Effect of air-flow on biodrying method of municipal solid waste in Indonesia

NASA Astrophysics Data System (ADS)

Kristanto, Gabriel Andari; Hanany, Ismi

2017-11-01

The process of bio-drying could be an interesting solution for municipal solid waste management and energy demand in Indonesia. By using the heat from bio-degradation process consists in bio-drying, moisture content in a solid waste can be reduced. Solid wastes with a low moisture content, could be used as a fuel with a good energy content. In this study, 85% of garden wastes and 15% of food waste from Indonesia's municipal solid waste were bio-dried in aerobic condition using 3 variations of air flow-rates, which were 8 L/min.kg; 10 L/min.kg; and 12 L/min.kg. The experiment performs with three different reactors with known volume 75cm × 50cm × 40cm and using Styrofoam as an insulation. The process of bio-drying lasted 21 days. In the end, the experiment with 10 L/min.kg aeration, has the lowest moisture contents about 23% with high temperature and NHV about 3595.29 kcal/kg.

Effect of shrinkage on isothermal drying behavior of 2-phase olive mill waste

USDA-ARS?s Scientific Manuscript database

The objective of this study was to determine the drying behavior of 2-phase olive mill waste (2POMW) under isothermal microwave-convection drying conditions. 2POMW samples were dried in a thin layer in a variable-power pilot microwave oven with impinging air, using a feedback controller to maintain...

Evaluating the biogas potential of the dry fraction from pretreatment of food waste from households

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murto, Marika, E-mail: marika.murto@biotek.lu.se; Björnsson, Lovisa, E-mail: lovisa.bjornsson@miljo.lth.se; Environmental and Energy Systems Studies, Lund University, P.O. Box 118, SE-221 00 Lund

2013-05-15

Highlights: ► A novel approach for biogas production from a waste fraction that today is incinerated. ► Biogas production is possible in spite of the impurities of the waste. ► Tracer studies are applied in a novel way. ► Structural material is needed to improve the flow pattern of the waste. ► We provide a solution to biological treatment for the complex waste fraction. - Abstract: At the waste handling company NSR, Helsingborg, Sweden, the food waste fraction of source separated municipal solid waste is pretreated to obtain a liquid fraction, which is used for biogas production, and a drymore » fraction, which is at present incinerated. This pretreatment and separation is performed to remove impurities, however also some of the organic material is removed. The possibility of realising the methane potential of the dry fraction through batch-wise dry anaerobic digestion was investigated. The anaerobic digestion technique used was a two-stage process consisting of a static leach bed reactor and a methane reactor. Treatment of the dry fraction alone and in a mixture with structural material was tested to investigate the effect on the porosity of the leach bed. A tracer experiment was carried out to investigate the liquid flow through the leach beds, and this method proved useful in demonstrating a more homogenous flow through the leach bed when structural material was added. Addition of structural material to the dry fraction was needed to achieve a functional digestion process. A methane yield of 98 m{sup 3}/ton was obtained from the dry fraction mixed with structural material after 76 days of digestion. This was in the same range as obtained in the laboratory scale biochemical methane potential test, showing that it was possible to extract the organic content in the dry fraction in this type of dry digestion system for the production of methane.« less

40 CFR 60.53a - Standard for municipal waste combustor organics.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Municipal Waste Combustors for Which Construction is Commenced After December 20, 1989 and on or Before... exceed 30 nanograms per dry standard cubic meter (12 grains per billion dry standard cubic feet), corrected to 7 percent oxygen (dry basis). ...

Enhanced production of raw starch degrading enzyme using agro-industrial waste mixtures by thermotolerant Rhizopus microsporus for raw cassava chip saccharification in ethanol production.

PubMed

Trakarnpaiboon, Srisakul; Srisuk, Nantana; Piyachomkwan, Kuakoon; Sakai, Kenji; Kitpreechavanich, Vichien

2017-09-14

In the present study, solid-state fermentation for the production of raw starch degrading enzyme was investigated by thermotolerant Rhizopus microsporus TISTR 3531 using a combination of agro-industrial wastes as substrates. The obtained crude enzyme was applied for hydrolysis of raw cassava starch and chips at low temperature and subjected to nonsterile ethanol production using raw cassava chips. The agro-industrial waste ratio was optimized using a simplex axial mixture design. The results showed that the substrate mixture consisting of rice bran:corncob:cassava bagasse at 8 g:10 g:2 g yielded the highest enzyme production of 201.6 U/g dry solid. The optimized condition for solid-state fermentation was found as 65% initial moisture content, 35°C, initial pH of 6.0, and 5 × 10 6 spores/mL inoculum, which gave the highest enzyme activity of 389.5 U/g dry solid. The enzyme showed high efficiency on saccharification of raw cassava starch and chips with synergistic activities of commercial α-amylase at 50°C, which promotes low-temperature bioethanol production. A high ethanol concentration of 102.2 g/L with 78% fermentation efficiency was achieved from modified simultaneous saccharification and fermentation using cofermentation of the enzymatic hydrolysate of 300 g raw cassava chips/L with cane molasses.

Monitoring and Inventory of Hazardous Pollutants Emissions from Solid Waste Open Burning

NASA Astrophysics Data System (ADS)

KIM Oanh, N. T.

2017-12-01

Open burning remains a way to dispose of solid waste in developing countries, commonly practiced in places where municipal solid waste (MSW) management is not sufficiently efficient. This open burning practice emits huge amounts of toxic air pollutants, including semi-VOC of dioxins (PCDD/F) and polycyclic aromatic hydrocarbons (PAHs), particulate matters (PM), and toxic gases. This study measured toxic substances released from simulated open burning experiments of MSW (5 batches) and plastic waste (3 batches) to determine emission factors (EFs). Carbon content of the waste before and after burning was measured and the EFs were calculated using the carbon balance method. The obtained EFs of CO; CO2; NO2 and SO2 were 102±61; 1,684±96; 0.69±0.54; and 1.44±1.18 g/kg of dry MSW. The corresponding values for plastic waste were 13.0±6.0; 1,824±10; 0.12±0.07; and 0.14±0.09 g/kg, respectively. The EF of coarse PM (PM10-2.5); PM2.5 and BC in PM2.5 were, respectively, 6.1±5.6; 6.4±5.1 and 1.1±0.7 g/kg of MSW, and 2.3±0.1; 2.5±0.3; and 0.2±0.2 g/kg of plastic waste. The EFs of 17 dioxins and 16 PAHs were respectively 1,050±500 ng-TEQ dioxins (70% in gas phase) and 117± 21 mg PAHs (92% in gas phase) per kg of MSW, while those for plastic waste were 8.6 ng TEQ dioxins (36% in gas phase) and 85.2±0.06 mg PAHs (99% in gas phase). Using the activity data from own surveys and literature, we estimated the annual emissions from solid waste open burning in Southeast Asia for 2015. Higher emissions in the domain were seen during the dry months and over large urban areas. The large amounts of toxic pollutants emitted from this open burning activity call for actions to stop this practice which in turn requires integrated environmental management approach simultaneously considering both solid waste and air pollution.

Study on the correlation between volatile fatty acids and gas production in dry fermentation of kitchen waste

NASA Astrophysics Data System (ADS)

Li, Qiangqiang; Ma, Yunfeng; Du, Boying; Wang, Qi; Hu, Qiongqiong; Bian, Yushan

2018-02-01

In this study, continuous kitchen waste fermentation and anaerobic digestion experiments were conducted to analyze the gas production potential, and to study the correlation between gas production rate and volatile fatty acid (VFAs) and its component concentration. During the experiment, the total solid(TS) concentration of the reaction system was increased by adding the kitchen waste, analysis of kitchen waste dry fermentation process to start, run, imbalance and imbalance after recovery and the parameters in the process of realizing the change trend and influencing factors of dry fermentation process, pH and ammonia concentration.

Experimental research of solid waste drying in the process of thermal processing

NASA Astrophysics Data System (ADS)

Bukhmirov, V. V.; Kolibaba, O. B.; Gabitov, R. N.

2015-10-01

The convective drying process of municipal solid waste layer as a polydispersed multicomponent porous structure is studied. On the base of the experimental data criterial equations for calculating heat transfer and mass transfer processes in the layer, depending on the humidity of the material, the speed of the drying agent and the layer height are obtained. These solutions are used in the thermal design of reactors for the thermal processing of multicomponent organic waste.

75 FR 43409 - Rhode Island: Final Authorization of State Hazardous Waste Management Program Revisions

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-26

..., nickel-cadmium batteries or lithium batteries. Rhode Island has decided to regulate circuit boards, as... universal waste program, Rhode Island regulates certain dry cell batteries (i.e., waste-nickel cadmium, mercuric oxide, and lead acid dry cell batteries), used electronics, mercury containing equipment and...

Energy-saving drying and its application

NASA Astrophysics Data System (ADS)

Kovbasyuk, V. I.

2015-09-01

Superheated steam is efficiently applied as a coolant for the intensification of drying, which is an important component of many up-to-date technologies. However, traditional drying is extremely energy consuming, and many drying apparatus are environmentally unfriendly. Thus, it is important to implement the proposed drying technique using superheated steam under pressure significantly higher than the atmospheric one with subsequent steam transfer for use in a turbine for electric power generation as a compensation of energy costs for drying. This paper includes a brief thermodynamic analysis of such a technique, its environmental advantages, and possible benefits of the use of wet wastes and obtaining high-quality fuels from wet raw materials. A scheme is developed for the turbine protection from impurities that can occur in the steam at drying. Potential advantage of the technique are also the absence of heating surfaces that are in contact with wet media, the absence of the emissions to the atmosphere, and the use of low potential heat for desalination and the purification of water. The new drying technique can play an extremely important part in the implementation in the field of thermal destruction of anthropogenic wastes. In spite of the promotion of waste sorting to obtain valuable secondary raw materials, the main problem of big cities is nonutilizable waste, which makes not less than 85% of the starting quantity of waste. This can only be totally solved by combustion, which even more relates to the sewage sludge utilization. The wastes can be safely and efficiently combusted only provided that they are free of moisture. Combustion temperature optimization makes possible full destruction of dioxins and their toxic analogues.

Sustainable multistage process for enhanced productivity of bioplastics from waste remediation through aerobic dynamic feeding strategy: Process integration for up-scaling.

PubMed

Amulya, K; Jukuri, Srinivas; Venkata Mohan, S

2015-01-01

Polyhydroxyalkanoates (PHA) production was evaluated in a multistage operation using food waste as a renewable feedstock. The first step involved the production of bio-hydrogen (bio-H2) via acidogenic fermentation. Volatile fatty acid (VFA) rich effluent from bio-H2 reactor was subsequently used for PHA production, which was carried out in two stages, Stage II (culture enrichment) and Stage III (PHA production). PHA-storing microorganisms were enriched in a sequencing batch reactor (SBR), operated at two different cycle lengths (CL-24; CL-12). Higher polymer recovery as well as VFA removal was achieved in CL-12 operation both in Stage II (16.3% dry cell weight (DCW); VFA removal, 84%) and Stage III (23.7% DCW; VFA removal, 88%). The PHA obtained was a co-polymer [P(3HB-co-3HV)] of PHB and PHV. The results obtained indicate that this integrated multistage process offers new opportunities to further leverage large scale PHA production with simultaneous waste remediation in the framework of biorefinery. Copyright © 2015 Elsevier Ltd. All rights reserved.

Helically agitated mixing in dry dilute acid pretreatment enhances the bioconversion of corn stover into ethanol

PubMed Central

2014-01-01

Background Dry dilute acid pretreatment at extremely high solids loading of lignocellulose materials demonstrated promising advantages of no waste water generation, less sugar loss, and low steam consumption while maintaining high hydrolysis yield. However, the routine pretreatment reactor without mixing apparatus was found not suitable for dry pretreatment operation because of poor mixing and mass transfer. In this study, helically agitated mixing was introduced into the dry dilute acid pretreatment of corn stover and its effect on pretreatment efficiency, inhibitor generation, sugar production, and bioconversion efficiency through simultaneous saccharification and ethanol fermentation (SSF) were evaluated. Results The overall cellulose conversion taking account of cellulose loss in pretreatment was used to evaluate the efficiency of pretreatment. The two-phase computational fluid dynamics (CFD) model on dry pretreatment was established and applied to analyze the mixing mechanism. The results showed that the pretreatment efficiency was significantly improved and the inhibitor generation was reduced by the helically agitated mixing, compared to the dry pretreatment without mixing: the ethanol titer and yield from cellulose in the SSF reached 56.20 g/L and 69.43% at the 30% solids loading and 15 FPU/DM cellulase dosage, respectively, corresponding to a 26.5% increase in ethanol titer and 17.2% increase in ethanol yield at the same fermentation conditions. Conclusions The advantage of helically agitated mixing may provide a prototype of dry dilute acid pretreatment processing for future commercial-scale production of cellulosic ethanol. PMID:24387051

Experimental evaluation of drying characteristics of sewage sludge and hazelnut shell mixtures

NASA Astrophysics Data System (ADS)

Pehlivan, Hüseyin; Ateş, Asude; Özdemir, Mustafa

2016-11-01

In this study the drying behavior of organic and agricultural waste mixtures has been experimentally investigated. The usability of sewage sludge as an organic waste and hazelnut shell as an agricultural waste was assessed in different mixture range. The paper discusses the applicability of these mixtures as a recovery energy source. Moisture content of mixtures has been calculated in laboratory and plant conditions. Indoor and outdoor solar sludge drying plants were constructed in pilot scale for experimental purposes. Dry solids and climatic conditions were constantly measured. A total more than 140 samples including for drying has been carried out to build up results. Indoor and outdoor weather conditions are taken into consideration in winter and summer. The most effective drying capacity is obtained in mixture of 20 % hazelnut shell and 80 % sewage sludge.

A sustainable biorefinery to convert agricultural residues into value-added chemicals.

PubMed

Liu, Zhiguo; Liao, Wei; Liu, Yan

2016-01-01

Animal wastes are of particular environmental concern due to greenhouse gases emissions, odor problem, and potential water contamination. Anaerobic digestion (AD) is an effective and widely used technology to treat them for bioenergy production. However, the sustainability of AD is compromised by two by-products of the nutrient-rich liquid digestate and the fiber-rich solid digestate. To overcome these limitations, this paper demonstrates a biorefinery concept to fully utilize animal wastes and create a new value-added route for animal waste management. The studied biorefinery includes an AD, electrocoagulation (EC) treatment of the liquid digestate, and fungal conversion of the solid fiber into a fine chemical-chitin. Animal wastes were first treated by an AD to produce methane gas for energy generation to power the entire biorefinery. The resulting liquid digestate was treated by EC to reclaim water. Enzymatic hydrolysis and fungal fermentation were then applied on the cellulose-rich solid digestate to produce chitin. EC water was used as the processing water for the fungal fermentation. The results indicate that the studied biorefinery converts 1 kg dry animal wastes into 17 g fungal biomass containing 12 % of chitin (10 % of glucosamine), and generates 1.7 MJ renewable energy and 8.5 kg irrigation water. This study demonstrates an energy positive and freshwater-free biorefinery to simultaneously treat animal wastes and produce a fine chemical-chitin. The sustainable biorefinery concept provides a win-win solution for agricultural waste management and value-added chemical production.

Minimally processed beetroot waste as an alternative source to obtain functional ingredients.

PubMed

Costa, Anne Porto Dalla; Hermes, Vanessa Stahl; Rios, Alessandro de Oliveira; Flôres, Simone Hickmann

2017-06-01

Large amounts of waste are generated by the minimally processed vegetables industry, such as those from beetroot processing. The aim of this study was to determine the best method to obtain flour from minimally processed beetroot waste dried at different temperatures, besides producing a colorant from such waste and assessing its stability along 45 days. Beetroot waste dried at 70 °C originates flour with significant antioxidant activity and higher betalain content than flour produced from waste dried at 60 and 80 °C, while chlorination had no impact on the process since microbiological results were consistent for its application. The colorant obtained from beetroot waste showed color stability for 20 days and potential antioxidant activity over the analysis period, thus it can be used as a functional additive to improve nutritional characteristics and appearance of food products. These results are promising since minimally processed beetroot waste can be used as an alternative source of natural and functional ingredients with high antioxidant activity and betalain content.

Bread enriched in lycopene and other bioactive compounds by addition of dry tomato waste.

PubMed

Nour, Violeta; Ionica, Mira Elena; Trandafir, Ion

2015-12-01

The tomato processing industry generates high amounts of waste, mainly tomato skins and seeds, which create environmental problems. These residues are attractive sources of valuable bioactive components and pigments. A relatively simple recovery technology could consist of production of powders to be directly incorporated into foods. Tomato waste coming from a Romanian tomato processing unit were analyzed for the content of several bioactive compounds like ascorbic acid, β-carotene, lycopene, total phenolics, mineral and trace elements. In addition, its antioxidant capacity was assayed. Results revealed that tomato waste (skins and seeds) could be successfully utilized as functional ingredient for the formulation of antioxidant rich functional foods. Dry tomato processing waste were used to supplement wheat flour at 6 and 10 % levels (w/w flour basis) and the effects on the bread's physicochemical, baking and sensorial characteristics were studied. The following changes were observed: increase in moisture content, titratable acidity and bread crumb elasticity, reduction in specific volume and bread crumb porosity. The addition of dry tomato waste at 6 % resulted in bread with good sensory characteristics and overall acceptability but as the amount of dry tomato waste increased to 10 %, bread was less acceptable.

Torrefaction Processing for Human Solid Waste Management

NASA Technical Reports Server (NTRS)

Serio, Michael A.; Cosgrove, Joseph E.; Wójtowicz, Marek A.; Stapleton, Thomas J.; Nalette, Tim A.; Ewert, Michael K.; Lee, Jeffrey; Fisher, John

2016-01-01

This study involved a torrefaction (mild pyrolysis) processing approach that could be used to sterilize feces and produce a stable, odor-free solid product that can be stored or recycled, and also to simultaneously recover moisture. It was demonstrated that mild heating (200-250 C) in nitrogen or air was adequate for torrefaction of a fecal simulant and an analog of human solid waste (canine feces). The net result was a nearly undetectable odor (for the canine feces), complete recovery of moisture, some additional water production, a modest reduction of the dry solid mass, and the production of small amounts of gas and liquid. The liquid product is mainly water, with a small Total Organic Carbon content. The amount of solid vs gas plus liquid products can be controlled by adjusting the torrefaction conditions (final temperature, holding time), and the current work has shown that the benefits of torrefaction could be achieved in a low temperature range (< 250 C). These temperatures are compatible with the PTFE bag materials historically used by NASA for fecal waste containment and will reduce the energy consumption of the process. The solid product was a dry material that did not support bacterial growth and was hydrophobic relative to the starting material. In the case of canine feces, the solid product was a mechanically friable material that could be easily compacted to a significantly smaller volume (approx. 50%). The proposed Torrefaction Processing Unit (TPU) would be designed to be compatible with the Universal Waste Management System (UWMS), now under development by NASA. A stand-alone TPU could be used to treat the canister from the UWMS, along with other types of wet solid wastes, with either conventional or microwave heating. Over time, a more complete integration of the TPU and the UWMS could be achieved, but will require design changes in both units.

Mechanical-biological waste treatment and the associated occupational hygiene in Finland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tolvanen, Outi K.; Haenninen, Kari I.

2006-07-01

A special feature of waste management in Finland has been the emphasis on the source separation of kitchen biowaste (catering waste); more than two-thirds of the Finnish population participates in this separation. Source-separated biowaste is usually treated by composting. The biowaste of about 5% of the population is handled by mechanical-biological treatment. A waste treatment plant at Mustasaari is the only plant in Finland using digestion for kitchen biowaste. For the protection of their employees, the plant owners commissioned a study on environmental factors and occupational hygiene in the plant area. During 1998-2000 the concentrations of dust, microbes and endotoxinsmore » and noise levels were investigated to identify possible problems at the plant. Three different work areas were investigated: the pre-processing and crushing hall, the bioreactor hall and the drying hall. Employees were asked about work-related health problems. Some problems with occupational hygiene were identified: concentrations of microbes and endotoxins may increase to levels harmful to health during waste crushing and in the bioreactor hall. Because employees complained of symptoms such as dry cough and rash or itching appearing once or twice a month, it is advisable to use respirator masks (class P3) during dusty working phases. The noise level in the drying hall exceeded the Finnish threshold value of 85 dBA. Qualitatively harmful factors for the health of employees are similar in all closed waste treatment plants in Finland. Quantitatively, however, the situation at the Mustasaari treatment plant is better than at some Finnish dry waste treatment plants. Therefore is reasonable to conclude that mechanical sorting, which produces a dry waste fraction for combustion and a biowaste fraction for anaerobic treatment, is in terms of occupational hygiene better for employees than combined aerobic treatment and dry waste treatment.« less

Solid waste characterization in Ketao, a rural town in Togo, West Africa.

PubMed

Edjabou, Maklawe Essonanawe; Møller, Jacob; Christensen, Thomas H

2012-07-01

In Africa the majority of solid waste data is for big cities. Small and rural towns are generally neglected and waste data from these areas are often unavailable, which makes planning a proper solid waste management difficult. This paper presents the results from two waste characterization projects conducted in Kétao, a rural town in Togo during the rainy season and the dry season in 2010. The seasonal variation has a significant impact on the waste stream. The household waste generation rate was estimated at 0.22 kg person(-1) day(-1) in the dry season and 0.42 in the rainy season. Likewise, the waste moisture content was 4% in the dry season while it was 33-63% in the rainy season. The waste consisted mainly of soil and dirt characterized as 'other' (41%), vegetables and putrescibles (38%) and plastic (11%). In addition to these fractions, considerable amounts of material are either recycled or reused locally and do not enter the waste stream. The study suggests that additional recycling is not feasible, but further examination of the degradability of the organic fraction is needed in order to assess whether the residual waste should be composed or landfilled.

Bio-drying and size sorting of municipal solid waste with high water content for improving energy recovery.

PubMed

Shao, Li-Ming; Ma, Zhong-He; Zhang, Hua; Zhang, Dong-Qing; He, Pin-Jing

2010-07-01

Bio-drying can enhance the sortability and heating value of municipal solid waste (MSW), consequently improving energy recovery. Bio-drying followed by size sorting was adopted for MSW with high water content to improve its combustibility and reduce potential environmental pollution during the follow-up incineration. The effects of bio-drying and waste particle size on heating values, acid gas and heavy metal emission potential were investigated. The results show that, the water content of MSW decreased from 73.0% to 48.3% after bio-drying, whereas its lower heating value (LHV) increased by 157%. The heavy metal concentrations increased by around 60% due to the loss of dry materials mainly resulting from biodegradation of food residues. The bio-dried waste fractions with particle size higher than 45 mm were mainly composed of plastics and papers, and were preferable for the production of refuse derived fuel (RDF) in view of higher LHV as well as lower heavy metal concentration and emission. However, due to the higher chlorine content and HCl emission potential, attention should be paid to acid gas and dioxin pollution control. Although LHVs of the waste fractions with size <45 mm increased by around 2x after bio-drying, they were still below the quality standards for RDF and much higher heavy metal pollution potential was observed. Different incineration strategies could be adopted for different particle size fractions of MSW, regarding to their combustibility and pollution property. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

Current-use and organochlorine pesticides and polychlorinated biphenyls in the biodegradable fraction of source separated household waste, compost, and anaerobic digest.

PubMed

Hellström, Anna; Nilsson, Marie-Louise; Kylin, Henrik

2011-01-01

Several current-use (≤ 80 ng g⁻¹ dry weight) and organochlorine pesticides (≤ 15 ng g⁻¹ dry weight) and polychlorinated biphenyls (≤ 18 ng g⁻¹ dry weight) were found in the biodegradable fraction of source separated household waste, compost, and/or anaerobic digestate. The degradation rates of individual compounds differ depending on the treatment. Dieldrin and pentachloroaniline, e.g., degrade more rapidly than the waste is mineralized and accumulates in the products after all treatments. Many organochlorines degrade at the same rate as the waste and have the same concentrations in the waste and products. Chlorpyrifos degrades slower than the waste and accumulates in all products and ethion during anaerobic digestion. The polychlorinated biphenyls and some pesticides show different degradations rates relative the waste during different processes. Understanding the degradation of the contaminants under different conditions is necessary to develop quality criteria for the use of compost and digest.

Influence of effective stress and dry density on the permeability of municipal solid waste.

PubMed

Zhang, Zhenying; Wang, Yingfeng; Xu, Hui; Fang, Yuehua; Wu, Dazhi

2018-05-01

A landfill is one of the main sites for disposal of municipal solid waste and the current landfill disposal system faces several problems. For instance, excessive leachate water is an important factor leading to landfill instability. Understanding the permeability characteristics of municipal solid waste is a relevant topic in the field of environmental geotechnical engineering. In this paper, the current research progress on permeability characteristics of municipal solid waste is discussed. A review of recent studies indicates that the research in this field is divided into two categories based on the experimental method employed: field tests and laboratory tests. This paper summarizes test methods, landfill locations, waste ages, dry densities and permeability coefficients across different studies that focus on permeability characteristics. Additionally, an experimental study on compressibility and permeability characteristics of fresh municipal solid waste under different effective stresses and compression times was carried out. Moreover, the relationships between the permeability coefficient and effective stress as well as dry density were obtained and a permeability prediction model was established. Finally, the experimental results from the existing literature and this paper were compared and the effects of effective stress and dry density on the permeability characteristics of municipal solid waste were summarized. This study provides the basis for analysis of leachate production in a landfill.

Extractable and Non-Extractable Phenolics and Antioxidant Capacity of Mandarin Waste Dried at Different Temperatures.

PubMed

Esparza-Martínez, Francisco J; Miranda-López, Rita; Mata-Sánchez, Sara M; Guzmán-Maldonado, Salvador H

2016-09-01

The mandarin industry is generating more waste due to the increasing demand for juice. In this study, extractable and non-extractable phenolics as well as 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS), ferric reducing ability of plasma (FRAP), and oxygen radical absorbance capacity (ORAC) antioxidant activities in Satsuma mandarin waste dried at different temperatures were determined. The amounts of non-extractable total phenols, total flavonoids, and condensed tannins measured in mandarin waste dried at 120 °C were 39.4, 44.3, and 45.6 %, respectively, which were higher than those of fresh-mandarin waste. Dried mandarin waste is rich in extractable and non-extractable hesperidin (259.86 and 182.52 mg/g, respectively) and eriocitrin (85.12 and 197.24 mg/g, respectively), as well as non-extractable gallic acid (36.08 μg/g). The antioxidant capacities of extractable and non-extractable phenolics, from the highest to the lowest, were ABTS > ORAC > DPPH > FRAP and ORAC > ABTS > DPPH > FRAP, respectively. The information reported here may encourage mandarin industry operators to re-evaluate their by-products, extending the application of mandarin fruits and reducing waste.

Hazardous waste management and weight-based indicators--the case of Haifa Metropolis.

PubMed

Elimelech, E; Ayalon, O; Flicstein, B

2011-01-30

The quantity control of hazardous waste in Israel relies primarily on the Environmental Services Company (ESC) reports. With limited management tools, the Ministry of Environmental Protection (MoEP) has no applicable methodology to confirm or monitor the actual amounts of hazardous waste produced by various industrial sectors. The main goal of this research was to develop a method for estimating the amounts of hazardous waste produced by various sectors. In order to achieve this goal, sector-specific indicators were tested on three hazardous waste producing sectors in the Haifa Metropolis: petroleum refineries, dry cleaners, and public hospitals. The findings reveal poor practice of hazardous waste management in the dry cleaning sector and in the public hospitals sector. Large discrepancies were found in the dry cleaning sector, between the quantities of hazardous waste reported and the corresponding indicator estimates. Furthermore, a lack of documentation on hospitals' pharmaceutical and chemical waste production volume was observed. Only in the case of petroleum refineries, the reported amount was consistent with the estimate. Copyright © 2010 Elsevier B.V. All rights reserved.

Evaluating the biogas potential of the dry fraction from pretreatment of food waste from households.

PubMed

Murto, Marika; Björnsson, Lovisa; Rosqvist, Håkan; Bohn, Irene

2013-05-01

At the waste handling company NSR, Helsingborg, Sweden, the food waste fraction of source separated municipal solid waste is pretreated to obtain a liquid fraction, which is used for biogas production, and a dry fraction, which is at present incinerated. This pretreatment and separation is performed to remove impurities, however also some of the organic material is removed. The possibility of realising the methane potential of the dry fraction through batch-wise dry anaerobic digestion was investigated. The anaerobic digestion technique used was a two-stage process consisting of a static leach bed reactor and a methane reactor. Treatment of the dry fraction alone and in a mixture with structural material was tested to investigate the effect on the porosity of the leach bed. A tracer experiment was carried out to investigate the liquid flow through the leach beds, and this method proved useful in demonstrating a more homogenous flow through the leach bed when structural material was added. Addition of structural material to the dry fraction was needed to achieve a functional digestion process. A methane yield of 98 m3/ton was obtained from the dry fraction mixed with structural material after 76 days of digestion. This was in the same range as obtained in the laboratory scale biochemical methane potential test, showing that it was possible to extract the organic content in the dry fraction in this type of dry digestion system for the production of methane. Copyright © 2013 Elsevier Ltd. All rights reserved.

CLEANING OF FLUE GASES FROM WASTE COMBUSTORS

EPA Science Inventory

The paper addresses flue gas cleaning processes currently used commercially in waste combustion facilities. It also discusses the operating concepts of dry, semi-dry, and wet processes and their effectiveness in controlling various pollutants. Air pollutants from the combustion o...

Utilization of simultaneous saccharification and fermentation residues as feedstock for lipid accumulation in Rhodococcus opacus.

PubMed

Le, Rosemary K; Das, Parthapratim; Mahan, Kristina M; Anderson, Seth A; Wells, Tyrone; Yuan, Joshua S; Ragauskas, Arthur J

2017-09-29

Use of oleaginous microorganisms as "micro-factories" for accumulation of single cell oils for biofuel production has increased significantly to mitigate growing energy demands, resulting in efforts to upgrade industrial waste, such as second-generation lignocellulosic residues, into potential feedstocks. Dilute-acid pretreatment (DAP) is commonly used to alter the physicochemical properties of lignocellulosic materials and is typically coupled with simultaneous saccharification and fermentation (SSF) for conversion of sugars into ethanol. The resulting DAP residues are usually processed as a waste stream, e.g. burned for power, but this provides minimal value. Alternatively, these wastes can be utilized as feedstock to generate lipids, which can be converted to biofuel. DAP-SSF residues were generated from pine, poplar, and switchgrass. High performance liquid chromatography revealed less than 0.13% monomeric sugars in the dry residue. Fourier transform infrared spectroscopy was indicative of the presence of lignin and polysaccharides. Gel permeation chromatography suggested the bacterial strains preferred molecules with molecular weight ~ 400-500 g/mol. DAP-SSF residues were used as the sole carbon source for lipid production by Rhodococcus opacus DSM 1069 and PD630 in batch fermentations. Depending on the strain of Rhodococcus employed, 9-11 lipids for PD630 and DSM 1069 were observed, at a final concentration of ~ 15 mg/L fatty acid methyl esters (FAME) detected. Though the DAP-SSF substrate resulted in low FAME titers, novel analysis of solid-state fermentations was investigated, which determined that DAP-SSF residues could be a viable feedstock for lipid generation.

Vitrification of waste with conitnuous filling and sequential melting

DOEpatents

Powell, James R.; Reich, Morris

2001-09-04

A method of filling a canister with vitrified waste starting with a waste, such as high-level radioactive waste, that is cooler than its melting point. Waste is added incrementally to a canister forming a column of waste capable of being separated into an upper zone and a lower zone. The minimum height of the column is defined such that the waste in the lower zone can be dried and melted while maintaining the waste in the upper zone below its melting point. The maximum height of the column is such that the upper zone remains porous enough to permit evolved gases from the lower zone to flow through the upper zone and out of the canister. Heat is applied to the waste in the lower zone to first dry then to raise and maintain its temperature to a target temperature above the melting point of the waste. Then the heat is applied to a new lower zone above the melted waste and the process of adding, drying and melting the waste continues upward in the canister until the entire canister is filled and the entire contents are melted and maintained at the target temperature for the desired period. Cooling of the melted waste takes place incrementally from the bottom of the canister to the top, or across the entire canister surface area, forming a vitrified product.

Drying Shrinkage of Mortar Incorporating High Volume Oil Palm Biomass Waste

NASA Astrophysics Data System (ADS)

Shukor Lim, Nor Hasanah Abdul; Samadi, Mostafa; Rahman Mohd. Sam, Abdul; Khalid, Nur Hafizah Abd; Nabilah Sarbini, Noor; Farhayu Ariffin, Nur; Warid Hussin, Mohd; Ismail, Mohammed A.

2018-03-01

This paper studies the drying shrinkage of mortar incorporating oil palm biomass waste including Palm Oil Fuel Ash, Oil Palm Kernel Shell and Oil Palm Fibre. Nano size of palm oil fuel ash was used up to 80 % as cement replacement by weight. The ash has been treated to improve the physical and chemical properties of mortar. The mass ratio of sand to blended ashes was 3:1. The test was carried out using 25 × 25 × 160 mm prism for drying shrinkage tests and 70 × 70 ×70 mm for compressive strength test. The results show that the shrinkage value of biomass mortar is reduced by 31% compared with OPC mortar thus, showing better performance in restraining deformation of the mortar while the compressive strength increased by 24% compared with OPC mortar at later age. The study gives a better understanding of how the biomass waste affect on mortar compressive strength and drying shrinkage behaviour. Overall, the oil palm biomass waste can be used to produce a better performance mortar at later age in terms of compressive strength and drying shrinkage.

An Evaluation of the Functionality of Advanced Fuel Research Prototype Dry Pyrolyzer for Destruction of Solid Wastes

NASA Technical Reports Server (NTRS)

Fisher, John; Wignarajah, K.; Howard, Kevin; Serio, Mike; Kroo, Eric

2004-01-01

The prototype dry pyrolyser delivered to Ames Research Center is the end-product of a Phase I1 Small Business Initiative Research (SBIR) project. Some of the major advantages of pyrolysis for processing solid wastes are that it can process solid wastes, it permits elemental recycling while conserving oxygen use, and it can function as a pretreatment for combustion processes. One of the disadvantages of pyrolysis is the formation of tars. By controlling the rate of heating, tar formation can be minimized. This paper presents data on the pyrolysis of various space station wastes. The performance of the pyrolyser is also discussed and appropriate modifications suggested to improve the performance of the dry pyrolyzer.

Sewage sludge drying process integration with a waste-to-energy power plant.

PubMed

Bianchini, A; Bonfiglioli, L; Pellegrini, M; Saccani, C

2015-08-01

Dewatered sewage sludge from Waste Water Treatment Plants (WWTPs) is encountering increasing problems associated with its disposal. Several solutions have been proposed in the last years regarding energy and materials recovery from sewage sludge. Current technological solutions have relevant limits as dewatered sewage sludge is characterized by a high water content (70-75% by weight), even if mechanically treated. A Refuse Derived Fuel (RDF) with good thermal characteristics in terms of Lower Heating Value (LHV) can be obtained if dewatered sludge is further processed, for example by a thermal drying stage. Sewage sludge thermal drying is not sustainable if the power is fed by primary energy sources, but can be appealing if waste heat, recovered from other processes, is used. A suitable integration can be realized between a WWTP and a waste-to-energy (WTE) power plant through the recovery of WTE waste heat as energy source for sewage sludge drying. In this paper, the properties of sewage sludge from three different WWTPs are studied. On the basis of the results obtained, a facility for the integration of sewage sludge drying within a WTE power plant is developed. Furthermore, energy and mass balances are set up in order to evaluate the benefits brought by the described integration. Copyright © 2015 Elsevier Ltd. All rights reserved.

Recycling agroindustrial waste by lactic fermentations: coffee pulp silage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carrizales, V.; Ferrer, J.

1985-04-03

This UNIDO publication on lactic acid fermentation of coffee pulp for feed production covers (1) a process which can be adapted to existing coffee processing plants for drying the product once harvesting time has finished (2) unit operations involved: pressing (optional), silaging, liming and drying (3) experiments, results and discussion, bibliography, process statistics, and diagrams. Additional references: storage, biotechnology, lime, agricultural wastes, recycling, waste utilization.

Addition of polyaluminiumchloride (PACl) to waste activated sludge to mitigate the negative effects of its sticky phase in dewatering-drying operations.

PubMed

Peeters, Bart; Dewil, Raf; Vernimmen, Luc; Van den Bogaert, Benno; Smets, Ilse Y

2013-07-01

This paper presents a new application of polyaluminiumchloride (PACl) as a conditioner for waste activated sludge prior its dewatering and drying. It is demonstrated at lab scale with a shear test-based protocol that a dose ranging from 50 to 150 g PACl/kg MLSS (mixed liquor suspended solids) mitigates the stickiness of partially dried sludge with a dry solids content between 25 and 60 %DS (dry solids). E.g., at a solids dryness of 46% DS the shear stress required to have the pre-consolidated sludge slip over a steel surface is reduced with 35%. The salient feature of PACl is further supported by torque data from a full scale decanter centrifuge used to dewater waste sludge. The maximal torque developed by the screw conveyor inside the decanter centrifuge is substantially reduced with 20% in the case the sludge feed is conditioned with PACl. The beneficial effect of waste sludge conditioning with PACl is proposed to be the result of the bound water associated with the aluminium polymers in PACl solutions which act as a type of lubrication for the intrinsically sticky sludge solids during the course of drying. It can be anticipated that PACl addition to waste sludge will become a technically feasible and very effective method to avoid worldwide fouling problems in direct sludge dryers, and to reduce torque issues in indirect sludge dryers as well as in sludge decanter centrifuges. Copyright © 2013 Elsevier Ltd. All rights reserved.

A study of the impact of moist-heat and dry-heat treatment processes on hazardous trace elements migration in food waste.

PubMed

Chen, Ting; Jin, Yiying; Qiu, Xiaopeng; Chen, Xin

2015-03-01

Using laboratory experiments, the authors investigated the impact of dry-heat and moist-heat treatment processes on hazardous trace elements (As, Hg, Cd, Cr, and Pb) in food waste and explored their distribution patterns for three waste components: oil, aqueous, and solid components. The results indicated that an insignificant reduction of hazardous trace elements in heat-treated waste-0.61-14.29% after moist-heat treatment and 4.53-12.25% after dry-heat treatment-and a significant reduction in hazardous trace elements (except for Hg without external addition) after centrifugal dehydration (P < 0.5). Moreover, after heat treatment, over 90% of the hazardous trace elements in the waste were detected in the aqueous and solid components, whereas only a trace amount of hazardous trace elements was detected in the oil component (<0.01%). In addition, results indicated that heat treatment process did not significantly reduce the concentration of hazardous trace elements in food waste, but the separation process for solid and aqueous components, such as centrifugal dehydration, could reduce the risk considerably. Finally, combined with the separation technology for solid and liquid components, dry-heat treatment is superior to moist-heat treatment on the removal of external water-soluble ionic hazardous trace elements. An insignificant reduction of hazardous trace elements in heat-treated waste showed that heat treatment does not reduce trace elements contamination in food waste considerably, whereas the separation process for solid and aqueous components, such as centrifugal dehydration, could reduce the risk significantly. Moreover, combined with the separation technology for solid and liquid components, dry-heat treatment is superior to moist-heat treatment for the removal of external water-soluble ionic hazardous trace elements, by exploring distribution patterns of trace elements in three waste components: oil, aqueous, and solid components.

A Remote Absorption Process for Disposal of Evaporate and Reverse Osmosis Concentrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brunsell, D.A.

2008-07-01

Many commercial nuclear plants and DOE facilities generate secondary waste streams consisting of evaporator bottoms and reverse osmosis (RO) concentrate. Since liquids are not permitted in disposal facilities, these waste streams must be converted to dry solids, either by evaporation to dried solids or by solidification to liquid-free solids. Evaporation of the liquid wastes reduces their volume, but requires costly energy and capital equipment. In some cases, concentration of the contaminants during drying can cause the waste to exceed Class A waste for nuclear utilities or exceed DOE transuranic limits. This means that disposal costs will be increased, or that,more » when the Barnwell, SC disposal site closes to waste outside of the Atlantic Compact in July 2008, the waste will be precluded from disposal for the foreseeable future). Solidification with cement agents requires less energy and equipment than drying, but results in a volume increase of 50-100%. The doubling or tripling of waste weight, along with the increased volume, sharply increases shipping and disposal costs. Confronted with these unattractive alternatives, Diversified Technologies Services (DTS), in conjunction with selected nuclear utilities and D and D operations at Rocky Flats, undertook an exploratory effort to convert this liquid wastewater to a solid without using cement. This would avoid the bulking effect of cement, and permit the waste to be disposed of the Energy Solutions facility in Utah as well as some DOE facilities. To address the need for an attractive alternative to drying and cement solidification, a test program was developed using a polymer absorbent media to convert the concentrate streams to a liquid-free waste form that meets the waste acceptance criteria of the pertinent burial sites. Two approaches for mixing the polymer with the liquid were tested: mechanical mixing and in-situ incorporation. As part of this test program, a process control program (PCP) was developed that is 100% scalable from a concentrate test sample as small as 50 grams to full-scale processing of 100 cubic foot containers or larger. In summary: The absorption process offers utilities a viable and less costly alternative to on-site drying or solidification of concentrates. The absorption process can be completed by site personnel or by a vendor as a turnkey service. The process is suitable for multiple types of waste, including RO and evaporator concentrates, sludges, and other difficult to process waters and wet solids. (author)« less

Recovery of Waste Heat from Propellant Forced-Air Dry House

DTIC Science & Technology

1978-12-01

function of bulk air side film heat transfer coefficient and diffusivity 66 15. Dry house waste heat recovery system instrumentation 67 16. Sample data...inlet condition by, maintaining the exhaust temperature above the NG dew point. The set point is adjustable to accommodate various propel- lant and...system. In dry cycle operation, an overall energy recovery effectiveness of about 40% was measured for winter operation when the exhaust temperature

Consolidation process for producing ceramic waste forms

DOEpatents

Hash, Harry C.; Hash, Mark C.

2000-01-01

A process for the consolidation and containment of solid or semisolid hazardous waste, which process comprises closing an end of a circular hollow cylinder, filling the cylinder with the hazardous waste, and then cold working the cylinder to reduce its diameter while simultaneously compacting the waste. The open end of the cylinder can be sealed prior to or after the cold working process. The preferred method of cold working is to draw the sealed cylinder containing the hazardous waste through a plurality of dies to simultaneously reduce the diameter of the tube while compacting the waste. This process provides a quick continuous process for consolidating hazardous waste, including radioactive waste.

Solid and Liquid Waste Drying Bag

NASA Technical Reports Server (NTRS)

Litwiller, Eric (Inventor); Hogan, John A. (Inventor); Fisher, John W. (Inventor)

2009-01-01

Method and system for processing waste from human activities, including solids, liquids and vapors. A fluid-impermeable bag, lined with a liquid-impermeable but vapor-permeable membrane, defining an inner bag, is provided. A vacuum force is provided to extract vapors so that the waste is moved toward a selected region in the inner bag, extracted vapors, including the waste vapors and vaporized portions of the waste liquids are transported across the membrane, and most or all of the solids remain within the liner. Extracted vapors are filtered, and sanitized components thereof are isolated and optionally stored. The solids remaining within the liner are optionally dried and isolated for ultimate disposal.

Combined alkaline and ultrasonic pretreatment of sludge before aerobic digestion.

PubMed

Jin, Yiying; Li, Huan; Mahar, Rasool Bux; Wang, Zhiyu; Nie, Yongfeng

2009-01-01

Alkaline and ultrasonic sludge disintegration can be used as the pretreatment of waste activated sludge (WAS) to promote the subsequent anaerobic or aerobic digestion. In this study, different combinations of these two methods were investigated. The evaluation was based on the quantity of soluble chemical oxygen demand (SCOD) in the pretreated sludge as well as the degradation of organic matter in the subsequent aerobic digestion. For WAS samples with combined pretreatment, the released COD levels were higher than those with ultrasonic or alkaline pretreatment alone. When combined with the ultrasonic treatment, NaOH treatment was more efficient than Ca(OH)2 for WAS solubilization. The COD levels released in various sequential options of combined NaOH and ultrasonic treatments were in the the following descending order: simultaneous treatment > NaOH treatment followed by ultrasonic treatment > ultrasonic treatment followed by NaOH treatment. For simultaneous treatment, low NaOH dosage (100 g/kg dry solid), short duration (30 min) of NaOH treatment, and low ultrasonic specific energy (7500 kJ/kg dry solid) were suitable for sludge disintegration. Using combined NaOH and ultrasonic pretreatment with optimal parameters, the degradation efficiency of organic matter was increased from 38.0% to 50.7%, which is much higher than that with ultrasonic (42.5%) or with NaOH pretreatment (43.5%) in the subsequent aerobic digestion at the same retention time.

40 CFR 60.54a - Standard for municipal waste combustor acid gases.

Code of Federal Regulations, 2010 CFR

2010-07-01

... for Municipal Waste Combustors for Which Construction is Commenced After December 20, 1989 and on or... weight or volume) or 30 parts per million by volume, corrected to 7 percent oxygen (dry basis), whichever... by volume, corrected to 7 percent oxygen (dry basis), whichever is less stringent. ...

Sustainable biobutanol production from pineapple waste by using Clostridium acetobutylicum B 527: Drying kinetics study.

PubMed

Khedkar, Manisha A; Nimbalkar, Pranhita R; Gaikwad, Shashank G; Chavan, Prakash V; Bankar, Sandip B

2017-02-01

Present investigation explores the use of pineapple peel, a food industry waste, for acetone-butanol-ethanol (ABE) production using Clostridium acetobutylicum B 527. Proximate analysis of pineapple peel shows that it contains 35% cellulose, 19% hemicellulose, and 16% lignin on dry basis. Drying experiments on pineapple peel waste were carried out in the temperature range of 60-120°C and experimental drying data was modeled using moisture diffusion control model to study its effect on ABE production. The production of ABE was further accomplished via acid hydrolysis, detoxification, and fermentation process. Maximum total sugar release obtained by using acid hydrolysis was 97g/L with 95-97% and 10-50% removal of phenolics and acetic acid, respectively during detoxification process. The maximum ABE titer obtained was 5.23g/L with 55.6% substrate consumption when samples dried at 120°C were used as a substrate (after detoxification). Copyright © 2016 Elsevier Ltd. All rights reserved.

Potential gases emissions from the combustion of municipal solid waste by bio-drying.

PubMed

Zhang, Dong-Qing; He, Pin-Jing; Shao, Li-Ming

2009-09-15

One aerobic and two combined hydrolytic-aerobic processes were set up to investigate the influence of bio-drying on the potential emissions of combustion gases and the quantitative relationships of potential emissions with organics degradation. Results showed that the bio-drying would result in the increase of the HCl and SO(2) emissions and potential for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) formation, but the decrease of NO(x) emissions in the combustion. The potential emissions of combustion gases were correlated with organics degradation (correlation coefficient, r=0.67 for HCl, r=0.96 for SO(2), r=0.91 for PCDD/Fs and r=-0.60 for NO(x)). Interestingly, the total emissions of combustion gases based on input waste could be minimized by bio-drying. The bio-drying caused a reduction of NO(x) emissions but a negligible variation of total emissions of HCl and SO(2) as well as the potential for total PCDD/Fs formation. Moreover, the bio-drying could significantly improve the ratio of gas emissions to low heating values. The mixed waste after bio-drying was more favorable for combustion and the combined process with insufficient aeration during the hydrolytic stage was proposed for the bio-drying operation.

Heat of Hydration of Low Activity Cementitious Waste Forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nasol, D.

2015-07-23

During the curing of secondary waste grout, the hydraulic materials in the dry mix react exothermally with the water in the secondary low-activity waste (LAW). The heat released, called the heat of hydration, can be measured using a TAM Air Isothermal Calorimeter. By holding temperature constant in the instrument, the heat of hydration during the curing process can be determined. This will provide information that can be used in the design of a waste solidification facility. At the Savannah River National Laboratory (SRNL), the heat of hydration and other physical properties are being collected on grout prepared using three simulantsmore » of liquid secondary waste generated at the Hanford Site. From this study it was found that both the simulant and dry mix each had an effect on the heat of hydration. It was also concluded that the higher the cement content in the dry materials mix, the greater the heat of hydration during the curing of grout.« less

Technical evaluation of a tank-connected food waste disposer system for biogas production and nutrient recovery.

PubMed

Davidsson, Å; Bernstad Saraiva, A; Magnusson, N; Bissmont, M

2017-07-01

In this study, a tank-connected food waste disposer system with the objective to optimise biogas production and nutrient recovery from food waste in Malmö was evaluated. The project investigated the source-separation ratio of food waste through waste composition analyses, determined the potential biogas production in ground food waste, analysed the organic matter content and the limiting components in ground food waste and analysed outlet samples to calculate food waste losses from the separation tank. It can be concluded that the tank-connected food waste disposer system in Malmö can be used for energy recovery and optimisation of biogas production. The organic content of the collected waste is very high and contains a lot of energy rich fat and protein, and the methane potential is high. The results showed that approximately 38% of the food waste dry matter is collected in the tank. The remaining food waste is either found in residual waste (34% of the dry matter) or passes the tank and goes through the outlet to the sewer (28%). The relatively high dry matter content in the collected fraction (3-5% DM) indicates that the separation tank can thicken the waste substantially. The potential for nutrient recovery is rather limited considering the tank content. Only small fractions of the phosphorus (15%) and nitrogen (21%) are recyclable by the collected waste in the tank. The quality of the outlet indicates a satisfactory separation of particulate organic matter and fat. The organic content and nutrients, which are in dissolved form, cannot be retained in the tank and are rather led to the sewage via the outlet. Copyright © 2017 Elsevier Ltd. All rights reserved.

Concentrations, profiles, and estimated human exposures for polychlorinated dibenzo-p-dioxins and dibenzofurans from electronic waste recycling facilities and a chemical industrial complex in Eastern China.

PubMed

Ma, Jing; Kannan, Kurunthachalam; Cheng, Jinping; Horii, Yuichi; Wu, Qian; Wang, Wenhua

2008-11-15

Environmental pollution arising from electronic waste (e-waste) disposal and recycling has received considerable attention in recent years. Treatment, at low temperatures, of e-wastes that contain polyvinylchloride and related polymers can release polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Although several studies have reported trace metals and polybrominated diphenyl ethers (PBDEs) released from e-waste recycling operations, environmental contamination and human exposure to PCDD/Fs from e-waste recycling operations are less well understood. In this study, electronic shredder waste and dust from e-waste facilities, and leaves and surface soil collected in the vicinity of a large scale e-waste recycling facility in Taizhou, Eastern China, were analyzed for total PCDD/ Fs including 2,3,7,8-substituted congeners. We also determined PCDD/Fs in surface agricultural soils from several provinces in China for comparison with soils from e-waste facilities. Concentrations of total PCDD/Fs were high in all of the matrices analyzed and ranged from 30.9 to 11400 pg/g for shredder waste, 3460 to 9820 pg/g dry weight for leaves, 2560 to 148000 pg/g dry weight for workshop-floor dust, and 854 to 10200 pg/g dry weight for soils. We also analyzed surface soils from a chemical industrial complex (a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) in Shanghai. Concentrations of total PCDD/Fs in surface soil (44.5-531 pg/g dry wt) from the chemical industrial complex were lower than the concentrations found in soils from e-waste recycling plants, but higher than the concentrations found in agricultural soils. Agricultural soils from six cities in China contained low levels (3.44-33.8 pg/g dry wt) of total PCDD/Fs. Profiles of dioxin toxic equivalents (TEQs) of 2,3,7,8-PCDD/Fs in soils from e-waste facilities in Taizhou differed from the profiles found in agricultural soils. The estimated daily intakes of TEQs of PCDD/ Fs via soil/dust ingestion and dermal exposure (2.3 and 0.363 pg TEQ/kg bw/day for children and adults, respectively) were 2 orders of magnitude higher in people at e-waste recycling facilities than in people at the chemical industrial site (0.021 and 0.0053 pg TEQ/kg bw/day for children and adults, respectively), implying greater health risk for humans from dioxin exposures at e-waste recycling facilities. The calculated TEQ exposures for e-waste workers from dust and soil ingestion alone were 2-3 orders of magnitude greater than the exposures from soils in reference locations.

Dry Cleaning Sector (NAICS 8123)

EPA Pesticide Factsheets

The dry cleaning sector includes establishments engaged in providing laundry services and industrial launderers. Find environmental regulatory information for perchloroethylene (PERC) cleaners as well as hazardous waste regulations for dry cleaners.

Estimating biogas production of biologically treated municipal solid waste.

PubMed

Scaglia, Barbara; Confalonieri, Roberto; D'Imporzano, Giuliana; Adani, Fabrizio

2010-02-01

In this work, a respirometric approach, i.e., Dynamic Respiration Index (DRI), was used to predict the anaerobic biogas potential (ABP), studying 46 waste samples coming directly from MBT full-scale plants. A significant linear regression model was obtained by a jackknife approach: ABP=(34.4+/-2.5)+(0.109+/-0.003).DRI. The comparison of the model of this work with those of the previous works using a different respirometric approach (Sapromat-AT(4)), allowed obtaining similar results and carrying out direct comparison of different limits to accept treated waste in landfill, proposed in the literature. The results indicated that on an average, MBT treatment allowed 56% of ABP reduction after 4weeks of treatment, and 79% reduction after 12weeks of treatment. The obtainment of another regression model allowed transforming Sapromat-AT(4) limit in DRI units, and achieving a description of the kinetics of DRI and the corresponding ABP reductions vs. MBT treatment-time.

SELF SINTERING OF RADIOACTIVE WASTES

DOEpatents

McVay, T.N.; Johnson, J.R.; Struxness, E.G.; Morgan, K.Z.

1959-12-29

A method is described for disposal of radioactive liquid waste materials. The wastes are mixed with clays and fluxes to form a ceramic slip and disposed in a thermally insulated container in a layer. The temperature of the layer rises due to conversion of the energy of radioactivity to heat boillng off the liquid to fomn a dry mass. The dry mass is then covered with thermal insulation, and the mass is self-sintered into a leach-resistant ceramic cake by further conversion of the energy of radioactivity to heat.

Utilization of waste tire rubber in manufacture of oriented strandboard.

PubMed

Ayrilmis, Nadir; Buyuksari, Umit; Avci, Erkan

2009-09-01

Some physical and mechanical properties of oriented strandboards (OSBs) containing waste tire rubber at various addition levels based on the oven-dry strand weight, using the same method as that used in the manufacture of OSB. Two resin types, phenol-formaldehyde (PF) and polyisocyanate, were used in the experiments. The manufacturing parameters were: a specific gravity of 0.65 and waste tire rubber content (10/90, 20/80 and 30/70 by wt.% of waste tire rubber/wood strand). Average internal bond values of PF-bonded OSB panels with rubber chips were between 17.6% and 48.5% lower than the average of the control samples while polyisocyanate bonded OSBs were 16.5-50.6%. However, water resistance and mechanical properties of OSBs made using polyisocyanate resin were found to comply with general-purpose OSB minimum property requirements of EN 300 Type 1 (1997) values for use in dry conditions at the lowest tire rubber loading level (10%) based on the oven-dry panel weight. The tire rubber improved water resistance of the OSB panel due to its almost hydrophobic property. Based on the findings obtained from this study, we concluded that waste tire rubber could be used for general-purpose OSB manufacturing up to 10% ratio based on the oven-dry panel weight.

Production of ethanol from a mixture of waste paper and kitchen waste via a process of successive liquefaction, presaccharification, and simultaneous saccharification and fermentation.

PubMed

Nishimura, Hiroto; Tan, Li; Kira, Noriko; Tomiyama, Shigeo; Yamada, Kazuo; Sun, Zhao-Yong; Tang, Yue-Qin; Morimura, Shigeru; Kida, Kenji

2017-09-01

Efficient ethanol production from waste paper requires the addition of expensive nutrients. To reduce the production cost of ethanol from waste paper, a study on how to produce ethanol efficiently by adding kitchen waste (potentially as a carbon source, nutrient source, and acidity regulator) to waste paper was performed and a process of successive liquefaction, presaccharification, and simultaneous saccharification and fermentation (L+PSSF) was developed. The individual saccharification performances of waste paper and kitchen waste were not influenced by their mixture. Liquefaction of kitchen waste at 90°C prior to presaccharification and simultaneous saccharification and fermentation (PSSF) was essential for efficient ethanol fermentation. Ethanol at concentrations of 46.6 or 43.6g/l was obtained at the laboratory scale after fermentation for 96h, even without pH adjustment and/or the addition of extra nutrients. Similarly, ethanol at a concentration of 45.5g/l was obtained at the pilot scale after fermentation for 48h. The ethanol concentration of L+PSSF of the mixture of waste paper and kitchen waste was comparable to that of PSSF of waste paper with added nutrients (yeast extract and peptone) and pH adjustment using H 2 SO 4 , indicating that kitchen waste is not only a carbon source but also an excellent nutrient source and acidity regulator for fermentation of the mixture of waste paper and kitchen waste. Copyright © 2017. Published by Elsevier Ltd.

Reductive capacity measurement of waste forms for secondary radioactive wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Um, Wooyong; Yang, Jung-Seok; Serne, R. Jeffrey

2015-12-01

The reductive capacities of dry ingredients and final solid waste forms were measured using both the Cr(VI) and Ce(IV) methods and the results were compared. Blast furnace slag (BFS), sodium sulfide, SnF2, and SnCl2 used as dry ingredients to make various waste forms showed significantly higher reductive capacities compared to other ingredients regardless of which method was used. Although the BFS exhibits appreciable reductive capacity, it requires greater amounts of time to fully react. In almost all cases, the Ce(IV) method yielded larger reductive capacity values than those from the Cr(VI) method and can be used as an upper boundmore » for the reductive capacity of the dry ingredients and waste forms, because the Ce(IV) method subjects the solids to a strong acid (low pH) condition that dissolves much more of the solids. Because the Cr(VI) method relies on a neutral pH condition, the Cr(VI) method can be used to estimate primarily the waste form surface-related and readily dissolvable reductive capacity. However, the Cr(VI) method does not measure the total reductive capacity of the waste form, the long-term reductive capacity afforded by very slowly dissolving solids, or the reductive capacity present in the interior pores and internal locations of the solids.« less

Prediction of the compression ratio for municipal solid waste using decision tree.

PubMed

Heshmati R, Ali Akbar; Mokhtari, Maryam; Shakiba Rad, Saeed

2014-01-01

The compression ratio of municipal solid waste (MSW) is an essential parameter for evaluation of waste settlement and landfill design. However, no appropriate model has been proposed to estimate the waste compression ratio so far. In this study, a decision tree method was utilized to predict the waste compression ratio (C'c). The tree was constructed using Quinlan's M5 algorithm. A reliable database retrieved from the literature was used to develop a practical model that relates C'c to waste composition and properties, including dry density, dry weight water content, and percentage of biodegradable organic waste using the decision tree method. The performance of the developed model was examined in terms of different statistical criteria, including correlation coefficient, root mean squared error, mean absolute error and mean bias error, recommended by researchers. The obtained results demonstrate that the suggested model is able to evaluate the compression ratio of MSW effectively.

Evaluation and comparison of alternative designs for water/solid-waste processing systems for spacecraft

NASA Technical Reports Server (NTRS)

Spurlock, J. M.

1975-01-01

Promising candidate designs currently being considered for the management of spacecraft solid waste and waste-water materials were assessed. The candidate processes were: (1) the radioisotope thermal energy evaporation/incinerator process; (2) the dry incineration process; and (3) the wet oxidation process. The types of spacecraft waste materials that were included in the base-line computational input to the candidate systems were feces, urine residues, trash and waste-water concentrates. The performance characteristics and system requirements for each candidate process to handle this input and produce the specified acceptable output (i.e., potable water, a storable dry ash, and vapor phase products that can be handled by a spacecraft atmosphere control system) were estimated and compared. Recommendations are presented.

Soil contamination by brominated flame retardants in open waste dumping sites in Asian developing countries.

PubMed

Eguchi, Akifimi; Isobe, Tomohiko; Ramu, Karri; Tue, Nguyen Minh; Sudaryanto, Agus; Devanathan, Gnanasekaran; Viet, Pham Hung; Tana, Rouch Seang; Takahashi, Shin; Subramanian, Annamalai; Tanabe, Shinsuke

2013-03-01

In Asian developing countries, large amounts of municipal wastes are dumped into open dumping sites each day without adequate management. This practice may cause several adverse environmental consequences and increase health risks to local communities. These dumping sites are contaminated with many chemicals including brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecanes (HBCDs). BFRs may be released into the environment through production processes and through the disposal of plastics and electronic wastes that contain them. The purpose of this study was to elucidate the status of BFR pollution in municipal waste dumping sites in Asian developing countries. Soil samples were collected from six open waste dumping sites and five reference sites in Cambodia, India, Indonesia, Malaysia, and Vietnam from 1999 to 2007. The results suggest that PBDEs are the dominant contaminants in the dumping sites in Asian developing countries, whereas HBCD contamination remains low. Concentrations of PBDEs and HBCDs ranged from ND to 180 μg/kg dry wt and ND to 1.4 μg/kg dry wt, respectively, in the reference sites and from 0.20 to 430 μg/kg dry wt and ND to 2.5 μg/kg dry wt, respectively, in the dumping sites. Contamination levels of PBDEs in Asian municipal dumping sites were comparable with those reported from electronic waste dismantling areas in Pearl River delta, China. Copyright © 2012 Elsevier Ltd. All rights reserved.

Potential SRF generation from a closed landfill in northern Italy.

PubMed

Passamani, Giorgia; Ragazzi, Marco; Torretta, Vincenzo

2016-01-01

The aim of this work is to assess the possibility of producing solid recovered fuel (SRF) and "combustible SRF" from a landfill located in the north of Italy, where the waste is placed in cylindrical wrapped bales. Since the use of landfills for the disposal of municipal solid waste has many technical limitations and is subject to strict regulations and given that landfill post-closure care is very expensive, an interesting solution is to recover the bales that are stored in the landfill. The contents of the bales can then be used for energy recovery after specific treatments. Currently the landfill is closed and the local municipal council together with an environmental agency are considering constructing a mechanical biological treatment (MBT) plant for SRF production. The municipal solid waste that is stored in the landfill, the bio-dried material produced by the hypothetically treated waste in a plant for bio-drying, and the SRF obtained after the post-extraction of inert materials, metals and glass from the bio-dried material were characterized according to the quality and classification criteria of regulations in Italy. The analysis highlighted the need to treat the excavated waste in a bio-drying plant and later to remove the inert waste, metals and glass. Thus in compliance with Italian law, the material has a high enough LHV to be considered as "combustible SRF", (i.e. an SRF with enhanced characteristics). Copyright © 2015 Elsevier Ltd. All rights reserved.

Non-steady state partitioning of dry cleaning surfactants between tetrachloroethylene (PCE) and water in porous media.

PubMed

Hoggan, James L; Bae, Keonbeom; Kibbey, Tohren C G

2007-08-15

Trapped organic solvents, in both the vadose zone and below the water table, are frequent sources of environmental contamination. A common source of organic solvent contamination is spills, leaks, and improper solvent disposal associated with dry cleaning processes. Dry cleaning solvents, such as tetrachloroethylene (PCE), are typically enhanced with the addition of surfactants to improve cleaning performance. The objective of this work was to examine the partitioning behavior of surfactants from PCE in contact with water. The relative rates of surfactants partitioning and PCE dissolution are important for modeling the behavior of waste PCE in the subsurface, in that they influence the interfacial tension of the PCE, and how (or if) interfacial tension changes over time in the subsurface. The work described here uses a flow-through system to examine simultaneous partitioning and PCE dissolution in a porous medium. Results indicate that both nonylphenol ethoxylate nonionic surfactants and a sulfosuccinate anionic surfactant partition out of residual PCE much more rapidly than the PCE dissolves, suggesting that in many cases interfacial tension changes caused by partitioning may influence infiltration and distribution of PCE in the subsurface. Non-steady-state partitioning is found to be well-described by a linear driving force model incorporating measured surfactant partition coefficients.

Nutrient digestibility of vegetables waste flour on male quail (Coturnix coturnix japonica)

NASA Astrophysics Data System (ADS)

Pramono, A.; Primadhani, M. S.; Swastike, W.; Sutrisno, J.

2018-03-01

The aim of this research is to determine the nutrient digestibility of vegetables waste flour on of male quail. Four hundred male quails were divided into four groups with five replications. The experiment is Completely Randomized Design and the data were analyzed by analyses of variants. The experimental diets were P0 = basal diet, P1 = 97% basal diet + 3% vegetables waste flour, P2 = 94% basal diet + 6% vegetables waste flour, and P3 = 91% basal diet + 9% vegetables waste flour. The observed variables were the digestibility of dry matter, crude protein and extract ether. Result showed that of the addition of vegetable waste flour in the diet had no effect on crude protein digestibility (P>0.05), however shown significant effect on dry matter (P <0.01) and extract ether (P <0.01) digestibility.

A study on the dewatering of industrial waste sludge by fry-drying technology.

