS)

Sagapuram, Dinakar

Application of lightweight Mg sheet is limited by its low workability, both in production of sheet (typically by multistep hot and cold-rolling) and forming of sheet into components. Large strain extrusion machining (LSEM), a constrained chip formation process, is used to create Mg alloy AZ31B sheet in a single deformation step. The deformation in LSEM is shown to be intense simple shear that is confined to a narrow zone, which results in significant deformation-induced heating up to ~ 200°C and reduces the need for pre-heating to realize continuous sheet forms. This study focuses on the texture and microstructure development in the sheet processed by LSEM. Interestingly, deep, highly twinned steady-state layer develops in the workpiece subsurface due to the compressive field ahead of the shear zone. The shear deformation, in conjunction with this pre-deformed twinned layer, results in tilted-basal textures in the sheet with basal planes tilted well away from the surface. These textures are significantly different from those in rolled sheet, where basal planes are nearly parallel to the surface. By controlling the strain path, the basal plane inclination from the surface could be varied in the range of 32-53°. B-fiber (basal plane parallel to LSEM shear plane), associated with basal slip, is the major texture component in the sheet. An additional minor C2-fiber component appears above 250°C due to the thermal activation of pyramidal slip. Together with these textures, microstructure ranges from severely cold-worked to (dynamically) recrystallized type, with the corresponding grain sizes varying from ultrafine- (~ 200 nm) to fine- (2 mum) grained. Small-scale limiting dome height (LDH) confirmed enhanced formability (~ 50% increase in LDH) of LSEM sheet over the conventional rolled sheet. Premature, twinning-driven shear fractures are observed in the rolled sheet with the basal texture. In contrast, LSEM sheet with a tilted-basal texture favorably oriented for basal slip exhibits ductile tensile-type fracture. A two-fold increase in ductility is also observed for the LSEM sheet under uniaxial tensile testing without significant changes in the strength. Among texture and microstructure (grain size), texture is shown to be more critical for Mg sheet formability. However, in conjunction with a favorable texture, fine recrystallized microstructure provides for additional enhancement of strain-hardening capacity and formability. In-situ imaging of material flow during uniaxial tensile testing revealed new, interesting flow localization phenomena and fracture behavior. It is shown that the deformation behavior of Mg sheet is highly texture dependent, and also radically different from that of conventional ductile metals both in terms of necking and fracture. The implications of these observations for the LDH test results and formability of Mg sheet, in general, are briefly discussed.

A synthesis of the basal thermal state of the Greenland Ice Sheet

PubMed Central

MacGregor, Joseph A.; Fahnestock, Mark A.; Catania, Ginny A.; Aschwanden, Andy; Clow, Gary D.; Colgan, William T.; Gogineni, S. Prasad; Morlighem, Mathieu; Nowicki, Sophie M. J.; Paden, John D.; Price, Stephen F.; Seroussi, Hélène

2017-01-01

The basal thermal state of an ice sheet (frozen or thawed) is an important control upon its evolution, dynamics and response to external forcings. However, this state can only be observed directly within sparse boreholes or inferred conclusively from the presence of subglacial lakes. Here we synthesize spatially extensive inferences of the basal thermal state of the Greenland Ice Sheet to better constrain this state. Existing inferences include outputs from the eight thermomechanical ice-flow models included in the SeaRISE effort. New remote-sensing inferences of the basal thermal state are derived from Holocene radiostratigraphy, modern surface velocity and MODIS imagery. Both thermomechanical modeling and remote inferences generally agree that the Northeast Greenland Ice Stream and large portions of the southwestern ice-drainage systems are thawed at the bed, whereas the bed beneath the central ice divides, particularly their west-facing slopes, is frozen. Elsewhere, there is poor agreement regarding the basal thermal state. Both models and remote inferences rarely represent the borehole-observed basal thermal state accurately near NorthGRIP and DYE-3. This synthesis identifies a large portion of the Greenland Ice Sheet (about one third by area) where additional observations would most improve knowledge of its overall basal thermal state. PMID:28163988

A synthesis of the basal thermal state of the Greenland Ice Sheet.

PubMed

MacGregor, Joseph A; Fahnestock, Mark A; Catania, Ginny A; Aschwanden, Andy; Clow, Gary D; Colgan, William T; Gogineni, S Prasad; Morlighem, Mathieu; Nowicki, Sophie M J; Paden, John D; Price, Stephen F; Seroussi, Hélène

2016-08-10

The basal thermal state of an ice sheet (frozen or thawed) is an important control upon its evolution, dynamics and response to external forcings. However, this state can only be observed directly within sparse boreholes or inferred conclusively from the presence of subglacial lakes. Here we synthesize spatially extensive inferences of the basal thermal state of the Greenland Ice Sheet to better constrain this state. Existing inferences include outputs from the eight thermomechanical ice-flow models included in the SeaRISE effort. New remote-sensing inferences of the basal thermal state are derived from Holocene radiostratigraphy, modern surface velocity and MODIS imagery. Both thermomechanical modeling and remote inferences generally agree that the Northeast Greenland Ice Stream and large portions of the southwestern ice-drainage systems are thawed at the bed, whereas the bed beneath the central ice divides, particularly their west-facing slopes, is frozen. Elsewhere, there is poor agreement regarding the basal thermal state. Both models and remote inferences rarely represent the borehole-observed basal thermal state accurately near NorthGRIP and DYE-3. This synthesis identifies a large portion of the Greenland Ice Sheet (about one third by area) where additional observations would most improve knowledge of its overall basal thermal state.

A synthesis of the basal thermal state of the Greenland Ice Sheet

USGS Publications Warehouse

MacGregor, Joseph A; Fahnestock, Mark A; Catania, Ginny A; Aschwanden, Andy; Clow, Gary D.; Colgan, William T.; Gogineni, Prasad S.; Morlighem, Mathieu; Nowicki, Sophie M .J.; Paden, John D; Price, Stephen F.; Seroussi, Helene

2016-01-01

The basal thermal state of an ice sheet (frozen or thawed) is an important control upon its evolution, dynamics and response to external forcings. However, this state can only be observed directly within sparse boreholes or inferred conclusively from the presence of subglacial lakes. Here we synthesize spatially extensive inferences of the basal thermal state of the Greenland Ice Sheet to better constrain this state. Existing inferences include outputs from the eight thermomechanical ice-flow models included in the SeaRISE effort. New remote-sensing inferences of the basal thermal state are derived from Holocene radiostratigraphy, modern surface velocity and MODIS imagery. Both thermomechanical modeling and remote inferences generally agree that the Northeast Greenland Ice Stream and large portions of the southwestern ice-drainage systems are thawed at the bed, whereas the bed beneath the central ice divides, particularly their west-facing slopes, is frozen. Elsewhere, there is poor agreement regarding the basal thermal state. Both models and remote inferences rarely represent the borehole-observed basal thermal state accurately near NorthGRIP and DYE-3. This synthesis identifies a large portion of the Greenland Ice Sheet (about one third by area) where additional observations would most improve knowledge of its overall basal thermal state.

Green synthesis of nitrogen-doped graphitic carbon sheets with use of Prunus persica for supercapacitor applications

NASA Astrophysics Data System (ADS)

Atchudan, Raji; Edison, Thomas Nesakumar Jebakumar Immanuel; Perumal, Suguna; Lee, Yong Rok

2017-01-01

Nitrogen-doped graphitic carbon sheets (N-GCSs) were prepared from the extract of unripe Prunus persica fruit by a direct hydrothermal method. The synthesized N-GCSs were examined by high resolution transmission electron microscopy (HRTEM), nitrogen adsorption-desorption isotherms, X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FT-IR) spectroscopy. HRTEM showed that the synthesized carbon sheets were graphitic with lattice fringes and an inter-layer distance of 0.36 nm. Doping with the nitrogen moiety present over the synthesized GCSs was confirmed by XPS, FT-IR spectroscopy, and energy dispersive X-ray spectroscopy elemental mapping. The fruit extract associated with hydrothermal-carbonization method is economical and eco-friendly with a single step process. The resulting carbon sheets could be modified and are promising candidates for nano-electronic applications, including supercapacitors. The synthesized N-GCSs-2 provided a high specific capacitance of 176 F g-1 at a current density of 0.1 A g-1. This electrode material has excellent cyclic stability, even after 2000 cycles of charge-discharge at a current density of 0.5 A g-1.

Metal based gas diffusion layers for enhanced fuel cell performance at high current densities

NASA Astrophysics Data System (ADS)

Hussain, Nabeel; Van Steen, Eric; Tanaka, Shiro; Levecque, Pieter

2017-01-01

The gas diffusion layer strongly influences the performance and durability of polymer electrolyte fuel cells. A major drawback of current carbon fiber based GDLs is the non-controlled variation in porosity resulting in a random micro-structure. Moreover, when subjected to compression these materials show significant reduction in porosity and permeability leading to water management problems and mass transfer losses within the fuel cell. This study investigated the use of uniform perforated metal sheets as GDLs in conjunction with microchannel flowfields. A metal sheet design with a pitch of 110 μm and a hole diameter of 60 μm in combination with an MPL showed superior performance in the high current density region compared to a commercially available carbon paper based GDL in a single cell environment. Fuel cell testing with different oxidants (air, heliox and oxygen) indicate that the metal sheet offers both superior diffusion and reduced flooding in comparison to the carbon based GDL. The presence of the MPL has been found to be critical to the functionality of the metal sheet suggesting that the MPL design may represent an important optimisation parameter for further improvements in performance.

Enabling Colloidal Synthesis of Edge-Oriented MoS2 with Expanded Interlayer Spacing for Enhanced HER Catalysis.

PubMed

Sun, Yugang; Alimohammadi, Farbod; Zhang, Dongtang; Guo, Guangsheng

2017-03-08

By selectively promoting heterogeneous nucleation/growth of MoS 2 on graphene monolayer sheets, edge-oriented (EO) MoS 2 nanosheets with expanded interlayer spacing (∼9.4 Å) supported on reduced graphene oxide (rGO) sheets were successfully synthesized through colloidal chemistry, showing the promise in low-cost and large-scale production. The number and edge length of MoS 2 nanosheets per area of graphene sheets were tuned by controlling the reaction time in the microwave-assisted solvothermal reduction of ammonium tetrathiomolybdate [(NH 4 ) 2 MoS 4 ] in dimethylformamide. The edge-oriented and interlayer-expanded (EO&IE) MoS 2 /rGO exhibited significantly improved catalytic activity toward hydrogen evolution reaction (HER) in terms of larger current density, lower Tafel slope, and lower charge transfer resistance compared to the corresponding interlayer-expanded MoS 2 sheets without edge-oriented geometry, highlighting the importance of synergistic effect between edge-oriented geometry and interlayer expansion on determining HER activity of MoS 2 nanosheets. Quantitative analysis clearly shows the linear dependence of current density on the edge length of MoS 2 nanosheets.

Plane-wave pseudopotential implementation and performance of SCAN meta-GGA exchange-correlation functional for extended systems

NASA Astrophysics Data System (ADS)

Yao, Yi; Kanai, Yosuke

2017-06-01

We present the implementation and performance of the strongly constrained and appropriately normed, SCAN, meta-GGA exchange-correlation (XC) approximation in the planewave-pseudopotential (PW-PP) formalism using the Troullier-Martins pseudopotential scheme. We studied its performance by applying the PW-PP implementation to several practical applications of interest in condensed matter sciences: (a) crystalline silicon and germanium, (b) martensitic phase transition energetics of phosphorene, and (c) a single water molecule physisorption on a graphene sheet. Given the much-improved accuracy over the GGA functionals and its relatively low computational cost compared to hybrid XC functionals, the SCAN functional is highly promising for various practical applications of density functional theory calculations for condensed matter systems. At same time, the SCAN meta-GGA functional appears to require more careful attention to numerical details. The meta-GGA functional shows more significant dependence on the fast Fourier transform grid, which is used for evaluating the XC potential in real space in the PW-PP formalism, than other more conventional GGA functionals do. Additionally, using pseudopotentials that are generated at a different/lower level of XC approximation could introduce noticeable errors in calculating some properties such as phase transition energetics.

THE FREE-FALL TIME OF FINITE SHEETS AND FILAMENTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Toala, Jesus A.; Vazquez-Semadeni, Enrique; Gomez, Gilberto C.

2012-01-10

Molecular clouds often exhibit filamentary or sheet-like shapes. We compute the free-fall time ({tau}{sub ff}) for finite, uniform, self-gravitating circular sheets and filamentary clouds of small but finite thickness, so that their volume density {rho} can still be defined. We find that, for thin sheets, the free-fall time is larger than that of a uniform sphere with the same volume density by a factor proportional to {radical}A, where the aspect ratio A is given by A = R/h, R being the sheet's radius and h is its thickness. For filamentary clouds, the aspect ratio is defined as A=L/R, where Lmore » is the filament's half-length and R is its (small) radius, and the modification factor is more complicated, although in the limit of large A it again reduces to nearly {radical}A. We propose that our result for filamentary shapes naturally explains the ubiquitous configuration of clumps fed by filaments observed in the densest structures of molecular clouds. Also, the longer free-fall times for non-spherical geometries in general may contribute toward partially alleviating the 'star formation conundrum', namely, the star formation rate in the Galaxy appears to be proceeding in a timescale much larger than the total molecular mass in the Galaxy divided by its typical free-fall time. If molecular clouds are in general formed by thin sheets and long filaments, then their relevant free-fall time may have been systematically underestimated, possibly by factors of up to one order of magnitude.« less

Controlled cell morphology and liver-specific function of engineered primary hepatocytes by fibroblast layer cell densities.

PubMed

Sakai, Yusuke; Koike, Makiko; Kawahara, Daisuke; Hasegawa, Hideko; Murai, Tomomi; Yamanouchi, Kosho; Soyama, Akihiko; Hidaka, Masaaki; Takatsuki, Mitsuhisa; Fujita, Fumihiko; Kuroki, Tamotsu; Eguchi, Susumu

2018-03-05

Engineered primary hepatocytes, including co-cultured hepatocyte sheets, are an attractive to basic scientific and clinical researchers because they maintain liver-specific functions, have reconstructed cell polarity, and have high transplantation efficiency. However, co-culture conditions regarding engineered primary hepatocytes were suboptimal in promoting these advantages. Here we report that the hepatocyte morphology and liver-specific function levels are controlled by the normal human diploid fibroblast (TIG-118 cell) layer cell density. Primary rat hepatocytes were plated onto TIG-118 cells, previously plated 3 days before at 1.04, 5.21, and 26.1×10 3  cells/cm 2 . Hepatocytes plated onto lower TIG-118 cell densities expanded better during the early culture period. The hepatocytes gathered as colonies and only exhibited small adhesion areas because of the pushing force from proliferating TIG-118 cells. The smaller areas of each hepatocyte result in the development of bile canaliculi. The highest density of TIG-118 cells downregulated albumin synthesis activity of hepatocytes. The hepatocytes may have undergone apoptosis associated with high TGF-β1 concentration and necrosis due to a lack of oxygen. These occurrences were supported by apoptotic chromatin condensation and high expression of both proteins HIF-1a and HIF-1b. Three types of engineered hepatocyte/fibroblast sheets comprising different TIG-118 cell densities were harvested after 4 days of hepatocyte culture and showed a complete cell sheet format without any holes. Hepatocyte morphology and liver-specific function levels are controlled by TIG-118 cell density, which helps to design better engineered hepatocytes for future applications such as in vitro cell-based assays and transplantable hepatocyte tissues. Copyright © 2018 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

Measuring Alignments between Galaxies and the Cosmic Web at z ˜ 2-3 Using IGM Tomography

NASA Astrophysics Data System (ADS)

Krolewski, Alex; Lee, Khee-Gan; Lukić, Zarija; White, Martin

2017-03-01

Many galaxy formation models predict alignments between galaxy spin and the cosmic web (I.e., directions of filaments and sheets), leading to an intrinsic alignment between galaxies that creates a systematic error in weak-lensing measurements. These effects are often predicted to be stronger at high redshifts (z ≳ 1) that are inaccessible to massive galaxy surveys on foreseeable instrumentation, but IGM tomography of the Lyα forest from closely spaced quasars and galaxies is starting to measure the z ˜ 2-3 cosmic web with requisite fidelity. Using mock surveys from hydrodynamical simulations, we examine the utility of this technique, in conjunction with coeval galaxy samples, to measure alignment between galaxies and the cosmic web at z ˜ 2.5. We show that IGM tomography surveys with ≲5 h -1 Mpc sightline spacing can accurately recover the eigenvectors of the tidal tensor, which we use to define the directions of the cosmic web. For galaxy spins and shapes, we use a model parameterized by the alignment strength, {{Δ }}< \\cos θ > , with respect to the tidal tensor eigenvectors from the underlying density field, and also consider observational effects such as errors in the galaxy position angle, inclination, and redshift. Measurements using the upcoming ˜1 deg2 CLAMATO tomographic survey and 600 coeval zCOSMOS-Deep galaxies should place 3σ limits on extreme alignment models with {{Δ }}< \\cos θ > ˜ 0.1, but much larger surveys encompassing >10,000 galaxies, such as Subaru PFS, will be required to constrain models with {{Δ }}< \\cos θ > ˜ 0.03. These measurements will constrain models of galaxy-cosmic web alignment and test tidal torque theory at z ˜ 2, improving our understanding of the physics of intrinsic alignments.

Measuring Alignments between Galaxies and the Cosmic Web at z ~ 2–3 Using IGM Tomography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krolewski, Alex; Lee, Khee-Gan; Luki?, Zarija

Many galaxy formation models predict alignments between galaxy spin and the cosmic web (i.e., directions of filaments and sheets), leading to an intrinsic alignment between galaxies that creates a systematic error in weak-lensing measurements. These effects are often predicted to be stronger at high redshifts (z ≳ 1) that are inaccessible to massive galaxy surveys on foreseeable instrumentation, but IGM tomography of the Lyα forest from closely spaced quasars and galaxies is starting to measure the z ~ 2-3 cosmic web with requisite fidelity. Using mock surveys from hydrodynamical simulations, we examine the utility of this technique, in conjunction withmore » coeval galaxy samples, to measure alignment between galaxies and the cosmic web at z ~ 2.5. We show that IGM tomography surveys with ≲ 5 h -1 Mpc sightline spacing can accurately recover the eigenvectors of the tidal tensor, which we use to define the directions of the cosmic web. For galaxy spins and shapes, we use a model parameterized by the alignment strength, Δ (cos θ), with respect to the tidal tensor eigenvectors from the underlying density field, and also consider observational effects such as errors in the galaxy position angle, inclination, and redshift. Measurements using the upcoming ~ 1 deg 2 CLAMATO tomographic survey and 600 coeval zCOSMOS-Deep galaxies should place 3σ limits on extreme alignment models with Δ (cos θ) ~ 0.1, but much larger surveys encompassing > 10,000 galaxies, such as Subaru PFS, will be required to constrain models with Δ (cos θ) ~ 0.3. These measurements will constrain models of galaxy-cosmic web alignment and test tidal torque theory at z ~ 2, improving our understanding of the physics of intrinsic alignments.« less

Measuring Alignments between Galaxies and the Cosmic Web at z ~ 2–3 Using IGM Tomography

DOE PAGES

Krolewski, Alex; Lee, Khee-Gan; Luki?, Zarija; ...

2017-02-28

Many galaxy formation models predict alignments between galaxy spin and the cosmic web (i.e., directions of filaments and sheets), leading to an intrinsic alignment between galaxies that creates a systematic error in weak-lensing measurements. These effects are often predicted to be stronger at high redshifts (z ≳ 1) that are inaccessible to massive galaxy surveys on foreseeable instrumentation, but IGM tomography of the Lyα forest from closely spaced quasars and galaxies is starting to measure the z ~ 2-3 cosmic web with requisite fidelity. Using mock surveys from hydrodynamical simulations, we examine the utility of this technique, in conjunction withmore » coeval galaxy samples, to measure alignment between galaxies and the cosmic web at z ~ 2.5. We show that IGM tomography surveys with ≲ 5 h -1 Mpc sightline spacing can accurately recover the eigenvectors of the tidal tensor, which we use to define the directions of the cosmic web. For galaxy spins and shapes, we use a model parameterized by the alignment strength, Δ (cos θ), with respect to the tidal tensor eigenvectors from the underlying density field, and also consider observational effects such as errors in the galaxy position angle, inclination, and redshift. Measurements using the upcoming ~ 1 deg 2 CLAMATO tomographic survey and 600 coeval zCOSMOS-Deep galaxies should place 3σ limits on extreme alignment models with Δ (cos θ) ~ 0.1, but much larger surveys encompassing > 10,000 galaxies, such as Subaru PFS, will be required to constrain models with Δ (cos θ) ~ 0.3. These measurements will constrain models of galaxy-cosmic web alignment and test tidal torque theory at z ~ 2, improving our understanding of the physics of intrinsic alignments.« less

High-carrier-density phase in LaTiO3/SrTiO3 superlattices

NASA Astrophysics Data System (ADS)

Park, Se Young; Rabe, Karin; Millis, Andrew

2015-03-01

We investigate superlattices composed of alternating layers of Mott insulating LaTiO3 and band insulating SrTiO3 from first principles, using the density functional theory plus U (DFT+U) method. For values of U above a critical threshold, we find that melting of the Mott-insulating phase can extend from the interface into the LaTiO3 layer, resulting in a sheet carrier density exceeding the density of 0.5 electrons per in-plane unit cell found in previous studies. The critical U for the melting transition is larger than the critical Coulomb correlation required for the insulating LaTiO3, suggesting the existence of a high sheet carrier density phase in LaTiO3/SrTiO3 superlattices. The effects of in-plane strain and varying layer thickness on the melting transition are discussed. For insulating superlattices, we study the strain and thickness dependence of the polarization and its relation to near-interface local atomic distortions. Support: DOE ER 046169, ONR N00014-11-0666.

Ice streaming in western Scotland and the deglaciation of the Hebrides Shelf and Firth of Lorn

NASA Astrophysics Data System (ADS)

Arosio, Riccardo; Howe, John; O'Cofaigh, Colm; Crocket, Kirsty

2014-05-01

Previously, numerous studies have been undertaken both onshore and offshore to decipher the morphological and sedimentological record in order to better constrain the limits and duration of the British-Irish Ice Sheet (BIIS) (Ballantyne et al. 2009, Bradwell et al. 2008b, Clark et al. 2011, Dunlop et al. 2010, Howe et al. 2012, O'Cofaigh et al., 2012). Late glacial ice sheet dynamics have been revealed to be far more rapid and responsive to climatic amelioration than had previously been considered. Notable in this debate has been the evidence that has been obtained in the inshore and, to a lesser extent, offshore on the UK continental shelf. Here new geomorphological data, principally multibeam echo sounder (MBES) data has provided imagery of previously unseen features interpreted as being glacial in origin. In the wake of these new discoveries this projects aims to investigate the extent, timing, growth and final disintegration of the BIIS across Western Scotland. This area of particular interest for the development of the glaciated North Atlantic margin has been generally neglected in past studies, especially across the mid-outer shelf, which constitutes a missing part in the jigsaw of the reconstructed BIIS during the last ~20.000yrs. We aim to mainly focus on geomorphological analyses of MBES data collected in the Firth of Lorn and Sea of Hebrides; a study of features as moraines, glacial lineations and drumlins will provide important clues on the dynamics and maximum extension of the sheet. Subsequently we will examine the geometry and composition of the shelf sediment infill, aiming to constrain the influence of ice retreat on depositional environments using multi-element geochemical (Pb-isotopes ratios, 14C and OSL dating) and sedimentological techniques. Such an investigation will also give retrospective information on the sources for these sediments, hence more indications on ice configuration. Ultimately we aim to provide a model of deglaciation for the western sector of the BIIS. Keywords: British-Irish Ice Sheet, NW Scotland, glacial bedforms, geochronology References Ballantyne, C.K., Schnabel, C. & Xu, S. 2009. Readvance of the last British Ice Sheet during Greenland Interstade (GI-1): the Wester Ross Readvance, NW Scotland. Quaternary Science Reviews, 28, 783-789 Bradwell, T., Fabel, D., Stoker, M., Mathers, H., McHargue, L., Howe, J., 2008b. Ice caps existed throughout the Late glacial interstadial in northern Scotland. Journal of Quaternary Science 23, 401-407. Clark, C.D., Hughes, A.L.C., Greenwood, S.L., Jordan, C., Sejrup, H.P. 2012. Pattern and timing of retreat of the last British-Irish Ice Sheet. Quaternary Science Reviews. Dunlop, P., Shannon, R., McCabe, M., Quinn, R., Doyle, E. 2010. Marine geophysical evidence for ice sheet extension and recession on the Malin Shelf: New evidence for the western limits of the British-Irish Ice Sheet. Marine Geology, 276: 86-99. Howe, J. A., Dove, D., Bradwell, T. & Gaferia, J. 2012. Submarine geomorphology and glacial history of the Sea of the Hebrides, UK. Marine Geology 315-318, 64-78 O' Cofaigh, C., Dunlop, P. Benetti, S., 2012. Marine geophysical evidence for Late Pleistocene ice sheet extent and recession off northwest Ireland, Quaternary Science Reviews. In press.

Collisionless distribution function for the relativistic force-free Harris sheet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stark, C. R.; Neukirch, T.

A self-consistent collisionless distribution function for the relativistic analogue of the force-free Harris sheet is presented. This distribution function is the relativistic generalization of the distribution function for the non-relativistic collisionless force-free Harris sheet recently found by Harrison and Neukirch [Phys. Rev. Lett. 102, 135003 (2009)], as it has the same dependence on the particle energy and canonical momenta. We present a detailed calculation which shows that the proposed distribution function generates the required current density profile (and thus magnetic field profile) in a frame of reference in which the electric potential vanishes identically. The connection between the parameters ofmore » the distribution function and the macroscopic parameters such as the current sheet thickness is discussed.« less

Predicting the structural and electronic properties of two-dimensional single layer boron nitride sheets

NASA Astrophysics Data System (ADS)

Li, Xiao-Dong; Cheng, Xin-Lu

2018-02-01

Three two-dimensional (2D) single layer boron nitride sheets have been predicted based on the first-principles calculations. These 2D boron nitride sheets are comprised of equivalent boron atoms and nitride atoms with sp2 and sp bond hybridization. The geometry optimization reflects that they all possess stable planar crystal structures with the space group P 6 bar 2 m (D3h3) symmetry. The charge density distribution manifests that the B-N bonds in these boron nitride sheets are covalent in nature but with ionic characteristics. The tunable band gaps indicate their potential applications in nanoscale electronic and optoelectronic devices by changing the length of sp-bonded Bsbnd N linkages.

Mass-production of highly-crystalline few-layer graphene sheets by arc discharge in various H2-inert gas mixtures

NASA Astrophysics Data System (ADS)

Chen, Yani; Zhao, Hongbin; Sheng, Leimei; Yu, Liming; An, Kang; Xu, Jiaqiang; Ando, Yoshinori; Zhao, Xinluo

2012-06-01

Large-scale production of graphene sheets has been achieved by direct current arc discharge evaporation of pure graphite electrodes in various H2-inert gas mixtures. The as-prepared few-layer graphene sheets have high purity, high crystallinity and high oxidation resistance temperature. Their electrochemical characteristics have been evaluated in coin-type cells versus metallic lithium. The first cell discharge capacity reached 1332 mA h g-1 at a current density of 50 mA g-1. After 350 cycles, the discharge capacity still remained at 323 mA h g-1. Graphene sheets produced by this method should be a promising candidate for the electrode material of lithium-ion batteries.

Theoretical predictions on the electronic structure and charge carrier mobility in 2D Phosphorus sheets

PubMed Central

Xiao, Jin; Long, Mengqiu; Zhang, Xiaojiao; Ouyang, Jun; Xu, Hui; Gao, Yongli

2015-01-01

We have investigated the electronic structure and carrier mobility of four types of phosphorous monolayer sheet (α-P, β-P,γ-P and δ-P) using density functional theory combined with Boltzmann transport method and relaxation time approximation. It is shown that α-P, β-P and γ-P are indirect gap semiconductors, while δ-P is a direct one. All four sheets have ultrahigh carrier mobility and show anisotropy in-plane. The highest mobility value is ~3 × 105 cm2V−1s−1, which is comparable to that of graphene. Because of the huge difference between the hole and electron mobilities, α-P, γ-P and δ-P sheets can be considered as n-type semiconductors, and β-P sheet can be considered as a p-type semiconductor. Our results suggest that phosphorous monolayer sheets can be considered as a new type of two dimensional materials for applications in optoelectronics and nanoelectronic devices. PMID:26035176

Damage Tolerance of Sandwich Plates with Debonded Face Sheets

NASA Technical Reports Server (NTRS)

Avery, John L., III; Sankar, Bhavani V.

1998-01-01

Axial compression tests were performed on debonded sandwich composites made of graphite/epoxy face-sheets and aramid fiber honeycomb core. The sandwich beams were manufactured using a vacuum baccrin2 process. The face-sheet and the sandwich beam were co-cured. Delamination between one of the face sheets and the core was introduced by using a Teflon layer during the curing process. Axial compression tests were performed to determine the ultimate load carrying capacity of the debonded beams. Flatwise tension tests and Double Cantilever Beam tests were performed to determine. respectively, the strength and fracture toughness of the face-sheet/core interface. From the test results semi-empirical formulas were derived for the fracture toughness and ultimate compressive load carrying capacity in terms of the core density. core thickness. face-sheet thickness and debond length. Four different failure modes and their relation to the structural properties were identified. Linear buckling analysis was found to be inadequate in predicting the compressive load carrying capacity of the debonded sandwich composites.

Effects of electron pressure anisotropy on current sheet configuration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Artemyev, A. V., E-mail: aartemyev@igpp.ucla.edu; Angelopoulos, V.; Runov, A.

2016-09-15

Recent spacecraft observations in the Earth's magnetosphere have demonstrated that the magnetotail current sheet can be supported by currents of anisotropic electron population. Strong electron currents are responsible for the formation of very thin (intense) current sheets playing the crucial role in stability of the Earth's magnetotail. We explore the properties of such thin current sheets with hot isotropic ions and cold anisotropic electrons. Decoupling of the motions of ions and electrons results in the generation of a polarization electric field. The distribution of the corresponding scalar potential is derived from the electron pressure balance and the quasi-neutrality condition. Wemore » find that electron pressure anisotropy is partially balanced by a field-aligned component of this polarization electric field. We propose a 2D model that describes a thin current sheet supported by currents of anisotropic electrons embedded in an ion-dominated current sheet. Current density profiles in our model agree well with THEMIS observations in the Earth's magnetotail.« less

Geometry of thin liquid sheet flows

NASA Technical Reports Server (NTRS)

Chubb, Donald L.; Calfo, Frederick D.; Mcconley, Marc W.; Mcmaster, Matthew S.; Afjeh, Abdollah A.

1994-01-01

Incompresible, thin sheet flows have been of research interest for many years. Those studies were mainly concerned with the stability of the flow in a surrounding gas. Squire was the first to carry out a linear, invicid stability analysis of sheet flow in air and compare the results with experiment. Dombrowski and Fraser did an experimental study of the disintegration of sheet flows using several viscous liquids. They also detected the formulation of holes in their sheet flows. Hagerty and Shea carried out an inviscid stability analysis and calculated growth rates with experimental values. They compared their calculated growth rates with experimental values. Taylor studied extensively the stability of thin liquid sheets both theoretically and experimentally. He showed that thin sheets in a vacuum are stable. Brown experimentally investigated thin liquid sheet flows as a method of application of thin films. Clark and Dumbrowski carried out second-order stability analysis for invicid sheet flows. Lin introduced viscosity into the linear stability analysis of thin sheet flows in a vacuum. Mansour and Chigier conducted an experimental study of the breakup of a sheet flow surrounded by high-speed air. Lin et al. did a linear stability analysis that included viscosity and a surrounding gas. Rangel and Sirignano carried out both a linear and nonlinear invisid stability analysis that applies for any density ratio between the sheet liquid and the surrounding gas. Now there is renewed interest in sheet flows because of their possible application as low mass radiating surfaces. The objective of this study is to investigate the fluid dynamics of sheet flows that are of interest for a space radiator system. Analytical expressions that govern the sheet geometry are compared with experimental results. Since a space radiator will operate in a vacuum, the analysis does not include any drag force on the sheet flow.

Efficient Flowline Simulations of Ice Shelf-Ocean Interactions: Sensitivity Studies with a Fully Coupled Model

NASA Technical Reports Server (NTRS)

Walker, Ryan Thomas; Holland, David; Parizek, Byron R.; Alley, Richard B.; Nowicki, Sophie M. J.; Jenkins, Adrian

2013-01-01

Thermodynamic flowline and plume models for the ice shelf-ocean system simplify the ice and ocean dynamics sufficiently to allow extensive exploration of parameters affecting ice-sheet stability while including key physical processes. Comparison between geophysically and laboratory-based treatments of ice-ocean interface thermodynamics shows reasonable agreement between calculated melt rates, except where steep basal slopes and relatively high ocean temperatures are present. Results are especially sensitive to the poorly known drag coefficient, highlighting the need for additional field experiments to constrain its value. These experiments also suggest that if the ice-ocean interface near the grounding line is steeper than some threshold, further steepening of the slope may drive higher entrainment that limits buoyancy, slowing the plume and reducing melting; if confirmed, this will provide a stabilizing feedback on ice sheets under some circumstances.

Hypervelocity impact shield

NASA Technical Reports Server (NTRS)

Cour-Palais, Burton G. (Inventor); Crews, Jeanne Lee (Inventor)

1991-01-01

A hypervelocity impact shield and method for protecting a wall structure, such as a spacecraft wall, from impact with particles of debris having densities of about 2.7 g/cu cm and impact velocities up to 16 km/s are disclosed. The shield comprises a stack of ultra thin sheets of impactor disrupting material supported and arranged by support means in spaced relationship to one another and mounted to cover the wall in a position for intercepting the particles. The sheets are of a number and spacing such that the impacting particle and the resulting particulates of the impacting particle and sheet material are successively impact-shocked to a thermal state of total melt and/or vaporization to a degree as precludes perforation of the wall. The ratio of individual sheet thickness to the theoretical diameter of particles of debris which may be of spherical form is in the range of 0.03 to 0.05. The spacing between adjacent sheets is such that the debris cloud plume of liquid and vapor resulting from an impacting particle penetrating a sheet does not puncture the next adjacent sheet prior to the arrival thereat of fragment particulates of sheet material and the debris particle produced by a previous impact.

Fusion of Hard and Soft Information in Nonparametric Density Estimation

DTIC Science & Technology

2015-06-10

and stochastic optimization models, in analysis of simulation output, and when instantiating probability models. We adopt a constrained maximum...particular, density estimation is needed for generation of input densities to simulation and stochastic optimization models, in analysis of simulation output...an essential step in simulation analysis and stochastic optimization is the generation of probability densities for input random variables; see for

Potential-field sounding using Euler's homogeneity equation and Zidarov bubbling

USGS Publications Warehouse

Cordell, Lindrith

1994-01-01

Potential-field (gravity) data are transformed into a physical-property (density) distribution in a lower half-space, constrained solely by assumed upper bounds on physical-property contrast and data error. A two-step process is involved. The data are first transformed to an equivalent set of line (2-D case) or point (3-D case) sources, using Euler's homogeneity equation evaluated iteratively on the largest residual data value. Then, mass is converted to a volume-density product, constrained to an upper density bound, by 'bubbling,' which exploits circular or radial expansion to redistribute density without changing the associated gravity field. The method can be developed for gravity or magnetic data in two or three dimensions. The results can provide a beginning for interpretation of potential-field data where few independent constraints exist, or more likely, can be used to develop models and confirm or extend interpretation of other geophysical data sets.

Experimental Method for Characterizing Electrical Steel Sheets in the Normal Direction

PubMed Central

Hihat, Nabil; Lecointe, Jean Philippe; Duchesne, Stephane; Napieralska, Ewa; Belgrand, Thierry

2010-01-01

This paper proposes an experimental method to characterise magnetic laminations in the direction normal to the sheet plane. The principle, which is based on a static excitation to avoid planar eddy currents, is explained and specific test benches are proposed. Measurements of the flux density are made with a sensor moving in and out of an air-gap. A simple analytical model is derived in order to determine the permeability in the normal direction. The experimental results for grain oriented steel sheets are presented and a comparison is provided with values obtained from literature. PMID:22163394

First principles study of electronic properties, interband transitions and electron energy loss of α-graphyne

NASA Astrophysics Data System (ADS)

Behzad, Somayeh

2016-04-01

The electronic and optical properties of α-graphyne sheet are investigated by using density functional theory. The results confirm that α-graphyne sheet is a zero-gap semimetal. The optical properties of the α-graphyne sheet such as dielectric function, refraction index, electron energy loss function, reflectivity, absorption coefficient and extinction index are calculated for both parallel and perpendicular electric field polarizations. The optical spectra are strongly anisotropic along these two polarizations. For (E ∥ x), absorption edge is at 0 eV, while there is no absorption below 8 eV for (E ∥ z).

Effects of mechanical strain on the performance of germanene sheets: Strength, failure behavior, and electronic structure

NASA Astrophysics Data System (ADS)

Ding, Ning; Wang, Huan; Liu, Long; Guo, Weimin; Chen, Xiangfeng; Wu, Chi-Man Lawrence

2018-02-01

As a two-dimensional material with a low-buckling structure, germanene has attracted considerable interest because of its excellent physical properties, such as massless Dirac fermions and quantum spin Hall effect. The mechanical characteristics of germanene are of the utmost importance when one is assessing its viability for nanodevices, especially for ones with defects. In this work, the stabilities, mechanical properties, and changes in electronic properties under mechanical strain for both pristine and defective germanene sheets were studied and analyzed with use of density functional theory. The mechanical properties of defect-free germanene exhibited obvious anisotropy along different directions. The mechanical properties of germanene sheets exhibited high sensitivity to the defect parameters, such as the linear density of vacancies, the width of the cracks, and the inflection angles caused by the grain boundaries. In addition, the applied mechanical strain changed the electronic properties of germanene to a large extent. The information obtained will be useful for the understanding and potential application of germanene.

Density functional theory study of β-hairpins in antiparallel β-sheets, a new classification based upon H-bond topology.

PubMed

Roy, Dipankar; Pohl, Gabor; Ali-Torres, Jorge; Marianski, Mateusz; Dannenberg, J J

2012-07-10

We present a new classification of β-turns specific to antiparallel β-sheets based upon the topology of H-bond formation. This classification results from ONIOM calculations using B3LYP/D95** density functional theory and AM1 semiempirical calculations as the high and low levels, respectively. We chose acetyl(Ala)(6)NH(2) as a model system as it is the simplest all-alanine system that can form all the H-bonds required for a β-turn in a sheet. Of the 10 different conformations we have found, the most stable structures have C(7) cyclic H-bonds in place of the C(10) interactions specified in the classic definition. Also, the chiralities specified for residues i + 1 and i + 2 in the classic definition disappear when the structures are optimized using our techniques, as the energetic differences among the four diastereomers of each structure are not substantial for 8 of the 10 conformations.

Failure Maps for Rectangular 17-4PH Stainless Steel Sandwiched Foam Panels

NASA Technical Reports Server (NTRS)

Raj, S. V.; Ghosn, L. J.

2007-01-01

A new and innovative concept is proposed for designing lightweight fan blades for aircraft engines using commercially available 17-4PH precipitation hardened stainless steel. Rotating fan blades in aircraft engines experience a complex loading state consisting of combinations of centrifugal, distributed pressure and torsional loads. Theoretical failure plastic collapse maps, showing plots of the foam relative density versus face sheet thickness, t, normalized by the fan blade span length, L, have been generated for rectangular 17-4PH sandwiched foam panels under these three loading modes assuming three failure plastic collapse modes. These maps show that the 17-4PH sandwiched foam panels can fail by either the yielding of the face sheets, yielding of the foam core or wrinkling of the face sheets depending on foam relative density, the magnitude of t/L and the loading mode. The design envelop of a generic fan blade is superimposed on the maps to provide valuable insights on the probable failure modes in a sandwiched foam fan blade.

Heating and cooling of the earth's plasma sheet

NASA Technical Reports Server (NTRS)

Goertz, C. K.

1990-01-01

Magnetic-field models based on pressure equilibrium in the quiet magnetotail require nonadiabatic cooling of the plasma as it convects inward or a decrease of the flux tube content. Recent in situ observations of plasma density and temperature indicate that, during quiet convection, the flux tube content may actually increase. Thus the plasma must be cooled during quiet times. The earth plasma sheet is generally significantly hotter after the expansion phase of a substorm than before the plasma sheet thinning begins and cools during the recovery phase. Heating mechanisms such as reconnection, current sheet acceleration, plasma expansion, and resonant absorption of surface waves are discussed. It seems that all mechanisms are active, albeit in different regions of the plasma sheet. Near-earth tail signatures of substorms require local heating as well as a decrease of the flux tube content. It is shown that the resonant absorption of surface waves can provide both.