PubMed

Ohm, Tae-In; Chae, Jong-Seong; Kim, Jeong-Eun; Kim, Hee-Kyum; Moon, Seung-Hyun

2009-08-30

In sludge treatment, drying sludge using typical technology with high water content to a water content of approximately 10% is always difficult because of adhesive characteristics of sludge. Many methods have been applied, including direct and indirect heat drying, but these approaches of reducing water content to below 40% after drying is very inefficient in energy utilization of drying sludge. In this study, fry-drying technology with a high heat transfer coefficient of approximately 500 W/m(2) degrees C was used to dry industrial wastewater sludge. Also waste oil was used in the fry-drying process, and because the oil's boiling point is between 240 and 340 degrees C and the specific heat is approximately 60% of that of water. In the fry-drying system, the sludge is input by molding it into a designated form after heating the waste oil at temperatures between 120 and 170 degrees C. At these temperatures, the heated oil rapidly evaporates the water contained in the sludge, leaving the oil itself. After approximately 10 min, the water content of the sludge was less than 10%, and its heating value surpassed 5300 kcal/kg. Indeed, this makes the organic sludge appropriate for use as a solid fuel. The wastewater sludge used in this study was the designated waste discharged from chemical, leather and plating plants. These samples varied in characteristics, especially with regard to heavy metal concentration. After drying the three kinds of wastewater sludge at oil temperatures 160 degrees C for 10 min, it was found that the water content in the sludge from the chemical, leather, and plating plants reduced from 80.0 to 5.5%, 81.6 to 1.0%, and 65.4 to 0.8%, respectively. Furthermore, the heat values of the sludge from the chemical, leather, and plating plants prior to fry-drying were 217, 264, and 428 kcal/kg, respectively. After drying, these values of sludge increased to 5317, 5983 and 6031 kcal/kg, respectively. The heavy metals detected in the sludge after drying were aluminum, lead, zinc, mercury, and cadmium. Most importantly, if the dried sludge is used as a solid fuel, these heavy metals can be collected from the dust collector after combustion.

Remediation of textile dye waste water using a white-rot fungus Bjerkandera adusta through solid-state fermentation (SSF).

PubMed

Robinson, Tim; Nigam, Poonam Singh

2008-12-01

A strict screening strategy for microorganism selection was followed employing a number of white-rot fungi for the bioremediation of textile effluent, which was generated from one Ireland-based American textile industry. Finally, one fungus Bjerkandera adusta has been investigated in depth for its ability to simultaneously degrade and enrich the nutritional quality of highly coloured textile effluent-adsorbed barley husks through solid-state fermentation (SSF). Certain important parameters such as media requirements, moisture content, protein/biomass production and enzyme activities were examined in detail. A previously optimised method of dye desorption was employed to measure the extent of dye remediation through effluent decolorisation achieved as a result of fungal activity in SSF. B. adusta was capable of decolourising a considerable concentration of the synthetic dye effluent (up to 53%) with a moisture content of 80-85%. Protein enrichment of the fermented mass was achieved to the extent of 229 g/kg dry weight initial substrate used. Lignin peroxidase and laccase were found to be the two main enzymes produced during SSF of the dye-adsorbed lignocellulosic waste residue.

Effect of simultaneous infrared dry-blanching and dehydration on quality characteristics of carrot slices

USDA-ARS?s Scientific Manuscript database

This study investigated the effects of various processing parameters on carrot slices exposed to infrared (IR) radiation heating for achieving simultaneous infrared dry-blanching and dehydration (SIRDBD). The investigated parameters were product surface temperature, slice thickness and processing ti...

Thermal Flammable Gas Production from Bulk Vitrification Feed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scheele, Randall D.; McNamara, Bruce K.; Bagaasen, Larry M.

2008-05-21

The baseline bulk-vitrification (BV) process (also known as in-container vitrification ICV™) includes a mixer/dryer to convert liquid low-activity waste (LAW) into a dried, blended feed for vitrification. Feed preparation includes blending LAW with glass-forming minerals (GFMs) and cellulose and drying the mixture to a suitable dryness, consistency, and particle size for transport to the ICVTM container. The cellulose is to be added to the BV feed at a rate sufficient to destroy 75% of the nitrogen present as nitrate or nitrite. Concern exists that flammable gases may be produced during drying operations at levels that could pose a risk. Themore » drying process is conducted under vacuum in the temperature range of 60 to 80°C. These flammable gases could be produced either through thermal decomposition of cellulose or waste organics or as a by-product of the reaction of cellulose and/or waste organics with nitrate or the postulated small amount of nitrite present in the waste. To help address the concern about flammable gas production during drying, the Pacific Northwest National Laboratory (PNNL) performed studies to identify the gases produced at dryer temperatures and at possible process upset conditions. Studies used a thermogravimetric analyzer (TGA) up to 525°C and isothermal testing up to 120°C to determine flammable gas production resulting from the cellulose and organic constituents in bulk vitrification feed. This report provides the results of those studies to determine the effects of cellulose and waste organics on flammable gas evolution« less

Simultaneous treatment of SO2 containing stack gases and waste water

NASA Technical Reports Server (NTRS)

Poradek, J. C.; Collins, D. D. (Inventor)

1978-01-01

A process for simultaneously removing sulfur dioxide from stack gases and the like and purifying waste water such as derived from domestic sewage is described. A portion of the gas stream and a portion of the waste water, the latter containing dissolved iron and having an acidic pH, are contacted in a closed loop gas-liquid scrubbing zone to effect absorption of the sulfur dioxide into the waste water. A second portion of the gas stream and a second portion of the waste water are controlled in an open loop gas-liquid scrubbing zone. The second portion of the waste water contains a lesser amount of iron than the first portion of the waste water. Contacting in the openloop scrubbing zone is sufficient to acidify the waste water which is then treated to remove solids originally present.

Immersion frying for the thermal drying of sewage sludge: an economic assessment.

PubMed

Peregrina, Carlos; Rudolph, Victor; Lecomte, Didier; Arlabosse, Patricia

2008-01-01

This paper presents an economic study of a novel thermal fry-drying technology which transforms sewage sludge and recycled cooking oil (RCO) into a solid fuel. The process is shown to have significant potential advantage in terms of capital costs (by factors of several times) and comparable operating costs. Three potential variants of the process have been simulated and costed in terms of both capital and operating requirements for a commercial scale of operation. The differences are in the energy recovery systems, which include a simple condensation of the evaporated water and two different heat pump configurations. Simple condensation provides the simplest process, but the energy efficiency gain of an open heat pump offset this, making it economically somewhat more attractive. In terms of operating costs, current sludge dryers are dominated by maintenance and energy requirements, while for fry-drying these are comparatively small. Fry-drying running costs are dominated by provision of makeup waste oil. Cost reduction could focus on cheaper waste oil, e.g. from grease trap waste.

Recovery of rare metal compounds from nickel-metal hydride battery waste and their application to CH4 dry reforming catalyst.

PubMed

Kanamori, Tomohiro; Matsuda, Motohide; Miyake, Michihiro

2009-09-30

The recovery of valuable components such as nickel from nickel-metal hydride (Ni-MH) battery waste by chemical processes and their applications to CH(4) dry reforming catalysts were investigated. Three types of compound, identified by XRD analysis as NiO, CeO(2) and LaCoO(3) phases, were successfully separated from the waste by a series of chemical processes at room temperature using aqueous solutions of HCl, NaOH and NH(3), and Ni component of approximately 70% in Ni-MH battery waste was recovered. The separated NiO, CeO(2) and LaCoO(3) showed catalytic activities for CH(4) dry reforming. In particular, the separated NiO easily reduced to Ni(0) at an initial stage, and exhibited excellent catalytic activity in terms of CH(4) conversion and stability. Furthermore, it was found that the resulting Ni from separated NiO exhibited an anomalous catalysis from the comparison with that from regent NiO.

Simultaneous detection of multiple adulterants in dry milk using macro-scale Raman chemical imaging

USDA-ARS?s Scientific Manuscript database

The potential of Raman chemical imaging for simultaneously detecting multiple adulterants in milk powder was investigated. Potential chemical adulterants, including ammonium sulfate, dicyandiamide, melamine, and urea, were mixed together into skim dry milk in the concentration range of 0.1–5.0% for ...

Simultaneous drying and decontamination of rough rice using combined pulsed light and holding treatment

USDA-ARS?s Scientific Manuscript database

Pulsed light (PL) technology has been proven effective in food disinfection. However, increasing the light intensity or treatment time could swiftly increase the temperature of the food product. Using the thermal effect in an appropriate way may achieve a simultaneous disinfection and drying effect....

Evaluation of landfill gas emissions from municipal solid waste landfills for the life-cycle analysis of waste-to-energy pathways

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Uisung; Han, Jeongwoo; Wang, Michael

Various waste-to-energy (WTE) conversion technologies can generate energy products from municipal solid waste (MSW). Accurately evaluating landfill gas (LFG, mainly methane) emissions from base case landfills is critical to conducting a WTE life-cycle analysis (LCA) of their greenhouse gas (GHG) emissions. To reduce uncertainties in estimating LFG, this study investigated key parameters for its generation, based on updated experimental results. These results showed that the updated parameters changed the calculated GHG emissions from landfills significantly depending on waste stream; they resulted in a 65% reduction for wood (from 2412 to 848 t CO 2e/dry t) to a 4% increase formore » food waste (from 2603 to 2708 t CO 2e/dry t). Landfill GHG emissions also vary significantly based on LFG management practices and climate. In LCAs of WTE conversion, generating electricity from LFG helps reduce GHG emissions indirectly by displacing regional electricity. When both active LFG collection and power generation are considered, GHG emissions are 44% less for food waste (from 2708 to 1524 t CO 2e/dry t), relative to conventional MSW landfilling. The method developed and data collected in this study can help improve the assessment of GHG impacts from landfills, which supports transparent decision-making regarding the sustainable treatment, management, and utilization of MSW.« less

Evaluation of landfill gas emissions from municipal solid waste landfills for the life-cycle analysis of waste-to-energy pathways

DOE PAGES

Lee, Uisung; Han, Jeongwoo; Wang, Michael

2017-08-05

Various waste-to-energy (WTE) conversion technologies can generate energy products from municipal solid waste (MSW). Accurately evaluating landfill gas (LFG, mainly methane) emissions from base case landfills is critical to conducting a WTE life-cycle analysis (LCA) of their greenhouse gas (GHG) emissions. To reduce uncertainties in estimating LFG, this study investigated key parameters for its generation, based on updated experimental results. These results showed that the updated parameters changed the calculated GHG emissions from landfills significantly depending on waste stream; they resulted in a 65% reduction for wood (from 2412 to 848 t CO 2e/dry t) to a 4% increase formore » food waste (from 2603 to 2708 t CO 2e/dry t). Landfill GHG emissions also vary significantly based on LFG management practices and climate. In LCAs of WTE conversion, generating electricity from LFG helps reduce GHG emissions indirectly by displacing regional electricity. When both active LFG collection and power generation are considered, GHG emissions are 44% less for food waste (from 2708 to 1524 t CO 2e/dry t), relative to conventional MSW landfilling. The method developed and data collected in this study can help improve the assessment of GHG impacts from landfills, which supports transparent decision-making regarding the sustainable treatment, management, and utilization of MSW.« less

Quantifying the transport impacts of domestic waste collection strategies.

PubMed

McLeod, Fraser; Cherrett, Tom

2008-11-01

This paper models the effects of three different options for domestic waste collection using data from three Hampshire authorities: (i) joint working between neighbouring waste collection authorities; (ii) basing vehicles at waste disposal sites; and (iii) alternate weekly collection of residual waste and dry recyclables. A vehicle mileage savings of 3% was modelled for joint working, where existing vehicle allocations to depots were maintained, which increased to 5.9% when vehicles were re-allocated to depots optimally. Vehicle mileage was reduced by 13.5% when the collection rounds were based out of the two waste disposal sites rather than out of the existing depots, suggesting that the former could be the most effective place to keep vehicles providing that travel arrangements for the crews could be made. Alternate weekly collection was modelled to reduce vehicle mileage by around 8% and time taken by 14%, when compared with a typical scenario of weekly collection of residual and fortnightly collection of recyclable waste. These results were based on an assumption that 20% of the residual waste would be directly diverted into the dry recyclables waste stream.

40 CFR Table Tt-1 to Subpart Tt of... - Default DOC and Decay Rate Values for Industrial Waste Landfills

Code of Federal Regulations, 2013 CFR

2013-07-01

... Industrial Waste Landfills TT Table TT-1 to Subpart TT of Part 98 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Industrial Waste... for Industrial Waste Landfills Industry/Waste Type DOC(weight fraction, wet basis) k[dry climatea] (yr...

40 CFR Table Tt-1 to Subpart Tt of... - Default DOC and Decay Rate Values for Industrial Waste Landfills

Code of Federal Regulations, 2014 CFR

2014-07-01

... Industrial Waste Landfills TT Table TT-1 to Subpart TT of Part 98 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Industrial Waste... for Industrial Waste Landfills Industry/Waste Type DOC(weight fraction, wet basis) k[dry climatea] (yr...

Techno-economic evaluation of a tandem dry batch, garage-style digestion-compost process for remote work camp environments.

PubMed

Hayes, Alexander C; Enongene Ekwe, S; Mervin, Steve; Jenson, Earl

2016-12-01

The extraction of natural resources often involves housing workers in remote work camps far from population centres. These camps are prevalent in northern Alberta where they house approximately 40,000 workers involved in oil sands processing. The central, full-service cafeterias at these camps produce a significant quantity of food and cardboard waste. Due to their remote nature, these camps face high waste disposal costs associated with trucking waste long distances to the landfill. In this study, we investigated the techno-economic feasibility of on-site treatment of food and cardboard waste in a tandem dry batch, garage-style anaerobic digestion-compost process in which the waste material is converted into renewable energy used to heat the camp water supply and a nutrient-rich soil amendment for local land reclamation projects. Dry batch digestion and windrow composting pilot trials were performed on a simulated work camp waste in order to assess technical performance. The quality of the final compost was found to meet regulatory standards. A complete mass balance was then developed for a facility treating 3000 tonnes food waste and 435 tonnes waste cardboard annually. An economic assessment of such a facility was performed and, depending on the level of capital support and recognition of carbon credits for landfill methane mitigation, would require waste disposal costs to be between $115 and $195 CAD per tonne to meet financial criteria for project selection in Alberta's oil and gas industry. Copyright © 2016 Elsevier Ltd. All rights reserved.

Spatial distribution of polybrominated diphenyl ethers and polychlorinated dibenzo-p-dioxins and dibenzofurans in soil and combusted residue at Guiyu, an electronic waste recycling site in southeast China.

PubMed

Leung, Anna O W; Luksemburg, William J; Wong, Anthony S; Wong, Ming H

2007-04-15

Surface soils and combusted residue from a village located in southeast China, which has been intensely involved in the dismantling and "recycling" of computer parts (e-waste) for the past decade, were analyzed for polybrominated diphenyl ethers (PBDEs) and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Total PBDE concentrations were highest in combusted residue of plastic chips and cables collected from a residential area (33,000-97,400 ng/g, dry wt), in soils from an acid leaching site (2720-4250 ng/g, dry wt), and a printer roller dump site (593-2890 ng/g, dry wt). BDE-209 was the most dominant congener (35-82%) among the study sites indicating the prevalence of commercial Deca-BDE, however signature congeners from commercial Penta- and Octa-BDE were also found. PCDD/F concentrations were also highest in soil from the acid leaching site (12,500-89,800 pg/g, 203-1100 pg WHO-TEQ/g, dry wt) and in combusted residue (13,500-25,300 pg/g, 84.3-174 pg WHO-TEQ/g, dry wt) and were comparable to PCDD/F levels of some open dumping sites in Asian developing countries. Of the e-waste activities, acid leaching and open burning emitted the highest concentrations of PBDEs and PCDD/Fs. This study is among the very few studies dealing with the important issue of pollution generated from crude e-waste recycling. Our results showthatthe crude processing of e-waste has become one of the major contributors of PBDEs and PCDD/Fs to the terrestrial environment.

Utilization of biocatalysts in cellulose waste minimization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woodward, J.; Evans, B.R.

1996-09-01

Cellulose, a polymer of glucose, is the principal component of biomass and, therefore, a major source of waste that is either buried or burned. Examples of biomass waste include agricultural crop residues, forestry products, and municipal wastes. Recycling of this waste is important for energy conservation as well as waste minimization and there is some probability that in the future biomass could become a major energy source and replace fossil fuels that are currently used for fuels and chemicals production. It has been estimated that in the United States, between 100-450 million dry tons of agricultural waste are produced annually,more » approximately 6 million dry tons of animal waste, and of the 190 million tons of municipal solid waste (MSW) generated annually, approximately two-thirds is cellulosic in nature and over one-third is paper waste. Interestingly, more than 70% of MSW is landfilled or burned, however landfill space is becoming increasingly scarce. On a smaller scale, important cellulosic products such as cellulose acetate also present waste problems; an estimated 43 thousand tons of cellulose ester waste are generated annually in the United States. Biocatalysts could be used in cellulose waste minimization and this chapter describes their characteristics and potential in bioconversion and bioremediation processes.« less

Hazardous Waste Minimization Assessment: Fort Campbell, Kentucky

DTIC Science & Technology

1991-03-01

Used Oii - Better Operating Practices . Selective Segregation 97 Used Oil - Process Change - Fast Lube Oil Change System (FLOCS) 98 Caustic Wastes...Product Substitution 98 Caustic Wastes - Process Change - Hot Tank (Equipment) Modifications 98 Aqueous or Caustic Wastes - Process Change - Dry Ovens...Aqueous or Caustic Wastes - Equipment Leasiag 102 Dirty Rags/Uniforms • Onsite/Offsite Recycling - Laundry Service 103 Treatment 103 Used Oil - Onsite

Characterization of screenings from three municipal wastewater treatment plants in the Region Rhône-Alpes.

PubMed

Le Hyaric, R; Canler, J-P; Barillon, B; Naquin, P; Gourdon, R

2009-01-01

The objective of this study was to analyze the composition of the screenings sampled from three municipal wastewater treatment plants (wwtp) located in the Region Rhône-Alpes, France. The plants were equipped with multi screening stages with gap sizes ranging from 60 to 3 mm. Waste production flows from each plant were monitored over at least 48 hours in each sampling campaign in order to calculate average production rates. Waste samples of at least 7 kg were collected from each screening stage in each plant at different seasons to evaluate the influence of different parameters on the composition of the waste. An overall 30 samples were thereby collected between May 2007 and February 2008, dried at 80 degrees C for a week, and subsequently hand sorted into 10 fractions of waste materials. Results showed that the average production varied between 0.53 and 3.49 kg (wet mass) per capita per year. The highest production rates were observed during or immediately after rainy weather conditions. The dry matter content ranged between 14.4 and 29.2% of wet mass, and the volatile matter content was between 70.0 and 90.5% of dry mass. The predominant materials in the screenings were found to be sanitary textiles which accounted for 65.2% to 73.6% of dry weight and fines (<20 mm) which accounted for 15.2% to 18.2% of dry weight. These proportions were relatively similar in each plant and each sampling campaign.

Impact of different particle size distributions on anaerobic digestion of the organic fraction of municipal solid waste.

PubMed

Zhang, Y; Banks, C J

2013-02-01

Particle size may significantly affect the speed and stability of anaerobic digestion, and matching the choice of particle size reduction equipment to digester type can thus determine the success or failure of the process. In the current research the organic fraction of municipal solid waste was processed using a combination of a shear shredder, rotary cutter and wet macerator to produce streams with different particle size distributions. The pre-processed waste was used in trials in semi-continuous 'wet' and 'dry' digesters at organic loading rate (OLR) up to 6kg volatile solids (VS) m(-3)day(-1). The results indicated that while difference in the particle size distribution did not change the specific biogas yield, the digester performance was affected. In the 'dry' digesters the finer particle size led to acidification and ultimately to process failure at the highest OLR. In 'wet' digestion a fine particle size led to severe foaming and the process could not be operated above 5kgVSm(-3)day(-1). Although the trial was not designed as a direct comparison between 'wet' and 'dry' digestion, the specific biogas yield of the 'dry' digesters was 90% of that produced by 'wet' digesters fed on the same waste at the same OLR. Copyright © 2012 Elsevier Ltd. All rights reserved.

Dry ice blasting

NASA Astrophysics Data System (ADS)

Lonergan, Jeffrey M.

1992-04-01

As legal and societal pressures against the use of hazardous waste generating materials has increased, so has the motivation to find safe, effective, and permanent replacements. Dry ice blasting is a technology which uses CO2 pellets as a blasting medium. The use of CO2 for cleaning and stripping operations offers potential for significant environmental, safety, and productivity improvements over grit blasting, plastic media blasting, and chemical solvent cleaning. Because CO2 pellets break up and sublime upon impact, there is no expended media to dispose of. Unlike grit or plastic media blasting which produce large quantities of expended media, the only waste produced by CO2 blasting is the material removed. The quantity of hazardous waste produced, and thus the cost of hazardous waste disposal is significantly reduced.

Predicting the toxicity of sediment-associated trace metals with simultaneously extracted trace metal: Acid-volatile sulfide concentrations and dry weight-normalized concentrations: A critical comparison

USGS Publications Warehouse

Long, E.R.; MacDonald, D.D.; Cubbage, J.C.; Ingersoll, C.G.

1998-01-01

The relative abilities of sediment concentrations of simultaneously extracted trace metal: acid-volatile sulfide (SEM: AVS) and dry weight-normalized trace metals to correctly predict both toxicity and nontoxicity were compared by analysis of 77 field-collected samples. Relative to the SEM:AVS concentrations, sediment guidelines based upon dry weight-normalized concentrations were equally or slightly more accurate in predicting both nontoxic and toxic results in laboratory tests.

Assessment of Cr and Ni phytotoxicity from cutlery-washing waste-waters using biomass and chlorophyll production tests on mustard Sinapis alba L. seedlings.

PubMed

Fargasová, Agáta; Molnárová, Marianna

2010-01-01

The aim of this work was to determine phytotoxicity of washing waste-waters from a cutlery production line with high content of Cr and Ni. These waters were previously classified, without verification, as dangerous and it is now necessary to question the justice of the present classification under the new legislation for waste management (Waste Law No. 223/2001) in the Slovak Republic. Young seedling of the dicotyledon terrestrial plant mustard Sinapis alba L. were used for determination of the dry and fresh root and shoot biomass and photosynthetic pigment production. Observed parameters were evaluated in laboratory experiments with three types of washing waste-waters from a cutlery production line. All contamination of tested washing waste-waters came from heavy metals (Ni, Cr), non-polar extractable compounds (NEC; residues of oils and waxes from polishing of stainless steel cutlery) and detergents (used for cutlery degreasing). Photosynthetic pigments (chlorophyll a, b, and total carotenoids) were extracted in 96% ethanol and measured spectrophotometrically at 665, 649, and 470 nm. All phytotoxicity tests were carried out in triplicate, and they included a control in tap water. All tested washing waters reduced root dry mass, whereas the shoot dry mass was either unaffected or it increased. The tested washing waters' effect was stronger on fresh mass production than on dry mass production. This indicated problems in water reception and translocation. The adverse effect on photosynthetic pigments production increased only slowly with remaining washing waste-water concentration. Almost all Chl a/b ratios were the same as for the control and this indicated no significant differences in the reduction of either a or b chlorophylls. As opposed to chlorophylls, carotenoids content increased in the presence of tested washing waste-waters and equaled or exceeded their content in the control. As the ratio of Chl(a + b)/Car was lower than that for the control for almost all tested samples, a stronger reduction in chlorophylls than in carotenoids was confirmed. The phytotoxicity of waste-waters from cutlery production line washing reservoirs was evaluated and the effects on dry and fresh mass production and photosynthetic pigments amount was discussed as Cr and Ni toxicity. It is concluded from the present study that washing waste-waters from cutlery production line are quite toxic to plants, thus reducing biomass and photosynthetic pigment production and influencing water translocation through the plant. These determined adverse effects of washing waste-waters from this cutlery production line classified them as too dangerous to be spread on open-land soil. On the basis of this study, high toxicity of the presented waste-waters from metal surface-finishing as well as justness of their liquidation as hazardous wastes by legally assigned persons were recommended.

The Auburn Engineering Technical Assistance Program investigation of polyvinyl alcohol film developments pertaining to radioactive particle decontamination and industrial waste minimization

NASA Astrophysics Data System (ADS)

Mole, Tracey Lawrence

In this work, an effective and systematic model is devised to synthesize the optimal formulation for an explicit engineering application in the nuclear industry, i.e. radioactive decontamination and waste reduction. Identification of an optimal formulation that is suitable for the desired system requires integration of all the interlacing behaviors of the product constituents. This work is unique not only in product design, but also in these design techniques. The common practice of new product development is to design the optimized product for a particular industrial niche and then subsequent research for the production process is conducted, developed and optimized separately from the product formulation. In this proposed optimization design technique, the development process, disposal technique and product formulation is optimized simultaneously to improve production profit, product behavior and disposal emissions. This "cradle to grave" optimization approach allowed a complex product formulation development process to be drastically simplified. The utilization of these modeling techniques took an industrial idea to full scale testing and production in under 18 months by reducing the number of subsequent laboratory trials required to optimize the formula, production and waste treatment aspects of the product simultaneously. This particular development material involves the use of a polymer matrix that is applied to surfaces as part of a decontamination system. The polymer coating serves to initially "fix" the contaminants in place for detection and ultimate elimination. Upon mechanical entrapment and removal, the polymer coating containing the radioactive isotopes can be dissolved in a solvent processor, where separation of the radioactive metallic particles can take place. Ultimately, only the collection of divided solids should be disposed of as nuclear waste. This creates an attractive alternative to direct land filling or incineration. This philosophy also provides waste generators a way to significantly reduce waste and associated costs, and help meet regulatory, safety and environmental requirements. In order for the polymeric film exhibit the desired performance, a combination of discrete constraints must be fulfilled. These interacting characteristics include the choice of polymer used for construction, drying time, storage constraints, decontamination ability, removal behavior, application process, coating strength and dissolvability processes. Identification of an optimized formulation that is suitable for this entire decontamination system requires integration of all the interlacing characteristics of the coating composition that affect the film behavior. A novel systematic method for developing quantitative values for theses qualitative characteristics is being developed in order to simultaneously optimize the design formulation subject to the discrete product specifications. This synthesis procedure encompasses intrinsic characteristics vital to successful product development, which allows for implementation of the derived model optimizations to operate independent of the polymer film application. This contribution illustrates the optimized synthesis example by which a large range of polymeric compounds and mixtures can be completed. (Abstract shortened by UMI.)

Timing of Getter Material Addition in Cementitious Wasteforms

NASA Astrophysics Data System (ADS)

Lawter, A.; Qafoku, N. P.; Asmussen, M.; Neeway, J.; Smith, G. L.

2015-12-01

A cementitious waste form, Cast Stone, is being evaluated as a possible supplemental immobilization technology for the Hanford sites's low activity waste (LAW), which contains radioactive 99Tc and 129I, as part of the tank waste cleanup mission. Cast Stone is made of a dry blend 47% blast furnace slag, 45% fly ash, and 8% ordinary Portland cement, mixed with a low-activity waste (LAW). To improve the retention of Tc and/or I in Cast Stone, materials with a high affinity for Tc and/or I, termed "getters," can be added to provide a stable domain for the radionuclides of concern. Previous testing conducted with a variety of getters has identified Tin(II)-Apatite and Silver Exchanged Zeolite as promising candidates for Tc and I, respectively. Investigation into the sequence in which getters are added to Cast Stone was performed following two methods: 1) adding getters to the Cast Stone dry blend, and then mixing with liquid waste, and 2) adding getters to the liquid waste first, followed by addition of the Cast Stone dry blend. Cast Stone monolith samples were prepared with each method and leach tests, following EPA method 1315, were conducted in either distilled water or simulated vadose zone porewater for a period of up to 63 days. The leachate was analyzed for Tc, I, Na, NO3-, NO2- and Cr with ICP-MS, ICP-OES and ion chromatography and the results indicated that the Cast Stone with getter addition in the dry blend mix (method 1) has lower rates of Tc and I leaching. The mechanisms of radionuclide release from the Cast Stone were also investigated with a variety of solid phase characterization techniques of the monoliths before and after leaching, such as XRD, SEM/EDS, TEM/SAED and other spectroscopic techniques.

Life cycle assessment of biochar systems: estimating the energetic, economic, and climate change potential.

PubMed

Roberts, Kelli G; Gloy, Brent A; Joseph, Stephen; Scott, Norman R; Lehmann, Johannes

2010-01-15

Biomass pyrolysis with biochar returned to soil is a possible strategy for climate change mitigation and reducing fossil fuel consumption. Pyrolysis with biochar applied to soils results in four coproducts: long-term carbon (C) sequestration from stable C in the biochar, renewable energy generation, biochar as a soil amendment, and biomass waste management. Life cycle assessment was used to estimate the energy and climate change impacts and the economics of biochar systems. The feedstocks analyzed represent agricultural residues (corn stover), yard waste, and switchgrass energy crops. The net energy of the system is greatest with switchgrass (4899 MJ t(-1) dry feedstock). The net greenhouse gas (GHG) emissions for both stover and yard waste are negative, at -864 and -885 kg CO(2) equivalent (CO(2)e) emissions reductions per tonne dry feedstock, respectively. Of these total reductions, 62-66% are realized from C sequestration in the biochar. The switchgrass biochar-pyrolysis system can be a net GHG emitter (+36 kg CO(2)e t(-1) dry feedstock), depending on the accounting method for indirect land-use change impacts. The economic viability of the pyrolysis-biochar system is largely dependent on the costs of feedstock production, pyrolysis, and the value of C offsets. Biomass sources that have a need for waste management such as yard waste have the highest potential for economic profitability (+$69 t(-1) dry feedstock when CO(2)e emission reductions are valued at $80 t(-1) CO(2)e). The transportation distance for feedstock creates a significant hurdle to the economic profitability of biochar-pyrolysis systems. Biochar may at present only deliver climate change mitigation benefits and be financially viable as a distributed system using waste biomass.

Sewage sludge drying by energy recovery from OFMSW composting: Preliminary feasibility evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rada, Elena Cristina; Ragazzi, Marco; Villotti, Stefano

2014-05-01

Highlights: • The aim is to support the drying of sewage sludge, using a solar greenhouse. • The system allows the exploitation of heat available from OFMSW aerobic process. • Another aim is to face the problem of OFMSW treatment, in particular food waste. • Energy and mass balances are presented for a case study. - Abstract: In this paper an original energy recovery method from composting is analyzed. The integrated system exploits the heat available from the aerobic biochemical process in order to support the drying of sewage sludge, using a specific solar greenhouse. The aim is to tacklemore » the problem of organic waste treatment, with specific regard to food waste. This is done by optimizing the energy consumption of the aerobic process of composting, using the heat produced to solve a second important waste management problem such as the sewage waste treatment. Energy and mass balances are presented in a preliminary feasibility study. Referring to a composting plant with a capacity of 15,000 t/y of food waste, the estimation of the power from recovered heat for the entire plant resulted about 42 kW. The results demonstrated that the energy recoverable can cover part of the heat necessary for the treatment of sludge generated by the population served by the composting plant (in terms of food waste and green waste collection). The addition of a renewable source such as solar energy could cover the residual energy demand. The approach is presented in detail in order for it to be replicated in other case studies or at full scale applications.« less

Method for solidification of radioactive and other hazardous waste

DOEpatents

Anshits, Alexander G.; Vereshchagina, Tatiana A.; Voskresenskaya, Elena N.; Kostin, Eduard M.; Pavlov, Vyacheslav F.; Revenko, Yurii A.; Tretyakov, Alexander A.; Sharonova, Olga M.; Aloy, Albert S.; Sapozhnikova, Natalia V.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

2002-01-01

Solidification of liquid radioactive waste, and other hazardous wastes, is accomplished by the method of the invention by incorporating the waste into a porous glass crystalline molded block. The porous block is first loaded with the liquid waste and then dehydrated and exposed to thermal treatment at 50-1,000.degree. C. The porous glass crystalline molded block consists of glass crystalline hollow microspheres separated from fly ash (cenospheres), resulting from incineration of fossil plant coals. In a preferred embodiment, the porous glass crystalline blocks are formed from perforated cenospheres of grain size -400+50, wherein the selected cenospheres are consolidated into the porous molded block with a binder, such as liquid silicate glass. The porous blocks are then subjected to repeated cycles of saturating with liquid waste, and drying, and after the last cycle the blocks are subjected to calcination to transform the dried salts to more stable oxides. Radioactive liquid waste can be further stabilized in the porous blocks by coating the internal surface of the block with metal oxides prior to adding the liquid waste, and by coating the outside of the block with a low-melting glass or a ceramic after the waste is loaded into the block.

Reuse of waste iron as a partial replacement of sand in concrete.

PubMed

Ismail, Zainab Z; Al-Hashmi, Enas A

2008-11-01

One of the major environmental issues in Iraq is the large quantity of waste iron resulting from the industrial sector which is deposited in domestic waste and in landfills. A series of 109 experiments and 586 tests were carried out in this study to examine the feasibility of reusing this waste iron in concrete. Overall, 130 kg of waste iron were reused to partially replace sand at 10%, 15%, and 20% in a total of 1703 kg concrete mixtures. The tests performed to evaluate waste-iron concrete quality included slump, fresh density, dry density, compressive strength, and flexural strength tests: 115 cubes of concrete were molded for the compressive strength and dry density tests, and 87 prisms were cast for the flexural strength tests. This work applied 3, 7, 14, and 28 days curing ages for the concrete mixes. The results confirm that reuse of solid waste material offers an approach to solving the pollution problems that arise from an accumulation of waste in a production site; in the meantime modified properties are added to the concrete. The results show that the concrete mixes made with waste iron had higher compressive strengths and flexural strengths than the plain concrete mixes.

Dry anaerobic digestion of food waste and cardboard at different substrate loads, solid contents and co-digestion proportions.

PubMed

Capson-Tojo, Gabriel; Trably, Eric; Rouez, Maxime; Crest, Marion; Steyer, Jean-Philippe; Delgenès, Jean-Philippe; Escudié, Renaud

2017-06-01

The increasing food waste production calls for developing efficient technologies for its treatment. Anaerobic processes provide an effective waste valorization. The influence of the initial substrate load on the performance of batch dry anaerobic co-digestion reactors treating food waste and cardboard was investigated. The load was varied by modifying the substrate to inoculum ratio (S/X), the total solids content and the co-digestion proportions. The results showed that the S/X was a crucial parameter. Within the tested values (0.25, 1 and 4gVS·gVS -1 ), only the reactors working at 0.25 produced methane. Methanosarcina was the main archaea, indicating its importance for efficient methanogenesis. Acidogenic fermentation was predominant at higher S/X, producing hydrogen and other metabolites. Higher substrate conversions (≤48%) and hydrogen yields (≤62mL·gVS -1 ) were achieved at low loads. This study suggests that different value-added compounds can be produced in dry conditions, with the initial substrate load as easy-to-control operational parameter. Copyright © 2017 Elsevier Ltd. All rights reserved.

Comparison of alternative flue gas dry treatment technologies in waste-to-energy processes.

PubMed

Dal Pozzo, Alessandro; Antonioni, Giacomo; Guglielmi, Daniele; Stramigioli, Carlo; Cozzani, Valerio

2016-05-01

Acid gases such as HCl and SO2 are harmful both for human health and ecosystem integrity, hence their removal is a key step of the flue gas treatment of Waste-to-Energy (WtE) plants. Methods based on the injection of dry sorbents are among the Best Available Techniques for acid gas removal. In particular, systems based on double reaction and filtration stages represent nowadays an effective technology for emission control. The aim of the present study is the simulation of a reference two-stage (2S) dry treatment system performance and its comparison to three benchmarking alternatives based on single stage sodium bicarbonate injection. A modelling procedure was applied in order to identify the optimal operating configuration of the 2S system for different reference waste compositions, and to determine the total annual cost of operation. Taking into account both operating and capital costs, the 2S system appears the most cost-effective solution for medium to high chlorine content wastes. A Monte Carlo sensitivity analysis was carried out to assess the robustness of the results. Copyright © 2016. Published by Elsevier Ltd.

Bio-drying of municipal solid waste with high water content by aeration procedures regulation and inoculation.

PubMed

Zhang, Dong-Qing; He, Pin-Jing; Jin, Tai-Feng; Shao, Li-Ming

2008-12-01

To improve the water content reduction of municipal solid waste with high water content, the operations of supplementing a hydrolytic stage prior to aerobic degradation and inoculating the bio-drying products were conducted. A 'bio-drying index' was used to evaluate the bio-drying performance. For the aerobic processes, the inoculation accelerated organics degradation, enhanced the lignocelluloses degradation rate by 10.4%, and lowered water content by 7.0%. For the combined hydrolytic-aerobic processes, the inoculum addition had almost no positive effect on the bio-drying efficiency, but it enhanced the lignocelluloses degradation rate by 9.6% and strengthened the acidogenesis in the hydrolytic stage. Compared with the aerobic processes, the combined processes had a higher bio-drying index (4.20 for non-inoculated and 3.67 for the inoculated trials). Moreover, the lowest final water content occurred in the combined process without inoculation (50.5% decreased from an initial 72.0%).

Human life support during interplanetary travel and domicile. V - Mars expedition technology trade study for solid waste management

NASA Technical Reports Server (NTRS)

Ferrall, Joe; Rohatgi, Naresh K.; Seshan, P. K.

1992-01-01

A model has been developed for NASA to quantitatively compare and select life support systems and technology options. The model consists of a modular, top-down hierarchical breakdown of the life support system into subsystems, and further breakdown of subsystems into functional elements representing individual processing technologies. This paper includes the technology trades for a Mars mission, using solid waste treatment technologies to recover water from selected liquid and solid waste streams. Technologies include freeze drying, thermal drying, wet oxidation, combustion, and supercritical-water oxidation. The use of these technologies does not have any significant advantages with respect to weight; however, significant power penalties are incurred. A benefit is the ability to convert hazardous waste into a useful resource, namely water.

Environmental control and waste management system design concept

NASA Technical Reports Server (NTRS)

Gandy, A. R.

1974-01-01

Passive device contains both solid and liquid animal waste matter for extended period without being cleaned and without contaminating animal. Constant airflow dries solid waste and evaporates liquid matter. Technique will maintain controlled atmospheric conditions and cage cleanliness during periods of 6 months to 1 year.

The effect of drying and size reduction pretreatments on recovery of inorganic crop nutrients from inedible wheat residues

NASA Technical Reports Server (NTRS)

Strayer, R. F.; Alazraki, M. P.; Judkins, J.

2003-01-01

Inorganic nutrients can be easily recovered from ALS crop residue solid wastes by aqueous leaching. However, oven drying and milling pretreatment of these residues has been frequently required to accommodate crop scientists and facility storage limitations. As part of a research study that will compare three different bioreactor technologies for processing these wastes, we realized that different drying and size-reduction pretreatments had been utilized for each technology. This paper compares the effects of residue pretreatment on recovery of nutrients by leaching. Pretreatments included three drying methods [fresh, oven-dried (70 degrees C overnight), and freeze-dried] and two size reduction methods [chopped (2 cm length) and milled (2 mm diameter)]. Determination of mass balances (dry weight and ash content of solids) before and after leaching indicated solubilization was least for fresh residues (23% dry weight loss and 50% for ash loss), and most for freeze-dried residues (41-47% dry weight loss and nearly 100% for ash loss). Mineral recovery of major elements (NO3, PO4, K, Ca, and Mg) in leachates was poorest for fresh residues. P and K recovery in leachates were best for oven-dried residues and Ca, Mg, and N recovery best for freeze-dried residues. The differences in recovery for N, P, and K in leachates were minimal between chopping and milling and slightly better for Ca and Mg from milled residues.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This volume contains the interim change notice for the safety operation procedure for hot cell. It covers the master-slave manipulators, dry waste removal, cell transfers, hoists, cask handling, liquid waste system, and physical characterization of fluids.

Simultaneous saccharification and fermentation of acid-pretreated rapeseed meal for succinic acid production using Actinobacillus succinogenes.

PubMed

Chen, Kequan; Zhang, Han; Miao, Yelian; Wei, Ping; Chen, Jieyu

2011-04-07

Rapeseed meal was evaluated for succinic acid production by simultaneous saccharification and fermentation using Actinobacillus succinogenes ATCC 55618. Diluted sulfuric acid pretreatment and subsequent hydrolysis with pectinase was used to release sugars from rapeseed meal. The effects of culture pH, pectinase loading and yeast extract concentration on succinic acid production were investigated. When simultaneous saccharification and fermentation of diluted acid pretreated rapeseed meal with a dry matter content of 12.5% (w/v) was performed at pH 6.4 and a pectinase loading of 2% (w/w, on dry matter) without supplementation of yeast extract, a succinic acid concentration of 15.5 g/L was obtained at a yield of 12.4 g/100g dry matter. Fed-batch simultaneous saccharification and fermentation was carried out with supplementation of concentrated pretreated rapeseed meal and pectinase at 18 and 28 h to yield a final dry matter content of 20.5% and pectinase loading of 2%, with the succinic acid concentration enhanced to 23.4 g/L at a yield of 11.5 g/100g dry matter and a productivity of 0.33 g/(Lh). This study suggests that rapeseed meal may be an alternative substrate for the efficient production of succinic acid by A. succinogenes without requiring nitrogen source supplementation. Copyright © 2011 Elsevier Inc. All rights reserved.

Goodbye, Waste! What We Make. Science and Technology Education in Philippine Society.

ERIC Educational Resources Information Center

Philippines Univ., Quezon City. Science Education Center.

This module: (1) discusses the need for disposing of waste safely; (2) provides information and activities on wet and dry wastes; and (3) shows how to prepare, maintain, and study a fertilizer basket (in which fertilizer is made from wet waste). Information on the biology of the basket (including role of bacteria and fungi in the decay process) is…

Cleanup Verification Package for the 618-2 Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

W. S. Thompson

2006-12-28

This cleanup verification package documents completion of remedial action for the 618-2 Burial Ground, also referred to as Solid Waste Burial Ground No. 2; Burial Ground No. 2; 318-2; and Dry Waste Burial Site No. 2. This waste site was used primarily for the disposal of contaminated equipment, materials and laboratory waste from the 300 Area Facilities.

On-site production of crude glucoamylase for kitchen waste hydrolysis.

PubMed

Wang, Xiao Qiang; Wang, Qun Hui; Liu, Ying Ying; Ma, Hong Zhi

2010-06-01

Kitchen waste from dining rooms accounts for a considerable proportion of municipal solid garbage, and economical recycle ways are needed to be developed. This study investigated glucoamylase production from kitchen waste and the feasibility of kitchen waste hydrolysis by the crude enzymes produced. The key problems of high water content and poor porosity in kitchen waste for glucoamylase production under solid-state fermentation could be solved readily by the addition of corn stover or paddy husk. As a support medium, corn stover was better than paddy husk. Smashed kitchen waste (sKW) mixed with corn stover in the ratio of 3.75 : 1 (dry basis) produced 1838 U g(-1) of glucoamylase by Aspergillus niger UV-60 within 96 h. The enzyme productivity from kitchen waste was over two-fold higher than that from wheat bran with additional nutrients. Without any recovery treatment, the produced glucoamylase could be used directly to hydrolyse sKW slurry. The optimum enzyme dose 8% (crude enzyme/kichen waste, w/w) was not too big, and was sufficient to hydrolyse 10% (dry basis) sKW slurry to produce a maximum amount of reducing sugar of 55.4 g L(-1).

75 FR 27842 - Request for a License to Export Radioactive Waste

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-18

... NUCLEAR REGULATORY COMMISSION Request for a License to Export Radioactive Waste Pursuant to 10 CFR... Duratek Services, Inc. (a Class A Approximately 680 Storage or Canada. subsidiary of radioactive pounds (53 cubic disposal by the EnergySolutions), April 19, waste in the feet) of dry original 2010, April...

Development of a microwave clothes dryer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kesselring, J.P.; Smith, R.D.

1996-01-01

A laboratory test model of a microwave clothes dryer was constructed and tested over a wide range of test variables, including number of magnetrons and use of auxiliary heat. The tests identified three distinct operating modes: cool drying, which uses only microwave energy and drying occurs at less than 105 F; fast drying, where microwave drying is superimposed on conventional drying; and efficient drying, where the use of microwave energy with waste heat recovery from the power supply results in significant efficiency improvements compared to conventional dryers.

Utilization of household food waste for the production of ethanol at high dry material content.

PubMed

Matsakas, Leonidas; Kekos, Dimitris; Loizidou, Maria; Christakopoulos, Paul

2014-01-08

Environmental issues and shortage of fossil fuels have turned the public interest to the utilization of renewable, environmentally friendly fuels, such as ethanol. In order to minimize the competition between fuels and food production, researchers are focusing their efforts to the utilization of wastes and by-products as raw materials for the production of ethanol. household food wastes are being produced in great quantities in European Union and their handling can be a challenge. Moreover, their disposal can cause severe environmental issues (for example emission of greenhouse gasses). On the other hand, they contain significant amounts of sugars (both soluble and insoluble) and they can be used as raw material for the production of ethanol. Household food wastes were utilized as raw material for the production of ethanol at high dry material consistencies. A distinct liquefaction/saccharification step has been included to the process, which rapidly reduced the viscosity of the high solid content substrate, resulting in better mixing of the fermenting microorganism. This step had a positive effect in both ethanol production and productivity, leading to a significant increase in both values, which was up to 40.81% and 4.46 fold, respectively. Remaining solids (residue) after fermentation at 45% w/v dry material (which contained also the unhydrolyzed fraction of cellulose), were subjected to a hydrothermal pretreatment in order to be utilized as raw material for a subsequent ethanol fermentation. This led to an increase of 13.16% in the ethanol production levels achieving a final ethanol yield of 107.58 g/kg dry material. In conclusion, the ability of utilizing household food waste for the production of ethanol at elevated dry material content has been demonstrated. A separate liquefaction/saccharification process can increase both ethanol production and productivity. Finally, subsequent fermentation of the remaining solids could lead to an increase of the overall ethanol production yield.

Utilization of household food waste for the production of ethanol at high dry material content

PubMed Central

2014-01-01

Background Environmental issues and shortage of fossil fuels have turned the public interest to the utilization of renewable, environmentally friendly fuels, such as ethanol. In order to minimize the competition between fuels and food production, researchers are focusing their efforts to the utilization of wastes and by-products as raw materials for the production of ethanol. household food wastes are being produced in great quantities in European Union and their handling can be a challenge. Moreover, their disposal can cause severe environmental issues (for example emission of greenhouse gasses). On the other hand, they contain significant amounts of sugars (both soluble and insoluble) and they can be used as raw material for the production of ethanol. Results Household food wastes were utilized as raw material for the production of ethanol at high dry material consistencies. A distinct liquefaction/saccharification step has been included to the process, which rapidly reduced the viscosity of the high solid content substrate, resulting in better mixing of the fermenting microorganism. This step had a positive effect in both ethanol production and productivity, leading to a significant increase in both values, which was up to 40.81% and 4.46 fold, respectively. Remaining solids (residue) after fermentation at 45% w/v dry material (which contained also the unhydrolyzed fraction of cellulose), were subjected to a hydrothermal pretreatment in order to be utilized as raw material for a subsequent ethanol fermentation. This led to an increase of 13.16% in the ethanol production levels achieving a final ethanol yield of 107.58 g/kg dry material. Conclusions In conclusion, the ability of utilizing household food waste for the production of ethanol at elevated dry material content has been demonstrated. A separate liquefaction/saccharification process can increase both ethanol production and productivity. Finally, subsequent fermentation of the remaining solids could lead to an increase of the overall ethanol production yield. PMID:24401142

Precipitation-adsorption process for the decontamination of nuclear waste supernates

DOEpatents

Lee, Lien-Mow; Kilpatrick, Lester L.

1984-01-01

High-level nuclear waste supernate is decontaminated of cesium by precipitation of the cesium and potassium with sodium tetraphenyl boron. Simultaneously, strontium-90 is removed from the waste supernate sorption of insoluble sodium titanate. The waste solution is then filtered to separate the solution decontaminated of cesium and strontium.

Precipitation-adsorption process for the decontamination of nuclear waste supernates

DOEpatents

Lee, L.M.; Kilpatrick, L.L.

1982-05-19

High-level nuclear waste supernate is decontaminated of cesium by precipitation of the cesium and potassium with sodium tetraphenyl boron. Simultaneously, strontium-90 is removed from the waste supernate sorption of insoluble sodium titanate. The waste solution is then filtered to separate the solution decontaminated of cesium and strontium.

Method of preparing nuclear wastes for tansportation and interim storage

DOEpatents

Bandyopadhyay, Gautam; Galvin, Thomas M.

1984-01-01

Nuclear waste is formed into a substantially water-insoluble solid for temporary storage and transportation by mixing the calcined waste with at least 10 weight percent powdered anhydrous sodium silicate to form a mixture and subjecting the mixture to a high humidity environment for a period of time sufficient to form cementitious bonds by chemical reaction. The method is suitable for preparing an interim waste form from dried high level radioactive wastes.

Influence of tropical seasonal variations on landfill leachate characteristics--results from lysimeter studies.

PubMed

Tränkler, J; Visvanathan, C; Kuruparan, P; Tubtimthai, O

2005-01-01

Considering the quality of design and construction of landfills in developing countries, little information can be derived from randomly taken leachate samples. Leachate generation and composition under monsoon conditions have been studied using lysimeters to simulate sanitary landfills and open cell settings. In this study, lysimeters were filled with domestic waste, highly organic market waste and pre-treated waste. Results over two subsequent dry and rainy seasons indicate that the open cell lysimeter simulation showed the highest leachate generation throughout the rainy season, with leachate flow in all lysimeters coming to a halt during the dry periods. More than 60% of the precipitation was found in the form of leachate. The specific COD and TKN load discharged from the open cell was 20% and 180% more than that of the sanitary landfill lysimeters. Types of waste material and kind of pre-treatment prior to landfilling strongly influenced the pollutant load. Compared to the sanitary landfill lysimeter filled with domestic waste, the specific COD and TKN load discharged from the pre-treated waste lysimeter accounted for only 4% and 16%, respectively. Considering the local settings of tropical landfills, these results suggest that landfill design and operation has to be adjusted. Leachate can be collected and stored during the rainy season, and recirculation of leachate is recommended to maintain a steady and even accelerated degradation during the prolonged dry season. The open cell approach in combination with leachate recirculation is suggested as an option for interim landfill operations.

Lyophilization -Solid Waste Treatment

NASA Technical Reports Server (NTRS)

Litwiller, Eric; Flynn, Michael; Fisher, John; Reinhard, Martin

2004-01-01

This paper discusses the development of a solid waste treatment system that has been designed for a Mars transit exploration mission. The technology described is an energy-efficient lyophilization technique that is designed to recover water from spacecraft solid wastes. Candidate wastes include feces, concentrated brines from water processors, and other solid wastes that contain free water. The system is designed to operate as a stand-alone process or to be integrated into the International Space Station Waste Collection System. In the lyophilization process, water in an aqueous waste is frozen and then sublimed, separating the waste into a dried solid material and liquid water. The sublimed water is then condensed in a solid ice phase and then melted to generate a liquid product. In the subject system the waste solids are contained within a 0.2 micron bio-guard bag and after drying are removed from the system and stored in a secondary container. This technology is ideally suited to applications such as the Mars Reference Mission, where water recovery rates approaching 100% are desirable but production of CO2 is not. The system is designed to minimize power consumption through the use of thermoelectric heat pumps. The results of preliminary testing of a prototype system and testing of the final configuration are provided. A mathematical model of the system is also described.

Biodegradation and flushing of MBT wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siddiqui, A.A., E-mail: aasiddiqui.cv@amu.ac.in; Richards, D.J.; Powrie, W.

Highlights: • Stabilization was achieved for MBT wastes of different degrees of pretreatment. • About 92% reduction in the gas generation compared with raw MSW. • Pretreatment resulted in reduced TOC, nitrogen and heavy metals in leachate. • A large proportion of carbon and nitrogen remained in the waste material. - Abstract: Mechanical–biological treatment (MBT) processes are increasingly being adopted as a means of diverting biodegradable municipal waste (BMW) from landfill, for example to comply with the EU Landfill Directive. However, there is considerable uncertainty concerning the residual pollution potential of such wastes. This paper presents the results of laboratorymore » experiments on two different MBT waste residues, carried out to investigate the remaining potential for the generation of greenhouse gases and the flushing of contaminants from these materials when landfilled. The potential for gas generation was found to be between 8% and 20% of that for raw MSW. Pretreatment of the waste reduced the potential for the release of organic carbon, ammoniacal nitrogen, and heavy metal contents into the leachate; and reduced the residual carbon remaining in the waste after final degradation from ∼320 g/kg dry matter for raw MSW to between 183 and 195 g/kg dry matter for the MBT wastes.« less

USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edward Levy; Harun Bilirgen; Ursla Levy

2006-01-01

This is the twelfth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report and results are shown for a drying system utilizing a combination of waste heat from the condenser and thermal energymore » extracted from boiler flue gas.« less

On thermohydrologic conditions near high-level nuclear wastes emplaced in partially saturated fractured tuff: 1. Simulation studies with explicit consideration of fracture effects

NASA Astrophysics Data System (ADS)

Pruess, K.; Wang, J. S. Y.; Tsang, Y. W.

1990-06-01

We have performed modeling studies on the simultaneous transport of heat, liquid water, vapor, and air in partially saturated, fractured porous rock. Formation parameters were chosen as representative of the potential nuclear waste repository site in the Topopah Spring unit of the Yucca Mountain tuffs. The presence of fractures makes the transport problem very complex, both in terms of flow geometry and physics. The numerical simulator used for our flow calculations takes into account most of the physical effects believed to be important in multiphase fluid and heat flow. It has provisions for handling the extreme nonlinearities that arise in phase transitions, component disappearances, and capillary discontinuities at fracture faces. We model a region around an infinite linear string of nuclear waste canisters, taking into account both the discrete fractures and the porous matrix. Thermohydrologic conditions in the vicinity of the waste packages are found to depend strongly on relative permeability and capillary pressure characteristics of the fractures, which are unknown at the present time. If liquid held on the rough walls of drained fractures is assumed to be mobile, strong heat pipe effects are predicted. Under these conditions the host rock will remain in two-phase conditions right up to the emplacement hole, and formation temperatures will peak near 100°C. If it is assumed that liquid cannot move along drained fractures, the region surrounding the waste packages is predicted to dry up, and formation temperatures will rise beyond 200°C. A substantial fraction of waste heat can be removed if emplacement holes are left open and ventilated, as opposed to backfilled and sealed emplacement conditions. Comparing our model predictions with observations from in situ heater experiments reported by Zimmerman and coworkers, some intriguing similarities are noted. However, for a quantitative evaluation, additional carefully controlled laboratory and field experiments will be needed.

Chlorinated and parent polycyclic aromatic hydrocarbons in environmental samples from an electronic waste recycling facility and a chemical industrial complex in China.

PubMed

Ma, Jing; Horii, Yuichi; Cheng, Jinping; Wang, Wenhua; Wu, Qian; Ohura, Takeshi; Kannan, Kurunthachalam

2009-02-01

Chlorinated polycyclic aromatic hydrocarbons (CIPAHs) are a class of halogenated contaminants found in the urban atmosphere; they have toxic potential similar to that of dioxins. Information on the sources of CIPAHs is limited. In this study, concentrations of 20 CIPAHs and 16 parent PAHs were measured in electronic wastes, workshop-floor dust, vegetation, and surface soil collected from the vicinity of an electronic waste (e-waste) recycling facility and in surface soil from a chemical industrial complex (comprising a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant), and agricultural areas in central and eastern China. High concentrations of SigmaCIPAHs were found in floor dust (mean, 103 ng/g dry wt), followed in order of decreasing concentration by leaves (87.5 ng/g drywt), electronic shredder waste (59.1 ng/g dry wt), and soil (26.8 ng/g dry wt) from an e-waste recycling facility in Taizhou. The mean concentration of SigmaCIPAHs in soil from the chemical industrial complex (88 ng/g dry wt) was approximately 3-fold higher than the concentration in soil from e-waste recycling facilities. The soils from e-waste sites and industrial areas contained mean concentrations of SigmaCIPAHs 2 to 3 orders of magnitude higher than the concentrations in agricultural soils (ND-0.76 ng/g), suggesting that e-waste recycling and chlorine-chemical industries are potential emission sources of CIPAHs. The profiles of CIPAHs in soil and dust were similar to a profile that has been reported previously for fly ash from municipal solid waste incinerators (6-CIBaP was the predominant compound), but the profiles in vegetation and electronic shredder waste were different from those found in fly ash. Concentrations of 16 parent PAHs were high (150-49,700 ng/g) in samples collected from the e-waste recycling facility. Significant correlation between SigmaCIPAH and SigmaPAH concentrations suggests that direct chlorination of parent PAHs is the major pathway of formation of CIPAHs during e-waste recycling operations. Dioxin-like toxic equivalency quotients (TEQs) for CIPAHs and PAHs in samples were calculated on the basis of relative potencies reported for CIPAHs and PAHs. The highest mean TEQ concentrations of CIPAHs (518 pg-TEQ/g) were found for workshop-floor dust, followed by leaves (361 pg-TEQ/g), electronic shredder waste (308 pg-TEQ/g), soil from the chemical industrial complex (146 pg-TEQ/g), and soil from the sites of the e-waste recycling facility (92.3 pg-TEQ/g). With one exception, the floor dust samples, the TEQ concentrations of CIPAHs found in multiple environmental matrices in this study were higher than the TEQ concentrations of PCDD/Fs in the same samples reported in our earlier study.

Comparison of mass balance, energy consumption and cost of composting facilities for different types of organic waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Huijun; Matsuto, Toshihiko, E-mail: matsuto@eng.hokudai.ac.jp

2011-03-15

Mass balance, energy consumption and cost are basic pieces of information necessary for selecting a waste management technology. In this study, composting facilities that treat different types of organic waste were studied by questionnaire survey and via a chemical analysis of material collected at the facilities. The mass balance was calculated on a dry weight basis because the moisture content of organic waste was very high. Even though the ratio of bulking material to total input varied in the range 0-65% on a dry basis, the carbon and ash content, carbon/nitrogen ratio, heavy metal content and inorganic nutrients in themore » compost were clearly influenced by the different characteristics of the input waste. The use of bulking material was not correlated with ash or elemental content in the compost. The operating costs were categorised into two groups. There was some economy of scale for wages and maintenance cost, but the costs for electricity and fuel were proportional to the amount of waste. Differences in operating costs can be explained by differences in the process characteristics.« less

Ethanol production from food waste at high solids content with vacuum recovery technology.

PubMed

Huang, Haibo; Qureshi, Nasib; Chen, Ming-Hsu; Liu, Wei; Singh, Vijay

2015-03-18

Ethanol production from food wastes does not only solve environmental issues but also provides renewable biofuels. This study investigated the feasibility of producing ethanol from food wastes at high solids content (35%, w/w). A vacuum recovery system was developed and applied to remove ethanol from fermentation broth to reduce yeast ethanol inhibition. A high concentration of ethanol (144 g/L) was produced by the conventional fermentation of food waste without a vacuum recovery system. When the vacuum recovery is applied to the fermentation process, the ethanol concentration in the fermentation broth was controlled below 100 g/L, thus reducing yeast ethanol inhibition. At the end of the conventional fermentation, the residual glucose in the fermentation broth was 5.7 g/L, indicating incomplete utilization of glucose, while the vacuum fermentation allowed for complete utilization of glucose. The ethanol yield for the vacuum fermentation was found to be 358 g/kg of food waste (dry basis), higher than that for the conventional fermentation at 327 g/kg of food waste (dry basis).

Reuse of Boron Waste as an Additive in Road Base Material

PubMed Central

Zhang, Yutong; Guo, Qinglin; Li, Lili; Jiang, Ping; Jiao, Yubo; Cheng, Yongchun

2016-01-01

The amount of boron waste increases year by year. There is an urgent demand to manage it in order to reduce the environmental impact. In this paper, boron waste was reused as an additive in road base material. Lime and cement were employed to stabilize the waste mixture. Mechanical performances of stabilized mixture were evaluated by experimental methods. A compaction test, an unconfined compressive test, an indirect tensile test, a modulus test, a drying shrinkage test, and a frost resistance test were carried out. Results indicated that mechanical strengths of lime-stabilized boron waste mixture (LSB) satisfy the requirements of road base when lime content is greater than 8%. LSB can only be applied in non-frozen regions as a result of its poor frost resistance. The lime–cement-stabilized mixture can be used in frozen regions when lime and cement contents are 8% and 5%, respectively. Aggregate reduces the drying shrinkage coefficient effectively. Thus, aggregate is suggested for mixture stabilization properly. This work provides a proposal for the management of boron waste. PMID:28773539

Rapid measurement of the yield stress of anaerobically-digested solid waste using slump tests.

PubMed

Garcia-Bernet, D; Loisel, D; Guizard, G; Buffière, P; Steyer, J P; Escudié, R

2011-04-01

The anaerobic digestion of solid waste is usually performed using dry or semi-dry technology. Incoming waste and fermenting digestate are pasty media and thus, at the industrial scale, their suitability for pumping and mixing is a prerequisite at the industrial scale. However, their rheology has been poorly characterised in the literature because there is no suitable experimental system for analysing heterogeneous media composed of coarse particles. We have developed a practical rheometrical test, a "slump test", for the analysis of actual digested solid waste. It makes it possible to estimate yield stress from the final slump height. From the slump behavior, we conclude that digestates behave as visco-elastic materials. The yield stress of different digested waste was measured between 200 and 800Pa. We show that the media containing smaller particles or with higher moisture content are characterised by smaller yield stresses. This study thus demonstrates the impact of the origin of the digestate on the yield stress. Copyright © 2010 Elsevier Ltd. All rights reserved.

Cardboard proportions and total solids contents as driving factors in dry co-fermentation of food waste.

PubMed

Capson-Tojo, Gabriel; Trably, Eric; Rouez, Maxime; Crest, Marion; Bernet, Nicolas; Steyer, Jean-Philippe; Delgenès, Jean-Philippe; Escudié, Renaud

2018-01-01

This study evaluated the influence of the co-substrate proportions (0-60% of cardboard in dry basis) and the initial total solid contents (20-40%) on the batch fermentation performance. Maximum hydrogen yields were obtained when mono-fermenting food waste at high solids contents (89mlH 2 ·gVS -1 ). The hydrogen yields were lower when increasing the proportions of cardboard. The lower hydrogen yields at higher proportions of cardboard were translated into higher yields of caproic acid (up to 70.1gCOD·kgCOD bio -1 ), produced by consumption of acetic acid and hydrogen. The highest substrate conversions were achieved at low proportions of cardboard, indicating a stabilization effect due to higher buffering capacities in co-fermentation. Clostridiales were predominant in all operational conditions. This study opens up new possibilities for using the cardboard proportions for controlling the production of high added-value products in dry co-fermentation of food waste. Copyright © 2017 Elsevier Ltd. All rights reserved.

Dewatering Treatment Scale-up Testing Results of Hanford Tank Wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tedeschi, A.R.; May, T.H.; Bryan, W.E.

2008-07-01

This report documents CH2M HILL Hanford Group Inc. (CH2M HILL) 2007 dryer testing results in Richland, WA at the AMEC Nuclear Ltd., GeoMelt Division (AMEC) Horn Rapids Test Site. It provides a discussion of scope and results to qualify the dryer system as a viable unit-operation in the continuing evaluation of the bulk vitrification process. A 10,000 liter (L) dryer/mixer was tested for supplemental treatment of Hanford tank low activity wastes, drying and mixing a simulated non-radioactive salt solution with glass forming minerals. Testing validated the full scale equipment for producing dried product similar to smaller scale tests, and qualifiedmore » the dryer system for a subsequent integrated dryer/vitrification test using the same simulant and glass formers. The dryer system is planned for installation at the Hanford tank farms to dry/mix radioactive waste for final treatment evaluation of the supplemental bulk vitrification process. (authors)« less

Freeze Drying of Fruits and Vegetables: A Laboratory Experiment.

ERIC Educational Resources Information Center

Noble, Richard D.

1979-01-01

Describes a laboratory experiment for freeze-drying fruits and vegetables which aims to expose college students to the principles of drying and simultaneous heat and mass transfer. The experimental apparatus, procedure of the experiment, and data analysis are also included. (HM)

Emission of volatile sulfur compounds during composting of municipal solid waste (MSW)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Hongyu; College of Resources and Environment Sciences, China Agricultural University, Beijing 100094; Schuchardt, Frank

2013-04-15

Highlights: ► We compare the volatile sulfur compounds (VSCs) emissions during three types of municipal solid wastes (MSWs) composting. ► The VSCs released from the kitchen waste composting was significantly higher than that from 15–80 mm fraction of MSW. ► Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. ► Addition of 20% cornstalks could significantly reduce the VSCs emissions during kitchen waste composting. - Abstract: Volatile sulfur compounds (VSCs) are the main source for malodor from composting plants. In this study, the VSCs generated from composting of 15–80 mm municipal solidmore » waste (T0), kitchen waste (T1) and kitchen waste mixed dry cornstalks (T2) were measured in 60 L reactors with forced aeration for a period of 30 days. The VSCs detected in all treatments were hydrogen sulfide (H{sub 2}S), methyl mercaptan (MM), dimethyl sulfide (DMS), carbon bisulfide (CS{sub 2}) and dimethyl disulfide (DMDS). Over 90% of the VSCs emissions occurred during the first 15 days, and reached their peak values at days 4–7. The emission profiles of five VSCs species were significantly correlated with internal materials temperature and outlet O{sub 2} concentration (p < 0.05). Total emissions of the VSCs were 216.1, 379.3 and 126.0 mg kg{sup −1} (dry matter) for T0, T1 and T2, respectively. Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. Composting of kitchen waste from separate collection posed a negative influence on the VSC and leachate production because of its high moisture content. An addition of dry cornstalks at a mixing ratio of 4:1 (wet weight) could significantly reduce the VSCs emissions and avoid leachate. Compared to pure kitchen waste, VSCs were reduced 66.8%.« less

Kinetic study of dry anaerobic co-digestion of food waste and cardboard for methane production.