Constrained Kalman Filtering Via Density Function Truncation for Turbofan Engine Health Estimation

NASA Technical Reports Server (NTRS)

Simon, Dan; Simon, Donald L.

2006-01-01

Kalman filters are often used to estimate the state variables of a dynamic system. However, in the application of Kalman filters some known signal information is often either ignored or dealt with heuristically. For instance, state variable constraints (which may be based on physical considerations) are often neglected because they do not fit easily into the structure of the Kalman filter. This paper develops an analytic method of incorporating state variable inequality constraints in the Kalman filter. The resultant filter truncates the PDF (probability density function) of the Kalman filter estimate at the known constraints and then computes the constrained filter estimate as the mean of the truncated PDF. The incorporation of state variable constraints increases the computational effort of the filter but significantly improves its estimation accuracy. The improvement is demonstrated via simulation results obtained from a turbofan engine model. The turbofan engine model contains 3 state variables, 11 measurements, and 10 component health parameters. It is also shown that the truncated Kalman filter may be a more accurate way of incorporating inequality constraints than other constrained filters (e.g., the projection approach to constrained filtering).

Theoretical calculation of reorganization energy for electron self-exchange reaction by constrained density functional theory and constrained equilibrium thermodynamics.

PubMed

Ren, Hai-Sheng; Ming, Mei-Jun; Ma, Jian-Yi; Li, Xiang-Yuan

2013-08-22

Within the framework of constrained density functional theory (CDFT), the diabatic or charge localized states of electron transfer (ET) have been constructed. Based on the diabatic states, inner reorganization energy λin has been directly calculated. For solvent reorganization energy λs, a novel and reasonable nonequilibrium solvation model is established by introducing a constrained equilibrium manipulation, and a new expression of λs has been formulated. It is found that λs is actually the cost of maintaining the residual polarization, which equilibrates with the extra electric field. On the basis of diabatic states constructed by CDFT, a numerical algorithm using the new formulations with the dielectric polarizable continuum model (D-PCM) has been implemented. As typical test cases, self-exchange ET reactions between tetracyanoethylene (TCNE) and tetrathiafulvalene (TTF) and their corresponding ionic radicals in acetonitrile are investigated. The calculated reorganization energies λ are 7293 cm(-1) for TCNE/TCNE(-) and 5939 cm(-1) for TTF/TTF(+) reactions, agreeing well with available experimental results of 7250 cm(-1) and 5810 cm(-1), respectively.

Observationally constrained projections of Antarctic ice sheet instability

NASA Astrophysics Data System (ADS)

Edwards, Tamsin; Ritz, Catherine; Durand, Gael; Payne, Anthony; Peyaud, Vincent; Hindmarsh, Richard

2015-04-01

Large parts of the Antarctic ice sheet lie on bedrock below sea level and may be vulnerable to a positive feedback known as Marine Ice Sheet Instability (MISI), a self-sustaining retreat of the grounding line triggered by oceanic or atmospheric changes. There is growing evidence MISI may be underway throughout the Amundsen Sea Embayment (ASE) of West Antarctica, induced by circulation of warm Circumpolar Deep Water. If this retreat is sustained the region could contribute up to 1-2 m to global mean sea level, and if triggered in other areas the potential contribution to sea level on centennial to millennial timescales could be two to three times greater. However, physically plausible projections of Antarctic MISI are challenging: numerical ice sheet models are too low in spatial resolution to resolve grounding line processes or else too computationally expensive to assess modelling uncertainties, and no dynamical models exist of the ocean-atmosphere-ice sheet system. Furthermore, previous numerical ice sheet model projections for Antarctica have not been calibrated with observations, which can reduce uncertainties. Here we estimate the probability of dynamic mass loss in the event of MISI under a medium climate scenario, assessing 16 modelling uncertainties and calibrating the projections with observed mass losses in the ASE from 1992-2011. We project losses of up to 30 cm sea level equivalent (SLE) by 2100 and 72 cm SLE by 2200 (95% credibility interval: CI). Our results are substantially lower than previous estimates. The ASE sustains substantial losses, 83% of the continental total by 2100 and 67% by 2200 (95% CI), but in other regions losses are limited by ice dynamical theory, observations, or a lack of projected triggers.

Interactions of ice sheet evolution, sea level and GIA in a region of complex Earth structure

NASA Astrophysics Data System (ADS)

Gomez, N. A.; Chan, N. H.; Latychev, K.; Pollard, D.; Powell, E. M.

2017-12-01

Constraining glacial isostatic adjustment (GIA) is challenging in Antarctica, where the solid Earth deformation, sea level changes and ice dynamics are strongly linked on all timescales. Furthermore, Earth structure beneath the Antarctic Ice Sheet is characterized by significant lateral variability. A stable, thick craton exists in the east, while the west is underlain by a large continental rift system, with a relatively thin lithosphere and hot, low viscosity asthenosphere, as indicated by high resolution seismic tomography. This implies that in parts of the West Antarctic, the Earth's mantle may respond to surface loading on shorter than average (centennial, or even decadal) timescales. Accounting for lateral variations in viscoelastic Earth structure alters the timing and geometry of load-induced Earth deformation, which in turn impacts the timing and extent of the ice-sheet retreat via a sea-level feedback, as well as predictions of relative sea-level change and GIA. We explore the impact of laterally varying Earth structure on ice-sheet evolution, sea level change and Earth deformation in the Antarctic region since the Last Glacial Maximum using a newly developed coupled ice sheet - sea level model that incorporates 3-D variations in lithospheric thickness and mantle viscosity derived from recent seismic tomographic datasets. Our results focus on identifying the regions and time periods in which the incorporation of 3-D Earth structure is critical for accurate predictions of ice sheet evolution and interpretation of geological and geodetic observations. We also investigate the sensitivity to the regional Earth structure of the relative contributions to modern GIA predictions of Last Deglacial and more recent Holocene ice cover changes.

Facts about...Blood Cholesterol. Revised.

ERIC Educational Resources Information Center

National Heart, Lung, and Blood Inst. (DHHS/NIH), Bethesda, MD.

This fact sheet on blood cholesterol examines the connection between cholesterol and heart disease, lists risk factors for heart disease that can and cannot be controlled, points out who can benefit from lowering blood cholesterol, distinguishes between blood and dietary cholesterol, describes low density lipoprotein and high density lipoprotein…

Extracting electron transfer coupling elements from constrained density functional theory

NASA Astrophysics Data System (ADS)

Wu, Qin; Van Voorhis, Troy

2006-10-01

Constrained density functional theory (DFT) is a useful tool for studying electron transfer (ET) reactions. It can straightforwardly construct the charge-localized diabatic states and give a direct measure of the inner-sphere reorganization energy. In this work, a method is presented for calculating the electronic coupling matrix element (Hab) based on constrained DFT. This method completely avoids the use of ground-state DFT energies because they are known to irrationally predict fractional electron transfer in many cases. Instead it makes use of the constrained DFT energies and the Kohn-Sham wave functions for the diabatic states in a careful way. Test calculations on the Zn2+ and the benzene-Cl atom systems show that the new prescription yields reasonable agreement with the standard generalized Mulliken-Hush method. We then proceed to produce the diabatic and adiabatic potential energy curves along the reaction pathway for intervalence ET in the tetrathiafulvalene-diquinone (Q-TTF-Q) anion. While the unconstrained DFT curve has no reaction barrier and gives Hab≈17kcal /mol, which qualitatively disagrees with experimental results, the Hab calculated from constrained DFT is about 3kcal /mol and the generated ground state has a barrier height of 1.70kcal/mol, successfully predicting (Q-TTF-Q)- to be a class II mixed-valence compound.

Resistive switching near electrode interfaces: Estimations by a current model

NASA Astrophysics Data System (ADS)

Schroeder, Herbert; Zurhelle, Alexander; Stemmer, Stefanie; Marchewka, Astrid; Waser, Rainer

2013-02-01

The growing resistive switching database is accompanied by many detailed mechanisms which often are pure hypotheses. Some of these suggested models can be verified by checking their predictions with the benchmarks of future memory cells. The valence change memory model assumes that the different resistances in ON and OFF states are made by changing the defect density profiles in a sheet near one working electrode during switching. The resulting different READ current densities in ON and OFF states were calculated by using an appropriate simulation model with variation of several important defect and material parameters of the metal/insulator (oxide)/metal thin film stack such as defect density and its profile change in density and thickness, height of the interface barrier, dielectric permittivity, applied voltage. The results were compared to the benchmarks and some memory windows of the varied parameters can be defined: The required ON state READ current density of 105 A/cm2 can only be achieved for barriers smaller than 0.7 eV and defect densities larger than 3 × 1020 cm-3. The required current ratio between ON and OFF states of at least 10 requests defect density reduction of approximately an order of magnitude in a sheet of several nanometers near the working electrode.

Supercapacitors based on graphene-supported iron nanosheets as negative electrode materials.

PubMed

Long, Conglai; Wei, Tong; Yan, Jun; Jiang, Lili; Fan, Zhuangjun

2013-12-23

We report a facile strategy to prepare iron nanosheets directly grown on graphene sheets nanocomposite (C-PGF) through the carbonization of iron ions adsorbed onto polyaniline nanosheet/graphene oxide hybrid material. Because of the synergistic effect of iron nanosheets and graphene sheets, the as-obtained C-PGF exhibits an ultrahigh capacitance of ca. 720 F g(-1) in 6 M KOH aqueous solution. Additionally, the assembled asymmetric supercapacitor (C-PGF//Ni(OH)2/CNTs) delivers a remarkable high power density and a noticeable ultrahigh energy density of ca. 140 Wh kg(-1) (based on the total mass of active materials) and an acceptable cycling performance of 78% retention after 2000 cycles. Therefore, the designed supercapacitors with high energy density, comparable to rechargeable lithium-ion batteries (LIBs), offer an important guideline for future design of advanced next-generation supercapacitors for both industrial and consumer applications.

Enhancement mechanism of field electron emission properties in hybrid carbon nanotubes with tree- and wing-like features

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, G.M.; School of Materials Science and Engineering, The University of New South Wales, NSW 2052; Yang, C.C., E-mail: ccyang@unsw.edu.a

2009-12-15

In this work, the tree-like carbon nanotubes (CNTs) with branches of different diameters and the wing-like CNTs with graphitic-sheets of different densities were synthesized by using plasma enhanced chemical vapor deposition. The nanostructures of the as-prepared hybrid carbon materials were characterized by scanning electron microscopy and transmission electron microscopy. The structural dependence of field electron emission (FEE) property was also investigated. It is found that both of the tree- and wing-like CNTs exhibit a lower turn-on field and higher emission current density than the pristine CNTs, which can be ascribed to the effects of branch size, crystal orientation, and graphitic-sheetmore » density. - Graphical abstract: Tree-like carbon nanotubes (CNTs) with branches and the wing-like CNTs with graphitic-sheets were synthesized by using plasma enhanced chemical vapor deposition. The structural dependence of field electron emission property was also investigated.« less

Suprathermal O(+) and H(+) ion behavior during the March 22, 1979 (CDAW 6), substorms

NASA Technical Reports Server (NTRS)

Ipavich, F. M.; Galvin, A. B.; Gloeckler, G.; Scholer, M.; Hovestadt, D.; Klecker, B.

1985-01-01

The present investigation has the objective to report on the behavior of energetic (approximately 130 keV) O(+) ions in the earth's plasma sheet, taking into account observations by the ISEE 1 spacecraft during a magnetically active time interval encompassing two major substorms on March 22, 1979. Attention is also given to suprathermal H(+) and He(++) ions. ISEE 1 plasma sheet observations of the proton and alpha particle phase space densities as a function of energy per charge during the time interval 0933-1000 UT on March 22, 1979 are considered along with the proton phase space density versus energy in the energy interval approximately 10 to 70 keV for the selected time periods 0933-1000 UT (presubstorm) and 1230-1243 UT (recovery phase) during the 1055 substorm on March 22, 1979. A table listing the proton energy density for presubstorm and recovery periods is also provided.

Migration in the shearing sheet and estimates for young open cluster migration

NASA Astrophysics Data System (ADS)

Quillen, Alice C.; Nolting, Eric; Minchev, Ivan; De Silva, Gayandhi; Chiappini, Cristina

2018-04-01

Using tracer particles embedded in self-gravitating shearing sheet N-body simulations, we investigate the distance in guiding centre radius that stars or star clusters can migrate in a few orbital periods. The standard deviations of guiding centre distributions and maximum migration distances depend on the Toomre or critical wavelength and the contrast in mass surface density caused by spiral structure. Comparison between our simulations and estimated guiding radii for a few young supersolar metallicity open clusters, including NGC 6583, suggests that the contrast in mass surface density in the solar neighbourhood has standard deviation (in the surface density distribution) divided by mean of about 1/4 and larger than measured using COBE data by Drimmel and Spergel. Our estimate is consistent with a standard deviation of ˜0.07 dex in the metallicities measured from high-quality spectroscopic data for 38 young open clusters (<1 Gyr) with mean galactocentric radius 7-9 kpc.

A Density Functional Theory Study of New Boron Nanotubes

NASA Astrophysics Data System (ADS)

Chen, Zhao-Hua; Xie, Zun

2017-11-01

Using first-principles calculations, a series of new boron nanotubes (BNTs), which show various electronic properties, were theoretically predicted. Stable nanotubes with various chiral vectors and diameters can be formed by rolling up the boron sheet with relative stability [H. Tang and S. I. Beigi, Phys. Rev. B 82, 115412 (2010).]. By increasing the diameter for BNT, the stability is enhanced. The calculated density of states and band structures demonstrate that all the predicted BNTs are metallic, regardless of their diameter and chirality. The multicentre chemical bonds of the relatively stable boron sheet and BNTs are analysed using the deformation electron density. Within our study, the BNTs all have metallic conductive characteristics, in addition to having a low effective quality and high carrier concentration, which are very good nanoconductive material properties and could be combined to form high-power electrodes for lithium-ion batteries such as those used in many modern electronics.

The effects of disulfide bonds on the denatured state of barnase.

PubMed Central

Clarke, J.; Hounslow, A. M.; Bond, C. J.; Fersht, A. R.; Daggett, V.

2000-01-01

The effects of engineered disulfide bonds on protein stability are poorly understood because they can influence the structure, dynamics, and energetics of both the native and denatured states. To explore the effects of two engineered disulfide bonds on the stability of barnase, we have conducted a combined molecular dynamics and NMR study of the denatured state of the two mutants. As expected, the disulfide bonds constrain the denatured state. However, specific extended beta-sheet structure can also be detected in one of the mutant proteins. This mutant is also more stable than would be predicted. Our study suggests a possible cause of the very high stability conferred by this disulfide bond: the wild-type denatured ensemble is stabilized by a nonnative hydrophobic cluster, which is constrained from occurring in the mutant due to the formation of secondary structure. PMID:11206061

Constraining East Antarctic mass trends using a Bayesian inference approach

NASA Astrophysics Data System (ADS)

Martin-Español, Alba; Bamber, Jonathan L.

2016-04-01

East Antarctica is an order of magnitude larger than its western neighbour and the Greenland ice sheet. It has the greatest potential to contribute to sea level rise of any source, including non-glacial contributors. It is, however, the most challenging ice mass to constrain because of a range of factors including the relative paucity of in-situ observations and the poor signal to noise ratio of Earth Observation data such as satellite altimetry and gravimetry. A recent study using satellite radar and laser altimetry (Zwally et al. 2015) concluded that the East Antarctic Ice Sheet (EAIS) had been accumulating mass at a rate of 136±28 Gt/yr for the period 2003-08. Here, we use a Bayesian hierarchical model, which has been tested on, and applied to, the whole of Antarctica, to investigate the impact of different assumptions regarding the origin of elevation changes of the EAIS. We combined GRACE, satellite laser and radar altimeter data and GPS measurements to solve simultaneously for surface processes (primarily surface mass balance, SMB), ice dynamics and glacio-isostatic adjustment over the period 2003-13. The hierarchical model partitions mass trends between SMB and ice dynamics based on physical principles and measures of statistical likelihood. Without imposing the division between these processes, the model apportions about a third of the mass trend to ice dynamics, +18 Gt/yr, and two thirds, +39 Gt/yr, to SMB. The total mass trend for that period for the EAIS was 57±20 Gt/yr. Over the period 2003-08, we obtain an ice dynamic trend of 12 Gt/yr and a SMB trend of 15 Gt/yr, with a total mass trend of 27 Gt/yr. We then imposed the condition that the surface mass balance is tightly constrained by the regional climate model RACMO2.3 and allowed height changes due to ice dynamics to occur in areas of low surface velocities (<10 m/yr) , such as those in the interior of East Antarctica (a similar condition as used in Zwally 2015). The model must find a solution that satisfies all the input data, given these constraints. By imposing these conditions, over the period 2003-13 we obtained a mass gain due to ice dynamics of 103±15 Gt/yr but this was offset by a negative trend in SMB of 47 Gt/yr, resulting in an overall positive trend of 56±15 Gt/yr. Over 2003-08, the ice dynamics trend is 96 Gt/yr, offset by a strong negative SMB trend of -81 Gt/yr, with a total mass trend of 15±13Gt/yr. Even after relaxing the ice dynamics constraint over East Antarctica, we are unable to reproduce the large positive trend obtained in Zwally2015. We conclude that this result is inconsistent with the combined observations, irrespective of any assumption made about the density of surface elevation changes.

Communication: CDFT-CI couplings can be unreliable when there is fractional charge transfer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mavros, Michael G.; Van Voorhis, Troy, E-mail: tvan@mit.edu

2015-12-21

Constrained density functional theory with configuration interaction (CDFT-CI) is a useful, low-cost tool for the computational prediction of electronic couplings between pseudo-diabatic constrained electronic states. Such couplings are of paramount importance in electron transfer theory and transition state theory, among other areas of chemistry. Unfortunately, CDFT-CI occasionally fails significantly, predicting a coupling that does not decay exponentially with distance and/or overestimating the expected coupling by an order of magnitude or more. In this communication, we show that the eigenvalues of the difference density matrix between the two constrained states can be used as an a priori metric to determine whenmore » CDFT-CI are likely to be reliable: when the eigenvalues are near 0 or ±1, transfer of a whole electron is occurring, and CDFT-CI can be trusted. We demonstrate the utility of this metric with several illustrative examples.« less

Communication: CDFT-CI couplings can be unreliable when there is fractional charge transfer

NASA Astrophysics Data System (ADS)

Mavros, Michael G.; Van Voorhis, Troy

2015-12-01

Constrained density functional theory with configuration interaction (CDFT-CI) is a useful, low-cost tool for the computational prediction of electronic couplings between pseudo-diabatic constrained electronic states. Such couplings are of paramount importance in electron transfer theory and transition state theory, among other areas of chemistry. Unfortunately, CDFT-CI occasionally fails significantly, predicting a coupling that does not decay exponentially with distance and/or overestimating the expected coupling by an order of magnitude or more. In this communication, we show that the eigenvalues of the difference density matrix between the two constrained states can be used as an a priori metric to determine when CDFT-CI are likely to be reliable: when the eigenvalues are near 0 or ±1, transfer of a whole electron is occurring, and CDFT-CI can be trusted. We demonstrate the utility of this metric with several illustrative examples.

High performance asymmetric supercapacitor based on polypyrrole/graphene composite and its derived nitrogen-doped carbon nano-sheets

NASA Astrophysics Data System (ADS)

Zhu, Jianbo; Feng, Tianyu; Du, Xianfeng; Wang, Jingping; Hu, Jun; Wei, LiPing

2017-04-01

Neutral aqueous medium is a promising electrolyte for supercapacitors because it is low-cost, environmental-friendly and can achieve rapid charging/discharging with high power density. However, the energy density of such supercapacitor is significantly limited by its narrow operational voltage window. Herein, we demonstrated an effective approach to broaden the operational voltage window by fabricating an asymmetric supercapacitor (ASC) with polypyrrole/reduced graphene oxide (PPy/rGO) composite and its derived Nitrogen-doped carbon nano-sheets (NCs) as positive and negative electrode material, respectively. The homogeneous nano-sheet and mesoporous structure of PPy/rGO and NCs can facilitate rapid charge/ion migration and provide more active sites for ions adsorption/exchange to improve their electrochemical performance. Benefiting from high capacitance and good rate performance of PPy/rGO and NCs electrodes, the as-fabricated ASCs devices in a polyvinyl alcohol/LiCl gel electrolyte can realize a wide operational voltage of 1.6 V and deliver high energy density of 15.8 wh kg-1 (1.01 mWh cm-3) at 0.14 kW kg-1 (19.3 mW cm-3), which still remains 9.5 wh kg-1as power density increases to 6.56 kW kg-1, as well as excellent long-term cycling stability with about 88.7% capacitance retention after 10000 cycles. The remarkable performances suggest that the ASCs devices are promising for future energy storage applications.

The most intense current sheets in the high-speed solar wind near 1 AU

NASA Astrophysics Data System (ADS)

Podesta, John J.

2017-03-01

Electric currents in the solar wind plasma are investigated using 92 ms fluxgate magnetometer data acquired in a high-speed stream near 1 AU. The minimum resolvable scale is roughly 0.18 s in the spacecraft frame or, using Taylor's "frozen turbulence" approximation, one proton inertial length di in the plasma frame. A new way of identifying current sheets is developed that utilizes a proxy for the current density J obtained from the derivatives of the three orthogonal components of the observed magnetic field B. The most intense currents are identified as 5σ events, where σ is the standard deviation of the current density. The observed 5σ events are characterized by an average scale size of approximately 3di along the flow direction of the solar wind, a median separation of around 50di or 100di along the flow direction of the solar wind, and a peak current density on the order of 0.5 pA/cm2. The associated current-carrying structures are consistent with current sheets; however, the planar geometry of these structures cannot be confirmed using single-point, single-spacecraft measurements. If Taylor's hypothesis continues to hold for the energetically dominant fluctuations at kinetic scales 1

Electron Mobility in γ -Al2O3/SrTiO3

NASA Astrophysics Data System (ADS)

Christensen, D. V.; Frenkel, Y.; Schütz, P.; Trier, F.; Wissberg, S.; Claessen, R.; Kalisky, B.; Smith, A.; Chen, Y. Z.; Pryds, N.

2018-05-01

One of the key issues in engineering oxide interfaces for electronic devices is achieving high electron mobility. SrTiO3 -based interfaces with high electron mobility have gained a lot of interest due to the possibility of combining quantum phenomena with the many functionalities exhibited by SrTiO3 . To date, the highest electron mobility (140 000 cm2/V s at 2 K) is obtained by interfacing perovskite SrTiO3 with spinel γ -Al2O3 . The origin of the high mobility, however, remains poorly understood. Here, we investigate the scattering mechanisms limiting the mobility in γ -Al2O3/SrTiO3 at temperatures between 2 and 300 K and over a wide range of sheet carrier densities. For T >150 K , we find that the mobility is limited by longitudinal optical phonon scattering. For large sheet carrier densities (>8 ×1013 cm-2 ), the screened electron-phonon coupling leads to room-temperature mobilities up to μ ˜12 cm2/V s . For 5 K

Facile template-free synthesis of vertically aligned polypyrrole nanosheets on nickel foams for flexible all-solid-state asymmetric supercapacitors

NASA Astrophysics Data System (ADS)

Yang, Xiangwen; Lin, Zhixing; Zheng, Jingxu; Huang, Yingjuan; Chen, Bin; Mai, Yiyong; Feng, Xinliang

2016-04-01

This paper reports a novel and remarkably facile approach towards vertically aligned nanosheets on three-dimensional (3D) Ni foams. Conducting polypyrrole (PPy) sheets were grown on Ni foam through the volatilization of the environmentally friendly solvent from an ethanol-water solution of pyrrole (Py), followed by the polymerization of the coated Py in ammonium persulfate (APS) solution. The PPy-decorated Ni foams and commercial activated carbon (AC) modified Ni foams were employed as the two electrodes for the assembly of flexible all-solid-state asymmetric supercapacitors. The sheet-like structure of PPy and the macroporous feature of the Ni foam, which render large electrode-electrolyte interfaces, resulted in good capacitive performance of the supercapacitors. Moreover, a high energy density of ca. 14 Wh kg-1 and a high power density of 6.2 kW kg-1 were achieved for the all-solid-state asymmetric supercapacitors due to the wide cell voltage window.This paper reports a novel and remarkably facile approach towards vertically aligned nanosheets on three-dimensional (3D) Ni foams. Conducting polypyrrole (PPy) sheets were grown on Ni foam through the volatilization of the environmentally friendly solvent from an ethanol-water solution of pyrrole (Py), followed by the polymerization of the coated Py in ammonium persulfate (APS) solution. The PPy-decorated Ni foams and commercial activated carbon (AC) modified Ni foams were employed as the two electrodes for the assembly of flexible all-solid-state asymmetric supercapacitors. The sheet-like structure of PPy and the macroporous feature of the Ni foam, which render large electrode-electrolyte interfaces, resulted in good capacitive performance of the supercapacitors. Moreover, a high energy density of ca. 14 Wh kg-1 and a high power density of 6.2 kW kg-1 were achieved for the all-solid-state asymmetric supercapacitors due to the wide cell voltage window. Electronic supplementary information (ESI) available: ESI figures. See DOI: 10.1039/c6nr00468g

Flow and diffusion in channel-guided cell migration.

PubMed

Marel, Anna-Kristina; Zorn, Matthias; Klingner, Christoph; Wedlich-Söldner, Roland; Frey, Erwin; Rädler, Joachim O

2014-09-02

Collective migration of mechanically coupled cell layers is a notable feature of wound healing, embryonic development, and cancer progression. In confluent epithelial sheets, the dynamics have been found to be highly heterogeneous, exhibiting spontaneous formation of swirls, long-range correlations, and glass-like dynamic arrest as a function of cell density. In contrast, the flow-like properties of one-sided cell-sheet expansion in confining geometries are not well understood. Here, we studied the short- and long-term flow of Madin-Darby canine kidney (MDCK) cells as they moved through microchannels. Using single-cell tracking and particle image velocimetry (PIV), we found that a defined averaged stationary cell current emerged that exhibited a velocity gradient in the direction of migration and a plug-flow-like profile across the advancing sheet. The observed flow velocity can be decomposed into a constant term of directed cell migration and a diffusion-like contribution that increases with density gradient. The diffusive component is consistent with the cell-density profile and front propagation speed predicted by the Fisher-Kolmogorov equation. To connect diffusion-mediated transport to underlying cellular motility, we studied single-cell trajectories and occurrence of vorticity. We discovered that the directed large-scale cell flow altered fluctuations in cellular motion at short length scales: vorticity maps showed a reduced frequency of swirl formation in channel flow compared with resting sheets of equal cell density. Furthermore, under flow, single-cell trajectories showed persistent long-range, random-walk behavior superimposed on drift, whereas cells in resting tissue did not show significant displacements with respect to neighboring cells. Our work thus suggests that active cell migration manifests itself in an underlying, spatially uniform drift as well as in randomized bursts of short-range correlated motion that lead to a diffusion-mediated transport. Copyright © 2014 Biophysical Society. Published by Elsevier Inc. All rights reserved.

Electrostatic-Interaction-Assisted Construction of 3D Networks of Manganese Dioxide Nanosheets for Flexible High-Performance Solid-State Asymmetric Supercapacitors.

PubMed

Liu, Na; Su, Yanli; Wang, Zhiqiang; Wang, Zhen; Xia, Jinsong; Chen, Yong; Zhao, Zhigang; Li, Qingwen; Geng, Fengxia

2017-08-22

A three-dimensional (3D) macroscopic network of manganese oxide (MnO 2 ) sheets was synthesized by an easily scalable solution approach, grafting the negatively charged surfaces of the MnO 2 sheets with an aniline monomer by electrostatic interactions followed by a quick chemical oxidizing polymerization reaction. The obtained structure possessed MnO 2 sheets interconnected with polyaniline chains, producing a 3D monolith rich in mesopores. The MnO 2 sheets had almost all their reactive centers exposed on the electrode surface, and combined with the electron transport highways provided by polyaniline and the shortened diffusion paths provided by the porous structure, the deliberately designed electrode achieved an excellent capacitance of 762 F g -1 at a current of 1 A g -1 and cycling performance with a capacity retention of 90% over 8000 cycles. Furthermore, a flexible asymmetric supercapacitor based on the constructed electrode and activated carbon serving as the positive and negative electrodes, respectively, was successfully fabricated, delivering a maximum energy density of 40.2 Wh kg -1 (0.113 Wh cm -2 ) and power density of 6227.0 W kg -1 (17.44 W cm -2 ) in a potential window of 0-1.7 V in a PVA/Na 2 SO 4 gel electrolyte.

Obliquity-paced Pliocene West Antarctic ice sheet oscillations

USGS Publications Warehouse

Naish, T.; Powell, R.; Levy, R.; Wilson, G.; Scherer, R.; Talarico, F.; Krissek, L.; Niessen, F.; Pompilio, M.; Wilson, T.; Carter, L.; DeConto, R.; Huybers, P.; McKay, R.; Pollard, D.; Ross, J.; Winter, D.; Barrett, P.; Browne, G.; Cody, R.; Cowan, E.; Crampton, J.; Dunbar, G.; Dunbar, N.; Florindo, F.; Gebhardt, C.; Graham, I.; Hannah, M.; Hansaraj, D.; Harwood, D.; Helling, D.; Henrys, S.; Hinnov, L.; Kuhn, G.; Kyle, P.; Laufer, A.; Maffioli, P.; Magens, D.; Mandernack, K.; McIntosh, W.; Millan, C.; Morin, R.; Ohneiser, C.; Paulsen, T.; Persico, D.; Raine, I.; Reed, J.; Riesselman, C.; Sagnotti, L.; Schmitt, D.; Sjunneskog, C.; Strong, P.; Taviani, M.; Vogel, S.; Wilch, T.; Williams, T.

2009-01-01

Thirty years after oxygen isotope records from microfossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth's orbital geometry control the ice ages1, fundamental questions remain over the response of the Antarctic ice sheets to orbital cycles2. Furthermore, an understanding of the behaviour of the marine-based West Antarctic ice sheet (WAIS) during the 'warmer-than-present' early-Pliocene epoch (5–3 Myr ago) is needed to better constrain the possible range of ice-sheet behaviour in the context of future global warming3. Here we present a marine glacial record from the upper 600 m of the AND-1B sediment core recovered from beneath the northwest part of the Ross ice shelf by the ANDRILL programme and demonstrate well-dated, 40-kyr cyclic variations in ice-sheet extent linked to cycles in insolation influenced by changes in the Earth's axial tilt (obliquity) during the Pliocene. Our data provide direct evidence for orbitally induced oscillations in the WAIS, which periodically collapsed, resulting in a switch from grounded ice, or ice shelves, to open waters in the Ross embayment when planetary temperatures were up to 3 °C warmer than today4 and atmospheric CO2 concentration was as high as 400 p.p.m.v. (refs 5, 6). The evidence is consistent with a new ice-sheet/ice-shelf model7 that simulates fluctuations in Antarctic ice volume of up to +7 m in equivalent sea level associated with the loss of the WAIS and up to +3 m in equivalent sea level from the East Antarctic ice sheet, in response to ocean-induced melting paced by obliquity. During interglacial times, diatomaceous sediments indicate high surface-water productivity, minimal summer sea ice and air temperatures above freezing, suggesting an additional influence of surface melt8 under conditions of elevated CO2.

A new research project on the interaction of the solid Earth and the Antarctic Ice Sheet

NASA Astrophysics Data System (ADS)

Fukuda, Y.; Nishijima, J.; Kazama, T.; Nakamura, K.; Doi, K.; Suganuma, Y.; Okuno, J.; Araya, A.; Kaneda, H.; Aoyama, Y.

2017-12-01

A new research project of "Grant-in-Aid for Scientific Research on Innovative Areas" funded by JSPS (Japan Society for the Promotion of Science) has recently been launched. The title of the project is "Giant reservoirs of heat/water/material: Global environmental changes driven by Southern Ocean and Antarctic Ice Sheet", and as a five years project, is aiming to establish a new research area for Antarctic environmental system science. The project consists of 7 research topics, including Antarctic ice sheet and Southern ocean sciences, new observation methodology, modeling and other interdisciplinary topics, and we are involved in the topic A02-2, "Interaction of the solid Earth and the Antarctic Ice Sheet". The Antarctic ice sheet, which relates to the global climate changes through the sea level rise and ocean circulation, is an essential element of the Earth system for predicting the future environment changes. Thus many studies of the ice sheet changes have been conducted by means of geomorphological, geological, geodetic surveys, as well as satellite gravimetry and satellite altimetry. For these studies, one of the largest uncertainties is the effects of GIA. Therefore, GIA as a key to investigate the interaction between the solid Earth and the ice sheet changes, we plan to conduct geomorphological, geological and geodetic surveys in the inland mountain areas and the coastal areas including the surrounding areas of a Japanese station Syowa in East Antarctica, where the in-situ data for constraining GIA models are very few. Combining these new observations with other in-site data, various satellite data and numerical modeling, we aim to estimating a precise GIA model, constructing a reliable ice melting history after the last glacial maximum and obtaining the viscoelastic structure of the Earth's interior. In the presentation, we also show the five years research plans as well. This study was partially supported by JSPS KAKENHI Grant No. 17H06321.

Obliquity-paced Pliocene West Antarctic ice sheet oscillations.

PubMed

Naish, T; Powell, R; Levy, R; Wilson, G; Scherer, R; Talarico, F; Krissek, L; Niessen, F; Pompilio, M; Wilson, T; Carter, L; DeConto, R; Huybers, P; McKay, R; Pollard, D; Ross, J; Winter, D; Barrett, P; Browne, G; Cody, R; Cowan, E; Crampton, J; Dunbar, G; Dunbar, N; Florindo, F; Gebhardt, C; Graham, I; Hannah, M; Hansaraj, D; Harwood, D; Helling, D; Henrys, S; Hinnov, L; Kuhn, G; Kyle, P; Läufer, A; Maffioli, P; Magens, D; Mandernack, K; McIntosh, W; Millan, C; Morin, R; Ohneiser, C; Paulsen, T; Persico, D; Raine, I; Reed, J; Riesselman, C; Sagnotti, L; Schmitt, D; Sjunneskog, C; Strong, P; Taviani, M; Vogel, S; Wilch, T; Williams, T

2009-03-19

Thirty years after oxygen isotope records from microfossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth's orbital geometry control the ice ages, fundamental questions remain over the response of the Antarctic ice sheets to orbital cycles. Furthermore, an understanding of the behaviour of the marine-based West Antarctic ice sheet (WAIS) during the 'warmer-than-present' early-Pliocene epoch ( approximately 5-3 Myr ago) is needed to better constrain the possible range of ice-sheet behaviour in the context of future global warming. Here we present a marine glacial record from the upper 600 m of the AND-1B sediment core recovered from beneath the northwest part of the Ross ice shelf by the ANDRILL programme and demonstrate well-dated, approximately 40-kyr cyclic variations in ice-sheet extent linked to cycles in insolation influenced by changes in the Earth's axial tilt (obliquity) during the Pliocene. Our data provide direct evidence for orbitally induced oscillations in the WAIS, which periodically collapsed, resulting in a switch from grounded ice, or ice shelves, to open waters in the Ross embayment when planetary temperatures were up to approximately 3 degrees C warmer than today and atmospheric CO(2) concentration was as high as approximately 400 p.p.m.v. (refs 5, 6). The evidence is consistent with a new ice-sheet/ice-shelf model that simulates fluctuations in Antarctic ice volume of up to +7 m in equivalent sea level associated with the loss of the WAIS and up to +3 m in equivalent sea level from the East Antarctic ice sheet, in response to ocean-induced melting paced by obliquity. During interglacial times, diatomaceous sediments indicate high surface-water productivity, minimal summer sea ice and air temperatures above freezing, suggesting an additional influence of surface melt under conditions of elevated CO(2).

The Magnetic Field Structure of Mercury's Magnetotail

NASA Astrophysics Data System (ADS)

Rong, Z. J.; Ding, Y.; Slavin, J. A.; Zhong, J.; Poh, G.; Sun, W. J.; Wei, Y.; Chai, L. H.; Wan, W. X.; Shen, C.

2018-01-01

In this study, we use the magnetic field data measured by MErcury Surface, Space ENvironment, GEochemistry, and Ranging from 2011 to 2015 to investigate the average magnetic field morphology of Mercury's magnetotail in the down tail 0-3 RM (RM = 2,440 km, Mercury's radius). It is found that Mercury has a terrestrial-like magnetotail; the magnetic field structure beyond 1.5 RM down tail is stretched significantly with typical lobe field 50 nT. A cross-tail current sheet separating the antiparallel field lines of lobes is present in the equatorial plane. The magnetotail width in north-south direction is about 5 RM, while the transverse width is about 4 RM. Thus, the magnetotail shows elongation along the north-south direction. At the cross-tail current sheet center, the normal component of magnetic field (10-20 nT) is much larger than the cross-tail component. The lobe-field-aligned component of magnetic field over current sheet can be well fitted by Harris sheet model. The curvature radius of field lines at sheet center usually reaches a minimum around midnight (100-200 km) with stronger current density (40-50 nA/m2), while the curvature radius increases toward both flanks (400-600 km) with the decreased current density (about 20 nA/m2). The half-thickness of current sheet around midnight is about 0.25 RM or 600 km, and the inner edge of current sheet is located at the down tail about 1.5 RM. Our results about the field structure in the near Mercury's tail show an evident dawn-dusk asymmetry as that found in the Earth's magnetotail, but reasons should be different. Possible reasons are discussed.

Jupiter's Magnetodisc in the Juno Era and Implications for the Aurora

NASA Astrophysics Data System (ADS)

Vogt, M. F.; Spalsbury, L.; Connerney, J. E. P.

2017-12-01

The magnetic field in Jupiter's middle and outer magnetosphere is highly radially stretched by the presence of an azimuthally directed current sheet or magnetodisc. Magnetic field measurements from the Voyager, Pioneer, and Galileo spacecraft have been used to construct models of this current sheet, but these observations were limited to latitudes near the jovigraphic equator. High-latitude measurements, such as those recently collected by the Juno spacecraft in its polar orbit of Jupiter, are needed to more fully constrain our understanding of the magnetodisc structure and its effects on the coupling between the ionosphere and middle and outer magnetosphere. Here we will present Juno magnetic field observations from Jupiter's middle magnetosphere and will fit these data to current sheet models, including the Connerney et al. (1981) and Khurana (1997) models, to study the structure of the magnetodisc. We will examine how well the observations are fit by the available current sheet models and discuss any model modifications that are necessary to accurately represent the magnetic field measurements at high latitudes. We will also discuss temporal changes in the magnetodisc between successive Juno orbits ( 53 days) and on longer time scales by comparing Juno data to data from the Voyager, Pioneer, and Galileo spacecraft. Finally, we will consider the implications of our findings for other magnetospheric and auroral processes, particularly the magnetic mapping between the ionosphere and middle and outer magnetosphere.

Single-Molecule Light-Sheet Imaging of Suspended T Cells.

PubMed

Ponjavic, Aleks; McColl, James; Carr, Alexander R; Santos, Ana Mafalda; Kulenkampff, Klara; Lippert, Anna; Davis, Simon J; Klenerman, David; Lee, Steven F

2018-05-08

Adaptive immune responses are initiated by triggering of the T cell receptor. Single-molecule imaging based on total internal reflection fluorescence microscopy at coverslip/basal cell interfaces is commonly used to study this process. These experiments have suggested, unexpectedly, that the diffusional behavior and organization of signaling proteins and receptors may be constrained before activation. However, it is unclear to what extent the molecular behavior and cell state is affected by the imaging conditions, i.e., by the presence of a supporting surface. In this study, we implemented single-molecule light-sheet microscopy, which enables single receptors to be directly visualized at any plane in a cell to study protein dynamics and organization in live, resting T cells. The light sheet enabled the acquisition of high-quality single-molecule fluorescence images that were comparable to those of total internal reflection fluorescence microscopy. By comparing the apical and basal surfaces of surface-contacting T cells using single-molecule light-sheet microscopy, we found that most coated-glass surfaces and supported lipid bilayers profoundly affected the diffusion of membrane proteins (T cell receptor and CD45) and that all the surfaces induced calcium influx to various degrees. Our results suggest that, when studying resting T cells, surfaces are best avoided, which we achieve here by suspending cells in agarose. Copyright © 2018. Published by Elsevier Inc.

Uncertainties in the Modelled CO2 Threshold for Antarctic Glaciation

NASA Technical Reports Server (NTRS)

Gasson, E.; Lunt, D. J.; DeConto, R.; Goldner, A.; Heinemann, M.; Huber, M.; LeGrande, A. N.; Pollard, D.; Sagoo, N.; Siddall, M.;

Current-Sheet Formation and Reconnection at a Magnetic X Line in Particle-in-Cell Simulations

NASA Technical Reports Server (NTRS)

Black, C.; Antiochos, S. K.; Hesse, M.; Karpen, J. T.; Kuznetsova, M. M.; Zenitani, S.

2011-01-01

The integration of kinetic effects into macroscopic numerical models is currently of great interest to the heliophysics community, particularly in the context of magnetic reconnection. Reconnection governs the large-scale energy release and topological rearrangement of magnetic fields in a wide variety of laboratory, heliophysical, and astrophysical systems. We are examining the formation and reconnection of current sheets in a simple, two-dimensional X-line configuration using high-resolution particle-in-cell (PIC) simulations. The initial minimum-energy, potential magnetic field is perturbed by excess thermal pressure introduced into the particle distribution function far from the X line. Subsequently, the relaxation of this added stress leads self-consistently to the development of a current sheet that reconnects for imposed stress of sufficient strength. We compare the time-dependent evolution and final state of our PIC simulations with macroscopic magnetohydrodynamic simulations assuming both uniform and localized electrical resistivities (C. R. DeVore et al., this meeting), as well as with force-free magnetic-field equilibria in which the amount of reconnection across the X line can be constrained to be zero (ideal evolution) or optimal (minimum final magnetic energy). We will discuss implications of our results for understanding magnetic-reconnection onset and cessation at kinetic scales in dynamically formed current sheets, such as those occurring in the solar corona and terrestrial magnetotail.

Method of forming magnesium alloy sheets

DOEpatents

Mualidharan, Govindarajan; Muth, Thomas R.; Harper, David C.

2015-12-22

A machine for asymmetric rolling of a work-piece includes pair of rollers disposed in an arrangement to apply opposing, asymmetric rolling forces to roll a work-piece therebetween, wherein a surface of the work-piece is rolled faster than an opposite surface of the work-piece; and an exit constraint die rigidly disposed adjacent an exit side of the pair of rollers so that, as the work-piece exits the pair of rollers, the work-piece contacts the exit constraint die to constrain curling of the work-piece.

Theoretical investigation of structures and energetics of sodium adatom and its dimer on graphene: DFT study

NASA Astrophysics Data System (ADS)

Kaur, Gagandeep; Gupta, Shuchi; Rani, Pooja; Dharamvir, Keya

2015-11-01

Extensive ab initio calculations have been performed to study the energetics of a sodium (Na) atom and its dimer adsorbed on graphene using the SIESTA package Soler et al. (2002) [1] which works within a DFT(density functional theory)-GGA (generalized gradient approximation) pseudopotential framework. The adsorption energy, geometry, charge transfer, ionization potential and density of states (DOS), partial density states (PDOS) of adatom/dimer-graphene system have been calculated. After considering various sites for adsorption of Na on graphene, the center of a hexagonal ring of carbon atoms is found to be the preferred site of adsorption while the Na2 dimer prefers to rest parallel to the graphene sheet. We find insignificant energy differences among adsorption configurations involving different possible sites in parallel orientation, which implies high mobility of the dimer on the graphene sheet. We also notice only a slight distortion of the graphene sheet perpendicular to its plane upon adatom adsorption. However, some lateral displacements seen are more perceptible. Summary The adsorption energy, geometry, charge transfer, ionization potential and density of states (DOS) and PDOS of adatom/dimer-graphene system have been calculated using SIESTA package Soler et al. (2002) [1] which works within a DFT(density functional theory)-GGA (generalized gradient approximation) pseudopotential framework. Preferred site for adsorption of a sodium atom on graphene is the hollow site. For the Na dimer adsorption, we found that horizontal orientation is favored over the vertical one. From DOS plots, it is clear that graphene's states are nearly unaffected by the adsorption of Na adatom and Interaction between sodium and graphene is predominantly ionic

Constraining the interior density profile of a Jovian planet from precision gravity field data

NASA Astrophysics Data System (ADS)

Movshovitz, Naor; Fortney, Jonathan J.; Helled, Ravit; Hubbard, William B.; Thorngren, Daniel; Mankovich, Chris; Wahl, Sean; Militzer, Burkhard; Durante, Daniele

2017-10-01

The external gravity field of a planetary body is determined by the distribution of mass in its interior. Therefore, a measurement of the external field, properly interpreted, tells us about the interior density profile, ρ(r), which in turn can be used to constrain the composition in the interior and thereby learn about the formation mechanism of the planet. Planetary gravity fields are usually described by the coefficients in an expansion of the gravitational potential. Recently, high precision measurements of these coefficients for Jupiter and Saturn have been made by the radio science instruments on the Juno and Cassini spacecraft, respectively.The resulting coefficients come with an associated uncertainty. And while the task of matching a given density profile with a given set of gravity coefficients is relatively straightforward, the question of how best to account for the uncertainty is not. In essentially all prior work on matching models to gravity field data, inferences about planetary structure have rested on imperfect knowledge of the H/He equation of state and on the assumption of an adiabatic interior. Here we wish to vastly expand the phase space of such calculations. We present a framework for describing all the possible interior density structures of a Jovian planet, constrained only by a given set of gravity coefficients and their associated uncertainties. Our approach is statistical. We produce a random sample of ρ(a) curves drawn from the underlying (and unknown) probability distribution of all curves, where ρ is the density on an interior level surface with equatorial radius a. Since the resulting set of density curves is a random sample, that is, curves appear with frequency proportional to the likelihood of their being consistent with the measured gravity, we can compute probability distributions for any quantity that is a function of ρ, such as central pressure, oblateness, core mass and radius, etc. Our approach is also bayesian, in that it can utilize any prior assumptions about the planet's interior, as necessary, without being overly constrained by them.We demonstrate this approach with a sample of Jupiter interior models based on recent Juno data and discuss prospects for Saturn.

Constraining Saturn's interior density profile from precision gravity field measurement obtained during Grand Finale

NASA Astrophysics Data System (ADS)

Movshovitz, N.; Fortney, J. J.; Helled, R.; Hubbard, W. B.; Mankovich, C.; Thorngren, D.; Wahl, S. M.; Militzer, B.; Durante, D.

2017-12-01

The external gravity field of a planetary body is determined by the distribution of mass in its interior. Therefore, a measurement of the external field, properlyinterpreted, tells us about the interior density profile, ρ(r), which in turn can be used to constrain the composition in the interior and thereby learn about theformation mechanism of the planet. Recently, very high precision measurements of the gravity coefficients for Saturn have been made by the radio science instrument on the Cassini spacecraft during its Grand Finale orbits. The resulting coefficients come with an associated uncertainty. The task of matching a given density profile to a given set of gravity coefficients is relatively straightforward, but the question of how to best account for the uncertainty is not. In essentially all prior work on matching models to gravity field data inferences about planetary structure have rested on assumptions regarding the imperfectly known H/He equation of state and the assumption of an adiabatic interior. Here we wish to vastly expand the phase space of such calculations. We present a framework for describing all the possible interior density structures of a Jovian planet constrained by a given set of gravity coefficients and their associated uncertainties. Our approach is statistical. We produce a random sample of ρ(a) curves drawn from the underlying (and unknown) probability distribution of all curves, where ρ is the density on an interior level surface with equatorial radius a. Since the resulting set of density curves is a random sample, that is, curves appear with frequency proportional to the likelihood of their being consistent with the measured gravity, we can compute probability distributions for any quantity that is a function of ρ, such as central pressure, oblateness, core mass and radius, etc. Our approach is also Bayesian, in that it can utilize any prior assumptions about the planet's interior, as necessary, without being overly constrained by them. We apply this approach to produce a sample of Saturn interior models based on gravity data from Grand Finale orbits and discuss their implications.

Improved age constraints for the retreat of the Irish Sea Ice Stream

NASA Astrophysics Data System (ADS)

Smedley, Rachel; Chiverrell, Richard; Duller, Geoff; Scourse, James; Small, David; Fabel, Derek; Burke, Matthew; Clarke, Chris; McCarroll, Danny; McCarron, Stephen; O'Cofaigh, Colm; Roberts, David

2016-04-01

BRITICE-CHRONO is a large (> 45 researchers) consortium project working to provide an extensive geochronological dataset constraining the rate of retreat of a number of ice streams of the British-Irish Ice Sheet following the Last Glacial Maximum. When complete, the large empirical dataset produced by BRITICE-CHRONO will be integrated into model simulations to better understand the behaviour of the British-Irish Ice Sheet in response to past climate change, and provide an analogue for contemporary ice sheets. A major feature of the British-Irish Ice Sheet was the dynamic Irish Sea Ice Stream, which drained a large proportion of the ice sheet and extended to the proposed southern limit of glaciation upon the Isles of Scilly (Scourse, 1991). This study will focus on a large suite of terrestrial samples that were collected along a transect of the Irish Sea basin, covering the line of ice retreat from the Isles of Scilly (50°N) in the south, to the Isle of Man (54°N) in the north; a distance of 500 km. Ages are determined for both the eastern and western margins of the Irish Sea using single-grain luminescence dating (39 samples) and terrestrial cosmogenic nuclide dating (10 samples). A Bayesian sequence model is then used in combination with the prior information determined for deglaciation to integrate the geochronological datasets, and assess retreat rates for the Irish Sea Ice Stream. Scourse, J.D., 1991. Late Pleistocene stratigraphy and palaeobotany of the Isles of Scilly. Philosophical Transactions of the Royal Society of London B334, 405 - 448.

Field evaluation of ZeroFly--an insecticide incorporated plastic sheeting against malaria vectors & its impact on malaria transmission in tribal area of northern Orissa.

PubMed

Sharma, S K; Upadhyay, A K; Haque, M A; Tyagi, P K; Mohanty, S S; Mittal, P K; Dash, A P

2009-10-01

Insecticide incorporated plastic sheeting is a new technology to control mosquitoes in emergency shelter places and also temporary habitations in different locations. Therefore, field studies were conducted to assess the efficacy of ZeroFly plastic sheeting treated with deltamethrin on prevailing disease vectors Anopheles culicifacies and An. fluviatilis and its impact on malaria transmission in one of the highly endemic areas of Orissa. The study was conducted in Birkera block of Sundargarh district, Orissa state. The study area comprised 3 villages, which were randomized as ZeroFly plastic sheet, untreated plastic sheet and no sheet area. ZeroFly plastic sheets and untreated plastic sheets were fixed in study and control villages respectively covering all the rooms in each household. Longitudinal studies were conducted on the bioefficacy with the help of cone bioassays, monitoring of the mosquito density through hand catch, floor sheet and exit trap collections and fortnightly domiciliary active surveillance in all the study villages. In ZeroFly plastic sheeting area, there was a significant reduction of 84.7 per cent in the entry rate of total mosquitoes in comparison to pre-intervention phase. There was 56.2 per cent immediate mortality in total mosquitoes in houses with ZeroFly sheeting. The overall feeding success rate of mosquitoes in the trial village was only 12.5 per cent in comparison to 49.7 and 51.1 per cent in villages with untreated plastic sheet and no sheet respectively. There was a significant reduction of 65.0 and 70.5 per cent in malaria incidence in ZeroFly plastic sheeting area as compared to untreated plastic sheet and no sheet area respectively. Our study showed that introduction of ZeroFly plastic sheets in a community-based intervention programme is operationally feasible to contain malaria especially in the high transmission difficult areas.

Deciphering the evolution of the last Eurasian ice sheets

NASA Astrophysics Data System (ADS)

Hughes, Anna; Gyllencreutz, Richard; Mangerud, Jan; Svendsen, John Inge

2016-04-01

Glacial geologists need ice sheet-scale chronological reconstructions of former ice extent to set individual records in a wider context and compare interpretations of ice sheet response to records of past environmental changes. Ice sheet modellers require empirical reconstructions on size and volume of past ice sheets that are fully documented, specified in time and include uncertainty estimates for model validation or constraints. Motivated by these demands, in 2005 we started a project (Database of the Eurasian Deglaciation, DATED) to compile and archive all published dates relevant to constraining the build-up and retreat of the last Eurasian ice sheets, including the British-Irish, Scandinavian and Svalbard-Barents-Kara Seas ice sheets (BIIS, SIS and SBKIS respectively). Over 5000 dates were assessed for reliability and used together with published ice-sheet margin positions to reconstruct time-slice maps of the ice sheets' extent, with uncertainty bounds, every 1000 years between 25-10 kyr ago and at four additional periods back to 40 kyr ago. Ten years after the idea for a database was conceived, the first version of results (DATED-1) has now been released (Hughes et al. 2016). We observe that: i) both the BIIS and SBKIS achieve maximum extent, and commence retreat earlier than the larger SIS; ii) the eastern terrestrial margin of the SIS reached its maximum extent up to 7000 years later than the westernmost marine margin; iii) the combined maximum ice volume (~24 m sea-level equivalent) was reached c. 21 ka; iv) large uncertainties exist; predominantly across marine sectors (e.g. the timing of coalescence and separation of the SIS and BKIS) but also in well-studied areas due to conflicting yet equally robust data. In just three years since the DATED-1 census (1 January 2013), the volume of new information (from both dates and mapped glacial geomorphology) has grown significantly (~1000 new dates). Here, we present the DATED-1 results in the context of the climatic changes of the last glacial, discuss the implications of emerging post-census data, and describe plans for the next version of the database, DATED-2. Hughes, A. L. C., Gyllencreutz, R., Lohne, Ø. S., Mangerud, J., Svendsen, J. I. 2016: The last Eurasian ice sheets - a chronological database and time-slice reconstruction, DATED-1. Boreas, 45, 1-45. 10.1111/bor.12142

Tissue Engineering of the Corneal Endothelium: A Review of Carrier Materials

PubMed Central

Teichmann, Juliane; Valtink, Monika; Nitschke, Mirko; Gramm, Stefan; Funk, Richard H.W.; Engelmann, Katrin; Werner, Carsten

2013-01-01

Functional impairment of the human corneal endothelium can lead to corneal blindness. In order to meet the high demand for transplants with an appropriate human corneal endothelial cell density as a prerequisite for corneal function, several tissue engineering techniques have been developed to generate transplantable endothelial cell sheets. These approaches range from the use of natural membranes, biological polymers and biosynthetic material compositions, to completely synthetic materials as matrices for corneal endothelial cell sheet generation. This review gives an overview about currently used materials for the generation of transplantable corneal endothelial cell sheets with a special focus on thermo-responsive polymer coatings. PMID:24956190

Faraday polarization fluctuations of satellite beacon signals

NASA Technical Reports Server (NTRS)

Lee, M. C.; Klobuchar, J. A.

1988-01-01

The anisotropic effects of random density irregularities in causing Faraday polarization fluctuations of VHF radio signals are examined, taking both rod-like and sheet-like irregularities into consideration. It is found that the variance of Faraday polarization fluctuations depends on the ratio of perpendicular to parallel correlation lengths. The anisotropic effect of rod-like ionospheric irregularities are shown to be most appreciable for longitudinal propagation. The anisotropic effect of sheet-like ionospheric irregularities, however, is not strongly dependent on the radio propagation angle. During transionospheric propagation at large angles with respect to the geomagnetic field, sheet-like irregularities may cause greater Faraday polarization fluctuations than rod-like irregularities.

Tunable electronic, electrical and optical properties of graphene oxide sheets by ion irradiation

NASA Astrophysics Data System (ADS)

Jayalakshmi, G.; Saravanan, K.; Panigrahi, B. K.; Sundaravel, B.; Gupta, Mukul

2018-05-01

The tunable electronic, electrical and optical properties of graphene oxide (GO) sheets were investigated using a controlled reduction by 500 keV Ar+-ion irradiation. The carbon to oxygen ratio of the GO sheets upon the ion beam reduction has been estimated using resonant Rutherford backscattering spectrometry analyses and its effect on the electrical and optical properties of GO sheets has been studied using sheet resistance measurements and photoluminescence (PL) measurements. The restoration of sp 2-hybridized carbon atoms within the sp 3 matrix is found to be increases with increasing the Ar+-ion fluences as evident from Fourier transform infrared, and x-ray absorption near-edge structure measurements. The decrease in the number of disorder-induced local density of states (LDOSs) within the π-π* gap upon the reduction causes the shifting of PL emission from near infra-red to blue region and decreases the sheet resistance. The improved electrical and optical properties of GO sheets were correlated to the decrease in the number of LDOSs within the π-π* gap. Our experimental investigations suggest ion beam irradiation is one of an effective approaches to reduce GO to RGO and to tailor its electronic, electrical and optical properties.

Tunable electronic, electrical and optical properties of graphene oxide sheets by ion irradiation.

PubMed

Jayalakshmi, G; Saravanan, K; Panigrahi, B K; Sundaravel, B; Gupta, Mukul

2018-05-04

The tunable electronic, electrical and optical properties of graphene oxide (GO) sheets were investigated using a controlled reduction by 500 keV Ar + -ion irradiation. The carbon to oxygen ratio of the GO sheets upon the ion beam reduction has been estimated using resonant Rutherford backscattering spectrometry analyses and its effect on the electrical and optical properties of GO sheets has been studied using sheet resistance measurements and photoluminescence (PL) measurements. The restoration of sp 2 -hybridized carbon atoms within the sp 3 matrix is found to be increases with increasing the Ar + -ion fluences as evident from Fourier transform infrared, and x-ray absorption near-edge structure measurements. The decrease in the number of disorder-induced local density of states (LDOSs) within the π-π* gap upon the reduction causes the shifting of PL emission from near infra-red to blue region and decreases the sheet resistance. The improved electrical and optical properties of GO sheets were correlated to the decrease in the number of LDOSs within the π-π* gap. Our experimental investigations suggest ion beam irradiation is one of an effective approaches to reduce GO to RGO and to tailor its electronic, electrical and optical properties.

Patterns through elastic instabilities, from thin sheets to twisted ribbons

NASA Astrophysics Data System (ADS)

Damman, Pascal

Sheets embedded in a given shape by external forces store the exerted work in elastic deformations. For pure tensile forces, the work is stored as stretching energy. When the forces are compressive, several ways to store the exerted work, combining stretching and bending deformations can be explored. For large deflections, the ratio of bending, Eh3ζ2 /L4 and stretching, Ehζ4 /L4 energies, suggests that strain-free solutions should be favored for thin sheets, provided ζ2 >>h2 (where E , ζ , Land h are the elastic modulus, the deflection, a characteristic sheet size and its thickness). For uniaxially constrained sheets deriving from the Elastica, strain-free solutions are obvious, i.e., buckles, folds or wrinkles grow to absorb the stress of compression. In contrast, crumpled sheets exhibit ``origami-like'' solutions usually described as an assembly of flat polygonal facets delimitated by ridges focusing strains are observed. This type of solutions is particularly interesting since a faceted morphology is isometric to the undeformed sheet, except at those narrow ridges. In some cases however, the geometric constraints imposed by the external forces do not allow solutions with negligible strain in the deformed state. For instance, considering a circular sheet on a small drop, so thin that bending becomes negligible, i.e., Eh3 / γL2 << 1 . The capillary tension, γ at the edge forces the sheet to follow the spherical shape of the drop. Depending on the magnitude of the capillary tension with respect to the stretching modulus, such a sheet on a sphere can be in full tension or subjected to azimuthal compression. These spherical solutions could generate a hoop stress of compression within a small strip at the sheet's edge. The mechanical response of the sheet will generate tiny wrinkles decorating the edge to relax the compression stress while keeping its spherical shape. Finally, twisting a paper ribbon under high tension spontaneously produces helicoidal shapes that also reflect stretching and bending deformations. When the tension is progressively relieved, longitudinal and transverse compressive stresses build. To relax the longitudinal stress while keeping the helicoid shape, the ribbons produce wrinkles that ultimately becomes sharp folds similar to the ridge singularities observed in crumpled paper. The relaxation of the transverse compression stress produces cylindrical solutions. All these examples illustrates the natural tendency of an elastic sheet to stay as close as possible to the imposed shape, i.e. flat, spherical, helicoid. The mechanical response of the elastic sheet aims to relieve the compressive stress by growing a given micro-structure, i.e. wrinkles, singularities. In this talk, we will explore the general mechanisms at work, based on geometry and a competition between various energy terms, involving stretching and bending modes.

Numerical methods for the inverse problem of density functional theory

DOE PAGES

Jensen, Daniel S.; Wasserman, Adam

2017-07-17

Here, the inverse problem of Kohn–Sham density functional theory (DFT) is often solved in an effort to benchmark and design approximate exchange-correlation potentials. The forward and inverse problems of DFT rely on the same equations but the numerical methods for solving each problem are substantially different. We examine both problems in this tutorial with a special emphasis on the algorithms and error analysis needed for solving the inverse problem. Two inversion methods based on partial differential equation constrained optimization and constrained variational ideas are introduced. We compare and contrast several different inversion methods applied to one-dimensional finite and periodic modelmore » systems.« less

Numerical methods for the inverse problem of density functional theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jensen, Daniel S.; Wasserman, Adam

Here, the inverse problem of Kohn–Sham density functional theory (DFT) is often solved in an effort to benchmark and design approximate exchange-correlation potentials. The forward and inverse problems of DFT rely on the same equations but the numerical methods for solving each problem are substantially different. We examine both problems in this tutorial with a special emphasis on the algorithms and error analysis needed for solving the inverse problem. Two inversion methods based on partial differential equation constrained optimization and constrained variational ideas are introduced. We compare and contrast several different inversion methods applied to one-dimensional finite and periodic modelmore » systems.« less

Carbon nanofibers with radially grown graphene sheets derived from electrospinning for aqueous supercapacitors with high working voltage and energy density

NASA Astrophysics Data System (ADS)

Zhao, Lei; Qiu, Yejun; Yu, Jie; Deng, Xianyu; Dai, Chenglong; Bai, Xuedong

2013-05-01

Improvement of energy density is an urgent task for developing advanced supercapacitors. In this paper, aqueous supercapacitors with high voltage of 1.8 V and energy density of 29.1 W h kg-1 were fabricated based on carbon nanofibers (CNFs) and Na2SO4 electrolyte. The CNFs with radially grown graphene sheets (GSs) and small average diameter down to 11 nm were prepared by electrospinning and carbonization in NH3. The radially grown GSs contain between 1 and a few atomic layers with their edges exposed on the surface. The CNFs are doped with nitrogen and oxygen with different concentrations depending on the carbonizing temperature. The supercapacitors exhibit excellent cycling performance with the capacity retention over 93.7% after 5000 charging-discharging cycles. The unique structure, possessing radially grown GSs, small diameter, and heteroatom doping of the CNFs, and application of neutral electrolyte account for the high voltage and energy density of the present supercapacitors. The present supercapacitors are of high promise for practical application due to the high energy density and the advantages of neutral electrolyte including low cost, safety, low corrosivity, and convenient assembly in air.

Inferences Concerning the Magnetospheric Source Region for Auroral Breakup

NASA Technical Reports Server (NTRS)

Lyons, L. R.

1992-01-01

It is argued that the magnetospheric source region for auroral arc breakup and substorm initiation is along boundary plasma sheet (BPS) magnetic field lines. This source region lies beyond a distinct central plasma sheet (CPS) region and sufficiently far from the Earth that energetic ion motion violates the guiding center approximation (i.e., is chaotic). The source region is not constrained to any particular range of distances from the Earth, and substorm initiation may be possible over a wide range of distances from near synchronous orbit to the distant tail. It is also argued that the layer of low-energy electrons and velocity dispersed ion beams observed at low altitudes on Aureol 3 is not a different region from the region of auroral arcs. Both comprise the BPS. The two regions occasionally appear distinct at low altitudes because of the effects of arc field-aligned potential drops on precipitating particles.

Conformational Effects through Hydrogen Bonding in a Constrained γ-Peptide Template: From Intraresidue Seven-Membered Rings to a Gel-Forming Sheet Structure.

PubMed

Awada, Hawraà; Grison, Claire M; Charnay-Pouget, Florence; Baltaze, Jean-Pierre; Brisset, François; Guillot, Régis; Robin, Sylvie; Hachem, Ali; Jaber, Nada; Naoufal, Daoud; Yazbeck, Ogaritte; Aitken, David J

2017-05-05

A series of three short oligomers (di-, tri-, and tetramers) of cis-2-(aminomethyl)cyclobutane carboxylic acid, a γ-amino acid featuring a cyclobutane ring constraint, were prepared, and their conformational behavior was examined spectroscopically and by molecular modeling. In dilute solutions, these peptides showed a number of low-energy conformers, including ribbonlike structures pleated around a rarely observed series of intramolecular seven-membered hydrogen bonds. In more concentrated solutions, these interactions defer to an organized supramolecular assembly, leading to thermoreversible organogel formation notably for the tripeptide, which produced fibrillar xerogels. In the solid state, the dipeptide adopted a fully extended conformation featuring a one-dimensional network of intermolecularly H-bonded molecules stacked in an antiparallel sheet alignment. This work provides unique insight into the interplay between inter- and intramolecular H-bonded conformer topologies for the same peptide template.

Antarctic mass balance changes from GRACE

NASA Astrophysics Data System (ADS)

Kallenberg, B.; Tregoning, P.

2012-04-01

The Antarctic ice sheet contains ~30 million km3 of ice and constitutes a significant component of the global water balance with enough freshwater to raise global sea level by ~60 m. Altimetry measurements and climate models suggest variable behaviour across the Antarctic ice sheet, with thickening occurring in a vast area of East Antarctica and substantial thinning in West Antarctica caused by increased temperature gradients in the surrounding ocean. However, the rate at which the polar ice cap is melting is still poorly constrained. To calculate the mass loss of an ice sheet it is necessary to separate present day mass balance changes from glacial isostatic adjustment (GIA), the response of the Earth's crust to mass loss, wherefore it is essential to undertake sufficient geological and geomorphological sampling. As there is only a limited possibility for this in Antarctica, all models (i.e. geological, hydrological as well as atmospheric) are very poorly constrained. Therefore, space-geodetic observations play an important role in detecting changes in mass and spatial variations in the Earth's gravity field. The Gravity Recovery And Climate Experiment (GRACE) observed spatial variations in the Earth's gravity field over the past ten years. The satellite detects mass variations in the Earth system including geophysical, hydrological and atmospheric shifts. GRACE itself is not able to separate the GIA from mass balance changes and, due to the insufficient geological and geomorphological database, it is not possible to model the GIA effect accurately for Antarctica. However, the results from GRACE can be compared with other scientific results, coming from other geodetic observations such as satellite altimetry and GPS or by the use of geological observations. In our contribution we compare the GRACE data with recorded precipitation patterns and mass anomalies over East Antarctica to separate the observed GRACE signal into its two components: GIA as a result of mass loss and present day surface load changes due to possible snow/ice accumulation.

Ice-sheet thinning and acceleration at Camp Century, Greenlan

NASA Astrophysics Data System (ADS)

Colgan, W. T.

2017-12-01

Camp Century, Greenland (77.18 °N, 61.12 °W, 1900 m), is located approximately 150 km inland from the ice-sheet margin in Northwest Greenland. In-situ and remotely-sensed measurements of ice-sheet elevation at Camp Century exhibit a thinning trend between 1964 and the present. A comparison of 1966 and 2017 firn density profiles indicates that a portion of this ice-sheet thinning is attributable to increased firn compaction rate. In-situ measurements of increasing ice surface velocity over the 1977-2017 period indicate that enhanced horizontal divergence of ice flux is also contributing to ice dynamic thinning at Camp Century. This apparent ice dynamic thinning could potentially result from a migrating local flow divide or decreasing effective ice viscosity. In a shorter-term context, observations of decadal-scale ice-sheet thinning and acceleration at Camp Century highlights underappreciated transience in inland ice form and flow during the satellite era. In a longer-term context, these multi-decadal observations contrast with inferences of millennial-scale ice-sheet thickening and deceleration at Camp Century.

MABEL Photon-Counting Laser Altimetry Data in Alaska for ICESat-2 Simulations and Development

NASA Technical Reports Server (NTRS)

Brunt, Kelly; Neumann, T. A.; Amundson, M.; Kavanaugh, J. L.; Moussavi, M. S.; Walsh, K. M.; Cook, W. B.; Markus, T.

2016-01-01

Multiple Altimeter Beam Experimental Lidar (MABEL) maps Alaskan crevasses in detail, using 50 of the expected along-track Advanced Topographic Laser Altimeter System (ATLAS) signal-photon densities over summer ice sheets. Ice, Cloud, and Land Elevation Satellite 2 (ICESat-2) along-track data density, and spatial data density due to the multiple-beam strategy, will provide a new dataset to mid-latitude alpine glacier researchers.

40 CFR Appendix A to Subpart II of... - VOC Data Sheet 1

Code of Federal Regulations, 2012 CFR

2012-07-01

...) National Emission Standards for Shipbuilding and Ship Repair (Surface Coating) Pt. 63, Subpt. II, App. A... supplied” by the manufacturer. Properties of the coating as supplied 1 to the customer: A. Coating Density... (nonvolatiles) 2. __ g/L coating (less water and exempt compounds) G. Thinner Density: Dth __ g/L ASTM...

Ultrathin Hierarchical Porous Carbon Nanosheets for High-Performance Supercapacitors and Redox Electrolyte Energy Storage.

PubMed

Jayaramulu, Kolleboyina; Dubal, Deepak P; Nagar, Bhawna; Ranc, Vaclav; Tomanec, Ondrej; Petr, Martin; Datta, Kasibhatta Kumara Ramanatha; Zboril, Radek; Gómez-Romero, Pedro; Fischer, Roland A

2018-04-01

The design of advanced high-energy-density supercapacitors requires the design of unique materials that combine hierarchical nanoporous structures with high surface area to facilitate ion transport and excellent electrolyte permeability. Here, shape-controlled 2D nanoporous carbon sheets (NPSs) with graphitic wall structure through the pyrolysis of metal-organic frameworks (MOFs) are developed. As a proof-of-concept application, the obtained NPSs are used as the electrode material for a supercapacitor. The carbon-sheet-based symmetric cell shows an ultrahigh Brunauer-Emmett-Teller (BET)-area-normalized capacitance of 21.4 µF cm -2 (233 F g -1 ), exceeding other carbon-based supercapacitors. The addition of potassium iodide as redox-active species in a sulfuric acid (supporting electrolyte) leads to the ground-breaking enhancement in the energy density up to 90 Wh kg -1 , which is higher than commercial aqueous rechargeable batteries, maintaining its superior power density. Thus, the new material provides a double profits strategy such as battery-level energy and capacitor-level power density. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The influence of the environment on the propagation of protostellar outflows

NASA Astrophysics Data System (ADS)

Moraghan, Anthony; Smith, Michael D.; Rosen, Alexander

2008-06-01

The properties of bipolar outflows depend on the structure in the environment as well as the nature of the jet. To help distinguish between the two, we investigate here the properties pertaining to the ambient medium. We execute axisymmetric hydrodynamic simulations, injecting continuous atomic jets into molecular media with density gradients (protostellar cores) and density discontinuities (thick swept-up sheets). We determine the distribution of outflowing mass with radial velocity (the mass spectrum) to quantify our approach and to compare to observationally determined values. We uncover a sequence from clump entrainment in the flanks to bow shock sweeping as the density profile steepens. We also find that the dense, highly supersonic outflows remain collimated but can become turbulent after passing through a shell. The mass spectra vary substantially in time, especially at radial speeds exceeding 15 kms-1. The mass spectra also vary according to the conditions: both envelope-type density distributions and the passage through dense sheets generate considerably steeper mass spectra than a uniform medium. The simulations suggest that observed outflows penetrate highly non-uniform media.

Electronic Coupling Calculations for Bridge-Mediated Charge Transfer Using Constrained Density Functional Theory (CDFT) and Effective Hamiltonian Approaches at the Density Functional Theory (DFT) and Fragment-Orbital Density Functional Tight Binding (FODFTB) Level

DOE PAGES

Gillet, Natacha; Berstis, Laura; Wu, Xiaojing; ...

2016-09-09

In this paper, four methods to calculate charge transfer integrals in the context of bridge-mediated electron transfer are tested. These methods are based on density functional theory (DFT). We consider two perturbative Green's function effective Hamiltonian methods (first, at the DFT level of theory, using localized molecular orbitals; second, applying a tight-binding DFT approach, using fragment orbitals) and two constrained DFT implementations with either plane-wave or local basis sets. To assess the performance of the methods for through-bond (TB)-dominated or through-space (TS)-dominated transfer, different sets of molecules are considered. For through-bond electron transfer (ET), several molecules that were originally synthesizedmore » by Paddon-Row and co-workers for the deduction of electronic coupling values from photoemission and electron transmission spectroscopies, are analyzed. The tested methodologies prove to be successful in reproducing experimental data, the exponential distance decay constant and the superbridge effects arising from interference among ET pathways. For through-space ET, dedicated p-stacked systems with heterocyclopentadiene molecules were created and analyzed on the basis of electronic coupling dependence on donor-acceptor distance, structure of the bridge, and ET barrier height. The inexpensive fragment-orbital density functional tight binding (FODFTB) method gives similar results to constrained density functional theory (CDFT) and both reproduce the expected exponential decay of the coupling with donor-acceptor distances and the number of bridging units. Finally, these four approaches appear to give reliable results for both TB and TS ET and present a good alternative to expensive ab initio methodologies for large systems involving long-range charge transfers.« less

Electronic Coupling Calculations for Bridge-Mediated Charge Transfer Using Constrained Density Functional Theory (CDFT) and Effective Hamiltonian Approaches at the Density Functional Theory (DFT) and Fragment-Orbital Density Functional Tight Binding (FODFTB) Level

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gillet, Natacha; Berstis, Laura; Wu, Xiaojing

In this paper, four methods to calculate charge transfer integrals in the context of bridge-mediated electron transfer are tested. These methods are based on density functional theory (DFT). We consider two perturbative Green's function effective Hamiltonian methods (first, at the DFT level of theory, using localized molecular orbitals; second, applying a tight-binding DFT approach, using fragment orbitals) and two constrained DFT implementations with either plane-wave or local basis sets. To assess the performance of the methods for through-bond (TB)-dominated or through-space (TS)-dominated transfer, different sets of molecules are considered. For through-bond electron transfer (ET), several molecules that were originally synthesizedmore » by Paddon-Row and co-workers for the deduction of electronic coupling values from photoemission and electron transmission spectroscopies, are analyzed. The tested methodologies prove to be successful in reproducing experimental data, the exponential distance decay constant and the superbridge effects arising from interference among ET pathways. For through-space ET, dedicated p-stacked systems with heterocyclopentadiene molecules were created and analyzed on the basis of electronic coupling dependence on donor-acceptor distance, structure of the bridge, and ET barrier height. The inexpensive fragment-orbital density functional tight binding (FODFTB) method gives similar results to constrained density functional theory (CDFT) and both reproduce the expected exponential decay of the coupling with donor-acceptor distances and the number of bridging units. Finally, these four approaches appear to give reliable results for both TB and TS ET and present a good alternative to expensive ab initio methodologies for large systems involving long-range charge transfers.« less

Electronic Coupling Calculations for Bridge-Mediated Charge Transfer Using Constrained Density Functional Theory (CDFT) and Effective Hamiltonian Approaches at the Density Functional Theory (DFT) and Fragment-Orbital Density Functional Tight Binding (FODFTB) Level.

PubMed

Gillet, Natacha; Berstis, Laura; Wu, Xiaojing; Gajdos, Fruzsina; Heck, Alexander; de la Lande, Aurélien; Blumberger, Jochen; Elstner, Marcus

2016-10-11

In this article, four methods to calculate charge transfer integrals in the context of bridge-mediated electron transfer are tested. These methods are based on density functional theory (DFT). We consider two perturbative Green's function effective Hamiltonian methods (first, at the DFT level of theory, using localized molecular orbitals; second, applying a tight-binding DFT approach, using fragment orbitals) and two constrained DFT implementations with either plane-wave or local basis sets. To assess the performance of the methods for through-bond (TB)-dominated or through-space (TS)-dominated transfer, different sets of molecules are considered. For through-bond electron transfer (ET), several molecules that were originally synthesized by Paddon-Row and co-workers for the deduction of electronic coupling values from photoemission and electron transmission spectroscopies, are analyzed. The tested methodologies prove to be successful in reproducing experimental data, the exponential distance decay constant and the superbridge effects arising from interference among ET pathways. For through-space ET, dedicated π-stacked systems with heterocyclopentadiene molecules were created and analyzed on the basis of electronic coupling dependence on donor-acceptor distance, structure of the bridge, and ET barrier height. The inexpensive fragment-orbital density functional tight binding (FODFTB) method gives similar results to constrained density functional theory (CDFT) and both reproduce the expected exponential decay of the coupling with donor-acceptor distances and the number of bridging units. These four approaches appear to give reliable results for both TB and TS ET and present a good alternative to expensive ab initio methodologies for large systems involving long-range charge transfers.

Nonlinear distortion of thin liquid sheets

NASA Astrophysics Data System (ADS)

Mehring, Carsten Ralf

Thin planar, annular and conical liquid sheets or films are analyzed, in a unified manner, by means of a reduced- dimension approach providing governing equations for the nonlinear motion of planar and swirling annular thin inviscid and incompressible liquid sheets in zero gravity and with axial disturbances only. Temporal analyses of periodically disturbed infinite sheets are considered, as well as spatial analyses of semi-infinite sheets modulated at the nozzle exit. Results on planar and swirling annular or conical sheets are presented for a zero density ambient gas. Here, conical sheets are obtained in the nearfield of the nozzle exit by considering sheets or films with swirl in excess of that needed to stabilize the discharging stream in its annular configuration. For nonswirling annular sheets a spatially and/or temporally constant gas-core pressure is assumed. A model extension considering the influence of aerodynamic effects on planar sheets is proposed. For planar and annular sheets, linear analyses of the pure initial- and pure boundary-value problem provide insight into the propagation characteristics of dilational and sinuous waves, the (linear) coupling between both wave modes, the stability limits for the annular configuration, as well as the appearance of particular waves on semi-infinite modulated sheets downstream from the nozzle exit. Nonlinear steady-state solutions for the conical configuration (without modulation) are illustrated. Comparison between nonlinear and linear numerical and linear analytical solutions for temporally or spatially developing sheets provides detailed information on the nonlinear distortion characteristics including nonlinear wave propagation and mode-coupling for all the considered geometric configurations and for a variety of parameter configurations. Sensitivity studies on the influence of Weber number, modulation frequency, annular radius, forcing amplitude and sheet divergence on breakup or collapse length and times are reported for modulated semi-infinite annular and conical sheets. Comparisons between the different geometric configurations are made. For periodically disturbed planar sheets, accuracy of the employed reduced-dimension approach is demonstrated by comparison with more accurate two-dimensional vortex dynamics simulations.

Molecular simulation insights on the in vacuo adsorption of amino acids on graphene oxide surfaces with varying surface oxygen densities

NASA Astrophysics Data System (ADS)

Rahmani, Farzin; Nouranian, Sasan; Mahdavi, Mina; Al-Ostaz, Ahmed

2016-11-01

In this fundamental study, a series of molecular dynamics simulations were performed in vacuo to investigate the energetics and select geometries of 20 standard amino acids (AAs) on pristine graphene (PG) and graphene oxide (GO) surfaces as a function of graphene surface oxygen density. These interactions are of key interest to graphene/biomolecular systems. Our results indicate that aromatic AAs exhibit the strongest total interactions with the PG surfaces due to π-π stacking. Tryptophan (Trp) has the highest aromaticity due to its indole side chain and, hence, has the strongest interaction among all AAs (-16.66 kcal/mol). Aliphatic, polar, and charged AAs show various levels of affinity to the PG sheets depending on the strength of their side chain hydrophobic interactions. For example, arginine (Arg) with its guanidinium side chain exhibits the strongest interaction with the PG sheets (-13.81 kcal/mol) following aromatic AAs. Also, glycine (Gly; a polar AA) has the weakest interaction with the PG sheets (-7.29 kcal/mol). When oxygen-containing functional groups are added to the graphene sheets, the π-π stacking in aromatic AAs becomes disrupted and perfect parallelism of the aromatic rings is lost. Moreover, hydrogen bonding and/or electrostatic interactions become more pronounced. Charged AAs exhibit the strongest interactions with the GO surfaces. In general, the AA-GO interactions increase with increasing surface oxygen density, and the effect is more pronounced at higher O/C ratios. This study provides a quantitative measure of AA-graphene interactions for the design and tuning of biomolecular systems suitable for biosensing, drug delivery, and gene delivery applications.

Evolution of a Greenland Ice sheet Including Shelves and Regional Sea Level Variations

NASA Astrophysics Data System (ADS)

Bradley, S.; Reerink, T.; Vandewal, R.; Helsen, M.