PubMed

Capson-Tojo, Gabriel; Rouez, Maxime; Crest, Marion; Trably, Eric; Steyer, Jean-Philippe; Bernet, Nicolas; Delgenès, Jean-Philippe; Escudié, Renaud

2017-11-01

Dry anaerobic digestion is a promising option for food waste treatment and valorization. However, accumulation of ammonia and volatile fatty acids often occurs, leading to inefficient processes and digestion failure. Co-digestion with cardboard may be a solution to overcome this problem. The effect of the initial substrate to inoculum ratio (0.25 to 1gVS·gVS -1 ) and the initial total solids contents (20-30%) on the kinetics and performance of dry food waste mono-digestion and co-digestion with cardboard was investigated in batch tests. All the conditions produced methane efficiently (71-93% of the biochemical methane potential). However, due to lack of methanogenic activity, volatile fatty acids accumulated at the beginning of the digestion and lag phases in the methane production were observed. At increasing substrate to inoculum ratios, the initial acid accumulation was more pronounced and lower cumulative methane yields were obtained. Higher amounts of soluble organic matter remained undegraded at higher substrate loads. Although causing slightly longer lag phases, high initial total solids contents did not jeopardize the methane yields. Cardboard addition reduced acid accumulation and the decline in the yields at increasing substrate loads. However, cardboard addition also caused higher concentrations of propionic acid, which appeared as the most last acid to be degraded. Nevertheless, dry co-digestion of food waste and cardboard in urban areas is demonstrated asan interesting feasible valorization option. Copyright © 2017 Elsevier Ltd. All rights reserved.

A sustainable approach towards rural development: dry toilets in Nepal.

PubMed

Regmi, M R

2005-01-01

Existing inadequate sewerage systems and direct disposal of household waste into water courses has tremendously increased water pollution. Dry toilets are feasible in rural and peri-urban areas to reduce the consumption of costlier water that is required for flushing. As conventional treatment technologies require high investment, and operation and maintenance costs, dry toilets are the only suitable option left for sanitation in the 21st century when working with limited financial resources. To reduce environmental degradation and overcome this problem, the dry toilet is only the realistic option in Nepal. Two reactors, one exposed to sunrays and the other without sunrays, were constructed. In the model with sunrays, it was found that in 48 days of observation faecal coliform presence depleted to 610 cells per gm from the initial value of 7 x 10(10) and volatile organic matter came down from 98.09% to 70.18%. Similarly, in the other model, the destruction of faecal coliform in 65 days was found to be 920 cells/gm while the destruction of organic matter took 75 days. Also, observing from 313 people in a cluster on the pilot project, the annually recovered value of N, P and K was found to be 1565 kg, 125 kg, 344 kg, respectively. This paper deals with the different types of dry ecological toilet, their performance and feasibility study in Nepal, with the full involvement of local people, based on complete laboratory analysis and regular monitoring. Using dry toilets will save 14 LPCD, which is equivalent to 14 MLD and the resulting demand will become only 80 MLD for the urban area of Kathmandu. The result advocates the implementation of ecological dry toilets to save valuable water wasted in flushing, as well as saving the resources needed to treat the waste.

Creating Methane from Plastics: Recycling at a Lunar Outpost

NASA Technical Reports Server (NTRS)

Captain, Janine; Santiago, Eddie; Wheeler, Ray; Strayer, RIchard; Garland, Jay; Parrish, Clyde

2010-01-01

The high cost of re-supply from Earth demands resources to be utilized to the fullest extent for exploration missions. Recycling is a key technology that maximizes the available resources by converting waste products into useful commodities. One example of this is to convert crew member waste such as plastic packaging, food scraps, and human waste, into fuel. The ability to refuel on the lunar surface would reduce the vehicle mass during launch and provide excess payload capability. The goal of this project is to determine the feasibility of recycling waste into methane on the lunar outpost by performing engineering assessments and lab demonstrations of the technology. The first goal of the project was to determine how recycling could influence lunar exploration. Table I shows an estimation of the typical dried waste stream generated each day for a crew of four. Packaging waste accounts for nearly 86% of the dry waste stream and is a significant source of carbon on the lunar surface. This is important because methane (CH4) can be used as fuel and no other source of carbon is available on the lunar surface. With the initial assessment indicating there is sufficient resources in the waste stream to provide refueling capabilities, the project was designed to examine the conversion of plastics into methane.

Concentrations, profiles, and estimated human exposures for polychlorinated dibenzo-p-dioxins and dibenzofurans from electronic waste recycling facilities and a chemical industrial complex in Eastern China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ma, J.; Kannan, K.; Cheng, J.

2008-11-15

Electronic shredder waste and dust from e-waste facilities, and leaves and surface soil collected in the vicinity of a large scale e-waste recycling facility in Taizhou, Eastern China, were analyzed for total dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) including 2,3,7,8-substituted congeners. We also determined PCDD/Fs in surface agricultural soils from several provinces in China for comparison with soils from e-waste facilities. Concentrations of total PCDD/Fs were high in all of the matrices analyzed and ranged from 30.9 to 11,400 pg/g for shredder waste, 3460 to 9820 pg/g dry weight for leaves, 2560 to 148,000 pg/g dry weight for workshop-floor dust, and 854more » to 10200 pg/g dry weight for soils. We also analyzed surface soils from a chemical industrial complex (a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) in Shanghai. Concentrations of total PCDD/Fs in surface soil from the chemical industrial complex were lower than the concentrations found in soils from e-waste recycling plants, but higher than the concentrations found in agricultural soils. Agricultural soils from six cities in China contained low levels of total PCDD/Fs. Profiles of dioxin toxic equivalents (TEQs) of 2,3,7,8-PCDD/Fs in soils from e-waste facilities in Taizhou differed from the profiles found in agricultural soils. The estimated daily intakes of TEQs of PCDD/Fs via soil/dust ingestion and dermal exposure were 2 orders of magnitude higher in people at e-waste recycling facilities than in people at the chemical industrial site, implying greater health risk for humans from dioxin exposures at e-waste recycling facilities. The calculated TEQ exposures for e-waste workers from dust and soil ingestion alone were 2-3 orders of magnitude greater than the exposures from soils in reference locations. 37 refs., 1 fig., 2 tabs.« less

Combustion quality analysis of briquettes from variety of agricultural waste as source of alternative fuels

NASA Astrophysics Data System (ADS)

Suryaningsih, S.; Nurhilal, O.; Yuliah, Y.; Mulyana, C.

2017-05-01

The increasing in world population and the industrial sector led to increased demand for energy sources. To do this by utilizing the agricultural waste as a fuel source of alternative energy in the form of bio briquette. The aim at this study was to obtain data onto the characteristics of a wide variety of biomass briquettes from waste agricultural industry. The basic ingredients used are biomass waste from coconut husks, sawdust, rice husks and coffee husks. Each of these biomass residues are dried, crushed, then mixed with starch adhesives. This mixture is molded and dried using sunlight. Each type of briquettes was characterized and analyzed the physical-chemical properties, including calorific value, water content, fixed carbon content and the results were compared with charcoal and coal that was used as fuel in public. The results showed that bio briquettes from coconut husks get the highest calorific value of 4,451 cal/g.

Alternative fuels for multiple-hearth furnaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bracken, B.D.; Lawson, T.U.

1980-04-01

A study of alternative procedures for reducing the consumption of No. 2 fuel oil at the Lower Molonglo Water Quality Control Centre near Canberra, Aust., indicated that in comparison with the present system of incineration with heat supplied by burning fuel oil, the installation of a sludge drying operation, consisting of a rotary dryer heated by furnace exhaust gases with the dried sludge used to fuel the furnace, would become economically desirable by 1985 if afterburning is not required, and would be justified immediately if afterburning is required to meet air pollution control regulations. The substitution of any of fourmore » waste fuels (refuse-derived fuel, waste paper, wood waste, or waste oil) or of coal for the No. 2 fuel oil would not be cost-effective through 1989. The furnace system, including afterburning and fuel oil requirements, the envisioned alternative fuel use systems, sludge processing alternatives, heat balance results, and economics are discussed.« less

40 CFR 63.1205 - What are the standards for hazardous waste burning lightweight aggregate kilns that are effective...

Code of Federal Regulations, 2012 CFR

2012-07-01

... rolling average, dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid... hydrochloric acid equivalents, dry basis and corrected to 7 percent oxygen; and (7) Particulate matter in... average, dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid and...

40 CFR 63.1205 - What are the standards for hazardous waste burning lightweight aggregate kilns that are effective...

Code of Federal Regulations, 2010 CFR

2010-07-01

... rolling average, dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid... hydrochloric acid equivalents, dry basis and corrected to 7 percent oxygen; and (7) Particulate matter in... average, dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid and...

40 CFR 63.1205 - What are the standards for hazardous waste burning lightweight aggregate kilns that are effective...

Code of Federal Regulations, 2011 CFR

2011-07-01

... rolling average, dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid... hydrochloric acid equivalents, dry basis and corrected to 7 percent oxygen; and (7) Particulate matter in... average, dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid and...

Investigating alternative solutions for adsorption-contact drying when burning vegetable wastes

NASA Astrophysics Data System (ADS)

Golubkovich, A. V.

2007-06-01

Results are presented from investigation of three alternative solutions for adsorption-contact drying: combined (with cooling by means of outdoor air), with afterburning of combustible matters, and with limited adsorption of moisture using solid products of fuel combustion. Mathematical models and simplified expressions for calculating the time taken for the fuel drying to proceed are proposed.

Letter Report: LAW Simulant Development for Cast Stone Screening Test

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Renee L.; Westsik, Joseph H.; Swanberg, David J.

2013-03-27

More than 56 million gallons of radioactive and hazardous waste are stored in 177 underground storage tanks at the U.S. Department of Energy’s (DOE’s) Hanford Site in southeastern Washington State. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the wastes and immobilize them in a glass waste form. The WTP includes a pretreatment facility to separate the wastes into a small volume of high-level waste (HLW) containing most of the radioactivity and a larger volume of low-activity waste (LAW) containing most of the nonradioactive chemicals. The HLW will be converted to glass in themore » HLW vitrification facility for ultimate disposal at an offsite federal repository. At least a portion (~35%) of the LAW will be converted to glass in the LAW vitrification facility and will be disposed of onsite at the Integrated Disposal Facility (IDF). The pretreatment and HLW vitrification facilities will have the capacity to treat and immobilize the wastes destined for each facility. However, a second facility will be needed for the expected volume of additional LAW requiring immobilization. A cementitious waste form known as Cast Stone is being considered to provide the required additional LAW immobilization capacity. The Cast Stone waste form must be acceptable for disposal in the IDF. The Cast Stone waste form and immobilization process must be tested to demonstrate that the final Cast Stone waste form can comply with waste acceptance criteria for the IDF disposal facility and that the immobilization processes can be controlled to consistently provide an acceptable waste form product. Further, the waste form must be tested to provide the technical basis for understanding the long term performance of the waste form in the IDF disposal environment. These waste form performance data are needed to support risk assessment and performance assessment (PA) analyses of the long-term environmental impact of the waste disposal in the IDF. A testing program was developed in fiscal year (FY) 2012 describing in some detail the work needed to develop and qualify Cast Stone as a waste form for the solidification of Hanford LAW (Westsik et al. 2012). Included within Westsik et al. (2012) is a section on the near-term needs to address Tri-Party Agreement Milestone M-062-40ZZ. The objectives of the testing program to be conducted in FY 2013 and FY 2014 are to: • Determine an acceptable formulation for the LAW Cast Stone waste form. • Evaluate sources of dry materials for preparing the LAW Cast Stone. • Demonstrate the robustness of the Cast Stone waste form for a range of LAW compositions. • Demonstrate the robustness of the formulation for variability in the Cast Stone process. • Provide Cast Stone contaminant release data for PA and risk assessment evaluations. The first step in determining an acceptable formulation for the LAW Cast Stone waste form is to conduct screening tests to examine expected ranges in pretreated LAW composition, waste stream concentrations, dry-materials sources, and mix ratios of waste feed to dry blend. A statistically designed test matrix will be used to evaluate the effects of these key parameters on the properties of the Cast Stone as it is initially prepared and after curing. The second phase of testing will focus on selection of a baseline Cast Stone formulation for LAW and demonstrating that Cast Stone can meet expected waste form requirements for disposal in the IDF. It is expected that this testing will use the results of the screening tests to define a smaller suite of tests to refine the composition of the baseline Cast Stone formulation (e.g. waste concentration, water to dry mix ratio, waste loading).« less

Pre-incubation in soil improves the nitrogen fertiliser value of hair waste.

PubMed

Malepfane, N M; Muchaonyerwa, P

2018-01-25

Global generation of human hair waste and its disposal at landfills could contribute to the leaching of nitrates into ground water. High concentrations of nitrogen (N) and other elements suggest that the waste could be a source of plant nutrients and differences in ethnic hair types could affect nutrient release and fertiliser value. The objective of this study was to determine the effects of hair type, as an N source, and pre-incubation time on dry-matter yield, nutrient uptake by spinach (Spinacia oleracea L.) and residual soil nutrients. Salons in Pietermaritzburg provided bulk African and Caucasian hair waste, without distinguishing age, sex, health status or livelihood of the individuals. The hair waste was analysed for elemental composition. A pot experiment was set up under glasshouse conditions. The hair waste was incorporated (400 kg N ha -1 ) into a loamy oxisol and pre-incubated for 0, 28, 56 and 84 days before planting spinach. Potassium (K) and phosphorus (P) were corrected to the same level for all treatments. Spinach seedlings were then cultivated for 6 weeks. Shoot dry-matter and the uptake of all nutrients, except P, were increased by the pre-incubation of hair. African hair pre-incubated for 28 days resulted in greater dry-matter, N, K, Mn and S uptake than Caucasian hair. Increasing pre-incubation resulted in a decline in the residual soil pH and exchangeable K. The findings suggested that pre-incubation improves the N fertiliser value of hair and that African hair has greater value than Caucasian hair when pre-incubated for a short period.

Updraft gasification of salmon processing waste.

PubMed

Rowland, Sarah; Bower, Cynthia K; Patil, Krushna N; DeWitt, Christina A Mireles

2009-10-01

The purpose of this study was to judge the feasibility of gasification for the disposal of waste streams generated through salmon harvesting. Gasification is the process of converting carbonaceous materials into combustible "syngas" in a high temperature (above 700 degrees C), oxygen deficient environment. Syngas can be combusted to generate power, which recycles energy from waste products. At 66% to 79% moisture, raw salmon waste streams are too wet to undergo pyrolysis and combustion. Ground raw or de-oiled salmon whole fish, heads, viscera, or frames were therefore "dried" by mixing with wood pellets to a final moisture content of 20%. Ground whole salmon with moisture reduced to 12% moisture was gasified without a drying agent. Gasification tests were performed in a small-scale, fixed-bed, updraft gasifer. After an initial start-up period, the gasifier was loaded with 1.5 kg of biomass. Temperature was recorded at 6 points in the gasifier. Syngas was collected during the short steady-state period during each gasifier run and analyzed. Percentages of each type of gas in the syngas were used to calculate syngas heating value. High heating value (HHV) ranged from 1.45 to 1.98 MJ/kg. Bomb calorimetry determined maximum heating value for the salmon by-products. Comparing heating values shows the efficiency of gasification. Cold gas efficiencies of 13.6% to 26% were obtained from the various samples gasified. Though research of gasification as a means of salmon waste disposal and energy production is ongoing, it can be concluded that pre-dried salmon or relatively low moisture content mixtures of waste with wood are gasifiable.

Smoke emissions due to burning of green waste in the Mediterranean area: Influence of fuel moisture content and fuel mass

NASA Astrophysics Data System (ADS)

Tihay-Felicelli, V.; Santoni, P. A.; Gerandi, G.; Barboni, T.

2017-06-01

The aim of this study was to investigate emission characteristics in relation to differences in fuel moisture content (FMC) and initial dry mass. For this purpose, branches and twigs with leaves of Cistus monspeliensis were burned in a Large Scale Heat Release apparatus coupled to a Fourier Transform Infrared Spectrometer. A smoke analysis was conducted and the results highlighted the presence of CO2, H2O, CO, CH4, NO, NO2, NH3, SO2, and non-methane organic compounds (NMOC). CO2, NO, and NO2 species are mainly released during flaming combustion, whereas CO, CH4, NH3, and NMOC are emitted during both flaming and smoldering combustion. The emission of these compounds during flaming combustion is due to a rich fuel to air mixture, leading to incomplete combustion. The fuel moisture content and initial dry mass influence the flame residence time, the duration of smoldering combustion, the combustion efficiency, and the emission factors. By increasing the initial dry mass, the emission factors of NO, NO2, and CO2 decrease, whereas those of CO and CH4 increase. The increase of FMC induces an increase of the emission factors of CO, CH4, NH3, NMOC, and aerosols, and a decrease of those of CO2, NO, and NO2. Increasing fuel moisture content reduces fuel consumption, duration of smoldering, and peak heat release rate, but simultaneously increases the duration of propagation within the packed bed, and the flame residence time. Increasing the initial dry mass, causes all the previous combustion parameters to increase. These findings have implications for modeling biomass burning emissions and impacts.

Enhancement of anaerobic biodegradability of flower stem wastes with vegetable wastes by co-hydrolysis.

PubMed

Zhang, Bo; He, Pinjing; Lü, Fan; Shao, Liming

2008-01-01

The vegetable wastes and flower stems were co-digested to evaluate the anaerobic hydrolysis performance of difficultly biodegradable organic wastes by introducing readily biodegradable organic wastes. The experiments were carried out in batches. When the vegetable wastes were mixed with the flower stems at the dry weight ratio of 1 to 13, the overall hydrolysis rate increased by 8%, 12%, and 2% according to the carbon, nitrogen, and total solid (TS) conversion rate, respectively. While the dry weight ratio was designed as 1 to 3, there was a respective rise of 5%, 15%, and 4% in the conversion rate of carbon, nitrogen, and TS. The enhancement of anaerobic hydrolysis from the mixed vegetable wastes and flower stems can be attributed to the formation of volatile fatty acids (VFA) and nutrient supplement like nitrogen content. The maximum VFA concentration can achieve 1.7 g/L owing to the rapid acidification of vegetable wastes, loosing the structure of lignocellulose materials. The statistic bivariate analysis revealed that the hydrolysis performance was significantly related to the physical and biochemical compositions of the feeding substrate. Especially, the soluble carbon concentration in the liquid was significantly positively correlated to the concentration of nitrogen and hemicellulose, and negatively correlated to the concentration of carbon and lignocellulose in the feeding substrate, suggesting that the regulation and control of feedstock can have an important influence on the anaerobic hydrolysis of organic wastes.

[Application of microbial fuel cell (MFC) in solid waste composting].

PubMed

Cui, Jinxin; Wang, Xin; Tang, Jingchun

2012-03-01

Microbial fuel cell (MFC) is a new technology that can recover energy from biomass with simultaneous waste treatment. This technique has been developed fast in recent years in combining with environmental techniques such as wastewater treatment, degradation of toxic pollutants and desalination. With the increase of solid waste, applying MFC in composting is promising due to its property of waste disposal with simultaneous energy generation. In this paper, the microbial community of MFCs during composting was summarized. Four major influencing factors including electrodes, separators, oxygen supplement and configurations on the performance of composting MFCs were discussed. The characteristics of composting MFC as a new technique for reducing solid waste were as follows: high microbial biomass resulted in the high current density; adaptable to different environmental conditions; self-adjustable temperature with high energy efficiency; the transportation of proton from anode to cathode were limited by different solid substrates.

MOBILITY AND DEGRADATION OF RESIDUES AT HAZARDOUS WASTE LAND TREATMENT SITES AT CLOSURE

EPA Science Inventory

Soil treatment systems that are designed and managed based on a knowledge of soil-waste interactions may represent a significant technology for simultaneous treatment and ultimate disposal of selected hazardous wastes in an environmentally acceptable manner. hese soil treatment s...

The application of SRF vs. RDF classification and specifications to the material flows of two mechanical-biological treatment plants of Rome: Comparison and implications.

PubMed

Di Lonardo, Maria Chiara; Franzese, Maurizio; Costa, Giulia; Gavasci, Renato; Lombardi, Francesco

2016-01-01

This work assessed the quality in terms of solid recovered fuel (SRF) definitions of the dry light flow (until now indicated as refuse derived fuel, RDF), heavy rejects and stabilisation rejects, produced by two mechanical biological treatment plants of Rome (Italy). SRF classification and specifications were evaluated first on the basis of RDF historical characterisation methods and data and then applying the sampling and analytical methods laid down by the recently issued SRF standards. The results showed that the dry light flow presented a worst SRF class in terms of net calorific value applying the new methods compared to that obtained from RDF historical data (4 instead of 3). This lead to incompliance with end of waste criteria established by Italian legislation for SRF use as co-fuel in cement kilns and power plants. Furthermore, the metal contents of the dry light flow obtained applying SRF current methods proved to be considerably higher (although still meeting SRF specifications) compared to those resulting from historical data retrieved with RDF standard methods. These differences were not related to a decrease in the quality of the dry light flow produced in the mechanical-biological treatment plants but rather to the different sampling procedures set by the former RDF and current SRF standards. In particular, the shredding of the sample before quartering established by the latter methods ensures that also the finest waste fractions, characterised by higher moisture and metal contents, are included in the sample to be analysed, therefore affecting the composition and net calorific value of the waste. As for the reject flows, on the basis of their SRF classification and specification parameters, it was found that combined with the dry light flow they may present similar if not the same class codes as the latter alone, thus indicating that these material flows could be also treated in combustion plants instead of landfilled. In conclusion, the introduction of SRF definitions, classification and specification procedures, while not necessarily leading to an upgrade of the waste as co-fuel in cement kilns and power plants, may anyhow provide new possibilities for energy recovery from waste by increasing the types of mechanically treated waste flows that may be thermally treated. Copyright © 2015 Elsevier Ltd. All rights reserved.

Process for immobilizing radioactive boric acid liquid wastes

DOEpatents

Greenhalgh, Wilbur O.

1986-01-01

A method of immobilizing boric acid liquid wastes containing radionuclides by neutralizing the solution and evaporating the resulting precipitate to near dryness. The dry residue is then fused into a reduced volume, insoluble, inert, solid form containing substantially all the radionuclides.

MERCURY CONTROL IN MUNICIPAL WASTE COMBUSTORS AND COAL-FIRED UTILITIES

EPA Science Inventory

Control of mercury (Hg) emissions from municipal waste combustors (MWCs) and coal-fired utilities has attracted attention due to current and potential regulations. Among several techniques evaluated for Hg control, dry sorbent injection (primarily injection of activated carbon) h...

40 CFR 63.1217 - What are the standards for liquid fuel boilers that burn hazardous waste?

Code of Federal Regulations, 2010 CFR

2010-07-01

... ng TEQ/dscm, corrected to 7 percent oxygen, for liquid fuel boilers equipped with a dry air pollution... by paragraph (a)(5) of this section for sources not equipped with a dry air pollution control system; (iii) A source equipped with a wet air pollution control system followed by a dry air pollution control...

40 CFR 63.1217 - What are the standards for liquid fuel boilers that burn hazardous waste?

Code of Federal Regulations, 2011 CFR

2011-07-01

... ng TEQ/dscm, corrected to 7 percent oxygen, for liquid fuel boilers equipped with a dry air pollution... by paragraph (a)(5) of this section for sources not equipped with a dry air pollution control system; (iii) A source equipped with a wet air pollution control system followed by a dry air pollution control...

Biopesticide effect of green compost against fusarium wilt on melon plants.

PubMed

Ros, M; Hernandez, M T; Garcia, C; Bernal, A; Pascual, J A

2005-01-01

The biopesticide effect of four green composts against fusarium wilt in melon plants and the effect of soil quality in soils amended with composts were assayed. The composts consisted of pruning wastes, with or without addition of coffee wastes (3/1 and 4/1, dry wt/dry wt) or urea (1000/1, dry wt/dry wt). In vitro experiments suggested the biopesticide effect of the composts against Fusarium oxysporum, while only the compost of pine bark and urea (1000/1dry wt/dry wt) had an abiotic effect. Melon plant growth with composts and F. oxysporum was one to four times greater than in the non-amended soil, although there was no significant decrease in the level of the F. oxysporum in the soil. The addition of composts to the soil also improved its biological quality, as assessed by microbiological and biochemical parameters: ATP and hydrolases involved in the P (phosphatase), C (beta-glucosidase) and N (urease) cycles. Green composts had greater beneficial characteristics, improved plant growth and controlled fusarium wilt in melon plants. These composts improve the soil quality of semi-arid agricultural soils. Biotic and abiotic factors from composts have been tested as responsible of their biopesticide activity against fusarium wilt.

Emissions from small-scale energy production using co-combustion of biofuel and the dry fraction of household waste.

PubMed

Hedman, Björn; Burvall, Jan; Nilsson, Calle; Marklund, Stellan

2005-01-01

In sparsely populated rural areas, recycling of household waste might not always be the most environmentally advantageous solution due to the total amount of transport involved. In this study, an alternative approach to recycling has been tested using efficient small-scale biofuel boilers for co-combustion of biofuel and high-energy waste. The dry combustible fraction of source-sorted household waste was mixed with the energy crop reed canary-grass (Phalaris Arundinacea L.), and combusted in both a 5-kW pilot scale reactor and a biofuel boiler with 140-180 kW output capacity, in the form of pellets and briquettes, respectively. The chlorine content of the waste fraction was 0.2%, most of which originated from plastics. The HCl emissions exceeded levels stipulated in new EU-directives, but levels of equal magnitude were also generated from combustion of the pure biofuel. Addition of waste to the biofuel did not give any apparent increase in emissions of organic compounds. Dioxin levels were close to stipulated limits. With further refinement of combustion equipment, small-scale co-combustion systems have the potential to comply with emission regulations.

Monitoring household waste recycling centres performance using mean bin weight analyses.

PubMed

Maynard, Sarah; Cherrett, Tom; Waterson, Ben

2009-02-01

This paper describes a modelling approach used to investigate the significance of key factors (vehicle type, compaction type, site design, temporal effects) in influencing the variability in observed nett amenity bin weights produced by household waste recycling centres (HWRCs). This new method can help to quickly identify sites that are producing significantly lighter bins, enabling detailed back-end analyses to be efficiently targeted and best practice in HWRC operation identified. Tested on weigh ticket data from nine HWRCs across West Sussex, UK, the model suggests that compaction technique, vehicle type, month and site design explained 76% of the variability in the observed nett amenity weights. For each factor, a weighting coefficient was calculated to generate a predicted nett weight for each bin transaction and three sites were subsequently identified as having similar characteristics but returned significantly different mean nett bin weights. Waste and site audits were then conducted at the three sites to try and determine the possible sources of the remaining variability. Significant differences were identified in the proportions of contained waste (bagged), wood, and dry recyclables entering the amenity waste stream, particularly at one site where significantly less contaminated waste and dry recyclables were observed.

Biomass waste-to-energy valorisation technologies: a review case for banana processing in Uganda.

PubMed

Gumisiriza, Robert; Hawumba, Joseph Funa; Okure, Mackay; Hensel, Oliver

2017-01-01

Uganda's banana industry is heavily impeded by the lack of cheap, reliable and sustainable energy mainly needed for processing of banana fruit into pulp and subsequent drying into chips before milling into banana flour that has several uses in the bakery industry, among others. Uganda has one of the lowest electricity access levels, estimated at only 2-3% in rural areas where most of the banana growing is located. In addition, most banana farmers have limited financial capacity to access modern solar energy technologies that can generate sufficient energy for industrial processing. Besides energy scarcity and unreliability, banana production, marketing and industrial processing generate large quantities of organic wastes that are disposed of majorly by unregulated dumping in places such as swamps, thereby forming huge putrefying biomass that emit green house gases (methane and carbon dioxide). On the other hand, the energy content of banana waste, if harnessed through appropriate waste-to-energy technologies, would not only solve the energy requirement for processing of banana pulp, but would also offer an additional benefit of avoiding fossil fuels through the use of renewable energy. The potential waste-to-energy technologies that can be used in valorisation of banana waste can be grouped into three: Thermal (Direct combustion and Incineration), Thermo-chemical (Torrefaction, Plasma treatment, Gasification and Pyrolysis) and Biochemical (Composting, Ethanol fermentation and Anaerobic Digestion). However, due to high moisture content of banana waste, direct application of either thermal or thermo-chemical waste-to-energy technologies is challenging. Although, supercritical water gasification does not require drying of feedstock beforehand and can be a promising thermo-chemical technology for gasification of wet biomass such as banana waste, it is an expensive technology that may not be adopted by banana farmers in Uganda. Biochemical conversion technologies are reported to be more eco-friendly and appropriate for waste biomass with high moisture content such as banana waste. Uganda's banana industrialisation is rural based with limited technical knowledge and economic capability to setup modern solar technologies and thermo-conversions for drying banana fruit pulp. This review explored the advantages of various waste-to-energy technologies as well as their shortfalls. Anaerobic digestion stands out as the most feasible and appropriate waste-to-energy technology for solving the energy scarcity and waste burden in banana industry. Finally, potential options for the enhancement of anaerobic digestion of banana waste were also elucidated.

Sewage sludge drying by energy recovery from OFMSW composting: preliminary feasibility evaluation.

PubMed

Rada, Elena Cristina; Ragazzi, Marco; Villotti, Stefano; Torretta, Vincenzo

2014-05-01

In this paper an original energy recovery method from composting is analyzed. The integrated system exploits the heat available from the aerobic biochemical process in order to support the drying of sewage sludge, using a specific solar greenhouse. The aim is to tackle the problem of organic waste treatment, with specific regard to food waste. This is done by optimizing the energy consumption of the aerobic process of composting, using the heat produced to solve a second important waste management problem such as the sewage waste treatment. Energy and mass balances are presented in a preliminary feasibility study. Referring to a composting plant with a capacity of 15,000 t/y of food waste, the estimation of the power from recovered heat for the entire plant resulted about 42 kW. The results demonstrated that the energy recoverable can cover part of the heat necessary for the treatment of sludge generated by the population served by the composting plant (in terms of food waste and green waste collection). The addition of a renewable source such as solar energy could cover the residual energy demand. The approach is presented in detail in order for it to be replicated in other case studies or at full scale applications. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effect of total solids content on methane and volatile fatty acid production in anaerobic digestion of food waste.

PubMed

Liotta, Flavia; d'Antonio, Giuseppe; Esposito, Giovanni; Fabbricino, Massimiliano; van Hullebusch, Eric D; Lens, Piet N L; Pirozzi, Francesco; Pontoni, Ludovico

2014-10-01

This work investigates the role of the moisture content on anaerobic digestion of food waste, as representative of rapidly biodegradable substrates, analysing the role of volatile fatty acid production on process kinetics. A range of total solids from 4.5% to 19.2% is considered in order to compare methane yields and kinetics of reactors operated under wet to dry conditions. The experimental results show a reduction of the specific final methane yield of 4.3% and 40.8% in semi-dry and dry conditions compared with wet conditions. A decreasing trend of the specific initial methane production rate is observed when increasing the total solids concentration. Because of lack of water, volatile fatty acids accumulation occurs during the first step of the process at semi-dry and dry conditions, which is considered to be responsible for the reduction of process kinetic rates. The total volatile fatty acids concentration and speciation are proposed as indicators of process development at different total solids content. © The Author(s) 2014.

Energy balance, greenhouse gas emissions, and profitability of thermobarical pretreatment of cattle waste in anaerobic digestion.

PubMed

Budde, Jörn; Prochnow, Annette; Plöchl, Matthias; Suárez Quiñones, Teresa; Heiermann, Monika

2016-03-01

In this study modeled full scale application of thermobarical hydrolysis of less degradable feedstock for biomethanation was assessed in terms of energy balance, greenhouse gas emissions, and economy. Data were provided whether the substitution of maize silage as feedstock for biogas production by pretreated cattle wastes is beneficial in full-scale application or not. A model device for thermobarical treatment has been suggested for and theoretically integrated in a biogas plant. The assessment considered the replacement of maize silage as feedstock with liquid and/or solid cattle waste (feces, litter, and feed residues from animal husbandry of high-performance dairy cattle, dry cows, and heifers). The integration of thermobarical pretreatment is beneficial for raw material with high contents of organic dry matter and ligno-cellulose: Solid cattle waste revealed very short payback times, e.g. 9 months for energy, 3 months for greenhouse gases, and 3 years 3 months for economic amortization, whereas, in contrast, liquid cattle waste did not perform positive replacement effects in this analysis. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

Modified Anaerobic Digestion Model No.1 for dry and semi-dry anaerobic digestion of solid organic waste.

PubMed

Liotta, Flavia; Chatellier, Patrice; Esposito, Giovanni; Fabbricino, Massimiliano; Frunzo, Luigi; van Hullebusch, Eric D; Lens, Piet N L; Pirozzi, Francesco

2015-01-01

The role of total solids (TS) content in anaerobic digestion of selected complex organic matter, e.g. rice straw and food waste, was investigated. A range of TS from wet (4.5%) to dry (23%) was evaluated. A modified version of the Anaerobic Digestion Model No.1 for a complex organic substrate is proposed to take into account the effect of the TS content on anaerobic digestion. A linear function that correlates the kinetic constants of three specific processes (i.e. disintegration, acetate and propionate up-take) was included in the model. Results of biomethanation and volatile fatty acids production tests were used to calibrate the proposed model. Model simulations showed a good agreement between numerical and observed data.

Municipal waste processing apparatus

DOEpatents

Mayberry, J.L.

1988-04-13

This invention relates to apparatus for processing municipal waste, and more particularly to vibrating mesh screen conveyor systems for removing grit, glass, and other noncombustible materials from dry municipal waste. Municipal waste must be properly processed and disposed of so that it does not create health risks to the community. Generally, municipal waste, which may be collected in garbage trucks, dumpsters, or the like, is deposited in processing areas such as landfills. Land and environmental controls imposed on landfill operators by governmental bodies have increased in recent years, however, making landfill disposal of solid waste materials more expensive. 6 figs.

Central waste processing system

NASA Technical Reports Server (NTRS)

Kester, F. L.

1973-01-01

A new concept for processing spacecraft type wastes has been evaluated. The feasibility of reacting various waste materials with steam at temperatures of 538 - 760 C in both a continuous and batch reactor with residence times from 3 to 60 seconds has been established. Essentially complete gasification is achieved. Product gases are primarily hydrogen, carbon dioxide, methane, and carbon monoxide. Water soluble synthetic wastes are readily processed in a continuous tubular reactor at concentrations up to 20 weight percent. The batch reactor is able to process wet and dry wastes at steam to waste weight ratios from 2 to 20. Feces, urine, and synthetic wastes have been successfully processed in the batch reactor.

Process for immobilizing radioactive boric acid liquid wastes

DOEpatents

Greenhalgh, W.O.

1984-05-10

Disclosed is a method of immobilizing boric acid liquid wastes containing radionuclides by neutralizing the solution and evaporating the resulting precipitate to near dryness. The dry residue is then fused into a reduced volume, insoluble, inert, solid form containing substantially all the radionuclides.

The effects of leachate recirculation with supplemental water addition on methane production and waste decomposition in a simulated tropical landfill.

PubMed

Sanphoti, N; Towprayoon, S; Chaiprasert, P; Nopharatana, A

2006-10-01

In order to increase methane production efficiency, leachate recirculation is applied in landfills to increase moisture content and circulate organic matter back into the landfill cell. In the case of tropical landfills, where high temperature and evaporation occurs, leachate recirculation may not be enough to maintain the moisture content, therefore supplemental water addition into the cell is an option that could help stabilize moisture levels as well as stimulate biological activity. The objectives of this study were to determine the effects of leachate recirculation and supplemental water addition on municipal solid waste decomposition and methane production in three anaerobic digestion reactors. Anaerobic digestion with leachate recirculation and supplemental water addition showed the highest performance in terms of cumulative methane production and the stabilization period time required. It produced an accumulated methane production of 54.87 l/kg dry weight of MSW at an average rate of 0.58 l/kg dry weight/d and reached the stabilization phase on day 180. The leachate recirculation reactor provided 17.04 l/kg dry weight at a rate of 0.14l/kg dry weight/d and reached the stabilization phase on day 290. The control reactor provided 9.02 l/kg dry weight at a rate of 0.10 l/kg dry weight/d, and reached the stabilization phase on day 270. Increasing the organic loading rate (OLR) after the waste had reached the stabilization phase made it possible to increase the methane content of the gas, the methane production rate, and the COD removal. Comparison of the reactors' efficiencies at maximum OLR (5 kgCOD/m(3)/d) in terms of the methane production rate showed that the reactor using leachate recirculation with supplemental water addition still gave the highest performance (1.56 l/kg dry weight/d), whereas the leachate recirculation reactor and the control reactor provided 0.69 l/kg dry weight/d and 0.43 l/kg dry weight/d, respectively. However, when considering methane composition (average 63.09%) and COD removal (average 90.60%), slight differences were found among these three reactors.

Long-Term High-Level Defense-Waste technology

NASA Astrophysics Data System (ADS)

1982-07-01

In the residual liquid solidification effort, the primary alternative studied is the wiped film evaporator approach to solidifying salt well pumped liquids and returning the molten material to single shell tanks for microwave final stabilization to a hard dry product. Both systems analysis and experimental work are proceeding to evaluate this approach. The primary alternative for in situ stabilization of in-tank wastes is microwave drying of wet salt cake and unpumped sludges. Experimental work was successfully conducted on a 1/12 scale tank containing wet synthetic salt cake. Related systems analysis of a full scale system was initiated.

Identification of locally available structural material as co-substrate for organic waste composting in Tamil Nadu, India.

PubMed

Springer, C; Heldt, N

2016-06-01

Owing to the lack in structural strength while composting certain kinds of organic wastes, 11 co-substrates were tested that are generally locally available in rural areas of northern Tamil Nadu, India. In addition to the classical composting parameters such as carbon/nitrogen ratio, moisture content, dry matter and organic dry matter, a compression test was conducted to evaluate the structural strength and the suitability as bulking agent for composting processes. Additionally, with respect to the climatic conditions in India, the water holding capacity was also evaluated. © The Author(s) 2016.

Fabrication of microfibrillated cellulose gel from waste pulp sludge via mild maceration combined with mechanical shearing

Treesearch

Nusheng Chen; Junyong Zhu; Zhaohui Tong

2016-01-01

This article describes a facile route, which combines mild maceration of waste pulp sludge and a mechanical shearing process, to prepare microfibrillated cellulose (MFC) with a high storage modulus. In the maceration, the mixture of glacial acetic acid and hydrogen peroxide was used to extract cellulose from never-dried waste pulp sludge. Then, two different mechanical...

Environmental Impact of the Helen, Research, and Chicago Mercury Mines on Water, Sediment, and Biota in the Upper Dry Creek Watershed, Lake County, California

USGS Publications Warehouse

Rytuba, James J.; Hothem, Roger L.; May, Jason T.; Kim, Christopher S.; Lawler, David; Goldstein, Daniel; Brussee, Brianne E.

2009-01-01

The Helen, Research, and Chicago mercury (Hg) deposits are among the youngest Hg deposits in the Coast Range Hg mineral belt and are located in the southwestern part of the Clear Lake volcanic field in Lake County, California. The mine workings and tailings are located in the headwaters of Dry Creek. The Helen Hg mine is the largest mine in the watershed having produced about 7,600 flasks of Hg. The Chicago and Research Hg mines produced only a small amount of Hg, less than 30 flasks. Waste rock and tailings have eroded from the mines, and mine drainage from the Helen and Research mines contributes Hg-enriched mine wastes to the headwaters of Dry Creek and contaminate the creek further downstream. The mines are located on federal land managed by the U.S. Bureau of Land Management (USBLM). The USBLM requested that the U.S. Geological Survey (USGS) measure and characterize Hg and geochemical constituents in tailings, sediment, water, and biota at the Helen, Research, and Chicago mines and in Dry Creek. This report is made in response to the USBLM request to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA - Removal Site Investigation (RSI). The RSI applies to removal of Hg-contaminated mine waste from the Helen, Research, and Chicago mines as a means of reducing Hg transport to Dry Creek. This report summarizes data obtained from field sampling of mine tailings, waste rock, sediment, and water at the Helen, Research, and Chicago mines on April 19, 2001, during a storm event. Further sampling of water, sediment, and biota at the Helen mine area and the upper part of Dry Creek was completed on July 15, 2003, during low-flow conditions. Our results permit a preliminary assessment of the mining sources of Hg and associated chemical constituents that could elevate levels of monomethyl Hg (MMeHg) in the water, sediment, and biota that are impacted by historic mining.

The Orbital Workshop Waste Management Compartment

NASA Technical Reports Server (NTRS)

1972-01-01

This image is a wide-angle view of the Orbital Workshop waste management compartment. The waste management facilities presented a unique challenge to spacecraft designers. In addition to collection of liquid and solid human wastes, there was a medical requirement to dry all solid human waste products and to return the residue to Earth for examination. Liquid human waste (urine) was frozen for return to Earth. Total quantities of each astronaut's liquid and solid wastes were precisely measured. Cabin air was drawn into the toilet, shown on the wall at right in this photograph, and over the waste products to generate a flow of the waste in the desired direction. The air was then filtered for odor control and antiseptic purposes prior to being discharged back into the cabin.

Separate collection of household food waste for anaerobic degradation - Comparison of different techniques from a systems perspective

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bernstad, A., E-mail: Anna.bernstad@chemeng.lth.se; Cour Jansen, J. la

Highlight: Black-Right-Pointing-Pointer Four modern and innovative systems for household food waste collection are compared. Black-Right-Pointing-Pointer Direct emissions and resource use were based on full-scale data. Black-Right-Pointing-Pointer Conservation of nutrients/energy content over the system was considered. Black-Right-Pointing-Pointer Systems with high energy/nutrient recovery are most environmentally beneficial. - Abstract: Four systems for household food waste collection are compared in relation the environmental impact categories eutrophication potential, acidification potential, global warming potential as well as energy use. Also, a hotspot analysis is performed in order to suggest improvements in each of the compared collection systems. Separate collection of household food waste in papermore » bags (with and without drying prior to collection) with use of kitchen grinders and with use of vacuum system in kitchen sinks were compared. In all cases, food waste was used for anaerobic digestion with energy and nutrient recovery in all cases. Compared systems all resulted in net avoidance of assessed environmental impact categories; eutrophication potential (-0.1 to -2.4 kg NO{sub 3}{sup -}eq/ton food waste), acidification potential (-0.4 to -1.0 kg SO{sub 2}{sup -}eq/ton food waste), global warming potential (-790 to -960 kg CO{sub 2}{sup -}eq/ton food waste) and primary energy use (-1.7 to -3.6 GJ/ton food waste). Collection with vacuum system results in the largest net avoidance of primary energy use, while disposal of food waste in paper bags for decentralized drying before collection result in a larger net avoidance of global warming, eutrophication and acidification. However, both these systems not have been taken into use in large scale systems yet and further investigations are needed in order to confirm the outcomes from the comparison. Ranking of scenarios differ largely if considering only emissions in the foreground system, indicating the importance of taking also downstream emissions into consideration when comparing different collection systems. The hot spot identification shows that losses of organic matter in mechanical pretreatment as well as tank connected food waste disposal systems and energy in drying and vacuum systems reply to the largest impact on the results in each system respectively.« less

DISPOSAL OF FLUE-GAS-CLEANING WASTES

EPA Science Inventory

The article describes current commercial and emerging technology for disposal of wastes from flue gas cleaning (FGC) systems for coal-fired power plants. Over 80 million metric tons/yr (dry) of coal ash and desulfurization solids are expected to be produced by the 1980's. Althoug...

40 CFR 761.295 - Reporting and recordkeeping of the PCB concentrations in samples.

Code of Federal Regulations, 2010 CFR

2010-07-01

... On-Site Disposal of Bulk PCB Remediation Waste and Porous Surfaces in Accordance With § 761.61(a)(6... concentrations for bulk PCB remediation waste and porous surfaces on a dry weight basis and as micrograms of PCBs...

Environmental assessment of a wood-waste-fired industrial watertube boiler. Volume 1. Technical results. Final report, March 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; Waterland, L.R.

1987-03-01

The two-volume report gives results from field tests of a wood-waste-fired industrial watertube boiler. Two series of tests were performed: one firing dry (11% moisture) wood waste, and the other firing green (34% moisture) wood waste. Emission measurements included: continuous monitoring of flue-gas emissions; source-assessment sampling system (SASS) sampling of the flue gas with subsequent laboratory analysis of samples to give total flue-gas organics in two boiling-point ranges, compound category information within these ranges, specific quantitation of the semi-volatile organic priority pollutants, and flue-gas concentrations of 73 trace elements; Method 5 sampling for particulate; controlled condensation system sampling for SO/submore » 2/ and SO/sub 3/; and grab sampling of boiler mechanical collector hopper ash for inorganic composition determinations. Total organic emissions decreased from 60-135 mg/dscm firing dry wood to 2-65 mg/dscm firing green wood, in parallel with corresponding boiler CO emissions.« less

Environmental assessment of a wood-waste-fired industrial watertube boiler. Volume 2. Data supplement. Final report, March 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; Waterland, L.R.

1987-03-01

The two-volume report gives results from field tests of a wood-waste-fired industrial watertube boiler. Two series of tests were performed: one firing dry (11% moisture) wood waste, and the other firing green (34% moisture) wood waste. Emission measurements included: continuous monitoring of flue-gas emissions; source-assessment sampling system (SASS) sampling of the flue-gas with subsequent laboratory analysis of samples to give total flue-gas organics in two boiling-point ranges, compound category information within these ranges, specific quantitation of the semi-volatile organic priority pollutants, and flue gas concentrations of 73 trace elements; Method 5 sampling for particulate; controlled condensation system sampling for SO/submore » 2/ and SO/sub 3/; and grab sampling of boiler mechanical collector hopper ash for inorganic and organic composition determinations. Total organic emissions decreased from 60-135 mg/dscm firing dry wood to 2-65 mg/dscm firing green wood, in parallel with corresponding boiler CO emissions.« less

A modified method for COD determination of solid waste, using a commercial COD kit and an adapted disposable weighing support.

PubMed

André, L; Pauss, A; Ribeiro, T

2017-03-01

The chemical oxygen demand (COD) is an essential parameter in waste management, particularly when monitoring wet anaerobic digestion processes. An adapted method to determine COD was developed for solid waste (total solids >15%). This method used commercial COD tubes and did not require sample dilution. A homemade plastic weighing support was used to transfer the solid sample into COD tubes. Potassium hydrogen phthalate and glucose used as standards showed an excellent repeatability. A small underestimation of the theoretical COD value (standard values around 5% lower than theoretical values) was also observed, mainly due to the intrinsic COD of the weighing support and to measurement uncertainties. The adapted COD method was tested using various solid wastes in the range of 1-8 mg COD , determining the COD of dried and ground cellulose, cattle manure, straw and a mixed-substrate sample. This new adapted method could be used to monitor and design dry anaerobic digestion processes.

Relationship between food waste, diet quality, and environmental sustainability

PubMed Central

Niles, Meredith T.; Neher, Deborah A.; Roy, Eric D.; Tichenor, Nicole E.; Jahns, Lisa

2018-01-01

Improving diet quality while simultaneously reducing environmental impact is a critical focus globally. Metrics linking diet quality and sustainability have typically focused on a limited suite of indicators, and have not included food waste. To address this important research gap, we examine the relationship between food waste, diet quality, nutrient waste, and multiple measures of sustainability: use of cropland, irrigation water, pesticides, and fertilizers. Data on food intake, food waste, and application rates of agricultural amendments were collected from diverse US government sources. Diet quality was assessed using the Healthy Eating Index-2015. A biophysical simulation model was used to estimate the amount of cropland associated with wasted food. This analysis finds that US consumers wasted 422g of food per person daily, with 30 million acres of cropland used to produce this food every year. This accounts for 30% of daily calories available for consumption, one-quarter of daily food (by weight) available for consumption, and 7% of annual cropland acreage. Higher quality diets were associated with greater amounts of food waste and greater amounts of wasted irrigation water and pesticides, but less cropland waste. This is largely due to fruits and vegetables, which are health-promoting and require small amounts of cropland, but require substantial amounts of agricultural inputs. These results suggest that simultaneous efforts to improve diet quality and reduce food waste are necessary. Increasing consumers’ knowledge about how to prepare and store fruits and vegetables will be one of the practical solutions to reducing food waste. PMID:29668732

[Effects of stabilization treatment on migration and transformation of heavy metals in mineral waste residues].

PubMed

Zhao, Shu-Hua; Chen, Zhi-Liang; Zhang, Tai-Ping; Pan, Wei-Bin; Peng, Xiao-Chun; Che, Rong; Ou, Ying-Juan; Lei, Guo-Jian; Zhou, Ding

2014-04-01

Different forms of heavy metals in soil will produce different environmental effects, and will directly influence the toxicity, migration and bioavailability of heavy metals. This study used lime, fly ash, dried sludge, peanut shells as stabilizers in the treatment of heavy metals in mineral waste residues. Morphological analyses of heavy metal, leaching experiments, potted plant experiments were carried out to analyze the migration and transformation of heavy metals. The results showed that after adding stabilizers, the pH of the acidic mineral waste residues increased to more than neutral, and the organic matter content increased significantly. The main existing forms of As, Pb, and Zn in the mineral waste residues were the residual. The contents of exchangeable and organic matter-bound As decreased by 65.6% and 87.7% respectively after adding fly ash, dried sludge and peanut shells. Adding lime, fly ash and peanut shells promoted the transformation of As from the Fe-Mn oxide-bound to the carbonate-bound, and adding lime and fly ash promoted the transformation of Pb and Zn from the exchangeable, Fe-Mn oxide-bound, organic matter-bound to the residual. After the early stage of the stabilization treatment, the contents of As, Pb and Zn in the leachate had varying degrees of decline, and adding peanut shells could reduce the contents of As, Pb and Zn in the leachate further. Among them, the content of As decreased most significantly after treatment with fly ash, dried sludge and peanut shells, with a decline of 57.4%. After treatment with lime, fly ash and peanut shells, the content of Zn decreased most significantly, by 24.9%. The addition of stabilizers was advantageous to the germination and growth of plants. The combination of fly ash, dried sludge and peanut shell produced the best effect, and the Vetiveria zizanioides germination rate reached 76% in the treated wasted mineral residues.

Design of pyrolysis reactor for production of bio-oil and bio-char simultaneously

NASA Astrophysics Data System (ADS)

Aladin, Andi; Alwi, Ratna Surya; Syarif, Takdir

2017-05-01

The residues from the wood industry are the main contributors to biomass waste in Indonesia. The conventional pyrolysis process, which needs a large energy as well as to produce various toxic chemical to the environment. Therefore, a pyrolysis unit on the laboratory scale was designed that can be a good alternative to achieve zero-waste and low energy cost. In this paper attempts to discuss design and system of pyrolysis reactor to produce bio-oil and bio-char simultaneously.

Continuous high-solids anaerobic co-digestion of organic solid wastes under mesophilic conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Dong-Hoon; Oh, Sae-Eun, E-mail: saeun@hanbat.ac.kr

2011-09-15

Highlights: > High-solids (dry) anaerobic digestion is attracting a lot of attention these days. > One reactor was fed with food waste (FW) and paper waste. > Maximum biogas production rate of 5.0 m{sup 3}/m{sup 3}/d was achieved at HRT 40 d and 40% TS. > The other reactor was fed with FW and livestock waste (LW). > Until a 40% LW content increase, the reactor exhibited a stable performance. - Abstract: With increasing concerns over the limited capacity of landfills, conservation of resources, and reduction of CO{sub 2} emissions, high-solids (dry) anaerobic digestion of organic solid waste (OSW) ismore » attracting a great deal of attention these days. In the present work, two dry anaerobic co-digestion systems fed with different mixtures of OSW were continuously operated under mesophilic conditions. Dewatered sludge cake was used as a main seeding source. In reactor (I), which was fed with food waste (FW) and paper waste (PW), hydraulic retention time (HRT) and solid content were controlled to find the maximum treatability. At a fixed solid content of 30% total solids (TS), stable performance was maintained up to an HRT decrease to 40 d. However, the stable performance was not sustained at 30 d HRT, and hence, HRT was increased to 40 d again. In further operation, instead of decreasing HRT, solid content was increased to 40% TS, which was found to be a better option to increase the treatability. The biogas production rate (BPR), CH{sub 4} production yield (MPY) and VS reduction achieved in this condition were 5.0 m{sup 3}/m{sup 3}/d, 0.25 m{sup 3} CH{sub 4}/g COD{sub added}, and 80%, respectively. Reactor (II) was fed with FW and livestock waste (LW), and LW content was increased during the operation. Until a 40% LW content increase, reactor (II) exhibited a stable performance. A BPR of 1.7 m{sup 3}/m{sup 3}/d, MPY of 0.26 m{sup 3} CH{sub 4}/g COD{sub added}, and VS reduction of 72% was achieved at 40% LW content. However, when the LW content was increased to 60%, there was a significant performance drop, which was attributed to free ammonia inhibition. The performances in these two reactors were comparable to the ones achieved in the conventional wet digestion and thermophilic dry digestion processes.« less

Improvement of Leaching Resistance of Low-level Waste Form in Korea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, J.Y.; Lee, B.C.; Kim, C.L.

2006-07-01

Low-level liquid concentrate wastes including boric acid have been immobilized with paraffin wax using concentrate waste drying system in Korean nuclear power plants since 1995. Small amount of low density polyethylene (LDPE) was added to increase the leaching resistance of the existing paraffin waste form and the influence of LDPE on the leaching behavior of waste form was investigated. It was observed that the leaching of nuclides immobilized within paraffin waste form remarkably reduced as the content of LDPE increased. The acceptance criteria of paraffin waste form associated with leachability index and compressive strength after the leaching test were successfullymore » satisfied with the help of LDPE. (authors)« less

Waste streams in a crewed space habitat

NASA Technical Reports Server (NTRS)

Wydeven, T.; Golub, M. A.

1991-01-01

A judicious compilation of generation rates and chemical compositions of potential waste feed streams in a typical crewed space habitat was made in connection with the waste-management aspect of NASA's Physical/Chemical Closed-Loop Life Support Program. Waste composition definitions are needed for the design of waste-processing technologies involved in closing major life support functions in future long-duration human space missions. Tables of data for the constituents and chemical formulas of the following waste streams are presented and discussed: human urine, feces, hygiene (laundry and shower) water, cleansing agents, trash, humidity condensate, dried sweat, and trace contaminants. Tables of data on dust generation and pH values of the different waste streams are also presented and discussed.

Recovery of energy and nutrient resources from cattle paunch waste using temperature phased anaerobic digestion.

PubMed

Jensen, Paul D; Mehta, Chirag M; Carney, Chris; Batstone, D J

2016-05-01

Cattle paunch is comprised of partially digested cattle feed, containing mainly grass and grain and is a major waste produced at cattle slaughterhouses contributing 20-30% of organic matter and 40-50% of P waste produced on-site. In this work, Temperature Phased Anaerobic Digestion (TPAD) and struvite crystallization processes were developed at pilot-scale to recover methane energy and nutrients from paunch solid waste. The TPAD plant achieved a maximum sustainable organic loading rate of 1-1.5kgCODm(-3)day(-1) using a feed solids concentration of approximately 3%; this loading rate was limited by plant engineering and not the biology of the process. Organic solids destruction (60%) and methane production (230LCH4kg(-1) VSfed) achieved in the plant were similar to levels predicted from laboratory biochemical methane potential (BMP) testing. Model based analysis identified no significant difference in batch laboratory parameters vs pilot-scale continuous parameters, and no change in speed or extent of degradation. However the TPAD process did result in a degree of process intensification with a high level of solids destruction at an average treatment time of 21days. Results from the pilot plant show that an integrated process enabled resource recovery at 7.8GJ/dry tonne paunch, 1.8kgP/dry tonne paunch and 1.0kgN/dry tonne paunch. Copyright © 2016 Elsevier Ltd. All rights reserved.

Environmental and health impacts of using food waste as animal feed: a comparative analysis of food waste management options.

PubMed

Salemdeeb, Ramy; Zu Ermgassen, Erasmus K H J; Kim, Mi Hyung; Balmford, Andrew; Al-Tabbaa, Abir

2017-01-01

The disposal of food waste is a large environmental problem. In the United Kingdom (UK), approximately 15 million tonnes of food are wasted each year, mostly disposed of in landfill, via composting, or anaerobic digestion (AD). European Union (EU) guidelines state that food waste should preferentially be used as animal feed though for most food waste this practice is currently illegal, because of disease control concerns. Interest in the potential diversion of food waste for animal feed is however growing, with a number of East Asian states offering working examples of safe food waste recycling - based on tight regulation and rendering food waste safe through heat treatment. This study investigates the potential benefits of diverting food waste for pig feed in the UK. A hybrid, consequential life cycle assessment (LCA) was conducted to compare the environmental and health impacts of four technologies for food waste processing: two technologies of South Korean style-animal feed production (as a wet pig feed and a dry pig feed) were compared with two widespread UK disposal technologies: AD and composting. Results of 14 mid-point impact categories show that the processing of food waste as a wet pig feed and a dry pig feed have the best and second-best scores, respectively, for 13/14 and 12/14 environmental and health impacts. The low impact of food waste feed stems in large part from its substitution of conventional feed, the production of which has substantial environmental and health impacts. While the re-legalisation of the use of food waste as pig feed could offer environmental and public health benefits, this will require support from policy makers, the public, and the pig industry, as well as investment in separated food waste collection which currently occurs in only a minority of regions.

Simultaneous rough rice drying and rice bran stabilization using infrared radiation heating

USDA-ARS?s Scientific Manuscript database

The objective of this study was to develop a new rice drying method by using IR heating followed by tempering. Freshly harvested medium grain rice (M206) samples with different initial moisture contents (IMCs) were used in this study. The samples were dried for one- and two-passes by using a catalyt...

Possibility of using waste tire rubber and fly ash with Portland cement as construction materials.

PubMed

Yilmaz, Arin; Degirmenci, Nurhayat

2009-05-01

The growing amount of waste rubber produced from used tires has resulted in an environmental problem. Recycling waste tires has been widely studied for the last 20 years in applications such as asphalt pavement, waterproofing systems and membrane liners. The aim of this study is to evaluate the feasibility of utilizing fly ash and rubber waste with Portland cement as a composite material for masonry applications. Class C fly ash and waste automobile tires in three different sizes were used with Portland cement. Compressive and flexural strength, dry unit weight and water absorption tests were performed on the composite specimens containing waste tire rubber. The compressive strength decreased by increasing the rubber content while increased by increasing the fly ash content for all curing periods. This trend is slightly influenced by particle size. For flexural strength, the specimens with waste tire rubber showed higher values than the control mix probably due to the effect of rubber fibers. The dry unit weight of all specimens decreased with increasing rubber content, which can be explained by the low specific gravity of rubber particles. Water absorption decreased slightly with the increase in rubber particles size. These composite materials containing 10% Portland cement, 70% and 60% fly ash and 20% and 30% tire rubber particles have sufficient strength for masonry applications.

Energy content of municipal solid waste bales.

PubMed

Ozbay, Ismail; Durmusoglu, Ertan

2013-07-01

Baling technology is a preferred method for temporary storage of municipal solid waste (MSW) prior to final disposal. If incineration is intended for final disposal of the bales, the energy content of the baled MSW gains importance. In this study, nine cylindrical bales containing a mix of different waste materials were constructed and several parameters, including total carbon (TC), total organic carbon (TOC), total Kjeldahl nitrogen, moisture content, loss on ignition, gross calorific value and net calorific value (NCV) were determined before the baling and at the end of 10 months of storage. In addition, the relationships between the waste materials and the energy contents of the bales were investigated by the bivariate correlation analyses. At the end, linear regression models were developed in order to forecast the decrease of energy content during storage. While the NCVs of the waste materials before the baling ranged between 6.2 and 23.7 MJ kg(-1) dry basis, they ranged from 1.0 to 16.4 MJ kg(-1) dry basis at the end of the storage period. Moreover, food wastes exhibited the highest negative correlation with NCVs, whereas plastics have significant positive correlation with both NCVs and TCs. Similarly, TOCs and carbon/nitrogen ratios decreased with the increase in food amounts inside the bales. In addition, textile, wood and yard wastes increase the energy content of the bales slightly over the storage period.

Skylab

NASA Image and Video Library

1972-05-01

This image is a wide-angle view of the Orbital Workshop waste management compartment. The waste management facilities presented a unique challenge to spacecraft designers. In addition to collection of liquid and solid human wastes, there was a medical requirement to dry all solid human waste products and to return the residue to Earth for examination. Liquid human waste (urine) was frozen for return to Earth. Total quantities of each astronaut's liquid and solid wastes were precisely measured. Cabin air was drawn into the toilet, shown on the wall at right in this photograph, and over the waste products to generate a flow of the waste in the desired direction. The air was then filtered for odor control and antiseptic purposes prior to being discharged back into the cabin.

Improved method and composition for immobilization of waste in cement-based material

DOEpatents

Tallent, O.K.; Dodson, K.E.; McDaniel, E.W.

1987-10-01

A composition and method for fixation or immobilization of aqueous hazardous waste material in cement-based materials (grout) is disclosed. The amount of drainable water in the cured grout is reduced by the addition of an ionic aluminum compound to either the waste material or the mixture of waste material and dry-solid cement- based material. This reduction in drainable water in the cured grout obviates the need for large, expensive amounts of gelling clays in grout materials and also results in improved consistency and properties of these cement-based waste disposal materials.

Design and Testing of a Lyophilizer for Water Recovery from Solid Waste

NASA Technical Reports Server (NTRS)

Litwiller, Eric; Fisher, John; Flynn, Michael

2005-01-01

Mixed liquid/solid wastes, including feces, water processor effluents, and food waste, can be lyophilized (freeze-dried) to recover the water they contain and stabilize the solids remain. Previous research has demonstrated the potential benefits of using thermoelectric heat pumps to build a lyophilizer for processing waste in microgravity. These results were used to build a working prototype suitable for ground-based human testing. This paper describes the prototype design and presents the results of functional and performance tests. Equivalent system mass parameters are calculated, and practical issues such as sanitary waste handling in microgravity are addressed.

Evaluation of biogas production by dry anaerobic digestion of switchgrass-animal manure mixtures

USDA-ARS?s Scientific Manuscript database

Anaerobic digestion is a biological method used to convert organic wastes into a stable product for land application without adverse environmental effects. The biogas produced can be used as an alternative renewable energy source. Dry anaerobic digestion (> 15% TS; total solid) has an advantage ov...

The effects of recycling loops in food waste management in Japan: based on the environmental and economic evaluation of food recycling.

PubMed

Takata, Miki; Fukushima, Kazuyo; Kino-Kimata, Noriko; Nagao, Norio; Niwa, Chiaki; Toda, Tatsuki

2012-08-15

In Japan, a revised Food Recycling Law went into effect in 2007 to promote a "recycling loop" that requires food industries to purchase farm products that are grown using food waste-derived compost/animal feed. To realize and expand food recycling, it is necessary to evaluate how the recycling facilities work in the recycling loop. The purpose of this study is to assess the environmental and economic efficiency of the food recycling facilities that are involved in the recycling loop, which are also known as looped facilities. The global warming potential and running cost of five looped facilities were evaluated by LCA (life cycle assessment) and LCC (life cycle cost) approaches: machine integrated compost, windrow compost, liquid feed, dry feed, and bio-gasification. The LCA results showed low total GHG (greenhouse gas) emissions of -126 and -49 kg-CO(2)/t-waste, respectively, for dry feed and bio-gasification facilities, due to a high substitution effect. The LCC study showed a low running cost for composting facilities of -15,648 and -18,955 yen/t-waste, respectively, due to high revenue from the food waste collection. It was found that the mandatory reporting of food waste emitters to the government increased collection fees; however, the collection fee in animal feed facilities was relatively low because food waste was collected at a low price or nutritious food waste was purchased to produce quality feed. In the characterisation survey of various treatment methods, the composting facilities showed a relatively low environmental impact and a high economic efficiency. Animal feed facilities had a wide distribution of the total GHG emissions, depending on both the energy usage during the drying process and the substitution effect, which were related to the water content of the food waste and the number of recycled products. In comparison with incineration, the majority of the food recycling facilities showed low GHG emissions and economic effectiveness. This paper also reported on the effects of recycling loops by comparing looped and non-looped animal feed facilities, and confirmed that the looped facilities were economically effective, due to an increased amount of food waste collection. Copyright © 2012 Elsevier B.V. All rights reserved.

The production of chemicals from food processing wastes using a novel fermenter separator. Annual progress report, January 1993--March 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dale, M.C.; Venkatesh, K.V.; Choi, H.

The basic objective of this project is to convert waste streams from the food processing industry to usable fuels and chemicals using novel bioreactors. These bioreactors should allow economical utilization of waste (whey, waste sugars, waste starch, bottling wastes, candy wastes, molasses, and cellulosic wastes) by the production of ethanol, acetone/butanol, organic acids (acetic, lactic, and gluconic), yeast diacetyl flavor, and antifungal compounds. Continuous processes incorporating various processing improvements such as simultaneous product separation and immobilized cells are being developed to allow commercial scale utilization of waste stream. The production of ethanol by a continuous reactor-separator is the process closestmore » to commercialization with a 7,500 liter pilot plant presently sited at an Iowa site to convert whey lactose to ethanol. Accomplishments during 1993 include installation and start-up of a 7,500 liter ICRS for ethanol production at an industry site in Iowa; Donation and installation of a 200 liter yeast pilot Plant to the project from Kenyon Enterprises; Modeling and testing of a low energy system for recovery of ethanol from vapor is using a solvent absorption/extractive distillation system; Simultaneous saccharification/fermentation of raw corn grits and starch in a stirred reactor/separator; Testing of the ability of `koji` process to ferment raw corn grits in a `no-cook` process.« less

Simultaneous utilization of soju industrial waste for silica production and its residue ash as effective cationic dye adsorbent

USDA-ARS?s Scientific Manuscript database

Soju industrial waste is an important biomass resource. The present study is aimed to utilize soju industrial waste for silica extraction, and residual ash as a low cost adsorbent for the removal of Methylene Blue (MB) from aqueous solution. High percentage of pure amorphous nanosilica was obtained ...

Hydrothermal carbonization of biomass residuals: A comparative review of the chemistry, processes and applications of wet and dry pyrolysis

USDA-ARS?s Scientific Manuscript database

This paper reviews chemistry, processes and application of hydrothermcally carbonized biomass wastes. Potential feedstock for the hydrothermal carbonization (HTC) includes variety of the non-traditional renewable wet agricultural and municipal waste streams. Pyrolysis and HTC show a comparable calor...