2015-12-01

Observational evidence, including offshore moraines and marine sediment cores infer that at the Last Glacial maximum (LGM) the Greenland ice sheet (GIS) grounded out across the Davis Strait into Baffin Bay, with fast flowing ice streams extending out to the continental shelf break along the NW margin. These observations lead to a number of questions as to weather the GIS and Laurentide ice sheet (LIS) coalesced during glacial maximums, and if so, did a significant ice shelf develop across Baffin Bay and how would such a configuration impact on the relative contribution of these ice sheets to eustatic sea level (ESL). Most previous paleo ice sheet modelling simulations of the GIS recreated an ice sheet that either did not extend out onto the continental shelf or utilised a simplified marine ice parameterisation to recreate an extended GIS, and therefore did not fully include ice shelf dynamics. In this study we simulate the evolution of the GIS from 220 kyr BP to present day using IMAU-ice; a 3D thermodynamical ice sheet model which fully accounts for grounded and floating ice, calculates grounding line migration and ice shelf dynamics. There is few observational estimates of long-term (yrs) sub marine basal melting rates (mbm) for the GIS. Therefore we investigate a range of relationships to constrain the spatial and temporal parameterisation of mbm within IMAU-ice related to changes in paleo water depth, driven by changes in relative sea level and ocean temperature. We will present results of how changes in the mbm directly impacts on the ice sheet dynamics, timing and spatial extent of the GIS at the glacial maximums, but also on the rate of retreat and spatial extent at the Last interglacial (LIG) minimum. Initial results indicate that with the inclusion of ice shelf dynamics, a larger GIS is generated which is grounded out into Davis strait, up to a water depth of -750 m, but the total contribution to LIG ESL is reduced by up to 0.6 m.

Extracting electron transfer coupling elements from constrained density functional theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu Qin; Van Voorhis, Troy

2006-10-28

Constrained density functional theory (DFT) is a useful tool for studying electron transfer (ET) reactions. It can straightforwardly construct the charge-localized diabatic states and give a direct measure of the inner-sphere reorganization energy. In this work, a method is presented for calculating the electronic coupling matrix element (H{sub ab}) based on constrained DFT. This method completely avoids the use of ground-state DFT energies because they are known to irrationally predict fractional electron transfer in many cases. Instead it makes use of the constrained DFT energies and the Kohn-Sham wave functions for the diabatic states in a careful way. Test calculationsmore » on the Zn{sub 2}{sup +} and the benzene-Cl atom systems show that the new prescription yields reasonable agreement with the standard generalized Mulliken-Hush method. We then proceed to produce the diabatic and adiabatic potential energy curves along the reaction pathway for intervalence ET in the tetrathiafulvalene-diquinone (Q-TTF-Q) anion. While the unconstrained DFT curve has no reaction barrier and gives H{sub ab}{approx_equal}17 kcal/mol, which qualitatively disagrees with experimental results, the H{sub ab} calculated from constrained DFT is about 3 kcal/mol and the generated ground state has a barrier height of 1.70 kcal/mol, successfully predicting (Q-TTF-Q){sup -} to be a class II mixed-valence compound.« less

ELUCID - Exploring the Local Universe with ReConstructed Initial Density Field III: Constrained Simulation in the SDSS Volume

NASA Astrophysics Data System (ADS)

Wang, Huiyuan; Mo, H. J.; Yang, Xiaohu; Zhang, Youcai; Shi, JingJing; Jing, Y. P.; Liu, Chengze; Li, Shijie; Kang, Xi; Gao, Yang

2016-11-01

A method we developed recently for the reconstruction of the initial density field in the nearby universe is applied to the Sloan Digital Sky Survey Data Release 7. A high-resolution N-body constrained simulation (CS) of the reconstructed initial conditions, with 30723 particles evolved in a 500 {h}-1 {Mpc} box, is carried out and analyzed in terms of the statistical properties of the final density field and its relation with the distribution of Sloan Digital Sky Survey galaxies. We find that the statistical properties of the cosmic web and the halo populations are accurately reproduced in the CS. The galaxy density field is strongly correlated with the CS density field, with a bias that depends on both galaxy luminosity and color. Our further investigations show that the CS provides robust quantities describing the environments within which the observed galaxies and galaxy systems reside. Cosmic variance is greatly reduced in the CS so that the statistical uncertainties can be controlled effectively, even for samples of small volumes.

TH-AB-209-04: 3D Light Sheet Luminescence Imaging with Cherenkov Radiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bruza, P; Lin, H; Jarvis, L

Purpose: To recover a three-dimensional density distribution of luminescent molecular probes located several centimeters deep within a highly scattering tissue. Methods: We developed a novel sheet beam Cherenkov-excited luminescence scanned imaging (CELSI) methodology. The sample was irradiated by a horizontally oriented, vertically scanned 6 MV X-ray sheet beam (200mm × 5mm, 0.2mm vertical step) from a radiotherapy linear accelerator. The resulting Cherenkov light emission – and thus luminescent probe excitation – occurred exclusively along the irradiation plane due to a short diffusion path of secondary particles and Cherenkov photons. Cherenkov-excited luminescence was detected orthogonally to the sheet beam by gated,more » intensified charge coupled device camera. Analogously to light sheet microscopy, a series of luminescence images was taken for varied axial positions (depths) of the Cherenkov light sheet in sample. Knowledge of the excitation plane position allowed a 3D image stack deconvolution and depth-variant attenuation correction. The 3D image post-processing yielded a true spatial density distribution of luminescent molecules in highly scattering tissue. Results: We recovered a three-dimensional shape and position of 400 µL lesion-mimicking phantom tubes containing 25 µM solution of PtG4 molecular probe from 3 centimeter deep tissue-like media. The high sensitivity of CELSI also allowed resolving 100 micron capillaries of test solution. Functional information of partial oxygen pressure at the site of PtG4 molecular probe was recovered from luminescence lifetime CELSI. Finally, in-vivo sheet beam CELSI localized milimeter-sized PtG4-labelled tumor phantoms in multiple biological objects (hairless mice) from single scan. Conclusion: Presented sheet beam CELSI technique greatly extended the useful depth range of luminescence molecular imaging. More importantly, the light sheet microscopy approach was successfully adapted to CELSI, providing means to recover a completely attenuation-corrected 3D image of luminescent probe distribution. Gated CELSI acquisition yielded functional information of a spatially resolved oxygen concentration map of deep lying targets. This work was supported by NIH research grant R01CA109558 and R21EB017559, as well as by Pilot Grant Funds from the Norris Cotton Cancer Center.« less

Electro-thermo-mechanical coupling analysis of deep drawing with resistance heating for aluminum matrix composites sheet

NASA Astrophysics Data System (ADS)

Zhang, Kaifeng; Zhang, Tuoda; Wang, Bo

2013-05-01

Recently, electro-plastic forming to be a focus of attention in materials hot processing research area, because it is a sort of energy-saving, high efficient and green manufacturing technology. An electro-thermo-mechanical model can be adopted to carry out the sequence simulation of aluminum matrix composites sheet deep drawing via electro-thermal coupling and thermal-mechanical coupling method. The first step of process is resistance heating of sheet, then turn off the power, and the second step is deep drawing. Temperature distribution of SiCp/2024Al composite sheet by resistance heating and sheet deep drawing deformation were analyzed. During the simulation, effect of contact resistances, temperature coefficient of resistance for electrode material and SiCp/2024Al composite on temperature distribution were integrally considered. The simulation results demonstrate that Sicp/2024Al composite sheet can be rapidly heated to 400° in 30s using resistances heating and the sheet temperature can be controlled by adjusting the current density. Physical properties of the electrode materials can significantly affect the composite sheet temperature distribution. The temperature difference between the center and the side of the sheet is proportional to the thermal conductivity of the electrode, the principal cause of which is that the heat transfers from the sheet to the electrode. SiCp/2024Al thin-wall part can be intactly manufactured at strain rate of 0.08s-1 and the sheet thickness thinning rate is limited within 20%, which corresponds well to the experimental result.

Ground-state densities from the Rayleigh-Ritz variation principle and from density-functional theory.

PubMed

Kvaal, Simen; Helgaker, Trygve

2015-11-14

The relationship between the densities of ground-state wave functions (i.e., the minimizers of the Rayleigh-Ritz variation principle) and the ground-state densities in density-functional theory (i.e., the minimizers of the Hohenberg-Kohn variation principle) is studied within the framework of convex conjugation, in a generic setting covering molecular systems, solid-state systems, and more. Having introduced admissible density functionals as functionals that produce the exact ground-state energy for a given external potential by minimizing over densities in the Hohenberg-Kohn variation principle, necessary and sufficient conditions on such functionals are established to ensure that the Rayleigh-Ritz ground-state densities and the Hohenberg-Kohn ground-state densities are identical. We apply the results to molecular systems in the Born-Oppenheimer approximation. For any given potential v ∈ L(3/2)(ℝ(3)) + L(∞)(ℝ(3)), we establish a one-to-one correspondence between the mixed ground-state densities of the Rayleigh-Ritz variation principle and the mixed ground-state densities of the Hohenberg-Kohn variation principle when the Lieb density-matrix constrained-search universal density functional is taken as the admissible functional. A similar one-to-one correspondence is established between the pure ground-state densities of the Rayleigh-Ritz variation principle and the pure ground-state densities obtained using the Hohenberg-Kohn variation principle with the Levy-Lieb pure-state constrained-search functional. In other words, all physical ground-state densities (pure or mixed) are recovered with these functionals and no false densities (i.e., minimizing densities that are not physical) exist. The importance of topology (i.e., choice of Banach space of densities and potentials) is emphasized and illustrated. The relevance of these results for current-density-functional theory is examined.

Slow Mode Waves in the Heliospheric Plasma Sheet

NASA Technical Reports Server (NTRS)

Smith, Edward. J.; Zhou, Xiaoyan

2007-01-01

We report the results of a search for waves/turbulence in the Heliospheric Plasma Sheet (HPS) surrounding the Heliospheric Current Sheet (HCS). The HPS is treated as a distinctive heliospheric structure distinguished by relatively high Beta, slow speed plasma. The data used in the investigation are from a previously published study of the thicknesses of the HPS and HCS that were obtained in January to May 2004 when Ulysses was near aphelion at 5 AU. The advantage of using these data is that the HPS is thicker at large radial distances and the spacecraft spends longer intervals inside the plasma sheet. From the study of the magnetic field and solar wind velocity components, we conclude that, if Alfven waves are present, they are weak and are dominated by variations in the field magnitude, B, and solar wind density, NP, that are anti-correlated.

Two-dimensional boron: Lightest catalyst for hydrogen and oxygen evolution reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mir, Showkat H.; Chakraborty, Sudip, E-mail: sudiphys@gmail.com, E-mail: prakash.jha@cug.ac.in; Wärnå, John

The hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) have been envisaged on a two-dimensional (2D) boron sheet through electronic structure calculations based on a density functional theory framework. To date, boron sheets are the lightest 2D material and, therefore, exploring the catalytic activity of such a monolayer system would be quite intuitive both from fundamental and application perspectives. We have functionalized the boron sheet (BS) with different elemental dopants like carbon, nitrogen, phosphorous, sulphur, and lithium and determined the adsorption energy for each case while hydrogen and oxygen are on top of the doping site of themore » boron sheet. The free energy calculated from the individual adsorption energy for each functionalized BS subsequently guides us to predict which case of functionalization serves better for the HER or the OER.« less

Constraints on particle density evolution within a CME at Mercury

NASA Astrophysics Data System (ADS)

Exner, W.; Liuzzo, L.; Heyner, D.; Feyerabend, M.; Motschmann, U. M.; Glassmeier, K. H.; Shiota, D.; Kusano, K.

2017-12-01

Mercury (RM=2440) is the closest orbiting planet around the Sun and is embedded in an intensive and highly varying solar wind.Mercury's intrinsic dipole with a southward magnetic moment is aligned with the rotation axis and has a northward offset of 0.2 RM.In-situ data from the MESSENGER spacecraft of the magnetic environment near Mercury indicate that a coronal mass ejection (CME) passed the planet on 8 May 2012. The data constrain the direction and magnitude of the CME magnetic field but no information on its particle density could be determined.We apply the hybrid (kinetic ions, electron fluid) code A.I.K.E.F. to study the interaction of Mercury's magnetosphere with the CME.We use MESSENGER magnetic field observations as well as simulation results to constrain the evolution of the particle density inside the CME.We show that within a 24-hour period the particle density within the CME had to vary between 1-100 cm-3 in order to explain MESSENGER magnetic field observations.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fattoyev, F. J.; Piekarewicz, J.

The sensitivity of the stellar moment of inertia to the neutron-star matter equation of state is examined using accurately calibrated relativistic mean-field models. We probe this sensitivity by tuning both the density dependence of the symmetry energy and the high-density component of the equation of state, properties that are at present poorly constrained by existing laboratory data. Particularly attractive is the study of the fraction of the moment of inertia contained in the solid crust. Analytic treatments of the crustal moment of inertia reveal a high sensitivity to the transition pressure at the core-crust interface. This may suggest the existencemore » of a strong correlation between the density dependence of the symmetry energy and the crustal moment of inertia. However, no correlation was found. We conclude that constraining the density dependence of the symmetry energy - through, for example, the measurement of the neutron skin thickness in {sup 208}Pb - will place no significant bound on either the transition pressure or the crustal moment of inertia.« less

Electron flat-top distributions and cross-scale wave modulations observed in the current sheet of geomagnetic tail

NASA Astrophysics Data System (ADS)

Zhao, Duo; Fu, Suiyan; Parks, George K.; Sun, Weijie; Zong, Qiugang; Pan, Dongxiao; Wu, Tong

2017-08-01

We present new observations of electron distributions and the accompanying waves during the current sheet activities at ˜60 RE in the geomagnetic tail detected by the ARTEMIS (Acceleration, Reconnection, Turbulence, and Electrodynamics of the Moon's Interaction with the Sun) spacecraft. We find that electron flat-top distribution is a common feature near the neutral sheet of the tailward flowing plasmas, consistent with the electron distributions that are shaped in the reconnection region. Whistler mode waves are generated by the anisotropic electron temperature associated with the electron flat-top distributions. These whistler mode waves are modulated by low frequency ion scale waves that are possibly excited by the high-energy ions injected during the current sheet instability. The magnetic and electric fields of the ion scale waves are in phase with electron density variations, indicating that they are compressional ion cyclotron waves. Our observations present examples of the dynamical processes occurring during the current sheet activities far downstream of the geomagnetic tail.

Collisionless current sheet equilibria

NASA Astrophysics Data System (ADS)

Neukirch, T.; Wilson, F.; Allanson, O.

2018-01-01

Current sheets are important for the structure and dynamics of many plasma systems. In space and astrophysical plasmas they play a crucial role in activity processes, for example by facilitating the release of magnetic energy via processes such as magnetic reconnection. In this contribution we will focus on collisionless plasma systems. A sensible first step in any investigation of physical processes involving current sheets is to find appropriate equilibrium solutions. The theory of collisionless plasma equilibria is well established, but over the past few years there has been a renewed interest in finding equilibrium distribution functions for collisionless current sheets with particular properties, for example for cases where the current density is parallel to the magnetic field (force-free current sheets). This interest is due to a combination of scientific curiosity and potential applications to space and astrophysical plasmas. In this paper we will give an overview of some of the recent developments, discuss their potential applications and address a number of open questions.

Thermal management of thermoacoustic sound projectors using a free-standing carbon nanotube aerogel sheet as a heat source.

PubMed

Aliev, Ali E; Mayo, Nathanael K; Baughman, Ray H; Avirovik, Dragan; Priya, Shashank; Zarnetske, Michael R; Blottman, John B

2014-10-10

Carbon nanotube (CNT) aerogel sheets produce smooth-spectra sound over a wide frequency range (1-10(5) Hz) by means of thermoacoustic (TA) sound generation. Protective encapsulation of CNT sheets in inert gases between rigid vibrating plates provides resonant features for the TA sound projector and attractive performance at needed low frequencies. Energy conversion efficiencies in air of 2% and 10% underwater, which can be enhanced by further increasing the modulation temperature. Using a developed method for accurate temperature measurements for the thin aerogel CNT sheets, heat dissipation processes, failure mechanisms, and associated power densities are investigated for encapsulated multilayered CNT TA heaters and related to the thermal diffusivity distance when sheet layers are separated. Resulting thermal management methods for high applied power are discussed and deployed to construct efficient and tunable underwater sound projector for operation at relatively low frequencies, 10 Hz-10 kHz. The optimal design of these TA projectors for high-power SONAR arrays is discussed.

Simultaneous Denoising, Deconvolution, and Demixing of Calcium Imaging Data

PubMed Central

Pnevmatikakis, Eftychios A.; Soudry, Daniel; Gao, Yuanjun; Machado, Timothy A.; Merel, Josh; Pfau, David; Reardon, Thomas; Mu, Yu; Lacefield, Clay; Yang, Weijian; Ahrens, Misha; Bruno, Randy; Jessell, Thomas M.; Peterka, Darcy S.; Yuste, Rafael; Paninski, Liam

2016-01-01

SUMMARY We present a modular approach for analyzing calcium imaging recordings of large neuronal ensembles. Our goal is to simultaneously identify the locations of the neurons, demix spatially overlapping components, and denoise and deconvolve the spiking activity from the slow dynamics of the calcium indicator. Our approach relies on a constrained nonnegative matrix factorization that expresses the spatiotemporal fluorescence activity as the product of a spatial matrix that encodes the spatial footprint of each neuron in the optical field and a temporal matrix that characterizes the calcium concentration of each neuron over time. This framework is combined with a novel constrained deconvolution approach that extracts estimates of neural activity from fluorescence traces, to create a spatiotemporal processing algorithm that requires minimal parameter tuning. We demonstrate the general applicability of our method by applying it to in vitro and in vivo multineuronal imaging data, whole-brain light-sheet imaging data, and dendritic imaging data. PMID:26774160

Multifunctional smart composites with integrated carbon nanotube yarn and sheet

NASA Astrophysics Data System (ADS)

Chauhan, Devika; Hou, Guangfeng; Ng, Vianessa; Chaudhary, Sumeet; Paine, Michael; Moinuddin, Khwaja; Rabiee, Massoud; Cahay, Marc; Lalley, Nicholas; Shanov, Vesselin; Mast, David; Liu, Yijun; Yin, Zhangzhang; Song, Yi; Schulz, Mark

2017-04-01

Multifunctional smart composites (MSCs) are materials that combine the good electrical and thermal conductivity, high tensile and shear strength, good impact toughness, and high stiffness properties of metals; the light weight and corrosion resistance properties of composites; and the sensing or actuation properties of smart materials. The basic concept for MSCs was first conceived by Daniel Inman and others about 25 years ago. Current laminated carbon and glass fiber polymeric composite materials have high tensile strength and are light in weight, but they still lack good electrical and thermal conductivity, and they are sensitive to delamination. Carbon nanotube yarn and sheets are lightweight, electrically and thermally conductive materials that can be integrated into laminated composite materials to form MSCs. This paper describes the manufacturing of high quality carbon nanotube yarn and sheet used to form MSCs, and integrating the nanotube yarn and sheet into composites at low volume fractions. Various up and coming technical applications of MSCs are discussed including composite toughening for impact and delamination resistance; structural health monitoring; and structural power conduction. The global carbon nanotube overall market size is estimated to grow from 2 Billion in 2015 to 5 Billion by 2020 at a CAGR of 20%. Nanotube yarn and sheet products are predicted to be used in aircraft, wind machines, automobiles, electric machines, textiles, acoustic attenuators, light absorption, electrical wire, sporting equipment, tires, athletic apparel, thermoelectric devices, biomedical devices, lightweight transformers, and electromagnets. In the future, due to the high maximum current density of nanotube conductors, nanotube electromagnetic devices may also become competitive with traditional smart materials in terms of power density.

Porous Ni3(NO3)2(OH)4 nano-sheets for supercapacitors: Facile synthesis and excellent rate performance at high mass loadings

NASA Astrophysics Data System (ADS)

Shi, Mingjie; Cui, Mangwei; Kang, Litao; Li, Taotao; Yun, Shan; Du, Jing; Xu, Shoudong; Liu, Ying

2018-01-01

For supercapacitors, pores in electrode materials can accelerate chemical reaction kinetics by shortening ion diffusion distances and by enlarging electrolyte/electrode interfaces. This article describes a simple one-step route for the preparation of pure-phase porous Ni3(NO3)2(OH)4 nano-sheets by directly heating a mild Ni(NO3)2 and urea solution. During heating, urea decomposed into NH3·H2O, which provided a suitable alkaline environment for the formation of Ni3(NO3)2(OH)4 nano-sheets. Meanwhile, the side product, NH4NO3, created numerous pores as a pore-forming agent. After NH4NO3 removal, the specific surface areas and pore volumes of products were boosted by ∼180-times (from 0.61 to 113.12 m2/g) and ∼90-times (from 3.40 × 10-3 to 3.17 × 10-1 m2/g), respectively. As a cathode material of supercapacitor, the porous Ni3(NO3)2(OH)4 nano-sheets exhibited a high specific capacitance of 1094 F/g at an ultrahigh mass loading of 17.55 mg/cm2, leading to an impressive areal capacitance of 19.2 F/cm2. Furthermore, a Ni3(NO3)2(OH)4 nano-sheet//commercial active carbon asymmetric supercapacitor was constructed and delivered an energy density of 33.2 Wh/Kg at a power density of 190.5 W/Kg, based on the mass of active materials on both electrodes.

Radar Detection of Layering in Ice: Experiments on a Constructed Layered Ice Sheet

NASA Astrophysics Data System (ADS)

Carter, L. M.; Koenig, L.; Courville, Z.; Ghent, R. R.; Koutnik, M. R.

2016-12-01

The polar caps and glaciers of both Earth and Mars display internal layering that preserves a record of past climate. These layers are apparent both in optical datasets (high resolution images, core samples) and in ground penetrating radar (GPR) data. On Mars, the SHARAD (Shallow Radar) radar on the Mars Reconnaissance Orbiter shows fine layering that changes spatially and with depth across the polar caps. This internal layering has been attributed to changes in fractional dust contamination due to obliquity-induced climate variations, but there are other processes that can lead to internal layers visible in radar data. In particular, terrestrial sounding of ice sheets compared with core samples have revealed that ice density and composition differences account for the majority of the radar reflectors. The large cold rooms and ice laboratory facility at the U.S. Army Cold Regions Research and Engineering Laboratory (CRREL) provide us a unique opportunity to construct experimental ice sheets in a controlled setting and measure them with radar. In a CRREL laboratory, we constructed a layered ice sheet that is 3-m deep with a various snow and ice layers with known dust concentrations (using JSC Mars-1 basaltic simulant) and density differences. These ice sheets were profiled using a commercial GPR, at frequencies of 200, 400 and 900 MHz, to determine how the radar profile changes due to systematic and known changes in snow and ice layers, including layers with sub-wavelength spacing. We will report results from these experiments and implications for interpreting radar-detected layering in ice on Earth and Mars.

Superhydrophobic hybrid membranes by grafting arc-like macromolecular bridges on graphene sheets: Synthesis, characterization and properties

NASA Astrophysics Data System (ADS)

Mo, Zhao-Hua; Luo, Zheng; Huang, Qiang; Deng, Jian-Ping; Wu, Yi-Xian

2018-05-01

Grafting single end-tethered polymer chains on the surface of graphene is a conventional way to modify the surface properties of graphene oxide. However, grafting arc-like macromolecular bridges on graphene surfaces has been barely reported. Herein, a novel arc-like polydimethylsiloxane (PDMS) macromolecular bridges grafted graphene sheets (GO-g-Arc PDMS) was successfully synthesized via a confined interface reaction at 90 °C. Both the hydrophilic α- and ω-amino groups of linear hydrophobic NH2-PDMS-NH2 macromolecular chains rapidly reacted with epoxy and carboxyl groups on the surfaces of graphene oxide in water suspension to form arc-like PDMS macromolecular bridges on graphene sheets. The grafting density of arc-like PDMS bridges on graphene sheets can reach up to 0.80 mmol g-1 or 1.32 arc-like bridges per nm2 by this confined interface reaction. The water contact angle (WCA) of the hybrid membrane could be increased with increasing both the grafting density and content of covalent arc-like bridges architecture. The superhydrophobic hybrid membrane with a WCA of 153.4° was prepared by grinding of the above arc-like PDMS bridges grafted graphene hybrid, dispersing in ethanol and filtrating by organic filter membrane. This superhydrophobic hybrid membrane shows good self-cleaning and complete oil-water separation properties, which provides potential applications in anticontamination coating and oil-water separation. To the best of our knowledge, this is the first report on the synthesis of functional hybrid membranes by grafting arc-like PDMS macromolecular bridges on graphene sheets via a confined interface reaction.

Mass transfer of hydrophobic organic chemicals between silicone sheets and through plant leaves and low-density polyethylene.

PubMed

Ahmadi, Hamid; Bolinius, Damien Johann; Jahnke, Annika; MacLeod, Matthew

2016-12-01

Plant leaves play an important role in the fate of hydrophobic organic contaminants (HOCs) in the environment. Yet much remains unknown about the permeability of leaves by HOCs. In this pilot study we measured (i) the kinetics of mass transfer of three polycyclic aromatic hydrocarbons (PAHs) and six polychlorinated biphenyls between a spiked and an unspiked sheet of polydimethylsiloxane (PDMS) in direct contact with each other for 24 h and (ii) kinetics of mass transfer of two PAHs through leaves and low-density polyethylene (LDPE) in a passive dosing experiment by inserting these matrices between the two sheets of PDMS for 48 h. The kinetics of mass transfer of fluoranthene between PDMS sheets in direct contact were a factor of 12 slower than those reported in the literature. The kinetics of mass transfer of fluorene and phenanthrene through leaves were within the range of those previously reported for 2,4-dichlorophenoxyacetic acid through isolated cuticles. Our results provide a proof-of-concept demonstration that the passive dosing method applied in this study can be used to measure the mass transfer coefficients of organic chemicals through leaves. Key recommendations for future experiments are to load the PDMS at the highest feasible concentrations to avoid working at analyte levels close to the limit of detection, to keep the leaves moist and to minimize potential pathways for contamination of the PDMS sheets by exposure to laboratory air. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

High current density sheet-like electron beam generator

NASA Astrophysics Data System (ADS)

Chow-Miller, Cora; Korevaar, Eric; Schuster, John

Sheet electron beams are very desirable for coupling to the evanescent waves in small millimeter wave slow-wave circuits to achieve higher powers. In particular, they are critical for operation of the free-electron-laser-like Orotron. The program was a systematic effort to establish a solid technology base for such a sheet-like electron emitter system that will facilitate the detailed studies of beam propagation stability. Specifically, the effort involved the design and test of a novel electron gun using Lanthanum hexaboride (LaB6) as the thermionic cathode material. Three sets of experiments were performed to measure beam propagation as a function of collector current, beam voltage, and heating power. The design demonstrated its reliability by delivering 386.5 hours of operation throughout the weeks of experimentation. In addition, the cathode survived two venting and pump down cycles without being poisoned or losing its emission characteristics. A current density of 10.7 A/sq cm. was measured while operating at 50 W of ohmic heating power. Preliminary results indicate that the nearby presence of a metal plate can stabilize the beam.

Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries.

PubMed

Dash, Ranjan; Pannala, Sreekanth

2016-06-17

Silicon (Si) is under consideration as a potential next-generation anode material for the lithium ion battery (LIB). Experimental reports of up to 40% increase in energy density of Si anode based LIBs (Si-LIBs) have been reported in literature. However, this increase in energy density is achieved when the Si-LIB is allowed to swell (volumetrically expand) more than graphite based LIB (graphite-LIB) and beyond practical limits. The volume expansion of LIB electrodes should be negligible for applications such as automotive or mobile devices. We determine the theoretical bounds of Si composition in a Si-carbon composite (SCC) based anode to maximize the volumetric energy density of a LIB by constraining the external dimensions of the anode during charging. The porosity of the SCC anode is adjusted to accommodate the volume expansion during lithiation. The calculated threshold value of Si was then used to determine the possible volumetric energy densities of LIBs with SCC anode (SCC-LIBs) and the potential improvement over graphite-LIBs. The level of improvement in volumetric and gravimetric energy density of SCC-LIBs with constrained volume is predicted to be less than 10% to ensure the battery has similar power characteristics of graphite-LIBs.

Communication: phase transitions, criticality, and three-phase coexistence in constrained cell models.

PubMed

Nayhouse, Michael; Kwon, Joseph Sang-Il; Orkoulas, G

2012-05-28

In simulation studies of fluid-solid transitions, the solid phase is usually modeled as a constrained system in which each particle is confined to move in a single Wigner-Seitz cell. The constrained cell model has been used in the determination of fluid-solid coexistence via thermodynamic integration and other techniques. In the present work, the phase diagram of such a constrained system of Lennard-Jones particles is determined from constant-pressure simulations. The pressure-density isotherms exhibit inflection points which are interpreted as the mechanical stability limit of the solid phase. The phase diagram of the constrained system contains a critical and a triple point. The temperature and pressure at the critical and the triple point are both higher than those of the unconstrained system due to the reduction in the entropy caused by the single occupancy constraint.

Mantle viscosity structure constrained by joint inversions of seismic velocities and density

NASA Astrophysics Data System (ADS)

Rudolph, M. L.; Moulik, P.; Lekic, V.

2017-12-01

The viscosity structure of Earth's deep mantle affects the thermal evolution of Earth, the ascent of mantle upwellings, sinking of subducted oceanic lithosphere, and the mixing of compositional heterogeneities in the mantle. Modeling the long-wavelength dynamic geoid allows us to constrain the radial viscosity profile of the mantle. Typically, in inversions for the mantle viscosity structure, wavespeed variations are mapped into density variations using a constant- or depth-dependent scaling factor. Here, we use a newly developed joint model of anisotropic Vs, Vp, density and transition zone topographies to generate a suite of solutions for the mantle viscosity structure directly from the seismologically constrained density structure. The density structure used to drive our forward models includes contributions from both thermal and compositional variations, including important contributions from compositionally dense material in the Large Low Velocity Provinces at the base of the mantle. These compositional variations have been neglected in the forward models used in most previous inversions and have the potential to significantly affect large-scale flow and thus the inferred viscosity structure. We use a transdimensional, hierarchical, Bayesian approach to solve the inverse problem, and our solutions for viscosity structure include an increase in viscosity below the base of the transition zone, in the shallow lower mantle. Using geoid dynamic response functions and an analysis of the correlation between the observed geoid and mantle structure, we demonstrate the underlying reason for this inference. Finally, we present a new family of solutions in which the data uncertainty is accounted for using covariance matrices associated with the mantle structure models.

Understanding the dust cycle at high latitudes: integrating models and observations

NASA Astrophysics Data System (ADS)

Albani, S.; Mahowald, N. M.; Maggi, V.; Delmonte, B.; Winckler, G.; Potenza, M. A. C.; Baccolo, G.; Balkanski, Y.

2017-12-01

Changing climate conditions affect dust emissions and the global dust cycle, which in turn affects climate and biogeochemistry. Paleodust archives from land, ocean, and ice sheets preserve the history of dust deposition for a range of spatial scales from close to the major hemispheric sources to remote sinks such as the polar ice sheets. In each hemisphere common features on the glacial-interglacial time scale mark the baseline evolution of the dust cycle, and inspired the hypothesis that increased dust deposition to ocean stimulated the glacial biological pump contributing to the reduction of atmospheric carbon dioxide levels. On the other hand finer geographical and temporal scales features are superposed to these glacial-interglacial trends, providing the chance of a more sophisticated understanding of the dust cycle, for instance allowing distinctions in terms of source availability or transport patterns as recorded by different records. As such paleodust archives can prove invaluable sources of information, especially when characterized by a quantitative estimation of the mass accumulation rates, and interpreted in connection with climate models. We review our past work and present ongoing research showing how climate models can help in the interpretation of paleodust records, as well as the potential of the same observations for constraining the representation of the global dust cycle embedded in Earth System Models, both in terms of magnitude and physical parameters related to particle sizes and optical properties. Finally we show the impacts on climate, based on this kind of observationally constrained model simulations.

Reconstruction of a Large-scale Pre-flare Coronal Current Sheet Associated with a Homologous X-shaped Flare

NASA Astrophysics Data System (ADS)

Jiang, Chaowei; Yan, Xiaoli; Feng, Xueshang; Duan, Aiying; Hu, Qiang; Zuo, Pingbing; Wang, Yi

2017-11-01

As a fundamental magnetic structure in the solar corona, electric current sheets (CSs) can form either prior to or during a solar flare, and they are essential for magnetic energy dissipation in the solar corona because they enable magnetic reconnection. However, the static reconstruction of a CS is rare, possibly due to limitations that are inherent in the available coronal field extrapolation codes. Here we present the reconstruction of a large-scale pre-flare CS in solar active region 11967 using an MHD-relaxation model constrained by the SDO/HMI vector magnetogram. The CS is associated with a set of peculiar homologous flares that exhibit unique X-shaped ribbons and loops occurring in a quadrupolar magnetic configuration.This is evidenced by an ’X’ shape, formed from the field lines traced from the CS to the photosphere. This nearly reproduces the shape of the observed flare ribbons, suggesting that the flare is a product of the dissipation of the CS via reconnection. The CS forms in a hyperbolic flux tube, which is an intersection of two quasi-separatrix layers. The recurrence of the X-shaped flares might be attributed to the repetitive formation and dissipation of the CS, as driven by the photospheric footpoint motions. These results demonstrate the power of a data-constrained MHD model in reproducing a CS in the corona as well as providing insight into the magnetic mechanism of solar flares.

Methods for Tier 1 Modeling within the Training Range Environmental Evaluation and Characterization System

DTIC Science & Technology

2009-08-01

properties, part b. USLE K-Factor by Organic Matter Content Soil -Texture Classification Dry Bulk Density, g/cm3 Field Capacity, % Available...Universal Soil Loss Equation ( USLE ) can be used to estimate annual average sheet and rill erosion, A (tons/acre-yr), from the equation A R K L S...erodibility factors, K, for various soil classifications and percent organic matter content ( USLE Fact Sheet 2008). Textural Class Average Less than 2

Effective Elastic and Neutron Capture Cross Section Calculations Corresponding to Simulated Fluid Properties from CO2 Push-Pull Simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chugunov, Nikita; Altundas, Bilgin

The submission contains a .xls files consisting of 10 excel sheets, which contain combined list of pressure, saturation, salinity, temperature profiles from the simulation of CO2 push-pull using Brady reservoir model and the corresponding effective compressional and shear velocity, bulk density, and fluid and time-lapse neutron capture cross section profiles of rock at times 0 day (baseline) through 14 days. First 9 sheets (each named after the corresponding CO2 push-pull simulation time) contains simulated pressure, saturation, temperature, salinity profiles and the corresponding effective elastic and neutron capture cross section profiles of rock matrix at the time of CO2 injection. Eachmore » sheet contains two sets of effective compressional velocity profiles of the rock, one based on Gassmann and the other based on Patchy saturation model. Effective neutron capture cross section calculations are done using a proprietary neutron cross-section simulator (SNUPAR) whereas for the thermodynamic properties of CO2 and bulk density of rock matrix filled with fluid, a standalone fluid substitution tool by Schlumberger is used. Last sheet in the file contains the bulk modulus of solid rock, which is inverted from the rock properties (porosity, sound speed etc) based on Gassmann model. Bulk modulus of solid rock in turn is used in the fluid substitution.« less

Effects of homogenization treatment on recrystallization behavior of 7150 aluminum sheet during post-rolling annealing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guo, Zhanying; Department of Applied Science, University of Québec at Chicoutimi, Saguenay, QC G7H 2B1; Zhao, Gang

2016-04-15

The effects of two homogenization treatments applied to the direct chill (DC) cast billet on the recrystallization behavior in 7150 aluminum alloy during post-rolling annealing have been investigated using the electron backscatter diffraction (EBSD) technique. Following hot and cold rolling to the sheet, measured orientation maps, the recrystallization fraction and grain size, the misorientation angle and the subgrain size were used to characterize the recovery and recrystallization processes at different annealing temperatures. The results were compared between the conventional one-step homogenization and the new two-step homogenization, with the first step being pretreated at 250 °C. Al{sub 3}Zr dispersoids with highermore » densities and smaller sizes were obtained after the two-step homogenization, which strongly retarded subgrain/grain boundary mobility and inhibited recrystallization. Compared with the conventional one-step homogenized samples, a significantly lower recrystallized fraction and a smaller recrystallized grain size were obtained under all annealing conditions after cold rolling in the two-step homogenized samples. - Highlights: • Effects of two homogenization treatments on recrystallization in 7150 Al sheets • Quantitative study on the recrystallization evolution during post-rolling annealing • Al{sub 3}Zr dispersoids with higher densities and smaller sizes after two-step treatment • Higher recrystallization resistance of 7150 sheets with two-step homogenization.« less

Free-Standing Hybrid Graphene Paper Encapsulating Nanostructures for High Cycle-Life Supercapacitors.

PubMed

Jiao, Xinyan; Hao, Qingli; Xia, Xifeng; Lei, Wu; Ouyang, Yu; Ye, Haitao; Mandler, Daniel

2018-03-09

The incorporation of spacers between graphene sheets has been investigated as an effective method to improve the electrochemical performance of graphene papers (GPs) for supercapacitors. Here, we report the design of free-standing GP@NiO and GP@Ni hybrid GPs in which NiO nanoclusters and Ni nanoparticles are encapsulated into graphene sheets through electrostatic assembly and subsequent vacuum filtration. The encapsulated NiO nanoclusters and Ni nanoparticles can mitigate the restacking of graphene sheets, providing sufficient spaces for high-speed ion diffusion and electron transport. In addition, the spacers strongly bind to graphene sheets, which can efficiently improve the electrochemical stability. Therefore, at a current density of 0.5 A g -1 , the GP@NiO and GP@Ni electrodes exhibit higher specific capacitances of 306.9 and 246.1 F g -1 than the GP electrode (185.7 F g -1 ). The GP@NiO and GP@Ni electrodes exhibit capacitance retention of 98.7 % and 95.6 % after 10000 cycles, demonstrating an outstanding cycling stability. Additionally, the GP@NiO∥GP@Ni delivers excellent cycling stability (93.7 % after 10 000 cycles) and high energy density. These free-standing encapsulated hybrid GPs have great potential as electrode for high-performance supercapacitors. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bouquet-Like Mn2SnO4 Nanocomposite Engineered with Graphene Sheets as an Advanced Lithium-Ion Battery Anode.

PubMed

Rehman, Wasif Ur; Xu, Youlong; Sun, Xiaofei; Ullah, Inam; Zhang, Yuan; Li, Long

2018-05-30

Volume expansion is a major challenge associated with tin oxide (SnO x ), which causes poor cyclability in lithium-ion battery anode. Bare tin dioxide (SnO 2 ), tin dioxide with graphene sheets (SnO 2 @GS), and bouquet-like nanocomposite structure (Mn 2 SnO 4 @GS) are prepared via hydrothermal method followed by annealing. The obtained composite material presents a bouquet structure containing manganese and tin oxide nanoparticle network with graphene sheets. Benefiting from this porous nanostructure, in which graphene sheets provide high electronic pathways to enhance the electronic conductivity, uniformly distributed particles offer accelerated kinetic reaction with lithium ion and reduced volume deviation in the tin dioxide (SnO 2 ) particle during charge-discharge testing. As a consequence, ternary composite Mn 2 SnO 4 @GS showed a high rate performance and outstanding cyclability of anode material for lithium-ion batteries. The electrode achieved a specific capacity of about 1070 mA h g -1 at a current density of 400 mA g -1 after 200 cycles; meanwhile, the electrode still delivered a specific capacity of about 455 mA h g -1 at a high current density of 2500 mA g -1 . Ternary Mn 2 SnO 4 @GS material could facilitate fabrication of unique structure and conductive network as advanced lithium-ion battery.

Low-temperature fabrication of 3D drilled graphene sheets hydrogel for supercapacitors with ultralong cycle life

NASA Astrophysics Data System (ADS)

Qiu, Zenghui; He, Dawei; Wang, Yongsheng; Li, Jiayuan

2017-09-01

A simple cobalt catalyzed gasification strategy to synthesize drilled graphene sheets (DGNs) is performed, and 3D DGNs hydrogel is prepared at a relatively low temperature. Due to mesopore hydrogel structure that increases the charge transfer efficiency by providing pathways for ionic into the overlaps of DGNs hydrogel and hole density displays controllably, the resulting DGNs hydrogel electrode provides excellent rate capability with an ultrahigh specific capacitance of 264.1 F g-1 at 1 A g-1 compared to a value of 187.8 F g-1 for graphene sheets (GNs) pole. DGNs hydrogel expands the design space for developing high-performance energy storage devices.

Fire protection covering for small diameter missiles

NASA Technical Reports Server (NTRS)

Riccitiello, S. R.; Sawko, P. M. (Inventor)

1979-01-01

Flexible intumescent protection sheeting of unusually uniform thickness were prepared from epoxy-polysulfide compositions, containing microfibers and the ammonium salt of 1,4-nitroaniline-2-sulfonic acid, as disclosed in U.S. Pat. No. 3,663,464, except that an ammonium salt particle size in the order of 5 to 8 microns and a fiber size of about 1/128th inch in length and 3 to 5 microns in diameter were found critical to obtain the required density of 1.46 to 1.50 g/cc. The insulation sheeting was prepared by a continuous process involving vacuum mixing, calendering, and curing under very strict conditions which depend to some extent upon the thickness of the sheet produced.

Maps and models of density and stiffness within individual Douglas-fir trees

Treesearch

Christine L. Todoroki; Eini C. Lowell; Dennis P. Dykstra; David G. Briggs

2012-01-01

Spatial maps of density and stiffness patterns within individual trees were developed using two methods: (1) measured wood properties of veneer sheets; and (2) mixed effects models, to test the hypothesis that within-tree patterns could be predicted from easily measurable tree variables (height, taper, breast-height diameter, and acoustic velocity). Sample trees...

Densification behavior of ceramic and crystallizable glass materials constrained on a rigid substrate

NASA Astrophysics Data System (ADS)

Calata, Jesus N.

2005-11-01

Constrained sintering is an important process for many applications. The sintering process almost always involves some form of constraint, both internal and external, such as rigid particles, reinforcing fibers and substrates to which the porous body adheres. The densification behavior of zinc oxide and cordierite-base crystallizable glass constrained on a rigid substrate was studied to add to the understanding of the behavior of various materials undergoing sintering when subjected to external substrate constraint. Porous ZnO films were isothermally sintered at temperatures between 900°C and 1050°C. The results showed that the densification of films constrained on substrates is severely reduced. This was evident in the sintered microstructures where the particles are joined together by narrower necks forming a more open structure, instead of the equiaxed grains with wide grain boundaries observed in the freestanding films. The calculated activation energies of densification were also different. For the density range of 60 to 64%, the constrained film had an activation energy of 391 +/- 34 kJ/mole compared to 242 +/- 21 kJ/mole for the freestanding film, indicating a change in the densification mechanism. In-plane stresses were observed during the sintering of the constrained films. Yielding of the films, in which the stresses dropped slight or remained unchanged, occurred at relative densities below 60% before the stresses climbed linearly with increasing density followed by a gradual relaxation. A substantial amount of the stresses remained after cooling. Free and constrained films of the cordierite-base crystallizable glass (glass-ceramic) were sintered between 900°C and 1000°C. The substrate constraint did not have a significant effect on the densification rate but the constrained films eventually underwent expansion. Calculations of the densification activation energy showed that, on average, it was close to 1077 kJ/mole, the activation energy of the glass, indicating that the prevailing mechanism was still viscous flow. The films expanded earlier and faster with increasing sintering temperature. The expansion was traced to the formation of pores at the interface with the silicon substrate and to a lesser extent on aluminum nitride. It was significantly reduced when the silicon substrate was pre-oxidized at 900°C, leading to the conclusion that the pore formation at the interface was due to poor wetting, which in turn was caused by the loss of the thin oxide layer through a reaction with the glass.

Calculations of Hubbard U from first-principles

NASA Astrophysics Data System (ADS)

Aryasetiawan, F.; Karlsson, K.; Jepsen, O.; Schönberger, U.

2006-09-01

The Hubbard U of the 3d transition metal series as well as SrVO3 , YTiO3 , Ce, and Gd has been estimated using a recently proposed scheme based on the random-phase approximation. The values obtained are generally in good accord with the values often used in model calculations but for some cases the estimated values are somewhat smaller than those used in the literature. We have also calculated the frequency-dependent U for some of the materials. The strong frequency dependence of U in some of the cases considered in this paper suggests that the static value of U may not be the most appropriate one to use in model calculations. We have also made comparison with the constrained local density approximation (LDA) method and found some discrepancies in a number of cases. We emphasize that our scheme and the constrained local density approximation LDA method theoretically ought to give similar results and the discrepancies may be attributed to technical difficulties in performing calculations based on currently implemented constrained LDA schemes.

The asymptotics of large constrained graphs

NASA Astrophysics Data System (ADS)

Radin, Charles; Ren, Kui; Sadun, Lorenzo

2014-05-01

We show, through local estimates and simulation, that if one constrains simple graphs by their densities ɛ of edges and τ of triangles, then asymptotically (in the number of vertices) for over 95% of the possible range of those densities there is a well-defined typical graph, and it has a very simple structure: the vertices are decomposed into two subsets V1 and V2 of fixed relative size c and 1 - c, and there are well-defined probabilities of edges, gjk, between vj ∈ Vj, and vk ∈ Vk. Furthermore the four parameters c, g11, g22 and g12 are smooth functions of (ɛ, τ) except at two smooth ‘phase transition’ curves.

Chondrocyte Differentiation of Human Endometrial Gland-Derived MSCs in Layered Cell Sheets

PubMed Central

Shimizu, Tatsuya; Yamato, Masayuki; Umezawa, Akihiro; Okano, Teruo

2013-01-01

Recently, regenerative medicine using engineered three-dimensional (3D) tissues has been focused. In the fields of cell therapy and regenerative medicine, mesenchymal stem cells (MSCs) are attractive autologous cell sources. While, in bioengineered tissues, a 3D environment may affect the differentiation of the stem cells, little is known regarding the effect of 3D environment on cellular differentiation. In this study, MSC differentiation in in vitro 3D tissue models was assessed by human endometrial gland-derived MSCs (hEMSCs) and cell sheet technology. hEMSC sheets were layered into cell-dense 3D tissues and were cultured on porous membranes. The tissue sections revealed that chondrocyte-like cells were found within the multilayered cell sheets even at 24 h after layering. Immunostainings of chondrospecific markers were positive within those cell sheet constructs. In addition, sulfated glycosaminoglycan accumulation within the tissues increased in proportion to the numbers of layered cell sheets. The findings suggested that a high cell density and hypoxic environment in 3D tissues by layering cell sheets might accelerate a rapid differentiation of hEMSCs into chondrocytes without the help of chondro-differentiation reagents. These tissue models using cell sheets would give new insights to stem cell differentiation in 3D environment and contribute to the future application of stem cells to cartilage regenerative therapy. PMID:24348153

Airborne Laser Altimetry Mapping of the Greenland Ice Sheet: Application to Mass Balance Assessment

NASA Technical Reports Server (NTRS)

Abdalati, W.; Krabill, W.; Frederick, E.; Manizade, S.; Martin, C.; Sonntag, J.; Swift, R.; Thomas, R.; Wright, W.; Yungel, J.

2000-01-01

In 1998 and '99, the Arctic Ice Mapping (AIM) program completed resurveys of lines occupied 5 years earlier revealing elevation changes of the Greenland ice sheet and identifying areas of significant thinning, thickening and balance. In planning these surveys, consideration had to be given to the spatial constraints associated with aircraft operation, the spatial nature of ice sheet behavior, and limited resources, as well as temporal issues, such as seasonal and interannual variability in the context of measurement accuracy. This paper examines the extent to which the sampling and survey strategy is valid for drawing conclusions on the current state of balance of the Greenland ice sheet. The surveys covered the entire ice sheet with an average distance of 21.4 km between each location on the ice sheet and the nearest flight line. For most of the ice sheet, the elevation changes show relatively little spatial variability, and their magnitudes are significantly smaller than the observed elevation change signal. As a result, we conclude that the density of the sampling and the accuracy of the measurements are sufficient to draw meaningful conclusions on the state of balance of the entire ice sheet over the five-year survey period. Outlet glaciers, however, show far more spatial and temporal variability, and each of the major ones is likely to require individual surveys in order to determine its balance.

Electrochemical Properties of Poly(Anthraquinonyl Sulfide)/Graphene Sheets Composites as Electrode Materials for Electrochemical Capacitors.

PubMed

Lee, Wonkyun; Suzuki, Shinya; Miyayama, Masaru

2014-07-30

Poly(anthraquinonyl sulfide) (PAQS)/graphene sheets (GSs) composite was synthesized through in situ polymerization to evaluate its performance as an electrode material for electrochemical capacitors. PAQS was successfully synthesized in the presence of GSs with uniform distribution. PAQS/GSs showed a pair of reversible redox peaks at around 0 V ( vs. Ag/AgCl). The specific capacitance of PAQS/GSs was 349 F·g -1 (86 mAh·g -1 ) at a current density of 500 mA·g -1 , and a capacitance of 305 F·g -1 was maintained even at a high current density of 5000 mA·g -1 . The in situ polymerization of PAQS with GSs facilitated their interaction and enabled faster charge transfer and redox reaction, resulting in enhanced electrode properties.

Capping Parallel β-Sheets of Acetyl(Ala)6NH2 with an Acetyl(Ala)5ProNH2 Can Arrest the Growth of the Sheet, Suggesting a Potential for Curtailing Amyloid Growth. An ONIOM and Density Functional Theory Study

PubMed Central

2015-01-01

We present ONIOM calculations using B3LYP/d95(d,p) as the high level and AM1 as the medium level on parallel β-sheets containing four strands of Ac-AAAAAA-NH2 capped with either Ac-AAPAAA-NH2 or Ac-AAAPAA-NH2. Because Pro can form H-bonds from only one side of the peptide linkage (that containing the C=O H-bond acceptor), only one of the two Pro-containing strands can favorably add to the sheet on each side. Surprisingly, when the sheet is capped with AAPAAA-NH2 at one edge, the interaction between the cap and sheet is slightly more stabilizing than that of another all Ala strand. Breaking down the interaction enthalpies into H-bonding and distortion energies shows the favorable interaction to be due to lower distortion energies in both the strand and the four-stranded sheet. Because another strand would be inhibited for attachment to the other side of the capping (Pro-containing) strand, we suggest the possible use of Pro residues in peptides designed to arrest the growth of many amyloids. PMID:24422496

Dark energy in the dark ages

NASA Astrophysics Data System (ADS)

Linder, Eric V.

2006-08-01

Non-negligible dark energy density at high redshifts would indicate dark energy physics distinct from a cosmological constant or "reasonable" canonical scalar fields. Such dark energy can be constrained tightly through investigation of the growth of structure, with limits of ≲2% of total energy density at z ≫ 1 for many models. Intermediate dark energy can have effects distinct from its energy density; the dark ages acceleration can be constrained to last less than 5% of a Hubble e-fold time, exacerbating the coincidence problem. Both the total linear growth, or equivalently σ8, and the shape and evolution of the nonlinear mass power spectrum for z < 2 (using the Linder-White nonlinear mapping prescription) provide important windows. Probes of growth, such as weak gravitational lensing, can interact with supernovae and CMB distance measurements to scan dark energy behavior over the entire range z = 0-1100.

Optimization of Stability Constrained Geometrically Nonlinear Shallow Trusses Using an Arc Length Sparse Method with a Strain Energy Density Approach

NASA Technical Reports Server (NTRS)

Hrinda, Glenn A.; Nguyen, Duc T.

2008-01-01

A technique for the optimization of stability constrained geometrically nonlinear shallow trusses with snap through behavior is demonstrated using the arc length method and a strain energy density approach within a discrete finite element formulation. The optimization method uses an iterative scheme that evaluates the design variables' performance and then updates them according to a recursive formula controlled by the arc length method. A minimum weight design is achieved when a uniform nonlinear strain energy density is found in all members. This minimal condition places the design load just below the critical limit load causing snap through of the structure. The optimization scheme is programmed into a nonlinear finite element algorithm to find the large strain energy at critical limit loads. Examples of highly nonlinear trusses found in literature are presented to verify the method.

Experiment of constraining symmetry energy at supra-saturation density with π-/π+ at HIRFL-CSR

NASA Astrophysics Data System (ADS)

Zhang, Ming; Xiao, Zhi-Gang; Zhu, Sheng-Jiang

2010-08-01

The possibility of the experiment for constraining the symmetry energy Esym(ρ) at supra-densities via π-/π+ probe on the external target experiment of phase I (ETE(I)) with part coverage at forward angle at HIRFL-CSR is studied for the first time by using the isospin and momentum dependent hadronic transport model IBUU04. Based on the transport simulation with Au+Au collisions at 400 MeV/u, it is found that the differential π-/π+ ratios are more sensitive to Esym(ρ) at forward angles in laboratory reference, compared with the total yield ratio widely proposed. The insufficient coverage at lower transverse momentum maintains the sensitivity of the dependence of π-/π+ ratio on the Esym(ρ) at high density, indicating that the ETF (I) under construction in Lanzhou provides the possibility of performing the experiment for probing the asymmetric nuclear equation of state.

Finite-density effects in the Fredrickson-Andersen and Kob-Andersen kinetically-constrained models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Teomy, Eial, E-mail: eialteom@post.tau.ac.il; Shokef, Yair, E-mail: shokef@tau.ac.il

2014-08-14

We calculate the corrections to the thermodynamic limit of the critical density for jamming in the Kob-Andersen and Fredrickson-Andersen kinetically-constrained models, and find them to be finite-density corrections, and not finite-size corrections. We do this by introducing a new numerical algorithm, which requires negligible computer memory since contrary to alternative approaches, it generates at each point only the necessary data. The algorithm starts from a single unfrozen site and at each step randomly generates the neighbors of the unfrozen region and checks whether they are frozen or not. Our results correspond to systems of size greater than 10{sup 7} ×more » 10{sup 7}, much larger than any simulated before, and are consistent with the rigorous bounds on the asymptotic corrections. We also find that the average number of sites that seed a critical droplet is greater than 1.« less

Nonlinear Dynamics of Non-uniform Current-Vortex Sheets in Magnetohydrodynamic Flows

NASA Astrophysics Data System (ADS)

Matsuoka, C.; Nishihara, K.; Sano, T.

2017-04-01

A theoretical model is proposed to describe fully nonlinear dynamics of interfaces in two-dimensional MHD flows based on an idea of non-uniform current-vortex sheet. Application of vortex sheet model to MHD flows has a crucial difficulty because of non-conservative nature of magnetic tension. However, it is shown that when a magnetic field is initially parallel to an interface, the concept of vortex sheet can be extended to MHD flows (current-vortex sheet). Two-dimensional MHD flows are then described only by a one-dimensional Lagrange parameter on the sheet. It is also shown that bulk magnetic field and velocity can be calculated from their values on the sheet. The model is tested by MHD Richtmyer-Meshkov instability with sinusoidal vortex sheet strength. Two-dimensional ideal MHD simulations show that the nonlinear dynamics of a shocked interface with density stratification agrees fairly well with that for its corresponding potential flow. Numerical solutions of the model reproduce properly the results of the ideal MHD simulations, such as the roll-up of spike, exponential growth of magnetic field, and its saturation and oscillation. Nonlinear evolution of the interface is found to be determined by the Alfvén and Atwood numbers. Some of their dependence on the sheet dynamics and magnetic field amplification are discussed. It is shown by the model that the magnetic field amplification occurs locally associated with the nonlinear dynamics of the current-vortex sheet. We expect that our model can be applicable to a wide variety of MHD shear flows.

Late Holocene spatio-temporal variability of the south Greenland Ice Sheet and adjacent mountain glaciers

NASA Astrophysics Data System (ADS)

Sinclair, G.; Carlson, A. E.; Rood, D. H.; Axford, Y.

2017-12-01

The late Holocene, with its spatially complex pattern of centennial-scale climate variation, is an ideal time period to test the response of the cryosphere to atmospheric and oceanic temperature changes. The south Greenland Ice Sheet (sGrIS), with its proximity to areas of North Atlantic Deep Water formation and a large spectrum of glaciological regimes over a relatively small area, provides an excellent location to examine the spatial heterogeneity of ice-sheet and glacier responses to climate change. Here, we will present 50 Be-10 surface exposure ages from eight moraines in six locations around the margin of the sGrIS. These moraines are located just outboard of historical moraines, and will therefore allow us to constrain the timing of the most extensive prehistoric late-Holocene advance and retreat of ice margins draining the sGrIS and independent valley glaciers. The dataset includes both marine- and land-terminating glaciers draining the sGrIS, the low-altitude Qassimiut lobe, the high-altitude alpine Julianhåb ice cap and isolated valley glaciers. This diverse dataset will allow us to determine to what extent late-Holocene centennial-scale behavior of the ice-sheet and glacier margins were synchronous, perhaps in response to an external climate forcing, or more stochastic, governed instead by local factors such as basal thermal regime, bedrock topography, or microclimates. This has implications for understanding the forcings and responses of cryospheric changes at timescales relevant to human society. In addition to providing context for paleoclimatic and glacial geologic investigations, this work will inform future sea-level projections by providing targets for validating high-resolution ice-sheet and glacier models.

Unveiling climate and ice-sheet history from drilling in high-latitude margins and future perspectives

NASA Astrophysics Data System (ADS)

Escutia Dotti, Carlota

2010-05-01

Polar ice is an important component of the climate system, affecting global sea level, ocean circulation and heat transport, marine productivity, and albedo. During the last decades drilling in the Arctic (IODP ACEX and Bering Expeditions) and in Antarctica (ODP Legs 178, 188, IODP Expedition 318 and ANDRILL) has revealed regional information about sea ice and ice sheets development and evolution. Integration of this data with numerical modeling provide an understanding of the early development of the ice sheets and their variability through the Cenozoic. Much of this work points to atmospheric CO2 and other greenhouse gases concentrations as important triggering mechanism driving the onset of glaciation and subsequent ice volume variability. With current increasing atmospheric greenhouse gases concentrations resulting in rapidly rising global temperatures, studies of polar climates become increasingly prominent on the research agenda. Despite of the relevance of the high-latitudes in the global climate systems, the short- and long-term history of the ice sheets and sea-ice and its relationships with paleoclimatic, paleoceanographic, and sea level changes is still poorly understood. A multinational, multiplatform scientific drilling strategy is being developed to recover key physical evidence from selected high-latitude areas. This strategy is aimed at addressing key knowledge gaps about the role of polar ice in climate change, targeting questions such as timing of events, rates of change, tipping points, regional variations, and northern vs. southern hemispheres (in phase or out-of-phase) variability. This data is critical to provide constrains to sea-ice and ice sheet models, which are the basis for forecasting the future of the cryosphere in a warming world.

Foam Core Shielding for Spacecraft

NASA Technical Reports Server (NTRS)

Adams, Marc

2007-01-01

A foam core shield (FCS) system is now being developed to supplant multilayer insulation (MLI) systems heretofore installed on spacecraft for thermal management and protection against meteoroid impacts. A typical FCS system consists of a core sandwiched between a face sheet and a back sheet. The core can consist of any of a variety of low-to-medium-density polymeric or inorganic foams chosen to satisfy application-specific requirements regarding heat transfer and temperature. The face sheet serves to shock and thereby shatter incident meteoroids, and is coated on its outer surface to optimize its absorptance and emittance for regulation of temperature. The back sheet can be dimpled to minimize undesired thermal contact with the underlying spacecraft component and can be metallized on the surface facing the component to optimize its absorptance and emittance. The FCS systems can perform better than do MLI systems, at lower mass and lower cost and with greater volumetric efficiency.

Advanced Sulfur Cathode Enabled by Highly Crumpled Nitrogen-Doped Graphene Sheets for High-Energy-Density Lithium-Sulfur Batteries.

PubMed

Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail L; Wang, Donghai

2016-02-10

Herein, we report a synthesis of highly crumpled nitrogen-doped graphene sheets with ultrahigh pore volume (5.4 cm(3)/g) via a simple thermally induced expansion strategy in absence of any templates. The wrinkled graphene sheets are interwoven rather than stacked, enabling rich nitrogen-containing active sites. Benefiting from the unique pore structure and nitrogen-doping induced strong polysulfide adsorption ability, lithium-sulfur battery cells using these wrinkled graphene sheets as both sulfur host and interlayer achieved a high capacity of ∼1000 mAh/g and exceptional cycling stability even at high sulfur content (≥80 wt %) and sulfur loading (5 mg sulfur/cm(2)). The high specific capacity together with the high sulfur loading push the areal capacity of sulfur cathodes to ∼5 mAh/cm(2), which is outstanding compared to other recently developed sulfur cathodes and ideal for practical applications.

Ethylene-vinyl acetate foam as a new lung substitute in radiotherapy.

PubMed

Marqués, Enrique; Mancha, Pedro J

2018-04-01

The purpose of this study was to evaluate ethylene-vinyl acetate (EVA) foam as a new lung substitute in radiotherapy and to study its physical and dosimetric characteristics. We calculated the ideal vinyl acetate (VA) content of EVA foam sheets to mimic the physical and dosimetric characteristics of the ICRU lung tissue. We also computed the water-to-medium mass collision stopping power ratios, mass attenuation coefficients, CT numbers, effective atomic numbers and electron densities for: ICRU lung tissue, the RANDO commercial phantom, scaled WATER and EVA foam sheets with varying VA contents in a range between the minimum and maximum values supplied by the manufacturer. For all these substitutes, we simulated percent depth-dose curves with EGSnrc Monte Carlo (MC PDDs) in a water-lung substitute-water slab phantom expressed as dose-to-medium and dose-to-water for 3 × 3- and 10 × 10-cm 2 field sizes. PDD for the 10 × 10-cm 2 field size was also calculated with the MultiGrid Superposition algorithm (MGS PDD) for a relative electron density to water ratio of 0.26. The latter was compared with the MC PDDs in dose-to-water for scaled WATER and EVA foam sheets with the VA content that was most similar to the calculated ideal content that is physically achievable in practice. We calculated an ideal VA content of 55%; however, the maximum physically achievable content with current manufacturing techniques is 40%. The physical characteristics of the EVA foam sheets with a VA content of 40% (EVA40) are very close to those of the ICRU lung reference. The physical densities of the EVA40 foam sheets ranged from 0.030 to 0.965 g/cm 3 , almost covering the entire physical density range of the inflated/deflated lung (0.260-1.050 g/cm 3 ). Its mass attenuation coefficient at the effective energy of a 6-MV photon beam agrees within 0.8% of the ICRU reference value, and its CT number agrees within 6 HU. The effective atomic number for EVA40 varies by less than 0.42 of the ICRU value, and its effective electron density is within 0.9%. PDDs expressed in dose-to-medium and dose-to-water agree with the ICRU curve within 2% in all regions. PDDs calculated with both MC and MGS were within 1.5%. The EVA40 is an excellent cork-like lung substitute for radiotherapy applications. From a sole material used in footwear, it is possible to obtain a lung substitute that mimics the physical and dosimetric characteristics of ICRU lung tissue even better than the RANDO commercial phantom. © 2018 American Association of Physicists in Medicine.

Density-based Energy Decomposition Analysis for Intermolecular Interactions with Variationally Determined Intermediate State Energies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Q.; Ayers, P.W.; Zhang, Y.

2009-10-28

The first purely density-based energy decomposition analysis (EDA) for intermolecular binding is developed within the density functional theory. The most important feature of this scheme is to variationally determine the frozen density energy, based on a constrained search formalism and implemented with the Wu-Yang algorithm [Q. Wu and W. Yang, J. Chem. Phys. 118, 2498 (2003) ]. This variational process dispenses with the Heitler-London antisymmetrization of wave functions used in most previous methods and calculates the electrostatic and Pauli repulsion energies together without any distortion of the frozen density, an important fact that enables a clean separation of these twomore » terms from the relaxation (i.e., polarization and charge transfer) terms. The new EDA also employs the constrained density functional theory approach [Q. Wu and T. Van Voorhis, Phys. Rev. A 72, 24502 (2005)] to separate out charge transfer effects. Because the charge transfer energy is based on the density flow in real space, it has a small basis set dependence. Applications of this decomposition to hydrogen bonding in the water dimer and the formamide dimer show that the frozen density energy dominates the binding in these systems, consistent with the noncovalent nature of the interactions. A more detailed examination reveals how the interplay of electrostatics and the Pauli repulsion determines the distance and angular dependence of these hydrogen bonds.« less

Thin laser light sheet microscope for microbial oceanography

NASA Astrophysics Data System (ADS)

Fuchs, Eran; Jaffe, Jules S.; Long, Richard A.; Azam, Farooq

2002-01-01

Despite a growing need, oceanographers are limited by existing technological constrains and are unable to observe aquatic microbes in their natural setting. In order to provide a simple and easy to implement solution for such studies, a new Thin Light Sheet Microscope (TLSM) has been developed. The TLSM utilizes a well-defined sheet of laser light, which has a narrow (23 micron) axial dimension over a 1 mm x 1 mm field of view. This light sheet is positioned precisely within the depth of field of the microscope’s objective lens. The technique thus utilizes conventional microscope optics but replaces the illumination system. The advantages of the TLSM are two-fold: First, it concentrates light only where excitation is needed, thus maximizing the efficiency of the illumination source. Secondly, the TLSM maximizes image sharpness while at the same time minimizing the level of background noise. Particles that are not located within the objective's depth of field are not illuminated and therefore do not contribute to an out-of-focus image. Images from a prototype system that used SYBR Green I fluorescence stain in order to localize single bacteria are reported. The bacteria were in a relatively large and undisturbed volume of 4ml, which contained natural seawater. The TLSM can be used for fresh water studies of bacteria with no modification. The microscope permits the observation of interactions at the microscale and has potential to yield insights into how microbes structure pelagic ecosystems.

Effects of process variables in decarburization annealing of Fe-3%Si-0.3%C steel sheet on textures and magnetic properties

NASA Astrophysics Data System (ADS)

Park, Se Min; Koo, Yang Mo; Shim, Byoung Yul; Lee, Dong Nyung

2017-01-01

In Fe-3%Si-0.3%C steel sheet, a relatively strong <100>//ND texture can evolve in the surface layer through the α→γ→α phase transformation in relatively low vacuum (4 Pa) for an annealing time of 10 min and at a cooling rate of 20 K/s. Oxidation of the steel sheet surface prevents the evolution of the <100>//ND texture. However, vacuum-annealing under a vacuum pressure of 1.3×10-3 Pa causes decarburization of the steel sheet, which suppresses oxidation of the steel sheet surface, and subsequent annealing in wet hydrogen of 363 K in dew points causes a columnar grain structure with the <100>//ND texture. After the two-step-annealing (the vacuum annealing under a vacuum pressure of 1.3×10-3 Pa and subsequent decarburizing annealing in wet hydrogen of 363 K in dew points), the decarburized steel sheet exhibits good soft magnetic properties in NO with 3%Si, W15/50 (core loss at 1.5T and 50 Hz) = 2.47 W/kg and B50 (magnetic flux density at 5000 A/m) = 1.71 T.

Thermoelectric properties of single-layered SnSe sheet.

PubMed

Wang, Fancy Qian; Zhang, Shunhong; Yu, Jiabing; Wang, Qian

2015-10-14

Motivated by the recent study of inspiring thermoelectric properties in bulk SnSe [Zhao et al., Nature, 2014, 508, 373] and the experimental synthesis of SnSe sheets [Chen et al., J. Am. Chem. Soc., 2013, 135, 1213], we have carried out systematic calculations for a single-layered SnSe sheet focusing on its stability, electronic structure and thermoelectric properties by using density functional theory combined with Boltzmann transport theory. We have found that the sheet is dynamically and thermally stable with a band gap of 1.28 eV, and the figure of merit (ZT) reaches 3.27 (2.76) along the armchair (zigzag) direction with optimal n-type carrier concentration, which is enhanced nearly 7 times compared to its bulk counterpart at 700 K due to quantum confinement effect. Furthermore, we designed four types of thermoelectric couples by assembling single-layered SnSe sheets with different transport directions and doping types, and found that their efficiencies are all above 13%, which are higher than those of thermoelectric couples made of commercial bulk Bi2Te3 (7%-8%), suggesting the great potential of single-layered SnSe sheets for heat-electricity conversion.

Generation of Alfvenic Waves and Turbulence in Magnetic Reconnection Jets

NASA Astrophysics Data System (ADS)

Hoshino, M.

2014-12-01

The magneto-hydro-dynamic (MHD) linear stability for the plasma sheet with a localized bulk plasma flow parallel to the neutral sheet is investigated. We find three different unstable modes propagating parallel to the anti-parallel magnetic field line, and we call them as "streaming　tearing'', "streaming sausage'', and "streaming kink'' mode. The streaming tearing and sausage modes have the tearing mode-like structure with symmetric density fluctuation to the neutral sheet, and the streaming kink mode has the asymmetric fluctuation.　The growth rate of the streaming tearing mode decreases with increasing the magnetic Reynolds number, while those of the streaming　sausage and kink modes do not strongly depend on the Reynolds number. The wavelengths of these unstable modes are of the order of the thickness of plasma sheet, which behavior is almost same as the standard　tearing mode with no bulk flow. Roughly speaking the growth rates of　three modes become faster than the standard tearing mode. The situation of the plasma sheet with the bulk flow can be realized in the reconnection exhaust with the Alfvenic reconnection jet, and the unstable modes may be regarded as one of the generation processes of Alfvenic　turbulence in the plasma sheet during magnetic reconnection.

Ni-Flash-Coated Galvannealed Steel Sheet with Improved Properties

NASA Astrophysics Data System (ADS)

Pradhan, D.; Dutta, M.; Venugopalan, T.

2016-11-01

In the last several years, automobile industries have increasingly focused on galvannealed (GA) steel sheet due to their superior properties such as weldability, paintability and corrosion protection. To improve the properties further, different coatings on GA have been reported. In this context, an electroplating process (flash coating) of bright and adherent Ni plating was developed on GA steel sheet for covering the GA defects and enhancing the performances such as weldability, frictional behavior, corrosion resistance and phosphatability. For better illustration, a comparative study with bare GA steel sheet has also been carried out. The maximum electroplating current density of 700 A/m2 yielded higher cathode current efficiency of 95-98%. The performances showed that Ni-coated (coating time 5-7 s) GA steel sheet has better spot weldability, lower dynamic coefficient of friction (0.07 in lubrication) and three times more corrosion resistance compared to bare GA steel sheet. Plate-like crystal of phosphate coating with size of 10-25 µm was obtained on the Ni-coated GA. The main phase in the phosphate compound was identified as hopeite (63.4 wt.%) along with other phases such as spencerite (28.3 wt.%) and phosphophyllite (8.3 wt.%).

Development of the apparatus for measuring magnetic properties of electrical steel sheets in arbitrary directions under compressive stress normal to their surface

NASA Astrophysics Data System (ADS)

Maeda, Yoshitaka; Urata, Shinya; Nakai, Hideo; Takeuchi, Yuuya; Yun, Kyyoul; Yanase, Shunji; Okazaki, Yasuo

2017-05-01

In designing motors, one must grasp the magnetic properties of electrical steel sheets considering actual conditions in motors. Especially important is grasping the stress dependence of magnetic power loss. This paper describes a newly developed apparatus to measure two-dimensional (2-D) magnetic properties (properties under the arbitrary alternating and the rotating flux conditions) of electrical steel sheets under compressive stress normal to the sheet surface. The apparatus has a 2-D magnetic excitation circuit to generate magnetic fields in arbitrary directions in the evaluation area. It also has a pressing unit to apply compressive stress normal to the sheet surface. During measurement, it is important to apply uniform stress throughout the evaluation area. Therefore, we have developed a new flux density sensor using needle probe method. It is composed of thin copper foils sputtered on electrical steel sheets. By using this sensor, the stress can be applied to the surface of the specimen without influence of this sensor. This paper described the details of newly developed apparatus with this sensor, and measurement results of iron loss by using are shown.

Band offset engineering of 2DEG oxide systems on Si

NASA Astrophysics Data System (ADS)

Jin, Eric; Kornblum, Lior; Kumah, Divine; Zou, Ke; Broadbridge, Christine; Ngai, Joseph; Ahn, Charles; Walker, Fred

2015-03-01

The discovery of 2-dimensional electron gases (2DEGs) at perovskite oxide interfaces has sparked much interest in recent years due to their large carrier densities when compared with semiconductor heterostructures. For device applications, these oxide systems are plagued by low room temperature electrical mobilities. We present an approach to combine the high carrier density of 2DEG oxides with a higher mobility medium in order to realize the combined benefits of higher mobility and carrier density. We grow epitaxial films of the interfacial oxide system LaTiO3/SrTiO3 (LTO/STO) on silicon by molecular beam epitaxy. Magnetotransport measurements show that the sheet carrier densities of the heterostructures scale with the number of LTO/STO interfaces, consistent with the presence of a 2DEG at each interface. Sheet carrier densities of 8.9 x 1014 cm-2 per interface are measured. Band offsets between the STO and Si are obtained, showing that the conduction band edge of the STO is close in energy to that of silicon, but in a direction that hinders carrier transfer to the silicon substrate. Through modification of the STO/Si interface, we suggest an approach to raise the band offset in order to move the 2DEG from the oxide into the silicon.

Observations of supra-arcade fans: instabilities at the head of reconnection jets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Innes, D. E.; Guo, L.-J.; Schmit, D.

2014-11-20

Supra-arcade fans are bright, irregular regions of emission that develop during eruptive flares above flare arcades. The underlying flare arcades are thought to be a consequence of magnetic reconnection along a current sheet in the corona. At the same time, theory predicts plasma jets from the reconnection sites which are extremely difficult to observe directly because of their low densities. It has been suggested that the dark supra-arcade downflows (SADs) seen falling through supra-arcade fans may be low-density jet plasma. The head of a low-density jet directed toward higher-density plasma would be Rayleigh-Taylor unstable, and lead to the development ofmore » rapidly growing low- and high-density fingers along the interface. Using Solar Dynamics Observatory/Atmospheric Imaging Assembly 131 Å images, we show details of SADs seen from three different orientations with respect to the flare arcade and current sheet, and highlight features that have been previously unexplained, such as the splitting of SADs at their heads, but are a natural consequence of instabilities above the arcade. Comparison with three-dimensional magnetohydrodynamic simulations suggests that SADs are the result of secondary instabilities of the Rayleigh-Taylor type in the exhaust of reconnection jets.« less

The build-up, configuration, and dynamical sensitivity of the Eurasian ice-sheet complex to Late Weichselian climatic and oceanic forcing

NASA Astrophysics Data System (ADS)

Patton, Henry; Hubbard, Alun; Andreassen, Karin; Winsborrow, Monica; Stroeven, Arjen P.

2016-12-01

The Eurasian ice-sheet complex (EISC) was the third largest ice mass during the Last Glacial Maximum (LGM), after the Antarctic and North American ice sheets. Despite its global significance, a comprehensive account of its evolution from independent nucleation centres to its maximum extent is conspicuously lacking. Here, a first-order, thermomechanical model, robustly constrained by empirical evidence, is used to investigate the dynamics of the EISC throughout its build-up to its maximum configuration. The ice flow model is coupled to a reference climate and applied at 10 km spatial resolution across a domain that includes the three main spreading centres of the Celtic, Fennoscandian and Barents Sea ice sheets. The model is forced with the NGRIP palaeo-isotope curve from 37 ka BP onwards and model skill is assessed against collated flowsets, marginal moraines, exposure ages and relative sea-level history. The evolution of the EISC to its LGM configuration was complex and asynchronous; the western, maritime margins of the Fennoscandian and Celtic ice sheets responded rapidly and advanced across their continental shelves by 29 ka BP, yet the maximum aerial extent (5.48 × 106 km2) and volume (7.18 × 106 km3) of the ice complex was attained some 6 ka later at c. 22.7 ka BP. This maximum stand was short-lived as the North Sea and Atlantic margins were already in retreat whilst eastern margins were still advancing up until c. 20 ka BP. High rates of basal erosion are modelled beneath ice streams and outlet glaciers draining the Celtic and Fennoscandian ice sheets with extensive preservation elsewhere due to frozen subglacial conditions, including much of the Barents and Kara seas. Here, and elsewhere across the Norwegian shelf and North Sea, high pressure subglacial conditions would have promoted localised gas hydrate formation.

Automated drumlin shape and volume estimation using high resolution LiDAR imagery (Curvature Based Relief Separation): A test from the Wadena Drumlin Field, Minnesota

NASA Astrophysics Data System (ADS)

Yu, Peter; Eyles, Nick; Sookhan, Shane

2015-10-01

Resolving the origin(s) of drumlins and related megaridges in areas of megascale glacial lineations (MSGL) left by paleo-ice sheets is critical to understanding how ancient ice sheets interacted with their sediment beds. MSGL is now linked with fast-flowing ice streams but there is a broad range of erosional and depositional models. Further progress is reliant on constraining fluxes of subglacial sediment at the ice sheet base which in turn is dependent on morphological data such as landform shape and elongation and most importantly landform volume. Past practice in determining shape has employed a broad range of geomorphological methods from strictly visualisation techniques to more complex semi-automated and automated drumlin extraction methods. This paper reviews and builds on currently available visualisation, semi-automated and automated extraction methods and presents a new, Curvature Based Relief Separation (CBRS) technique; for drumlin mapping. This uses curvature analysis to generate a base level from which topography can be normalized and drumlin volume can be derived. This methodology is tested using a high resolution (3 m) LiDAR elevation dataset from the Wadena Drumlin Field, Minnesota, USA, which was constructed by the Wadena Lobe of the Laurentide Ice Sheet ca. 20,000 years ago and which as a whole contains 2000 drumlins across an area of 7500 km2. This analysis demonstrates that CBRS provides an objective and robust procedure for automated drumlin extraction. There is strong agreement with manually selected landforms but the method is also capable of resolving features that were not detectable manually thereby considerably expanding the known population of streamlined landforms. CBRS provides an effective automatic method for visualisation of large areas of the streamlined beds of former ice sheets and for modelling sediment fluxes below ice sheets.

The Spin and Orientation of Dark Matter Halos Within Cosmic Filaments

NASA Astrophysics Data System (ADS)

Zhang, Youcai; Yang, Xiaohu; Faltenbacher, Andreas; Springel, Volker; Lin, Weipeng; Wang, Huiyuan

2009-11-01

Clusters, filaments, sheets, and voids are the building blocks of the cosmic web. Forming dark matter halos respond to these different large-scale environments, and this in turn affects the properties of galaxies hosted by the halos. It is therefore important to understand the systematic correlations of halo properties with the morphology of the cosmic web, as this informs both about galaxy formation physics and possible systematics of weak lensing studies. In this study, we present and compare two distinct algorithms for finding cosmic filaments and sheets, a task which is far less well established than the identification of dark matter halos or voids. One method is based on the smoothed dark matter density field and the other uses the halo distributions directly. We apply both techniques to one high-resolution N-body simulation and reconstruct the filamentary/sheet like network of the dark matter density field. We focus on investigating the properties of the dark matter halos inside these structures, in particular, on the directions of their spins and the orientation of their shapes with respect to the directions of the filaments and sheets. We find that both the spin and the major axes of filament halos with masses lsim1013 h -1 M sun are preferentially aligned with the direction of the filaments. The spins and major axes of halos in sheets tend to lie parallel to the sheets. There is an opposite mass dependence of the alignment strength for the spin (negative) and major (positive) axes, i.e. with increasing halo mass the major axis tends to be more strongly aligned with the direction of the filament, whereas the alignment between halo spin and filament becomes weaker with increasing halo mass. The alignment strength as a function of the distance to the most massive node halo indicates that there is a transit large-scale environment impact: from the two-dimensional collapse phase of the filament to the three-dimensional collapse phase of the cluster/node halo at small separation. Overall, the two algorithms for filament/sheet identification investigated here agree well with each other. The method based on halos alone can be easily adapted for use with observational data sets.

Simultaneous measurements of magnetotail dynamics by IMP spacecraft

NASA Technical Reports Server (NTRS)

Fairfield, D. H.; Lepping, R. P.; Hones, E. W., Jr.; Bame, S. J.; Asbridge, J. R.

1980-01-01

Changes in tail energy density during substorms in the magnetotail are given. In addition to plasma sheet thinnings seen prior to substorm onsets, a gradual decrease in plasma beta was detected in the deep tail which precedes onset and the more prominent plasma disappearance that typically accompanies it. The frequency of thinnings and the regions over which they occurred indicate that drastic changes in plasma sheet thickness are common features of substorms which occur at all locations across the tail.

Current sheet in plasma as a system with a controlling parameter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fridman, Yu. A., E-mail: yulya-fridman@yandex.ru; Chukbar, K. V., E-mail: Chukbar-KV@nrcki.ru

2015-08-15

A simple kinetic model describing stationary solutions with bifurcated and single-peaked current density profiles of a plane electron beam or current sheet in plasma is presented. A connection is established between the two-dimensional constructions arising in terms of the model and the one-dimensional considerations by Bernstein−Greene−Kruskal facilitating the reconstruction of the distribution function of trapped particles when both the profile of the electric potential and the free particles distribution function are known.