75 FR 39008 - Environmental Management Site-Specific Advisory Board, Idaho National Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-07

... Dry Storage. Waste Area Group--7 Update. In-Situ Grouting. Comment Resolution--Environmental... meeting be announced in the Federal Register. DATES: Wednesday, July 14, 2010 8 a.m.-5 p.m. Opportunities... management in the areas of environmental restoration, waste management, and related activities. Tentative...

Steroid hormones in biosolids and poultry litter: a comparison of potential environmental inputs.

PubMed

Bevacqua, Christine E; Rice, Clifford P; Torrents, Alba; Ramirez, Mark

2011-05-01

Steroid hormones can act as potent endocrine disruptors when released into the environment. The main sources of these chemicals are thought to be wastewater treatment plant discharges and waste from animal feeding operations. While these compounds have frequently been found in wastewater effluents, few studies have investigated biosolids or manure, which are routinely land applied, as potential sources. This study assessed the potential environmental contribution of steroid hormones from biosolids and chicken litter. Hormone concentrations in samples of limed biosolids collected at a waste treatment plant over a four year period ranged from <2.5 to 21.7ng/g dry weight for estrone (E1) and <2.5 to 470ng/g dry weight for progesterone. Chicken litter from 12 mid-Atlantic farms had averages of 41.4ng/g dry weight E1, 63.4ng/g dry weight progesterone, and 19.2ng/g dry weight E1-sulfate (E1-S). Other analytes studied were 17β-estradiol (E2), estriol (E3), 17α-ethinylestradiol (EE2), testosterone, E2-3-sulfate (E2-3-S), and E2-17-sulfate (E2-17-3). Copyright © 2011 Elsevier B.V. All rights reserved.

Space-time mapping of wasting among children under the age of five years in Somalia from 2007 to 2010.

PubMed

Kinyoki, Damaris K; Berkley, James A; Moloney, Grainne M; Odundo, Elijah O; Kandala, Ngianga-Bakwin; Noor, Abdisalan M

2016-02-01

To determine the sub-national seasonal prevalence and trends in wasting from 2007 to 2010 among children aged 6-59 months in Somalia using remote sensing and household survey data from nutritional surveys. Bayesian hierarchical space-time model was implemented using a stochastic partial differential equation (SPDE) approach in integrated nested Laplace approximations (INLA) to produce risk maps of wasting at 1 × 1 km(2) spatial resolution and predict to seasons in each year of study from 2007 to 2010. The prevalence of wasting was generally at critical levels throughout the country, with most of the areas remaining in the upper classes of critical and very critical levels. There was minimal variation in wasting from year-to-year, but a well-defined seasonal variation was observed. The mean difference of the prevalence of wasting between the dry and wet season ranges from 0% to 5%. The risks of wasting in the South Central zone were highest in the Gedo (37%) and Bay (32%) regions. In North East zone the risk was highest in Nugaal (25%) and in the North West zone the risk was high in Awdal and Woqooyi Galbeed regions with 23%. There was a clear seasonal variation in wasting with minimal year-to-year variability from 2007 to 2010 in Somalia. The prevalence was high during the long dry season, which affects the prevalence in the preceding long rainy season. Understanding the seasonal fluctuations of wasting in different locations and at different times is important to inform timely interventions. Copyright © 2016. Published by Elsevier Ltd.

Use of Drying Technologies for Resource Recovery from Solid Wastes and Brines

NASA Technical Reports Server (NTRS)

Wignarajah, Kanapathipillai; Alba, Ric; Fisher, John W.; Hogan, John A.; Polonsky, Alex

2010-01-01

Long term storage of unprocessed biological wastes and human wastes can present major health issues and a loss of potential resources. Space vehicles and planetary habitats are typically resource-scarce or resource-limited environments for long-term human habitation. To-date, most of the resources will need to be supplied from Earth, but this may not be possible for long duration human exploration. Based on present knowledge, there is only very limited in-situ resources on planetary habitats. Hence, the opportunity to "live off the land" in a planetary habitat is limited. However, if we assume that wastes generated by human explorers are viewed as resources, there is great potential to utilize and recycle them, thereby reducing the requirements for supply Earth and enabling the "live off the land" exploration scenario. Technologies used for the recovery of resources from wastes should be reliable, safe, easy to operate, fail-proof, modular, automated and preferably multifunctional in being capable of handling mixed solid and liquid wastes. For a lunar habitat, energy does not appear to be the major driving factor amongst the technologies studied. Instead, reliability appears to be more important[1] . This paper reports studies to date on drying technologies to remove water from solid wastes and brines. Experimental performance data obtained for recovery water from wastes and brine are presented. Simplicity of operation of hardware and energy efficiency are discussed. Some improvements and modifications to hardware were performed. Hopefully, this information will assist in future efforts in the "downselection" of technologies for recovery of water and resources from solid wastes and brines.

Biological treatment of chicken feather waste for improved biogas production.

PubMed

Forgács, Gergely; Alinezhad, Saeid; Mirabdollah, Amir; Feuk-Lagerstedt, Elisabeth; Horváth, Ilona Sárvári

2011-01-01

A two-stage system was developed which combines the biological degradation of keratin-rich waste with the production of biogas. Chicken feather waste was treated biologically with a recombinant Bacillus megaterium strain showing keratinase activity prior to biogas production. Chopped, autoclaved chicken feathers (4%, W/V) were completely degraded, resulting in a yellowish fermentation broth with a level of 0.51 mg/mL soluble proteins after 8 days of cultivation of the recombinant strain. During the subsequent anaerobic batch digestion experiments, methane production of 0.35 Nm3/kg dry feathers (i.e., 0.4 Nm3/kg volatile solids of feathers), corresponding to 80% of the theoretical value on proteins, was achieved from the feather hydrolyzates, independently of the pre-hydrolysis time period of 1, 2 or 8 days. Cultivation with a native keratinase producing strain, Bacillus licheniformis resulted in only 0.25 mg/mL soluble proteins in the feather hydrolyzate, which then was digested achieving a maximum accumulated methane production of 0.31 Nm3/kg dry feathers. Feather hydrolyzates treated with the wild type B. megaterium produced 0.21 Nm3 CH4/kg dry feathers as maximum yield.

Developing a model for moisture in saltcake waste tanks: Progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simmons, C.S.; Aimo, N.; Fayer, M.J.

1997-07-01

This report describes a modeling effort to provide a computer simulation capability for estimating the distribution and movement of moisture in the saltcake-type waste contained in Hanford`s single-shell radioactive waste storage tanks. This moisture model goes beyond an earlier version because it describes water vapor movement as well as the interstitial liquid held in a saltcake waste. The work was performed by Pacific Northwest National Laboratory to assist Duke Engineering and Services Hanford with the Organic Tank Safety Program. The Organic Tank Safety Program is concerned whether saltcake waste, when stabilized by jet pumping, will retain sufficient moisture near themore » surface to preclude any possibility of an accidental ignition and propagation of burning. The nitrate/nitrite saltcake, which might also potentially include combustible organic chemicals might not always retain enough moisture near the surface to preclude any such accident. Draining liquid from a tank by pumping, coupled with moisture evaporating into a tank`s head space, may cause a dry waste surface that is not inherently safe. The moisture model was devised to help examine this safety question. The model accounts for water being continually cycled by evaporation into the head space and returned to the waste by condensation or partly lost through venting to the external atmosphere. Water evaporation occurs even in a closed tank, because it is driven by the transfer to the outside of the heat load generated by radioactivity within the waste. How dry a waste may become over time depends on the particular hydraulic properties of a saltcake, and the model uses those properties to describe the capillary flow of interstitial liquid as well as the water vapor flow caused by thermal differences within the porous waste.« less

Data sharing report characterization of population 7: Personal protective equipment, dry active waste, and miscellaneous debris, surveillance and maintenance project Oak Ridge National Laboratory Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harpenau, Evan M.

2013-10-10

The U.S. Department of Energy (DOE) Oak Ridge Office of Environmental Management (EM-OR) requested that Oak Ridge Associated Universities (ORAU), working under the Oak Ridge Institute for Science and Education (ORISE) contract, provide technical and independent waste management planning support under the American Recovery and Reinvestment Act (ARRA). Specifically, DOE EM-OR requested that ORAU plan and implement a sampling and analysis campaign targeting certain URS|CH2M Oak Ridge, LLC (UCOR) surveillance and maintenance (S&M) process inventory waste. Eight populations of historical and reoccurring S&M waste at the Oak Ridge National Laboratory (ORNL) have been identified in the Waste Handling Plan formore » Surveillance and Maintenance Activities at the Oak Ridge National Laboratory, DOE/OR/01-2565&D2 (WHP) (DOE 2012) for evaluation and processing to determine a final pathway for disposal. Population 7 (POP 7) consists of 56 containers of aged, low-level and potentially mixed S&M waste that has been staged in various locations around ORNL. Several of these POP 7 containers primarily contain personal protective equipment (PPE) and dry active waste (DAW), but may contain other miscellaneous debris. This data sharing report addresses the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) specified waste in a 13-container subpopulation (including eight steel boxes, three 55-gal drums, one sealand, and one intermodal) that lacked sufficient characterization data for possible disposal at the Environmental Management Waste Management Facility (EMWMF) using the approved Waste Lot (WL) 108.1 profile.« less

Effects of Moisture Content in Solid Waste Landfills

DTIC Science & Technology

2000-03-01

C02 + CH4 + NH3 + H2S + Heat The biological conversion of the organic fraction of the solid waste during anaerobic transformation is thought to occur...of placement (Blight, 1995: 11). In dry climates, the field capacity of the waste may never be naturally reached. Conversely , in a wet climate, the...detected in the cellulase activity (Barlaz and others, 1990: 570). Protease, amylase, and cellulase are the enzymes that degrade proteins, starches, and

Final Environmental Impact Statement for Treating Transuranic (TRU)/Alpha Low-level Waste at the Oak Ridge National Laboratory Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

N /A

2000-06-30

The DOE proposes to construct, operate, and decontaminate/decommission a TRU Waste Treatment Facility in Oak Ridge, Tennessee. The four waste types that would be treated at the proposed facility would be remote-handled TRU mixed waste sludge, liquid low-level waste associated with the sludge, contact-handled TRU/alpha low-level waste solids, and remote-handled TRU/alpha low-level waste solids. The mixed waste sludge and some of the solid waste contain metals regulated under the Resource Conservation and Recovery Act and may be classified as mixed waste. This document analyzes the potential environmental impacts associated with five alternatives--No Action, the Low-Temperature Drying Alternative (Preferred Alternative), themore » Vitrification Alternative, the Cementation Alternative, and the Treatment and Waste Storage at Oak Ridge National Laboratory (ORNL) Alternative.« less

Generation rates and chemical compositions of waste streams in a typical crewed space habitat

NASA Technical Reports Server (NTRS)

Wydeven, Theodore; Golub, Morton A.

1990-01-01

A judicious compilation of generation rates and chemical compositions of potential waste feed streams in a typical crewed space habitat was made in connection with the waste-management aspect of NASA's Physical/Chemical Closed-Loop Life Support Program. Waste composition definitions are needed for the design of waste-processing technologies involved in closing major life support functions in future long-duration human space missions. Tables of data for the constituents and chemical formulas of the following waste streams are presented and discussed: human urine, feces, hygiene (laundry and shower) water, cleansing agents, trash, humidity condensate, dried sweat, and trace contaminants. Tables of data on dust generation and pH values of the different waste streams are also presented and discussed.

Synthesis of nano-crystalline hydroxyapatite and ammonium sulfate from phosphogypsum waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mousa, Sahar, E-mail: dollyriri@yahoo.com; King Abdulaziz University, Science and Art College, Chemistry Department, Rabigh Campus, P.O. Box:344, Postal code: 21911 Rabigh; Hanna, Adly

2013-02-15

Graphical abstract: TEM micrograph of dried HAP at 800 °C. -- Abstract: Phosphogypsum (PG) waste which is derived from phosphoric acid manufacture by using wet method was converted into hydroxyapatite (HAP) and ammonium sulfate. Very simple method was applied by reacting PG with phosphoric acid in alkaline medium with adjusting pH using ammonia solution. The obtained nano-HAP was dried at 80 °C and calcined at 600 °C and 900 °C for 2 h. Both of HAP and ammonium sulfate were characterized by X-ray diffraction (XRD) and infrared spectroscopy (IR) to study the structural evolution. The thermal behavior of nano-HAP wasmore » studied; the particle size and morphology were estimated by using transmission electron microscopy (TEM) and scanning electron microscopy (SEM). All the results showed that HAP nano-crystalline and ammonium sulfate can successfully be produced from phosphogypsum waste.« less

Valorisation of food waste to produce new raw materials for animal feed.

PubMed

San Martin, D; Ramos, S; Zufía, J

2016-05-01

This study assesses the suitability of vegetable waste produced by food industry for use as a raw material for animal feed. It includes safety and nutritional viability, technical feasibility and environmental evaluation. Vegetable by-products were found to be nutritionally and sanitarily appropriate for use in animal feed. The drying technologies tested for making vegetable waste suitable for use in the animal feed market were pulse combustion drying, oven and microwave. The different meal prototypes obtained were found to comply with all the requirements of the animal feed market. An action plan that takes into account all the stages of the valorisation process was subsequently defined in agreement with local stakeholders. This plan was validated in a pilot-scale demonstration trial. Finally, the technical feasibility was studied and environmental improvement was performed. This project was funded by the European LIFE+ program (LIFE09 ENV/ES/000473). Copyright © 2015 Elsevier Ltd. All rights reserved.

Papaya drying and waste conversion system. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-02-12

This project, performed under United States Department of Energy Small-scale Appropriate Energy Technology Grant, involves demonstration of an integrated system using solar energy to process off-grade or reject fruit into marketable food products. The integrated system consists of three phases: (1) solar dehydration of usable fruit; (2) solar vacuum distillation of fermented wastes (peelings, rinds, skins, and seeds) to produce an ethanol fuel to use as a backup source of heat for dehydration; and (3) land reclamation by mixing stillage and compost with volcanic cinder and ash to produce on marginal land a rich soil suitable for growing more cropsmore » to dry. Although the system is not 100% complete the investigators have demonstrated that a small business can efficiently use solar energies in an integrated fashion to process waste into food, improve the quality of the land, and provide meaningful jobs in a region of very high unemployment.« less

Contact drying: a review of experimental and mechanistic modeling approaches.

PubMed

Sahni, Ekneet Kaur; Chaudhuri, Bodhisattwa

2012-09-15

Drying is one of the most complex unit operations with simultaneous heat and mass transfer. The contact drying process is also not well understood as several physical phenomena occur concurrently. This paper reviews current experimental and modeling approaches employed towards a better understanding of the contact drying operation. Additionally, an overview of some fundamental aspects relating to contact drying is provided. A brief discussion of some model extensions such as incorporation of noncontact forces, interstitial fluids and attrition rate is also presented. Copyright © 2012 Elsevier B.V. All rights reserved.

In-situ transesterification of wet spent coffee grounds for sustainable biodiesel production.

PubMed

Park, Jeongseok; Kim, Bora; Lee, Jae W

2016-12-01

This work addresses in-situ transesterification of wet spent coffee grounds (SCGs) for the production of biodiesel. For in-situ transesterification process, the methanol, organic solvent and acid catalyst were mixed with wet SCG in one pot and the mixture was heated for simultaneous lipid extraction and transesterification. Maximum yield of fatty acid methyl esters (FAME) was 16.75wt.% based on the weight of dry SCG at 95°C. Comprehensive experiments were conducted with varying temperatures and various amounts of moisture, methanol, co-solvent and acid catalyst. Moderate polar and alcohol-miscible organic solvent is suitable for the high FAME yield. Unsaturated FAMEs are subject to oxidative cleavage by nitric acid and shorter chain (C6 and C10) FAMEs were mainly produced while sulfuric acid yielded long chain unsaturated FAMEs (C16 and C18). Utilization of wet SCGs as a biodiesel feedstock gives economic and environmental benefits by recycling the municipal waste. Copyright © 2016 Elsevier Ltd. All rights reserved.

Anther evolution: pollen presentation strategies when pollinators differ.

PubMed

Castellanos, Maria Clara; Wilson, Paul; Keller, Sarah J; Wolfe, Andrea D; Thomson, James D

2006-02-01

Male-male competition in plants is thought to exert selection on flower morphology and on the temporal presentation of pollen. Theory suggests that a plant's pollen dosing strategy should evolve to match the abundance and pollen transfer efficiency of its pollinators. Simultaneous pollen presentation should be favored when pollinators are infrequent or efficient at delivering the pollen they remove, whereas gradual dosing should optimize delivery by frequent and wasteful pollinators. Among Penstemon and Keckiella species, anthers vary in ways that affect pollen release, and the morphology of dried anthers reliably indicates how they dispense pollen. In these genera, hummingbird pollination has evolved repeatedly from hymenopteran pollination. Pollen production does not change with evolutionary shifts between pollinators. We show that after we control for phylogeny, hymenopteran-adapted species present their pollen more gradually than hummingbird-adapted relatives. In a species pair that seemed to defy the pattern, the rhythm of anther maturation produced an equivalent dosing effect. These results accord with previous findings that hummingbirds can be more efficient than bees at delivering pollen.

Bioactive compounds and antioxidant activity in scalded Jalapeño pepper industrial byproduct (Capsicum annuum).

PubMed

Sandoval-Castro, Claudia Jaqueline; Valdez-Morales, Maribel; Oomah, B Dave; Gutiérrez-Dorado, Roberto; Medina-Godoy, Sergio; Espinosa-Alonso, L Gabriela

2017-06-01

Bioactive compounds and antioxidant activity were evaluated from industrial Jalapeño pepper byproducts and simulated non processed byproducts from two Mexican states (Chihuahua and Sinaloa) to determine their value added potential as commercial food ingredients. Aqueous 80% ethanol produced about 13% of dry extract of polar compounds. Total phenolic content increased and capsaicin and dihydrocapsaicin decreased on scalding samples (80 °C, 2 min) without affecting ascorbic acid. The major phenolic compounds, rutin, epicatechin and catechin comprised 90% of the total compounds detected by HPLC of each Jalapeño pepper byproducts. ORAC analysis showed that the origin and scalding process affected the antioxidant activity which correlated strongly with capsaicin content. Although scalding decreased capsaicinoids (up to 42%), phenolic content by (up to 16%), and the antioxidant activity (variable). Jalapeño pepper byproduct is a good source of compounds with antioxidant activity, and still an attractive ingredient to develop useful innovative products with potential food/non-food applications simultaneously reducing food loss and waste.

Optimization of fermentation parameters for production of ethanol from kinnow waste and banana peels by simultaneous saccharification and fermentation.

PubMed

Sharma, Naresh; Kalra, K L; Oberoi, Harinder Singh; Bansal, Sunil

2007-12-01

A study was taken up to evaluate the role of some fermentation parameters like inoculum concentration, temperature, incubation period and agitation time on ethanol production from kinnow waste and banana peels by simultaneous saccharification and fermentation using cellulase and co-culture of Saccharomyces cerevisiae G and Pachysolen tannophilus MTCC 1077. Steam pretreated kinnow waste and banana peels were used as substrate for ethanol production in the ratio 4:6 (kinnow waste: banana peels). Temperature of 30°C, inoculum size of S. cerevisiae G 6% and (v/v) Pachysolen tannophilus MTCC 1077 4% (v/v), incubation period of 48 h and agitation for the first 24 h were found to be best for ethanol production using the combination of two wastes. The pretreated steam exploded biomass after enzymatic saccharification containing 63 gL(-1) reducing sugars was fermented with both hexose and pentose fermenting yeast strains under optimized conditions resulting in ethanol production, yield and fermentation efficiency of 26.84 gL(-1), 0.426 gg (-1) and 83.52 % respectively. This study could establish the effective utilization of kinnow waste and banana peels for bioethanol production using optimized fermentation parameters.

Efficiency and design analysis of a solar thermal powered flat plate dryer (abstract)

USDA-ARS?s Scientific Manuscript database

Specialty crop fruit and vegetable pomaces are a common byproduct of the food processing and juicing industries. These pomaces can have high nutritional value, but are currently underutilized or treated as waste. Drum drying is one method that could be adopted to dry and stabilize fruit and vegetabl...

NAICS Impact on Small Business Set-Asides

DTIC Science & Technology

2014-12-01

APPENDIX C. AIRFIELD DEMOLITION SOLICITATION ...............................83 APPENDIX D. HAZARDOUS AND TOXIC WASTE REMOVAL SOLICITATION...Suitability for Transfer GPE government-wide point of entry GSA General Services Administration HTW hazardous and toxic waste HUBZone...Oilseed (except Soybean) Farming $0.75 111130 Dry Pea and Bean Farming $0.75 Subsector 112 – Animal Production 112111 Beef Cattle

High-Performance Computing Data Center | Computational Science | NREL

Science.gov Websites

liquid cooling to achieve its very low PUE, then captures and reuses waste heat as the primary heating dry cooler that uses refrigerant in a passive cycle to dissipate heat-is reducing onsite water Measuring efficiency through PUE Warm-water liquid cooling Re-using waste heat from computing components

40 CFR 60.52b - Standards for municipal waste combustor metals, acid gases, organics, and nitrogen oxides.

Code of Federal Regulations, 2010 CFR

2010-07-01

... SOURCES Standards of Performance for Large Municipal Waste Combustors for Which Construction is Commenced... section. (i) For affected facilities that commenced construction, modification, or reconstruction after September 20, 1994, and on or before December 19, 2005, the emission limit is 24 milligrams per dry standard...

Archaeal community dynamics and abiotic characteristics in a mesophilic anaerobic co-digestion process treating fruit and vegetable processing waste sludge with chopped fresh artichoke waste.

PubMed

Ros, M; Franke-Whittle, I H; Morales, A B; Insam, H; Ayuso, M; Pascual, J A

2013-05-01

This study evaluated the feasibility of obtaining methane in anaerobic digestion (AD) from the waste products generated by the processing of fruit and vegetables. During the first phase (0-55 d) of the AD using sludge from fruit and vegetable processing, an average value of 244±88 L kg(-1) dry matter d(-1)of biogas production was obtained, and methane content reached 65% of the biogas. Co-digestion with chopped fresh artichoke wastes in a second phase (55-71 d) enhanced biogas production, and resulted in an average value of 354±68 L kg(-1) dry matter d(-1), with higher methane content (more than 70%). The archaeal community involved in methane production was studied using the ANAEROCHIP microarray and real-time PCR. Results indicated that species of Methanosaeta and Methanosarcina were important during the AD process. Methanosarcina numbers increased after the addition of chopped fresh artichoke, while Methanosaeta numbers decreased. Copyright © 2013 Elsevier Ltd. All rights reserved.

Water hyacinths for water quality improvement and biomass production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reddy, K.R.; Sutton, D.L.

The potential use of water hyacinth (Eichhornia crassipes (Mart.) Solms) for biomass production and for nutrient removal from waste waters is discussed. Warm climates in tropical and subtropical areas are conducive for establishing waste water treatment systems and biomass production farms with water hyacinth. Sources of nutrients available to culture water hyacinths include sewage effluent, agricultural drainage water, runoff from animal waste operations, methane digestor effluent, and water from eutrophic lakes and rivers. Growth rates of water hyacinths were found to be influenced by the nutrient composition of the water, plant density, solar radiation, and temperature. Annual yields of watermore » hyacinth biomass were found to range from 47 to 106 Mg dry wt ha/sup -1/ y/sup -1/, with approximately 50% of the biomass produced during May through August. A pond with a surface area of 2.65 ha and 1.0 m in depth containing 15 to 30 kg wet wt of water hyacinth per square meter (750-1500 g dry wt m/sup -2/) and a detention period of 7 d is adequate to treat 3785 m/sup 3/ d/sup -1/ (million gallons per day (mdg)) of sewage effluent. This hypothetical system would achieve 70 to 80% N removal, 40 to 50% P removal, and would produce a biomass yield of 690 to 1060 kg dry wt d/sup -1/ (13-20 g dry wt m/sup -2/ d/sup -1/). The biomass upon anaerobic digestion would yield 180 to 280 m/sup 3/ of methane/d. This is equivalent to 549 to 843 GJ ha/sup -1/ of energy from water hyacinth produced at a rate of 48 to 73 Mg dry wt ha/sup -1/ y/sup -1/.« less

Material and energy recovery in integrated waste management systems: an innovative approach for the characterization of the gaseous emissions from residual MSW bio-drying.

PubMed

Ragazzi, M; Rada, E C; Antolini, D

2011-01-01

In the sector of residual municipal solid waste management an increasing attention is put towards the role of biological treatments like bio-drying and bio-stabilization in order to decrease the need of landfilling volumes. The literature shows a lack of information concerning the emission factor of pollutants released from these processes. The available data are generally spot characterizations of concentration and air flow-rate that are used together in order to assess the emission factors. This approach caused significant differences among the available data as the release of pollutants is not steady. This paper belongs to a group of six papers concerning a research on material and energy recovery in integrated waste management systems, developed by a network of five universities. The contribution of the University of Trento, focuses on the bio-drying process with the following targets: (a) developing an innovative low cost method of sampling/measurement able to take into account the dynamics of release of pollutants; (b) checking the efficiency of a bio-filter; (c) verifying the variability of generation of some pollutants; (d) generating emission factors. The research was developed using a bio-drying pilot plant. As a treatment of the process air, the bio-reactor was coupled with a bio-filter. The emissions were characterized using an original approach based on the adoption of two measurement chambers suitable for hosting passive samplers. The passive samplers allowed the characterization of VOCs, N(2)O, NH(3) and H(2)S. A bio-chemical model, useful for energy and mass balances, supported the interpretation of the presented bio-drying run. Copyright © 2011 Elsevier Ltd. All rights reserved.

Limits to the use of highly compacted bentonite as a deterrent for microbiologically influenced corrosion in a nuclear fuel waste repository

NASA Astrophysics Data System (ADS)

Stroes-Gascoyne, Simcha; Hamon, Connie J.; Maak, Peter

Recent studies have suggested that microbial activity in highly compacted bentonite (⩾1600 kg/m 3) is severely suppressed. Therefore, it appears that the dry density of emplaced bentonite barriers in a geological repository for nuclear waste may be tailored such that a microbiologically unfavorable environment can be created adjacent to used fuel containers. This would ensure that microbiologically influenced corrosion is a negligible contributor to the overall corrosion process. However, this premise is valid only as long as the emplaced bentonite maintains a uniform high dry density (⩾1600 kg/m 3) because it has been shown that high dry density only suppresses microbial activity but not necessarily eliminates the viable microbial population in bentonite. In a repository, a reduction in the dry density of highly compacted bentonite may occur at a number of interface locations, such as placement gaps, contact regions with materials of different densities and contact points with water-carrying fractures in the rock. Experiments were carried out in our laboratory to examine the effects of a reduction in dry density (from 1600 kg/m 3 to about 1000 kg/m 3) on the recovery of microbial culturability in compacted bentonite. Results showed that upon expansion of compacted bentonite into a void, the resulting reduction in dry density stimulated or restored culturability of indigenous microbes. In a repository this would increase the possibility of in situ activity, which might be detrimental for the longevity of waste containers. Reductions in dry density, therefore, should be minimized or eliminated by adequate design and placement methods of compacted bentonite. Materials compliance models can be used to determine the required as-placed dry densities of bentonite buffer and gap fillings to achieve specific targets for long-term equilibrium dry densities for various container placement room designs. Locations where flowing fractures could be in contact with highly compacted bentonite should either be avoided or grouted adequately to limit contact between bentonite and flowing water. Even if localized enhanced microbial activity at interfaces remains of concern, despite adequate engineering and placement methods, the potential consequences can be assessed and quantified adequately by a combination of in situ activity measurements and modeling calculations.

RELEASE OF DRIED RADIOACTIVE WASTE MATERIALS TECHNICAL BASIS DOCUMENT

DOE Office of Scientific and Technical Information (OSTI.GOV)

KOZLOWSKI, S.D.

2007-05-30

This technical basis document was developed to support RPP-23429, Preliminary Documented Safety Analysis for the Demonstration Bulk Vitrification System (PDSA) and RPP-23479, Preliminary Documented Safety Analysis for the Contact-Handled Transuranic Mixed (CH-TRUM) Waste Facility. The main document describes the risk binning process and the technical basis for assigning risk bins to the representative accidents involving the release of dried radioactive waste materials from the Demonstration Bulk Vitrification System (DBVS) and to the associated represented hazardous conditions. Appendices D through F provide the technical basis for assigning risk bins to the representative dried waste release accident and associated represented hazardous conditionsmore » for the Contact-Handled Transuranic Mixed (CH-TRUM) Waste Packaging Unit (WPU). The risk binning process uses an evaluation of the frequency and consequence of a given representative accident or represented hazardous condition to determine the need for safety structures, systems, and components (SSC) and technical safety requirement (TSR)-level controls. A representative accident or a represented hazardous condition is assigned to a risk bin based on the potential radiological and toxicological consequences to the public and the collocated worker. Note that the risk binning process is not applied to facility workers because credible hazardous conditions with the potential for significant facility worker consequences are considered for safety-significant SSCs and/or TSR-level controls regardless of their estimated frequency. The controls for protection of the facility workers are described in RPP-23429 and RPP-23479. Determination of the need for safety-class SSCs was performed in accordance with DOE-STD-3009-94, Preparation Guide for US. Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses, as described below.« less

Simultaneous measurement of tear film dynamics using wavefront sensor and optical coherence tomography.

PubMed

Koh, Shizuka; Tung, Cynthia; Aquavella, James; Yadav, Rahul; Zavislan, James; Yoon, Geunyoung

2010-07-01

PURPOSE. To investigate tear film dynamics using simultaneous measurements of ocular aberrations and lower tear meniscus. METHODS. Simultaneous measurements of wavefront aberration and lower tear meniscus were performed for 11 normal eyes and 7 eyes with short tear film break-up time (SBUT) dry eye, with a tear film break-up time shorter than 5 seconds, using a wavefront sensor and an anterior segment optical coherence tomography (OCT). During the measurement, the subjects were instructed to blink every 6 seconds for a total of 30 seconds. From the measured aberration, root mean square (RMS) wavefront error and volume modulation transfer function (vMTF) induced by changes in tear film dynamics were calculated for a 5-mm pupil. Lower tear meniscus height (TMH) and area (TMA) were estimated from the cross-sectional OCT images of lower tear meniscus. RESULTS. There was a positive correlation between RMS and tear meniscus dimensions and a negative correlation between vMTF and tear meniscus in both groups. There were moderate negative correlations between the postblink initial RMS change and baseline TMH (R = -0.61) and TMA (R = -0.54) in SBUT dry eyes that were stronger than in normal eyes (R = -0.37, R = -0.38). CONCLUSIONS. Tear meniscus dimensions increase with RMS over time, and tear quantity before blink has a significant role in maintaining initial optical integrity, especially in SBUT dry eye. Simultaneous measurement of optical quality and tear meniscus has the potential to improve understanding of tear stability in normal eyes and dry eyes.

Assessment of a combined dry anaerobic digestion and post-composting treatment facility for source-separated organic household waste, using material and substance flow analysis and life cycle inventory.

PubMed

Jensen, Morten Bang; Møller, Jacob; Scheutz, Charlotte

2017-08-01

The fate of total solids, volatile solids, total organic carbon, fossil carbon, biogenic carbon and 17 substances (As, Ca, CaCO 3 , Cd, Cl, Cr, Cu, H, Hg, K, Mg, N, Ni, O, P, Pb, S, Zn) in a combined dry anaerobic digestion and post-composting facility were assessed. Mass balances showed good results with low uncertainties for non-volatile substances, while balances for nitrogen, carbon, volatile solids and total organic carbon showed larger but reasonable uncertainties, due to volatilisation and emissions into the air. Material and substance flow analyses were performed in order to obtain transfer coefficients for a combined dry anaerobic digestion and post-composting facility. All metals passed through the facility and ended up in compost or residues, but all concentrations of metals in the compost complied with legislation. About 23% of the carbon content of the organic waste was transferred to the biogas, 24% to the compost, 13% to residues and 40% into the atmosphere. For nitrogen, 69% was transferred to the compost, 10% volatilised to the biofilter, 11% directly into the atmosphere and 10% to residues. Finally, a full life cycle inventory was conducted for the combined dry anaerobic digestion and post-composting facility, including waste received, fuel consumption, energy use, gaseous emissions, products, energy production and chemical composition of the compost produced. Copyright © 2017. Published by Elsevier Ltd.

Ethene removal from a synthetic waste gas using a dry biobed.

PubMed

De Heyder, B; Overmeire, A; Van Langenhove, H; Verstraete, W

1994-08-20

A packed granular activated carbon (GAC) biobed, inoculated with the ethane-degrading strain Mycobacterium E3, was used to study ethene removal from a synthetic waste gas. Ethene, for which the dimensionless partition coefficient for an air-water system at 20 degrees C is about 7.6, was used as a model compound for poorly water soluble gaseous pollutants. In a first mode or operation, the GAC biobed was sprinkled intermittently and the waste gas influent was continuously pre-humidified, establishing relatively moist conditions (water content >40% to 45%). A volumetric ethene removal rate of 0.382 kg COD x m(-3) x d(-1) (0.112 kg ethene x m(-3) x d(-1)) was obtained for an influent concentration of 125 ppm, a superficial waste gas velocity of 3.6E-3 m x s(-1) and a pseudo residence time of 45 s. However, in the second mode of operation, omitting the pre-humidification of the waste gas influent and establishing a "dry" biobed (water content <40% to 45%), and thus obtaining better mass transfer to the biofilm, the ethene removal could be doubled for otherwise comparable operating parameters. Furthermore, under decreased wetting and for the given experimental conditions (influent concentration 125 to 816 ppm, waste gas superficial velocity 3.0E-3 m x s(-1), pseudo waste gas residence time 43 s), the ethene removal was not limited by mass transfer of ethene through the water layer covering the biofilm.

A study of inter-particle bonds in dry bauxite waste resulting in atmospheric aerosols

NASA Astrophysics Data System (ADS)

Wagh, Arun S.; Thompson, Bentley

1988-02-01

Bauxite and Alumina production are one of the main activities of several third world countries such as Jamaica, Brazil, India, Guinea, eastern European countries such as Hungary and Rumania and advanced countries such as Australia, West Germany, Japan and the United States. The mining operations lead to dust pollution, but the refining of bauxite to alumina yield large amounts of highly caustic sludge waste, called "Red Mud". Millions of tons of the waste produced in every country are stored in containment dams or natural valleys. This leads to ground water pollution, destruction of plant and bird life and is hazardous to human settlement in earthquake prone regions like Jamaica. As a result several companies have been looking into dry mud stacking which involves thickening the mud in the refining plants and sprying it on the slopes to sun dry it. Typically it involves a drying field of about two hundred acres, which could act as a potential source of caustic dust. In Jamaica one company has started disposing of the mud in this way. The aerosol formation from such areas depends mainly on the integrity of the top dry layers. Presently this is done by studying the approximate parameters such as the friability of the mud. However, following the recent advances in powder technology it has been possible for us to develop an instrument to study the average interparticle forces between the red mud particles. The instrument is based on the principle of a tensometer and a split cell is used to load specimens. A load cell is used to measure the force and a chart recorder is used for plotting separation and the force. The present study reports elemental composition of the dust and its health hazards. It also reports the physical measurement of the average interparticle force as a function of their separation in the Jamaican mud. The effect of ultraviolet radiation on the strength of the material is studied to see the effect of sun-drying of the waste. The five-fold increase in tensile strength indicates that laterisation process is responsible for this phenomenon in Jamaican red mud. The study is crucial to the development of dust free mud stacking by the proper modifications in the process technology. Finally, such a case study is general enough in the characterisation of other sources of aerosols.

Engineering Yarrowia lipolytica to Simultaneously Produce Lipase and Single Cell Protein from Agro-industrial Wastes for Feed.

PubMed

Yan, Jinyong; Han, Bingnan; Gui, Xiaohua; Wang, Guilong; Xu, Li; Yan, Yunjun; Madzak, Catherine; Pan, Dujie; Wang, Yaofeng; Zha, Genhan; Jiao, Liangcheng

2018-01-15

Lipases are scarcely exploited as feed enzymes in hydrolysis of lipids for increasing energy supply and improving nutrient use efficiency. In this work, we performed homologous overexpression, in vitro characterization and in vivo assessment of a lipase from the yeast Yarrowia lipolytica for feed purpose. Simultaneously, a large amount of yeast cell biomass was produced, for use as single cell protein, a potential protein-rich feed resource. Three kinds of low cost agro-industrial wastes were tested as substrates for simultaneous production of lipase and single cell protein (SCP) as feed additives: sugarcane molasses, waste cooking oil and crude glycerol from biodiesel production. Sugarcane molasses appeared as the most effective cheap medium, allowing production of 16420 U/ml of lipase and 151.2 g/L of single cell protein at 10 liter fermentation scale. In vitro characterization by mimicking a gastro-intestinal environment and determination of essential amino acids of the SCP, and in vivo oral feeding test on fish all revealed that lipase, SCP and their combination were excellent feed additives. Such simultaneous production of this lipase and SCP could address two main concerns of feed industry, poor utilization of lipid and shortage of protein resource at the same time.

40 CFR Table 1a to Subpart Ec of... - Emissions Limits for Small, Medium, and Large HMIWI at Affected Facilities as Defined in § 60.50c...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Waste Incinerators for Which Construction is Commenced After June 20, 1996 Pt. 60, Subpt. Ec, Table 1A... Facilities as Defined in § 60.50c(a)(1) and (2) Pollutant Units (7 percent oxygen, dry basis) Emissions... matter Milligrams per dry standard cubic meter (grains per dry standard cubic foot) 69 (0.03) 34 (0.015...

40 CFR Table 1b to Subpart Ec of... - Emissions Limits for Small, Medium, and Large HMIWI at Affected Facilities as Defined in § 60.50c...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Waste Incinerators for Which Construction is Commenced After June 20, 1996 Pt. 60, Subpt. Ec, Table 1B... Facilities as Defined in § 60.50c(a)(3) and (4) Pollutant Units (7 percent oxygen, dry basis) Emissions... matter Milligrams per dry standard cubic meter (grains per dry standard cubic foot) 66 (0.029) 22 (0.0095...

Thermophilic Dry Methane Fermentation of Distillation Residue Eluted from Ethanol Fermentation of Kitchen Waste and Dynamics of Microbial Communities.

PubMed

Huang, Yu-Lian; Tan, Li; Wang, Ting-Ting; Sun, Zhao-Yong; Tang, Yue-Qin; Kida, Kenji

2017-01-01

Thermophilic dry methane fermentation is advantageous for feedstock with high solid content. Distillation residue with 65.1 % moisture content was eluted from ethanol fermentation of kitchen waste and subjected to thermophilic dry methane fermentation, after adjusting the moisture content to 75 %. The effect of carbon to nitrogen (C/N) ratio on thermophilic dry methane fermentation was investigated. Results showed that thermophilic dry methane fermentation could not be stably performed for >10 weeks at a C/N ratio of 12.6 and a volatile total solid (VTS) loading rate of 1 g/kg sludge/d; however, it was stably performed at a C/N ratio of 19.8 and a VTS loading rate of 3 g/kg sludge/d with 83.4 % energy recovery efficiency. Quantitative PCR analysis revealed that the number of bacteria and archaea decreased by two orders of magnitude at a C/N ratio of 12.6, whereas they were not influenced at a C/N ratio of 19.8. Microbial community analysis revealed that the relative abundance of protein-degrading bacteria increased and that of organic acid-oxidizing bacteria and acetic acid-oxidizing bacteria decreased at a C/N ratio of 12.6. Therefore, there was accumulation of NH 4 + and acetic acid, which inhibited thermophilic dry methane fermentation.

Lyophilization for Water Recovery III, System Design

NASA Technical Reports Server (NTRS)

Litwiller, Eric; Reinhard, Martin; Fisher, John; Flynn, Michael

2005-01-01

Mixed liquid/solid wastes, including feces, water processor effluents, and food waste, can be lyophilized (freeze-dried) to recover the water they contain and stabilize the solids that remain. Our previous research has demonstrated the potential benefits of using thermoelectric heat pumps to build a lyophilizer for processing waste in microgravity. These results were used to build a working prototype suitable for ground- based human testing. This paper describes the prototype design and presents results of functional and performance tests.

Space–time mapping of wasting among children under the age of five years in Somalia from 2007 to 2010

PubMed Central

Kinyoki, Damaris K; Berkley, James A; Moloney, Grainne M; Odundo, Elijah O; Kandala, Ngianga-Bakwin; Noor, Abdisalan M

2016-01-01

Objective To determine the sub-national seasonal prevalence and trends in wasting from 2007 to 2010 among children aged 6–59 months in Somalia using remote sensing and household survey data from nutritional surveys. Methods Bayesian hierarchical space–time model was implemented using a stochastic partial differential equation (SPDE) approach in integrated nested Laplace approximations (INLA) to produce risk maps of wasting at 1 × 1 km2 spatial resolution and predict to seasons in each year of study from 2007 to 2010. Results The prevalence of wasting was generally at critical levels throughout the country, with most of the areas remaining in the upper classes of critical and very critical levels. There was minimal variation in wasting from year-to-year, but a well-defined seasonal variation was observed. The mean difference of the prevalence of wasting between the dry and wet season ranges from 0% to 5%. The risks of wasting in the South Central zone were highest in the Gedo (37%) and Bay (32%) regions. In North East zone the risk was highest in Nugaal (25%) and in the North West zone the risk was high in Awdal and Woqooyi Galbeed regions with 23%. Conclusion There was a clear seasonal variation in wasting with minimal year-to-year variability from 2007 to 2010 in Somalia. The prevalence was high during the long dry season, which affects the prevalence in the preceding long rainy season. Understanding the seasonal fluctuations of wasting in different locations and at different times is important to inform timely interventions. PMID:26919757

Exploration of using stripped ammonia and ash from poultry litter for the cultivation of the cyanobacterium Arthrospira platensis and the green microalga Chlorella vulgaris.

PubMed

Markou, Giorgos; Iconomou, Dimitris; Sotiroudis, Theodore; Israilides, Cleanthes; Muylaert, Koenraad

2015-11-01

Herein a new approach of exploiting poultry litter (PL) is demonstrated. The suggested method includes drying of PL with simultaneously striping and recovery of ammonia, followed by the direct combustion of dried PL. The generated ash after the combustion, and the striped ammonia consequently, could be used as nutrient source for the cultivation of microalgae or cyanobacteria to produce feed additives. The present study explored the application of PL ash and recovered ammonia for the cultivation of Arthrospira platensis and Chlorella vulgaris. For a simultaneously 90% dissolution of ash potassium and phosphorus, a ratio of acid to ash of 0.02mol-H(+)/g was required. The optimum mass of ash required was 0.07-0.08g/g dry biomass, while the addition of ammoniac nitrogen of 8-9mgN per g of dry biomass per day was adequate for a satisfactory production of A. platensis and C. vulgaris. Copyright © 2015 Elsevier Ltd. All rights reserved.

Thermal and mechanical stabilization process of the organic fraction of the municipal solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Giudicianni, Paola, E-mail: giudicianni@irc.cnr.it; Bozza, Pio, E-mail: pi.bozza@studenti.unina.it; Sorrentino, Giancarlo, E-mail: g.sorrentino@unina.it

2015-10-15

Graphical abstract: Display Omitted - Highlights: • A domestic scale prototype for the pre-treatment of OFMSW has been tested. • Two grinding techniques are compared and thermopress is used for the drying stage. • Increasing temperature up to 170 °C reduces energy consumption of the drying stage. • In the range 5–10 bar a reduction of 97% of the initial volume is obtained. • In most cases energy recovery from the dried waste matches energy consumption. - Abstract: In the present study a thermo-mechanical treatment for the disposal of the Organic Fraction of Municipal Solid Waste (OFMSW) at apartment ormore » condominium scale is proposed. The process presents several advantages allowing to perform a significant volume and moisture reduction of the produced waste at domestic scale thus producing a material with an increased storability and improved characteristics (e.g. calorific value) that make it available for further alternative uses. The assessment of the applicability of the proposed waste pretreatment in a new scheme of waste management system requires several research steps involving different competences and application scales. In this context, a preliminary study is needed targeting to the evaluation and minimization of the energy consumption associated to the process. To this aim, in the present paper, two configurations of a domestic appliance prototype have been presented and the effect of some operating variables has been investigated in order to select the proper configuration and the best set of operating conditions capable to minimize the duration and the energy consumption of the process. The performances of the prototype have been also tested on three model mixtures representing a possible daily domestic waste and compared with an existing commercially available appliance. The results obtained show that a daily application of the process is feasible given the short treatment time required and the energy consumption comparable to the one of the common domestic appliances. Finally, the evaluation of the energy recovered in the final product per unit weight of raw material shows that in most cases it is comparable to the energy required from the treatment.« less

Ethene removal from a synthetic waste gas using a dry biobed

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Heyder, B.; Overmeire, A.; Van Langenhove, H.

A packed granular activated carbon (GAC) biobed, inoculated with the ethene-degrading strain Mycobacterium E3, was used to study ethene removal from a synthetic waste gas. Ethene, for which the dimensionless partition coefficient for an air-water system at 20C is about 7.6, was used as a model compound for poorly water soluble gaseous pollutants. In a first mode of operation, the GAC biobed was sprinkled intermittently and the waste gas influent was continuously pre-humidified, establishing relatively moist conditions. A volumetric ethene removal rate of 0.382 kg COD [center dot] m[sup [minus]3] [center dot] d[sup [minus]1] was obtained for an influent concentrationmore » of 125 ppm, a superficial waste gas velocity of 3.6E-3 m [center dot] s[sup [minus]1] and a pseudo residence time of 45 s. However, in the second mode of operation, omitting the pre-humidification of the waste gas influent and establishing a dry'' biobed and thus obtaining better mass transfer to the biofilm, the ethene removal could be doubled for otherwise comparable operating parameters. Furthermore, under decreased wetting and for the given experimental conditions, the ethene removal was not limited by mass transfer of ethene through the water layer covering the biofilm.« less

Experimental landfill caps for semi-arid and arid climates.

PubMed

Blight, Geoffrey E; Fourie, Andries B

2005-04-01

The United States EPA Subtitle D municipal solid waste landfill requirements specify that the permeability of a cap to a landfill be no greater than the permeability of the underliner. In recent years the concept of the evapotranspirative (ET) cap has been developed in which the cap is designed to store all rain infiltration and re-evapotranspire it during dry weather. Concern at the long period required for landfilled municipal solid waste to decompose and stabilize in arid and semi-arid climates has led to an extension of the concept of the ET cap. With the infiltrate-stabilize-evapotranspire (ISE) cap, rain infiltration during wet weather is permitted to enter the underlying waste, thus accelerating the decomposition and stabilization process. Excess infiltration is then removed from both waste and cap by evaporation during dry weather. The paper describes the construction and operation of two sets of experimental ISE caps, one in a winter rainfall semi-arid climate, and the other in a summer rainfall semi-arid climate. Observation of the rainfall, soil evaporation and amount of water stored in the caps has allowed water balances to be constructed for caps of various thicknesses. These observations show that the ISE concept is viable. In the limit, when there is insufficient rainfall to infiltrate the waste, an ISE cap operates as an ET cap.

WASTE-TO-RESOURCE: NOVEL MEMBRANE SYSTEMS FOR SAFE AND SUSTAINABLE BRINE MANAGEMENT

EPA Science Inventory

Decentralized waste-to-reuse systems will be optimized to maximize resource and energy recovery and minimize chemicals and energy use. This research will enhance fundamental knowledge on simultaneous heat and mass transport through membranes, lower process costs, and furthe...

Status report on the disposal of radioactive wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Culler, F.L. Jr.; McLain, S.

1957-06-25

A comprehensive survey of waste disposal techniques, requirements, costs, hazards, and long-range considerations is presented. The nature of high level wastes from reactors and chemical processes, in the form of fission product gases, waste solutions, solid wastes, and particulate solids in gas phase, is described. Growth predictions for nuclear reactor capacity and the associated fission product and transplutonic waste problem are made and discussed on the basis of present knowledge. Biological hazards from accumulated wastes and potential hazards from reactor accidents, ore and feed material processing, chemical reprocessing plants, and handling of fissionable and fertile material after irradiation and decontaminationmore » are surveyed. The waste transportation problem is considered from the standpoints of magnitude of the problem, present regulations, costs, and cooling periods. The possibilities for ultimate waste management and/or disposal are reviewed and discussed. The costs of disposal, evaporation, storage tanks, and drum-drying are considered.« less

Improvement of nuclide leaching resistance of paraffin waste form with low density polyethylene.

PubMed

Kim, Chang Lak; Park, Joo Wan; Kim, Ju Youl; Chung, Chang Hyun

2002-01-01

Low-level liquid borate wastes have been immobilized with paraffin wax using a concentrate waste drying system (CWDS) in Korean nuclear power plants. The possibility for improving chemical durability of paraffin waste form was suggested in this study. A small amount of low density polyethylene (LDPE) was added to increase the leaching resistance of the existing paraffin waste form. The influence of LDPE on the leaching behavior of waste form was investigated by performing leaching test according to ANSI/ANS-16.1 procedure during 325 days. It was observed that the leaching of nuclides immobilized within paraffin waste form made a marked reduction although little content of LDPE was added to waste form. The acceptance criteria of paraffin waste form associated with leachability index (LI) and compressive strength after the leaching test were fully satisfied with the help of LDPE.

40 CFR 60.33b - Emission guidelines for municipal waste combustor metals, acid gases, organics, and nitrogen oxides.

Code of Federal Regulations, 2010 CFR

2010-07-01

... from a designated facility is 400 micrograms per dry standard cubic meter, corrected to 7 percent... discharged to the atmosphere from a designated facility is 27 milligrams per dry standard cubic meter... standard cubic meter, corrected to 7 percent oxygen. (ii) [Reserved] (iii) The emission limit for opacity...

Multivariate optimization of headspace trap for furan and furfural simultaneous determination in sponge cake.

PubMed

Cepeda-Vázquez, Mayela; Blumenthal, David; Camel, Valérie; Rega, Barbara

2017-03-01

Furan, a possibly carcinogenic compound to humans, and furfural, a naturally occurring volatile contributing to aroma, can be both found in thermally treated foods. These process-induced compounds, formed by close reaction pathways, play an important role as markers of food safety and quality. A method capable of simultaneously quantifying both molecules is thus highly relevant for developing mitigation strategies and preserving the sensory properties of food at the same time. We have developed a unique reliable and sensitive headspace trap (HS trap) extraction method coupled to GC-MS for the simultaneous quantification of furan and furfural in a solid processed food (sponge cake). HS Trap extraction has been optimized using an optimal design of experiments (O-DOE) approach, considering four instrumental and two sample preparation variables, as well as a blocking factor identified during preliminary assays. Multicriteria and multiple response optimization was performed based on a desirability function, yielding the following conditions: thermostatting temperature, 65°C; thermostatting time, 15min; number of pressurization cycles, 4; dry purge time, 0.9min; water / sample amount ratio (dry basis), 16; and total amount (water + sample amount, dry basis), 10g. The performances of the optimized method were also assessed: repeatability (RSD: ≤3.3% for furan and ≤2.6% for furfural), intermediate precision (RSD: 4.0% for furan and 4.3% for furfural), linearity (R 2 : 0.9957 for furan and 0.9996 for furfural), LOD (0.50ng furan g sample dry basis -1 and 10.2ng furfural g sample dry basis -1 ), LOQ (0.99ng furan g sample dry basis -1 and 41.1ng furfural g sample dry basis -1 ). Matrix effect was observed mainly for furan. Finally, the optimized method was applied to other sponge cakes with different matrix characteristics and levels of analytes. Copyright © 2016. Published by Elsevier B.V.

Vitrification of radioactive high-level waste by spray calcination and in-can melting

NASA Astrophysics Data System (ADS)

Hanson, M. S.; Bjorklund, W. J.

1980-07-01

After several nonradioactive test runs, radioactive waste from the processing of 1.5 t of spent, light water reactor fuel was successfully concentrated, dried and converted to a vitreous product. A total of 97 L of waste glass (in two stainless steel canisters) was produced. The spray calcination process coupled to the in-can melting process, as developed at Pacific Northwest Labortory, was used to vitrify the waste. An effluent system consisting of a variety of condensation of scrubbing steps more than adequately decontaminated the process off gas before it was released to the atmosphere.

Simultaneous stack-gas scrubbing and waste water treatment

NASA Technical Reports Server (NTRS)

Poradek, J. C.; Collins, D. D.

1980-01-01

Simultaneous treatment of wastewater and S02-laden stack gas make both treatments more efficient and economical. According to results of preliminary tests, solution generated by stack gas scrubbing cycle reduces bacterial content of wastewater. Both processess benefit by sharing concentrations of iron.

40 CFR 761.295 - Reporting and recordkeeping of the PCB concentrations in samples.

Code of Federal Regulations, 2013 CFR

2013-07-01

... concentrations in samples. 761.295 Section 761.295 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... On-Site Disposal of Bulk PCB Remediation Waste and Porous Surfaces in Accordance With § 761.61(a)(6... concentrations for bulk PCB remediation waste and porous surfaces on a dry weight basis and as micrograms of PCBs...

40 CFR 761.295 - Reporting and recordkeeping of the PCB concentrations in samples.

Code of Federal Regulations, 2014 CFR

2014-07-01

... concentrations in samples. 761.295 Section 761.295 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... On-Site Disposal of Bulk PCB Remediation Waste and Porous Surfaces in Accordance With § 761.61(a)(6... concentrations for bulk PCB remediation waste and porous surfaces on a dry weight basis and as micrograms of PCBs...

40 CFR 761.295 - Reporting and recordkeeping of the PCB concentrations in samples.

Code of Federal Regulations, 2011 CFR

2011-07-01

... concentrations in samples. 761.295 Section 761.295 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... On-Site Disposal of Bulk PCB Remediation Waste and Porous Surfaces in Accordance With § 761.61(a)(6... concentrations for bulk PCB remediation waste and porous surfaces on a dry weight basis and as micrograms of PCBs...

40 CFR 761.295 - Reporting and recordkeeping of the PCB concentrations in samples.

Code of Federal Regulations, 2012 CFR

2012-07-01

... concentrations in samples. 761.295 Section 761.295 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... On-Site Disposal of Bulk PCB Remediation Waste and Porous Surfaces in Accordance With § 761.61(a)(6... concentrations for bulk PCB remediation waste and porous surfaces on a dry weight basis and as micrograms of PCBs...

Liquid secondary waste: Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, including Direct Feed Low Activity Waste (DFLAW) vitrification, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. The powdered salt waste form produced by the ETF will be replaced by a stabilized solidified waste form for disposal in Hanford’s Integrated Disposal Facility (IDF). Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilizationmore » Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the IDF. Waste form testing to support this plan is composed of work in the near term to provide data as input to a performance assessment (PA) for Hanford’s IDF. In 2015, three Hanford Liquid Secondary Waste simulants were developed based on existing and projected waste streams. Using these waste simulants, fourteen mixes of Hanford Liquid Secondary Waste were prepared and tested varying the waste simulant, the water-to-dry materials ratio, and the dry materials blend composition.1 In FY16, testing was performed using a simulant of the EMF process condensate blended with the caustic scrubber—from the Low Activity Waste (LAW) melter—, processed through the ETF. The initial EMF-16 simulant will be based on modeling efforts performed to determine the mass balance of the ETF for the DFLAW.2 The compressive strength of all of the mixes exceeded the target of 3.4 MPa (500 psi) to meet the requirements identified as potential IDF Waste Acceptance Criteria in Table 1 of the Secondary Liquid Waste Immobilization Technology Development Plan.3 The hydraulic properties of the waste forms tested (hydraulic conductivity and water characteristic curves) were comparable to the properties measured on the Savannah River Site (SRS) Saltstone waste form. Future testing should include efforts to first; 1) determine the rate and amount of ammonia released during each unit operation of the treatment process to determine if additional ammonia management is required, then; 2) reduce the ammonia content of the ETF concentrated brine prior to solidification, making the waste more amenable to grouting, or 3) manage the release of ammonia during production and ongoing release during storage of the waste form, or 4) develop a lower pH process/waste form thereby precluding ammonia release.« less

Start-up of thermophilic-dry anaerobic digestion of OFMSW using adapted modified SEBAC inoculum.

PubMed

Fdéz-Güelfo, L A; Alvarez-Gallego, C; Sales Márquez, D; Romero García, L I

2010-12-01

The work presented here concerns the start-up and stabilization stages of a Continuous Stirred Tank Reactor (CSTR) semicontinuously fed for the treatment of the Organic Fraction of Municipal Solid Waste (OFMSW) through anaerobic digestion at thermophilic temperature range (55 degrees C) and dry conditions (30% Total Solids). The procedure reported involves two novel aspects with respect to other start-up and stabilization protocols reported in the literature. The novel aspects concern the adaptation of the inoculum to both the operating conditions (thermophilic and dry) and to the type of waste by employing a modified SEBAC (Sequential Batch Anaerobic Composting) system and, secondly, the direct start-up of the process in a thermophilic temperature regime and feeding of the system from the first day of operation. In this way a significant reduction in the start-up time and stabilization is achieved i.e. 110 days in comparison to 250 days for the processes reported by other authors for the same type of waste and digester. The system presents suitable operational conditions to stabilize the reactor at SRT of 35 days, with a maximum biogas production of 1.944 LR/L.d with a CH(4) and CO(2) percentage of 25.27% and 68.15%, respectively. 2010 Elsevier Ltd. All rights reserved.

Effects of season on ecological processes in extensive earthen tilapia ponds in Southeastern Brazil.

PubMed

Favaro, E G P; Sipaúba-Tavares, L H; Milstein, A

2015-11-01

In Southeastern Brazil tilapia culture is conducted in extensive and semi-intensive flow-through earthen ponds, being water availability and flow management different in the rainy and dry seasons. In this region lettuce wastes are a potential cheap input for tilapia culture. This study examined the ecological processes developing during the rainy and dry seasons in three extensive flow-through earthen tilapia ponds fertilized with lettuce wastes. Water quality, plankton and sediment parameters were sampled monthly during a year. Factor analysis was used to identify the ecological processes occurring within the ponds and to construct a conceptual graphic model of the pond ecosystem functioning during the rainy and dry seasons. Processes related to nitrogen cycling presented differences between both seasons while processes related to phosphorus cycling did not. Ecological differences among ponds were due to effects of wind protection by surrounding vegetation, organic loading entering, tilapia density and its grazing pressure on zooplankton. Differences in tilapia growth among ponds were related to stocking density and ecological process affecting tilapia food availability and intraspecific competition. Lettuce wastes addition into the ponds did not produce negative effects, thus this practice may be considered a disposal option and a low-cost input source for tilapia, at least at the amounts applied in this study.

The slag original from the process of sewage sludge incineration selected properties characteristic

NASA Astrophysics Data System (ADS)

Głowacka, Anna; Rucińska, Teresa; Kiper, Justyna

2017-11-01

This work characterizes the physical and chemical properties of slag from combustion of municipal sewage sludge in "Pomorzany" waste treatment plant in Szczecin. The technology of sludge management is based on drying the sludge in low-temperature belt driers, to a content level of at least 90%, dry mass., and then burning in a grate boiler with mobile grate. The research of the slag resulting from combustion of municipal sewage sludge was conducted using reference methods, presenting images from a scanning electron microscope. The tested waste contained from 16.300 to 23.150% P2O5 completely soluble in strong acids, pH 8.03, mineral substance 98.73% dry mass. The content of heavy metals did not exceed the permissible amount specified in the Regulation of the Minister of Agriculture and Rural Development of 18 June 2008 on the implementation of certain provisions of the Act on fertilizers and fertilization (Journal of Laws of 2008 No. 119, item. 765). The screening trials showed that 48.4% are fractions of 630 µm-1.25 mm. The results show that the waste code 19 01 12 may be used as: alternative source of phosphorus for direct application to soil treatment, for production of organic - mineral fertilizers and as construction aggregate for production of concrete mortars.

Mesophilic and thermophilic anaerobic co-digestion of winery wastewater sludge and wine lees: An integrated approach for sustainable wine production.

PubMed

Da Ros, C; Cavinato, C; Pavan, P; Bolzonella, D

2017-12-01

In this work, winery wastes generated by a cellar producing approximately 300,000 hL of wine per year was monitored for a period of one year. On average, 196 L of wastewater, 0.1 kg of waste activated sludge (dry matter) and 1.6 kg of wine lees were produced per hectoliter of wine produced. Different winery wastes, deriving from different production steps, namely waste activated sludge from wastewater treatment and wine lees, were co-treated using an anaerobic digestion process. Testing was conducted on a pilot scale for both mesophilic and thermophilic conditions. The process was stable for a long period at 37 °C, with an average biogas production of 0.386 m 3 /kg COD fed . On the other hand, for thermophilic conditions, volatile fatty acids accumulated in the reactor and the process failed after one hydraulic retention time (23 days). In order to fix the biological process, trace elements (iron, cobalt and nickel) were added to the feed of the thermophilic reactor. Metals augmentation improved process stability and yields at 55 °C. The pH ranged between 7.8 and 8.0, and specific gas production was 0.450 m 3 /kg COD fed , which corresponded to dry matter and COD removals of 34% and 88%, respectively. Although the observed performances in terms of biogas production were good, the thermophilic process exhibited some limitations related to both the necessity of metals addition and the worse dewaterability properties. In fact, while the mesophilic digestates reached a good dewatering quality via the addition of 6.5 g of polymer per kg of dry matter, the required dosage for the thermophilic sludge was greater than 10 g/kg of dry matter. Copyright © 2016 Elsevier Ltd. All rights reserved.

Solid state anaerobic co-digestion of yard waste and food waste for biogas production.

PubMed

Brown, Dan; Li, Yebo

2013-01-01

Food and yard wastes are available year round at low cost and have the potential to complement each other for SS-AD. The goal of this study was to determine optimal feedstock/effluent (F/E) and food waste/yard waste mixing ratios for optimal biogas production. Co-digestion of yard and food waste was carried out at F/E ratios of 1, 2, and 3. For each F/E ratio, food waste percentages of 0%, 10%, and 20%, based on dry volatile solids, were evaluated. Results showed increased methane yields and volumetric productivities as the percentage of food waste was increased to 10% and 20% of the substrate at F/E ratios of 2 and 1, respectively. This study showed that co-digestion of food waste with yard waste at specific ratios can improve digester operating characteristics and end performance metrics over SS-AD of yard waste alone. Copyright © 2012 Elsevier Ltd. All rights reserved.

Parameter Estimation for Simultaneous Saccharification and Fermentation of Food Waste Into Ethanol Using Matlab Simulink

NASA Astrophysics Data System (ADS)

Davis, Rebecca Anne

The increase in waste disposal and energy costs has provided an incentive to convert carbohydrate-rich food waste streams into fuel. For example, dining halls and restaurants discard foods that require tipping fees for removal. An effective use of food waste may be the enzymatic hydrolysis of the waste to simple sugars and fermentation of the sugars to ethanol. As these wastes have complex compositions which may change day-to-day, experiments were carried out to test fermentability of two different types of food waste at 27° C using Saccharomyces cerevisiae yeast (ATCC4124) and Genencor's STARGEN™ enzyme in batch simultaneous saccharification and fermentation (SSF) experiments. A mathematical model of SSF based on experimentally matched rate equations for enzyme hydrolysis and yeast fermentation was developed in Matlab Simulink®. Using Simulink® parameter estimation 1.1.3, parameters for hydrolysis and fermentation were estimated through modified Michaelis-Menten and Monod-type equations with the aim of predicting changes in the levels of ethanol and glycerol from different initial concentrations of glucose, fructose, maltose, and starch. The model predictions and experimental observations agree reasonably well for the two food waste streams and a third validation dataset. The approach of using Simulink® as a dynamic visual model for SSF represents a simple method which can be applied to a variety of biological pathways and may be very useful for systems approaches in metabolic engineering in the future.

Effective remediation of fish processing waste using mixed culture biofilms capable of simultaneous nitrification and denitrification.

PubMed

Markande, Anoop R; Kapagunta, Chandrika; Patil, Pooja S; Nayak, Binaya B

2016-09-01

Fish processing waste water causes pollution and eutrophication of water bodies when released untreated. Use of bacteria capable of simultaneous nitrification and denitrification (SND) as biofilms on carriers in a moving bed bioreactor (MBBR) is a popular approach but seldom used for fish processing waste water remediation. Here, we studied the variations in biofilm formation and application activities by isolates Lysinibacillus sp. HT13, Alcaligenes sp. HT15 and Proteus sp. HT37 previously reported by us. While HT13 and HT15 formed significantly higher biofilms in polystyrene microtitre plates than on carriers, HT37 exhibited highest on carriers. A consortium of the three selected bacteria grown as biofilm on MBBR carriers exhibited better remediation of ammonia (200-600 ppm and 50 mM) than the individual isolates on carriers. The mixed biofilm set on the carriers was used for nitrogenous waste removal from fish processing waste water in 2 and 20 L setups. The total nitrogen estimated by elemental analysis showed complete remediation from 250 ppm in both 2 and 20 L waste water systems within 48 h. The usual toxic nitrogenous components-ammonia, nitrite and nitrate were also remediated efficiently. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hazardous Waste Water Remediation by Ecoresin-Dry Cow Dung Powder

NASA Astrophysics Data System (ADS)

Bagla, Hemlata; Barot, Nisha

2013-04-01

Water, the matter, matrix, medium and the mother of our life, is indeed one of the drivers of Nature. Through water cycle only the intra and inter equilibrium is maintained constantly between entire 'green' and 'blue'. Unfortunately, with each successive epoch of industrialization and urbanization, human societies have produced non-biodegradable waste hulk with far beyond handling capacities of mankind. At this juncture the very need is to appreciate and move towards the cost as well as time effective scientific alternatives for the removal of aqueous heavy metal pollutants. Green chemistry advocates the utilization of naturally available bio-resins which are environmentally benign alternative to current synthetic materials and technologies employed for waste water treatment. This explicit investigation aims to explore Dry Cow dung powder, DCP, a natural biosorbent as a green and clean alternative for the aqueous waste water treatment. It is naturally available bio-organic, complex, polymorphic humified fecal matter of cow and is enriched with minerals, carbohydrates, fats, proteins, bile pigments, aliphatic - aromatic species such as 'Humic acid'(HA). The HA has been successfully extracted by authors from DCP and this piece of work has been published in the International Journal [1]. We have developed simple, efficient and eco-friendly method for the removal of aqueous heavy metal pollutant such as Cr(VI) [2], Cd(II), Cr(III) [3] and Hg(II) as well radiotoxic 90Sr(II) [4], employing DCP. DCP is employed without any pre or post treatment. Being freely and easily available DCP has an edge over processed natural adsorbent considering their cost, time and energy efficiency. In nutshell we have to remember that prevention is better than the cure. If we fail to meet this, the situation will surely augment which will drain our water, our life, to slaughters knife..! Reference: 1. H.K.Bagla, N.S.Barot, Soil Amendement by Green Supplement: Dry Cowdung powder, EGUGA - 11, 515B, (2009). 2. H.K.Bagla, N.S.Barot, Adsorption studies of Cr(VI) by a Green resin : Dry Cow Dung Powder employing Tracer Technique, Radiochemica Acta, 100, pp. 1- 10, (2012). 3. H.K.Bagla,N.S.Barot, Eco-friendly waste water treatment by cow-dung powder (Adsorption studies of Cr(III), Cr (VI) & Cd(II) using Tracer Technique), Desalination & Water Treatment, 38(1-3), pp.104-113, (2012). 4. H.K.Bagla, N.S.Barot, Biosorption of Radiotoxic 90Sr by Green adsorbent: Dry Cow Dung Powder, Journal of Radioanalytical and Nuclear Chemistry, 294, pp. 81-86, (2012) .