Rapid welding and rheomorphism in unconfined (sheet-like) ignimbrites in Idaho, England and Pantelleria

NASA Astrophysics Data System (ADS)

Barry, T. L.; Branney, M. J.; Andrews, G.

2003-04-01

Sheet-like rheomorphic ignimbrites of diverse chemistry and geological setting preserve evidence of very rapid welding and rheomorphism, with time-scales of the same order-of-magnitude as the duration of the pyroclastic density current (mins-hrs). This is in contrast to rheomorphism that occurs primarily after emplacement; for example, in the Crinkles Tuffs of Scafell caldera in England individual rheomorphic folds affect more than one ignimbrite. In this case two or more ignimbrites were emplaced and then underwent rheomorphism together, prior to cooling. In contrast to valley-filling rheomorphic ignimbrites, in which the orientation of sheathfold axes and elongation lineations remain parallel to the valley (1) (i.e. the valley served to maintain the flow direction by chanelling), sheathfolds axes and elongation lineations in sheet-like ignimbrites emplaced onto low-angle slopes vary at each individual geographic location. At individual heights in the ignimbrite sheet, the orientation trends cluster, and the azimuth orientation of the clusters change systematically with height. We interpret this as indicating that the flow-direction of the pyroclastic density current changed with time during progressive aggradation of the ignimbrite. During deposition, agglutination and rheomorphism occurred in a relatively narrow, rising ductile shear zone. The transport direction at a particular moment was preserved as rheomorphic fabrics became frozen into the deposit when this shear zone migrated away upwards. Each level in the ignimbrite thus provides a snap-shot of the flow direction at a particular time. Changes in flow-direction in sustained pyroclastic density currents occur due to depositional and erosional modification of topography (2). Chilled basal vitrophyres of rheomorphic ignimbrites are particularly instructive, as rapid chilling uniquely preserves early stages of welding and deformation. Oblique fabrics are typical, and record agglutination and initial rheomorphism that elsewhere is transposed and overprinted by more protracted shear and attenuation. In contrast, upper vitrophyres of some rheomorphic ignimbrites show well-developed sheath and flow-perturbation folds(3). (1) Branney MJ and Barry TL (2003) Abstract in this volume. (2) Branney MJ and Kokelaar P (2003) Pyroclastic density currents and the sedimentation of ignimbrites. Geol. Soc. London Mem. 27. 150 pp. (3) Alsop GI and Holdsworth RE (2002) Tectonophysics 6605.

Static current-sheet models of quiescent prominences

NASA Technical Reports Server (NTRS)

Wu, F.; Low, B. C.

1986-01-01

A particular class of theoretical models idealize the prominence to be a discrete flat electric-current sheet suspended vertically in a potential magnetic field. The weight of the prominence is supported by the Lorentz force in the current sheet. These models can be extended to have curved electric-current sheets and to vary three-dimensionally. The equation for force balance is 1 over 4 pi (del times B) times Bdel p- p9 z=zero. Using Cartesian coordinates we take, for simplicity, a uniform gravity with constant acceleration g in the direction -z. If we are interested not in the detailed internal structure of the prominence, but in the global magnetic configuration around the prominence, we may take prominence plasma to be cold. Consideration is given to how such equilibrium states can be constructed. To simplify the mathematical problem, suppose there is no electric current in the atmosphere except for the discrete currents in the cold prominence sheet. Let us take the plane z =0 to be the base of the atmosphere and restrict our attention to the domain z greater than 0. The task we have is to solve for a magnetic field which is everywhere potential except on some free surface S, subject to suit able to boundary conditions. The surface S is determined by requiring that it possesses a discrete electric current density such that the Lorentz force on it is everywhere vertically upward to balance the weight of the material m(S). Since the magnetic field is potential in the external atmosphere, the latter is decoupled from the magnetic field and its plane parallel hydrostatic pressure and density can be prescribed.

Static current-sheet models of quiescent prominences

NASA Astrophysics Data System (ADS)

Wu, F.; Low, B. C.

1986-12-01

A particular class of theoretical models idealize the prominence to be a discrete flat electric-current sheet suspended vertically in a potential magnetic field. The weight of the prominence is supported by the Lorentz force in the current sheet. These models can be extended to have curved electric-current sheets and to vary three-dimensionally. The equation for force balance is 1 over 4 pi (del times B) times Bdel p- p9 z=zero. Using Cartesian coordinates we take, for simplicity, a uniform gravity with constant acceleration g in the direction -z. If we are interested not in the detailed internal structure of the prominence, but in the global magnetic configuration around the prominence, we may take prominence plasma to be cold. Consideration is given to how such equilibrium states can be constructed. To simplify the mathematical problem, suppose there is no electric current in the atmosphere except for the discrete currents in the cold prominence sheet. Let us take the plane z =0 to be the base of the atmosphere and restrict our attention to the domain z greater than 0. The task we have is to solve for a magnetic field which is everywhere potential except on some free surface S, subject to suit able to boundary conditions. The surface S is determined by requiring that it possesses a discrete electric current density such that the Lorentz force on it is everywhere vertically upward to balance the weight of the material m(S). Since the magnetic field is potential in the external atmosphere, the latter is decoupled from the magnetic field and its plane parallel hydrostatic pressure and density can be prescribed.

Ab initio and classical molecular dynamics studies of the structural and dynamical behavior of water near a hydrophobic graphene sheet.

PubMed

Rana, Malay Kumar; Chandra, Amalendu

2013-05-28

The behavior of water near a graphene sheet is investigated by means of ab initio and classical molecular dynamics simulations. The wetting of the graphene sheet by ab initio water and the relation of such behavior to the strength of classical dispersion interaction between surface atoms and water are explored. The first principles simulations reveal a layered solvation structure around the graphene sheet with a significant water density in the interfacial region implying no drying or cavitation effect. It is found that the ab initio results of water density at interfaces can be reproduced reasonably well by classical simulations with a tuned dispersion potential between the surface and water molecules. Calculations of vibrational power spectrum from ab initio simulations reveal a shift of the intramolecular stretch modes to higher frequencies for interfacial water molecules when compared with those of the second solvation later or bulk-like water due to the presence of free OH modes near the graphene sheet. Also, a weakening of the water-water hydrogen bonds in the vicinity of the graphene surface is found in our ab initio simulations as reflected in the shift of intermolecular vibrational modes to lower frequencies for interfacial water molecules. The first principles calculations also reveal that the residence and orientational dynamics of interfacial water are somewhat slower than those of the second layer or bulk-like molecules. However, the lateral diffusion and hydrogen bond relaxation of interfacial water molecules are found to occur at a somewhat faster rate than that of the bulk-like water molecules. The classical molecular dynamics simulations with tuned Lennard-Jones surface-water interaction are found to produce dynamical results that are qualitatively similar to those of ab initio molecular dynamics simulations.

Scalable synthesis of Fe₃O₄ nanoparticles anchored on graphene as a high-performance anode for lithium ion batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dong, Yu Cheng; Center of Super-Diamond and Advanced Films; Ma, Ru Guang

2013-05-01

We report a scalable strategy to synthesize Fe₃O₄/graphene nanocomposites as a high-performance anode material for lithium ion batteries. In this study, ferric citrate is used as precursor to prepare Fe₃O₄ nanoparticles without introducing additional reducing agent; furthermore and show that such Fe₃O₄ nanoparticles can be anchored on graphene sheets which attributed to multifunctional group effect of citrate. Electrochemical characterization of the Fe₃O₄/graphene nanocomposites exhibit large reversible capacity (~1347 mA h g⁻¹ at a current density of 0.2 C up to 100 cycles, and subsequent capacity of ~619 mA h g⁻¹ at a current density of 2 C up to 200more » cycles), as well as high coulombic efficiency (~97%), excellent rate capability, and good cyclic stability. High resolution transmission electron microscopy confirms that Fe₃O₄ nanoparticles, with a size of ~4–16 nm are densely anchored on thin graphene sheets, resulting in large synergetic effects between Fe₃O₄ nanoparticles and graphene sheets with high electrochemical performance. - Graphical abstract: The reduction of Fe³⁺ to Fe²⁺ and the deposition of Fe₃O₄ on graphene sheets occur simultaneously using citrate function as reductant and anchor agent in this reaction process. Highlights: • Fe₃O₄/graphene composites are synthesized directly from graphene and C₆H₅FeO₇. • The citrate function as reductant and anchor agent in this reaction process. • The resulting Fe₃O₄ particles (~4–16 nm) are densely anchored on graphene sheets. • The prepared Fe₃O₄/graphene composites exhibit excellent electrochemical performance.« less

A reduced graphene oxide/Co 3O 4 composite for supercapacitor electrode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiang, Chengcheng; Li, Ming; Zhi, Mingjia

2013-03-01

20 nm sized Co 3O 4 nanoparticles are in-situ grown on the chemically reduced graphene oxide (rGO) sheets to form a rGO-Co 3O 4 composite during hydrothermal processing. The rGO-Co 3O 4 composite is employed as the pseudocapacitor electrode in the 2 M KOH aqueous electrolyte solution. The rGOCo 3O 4 composite electrode exhibits a specific capacitance of 472 F/g at a scan rate of 2 mV/s in a two-electrode cell. 82.6% of capacitance is retained when the scan rate increases to 100 mV/s. The rGOCo 3O 4 composite electrode shows high rate capability and excellent long-term stability. It alsomore » exhibits high energy density at relatively high power density. The energy density reaches 39.0 Wh/kg at a power density of 8.3 kW/kg. The super performance of the composite electrode is attributed to the synergistic effects of small size and good redox activity of the Co 3O 4 particles combined with high electronic conductivity of the rGO sheets.« less

Communication: Density functional theory embedding with the orthogonality constrained basis set expansion procedure

NASA Astrophysics Data System (ADS)

Culpitt, Tanner; Brorsen, Kurt R.; Hammes-Schiffer, Sharon

2017-06-01

Density functional theory (DFT) embedding approaches have generated considerable interest in the field of computational chemistry because they enable calculations on larger systems by treating subsystems at different levels of theory. To circumvent the calculation of the non-additive kinetic potential, various projector methods have been developed to ensure the orthogonality of molecular orbitals between subsystems. Herein the orthogonality constrained basis set expansion (OCBSE) procedure is implemented to enforce this subsystem orbital orthogonality without requiring a level shifting parameter. This scheme is a simple alternative to existing parameter-free projector-based schemes, such as the Huzinaga equation. The main advantage of the OCBSE procedure is that excellent convergence behavior is attained for DFT-in-DFT embedding without freezing any of the subsystem densities. For the three chemical systems studied, the level of accuracy is comparable to or higher than that obtained with the Huzinaga scheme with frozen subsystem densities. Allowing both the high-level and low-level DFT densities to respond to each other during DFT-in-DFT embedding calculations provides more flexibility and renders this approach more generally applicable to chemical systems. It could also be useful for future extensions to embedding approaches combining wavefunction theories and DFT.

The temperature-productivity squeeze: Constraints on brook trout growth along an Appalachian river continuum

USGS Publications Warehouse

Petty, J. Todd; Thorne, David; Huntsman, Brock M.; Mazik, Patricia M.

2014-01-01

We tested the hypothesis that brook trout growth rates are controlled by a complex interaction of food availability, water temperature, and competitor density. We quantified trout diet, growth, and consumption in small headwater tributaries characterized as cold with low food and high trout density, larger tributaries characterized as cold with moderate food and moderate trout density, and large main stems characterized as warm with high food and low trout density. Brook trout consumption was highest in the main stem where diets shifted from insects in headwaters to fishes and crayfish in larger streams. Despite high water temperatures, trout growth rates also were consistently highest in the main stem, likely due to competitively dominant trout monopolizing thermal refugia. Temporal changes in trout density had a direct negative effect on brook trout growth rates. Our results suggest that competition for food constrains brook trout growth in small streams, but access to thermal refugia in productive main stem habitats enables dominant trout to supplement growth at a watershed scale. Brook trout conservation in this region should seek to relieve the “temperature-productivity squeeze,” whereby brook trout productivity is constrained by access to habitats that provide both suitable water temperature and sufficient prey.

Dynamics, rate and nature of retreat of the British Irish Ice-Sheet offshore of NW Ireland following the Last Glacial Maximum

NASA Astrophysics Data System (ADS)

Weilbach, K.; O'Cofaigh, C.; Lloyd, J. M.; Benetti, S.; Dunlop, P.

2016-12-01

Recent studies of the British and Irish Ice Sheet (BIIS) have identified evidence of ice extending to the continental shelf edge along the western margin of the ice sheet off NW Ireland. While this advance is assumed to have occurred during the LGM, exact timing of maximum advance, and the timing and nature of the subsequent retreat is not well constrained. The location of the north-western sector of the BIIS adjacent to the North Atlantic makes this area ideal to study the ice sheet dynamics of a major marine terminating ice sheet, and the rate and nature of its retreat following the LGM. High resolution swath bathymetry and sub-bottom profiler (SBP) data along with sedimentological, micropalaeontological and geochronological investigations of sediment cores, collected across the NW Irish shelf, have been used to establish the extent, timing and nature of retreat of this sector of the BIIS. Swath bathymetry show glacial landforms on the shelf, and SBP-data along with twenty seven vibro-cores were collected in east-west oriented transects across a series of arcuate recessional moraines stretching from the shelf edge to Donegal Bay. These moraines record progressive still stands of a lobate ice margin during its retreat from the shelf edge, and are therefore ideal for the investigation of ice-sheet dynamics and chronology during retreat. Twenty two radiocarbon dates from foraminifera and macrofossils, sampled from the sediment cores, indicate that maximum ice sheet extent occurred around 26200 y cal BP, with an initial rapid retreat across the shelf. Visual logging, X-ray imagery, MSCL data and palaeoenvironmental analyses of the sediment cores, indicate that retreat happened in a glacimarine environment, and was punctuated by multiple stillstands and possible readvances across the mid and inner shelf, forming the arcuate moraines. The radiocarbon dates suggest that final retreat occurred after 17857 y. cal BP, which is consistent with onshore cosmogenic exposure ages from NW Ireland, showing de-glaciation around 17400 y cal BP.

Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries

PubMed Central

Dash, Ranjan; Pannala, Sreekanth

2016-01-01

Silicon (Si) is under consideration as a potential next-generation anode material for the lithium ion battery (LIB). Experimental reports of up to 40% increase in energy density of Si anode based LIBs (Si-LIBs) have been reported in literature. However, this increase in energy density is achieved when the Si-LIB is allowed to swell (volumetrically expand) more than graphite based LIB (graphite-LIB) and beyond practical limits. The volume expansion of LIB electrodes should be negligible for applications such as automotive or mobile devices. We determine the theoretical bounds of Si composition in a Si–carbon composite (SCC) based anode to maximize the volumetric energy density of a LIB by constraining the external dimensions of the anode during charging. The porosity of the SCC anode is adjusted to accommodate the volume expansion during lithiation. The calculated threshold value of Si was then used to determine the possible volumetric energy densities of LIBs with SCC anode (SCC-LIBs) and the potential improvement over graphite-LIBs. The level of improvement in volumetric and gravimetric energy density of SCC-LIBs with constrained volume is predicted to be less than 10% to ensure the battery has similar power characteristics of graphite-LIBs. PMID:27311811

The density of dark matter in the Galactic bulge and implications for indirect detection

DOE PAGES

Hooper, Dan

2016-11-29

A recent study, making use of the number of horizontal branch stars observed in infrared photometric surveys and kinematic measurements of M-giant stars from the BRAVA survey, combined with N-body simulations of stellar populations, has presented a new determination of the dark matter mass within the bulge-bar region of the Milky Way. That study constrains the total mass within themore » $$\\pm 2.2 \\times \\pm 1.4 \\times \\pm 1.2$$ kpc volume of the bulge-bar region to be ($$1.84 \\pm 0.07) \\times 10^{10} \\, M_{\\odot}$$, of which 9-30% is made up of dark matter. Here, we use this result to constrain the the Milky Way's dark matter density profile, and discuss the implications for indirect dark matter searches. Furthermore uncertainties remain significant, these results favor dark matter distributions with a cusped density profile. For example, for a scale radius of 20 kpc and a local dark matter density of 0.4 GeV/cm$^3$, density profiles with an inner slope of 0.69 to 1.40 are favored, approximately centered around the standard NFW value. In contrast, profiles with large flat-density cores are disfavored by this information.« less

Survey of the plasma electron environment of Jupiter: A view from Voyager

NASA Technical Reports Server (NTRS)

Scudder, J. D.; Sittler, E. C., Jr.; Bridge, H. S.

1980-01-01

The plasma environment within Jupiter's bow shock is considered in terms of the in situ, calibrated electron plasma measurements made between 10 eV and 5.95 keV by the Voyager plasma science experiment (PLS). Measurements were analyzed and corrected for spacecraft potential variations; the data were reduced to nearly model independent macroscopic parameters of the local electron density and temperature. It is tentatively concluded that the radial temperature profile within the plasma sheet is caused by the intermixing of two different electron populations that probably have different temporal histories and spatial paths to their local observation. The cool plasma source of the plasma sheet and spikes is probably the Io plasma torus and arrives in the plasma sheet as a result of flux tube interchange motions or other generalized transport which can be accomplished without diverting the plasma from the centrifugal equator. The hot suprathermal populations in the plasma sheet have most recently come from the sparse, hot mid-latitude "bath" of electrons which were directly observed juxtaposed to the plasma sheet.

Adsorbing H₂S onto a single graphene sheet: A possible gas sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reshak, A. H., E-mail: maalidph@yahoo.co.uk; Center of Excellence Geopolymer and Green Technology, School of Material Engineering, University Malaysia Perlis, 01007 Kangar, Perlis; Auluck, S.

2014-09-14

The electronic structure of pristine graphene sheet and the resulting structure of adsorbing a single molecule of H₂S on pristine graphene in three different sites (bridge, top, and hollow) are studied using the full potential linearized augmented plane wave method. Our calculations show that the adsorption of H₂S molecule on the bridge site opens up a small direct energy gap of about 0.1 eV at symmetry point M, while adsorption of H₂S on top site opens a gap of 0.3 eV around the symmetry point K. We find that adsorbed H₂S onto the hollow site of pristine graphene sheet causesmore » to push the conduction band minimum and the valence band maximum towards Fermi level resulting in a metallic behavior. Comparing the angular momentum decomposition of the atoms projected electronic density of states of pristine graphene sheet with that of H₂S–graphene for three different cases, we find a significant influence of the location of the H₂S molecule on the electronic properties especially the strong hybridization between H₂S molecule and graphene sheet.« less

Space-based Swath Imaging Laser Altimeter for Cryospheric Topographic and Surface Property Mapping

NASA Technical Reports Server (NTRS)

Abshire, James; Harding, David; Shuman, Chris; Sun, Xiaoli; Dabney, Phil; Krainak, Michael; Scambos, Ted

2005-01-01

Uncertainties in the response of the Greenland and Antarctic polar ice sheets to global climatic change inspired the development of ICESat/GLAS as part of NASA's Earth Observing System. ICESat's primary purpose is the measurement of ice sheet surface elevation profiles with sufficient accuracy, spatial density, and temporal coverage so that elevation changes can be derived with an accuracy of <1.5 cm/year for averages of measurements over the ice sheets with areas of 100 x 100 km. The primary means to achieve this elevation change detection is spatial averaging of elevation differences at cross-overs between ascending and descending profiles in areas of low ice surface slope. Additional information is included in the original extended abstract.

Penetration Depth Study of Superconducting Gap Structure of 2H-NbSe2

NASA Astrophysics Data System (ADS)

Fletcher, J. D.; Carrington, A.; Diener, P.; Rodière, P.; Brison, J. P.; Prozorov, R.; Olheiser, T.; Giannetta, R. W.

2007-02-01

We report measurements of the temperature dependence of both in-plane and out-of-plane penetration depths (λa and λc, respectively) in 2H-NbSe2. Measurements were made with a radio-frequency tunnel diode oscillator circuit at temperatures down to 100 mK. Analysis of the anisotropic superfluid density shows that a reduced energy gap is located on one or more of the quasi-two-dimensional Nb Fermi surface sheets rather than on the Se sheet, in contrast with some previous reports. This result suggests that the gap structure is not simply related to the weak electron-phonon coupling on the Se sheet and is therefore important for microscopic models of anisotropic superconductivity in this compound.

Polar semiconductor heterojunction structure energy band diagram considerations

NASA Astrophysics Data System (ADS)

Lin, Shuxun; Wen, Cheng P.; Wang, Maojun; Hao, Yilong

2016-03-01

The unique nature of built-in electric field induced positive/negative charge pairs of polar semiconductor heterojunction structure has led to a more realistic device model for hexagonal III-nitride HEMT. In this modeling approach, the distribution of charge carriers is dictated by the electrostatic potential profile instead of Femi statistics. The proposed device model is found suitable to explain peculiar properties of GaN HEMT structures, including: (1) Discrepancy in measured conventional linear transmission line model (LTLM) sheet resistance and contactless sheet resistance of GaN HEMT with thin barrier layer. (2) Below bandgap radiation from forward biased Nickel Schottky barrier diode on GaN HEMT structure. (3) GaN HEMT barrier layer doping has negligible effect on transistor channel sheet charge density.

Tree canopy types constrain plant distributions in ponderosa pine-Gambel oak forests, northern Arizona

Treesearch

Scott R. Abella

2009-01-01

Trees in many forests affect the soils and plants below their canopies. In current high-density southwestern ponderosa pine (Pinus ponderosa) forests, managers have opportunities to enhance multiple ecosystem values by manipulating tree density, distribution, and canopy cover through tree thinning. I performed a study in northern Arizona ponderosa...

Spectral and Imaging Observations of a Current Sheet Region in a Small-scale Magnetic Reconnection Event

NASA Astrophysics Data System (ADS)

Xue, Zhike; Yan, Xiaoli; Yang, Liheng; Wang, Jincheng; Feng, Song; Li, Qiaoling; Ji, Kaifan; Zhao, Li

2018-05-01

We report a possible current sheet region associated with a small-scale magnetic reconnection event by using the spectral and imaging observations of the Interface Region Imaging Spectrograph (IRIS) and the magnetograms obtained by the Solar Dynamics Observatory on 2016 August 08. The length and width of the current sheet region are estimated to be from 1.4 ± 0.1 Mm to 3.0 ± 0.3 Mm and from 0.34 ± 0.01 Mm to 0.64 ± 0.09 Mm, respectively. The evolutions of the length of the current sheet region are positively correlated with that of the width. These measurements are among the smallest reported. When the IRIS slit scans the current sheet region, the spectroscopic observations show that the Si IV line is broadened in the current sheet region and the plasma has a blueshifted feature at the middle and a redshifted feature at the ends of the current sheet region. The maximum measured blueshifted and redshifted Doppler velocities are ‑20.8 ± 0.9 and 34.1 ± 0.4 km s‑1, respectively. Additionally, the electron number densities of the plasma in the current sheet region are computed to be around 1011 cm‑3 based on the spectrums of the two O IV lines. The emergence, movement, and cancellation of a small sunspot with negative polarity are observed during the formation and shift of the current sheet region. We suggest that the occurrence and evolution of the magnetic reconnection are driven by the movement of the small sunspot in the photosphere.

Method of manufacturing aluminide sheet by thermomechanical processing of aluminide powders

DOEpatents

Hajaligol, Mohammad R.; Scorey, Clive; Sikka, Vinod K.; Deevi, Seetharama C.; Fleishhauer, Grier; Lilly, Jr., A. Clifton; German, Randall M.

2003-12-09

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3% Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Thermomechanical processing of plasma sprayed intermetallic sheets

DOEpatents

Hajaligol, Mohammad R.; Scorey, Clive; Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier; Lilly, Jr., A. Clifton; German, Randall M.

2001-01-01

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3% Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Method of manufacturing aluminide sheet by thermomechanical processing of aluminide powders

DOEpatents

Hajaligol, Mohammad R.; Scorey, Clive; Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier; Lilly, Jr., A. Clifton; German, Randall M.

2000-01-01

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr.ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3% Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Deep drawability of Ti/resin/Ti laminated sheet

NASA Astrophysics Data System (ADS)

Hardada, Yasunroi; Hattori, Shuji

2017-10-01

Aiming to enhance functionality of titanium cup, the formability of titanium/resin/titanium laminated sheet by deep drawing was investigated. Although pure titanium has excellent corrosion resistance, the density of titanium is higher than that of light metals, such as aluminum and magnesium. Part of the titanium cup made of resin allows for weight reduction of the cup. Furthermore, the clad cup is more likely to have heat retention and protection against vibration characteristics. In the experiment, the materials were pure titanium and polycarbonate. The initial thickness of the sheet was 0.2 to 0.5 mm in thickness. A total plate thickness of the blank was 1.0 to 1.5 mm in thickness. The blank diameter is 70 mm. The laminated sheet was constituted by interposing resin between two titanium sheets. Each sheet in stacked condition was not joined each other. In the deep drawing process, the laminated sheet was employed and a flat sheet blank was formed into a circle by a punch. For the prevention of seizure in contact area between a drawing tool and titanium, titanium blank was treated by oxide coating. By this method, the fresh and clean titanium is not in direct contact with the die during the forming due to the existence of the oxide layer. The deep drawing was carried out to investigate the formability. The laminated sheet was successfully drawn without the cracks. The section of the drawn cup was observed to examine a formability of the resin sheet. The reduction rate of the thickness was less than 10%. It was found that the titanium/resin/titanium clad cup was successfully drawn.

Diabetes flow sheet use associated with guideline adherence.

PubMed

Hahn, Karissa A; Ferrante, Jeanne M; Crosson, Jesse C; Hudson, Shawna V; Crabtree, Benjamin F

2008-01-01

Many intervention studies have found that flow sheet use improves patient care by drawing attention to a particular medical condition or needed preventive service and encouraging an immediate response from the health care professional; however, there are no studies examining how often flow sheets are used for diabetes in primary care practice. We assessed the relationship between diabetes flow sheet use and diabetes patient care outcomes in the everyday practice of primary care. We abstracted the medical records of 1,016 patients with diabetes seen at 54 New Jersey and eastern Pennsylvania family practices participating in a quality improvement trial. The use of diabetes flow sheets was noted for each medical record. Scores for adherence to evidence-based diabetes guidelines in terms of assessment, treatment, and target attainment were determined on 100-point scales, with higher scores indicating better adherence. Generalized linear models were used to determine associations between use of diabetes flow sheets and adherence to guidelines. Diabetes flow sheets were used in 23% of the medical records of patients with diabetes. Use of flow sheets was associated with better mean guideline adherence scores for the assessment of diabetes (55.38 vs 50.13, P = .02) and the treatment of diabetes (79.59 vs 74.71, P = .004), but not for the attainment of intermediate diabetes outcome targets (hemoglobin A(1c) level, low-density lipoprotein cholesterol level, and blood pressure). Diabetes flow sheets can be used to promote better adherence to guidelines when it comes to assessing and treating diabetes. Additional research is needed to explore patient and physician variables that mediate the relationship between use of diabetes flow sheets and intermediate outcome targets for diabetes.

20-nm enhancement-mode metamorphic GaAs HEMT with highly doped InGaAs source/drain regions for high-frequency applications

NASA Astrophysics Data System (ADS)

Ajayan, J.; Nirmal, D.

2017-03-01

In this article, the DC and RF performance of a SiN passivated 20-nm gate length metamorphic high electron mobility transistor (MHEMT) on GaAs substrate with highly doped InGaAs source/drain (S/D) regions have investigated using the Synopsys TCAD tool. The 20-nm enhancement-mode (E-mode) MHEMT device also features δ-doped sheets on either side of the In0.53Ga0.47As/InAs/In0.53Ga0.47As channel which exhibits a transconductance of 3100 mS/mm, cut-off frequency (fT) of 740 GHz and a maximum oscillation frequency (fmax) of 1040 GHz. The threshold voltage of the device is found to be 0.07 V. The room temperature Hall mobilities of the 2-dimensional sheet charge density are measured to be over 12,600 cm2/Vs with a sheet charge density larger than 3.6 × 1012 cm-2. These high-performance E-mode MHEMTs are attractive candidates for sub-millimetre wave applications such as high-resolution radars for space research, remote atmospheric sensing, imaging systems and also for low noise wide bandwidth amplifier for future communication systems.

Field-dependent critical state of high-Tc superconducting strip simultaneously exposed to transport current and perpendicular magnetic field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xue, Cun; He, An; Yong, Huadong

We present an exact analytical approach for arbitrary field-dependent critical state of high-T{sub c} superconducting strip with transport current. The sheet current and flux-density profiles are derived by solving the integral equations, which agree with experiments quite well. For small transport current, the approximate explicit expressions of sheet current, flux-density and penetration depth for the Kim model are derived based on the mean value theorem for integration. We also extend the results to the field-dependent critical state of superconducting strip in the simultaneous presence of applied field and transport current. The sheet current distributions calculated by the Kim model agreemore » with experiments better than that by the Bean model. Moreover, the lines in the I{sub a}-B{sub a} plane for the Kim model are not monotonic, which is quite different from that the Bean model. The results reveal that the maximum transport current in thin superconducting strip will decrease with increasing applied field which vanishes for the Bean model. The results of this paper are useful to calculate ac susceptibility and ac loss.« less

Computational insights of water droplet transport on graphene sheet with chemical density

NASA Astrophysics Data System (ADS)

Zhang, Liuyang; Wang, Xianqiao

2014-05-01

Surface gradient has been emerging as an intriguing technique for nanoscale particle manipulation and transportation. Owing to its outstanding and stable chemical properties, graphene with covalently bonded chemical groups represents extraordinary potential for the investigation of nanoscale transport in the area of physics and biology. Here, we employ molecular dynamics simulations to investigate the fundamental mechanism of utilizing a chemical density on a graphene sheet to control water droplet motions on it. Simulation results have demonstrated that the binding energy difference among distinct segment of graphene in terms of interaction between the covalently bonded oxygen atoms on graphene and the water molecules provides a fundamental driving force to transport the water droplet across the graphene sheet. Also, the velocity of the water droplet has showed a strong dependence on the relative concentration of oxygen atoms between successive segments. Furthermore, a multi-direction channel provides insights to guide the transportation of objects towards a targeted position, separating the mixtures with a system of specific chemical functionalization. Our findings shed illuminating lights on the surface gradient method and therefore provide a feasible way to control nanoscale motion on the surface and mimic the channelless microfluidics.

Light Sheet Tomography (LST) for in situ imaging of plant roots.

PubMed

Yang, Zhengyi; Downie, Helen; Rozbicki, Emil; Dupuy, Lionel X; MacDonald, Michael P

2013-07-15

The production of crops capable of efficient nutrient use is essential for addressing the problem of global food security. The ability of a plant's root system to interact with the soil micro-environment determines how effectively it can extract water and nutrients. In order to assess this ability and develop the fast and cost effective phenotyping techniques which are needed to establish efficient root systems, in situ imaging in soil is required. To date this has not been possible due to the high density of scatterers and absorbers in soil or because other growth substrates do not sufficiently model the heterogeneity of a soil's microenvironment. We present here a new form of light sheet imaging with novel transparent soil containing refractive index matched particles. This imaging method does not rely on fluorescence, but relies solely on scattering from root material. We term this form of imaging Light Sheet Tomography (LST). We have tested LST on a range of materials and plant roots in transparent soil and gel. Due to the low density of root structures, i.e. relatively large spaces between adjacent roots, long-term monitoring of lettuce root development in situ with subsequent quantitative analysis was achieved.

On application of asymmetric Kan-like exact equilibria to the Earth magnetotail modeling

NASA Astrophysics Data System (ADS)

Korovinskiy, Daniil B.; Kubyshkina, Darya I.; Semenov, Vladimir S.; Kubyshkina, Marina V.; Erkaev, Nikolai V.; Kiehas, Stefan A.

2018-04-01

A specific class of solutions of the Vlasov-Maxwell equations, developed by means of generalization of the well-known Harris-Fadeev-Kan-Manankova family of exact two-dimensional equilibria, is studied. The examined model reproduces the current sheet bending and shifting in the vertical plane, arising from the Earth dipole tilting and the solar wind nonradial propagation. The generalized model allows magnetic configurations with equatorial magnetic fields decreasing in a tailward direction as slow as 1/x, contrary to the original Kan model (1/x3); magnetic configurations with a single X point are also available. The analytical solution is compared with the empirical T96 model in terms of the magnetic flux tube volume. It is found that parameters of the analytical model may be adjusted to fit a wide range of averaged magnetotail configurations. The best agreement between analytical and empirical models is obtained for the midtail at distances beyond 10-15 RE at high levels of magnetospheric activity. The essential model parameters (current sheet scale, current density) are compared to Cluster data of magnetotail crossings. The best match of parameters is found for single-peaked current sheets with medium values of number density, proton temperature and drift velocity.

Tuning the tunneling magnetoresistance by using fluorinated graphene in graphene based magnetic junctions

NASA Astrophysics Data System (ADS)

Meena, Shweta; Choudhary, Sudhanshu

2017-12-01

Spin polarized properties of fluorinated graphene as tunnel barrier with CrO2 as two HMF electrodes are studied using first principle methods based on density functional theory. Fluorinated graphene with different fluorine coverages is explored as tunnel barriers in magnetic tunnel junctions. Density functional computation for different fluorine coverages imply that with increase in fluorine coverages, there is increase in band gap (Eg) of graphene, Eg ˜ 3.466 e V was observed when graphene sheet is fluorine adsorbed on both-side with 100% coverage (CF). The results of CF graphene are compared with C4F (fluorination on one-side of graphene sheet with 25% coverage) and out-of-plane graphene based magnetic tunnel junctions. On comparison of the results it is observed that CF graphene based structure offers high TMR ˜100%, and the transport of carrier is through tunneling as there are no transmission states near Fermi level. This suggests that graphene sheet with both-side fluorination with 100% coverages acts as a perfect insulator and hence a better barrier to the carriers which is due to negligible spin down current (I ↓ ) in both Parallel Configuration (PC) and Antiparallel Configuration (APC).

Microwave effects on NiMoS and CoMoS single-sheet catalysts.

PubMed

Borges, I; Silva, Alexander M; Modesto-Costa, Lucas

2018-05-04

Single-sheet nanoclusters of MoS 2 , NiMoS or CoMoS are widely used in hydrodesulfurization (HDS) catalysis in the petroleum industry. In HDS reactions under microwave irradiation, experiments indirectly pointed out that for pristine MoS 2 reaction rates are accelerated because hot spots are generated on the catalyst bed. In this work, we investigated NiMoS and CoMoS isolated single-sheet substituted catalysts before and after thiophene adsorption focusing on quantifying the effect of microwave irradiation. For that purpose, density functional theory (DFT) molecular charge densities of each system were decomposed according to the distributed multipole analysis (DMA) of Stone. Site dipole values of each system were directly associated with a larger or smaller interaction with the microwave field according to a proposed general approach. We showed that microwave enhancement of HDS reaction rates can occur more efficiently in the CoMoS and NiMoS promoted clusters compared to pristine MoS 2 in the following order: CoMoS > NiMoS > MoS 2 . The atomic origin of the catalyst hot spots induced by microwaves was clearly established in the promoted clusters.

Electrochemical Properties of Poly(Anthraquinonyl Sulfide)/Graphene Sheets Composites as Electrode Materials for Electrochemical Capacitors

PubMed Central

Lee, Wonkyun; Suzuki, Shinya; Miyayama, Masaru

2014-01-01

Poly(anthraquinonyl sulfide) (PAQS)/graphene sheets (GSs) composite was synthesized through in situ polymerization to evaluate its performance as an electrode material for electrochemical capacitors. PAQS was successfully synthesized in the presence of GSs with uniform distribution. PAQS/GSs showed a pair of reversible redox peaks at around 0 V (vs. Ag/AgCl). The specific capacitance of PAQS/GSs was 349 F·g−1 (86 mAh·g−1) at a current density of 500 mA·g−1, and a capacitance of 305 F·g−1 was maintained even at a high current density of 5000 mA·g−1. The in situ polymerization of PAQS with GSs facilitated their interaction and enabled faster charge transfer and redox reaction, resulting in enhanced electrode properties. PMID:28344238

Density functional study of molecular interactions in secondary structures of proteins.

PubMed

Takano, Yu; Kusaka, Ayumi; Nakamura, Haruki

2016-01-01

Proteins play diverse and vital roles in biology, which are dominated by their three-dimensional structures. The three-dimensional structure of a protein determines its functions and chemical properties. Protein secondary structures, including α-helices and β-sheets, are key components of the protein architecture. Molecular interactions, in particular hydrogen bonds, play significant roles in the formation of protein secondary structures. Precise and quantitative estimations of these interactions are required to understand the principles underlying the formation of three-dimensional protein structures. In the present study, we have investigated the molecular interactions in α-helices and β-sheets, using ab initio wave function-based methods, the Hartree-Fock method (HF) and the second-order Møller-Plesset perturbation theory (MP2), density functional theory, and molecular mechanics. The characteristic interactions essential for forming the secondary structures are discussed quantitatively.

Low density bismaleimide-carbon microballoon composites. [aircraft and submarine compartment safety

NASA Technical Reports Server (NTRS)

Kourtides, D. A.; Parker, J. A. (Inventor)

1978-01-01

A process is described for constructing for a composite laminate structure which exhibits a high resistance to heat and flame provides safer interior structures for aircraft and submarine compartments. Composite laminate structures are prepared by the bismaleimide resin preimpregnation of a fiberglass cloth to form a face sheet which is bonded with a bismaleimide hot melt adhesive to a porous core structure selected from the group consisting of polyamide paper and bismaleimide-glass fabric which is filled with carbon microballoons. The carbon microballoons are prepared by pyrolyzing phenolic micro-balloons in the presence of nitrogen. A slurry of the carbon microballoons is prepared to fill the porous core structure. The porous core structure and face sheet are bonded to provide panel structures exhibiting increased mechanical capacities and lower oxygen limit values and smoke density values.

Evidence for an east-west regional gravity trend in northern Tunisia: Insight into the structural evolution of northern Tunisian Atlas

NASA Astrophysics Data System (ADS)

Jallouli, Chokri; Mogren, Saad; Mickus, Kevin; Turki, Mohamed Moncef

2013-11-01

The Atlas orogeny in northern Algeria and Tunisia led to the destruction of Tethys oceanic lithosphere and cumulated in a collision of microplates rifted off the European margin with the North African continental margin. The location of the boundary between African plate and Kabylian microplate is expressed in northern Algeria by a crustal wedge with double vergence of thrust sheets, whereas in northern Tunisia the geologic environment is more complex and the location of the plate boundary is ambiguous. In this study, we analyzed gravity data to constrain the crustal structure along the northern margin of Tunisia. The analysis includes a separation of regional and residual gravity anomalies and the application of gradient operators to locate density contrast boundaries. The horizontal gradient magnitude and directional gradient highlight a prominent regional E-W gravity gradient in the northern Tunisian Atlas interpreted as a deep fault (active since at least the Early Mesozoic) having a variable kinematic activity depending on the tectonic regime in the region. The main E-W gravity gradient separates two blocks having different gravitational and seismic responses. The southern block has numerous gravity lineaments trending in different directions implying several density variations within the crust, whereas the northern block shows a long-wavelength negative gravity anomaly with a few lineaments. Taking into account the geologic context of the Western Mediterranean region, we consider the E-W prominent feature as the boundary between African plate and Kabylian microplate in northern Tunisia that rifted off Europe. This hypothesis fits most previous geological and geophysical studies and has an important impact on the petroleum and mineral resource prospection as these two blocks were separated by an ocean and they did not belong to the same margin.

Extraction of Ice Sheet Layers from Two Intersected Radar Echograms Near Neem Ice Core in Greenland

NASA Astrophysics Data System (ADS)

Xiong, S.; Muller, J.-P.

2016-06-01

Accumulation of snow and ice over time result in ice sheet layers. These can be remotely sensed where there is a contrast in electromagnetic properties, which reflect variations of the ice density, acidity and fabric orientation. Internal ice layers are assumed to be isochronous, deep beneath the ice surface, and parallel to the direction of ice flow. The distribution of internal layers is related to ice sheet dynamics, such as the basal melt rate, basal elevation variation and changes in ice flow mode, which are important parameters to model the ice sheet. Radar echo sounder is an effective instrument used to study the sedimentology of the Earth and planets. Ice Penetrating Radar (IPR) is specific kind of radar echo sounder, which extends studies of ice sheets from surface to subsurface to deep internal ice sheets depending on the frequency utilised. In this study, we examine a study site where folded ice occurs in the internal ice sheet south of the North Greenland Eemian ice drilling (NEEM) station, where two intersected radar echograms acquired by the Multi-channel Coherent Radar Depth Sounder (MCoRDS) employed in the NASA's Operation IceBridge (OIB) mission imaged this folded ice. We propose a slice processing flow based on a Radon Transform to trace and extract these two sets of curved ice sheet layers, which can then be viewed in 3-D, demonstrating the 3-D structure of the ice folds.

Implications for Crustal Structures and Heat Fluxes from Depth-to-the-Bottom of the Magnetic Source Estimates in West Antarctica, Amundsen Sea Sector

NASA Astrophysics Data System (ADS)

Dziadek, R.; Ferraccioli, F.; Gohl, K.; Spiegel, C.; Kaul, N. E.

2017-12-01

The West Antarctic Rift System is one of the least understood rift systems on earth, but displays a unique coupled relationship between tectonic processes and ice sheet dynamics. Geothermal heat flux (GHF) is a poorly constrained parameter in Antarctica and suspected to affect basal conditions of ice sheets, i.e., basal melting and subglacial hydrology. Thermomechanical models demonstrate the influential boundary condition of geothermal heat flux for (paleo) ice sheet stability. Young, continental rift systems are regions with significantly elevated geothermal heat flux (GHF), because the transient thermal perturbation to the lithosphere caused by rifting requires 100 Ma to reach long-term thermal equilibrium. We discuss airborne, high-resolution magnetic anomaly data from the Amundsen Sea Sector, to provide additional insight into deeper crustal structures related to the West Antarctic Rift System in the Amundsen/Bellingshausen sector. With the depth-to-the-bottom of the magnetic source (DBMS) estimates we reveal spatial changes at the bottom of the igneous crust and the thickness of the magnetic layer, which can be further incorporated into tectonic interpretations. The DBMS also marks an important temperature transition zone of approximately 580°C and therefore serves as a boundary condition for our numerical FEM thermal models in 2D and 3D.

Probabilistic framework for assessing the ice sheet contribution to sea level change.

PubMed

Little, Christopher M; Urban, Nathan M; Oppenheimer, Michael

2013-02-26

Previous sea level rise (SLR) assessments have excluded the potential for dynamic ice loss over much of Greenland and Antarctica, and recently proposed "upper bounds" on Antarctica's 21st-century SLR contribution are derived principally from regions where present-day mass loss is concentrated (basin 15, or B15, drained largely by Pine Island, Thwaites, and Smith glaciers). Here, we present a probabilistic framework for assessing the ice sheet contribution to sea level change that explicitly accounts for mass balance uncertainty over an entire ice sheet. Applying this framework to Antarctica, we find that ongoing mass imbalances in non-B15 basins give an SLR contribution by 2100 that: (i) is comparable to projected changes in B15 discharge and Antarctica's surface mass balance, and (ii) varies widely depending on the subset of basins and observational dataset used in projections. Increases in discharge uncertainty, or decreases in the exceedance probability used to define an upper bound, increase the fractional contribution of non-B15 basins; even weak spatial correlations in future discharge growth rates markedly enhance this sensitivity. Although these projections rely on poorly constrained statistical parameters, they may be updated with observations and/or models at many spatial scales, facilitating a more comprehensive account of uncertainty that, if implemented, will improve future assessments.

Multi-millennia simulation of Greenland deglaciation from the Max-Plank-Institute Model (MPI-ISM) 2xCO2 simulation

NASA Astrophysics Data System (ADS)

Cabot, Vincent; Vizcaino, Miren; Mikolajewicz, Uwe

2016-04-01

Long-term ice sheet and climate coupled simulations are of great interest since they assess how the Greenland Ice Sheet (GrIS) will respond to global warming and how GrIS changes will impact on the climate system. We have run the Max-Plank-Institute Earth System Model coupled with an Ice Sheet Model (SICOPOLIS) over a time period of 10500 years under two times CO2 forcing. This is a coupled atmosphere (ECHAM5T31), ocean (MPI-OM), dynamic vegetation (LPJ), and ice sheet (SICOPOLIS, 10 km horizontal resolution) model. Given the multi-millennia simulation, the horizontal spatial resolution of the atmospheric component is relatively coarse (3.75°). A time-saving technique (asynchronous coupling) is used once the global climate reaches quasi-equilibrium. In our doubling-CO2 simulation, the GrIS is expected to break up into two pieces (one ice cap in the far north on one ice sheet in the south and east) after 3000 years. During the first 500 simulation years, the GrIS climate and surface mass balance (SMB) are mainly affected by the greenhouse effect-forced climate change. After the simulated year 500, the global climate reaches quasi-equilibrium. Henceforth Greenland climate change is mainly due to ice sheet decay. GrIS albedo reduction enhances melt and acts as a powerful feedback for deglaciation. Due to increased cloudiness in the Arctic region as a result of global climate change, summer incoming shortwave radiation is substantially reduced over Greenland, reducing deglaciation rates. At the end of the simulation, Greenland becomes green with forest growing over the newly deglaciated regions. References: Helsen, M. M., van de Berg, W. J., van de Wal, R. S. W., van den Broeke, M. R., and Oerlemans, J. (2013), Coupled regional climate-ice-sheet simulation shows limited Greenland ice loss during the Eemian, Climate of the Past, 9, 1773-1788, doi: 10.5194/cp-9-1773-2013 Helsen, M. M., van de Wal, R. S. W., van den Broeke, M. R., van de Berg, W. J., and Oerlemans, J. (2015), Coupling of climate models and ice sheet models by the surface mass balance gradients: application to the Greenland Ice Sheet, The Cryosphere, 6, 255-272, doi: 10.5194/tc-6-255-2012 Robinson, A., Calov, R., and Ganopolski, A. (2011), Greenland ice sheet model parameters constrained using simulations of the Eemian Interglacial, Climate of the Past, 7, 381-396, doi: 10.5194/cp-7-381-2011 Vizcaino, M., Mikolajewicz, U., Ziemen, F., Rodehacke, C. B., Greve, R., and van den Broeke, M. R. (2015), Coupled simulations of Greenland Ice Sheet and climate change up to A.D. 2300, Geophysical Research Letters, 42, doi: 10.1002/2014GL061142

Microstructure, Mechanical Properties, and Flatness of SEBM Ti-6Al-4V Sheet in As-Built and Hot Isostatically Pressed Conditions

NASA Astrophysics Data System (ADS)

Tang, H. P.; Wang, J.; Song, C. N.; Liu, N.; Jia, L.; Elambasseril, J.; Qian, M.

2017-03-01

Sheet (0.41-4.80 mm thick) or thin plate structures commonly exist in additively manufactured Ti-6Al-4V components for load-bearing applications. A batch of 64 Ti-6Al-4V sheet samples with dimensions of 210/180 mm × 42 mm × 3 mm have been additively manufactured by selective electron beam melting (SEBM). A comprehensive assessment was then made of their density, surface flatness, microstructure, and mechanical properties in both as-built and hot isostatically pressed conditions, including the influence of the hot isostatic pressing (HIP) temperature. In particular, standard long tensile (156 mm long, 2 mm thick) and fatigue (206 mm long, 2 mm thick) test sheet samples were used for assessment. As-built SEBM Ti-6Al-4V sheet samples with machined surfaces fully satisfied the minimum tensile property requirements for mill-annealed TIMETAL Ti-6Al-4V sheet products, whereas HIP-processed samples (2 mm thick) with machined surfaces achieved a high cycle fatigue (HCF) strength of 625 MPa (R = 0.06, 107 cycles), similar to mill-annealed Ti-6Al-4V (500-700 MPa). The unflatness was limited to 0.2 mm in both the as-built and HIP-processed conditions. A range of other revealing observations was discussed for the additive manufacturing of the Ti-6Al-4V sheet structures.

Compensation of Gaussian curvature in developable cones is local

NASA Astrophysics Data System (ADS)

Wang, Jin W.; Witten, Thomas A.

2009-10-01

We use the angular deficit scheme [V. Borrelli, F. Cazals, and J.-M. Morvan, Comput. Aided Geom. Des. 20, 319 (2003)] to determine the distribution of Gaussian curvature in developable cones (d-cones) [E. Cerda, S. Chaieb, F. Melo, and L. Mahadevan, Nature (London) 401, 46 (1999)] numerically. These d-cones are formed by pushing a thin elastic sheet into a circular container. Negative Gaussian curvatures are identified at the rim where the sheet touches the container. Around the rim there are two narrow bands with positive Gaussian curvatures. The integral of the (negative) Gaussian curvature near the rim is almost completely compensated by that of the two adjacent bands. This suggests that the Gauss-Bonnet theorem which constrains the integral of Gaussian curvature globally does not explain the spontaneous curvature cancellation phenomenon [T. Liang and T. A. Witten, Phys. Rev. E 73, 046604 (2006)]. The locality of the compensation seems to increase for decreasing d-cone thickness. The angular deficit scheme also provides a way to confirm the curvature cancellation phenomenon.

Can Seismic Observations of Bed Conditions on Ice Streams Help Constrain Parameters in Ice Flow Models?

NASA Astrophysics Data System (ADS)

Kyrke-Smith, Teresa M.; Gudmundsson, G. Hilmar; Farrell, Patrick E.

2017-11-01

We investigate correlations between seismically derived estimates of basal acoustic impedance and basal slipperiness values obtained from a surface-to-bed inversion using a Stokes ice flow model. Using high-resolution measurements along several seismic profiles on Pine Island Glacier (PIG), we find no significant correlation at kilometer scale between acoustic impedance and either retrieved basal slipperiness or basal drag. However, there is a stronger correlation when comparing average values along the individual profiles. We hypothesize that the correlation appears at the length scales over which basal variations are important to large-scale ice sheet flow. Although the seismic technique is sensitive to the material properties of the bed, at present there is no clear way of incorporating high-resolution seismic measurements of bed properties on ice streams into ice flow models. We conclude that more theoretical work needs to be done before constraints on mechanical conditions at the ice-bed interface from acoustic impedance measurements can be of direct use to ice sheet models.

A quasi-Newton approach to optimization problems with probability density constraints. [problem solving in mathematical programming

NASA Technical Reports Server (NTRS)

Tapia, R. A.; Vanrooy, D. L.

1976-01-01

A quasi-Newton method is presented for minimizing a nonlinear function while constraining the variables to be nonnegative and sum to one. The nonnegativity constraints were eliminated by working with the squares of the variables and the resulting problem was solved using Tapia's general theory of quasi-Newton methods for constrained optimization. A user's guide for a computer program implementing this algorithm is provided.

Fuels planning: science synthesis and integration; environmental consequences fact sheet 14: Fuels reduction and compaction

Treesearch

Deborah Page-Dumroese

2005-01-01

Moving equipment and logs over the surface of forest soils causes gouges and ruts in the mineral soil, displaces organic matter, and can cause compaction. Compaction is the component of soil productivity most influenced by forest management, but the degree to which soils may be compacted depends on initial soil bulk density. For example, low bulk density soils (such as...

Control of silicification by genetically engineered fusion proteins: silk-silica binding peptides.

PubMed

Zhou, Shun; Huang, Wenwen; Belton, David J; Simmons, Leo O; Perry, Carole C; Wang, Xiaoqin; Kaplan, David L

2015-03-01

In the present study, an artificial spider silk gene, 6mer, derived from the consensus sequence of Nephila clavipes dragline silk gene, was fused with different silica-binding peptides (SiBPs), A1, A3 and R5, to study the impact of the fusion protein sequence chemistry on silica formation and the ability to generate a silk-silica composite in two different bioinspired silicification systems: solution-solution and solution-solid. Condensed silica nanoscale particles (600-800 nm) were formed in the presence of the recombinant silk and chimeras, which were smaller than those formed by 15mer-SiBP chimeras, revealing that the molecular weight of the silk domain correlated to the sizes of the condensed silica particles in the solution system. In addition, the chimeras (6mer-A1/A3/R5) produced smaller condensed silica particles than the control (6mer), revealing that the silica particle size formed in the solution system is controlled by the size of protein assemblies in solution. In the solution-solid interface system, silicification reactions were performed on the surface of films fabricated from the recombinant silk proteins and chimeras and then treated to induce β-sheet formation. A higher density of condensed silica formed on the films containing the lowest β-sheet content while the films with the highest β-sheet content precipitated the lowest density of silica, revealing an inverse correlation between the β-sheet secondary structure and the silica content formed on the films. Intriguingly, the 6mer-A3 showed the highest rate of silica condensation but the lowest density of silica deposition on the films, compared with 6mer-A1 and -R5, revealing antagonistic crosstalk between the silk and the SiBP domains in terms of protein assembly. These findings offer a path forward in the tailoring of biopolymer-silica composites for biomaterial related needs. Copyright © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Control of silicification by genetically engineered fusion proteins: Silk–silica binding peptides

PubMed Central

Zhou, Shun; Huang, Wenwen; Belton, David J.; Simmons, Leo O.; Perry, Carole C.; Wang, Xiaoqin; Kaplan, David L.

2014-01-01

In the present study, an artificial spider silk gene, 6mer, derived from the consensus sequence of Nephila clavipes dragline silk gene, was fused with different silica-binding peptides (SiBPs), A1, A3 and R5, to study the impact of the fusion protein sequence chemistry on silica formation and the ability to generate a silk–silica composite in two different bioinspired silicification systems: solution–solution and solution– solid. Condensed silica nanoscale particles (600–800 nm) were formed in the presence of the recombinant silk and chimeras, which were smaller than those formed by 15mer-SiBP chimeras [1], revealing that the molecular weight of the silk domain correlated to the sizes of the condensed silica particles in the solution system. In addition, the chimeras (6mer-A1/A3/R5) produced smaller condensed silica particles than the control (6mer), revealing that the silica particle size formed in the solution system is controlled by the size of protein assemblies in solution. In the solution–solid interface system, silicification reactions were performed on the surface of films fabricated from the recombinant silk proteins and chimeras and then treated to induce β-sheet formation. A higher density of condensed silica formed on the films containing the lowest β-sheet content while the films with the highest β-sheet content precipitated the lowest density of silica, revealing an inverse correlation between the β-sheet secondary structure and the silica content formed on the films. Intriguingly, the 6mer-A3 showed the highest rate of silica condensation but the lowest density of silica deposition on the films, compared with 6mer-A1 and -R5, revealing antagonistic crosstalk between the silk and the SiBP domains in terms of protein assembly. These findings offer a path forward in the tailoring of biopolymer–silica composites for biomaterial related needs. PMID:25462851

Study of Interpolated Timing Recovery Phase-Locked Loop with Linearly Constrained Adaptive Prefilter for Higher-Density Optical Disc

NASA Astrophysics Data System (ADS)

Kajiwara, Yoshiyuki; Shiraishi, Junya; Kobayashi, Shoei; Yamagami, Tamotsu

2009-03-01

A digital phase-locked loop (PLL) with a linearly constrained adaptive filter (LCAF) has been studied for higher-linear-density optical discs. LCAF has been implemented before an interpolated timing recovery (ITR) PLL unit in order to improve the quality of phase error calculation by using an adaptively equalized partial response (PR) signal. Coefficient update of an asynchronous sampled adaptive FIR filter with a least-mean-square (LMS) algorithm has been constrained by a projection matrix in order to suppress the phase shift of the tap coefficients of the adaptive filter. We have developed projection matrices that are suitable for Blu-ray disc (BD) drive systems by numerical simulation. Results have shown the properties of the projection matrices. Then, we have designed the read channel system of the ITR PLL with an LCAF model on the FPGA board for experiments. Results have shown that the LCAF improves the tilt margins of 30 gigabytes (GB) recordable BD (BD-R) and 33 GB BD read-only memory (BD-ROM) with a sufficient LMS adaptation stability.

AB INITIO STUDY OF THE ELECTRONIC AND MAGNETIC PROPERTIES OF GRAPHENE WITH AND WITHOUT ADSORPTION OF M ATOM (M = C, N, O, F, Cl)

NASA Astrophysics Data System (ADS)

Ismail, Ali I.; Mubarak, A. A.

We present here an ab initio study for the energetic, electronic, magnetic and optical structures of the graphene sheet with and without the adsorption of M atom (M = C, N, O, F, Cl). The calculations are preformed using the full-potential linearized augmented plane wave (FP-LAPW) within the generalized gradient approximation (GGA) to describe the exchange-correlation potential. The calculations show that N prefers the bridge site, while C, O, F and Cl prefer the top site above the graphene sheet. The calculated M-graphene bond length is found to be inversely proportional to the adsorption energy. The hybridization between sp-states of the graphene sheet and M adatom is determined by the analysis of the partial and local density of states (PDOS and TDOS). In case of O and F as adsorbed atoms, graphene sheets show a wide energy band-gap and some significant magnetic moments. The optical properties of the studied sheets are performed in different radiation regions using the real and imaginary parts of the dielectric function. We think that the energetic, electronic, optical and magnetic properties of the M-graphene sheets are governed by two main factors; the number of unpaired valence electrons and the electronegativity of the M atom.

The Growth of Instabilities in Annular Liquid Sheets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duke, Daniel J.; Honnery, Damon R; Soria, Julio

An annular liquid sheet surrounded by parallel co-flowing gas is an effective atomiser. However, the initial instabilities which determine the primary break-up of the liquid sheet are not well understood. Lack of agreement on the influence of the boundary conditions and the non-dimension scaling of the initial instability persists between theoretical stability analyses and experiments. To address this matter, we have undertaken an experimental parametric study of an aerodynamically-driven, non-swirling annular water sheet. The effects of sheet thickness, inner and outer gas-liquid momentum ratio were investigated over an order of magnitude variation in Reynolds and Weber number. From high-speed imagemore » correlation measurements in the near-nozzle region, we propose new empirical correlations for the frequency of the instability as a function of the total gas-liquid momentum ratio, with good non-dimensional collapse. From analysis of the instability velocity probability densities, we find two persistent and distinct superimposed instabilities with different growth rates. The first is a short-lived, rapidly saturating sawtooth-like instability. The second is a slower-growing stochastic instability which persists through the break-up of the sheet. The presence of multiple instabilities whose growth rates do not strongly correlate with the shear velocities may explain some of the discrepancies between experiments and stability analyses.« less

On the large-scale structures formed by wakes of open cosmic strings

NASA Technical Reports Server (NTRS)

Hara, Tetsuya; Morioka, Shoji; Miyoshi, Shigeru

1990-01-01

Large-scale structures of the universe have been variously described as sheetlike, filamentary, cellular, bubbles or spongelike. Recently cosmic strings became one of viable candidates for a galaxy formation scenario, and some of the large-scale structures seem to be simply explained by the open cosmic strings. According to this scenario, sheets are wakes which are traces of moving open cosmic strings where dark matter and baryonic matter have accumulated. Filaments are intersections of such wakes and high density regions are places where three wakes intersect almost orthogonally. The wakes formed at t sub eq become the largest surface density among all wakes, where t sub eq is the epoch when matter density equals to radiation density. If we assume that there is one open cosmic string per each horizon, then it can be explained that the typical distances among wakes, filaments and clusters are also approx. 10(exp 2) Mpc. This model does not exclude a much more large scale structure. Open cosmic string may move even now and accumulate cold dark matter after its traces. However, the surface density is much smaller than the ones formed at t sub eq. From this model, it is expected that the typical high density region will have extended features such as six filaments and three sheets and be surrounded by eight empty regions (voids). Here, the authors are mainly concerned with such structures and have made numerical simulations for the formation of such large scale structures.

Constraining dark matter by the 511 keV line

NASA Astrophysics Data System (ADS)

Chan, Man Ho; Leung, Chung Hei

2018-06-01

In the past few decades, observations indicated that an unexplained high production rate of positrons (the strong 511 keV line) exists in the Milky Way center. By using the fact that a large amount of high density gas used to exist near the Milky Way center million years ago, we model the rate of positrons produced due to dark matter annihilation. We consider the effect of adiabatic contraction of dark matter density due to the supermassive black hole at the Milky Way center and perform a detailed calculation to constrain the possible annihilation channel and dark matter mass range. We find that only three annihilation channels (μ+μ-, 4e and 4μ) can provide the required positron production rate and satisfy the stringent constraint of gamma-ray observations. In particular, the constrained mass range for the μ+μ- channel is m ≈ 80 - 100 GeV, which is close to the mass range obtained for the dark matter interpretation of the GeV gamma-ray and positron excess. In other words, the proposed scenario can simultaneously provide the required positron production rate to explain the 511 keV emission, the positron excess and the GeV gamma-ray excess in our Milky Way, and it is compatible with the density spike due to adiabatic growth model of the supermassive black hole.

The South Circumpolar Dorsa Argentea Formation and the Noachian-Hesperian Climate of Mars

NASA Astrophysics Data System (ADS)

Head, J. W., III; Scanlon, K. E.; Fastook, J.; Wordsworth, R. D.

2017-12-01

The Dorsa Argentea Formation (DAF), a set of geomorphologic units covering 1.5 · 106 km2 in the south circumpolar region of Mars with lobes extending along the 0° and 90°W meridians, has been interpreted as the remnants of a large Noachian-Hesperian ice sheet. Determining the extent and thermal regime of the DAF ice sheet, and the controls on its development, can therefore provide insight into the ancient martian climate. We used the Laboratoire de Météorologie Dynamique early Mars global climate model (GCM) and the University of Maine Ice Sheet Model (UMISM) glacial flow model to constrain climates that would permit both development of a south polar ice sheet of DAF-like size and shape and melting consistent with observed eskers and channels. An asymmetric south polar cold trap is a robust feature of GCM simulations with spin-axis obliquity of 15° or 25° and a 600 - 1000 mb CO2 atmosphere. The shape results from the strong dependence of surface temperature on altitude in a thicker atmosphere. Of the scenarios considered here, the shape and extent of the modeled DAF ice sheet in UMISM simulations most closely match those of the DAF when the surface water ice inventory of Mars is 20 · 106 km3 and obliquity is 15°. In climates warmed only by CO2, basal melting does not occur except when the ice inventory is larger than most estimates for early Mars. In this case, the extent of the ice sheet is also much larger than that of the DAF, and melting is more widespread than observed landforms indicate. When an idealized greenhouse gas warms the surface by at least 20° near the poles relative to CO2 alone, the extent of the ice sheet is less than that of the DAF, but strong basal melting occurs, with maxima in the locations where eskers and channels are observed. We conclude that the glaciofluvial landforms in the DAF implicate warming by a gas other than CO2 alone. Previously published exposure ages of eskers in the DAF indicate that eskers were being exposed as activity was ceasing in the equatorial valley networks, suggesting that the warming that allowed basal melting of the DAF ice sheet was broadly contemporaneous with development of the valley networks. Elevated Tharsis topography is required to produce an ice sheet with the shape of the DAF. Thus, our results are not consistent with the DAF (and the valley networks) forming before Tharsis, as recently suggested.

Recent Rise in West Greenland Surface Melt and Firn Density Driven by North Atlantic SSTs and Blocking Events

NASA Astrophysics Data System (ADS)

Osterberg, E. C.; Graeter, K.; Hawley, R. L.; Marshall, H. P.; Ferris, D. G.; Lewis, G.; Birkel, S. D.; Meehan, T.; McCarthy, F.

2017-12-01

The Greenland Ice Sheet (GrIS) has been losing mass since at least the early 2000s, mostly due to enhanced surface melt. Approximately 40% of the surface melt currently generated on the GrIS percolates into the snow/firn and refreezes, where it has no immediate impact on GrIS mass balance or sea-level rise. However, in situ observations of surface melt are sparse, and thus it remains unclear how melt water percolation and refreezing are modifying the GrIS percolation zone under recent warming. In addition, understanding the climatic drivers behind the recent increase in melt is critical for accurately predicting future GrIS surface melt rates and contributions to sea-level rise. Here we show that there have been significant increases in melt refreeze and firn density over the past 30-50 years along a 250 km-long region of the Western Greenland percolation zone (2137 - 2218 m elevation). We collected seven shallow firn cores as part of the 2016 Greenland Traverse for Accumulation and Climate Studies (GreenTrACS), analyzed each for melt layer stratigraphy and density, and developed timescales for each based on annual layer counting of seasonal chemical oscillations (e.g. δ18O, dust, and biogenic sulfur). The cores indicate that refrozen melt layers have increased 2- to 9-fold since 1970, with statistically significant (p < 0.05) linear trends at the five southernmost core sites. Comparisons of two GreenTrACS cores to co-located PARCA cores collected in 1998 reveal significant (p < 0.05) increases in density averaged over the top 10 m of firn ranging from 32-42 kg/m3. Recent density increases closely correspond with the locations of refrozen melt water. We use output from the MARv3.7 Regional Climate Model to assess climatic forcing of surface melt at GreenTrACS sites, and find significant summer-to-summer correlations between melt generation and the frequency of blocking high pressure centers over Greenland (represented by the Greenland Blocking Index; GBI), and with North Atlantic sea surface temperatures (represented by the Atlantic Multidecadal Oscillation; AMO). Thus, future surface melt rates in Western Greenland depend on the complex evolution of the GBI and AMO under anthropogenic forcing, both of which remain poorly constrained in 21st century model projections.

AB-stacked square-like bilayer ice in graphene nanocapillaries.

PubMed

Zhu, YinBo; Wang, FengChao; Bai, Jaeil; Zeng, Xiao Cheng; Wu, HengAn

2016-08-10

Water, when constrained between two graphene sheets and under ultrahigh pressure, can manifest dramatic differences from its bulk counterparts such as the van der Waals pressure induced water-to-ice transformation, known as the metastability limit of two-dimensional (2D) liquid. Here, we present result of a new crystalline structure of bilayer ice with the AB-stacking order, observed from molecular dynamics simulations of constrained water. This AB-stacked bilayer ice (BL-ABI) is transformed from the puckered monolayer square-like ice (pMSI) under higher lateral pressure in the graphene nanocapillary at ambient temperature. BL-ABI is a proton-ordered ice with square-like pattern. The transition from pMSI to BL-ABI is through crystal-to-amorphous-to-crystal pathway with notable hysteresis-loop in the potential energy during the compression/decompression process, reflecting the compression/tensile limit of the 2D monolayer/bilayer ice. In a superheating process, the BL-ABI transforms into the AB-stacked bilayer amorphous ice with the square-like pattern.

A molecular dynamics study on the interaction between epoxy and functionalized graphene sheets

NASA Astrophysics Data System (ADS)

Melro, L. S.; Pyrz, R.; Jensen, L. R.

2016-07-01

The interaction between graphene and epoxy resin was studied using molecular dynamics simulations. The interfacial shear strength and pull out force were calculated for functionalised graphene layers (carboxyl, carbonyl, and hydroxyl) and epoxy composites interfaces. The influence of functional groups, as well as their distribution and coverage density on the graphene sheets were also analysed through the determination of the Young's modulus. Functionalisation proved to be detrimental to the mechanical properties, nonetheless according to interfacial studies the interaction between graphene and epoxy resin increases.

Tunable electrical conductivity of individual graphene oxide sheets reduced at "low" temperatures.

PubMed

Jung, Inhwa; Dikin, Dmitriy A; Piner, Richard D; Ruoff, Rodney S

2008-12-01

Step-by-step controllable thermal reduction of individual graphene oxide sheets, incorporated into multiterminal field effect devices, was carried out at low temperatures (125-240 degrees C) with simultaneous electrical measurements. Symmetric hysteresis-free ambipolar (electron- and hole-type) gate dependences were observed as soon as the first measurable resistance was reached. The conductivity of each of the fabricated devices depended on the level of reduction (was increased more than 10(6) times as reduction progressed), strength of the external electrical field, density of the transport current, and temperature.

Finite geometry effects of field-aligned currents

NASA Technical Reports Server (NTRS)

Fung, Shing F.; Hoffman, R. A.

1992-01-01

Results are presented of model calculations of the magnetic field produced by finite current regions that would be measured by a spaceborne magnetometer. Conditions were examined under which the infinite current sheet approximation can be applied to the calculation of the field-aligned current (FAC) density, using satellite magnetometer data. The accuracy of the three methods used for calculating the current sheet normal direction with respect to the spacecraft trajectory was assessed. It is shown that the model can be used to obtain the position and the orientation of the spacecraft trajectory through the FAC region.

Ultrathin metallized PBI paper

NASA Technical Reports Server (NTRS)

Chenevey, E. C.

1978-01-01

A study to determine the feasibility of preparing ultrathin papers with a target weight of 3.5 g/m squared from polybenzimidazole (PBI) fibrids was undertaken. Small hand sheets of target weight were fabricated. They were light brown, low density materials with sufficient strength to be readily handleable. Characterization of these sheets included strength, fold endurance, thermal gravimetric analysis in air and nitrogen and photomicrographs. Two different batches of PBI fibrids were studied and differences in fabrication performance were noted. In neither case could target weight papers be prepared using conventional paper making techniques.

Optimization of constrained density functional theory

NASA Astrophysics Data System (ADS)

O'Regan, David D.; Teobaldi, Gilberto

2016-07-01

Constrained density functional theory (cDFT) is a versatile electronic structure method that enables ground-state calculations to be performed subject to physical constraints. It thereby broadens their applicability and utility. Automated Lagrange multiplier optimization is necessary for multiple constraints to be applied efficiently in cDFT, for it to be used in tandem with geometry optimization, or with molecular dynamics. In order to facilitate this, we comprehensively develop the connection between cDFT energy derivatives and response functions, providing a rigorous assessment of the uniqueness and character of cDFT stationary points while accounting for electronic interactions and screening. In particular, we provide a nonperturbative proof that stable stationary points of linear density constraints occur only at energy maxima with respect to their Lagrange multipliers. We show that multiple solutions, hysteresis, and energy discontinuities may occur in cDFT. Expressions are derived, in terms of convenient by-products of cDFT optimization, for quantities such as the dielectric function and a condition number quantifying ill definition in multiple constraint cDFT.

Evaluating competing forces constraining glacial grounding-line stability (Invited)

NASA Astrophysics Data System (ADS)

Powell, R. D.

2013-12-01

Stability of grounding lines of marine-terminating glaciers and ice sheets is of concern due to their importance in governing rates of ice mass loss and consequent sea level rise during global warming. Although processes are similar at tidewater and floating grounding zones their relative magnitudes in terms of their influence on grounding-line stability vary between these two end members. Processes considered Important for this discussion are ice dynamics, ice surface melting and crevassing, ocean dynamics, subglacial sediment and water dynamics, and subglacial bed geometries. Models have continued to improve in their representation of these complex interactions but reliable field measurements and data continue to be hard earned and too few to properly constrain the range of boundary conditions in this complicated system. Some data will be presented covering a range of regimes from Alaska, Svalbard and Antarctica. Certainly more data are required on subglacial sediment/water dynamics and fluxes to fully represent the spectrum of glacial regimes and to assess the significance of grounding-zone sediment systems in counteracting the other processes to force grounding-line stability. Especially important here is constraining the duration of the stability that could be maintained by sediment flux - present data appear to show that it is likely to be a limited period.

Solving the Secondary Structure Matching Problem in Cryo-EM De Novo Modeling Using a Constrained K-Shortest Path Graph Algorithm.

PubMed

Al Nasr, Kamal; Ranjan, Desh; Zubair, Mohammad; Chen, Lin; He, Jing

2014-01-01

Electron cryomicroscopy is becoming a major experimental technique in solving the structures of large molecular assemblies. More and more three-dimensional images have been obtained at the medium resolutions between 5 and 10 Å. At this resolution range, major α-helices can be detected as cylindrical sticks and β-sheets can be detected as plain-like regions. A critical question in de novo modeling from cryo-EM images is to determine the match between the detected secondary structures from the image and those on the protein sequence. We formulate this matching problem into a constrained graph problem and present an O(Δ(2)N(2)2(N)) algorithm to this NP-Hard problem. The algorithm incorporates the dynamic programming approach into a constrained K-shortest path algorithm. Our method, DP-TOSS, has been tested using α-proteins with maximum 33 helices and α-β proteins up to five helices and 12 β-strands. The correct match was ranked within the top 35 for 19 of the 20 α-proteins and all nine α-β proteins tested. The results demonstrate that DP-TOSS improves accuracy, time and memory space in deriving the topologies of the secondary structure elements for proteins with a large number of secondary structures and a complex skeleton.

Subglacial carbonate precipitates on central Baffin Island, Arctic Canada may constrain basal conditions for the Foxe sector of the Laurentide Ice Sheet

NASA Astrophysics Data System (ADS)

Miller, G. H.; Refsnider, K. A.

2009-12-01

Extensive, widespread carbonate deposits on gneissic bedrock have recently been discovered around the Barnes Ice Cap, central Baffin Island. Deposits range from conglomeratic crack-fillings ≤5 cm thick to laminated, striated films plastered on bedrock surfaces, often in the lee of obstacles. A single outcrop of these carbonates was first described by Andrews et al. (1972, Canadian Journal of Earth Sciences, 9, 233-238) and was interpreted as an early Tertiary limestone based on the presence of warm-climate palynomorphs including Liriodendron (tulip tree), Ulmus (elm), and Taxodium (cypress). However, recent fieldwork in the region has demonstrated that these carbonates are far more ubiquitous than previously thought and found on both glacially-polished bedrock surfaces and till boulders that melted out in recent decades from Laurentide ice at the base of the Barnes Ice Cap. In many cases, these carbonates exhibit the characteristic morphologies of subglacial carbonates (flutes, furrows, and striations parallel to the direction of ice flow, columnar spicules, and tufa-dam-like forms). A few deposits include angular sands, gravels, and pebbles. The nearest carbonate bedrock is Paleozoic limestone flooring Foxe Basin 130 km west of the Barnes Ice Cap summit. While subglacial carbonate deposits have been documented adjacent to retreating mountain and outlet glaciers and in areas previously covered by Pleistocene ice sheets, few localities are distant from carbonate bedrock. Thus, the carbon required for carbonate deposition in the Barnes region was either (1) derived from Paleozoic limestone and dissolved in subglacial water that was subject to long-distance transport, or (2) there was sufficient trapped atmospheric CO2 in the ice to yield alkaline basal meltwater which hydrolyzed calcium-bearing silicates in the local bedrock. Given the volume of carbonate deposited at some sites, we find the latter model unlikely. If the former model is applicable, these carbonates will provide considerable insight into subglacial processes beneath the Foxe sector of the Laurentide Ice Sheet and possibly constrain the former ice thicknesses above these sites. Quantitative x-ray diffraction defines the mineralogy of both the carbonate and clastic components. Carbon and strontium isotopes in the carbonate precipitates, Foxe Basin Paleozoic bedrock, and local bedrock should define the source of the carbon and calcium in the deposits. Oxygen isotopes of Barnes Ice Cap Laurentide ice and the carbonates provide a unique opportunity to compare the isotopic composition of subglacial carbonates with the isotopic composition of the actual ice sheet under which they were precipitated.

Improved GIA Correction and Antarctic Contribution to Sea-level Rise Observed by GRACE

NASA Astrophysics Data System (ADS)

Ivins, Erik; James, Thomas; Wahr, John; Schrama, Ernst; Landerer, Felix; Simon, Karen

2013-04-01

Measurement of continent-wide glacial isostatic adjustment (GIA) is needed to interpret satellite-based trends for the grounded ice mass change of the Antarctic ice sheet (AIS). This is especially true for trends determined from the Gravity Recovery and Climate Experiment (GRACE) satellite mission. Three data sets have matured to the point where they can be used to shrink the range of possible GIA models for Antarctica: the glacial geological record has expanded to include exposure ages using 10Be,26Al measurements that constrain past thickness of the ice sheet, modelled ice core records now better constrain the temporal variation in past rates of snow accumulation, and Global Positioning System (GPS) vertical rate trends from across the continent are now available. The volume changes associated with Antarctic ice loading and unloading during the past 21 thousand years (21 ka) are smaller than previously thought, generating model present-day uplift rates that are consistent with GPS observations. We construct an ice sheet history that is designed to predict maximum volume changes, and in particular, maximum Holocene change. This ice sheet model drives a forward model prediction of GIA gravity signal, that in turn, should give maximum GIA response predictions. The apparent surface mass change component of GIA is re-evaluated to be +55 ± 13 Gt/yr by considering a revised ice history model and a parameter search for vertical motion predictions that best-fit the GPS observations at 18 high-quality stations. Although the GIA model spans a wide range of possible earth rheological structure values, the data are not yet sufficient for solving for a preferred value of upper and lower mantle viscosity, nor for a preferred lithospheric thickness. GRACE monthly solutions from CSR-RL04 release time series from Jan. 2003 through the beginning of Jan. 2012, uncorrected for GIA, yield an ice mass rate of +2.9 ± 34 Gt/yr. A new rough upper bound to the GIA correction is about 60-65 Gt/yr. The new correction increases the solved-for ice mass imbalance of Antarctica to -57 ± 34 Gt/yr. The revised GIA correction is smaller than past GRACE estimates by about 50 to 90 Gt/yr. The new upper bound to sea-level rise from AIS mass loss averaged over the time span 2003.0 - 2012.0 is about 0.16 ± 0.09 mm/yr. We discuss the differences in spatio-temporal character of the gain-loss regimes of Antarctica over the observing period.

Damage Tolerance of Sandwich Plates With Debonded Face Sheets

NASA Technical Reports Server (NTRS)

Sankar, Bhavani V.

2001-01-01

A nonlinear finite element analysis was performed to simulate axial compression of sandwich beams with debonded face sheets. The load - end-shortening diagrams were generated for a variety of specimens used in a previous experimental study. The energy release rate at the crack tip was computed using the J-integral, and plotted as a function of the load. A detailed stress analysis was performed and the critical stresses in the face sheet and the core were computed. The core was also modeled as an isotropic elastic-perfectly plastic material and a nonlinear post buckling analysis was performed. A Graeco-Latin factorial plan was used to study the effects of debond length, face sheet and core thicknesses, and core density on the load carrying capacity of the sandwich composite. It has been found that a linear buckling analysis is inadequate in determining the maximum load a debonded sandwich beam can carry. A nonlinear post-buckling analysis combined with an elastoplastic model of the core is required to predict the compression behavior of debonded sandwich beams.

Anisotropic carrier mobility in single- and bi-layer C3N sheets

NASA Astrophysics Data System (ADS)

Wang, Xueyan; Li, Qingfang; Wang, Haifeng; Gao, Yan; Hou, Juan; Shao, Jianxin

2018-05-01

Based on the density functional theory combined with the Boltzmann transport equation with relaxation time approximation, we investigate the electronic structure and predict the carrier mobility of single- and bi-layer newly fabricated 2D carbon nitrides C3N. Although C3N sheets possess graphene-like planar hexagonal structure, the calculated carrier mobility is remarkably anisotropic, which is found mainly induced by the anisotropic effective masses and deformation potential constants. Importantly, we find that both the electron and hole mobilities are considerable high, for example, the hole mobility along the armchair direction of single-layer C3N sheets can arrive as high as 1.08 ×104 cm2 V-1 s-1, greatly larger than that of C2N-h2D and many other typical 2D materials. Owing to the high and anisotropic carrier mobility and appropriate band gap, single- and bi-layer semiconducting C3N sheets may have great potential applications in high performance electronic and optoelectronic devices.

Mass balance of the Antarctic ice sheet.

PubMed

Wingham, D J; Shepherd, A; Muir, A; Marshall, G J

2006-07-15

The Antarctic contribution to sea-level rise has long been uncertain. While regional variability in ice dynamics has been revealed, a picture of mass changes throughout the continental ice sheet is lacking. Here, we use satellite radar altimetry to measure the elevation change of 72% of the grounded ice sheet during the period 1992-2003. Depending on the density of the snow giving rise to the observed elevation fluctuations, the ice sheet mass trend falls in the range -5-+85Gtyr-1. We find that data from climate model reanalyses are not able to characterise the contemporary snowfall fluctuation with useful accuracy and our best estimate of the overall mass trend-growth of 27+/-29Gtyr-1-is based on an assessment of the expected snowfall variability. Mass gains from accumulating snow, particularly on the Antarctic Peninsula and within East Antarctica, exceed the ice dynamic mass loss from West Antarctica. The result exacerbates the difficulty of explaining twentieth century sea-level rise.

Particle-in-cell simulations of collisionless magnetic reconnection with a non-uniform guide field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilson, F., E-mail: fw237@st-andrews.ac.uk; Neukirch, T., E-mail: tn3@st-andrews.ac.uk; Harrison, M. G.

Results are presented of a first study of collisionless magnetic reconnection starting from a recently found exact nonlinear force-free Vlasov–Maxwell equilibrium. The initial state has a Harris sheet magnetic field profile in one direction and a non-uniform guide field in a second direction, resulting in a spatially constant magnetic field strength as well as a constant initial plasma density and plasma pressure. It is found that the reconnection process initially resembles guide field reconnection, but that a gradual transition to anti-parallel reconnection happens as the system evolves. The time evolution of a number of plasma parameters is investigated, and themore » results are compared with simulations starting from a Harris sheet equilibrium and a Harris sheet plus constant guide field equilibrium.« less

3D MHD SIMULATION OF FLARE SUPRA-ARCADE DOWNFLOWS IN A TURBULENT CURRENT SHEET MEDIUM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cécere, M.; Zurbriggen, E.; Costa, A.