Local root abscisic acid (ABA) accumulation depends on the spatial distribution of soil moisture in potato: implications for ABA signalling under heterogeneous soil drying

PubMed Central

Puértolas, Jaime; Conesa, María R.; Ballester, Carlos; Dodd, Ian C.

2015-01-01

Patterns of root abscisic acid (ABA) accumulation ([ABA]root), root water potential (Ψroot), and root water uptake (RWU), and their impact on xylem sap ABA concentration ([X-ABA]) were measured under vertical partial root-zone drying (VPRD, upper compartment dry, lower compartment wet) and horizontal partial root-zone drying (HPRD, two lateral compartments: one dry, the other wet) of potato (Solanum tuberosum L.). When water was withheld from the dry compartment for 0–10 d, RWU and Ψroot were similarly lower in the dry compartment when soil volumetric water content dropped below 0.22cm3 cm–3 for both spatial distributions of soil moisture. However, [ABA]root increased in response to decreasing Ψroot in the dry compartment only for HPRD, resulting in much higher ABA accumulation than in VPRD. The position of the sampled roots (~4cm closer to the surface in the dry compartment of VPRD than in HPRD) might account for this difference, since older (upper) roots may accumulate less ABA in response to decreased Ψroot than younger (deeper) roots. This would explain differences in root ABA accumulation patterns under vertical and horizontal soil moisture gradients reported in the literature. In our experiment, these differences in root ABA accumulation did not influence [X-ABA], since the RWU fraction (and thus ABA export to shoots) from the dry compartment dramatically decreased simultaneously with any increase in [ABA]root. Thus, HPRD might better trigger a long-distance ABA signal than VPRD under conditions allowing simultaneous high [ABA]root and relatively high RWU fraction. PMID:25547916

Local root abscisic acid (ABA) accumulation depends on the spatial distribution of soil moisture in potato: implications for ABA signalling under heterogeneous soil drying.

PubMed

Puértolas, Jaime; Conesa, María R; Ballester, Carlos; Dodd, Ian C

2015-04-01

Patterns of root abscisic acid (ABA) accumulation ([ABA]root), root water potential (Ψroot), and root water uptake (RWU), and their impact on xylem sap ABA concentration ([X-ABA]) were measured under vertical partial root-zone drying (VPRD, upper compartment dry, lower compartment wet) and horizontal partial root-zone drying (HPRD, two lateral compartments: one dry, the other wet) of potato (Solanum tuberosum L.). When water was withheld from the dry compartment for 0-10 d, RWU and Ψroot were similarly lower in the dry compartment when soil volumetric water content dropped below 0.22cm(3) cm(-3) for both spatial distributions of soil moisture. However, [ABA]root increased in response to decreasing Ψroot in the dry compartment only for HPRD, resulting in much higher ABA accumulation than in VPRD. The position of the sampled roots (~4cm closer to the surface in the dry compartment of VPRD than in HPRD) might account for this difference, since older (upper) roots may accumulate less ABA in response to decreased Ψroot than younger (deeper) roots. This would explain differences in root ABA accumulation patterns under vertical and horizontal soil moisture gradients reported in the literature. In our experiment, these differences in root ABA accumulation did not influence [X-ABA], since the RWU fraction (and thus ABA export to shoots) from the dry compartment dramatically decreased simultaneously with any increase in [ABA]root. Thus, HPRD might better trigger a long-distance ABA signal than VPRD under conditions allowing simultaneous high [ABA]root and relatively high RWU fraction. © The Author 2014. Published by Oxford University Press on behalf of the Society for Experimental Biology.

Simultaneous improvement of waste gas purification and nitrogen removal using a novel aerated vertical flow constructed wetland.

PubMed

Zhang, Xinwen; Hu, Zhen; Ngo, Huu Hao; Zhang, Jian; Guo, Wenshan; Liang, Shuang; Xie, Huijun

2018-03-01

Insufficient oxygen supply is identified as one of the major factors limiting organic pollutant and nitrogen (N) removal in constructed wetlands (CWs). This study designed a novel aerated vertical flow constructed wetland (VFCW) using waste gas from biological wastewater treatment systems to improve pollutant removal in CWs, its potential in purifying waste gas was also identified. Compared with unaerated VFCW, the introduction of waste gas significantly improved NH 4 + -N and TN removal efficiencies by 128.48 ± 3.13% and 59.09 ± 2.26%, respectively. Furthermore, the waste gas ingredients, including H 2 S, NH 3 , greenhouse gas (N 2 O) and microbial aerosols, were remarkably reduced after passing through the VFCW. The removal efficiencies of H 2 S, NH 3 and N 2 O were 77.78 ± 3.46%, 52.17 ± 2.53%, and 87.40 ± 3.89%, respectively. In addition, the bacterial and fungal aerosols in waste gas were effectively removed with removal efficiencies of 42.72 ± 3.21% and 47.89 ± 2.82%, respectively. Microbial analysis results revealed that the high microbial community abundance in the VFCW, caused by the introduction of waste gas from the sequencing batch reactor (SBR), led to its optimized nitrogen transformation processes. These results suggested that the VFCW intermittently aerated with waste gas may have potential application for purifying wastewater treatment plant effluent and waste gas, simultaneously. Copyright © 2017 Elsevier Ltd. All rights reserved.

Thermodynamic and Microstructural Mechanisms in the Corrosion of Advanced Ceramic Tc-bearing Waste Forms and Thermophysical Properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hartmann, Thomas

Technetium-99 (Tc, t 1/2 = 2.13x10 5 years) is a challenge from a nuclear waste perspective and is one of the most abundant, long-lived radioisotopes found in used nuclear fuel (UNF). Within the Hanford Tank Waste Treatment and Immobilization Plant, technetium volatilizes at typical glass melting temperature, is captured in the off-gas treatment system and recycled back into the feed to eventually increase Tc-loadings of the glass. The aim of this NEUP project was to provide an alternative strategy to immobilize fission technetium as durable ceramic waste form and also to avoid the accumulation of volatile technetium within the offmore » gas melter system in the course of vitrifying radioactive effluents in a ceramic melter. During this project our major attention was turned to the fabrication of chemical durable mineral phases where technetium is structurally bond entirely as tetravalent cation. These mineral phases will act as the primary waste form with optimal waste loading and superior resistance against leaching and corrosion. We have been very successful in fabricating phase-pure micro-gram amounts of lanthanide-technetium pyrochlores by dry-chemical synthesis. However, upscaling to a gram-size synthesis route using either dry- or wet-chemical processing was not always successful, but progress can be reported on a variety of aspects. During the course of this 5-year NEUP project (including a 2-year no-cost extension) we have significantly enhanced the existing knowledge on the fabrication and properties of ceramic technetium waste forms.« less

Using oxidized liquid and solid human waste as nutrients for Chlorella vulgaris and cyanobacterium Oscillatoria deflexa

NASA Astrophysics Data System (ADS)

Trifonov, Sergey V.; Kalacheva, Galina; Tirranen, Lyalya; Gribovskaya, Iliada

At stationary terrestrial and space stations with closed and partially closed substance exchange not only plants, but also algae can regenerate atmosphere. Their biomass can be used for feeding Daphnia and Moina species, which, in their turn, serve as food for fish. In addition, it is possible to use algae for production of biological fuel. We suggested two methods of human waste mineralization: dry (evaporation with subsequent incineration in a muffle furnace) and wet (oxidation in a reactor using hydrogen peroxide). The research task was to prepare nutrient media for green alga Chlorella vulgaris and cyanobacterium Oscillatoria deflexa using liquid human waste mineralized by dry method, and to prepare media for chlorella on the basis of 1) liquid and 2) liquid and solid human waste mineralized by wet method. The algae were grown in batch culture in a climate chamber with the following parameters: illumination 7 klx, temperature 27-30 (°) C, culture density 1-2 g/l of dry weight. The control for chlorella was Tamiya medium, pH-5, and for oscillstoria — Zarrouk medium, pH-10. Maximum permissible concentrations of NaCl, Cl, urea (NH _{2}) _{2}CO, and native urine were established for algae. Missing ingredients (such as salts and acids) for experimental nutrient media were determined: their addition made it possible to obtain the biomass production not less than that in the control. The estimation was given of the mineral and biochemical composition of algae grown on experimental media. Microbiological test revealed absence of foreign microbial flora in experimental cultures.

USERS GUIDE FOR THE CONVERSION OF NAVY PAINT SPRAY BOOTH PARTICULATE EMISSION CONTROL SYSTEMS FROM WET TO DRY OPERATION

EPA Science Inventory

The report is a guide or convrting U.S. Navy paint spray booth particulate emission control systems from wet to dry operation. The use of water curtains for air pollution control of paint spray booths is considered a major source of water and solid waste pol-lution from industria...

40 CFR 63.1203 - What are the standards for hazardous waste incinerators that are effective until compliance with...

Code of Federal Regulations, 2010 CFR

2010-07-01

... monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid... hydrochloric acid equivalents, dry basis and corrected to 7 percent oxygen; and (7) Particulate matter in... oxygen, and reported as propane; (6) Hydrochloric acid and chlorine gas in excess of 21 parts per million...

40 CFR 63.1203 - What are the standards for hazardous waste incinerators that are effective until compliance with...

Code of Federal Regulations, 2011 CFR

2011-07-01

... monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid... hydrochloric acid equivalents, dry basis and corrected to 7 percent oxygen; and (7) Particulate matter in... oxygen, and reported as propane; (6) Hydrochloric acid and chlorine gas in excess of 21 parts per million...

40 CFR 63.1203 - What are the standards for hazardous waste incinerators that are effective until compliance with...

Code of Federal Regulations, 2012 CFR

2012-07-01

... monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane; (6) Hydrochloric acid... hydrochloric acid equivalents, dry basis and corrected to 7 percent oxygen; and (7) Particulate matter in... oxygen, and reported as propane; (6) Hydrochloric acid and chlorine gas in excess of 21 parts per million...

Landfill disposal systems.

PubMed

Slimak, K M

1978-12-01

The current status of landfill disposal of hazardous wastes in the United States is indicated by presenting descriptions of six operating landfills. These landfills illustrate the variety of techniques that exist in landfill disposal of hazardous wastes. Although some landfills more effectively isolate hazardous waste than others, all landfills must deal with the following problems. Leachate from hazardous waste landfills is generally highly polluted. Most landfills attempt to contain leachate at the site and prevent its discharge to surface or groundwaters. To retain leachate within a disposal area, subsurface barriers of materials such as concrete, asphalt, butyl rubber, vinyl, and clay are used. It is difficult to assure that these materials can seal a landfill indefinitely. When a subsurface barrier fails, the leachate enters the groundwater in a concentrated, narrow band which may bypass monitoring wells. Once a subsurface barrier has failed, repairs are time-consuming and costly, since the waste above the repair site may have to be removed. The central problem in landfill disposal is leachate control. Recent emphasis has been on developing subsurface barriers to contain the wastes and any leachate. Future emphasis should also be on techniques for removing water from hazardous wastes before they are placed in landfills, and on methods for preventing contact of the wastes with water during and after disposal operations. When leachate is eliminated, the problems of monitoring, and subsurface barrier failure and repair can be addressed, and a waste can be effectively isolated.A surface seal landfill design is recommended for maintaining the dry state of solid hazardous wastes and for controlling leachate. Any impervious liner is utilized over the top of the landfill to prevent surface water from seeping into the waste. The surface barrier is also the site where monitoring and maintenance activities are focused. Barrier failure can be detected by visual inspections and any repairs can be made without disturbing the waste. The surface seal landfill does not employ a subsurface barrier. The surface seal landfill successfully addresses each of the four environmental problems listed above, provided that this landfill design is utilized for dry wastes only and is located at a site which provides protection from groundwater and temporary perched water tables.

Optimal conditions for preparation of banana peels, sugarcane bagasse and watermelon rind in removing copper from water.

PubMed

Liu, Cong; Ngo, Huu Hao; Guo, Wenshan; Tung, Kuo-Lun

2012-09-01

In this study, three agro-waste materials were used as biosorbents for removal of copper (Cu) from water. This work aims to optimise conditions for preparation of these materials to obtain maximum Cu adsorption capacity. The optimal conditions were determined in terms of Cu removal efficiency and/or energy consumption. The results indicate that banana peels dried at 120°C for 2h and ground into powder form led to a better performance in terms of both copper removal efficiency and energy consumption. For sugarcane bagasse and watermelon rind, 120°C was the suitable drying temperature. However, the best drying time was 1h for sugarcane bagasse and 3h for watermelon rind. The powder form with size of <150 μm was optimal for all biosorbents in terms of removal efficiency and equilibration time. The findings are beneficial to the application of these agro-waste materials for Cu removal from water and wastewater treatment. Copyright © 2012. Published by Elsevier Ltd.

Swarm motility inhibitory and antioxidant activities of pomegranate peel processed under three drying conditions.

PubMed

John, K M Maria; Bhagwat, Arvind A; Luthria, Devanand L

2017-11-15

During processing of ready-to-eat fresh fruits, large amounts of peel and seeds are discarded as waste. Pomegranate (Punicagranatum) peels contain high amounts of bioactive compounds which inhibit migration of Salmonella on wet surfaces. The metabolic distribution of bioactives in pomegranate peel, inner membrane, and edible aril portion was investigated under three different drying conditions along with the anti-swarming activity against Citrobacter rodentium. Based on the multivariate analysis, 29 metabolites discriminated the pomegranate peel, inner membrane, and edible aril portion, as well as the three different drying methods. Punicalagins (∼38.6-50.3mg/g) were detected in higher quantities in all fractions as compared to ellagic acid (∼0.1-3.2mg/g) and punicalins (∼0-2.4mg/g). The bioactivity (antioxidant, anti-swarming) and phenolics content was significantly higher in peels than the edible aril portion. Natural anti-swarming agents from food waste may have promising potential for controlling food borne pathogens. Published by Elsevier Ltd.

Pretreatment effects on orange processing waste for making ethanol by simultaneous saccharification and fermentation

USDA-ARS?s Scientific Manuscript database

Pretreatment of orange processing waste (CPW) by steam explosion under various conditions (pretreatment time, pH and temperatures) was investigated. Pretreatments longer than 4 min with steam purging resulted in CPW containing less than 0.1% limonene, an inhibitor for fermentation. Steam pretreatmen...

DO WASTE INCINERATORS INDUCE ADVERSE RESPIRATORY EFFECTS? AN AIR QUALITY AND EPIDEMIOLOGICAL STUDY OF SIX COMMUNITIES

EPA Science Inventory

The purpose of this study was to measure simultaneously air quality and respiratory function and symptoms in populations living in the neighborhood of waste incinerators, and to estimate the contribution of incinerator emissions to the particulate air mass in these neighborhoods....

Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

DOEpatents

Moens, Luc

1995-01-01

A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.

Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

DOEpatents

Moens, L.

1995-07-11

A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350 and 375 C to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan. 2 figs.

A new approach for concurrently improving performance of South Korean food waste valorization and renewable energy recovery via dry anaerobic digestion under mesophilic and thermophilic conditions.

PubMed

Nguyen, Dinh Duc; Yeop, Jeong Seong; Choi, Jaehoon; Kim, Sungsu; Chang, Soon Woong; Jeon, Byong-Hun; Guo, Wenshan; Ngo, Huu Hao

2017-08-01

Dry semicontinuous anaerobic digestion (AD) of South Korean food waste (FW) under four solid loading rates (SLRs) (2.30-9.21kg total solids (TS)/m 3 day) and at a fixed TS content was compared between two digesters, one each under mesophilic and thermophilic conditions. Biogas production and organic matter reduction in both digesters followed similar trends, increasing with rising SLR. Inhibitor (intermediate products of the anaerobic fermentation process) effects on the digesters' performance were not observed under the studied conditions. In all cases tested, the digesters' best performance was achieved at the SLR of 9.21kg TS/m 3 day, with 74.02% and 80.98% reduction of volatile solids (VS), 0.87 and 0.90m 3 biogas/kg VS removed , and 0.65 (65% CH 4 ) and 0.73 (60.02% CH 4 ) m 3 biogas/kg VS fed , under mesophilic and thermophilic conditions, respectively. Thermophilic dry AD is recommended for FW treatment in South Korea because it is more efficient and has higher energy recovery potential when compared to mesophilic dry AD. Copyright © 2017 Elsevier Ltd. All rights reserved.

Fabrication of cellulose-based aerogels from waste newspaper without any pretreatment and their use for absorbents.

PubMed

Jin, Chunde; Han, Shenjie; Li, Jingpeng; Sun, Qingfeng

2015-06-05

Cellulose-based aerogel (CBA) was prepared from waste newspaper (WNP) without any pretreatment using 1-allyl-3-methyimidazolium chloride (AmImCl) as a solvent via regeneration and an environmentally friendly freeze-drying method. After being treated with trimethylchlorosilane (TMCS) via a simple thermal chemical vapor deposition process, the resulting CBAs were rendered both hydrophobic and oleophilic. Successful silanization on the surface of the porous CBA was verified by a variety of techniques including scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), and water contact angle (WCA) measurements. As a result, the silane-coated, interconnected CBAs not only exhibited good absorption performance for oils (e.g., waste engine oil), but also showed absorption capacity for organic solvents such as chloroform (with a representative weight gain ranging from 11 to 22 times of their own dry weight), making them diversified absorbents for potential applications including sewage purification. Copyright © 2015 Elsevier Ltd. All rights reserved.

Gaseous emissions during the solid state fermentation of different wastes for enzyme production at pilot scale.

PubMed

Maulini-Duran, Caterina; Abraham, Juliana; Rodríguez-Pérez, Sheila; Cerda, Alejandra; Jiménez-Peñalver, Pedro; Gea, Teresa; Barrena, Raquel; Artola, Adriana; Font, Xavier; Sánchez, Antoni

2015-03-01

The emissions of volatile organic compounds (VOC), CH4, N2O and NH3 during the solid state fermentation process of some selected wastes to obtain different enzymes have been determined at pilot scale. Orange peel+compost (OP), hair wastes+raw sludge (HW) and winterization residue+raw sludge (WR) have been processed in duplicate in 50 L reactors to provide emission factors and to identify the different VOC families present in exhaust gaseous emissions. Ammonia emission from HW fermentation (3.2±0.5 kg Mg(-1) dry matter) and VOC emission during OP processes (18±6 kg Mg(-1) dry matter) should be considered in an industrial application of these processes. Terpenes have been the most emitted VOC family during all the processes although the emission of sulphide molecules during HW SSF is notable. The most emitted compound was dimethyl disulfide in HW and WR processes, and limonene in the SSF of OP. Copyright © 2014 Elsevier Ltd. All rights reserved.

Military Wastes-to-Energy Applications,

DTIC Science & Technology

1980-11-01

and silvicultural resources of several tree species . Aquaculture uses kelp and other plant species . Energy-rich organic wastes and residue are from...dry tons/year would require about 20,000 to 50,000 acres depending on tree species , culitivation method, land conditions, and other factors...recommendations for specific sites. For example, tree species selection information are not adequate to determine whether a particular specie would be

Dry anaerobic co-digestion of food waste and cattle manure: Impact of total solids, substrate ratio and thermal pre treatment on methane yield and quality of biomanure.

PubMed

Arelli, Vijayalakshmi; Begum, Sameena; Anupoju, Gangagni Rao; Kuruti, Kranti; S, Shailaja

2018-04-01

The objective of the present study is to assess the impact of TS concentration, substrate mixing ratio (co digestion) and thermal pretreatment on biogas production, methane yield, VS reduction (%) and quality of biomanure through dry anaerobic digestion (DAD) of food waste (FW) and cattle manure (CM). Results divulged that the optimum methane yield and biomanure of 0.18 and 0.21 m 3 CH 4 /(kg VS reduced) and 3.15 and 2.8 kg/kg waste was obtained from FW at TS of 25% and 30% at an HRT of 41 and 31 days respectively whereas it was 0.32 and 0.43 m 3 CH 4 /(kg VS reduced) and 2.2 and 1.15 kg/kg waste from pretreated FW at an HRT of 16 and 20 days correspondingly. Improvement of methane from 62 to 81% was obtained due to thermal pretreatment. The highest nutrient recovery in terms of N, P, K was found to be 5.14, 2.6 and 3.2 respectively. Copyright © 2018 Elsevier Ltd. All rights reserved.

Winery waste recycling through anaerobic co-digestion with waste activated sludge.

PubMed

Da Ros, C; Cavinato, C; Pavan, P; Bolzonella, D

2014-11-01

In this study biogas and high quality digestate were recovered from winery waste (wine lees) through anaerobic co-digestion with waste activated sludge both in mesophilic and thermophilic conditions. The two conditions studied showed similar yields (0.40 m(3)/kgCODfed) but different biological process stability: in fact the mesophilic process was clearly more stable than the thermophilic one in terms of bioprocess parameters. The resulting digestates showed good characteristics for both the tested conditions: heavy metals, dioxins (PCDD/F), and dioxin like bi-phenyls (PCBs) were concentred in the effluent if compared with the influent because of the important reduction of the solid dry matter, but remained at levels acceptable for agricultural reuse. Pathogens in digestate decreased. Best reductions were observed in thermophilic condition, while at 37°C the concentration of Escherichia coli was at concentrations level as high as 1000 UFC/g. Dewatering properties of digestates were evaluated by means of the capillary suction time (CST) and specific resistance to filtration (SRF) tests and it was found that a good dewatering level was achievable only when high doses of polymer (more than 25 g per kg dry solids) were added to sludge. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effect of moisture content on fed batch composting reactor of vegetable and fruit wastes.

PubMed

Jolanun, B; Tripetchkul, S; Chiemchaisri, C; Chaiprasert, P; Towprayoon, S

2005-03-01

Vegetable and fruit wastes mixed with sawdust were composted in a laboratory scale reactor by controlling the waste feeding rate at 21 kg m(-3) day(-1) and aeration rate at 10.6 l m(-3) min(-1). The effects of initial moisture content on organic matter degradation and process performance of fed batch composting were investigated. The absolute amount of removal, removal percentage, and removal rate of dry mass obtained were substantially different among the initial moisture contents. The rapid rise of moisture content and the lowest absolute amount of removal observed were achieved in the 50% condition. The initial moisture content yielding the largest absolute amount of removal in both feeding and curing stage was 30% whereas the removal percentage and rate constant of waste decomposition were highest in the 50% condition. Examined by traditional soil physics method, the moisture content at 50-55% was suitable for satisfying the degree of free air space (65-70%) of compost during the fed batch composting. Most degradable organic matter was mainly consumed in the feeding stage as indicated by a higher removal rate of dry mass in all cases. It is recommended that the initial moisture content of 30% and mode of aeration and agitation should be adopted for achieving practical fed batch composting of vegetable and fruit wastes. The study also demonstrated that the composting kinetics of vegetable and fruit wastes mixed with sawdust can be described by a first order model.

Battery collection in municipal waste management in Japan: challenges for hazardous substance control and safety.

PubMed

Terazono, Atsushi; Oguchi, Masahiro; Iino, Shigenori; Mogi, Satoshi

2015-05-01

To clarify current collection rules of waste batteries in municipal waste management in Japan and to examine future challenges for hazardous substance control and safety, we reviewed collection rules of waste batteries in the Tokyo Metropolitan Area. We also conducted a field survey of waste batteries collected at various battery and small waste electric and electronic equipment (WEEE) collection sites in Tokyo. The different types of batteries are not collected in a uniform way in the Tokyo area, so consumers need to pay attention to the specific collection rules for each type of battery in each municipality. In areas where small WEEE recycling schemes are being operated after the enforcement of the Act on Promotion of Recycling of Small Waste Electrical and Electronic Equipment in Japan in 2013, consumers may be confused about the need for separating batteries from small WEEE (especially mobile phones). Our field survey of collected waste batteries indicated that 6-10% of zinc carbon and alkaline batteries discarded in Japan currently could be regarded as containing mercury. More than 26% of zinc carbon dry batteries currently being discarded may have a lead content above the labelling threshold of the EU Batteries Directive (2006/66/EC). In terms of safety, despite announcements by producers and municipalities about using insulation (tape) on waste batteries to prevent fires, only 2.0% of discarded cylindrical dry batteries were insulated. Our field study of small WEEE showed that batteries made up an average of 4.6% of the total collected small WEEE on a weight basis. Exchangeable batteries were used in almost all of mobile phones, digital cameras, radios, and remote controls, but the removal rate was as low as 22% for mobile phones. Given the safety issues and the rapid changes occurring with mobile phones or other types of small WEEE, discussion is needed among stakeholders to determine how to safely collect and recycle WEEE and waste batteries. Copyright © 2015 Elsevier Ltd. All rights reserved.

The analysis of waste treatment methods and managerial skills towards the effectiveness of CO2 emmissions (an ex post facto study at TPA Bantar Gebang Bekasi)

NASA Astrophysics Data System (ADS)

Ria Rajagukguk, Jenni; Siagian, Lestina

2017-09-01

In the last three years, Java Island produces 29.413.336 m3/year of waste, coming from settlement (house hold) and non-settlement waste. Recently, this waste is managed with conventional technology, composting and recycling. Based on law No. 18 of 2008 on Waste Management, Chapter III Article 5, it is firmly stated that the government and regional governments are responsible for ensuring proper and environmentally sound waste management in accordance with the objectives. The observation of managerial skills is highly needed to investigate the operation of waste management at TPA Bantar Gebang towards the effectiveness of CO2 emissions.The problems are (1)Whether there is any influence between the method of waste management through Biogas Technology to the effectiveness of CO2 emissions. (2) Whether there is any influence between managerial skills to effectiveness of CO2 emission. (3) Whether there is any simultaneous influence between waste management method and managerial skill to CO2 emission effectiveness and (4) how is the method of waste management. Quantitative and egineering method were used to process the data.Biogas Technology variables and Managerial Skill are simultaneously and significantly influenced to CO2 Emission Effectiveness, this is based on Fh > Ft value of 168,453 > 3.072467) and its significance is 0.000 < 0,05. Then Ho was rejected and Ha was accepted which means that variable of Managerial Skill have influence or very big influence to Effeciveness of CO2 Emission, Correlation coefficient value 94,1% which means there is very strong relation between variable of Biogas Technology, Managerial Skill to Effectiveness of CO2 emission. Then Technology management through Biogas Technology is anaerobic biology.

Sintered bentonite ceramics for the immobilization of cesium- and strontium-bearing radioactive waste

NASA Astrophysics Data System (ADS)

Ortega, Luis Humberto

The Advanced Fuel Cycle Initiative (AFCI) is a Department of Energy (DOE) program, that has been investigating technologies to improve fuel cycle sustainability and proliferation resistance. One of the program's goals is to reduce the amount of radioactive waste requiring repository disposal. Cesium and strontium are two primary heat sources during the first 300 years of spent nuclear fuel's decay, specifically isotopes Cs-137 and Sr-90. Removal of these isotopes from spent nuclear fuel will reduce the activity of the bulk spent fuel, reducing the heat given off by the waste. Once the cesium and strontium are separated from the bulk of the spent nuclear fuel, the isotopes must be immobilized. This study is focused on a method to immobilize a cesium- and strontium-bearing radioactive liquid waste stream. While there are various schemes to remove these isotopes from spent fuel, this study has focused on a nitric acid based liquid waste. The waste liquid was mixed with the bentonite, dried then sintered. To be effective sintering temperatures from 1100 to 1200°C were required, and waste concentrations must be at least 25 wt%. The product is a leach resistant ceramic solid with the waste elements embedded within alumino-silicates and a silicon rich phase. The cesium is primarily incorporated into pollucite and the strontium into a monoclinic feldspar. The simulated waste was prepared from nitrate salts of stable ions. These ions were limited to cesium, strontium, barium and rubidium. Barium and rubidium will be co-extracted during separation due to similar chemical properties to cesium and strontium. The waste liquid was added to the bentonite clay incrementally with drying steps between each addition. The dry powder was pressed and then sintered at various temperatures. The maximum loading tested is 32 wt. percent waste, which refers to 13.9 wt. percent cesium, 12.2 wt. percent barium, 4.1 wt. percent strontium, and 2.0 wt. percent rubidium. Lower loadings of waste were also tested. The final solid product was a hard dense ceramic with a density that varied from 2.12 g/cm3 for a 19% waste loading with a 1200°C sintering temperature to 3.03 g/cm 3 with a 29% waste loading and sintered at 1100°C. Differential Scanning Calorimetry and Thermal Gravimetric Analysis (DSC-TGA) of the loaded bentonite displayed mass loss steps which were consistent with water losses in pure bentonite. Water losses were complete after dehydroxylation at ˜650°C. No mass losses were evident beyond the dehydroxylation. The ceramic melts at temperatures greater than 1300°C. Light flash analysis found heat capacities of the ceramic to be comparable to those of strontium and barium feldspars as well as pollucite. Thermal conductivity improved with higher sintering temperatures, attributed to lower porosity. Porosity was minimized in 1200°C sinterings. Ceramics with waste loadings less than 25 wt% displayed slump, the lowest waste loading, 15 wt% bloated at a 1200°C sintering. Waste loading above 25 wt% produced smooth uniform ceramics when sintered >1100°C. Sintered bentonite may provide a simple alternative to vitrification and other engineered radioactive waste-forms.

Anisotropic capillary barrier for waste site surface covers

DOEpatents

Stormont, J.C.

1996-08-27

Waste sites are capped or covered upon closure. The cover structure incorporates a number of different layers each having a contributory function. One such layer is the barrier layer. Traditionally the barriers have been compacted soil and geosynthetics. These types of barriers have not been successfully implemented in unsaturated ground conditions like those found in dry climates. Capillary barriers have been proposed as barrier layers in dry environments, but the divergence length of these barriers has been found to be inadequate. An alternative to the capillary barrier is a anisotropic capillary barrier. An anisotropic capillary barrier has an increased divergence length which results in more water being diverted laterally preventing the majority of water from percolating in a downward direction through the barrier. 10 figs.

Anisotropic capillary barrier for waste site surface covers

DOEpatents

Stormont, John C.

1996-01-01

Waste sites are capped or covered upon closure. The cover structure incorporates a number of different layers each having a contributory function. One such layer is the barrier layer. Traditionally the barriers have been compacted soil and geosynthetics. These types of barriers have not been successfully implemented in unsaturated ground conditions like those found in dry climates. Capillary barriers have been proposed as barrier layers in dry environments, but the divergence length of these barriers has been found to be inadequate. An alternative to the capillary barrier is a anisotropic capillary barrier. An anisotropic capillary barrier has an increased divergence length which results in more water being diverted laterally preventing the majority of water from percolating in a downward direction through the barrier.

Raw Starch Degrading Amylase Production by Various Fungal Cultures Grown on Cassava Waste

PubMed Central

Balaji, P.; Eyini, M.

2006-01-01

The solid waste of sago industry using cassava was fermented by Aspergillus niger, Aspergillus terreus and Rhizopus stolonifer in solid state fermentation. Cassava waste contained 52 per cent starch and 2.9 per cent protein by dry weight. The amylase activity was maintained at a high level and the highest amylase activity was observed on the 8th day in R. stolonifer mediated fermentation. R. stolonifer was more efficient than Aspergillus niger and Aspergillus terreus in bioconverting cassava waste into fungal protein (90.24 mg/g) by saccharifying 70% starch and releasing 44.5% reducing sugars in eight days of solid state fermentation. PMID:24039485

The valorization of the plastic waste to the rheological characteristics of bituminous mixtures

NASA Astrophysics Data System (ADS)

Boucherba, Mohammed; Kriker, Abdelouahed; Kebaili, Nabil

2017-02-01

The valorization of materials used at the end of the cycle currently constitutes one of the major challenges for the state for the safeguarding of the environment. Indeed, plastic waste from their obstruction and weak biodegradability often constitutes a threat for health, nature and the environment. The present study treats a mining method and valorization of these wastes in the road, where this waste is incorporated in the pure bitumen of asphalt concretes using the Dry process. The vital objective of this work is to see their impact on the mechanical behavior of these concretes using the Marshall Test and NAT.

Drying of restructured chips made from the old stalks of Asparagus officinalis: impact of different drying methods.

PubMed

Liu, Zhenbin; Zhang, Min; Wang, Yuchuan

2016-06-01

Old stalks of Asparagus officinalis, which account for one third of the total length of each spear, are always discarded as waste. To make full use of the resource, a kind of restructured Asparagus officinalis chip was made. The effects of pulse-spouted microwave-assisted vacuum drying (PSMVD), microwave-assisted vacuum drying (MVD) and vacuum drying (VD) on texture, color and other quality parameters of restructured chips were then studied to obtain high-quality dried chips. Results indicated that the drying time was significantly affected by drying methods, and PSMVD had much better drying uniformity than MVD. The expansion ratio and crispness of chips increased with increasing microwave power and vacuum degree. The browning reaction of samples in VD was more serious, which was confirmed by the results of color test and electronic nose. The PSMVD drying method showed much better drying uniformity than MVD. The dried chips obtained by PSMVD showed optimal quality and were more readily accepted by consumers. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

Dry thermal resistance of Bacillus anthracis (Sterne) spores and spores of other Bacillus species: implications for biological agent destruction via waste incineration.

PubMed

Wood, J P; Lemieux, P; Betancourt, D; Kariher, P; Gatchalian, N G

2010-07-01

To obtain needed data on the dry thermal resistance of Bacillus anthracis spores and other Bacillus species for waste incinerator applications. Tests were conducted in a pilot-scale incinerator utilizing biological indicators comprised of spores of Geobacillus stearothermophilus, Bacillus atrophaeus and B. anthracis (Sterne) and embedded in building material bundles. Tests were also conducted in a dry heat oven to determine the destruction kinetics for the same species. In the pilot-scale incinerator tests, B. atrophaeus and G. stearothermophilus demonstrated similar thermal sensitivity, but B. anthracis (Sterne) was less thermally resistant than G. stearothermophilus. For the dry heat oven tests conducted at 175°C, the D-values were 0·4, 0·2 and 0·3 min for B. atrophaeus, B. anthracis (Sterne) and G. stearothermophilus, respectively. Bacillus anthracis (Sterne) possesses similar or less dry heat resistance compared to B. atrophaeus and G. stearothermophilus. Previous studies have demonstrated conditions under which bacterial spores may survive in an incinerator environment. The data from this study may assist in the selection of surrogates or indicator micro-organisms to ensure B. anthracis spores embedded in building materials are completely inactivated in an incinerator. © 2009 The Society for Applied Microbiology, Journal of Applied Microbiology. No claim to US Government works.

14 CFR 139.317 - Aircraft rescue and firefighting: Equipment and agents.

Code of Federal Regulations, 2011 CFR

2011-01-01

... pounds of potassium-based dry chemical and water with a commensurate quantity of AFFF to total 100 gallons for simultaneous dry chemical and AFFF application. (b) Index B. Either of the following: (1) One... gallons of water and the commensurate quantity of AFFF for foam production. (2) Two vehicles— (i) One...

14 CFR 139.317 - Aircraft rescue and firefighting: Equipment and agents.

Code of Federal Regulations, 2012 CFR

2012-01-01

... pounds of potassium-based dry chemical and water with a commensurate quantity of AFFF to total 100 gallons for simultaneous dry chemical and AFFF application. (b) Index B. Either of the following: (1) One... gallons of water and the commensurate quantity of AFFF for foam production. (2) Two vehicles— (i) One...

14 CFR 139.317 - Aircraft rescue and firefighting: Equipment and agents.

Code of Federal Regulations, 2010 CFR

2010-01-01

... pounds of potassium-based dry chemical and water with a commensurate quantity of AFFF to total 100 gallons for simultaneous dry chemical and AFFF application. (b) Index B. Either of the following: (1) One... gallons of water and the commensurate quantity of AFFF for foam production. (2) Two vehicles— (i) One...

14 CFR 139.317 - Aircraft rescue and firefighting: Equipment and agents.

Code of Federal Regulations, 2014 CFR

2014-01-01

... pounds of potassium-based dry chemical and water with a commensurate quantity of AFFF to total 100 gallons for simultaneous dry chemical and AFFF application. (b) Index B. Either of the following: (1) One... gallons of water and the commensurate quantity of AFFF for foam production. (2) Two vehicles— (i) One...

14 CFR 139.317 - Aircraft rescue and firefighting: Equipment and agents.

Code of Federal Regulations, 2013 CFR

2013-01-01

... pounds of potassium-based dry chemical and water with a commensurate quantity of AFFF to total 100 gallons for simultaneous dry chemical and AFFF application. (b) Index B. Either of the following: (1) One... gallons of water and the commensurate quantity of AFFF for foam production. (2) Two vehicles— (i) One...

Year-round atmospheric wet and dry deposition of nitrogen and phosphorus on water and land surfaces in Nanjing, China.

PubMed

Sun, Liying; Li, Bo; Ma, Yuchun; Wang, Jinyang; Xiong, Zhengqin

2013-06-01

The dry deposition of ammonium, nitrate, and total phosphorus (TP) to both water (DW) and land (DD) surfaces, along with wet deposition, were simultaneously monitored from March 2009 to February 2011 in Nanjing, China. Results showed that wet deposition of total phosphorus was 1.1 kg phosphorus ha (-1)yr(-1), and inorganic nitrogen was 28.7 kg nitrogen ha (-1)yr(-1), with 43% being ammonium nitrogen. Dry deposition of ammonium, nitrate, and total phosphorus, measured by the DW/DD method, was 7.5/2.2 kg nitrogen ha (-1)yr(-1), 6.3/ 4.9 kg nitrogen ha (-1)yr(-1), and 1.9/0.4 kg phosphorus ha (-1)yr(-1), respectively. Significant differences between the DW and DD methods indicated that both methods should be employed simultaneously when analyzing deposition to aquatic and terrestrial ecosystems in watershed areas. The dry deposition of ammonium, nitrate, and total phosphorus contributed 38%, 28%, and 63%, respectively, to the total deposition in the simulated aquatic ecosystem; this has significance for the field of water eutrophication control.

Utilization of open pit burned household waste ash--a feasibility study in Dhaka.

PubMed

Haque, Md Obaidul; Sharif, Ahmed

2014-05-01

Informal incineration or open pit burning of waste materials is a common practice in the peripheral area of Dhaka, one of the fastest growing mega-cities in the world. This study deals with the effect of open pit burned (i.e. open burned) household waste bottom ash on fired clay bricks. Between 0 to 50% (by weight) of open pit burned household waste bottom ash was mixed with clay to make bricks. The molded specimens were air-dried at room temperature for 24 h and then oven dried at 100 °C for another 24 h to remove the water. The raw bricks were fired in a muffle furnace to a designated temperature (800, 900 and 1000 °C, respectively). The firing behaviour (mechanical strength, water absorption and shrinkage) was determined. The microstructures, phase compositions and leachates were evaluated for bricks manufactured at different firing temperatures. These results demonstrate that open pit burned ash can be recycled in clay bricks. This study also presents physical observations of the incinerated ash particles and determination of the chemical compositions of the raw materials by wet analysis. Open pit burned ash can be introduced easily into bricks up to 20% wt. The concentrations of hazardous components in the leachates were below the standard threshold for inert waste category landfill and their environmental risk during their use-life step can be considered negligible.

Conversion of organic material by black soldier fly larvae: establishing optimal feeding rates.

PubMed

Diener, Stefan; Zurbrügg, Christian; Tockner, Klement

2009-09-01

Larvae of the black soldier fly, Hermetia illucens (Diptera: Stratiomyidae), are voracious feeders of organic material and may thus be used in simple engineered systems to reduce organic waste in low- and middle-income countries. Controlled feeding experiments with standard fodder were conducted to assess the optimum amount of organic waste to be added to a CORS system (Conversion of Organic Refuse by Saprophages). A daily feeding rate of 100 mg chicken feed (60% moisture content) per larva resulted in an optimum trade-off between material reduction efficiency (41.8%, SE 0.61) and biomass production (prepupal dry weight: 48.0 mg, SE 2.0). Applied to market waste and human faeces, this corresponds to a potential daily feeding capacity of 3-5 kg/m(2) and 6.5 kg/m(2), respectively. In addition, H. illucens prepupae quality was assessed to determine their suitability to substitute fishmeal in animal feed production. The chitin-corrected crude protein content ranged from 28.2 to 42.5%, depending on the amount of food provided to the larvae. Based on our study, a waste processing unit could yield a daily prepupal biomass of 145 g (dry mass) per m(2). We conclude that larvae of the black soldier fly are potentially capable of converting large amounts of organic waste into protein-rich biomass to substitute fishmeal, thereby contributing to sustainable aquaculture.

Suspected hypoglycaemia in out patient practice: accuracy of dried blood spot analysis.

PubMed

Parker, D R; Bargiota, A; Cowan, F J; Corrall, R J

1997-12-01

The assay of dried blood spots on filter paper to determine blood glucose concentration has been used to detect hypoglycaemia in out patients. We assessed the accuracy of this approach in assaying blood glucose concentrations in the hypoglycaemic range. Volunteers were rendered hypoglycaemic by intravenous infusion of insulin. The glucose concentration in simultaneously taken blood samples was measured either fresh or after drying on filter paper. Twenty-four healthy young volunteers and 9 patients with insulin-dependent diabetes were studied. Plasma glucose concentrations were measured using a standard auto analyser glucose oxidase method. Whole blood taken simultaneously was placed on prepared filter paper and allowed to dry; glucose concentration was then measured using a well-established technique. A correction factor was applied to convert the glucose concentration of plasma to that of whole blood. The relationship between glucose concentrations measured by the two methods was determined by regression coefficient. In the unequivocally hypoglycaemic range (plasma < or = 2.5 mmol/l), corrected dried blood spot glucose concentrations significantly correlated with standard plasma glucose concentrations (r = 0.81; P < 0.001). The dried blood spot method had a sensitivity of 91%. In the range designated probable hypoglycaemia (plasma < or = 3.3 mmol/l), there was also significant correlation (r = 0.90; P < 0.001) and the sensitivity was 96%. The specificity of the dried blood spot method was 100% in both ranges. Measurement of glucose concentrations in dried blood spots is specific and sensitive in the hypoglycaemic range. The present study indicates that hypoglycaemia may be excluded or confirmed respectively when levels in excess of 3.7 or below 2.8 mmol/l are found in uncorrected dried blood spot analysis.

Simultaneous personnel and vehicle shift scheduling in the waste management sector.

PubMed

Ghiani, Gianpaolo; Guerriero, Emanuela; Manni, Andrea; Manni, Emanuele; Potenza, Agostino

2013-07-01

Urban waste management is becoming an increasingly complex task, absorbing a huge amount of resources, and having a major environmental impact. The design of a waste management system consists in various activities, and one of these is related to the definition of shift schedules for both personnel and vehicles. This activity has a great incidence on the tactical and operational cost for companies. In this paper, we propose an integer programming model to find an optimal solution to the integrated problem. The aim is to determine optimal schedules at minimum cost. Moreover, we design a fast and effective heuristic to face large-size problems. Both approaches are tested on data from a real-world case in Southern Italy and compared to the current practice utilized by the company managing the service, showing that simultaneously solving these problems can lead to significant monetary savings. Copyright © 2013 Elsevier Ltd. All rights reserved.

Installation Restoration Program. Phase I. Records Search, Hazardous Materials Disposal Sites, Griffiss AFB, New York.

DTIC Science & Technology

1981-07-01

Disposal Methods 4-31 Evaluation of Past and Present Waste 4-35 Disposal Facilities Landfills 4-35 Dry Wells 4-37 Rating of Waste Disposal Sites 4-37 V 2...Problems Identified at GAPE Landfills 4-36 4.12 Priority Ranking of Potential 4-38 Contamination Sources 4.13 -4.31 Rating Forms for Waste Disposal Sites 4...39 -4-76 5.1 Priority Ranking of Potential Con- 5-2 tamination Sources B.1 Rating Factor System B-2 -B-5 4W EXECUTIVE SUMMARY The Resource

Waste streams in a crewed space habitat. II

NASA Technical Reports Server (NTRS)

Golub, Morton A.; Wydeven, Theodore

1992-01-01

An update is presented of a compilation of generation rates and chemical compositions of potential waste streams in a typical crewed space habitat which was reported in the NASA Technical Memorandum. New topics under consideration include data obtained from Soviet literature on life support issues and data on various minor human body wastes not presented previously (saliva, Flatus, hair, finger- and toenails, dried skin and skin secretions, tears and semen). Attention is also given to the latest information on the environmental control and life support system design parameters for SSF.

Obtaining of caffeine from Turkish tea fiber and stalk wastes.

PubMed

Gürü, M; Içen, H

2004-08-01

The aim of this study was to find a cheap method to obtain caffeine. Experiments were performed on fiber and stalk wastes of Turkish tea plants that had no economical value other than being used merely as low grade fuel and fodder. Tea stalks and fiber were obtained from tea factories. Parameters affecting caffeine extraction from tea wastes were determined to be, mixing rate, water/tea ratio, temperature, time and particle size. The maximum yields by dried mass from the tea fibers and stalks were 1.16% and 0.92%, respectively.

Using MCDA and GIS for hazardous waste landfill siting considering land scarcity for waste disposal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feo, Giovanni De, E-mail: g.defeo@unisa.it; Gisi, Sabino De

Highlights: • Wasting land for the siting of hazardous waste landfills must be avoided. • The siting procedure is based on a land use map of potentially suitable areas. • All the waste facilities of the management system are simultaneously considered. • A case study is developed considering two multi-criteria techniques. • An innovative criteria weighting tool (PSW) is used in combination with the AHP. - Abstract: The main aim of this study was to develop a procedure that minimizes the wasting of space for the siting of hazardous waste landfills as part of a solid waste management system. Wemore » wanted to tackle the shortage of land for waste disposal that is a serious and growing problem in most large urban regions. The procedure combines a multi-criteria decision analysis (MCDA) approach with a geographical information system (GIS). The GIS was utilised to obtain an initial screening in order to eliminate unsuitable areas, whereas the MCDA was developed to select the most suitable sites. The novelty of the proposed siting procedure is the introduction of a new screening phase before the macro-siting step aimed at producing a “land use map of potentially suitable areas” for the siting of solid waste facilities which simultaneously takes into consideration all plant types. The issue of obtaining sites evaluations of a specific facility was coupled with the issue of not wasting land appropriate to facilitate other types of waste management options. In the developed case study, the use of an innovative criteria weighting tool (the “Priority Scale”) in combination with the Analytic Hierarchy Process was useful to easier define the priorities of the evaluation criteria in comparison with other classic methods such as the Paired Comparison Technique in combination with the Simple Additive Weighting method.« less

Simultaneous Heat and Mass Transfer Model for Convective Drying of Building Material

NASA Astrophysics Data System (ADS)

Upadhyay, Ashwani; Chandramohan, V. P.

2018-04-01

A mathematical model of simultaneous heat and moisture transfer is developed for convective drying of building material. A rectangular brick is considered for sample object. Finite-difference method with semi-implicit scheme is used for solving the transient governing heat and mass transfer equation. Convective boundary condition is used, as the product is exposed in hot air. The heat and mass transfer equations are coupled through diffusion coefficient which is assumed as the function of temperature of the product. Set of algebraic equations are generated through space and time discretization. The discretized algebraic equations are solved by Gauss-Siedel method via iteration. Grid and time independent studies are performed for finding the optimum number of nodal points and time steps respectively. A MATLAB computer code is developed to solve the heat and mass transfer equations simultaneously. Transient heat and mass transfer simulations are performed to find the temperature and moisture distribution inside the brick.

Chemical composition and methane potential of commercial food wastes.

PubMed

Lopez, Victoria M; De la Cruz, Florentino B; Barlaz, Morton A

2016-10-01

There is increasing interest in anaerobic digestion in the U.S. However, there is little information on the characterization of commercial food waste sources as well as the effect of waste particle size on methane yield. The objective of this research was to characterize four commercial food waste sources: (1) university dining hall waste, (2) waste resulting from prepared foods and leftover produce at a grocery store, (3) food waste from a hotel and convention center, and (4) food preparation waste from a restaurant. Each sample was tested in triplicate 8L batch anaerobic digesters after shredding and after shredding plus grinding. Average methane yields for the university dining, grocery store, hotel, and restaurant wastes were 363, 427, 492, and 403mL/dry g, respectively. Starch exhibited the most complete consumption and particle size did not significantly affect methane yields for any of the tested substrates. Lipids represented 59-70% of the methane potential of the fresh substrates. Copyright © 2016 Elsevier Ltd. All rights reserved.

Mixed-waste treatment -- What about the residuals?. A compartive analysis of MSO and incineration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carlson, T.; Carpenter, C.; Cummins, L.

1993-11-01

Incineration currently is the best demonstrated available technology for the large inventory of U.S. Department of Energy (DOE) mixed waste. However, molten salt oxidation (MSO) is an alternative thermal treatment technology with the potential to treat a number of these wastes. Of concern for both technologies is the final waste forms, or residuals, that are generated by the treatment process. An evaluation of the two technologies focuses on 10 existing DOE waste streams and current hazardous-waste regulations, specifically for the delisting of ``derived-from`` residuals. Major findings include that final disposal options are more significantly impacted by the type of wastemore » treated and existing regulations than by the type of treatment technology; typical DOE waste streams are not good candidates for delisting; and mass balance calculations indicate that MSO and incineration generate similar quantities (dry) and types of residuals.« less

Periodic Verification of the Scaling Factor for Radwastes in Korean NPPs - 13294

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Yong Joon; Ahn, Hong Joo; Song, Byoung Chul

2013-07-01

According to the acceptance criteria for a low and intermediate level radioactive waste (LILW) listed in Notice No. 2012-53 of the Nuclear Safety and Security Commission (NSSC), specific concentrations of radionuclides inside a drum has to be identified and quantified. In 5 years of effort, scaling factors were derived through destructive radiochemical analysis, and the dry active waste, spent resin, concentration bottom, spent filter, and sludge drums generated during 2004 ∼ 2008 were evaluated to identify radionuclide inventories. Eventually, only dry active waste among LILWs generated from Korean NPPs were first shipped to a permanent disposal facility on December 2010.more » For the LILWs generated after 2009, the radionuclides are being radiochemically quantified because the Notice clarifies that the certifications of the scaling factors should be verified biennially. During the operation of NPP, the radionuclides designated in the Notice are formed by neutron activation of primary coolant, reactor structural materials, corrosion products, and fission products released into primary coolant through defects or failures in fuel cladding. Eventually, since the radionuclides released into primary coolant are transported into the numerous auxiliary and support systems connected to primary system, the LILWs can be contaminated, and the radionuclides can have various concentration distributions. Thus, radioactive wastes, such as spent resin and dry active waste generated at various Korean NPP sites, were sampled at each site, and the activities of the regulated radionuclides present in the sample were determined using radiochemical methods. The scaling factors were driven on the basis of the activity ratios between a or β-emitting nuclides and γ-emitting nuclides. The resulting concentrations were directly compared with the established scaling factors' data using statistical methods. In conclusions, the established scaling factors were verified with a reliability of within 2σ, and the scaling factors will be applied for newly analyzed LILWs to evaluate the radionuclide inventories. (authors)« less

Pulsed atmospheric fluidized bed combustor apparatus and process

DOEpatents

Mansour, Momtaz N.

1992-01-01

A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g. organic and medical waste, drying, calcining and the like.

Effect of microwave- and microwave-convection drying conditions on the total soluble phenolic content of 2-phase olive mill waste

USDA-ARS?s Scientific Manuscript database

The California olive oil industry produces tons of 2-phase olive mill waste (2POMW) every year as a byproduct of the olive oil milling process. 2POMW is rich in health-promoting phenolic compounds, but it is greater than 60% moisture (wet basis) in its native form and thus expensive to store and tr...

Battery collection in municipal waste management in Japan: Challenges for hazardous substance control and safety

DOE Office of Scientific and Technical Information (OSTI.GOV)

Terazono, Atsushi, E-mail: terazono@nies.go.jp; Oguchi, Masahiro; Iino, Shigenori

Highlights: • Consumers need to pay attention to the specific collection rules for each type of battery in each municipality in Japan. • 6–10% of zinc carbon and alkaline batteries discarded in Japan currently could be regarded as containing mercury. • Despite announcements by producers and municipalities, only 2.0% of discarded cylindrical dry batteries were insulated. • Batteries made up an average of 4.6% of the total collected small WEEE under the small WEEE recycling scheme in Japan. • Exchangeable batteries were used in almost all of mobile phones, but the removal rate was as low as 22% for mobilemore » phones. - Abstract: To clarify current collection rules of waste batteries in municipal waste management in Japan and to examine future challenges for hazardous substance control and safety, we reviewed collection rules of waste batteries in the Tokyo Metropolitan Area. We also conducted a field survey of waste batteries collected at various battery and small waste electric and electronic equipment (WEEE) collection sites in Tokyo. The different types of batteries are not collected in a uniform way in the Tokyo area, so consumers need to pay attention to the specific collection rules for each type of battery in each municipality. In areas where small WEEE recycling schemes are being operated after the enforcement of the Act on Promotion of Recycling of Small Waste Electrical and Electronic Equipment in Japan in 2013, consumers may be confused about the need for separating batteries from small WEEE (especially mobile phones). Our field survey of collected waste batteries indicated that 6–10% of zinc carbon and alkaline batteries discarded in Japan currently could be regarded as containing mercury. More than 26% of zinc carbon dry batteries currently being discarded may have a lead content above the labelling threshold of the EU Batteries Directive (2006/66/EC). In terms of safety, despite announcements by producers and municipalities about using insulation (tape) on waste batteries to prevent fires, only 2.0% of discarded cylindrical dry batteries were insulated. Our field study of small WEEE showed that batteries made up an average of 4.6% of the total collected small WEEE on a weight basis. Exchangeable batteries were used in almost all of mobile phones, digital cameras, radios, and remote controls, but the removal rate was as low as 22% for mobile phones. Given the safety issues and the rapid changes occurring with mobile phones or other types of small WEEE, discussion is needed among stakeholders to determine how to safely collect and recycle WEEE and waste batteries.« less

Development of black soldier fly (Diptera: Stratiomyidae) larvae fed dairy manure.

PubMed

Myers, Heidi M; Tomberlin, Jeffery K; Lambert, Barry D; Kattes, David

2008-02-01

Black soldier flies, Hermetia illucens L., are a common colonizer of animal wastes. However, all published development data for this species are from studies using artificial diets. This study represents the first examining black soldier fly development on animal wastes. Additionally, this study examined the ability of black soldier fly larvae to reduce dry matter and associated nutrients in manure. Black soldier fly larvae were fed four rates of dairy manure to determine their effects on larval and adult life history traits. Feed rate affected larval and adult development. Those fed less ration daily weighed less than those fed a greater ration. Additionally, larvae provided the least amount of dairy manure took longer to develop to the prepupal stage; however, they needed less time to reach the adult stage. Adults resulting from larvae provided 27 g dairy manure/d lived 3-4 d less than those fed 70 g dairy manure. Percentage survivorship to the prepupal or adult stages did not differ across treatments. Larvae fed 27 g dairy manure daily reduced manure dry matter mass by 58%, whereas those fed 70 g daily reduced dry matter 33%. Black soldier fly larvae were able to reduce available P by 61-70% and N by 30-50% across treatments. Based on results from this study, the black soldier fly could be used to reduce wastes and associated nutrients in confined bovine facilities.

Lifecycle assessment of a system for food waste disposers to tank - A full-scale system evaluation.

PubMed

Bernstad Saraiva, A; Davidsson, Å; Bissmont, M

2016-08-01

An increased interest for separate collection of household food waste in Sweden has led to development of a number of different collection-systems - each with their particular benefits and drawbacks. In the present study, two systems for collection of food waste in households were compared; (a) use of food waste disposers (FWD) in kitchen sinks and (b) collection of food waste in paper bags for further treatment. The comparison was made in relation to greenhouse gas emissions as well as primary energy utilization. In both cases, collected food waste was treated through anaerobic digestion and digestate was used as fertilizer on farmland. Systems emissions of greenhouse gases from collection and treatment of 1ton of food waste (dry matter), are according to the performed assessment lower from the FWD-system compared to the reference system (-990 and -770kgCO2-eq./ton food waste dry matter respectively). The main reasons are a higher substitution of mineral nitrogen fertilizer followed by a higher substitution of diesel. Performed uncertainty analyses state that results are robust, but that decreasing losses of organic matter in pre-treatment of food waste collected in paper bags, as well as increased losses of organic matter and nutrients from the FWD-system could change the hierarchy in relation to greenhouse gas emissions. Owing to a higher use of electricity in the FWD-system, the paper bag collection system was preferable in relation to primary energy utilization. Due to the many questions still remaining regarding the impacts of an increased amount of nutrients and organic matter to the sewage system through an increased use of FWD, the later treatment of effluent from the FWD-system, as well as treatment of wastewater from kitchen sinks in the reference system, was not included in the assessment. In future work, these aspects would be of relevance to monitor. Copyright © 2016 Elsevier Ltd. All rights reserved.

Chemical digestion of low level nuclear solid waste material

DOEpatents

Cooley, Carl R.; Lerch, Ronald E.

1976-01-01

A chemical digestion for treatment of low level combustible nuclear solid waste material is provided and comprises reacting the solid waste material with concentrated sulfuric acid at a temperature within the range of 230.degree.-300.degree.C and simultaneously and/or thereafter contacting the reacting mixture with concentrated nitric acid or nitrogen dioxide. In a special embodiment spent ion exchange resins are converted by this chemical digestion to noncombustible gases and a low volume noncombustible residue.

29 CFR 1915.91 - Housekeeping.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) All working areas on or immediately surrounding vessels and dry docks, graving docks, or marine... boxes or fire-extinguishing equipment. (e) All oils, paints thinners, solvents, waste, rags, or other...

Separation and collection of coarse aggregate from waste concrete by electric pulsed power

NASA Astrophysics Data System (ADS)

Shigeishi, Mitsuhiro

2017-09-01

Waste concrete accounts for a substantial fraction of construction waste, and the recycling of waste concrete as concrete aggregate for construction is an important challenge associated with the rapid increase in the amount of waste concrete and the tight supply of natural aggregate. In this study, we propose a technique based on the use of high-voltage pulsed electric discharge into concrete underwater for separating and collecting aggregate from waste concrete with minimal deterioration of quality. By using this technique, the quality of the coarse aggregate separated and collected from concrete test specimens is comparable to that of coarse aggregate recycled by heating and grinding methods, thus satisfying the criteria in Japan Industrial Standard (JIS) A 5021 for the oven-dry density and the water absorption of coarse aggregate by advanced recycling.

Co-composting of Beef Cattle Feedlot Manure with Construction and Demolition Waste.

PubMed

Hao, Xiying; Hill, Brett; Caffyn, Pam; Travis, Greg; Olson, Andrew F; Larney, Francis J; McAllister, Tim; Alexander, Trevor

2014-09-01

With increased availability of dried distillers' grains with solubles (DDGS) as cattle feed and the need to recycle organic wastes, this research investigated the feasibility of co-composting DDGS cattle feedlot manure with construction and demolition (C&D) waste. Manure was collected from cattle fed a typical western Canadian finishing diet (CK) of 860 g rolled barley ( L.) grain, 100 g barley silage, and 40 g vitamin and mineral supplement kg dry matter (DM) and from cattle fed the same diet but (DG manure) with 300 g kg DM barley grain being replaced by DDGS. The CK and DG manures were co-composted with and without C&D waste in 13 m bins. Compost materials were turned on Days 14, 37, and 64, and terminated on Day 99. Adding C&D waste led to higher compost temperatures (0.4 to 16.3°C, average 7.2°C) than manure alone. Final composts had similar total C, total N, C/N ratios, and water-extractable K, Mg, and NO content across all treatments. However, adding C&D waste increased δC, δN, water-extractable SO, and Ca contents and decreased pH, total P (TP), water-extractable C, N, and P and most volatile fatty acids (VFA). The higher C&D compost temperatures should reduce pathogens while reduced VFA content should reduce odors. When using the final compost product, the increased SO and reduced TP and available N and P content in C&D waste compost should be taken into consideration. Increased S content in C&D compost may be beneficial for some crops grown on S-deficient soils. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Potential of diatom consortium developed by nutrient enrichment for biodiesel production and simultaneous nutrient removal from waste water.

PubMed

Marella, Thomas Kiran; Parine, Narasimha Reddy; Tiwari, Archana

2018-05-01

Because of the decreasing fossil fuel supply and increasing greenhouse gas (GHG) emissions, microalgae have been identified as a viable and sustainable feedstock for biofuel production. The major effect of the release of wastewater rich in organic compounds has led to the eutrophication of freshwater ecosystems. A combined approach of freshwater diatom cultivation with urban sewage water treatment is a promising solution for nutrient removal and biofuel production. In this study, urban wastewater from eutrophic Hussain Sagar Lake was used to cultivate a diatom algae consortium, and the effects of silica and trace metal enrichment on growth, nutrient removal, and lipid production were evaluated. The nano-silica-based micronutrient mixture Nualgi containing Si, Fe, and metal ions was used to optimize diatom growth. Respectively, N and P reductions of 95.1% and 88.9%, COD and BOD reductions of 91% and 51% with a biomass yield of 122.5 mg L -1  day -1 and lipid productivity of 37 mg L -1  day -1 were observed for cultures grown in waste water using Nualgi. Fatty acid profiles revealed 13 different fatty acids with slight differences in their percentage of dry cell weight (DCW) depending on enrichment level. These results demonstrate the potential of diatom algae grown in wastewater to produce feedstock for renewable biodiesel production. Enhanced carbon and excess nutrient utilization makes diatoms ideal candidates for co-processes such as CO 2 sequestration, biodiesel production, and wastewater phycoremediation.

Occurrence and Source Effect of Novel Brominated Flame Retardants (NBFRs) in Soils from Five Asian Countries and Their Relationship with PBDEs.

PubMed

Li, Wen-Long; Ma, Wan-Li; Zhang, Zi-Feng; Liu, Li-Yan; Song, Wei-Wei; Jia, Hong-Liang; Ding, Yong-Sheng; Nakata, Haruhiko; Minh, Nguyen Hung; Sinha, Ravindra Kumar; Moon, Hyo-Bang; Kannan, Kurunthachalam; Sverko, Ed; Li, Yi-Fan

2017-10-03

This paper presents the first comprehensive survey of 19 novel brominated flame retardants (NBFRs) in soil samples collected among five Asian countries. High variability in concentrations of all NBFRs was found in soils with the geometric mean (GM) values ranging from 0.50 ng/g dry weight (dw) in Vietnam to 540 ng/g dw in the vicinity of a BFR manufacturer in China. In urban, rural, and background locations, the GM concentrations of ∑ 19 NBFRs decreased in the order of Japan > South Korea > China > India > Vietnam. Correlations among different NBFR compounds were positive and statistically significant (p < 0.05), suggesting that they originate from similar sources. Evidence for simultaneous application between polybrominated diphenyl ethers (PBDEs) and NBFRs were also noted. Principal component analysis of NBFR concentrations revealed specific pollution sources for different NBFRs coming from urban, BFR-related industrial, and e-waste sites. For the first time, this study demonstrates a "point source fractionation effect" for NBFRs and PBDEs. The concentrations of all NBFRs and PBDEs were negatively and significantly correlated with the distance from BFR-related industrial and e-waste regions. Positive and significant correlation between population density and NBFR concentrations in soils was identified. Our study revealed that the primary sources effects were stronger than the secondary sources effects in controlling the levels and distribution of NBFRs and PBDEs in soils in these five Asian countries.

Experimental investigation of wood combustion in a fixed bed with hot air

DOE Office of Scientific and Technical Information (OSTI.GOV)

Markovic, Miladin, E-mail: m.markovic@utwente.nl; Bramer, Eddy A.; Brem, Gerrit

Highlights: • Upward combustion is a new combustion concept with ignition by hot primary air. • Upward combustion has three stages: short drying, rapid devolatilization and char combustion. • Variation of fuel moisture and inert content have little influence on the combustion. • Experimental comparison between conventional and upward combustion is presented. - Abstract: Waste combustion on a grate with energy recovery is an important pillar of municipal solid waste (MSW) management in the Netherlands. In MSW incinerators fresh waste stacked on a grate enters the combustion chamber, heats up by radiation from the flame above the layer and ignitionmore » occurs. Typically, the reaction zone starts at the top of the waste layer and propagates downwards, producing heat for drying and devolatilization of the fresh waste below it until the ignition front reaches the grate. The control of this process is mainly based on empiricism. MSW is a highly inhomogeneous fuel with continuous fluctuating moisture content, heating value and chemical composition. The resulting process fluctuations may cause process control difficulties, fouling and corrosion issues, extra maintenance, and unplanned stops. In the new concept the fuel layer is ignited by means of preheated air (T > 220 °C) from below without any external ignition source. As a result a combustion front will be formed close to the grate and will propagate upwards. That is why this approach is denoted by upward combustion. Experimental research has been carried out in a batch reactor with height of 4.55 m, an inner diameter of 200 mm and a fuel layer height up to 1 m. Due to a high quality two-layer insulation adiabatic conditions can be assumed. The primary air can be preheated up to 350 °C, and the secondary air is distributed via nozzles above the waste layer. During the experiments, temperatures along the height of the reactor, gas composition and total weight decrease are continuously monitored. The influence of the primary air speed, fuel moisture and inert content on the combustion characteristics (ignition rate, combustion rate, ignition front speed and temperature of the reaction zone) is evaluated. The upward combustion concept decouples the drying, devolatilization and burnout phase. In this way the moisture and inert content of the waste have almost no influence on the combustion process. In this paper an experimental comparison between conventional and reversed combustion is presented.« less

Modeling and optimization of red currants vacuum drying process by response surface methodology (RSM).

PubMed

Šumić, Zdravko; Vakula, Anita; Tepić, Aleksandra; Čakarević, Jelena; Vitas, Jasmina; Pavlić, Branimir

2016-07-15

Fresh red currants were dried by vacuum drying process under different drying conditions. Box-Behnken experimental design with response surface methodology was used for optimization of drying process in terms of physical (moisture content, water activity, total color change, firmness and rehydratation power) and chemical (total phenols, total flavonoids, monomeric anthocyanins and ascorbic acid content and antioxidant activity) properties of dried samples. Temperature (48-78 °C), pressure (30-330 mbar) and drying time (8-16 h) were investigated as independent variables. Experimental results were fitted to a second-order polynomial model where regression analysis and analysis of variance were used to determine model fitness and optimal drying conditions. The optimal conditions of simultaneously optimized responses were temperature of 70.2 °C, pressure of 39 mbar and drying time of 8 h. It could be concluded that vacuum drying provides samples with good physico-chemical properties, similar to lyophilized sample and better than conventionally dried sample. Copyright © 2016 Elsevier Ltd. All rights reserved.

A Review of the Anaerobic Digestion of Fruit and Vegetable Waste.

PubMed

Ji, Chao; Kong, Chui-Xue; Mei, Zi-Li; Li, Jiang

2017-11-01

Fruit and vegetable waste is an ever-growing global question. Anaerobic digestion techniques have been developed that facilitate turning such waste into possible sources for energy and fertilizer, simultaneously helping to reduce environmental pollution. However, various problems are encountered in applying these techniques. The purpose of this study is to review local and overseas studies, which focus on the use of anaerobic digestion to dispose fruit and vegetable wastes, discuss the acidification problems and solutions in applying anaerobic digestion for fruit and vegetable wastes and investigate the reactor design (comparing single phase with two phase) and the thermal pre-treatment for processing raw wastes. Furthermore, it analyses the dominant microorganisms involved at different stages of digestion and suggests a focus for future studies.

The comparison of fossil carbon fraction and greenhouse gas emissions through an analysis of exhaust gases from urban solid waste incineration facilities.

PubMed

Kim, Seungjin; Kang, Seongmin; Lee, Jeongwoo; Lee, Seehyung; Kim, Ki-Hyun; Jeon, Eui-Chan

2016-10-01

In this study, in order to understand accurate calculation of greenhouse gas emissions of urban solid waste incineration facilities, which are major waste incineration facilities, and problems likely to occur at this time, emissions were calculated by classifying calculation methods into 3 types. For the comparison of calculation methods, the waste characteristics ratio, dry substance content by waste characteristics, carbon content in dry substance, and (12)C content were analyzed; and in particular, CO2 concentration in incineration gases and (12)C content were analyzed together. In this study, 3 types of calculation methods were made through the assay value, and by using each calculation method, emissions of urban solid waste incineration facilities were calculated then compared. As a result of comparison, with Calculation Method A, which used the default value as presented in the IPCC guidelines, greenhouse gas emissions were calculated for the urban solid waste incineration facilities A and B at 244.43 ton CO2/day and 322.09 ton CO2/day, respectively. Hence, it showed a lot of difference from Calculation Methods B and C, which used the assay value of this study. It is determined that this was because the default value as presented in IPCC, as the world average value, could not reflect the characteristics of urban solid waste incineration facilities. Calculation Method B indicated 163.31 ton CO2/day and 230.34 ton CO2/day respectively for the urban solid waste incineration facilities A and B; also, Calculation Method C indicated 151.79 ton CO2/day and 218.99 ton CO2/day, respectively. This study intends to compare greenhouse gas emissions calculated using (12)C content default value provided by the IPCC (Intergovernmental Panel on Climate Change) with greenhouse gas emissions calculated using (12)C content and waste assay value that can reflect the characteristics of the target urban solid waste incineration facilities. Also, the concentration and (12)C content were calculated by directly collecting incineration gases of the target urban solid waste incineration facilities, and greenhouse gas emissions of the target urban solid waste incineration facilities through this survey were compared with greenhouse gas emissions, which used the previously calculated assay value of solid waste.

Manufacture of reconstruction-bricks in Mexico

NASA Astrophysics Data System (ADS)

Rojas-Valencia, Ma. Neftalí; Penagos, Armando Aguilar; Rojas, Denise Y. Fernández; López, Alberto López; Gálves, David Morillón

2017-12-01

In Mexico, around 33.600 tons of construction wastes are generated every day, Mexico City contributing for around tons/day, with fewer than 1.000 tons/day being sent to be recycled. For that reason the purpose of this study was to manufacture sustainable bricks, based on three types of wastes generated in the building industry: wood cutting residues, wastes from the excavation process (From Coapa and Cuautlancingo, Puebla, Mexico) and recycled aggregates. Water was added as kneading material, and Opuntia ficus-indica (mucilage) was supplemented as natural additive to improve the workability of the mixtures. Conventional firing process was substituted by drying in a solar drying chamber. Nine mixtures were prepared using 62% excavation wastes, 4% wood cutting residues and 11%, 17% and 34% recycled aggregates. These mixtures were classified in two groups depending on their granulometry: the first one denominated cementitious recycled aggregates only having granulometry from 25.4 mm, 9.52 mm to 6.35 mm to fines and the second group denominated all in one recycled aggregates having granulometry of 6.35 mm to fines. The quality of the sustainable bricks was evaluated according to compressive strength and water absorption parameters. The results of nine mixtures showed that the reconstruction-bricks manufactured with the mixture seven consisting of 9.52 mm and 6.35 mm construction residues (all in one) fines presented the highest strength values, lowest maximum initial absorption (4 g/min) compared to the norm NMX-C-037-ONNCCE-2013 which establishes that the maximum limit for walls exposed to the outside is 5 g/min. Using a solar desiccator made from construction residues, the bricks were dried in 11 days, the maximum temperature was 76 °C and the maximum solar radiation captured was 733.4 W/m2.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brandstätter, Christian, E-mail: bran.chri@gmail.com; Laner, David, E-mail: david.laner@tuwien.ac.at; Fellner, Johann, E-mail: johann.fellner@tuwien.ac.at

Graphical abstract: Display Omitted - Highlights: • 40 year old waste from an old MSW landfill was incubated in LSR experiments. • Carbon balances for anaerobic and aerobic waste degradation were established. • The transformation of carbon pools during waste degradation was investigated. • Waste aeration resulted in the formation of a new, stable organic carbon pool. • Water addition did not have a significant effect on aerobic waste degradation. - Abstract: Landfill aeration has been proven to accelerate the degradation of organic matter in landfills in comparison to anaerobic decomposition. The present study aims to evaluate pools of organicmore » matter decomposing under aerobic and anaerobic conditions using landfill simulation reactors (LSR) filled with 40 year old waste from a former MSW landfill. The LSR were operated for 27 months, whereby the waste in one pair was kept under anaerobic conditions and the four other LSRs were aerated. Two of the aerated LSR were run with leachate recirculation and water addition and two without. The organic carbon in the solid waste was characterized at the beginning and at the end of the experiments and major carbon flows (e.g. TOC in leachate, gaseous CO{sub 2} and CH{sub 4}) were monitored during operation. After the termination of the experiments, the waste from the anaerobic LSRs exhibited a long-term gas production potential of more than 20 NL kg{sup −1} dry waste, which corresponded to the mineralization of around 12% of the initial TOC (67 g kg{sup −1} dry waste). Compared to that, aeration led to threefold decrease in TOC (32–36% of the initial TOC were mineralized), without apparent differences in carbon discharge between the aerobic set ups with and without water addition. Based on the investigation of the carbon pools it could be demonstrated that a bit more than 10% of the initially present organic carbon was transformed into more recalcitrant forms, presumably due to the formation of humic substances. The source of anaerobic degradation could be identified mainly as cellulose which played a minor role during aerobic degradation in the experiment.« less

Exposure to PCBs, through inhalation, dermal contact and dust ingestion at Taizhou, China--a major site for recycling transformers.

PubMed

Xing, Guan Hua; Liang, Ying; Chen, Ling Xuan; Wu, Sheng Chun; Wong, Ming Hung

2011-04-01

Air samples containing gaseous and particulate phases were collected from e-waste workplaces and residential areas of an intensive e-waste recycling area and compared with a reference site. The highest total concentration of PCBs was detected at transformer recycling workshops (17.6 ng m(-3)), followed by the residential area (3.37 ng m(-3)) at Taizhou, and the lowest was obtained at the residential area of the reference site, Lin'an (0.46 ng m(-3)). The same trend was also observed with regards to PCB levels in dust samples. The highest average PCBs level of 2824 ng g(-1) (dry wt) was found in the transformer recycling workshops, and was significantly higher than that of residential areas of Taizhou (572 ng g(-1) dry wt) and Lin'an (42.4 ng g(-1) dry wt). WHO-PCB-TEQ level in the workshops of Taizhou was 2216 pg TEQ(1998)g(-1) dry wt or 2159 pg TEQ(2005)g(-1) dry wt, due to the high abundance of PCB 126 (21.5 ng g(-1) dry wt), which contributed 97% or 99% of WHO-PCB-TEQs. The estimated intake of PCBs via dust ingestion and dermal absorption by transformer recycling workers were 77.5×10(-5) and 36.0×10(-5) pg WHO-PCB-TEQ(1998)kg(-1)d(-1), and 67.3×10(-5) and 31.3×10(-5) pg WHO-PCB-TEQ(2005)kg(-1)d(-1), respectively. Copyright © 2011. Published by Elsevier Ltd.

Studies on the current state of water quality in the Segamat River

NASA Astrophysics Data System (ADS)

Razelan, Faridah Mohd; Tahir, Wardah; E. M Yahaya, Nasehir Khan

2018-04-01

Nowadays, pollution has become a major concern in developed and developing countries. In a study on the current state of Segamat River water quality; on-site data collection and observation and also laboratory data analysis have been implemented. Studies showed that the downstream of the Segamat River has recorded a significant reduction in quality of water during the dry season compared to the wet season. The deterioration of water quality is caused by the activities along the river such as palm oil plantation, municipal waste and waste from settlements. It was also recorded that the point sources were dominating the pollution at Segamat River during the dry season. However, during the wet season, the water quality was impaired by the non-point sources which originated from the upstream of the river.

PCDD/F enviromental impact from municipal solid waste bio-drying plant.

PubMed

Rada, E C; Ragazzi, M; Zardi, D; Laiti, L; Ferrari, A

2011-06-01

The present work indentifies some environmental and health impacts of a municipal solid waste bio-drying plant taking into account the PCDD/F release into the atmosphere, its concentration at ground level and its deposition. Four scenarios are presented for the process air treatment and management: biofilter or regenerative thermal oxidation treatment, at two different heights. A Gaussian dispersion model, AERMOD, was used in order to model the dispersion and deposition of the PCDD/F emissions into the atmosphere. Considerations on health risk, from different exposure pathways are presented using an original approach. The case of biofilter at ground level resulted the most critical, depending on the low dispersion of the pollutants. Suggestions on technical solutions for the optimization of the impact are presented. Copyright © 2011 Elsevier Ltd. All rights reserved.

University of Wisconsin Oshkosh Anaerobic Dry Digestion Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koker, John; Lizotte, Michael

The University of Wisconsin Oshkosh Anaerobic Dry Digestion Facility is a demonstration project that supported the first commercial-scale use in the United States of high solids, static pile technology for anaerobic digestion of organic waste to generate biogas for use in generating electricity and heat. The research adds to the understanding of startup, operation and supply chain issues for anaerobic digester technology. Issues and performance were documented for equipment installation and modifications, feedstock availability and quality, weekly loading and unloading of digestion chambers, chemical composition of biogas produced, and energy production. This facility also demonstrated an urban industrial ecology approachmore » to siting such facilities near sewage treatment plants (to capture and use excess biogas generated by the plants) and organic yard waste collection sites (a source of feedstock).« less

Simultaneous recovery of phosphorus and nitrogen from anaerobic digestion effluents in municipal and livestock systems

USDA-ARS?s Scientific Manuscript database

Conservation and recovery of nitrogen (N) and phosphorus (P) from animal wastes is important in agriculture because of the high cost of commercial fertilizers and for environmental reasons. The objective of this work was to develop new technology for simultaneous N and P recovery suitable for anaero...

Dry-thermophilic anaerobic digestion of organic fraction of municipal solid waste: methane production modeling.

PubMed

Fdez-Güelfo, L A; Alvarez-Gallego, C; Sales, D; García, L I Romero

2012-03-01

The influence of particle size and organic matter content of organic fraction of municipal solid waste (OFMSW) in the overall kinetics of dry (30% total solids) thermophilic (55°C) anaerobic digestion have been studied in a semi-continuous stirred tank reactor (SSTR). Two types of wastes were used: synthetic OFMSW (average particle size of 1mm; 0.71 g Volatile Solids/g waste), and OFMSW coming from a composting full scale plant (average particle size of 30 mm; 0.16 g Volatile Solids/g waste). A modification of a widely-validated product-generation kinetic model has been proposed. Results obtained from the modified-model parameterization at steady-state (that include new kinetic parameters as K, Y(pMAX) and θ(MIN)) indicate that the features of the feedstock strongly influence the kinetics of the process. The overall specific growth rate of microorganisms (μ(max)) with synthetic OFMSW is 43% higher compared to OFMSW coming from a composting full scale plant: 0.238 d(-1) (K=1.391 d(-1); Y(pMAX)=1.167 L CH(4)/gDOC(c); θ(MIN)=7.924 days) vs. 0.135 d(-1) (K=1.282 d(-1); Y(pMAX)=1.150 L CH(4)/gDOC(c); θ(MIN)=9.997 days) respectively. Finally, it could be emphasized that the validation of proposed modified-model has been performed successfully by means of the simulation of non-steady state data for the different SRTs tested with each waste. Copyright © 2011 Elsevier Ltd. All rights reserved.

A Leptolyngbya-based microbial consortium for agro-industrial wastewaters treatment and biodiesel production.

PubMed

Tsolcha, Olga N; Tekerlekopoulou, Athanasia G; Akratos, Christos S; Antonopoulou, Georgia; Aggelis, George; Genitsaris, Savvas; Moustaka-Gouni, Maria; Vayenas, Dimitrios V

2018-04-22

A mixed cyanobacterial-mixotrophic algal population, dominated by the filamentous cyanobacterium Leptolyngbya sp. and the microalga Ochromonas (which contributed to the total photosynthetic population with rates of less than 5%), was studied under non-aseptic conditions for its efficiency to remove organic and inorganic compounds from different types of wastes/wastewaters while simultaneously producing lipids. Second cheese whey, poplar sawdust, and grass hydrolysates were used in lab-scale experiments, in photobioreactors that operated under aerobic conditions with different initial nutrient (C, N and P) concentrations. Nutrient removal rates, biomass productivity, and the maximum oil production rates were determined. The highest lipid production was achieved using the biologically treated dairy effluent (up to 14.8% oil in dry biomass corresponding to 124 mg L -1 ) which also led to high nutrient removal rates (up to 94%). Lipids synthesized by the microbial consortium contained high percentages of saturated and mono-unsaturated fatty acids (up to 75% in total lipids) for all the substrates tested, which implies that the produced biomass may be harnessed as a source of biodiesel.

Low-grade oils and fats: effect of several impurities on biodiesel production over sulfonic acid heterogeneous catalysts.

PubMed

Morales, Gabriel; Bautista, L Fernando; Melero, Juan A; Iglesias, Jose; Sánchez-Vázquez, Rebeca

2011-10-01

Different lipidic wastes and low-grade oils and fats have been characterized and evaluated as feedstocks for the acid-catalyzed production of FAME. The characterization of these materials has revealed significant contents of free fatty acids, Na, K, Ca, Mg, P, unsaponifiable matter and humidity. Arenesulfonic acid-functionalized SBA-15 silica catalyst has provided yields to FAME close to 80% in the simultaneous esterification-transesterification of the different feedstocks, regardless of their nature and properties, using methanol under the following reaction conditions: 160 °C, 2 h, methanol to oil molar ratio of 30, 8 wt.% catalyst loading, and 2000 rpm stirring rate. Nevertheless, reutilization of the catalyst is compromised by high levels of impurities, especially because of deactivation by strong interaction of unsaponifiable matter with the catalytic sites. The conditioning of these materials by aqueous washing in the presence of cationic-exchange resin Amberlyst-15, followed by a drying step, resulted in a lower deactivation of the catalyst. Copyright © 2011 Elsevier Ltd. All rights reserved.

Development of an Integrated Raman and Turbidity Fiber Optic Sensor for the In-Situ Analysis of High Level Nuclear Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gasbarro, Christina; Bello, Job M.; Bryan, Samuel A.

2013-02-24

Stored nuclear waste must be retrieved from storage, treated, separated into low- and high-level waste streams, and finally put into a disposal form that effectively encapsulates the waste and isolates it from the environment for a long period of time. Before waste retrieval can be done, waste composition needs to be characterized so that proper safety precautions can be implemented during the retrieval process. In addition, there is a need for active monitoring of the dynamic chemistry of the waste during storage since the waste composition can become highly corrosive. This work describes the development of a novel, integrated fibermore » optic Raman and light scattering probe for in situ use in nuclear waste solutions. The dual Raman and turbidity sensor provides simultaneous chemical identification of nuclear waste as well as information concerning the suspended particles in the waste using a common laser excitation source.« less

Development of an Integrated Raman and Turbidity Fiber Optic Sensor for the In-Situ Analysis of High Level Nuclear Waste - 13532

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gasbarro, Christina; Bello, Job; Bryan, Samuel

2013-07-01

Stored nuclear waste must be retrieved from storage, treated, separated into low- and high-level waste streams, and finally put into a disposal form that effectively encapsulates the waste and isolates it from the environment for a long period of time. Before waste retrieval can be done, waste composition needs to be characterized so that proper safety precautions can be implemented during the retrieval process. In addition, there is a need for active monitoring of the dynamic chemistry of the waste during storage since the waste composition can become highly corrosive. This work describes the development of a novel, integrated fibermore » optic Raman and light scattering probe for in situ use in nuclear waste solutions. The dual Raman and turbidity sensor provides simultaneous chemical identification of nuclear waste as well as information concerning the suspended particles in the waste using a common laser excitation source. (authors)« less

Thermal and chemical remediation of mixed waste

DOEpatents

Nelson, P.A.; Swift, W.M.

1994-08-09

A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500 C by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO[sub 3]. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed. 3 figs.

Thermal and chemical remediation of mixed waste

DOEpatents

Nelson, Paul A.; Swift, William M.

1994-01-01

A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500.degree. C. by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO.sub.3. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed.

Warehouse hazardous and toxic waste design in Karingau Balikpapan

NASA Astrophysics Data System (ADS)

Pratama, Bayu Rendy; Kencanawati, Martheana

2017-11-01

PT. Balikpapan Environmental Services (PT. BES) is company that having core business in Hazardous and Toxic Waste Management Services which consisting storage and transporter at Balikpapan. This research starting with data collection such as type of waste, quantity of waste, dimension area of existing building, waste packaging (Drum, IBC tank, Wooden Box, & Bulk Bag). Processing data that will be done are redesign for warehouse dimension and layout of position waste, specify of capacity, specify of quantity, type and detector placement, specify of quantity, type and fire extinguishers position which refers to Bapedal Regulation No. 01 In 1995, SNI 03-3985-2000, Employee Minister Regulation RI No. Per-04/Men/1980. Based on research that already done, founded the design for warehouse dimension of waste is 23 m × 22 m × 5 m with waste layout position appropriate with type of waste. The necessary of quantity for detector on this waste warehouse design are 56 each. The type of fire extinguisher that appropriate with this design is dry powder which containing natrium carbonate, alkali salts, with having each weight of 12 Kg about 18 units.

New Insight into Sugarcane Industry Waste Utilization (Press Mud) for Cleaner Biobutanol Production by Using C. acetobutylicum NRRL B-527.

PubMed

Nimbalkar, Pranhita R; Khedkar, Manisha A; Gaikwad, Shashank G; Chavan, Prakash V; Bankar, Sandip B

2017-11-01

In the present study, press mud, a sugar industry waste, was explored for biobutanol production to strengthen agricultural economy. The fermentative production of biobutanol was investigated via series of steps, viz. characterization, drying, acid hydrolysis, detoxification, and fermentation. Press mud contains an adequate amount of cellulose (22.3%) and hemicellulose (21.67%) on dry basis, and hence, it can be utilized for further acetone-butanol-ethanol (ABE) production. Drying experiments were conducted in the temperature range of 60-120 °C to circumvent microbial spoilage and enhance storability of press mud. Furthermore, acidic pretreatment variables, viz. sulfuric acid concentration, solid to liquid ratio, and time, were optimized using response surface methodology. The corresponding values were found to be 1.5% (v/v), 1:5 g/mL, and 15 min, respectively. In addition, detoxification studies were also conducted using activated charcoal, which removed almost 93-97% phenolics and around 98% furans, which are toxic to microorganisms during fermentation. Finally, the batch fermentation of detoxified press mud slurry (the sample dried at 100 °C and pretreated) using Clostridium acetobutylicum NRRL B-527 resulted in a higher butanol production of 4.43 g/L with a total ABE of 6.69 g/L.

Pulsed atmospheric fluidized bed combustor apparatus

DOEpatents

Mansour, Momtaz N.

1993-10-26

A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

Processing waste fats into a fuel oil substitute

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pudel, F.; Lengenfeld, P.

1993-12-31

Waste fats have a high energy potential. They also contain impurities. For example, fats used for deep-frying contain high contents of solids, water, and chlorides. The process described in this paper removes the impurities by simple processing such as screening, washing, separating, drying, and filtering. The final quality of processed fat allows its use as a fuel oil substitute, and also as a raw material for chemical production.

Filtration of Runoff From Pressure Washing Vessel Hull in Drydock

DTIC Science & Technology

1995-09-01

the most cost-effective treatment system for particular waste streams, especially heavy metals such as Tributyltin ( TBT ), Lead, Zinc, and Copper...ported the original hypothesis that little dissolved matter was present in the water. Furthermore, it suggested that TBT , if present, was unlikely to be...of the dry dock and that some vessels’ paint systems contained TBT antifoulants, although it was not noted which ones. The Maritime Industrial Waste

A comprehensive review of thin-layer drying models used in agricultural products.

PubMed

Ertekin, Can; Firat, M Ziya

2017-03-04

Drying is one of the widely used methods of grain, fruit, and vegetable preservation. The important aim of drying is to reduce the moisture content and thereby increase the lifetime of products by limiting enzymatic and oxidative degradation. In addition, by reducing the amount of water, drying reduces the crop losses, improves the quality of dried products, and facilitates its transportation, handling, and storage requirements. Drying is a process comprising simultaneous heat and mass transfer within the material, and between the surface of the material and the surrounding media. Many models have been used to describe the drying process for different agricultural products. These models are used to estimate drying time of several products under different drying conditions, and how to increase the drying process efficiency and also to generalize drying curves, for the design and operation of dryers. Several investigators have proposed numerous mathematical models for thin-layer drying of many agricultural products. This study gives a comprehensive review of more than 100 different semitheoretical and empirical thin-layer drying models used in agricultural products and evaluates the statistical criteria for the determination of appropriate model.

Composting on Mars or the Moon: II. Temperature feedback control with top-wise introduction of waste material and air

NASA Technical Reports Server (NTRS)

Finstein, M. S.; Hogan, J. A.; Sager, J. C.; Cowan, R. M.; Strom, P. F.; Janes, H. W. (Principal Investigator)

1999-01-01

Whereas Earth-based composting reactors that effectively control the process are batch operations with bottom-to-top airflow, in extraterrestrial application both the fresh waste and the air need to be introduced from above. Stabilized compost and used air would exit below. This materials flow pattern permits the addition of waste whenever generated, obviating the need for multiple reactors, and the incorporation of a commode in the lid. Top loading in turn dictates top-down aeration, so that the most actively decomposing material (greatest need for heat removal and O2 replenishment) is first encountered. This novel material and aeration pattern was tested in conjunction with temperature feedback process control. Reactor characteristics were: working, volume, 0.15 m3; charge, 2 kg dry biomass per day (comparable to a 3-4 person self-sufficient bioregenerative habitat); retention time, 7 days. Judging from temperature profile, O2 level, air usage, pressure head loss, moisture, and odor, the system was effectively controlled over a 35-day period. Dry matter disappearance averaged 25% (10-42%). The compost product was substantially, though not completely, stabilized. This demonstrates the compatibility of top-wise introduction of waste and air with temperature feedback process control.

Sustainable sources of biomass for bioremediation of heavy metals in waste water derived from coal-fired power generation.

PubMed

Saunders, Richard J; Paul, Nicholas A; Hu, Yi; de Nys, Rocky

2012-01-01

Biosorption of heavy metals using dried algal biomass has been extensively described but rarely implemented. We contend this is because available algal biomass is a valuable product with a ready market. Therefore, we considered an alternative and practical approach to algal bioremediation in which algae were cultured directly in the waste water stream. We cultured three species of algae with and without nutrient addition in water that was contaminated with heavy metals from an Ash Dam associated with coal-fired power generation and tested metal uptake and bioremediation potential. All species achieved high concentrations of heavy metals (to 8% dry mass). Two key elements, V and As, reached concentrations in the biomass of 1543 mg.kg(-1) DW and 137 mg.kg(-1) DW. Growth rates were reduced by more than half in neat Ash Dam water than when nutrients were supplied in excess. Growth rate and bioconcentration were positively correlated for most elements, but some elements (e.g. Cd, Zn) were concentrated more when growth rates were lower, indicating the potential to tailor bioremediation depending on the pollutant. The cosmopolitan nature of the macroalgae studied, and their ability to grow and concentrate a suite of heavy metals from industrial wastes, highlights a clear benefit in the practical application of waste water bioremediation.

Composting on Mars or the Moon: II. Temperature feedback control with top-wise introduction of waste material and air.

PubMed

Finstein, M S; Hogan, J A; Sager, J C; Cowan, R M; Strom, P F

1999-01-01

Whereas Earth-based composting reactors that effectively control the process are batch operations with bottom-to-top airflow, in extraterrestrial application both the fresh waste and the air need to be introduced from above. Stabilized compost and used air would exit below. This materials flow pattern permits the addition of waste whenever generated, obviating the need for multiple reactors, and the incorporation of a commode in the lid. Top loading in turn dictates top-down aeration, so that the most actively decomposing material (greatest need for heat removal and O2 replenishment) is first encountered. This novel material and aeration pattern was tested in conjunction with temperature feedback process control. Reactor characteristics were: working, volume, 0.15 m3; charge, 2 kg dry biomass per day (comparable to a 3-4 person self-sufficient bioregenerative habitat); retention time, 7 days. Judging from temperature profile, O2 level, air usage, pressure head loss, moisture, and odor, the system was effectively controlled over a 35-day period. Dry matter disappearance averaged 25% (10-42%). The compost product was substantially, though not completely, stabilized. This demonstrates the compatibility of top-wise introduction of waste and air with temperature feedback process control.

Simultaneous application of microwave energy and hot air to whole drying process of apple slices: drying kinetics, modeling, temperature profile and energy aspect

NASA Astrophysics Data System (ADS)

Horuz, Erhan; Bozkurt, Hüseyin; Karataş, Haluk; Maskan, Medeni

2018-02-01

Drying kinetics, modeling, temperature profile and energy indices were investigated in apple slices during drying by a specially designed microwave-hot air domestic hybrid oven at the following conditions: 120, 150 and 180 W microwave powers coupled with 50, 60 and 70 °C air temperatures. Both sources of energy were applied simultaneously during the whole drying processes. The drying process continued until the moisture content of apple slices reached to 20% from 86.3% (wet basis, w.b). Drying times ranged from 330 to 800 min and decreased with increasing microwave power and air temperatures. The constant rate period was only observed at low microwave powers and air temperatures. Two falling rate periods were observed. Temperature of apple slices sharply increased within the first 60 min, then reached equilibrium with drying medium and finally increased at the end of the drying process. In order to describe drying behavior of apple slices nine empirical models were applied. The Modified Logistic Model fitted the best our experimental data ( R 2 = 0.9955-0.9998; χ 2 = 3.46 × 10-5-7.85 × 10-4 and RMSE = 0.0052-0.0221). The effective moisture and thermal diffusivities were calculated by Fick's second law and ranged from 1.42 × 10-9 to 3.31 × 10-9 m2/s and 7.70 × 10-9 to 12.54 × 10-9 m2/s, respectively. The activation energy ( Ea) values were calculated from effective moisture diffusivity ( Deff), thermal diffusivity ( α) and the rate constant of the best model ( k). The Ea values found from these three terms were similar and varied from 13.04 to 33.52 kJ/mol. Energy consumption and specific energy requirement of the hybrid drying of apple slices decreased and energy efficiency of the drying system increased with increasing microwave power and air temperature. Apples can be dried rapidly and effectively by use of the hybrid technique.

Effect of different pretreatments on dried chilli (Capsicum annum L.) quality

NASA Astrophysics Data System (ADS)

Anoraga, S. B.; Sabarisman, I.; Ainuri, M.

2018-03-01

Chilli (Capsicum annum L.) has significant price fluctuation. When the chilli price is declined, it causes food waste from unsold chilli. Therefore, drying chilli is a solution for this condition. Futhermore, it can be processed for various product like chilli powder, chilli sauce, etc. The aim of this study was to investigate the effect of different pretreatments on dried chilli quality. Chilli was blenched with hot water and steam before drying. The purpose of this pretreatments is to inactivate enzyme that prevents color and vitamin C losses. The quality parameters were moisture content, colour, vitamin C content, and capsaicin. Changes were observed by gravimetri method for moisture content, chromameter in L* a * b * colour model, and iodine titration for vitamin C. After drying for 20 hours at 60°C, chilli with steam blanching pretreatment dried rapidly than other samples. Unpretreated chilli had higher vitamin C content and better color than blanched chilli.

A surprising method for green extraction of essential oil from dry spices: Microwave dry-diffusion and gravity.

PubMed

Farhat, Asma; Fabiano-Tixier, Anne-Sylvie; Visinoni, Franco; Romdhane, Mehrez; Chemat, Farid

2010-11-19

Without adding any solvent or water, we proposed a novel and green approach for the extraction of secondary metabolites from dried plant materials. This "solvent, water and vapor free" approach based on a simple principle involves the application of microwave irradiation and earth gravity to extract the essential oil from dried caraway seeds. Microwave dry-diffusion and gravity (MDG) has been compared with a conventional technique, hydrodistillation (HD), for the extraction of essential oil from dried caraway seeds. Essential oils isolated by MDG were quantitatively (yield) and qualitatively (aromatic profile) similar to those obtained by HD, but MDG was better than HD in terms of rapidity (45min versus 300min), energy saving, and cleanliness. The present apparatus permits fast and efficient extraction, reduces waste, avoids water and solvent consumption, and allows substantial energy savings. Copyright © 2010 Elsevier B.V. All rights reserved.

Occurrence, distribution, and sources of emerging organic contaminants in tropical coastal sediments of anthropogenically impacted Klang River estuary, Malaysia.

PubMed

Omar, Tuan Fauzan Tuan; Aris, Ahmad Zaharin; Yusoff, Fatimah Md; Mustafa, Shuhaimi

2018-06-01

This baseline assessment reports on the occurrence, distribution, and sources of emerging organic contaminants (EOCs) in tropical coastal sediments of anthropogenically impacted Klang River estuary, Malaysia. Bisphenol A was the highest concentration detected at 16.84 ng g -1 dry weight, followed by diclofenac (13.88 ng g -1 dry weight) and E1 (12.47 ng g -1 dry weight). Five compounds, namely, amoxicillin, progesterone, diazinon, bisphenol A, and E1, were found in all sampling stations assessed, and other compounds such as primidone, diclofenac, testosterone, E2, and EE2 were ubiquitously present in sediment samples, with percentage of detection range from 89.04% to 98.38%. Organic carbon content and pH were the important factors controlling the fate of targeted compounds in the tropical estuarine sediment. On the basis of the literature from other studies, the sources of EOCs are thought to be from wastewater treatment plants, domestic/medical waste discharge, livestock activities, industrial waste discharge, and agricultural activities. Copyright © 2018 Elsevier Ltd. All rights reserved.

Solid metabolic waste transport and stowage investigation

NASA Technical Reports Server (NTRS)

Burt, R. A.; Koesterer, M. G.; Hunt, S. R., Jr.

1974-01-01

The basic Waste Collection System (WCS) design under consideration utilized air flow to separate the stool from the WCS user and to transport the fecal material to a slinger device for subsequent deposition on a storage bowel. The major parameters governing stool separation and transport were found to be the area of the air inlet orifices, the configuration of the air inlet orifice and the transport air flow. Separation force and transport velocity of the stool were studied. The developed inlet orifice configuration was found to be an effective design for providing fecal separation and transport. Simulated urine tests and female user tests in zero gravity established air flow rates between 0.08 and 0.25 cu sm/min (3 and 9 scfm) as satisfactory for entrapment, containment and transport of urine using an urinal. The investigation of air drying of fecal material as a substitute for vacuum drying in a WCS breadboard system showed that using baseline conditions anticipated for the shuttle cabin ambient atmosphere, flow rates of 0.14 cu sm/min (5 cfm) were adequate for drying and maintaining biological stability of the fecal material.

Chinese medicinal herbal residues as a bulking agent for food waste composting.

PubMed

Zhou, Ying; Selvam, Ammaiyappan; Wong, Jonathan W C

2018-02-01

This study aimed to co-compost Chinese medicinal herbal residues (CMHRs) as the bulking agent with food waste (FW) to develop a high value antipathogenic compost. The FW, sawdust (SD) and CMHRs were mixed at three different mixing ratios, 5:5:1, 2:2:1 and 1:1:1 on dry weight basis. Lime at 2.25% was added to the composting mix to buffer the pH during the composting. A control without lime addition was also included. The mixtures were composted in 20-L in-vessel composters for 56 days. A maximum of 67.2% organic decomposition was achieved with 1:1:1 mixing ratio within 8 weeks. The seed germination index was 157.2% in 1:1:1 mixing ratio, while other ratios showed <130.0% and the treatment without lime showed 40.3%. Therefore use of CMHRs as the bulking agent to compost food waste at the dry weight ratio of 1:1:1 (FW: SD: CMHRs) was recommended for FW-CMHRs composting. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effect of textile waste water on tomato plant, Lycopersicon esculentum.

PubMed

Marwari, Richa; Khan, T I

2012-09-01

In this study Sanganer town, Jaipur was selected as study area. The plants of Lycopersicon esculentum var. K 21(Tomato) treated with 20 and 30% textile wastewater were analyzed for metal accumulation, growth and biochemical parameters at per, peak and post flowering stages. Findings of the study revealed that chlorophyll content was most severely affected with the increase in metal concentration. Total chlorophyll content showed a reduction of 72.44% while carbohydrate, protein and nitrogen content showed a reduction of 46.83, 71.65 and 71.65% respectively. With the increase in waste water treatment the root and shoot length, root and shoot dry weight and total dry weight were reduced to 50.55, 52.06, 69.93, 72.42, 72.10% respectively. After crop harvesting, the fruit samples of the plants treated with highest concentration of textile waste water contained 2.570 mg g(-1)d.wt. of Zn, 0.800 mg g(-1) d.wt. Cu, 1.520 mg g(-1) d.wt. Cr and 2.010 mg g(-1) d.wt. Pb.

Sediment Quality Characterization Naval Station San Diego

DTIC Science & Technology

1999-01-01

Bioassays using an am- phipod (Rhepoxynius abronius), larvae of the sea urchin (Strongylocentrotus purpuratus), and larval abalone (Haliotis sp.) indicated...sulfide (AVS) and simultaneously extracted metal ( SEM ) in bulk sedim ent (pm ole.g-dry1...Diego Gas & Electric SDIWQR San Diego Interagency Water Quality Control Board SEM Simultaneously Extracted Metals Si Silicon SI Site Investigation SOD

Polyhydroxyalkanoate (PHA) production from waste.

PubMed

Rhu, D H; Lee, W H; Kim, J Y; Choi, E

2003-01-01

PHA (polyhydroxyalkanoate) production was attempted with SBRs from food waste. Seed microbes were collected from a sewage treatment plant with a biological nutrient removal process, and acclimated with synthetic substrate prior to the application of the fermented food waste. Laboratory SBRs were used to produce PHA with limited oxygen and nutrients. The maximum content of 51% PHA was obtained with an anaerobic/aerobic cycle with P limitation, and the yield was estimated to be about 0.05 gPHA(produced)/gCOD(applied) or 25 kg PHA/dry ton of food waste, assuming more than 40% of the PHA contents were recoverable. PHB/PHA ratios were 0.74 to 0.77 due to the higher acetate concentrations. Economical analysis seemed to suggest the PHA produced from the food waste could be an alternative material to produce the biodegradable plastic to be used for the collection bags for solid waste.

Method for acid oxidation of radioactive, hazardous, and mixed organic waste materials

DOEpatents

Pierce, Robert A.; Smith, James R.; Ramsey, William G.; Cicero-Herman, Connie A.; Bickford, Dennis F.

1999-01-01

The present invention is directed to a process for reducing the volume of low level radioactive and mixed waste to enable the waste to be more economically stored in a suitable repository, and for placing the waste into a form suitable for permanent disposal. The invention involves a process for preparing radioactive, hazardous, or mixed waste for storage by contacting the waste starting material containing at least one organic carbon-containing compound and at least one radioactive or hazardous waste component with nitric acid and phosphoric acid simultaneously at a contacting temperature in the range of about 140.degree. C. to about 210 .degree. C. for a period of time sufficient to oxidize at least a portion of the organic carbon-containing compound to gaseous products, thereby producing a residual concentrated waste product containing substantially all of said radioactive or inorganic hazardous waste component; and immobilizing the residual concentrated waste product in a solid phosphate-based ceramic or glass form.

Grout formulation for disposal of low-level and hazardous waste streams containing fluoride

DOEpatents

McDaniel, E.W.; Sams, T.L.; Tallent, O.K.

1987-06-02

A composition and related process for disposal of hazardous waste streams containing fluoride in cement-based materials is disclosed. the presence of fluoride in cement-based materials is disclosed. The presence of fluoride in waste materials acts as a set retarder and as a result, prevents cement-based grouts from setting. This problem is overcome by the present invention wherein calcium hydroxide is incorporated into the dry-solid portion of the grout mix. The calcium hydroxide renders the fluoride insoluble, allowing the grout to set up and immobilize all hazardous constituents of concern. 4 tabs.

Assessment of sanitary landfill leachate characterizations and its impacts on groundwater at Alexandria.

PubMed

Hassan, Ahmed Hossam; Ramadan, Mohamed Hassan

2005-01-01

The total amount of solid waste generated in Alexandria is 2820 tons/d which increases to 3425 tons/day during summer. In the past, 77% of the collected solid wastes was open dumped. The open dumping sites did not have the minimum requirements for pollution control. Following the exacerbation of the problem, the Alexandria Governorate contracted a company to carry out the solid waste management. The contracted company transferred 75% of the daily generated solid wastes to a new constructed sanitary lanfill. The site receives a daily average of 1910 tons. The landfilling is performed by trench method in the form of cells. The produced leachate is discharged into two lined aerated lagoons. The biogas formed from biodegradation of landfilled solid wastes is burned and the produced heat is used for drying the lagoons leachate. The remaining residues are relandfilled. The study aims at assessment of the solid waste sanitary landfill leachate characterization and its impacts on the groundwater. The analysis of the collected data confirms that leachates from the landfill are severely contaminated with organics, salts, and heavy metals. The fluctuations in concentration levels of the different parameters were attributed to aging and thickness of waste layers, stage of decomposition, and re-landfilling of the concentrated residues from the drying lagoons. The concentrations of NH4-N (600 mg/l) indicated that the process of stabilization was still in the initial stages and attributed to the compaction process. The high BOD5 results (28,833 mg/l) indicated that the process of stabilization was in the initial stages which were very slow. The high COD results (45,240 mg/l) can be attributed to the compaction of the wastes which also retards the degradation of the solid wastes. The BOD and COD values indicated clearly severe contamination. The BOD5/COD ratio measured in the current study (0.64) indicated that the leachate of the present study was biodegradable and unstabilized, and required time and favourable conditions for anaerobic biodegradation. Heavy metals were lower compared with what have been observed in other countries. Re-landfilling of the residue after drying the leachate in lagoons and the short time of biodegradation in the landfill site were factors which effected the high strength of most of the parameters concentrations of the leachate. Assessment of groundwater contamination through piezometer wells around the active cells indicated that there was no contamination from the leachate to the groundwater surrounding the site. The study recommended emphasizing the importance of adjusting the biodegradation factors, the monitoring program, the prohibition of disposing heavy metals, determination of the leachate generation rate, and treatment of leachate.

Developmental and waste reduction plasticity of three black soldier fly strains (Diptera: Stratiomyidae) raised on different livestock manures.

PubMed

Zhou, Fen; Tomberlin, Jeffery K; Zheng, Longyu; Yu, Ziniu; Zhang, Jibin

2013-11-01

Black soldier flies, Hermetia illucens L., are distributed throughout the temperate and tropic regions of the world and are known an established method for sustainably managing animal wastes. Colonies used to conduct research on the black soldier fly within the past 20 yr have predominately been established from eggs or larvae received from a colony originated from Bacon County, GA. Consequently, little is known about the phenotypic plasticity (i.e., development and waste conversion) across strains from different regions. This study compared the development of three strains of the black soldier fly (Texas; Guangzhou, China; and Wuhan, China) and their ability to reduce dry matter and associated nutrients in swine, dairy, and chicken manure. The Wuhan strain appeared to be more fit. Larvae from Wuhan needed 17.7-29.9% less time to reach the prepupal stage than those from Guangzhou or Texas, respectively. Larvae from Wuhan weighed 14.4-37.0% more than those from Guanghzhou or Texas, respectively. Larvae from the Wuhan strain reduced dry matter 46.0% (swine), 40.1% (dairy), and 48.4% (chicken) more than the Guangzhou strain and 6.9, 7.2, and 7.9% more than the Texas strain. This study demonstrates that phenotypic plasticity (e.g., development and waste conversion) varies across populations of black soldier flies and should be taken into account when selecting and establishing a population as a waste management agent in a given region of the world.

Apparatus and method for investigation of energy consumption of microwave assisted drying systems.

PubMed

Göllei, Attila; Vass, András; Magyar, Attila; Pallai, Elisabeth

2009-10-01

Convective, hot air drying by itself is relatively efficient for removing water from the surface environment of agricultural seed products. However, moving internal moisture to the surface needs rather a long time, as a rule. The major research aim of the authors was to decrease the processing time and processing costs, to improve the quality of the dried product, and to increase drying efficiency. For this reason their research activities focused on the development of a special drying apparatus and a method suitable for measuring of energy conditions in a hybrid (microwave and convective) dryer. Experimental investigations were made with moistened wheat as model material. Experiments were carried out in microwave, convective and hybrid drying systems. The microwave drying alone was more efficient than the convective method. The lowest energy consumption and shortest drying time were obtained by the use of a hybrid method in which the waste energy of magnetron was utilized and the temperature was controlled. In this way, it was possible to keep the temperature of the dried product at a constant and safe value and to considerably decrease the energy consumption.

Simultaneous analysis of consumer variables, acceptability and sensory characteristics of dry-cured ham.

PubMed

Sugimoto, Masahiro; Obiya, Shinichi; Kaneko, Miku; Enomoto, Ayame; Honma, Mayu; Wakayama, Masataka; Tomita, Masaru

2016-11-01

We conducted a consumer acceptability analysis of dry-cured ham based on sensory evaluation. Consumer acceptability data are rendered heterogeneous by the diverse backgrounds and assessment abilities of the participants, requiring versatile analytical methods for their interpretation. Totally, 9 sensory attributes of 12 kinds of dry-cured ham samples collected from Japan (n=9), Italy (n=1), Spain (n=1), and Germany (n=1) were tasted by 117 Japanese consumers who showed acceptable evaluation abilities during blind sampling. Common techniques, such as hierarchical clustering, principal component analysis, and external preference mapping, were simultaneously utilized to analyze each characteristics scored in modified hedonic scale. These analyses revealed the relationships between the features and preferences of the assessors. For example, consumers aged 20-30 with smoking and drinking habits preferred sweetness and saltiness, and gave high ratings to Spanish Jómon serrano and Italian prosciutto. Our approach could assist ham marketers to identify potential purchasers and the preferred characteristics of their products. Copyright © 2016 Elsevier Ltd. All rights reserved.

The New Challenges of China's South to North Water Diversion Project

NASA Astrophysics Data System (ADS)

Liu, X.

2017-12-01

Water shortage has restricted the economic and social development of Beijing during recent years. The central route of China's South to North Water Diversion Project is planned to divert water from the Danjiangkou Reservoir to Beijing. Currently, the main local surface water source for Beijing is the Miyun Reservoir. We found that annual runoffs in both of the Danjiangkou Reservoir Basin and Miyun Reservoir Basin decreased significantly from 1956 to 2015. The decrease in runoff represents a decrease in available water resources. We classified each year between 1956 and 2015 as either a wet, normal or dry year based on the Pearson-III probability distribution of annual runoff. The probability of a simultaneous dry year in the two basins was about 8.8% during 1956 to 1989, while it increased to 33.7% during 1990 to 2015. The increase in probability of a simultaneous dry year could threaten the success of the water diversion project. We suggest that urgent adaptive measures are implemented in advance to face this challenge.

Ultrasonic recovery of copper and iron through the simultaneous utilization of Printed Circuit Boards (PCB) spent acid etching solution and PCB waste sludge.

PubMed

Huang, Zhiyuan; Xie, Fengchun; Ma, Yang

2011-01-15

A method was developed to recover the copper and iron from Printed Circuit Boards (PCB) manufacturing generated spent acid etching solution and waste sludge with ultrasonic energy at laboratory scale. It demonstrated that copper-containing PCB spent etching solution could be utilized as a leaching solution to leach copper from copper contained PCB waste sludge. It also indicated that lime could be used as an alkaline precipitating agent in this method to precipitate iron from the mixture of acidic PCB spent etching solution and waste sludge. This method provided an effective technique for the recovery of copper and iron through simultaneous use of PCB spent acid solution and waste sludge. The leaching rates of copper and iron enhanced with ultrasound energy were reached at 93.76% and 2.07% respectively and effectively separated copper from iron. Followed by applying lime to precipitate copper from the mixture of leachate and rinsing water produced by the copper and iron separation, about 99.99% and 1.29% of soluble copper and calcium were settled as the solids respectively. Furthermore the settled copper could be made as commercial rate copper. The process performance parameters studied were pH, ultrasonic power, and temperature. This method provided a simple and reliable technique to recover copper and iron from waste streams generated by PCB manufacturing, and would significantly reduce the cost of chemicals used in the recovery. Copyright © 2010 Elsevier B.V. All rights reserved.

Source separation of household waste: a case study in China.

PubMed

Zhuang, Ying; Wu, Song-Wei; Wang, Yun-Long; Wu, Wei-Xiang; Chen, Ying-Xu

2008-01-01

A pilot program concerning source separation of household waste was launched in Hangzhou, capital city of Zhejiang province, China. Detailed investigations on the composition and properties of household waste in the experimental communities revealed that high water content and high percentage of food waste are the main limiting factors in the recovery of recyclables, especially paper from household waste, and the main contributors to the high cost and low efficiency of waste disposal. On the basis of the investigation, a novel source separation method, according to which household waste was classified as food waste, dry waste and harmful waste, was proposed and performed in four selected communities. In addition, a corresponding household waste management system that involves all stakeholders, a recovery system and a mechanical dehydration system for food waste were constituted to promote source separation activity. Performances and the questionnaire survey results showed that the active support and investment of a real estate company and a community residential committee play important roles in enhancing public participation and awareness of the importance of waste source separation. In comparison with the conventional mixed collection and transportation system of household waste, the established source separation and management system is cost-effective. It could be extended to the entire city and used by other cities in China as a source of reference.

Impact of Acid Mine Drainage on the hydrogeological system at Sia, Cyprus

NASA Astrophysics Data System (ADS)

Ng, Stephen; Malpas, John

2013-04-01

Discontinued mining of the volcanogenic massive sulphide ore bodies of Cyprus has left significant environmental concerns including Acid Mine Drainage. Remnant sulphide ore and tailings in waste dumps react with oxygenated rainwater to produce sulphuric acid, a process which is multiplied when metal-loving acidophilic bacteria are present. Given that Cyprus has a Mediterranean climate, characterized by its warm and dry summers and cool and wet winters, the low pH effluent with high levels of trace elements, particularly metals, is leached out of the waste tips particularly during the wet season. The Sia site includes an open mine-pit lake, waste rock and tailings dumps, a river leading to a downstream dam-lake, and a localised groundwater system. The study intends to: identify the point source and nature of contamination; analyze the mechanism and results of local acid generation; and understand how the hydrogeological system responds to seasonal variations. During two sampling campaigns, in the wet and dry seasons of 2011, water samples were collected from the mine pit lake, from upstream of the adjacent river down to the dam catchment, and from various boreholes close to the sulphide mine. The concentration of ions in waters varies between wet and dry seasons but, in both, relative amounts are directly related to pH. In the mine-pit lake, Fe, Mn, Mg, Cu, Pb, Zn, Ni, Co and Cd are found in higher concentrations in the dry season, as a result of substantial evaporation of water. The Sia River runs continuously in the wet season, and waters collected close to the waste tips have pH as low as 2.5 and higher concentrations of Al, Cu, Fe and Zn. Further downstream there is a significant decrease in trace metal contents with a concomitant rise of pH. Al and Fe dominate total cation content when pH is lower than 4. Al is derived from the weathering of clay minerals, especially during the wet season. Fe is derived from the oxidation of pyrite. Once pH's exceed 4, a white precipitate of gibbsite (Al(OH)3) settles to the stream bed removing Al from the water. This is finely laminated together with orange-brown layers of similarly precipitated Fe(OH)3. During the dry season the Sia River dries up and the mine-pit lake is greatly reduced in surface area leading to the crystallisation of a variety of multi-coloured salts, which form on the muddy substrate through capillary action. These include large amounts of gypsum and hexahydrite, and lesser amounts of chalcanthite, jarosite, wupatkiite, halotrichite, malachite, etc. These are ephemeral in nature being quickly dissolved by early rains of the wet season that, in the stream waters, produces short-lived toxic concentrations of metals. Groundwaters sampled directly at the mine site show the influence of drainage from the waste tips. Elsewhere, apart from sporadic high Boron concentrations, there is no evidence of contamination from the mine workings. The origin of Boron is a problem that arises at a number of sites throughout Cyprus, especially on the Mesaoria Plain and in the Troodos Complex.

Rational preparation of waste coal mixture for production of bricks by the method of compression molding

NASA Astrophysics Data System (ADS)

Stolboushkin, A. Yu; Ivanov, A. I.; Temlyantsev, M. V.; Fomina, O. A.

2016-10-01

Rational preparation of the mixture containing technogenic raw material - waste coal for the production of wall ceramics is developed. It was established that the technology of high-quality ceramic bricks requires: grinding of raw materials to class 0.3 + 0 mm, its aggregation in the intensive mixers into granules 1-3 mm, compression molding of adobe to plastic deformation of granules, drying and firing.

Determination of mechanical behavior of new biocomposites

NASA Astrophysics Data System (ADS)

Busuioceanu, Ioana Iuliana; Enǎchescu, Georgiana-Luminita; Baciu, Florin; Dinu, Gabriela; Ştefǎnescu, Mariana Florentina

2018-02-01

The paper includes the results of experimental research to find new biocomposite materials, consisting of a resin matrix reinforforced with natural fiber waste. The resin used was natural resin collected from coniferous forests in Romania and natural wastes were walnut shells, pine needles and green ash. Despite all the difficulties encountered, regarding the high viscosity of the obtained biocomposites, the sticky character, the high drying and strengthening times, some conclusions could be drawn.

Thermal properties of simulated Hanford waste glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodriguez, Carmen P.; Chun, Jaehun; Crum, Jarrod V.

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will vitrify the mixed hazardous wastes generated from 45 years of plutonium production. The molten glasses will be poured into stainless steel containers or canisters and subsequently quenched for storage and disposal. Such highly energy-consuming processes require precise thermal properties of materials for appropriate facility design and operations. Key thermal properties (heat capacity, thermal diffusivity, and thermal conductivity) of representative high-level and low-activity waste glasses were studied as functions of temperature in the range of 200 to 800°C (relevant to the cooling process), implementing simultaneous differential scanning calorimetry-thermal gravimetry (DSC-TGA), Xe-flashmore » diffusivity, pycnometry, and dilatometry. The study showed that simultaneous DSC-TGA would be a reliable method to obtain heat capacity of various glasses at the temperature of interest. Accurate thermal properties from this study were shown to provide a more realistic guideline for capacity and time constraint of heat removal process, in comparison to the design basis conservative engineering estimates. The estimates, though useful for design in the absence measured physical properties, can now be supplanted and the measured thermal properties can be used in design verification activities.« less

Ecotoxicological characterization of hazardous wastes.

PubMed

Wilke, B-M; Riepert, F; Koch, Christine; Kühne, T

2008-06-01

In Europe hazardous wastes are classified by 14 criteria including ecotoxicity (H 14). Standardized methods originally developed for chemical and soil testing were adapted for the ecotoxicological characterization of wastes including leachate and solid phase tests. A consensus on which tests should be recommended as mandatory is still missing. Up to now, only a guidance on how to proceed with the preparation of waste materials has been standardized by CEN as EN 14735. In this study, tests including higher plants, earthworms, collembolans, microorganisms, duckweed and luminescent bacteria were selected to characterize the ecotoxicological potential of a boiler slag, a dried sewage sludge, a thin sludge and a waste petrol. In general, the instructions given in EN 14735 were suitable for all wastes used. The evaluation of the different test systems by determining the LC/EC(50) or NOEC-values revealed that the collembolan reproduction and the duckweed frond numbers were the most sensitive endpoints. For a final classification and ranking of wastes the Toxicity Classification System (TCS) using EC/LC(50) values seems to be appropriate.

Electric energy production from food waste: Microbial fuel cells versus anaerobic digestion.

PubMed

Xin, Xiaodong; Ma, Yingqun; Liu, Yu

2018-05-01

A food waste resourceful process was developed by integrating the ultra-fast hydrolysis and microbial fuel cells (MFCs) for energy and resource recovery. Food waste was first ultra-fast hydrolyzed by fungal mash rich in hydrolytic enzymes in-situ produced from food waste. After which, the separated solids were readily converted to biofertilizer, while the liquid was fed to MFCs for direct electricity generation with a conversion efficiency of 0.245 kWh/kg food waste. It was estimated that about 192.5 million kWh of electricity could be produced from the food waste annually generated in Singapore, together with 74,390 tonnes of dry biofertilizer. Compared to anaerobic digestion, the proposed approach was more environmentally friendly and economically viable in terms of both electricity conversion and process cost. It is expected that this study may lead to the paradigm shift in food waste management towards ultra-fast concurrent recovery of resource and electricity with zero-solid discharge. Copyright © 2018 Elsevier Ltd. All rights reserved.

Industrial wastes as a promising renewable source for production of microbial lipid and direct transesterification of the lipid into biodiesel.

PubMed

Cheirsilp, Benjamas; Louhasakul, Yasmi

2013-08-01

Two strategies of converting industrial wastes to microbial lipid and direct transesterification of obtained lipid into biodiesel were attempted. Several oleaginous yeasts were cultivated on industrial wastes. The yeasts grew well on the wastes with low C/N ratio (i.e. serum latex) but accumulated high lipid content only when the wastes had a high C/N ratio (i.e. palm oil mill effluent and crude glycerol). The yeast lipids have similar fatty acid composition to that of plant oil indicating their potential use as biodiesel feedstocks. The combination of these wastes and two-phase cultivation for cell growth and lipid accumulation improved lipid productivity of the selected yeast. The direct transesterification process that eliminates cell drying and lipid extraction steps, gave comparable yield of biodiesel (fatty acid methyl ester >70% within 1h) to that of conventional method. These two successful strategies may contribute greatly to industrializing oil production from microbes and industrial wastes. Copyright © 2013 Elsevier Ltd. All rights reserved.

Potential application of biodrying to treat solid waste

NASA Astrophysics Data System (ADS)

Zaman, Badrus; Oktiawan, Wiharyanto; Hadiwidodo, Mochtar; Sutrisno, Endro; Purwono; Wardana, Irawan Wisnu

2018-02-01

The generation of solid waste around the world creates problems if not properly managed. The method of processing solid waste by burning or landfill is currently not optimal. The availability of land where the final processing (TPA) is critical, looking for a new TPA alternative will be difficult and expensive, especially in big cities. The processing of solid waste using bio drying technology has the potential to produce renewable energy and prevention of climate change. Solid waste processing products can serve as Refuse Derived Fuel (RDF), reduce water content of solid waste, meningkatkan kualitas lindi and increase the amount of recycled solid waste that is not completely separated from home. Biodrying technology is capable of enhancing the partial disintegration and hydrolysis of macromolecule organic compounds (such as C-Organic, cellulose, hemicellulose, lignin, total nitrogen). The application of biodrying has the potential to reduce greenhouse gas emissions such as carbon dioxide (CO2), methane (CH4), and dinitrooksida (N2O). These gases cause global warming.

Advanced degradation of brominated epoxy resin and simultaneous transformation of glass fiber from waste printed circuit boards by improved supercritical water oxidation processes.

PubMed

Liu, Kang; Zhang, Zhiyuan; Zhang, Fu-Shen

2016-10-01

This work investigated various supercritical water oxidation (SCWO) systems, i.e. SCWO1 (only water), SCWO2 (water+H2O2) and SCWO3 (water+H2O2/NaOH), for waste printed circuit boards (PCBs) detoxification and recycling. Response surface methodology (RSM) was applied to optimize the operating conditions of the optimal SCWO3 systems. The optimal reaction conditions for debromination were found to be the NaOH of 0.21g, the H2O2 volume of 9.04mL, the time of 39.7min, maximum debromination efficiency of 95.14%. Variance analysis indicated that the factors influencing debromination efficiency was in the sequence of NaOH>H2O2>time. Mechanism studies indicated that the dissociated ions from NaOH in supercritical water promoted the debromination of brominated epoxy resins (BERs) through an elimination reaction and nucleophilic substitution. HO2, produced by H2O2 could induce the oxidation of phenol ring to open (intermediates of BERs), which were thoroughly degraded to form hydrocarbons, CO2, H2O and NaBr. In addition, the alkali-silica reaction between OH(-) and SiO2 induced the phase transformation of glass fibers, which were simultaneously converted into anorthite and albite. Waste PCBs in H2O2/NaOH improved SCWO system were fully degraded into useful products and simultaneously transformed into functional materials. These findings are helpful for efficient recycling of waste PCBs. Copyright © 2016 Elsevier Ltd. All rights reserved.

Simultaneous hydrolysis and fermentation of unprocessed food waste into ethanol using thermophilic anaerobic bacteria.

PubMed

Dhiman, Saurabh Sudha; David, Aditi; Shrestha, Namita; Johnson, Glenn R; Benjamin, Kenneth M; Gadhamshetty, Venkataramana; Sani, Rajesh K

2017-11-01

The one-pot CRUDE (Conversion of Raw and Untreated Disposal into Ethanol) process was developed for simultaneous hydrolysis and fermentation of unprocessed food waste into ethanol using thermophilic (growing at 65°C) anaerobic bacteria. Unlike existing waste to energy technologies, the CRUDE process obviates the need for any pre-treatment or enzyme addition. A High-Temperature-High-Pressure (HTHP) distillation technique was also applied that facilitated efficient use of fermentation medium, inoculum recycling, and in-situ ethanol collection. For material balancing of the process, each characterized component was represented in terms of C-mol. Recovery of 94% carbon at the end confirmed the operational efficiency of CRUDE process. The overall energy retaining efficiency calculated from sugars to ethanol was 1262.7kJdryweightkg -1 of volatile solids using HTHP. These results suggest that the CRUDE process can be a starting point for the development of a commercial ethanol production process. Copyright © 2017 Elsevier Ltd. All rights reserved.

Food waste as nutrient source in heterotrophic microalgae cultivation.

PubMed

Pleissner, Daniel; Lam, Wan Chi; Sun, Zheng; Lin, Carol Sze Ki

2013-06-01

Glucose, free amino nitrogen (FAN), and phosphate were recovered from food waste by fungal hydrolysis using Aspergillus awamori and Aspergillus oryzae. Using 100g food waste (dry weight), 31.9 g glucose, 0.28 g FAN, and 0.38 g phosphate were recovered after 24h of hydrolysis. The pure hydrolysate has then been used as culture medium and nutrient source for the two heterotrophic microalgae Schizochytrium mangrovei and Chlorella pyrenoidosa, S. mangrovei and C. pyrenoidosa grew well on the complex food waste hydrolysate by utilizing the nutrients recovered. At the end of fermentation 10-20 g biomass were produced rich in carbohydrates, lipids, proteins, and saturated and polyunsaturated fatty acids. Results of this study revealed the potential of food waste hydrolysate as culture medium and nutrient source in microalgae cultivation. Copyright © 2013 Elsevier Ltd. All rights reserved.

Use of overburden rocks from open-pit coal mines and waste coals of Western Siberia for ceramic brick production with a defect-free structure

NASA Astrophysics Data System (ADS)

Stolboushkin, A. Yu; Ivanov, A. I.; Storozhenko, G. I.; Syromyasov, V. A.; Akst, D. V.

2017-09-01

The rational technology for the production of ceramic bricks with a defect-free structure from coal mining and processing wastes was developed. The results of comparison of physical and mechanical properties and the structure of ceramic bricks manufactured from overburden rocks and waste coal with traditional for semi-dry pressing mass preparation and according to the developed method are given. It was established that a homogeneous, defect-free brick texture obtained from overburden rocks of open-pit mines and waste coal improves the quality of ceramic wall materials produced by the method of compression molding by more than 1.5 times compared to the brick with a traditional mass preparation.

Good Housekeeping Implementation for Improving Efficiency in Cassava Starch Industry (Case Study : Margoyoso District, Pati Regency)

NASA Astrophysics Data System (ADS)

Aji, Wijayanto Setyo; Purwanto; Suherman, S.

2018-02-01

Cassava starch industry is one of the leading small-medium enterprises (SMEs) in Pati Regency. Cassava starch industry released waste that reduces the quantity of final product and potentially contamined the environment. This study was conducted to observe the feasibility of good housekeeping implementation to reduce waste and at the same time improve efficiency of production process. Good housekeeping opportunities are consideration by three aspect, technical, economy and environmental. Good housekeeping opportunities involved water conservation and waste reduction. These included reuse of water in washing process, improving workers awareness in drying section and packaging section. Implementation of these opportunities can reduce water consumption, reduce wastewater and solid waste generation also increased quantity of final product.

Recent advances in yeast cell-surface display technologies for waste biorefineries.

PubMed

Liu, Zhuo; Ho, Shih-Hsin; Hasunuma, Tomohisa; Chang, Jo-Shu; Ren, Nan-Qi; Kondo, Akihiko

2016-09-01

Waste biorefinery aims to maximize the output of value-added products from various artificial/agricultural wastes by using integrated bioprocesses. To make waste biorefinery economically feasible, it is thus necessary to develop a low-cost, environment-friendly technique to perform simultaneous biodegradation and bioconversion of waste materials. Cell-surface display engineering is a novel, cost-effective technique that can auto-immobilize proteins on the cell exterior of microorganisms, and has been applied for use with waste biofinery. Through tethering different enzymes (e.g., cellulase, lipase, and protease) or metal-binding peptides on cell surfaces, various yeast strains can effectively produce biofuels and biochemicals from sugar/protein-rich waste materials, catalyze waste oils into biodiesels, or retrieve heavy metals from wastewater. This review critically summarizes recent applications of yeast cell-surface display on various types of waste biorefineries, highlighting its potential and future challenges with regard to commercializing this technology. Copyright © 2016 Elsevier Ltd. All rights reserved.

Simultaneous column chromatographic extraction and purification of abscisic acid in peanut plants for direct HPLC analysis.

PubMed

Zhang, Ya-Wen; Fan, Wei-Wei; Li, Hui; Ni, He; Han, Han-Bing; Li, Hai-Hang

2015-10-01

Abscisic acid (ABA), a universal signaling molecule, plays important roles in regulating plant growth, development and stress responses. The low contents and complex components in plants make it difficult to be accurately analyzed. A novel one-step sample preparation method for ABA in plants was developed. Fresh peanut (Arachis hypogaea) plant materials were fixed by oven-drying, microwave drying, boiling or Carnoy's fixative, and loaded onto a mini-preparing column. After washed the impurities, ABA was eluted with a small amount of solvent. ABA in plant materials was completely extracted and purified in 2mL solution and directly analyzed by HPLC, with a 99.3% recovery rate. Multiple samples can be simultaneously prepared. Analyses using this method indicated that the endogenous ABA in oven-dried peanut leaves increased 20.2-fold from 1.01 to 20.37μgg(-1) dry weight within 12h and then decreased in 30% polyethylene glycol 6000 treated plants, and increased 3.34-fold from 0.85 to 2.84μgg(-1) dry weight in 5 days and then decreased in soil drought treated plants. The method combined the column chromatographic extraction and solid-phase separation technologies in one step and can completely extracted plant endogenous ABA in a purified and highly concentrated form for direct HPLC analysis. Copyright © 2015 Elsevier B.V. All rights reserved.