2015-07-01

Supra-arcade downflows (SADs) are sunward, generally dark, plasma density depletions originated above posteruption flare arcades. In this paper, using 3D MHD simulations we investigate whether the SAD cavities can be produced by a direct combination of the tearing mode and Kelvin–Helmholtz instabilities leading to a turbulent current sheet (CS) medium or if the current sheet is merely the background where SADs are produced, triggered by an impulsive deposition of energy. We find that to give an account of the observational dark lane structures an addition of local energy, provided by a reconnection event, is required. We suggest that there maymore » be a closed relation between characteristic SAD sizes and CS widths that must be satisfied to obtain an observable SAD.« less

3D MHD Simulation of Flare Supra-Arcade Downflows in a Turbulent Current Sheet Medium

NASA Astrophysics Data System (ADS)

Cécere, M.; Zurbriggen, E.; Costa, A.; Schneiter, M.

2015-07-01

Supra-arcade downflows (SADs) are sunward, generally dark, plasma density depletions originated above posteruption flare arcades. In this paper, using 3D MHD simulations we investigate whether the SAD cavities can be produced by a direct combination of the tearing mode and Kelvin-Helmholtz instabilities leading to a turbulent current sheet (CS) medium or if the current sheet is merely the background where SADs are produced, triggered by an impulsive deposition of energy. We find that to give an account of the observational dark lane structures an addition of local energy, provided by a reconnection event, is required. We suggest that there may be a closed relation between characteristic SAD sizes and CS widths that must be satisfied to obtain an observable SAD.

A MoO2 sheet as a promising electrode material: ultrafast Li-diffusion and astonishing Li-storage capacity

NASA Astrophysics Data System (ADS)

Zhou, Yungang; Geng, Cheng

2017-03-01

The potential of MoO2 crystal as an electrode material is reported, and nanostructural MoO2 systems, including nanoparticles, nanospheres, nanobelts and nanowires, were synthesized and proved to be advanced electrode materials. A two-dimensional (2D) geometric structure represents an extreme of surface-to-volume ratio, and thus is more suitable as an electrode material in general. Stimulated by the recent fabrication of 2D MoO2, we adopted an ab initio molecular dynamics simulation and density functional theory calculation to study the stability and electrochemical properties of a MoO2 sheet. Identified by a phonon dispersion curve and potential energy curve calculations, the MoO2 sheet proved to be dynamically and thermally stable. After lithiation, similar to most promising 2D structures, we found that a Li atom can strongly adsorb on a MoO2 sheet, and the lithiated MoO2 sheet presented excellent metallic properties. Note that, compared with most promising 2D structures, we unexpectedly revealed that the diffusion barrier of the Li atom on the MoO2 sheet was much lower and the storage capacity of the MoO2 sheet was much larger. The calculated energy barrier for the diffusion of Li on the MoO2 sheet was only 75 meV, and, due to multilayer adsorption, the theoretical capacity of the MoO2 sheet can reach up to 2513 mA h g-1. Benefiting from general properties, such as strong Li-binding and excellent conductivity, and unique phenomena, such as ultrafast diffusion capacity and astonishing storage capacity, we highlight a new promising electrode material for the Li-ion battery.

Polymer quenched prealloyed metal powder

DOEpatents

Hajaligol, Mohammad R.; Fleischhauer, Grier; German, Randall M.

2001-01-01

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

New X-ray bound on density of primordial black holes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Inoue, Yoshiyuki; Kusenko, Alexander, E-mail: yinoue@astro.isas.jaxa.jp, E-mail: kusenko@ucla.edu

We set a new upper limit on the abundance of primordial black holes (PBH) based on existing X-ray data. PBH interactions with interstellar medium should result in significant fluxes of X-ray photons, which would contribute to the observed number density of compact X-ray objects in galaxies. The data constrain PBH number density in the mass range from a few M {sub ⊙} to 2× 10{sup 7} M {sub ⊙}. PBH density needed to account for the origin of black holes detected by LIGO is marginally allowed.

Charge transport in nanostructured materials: Implementation and verification of constrained density functional theory

DOE PAGES

Goldey, Matthew B.; Brawand, Nicholas P.; Voros, Marton; ...

2017-04-20

The in silico design of novel complex materials for energy conversion requires accurate, ab initio simulation of charge transport. In this work, we present an implementation of constrained density functional theory (CDFT) for the calculation of parameters for charge transport in the hopping regime. We verify our implementation against literature results for molecular systems, and we discuss the dependence of results on numerical parameters and the choice of localization potentials. In addition, we compare CDFT results with those of other commonly used methods for simulating charge transport between nanoscale building blocks. As a result, we show that some of thesemore » methods give unphysical results for thermally disordered configurations, while CDFT proves to be a viable and robust approach.« less

Experimental investigation of fiberglass sandwich composite bending behaviour after severe aging condition

NASA Astrophysics Data System (ADS)

Gambaro, Carla; Lertora, Enrico; Mandolfino, Chiara

2016-10-01

Fiber Reinforced Polymer (FRP) sandwich panels are increasing their application as structural and non-structural components in all kinds of construction. By varying the material and thickness of core and face sheets, it is possible to obtain sandwich structures with different properties and performance. In particular, their advantages as lightweight and high mechanical properties make them extremely suitable for the transport industry. One of the most critical aspects regarding composite materials for engineering application is their performance after hygrothermal aging. The panels used in this study are composed of low density core, made by thermosetting resin foam with microspheres and glass fibers rolled until obtaining the required thickness, and two face sheets of the same material but realized in high density. In this study, the authors focused on the bending behaviour of this kind of sandwich panel, as received and after severe aging cycles.

Bouguer gravity anomaly and isostatic residual gravity maps of the Tonopah 1 degree by 2 degrees Quadrangle, central Nevada

USGS Publications Warehouse

Plouff, Donald

1992-01-01

A residual isostatic gravity map (sheet 2) was prepared so that the regional effect of isostatic compensation present on the Bouguer gravity anomaly map (sheet 1) would be minimized. Isostatic corrections based on the Airy-Heiskanen system (Heiskanen and Vening Meinesz, 1958, p. 135-137) were estimated by using 3-minute topographic digitization and applying the method of Jachens and Roberts (1981). Parameters selected for the isostatic model were 25 km for the normal crustal thickness at sea level, 2.67 g/cm3 for the density of the crust, and 0.4 g/cm3 for the contrast in density between the crust and the upper mantle. These parameters were selected so that the isostatic residual gravity map would be consistent with isostatic residual gravity maps of the adjacent Walker Lake quadrangle (Plouff, 1987) and the state of Nevada (Saltus, 1988c).

Advanced Class of FML on the Base Al-Li Alloy 1441 with Lower Density

NASA Astrophysics Data System (ADS)

Antipov, V. V.; Senatorova, O. G.; Lukina, N. F.

Structure, composition, properties combination of specimens and components, a number of technological parameters for production of advanced FML based on high-modulus Al-Li 1441 alloy (E 79 GPa) with reduced density (d 2.6 g/m3) and optimized adhesive prepreg reinforced with high-strength high-modulus VMP glass fibres are described. Service life 1441 alloy provides the possibility of manufacture of thin sheets (up to 0.3 mm), clad and unclad. Moreover, some experience on the usage of 1441 T1, T11 sheets and shapes in Be 200 and Be 103 aircraft was accumulated. The class of FML materials based on Al-Li alloy provide an 5% improvement in weight efficiency and stiffness of skin structures as compared with those made from FML with conventional Al-Cu-Mg (2024T3 a.o.) and Al-Zn-Mg-Cu (7475T76 a.o.) alloys.

Relationships between field-aligned currents, electric fields, and particle precipitation as observed by Dynamics Explorer-2

NASA Technical Reports Server (NTRS)

Sugiura, M.; Iyemori, T.; Hoffman, R. A.; Maynard, N. C.; Burch, J. L.; Winningham, J. D.

1984-01-01

The relationships between field-aligned currents, electric fields, and particle fluxes are determined using observations from the polar orbiting low-altitude satellite Dynamics Explorer-2. It is shown that the north-south electric field and the east-west magnetic field components are usually highly correlated in the field-aligned current regions. This proportionality observationally proves that the field-aligned current equals the divergence of the height-integrated ionospheric Pedersen current in the meridional plane to a high degree of approximation. As a general rule, in the evening sector the upward field-aligned currents flow in the boundary plasma sheet region and the downward currents flow in the central plasma sheet region. The current densities determined independently from the plasma and magnetic field measurements are compared. Although the current densities deduced from the two methods are in general agreement, the degree and extent of the agreement vary in individual cases.

Relationships between field-aligned currents, electric fields and particle precipitation as observed by dynamics Explorer-2

NASA Technical Reports Server (NTRS)

Sugiura, M.; Iyemori, T.; Hoffman, R. A.; Maynard, N. C.; Burch, J. L.; Winningham, J. D.

1983-01-01

The relationships between field-aligned currents, electric fields, and particle fluxes are determined using observations from the polar orbiting low-altitude satellite Dynamics Explorer-2. It is shown that the north-south electric field and the east-west magnetic field components are usually highly correlated in the field-aligned current regions. This proportionality observationally proves that the field-aligned current equals the divergence of the height-integrated ionospheric Pedersen current in the meridional plane to a high degree of approximation. As a general rule, in the evening sector the upward field-aligned currents flow in the boundary plasma sheet region and the downward currents flow in the central plasma sheet region. The current densities determined independently from the plasma and magnetic field measurements are compared. Although the current densities deduced from the two methods are in general agreement, the degree and extent of the agreement vary in individual cases.

Comparison on exfoliated graphene nano-sheets and triturated graphite nano-particles for mode-locking the Erbium-doped fibre lasers

NASA Astrophysics Data System (ADS)

Yang, Chun-Yu; Lin, Yung-Hsiang; Wu, Chung-Lun; Cheng, Chih-Hsien; Tsai, Din-Ping; Lin, Gong-Ru

2018-06-01

Comparisons on exfoliated graphene nano-sheets and triturated graphite nano-particles for mode-locking the Erbium-doped fiber lasers (EDFLs) are performed. As opposed to the graphite nano-particles obtained by physically triturating the graphite foil, the tri-layer graphene nano-sheets is obtained by electrochemically exfoliating the graphite foil. To precisely control the size dispersion and the layer number of the exfoliated graphene nano-sheet, both the bias of electrochemical exfoliation and the speed of centrifugation are optimized. Under a threshold exfoliation bias of 3 volts and a centrifugation at 1000 rpm, graphene nano-sheets with an average diameter of 100  ±  40 nm can be obtained. The graphene nano-sheets with an area density of 15 #/µm2 are directly imprinted onto the end-face of a single-mode fiber made patchcord connector inside the EDFL cavity. Such electrochemically exfoliated graphene nano-sheets show comparable saturable absorption with standard single-graphene and perform the self-amplitude modulation better than physically triturated graphite nano-particles. The linear transmittance and modulation depth of the inserted graphene nano-sheets are 92.5% and 53%, respectively. Under the operation with a power gain of 21.5 dB, the EDFL can be passively mode-locked to deliver a pulsewidth of 454.5 fs with a spectral linewidth of 5.6 nm. The time-bandwidth product of 0.31 is close to the transform limit. The Kelly sideband frequency spacing of 1.34 THz is used to calculate the chirp coefficient as  ‑0.0015.

Engineering the work function of buckled boron α-sheet by lithium adsorption: a first-principles investigation.

PubMed

Zheng, Bing; Yu, Hai-tao; Xie, Ying; Lian, Yong-fu

2014-11-26

First-principles density functional theory calculations were performed to study the effect of Li adsorption on the structural and electronic properties, particularly the work function, of boron α-sheet. The calculated binding energies indicated that boron α-sheet could be well stabilized by the adsorption of Li atoms. Furthermore, the work functions of Li-adsorbed boron α-sheets were observed to decrease drastically with increasing Li coverage. The work functions are lower than that of Mg and even, for some of them, lower than that of Ca, indicating a considerable potential application of Li-adsorbed boron α-sheets as field-emission and electrode materials. Based on the calculated geometric and electronic structures, we discuss in details some possible aspects affecting the work function. The Li coverage dependence of the work functions of Li-adsorbed boron α-sheets was further confirmed by electrostatic potential analyses. The relationship between the work function variation and the Fermi and vacuum energy level shifts was also discussed, and we observed that the variation of the work function is primarily associated with the shift of the Fermi energy level. It is the surface dipole formed by the interaction between adatoms and substrate that should be responsible for the observed variation of the work function, whereas the increasing negative charge and rumpling for boron α-sheet only play minor roles. Additionally, the effect of Li adatoms on the work function of boron α-sheet was confirmed to be much stronger than that of graphene or a graphene double layer.

High-Energy-Density Capacitors

NASA Technical Reports Server (NTRS)

Slenes, Kirk

2003-01-01

Capacitors capable of storing energy at high densities are being developed for use in pulse-power circuits in such diverse systems as defibrillators, particle- beam accelerators, microwave sources, and weapons. Like typical previously developed energy-storage capacitors, these capacitors are made from pairs of metal/solid-dielectric laminated sheets that are wound and pressed into compact shapes to fit into cans, which are then filled with dielectric fluids. Indeed, these capacitors can be fabricated largely by conventional fabrication techniques. The main features that distinguish these capacitors from previously developed ones are improvements in (1) the selection of laminate materials, (2) the fabrication of the laminated sheets from these materials, and (3) the selection of dielectric fluids. In simplest terms, a high-performance laminated sheet of the type used in these capacitors is made by casting a dielectric polymer onto a sheet of aluminized kraft paper. The dielectric polymer is a siloxane polymer that has been modified with polar pendant groups to increase its permittivity and dielectric strength. Potentially, this polymer is capable of withstanding an energy density of 7.5 J/cm3, which is four times that of the previous state-of-the-art-capacitor dielectric film material. However, the full potential of this polymer cannot be realized at present because (1) at thicknesses needed for optimum performance (.8.0 m), the mechanical strength of a film of this polymer is insufficient for incorporation into a wound capacitor and (2) at greater thickness, the achievable energy density decreases because of a logarithmic decrease in dielectric strength with increasing thickness. The aluminized kraft paper provides the mechanical strength needed for processing of the laminate and fabrication of the capacitor, and the aluminum film serves as an electrode layer. Because part of the thickness of the dielectric is not occupied by the modified siloxane polymer, the achievable energy density must be somewhat less than the maximum value. The laminate is produced by a continuous film-casting process, using the machinery depicted schematically in the figure. The designs of the process and machinery are dictated partly by the fact that during the processing step prior to casting the polymer, the aluminized kraft paper becomes wet with water. Because the polymer resin to be cast is hydrophobic, the paper must be dried to make it possible to coat the paper uniformly, leaving no pinholes. Accordingly, an infrared heater is placed next to the paper feed roll to dry the paper prior to casting.

Constraining calving front processes on W Greenland outlet glaciers using inertial-corrected laser scanning & swath-bathymetry

NASA Astrophysics Data System (ADS)

Bates, R.; Hubbard, A.; Neale, M.; Woodward, J.; Box, J. E.; Nick, F.

2010-12-01

Calving and submarine melt account for the majority of loss from the Antarctic and over 50% of that from the Greenland Ice Sheet. These ice-ocean processes are highly efficient mass-loss mechanisms, providing a rapid link between terrestrial ice (storage) and the oceanic sink (sea level/freshwater flux) which renders the ocean-outlet-ice sheet system potentially highly non-linear. Despite this, the controls on tidewater processes are poorly understood and a process based description of them is lacking from the present generation of coupled ice sheet models. We present details from an innovative study where two survey techniques are integrated to enable the construction of accurate, ~m resolution 3d digital terrain models (DTMs) of the aerial and submarine ice front of calving outlet glaciers. A 2km range terrestrial laser scanner was combined with a 416KHz swath-interferometric system and corrected via an inertial motion unit stabilized by RTK GPS and gyro-compass data. The system was mounted aboard a heavy displacement (20,000kg) yacht in addition to a light displacement (100kg) semi-autonomous boat and used to image the aerial and submarine calving fronts of two large outlet glaciers in W Greenland. Six daily surveys, each 2.5km long were repeated across Lille Glacier during which significant ice flow, melt and calving events were observed and captured from on-ice GPS stations and time-lapse sequences. A curtain of CTD and velocity casts were also conducted to constrain the fresh and oceanic mass and energy fluxes within the fjord. The residual of successive DTMs yield the spatial pattern of frontal change enabling the processes of aerial and submarine calving and melt to be quantified and constrained in unprecedented detail. These observed frontal changes are tentatively related to local dynamic, atmospheric and oceanographic processes that drive them. A partial survey of Store Glacier (~7km calving front & W Greenland 2nd largest outlet after Jakobshavn Isbrae) was conducted, indicating that the technique is successful up to ~500m from the ice front and to a similar water depth. These data sets show that it is possible to integrate and build 3d DTMs at the metre-scale both above and below the water surface. The successful acquisition from our semi-autonomous vessel supervised up to 2km away greatly eases repeat surveys and reduces the exposure of equipment and personnel to the risks posed by large, active calving glaciers. Lille Glacier and s/v Gambo surveyed & photographed from the semi-autonomous vessel. Mock-up of Lille Glacier calving front and fore-bay submarine topography imaged by interferometric swath-bathymetry.

On the calculation of charge transfer transitions with standard density functionals using constrained variational density functional theory.

PubMed

Ziegler, Tom; Krykunov, Mykhaylo

2010-08-21

It is well known that time-dependent density functional theory (TD-DFT) based on standard gradient corrected functionals affords both a quantitative and qualitative incorrect picture of charge transfer transitions between two spatially separated regions. It is shown here that the well known failure can be traced back to the use of linear response theory. Further, it is demonstrated that the inclusion of higher order terms readily affords a qualitatively correct picture even for simple functionals based on the local density approximation. The inclusion of these terms is done within the framework of a newly developed variational approach to excitation energies called constrained variational density functional theory (CV-DFT). To second order [CV(2)-DFT] this theory is identical to adiabatic TD-DFT within the Tamm-Dancoff approximation. With inclusion of fourth order corrections [CV(4)-DFT] it affords a qualitative correct description of charge transfer transitions. It is finally demonstrated that the relaxation of the ground state Kohn-Sham orbitals to first order in response to the change in density on excitation together with CV(4)-DFT affords charge transfer excitations in good agreement with experiment. The new relaxed theory is termed R-CV(4)-DFT. The relaxed scheme represents an effective way in which to introduce double replacements into the description of single electron excitations, something that would otherwise require a frequency dependent kernel.

Tidal tomography constrains Earth's deep-mantle buoyancy.

PubMed

Lau, Harriet C P; Mitrovica, Jerry X; Davis, James L; Tromp, Jeroen; Yang, Hsin-Ying; Al-Attar, David

2017-11-15

Earth's body tide-also known as the solid Earth tide, the displacement of the solid Earth's surface caused by gravitational forces from the Moon and the Sun-is sensitive to the density of the two Large Low Shear Velocity Provinces (LLSVPs) beneath Africa and the Pacific. These massive regions extend approximately 1,000 kilometres upward from the base of the mantle and their buoyancy remains actively debated within the geophysical community. Here we use tidal tomography to constrain Earth's deep-mantle buoyancy derived from Global Positioning System (GPS)-based measurements of semi-diurnal body tide deformation. Using a probabilistic approach, we show that across the bottom two-thirds of the two LLSVPs the mean density is about 0.5 per cent higher than the average mantle density across this depth range (that is, its mean buoyancy is minus 0.5 per cent), although this anomaly may be concentrated towards the very base of the mantle. We conclude that the buoyancy of these structures is dominated by the enrichment of high-density chemical components, probably related to subducted oceanic plates or primordial material associated with Earth's formation. Because the dynamics of the mantle is driven by density variations, our result has important dynamical implications for the stability of the LLSVPs and the long-term evolution of the Earth system.

Bi2S3microspheres grown on graphene sheets as low-cost counter-electrode materials for dye-sensitized solar cells

NASA Astrophysics Data System (ADS)

Li, Guang; Chen, Xiaoshuang; Gao, Guandao

2014-02-01

In this work, we synthesized 3D Bi2S3 microspheres comprised of nanorods grown along the (211) facet on graphene sheets by a solvothermal route, and investigated its catalytic activities through I-V curves and conversion efficiency tests as the CE in DSSCs. Although the (211) facet has a large band gap for a Bi2S3 semiconductor, owing to the introduction of graphene into the system, its short-circuit current density, open-circuit voltage, fill factor, and efficiency were Jsc = 12.2 mA cm-2, Voc = 0.75 V, FF = 0.60, and η = 5.5%, respectively. By integrating it with graphene sheets, our material achieved the conversion efficiency of 5.5%, which is almost triple the best conversion efficiency value of the DSSCs with (211)-faceted 3D Bi2S3 without graphene (1.9%) reported in the latest literature. Since this conversion-efficient 3D material grown on the graphene sheets significantly improves its catalytic properties, it paves the way for designing and applying low-cost Pt-free CE materials in DSSC from inorganic nanostructures.In this work, we synthesized 3D Bi2S3 microspheres comprised of nanorods grown along the (211) facet on graphene sheets by a solvothermal route, and investigated its catalytic activities through I-V curves and conversion efficiency tests as the CE in DSSCs. Although the (211) facet has a large band gap for a Bi2S3 semiconductor, owing to the introduction of graphene into the system, its short-circuit current density, open-circuit voltage, fill factor, and efficiency were Jsc = 12.2 mA cm-2, Voc = 0.75 V, FF = 0.60, and η = 5.5%, respectively. By integrating it with graphene sheets, our material achieved the conversion efficiency of 5.5%, which is almost triple the best conversion efficiency value of the DSSCs with (211)-faceted 3D Bi2S3 without graphene (1.9%) reported in the latest literature. Since this conversion-efficient 3D material grown on the graphene sheets significantly improves its catalytic properties, it paves the way for designing and applying low-cost Pt-free CE materials in DSSC from inorganic nanostructures. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr06093d

Estimating Antarctica land topography from GRACE gravity and ICESat altimetry data

NASA Astrophysics Data System (ADS)

Wu, I.; Chao, B. F.; Chen, Y.

2009-12-01

We propose a new method combining GRACE (Gravity Recovery and Climate Experiment) gravity and ICESat (Ice, Cloud, and land Elevation Satellite) altimetry data to estimate the land topography for Antarctica. Antarctica is the fifth-largest continent in the world and about 98% of Antarctica is covered by ice, where in-situ measurements are difficult. Some experimental airborne radar and ground-based radar data have revealed very limited land topography beneath heavy ice sheet. To estimate the land topography for the full coverage of Antarctica, we combine GRACE data that indicate the mass distribution, with data of ICESat laser altimetry that provide high-resolution mapping of ice topography. Our approach is actually based on some geological constraints: assuming uniform densities of the land and ice considering the Airy-type isostasy. In the beginning we construct an initial model for the ice thickness and land topography based on the BEDMAP ice thickness and ICESat data. Thereafter we forward compute the model’s gravity field and compare with the GRACE observed data. Our initial model undergoes the adjustments to improve the fit between modeled results and the observed data. Final examination is done by comparing our results with previous but sparse observations of ice thickness to reconfirm the reliability of our results. As the gravitational inversion problem is non-unique, our estimating result is just one of all possibilities constrained by available data in optimal way.

Self-enhanced catalytic activities of functionalized graphene sheets in the combustion of nitromethane: molecular dynamic simulations by molecular reactive force field.

PubMed

Zhang, Chaoyang; Wen, Yushi; Xue, Xianggui

2014-08-13

Functionalized graphene sheet (FGS) is a promising additive that enhances fuel/propellant combustion, and the determination of its mechanism has attracted much interest. In the present study, a series of molecular dynamic simulations based on a reactive force field (ReaxFF) are performed to explore the catalytic activity (CA) of FGS in the thermal decay of nitromethane (NM, CH3NO2). FGSs and pristine graphene sheets (GSs) are oxidized in hot NM liquid to increase their functionalities and subsequently show self-enhanced CAs during the decay. The CAs result from the interatomic exchanges between the functional groups on the sheets and the NM liquid, i.e., mainly between H and O atoms. CA is dependent on the density of NM, functionalities of sheets, and temperature. The GSs and FGSs that originally exhibit different functionalities tend to possess similar functionalities and consequently similar CAs as temperature increases. Other carbon materials and their oxides can accelerate combustion of other fuels/propellants similar to NM, provided that they can be dispersed and their key reaction steps in combustion are similar to NM.

Silicene-terminated surface of calcium and strontium disilicides: properties and comparison with bulk structures by computational methods

NASA Astrophysics Data System (ADS)

Brázda, Petr; Mutombo, Pingo; Ondráček, Martin; Corrêa, Cinthia Antunes; Kopeček, Jaromír; Palatinus, Lukáš

2018-05-01

The bulk and surface structures of calcium and strontium disilicides are investigated by computational methods using density functional theory. The investigated structures are R6, R3 and P1-CaSi2 and P1-SrSi2. The investigated properties are the cleavage energy at the silicene sheet, buckling of the bulk and surface silicene layers, charge transfer from calcium to silicon, band structure of bulk and surface-terminated structures and adsorption energies on H atoms and H2 molecules on the silicene-terminated surface of the R3 phase. The cleavage energy at the silicene surface is low in all cases. Structures P1-CaSi2 and R3-CaSi2 contain silicene sheets with different coordination to Ca, while R6-CaSi2 contains both types of the sheets. It is shown that the properties of the two types of silicene-like sheets in R6-CaSi2 are similar to those of the corresponding sheets in P1-CaSi2 and R3-CaSi2, and the thermodynamically stable R6 phase is a good candidate for experimental investigation of silicene-terminated surface in calcium disilicide.

Separable fastening device

DOEpatents

Harvey, Andrew C.; Ribich, William A.; Marinaccio, Paul J.; Sawaf, Bernard E.

1987-12-01

A separable fastener system has a first separable member that includes a series of metal hook sheets disposed in stacked relation that defines an array of hook elements on its broad surface. Each hook sheet is a planar metal member of uniform thickness and has a body portion with a series of hook elements formed along one edge of the body. Each hook element includes a stem portion, a deflecting surface portion, and a latch portion. Metal spacer sheets are disposed between the hook sheets and may be varied in thickness and in number to control the density of the hook elements on the broad surface of the first fastener member. The hook and spacer sheets are secured together in stacked relation. A second fastener member has a surface of complementary engaging elements extending along its broad surface which are releasably interengageable with the hook elements of the first fastener member, the deflecting surfaces of the hook elements of the first fastener member tending to deflect hook engaging portions of the second fastener member and the latch portions of the hook elements of the first fastener member engaging portions of the second fastener member in fastening relation.

Construction of osteochondral-like tissue graft combining β-tricalcium phosphate block and scaffold-free centrifuged chondrocyte cell sheet.

PubMed

Niyama, Kouhei; Ide, Naoto; Onoue, Kaori; Okabe, Takahiro; Wakitani, Shigeyuki; Takagi, Mutsumi

2011-09-01

The combination of a β-tricalcium phosphate (βTCP) block with a scaffold-free chondrocyte sheet formed by the centrifugation of chondrocytes in a well was investigated with the aim of constructing an osteochondral-like structure. Human and porcine articular cartilage chondrocytes were respectively centrifuged in a 96-well plate or cell culture insert (0.32 cm(2)) that was set in a 24-well plate, cultivated in the respective vessel for 3 weeks, and the cell sheets were harvested. In some cases, a cylindrical βTCP block (diameter 5 mm, height 3 mm) was placed on the sheet on days 1-7. The sheet size, cell number, and sulfated glycosaminoglycan accumulation were determined. The use of a 96-well plate for not suspension but adhesion culture and the initial centrifugation of a well containing cells were crucial to obtaining a uniformly thick cell sheet. The glycosaminoglycan density of the harvested cell sheet was comparable to that of the pellet culture. An inoculum cell number of more than 31 × 10(5) cells tended to result in a curved cell sheet. Culture involving 18.6 × 10(5) cells and the 96-well plate for adhesion culture showed no curving of the cell sheet (thickness of 0.85 mm), and these were found to be the best of the culture conditions tested. The timing of the addition of a βTCP block to the cell sheet (1-7 days) markedly affected the balance between the thickness of cell sheet parts on and in the βTCP block. Centrifugation and subsequent cultivation of chondrocytes (18.6 × 10(5) cells) in a 96-well plate for adhesion culture led to the production of a scaffold-free cartilage-like cell sheet with a thickness of 0.85 mm. A combined osteochondral-like structure was produced by putting a βTCP block on the cell sheet. The thickness of the cell sheet on the βTCP block and the binding strength between the cell sheet and the βTCP block could be optimized by adjusting the inoculum cell number and timing of βTCP block addition.

Liquid phase exfoliated graphene for electronic applications

NASA Astrophysics Data System (ADS)

Sukumaran, Sheena S.; Jinesh, K. B.; Gopchandran, K. G.

2017-09-01

Graphene dispersions were prepared using the liquid phase exfoliation method with three different surfactants. One surfactant was used from each of the surfactant types, anionic, cationic, and non-ionic; those used, were sodium dodecylbenzene sulfonate (SDBS), cetyltrimethylammonium bromide (CTAB) and polyvinylpyrrolidone (PVP), respectively. Raman spectroscopy was used to investigate the number of layers and the nature of any defects present in the exfoliated graphene. The yield of graphene was found to be less with the non-ionic surfactant, PVP. The deconvolution of 2D peaks at ~2700 cm-1 indicated that graphene prepared using these surfactants resulted in sheets consisting of few-layer graphene. The ratio of intensity of the D and G bands in the Raman spectra showed that edge defect density is high for samples prepared with SDBS compared to the other two, and is attributed to the smaller size of the graphene sheets, as shown in the electron micrographs. In the case of the dispersion in PVP, it is found that the sizes of the graphene sheets are highly sensitive to the concentration of the surfactant used. Here, we have made an attempt to investigate the local density of states in the graphene sheets by measuring the tunnelling current-voltage characteristics. Graphene layers have shown consistent p-type behaviour when exfoliated with SDBS and n-type behaviour when exfoliated with CTAB, with a larger band gap for graphene exfoliated using CTAB. Hence, in addition to the known advantages of liquid phase exfoliation, we found that by selecting suitable surfactants, to a certain extent it is possible to tune the band gap and determine the type of majority carriers.

Oscillations Excited by Plasmoids Formed During Magnetic Reconnection in a Vertical Gravitationally Stratified Current Sheet

NASA Astrophysics Data System (ADS)

Jelínek, P.; Karlický, M.; Van Doorsselaere, T.; Bárta, M.

2017-10-01

Using the FLASH code, which solves the full set of the 2D non-ideal (resistive) time-dependent magnetohydrodynamic (MHD) equations, we study processes during the magnetic reconnection in a vertical gravitationally stratified current sheet. We show that during these processes, which correspond to processes in solar flares, plasmoids are formed due to the tearing mode instability of the current sheet. These plasmoids move upward or downward along the vertical current sheet and some of them merge into larger plasmoids. We study the density and temperature structure of these plasmoids and their time evolution in detail. We found that during the merging of two plasmoids, the resulting larger plasmoid starts to oscillate with a period largely determined by L/{c}{{A}}, where L is the size of the plasmoid and c A is the Alfvén speed in the lateral parts of the plasmoid. In our model, L/{c}{{A}} evaluates to ˜ 25 {{s}}. Furthermore, the plasmoid moving downward merges with the underlying flare arcade, which causes oscillations of the arcade. In our model, the period of this arcade oscillation is ˜ 35 {{s}}, which also corresponds to L/{c}{{A}}, but here L means the length of the loop and c A is the average Alfvén speed in the loop. We also show that the merging process of the plasmoid with the flare arcade is a complex process as presented by complex density and temperature structures of the oscillating arcade. Moreover, all these processes are associated with magnetoacoustic waves produced by the motion and merging of plasmoids.

Density diagnostics of ionized outflows in active galacitc nuclei

NASA Astrophysics Data System (ADS)

Mao, J.; Kaastra, J.; Mehdipour, M.; Raassen, T.; Gu, L.

2017-10-01

Ionized outflows in Active Galactic Nuclei are thought to influence their nuclear and local galactic environment. However, the distance of outflows with respect to the central engine is poorly constrained, which limits our understanding of the kinetic power by the outflows. Therefore, the impact of AGN outflows on their host galaxies is uncertain. Given the density of the outflows, their distance can be immediately obtained by the definition of the ionization parameter. Here we carry out a theoretical study of density diagnostics of AGN outflows using absorption lines from metastable levels in Be-like to F-like ions. With the new self-consistent photoionization model (PION) in the SPEX code, we are able to calculate ground and metastable level populations. This enable us to determine under what physical conditions these levels are significantly populated. We then identify characteristic transitions from these metastable levels in the X-ray band. Firm detections of absorption lines from such metastable levels are challenging for current grating instruments. The next generation of spectrometers like X-IFU onboard Athena will certainly identify the presence/absence of these density- sensitive absorption lines, thus tightly constraining the location and the kinetic power of AGN outflows.

Equations of state and anisotropy of Fe-Ni-Si alloys

NASA Astrophysics Data System (ADS)

Morrison, R. A.; Jackson, J. M.; Sturhahn, W.; Zhang, D.; Greenberg, E.

2017-12-01

Seismic observations provide constraints on the density, bulk sound speed, and bulk modulus of Earth's inner core, and x-ray diffraction (XRD) experiments can experimentally constrain such properties of iron alloys. The deviation of these seismically-inferred values from the properties of iron suggests the presence of light elements (e.g. Si, O, S, C, H) inside the core. While cosmochemical studies suggest Earth's core is composed primarily of iron alloyed with 5 wt% nickel, existing experimental XRD studies constraining pressure-density relations have predominantly focused on iron and iron alloyed with light elements, while neglecting the effect of nickel. In this study, we present high-precision equations of state for bcc- and hcp-structured Fe0.91Ni0.09 and Fe0.80Ni0.10Si0.10 using powder XRD at room temperature up to 167 GPa and 175 GPa, respectively. By using tungsten powder as a pressure calibrant and helium as a pressure transmitting medium, we minimize error due to pressure calibration and non-hydrostatic stresses. The results are high fidelity equations of state (EOS). By systematically comparing our findings to an established EOS of hcp-Fe [Dewaele et al. 2006], we constrain the effect of nickel and silicon on the density, bulk sound speed, and bulk modulus of iron alloys, which is a critical step towards constraining the inner core's composition. We find that for iron alloys, high quality ambient temperature EOSs can dramatically improve the extrapolated high temperature equations of state to inner core conditions. By combining seismic observations and their associated uncertainties with our data and existing Fe light-element-alloy EOSs, we estimate their densities, bulk moduli, and bulk sound speeds at inner core conditions and propose an experimentally and seismologically consistent range of inner core compositions. Additionally, we obtain an unprecedented constraint on the effect of nickel and silicon on the axial ratio of iron alloys. Nickel has a measurably distinct effect on the c/a axial ratio of iron, as does alloying iron-nickel with silicon. We investigate the relationship between the c/a axial ratio and elastic anisotropy of iron alloys and discuss the implications for inner core seismic anisotropy.

A New Family of Solvable Pearson-Dirichlet Random Walks

NASA Astrophysics Data System (ADS)

Le Caër, Gérard

2011-07-01

An n-step Pearson-Gamma random walk in ℝ d starts at the origin and consists of n independent steps with gamma distributed lengths and uniform orientations. The gamma distribution of each step length has a shape parameter q>0. Constrained random walks of n steps in ℝ d are obtained from the latter walks by imposing that the sum of the step lengths is equal to a fixed value. Simple closed-form expressions were obtained in particular for the distribution of the endpoint of such constrained walks for any d≥ d 0 and any n≥2 when q is either q = d/2 - 1 ( d 0=3) or q= d-1 ( d 0=2) (Le Caër in J. Stat. Phys. 140:728-751, 2010). When the total walk length is chosen, without loss of generality, to be equal to 1, then the constrained step lengths have a Dirichlet distribution whose parameters are all equal to q and the associated walk is thus named a Pearson-Dirichlet random walk. The density of the endpoint position of a n-step planar walk of this type ( n≥2), with q= d=2, was shown recently to be a weighted mixture of 1+ floor( n/2) endpoint densities of planar Pearson-Dirichlet walks with q=1 (Beghin and Orsingher in Stochastics 82:201-229, 2010). The previous result is generalized to any walk space dimension and any number of steps n≥2 when the parameter of the Pearson-Dirichlet random walk is q= d>1. We rely on the connection between an unconstrained random walk and a constrained one, which have both the same n and the same q= d, to obtain a closed-form expression of the endpoint density. The latter is a weighted mixture of 1+ floor( n/2) densities with simple forms, equivalently expressed as a product of a power and a Gauss hypergeometric function. The weights are products of factors which depends both on d and n and Bessel numbers independent of d.

The 7 × 1 Fermi Surface Reconstruction in a Two-dimensional f -electron Charge Density Wave System: PrTe 3

DOE PAGES

Lee, Eunsook; Kim, D. H.; Kim, Hyun Woo; ...

2016-07-25

The electronic structure of a charge density wave (CDW) system PrTe 3 and its modulated structure in the CDW phase have been investigated by employing ARPES, XAS, Pr 4 f RPES, and first-principles band structure calculation. Pr ions are found to be nearly trivalent, supporting the CDW instability in the metallic Te sheets through partial filling. Finite Pr 4 f spectral weight is observed near the Fermi level, suggesting the non-negligible Pr 4 f contribution to the CDW formation through the Pr 4 f -Te 5p hybridization. The two-fold symmetric features in the measured Fermi surface (FS) of PrTe 3more » are explained by the calculated FS for the assumed 7 × 1 CDW supercell formation in Te sheets. The shadow bands and the corresponding very weak FSs are observed, which originate from both the band folding due to the 3D interaction of Te sheets with neighboring Pr-Te layers and that due to the CDW-induced FS reconstruction. The straight vertical FSs are observed along k z, demonstrating the nearly 2D character for the near-EF states. The observed linear dichroism reveals the in-plane orbital character of the near-E F Te 5p states.« less

Strongly Coupled Molybdenum Carbide on Carbon Sheets as a Bifunctional Electrocatalyst for Overall Water Splitting.

PubMed

Wang, Hao; Cao, Yingjie; Sun, Cheng; Zou, Guifu; Huang, Jianwen; Kuai, Xiaoxiao; Zhao, Jianqing; Gao, Lijun

2017-09-22

High-performance and affordable electrocatalysts from earth-abundant elements are desirably pursued for water splitting involving hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Here, a bifunctional electrocatalyst of highly crystalline Mo 2 C nanoparticles supported on carbon sheets (Mo 2 C/CS) was designed toward overall water splitting. Owing to the highly active catalytic nature of Mo 2 C nanoparticles, the high surface area of carbon sheets and efficient charge transfer in the strongly coupled composite, the designed catalysts show excellent bifunctional behavior with an onset potential of -60 mV for HER and an overpotential of 320 mV to achieve a current density of 10 mA cm -2 for OER in 1 m KOH while maintaining robust stability. Moreover, the electrolysis cell using the catalyst only requires a low cell voltage of 1.73 V to achieve a current density of 10 mA cm -2 and maintains the activity for more than 100 h when employing the Mo 2 C/CS catalyst as both anode and cathode electrodes. Such high performance makes Mo 2 C/CS a promising electrocatalyst for practical hydrogen production from water splitting. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Lithium doping and vacancy effects on the structural, electronic and magnetic properties of hexagonal boron nitride sheet: A first-principles calculation

NASA Astrophysics Data System (ADS)

Fartab, Dorsa S.; Kordbacheh, Amirhossein Ahmadkhan

2018-06-01

The first-principles calculations based on spin-polarized density functional theory is carried out to investigate the structural, electronic and magnetic properties of a hexagonal boron nitride sheet (h-BNS) doped by one or two lithium atom(s). Moreover, a vacancy in the neighborhood of one Li-substituted atom is introduced into the system. All optimized structures indicate significant local deformations with Li atom(s) protruded to the exterior of the sheet. The defects considered at N site are energetically more favorable than their counterpart structures at B site. The spin-polarized impurity states appear within the bandgap region of the pristine h-BNS, which lead to a spontaneous magnetization with the largest magnetic moments of about 2 μB in where a single or two B atom(s) are replaced by Li atom(s). Furthermore, the Li substitution for a single B atom increases the density of holes compared to that of electrons forming a p-type semiconductor. More interestingly, the structure in which two Li are substituted two neighboring B atoms appears to show desired half-metallic behavior that may be applicable in spintronic. The results provide a way to enhance the conductivity and magnetism of the pristine h-BNS for potential applications in BN-based nanoscale devices.