Equipment evaluation for low density polyethylene encapsulated nitrate salt waste at the Rocky Flats Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yamada, W.I.; Faucette, A.M.; Jantzen, R.C.

1993-08-30

Mixed wastes at the Rocky Flats Plant (RFP) are subject to regulation by the Resource Conservation and Recovery Act (RCRA). Polymer solidification is being developed as a final treatment technology for several of these mixed wastes, including nitrate salts. Encapsulation nitrate salts with low density polyethylene (LDPE) has been the preliminary focus of the RFP polymer solidification effort. Literature reviews, industry surveys, and lab-scale and pilot-scale tests have been conducted to evaluate several options for encapsulating nitrate salts with LDPE. Most of the effort has focused on identifying compatible drying and extrusion technologies. Other processing options, specifically meltration and non-heatedmore » compounding machines, were also investigated. The best approach appears to be pretreatment of the nitrate salt waste brine in either a vertical or horizontal thin film evaporator followed by compounding of the dried waste with LDPE in an intermeshing, co-rotating, twin-screw extruder. Additional pilot-scale tests planned for the fall of 1993 should further support this recommendation. Preliminary evaluation work indicates that meltration is not possible at atmospheric pressure with the LDPE (Chevron PE-1409) provided by RFP. However, meltration should be possible at atmospheric pressure using another LDPE formulation with altered physical and rheological properties: Lower molecular weight and lower viscosity (Epoline C-15). Contract modifications are now in process to allow a follow-on pilot scale demonstration. Questions regarding changed safety and physical properties of the resultant LDPE waste form due to use of the Epoline C-15 will be addressed. No additional work with non-heated mixer compounder machines is planned at this time.« less

Elemental and thermo-chemical analysis of oil palm fronds for biomass energy conversion

NASA Astrophysics Data System (ADS)

Guangul, Fiseha Mekonnen; Sulaiman, Shaharin Anwar; Raghavan, Vijay R.

2012-06-01

Oil palm frond is the most abundant yet untapped biomass waste in Malaysia. This paper investigates the characteristics of raw oil palm fronds and its ash to evaluate its potential utilization as a biomass fuel for gasification process using single throat downdraft gasifier. The morphological nature, elemental content, proximate and ultimate analysis and calorific value were studied. Field emission scanning electron microscopy and x-ray fluorescence were used to investigate the surface morphology, elemental and mineralogical nature of oil palm frond and its ash. The results were compared with other agricultural and forestry biomass wastes. From proximate analysis volatile matter, fixed carbon and ash were found to be 83.5%, 15.2% and 1.3%, respectively on dry basis. From ultimate analysis result values of 44.58%, 4.53%, 0.71% and 0.07% for carbon, hydrogen, nitrogen and sulfur were found respectively on dry basis. Oxygen was determined by difference and found to be 48.81%. The proximate and ultimate analysis results indicate that oil palm frond is better than agricultural wastes and less than most forestry wastes to use as a feedstock in the gasification process in order to get a better quality of syngas. The amount of ash content in OPF was found to be much less than in agricultural wastes and higher than most forestry wastes. From x-ray fluorescence analysis CaO and K2O were found as the major oxides in oil palm fronds and rice husk ash with the amount of 28.46% and 15.71% respectively. The overall results of oil palm fronds were found to be satisfactory to use as a feedstock for the process of gasification.

Use of a CO{sub 2} pellet non-destructive cleaning system to decontaminate radiological waste and equipment in shielded hot cells at the Bettis Atomic Power Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bench, T.R.

1997-05-01

This paper details how the Bettis Atomic Power Laboratory modified and utilized a commercially available, solid carbon dioxide (CO{sub 2}) pellet, non-destructive cleaning system to support the disposition and disposal of radioactive waste from shielded hot cells. Some waste materials and equipment accumulated in the shielded hot cells cannot be disposed directly because they are contaminated with transuranic materials (elements with atomic numbers greater than that of uranium) above waste disposal site regulatory limits. A commercially available CO{sub 2} pellet non-destructive cleaning system was extensively modified for remote operation inside a shielded hot cell to remove the transuranic contaminants frommore » the waste and equipment without generating any secondary waste in the process. The removed transuranic contaminants are simultaneously captured, consolidated, and retained for later disposal at a transuranic waste facility.« less

The effects of unit pricing system upon household solid waste management: The Korean experience

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hong, S.

1999-09-01

Initial effects of adoption of a unit pricing system paired with aggressive recycling programs appear to be substantial. This paper explores the impact of price incentives under the unit pricing system on household solid waste generation and recycling in Korea. The author employs a simultaneous equation model considering the feedback effects between total waste generation and recycling. Estimation results using 3017 Korean household survey data indicate that a rise in waste collection fee induces households to recycle more wastes. However, this effect is partially offset by decreases in source-reduction efforts due to the feedback effects, resulting in relatively lower pricemore » elasticity of demand for solid waste collection services. This implies that household demand for solid waste collection services will not decrease much with additional increases in the collection fee, unless further recycling incentives such as more frequent recyclable pickup services are accompanied.« less

Property-close source separation of hazardous waste and waste electrical and electronic equipment--a Swedish case study.

PubMed

Bernstad, Anna; la Cour Jansen, Jes; Aspegren, Henrik

2011-03-01

Through an agreement with EEE producers, Swedish municipalities are responsible for collection of hazardous waste and waste electrical and electronic equipment (WEEE). In most Swedish municipalities, collection of these waste fractions is concentrated to waste recycling centres where households can source-separate and deposit hazardous waste and WEEE free of charge. However, the centres are often located on the outskirts of city centres and cars are needed in order to use the facilities in most cases. A full-scale experiment was performed in a residential area in southern Sweden to evaluate effects of a system for property-close source separation of hazardous waste and WEEE. After the system was introduced, results show a clear reduction in the amount of hazardous waste and WEEE disposed of incorrectly amongst residual waste or dry recyclables. The systems resulted in a source separation ratio of 70 wt% for hazardous waste and 76 wt% in the case of WEEE. Results show that households in the study area were willing to increase source separation of hazardous waste and WEEE when accessibility was improved and that this and similar collection systems can play an important role in building up increasingly sustainable solid waste management systems. Copyright © 2010 Elsevier Ltd. All rights reserved.

Statistical optimization of process parameters for the simultaneous adsorption of Cr(VI) and phenol onto Fe-treated tea waste biomass

NASA Astrophysics Data System (ADS)

Gupta, Ankur; Balomajumder, Chandrajit

2017-12-01

In this study, simultaneous removal of Cr(VI) and phenol from binary solution was carried out using Fe-treated tea waste biomass. The effect of process parameters such as adsorbent dose, pH, initial concentration of Cr(VI) (mg/L), and initial concentration of phenol (mg/L) was optimized. The analysis of variance of the quadratic model demonstrates that the experimental results are in good agreement with the predicted values. Based on experimental design at an initial concentration of 55 mg/L of Cr(VI), 27.50 mg/L of phenol, pH 2.0, 15 g/L adsorbent dose, 99.99% removal of Cr(VI), and phenol was achieved.

Energy Production and Transmutation of Nuclear Waste by Accelerator Driven Systems

NASA Astrophysics Data System (ADS)

Zhivkov, P. K.

2018-05-01

There is a significant amount of highly radiotoxic long-life nuclear waste (NW) produced by NPP (Nuclear Power Plants). Transmutation is a process which transforms NW into less radiotoxic nuclides with a shorter period of half-life by spallation neutrons or radiative capture of neutrons produced by ADS (Accelerator Driven System). In the processes of transmutation new radioactive nuclides are produced. ADS is big energy consumer equipment. It is a method for production of a high-flux and high-energy neutron field. All these processes occur in ADS simultaneously. ADS is able to transmute actinides and produce energy simultaneously. The article considers the energy production problems in ADS. Several ideas are developed regarding the solution of the global energy supply.

Simultaneous enhancement of methane production and methane content in biogas from waste activated sludge and perennial ryegrass anaerobic co-digestion: The effects of pH and C/N ratio.

PubMed

Dai, Xiaohu; Li, Xiaoshuai; Zhang, Dong; Chen, Yinguang; Dai, Lingling

2016-09-01

It is necessary to find an appropriate strategy to simultaneously enhance the methane production and methane content in biogas from waste activated sludge (WAS) and grass co-digestion. In this study an efficient strategy, i.e., adjusting the initial pH 12 and C/N ratio 17/1, for simultaneous enhancement of methane production and methane content in biogas from WAS and perennial ryegrass co-digestion was reported. Experimental results indicated that the maximal methane production was 310mL/gVSadd at the optimum conditions after 30-d anaerobic digestion, which was, respectively, about 1.5- and 3.8-fold of the sole WAS and sole perennial ryegrass anaerobic digestion. Meanwhile, the methane content in biogas was about 74%, which was much higher than that of sole WAS (64%) or sole perennial ryegrass (54%) anaerobic digestion. Copyright © 2016 Elsevier Ltd. All rights reserved.

10 CFR 850.30 - Housekeeping.

Code of Federal Regulations, 2010 CFR

2010-01-01

... beryllium dusts and waste must not exceed a removable contamination level of 3 µg/100 cm2 during non..., that avoid the production of airborne dust. Compressed air or dry methods must not be used for such...

Economical and environmentally-friendly approaches for usage of onion (Allium cepa L.) waste.

PubMed

Sharma, Kavita; Mahato, Neelima; Nile, Shivraj Hariram; Lee, Eul Tal; Lee, Yong Rok

2016-08-10

Onion (Allium cepa L.) is one of the most commonly cultivated crops across the globe, and its production is increasing every year due to increasing consumer demand. Simultaneously, huge amounts of waste are produced from different parts of the onion, which ultimately affect the environment in various ways. Hence, proper usage as well as disposal of this waste is important from the environmental aspect. This review summarizes various usage methods of onion waste material, and processes involved to achieve maximum benefits. Processing industries produce the largest amount of onion waste. Other sources are storage systems, domestic usage and cultivation fields. Particular emphasis has been given to the methods used for better extraction and usage of onion waste under specific topics: viz. organic synthesis, production of biogas, absorbent for pollutants and value added products.

Effect of different drying methods on moisture ratio and rehydration of pumpkin slices.

PubMed

Seremet Ceclu, Liliana; Botez, Elisabeta; Nistor, Oana-Viorela; Andronoiu, Doina Georgeta; Mocanu, Gabriel-Danut

2016-03-15

This study was carried to determine the influence of hot air drying process and combined methods on physicochemical properties of pumpkin (Cucurbita moschata) samples. The experiments in hot air chamber were lead at 50, 60 and 70 °C. The combined method consists of a triple combination of the main drying techniques. Thus, in first stage the samples were dried in hot air convection at 60 °C followed by hot air ventilation at 40 °C simultaneous with microwave. The time required to reduce the moisture content to any given level was highly dependent on the drying conditions. So, the highest value of drying time in hot air has been 540 min at 50 °C, while the lowest time has been 189 min in hot air combined by microwave at 40 °C and a power of 315 W. The samples dried by hot air shows a higher rehydration capacity than samples dried by combined method. Copyright © 2015 Elsevier Ltd. All rights reserved.

Drying of Pigment-Cellulose Nanofibril Substrates

PubMed Central

Timofeev, Oleg; Torvinen, Katariina; Sievänen, Jenni; Kaljunen, Timo; Kouko, Jarmo; Ketoja, Jukka A.

2014-01-01

A new substrate containing cellulose nanofibrils and inorganic pigment particles has been developed for printed electronics applications. The studied composite structure contains 80% fillers and is mechanically stable and flexible. Before drying, the solids content can be as low as 20% due to the high water binding capacity of the cellulose nanofibrils. We have studied several drying methods and their effects on the substrate properties. The aim is to achieve a tight, smooth surface keeping the drying efficiency simultaneously at a high level. The methods studied include: (1) drying on a hot metal surface; (2) air impingement drying; and (3) hot pressing. Somewhat surprisingly, drying rates measured for the pigment-cellulose nanofibril substrates were quite similar to those for the reference board sheets. Very high dewatering rates were observed for the hot pressing at high moisture contents. The drying method had significant effects on the final substrate properties, especially on short-range surface smoothness. The best smoothness was obtained with a combination of impingement and contact drying. The mechanical properties of the sheets were also affected by the drying method and associated temperature. PMID:28788220

Experimental Investigation and Aspen Plus Simulation of the MSW Pyrolysis Process

NASA Astrophysics Data System (ADS)

Ansah, Emmanuel

Municipal solid waste (MSW) is a potential feedstock for producing transportation fuels because it is readily available using an existing collection/transportation infrastructure and fees are provided by the suppliers or government agencies to treat MSW. North Carolina with a population of 9.4 millions generates 3.629 million metric tons of MSW each year, which contains about 113,396,356 TJs of energy. The average moisture content of MSW samples is 44.3% on a wet basis. About 77% of the dry MSW mass is combustible components including paper, organics, textile and plastics. The average heating values of MSW were 9.7, 17.5, and 22.7 MJ/kg on a wet basis, dry basis and dry combustible basis, respectively. The MSW generated in North Carolina can produce 7.619 million barrels of crude bio-oil or around 4% of total petroleum consumption in North Carolina. MSW can be thermally pyrolyzed into bio-oil in the absence of oxygen or air at a temperature of 500°C or above. As bio-oil can be easily stored and transported, compared to bulky MSW, landfill gas and electricity, pyrolysis offers significant logistical and economic advantages over landfilling and other thermal conversion processes such as combustion and gasification. Crude bio-oils produced from the pyrolysis of MSW can be further refined to transportation fuels in existing petroleum refinery facilities. The objective of this research is to analyze the technical and economic feasibility of pyrolyzing MSW into liquid transportation fuels. A combined thermogravimetric analyzer (TGA) and differential scanning calorimeter (DSC) instrument, which can serve as a micro-scale pyrolysis reactor, was used to simultaneously determine the degradation characteristics of MSW during pyrolysis. An ASPEN Plus-based mathematical model was further developed to analyze the technical and economic feasibility of pyrolysing of MSW into liquid transportation fuels in fixed bed reactors at varying operating conditions

Technical Requirements for On-Site Thermal Desorption of Solid Media Contaminated with Hazardous Chlorinated Organics

DTIC Science & Technology

1997-09-18

scrubbers , detectable dioxin/furans may occur, since dioxin/furans are much more soluble in organics than in water. Carbon adsorption is frequently...air pollution control device is required. Acid gases may be controlled by using a wet or dry scrubber or by using a coated baghouse. Operating...unit: 1. exit treated waste temperature; 2. baghouse pressure drop, venturi pressure drop, or drop in liquid/gas ratio; 3. waste feed rate; 4

Effect of Increasing Total Solids Contents on Anaerobic Digestion of Food Waste under Mesophilic Conditions: Performance and Microbial Characteristics Analysis

PubMed Central

Jin, Jingwei; Dai, Xiaohu

2014-01-01

The total solids content of feedstocks affects the performances of anaerobic digestion and the change of total solids content will lead the change of microbial morphology in systems. In order to increase the efficiency of anaerobic digestion, it is necessary to understand the role of the total solids content on the behavior of the microbial communities involved in anaerobic digestion of organic matter from wet to dry technology. The performances of mesophilic anaerobic digestion of food waste with different total solids contents from 5% to 20% were compared and the microbial communities in reactors were investigated using 454 pyrosequencing technology. Three stable anaerobic digestion processes were achieved for food waste biodegradation and methane generation. Better performances mainly including volatile solids reduction and methane yield were obtained in the reactors with higher total solids content. Pyrosequencing results revealed significant shifts in bacterial community with increasing total solids contents. The proportion of phylum Chloroflexi decreased obviously with increasing total solids contents while other functional bacteria showed increasing trend. Methanosarcina absolutely dominated in archaeal communities in three reactors and the relative abundance of this group showed increasing trend with increasing total solids contents. These results revealed the effects of the total solids content on the performance parameters and the behavior of the microbial communities involved in the anaerobic digestion of food waste from wet to dry technologies. PMID:25051352

Sustainable Sources of Biomass for Bioremediation of Heavy Metals in Waste Water Derived from Coal-Fired Power Generation

PubMed Central

Saunders, Richard J.; Paul, Nicholas A.; Hu, Yi; de Nys, Rocky

2012-01-01

Biosorption of heavy metals using dried algal biomass has been extensively described but rarely implemented. We contend this is because available algal biomass is a valuable product with a ready market. Therefore, we considered an alternative and practical approach to algal bioremediation in which algae were cultured directly in the waste water stream. We cultured three species of algae with and without nutrient addition in water that was contaminated with heavy metals from an Ash Dam associated with coal-fired power generation and tested metal uptake and bioremediation potential. All species achieved high concentrations of heavy metals (to 8% dry mass). Two key elements, V and As, reached concentrations in the biomass of 1543 mg.kg−1 DW and 137 mg.kg−1 DW. Growth rates were reduced by more than half in neat Ash Dam water than when nutrients were supplied in excess. Growth rate and bioconcentration were positively correlated for most elements, but some elements (e.g. Cd, Zn) were concentrated more when growth rates were lower, indicating the potential to tailor bioremediation depending on the pollutant. The cosmopolitan nature of the macroalgae studied, and their ability to grow and concentrate a suite of heavy metals from industrial wastes, highlights a clear benefit in the practical application of waste water bioremediation. PMID:22590550

Effect of increasing total solids contents on anaerobic digestion of food waste under mesophilic conditions: performance and microbial characteristics analysis.

PubMed

Yi, Jing; Dong, Bin; Jin, Jingwei; Dai, Xiaohu

2014-01-01

The total solids content of feedstocks affects the performances of anaerobic digestion and the change of total solids content will lead the change of microbial morphology in systems. In order to increase the efficiency of anaerobic digestion, it is necessary to understand the role of the total solids content on the behavior of the microbial communities involved in anaerobic digestion of organic matter from wet to dry technology. The performances of mesophilic anaerobic digestion of food waste with different total solids contents from 5% to 20% were compared and the microbial communities in reactors were investigated using 454 pyrosequencing technology. Three stable anaerobic digestion processes were achieved for food waste biodegradation and methane generation. Better performances mainly including volatile solids reduction and methane yield were obtained in the reactors with higher total solids content. Pyrosequencing results revealed significant shifts in bacterial community with increasing total solids contents. The proportion of phylum Chloroflexi decreased obviously with increasing total solids contents while other functional bacteria showed increasing trend. Methanosarcina absolutely dominated in archaeal communities in three reactors and the relative abundance of this group showed increasing trend with increasing total solids contents. These results revealed the effects of the total solids content on the performance parameters and the behavior of the microbial communities involved in the anaerobic digestion of food waste from wet to dry technologies.

Pineapple peel wastes as a potential source of antioxidant compounds

NASA Astrophysics Data System (ADS)

Saraswaty, V.; Risdian, C.; Primadona, I.; Andriyani, R.; Andayani, D. G. S.; Mozef, T.

2017-03-01

Indonesia is a large pineapple (Ananas comosus) producing country. Food industries in Indonesia processed this fruit for new products and further resulted wastes of which cause an environmental problems. Approximately, one pineapple fruit total weight is 400 gr of which 60 g is of peel wastes. In order to reduce such pineapple peel wastes (PPW), processing to a valuable product using an environmentally friendly technique is indispensable. PPW contained phenolic compound, ferulic acid, and vitamin A and C as antioxidant. This study aimed to PPW using ethanol and water as well as to analyze its chemical properties. Both dried and fresh PPW were extracted using mixtures of ethanol and water with various concentrations ranging from 15 to 95% (v/v) at room temperature for 24 h. The chemical properties, such as antioxidant activity, total phenolic content (Gallic acid equivalent/GAE), and total sugar content were determined. The results showed that the range of Inhibition Concentration (IC)50 value as antioxidant activity of extracts from dried and fresh PPW were in the range of 0.8±0.05 to 1.3±0.09 mg.mL-1 and 0.25±0.01 to 0.59±0.01 mg.mL-1, respectively, with the highest antioxidant activity was in water extract. The highest of total phenolic content of 0.9 mg.g-1 GAE, was also found in water extract.

Development of an extraction and purification method for the determination of multi-class pharmaceuticals and endocrine disruptors in freshwater invertebrates.

PubMed

Huerta, B; Jakimska, A; Llorca, M; Ruhí, A; Margoutidis, G; Acuña, V; Sabater, S; Rodriguez-Mozaz, S; Barcelò, D

2015-01-01

Aquatic organisms from freshwater ecosystems impacted by waste water treatment plant (WWTP) effluents are constantly exposed to constant concentrations of pharmaceuticals, endocrine disruptors and related compounds, among other anthropogenic contaminants. Macroinvertebrates inhabiting freshwater ecosystems might be useful bioindicators of exposure to contaminants, since their lives are long enough to bioaccumulate, but at the same time may integrate short-term changes in the environment. However, studies about potential bioaccumulation of emerging contaminants in these organisms are very scarce. The objectives of this study were to develop an analytical methodology for the analysis of 41 pharmaceuticals and 21 endocrine disruptors in freshwater invertebrates. In addition, bioaccumulation of these contaminants in three macroinvertebrate taxa inhabiting a waste water treatment plant -impacted river was evaluated. The method for the simultaneous extraction of both families of compounds is based on sonication, purification via removal of phospholipids, and analysis by ultra performance liquid chromatography coupled to a mass spectrometer (UPLC-MS/MS) in tandem. Recoveries for pharmaceuticals were 34-125%, and for endocrine disruptors were 48-117%. Method detection limits (MDLs) for EDCs were in the range of 0.080-2.4 ng g(-1), and for pharmaceuticals, 0.060-4.3 ng g(-1). These pollutants were detected in water samples taken downstream the waste water treatment plant effluent at concentrations up to 572 ng L(-1). Two non-esteroidal anti-inflammatory drugs, diclofenac and ibuprofen, and four endocrine disruptors - estrone, bisphenol A, TBEP, and nonylphenol - were detected in at least one macroinvertebrate taxa in concentrations up to 183 ng g(-1) (dry weight). An isobaric interference was identified during the analysis of diclofenac in Hydropsyche samples, which was successfully discriminated via accurate mass determination by TFC-LTQ Orbitrap. Copyright © 2014 Elsevier B.V. All rights reserved.

Extraction of mineral elements from inedible wastes of biological components of a life-support system and their utilization for plant nutrition

NASA Astrophysics Data System (ADS)

Gribovskaya, I. V.; Gladchenko, I. A.; Zinenko, G. K.

Two methods of extracting mineral elements from otherwise deadlock products of a life-support system are presented. We describe first optimum conditions for recovering elements by water extraction from dry wastes of plants, biomass ash, and solid human wastes after passing them through the catalytic furnace; and, second, we describe acid extracts of biogenous elements by 1N and 2N HNO_3 from these products. Ways to use the extracts of elements in plant nutrition are considered in order to increase the extent to which the mineral loop of a life-support system can be closed.

Waste Management System overview for future spacecraft.

NASA Technical Reports Server (NTRS)

Ingelfinger, A. L.; Murray, R. W.

1973-01-01

Waste Management Systems (WMS) for post Apollo spacecraft will be significantly more sophisticated and earthlike in user procedures. Some of the features of the advanced WMS will be accommodation of both males and females, automatic operation, either tissue wipe or anal wash, measurement and sampling of urine, feces and vomitus for medical analysis, water recovery, and solids disposal. This paper presents an overview of the major problems of and approaches to waste management for future spacecraft. Some of the processes discussed are liquid/gas separation, the Dry-John, the Hydro-John, automated sampling, vapor compression distillation, vacuum distillation-catalytic oxidation, incineration, and the integration of the above into complete systems.

Effects of drying pretreatment and particle size adjustment on the composting process of discarded flue-cured tobacco leaves.

PubMed

Zhao, Gui-Hong; Yu, Yan-Ling; Zhou, Xiang-Tong; Lu, Bin-Yu; Li, Zi-Mu; Feng, Yu-Jie

2017-05-01

The main characteristic of discarded flue-cured tobacco leaves is their high nicotine content. Aerobic composting is an effective method to decrease the nicotine level in tobacco leaves and stabilize tobacco wastes. However, high levels of nicotine in discarded flue-cured tobacco leaves complicate tobacco waste composting. This work proposes a drying pretreatment process to reduce the nicotine content in discarded flue-cured tobacco leaves and thus enhance its carbon-to-nitrogen ratio to a suitable level for composting. The effect of another pretreatment method, particle size adjustment, on composting efficiency was also tested in this work. The results indicated that the air-dried (nicotine content: 1.35%) and relatively long discarded flue-cured tobacco leaves (25 mm) had a higher composting efficiency than damp (nicotine content: 1.57%) and short discarded flue-cured tobacco leaves (15 mm). When dry/25 mm discarded flue-cured tobacco leaves mixed with tobacco stems in an 8:2 ratio was composted at a temperature above 55 °C for 9 days, the nicotine content dropped from 1.29% to 0.28%. Since the discarded flue-cured tobacco leaves was successfully composted to a fertile and harmless material, the germination index values increased to 85.2%. The drying pretreatment and particle size adjustment offered ideal physical and chemical conditions to support microbial growth and bioactivity during the composting process, resulting in efficient conversion of discarded flue-cured tobacco leaves into a high quality and mature compost.

A Technical and Policy Case Study of Large-Scale Rescue and Redistribution of Perishable Foods by the "Leket Israel" Food Bank.

PubMed

Philip, Dana; Hod-Ovadia, Smadar; Troen, Aron M

2017-06-01

Food banks seeking to rescue and redistribute highly nutritious perishable foods to simultaneously alleviate food insecurity and reduce food waste often encounter practical, ethical, and political dilemmas. We present a case study of "Leket Israel," an Israeli food bank that uses an effective large-scale logistical model for the rescue and redistribution of perishable food and discuss the challenges and solutions it offers. The organization operates in a rich country plagued with poverty and inequality, where the government passively encourages nongovernmental organizations to respond to the serious and growing problem of food insecurity. Operating under a business-to-business model, Leket Israel distributes food via intermediary nonprofit organizations (NPOs), enriching the food they provide with fresh produce. Food is obtained through an Agricultural Gleaning project, Self-Growing Farm project, and Meal Rescue project. The partnering NPOs then distribute the food to people in need. Although the rescue and redistribution of highly perishable food is more costly and complex than acquiring, storing, and distributing dried and staple foods and it requires specialized knowledge and infrastructure in order to maintain rigorous safety standards, it improves the nutritional quality of the aid. In 2015, Leket Israel distributed 15 217 389 kg of food, 90% of which was fruit and vegetables, to 180 partnering NPOs nationwide, reaching an estimated 175 000 recipients. "Leket Israel" offers a valuable model that can be studied and emulated by international nutrition scientists, practitioners, and policy makers who are seeking to reduce food insecurity and food waste in other countries.

Solid recovered fuel: An experiment on classification and potential applications.

PubMed

Bessi, C; Lombardi, L; Meoni, R; Canovai, A; Corti, A

2016-01-01

The residual urban waste of Prato district (Italy) is characterized by a high calorific value that would make it suitable for direct combustion in waste-to-energy plants. Since the area of central Italy lacks this kind of plant, residual municipal waste is quite often allocated to mechanical treatment plants in order to recover recyclable materials (such as metals) and energy content, sending the dry fractions to waste-to-energy plants outside the region. With the previous Italian legislation concerning Refuse Derived Fuels, only the dry stream produced as output by the study case plant, considered in this study, could be allocated to energy recovery, while the other output flows were landfilled. The most recent Italian regulation, introduced a new classification for the fuel streams recovered from waste following the criteria of the European standard (EN 15359:2011), defining the Solid Recovered Fuel (SRF). In this framework, the aim of this study was to check whether the different streams produced as output by the study case plant could be classified as SRF. For this reason, a sampling and analysis campaign was carried out with the purpose of characterizing every single output stream that can be obtained from the study case mechanical treatment plant, when operating it in different ways. The results showed that all the output flows from the study case mechanical treatment plant were classified as SRF, although with a wide quality range. In particular, few streams, of rather poor quality, could be fed to waste-to-energy plants, compatibly with the plant feeding systems. Other streams, with very high quality, were suitable for non-dedicated facilities, such as cement plants or power plants, as a substitute for coal. The implementation of the new legislation has hence the potential for a significant reduction of landfilling, contributing to lowering the overall environmental impact by avoiding the direct impacts of landfilling and by exploiting the beneficial effects of energy recovery from waste. Copyright © 2015 Elsevier Ltd. All rights reserved.

Research challenges in municipal solid waste logistics management.

PubMed

Bing, Xiaoyun; Bloemhof, Jacqueline M; Ramos, Tania Rodrigues Pereira; Barbosa-Povoa, Ana Paula; Wong, Chee Yew; van der Vorst, Jack G A J

2016-02-01

During the last two decades, EU legislation has put increasing pressure on member countries to achieve specified recycling targets for municipal household waste. These targets can be obtained in various ways choosing collection methods, separation methods, decentral or central logistic systems, etc. This paper compares municipal solid waste (MSW) management practices in various EU countries to identify the characteristics and key issues from a waste management and reverse logistics point of view. Further, we investigate literature on modelling municipal solid waste logistics in general. Comparing issues addressed in literature with the identified issues in practice result in a research agenda for modelling municipal solid waste logistics in Europe. We conclude that waste recycling is a multi-disciplinary problem that needs to be considered at different decision levels simultaneously. A holistic view and taking into account the characteristics of different waste types are necessary when modelling a reverse supply chain for MSW recycling. Copyright © 2015 Elsevier Ltd. All rights reserved.

33 CFR 159.131 - Safety: Incinerating device.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) POLLUTION MARINE SANITATION DEVICES Design, Construction, and Testing § 159.131 Safety.... Unitized incineration devices must completely burn to a dry, inert ash, a simultaneous defecation and...

Progress report Waste Resources Utilization Program period ending March 31, 1976. [Radiosterilization of sewage sludge for safe application as fertilizer or animal feed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1976-06-01

This report describes the work on the Waste Resources Utilization Program for the quarter ending March 31, 1976. The purpose of this program is to develop technologies to utilize a /sup 137/Cs ..gamma.. source to modify sewage sludge for safe application as a fertilizer or an animal feed supplement. Results are reported from studies in microbiology, virology, and physical-chemical studies. Determinations were made of inactivation rates for Salmonella species, coliforms, and fecal strep in sewage sludge when radiation and thermoradiation were applied while bubbling oxygen through the sludge. Virology studies were continued investigating virucidal characteristics of anaerobically digested sludge. Anothermore » area of study was the dewatering of sewage sludge to reduce the drying time of the sewage sludge in the drying beds. A centrifuge was also installed to dewater treated sludge to approximately 30 percent solids. (auth)« less

Vermicomposting of a lignocellulosic waste from olive oil industry: a pilot scale study.

PubMed

Benítez, E; Sainz, H; Melgar, R; Nogales, R

2002-04-01

The vermicomposting with Eisenia andrei of dry olive cake, a lignocellulosic waste produced during the extraction of olive oil, either alone or mixed with municipal biosolids, was studied in a nine-month pilot scale experiment. Number and biomass of earthworms and enzyme activities were periodically monitored and relevant properties of the final products were determined. In the assayed substrates, the total biomass of earthworms increased at the end of the experimental period between 9 and 12-fold respectively in comparison with the earthworm biomass initially inoculated. The increase in hydrolytic enzymes and overall microbial activity during the vermicomposting process indicated the biodegradation of the olive cake and resulted in the disappearance of the initial phytotoxicity of the substrate. However, the recalcitrant lignocellulosic nature of the dry olive cake prevented suitable humification during the vermicomposting process. For this reason, in addition to organic amendments, other management procedures should be considered.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seiple, Timothy E.; Coleman, André M.; Skaggs, Richard L.

Within the United States and Puerto Rico, publicly owned treatment works (POTWs) process 130.5 Gl/d (34.5 Bgal/d) of wastewater, producing sludge as a waste product. Emerging technologies offer novel waste-to-energy pathways through whole sludge conversion into biofuels. Assessing the feasibility, scalability and tradeoffs of various energy conversion pathways is difficult in the absence of highly spatially resolved estimates of sludge production. In this study, average wastewater solids concentrations and removal rates, and site specific daily average influent flow are used to estimate site specific annual sludge production on a dry weight basis for >15,000 POTWs. Current beneficial uses, regional productionmore » hotspots and feedstock aggregation potential are also assessed. Analyses indicate 1) POTWs capture 12.56 Tg/y (13.84 MT/y) of dry solids; 2) 50% are not beneficially utilized, and 3) POTWs can support seven regions that aggregate >910 Mg/d (1000 T/d) of sludge within a travel distance of 100 km.« less

Stimulation of the anaerobic digestion of the dry organic fraction of municipal solid waste (OFMSW) with carbon-based conductive materials.

PubMed

Dang, Yan; Sun, Dezhi; Woodard, Trevor L; Wang, Li-Ying; Nevin, Kelly P; Holmes, Dawn E

2017-08-01

Growth of bacterial and archaeal species capable of interspecies electron exchange was stimulated by addition of conductive materials (carbon cloth or granular activated carbon (GAC)) to anaerobic digesters treating dog food (a substitute for the dry-organic fraction of municipal solid waste (OFMSW)). Methane production (772-1428mmol vs <80mmol), volatile solids removal (78%-81% vs 54%-64%) and COD removal efficiencies (∼80% vs 20%-30%) were all significantly higher in reactors amended with GAC or carbon cloth than controls. OFMSW degradation was also significantly accelerated and VFA concentrations were substantially lower in reactors amended with conductive materials. These results suggest that both conductive materials (carbon cloth and GAC) can promote conversion of OFMSW to methane even in the presence of extremely high VFA concentrations (∼500mM). Copyright © 2017 Elsevier Ltd. All rights reserved.

Treatment of CELSS and PCELSS waste to produce nutrients for plant growth. [Controlled Ecological Life Support Systems and Partially Controlled Ecological Life Support Systems

NASA Technical Reports Server (NTRS)

Modell, M.; Meissner, H.; Karel, M.; Carden, J.; Lewis, S.

1981-01-01

The research program entitled 'Development of a Prototype Experiment for Treating CELSS (Controlled Ecological Life Support Systems) and PCELSS (Partially Controlled Ecological Life Support Systems) Wastes to Produce Nutrients for Plant Growth' consists of two phases: (1) the development of the neccessary facilities, chemical methodologies and models for meaningful experimentation, and (2) the application of what methods and devices are developed to the interfacing of waste oxidation with plant growth. Homogeneous samples of freeze-dried human feces and urine have been prepared to ensure comparability of test results between CELSS waste treatment research groups. A model of PCELSS food processing wastes has been developed, and an automated gas chromatographic system to analyze oxidizer effluents was designed and brought to operational status. Attention is given the component configuration of the wet oxidation system used by the studies.

Waste streams in a typical crewed space habitat: An update

NASA Technical Reports Server (NTRS)

Golub, M. A.; Wydeven, T.

1992-01-01

A compilation of generation rates and chemical compositions of potential waste streams in a typical crewed space habitat, reported in a prior NASA Technical Memorandum and a related journal article, was updated. This report augments that compilation by the inclusion of the following new data: those data uncovered since completion of the prior report; those obtained from Soviet literature relevant to life support issues; and those for various minor human body wastes not presented previously (saliva, flatus, hair, finger- and toenails, dried skin and skin secretions, tears, and semen), but included here for purposes of completeness. These waste streams complement those discussed previously: toilet waste (urine, feces, etc.), hygiene water (laundry, shower/handwash, dishwasher water and cleansing agents), trash, humidity condensate, perspiration and respiration water, trace contaminants, and dust generation. This report also reproduces the latest information on the environmental control and life support system design parameters for Space Station Freedom.

Performance Characteristics of Waste Glass Powder Substituting Portland Cement in Mortar Mixtures

NASA Astrophysics Data System (ADS)

Kara, P.; Csetényi, L. J.; Borosnyói, A.

2016-04-01

In the present work, soda-lime glass cullet (flint, amber, green) and special glass cullet (soda-alkaline earth-silicate glass coming from low pressure mercury-discharge lamp cullet and incandescent light bulb borosilicate glass waste cullet) were ground into fine powders in a laboratory planetary ball mill for 30 minutes. CEM I 42.5N Portland cement was applied in mortar mixtures, substituted with waste glass powder at levels of 20% and 30%. Characterisation and testing of waste glass powders included fineness by laser diffraction particle size analysis, specific surface area by nitrogen adsorption technique, particle density by pycnometry and chemical analysis by X-ray fluorescence spectrophotometry. Compressive strength, early age shrinkage cracking and drying shrinkage tests, heat of hydration of mortars, temperature of hydration, X-ray diffraction analysis and volume stability tests were performed to observe the influence of waste glass powder substitution for Portland cement on physical and engineering properties of mortar mixtures.

Waste, Economists and American Healthcare

PubMed Central

Evans, Robert G.

2013-01-01

Twenty-five years ago, Uwe Reinhardt pointed out that sheer bureaucratic waste, particularly in the private sector, accounted for much of the extraordinarily high cost of American health-care. Last year an expert panel of the Institute of Medicine reconfirmed his point, estimating that in 2009, administrative waste accounted for $190 billion out of a total of $765 billion in various forms of waste – 31% of overall American spending on healthcare. Reinhardt recently noted a peculiar schizophrenia among American economists, simultaneously deploring this monumental waste while celebrating the contribution of healthcare, and particularly medical research, to the American economy. The apparent paradox may arise from a confusion between the meanings of “value” in economic and everyday language, and from economists' tendency to create pseudo-aggregates of diverse and non-commensurate entities. PMID:24359713

Waste, economists and American healthcare.

PubMed

Evans, Robert G

2013-11-01

Twenty-five years ago, Uwe Reinhardt pointed out that sheer bureaucratic waste, particularly in the private sector, accounted for much of the extraordinarily high cost of American health-care. Last year an expert panel of the Institute of Medicine reconfirmed his point, estimating that in 2009, administrative waste accounted for $190 billion out of a total of $765 billion in various forms of waste--31% of overall American spending on healthcare. Reinhardt recently noted a peculiar schizophrenia among American economists, simultaneously deploring this monumental waste while celebrating the contribution of healthcare, and particularly medical research, to the American economy. The apparent paradox may arise from a confusion between the meanings of "value" in economic and everyday language, and from economists' tendency to create pseudo-aggregates of diverse and non-commensurate entities. Copyright © 2013 Longwoods Publishing.

Simulation of co-incineration of sewage sludge with municipal solid waste in a grate furnace incinerator.

PubMed

Lin, Hai; Ma, Xiaoqian

2012-03-01

Incineration is one of the most important methods in the resource recovery disposal of sewage sludge. The combustion characteristics of sewage sludge and an increasing number of municipal solid waste (MSW) incineration plants provide the possibility of co-incineration of sludge with MSW. Computational fluid dynamics (CFD) analysis was used to verify the feasibility of co-incineration of sludge with MSW, and predict the effect of co-incineration. In this study, wet sludge and semi-dried sludge were separately blended with MSW as mixed fuels, which were at a co-incineration ratios of 5 wt.% (wet basis, the same below), 10 wt.%, 15 wt.%, 20 wt.% and 25 wt.%. The result indicates that co-incineration of 10 wt.% wet sludge with MSW can ensure the furnace temperature, the residence time and other vital items in allowable level, while 20 wt.% of semi-dried sludge can reach the same standards. With lower moisture content and higher low heating value (LHV), semi-dried sludge can be more appropriate in co-incineration with MSW in a grate furnace incinerator. Copyright © 2011 Elsevier Ltd. All rights reserved.

Reuse of thermosetting plastic waste for lightweight concrete.

PubMed

Panyakapo, Phaiboon; Panyakapo, Mallika

2008-01-01

This paper presents the utilization of thermosetting plastic as an admixture in the mix proportion of lightweight concrete. Since this type of plastic cannot be melted in the recycling process, its waste is expected to be more valuable by using as an admixture for the production of non-structural lightweight concrete. Experimental tests for the variation of mix proportion were carried out to determine the suitable proportion to achieve the required properties of lightweight concrete, which are: low dry density and acceptable compressive strength. The mix design in this research is the proportion of plastic, sand, water-cement ratio, aluminum powder, and lignite fly ash. The experimental results show that the plastic not only leads to a low dry density concrete, but also a low strength. It was found that the ratio of cement, sand, fly ash, and plastic equal to 1.0:0.8:0.3:0.9 is an appropriate mix proportion. The results of compressive strength and dry density are 4.14N/mm2 and 1395 kg/m3, respectively. This type of concrete meets most of the requirements for non-load-bearing lightweight concrete according to ASTM C129 Type II standard.

Optimisation of single-phase dry-thermophilic anaerobic digestion under high organic loading rates of industrial municipal solid waste: population dynamics.

PubMed

Zahedi, S; Sales, D; Romero, L I; Solera, R

2013-10-01

Different high feed organic loading rates (OLRs) (from 5.7 g to 46.0 g TVS/l/d) or hydraulic retention times (HRTs) (from 15 d to 2 d) in single-phase dry-thermophilic anaerobic digestion (AD) of organic fraction municipal solid waste (OFMSW) were investigated. The specific gas production (SGP) values (0.25-0.53 m(3)/kg TVS) and the percentages of Eubacteria, Archaea, H2-utilising methanogens (HUMs) and acetate-utilising methanogens (AUMs) were stable within the ranges 80.2-91.1%, 12.4-18.5%, 4.4-9.8% and 5.5-10.9%, respectively. A HUM/AUM ratio greater than 0.7 seems to be necessary to maintain very low partial pressures of H2 required for dry AD process. Increasing OLR resulted in an increase in all the populations, except for propionate-utilising acetogens (PUAs). Optimal conditions were obtained at 3d HRT (OLR=30.7 g TVS/l/d), which is lower than the doubling time of acetogens and methanogens. The methane production (MP) was clearly higher than those reported in AD of OFMSW. Copyright © 2013 Elsevier Ltd. All rights reserved.

Comparison through a LCA evaluation analysis of food waste disposal options from the perspective of global warming and resource recovery.

PubMed

Kim, Mi-Hyung; Kim, Jung-Wk

2010-09-01

This study evaluated feed manufacturing including dry feeding and wet feeding, composting, and landfilling for food waste disposal options from the perspective of global warming and resource recovery. The method of the expanded system boundaries was employed in order to compare different by-products. The whole stages of disposal involved in the systems such as separate discharge, collection, transportation, treatment, and final disposal, were included in the system boundary and evaluated. The Global Warming Potential generated from 1tonne of food wastes for each disposal system was analyzed by the life cycle assessment method. The results showed that 200kg of CO(2)-eq could be produced from dry feeding process, 61kg of CO(2)-eq from wet feeding process, 123kg of CO(2)-eq from composting process, and 1010kg of CO(2)-eq from landfilling. Feed manufacturing and composting, the common treatment methods currently employed, have been known to be environment friendlier than other methods. However, this study shows that they can negatively affect the environment if their by-products are not appropriately utilized as intended. Copyright 2010 Elsevier B.V. All rights reserved.

Hanford Waste Physical and Rheological Properties: Data and Gaps

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wells, Beric E.; Kurath, Dean E.; Mahoney, Lenna A.

2011-08-01

The Hanford Site in Washington State manages 177 underground storage tanks containing approximately 250,000 m3 of waste generated during past defense reprocessing and waste management operations. These tanks contain a mixture of sludge, saltcake and supernatant liquids. The insoluble sludge fraction of the waste consists of metal oxides and hydroxides and contains the bulk of many radionuclides such as the transuranic components and 90Sr. The saltcake, generated by extensive evaporation of aqueous solutions, consists primarily of dried sodium salts. The supernates consist of concentrated (5-15 M) aqueous solutions of sodium and potassium salts. The 177 storage tanks include 149 single-shellmore » tanks (SSTs) and 28 double -hell tanks (DSTs). Ultimately the wastes need to be retrieved from the tanks for treatment and disposal. The SSTs contain minimal amounts of liquid wastes, and the Tank Operations Contractor is continuing a program of moving solid wastes from SSTs to interim storage in the DSTs. The Hanford DST system provides the staging location for waste feed delivery to the Department of Energy (DOE) Office of River Protection’s (ORP) Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP is being designed and constructed to pretreat and then vitrify a large portion of the wastes in Hanford’s 177 underground waste storage tanks.« less

Optimization of waste combinations during in-vessel composting of agricultural waste.

PubMed

Varma, V Sudharsan; Kalamdhad, Ajay S; Kumar, Bimlesh

2017-01-01

In-vessel composting of agricultural waste is a well-described approach for stabilization of compost within a short time period. Although composting studies have shown the different combinations of waste materials for producing good quality compost, studies of the particular ratio of the waste materials in the mix are still limited. In the present study, composting was conducted with a combination of vegetable waste, cow dung, sawdust and dry leaves using a 550 L rotary drum composter. Application of a radial basis functional neural network was used to simulate the composting process. The model utilizes physico-chemical parameters with different waste materials as input variables and three output variables: volatile solids, soluble biochemical oxygen demand and carbon dioxide evolution. For the selected model, the coefficient of determination reached the high value of 0.997. The complicated interaction of agricultural waste components during composting makes it a nonlinear problem so it is difficult to find the optimal waste combinations for producing quality compost. Optimization of a trained radial basis functional model has yielded the optimal proportion as 62 kg, 17 kg and 9 kg for vegetable waste, cow dung and sawdust, respectively. The results showed that the predictive radial basis functional model described for drum composting of agricultural waste was well suited for organic matter degradation and can be successfully applied.

Poultry production's environmental impact on water quality.

PubMed

Pope, C W

1991-05-01

Poultry meat and eggs are rapidly becoming the major source of animal protein in the diets of American consumers. Such expansion has resulted in a similar increase in waste management problems. The national production of broilers and mature chickens was 5.68 billion, 242 million turkeys, 31 million ducks, and 69 trillion table eggs in 1989 based on the USDA National Statistics Survey. Annual production of fecal waste from poultry flocks was 8.8 million tons on a dry weight basis plus more than 106,000 metric tons of broiler hatchery waste. Add to this 37 million dead birds and condemnations at processing plants (figures are also from USDA for 1989 based on USDA National Statistics Survey). When all this waste is added together, the task of keeping the environment clean becomes monumental. The following waste management practices can and must take care of these poultry industry waste products: sanitary land fills, rendering facilities, extrusion machinery, compost plants, lagoons or holding tanks, and land application techniques.

Evaluation of soil manipulation to prepare engineered earthen waste covers for revegetation

DOE PAGES

Waugh, W. Joseph; Benson, Craig H.; Albright, William H.; ...

2015-10-21

Seven ripping treatments designed to improve soil physical conditions for revegetation were compared on a test pad simulating an earthen cover for a waste disposal cell. The field test was part of study of methods to convert compacted-soil waste covers into evapotranspiration covers. The test pad consisted of a compacted layer of fine-textured soil simulating a barrier protection layer overlain by a gravelly sand bedding layer and a cobble armor layer. Treatments included combinations of soil-ripping implements (conventional shank [CS], wing-tipped shank [WTS], and parabolic oscillating shank with wings [POS]), ripping depths, and number of passes. Dimensions, dry density, moisturemore » content, and particle size distribution of disturbance zones were determined in two trenches excavated across rip rows. The goal was to create a root-zone dry density between 1.2 and 1.6 Mg m-3 and a seedbed soil texture ranging from clay loam to sandy loam with low rock content. All treatments created V-shaped disturbance zones as measured on trench faces. Disturbance zone size was most influenced by ripping depth. Winged implements created larger disturbance zones. All treatments lifted fines into the bedding layer, moved gravel and cobble down into the fine-textured protection layer, and thereby disrupted the capillary barrier at the interface. Changes in dry density within disturbance zones were comparable for the CS and WTS treatments but were highly variable among POS treatments. Water content increased in the bedding layer and decreased in the protection layer after ripping. The POS at 1.2-m depth and two passes created the largest zone with a low dry density (1.24 Mg m-3) and the most favorable seedbed soil texture (gravely silt loam). Furthermore, ripping also created large soil aggregates and voids in the protection layer that may produce preferential flow paths and reduce water storage capacity.« less

Chemical Species in the Vapor Phase of Hanford Double-Shell Tanks: Potential Impacts on Waste Tank Corrosion Processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Felmy, Andrew R.; Qafoku, Odeta; Arey, Bruce W.

2010-09-22

The presence of corrosive and inhibiting chemicals on the tank walls in the vapor space, arising from the waste supernatant, dictate the type and degree of corrosion that occurs there. An understanding of how waste chemicals are transported to the walls and the affect on vapor species from changing supernatant chemistry (e.g., pH, etc.), are basic to the evaluation of risks and impacts of waste changes on vapor space corrosion (VSC). In order to address these issues the expert panel workshop on double-shell tank (DST) vapor space corrosion testing (RPP-RPT-31129) participants made several recommendations on the future data and modelingmore » needs in the area of DST corrosion. In particular, the drying of vapor phase condensates or supernatants can form salt or other deposits at the carbon steel interface resulting in a chemical composition at the near surface substantially different from that observed directly in the condensates or the supernatants. As a result, over the past three years chemical modeling and experimental studies have been performed on DST supernatants and condensates to predict the changes in chemical composition that might occur as condensates or supernatants equilibrate with the vapor space species and dry at the carbon steel surface. The experimental studies included research on both the chemical changes that occurred as the supernatants dried as well as research on how these chemical changes impact the corrosion of tank steels. The chemical modeling and associated experimental studies were performed at the Pacific Northwest National Laboratory (PNNL) and the research on tank steel corrosion at the Savannah River National Laboratory (SRNL). This report presents a summary of the research conducted at PNNL with special emphasis on the most recent studies conducted in FY10. An overall summary of the project results as well as their broader implications for vapor space corrosion of the DST’s is given at the end of this report.« less

Depleted uranium as a backfill for nuclear fuel waste package

DOEpatents

Forsberg, Charles W.

1998-01-01

A method for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package.

Depleted uranium as a backfill for nuclear fuel waste package

DOEpatents

Forsberg, C.W.

1998-11-03

A method is described for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package. 6 figs.

Dry method for recycling iodine-loaded silver zeolite

DOEpatents

Thomas, Thomas R.; Staples, Bruce A.; Murphy, Llewellyn P.

1978-05-09

Fission product iodine is removed from a waste gas stream and stored by passing the gas stream through a bed of silver-exchanged zeolite until the zeolite is loaded with iodine, passing dry hydrogen gas through the bed to remove the iodine and regenerate the bed, and passing the hydrogen stream containing the hydrogen iodide thus formed through a lead-exchanged zeolite which adsorbs the radioactive iodine from the gas stream and permanently storing the lead-exchanged zeolite loaded with radioactive iodine.

Effects of processing methods on composition and functionality of volatile components isolated from immature fruits of atemoya.

PubMed

Liu, Tai-Ti; Chao, Louis Kuo-Ping; Peng, Chi-Wei; Yang, Tsung-Shi

2016-07-01

Atemoya is one of the most important commercial fruits of the family Annonaceae. The immature fruits of atemoya amply produced from a fruit-thinning process is normally regarded as waste and discarded. This research aimed at studying antimicrobial, antioxidant, and anti-inflammatory activities of the essential oil (EO) isolated from the immature fruits to explore its potential application. The fruits were subjected to different drying methods: solar drying (SD), oven drying at 30°C (OD-30), and at 50°C (OD-50). The oven drying method gave a higher EO yield than the solar drying method. Spathulenol was the largest compound in the EO after the drying process. Antimicrobial effect was not affected by the different drying methods. Antioxidant activity of the EO was measured by DPPH, nitric oxide, and reducing power methods. The EOOD-50 exhibited a stronger antioxidant activity than EOSD and EOOD-30. The EO also showed an anti-inflammatory activity in a cell model. Copyright © 2016. Published by Elsevier Ltd.

In Situ Bioremediation of Chlorinated Solvent Source Areas with Enhanced Mass Transfer

DTIC Science & Technology

2008-09-01

immerse in cold water. Do not apply ointment , grease or Vaseline. Cover burns with thick, dry sterile dressings. Keep burned feet or legs elevated...about six to eight barrels per month of waste TCE and POL may have been disposed. These materials were also used to aid in burning other wastes...These consist of man-made fill in the trench areas and include debris and burned material. These materials typically extend to less than 12 ft bgs

Dual mechanochemical immobilization of heavy metals and decomposition of halogenated compounds in automobile shredder residue using a nano-sized metallic calcium reagent.

PubMed

Mallampati, Srinivasa Reddy; Lee, Byoung Ho; Mitoma, Yoshiharu; Simion, Cristian

2016-11-01

Simultaneous immobilization of heavy metals and decomposition of halogenated organic compounds in different fractions of automobile shredder residue (ASR) were achieved with a nano-sized metallic calcium through a 60-min ball milling treatment. Heavy metal (HM) immobilization and chlorinated/brominated compound (CBC) decomposition efficiencies both reached 90-100 %, after ball milling with nanometallic calcium/calcium oxide (Ca/CaO) dispersion, regardless of ASR particle size (1.0, 0.45-1.0, and 0.250 mm). Concentrations of leachable HMs substantially decreased to a level lower than the regulatory standard limits (Co and Cd 0.3 mg L -1 ; Cr 1.5 mg L -1 ; Fe, Pb, and Zn 3.0 mg L -1 ; Mn and Ni 1 mg L -1 ) proposed by the Korean hazardous waste elution standard regulatory threshold. Scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) element maps/spectra showed that while the amounts of HMs and CBCs detectable in ASR significantly decreased, the calcium mass percentage increased. X-ray powder diffraction (XRD) patterns indicate that the main fraction of enclosed/bound materials on ASR includes Ca-associated crystalline complexes that remarkably inhibit HM desorption and simultaneously transform dangerous CBCs into harmless compounds. The use of a nanometallic Ca/CaO mixture in a mechanochemical process to treat hazardous ASR (dry conditions) is an innovative approach to remediate cross-contaminated residues with heavy metals and halogenated compounds.

A fully automated method for simultaneous determination of aflatoxins and ochratoxin A in dried fruits by pressurized liquid extraction and online solid-phase extraction cleanup coupled to ultra-high-pressure liquid chromatography-tandem mass spectrometry.

PubMed

Campone, Luca; Piccinelli, Anna Lisa; Celano, Rita; Russo, Mariateresa; Valdés, Alberto; Ibáñez, Clara; Rastrelli, Luca

2015-04-01

According to current demands and future perspectives in food safety, this study reports a fast and fully automated analytical method for the simultaneous analysis of the mycotoxins with high toxicity and wide spread, aflatoxins (AFs) and ochratoxin A (OTA) in dried fruits, a high-risk foodstuff. The method is based on pressurized liquid extraction (PLE), with aqueous methanol (30%) at 110 °C, of the slurried dried fruit and online solid-phase extraction (online SPE) cleanup of the PLE extracts with a C18 cartridge. The purified sample was directly analysed by ultra-high-pressure liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) for sensitive and selective determination of AFs and OTA. The proposed analytical procedure was validated for different dried fruits (vine fruit, fig and apricot), providing method detection and quantification limits much lower than the AFs and OTA maximum levels imposed by EU regulation in dried fruit for direct human consumption. Also, recoveries (83-103%) and repeatability (RSD < 8, n = 3) meet the performance criteria required by EU regulation for the determination of the levels of mycotoxins in foodstuffs. The main advantage of the proposed method is full automation of the whole analytical procedure that reduces the time and cost of the analysis, sample manipulation and solvent consumption, enabling high-throughput analysis and highly accurate and precise results.

40 CFR 761.62 - Disposal of PCB bulk product waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... molded rubber parts and components; applied dried paints, varnishes, waxes or other similar coatings or... released or dispersed by wind or other action; or (2) Under asphalt as part of a road bed. [63 FR 35451...

40 CFR 761.62 - Disposal of PCB bulk product waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... molded rubber parts and components; applied dried paints, varnishes, waxes or other similar coatings or... released or dispersed by wind or other action; or (2) Under asphalt as part of a road bed. [63 FR 35451...

40 CFR 761.62 - Disposal of PCB bulk product waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... molded rubber parts and components; applied dried paints, varnishes, waxes or other similar coatings or... released or dispersed by wind or other action; or (2) Under asphalt as part of a road bed. [63 FR 35451...

40 CFR 761.62 - Disposal of PCB bulk product waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... molded rubber parts and components; applied dried paints, varnishes, waxes or other similar coatings or... released or dispersed by wind or other action; or (2) Under asphalt as part of a road bed. [63 FR 35451...

Oil palm waste and synthetic zeolite: an alternative soil-less growth substrate for lettuce production as a waste management practice.

PubMed

Jayasinghe, Guttila Y; Tokashiki, Yoshihiro; Kitou, Makato; Kinjo, Kazutoshi

2008-12-01

A study was conducted to assess the characteristics and the prospective utilization of oil palm waste (OP) and synthetic zeolite (SZ) developed by coal fly ash, as an alternative substrate to peat and commercial perlite for lettuce (Lactuca sativa L.) production. The SZ, OP, sphagnum peat (PE), perlite (PL) and two different SZ-OP mixtures (v/v) at the ratio of 1 : 3 and 1 : 10 were utilized as the substrates under this study. The substrates formulated by mixing SZ with OP at the ratio of 1 : 3 and 1 : 10 showed improved substrate physical and chemical properties such as air space, bulk density, particle density, water-holding capacity, pH and electrical conductivity (EC), which were in the ideal substrate range when compared with PL. Furthermore, the water-holding capacity of the substrate having a 1 : 10 mixing ratio of SZ with OP was higher than that of the PL by 28.23%, whereas the bulk density was lower than that of PL by 35%. A greenhouse experiment was carried out to assess the influence of the substrates on the growth and development of lettuce. The shoot fresh weight, shoot dry weight, root fresh weight, root dry weight and number of leaves per plant of the lettuce grown in the 1 : 10 mixing ratio of SZ and OP were the highest, which showed increased values compared with that of PL by 11.56, 9.77, 3.48, 17.35 and 16.53%, respectively. The shoot fresh weight, shoot dry weight, root fresh weight, root dry weight and number of leaves per plant of the lettuce grown in the 1 : 10 mixing ratio of SZ and OP showed increased percentages compared with that of PE by 12.12, 11.37, 3.74, 23.66 and 17.50%, respectively. In addition, the growth and yield parameters of lettuce grown in the 1 : 3 mixing ratio and the OP did not show any significant difference with PL and PE but differed from the 1 : 10 mixing ratio. The results of the study suggest that the SZ-OP-based substrates and OP can be successfully utilized as alternatives to the commercial perlite and to substitute the conventional peat substrate for lettuce cultivation. In addition, this can be proposed as an alternative waste management practice.

Enhanced Bio-Ethanol Production from Industrial Potato Waste by Statistical Medium Optimization.

PubMed

Izmirlioglu, Gulten; Demirci, Ali

2015-10-15

Industrial wastes are of great interest as a substrate in production of value-added products to reduce cost, while managing the waste economically and environmentally. Bio-ethanol production from industrial wastes has gained attention because of its abundance, availability, and rich carbon and nitrogen content. In this study, industrial potato waste was used as a carbon source and a medium was optimized for ethanol production by using statistical designs. The effect of various medium components on ethanol production was evaluated. Yeast extract, malt extract, and MgSO₄·7H₂O showed significantly positive effects, whereas KH₂PO₄ and CaCl₂·2H₂O had a significantly negative effect (p-value<0.05). Using response surface methodology, a medium consisting of 40.4 g/L (dry basis) industrial waste potato, 50 g/L malt extract, and 4.84 g/L MgSO₄·7H₂O was found optimal and yielded 24.6 g/L ethanol at 30 °C, 150 rpm, and 48 h of fermentation. In conclusion, this study demonstrated that industrial potato waste can be used effectively to enhance bioethanol production.

Pie waste - A component of food waste and a renewable substrate for producing ethanol.

PubMed

Magyar, Margaret; da Costa Sousa, Leonardo; Jayanthi, Singaram; Balan, Venkatesh

2017-04-01

Sugar-rich food waste is a sustainable feedstock that can be converted into ethanol without an expensive thermochemical pretreatment that is commonly used in first and second generation processes. In this manuscript we have outlined the pie waste conversion to ethanol through a two-step process, namely, enzyme hydrolysis using commercial enzyme products mixtures and microbial fermentation using yeast. Optimized enzyme cocktail was found to be 45% alpha amylase, 45% gamma amylase, and 10% pectinase at 2.5mg enzyme protein/g glucan produced a hydrolysate with high glucose concentration. All three solid loadings (20%, 30%, and 40%) produced sugar-rich hydrolysates and ethanol with little to no enzyme or yeast inhibition. Enzymatic hydrolysis and fermentation process mass balance was carried out using pie waste on a 1000g dry weight basis that produced 329g ethanol at 20% solids loading. This process clearly demonstrate how food waste could be efficiently converted to ethanol that could be used for making biodiesel by reacting with waste cooking oil. Copyright © 2017 Elsevier Ltd. All rights reserved.

Simultaneous water vapor and dry air optical path length measurements and compensation with the large binocular telescope interferometer

NASA Astrophysics Data System (ADS)

Defrère, D.; Hinz, P.; Downey, E.; Böhm, M.; Danchi, W. C.; Durney, O.; Ertel, S.; Hill, J. M.; Hoffmann, W. F.; Mennesson, B.; Millan-Gabet, R.; Montoya, M.; Pott, J.-U.; Skemer, A.; Spalding, E.; Stone, J.; Vaz, A.

2016-08-01

The Large Binocular Telescope Interferometer uses a near-infrared camera to measure the optical path length variations between the two AO-corrected apertures and provide high-angular resolution observations for all its science channels (1.5-13 microns). There is however a wavelength dependent component to the atmospheric turbulence, which can introduce optical path length errors when observing at a wavelength different from that of the fringe sensing camera. Water vapor in particular is highly dispersive and its effect must be taken into account for high-precision infrared interferometric observations as described previously for VLTI/MIDI or the Keck Interferometer Nuller. In this paper, we describe the new sensing approach that has been developed at the LBT to measure and monitor the optical path length fluctuations due to dry air and water vapor separately. After reviewing the current performance of the system for dry air seeing compensation, we present simultaneous H-, K-, and N-band observations that illustrate the feasibility of our feedforward approach to stabilize the path length fluctuations seen by the LBTI nuller.

Solvent for the simultaneous recovery of radionuclides from liquid radioactive wastes

DOEpatents

Romanovskiy, Valeriy Nicholiavich; Smirnov, Igor V.; Babain, Vasiliy A.; Todd, Terry A.; Brewer, Ken N.

2002-01-01

The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.

Method for the simultaneous recovery of radionuclides from liquid radioactive wastes using a solvent

DOEpatents

Romanovskiy, Valeriy Nicholiavich; Smirnov, Igor V.; Babain, Vasiliy A.; Todd, Terry A.; Brewer, Ken N.

2001-01-01

The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.

Impact of co-digestion on existing salt and nutrient mass balances for a full-scale dairy energy project.

PubMed

Camarillo, Mary Kay; Stringfellow, William T; Spier, Chelsea L; Hanlon, Jeremy S; Domen, Jeremy K

2013-10-15

Anaerobic digestion of manure and other agricultural waste streams with subsequent energy production can result in more sustainable dairy operations; however, importation of digester feedstocks onto dairy farms alters previously established carbon, nutrient, and salinity mass balances. Salt and nutrient mass balance must be maintained to avoid groundwater contamination and salination. To better understand salt and nutrient contributions of imported methane-producing substrates, a mass balance for a full-scale dairy biomass energy project was developed for solids, carbon, nitrogen, sulfur, phosphorus, chloride, and potassium. Digester feedstocks, consisting of thickened manure flush-water slurry, screened manure solids, sudan grass silage, and feed-waste, were tracked separately in the mass balance. The error in mass balance closure for most elements was less than 5%. Manure contributed 69.2% of influent dry matter while contributing 77.7% of nitrogen, 90.9% of sulfur, and 73.4% of phosphorus. Sudan grass silage contributed high quantities of chloride and potassium, 33.3% and 43.4%, respectively, relative to the dry matter contribution of 22.3%. Five potential off-site co-digestates (egg waste, grape pomace, milk waste, pasta waste, whey wastewater) were evaluated for anaerobic digestion based on salt and nutrient content in addition to bio-methane potential. Egg waste and wine grape pomace appeared the most promising co-digestates due to their high methane potentials relative to bulk volume. Increasing power production from the current rate of 369 kW to the design value of 710 kW would require co-digestion with either 26800 L d(-1) egg waste or 60900 kg d(-1) grape pomace. However, importation of egg waste would more than double nitrogen loading, resulting in an increase of 172% above the baseline while co-digestion with grape pomace would increase potassium by 279%. Careful selection of imported co-digestates and management of digester effluent is required to manage salt and nutrient mass loadings and reduce groundwater impacts. Copyright © 2013 Elsevier Ltd. All rights reserved.

Innovative dual-step management of semi-aerobic landfill in a tropical climate.

PubMed

Lavagnolo, Maria Cristina; Grossule, Valentina; Raga, Roberto

2018-04-01

Despite concerted efforts to innovate the solid waste management (SWM) system, land disposal continues to represent the most widely used technology in the treatment of urban solid waste worldwide. On the other hand, landfilling is an unavoidable step in closing the material cycle, since final residues, although minimized, need to be safely disposed of and confined. In recent years, the implementation of more sustainable landfilling aims to achieve the Final Storage Quality conditions as fast as possible. In particular, semi-aerobic landfill appears to represent an effective solution for use in the poorest economies due to lower management costs and shorter aftercare resulting from aerobic stabilisation of the waste. Nevertheless, the implementation of a semi-aerobic landfill in a tropical climate may affect the correct functioning of the plant: a lack of moisture during the dry season and heavy rainfalls during the wet season could negatively affect performance of both the degradation process, and of leachate and biogas management. This paper illustrates the results obtained through the experimentation of a potential dual-step management of semi-aerobic landfilling in a tropical climate in which composting process was reproduced during the dry season and subsequently flushing (high rainfall rate) during the wet period. Eight bioreactors specifically designed: four operated under anaerobic conditions and four under semi-aerobic conditions; half of the reactors were filled with high organic content waste, half with residual waste obtained following enhanced source segregation. The synergic effect of the subsequent phases (composting and flushing) in the semi-aerobic landfill was evaluated on the basis of both types of waste. Biogas production, leachate composition and waste stabilization were analysed during the trial and at the end of each step, and compared in view of the performance of anaerobic reactors. The results obtained underlined the effectiveness of the dual-step management evidencing how wastes reached a higher degree of stabilization and reference FSQ values for leachate were achieved over a one-year simulation period. Copyright © 2018 Elsevier Ltd. All rights reserved.

Kinetics of Cold-Cap Reactions for Vitrification of Nuclear Waste Glass Based on Simultaneous Differential Scanning Calorimetry - Thermogravimetry (DSC-TGA) and Evolved Gas Analysis (EGA)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodriguez, Carmen P.; Pierce, David A.; Schweiger, Michael J.

2013-12-03

For vitrifying nuclear waste glass, the feed, a mixture of waste with glass-forming and modifying additives, is charged onto the cold cap that covers 90-100% of the melt surface. The cold cap consists of a layer of reacting molten glass floating on the surface of the melt in an all-electric, continuous glass melter. As the feed moves through the cold cap, it undergoes chemical reactions and phase transitions through which it is converted to molten glass that moves from the cold cap into the melt pool. The process involves a series of reactions that generate multiple gases and subsequent massmore » loss and foaming significantly influence the mass and heat transfers. The rate of glass melting, which is greatly influenced by mass and heat transfers, affects the vitrification process and the efficiency of the immobilization of nuclear waste. We studied the cold-cap reactions of a representative waste glass feed using both the simultaneous differential scanning calorimetry thermogravimetry (DSC-TGA) and the thermogravimetry coupled with gas chromatography-mass spectrometer (TGA-GC-MS) as complementary tools to perform evolved gas analysis (EGA). Analyses from DSC-TGA and EGA on the cold-cap reactions provide a key element for the development of an advanced cold-cap model. It also helps to formulate melter feeds for higher production rate.« less

Optimization of Eisenia fetida stocking density for the bioconversion of rock phosphate enriched cow dung-waste paper mixtures.

PubMed

Unuofin, F O; Mnkeni, P N S

2014-11-01

Vermitechnology is gaining recognition as an environmental friendly waste management strategy. Its successful implementation requires that the key operational parameters like earthworm stocking density be established for each target waste/waste mixture. One target waste mixture in South Africa is waste paper mixed with cow dung and rock phosphate (RP) for P enrichment. This study sought to establish optimal Eisenia fetida stocking density for maximum P release and rapid bioconversion of RP enriched cow dung-paper waste mixtures. E. fetida stocking densities of 0, 7.5, 12.5, 17.5 and 22.5 g-worms kg(-1) dry weight of cow dung-waste paper mixtures were evaluated. The stocking density of 12.5 g-worms kg(-1) resulted in the highest earthworm growth rate and humification of the RP enriched waste mixture as reflected by a C:N ratio of <12 and a humic acid/fulvic acid ratio of >1.9 in final vermicomposts. A germination test revealed that the resultant vermicompost had no inhibitory effect on the germination of tomato, carrot, and radish. Extractable P increased with stocking density up to 22.5 g-worm kg(-1) feedstock suggesting that for maximum P release from RP enriched wastes a high stocking density should be considered. Copyright © 2014. Published by Elsevier Ltd.

Potential of fecal waste for the production of biomethane, bioethanol and biodiesel.

PubMed

Gomaa, Mohamed A; Abed, Raeid M M

2017-07-10

Fecal waste is an environmental burden that requires proper disposal, which ultimately becomes also an economic burden. Because fecal waste is nutrient-rich and contains a diverse methanogenic community, it has been utilized to produce biomethane via anaerobic digestion. Carbohydrates and lipids in fecal waste could reach up to 50% of the dry weight, which also suggests a potential as a feedstock for bioethanol and biodiesel production. We measured biomethane production from fecal waste of cows, chickens, goats and humans and compared the microbial community composition before and after anaerobic digestion. We also compared the fecal waste for cellulase production, saccharification and fermentation to produce bioethanol and for lipid content and fatty acid profiles to produce biodiesel. All fecal waste produced biomethane, with the highest yield of 433.4±77.1ml CH 4 /g VS from cow fecal waste. Production of bioethanol was achieved from all samples, with chicken fecal waste yielding as high as 1.6±0.25g/l. Sludge samples exhibited the highest extractable portion of lipids (20.9±0.08wt%) and conversion to fatty acid methyl esters (11.94wt%). Utilization of fecal waste for the production of biofuels is environmentally and economically beneficial. Copyright © 2017 Elsevier B.V. All rights reserved.

Sister Earth, Our Common Home: Toward a Sustainable, Planet Friendly Approach to Dialysis, a Paradigm of High Technology Medicine.

PubMed

Piccoli, Giorgina Barbara; Mery, David

2017-11-01

In our high-technology, highly polluted world, medicine plays an important role balancing saving lives with the expenses of growing amounts of waste products, not only biologically dangerous (the potentially "contaminated" or "hazardous" waste) but also potentially harmful for the planet (nonrecyclable, plastic waste). Dialysis, the prototype of high-technology medicine, is central to these problems, as the present treatment of about 2 million patients produces an enormous quantity of waste (considering hazardous waste only about 2 kg per session, with 160 sessions per year, that is 320 kg per patient, or about 640,000 tons of hazardous waste per year for 2 million patients, roughly corresponding to 6 nuclear aircraft carriers). Furthermore, obsolete dialysis machines, and water treatments are discharged, adding to the "technological waste." Water produced by the reverse osmosis is also discharged; this is the only nonhazardous, nonpolluting waste, but in particular in dry areas, wasting water is a great ecologic concern. The present review is aimed at discussing strategies already in place and to be further implemented for reducing this particular "uremic toxin" for the earth: dialysis waste, including dialysis disposables, water, and dialysis machines. Copyright © 2017 National Kidney Foundation, Inc. Published by Elsevier Inc. All rights reserved.

Simultaneous high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS-MS) analysis of cyanide and thiocyanate from swine plasma.

PubMed

Bhandari, Raj K; Manandhar, Erica; Oda, Robert P; Rockwood, Gary A; Logue, Brian A

2014-01-01

An analytical procedure for the simultaneous determination of cyanide and thiocyanate in swine plasma was developed and validated. Cyanide and thiocyanate were simultaneously analyzed by high-performance liquid chromatography tandem mass spectrometry in negative ionization mode after rapid and simple sample preparation. Isotopically labeled internal standards, Na(13)C(15)N and NaS(13)C(15)N, were mixed with swine plasma (spiked and nonspiked), proteins were precipitated with acetone, the samples were centrifuged, and the supernatant was removed and dried. The dried samples were reconstituted in 10 mM ammonium formate. Cyanide was reacted with naphthalene-2,3-dicarboxaldehyde and taurine to form N-substituted 1-cyano[f]benzoisoindole, while thiocyanate was chemically modified with monobromobimane to form an SCN-bimane product. The method produced dynamic ranges of 0.1-50 and 0.2-50 μM for cyanide and thiocyanate, respectively, with limits of detection of 10 nM for cyanide and 50 nM for thiocyanate. For quality control standards, the precision, as measured by percent relative standard deviation, was below 8 %, and the accuracy was within ±10 % of the nominal concentration. Following validation, the analytical procedure successfully detected cyanide and thiocyanate simultaneously from the plasma of cyanide-exposed swine.

Recovery of phosphorus and volatile fatty acids from wastewater and food waste with an iron-flocculation sequencing batch reactor and acidogenic co-fermentation.

PubMed

Li, Ruo-Hong; Li, Xiao-Yan

2017-12-01

A sequencing batch reactor-based system was developed for enhanced phosphorus (P) removal and recovery from municipal wastewater. The system consists of an iron-dosing SBR for P precipitation and a side-stream anaerobic reactor for sludge co-fermentation with food waste. During co-fermentation, sludge and food waste undergo acidogenesis, releasing phosphates under acidic conditions and producing volatile fatty acids (VFAs) into the supernatant. A few types of typical food waste were investigated for their effectiveness in acidogenesis and related enzymatic activities. The results show that approximately 96.4% of total P in wastewater was retained in activated sludge. Food waste with a high starch content favoured acidogenic fermentation. Around 55.7% of P from wastewater was recovered as vivianite, and around 66% of food waste loading was converted into VFAs. The new integration formed an effective system for wastewater treatment, food waste processing and simultaneous recovery of P and VFAs. Copyright © 2017 Elsevier Ltd. All rights reserved.

1980 scrubber highlights: dry-process startups, dual-alkali progress highlight scrubber advances

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-06-01

A survey of electric utilities reports scrubbers on 13% of existing capacity and estimates 29% by 1990, but compliance with the New Source Performance Standards may raise the total even higher. Dry scrubbers at two Northern States Power installations show test performances that indicate sound design and report modest manpower requirements. Other utilities are ordering demonstration dry-scrubber units, although orders for wet scrubbers continue to do well. A new dual-alkali scrubber is performing well at three installations in terms of availability and sulfur-dioxide-removal efficiency. A full-scale utility dump site test will identify any hazardous materials in pollution control ash andmore » sludge wastes. (DCK)« less

Development of a microwave clothes dryer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-07-01

The objective of the project is to investigate the microwave drying of clothes and to produce an impartial, generic database for use by interested parties, including appliance manufacturers, who may want to use it when designing and developing microwave clothes dryers. This interim report covers the first year of activity on the project. During that time, a laboratory test model of a microwave clothes dryer was constructed and tested over a wide range of parameters. The test unit was the same size as a residential home dryer and had eight 0.85-kW microwave power supplies from home ovens and a 5-kWmore » resistance air heater. Thus, the model could be used for microwave drying, hot air drying or for a combination of both drying techniques. Microwave drying was effective in three drying modes: Cool drying, fast drying and very efficient drying. Microwaves penetrate the clothes and heat the water molecules directly while conventional heat energy must be conducted through the clothes to evaporate the water. In cool drying, microwaves alone heat the water and an airflow of slightly warmed air carries away the moisture. In fast drying, the microwave power is combined with hot air drying to reduce drying times by as much as 50%. In the most efficient mode of drying, microwave power is used along with the waste heat from the microwave power supply. Hazards testing and fine fabric tests are scheduled for the future.« less

Thermoelectric energy harvesting for a solid waste processing toilet

NASA Astrophysics Data System (ADS)

Stokes, C. David; Baldasaro, Nicholas G.; Bulman, Gary E.; Stoner, Brian R.

2014-06-01

Over 2.5 billion people do not have access to safe and effective sanitation. Without a sanitary sewer infrastructure, self-contained modular systems can provide solutions for these people in the developing world and remote areas. Our team is building a better toilet that processes human waste into burnable fuel and disinfects the liquid waste. The toilet employs energy harvesting to produce electricity and does not require external electrical power or consumable materials. RTI has partnered with Colorado State University, Duke University, and Roca Sanitario under a Bill and Melinda Gates Foundation Reinvent the Toilet Challenge (RTTC) grant to develop an advanced stand-alone, self-sufficient toilet to effectively process solid and liquid waste. The system operates through the following steps: 1) Solid-liquid separation, 2) Solid waste drying and sizing, 3) Solid waste combustion, and 4) Liquid waste disinfection. Thermoelectric energy harvesting is a key component to the system and provides the electric power for autonomous operation. A portion of the exhaust heat is captured through finned heat-sinks and converted to electricity by thermoelectric (TE) devices to provide power for the electrochemical treatment of the liquid waste, pumps, blowers, combustion ignition, and controls.

Immobilization of radioiodine in synthetic boracite

DOEpatents

Babad, H.; Strachan, D.M.

1982-09-23

A nuclear waste storage product is disclosed in which radioiodine is incorporated in a synthetic boracite. The boracite may be prepared by reacting a transition metal iodide with an alkali horate under mild hydrothermal conditions, drying the reaction product, and then hot pressing.

Study on the Volatility of Cesium in Dry Ashing Pretreatment and Dissolution of Ash by Microwave Digestion System - 13331

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choi, Kwang-Soon; Lee, Chang Heon; Ahn, Hong-Joo

2013-07-01

Based on the regulation of the activity concentration of Cs-137, Co-58, Co-60, Fe-55, Ni-59, Ni-63, Sr-90, Nb-94, and Tc-99, and the total alpha from the radioactive waste acceptance criteria, the measurement of the activity concentration of these nuclides in low and intermediate levels of radioactive waste such as in paper, cotton, vinyl and plastic samples was investigated. A dry ashing method was applied to obtain a concentration effect of the samples. Owing to the temperature dependence of the volatility for cesium, the temperature of 300 to 650 deg. C was examined. It was found that 450 deg. C is themore » optimum dry ashing temperature. After dry ashing, the produced ash was dissolved with HNO{sub 3}, HCl, and HF by a high-performance microwave digestion system. The ash sample, for the most part, was completely dissolved with 10 mL of HNO{sub 3}, 4 mL of HCl, and 0.25 mL of HF by a high-performance microwave digestion system using a nova high temperature rotor at 250 deg. C for 90 min until reaching 0.2 g. To confirm the reliability of cesium loss after the performance of the dry ashing procedure, a cesium standard solution for AAS and a Cs-137 standard solution for gamma spectrometry were added to a paper towel or a planchet of stainless steel, respectively. Cesium was measured by AAS, ICP-MS, and gamma spectrometry. The volatility of cesium did not occur until 450 deg. C ashing. (authors)« less

Simulation of fluid flow and energy transport processes associated with high-level radioactive waste disposal in unsaturated alluvium

USGS Publications Warehouse

Pollock, David W.

1986-01-01

Many parts of the Great Basin have thick zones of unsaturated alluvium which might be suitable for disposing of high-level radioactive wastes. A mathematical model accounting for the coupled transport of energy, water (vapor and liquid), and dry air was used to analyze one-dimensional, vertical transport above and below an areally extensive repository. Numerical simulations were conducted for a hypothetical repository containing spent nuclear fuel and located 100 m below land surface. Initial steady state downward water fluxes of zero (hydrostatic) and 0.0003 m yr−1were considered in an attempt to bracket the likely range in natural water flux. Predicted temperatures within the repository peaked after approximately 50 years and declined slowly thereafter in response to the decreasing intensity of the radioactive heat source. The alluvium near the repository experienced a cycle of drying and rewetting in both cases. The extent of the dry zone was strongly controlled by the mobility of liquid water near the repository under natural conditions. In the case of initial hydrostatic conditions, the dry zone extended approximately 10 m above and 15 m below the repository. For the case of a natural flux of 0.0003 m yr−1 the relative permeability of water near the repository was initially more than 30 times the value under hydrostatic conditions, consequently the dry zone extended only about 2 m above and 5 m below the repository. In both cases a significant perturbation in liquid saturation levels persisted for several hundred years. This analysis illustrates the extreme sensitivity of model predictions to initial conditions and parameters, such as relative permeability and moisture characteristic curves, that are often poorly known.

Optimization of solid state anaerobic digestion of the OFMSW by digestate recirculation: A new approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michele, Pognani, E-mail: michele.pognani@unimi.it; Giuliana, D’Imporzano, E-mail: giuliana.dimporzano@unimi.it; Gruppo Ricicla - DiSAA, Università degli Studi di Milano, Biomass and Bioenergy Lab., Parco Tecnologico Padano, Via Einstein, Loc. C.na Codazza, 26900 Lodi

2015-01-15

Highlights: • Solid State Anaerobic Digestion (SSAD) of OFMSW can be optimized by irrigation with digestate. • Digestate spreading allows keeping optimal process parameters and high hydrolysis rate. • The 18.4% of CH{sub 4} was produced in the reactor, leaving the 49.7% in the percolate. • Successive CSTR feed with percolate shows a biogas enriched in methane (more than 80%). • The proposed process allow producing the 68% of OFMSW potential CH{sub 4}, getting high quality organic amendment. - Abstract: Dry anaerobic digestion (AD) of OFMSW was optimized in order to produce biogas avoiding the use of solid inoculum. Doingmore » so the dry AD was performed irrigating the solid waste with liquid digestate (flow rate of 1:1.18–1:0.9 w/w waste/digestate; 21 d of hydraulic retention time – HRT) in order to remove fermentation products inhibiting AD process. Results indicated that a high hydrolysis rate of organic matter (OM) and partial biogas production were obtained directly during the dry AD. Hydrolysate OM was removed from digester by the percolate flow and it was subsequently used to feed a liquid anaerobic digester. During dry AD a total loss of 36.9% of total solids was recorded. Methane balance indicated that 18.4% of potential methane can be produced during dry AD and 49.7% by the percolate. Nevertheless results obtained for liquid AD digestion indicated that only 20.4% and 25.7% of potential producible methane was generated by adopting 15 and 20 days of HRT, probably due to the AD inhibition due to high presence of toxic ammonia forms in the liquid medium.« less

Comparison of external costs between dry tomb and bioreactor landfills: taking intergenerational effects seriously.

PubMed

Méry, Jacques; Bayer, Stefan

2005-12-01

Dry tomb and bioreactor landfills were analyzed with respect to their external costs in an intergenerational cost-benefit analysis in a partial framework which enabled a sounder comparison to be carried out between these two technologies from a socio-economic viewpoint. Obviously, this approach was only a first step for building a comprehensive basis of any environmental as well as fiscal policy in the field of waste management. All external costs are identified and evaluated in three different scenarios, corresponding to a worst case, a best guess and a best case. Obviously, discounting is crucial with respect to an intergenerational perspective. Generation-adjusted discounting (GAD) was applied to take into account equity as well as efficiency criteria, in order to deal with three different types of uncertainties that are decisive in waste policy decisions: a physical uncertainty is captured by introducing our three different scenarios; a macroeconomic uncertainty is taken into consideration by calculating present values using different real growth rates; and a microeconomic uncertainty is taken into account by considering individual peculiarities reflected in their subjective time preference rate. The findings show, that whenever there is a low real GDP growth of less than 1%, the bioreactor is generally superior to the dry tomb (lower present values of external costs). This statement becomes more valid as the growth rate decreases. However, whenever there are high positive growth rates, it is the dry tomb technology which is superior to the bioreactor system.

Integrated management of hazardous waste generated from community sources in Thailand

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yodnane, P.; Spaeder, D.J.

A system for the collection, transport, disposal and recycling of hazardous waste was developed as part of an overall master plan for the management of hazardous waste generated from community sources in Thailand. Results of a waste generation survey conducted as part of the study indicated that over 300 million kilograms per year of hazardous waste is generated from non-industrial, community sources such as automotive repair shops, gas stations, hospitals, farms, and households in Thailand. Hazardous waste from community sources consists primarily of used oils, lead-acid and dry cell batteries, cleaning chemicals, pesticides, medical wastes, solvents and fuels. Most ofmore » this waste was found to be mismanaged by codisposing with municipal waste in burning, unlined dumps, dumping directly to land or water courses, dumping into sewers, or recycling improperly, all of which pose serious threats to human health and the environment. The survey data on waste generation quantities and data from a reconnaissance survey of the conditions and operations of 86 existing waste disposal facilities was incorporated into a nationwide Geographic Information System (GIS) database. Based on this data, problems associated with hazardous waste were identified and needs for waste management systems were tabulated. A system was developed for ranking geographic regions according to hazardous waste management problems and needs, in order to prioritize implementation of waste management programs. The data were also used in developing solutions for hazardous waste management, which addressed methods for storing, collecting, transporting, disposing, and recycling the waste. It was recommended that centralized waste management facilities be utilized which included hazardous waste and medical waste incinerators, waste stabilization units, and secure landfills.« less

Preliminary trial on degradation of waste activated sludge and simultaneous hydrogen production in a newly-developed solar photocatalytic reactor with AgX/TiO2-coated glass tubes.

PubMed

Liu, Chunguang; Lei, Zhongfang; Yang, Yingnan; Zhang, Zhenya

2013-09-15

A solar fluidized tubular photocatalytic reactor (SFTPR) with simple and efficient light collector was developed to degrade waste activated sludge (WAS) and simultaneously produce hydrogen. The photocatalyst was a TiO2 film doped by silver and silver compounds (AgX). The synthesized photocatalyst, AgX/TiO2, exhibited higher photocatalytic activity than TiO2 (99.5% and 30.6% of methyl orange removal, respectively). The installation of light collector could increase light intensity by 26%. For WAS treatment using the SFTPR, 69.1% of chemical oxygen demand (COD) removal and 7866.7 μmol H2/l-sludge of hydrogen production were achieved after solar photocatalysis for 72 h. The SFTPR could be a promising photocatalysis reactor to effectively degrade WAS with simultaneous hydrogen production. The results can also provide a useful base and reference for the application of photocatalysis on WAS degradation in practice. Copyright © 2013 Elsevier Ltd. All rights reserved.

Simultaneous recovery of Ni and Cu from computer-printed circuit boards using bioleaching: statistical evaluation and optimization.

PubMed

Arshadi, M; Mousavi, S M

2014-12-01

Computer printed circuit boards (CPCBs) have a rich metal content and are produced in high volume, making them an important component of electronic waste. The present study used a pure culture of Acidithiobacillus ferrooxidans to leach Cu and Ni from CPCBs waste. The adaptation phase began at 1g/l CPCBs powder with 10% inoculation and final pulp density was reached at 20g/l after about 80d. Four effective factors including initial pH, particle size, pulp density, and initial Fe(3+) concentration were optimized to achieve maximum simultaneous recovery of Cu and Ni. Their interactions were also identified using central composite design in response surface methodology. The suggested optimal conditions were initial pH 3, initial Fe(3+) 8.4g/l, pulp density 20g/l and particle size 95μm. Nearly 100% of Cu and Ni were simultaneously recovered under optimum conditions. Finally, bacterial growth characteristics versus time at optimum conditions were plotted. Copyright © 2014 Elsevier Ltd. All rights reserved.

Experimental digester facility modifications and digester gas upgrading research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Srivastava, V.J.; Biljetina, R.; Akin, C.

1989-01-01

The Institute of Gas Technology (IGT) has been participating in an experimental program at the Community Waste Research Facility (CWRF) located at the Walt Disney World Resort Complex, Orlando, Florida. Four institutions have formed a team to provide solutions to community waste treatment and disposal programs. Of primary importance to this research effort is the implementation of low-cost, energy-efficient waste treatment and recovery technologies and the net production of energy (methane) from biomass and waste resources. The production of methane is being studied in a novel, high-rate digester. During 1988, we were responsible for modifying the Experimental Test Unit (ETU)more » to permit dry solids feeding of refuse-derived fuel (RDF) and for conducting bench-scale experiments to evaluate techniques for efficient removal of carbon dioxide produced during anaerobic digestion.« less

Improve protective clothing and reduce radwaste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnstone, G.A.; Fryer, J.; Smith, J.M.

1995-12-31

Nuclear power plants have been reducing radioactive waste production through aggressive volume reduction and control at the point of generation. Waste reduction efforts may, however, have reached a plateau. Certain items, such as protective clothing, are a necessary part of plant operations and cannot be eliminated. There are more than 800,000 sets of protective clothing currently in use at U.S. nuclear plants. Since up to 25% of these garments are removed from service each year, spent protective wear accounts for {approximately}100,000 ft{sup 3} of prevolume reduced waste annually. Furthermore, up to 10% of dry active waste produced at commercial powermore » reactor sites is comprised of exhausted protective clothing and related goods. This report describes the design of protective clothing which lasts longer and is lighter than traditional fabrics.« less

Napropamide residues in runoff and infiltration water from pepper production.

PubMed

Antonious, George F; Patterson, Matthew A

2005-01-01

A field study was conducted on a Lowell silty loam soil of 2.7% organic matter at the Kentucky State University Research Farm, Franklin County, Kentucky. Eighteen universal soil loss equation (USLE) standard plots (22 x 3.7 m each) were established on a 10% slope. Three soil management practices were used: (i) class-A biosolids (sewage sludge), (ii) yard waste compost, each mixed with native soil at a rate of 50 ton acre(-1) on a dry-weight basis, and (iii) a no-mulch (NM) treatment (rototilled bare soil), used for comparison purposes. Devrinol 50-DF "napropamide" [N,N-diethyl-2-(1-naphthyloxy) propionamide] was applied as a preemergent herbicide, incorporated into the soil surface, and the plots were planted with 60-day-old sweet bell pepper seedlings. Napropamide residues one hour following spraying averaged 0.8, 0.4, and 0.3 microg g(-1) dry soil in sewage sludge, yard waste compost, and no-mulch treatments, respectively. Surface runoff water, runoff sediment, and napropamide residues in runoff were significantly reduced by the compost and biosolid treatments. Yard waste compost treatments increased water infiltration and napropamide residues in the vadose zone compared to sewage sludge and NM treatments. Total pepper yields from yard waste compost amended soils (9187 lbs acre(-1)) was significantly higher (P < 0.05) than yield from either the soil amended with class-A biosolids (6984 lbs acre(-1)) or the no-mulch soil (7162 lbs acre(-1)).

Performance and kinetic study of semi-dry thermophilic anaerobic digestion of organic fraction of municipal solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sajeena Beevi, B., E-mail: sajeenanazer@gmail.com; Madhu, G., E-mail: profmadhugopal@gmail.com; Sahoo, Deepak Kumar, E-mail: dksahoo@gmail.com

2015-02-15

Highlights: • Performance of the reactor was evaluated by the degradation of volatile solids. • Biogas yield at the end of the digestion was 52.9 L/kg VS. • Value of reaction rate constant, k, obtained was 0.0249 day{sup −1}. • During the digestion 66.7% of the volatile solid degradation was obtained. - Abstract: Anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW) is promoted as an energy source and waste disposal. In this study semi dry anaerobic digestion of organic solid wastes was conducted for 45 days in a lab-scale batch experiment for total solid concentration ofmore » 100 g/L for investigating the start-up performances under thermophilic condition (50 °C). The performance of the reactor was evaluated by measuring the daily biogas production and calculating the degradation of total solids and the total volatile solids. The biogas yield at the end of the digestion was 52.9 L/kg VS (volatile solid) for the total solid (TS) concentration of 100 g/L. About 66.7% of the volatile solid degradation was obtained during the digestion. A first order model based on the availability of substrate as the limiting factor was used to perform the kinetic studies of batch anaerobic digestion system. The value of reaction rate constant, k, obtained was 0.0249 day{sup −1}.« less

Bio-charcoal production from municipal organic solid wastes

NASA Astrophysics Data System (ADS)

AlKhayat, Z. Q.

2017-08-01

The economic and environmental problems of handling the increasingly huge amounts of urban and/or suburban organic municipal solid wastes MSW, from collection to end disposal, in addition to the big fluctuations in power supply and other energy form costs for the various civilian needs, is studied for Baghdad city, the ancient and glamorous capital of Iraq, and a simple control device is suggested, built and tested by carbonizing these dried organic wastes in simple environment friendly bio-reactor in order to produce low pollution potential, economical and local charcoal capsules that might be useful for heating, cooking and other municipal uses. That is in addition to the solve of solid wastes management problem which involves huge human and financial resources and causes many lethal health and environmental problems. Leftovers of different social level residential campuses were collected, classified for organic materials then dried in order to be supplied into the bio-reactor, in which it is burnt and then mixed with small amounts of sugar sucrose that is extracted from Iraqi planted sugar cane, to produce well shaped charcoal capsules. The burning process is smoke free as the closed burner’s exhaust pipe is buried 1m underground hole, in order to use the subsurface soil as natural gas filter. This process has proved an excellent performance of handling about 120kg/day of classified MSW, producing about 80-100 kg of charcoal capsules, by the use of 200 l reactor volume.

Methods and system for subsurface stabilization using jet grouting

DOEpatents

Loomis, Guy G.; Weidner, Jerry R.; Farnsworth, Richard K.; Gardner, Bradley M.; Jessmore, James J.

1999-01-01

Methods and systems are provided for stabilizing a subsurface area such as a buried waste pit for either long term storage, or interim storage and retrieval. A plurality of holes are drilled into the subsurface area with a high pressure drilling system provided with a drill stem having jet grouting nozzles. A grouting material is injected at high pressure through the jet grouting nozzles into a formed hole while the drill stem is withdrawn from the hole at a predetermined rate of rotation and translation. A grout-filled column is thereby formed with minimal grout returns, which when overlapped with other adjacent grout-filled columns encapsulates and binds the entire waste pit area to form a subsurface agglomeration or monolith of grout, soil, and waste. The formed monolith stabilizes the buried waste site against subsidence while simultaneously providing a barrier against contaminate migration. The stabilized monolith can be left permanently in place or can be retrieved if desired by using appropriate excavation equipment. The jet grouting technique can also be utilized in a pretreatment approach prior to in situ vitrification of a buried waste site. The waste encapsulation methods and systems are applicable to buried waste materials such as mixed waste, hazardous waste, or radioactive waste.

Effect of different drying techniques on flowability characteristics and chemical properties of natural carbohydrate-protein Gum from durian fruit seed

PubMed Central

2013-01-01

Background A natural carbohydrate biopolymer was extracted from the agricultural biomass waste (durian seed). Subsequently, the crude biopolymer was purified by using the saturated barium hydroxide to minimize the impurities. Finally, the effect of different drying techniques on the flow characteristics and functional properties of the purified biopolymer was investigated. The present study elucidated the main functional characteristics such as flow characteristics, water- and oil-holding capacity, solubility, and foaming capacity. Results In most cases except for oven drying, the bulk density decreased, thus increasing the porosity. This might be attributed to the increase in the inter-particle voids of smaller sized particles with larger contact surface areas per unit volume. The current study revealed that oven-dried gum and freeze-dried gum had the highest and lowest compressibility index, thus indicating the weakest and strongest flowability among all samples. In the present work, the freeze-dried gum showed the lowest angle of repose, bulk, tapped and true density. This indicates the highest porosity degree of freeze dried gum among dried seed gums. It also exhibited the highest solubility, and foaming capacity thus providing the most desirable functional properties and flow characteristics among all drying techniques. Conclusion The present study revealed that freeze drying among all drying techniques provided the most desirable functional properties and flow characteristics for durian seed gum. PMID:23289739

Effective moisture diffusivity and activation energy of rambutan seed under different drying methods to promote storage stability

NASA Astrophysics Data System (ADS)

Ahmad, So'bah; Shamsul Anuar, Mohd; Saleena Taip, Farah; Shamsudin, Rosnah; M, Siti Roha A.

2017-05-01

The effects of two drying methods, oven and microwave drying on the effective moisture diffusivity and activation energy of rambutan seed were studied. Effective moisture diffusivity and activation energy are the main indicators used for moisture movement within the material. Hence, it is beneficial to determine an appropriate drying method to attain a final moisture content of rambutan seed that potentially could be used as secondary sources in the industry. An appropriate final moisture content will provide better storage stability that can extend the lifespan of the rambutan seed. The rambutan seeds were dried with two drying methods (oven and microwave) at two level of the process variables (oven temperature; 40°C and 60°C and microwave power; 250W and 1000W) at constant initial moisture contents. The result showed that a higher value of effective moisture diffusivity and less activation energy were observed in microwave drying compared to oven drying. This finding portrays microwave drying expedites the moisture removal to achieve the required final moisture content and the most appropriate drying method for longer storage stability for rambutan seed. With respect to the process variables; higher oven temperatures and lower microwave powers also exhibit similar trends. Hopefully, this study would provide a baseline data to determine an appropriate drying method for longer storage period for turning waste to by-products.

Total phenolics content, anthocyanins, and dietary fiber content of apple pomace powders produced by vacuum-belt drying.

PubMed

Yan, Huitong; Kerr, William L

2013-04-01

Apple pomace is a waste material from apple juice processing, and contains significant amounts of dietary fiber and phytochemicals. Many of these compounds may be degraded post-pressing and during drying operations. Continuous vacuum-belt drying (VBD) was studied as a means of drying and maintaining quality of apple pomace. The color and chemical properties of samples dried by vacuum-belt drying at different temperatures were evaluated including total phenolics content (TPC), monomeric anthocyanins (TMA) and dietary fiber content (TDF). VBD powders were pale golden yellow, and those dried at 80°C did not differ in L*, a* and b* values from freeze-dried powders. VBD pomace had 44.9 to 51.9 g gallic acid equivalents kg(-1) TPC, with greatest retention for pomace dried at 80 and 95°C. TPC for pomace dried at 80 or 95°C was not significantly different from that for freeze-dried pomace. TMA levels (74.0 mg C3G kg(-1), where C3G is cyanidine 3-O-glucoside equivalents) were highest in pomace vacuum dried at 80°C. TDF ranged from 442 to 495 g kg(-1) in vacuum-dried pomace and was not significantly different from TDF of freeze-dried poamce (480 g kg(-1)). In all cases, TPC, TMA and TDF were higher in VBD pomace than in freeze-dried whole apple, while VBD pomace prepared at 80 or 95°C had fiber and phytochemical levels similar to freeze-dried powders. © 2012 Society of Chemical Industry.

Real-time Control of sewer pumps by using ControlNEXT to smooth inflow at Waste Water Treatment Plant Garmerwolde

NASA Astrophysics Data System (ADS)

van Heeringen, Klaas-Jan; van Nooijen, Ronald; Kooij, Kees; Postma, Bokke

2016-04-01

The Garmerwolde waste water treatment plant (WWTP) in the Groningen area of the Netherlands, receives waste water from a large area. That waste water is collected from many sewer systems and transported to the WWTP through pressurized pipes. The supply of waste water to the WWTP is relatively low and very irregular during dry-weather conditions, resulting in a random pattern of flows. This irregularity is the effect of the local control of the pumps, where the pumps are individually operated as an on/off control based on the water levels in the connected sewer system. The influent may change from zero to high values in a few minutes. The treatment processes at the WWTP are negatively influenced by this irregularity, which ends in high costs for energy and use of chemicals. The ControlNEXT central control system is used to control the 5 largest pump stations, such that the total inflow at the WWTP becomes much smoother. This results in a reduction of operational costs of about 10%. The control algorithm determines whether the actual condition is dry or wet, based on real-time radar precipitation images and the rainfall forecast product HiRLAM. All actual data is also collected and validated, like water levels, pump operations and pump availability. This data management is done using Delft-FEWS. If the situation is identified as "wet", the sewer systems are emptied as far as possible to create maximum storage. If the situation is "dry" (and of course there is a dead band between dry and wet), the pumps are operated such that the total inflow into the WWTP is smoothed. This is done with a Greedy algorithm, developed by Delft University of Technology. The algorithm makes a plan for the next 24 hours (as the daily inflow has a typical daily pattern) and generally stores some water volume in the sewer systems during the day to be able to continue operations during the night. The pumps are controlled with a time step of 5 minutes, where ControlNEXT manages the communication of pump operation setpoints to the SCADA system. In case of failing communication, backup procedures are programmed in the PLC of the pump stations. In that case the old on/off operation based on local water levels will be used. The system has been operational since January 2016 and has been monitored since then. In addition to monitoring the positive effect on the inflow at the WWTP, an important issue is the possible sedimentation in the sewer systems. This will be monitored too.

Utilization of solid catfish manure waste as carbon and nutrient source for lactic acid production.

PubMed

Shi, Suan; Li, Jing; Blersch, David M

2018-06-01

The aim of this work was to study the solid waste (manure) produced by catfish as a potential feedstock for the production of lactic acid (LA) via fermentation. The solid waste contains high levels of both carbohydrates and nutrients that are sufficient for LA bacteria. Simultaneous saccharification and co-fermentation (SSCF) was applied using enzyme and Lactobacillus pentosus, and different loadings of enzyme and solid waste were tested. Results showed LA concentrations of 35.7 g/L were obtained at 15% solids content of catfish waste. Because of the high nutrient content in the fish waste, it could also be used as supplementary substrate for nitrogen and carbon sources with other lignocellulosic materials. A combined feedstock of catfish waste and paper mill sludge was tested, increasing the final LA concentration to 43.1 g/L at 12% solids loading. The catfish waste was shown to be a potential feedstock to provide both carbon and nutrients for LA production, suggesting its use as a sole substrate or in combination with other lignocellulosic materials.

Round-bale feeder design affects hay waste and economics during horse feeding.

PubMed

Martinson, K; Wilson, J; Cleary, K; Lazarus, W; Thomas, W; Hathaway, M

2012-03-01

Many horse owners find round bales convenient, less labor intensive, and more affordable than other hay types, but report an inability to control horse BW gain and excessive hay waste. The objectives were to compare hay waste, hay intake, and payback of 9 round-bale feeders and a no-feeder control when used during horse feeding. Nine round-bale feeders were tested: Cinch Net, Cone, Covered Cradle, Hayhut, Hay Sleigh, Ring, Tombstone, Tombstone Saver, and Waste Less. Each feeder design was placed on the ground in a dirt paddock. Five groups of 5 horses were fed in rotation for a 4-d period with each feeder. Every fourth day, groups were rotated among paddocks and a new round bale was placed in each feeder. In the 5 paddocks used, 5 feeders were installed for d 1 through 20, and the remaining 4 feeders and no-feeder control were installed for d 21 through 40. Groups of horses were sequentially assigned to feeders using two 5 × 5 Latin squares, the first for d 1 through 20, the second for d 21 through 40. Horse groups of similar age, BW, breed, and sex were formed from 25 Quarter Horse and Thoroughbred geldings and open mares (means: 11 yr; 541 kg of BW). Hay on the ground surrounding the feeder was collected daily, dried, and weighed. The total amount of hay removed around each feeder for a 4-d period was considered waste. Dry matter intake was estimated as the difference between hay disappearance and waste. Number of months for the reduction in waste to repay feeder cost (payback) were calculated using hay valued at $110/t, and improved feeder efficiency over the control. Feeder design did not affect hay intake (P > 0.05); all feeders resulted in an estimated hay intake of 2.0 to 2.4% BW; the no-feeder control resulted in a reduced intake of 1.3% BW (P = 0.001). Mean percentage of hay waste differed among feeders (P < 0.001): Waste Less, 5%; Cinch Net, 6%; Hayhut, 9%; Covered Cradle, 11%; Tombstone Saver, 13%; Tombstone, Cone, and Ring, 19%; Hay Sleigh, 33%; and no-feeder control, 57%. Feeder design also affected payback (P < 0.01). The Cinch Net paid for itself in less than 1 mo; Tombstone and Ring, 2 mo; Hayhut and Tombstone Saver, 4 mo; Hay Sleigh, 5 mo; Waste Less, 8 mo; Cone, 9 mo; and Covered Cradle, 20 mo. Round-bale feeder design affected hay waste and payback, but not estimated hay intake or BW change during horse feeding.

Health risk assessment as an approach to manage an old landfill and to propose integrated solid waste treatment: A case study in Italy.

PubMed

Paladino, O; Massabò, M

2017-10-01

The aim of the present paper is to show how an approach based on human health risk analysis can be used as a decisional tool for the evaluation of impacts on population and for deciding between different waste treatment processes. The situation in which the increasing production of solid wastes cannot be confined in the old existing Municipal Solid Waste landfill (settled in Genoa, Liguria Region, Italy) is used as a case study. Risk assessment for human health due to air, surface water, groundwater and soil contamination is performed in different scenarios for the old landfill and compared with alternative Waste-to-Energy management solutions that consider thermal treatment by gasification of the total waste or gasification of the dry fraction coupled with anaerobic digestion of the wet fraction, plus biogas combustion with or without sludge and bottom ash/slag disposal in the old landfill. Hazard Index (HI) and Cancer Risk (CR) in case of operating landfill and under the suspected situation of failure of the sealing system, were respectively 1.15 and 1.1∗10 -7 . Unacceptable HI were found due to groundwater contamination, while HI due to river pollution was slightly under the threshold. Vegetables ingestion was the most important pathway and ammonia the most responsible of toxic adverse effects. Fish ingestion and dermal contact with contaminated water were found to be the most important exposure pathways for carcinogenic risk, due mainly to BTEX. HI and CR in the supposed scenario of total waste gasification were respectively 9.4∗10 -1 and 1.1∗10 -5 while they were respectively 3.2∗10 -1 and 6∗10 -6 in case of gasification of the dry fraction. CR in both scenarios was over the threshold mainly due to dioxins, where milk and meat ingestion were found to be the highest risk pathways. Inhalation resulted as the highest not-carcinogenic risk exposure pathway, mainly due to NOx. Decision making was made by weighing up the different scenarios, and results suggested to definitively close the landfill and to eliminate gasification of the total waste as a possible waste treatment process. Copyright © 2017 Elsevier Ltd. All rights reserved.

Dry-thermophilic anaerobic digestion of organic fraction of municipal solid waste: Methane production modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fdez-Gueelfo, L.A., E-mail: alberto.fdezguelfo@uca.es; Alvarez-Gallego, C.; Sales, D.

2012-03-15

Highlights: Black-Right-Pointing-Pointer Methane generation may be modeled by means of modified product generation model of Romero Garcia (1991). Black-Right-Pointing-Pointer Organic matter content and particle size influence the kinetic parameters. Black-Right-Pointing-Pointer Higher organic matter content and lower particle size enhance the biomethanization. - Abstract: The influence of particle size and organic matter content of organic fraction of municipal solid waste (OFMSW) in the overall kinetics of dry (30% total solids) thermophilic (55 Degree-Sign C) anaerobic digestion have been studied in a semi-continuous stirred tank reactor (SSTR). Two types of wastes were used: synthetic OFMSW (average particle size of 1 mm; 0.71more » g Volatile Solids/g waste), and OFMSW coming from a composting full scale plant (average particle size of 30 mm; 0.16 g Volatile Solids/g waste). A modification of a widely-validated product-generation kinetic model has been proposed. Results obtained from the modified-model parameterization at steady-state (that include new kinetic parameters as K, Y{sub pMAX} and {theta}{sub MIN}) indicate that the features of the feedstock strongly influence the kinetics of the process. The overall specific growth rate of microorganisms ({mu}{sub max}) with synthetic OFMSW is 43% higher compared to OFMSW coming from a composting full scale plant: 0.238 d{sup -1} (K = 1.391 d{sup -1}; Y{sub pMAX} = 1.167 L CH{sub 4}/gDOC{sub c}; {theta}{sub MIN} = 7.924 days) vs. 0.135 d{sup -1} (K = 1.282 d{sup -1}; Y{sub pMAX} = 1.150 L CH{sub 4}/gDOC{sub c}; {theta}{sub MIN} = 9.997 days) respectively. Finally, it could be emphasized that the validation of proposed modified-model has been performed successfully by means of the simulation of non-steady state data for the different SRTs tested with each waste.« less

Utilization of papaya waste and oil production by Chlorella protothecoides

USDA-ARS?s Scientific Manuscript database

Algae derived oils have outstanding potential for use in biodiesel production. Chlorella protothecoides has been shown to accumulate lipid up to 60% of its cellular dry weight with glucose supplementation under heterotrophic growth conditions. To reduce production costs, alternative carbon feedstock...

Hydrothermal carbonization of animal manures: Processes and energetics

USDA-ARS?s Scientific Manuscript database

Hydrothermal carbonization (HTC) is an emerging technology for thermochemically converting biomass and waste materials into value-added carbonaceous char called hydrochar. HTC is well suited to manage wet feedstocks streams because pre-drying prior to processing is not required as with gasification...

40 CFR 35.918 - Individual systems.

Code of Federal Regulations, 2010 CFR

2010-07-01

... STATE AND LOCAL ASSISTANCE Grants for Construction of Treatment Works-Clean Water Act § 35.918... commercial establishment with waste water flow equal to or smaller than one user equivalent (generally 300 gallons per day dry weather flows) is included. (3) Small commercial establishments. Private...

Mechanism of microwave sterilization in the dry state.

PubMed Central

Jeng, D K; Kaczmarek, K A; Woodworth, A G; Balasky, G

1987-01-01

With an automated computerized temperature control and a specialized temperature measurement system, dry spores of Bacillus subtilis subsp. niger were treated with heat simultaneously in a convection dry-heat oven and a microwave oven. The temperature of the microwave oven was monitored such that the temperature profiles of the spore samples in both heat sources were nearly identical. Under these experimental conditions, we unequivocally demonstrated that the mechanism of sporicidal action of the microwaves was caused solely by thermal effects. Nonthermal effects were not significant in a dry microwave sterilization process. Both heating systems showed that a dwelling time of more than 45 min was required to sterilize 10(5) inoculated spores in dry glass vials at 137 degrees C. The D values of both heating systems were 88, 14, and 7 min at 117, 130, and 137 degrees C, respectively. The Z value was estimated to be 18 degrees C. PMID:3118807

In-line and real-time process monitoring of a freeze drying process using Raman and NIR spectroscopy as complementary process analytical technology (PAT) tools.

PubMed

De Beer, T R M; Vercruysse, P; Burggraeve, A; Quinten, T; Ouyang, J; Zhang, X; Vervaet, C; Remon, J P; Baeyens, W R G

2009-09-01

The aim of the present study was to examine the complementary properties of Raman and near infrared (NIR) spectroscopy as PAT tools for the fast, noninvasive, nondestructive and in-line process monitoring of a freeze drying process. Therefore, Raman and NIR probes were built in the freeze dryer chamber, allowing simultaneous process monitoring. A 5% (w/v) mannitol solution was used as model for freeze drying. Raman and NIR spectra were continuously collected during freeze drying (one Raman and NIR spectrum/min) and the spectra were analyzed using principal component analysis (PCA) and multivariate curve resolution (MCR). Raman spectroscopy was able to supply information about (i) the mannitol solid state throughout the entire process, (ii) the endpoint of freezing (endpoint of mannitol crystallization), and (iii) several physical and chemical phenomena occurring during the process (onset of ice nucleation, onset of mannitol crystallization). NIR spectroscopy proved to be a more sensitive tool to monitor the critical aspects during drying: (i) endpoint of ice sublimation and (ii) monitoring the release of hydrate water during storage. Furthermore, via NIR spectroscopy some Raman observations were confirmed: start of ice nucleation, end of mannitol crystallization and solid state characteristics of the end product. When Raman and NIR monitoring were performed on the same vial, the Raman signal was saturated during the freezing step caused by reflected NIR light reaching the Raman detector. Therefore, NIR and Raman measurements were done on a different vial. Also the importance of the position of the probes (Raman probe above the vial and NIR probe at the bottom of the sidewall of the vial) in order to obtain all required critical information is outlined. Combining Raman and NIR spectroscopy for the simultaneous monitoring of freeze drying allows monitoring almost all critical freeze drying process aspects. Both techniques do not only complement each other, they also provided mutual confirmation of specific conclusions.

Production of a solid fuel using sewage sludge and spent cooking oil by immersion frying.

PubMed

Wu, Zhonghua; Zhang, Jing; Li, Zhanyong; Xie, Jian; Mujumdar, Arun S

2012-12-01

Sewage sludge and spent cooking oil are two main waste sources of modern Chinese cities. In this paper, the immersion frying method using spent cooking oil as the heating medium was applied to dry and convert wet sewage sludge into a solid fuel. The drying and oil uptake curves were plotted to demonstrate the fry-drying characteristics of the sewage sludge. Parametric studies were carried out to identify the governing parameters in the frying drying operation. It was found that at frying oil temperatures of 140-160°C, the wet sewage sludge could be dried completely in 6-9 min and converted into a solid fuel with a high calorific value of 21.55-24.08 MJ/kg. The fuel structure, chemical components, pyrolysis and combustion characteristics were investigated and the experimental results showed the solid fuel had a porous internal structure and a low ignition temperature of 250°C due to presence of oil. The frying drying mechanism was also discussed. Copyright © 2012 Elsevier B.V. All rights reserved.

Performance and Analysis of Floating dome Anaerobic Digester with Wet and Dry Feedstock

NASA Astrophysics Data System (ADS)

Sathish, S.; Parthiban, A.; Venugopal, S.; Jothi Prakash, V. M.

2017-03-01

The objective of this study is to evaluate the feasibility of anaerobic digestion to generate biogas yield and it’s performed using wet and dry feed stock. The laboratory experiment is conducted in a floating dome type anaerobic digester with 1m3 capacity. It is made up of fibre material at continues process. The starter cowdung used as an inoculum of the anaerobic digester. Then raw materials feeded as a wet type wheat straw and dry type wheat straw is the ratio of 1:1 waste/water in both the experiments wet and dry wheat straw. In this experiments are fermented at 30ºC to 35ºC temperature is maintained. The daily biogas yield, cumulative biogas yield, pH, CH4, and hydro retention time these parameters is studied and analysed. The maximum daily biogas is 25liters and 42% of methane is achieved in dry wheat straw at 15th day of digestion. The highest gas yield obtained in dry condition compare to wet condition and acid level also decreased in wet digestion.

Simultaneous Water Vapor and Dry Air Optical Path Length Measurements and Compensation with the Large Binocular Telescope Interferometer

NASA Technical Reports Server (NTRS)

Defrere, D.; Hinz, P.; Downey, E.; Boehm, M.; Danchi, W. C.; Durney, O.; Ertel, S.; Hill, J. M.; Hoffmann, W. F.; Mennesson, B.;

Compost and Crude Humic Substances Produced from Selected Wastes and Their Effects on Zea mays L. Nutrient Uptake and Growth

PubMed Central

Palanivell, Perumal; Susilawati, Kasim; Ahmed, Osumanu Haruna; Majid, Nik Muhamad

2013-01-01

Production of agriculture and timber commodities leads generation of enormous quantity of wastes. Improper disposal of these agroindustrial wastes pollutes the environment. This problem could be reduced by adding value to them. Therefore, a study was carried out to analyse and compare the nutrients content of RS, RH, SD, and EFB of composts and crude humic substances; furthermore, their effect on growth, dry matter production, and nutrient uptake for Zea mays L., and selected soil chemical properties were evaluated. Standard procedures were used to analyze humic acids (HA), crude fulvic acids (CFA), crude humin (CH), soil, dry matter production and nutrient uptake. Sawdust and RS compost matured at 42 and 47 days, respectively, while RH and EFB composts were less matured at 49th day of composting. Rice straw compost had higher ash, N, P, CEC, HA, K, and Fe contents with lower organic matter, total organic carbon, and C/N and C/P ratios. The HA of sawdust compost showed higher carbon, carboxylic, K, and Ca contents compared to those of RS, RH, and EFB. Crude FA of RS compost showed highest pH, total K, Ca, Mg, and Na contents. Crude humin from RS compost had higher contents of ash, N, P, and CEC. Rice straw was superior in compost, CFA, and CH, while sawdust compost was superior in HA. Application of sawdust compost significantly increased maize plants' diameter, height, dry matter production, N, P, and cations uptake. It also reduced N, P, and K based chemical fertilizer use by 90%. Application of CH and the composts evaluated in this study could be used as an alternative for chemical fertilizers in maize cultivation. PMID:24319353

Analysis of Monolith Cores from an Engineering Scale Demonstration of a Prospective Cast Stone Process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crawford, C. L.; Cozzi, A. D.; Hill, K. A.

2016-06-01

The primary disposition path of Low Activity Waste (LAW) at the DOE Hanford Site is vitrification. A cementitious waste form is one of the alternatives being considered for the supplemental immobilization of the LAW that will not be treated by the primary vitrification facility. Washington River Protection Solutions (WRPS) has been directed to generate and collect data on cementitious or pozzolanic waste forms such as Cast Stone. This report documents the coring and leach testing of monolithic samples cored from an engineering-scale demonstration (ES Demo) with non-radioactive simulants. The ES Demo was performed at SRNL in October of 2013 usingmore » the Scaled Continuous Processing Facility (SCPF) to fill an 8.5 ft. diameter x 3.25 ft. high container with simulated Cast Stone grout. The Cast Stone formulation was chosen from the previous screening tests. Legacy salt solution from previous Hanford salt waste testing was adjusted to correspond to the average LAW composition generated from the Hanford Tank Waste Operation Simulator (HTWOS). The dry blend materials, ordinary portland cement (OPC), Class F fly ash, and ground granulated blast furnace slag (GGBFS or BFS), were obtained from Lafarge North America in Pasco, WA. In 2014 core samples originally obtained approximately six months after filling the ES Demo were tested along with bench scale molded samples that were collected during the original pour. A latter set of core samples were obtained in late March of 2015, eighteen months after completion of the original ES Demo. Core samples were obtained using a 2” diameter x 11” long coring bit. The ES Demo was sampled in three different regions consisting of an outer ring, a middle ring and an inner core zone. Cores from these three lateral zones were further segregated into upper, middle and lower vertical segments. Monolithic core samples were tested using the Environmental Protection Agency (EPA) Method 1315, which is designed to provide mass transfer rates (release rates) of inorganic analytes contained in monolithic material under diffusion controlled release conditions as a function of leaching time. Compressive strength measurements and drying tests were also performed on the 2015 samples. Leachability indices reported are based on analyte concentrations determined from dissolution of the dried samples.« less

Dry reforming of methane to syngas: a potential alternative process for value added chemicals-a techno-economic perspective.

PubMed

Mondal, Kartick; Sasmal, Sankar; Badgandi, Srikant; Chowdhury, Dipabali Roy; Nair, Vinod

2016-11-01

During the past decade, there has been increasing global concern over the rise of anthropogenic CO 2 emission into the Earth's atmosphere (J Air Waste Manage Assoc 53:645-715, 2003). The utilization of CO 2 to produce any valuable product is need of the hour. The production of syngas from CO 2 and CH 4 seems to be one of the promising alternatives in terms of industrial utilization, as it offers several advantages: (a) mitigation of CO 2 , (b) transformation of natural gas and CO 2 into valuable syngas, and (c) producing syngas with H 2 /CO ratio 1 which may further be used for the production of valuable petrochemicals (J Air Waste Manage Assoc 53:645-715, 2003). A conceptual design for the production of synthesis gas by dry reforming of methane is presented here. An economic assessment of this process with an integrated methanol production section as a case was conceptualized and compared with the conventional steam methane reforming route to produce methanol. The economic study indicated that dry reforming of natural gas/methane is a competitive process with lower operating and capital costs in comparison with steam reforming assuming negligible cost of CO 2 import.

Evaluation of medium-chain-length polyhydroxyalkanoate production by Pseudomonas putida LS46 using biodiesel by-product streams.

PubMed

Fu, Jilagamazhi; Sharma, Umesh; Sparling, Richard; Cicek, Nazim; Levin, David B

2014-07-01

Medium-chain-length polyhydroxyalkanoate (mcl-PHA) production by Pseudomonas putida LS46 was analyzed in shake-flask-based batch reactions, using pure chemical-grade glycerol (PG), biodiesel-derived "waste" glycerol (WG), and biodiesel-derived "waste" free fatty acids (WFA). Cell growth, substrate consumption, mcl-PHA accumulation within the cells, and the monomer composition of the synthesized biopolymers were monitored. The patterns of mcl-PHA synthesis in P. putida LS46 cells grown on PG and WG were similar but differed from that of cells grown with WFA. Polymer accumulation in glycerol-based cultures was stimulated by nitrogen limitation and plateaued after 48 h in both PG and WG cultures, with a total accumulation of 17.9% cell dry mass and 16.3% cell dry mass, respectively. In contrast, mcl-PHA synthesis was independent of nitrogen concentration in P. putida LS46 cells cultured with WFA, which accumulated to 29% cell dry mass. In all cases, the mcl-PHAs synthesized consisted primarily of 3-hydroxyoctanoate (C(8)) and 3-hydroxydecanoate (C(10)). WG and WFA supported similar or greater cell growth and mcl-PHA accumulation than PG under the experimental conditions used. These results suggest that biodiesel by-product streams could be used as low-cost carbon sources for sustainable mcl-PHA production.

Experimental and modelling studies on a laboratory scale anaerobic bioreactor treating mechanically biologically treated municipal solid waste.

PubMed

Lakshmikanthan, P; Sughosh, P; White, James; Sivakumar Babu, G L

2017-07-01

The performance of an anaerobic bioreactor in treating mechanically biologically treated municipal solid waste was investigated using experimental and modelling techniques. The key parameters measured during the experimental test period included the gas yield, leachate generation and settlement under applied load. Modelling of the anaerobic bioreactor was carried out using the University of Southampton landfill degradation and transport model. The model was used to simulate the actual gas production and settlement. A sensitivity analysis showed that the most influential model parameters are the monod growth rate and moisture. In this case, pH had no effect on the total gas production and waste settlement, and only a small variation in the gas production was observed when the heat transfer coefficient of waste was varied from 20 to 100 kJ/(m d K) -1 . The anaerobic bioreactor contained 1.9 kg (dry) of mechanically biologically treated waste producing 10 L of landfill gas over 125 days.

Waste Handeling Building Conceptual Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

G.W. Rowe

2000-11-06

The objective of the ''Waste Handling Building Conceptual Study'' is to develop proposed design requirements for the repository Waste Handling System in sufficient detail to allow the surface facility design to proceed to the License Application effort if the proposed requirements are approved by DOE. Proposed requirements were developed to further refine waste handling facility performance characteristics and design constraints with an emphasis on supporting modular construction, minimizing fuel inventory, and optimizing facility maintainability and dry handling operations. To meet this objective, this study attempts to provide an alternative design to the Site Recommendation design that is flexible, simple, reliable,more » and can be constructed in phases. The design concept will be input to the ''Modular Design/Construction and Operation Options Report'', which will address the overall program objectives and direction, including options and issues associated with transportation, the subsurface facility, and Total System Life Cycle Cost. This study (herein) is limited to the Waste Handling System and associated fuel staging system.« less

Fabrication of hydroxyapatite from fish bones waste using reflux method

NASA Astrophysics Data System (ADS)

Cahyanto, A.; Kosasih, E.; Aripin, D.; Hasratiningsih, Z.

2017-02-01

The aim of this present study was to investigate the fabrication of hydroxyapatites, which were synthesized from fish bone wastes using reflux method. The fish bone wastes collected from the restaurant were brushed and boiled at 100°C for 10 minutes to remove debris and fat. After drying, the fish bones were crushed, and ball milled into a fine powder. The fish bone wastes were then processed by refluxing using KOH and H3PO4 solutions. The samples were calcined at 900°C and characterized by X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectrometry (FT-IR). The XRD pattern of samples after treatment revealed that the peak of hydroxyapatite was observed and the bands of OH- and PO4 3- were observed by FT-IR. The scanning electron microscope evaluation of sample showed the entangled crystal and porous structure of hydroxyapatite. In conclusion, the hydroxyapatite was successfully synthesized from fish bone wastes using reflux method.

Construction and demolition waste as a source of PVC for recycling.

PubMed

Prestes, Sabrina Moretto Darbello; Mancini, Sandro Donnini; Rodolfo, Antonio; Keiroglo, Raquel Carramillo

2012-02-01

Construction and demolition waste can contain considerable amounts of polyvinyl chloride (PVC). This paper describes a study of the recycling of PVC pipes collected from such waste materials. In a sorting facility for the specific disposal of construction and demolition waste, PVC was found to represent one-third of the plastics separated by workers. Pipes were sorted carefully to preclude any possible contamination by poly(ethylene terephthalate) (PET) found in the waste. The material was ground into two distinct particle sizes (final mesh of 12.7 and 8 mm), washed, dried and recycled. The average formulation of the pipes was determined based on ash content tests and used in the fabrication of a similar compound made mainly of virgin PVC. Samples of recycled pipes and of compound based on virgin material were subjected to tensile and impact tests and provided very similar results. These results are a good indication of the application potential of the recycled material and of the fact that longer grinding to obtain finer particles is not necessarily beneficial.

Combined alkaline hydrolysis and ultrasound-assisted extraction for the release of nonextractable phenolics from cauliflower (Brassica oleracea var. botrytis) waste.

PubMed

Gonzales, Gerard Bryan; Smagghe, Guy; Raes, Katleen; Van Camp, John

2014-04-16

Cauliflower waste contains high amounts phenolic compounds, but conventional solvent extraction misses high amounts of nonextractable phenolics (NEP), which may contribute more to the valorization of these waste streams. In this study, the NEP content and composition of cauliflower waste were investigated. The ability of alkaline hydrolysis, sonication, and their combination to release NEP was assessed. Alkaline hydrolysis with sonication was found to extract the highest NEP content (7.3 ± 0.17 mg gallic acid equivalents (GAE)/g dry waste), which was higher than the extractable fraction. The highest yield was obtained after treatment of 2 M NaOH at 60 °C for 30 min of sonication. Quantification and identification were done using U(H)PLC-DAD and U(H)PLC-ESI-MS(E). Kaempferol and quercetin glucosides along with several phenolic acids were found. The results of the study show that there are higher amounts of valuable health-promoting compounds from cauliflower waste than what is currently described in the literature.

Modeling the economics of landfilling organic processing waste streams

NASA Astrophysics Data System (ADS)

Rosentrater, Kurt A.

2005-11-01

As manufacturing industries become more cognizant of the ecological effects that their firms have on the surrounding environment, their waste streams are increasingly becoming viewed not only as materials in need of disposal, but also as resources that can be reused, recycled, or reprocessed into valuable products. Within the food processing sector are many examples of various liquid, sludge, and solid biological and organic waste streams that require remediation. Alternative disposal methods for food and other bio-organic manufacturing waste streams are increasingly being investigated. Direct shipping, blending, extrusion, pelleting, and drying are commonly used to produce finished human food, animal feed, industrial products, and components ready for further manufacture. Landfilling, the traditional approach to waste remediation, however, should not be dismissed entirely. It does provide a baseline to which all other recycling and reprocessing options should be compared. This paper discusses the implementation of a computer model designed to examine the economics of landfilling bio-organic processing waste streams. Not only are these results applicable to food processing operations, but any industrial or manufacturing firm would benefit from examining the trends discussed here.

ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM- 2007

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, B; Ruel Waltz, R

2008-06-05

Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. The 2007 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. A very small amount of material had seeped from Tank 12 from a previously identified leaksite. The material observed had dried on the tank wall and did not reach the annulus floor. A total of 5945 photographs were made and 1221 visual and video inspections were performed during 2007. Additionally, ultrasonic testing was performed on four Waste Tanksmore » (15, 36, 37 and 38) in accordance with approved inspection plans that met the requirements of WSRC-TR-2002- 00061, Revision 2 'In-Service Inspection Program for High Level Waste Tanks'. The Ultrasonic Testing (UT) In-Service Inspections (ISI) are documented in a separate report that is prepared by the ISI programmatic Level III UT Analyst. Tanks 15, 36, 37 and 38 are documented in 'Tank Inspection NDE Results for Fiscal Year 2007'; WSRC-TR-2007-00064.« less

Study on Fired Clay Bricks by Replacing Clay with Palm Oil Waste: Effects on Physical and Mechanical Properties

NASA Astrophysics Data System (ADS)

Kadir, A. A.; Sarani, N. A.; Abdullah, M. M. A. B.; Perju, M. C.; Sandu, A. V.

2017-06-01

Palm oil is one of the major agricultural industries in Malaysia. Due to the poor management system, the discarded palm oil waste has always been linked to the environment issues. During processing of palm oil, a considerable amount of solid waste by-products in the form of fibres, shells, empty fruit bunches and fly ashes are produce rapidly. Therefore, this study was conducted to incorporate 1%, 5% and 10% of palm oil waste into fired clay brick. Samples of brick were fired at 1050°C temperature with heating rates of 1°C/min. Manufactured bricks were tested with physical and mechanical properties including firing shrinkage, dry density, water absorption and compressive strength. The results demonstrated that the replacement of 1% up to 5% of palm oil waste had improved several properties, although, a decrease of performance in certain aspects has also been observed. As a result, palm oil waste can be utilized in an environmentally safe way into fired clay brick thus providing adequate properties of fired clay brick.

Process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

DOEpatents

Colombo, Peter; Kalb, Paul D.; Heiser, III, John H.

1997-11-14

The present invention provides a method for encapsulating and stabilizing radioactive, hazardous and mixed wastes in a modified sulfur cement composition. The waste may be incinerator fly ash or bottom ash including radioactive contaminants, toxic metal salts and other wastes commonly found in refuse. The process may use glass fibers mixed into the composition to improve the tensile strength and a low concentration of anhydrous sodium sulfide to reduce toxic metal solubility. The present invention preferably includes a method for encapsulating radioactive, hazardous and mixed wastes by combining substantially anhydrous wastes, molten modified sulfur cement, preferably glass fibers, as well as anhydrous sodium sulfide or calcium hydroxide or sodium hydroxide in a heated double-planetary orbital mixer. The modified sulfur cement is preheated to about 135.degree..+-.5.degree. C., then the remaining substantially dry components are added and mixed to homogeneity. The homogeneous molten mixture is poured or extruded into a suitable mold. The mold is allowed to cool, while the mixture hardens, thereby immobilizing and encapsulating the contaminants present in the ash.

Cellulose-based films prepared directly from waste newspapers via an ionic liquid.

PubMed

Xia, Guangmei; Wan, Jiqiang; Zhang, Jinming; Zhang, Xiaoyu; Xu, Lili; Wu, Jin; He, Jiasong; Zhang, Jun

2016-10-20

Waste newspapers, composed of cellulose (>60wt%), lignin (∼15wt%), hemicellulose (∼10wt%) and other additives, are one kind of low-cost, easily collected and abundant resources. In order to get value-added products from this waste, in this work an attempt was made to directly convert waste newspapers into cellulose-based films by employing an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl) as a solvent. Most of the organic substances in this waste were dissolved quickly in AmimCl under mild conditions, and then coagulated and dried. Although containing lignin, hemicellulose and inorganic additives, the regenerated cellulose-based films were smooth, compact and semi-transparent, and exhibited good mechanical properties. If the newspaper/AmimCl solution was filtered to remove undissolved inorganic substances, the regenerated films became transparent and had a tensile strength of 80MPa. Thus, this work provides a new, simple and highly efficient way to achieve a high-valued utilization of waste newspapers for packaging and wrapping. Copyright © 2016 Elsevier Ltd. All rights reserved.